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1

DEPARTMENT OFl!NI1RGY EERE PROJECT MANAGEMENT CENTER NEPA DETERMINATIO...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

OFlNI1RGY EERE PROJECT MANAGEMENT CENTER NEPA DETERMINATION Page 1 of2 RECIPIENT:County of Lancaster STATE: PA PROJECf TITLE : EECBG - Lancaster County Prison Energy Eficiency...

2

U.S. DEPARTMENT OF I!NI!RGY EERE PROJECT MANAGEMENT CENTER NFPA DETTIUlIINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

I!NI!RGY I!NI!RGY EERE PROJECT MANAGEMENT CENTER NFPA DETTIUlIINATION RECIPIENT:Magelian Midstream Partners. LP (SEP Sub-recipient of the Iowa Office of Energy STATE: IA Independence) PROJECf TITLE: Magellan Des Moines Biodiesel Terminal Project Page 10f3 Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number DE FDA 000052 OE-EE-OOOO162 GFQ-OOOO162-016 EE162 Based on my review orlbe information concerning tbe proposed action, as NEPA Compliance Officer (authorl7.ed under DOE Order 451.JA), I have made the following determination: ex, EA, ~:IS APPI<:NDIX AND NUMBER: Description: 85.1 Actions to oonserve energy, demonstrate potential energy conservation, and promote energy-efficiency that do not increase the indoor concentrations of potentially harmful substances. These actions may involve financial and techmcal

3

www.cleanenergysolutions.org IndIan Renewable eneRgy and eneRgy effIcIency PolIcy database  

E-Print Network (OSTI)

www.cleanenergysolutions.org IndIan Renewable eneRgy and eneRgy effIcIency PolIcy database India's union and state governments have established a policy environment to support investment in energy to disseminate information on India's renewable energy and energy efficiency policies, regulations, and incentive

4

U.S. DEP_~TIVffNT OFl1N1!RGY EERE PROJECT MANAGEMENT CENTER  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DEP_~TIVffNT OFl1N1!RGY DEP_~TIVffNT OFl1N1!RGY EERE PROJECT MANAGEMENT CENTER NliPA DI!Tl!RMINATION RECIPIENT: UALR Nanotechnology Center PROJECT TITLE: Nanostructred Solar Cells Page 1 of2 STATE: AR Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number em Number FY 2010 COP DE-FG36-06G086072 GF0-06-067b G066702 Based on my review onbe information conce.-niog the propoud action, as NEPA Compliance OWletr (authori7.ed under DOE Order45I.1A), I hJl\'c made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: 83.6 Siting, oonstrudion (or modification), operation, and decommissioning of facilities for indoor bench-scale research projects and oonventionallaboratory operations (for example, preparation of chemical standards and sample analysis):

5

BUDGET DETAILS BOOK FOUR DPRMN OF N RGY U.S. Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

BUDGET DETAILS BUDGET DETAILS BOOK FOUR DPRMN OF N RGY U.S. Department of Energy Transition Team Budget Book Office of the Chief Financial Officer Office of Budget 1. Budget Overview 2. Funding Tables and Charts 3. Appropriations Subcommittees 4. Program Overviews 5. Major Construction Projects, Activities, and Initiatives 6. Laboratory and State Data Acronyms commonly used in budget documents. ACI American Competitiveness Initiative AEI Advanced Energy Initiative AFP Approved Funding Program (monthly financial plan that dictates how funding is to be executed) AlP Accelerator Improvement Project Ames Ames National Laboratory ANL Argonne National Laboratory B&R Budget and Reference Code BA Budget Authority BAPL Bettis Atomic Power Laboratory BNL Brookhaven National Laboratory BO Budget Outlay

6

The Path of Carbon in Photosynthesis VI.  

E-Print Network (OSTI)

PATH OF CkRBON IN PHOTOSYNTHESIS. VI. * Ni. Calvin Radiationdetermination of the path of carbon in photosynthesis. Theredark fixation of photosynthesis and methods of separation

Calvin, M.

1949-01-01T23:59:59.000Z

7

u.s. DEPARTMENT OF ENl!RGY EERE PROJECT MANAGEMENT CENTER NEPA DFTEIu.llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ENl!RGY ENl!RGY EERE PROJECT MANAGEMENT CENTER NEPA DFTEIu.llNATION RECIPIENT:Oklahoma Department of Commerce PROJECT TITL.E: DE EE 0000922 Warr Aetes Ground Source Heat Project w/HVAC retrofit Page 1 of2 STATE : OK Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number em Number DE FDA 0000013 DE EE 0000922 0 Based on my review orlh" information concerning (he proposed action, as NEPA Compliance Officer (authorized under DOE Order 4Sl.lA), I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: 85.1 Actions to conserve energy, demonstrate potential energy conservation, and promote energy-efficiency thaI do not increase the indoor concentrations of potentially harmful substances. These actions may involve financial and technical

8

DEPARTMENT OFENl!RGY EERE PROJECT MANAGEMENT CENTER Nl!PA DETl!lU.nNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

OFENl!RGY OFENl!RGY EERE PROJECT MANAGEMENT CENTER Nl!PA DETl!lU.nNATION RECIPIENT:Atargis Energy Inc. PROJECT TITLE : Cycloidal Wave Energy Converter Page lof2 STATE: CO Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number elD Number DE·FOA-OOOO293 DE-EEOOO3635 GFQ-000363S-001 0 Based on my review of tbe information concerning tbe proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.IA). I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including, bul not limited to, literature surveys, inventories, audits), data analysis (including computer modeling), document preparation (such as conceptual design or feasibility studies. analytical energy supply

9

U.S DEPARTMENT OFl!NllRGY EERE PROJ ECT MANAG EMENT CENTER NEPA D:E=llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

S DEPARTMENT OFl!NllRGY S DEPARTMENT OFl!NllRGY EERE PROJ ECT MANAG EMENT CENTER NEPA D:E=llNATION R[CIPIENT: Scientific Solutions, Inc. STATE: NH PROJECf TITLE: Underwater Active Acoustic Monitoring Network for Marine and Hydrokinetic Energy Projects FUnding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number elD Number DE· FQA'{)()()293 DE-EEOOO3639 GF()'{)()()3639-002 G03639 Based on my review ofthe Information concerning the proposed aelion,.1.5 NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: B3.3 Research related to Field and laboratory research, inventory, and information collection activities that are directly conservation of fi sh, wildlife, related to the conservation of fish and wildlife resources or to the protection of cultural

10

DFPARThIFNT OFENJ!RGY EERE PROJECT MANAGEMENT CENTER NEPA DETER1>llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DFPARThIFNT OFENJ!RGY DFPARThIFNT OFENJ!RGY EERE PROJECT MANAGEMENT CENTER NEPA DETER1>llNATION Page I of3 RECIPIENT :Oklahoma State University - New Product Development Center ST ATE: OK PROJEL. TITLE; Manufacturing Improvement Program for the Oil and Gas Industry Supply Chain Funding Opportunity Announcement Number JIAC2012AM Procurement Instrument Number DE-EE0006029 NKPA Control Number GFO-OOO6029-001 CID Number G06029 Based on my review ofthe information concerning the proposed action, as NEPA Compliance Officer (authorized under DOE O rder 451.IA), I have made the following determination : CX, EA, EIS APPENDIX AND NUMBER : Description: A9 Information gathering, analysis, and dissemination A11 Technical advice and assistance to organizations Information gathering (including, but not limited to, literature surveys, inventories, site visits, and

11

U.S. DEPARTMENT OF ENl'RGY EERE PROJECT MANAGEMENT CENTER NFPA DFIFIU.llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ENl'RGY ENl'RGY EERE PROJECT MANAGEMENT CENTER NFPA DFIFIU.llNATION RECIPIENT: Unlverslty of Maine at Presque Isle PROJECT TITLE: Solar Energy for the North Page I of2 STATE: ME Funding Opportunity Announcement Number FY 2010 COP Procurt'mcnt Instrument Number EEOOO3185 NEPA Control Number cm Number GFO-OO03185-OO1 EE3185 Based on my rt'yiew oftbe information concerning tbe proposed action, as NEPA Compliance Officer (authorized under DOE Order 4SI.lA), I baye made the following determination: C X, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering (including, but not limited to, literature surveys, inventories, audits), data analysis (including computer modeling), document preparation (such as conceptual design or feasibility studies, analytical energy supply

12

US. DEPARThIENI OFI!Nl!RGY EERE PROJECT MANAGEMDH CENTER NEPA DI!TI!RMINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DEPARThIENI OFI!Nl!RGY DEPARThIENI OFI!Nl!RGY EERE PROJECT MANAGEMDH CENTER NEPA DI!TI!RMINATION Page I of2 RECIPIENT: Board of Trustees of the Leland Stanford Junior University STATE: CA PROJECr TlTl.E : PVMI Bay Area Photovoltaic Consortium Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number elD Numbn OE-FOA-000259, PV DE-EEOOO4946 GFO-OO4946-004 G04946 Based on my review ofthe information concerning the proposed action, as NEPA Compliance Officer (authorb,cd under DO": Order451.1A), I bave made the following determination: ex, EA, [IS APPENDIX AND NUMBER: Description: A9 Information gathering, analysis, and dissemination 83.15 Small-scale Indoor research and development projects using nanoscale materials Information gathering (including, but not limited to, literature surveys, inventories, site visits, and

13

US DEPARTMENT OF ENJ!RGY EERE PROJECT MANAGEMENT CENTER NFPA DF1'EIU.llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ENJ!RGY ENJ!RGY EERE PROJECT MANAGEMENT CENTER NFPA DF1'EIU.llNATION Page 1 of2 RECIPIENT:Ben Franklin Technology Partners STATE: PA PROJECf TITLE: Altemative and Clean Energy Technology Development and Commercialization Initiative Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number DE-EEOOO1967 GF0-0001967 -001 NT1967 Based on my review orlhe informalion concerning the proposed action,.s NEPA Compliance Officer (authorized under DOE Order 451.IA), I have made the following determination: ex, EA, EIS APP .. : NDIX AND NUMBER : Description: 83.6 Small-scale research and development, labo rat ory operations, and pilot projects Rational for detennination: Siting, construction. modification, operation, and decommissioning of facilities for smallscale research

14

Vi Rapp  

NLE Websites -- All DOE Office Websites (Extended Search)

Vi Rapp Vi Rapp Vi Rapp Residential Building Systems Group Lawrence Berkeley National Laboratory 1 Cyclotron Road MS 90R3074 Berkeley CA 94720 Office Location: 90-3080 (510) 495-2035 VHRapp@lbl.gov This publications database is an ongoing project, and not all Division publications are represented here yet. Publications 2013 Rapp, Vi H., Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray. Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II., 2013. Download: PDF (836.92 KB) 2012 Rapp, Vi H., Brett C. Singer, J. Chris Stratton, and Craig P. Wray. Assessment of Literature Related to Combustion Appliance Venting Systems., 2012. Download: PDF (1.78 MB) Rapp, Vi H., A. DeFilippo, and Samveg Saxena. "Extending the lean operating

15

U.S. DEPARTMENT OF ENl!RGY EERE PROJECT MANAGEMENT CENTER Nl!PA DETl!R1.llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ENl!RGY ENl!RGY EERE PROJECT MANAGEMENT CENTER Nl!PA DETl!R1.llNATION RECIPIENT: Magma Energy (U.S .) Corp. Page 1 of3 STATE: NV PROJECf TITLE: Recovery Act: A 3D·3C Reflection Seismic Survey and Data Integration to Identify the Seismic Response of Fractures and Permeable Zones over a Known Geothermal Resource: Soda lake , Churchill Co" NV Funding Opportunity Announcement Number PrO(u.-ement Instrument Number NEPA Control Number em Number 0000109 DE-EEOOO2832 GFO-OOO2832·003 0 Based on my review oftbe informatioD concerning the proposed action, as NEPA Compliance Officer (authori7.ed under DOE Order 451.IA), I have made the following determination: ex, EA, [IS APPENDIX AND NUMBER: Description: A9 Information gathenng (including , but nollimiled 10, literature surveys, inventories, audits), data analYSIS (including

16

Vi Rapp  

NLE Websites -- All DOE Office Websites (Extended Search)

2011 DeFilippo, A., Samveg Saxena, Vi H. Rapp, J. - Y. Chen, and Robert W. Dibble. Extending the lean flammability limit of gasoline using a microwave assisted sparkplug., 2011...

17

Energy for the future with Ris from nuclear power to sustainable energy Ris NatioNal laboRatoRy foR sustaiNable eNeRgy  

E-Print Network (OSTI)

Energy for the future ­ with Risø from nuclear power to sustainable energy Risø NatioNal laboRatoRy foR sustaiNable eNeRgy edited by MoRteN JastRup #12;Energy for the future #12;Energy for the future ­ with Risø from nuclear power to sustainable energy Translated from 'Energi til fremtiden ­ med Risø fra

18

Kinetics of Ni Sorption in Soils: Roles of Soil Organic Matter and Ni Precipitation  

E-Print Network (OSTI)

Aqueous Model (WHAM),6,20 which is able to account for the effects of solution chemistry and SOM WHAM VI was integrated into the kinetics model to account for the effects of SOM concentrations by an electrostatic model built in WHAM VI for cation exchange on clay minerals. Ni precipitation kinetics were

Sparks, Donald L.

19

NATIONAL AND GLOBAL FORECASTS WEST VIRGINIA PROFILES AND FORECASTS  

E-Print Network (OSTI)

· NATIONAL AND GLOBAL FORECASTS · WEST VIRGINIA PROFILES AND FORECASTS · ENERGY · HEALTHCARE Industry Insight: West Virginia Fiscal Forecast 34 CHAPTER 4: WEST ViRGiNiA'S 35 COUNTiES AND MSAs West Forecast Summary 2 CHAPTER 1: THE UNiTED STATES ECONOMY Figure 1.1: United States Real GDP Growth 3 Figure

Mohaghegh, Shahab

20

Electrical contacts for II-VI semiconducting devices  

Science Conference Proceedings (OSTI)

High resistivity II-VI semiconductors in general and CdTe and its associated materials like CdZnTe and CdMnTe in particular are suffering from ohmic contacting problem due to their high electron affinity and consequently large work function. Ni, Au, ... Keywords: CdTe-CdS thin film solar cells, Defect induced contact formation, Ohmic contact, Workfunction engineering

Biswajit Ghosh

2009-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Title VI | Department of Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

VI VI Title VI Title VI of the Civil Rights Act of 1964 prohibits discrimination on the basis of race, color, and national origin in programs and activities that receive federal financial assistance. The law states, in part, that: No person in the United States shall, on the ground of race, color, or national origin, be excluded from participation in, be denied the benefits of, or be subjected to discrimination under any program or activity receiving Federal financial assistance. The Office of Civil Rights is responsible for monitoring and enforcing compliance with Title VI, investigating Title VI-related complaints, and providing technical assistance to recipients of Department of Energy financial assistance. The Department has promulgated regulations that

22

LABORATORY VI ELECTRICITY FROM MAGNETISM  

E-Print Network (OSTI)

LABORATORY VI ELECTRICITY FROM MAGNETISM Lab VI - 1 In the previous problems you explored by electric currents. This lab will carry that investigation one step further, determining how changing magnetic fields can give rise to electric currents. This is the effect that allows the generation

Minnesota, University of

23

FUNDAMENTALS OF GAMMA TITANIUM ALUMINIDES: VI ...  

Science Conference Proceedings (OSTI)

FUNDAMENTALS OF GAMMA TITANIUM ALUMINIDES: Session VI: Microstructure/Property Relationships--Creep and Environmental Effects. Sponsored by:...

24

North American Standard Level VI Inspection Program Update: Ensuring...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

North American Standard Level VI Inspection Program Update: Ensuring Safe Transportation of Radioactive Material North American Standard Level VI Inspection Program Update:...

25

LABORATORY VI ENERGY AND THERMAL PROCESSES  

E-Print Network (OSTI)

LABORATORY VI ENERGY AND THERMAL PROCESSES Lab VI - 1 The change of the internal energy of a system temperature by sweating to cool down. Running seems to be the conversion of chemical energy to thermal energy energy into thermal energy, you decide to make some measurements in the laboratory. To make

Minnesota, University of

26

Blue Canyon VI | Open Energy Information  

Open Energy Info (EERE)

VI VI Jump to: navigation, search Name Blue Canyon VI Facility Blue Canyon VI Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner EDP Renewables North America LLC Developer EDP Renewables North America LLC Energy Purchaser Merchant Location Lawton OK Coordinates 34.8582°, -98.54752° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":34.8582,"lon":-98.54752,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

27

ORNL fission product release tests VI-6  

DOE Green Energy (OSTI)

The ORNL fission product release tests investigate release and transport of the major fission products from high-burnup fuel under LWR accident conditions. The two most recent tests (VI-4 and VI-5) were conducted in hydrogen. In three previous tests in this series (VI-1, VI-2, and VI-3), which had been conducted in steam, the oxidized Zircaloy cladding remained largely intact and acted as a barrier to steam reaction with the UO{sub 2}. Test VI-6 was designed to insure significant oxidation of the UO{sub 2} fuel, which has been shown to enhance release of certain fission products, especially molybdenum and ruthenium. The BR3 fuel specimen used in test VI-6 will be heated in hydrogen to 2300 K; the Zircaloy cladding is expected to melt and runoff at {approximately}2150 K. Upon reaching the 2300 K test temperature, the test atmosphere will be changed to steam, and that temperature will be maintained for 60 min, with the three collection trains being operated for 2-, 18-, and 40-min periods. The releases of {sup 85}Kr and {sup 137}Cs will be monitored continuously throughout the test. Posttest analyses of the material collected on the three trains will provide results on the release and transport of Mo, Ru, Sb, Te, Ba, Ce, and Eu as a function of time at 2300 K. Continuous monitoring of the hydrogen produced during the steam atmosphere period at high temperature will provide a measure of the oxidation rate of the cladding and fuel. Following delays in approval of the safety documentation and in decontamination of the hot cell and test apparatus, test VI-6 will be conducted in late May.

Osborne, M.F.; Lorenz, R.A.; Collins, J.L.; Lee, C.S.

1991-01-01T23:59:59.000Z

28

DarkStar VI | Open Energy Information  

Open Energy Info (EERE)

DarkStar VI DarkStar VI Jump to: navigation, search Name DarkStar VI Place Collinsville, Illinois Zip 62234-2022 Sector Services Product Manufacturer of biodiesel processing equipment and supplier of accessories, information and services. Coordinates 36.720014°, -79.91284° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.720014,"lon":-79.91284,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

29

ViDe White Paper Evaluating Microsoft  

E-Print Network (OSTI)

ViDe White Paper Evaluating Microsoft® Exchange 2000 Conferencing Server for use in Higher UNRELATED TO CURRENT TRENDS IN VIDEOCONFERENCING OR IN MICROSOFT PRODUCTS. September 2003 #12;White Paper, Australian National University Support for this White Paper activity was provided by Southeastern

Tennessee, University of

30

Properties of O VI Absorption in the Local Interstellar Medium  

E-Print Network (OSTI)

We report on the properties of LISM O VI absorption observed with 20 km/s resolution FUSE observations of 39 white dwarfs (WDs) ranging in distance from 37 to 230 pc with a median distance of 109 pc. LISM O VI is detected with >2sigma significance along 24 of 39 lines of sight. The column densities range from log N(O VI) = 12.38 to 13.60 with a median value of 13.10. The line of sight volume density, n(O VI) = N(O VI)/d exhibits a large dispersion ranging from (0.68 to 13.0)x10(-8) cm(-3) with an average value 3.6x10(-8) cm(-3) twice larger than found for more distant sight lines in the Galactic disk. The narrowest profiles are consistent with thermal Doppler broadening of O VI near its temperature of peak abundance, 2.8x10(5) K. Comparison of the average velocities of O VI and C II absorption reveals 10 cases where the O VI absorption is closely aligned with the C II absorption as expected if the O VI is formed in a condensing interface between the cool and warm absorption and a hot exterior gas. The comparison also reveals 13 cases where O VI absorption is displaced to positive velocity by 7 to 29 km/s from the average velocity of C II. The positive velocity O VI appears to be tracing the evaporative flow of O VI from a young interface between warm gas and a hot exterior medium. However, it is possible the positive velocity O VI is instead tracing cooling hot Local Bubble (LB) gas. The properties of the O VI absorption in the LISM are broadly consistent with the expectations of the theory of conductive interfaces caught in the old condensing phase and possibly in the young evaporative phase of their evolution.

Blair D. Savage; Nicholas Lehner

2005-09-15T23:59:59.000Z

31

Low Dose Radiation Program: Workshop VI Abstracts  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop VI Principal Investigator and Abstracts Workshop VI Principal Investigator and Abstracts Anderson, Carl Whole Genome Analysis of Functional Protein Binding Sites and DNA Methylation: Application to p53 and Low Dose Ionizing Radiation. Averbeck, Dietrich Cellular Responses at Low Doses of Ionizing Radiation. Azzam, Edouard Adaptive Responses to Low Dose/Low Dose-Rate ?-Rays in Normal Human Fibroblasts: The Role of Oxidative Metabolism. Bailey, Susan The Role of Telomere Dysfunction in Driving Genomic Instability. Balajee, Adayabalam Low Dose Radiation Induced DNA Damage Signaling and Repair Responses in Human 3-Dimensional Skin Model System. Barcellos-Hoff, Mary Helen Imaging Bioinformatics for Mapping Multidimensional Responses. Barcellos-Hoff, Mary Helen Biological Response to Radiation Mediated through the Microenvironment and

32

Cu-Ni  

Science Conference Proceedings (OSTI)

... Ternary Fe-Cu-Ni many-body potential to model reactor pressure vessel ... alloy, This file was provided by Giovanni Bonny (Nuclear Materials Science ...

2013-07-06T23:59:59.000Z

33

Integrated Ecogenomics Study for Bioremediation of Cr(VI) at Hanford 100H Area  

E-Print Network (OSTI)

reducer isolated from the Hanford 100H site capable of Iron(study for bioremediation of Cr(VI) at Hanford 100H area RomyVI)contamination at Hanford ?? Cr(VI) highly soluble, toxic

Chakraborty, Romy

2008-01-01T23:59:59.000Z

34

Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite  

E-Print Network (OSTI)

E. , Thesis, Reactions of Plutonium(VI) with the Iron Oxideof Uranium, Neptunium, Plutonium, Americium and Technetium;Molecular Interactions of Plutonium(VI) with Synthetic

Hu, Yung-Jin

2011-01-01T23:59:59.000Z

35

FROM: MEMORAN RGY PROCUREMENT DIRECTORS OFFICE OF PROCUREMENT...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waiver of Mandatory Use of the Strategic lntegrated Procurement Enterprise System (STRIPES) for Certain Purchase Card Transactions Acquisition Letter (AL) 2010-03, dated...

36

2009 -Asia rld Reneuvable ffxx*rgy Smxlgr&$$ XSSS * Asia  

E-Print Network (OSTI)

Production Btu in Fuel Total Btu Spent for One Btu Available at Fuel Pumps "In summary, bioethanol may play

37

Residual oil saturation, Annex VI-1. Venezuela-MEM/USA-DOE fossil energy report VI-1  

SciTech Connect

This report, dealing with the US/Venezuela Cooperative exchange agreement on residual oil saturation (Annex VI), contains the results of efforts by scientists from both countries to improve the state of present technology for accurately measuring the amount of residual oil remaining in a particular reservoir of interest. To date, those efforts have resulted in an exchange of ideas through a sharing of technical literature and bibliographic listings pertinent to the subject, reciprocal visits to the laboratories and field sites where residual oil saturation measurement R and D is in progress, an exchange of ideas through workshops held in each country, and open discussions covering areas of future cooperative R and D. The text of the basic agreement , Annex VI and all amendments, are appended to the report. In addition to a chronicle of events detailing progress under Annex VI, this report also inlcudes a discussion of future work to be performed in the areas of subsidence accompanying the extraction of oil and interwell oil saturation measurement. A meeting was held in Bartlesville May 10 and 11 to formulate plans in this area.

Wesson, T.C.; VonDomselaar, H.

1983-04-01T23:59:59.000Z

38

SEGS VI Solar Power Plant | Open Energy Information  

Open Energy Info (EERE)

SEGS VI Solar Power Plant SEGS VI Solar Power Plant Jump to: navigation, search Name SEGS VI Solar Power Plant Facility SEGS VI Sector Solar Facility Type Concentrating Solar Power Developer Luz Location Kramer Junction, California Coordinates 34.9925°, -117.540833° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":34.9925,"lon":-117.540833,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

39

Stability of plutonium(VI) in WIPP brine  

Science Conference Proceedings (OSTI)

The redox stability of plutonium (VI) in WIPP brine was investigated by monitoring the oxidation state as a function of time using a combination of absorption spectrometry, radiochemical counting and filtration. Studies were performed with Pu-239 and Pu-238 in four WIPP brines at concentrations between 10{sup {minus}3} and 10{sup {minus}8} M for durations as long as two years. Two synthetic brines, Brine A and ERDA-6, and two underground collected brines, DH-36 and G-Seep, were used. The stability of Pu(VI) depended on the brine composition and the speciation of the plutonium in that brine. When carbonate was present, a Pu(VI)-carbonate complex was observed that was stable. In the absence of carbonate, Pu(VI) hydrolytic species predominated which had a wide range of stability in the brines investigated. The results reported will help define the speciation of plutonium in WIPP brine and hence its potential for migration.

Reed, D.T.; Okajima, S.

1993-12-01T23:59:59.000Z

40

Finite element modeling of Cr(VI) reduction by Shewanella oneidensis MR-1 employing the dual-enzyme kinetic model  

Science Conference Proceedings (OSTI)

Chromium (VI) (Cr(VI)) contamination of soil and groundwater is considered a major environmental concern. Bioreduction of Cr(VI) to chromium (III) (Cr(III)) can be considered an effective technology in remediating Cr(VI) contaminated sites. Among the ... Keywords: Bioreduction, Cr(VI), Dual-enzyme, Modeling

Md. Akram Hossain; Mahbub Alam; David Yonge; Prashanta Dutta

2005-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Marcos Heil Costa Departamento de Engenharia Agrícola, Universidade Federal de Viçosa, Brasil  

NLE Websites -- All DOE Office Websites (Extended Search)

43 a 553. 43 a 553. 1 Efeitos de Variabilidade Climática e Desmatamento No Regime de Águas Superficiais Marcos Heil Costa Departamento de Engenharia Agrícola, Universidade Federal de Viçosa, Brasil Michael T. Coe Woods Hole Research Center, Falmouth, Massachusetts, USA Jean Loup Guyot LMTG, Institut de Recherche pour le Développement, Toulouse, France O regime de escoamento de rios na Bacia Amazônica mostra uma considerável variabilidade em escalas interanuais e decadais. A principal fonte de variação são os eventos do El Niño-Oscilação Sul (ENOS). Eventos de El Niño causam diminuição de precipitação, escoamento fluvial e padrões de inundação em toda a região, com reduções mais fortes que ocorrem na parte norte da bacia. Por outro lado, os eventos do La Niña causam aumento

42

Complexation of Gluconate with Uranium(VI) in Acidic Solutions: Thermodynamic Study with Structural Analysis  

E-Print Network (OSTI)

of the thermodynamic quantities of uranium(VI)carboxylateComplexation of Uranium(VI) by Gluconate Thermodynamic Studyacid (H A ) Hexavalent uranium as the UO 22+ ion was studied

Zhang, Zhicheng

2009-01-01T23:59:59.000Z

43

Examination of Uranium(VI) Leaching During Ligand Promoted Dissolution of Waste Tank Sludge Surrogates  

E-Print Network (OSTI)

Effects of phosphate on uranium(VI) adsorption to goethite-and ionic strength upon uranium(VI) sorption onto alumina asD. R. , Leslie, B. W. , Uranium sorption on a-alumina:

Powell, Brian A.

2008-01-01T23:59:59.000Z

44

Tracking the Sun VI: An Historical Summary of the Installed Price...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracking the Sun VI: An Historical Summary of the Installed Price of Photovoltaics in the United States from 1998 to 2012 Title Tracking the Sun VI: An Historical Summary of the...

45

Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report  

Science Conference Proceedings (OSTI)

A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory proteins (Gmet_2478 and Gmet_1641) were up-regulated with exposure to Cr(VI). A nine-heme cytochrome C was purified that could reduce nitrite and could be oxidized by Cr(VI). For D. desulfuricans, we found that confirmed that Cr(VI) induced a prolonged lag period when Cr(VI) was reduced. Over three hundred proteins were unequivocally identified by LC/MS-MS and a significant number of down-regulated proteins for which the levels were changed >2 fold compared to control. Sulfite reductase levels were similar, however, nitrate and nitrite reductase were down-regulated. The supernatant of spent cultures was found to contain a filterable, heat stable compound that rapidly reduced Cr(VI). In addition, desulfoviridin was purified from nitrate grown cells and shown to have nitrite reductase activity that was inhibited by Cr(VI). For S. barnesii, periplasmic nitrate reductase (Nap), nitrite reductase (Nrf), and the metalloid reductase (Rar) were purified and characterized. The supernatant of spent cultures was also found to contain a filterable, heat stable compound that rapidly reduced Cr(VI) but that Rar also reduced Cr(VI). Our results from specific aims 1 through 3 indicate that for G. metallireducens, Cr(VI) inhibits nitrate respiration as it oxidizes cytochromes involved in nitrate respiration. Iron reduction is apparently not affected and the inhibitory affects of Cr(VI) may be attenuated by the addition of sufficient Fe(III) to generate Fe(II) that abiotically reduces the chromium. For S. barnesii, although the enzyme assays indicate that the components of the respiratory pathway for nitrate (e.g. Nap and Nrf) are inhibited by chromate, the organism has a mechanism to prevent this from actually occurring. Our current hypothesis is that the non-specific metalloid reductase (Rar) is providing resistance by reducing the Cr(VI). The strategy here would be to enhance its growth and metabolism in the natural setting. Lactate is a suitable electron donor for S. barnesii but other donors are possible. Although the version of the Phylochip used for monitoring the microb

John F. Stolz

2011-06-15T23:59:59.000Z

46

Contribution of Extracellular Polymeric Substances from Shewanella sp. HRCR-1 Biofilms to U(VI) Immobilization  

Science Conference Proceedings (OSTI)

The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) in U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells without EPS, we showed that i) bEPS from Shewanella sp. HRCR-1 biofilms contributed significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; ii) bEPS could be considered as a functional extension of the cells for U(VI) immobilization and they likely play more important roles at initial U(VI) concentrations; and iii) U(VI) reduction efficiency was found to be dependent upon initial U(VI) concentration and the efficiency decreased at lower concentrations. To quantify relative contribution of sorption and reduction in U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(V). We found that, when in reduced form, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated reactivity of laEPS while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, might facilitate U(VI) reduction.

Cao, Bin; Ahmed, B.; Kennedy, David W.; Wang, Zheming; Shi, Liang; Marshall, Matthew J.; Fredrickson, Jim K.; Isern, Nancy G.; Majors, Paul D.; Beyenal, Haluk

2011-06-05T23:59:59.000Z

47

Ni-Zr (Nickel - Zirconium)  

Science Conference Proceedings (OSTI)

Ni-Zr crystallographic data...99.9 to 100 hP 2 P 6 3 / mmc (a) Triclinic. (b) Stoichiometric. (c) Zr-rich...

48

Imaging Chemical Aggregation of Ni/NiO Particles from Reduced NiO-YSZ  

SciTech Connect

Energy dispersive X-ray spectroscopy (EDS) mapping of nickel oxide yttria-stabilized zirconia (NiO-YSZ) was carried out after various hydrogen reducing and methane steam reforming conditions. Nickel aggregation was visualized after methane steam reforming by correlating Ni K{sub {alpha}} map with scanning transmission electron microscopy (STEM) images. From the reduced O K{sub {alpha}} intensities in the Ni K{sub {alpha}} dominated regions after methane steam reforming, NiO reduction in to Ni can be interpreted. From correlation between Zr K{sub {alpha}} and O K{sub {alpha}} maps, high stability of YSZ was also realized. Examples of NiO-YSZ overlapped particles are considered to discuss chemical imaging of a single particle.

Saraf, Laxmikant V.

2011-07-20T23:59:59.000Z

49

Remediation of chromium(VI) in the vadose zone: stoichiometry and kinetics of chromium(VI) reduction by sulfur dioxide  

E-Print Network (OSTI)

Immobilization and detoxification of chromium in the vadose zone is made possible by the existence of an effective reductant, SO2, that exists in a gaseous form at room temperature. Experimental studies were designed to characterize stoichiometry and kinetics of chromium reduction both in aqueous solutions at pH values near neutrality and in soil. First, batch experiments and elemental analyses were conducted to characterize the stoichiometry and kinetics of Cr(VI) reduction in water. The stoichiometric ratio of S(IV) removed to Cr(VI) removed ranged between 1.6 and 1.8. The overall reaction is believed to be the result of a linear combination of two reactions in which dithionate is an intermediate and sulfate is the stable oxidized product. The reaction was also rapid, with the half-time of about 45 minutes at pH 6 and about 16 hours at pH 7. A two-step kinetic model was developed to describe changes in concentrations of Cr(VI), S(IV), and S(V). Nonlinear regression was applied to obtain the kinetic parameters. The rate of reaction was assumed to be second-order with respect to [Cr(VI)] and first-order with respect to [S(IV)], and [S(V)]. The values for the rate coefficient for the first reaction (k1) were found to be 4.5 (?10%), 0.25 (?9.4%) (mM-2h-1) at pH 6 and 7, respectively. The values of the rate coefficient for the second reaction (k2) were 25 (?29%), 1.1 (? 30%) (mM-2h-1) at pH 6 and 7, respectively. The reaction rate decreased as pH increased. Experiments showed that the rate at pH 7 was lower than that at pH 6 by one order of magnitude. Second, batch experiments and elemental analyses were conducted to characterize the stoichiometry and kinetics of Cr(VI) reduction in soil. The stoichiometric ratio of S(IV) removed to Cr(VI) removed was almost 2, which is slightly higher than that for the reaction in water. This higher value may be due to S(IV) oxidation by soil-derived Fe(III). The reaction was rapid, with the half-time less than 2 minutes, which is faster than in water. The rate coefficients, k1 and k2, were 22 (?41%) and 13 (?77%) (M-2h-1), respectively.

Ahn, Min

2003-08-01T23:59:59.000Z

50

ENDF-201: ENDF/B-VI summary documentation  

Science Conference Proceedings (OSTI)

Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe{sup 56}. The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on ``tapes.`` Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the ``tape`` number. These evaluations have been released without restrictions on their distribution or use.

Rose, P.F. [comp.

1991-10-01T23:59:59.000Z

51

ENDF-201: ENDF/B-VI summary documentation  

Science Conference Proceedings (OSTI)

Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe{sup 56}. The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on tapes.'' Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the tape'' number. These evaluations have been released without restrictions on their distribution or use.

Rose, P.F. (comp.)

1991-10-01T23:59:59.000Z

52

Recovery and Detection of Uranium (VI) From Building Materials  

SciTech Connect

As a legacy of the United States' 50 year old nuclear weapons program, the Department of Energy is responsible for cleaning up and decommissioning contaminated sites that were used for the production of these weapons. The method presented here addresses the problem of detecting and quantifying uranium (VI) in concrete. Specifically, the uranium (VI) is removed from concrete surfaces using a low pH buffer rinse that dissolves the surface layer. The amount of uranium in the wash solution can be quite low, even with extraction efficiencies exceeding 50 %. Therefore, the uranium is complexed with an organic chelating agent (arsenazo III) and concentrated using C18 solid phase extraction. Because the absorbance maximum of arsenazo III shifts upon binding to uranium, the concentrated complex can be detected using ultraviolet-visible spectroscopy. Low part-per-billion levels of uranium (VI) in cement can be detected by this method. Results of work related to other building material s such as stainless steel and plexiglass will also be reported.

Greene, Philip A.; Copper, Christine L.; Berv, David; Ramsey, Jeremy D.; Collins, Greg E.

2004-03-29T23:59:59.000Z

53

Summary of the planning, management, and evaluation process for the Geothermal Program Review VI conference  

DOE Green Energy (OSTI)

The purpose of this document is to present an overview of the planning, facilitation, and evaluation process used to conduct the Geothermal Program Review VI (PR VI) conference. This document was also prepared to highlight lessons learned from PR VI and, by utilizing the evaluation summaries and recommendations, be used as a planning tool for PR VII. The conference, entitled Beyond Goals and Objectives,'' was sponsored by the US Department of Energy's (DOE) Geothermal Technology Division (GTD), PR VI was held in San Francisco, California on April 19--21, 1988 and was attended by 127 participants. PR VI was held in conjunction with the National Geothermal Association's (NGA) Industry Round Table. This document presents a brief summary of the activities, responsibilities, and resources for implementing the PR VI meeting and provides recommendations, checklists, and a proposed schedule for assisting in planning PR VII.

Not Available

1988-10-01T23:59:59.000Z

54

Method for making graded I-III-VI.sub.2 semiconductors and solar cell obtained thereby  

DOE Patents (OSTI)

Improved cell photovoltaic conversion efficiencies are obtained by the simultaneous elemental reactive evaporation process of Mickelsen and Chen for making semiconductors by closer control of the evaporation rates and substrate temperature during formation of the near contact, bulk, and near junction regions of a graded I-III-VI.sub.2, thin film, semiconductor, such as CuInSe.sub.2 /(Zn,Cd)S or another I-III-VI.sub.2 /II-VI heterojunction.

Devaney, Walter E. (Seattle, WA)

1987-08-04T23:59:59.000Z

55

Influence of nuclear structure on sub-barrier hindrance in Ni+Ni fusion  

E-Print Network (OSTI)

Fusion-evaporation cross sections for $^{64}$Ni+$^{64}$Ni have been measured down to the 10 nb level. For fusion between two open-shell nuclei, this is the first observation of a maximum in the $S$-factor, which signals a strong sub-barrier hindrance. A comparison with the $^{58}$Ni+$^{58}$Ni, $^{58}$Ni+$^{60}$Ni, and $^{58}$Ni+$^{64}$Ni systems indicates a strong dependence of the energy where the hindrance occurs on the stiffness of the interacting nuclei.

