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Sample records for view history catalytic

  1. Catalytic Reforming Downstream Processing of Fresh Feed Input

    Gasoline and Diesel Fuel Update (EIA)

    Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History U.S. 2,854 2,929 2,837 2,690 2,748 2,812 2010-2015 PADD 1 189 185 160 185 192 172 2010-2015 East Coast 173 169 144 171 176 155

  2. History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Physics Isotopes History History Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe....

  3. History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History History Print Photos 20th Anniversary Kickoff Brunch, January 11, 2013 ALS 20th Anniversary Celebration, October 4, 2013 Videos ALS Dedication, October 22, 1993 (excerpts) ALS Dedication, October 22, 1993 (full) The ALS Beamline Clock Articles BRIGHT BEAMS: The Advanced Light Source LBL Research Review (Spring 1993) A history of the ALS, From Cyclotron to Synchrotron Interactive Timeline ALS History: The First 20 Years

  4. History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History History A repository for images about our legacy as a Laboratory. News Releases Science Briefs Photos Picture of the Week Social Media Videos Fact Sheets Publications PHOTOS BY TOPIC Careers Community Visitors Environment History Science The Lab Click thumbnails to enlarge. Photos arranged by most recent first, horizontal formats before vertical. See Flickr for more sizes and details. Back in the day Back in the day LA bridge in Los Alamos LA bridge in Los Alamos 1945 Army-Navy

  5. History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Print Photos 20th Anniversary Kickoff Brunch, January 11, 2013 ALS 20th Anniversary Celebration, October 4, 2013 Videos ALS Dedication, October 22, 1993 (excerpts) ALS Dedication, October 22, 1993 (full) The ALS Beamline Clock Articles BRIGHT BEAMS: The Advanced Light Source LBL Research Review (Spring 1993) A history of the ALS, From Cyclotron to Synchrotron Interactive Timeline ALS History: The First 20 Years

  6. history

    National Nuclear Security Administration (NNSA)

    several contributions over SRS's history, including large-scale production of aluminum-lithium alloys; production of kilogram quantities of radioactive waste glass; materials...

  7. history

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Volume One Film Collection Volume Two 75th Anniversary Hydropower in the Northwest Woody Guthrie Videos Strategic Direction Branding & Logos Power of the River History Book...

  8. History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Physics » Isotopes » History History Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. History isotopes Proton-induced nuclear reactions at 800 and 100 megaelectronvolts (MeV). At energies of up to 100 MeV, protons cause the release of one or several neutrons and sometimes the release of a proton or an alpha particle in addition to neutrons. At 800 MeV, protons include spallation reactions that break apart

  9. Catalytic reactor

    DOE Patents [OSTI]

    Aaron, Timothy Mark; Shah, Minish Mahendra; Jibb, Richard John

    2009-03-10

    A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

  10. Rich catalytic injection

    DOE Patents [OSTI]

    Veninger, Albert (Coventry, CT)

    2008-12-30

    A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

  11. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1984-01-01

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  12. Catalytic cracking process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA); Baker, Richard W. (Palo Alto, CA)

    2001-01-01

    Processes and apparatus for providing improved catalytic cracking, specifically improved recovery of olefins, LPG or hydrogen from catalytic crackers. The improvement is achieved by passing part of the wet gas stream across membranes selective in favor of light hydrocarbons over hydrogen.

  13. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  14. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  15. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  16. Catalytic nanoporous membranes

    DOE Patents [OSTI]

    Pellin, Michael J; Hryn, John N; Elam, Jeffrey W

    2013-08-27

    A nanoporous catalytic membrane which displays several unique features Including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity. Also provided is a method for producing a catalytic membrane having flow-through pores and discreet catalytic clusters adhering to the inside surfaces of the pores.

  17. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  18. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

    1986-01-01

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  19. Catalytic conversion of LPG

    SciTech Connect (OSTI)

    Pujado, P.R.; Vora, B.V.; Mowry, J.R.; Anderson, R.F.

    1986-01-01

    The low reactivity of light paraffins has long hindered their utilization as petrochemical feedstocks. Except for their use in ethylene crackers, LPG fractions have traditionally been consumed as fuel. New catalytic processes now being commercialized open new avenues for the utilization of LPG as sources of valuable petrochemical intermediates. This paper discusses processes for the dehydrogenation and aromatization of LPG.

  20. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  1. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  2. Concentric catalytic combustor

    DOE Patents [OSTI]

    Bruck, Gerald J. (Oviedo, FL); Laster, Walter R. (Oviedo, FL)

    2009-03-24

    A catalytic combustor (28) includes a tubular pressure boundary element (90) having a longitudinal flow axis (e.g., 56) separating a first portion (94) of a first fluid flow (e.g., 24) from a second portion (95) of the first fluid flow. The pressure boundary element includes a wall (96) having a plurality of separate longitudinally oriented flow paths (98) annularly disposed within the wall and conducting respective portions (100, 101) of a second fluid flow (e.g., 26) therethrough. A catalytic material (32) is disposed on a surface (e.g., 102, 103) of the pressure boundary element exposed to at least one of the first and second portions of the first fluid flow.

  3. Catalytic nanoporous membranes

    DOE Patents [OSTI]

    Pellin, Michael J. (Naperville, IL); Hryn, John N. (Naperville, IL); Elam, Jeffrey W. (Elmhurst, IL)

    2009-12-01

    A nanoporous catalytic membrane which displays several unique features including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity.

  4. Sandia National Laboratories: About Sandia: History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History View as list Resources Sandia's government owned/contractor operated (GOCO) heritage Sandia history reports and publications Always/Never: The Quest for Safety, Control & Survivability For more information, contact the Corporate Historian Rebecca Ullrich.

  5. Catalytic reforming methods

    DOE Patents [OSTI]

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  6. Catalytic Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalytic Combustion Catalytic Combustion Advanced Catalytic Combustion System Reduces NOx Emissions Natural-gas-fired turbine systems currently require complex after-treatment systems to clean the exhaust of harmful emissions. Many of these emissions could be reduced by lower operating temperatures during the combustion process. With the support and recognition from many organizations, including AMO, the California Air Resources Board, the California Energy Commission, and the U.S.

  7. Novel Catalytic Membrane Reactors

    SciTech Connect (OSTI)

    Stuart Nemser, PhD

    2010-10-01

    There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

  8. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants...

  9. Catalytic Solutions Inc CSI | Open Energy Information

    Open Energy Info (EERE)

    Place: Oxnard, California Zip: 93033 Product: Developer of the breakthrough catalytic coating technology and the Mixed Phase Catalyst (MPCTM), and also manufacturer of catalytic...

  10. History Images

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Images Los Alamos History in Images Los Alamos has a proud history and heritage of almost 70 years of science and innovation. The people of the Laboratory work on advanced technologies to provide the best scientific and engineering solutions to many of the nation's most crucial security challenges. Click thumbnails to enlarge. Photos arranged by most recent first, horizontal formats before vertical. See Flickr for more sizes and details. Back in the day Back in the day LA bridge in Los

  11. History Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Gallery History Gallery Exhibits in this gallery capture Laboratory's history of the secret town of Los Alamos and its role with the Manhattan Project. August 18, 2014 museum plan showing the history gallery Los Alamos, once the site of a boys' ranch school, became the focus of the secret project to develop a new weapon, one that derived its power from splitting the atom. The Atomic Age begins The conflict that darkened Europe in the late 1930s at first cast no shadow here on the sunny

  12. ORISE: History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History The Oak Ridge Institute for Science and Education (ORISE) is a national leader in science education and research, with programs dating back to 1946 and having served as an...

  13. Workshop History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshop History The 2014 event is the seventh joint workshop held by the EFCOG ESH Electrical Safety subgroup. The first "joint" Electrical Safety Workshop was held in the summer...

  14. NERSC History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Console 19 BACK TO NERSC.GOV About this timeline Search Enter search term Go Displaying: All storiesX1 stories matching '' (clear) Close Category Filter Close View Type Standard...

  15. Catalytic Upgrading Sugars To Hydrocarbons | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sugars To Hydrocarbons Catalytic Upgrading Sugars To Hydrocarbons PDF on catalytic bioenergy process PDF icon Catalytic Upgrading Sugars To Hydrocarbons More Documents &...

  16. Beam History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beam History Print Beamline History Request Form To request a beam current histograph from the ALS storage ring beam histograph database, select the year, month, and day, then click on "Submit Request". Histographs are available as far back as February 2, 1994. Year 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Day 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17

  17. Beam History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beam Status Beam History Print Beamline History Request Form To request a beam current histograph from the ALS storage ring beam histograph database, select the year, month, and day, then click on "Submit Request". Histographs are available as far back as February 2, 1994. Year 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Day 01 02 03 04 05 06 07 08 09 10 11 12 13

  18. Beam History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beam History Print Beamline History Request Form To request a beam current histograph from the ALS storage ring beam histograph database, select the year, month, and day, then click on "Submit Request". Histographs are available as far back as February 2, 1994. Year 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Day 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17

  19. SCADA History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  20. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOE Patents [OSTI]

    Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

    2014-01-07

    A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

  1. Making History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    YGG 05-0181 Making History It's hard to imagine . . . . . . an entire city existing in secret. . . . 60,000 acres set aside for one, top-secret purpose. . . . a discovery so huge it could end a World War. It's hard to imagine - but it's true. Ray Smith * Y-12 Projects Division; Historian * oak riDge, tennessee Calutron: Designed by ernest orlando (e.o.) Lawrence to separate the isotopes of Uranium 235 (U-235) from naturally occurring uranium, where the majority is Uranium 238 (U-238). U-235 is

  2. Catalytic membranes for fuel cells

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

    2011-04-19

    A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

  3. Views of the solar system

    SciTech Connect (OSTI)

    Hamilton, C.

    1995-02-01

    Views of the Solar System has been created as an educational tour of the solar system. It contains images and information about the Sun, planets, moons, asteroids and comets found within the solar system. The image processing for many of the images was done by the author. This tour uses hypertext to allow space travel by simply clicking on a desired planet. This causes information and images about the planet to appear on screen. While on a planet page, hyperlinks travel to pages about the moons and other relevant available resources. Unusual terms are linked to and defined in the Glossary page. Statistical information of the planets and satellites can be browsed through lists sorted by name, radius and distance. History of Space Exploration contains information about rocket history, early astronauts, space missions, spacecraft and detailed chronology tables of space exploration. The Table of Contents page has links to all of the various pages within Views Of the Solar System.

  4. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Infrared Mapping Helps Optimize Catalytic Reactions Print Wednesday, 20 August 2014 07:59 A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ

  5. Catalytic oxidizers and Title V requirements

    SciTech Connect (OSTI)

    Uberoi, M.; Rach, S.E.

    1999-07-01

    Catalytic oxidizers have been used to reduce VOC emissions from various industries including printing, chemical, paint, coatings, etc. A catalytic oxidizer uses a catalyst to reduce the operating temperature for combustion to approximately 600 F, which is substantially lower than thermal oxidation unit. Title V requirements have renewed the debate on the best methods to assure compliance of catalytic oxidizers, with some suggesting the need for continuous emission monitoring equipment. This paper will discuss the various aspects of catalytic oxidation and consider options such as monitoring inlet/outlet temperatures, delta T across the catalyst, periodic laboratory testing of catalyst samples, and preventive maintenance procedures as means of assuring continuous compliance.

  6. Catalytic Device International LLC | Open Energy Information

    Open Energy Info (EERE)

    Pleasanton, California Product: California-based, firm focused on portable, heat-on-demand products. References: Catalytic Device International LLC1 This article is a stub....

  7. Plasma-assisted catalytic reduction system

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1998-01-27

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  8. BioCatalytics | Open Energy Information

    Open Energy Info (EERE)

    Biomass Product: BioCatalytics Inc. provides a broadest range of enzymes for chemical synthesis, especially biomass to biofuel enzymes along with the resources and technology to...

  9. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report You are accessing a document from the Department of Energy's (DOE)...

  10. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report In this Quarter, the research was focused continually on the...

  11. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 The research was...

  12. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 You are accessing a...

  13. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 You are accessing...

  14. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 In this Quarter, the...

  15. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report In this Quarter, the research was focused continually on the two...

  16. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report You are accessing a document from the Department of...

  17. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  18. Molecular catalytic hydrogenation of aromatic hydrocarbons and...

    Office of Scientific and Technical Information (OSTI)

    hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Citation Details In-Document Search Title: Molecular catalytic hydrogenation of aromatic hydrocarbons and...

  19. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems...

  20. Innovative Catalytic Converter Wins National Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Golden, Colo., July 25, 1996A new catalytic converter design that could dramatically reduce automobile emissions and urban air pollution has been named one of the years most ...

  1. Microchannel Reactor System for Catalytic Hydrogenation

    SciTech Connect (OSTI)

    2004-07-01

    Energy-Efficient Catalytic Hydrogenation Reactions. Hydrogenation reactions are very versatile and account for 10% to 20% of all reactions in the pharmaceutical industry.

  2. Center for Direct Catalytic Conversion of Biomass to Biofuels (C3Bio) |

    Office of Science (SC) Website

    U.S. DOE Office of Science (SC) Center for Direct Catalytic Conversion of Biomass to Biofuels (C3Bio) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Direct Catalytic Conversion of Biomass to Biofuels (C3Bio) Print Text Size: A A A FeedbackShare Page C3Bio Header Director Maureen McCann Lead Institution Purdue University Year Established 2009 Mission To

  3. Catalytic reactor with improved burner

    DOE Patents [OSTI]

    Faitani, Joseph J.; Austin, George W.; Chase, Terry J.; Suljak, George T.; Misage, Robert J.

    1981-01-01

    To more uniformly distribute heat to the plurality of catalyst tubes in a catalytic reaction furnace, the burner disposed in the furnace above the tops of the tubes includes concentric primary and secondary annular fuel and air outlets. The fuel-air mixture from the primary outlet is directed towards the tubes adjacent the furnace wall, and the burning secondary fuel-air mixture is directed horizontally from the secondary outlet and a portion thereof is deflected downwardly by a slotted baffle toward the tubes in the center of the furnace while the remaining portion passes through the slotted baffle to another baffle disposed radially outwardly therefrom which deflects it downwardly in the vicinity of the tubes between those in the center and those near the wall of the furnace.

  4. Non-catalytic recuperative reformer

    DOE Patents [OSTI]

    Khinkis, Mark J.; Kozlov, Aleksandr P.; Kurek, Harry

    2015-12-22

    A non-catalytic recuperative reformer has a flue gas flow path for conducting hot flue gas from a thermal process and a reforming mixture flow path for conducting a reforming mixture. At least a portion of the reforming mixture flow path is embedded in the flue gas flow path to permit heat transfer from the hot flue gas to the reforming mixture. The reforming mixture flow path contains substantially no material commonly used as a catalyst for reforming hydrocarbon fuel (e.g., nickel oxide, platinum group elements or rhenium), but instead the reforming mixture is reformed into a higher calorific fuel via reactions due to the heat transfer and residence time. In a preferred embodiment, extended surfaces of metal material such as stainless steel or metal alloy that are high in nickel content are included within at least a portion of the reforming mixture flow path.

  5. Method of fabricating a catalytic structure

    DOE Patents [OSTI]

    Rollins, Harry W.; Petkovic, Lucia M.; Ginosar, Daniel M.

    2009-09-22

    A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.

  6. History of Hydropower | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History of Hydropower History of Hydropower

  7. Nanoporous carbon catalytic membranes and method for making the same

    DOE Patents [OSTI]

    Foley, Henry C. (Hockessin, DE); Strano, Michael (Wilmington, DE); Acharya, Madhav (New Castle, DE); Raich, Brenda A. (Houston, TX)

    2002-01-01

    Catalytic membranes comprising highly-dispersed, catalytically-active metals in nanoporous carbon membranes and a novel single-phase process to produce the membranes.

  8. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants 2005 Diesel Engine...

  9. New Developments in Titania-Based Catalysts for Selective Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx New Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx Presentation...

  10. Passive Catalytic Approach to Low Temperature NOx Emission Abatement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce ...

  11. Molecular catalytic coal liquid conversion (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Conference: Molecular catalytic coal liquid conversion Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion This research, which is relevant to the...

  12. Molecular catalytic coal liquid conversion (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Conference: Molecular catalytic coal liquid conversion Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion You are accessing a document from...

  13. National Women's History Month

    Broader source: Energy.gov [DOE]

    NATIONAL WOMEN’S HISTORY MONTH is an annual declared month that highlights the contributions of women to events in history and contemporary society.

  14. Vacuum-insulated catalytic converter

    DOE Patents [OSTI]

    Benson, David K. (Golden, CO)

    2001-01-01

    A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

  15. Catalytic converter for automotive exhaust system

    SciTech Connect (OSTI)

    Merry, R.P.

    1986-10-14

    This patent describes a catalytic converter having a metallic casing, a unitary, solid ceramic catalytic element disposed within the casing, and resilient means disposed between the catalytic element and the metallic casing for positioning the catalytic element and for absorbing mechanical and thermal shock. The improvement described here comprises: the resilient means being a flexible intumescent planar sheet corrugated with a generally sinusoidal wave pattern along both its lengthwise edges. The corrugations are generally parallel and regular and are comprised of substantially equal ridges and hollows having a perimeter to frequency ratio in a range of 2.44 to 4.88 and amplitude in a range of 12 to 50% of the width of the sheet.

  16. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and optimization of the catalytic reaction. Research conducted by: E. Gross, X.-Z. Shu, S. Alayoglu, F.D. Toste, and G.A. Somorjai (Univ. of California, Berkeley), and H.A....

  17. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  18. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  19. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  20. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  1. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  2. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  3. Infrared Mapping Helps Optimize Catalytic Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  4. Department of Chemistry | Center for Catalytic Hydrocarbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionalization Chemistry Open Rank Faculty Position Faculty & Research Outreach Programs Graduate Studies Events & Seminars Undergraduate Studies Contact Us Faculty & Research > Research Centers & Programs > Center for Catalytic Hydrocarbon Functionalization CCHF Center for Catalytic Hydrocarbon Functionalization Catalysts are central to the efficient and clean utilization of energy resources, and they impact all aspects of the energy sector. With the University of

  5. Sandia National Laboratories: History: History Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facebook Twitter YouTube Flickr RSS About History Reports Building a Nuclear Ordnance Engineering Lab (slides from presentation to NSF Short Course "The Birthplace and Early...

  6. History of Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Org Chart NERSC History Interactive Timeline History of Systems NERSC Stakeholders Usage and User Demographics Careers Visitor Info Web Policies Home » About » NERSC History » History of Systems History of Systems Established in 1974 at Lawrence Livermore National Laboratory, NERSC was moved to Berkeley Lab in 1996 with a goal of increased interactions with the UC Berkeley campus. NERSC Systems System Name Installed System Type CPU Computational Pool Interconnect Disk (TB) Avg. Power Linpack

  7. JOBAID-VIEWING USER RECORDS

    Office of Energy Efficiency and Renewable Energy (EERE)

    In this job aid you will View To-Do List using Filter and View options, View Completed Work, and View Curriculum Status and Detials areas.

  8. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    W. R. Laster; E. Anoshkina

    2008-01-31

    Under the sponsorship of the U. S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1 - Implementation Plan, Phase 2 - Validation Testing and Phase 3 - Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

  9. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    Laster, W. R.; Anoshkina, E.

    2008-01-31

    Under the sponsorship of the U. S. Department of Energys National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1- Implementation Plan, Phase 2- Validation Testing and Phase 3 Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

  10. ThreatView

    Energy Science and Technology Software Center (OSTI)

    2007-09-25

    The ThreatView project is based on our prior work with the existing ParaView open-source scientific visualization application. Where ParaView provides a grapical client optimized scientific visualization over the VTK parallel client server architecture, ThreatView provides a client optimized for more generic visual analytics over the same architecture. Because ThreatView is based on the VTK parallel client-server architecture, data sources can reside on remote hosts, and processing and rendering can be performed in parallel. As seenmore » in Fig. 1, ThreatView provides four main methods for visualizing data: Landscape View, which displays a graph using a landscape metaphor where clusters of graph nodes produce "hills" in the landscape; Graph View, which displays a graph using a traditional "ball-and-stick" style; Table View, which displays tabular data in a standard spreadsheet; and Attribute View, which displays a tabular "histogram" of input data - for a selected table column, the Attribute View displays each unique value within the column, and the number of times that value appears in the data. There are two supplemental view types: Text View, which displays tabular data one-record-at-a-time; and the Statistics View, which displays input metadata, such as the number of vertices and edges in a graph, the number of rows in a table, etc.« less

  11. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  12. National Women's History Month

    Broader source: Energy.gov [DOE]

    During Women's History Month, we recall that the pioneering legacy of our grandmothers and great-grandmothers is revealed not only in our museums and history books, but also in the fierce...

  13. HISTORY OF BUILDING 828

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1997); and for a summary of the early history of Kirtland Air Force Base, see Don E. Alberts and Allan E. Putnam, A History of Kirtland Air Force Base 1928-1982 (Albuquerque:...

  14. BLACK HISTORY MONTH

    Broader source: Energy.gov [DOE]

    Black History Month is an annual celebration of achievements by black Americans and a time for recognizing the central role of African Americans in U.S. history. The event grew out of “Negro History Week,” created by historian Carter G. Woodson and other prominent African Americans. Other countries around the world, including Canada and the United Kingdom, also devote a month to celebrating black history.

