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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

history  

National Nuclear Security Administration (NNSA)

highlights of the site's history now is available for viewing on the Y-12 public Web site at

2

Video Navigation with a Personal Viewing History Abir Al-Hajri, Gregor Miller, Sidney Fels, and Matthew Fong  

E-Print Network [OSTI]

Video Navigation with a Personal Viewing History Abir Al-Hajri, Gregor Miller, Sidney Fels, Canada {abira, gregor, ssfels, mfong}@ece.ubc.ca Abstract. We describe a new video interface based previously viewed intervals, highlight segments of video the user found interesting and support other video

Millerm Gregor

3

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History History A repository for images about our legacy as a Laboratory. News Releases Media Contacts Videos Photos Fact Sheets Social Media PHOTOS BY TOPIC Careers Community...

4

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The target chamber under construction. Holes in the target chamber provide access for the laser beams and viewing ports for NIF diagnostic equipment. Photo Number: NIF-1209-18056...

5

It's Elemental - The Element Sulfur  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phosphorus Phosphorus Previous Element (Phosphorus) The Periodic Table of Elements Next Element (Chlorine) Chlorine The Element Sulfur [Click for Isotope Data] 16 S Sulfur 32.065 Atomic Number: 16 Atomic Weight: 32.065 Melting Point: 388.36 K (115.21°C or 239.38°F) Boiling Point: 717.75 K (444.60°C or 832.28°F) Density: 2.067 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 16 Group Name: Chalcogen What's in a name? From the Sanskrit word sulvere and the Latin word sulphurium. Say what? Sulfur is pronounced as SUL-fer. History and Uses: Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a

6

ESnet History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site Feedback: info@es.net ESnet History View ESnet's 25-year anniversary timeline in...

7

Offshore Sulfur Comes In  

Science Journals Connector (OSTI)

Offshore Sulfur Comes In ... "The deposit is a major new source of sulfur," say Hines H. Baker, president of Humble Oil, and Langbourne M. Williams, president of Freeport Sulphur. ... Humble's deposit, known as Grand Isle (Block 18), was discovered in the course of offshore oil exploration and it ranks among the most important sulfur discoveries of recent years. ...

1956-10-01T23:59:59.000Z

8

Analyses of sulfur-asphalt field trials in Texas  

E-Print Network [OSTI]

128 LIST OF FIGURES FIGURE PAGF Layout of SNPA sulfur bitumen binder pavem nt test ? U. S. Highway 69, Lufkin, Texas 15 Col 1oi d mi 1 1 furnished by SNPA for preparation of sul fur-asphalt emulsions View of mixing station showing sulfur... designed to investigate the advantage of using a colloid mill to prepare sulfur-asphalt binders as compared to comingling the asphalt and molten sulfur in a pipeline leading directly to the pug mill. After only six months of testing, the results...

Newcomb, David Edward

1979-01-01T23:59:59.000Z

9

ADVANCED SULFUR CONTROL CONCEPTS  

SciTech Connect (OSTI)

Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

2003-01-01T23:59:59.000Z

10

Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single...

11

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for LithiumSulfur Cells Lawrence Berkeley National...

12

Elemental sulfur recovery process  

DOE Patents [OSTI]

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

13

Chapter 11 - Sulfur Recovery  

Science Journals Connector (OSTI)

Abstract Sulfur is present in many raw industrial gases and in natural gas in the form of hydrogen sulfide. Sulfur removal facilities are located at the majority of oil and gas processing facilities throughout the world. The sulfur recovery unit does not make a profit for the operator but it is an essential processing step to allow the overall facility to operate, as the discharge of sulfur compounds to the atmosphere is severely restricted by environmental regulations. Concentration levels of H2S vary significantly depending upon their source. H2S produced from absorption processes, such as amine treating of natural gas or refinery gas, can contain 5075% H2S by volume or higher. This chapter provides information about fundamentals of sulfur removal facilities in the natural gas industry.

Alireza Bahadori

2014-01-01T23:59:59.000Z

14

Bacterial Sulfur Storage Globules  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by I. J. Pickering and G. N. George by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as far back as 1887 (1); all known forms (or allotropes) of elemental sulfur are solid at room temperature, but globule sulfur has been described as "liquid", and it apparently has a low density – 1.3 compared to 2.1 for the common yellow allotrope a-sulfur. Various exotic forms of sulfur have been proposed to explain these properties, including micelles (small bubble-like structures) formed from long-chain polythionates, but all of these deductions have been based upon indirect evidence (for example the density was estimated by flotation of intact cells), and many questions remained.

15

Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities  

U.S. Energy Information Administration (EIA) Indexed Site

(Percent) (Percent) Type: Sulfur Content API Gravity Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Type Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 1.43 1.38 1.41 1.43 1.47 1.42 1985-2013 PADD 1 0.75 0.73 0.69 0.68 0.73 0.68 1985-2013 East Coast 0.67 0.66 0.61 0.63 0.66 0.57 1985-2013 Appalachian No. 1 2.0 1.72 1.52 1.40 1.55 1.74 1985-2013 PADD 2 1.42 1.34 1.44 1.46 1.61 1.49 1985-2013 Ind., Ill. and Ky. 1.45 1.36 1.47 1.56 1.75 1.67 1985-2013 Minn., Wis., N. Dak., S. Dak. 2.33 2.11 2.18 2.03 2.01 1.69 1985-2013 Okla., Kans., Mo. 0.89 0.89 0.92 0.82 0.87 0.85 1985-2013 PADD 3 1.54 1.48 1.51 1.52 1.54 1.48 1985-2013

16

history | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

highlights of the site's history now is available for viewing on the Y-12 public Web site at http:www.y12.doe.gov Office of Secure Transportation History Since 1947,...

17

Freeport Begins Offshore Sulfur Plant  

Science Journals Connector (OSTI)

Freeport Begins Offshore Sulfur Plant ... Discovered by Humble Oil & Refining, the sulfur deposit off Grand Isle is believed by industry observers to be one of the largest discovered in recent years. ...

1958-07-07T23:59:59.000Z

18

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

19

Why sequence Alkaliphilic sulfur oxidizing bacteria for sulfur pollution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alkaliphilic sulfur oxidizing Alkaliphilic sulfur oxidizing bacteria for sulfur pollution remediation? Burning sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such as air pollution and acid rain, besides contributing to the loss of the ozone layer. One method of managing sulfur compounds released as byproducts from industrial processes is to scrub them out using chemical treatments and activated charcoal beds. A lower-cost solution relies on incorporating alkaliphic sulfur-oxidizing bacteria into biofilters to convert the volatile and toxic compounds into insoluble sulfur for easier removal. Discovered in the last decade, these bacteria have been found to thrive in habitats that span the full pH range. The bacteria could have applications

20

Why sequence purple sulfur bacteria?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

purple sulfur bacteria? purple sulfur bacteria? The process by which plants and some bacteria can convert light energy to sugar, or photosynthesis, is crucial to global food webs, and complicated. Very little is known about the photosynthetic bacteria in the purple sulfur bacteria group, which may represent one of the most primitive photosynthetic organisms and are capable of carbon fixation and sequestration in both light and dark conditions with the help of sulfur compounds. Purple sulfur bacteria are autotrophic and can synthesize organic compounds from inorganic sources. Researchers hope to learn more by sequencing nine type strains of purple sulfur bacteria that are found in freshwater, brackish and marine systems. The information would lead to a better understanding of the process of photosynthesis as well as the global

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Microbial transformations of sulfur compounds  

Science Journals Connector (OSTI)

Oct 13, 1978 ... tains a large part of the chemical energy transferred ... ical energy is partly preserved in the bio- mass of .... ethanol to remove elemental sulfur.

2000-01-10T23:59:59.000Z

22

GoddardView Welcome Home!  

E-Print Network [OSTI]

GoddardView Welcome Home! Pg 2 - 3 History's Greatest Comet Hunter Pg 8 Employee Spotlight: Ernest Program Ends Amid Kudos - 6 Engineers Organize With A Desire To Inspire - 7 History's Greatest Comet on the runway at Edwards Air Force Base, California, after a safe landing August 9, 2005. Photo Credit: NASA 02

Christian, Eric

23

Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes  

SciTech Connect (OSTI)

Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

2014-06-17T23:59:59.000Z

24

Beam History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beam History Print Beamline History Request Form To request a beam current histograph from the ALS storage ring beam histograph database, select the year, month, and day, then...

25

Beam History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beam Status Beam History Print Beamline History Request Form To request a beam current histograph from the ALS storage ring beam histograph database, select the year, month, and...

26

Sulfur minimization in bacterial leaching  

SciTech Connect (OSTI)

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

27

Sulfur capture in combination bark boilers  

SciTech Connect (OSTI)

A review of sulfur dioxide emission data for eight combination bark boilers in conjunction with the sulfur contents of the fuels reveals significant sulfur capture ranging from 10% to over 80% within the solid ash phase. Wood ash characteristics similar to activated carbon as well as the significant wood ash alkali oxide and carbonate fractions are believed responsible for the sulfur capture. Sulfur emissions from combination bark-fossil fuel firing are correlated to the sulfur input per ton of bark or wood residue fired.

Someshwar, A.V.; Jain, A.K. (National Council of the Paper Industry for Air and Stream Improvement, Gainesville, FL (United States))

1993-07-01T23:59:59.000Z

28

Revisit Carbon/Sulfur Composite for Li-S Batteries  

SciTech Connect (OSTI)

To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

2013-07-23T23:59:59.000Z

29

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

30

Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of LithiumSulfur Battery  

Science Journals Connector (OSTI)

Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of LithiumSulfur Battery ... An amylopectin wrapped graphene oxide-sulfur composite was prepared to construct a 3-dimensionally cross-linked structure through the interaction between amylopectin and graphene oxide, for stabilizing lithium sulfur batteries. ...

Weidong Zhou; Hao Chen; Yingchao Yu; Deli Wang; Zhiming Cui; Francis J. DiSalvo; Hctor D. Abrua

2013-09-05T23:59:59.000Z

31

Sulfur: its clinical and toxicologic aspects  

Science Journals Connector (OSTI)

Although there is no known dietary requirement for inorganic sulfur, it is an essential element for all animal species in as much as they all require the sulfur-containing amino acid methionine. There are three predominate forms of organic sulfur in animals and humans: 1) the thiomethyl of methionine residues in protein; 2) the sulfhydryl disulfides of protein; and 3) the compounds containing ester or amide bound sulfates of glycosaminoglycans, steroids, and many xenobiotic metabolites. Thus, sulfur becomes an important constituent of amino acids, proteins, enzymes, vitamins and other biomolecules. Unlike mammalian species, plants can use inorganic sulfur and synthesize methionine from which are synthesized all the other important sulfur compounds. Hence, sulfur deficiency occurs mainly when plants are grown in sulfur-depleted soils and when humans and animals consume low-protein diets. In recent times, however, the increasing prevalence of refining petroleum and smelting sulfur compounds of metallic minerals into free metals are having a large impact on the balance of sulfur in the environment. Sulfur toxicity is associated mainly with high levels of the element and its toxic volatile substances in the environment. Sulfur dioxide (SO2), a major air pollutant, may adversely affect animal and human health by causing bronchitis, bronchoconstriction, and increased pulmonary resistance.

Lioudmila A Komarnisky; Robert J Christopherson; Tapan K Basu

2003-01-01T23:59:59.000Z

32

Two stage sorption of sulfur compounds  

DOE Patents [OSTI]

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

33

Why Sequence Sulfur-Oxidizing Bacteria?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur-Oxidizing Bacteria? Sulfur-Oxidizing Bacteria? Several environmental problems, such as acid rain, biocorrosion, etc., are caused by sulfur compounds, such as sulfur dioxide (SO2) and hydrogen sulfide (H2S). A sustainable process to remove these sulfur compounds is the production of elemental sulfur from H2S-containing gas streams by the use of sulfide-oxidizing bacteria. In this process, H2S is absorbed into the alkaline solution in the scrubber unit, followed by the biological oxidation of H2S to elemental sulfur and the recycling of water. With this two-step process, a variety of gas streams (i.e., natural gas, synthesis gas, biogas, and refinery gas) can be treated. For the treatment of sulfate-containing waste streams, an extra step has to be introduced: the transformation of sulfate into H2S by sulfate-reducing bacteria. In

34

SRS - History Highlights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 SEARCH GO Side Menu Spacer SRS Mission & Vision Where We Are SRS History Fact Sheets Tour SRS Contact SRS SRS Home SRS History Highlights The Savannah River Site was constructed during the early 1950s to produce the basic materials used in the fabrication of nuclear weapons, primarily tritium and plutonium-239, in support of our nation's defense programs. Five reactors were built to produce these materials. Also built were a number of support facilities including two chemical separations plants, a heavy water extraction plant, a nuclear fuel and target fabrication facility, a tritium extraction facility and waste management facilities. If you wish to view an in-depth history (1950-2000), please explore SRS at Fifty, our 50th anniversary book. Browse by Era: 1950s * 1960s * 1970s * 1980s * 1990s * 2000s * 2010s

35

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries 2011 DOE...

36

Improve reformer operation with trace sulfur removal  

SciTech Connect (OSTI)

Modern bimetallic reforming catalysts typically have feed specifications for sulfur of 0.5 to 1 wppm in the reformer naphtha carge. Sulfur in the raw naphtha is reduced to this level by naphtha hydrotreating. While most naphtha hydrotreating operations can usually obtain these levels without substantial problems. It is difficult to obtain levels much below 0.5 to 1 wppm with this process. Revamp of a constrained existing hydrotreater to reduce product sulfur slightly can be extremely costly typically entailing replacement or addition of a new reactor. At Engelhard the authors demonstrated that if the last traces of sulfur remaining from hydrotreating can be removed, the resulting ultra-low sulfur feed greatly improves the reformer operation and provides substantial economic benefit to the refiner. Removal of the remaining trace sulfur is accomplished in a simple manner with a special adsorbent bed, without adding complexity to the reforming operation.

McClung, R.G.; Novak, W.J.

1987-01-01T23:59:59.000Z

37

Preserving and Querying Histories of XML-Published Relational Databases  

E-Print Network [OSTI]

Preserving and Querying Histories of XML-Published Relational Databases Fusheng Wang and Carlo the evolution history of such a view as yet another XML document, whereby the complete history of the database, and identify and select those which are best for representing and querying database histories. We show

Zaniolo, Carlo

38

Contribution of isotopologue self-shielding to sulfur mass-independent fractionation during sulfur dioxide photolysis  

E-Print Network [OSTI]

Signatures of sulfur mass-independent fractionation (S-MIF) are observed for sulfur minerals in Archean rocks, and for modern stratospheric sulfate aerosols (SSA) deposited in polar ice. Ultraviolet light photolysis of ...

Lyons, J. R.

39

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

40

VILLAR-ARGAIZ, MANUEL, AND ROBERT W. STERNER Life history  

Science Journals Connector (OSTI)

PATTERSON, M. R. 1992. A chemical engineering view of cnidarian ... Life history bottlenecks in Diaptomus clavipes induced by phosphorus-limited algae.

2002-06-25T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Sulfur determination in blood from inhabitants of Brazil using neutron activation analysis  

SciTech Connect (OSTI)

In this study the NAA technique was applied to analyze sulfur in blood from inhabitants of Brazil for the proposition of an indicative interval. The measurements were performed considering lifestyle factors (non-smokers, non-drinkers and no history of toxicological exposure) of Brazilian inhabitants. The influence of gender was also investigated considering several age ranges (18-29, 30-39, 40-49, >50 years). These data are useful in clinical investigations, to identify or prevent diseases caused by inadequate sulfur ingestion and for nutritional evaluation of Brazilian population.

Oliveira, Laura C.; Zamboni, Cibele B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN-CNEN/SP) Av. Professor Lineu Prestes 2242 05508-000 Sao Paulo, SP (Brazil)

2013-05-06T23:59:59.000Z

42

Sulfur-Free Selective Pulping  

E-Print Network [OSTI]

Technoeconomic Appraisal," December 1991. 5. DOE Annual Report on Contract No. AC02-83CH10093, Bozell, J. J., Hames, B., Chum, H. L., Dimmel, D. R, Althen, E., Caldwell, P. L., Daube, Oxidation ;; Diels-Alder .. I I -Methanol .. ~ 5 I 3 (C~O) OCH... - Hydrogen 3 (Q-IP) # Q-I 3 o o ~ o 1 2 ~ (H) Lignin DMBQ =two OCH3 groups Anthraquinone MMBQ =one OCH3 group A. K, and Kuroda, K-I.,"Sulfur-free Selective Pulping," March 1992. 6. DOE Annual Report on Contrac No. DE-AC02-83CH10093, Bozell, J. J...

Dimmel, D. R.; Bozell, J. J.

43

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network [OSTI]

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

44

History Images  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History Images History Images Los Alamos History in Images Los Alamos has a proud history and heritage of almost 70 years of science and innovation. The people of the Laboratory work on advanced technologies to provide the best scientific and engineering solutions to many of the nation's most crucial security challenges. Click thumbnails to enlarge. Photos arranged by most recent first, horizontal formats before vertical. See Flickr for more sizes and details. Back in the day Back in the day LA bridge in Los Alamos LA bridge in Los Alamos 1945 Army-Navy "E" Award 1945 Army-Navy "E" Award Louis Rosen Louis Rosen Bob Van Ness Robert Kuckuck and Michael Anastasio Bob Van Ness Robert Kuckuck and Michael Anastasio TA-18 TA-18 Elmer Island TU-4 assembly area Elmer Island TU-4 assembly area

45

Graphene-wrapped sulfur nanospheres with ultra-high sulfur loading for high energy density lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithiumsulfur (LiS) battery with high theoretical energy density is one of the most promising energy storage systems for electric vehicles and intermittent renewable energy. However, due to the poor conductivity of the active material, considerable weight of the electrode is occupied by the conductive additives. Here we report a graphene-wrapped sulfur nanospheres composite (S-nanosphere@G) with sulfur content up to 91wt% as the high energy density cathode material for LiS battery. The sulfur nanospheres with diameter of 400500nm are synthesized through a solution-based approach with the existence of polyvinylpyrrolidone (PVP). Then the sulfur nanospheres are uniformly wrapped by conductive graphene sheets through the electrostatic interaction between graphene oxide and PVP, followed by reducing of graphene oxide with hydrazine. The design of graphene wrapped sulfur nanoarchitecture provides flexible conductive graphene coating with void space to accommodate the volume expansion of sulfur and to minimize polysulfide dissolution. As a result, the S-nanosphere@G nanocomposite with 91wt% sulfur shows a reversible initial capacity of 970mAhg?1 and an average columbic efficiency>96% over 100 cycles at a rate of 0.2C. Taking the total mass of electrode into account, the S-nanosphere@G composite is a promising cathode material for high energy density LiS batteries.

Ya Liu; Jinxin Guo; Jun Zhang; Qingmei Su; Gaohui Du

2015-01-01T23:59:59.000Z

46

Cosmic Growth History and Expansion History  

E-Print Network [OSTI]

of the expansion history dark energy equation of state,and growth history constraints on the dark energy equationand growth history constraints on the dark energy equation

Linder, Eric V.

2009-01-01T23:59:59.000Z

47

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

High-Sulfur...FLUIDIZED-BED COMBUSTORS, COMBUSTION...MAY FLUE GAS DES S E...1971 ). High-sulfur...was brief. Natural gas became...overdependent on natural gas and oil to...elevated pressure with a downward...coals of high ash-fusion...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

48

Method of removal of sulfur from coal and petroleum products  

DOE Patents [OSTI]

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

49

Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...  

Broader source: Energy.gov (indexed) [DOE]

of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of...

50

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

51

Manipulating the Surface Reactions in Lithium Sulfur Batteries...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode...

52

NETL: History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History History About NETL History Over the past century, fossil energy research and technology development has been advanced by NETL and its predecessor facilities as the energy needs of the Nation have grown and evolved. 1910 - The newly created Bureau of Mines in the U.S. Department of the Interior (DOI) opens the Pittsburgh Experiment Station in Bruceton, Pennsylvania, 12 miles south of Pittsburgh. The station includes an experimental coal mine and offers advanced training for coal operators and miners. Onsite research focuses on developing innovative coal-mining safety equipment and practices. 1918 - Following new discoveries of oil in Oklahoma and Texas, the Petroleum Experiment Station is established in Bartlesville, Oklahoma, as one of 17 DOI Bureau of Mines facilities under Public Law 283 (63rd Congress, 1915). The Station pursues systematic application of engineering and scientific methods to oil drilling, helping the early "boom and bust" oil industry create operating and safety standards.

53

NERSC History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History History NERSC History Powering Scientific Discovery Since 1974 Contact: Jon Bashor, jbashor@lbl.gov, +1 510 486 4236 For more information, read "25 Years of Leadership," a historical perspective written at NERSC's quarter-century mark.⨠Download (PDF, 1.7MB) The oil crisis of 1973 did more than create long lines at the gas pumps - it jumpstarted a supercomputing revolution. The quest for alternative energy sources led to increased funding for the Department of Energy's Magnetic Fusion Energy program, and simulating the behavior of plasma in a fusion reactor required a computer center dedicated to this purpose. Founded in 1974 at Lawrence Livermore National Laboratory, the Controlled Thermonuclear Research Computer Center was the first unclassified supercomputer center and was the model for those that

54

Sulfur nanocrystals anchored graphene composite with highly improved electrochemical performance for lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract Two kinds of graphenesulfur composites with 50wt% of sulfur are prepared using hydrothermal method and thermal mixing, respectively. Transmission Electron Microscopy (TEM) and Energy Dispersive X-ray Spectra mapping show that sulfur nanocrystals with size of ?5nm dispersed on graphene sheets homogeneously for the sample prepared by hydrothermal method (NanoS@G). While for the thermal mixed graphenesulfur composite (SG mixture), sulfur shows larger and uneven size (50200nm). X-ray Photoelectron Spectra (XPS) reveals the strong chemical bonding between the sulfur nanocrystals and graphene. Comparing with the SG mixture, the NanoS@G composite shows highly improved electrochemical performance as cathode for lithiumsulfur (LiS) battery. The NanoS@G composite delivers an initial capacity of 1400mAhg?1 with the sulfur utilization of 83.7% at a current density of 335mAg?1. The capacity keeps above 720mAhg?1 over 100 cycles. The strong adherence of the sulfur nanocrystals on graphene immobilizes sulfur and polysulfides species and suppressed the shuttle effect, resulting higher coulombic efficiency and better capacity retention. Electrochemical impedance also suggests that the strong bonding enabled rapid electronic/ionic transport and improved electrochemical kinetics, therefore good rate capability is obtained. These results demonstrate that the NanoS@G composite is a very promising candidate for high-performance LiS batteries.

Jun Zhang; Zimin Dong; Xiuli Wang; Xuyang Zhao; Jiangping Tu; Qingmei Su; Gaohui Du

2014-01-01T23:59:59.000Z

55

Catalyst for elemental sulfur recovery process  

DOE Patents [OSTI]

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

56

Sulfur-graphene oxide material for lithium-sulfur battery cathodes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur-graphene oxide material for lithium-sulfur battery cathodes Sulfur-graphene oxide material for lithium-sulfur battery cathodes Theoretical specific energy and theoretical energy density Scanning electron micrograph of the GO-S nanocomposite June 2013 Searching for a safer, less expensive alternative to today's lithium-ion batteries, scientists have turned to lithium-sulfur as a possible chemistry for next-generation batteries. Li/S batteries have several times the energy storage capacity of the best currently available rechargeable Li-ion battery, and sulfur is inexpensive and nontoxic. Current batteries using this chemistry, however, suffer from extremely short cycle life-they don't last through many charge-discharge cycles before they fail. A research team led by Elton Cairns and Yuegang Zhang has developed a new

57

ORISE: History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History History The Oak Ridge Institute for Science and Education (ORISE) is a national leader in science education and research, with programs dating back to 1946 and having served as an official U.S. Department of Energy (DOE) institute since 1992. The institute that eventually became what is known today as ORISE was the brainchild of University of Tennessee (UT) physics professor Dr. William G. Pollard. Aware of the valuable assets on hand in Oak Ridge, Tenn., as part of the Manhattan Project, Pollard talked about the possibility of aligning regional universities with the scientific resources and state-of-the-art equipment in Oak Ridge. On Oct. 17, 1946, Pollard's vision became a reality when the Oak Ridge Institute of Nuclear Studies (ORINS) received a charter of incorporation

58

Revision History  

Broader source: Energy.gov (indexed) [DOE]

Revision History Revision History Rev. 0, August 2012 Original submittal for milestone M3FT-12SN0804032 (Sandia programmatic and classification review) Rev. 1, September 2012 Corrected transposition errors in costing tables; recalculated stainless steel overpacks to be carbon steel; corrected various editorial problems. (SAND2012-7979P) Rev. 2, November 2012 Performed peer review and retitled. Submittal for milestone M2FT-13SN0804031 (formerly milestone M2FT- 12SN0804031) (SAND2012-9737P) Unclassified Unlimited Release Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

59

History - Cyclotron  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History History Lawrence's original Cyclotron, for which he received a patent and the Nobel Prize. Lawrence's original cyclotron design was limited to energies where relativistic effects were not important. The third generation cyclotron included "sector-focusing" to allow higher energies to be obtained. The 88-Inch Cyclotron was based on Lawrence's design of a sector-focused cyclotron for the MTA project at Livermore. 1500 man-hours of work were necessary to assemble the trim coils which help regulate the strength and shape of the accelerator's magnetic field. Discussing the cyclotron magnet (seen in the background) are Dr. Elmer Kelly, physicist in charge of the 88-Inch Cyclotron and Warren Dexter, electrical coordinator for the cyclotron project.

60

Phosphazene groups modified sulfur composites as active cathode materials for rechargeable lithium/sulfur batteries  

Science Journals Connector (OSTI)

A novel phosphazene groups modified sulfur composites cathode [triphosphazene sulfide composite (PS) or nitroanilinetriphosphazene disulfide composite (NPS)] which can give good affinity with electrolytes was...

J. D. Liu; S. Q. Zhang; S. B. Yang; Z. F. Shi; S. T. Zhang; L. K. Wu

2013-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Energy Levels in Sulfur Nuclei  

Science Journals Connector (OSTI)

A study has been made of the proton groups from the reaction of 3.22-Mev deuterons with sulfur in the form, primarily, of H2S gas. The following Q values have been assigned to the reaction S32(dp)S33:6.48,5.69,4.58,4.31,3.63,3.33,2.60,2.33,2.06,1.78,1.37,0.85,and0.18 Mev, corresponding to the ground state and twelve excited states of S33. Four of these groups have been investigated for proton gamma-ray coincidences to confirm this assignment. The yield as a function of deuteron energy has been observed for the six highest energy groups and indication of the presence of some broad resonances found. A qualitative measurement of the variation with angle of relative yields of the groups has indicated a proton intensity distribution that is symmetric for some groups and asymmetric for others. The cross section for the reaction for 90 observation has been found to be 1.2 barns. The mass difference S33-S32 has been calculated to be 0.99963 mass unit.Two low intensity, high energy groups have been assigned to the reaction S33(dp)S34 with Q values of 8.67 and 7.85 Mev. This, together with the above observation, leads to a value of 1.99691 for the mass difference S34-S32.

Perry W. Davison

1949-03-01T23:59:59.000Z

62

Steam reforming utilizing sulfur tolerant catalyst  

SciTech Connect (OSTI)

This patent describes a steam reforming process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of: adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalyst of platinum supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. It also describes a steam process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of steam to the hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalysts consisting essentially of iridium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. In addition a steam reforming process is described for converting hydrocarbon material to hydrogen gas in the presence of sulfur comprising adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity sulfur tolerant catalysts consisting essentially of palladium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina.

Setzer, H.J.; Karavolis, S.; Bett, J.A.S.

1987-09-15T23:59:59.000Z

63

Complexity in Big History  

E-Print Network [OSTI]

Spier, Fred. How Big History Works: Energy Flows and RiseSmil, Vaclav. Energy in World History. Boulder, CO: Westviewkg) Energy and complexity Spier: Complexity in Big History.

Spier, Fred

2011-01-01T23:59:59.000Z

64

Jefferson and Hamilton as viewed by historians  

E-Print Network [OSTI]

JEFFERSON AND HAMILTON AS VIEHED BY HISTORIANS A Thesis Paul Edward Jungmeyer Submitted to the Graduate College of Texas A&M University in ' partial fulfillment of the requirement for the degree of MASTER OF ARTS August, 1970 Major Subject...: History JEFFERSON AND HAMILTON AS VIEWED BY HISTORIANS A Thesis by Paul Edward Jungmeyer Approved as to style and content by: (Chairman of Committee d i~) (Member) (M er) August, 1970 ABSTRACT JEFFERSON AND HAMILTON AS VIEWED BY HISTORIANS...

Jungmeyer, Paul Edward

2012-06-07T23:59:59.000Z

65

Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions  

SciTech Connect (OSTI)

When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

1995-12-31T23:59:59.000Z

66

The reaction kinetics of gasoline sulfur compounds: Catalytic mechanisms for sulfur reduction  

SciTech Connect (OSTI)

One of the key elements of reformulated gasoline is the reduction of the sulfur compounds produced by fluid catalytic cracking. This paper probes the reaction kinetics of refractory gasoline-range thiophene derivatives (thiophene, tetrahydrothiophene, and alkylthiophenes) in an effort to determine the mechanisms of sulfur compound cracking in the FCC unit. The gasoline-range sulfur compounds were analyzed using gas chromatography with an atomic emission detector. The authors` results show that the FCC catalysts affects the cracking of sulfur compounds through both hydrogen transfer and zeolite pore restriction mechanisms. An experimental FCC catalyst is shown to reduce gasoline sulfur content in the Davidson Circulating Riser (DCR{sup TM}) pilot unit. Model compound tests show that the activity of the catalyst is due to both its catalytic and adsorptive properties. Tetrahydrothiophene, which is produced from thiophenes by hydrogen transfer, is completely removed by the experimental catalyst.