C. L. Jiang; K. E. Rehm; R. V. F. Janssens; H. Esbensen; I. Ahmad; B. B. Back; P. Collon; C. N. Davids; J. P. Greene; D. J. Henderson; G. Mukherjee; R. C. Pardo; M. Paul; T. O. Pennington; D. Seweryniak; S. Sinha; Z. Zhou

2004-02-25T23:59:59.000Z

56

Group I-III-VI.sub.2 semiconductor films for solar cell application  

SciTech Connect

This invention relates to an improved thin film solar cell with excellent electrical and mechanical integrity. The device comprises a substrate, a Group I-III-VI.sub.2 semiconductor absorber layer and a transparent window layer. The mechanical bond between the substrate and the Group I-III-VI.sub.2 semiconductor layer is enhanced by an intermediate layer between the substrate and the Group I-III-VI.sub.2 semiconductor film being grown. The intermediate layer contains tellurium or substitutes therefor, such as Se, Sn, or Pb. The intermediate layer improves the morphology and electrical characteristics of the Group I-III-VI.sub.2 semiconductor layer.

Basol, Bulent M. (Redondo Beach, CA); Kapur, Vijay K. (Northridge, CA)

1991-01-01T23:59:59.000Z

57

Behavior of Uranium(VI) during HEDPA Leaching for Aluminum Dissolution in Tank Waste Sludges  

E-Print Network (OSTI)

Behavior of Uranium(VI) during HEDPA Leaching for Aluminuman increase in the aqueous phase uranium concentration.The concentration of uranium continually increased over 59

Powell, Brian A.; Rao, Linfeng; Nash, Kenneth L.; Martin, Leigh

2006-01-01T23:59:59.000Z

58

Reaction of Plutonium(VI) with the Manganese-Substituted Iron Oxide Mineral Goethite  

E-Print Network (OSTI)

Plutonium(VI) Sorption on Manganese-SubstitutedX-ray Beam-Induced Chemistry on Plutonium Sorbed on Variousof Plutonium . . . . . . . . . . . . . . . . .159 v E Anion

Hu, Yung-Jin Hu

2011-01-01T23:59:59.000Z

59

The Galactic Halo's O VI Resonance Line Intensity  

E-Print Network (OSTI)

We used FUSE to observe ultraviolet emission from diffuse O VI in the hot gas in the Galactic halo. By comparing our result with another, nearby observation blocked by an opaque cloud at a distance of 230 pc, we could subtract off the contribution from the Local Bubble, leading to an apparent halo intensity of I_{OVI} = 4680^{+570}_{-660} photons/cm^2/s/sr. A correction for foreground extinction leads to an intrinsic intensity that could be as much as twice this value. Assuming T ~ 3 x 10^5 K, we conclude that the electron density, n_e, is 0.01-0.02 /cm^3, the thermal pressure, p/k, is 7000-10,000 K/cm^3, and that the hot gas is spread over a length of 50-70 pc, implying a small filling factor for O VI-rich gas. ROSAT observations of emission at 1/4 keV in the same direction indicate that the X-rays are weaker by a factor of 1.1 to 4.7, depending on the foreground extinction. Simulated supernova remnants evolving in low density gas have similar O VI to X-ray ratios when the remnant plasma is approaching collisional ioinizational equilibrium and the physical structures are approaching dynamical ``middle age''. Alternatively, the plasma can be described by a temperature power-law. Assuming that the material is approximately isobaric and the length scales according to T^(beta) d(ln T), we find beta = 1.5+/-0.6 and an upper temperature cutoff of 10^{6.6(+0.3,-0.2)} K. The radiative cooling rate for the hot gas, including that which is too hot to hold O VI, is 6 x 10^{38} erg/s/kpc^2. This rate implies that ~70% of the energy produced in the disk and halo by SN and pre-SN winds is radiated by the hot gas in the halo.

Robin L. Shelton; Shauna M. Sallmen; Edward B. Jenkins

2006-12-18T23:59:59.000Z

60

Evaluated nuclear data file ENDF/B-VI  

SciTech Connect

For the past 25 years, the United States Department of Energy has sponsored a cooperative program among its laboratories, contractors and university research programs to produce an evaluated nuclear data library which would be application independent and universally accepted. The product of this cooperative activity is the ENDF/B evaluated nuclear data file. After approximately eight years of development, a new version of the data file, ENDF/B-VI has been released. The essential features of this evaluated data library are described in this paper. 7 refs.

Dunford, C.L.

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Bistability of Cation Interstitials in II-VI Semiconductors  

DOE Green Energy (OSTI)

The stability of cation interstitials in II-VI semiconductors is studied using ab initio methods. We find that interstitials in the neutral charge state are more stable in the tetrahedral interstitial site near the cation, whereas in the (2+) charge state, they are more stable near the anion. The diffusion energy barrier changes when the defect charge state changes. Therefore, if electrons/holes are taken from the defect level by light, changing its charge state, the interstitial atom will be able to diffuse almost spontaneously due to a reduced diffusion barrier.

Wei, S. H.; Dalpian, G. M.

2005-11-01T23:59:59.000Z

62

Neutron Imaging @ SNS (NI@SNS 2008)  

NLE Websites -- All DOE Office Websites (Extended Search)

Neutron Imaging at SNS Workshop (NI@SNS 2008) November 3, 2008 * Building 8600, Central Laboratory & Office Building * Oak Ridge, TN 37831 NI@SNS2008 home Neutron Imaging Agenda...

63

Modeling the Removal of Uranium U(VI) from Aqueous Solutions in the  

E-Print Network (OSTI)

Modeling the Removal of Uranium U(VI) from Aqueous Solutions in the Presence of Sulfate Reducing Colorado School of Mines, Division of Environmental Science and Engineering, Golden, Colorado 80401 The reduction kinetics of soluble hexavalent uranium (U(VI)) to insoluble tetravalent U(IV) by both a mixed

64

Simulation of reactive transport of uranium(VI) in groundwater with variable chemical conditions  

E-Print Network (OSTI)

transport of U(VI) in an alluvial aquifer at a former uranium ore-processing mill near Naturita, CO. The SCM alluvial aquifer beneath a former U(VI) mill located near Naturita, CO, was simulated using a surface. Site Characterization 2.1. Site Description [9] The former uranium mill site is approximately 3 km

65

Uranium (VI) solubility in carbonate-free ERDA-6 brine  

Science Conference Proceedings (OSTI)

When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

Lucchini, Jean-francois [Los Alamos National Laboratory; Khaing, Hnin [Los Alamos National Laboratory; Reed, Donald T [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

66

Data summary report for fission product release Test VI-7  

SciTech Connect

Test VI-7 was the final test in the VI series conducted in the vertical furnace. The fuel specimen was a 15.2-cm-long section of a fuel rod from the Monticello boiling water reactor (BWR). The fuel had experienced a burnup of {approximately}-40 Mwd/kg U. It was heated in an induction furnace for successive 20-min periods at 2000 and 2300 K in a moist air-helium atmosphere. Integral releases were 69% for {sup 85}Kr, 52% for {sup 125}Sb, 71% for both {sup 134}Cs and {sup 137}Cs, and 0.04% for {sup 154}Eu. For the non-gamma-emitting species, release values for 42% for I, 4.1% for Ba, 5.3% for Mo, and 1.2% for Sr were determined. The total mass released from the furnace to the collection system, including fission products, fuel, and structural materials, was 0.89 g, with 37% being collected on the thermal gradient tubes and 63% downstream on filters. Posttest examination of the fuel specimen indicated that most of the cladding was completely oxidized to ZrO{sub 2}, but that oxidation was not quite complete at the upper end. The release behaviors for the most volatile elements, Kr and Cs, were in good agreement with the ORNL-Booth Model.

Osborne, M.F.; Lorentz, R.A.; Travis, J.R.; Collins, J.L.; Webster, C.S. [Oak Ridge National Lab., TN (United States)

1995-05-01T23:59:59.000Z

67

Geothermal Program Review VI: proceedings. Beyond goals and objectives  

DOE Green Energy (OSTI)

Program Review VI was comprised of six sessions, including an opening session, four technical sessions that addressed each of the major DOE research areas, and a session on special issues. The technical sessions were on Hydrothermal, Hot Dry Rock, Geopressured and Magma resources. Presenters in the technical sessions discussed their R and D activities within the context of specific GTD Programmatic Objectives for that technology, their progress toward achieving those objectives, and the value of those achievements to industry. The ''Special Issues'' presentations addressed several topics such as the interactions between government and industry on geothermal energy R and D; the origin and basis for the programmatic objectives analytical computer model; and international marketing opportunities for US geothermal equipment and services. The unique aspect of Program Review VI was that it was held in conjunction with the National Geothermal Association's Industry Round Table on Federal R and D. The Round Table provided a forum for open and lively discussions between industry and government researchers and gave industry an opportunity to convey their needs and perspectives on DOE's research programs. These discussions also provided valuable information to DOE regarding industry's priorities and directions.

Not Available

1988-01-01T23:59:59.000Z

68

SF 6432-NI (02-22-10)  

interpreted in accordance with laws of New Mexico, and, where appropriate, the United States federal law. NI03 ASSIGNMENT

69

Affinity of An(VI) for N4-Tetradentate Donor Ligands: Complexation of the Actinyl(VI) Ions with N4-Tetradentate Ligands  

Science Conference Proceedings (OSTI)

In this report the affinity of four N4-tetradentate ligands that incorporate the 2- methylpyridyl functionality with hexavalent actinides (AnO2+2 ) has been investigated in methanol solution. The ligands studied include N,N*-bis(2-methylpyridyl)diaminoethane (BPMDAE), N,N-bis(2-methylpyridyl)-1,3-diaminopropane (BPMDAP), N,N*-bis(2-pyridylmethyl) piperazine (BPMPIP), and trans-N,N-bis(2-pyridylmethyl)-1,2-diaminocyclohexane (BPMDAC). Conditional stability constants describing the strength of the interaction were determined by UV-visible spectrophotometry. The log10K101 values for both U(VI) and Pu(VI) are comparable and show the same trend of stability with ligand structure. Dinuclear complexes are also indicated as being important. The log10K201 values for Pu(VI) complexation with the N4-ligands are identical for the four ligands (within experimental error), indicating that the structure of the ligand backbone has little effect on the stability of the (PuO2)2L2+ complex. The exception to this trend is the behavior of N,N*- bis(2-pyridylmethyl)piperazine (BPMPIP) with Pu(VI). This ligand displays a tendency to reduce Pu(VI) within the experimental time frame of 45 minutes. BPMPIP is the only ligand tested that contains tertiary amines in the ligand backbone. The decomposition of BPMPIP by Pu(VI) suggests a susceptibility of tertiary amines to oxidative degradation.

Ogden, Mark; Sinkov, Sergey I.; Lumetta, Gregg J.; Nash, Kenneth L.

2012-05-01T23:59:59.000Z

70

Relativity and Magnetism in Ni-Pd and Ni-Pt Alloys Abstract  

E-Print Network (OSTI)

We show that the differences in the magnetic properties of Ni-Pd and Ni-Pt alloys arise mainly due to relativity. In particular, we find that the local magnetic moment of Ni increases with the addition of Pd in Ni-Pd while it decreases with the addition of Pt in Ni-Pt, as found experimentally, only if relativity is present. Our analysis is based on the effects of relativity on (i) the spin-polarized densities of states of Ni, (ii) the splitting of majority and minority spin d-band centers of Ni, and (iii) the separation between s-d band centers of Pd and Pt in Ni-Pd and Ni-Pt alloys. 1

Prabhakar P. Singh

2002-01-01T23:59:59.000Z

71

Data summary report for fission product release test VI-6  

SciTech Connect

Test VI-6 was the sixth test in the VI series conducted in the vertical furnace. The fuel specimen was a 15.2-cm-long section of a fuel rod from the BR3 reactor in Belgium. The fuel had experienced a burnup of {approximately}42 MWd/kg, with inert gas release during irradiation of {approximately}2%. The fuel specimen was heated in an induction furnace at 2300 K for 60 min, initially in hydrogen, then in a steam atmosphere. The released fission products were collected in three sequentially operated collection trains designed to facilitate sampling and analysis. The fission product inventories in the fuel were measured directly by gamma-ray spectrometry, where possible, and were calculated by ORIGEN2. Integral releases were 75% for {sup 85}Kr, 67% for {sup 129}I, 64% for {sup 125}Sb, 80% for both {sup 134}Cs and {sup 137}Cs, 14% for {sup 154}Eu, 63% for Te, 32% for Ba, 13% for Mo, and 5.8% for Sr. Of the totals released from the fuel, 43% of the Cs, 32% of the Sb, and 98% of the Eu were deposited in the outlet end of the furnace. During the heatup in hydrogen, the Zircaloy cladding melted, ran down, and reacted with some of the UO{sub 2} and fission products, especially Te and Sb. The total mass released from the furnace to the collection system, including fission products, fuel, and structural materials, was 0.57 g, almost equally divided between thermal gradient tubes and filters. The release behaviors for the most volatile elements, Kr and Cs, were in good agreement with the ORNL Diffusion Model.

Osborne, M.F.; Lorenz, R.A.; Travis, J.R.; Webster, C.S.; Collins, J.L. [Oak Ridge National Lab., TN (United States)

1994-03-01T23:59:59.000Z

72

Plutonium(V/VI) Reduction by the Metal-Reducing Bacteria  

E-Print Network (OSTI)

We examined the ability of the metal-reducing bacteria Geobacter metallireducens GS-15 and Shewanella oneidensis MR-1 to reduce Pu(VI) and Pu(V). Cell suspensions of both bacteria reduced oxidized Pu [a mixture of Pu(VI) and Pu(V)] to Pu(IV). The rate of plutonium reduction was similar to the rate of U(VI) reduction obtained under similar conditions for each bacteria. The rates of Pu(VI) and U(VI) reduction by cell suspensions of S. oneidensis were slightly higher than the rates observed with G. metallireducens. The reduced form of Pu was characterized as aggregates of nanoparticulates of Pu(IV). Transmission electron microscopy images of the solids obtained from the cultures after the reduction of Pu(VI) and Pu(V) by S. oneidensis show that the Pu precipitates have a crystalline structure. The nanoparticulates of Pu(IV) were precipitated on the surface of or within the cell walls of the bacteria. The production of Pu(III) was not observed, which indicates that Pu(IV) was the stable form of reduced Pu under these experimental conditions. Experiments examining the ability of these bacteria to use Pu(VI) as a terminal electron acceptor for growth were inconclusive. A slight increase in cell density was observed for both G. metallireducens and S. oneidensis when Pu(VI) was provided as the sole electron acceptor; however, Pu(VI) concentrations decreased similarly in both the experimental and control cultures. Effective bioremediation and waste management strategies

Gary A. Icopini; Joe G. Lack; Larry E. Hersman; Mary P. Neu; Hakim Boukhalfa

2009-01-01T23:59:59.000Z

73

Microsoft Word - Tracking the Sun VI_working version.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

VI VI An Historical Summary of the Installed Price of Photovoltaics in the United States from 1998 to 2012 Galen Barbose, Naïm Darghouth, Samantha Weaver, and Ryan Wiser July 2013 Tracking the Sun VI An Historical Summary of the Installed Price of Photovoltaics in the United States from 1998 to 2012 Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory Primary Authors: Galen Barbose, Naïm Darghouth, Samantha Weaver, Ryan Wiser Executive Summary ...................................................................................................... 1 1. Introduction .............................................................................................................. 5 2. Data Summary .......................................................................................................... 8

74

Diffusion in L12 Structures: A Comparison of Ni3Al, Ni3Ga and Ni3Ge  

Science Conference Proceedings (OSTI)

... that while the diffusivities of the majority component Ni in these compounds are similar, ... First Order Structural Transformations in Symmetrical Tilt S5 Grain...

75

The data base of the standards and related cross sections after ENDF/B-VI  

DOE Green Energy (OSTI)

A brief description is given of the procedure used in the global evaluation of the standards and other important cross sections for ENDF/B-VI. The results of the evaluation are compared with new or revised experimental data.

Poenitz, W.P. [Argonne National Lab., IL (United States); Carlson, A.D. [National Inst. of Standards and Technology, Washington, DC (United States)

1992-12-31T23:59:59.000Z

76

The data base of the standards and related cross sections after ENDF/B-VI  

DOE Green Energy (OSTI)

A brief description is given of the procedure used in the global evaluation of the standards and other important cross sections for ENDF/B-VI. The results of the evaluation are compared with new or revised experimental data.

Poenitz, W.P. (Argonne National Lab., IL (United States)); Carlson, A.D. (National Inst. of Standards and Technology, Washington, DC (United States))

1992-01-01T23:59:59.000Z

77

Initial data testing of ENDF/B-VI for thermal reactor benchmark analysis  

SciTech Connect

This paper summarizes some early data testing of ENDF/B-VI by members of the Cross Section Evaluation Working Group (CSEWG) Thermal Reactor Data Testing Subcommittee. Projections of ENDF/B-VI performance in thermal benchmark calculations are beginning to be available; and in some cases the calculations were performed with only a portion of the cross sections taken from version VI, the remainder taken from earlier data files. A factor delaying the thermal reactor data testing is that the final {sup 235}U evaluation has not yet been officially released--only an earlier evaluation with a constant low-energy eta value (like in version V) is currently available. The official version VI {sup 235}U evaluation (scheduled for release as Mod-1) gives a drooping eta variation at low energy; i.e., eta decreases with decreasing energy. This behavior was suggested by European studies to improve the calculation of temperature coefficients in LWRs.

Williams, M.L. [Louisiana State Univ., Baton Rouge, LA (United States). Nuclear Science Center; Kahler, A.C. [Bettis Atomic Power Lab., West Mifflin, PA (United States); MacFarlane, R.E. [Los Alamos National Lab., NM (United States); Milgram, M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Wright, R.Q. [Oak Ridge National Lab., TN (United States)

1991-12-31T23:59:59.000Z

78

TY RPRT T1 Tracking the Sun VI An Historical Summary of the Installed...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracking the Sun VI An Historical Summary of the Installed Price of Photovoltaics in the United States from to A1 Galen L Barbose A1 Na m Darghouth A1 Samantha Weaver A1 Ryan H...

79

Lawrence Livermore pulsed sphere benchmark analysis of MCNP{trademark} ENDF/B-VI  

Science Conference Proceedings (OSTI)

Twenty-eight Lawrence Livermore pulsed sphere experiments were modeled using MCNP for the purpose of bench- marking the new MCNP ENDF/B-VI data library. The twenty-eight pulsed sphere experiments contain thirty-four of the 124 isotopic or elemental evaluations contained in the new ENDF/B-VI set. The ENDF/B-VI results are compared to experimental neutron time-of-flight data, the results obtained from using ENDF/B-V, and against an additional data set, the MCNP Recommended Library, which includes Los Alamos group T-2 evaluations. The results show that ENDF/B-VI results give better or comparable results in comparison to experiment to ENDF/B-V in many cases, and do not deviate grossly in the other cases.

Court, J.D.; Brockhoff, R.C.; Hendricks, J.S.

1994-12-01T23:59:59.000Z

80

Preparation and characterization of Ni(OH)2 and NiO mesoporous nanosheets  

Science Conference Proceedings (OSTI)

Mesoporous nanosheets of single-crystalline ?-nickel hydroxide (?-Ni(OH)2) were successfully synthesized via a facile hydrothermal method using Ni(NO3)2 ? 6H2O as precursor in a mixed solution ...

Changyu Li; Shouxin Liu

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Nearly itinerant ferromagnetism in CaNi2 and CaNi3  

SciTech Connect

Single crystals of CaNi2 and CaNi3 are successfully grown out of excess Ca. Both compounds manifest a metallic ground state with enhanced, temperature-dependent magnetic susceptibility. The relatively high Stoner factors of Z=0.79 and 0.87 found for CaNi2 and CaNi3, respectively, reveal their close vicinity to ferromagnetic instabilities. The pronounced field dependence of the magnetic susceptibility of CaNi3 at low temperatures (T<25 K) suggests strong ferromagnetic fluctuations. A corresponding contribution to the specific heat with a temperature dependence of T3lnT is also observed.

Jesche, Anton; Dennis, Kevin W.; Kreyssig, Andreas; Canfield, Paul C.

2012-06-26T23:59:59.000Z

82

Development of Ni Base Superalloy for Industrial Gas Turbine  

Science Conference Proceedings (OSTI)

In response to this demand, Ni-base superalloys have been developed by MHI's alloy design system. These Ni-base superalloys have been applied to rotating...

83

Electrodeposited NiCo/Cu Superlattices  

Science Conference Proceedings (OSTI)

NiCo/Cu superlattices were electrodeposited on polycrystalline Cu substrates from a single electrolyte under potentiostatic control. The X-ray diffraction (XRD) patterns showed that NiCo/Cu superlattices have the same crystal structure and texture as in their substrates. The films exhibited giant magnetoresistance (GMR) or anisotropic magnetoresistance (AMR), depending on the Cu layer thicknesses.

Safak, M.; Alper, M. [Department of Physics, Faculty of Science and Literature, University of Uludag, Goeruekle, Bursa (Turkey)

2007-04-23T23:59:59.000Z

84

Thermodynamics of the Complexation of Uranium(VI) by oxalate in aqueous solution at 10-70oC  

E-Print Network (OSTI)

O. Tochiyama in Chemical Thermodynamics of Compounds andUpdate on the Chemical Thermodynamics of Uranium, Neptunium,Thermodynamics of the Complexation of Uranium(VI) with

Di Bernardo, Plinio

2009-01-01T23:59:59.000Z

85

Rate-limited U(VI) desorption during a small-scale tracer test in a hetereogeneous uranium contaminated aquifer  

E-Print Network (OSTI)

reactive transport modeling of uranium bioremediation fieldof calcium on aqueous uranium(VI) speciation and adsorptiontransport modeling of a uranium bioremediation field

Fox, P.M.

2013-01-01T23:59:59.000Z

86

Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments  

SciTech Connect

The microbial reduction of Fe(III) and U(VI) were investigated in shallow aquifer sediments collected from subsurface Pleistocene flood deposits near the Hanford Reach of the Columbia River in Washington State. Increases in 0.5 N HCl-extractable Fe(II) were observed in incubated sediments and 57Fe Mssbauer spectroscopy revealed that Fe(III) associated with phyllosilicates and pyroxene was reduced to Fe(II). Aqueous uranium(VI) concentrations decreased in incubated Hanford sediments with the rate and extent being greater in sediment amended with organic carbon. X-ray absorption spectroscopy of bioreduced sediments indicated that 67-77% of the U signal was U(VI), probably as an adsorbed species associated with a new or modified reactive mineral phase. Phylotypes within the Deltaproteobacteria were more common in Hanford sediments incubated with U(VI) than without and in U(VI)-free incubations, members of the Clostridiales were dominant with sulfate-reducing phylotypes more common in the sulfate-amended sediments. These results demonstrate the potential for anaerobic reduction phyllosilicate Fe(III) and sulfate in Hanford unconfined aquifer sediments and biotransformations involving reduction and adsorption leading to decreased aqueous U concentrations.

Lee, Ji-Hoon; Fredrickson, Jim K.; Kukkadapu, Ravi K.; Boyanov, Maxim I.; Kemner, Kenneth M.; Lin, Xueju; Kennedy, David W.; Bjornstad, Bruce N.; Konopka, Allan; Moore, Dean A.; Resch, Charles T.; Phillips, Jerry L.

2012-04-14T23:59:59.000Z

87

T-637: VMSA-2011-0009 VMware hosted product updates, ESX patches and VI ,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7: VMSA-2011-0009 VMware hosted product updates, ESX patches 7: VMSA-2011-0009 VMware hosted product updates, ESX patches and VI , Client update resolve multiple T-637: VMSA-2011-0009 VMware hosted product updates, ESX patches and VI , Client update resolve multiple June 6, 2011 - 3:04pm Addthis PROBLEM: VMSA-2011-0009 VMware hosted product updates, ESX patches and VI , Client update resolve multiple PLATFORM: Supported Platforms VMSA-2011-0009 ABSTRACT: This patch provides a fix for the following three security issues in the VMware Host Guest File System (HGFS). None of these issues affect Windows based Guest Operating Systems. CVE-2011-2146 Mount.vmhgfs Information Disclosure, information disclosure via a vulnerability that allows an attacker with access to the Guest to determine if a path exists in the Host filesystem and whether it is a file or directory regardless of permissions.

88

U.S. DEPARTMENT OF l!Nl!RGY EERE PROJECT MANAGEMENT CENTER NEPA DETERMINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NEPA DETERMINATION NEPA DETERMINATION RECIPIENT:Recovery Act: City of North Uttle Rock Page I of3 STATE: AR PROJECT TITLE: Hydroelectric Facility Improvement Project· Automated Intake Cleaning Equipment and Materials Management Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CIO Number DE-FOA-OOOO120 DE-EEOOO2674 GF~2674..oo2 EE2674 Based on my review of the Information concerning tbe proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1 A), J have made tbe following determination: CX, EA, EIS APPENDIX AND NUMBER : Description: B5.1 Actions to conserve energy, demonstrate potential energy conservation, and promote energy--efficlency that do not increase the indoor concentrations of potentially harmful substances. These acllons may involve financial and tecl"lOica!

89

U.S. DEPARTMENT OF 1!Nl!RGY EERE PROJECT MANAGEMENT CENTER Nl...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

for this award will be used to perfOfm feasibility studies for future development of tidal power in the Puget Sound, WA. The project will also involve developing deployment...

90

Those early days as we remember them (Part VI) - Met Lab & Early Argonne History  

NLE Websites -- All DOE Office Websites (Extended Search)

VI | Met Lab and Early Argonne History | Argonne National Laboratory VI | Met Lab and Early Argonne History | Argonne National Laboratory 1/2 Those early days as we remember them Part Vl Lester C. Furney (second from right), who formerly handled public relations at Argonne and is author of the article below, is pictured here in February 1956 with (l to r) Major General D. J. Keirn, Major General James McCormack, Jr. (Ret.), and Lt. General James H. Doolittle (Ret.) during a

91

Phase Field Simulation of Ni4Ti3 Precipitation in Porous NiTi Shape ...  

Science Conference Proceedings (OSTI)

Generally, porous NiTi alloys may undergo thermomechnical treatment which .... of First Derivative of Dilatation in Low Carbon Steels Multi-Phase Presenting.

92

Solidification and Microstructure Evaluation of the Ni-Ga and Co-Ni ...  

Science Conference Proceedings (OSTI)

Ni-Ga binary system is thus one of the basic binary system which forms the dominated ? ... The Effects of Natural and Marangoni Convection on the Resultant...

93

Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers  

Science Conference Proceedings (OSTI)

Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

2012-09-01T23:59:59.000Z

94

Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite  

E-Print Network (OSTI)

in aqueous solution for Pu(VI) taken from Guillaumont etTable 3. Least-squares fits of Pu L III -edge XANES data toIV) Figure 4. Energy (eV) Pu Solution Speciation pH Figure

Hu, Yung-Jin

2011-01-01T23:59:59.000Z

95

Characterization of U(VI) Sorption-Desorption Processes and Model Upscaling  

SciTech Connect

The objectives of the overall collaborative EMSP effort (with which this project is associated) were to characterize sorption and desorption processes of U(VI) on pristine and contaminated Hanford sediments over a range of sediment facies and materials properties and to relate such characterization both to fundamental molecular-scale understanding and field-scale models of geochemistry and mass transfer. The research was intended to provide new insights on the mechanisms of U(VI) retardation at Hanford, and to allow the development of approaches by which laboratory-developed geochemical models could be upscaled for defensible field-scale predictions of uranium transport in the environment. Within this broader context, objectives of the JHU-based project were to test hypotheses regarding the coupled roles of adsorption and impermeable-zone diffusion in controlling the fate and transport of U(VI) species under conditions of comparatively short-term exposure. In particular, this work tested the following hypotheses: (1) the primary adsorption processes in the Hanford sediment over the pH range of 7 to 10 are surface complexation reactions of aqueous U(VI) hydroxycarbonate and carbonate complexes with amphoteric edge sites on detrital phyllosilicates in the silt/clay size fraction; (2) macroscopic adsorption intensity (at given aqueous conditions) is a function of mineral composition and aquatic chemistry; and (3) equilibrium sorption and desorption to apply in short-term, laboratory-spiked pristine sediments; and (4) interparticle diffusion can be fully understood in terms of a model that couples molecular diffusion of uranium species in the porewater with equilibrium sorption under the relevant aqueous conditions. The primary focus of the work was on developing and applying both models and experiments to test the applicability of "local equilibrium" assumptions in the modeling interpretation of sorption retarded interparticle diffusion, as relevant to processes of U(VI) diffusion in silt/clay layers. Batch isotherm experiments were first used to confirm sorption isotherms under the intended test conditions and diffusion cell experiments were then conducted to explore the diffusion hypotheses. Important new information was obtained about the role of aqueous calcium and solid calcium carbonate in controlling sorption equilibrium with Hanford sediments. The retarded interparticle diffusion model with local sorption equilibrium was shown to very successfully simulate diffusion at high aqueous concentration of U(VI). By contrast, however, diffusion data obtained at low concentration suggested nonequilibrium of sorption even at diffusion time scales. Such nonequilibrium effects at low concentration are likely to be the result of sorption retarded intraparticle diffusion, and strong U(VI) sorption in the low concentration range.

Bai, Jing; Dong, Wenming; Ball, William P.

2006-10-12T23:59:59.000Z

96

Improvement of thermoelectric properties for half-Heusler TiNiSn by interstitial Ni defects  

SciTech Connect

We have synthesized off-stoichiometric Ti-Ni-Sn half-Heusler thermoelectrics in order to investigate the relation between randomly distributed defects and thermoelectric properties. A small change in the composition of Ti-Ni-Sn causes a remarkable change in the thermal conductivity. An excess content of Ni realizes a low thermal conductivity of 2.93 W/mK at room temperature while keeping a high power factor. The low thermal conductivity originates in the defects generated by an excess content of Ni. To investigate the detailed defect structure, we have performed first-principles calculations and compared with x ray photoemission spectroscopy measurement. Based on these analyses, we conclude that the excess Ni atoms randomly occupy the vacant sites in the half-Heusler structure, which play as phonon scattering centers, resulting in significant improvement of the figure of merit without any substitutions of expensive heavy elements, such as Zr and Hf.

Hazama, Hirofumi; Matsubara, Masato; Asahi, Ryoji [Toyota Central R and D Labs., Inc., Nagakute, Aichi 480-1192 (Japan); Takeuchi, Tsunehiro [Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan)

2011-09-15T23:59:59.000Z

97

Preparation of PtNi Nanoparticles for the Electrocatalytic Oxidation of Methanol  

E-Print Network (OSTI)

Carbon supported PtNi nanoparticles were prepared by hydrazine reduction of Pt and Ni precursor salts under different conditions, namely by conventional heating (PtNi-1), by prolonged reaction at room temperature (PtNi-2) ...

Deivaraj, T.C.

98

Airtricity Developments NI Ltd | Open Energy Information  

Open Energy Info (EERE)

NI Ltd NI Ltd Jump to: navigation, search Name Airtricity Developments NI Ltd Place Belfast, Northern Ireland, United Kingdom Zip BT2 7AF Sector Wind energy Product Focused on construction of wind farms in Northern Ireland. Coordinates 54.595295°, -5.934524° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":54.595295,"lon":-5.934524,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

99

Carbon Nanotube Growth Using Ni Catalyst in Different Layouts  

E-Print Network (OSTI)

Vertically aligned carbon nanotubes have been grown using Ni as catalyst by plasma enhanced chemical vapor deposition system (PECVD) in various pre-patterned substrates. Ni was thermally evaporated on silicon substrates ...

Nguyen, H. Q.

100

Effects of Chromium(VI) and Chromium(III) on Desulfovibrio vulgaris Cells  

DOE Green Energy (OSTI)

Desulfovibrio vulgaris ATCC 29579 is a well studied sulfate reducer that has known capabilities of reducing heavy metals and radionuclides, like chromium and uranium. Cultures grown in a defined medium (i.e. LS4D) had a lag period of approximately 40 h when exposed to 50 ?Mof Cr(VI). Substrate analysis revealed that although chromium is reduced within the first 5 h, growth does not resume for another 35 h. During this time, small amounts of lactate are still utilized but the reduction of sulfate does not occur. Sulfate reduction occurs concurrently with the accumulation of acetate approximately 40 h after inoculation, when growth resumes. Similar amounts of hydrogen are produced during this time compared to hydrogen production by cells not exposed to Cr(VI); therefore an accumulation of hydrogen cannot account for the utilization of lactate. There is a significant decrease in the carbohydrate to protein ratio at approximately 25 h, and this result indicated that lactate is not converted to glycogen. Most probable number analysis indicated that cell viability decreased steadily after inoculation and reached approximately 6 x 104 cells/ml 20 h post-chromium exposure. Regeneration of reducing conditions during chromium exposure does not induce growth and in fact may make the growth conditions even more unfavorable. This result suggested that an increase in Eh was not solely responsible for the decline in viability. Cell pellets collected 10 h after chromium-exposure were unable to resume growth when suspended into fresh medium. Supernatants from these pellets were able to support cell growth upon re- inoculation. D. vulgaris cells treated with a non-dose dependent addition of ascorbate at the same time of Cr(VI) addition did not enter a lag period. Ascorbate added 3 h post-Cr(VI) exposure did not prevent the growth lag. These results indicated that Desulfovibrio utilized lactate to reduce Cr(VI) without the reduction of sulfate, that the decline in cell viability and cell growth was most likely a consequence of Cr(III), and that an organic ligand could protect D. vulgaris cells from Cr(III) toxicity. Lactate consumption decoupled from sulfate reduction in the presence of Cr(VI) could provide organic carbon for organo- Cr(III) complexes.

M.E. Clark; A. Klonowska; S.B. Thieman; B. Giles; J.D. Wall; and M.W. Fields

2007-04-19T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Ni spin switching induced by magnetic frustration in FeMn/Ni/Cu(001)  

SciTech Connect

Epitaxially grown FeMn/Ni/Cu(001) films are investigated by Photoemission Electron Microscopy and Magneto-Optic Kerr Effect. We find that as the FeMn overlayer changes from paramagnetic to antiferromagnetic state, it could switch the ferromagnetic Ni spin direction from out-of-plane to in-plane direction of the film. This phenomenon reveals a new mechanism of creating magnetic anisotropy and is attributed to the out-of-plane spin frustration at the FeMn-Ni interface.

Wu, J.; Choi, J.; Scholl, A.; Doran, A.; Arenholz, E.; Hwang, Chanyong; Qiu, Z. Q.

2009-03-08T23:59:59.000Z

102

Magnetoelastic Coupling in NiMnGa Ferromagnetic Shape ...  

Science Conference Proceedings (OSTI)

... Magnetoelastic Coupling in NiMnGa Ferromagnetic Shape Memory Alloys. Peng Zhao (Dept. of Materials Science and ...

103

Sputtered II-VI Alloys and Structures forTandem PV: Final Subcontract Report, 9 December 2003 - 30 July 2007  

Science Conference Proceedings (OSTI)

This report elaborates on Phase 3 and provides summaries of the first two Phases. Phase 3 research work was divided into five task areas covering different aspects of the II-VI tandem cell.

Compaan, A. D.; Collins, R.; Karpov, V. G.; Giolando, D.

2008-09-01T23:59:59.000Z

104

Microbial community changes during sustained Cr(VI) reduction at the 100H site in Hanford, WA  

E-Print Network (OSTI)

at the 100H site in Hanford, WA Romy Chakraborty 1 , Eoin Lcontaminated aquifer at the Hanford (WA) 100H site in 2004.Cr(VI) reduction at Hanford, and a comparison of the

Chakraborty, Romy

2010-01-01T23:59:59.000Z

105

Rate-limited U(VI) desorption during a small-scale tracer test in a hetereogeneous uranium contaminated aquifer  

E-Print Network (OSTI)

of Contaminants in the Hanford Vadose Zone, Vadose Zone J. ,transport in a contaminated Hanford sediment, Environ. Sci.of U(VI) observed in Hanford sediment column experiments. A

Fox, P.M.

2013-01-01T23:59:59.000Z

106

Detection and Quantification of Pu(III, IV, V, and VI) Using a 1.0-meter Liquid Core Waveguide  

E-Print Network (OSTI)

absorption spectra of Pu ions in 1 M perchloric acidA. ) Pu III, B. )Pu IV, C. ) Pu V (0.001 M HClO 4 ), D. ) Pu VI. D

Wilson, Richard E.; Hu, Yung-Jin; Nitsche, Heino

2005-01-01T23:59:59.000Z

107

High Temperature coatings based on {beta}-NiAI  

Science Conference Proceedings (OSTI)

High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAlTiB{sub 2} composite are explained. A novel coating process for MoNiAl alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated MoNiAl alloys is discussed.

Severs, Kevin

2012-07-10T23:59:59.000Z

108

KENO3D Visualization Tool for KENO V.a and KENO-VI Geometry Models  

SciTech Connect

Criticality safety analyses often require detailed modeling of complex geometries. Effective visualization tools can enhance checking the accuracy of these models. This report describes the KENO3D visualization tool developed at the Oak Ridge National Laboratory (ORNL) to provide visualization of KENO V.a and KENO-VI criticality safety models. The development of KENO3D is part of the current efforts to enhance the SCALE (Standardized Computer Analyses for Licensing Evaluations) computer software system.

Horwedel, J.E.; Bowman, S.M.