  15. Process for catalytically oxidizing cycloolefins, particularly cyclohexene

    DOE Patents [OSTI]

    Mizuno, Noritaka (Sapporo, JP); Lyon, David K. (Bend, OR); Finke, Richard G. (Eugene, OR)

    1993-01-01

    This invention is a process for catalytically oxidizing cycloolefins, particularly cyclohexenes, to form a variety of oxygenates. The catalyst used in the process is a covalently bonded iridium-heteropolyanion species. The process uses the catalyst in conjunction with a gaseous oxygen containing gas to form 2-cyclohexen-1-ol and also 2-cyclohexen-1-one.

  16. Method of making a catalytic converter

    SciTech Connect (OSTI)

    Bailey, C.H.; De Palma, T.V.; Dillon, J.E.

    1982-08-10

    Arrangement for resiliently mounting a ceramic monolithic type catalytic converter element in a metal housing with a blanket of knit wire mesh material includes at least one circumferential band of high temperature intumescent material containing ceramic fibers positioned within the wire mesh blanket which prevents virtually all bypass leakage around the element and substantially reduces the temperature of the wire mesh.

  17. Performance characterization of a hydrogen catalytic heater.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Kanouff, Michael P.

    2010-04-01

    This report describes the performance of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to the GM Hydrogen Storage Demonstration System. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to a circulating heat transfer fluid. The fluid then transfers the heat to one or more of the four hydrogen storage modules that make up the Demonstration System to drive off the chemically bound hydrogen. The heater consists of three main parts: (1) the reactor, (2) the gas heat recuperator, and (3) oil and gas flow distribution manifolds. The reactor and recuperator are integrated, compact, finned-plate heat exchangers to maximize heat transfer efficiency and minimize mass and volume. Detailed, three-dimensional, multi-physics computational models were used to design and optimize the system. At full power the heater was able to catalytically combust a 10% hydrogen/air mixture flowing at over 80 cubic feet per minute and transfer 30 kW of heat to a 30 gallon per minute flow of oil over a temperature range from 100 C to 220 C. The total efficiency of the catalytic heater, defined as the heat transferred to the oil divided by the inlet hydrogen chemical energy, was characterized and methods for improvement were investigated.

  18. Production of LPG olefins by catalytic dehydrogenation

    SciTech Connect (OSTI)

    Pujado, P.R.; Vora, B.V.

    1984-09-01

    Catalytic dehydrogenation allows for the production of specific olefins thus avoiding the large capital and operating expenses associated with the recovery and processing of the many by-products from pyrolysis units. The chemistry of the process is discussed along with the process economics.

  19. A Photosynthetic Hydrogel for Catalytic Hydrogen Production | ANSER Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Argonne-Northwestern National Laboratory A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production

  20. History of Wind Energy | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History of Wind Energy History of Wind Energy

  1. History of Wind Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History of Wind Energy History of Wind Energy

  2. History | Department of Energy

    Energy Savers [EERE]

    About Us » History History The following is a short history recounting the evolution of the project management office within the Department of Energy: The project management office was originally called the Office of Field Management (FM) and was under the purview of the Office of the Chief Financial Officer in the 1990s. In the fiscal year 2000 Energy & Water Development Appropriations, the Senate initiated and the House concurred to eliminate funding for DOE's Office of Field Management.

  3. Method and apparatus for a catalytic firebox reactor

    DOE Patents [OSTI]

    Smith, Lance L. (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Ulkarim, Hasan (Hamden, CT); Castaldi, Marco J. (Bridgeport, CT); Pfefferle, William C. (Madison, CT)

    2001-01-01

    A catalytic firebox reactor employing an exothermic catalytic reaction channel and multiple cooling conduits for creating a partially reacted fuel/oxidant mixture. An oxidation catalyst is deposited on the walls forming the boundary between the multiple cooling conduits and the exothermic catalytic reaction channel, on the side of the walls facing the exothermic catalytic reaction channel. This configuration allows the oxidation catalyst to be backside cooled by any fluid passing through the cooling conduits. The heat of reaction is added to both the fluid in the exothermic catalytic reaction channel and the fluid passing through the cooling conduits. After discharge of the fluids from the exothermic catalytic reaction channel, the fluids mix to create a single combined flow. A further innovation in the reactor incorporates geometric changes in the exothermic catalytic reaction channel to provide streamwise variation of the velocity of the fluids in the reactor.

  4. Catalytic fast pyrolysis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

    2014-11-21

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuelbio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

  5. Preface: Challenges for Catalytic Exhaust Aftertreatment

    SciTech Connect (OSTI)

    Nova, Isabella; Epling, Bill; Peden, Charles HF

    2014-03-31

    This special issue of Catalysis Today continues the tradition established since the 18th NAM in Cancun, 2003, of publishing the highlights coming from these catalytic after-treatment technologies sessions, where this volume contains 18 papers based on oral and poster presentations of the 23rd NAM, 2013. The guest editors would like to thank all of the catalyst scientists and engineers who presented in the "Emission control" sessions, and especially the authors who contributed to this special issue of Catalysis Today.

  6. Pulsating catalytic combustion of gaseous fuels

    SciTech Connect (OSTI)

    Gal-Ed, R.

    1988-01-01

    This study investigated the feasibility of operating catalytic combustors under pulsating conditions and the circumstances under which acoustic pulsations increase the combustion efficiencies and output of catalytic combustors. An experimental catalytic combustor was developed, and a theoretical model of acoustic motions in non-isothermal, low match number, duct flow was used to predict the acoustic behavior of the combustor. The effects of pulsations were determined by comparing temperature and species concentration data measured during operation with pulsations at different frequencies and pressure amplitudes to similar data measured during non-pulsating combustion. Experiments conducted with lean mixtures of methane or propane with air revealed that acoustic pulsations affected the temperature distribution along the combustor at flow Reynolds numbers less than 17,500. Excitation of pulsations during methane combustion caused shifts in the location of the combustion, and sometimes the onset of extinction of gas phase reactions. This occurred when several catalyst segments were located in the combustion section between an upstream pressure node and a downstream velocity node, defined here as an in phase location. Propane mixtures were used to investigate possible improvements in combustor's performance. Burning propane mixtures on a single catalyst segment at an in phase location showed that the excitation of acoustic pulsations increased the combustion efficiency by 10 to 50%. The changes in the operation of catalytic combustors caused by acoustic waves are explained by acoustic streaming. When the catalyst surfaces are at an in phase location, rotational flows caused by acoustic streaming enhance the reactants and products diffusion rate to and from the catalyst surfaces, respectively, improving combustion efficiency.

  7. Catalytic extraction processing of contaminated scrap metal

    SciTech Connect (OSTI)

    Griffin, T.P.; Johnston, J.E.; Payea, B.M.; Zeitoon, B.M.

    1995-12-01

    Molten Metal Technology was awarded a contract to demonstrate the applicability of the Catalytic Extraction Process, a proprietary process that could be applied to US DOE`s inventory of low level mixed waste. This paper is a description of that technology, and included within this document are discussions of: (1) Program objectives, (2) Overall technology review, (3) Organic feed conversion to synthetic gas, (4) Metal, halogen, and transuranic recovery, (5) Demonstrations, (6) Design of the prototype facility, and (7) Results.

  8. Microscale acceleration history discriminators

    DOE Patents [OSTI]

    Polosky, Marc A. (Albuquerque, NM); Plummer, David W. (Albuquerque, NM)

    2002-01-01

    A new class of micromechanical acceleration history discriminators is claimed. These discriminators allow the precise differentiation of a wide range of acceleration-time histories, thereby allowing adaptive events to be triggered in response to the severity (or lack thereof) of an external environment. Such devices have applications in airbag activation, and other safety and surety applications.

  9. Hanford History - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Hanford History About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Contact Us Hanford History Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size The Hanford Site sits on 586-square-miles of shrub-steppe desert in southeastern Washington State. Beginning in 1943, the site was used to produce plutonium for the bomb that brought an end to World War II. After a short lull, production was ramped up in 1947 to meet the challenges of the

  10. History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About Energy.gov » History History What's New in History July 28, 2015: Draft Memorandum of Agreement between DOE and NPS posted July 28, 2015: Draft Memorandum of Agreement between DOE and NPS posted The NPS posts for comment the draft Memorandum of Agreement between DOE and NPS on its Planning, Environment and Public Comment (PEPC) site. The Park Service also provides a list of Frequently Asked Questions and maps with the initial properties to be included in the park. Read more May 29, 2015:

  11. Taking the long view

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Taking the long view Taking the long view on environmental stewardship A newly articulated mission for environmental stewardship at the Laboratory can be summed up in a simple phrase: clean up the past, control current operations, and create a sustainable future. March 20, 2012 Los Alamos Aerial Aerial view of a canyon in Los Alamos, New Mexico. Contact Environmental Communication & Public Outreach P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email "The future viability of

  12. Departmental History Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1992-03-26

    The order describes the DOE history program and establishes policy and objectives for the preservation of historical records and institutional memory for DOE and its predecessor agencies. Cancels DOE 1324.7.

  13. Black History Month

    Broader source: Energy.gov [DOE]

    During National African American History Month, we pay tribute to the contributions of past generations and reaffirm our commitment to keeping the American dream alive for the next generation. In...

  14. About SRNL - Our History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From the Director Operational Excellence Leadership Directorates Our History Visiting SRNL SRNL Home SRNL historic image SRNL historic image About SRNL Our History Evolution of SRNL's Department of Energy Role The Savannah River Site was constructed to produce the basic materials necessary in the fabrication of nuclear weapons, primarily tritium and plutonium-239. Five reactors were also built in an effort to produce these materials for our nation's defense programs. In support of these efforts,

  15. History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History History The Better Buildings Neighborhood Program was first announced by Vice President Biden as "Retrofit Ramp-Up" on April 21, 2010. The program presented initial awards of $452 million in American Recovery and Reinvestment Act (ARRA or Recovery Act) funding to 25 state and local governments to "ramp up" energy efficiency building retrofits. The Better Buildings Neighborhood Program then distributed a total of $508 million to support hundreds of communities served

  16. History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About » History History This timeline features the key innovations that have advanced the solar industry in the United States. Learn more about these key events from 1955 to present. To see more details, either drag the timeline to the left or right or click the (+) icons. Solar Achievements Timeline INSTRUCTIONS Instructional graphic for mouse use. Click and drag screen or scroll mouse wheel to navigate through timeline. 2011 INDUSTRY Graphic of the U.S. Department of Energy logo. A yellow,

  17. History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History History 2015 JULY Mark McCall hired as Executive Director, Loan Programs Office JUNE Loan guarantees issued for Vogtle (MEAG Power) MARCH Conditional commitment for ATVM loan offered to Alcoa FEBRUARY Powering New Markets: Utility-scale Photovoltaic Solar report released 2014 DECEMBER Agua Caliente awarded 2014 Top Plant (Solar) - POWER Magazine Ivanpah awarded Renewable Energy Project of the Year - Pennwell Crescent Dunes awarded Project of the Year, Best Energy/Industrial &

  18. Taking the long view

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2012 Los Alamos Aerial Aerial view of a canyon in Los Alamos, New Mexico. Contact Environmental Communication & Public Outreach P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505)...

  19. History of Women at the Energy Department | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Women at the Energy Department History of Women at the Energy Department March 27, 2014 - 5:55pm Addthis Dot Harris Dot Harris Director, Office of Economic Impact and Diversity Terry Fehner Terry Fehner Historian, Federal Preservation Officer Women have been making a significant impact in science, technology, engineering and mathematics (STEM) fields for centuries. Join the Energy Department in celebrating Women's History Month by viewing this timeline for a glimpse of the accomplishments of

  20. In-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect In-Situ Catalytic Fast Pyrolysis Technology Pathway Citation Details In-Document Search Title: In-Situ Catalytic Fast Pyrolysis Technology Pathway This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have

  1. Passive Catalytic Approach to Low Temperature NOx Emission Abatement |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle PDF icon deer11_henry.pdf More Documents & Publications Advanced Technology Light Duty Diesel Aftertreatment System Cummins' Next Generation Tier 2, Bin 2 Light

  2. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Ex-Situ Catalytic Fast Pyrolysis Technology Pathway Citation Details In-Document Search Title: Ex-Situ Catalytic Fast Pyrolysis Technology Pathway This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have

  3. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway Citation Details In-Document Search Title: Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs

  4. 15.02.10 RH Transparent Catalytic - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Catalytic Nickel Oxide Protecting Films for Photoanodes Sun, K. et al. Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films. PNAS 112 ( 12), 3612-3617, DOI: 10.1073/ pnas . 1423034112 (2015). Scientific Achievement Reactively sputtered NiOx layer provides a transparent, anti-reflective, conductive, chemically stable, inherently catalytic coating that stabilizes many efficient and technologically important

  5. Measurement of diesel solid nanoparticle emissions using a catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    stripper for comparison with Europe's PMP protocol | Department of Energy diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Measurement of diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Evaluation and comparison of the measurements of diesel solid nanoparticle emissions using the European Particle Measurement Programme (PMP) system and catalytic stripper PDF icon deer11_jung.pdf

  6. Hydrogen-assisted catalytic ignition characteristics of different fuels

    SciTech Connect (OSTI)

    Zhong, Bei-Jing; Yang, Fan; Yang, Qing-Tao

    2010-10-15

    Hydrogen-assisted catalytic ignition characteristics of methane (CH{sub 4}), n-butane (n-C{sub 4}H{sub 10}) and dimethyl ether (DME) were studied experimentally in a Pt-coated monolith catalytic reactor. It is concluded that DME has the lowest catalytic ignition temperature and the least required H{sub 2} flow, while CH{sub 4} has the highest catalytic ignition temperature and the highest required H{sub 2} flow among the three fuels. (author)

  7. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Opportunity Fuels This fact sheet provides an overview of the Next Generation Manufacturing Processes project to develop a unique, fuel-flexible catalytic combustor...

  8. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  9. Measurement of diesel solid nanoparticle emissions using a catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particle Measurement Programme (PMP) system and catalytic stripper PDF icon deer11jung.pdf More Documents & Publications Evaluation of the European PMP Methodologies Using ...

  10. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Pathway This technology pathway case investigates the catalytic conversion of ... Process Design and Economics for the Conversion of Lignocellulosic Biomass to ...

  11. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Office of Scientific and Technical Information (OSTI)

    the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

  12. Comparison of Water-Hydrogen Catalytic Exchange Processes vs...

    Office of Environmental Management (EM)

    at Tritium Focus Group Meeting, April 22-24, 2014, Aiken, SC COMPARISON OF WATER-HYDROGEN CATALYTIC EXCHANGE PROCESSES VERSUS WATER DISTILLATION FOR WATER DETRITIATION A. Busigin,...

  13. Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduction | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2 Reduction

  14. Piloted rich-catalytic lean-burn hybrid combustor

    DOE Patents [OSTI]

    Newburry, Donald Maurice (Orlando, FL)

    2002-01-01

    A catalytic combustor assembly which includes, an air source, a fuel delivery means, a catalytic reactor assembly, a mixing chamber, and a means for igniting a fuel/air mixture. The catalytic reactor assembly is in fluid communication with the air source and fuel delivery means and has a fuel/air plenum which is coated with a catalytic material. The fuel/air plenum has cooling air conduits passing therethrough which have an upstream end. The upstream end of the cooling conduits is in fluid communication with the air source but not the fuel delivery means.

  15. DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins...

    Office of Scientific and Technical Information (OSTI)

    DFT Investigation of the Catalytic Hydromethylation ofalpha-Olefins bvy Metallocenes. 1. Difference betrween Scandium andLutetium in Propene Hydromethylation Citation Details ...

  16. In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified. In-Situ Catalytic Fast Pyrolysis Technology Pathway...

  17. Catalytic reactor for low-Btu fuels

    DOE Patents [OSTI]

    Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

    2009-04-21

    An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

  18. ARM Orientation: Overview and History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Orientation: ARM Orientation: Overview and History Overview and History Mar 2007 ARM Orientation 2 ARM ARM Atmospheric Radiation Measurement Atmospheric Radiation Measurement ...

  19. TotalView Training 2015

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TotalView Training 2015 TotalView Training 2015 NERSC will host an in-depth training course on TotalView, a graphical parallel debugger developed by Rogue Wave Software, on...

  20. ESnet IPv6 History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Engineering Services The Network OSCARS Fasterdata IPv6 Network IPv6 Implementation Checklist ESnet IPv6 Mirror Servers ESnet IPv6 History ESnet supports Sandia and APNIC IPv6 Background Radiation research Network Performance Tools The ESnet Engineering Team Contact Us Technical Assistance: 1 800-33-ESnet (Inside US) 1 800-333-7638 (Inside US) 1 510-486-7600 (Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site Feedback: info@es.net ESnet IPv6

  1. LANSCE | About | History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History The History of LANSCE Since 1972, the 800-million-electron-volt (MeV) accelerator and its attendant facilities at Technical Area 53 (TA-53, often referred to as "the Mesa") at Los Alamos National Laboratory have been a resource to a broad international community of scientific researchers. The Los Alamos Meson Physics Facility (LAMPF), as it was originally called, hosted about 1000 users per year to to perform medium energy physics experiments. In 1977, a pulsed spallation

  2. History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History History Although they are tiny, atoms have a large amount of energy holding their nuclei together. Certain isotopes of some elements can be split and will release part of their energy as heat. This splitting is called fission. The heat released in fission can be used to help generate electricity in powerplants. Uranium-235 (U-235) is one of the isotopes that fissions easily. During fission, U-235 atoms absorb loose neutrons. This causes U-235 to become unstable and split into two light

  3. History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History History The U. S. Army Corps of Engineers began acquiring land, in the area that became Oak Ridge, in October 1942 for the Manhattan Project. By March 1943, 56,000 acres were sealed behind fences and major industrial facilities were under construction. The K-25, S-50, and Y-12 plants were all built to separate the fissile isotope uranium-235 from uranium-238, while the X-10 site was established as a pilot plant for the Graphite Reactor. Throughout the next six decades the three major

  4. Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons | Department of Energy 4 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Argonne National Laboratory PDF icon 2004_deer_marshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction

  5. Catalytic cartridge SO.sub.3 decomposer

    DOE Patents [OSTI]

    Galloway, Terry R. (Berkeley, CA)

    1982-01-01

    A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO.sub.3 decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO.sub.3 gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO.sub.3 gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety.

  6. Catalytic cartridge SO.sub.3 decomposer

    DOE Patents [OSTI]

    Galloway, Terry R. (Berkeley, CA)

    1982-01-01

    A catalytic cartridge internally heated is utilized as a SO.sub.3 decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO.sub.3 gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube being internally heated. In the axial-flow cartridge, SO.sub.3 gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and being internally heated. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety.

  7. Catalytic cartridge SO/sub 3/ decomposer

    DOE Patents [OSTI]

    Galloway, T.R.

    1980-11-18

    A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

  8. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  9. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  10. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  11. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  12. Make the most of catalytic hydrogenations

    SciTech Connect (OSTI)

    Landert, J.P.; Scubla, T. [Biazzi S.A., Chailly-Montreux (Switzerland)

    1995-03-01

    Liquid-phase catalytic hydrogenation is one of the most useful and versatile reactions available for organic synthesis. Because it is environmentally clean, it has replaced other reduction processes, such as the Bechamp reaction, and zinc and sulfide reductions. Moreover, the economics are favorable, provided that raw materials free of catalyst poisons are used. The hydrogenation reaction is very selective with appropriate catalysts and can often be carried out without a solvent. Applications include reduction of unsaturated carbon compounds to saturated derivatives (for example, in vegetable-oil processing), carbonyl compounds to alcohols (such as sorbitol), and nitrocompounds to amines. the reactions are usually run in batch reactors to rapidly reach complete conversion and allow quick change-over of products. The paper describes the basics of hydrogenation; steering clear of process hazards; scale-up and optimization; and system design in practice.

  13. Biofuel from fast pyrolysis and catalytic hydrodeoxygenation.

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2015-09-04

    This review addresses recent developments in biomass fast pyrolysis bio-oil upgrading by catalytic hydrotreating. The research in the field has expanded dramatically in the past few years with numerous new research groups entering the field while existing efforts from others expand. The issues revolve around the catalyst formulation and operating conditions. Much work in batch reactor tests with precious metal catalysts needs further validation to verify long-term operability in continuous flow systems. The effect of the low level of sulfur in bio-oil needs more study to be better understood. Utilization of the upgraded bio-oil for feedstock to finished fuels is still in an early stage of understanding.

  14. Quantum histories without contrary inferences

    SciTech Connect (OSTI)

    Losada, Marcelo; Laura, Roberto

    2014-12-15

    In the consistent histories formulation of quantum theory it was shown that it is possible to retrodict contrary properties. We show that this problem do not appear in our formalism of generalized contexts for quantum histories. - Highlights: We prove ordinary quantum mechanics has no contrary properties. Contrary properties in consistent histories are reviewed. We prove generalized contexts for quantum histories have no contrary properties.

  15. Simulation of catalytic oxidation and selective catalytic NOx reduction in lean-exhaust hybrid vehicles

    SciTech Connect (OSTI)

    Gao, Zhiming; Daw, C Stuart; Chakravarthy, Veerathu K

    2012-01-01

    We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel powered hybrid vehicles. The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust. Our results illustrate the potential impact of DOC and SCR interactions for lean hybrid electric and plug-in hybrid electric vehicles.

  16. Highlights of Y-12's History | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights of Y-12's ... Highlights of Y-12's History Click a decade at right to show its highlights. Click again to hide. View highlights by decade since Y-12's initial planning...

  17. Y-12's history captured in short film | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    To close out the celebration of Y-12's 70th anniversary, a short film capturing highlights of the site's history now is available for viewing on the Y-12 public Web site at http:...