Harding, R.H.; Gatte, R.R.; Albro, T.G.; Wormsbecher, R.F. [W.R. Grace & Co. Conn, Columbia, MD (United States)

1993-12-31T23:59:59.000Z

67

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries...

68

An Aerosol Condensation Model for Sulfur Trioxide  

SciTech Connect (OSTI)

This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

Grant, K E

2008-02-07T23:59:59.000Z

69

History Overview of Solid-State Lighting - History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Condensed History of Lighting | Review Articles | FAQs | Condensed History of Lighting | Review Articles | FAQs | Documents Archive | CONDENSED HISTORY OF LIGHTING Figure courtesy of Jeff Tsao; a version of this figure was published in IEEE Circuits and Devices Vol 20, No 3, pp 28-37, May/June, 2004 Lighting technologies are substitutes for sunlight in the 425-675 nm spectral region where sunlight is most concentrated and to which the human eye has evolved to be most sensitive. The history of lighting can be viewed as the development of increasingly efficient technologies for creating visible light inside, but not wasted light outside, of that spectral region. A 200-year perspective on that history is shown in the figure above. The left axis indicates luminous efficacy, in units of lumens (a measure of light which factors in the human visual response to various wavelengths) per watt. The right axis indicates the corresponding power-conversion efficiency for a tri-LED tri-color white light source with moderate color rendering (CRI=80) and relatively warm color temperature (CCT=3900K). For such a source, 400lm/W would correspond to 100% power-conversion efficiency.

70

Safety considerations for the use of sulfur in sulfur-modified pavement materials  

E-Print Network [OSTI]

on the surround1ng environment. As sulfur-modified paving materials were being developed, there was a corresponding concern for studying the amounts of gaseous emiss1ons that were generated. The Texas Trans- portat1on Inst1tute (TTI) was one of the first... organizations in the United States to become 1nvolved in the research and development of sulfur-modified pavements, Throughout 1ts laboratory stud1es TTI cont1nually mon1tored hydrogen sulf1de (H25) and sulfur d1oxide (502) em1ssions produced during mix...

Jacobs, Carolyn Yuriko

2012-06-07T23:59:59.000Z

71

Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline  

Broader source: Energy.gov [DOE]

Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of sulfur in gasoline (Tier 2 standards)....

72

ORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation  

E-Print Network [OSTI]

). Methylotrophs and iron oxidizers were also active in plume waters and expressed key proteins for methane by bacteria (especially, alpha-, gamma- and epsilon-proteobacteria) that likely participate in the oxidationORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation at a biogeochemical hot spot in the dark

Hansell, Dennis

73

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

...amounts of coal, because...Director-Mineral Re-sources...of Gas from Coal through a...on coals of high ash-fusion temperature...per ton of high-sulfur coal burned. Absorp-tion...particulate matter as well as...capable of remov-ing up to...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

74

Short communication Influence of molybdenum and sulfur on copper  

E-Print Network [OSTI]

Short communication Influence of molybdenum and sulfur on copper metabolism in sheep: comparison of molybdenum able to trigger the copper sulfur molybdenum interference in sheep was measured with either only) and 4 increasing molybdenum doses. The sulfur-molybdenum-copper interference was quantified

Paris-Sud XI, Université de

75

A novel lithium/sulfur battery based on sulfur/graphene nanosheet composite cathode and gel polymer electrolyte  

Science Journals Connector (OSTI)

A novel sulfur/graphene nanosheet (S/GNS) composite was prepared ... ball milling of sulfur with commercial multi-layer graphene nanosheet, followed by a heat treatment. ... of irregularly interlaced nanosheet-li...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-03-01T23:59:59.000Z

76

A simple approach to synthesize nanosized sulfur/graphene oxide materials for high-performance lithium/sulfur batteries  

Science Journals Connector (OSTI)

We report on a simple and facile synthesis route for the sulfur/graphene oxide composite via ultrasonic mixing of the nano-sulfur and graphene oxide aqueous suspensions followed by a low-temperature heat treat...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-07-01T23:59:59.000Z

77

SearchHistoryShopper Last Updated 10/23/2013 lks  

E-Print Network [OSTI]

invoices. · View the status of documents. · Search by Requester name using advanced search. History Search.......................................................................................................................................11 Advanced search.........................................................................................................................................................................12 Advanced search

Shull, Kenneth R.

78

Archives and History Office: Oral History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oral History Oral History Oral History Oral History interviews with SLAC staff and users have been conducted at SLAC and at other institutions by SLAC Archives and History Office staff and by others interested in the history of physics and computing. Information collected in these interviews supplements original correspondence and other primary source materials collected by the Archives and History Office. SLAC Interviews Interviews have been conducted by SLAC staff on an irregular basis, as resources have permitted. The Archives and History Office staff are currently working on a project to identify all past interview subjects, locate interview tapes and permission forms, and create interview transcripts. Our holdings contain tapes or transcripts of interviews with the following staff members and users:

79

Graphene-Wrapped Sulfur Particles as a Rechargeable LithiumSulfur Battery Cathode Material with High Capacity and Cycling Stability  

Science Journals Connector (OSTI)

Graphene-Wrapped Sulfur Particles as a Rechargeable LithiumSulfur Battery Cathode Material with High Capacity and Cycling Stability ... The resulting graphenesulfur composite showed high and stable specific capacities up to ?600 mAh/g over more than 100 cycles, representing a promising cathode material for rechargeable lithium batteries with high energy density. ...

Hailiang Wang; Yuan Yang; Yongye Liang; Joshua Tucker Robinson; Yanguang Li; Ariel Jackson; Yi Cui; Hongjie Dai

2011-06-24T23:59:59.000Z

80

User_ViewRecords  

Broader source: Energy.gov (indexed) [DOE]

User Records User Records © 2011 SuccessFactors, Inc. - 1 - SuccessFactors Learning Confidential. All rights reserved. Job Aid: Viewing User Records Purpose The purpose of this job aid is to guide users through the step-by-step process of viewing their records. Each task demonstrates viewing of different records. Task A. View To-Do List Enter the web address (URL) of the user application into your browser Address field and press the Enter key. Enter your user ID in the User ID textbox. Enter your password in the Password textbox. Click Sign In. View To-Do List (filter, view) 7 Steps Task A View Completed Work 8 Steps Task B View Curriculum Status and Details 11 Steps Task C 3 3 1 2 2 1 SuccessFactors Learning v 6.4 User Job Aid Viewing User Records

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Internalizing Native American History: Comprehending Cherokee and Muscogulge Identities  

E-Print Network [OSTI]

indigenous societies to be used as models to interpret history from the native point of view. The example used here involves the reconstruction of Cherokee and Muscogulge societies by examining the center of their socio-political systems, the clan...

Haggard, Dixie Ray

2000-09-01T23:59:59.000Z

82

CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

Hobbs, D; Hector Colon-Mercado, H

2007-01-31T23:59:59.000Z

83

Method to prevent sulfur accumulation in membrane electrode assembly  

DOE Patents [OSTI]

A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

Steimke, John L; Steeper, Timothy J; Herman, David T

2014-04-29T23:59:59.000Z

84

ESnet IPv6 History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History Engineering Services The Network OSCARS Fasterdata IPv6 Network IPv6 Implementation Checklist ESnet IPv6 Mirror Servers ESnet IPv6 History ESnet supports Sandia and APNIC...

85

Idaho National Laboratory History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Area Attractions and Events Area Geography Area History Area Links Driving Directions Idaho Falls Attractions and Events INL History INL Today Research Park Sagebrush Steppe...

86

Southeast Idaho History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Area Attractions and Events Area Geography Area History Area Links Driving Directions Idaho Falls Attractions and Events INL History INL Today Research Park Sagebrush Steppe...

87

Lake View Geothermal Facility | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Lake View Geothermal Facility Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Lake View Geothermal Facility General Information Name Lake View Geothermal Facility Facility Lake View Sector Geothermal energy Location Information Location The Geysers, California Coordinates 38.823527148671°, -122.78173327446° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.823527148671,"lon":-122.78173327446,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

88

sulfur dioxide emissions | OpenEI  

Open Energy Info (EERE)

sulfur dioxide emissions sulfur dioxide emissions Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago) Keywords buildings carbon dioxide emissions carbon footprinting CO2 commercial buildings electricity emission factors ERCOT hourly emission factors interconnect nitrogen oxides

89

Sulfur-isotope separation by distillation  

SciTech Connect (OSTI)

Sulfur-isotope separation by low-temperature distillation of hydrogen sulfide was studied in an 8-m, 25-mm diameter distillation column. Column temperature was controlled by a propane-propylene heat pipe. Column packing HETP was measured using nitric oxide in the column. The column was operated at pressures from 45 to 125 kPa. The relative volatility of S-32 vs. S-34 varied from 1.0008 to 1.0014.

Mills, T.R.

1982-01-01T23:59:59.000Z

90

Sulfur/three-dimensional graphene composite for high performance lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract A sulfur/graphene composite is prepared by loading elemental sulfur into three-dimensional graphene (3D graphene), which is assembled using a metal ions assisted hydrothermal method. When used as cathode materials for lithiumsulfur (LiS) batteries, the sulfur/graphene composite (S@3D-graphene) with 73wt % sulfur shows a significantly enhanced cycling performance (>700mAhg?1 after 100 cycles at 0.1C rate with a Coulombic efficiency>96%) as well as high rate capability with a capacity up to 500mAhg?1 at 2C rate (3.35Ag?1). The superior electrochemical performance could be attributed to the highly porous structure of three-dimensional graphene that not only enables stable and continue pathway for rapid electron and ion transportation, but also restrain soluble polysulfides and suppress the shuttle effect. Moreover, the robust structure of 3D graphene can keep cathode integrity and accommodate the volume change during high-rate charge/discharge processes, making it a promising candidate as cathode for high performance LiS batteries.

Chunmei Xu; Yishan Wu; Xuyang Zhao; Xiuli Wang; Gaohui Du; Jun Zhang; Jiangping Tu

2015-01-01T23:59:59.000Z

91

Development of the Hybrid Sulfur Thermochemical Cycle  

SciTech Connect (OSTI)

The production of hydrogen via the thermochemical splitting of water is being considered as a primary means for utilizing the heat from advanced nuclear reactors to provide fuel for a hydrogen economy. The Hybrid Sulfur (HyS) Process is one of the baseline candidates identified by the U.S. Department of Energy [1] for this purpose. The HyS Process is a two-step hybrid thermochemical cycle that only involves sulfur, oxygen and hydrogen compounds. Recent work has resulted in an improved process design with a calculated overall thermal efficiency (nuclear heat to hydrogen, higher heating value basis) approaching 50%. Economic analyses indicate that a nuclear hydrogen plant employing the HyS Process in conjunction with an advanced gas-cooled nuclear reactor system can produce hydrogen at competitive prices. Experimental work has begun on the sulfur dioxide depolarized electrolyzer, the major developmental component in the cycle. Proof-of-concept tests have established proton-exchange-membrane cells (a state-of-the-art technology) as a viable approach for conducting this reaction. This is expected to lead to more efficient and economical cell designs than were previously available. Considerable development and scale-up issues remain to be resolved, but the development of a viable commercial-scale HyS Process should be feasible in time to meet the commercialization schedule for Generation IV gas-cooled nuclear reactors.

Summers, William A.; Steimke, John L

2005-09-23T23:59:59.000Z

92

Process for production of synthesis gas with reduced sulfur content  

DOE Patents [OSTI]

A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

1989-01-01T23:59:59.000Z

93

Long-term history of chemosynthetic molluscan assemblages at Gulf of Mexico hydrocarbons seep sites  

E-Print Network [OSTI]

, Vesicomya cordata, and Calyptogena ponderosa, harbor sulfur-oxidizing symbionts. Seep assemblages from three sites, GB-386, GB-425, and GC-234, were sampled by piston core, in order to determine the long-term history of these assemblages from their preserved...

Warren, Kenneth Anderson

2012-06-07T23:59:59.000Z

94

OIL & GAS HISTORY 1 History in California  

E-Print Network [OSTI]

OIL & GAS HISTORY 1 History in California 4 Superior figures refer to references at the end of the essay. OIL AND GAS PRODUCTION California oil was always a valued commodity. When the Spanish explorers landed in California in the 1500s, they found Indians gathering asphaltum (very thick oil) from natural

95

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents [OSTI]

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

96

Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Advanced Materials Find More Like This Return to Search LithiumSulfur Batteries Based on Doped Mesoporous Carbon Oak Ridge National Laboratory Contact ORNL About...

97

Development of sulfur cathode material for Li-S batteries.  

E-Print Network [OSTI]

??M.S. Efforts were taken to fabricate a cathode material having Sulfur as the active material. First step is composed of identifying potential ways of fabricating (more)

Dharmasena, Ruchira Ravinath, 1984-

2014-01-01T23:59:59.000Z

98

Project Profile: Baseload CSP Generation Integrated with Sulfur...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Related Links FAQs Contact Us Offices You are here Home Concentrating Solar Power Project Profile: Baseload CSP Generation Integrated with Sulfur-Based...

99

SULFUR-TOLERANT CATALYST FOR THE SOLID OXIDE FUEL CELL.  

E-Print Network [OSTI]

??JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which (more)

Bozeman, Joe Frank, III

2010-01-01T23:59:59.000Z

100

Fundamental Studies of Lithium-Sulfur Cell Chemistry  

Broader source: Energy.gov (indexed) [DOE]

Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Abatement of Air Pollution: Control of Sulfur Compound Emissions  

Broader source: Energy.gov (indexed) [DOE]

Abatement of Air Pollution: Control of Sulfur Compound Emissions Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These regulations set limits on the sulfur content of allowable fuels (1.0%

102

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

Narain, N.K.; Ruether, J.A.; Smith, D.N.

1987-10-07T23:59:59.000Z

103

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

1988-01-01T23:59:59.000Z

104

Sulfur isotopes in coal constrain the evolution of the Phanerozoic sulfur cycle  

Science Journals Connector (OSTI)

...obviously influence the average isotope values. For the other data, samples...pp 87105 . 19 Price FT Casagrande DJ ( 1991 ) Sulfur...coals. Geology of Fossil Fuels, Proc 30th Int Geol Congress...Jersey Pinelands and its effect on stream water chemistry...223 248 . 29 Price FT Shieh YN ( 1979 ) Fractionation...

Donald E. Canfield

2013-01-01T23:59:59.000Z

105

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

106

SYNTHESIS OF SULFUR-BASED WATER TREATMENT AGENT FROM SULFUR DIOXIDE WASTE STREAMS  

SciTech Connect (OSTI)

We propose a process that uses sulfur dioxide from coal combustion as a raw material to synthesize polymeric ferric sulfate (PFS), a water treatment agent. The process uses sodium chlorate as an oxidant and ferrous sulfate as an absorbent. The major chemical mechanisms in this reaction system include oxidation, hydrolysis, and polymerization. Oxidation determines sulfur conversion efficiency while hydrolysis and polymerization control the quality of product. Many factors, including SO{sub 2} inlet concentration, flow rate of simulated flue gas, reaction temperature, addition rate of oxidant and stirring rate, may affect the efficiencies of SO{sub 2} removal. Currently, the effects of SO{sub 2} inlet concentration, the flow rate of simulated flue gas and addition rate of flue gas on removal efficiencies of SO{sub 2}, are being investigated. Experiments shown in this report have demonstrated that the conversion efficiencies of sulfur dioxide with ferrous sulfate as an absorbent are in the range of 60-80% under the adopted process conditions. However, the conversion efficiency of sulfur dioxide may be improved by optimizing reaction conditions to be investigated. Partial quality indices of the synthesized products, including Fe{sup 2+} concentration and total iron concentration, have been evaluated.

Robert C. Brown; Maohong Fan

2001-12-01T23:59:59.000Z

107

Views on Automation  

Science Journals Connector (OSTI)

Views on Automation ... Industrial managements, he feels, must allay workers' fears by showing how they can take pride in the greater accomplishment of automated plants. ...

1957-07-29T23:59:59.000Z

108

Uganda: A Modern History  

E-Print Network [OSTI]

pages, hardcover,. $27.50. uganda; A Modern History. Jan J .contemporary history Qf Uganda. His work supplies us with aand integration of Uganda's economy into the World capita 1

Ssali, Ndugu Mike

1983-01-01T23:59:59.000Z

109

Lithiumsulfur batteries: Influence of C-rate, amount of electrolyte and sulfur loading on cycle performance  

Science Journals Connector (OSTI)

Abstract In the past four years major improvement of the lithium sulfur battery technology has been reported. Novel carbon cathode materials offer high sulfur loading, sulfur utilization and cycle stability. An often neglected aspect is that sulfur loading and amount of electrolyte strongly impact the performance. In this paper, we demonstrate how the amount of electrolyte, sulfur loading, lithium excess and cycling rate influences the cycle stability and sulfur utilization. We chose vertically aligned carbon nanotubes (VA-CNT) as model system with a constant areal loading of carbon. For a high reproducibility, decreased weight of current collector and good mechanical adhesion of the VA-CNTs we present a layer transfer technique that enables a light-weight sulfur cathode. The sulfur loading of the cathode was adjusted from 20 to 80wt.-%. Keeping the total amount of electrolyte constant and varying the C-rate, we are able to demonstrate that the capacity degradation is reduced for high rates, high amount of electrolyte and low sulfur loading. In addition idle periods in the cycling regiment and lower rates result in an increased degradation. We attribute this to the redox-reaction between reactive lithium and polysulfides that correlates with the cycling time, rather than cycle number.

Jan Brckner; Sren Thieme; Hannah Tamara Grossmann; Susanne Drfler; Holger Althues; Stefan Kaskel

2014-01-01T23:59:59.000Z

110

BLACK HISTORY MONTH  

Broader source: Energy.gov [DOE]

Black History Month is an annual celebration of achievements by black Americans and a time for recognizing the central role of African Americans in U.S. history. The event grew out of Negro History Week, created by historian Carter G. Woodson and other prominent African Americans. Other countries around the world, including Canada and the United Kingdom, also devote a month to celebrating black history.

111

A handbook of history  

Science Journals Connector (OSTI)

...February-March 1997 review-article Reviews A handbook of history P D Hingley Librarian of the RAS Burlington House...it all. REVIEWS February/March 1997 Vol 38 Issue1 32 A handbook of history Cambridge Illustrated History of Astronomy by......

P D Hingley

1997-01-01T23:59:59.000Z

112

NEWS & VIEWS Glass dynamics  

E-Print Network [OSTI]

NEWS & VIEWS Glass dynamics Diverging views on glass transition Gregory B. mc.mckenna@ttu.edu T he glass transition is one of the most intriguing phenomena in the world of soft condensed matter. Despite decades of study, many aspects of the behaviour of glass-forming liquids remain elusive

Weeks, Eric R.

113

News and Views  

Science Journals Connector (OSTI)

......Model 8600 and 8700 gas chromatographs to...untended operation of the gas chromatograph under...0325) 311044. 133 News and Views Macintosh-compatible...speed of the Apple drives and a software incompatibility...for a corporate 134 News and Views licence...that Chem-X was the natural choice: 'Chem-X......

Alan H. Fielding

1990-04-01T23:59:59.000Z

114

Using ISC & GIS to predict sulfur deposition from coal-fired power plants  

E-Print Network [OSTI]

The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

Lopez, Jose Ignacio

2012-06-07T23:59:59.000Z

115

Molecular view of an electron transfer process essential for ironsulfur protein biogenesis  

Science Journals Connector (OSTI)

...2010 ) Nature of the energy landscape for gated electron...2009 ) TALOS+: A hybrid method for predicting...Strategy Forum on Research Infrastructures (ESFRI)] and by national...2009) TALOS+: A hybrid method for predicting...Rosato A (2011) A Grid-enabled web portal...

Lucia Banci; Ivano Bertini; Vito Calderone; Simone Ciofi-Baffoni; Andrea Giachetti; Deepa Jaiswal; Maciej Mikolajczyk; Mario Piccioli; Julia Winkelmann

2013-01-01T23:59:59.000Z

116

Integrated boiler, superheater, and decomposer for sulfuric acid decomposition  

DOE Patents [OSTI]

A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

2010-01-12T23:59:59.000Z

117

HEALTH AND CLIMATE POLICY IMPACTS ON SULFUR EMISSION CONTROL  

E-Print Network [OSTI]

the climate and health effects of sulfate aerosol into an integrated-assessment model of fossil fuel emission warming and health simultaneously will support more stringent fossil fuel and sulfur controls control. Our simulations show that a policy that adjusts fossil fuel and sulfur emissions to address both

Russell, Lynn

118

Metal-sulfur type cell having improved positive electrode  

DOE Patents [OSTI]

An novel metal-sulfur type cell operable at a temperature of 200.degree. C. or less with an energy density of 150 Whrs/Kg or better is disclosed characterized by an organo-sulfur cathode formed from an organic-sulfur compound having the general formula, in its charged state, of (R(S).sub.y).sub.n wherein y=1 to 6; n=2 to 20; and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, or nitrogen heteroatoms when R comprisises one of more aromatic rings, or one or more oxygen, sulfur, nitrogen, or fluorine atoms associtated with the chain when R comprises an aliphatic chain, wherein the aliphatic group may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

Dejonghe, Lutgard C. (Berkeley, CA); Visco, Steven J. (Berkeley, CA); Mailhe, Catherine C. (Berkeley, CA); Armand, Michel B. (St. Martin D'Uriage, FR)

1989-01-01T23:59:59.000Z

119

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

May 2011 CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries "This presentation does not contain any proprietary, confidential, or otherwise...

120

E-Print Network 3.0 - amoco sulfur recovery process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 80 Sulfur and oxygen isotope composition of the atmosphere in Saxony (Germany) Tichomirowa et al. Summary: ? a) Mixing processes 12;Sulfur and oxygen isotope...

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

122

Taking the long view  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Taking the long view Taking the long view Taking the long view on environmental stewardship A newly articulated mission for environmental stewardship at the Laboratory can be summed up in a simple phrase: clean up the past, control current operations, and create a sustainable future. March 20, 2012 Los Alamos Aerial Aerial view of a canyon in Los Alamos, New Mexico. Contact Environmental Communication & Public Outreach P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email "The future viability of the Lab hinges on demonstrating to public that we protect human health and the environment." Environmental stewardship strategy looks 50 years into the future As a way of integrating environmental protection activities into a comprehensive strategy, Kevin Smith, manager of the U.S. Department of

123

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect (OSTI)

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

124

History | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

About Energy.gov » History About Energy.gov » History History History The Department of Energy has one of the richest and most diverse histories in the Federal Government. Although only in existence since 1977, the Department traces its lineage to the Manhattan Project effort to develop the atomic bomb during World War II and to the various energy-related programs that previously had been dispersed throughout various Federal agencies. The Department has made available to researchers and the general public a rich variety of materials and information: Historical Resources, including published and online histories of the Department and its predecessor agencies and information on records, exhibits, museums, and tours available online and at various locations both within and outside the Department. Major publications and websites can be

125

NETL: Albany, Oregon History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Home > About NETL > History > Albany Research Center History Home > About NETL > History > Albany Research Center History About NETL Albany, Oregon History Albany Research Center has a history rich in successful materials research and development. It was on March 17, 1943 that President Franklin D. Roosevelt announced that the U. S. Bureau of Mines had selected a site in Albany, Oregon for the new Northwest Electro-development Laboratory. The original mission of the center was to find methods for using the abundant low-grade resources of the area, and to develop new metallurgical processes using the abundant electrical energy in the area. The name of the center was changed in 1945 to the Albany Metallurgy Research Center and was used through 1977 where the name was shortened to Albany Research Center. One of our first successes was the development

126

History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

About Energy.gov » History About Energy.gov » History History History The Department of Energy has one of the richest and most diverse histories in the Federal Government. Although only in existence since 1977, the Department traces its lineage to the Manhattan Project effort to develop the atomic bomb during World War II and to the various energy-related programs that previously had been dispersed throughout various Federal agencies. The Department has made available to researchers and the general public a rich variety of materials and information: Historical Resources, including published and online histories of the Department and its predecessor agencies and information on records, exhibits, museums, and tours available online and at various locations both within and outside the Department. Major publications and websites can be

127

Kristie Stremel Oral History  

E-Print Network [OSTI]

Under the Rainbow: Oral Histories of GLBTQ People in Kansas Kristie Stremel Oral History Part 1 video platform video management video solutionsvideo player Part 2 video platform video management video solutionsvideo player... Part 3 video platform video management video solutionsvideo player Part 4 video platform video management video solutionsvideo player Return to Kristie Stremel Oral History in KU ScholarWorks Tami Albin, Director for Under the Rainbow...

Stremel, Kristie; Albin, Tami

2009-10-27T23:59:59.000Z

128

Coastal engineering, history of  

Science Journals Connector (OSTI)

Turner I.L., Leatherman S.P., 1997. Beach dewatering as a soft' engineering solution to coastal erosion A history and critical review. J Coastal Res 13...

Per Bruun

1982-01-01T23:59:59.000Z

129

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents [OSTI]

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

130

Synergistic capture mechanisms for alkali and sulfur species from combustion. Final report  

SciTech Connect (OSTI)

Experimental work was carried out on a 17 kW, 600 cm long, gas laboratory combustor, to investigate the post flame reactive capture of alkali species by kaolinite. Emphasis was on alkali/sorbent interactions occurring in flue gas at temperatures above the alkali dewpoint and on the formation of water insoluble reaction products. Time-temperature studies were carried out by injecting kaolinite at different axial points along the combustor. The effect of chlorine and sulfur on alkali capture was investigated by doping the flame with SO{sub 2} and Cl{sub 2} gases to simulate coal flame environments. Particle time and temperature history was kept as close as possible to that which would ordinarily be found in a practical boiler. Experiments designed to extract apparent initial reaction rates were carried using a narrow range, 1-2 {mu}m modal size sorbent, while, a coarse, multi size sorbent was used to investigate the governing transport mechanisms. The capture reaction has been proposed to be between alkali hydroxide and activated kaolinite, and remains so in the presence of sulfur and chlorine. The presence of sulfur reduces sodium capture by under 10% at 1300{degree}C. Larger reductions at lower temperatures are attributed to the elevated dewpoint of sodium ({approximately}850{degree}C) with subsequent reduction in sorbent residence time in the alkali gas phase domain. Chlorine reduces sodium capture by 30% across the temperature range covered by the present experiments. This result has been linked to thermodynamic equilibria between sodium hydroxide, sodium chloride and water.

Peterson, T.W.; Shadman, F.; Wendt, J.O.L.; Mwabe, P.O.

1994-02-01T23:59:59.000Z

131

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

132

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents [OSTI]

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

133

History of Astronomy  

Science Journals Connector (OSTI)

... pages Prof. G. Abetti gives the reader a straightforward summary of the history of astronomy. As he remarks in the preface, a book of this size "can be ... the history and civilization of the peoples of the Earth". First we have ancient astronomy, which can be traced back to about forty centuries before Christ and which can ...

W. M. H. GREAVES

1955-08-20T23:59:59.000Z

134

David Ollington Oral History  

E-Print Network [OSTI]

Under the Rainbow: Oral Histories of GLBTQ People in Kansas David Ollington Oral History Part 1 video platform video management video solutionsvideo player Part 2 video platform video management video solutionsvideo player... Part 3 video platform video management video solutionsvideo player Part 4 video platform video management video solutionsvideo player Part 5 video platform video management video solutionsvideo player Return to David Ollington...

Ollington, David; Albin, Tami

2010-01-11T23:59:59.000Z

135

George Paris Oral History  

E-Print Network [OSTI]

Part 3 video platform video management video solutionsvideo player Part 4 video platform video management video solutionsvideo player Part 5 video platform video management video solutionsvideo player Part 6 video platform video... Under the Rainbow: Oral Histories of GLBTQ People in Kansas George Paris Oral History Part 1 video platform video management video solutionsvideo player Part 2 video platform video management video solutionsvideo player...

Paris, George; Albin, Tami

2010-01-11T23:59:59.000Z

136

Steven Brown Oral History  

E-Print Network [OSTI]

Part 4 video platform video management video solutionsvideo player Part 5 video platform video management video solutionsvideo player Part 6 video platform video management video solutionsvideo player Part 7 video platform video... Under the Rainbow: Oral Histories of GLBTQ People in Kansas Steven Brown Oral History Part 2 video platform video management video solutionsvideo player Part 3 video platform video management video solutionsvideo player...

Brown, Steven; Albin, Tami

2010-11-24T23:59:59.000Z

137

Microscale acceleration history discriminators  

DOE Patents [OSTI]

A new class of micromechanical acceleration history discriminators is claimed. These discriminators allow the precise differentiation of a wide range of acceleration-time histories, thereby allowing adaptive events to be triggered in response to the severity (or lack thereof) of an external environment. Such devices have applications in airbag activation, and other safety and surety applications.

Polosky, Marc A. (Albuquerque, NM); Plummer, David W. (Albuquerque, NM)

2002-01-01T23:59:59.000Z

138

A handbook of history  

Science Journals Connector (OSTI)

......review-article Reviews A handbook of history P D Hingley...professional astronomy. This does not mean that it skimps...1997 Vol 38 Issue1 32 A handbook of history Cambridge Illustrated...this magnificent new work does not totally replace the......