2000-06-01T23:59:59.000Z

109

Process for forming shaped group II-VI semiconductor nanocrystals, and product formed using process  

DOE Patents (OSTI)

A process for the formation of shaped Group II-VI semiconductor nanocrystals comprises contacting the semiconductor nanocrystal precursors with a liquid media comprising a binary mixture of phosphorus-containing organic surfactants capable of promoting the growth of either spherical semiconductor nanocrystals or rod-like semiconductor nanocrystals, whereby the shape of the semiconductor nanocrystals formed in said binary mixture of surfactants is controlled by adjusting the ratio of the surfactants in the binary mixture.

Alivisatos, A. Paul (Oakland, CA); Peng, Xiaogang (Fayetteville, AR); Manna, Liberato (Palo del Colle, IT)

2001-01-01T23:59:59.000Z

110

Thermodynamics of the Complexation of Uranium(VI) by oxalate in aqueous solution at 10-70oC  

SciTech Connect

The protonation reactions of oxalate (ox) and the complex formation of uranium(VI) with oxalate in 1.05 mol kg{sup -1} NaClO{sub 4} were studied at variable temperatures (10-70 C). Three U(VI)/ox complexes (UO{sub 2}ox{sub j}{sup (2-2j){sup +}} with j = 1, 2, 3) were identified in this temperature range. The formation constants and the molar enthalpies of complexation were determined by spectrophotometry and calorimetry. The complexation of uranium(VI) with oxalate ion is exothermic at lower temperatures (10-40 C) and becomes endothermic at higher temperatures (55-70 C). In spite of this, the free energy of complexation becomes more negative at higher temperatures due to increasingly more positive entropy of complexation that exceeds the increase of the enthalpy of complexation. The thermodynamic parameters at different temperatures, in conjunction with the literature data for other dicarboxylic acids, provide insight into the relative strength of U(VI) complexes with a series of dicarboxylic acids (oxalic, malonic and oxydiacetic) and rationalization for the highest stability of U(VI)/oxalate complexes in the series. The data reported in this study are of importance in predicting the migration of uranium(VI) in geological environments in the case of failure of the engineering barriers which protect waste repositories.

Di Bernardo, Plinio; Zanonato, Pier Luigi; Tian, Guoxin; Tolazzi, Marilena; Rao, Linfeng

2009-03-31T23:59:59.000Z

111

Measurement of {sup 63}Ni and {sup 59}Ni by accelerator mass spectrometry using characteristic projectile x-rays  

Science Conference Proceedings (OSTI)

The long-lived isotopes of nickel ({sup 59}Ni, {sup 63}Ni) have current and potential use in a number of applications including cosmic radiation studies, biomedical tracing, characterization of low-level radioactive wastes, and neutron dosimetry. Methods are being developed at LLNL for the routine detection of these isotopes by AMS. One intended application is in Hiroshima dosimetry. The reaction {sup 63}Cu(n,p){sup 63}Ni has been identified as one of a small number of reactions which might be used for the direct determination of the fast neutron fluence emitted by the Hiroshima bomb. AMS measurement of {sup 63}Ni(t{sub 1/2} = 100 y) requires the chemical removal of {sup 63}Cu, which is a stable isobar of {sup 63}Ni. Following the electrochemical separation of Ni from gram-sized copper samples, the Cu concentration is further lowered to Hiroshima hypocenter. For the demonstration samples, the Cu content was chemically reduced by a factor of 10{sup 12} with quantitative retention of {sup 63}Ni. Detection sensitivity (3{sigma}) was {approximately}20 fg {sup 63}Ni in 1 mg Ni carrier ({sup 63}Ni/Ni {approx} 2 x 10{sup -11}). Significant improvements in sensitivity are expected with planned incremental changes in the methods. Preliminary results indicate that a similar sensitivity is achievable for {sup 59}Ni (t{sub 1/2} = 10{sup 5} y).

McAninch, J.E.; Hainsworth, L.J.; Marchetti, A.A. [and others

1996-05-01T23:59:59.000Z

112

New thermal neutron scattering files for ENDF/B-VI release 2  

SciTech Connect

At thermal neutron energies, the binding of the scattering nucleus in a solid, liquid, or gas affects the cross section and the distribution of secondary neutrons. These effects are described in the thermal sub-library of Version VI of the Evaluated Nuclear Data Files (ENDF/B-VI) using the File 7 format. In the original release of the ENDF/B-VI library, the data in File 7 were obtained by converting the thermal scattering evaluations of ENDF/B-III to the ENDF-6 format. These original evaluations were prepared at General Atomics (GA) in the late sixties, and they suffer from accuracy limitations imposed by the computers of the day. This report describes new evaluations for six of the thermal moderator materials and six new cold moderator materials. The calculations were made with the LEAPR module of NJOY, which uses methods based on the British code LEAP, together with the original GA physics models, to obtain new ENDF files that are accurate over a wider range of energy and momentum transfer than the existing files. The new materials are H in H{sub 2}O, Be metal, Be in BeO, C in graphite, H in ZrH, Zr in ZrH, liquid ortho-hydrogen, liquid para-hydrogen, liquid ortho-deuterium, liquid para-deuterium liquid methane, and solid methane.

MacFarlane, R.E.

1994-03-01T23:59:59.000Z

113

Electrode Induced Removal and Recovery of Uranium (VI) from Acidic Subsurfaces  

SciTech Connect

The overarching objective of this research is to provide an improved understanding of how aqueous geochemical conditions impact the removal of U and Tc from groundwater and how engineering design may be utilized to optimize removal of these radionuclides. Experiments were designed to address the unique conditions in Area 3 of ORNL while also providing broader insight into the geochemical effectors of the removal rates and extent for U and Tc. The specific tasks of this work were to: 1) quantify the impact of common aqueous geochemical and operational conditions on the rate and extent of U removal and recovery from water, 2) investigate the removal of Tc with polarized graphite electrode, and determine the influence of geochemical and operational conditions on Tc removal and recovery, 3) determine whether U and Tc may be treated simultaneous from Area 3 groundwater, and examine the bench-scale performance of electrode-based treatment, and 4) determine the capacity of graphite electrodes for U(VI) removal and develop a mathematical, kinetic model for the removal of U(VI) from aqueous solution. Overall the body of work suggests that an electrode-based approach for the remediation of acidic subsurface environments, such as those observed in Area 3 of ORNL may be successful for the removal for both U(VI) and Tc. Carbonaceous (graphite) electrode materials are likely to be the least costly means to maximize removal rates and efficiency by maximizing the electrode surface area.

Gregory, Kelvin [Carnegie Mellon University] [Carnegie Mellon University

2013-08-12T23:59:59.000Z

114

Comparison of Three Ni-Hard I Alloys  

Office of Scientific and Technical Information (OSTI)

Comparison of Three Ni-Hard I Alloys Comparison of Three Ni-Hard I Alloys Ö. N. Do-an 1 , J.A. Hawk 1 , and J.Rice 2 1 U.S. Department of Energy, Albany Research Center, Albany, Oregon 2 Texaloy Foundry Co., Inc., Floresville, Texas Keywords: Ni-Hard white irons, Bainite, Martensite, Austenite, Abrasion resistant iron Abstract This report documents the results of an investigation which was undertaken to reveal the similarities and differences in the mechanical properties and microstructural characteristics of three Ni-Hard I alloys. One alloy (B1) is ASTM A532 class IA Ni-Hard containing 4.2 wt. pct. Ni. The second alloy (B2) is similar to B1 but higher in Cr, Si, and Mo. The third alloy (T1) also falls in the same ASTM specification, but it contains 3.3 wt. pct. Ni. The alloys were evaluated in both as-cast and

115

Synthesis and characterization of T[Ni(CN){sub 4}].2pyz with T=Fe, Ni; pyz=pyrazine: Formation of T-pyz-Ni bridges  

Science Conference Proceedings (OSTI)

The formation of T-pyz-Ni bridges (pyz=pyrazine) in the T[Ni(CN){sub 4}].2pyz series is known for T=Mn, Zn, Cd and Co but not with T=Fe, Ni. In this contribution the existence of such bridges also for T=Fe, Ni is discussed. The obtained pillared solids, T[Ni(CN){sub 4}].2pyz, were characterized from XRD, TG, UV-Vis, IR, Raman, Moessbauer and magnetic data. Their crystal structures were refined in the orthorhombic Pmna space group from XRD powder patterns. The structural behavior of these solids on cooling down to 77 K was also studied. In the 180-200 K temperature range the occurrence of a structural transition to a monoclinic structure (P2{sub 1}/c space group) was observed. No temperature induced spin transition was observed for Fe[Ni(CN){sub 4}].2pyz. The iron (II) was found to be in high spin electronic state and this configuration is preserved on cooling down to 2 K. The magnetic data indicate the occurrence of a low temperature weak anti-ferromagnetic interaction between T metal centers within the T[Ni(CN){sub 4}] layer. In the paramagnetic region for Ni[Ni(CN){sub 4}].2pyz, a reversible temperature induced spin transition for the inner Ni atom was detected. - Graphical abstract: Rippled sheets structure for the pillared solids T[Ni(CN){sub 4}].2pyz. The pyrazine molecule is found forming T-pyz-Ni bridges between neighboring layers. Highlights: > Pillared 2D solids. > Inorganic-organic solids. > Assembling of molecular blocks. > From 1D and 2D building blocks to 3D solids.

Lemus-Santana, A.A. [Center for Applied Science and Advanced Technology, Legaria Unit, National Polytechnic Institute of Mexico, Mexico D.F. (Mexico); Rodriguez-Hernandez, J. [Center for Applied Science and Advanced Technology, Legaria Unit, National Polytechnic Institute of Mexico, Mexico D.F. (Mexico); Institute of Materials Science and Technology, University of Havana (Cuba); Gonzalez, M. [Center for Applied Science and Advanced Technology, Legaria Unit, National Polytechnic Institute of Mexico, Mexico D.F. (Mexico); Demeshko, S. [Institut fuer Anorganische Chemie, Georg-August-Universitaet Goettingen, Tammannstrasse 4, 37077 Goettingen (Germany); Avila, M. [Center for Applied Science and Advanced Technology, Legaria Unit, National Polytechnic Institute of Mexico, Mexico D.F. (Mexico); Knobel, M. [Institute of Physics 'Gleb Wataghin', UNICAMP, 13083-970 Campinas, SP (Brazil); Reguera, E., E-mail: ereguera@yahoo.com [Center for Applied Science and Advanced Technology, Legaria Unit, National Polytechnic Institute of Mexico, Mexico D.F. (Mexico)

2011-08-15T23:59:59.000Z

116

Investigations of HRC-Stimulated Bioreduction of Cr(VI) at Hanford 100H  

DOE Green Energy (OSTI)

Hypothesis: Lactate (Hydrogen Release Compound-HRC{trademark}) injection into chromium contaminated groundwater through an injection well will cause indirect or direct bioreduction of chromate [Cr(VI)] and precipitation of insoluble species of [Cr(III)] on soil particles, probably catalyzed at oxide surfaces, at the field scale. Objective: Assess the potential for immobilizing and detoxifying chromium-contaminated groundwater using lactate-stimulated bioreduction of Cr(VI) to Cr(III) at the Hanford Site's 100-H Area field site. Types of Research: A three-well system (injection well and upgradient and downgradient monitoring wells) was used for conducting the in situ biostimulation and monitoring. To assess the pre- and post-injection test groundwater conditions, we used an integrated monitoring approach, involving hydraulic, geochemical, microbial, and geophysical techniques and analytical methods, as well as conducted five Br-tracer injection tests and four pumping tests (concurrently with the Br-tracer tests). Groundwater biostimulation was conducted by injection of 40 lbs of {sup 13}C-labeled HRC into the injection well (over the depth interval from 44-50 ft) on 8/3/2004, followed by low-flow pumping (1.2 to 2.5 l/min) through the downgradient well (to ensure capture of groundwater flow lines passing through the injection well) for 27 days. Main Results: Although the total microbial population in sediments is relatively low (<10{sup 5} cells g-1) under background conditions, which is likely insufficient for direct enzymatic Cr(VI) reduction, several types of bacteria, e.g., Bacillus/Arthrobacter and Geobacter, are present in the Hanford sediments, which are known to reduce or sorb hexavalent chromium. The HRC injection stimulated microbial cell counts to reach the maximum of 2 x 10{sup 7} cells g{sup -1} 13-17 days after the injection, and generated highly reducing conditions. Geochemical and isotopic observations confirmed microbial metabolism of HRC. The Cr(VI) concentration in the monitoring and pumping wells decreased below drinking water minimum contaminant limits and remained below background concentrations even after 1.5 years, when redox conditions and microbial densities had returned to background levels. Fe(II) levels have remained high and may account for the continued reduction of Cr(VI).

T.C. Hazen; B. Faybishenko; D. Joyner; S. Borglin; E.Brodie; S. Hubbard; K. Williams; J. Peterson; J. Wan; T. Tokunaga; Long, P.E.; Newcomer, D.; Koenigsberg, S.; Willet, A.

2005-04-18T23:59:59.000Z

117

Investigations of HRC-Stimulated Bioreduction of Cr(VI) at Hanford 100H  

DOE Green Energy (OSTI)

Hypothesis: Lactate (Hydrogen Release Compound-HRC{trademark}) injection into chromium contaminated groundwater through an injection well will cause indirect or direct bioreduction of chromate [Cr(VI)] and precipitation of insoluble species of [Cr(III)] on soil particles, probably catalyzed at oxide surfaces, at the field scale. Objective: Assess the potential for immobilizing and detoxifying chromium-contaminated groundwater using lactate-stimulated bioreduction of Cr(VI) to Cr(III) at the Hanford Site's 100-H Area field site. Types of Research: A three-well system (injection well and upgradient and downgradient monitoring wells) was used for conducting the in situ biostimulation and monitoring. To assess the pre- and post-injection test groundwater conditions, we used an integrated monitoring approach, involving hydraulic, geochemical, microbial, and geophysical techniques and analytical methods, as well as conducted five Br-tracer injection tests and four pumping tests (concurrently with the Br-tracer tests). Groundwater biostimulation was conducted by injection of 40 lbs of {sup 13}C-labeled HRC into the injection well (over the depth interval from 44-50 ft) on 8/3/2004, followed by low-flow pumping (1.2 to 2.5 l/min) through the downgradient well (to ensure capture of groundwater flow lines passing through the injection well) for 27 days. Main Results: Although the total microbial population in sediments is relatively low (<10{sup 5} cells g{sup -1}) under background conditions, which is likely insufficient for direct enzymatic Cr(VI) reduction, several types of bacteria, e.g., Bacillus/Arthrobacter and Geobacter, are present in the Hanford sediments, which are known to reduce or sorb hexavalent chromium. The HRC injection stimulated microbial cell counts to reach the maximum of 2 x 10{sup 7} cells g{sup -1} 13-17 days after the injection, and generated highly reducing conditions. Geochemical and isotopic observations confirmed microbial metabolism of HRC. The CR(VI) concentration in the monitoring and pumping wells decreased below drinking water minimum contaminant limits and remained below background concentrations even after 1.5 years, when redox conditions and microbial densities had returned to background levels. Fe(II) levels have remained high and may account for the continued reduction of Cr(VI).

Hazen, T.C.; Faybishenko, B.; Joyner, D.; Borglin, S.; Brodie, E.; Hubbard, S.; Williams, K.; Peterson, J.; Wan, J.; Tokunaga, T.; Firestone, M.; Long, P.E.; Resch, C.T.; Cantrell, K.; Newcomer, D.; Koenigsberg, S.; Willet, A.

2006-04-05T23:59:59.000Z

118

Innovative Approach to Prevent Acid Drainage from Uranium Mill Tailings Based on the Application of Na-Ferrate (VI)  

SciTech Connect

The operation of uranium mining and milling plants gives rise to huge amounts of wastes from both mining and milling operations. When pyrite is present in these materials, the generation of acid drainage can take place and result in the contamination of underground and surface waters through the leaching of heavy metals and radionuclides. To solve this problem, many studies have been conducted to find cost-effective solutions to manage acid mine drainage; however, no adequate strategy to deal with sulfide-ric h wastes is currently available. Ferrate (VI) is a powerful oxidizing agent in aqueous media. Under acidic conditions, the redox potential of the Ferrate (VI) ion is the highest of any other oxidant used in wastewater treatment processes. The standard half cell reduction potential of ferrate (VI) has been determined as +2.20 V to + 0.72 V in acidic and basic solutions, respectively. Ferrate (VI) exhibits a multitude of advantageous properties, including higher reactivity and selectivity than traditional oxidant alternatives, as well as disinfectant, flocculating, and coagulant properties. Despite numerous beneficial properties in environmental applications, ferrate (VI) has remained commercially unavailable. Starting in 1953, different methods for producing a high purity, powdered ferrate (VI) product were developed. However, producing this dry, stabilized ferrate (VI) product required numerous process steps which led to excessive synthesis costs (over $20/lb) thereby preventing bulk industrial use. Recently a novel synthesis method for the production of a liquid ferrate (VI) based on hypochlorite oxidation of ferric ion in strongly alkaline solutions has been discovered (USPTO 6,790,428; September 14, 2004). This on-site synthesis process dramatically reduces manufacturing cost for the production of ferrate (VI) by utilizing common commodity feedstocks. This breakthrough means that for the first time ferrate (VI) can be an economical alternative to treating acid mining drainage generating materials. The objective of the present study was to investigate a methodology of preventing the generation of acid drainage by applying ferrate (VI) to acid generating materials prior to the disposal in impoundments or piles. Oxidizing the pyritic material in mining waste could diminish the potential for acid generation and its related environmental risks and long-term costs at disposal sites. The effectiveness of toxic metals removal from acid mine drainage by applying ferrate (VI) is also examined. Preliminary results presented in this paper show that the oxidation of pyrite by ferrate is a first-order rate reaction in Fe(VI) with a half-life of about six hours. The stability of Fe(VI) in water solutions will not influence the reaction rate in a significant manner. New low-cost production methods for making liquid ferrate on-site makes this technology a very attractive option to mitigate one of the most pressing environmental problems in the mining industry. (authors)

Fernandes, H.M.; Reinhart, D.; Lettie, L.; Franklin, M.R. [University of Central Florida, P.O. Box. 162450, Orlando, FL, 32816-2450 (United States); Fernandes, H.M.; Franklin, M.R. [Institute of Radiation Protection and Dosimetry (IRD), Av. Salvador Allende s/n - Recreio - Rio de Janeiro - RJ - 22795-090 (Brazil); Sharma, V. [Florida Institute of Technology, 150 West University Boulevard, Melbourne, FL 32901 (United States); Daly, L.J. [Ferrate Treatment Technologies, LLC, 6432 Pine Castle Blvd. Unit 2C, Orlando, FL, 32809 (United States)

2006-07-01T23:59:59.000Z

119

Stripe-to-bubble transition of magnetic domains at the spin reorientation of (Fe/Ni)/Cu/Ni/Cu(001)  

Science Conference Proceedings (OSTI)

Magnetic domain evolution at the spin reorientation transition (SRT) of (Fe/Ni)/Cu/Ni/Cu(001) is investigated using photoemission electron microscopy. While the (Fe/Ni) layer exhibits the SRT, the interlayer coupling of the perpendicularly magnetized Ni layer to the (Fe/Ni) layer serves as a virtual perpendicular magnetic field exerted on the (Fe/Ni) layer. We find that the perpendicular virtual magnetic field breaks the up-down symmetry of the (Fe/Ni) stripe domains to induce a net magnetization in the normal direction of the film. Moreover, as the virtual magnetic field increases to exceed a critical field, the stripe domain phase evolves into a bubble domain phase. Although the critical field depends on the Fe film thickness, we show that the area fraction of the minority domain exhibits a universal value that determines the stripe-to-bubble phase transition.

Wu, J.; Choi, J.; Won, C.; Wu, Y. Z.; Scholl, A.; Doran, A.; Hwang, Chanyong; Qiu, Z.

2010-06-09T23:59:59.000Z

120

SF 6432-NI (04-95)  

NLE Websites -- All DOE Office Websites (Extended Search)

6/14/11 6/14/11 Page 1 of 14 Printed copies of this document are uncontrolled. Retrieve latest version electronically. SF 6432-NI (06/14/11) SECTION II STANDARD TERMS AND CONDITIONS FOR FIXED PRICE CONTRACTS WITH THE NEWLY INDEPENDENT STATES OF THE FORMER SOVIET UNION INDEX OF CLAUSES. THE FOLLOWING CLAUSES APPLY TO REQUESTS FOR QUOTATION AND CONTRACTS AS INDICATED UNLESS SPECIFICALLY DELETED, OR EXCEPT TO THE EXTENT THEY ARE SPECIFICALLY SUPPLEMENTED OR AMENDED IN WRITING IN THE SIGNATURE PAGE OR SECTION I. NI01 - ACCEPTANCE OF TERMS AND CONDITIONS Contractor, by signing this Agreement, beginning performance, and/or delivering Items or services ordered under this Agreement, agrees to comply with all the terms and conditions and all specifications and other documents that this Contract incorporated by

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121

Microsoft Word - NiR.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Side-on Cu-Nitrosyl Coordination by Nitrite Reductase Side-on Cu-Nitrosyl Coordination by Nitrite Reductase Elitza I. Tocheva and Michael E. P. Murphy Department of Microbiology & Immunology, The University of British Columbia, Vancouver, BC, Canada V6T 1Z3. Nitric oxide (NO) is one of the smallest and simplest biologically active molecules. In mammals, NO is produced from arginine by isoforms of nitric oxide synthase, and it func- tions in signal transduction and as a cytoprotective or cytotoxic agent. In bacteria, NO is produced by nitrite reductase (NiR), a copper-containing enzyme, which is responsible for the reduction of nitrite to nitric oxide (NO) in the process of dissimilatory denitrification. Cu- containing NiRs are homotrimers with two distinct Cu sites per monomeric unit (1). The type

122

Measurement of {sup 63}Ni and {sup 59}Ni by accelerator mass spectrometry using characteristic projectile x-rays  

SciTech Connect

The long-lived isotopes of nickel ({sup 59}Ni, {sup 63}Ni) have current and potential use in a number of applications including cosmic radiation studies, biomedical tracing, characterization of low-level radioactive wastes, and neutron dosimetry. Methods are being developed at LLNL for the routine detection of these isotopes by AMS. One intended application is in Hiroshima dosimetry. The reaction {sup 63}Cu(n,p){sup 63}Ni has been identified as one of a small number of reactions which might be used for the direct determination of the fast neutron fluence emitted by the Hiroshima bomb. AMS measurement of {sup 63}Ni(t{sub 1/2} = 100 y) requires the chemical removal of {sup 63}Cu, which is a stable isobar of {sup 63}Ni. Following the electrochemical separation of Ni from gram-sized copper samples, the Cu concentration is further lowered to < 2 x 10{sup -8} (Cu/Ni) using the reaction of Ni with carbon monoxide to form the gas Ni(CO){sub 4}. The Ni(CO){sub 4} is thermally decomposed directly in sample holders for measurement by AMS. After analysis in the AMS spectrometer, the ions are identified using characteristic projectile x-rays, allowing further rejection of remaining {sup 63}Cu. In a demonstration experiment, {sup 63}Ni was measured in Cu wires (2-20 g) which had been exposed to neutrons from a {sup 252}Cf source. We successfully measured {sup 63}Ni at levels necessary for the measurement of Cu samples exposed near the Hiroshima hypocenter. For the demonstration samples, the Cu content was chemically reduced by a factor of 10{sup 12} with quantitative retention of {sup 63}Ni. Detection sensitivity (3{sigma}) was {approximately}20 fg {sup 63}Ni in 1 mg Ni carrier ({sup 63}Ni/Ni {approx} 2 x 10{sup -11}). Significant improvements in sensitivity are expected with planned incremental changes in the methods. Preliminary results indicate that a similar sensitivity is achievable for {sup 59}Ni (t{sub 1/2} = 10{sup 5} y).

McAninch, J.E.; Hainsworth, L.J.; Marchetti, A.A. [and others

1996-05-01T23:59:59.000Z

123

NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance  

SciTech Connect

Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

Rangan, M.; Yung, M. M.; Medlin, J. W.

2012-06-01T23:59:59.000Z

124

Optimizing Cr(VI) and Tc(VII) remediation through nano-scale biomineral engineering  

Science Conference Proceedings (OSTI)

To optimize the production of biomagnetite for the bioremediation of metal oxyanion contaminated waters, the reduction of aqueous Cr(VI) to Cr(III) by two biogenic magnetites and a synthetic magnetite was evaluated under batch and continuous flow conditions. Results indicate that nano-scale biogenic magnetite produced by incubating synthetic schwertmannite powder in cell suspensions of Geobacter sulfurreducens is more efficient at reducing Cr(VI) than either biogenic nano-magnetite produced from a suspension of ferrihydrite 'gel' or synthetic nano-scale Fe{sub 3}O{sub 4} powder. Although X-ray Photoelectron Spectroscopy (XPS) measurements obtained from post-exposure magnetite samples reveal that both Cr(III) and Cr(VI) are associated with nanoparticle surfaces, X-ray Magnetic Circular Dichroism (XMCD) studies indicate that some Cr(III) has replaced octahedrally coordinated Fe in the lattice of the magnetite. Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) measurements of total aqueous Cr in the associated solution phase indicated that, although the majority of Cr(III) was incorporated within or adsorbed to the magnetite samples, a proportion ({approx}10-15 %) was released back into solution. Studies of Tc(VII) uptake by magnetites produced via the different synthesis routes also revealed significant differences between them as regards effectiveness for remediation. In addition, column studies using a {gamma}-camera to obtain real time images of a {sup 99m}Tc(VII) radiotracer were performed to visualize directly the relative performances of the magnetite sorbents against ultra-trace concentrations of metal oxyanion contaminants. Again, the magnetite produced from schwertmannite proved capable of retaining more ({approx}20%) {sup 99m}Tc(VII) than the magnetite produced from ferrihydrite, confirming that biomagnetite production for efficient environmental remediation can be fine-tuned through careful selection of the initial Fe(III) mineral substrate supplied to Fe(III)-reducing bacteria.

Cutting, R. S.; Coker, V. S.; Telling, N. D.; Kimber, R. L.; Pearce, C. I.; Ellis, B.; Lawson, R; van der Laan, G.; Pattrick, R.A.D.; Vaughan, D.J.; Arenholz, E.; Lloyd, J. R.

2009-09-09T23:59:59.000Z

125

Rotational Augmentation Disparities in the MEXICO and UAE Phase VI Experiments: Preprint  

DOE Green Energy (OSTI)

Wind turbine structures and components suffer excessive loads and premature failures when key aerodynamic phenomena are not well characterized, fail to be understood, or are inaccurately predicted. Turbine blade rotational augmentation remains incompletely characterized and understood, thus limiting robust prediction for design. Pertinent rotational augmentation research including experimental, theoretical, and computational work has been pursued for some time, but large scale wind tunnel testing is a relatively recent development for investigating wind turbine blade aerodynamics. Because of their large scale and complementary nature, the MEXICO and UAE Phase VI wind tunnel experiments offer unprecedented synergies to better characterize and understand rotational augmentation of blade aerodynamics.

Schreck, S.; Sant, T.; Micallef, D.

2010-05-01T23:59:59.000Z

126

Magnetized Bianchi Type $VI_{0}$ Barotropic Massive String Universe with Decaying Vacuum Energy Density $?$  

E-Print Network (OSTI)

Bianchi type $VI_{0}$ massive string cosmological models using the technique given by Letelier (1983) with magnetic field are investigated. To get the deterministic models, we assume that the expansion ($\\theta$) in the model is proportional to the shear ($\\sigma$) and also the fluid obeys the barotropic equation of state. It was found that vacuum energy density $\\Lambda \\propto \\frac{1}{t^{2}}$ which matches with natural units. The behaviour of the models from physical and geometrical aspects in presence and absence of magnetic field is also discussed.

Anirudh Pradhan; Raj Bali

2008-05-22T23:59:59.000Z

127

Simplified Production of Ni-Based Oxide Dispersion Strengthened  

Science Conference Proceedings (OSTI)

Austenitic Steel Oxidation in Steam: Alloy Composition and Surface Modification ... Ni-Base Alloys for Use as Components in Advanced-USC Steam Turbines.

128

Development of Ni-Fe Hydrogenation Catalyst from D. Gigas ...  

Development of Ni-Fe Hydrogenation Catalyst from D. Gigas Hydrogenase Note: The technology described above is an early stage opportunity. Licensing rights to this ...

129

Cyclic Oxidation Behavior of Detonation Gun Sprayed Ni-20Cr ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cyclic Oxidation Behavior of Detonation Gun Sprayed Ni-20Cr Coating on a Boiler Steel at 900C. Author(s), Gagandeep Kaushal, Harpreet...

130

Hot Tearing in Directionally Solidified Ni-Based Superalloys  

Science Conference Proceedings (OSTI)

It is found that in most of the Ni-based superalloys studied there exists a critical ..... welds: minor elements do not individually cause significant increases in heat

131

Synthesis of Ni-Al Intermetallic Nanoparticle Catalysts by Vacuum ...  

Science Conference Proceedings (OSTI)

... methanol decomposition and methane steam reforming, indicating a possibility to develop Ni-Al intermetallic compounds as catalysts for hydrogen production.

132

Thermochemical Simulation of Cu-Ni Smelting Operations  

Science Conference Proceedings (OSTI)

As a second example, an advanced on-line thermochemical simulation of Xstrata Nickel's Sudbury NiCu sulphide smelting plant will be presented. The on-line...

133

Study of Supercritical CO2 Emulsion in Ni Electroplating and ...  

Science Conference Proceedings (OSTI)

Presentation Title, Study of Supercritical CO2 Emulsion in Ni Electroplating and Application in Fabrication of Defect-Free Micromechanical Component with High ...

134

Carbon Fiber with Ni-Coated Reinforced Aluminum Alloy Matrix ...  

Science Conference Proceedings (OSTI)

May 1, 2007 ... Carbon Fiber with Ni-Coated Reinforced Aluminum Alloy Matrix Composites by Bianhua Han, Tianjiao Luo, Chunlin Liang,Guangchun Yao,...

135

An Exploration of Catalytic Chemistry on Au/Ni(111)  

Science Conference Proceedings (OSTI)

This project explored the catalytic oxidation chemistry that can be effected on a Au/Ni(111) surface alloy. A Au/Ni(111) surface alloy is a Ni(111) surface on which less than 60% of the Ni atoms are replaced at random positions by Au atoms. The alloy is produced by vapor deposition of a small amount of Au onto Ni single crystals. The Au atoms do not result in an epitaxial Au overlayer or in the condensation of the Au into droplets. Instead, Au atoms displace and then replace Ni atoms on a Ni(111) surface, even though Au is immiscible in bulk Ni. The two dimensional structure of the clean Ni surface is preserved. This alloy is found to stabilize an adsorbed peroxo-like O2 species that is shown to be the critical reactant in the low temperature catalytic oxidation of CO and that is suspected to be the critical reactant in other oxidation reactions. This investigation revealed a new, practically important catalyst for CO oxidation that has since been patented.

Sylvia T. Ceyer

2011-12-09T23:59:59.000Z

136

Determination of Atomistic Structure of Ni-Base Single Crystal ...  

Science Conference Proceedings (OSTI)

l-2-1, Sengen, Tsukuba Science City, 305, Japan. *Department of ... The atomic locations of alloying elements in some Ni-base single crystal superalloys have...

137

Ni-Based Molecular Electrocatalysts for Hydrogen Oxidation  

NLE Websites -- All DOE Office Websites (Extended Search)

Ni-Based Molecular Electrocatalysts for Hydrogen Oxidation Dan DuBois National Renewable Energy Laboratory Nicolet, Y.; de Lacey, A. L.; Vernde, X.; Fernandez, V. M.; Hatchikian,...

138

Lessons Learned in Sputtering TiNi Thin Film  

Science Conference Proceedings (OSTI)

Experimental results have been published in journals and conference proceedings, but as yet TiNi thin film is not commercially available. The author and...

139

Catalytic Properties of Ni-Al Intermetallic Nanoparticle Catalysts for ...  

Science Conference Proceedings (OSTI)

In order to pursue high catalytic performance of Ni-Al intermetallic ... very high catalytic activity for methanol decomposition and methane steam reforming.

140

Fusion of radioactive $^{132}$Sn with $^{64}$Ni  

E-Print Network (OSTI)

Evaporation residue and fission cross sections of radioactive $^{132}$Sn on $^{64}$Ni were measured near the Coulomb barrier. A large sub-barrier fusion enhancement was observed. Coupled-channel calculations including inelastic excitation of the projectile and target, and neutron transfer are in good agreement with the measured fusion excitation function. When the change in nuclear size and shift in barrier height are accounted for, there is no extra fusion enhancement in $^{132}$Sn+$^{64}$Ni with respect to stable Sn+$^{64}$Ni. A systematic comparison of evaporation residue cross sections for the fusion of even $^{112-124}$Sn and $^{132}$Sn with $^{64}$Ni is presented.

J. F. Liang; D. Shapira; J. R. Beene; C. J. Gross; R. L. Varner; A. Galindo-Uribarri; J. Gomez del Campo; P. A. Hausladen; P. E. Mueller; D. W. Stracener; H. Amro; J. J. Kolata; J. D. Bierman; A. L. Caraley; K. L. Jones; Y. Larochelle; W. Loveland; D. Peterson

2007-04-05T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Microstructure Control of Ni Base Alloys with High Volume Fraction ...  

Science Conference Proceedings (OSTI)

hypo-stoichiometric composition of Ni3V, formation of "multi- variant structure ... reasons; one is the high TC (1318 K) at its stoichiometric composition [1, 2], and...

142

NREL Improves Hole Transport in Sensitized CdS?NiO Nanoparticle...  

NLE Websites -- All DOE Office Websites (Extended Search)

effective sensitizing dyes for p-type NiO. One of the factors limiting the use of NiO for solar cell application is the low hole conductivity in p-NiO. A team of researchers from...

143

Influence of support material on Ni catalysts for propane dry reforming to synthesis gas.  

E-Print Network (OSTI)

??Ni/SiO2 and Ni/Mg(Al)O catalysts with difference metal loadings have been prepared. The activity, selectivity and stability of supported Ni catalysts for propane dry reforming to (more)

Dai, Xin

2008-01-01T23:59:59.000Z

144

El Ni~no and La Ni~na: Causes and Global Consequences Michael J McPhaden  

E-Print Network (OSTI)

of an El Niño, the Aleutian low pressure system tends to be larger and more intense than in other years

145

Formation of a Novel Ordered Ni3Al Surface Structure by Codeposition on NiAl(110)  

SciTech Connect

The formation of a new type of ordered 2D Ni3Al overlayer by low-temperature codeposition on NiAl(110) is demonstrated by kinetic Monte Carlo simulation of a multisite atomistic lattice-gas model with a precise treatment of surface diffusion kinetics. Simultaneous codeposition with 3?1 Ni?Al yields poor ordering at 300 K but well-ordered structures by ?500??K. Sequential codeposition of Ni then Al yields unmixed core-ring nanostructures at 300 K but strong intermixing and ordering by ?500??K.

Han, Yong; Unal, Baris; Evans, James W.

2012-05-23T23:59:59.000Z

146

Synthesis and optical properties of II-O-VI highly mismatched alloys  

DOE Green Energy (OSTI)

We have synthesized ternary and quaternary diluted II-VI oxides using the combination of O ion implantation and pulsed laser melting. CdO{sub x}Te{sub 1-x} thin films with x up to 0.015, and the energy gap reduced by 150 meV were formed by O{sup +}-implantation in CdTe followed by pulsed laser melting. Quaternary Cd{sub 0.6}Mn{sub 0.4}O{sub x}Te{sub 1-x} and Zn{sub 0.88}Mn{sub 0.12}O{sub x}Te{sub 1-x} with mole fraction of incorporated O as high as 0.03 were also formed. The enhanced O incorporation in Mn-containing alloys is believed to be due to the formation of relatively strong Mn-O bonds. Optical transitions associated with the lower (E{sub -}) and upper (E{sub +}) conduction subbands resulting from the anticrossing interaction between the localized O states and the extended conduction states of the host are clearly observed in these quaternary diluted II-VI oxides. These alloys fulfill the criteria for a multiband semiconductor that has been proposed as a material for making high efficiency, single-junction solar cells.

Yu, K.M.; Walukiewicz, W.; Shan, W.; Wu, J.; Beeman, J.W.; Scarpulla, M.A.; Dubon, O.D.; Becla, P.

2004-01-20T23:59:59.000Z

147

Session VI  

Science Conference Proceedings (OSTI)

Aug 9, 2013 ... Materials for Inertial Fusion Energy: Michael Fluss1; Luke Hsiung1; ... Thoria- based fuel is regarded as a fuel for safer nuclear reactors as it has...

148

IREX VI  

Science Conference Proceedings (OSTI)

... particularly with respect to wavelength of the infra-red illuminant14 the angle of incident infrared light due to light emitting diode (LED) placement ...

2013-07-24T23:59:59.000Z

149

Rejuvenation of Ni-based Superalloys GTD444(DS) and Ren N5(SX)  

Science Conference Proceedings (OSTI)

D3: Weld Solidification Behavior of Ni-base Superalloys for Use in Advanced Supercritical Coal-fired Power Plants D4: Sputtered Ni-base Superalloys for...

150

Ni-Base Alloys for Use as Components in Advanced-USC Steam ...  

Science Conference Proceedings (OSTI)

Symposium, Properties, Processing, and Performance of Steels and Ni-Based Alloys for Advanced Steam Conditions. Presentation Title, Ni-Base Alloys for Use

151

Low temperature epitaxial growth of Ge on cube- textured Ni  

SciTech Connect

Quasi- single crystal Ge films were grown on [001]<010> textured Ni substrate at a temperature of 350 oC using an insulating buffer layer of CaF2. A direct deposition of Ge on Ni at 350 oC was shown to alloy with Ni. From x- ray pole figure analysis, it was shown that Ge grew epitaxially with the same orientation as CaF2 and the dispersions in the out- of- plane and in- plane directions were found to be 1.7 0.1o and 6 1o, respectively. In the out- of- plane direction, Ge[111]||CaF2[111]||Ni[001]. In addition, the Ge consisted of four equivalent in- plane oriented domains such that two mutually orthogonal directions: Ge 211 and Ge 011 are parallel to mutually orthogonal directions: Ni 110 and Ni 110 , respectively of the Ni(001) surface. This was shown to be originated from the four equivalent in- plane oriented domains of CaF2 created to minimize the mismatch strain between CaF2 and Ni in those directions.