  18. History of Air Conditioning

    Broader source: Energy.gov [DOE]

    We take it for granted but what would life be like without the air conditioner? Once considered a luxury, this invention is now an essential, allowing us to cool everything from homes, businesses, businesses, data centers, laboratories and other buildings vital to our daily lives. Explore this timeline to learn some of the key dates in the history of air conditioning.

  19. Stereoscopic optical viewing system

    DOE Patents [OSTI]

    Tallman, Clifford S. (Walnut Creek, CA)

    1987-01-01

    An improved optical system which provides the operator a stereoscopic viewing field and depth of vision, particularly suitable for use in various machines such as electron or laser beam welding and drilling machines. The system features two separate but independently controlled optical viewing assemblies from the eyepiece to a spot directly above the working surface. Each optical assembly comprises a combination of eye pieces, turning prisms, telephoto lenses for providing magnification, achromatic imaging relay lenses and final stage pentagonal turning prisms. Adjustment for variations in distance from the turning prisms to the workpiece, necessitated by varying part sizes and configurations and by the operator's visual accuity, is provided separately for each optical assembly by means of separate manual controls at the operator console or within easy reach of the operator.

  20. Stereoscopic optical viewing system

    DOE Patents [OSTI]

    Tallman, C.S.

    1986-05-02

    An improved optical system which provides the operator with a stereoscopic viewing field and depth of vision, particularly suitable for use in various machines such as electron or laser beam welding and drilling machines. The system features two separate but independently controlled optical viewing assemblies from the eyepiece to a spot directly above the working surface. Each optical assembly comprises a combination of eye pieces, turning prisms, telephoto lenses for providing magnification, achromatic imaging relay lenses and final stage pentagonal turning prisms. Adjustment for variations in distance from the turning prisms to the workpiece, necessitated by varying part sizes and configurations and by the operator's visual accuity, is provided separately for each optical assembly by means of separate manual controls at the operator console or within easy reach of the operator.

  1. Energy/Water History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  2. History - 88-Inch Cyclotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Lawrence's original Cyclotron, for which he received a patent and the Nobel Prize. Lawrence's original cyclotron design was limited to energies where relativistic effects were not important. The third generation cyclotron included "sector-focusing" to allow higher energies to be obtained. The 88-Inch Cyclotron was based on Lawrence's design of a sector-focused cyclotron for the MTA project at Livermore. 1500 man-hours of work were necessary to assemble the trim coils which help

  3. History of the Lightbulb | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lightbulb History of the Lightbulb Read more about the History of the Light Bulb.

  4. Catalytic Reactor For Oxidizing Mercury Vapor

    DOE Patents [OSTI]

    Helfritch, Dennis J.

    1998-07-28

    A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

  5. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christopher P; Boldingh, Edwin P

    2014-10-07

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  6. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christpher P; Boldingh, Edwin P

    2013-12-17

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  7. ARM Orientation: Overview and History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mar 2007 ARM Orientation 14 Where did ARM come from? Where did ARM come from? A nutshell history A nutshell history ICRCCM-1: Intercomparison of Radiation Codes in Climate Models...

  8. Our History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History Our History Our History The history of Office of Electricity Delivery and Energy Reliability (OE) begins in August 2003, when the Department created two offices to provide focus in several critical areas: the Office of Electric Transmission and Distribution (TD), which included elements from the DOE Energy Efficiency and Renewable Energy office and the DOE Policy and International Affairs office, to advance the technologies needed to ensure a reliable, robust and modern U.S. electricity

  9. History Publications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History Publications History Publications History Publications Since its establishment in 1957, the Office of History and Heritage Resources (OHHR) has consistently sought to maintain a level of excellence in its publications that meets all scholarly standards and yet is accessible to the general public. At the same time, OHHR has partnered with DOE program offices and field sites to provide historical products that are useful and fill specific departmental needs. In this effort, OHHR has

  10. Control of Substrate Access to the Active Site and Catalytic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control of Substrate Access to the Active Site and Catalytic Mechanism of Methane and Toluene Monooxygenases Friday, June 22, 2012 - 3:30pm SSRL Main Conference Room 137-322 Prof....

  11. Printing 3D Catalytic Devices | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printing 3D Catalytic Devices An error occurred. Try watching this video on www.youtube.com, or enable JavaScript if it is disabled in your browser. Ames Laboratory scientist Igor...

  12. Hydrogen permeable protective coating for a catalytic surface

    DOE Patents [OSTI]

    Liu, Ping (Irvine, CA); Tracy, C. Edwin (Golen, CO); Pitts, J. Roland (Lakewood, CO); Lee, Se-Hee (Lakewood, CO)

    2007-06-19

    A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

  13. The View from HQ

    National Nuclear Security Administration (NNSA)

     NA-ASC-500-07 Issue 2 January 2007 The View from HQ Sitting in airports and planes is risky beyond the obvious dangers now in the news. Uninter- rupted time to think may lead to new ideas. Instinct instructs us that when we hear Wash- ington has some new ideas, the result must be bad. After all, ideas suggest change, which is inherently disruptive. Today the notion of predictivity is on my mind as I am leaving the V&V 2007 meeting in Los Alamos. Predictivity is on my short list of

  14. The View from HQ

    National Nuclear Security Administration (NNSA)

    A publication of the Office of Advanced Simulation & Computing, NNSA Defense Programs NA-ASC-500-07-Issue 3 May 2007 The View from HQ by Dimitri Kusnezov I have been spending much of my time these days thinking about science, technology and engineering and the role of the laboratories and how that will be reflected in the Complex of the future. This is on my mind for two reasons: one is my responsibility to produce a science and technology roadmap for Complex 2030-Defense Program's vision

  15. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    Broader source: Energy.gov [DOE]

    This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

  16. Northwestern University Facility for Clean Catalytic Process Research

    SciTech Connect (OSTI)

    Marks, Tobin Jay

    2013-05-08

    Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

  17. Reactive and Catalytic Air Purification Materials - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search Reactive and Catalytic Air Purification Materials Naval Research Laboratory Contact NRL About This Technology Publications: PDF Document Publication AirPurification (546 KB) Technology Marketing SummarySorbents for the removal of toxic in-dustrial gases such as ammonia and phosgene. The materials offer reactive and/or catalytic sites within a high surface

  18. Long Wavelength Catalytic Infrared Drying System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Long Wavelength Catalytic Infrared Drying System Long Wavelength Catalytic Infrared Drying System New Infrared Drying System Removes Moisture More Efficiently Without Heating Surrounding Air Conventional drying systems for wood particulates, typically in the form of sawdust or chips, currently employ a rotary drum dryer that shoots a raw flame through a 20' to 30' rotating drum while tumbling the wood product. Product scorching and air emission problems, particularly with carbon, NOx, and

  19. Briefly Bound to Activate: Transient Binding of a Second Catalytic

    Office of Scientific and Technical Information (OSTI)

    Magnesium Activates the Structure and Dynamics of CDK2 Kinase for Catalysis (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Briefly Bound to Activate: Transient Binding of a Second Catalytic Magnesium Activates the Structure and Dynamics of CDK2 Kinase for Catalysis Citation Details In-Document Search Title: Briefly Bound to Activate: Transient Binding of a Second Catalytic Magnesium Activates the Structure and Dynamics of CDK2 Kinase for Catalysis We have

  20. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of

    Office of Scientific and Technical Information (OSTI)

    mixed polymer waste streams to sequentially recover monomers or other high value products (Patent) | SciTech Connect catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products Citation Details In-Document Search Title: Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products A process of using fast

  1. New Developments in Titania-Based Catalysts for Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction of NOx | Department of Energy Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx New Developments in Titania-Based Catalysts for Selective Catalytic Reduction of NOx Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_chapman.pdf More Documents & Publications The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR

  2. Catalytic Conversion of Bioethanol to Hydrocarbons - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Startup America Startup America Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Catalytic Conversion of Bioethanol to Hydrocarbons Oak Ridge National Laboratory Contact ORNL About This Technology Publications: PDF Document Publication 11-G00219_ID2414.pdf (629 KB) Technology Marketing SummaryA method for catalytically converting an alcohol to a hydrocarbon without requiring

  3. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials | Department of Energy Materials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_25_peden.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber

  4. Dynamic Electronic Control of Catalytic Converters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electronic Control of Catalytic Converters Dynamic Electronic Control of Catalytic Converters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_stout.pdf More Documents & Publications Commonalities between Non-road and On-road Diesel Emissions Diesel Injection Shear-Stress

  5. Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons | Department of Energy 3 DEER Conference Presentation: Argonne National Laboratory PDF icon 2003_deer_marshall.pdf More Documents & Publications Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems

  6. DOE - Office of Legacy Management -- Catalytic Co - PA 40

    Office of Legacy Management (LM)

    Catalytic Co - PA 40 FUSRAP Considered Sites Site: Catalytic Co. (PA.40 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Philadelphia , Pennsylvania PA.40-1 Evaluation Year: 1991 PA.40-1 Site Operations: Prime contractor for construction of the Fernald facility. Records indicate one time shipment of a very small quantity (4 lbs) of uranium metal to this site. PA.40-1 Site Disposition: Eliminated - Construction contractor -

  7. September 2013 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy, Office of Scientific and Technical Information September 2013 Most Viewed Documents for Fossil Fuels Science Subject Feed EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 42 /> Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. (1996) 36 /> Fluid Dynamics in Sucker Rod Pumps Cutler, R.P.; Mansure, A.J. (1999) 35 />

  8. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2000-01-01

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  9. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2002-01-01

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  10. Protective laser beam viewing device

    DOE Patents [OSTI]

    Neil, George R.; Jordan, Kevin Carl

    2012-12-18

    A protective laser beam viewing system or device including a camera selectively sensitive to laser light wavelengths and a viewing screen receiving images from the laser sensitive camera. According to a preferred embodiment of the invention, the camera is worn on the head of the user or incorporated into a goggle-type viewing display so that it is always aimed at the area of viewing interest to the user and the viewing screen is incorporated into a video display worn as goggles over the eyes of the user.

  11. False color viewing device

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08

    This invention consists of a viewing device for observing objects in near-infrared false-color comprising a pair of goggles with one or more filters in the apertures, and pads that engage the face for blocking stray light from the sides so that all light reaching, the user`s eyes come through the filters. The filters attenuate most visible light and pass near-infrared (having wavelengths longer than approximately 700 nm) and a small amount of blue-green and blue-violet (having wavelengths in the 500 to 520 nm and shorter than 435 nm, respectively). The goggles are useful for looking at vegetation to identify different species and for determining the health of the vegetation, and to detect some forms of camouflage.

  12. False color viewing device

    DOE Patents [OSTI]

    Kronberg, J.W.

    1992-10-20

    A viewing device for observing objects in near-infrared false-color comprising a pair of goggles with one or more filters in the apertures, and pads that engage the face for blocking stray light from the sides so that all light reaching the user's eyes come through the filters. The filters attenuate most visible light and pass near-infrared (having wavelengths longer than approximately 700 nm) and a small amount of blue-green and blue-violet (having wavelengths in the 500 to 520 nm and shorter than 435 nm, respectively). The goggles are useful for looking at vegetation to identify different species and for determining the health of the vegetation, and to detect some forms of camouflage. 7 figs.

  13. False color viewing device

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1992-01-01

    A viewing device for observing objects in near-infrared false-color comprising a pair of goggles with one or more filters in the apertures, and pads that engage the face for blocking stray light from the sides so that all light reaching the user's eyes come through the filters. The filters attenuate most visible light and pass near-infrared (having wavelengths longer than approximately 700 nm) and a small amount of blue-green and blue-violet (having wavelengths in the 500 to 520 nm and shorter than 435 nm, respectively). The goggles are useful for looking at vegetation to identify different species and for determining the health of the vegetation, and to detect some forms of camouflage.

  14. Catalytic Behavior of Dense Hot Water

    SciTech Connect (OSTI)

    Wu, C J; Fried, L E; Yang, L H; Goldman, N; Bastea, S

    2008-06-05

    Water is known to exhibit fascinating physical properties at high pressures and temperatures. Its remarkable structural and phase complexity suggest the possibility of exotic chemical reactivity under extreme conditions, though this remains largely unstudied. Detonations of high explosives containing oxygen and hydrogen produce water at thousands of K and tens of GPa, similar to conditions of giant planetary interiors. These systems thus provide a unique means to elucidate the chemistry of 'extreme water'. Here we show that water plays an unexpected role in catalyzing complex explosive reactions - contrary to the current view that it is simply a stable detonation product. Using first-principles atomistic simulations of the detonation of high explosive pentaerythritol tetranitrate (PETN), we discovered that H{sub 2}O (source), H (reducer) and OH (oxidizer) act as a dynamic team that transports oxygen between reaction centers. Our finding suggests that water may catalyze reactions in other explosives and in planetary interiors.

  15. Mountain View Grand | Open Energy Information

    Open Energy Info (EERE)

    Mountain View Grand Jump to: navigation, search Name Mountain View Grand Facility Mountain View Grand Sector Wind energy Facility Type Small Scale Wind Facility Status In Service...

  16. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  17. ARM - Climate Change Through History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Change Through History Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Climate Change Through History Scientists know that there have been many climatic changes throughout the earth's history. For example, the overall temperature across the globe is at least 5.5 degrees Celsius (10 degrees

  18. Our History | Department of Energy

    Energy Savers [EERE]

    About Us » Our History Our History The Office of Hearings and Appeals is the central adjudicative forum for the Department of Energy. The Secretary of Energy has delegated to the OHA Director the authority to act for him in many different areas. The OHA Director's decision typically serves as final agency action. During it's over 30-year history, OHA has had broad-ranging subject matter jurisdiction. Originally, OHA's primary function was to consider exceptions and other petitions related to

  19. Fermilab | Tritium at Fermilab | Ferry Creek Aerial View

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ferry Creek Aerial View Ferry Creek Aerial View

  20. Fermilab | Tritium at Fermilab | Kress Creek Aerial View

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kress Creek Aerial View Kress Creek Aerial View

  1. Method for measuring recovery of catalytic elements from fuel cells

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley, NJ)

    2011-03-08

    A method is provided for measuring the concentration of a catalytic clement in a fuel cell powder. The method includes depositing on a porous substrate at least one layer of a powder mixture comprising the fuel cell powder and an internal standard material, ablating a sample of the powder mixture using a laser, and vaporizing the sample using an inductively coupled plasma. A normalized concentration of catalytic element in the sample is determined by quantifying the intensity of a first signal correlated to the amount of catalytic element in the sample, quantifying the intensity of a second signal correlated to the amount of internal standard material in the sample, and using a ratio of the first signal intensity to the second signal intensity to cancel out the effects of sample size.

  2. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    SciTech Connect (OSTI)

    Eteman, Shahrokh

    2013-06-30

    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  3. New process model proves accurate in tests on catalytic reformer

    SciTech Connect (OSTI)

    Aguilar-Rodriguez, E.; Ancheyta-Juarez, J. )

    1994-07-25

    A mathematical model has been devised to represent the process that takes place in a fixed-bed, tubular, adiabatic catalytic reforming reactor. Since its development, the model has been applied to the simulation of a commercial semiregenerative reformer. The development of mass and energy balances for this reformer led to a model that predicts both concentration and temperature profiles along the reactor. A comparison of the model's results with experimental data illustrates its accuracy at predicting product profiles. Simple steps show how the model can be applied to simulate any fixed-bed catalytic reformer.

  4. Highland View school | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highland View school Highland View school Aerial showing Highland View school and surrounding homes

  5. Radiation View Factor With Shadowing

    Energy Science and Technology Software Center (OSTI)

    1992-02-24

    FACET calculates the radiation geometric view factor (alternatively called shape factor, angle factor, or configuration factor) between surfaces for axisymmetric, two-dimensional planar and three-dimensional geometries with interposed third surface obstructions. FACET was developed to calculate view factors as input data to finite element heat transfer analysis codes.

  6. ULTRA LOW NOx CATALYTIC COMBUSTION FOR IGCC POWER PLANTS

    SciTech Connect (OSTI)

    Lance L. Smith

    2004-03-01

    Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using PCI's two-stage (catalytic / gas-phase) combustion process for syngas fuel. In this process, the first stage is a Rich-Catalytic Lean-burn (RCL{trademark}) catalytic reactor, wherein a fuel-rich mixture contacts the catalyst and reacts while final and excess combustion air cool the catalyst. The second stage is a gas-phase combustor, wherein the catalyst cooling air mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During the reporting period, PCI successfully achieved NOx = 0.011 lbs/MMBtu at 10 atm pressure (corresponding to 2.0 ppm NOx corrected to 15% O{sub 2} dry) with near-zero CO emissions, surpassing the project goal of < 0.03 lbs/MMBtu NOx. These emissions levels were achieved at scaled (10 atm, sub-scale) baseload conditions corresponding to Tampa Electric's Polk Power Station operation on 100% syngas (no co-firing of natural gas).

  7. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Broader source: Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  8. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Broader source: Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  9. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOE Patents [OSTI]

    MacArthur, James B.; McLean, Joseph B.; Comolli, Alfred G.

    1989-01-01

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  10. Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons

    DOE Patents [OSTI]

    Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

    2011-02-01

    Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

  11. A Simple Approach of Tuning Catalytic Activity of MFI-Zeolites...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Simple Approach of Tuning Catalytic Activity of MFI-Zeolites for Low-Temperature SCR of NOx A Simple Approach of Tuning Catalytic Activity of MFI-Zeolites for Low-Temperature SCR...

  12. Incorporation of Catalytic Compounds in the Porosity of SiC Wall...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples Incorporation of Catalytic Compounds in the Porosity...

  13. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using ...

  14. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: ...

  15. The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone...

    Office of Scientific and Technical Information (OSTI)

    The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone for the H2A.Z-H2B Dimer Citation Details In-Document Search Title: The Catalytic Subunit of the SWR1 Remodeler Is ...

  16. Industrial Gas Turbine Engine Catalytic Pilot Combustor-Prototype Testing

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2009-09-30

    PCI has developed and demonstrated its Rich Catalytic Lean-burn (RCL®) technology for industrial and utility gas turbines to meet DOE??s goals of low single digit emissions. The technology offers stable combustion with extended turndown allowing ultra-low emissions without the cost of exhaust after-treatment and further increasing overall efficiency (avoidance of after-treatment losses). The objective of the work was to develop and demonstrate emission benefits of the catalytic technology to meet strict emissions regulations. Two different applications of the RCL® concept were demonstrated: RCL® catalytic pilot and Full RCL®. The RCL® catalytic pilot was designed to replace the existing pilot (a typical source of high NOx production) in the existing Dry Low NOx (DLN) injector, providing benefit of catalytic combustion while minimizing engine modification. This report discusses the development and single injector and engine testing of a set of T70 injectors equipped with RCL® pilots for natural gas applications. The overall (catalytic pilot plus main injector) program NOx target of less than 5 ppm (corrected to 15% oxygen) was achieved in the T70 engine for the complete set of conditions with engine CO emissions less than 10 ppm. Combustor acoustics were low (at or below 0.1 psi RMS) during testing. The RCL® catalytic pilot supported engine startup and shutdown process without major modification of existing engine controls. During high pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over a wide range of flame temperatures. In applications where lower NOx production is required (i.e. less than 3 ppm), in parallel, a Full RCL® combustor was developed that replaces the existing DLN injector providing potential for maximum emissions reduction. This concept was tested at industrial gas turbine conditions in a Solar Turbines, Incorporated high-pressure (17 atm.) combustion rig and in a modified Solar Turbines, Incorporated Saturn engine rig. High pressure single-injector rig and modified engine rig tests demonstrated NOx less than 2 ppm and CO less than 10 ppm over a wide flame temperature operating regime with low combustion noise (<0.15% peak-to-peak). Minimum NOx for the optimized engine retrofit Full RCL® designs was less than 1 ppm with CO emissions less than 10 ppm. Durability testing of the substrate and catalyst material was successfully demonstrated at pressure and temperature showing long term stable performance of the catalytic reactor element. Stable performance of the reactor element was achieved when subjected to durability tests (>5000 hours) at simulated engine conditions (P=15 atm, Tin=400C/750F.). Cyclic tests simulating engine trips was also demonstrated for catalyst reliability. In addition to catalyst tests, substrate oxidation testing was also performed for downselected substrate candidates for over 25,000 hours. At the end of the program, an RCL® catalytic pilot system has been developed and demonstrated to produce NOx emissions of less than 3 ppm (corrected to 15% O2) for 100% and 50% load operation in a production engine operating on natural gas. In addition, a Full RCL® combustor has been designed and demonstrated less than 2 ppm NOx (with potential to achieve 1 ppm) in single injector and modified engine testing. The catalyst/substrate combination has been shown to be stable up to 5500 hrs in simulated engine conditions.

  17. Our History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History Our History Elk Hills Naval Petroleum Reserve Circa 1920s Elk Hills Naval Petroleum Reserve Circa 1920s The Office of Fossil Energy has the longest directly-traceable history of any organization in the Department of Energy. While the nuclear energy program can look back to the Manhattan Project of World War II for its origins, the Federal Government's involvement in fossil fuel resources began several decades earlier, in the early 1900s. Oil Dominates Early Concerns The U.S.S. Colorado,

  18. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels

    Broader source: Energy.gov [DOE]

    Factsheet overview of how project will develop a unique, feul-flexible catalytic combustor for gas turbines

  19. Agglutination of single catalyst particles during fluid catalytic cracking as observed by X-ray nanotomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meirer, F.; Kalirai, S.; Weker, J. Nelson; Liu, Y.; Andrews, J. C.; Weckhuysen, B. M.

    2015-04-14

    Metal accumulation at the catalyst particle surface plays a role in particle agglutination during fluid catalytic cracking.