P D Hingley

1997-01-01T23:59:59.000Z

139

Mosquito Life Histories  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Life Histories Life Histories Nature Bulletin No. 682 June 2, 1962 Forest Preserve District of Cook County John J. Duffy, President David H. Thompson, Senior Naturalist MOSQUITO LIFE HISTORIES Everybody knows that a mosquito is a small, long-legged insect that bites. However, there are many kinds of them each with its own peculiarities of life history and habits. Some are produced in marshes or in flood plains of streams, some in puddles, some in woodlands, and others in cities and towns. Here in the Chicago region, although mosquito-borne diseases are no longer a danger, they become nuisances in many places at certain times in almost every year. In times past and in many countries the mosquitoes which carried malaria, yellow fever and other infections shaped the course of history. Hundreds of scientists have studied them for years but much remains to be learned.

140

Prarie View RDF  

Broader source: Energy.gov (indexed) [DOE]

PRAIRIE VIEW RDF PRAIRIE VIEW RDF 2 Prairie View RDF  Located at JAAP (approx. 40 miles southwest of Chicago), 223 acres on 455 Acre Parcel  Will County Owner; Waste Management, Operator  Maximum 23-Year Life WM/Will County Methane to Energy Plant  Landfill Contract Signed w/WM in 1997 w/Gas-to- Energy Plant Clause  County Retains Gas Rights &WM Installs Gas Collection System  WM owns Methane to Energy Plant &Tax Credits 3 CONTRACT PHASE  DOE Grant Applied 6/09  County Board Approves DOE EECBG Strategy 11/09  1 Million DOE Funds to Methane to Energy Plant  Schiff Harden Hired to Negotiate Gas to Energy Contract  February 2010 County Board Authorizes Contract Execution 4 5 METHANE TO ENERGY PLANT DETAILS  Waste Management Required To

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

2013-08-13T23:59:59.000Z

142

Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open Energy  

Open Energy Info (EERE)

Martinez Sulfuric Acid Regeneration Plt Biomass Facility Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid Regeneration Plt Sector Biomass Facility Type Non-Fossil Waste Location Contra Costa County, California Coordinates 37.8534093°, -121.9017954° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":37.8534093,"lon":-121.9017954,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

143

Diesel Emissions Control-Sulfur Effects (DECSE) Program Status  

SciTech Connect (OSTI)

Determine the impact of fuel sulfur levels on emission control systems that could be implemented to lower emissions of NO{sub x} and PM from on-highway trucks in the 2002-2004 time frame.

None

1999-06-29T23:59:59.000Z

144

Hybrid Microfabricated Device for Field Measurement of Atmospheric Sulfur Dioxide  

Science Journals Connector (OSTI)

It is also now generally agreed that forthcoming major volcanic eruptions will sensitively monitored for increasing sulfur gas emissions as indicated by increasing seismic activity. ... (12)?Fish, B. R.; Durham, J. L. Environ. ...

Shin-Ichi Ohira; Kei Toda; Shin-Ichiro Ikebe; Purnendu K. Dasgupta

2002-10-10T23:59:59.000Z

145

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

146

Novel Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

One of the unique advantages of SOFCs over other types of fuel cells is the potential for direct utilization of hydrocarbon fuels (it may involve internal reforming). Unfortunately, most hydrocarbon fuels contain sulfur, which would dramatically degrade SOFC performance at parts-per-million (ppm) levels. Low concentration of sulfur (ppm or below) is difficult to remove efficiently and cost-effectively. Therefore, knowing the exact poisoning process for state-of-the-art anode-supported SOFCs with Ni-YSZ cermet anodes, understanding the detailed anode poisoning mechanism, and developing new sulfur-tolerant anodes are essential to the promotion of SOFCs that run on hydrocarbon fuels. The effect of cell operating conditions (including temperature, H{sub 2}S concentration, cell voltage/current density, etc.) on sulfur poisoning and recovery of nickel-based anode in SOFCs was investigated. It was found that sulfur poisoning is more severe at lower temperature, higher H{sub 2}S concentration or lower cell current density (higher cell voltage). In-situ Raman spectroscopy identified the nickel sulfide formation process on the surface of a Ni-YSZ electrode and the corresponding morphology change as the sample was cooled in H{sub 2}S-containing fuel. Quantum chemical calculations predicted a new S-Ni phase diagram with a region of sulfur adsorption on Ni surfaces, corresponding to sulfur poisoning of Ni-YSZ anodes under typical SOFC operating conditions. Further, quantum chemical calculations were used to predict the adsorption energy and bond length for sulfur and hydrogen atoms on various metal surfaces. Surface modification of Ni-YSZ anode by thin Nb{sub 2}O{sub 5} coating was utilized to enhance the sulfur tolerance. A multi-cell testing system was designed and constructed which is capable of simultaneously performing electrochemical tests of 12 button cells in fuels with four different concentrations of H{sub 2}S. Through systematical study of state-of-the-art anode-supported SOFC button cells, it is seen that the long-term sulfur poisoning behavior of those cells indicate that there might be a second-stage slower degradation due to sulfur poisoning, which would last for a thousand hour or even longer. However, when using G-18 sealant from PNNL, the 2nd stage poisoning was effectively prohibited.

Lei Yang; Meilin Liu

2008-12-31T23:59:59.000Z

147

View dependent fluid dynamics  

E-Print Network [OSTI]

VIEW DEPENDENT FLUID DYNAMICS A Thesis by BRIAN ARTHUR BARRAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2006 Major Subject: Visualization... Sciences VIEW DEPENDENT FLUID DYNAMICS A Thesis by BRIAN ARTHUR BARRAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved by: Chair of Committee, Donald...

Barran, Brian Arthur

2006-08-16T23:59:59.000Z

148

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Final report  

SciTech Connect (OSTI)

This project has investigated new metal oxide catalysts for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as CO. Significant progress in catalyst development has been made during the course of the project. We have found that fluorite oxides, CeO{sub 2} and ZrO{sub 2}, and rare earth zirconates such as Gd{sub 2}Zr{sub 2}O{sub 7} are active and stable catalysts for reduction Of SO{sub 2} by CO. More than 95% sulfur yield was achieved at reaction temperatures about 450{degrees}C or higher with the feed gas of stoichiometric composition. Reaction of SO{sub 2} and CO over these catalysts demonstrated a strong correlation of catalytic activity with the catalyst oxygen mobility. Furthermore, the catalytic activity and resistance to H{sub 2}O and CO{sub 2} poisoning of these catalysts were significantly enhanced by adding small amounts of transition metals, such as Co, Ni, Co, etc. The resulting transition metal-fluorite oxide composite catalyst has superior activity and stability, and shows promise in long use for the development of a greatly simplified single-step sulfur recovery process to treat variable and dilute SO{sub 2} concentration gas streams. Among various active composite catalyst systems the Cu-CeO{sub 2} system has been extensively studied. XRD, XPS, and STEM analyses of the used Cu-CeO{sub 2} catalyst found that the fluorite crystal structure of ceria was stable at the present reaction conditions, small amounts of copper was dispersed and stabilized on the ceria matrix, and excess copper oxide particles formed copper sulfide crystals of little contribution to catalytic activity. A working catalyst consisted of partially sulfated cerium oxide surface and partially sulfided copper clusters. The overall reaction kinetics were approximately represented by a first order equation.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1995-06-01T23:59:59.000Z

149

METHOD TO PREVENT SULFUR ACCUMULATION INSIDE MEMBRANE ELECTRODE ASSEMBLY  

SciTech Connect (OSTI)

HyS is conceptually the simplest of the thermochemical cycles and involves only sulfur chemistry. In the HyS Cycle hydrogen gas (H{sub 2}) is produced at the cathode of the electrochemical cell (or electrolyzer). Sulfur dioxide (SO{sub 2}) is oxidized at the anode to form sulfuric acid (H{sub 2}SO{sub 4}) and protons (H{sup +}) as illustrated below. A separate high temperature reaction decomposes the sulfuric acid to water and sulfur dioxide which are recycled to the electrolyzers, and oxygen which is separated out as a secondary product. The electrolyzer includes a membrane that will allow hydrogen ions to pass through but block the flow of hydrogen gas. The membrane is also intended to prevent other chemical species from migrating between electrodes and undergoing undesired reactions that could poison the cathode or reduce overall process efficiency. In conventional water electrolysis, water is oxidized at the anode to produce protons and oxygen. The standard cell potential for conventional water electrolysis is 1.23 volts at 25 C. However, commercial electrolyzers typically require higher voltages ranging from 1.8 V to 2.6 V [Kirk-Othmer, 1991]. The oxidation of sulfur dioxide instead of water in the HyS electrolyzer occurs at a much lower potential. For example, the standard cell potential for sulfur dioxide oxidation at 25 C in 50 wt % sulfuric acid is 0.29 V [Westinghouse, 1980]. Since power consumption by the electrolyzers is equal to voltage times current, and current is proportional to hydrogen production, a large reduction in voltage results in a large reduction in electrical power cost per unit of hydrogen generated.

Steimke, J.; Steeper, T.; Herman, D.; Colon-Mercado, H.; Elvington, M.

2009-06-22T23:59:59.000Z

150

Low temperature fracture evaluation of plasticized sulfur paving mixtures  

E-Print Network [OSTI]

May 1985 Major Subject: Civil Engineering LOW TEMPERATURE FRACTURE EVALUATION OF PLASTICIZED SULFUR PAVING MIXTURES A Thesis by KAMYAR MAHBOUB Approved as to style and content by: Dallas N. Li tie (Chai rman of Committee) Ro e . Lytto Member... modifications to the standard ASTM procedure. These modifications were required due to the nature of plasticized sulfur mixtures and asphalt cement mixtures. The J-integral version of Paris ' law was successfully used to characterize the fatigue...

Mahboub, Kamyar

2012-06-07T23:59:59.000Z

151

Recent advances in lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithiumsulfur (LiS) batteries have attracted much attention lately because they have very high theoretical specific energy (2500Whkg?1), five times higher than that of the commercial LiCoO2/graphite batteries. As a result, they are strong contenders for next-generation energy storage in the areas of portable electronics, electric vehicles, and storage systems for renewable energy such as wind power and solar energy. However, poor cycling life and low capacity retention are main factors limiting their commercialization. To date, a large number of electrode and electrolyte materials to address these challenges have been investigated. In this review, we present the latest fundamental studies and technological development of various nanostructured cathode materials for LiS batteries, including their preparation approaches, structure, morphology and battery performance. Furthermore, the development of other significant components of LiS batteries including anodes, electrolytes, additives, binders and separators are also highlighted. Not only does the intention of our review article comprise the summary of recent advances in LiS cells, but also we cover some of our proposals for engineering of LiS cell configurations. These systematic discussion and proposed directions can enlighten ideas and offer avenues in the rational design of durable and high performance LiS batteries in the near future.

Lin Chen; Leon L. Shaw

2014-01-01T23:59:59.000Z

152

Heat Transfer Characteristics of Sulfur and Sulfur Diluted with Hydrogen Sulfide Flowing Through Circular Tubes  

E-Print Network [OSTI]

is called the pumping-power advantage factor, and has the value 2. 5 x 10 for sodium. The only metals having a higher value of H are 13 lithium 7 and bismuth. Lithium 7 comprises 92. 5% of natural lithium, but the cost of separating it from lithium 6...-section for thermal neutrons being 0. 130 barns. For comparison, water has an absorption cross-section of 0. 58 barns for thermal neutrons (2) . Sulfur is not activated by exposure to neutron flux in such a way as to produce a radioactive isotope which...

Stone, Porter Walwyn

1960-01-01T23:59:59.000Z

153

Polyaniline-modified cetyltrimethylammonium bromide-graphene oxide-sulfur nanocomposites with enhanced performance for lithium-sulfur batteries  

Science Journals Connector (OSTI)

Conductive polymer coatings can boost the power storage capacity of lithium-sulfur batteries. We report here on the design and ... polyaniline (PANI)-modified cetyltrimethylammonium bromide (CTAB)-graphene oxide ...

Yongcai Qiu; Wanfei Li; Guizhu Li; Yuan Hou; Lisha Zhou; Hongfei Li

2014-09-01T23:59:59.000Z

154

COMPONENT DEVELOPMENT NEEDS FOR THE HYBRID SULFUR ELECTROLYZER  

SciTech Connect (OSTI)

Fiscal year 2008 studies in electrolyzer component development have focused on the characterization of membrane electrode assemblies (MEA) after performance tests in the single cell electrolyzer, evaluation of electrocatalysts and membranes using a small scale electrolyzer and evaluating the contribution of individual cell components to the overall electrochemical performance. Scanning electron microscopic (SEM) studies of samples taken from MEAs testing in the SRNL single cell electrolyzer test station indicates a sulfur-rich layer forms between the cathode catalyst layer and the membrane. Based on a review of operating conditions for each of the MEAs evaluated, we conclude that the formation of the layer results from the reduction of sulfur dioxide as it passes through the MEA and reaches the catalyst layer at the cathode-membrane interface. Formation of the sulfur rich layer results in partial delamination of the cathode catalyst layer leading to diminished performance. Furthermore we believe that operating the electrolyzer at elevated pressure significantly increases the rate of formation due to increased adsorption of hydrogen on the internal catalyst surface. Thus, identification of a membrane that exhibits much lower transport of sulfur dioxide is needed to reduce the quantity of sulfur dioxide that reaches the cathode catalyst and is reduced to produce the sulfur-rich layer. Three candidate membranes are currently being evaluated that have shown promise from preliminary studies, (1) modified Nafion{reg_sign}, (2) polybenzimidazole (PBI), and (3) sulfonated Diels Alder polyphenylene (SDAPP). Testing examined the activity for the sulfur dioxide oxidation of platinum (Pt) and platinum-alloy catalysts in 30 wt% sulfuric acid solution. Linear sweep voltammetry showed an increase in activity when catalysts in which Pt is alloyed with non-noble transition metals such as cobalt and chromium. However when Pt is alloyed with noble metals, such as iridium or ruthenium, the kinetic activity decreases. We recommend further testing to determine if these binary alloys will provide the increased reaction kinetic needed to meet the targets. We also plan to test the performance of these catalyst materials for both proton and sulfur dioxide reduction. The latter may provide another parameter by which we can control the reduction of sulfur dioxide upon transport to the cathode catalyst surface. A small scale electrolyzer (2 cm{sup 2}) has been fabricated and successfully installed as an additional tool to evaluate the effect of different operating conditions on electrolyzer and MEA performance. Currently this electrolyzer is limited to testing at temperatures up to 80 C and at atmospheric pressure. Selected electrochemical performance data from the single cell sulfur dioxide depolarized electrolyzer were analyzed with the aid of an empirical equation which takes into account the overpotential of each of the components. By using the empirical equation, the performance data was broken down into its components and a comparison of the potential losses was made. The results indicated that for the testing conditions of 80 C and 30 wt% sulfuric acid, the major overpotential contribution ({approx}70 % of all losses) arise from the slow reaction rate of oxidation of sulfur dioxide. The results indicate that in order to meet the target of hydrogen production at 0.5 A/cm{sup 2} at 0.6 V and 50 wt% sulfuric acid, identification of a better catalyst for sulfur dioxide oxidation will provide the largest gain in electrolyzer performance.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-05-30T23:59:59.000Z

155

News and Views  

Science Journals Connector (OSTI)

... -16. The discussions on road lighting, from the point of view both of the pedestrian and the car driver, were valuable, as they show how complex the problem is ... problem is, depending as it does on difficult questions of physiology and psychology. The pedestrian wants to see small obstructions on the road and the numbers on the houses; ...

1928-07-28T23:59:59.000Z

156

ParaView at NERSC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ParaView ParaView ParaView Introduction ParaView is an open-source, multi-platform data analysis and visualization application. ParaView users can quickly build visualizations to analyze their data using qualitative and quantitative techniques. The data exploration can be done interactively in 3D or programmatically using ParaView's batch processing capabilities. ParaView was developed to analyze extremely large datasets using distributed memory computing resources. It can be run on supercomputers to analyze datasets of terascale as well as on laptops for smaller data. Remote Visualization with ParaView ParaView is a client-server application. The ParaView client (or simply paraview) will run on your desktop while the server will run at the remote supercomputing site. The following describes the steps you will take to

157

Allelic Loss in Esophageal Squamous Cell Carcinoma Patients with and without Family History of Upper Gastrointestinal Tract Cancer  

Science Journals Connector (OSTI)

...patients in group 2 had no family history of upper gastrointestinal or...cancers were combined for family history because historically both were...daily), and a detailed family history of cancer (including all cancers...microdissection (Pixcell 100; Arcturus Engineering, Mountain View, CA). Procured...

Nan Hu; Mark J. Roth; Michael R. Emmert-Buck; Ze-Zhong Tang; Mihael Polymeropolous; Quan-Hong Wang; Alisa M. Goldstein; Xiao-You Han; Sanford M. Dawsey; Ti Ding; Carol Giffen; and Philip R. Taylor

1999-11-01T23:59:59.000Z

158

BNL | Our History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Our History Our History A Passion for Discovery, a History of Scientific Achievement Brookhaven National Laboratory was established in 1947 on the eastern end of Long Island at the former site of the U.S. Army's Camp Upton. Originally built out of a post-World War II desire to explore the peaceful applications of atomic energy, the Laboratory now has a broader mission: to perform basic and applied research at the frontiers of science, including nuclear and high-energy physics; physics and chemistry of materials; nanoscience; energy and environmental research; national security and nonproliferation; neurosciences; structural biology; and computational sciences. Over its history, Brookhaven Lab has housed three research reactors, numerous one-of-a-kind particle accelerators, and other

159

Kelli Cox Oral History  

E-Print Network [OSTI]

Oral history interview with Kelli Cox conducted by Lauren Helmer in Lawrence, Kansas, on December 30, 2010. In this inteview, Kelli Cox discusses her experiences attending a variety of churches in Lawrence, including the Christ Community Church...

Cox, Kelli; Helmer, Lauren

2010-12-30T23:59:59.000Z

160

Noah Hamilton Oral History  

E-Print Network [OSTI]

Oral history interview with Noah Hamilton conducted by Stephanie Meador in Topeka, Kansas, on November 20, 2009. In this interview, Noah Hamilton describes the experience of being raised in the Bah' faith. He discusses the tenets of Bah...

Hamilton, Noah; Meador, Stephanie Rae

2009-11-20T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Black History Month  

Broader source: Energy.gov [DOE]

During National African American History Month, we pay tribute to the contributions of past generations and reaffirm our commitment to keeping the American dream alive for the next generation. In...

162

Beverly Boyd Oral History  

E-Print Network [OSTI]

Oral history interview with Beverly Boyd conducted by Steve Teichgraeber in Lawrence, Kansas, on November 12, 2010. In this interview, Beverly Boyd discusses the life of Saint Rose-Phillippine Duchesne (1769-1852), a ...

Boyd, Beverly; Teichgraeber, Steve

2010-11-12T23:59:59.000Z

163

Garrett Fugate Oral History  

E-Print Network [OSTI]

Oral history interview with Garrett Fugate conducted by Jeremy Adkison in 2010. In this interview, University of Kansas student Garrett Fugate discusses his childhood experiences as a member of the Greek Orthodox community, and his eventual decision...

Fugate, Garrett; Adkison, Jeremy

2010-01-01T23:59:59.000Z

164

Hybrid Sulfur Thermochemical Process Development Annual Report  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) Thermochemical Process is a means of producing hydrogen via water-splitting through a combination of chemical reactions and electrochemistry. Energy is supplied to the system as high temperature heat (approximately 900 C) and electricity. Advanced nuclear reactors (Generation IV) or central solar receivers can be the source of the primary energy. Large-scale hydrogen production based on this process could be a major contributor to meeting the needs of a hydrogen economy. This project's objectives include optimization of the HyS process design, analysis of technical issues and concerns, creation of a development plan, and laboratory-scale proof-of-concept testing. The key component of the HyS Process is the SO2-depolarized electrolyzer (SDE). Studies were performed that showed that an electrolyzer operating in the range of 500-600 mV per cell can lead to an overall HyS cycle efficiency in excess of 50%, which is superior to all other currently proposed thermochemical cycles. Economic analysis indicated hydrogen production costs of approximately $1.60 per kilogram for a mature nuclear hydrogen production plant. However, in order to meet commercialization goals, the electrolyzer should be capable of operating at high current density, have a long operating lifetime , and have an acceptable capital cost. The use of proton-exchange-membrane (PEM) technology, which leverages work for the development of PEM fuel cells, was selected as the most promising route to meeting these goals. The major accomplishments of this project were the design and construction of a suitable electrolyzer test facility and the proof-of-concept testing of a PEM-based SDE.

Summers, William A.; Buckner, Melvin R.

2005-07-21T23:59:59.000Z

165

Ryan Campbell Oral History  

E-Print Network [OSTI]

Under the Rainbow: Oral Histories of GLBTQ People in Kansas Ryan Campbell Oral History Part 1 video platform video management video solutionsvideo player Part 2 video platform video management video solutionsvideo player... Lawrence, KS 66045 Requestors must identify: 1. Type of publication 2. Proposed title 3. Specific passages to be quoted 4. Anticipated uses of the passages 5. Publisher's name 6. Expected date of publication ...

Campbell, Ryan; Albin, Tami

2009-12-16T23:59:59.000Z

166

Y-12's history captured in short film | National Nuclear Security...  

National Nuclear Security Administration (NNSA)

highlights of the site's history now is available for viewing on the Y-12 public Web site at http:www.y12.doe.govlibraryvideos70-years-making-world-safer. The...

167

Stereoscopic optical viewing system  

DOE Patents [OSTI]

An improved optical system which provides the operator with a stereoscopic viewing field and depth of vision, particularly suitable for use in various machines such as electron or laser beam welding and drilling machines. The system features two separate but independently controlled optical viewing assemblies from the eyepiece to a spot directly above the working surface. Each optical assembly comprises a combination of eye pieces, turning prisms, telephoto lenses for providing magnification, achromatic imaging relay lenses and final stage pentagonal turning prisms. Adjustment for variations in distance from the turning prisms to the workpiece, necessitated by varying part sizes and configurations and by the operator's visual accuity, is provided separately for each optical assembly by means of separate manual controls at the operator console or within easy reach of the operator.

Tallman, C.S.

1986-05-02T23:59:59.000Z

168

ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT  

SciTech Connect (OSTI)

The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

Amoroso, J.; Fox, K.

2011-09-07T23:59:59.000Z

169

Reconstructing the Star Formation Histories of Galaxies  

E-Print Network [OSTI]

We present a methodological study to find out how far back and to what precision star formation histories of galaxies can be reconstructed from CMDs, from integrated spectra and Lick indices, and from integrated multi-band photometry. Our evolutionary synthesis models GALEV allow to describe the evolution of galaxies in terms of all three approaches and we have assumed typical observational uncertainties for each of them and then investigated to what extent and accuracy different star formation histories can be discriminated. For a field in the LMC bar region with both a deep CMD from HST observations and a trailing slit spectrum across exactly the same field of view we could test our modelling results against real data.

Uta Fritze; Thomas Lilly

2007-01-15T23:59:59.000Z

170

URAT: astrometric requirements and design history  

E-Print Network [OSTI]

The U.S. Naval Observatory Robotic Astrometric Telescope (URAT) project aims at a highly accurate (5 mas), ground-based, all-sky survey. Requirements are presented for the optics and telescope for this 0.85 m aperture, 4.5 degree diameter field-of-view, specialized instrument, which are close to the capability of the industry. The history of the design process is presented as well as astrometric performance evaluations of the toleranced, optical design, with expected wavefront errors included.

Zacharias, N; Rakich, A; Epps, H

2006-01-01T23:59:59.000Z

171

Why sequence Sulfur cycling in the Frasassi aquifer?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sulfur cycling in the Frasassi aquifer? sulfur cycling in the Frasassi aquifer? The terrestrial subsurface remains one of the least explored microbial habitats on earth, and is critical for understanding pollutant migration and attenuation, subsurface processes such as limestone dissolution (affecting porosity), and the search for life elsewhere in the solar system and beyond. The deep and sulfidic Frasassi aquifer (of Ancona, Italy) has emerged as a model system for studying sulfur cycling in the terrestrial subsurface, and this sequencing project has relevance for developing applications for wastewater treatment and capabilities relevant for radionuclide, metal and organic pollutant remediation that can be applied at environments at DOE subsurface sites. Principal Investigators: Jennifer Macalady, Penn State University

172

Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

II. Phase Equilibria II. Phase Equilibria Title Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria Publication Type Journal Article Year of Publication 1996 Authors Ridgway, Paul L., Frank R. McLarnon, and John S. Newman Journal Journal of the Electrochemistry Society Volume 143 Issue 2 Pagination 412-417 Keywords 25 ENERGY STORAGE, 36 MATERIALS SCIENCE, ALUMINIUM OXIDES, equilibrium, performance, PHASE DIAGRAMS, PHOSPHIDES, PHOSPHORUS ADDITIONS, SODIUM COMPOUNDS, SODIUM SULFIDES, SODIUM-SULFUR BATTERIES Abstract Equilibrium open-circuit cell voltage data from a sodium/{beta}{double_prime}-alumina/phosphorus-sulfur cell utilizing P/S ratios of 0, 0.143, and 0.332 and a sodium atom fraction ranging from 0 to 0.4 were interpreted to construct ternary phase diagrams of the Na-P-S ternary system at 350 and 400 C.

173

Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results  

SciTech Connect (OSTI)

A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

2004-01-25T23:59:59.000Z

174

Indication of Meissner Effect in Sulfur-Substituted Strontium Ruthenates  

E-Print Network [OSTI]

Ceramic samples of Sr2RuO(4-y)Sy (y=0.03-1.2) with intended isovalent substitution of oxygen by sulfur have been synthesized and explored in the temperature range 4-300K. It is found that at a range of optimum sulfur substitution the magnetic response of ceramic samples reveals large diamagnetic signal with amplitudes approaching comparability with that of the YBCO-superconductors. Contrary to a pure ceramic Sr2RuO4, if properly optimized, the resistivity of sulfur-substituted samples has a metallic behavior except at lower temperatures where an upturn occurs. Both synthesis conditions and results of measurements are reported. The Meissner effect may point to high-temperature superconductivity.

Gulian, Armen

2011-01-01T23:59:59.000Z

175

HYBRID SULFUR ELECTROLYZER DEVELOPMENT FY09 SECOND QUARTER REPORT  

SciTech Connect (OSTI)

The primary objective of the DOE-NE Nuclear Hydrogen Initiative (NHI) is to develop the nuclear hydrogen production technologies necessary to produce hydrogen at a cost competitive with other alternative transportation fuels. The focus of the NHI is on thermochemical cycles and high temperature electrolysis that can be powered by heat from high temperature gas reactors. The Savannah River National Laboratory (SRNL) has been tasked with the primary responsibility to perform research and development in order to characterize, evaluate and develop the Hybrid Sulfur (HyS) thermochemical process. This report documents work during the first quarter of Fiscal Year 2009, for the period between January 1, 2009 and March 31, 2009. The HyS Process is a two-step hybrid thermochemical cycle that is part of the 'Sulfur Family' of cycles. As a sulfur cycle, it uses high temperature thermal decomposition of sulfuric acid to produce oxygen and to regenerate the sulfur dioxide reactant. The second step of the process uses a sulfur dioxide depolarized electrolyzer (SDE) to split water and produce hydrogen by electrochemically reacting sulfur dioxide with H{sub 2}O. The SDE produces sulfuric acid, which is then sent to the acid decomposer to complete the cycle. The DOE NHI program is developing the acid decomposer at Sandia National Laboratory for application to both the HyS Process and the Sulfur Iodine Cycle. The SDE is being developed at SRNL. During FY05 and FY06, SRNL designed and conducted proof-of-concept testing for a SDE using a low temperature, PEM fuel cell-type design concept. The advantages of this design concept include high electrochemical efficiency, small footprint and potential for low capital cost, characteristics that are crucial for successful implementation on a commercial scale. During FY07, SRNL extended the range of testing of the SDE to higher temperature and pressure, conducted a 100-hour longevity test with a 60-cm{sup 2} single cell electrolyzer, and designed and built a larger, multi-cell stack electrolyzer. During FY08, SRNL continued SDE development, including development and successful testing of a three-cell electrolyzer stack with a rated capacity of 100 liters per hour. The HyS program for FY09 program will address improving SDE performance by focusing on preventing or minimizing sulfur deposition inside the cell caused by SO{sub 2} crossover, reduction of cell voltage for improved efficiency, an extension of cell operating lifetime. During FY09 a baseline technology development program is being conducted to address each of these issues. Button-cell (2-cm{sup 2}) and single cell (60-cm{sup 2}) SDEs will be fabricated and tested. A pressurized button-cell test facility will be designed and constructed to facilitate addition testing. The single cell test facility will be upgraded for unattended operation, and later for operation at higher temperature and pressure. Work will continue on development of the Gas Diffusion Electrode (GDE), or Gap Cell, as an alternative electrolyzer design approach that is being developed under subcontract with industry partner Giner Electrochemical Systems. If successful, it could provide an alternative means of preventing sulfur crossover through the proton exchange membrane, as well as the possibility for higher current density operation based on more rapid mass transfer in a gas-phase anode. Promising cell components will be assembled into membrane electrode assemblies (MEAs) and tested in the single cell test facility. Upon modification for unattended operation, test will be conducted for 200 hours or more. Both the button-cell and modified single cell facility will be utilized to demonstrate electrolyzer operation without sulfur build-up limitations, which is a Level 1 Milestone.

Herman, D; David Hobbs, D; Hector Colon-Mercado, H; Timothy Steeper, T; John Steimke, J; Mark Elvington, M

2009-04-15T23:59:59.000Z

176

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range (400--650{degree}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2} formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1993-12-31T23:59:59.000Z

177

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 4, April--June 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650{degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams, The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Williams, R.S.