GIARE, C [Rensselaer Polytechnic Institute (RPI); Palazzo, J [Rensselaer Polytechnic Institute (RPI); Goyal, Amit [ORNL; WANG, G [Rensselaer Polytechnic Institute (RPI); LU, T [Rensselaer Polytechnic Institute (RPI)

2012-01-01T23:59:59.000Z

152

Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants  

DOE Patents (OSTI)

A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd{sub 0.54}Er{sub 0.46})AlNi alloys having a relatively constant {Delta}Tmc over a wide temperature range. 16 figs.

Gschneidner, K.A. Jr.; Takeya, Hiroyuki

1995-10-31T23:59:59.000Z

153

Ni-Pt silicide formation through Ti mediating layers  

Science Conference Proceedings (OSTI)

With Ni"1"-"xPt"xSi, the variation in queue time between the final surface cleaning and Ni-Pt deposition represents a significant manufacturability issue. A short queue time is often difficult to maintain, leading to the formation of an oxide layer on ... Keywords: Mediated reaction, Nickel silicide, Oxidation, Titanium

Paul Besser; Christian Lavoie; Ahmet Ozcan; Conal Murray; Jay Strane; Keith Wong; Michael Gribelyuk; Yun-Yu Wang; Christopher Parks; Jean Jordan-Sweet

2007-11-01T23:59:59.000Z

154

Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants  

DOE Patents (OSTI)

A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd.sub.0.54 Er.sub.0.46)AlNi alloys having a relatively constant .DELTA.Tmc over a wide temperature range.

Gschneidner, Jr., Karl A. (Ames, IA); Takeya, Hiroyuki (Ibaraki, JP)

1995-10-31T23:59:59.000Z

155

Ultrathin Silver Films on Ni(111)  

SciTech Connect

The growth and atomic structure of ultrathin silver films on Ni(111) was investigated by low-energy electron microscopy and diffraction (LEEM/LEED) as well as intensity-voltage [I(V)]-LEEM in the growth temperature range between 470 and 850 K. We find that silver grows in a Stranski-Krastanov mode with a two monolayer thin wetting layer which takes on a p(7 x 7) reconstruction at temperatures lower than 700 K and a ({radical}52 x {radical}52)R13.9{sup o} reconstruction at higher temperatures. The occurrence of the two distinct reconstructions is shown to have profound implications for the growth characteristics of films exhibiting thicknesses of one and two monolayers. The nanoscale I(V) characteristics of the films were analyzed by means of multiple-scattering calculations based on dynamical LEED theory. Furthermore, the vertical interatomic spacing at the interface between the Ag film and the Ni substrate was determined to (2.8 {+-} 0.1) {angstrom} for all film thicknesses (<13 ML) while the uppermost silver layer relaxes by about (4 {+-} 1)% toward the crystal.

Meyer, A.; Flege, J; Rettew, R; Senanayake, S; Schmidt, T; Alamgir, F; Falta, J

2010-01-01T23:59:59.000Z

156

Ultrathin Silver Films on Ni(111)  

SciTech Connect

The growth and atomic structure of ultrathin silver films on Ni(111) was investigated by low-energy electron microscopy and diffraction (LEEM/LEED) as well as intensity-voltage [I(V)]-LEEM in the growth temperature range between 470 and 850 K. We find that silver grows in a Stranski-Krastanov mode with a two monolayer thin wetting layer which takes on a p(7 x 7) reconstruction at temperatures lower than 700 K and a ({radical}52 x {radical}52)R13.9{sup o} reconstruction at higher temperatures. The occurrence of the two distinct reconstructions is shown to have profound implications for the growth characteristics of films exhibiting thicknesses of one and two monolayers. The nanoscale I(V) characteristics of the films were analyzed by means of multiple-scattering calculations based on dynamical LEED theory. Furthermore, the vertical interatomic spacing at the interface between the Ag film and the Ni substrate was determined to (2.8 {+-} 0.1) {angstrom} for all film thicknesses (<13 ML) while the uppermost silver layer relaxes by about (4 {+-} 1)% toward the crystal.

Flege, J.I.; Senanayake, S.; Meyer, A.; Rettew, R.E.; Schmidt, T.; Alamgir, F.M.; Falta, J.

2010-08-16T23:59:59.000Z

157

All-vapor processing of P-type tellurium-containing II-VI semiconductor and ohmic contacts thereof  

DOE Patents (OSTI)

An all dry method for producing solar cells is provided comprising first heat-annealing a II-VI semiconductor; enhancing the conductivity and grain size of the annealed layer; modifying the surface and depositing a tellurium layer onto the enhanced layer; and then depositing copper onto the tellurium layer so as to produce a copper tellurium compound on the layer.

McCandless, Brian E.

2000-03-01T23:59:59.000Z

158

Formation of a Novel Ordered Ni3Al Surface Structure by Codeposition on NiAl(110)  

E-Print Network (OSTI)

The formation of a new type of ordered 2D Ni3Al overlayer by low-temperature codeposition on NiAl(110) is demonstrated by kinetic Monte Carlo simulation of a multisite atomistic lattice-gas model with a precise treatment ...

Han, Yong

159

Evaluation of electron capture reaction rates in Ni isotopes in stellar environments  

SciTech Connect

Electron capture rates in Ni isotopes are studied in stellar environments, that is, at high densities and high temperatures during the core-collapse and postbounce explosive nucleosynthesis in supernovae. Reaction rates in {sup 58}Ni and {sup 60}Ni, as well as in {sup 56}Ni, {sup 62}Ni, and {sup 64}Ni, are evaluated by shell-model calculations with the use of a new shell-model Hamiltonian in the fp shell, GXPF1J. While the previous shell-model calculations failed to reproduce the measured peaks of Gamow-Teller strength in {sup 58}Ni and {sup 60}Ni, the present new Hamiltonian is found to reproduce them very well, as well as the capture rates obtained from the observed strengths. Strengths and energies of the Gamow-Teller transitions in {sup 56}Ni, {sup 62}Ni, and {sup 64}Ni are also found to be consistent with the observations.

Suzuki, Toshio [Department of Physics and Graduate School of Integrated Basic Sciences, College of Humanities and Sciences, Nihon University Sakurajosui 3-25-40, Setagaya-ku, Tokyo 156-8550 (Japan); Center for Nuclear Study, University of Tokyo, Hirosawa, Wako-shi, Saitama 351-0198 (Japan); National Astronomical Observatory of Japan, Mitaka, Tokyo 181-8588 (Japan); Honma, Michio [Center for Mathematical Sciences, University of Aizu, Aizu-Wakamatsu, Fukushima 965-8580 (Japan); Mao, Helene [ENSPS, Pole API-Parc d'Innovation, Boulevard Sebastien Brant, BP 10413, F-67412 Illkirch Cedex (France); Otsuka, Takaharu [Department of Physics and Center for Nuclear Study, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Kajino, Toshitaka [National Astronomical Observatory of Japan, Mitaka, Tokyo 181-8588 (Japan); Deaprtment of Astronomy, Graduate School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan)

2011-04-15T23:59:59.000Z

160

THE DIAGNOSTIC O VI ABSORPTION LINE IN DIFFUSE PLASMAS: COMPARISON OF NON-EQUILIBRIUM IONIZATION STRUCTURE SIMULATIONS TO FUSE DATA  

Science Conference Proceedings (OSTI)

The nature of the interstellar O VI in the Galactic disk is studied by means of a multi-fluid hydrodynamical approximation, tracing the detailed time-dependent evolution of the ionization structure of the plasma. Our focus is to explore the signature of any non-equilibrium ionization condition present in the interstellar medium using the diagnostic O VI ion. A detailed comparison between the simulations and FUSE data is carried out by taking lines of sight (LOS) measurements through the simulated Galactic disk, covering an extent of 4 kpc from different vantage points. The simulation results bear a striking resemblance with the observations: (1) the N(O VI) distribution with distance and angle fall within the minimum and maximum values of the FUSE data; (2) the column density dispersion with distance is constant for all the LOS, showing a mild decrease at large distances; (3) O VI has a clumpy distribution along the LOS; and (4) the time-averaged midplane density for distances >400 pc has a value of (1.3-1.4) Multiplication-Sign 10{sup -8} cm{sup -3}. The highest concentration of O VI by mass occurs in the thermally stable (10{sup 3.9} K < T {<=} 10{sup 4.2} K; 20%) and unstable (10{sup 4.2} K < T < 10{sup 5} K; 50%) regimes, both well below its peak temperature in collisional ionization equilibrium, with the corresponding volume filling factors oscillating with time between 8%-20% and 4%-5%, respectively. These results may also be relevant for intergalactic metal absorption systems at high redshifts.

De Avillez, Miguel A. [Department of Mathematics, University of Evora, R. Romao Ramalho 59, 7000 Evora (Portugal); Breitschwerdt, Dieter [Zentrum fuer Astronomie und Astrophysik, Technische Universitaet Berlin, Hardenbergstrasse 36, D-10623 Berlin (Germany)

2012-12-20T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Calculation of the electron structure of vacancies and their compensated states in III-VI semiconductors  

Science Conference Proceedings (OSTI)

The Green's functions theory and the bond-orbital model are used as a basis for calculations of the electron structure of local defects-specifically, vacancies and their compensated states in III-VI semiconductors. The energy levels in the band gap are established, and the changes induced in the electron densities in the GaS, GaSe, and InSe semiconductors by anion and cation vacancies and their compensated states are calculated. It is established that, if a vacancy is compensated by an atom of an element from the same subgroup with the same tetrahedral coordination and if the ionic radius of the compensating atom is smaller than that of the substituted atom, the local levels formed by the vacancy completely disappear. It is shown that this mechanism of compensation of vacancies provides a means not only for recovering the parameters of the crystal, but for improving the characteristics of the crystal as well.

Mehrabova, M. A., E-mail: Mehrabova@mail.ru; Madatov, R. S. [Azerbaijan National Academy of Sciences, Institute of Radiation Problems (Azerbaijan)

2011-08-15T23:59:59.000Z

162

OFFICE OF THE GOVERNOR GOVERNMENT HOUSE Charlotte Amalie, V.I. 00802  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

GOVERNMENT HOUSE GOVERNMENT HOUSE Charlotte Amalie, V.I. 00802 340-774-0001 March 4,2009 The Honorable Steven Chu Secretary U.S. Department of Energy 1000 Independence Avenue, S . W. Washington, D.C. 20585 Re: State Energy Program Assurances Dear Secretary Chu: As a condition of receiving our State share of the $3.1 billion funding for the State Energy Program (SEP) under the American Recovery and Reinvestment Act of 2009 (ARRA), P.L. 11 1-5, I am providing the following assurances. I have written to the chairman of our Public Service Commission and requested that it consider additional actions to promote energy efficiency, consistent with the statutory requirements set forth in the ARRA and its obligations to maintain just and reasonable rates, while protecting the public. I have also written to the

163

Modification of Ni state to promote the stability of Ni-Al{sub 2}O{sub 3} catalyst in methane decomposition to produce hydrogen and carbon nanofibers  

SciTech Connect

The methodology was illustrated for modifying the state of Ni to promote the stability of the coprecipitated Ni-Al{sub 2}O{sub 3} catalyst via incorporating ZnO and Cu in methane decomposition to produce hydrogen and carbon nanofibers. The influences of the incorporation on the state of Ni were examined with XRD, TPR, XPS and TEM. For the incorporation of ZnO, ZnAl{sub 2}O{sub 4} spinel-like structure could be formed in the interface between ZnO and Al{sub 2}O{sub 3}. The interaction between Ni and the ZnAl{sub 2}O{sub 4} structure can promote both the activity and the stability of Ni in methane decomposition. The formation of a Ni-Cu alloy from Ni and the incorporated Cu decreases the activity of Ni, however, promotes the stability pronouncedly. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer Methodology for modifying Ni state of coprecipitated Ni-Al{sub 2}O{sub 3} was illustrated. Black-Right-Pointing-Pointer Influence of incorporating ZnO/Cu on Ni state of Ni-Al{sub 2}O{sub 3} was compared. Black-Right-Pointing-Pointer Influence of modifying Ni state on performance of Ni-Al{sub 2}O{sub 3} was investigated.

Chen Jiuling, E-mail: cjlchen@yahoo.com [Department of Catalysis Science and Technology, School of Chemical Engineering, Tianjin University, Tianjin 300072 (China); Qiao Yuanhua; Li Yongdan [Department of Catalysis Science and Technology, School of Chemical Engineering, Tianjin University, Tianjin 300072 (China)

2012-07-15T23:59:59.000Z

164

Geometric and Electronic Structures of the Ni(I) and Methyl-Ni(III)  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 Geometric and Electronic Structures of the Ni(I) and Methyl-Ni(III) Intermediates of Methyl-Coenzyme M Reductase Methyl-coenzyme M reductase (MCR) from methanogenic archaea catalyzes the terminal step in biological methane synthesis. Using coenzyme B (CoBSH) as the two-electron donor, MCR reduces methyl-coenzyme M (methyl-SCoM) to form methane and the heterodisulfide product, CoBS-SCoM. MCR contains an essential redox active nickel tetrapyrrolic cofactor called coenzyme F430 at its active site, which is active in the reduced Ni(I) state (MCRred1). All of the biologically generated methane, amounting to 1 billion tons per annum globally, is formed by MCR. Furthermore, recent evidence indicates that anaerobic methane oxidation is also catalyzed by MCR and occurs by a reversal of the methane synthesis reaction. Methane is a potent greenhouse gas, trapping 20 times more heat than CO2. In addition, methane is also an important and clean fuel as it produced the least amount of CO2 per unit of heat released. Thus, it is critically important to understand the mechanism of formation of the smallest hydrocarbon in nature.

165

Mesoscale assembly of NiO nanosheets into spheres  

SciTech Connect

NiO solid/hollow spheres with diameters about 100 nm have been successfully synthesized through thermal decomposition of nickel acetate in ethylene glycol at 200 deg. C. These spheres are composed of nanosheets about 3-5 nm thick. Introducing poly(vinyl pyrrolidone) (PVP) surfactant to reaction system can effectively control the products' morphology. By adjusting the quantity of PVP, we accomplish surface areas-tunable NiO assembled spheres from {approx}70 to {approx}200 m{sup 2} g{sup -1}. Electrochemical tests show that NiO hollow spheres deliver a large discharge capacity of 823 mA h g{sup -1}. Furthermore, these hollow spheres also display a slow capacity-fading rate. A series of contrastive experiments demonstrate that the surface area of NiO assembled spheres has a noticeable influence on their discharge capacity. - Graphical abstract: The mesoscale assembly of NiO nanosheets into spheres have been achieved by a solvothermal method. N{sub 2} adsorption/desorption isotherms show the S{sub BET} of NiO is tunable. NiO spheres show large discharge capacity and slow capacity-fading rate.

Zhang Meng, E-mail: meng_zhang@haut.edu.c [School of Materials Science and Engineering, Henan University of Technology, Zhengzhou, Henan 450007 (China); Yan Guojin; Hou Yonggai; Wang Chunhua [School of Materials Science and Engineering, Henan University of Technology, Zhengzhou, Henan 450007 (China)

2009-05-15T23:59:59.000Z

166

Overall Photocatalytic Water Splitting with NiOx-SrTiO3 A Revised Mechanism  

Science Conference Proceedings (OSTI)

NiOx (0 water splitting under UV light. The established mechanism for this and many other NiOx containing catalysts assumes water oxidation to occur at the early transition metal oxide and water reduction at NiOx. Here we show that NiOx-STO is more likely a three component Ni-STO-NiO catalyst, in which STO absorbs the light, Ni reduces protons, and NiO oxidizes water. This interpretation is based on systematic H2/O2 evolution tests of appropriately varied catalyst compositions using oxidized, chemically and photochemically added nickel and NiO nanoparticle cocatalysts. Surface photovoltage (SPV) measurements reveal that Ni(0) serves as an electron trap (site for water reduction) and that NiO serves as a hole trap (site for water oxidation). Electrochemical measurements show that the overpotential for water oxidation correlates with NiO content, whereas the water reduction overpotential depends on Ni content. Photodeposition experiments with NiCl2 and H2PtCl6 on NiO-STO show that electrons are available on the STO surface, not on the NiO particles. Based on photoelectrochemistry, both NiO and Ni particles suppress the Fermi level in STO, but the effect of this shift on catalytic activity is not clear. Overall, the results suggest a revised role for NiO in NiOx-STO and in many other nickel-containing water splitting systems, including NiOx-La:KTaO3, and many layered perovskites.

Townsend, Troy K.; Browning, Nigel D.; Osterloh, Frank

2012-11-01T23:59:59.000Z

167

Graphene Monolayer Rotation on Ni(111) Facilities Bilayer Graphene Growth  

Science Conference Proceedings (OSTI)

Synthesis of bilayer graphene by chemical vapor deposition is of importance for graphene-based field effect devices. Here, we demonstrate that bilayer graphene preferentially grows by carbon-segregation under graphene sheets that are rotated relative to a Ni(111) substrate. Rotated graphene monolayer films can be synthesized at growth temperatures above 650 C on a Ni(111) thin-film. The segregated second graphene layer is in registry with the Ni(111) substrate and this suppresses further C-segregation, effectively self-limiting graphene formation to two layers.

Batzill M.; Sutter P.; Dahal, A.; Addou, R.

2012-06-11T23:59:59.000Z

168

U.S. DEPARTMENT OFENl!RGY EERE PROJECT MANAGEMENT CENTER NEPA DE1'FIU.llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NEPA DE1'FIU.llNATION NEPA DE1'FIU.llNATION RECIPIENT:Colorado School of Mines Page 1 of2 STATE: CO PROJECf TITLE: Hot Carrier Collection in Thin Film Silicon with Tailored Nanocrystalline/Amorphous Structure Funding Opportunity Announcement Numbu Procurement Instrument Number NEPA Control Number elD Number OE-FOA-OOOO387 DE-EE0005326 GF0-0005326-001 0 Based on my review oftbe Information conccming the proposed action, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the follo",," ing determination: ex, EA, EIS APPENDIX AND NUMBER: Description: 8 3.15 Small-scale i ndoor research and development projects usIng nanascate materials Siting, construction, modrficabon, operation, and decommissioning of facilities for indoor small-scale research and

169

U.S. DEPARTMENT OFENl!RGY EERE PROJECT MANAGEMENT CENTER Nl!PA DETlffiMINATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nl!PA DETlffiMINATION Nl!PA DETlffiMINATION R[CIPIENT:New York State Energy Research and Development Authority PROJECf TITLE: Program Year 2012 Formula Grants - State Energy Program Page 1 of3 STATE: NY Funding Opportunity Announcement Numbel" Procurement Instrument Number NEPA Control Number CID Number DE-FOA-Q000643 R130772 GF0-0130772-OO1 Based on my review orlbe information concerning the proposed action, as NEPA Compliance Omen (authorized under DOE Order 451.1A), I hne made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: All Technical advice and assistance to organization, A9 Information gathering, analysis, and dissemination Rational for determination: Technical advice and planning aSSistance to international, national, slate, and local organizations.

170

Renewable and alteRnative eneRgy Fact Sheet College of Agricultural Sciences Agricultural Research and Cooperative Extension  

E-Print Network (OSTI)

the performance you can expect when running an engine on biodiesel. Properties of biodiesel versus Petroleum Research and Cooperative Extension What's So Different about Biodiesel Fuel? 1. If the biodiesel is made"(FAEE). introduction Biodiesel is a liquid fuel that is created by chemically process- ing vegetable oil and altering

Boyer, Elizabeth W.

171

$^{64}$Ni+$^{64}$Ni fusion reaction calculated with the density-constrained time-dependent Hartree-Fock formalism  

E-Print Network (OSTI)

We study fusion reactions of the $^{64}$Ni+$^{64}$Ni system using the density-constrained time-dependent Hartree-Fock (TDHF) formalism. In this formalism the fusion barriers are directly obtained from TDHF dynamics. In addition, we incorporate the entrance channel alignments of the slightly deformed (oblate) $^{64}$Ni nuclei due to dynamical Coulomb excitation. We show that alignment leads to a fusion barrier distribution and alters the naive picture for defining which energies are actually sub-barrier. We also show that core polarization effects could play a significant role in fusion cross section calculations.

A. S. Umar; V. E. Oberacker

2007-09-25T23:59:59.000Z

172

Powder Metallurgy Processing of Replicated Ni-Mn-Ga Foams  

Science Conference Proceedings (OSTI)

Development of a SMA-Based Drive Unit for Prehension Orthoses to Support Disabled People Effect of H in Metals and Alloys: An Application to bcc W and NiTi...

173

The Application of CALPHAD Calculations to Ni-Based Superalloys  

Science Conference Proceedings (OSTI)

The Cr content was raised from 20 to 24wt% to increase coal ash corrosion resistance. 2. ..... Ni-based Alloys, Univ.Cambridge report to Rolls-Royce plc.,. Derby...

174

Electrochemically Preparing of Ni-Fe Alloys in Molten Sodium ...  

Science Conference Proceedings (OSTI)

A Pilot-plant Scale Test of Coal-based Rotary Kiln Direct Reduction of Laterite Ore for Fe-Ni Production A Pilot-plant Scale Test on DRI Preparation from...

175

Spatially resolved U(VI) partitioning and speciation: Implications for plume scale behavior of contaminant U in the Hanford vadose zone  

E-Print Network (OSTI)

EM/GJ1302- 2006, Stoller Hanford Office, Richland, WA. 2006.characterization of U(VI) in Hanford vadose zone poreUranium Geochemistry at the Hanford Site. Pacific Northwest

Wan, Jiamin

2009-01-01T23:59:59.000Z

176

A Conceptual model of coupled biogeochemical and hydrogeological processes affected by in situ Cr(VI) bioreduction in groundwater at Hanford 100H Site  

E-Print Network (OSTI)

in Groundwater at Hanford 100H Site B.Faybishenko, P.E.Long,Cr(VI) contaminated groundwater at Hanford 100H site. A slowHRC TM ), was injected in Hanford sediments to stimulate

2006-01-01T23:59:59.000Z

177

XPS study of Ni-Fe manganite thermistor material  

SciTech Connect

The resistivity of the as-fabricated thermistor material, nickel-iron-manganite, changes during initial aging in the temperature range of 150-300{degrees}C before becoming stable. X-ray photoelectron spectroscopy (XPS) was used to determine if any valency change or chemical shift of the cations or oxygen occurred after aging. The goal of the study was to identify any ionic changes that might affect thermistor stability. The only observed changes in 2p{sub 3/2} peaks due to aging were those related to Ni ions; the same peaks for Mn, Fe, and O remained unchanged. The changes in the Ni 2p{sub 3/2} peak may be related to: (a) the migration of Ni{sup 2+} ions from octahedral to tetrahedral sites, (b) subtle changes in the energy states of Ni{sup 2+} which promoted a more stable ionic structure, and/or (c) the presence of Ni{sup 3+} ions, some of which revert back to Ni{sup 2+}.

Braski, D.N. [Oak Ridge National Lab., TN (United States); Osborne, N.R. [Univ. of Dayton Research Institute, OH (United States); Zurbuchen, J.M. [Yellow Springs Instruments, Inc., OH (United States)

1995-03-01T23:59:59.000Z

178

Gas Combustion Appliances: Validating VENT-II Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and  

NLE Websites -- All DOE Office Websites (Extended Search)

Predicting Backdrafting and Spillage for Natural-Draft Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray Environmental Energy Technologies Division April 2013 In Press as: Vi H. Rapp, Albert Pastor-Perez, Brett C. Singer, and Craig P. Wray. 2013. "Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: A Validation of VENT-II". HVAC&R Research, DOI:10.1080/10789669.2013.771948 LBNL-6193E 2 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof,

179

CORROSION STUDY FOR THE EFFLUENT TREATMENT FACILITY (ETF) CHROME (VI) REDUCTANT SOLUTION USING 304 & 316L STAINLESS STEEL  

Science Conference Proceedings (OSTI)

The Effluent Treatment Facility has developed a method to regenerate spent resin from the groundwater pump and treat intercepting chrome(VI) plumes (RPP-RPT-32207, Laboratory Study on Regeneration of Spent DOWEX 21K 16-20 Mesh Ion Exchange Resin). Subsequent laboratory studies have shown that the chrome(VI) may be reduced to chrome(III) by titrating with sodium metabisulfite to an oxidation reduction potential (ORP) of +280 mV at a pH of 2. This test plan describes the use of cyclic potentiodynamic polarization and linear polarization techniques to ascertain the electrochemical corrosion and pitting propensity of the 304 and 316L stainless steel in the acidified reducing the solution that will be contained in either the secondary waste receiver tank or concentrate tank.

DUNCAN, J.B.

2007-06-27T23:59:59.000Z

180

Transformation Induced Fatigue of Ni-Rich NiTi Shape Memory Alloy Actuators  

E-Print Network (OSTI)

In this work the transformation induced fatigue of Ni-rich NiTi shape memory alloys (SMAs) was investigated. The aerospace industry is currently considering implementing SMA actuators into new applications. However, before any new applications can be put into production they must first be certified by the FAA. Part of this certification process includes the actuator fatigue life. In this study, as-received and polished at dogbone SMA specimens underwent transformation induced fatigue testing at constant loading. The constant applied loading ranged from 100 MPa to 200 MPa. Specimens were thermally cycled through complete actuation (above Af to below Mf ) by Joule heating and environmental cooling. There were three cooling environments studied: liquid, gaseous nitrogen and vortex cooled air. It was shown that polished specimens had fatigue lives that were two to four times longer than those of as-received specimens. Test environment was also found to have an effect on fatigue life. Liquid cooling was observed to be corrosive, while the gaseous nitrogen and vortex air cooling were observed to be non-corrosive. The two non-corrosive cooling environments performed similarly with specimen fatigue lives that were twice that of specimens fatigue tested in the corrosive cooling environment. Transformation induced fatigue testing of polished specimens in a non-corrosive environment at 200 MPa had an average fatigue life of 14400 actuation cycles; at 150 MPa the average fatigue life was 20800 cycles and at 100 MPa it was 111000 cycles. For all specimens constant actuation from the beginning of testing until failure was observed, without the need for training. Finally, a microstructural study showed that the Ni3Ti precipitates in the material were one of the causes of crack initiation and propagation in the actuators.

Schick, Justin Ryan

2009-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Stable ohmic contacts to thin films of p-type tellurium-containing II-VI semiconductors  

SciTech Connect

A photovolatic device is described comprising: a light transmissive substrate; an electrically conductive, transparent layer disposed on the substrate as a first electrode; a layer of a first semiconductor disposed on the first electrode; a p-type thin film of a tellurium-containing II-VI semiconductor disposed on the first semiconductor to form a photoresponsive junction with it; and a second electrode contacting the thin film.

Szabo, L.F.; Biter, W.J.

1988-04-05T23:59:59.000Z

182

THE PROPERTIES OF TWO LOW-REDSHIFT O VI ABSORBERS AND THEIR ASSOCIATED GALAXIES TOWARD 3C 263 ,  

SciTech Connect

Ultraviolet observations of the QSO 3C 263 (z{sub em} = 0.652) with Cosmic Origins Spectrograph and FUSE reveal O VI absorption systems at z = 0.06342 and 0.14072. WIYN multi-object spectrograph observations provide information about the galaxies associated with the absorbers. The multi-phase system at z = 0.06342 traces cool photoionized gas and warm collisionally ionized gas associated with an L {approx} 0.31 L* compact spiral emission line galaxy with an impact parameter of 63 kpc. The cool photoionized gas in the absorber is well modeled, with log U {approx} -2.6, log N(H) {approx} 17.8, log n(H) {approx} -3.3 and [Si/H] = -0.14 {+-} 0.23. The collisionally ionized gas containing C IV and O VI probably arises in cooling shock-heated transition temperature gas with log T {approx} 5.5. The absorber is likely tracing circumgalactic gas enriched by gas ejected from the spiral emission line galaxy. The simple system at z = 0.14072 only contains O VI and broad and narrow H I. The O VI with b = 33.4 {+-} 11.9 km s{sup -1} is likely associated with the broad H I {lambda}1215 absorption, with b = 86.7 {+-} 15.4 km s{sup -1}. The difference in Doppler parameters implies the detection of a very large column of warm gas with log T = 5.61(+0.16, -0.25), log N(H) = 19.54(+0.26, -0.44), and [O/H] = -1.48 (+0.46, -0.26). This absorber is possibly associated with a 1.6 L* absorption line galaxy with an impact parameter of 617 kpc, although an origin in warm filament gas or in the halo of a fainter galaxy is more likely.

Savage, B. D.; Kim, T.-S.; Wakker, B. P. [Department of Astronomy, University of Wisconsin, Madison, WI 53706 (United States); Keeney, B.; Stocke, J.; Syphers, D. [CASA, University of Colorado, Boulder, CO (United States); Narayanan, A. [Indian Institute of Space Science and Technology, Thiruvananthapuram 695547, Kerala (India)

2012-07-01T23:59:59.000Z

183

Synthesis of Zr Doped NiO Layers on NiSi2 Linling Gu/Si-MCP Structures for Supercapacitors  

Science Conference Proceedings (OSTI)

Three-dimensional super capacitors consisting of NiSi2/silicon micro channel plates (MCPs) with Zr doped NiO layers have been fabricated. The silicon MCPs produced by electrochemical etching is utilized as a backbone of the 3D structure. Nickle layer ... Keywords: Zr doped NiO, Electrochemical properties, Silicon microchannel plate

Linling Gu; Tao Liu; Fei Wang; Shaohui Xu; Lianwei Wang; Paul K. Chu

2012-04-01T23:59:59.000Z

184

U(VI) bioreduction with emulsified vegetable oil as the electron donor-- Microcosm tests and model development  

Science Conference Proceedings (OSTI)

Microcosm tests were conducted to study U(VI) bioreduction in contaminated sediments with emulsified vegetable oil (EVO) as the electron donor. In the microcosms, EVO was degraded by indigenous microorganisms and stimulated Fe, U, and sulfate bioreduction, and methanogenesis. Removal of aqueous U occurred concurrently with sulfate reduction, with more reduction of total U in the case of higher initial sulfate concentrations. X-ray absorption near-edge spectroscopy (XANES) analysis confirmed U(VI) reduction to U(IV). As the acetate concentration peaked in 10~20 days in oleate microcosms, the maximum was reached in 100~120 days in the EVO microcosms, indicating that EVO hydrolysis was rate-limiting. The acetate accumulation was sustained over 50 days longer in the oleate and EVO than in the ethanol microcosms, suggesting that acetate-utilizing methanogenesis was slower in the cases of oleate and EVO. Both slow hydrolysis and methanogenesis could contribute to potential sustained bioreduction in field application. Biogeochemical models were developed to couple degradation of EVO, production and oxidation of long-chain fatty acids, glycerol, acetate, and hydrogen, reduction of Fe(III), U(VI) and sulfate, and methanogenesis with growth and decay of microbial functional groups. The models were used to simulate the coupled processes in a field test in a companion article.

Tang, Guoping [ORNL; Wu, Wei-min [Stanford University; Watson, David B [ORNL; Parker, Jack C. [University of Tennessee, Knoxville (UTK); Schadt, Christopher Warren [ORNL; Brooks, Scott C [ORNL; Shi, Xiaoqing [ORNL

2013-01-01T23:59:59.000Z

185

Cr(VI) adsorption on functionalized amorphous and mesoporous silica from aqueous and non-aqueous media  

Science Conference Proceedings (OSTI)

A mesoporous silica (SBA-15) and amorphous silica (SG) have been chemically modified with 2-mercaptopyridine using the homogeneous route. This synthetic route involved the reaction of 2-mercaptopyridine with 3-chloropropyltriethoxysilane prior to immobilization on the support. The resulting material has been characterized by powder X-ray diffraction, nitrogen gas sorption, FT-IR and MAS NMR spectroscopy, thermogravimetry and elemental analysis. The solid was employed as a Cr(VI) adsorbent from aqueous and non-aqueous solutions at room temperature. The effect of several variables (stirring time, pH, metal concentration and solvent polarity) has been studied using the batch technique. The results indicate that under the optimum conditions, the maximum adsorption value for Cr(VI) was 1.83 {+-} 0.03 mmol/g for MP-SBA-15, whereas the adsorption capacity of the MP-SG was 0.86 {+-} 0.02 mmol/g. On the basis of these results, it can be concluded that it is possible to modify chemically SBA-15 and SG with 2-mercaptopyridine and to use the resulting modified silicas as effective adsorbents for Cr(VI)

Perez-Quintanilla, Damian [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain)]. E-mail: damian.perez@urjc.es; Hierro, Isabel del [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Fajardo, Mariano [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Sierra, Isabel [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain)]. E-mail: isabel.sierra@urjc.es

2007-08-07T23:59:59.000Z

186

Structure of ABC Transporter MsbA in Complex with ATP Vi and  

NLE Websites -- All DOE Office Websites (Extended Search)

ABC Transporter MsbA ABC Transporter MsbA in Comlex with ATP Vi and Lipopolysaccharide: Implications for Lipid Flipping Christopher L. Reyes and Geoffrey Chang* Department of Molecular Biology, The Scripps Research Institute, 10550 N. Torrey Pines Rd. CB105, La Jolla, CA 92137 ATP-binding cassette (ABC) transporters are integral membrane proteins critical for the transport of a wide variety of substrate molecules across the cell membrane. MsbA, along with human MDR1 P-glycoprotein, are members of the ABC transporter family that have been implicated in multidrug resistance by coupling ATP binding and hydrolysis to substrate transport. This drug efflux results in resistance to antibiotics in microorganisms and resistance to chemotherapeutic drugs in human cancer cells1. Using x-ray diffraction data collected at SSRL Beam Line 11-1 and ALS, we have determined the 4.2 Å x-ray crystal structure of MsbA in complex with transition state mimic ADP, vanadate (an analog of the g phosphate of ATP) and the human immunomodulatory substrate Ra lipopolysaccharide. This structure is the first intact ABC transporter in complex with nucleotide and substrate.

187

Coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides  

SciTech Connect

We show that inversion symmetry breaking together with spin-orbit coupling leads to coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides, making possible controls of spin and valley in these 2D materials. The spin-valley coupling at the valence band edges suppresses spin and valley relaxation, as flip of each index alone is forbidden by the 0.1 eV valley contrasting spin splitting. Valley Hall and spin Hall effects coexist in both electron-doped and hole-doped systems. Optical interband transitions have frequency-dependent polarization selection rules which allow selective photoexcitation of carriers with various combination of valley and spin indices. Photo-induced spin Hall and valley Hall effects can generate long lived spin and valley accumulations on sample boundaries. The physics discussed here provides a route towards the integration of valleytronics and spintronics in multi-valley materials with strong spin-orbit coupling and inversion symmetry breaking.

Xiao, Di [ORNL; Liu, G. B. [University of Hong Kong, The; Feng, wanxiang [Chinese Academy of Sciences; Xu, Xiaodong [University of Washington; Yao, Wang [University of Hong Kong, The

2012-01-01T23:59:59.000Z

188

Methods for forming thin-film heterojunction solar cells from I-III-VI{sub 2}  

DOE Patents (OSTI)

An improved thin-film, large area solar cell, and methods for forming the same are disclosed, having a relatively high light-to-electrical energy conversion efficiency and characterized in that the cell comprises a p-n type heterojunction formed of: (i) a first semiconductor layer comprising a photovoltaic active material selected from the class of I-III-VI{sub 2} chalcopyrite ternary materials which is vacuum deposited in a thin ``composition-graded`` layer ranging from on the order of about 2.5 microns to about 5.0 microns ({approx_equal}2.5 {mu}m to {approx_equal}5.0 {mu}m) and wherein the lower region of the photovoltaic active material preferably comprises a low resistivity region of p-type semiconductor material having a superimposed region of relatively high resistivity, transient n-type semiconductor material defining a transient p-n homojunction; and (ii) a second semiconductor layer comprising a low resistivity n-type semiconductor material; wherein interdiffusion occurs (a) between the elemental constituents of the two discrete juxtaposed regions of the first semiconductor layer defining a transient p-n homojunction layer, and (b) between the transient n-type material in the first semiconductor layer and the second n-type semiconductor layer. 16 figs.

Mickelsen, R.A.; Chen, W.S.

1985-08-13T23:59:59.000Z

189

Methods for forming thin-film heterojunction solar cells from I-III-VI[sub 2  

DOE Patents (OSTI)

An improved thin-film, large area solar cell, and methods for forming the same are disclosed, having a relatively high light-to-electrical energy conversion efficiency and characterized in that the cell comprises a p-n type heterojunction formed of: (1) a first semiconductor layer comprising a photovoltaic active material selected from the class of I-III-VI[sub 2] chalcopyrite ternary materials which is vacuum deposited in a thin composition-graded'' layer ranging from on the order of about 2.5 microns to about 5.0 microns ([approx equal]2.5[mu]m to [approx equal]5.0[mu]m) and wherein the lower region of the photovoltaic active material preferably comprises a low resistivity region of p-type semiconductor material having a superimposed region of relatively high resistivity, transient n-type semiconductor material defining a transient p-n homojunction; and (2), a second semiconductor layer comprising a low resistivity n-type semiconductor material; wherein interdiffusion (a) between the elemental constituents of the two discrete juxtaposed regions of the first semiconductor layer defining a transient p-n homojunction layer, and (b) between the transient n-type material in the first semiconductor layer and the second n-type semiconductor layer, is allowed.

Mickelsen, R.A.; Chen, W.S.