  20. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductants | Department of Energy Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_marshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by

  1. Enhanced thermal and gas flow performance in a three-way catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    converter through use of insulation within the ceramic monolith | Department of Energy thermal and gas flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith Enhanced thermal and gas flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith Emissions performance comparison of conventional catalytic converter with multi-channel catalytic converter (ceramic fiber insulation layers introduced into

  2. Berkeley Lab Marks Black History Month

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Berkeley Lab Marks Black History Month Each February Americans celebrate Black History Month, also known as African American History Month, to recognize the importance of Black history in American history. We profile three employees - Jackie Scoggins, Matt Rice, and Thierry Nouidui - who tell their stories of how they came to Berkeley Lab.

  3. Y-12 and uranium history

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    did happen six days after he was given the assignment. The history of uranium at Y-12 began with that decision, which will be commemorated on September 19, 2012, at...

  4. history | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    history | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home

  5. A History of Geothermal Energy Research and Development in the United States: Exploration 1976-2006

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exploration 1976 - 2006 A History of Geothermal Energy Research and Development in the United States Cover Photo Credit Photomicrograph of quartz sampled from a depth of 948 feet in Lake City Observation Hole-1, Lake City geothermal system, California. The image was taken under crossed nicols. The vibrant birefringence colors are due to the section being extra thick. The field of view is 0.07 inches across. (Courtesy: Joseph N. Moore) A History of Geothermal Energy Research and Development in

  6. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ); Heinz, Robert (Ludwigshafen, DE)

    2012-06-26

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  7. Tag: History | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Tag: History Displaying 1 - 10 of 119... Category: About Deputy Secretary meets two calutron girls When the Deputy Secretary of Energy, Elizabeth Sherwood-Randall, was in...

  8. Catalytic conversion of alcohols to hydrocarbons with low benzene content

    DOE Patents [OSTI]

    Narula, Chaitanya K.; Davison, Brian H.; Keller, Martin

    2016-03-08

    A method for converting an alcohol to a hydrocarbon fraction having a lowered benzene content, the method comprising: converting said alcohol to a hydrocarbon fraction by contacting said alcohol, under conditions suitable for converting said alcohol to said hydrocarbon fraction, with a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon fraction, and contacting said hydrocarbon fraction with a benzene alkylation catalyst, under conditions suitable for alkylating benzene, to form alkylated benzene product in said hydrocarbon fraction. Also described is a catalyst composition useful in the method, comprising a mixture of (i) a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon, and (ii) a benzene alkylation catalyst, in which (i) and (ii) may be in a mixed or separated state. A reactor for housing the catalyst and conducting the reaction is also described.

  9. Role of surface generated radicals in catalytic combustion

    SciTech Connect (OSTI)

    Santavicca, D.A.; Stein, Y.; Royce, B.S.H.

    1984-04-01

    The role of surface generated OH radicals in determining the catalytic ignition characteristics for propane oxidation on platinum were studied. The experiments were conducted in a stacked-plate, catalyst bed. Transient measurements, during catalytic ignition, of the catalyst's axial temperature profile were made and the effect of equivalence ratio, inlet temperature and inlet velocity was investigated. These measurements will provide insights which will be useful in planning and interpreting to OH measurements. Attempts to measure OH concentration in the catalyst bed using resonance absorption spectroscopy were unsuccessful, indicating that OH concentrations are below 10 to the 16th power/cc but still possibly above equilibrium values. Measurements are currently underway using forward scatter laser induced fluorescence which should extend the OH detection limits several orders of magnitude below the equilibrium concentrations.

  10. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Foran, Michael T. (Rocky Point, NY)

    1984-01-01

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150.degree.-260.degree. C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO.sub.4 and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect.

  11. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  12. Catalytic effects of minerals on NOx emission from coal combustion

    SciTech Connect (OSTI)

    Yao, M.Y.; Che, D.F.

    2007-07-01

    The catalytic effects of inherent mineral matters on NOx emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NOx are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NOx mostly. But the mechanistic effect on NOx formation varies from coal to coal. Ca and Mg promote NOx emission. Na, K, Fe suppress NOx formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions.

  13. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Jones, Susanne B.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

  14. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

    1984-01-06

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

  15. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W.; Reinhard, Martin

    2002-01-01

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  16. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Situ Catalytic Fast Pyrolysis Technology Pathway Mary Biddy and Abhijit Dutta National Renewable Energy Laboratory Susanne Jones and Aye Meyer Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy under

  17. Catalytic Self-Decontaminating Materials - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalytic Self-Decontaminating Materials Naval Research Laboratory Contact NRL About This Technology Publications: PDF Document Publication SelfDecontaminatingMaterials (383 KB) Technology Marketing SummarySelf-decontaminating structures based on porphyrin-embedded, target imprinted, porous, organosilicate sorbents. The materials rapidly sequester targets as a result of the affinity of the sorbent structures. Catalysis proceeds upon stimulation of the porphyrin moieties through illumination or

  18. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway Mary Biddy National Renewable Energy Laboratory Susanne Jones Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy under contract

  19. New Catalytic Approach Builds Molecules with Specific Functionality More

    Office of Science (SC) Website

    Safely and Efficiently | U.S. DOE Office of Science (SC) New Catalytic Approach Builds Molecules with Specific Functionality More Safely and Efficiently Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301)

  20. Hybrid lean premixing catalytic combustion system for gas turbines

    DOE Patents [OSTI]

    Critchley, Ian L.

    2003-12-09

    A system and method of combusting a hydrocarbon fuel is disclosed. The system combines the accuracy and controllability of an air staging system with the ultra-low emissions achieved by catalytic combustion systems without the need for a pre-heater. The result is a system and method that is mechanically simple and offers ultra-low emissions over a wide range of power levels, fuel properties and ambient operating conditions.

  1. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ex-Situ Catalytic Fast Pyrolysis Technology Pathway Mary Biddy and Abhijit Dutta National Renewable Energy Laboratory Susanne Jones and Aye Meyer Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy under

  2. Converting sugars to sugar alcohols by aqueous phase catalytic hydrogenation

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Werpy, Todd A. (West Richland, WA); Wang, Yong (Richland, WA); Frye, Jr., John G. (Richland, WA)

    2003-05-27

    The present invention provides a method of converting sugars to their corresponding sugar alcohols by catalytic hydrogenation in the aqueous phase. It has been found that surprisingly superior results can be obtained by utilizing a relatively low temperature (less than 120.degree. C.), selected hydrogenation conditions, and a hydrothermally stable catalyst. These results include excellent sugar conversion to the desired sugar alcohol, in combination with long life under hydrothermal conditions.

  3. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials | Department of Energy Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace055_peden_2011_o.pdf More

  4. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials | Department of Energy 3 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace055_peden_2013_o.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon AdsorberMaterials Deactivation Mechanisms of Base Metal/Zeolite

  5. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace055_peden_2012_o.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation Mechanisms of Base Metal/Zeolite

  6. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOEs) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  7. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway Mary Biddy National Renewable Energy Laboratory Susanne Jones Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy under contract

  8. Dedicated Beamline Facilities for Catalytic Research. Synchrotron Catalysis Consortium (SCC)

    SciTech Connect (OSTI)

    Chen, Jingguang; Frenkel, Anatoly; Rodriguez, Jose; Adzic, Radoslav; Bare, Simon R.; Hulbert, Steve L.; Karim, Ayman; Mullins, David R.; Overbury, Steve

    2015-03-04

    Synchrotron spectroscopies offer unique advantages over conventional techniques, including higher detection sensitivity and molecular specificity, faster detection rate, and more in-depth information regarding the structural, electronic and catalytic properties under in-situ reaction conditions. Despite these advantages, synchrotron techniques are often underutilized or unexplored by the catalysis community due to various perceived and real barriers, which will be addressed in the current proposal. Since its establishment in 2005, the Synchrotron Catalysis Consortium (SCC) has coordinated significant efforts to promote the utilization of cutting-edge catalytic research under in-situ conditions. The purpose of the current renewal proposal is aimed to provide assistance, and to develop new sciences/techniques, for the catalysis community through the following concerted efforts: Coordinating the implementation of a suite of beamlines for catalysis studies at the new NSLS-II synchrotron source; Providing assistance and coordination for catalysis users at an SSRL catalysis beamline during the initial period of NSLS to NSLS II transition; Designing in-situ reactors for a variety of catalytic and electrocatalytic studies; Assisting experimental set-up and data analysis by a dedicated research scientist; Offering training courses and help sessions by the PIs and co-PIs.

  9. New Catalytic DNA Biosensors for Radionuclides and Metal ions

    SciTech Connect (OSTI)

    Lu, Yi

    2003-06-01

    The goals of the project are to develop new catalytic DNA biosensors for simultaneous detection and quantification of bioavailable radionuclides and metal ions, and apply the sensors for on-site, real-time assessment of concentration, speciation and stability of the individual contaminants during and after bioremediation. A negative selection strategy was tested and validated. In vitro selection was shown to yield highly active and specific transition metal ion-dependent catalytic DNA/RNA. A fluorescence resonance energy transfer (FRET) study of in vitro selected DNA demonstrated that the trifluorophore labeled system is a simple and powerful tool in studying complex biomolecules structure and dynamics, and is capable of revealing new sophisticated structural changes. New fluorophore/quenchers in a single fluorosensor yielded improved signal to noise ratio in detection, identification and quantification of metal contaminants. Catalytic DNA fluorescent and colorimetric sensors were shown useful in sensing lead in lake water and in leaded paint. Project results were described in two papers and two patents, and won an international prize.

  10. New Catalytic DNA Biosensors for Radionuclides and Metal ions

    SciTech Connect (OSTI)

    Lu, Yi

    2002-06-01

    The goals of the project are to develop new catalytic DNA biosensors for simultaneous detection and quantification of bioavailable radionuclides and metal ions, and apply the sensors for on-site, real-time assessment of concentration, speciation and stability of the individual contaminants during and after bioremediation. A negative selection strategy was tested and validated. In vitro selection was shown to yield highly active and specific transition metal ion-dependent catalytic DNA/RNA. A fluorescence resonance energy transfer (FRET) study of in vitro selected DNA demonstrated that the trifluorophore labeled system is a simple and powerful tool in studying complex biomolecules structure and dynamics, and is capable of revealing new sophisticated structural changes. New fluorophore/quenchers in a single fluorosensor yielded improved signal to noise ratio in detection, identification and quantification of metal contaminants. Catalytic DNA fluorescent and colorimetric sensors were shown useful in sensing lead in lake water and in leaded paint. Project results were described in two papers and two patents, and won an international prize.

  11. View from the Bridge | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    View from the Bridge View from the Bridge This presentation gives an overview of Caterpillar's R&D focus on advanced diesel engines and exhaust aftertreatment. PDF icon...

  12. Women in Los Alamos History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Women in Los Alamos History Women in Los Alamos History WHEN: Mar 03, 2016 5:30 PM - 8:00 PM WHERE: Los Alamos Golf Course Clubhouse SPEAKER: Jill Tietjen CONTACT: Sarah Terrill (505) 709-0089 CATEGORY: Community INTERNAL: Calendar Login Event Description Tietjen is a well-known speaker on the topic of gender issues in the work place, and a motivational speaker for young women working toward educations and careers in science, engineering, technology and math (STEM). The community is invited to

  13. Drop History? No! | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Drop History? No! February 29, 2012 When I was in high school in England, especially in the smaller country schools, teachers were scarce and schedules, therefore, constrained. Further, the English style is for students to choose directions, and therefore subjects, at a relatively early age. So, at age 13, I had to choose between Physics and Chemistry on the one hand, and Latin and History on the other. Of course, I chose Physics and Chemistry, but thereby lost two subjects in which I was

  14. Wide field of view telescope

    DOE Patents [OSTI]

    Ackermann, Mark R. (Albuquerque, NM); McGraw, John T. (Placitas, NM); Zimmer, Peter C. (Albuquerque, NM)

    2008-01-15

    A wide field of view telescope having two concave and two convex reflective surfaces, each with an aspheric surface contour, has a flat focal plane array. Each of the primary, secondary, tertiary, and quaternary reflective surfaces are rotationally symmetric about the optical axis. The combination of the reflective surfaces results in a wide field of view in the range of approximately 3.8.degree. to approximately 6.5.degree.. The length of the telescope along the optical axis is approximately equal to or less than the diameter of the largest of the reflective surfaces.

  15. The history of the LHC

    ScienceCinema (OSTI)

    None

    2011-10-06

    Abstract: From the civil engineering, to the manufacturing of the various magnet types, each building block of this extraordinary machine required ambitious leaps in innovation. This lecture will review the history of the LHC project, focusing on the many challenges -- scientific, technological, managerial -- that had to be met during the various phases of R&D;, industrialization, construction, installation and commissioning.

  16. The history of the LHC

    SciTech Connect (OSTI)

    2010-05-11

    Abstract: From the civil engineering, to the manufacturing of the various magnet types, each building block of this extraordinary machine required ambitious leaps in innovation. This lecture will review the history of the LHC project, focusing on the many challenges -- scientific, technological, managerial -- that had to be met during the various phases of R&D;, industrialization, construction, installation and commissioning.

  17. Protein kinase A catalytic subunit primed for action: Time-lapse crystallography of Michaelis complex formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Amit; Gerlits, Oksana O.; Parks, Jerry M.; Langan, Paul; Kovalevskyi, Andrey Y.; Heller, William T.

    2015-11-12

    The catalytic subunit of the cyclic AMP-dependent protein kinase A (PKAc) catalyzes the transfer of the γ-phosphate of bound Mg2ATP to a serine or threonine residue of a protein substrate. Here, time-lapse X-ray crystallography was used to capture a series of complexes of PKAc with an oligopeptide substrate and unreacted Mg2ATP, including the Michaelis complex, that reveal important geometric rearrangements in and near the active site preceding the phosphoryl transfer reaction. Contrary to the prevailing view, Mg2+ binds first to the M1 site as a complex with ATP and is followed by Mg2+ binding to the M2 site. Furthermore, themore » target serine hydroxyl of the peptide substrate rotates away from the active site toward the bulk solvent, which breaks the hydrogen bond with D166. In conclusion, the serine hydroxyl of the substrate rotates back toward D166 to form the Michaelis complex with the active site primed for phosphoryl transfer.« less

  18. history

    National Nuclear Security Administration (NNSA)

    the Albuquerque Operations Office with other NNSA operations offices into the NNSA Service Center located in Albuquerque. OTS was renamed the Office of Secure Transportation...

  19. History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LES 9, both launched together on March 14, 1976. Radioisotope Thermoelectric Generator (RTG) DOE first supported the use of radioisotope power systems on National Aeronautics and ...

  20. History

    Broader source: Energy.gov [DOE]

    On January 7, 2011, the President signed H.R. 6523 (111th), the Ike Skelton National Defense Authorization Act for Fiscal Year 2011 (http://www.govtrack.us/congress/bills/111/hr6523) which became...

  1. A History of the Science Education Laboratory in Pictures | Princeton...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    image Plasma Speaker Lab renovation View larger image The "Loft" View larger image Teaching Lab renovation View larger image Dusty Plasma Lab completed View larger image The...

  2. Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device

    DOE Patents [OSTI]

    Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

    2014-05-06

    A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

  3. Recent Advances in Catalytic Conversion of Ethanol to Chemicals

    SciTech Connect (OSTI)

    Sun, Junming; Wang, Yong

    2014-04-30

    With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

  4. Method and apparatus for decoupled thermo-catalytic pollution control

    DOE Patents [OSTI]

    Tabatabaie-Raissi, Ali; Muradov, Nazim Z.; Martin, Eric

    2006-07-11

    A new method for design and scale-up of thermocatalytic processes is disclosed. The method is based on optimizing process energetics by decoupling of the process energetics from the DRE for target contaminants. The technique is applicable to high temperature thermocatalytic reactor design and scale-up. The method is based on the implementation of polymeric and other low-pressure drop support for thermocatalytic media as well as the multifunctional catalytic media in conjunction with a novel rotating fluidized particle bed reactor.

  5. Fabrication of catalytic electrodes for molten carbonate fuel cells

    DOE Patents [OSTI]

    Smith, James L.

    1988-01-01

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

  6. Catalytic pyrolysis of plastic wastes - Towards an economically viable process

    SciTech Connect (OSTI)

    McIntosh, M.J.; Arzoumanidis, G.G.; Brockmeier, F.E.

    1996-07-01

    The ultimate goal of our project is an economically viable pyrolysis process to recover useful fuels and/or chemicals from plastics- containing wastes. This paper reports the effects of various promoted and unpromoted binary oxide catalysts on yields and compositions of liquid organic products, as measured in a small laboratory pyrolysis reactor. On the basis of these results, a commercial scale catalytic pyrolysis reactor was simulated by the Aspen software and rough costs were estimated. The results suggest that such a process has potential economic viability.

  7. Method for low temperature catalytic production of hydrogen

    DOE Patents [OSTI]

    Mahajan, Devinder

    2003-07-22

    The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80.degree. C. to about 150.degree. C.

  8. Plasma-assisted catalytic ionization using porous nickel plate

    SciTech Connect (OSTI)

    Oohara, W.; Maeda, T.; Higuchi, T.

    2011-09-15

    Hydrogen atomic pair ions, i.e., H{sup +} and H{sup -} ions, are produced by plasma-assisted catalytic ionization using a porous nickel plate. Positive ions in a hydrogen plasma generated by dc arc discharge are irradiated to the porous plate, and pair ions are produced from the back of the irradiation plane. It becomes clear that the production quantity of pair ions mainly depends on the irradiation current of positive ions and the irradiation energy affects the production efficiency of H{sup -} ions.

  9. A Hybrid Catalytic Route to Fuels from Biomass Syngas Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LanzaTech. All rights reserved. 1 A Hybrid Catalytic Route to Fuels from Biomass Syngas BETO's Project Peer Review, March 2015 Alexandria, VA Alice Havill Senior Process Engineer Project Principle Investigator Hybrid Catalytic Route to Fuels from Biomass Syngas Project Objective: develop a hybrid conversion technology for catalytic upgrading of biomass- derived syngas to jet fuel and chemicals while ensure the cost, quality and environmental requirements of the aviation industry are met System

  10. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-09-29

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase is dispersed.

  11. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-03-17

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase id dispersed.

  12. Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Ames Laboratory Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity Thanks to a groundbreaking new method, scientists have created the first 3D super-resolution maps of catalytic activity on an individual catalytic nanoparticle while reactions are occurring. Catalysts are used in manufacturing everything from stain remover to rocket fuel; they make production more efficient by facilitating chemical reactions. Each catalyst being studied is only about 200 nanometers in

  13. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels This fact sheet provides an overview of the Next Generation Manufacturing Processes project to develop a unique, fuel-flexible catalytic combustor capable of enabling ultra-low emission, lean premixed combustion of a wide range of gaseous opportunity fuels. PDF icon Fact sheet - Enabling Clean Consumption of Low Btu and Reactive Fuels

  14. For current viewing resistor loads

    DOE Patents [OSTI]

    Lyons, Gregory R. (Tijeras, NM); Hass, Jay B. (Lee's Summit, MO)

    2011-04-19

    The invention comprises a terminal unit for a flat cable comprising a BNC-PCB connector having a pin for electrically contacting one or more conducting elements of a flat cable, and a current viewing resistor having an opening through which the pin extends and having a resistor face that abuts a connector face of the BNC-PCB connector, wherein the device is a terminal unit for the flat cable.

  15. Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them

    DOE Patents [OSTI]

    Schwartz, Michael; White, James H.; Sammells, Anthony F.

    2001-01-01

    A process for production of synthesis gas employing a catalytic membrane reactor wherein the membrane comprises a mixed metal oxide material.

  16. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis

    Broader source: Energy.gov [DOE]

    The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks.

  17. Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis

    Broader source: Energy.gov [DOE]

    In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks.

  18. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation...

    Office of Scientific and Technical Information (OSTI)

    This content will become publicly available on September 21, 2016 Title: Complex catalytic ... become publicly available on September 21, 2016 Publisher's Version of Record 10.1021...

  19. New Tandem Catalytic Cycles take to the Rhod(ium) | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Tandem Catalytic Cycles take to the Rhod(ium) Light, combined with a novel rhodium catalyst, enables greener production of chemical feedstocks from biorenewables. A key...

  20. Catalytic combustor for integrated gasification combined cycle power plant

    DOE Patents [OSTI]

    Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

    2008-12-16

    A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

  1. Well Record or History | Open Energy Information

    Open Energy Info (EERE)

    Record or History Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Well Record or HistoryLegal Published NA Year Signed or Took...

  2. The Manhattan Project National Security History Series

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Manhattan Project National Security History Series 5 Visit our Manhattan Project web site: http://www.cfo.doe.gov/me70/manhattan/index.htm 5 DOE/MA-0002 Revised F. G. Gosling Offce of History and Heritage Resources Executive Secretariat Offce of Management Department of Energy January 2010 The Manhattan Project National Security History Series 5 National Security History Series Volume I: The Manhattan Project: Making the Atomic Bomb Volume II: Building the Nuclear Arsenal: Cold War Nuclear

  3. History of the Strategic Petroleum Reserve

    Broader source: Energy.gov [DOE]

    This timeline explores the history of the Strategic Petroleum Reserve, or SPR, from conception through current events.