1993-12-31T23:59:59.000Z

178

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

179

History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

History History History On January 7, 2011, the President signed H.R. 6523 (111th), the Ike Skelton National Defense Authorization Act for Fiscal Year 2011 (http://www.govtrack.us/congress/bills/111/hr6523) which became Public Law 111-384. Section 3124 specifically states, "The Secretary of Energy may establish a program to permit the establishment of energy parks on former defense nuclear facilities" (50 U.S.C. 2814). In response, on February 17, 2011, the Department of Energy (DOE) established a Task Force on the ARI to address the legislation in detail. The purpose of the task force was to implement asset revitalization efforts in response to Congressional direction, and to develop recommendations for a continued formalized asset revitalization program. The task force achieved this through facilitating

180

PAFC History and Successes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PAFC History and Successes PAFC History and Successes John Ferro Manager Product Development john.ferro@utcpower.com 2 2 AGENDA Company overview and history System description and applications Failure modes and life analysis Summary 3 3 Research Center Hamilton Sundstrand Pratt & Whitney Sikorsky UTC Power Otis Carrier UTC Fire & Security UNITED TECHNOLOGIES CORPORATION 18 th largest U.S. manufacturer (2009 list, Industry Week) 37 th largest U.S. corporation (2009 list, Fortune) 61 st largest publicly held manufacturer in the world (2009 list, Industry Week) Revenues: $58.7 billion (2008) Commercial & Residential Building Systems, Aerospace & Transportation, Industrial systems 4 UTC POWER Markets Transportation fuel cells Stationary fuel cells Global sales 5 continents 19 countries Space & defense

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

NTS_History.indd  

Broader source: Energy.gov (indexed) [DOE]

Atmospheric Nuclear Atmospheric Nuclear Weapons Testing 1951 - 1963 Battlefi eld of the Cold War The Nevada Test Site United States Department of Energy Volume I Of related interest: Origins of the Nevada Test Site by Terrence R. Fehner and F. G. Gosling The Manhattan Project: Making the Atomic Bomb * by F. G. Gosling The United States Department of Energy: A Summary History, 1977 - 1994 * by Terrence R. Fehner and Jack M. Holl * Copies available from the U.S. Department of Energy 1000 Independence Ave. S.W., Washington, DC 20585 Attention: Offi ce of History and Heritage Resources Telephone: 301-903-5431 DOE/MA-0003 Terrence R. Fehner & F. G. Gosling Offi ce of History and Heritage Resources Executive Secretariat Offi ce of Management Department of Energy September 2006 Battlefi eld of the Cold War

182

History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

History History History Although they are tiny, atoms have a large amount of energy holding their nuclei together. Certain isotopes of some elements can be split and will release part of their energy as heat. This splitting is called fission. The heat released in fission can be used to help generate electricity in powerplants. Uranium-235 (U-235) is one of the isotopes that fissions easily. During fission, U-235 atoms absorb loose neutrons. This causes U-235 to become unstable and split into two light atoms called fission products. The combined mass of the fission products is less than that of the original U-235. The reduction occurs because some of the matter changes into energy. The energy is released as heat. Two or three neutrons are released along with the heat. These neutrons may hit other

183

Training History Report Training Services, Organizational Effectiveness/OHR 612-626-1373 UMReports  

E-Print Network [OSTI]

Training History Report Training Services, Organizational Effectiveness/OHR · 612-626-1373 UMReports www.umn.edu/ohr/trainingservices 1-30-13 Following are the steps to view one's training history. A report will be run in UMReports which displays training courses for one Emplid or by department

Thomas, David D.

184

The View from HQ  

National Nuclear Security Administration (NNSA)

A publication of the Office of Advanced Simulation & Computing, NNSA Defense Programs A publication of the Office of Advanced Simulation & Computing, NNSA Defense Programs NA-ASC-500-07-Issue 3 May 2007 The View from HQ by Dimitri Kusnezov I have been spending much of my time these days thinking about science, technology and engineering and the role of the laboratories and how that will be reflected in the Complex of the future. This is on my mind for two reasons: one is my responsibility to

185

Direct sulfur recovery during sorbent regeneration. Final report  

SciTech Connect (OSTI)

The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

1993-08-01T23:59:59.000Z

186

Oral Histories: Merril Eisenbud  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 6 HUMAN RADIATION STUDIES: REMEMBERING THE EARLY YEARS Oral History of Merril Eisenbud Conducted January 26, 1995 United States Department of Energy Office of Human Radiation Experiments May 1995 CONTENTS Foreword Short Biography Early Days as an Industrial Hygienist Hired as AEC's First Industrial Hygienist Insuring Atomic Workers Setting up the AEC's Health and Safety Laboratory Worker's Compensation History Contamination and Industrial Worker Education Federal Versus State Responsibility for Materials Production Safety Plant Safety and the Community Monitoring Radioactive Fallout Radiation and Cancer Rates Safety of the Nuclear Industry Use of Children in Research Developing Thyroid Radiation Counters Secrecy, Louis Strauss, and the Bravo Test Nuclear Test Fallout Studies

187

Microsoft Word - APRIL 2009 PMCDP Module CHRIS ESS Tutorial_MAINTAIN_PROJECT_HISTORY.doc  

Broader source: Energy.gov (indexed) [DOE]

MAINTIN PROJECT HISTORY MAINTIN PROJECT HISTORY REV: APRIL 2009 1 1. To update your project history, click on the "PMCDP Menu" and choose "Maintain project history." Maintain Project History ESS Tutorial, Project Management Career Development Program MAINTIN PROJECT HISTORY REV: APRIL 2009 2 2. A screen with the header "PMCDP Profile for [Your Name]" will appear titled "Step 3: Maintain project history." Options: Delete: This will delete all information for the selected project as currently showing in the table. Update: This will bring you back to the original input screen for project information. View Description: This will bring up a text box that will allow you to see the description previously entered. Sort: Project history information is presented in date-order, with the most recent position

188

NUPlans Budgeting Grant Input View  

E-Print Network [OSTI]

NUPlans Budgeting Grant Input View FMS704 NUPlansGrantInputViewV2 Last updated 4/7/2014 - rb © 2014 Northwestern University FMS704 NUPlans Contributor Budgeting 1 of 5 NUPlans Grant Input View NUPlans enables schools and units with grant projects to input grant expense estimates per project for the next fiscal

Shull, Kenneth R.

189

Extraction, separation, and analysis of high sulfur coal. Final report  

SciTech Connect (OSTI)

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. [comps.

1992-05-31T23:59:59.000Z

190

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. (comps.)

1992-05-31T23:59:59.000Z

191

Sulfur dioxide oxidation and plume formation at cement kilns  

SciTech Connect (OSTI)

Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

1980-10-01T23:59:59.000Z

192

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect (OSTI)

This second quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. Previous reports described development of a catalyst with the required selectivity and efficiency for producing sulfur dioxide from H{sub 2}S. In the laboratory, the catalyst was shown to be robust and stable in the presence of several intentionally added contaminants, including condensate from the pilot plant site. This report describes testing using the laboratory apparatus but operated at the pilot plant using the actual pilot plant gas, which contains far more contaminants than can be simulated in the laboratory. The results are very encouraging, with stable and efficient operation being obtained for a prolonged period of time.

Girish Srinivas; Steven C. Gebhard; David W. DeBerry

2002-07-01T23:59:59.000Z

193

Protective laser beam viewing device  

DOE Patents [OSTI]

A protective laser beam viewing system or device including a camera selectively sensitive to laser light wavelengths and a viewing screen receiving images from the laser sensitive camera. According to a preferred embodiment of the invention, the camera is worn on the head of the user or incorporated into a goggle-type viewing display so that it is always aimed at the area of viewing interest to the user and the viewing screen is incorporated into a video display worn as goggles over the eyes of the user.

Neil, George R.; Jordan, Kevin Carl

2012-12-18T23:59:59.000Z

194

Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Tier 2 Vehicle and Tier 2 Vehicle and Gasoline Sulfur Program to someone by E-mail Share Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Facebook Tweet about Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Twitter Bookmark Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Google Bookmark Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Delicious Rank Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on Digg Find More places to share Alternative Fuels Data Center: Tier 2 Vehicle and Gasoline Sulfur Program on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Tier 2 Vehicle and Gasoline Sulfur Program

195

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance...

196

Revisit Carbon/Sulfur Composite for Li-S Batteries. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Revisit CarbonSulfur Composite for Li-S Batteries. Revisit CarbonSulfur Composite for Li-S Batteries. Abstract: To correlate the carbon properties e.g. surface area and porous...

197

A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts  

E-Print Network [OSTI]

Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

Tang, Hairong

2005-01-01T23:59:59.000Z

198

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

2012-03-06T23:59:59.000Z

199

Ultra-Low Sulfur diesel Update & Future Light Duty Diesel | Department...  

Broader source: Energy.gov (indexed) [DOE]

Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Ultra-Low Sulfur diesel Update & Future Light Duty Diesel Presentation given at DEER 2006, August 20-24, 2006, Detroit,...

200

Wolf's History of Astronomy  

Science Journals Connector (OSTI)

... THE History of Astronomy, by Prof. Rudolf Wolf, of Zurich, a volume of 800 pages issued ... student. The production of such a work, involving an outline of the progress of astronomy from the earliest times to the present period, must have been a labour of ...

J. R. HIND

1878-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Oil Quantity : The histori  

E-Print Network [OSTI]

model for Prudhoe Bay. Figure 11: Historical Prudhoe Bay oil production data, modeled economically Production (million bbl per Month) Historical Production Best Fit (Hist. Tax w/ELF, Ref. P) High Price 120 140 160 19 Oil Quantity Con Wel N E A N N ng Results e Bay : The histori Bay over tim : Prudhoe Ba

Lin, C.-Y. Cynthia

202

Early History of Magnetism  

Science Journals Connector (OSTI)

... 2, Dr. J. B. Kramer read a paper on The Early History of Magnetism, in which he discussed the various accounts of the first discovery of a magnet ... accounts of the first discovery of a magnet, and the development of the science of magnetism down to A.D. 1600. His remarks were divided into five sections, the ...

1932-03-19T23:59:59.000Z

203

Exploring Mars' Climate History  

E-Print Network [OSTI]

Exploring Mars' Climate History #12;2 Mars Reconnaissance Orbiter ESA Mars Express (NASA: MARSIS by studying the solar wind and other interactions with the Sun. #12;The solar wind is a high-speed stream of electrons and protons released from the Sun. #12;High-energy photons (light) stream constantly from the Sun

204

Sulfur Degassing From Volcanoes: Source Conditions, Surveillance, Plume Chemistry and Earth System Impacts  

E-Print Network [OSTI]

of sulfur in magmas owes much to its multiple valence states (-II, 0, IV, VI), speciation (e.g., S2, H2S, SO on the redox chemistry of sulfur: by reducing sulfur, thiosulfate, sulfite and sulfate to H2S, or oxidizing sulfur and H2S to sulfate (e.g., Takano et al. 1997; Amend and Shock 2001; Shock et al. 2010

Boyer, Edmond

205

The View from HQ  

National Nuclear Security Administration (NNSA)

  NA-ASC-500-07 Issue 2 January 2007 The View from HQ Sitting in airports and planes is risky beyond the obvious dangers now in the news. Uninter- rupted time to think may lead to new ideas. Instinct instructs us that when we hear Wash- ington has some new ideas, the result must be bad. After all, ideas suggest change, which is inherently disruptive. Today the notion of predictivity is on my mind as I am leaving the V&V 2007 meeting in Los Alamos. Predictivity is on my short list of overused, ill-defined words. Washington main- tains a full lexicon of such words-a fair number of which find their way into common usage.

206

False color viewing device  

DOE Patents [OSTI]

This invention consists of a viewing device for observing objects in near-infrared false-color comprising a pair of goggles with one or more filters in the apertures, and pads that engage the face for blocking stray light from the sides so that all light reaching, the user`s eyes come through the filters. The filters attenuate most visible light and pass near-infrared (having wavelengths longer than approximately 700 nm) and a small amount of blue-green and blue-violet (having wavelengths in the 500 to 520 nm and shorter than 435 nm, respectively). The goggles are useful for looking at vegetation to identify different species and for determining the health of the vegetation, and to detect some forms of camouflage.

Kronberg, J.W.

1991-05-08T23:59:59.000Z

207

Sulfur-deactivated steam reforming of gasified biomass  

SciTech Connect (OSTI)

The effect of hydrogen sulfide on the stream reforming of methane has been studied. Methane is the most difficult component to convert by steam reforming in the mixture of hydrocarbons, which is produced in biomass gasification. Two catalysts were subjected to hydrogen sulfide levels up to 300 ppm so as to study the effect of sulfur on their deactivation. These catalysts were the C11-9-061, from United Catalyst Inc., and the HTSR1, from Haldor Topsoee. The activation energy of the sulfur-deactivated steam-reforming reaction was calculated to be 280 and 260 kJ/mol, for each catalyst, respectively. The high values most probably originate from the fact that the degree of sulfur coverage of the nickel surface is close to 1 for these experiments. Even under these severe conditions, steam reforming of methane is possible without any carbon formation. The HTSR1 catalyst exhibits a very high sulfur-free activity, resulting in a performance in the presence of hydrogen sulfide higher than that for the C11-9-061 catalyst. By using the HTSR1 catalyst, the reactor temperature can be lowered by 60 C in order to reach comparable levels of conversion.

Koningen, J.; Sjoestroem, K. [Kungl Tekniska Hoegskolan, Stockholm (Sweden)] [Kungl Tekniska Hoegskolan, Stockholm (Sweden)

1998-02-01T23:59:59.000Z

208

Effect of sulfur on heavy duty diesel engine lubricants  

SciTech Connect (OSTI)

Diesel engine exhaust legislation has become quite onerous for heavy duty engines. Yet, these high thermal efficiency engines continue to meet lower exhaust particulate and NOx emissions limits, due to new engine designs and the complementary engine oil performance requirements of the API service categories. In addition, the EPA has mandated changes in on-highway diesel fuel to help meet particulate emissions regulations. On October 1, 1993, when the EPA outlawed high sulfur fuels for on-highway use, the development of the API CG-4 engine oil performance specification was already in progress. All the new diesel engine tests in the category were therefore designed to run with low (< 0.05% wt.) sulfur fuel. In some engine tests, this new fuel improved some lubricant performance characteristics and degraded others. An engine oil specification for low sulfur fuel brings new challenges to developing future specifications for diesel engine oils. Both higher and lower lubricant additive treat rate products, high performance single grade oils, and formulations to meet world-wide specifications become viable. This paper discusses the results of a diesel engine oil technology that performs well with the new, low sulfur fuel in both engine tests and in the field.

Hayden, T.E. [Texaco Fuels and Lubricants Research Dept., Beacon, NY (United States)

1996-12-01T23:59:59.000Z

209

Workshop on sulfur chemistry in flue gas desulfurization  

SciTech Connect (OSTI)

The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

Wallace, W.E. Jr.

1980-05-01T23:59:59.000Z

210

Auction design and the market for sulfur dioxide emissions  

E-Print Network [OSTI]

Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

Joskow, Paul L.

1996-01-01T23:59:59.000Z

211

Sulfur tolerant molten carbonate fuel cell anode and process  

DOE Patents [OSTI]

Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

Remick, Robert J. (Naperville, IL)

1990-01-01T23:59:59.000Z

212

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents [OSTI]

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

213

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network [OSTI]

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

214

Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1  

E-Print Network [OSTI]

and 500 mbar CO2 with varying abundances of H2O and sulfur volatiles (H2S and SO2 mixing ratios of 10?3Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1 Michael A. Mischna,2 melting model, we obtain a high sulfur solubility, approximately 1400 ppm, in Martian mantle melts. We

Zuber, Maria

215

FY08 MEMBRANE CHARACTERIZATION REPORT FOR HYBRID SULFUR ELECTROLYZER  

SciTech Connect (OSTI)

This report summarizes results from all of the membrane testing completed to date at the Savannah River National Laboratory (SRNL) for the sulfur dioxide-depolarized electrolyzer (SDE). Several types of commercially-available membranes have been analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid (PFSA), sulfonated polyether-ketone-ketone (SPEKK), and polybenzimidazole membranes (PBI). Of these membrane types, the poly-benzimidazole membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Several experimental membranes have also been analyzed including hydrated sulfonated Diels-Alder polyphenylenes (SDAPP) membranes from Sandia National Laboratory, perfluorosulfonimide (PFSI) and sulfonated perfluorocyclobutyl aromatic ether (S-PFCB) prepared by Clemson University, hydrated platinum-treated PFSA prepared by Giner Electrochemical Systems (GES) and Pt-Nafion{reg_sign} 115 composites prepared at SRNL. The chemical stability, SO{sub 2} transport and ionic conductivity characteristics have been measured for several commercially available and experimental proton-conducting membranes. Commercially available PFSA membranes such as the Nafion{reg_sign} series exhibited excellent chemical stability and ionic conductivity in sulfur dioxide saturated sulfuric acid solutions. Sulfur dioxide transport in the Nafion{reg_sign} membranes varied proportionally with the thickness and equivalent weight of the membrane. Although the SO{sub 2} transport in the Nafion{reg_sign} membranes is higher than desired, the excellent chemical stability and conductivity makes this membrane the best commercially-available membrane at this time. Initial results indicated that a modified Nafion{reg_sign} membrane incorporating Pt nanoparticles exhibited significantly reduced SO{sub 2} transport. Reduced SO{sub 2} transport was also measured with commercially available PBI membrane and several experimental membranes produced at SNL and Clemson. These membranes also exhibit good chemical stability and conductivity in concentrated sulfuric acid solutions and, thus, serve as promising candidates for the SDE. Therefore, we recommend further testing of these membranes including electrolyzer testing to determine if the reduced SO{sub 2} transport eliminates the formation of sulfur-containing films at the membrane/cathode interface. SO{sub 2} transport measurements in the custom built characterization cell identified experimental limitations of the original design. During the last quarter of FY08 we redesigned and fabricated a new testing cell to overcome the previous limitations. This cell also offers the capability to test membranes under polarized conditions as well as test the performance of MEAs under selected electrolyzer conditions.

Hobbs, D; Hector Colon-Mercado, H; Mark Elvington, M

2008-09-01T23:59:59.000Z

216

Mound History and Information  

Office of Legacy Management (LM)

Mound Site History and Information Mound Site History and Information The Mound site, formerly known as the Mound Plant or Facility, takes its name from a nearby Na- tive American burial mound. The 306 acre facility is sited on a hill in the center of Miamisburg, Ohio. Construction of the Mound Plant began in 1946, and the site became operational in 1949. Mound, the nation's first post-war U.S. Atomic Energy Commission site to be constructed, was established to consolidate and continue the work conducted at the Dayton Units for the Manhattan Project. Much of the work at the Mound Plant during the Cold War involved production of the polonium- beryllium initiators used in early atomic weapons and the manufacture of and research related to ra- dionuclides. In the 1950s, the facility began to

217

About Fermilab - History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

What is Fermilab? What is Fermilab? what is Fermilab main page | mission | history | Enrico Fermi History - Wilson Hall Beauvais Cathedral A daring achievement of Gothic architecture, the Saint-Pierre Cathedral of Beauvais, France helped inspire the distinctive design of Wilson Hall. The Cathedral (A.D. 1225-1568) was never completed westward of the choir and transepts, and the site of the proposed nave is partly occupied by the Romanesque church known as the "Basse oeuvre" ("low work"). The roof fell (A.D. 1284); the choir was reconstructed and strengthened by additional piers (A.D. 1337-47), and in the 16th century the transepts were built. The height of the vault (157 ft., 6 ins.) is the loftiest in Europe, and measures about three and a half times its span. One of the most daring

218

BNL | Our History: Accelerators  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> See also: Reactors > See also: Reactors A History of Leadership in Particle Accelerator Design Cosmotron Cosmotron (1952-1966) Early in Brookhaven Lab history, the consortium of universities responsible for founding the new research center, decided that Brookhaven should provide leading facilities for high energy physics research. In April 1948, the Atomic Energy Commission approved a plan for a proton synchrotron to be built at Brookhaven. The new machine would accelerate protons to previously unheard of energies-comparable to the cosmic rays showering the earth's outer atmosphere. It would be called the Cosmotron. The Cosmotron was the first accelerator in the world to send particles to energies in the billion electron volt, or GeV, region. The machine reached its full design energy of 3.3 GeV in 1953.

219

RMOTC - About Us - History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History History Teapot Dome Scandal Teapot Dome was the popular name for the scandal during the administration of U.S. President Warren G. Harding. The scandal, which involved the secret leasing of naval oil reserve lands to private companies, was first revealed to the general public in 1924 after findings by a committee of the U.S. Senate. Teapot Rock, From which the famous Teapot Dome derives its name The creation of the Naval Petroleum Reserves originated with the growth of federal conservation policy under presidents Theodore Roosevelt, William Howard Taft, and Woodrow Wilson. The reserves were tracts of public land where oil should be kept in its natural reservoirs for the future use of the Navy. "Teapot Dome" originally acquired its name from a rock nearby

220

Reading Comprehension - Atomic History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atomic History Atomic History A Greek philosopher named Democritus said that all atoms are small, hard particles. He thought that atoms were made of a single material formed into different shapes and sizes. The word " _________ element compound mixture atom " is derived from the Greek word "atomos" which means "not able to be divided." In 1803, John Dalton, a school teacher, proposed his atomic theory. Dalton's theory states that elements (substances composed of only one type of _________ molecules ions atom ) combine in certain proportions to form _________ compounds atoms mixtures elements . In 1897, a British scientist named J. J. Thomson experimented with a cathode-ray tube which had a positively charged plate. The plate attracted negatively charged particles that we now call _________ protons neutrons

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1996-12-01T23:59:59.000Z

222

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Sixth quarterly technical progress report, January - March 1997  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-03-01T23:59:59.000Z

223

Enhanced electrochemical performance by wrapping graphene on carbon nanotube/sulfur composites for rechargeable lithiumsulfur batteries  

Science Journals Connector (OSTI)

Abstract A novel graphene-wrapped carbon nanotube/sulfur structure was designed to improve the electrochemical performance of the lithiumsulfur (LiS) batteries. Owing to the introduction of the reduced graphene oxide (rGO) with the aim to restrain the polysulfide anions diffusion phenomenon, increase the overall electronic conductivity of the electrode and accommodate volume expansion between the delithiated S and lithiated Li2S phases, the resulted graphene-wrapped carbon nanotube/sulfur (S/CNT@rGO) composite makes the cycling performance of the LiS batteries better than that without rGO. The S/CNT@rGO composite showed an initial discharge capacity of ~1299mAhg?1 at 0.2C rate. After 100 cycles of charge/discharge, the S/CNT@rGO composite retained a high specific capacity of ~670mAhg?1, much higher than that without rGO (graphene-wrapped carbon nanotube/sulfur composite could be a promising cathode material for high-rate performance LiS batteries.

Yishan Wu; Chunmei Xu; Jinxin Guo; Qingmei Su; Gaohui Du; Jun Zhang

2014-01-01T23:59:59.000Z

224

Strong Sulfur Binding with Conducting Magneli-Phase TinO2n-1 Nanomaterials for Improving Lithium-Sulfur Batteries  

E-Print Network [OSTI]

will go through a series of soluble intermediate higher-order polysulfides (Li2S8, Li2S6, and Li2S4 of Li2S2, Li2S, and sulfur.6-8 In order to solve these challenges, there have been recent developmentsStrong Sulfur Binding with Conducting Magneli-Phase TinO2n-1 Nanomaterials for Improving Lithium-Sulfur

Cui, Yi

225

NERSC Systems History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

History of Systems History of Systems History of Systems Established in 1974 at Lawrence Livermore National Laboratory, NERSC was moved to Berkeley Lab in 1996 with a goal of increased interactions with the UC Berkeley campus. NERSC Systems System Name Installed System Type CPU Computational Pool Interconnect Disk (TB) Avg. Power Linpack HPL/ Top Rank Peak GFlops/s Type Speed Nodes SMP Size Total Cores Aggregate Memory (GB) Avg. Memory/ CPU Edison 2013 Cray XC30 Xeon 12-Core 2.3 GHz 5,200 24 124,800 332,800 2.67GB Hopper 2010 Cray XE6 Opteron Hex-Core 2.1 GHz 6,384 24 153,216 216,832 1.3 GB Gemini 2,000 1,054,000 (5) 1,054,000 Carver 2010 IBM iDataPlex Intel Nehalem Quad-Core 2.6 GHz 400 8 3,200 9,600 3 GB 4X QDR InfiniBand NGF 36,856 (322) 42,656

226

Star Formation Histories in the Local Group  

E-Print Network [OSTI]

Deep color magnitude diagrams extending to the main sequence provide the most direct measure of the detailed star formation history in a stellar population. With large investments of observing time, HST can obtain such data for populations out to 1 Mpc, but its field of view is extremely small in comparison to the size of Local Group galaxies. This limitation severely constrains our understanding of galaxy formation. For example, the largest galaxy in the Local Group, Andromeda, offers an ideal laboratory for studying the formation of large spiral galaxies, but the galaxy shows substructure on a variety of scales, presumably due to its violent merger history. Within its remaining lifetime, HST can only sample a few sight-lines through this complex galaxy. In contrast, a wide field imager could provide a map of Andromeda's halo, outer disk, and tidal streams, revealing the spatially-dependent star formation history in each structure. The same data would enable many secondary studies, such as the age variation in Andromeda's globular cluster system, gigantic samples of variable stars, and microlensing tracers of the galaxy's dark matter distribution.

Thomas M. Brown

2004-07-09T23:59:59.000Z

227

Sulfur-tolerant anode materials for solid oxide fuel cell application  

SciTech Connect (OSTI)

This paper summarizes the degradation mechanisms for SOFC anodes in the presence of sulfur and recent developments in sulfur-tolerant anodes. There are two primary sulfur-degradation mechanisms for the anode materials: physical absorption of sulfur that blocks the hydrogen reaction sites, and chemical reaction that forms nickel sulfide. The sulfur-tolerant anodes are categorized into three kinds of materials: thiospinels and metal sulfides, metal cermets, and mixed ionic and electronic conductors. Each material has its own advantages and disadvantages, and the combined application of available materials to serve as different functional components in anodes through proper design may be effective to achieve a balance between stability and performance.

Gong, M. (West Virginia University, Morgantown, WV); Liu, X. (West Virginia University, Morgantown, WV); Trembly, J.; Johnson, C.

2007-06-01T23:59:59.000Z

228

Sulfur tolerant anode materials. Quarterly report, October 1--December 31, 1987  

SciTech Connect (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-02-01T23:59:59.000Z

229

Sulfur tolerant anode materials. Quarterly report, January 1--March 31, 1988  

SciTech Connect (OSTI)

The goal of this program is the development of a molten carbonate fuel cell (MCFC) anode which is more tolerant of sulfur contaminants in the fuel than the current state-of-the-art nickel-based anode structures. This program addresses two different but related aspects of the sulfur contamination problem. The primary aspect is concerned with the development of a sulfur tolerant electrocatalyst for the fuel oxidation reaction. A secondary issue is the development of a sulfur tolerant water-gas-shift reaction catalyst and an investigation of potential steam reforming catalysts which also have some sulfur tolerant capabilities. These two aspects are being addressed as two separate tasks.

Not Available

1988-05-01T23:59:59.000Z

230

Method of burning sulfur-containing fuels in a fluidized bed boiler  

DOE Patents [OSTI]

A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

Jones, Brian C. (Windsor, CT)

1982-01-01T23:59:59.000Z

231

Flue-gas sulfur-recovery plant for a multifuel boiler  

SciTech Connect (OSTI)

In October 1991, a Finnish fluting mill brought on stream a flue-gas desulfurization plant with an SO{sub 2} reduction capacity of 99%. The desulfurization plant enabled the mill to discontinue the use of its sulfur burner for SO{sub 2} production. The required makeup sulfur is now obtained in the form of sulfuric acid used by the acetic acid plant, which operates in conjunction with the evaporating plant. The mill`s sulfur consumption has decreased by about 6,000 tons/year (13.2 million lb/year) because of sulfur recycling.

Miettunen, J. [Tampella Power Inc., Tampere (Finland); Aitlahti, S. [Savon Sellu Oy, Kuopio (Finland)

1993-12-01T23:59:59.000Z

232

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October 1993--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400-650 {degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought {open_quotes}Claus-alternative{close_quotes} for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1996-01-01T23:59:59.000Z

233

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

234

HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING  

SciTech Connect (OSTI)

This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a portion of the inlet H{sub 2}S. Oxidation catalysts may also produce some elemental sulfur under these conditions, which can be removed and recovered prior to the CrystaSulf absorber. The CrystaSulf-DO process can utilize direct oxidation catalyst from many sources. Numerous direct oxidation catalysts are available from many suppliers worldwide. They have been used for H{sub 2}S oxidation to sulfur and/or SO{sub 2} for decades. It was believed at the outset of the project that TDA Research, Inc., a subcontractor, could develop a direct oxidation catalyst that would offer advantages over other commercially available catalysts for this CrystaSulf-DO process application. This project involved the development of several of TDA's candidate proprietary direct oxidation catalysts through laboratory bench-scale testing. These catalysts were shown to be effective for conversion of H{sub 2}S to SO{sub 2} and to elemental sulfur under certain operating conditions. One of these catalysts was subsequently tested on a commercial gas stream in a bench-scale reactor at CrystaTech's pilot plant site in west Texas with good results. However, commercial developments have precluded the use of TDA catalysts in the CrystaSulf-DO process. Nonetheless, this project has advanced direct oxidation catalyst technology for H{sub 2}S control in energy industries and led to several viable paths to commercialization. TDA is commercializing the use of its direct oxidation catalyst technology in conjunction with the SulfaTreat{reg_sign} solid scavenger for natural gas applications and in conjunction with ConocoPhillips and DOE for gasification applications using ConocoPhillips gasification technology. CrystaTech is commercializing its CrystaSulf-DO process in conjunction with Gas Technology Institute for natural gas applications (using direct oxidation catalysts from other commercial sources) and in conjunction with ChevronTexaco and DOE for gasification applications using ChevronTexaco's gasification technology.