1982-06-15T23:59:59.000Z

190

Methods for forming thin-film heterojunction solar cells from I-III-VI.sub. 2  

DOE Patents (OSTI)

An improved thin-film, large area solar cell, and methods for forming the same, having a relatively high light-to-electrical energy conversion efficiency and characterized in that the cell comprises a p-n type heterojunction formed of: (i) a first semiconductor layer comprising a photovoltaic active material selected from the class of I-III-VI.sub.2 chalcopyrite ternary materials which is vacuum deposited in a thin "composition-graded" layer ranging from on the order ot about 2.5 microns to about 5.0 microns (.congruent.2.5 .mu.m to .congruent.5.0 .mu.m) and wherein the lower region of the photovoltaic active material preferably comprises a low resistivity region of p-type semiconductor material having a superimposed region of relatively high resistivity, transient n-type semiconductor material defining a transient p-n homojunction; and (ii), a second semiconductor layer comprising a low resistivity n-type semiconductor material; wherein interdiffusion (a) between the elemental constituents of the two discrete juxtaposed regions of the first semiconductor layer defining a transient p-n homojunction layer, and (b) between the transient n-type material in the first semiconductor layer and the second n-type semiconductor layer, causes the The Government has rights in this invention pursuant to Contract No. EG-77-C-01-4042, Subcontract No. XJ-9-8021-1 awarded by the U.S. Department of Energy.

Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

1985-01-01T23:59:59.000Z

191

Methods for forming thin-film heterojunction solar cells from I-III-VI.sub. 2  

DOE Patents (OSTI)

An improved thin-film, large area solar cell, and methods for forming the same, having a relatively high light-to-electrical energy conversion efficiency and characterized in that the cell comprises a p-n type heterojunction formed of: (i) a first semiconductor layer comprising a photovoltaic active material selected from the class of I-III-VI.sub.2 chalcopyrite ternary materials which is vacuum deposited in a thin "composition-graded" layer ranging from on the order of about 2.5 microns to about 5.0 microns (.congruent.2.5.mu.m to .congruent.5.0.mu.m) and wherein the lower region of the photovoltaic active material preferably comprises a low resistivity region of p-type semiconductor material having a superimposed region of relatively high resistivity, transient n-type semiconductor material defining a transient p-n homojunction; and (ii), a second semiconductor layer comprising a low resistivity n-type semiconductor material; wherein interdiffusion (a) between the elemental constituents of the two discrete juxtaposed regions of the first semiconductor layer defining a transient p-n homojunction layer, and (b) between the transient n-type material in the first semiconductor layer and the second n-type semiconductor layer, causes the transient n-type material in The Government has rights in this invention pursuant to Contract No. EG-77-C-01-4042, Subcontract No. XJ-9-8021-1 awarded by the U.S. Department of Energy.

Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

1982-01-01T23:59:59.000Z

192

NiO as a peculiar support for metal nanoparticles in polyols oxidation  

SciTech Connect

The peculiar influence of a NiO support was studied by preparing gold catalysts supported on NiO(1-x) TiO2(x) mixed oxides. PVA protected Au nanoparticles showed high activity when supported on NiO for the selective oxidation of glycerol and ethan-1,2-diol. A detailed characterization of the resulting Au catalysts revealed a preferential deposition of the metal nanoparticles on the NiO phase. However, the activity of Au on NiO(1-x)-TiO2(x) decreased with respect to pure NiO and the selectivity evolved with changes to the support.

Villa, Alberto [Universita di Milano, Italy; Veith, Gabriel M [ORNL; Ferri, Davide [EMPA, Laboratory for High Performance Ceramics, Duebendorf, Switzerland; Weidenkaff, Anke [EMPA, Laboratory for High Performance Ceramics, Duebendorf, Switzerland; Perry, Kelly A [ORNL; Campisi, Sebastiano [University of Milan and INFN, Milano, Italy; Prati, Laura [Universita di Milano, Italy

2013-01-01T23:59:59.000Z

193

Diffusion bonding of commercially pure Ni using Cu interlayer  

Science Conference Proceedings (OSTI)

The concentration dependence of diffusivity in a multi-component diffusion system makes it complicated to predict the concentration profiles of diffusing species. This so called chemical diffusivity can be expressed as a function of thermodynamic and kinetic data. DICTRA software can calculate the concentration profiles using appropriate mobility and thermodynamic data. It can also optimize the diffusivity data using experimental diffusivity data. Then the optimized diffusivity data is stored as mobility data which is a linear function of temperature. In this work, diffusion bonding of commercially pure Ni using Cu interlayers is reported. The mobility parameters of Ni-Cu alloy binary systems were optimized using DICTRA/Thermocalc software from the available self-, tracer and chemical diffusion coefficients. The optimized mobility parameters were used to simulate concentration profiles of Ni-Cu diffusion joints using DICTRA/Thermocalc software. The calculated and experimental concentration profiles agreed well at 1100 Degree-Sign C. Agreement between the simulated and experimental profiles was less good at 1050 Degree-Sign C due to the grain boundary contribution to the overall diffusion. - Highlights: Black-Right-Pointing-Pointer The concentration profiles of Cu in Ni-Cu diffusion joints are modeled. Black-Right-Pointing-Pointer Interdiffusion coefficients in Ni-Cu system are optimized. Black-Right-Pointing-Pointer Optimized interdiffusion coefficients are expressed as mobility parameters. Black-Right-Pointing-Pointer Simulated profiles are comparable with experimental profiles.

Rahman, A.H.M.E., E-mail: a.rahman@my.und.edu; Cavalli, M.N.

2012-07-15T23:59:59.000Z

194

Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin  

Science Conference Proceedings (OSTI)

Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

2011-02-28T23:59:59.000Z

195

Superlubricity through graphene multilayers between Ni(111) surfaces  

E-Print Network (OSTI)

A single graphene layer placed between two parallel Ni(111) surfaces screens the strong attractive force and results in a significant reduction of adhesion and sliding friction. When two graphene layers are inserted, each graphene is attached to one of the metal surfaces with a significant binding and reduces the adhesion further. In the sliding motion of these surfaces the transition from stick-slip to continuous sliding is attained, whereby non-equilibrium phonon generation through sudden processes is suppressed. The adhesion and corrugation strength continues to decrease upon insertion of the third graphene layer and eventually saturates at a constant value with increasing number of graphene layers. In the absence of Ni surfaces, the corrugation strength of multilayered graphene is relatively higher and practically independent of the number of layers. Present first-principles calculations reveal the superlubricant feature of graphene layers placed between pseudomorphic Ni(111) surfaces, which is achieved t...

Cahangirov, S; zelik, V Ongun

2013-01-01T23:59:59.000Z

196

Monte Carlo Simulations of Segregation in Pt-Ni Catalyst Nanoparticles  

E-Print Network (OSTI)

of Segregation in Pt-Ni Catalyst Nanoparticles Guofengsurface chemistry of catalyst nanoparticles (also called "Pt-Ni alloy is an electro-catalyst of interest in the air

Wang, Guofeng; Van Hove, Michel A.; Ross, Philip N.; Baskes, M.I.

2004-01-01T23:59:59.000Z

197

CoNiFe Alloy Powder Synthesis by High Energy Milling  

Science Conference Proceedings (OSTI)

CoNiFe alloy powder was synthesized by high energy milling of mixtures of Co, Ni and Fe powder as a bulk processing method for producing powder. A milling...

198

The Effect of Pellet Geometry on The Specific Activity of Ni-63.  

E-Print Network (OSTI)

?? 63Ni [Nickel-63] is routinely produced at HFIR with a specific activity of ~15 Ci/g [Curies/gram] by irradiating highly enriched stable 62Ni [Nickel-62] (86.31 %) (more)

Walsh, Spenser Riley

2013-01-01T23:59:59.000Z

199

Effect of amorphous Mg{sub 50}Ni{sub 50} on hydriding and dehydriding behavior of Mg{sub 2}Ni alloy  

SciTech Connect

Composite Mg{sub 2}Ni (25 wt.%) amorphous Mg{sub 50}Ni{sub 50} was prepared by mechanical milling starting with nanocrystalline Mg{sub 2}Ni and amorphous Mg{sub 50}Ni{sub 50} powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg{sub 50}Ni{sub 50} improved the hydriding and dehydriding kinetics of Mg{sub 2}Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: {yields} First study of the hydriding behavior of composite Mg{sub 2}Ni (25 wt.%) amorphous Mg{sub 50}Ni{sub 50}. {yields} Microstructural characterization of composite material using XRD and SEM was obtained. {yields} An improved effect of Mg{sub 50}Ni{sub 50} on the Mg{sub 2}Ni hydriding behavior was verified. {yields} The apparent activation energy for the hydrogen desorption of composite was obtained.

Guzman, D., E-mail: danny.guzman@uda.cl [Departamento de Ingenieria en Metalurgia, Facultad de Ingenieria, Universidad de Atacama y Centro Regional de Investigacion y Desarrollo Sustentable de Atacama (CRIDESAT), Av. Copayapu 485, Copiapo (Chile); Ordonez, S. [Departamento de Ingenieria Metalurgica, Facultad de Ingenieria, Universidad de Santiago de Chile, Av. Lib. Bernardo O'Higgins 3363, Santiago (Chile); Fernandez, J.F.; Sanchez, C. [Departamento de Fisica de Materiales, Facultad de Ciencias, Universidad Autonoma de Madrid, Cantoblanco 28049, Madrid (Spain); Serafini, D. [Departamento de Fisica, Facultad de Ciencias, Universidad de Santiago de Chile and Center for Interdisciplinary Research in Materials, CIMAT, Av. Lib. Bernardo O'Higgins 3363, Santiago (Chile); Rojas, P.A. [Escuela de Ingenieria Mecanica, Facultad de Ingenieria, Av. Los Carrera 01567, Quilpue, Pontificia Universidad Catolica de Valparaiso, PUCV (Chile); Aguilar, C. [Departamento de Ingenieria Metalurgica y Materiales, Universidad Tecnica Federico Santa Maria, Av. Espana 1680, Valparaiso (Chile); Tapia, P. [Departamento de Ingenieria en Metalurgia, Facultad de Ingenieria, Universidad de Atacama, Av. Copayapu 485, Copiapo (Chile)

2011-04-15T23:59:59.000Z

200

Single-step Precipitation of Ni Nanoparticle Catalyst on Zeolite and ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Ni nanoparticle catalyst was prepared on zeolite (pores size: 2 production rate from the methanol stream reforming reaction...

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Oxygen Reduction Activity of PtxNi1-x Alloy Nanoparticles on Multiwall Carbon Nanotubes  

E-Print Network (OSTI)

PtxNi1 - x nanoparticles (Pt:Ni; 1:0, 4:1, 3:1 and 0.7:1) of ~5 nm, were synthesized on carboxylic acid-functionalized multiwall carbon nanotubes (PtxNi1 - x NPs/MWNT). The oxygen reduction reaction (ORR) activity measurements ...

Kim, Junhyung

202

Improved thermal stability of Ni-silicides on Si: C epitaxial layers  

Science Conference Proceedings (OSTI)

The thermal stability of Ni-silicides on tensily strained in situ P doped Si:C epitaxial layers was evaluated. The baseline Ni silicidation process was shown to be compatible with Si:C Recessed Source-Drain (RSD) stressors for NMOS strain engineering ... Keywords: Epitaxy, Ni, SiC stressors, Silicide, Thermal stability

V. Machkaoutsan; S. Mertens; M. Bauer; A. Lauwers; K. Verheyden; K. Vanormelingen; P. Verheyen; R. Loo; M. Caymax; S. Jakschik; D. Theodore; P. Absil; S. G. Thomas; E. H. A. Granneman

2007-11-01T23:59:59.000Z

203

First principles study of Li diffusion in I-Li_{2}NiO_{2} structure  

E-Print Network (OSTI)

First principles computations have been used to study Li mobility in the orthorhombic Li2NiO2 structure with the Immm space group (I-Li2NiO2). Understanding Li mobility in I-Li2NiO2 structure other than the conventional ...

Ceder, Gerbrand

204

Preparation and Hydrogen storage properties of Mg-rich Mg-Ni ultrafine particles  

Science Conference Proceedings (OSTI)

In the present work, Mg-rich Mg-Ni ultrafine powders were prepared through an arc plasma method. The phase components, microstructure, and hydrogen storage properties of the powders were carefully investigated. It is found that Mg2Ni and MgNi2 ...

Jianxin Zou, Haiquan Sun, Xiaoqin Zeng, Gang Ji, Wenjiang Ding

2012-01-01T23:59:59.000Z

205

Stress evolution during Ni-Si compound formation for fully silicided (FUSI) gates  

Science Conference Proceedings (OSTI)

The stress (force) evolution during the formation of different Ni silicide phases was monitored by in situ curvature measurements, for the reaction of thin Ni films of various thicknesses with 100nm polycrystalline-Si deposited on oxidized (100) Si substrates. ... Keywords: In situ XRD, In situ curvature measurements, Ni-silicides

C. Torregiani; C. Van Bockstael; C. Detavernier; C. Lavoie; A. Lauwers; K. Maex; J. A. Kittl

2007-11-01T23:59:59.000Z

206

Microstructure and Corrosion Resistance of Pulse Electroplated Ni/nano-Al2O3 Composite Coatings  

Science Conference Proceedings (OSTI)

The Ni/nano-Al2O3 composite coatings were prepared by pulse electro-plating. The experiments of corrosion resistance were carried for 304 stainless steel, pure Ni coating and Ni/nano-Al2O3 composite coating in 3.5% NaCl and 10% HCl solutions. The microstrcuture ... Keywords: pulse electro-plating, composite coating, microhardness, corrosion resistance

Hu Bin-Liang, Tan Yuan-Qiang

2012-07-01T23:59:59.000Z

207

Permeability reduction mechanisms involved in in-situ gelation of a polyacrylamide/chromium (VI)/thiourea system  

SciTech Connect

In this paper an investigation of the in-situ gelation of a polyacrylamide/chromium(VI)/thiourea system under flow conditions in unconsolidated sandpacks is presented. High flow resistance was observed in a localized section of the sandpacks that was consistent with deep-bed filtration mechanisms. A method to measure the size of aggregates in gel solution is also presented. Results from this method showed that the gel aggregates grow with reaction time and distance traveled through the sandpack, supporting the conclusion that filtration is a dominant factor in the in-situ gelation process under flow conditions.

McCool, C.S.; Green, D.W.; Willhits, G.P. (University of Kansas, KS (US))

1991-02-01T23:59:59.000Z

208

Remediation of Cr(VI) by biogenic magnetic nanoparticles: An x-ray magnetic circular dichroism study  

SciTech Connect

Biologically synthesized magnetite (Fe{sub 3}O{sub 4}) nanoparticles are studied using x-ray absorption and x-ray magnetic circular dichroism following exposure to hexavalent Cr solution. By examining their magnetic state, Cr cations are shown to exist in trivalent form on octahedral sites within the magnetite spinel surface. The possibility of reducing toxic Cr(VI) into a stable, non-toxic form, such as a Cr{sup 3+}-spinel layer, makes biogenic magnetite nanoparticles an attractive candidate for Cr remediation.

Telling, N. D.; Coker, V. S.; Cutting, R. S.; van der Laan, G.; Pearce, C. I.; Pattrick, R. A. D.; Arenholz, E.; Lloyd, J. R.

2009-09-04T23:59:59.000Z

209

Stress-induced martensitic transformations in NiTi and NiTi-TiC composites investigated by neutron diffraction  

SciTech Connect

Superelastic NiTi (51.0 at% Ni) with 0, 10 and 20 vol% TiC particles were deformed under uniaxial compression as neutron diffraction spectra were simultaneously obtained. The experiments yielded in-situ measurements of the thermoelastic stress-induced transformation. A detailed Rietveld determination is made of the phase fractions and the evolving strains in the reinforcing TiC particles and the austenite as it transforms to martensite on loading (and its subsequent back transformation on unloading). These strains are used to shed light on the phenomenon of load transfer in composites where the matrix undergoes a stress-induced phase transformation.

Vaidyanathan, R. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Materials Science and Engineering; Bourke, M.A.M. [Los Alamos National Lab., NM (United States); Dunand, D.C. [Northwestern Univ., Evanston, IL (United States)

1998-12-31T23:59:59.000Z

210

INVESTIGATION OF NOVEL ALLOY TiC-Ni-Ni3Al FOR SOLID OXIDE FUEL CELL INTERCONNECT APPLICATIONS  

DOE Green Energy (OSTI)

Solid oxide fuel cell interconnect materials must meet stringent requirements. Such interconnects must operate at temperatures approaching 800 C while resisting oxidation and reduction, which can occur from the anode and cathode materials and the operating environment. They also must retain their electrical conductivity under these conditions and possess compatible coefficients of thermal expansion as the anode and cathode. Results are presented in this report for fuel cell interconnect candidate materials currently under investigation based upon nano-size titanium carbide (TiC) powders. The TiC is liquid phase sintered with either nickel (Ni) or nickel-aluminide (Ni{sub 3}Al) in varying concentrations. The oxidation resistance of the submicron grain TiC-metal materials is presented as a function weight change versus time at 700 C and 800 C for varying content of metal/intermetallic in the system. Electrical conductivity at 800 C as a function of time is also presented for TiC-Ni to demonstrate the vitality of these materials for interconnect applications. TGA studies showed that the weight gain was 0.8 mg/cm{sup 2} for TiC(30)-Ni(30wt.%) after 100 hours in wet air at 800 C and the weight gain was calculated to be 0.5205 mg/cm{sup 2} for TiC(30)- Ni(10 wt.%) after 100 hours at 700 C and 100 hours at 800 C. At room temperature the electrical conductivity was measured to be 2444 1/[ohm.cm] for TiC-Ni compositions. The electrical conductivities at 800 C in air was recorded to be 19 1/[ohm.cm] after 125 hours. Two identical samples were supplied to PNNL (Dr. Jeff Stevenson) for ASR testing during the pre-decision period and currently they are being tested there. Fabrication, oxidation resistance and electrical conductivity studies indicate that TiC-Ni-Ni{sub 3}Al ternary appears to be a very important system for the development of interconnect composition for solid oxide fuel cells.

Rasit Koc; Geoffrey Swift; Hua Xie

2005-01-25T23:59:59.000Z

211

Mechanical, Electrical, and Magnetic Properties of Ni Nanocontacts  

Science Conference Proceedings (OSTI)

The dynamic deformation upon stretching of Ni nanowires as those formed with mechanically controllable break junctions or with a scanning tunneling microscope is studied both experimentally and theoretically. Molecular dynamics simulations of the breaking ... Keywords: Ab initio, ab initio, conductance, nanocontacts, spintronics

M. R. Calvo; M. J. Caturla; D. Jacob; C. Untiedt; J. J. Palacios

2008-03-01T23:59:59.000Z

212

Molecular Dynamics Simulation of Reactions Forming Ni-Al ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Alloying reactions of a Ni-coated Al nanoparticle, Al-coated ... Atomistic Modeling of Screw Dislocation Mobility in Alpha-Fe ... Mesoscale Polycrystal Calculations of Damage Histories in Shock Loaded Metals ... Multi- time Scale Modeling of the Annealing of Radiation-Induced Defects at Tilt Grain Boundaries.

213

Electron Phonon Superconductivity in LaNiPO  

Science Conference Proceedings (OSTI)

We report first principles calculations of the electronic structure, phonon dispersions and electron phonon coupling of LaNiPO. These calculations show that this material can be explained as a conventional electron phonon superconductor in contrast to theFeAs based high temperature superconductors.

Subedi, Alaska P [ORNL; Singh, David J [ORNL; Du, Mao-Hua [ORNL

2008-01-01T23:59:59.000Z

214

In situ oxidation of ultrathin silver films on Ni(111)  

Science Conference Proceedings (OSTI)

Oxidation of silver films of one- and two-monolayer thicknesses on the Ni(111) surface was investigated by low-energy electron microscopy at temperatures of 500 and 600 K. Additionally, intensity--voltage curves were measured in situ during oxidation ...

A. Meyer; J. I. Flege; S. D. Senanayake; B. Kaemena; R. E. Rettew; F. M. Alamgir; J. Falta

2011-07-01T23:59:59.000Z

215

Microwave-Assisted Synthesis of II-VI Semiconductor Micro- and Nanoparticles towards Sensor Applications  

E-Print Network (OSTI)

Engineering particles at the nanoscale demands a high degree of control over process parameters during synthesis. For nanocrystal synthesis, solution-based techniques typically include application of external convective heat. This process often leads to slow heating and allows decomposition of reagents or products over time. Microwave-assisted heating provides faster, localized heating at the molecular level with near instantaneous control over reaction parameters. In this work, microwave-assisted heating has been applied for the synthesis of II-VI semiconductor nanocrystals namely, ZnO nanopods and CdX (X = Se, Te) quantum dots (QDs). Based on factors such as size, surface functionality and charge, optical properties of such nanomaterials can be tuned for application as sensors. ZnO is a direct bandgap semiconductor (3.37 eV) with a large exciton binding energy (60 meV) leading to photoluminescence (PL) at room temperature. A microwave-assisted hydrothermal approach allows the use of sub-5 nm ZnO zero-dimensional nanoparticles as seeds for generation of multi-legged quasi one-dimensional nanopods via heterogeneous nucleation. ZnO nanopods, having individual leg diameters of 13-15 nm and growing along the [0001] direction, can be synthesized in as little as 20 minutes. ZnO nanopods exhibit a broad defect-related PL spanning the visible range with a peak at ~615 nm. Optical sensing based on changes in intensity of the defect PL in response to external environment (e.g., humidity) is demonstrated in this work. Microwave-assisted synthesis was also used for organometallic synthesis of CdX(ZnS) (X = Se, Te) core(shell) QDs. Optical emission of these QDs can be altered ased on their size and can be tailored to specific wavelengths. Further, QDs were incorporated in Enhanced Green-Fluorescent Protein Ultrabithorax (EGFP-Ubx) fusion protein for the generation of macroscale composite protein fibers via hierarchal self-assembly. Variations in EGFP- UbxQD composite fiber surface morphology and internal QD distribution were studied with respect to (i) time of QD addition (i.e., pre or post protein self-assembly) and (ii) QD surface charge negatively charged QDs with dihydrolipoic acid functionalization and positively charged QDs with polyethyleneimine coating. Elucidating design motifs and understanding factors that impact the protein-nanoparticle interaction enables manipulation of the structure and mechanical properties of composite materials.

Majithia, Ravish

2013-05-01T23:59:59.000Z

216

Continuous spin reorientation transition in epitaxially grown antiferromagnetic NiO thin films  

SciTech Connect

Fe/NiO/MgO/Ag(001) films were grown epitaxially, and the Fe and NiO spin orientations were determined using x-ray magnetic dichroism. We find that the NiO spins are aligned perpendicularly to the in-plane Fe spins. Analyzing both the in-plane and out-of-plane spin components of the NiO layer, we demonstrate unambiguously that the antiferromagnetic NiO spins undergo a continuous spin reorientation transition from the in-plane to out-of-plane directions with increasing of the MgO thickness.

Li, J.; Arenholz, E.; Meng, Y.; Tan, A.; Park, J.; Jin, E.; Son, H.; Wu, J.; Jenkins, C. A.; Scholl, A.; Hwang, Chanyong; Qiu, Z. Q.

2011-03-01T23:59:59.000Z

217

Effect of Aging Heat Treatments on Ni52Ti48 Shape Memory Alloy  

E-Print Network (OSTI)

Ni-rich NiTi shape memory alloys (SMAs) are capable of attaining a wide range of transformation temperatures depending on the heat treatment conditions and superior thermo-mechanical cycling stability, which are desired for repeated solid-state actuation. High Ni-content Ni-rich SMAs have very low transformation temperatures in a solutionized condition due to the high Ni-content of the matrix. Slow cooling (furnacecooling) from solutionizing temperature and additional aging heat treatments result in the formation of Ni-rich precipitates such as Ni4Ti3, Ni3Ti2 and Ni3Ti and increase transformation temperatures above ambient by depleting excess Ni from the matrix. However, the precipitates do not undergo a martensitic phase transformation and they decrease the transformation strain by reducing the volume fraction of the material capable of transforming. Meanwhile, recent preliminary work shows that Ni3Ti precipitates dominate fatigue failure. The objectives of the present study are: (1) to eliminate Ni3Ti but still have Ni4Ti3 precipitates, which are responsible for the dimensional stability and increase transformation temperatures, (2) to investigate the effect of heat treatments on the transformation strain, and (3) to select single variant Ni4Ti3 precipitates through constrained aging for the formation of oriented internal stress and eventually obtain twoway shame memory effect (TWSME) and enhanced dimensional stability. Based on these objectives, the effect of aging heat treatment on transformation temperatures, microstructural evolution, and shape memory behavior were investigated for a Ni52Ti48 shape memory alloy (SMA) by using differential scanning calorimetry (DSC), optical microscopy, scanning electron microscopy (SEM), and thermo-mechanical testing, including isobaric heating-cooling experiments under various stress levels. It was observed that solutionizing at 900 degree C for 24 hours eliminated Ni3Ti type precipitates, but additional aging heat treatments are needed to form Ni4Ti3 precipitates to increase transformation temperatures. Furnace-cooling and additional aging heat treatment results in the multi-stage martensitic transformation due to chemical and stress inhomogeneities in the microstructure. Aging of the controlled furnace-cooled material at 400 degree C for 48 hours resulted in the highest transformation temperatures among all processing conditions investigated due to the combination of Ni3Ti precipitates and 27 percent volume fraction of the Ni4Ti3 precipitates, which led to the depletion of Ni from the transforming matrix. However, since overaging results in losing coherency of the precipitates, dimensional stability during isobaric thermal cycling was negatively impacted.

Akin, Erhan

2010-08-01T23:59:59.000Z

218

Observation of lines above 2000 A in O VIII and C VI in the Princeton Large Torus due to charge-exchange processes: Diagnostic applications  

DOE Green Energy (OSTI)

Hydrogenlike oxygen and carbon lines from transitions (..delta..n = 1) between levels of high principal quantum number n, with wavelengths above 2000 A have been observed. Observations of such transitions were possible due to charge-exchange processes during neutral beam injection of hydrogen atoms into the Princeton Large Torus tokamak. The lines are O VIII 2976 A (8--7 transitions), C VI 3434 A (7--6), and C VI 5291 A (8--7). Application of these lines for ion temperature measurements and initial observations of neutral beam vertical distributions in the plasma are presented.

Suckewer, S.; Skinner, C.H.; Stratton, B.; Bell, R.; Cavallo, A.; Hosea, J.; Hwang, D.; Schilling, G.

1984-08-01T23:59:59.000Z

219

Extraction of Th(IV) and U(VI) by dihexyl-N,N-diethylcarbamoylmethylphosphonate from aqueous nitrate media  

SciTech Connect

The extraction behavior of Th(IV) and U(VI) from nitrate media was studied using relatively pure dihexyl-N,N-diethylcarbamoylmethylphosphonate (DHDECMP). The data were compared with analogous measurements obtained with dibutyl butylphosphonate (DB(BP)). It was found that the extractant dependency is second power for U(VI) with both DHDECMP and DB(BP). However, the extractant dependency for Th(IV) is third power for DB(BP) but varied from 2.5 to 2.0 power for DHDECMP depending on the total nitrate concentration. The K/sub d/ data do not support the theory that DHDECMP is an effective chelating agent for actinide ions. Significant differences between DHDECMP and DB(BP) do appear in the extraction behavior of Th(IV) from 1 to 5 M HNO/sub 3/. These differences are explained by the ability of DHDECMP to buffer itself against the effects of HNO/sub 3/ by protonation of the amide group.

Horwitz, E.P.; Kalina, D.G.; Muscatello, A.C.

1981-05-01T23:59:59.000Z

220

First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions  

SciTech Connect

We investigate the structure and surface composition of the {gamma}{prime}-Ni{sub 3}Al(111) and {beta}-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel-aluminum alloys are protected by an oxide scale, but in case of oxide scale spallation, the alloy surface may be directly exposed to the reactive gas environment and vulnerable to metal dusting. By means of density functional theory and thermochemical calculations for both the Ni{sub 3}Al and NiAl surfaces, the conditions under which CO and OH adsorption is to be expected and under which it is inhibited, are mapped out. Because CO and OH are regarded as precursors for nucleating graphite or oxide on the surfaces, phase diagrams for the surfaces provide a simple description of their stability. Specifically, this study shows how the CO and OH coverages depend on the steam to carbon ratio (S/C) in the gas and thereby provide a ranking of the carbon limits on the different surface phases.

Saadi, Souheil

2011-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Calculation of thermodynamic, electronic, and optical properties of monoclinic Mg2NiH4  

DOE Green Energy (OSTI)

Ab initio total-energy density functional theory is used to investigate the low temperature (LT) monoclinic form of Mg2NiH4. The calculated minimum energy geometry of LT Mg2NiH4 is close to that determined from neutron diffraction data, and the NiH4 complex is close to a regular tetrahedron. The enthalpies of the phase change to high temperature (HT) pseudo-cubic Mg2NiH4 and of hydrogen absorption by Mg2Ni are calculated and compared with experimental values. LT Mg2NiH4 is found to be a semiconductor with an indirect band gap of 1.4 eV. The optical dielectric function of LT Mg2NiH4 differs somewhat from that of the HT phase. A calculated thin film transmittance spectrum is consistent with an experimental spectrum.

Myers, W.R.; Richardson, T.J.; Rubin, M.D.; Wang, L-W.

2001-10-01T23:59:59.000Z

222

Synthesis, electrochemistry, and spectroscopic properties of six-coordinate monooxomolybdenum(VI) complexes containing tridentate Schiff base and bidentate catecholate ligands. Crystal and molecular structure of (N-salicylidene-2-aminophenolato)(naphthalene-2,3-diolato)oxomolybdenum(VI)  

SciTech Connect

Six-coordinate monooxomolybdenum(VI) complexes, MoO(cat)(Sap), where Sap/sup 2 -/ = the Schiff base dianion N-salicylidene-2-aminophenolate and cat/sup 2 -/ = catecholate Cat/sup 2 -/, naphthalene-2,3-diolate (Naphcat/sup 2 -/), or 3,5-di-tert-butylcatecholate (DTBcat/sup 2 -/), are prepared by reacting the Mo(VI) dimer. (MoO/sub 2/(Sap))/sub 2/, with the appropriate catechol. The products are characterized by cyclic voltammetry, mass spectrometry, and uv/vis, ir, and /sup 95/Mo NMR spectroscopy. The MoO(cat)(Sap) complexes represent the first examples of a mononuclear MoO/sup 4 +/ center with a coordination number of six. The crystal structure of the MoO-(Naphcat)(Sap) derivative is reported, confirming the six-coordinate, distorted octahedrla environment about Mo(VI). Bond angles in the coordination group deviate from the ideal value of 90/degrees/ as a consequence of the ligand bite constraints and because all four O-Mo-O angles involving the terminal oxo ligand are larger than the ideal 90/degrees/ value. MoO(cat)(Sap) complexes undergo reversible one-electronic reduction at -0.5 to -0.7 V versus Fc /sup +/0/ followed by irreversible one-electron reduction at -1.6 to -1.9 V. Reversible MoO/sup 4 +//MoO/sup 3 +/ electrochemistry is attributed to the fact that the Mo d/sub xy/orbital of MoO(cat)(Sap) can be singly occupied upon reduction to Mo(V) without unfavorable interaction with the four bonds in its equatorial plane. This contrasts with the irreversible electrochemical behavior of seven-coordinate MoO/sup 4 +/ complexes, which contain five such bonds. The /sup 95/Mo NMR chemical shift of MoO(Naphcat)(Sap) is +385 ppM versus external molybdate; this value is highly deshielded with respect to seven-coordinate MoO/sup 4 +/ and six-coordinate MoO/sub 2//sup 2 +/ complexes with O and N donors. 35 references, 4 figures, 5 tables.

Mondal, J.U.; Schultz, F.A.; Brennan, T.D.; Scheidt, W.R.

1988-11-02T23:59:59.000Z

223

SaVi: satellite constellation visualization Research Fellow, Centre for Communication Systems Research at the University of Surrey, e-mail: L.Wood@surrey.ac.uk  

E-Print Network (OSTI)

Command Language (Tcl). This two-pronged approach allows SaVi to be scriptable. Simple, short, Tcl scripts to the scripts of the network simulator ns-2, which also relies on Tcl. Many scripts simulating, illustrating is presented in Tcl's Toolkit, Tk, which complements Tcl and allows for relatively straightforward creation

Wood, Lloyd

224

Quest for Environmentally-Benign Ligands for Actinide Separations: Thermodynamic, Spectroscopic, and Structural Characterization of U(VI) Complexes with Oxa-Diamide and Related Ligands  

SciTech Connect

Complexation of U(VI) with N,N,N{prime},N{prime}-tetramethyl-3-oxa-glutaramide (TMOGA) and N,N-dimethyl-3-oxa-glutaramic acid (DMOGA) was studied in comparison with their dicarboxylate analog, oxydiacetic acid (ODA). Thermodynamic parameters, including stability constants, enthalpy and entropy of complexation, were determined by spectrophotometry, potentiometry and calorimetry. Single-crystal X-ray diffractometry, EXAFS spectroscopy, FT-IR absorption and laser-induced luminescence spectroscopy were used to obtain structural information on the U(VI) complexes. Like ODA, TMOGA and DMOGA form tridentate U(VI) complexes, with three oxygen atoms (the amide, ether and/or carboxylate oxygen) coordinating to the linear UO{sub 2}{sup 2+} cation via the equatorial plane. The stability constants, enthalpy and entropy of complexation all decrease in the order ODA > DMOGA > TMOGA, showing that the complexation is entropy driven and the substitution of a carboxylate group with an amide group reduces the strength of complexation with U(VI) due to the decrease in the entropy of complexation. The trend in the thermodynamic stability of the complexes correlates very well with the structural and spectroscopic data obtained by single crystal XRD, FT-IR and laser-induced luminescence spectroscopy.

Advanced Light Source; Tian, Guoxin; Rao, Linfeng; Teat, Simon J.; Liu, Guokui

2009-01-05T23:59:59.000Z

225

Auxiliary Ligand-Dependent Assembly of Several Ni/Ni-Cd Compounds with N2O2 Donor Tetradentate Symmetrical Schiff Base Ligand  

DOE Green Energy (OSTI)

Several low-dimensional Ni/Ni-Cd complexes containing N2O2 donor tetradentate symmetrical Schiff base ligand bis(acetylacetone)ethylene-diamine (sy-H2L2), namely, [Ni(sy-L2)]2?HLa?ClO4 (2), (HLa)2?(ClO4)?(NO3) (3), [Ni(sy-L2)X]2](4,4-bipy) (where La = 5,7-dimethyl-3,6-dihydro-2H-1,4-diazepine, X = ClO4 (4), X=NO3 (5), [Ni(sy-L2)Cd(SCN)2]n (6) and [Ni(sy-L2)?Cd(N3)2]n (7) have been synthesized from [Ni(sy-L2)]2?H2O (1). Complex 2, is three component discrete assembly generated from (HLa)+ moiety bridged with [Ni(sy-L2)] unit and ClO4- anion. A solution containing complex 2 and Cd(NO3)2 results in a mixture of 1 and 3. Further re-crystallization of 1 and 3 with various auxiliary ligands, provides coordination complexes 4 7 stabilized by weak hydrogen bonds in which 6 and 7 represent the first 1D heteronuclear complexes based on symmetric acacen-base Schiff base ligand.

Ge, Ying Ying; Li, Guo-Bi; Fang, Hua-Cai; Zhan, Xu Lin; Gu, Zhi-Gang; Chen, Jin Hao; Sun, Feng; Cai, Yue-Peng; Thallapally, Praveen K.

2010-09-18T23:59:59.000Z

226

Environmentally Assisted Cracking of Ni-Base Alloys [Corrosion and  

NLE Websites -- All DOE Office Websites (Extended Search)

LWRs > Environmentally Assisted LWRs > Environmentally Assisted Cracking of Ni-Base Alloys Capabilities Materials Testing Environmentally Assisted Cracking (EAC) of Reactor Materials Corrosion Performance/Metal Dusting Overview Light Water Reactors Fatigue Testing of Carbon Steels and Low-Alloy Steels Environmentally Assisted Cracking of Ni-Base Alloys Irradiation-Induced Stress Corrosion Cracking of Austenitic Stainless Steels Steam Generator Tube Integrity Program Air Oxidation Kinetics for Zr-based Alloys Fossil Energy Fusion Energy Metal Dusting Publications List Irradiated Materials Steam Generator Tube Integrity Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Corrosion and Mechanics of Materials Light Water Reactors

227

Gamow-Teller transitions from {sup 56}Ni  

Science Conference Proceedings (OSTI)

A new technique to measure (p,n) charge-exchange reactions in inverse kinematics at intermediate energies on unstable isotopes was successfully developed and used to study the {sup 56}Ni(p,n) reaction at 110 MeV/u. Gamow-Teller transition strengths from {sup 56}Ni to {sup 56}Cu were obtained and compared with shell-model predictions in the pf-shell using the KB3G and GXPF1A interactions. The calculations with the GXPF1A interaction reproduce the experimental GT strength distribution much better than the calculations that employed the KB3G interaction, indicating deficiencies in the spin-orbit and proton-neutron residual potentials for the latter. The results are important for improving the description of electron-capture rates on nuclei in the iron region, which are important for modeling the late evolution of core-collapse and thermonuclear supernovae.

Sasano, M. [RIKEN Nishina Center, Wako, 351-0198 (Japan); Perdikakis, G. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, MI 48824-1321 (United States) and Joint Institute for Nuclear Astrophysics, Michigan State University, East Lansing, MI 48824 (United States); Zegers, R.G.T. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, MI 48824-1321 (United States) and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); and others

2012-11-12T23:59:59.000Z

228

Novel electrolyte chemistries for Mg-Ni rechargeable batteries.  