  4. NTS_History.indd | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NTS_History.indd NTS_History.indd PDF icon NTS_History.indd More Documents & Publications Fehner and Gosling, Atmospheric Nuclear Weapons Testing, 1951-1963. Battlefield of the Cold War: The Nevada Test Site, Volume I origins.indd Fehner and Gosling, Origins of the Nevada Test Site

  5. Better Buildings Network View | February 2016

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  6. Better Buildings Network View | January 2016

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  7. Better Buildings Network View | January 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  8. Better Buildings Network View | April 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  9. Better Buildings Network View | May 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  10. Better Buildings Network View | March 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  11. Better Buildings Network View | September 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  12. Better Buildings Network View | February 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  13. Better Buildings Network View | May 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  14. Better Buildings Network View | January 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  15. Better Buildings Network View | December 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  16. Better Buildings Network View | June 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  17. Better Buildings Network View | November 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  18. Better Buildings Network View | October 2014

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  19. Better Buildings Network View | October 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  20. Better Buildings Network View | April 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  1. Better Buildings Network View | December 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  2. Better Buildings Network View | June 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  3. Better Buildings Network View | November 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  4. Better Buildings Network View | March 2015

    Broader source: Energy.gov [DOE]

    The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network.

  5. MEMS-based fuel cells with integrated catalytic fuel processor and method thereof

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Havstad, Mark A. (Davis, CA)

    2011-08-09

    Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

  6. View Shed - Version 1.0

    Energy Science and Technology Software Center (OSTI)

    2014-09-18

    The View Shed library is a collection of Umbra modules that are used to calculate areas of visual coverage (view sheds). It maps high and low visibility areas and calculates sensor (camera placement for maximum coverage and performance. This assertion includes a managed C++ wrapper code (ViewShedWrapper) to enable C# applications, such as OpShed, to incorporate this library.

  7. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  8. Method For Selective Catalytic Reduction Of Nitrogen Oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  9. Method for selective catalytic reduction of nitrogen oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  10. Fabrication of fuel cell electrodes and other catalytic structures

    DOE Patents [OSTI]

    Smith, J.L.

    1987-02-11

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.

  11. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  12. Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels

    SciTech Connect (OSTI)

    Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

    2013-01-01

    Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

  13. Selective catalytic synthesis of functional allenes, cyclopentenones and oxolenes

    SciTech Connect (OSTI)

    Darcel, C.; Bruneau, C.; Dixneuf, P.H.

    1995-12-31

    The most powerful method to produce allene derivatives consists in the selective activation of prop-2-yn-1-carbonates by a Pd(0) catalyst, via allenyl palladium(II) intermediate. This strategy has been used for the selective catalytic synthesis of derivatives. The alkynyl cyclic carbonates have the advantage to be readily prepared directly from CO{sub 2} and contain both propargylic and homopropargylic functionalities. Their activation, under mild conditions, by palladium(0) catalysts, associated with the suitable phosphine ligand, can be oriented to selectively prepare either alkynyl {alpha}-hydroxy allenes, 5-hydroxy alka-2,3-dienoates, functional cyclopentenones or oxolenes via cross coupling, mono-carbonylation, dicarbonylation and Heck-Type reactions respectively.

  14. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  15. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  16. Coal hydrogenation and deashing in ebullated bed catalytic reactor

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Johanson, Edwin S. (Princeton, NJ)

    1983-01-01

    An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

  17. Catalytic gasification studies in a pressurized fluid-bed unit

    SciTech Connect (OSTI)

    Mudge, L.K.; Baker, E.G.; Mitchell, D.H.; Robertus, R.J.; Brown, M.D.

    1983-07-01

    The purpose of the project is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from October 1980 to November 1982. In the laboratory scale studis, active catalysts were developed for generation of synthesis gases from wood by steam gasification. A trimetallic catalyst, Ni-Co-Mo on silica-alumina doped with 2 wt % Na, was found to retain activity indefinitely for generation of a methanol synthesis gas from wood at 1380/sup 0/F (750/sup 0/C) and 1 atm (100 kPa) absolute pressure. Catalysts for generation of a methane-rich gas were deactivated rapidly and could not be regenerated as required for economic application. Sodium carbonate and potassium carbonate were effective as catalysts for conversion of wood to synthesis gases and methane-rich gas and should be economically viable. Catalytic gasification conditions were found to be suitable for processing of alternative feedstocks: bagasse, alfalfa, rice hulls, and almond hulls. The PDU was operated successfully at absolute pressures of up to 10 atm (1000 kPa) and temperatures of up to 1380/sup 0/F (750/sup 0/C). Yields of synthesis gases at elevated pressure were greater than those used for previous economic evaluations. A trimetallic catalyst, Ni-Cu-Mo on silica-alumina, did not display a long life as did the doped trimetallic catalyst used in laboratory studies. A computer program for a Radio Shack TRS-80 Model I microcomputer was developed to evaluate rapidly the economics of producing either methane or methanol from wood. The program is based on economic evaluations reported in previous studies. Improved yields from the PDU studies were found to result in a reduction of about 9 cents/gal in methanol cost.

  18. Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics

    SciTech Connect (OSTI)

    Kamil Klier; Richard G. Herman

    2005-11-30

    This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Br???????¸nsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

  19. DWPF CATALYTIC HYDROGEN GENERATION PROGRAM - REVIEW OF CURRENT STATUS

    SciTech Connect (OSTI)

    Koopman, D.

    2009-07-10

    Significant progress has been made in the past two years in improving the understanding of acid consumption and catalytic hydrogen generation during the Defense Waste Processing Facility (DWPF) processing of waste sludges in the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME). This report reviews issues listed in prior internal reviews, describes progress with respect to the recommendations made by the December 2006 external review panel, and presents a summary of the current understanding of catalytic hydrogen generation in the DWPF Chemical Process Cell (CPC). Noble metals, such as Pd, Rh, and Ru, are historically known catalysts for the conversion of formic acid into hydrogen and carbon dioxide. Rh, Ru, and Pd are present in the DWPF SRAT feed as by-products of thermal neutron fission of {sup 235}U in the original waste. Rhodium appears to become most active for hydrogen as the nitrite ion concentration becomes low (within a factor of ten of the Rh concentration). Prior to hydrogen generation, Rh is definitely active for nitrite destruction to N{sub 2}O and potentially active for nitrite to NO formation. These reactions are all consistent with the presence of a nitro-Rh complex catalyst, although definite proof for the existence of this complex during Savannah River Site (SRS) waste processing does not exist. Ruthenium does not appear to become active for hydrogen generation until nitrite destruction is nearly complete (perhaps less nitrite than Ru in the system). Catalytic activity of Ru during nitrite destruction is significantly lower than that of either Rh or Pd. Ru appears to start activating as Rh is deactivating from its maximum catalytic activity for hydrogen generation. The slow activation of the Ru, as inferred from the slow rate of increase in hydrogen generation that occurs after initiation, may imply that some species (perhaps Ru itself) has some bound nitrite on it. Ru, rather than Rh, is primarily responsible for the hydrogen generation in the SME cycle when the hydrogen levels are high enough to be noteworthy. Mercury has a role in catalytic hydrogen generation. Two potentially distinct roles have been identified. The most dramatic effect of Hg on hydrogen generation occurs between runs with and without any Hg. When a small amount of Hg is present, it has a major inhibiting effect on Rh-catalyzed H{sub 2} generation. The Rh-Ru-Hg matrix study showed that increasing mercury from 0.5 to 2.5 wt% in the SRAT receipt total solids did not improve the inhibiting effect significantly. The next most readily identified role for Hg is the impact it has on accelerating NO production from nitrite ion. This reaction shifts the time that the ideal concentration of nitrite relative to Rh occurs, and consequently causes the most active nitro-Rh species to form sooner. The potential consequences of this shift in timing are expected to be a function of other factors such as amount of excess acid, Rh concentration, etc. Graphical data from the Rh-Ru-Hg study suggested that Hg might also be responsible for partially inhibiting Ru-catalysis initially, but that the inhibition was not sustained through the SRAT and SME cycles. Continued processing led to a subsequent increase in hydrogen generation that was often abrupt and that frequently more than doubled the hydrogen generation rate. This phenomenon may have been a function of the extent of Hg stripping versus the initial Ru concentration in these tests. Palladium is an active catalyst, and activates during (or prior to) nitrite destruction to promote N{sub 2}O formation followed by a very small amount of hydrogen. Pd then appears to deactivate. Data to date indicate that Pd should not be a species of primary concern relative to Rh and Ru for hydrogen generation. Pd was a very mild catalyst for hydrogen generation compared to Rh and Ru in the simulated waste system. Pd was comparable to Rh in enhancing N{sub 2}O production when present at equal concentration. Pd, however, is almost always present at less than a quarter of the Rh concentration in S

  20. Prairie View Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    View Gas Recovery Biomass Facility Jump to: navigation, search Name Prairie View Gas Recovery Biomass Facility Facility Prairie View Gas Recovery Sector Biomass Facility Type...

  1. Better Buildings Network View | September 2015 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View | September 2015 Better Buildings Network View | September 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of...

  2. A View from the Bridge - DOE Perspective | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A View from the Bridge - DOE Perspective A View from the Bridge - DOE Perspective Broad view of DOE's approach to addressing transportation sector oil dependence PDF icon...

  3. History of Regulatory Oversight at LANL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History of Regulatory Oversight History of Regulatory Oversight at LANL History of Regulatory Oversight at LANL 1943-1950: Manhattan Project Era Few environmental regulations Best available protection technologies employed, though rudimentary 1950s-1970s: Cold War Era Laboratory moved from townsite to current location Advent of national environmental protection laws Clean Air Act Clean Water Act Resource Conservation and Recovery Act (RCRA) 1980s-1990s: Non-proliferation/Stockpile Reduction LANL

  4. Space Nuclear MIssion History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Power Systems » Space Nuclear MIssion History Space Nuclear MIssion History A HISTORY OF MISSION SUCCESSES For over fifty years, the Department of Energy has enabled space exploration on 27 missions by providing safe reliable radioistope power systems and radioisotope heater units for NASA, Navy, Air Force, DOE. Mission Year Launched Agency Regions Explored Transit 4a 1961 Navy Earth- Navy Navigation Satelitte Transit 4B 1961 Navy Earth - Navigation Satelitte Transit 5-BN-1 1963 Navy Earth -

  5. DOE History Timeline | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE History Timeline DOE History Timeline DOE History Timeline The Department of Energy is one of the most interesting and diverse agencies in the Federal Government. Activated on October 1, 1977, the twelfth cabinet-level department brought together for the first time within one agency two programmatic traditions that had long coexisted within the Federal establishment: 1) defense responsibilities that included the design, construction, and testing of nuclear weapons dating from the Manhattan

  6. Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 A presentation about how hydrogen can be reversibly absorbed and desorbed from NaAlH4 under moderate conditions by the addition of catalysts. PDF icon catalytic_effect_of_ti.pdf More Documents & Publications Final Report for the DOE Metal Hydride Center of Excellence Effects of Point Defects and Impurities on Kinetics in NaAlH4 Prediction of New Hydrogen Storage Compounds

  7. Commemorating Black History: Contributions of African Americans...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Speak of the Nation's History General Leslie Groves and J. Robert Oppenheimer are pictured here at the Trinity Test site in New Mexico, 1945. New Manhattan Project ...

  8. History of Load Participation in ERCOT

    SciTech Connect (OSTI)

    Patterson, Mark

    2011-10-25

    Presentation on demand integration by ERCOT for a DOE Workshop. Covers history of load participation in ERCOT from 2002 to present.

  9. Power of the River History Book

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power-of-the-River-BPA-History-Book Sign In About | Careers | Contact | Investors | bpa.gov Search News & Us Expand News & Us Projects & Initiatives Expand Projects &...

  10. Employee Women's History Month Celebration (DC)

    Broader source: Energy.gov [DOE]

    Celebrate Women's History Month with the Department of Energy headquarters, and hear from remarkable game-changing women and leading DOE engagement programs.

  11. July 2013 Most Viewed Documents for Biology And Medicine | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information July 2013 Most Viewed Documents for Biology And Medicine Science Subject Feed Carbon Dioxide Sequestering Using Microalgal Systems Daniel J. Stepan; Richard E. Shockey; Thomas A. Moe; Ryan Dorn (2002) 51 /> SURVEY OF NOISE SUPPRESSION SYSTEMS FOR ENGINE GENERATOR SETS. KRISHNA,C.R. (1999) 46 /> Human radiation studies: Remembering the early years. Oral history of Donner Lab Administrator Baird G. Whaley, August 15, 1994 NONE (1995)

  12. Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods

    SciTech Connect (OSTI)

    Vicic, David A.

    2014-05-01

    In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

  13. Low-temperature catalytic gasification of wet industrial wastes

    SciTech Connect (OSTI)

    Elliott, D C; Neuenschwander, G G; Baker, E G; Sealock, Jr, L J; Butner, R S

    1991-04-01

    Bench-scale reactor tests are in progress at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for treating a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. This report describes a test program which used a continuous-feed tubular reactor. This test program is an intermediate stage in the process development. The reactor is a laboratory-scale version of the commercial concept as currently envisioned by the process developers. An energy benefit and economic analysis was also completed on the process. Four conceptual commercial installations of the TEES process were evaluated for three food processing applications and one organic chemical manufacturing application. Net energy production (medium-Btu gas) was achieved in all four cases. The organic chemical application was found to be economically attractive in the present situation. Based on sensitivity studies included in the analysis, the three food processing cases will likely become attractive in the near future as waste disposal regulations tighten and disposal costs increase. 21 refs., 2 figs., 9 tabs.

  14. Mercury Oxidation via Catalytic Barrier Filters Phase II

    SciTech Connect (OSTI)

    Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

    2007-09-30

    In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

  15. New Catalytic DNA Biosensors for Radionuclides and Metal ion

    SciTech Connect (OSTI)

    Yi Lu

    2008-03-01

    We aim to develop new DNA biosensors for simultaneous detection and quantification of bioavailable radionuclides, such as uranium, technetium, and plutonium, and metal contaminants, such as lead, chromium, and mercury. The sensors will be highly sensitive and selective. They will be applied to on-site, real-time assessment of concentration, speciation, and stability of the individual contaminants before and during bioremediation, and for long-term monitoring of DOE contaminated sites. To achieve this goal, we have employed a combinatorial method called in vitro selection to search from a large DNA library (~ 1015 different molecules) for catalytic DNA molecules that are highly specific for radionuclides or other metal ions through intricate 3-dimensional interactions as in metalloproteins. Comprehensive biochemical and biophysical studies have been performed on the selected DNA molecules. The findings from these studies have helped to elucidate fundamental principles for designing effective sensors for radionuclides and metal ions. Based on the study, the DNA have been converted to fluorescent or colorimetric sensors by attaching to it fluorescent donor/acceptor pairs or gold nanoparticles, with 11 part-per-trillion detection limit (for uranium) and over million fold selectivity (over other radionuclides and metal ions tested). Practical application of the biosensors for samples from the Environmental Remediation Sciences Program (ERSP) Field Research Center (FRC) at Oak Ridge has also been demonstrated.

  16. Catalytic Growth of Macroscopic Carbon Nanofibers Bodies with Activated Carbon

    SciTech Connect (OSTI)

    Abdullah, N.; Muhammad, I. S.; Hamid, S. B. Abd.; Rinaldi, A.; Su, D. S.; Schlogl, R.

    2009-06-01

    Carbon-carbon composite of activated carbon and carbon nanofibers have been synthesized by growing Carbon nanofiber (CNF) on Palm shell-based Activated carbon (AC) with Ni catalyst. The composites are in an agglomerated shape due to the entanglement of the defective CNF between the AC particles forming a macroscopic body. The macroscopic size will allow the composite to be used as a stabile catalyst support and liquid adsorbent. The preparation of CNT/AC nanocarbon was initiated by pre-treating the activated carbon with nitric acid, followed by impregnation of 1 wt% loading of nickel (II) nitrate solutions in acetone. The catalyst precursor was calcined and reduced at 300 deg. C for an hour in each step. The catalytic growth of nanocarbon in C{sub 2}H{sub 4}/H{sub 2} was carried out at temperature of 550 deg. C for 2 hrs with different rotating angle in the fluidization system. SEM and N{sub 2} isotherms show the level of agglomeration which is a function of growth density and fluidization of the system. The effect of fluidization by rotating the reactor during growth with different speed give a significant impact on the agglomeration of the final CNF/AC composite and thus the amount of CNFs produced. The macrostructure body produced in this work of CNF/AC composite will have advantages in the adsorbent and catalyst support application, due to the mechanical and chemical properties of the material.

  17. Synthesis and catalytic activity of polysaccharide templated nanocrystalline sulfated zirconia

    SciTech Connect (OSTI)

    Sherly, K. B.; Rakesh, K.

    2014-01-28

    Nanoscaled materials are of great interest due to their unique enhanced optical, electrical and magnetic properties. Sulfate-promoted zirconia has been shown to exhibit super acidic behavior and high activity for acid catalyzed reactions. Nanocrystalline zirconia was prepared in the presence of polysaccharide template by interaction between ZrOCl{sub 2}?8H{sub 2}O and chitosan template. The interaction was carried out in aqueous phase, followed by the removal of templates by calcination at optimum temperature and sulfation. The structural and textural features were characterized by powder XRD, TG, SEM and TEM. XRD patterns showed the peaks of the diffractogram were in agreement with the theoretical data of zirconia with the catalytically active tetragonal phase and average crystalline size of the particles was found to be 9 nm, which was confirmed by TEM. TPD using ammonia as probe, FTIR and BET surface area analysis were used for analyzing surface features like acidity and porosity. The BET surface area analysis showed the sample had moderately high surface area. FTIR was used to find the type species attached to the surface of zirconia. UV-DRS found the band gap of the zirconia was found to be 2.8 eV. The benzylation of o-xylene was carried out batchwise in atmospheric pressure and 433K temperature using sulfated zirconia as catalyst.

  18. The Better Buildings Neighborhood View-- April 2013

    Broader source: Energy.gov [DOE]

    The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program - April 2013.

  19. High Performance Builder Spotlight: Clifton View Homes

    SciTech Connect (OSTI)

    2011-01-01

    Clifton View Homess remodel of a 1962 rambler, on Whidbey Island in Washington State, cut energy costs by two-thirds.

  20. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Investigation of a series of transition metal...

  1. Enhanced thermal and gas flow performance in a three-way catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    introduced into ceramic monolith of three-way catalytic converter) PDF icon deer11ley.pdf More Documents & Publications NH3 generation over commercial Three-Way Catalysts and ...

  2. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks. PDF icon ...

  3. Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks. PDF icon Bioenergy Technologies Office ...

  4. Impact of Biodiesel-based Na on the Selective Catalytic Reduction...

    Office of Scientific and Technical Information (OSTI)

    of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the ...

  5. Catalytic and reactive polypeptides and methods for their preparation and use

    DOE Patents [OSTI]

    Schultz, Peter (Oakland, CA)

    1993-01-01

    Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the bi.

  6. System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines

    SciTech Connect (OSTI)

    Shahrokh Etemad; Lance Smith; Kevin Burns

    2004-12-01

    Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

  7. Radioactivity and health: A history

    SciTech Connect (OSTI)

    Stannard, J.N.; Baalman, R.W. Jr.

    1988-10-01

    This book is designed to be primarily a history of research facts, measurements, and ideas and the people who developed them. ''Research'' is defined very broadly to include from bench-top laboratory experiments to worldwide environmental investigations. The book is not a monograph or a critical review. The findings and conclusions are presented largely as the investigators saw and reported them. Frequently, the discussion utilizes the terminology and units of the time, unless they are truly antiquated or potentially unclear. It is only when the work being reported is markedly iconoclastic or obviously wrong that I chose to make special note of it or to correct it. Nevertheless, except for direct quotations, the language is mine, and I take full responsibility for it. The working materials for this volume included published papers in scientific journals, books, published conferences and symposia, personal interviews with over 100 individuals, some of them more than once (see Appendix A), and particularly for the 1940--1950 decade and for the large government-supported laboratories to the present day, ''in-house'' reports. These reports frequently represent the only comprehensive archive of what was done and why. Unfortunately, this source is drying up because of storage problems and must be retrieved by ever more complex and inconvenient means. For this reason, special efforts have been taken to review and document these sources, though even now some sections of the field are partially inaccessible. Nevertheless, the volume of all materials available for this review was surprisingly large and the quality much better than might have been expected for so complex and disparate a fields approached under conditions of considerable urgency.

  8. Atomic power in space: A history

    SciTech Connect (OSTI)

    Not Available

    1987-03-01

    ''Atomic Power in Space,'' a history of the Space Isotope Power Program of the United States, covers the period from the program's inception in the mid-1950s through 1982. Written in non-technical language, the history is addressed to both the general public and those more specialized in nuclear and space technologies. 19 figs., 3 tabs.

  9. PAFC History and Successes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History and Successes PAFC History and Successes Presentation at the MCFC and PAFC R&D Workshop held Nov. 16, 2009, in Palm Springs, CA PDF icon mcfc_pafc_workshop_ferro.pdf More Documents & Publications MCFC and PAFC R&D Workshop Summary Report PAFC Cost Challenges Fuel Cell Development Status

  10. Newmark-Hall synthetic history development

    SciTech Connect (OSTI)

    Aramayo, G.A.

    1990-11-01

    The methodology used to develop synthetic acceleration time histories with spectral content that envelopes the Newmark-Hall spectra is described. Six acceleration time histories are developed for two conditions of foundation and 3 critical damping factors. The target spectra corresponds to the mediam centered probability level.

  11. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comparison to Reference Methods | Department of Energy Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_lake.pdf More Documents & Publications Reductant Utilization in a LNT + SCR System Spatiotemporal Distribution of NOx

  12. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels

    SciTech Connect (OSTI)

    2009-11-01

    Precision Combustion, Inc. will develop a unique, fuel-flexible Rich Catalytic Lean-Burn (RCL) injector with catalytic combustor capable of enabling ultralow-emission, lean premixed combustion of a wide range of gaseous opportunity fuels. This will broaden the range of opportunity fuels that can be utilized to include low- and ultralow-Btu gases, such as digester and blast furnace gases, and fuels containing reactive species, such as refinery, wellhead, and industrial byproduct gases.