Dennis Dalrymple

2004-06-01T23:59:59.000Z

235

In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In situ Observation of Sulfur in Living In situ Observation of Sulfur in Living Mammalian Cells: Uptake of Taurine into MDCK Cells Sulfur is essential for life. It plays important roles in the amino acids methionine and cysteine, and has a structural function in disulfide bonds. As a component of iron-sulfur clusters it takes part in electron and sulfur transfer reactions.1 Glutathione, a sulfur-containing tripeptide, is an important part of biological antioxidant systems.2 Another example for the biological relevance of sulfur is the amino acid taurine, which is present in high concentrations in algae and the animal kingdom. Taurine has been implicated in a range of physiological phenomena, but its osmolytic role in cell volume regulation has been studied in greatest detail.3 In situ information on sulfur is rare despite its important biological role. This is due to the fact that sulfur is not easily accessible with most biophysical techniques. In recent years, sulfur x-ray absorption spectroscopy (XAS) has become increasingly important in the study of sulfur species in biological systems.4 The near-edge region of the XAS spectrum is a sensitive probe of electronic structure and hence chemical form.5

236

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CSP Generation CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage to someone by E-mail Share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Facebook Tweet about SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Twitter Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Google Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Delicious Rank SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Digg Find More places to share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on

237

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

SciTech Connect (OSTI)

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

238

Hanford Overview and History - Hanford Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

About Us > Hanford Overview and History About Us Hanford Overview and History Hanford Cleanup Hanford Site Wide Programs Hanford Overview and History Email Email Page | Print Print...

239

Kami Oral History  

E-Print Network [OSTI]

this interview the way that I start off all the oral histories which is, Tell me where you were born and when. KAMI: I was born in Salt Lake City, Utah in August, 1950. And my father was at the University of Utah in school. And they lived in Layton, so we.... But yeah, I went across the country and I danced around and(laugh) and I love Salt Lake. And I didn't appreciate Salt Lake then the way I do now. I've really come tobut I had good friends in the dorms and, yeah I didn'tI was never homesick, never...

Albin, Tami; Kami

2010-01-11T23:59:59.000Z

240

Sulfur Lamps-The Next Generation of Efficient Light?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 5 Sulfur Lamps-The Next Generation of Efficient Light? The figure above is a schematic of the system installed at the National Air and Space Museum and the DOE headquarters in Washington, D.C., Light from the sulfur lamp is focused by a parabolic reflector so that it enters the light pipe within a small angular cone. Light travels down the pipe, reflecting off the prismatic film (A) that lines the outer acrylic tube. The prismatic film reflects the light through total internal reflection (C), an intrinsically efficient process. Some of the light striking the film (at A) is not reflected and "leaks out" of the pipe walls (B), giving the pipe a glowing appearance. A light ray that travels all the way down the pipe will strike the mirror at the end (D) and return back up the pipe.

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Cost-cutting for offshore sulfur recovery processes studied  

SciTech Connect (OSTI)

An increasing portion of future US gas supply is likely to come from offshore, primarily Gulf of Mexico. Because this gas can be sour, the industry has sought lower cost H{sub 2}S-removal/recovery processes for treating it. Usually the gas contains < 5 tons/day (tpd) of sulfur. A study to compare several emerging sulfur-removal/recovery processes against a baseline Amine/LO-CAT II process has indicated that some emerging processes, though not yet commercialized, show considerable potential for reducing costs. Specifically, the major findings were that Double Loop and CrystaSulf, developed by Radian International LLC, Austin, were the least expensive capital-cost processes by a significant margin and that Marathon Oil Co.`s Hysulf`s cost has the potential to compete with Double Loop and CrystaSulf.

Quinlan, M.P.; Echterhoff, L.W. [M.W. Kellogg Co., Houston, TX (United States); Leppin, D.; Meyer, H.S. [Gas Research Inst., Chicago, IL (United States)

1997-07-21T23:59:59.000Z

242

Method of making sulfur-resistant composite metal membranes  

DOE Patents [OSTI]

The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

2012-01-24T23:59:59.000Z

243

Availability of heavy fuel oils by sulfur level, September 1981  

SciTech Connect (OSTI)

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held, refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 2 figures, 13 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

244

More Economical Sulfur Removal for Fuel Processing Plants  

Broader source: Energy.gov (indexed) [DOE]

enabled TDA to develop and commercialize its direct oxidation process-a simple, catalyst-based system for removing sulfur from natural gas and petroleum-that was convenient and economical enough for smaller fuel processing plants to use. TDA Research, Inc. (TDA) of Wheat Ridge, CO, formed in 1987, is a privately-held R&D company that brings products to market either by forming internal business

245

Structure of Chemisorbed Sulfur on a Pt(111) Electrode  

Science Journals Connector (OSTI)

Contribution from the Department of Chemistry, University of Illinois and Frederick Seitz Materials Research Laboratory, 600 S. Mathews Ave., Urbana, Illinois 61801, and Dpartement de Chimie, Universit de Sherbrooke, Sherbrooke, Qubec, J1K 2R1, Canada ... Sulfur was deposited from aqueous sulfide and bisulfide media on Pt(111), and the interrogations were conducted by low electron energy diffraction (LEED), Auger electron spectroscopy (AES), and core-level electron energy loss spectroscopy (CEELS). ...

Y.-E. Sung; W. Chrzanowski; A. Zolfaghari; G. Jerkiewicz; A. Wieckowski

1997-01-08T23:59:59.000Z

246

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network [OSTI]

HYDROGEN AND SULFUR PRODUCTION FROM HYDROGEN SULFIDE WASTES? John B.L. Harkness and Richard D. Doctor, Argonne National Laboratory, Argonne. IL ABSTRACT A new hydrogen sulfide waste-treatment process that uses microwave plasma... to be economically competitive. In addition, the experiments show-that. typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology. BACKGROUND In 1987, Argonne staff found the first...

Harkness, J.; Doctor, R. D.

247

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

Coal Reaction Study: The results of the reaction of aqueous cupric chloride with Illinois {number sign}6 coal are listed on page 21. These results indicate that the oxidative desulfurization of coal with cupric chloride is more complex and less effective than previously reported. Although almost all the pyritic and sulfate sulfur are removed from the coal, the organic sulfur is actually reported to have increased. This may be due to an actual increase in the organic sulfur through a side reaction of the pyrite, or it may be caused by inaccuracy of the ASTM method when large proportions of chloro substituents are present. The amount of chlorine added to the coal (from 0 to 3.18%) is quite large and counterproductive. Most importantly, the amount of non-combustible ash has increased from 15.48 to 51.21%, most likely in the form of copper. This will dramatically decrease both the efficiency of combustion in terms of altering the heat capacity of the coal as well as decrease the amount of energy produced per ton of coal. As a result, it is quite evident that this method of desulfurization needs some modification prior to further exploitation.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

248

Removal of nitrogen and sulfur from oil-shale  

SciTech Connect (OSTI)

This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

Olmstead, W.N.

1986-01-28T23:59:59.000Z

249

RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

Hobbs, D.

2010-07-22T23:59:59.000Z

250

FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL  

SciTech Connect (OSTI)

This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

Gary M. Blythe

2001-11-06T23:59:59.000Z

251

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

252

ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION  

SciTech Connect (OSTI)

A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

Gorensek, M.; Edwards, T.

2009-06-11T23:59:59.000Z

253

History | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Argonne's Nobelists Argonne's Nobelists Three Argonne physicists have been honored with Nobel Prizes: Enrico Fermi, Argonne's founding director, won the 1938 Nobel Prize in physics for his demonstrations of the existence of new radioactive elements produced by neutron irradiation and for his related discovery of nuclear reactions brought about by slow neutrons. Maria Goeppert Mayer shared the 1963 Nobel Prize in physics. While working at Argonne in 1948, she developed the "nuclear shell model" to explain how neutrons and protons within atomic nuclei are structured. Alexei A. Abrikosov shared the 2003 Nobel Prize in physics for research on condensed-matter physics and superconductivity. Our history sparked the nation's future AVIDAC, Argonne's first digital computer, began operation in January 1953.

254

Chisolm View | Open Energy Information  

Open Energy Info (EERE)

Chisolm View Chisolm View Jump to: navigation, search Name Chisolm View Facility Chisolm View Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner GE Energy Financial Service / Enel Green Power North America Developer TradeWind Energy Energy Purchaser Alabama Power Company Location Hunter OK Coordinates 36.59527057°, -97.54501104° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.59527057,"lon":-97.54501104,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

255

Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent Tuning of Properties of Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in nature and catalyze one-electron transfer processes. These proteins have evolved into two classes that have large differences in their electrochemical potentials: high potential iron-sulfur proteins (HiPIPs) and bacterial ferredoxins (Fds). The role of the surrounding protein environment in tuning the redox potential of these iron sulfur clusters has been a persistent puzzle in biological electron transfer [1]. Although HiPIPs and Fds have the same iron sulfur structural motif - a cubane-type structure - (Figure 1), there are large differences in their electrochemical

256

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo Graphic of a diagram of squares and circles connected by arrows. Sulfur-based TES can compensate for diurnal and seasonal insolation fluctuations. General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power generation. Approach There are three main project objectives under this award: Study the sulfur generating disproportionation reaction and develop it into a practical engineering process step. Carry out preliminary process components design and experimental validation. The engineering data will be used for process integration between the CSP plant, the sulfur processing and storage plant, and the electricity generation unit.

257

A history of the neutron  

Science Journals Connector (OSTI)

A history of the neutron ... Describes some of the individuals and the work they did leading to the discovery of the neutron. ...

Vasilis Lavrakas

1952-01-01T23:59:59.000Z

258

History of Proton Linear Accelerators  

E-Print Network [OSTI]

much. References 1. Linear Accelerators, edited by P. M .at the 1986 Linear Accelerator Conference, SLAC, Stanford,HISTORY OF PROTON LINEAR ACCELERATORS Luis W. Alvarez TWO-

Alvarez, Luis W.

1987-01-01T23:59:59.000Z

259

doi:10.1016/j.gca.2005.02.002 Sulfur diffusion in basaltic melts  

E-Print Network [OSTI]

doi:10.1016/j.gca.2005.02.002 Sulfur diffusion in basaltic melts CARMELA FREDA,1, * DON R. BAKER,1,2 February 3, 2005) Abstract--We measured the diffusion coefficients of sulfur in two different basaltic for sulfur diffusion in anhydrous basalts: D 2.19 10 4 exp 226.3 58.3 RT where D is the diffusion coefficient

Long, Bernard

260

Microsoft Word - Vapor Phase Elemental Sulfur Tech Brief DRAFT bbl 08-24.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AT A GLANCE AT A GLANCE  eliminates excavation expense  applicable to large or small sites  straightforward deployment  uses heat to distribute sulfur throughout a soil  mercury reacts with sulfur to form immobile and insoluble minerals  patent applied for TechBrief Vapor Phase Elemental Sulfur Amendment for Sequestering Mercury in Contaminated Soil Scientists at the Savannah River National Laboratory (SRNL) have identified a method of targeting mercury in contaminated soil zone by use of sulfur vapor heated gas. Background Mercury contamination in soil is a common problem in the environment. The most common treatment is excavation - a method that works well for small sites where the

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite...  

Broader source: Energy.gov (indexed) [DOE]

October 04, 2011 Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System DEER CONFERENCE 2011 Outline Introduction Zeolite-based SCR behavior -...

262

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

263

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

264

Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...  

Gasoline and Diesel Fuel Update (EIA)

Energy Information Administration Petroleum Marketing Annual 1995 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon...

265

E-Print Network 3.0 - aqueous sulfuric acid Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TRACE ATMOSPHERIC CONSTITUENTS Summary: . Reactions of Sulfur(IV) with Transition-Metal Ions in Aqueous Solutions Robert E. Huie and Norman C... . Peterson 3. Catalytic...

266

E-Print Network 3.0 - aqueous organic sulfur Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TRACE ATMOSPHERIC CONSTITUENTS Summary: . Reactions of Sulfur(IV) with Transition-Metal Ions in Aqueous Solutions Robert E. Huie and Norman C... . Peterson 3. Catalytic...

267

E-Print Network 3.0 - ashless low-sulfur fuel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Blendstocks for Low Sulfur Diesel Fuel in PADD III . . . . . . . . . . . . . . . . 17... markets for low ... Source: Oak Ridge National Laboratory, Center for Transportation...

268

E-Print Network 3.0 - aromatic sulfur heterocycles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . Polycyclic aromatic sulfur heterocycles IV. Determination of polycyclic...

269

Portable instrument and method for detecting reduced sulfur compounds in a gas  

DOE Patents [OSTI]

A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

1983-06-01T23:59:59.000Z

270

Assessing Potential Acidification of Marine Archaeological Wood Based on Concentration of Sulfur Species  

SciTech Connect (OSTI)

The presence of sulfur in marine archaeological wood presents a challenge to conservation. Upon exposure to oxygen, sulfur compounds in waterlogged wooden artifacts are being oxidized, producing sulfuric acid. This speeds the degradation of the wood, potentially damaging specimens beyond repair. Sulfur K-edge x-ray absorption spectroscopy was used to identify the species of sulfur present in samples from the timbers of the Mary Rose, a preserved 16th century warship known to undergo degradation through acidification. The results presented here show that sulfur content varied significantly on a local scale. Only certain species of sulfur have the potential to produce sulfuric acid by contact with oxygen and seawater in situ, such as iron sulfides and elemental sulfur. Organic sulfurs, such as the amino acids cysteine and methionine, may produce acid but are integral parts of the wood's structure and may not be released from the organic matrix. The sulfur species contained in the sample reflect the exposure to oxygen while submerged, and this exposure can differ greatly over time and position. A better understanding of the species pathway to acidifications required, along with its location, in order to suggest a more customized and effective preservation strategy. Waterlogged archaeological wood, frequently in the form of shipwrecks, is being excavated for historical purposes in many countries around the world. Even after extensive efforts towards preservation, scientists are discovering that accumulation of sulfate salts results in acidic conditions on the surfaces of the artifacts. Sulfuric acid degrades structural fibers in the wood by acid hydrolysis of cellulose, accelerating the decomposition of the ship timbers. Determining the sulfur content of waterlogged wood is now of great importance in maritime archaeology. Artifact preservation is often more time consuming and expensive than the original excavation; but it is key to the availability of objects for future study as well as maintaining the integrity of historical data and preserving the value of museum pieces. Sulfur occurs in a wide number of oxidation states from -2 to +6, and appears in numerous organic and inorganic compounds in nature. However, it is a very minor component of wood. Sulfur K-edge x-ray absorption spectroscopy (XAS) is a valuable technique because it has the ability to detect very low concentrations of sulfur in the specimen. XAS is also sensitive to differences in oxidation states, as well as long and short range order in molecules.

Not Available

2011-06-22T23:59:59.000Z

271

Sulfur behavior in the Sasol-Lurgi fixed-bed dry-bottom gasification process  

SciTech Connect (OSTI)

This article reports on the findings of a study regarding the sulfur behavior across a Sasol-Lurgi gasifier. This was undertaken to understand the behavior of the various sulfur-bearing components in the coal, as they are exposed to the conditions in the gasifier. In this study, conventional characterization techniques were employed to monitor the behavior of sulfur-bearing mineral matter across the gasifier. It was observed from the study that the sulfur-bearing mineral (pyrite) in the coal structure undergoes various changes with pyrite being transformed to pyrrhotite and then to various oxides of iron with the subsequent loss of sulfur to form H{sub 2}S. A low proportion of the sulfur species including the organically associated sulfur was encapsulated by a melt that was formed by the interaction between kaolinite and fluxing minerals (pyrite, calcite, and dolomite/ankerite) present in the coal at elevated temperatures and pressure, thereby ending up in the ash. The remaining small proportions of sulfur-bearing mineral matter including pyrite and organically bound sulfur in the unburned carbon in the carbonaceous shales also report to the ash. 18 refs., 8 figs., 2 tabs.

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; H. Schobert [Sasol Technology R& amp; D, Sasolburg (South Africa)

2009-01-15T23:59:59.000Z

272

Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program  

SciTech Connect (OSTI)

DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

George Sverdrup

1999-06-07T23:59:59.000Z

273

Sulfur-tolerant natural gas reforming for fuel-cell applications.  

E-Print Network [OSTI]

??An attractive simplification of PEM-FC systems operated with natural gas would be the use of a sulfur tolerant reforming catalyst, but such a catalyst has (more)

Hennings, Ulrich

2010-01-01T23:59:59.000Z

274

E-Print Network 3.0 - absorbing sulfur dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

275

E-Print Network 3.0 - ambient sulfur dioxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

provides some chemicals which are incompatible with other compounds. Summary: Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other acids...

276

E-Print Network 3.0 - africa sulfur isotope Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: africa sulfur isotope Page: << < 1 2 3 4 5 > >> 1 Geobiology (2006), 4, 191201 2006 The...

277

Sulfur barrier for use with in situ processes for treating formations  

DOE Patents [OSTI]

Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

2009-12-15T23:59:59.000Z

278

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-03-04T23:59:59.000Z

279

SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

Gary M. Blythe; Richard McMillan

2002-07-03T23:59:59.000Z

280

SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS  

SciTech Connect (OSTI)

The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

Gary M. Blythe; Richard McMillan

2002-02-04T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Printed 3D Multi-View Images  

Science Journals Connector (OSTI)

The technique to produce full-parallax 3D multi-view still pictures is described. The matrix of source views (from 6x6 to 15x15 views) is built from computer-generated images or...

Kim, Sung-Sik; Son, Kwang-Hun; Saveljev, V V; Son, Jung-Young

2001-01-01T23:59:59.000Z

282

Central Appalachia: Production potential of low-sulfur coal  

SciTech Connect (OSTI)

The vast preponderance of eastern US low sulfur and 1.2-lbs SO{sub 2}/MMBtu compliance coal comes from a relatively small area composed of 14 counties located in eastern Kentucky, southern West Virginia and western Virginia. These 14 counties accounted for 68% of all Central Appalachian coal production in 1989 as well as 85% of all compliance coal shipped to electric utilities from this region. A property-by-property analysis of total production potential in 10 of the 14 counties (Floyd, Knott, Letcher, Harlan, Martin and Pike in Kentucky and Boone, Kanawha, Logan and Mingo in West Virginia) resulted in the following estimates of active and yet to be developed properties: (1) total salable reserves for all sulfur levels were 5.9 billion tons and (2) 1.2-lbs. SO{sub 2}/MMBtu compliance'' reserves totaled 2.38 billion tons. This potential supply of compliance coal is adequate to meet the expanded utility demand expected under acid rain for the next 20 years. Beyond 2010, compliance supplies will begin to reach depletion levels in some areas of the study region. A review of the cost structure for all active mines was used to categorize the cost structure for developing potential supplies. FOB cash costs for all active mines in the ten counties ranged from $15 per ton to $35 per ton and the median mine cost was about $22 per ton. A total of 47 companies with the ability to produce and ship coal from owned or leased reserves are active in the ten-county region. Identified development and expansion projects controlled by active companies are capable of expanding the region's current production level by over 30 million tons per year over the next twenty years. Beyond this period the issue of reserve depletion for coal of all sulfur levels in the ten county region will become a pressing issue. 11 figs., 12 tabs.

Watkins, J. (Hill and Associates, Inc., Annapolis, MD (United States))

1991-09-01T23:59:59.000Z

283

A HISTORY OF EMATS  

Science Journals Connector (OSTI)

This paper was prepared for a Special Session in the 34th Annual Review of Quantitative NDE devoted to Applications of EMATs. As such it reviews the past history of electromagnetic induction of vibrations in metals with special attention to the application to nondestructive testing. The first patent describing the use of Electromagnetic Acoustic Transducers (EMATs) to replace the commonly used piezoelectric transducer was in 1969 but their first appearance in the scientific literature was in 1939 when the principles were applied to exciting and detecting the longitudinal resonance modes of bars of brass. The first true application to nondestructive testing was an R&D program sponsored by the American Gas Association to develop a device for inspecting buried gas pipelines for stress corrosion cracks in the early 1970's. During this same time period theoretical models to describe the transduction mechanism appeared and led to the engineering of solutions to NDT and NDE problems that could not be accomplished with piezoelectric devices. The papers in the session to follow this historical summary show how the field has developed over the past 30 years and expose an impressive array of applications to quantitative nondestructive evaluation (QNDE) practices.

George Alers

2008-01-01T23:59:59.000Z

284

Sulfur polymer cement for macroencapsulation of mixed waste debris  

SciTech Connect (OSTI)

In FY 1997, the US DOE Mixed Waste Focus Area (MWFA) sponsored a demonstration of the macroencapsulation of mixed waste debris using sulfur polymer cement (SPC). Two mixed wastes were tested--a D006 waste comprised of sheets of cadmium and a D008/D009 waste comprised of lead pipes and joints contaminated with mercury. The demonstration was successful in rendering these wastes compliant with Land Disposal Restrictions (LDR), thereby eliminating one Mixed Waste Inventory Report (MWIR) waste stream from the national inventory.

Mattus, C.H.

1998-06-01T23:59:59.000Z

285

Removal of sulfur and nitrogen containing pollutants from discharge gases  

DOE Patents [OSTI]

Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

Joubert, James I. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

286

Our History | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Our History Our History Our History Our History The history of Office of Electricity Delivery and Energy Reliability (OE) begins in August 2003, when the Department created two offices to provide focus in several critical areas: the Office of Electric Transmission and Distribution (TD), which included elements from the DOE Energy Efficiency and Renewable Energy office and the DOE Policy and International Affairs office, to advance the technologies needed to ensure a reliable, robust and modern U.S. electricity grid; and the Office of Energy Assurance (EA), to coordinate Federal response activities within the energy sector during energy disruptions and developed strategies to harden infrastructure against such disruptions. On August 14, 2003, large portions of the Midwest and Northeast United

287

ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP  

SciTech Connect (OSTI)

Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Mack Trucks Inc.), a filter recycler (American Wastes Industries), and a low-sulfur fuel supplier (Equilon, a joint venture between Shell and Texaco).

Ron Rohrbach; Gary Zulauf; Tim Gavin

2003-04-01T23:59:59.000Z

288

List View | Data.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

List View List View Safety Data/Tools Apps Challenges Resources Blogs Let's Talk Safety You are here Data.gov » Communities » Safety List View Interactive applications that visually display large datasets provide a portal to explore data and make discoveries. Federal agencies collect information on energy production, use, natural resources, and energy infrastructure logistics and this data can be used to create calculators, interactive maps, and other applications that leverage this data. These applications provide user communities the ability to highlight the energy issues that are occurring within their communities, aid businesses plan and analyze their proposed projects, and provide a baseline for analyzing how energy resources can be most optimally and efficiently used. This page

289

Availability of heavy fuel oils by sulfur levels, February 1981  

SciTech Connect (OSTI)

This monthly report includes a narrative analysis of the status of the United States' total new supply of heavy fuel oils, with an emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and Refinery Districts. Imports are given by PAD District, by country or origin, and by importing state. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. The December issue repeats the seven major tables with final data in all categories for the previous calendar year. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. 2 figs., 13 tabs.

Wolfrey, J.

1981-10-15T23:59:59.000Z

290

Availability of heavy fuel oils by sulfur levels, March 1981  

SciTech Connect (OSTI)

This monthly report includes a narrative analysis of the status of the United States' total new supply of heavy fuel oils, with an emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and Refinery Districts. Imports are given by PAD District, by country of origin, and by importing state. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. The December issue repeats the seven major tables with final data in all categories for the previous calendar year. This report was previously published by the Bureau of Mines in the Minerals Industries Survey Series under the same title. 2 figs., 13 tabs.

Wolfrey, J.

1981-10-15T23:59:59.000Z

291

Availability of heavy fuel oils by sulfur level, August 1981  

SciTech Connect (OSTI)

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and Refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterborne movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 1 figure, 14 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

292

Availability of heavy fuel oils by sulfur level, October 1981  

SciTech Connect (OSTI)

A narrative analysis of the status of the United States' total new supply of heavy fuel oils, is given with emphasis on sulfur levels. Tables detail refinery production, stocks, and imports of residual fuel oil and No. 4 fuel oil by sulfur content. All data except stock figures are reported on a monthly and on a year-to-date basis; stock data are reported on an end-of-current-month basis. Units of measure are thousands of barrels. Stocks held at refineries and bulk terminals and refinery production are given by Petroleum Administration for Defense (PAD) and refinery Districts. Imports are given by PAD District, by country of origin, and by importing State. Waterbone movements from PAD District III to other districts are detailed for the most recent month only. This report was previously published by the Bureau of Mines in the Minerals Industries Surveys Series under the same title. Publication was discontinued with the December 1981 issue. 1 figure, 14 tables.

Wolfrey, J.

1981-01-01T23:59:59.000Z

293

Extracellular iron-sulfur precipitates from growth of Desulfovibrio desulfuricans  

SciTech Connect (OSTI)

The authors have examined extracellular iron-bearing precipitates resulting from the growth of Desulfovibrio desulfuricans in a basal medium with lactate as the carbon source and ferrous sulfate. Black precipitates were obtained when D. desulfuricans was grown with an excess of FeSO{sub 4}. When D. desulfuricans was grown under conditions with low amounts of FeSO{sub 4}, brown precipitates were obtained. The precipitates were characterized by iron K-edge XAFS (X-ray absorption fine structure), {sup 57}Fe Moessbauer-effect spectroscopy, and powder X-ray diffraction. Both were noncrystalline and nonmagnetic (at room temperature) solids containing high-spin Fe(III). The spectroscopic data for the black precipitates indicate the formation of an iron-sulfur phase with 6 nearest S neighbors about Fe at an average distance of 2.24(1) {angstrom}, whereas the brown precipitates are an iron-oxygen-sulfur phase with 6 nearest O neighbors about Fe at an average distance of 1.95(1) {angstrom}.

Antonio, M. R.; Tischler, M. L.; Witzcak, D.

1999-12-20T23:59:59.000Z

294

Demonstration of Mixed Waste Debris Macroencapsulation Using Sulfur Polymer Cement  

SciTech Connect (OSTI)

This report covers work performed during FY 1997 as part of the Evaluation of Sulfur Polymer Cement Fast-Track System Project. The project is in support of the ``Mercury Working Group/Mercury Treatment Demonstrations - Oak Ridge`` and is described in technical task plan (TTP) OR-16MW-61. Macroencapsulation is the treatment technology required for debris by the U.S. Environmental Protection Agency Land Disposal Restrictions (LDR) under the Resource Conservation and Recovery Act. Based upon the results of previous work performed at Oak Ridge, the concept of using sulfur polymer cement (SPC) for this purpose was submitted to the Mixed Waste Focus Area (MWFA). Because of the promising properties of the material, the MWFA accepted this Quick Win project, which was to demonstrate the feasibility of macroencapsulation of actual mixed waste debris stored on the Oak Ridge Reservation. The waste acceptance criteria from Envirocare, Utah, were chosen as a standard for the determination of the final waste form produced. During this demonstration, it was shown that SPC was a good candidate for macroencapsulation of mixed waste debris, especially when the debris pieces were dry. The matrix was found to be quite easy to use and, once the optimum operating conditions were identified, very straightforward to replicate for batch treatment. The demonstration was able to render LDR compliant more than 400 kg of mixed wastes stored at the Oak Ridge National Laboratory.

Mattus, C.H.

1998-07-01T23:59:59.000Z

295

Wide field of view telescope  

DOE Patents [OSTI]

A wide field of view telescope having two concave and two convex reflective surfaces, each with an aspheric surface contour, has a flat focal plane array. Each of the primary, secondary, tertiary, and quaternary reflective surfaces are rotationally symmetric about the optical axis. The combination of the reflective surfaces results in a wide field of view in the range of approximately 3.8.degree. to approximately 6.5.degree.. The length of the telescope along the optical axis is approximately equal to or less than the diameter of the largest of the reflective surfaces.

Ackermann, Mark R. (Albuquerque, NM); McGraw, John T. (Placitas, NM); Zimmer, Peter C. (Albuquerque, NM)

2008-01-15T23:59:59.000Z

296

Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis  

E-Print Network [OSTI]

The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

Harris, E.

297

A composite material of uniformly dispersed sulfur on reduced graphene oxide: Aqueous one-pot synthesis, characterization and excellent performance as the cathode in rechargeable lithium-sulfur batteries  

Science Journals Connector (OSTI)

Sulfur-reduced graphene oxide composite (SGC) materials with uniformly dispersed sulfur on reduced graphene oxide sheets have been prepared by a ... the simultaneous oxidation of sulfide and reduction of graphene

Hui Sun; Gui-Liang Xu; Yue-Feng Xu; Shi-Gang Sun; Xinfeng Zhang

2012-10-01T23:59:59.000Z

298

Revolutionizing history education : using augmented reality games to teach histories  

E-Print Network [OSTI]

In an ever-changing present of multiple truths and reconfigured histories, people need to be critical thinkers. Research has suggested the potential for using augmented reality (AR) games- location-based games that use ...