DOE Green Energy (OSTI)

Commercial hybrid electric vehicles (HEV) and battery electric vehicles (BEV) serve as means to reduce the nation's dependence on oil. Current electric vehicles use relatively heavy nickel metal hydride (Ni-MH) rechargeable batteries. Li-ion rechargeable batteries have been developed extensively as the replacement; however, the high cost and safety concerns are still issues to be resolved before large-scale production. In this study, we propose a new highly conductive solid polymer electrolyte for Mg-Ni high electrochemical capacity batteries. The traditional corrosive alkaline aqueous electrolyte (KOH) is replaced with a dry polymer with conductivity on the order of 10{sup -2} S/cm, as measured by impedance spectroscopy. Several potential novel polymer and polymer composite candidates are presented with the best-performing electrolyte results for full cell testing and cycling.

Garcia-Diaz, Brenda (Savannah River National Laboratory); Kane, Marie; Au, Ming (Savannah River National Laboratory)

2010-10-01T23:59:59.000Z

229

Fabrication Of Buried Self-Organized Stripes In The Ni/C{sub 60} Composite  

Science Conference Proceedings (OSTI)

A periodic array of striped nanoscopic domains, embedded in the epitaxially grown Ni layer, was formed after thermal annealing of the Ni/Ni+C{sub 60}/C{sub 60}/Ni thin multilayer sequence deposited on the MgO(001) monocrystal. The composite was annealed in 100 deg. C/1 hr increments in the range of 200-600 deg. C, and the structural evolution of the composite was analyzed mainly by Rutherford Backscattering and Scanning Electron Microscopy. The periodic system of the stripes was revealed after annealing at 600 deg. C. The possible mechanism of the domain formation is suggested as follows: temperatures below 500 deg. C incite diffusion (and consecutive disintegration) of the C{sub 60} molecules; temperatures above 500 deg. C induce forceful intermixing of the upper Ni/Ni+C{sub 60}/C{sub 60} layers; due to the pronounced immiscibility of the Ni and C (C{sub 60}) components the process of the phase separation is triggered. In the confined crystalline matrix of the buffer Ni layer the separation proceeds coordinately according to the Ni lattice template - the stripe domains are formed in a direction parallel to the main crystallographic orientation (001) of the Ni epilayer.

Vacik, J. [Nuclear Physics Institute (NPI) of AS CR, CZ-25068 Husinec - Rez (Czech Republic); Research Center Rez, 250 68 Husinec - Rez (Czech Republic); Lavrentiev, V.; Horak, P. [Nuclear Physics Institute (NPI) of AS CR, CZ-25068 Husinec - Rez (Czech Republic); Narumi, K. [Japan Atomic Energy Agency (JAEA), 1233 Watanuki, Takasaki, 370-1292 Gunma (Japan)

2011-06-01T23:59:59.000Z

230

Neutron to proton ratios of quasiprojectile and midrapidity emission in the {sup 58}Ni+{sup 58}Ni reaction at 52 MeV/nucleon  

SciTech Connect

By combining data from a charged particle {sup 58}Ni+{sup 58}Ni experiment at 52 MeV/nucleon with an {sup 36}Ar+{sup 58}Ni experiment at 50 MeV/nucleon for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction {sup 58}Ni+{sup 58}Ni at 52 MeV/nucleon. The neutron-to-proton ratio of the quasi-projectile emission is analyzed for the same reactions and is seen to decrease below the ratio of the initial system. Those observations suggest that an asymmetric exchange of neutrons and protons between the quasiprojectile and the midrapidity region exists.

Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; St-Pierre, C.; Turbide, S. [Laboratoire de Physique Nucleaire, Departement de Physique, Universite Laval, Quebec, G1K 7P4 (Canada); Samri, M. [Laboratoire de Physique Nucleaire et Applications, Universite Ibn Tofail, Kenitra (Morocco); Borderie, B.; Rivet, M. F. [Institut de Physique Nucleaire, IN2P3-CNRS, F-91406 Orsay Cedex (France); Bougault, R.; Colin, J.; Cussol, D.; Durand, D.; Lecolley, J.F. [LPC, IN2P3-CNRS, ISMRA and Universite, F-14050 Caen Cedex (France)] [and others

2005-01-01T23:59:59.000Z

231

Tribological behavior of NiTi alloy against 52100 steel and WC at elevated temperatures  

SciTech Connect

The dry tribological behavior of a Ti-50.3 at.% Ni alloy at temperatures of 25 deg. C, 50 deg. C and 200 deg. C was studied. The wear tests were performed on a high temperature pin-on-disk tribometer using 52100 steel and tungsten carbide pins. The worn surfaces of the NiTi alloy were examined by scanning electron microscope. The results showed that in the wear tests involving steel pins, the wear rate of the NiTi decreased as the wear testing temperature was increased. However, for the NiTi/WC contact, a reverse trend was observed. There was also a large decrease in the coefficient of friction for the NiTi/steel contact with increasing wear testing temperature. The formation of compact tribological layers could be the main reason for the reduction of the wear rate and coefficient of friction of the NiTi/steel contact at higher wear testing temperatures.

Abedini, M. [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ghasemi, H.M., E-mail: hghasemi@ut.ac.ir [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ahmadabadi, M. Nili [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

2010-07-15T23:59:59.000Z

232

INTERPRTATION DES FAUTES D'EMPILEMENT DANS L'ANTIFERROMAGNTIQUE K2NiF4  

E-Print Network (OSTI)

859. INTERPR?TATION DES FAUTES D'EMPILEMENT DANS L'ANTIFERROMAGN?TIQUE K2NiF4 Par R. PLUMIER. 2014 Nous montrons qu'une légère déformation orthorhombique de la maille de K2NiF4 entraîne parNiF4 cell leads to a decrease of the free energy of the crystal through an exchange striction

Paris-Sud XI, Université de

233

High Temperature Corrosion Resistance of Fe-Ni-Cr Alloys in CO2 ...  

Science Conference Proceedings (OSTI)

Austenitic Steel Oxidation in Steam: Alloy Composition and Surface Modification ... Ni-Base Alloys for Use as Components in Advanced-USC Steam Turbines.

234

In-Situ Neutron Diffraction Study of Porous NiO-YSZ Composite ...  

Science Conference Proceedings (OSTI)

Presentation Title, In-Situ Neutron Diffraction Study of Porous NiO-YSZ Composite ... Gas Turbines of the Future: Hydrogen and Oxy-Combustion Environments.

235

Shape Memory Response of NiTiHfPd High Strength and High ...  

Science Conference Proceedings (OSTI)

In this study, shape memory and superelastic properties of NiTiHfPd polycrystalline and single crystalline SMAs as functions of aging temperature and time were...

236

Investigation on Oxidation Resistance of NiCoCrAlY Coating ...  

Science Conference Proceedings (OSTI)

Presentation Title, Investigation on Oxidation Resistance of NiCoCrAlY Coating Irradiated by High Current Pulsed Electron Beam. Author(s), Xianxiu Mei, Cunxia ...

237

Pressure Water Leaching Molybdenum and Nickel from Mo-Ni ore of ...  

Science Conference Proceedings (OSTI)

Presentation Title, Pressure Water Leaching Molybdenum and Nickel from Mo-Ni ore of Black Shale without Reagent. Author(s), Zhigan Deng. On-Site Speaker...

238

Further Characterization of New NiTi Wire and Rotary Endodontic ...  

Science Conference Proceedings (OSTI)

Presentation Title, Further Characterization of New NiTi Wire and Rotary ... Higher-resolution transmission electron microscopy examination of M-Wire used to...

239

Effects of Changes in Alloy Composition on Toughness of Ni-Ta-X ...  

Science Conference Proceedings (OSTI)

On-Site Speaker (Planned), John J Lewandowski. Abstract Scope, The effects of changes in alloy chemistry on the fracture behavior of Ni-Ta-X glasses are...

240

F-8: Modeling of Mn-Ni-Si-Cu Precipitation in Reactor Pressure ...  

Science Conference Proceedings (OSTI)

Presentation Title, F-8: Modeling of Mn-Ni-Si-Cu Precipitation in Reactor .... Steels 316 and Comparison with the Rate Theory Model of a Multicomponent System.

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

SF6432-NI (02-01-12) Fixed Price Former Soviet Union  

NLE Websites -- All DOE Office Websites (Extended Search)

CORPORATION SF 6432-NI (072013) SECTION II STANDARD TERMS AND CONDITIONS FOR FIXED PRICE CONTRACTS WITH THE NEWLY INDEPENDENT STATES OF THE FORMER SOVIET UNION INDEX OF...

242

Mixed Conducting Molten Salt Electrolyte for Na/NiCl 2 Cell  

Science Conference Proceedings (OSTI)

Catalytic Properties of Ni-Al Intermetallic Nanoparticle Catalysts for Hydrogen Production from Methanol and Methane Ca, Li and Mg Based Lightweight...

243

Thermal and irradiation-induced phase separation in Fe-Ni based ...  

Science Conference Proceedings (OSTI)

magnetic, low-expansion Invar-type alloys and model austenitic Fe-Ni based alloys studied for ...... fast reactors such as the Fast Flux Test Facility (FFTF).

244

Thermodynamic Modeling of the Mg-Cu-Ni Ternary System using ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, COM 2011. Symposium, LIGHT METALS. Presentation Title, Thermodynamic Modeling of the Mg-Cu-Ni Ternary System using the...

245

Effect of Steam Exposure on the Creep Properties of Ni-Based Alloys  

Science Conference Proceedings (OSTI)

Symposium, Properties, Processing, and Performance of Steels and Ni-Based Alloys for Advanced Steam Conditions. Presentation Title, Effect of Steam...

246

Steam Oxidation of Fe-20Cr-30Ni-2Nb Austenitic Steel at 973 K  

Science Conference Proceedings (OSTI)

Symposium, Properties, Processing, and Performance of Steels and Ni-Based Alloys for Advanced Steam Conditions. Presentation Title, Steam Oxidation of...

247

Influence of the Water Vapour on the Oxidation Behaviour of a Ni ...  

Science Conference Proceedings (OSTI)

Presentation Title, Influence of the Water Vapour on the Oxidation Behaviour of a Ni-based Alloy Interest of an In-situ Microscopic Approach of Phenomena.

248

Ageing and Toughness of a Mn-Ni-Mo PWR Steel  

Science Conference Proceedings (OSTI)

Abstract Scope, Mn-Ni-Mo steels are widely used in the fabrication of pressurisers, steam generators and pressure vessels of pressurised water reactors (PWR).

249

Reduction of the Ni- and Ti-oxide mixtures by natural gas  

Science Conference Proceedings (OSTI)

In this work, the reduction of Ni- and Ti-oxides by natural gas has been studied. ... Reaction mechanism and reaction rate of Sn evaporation from liquid steel.

250

D3: Weld Solidification Behavior of Ni-base Superalloys for Use in ...  

Science Conference Proceedings (OSTI)

Presentation Title, D3: Weld Solidification Behavior of Ni-base Superalloys for Use in Advanced Supercritical Coal-fired Power Plants. Author(s), David Tung,...

251

Investigation on Corrosion Behaviour of Ni-Based Alloys in Molten ...  

Science Conference Proceedings (OSTI)

In this paper, corrosion processes of Ni-based superalloys including Inconel 600, Hastelloy X and Hastelloy C-276 were investigated in molten fluoride salts...

252

Self-assembly of Ni-nanoparticles in Aerosols Produced Thermally ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The self-assembly behavior in Ni-aerosols was studied on- ground ... In microgravity, convection within the thermally produced aerosols could be...

253

Large energy absorption in Ni-Mn-Ga/polymer composites  

SciTech Connect

Ferromagnetic shape memory alloys can respond to a magnetic field or applied stress by the motion of twin boundaries and hence they show large hysteresis or energy loss. Ni-Mn-Ga particles made by spark erosion have been dispersed and oriented in a polymer matrix to form pseudo 3:1 composites which are studied under applied stress. Loss ratios have been determined from the stress-strain data. The loss ratios of the composites range from 63% to 67% compared to only about 17% for the pure, unfilled polymer samples.

Feuchtwanger, Jorge; Richard, Marc L.; Tang, Yun J.; Berkowitz, Ami E.; O'Handley, Robert C.; Allen, Samuel M. [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); University of California, San Diego, La Joya, California 92093 (United States); Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2005-05-15T23:59:59.000Z

254

Upper critical field of Mo-Ni heterostructures  

SciTech Connect

Upper critical field and its anisotropy have been measured on two very short wavelength Mo-Ni heterostructures of different degrees of perfection, lambda = 13.8A (disordered structure) and lambda = 16.6A (layered structure). In both cases the parallel critical field has an unexpected temperature dependence, a large and temperature dependent anisotropy, and over 60% enhancement over the Clogston-Chandrasekhar limit. Data are fit to the Werthamer-Helfand-Hohenberg theory and the spin-orbit scattering times are found to be 1.79 x 10 T s and 2 x 10 T s, respectively.

Uher, C.; Watson, W.J.; Cohn, J.L.; Schuller, I.K.

1985-12-01T23:59:59.000Z

255

Grain Refinement in TiC-Ni3Al Composites  

DOE Green Energy (OSTI)

The Cooperative Research and Development Agreement (CRADA) was to develop composites of TiC-Ni{sub 3}Al with refined grain microstructures for application in diesel engine fuel injection devices. Grain refinement is important for improved wear resistance and high strength for the applications of interest. Attrition milling effectively reduces the initial particle size and leads to a reduction of the final grain size. However, an increase in the oxygen content occurs concomitantly with the grinding operation and decreased densification of the compacts occurs during sintering.

Tiegs, T.N.

2001-01-30T23:59:59.000Z

256

Spectromicroscopy study of interfacial Co/NiO(001)  

SciTech Connect

Photoemission electron microscopy (PEEM) with linearly polarized x-rays is used to determine the orientation of antiferromagnetic domains by monitoring the relative peak intensities at the 3d transition metal L{sub 2} absorption edge. In such an analysis the orientations of the x-ray polarization E and magnetization H with respect to the crystalline axes has to be taken into account. We address this problem by presenting a general expression of the angular dependence for both x-ray absorption spectroscopy and x-ray magnetic linear dichroism (XMLD) for arbitrary direction of E and H in the (001) cubic plane. In cubic symmetry the angular dependent XMLD is a linear combination of two spectra with different photon energy dependence, which reduces to one spectrum when E or H is along a high-symmetry axis. The angular dependent XMLD can be separated into an isotropic term, which is symmetric along H, and an anisotropic term, which depends on the orientation of the crystal axes. The anisotropic term has maximal intensity when E and H have equal but opposite angles with respect to the [100] direction. The Ni{sup 2+} L{sub 2} edge has the peculiarity that the isotropic term vanishes, which means that the maximum in the XMLD intensity is observed not only for E {parallel} H {parallel} [100] but also for (E {parallel} [110], H {parallel} [110]). We apply the angular dependent theory to determine the spin orientation near the Co/NiO(100) interface. The PEEM images show that the ferromagnetic Co moments and antiferromagnetic NiO moments are aligned perpendicular to each other. By rotating the sample with respect to the linear x-ray polarization we furthermore find that the perpendicular coupling with the ferromagnetic Co layer at the interface causes a canting of the antiferromagnetic Ni moments. This shows that taking into account the angular dependence of the XMLD in the detailed analysis of PEEM images leads to an accurate retrieval of the spin axes of the antiferromagnetic domains.

van der Laan, Gerrit; Telling, Neil; Potenza, Alberto; Dhesi, Sarnjeet; Arenholz, Elke

2010-09-26T23:59:59.000Z

257

Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents (OSTI)

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

Natesan, K.; Baxter, D.J.

1983-07-26T23:59:59.000Z

258

ENDF/B-VII.0, ENDF/B-VI, JEFF-3.1, AND JENDL-3.3 RESULTS FOR UNREFLECTED PLUTONIUM SOLUTIONS AND MOX LATTICES (U)  

SciTech Connect

Previous studies have indicated that ENDF/B-VII preliminary releases {beta}-2 and {beta}-3, predecessors to the recent initial release of ENDF/B-VII.0, produce significantly better overall agreement with criticality benchmarks than does ENDF/B-VI. However, one of those studies also suggests that improvements still may be needed for thermal plutonium cross sections. The current study substantiates that concern by examining criticality benchmarks for unreflected spheres of plutonium-nitrate solutions and for slightly and heavily borated mixed-oxide (MOX) lattices. Results are presented for the JEFF-3.1 and JENDL-3.3 nuclear data libraries as well as ENDF/B-VII.0 and ENDF/B-VI. It is shown that ENDF/B-VII.0 tends to overpredict reactivity for thermal plutonium benchmarks over at least a portion of the thermal range. In addition, it is found that additional benchmark data are needed for the deep thermal range.

MOSTELLER, RUSSELL D. [Los Alamos National Laboratory

2007-02-09T23:59:59.000Z

259

Force Field Development and Molecular Dynamics of [NiFe] Hydrogenase  

Science Conference Proceedings (OSTI)

Classical molecular force-field parameters describing the structure and motion of metal clusters in [NiFe] hydrogenase enzymes can be used to compare the dynamics and thermodynamics of [NiFe] under different oxidation, protonation, and ligation circumstances. Using density functional theory (DFT) calculations of small model clusters representative of the active site and the proximal, medial, and distal Fe/S metal centers and their attached protein side chains, we have calculated classical force-field parameters for [NiFe] in reduced and oxidized states, including internal coordinates, force constants, and atom-centered charges. Derived force constants revealed that cysteinate ligands bound to the metal ions are more flexible in the Ni-B active site, which has a bridging hydroxide ligand, than in the Ni-C active site, which has a bridging hydride. Ten nanosecond all-atom, explicit-solvent MD simulations of [NiFe] hydrogenase in oxidized and reduced catalytic states established the stability of the derived force-field parameters in terms of C{alpha} and metal cluster fluctuations. Average active site structures from the protein MD simulations are consistent with [NiFe] structures from the Protein Data Bank, suggesting that the derived force-field parameters are transferrable to other hydrogenases beyond the structure used for testing. A comparison of experimental H{sub 2}-production rates demonstrated a relationship between cysteinate side chain rotation and activity, justifying the use of a fully dynamic model of [NiFe] metal cluster motion.

Smith, Dayle MA; Xiong, Yijia; Straatsma, TP; Rosso, Kevin M.; Squier, Thomas C.

2012-05-09T23:59:59.000Z

260

A Linear Combination Analyses Approach For Directly Speciating Ni Contaminated Soils.  

E-Print Network (OSTI)

A Linear Combination Analyses Approach For Directly Speciating Ni Contaminated Soils. (S02-trivedi215458-Oral) Abstract: To provide an accurate description of the fate of Ni in aerial- contaminated soils to combine multiple analytical techniques to accurately determine metal speciation in complex soil systems

Sparks, Donald L.

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Synthesis and characterization of LiNiO2 nanopowder with various chelating agents  

Science Conference Proceedings (OSTI)

LiNiO2 powders were synthesized with acrylic acid, citric acid, oxalic acid, and triethanolamine (TEA) as a chelating agent. Crystallized LiNiO2 was synthesized in air at a calcinations temperature of 500C for 12 hours, when ...

Mehrdad Balandeh; Sirous Asgari

2010-01-01T23:59:59.000Z

262

Glass Forming Ability in Pr-(Cu, Ni)-Al Alloys  

E-Print Network (OSTI)

Glass forming ability (GFA) in the Pr-rich Pr-(Cu, Ni)-Al alloys at or near the eutectic points was systematically studied. It was found that the GFA in the pseudo-ternary alloys of Pr-(Cu, Ni)-Al is higher than that of ...

Zhang, Yong

263

Mechanochemical synthesis and rapid consolidation of nanocrystalline 3NiAl-Al2O3 composites  

Science Conference Proceedings (OSTI)

Nanopowders of 3NiAl and Al2O3 were synthesized from 3NiO and 5Al powders by high-energy ball milling. Nanocrystalline Al2O3 reinforced composite was consolidated by high-frequency induction-heated sintering ...

In-Jin Shon; In-Yong Ko; Seung-Hoon Jo; Jung-Mann Doh; Jin-Kook Yoon; Sang-Whan Park

2011-01-01T23:59:59.000Z

264

Fabrication and thermoelectric properties of fine-grained TiNiSn compounds  

Science Conference Proceedings (OSTI)

Nearly single-phased TiNiSn half-Heusler compound thermoelectric materials were synthesized by combining mechanical alloying (MA) and spark plasma sintering (SPS) in order to reduce its thermal conductivity by refining the grain sizes. Although TiNiSn compound powders were not synthesized directly via MA, dense bulk samples of TiNiSn compound were obtained by the subsequent SPS treatment. It was found that an excessive Ti addition relative to the TiNiSn stoichiometry is effective in increasing the phase purity of TiNiSn half-Heusler phase in the bulk samples, by compensating for the Ti loss caused by the oxidation of Ti powders and MA processing. The maximum power factor value obtained in the Ti-compensated sample is 1720 muW m{sup -1} K{sup -2} at 685 K. A relatively high ZT value of 0.32 is achieved at 785 K for the present undoped TiNiSn compound polycrystals. - Graphical abstract: Nearly single-phased TiNiSn-based half-Heusler compound polycrystalline materials with fine grains were fabricated by combining mechanical alloying (MA) and spark plasma sintering (SPS). A high ZT value for undoped TiNiSn was obtained because of the reduced thermal conductivity.

Zou Minmin [State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Li Jingfeng, E-mail: jingfeng@mail.tsinghua.edu.c [State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Du Bing; Liu Dawei [State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Kita, Takuji [Advanced Material Engineering Division, Vehicle Engineering Group, Higashifuji Technical Center, Toyota Motor Corporation, 1200, Mishuku, Susono, Shizuoka 410-1193 (Japan)

2009-11-15T23:59:59.000Z

265

Electrodeposition and characterization of nanocrystalline Ni-Mo catalysts for hydrogen production  

Science Conference Proceedings (OSTI)

Ni-Mo nanocrystalline deposits (7-43 nm) with a nodular morphology were prepared by electrodeposition using direct current from citrate-ammonia solutions. They exhibited a single Ni-Mo solid solution phase. The size of the nodules increased as electroplating ...

J. Halim; R. Abdel-Karim; S. El-Raghy; M. Nabil; A. Waheed

2012-01-01T23:59:59.000Z

266

LSCF Synthesis and Syngas Reactivity over LSCF-modified Ni/YSZ Anode.  

E-Print Network (OSTI)

??Simulated coal syngas reactivity over Ni/YSZ and LSCF (La0.6Sr0.4Co0.2Fe0.8)-modified Ni/YSZ anode of SOFC (solid oxide fuel cell) was investigated in this study. The contribution of (more)

Mirzababaei, Jelvehnaz

2011-01-01T23:59:59.000Z

267

WVU FY 2009Expanding West Virginia's Economy WE s t Vi rg i n i a U n i V E r s i t y  

E-Print Network (OSTI)

in business volume · $1 billion in employee compensation · $37.1 million in assorted state taxes The economic: · 45,500 jobs · $8.28 billion in business volume · $1.8 billion in employee compensation · $69 millionWVU FY 2009Expanding West Virginia's Economy WE s t Vi rg i n i a U n i V E r s i t y: amy

Mohaghegh, Shahab

268

FINAL REPORT FOR THE REDUCTION OF CHROME (VI) TO CHROME (III) IN THE SECONDARY WASTE STREAM OF THE EFFLUENT TREATMENT FACILITY  

SciTech Connect

This report documents the laboratory results of RPP-PLAN-35958, Test Plan for the Effluent Treatment Facility to Reduce Chrome (VI) to Chrome (III) in the Secondary Waste Stream With the exception of the electrochemical corrosion scans, all work was carried out at the Center for Laboratory Science (CLS) located at the Columbia Basin College. This document summarizes the work carried out at CLS and includes the electrochemical scans and associated corrosion rates for 304 and 316L stainless steel.

DUNCAN JB; GUTHRIE MD

2008-08-29T23:59:59.000Z

269

Hydrogen Permeability of Mulitphase V-Ti-Ni Metallic Membranes  

DOE Green Energy (OSTI)

Development of advanced hydrogen separation membranes in support of hydrogen production processes such as coal gasification and as front end gas purifiers for fuel cell based system is paramount to the successful implementation of a national hydrogen economy. Current generation metallic hydrogen separation membranes are based on Pd-alloys. Although the technology has proven successful, at issue is the high cost of palladium. Evaluation of non-noble metal based dense metallic separation membranes is currently receiving national and international attention. The focal point of the reported work was to evaluate a Group 5A-Ta, Nb, V-based alloy with respect to microstructural features and hydrogen permeability. Electrochemical hydrogen permeation testing of the V-Ti-Ni alloy is reported herein and compared to pure Pd measurements recorded as part of this same study. The V-Ti-Ni was demonstrated to have a steady state hydrogen permeation rate an order of magnitude higher than the pure Pd material in testing conducted at 22 C.

Adams, T. M.; Mickalonis, J.

2005-10-18T23:59:59.000Z

270

Direct synthesis of porous NiO nanowall arrays on conductive substrates for supercapacitor application  

Science Conference Proceedings (OSTI)

Porous NiO nanowall arrays (NWAs) grown on flexible Fe-Co-Ni alloy have been successfully synthesized by using nullaginite (Ni{sub 2}(OH){sub 2}CO{sub 3}) as precursor and investigated as supercapacitor electrodes. In details, we adopted a simple hydrothermal method to realize Ni{sub 2}(OH){sub 2}CO{sub 3} NWAs and examined their robust mechanical adhesion to substrate via a long-time ultrasonication test. Porous NiO NWAs were then obtained by a post-calcination towards precursors at 500 {sup o}C in nitrogen atmosphere. Electrochemical properties of as-synthesized NiO NWAs were evaluated by cyclic voltammetry and galvanostatic charge/discharge; porous NiO NWAs electrode delivered a specific capacitance of 270 F/g (0.67 A/g); even at high current densities, the electrode could still deliver a high capacitance up to 236 F/g (13.35 A/g). Meanwhile, it exhibited excellent cycle lifetime with {approx}93% specific capacitance kept after 4000 cycles. These results suggest that as-made porous NiO NWAs electrode is a promising candidate for future thin-film supercapacitors and other microelectronic systems. -- Graphical abstract: Porous NiO nanowall arrays (NWAs) grown on alloy substrate have been made using nullaginite as precursor and studied as supercapacitor electrodes. Porous nanowalls interconnected with each other resulting in the formation of extended-network architectures and exhibited excellent capacitor properties. NiO NWAs electrode delivered a capacitance of 270 F/g (0.67 A/g); even at high current density, the electrode could still deliver a high capacitance up to 236 F/g (13.35 A/g). Besides, it exhibited excellent cycle lifetime with {approx}93% capacitance kept after 4000 cycles. These remarkable results made it possible for mass production of NiO NWAs and future thin-film microelectronic applications. Display Omitted Research highlights: {yields} Large-scale nullaginite (Ni{sub 2}(OH){sub 2}CO{sub 3}) nanowall arrays (NWAs) have been synthesized on flexible alloy substrate by a facile hydrothermal method. {yields} Ultrasonication test has been conducted to demonstrate the robust mechanical adhesion between NWAs and substrate. {yields} As supercapacitor electrodes porous NiO NWAs obtained by a post-calcination towards Ni{sub 2}(OH){sub 2}CO{sub 3} precursors have exhibited excellent electrochemical properties.

Zhu, Jianhui; Jiang, Jian; Liu, Jingping; Ding, Ruimin; Ding, Hao; Feng, Yamin; Wei, Guangming [Institute of Nanoscience and Nanotechnology, Department of Physics, Huazhong Normal University, 430079 Wu Han (China); Huang, Xintang, E-mail: xthuang@phy.ccnu.edu.c [Institute of Nanoscience and Nanotechnology, Department of Physics, Huazhong Normal University, 430079 Wu Han (China)

2011-03-15T23:59:59.000Z

271

[Hydrogen induced C-C, C-N, and C-S bond activities on Pi and Ni surfaces]: Summary  

SciTech Connect

This document summarizes research applied to chemical bond activation studies. Topics summarized include: Carbon nitrogen bonds experimentation with aniline on Ni(111), Mi(100), and Pt(111) surfaces; carbon sulfur bonds experimentation with methanethiol, phenylthiol, and dimethyl disulfide on Pt(111) and Ni(111) surfaces; carbon-carbon bonds experimentation on Ni(100), Ni(111) and Pt(111) surfaces; and in-situ fluorescence yield near edge spectroscopy.

Gland, J.L.

1994-12-31T23:59:59.000Z

272

Hydrothermal synthesis and electrochemical performance of NiO microspheres with different nanoscale building blocks  

SciTech Connect

NiO microspheres were successfully obtained by calcining the Ni(OH){sub 2} precursor, which were synthesized via the hydrothermal reaction of nickel chloride, glucose and ammonia. The products were characterized by TGA, XRD and SEM. The influences of glucose and reaction temperature on the morphologies of NiO samples were investigated. Moreover, the possible growth mechanism for the spherical morphology was proposed. The charge/discharge test showed that the as-prepared NiO microspheres composed of nanoparticles can serve as an ideal electrode material for supercapacitor due to the spherical hollow structure. -- Graphical Abstract: Fig. 5 is the SEM image of NiO that was prepared in the different hydrothermal reaction temperatures. It showed that reaction temperature played a crucial role for the morphology of products.

Wang Ling; Hao Yanjing; Zhao Yan [College of Chemistry, Sichuan University, Chengdu 610064 (China); Lai Qiongyu, E-mail: laiqy5@hotmail.co [College of Chemistry, Sichuan University, Chengdu 610064 (China); Xu Xiaoyun [College of Chemistry, Sichuan University, Chengdu 610064 (China)

2010-11-15T23:59:59.000Z

273

Charge transfer effects in electrocatalytic Ni-C revealed by x-ray photoelectron spectroscopy  

SciTech Connect

Binary Ni-C thin-film alloys, which have been shown to be passive against corrosion in hot sulphuric acid solution whilst also being electrocatalytically active, were investigated by XPS to determine the oxidation state of the metal and carbon components. The Ni component produces a Ni 2p spectrum similar to that of metallic nickel (i.e., no oxidation occurs) but with a 0.3 eV shift to higher binding energy (BE) due to electron donation to the carbon matrix. The C 1s peak shows a shift to lower BE by accepting electrons from the Ni nanocrystals. A cluster-model analysis of the observed Ni 2p spectrum is consistent with the electron transfer from the nickel to the carbon.

Haslam, G. E.; Chin, X.-Y.; Burstein, G. T. [Department of Materials Science and Metallurgy, University of Cambridge, Pembroke St., Cambridge CB2 3QZ (United Kingdom); Sato, K.; Mizokawa, T. [Department of Complexity Science and Engineering, University of Tokyo, 5-1-5 Kashiwanoha, Chiba 277-8651 (Japan)

2012-06-04T23:59:59.000Z

274

Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil  

Science Conference Proceedings (OSTI)

The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

1994-06-01T23:59:59.000Z

275

Fe(III) Reduction and U(VI) Immobilization by Paenibacillus sp. Strain 300A, Isolated from Hanford 300A Subsurface Sediments  

Science Conference Proceedings (OSTI)

A facultative iron-reducing (Fe(III)-reducing) Paenibacillus sp. strain was isolated from Hanford 300A subsurface sediment biofilms that was capable of reducing soluble Fe(III) complexes (Fe(III)-NTA and Fe(III)-citrate) but unable to reduce poorly crystalline ferrihydrite (Fh). However, Paenibacillus sp. 300A was capable of reducing Fh in the presence of low concentrations (2 M) of either of electron transfer mediators (ETMs) flavin mononucleotide (FMN) or anthraquinone-2,6-disulfonate (AQDS). Maximum initial Fh reduction rates were observed at catalytic concentrations (Hanford 300A subsurface sediments. In the absence of ETMs, Paenibacillus sp. 300A was capable of immobilizing U(VI) through both reduction and adsorption. The relative contributions of adsorption and microbial reduction to U(VI) removal from the aqueous phase were ~7:3 in PIPES and ~1:4 in bicarbonate buffer. Our study demonstrated that Paenibacillus sp. 300A catalyzes Fe(III) reduction and U(VI) immobilization and that these reactions benefit from externally added or naturally existing ETMs in 300A subsurface sediments.

Ahmed, B.; Cao, B.; McLean, Jeffrey S.; Ica, Tuba; Dohnalkova, Alice; Istanbullu, Ozlem; Paksoy, Akin; Fredrickson, Jim K.; Beyenal, Haluk

2012-11-07T23:59:59.000Z

276

Development of FeNiMoB thin film materials for microfabricated magnetoelastic sensors  

Science Conference Proceedings (OSTI)

Metglas{sup TM} 2826MB foils of 25-30 {mu}m thickness with the composition of Fe{sub 40}Ni{sub 38}Mo{sub 4}B{sub 18} have been used for magnetoelastic sensors in various applications over many years. This work is directed at the investigation of {approx}3 {mu}m thick iron-nickel-molybdenum-boron (FeNiMoB) thin films that are intended for integrated microsystems. The films are deposited on Si substrate by co-sputtering of iron-nickel (FeNi), molybdenum (Mo), and boron (B) targets. The results show that dopants of Mo and B can significantly change the microstructure and magnetic properties of FeNi materials. When FeNi is doped with only Mo its crystal structure changes from polycrystalline to amorphous with the increase of dopant concentration; the transition point is found at about 10 at. % of Mo content. A significant change in anisotropic magnetic properties of FeNi is also observed as the Mo dopant level increases. The coercivity of FeNi films doped with Mo decreases to a value less than one third of the value without dopant. Doping the FeNi with B together with Mo considerably decreases the value of coercivity and the out-of-plane magnetic anisotropy properties, and it also greatly changes the microstructure of the material. In addition, doping B to FeNiMo remarkably reduces the remanence of the material. The film material that is fabricated using an optimized process is magnetically as soft as amorphous Metglas{sup TM} 2826MB with a coercivity of less than 40 Am{sup -1}. The findings of this study provide us a better understanding of the effects of the compositions and microstructure of FeNiMoB thin film materials on their magnetic properties.

Liang Cai; Gooneratne, Chinthaka; Cha, Dongkyu; Chen Long; Kosel, Jurgen [Computer Electrical and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, 4700 KAUST, Thuwal 23955 (Saudi Arabia); Gianchandani, Yogesh [Department of Electrical Engineering and Computer Science, 1301 Beal Ave., University of Michigan, Ann Arbor, Michigan 48109 (United States)

2012-12-01T23:59:59.000Z

277

Green chemical transformation of phenolic pollutants using mesoporous NiO nanocrystals with sheet-like morphology  

Science Conference Proceedings (OSTI)

We report the fabrication of hierarchical mesoporous NiO nanocrystals (NCs) with sheet-like morphology via a simple, and eco-friendly hydrothermal method. Mesoporous NiO particles were characterized by small- and wide-angle X-ray diffraction, nitrogen ... Keywords: chemical transformation, mesoporous NiO, nanocatalysts, pollutants

Mohamed Khairy; Sherif A. El-Safty; Mohamed Ismael; M. A. Shenashen

2012-02-01T23:59:59.000Z

278

Three-Dimensional Topological Insulators in I-III-VI2 and II-IV-V2 Chalcopyrite Semiconductors  

SciTech Connect

The recent discovery of topological insulators with exotic metallic surface states has garnered great interest in the fields of condensed matter physics and materials science.1 A number of spectacular quantum phenomena have been predicted when the surface states are under the influence of magnetism and superconductivity,2 5 which could open up new opportunities for technological applications in spintronics and quantum computing. To achieve this goal, material realization of topological insulators with desired physical properties is of crucial importance. Based on first-principles calculations, here we show that a large number of ternary chalcopyrite compounds of composition I-III-VI2 and II-IV-V2 can realize the topological insulating phase in their native states. The crystal structure of chalcopyrites is derived from the frequently used zinc-blende structure, and many of them possess a close lattice match to important mainstream semiconductors, which is essential for a smooth integration into current semiconductor technology. The diverse optical, electrical and structural properties of chalcopyrite semiconductors,6 and particularly their ability to host room-temperature ferromagnetism,7 9 make them appealing candidates for novel spintronic devices.

Feng, wanxiang [Chinese Academy of Sciences; Ding, Jun [Beijing National Laboratory for Condensed Matter Physics/Chinese Academy of Scie; Xiao, Di [ORNL; Yao, yugui [Chinese Academy of Sciences

2011-01-01T23:59:59.000Z

279

Stratospheric ozone protection: The Montreal Protocol and Title VI of the Clean Air Act Amendments of 1990  

Science Conference Proceedings (OSTI)

The stratospheric ozone layer protects the surface of the Earth from harmful ultraviolet (UV-B) radiation, which has been causally linked to skin cancer and cataracts, suppression of the human immune system, damage to crops and aquatic organisms, the formation of ground-level zone and the rapid weathering of outdoor plastics. In recent years, scientists have observed a significant deterioration of the ozone layer, particularly over the poles, but increasingly over populated regions as well. This deterioration has been attributed to the atmospheric release of certain man-made halocarbons, including chlorofluorocarbons (CFCs), halons, methyl chloroform and carbon tetrachloride. Once used extensively as propellants for aerosol sprays (but generally banned for such purposes since 1978), CFCs are widely used today as refrigerants, foams and solvents. All of these chlorinated (CFC, methyl chloroform and carbon tetrachloride) and brominated (halon) compounds are classified for regulatory purposes as Class I substances because of their significant ozone-depleting potential. Hydrochlorofluorocarbons (HCFCs), developed as alternatives to CFCs and halons for many different applications, have been classified for regulatory purposes as Class II substances because of their relatively less destructive impact on stratospheric ozone. This paper describes the following regulations to reduce destruction of the ozone layer: the Montreal Protocol; Title VI of the Clean air Act Amendments of 1990; Accelerated Phase-out schedules developed by the countries which signed the Montreal Protocol; Use restrictions; Recycling and Emission reduction requirements; Servicing of motor vehicle air conditions; ban on nonessential products; labeling requirements; safe alternatives. 6 refs.