  13. In situ XAS Characterization of Catalytic Nano-Materials with Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Fuel Cells and Batteries | Stanford Synchrotron Radiation Lightsource XAS Characterization of Catalytic Nano-Materials with Applications to Fuel Cells and Batteries Friday, July 12, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Qingying Jia, Dept. of Chemistry and Chemical Biology, Northeastern University, Boston, MA The development of novel electrode materials is hindered by the lack of fundamental understanding of the precise structural effects on the catalytic activity and

  14. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Investigation of a series of transition metal oxides and precious metal based catalysts for ammonia selective oxidation at low temperatures PDF icon deer12_thrun.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon

  15. Catalytic Upgrading of Pyrolysis Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office (BETO) 2015 Project Peer Review Catalytic Upgrading of Pyrolysis Products March 24 th , 2015 Thermochemical Conversion Josh Schaidle NREL This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 2.3.1.314 Goal Statement The goal of this project is to design and develop scalable and cost-effective next generation catalysts for ex-situ catalytic fast pyrolysis (CFP) to improve the fuel quality and stability of the resulting bio-oil by reducing

  16. The Better Buildings Neighborhood View -- April 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 The Better Buildings Neighborhood View -- April 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- April 2012 More Documents & Publications The Better Buildings Neighborhood View -- March 2012 The Better Buildings Neighborhood View - September 2012 The Better Buildings Neighborhood View -- July 2012

  17. The Better Buildings Neighborhood View -- August 2012 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy August 2012 The Better Buildings Neighborhood View -- August 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- August 2012 More Documents & Publications The Better Buildings Neighborhood View - September 2012 The Better Buildings Neighborhood View -- July 2012 The Better Buildings Neighborhood View -- June 2012

  18. The Better Buildings Neighborhood View -- Fall 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fall 2011 The Better Buildings Neighborhood View -- Fall 2011 Better Buildings Neighborhood View, from the Better Buildings Neighborhood Program of the U.S. Department of Energy. PDF icon BB Neighborhood View -- Fall 2011 More Documents & Publications The Better Buildings Neighborhood View -- July 2013 The Better Buildings Neighborhood View - October 2012 The Better Buildings Neighborhood View -- December 2013

  19. The Better Buildings Neighborhood View -- January 2012 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2 The Better Buildings Neighborhood View -- January 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- January 2012 More Documents & Publications The Better Buildings Neighborhood View -- March 2012 The Better Buildings Neighborhood View -- February 2012 The BetterBuildings View

  20. The Better Buildings Neighborhood View -- January 2013 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 3 The Better Buildings Neighborhood View -- January 2013 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program -- January 2013. PDF icon BB Neighborhood View -- January 2013 More Documents & Publications The Better Buildings Neighborhood View - September 2012 The Better Buildings Neighborhood View - October 2012 The Better Buildings Neighborhood View -- April 2013

  1. The Better Buildings Neighborhood View -- July 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 The Better Buildings Neighborhood View -- July 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- July 2012 More Documents & Publications The Better Buildings Neighborhood View -- December 2013 The Better Buildings Neighborhood View -- April 2012 The Better Buildings Neighborhood View -- June 2012

  2. The Better Buildings Neighborhood View -- July 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 The Better Buildings Neighborhood View -- July 2013 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program - July 2013. PDF icon BB Neighborhood View -- July 2013 More Documents & Publications The Better Buildings Neighborhood View -- Fall 2011 The Better Buildings Neighborhood View - October 2012 The Better Buildings Neighborhood View -- December 2013

  3. The Better Buildings Neighborhood View -- June 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June 2012 The Better Buildings Neighborhood View -- June 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- June 2012 More Documents & Publications The Better Buildings Neighborhood View -- August 2012 The Better Buildings Neighborhood View - October 2012 The Better Buildings Neighborhood View -- April 2012

  4. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

    2001-01-01

    A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

  5. Reducing cold-start emissions by catalytic converter thermal management

    SciTech Connect (OSTI)

    Burch, S D; Potter, T F; Keyser, M A; Brady, M J; Michaels, K F

    1995-01-01

    Vacuum insulation and phase-change thermal storage have been used to enhance the heat retention of a prototype catalytic converter. Storing heat in the converter between trips allows exhaust gases to be converted more quickly, significantly reducing cold-start emissions. Using a small metal hydride, the thermal conductance of the vacuum insulation can be varied continuously between 0.49 and 27 W/m{sup 2}K (R-12 to R-0.2 insulation) to prevent overheating of the catalyst. A prototype was installed in a Dodge Neon with a 2.0-liter engine. Following a standard preconditioning and a 23-hour cold soak, an FTP (Federal Test Procedure) emissions test was performed. Although exhaust temperatures during the preconditioning were not hot enough to melt the phase-change material, the vacuum insulation performed well, resulting in a converter temperature of 146{degrees}C after the 23-hour cold soak at 27{degrees}C. Compared to the same converter at ambient conditions, overall emissions of CO and HC were reduced by 52 % and 29 %, to 0.27 and 0.037 g/mile, respectively. The maximum converter temperature during the FTP cycle was 720{degrees}C. This limited testing was performed with a nearly-fresh palladium-only catalyst, but demonstrates the potential of this vacuum insulation approach for emissions reduction and thermal control. Further testing is ongoing. An initial assessment of several production issues is made, including high-volume fabrication challenges, durability, and cost.

  6. Integrating catalytic coal gasifiers with solid oxide fuel cells

    SciTech Connect (OSTI)

    Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

    2010-01-01

    A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

  7. Better Buildings Network View | March 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View | March 2014 Better Buildings Network View | March 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon Better Buildings Network View March 2014 More Documents & Publications Better Buildings Network View | June 2015 Better Buildings Network View | May 2015 Better Buildings Network View | April 2014 Home About the Better Buildings Residential Network How to Join Members

  8. The Better Buildings Neighborhood View - October 2012 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy The Better Buildings Neighborhood View - October 2012 The Better Buildings Neighborhood View - October 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program - October 2012 PDF icon bb_view_october2012.pdf More Documents & Publications The Better Buildings Neighborhood View -- July 2013 The Better Buildings Neighborhood View -- Fall 2011 The Better Buildings Neighborhood View -- December 2

  9. grid history | OpenEI Community

    Open Energy Info (EERE)

    Dc(266) Contributor 31 October, 2014 - 10:58 What do you know about the grid? black out brown out bulk power system electricity grid future grid grid history security Smart Grid...

  10. History of Hanford Site Defense Production (Brief)

    SciTech Connect (OSTI)

    GERBER, M S

    2001-02-01

    This paper acquaints the audience with the history of the Hanford Site, America's first full-scale defense plutonium production site. The paper includes the founding and basic operating history of the Hanford Site, including World War II construction and operations, three major postwar expansions (1947-55), the peak years of production (1956-63), production phase downs (1964-the present), a brief production spurt from 1984-86, the end of the Cold War, and the beginning of the waste cleanup mission. The paper also delineates historical waste practices and policies as they changed over the years at the Hanford Site, past efforts to chemically treat, ''fractionate,'' and/or immobilize Hanford's wastes, and resulting major waste legacies that remain today. This paper presents original, primary-source research into the waste history of the Hanford Site. Finally, the paper places the current Hanford Site waste remediation endeavors in the broad context of American and world history.

  11. History of SPR Releases | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History of SPR Releases History of SPR Releases The Strategic Petroleum Reserve exists, first and foremost, as an emergency response tool the President can use should the United States be confronted with an economically-threatening disruption in oil supplies. A Presidentially-directed release has occurred three times under these conditions. First, in 1991, at the beginning of Operation Desert Storm, the United States joined its allies in assuring the adequacy of global oil supplies when war

  12. Heating Oil Reserve History | Department of Energy

    Energy Savers [EERE]

    Heating Oil Reserve History Heating Oil Reserve History Creation of an emergency reserve of heating oil was directed by President Clinton on July 10, 2000, when he directed then-Energy Secretary Bill Richardson to establish a two million barrel home heating oil component of the Strategic Petroleum Reserve in the Northeast. The intent was to create a buffer large enough to allow commercial companies to compensate for interruptions in supply during severe winter weather, but not so large as to

  13. Environmental Justice History | Department of Energy

    Energy Savers [EERE]

    Justice History Environmental Justice History The exact start of the environmental justice movement in America is not clear. Local groups have complained about unwanted land uses for decades. Prior to the early eighties, these local protests were considered isolated and protesting communities were complaining by themselves and not associated with others similarly situated in other communities. This isolated protesting all changed in the early 1980's and the environmental justice movement became

  14. DOE - NNSA/NFO -- FRMAC History

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History NNSA/NFO Language Options U.S. DOE/NNSA - Nevada Field Office FRMAC History Photo of Three Mile Island Following the accident at the Three Mile Island Nuclear Power Plant in March 1979, the President and Congress directed the impacted federal agencies to develop a plan to provide for an integrated federal response to radiological emergencies. It was recognized that when a major radiological incident impacts the public, the state(s) may need federal assistance to characterize and assess

  15. DNA Origami: A History and Current Perspective

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Origami: A History and Current Perspective Authors: Nangreave, J., Han, D., Liu, Y., and Yan, H. Title: DNA Origami: A History and Current Perspective Source: Current Opinion in Chemical Biology Year: 2010 Volume: 14 Pages: 608-615 ABSTRACT: Researchers have been using DNA for the rational design and construction of nanoscale objects for nearly 30 years. Recently, [`]scaffolded DNA origami' has emerged as one of the most promising assembly techniques in DNA nanotechnology with a broad range of

  16. SPEAR History | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPEAR History Experimental Facilities : The SPEAR Storage Ring Stanford University has a long history of involvement in the development and use of colliding-beam storage rings for particle physics research. The first such machine at Stanford was a small electron-electron collider, shaped like a figure eight, located on the main campus. A collaborative effort between physicists from Princeton and Stanford Universities, this project produced the first physics results ever obtained with the

  17. Atomic Power in Space: A History

    DOE R&D Accomplishments [OSTI]

    1987-03-01

    "Atomic Power in Space," a history of the Space Isotope Power Program of the United States, covers the period from the program's inception in the mid-1950s through 1982. Written in non-technical language, the history is addressed to both the general public and those more specialized in nuclear and space technologies. Interplanetary space exploration successes and achievements have been made possible by this technology, for which there is no known substitue.

  18. History and Impacts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Appliance & Equipment Standards » About » History and Impacts History and Impacts Appliance and equipment efficiency standards have served as one of the nation's most effective policies for improving energy efficiency. The first standards were enacted at the state level in California in 1974. At the national level, the Energy Policy and Conservation Act (EPCA) was enacted in 1975, and established a federal program consisting of test procedures, labeling, and energy targets for consumer

  19. RVA: A Plugin for ParaView 3.14

    Energy Science and Technology Software Center (OSTI)

    2015-09-04

    RVA is a plugin developed for the 64-bit Windows version of the ParaView 3.14 visualization package. RVA is designed to provide support in the visualization and analysis of complex reservoirs being managed using multi-fluid EOR techniques. RVA, for Reservoir Visualization and Analysis, was developed at the University of Illinois at Urbana-Champaign, with contributions from the Illinois State Geological Survey, Department of Computer Science and National Center for Supercomputing Applications. RVA was designed to utilize andmore » enhance the state-of-the-art visualization capabilities within ParaView, readily allowing joint visualization of geologic framework and reservoir fluid simulation model results. Particular emphasis was placed on enabling visualization and analysis of simulation results highlighting multiple fluid phases, multiple properties for each fluid phase (including flow lines), multiple geologic models and multiple time steps. Additional advanced functionality was provided through the development of custom code to implement data mining capabilities. The built-in functionality of ParaView provides the capacity to process and visualize data sets ranging from small models on local desktop systems to extremely large models created and stored on remote supercomputers. The RVA plugin that we developed and the associated User Manual provide improved functionality through new software tools, and instruction in the use of ParaView-RVA, targeted to petroleum engineers and geologists in industry and research. The RVA web site (http://rva.cs.illinois.edu) provides an overview of functions, and the development web site (https://github.com/shaffer1/RVA) provides ready access to the source code, compiled binaries, user manual, and a suite of demonstration data sets. Key functionality has been included to support a range of reservoirs visualization and analysis needs, including: sophisticated connectivity analysis, cross sections through simulation results between selected wells, simplified volumetric calculations, global vertical exaggeration adjustments, ingestion of UTChem simulation results, ingestion of Isatis geostatistical framework models, interrogation of joint geologic and reservoir modeling results, joint visualization and analysis of well history files, location-targeted visualization, advanced correlation analysis, visualization of flow paths, and creation of static images and animations highlighting targeted reservoir features.« less

  20. TotalView Parallel Debugger at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The performance of the GUI can be greatly improved if used in conjunction with free NX software. The TotalView documentation web page is a good resource for learning more...

  1. JOBAID-VIEWING AN EMPLOYEE MATRIX (SUPERVISOR)

    Broader source: Energy.gov [DOE]

    The purpose of this job aid is to guide supervisor users through the step-by-step process of viewing an employee matrix within SuccessFactors Learning.

  2. A common-view disciplined oscillator

    SciTech Connect (OSTI)

    Lombardi, Michael A.; Dahlen, Aaron P.

    2010-05-15

    This paper describes a common-view disciplined oscillator (CVDO) that locks to a reference time scale through the use of common-view global positioning system (GPS) satellite measurements. The CVDO employs a proportional-integral-derivative controller that obtains near real-time common-view GPS measurements from the internet and provides steering corrections to a local oscillator. A CVDO can be locked to any time scale that makes real-time common-view data available and can serve as a high-accuracy, self-calibrating frequency and time standard. Measurement results are presented where a CVDO is locked to UTC(NIST), the coordinated universal time scale maintained at the National Institute of Standards and Technology in Boulder, Colorado.

  3. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B.; Comolli, Alfred G.; McLean, Joseph B.

    1989-01-01

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  4. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  5. Better Buildings Network View | February 2015 | Department of Energy

    Office of Environmental Management (EM)

    5 Better Buildings Network View | February 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon Better Buildings Network View February 2015 More Documents & Publications Better Buildings Network View | June 2015 Nothing But Networking for Residential Network Members Better Buildings Network View | November

  6. The Better Buildings Neighborhood View - Summer 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summer 2011 The Better Buildings Neighborhood View - Summer 2011 The quarterly update newsletter of the Better Buildings program of the U.S. Department of Energy. PDF icon BB Neighborhood View -- Summer 2011 More Documents & Publications The Better Buildings Neighborhood View -- January 2012 The Better Buildings Neighborhood View -- March 2012 The Better Buildings Neighborhood View -- May

  7. The Better Buildings Neighborhood View -- March 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 2012 The Better Buildings Neighborhood View -- March 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program PDF icon BB Neighborhood View -- March 2012 More Documents & Publications The Better Buildings Neighborhood View -- February 2012 The Better Buildings Neighborhood View -- January 2012 Commercial Buildings Integration Program Overview - 2015 BTO Peer Review

  8. The Better Buildings Neighborhood View -- May 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - May 2012 The Better Buildings Neighborhood View -- May 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program PDF icon BB Neighborhood View -- May 2012 More Documents & Publications The Better Buildings Neighborhood View - September 2012 The Better Buildings Neighborhood View -- April

  9. Utah Division of State History | Open Energy Information

    Open Energy Info (EERE)

    History Jump to: navigation, search Logo: Utah Division of State History Name: Utah Division of State History Address: 300 S. Rio Grande St. Place: Salt Lake City, Utah Zip: 84101...

  10. Y-12 History Center | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Y-12 History Center Y-12 History Center Located within the New Hope Center at Y-12, the History Center houses a fascinating collection of informational materials and historical...

  11. Labs and Field Site Histories | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Labs and Field Site Histories Labs and Field Site Histories Labs and Field Site Histories Note: Every effort is made to keep these links current and updated. Yet as many of the links below point to sites not under our direct control, some may stop working without warning . National Laboratories & Technology Centers Operations Offices & Field Sites Ames Laboratory (Iowa) -- History Chicago Office (Illinois) -- History Argonne National Laboratory (Illinois) -- Laboratory History and

  12. Two-stage Catalytic Reduction of NOx with Hydrocarbons

    SciTech Connect (OSTI)

    Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

    2005-12-21

    A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

  13. SPONTANEOUS CATALYTIC WET AIR OXIDATION DURING PRE-TREATMENT OF HIGH-LEVEL RADIOACTIVE WASTE SLUDGE

    SciTech Connect (OSTI)

    Koopman, D.; Herman, C.; Pareizs, J.; Bannochie, C.; Best, D.; Bibler, N.; Fellinger, T.

    2009-10-01

    Savannah River Remediation, LLC (SRR) operates the Defense Waste Processing Facility for the U.S. Department of Energy at the Savannah River Site. This facility immobilizes high-level radioactive waste through vitrification following chemical pretreatment. Catalytic destruction of formate and oxalate ions to carbon dioxide has been observed during qualification testing of non-radioactive analog systems. Carbon dioxide production greatly exceeded hydrogen production, indicating the occurrence of a process other than the catalytic decomposition of formic acid. Statistical modeling was used to relate the new reaction chemistry to partial catalytic wet air oxidation of both formate and oxalate ions driven by the low concentrations of palladium, rhodium, and/or ruthenium in the waste. Variations in process conditions led to increases or decreases in the total oxidative destruction, as well as partially shifting the preferred species undergoing destruction from oxalate ion to formate ion.

  14. Selective Catalytic Oxidation of Hydrogen Sulfide on Activated Carbons Impregnated with Sodium Hydroxide

    SciTech Connect (OSTI)

    Schwartz, Viviane [ORNL; Baskova, Svetlana [ORNL; Armstrong, Timothy R. [ORNL

    2009-01-01

    Two activated carbons of different origin were impregnated with the solution of sodium hydroxide (NaOH) of various concentrations up to 10 wt %, and the effect of impregnation on the catalytic performance of the carbons was evaluated. The catalytic activity was analyzed in terms of the capacity of carbons for hydrogen sulfide (H2S) conversion and removal from hydrogen-rich fuel streams and the emission times of H2S and the products of its oxidation [e.g., sulfur dioxide (SO2) and carbonyl sulfide (COS)]. The results of impregnation showed a significant improvement in the catalytic activity of both carbons proportional to the amount of NaOH introduced. NaOH introduces hydroxyl groups (OH-) on the surface of the activated carbon that increase its surface reactivity and its interaction with sulfur-containing compounds.

  15. Bike-Sharing:History, Impacts, Models of Provision, and Future...

    Open Energy Info (EERE)

    Bike-Sharing:History, Impacts, Models of Provision, and Future Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Bike-Sharing:History, Impacts, Models of Provision, and...

  16. Chronological History of Federal Energy-Efficient Product Procurement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chronological History of Federal Energy-Efficient Product Procurement: Executive, Legislative and Regulatory Requirements, Actions and Mandates Chronological History of Federal...

  17. Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium-Nickel Nanoalloys

    SciTech Connect (OSTI)

    Shan, Shiyao; Petkov, Valeri; Yang, Lefu; Luo, Jin; Joseph, Pharrah; Mayzel, Dina; Prasai, Binay; Wang, Lingyan; Engelhard, Mark H.; Zhong, Chuan-Jian

    2014-05-05

    Alloying palladium (Pd) with other transition metals at the nanoscale has become an important pathway for preparation of low-cost, highly-active and stable catalysts. However the lack of understanding of how the alloying phase state, chemical composition and atomic-scale structure of the alloys at the nanoscale influence their catalytic activity impedes the rational design of Pd-nanoalloy catalysts. This work addresses this challenge by a novel approach to investigating the catalytic oxidation of carbon monoxide (CO) over palladium-nickel (PdNi) nanoalloys with well-defined bimetallic composition, which reveals a remarkable a maximal catalytic activity at Pd:Ni ratio of ~50:50. Key to understanding the structural-catalytic synergy is the use of high-energy synchrotron X-ray diffraction coupled to atomic pair distribution function (HE-XRD/PDF) analysis to probe the atomic structure of PdNi nanoalloys under controlled thermochemical treatments and CO reaction conditions. Three-dimensional (3D) models of the atomic structure of the nanoalloy particles were generated by reverse Monte Carlo simulations (RMC) guided by the experimental HE-XRD/PDF data. Structural details of the PdNi nanoalloys were extracted from the respective 3D models and compared with the measured catalytic properties. The comparison revealed a strong correlation between the phase state, chemical composition and atomic-scale structure of PdNi nanoalloys and their catalytic activity for CO oxidation. This correlation is further substantiated by analyzing the first atomic neighbor distances and coordination numbers inside the nanoalloy particles and at their surfaces. These findings have provided new insights into the structural synergy of nanoalloy catalysts by controlling the phase state, composition and atomic structure, complementing findings of traditional density functional theory studies.

  18. The BetterBuildings View | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The BetterBuildings View The BetterBuildings View The BetterBuildings View Newsletter, April 2011, from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF...

  19. Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them

    DOE Patents [OSTI]

    Schwartz, Michael; White, James H.; Sammells, Anthony F.

    2005-09-27

    This invention relates to gas-impermeable, solid state materials fabricated into membranes for use in catalytic membrane reactors. This invention particularly relates to solid state oxygen anion- and electron-mediating membranes for use in catalytic membrane reactors for promoting partial or full oxidation of different chemical species, for decomposition of oxygen-containing species, and for separation of oxygen from other gases. Solid state materials for use in the membranes of this invention include mixed metal oxide compounds having the brownmillerite crystal structure.