Schrier, Karen L

2005-01-01T23:59:59.000Z

299

UCD School of History & Archives Student Handbook  

E-Print Network [OSTI]

UCD School of History & Archives Student Handbook 2014-2015 This handbook is relevant for all Students study history? Can Evening Arts students study history? How does the School of history School of History and Archives UCD: Student Handbook, 2014-15 2 #12;6. The ECTS credit system How are my

300

NEPA History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

History History NEPA History Selected documents providing historical information on NEPA. June 14, 2012 Federal Register Notices for DOE NEPA Guidelines and Regulations Historical compilation of Federal Register notices for DOE NEPA guidelines and regulations. December 31, 2009 Presidential Proclamation on the 40th Anniversary of the National Environmental Policy Act Proclamation of President Obama to "call upon all executive branch agencies to promote public involvement and transparency in their implementation of the National Environmental Policy Act." July 1, 1999 EPA's Section 309 Review: The Clean Air Act and NEPA This document discusses Section 309 of the Clean Air Act, which authorizes the Environmental Protection Agency to review certain proposed actions of

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Separation and Detection of Sulfur-Containing Anions Using Single-Column Ion Chromatography  

Science Journals Connector (OSTI)

......principal sulfur-containing anions in oil shale retort by-product waters are separated...electrochemical detection in some of the oil shale retort by-product water matrices...principal sulfur-containing anions in oil shale retort by-product waters are separated......

Richard E. Poulson; Harry M. Borg

1987-09-01T23:59:59.000Z

302

Quantitative Determination of Aliphatic Sulfur-Containing Additives by Pyrolysis-Gas Chromatography  

Science Journals Connector (OSTI)

......pyrolysis (7), infrared (8), combustion to SO4 = with subsequent determination...Drushel. The Analytical Chemistry of Sulfur and Its Compounds...London, p. 358. Sulfur in Coal and Coke by the Bomb Washing...organic materials by oxygen bomb combustion. Anal. Chem. 33:1760......

J.W. Sinclair; L. Schall; N.T. Crabb

1980-01-01T23:59:59.000Z

303

The sulfur content of volcanic gases on Mars Fabrice Gaillard, a  

E-Print Network [OSTI]

principles, we model here the likely sulfur contents of (1) the martian and terrestrial mantles and (2 a denser atmosphere are shown to be dominated by CO ± CO2 and H2 ± H2O species, depending on fO2, sulfur by H2S, which should have favored the acidification of any persistent water layer. The calculated

Boyer, Edmond

304

Evidence for a Plasma Core during Multibubble Sonoluminescence in Sulfuric Acid  

E-Print Network [OSTI]

.g., SOx, trace amounts of H2S, and elemental sulfur)7 are either highly soluble or solids. Prior MBSL to be problematic. These volatile products can have limited solubility in the liquid and therefore accumulate for the generation of higher temperatures during cavitation. Sulfuric acid is one such liquid because it has a very

Suslick, Kenneth S.

305

Linking Sulfur Metabolism to the Cell Division Machinery in Yeast  

E-Print Network [OSTI]

The longstanding view has been that metabolism allows for cell division to take place, but that metabolic processes do not actively promote cell division. I have recently challenged this notion by identifying a unique gain-of-function metabolic...

Blank, Heidi M.

2010-07-14T23:59:59.000Z

306

Toxicology Studies on Lewisite and Sulfur Mustard Agents: Subchronic Toxicity of Sulfur Mustard (HD) In Rats Final Report  

SciTech Connect (OSTI)

Occupational health standards have not been established for sulfur mustard [bis(2- chlorethyl)-sulfide], a strong alkylating agent with known mutagenic properties. Seventytwo Sprague-Dawley rats of each sex, 6-7 weeks old, were divided into six groups (12/group/ sex) and gavaged with either 0, 0.003 , 0.01 , 0.03 , 0.1 or 0.3 mg/kg of sulfur mustard in sesame oil 5 days/week for 13 weeks. No dose-related mortality was observed. A significant decrease (P ( 0.05) in body weight was observed in both sexes of rats only in the 0.3 mg/kg group. Hematological evaluations and clinical chemistry measurements found no consistent treatment-related effects at the doses studied. The only treatment-related lesion associated with gavage exposure upon histopathologic evaluation was epithelial hyperplasia of the forestomach of both sexes at 0.3 mg/kg and males at 0.1 mg/kg. The hyperplastic change was minimal and characterized by cellular disorganization of the basilar layer, an apparent increase in mitotic activity of the basilar epithelial cells, and thickening of the epithelial layer due to the apparent increase in cellularity. The estimated NOEL for HD in this 90-day study is 0.1 mg/kg/day when administered orally.

Sasser, L. B.; Miller, R. A.; Kalkwarf, D, R.; Buschbom, R. L.; Cushing, J. A.

1989-06-30T23:59:59.000Z

307

Limited View Angle Iterative CT Reconstruction  

E-Print Network [OSTI]

;Some Prior Literature in Limited View Tomography CT with limited-angle data and few views IRR algorithm Iterative Reconstruction-Reprojection (IRR) : An Algorithm for Limited Data Cardiac- Computed-views and limited-angle data in divergent-beam CT by E. Y. Sidky, CM Kao, and X. Pan (2006) Few-View Projection

308

Population, Economy and Energy Uses Influence on Sulfur Emissions in the United States Since 1900  

E-Print Network [OSTI]

This paper seeks to identify how changes in population, economic activity, and energy use have influenced sulfur emissions during this century. A linear model is presented which characterizes sulfur emissions as the product of these driving forces...

Kissock, J. K.; Husar, R. B.

309

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation  

E-Print Network [OSTI]

The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

310

Census and viewing of organisms  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Census and viewing of organisms Census and viewing of organisms Name: m hariaczyi Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: How many organisms exist in the world today? What is the most powerful microscope that could be used for viewing organism? Replies: The most powerful microscope is called an electron microscope, which can be used for viewing entire organisms, although few organisms are small enough to see all of them at high magnifications allowed by this microscope. So most often its used to look at fixed sections of organisms. Since the electron microscope only works in a vacuum, with no air, you cannot look at live organisms. To do that, probably the most powerful microscope is called a Nomarski, or in technical terms, a "differential interference contrast" microscope. This is a modification of a normal light microscope that allows better contrast in living tissue. It is not any more powerful than a light microscope, and is much less powerful than an electron microscope, but it allows you to see living things much better.

311

View  

Science Journals Connector (OSTI)

Mn, the concentration gradient that drives the diffusion is maintained by the precipitation of insoluble oxides. In the case of Cd, ... Cientifica e Tecnologica (

2000-10-07T23:59:59.000Z

312

View  

E-Print Network [OSTI]

May 18, 2012 ... bottleneck, long-time production simulations will be severely hampered ...... t 0.975, (g) t 1.0, (h) t 1.025, (i) t 1.275, (j) t 1.525, (k) t ...

S. Dong

2012-06-21T23:59:59.000Z

313

View  

E-Print Network [OSTI]

In order to increase the search capability of MBH, a population framework has been proposed ... The key idea is to avoid new individuals to enter the population if someone similar (in a ..... We measure the efficiency in terms of number of (two-.

andrea,,,

314

View  

E-Print Network [OSTI]

May 31, 2005 ... Robert M. Freund: MIT Sloan School of Management, 50 Memorial Drive, Cambridge, Massachusetts 02139-4307, ...... the transition kernel.

2005-05-30T23:59:59.000Z

315

View  

Science Journals Connector (OSTI)

89-l 1268) ran the carbon analysis of the sediment trap material ..... vehicle camera system were analyzed with a ... tribution of distances with the computer pro-.

1999-12-21T23:59:59.000Z

316

View  

E-Print Network [OSTI]

obtained by using different uncertainty sets estimated using simulated and ... Given a fixed mix of electric power plants (nuclear, thermal, hydroelectric, and...

2011-01-28T23:59:59.000Z

317

View  

E-Print Network [OSTI]

Aug 19, 2009 ... linear-algebraic and graph theoretic properties of this matrix class. The con- ..... The MatLab solvers linprog and quadprog were used.

2010-03-14T23:59:59.000Z

318

View  

E-Print Network [OSTI]

Mar 14, 2006 ... ... of the paper is devoted to the development of background material for ..... Note that the optimization problem in the correction phase is solved over ...... In Phase I

2006-03-31T23:59:59.000Z

319

View  

E-Print Network [OSTI]

Mar 1, 2007 ... 2The logarithmic barrier for the half space {u ? Rn | a u ? b} is ..... in the Uncapacitated Falicity Location Library (UflLib) [Hoe06]. .... For our test we use 36 unsolved UFL instances that come from two public sets of instances.

2007-03-01T23:59:59.000Z

320

View  

E-Print Network [OSTI]

cT w tj (cj z) + o (1) = wti (z) + o (1), since c-Ow(cz) = w(z) for any w E W and c > 0. We have obtained a contradiction with (2.29), which proves (2.28). If w t = w('...

2004-12-25T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

View  

Science Journals Connector (OSTI)

Apr 15, 1976 ... terms of Hairston's hypothesis, to find that only the ... be a component of the search by grazers .... to stop searching and to enter into a state.

2000-01-05T23:59:59.000Z

322

View  

E-Print Network [OSTI]

which has a 0 infimum, but does not attain it. Here the certificates of the bad behavior of the system in (3.32) are. Z = (. 1 0. 0 0. ) , V = (. 0 1. 1 0. ) . Example 2.

2014-05-14T23:59:59.000Z

323

View  

E-Print Network [OSTI]

1. Introduction. The purpose of the present paper is to develop some new directions of investigation in ..... For each i = 1, ..., m, and g = (x1, ..., xr,mr ), we have.

2003-09-25T23:59:59.000Z

324

View  

E-Print Network [OSTI]

Definition 1 The persistency of a variable xi is defined to be the probability that xi = 1 in the ..... i , we know a limited set of marginal moments mr i . We let ?...

2005-04-19T23:59:59.000Z

325

View  

E-Print Network [OSTI]

In [4], Devinatz, Hopkins, and Smith proved the nilpotence theorem, a remark- able result which provides algebraic means for detecting nilpotence in the...

1997-12-15T23:59:59.000Z

326

View  

Science Journals Connector (OSTI)

carbon (C) and increased mixing energies, making CO, limitation less likely. .... Verde Reef (Vera Cruz, Mexico). ..... solar energy is more important in deter-.

2000-03-03T23:59:59.000Z

327

View  

E-Print Network [OSTI]

Sep 3, 2003 ... Superconductors are able to carry equilibrium currents without resistance. .... by an Ohm's law where ? is the electric conductivity and b1 is a...

1910-31-00T23:59:59.000Z

328

Viewed  

Science Journals Connector (OSTI)

Oct 27, 1982 ... study area does not contain indigenous io- .... Zn Handbook ofgeochemistry. V. 7, part 4. Spring ... Lakes-physics, chemistry, geology. Springer.

2000-02-09T23:59:59.000Z

329

View  

Science Journals Connector (OSTI)

This lake is in the Kigezi Highlands, western Uganda, in a narrow steep-sided branching river valley about 20 km long that has been dammed and drowned by a.

Orcas

330

View  

Science Journals Connector (OSTI)

1943. Treatment of experimental data. Wiley,. New York, N.Y. 344 p. ZIIIN-ELDIN, Z. P. 1961. Plankton pigments in. East Lagoon, Galveston, Texas. Trans. Am.

Orcas

331

View  

E-Print Network [OSTI]

GLEV train, a new bullet train under development in Japan, is formulated as the ... conservation law and v ? c represents a constraint on the maximum capacity at each ... Railways Technical Research Institute, Kokubunji, Tokyo 185-8540 Japan ... optimization since 1984 when Karmarkar proposed the projective scaling...

2002-10-31T23:59:59.000Z

332

View  

E-Print Network [OSTI]

the random consequences of the chosen action, h(x, ?), are preferred to those of a baseline random variable Z for all utility ...... Ground truth. Envelope. Figure 3:...

2012-06-29T23:59:59.000Z

333

View  

E-Print Network [OSTI]

A major challenge in using optimization to make risk-averse decisions in the face of uncertainty is how to specify an acceptable level of risk. Recently, Dentcheva...

2011-06-22T23:59:59.000Z

334

View  

E-Print Network [OSTI]

maximum acceptable risk that one is willing to take. ... of initial wealth allocated to the assets, CVaR?(?T x) measures the risk of a given allocation x, b. 1...

2009-03-26T23:59:59.000Z

335

View  

E-Print Network [OSTI]

acceptable level of risk. As shown in [2], Problem (3) is a difficult, in fact NP-hard, combinatorial problem. Following [17] and [21], we choose to tackle it by...

2010-02-08T23:59:59.000Z

336

View  

E-Print Network [OSTI]

allowed to be violated an acceptable amount of time. There are no ... optimal investment strategies with a certain level of risk [10]. Up to this point most research...

2008-05-24T23:59:59.000Z

337

View  

E-Print Network [OSTI]

in the primal problem. As it can be seen by the number of floating point operations needed to generate the approximation to the set of efficient points, the strategy.

338

View  

E-Print Network [OSTI]

Oct 29, 2008 ... serial machine in floating point is well below our needs. 3 Notation. We are given an m d design matrix P of floating point numbers and an.

2008-10-28T23:59:59.000Z

339

View  

E-Print Network [OSTI]

function, and the nuclear norm. The support function is based on the graph of the product of a matrix with its transpose. Closed form expressions for the support...

2014-08-28T23:59:59.000Z

340

View  

E-Print Network [OSTI]

the results of [8] to obtain, for each natural number n, a simple nuclear C?- algebra An whose ordered K0-group is order isomorphic to Zn. This result was further...

2008-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

View  

E-Print Network [OSTI]

the UCT and reproves Huaxin Lin's theorem on the classification of nuclear tracially AF ... A deep conjecture of Elliott asserts that the simple separable nuclear...

2004-06-29T23:59:59.000Z

342

View  

E-Print Network [OSTI]

Q we have yi = Gdi and the Gorthogonality condition of vectors si, si+1 can be written as ?isT i Gsi+1 = yT i si+1 = 0 (we assume that ?i = 0). This together with...

2009-03-10T23:59:59.000Z

343

View  

E-Print Network [OSTI]

job Ji is a function of its completion time, usually denoted by Ci. ..... For any t > max(P, d), there exists a value ? > 0 and a job index i? ? {1,...,n} such that, for any...

2006-03-29T23:59:59.000Z

344

View  

E-Print Network [OSTI]

Feb 28, 2006 ... Abstract. The major focus of this work is to compare several methods for computing the proximal point of a nonconvex function via numerical...

2006-02-28T23:59:59.000Z

345

View  

E-Print Network [OSTI]

Our original motivating application is in Electronics and arises in the development of pulse ...... In 8th International Symposium on Fundamentals of Computa-.

Christoph Buchheim,,,

346

View  

E-Print Network [OSTI]

Feb 28, 2012 ... and P. Dorta-Gonzlez. Departamento de Mtodos Cuantitativos en Econom?a y Gestin. Universidad de Las Palmas de Gran Canaria (Spain).

2012-02-28T23:59:59.000Z

347

DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur  

Broader source: Energy.gov (indexed) [DOE]

DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate February 1, 2011 - 12:00pm Addthis Washington, DC - The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy (DOE) said today. The State of New York and other Northeastern states are implementing more stringent fuel standards that require replacement of high sulfur (2,000 parts per million) heating oil to ultra low sulfur fuel (15 parts per million). As a result, DOE will sell the current inventory of the Northeast

348

DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur  

Broader source: Energy.gov (indexed) [DOE]

Will Convert Northeast Home Heating Oil Reserve to Ultra Low Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate February 1, 2011 - 12:00pm Addthis Washington, DC - The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy (DOE) said today. The State of New York and other Northeastern states are implementing more stringent fuel standards that require replacement of high sulfur (2,000 parts per million) heating oil to ultra low sulfur fuel (15 parts per million). As a result, DOE will sell the current inventory of the Northeast Home Heating Oil Reserve, a total of approximately 2 million barrels, and

349

Direct determination of organic and inorganic sulfur in coal by controlled oxidation  

SciTech Connect (OSTI)

The overall objective of this project is to develop an analytical method to directly measure the forms of organic sulfur in coal. The method will provide a route to monitor the effectiveness of coal preparation research directed toward removal of organic sulfur in coal. The approach involves subjecting diluted coal samples simultaneously to an oxygen flow and a linear increase in temperature. Distinctive sulfur dioxide evolution patterns are observed among coals of different rank and between raw and treated coals. Assignments have been made relating each specific sulfur dioxide evolution to the non-aromatic organic, aromatic organic, and inorganic sulfur present in coals and treated coals. Work is progressing on schedule to optimize experimental conditions and to improve the efficiency of the controlled-atmosphere programmed-temperature oxidation (CAPTO) method by developing a multiple sample instrumental system.

LaCount, R.B.

1992-01-01T23:59:59.000Z

350

Direct determination of organic and inorganic sulfur in coal by controlled oxidation  

SciTech Connect (OSTI)

The overall objective of this project is to develop an analytical method to directly measure the forms of organic sulfur in coal. The method will provide a route to monitor the effectiveness of coal preparation research directed toward removal of organic sulfur in coal. The approach involves subjecting diluted coal samples simultaneously to an oxygen flow and a linear increase in temperature. Distinctive sulfur dioxide evolution patterns are observed among coals of different rank and between raw and treated coals. Assignments have been made relating each specific sulfur dioxide evolution to the non-aromatic organic, aromatic organic, and inorganic sulfur present in coals and treated coals. Work is progressing on schedule to optimize experimental conditions and to improve the efficiency of the controlled-atmosphere programmed-temperature oxidation (CAPTO) method by developing a multiple sample instrumental system.

LaCount, R.B.

1992-12-31T23:59:59.000Z

351

EM History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

EM History EM History EM History Before (left) and after (right) photos of the Hanford site's F Reactor during operations in 1956 and in 2012, when EM and its contractors completed cleanup there. It was the first reactor area at the 586-square-mile Hanford site to be fully remediated. Before (left) and after (right) photos of the Hanford site's F Reactor during operations in 1956 and in 2012, when EM and its contractors completed cleanup there. It was the first reactor area at the 586-square-mile Hanford site to be fully remediated. EM's HISTORY (1989 - present) Fifty years of nuclear weapons production and energy research generated millions of gallons of liquid radioactive waste, millions of cubic meters of solid radioactive wastes, thousands of tons of spent nuclear fuel and

352

Our History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

History History Our History Elk Hills Naval Petroleum Reserve Circa 1920s Elk Hills Naval Petroleum Reserve Circa 1920s The Office of Fossil Energy has the longest directly-traceable history of any organization in the Department of Energy. While the nuclear energy program can look back to the Manhattan Project of World War II for its origins, the Federal Government's involvement in fossil fuel resources began several decades earlier, in the early 1900s. Oil Dominates Early Concerns The U.S.S. Colorado, Maryland, and West Virginia off the coast of California during the 1920's. The West Virginia was one of the first oil-burning ships. Much as today, petroleum was a major concern for the Federal Government at the start of the 20th century. Barely 50 years after the birth of the

353

HFIR History - ORNL Neutron Sciences  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Home › Facilities › HFIR › History Home › Facilities › HFIR › History History of HFIR HFIR was constructed in the mid-1960s to fulfill a need for the production of transuranic isotopes (i.e., "heavy" elements such as plutonium and curium). Since then its mission has grown to include materials irradiation, neutron activation, and, most recently, neutron scattering. In 2007, HFIR completed the most dramatic transformation in its 40-year history. During a shutdown of more than a year, the facility was refurbished and a number of new instruments were installed, as well as a cold neutron source. The reactor was restarted in mid-May; it attained its full power of 85 MW within a couple of days, and experiments resumed within a week. Improvements and upgrades to HFIR include an overhaul of the

354

Center for the history of chemistry resources  

Science Journals Connector (OSTI)

Center for the history of chemistry resources ... A note alerting those interested in the histories of chemistry, chemical engineering, and chemical process industries to the resources available from the Center for the History of Chemistry. ... Chemical Engineering ...

Bruce V. Lewenstein

1988-01-01T23:59:59.000Z

355

Effect of Sulfur Compounds and Higher Homologues of Methane on Hydrogen Cyanide Production by the Andrussow Method  

Science Journals Connector (OSTI)

The influence of sulfur compounds, higher homologues of methane on the parameters ofoxidative ammonolysis of methane was studied.

N. V. Trusov

2001-10-01T23:59:59.000Z

356

Sulfur dioxide and nitrogen dioxide levels inside and outside homes and the implications on health effects research  

Science Journals Connector (OSTI)

Sulfur dioxide and nitrogen dioxide levels inside and outside homes and the implications on health effects research ...

John D. Spengler; Benjamin G. Ferris Jr.; Douglas W. Dockery; Frank E. Speizer

1979-10-01T23:59:59.000Z

357

A History Of Hot Dry Rock Geothermal Energy Systems | Open Energy  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » A History Of Hot Dry Rock Geothermal Energy Systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A History Of Hot Dry Rock Geothermal Energy Systems Details Activities (1) Areas (1) Regions (0) Abstract: This is a short history, so far as it can now be assembled, of early speculations and observations concerning the existence and origin of natural heat in the earth's crust; of some of the many methods proposed to extract and use it; and of recent investigations designed to develop and demonstrate such methods. It is probably only the preface to a much longer

358

Effects of Sulfur Dioxide on Formation of Fishy Off-Odor and Undesirable Taste in Wine Consumed with Seafood  

Science Journals Connector (OSTI)

Effects of Sulfur Dioxide on Formation of Fishy Off-Odor and Undesirable Taste in Wine Consumed with Seafood ... These results suggest that sulfur dioxide in wine participated in degradation of unsaturated fatty acids, causing an increase in undesirable taste and fishy off-odor in wine and seafood pairings. ... Wine; seafood; fishy off-odor; undesirable taste; unsaturated fatty acids; sulfur dioxide ...

Akiko Fujita; Atsuko Isogai; Michiko Endo; Hitoshi Utsunomiya; Shigeyoshi Nakano; Hiroshi Iwata

2010-03-10T23:59:59.000Z

359

Hanford Natural Resource Trustee Council History & Accomplishments...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Resource Trustee Council > HNRTC History & Accomplishments About Us Hanford Natural Resource Trustee Council HNRTC Members HNRTC History & Accomplishments Memorandum of...

360

History of Hydropower | Department of Energy  

Energy Savers [EERE]

History of Hydropower History of Hydropower Humans have been harnessing water to perform work for thousands of years. The Greeks used water wheels for grinding wheat into flour...

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

UC land grants: A photo history  

E-Print Network [OSTI]

Berkeley UC land grants: A photo history D Early days: 1862UCR/CMP UC land grants: A photo history H. In 1987, UC

Editors, By

2012-01-01T23:59:59.000Z

362

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

The work completed this past quarter has centered around the further study and characterization of the selective desulfurization of coal through the oxidative interaction of aqueous copper chloride. The reaction of the CuCl{sub 2} with the particular model compounds is conducted at a series of reaction times and reaction temperatures. The reaction times studied were 1, 3, 6, 12, and 24 hours. The reaction temperatures studied were 50, 130, 210, and 295{degree}C. After the reaction, the organic compounds were extracted with methylene chloride. These products were then analyzed via GC/IRD/MS and SFC/SCD (sulfur chemiluminescence detector). Model Coal Compounds reacted include: tetrahydrothiophene, methyl p-tolyl sulfide, cyclohexyl mercaptan, and thiophenol. At 130{degree}C, in addition to these compounds reacting, reactions were also detected for phenyl sulfide and benzo(b)thiophene. 14 figs.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

363

On the history of multi-particle production in high energy collisions  

E-Print Network [OSTI]

The 60th birthday of Johann Rafelski was celebrated during the Strangeness in Quark Matter 2011 in Krakow. Johann was born in Krakow and he initiated the series of the SQM conferences. This report, which briefly presents my personal view on a history of multi-particle production in high energy collisions, is dedicated to Johann.

M. Gazdzicki

2012-01-02T23:59:59.000Z

364

Three-Dimensional Flower-Shaped Activated Porous Carbon/Sulfur Composites as Cathode Materials for LithiumSulfur Batteries  

Science Journals Connector (OSTI)

After the active sulfur impregnation, both the FESEM images (Figure 1e,f) and TEM images (Figure 2c) of the FA-PC/S composite demonstrate a flower-shaped 3D superstructure similar to the original FA-PC material. ... Early on, carbonaceous materials dominated the anode and hence most of the possible improvements in the cell were anticipated at the cathode terminal; on the other hand, major developments in anode materials made in the last portion of the decade with the introduction of nanocomposite Sn/C/Co alloys and Si-C composites have demanded higher capacity cathodes to be developed. ... The photodecompn. of methyl orange indicates that such ZnO superstructures possess excellent photocatalytic activity. ...

Lan Zhou; Tao Huang; Aishui Yu

2014-09-19T23:59:59.000Z

365

A new view of avian life-history evolution tested on an incubation paradox  

Science Journals Connector (OSTI)

...Aging physiology Animals Argentina Arizona Biological Evolution...phylogenetically and ecologically between Argentina and Arizona are longer in Argentina. Long incubation periods...Williams 1996) and increased energy expenditure can increase mortality...

2002-01-01T23:59:59.000Z

366

A history of resistance to privatization in Russia  

Science Journals Connector (OSTI)

Abstract We investigate the connection between privatization in post-communist Russia and a mass privatization reform in Imperial Russia, the 1906 Stolypin land reform. Specifically, we relate historical measures of conflicts associated with the Stolypin reform to contemporary views on whether the privatization of the 1990s should be revised. These historical measures could influence contemporary views in two ways: first, differences in privatization-related conflicts in the past could have directly altered attitudes towards privatization in the 1990s and, second, these differences could merely reflect pre-determined dissimilarities in preferences. We first show that historical measures of resistance to privatization are associated with views that favor state ownership. One standard deviation increase in the historical resistance to privatization explains a quarter of the negative sentiment toward private property today. We also find that negative experiences with the Stolypin reform are associated with views on the procedural unfairness of modern privatization reforms, suggesting that pre-determined preferences cannot fully explain the weight of history.

Paul Castaeda Dower; Andrei Markevich

2014-01-01T23:59:59.000Z

367

Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sequestering Carbon Dioxide and Sulfur Dioxide Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,922,792 entitled "Method for Sequestering Carbon Dioxide and Sulfur Dioxide Utilizing a Plurality of Waste Streams." Disclosed in this patent is the invention of a neutralization/sequestration method that concomitantly treats bauxite residues from aluminum production processes, as well as brine wastewater from oil and gas production processes. The method uses an integrated approach that coincidentally treats multiple industrial waste by-product streams. The end results include neutralizing caustic

368

Method of making a current collector for a sodium/sulfur battery  

DOE Patents [OSTI]

This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

1987-03-10T23:59:59.000Z

369

The effect of sulfate sulfur on the yield and chemical composition of oats, vetch, and turnips  

E-Print Network [OSTI]

with sulfur and gypsum applications to alfalfa in Washington and Oregon. Subsequent vork showed that a large part of the ali'alfa land in Oregon vas deficient in sulfur. Experiments conducted over a period of several years on various soil types in southern... Oregon showed that, yields of ali'alf'a and cover crops could be increased from 50 percent to 1000 percent by the use of various fertilissrs containing sulfur (35). Other workers in Oregon ob- tained similar results with crops other than legumes...

Gipson, Jack Rogers

2012-06-07T23:59:59.000Z

370

Energy Dispersive X-ray Fluorescence Analysis of Sulfur in Biomass  

Science Journals Connector (OSTI)

An energy dispersive X-ray fluorescence (ED-XRF) spectroscopy method was developed to analyze low ppm level sulfur (S) in biomass feedstocks and in subsequent residues from pretreatment reactions. ... Representative biomass feedstocks and pretreatment residues were analyzed for S. ... The goal of this project was to determine whether an energy dispersive X-ray fluorescence (ED-XRF) spectroscopy method is effective in conducting sulfur analysis of woody biomass feedstocks at an appropriately useful sensitivity, especially when used to effectively monitor the extent of sulfur removal after biomass pretreatment reactions. ...

J. Michael Robinson; Staci R. Barrett; Kevin Nhoy; Rajesh K. Pandey; Joseph Phillips; Oscar M. Ramirez; Richard I. Rodriguez

2009-03-06T23:59:59.000Z

371

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

372

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

373

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

374

Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)  

Reports and Publications (EIA)

On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

2006-01-01T23:59:59.000Z

375

Bartlesville History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bartlesville History Bartlesville History Bartlesville History The Bartlesville Energy Technology Center, Bartlesville, Oklahoma, circa 1937. The Bartlesville Energy Technology Center, Bartlesville, Oklahoma, circa 1937. Origins of the U.S. Government's First Petroleum Research Laboratory By 1916 the Bureau of Mines, which had been established six years earlier in the U.S. Department of the Interior, recognized the transforming role that petroleum was playing in American society. Across the country, the Bureau had begun establishing experiment stations, each specializing in a different extraction industry - coal, metals, clay, and other minerals - and each located close to the major centers of each resource. Now, the Bureau announced its intent to establish a petroleum experiment station

376

APS USER TRAINING HISTORY Background  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

USER TRAINING HISTORY USER TRAINING HISTORY Background The User Program Division Director has delegated to the CATs the authority to authorize the conduct of experiments because the CATs have accepted responsibility for: * identifying and evaluating the hazards posed by the experiment, * specifying controls appropriate to the hazards, and * verifying that controls are in place. One form of hazard control frequently made mandatory by law and laboratory policy is worker knowledge. The accepted means of verifying that a worker has the required knowledge is ensuring that the worker has completed appropriate training. With CAT input, the APS has developed the APS User Training History. This web-based tool enables designated CAT personnel to examine data characterizing ES&H training courses

377

FTCP History | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

History History FTCP History In 1993, the Board issued Recommendation 93-3, Improving DOE Technical Capability in Defense Nuclear Facilities. This recommendation resulted in DOE's establishing the Federal Technical Capability Panel (FTCP) and developing two noteworthy standards: DOE M 426.1-1, Federal Technical Capability Manual, and DOE G 426.1-1, Recruiting, Hiring, and Retaining High Quality Technical Staff: A Manager's Guide to Administrative Flexibilities. These standards provide techniques and processes for improving the recruitment, retention, training, and qualification of high-quality personnel. Board Recommendation 93-3 was issued on June 1, 1993, and accepted by the Department of Energy on July 23, 1993. The Recommendation discussed the need to improve the technical capability of federal employees associated

378

NICMOS HISTORY DATABASE AND April 10, 1998  

E-Print Network [OSTI]

1 NICMOS HISTORY DATABASE AND WEB TOOLS C. Tullos April 10, 1998 ABSTRACT The history of NICMOS. The Database and Data A convenient way of keeping a history of some of the NICMOS instrument parameters parameters apply. Instrument Science Report OSG-CAL 98-01 #12;2 NICMOS HISTORY DATABASE LAYOUT 2. The Web

Sirianni, Marco

379

Laboratory automation-A case history  

Science Journals Connector (OSTI)

Laboratory automation-A case history ... This article describes an automated Raman spectrometer. ...