Babst, C.R. III

1993-08-01T23:59:59.000Z

280

U(VI) bioreduction with emulsified vegetable oil as the electron donor-Model application to a field test  

Science Conference Proceedings (OSTI)

A one-time 2-hour emulsified vegetable oil (EVO) injection in a fast flowing aquifer decreased U discharge to a stream for over a year. Using a comprehensive biogeochemical model developed in the companion article based on microcosm tests, we approximately matched the observed acetate, nitrate, Fe, U, and sulfate concentrations, and described the major evolution trends of multiple microbial functional groups in the field test. While the lab-determined parameters were generally applicable in the field-scale simulation, the EVO hydrolysis rate constant was estimated to be an order of magnitude greater in the field than in the microcosms. The model predicted substantial biomass (sulfate reducers) and U(IV) accumulation near the injection wells and along the side boundaries of the treatment zone where electron donors (long-chain fatty acids) from the injection wells met electron acceptors (sulfate) from the surrounding environment. While EVO retention and hydrolysis characteristics were expected to control treatment longevity, modeling results indicated that electron acceptors such as sulfate may not only compete for electrons but also play a conducive role in degrading complex substrates and enhancing U(VI) reduction and immobilization. As a result, the spacing of the injection wells could be optimized for effective sustainable bioremediation.

Tang, Guoping [ORNL; Watson, David B [ORNL; Wu, Wei-min [Stanford University; Schadt, Christopher Warren [ORNL; Parker, Jack C [ORNL; Brooks, Scott C [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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281

Impact of uranyl-calcium-carbonato complexes on uranium(VI) adsorption to synthetic and natural sediments  

Science Conference Proceedings (OSTI)

Adsorption on soil and sediment solids may decrease aqueous uranium concentrations and limit its propensity for migration in natural and contaminated settings. Uranium adsorption will be controlled in large part by its aqueous speciation, with a particular dependence on the presence of dissolved calcium and carbonate. Here we quantify the impact of uranyl speciation on adsorption to both goethite and sediments from the Hanford Clastic Dike and Oak Ridge Melton Branch Ridgetop formations. Hanford sediments were preconditioned with sodium acetate and acetic acid to remove carbonate grains, and Ca and carbonate were reintroduced at defined levels to provide a range of aqueous uranyl species. U(VI) adsorption is directly linked to UO{sub 2}{sup 2+} speciation, with the extent of retention decreasing with formation of ternary uranyl-calcium-carbonato species. Adsorption isotherms under the conditions studied are linear, and K{sub d} values decrease from 48 to 17 L kg{sup -1} for goethite, from 64 to 29 L kg{sup -1} for Hanford sediments, and from 95 to 51 L kg{sup -1} for Melton Branch sediments as the Ca concentration increases from 0 to 1 mM at pH 7. Our observations reveal that, in carbonate-bearing waters, neutral to slightly acidic pH values ({approx}5) and limited dissolved calcium are optimal for uranium adsorption.

Stewart, B.D. [Stanford University; Mayes, Melanie [ORNL; Fendorf, Scott [ORNL

2010-01-01T23:59:59.000Z

282

Extraction of actinide (III, IV, V, VI) ions and TcO4- byN,N,N',N'- tetraisobutyl-3-oxa-glutaramide  

SciTech Connect

The extraction behavior of U(VI), Np(V), Pu(IV), Am(III), and TcO{sub 4}{sup -} with N, N, N', N'-tetraisobutyl-3-oxa-glutaramide (TiBOGA) were investigated. An organic phase of 0.2 mol/L TiBOGA in 40/60% (V/V) 1-octanol/kerosene showed good extractability for actinides (III, IV, V VI) and TcO{sub 4}{sup -}from aqueous solutions of HNO{sub 3} (0.1 to 4 mol/L). At 25 C, the distribution ratio of the actinide ions (D{sub An}) generally increased as the concentration of HNO{sub 3} in the aqueous phase was increased from 0.1 to 4 mol/L, while the D{sub Tc} at first increased, then decreased, with a maximum of 3.0 at 2 mol/L HNO{sub 3}. Based on the slope analysis of the dependence of D{sub M} (M = An or Tc) on the concentrations of reagents, the formula of extracted complexes were assumed to be UO{sub 2}L{sub 2}(NO{sub 3}){sub 2}, NpO{sub 2}L{sub 2}(NO{sub 3}), PuL(NO{sub 3}){sub 4}, AmL{sub 3}(NO{sub 3}){sub 3}, and HL{sub 2}(TcO{sub 4}) where L = TiBOGA. The enthalpy and entropy of the corresponding extraction reactions, {Delta}{sub r}H and {Delta}{sub r}S, were calculated from the dependence of D on temperature in the range of 15-55 C. For U(VI), Np(V), Am(III) and TcO{sub 4}{sup -}, the extraction reactions are enthalpy driven and disfavored by entropy ({Delta}{sub r}H < 0 and {Delta}{sub r}S < 0). In contrast, the extraction reaction of Pu(IV) is entropy driven and disfavored by enthalpy ({Delta}{sub r}H > 0 and {Delta}{sub r}S > 0). A test run with 0.2 mol/L TiBOGA in 40/60% 1-octanol/kerosene was performed to separate actinides and TcO{sub 4}{sup -} from a simulated acidic high-level liquid waste (HLLW), using tracer amounts of {sup 238}U(VI), {sup 237}Np(V), {sup 239}Pu(VI), {sup 241}Am(III) and {sup 99}TcO{sub 4}{sup -}. The distribution ratios of U(VI), Np(V), Pu(VI), Am(III) and TcO{sub 4}{sup -} were 12.4, 3.9, 87, > 1000 and 1.5, respectively, confirming that TiBOGA is a promising extractant for the separation of all actinides and TcO{sub 4}{sup -} from acidic HLLW. It is noteworthy that the extractability of TiBOGA for Np(V) from acidic HLLW (D{sub Np(V)} = 3.9) is much higher than that of many other extractants that have been studies for the separation of actinides from HLLW.

Tian, Guoxin; Zhang, Ping; Wang, Jianchen; Rao, Linfeng

2005-05-01T23:59:59.000Z

283

NREL Improves Hole Transport in Sensitized CdS-NiO Nanoparticle Photocathodes (Fact Sheet)  

DOE Green Energy (OSTI)

Significantly improved charge-collection efficiencies result from a general chemical approach to synthesizing photocathodes. It has been reported that a dye-sensitized nickel oxide (NiO) photocathode, when coupled to a dye-sensitized photoanode, could significantly increase overall solar conversion efficiency. However, the conversion efficiencies of these cells are still low. There has been much effort to improve the conversion efficiency by fabricating films with improved properties and developing more effective sensitizing dyes for p-type NiO. One of the factors limiting the use of NiO for solar cell application is the low hole conductivity in p-NiO. A team of researchers from the National Renewable Energy Laboratory (NREL) developed a general chemical approach to synthesize NiO-cadmium sulfide (CdS) core-shell nanoparticle films as photocathodes for p-type semiconductor-sensitized solar cells. Compared to dye-sensitized NiO photocathodes, the CdS-sensitized NiO cathodes exhibited two orders of magnitude faster hole transport (attributable to the passivation of surface traps by the CdS) and almost 100% charge-collection efficiencies.

Not Available

2012-01-01T23:59:59.000Z

284

Carbon-Supported IrNi Core-Shell Nanoparticles: Synthesis Characterization and Catalytic Activity  

Science Conference Proceedings (OSTI)

We synthesized carbon-supported IrNi core-shell nanoparticles by chemical reduction and subsequent thermal annealing in H{sub 2}, and verified the formation of Ir shells on IrNi solid solution alloy cores by various experimental methods. The EXAFS analysis is consistent with the model wherein the IrNi nanoparticles are composed of two-layer Ir shells and IrNi alloy cores. In situ XAS revealed that the Ir shells completely protect Ni atoms in the cores from oxidation or dissolution in an acid electrolyte under elevated potentials. The formation of Ir shell during annealing due to thermal segregation is monitored by time-resolved synchrotron XRD measurements, coupled with Rietveld refinement analyses. The H{sub 2} oxidation activity of the IrNi nanoparticles was found to be higher than that of a commercial Pt/C catalyst. This is predominantly due to Ni-core-induced Ir shell contraction that makes the surface less reactive for IrOH formation, and the resulting more metallic Ir surface becomes more active for H{sub 2} oxidation. This new class of core-shell nanoparticles appears promising for application as hydrogen anode fuel cell electrocatalysts.

K Sasaki; K Kuttiyiel; L Barrio; D Su; A Frenkel; N Marinkovic; D Mahajan; R Adzic

2011-12-31T23:59:59.000Z

285

Structural chemistry of some phases in the YC-Ni-B system  

Science Conference Proceedings (OSTI)

NiB, monoclinic Ni{sub 4}B{sub 3}, Ni{sub 2}B and Ni{sub 3}B were prepared by arc-melting and their room-temperature crystal structures were refined by Rietveld analysis of neutron powder diffraction data. The NiB refinement is altogether new data. Although the B atoms in NiB form characteristic zigzag chains, the primary coordination of each atom by atoms of the other kind is similar and distinctively sevenfold, with one short (2.117 {angstrom}), two intermediate (2.152 {angstrom}), and four long (2.163 {angstrom}) bonds. Other samples with stoichiometries (YC)nNi{sub 2}B{sub 2}, n = 3, 4, did not yield single-phase material, but both x-ray and neutron powder diffraction suggest that the n = 4 structure is present in both of these samples. Phase-pure samples of these homologues may require non-stoichiometry and a more controlled thermal history than is attainable by arc melting. To screen samples for superconductivity, ac susceptibility measurements were made using the mutual inductance method with ac signal of 200 Hz.

Chakoumakos, B.C. [Oak Ridge National Lab., TN (United States). Solid State Div.

1994-12-31T23:59:59.000Z

286

Status of vibrational structure in {sup 62}Ni  

Science Conference Proceedings (OSTI)

Measurements consisting of {gamma}-ray excitation functions and angular distributions were performed using the (n,n{sup '{gamma}}) reaction on {sup 62}Ni. The excitation function data allowed us to check the consistency of the placement of transitions in the level scheme. From {gamma}-ray angular distributions, the lifetimes of levels up to {approx}3.8 MeV in excitation energy were extracted with the Doppler-shift attenuation method. The experimentally deduced values of reduced transition probabilities were compared with the predictions of the quadrupole vibrator model and with large-scale shell model calculations in the fp shell configuration space. Two-phonon states were found to exist with some notable deviation from the predictions of the quadrupole vibrator model, but no evidence for the existence of three-phonon states could be established. Z=28 proton core excitations played a major role in understanding the observed structure.

Chakraborty, A.; Orce, J. N.; Ashley, S. F.; Crider, B. P.; Elhami, E.; McEllistrem, M. T.; Mukhopadhyay, S. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506-0055 (United States); Brown, B. A. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Department of Physics and Astronomy, Michigan State University, East Lansing, Michigan 48824 (United States); Peters, E. E. [Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055 (United States); Singh, B. [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, L8S 4M1 (Canada); Yates, S. W. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506-0055 (United States); Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055 (United States)

2011-03-15T23:59:59.000Z

287

U.S. DEPARTMENT OF l!Nl!RGY EERE PROJECT MANAGEMENT CENTER Nl!PA DETl!la.llNATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nl!PA DETl!la.llNATION Nl!PA DETl!la.llNATION RECIPIENT:lmpact Technologies llC PROJECf TITLE : Deep Geothermal Drilling using Millimeter Wave Technology Page 1 of2 STATE: OK Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number em Number DE-FOA-OOOOS22 DE-EEOOO5504 GFO-OOO5504-OO1 G05504 Based on my review or lhe infonnation concerning the proposed action, as NEPA Compliance OtrlCCf (authorized unde r DOE OTdu451.IA), I have made the following determination: ex, EA, EIS APPENDIX AND NUMBER: Description: A9 Information gathering, analysis, and dissemination Information gathering (induding. but not limited to. literature surveys, inventories, site visits, and audits), data analysis (induding. but not limited 10, computer modeling), document preparation (induding. bul nollimited to, conceptual design,

288

Implications of NiMH Hysteresis on HEV Battery Testing and Performance  

SciTech Connect

Nickel Metal-Hydride (NiMH) is an advanced high-power battery technology that is presently employed in Hybrid Electric Vehicles (HEVs) and is one of several technologies undergoing continuing research and development by FreedomCAR. Unlike some other HEV battery technologies, NiMH exhibits a strong hysteresis effect upon charge and discharge. This hysteresis has a profound impact on the ability to monitor state-of-charge and battery performance. Researchers at the Idaho National Engineering and Environmental Laboratory (INEEL) have been investigating the implications of NiMH hysteresis on HEV battery testing and performance. Experimental results, insights, and recommendations are presented.

Motloch, Chester George; Belt, Jeffrey R; Hunt, Gary Lynn; Ashton, Clair Kirkendall; Murphy, Timothy Collins; Miller, Ted J.; Coates, Calvin; Tataria, H. S.; Lucas, Glenn E.; Duong, T.Q.; Barnes, J.A.; Sutula, Raymond

2002-08-01T23:59:59.000Z

289

Giant Magnetoresistance In Ni/Cu Multilayers Fabricated By Electron-Beam Evaporation  

Science Conference Proceedings (OSTI)

Electron beam evaporation technique has been used to deposit the multilayers of Ni-Cu, represented by Si[BL{sub t}/[Ni(t{sub FM})/Cu(t{sub NM})]xn] where Si is used as a substrate and BL is buffer layer, n is the number of bilayers, t, t{sub FM} and t{sub NM} are thicknesses of buffer layer, ferromagnetic (Ni) and nonmagnetic (Cu) layers, respectively. We characterize the multilayers using M-H curves, magnetoresistance measurement (at room temperature)

Vikram, V.; Rahman, Md. Rizwanur; Katiyar, Monica [Department of Materials and Metallurgical Engineering Indian Institute of Technology Kanpur, Uttar Pradesh, 208016 (India)

2008-04-24T23:59:59.000Z

290

Electrochemical and in situ neutron diffraction investigations of La-Ni-Al-H alloys  

DOE Green Energy (OSTI)

Li/metal hydride batteries are a strong contender to replace Ni/Cd batteries. Since the role of alloying components is not yet understood, a combination of electrochemical and neutron diffraction techniques has been designed to investigate metal hydrides. In this work, several Al-substituted LaNi{sub 5} alloys were investigated for their specific capacity (measured by mAh/La and symbolized by x in LaNi{sub 5-y}Al{sub y}H{sub x}), impedance, and cycling stability. Neutron diffraction was used to study the electrochemically induced phase transformation and structure change during charge/discharge.

Peng, W. [Illinois Institute of Technology (United States); Redey, L.; Vissers, D.R.; Myles, K.M.; Carpenter, J.; Richardson; Burr, G. [Argonne National Lab., IL (United States)

1996-05-01T23:59:59.000Z

291

Phonon densities of states of face-centered-cubic Ni-Fe alloys  

Science Conference Proceedings (OSTI)

Inelastic neutron scattering and nuclear resonant inelastic x-ray scattering were used to determine the phonon densities of states of face-centered-cubic Ni-Fe alloys. Increasing Fe concentration results in an average softening of the phonon modes. Chemical ordering of the Ni0.72Fe0.28 alloy results in a reduction of the partial vibrational entropy of the Fe atoms but does not significantly change the partial vibrational entropy of the Ni atoms. Changes in the phonon densities of states with composition and chemical ordering are discussed and analyzed with a cluster expansion method.

Lucas, Matthew [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Mauger, L [California Institute of Technology, W. M. Keck Laboratory, Pasadena] [California Institute of Technology, W. M. Keck Laboratory, Pasadena; Munoz, Jorge A. [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena; Halevy, I [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena; Horwath, J [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Semiatin, S L [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Leontsev, S. O. [University of Kentucky, Lexington] [University of Kentucky, Lexington; Stone, Matthew B [ORNL] [ORNL; Abernathy, Douglas L [ORNL] [ORNL; Xiao, Yuming [Carnegie Institution of Washington] [Carnegie Institution of Washington; Chow, P [HPCAT Geophysical Lab, Argonne, IL] [HPCAT Geophysical Lab, Argonne, IL; Fultz, B. [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena

2013-01-01T23:59:59.000Z

292

Phase-Field Modeling of Microstructure Evolution for Ni-Base ...  

Science Conference Proceedings (OSTI)

First Principles Modeling of Shape Memory Alloy Magnetic Refrigeration Materials ... of Lithium Battery Materials LiMPO4 (M = Mn, Fe, Co, and Ni): A Comparative ... Forming-Crush Simulation Optimization Using Internal State Variable Model.

293

NiTiHf High-Temperature Shape-Memory Alloys for near Term ...  

Science Conference Proceedings (OSTI)

Development of a SMA-Based Drive Unit for Prehension Orthoses to Support Disabled People Effect of H in Metals and Alloys: An Application to bcc W and NiTi...

294

Thermo-Mechanical Behavior of Cu-Al-Ni SMA for High ...  

Science Conference Proceedings (OSTI)

Development of a SMA-Based Drive Unit for Prehension Orthoses to Support Disabled People Effect of H in Metals and Alloys: An Application to bcc W and NiTi...

295

Structure-Property Relationships for Ni-Ti-Pt High Temperature ...  

Science Conference Proceedings (OSTI)

Development of a SMA-Based Drive Unit for Prehension Orthoses to Support Disabled People Effect of H in Metals and Alloys: An Application to bcc W and NiTi...

296

Hf-Doped Ni-Al2O3 Interfaces at Equilibrium  

SciTech Connect

In this study, a series of dewetting experiments of pure and Hf-doped Ni films on sapphire and HfO2 substrates were conducted in order to measure the change in interface energy of the Ni-Al2O3 interface in the presence of Hf, and to study Hf interfacial segregation. It was found that Hf oxidizes under the conditions of the experiment (P(O2)=10-20atm.), and that the presence of HfO2 at the Ni-Al2O3 interface increases the interface energy from 2.16 0.2 to 2.7 0.4 [J/m2]. This result contradicts several theoretical studies that predict that Hf segregates to the interface to stabilize it thermodynamically. The solubility of Hf in bulk Ni was found to be significantly lower than the value reported in the equilibrium phase diagram.

Meltzman, Hila [Technion, Israel Institute of Technology; Besmann, Theodore M [ORNL; Kaplan, Prof. Wayne D. [Technion, Israel Institute of Technology

2012-01-01T23:59:59.000Z

297

Absence of long-range chemical ordering in equimolar FeCoCrNi  

Science Conference Proceedings (OSTI)

Equimolar FeCoCrNi alloys have been the topic of recent research as 'high-entropy alloys,' where the name is derived from the high configurational entropy of mixing for a random solid solution. Despite their name, no systematic study of ordering in this alloy system has been performed to date. Here, we present results from anomalous x-ray scattering and neutron scattering on quenched and annealed samples. An alloy of FeNi{sub 3} was prepared in the same manner to act as a control. Evidence of long-range chemical ordering is clearly observed in the annealed FeNi{sub 3} sample from both experimental techniques. The FeCoCrNi sample given the same heat treatment lacks long-range chemical order.

Lucas, M. S. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); UTC Inc., 1270 North Fairfield Road, Dayton, Ohio 45432 (United States); Wilks, G. B.; Senkov, O. N. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); UES, Inc., 4401 Dayton-Xenia Rd., Dayton, Ohio 45432 (United States); Mauger, L.; Munoz, J. A. [California Institute of Technology, W. M. Keck Laboratory 138-78, Pasadena, California 91125 (United States); Michel, E. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Wright State University, Dayton, Ohio 45435 (United States); Horwath, J.; Semiatin, S. L. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Stone, M. B.; Abernathy, D. L. [Oak Ridge National Laboratory, 1, Bethel Valley Road, Oak Ridge, Tennessee 37831 (United States); Karapetrova, E. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2012-06-18T23:59:59.000Z

298

Controlling Activity and Stability of Ni-YSZ Catalysts for On-Anode Reforming  

DOE Green Energy (OSTI)

The purposes of the project are to develop an effective Ni-YSZ-based anode for on-anode reforming of methane and natural gas and develop methods to control endothermic steam reforming activity.

King, D.L.; Wang, Y.; Chin, Y-H.; Lin, Y.; Roh, H-S.; Rozmiarek, B.

2005-01-27T23:59:59.000Z

299

Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition  

E-Print Network (OSTI)

LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

Xia, Hui

300

E14: Grain Boundary Misorientation Statistics in Polycrystalline Ni-Bi  

Science Conference Proceedings (OSTI)

B7: Synthesis and Electrical Properties of K2NiF4-Type (Ca2-xLnx)MnO4 (Ln=Nd and Sm) B8: Monitoring Oxygen Diffusion in Gd-Doped Ceria by Null...

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Ni-Si Alloys for the S-I Reactor-Hydrogen Production Process Interface  

DOE Green Energy (OSTI)

The overall goal of this project was to develop Ni-Si alloys for use in vessels to contain hot, pressurized sulfuric acid. The application was to be in the decomposition loop of the thermochemical cycle for production of hydrogen.

Joseph W. Newkirk; Richard K. Brow

2010-01-21T23:59:59.000Z

302

Study of gamma cascades of 59Ni by thermal neutron reaction  

E-Print Network (OSTI)

The quantum properties are important to study nuclear structure. The energy, spin, parity, transition order are usually interesting to research. In this experiment, 59Ni is activated by thermal neutron on 3rd horizontal channel of Dalat nuclear Reactor.

Nguyen An Son

2013-10-07T23:59:59.000Z

303

Investigation of the Partition Coefficient in the Ni-Fe-Nb Alloys: A ...  

Science Conference Proceedings (OSTI)

*West Virginia University WV, USA, Universidad del Valle, Cali-Colombia ... The Nb containing Ni-based superalloys used for the production of large ... land based gas turbines. ... quenching oil bath in the bottom of the alumina tube furnace as.

304

Graphene-on-Insulator Transistors Made Using C on Ni Chemical-Vapor Deposition  

E-Print Network (OSTI)

Graphene transistors are made by transferring a thin graphene film grown on Ni onto an insulating SiO[subscript 2] substrate. The properties and integration of these graphene-on-insulator transistors are presented and ...

Keast, Craig L.

305

Stability of Ni-Nb-based and Zr-based bulk metallic glasses against environmental degradation.  

E-Print Network (OSTI)

???The ternary (Ni8Nb5)99.5Sb0.5 bulk metallic glass (BMG) was synthesized in this thesis and the corrosion, oxidation and high temperature induced crystallization behaviors are investigated. The (more)

L, Junxia (???)

2009-01-01T23:59:59.000Z

306

Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system  

SciTech Connect

NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

Teng, Zhenke [ORNL; Zhang, F [CompuTherm LLC, Madison, WI; Miller, Michael K [ORNL; Liu, Chain T [Hong Kong Polytechnic University; Huang, Shenyan [ORNL; Chou, Y.T. [Multi-Phase Services Inc., Knoxville; Tien, R [Multi-Phase Services Inc., Knoxville; Chang, Y A [ORNL; Liaw, Peter K [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

307

3D-FEM Calculations of Rafting in Ni-Base Superalloys Based on ...  

Science Conference Proceedings (OSTI)

of Ni-base superalloys, these belong to 1st, 2nd, and 3rd generation, have been .... [15] A narrow temperature distribution is also expected with the use of one...

308

Ab Initio Studies of Coke Formation on Ni Catalysts During Methane Reforming  

SciTech Connect

The atomic-scale processes that control the formation of carbon deposits on Ni catalysts in reforming applications are poorly understood. Ab initio Density Functional Theory calculations have been used to examine several key elementary steps in the complex network of chemical reactions that precedes carbon formation on practical catalysts. Attention has been focused on the disproportionation of CO. A comparative study of this reaction on flat and stepped crystal planes of Ni has provided the first direct evidence that surface carbon formation is driven by elementary reactions occurring at defect sites on Ni catalysts. The adsorption and diffusion of atomic H on several flat and stepped Ni surfaces has also been characterized experimentally.

David S. Sholl

2006-03-05T23:59:59.000Z

309

AB INITIO STUDIES OF COKE FORMATION ON NI CATALYSTS DURING METHANE REFORMING  

SciTech Connect

The atomic-scale processes that control the formation of carbon deposits on Ni catalysts in reforming applications are poorly understood. Ab initio Density Functional Theory calculations have been used to examine several key elementary steps in the complex network of chemical reactions that precedes carbon formation on practical catalysts. Attention has been focused on the disproportionation of CO. A comparative study of this reaction on flat and stepped crystal planes of Ni has provided the first direct evidence that surface carbon formation is driven by elementary reactions occurring at defect sites on Ni catalysts. The adsorption and diffusion of atomic H on several flat and stepped Ni surfaces has also been characterized experimentally.

David S. Sholl

2004-09-25T23:59:59.000Z

310

F-3: Hydrogen Storage Properties of Graphite-modified MgNiCe ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The Mg17Ni1.5Ce0.5 hydrogen storage composites with different contents of graphite were prepared by a new method of mechanical milling...

311

Evaluation of the Ni 3 Al Base Alloys IC221 and IC218LZr  

Science Conference Proceedings (OSTI)

National Laboratory (ORNL). This paper deals with properties of the two Ni Al base alloys, IC218LZr and IC221 whose compositions are given in Table I. These ...

312

Development of Co-Free Ni-Base Superalloy for HTGR  

Science Conference Proceedings (OSTI)

Co-free Ni-base superalloy which can be used for heat exchanger tube in high temper- ature helium gas cooled reactor. The effects of Cr, W and No as solution.

313

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

Science Conference Proceedings (OSTI)

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and ycapacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

314

Variation of electrical resistance in superelastic NiTi for sensor applications  

E-Print Network (OSTI)

Nickel-Titanium (NiTi) is a most commonly known as a heat-activated shape memory alloy. However, the material sometimes displays a constant-temperature property called "superelasticity." A superelastic material is one which ...

Russo, Analisa

2008-01-01T23:59:59.000Z

315

Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion  

DOE Patents (OSTI)

A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

1984-01-01T23:59:59.000Z

316

Towards the photoreduction of CO{sub 2} with Ni(bpy){sub n}{sup 2+} complexes  

DOE Green Energy (OSTI)

When an acetonitrile solution containing Ni(bpy){sub 3}{sup 2+}, trithylamine and CO{sub 2} is irradiated at 313 nm, CO is produced with a quantum yield {approximately} 0.1% (defined as CO produced/photons absorbed). Flash photolysis, electrochemistry, and pulse radiolysis experiments provide evidence for the formation of Ni{sup I}(bpy){sub 2+}, as an intermediate, in the photochemical Ni(bpy){sub 3}{sup 2+}/TEA/CO{sub 2} system. Although Ni{sup 0}(bpy){sub 2} does react with CO{sub 2}, Ni{sup I}(bpy){sub 2+} seems unreactive toward CO{sub 2} addition. The x-ray structure of [Ni{sub 3}(bpy){sub 6}](ClO{sub 4}), which crystallize as blue-violet needles, reveals the existence of a dimer in the solid. UV-vis spectra also indicate that reduced Ni(bpy){sub 3}{sup 2+} solutions contain Ni{sup I}(bpy){sub 2+}, Ni{sup 0}(bpy){sub 2} and [Ni(bpy){sub 2}]{sub 2} complexes in equilibrium.

Mori, Y.; Szalda, D.J.; Brunschwig, B.S.; Schwarz, H.A.; Fujita, E.

1995-08-01T23:59:59.000Z

317

Characteristics and effects of {gamma}-NiOOH on cell performance and a method to quantify it in nickel electrodes  

SciTech Connect

This study describes the characteristics and effects of gamma ({gamma})-NiOOH on cell performance and a method to quantify it in NiCd and NiMH battery systems. {gamma}-NiOOH is formed in nickel electrodes under conditions of aging, high percent overcharge, charge rates, and electrolyte concentrations. Formation of this phase results in swelling of the nickel electrode and leads to possible shorting due to fracturing. The fracturing of particles results in increased surface area. It also plays a role in drying the separator. All of these factors lead to cycle-life failure. These failure characteristics were measured in a NiCd cell as a function of charge and discharge cycles. A method to quantify {gamma}-NiOOH using x-ray diffraction was developed. It was found that the integrated peak intensities obtained from the 003 peak of {gamma}-NiOOH were approximately three times greater than that of the 001 peak of {beta}-NiOOH. These peaks were used since they were related to the highest intensities. This information was used in calculating the ratio of {gamma}/{gamma}+ {beta} in a charged NiOOH electrode. This technique allows one to quantify the amount of {gamma}-NiOOH as a function of cycles, rates, and different depths of discharge.

Singh, D. [Energizer Power Systems, Gainesville, FL (United States)

1998-01-01T23:59:59.000Z

318

Water-Gas Shift and CO Methanation Reactions over Ni-CeO2(111) Catalysts  

Science Conference Proceedings (OSTI)

X-ray and ultraviolet photoelectron spectroscopies were used to study the interaction of Ni atoms with CeO2(111) surfaces. Upon adsorption on CeO2(111) at 300 K, nickel remains in a metallic state. Heating to elevated temperatures (500 800 K) leads to partial reduction of the ceria substrate with the formation of Ni2? species that exists as NiO and/or Ce1-xNixO2-y. Interactions of nickel with the oxide substrate significantly reduce the density of occupied Ni 3d states near the Fermi level. The results of core-level photoemission and near-edge X-ray absorption fine structure point to weakly bound CO species on CeO2(111) which are clearly distinguishable from the formation of chemisorbed carbonates. In the presence of Ni, a stronger interaction is observed with chemisorption of CO on the admetal. When the Ni is in contact with Ce?3 cations, CO dissociates on the surface at 300 K forming NiCx compounds that may be involved in the formation of CH4 at higher temperatures. At medium and large Ni coverages ([0.3 ML), the Ni/CeO2(111) surfaces are able to catalyze the production of methane from CO and H2, with an activity slightly higher than that of Ni(100) or Ni(111). On the other hand, at small coverages of Ni (\\0.3 ML), the Ni/CeO2(111) surfaces exhibit a very low activity for CO methanation but are very good catalysts for the water gas shift reaction.

Senanayake, Sanjaya D [ORNL; Evans, Jaime [Universidad Central de Venezuela; Agnoli, Stefano [Brookhaven National Laboratory (BNL); Barrio, Laura [Brookhaven National Laboratory (BNL); Chen, Tsung-Liang [ORNL; Hrbek, Jan [Brookhaven National Laboratory (BNL); Radriguez, Jose [Brookhaven National Laboratory (BNL)

2011-01-01T23:59:59.000Z

319

Experimental determination and thermodynamic modeling of the Ni-Re binary system  

Science Conference Proceedings (OSTI)

The phase diagram of the Ni-Re binary system has been partially reinvestigated by chemical, structural and thermal characterization of the arc melted alloys. The experimental results obtained during the present investigation were combined with the literature data and a new phase diagram of the Ni-Re binary system is proposed. In comparison with the Ni-Re phase diagram proposed by Nash et al. in 1985 [1], significant differences in the homogeneity domains, freezing ranges and peritectic reaction temperature were evidenced. On the other hand, thermodynamic modeling of the studied system by using the new experimental information has also been carried out with the help of the CALPHAD method. The calculated Ni-Re phase diagram showed a good agreement with the selected experimental information. - Graphical abstract: Ni-Re phase diagram according to the present study. Highlights: Black-Right-Pointing-Pointer Re-investigation of the Ni-Re phase diagram. Black-Right-Pointing-Pointer Extended phase field of the hcp phase. Black-Right-Pointing-Pointer Different freezing ranges and peritectic reaction temperature. Black-Right-Pointing-Pointer Thermodynamic modeling of the studied system by using the CALPHAD method.

Yaqoob, Khurram [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)] [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France); Joubert, Jean-Marc, E-mail: jean-marc.joubert@icmpe.cnrs.fr [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)] [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)

2012-12-15T23:59:59.000Z

320

EFFECT OF FUEL IMPURITY ON STRUCTURAL INTEGRITY OF Ni-YSZ ANODE OF SOFCs  

SciTech Connect

Electricity production through the integration of coal gasification with solid oxide fuel cells (SOFCs) may potentially be an efficient technique for clean energy generation. However, multiple minor and trace components are naturally present in coals. These impurities in coal gas not only degrade the electrochemical performance of Ni-YSZ anode used in SOFCs, but also severely endanger the structural integrity of the Ni-YSZ anode. In this paper, effect of the trace impurity of the coal syngases on the mechanical degradation of Ni-YSZ anode was studied by using an integrated experimental/modeling approach. Phosphorus is taken as an example of impurity. Anode-support button cell was used to experimentally explore the migration of phosphorous impurity in the Ni-YSZ anode of SOFCs. X-ray mapping was used to show elemental distributions and new phase formation. The subsequent finite element stress analyses were conducted using the actual microstructure of the anode to illustrate the degradation mechanism. It was found that volume expansion induced by the Ni phase change produces high stress level such that local failure of the Ni-YSZ anode is possible under the operating conditions

Liu, Wenning N.; Sun, Xin; Marina, Olga A.; Pederson, Larry R.; Khaleel, Mohammad A.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Endophytic bacteria improve phytoremediation of Ni and TCE co-contamination  

Science Conference Proceedings (OSTI)

The aim of this work was to investigate if engineered endophytes can improve phytoremediation of co-contaminations by organic pollutants and toxic metals. As a model system, yellow lupine was inoculated with the endophyte Burkholderia cepacia VM1468 possessing (a) the pTOM-Bu61 plasmid, coding for constitutive trichloroethylene (TCE) degradation, and (b) the ncc-nre Ni resistance/sequestration system. Plants were exposed to Ni and TCE and (a) Ni and TCE phytotoxicity, (b) TCE degradation and evapotranspiration, and (c) Ni concentrations in the roots and shoots were determined. Inoculation with B. cepacia VM1468 resulted in decreased Ni and TCE phytotoxicity, as measured by 30% increased root biomass and up to 50% decreased activities of enzymes involved in anti-oxidative defence in the roots. In addition, TCE evapotranspiration showed a decreasing trend and a 5 times higher Ni uptake was observed after inoculation. Engineered endophytes can improve phytoremediation of mixed contaminations via enhanced degradation of organic contaminants and improved metal uptake and translocation.

Weyens, N.; van der Lelie, D.; Croes, S.; Dupae, J.; Newman, L.; Carleer, R.; Vangronsveld, J.

2010-07-01T23:59:59.000Z

322

Metallic glass alloys of Zr, Ti, Cu and Ni  

DOE Patents (OSTI)

At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

1997-01-01T23:59:59.000Z

323

The hydrogen embrittlement of Ni-Cr-Fe alloys  

Science Conference Proceedings (OSTI)

It has been proposed that the stress corrosion cracking (SCC) of nickel-based alloys in low-temperature hydrogenated water is due to hydrogen embrittlement. The purpose of this work was to investigate the role of chromium on hydrogen embrittlement of Ni-Cr-Fe alloys and thus develop a better understanding of the low-temperature SCC phenomenon. The effect of chromium on the hydrogen embrittlement was examined using tensile tests followed by material evaluation via scanning electron microscopy and light optical microscopy. Four alloys were prepared with chromium contents ranging from 6 wt. percent to 35 wt. percent. In the noncharged condition, ductility, as measured by the percent elongation or reduction in area, increased as the alloy chromium content increased. Hydrogen appeared to have only minor effects on the mechanical properties of the low chromium alloys. The addition of hydrogen had a marked effect on the ductility of the higher chromium alloys. In the 26% chromium alloy, the elongation to failure was reduced from 53% to 14% with a change in fracture mode from ductile dimple to intergranular failure. A maximum in embrittlement was observed in the 26% Cr alloy. The maximum in embrittlement coincided with the minimum in stacking-fault energy. It is proposed that the increased hydrogen embrittlement in the high-chromium alloys is due to increased slip planarity caused by the low stacking-fault energy. Slip planarity did not appear to affect the fracture of the noncharged specimens.

Symons, D.M.

1996-12-31T23:59:59.000Z

324

Development of a biomarker for Geobacter activity and strain composition: Proteogenomic analysis of the citrate synthase protein during bioremediation of U(VI)  

SciTech Connect

Monitoring the activity of target microorganisms during stimulated bioremediation is a key problem for the development of effective remediation strategies. At the US Department of Energy's Integrated Field Research Challenge (IFRC) site in Rifle, CO, the stimulation of Geobacter growth and activity via subsurface acetate addition leads to precipitation of U(VI) from groundwater as U(IV). Citrate synthase (gltA) is a key enzyme in Geobacter central metabolism that controls flux into the TCA cycle. Here, we utilize shotgun proteomic methods to demonstrate that the measurement of gltA peptides can be used to track Geobacter activity and strain evolution during in situ biostimulation. Abundances of conserved gltA peptides tracked Fe(III) reduction and changes in U(VI) concentrations during biostimulation, whereas changing patterns of unique peptide abundances between samples suggested sample-specific strain shifts within the Geobacter population. Abundances of unique peptides indicated potential differences at the strain level between Fe(III)-reducing populations stimulated during in situ biostimulation experiments conducted a year apart at the Rifle IFRC. These results offer a novel technique for the rapid screening of large numbers of proteomic samples for Geobacter species and will aid monitoring of subsurface bioremediation efforts that rely on metal reduction for desired outcomes.

Wilkins, M.J.; Callister, S.J.; Miletto, M.; Williams, K.H.; Nicora, C.D.; Lovley, D.R.; Long, P.E.; Lipton, M.S.