  20. Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them

    DOE Patents [OSTI]

    Schwartz, Michael; White, James H.; Sammels, Anthony F.

    2000-01-01

    This invention relates to gas-impermeable, solid state materials fabricated into membranes for use in catalytic membrane reactors. This invention particularly relates to solid state oxygen anion- and electron-mediating membranes for use in catalytic membrane reactors for promoting partial or full oxidation of different chemical species, for decomposition of oxygen-containing species, and for separation of oxygen from other gases. Solid state materials for use in the membranes of this invention include mixed metal oxide compounds having the brownmillerite crystal structure.

  1. A Simple Approach of Tuning Catalytic Activity of MFI-Zeolites for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature SCR of NOx | Department of Energy A Simple Approach of Tuning Catalytic Activity of MFI-Zeolites for Low-Temperature SCR of NOx A Simple Approach of Tuning Catalytic Activity of MFI-Zeolites for Low-Temperature SCR of NOx Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-18_yang.pdf More Documents & Publications Catalysts via First Principles (Agreement ID:10635)

  2. Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by

    Office of Scientific and Technical Information (OSTI)

    NH3 Over Cu-zeolite Catalysts (Journal Article) | SciTech Connect Journal Article: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Citation Details In-Document Search Title: Impact of Biodiesel-based Na on the Selective Catalytic Reduction of NOx by NH3 Over Cu-zeolite Catalysts Authors: Brookshear, D. William [1] ; Nguyen, Ke [1] ; Toops, Todd J [2] ; Bunting, Bruce G [2] ; Rohr, William F [2] + Show Author Affiliations University of

  3. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Using Cu-zeolite | Department of Energy Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Discusses the impact of Na in biodiesel on three emission control devices: the diesel particulate filter, diesel oxidation catalyst, and zeolyte-based SCR catalyst PDF icon deer11_toops.pdf More Documents & Publications Impacts of Biodiesel on Emission Control

  4. Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters - 4 Way Catalyst and DeNOx Application examples | Department of Energy Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's

  5. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Citation Details In-Document Search This content will become publicly available on September 21, 2016 Title: Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film

  6. NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy -Selective Catalytic Reduction over Ag/Al2O3 Catalysts NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts DRIFT spectroscopy used together with flow reactor experiments to investigate the role of H2 for SCR over Ag/Al2O3 PDF icon deer12_tamm.pdf More Documents & Publications Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis Experimental and Modelling Study of the Effect of Diffusional Limitations on the NH3 SCR Activity Development of Optimal Catalyst

  7. The Effects of Trace Contaminants on Catalytic Processing of Biomass-Derived Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Peterson, Keith L.; Muzatko, Danielle S.; Alderson, Eric V.; Hart, Todd R.; Neuenschwander, Gary G.

    2004-03-25

    Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to value-added chemical products. Trace components include inorganic elements such as alkali metals and alkaline earths, phosphorus or sulfur, aluminum or silicon, chloride, or transition metals. Protein components in biomass feedstocks can lead to formation of peptide fractions (from hydrolysis) or ammonium ions (from more severe breakdown) both of which might interfere with catalysis. The effects of these components on catalytic hydrogenation processing has been studied in batch reactor processing tests

  8. Polymer network/carbon layer on monolith support and monolith catalytic reactor

    DOE Patents [OSTI]

    Nordquist, Andrew Francis; Wilhelm, Frederick Carl; Waller, Francis Joseph; Machado, Reinaldo Mario

    2003-08-26

    The present invention relates to an improved monolith catalytic reactor and a monolith support. The improvement in the support resides in a polymer network/carbon coating applied to the surface of a porous substrate and a catalytic metal, preferably a transition metal catalyst applied to the surface of the polymer network/carbon coating. The monolith support has from 100 to 800 cells per square inch and a polymer network/carbon coating with surface area of from 0.1 to 15 m.sup.2 /gram as measured by adsorption of N.sub.2 or Kr using the BET method.

  9. ,"Catalytic Reforming Downstream Processing of Fresh Feed Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","12/2015","1/15/2010" ,"Release Date:","2/29/2016" ,"Next Release

  10. The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone for the

    Office of Scientific and Technical Information (OSTI)

    H2A.Z-H2B Dimer (Journal Article) | SciTech Connect The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone for the H2A.Z-H2B Dimer Citation Details In-Document Search Title: The Catalytic Subunit of the SWR1 Remodeler Is a Histone Chaperone for the H2A.Z-H2B Dimer Authors: Hong, Jingjun ; Feng, Hanqiao ; Wang, Feng ; Ranjan, Anand ; Chen, Jianhong ; Jiang, Jiansheng ; Ghirlando, Rodolfo ; Xiao, T. Sam ; Wu, Carl ; Bai, Yawen [1] ; HHMI) [2] + Show Author Affiliations (NIH) (

  11. Catalytic Templating Approaches for Three-Dimensional Hollow Carbon/Graphene Oxide Nano-Architectures

    SciTech Connect (OSTI)

    Moon, Gun-Hee; Shin, Yongsoon; Choi, Daiwon; Arey, Bruce W.; Exarhos, Gregory J.; Wang, Chong M.; Choi, Wonyong; Liu, Jun

    2013-01-01

    We report a catalytic templating method to synthesize well-controlled, three-dimensional (3D) nano-architectures with graphene oxide sheets. The 3D composites are prepared via self-assembly of carbon, GO, and spherical alumina-coated silica (ACS) templates during a catalytic reaction porcess. By changing the GO content, we can systematically tune the architecture from layered composites to 3D hollow structures to microporous materials. The composites show a synergistic effect with significantly superior properties than either pure carbon or r-GO prepared with a significant enhancement to its capacitance at high current density.

  12. Mountain View Power Partners III Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    III Wind Farm Jump to: navigation, search Name Mountain View Power Partners III Wind Farm Facility Mountain View Power Partners III Sector Wind energy Facility Type Commercial...

  13. City of Mountain View, Missouri (Utility Company) | Open Energy...

    Open Energy Info (EERE)

    View Place: Missouri Phone Number: (417) 934-2601 Website: mountainviewmo.comindex.phpg Facebook: https:www.facebook.comCityOfMountainViewMissouri Outage Hotline: (877)...

  14. Residential Windows and Window Coverings: A Detailed View of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    View of the Installed Base and User Behavior Residential Windows and Window Coverings: A Detailed View of the Installed Base and User Behavior Includes information about the ...

  15. Mountain View Power Partners II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    II Wind Farm Jump to: navigation, search Name Mountain View Power Partners II Wind Farm Facility Mountain View Power Partners II Sector Wind energy Facility Type Commercial Scale...

  16. OpenEI:Neutral point of view | Open Energy Information

    Open Energy Info (EERE)

    point of view Jump to: navigation, search Neutral point of view (NPOV) means that articles and content contributed or edited on the platform must be unbiased. All significant...

  17. The Better Buildings Neighborhood View -- January 2013 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 The Better Buildings Neighborhood View -- January 2013 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings...

  18. Better Buildings Network View | May 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | May 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon...

  19. Better Buildings Network View | May 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | May 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon...

  20. Better Buildings Network View | February 2014 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | February 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  1. Better Buildings Network View | April 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | April 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  2. Better Buildings Network View | September 2014 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 2014 Better Buildings Network View | September 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential...

  3. The Better Buildings Neighborhood View -- July 2013 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 The Better Buildings Neighborhood View -- July 2013 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood...

  4. Better Buildings Network View | July-August 2014 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | July-August 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network....

  5. Better Buildings Network View | March 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | March 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  6. Better Buildings Network View | July-August 2015 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | July-August 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network....

  7. The Better Buildings Neighborhood View -- April 2013 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 The Better Buildings Neighborhood View -- April 2013 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood...

  8. The Better Buildings Neighborhood View -- April 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 The Better Buildings Neighborhood View -- April 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood...

  9. Better Buildings Network View | November 2014 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | November 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  10. Better Buildings Network View | January 2014 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | January 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  11. Better Buildings Network View | December 2015 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | December 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  12. The Better Buildings Neighborhood View -- August 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2012 The Better Buildings Neighborhood View -- August 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings...

  13. Better Buildings Network View | June 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | June 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon...

  14. Better Buildings Network View | December 2014 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | December 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  15. Better Buildings Network View | November 2015 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | November 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  16. The Better Buildings Neighborhood View -- March 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 2012 The Better Buildings Neighborhood View -- March 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings...

  17. The Better Buildings Neighborhood View -- June 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June 2012 The Better Buildings Neighborhood View -- June 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings...

  18. The Better Buildings Neighborhood View -- July 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 The Better Buildings Neighborhood View -- July 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood...

  19. Better Buildings Network View | October 2014 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | October 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  20. The Better Buildings Neighborhood View -- January 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 The Better Buildings Neighborhood View -- January 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings...

  1. Better Buildings Network View | April 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | April 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  2. Better Buildings Network View | January 2015 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | January 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  3. Better Buildings Network View | February 2015 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | February 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  4. Better Buildings Network View | June 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Better Buildings Network View | June 2014 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon...

  5. The Better Buildings Neighborhood View -- May 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - May 2012 The Better Buildings Neighborhood View -- May 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings...

  6. Better Buildings Network View | March 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | March 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  7. The Better Buildings Neighborhood View -- Fall 2011 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fall 2011 The Better Buildings Neighborhood View -- Fall 2011 Better Buildings Neighborhood View, from the Better Buildings Neighborhood Program of the U.S. Department of Energy....

  8. Better Buildings Network View | October 2015 | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Better Buildings Network View | October 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF...

  9. ALS History: The First 20 Years

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History: The First 20 Years Print Below is an interactive timeline covering highlights of the first 20 years of ALS history. By no means exhaustive, it is meant to provide a broad overview of the people and events that have helped shape the ALS as well as a sense of the breadth of the science that has been done here. Click on items to see more detail. Slide the blue rectangle at bottom to move forward or backward in time. Color Key: Science Highlights (green); People and Events (orange);

  10. History of the DOE Human Genome Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the DOE Human Genome Program The following history is taken from the U.S. Department of Energy 1991-91 Human Genome Program Report (June 1992). This is an archived item. A brief history of the U.S. Department of Energy (DOE) Human Genome Program will be useful in a discussion of the objectives of the DOE program as well as those of the collaborative U.S. Human Genome Project. The Office of Health and Environmental Research (OHER) of DOE and its predecessor agencies--the Atomic Energy

  11. Introduction to Y-12's history

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Y-12's History This article marks the beginning of a series that will focus on the history of the Y-12 National Security Complex. Y-12 has employed from 22,000 at its peak to 8,000 in the 1980's during the winning of the Cold War and for the past several years has held an average of about 4,500. It is one of three major Manhattan Project sites in Oak Ridge. Y-12 is the nation's sole storage location for weapons grade uranium, is the Department of Energy's National Nuclear Security

  12. The History of DEER | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The History of DEER The History of DEER Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_eberhardt.pdf More Documents & Publications Update on Progress of APBF-DEC EGR/DPF/SCR Demonstration Program at SwRI After Petroleum Fuels of the Future for Cars and Trucks

  13. History of Air Conditioning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History of Air Conditioning History of Air Conditioning July 20, 2015 - 3:15pm Addthis Paul Lester Paul Lester Digital Content Specialist, Office of Public Affairs MORE ON AIR CONDITIONING Check out our Energy Saver 101 infographic to learn how air conditioners work. Go to Energy Saver for more tips and advice on home cooling. Stay up-to-date on how the Energy Department is working to improve air conditioning technology. We take the air conditioner for granted, but imagine what life would be

  14. A History of the Atomic Energy Commission | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Atomic Energy Commission A History of the Atomic Energy Commission A History of the Atomic Energy Commission - written by Alice L. Buck Washington, D.C.: U.S. Department of Energy, July 1983. 41 pp. PDF icon AEC History.pdf More Documents & Publications The History of Nuclear Energy The Manhattan Project Hewlett and Holl - Atoms for Peace and War

  15. Catalytic converter having a monolith with support and seal means therefor

    SciTech Connect (OSTI)

    Foster, M.R.; Smith, J.E.

    1980-12-16

    A catalytic converter is described that has a catalyst coated monolith of frangible material supported in a sheet metal housing by both a wire mesh sleeve and intumescent sleeve with the latter also providing sealing between the monolith and the housing.

  16. Catalytic cracking. (Latest citations from the NTIS data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The bibliography contains citations concerning applications of catalytic cracking in fluidized beds, moving beds, refineries, vacuum distillation, and reformers. Design criteria, models, controls, and operating procedures are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  17. Catalytic cracking. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The bibliography contains citations concerning applications of catalytic cracking in fluidized beds, moving beds, refineries, vacuum distillation, and reformers. Design criteria, models, controls, and operating procedures are also discussed. (Contains 250 citations and includes a subject term index and title list.)

  18. The structure of the catalytic domain of a plant cellulose synthase and its assembly into dimers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Olek, Anna T.; Rayon, Catherine; Makowski, Lee; Kim, Hyung Rae; Ciesielski, Peter; Badger, John; Paul, Lake N.; Ghosh, Subhangi; Kihara, Daisuke; Crowley, Michael; et al

    2014-07-10

    Cellulose microfibrils are para-crystalline arrays of several dozen linear (1→4)-β-d-glucan chains synthesized at the surface of the cell membrane by large, multimeric complexes of synthase proteins. Recombinant catalytic domains of rice (Oryza sativa) CesA8 cellulose synthase form dimers reversibly as the fundamental scaffold units of architecture in the synthase complex. Specificity of binding to UDP and UDP-Glc indicates a properly folded protein, and binding kinetics indicate that each monomer independently synthesizes single glucan chains of cellulose, i.e., two chains per dimer pair. In contrast to structure modeling predictions, solution x-ray scattering studies demonstrate that the monomer is a two-domain, elongatedmore » structure, with the smaller domain coupling two monomers into a dimer. The catalytic core of the monomer is accommodated only near its center, with the plant-specific sequences occupying the small domain and an extension distal to the catalytic domain. This configuration is in stark contrast to the domain organization obtained in predicted structures of plant CesA. As a result, the arrangement of the catalytic domain within the CesA monomer and dimer provides a foundation for constructing structural models of the synthase complex and defining the relationship between the rosette structure and the cellulose microfibrils they synthesize.« less

  19. Polarographic catalytic currents and their use in the analysis of waters

    SciTech Connect (OSTI)

    Kheifets, L.Ya.; Cherevik, A.V.; Vasyukov, A.E.; Kabanenko, L.F.

    1987-08-20

    It was shown that the magnitude of the catalytic effects and the lower limits of the determinable contents c/sub 1/ in the various types of polarography differ by 2-100 times for the following systems: Cu(II), Ni(II), Co(II)-dimethylglyoxime; V(V)-cupferron-quinine; Cr(III), (VI)-nitrate; Ti(IV)-organic acid-chlorate. The c/sub 1/ values obtained in practice do not correspond for all the systems to the values calculated from the magnitude of the catalytic effect, since the catalytic currents begin to show up on the attainment of a minimum (threshold) concentration of the metal for the given system. The threshold concentrations of the metals were established for some of the systems. The discovered characteristics of the catalytic currents were used in the selection of polarographic methods for the determination of Cu(II), Ni(II), Co(II), V(V), Cr(III), (VI), and Ti(IV) in natural waters at the level of the maximum permissible concentration.

  20. Control of Substrate Access to the Active Site and Catalytic Mechanism of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane and Toluene Monooxygenases | Stanford Synchrotron Radiation Lightsource Control of Substrate Access to the Active Site and Catalytic Mechanism of Methane and Toluene Monooxygenases Friday, June 22, 2012 - 3:30pm SSRL Main Conference Room 137-322 Prof. Stephen J. Lippard (MIT):

  1. Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Westmont, IL); Wang, Xiaoping (Naperville, IL)

    2010-08-03

    A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is then introduced to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes over the substrate with a catalytically active transition metal incorporated throughout the nanotubes.

  2. The Role of Organic Capping Layers of Platinum Nanoparticles in Catalytic Activity of CO Oxidation

    SciTech Connect (OSTI)

    Park, Jeong Y.; Aliaga, Cesar; Renzas, J. Russell; Lee, Hyunjoo; Somorjai, Gabor A.

    2008-12-17

    We report the catalytic activity of colloid platinum nanoparticles synthesized with different organic capping layers. On the molecular scale, the porous organic layers have open spaces that permit the reactant and product molecules to reach the metal surface. We carried out CO oxidation on several platinum nanoparticle systems capped with various organic molecules to investigate the role of the capping agent on catalytic activity. Platinum colloid nanoparticles with four types of capping layer have been used: TTAB (Tetradecyltrimethylammonium Bromide), HDA (hexadecylamine), HDT (hexadecylthiol), and PVP (poly(vinylpyrrolidone)). The reactivity of the Pt nanoparticles varied by 30%, with higher activity on TTAB coated nanoparticles and lower activity on HDT, while the activation energy remained between 27-28 kcal/mol. In separate experiments, the organic capping layers were partially removed using ultraviolet light-ozone generation techniques, which resulted in increased catalytic activity due to the removal of some of the organic layers. These results indicate that the nature of chemical bonding between organic capping layers and nanoparticle surfaces plays a role in determining the catalytic activity of platinum colloid nanoparticles for carbon monoxide oxidation.

  3. January 2013 Most Viewed Documents for National Defense | OSTI, US Dept of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy, Office of Scientific and Technical Information January 2013 Most Viewed Documents for National Defense Dynamic equation of state and strength properties of unreacted PBXW-128 explosive Chhabildas, L.C.; Grady, D.E.; Reinhart, W.D.; Wilson, L.T. From separations to reconstitution - a short history of Plutonium in the U.S. and Russia Gray, L W Condensation induced water hammer safety Gintner, M.A. Direct calibration of the yield of nuclear explosion Nakanishi, K.; Nikolayev, A.

  4. Women's History Month: Women of Geothermal

    Broader source: Energy.gov [DOE]

    When it comes to equality in employment for women, EERE's Geothermal Technologies Office is leading the way, literally. Guided by Dr. Susan Hamm as acting director, the program has equal representation of women in the office's science, technology, engineering and mathematics (STEM) positions. EERE celebrates the Women of Geothermal in Women's History Month.

  5. A Brief History in Time of Ion Traps and their Achievements in Science

    DOE R&D Accomplishments [OSTI]

    Holzscheiter, M. H.

    1994-01-01

    A short history of the development of the ion storage technique for precision experiments is given. This is by no means meant to be a complete review of the field, but the intend is to use a few specific examples to describe how the persistence, ingenuity, and experimental skill of a few people has generated the core of a field which is now growing at an ever faster pace, spreading into new areas, developing sub fields, and allowing a view at nature, using very modest experimental equipment, which by far rivals even the most ambitious dreams of high energy physics.

  6. Linked-View Parallel Coordinate Plot Renderer

    Energy Science and Technology Software Center (OSTI)

    2011-06-28

    This software allows multiple linked views for interactive querying via map-based data selection, bar chart analytic overlays, and high dynamic range (HDR) line renderings. The major component of the visualization package is a parallel coordinate renderer with binning, curved layouts, shader-based rendering, and other techniques to allow interactive visualization of multidimensional data.

  7. The Better Buildings Neighborhood View - September 2012 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy September 2012 The Better Buildings Neighborhood View - September 2012 Monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- September 2012 More Documents & Publications The Better Buildings Neighborhood View -- Fall 2011 The Better Buildings Neighborhood View -- July

  8. Better Buildings Network View | September 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View | September 2015 Better Buildings Network View | September 2015 The Better Buildings Network View monthly newsletter from the U.S. Department of Energy's Better Buildings Residential Network. PDF icon Better Buildings Network View September 2015 More Documents & Publications TTWG Licensing Guide ITP Aluminum: Technical Working Group on Inert Anode Technologies EIS-0333: Draft Environmental Impact Statement

  9. The Better Buildings Neighborhood View -- December 2013 | Department of

    Energy Savers [EERE]

    Energy The Better Buildings Neighborhood View -- December 2013 The Better Buildings Neighborhood View -- December 2013 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- December 2013 More Documents & Publications The Better Buildings Neighborhood View -- July 2013 Focus Series: Philadelphia Energyworks: In the City of Brotherly Love, Sharing Know-How Leads to

  10. The Better Buildings Neighborhood View -- February 2012 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy February 2012 The Better Buildings Neighborhood View -- February 2012 The Better Buildings Neighborhood View monthly newsletter from the U.S. Department of Energy's Better Buildings Neighborhood Program. PDF icon BB Neighborhood View -- February 2012 More Documents & Publications The Better Buildings Neighborhood View -- March 2012 The Better Buildings Neighborhood View -- January 2012 Microsoft Word - T4_VEIC_TO2_ Sub3_Residential Retrofit Program Design Guide Play Book_TEAM 4

  11. Extended Community: An Oral History of the Community Environmental Monitoring Program (CEMP), 1989 - 2003

    SciTech Connect (OSTI)

    Susan DeSilva

    2004-07-01

    Studying the Community Environmental Monitoring Program (CEMP) provides a unique opportunity to trace a concept created by two nuclear industry originators from inception, as it transitioned through several stewardship agencies, to management by a non-profit organization. This transition is informed not only by changes over two decades in the views of the general populace toward nuclear testing but also by changing political climates and public policies. Several parallel histories accompanied the development of the CEMP: an administrative history, an environmental history, and a history of changing public perception of not only nuclear testing, but other activities involving radiation such as waste transportation, as well. Although vital, those histories will be provided only as background to the subject of this study, the oral histories gathered in this project. The oral histories collected open a window into the nuclear testing history of Nevada and Utah that has not heretofore been opened. The nuclear industry has generated a great deal of positive and negative reaction since its inception. The CEMP emerged with specific objectives. It was designed to provide information to potential downwind communities and counter negative perceptions by creating more community involvement and education about the testing. The current objectives of the program are to: (1) Manage and maintain the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO) offsite monitoring program including 26 radiation and environmental monitoring stations with associated equipment. Provide air sample collection and analysis, radiological and meteorological data collection, interpretation and reporting. (2) Facilitate independent operation of radiological monitoring stations and data verification by private citizens living in communities in proximity to the Nevada Test Site (NTS). (3) Hire and initiate training of local citizens to serve as Community Environmental Monitors (CEMs) in designated communities. (4) Provide relevant training by qualified instructors to the CEMs as necessary. (5) Assist and manage CEMs in accomplishing their duties, and ensure that contracts and paychecks are issued on schedule. (6) Provide CEMs and Emeriti monthly materials to facilitate public awareness. This project explores how those objectives evolved over time with changes in the nuclear testing program. How similar are today's objectives to those originally established for the program? Do those objectives reflect a changing political landscape as well as changes in testing needs? Those questions and more will be addressed as we follow the program from its inception, through earlier versions administered first by the Public Health Service (PHS), then by the U.S. Environmental Protection Agency (EPA) to the current administrator, the Desert Research Institute (DRI).