Bernard J. Bulkin; Edward H. Cole; Arthur Noguerola

1974-01-01T23:59:59.000Z

380

UCD School of History & Archives Student Handbook  

E-Print Network [OSTI]

UCD School of History & Archives Student Handbook 2013-2014 This handbook is relevant for all of History and Archives UCD: Student Handbook, 2013-2014 2 Table of Contents 1: Introduction and welcome from Evening Arts students study history? How does the School of history and Archives communicate with its

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Better Buildings Network View | November 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

382

Better Buildings Network View | October 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

383

Better Buildings Network View | September 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

384

Better Buildings Network View | January 2015  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

385

Better Buildings Network View | December 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

386

The Better Buildings Neighborhood View- Fall 2011  

Broader source: Energy.gov [DOE]

Better Buildings Neighborhood View, from the Better Buildings Neighborhood Program of the U.S. Department of Energy.

387

Better Buildings Network View | February 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

388

California's Energy Future - The View to 2050  

E-Print Network [OSTI]

Energy Future - The View to 2050 Bin Biofuel Technology Hydrogen Ethanol from sugar and starch (e.g. , corn,

2011-01-01T23:59:59.000Z

389

The Better Buildings Neighborhood View- July 2012  

Broader source: Energy.gov [DOE]

The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program.

390

Better Buildings Network View | April 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

391

Better Buildings Network View | May 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

392

Better Buildings Network View | March 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

393

Better Buildings Network View | June 2014  

Broader source: Energy.gov [DOE]

The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

394

Secondary Capture of Chlorine and Sulfur during Thermal Conversion of Biomass  

Science Journals Connector (OSTI)

Secondary Capture of Chlorine and Sulfur during Thermal Conversion of Biomass ... Six biomasses with different chemical compositions ... ... Therefore, different types of woody biomass and biomass residues (shells) were thermochemically converted in an atmospheric flow ... ...

Jacob N. Knudsen; Peter A. Jensen; Weigang Lin; Kim Dam-Johansen

2005-02-10T23:59:59.000Z

395

Structural analysis of sulfur in natural rubber using X-ray absorption near-edge spectroscopy  

Science Journals Connector (OSTI)

The opportunity to employ X-ray absorption near-edge spectroscopy techniques to investigate the alteration of the structural properties of sulfur in various vulcanized rubber sheets is presented.

Pattanasiriwisawa, W.

2008-07-11T23:59:59.000Z

396

Cost-benefit analysis of ultra-low sulfur jet fuel  

E-Print Network [OSTI]

The growth of aviation has spurred increased study of its environmental impacts and the possible mitigation thereof. One emissions reduction option is the introduction of an Ultra Low Sulfur (ULS) jet fuel standard for ...

Kuhn, Stephen (Stephen Richard)

2010-01-01T23:59:59.000Z

397

Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and...  

Gasoline and Diesel Fuel Update (EIA)

EIA-782B, "Resellers'Retailers' Monthly Petroleum Product Sales Report." 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type Energy Information Administration ...

398

E-Print Network 3.0 - aromatic sulfur compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . It has been also shown that most of the sulfur compounds in oil shale are...

399

Infrared and Raman Spectra of a Sulfur-resistant Methanation Catalyst  

Science Journals Connector (OSTI)

The infrared and Raman spectra of a sulfur-resistant NiO/Cr2O3/MgSiO3 methanation catalyst are presented and compared to the spectra of the catalyst...

Stencel, J M; Bradley, E B; Brown, Fred R

1980-01-01T23:59:59.000Z

400

Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Data Report No. 1  

SciTech Connect (OSTI)

The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim data report summarizes results as of August, 1999, on the status of the test programs being conducted on three technologies: lean-NO{sub x} catalysts, diesel particulate filters and diesel oxidation catalysts.

DOE; ORNL; NREL; EMA; MECA

1999-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India  

E-Print Network [OSTI]

High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

Chatterjee, A.

402

Effective hydrogen generation and resource circulation based on sulfur cycle system  

SciTech Connect (OSTI)

For the effective hydrogen generation from H{sub 2}S, it should be compatible that the increscent of the photocatalytic (or electrochemical) activities and the development of effective utilization method of by-products (poly sulfide ion). In this study, system integration to construct the sulfur cycle system, which is compatible with the increscent of the hydrogen and or electron energy generation ratio and resource circulation, is investigated. Photocatalytic hydrogen generation rate can be enhanced by using stratified photocatalysts. Photo excited electron can be transpired to electrode to convert the electron energy to hydrogen energy. Poly sulfide ion as the by-products can be transferred into elemental sulfur and/or industrial materials such as rubber. Moreover, elemental sulfur can be transferred into H{sub 2}S which is the original materials for hydrogen generation. By using this system integration, the sulfur cycle system for the new energy generation can be constructed.

Takahashi, Hideyuki; Mabuchi, Takashi; Hayashi, Tsugumi; Yokoyama, Shun; Tohji, Kazuyuki [Graduate School of Environmental Studies, Tohoku University 6-6-20, Aramaki, Aoba-ku, Sendai, 980-8579 (Japan)

2013-12-10T23:59:59.000Z

403

Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage  

Broader source: Energy.gov [DOE]

General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power...

404

Electronic Transitions in Sulfur-Centered Radicals by Means of MSX? Calculations  

Science Journals Connector (OSTI)

Highly reactive sulfur-centered radicals, which play an important role in air pollution and in biological systems, are usually idientified by their UV/visible absorption and/or ESR spectra. Spectral informatio...

Maurizio Guerra

1990-01-01T23:59:59.000Z

405

History and philosophy of psychology  

Science Journals Connector (OSTI)

... not a rehash job, for it covers many topics in the history and philosophy of psychology of which most self-respecting Anglo-Saxon psychologists are entirely innocent. This is not ... , know what is meant by phenomenology, and understand the strengths and weaknesses of Gestalt psychology. All in all, Thines' choice of topics is excellent and their range impressive. ...

William Barnes-Gutteridge

1978-03-16T23:59:59.000Z

406

HISTORY OF PSYCHOLOGY Psychology 805  

E-Print Network [OSTI]

1 HISTORY OF PSYCHOLOGY Psychology 805 Department of Psychology Michigan State University Spring, 2011 Class meeting times: Tuesday, Thursday, 12:40-2:30 p.m. Place: 119 Psychology Building Instructor: L.J. Harris Office: 217 Psychology Building Office Hours: Mondays, 3:00 - 5 p.m.; other times

Liu, Taosheng

407

HISTORY OF PSYCHOLOGY Psychology 805  

E-Print Network [OSTI]

1 HISTORY OF PSYCHOLOGY Psychology 805 Department of Psychology Michigan State University Fall, 2012 Class meeting times: Tuesday, Thursday, 12:40-2:30 p.m. Place: 120 Psychology Building Instructor: L.J. Harris Office: 217 Psychology Building Office Hours: Mondays, 3:00 - 5 p.m.; other times

Liu, Taosheng

408

History of federal transportation policy  

E-Print Network [OSTI]

History of federal transportation policy TTP 220 S. Handy 4/7/14 #12;Federal Transportation Policy · Rise of road building (1910s +) · Rise of mandated planning (1960s +) · Rise of transit funding (1960s for road building support from the start! · Cars seen as way to decentralize, to get people away from ills

Handy, Susan L.

409

The history of the LHC  

ScienceCinema (OSTI)

Abstract: From the civil engineering, to the manufacturing of the various magnet types, each building block of this extraordinary machine required ambitious leaps in innovation. This lecture will review the history of the LHC project, focusing on the many challenges -- scientific, technological, managerial -- that had to be met during the various phases of R&D;, industrialization, construction, installation and commissioning.

None

2011-10-06T23:59:59.000Z

410

Invited paper History of Semiconductors  

E-Print Network [OSTI]

AbstractThe history of semiconductors is presented beginning with the first documented observation of a semiconductor effect (Faraday), through the development of the first devices (point-contact rectifiers and transistors, early field-effect transistors) and the theory of semiconductors up to the contemporary devices (SOI and multigate devices). Keywordsband theory, laser, Moores law, semiconductor, transistor.

Lidia ?ukasiak; Andrzej Jakubowski

411

Economic History Revisited: New Uncertainties  

E-Print Network [OSTI]

to the southern and midwestern regions of the United States. However, the large run-up in oil prices is increasingEconomic History Revisited: New Uncertainties I n the last Sitar-Rutgers Regional Report, we are paying ever-increasing prices for fewer available sites. Warehouse sites in the southern portion

412

US Energy Service Company Industry: History and Business Models  

Office of Energy Efficiency and Renewable Energy (EERE)

Information about the history of US Energy Service Company including industry history, setbacks, and lessons learned.

413

Earth Repair: A Transatlantic History of Environmental Restoration  

E-Print Network [OSTI]

Earth Repair: A Transatlantic History of EnvironmentalHall. Earth Repair: A Transatlantic History of Environmental

Hamilton-Smith, Elery

2006-01-01T23:59:59.000Z

414

Physicochemical aspects of the adsorption of sulfur dioxide by carbon adsorbents  

Science Journals Connector (OSTI)

Literature data on the chemistry of the adsorption of sulfur dioxide on carbon adsorbents are surveyed and described systematically. The influence of various factors (the nature of the carbon matrix, the activation method, the chemistry of the adsorbent surfaces, temperature, the composition of the gas stream, etc.) on the sorption of SO2 by activated carbons and semicokes is examined. The possible ways in which sulfur dioxide interacts with the carbon surface are discussed. The bibliography includes 128 references.

Sergey A Anurov

1996-01-01T23:59:59.000Z

415

Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation  

E-Print Network [OSTI]

SULFUR RESISTANCE OF GROUP VIII TRANSITION METAL PROMOTED NICKEL CATALYSTS FOR SYNTHESIS GAS METHANATION A Thesis by KELLEE HALL HAMLIN Submitted to the Graduate College of Texas AgrM University in partial fulfillment of the requirement...: Aydin Akger n (Chairman of Co 'ttee) Ahme M. Gadalla (Member) Michael . Rosynek (Member) aries D. Holland . ( ead of Department) May 1986 ABSTRACT Sulfur Resistance of Group VIII Transition Metal Promoted Nickel Catalysts For Synthesis Gas...

Hamlin, Kellee Hall

2012-06-07T23:59:59.000Z

416

The complete genome sequence of Staphylothermus marinus reveals differences in sulfur metabolism among heterotrophic Crenarchaeota  

SciTech Connect (OSTI)

Staphylothermus marinus is an anaerobic, sulfur-reducing peptide fermenter of the archaeal phylum Crenarchaeota. It is the third heterotrophic, obligate sulfur reducing crenarchaeote to be sequenced and provides an opportunity for comparative analysis of the three genomes. The 1.57 Mbp genome of the hyperthermophilic crenarchaeote Staphylothermus marinus has been completely sequenced. The main energy generating pathways likely involve 2-oxoacid:ferredoxin oxidoreductases and ADP-forming acetyl-CoA synthases. S. marinus possesses several enzymes not present in other crenarchaeotes including a sodium ion-translocating decarboxylase likely to be involved in amino acid degradation. S. marinus lacks sulfur-reducing enzymes present in the other two sulfur-reducing crenarchaeotes that have been sequenced - Thermofilum pendens and Hyperthermus butylicus. Instead it has three operons similar to the mbh and mbx operons of Pyrococcus furiosus, which may play a role in sulfur reduction and/or hydrogen production. The two marine organisms, S. marinus and H. butylicus, possess more sodium-dependent transporters than T. pendens and use symporters for potassium uptake while T. pendens uses an ATP-dependent potassium transporter. T. pendens has adapted to a nutrient-rich environment while H. butylicus is adapted to a nutrient-poor environment, and S. marinus lies between these two extremes. The three heterotrophic sulfur-reducing crenarchaeotes have adapted to their habitats, terrestrial vs. marine, via their transporter content, and they have also adapted to environments with differing levels of nutrients. Despite the fact that they all use sulfur as an electron acceptor, they are likely to have different pathways for sulfur reduction.

Anderson, iain J.; Dharmarajan, Lakshmi; Rodriguez, Jason; Hooper, Sean; Porat, Iris; Ulrich, Luke E.; Elkins, James G.; Mavromatis, Kostas; Sun, Hui; Land, Miriam; Lapidus, Alla; Lucas, Susan; Barry, Kerrie; Huber, Harald; Zhulin, Igor B.; Whitman, William B.; Mukhopadhyay, Biswarup; Woese, Carl; Bristow, James; Kyrpides, Nikos

2008-09-05T23:59:59.000Z

417

A Mathematical Model for a LithiumSulfur Cell Karthikeyan Kumaresan,a,  

E-Print Network [OSTI]

S8 l is reduced to S2- in steps. For example, S8 l is reduced to S8 2- , then to S6 2- , S4 2- , S2,4 Figure 1 presents a typical experimental discharge profile at a C/50 rate C = 2.5 Ah . The lithium/sulfur Development The schematic of the lithium/sulfur cell modeled in this work is shown in Fig. 2. The cell is made

418

Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production  

SciTech Connect (OSTI)

The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

2010-05-01T23:59:59.000Z

419

Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products  

SciTech Connect (OSTI)

A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

2011-11-17T23:59:59.000Z

420

Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks  

SciTech Connect (OSTI)

Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

Lopez-Lopez, D.; Wong-Moreno, A. [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

1998-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Insights On The Thermal History Of The Valles Caldera, New Mexico- Evidence  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » Insights On The Thermal History Of The Valles Caldera, New Mexico- Evidence From Zircon Fission-Track Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Insights On The Thermal History Of The Valles Caldera, New Mexico- Evidence From Zircon Fission-Track Analysis Details Activities (2) Areas (1) Regions (0) Abstract: The zircon fission-track dating method was applied to the VC-2B core obtained from the active hydrothermal system at Sulphur Springs, Valles caldera, New Mexico. Four samples were analyzed to obtain both zircon ages and track length data from Permian strata to Precambrian quartz

422

Street Light View: Enriching Navigable Panoramic Street View Maps with Informative Illumination Thumbnails  

E-Print Network [OSTI]

1 Street Light View: Enriching Navigable Panoramic Street View Maps with Informative Illumination, Stony Brook University ABSTRACT Google Street View is a technology featured in Google Maps and Google Earth that provides panoramic and immersive views of street scenes in many cities around the world

Mueller, Klaus

423

TotalView Parallel Debugger at NERSC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Totalview Totalview Totalview Description TotalView from Rogue Wave Software is a parallel debugging tool that can be run with up to 512 processors. It provides both X Windows-based Graphical User Interface (GUI) and command line interface (CLI) environments for debugging. The performance of the GUI can be greatly improved if used in conjunction with free NX software. The TotalView documentation web page is a good resource for learning more about some of the advanced TotalView features. Accessing Totalview at NERSC To use TotalView at NERSC, first load the TotalView modulefile to set the correct environment settings with the following command: % module load totalview Compiling Code to Run with TotalView In order to use TotalView, code must be compiled with the -g option. We

424

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 31 | Next | Last Back to Index Target Bay Foundation One unique challenge was creating the foundation for the NIF target bay, which is about 15 meters below ground level....

425

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 31 | Next | Last Back to Index NIF Groundbreaking Lawrence Livermore National Laboratory Director Bruce Tarter, Secretary of Energy Federico Pena, and Congresswoman Ellen...

426

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The U.S. Department of Energy (DOE) has provided radioisotope thermoelectric generators for space applications since 1961. These generators provide electrical power for spacecraft...

427

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

equipment. The chamber, a sphere ten meters (33 feet) in diameter, is covered with boron-injected concrete to absorb neutrons during NIF experiments. Photo Number: NIF-1209-18055...

428

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 31 | Next | Last Back to Index NIF at Night Crews often worked around the clock to build the stadium-size facility. Construction required more than 4,600 metric tons of...

429

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 31 | Next | Last Back to Index Nova Target Chamber In 1986, Nova produced the largest laser fusion yield to date - a record 11 trillion fusion neutrons. The following year,...

430

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Index Switchyard Construction The switchyards' support structures are built to resist vibration. They are firmly anchored to the building's reinforced concrete walls, which are 0.6...

431

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

convert infrared light to ultraviolet. Nova experiments provided confidence that a NIF-size laser could achieve thermonuclear ignition in a laboratory. Photo Number: NIF-1109-17878...

432

History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 31 | Next | Last Back to Index The Final "Golden Bolt" NIF and Photon Science Principal Associate Director Ed Moses honors a NIF contract worker by presenting him with the...

433

A PHILOSOPHICAL VIEW OF CIVILIZATION  

Science Journals Connector (OSTI)

Publisher Summary Civilization comprises the dynamic interchange or transaction between three open entitieshuman nature, values and environment, physical and idealand can be understood only as their emergence or transcendence. The scientific and technological age views civilization in East or West largely in the context of man's control and manipulation of nature. The furniture and appurtenances of civilized living, the scaffolding and the frame-work rather than the mansion itself loom larger in the picture. However, the mansion of civilization is represented by the insights, appreciations, values and aspirations of mankind. It is these enduring experiences of the race which embody the essence of civilization and should obtain primary consideration in any adequate treatment. As the philosophy of science and technology makes a tour round the globe, the meanings, appreciations, and values that civilization actually experiences in its orientation to cosmos and to existence as a whole are discounted as metaphysical and religiousirrelevant for modern secular culture.

RADHAKAMAL MUKERJEE

2014-01-01T23:59:59.000Z

434

A View from the Bridge - DOE Perspective | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

A View from the Bridge - DOE Perspective A View from the Bridge - DOE Perspective Broad view of DOE's approach to addressing transportation sector oil dependence...

435

Better Buildings Network View | April 2014 | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Network View | April 2014 Better Buildings Network View | April 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings...

436

September 2013 Most Viewed Documents for Biology And Medicine | OSTI, US  

Office of Scientific and Technical Information (OSTI)

September 2013 Most Viewed Documents for Biology And Medicine September 2013 Most Viewed Documents for Biology And Medicine Drug Retention Times Center for Human Reliability Studies (2007) 29 Oleoresin Capsicum toxicology evaluation and hazard review Archuleta, M.M. (1995) 27 SURVEY OF NOISE SUPPRESSION SYSTEMS FOR ENGINE GENERATOR SETS. KRISHNA,C.R. (1999) 27 Site-Directed Research and Development FY 2012 Annual Report , (2013) 27 Human radiation studies: Remembering the early years. Oral history of Donner Lab Administrator Baird G. Whaley, August 15, 1994 NONE (1995) 26 Degradation of high concentrations of glycols, antifreeze, and deicing fluids Strong-Gunderson, J.M.; Wheelis, S.; Carroll, S.L.; Waltz, M.D.; Palumbo, A.V. (1995) 24 Human radiation studies: Remembering the early years. Oral history of Dr. George Voelz, M.D., November 29, 1994

437

Comparison of Comprehensive Two-Dimensional Gas Chromatography Coupled with Sulfur-Chemiluminescence Detector to Standard Methods for Speciation of Sulfur-Containing Compounds in Middle Distillates  

Science Journals Connector (OSTI)

......in seconds). The general elution profile was...sulfur-specific analysis of diesel oils. Comparison...different types of diesel oils by XRF and GC...and LCO, light cycle gasoil. Figure 2...components in a light cycle oil of catalytic...compounds in gasoline and diesel range process streams......

Rosario Ruiz-Guerrero; Colombe Vendeuvre; Didier Thibaut; Fabrice Bertoncini; Didier Espinat

2006-10-01T23:59:59.000Z

438

Hydrogenase of the hyperthermophile Pyrococcus furiosus is an elemental sulfur reductase or sulfhydrogenase: evidence for a sulfur-reducing hydrogenase ancestor  

Science Journals Connector (OSTI)

...polysulfide reduction/geothermal biolog/evolution...appears to be an energy-conserving reaction...The publication costs of this article...sulfur-rich, geothermal environ- ments...fact, represent an energy- conserving reaction...the Department of Energy (FG09-88ER13901...

K Ma; R N Schicho; R M Kelly; M W Adams

1993-01-01T23:59:59.000Z

439

Comparison of Comprehensive Two-Dimensional Gas Chromatography Coupled with Sulfur-Chemiluminescence Detector to Standard Methods for Speciation of Sulfur-Containing Compounds in Middle Distillates  

Science Journals Connector (OSTI)

......discussed later (16,19). For straight-run samples (SR1 and SR2, Figures...identification of C4 and C5DBTs). For straight-run samples (SR1 and SR2), the...analysis of sulfur com- pounds in gasoline range petroleum products with......

Rosario Ruiz-Guerrero; Colombe Vendeuvre; Didier Thibaut; Fabrice Bertoncini; Didier Espinat

2006-10-01T23:59:59.000Z

440

Isotope shift in the sulfur electron affinity: Observation and theory  

SciTech Connect (OSTI)

The sulfur electron affinities {sup e}A(S) are measured by photodetachment microscopy for the two isotopes {sup 32}S and {sup 34}S (16 752.975 3(41) and 16 752.977 6(85) cm{sup -1}, respectively). The isotope shift in the electron affinity is found to be more probably positive, {sup e}A({sup 34}S)- {sup e}A({sup 32}S) =+0.0023(70) cm{sup -1}, but the uncertainty allows for the possibility that it may be either ''normal''[{sup e}A({sup 34}S) > {sup e}A({sup 32}S)] or ''anomalous''[{sup e}A({sup 34}S) < {sup e}A({sup 32}S)]. The isotope shift is estimated theoretically using elaborate correlation models, monitoring the electron affinity and the mass polarization term expectation value. The theoretical analysis predicts a very large specific mass shift (SMS) that counterbalances the normal mass shift (NMS) and produces an anomalous isotope shift {sup e}A({sup 34}S)- {sup e}A({sup 32}S) =-0.0053(24) cm{sup -1}, field shift corrections included. The total isotope shift can always be written as the sum of the NMS (here +0.0169 cm{sup -1}) and a residual isotope shift (RIS). Since the NMS has nearly no uncertainty, the comparison between experimental and theoretical RIS is more fair. With respective values of -0.0146(70) cm{sup -1} and -0.0222(24) cm{sup -1}, these residual isotope shifts are found to agree within the estimated uncertainties.

Carette, Thomas; Scharf, Oliver; Godefroid, Michel [Chimie Quantique et Photophysique, Universite Libre de Bruxelles - CP160/09, B-1050 Brussels (Belgium); Drag, Cyril; Blondel, Christophe; Delsart, Christian [Laboratoire Aime-Cotton, CNRS, Universite Paris-sud, F-91405 Orsay cedex (France); Froese Fischer, Charlotte [National Institute of Standards and Technology Gaithersburg, Maryland 20899-8420 (United States)

2010-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

The solubility of sulfur hexafluoride in water and seawater  

Science Journals Connector (OSTI)

The concentration of sulfur hexafluoride (SF6) in the atmosphere has been rapidly increasing during the past several decades. This long-lived compound enters the surface ocean by airsea gas exchange and is potentially a very useful transient tracer for studying ocean circulation and mixing. SF6 has also been directly injected into the ocean at a minimal number of locations as a part of deliberate tracer release experiments to study gas exchange and sub-surface mixing rates. In this study, laboratory measurements of the solubility of SF6 in water and seawater were made over the temperature range of ??0.5C to 40C. Volumes of water and seawater held at constant temperature in glass chambers were equilibrated with a gas mixture containing SF6 and CFC-12 (CF2Cl2) at parts-per-trillion levels in nitrogen. Small volume water samples were analyzed by electron capture gas chromatography. Using the method of least squares, equations previously used in describing gas solubility as a function of temperature and salinity were fit to the SF6 and CFC-12 measurements. The CFC-12 results were in good agreement with previous work, while substantial differences were found between these SF6 results and those reported in earlier studies. The mean error for the analytical measurements is estimated to be ?0.5%. Based on errors in the fits and the analytical errors, we estimate the overall accuracy of the SF6 solubility function to be of the order of 2%. The results from this work should be useful in determining equilibrium concentrations for SF6 in ocean observation and modeling studies.

John L Bullister; David P Wisegarver; Frederick A Menzia

2002-01-01T23:59:59.000Z

442

Rebekah Foster-Terry Oral History  

E-Print Network [OSTI]

Oral history interview with Reverend Rebekah Foster-Terry conducted by Stephanie Meador in 2009. In this interview, Rev. Foster-Terry, pastor of the Victory Tabernacle Church in Topeka, Kansas, discusses the history of the ...

Foster-Terry, Rebekah; Meador, Stephanie Rae

2009-01-01T23:59:59.000Z

443

Scepticism and the Study of History  

Science Journals Connector (OSTI)

During the two centuries prior to the publication of David Humes History of England, the attitude of the sceptical thinkers regarding the study of history had changed greatly. The ancient Greek sceptics and the ...

Richard H. Popkin

1970-01-01T23:59:59.000Z

444

The History of DEER | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

The History of DEER The History of DEER Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan....

445

Well Record or History | Open Energy Information  

Open Energy Info (EERE)

History Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Well Record or HistoryLegal Published NA Year Signed or Took Effect 2013...

446

14.731 Economic History, Fall 2003  

E-Print Network [OSTI]

A survey of world economic history, designed to introduce economics graduate students to the subject matter and methodology of economic history. Topics chosen to show a wide variety of historical experience and illuminate ...

Temin, Peter

447

Fisheries Science & Management: a Brief History  

E-Print Network [OSTI]

: a brief history ·Late 1800s: industrial revolution allowed rapid expansion of exploitation ·E in 1882 #12;Fisheries sci & mgt: a brief history ·Late 1800s: industrial revolution allowed rapid

Limburg, Karin E.

448

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision  

SciTech Connect (OSTI)

The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

1994-03-10T23:59:59.000Z

449

Effects of Fuel Sulfur Content and Diesel Oxidation Catalyst on PM Emitted from Light-Duty Diesel Engine  

Science Journals Connector (OSTI)

This work aims at the particle number concentrations and size distributions, sulfate and trace metals emitted from a diesel engine fueled with three different sulfur content fuels, operating with and without DOC. ... Figure 2. Sulfate emission rate and fuel consumption as a function of sulfur content at engine speed of 2690 rpm. ... Thus, the use of low metal fuels and lubricating oil is as important to the environment and human health as low sulfur fuels, especially for engines with after-treatment devices. ...

Hong Zhao; Yunshan Ge; Xiaochen Wang; Jianwei Tan; Aijuan Wang; Kewei You

2010-01-05T23:59:59.000Z

450

TUDE DE L'ABSORPTION ULTRAVIOLETTE DU SULFURE DE CARBONE Par Mlles ODETTE AMIOT et HENRIETTE MARSAC.  

E-Print Network [OSTI]

dilué de plus en plus le sulfure de carbone dans un solvant inactif. Nous avons choisi l'hexane, liquide montage par autocollimation. 2. Purification du sulfure de carbone et prépa- ration des solutions. - On sait que le sulfure de car- bone est un liquide altérable et qu'il se décompose à la lumière avec

Boyer, Edmond

451

Report. Web of Science History project  

Science Journals Connector (OSTI)

...September 2002 research-article Report. Web of Science History project J. Corden Archivist...Heritage Lottery Fund awarded 43,000 to the Web of Science History project, which was put...hosted by the Public Record Office at Kew. Web Of Science History|The Royal Society...

2002-01-01T23:59:59.000Z

452

BOSTON UNIVERSITY HISTORY OF ART & ARCHITECTURE  

E-Print Network [OSTI]

BOSTON UNIVERSITY HISTORY OF ART & ARCHITECTURE GRADUATE PROGRAM 2012-2013 Information & Architecture College of Arts & Sciences 725 Commonwealth Avenue, Room 302 Boston, MA 02215 Tel: (617) 353 ..................................................................... 5 THE MA DEGREE IN HISTORY OF ART AND ARCHITECTURE ........................ 5 History of Art

Goldberg, Bennett

453

The battle of batteries: a history of innovation in alternative energy cars  

Science Journals Connector (OSTI)

The paper gives a global view on the historical development of electrical cars. It is a history described in five major waves; the first one starting about 1835 and the last one ending about 2000. With two cases, important aspects of the two last waves are described in detail. The cases are the French VEL car and the Norwegian Think car. They have had their more specific setbacks. Problems in electrochemistry have caused important limitations, as they have through the whole history of electrical cars. This is the background for the paper title: The Battle of Batteries.

Karl G. Hoyer

2007-01-01T23:59:59.000Z

454

UNDERSTANDING OF CATALYST DEACTIVATION CAUSED BY SULFUR POISONING AND CARBON DEPOSITION IN STEAM REFORMING OF LIQUID HYDROCARBON FUELS.  

E-Print Network [OSTI]

??The present work was conducted to develop a better understanding on the catalyst deactivation in steam reforming of sulfur-containing liquid hydrocarbon fuels for hydrogen production. (more)

Xie, Chao

2011-01-01T23:59:59.000Z

455

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation .  

E-Print Network [OSTI]

??The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test (more)

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

456

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

world-best-practice-energy- intensity-values-selected-World Best Practice Energy Intensity Values for Selectedof the Targets for Energy Intensity and Sulfur Dioxide in

Zhou, Nan

2013-01-01T23:59:59.000Z

457

The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen .  

E-Print Network [OSTI]

??The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - (more)

Miu, Kevin (Kevin K.)

2006-01-01T23:59:59.000Z

458

The Better Buildings Neighborhood View- October 2012  

Broader source: Energy.gov [DOE]

The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program - October 2012

459

Fibrations and universal view updatability Michael Johnson  

E-Print Network [OSTI]

Fibrations and universal view updatability Michael Johnson Computing Department, Macquarie methods to manage the complexity. Dampney and Johnson [25] first showed how data models based on entity

Johnson, Michael

460

Fibrations and universal view updatability Michael Johnson  

E-Print Network [OSTI]

Fibrations and universal view updatability Michael Johnson Computing Department, Macquarie and Johnson [25] first showed how data models based on entity-relationship (ER) diagrams [10] are enhanced

Rosebrugh, Robert

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Toward Understanding the Effect of Nuclear Waste Glass Composition of Sulfur Solubility  

SciTech Connect (OSTI)

The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

2014-02-13T23:59:59.000Z

462

THE EFFECT OF ANOLYTE PRODUCT ACID CONCENTRATION ON HYBRID SULFUR CYCLE PERFORMANCE  

SciTech Connect (OSTI)

The Hybrid Sulfur (HyS) cycle (Fig. 1) is one of the simplest, all-fluids thermochemical cycles that has been devised for splitting water with a high-temperature nuclear or solar heat source. It was originally patented by Brecher and Wu in 1975 and extensively developed by Westinghouse in the late 1970s and early 1980s. As its name suggests, the only element used besides hydrogen and oxygen is sulfur, which is cycled between the +4 and +6 oxidation states. HyS comprises two steps. One is the thermochemical (>800 C) decomposition of sulfuric acid (H{sub 2}SO{sub 4}) to sulfur dioxide (SO{sub 2}), oxygen (O{sub 2}), and water. H{sub 2}SO{sub 4} = SO{sub 2} + 1/2 O{sub 2} + H{sub 2}O. The other is the SO{sub 2}-depolarized electrolysis of water to H{sub 2}SO{sub 4} and hydrogen (H{sub 2}), SO{sub 2} + 2 H{sub 2}O = H{sub 2}SO{sub 4} + H{sub 2}, E{sup o} = -0.156 V, explaining the 'hybrid' designation. These two steps taken together split water into H{sub 2} and O{sub 2} using heat and electricity. Researchers at the Savannah River National Laboratory (SRNL) and at the University of South Carolina (USC) have successfully demonstrated the use of proton exchange membrane (PEM) electrolyzers (Fig. 2) for the SO{sub 2}-depolarized electrolysis (sulfur oxidation) step, while Sandia National Laboratories (SNL) successfully demonstrated the high-temperature sulfuric acid decomposition (sulfur reduction) step using a bayonet-type reactor (Fig. 3). This latter work was performed as part of the Sulfur-Iodine (SI) cycle Integrated Laboratory Scale demonstration at General Atomics (GA). The combination of these two operations results in a simple process that will be more efficient and cost-effective for the massive production of hydrogen than alkaline electrolysis. Recent developments suggest that the use of PEMs other than Nafion will allow sulfuric acid to be produced at higher concentrations (>60 wt%), offering the possibility of net thermal efficiencies around 50% (HHV basis). The effect of operation at higher anolyte concentrations on the flowsheet, and on the net thermal efficiency for a nuclear-heated HyS process, is examined and quantified.

Gorensek, M.; Summers, W.

2010-03-24T23:59:59.000Z

463

Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content  

SciTech Connect (OSTI)

In the hydrotreating and steam reforming of an oxygen and sulfur bearing hydrocarbon fuel, the oxygen is first removed in an oxidizer containing a bed of platinum catalyst, the inlet temperature being well below 1000/sup 0/F and preferably on the order of 300/sup 0/F. The sulfur in the fuel does not harm the oxidizer catalyst and may be removed downstream by known hydrodesulfurization techniques prior to reforming. A process is described for removing oxygen from an oxygen and sulfur bearing hydrocarbon fuel, such as peak shared natural gas, upstream in the process so that sulfur can be removed later. The fuel and some hydrogen are introduced into an oxidizer at a temperature of 350/sup 0/F or less down to the minimum ignition temperature. The oxidizer consists of a platinum bed catalyst which catalyzes the oxidation of the oxygen to water with accompanying heat release to raise the exit gas temperature to less than 650/sup 0/F. The temperature desorbs the sulfur from the catalyst, and the exit gases are passed downstream to nickel subsulfide or molybdenum desfulfide catalysts where the hydrosulfurization process takes place. (BLM)

Lesieur, R.R.; Setzer, H.J.; Hawkins, J.R.

1980-01-01T23:59:59.000Z

464

Sulfur-passivated nickel catalysts for carbon-free steam reforming of methane  

SciTech Connect (OSTI)

It has been observed that carbon-free steam reforming of methane can be obtained on a partly sulfur-passivated nickel catalyst under conditions which, without the presence of sulfur, would result in formation of whisker carbon. This effect has been studied by means of kinetic experiments and thermogravimetry. The kinetic data can be explained by simple blockage of the surface as reflected in the observed kinetic orders and activation energy. The studies of carbon formation confirm a threshold coverage of about 70% of full coverage below which the inhibition of carbon is not effective. Above this coverage, amorphous carbon structures may be formed at a very high carbon potentials. The retarding effect of sulfur on carbon formation is a dynamic phenomenon. Sulfur inhibits the rate of carbon formation more than the rate of the reforming reactions. The effects are explained by assuming that a large ensemble is involved in the nucleation of carbon, whereas the reforming reaction can proceed on the small ensembles left a high sulfur coverages. 6 figures, 6 tables.

Rostrup-Nielsen, J.R.

1984-01-01T23:59:59.000Z

465

Sulfur transformations in early diagenetic sediments from the Bay of Concepcion, off Chile  

SciTech Connect (OSTI)

Despite the recognition that both organic sulfur and pyrite form during the very early stages of diagenesis, and that the amount of H{sub 2}S generated in bacterial sulfate reduction primarily limits their formation, the mechanisms and the active species involved still are not clear. In this study, we quantified the major forms of sulfur distributed in sediments to assess the geochemical mechanisms involved in these transformations. XANES spectroscopy, together with elemental analysis, were used to measure sulfur speciation in the organic-rich sediments from the Bay of Concepcion, Chile. Organic polysulfides constituted the major fraction of the organic sulfur, and occurred maximally just below the sediment surface (1--3 cm), where intermediates from H{sub 2}S oxidation were likely to be generated most abundantly. Sulfonates, which could be formed through the reactions of sulfate and thiosulfate, also showed a sub-surface maximum in the vicinity of the ``oxic-anoxic interface``. These results strongly suggest a geochemical origin for organic polysulfides and sulfonates, and illustrate that intermediates from H{sub 2}S oxidation play a dominant role in incorporating sulfur into organic matter. Pyrite was absent in the surficial layer, and first appeared just below the H{sub 2}S maximum, where organic polysulfides began to decrease in abundance. From these results, we argue, that an iron monosulfide precursor formed first from reactions with H{sub 2}S, and then reacts with organic polysulfides, completing the synthesis of pyrite in the sediment column.

Vairavamurth, M.A.; Wang, Shengke; Khandelwal, B.; Manowitz, B. [Brookhaven National Lab., Upton, NY (United States); Ferdelman, T.; Fossing, H. [Max Plank Institute for Marine Microbiology, Bremen (Germany). Dept. of Biogeochemistry

1995-04-01T23:59:59.000Z

466

Computational studies of experimentally observed structures of sulfur on metal surfaces  

SciTech Connect (OSTI)

First-principles electronic structure calculations were carried out to examine the experimentally observed structures of sulfur on close packed surfaces of a number of important metals - Ag(111), Cu(111), Ni(111), Pt(111), Rh(111), Re(0001) and Ru(0001). At low coverages ({le} 1/3 ML), the prediction is consistent with the typical pattern of preferred sulfur occupancy of threefold hollow sites, notably the fcc site on the (111) surfaces and the hcp site on the (0001) surfaces. Theoretical confirmation for the existence of pure sulfur overlayer phases on Pt(111), Rh(111), Re(0001) and Ru(0001) at higher coverages (> 1/3 ML) was provided. For the ({radical}7 x {radical}7) phase seen on Ag(111), the most preferred structure identified for adsorbed S trimer consists of an S atom on the top site bonded to two S atoms situated on the nearest neighbor off-bridge site positions. Among the different densely packed mixed sulfur-metal overlayer models suggested for the ({radical}7 x {radical}7) phase on Cu(111), the structure which consists of metal and S atoms in a hexagonal-like arrangement on the top substrate was found to be the most energetically favorable. For the (5{radical}3 x 2) phase on Ni(111), the calculations confirm the existence of clock-reconstructed top layer metal atoms onto which sulfur atoms are adsorbed.

Alfonso, Dominic

2011-09-01T23:59:59.000Z

467

Winnipegosis case history: Tableland Saskatchewan  

SciTech Connect (OSTI)

The geology and history of exploration in the Tableland area of southeast Saskatchewan will be reviewed in relation to a major Middle Devonian Winnipegosis oil discovery made in 1986 by Home Oil. Southern Saskatchewan is underlain by the northern third of the Williston basin. Although rich oil deposits have been found in the Devonian of the basin on the American side, dry holes have been the rule in Saskatchewan except for the Hummingbird Upper Devonian Birdbear discovery in 1966. The long history of failures in the Winnipegosis Formation had led to a general reluctance in the industry to drill deep wells especially with today's lower crude prices. Based on geology, seismic data, and modeling, Home Oil drilled Tableland 08-22-002-09W2M in february 1986 and encountered an oil-bearing Winnipegosis reef. This well has the highest production rate of any well in Saskatchewan and is the first commercially significant Winnipegosis well in a basinal setting within the Williston basin. A state-of-the-art pseudo 3-D processing of all the existing 2-D seismic data was performed to aid in choosing development well locations. As a result of this discovery, deep exploration plays in southeast Saskatchewan are now being pursued aggressively by many companies.

Orr, N.E.; Martindale, W.

1988-02-01T23:59:59.000Z

468

A Long View Of The Energy Market  

Science Journals Connector (OSTI)

A Long View Of The Energy Market ... Billionaire philanthropist and Microsoft Chairman Bill Gates and Nobel Prize-winning physicist and Energy Secretary Steven Chu hold similar views on the importance of finding new sources of inexpensive energy to better the plight of the worlds pooras well as to make money. ...

JEFF JOHNSON

2012-03-19T23:59:59.000Z

469

,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"  

U.S. Energy Information Administration (EIA) Indexed Site

Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","9/2013","1/15/1985" ,"Release Date:","11/27/2013" ,"Next Release Date:","Last Week of December 2013" ,"Excel File Name:","pet_pnp_crq_a_epc0_ycs_pct_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_crq_a_epc0_ycs_pct_m.htm" ,"Source:","Energy Information Administration"

470

Sodium/Phosphorus-Sulfur Cells I. Cell Performance Paul L. Ridgway,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sodium/Phosphorus-Sulfur Cells Sodium/Phosphorus-Sulfur Cells I. Cell Performance Paul L. Ridgway, Frank R. McLarnon, and Elton J. Cairns* Energy and Environment Division, Lawrence Berkeley National Laboratory, and Department of Chemical Engineering, University of California, Berkeley, California 94720, USA ABSTRACT Sodium/°-alumina/phosphorus-sulfur cells utilizing P/S ratios of 0, 0.143, 0.332, and 1.17 at temperatures from 350 to 500°C were studied by measurement of the equilibrium cell voltages at open circuit, and the steady-state cell voltages at current densities up to 70 mA/cm2. States of charge, represented by sodium atom fraction in the P-S electrode, ranged from 0 to 0.4. Open-circuit voltages up to 2.65 V were measured. Theoretical specific energies up to 825 Wh/kg were cal-

471

Electrochemical separation and concentration of sulfur containing gases from gas mixtures  

DOE Patents [OSTI]

A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

1981-01-01T23:59:59.000Z

472

Sulfur isotopes related to sedimentation conditions for metalliferous black shales of Pennsylvanian Age  

SciTech Connect (OSTI)

Sulfur isotope composition were determined for pyrite and sphalerite grains isolated from 8 metalliferous Missourian, Desmoinesian, and Atokan black shales from Missouri, Illinois, Kansas, and Indiana. The younger Missourian shales from the Forest City and Illinois basins contain consistently light sulfur as expected for euxinic conditions, but sulfides from the older shales show heavier and more erratic sulfur values. These isotope patterns suggest that younger shales accumulated slowly offshore, although older shales may have been deposited more quickly in shallower water. Isotope values, which also correlate with heavy metal patterns (e.g., higher molybdenum values for the eastern most older shales), may therefore reflect gradually deepening conditions for the epicontinental Pennsylvanian seas of the US Mid-Continent.

Coveney, R.M. Jr.; Shaffer, N.R.

1985-02-01T23:59:59.000Z

473

Evaluation of sulfur-reducing microorganisms for organic desulfurization. [Pyrococcus furiosus  

SciTech Connect (OSTI)

Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

Miller, K.W.

1991-01-01T23:59:59.000Z

474

Computational Study of Sulfurnickel Interactions: A New SNi Phase Diagram  

SciTech Connect (OSTI)

Prediction of the interactions between H2S-contaminated hydrogen fuel and Ni surfaces under conditions similar to those for solid oxide fuel cell (SOFC) operation using DFT (density function theory) calculations (with thermodynamic corrections) has resulted in a new SNi phase diagram, which suggests the existence of an intermediate state between clean Ni surfaces and nickel sulfides sulfur atoms adsorbed on Ni surfaces. This prediction is consistent with many experimental observations relevant to sulfur poisoning of Nibased anodes in SOFCs, which cannot be explained using the existing SNi bulk phase diagram from classical thermodynamics. The accurate prediction of the adsorption phase is vital to a fundamental understanding of the sulfur poisoning mechanism of Ni-based anodes under SOFC operating conditions.

Wang, Jeng-Han; Liu, Meilin

2007-06-22T23:59:59.000Z

475

U.S. Coal Reserves: An Update by Heat and Sulfur Content  

Gasoline and Diesel Fuel Update (EIA)

2) 2) Distribution Category UC-98 U.S. Coal Reserves: An Update by Heat and Sulfur Content February 1993 Energy Information Administration Office of Coal, Nuclear, Electric and Alternate Fuels U.S. Department of Energy Washington, DC 20585 Energy Information Administration/ U.S. Coal Reserves: An Update by Heat and Sulfur Content ii This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should not be construed as advocating or reflecting any policy position of the Department of Energy or of any other organization. Energy Information Administration/ U.S. Coal Reserves: An Update by Heat and Sulfur Content iii Contacts This report was prepared by the staff of the Energy

476

User_Sup_ViewEmpMatrix  

Broader source: Energy.gov (indexed) [DOE]

an Employee Matrix (Supervisor) an Employee Matrix (Supervisor) © 2011 SuccessFactors, Inc. - 1 - SuccessFactors Learning Confidential. All rights reserved. Job Aid: Viewing an Employee Matrix (Supervisor) Purpose The purpose of this job aid is to guide supervisor users through the step-by-step process of viewing an employee matrix within SuccessFactors Learning. Task A. View an Employee Matrix From the Home page, click the My Employees tab. Click the Employee Matrix supervisor link. Click the Change Measures expand arrow ( ) to select criteria for comparison. View an Employee Matrix 8 Steps Task A 3 3 1 1 2 2 SuccessFactors Learning v 6.4 User Job Aid Viewing an Employee Matrix (Supervisor) © 2011 SuccessFactors, Inc. - 2 - SuccessFactors Learning Select a measure for the

477

Mountain View Grand | Open Energy Information  

Open Energy Info (EERE)

Grand Grand Jump to: navigation, search Name Mountain View Grand Facility Mountain View Grand Sector Wind energy Facility Type Small Scale Wind Facility Status In Service Owner Mountain View Grand Developer Sustainable Energy Developments Energy Purchaser Mountain View Grand Location Mountain View Grand Resort & Spa NH Coordinates 44.397987°, -71.590306° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":44.397987,"lon":-71.590306,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

478

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992  

SciTech Connect (OSTI)

In developing the new Ohio University procedure the thermodynamic limitations of the reactions for removal of both pyritic and organic sulfur from coal at 400--600{degrees}C were studied using copper as a very strong H{sub 2}S-acceptor. Copper serves as a catalyst for ethanol dehydrogenation to form nascent hydrogen. Copper also serves as a scavenger to form copper sulfide from the hydrogen sulfide evolved during the reaction. Copper sulfide in turn serves as a catalyst for organic sulfur hydrodesulfurization reactions. If the coal to be desulfurized contains pyrite (FeS{sub 2}) or FeS, the copper scavenger effect reduces any back reaction of hydrogen sulfide with the iron and increases the removal of sulfur from the carbonaceous material. The desired effect of using copper can be achieved by using copper or copper containing alloys as materials of construction or as liners for a regenerable reactor. During the time period that Ohio Coal Development Office supported this work, small scale (560 grams) laboratory experiments with coals containing about 3.5% sulfur have achieved up to 90% desulfurization at temperatures of 500{degrees}C when using a copper reactor. Results from the autoclave experiments have identified the nature of the chemical reactions taking place. Because the process removes both pyritic and organic sulfur in coal, the successful scale up of the process would have important economic significance to the coal industry. Even though this and other chemical processes may be relatively expensive and far from being commercial, the reason for further development is that this process may hold the promise of achieving much greater sulfur reduction and of producing a cleaner coal than other methods. This would be especially important for small or older power plants and industrial boilers.

Not Available

1993-04-15T23:59:59.000Z

479

Bioprocessing of High-sulfur Crudes Via Appliaction of Critical Fluid Biocatalysis  

SciTech Connect (OSTI)

This experimental research project investigated protein-based biocatalysis in supercritical fluid solvents as an integrated process approach to catalyze the removal of sulfur atoms from crude oils and fuels. The work focused on the oxidation of model sulfur-containing compounds in supercritical reaction media and included three major tasks: microbiological induction experiments, proteincatalyzed biooxidation in supercritical solvents, and a work-in-kind cooperative research and development agreement (CRADA). This work demonstrated that the biooxidation reaction could be improved by an order-of-magnitude by carrying out the reaction in emulsions in supercritical fluids.

Ginosar, Daniel Michael; Bala, Greg Alan; Anderson, Raymond Paul; Fox, Sandra Lynn; Stanescue, Marina A.

2002-05-01T23:59:59.000Z

480

Structural and Functional Studies on Human Mitochondrial Iron-Sulfur Cluster Biosynthesis  

E-Print Network [OSTI]

. (2003) Formation of iron-sulfur clusters in bacteria: an emerging field in bioinorganic chemistry. Curr. Opin. Chem. Biol. 7, 166-173]. 3 as the nitrogen-fixation (NIF) machinery (8). The NIF pathway is often a specialized assembly system... of Fe?S Cluster Biogenesis in Human Mitochondria Name Essential in yeast Yeast homologs Bacterial homologs Proposed function & protein interactions Nfs1 Yes Nfs1 IscS, NifS, SufS Cysteine desulfurase, sulfur donor, Interacts with Isd11, Isu2...

Tsai, Chi-Lin

2012-07-16T23:59:59.000Z

Note: This page contains sample records for the topic "view history sulfur" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

NO[sub x] reduction by sulfur tolerant coronal-catalytic apparatus and method  

DOE Patents [OSTI]

This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter. 7 figs.

Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

1992-09-15T23:59:59.000Z

482

NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method  

DOE Patents [OSTI]

This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

1993-01-01T23:59:59.000Z

483

NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method  

DOE Patents [OSTI]

This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

1992-01-01T23:59:59.000Z

484

Sulfur adsorption on nickel(100) and its effect on carbon monoxide, nitric oxide, and deuterium chemisorption  

SciTech Connect (OSTI)

The adsorption of CO, NO, and D/sub 2/ was studied on clean and sulfided Ni(100) near 100K using Auger electron spectroscopy, thermal desorption spectroscopy, X-ray and ultraviolet photoelectron spectroscopies, and work function change measurements. The evidence suggests that sulfur's effects are predominantly steric in nature. Weak, short-range (approx.4 angstrom) electrostatic effects are also present, due to charge transfer of about 0.04 of an electron from nickel to sulfur. The blocking effect of S on the adsorption of each gas at various temperatures is discussed.

Hardegree, E.L.

1985-01-01T23:59:59.000Z

485

Sulfur Behavior in the Sasol?Lurgi Fixed-Bed Dry-Bottom Gasification Process  

Science Journals Connector (OSTI)

This article reports on the findings of a study regarding the sulfur behavior across a Sasol?Lurgi gasifier. ... (2) This ash, referred to as coarse ash, is a combination of red and white to gray sintered clinkers with heterogeneous texture varying from fine material to large irregularly shaped aggregates of sizes ranging from 4 to 75 mm. ... South African coals that are used for the Sasol?Lurgi gasification process are normally low-grade medium rank C (bituminous) coal with a total sulfur content of approximately 1?2 wt %, on an as-received basis. ...

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; Herold Schobert

2008-12-05T23:59:59.000Z

486

Thermodynamic Investigation of Carbon Deposition and Sulfur Evolution in Chemical Looping Combustion with Syngas  

Science Journals Connector (OSTI)

Thermodynamic Investigation of Carbon Deposition and Sulfur Evolution in Chemical Looping Combustion with Syngas ... Chemical looping combustion (CLC) with syngas, a synthesized gas mixture of CO, H2, CO2, H2O(g), N2, and H2S, was investigated using thermodynamic simulation, with focus on carbon deposition and sulfur evolution in CLC. ... Abad, A.; Garcia-Labiano, F.; de Diego, L. F.; Gayan, P.; Adanez, J. Reduction kinetics of Cu-,Ni-, and Fe-based oxygen carriers using syngas (CO+H2) for chemical-looping combustion Energy Fuels 2007 21 4 1854 1858 ...

Baowen Wang; Rong Yan; Dong Ho Lee; David Tee Liang; Ying Zheng; Haibo Zhao; Chuguang Zheng

2008-02-16T23:59:59.000Z

487

NONEQUILIBRIUM SULFUR CAPTURE AND RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR  

SciTech Connect (OSTI)

Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. They are deposited on the liquid slag layer on the combustor wall. Due to the low solubility of sulfur in slag, slag must be rapidly drained from the combustor to limit sulfur gas re-evolution. Analysis indicated that slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to perform a series of tests to determine the factors that control the retention of the sulfur in the slag. 36 days of testing on the combustor were completed prior to the end of this reporting period, 12/31/98. This compares with 16 tests required in the original project plan. Combustor tests in early 1997 with high (37%) ash, Indian coal confirmed that high slag mass flow rates of about 500 lb/hr resulted in retention in the slag of up to 20% of the injected sulfur content mineral matter. To further increase the slag flow rate, rice husks, which contain 20% ash, and rice husk char, which contain 70% ash, were co-fired with coal in the combustor. A series of 13 combustor tests were performed in fourth quarter of 1997 and a further 6 tests were performed in January 1998 and in the summer of 1998. The test objective was to achieve slag flow rates between 500 and 1,000 lb/hr. Due to the very low bulk density of rice husk, compared to pulverized coal, almost the entire test effort focused on developing methods for feeding the rice husks into combustor. In the last test of December 1997, a peak mineral matter, injection rate of 592 lb/hr was briefly achieved by injection of coal, rice husk char, gypsum, and limestone into the combustor. However, no significant sulfur concentration was measured in the slag removed from the combustor. The peak injection rate reached with biomass in the 1997 tests was 310 lb/hr with rice husk, and 584 lb/hr with rice husk char.

Dr. Bert Zauderer

1999-03-15T23:59:59.000Z

488

Department of Energy, 1977-1994, A Summary History | Department...  

Broader source: Energy.gov (indexed) [DOE]

Energy, 1977-1994, A Summary History Department of Energy, 1977-1994, A Summary History history fo the Department of Energy Department of Energy, 1977-1994, A Summary History More...

489

Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost and equipment  

E-Print Network [OSTI]

Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost gas instead of continuing to burn low-sulfur fuel oil, a report said. Switching to liquefied natural who switch from gasoline-powered vehicles to ones fueled by compressed natural gas could save as much

490

subm. to Surf. Sci. Ab initio molecular dynamics study of H2 adsorption on sulfur-and chlorine-covered  

E-Print Network [OSTI]

subm. to Surf. Sci. Ab initio molecular dynamics study of H2 adsorption on sulfur- and chlorine/Germany The adsorption of molecular hydrogen on sulfur- and chlorine-covered Pd(100) in a (2?2) geometry is studied by ab initio molecular dynamics simulations. The potential energy surfaces of H2/S(2 ? 2)/Pd(100) and H2/Cl(2

Ulm, Universität

491

Effects of Switching to Lower Sulfur Marine Fuel Oil on Air Quality in the San Francisco Bay Area  

Science Journals Connector (OSTI)

Effects of Switching to Lower Sulfur Marine Fuel Oil on Air Quality in the San Francisco Bay Area ... Beginning in July 2009, an emission control area was put into effect at ports and along the California coastline, requiring use of lower sulfur fuels in place of heavy fuel oil in main engines of ships. ...

Ling Tao; David Fairley; Michael J. Kleeman; Robert A. Harley

2013-08-14T23:59:59.000Z

492

HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS  

SciTech Connect (OSTI)

This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

2009-05-12T23:59:59.000Z

493

ARM Orientation: Overview and History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ARM Orientation: ARM Orientation: Overview and History Warren Wiscombe ARM Chief Scientist Brookhaven & NASA ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement 2 Mar 2006 ARM Orientation You want me to be Chief Scientist? Can you believe this guy? ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement 3 Mar 2006 ARM Orientation ARM in a nutshell ARM in a nutshell * * Largest global change research program Largest global change research program funded by the U.S. Department of Energy funded by the U.S. Department of Energy ($44M/yr; ~ ($44M/yr; ~ $10M/yr fo $10M/yr fo r Science Team r Science Team ) ) * * Created to improve cloud and radiation Created to improve cloud and radiation physics and cloud simulation capabilities in physics and cloud simulation capabilities in

494

Our History | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

History | National Nuclear Security Administration History | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Our History Home > About Us > Our History Our History The NNSA was established by Congress in 2000 as a separately organized agency within the U.S. Department of Energy, responsible for the management and security of the nation's nuclear weapons, nuclear nonproliferation,

495

Virtual Museum Captures Ohio Plant History: Web-based Project Preserves  

Broader source: Energy.gov (indexed) [DOE]

Virtual Museum Captures Ohio Plant History: Web-based Project Virtual Museum Captures Ohio Plant History: Web-based Project Preserves Plant's Uranium Enrichment Legacy Virtual Museum Captures Ohio Plant History: Web-based Project Preserves Plant's Uranium Enrichment Legacy May 21, 2012 - 12:00pm Addthis An online museum on the Portsmouth Gaseous Diffusion Plant went live earlier this year. An online museum on the Portsmouth Gaseous Diffusion Plant went live earlier this year. PIKETON, Ohio - Do you wonder what the interior of a uranium enrichment plant looks like without ever stepping foot in the facility? Now, the public can view photos, watch interviews with current and former workers who share historical accounts and browse old newsletters on the Portsmouth Gaseous Diffusion Plant from as far back as the early 1950s with

496

Virtual Museum Captures Ohio Plant History: Web-based Project Preserves  

Broader source: Energy.gov (indexed) [DOE]

Virtual Museum Captures Ohio Plant History: Web-based Project Virtual Museum Captures Ohio Plant History: Web-based Project Preserves Plant's Uranium Enrichment Legacy Virtual Museum Captures Ohio Plant History: Web-based Project Preserves Plant's Uranium Enrichment Legacy May 21, 2012 - 12:00pm Addthis An online museum on the Portsmouth Gaseous Diffusion Plant went live earlier this year. An online museum on the Portsmouth Gaseous Diffusion Plant went live earlier this year. PIKETON, Ohio - Do you wonder what the interior of a uranium enrichment plant looks like without ever stepping foot in the facility? Now, the public can view photos, watch interviews with current and former workers who share historical accounts and browse old newsletters on the Portsmouth Gaseous Diffusion Plant from as far back as the early 1950s with

497

Sulfur Emissions from Volcanic A c t i v i t y i n 1985 and 1990 Carmen M. Benkovitz and M. A l t a f Mubaraki  

E-Print Network [OSTI]

APPENDIX C Sulfur Emissions from Volcanic A c t i v i t y i n 1985 and 1990 Carmen M. Benkovitz). Global estimates o f anthropogenic emissions o f sulfur f o r 1985 are approximately 65 Tg S y-l (Benkovi Anthropogenic Sulfur Emissions f o r 1985 and 1990 i n t h i s report). Sulfur from biogenic sources i s emitted

498

The History of Element 43Technetium  

Science Journals Connector (OSTI)

The History of Element 43Technetium ... Department of Mining, Metallurgical and Materials Engineering, Laval University, G1K 7P4 Quebec City, Canada ...

Fathi Habashi

2006-02-01T23:59:59.000Z

499

1 Introduction 4 1.1 History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . *  

E-Print Network [OSTI]

Contents 1 Introduction 4 1.1 History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . * * 4 1.1.1 Early Experimental Work . . . . . . . . . . . . . . . . 4 1.2 Structure of This Paper

Martin, Alain

500

A Postage Stamp History of Chemistry  

Science Journals Connector (OSTI)

An earlier historical article in Applied Spectroscopy used postage stamps to provide colorful illustrations for a short history of spectroscopy. Since the Editor has kindly...

Miller, Foil A

1986-01-01T23:59:59.000Z