  12. Y-12 and history of clearance designators

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the history of clearance designators One of the major areas of emphasis for the Manhattan Project was to ensure that information about the project remained secure. There was good reason for concern as the information about splitting the atom had recently been announced in the scientific community and thus was known worldwide. Otto Hahn and Fritz Strassmann of Germany split the uranium atom, building on research by Enrico Fermi. The Atomic Archive's biography of Lise Meitner (1878-1968)

  13. Nuclear reactor characteristics and operational history

    Gasoline and Diesel Fuel Update (EIA)

    1. Capacity and Generation, Table 3. Characteristics and Operational History Table 2. U.S. Nuclear Reactor Ownership Data PDF XLS Plant/Reactor Name Generator ID Utility Name - Operator Owner Name % Owned Arkansas Nuclear One 1 Entergy Arkansas Inc Entergy Arkansas Inc 100 Arkansas Nuclear One 2 Entergy Arkansas Inc Entergy Arkansas Inc 100 Beaver Valley 1 FirstEnergy Nuclear Operating Company FirstEnergy Nuclear Generation Corp 100 Beaver Valley 2 FirstEnergy Nuclear Operating Company

  14. Nuclear reactor characteristics and operational history

    Gasoline and Diesel Fuel Update (EIA)

    Nuclear > U.S. reactor operation status tables Nuclear Reactor Operational Status Tables Release date: November 22, 2011 Next release date: TBD See also: Table 1. Capacity and Generation, Table 2. Ownership Data Table 3. Nuclear Reactor Characteristics and Operational History PDF XLS Plant Name Generator ID Type Reactor Supplier and Model Construction Start Grid Connection Original Expiration Date License Renewal Application License Renewal Issued Extended Expiration Arkansas Nuclear One 1

  15. A History of the Southeastern Power Administration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Southeastern Power Administration 1990-2010 SERVING SOUTHEAST the Distribu teD by us Department of energy southeastern Power Administration 2012 A History of the Southeastern Power Administration 1990-2010 SERVING SOUTHEAST the ii Project contribu tors Sponsor us Department of energy, southeastern Power Administration Contracting Agency us Army corps of engineers, Mobile District Author Patricia stallings, brockington and Associates, inc. Design and Editing john cason and Alicia sullivan,

  16. Monodisperse metal nanoparticle catalysts on silica mesoporous supports: synthesis, characterizations, and catalytic reactions

    SciTech Connect (OSTI)

    Somorjai, G.A.

    2009-09-14

    The design of high performance catalyst achieving near 100% product selectivity at maximum activity is one of the most important goals in the modern catalytic science research. To this end, the preparation of model catalysts whose catalytic performances can be predicted in a systematic and rational manner is of significant importance, which thereby allows understanding of the molecular ingredients affecting the catalytic performances. We have designed novel 3-dimensional (3D) high surface area model catalysts by the integration of colloidal metal nanoparticles and mesoporous silica supports. Monodisperse colloidal metal NPs with controllable size and shape were synthesized using dendrimers, polymers, or surfactants as the surface stabilizers. The size of Pt, and Rh nanoparticles can be varied from sub 1 nm to 15 nm, while the shape of Pt can be controlled to cube, cuboctahedron, and octahedron. The 3D model catalysts were generated by the incorporation of metal nanoparticles into the pores of mesoporous silica supports via two methods: capillary inclusion (CI) and nanoparticle encapsulation (NE). The former method relies on the sonication-induced inclusion of metal nanoparticles into the pores of mesoporous silica, whereas the latter is performed by the encapsulation of metal nanoparticles during the hydrothermal synthesis of mesoporous silica. The 3D model catalysts were comprehensively characterized by a variety of physical and chemical methods. These catalysts were found to show structure sensitivity in hydrocarbon conversion reactions. The Pt NPs supported on mesoporous SBA-15 silica (Pt/SBA-15) displayed significant particle size sensitivity in ethane hydrogenolysis over the size range of 1-7 nm. The Pt/SBA-15 catalysts also exhibited particle size dependent product selectivity in cyclohexene hydrogenation, crotonaldehyde hydrogenation, and pyrrole hydrogenation. The Rh loaded SBA-15 silica catalyst showed structure sensitivity in CO oxidation reaction. In addition, Pt-mesoporous silica core-shell structured NPs (Pt{at}mSiO{sub 2}) were prepared, where the individual Pt NP is encapsulated by the mesoporous silica layer. The Pt{at}mSiO{sub 2} catalysts showed promising catalytic activity in high temperature CO oxidation. The design of catalytic structures with tunable parameters by rational synthetic methods presents a major advance in the field of catalyst synthesis, which would lead to uncover the structure-function relationships in heterogeneous catalytic reactions.

  17. Better Buildings Network View November 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BetterBuildings Network View News From the Field Capturing Efficiency in Residential Real Estate Transactions The U.S. Departmenr of Energy (DOE) has released More Real Estate Resources a new white paper that highlights how residential programs can help make home resale prices account for the value of high- performance energy efficiency features to appraisers, real estate agents, mortgage lenders, homebuyers, and sellers. Dig deeper into the hot topic of Multiple studies in recent valuing energy

  18. Better Buildings Network View, April 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View News From the Field April 2015 On Earth Day, Discover Solutions in More Than 100 Past Peer Exchange Calls Mark Earth Day by going to a new interactive archive Expand Your Solutions containing 108 Peer Search Exchange Call summaries dating as far back as 2011 that is now available for residential energy efficiency program research and application. Users can sort summaries by call topic, title, and date, Find even more proven practices in the Better Buildings

  19. Better Buildings Network View, July 2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View | July 2014 Browse the New Better Buildings Residential Network Website We invite you to visit the new Better Buildings Residential Network website launched on July 14, 2014. Visitors can find everything from how to join the Residential Network to the benefits of becoming a member. Following are a few highlights: Upcoming Peer Exchange Call information is listed on our Home page. Our Resources page, devoted to materials such as program newsletters and the U.S.

  20. Better Buildings Network View, June 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View News From the Field June 2015 First-Ever Network Member Gathering Held at 2015 Better Buildings Summit More than 800 participants met at the 2015 Better Buildings Summit in Washington, D.C., to engage in dialogue focused on sharing proven approaches for greater energy efficiency in buildings. This year was the first to incorporate the residential sector with targeted sessions for energy efficiency program administrators and partners. Speakers included leaders from

  1. Better Buildings Network View, March 2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    From the Field Better Buildings Network View | March 2014 March 2014 Network Members Invited to Review Optional Program Benchmarking Guide The first Better Buildings Residential Network Next Steps voluntary initiative will Winter 2014: DOE finalizes benchmark programs so guide and pilots it with up to members can see how they nine Residential Network compare to others, and you members are invited to provide DOE evaluates feedback on a draft Guide Spring 2014: pilot and starts defining for

  2. Better Buildings Network View, March 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Network View | March 2015 News From the Field March 2015 Motivate Energy Upgrades With New Network Incentives Toolkit The Better Buildings Residential Network has Voluntary Initiatives Get developed a Designing Social-Take Part Incentives Toolkit to help energy efficiency organizations design incentives that motivate potential customers to act by lowering the risk, decreasing the cost, or offering additional benefits with home energy upgrades. Many residential energy efficiency programs have

  3. Better Buildings Network View, May 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View News From the Field May 2015 Nearly 50 Home Performance with ENERGY STAR ® Sponsors Join the Residential Network The U.S. Department of Energy's (DOE's) Home Performance with ENERGY STAR (HPwES) program announced this month that its 49 Sponsors will be considered members of the Better Buildings Residential Network and begin to receive Network membership benefits. The goal of Home Performance with ENERGY STAR is to help homeowners improve the efficiency and comfort

  4. BetterBuildings Network View, June 2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Network View | June 2014 More Than 60 Georgetown University Energy Prize Communities Join the Residential Network in Bulk The Better Buildings Residential Network announced an agreement with the Georgetown University Energy Prize (GUEP) competition to welcome all participating communities as members, which brings the total number to more than 130. More than 60 new members, representing cities and counties with populations between 5,000 and 250,000, will significantly expand the

  5. Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P.

    2012-11-13

    A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

  6. ALD Functionalized Nanoporous Gold: Thermal Stability, Mechanical Properties, and Catalytic Activity

    SciTech Connect (OSTI)

    Biener, M M; Biener, J; Wichmann, A; Wittstock, A; Baumann, T F; Baeumer, M; Hamza, A V

    2011-03-24

    Nanoporous metals have many technologically promising applications but their tendency to coarsen limits their long-term stability and excludes high temperature applications. Here, we demonstrate that atomic layer deposition (ALD) can be used to stabilize and functionalize nanoporous metals. Specifically, we studied the effect of nanometer-thick alumina and titania ALD films on thermal stability, mechanical properties, and catalytic activity of nanoporous gold (np-Au). Our results demonstrate that even only one-nm-thick oxide films can stabilize the nanoscale morphology of np-Au up to 1000 C, while simultaneously making the material stronger and stiffer. The catalytic activity of np-Au can be drastically increased by TiO{sub 2} ALD coatings. Our results open the door to high temperature sensor, actuator, and catalysis applications and functionalized electrodes for energy storage and harvesting applications.

  7. Low density microcellular carbon or catalytically impregnated carbon foams and process for their prepartion

    DOE Patents [OSTI]

    Hopper, Robert W. (Danville, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1988-01-01

    Machinable and structurally stable, low density microcellular carbon, and catalytically impregnated carbon, foams, and process for their preparation, are provided. Pulverized sodium chloride is classified to improve particle size uniformity, and the classified particles may be further mixed with a catalyst material. The particles are cold pressed into a compact having internal pores, and then sintered. The sintered compact is immersed and then submerged in a phenolic polymer solution to uniformly fill the pores of the compact with phenolic polymer. The compact is then heated to pyrolyze the phenolic polymer into carbon in the form of a foam. Then the sodium chloride of the compact is leached away with water, and the remaining product is freeze dried to provide the carbon, or catalytically impregnated carbon, foam.

  8. Low density microcellular carbon or catalytically impregnated carbon forms and process for their preparation

    DOE Patents [OSTI]

    Hopper, Robert W. (Danville, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1989-01-01

    Machinable and structurally stable, low density microcellular carbon, and catalytically impregnated carbon, foams, and process for their preparation, are provided. Pulverized sodium chloride is classified to improve particle size uniformity, and the classified particles may be further mixed with a catalyst material. The particles are cold pressed into a compact having internal pores, and then sintered. The sintered compact is immersed and then submerged in a phenolic polymer solution to uniformly fill the pores of the compact with phenolic polymer. The compact is then heated to pyrolyze the phenolic polymer into carbon in the form of a foam. Then the sodium chloride of the compact is leached away with water, and the remaining product is freeze dried to provide the carbon, or catalytically impregnated carbon, foam.

  9. Catalytic igniters and their use to ignite lean hydrogen-air mixtures

    DOE Patents [OSTI]

    McLean, William J. (Oakland, CA); Thorne, Lawrence R. (Livermore, CA); Volponi, Joanne V. (Livermore, CA)

    1988-01-01

    A catalytic igniter which can ignite a hydrogen-air mixture as lean as 5.5% hydrogen with induction times ranging from 20 s to 400 s, under conditions which may be present during a loss-of-liquid-coolant accident at a light water nuclear reactor comprises (a) a perforate catalytically active substrate, such as a platinum coated ceramic honeycomb or wire mesh screen, through which heated gases produced by oxidation of the mixture can freely flow and (b) a plurality of thin platinum wires mounted in a thermally conductive manner on the substrate and positioned thereon so as to be able to receive heat from the substrate and the heated gases while also in contact with unoxidized gases.

  10. Synthetic and Thermodynamic Investigations of Ancillary Ligand Influence on Catalytic Organometallic Systems. Final Report

    SciTech Connect (OSTI)

    Nolan, Steven

    2003-03-20

    During the grant period we have been involved in synthesizing and experimentally determining solution enthalpy values associated with partially fluorinated ligands. This has lead to the publication of manuscripts dealing with synthetic, calorimetric and catalytic behavior of partially fluorinated ligands. The collaboration with Los Alamos researchers has lead to the publication of catalytic results in sc CO{sub 2} which have proven very interesting. Furthermore, we have also examined ligands that behave as phosphine mimics. The N-heterocyclic carbenes have been explored as alternatives for tertiary phosphines and have resulted in the design and construction of efficient palladium and nickel system capable of performing C-C and C-N cross coupling reactions. The initial studies in this areas were made possible by exploratory work conducted under the DOE/EPSCoR grant.

  11. Low density microcellular carbon or catalytically impregnated carbon foams and process for their preparation

    DOE Patents [OSTI]

    Hooper, R.W.; Pekala, R.W.

    1987-04-30

    Machinable and structurally stable, low density microcellular carbon, and catalytically impregnated carbon, foams, and process for their preparation, are provided. Pulverized sodium chloride is classified to improve particle size uniformity, and the classified particles may be further mixed with a catalyst material. The particles are cold pressed into a compact having internal pores, and then sintered. The sintered compact is immersed and then submerged in a phenolic polymer solution to uniformly fill the pores of the compact with phenolic polymer. The compact is then heated to pyrolyze the phenolic polymer into carbon in the form of a foam. Then the sodium chloride of the compact is leached away with water, and the remaining product is freeze dried to provide the carbon, or catalytically impregnated carbon, foam.

  12. Catalytic and reactive polypeptides and methods for their preparation and use

    DOE Patents [OSTI]

    Schultz, Peter (Oakland, CA)

    1994-01-01

    Catalytic and reactive polypeptides include a binding site specific for a reactant or reactive intermediate involved in a chemical reaction of interest. The polypeptides further include at least one active functionality proximate the binding site, where the active functionality is capable of catalyzing or chemically participating in the chemical reaction in such a way that the reaction rate is enhanced. Methods for preparing the catalytic peptides include chemical synthesis, site-directed mutagenesis of antibody and enzyme genes, covalent attachment of the functionalities through particular amino acid side chains, and the like. This invention was made with Government support under Grant Contract No. AI-24695, awarded by the Department of health and Human Services, and under Grant Contract No. N 00014-87-K-0256, awarded by the Office of Naval Research. The Government has certain rights in this invention.

  13. Catalytic two-stage coal liquefaction process having improved nitrogen removal

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA)

    1991-01-01

    A process for catalytic multi-stage hydrogenation and liquefaction of coal to produce high yields of low-boiling hydrocarbon liquids containing low concentrations of nitogen compounds. First stage catalytic reaction conditions are 700.degree.-800.degree. F. temperature, 1500-3500 psig hydrogen partial pressure, with the space velocity maintained in a critical range of 10-40 lb coal/hr ft.sup.3 catalyst settled volume. The first stage catalyst has 0.3-1.2 cc/gm total pore volume with at least 25% of the pore volume in pores having diameters of 200-2000 Angstroms. Second stage reaction conditions are 760.degree.-870.degree. F. temperature with space velocity exceeding that in the first stage reactor, so as to achieve increased hydrogenation yield of low-boiling hydrocarbon liquid products having at least 75% removal of nitrogen compounds from the coal-derived liquid products.

  14. Structure and Reactivity of Surface Oxides on Pt(110) during Catalytic CO Oxidation

    SciTech Connect (OSTI)

    Ackermann, M.D.; Pedersen, T.M.; Hammer, B.; Hendriksen, B.L.M.; Bobaru, S.C.; Frenken, J.W.M.; Robach, O.; Quiros, C.

    2005-12-16

    We present the first structure determination by surface x-ray diffraction during the restructuring of a model catalyst under reaction conditions, i.e., at high pressure and high temperature, and correlate the restructuring with a change in catalytic activity. We have analyzed the Pt(110) surface during CO oxidation at pressures up to 0.5 bar and temperatures up to 625 K. Depending on the O{sub 2}/CO pressure ratio, we find three well-defined structures: namely, (i) the bulk-terminated Pt(110) surface, (ii) a thin, commensurate oxide, and (iii) a thin, incommensurate oxide. The commensurate oxide only appears under reaction conditions, i.e., when both O{sub 2} and CO are present and at sufficiently high temperatures. Density functional theory calculations indicate that the commensurate oxide is stabilized by carbonate ions (CO{sub 3}{sup 2-}). Both oxides have a substantially higher catalytic activity than the bulk-terminated Pt surface.

  15. Catalytic conversion of light alkanes, Phase 1. Topical report, January 1990--January 1993

    SciTech Connect (OSTI)

    1993-12-31

    The authors have found a family of new catalytic materials which, if successfully developed, will be effective in the conversion of light alkanes to alcohols or other oxygenates. Catalysts of this type have the potential to convert natural gas to clean-burning high octane liquid fuels directly without requiring the energy-intensive steam reforming step. In addition they also have the potential to upgrade light hydrocarbons found in natural gas to a variety of high value fuel and chemical products. In order for commercially useful processes to be developed, increases in catalytic life, reaction rate and selectivity are required. Recent progress in the experimental program geared to the further improvement of these catalysts is outlined.

  16. Electro-catalytic oxidation device for removing carbon from a fuel reformate

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL)

    2010-02-23

    An electro-catalytic oxidation device (ECOD) for the removal of contaminates, preferably carbonaceous materials, from an influent comprising an ECOD anode, an ECOD cathode, and an ECOD electrolyte. The ECOD anode is at a temperature whereby the contaminate collects on the surface of the ECOD anode as a buildup. The ECOD anode is electrically connected to the ECOD cathode, which consumes the buildup producing electricity and carbon dioxide. The ECOD anode is porous and chemically active to the electro-catalytic oxidation of the contaminate. The ECOD cathode is exposed to oxygen, and made of a material which promotes the electro-chemical reduction of oxygen to oxidized ions. The ECOD electrolyte is non-permeable to gas, electrically insulating and a conductor to oxidized. The ECOD anode is connected to the fuel reformer and the fuel cell. The ECOD electrolyte is between and in ionic contact with the ECOD anode and the ECOD cathode.

  17. In Situ Diffuse Reflectance IR Spectroscopy and X-ray Absorption Spectroscopy for Fast Catalytic Processes

    SciTech Connect (OSTI)

    N Marinkovic; Q Wang; A Frenkel

    2011-12-31

    A new instrument for synchronous in situ investigations of catalytic materials by IR and X-ray absorption spectroscopies was designed and built at the X18A beamline of the National Synchrotron Light Source of Brookhaven National Laboratory. It provides analytical tools for solving structural, electronic and kinetic problems in catalysis science by two complementary methods. Among the features attractive for catalysis research are the broad range of catalytically active elements that can be investigated (starting with Ni and beyond), the wide range of reaction conditions (temperatures up to 873 K, various reactive gases) and time scales (starting from tens of seconds). The results of several representative experiments that illustrate the attractive capabilities of the new set-up are discussed.

  18. Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia

    DOE Patents [OSTI]

    Pence, Dallas T.; Thomas, Thomas R.

    1980-01-01

    Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

  19. When ruthenia met titania: Achieving extraordinary catalytic activity at low temperature by nanostructuring of oxides

    SciTech Connect (OSTI)

    Graciani, J.; Stacchiola, D.; Yang, F.; Evans, J.; Vidal, A. B.; Rodriguez, J. A.; Sanz, J. F.

    2015-09-09

    Nanostructured RuOx/TiO2(110) catalysts have a remarkable catalytic activity for CO oxidation at temperatures in the range of 350375 K. Furthermore, the RuO2(110) surface has no activity. The state-of-the-art DFT calculations indicate that the main reasons for such an impressive improvement in the catalytic activity are: (i) a decrease of the diffusion barrier of adsorbed O atoms by around 40%, from 1.07 eV in RuO2(110) to 0.66 eV in RuOx/TiO2(110), which explains the shift of the activity to lower temperatures and (ii) a lowering of the barrier by 20% for the association of adsorbed CO and O species to give CO2 (the main barrier for the CO oxidation reaction) passing from around 0.7 eV in RuO2(110) to 0.55 eV in RuOx/TiO2(110). We show that the catalytic properties of ruthenia are strongly modified when supported as nanostructures on titania, attaining higher activity at temperatures 100 K lower than that needed for pure ruthenia. As in other systems consisting of ceria nanostructures supported on titania, nanostructured ruthenia shows strongly modified properties compared to the pure oxide, consolidating the fact that the nanostructuring of oxides is a main way to attain higher catalytic activity at lower temperatures.

  20. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic

    Office of Scientific and Technical Information (OSTI)

    Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Fluid-Bed Testing of Greatpoint