2010-02-15T23:59:59.000Z

325

Gradual localization of Ni 3d states in LaNiO3 ultrathin films induced by dimensional crossover  

Science Conference Proceedings (OSTI)

In situ photoemission spectroscopy and x-ray absorption spectroscopy (XAS) have been performed on LaNiO3 (LNO) ultrathin films grown on LaAlO3 substrates to investigate the origin of the thickness-dependent metalinsulator transition (MIT). With decreasing film thickness, the progressive weakening of a quasiparticle peak at the Fermi level (EF ) occurs below 10 monolayer (ML), and the further depletion of spectral weight at EF leads to pseudogap behavior at 3 6 ML. The pseudogap finally evolves into a full gap, indicating that the thickness-dependent MIT takes place at a critical film thickness of 2 3 ML. The observed spectral behavior is in line with the transport properties of LNO ultrathin films. The thickness dependence of the spectral intensity is compared with realistic multiorbital dynamical mean-field theory. The experimental spectral function was found to depend on the film thickness more strongly than the theoretical one for thinner systems, indicating that the thickness-dependent MIT in LNO is caused by the crossover from three to two dimensions, during which the spatial correlations are progressively enhanced. The XAS results suggest that a charge disproportionate state is strongly suppressed in LNO ultrathin films plausibly as a result of epitaxial strain from the substrates. These results strongly suggest that a novel insulating state is realized in LNO films at a thin limit.

Sakai, E. [University of Tokyo, Tokyo, Japan; Tamamitsu, M. [University of Tokyo, Tokyo, Japan; Yoshimatsu, K [University of Tokyo, Tokyo, Japan; Okamoto, Satoshi [ORNL; Horiba, K. [University of Tokyo, Tokyo, Japan; Oshima, M [University of Tokyo, Tokyo, Japan; Kumigashira, H [University of Tokyo, Tokyo, Japan

2013-01-01T23:59:59.000Z

326

Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys  

E-Print Network (OSTI)

The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase transformation in NiMnCoIn alloys. The ultimate goal of utilizing these mechanisms is to increase the actuation stress levels in magnetic shape memory alloys (MSMAs). Extensive experimental work on magneto-thermo-mechanical (MTM) characterization of these materials enabled us to i) better understand the ways to increase the actuation stress and strain and decrease the required magnetic field for actuation in MSMAs, ii) determine the effects of main MTM parameters on reversible magnetic field induced phase transformation, such as magnetocrystalline anisotropy energy (MAE), Zeeman energy (ZE), stress hysteresis, thermal hysteresis, critical stress for the stress induced phase transformation and crystal orientation, iii) find out the feasibility of employing polycrystal MSMAs, and iv) formulate a thermodynamical framework to capture the energetics of magnetic field-induced phase transformations in MSMAs. Magnetic shape memory properties of Ni2MnGa single crystals were characterized by monitoring magnetic field-induced strain (MFIS) as a function of compressive stress and stress-induced strain as a function of magnetic field. It is revealed that the selection of the operating temperature with respect to martensite start and Curie temperatures is critical in optimizing actuator performance. The actuation stress of 5 MPa and work output of 157 kJm?3 are obtained by the field-induced variant reorientation in NiMnGa alloys. Reversible and one-way stress-assisted field-induced phase transformations are observed in Ni2MnGa single crystals under low field magnitudes (transformation and shape memory characteristics of NiMnCoIn single crystals are also studied. Reversible field-induced phase transformation is observed only under high magnetic fields (>4T). Necessary magnetic and mechanical conditions, and materials design and selection guidelines are proposed to search for field-induced phase transformation in other ferromagnetic materials that undergo thermoelastic martensitic phase transformation.

Karaca, Haluk Ersin

2007-08-01T23:59:59.000Z

327

e vi rot  

Science Conference Proceedings (OSTI)

... before the peak was reached. The time-temperature curve of covered cigarettes was somewhat broader but showed the same peaks as uncovered ...

2013-02-25T23:59:59.000Z

328

Certain aspects of the melting, casting and welding of Ni{sub 3}Al alloys  

Science Conference Proceedings (OSTI)

Two alloys under development for castings are IC221M, (nominal composition Ni-8Al-7.7Cr-1.4Mo-1.7Zr wt %), and IC396M (nominal composition Ni-8Al-7.7Cr-3Mo-0.85Zr wt %). These alloys can be melted and cast using the techniques normally used for Ni-based materials. Oxidation of the liquid alloys can be controlled by vacuum processing or inert gas cover during processing. The liquid alloys can react with silica and zircon sands during casting, but this can be controlled through the use of appropriate mold washes like carbon-based materials. Welding studies showed that these alloys are susceptible to solidification cracking in weld fusion zones; the cracks are generally associated with occurrence of Ni-Ni{sub 5}Zr eutectic in interdendritic regions of the weld. Amount of eutectic in the weld microstructures increases with Zr concentration in weld filler metal. Weld filler metal Zr concentrations of 3 wt % and higher prevented solidification cracking of weld deposits on the base casting alloys; This is consistent with accepted phenomonological theory of this process. A weld filler metal with a composition of Ni-8Al-7.7Cr-1.5Mo-3.0Zr wt % was prepared and used to gas tungsten arc weld together 15-mm-thick plates of the IC221M alloy. This weldment was free of cracks. Weldment tensile specimens were machined from the plate and tested at 21, 800, and 900 C. Weldment yield strength at elevated temperatures was higher than room temperature and nearly comparable with that of the base IC221M alloy. Evaluation of the cast Ni{sub 3}Al alloys for furnace furniture, turbocharger rotors, and manufacturing tooling is also briefly discussed.

Santella, M.L.; Sikka, V.K.

1994-06-01T23:59:59.000Z

329

Reducing the deactivation of Ni-metal during the catalytic partial oxidation of a surrogate diesel fuel mixture  

SciTech Connect

Ni catalysts are active and selective for the conversion of hydrocarbon into synthesis gas. However, conventional supported Ni catalysts rapidly deactivate at the high temperatures required for partial oxidation of diesel fuel by sintering and metal vaporization, as well as by carbon deposition and sulfur poisoning. Thus, to reduce deactivation Ni (3 wt%) was substituted into the structures of Ba-hexaaluminate (BNHA) and LaSrZr pyrochlore (LSZN), and their activity was compared to a supported Ni/Al2O3 for the catalytic partial oxidation (CPOX) of a surrogate diesel fuel. Characterization by XRD showed a single phase #2;-alumina for the hexaaluminate, while LSZN had a pyrochlore structure with a defect SrZrO3 perovskite phase. Temperature programmed reduction experiments confirmed Ni was reducible in all catalysts. XANES results confirmed that Ni atoms were substituted into the hexaaluminate and pyrochlore structures, as spectra for each catalyst showed different coordination environments for Ni compared to a NiO standard. During CPOX activity tests (T = 900 ?C and WHSV= 50,000 scc/gcat/h), the LSZN pyrochlore produced stable H2 and CO yields in the presence of 5 wt% 1-methylnaphthalene and 50ppmw dibenzothiophene/n-tetradecane for 2 h, while both Ni/Al2O3 and BNHA catalysts were irreversibly deactivated by this mixture over the same time. Activity loss was strongly linked to carbon formation.

Haynes, D.; Campos, A.; Smith, M.; Berry, D.; Shekhawat, D.; Spivey, J.

2010-01-01T23:59:59.000Z

330

Metallic glass alloys of Zr, Ti, Cu and Ni  

DOE Patents (OSTI)

At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3} K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM{sub 1{minus}x}Ti{sub x}){sub a} Cu{sub b} (Ni{sub 1{minus}y}Co{sub y}){sub c} wherein x is from 0.1 to 0.3, y{center_dot}c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b. 2 figs.

Lin, X.; Peker, A.; Johnson, W.L.

1997-04-08T23:59:59.000Z

331

Purification and Characterization of [NiFe]-Hydrogenase of Shewanella oneidensis MR-1  

SciTech Connect

The ?-proteobacterium Shewanella oneidensis MR-1 possesses a periplasmic [NiFe]-hydrogenase (MR-1 [NiFe]-H2ase) that was implicated in both H2 production and oxidation as well as technetium [Tc(VII)] reduction. To characterize the roles of MR-1 [NiFe]-H2ase in these proposed reactions, the genes encoding both subunits of MR-1 [NiFe]-H2ase were cloned into a protein expression vector. The resulting plasmid was transformed into a MR-1 mutant deficient in H2 formation. Expression of MR-1 [NiFe]-H2ase in trans restored the mutants ability to produce H2 at 37% of that for wild type. Following expression, MR-1 [NiFe]-H2ase was purified to near homogeneity. The purified MR-1 [NiFe]-H2ase could couple H2 oxidation to reduction of Tc(VII) and methyl viologen directly. Change of the buffers used affected MR-1 [NiFe]-H2ase-mediated Tc(VII) but not methyl viologen reductions. Under the conditions tested, Tc(VII) reduction was complete in Tris buffer but not in HEPES buffer. The reduced Tc(IV) was soluble in Tris buffer but insoluble in HEPES buffer. Transmission electron microscopy analysis revealed that Tc(IV) precipitates formed in HEPES buffer were packed with crystallites. Although X-ray absorption near-edge spectroscopy measurements confirmed that the reduction products found in both buffers were Tc(IV), extended X-ray adsorption fine-structure measurements revealed that these products were very different. While the product in Tris buffer could not be determined, the Tc(IV) product in HEPES buffer was very similar to Tc(IV)O2nH2O. These results shows for the first time that MR-1 [NiFe]-H2ase is a bidirectional enzyme that catalyzes both H2 formation and oxidation as well as Tc(VII) reduction directly by coupling H2 oxidation.

Shi, Liang; Belchik, Sara M.; Plymale, Andrew E.; Heald, Steve M.; Dohnalkova, Alice; Sybirna, Kateryna; Bottin, Herve; Squier, Thomas C.; Zachara, John M.; Fredrickson, Jim K.

2011-08-02T23:59:59.000Z

332

In situ variable temperature X-ray diffraction studies on the transformations of nano-precursors to La-Ni-O phases  

SciTech Connect

In situ variable temperature XRD (VT-XRD) measurements on the transformation of nano-precursors to La-Ni-O phases are presented. Experimental results showed that LaNiO{sub 3} and La{sub 2}NiO{sub 4} phases were formed at ca. 700 deg. C via the reaction of La{sub 2}O{sub 3} and NiO (from the initial nano-precursors), where a relatively low temperature of 700 deg. C was found for the synthesis of La{sub 2}NiO{sub 4}. The formation of La{sub 3}Ni{sub 2}O{sub 7} at higher temperature (up to 1150 deg.C) appeared to proceed through a further reaction of La{sub 2}NiO{sub 4} with unreacted NiO, whilst the formation of La{sub 4}Ni{sub 3}O{sub 10} (at 1075 deg. C) proceeded via a further decomposition of LaNiO{sub 3}. Although phase pure La{sub 3}Ni{sub 2}O{sub 7} and La{sub 4}Ni{sub 3}O{sub 10} were not directly obtained under the processing conditions herein, the results of this study allow for a better understanding of formation pathways, particularly for the higher order La-Ni-O phases. - Graphical abstract: In situ variable temperature XRD showing the phase formation pathway of La{sub n+1}Ni{sub n}O{sub 3n+1} at evaluated temperatures. Highlights: > In situ VT-XRD was utilized to study the pathways for La{sub n+1}Ni{sub n}O{sub 3n+1} formations. > LaNiO{sub 3} and La{sub 2}NiO{sub 4} phases were formed via the reaction of La{sub 2}O{sub 3} and NiO, respectively. > La{sub 3}Ni{sub 2}O{sub 7} phase was formed via further reaction of La{sub 2}NiO{sub 4} phase with unreacted NiO. > La{sub 4}Ni{sub 3}O{sub 10} phase was formed via further decomposition of LaNiO{sub 3} phase.

Weng Xiaole [Department of Environmental Engineering, Zhejiang University, Zhejiang Provincial Engineering Research Center of Industrial Boiler and Furnace Flue Gas Pollution Control, Hangzhou 310027 (China); Knowles, Jonathan C. [Division of Biomaterials and Tissue Engineering, UCL Eastman Dental Institute, University College London, 256 Gray's Inn Road, London WC1X 8LD (United Kingdom); WCU Research Centre of Nanobiomedical Science, Dankook University, San 29, Anseo-dong, Dongnam-gu, Cheonan-si, Chungnam 330-714 (Korea, Republic of); Abrahams, Isaac [Centre for Materials Research, School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); Wu Zhongbiao [Department of Environmental Engineering, Zhejiang University, Zhejiang Provincial Engineering Research Center of Industrial Boiler and Furnace Flue Gas Pollution Control, Hangzhou 310027 (China); Darr, Jawwad A., E-mail: j.a.darr@ucl.ac.uk [Department of Chemistry, University College London, Christopher Ingold Laboratories, 20 Gordon Street, London WC1H 0AJ (United Kingdom)

2011-07-15T23:59:59.000Z

333

A decrease in NiO-MgO phase through its solid solution equilibrium with tetragonal (La1-zSrz)2Ni1-yMgyO4-?: effect on catalytic partial oxidation of methane  

Science Conference Proceedings (OSTI)

Calcination of an oxide mixture consisting of 0.4 La2O3, 0.2 SrCO2, (1 - x)NiO, and xMgO at 800C results in an equilibrium between tetragonal (La1-zSrz)2Ni1-yMgyO4-? ...

Xiong Yin; Liang Hong; Zhengliang Gong

2012-01-01T23:59:59.000Z

334

Room-temperature diluted magnetic semiconductors p-(Ga,Ni)N  

SciTech Connect

High concentration (5 at. %) Ni was incorporated into a chemical vapor deposition-grown GaN film by using a thin protecting Ni layer on top of the GaN film during ion implantation. After etching off the protecting layer, subsequent annealing up to 800 deg. C under flowing N{sub 2} resulted in a p-type GaN with apparent ferromagnetic behavior up to {approx}320 K. In addition, the ferromagnetic behavior became more manifest with increasing annealing temperature that increases hole concentration. No presence of any other second phases nor clusters in the Ni-implanted region was identifiable, at least to the 0.2 nm point-to-point resolution of high resolution transmission electron microscopy. This novel indirect implantation process that being easy to implement appears promising for attaining room-temperature diluted magnetic semiconductors which are applicable to magnetotransport, magneto-optical and spintronics devices, among others.

Huang, R.-T.; Hsu, C.-F.; Kai, J.-J.; Chen, F.-R.; Chin, T.-S. [Department of Engineering and System Science, National Tsing-Hua University, Hsinchu 300, Taiwan (China); Department of Materials Science and Engineering, National Tsing-Hua University, Hsinchu 300, Taiwan (China)

2005-11-14T23:59:59.000Z

335

Effect of Ni on Cu precipitation kinetics in \\alpha-Fe by AKMC study  

E-Print Network (OSTI)

The kinetics of coherent Cu rich precipitation in Fe-Cu and Fe-Cu-Ni alloys during thermal ageing have been modeled by Atomic Kinetic Monte Carlo method (AKMC). The AKMC is parameterized by existing ab-inito data to treat vacancy mediated diffusion which is depend on local atomic environment. A nonlinear semi-empirical time adjusting method is proposed to rescaled the MC time. The combined AKMC and time adjusting method give good agreement with experiments and other simulations, including advancement factor and the Cu cluster mobility. Simulations of ternary alloys reveal Ni has a temporal delay effect on Cu precipitation. This effect is caused by the decreasing diffusion coefficient of Cu clusters. And the reduction effect of diffusion coefficient weakens with cluster size. The simulations can be used to explain the experimental phenomenon that higher cluster number density formed during coasening stage in Fe-Cu-Ni alloys than corresponding binary alloy, which is related to cluster mobility.

Wang, Yi; Liu, Xiang Bing; Wang, Rong Shan; Wang, Jing Tao

2013-01-01T23:59:59.000Z

336

Nature of yrast excitations near N=40: Level structure of Ni-67  

E-Print Network (OSTI)

Excited states in Ni-67 were populated in deep-inelastic reactions of a Ni-64 beam at 430 MeV on a thick U-238 target. A level scheme built on the previously known 13 micro-s isomer has been delineated up to an excitation energy of ~5.3 MeV and a tentative spin and parity of (21/2-). Shell model calculations have been carried out using two effective interactions in the f5/2pg9/2 model space with a Ni-56 core. Satisfactory agreement between experiment and theory is achieved for the measured transition energies and branching ratios. The calculations indicate that the yrast states are associated with rather complex configurations, herewith demonstrating the relative weakness of the N=40 subshell gap and the importance of multi particle-hole excitations involving the g9/2 neutron orbital.

S. Zhu; R. V. F. Janssens; M. P. Carpenter; C. J. Chiara; R. Broda; B. Fornal; N. Hoteling; W. Krolas; T. Lauritsen; T. Pawlat; D. Seweryniak; I. Stefanescu; J. R. Stone; W. B. Walters; X. Wang; J. Wrzesinski

2012-03-17T23:59:59.000Z

337

Nature of yrast excitations near N=40: Level structure of Ni-67  

E-Print Network (OSTI)

Excited states in Ni-67 were populated in deep-inelastic reactions of a Ni-64 beam at 430 MeV on a thick U-238 target. A level scheme built on the previously known 13 micro-s isomer has been delineated up to an excitation energy of ~5.3 MeV and a tentative spin and parity of (21/2-). Shell model calculations have been carried out using two effective interactions in the f5/2pg9/2 model space with a Ni-56 core. Satisfactory agreement between experiment and theory is achieved for the measured transition energies and branching ratios. The calculations indicate that the yrast states are associated with rather complex configurations, herewith demonstrating the relative weakness of the N=40 subshell gap and the importance of multi particle-hole excitations involving the g9/2 neutron orbital.

Zhu, S; Carpenter, M P; Chiara, C J; Broda, R; Fornal, B; Hoteling, N; Krolas, W; Lauritsen, T; Pawlat, T; Seweryniak, D; Stefanescu, I; Stone, J R; Walters, W B; Wang, X; Wrzesinski, J

2012-01-01T23:59:59.000Z

338

Field dependence of the superconducting basal plane anisotropy of TmNi2B2C  

SciTech Connect

The superconductor TmNi2B2C possesses a significant fourfold basal plane anisotropy, leading to a square vortex lattice (VL) at intermediate fields. However, unlike other members of the borocarbide superconductors, the anisotropy in TmNi2B2C appears to decrease with increasing field, evident by a reentrance of the square VL phase. We have used small-angle neutron scattering measurements of the VL to study the field dependence of the anisotropy. Our results provide a direct, quantitative measurement of the decreasing anisotropy. We attribute this reduction of the basal plane anisotropy to the strong Pauli paramagnetic effects observed in TmNi2B2C and the resulting expansion of vortex cores near Hc2.

Das, P.; Densmore, J.M.; Rastovski, C.; Schlesinger, K.J.; Laver, M.; Dewhurst, C.D.; Littrell, K.; Budko, Serguei L.; Canfield, Paul C.; Eskildsen, M.R.

2012-10-01T23:59:59.000Z

339

Fabrication of Si nano-pillar array through Ni nano-dot mask using inductively coupled plasma  

E-Print Network (OSTI)

Fabrication of Si nano-pillar array through Ni nano-dot mask using inductively coupled plasma Mun-Dong, Jangan-Gu, Suwon, 440-746, South Korea Available online 9 September 2004 Abstract We formed Si nano-pillar array using inductively coupled plasma (ICP) etching of Si with Ni nano-dot mask. For the formation

Yeom, Geun Young

340

Catalytic partial oxidation of methane to synthesis gas over Ni-based catalysts. 2: Transient, FTIR, and XRD measurements  

SciTech Connect

Ni/La{sub 2}O{sub 3} and Ni/Al{sub 2}O{sub 3} catalysts were studied under conditions of partial oxidation of methane to synthesis gas. Temperature-programmed oxidation and hydrogenation experiments have shown that carbon accumulation over Ni/La{sub 2}O{sub 3} during CPO remains essentially constant after 2 h time on-stream, while over Ni/Al{sub 2}O{sub 3} it increases during the initial several hours. FTIR spectroscopy of surface species formed over the Ni/La{sub 2}O{sub 3} catalyst under reaction conditions indicates that the carbonate species formed over the support do not decompose under He and O{sub 2} treatment at 600 C. XRD spectra obtained following high ({approximately}90%) or low (<10%) methane conversions show that Ni, La{sub 2}O{sub 3}, La{sub 2}O{sub 2}CO{sub 3}, NiO, and Ni{sub 3}C phases are present in the case of high methane and complete oxygen conversions, while nickel oxide, nickel carbide and, to a small extent, La{sub 2}O{sub 2}CO{sub 3} phases are present in the case of low CH{sub 4} and incomplete oxygen conversions.

Tsipouriari, V.A.; Verykios, X.E. [Univ. of Patras (Greece). Dept. of Chemical Engineering

1998-10-01T23:59:59.000Z

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341

Mixed-sputter deposition of Ni-Ti-Cu shape memory films  

SciTech Connect

Ni-Ti-Cu shape memory films were mixed-sputter deposited from separate nickel, titanium, and copper targets, providing increased compositional flexibility. Shape memory characteristics, examined for films with 7 at. % Cu and 41--51 at. % Tl, were determined with temperature controlled substrate curvature measurements, and microstructure was studied with transmission electron microscopy. The Ni-Ti-Cu films were found to have shape memory properties comparable to bulk materials, with transformation temperatures between 20 and 62{degree}C, a 10--13{degree}C hysteresis, and up to 330 MPa recoverable stress.

Krulevitch, P.; Ramsey, P.B.; Makowiecki, D.M.; Lee, A.P.; Northrup, M.A. [Lawrence Livermore National Lab., CA (United States); Johnson, G.C. [California Univ., Berkeley, CA (United States). Dept. of Mechanical Engineering

1994-05-01T23:59:59.000Z

342

Strees Corrosion Cracking Initiation of Ni-Bassed Alloys in High Temperature Water  

DOE Green Energy (OSTI)

The goal of the work is to provide stress corrosion cracking (SCC) initiation data for Alloy 600 that is not compromised by (1) specimens that suffer from stress relaxation, (2) specimens which have an unknown stress state, (3) specimens which are tested at unknown positions electrochemically relative to the Ni/NiO phase transition, and (4) testing which relies on the period of time between specimen inspection intervals to estimate SCC initiation times. The current study was aimed at studying the effects of temperature and coolant hydrogen concentration on SCC initiation in high purity, high temperature water.

E Richey; D Morton

2005-03-21T23:59:59.000Z

343

Computational Thermodynamics of CoNiGa High Temperature Shape Memory Alloys  

E-Print Network (OSTI)

Shape Memory Alloys (SMAs) are advanced materials with interesting properties such as pseudoelasticity (PE) and the shape memory effect (SME). Recently, the CoNiGa system has emerged as the basis for very promising High Temperature Shape Memory Alloys (HTSMAs), with possible applications in the aerospace and automotive industries. Although the CoNiGa system shows significant promise for its use as HTSMAs, limited studies are available on them. Hence, a more intensive investigation of these alloys is necessary to understand their phase stability over a wide range of temperature and compositions in order for further development of CoNiGabased HTSMAs and future use of the model in alloy design. This formed the basis of motivation for the present work. In this work, a thermodynamic model of the ternary system is calculated based on the CALPHAD approach, to investigate the thermodynamic properties, phase stability and shape memory properties of these alloys. The CALPHAD approach is a computational method that enables the calculations of thermodynamic properties of systems. This method uses all available experimental and theoretical data in order to calculate the Gibbs energies of the phases in the system. The software used to carry out the calculations is "ThermoCalc," which is a computational software using CALPHAD principles, based on the minimization of Gibbs energy, and is enhanced by a global minimization technique on the system. The stability of the beta phase at high temperatures was enforced accurately by remodeling the CoGa system. The binary CoGa system that makes up the ternary was remodeled, as the beta phase (which is very important as it dominates the central region of the ternary CoNiGa system where the shape memory effect is observed), re-stabilizes as the temperature increases above the liquidus in the CoGa system. Phase relations and thermodynamic properties of the CoNiGa system based on all experimental information were evaluated. Different properties like enthalpies, activities, sublattice site fraction of vacancies and phase fractions calculated in the system matched well compared to the experimental information used to model the system. Also, the phase equilibria among the gamma (fcc), beta, gamma'(Ni3Ga), delta (Ni5Ga3) and epsilon (Ni13Ga9) were determined at various temperatures.

Chari, Arpita

2011-08-01T23:59:59.000Z

344

Characterizations Of Precipitate Phases In a Ti-Ni-Pd Alloy  

Science Conference Proceedings (OSTI)

Precipitates in the Ti46Ni37.5Pd16.5 alloy were investigated by electron diffraction and high-resolution scanning transmission electron microscopy. The phase content and stability were determined at several different temperatures and times. Aging at 400 C for an hour results in a new phase, which is consumed by P-phase at longer aging time. At 450 C, the new phase appears first, and then coexists with P-phase. At 500 C, the entire alloy transformed into the new phase. At 550 C, Ti3(Ni,Pd)4 phase begins to form.

Yang, Fan; Kovarik, Libor; Phillips, Patrick J.; Noebe, Ronald D.; Mills, M. J.

2012-06-01T23:59:59.000Z

345

Surface segregation effects in electrocatalysis: Kinetics ofoxygen reduction reaction on polycrystalline Pt3Ni alloy surfaces  

DOE Green Energy (OSTI)

Effects of surface segregation on the oxygen reduction reaction (ORR) have been studied on a polycrystalline Pt3Ni alloy in acid electrolyte using ultra high vacuum (UHV) surface sensitive probes and the rotating ring disk electrode (RRDE) method. Preparation, modification and characterization of alloy surfaces were done in ultra high vacuum (UHV). Depending on the preparation method, two different surface compositions of the Pt3Ni alloy are produced: a sputtered surface with 75 % Pt and an annealed surface (950 K ) with 100 % Pt. The latter surface is designated as the 'Pt-skin' structure, and is a consequence of surface segregation, i.e., replacement of Ni with Pt atoms in the first few atomic layers. Definitive surface compositions were established by low energy ion scattering spectroscopy (LEISS). The cyclic voltammetry of the 'Pt-skin' surface as well as the pseudocapacitance in the hydrogen adsorption/desorption potential region is similar to a polycrystalline Pt electrode. Activities of ORR on Pt3Ni alloy surfaces were compared to polycrystalline Pt in 0.1M HClO4 electrolyte for the observed temperature range of 293 < T < 333 K. The order of activities at 333 K was: 'Pt-skin' > Pt3Ni (75% Pt) > Pt with the maximum catalytic enhancement obtained for the 'Pt-skin' being 4 times that for pure Pt. Catalytic improvement of the ORR on Pt3Ni and 'Pt-skin' surfaces was assigned to the inhibition of Pt-OHad formation (on Pt sites) versus polycrystalline Pt. Production of H2O2 on both surfaces were similar compared to the pure Pt. Kinetic analyses of RRDE data confirmed that kinetic parameters for the ORR on the Pt3Ni and 'Pt-skin' surfaces are the same as on pure Pt: reaction order, m=1, two identical Tafel slopes, activation energy, {approx} 21-25 kJ/mol. Therefore the reaction mechanism on both Pt3Ni and 'Pt-skin' surfaces is the same as one proposed for pure Pt i.e. 4e{sup -} reduction pathway.

Stamenkovic, V.; Schmidt, T.J.; Ross, P.N.; Markovic, N.M.

2002-11-01T23:59:59.000Z

346

Magnetic and superconducting phase diagrams in ErNi2B2C  

SciTech Connect

We present measurements of the superconducting upper critical field Hc2(T) and the magneticphasediagram of the superconductor ErNi2B2C made with a scanning tunneling microscope (STM). The magnetic field was applied in the basal plane of the tetragonal crystal structure. We have found large gapless regions in the superconductingphasediagram of ErNi2B2C, extending between different magnetic transitions. A close correlation between magnetic transitions and Hc2(T) is found, showing that superconductivity is strongly linked to magnetism.

Galvis, J.A.; Crespo, M.; Guillamon, I.; Suderow, Hermann; Vieira, S.; Garcia Hernandez, M.; Budko, Serguei; Canfield, Paul

2012-03-30T23:59:59.000Z

347

Generators Yu.N. Barmakov, N.G. Ignatiev, B.D. Lemeshko, V.I. Mikerov, and D.I. Yurkov  

National Nuclear Security Administration (NNSA)

1(b): Techniques for Dynamic Experiments 1(b): Techniques for Dynamic Experiments Research of Possibility of Radiography in Fast Neutrons by Use of Portable Neutron Generators Yu.N. Barmakov, N.G. Ignatiev, B.D. Lemeshko, V.I. Mikerov, and D.I. Yurkov FSUE All-Russian Research Institute of Automatics Russia, Moscow, Suschevskaya st. 22, PO Box: 127055, web site: www.vniia.ru Neutron portable generators are one of the sources, generating neutron and X-ray radiations at one time. Those distinguish with rather small size of radiating area (~1mm), and, also, with wide ranges of radiation time spans (starting with continuous radiation and ending with pulses having »25 ns width). Just mentioned features, in general, provide wide range of generators possible practical applications, and, particularly, application in research

348

Underground Injection Control Permit Applications for FutureGen 2.0 Morgan County Class VI UIC Wells 1, 2, 3, and 4  

NLE Websites -- All DOE Office Websites (Extended Search)

FG-RPT-017 FG-RPT-017 Revision 1 Underground Injection Control Permit Applications for FutureGen 2.0 Morgan County Class VI UIC Wells 1, 2, 3, and 4 SUPPORTING DOCUMENTATION March 2013 (Revised May 2013 in accordance with the U.S. Environmental Protection Agency's Completeness Review) Acknowledgment: This material is based upon work supported by the Department of Energy under Award Number DE-FE0001882. Disclaimer: This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents

349

I-III-VI.sub.2 based solar cell utilizing the structure CuInGaSe.sub.2 CdZnS/ZnO  

SciTech Connect

A thin film I-III-VI.sub.2 based solar cell having a first layer of copper indium gallium selenide, a second layer of cadmium zinc sulfide, a double layer of zinc oxide, and a metallization structure comprised of a layer of nickel covered by a layer of aluminum. An optional antireflective coating may be placed on said metallization structure. The cadmium zinc sulfide layer is deposited by means of an aqueous solution growth deposition process and may actually consist of two layers: a low zinc content layer and a high zinc content layer. Photovoltaic efficiencies of 12.5% at Air Mass 1.5 illumination conditions and 10.4% under AMO illumination can be achieved.

Chen, Wen S. (Seattle, WA); Stewart, John M. (Seattle, WA)

1992-01-07T23:59:59.000Z

350

Theoretical analyses of (n,xn) reactions on sup 235 U, sup 238 U, sup 237 Np, and sup 239 Pu for ENDF/B-VI  

Science Conference Proceedings (OSTI)

Theoretical analyses were performed of neutron-induced reactions on {sup 235}U, {sup 238}U, {sup 237}Np, and {sup 239}Pu between 0.01 and 20 MeV in order to calculate neutron emission cross sections and spectra for ENDF/B-VI evaluations. Coupled-channel optical model potentials were obtained for each target nucleus by fitting total, elastic, and inelastic scattering cross section data, as well as low-energy average resonance data. The resulting deformed optical model potentials were used to calculate direct (n,n{prime}) cross sections and transmission coefficients for use in Hauser-Feshbach statistical theory analyses. A fission model with multiple barrier representation, width fluctuation corrections, and preequilibrium corrections were included in the analyses. Direct cross sections for higher-lying vibrational states were calculated using DWBA theory, normalized using B(E{ell}) values determined from (d,d{prime}) and Coulomb excitation data, where available, and from systematics otherwise. Initial fission barrier parameters and transition state density enhancements appropriate to the compound systems involved were obtained from previous analyses, especially fits to charged-particle fission probability data. The parameters for the fission model were adjusted for each target system to obtain optimum agreement with direct (n,f) cross section measurements, taking account of the various multichance fission channels, that is, the different compound systems involved. The results from these analyses were used to calculate most of the neutron (n,n), (n,n{prime}), and (n,xn) cross section data in the ENDF/B/VI evaluations for the above nuclei, and all of the energy-angle correlated spectra. The deformed optical model and fission model parameterizations are described. Comparisons are given between the results of these analyses and the previous ENDF/B-V evaluations as well as with the available experimental data. 14 refs., 3 figs., 1 tab.

Young, P.G.; Arthur, E.D.

1991-01-01T23:59:59.000Z

351

Molecular oxygen adsorbates at a Au/Ni(111) surface alloy and their role in catalytic CO oxidation at 70 - 250 K  

E-Print Network (OSTI)

Oxygen is observed to adsorb molecularly on 0.13 - 0.27 ML Au/Ni(1 111) surface alloys at 77 K, in stark contrast to dissociative adsorption on Ni and no adsorption on Au surfaces. Molecular 02 adsorbates on the Au/Ni(111) ...

Lahr, David Louis

2006-01-01T23:59:59.000Z

352

Effect of Nickel Microstructure on Methane Steam-Reforming Activity of Ni-YSZ Cermet Anode Catalyst  

Science Conference Proceedings (OSTI)

The activity of nickel-yttria stabilized zirconia (Ni-YSZ) solid oxide fuel cell (SOFC) cermet anodes for the steam reforming of methane has been investigated in the absence of electrochemical effects. The cermet was prepared by co-milling and sintering NiO and 5YSZ powders at 1375oC in air. During the high temperature sintering step, NiO dissolved into the YSZ particles to form a solid NiO-YSZ solution. During the subsequent catalyst reduction step, Ni exolved from the YSZ. As a result, many small Ni particles on the order of 10-20 nm formed at the surface of the YSZ. These small particles contribute significantly to the overall reforming activity, along with the large bulk Ni particles within the Ni-YSZ cermet. We have observed high initial activity that decreases by as much as an order of magnitude with time on stream, until the anode catalyst reaches a stable steady state activity. The time to reach this stable activity is a function of the reaction conditions and feed gas composition. Higher temperature, hydrogen partial pressure, and space velocity all accelerated the deactivation rate at a constant steam-to-carbon ratio of 3. Initial and lined out activities and average turnover frequencies were obtained for both Ni-YSZ and bulk Ni, based on a rate expression that is first order in methane and zero order in steam. Comparative tests at 750oC show high initial activity on a per-Ni site basis with both materials, but these turnover rates decline over a period of a few hours. Following lineout, there appears to be a negligible effect of Ni particle size on turnover rate. These results indicate the presence of structure sensitivity for methane reforming, but only with freshly calcined and reduced catalysts that may contain highly coordinatively unsaturated sites. There is an apparent structure insensitivity with aged catalysts where Ni particle sizes are generally 50 nm and greater. Under reaction conditions that employ high space velocities and low methane conversions, the water-gas-shift reaction does not establish thermodynamic equilibrium.

King, David L.; Strohm, James J.; Wang, Xianqin; Roh, Hyun-Seog; Wang, Chong M.; Chin, Ya-Huei; Wang, Yong; Lin, Yuehe; Rozmiarek, Robert T.; Singh, Prabhakar

2008-09-10T23:59:59.000Z

353

Modulation on Ni{sub 2}MnGa(001) surface  

SciTech Connect

We report periodic modulation on (001) surface of Ni2MnGa ferromagnetic shape memory alloy. For the stoichiometric surface, analysis of the low energy electron diffraction (LEED) spot profiles shows that the modulation is incommensurate. The modulation appears at 200 K, concomitant with the first order structural transition to the martensitic phase.

D'Souza, S. W.; Rai, Abhishek; Nayak, J.; Maniraj, M.; Dhaka, R. S.; Barman, S. R.; Schlagel, D. L.; Lograsso, T. A. [UGC-DAE Consortium for Scientific Research, Khandwa Road, Indore, 452001, Madhya Pradesh (India); Ames Laboratory U. S. DOE, Iowa State University, Ames, Iowa 50011-3020 (United States)

2011-07-15T23:59:59.000Z

354

The field emission properties of graphene aggregates films deposited on Fe-Cr-Ni alloy substrates  

Science Conference Proceedings (OSTI)

The graphene aggregates films were fabricated directly on Fe-Cr-Ni alloy substrates by microwave plasma chemical vapor deposition system (MPCVD). The source gas was a mixture of H2 and CH4 with flow rates of 100 sccm and 12 sccm, ...

Zhanling Lu; Wanjie Wang; Xiaotian Ma; Ning Yao; Lan Zhang; Binglin Zhang

2010-01-01T23:59:59.000Z

355

Aging effects in palladium and LaNi sub 4. 25 Al sub 0. 75 tritides  

DOE Green Energy (OSTI)

Palladium and LaNi{sub 5-x}Al{sub x} (x=0.30, 0.75, 0.85), which form reversible hydrides, are used for tritium processing and storage in the Savannah River Site (SRS) tritium facilities. As part of a program to develop technology based on the use of reversible metal hydrides for tritium processing and storage, the effects of aging on the thermodynamic behavior of palladium and LaNi{sub 4.25}Al{sub 0. 75} tritides are under investigation. During aging, the {sup 3}He tritium decay product remains in the tritide lattice and changes the thermodynamics of the tritium-metal tritide system. Aging effects in 755-day-aged palladium and 1423-day-aged LaNi{sub 4.25}Al{sub 0.75} tritides will be reported. Changes in the thermodynamics were determined by measuring tritium desorption isotherms on aging samples. In palladium, aging decreases the desorption isotherm plateau pressure and changes the {alpha}-phase portion of the isotherm. Aging-induced changes in desorption isotherms are more drastic in LaNi{sub 4.25}Al{sub 0.75}. Among the changes noted are: (1) decreased isotherm plateau pressure, (2) increased isotherm plateau slope, and (3) appearance of deep-trapped tritium, removable only by exchange with deuterium.

Nobile, A.; Wermer, J.R.; Walters, R.T.

1991-01-01T23:59:59.000Z

356

Ni(II) Sorption on Biogenic Mn-Oxides with Varying Mn  

E-Print Network (OSTI)

Lightsource (SSRL), Menlo Park, CA. EXAFS spectra from Ni(II) organic standards were collected in transmission-3 at SSRL. This method is described in detail in Zhu et al. (6). Results Sorption Isotherms and Dissolved Mn,anationaluserfacilityoperatedbyStanfordUniversity on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. The SSRL Structural Molecular

Sparks, Donald L.

357

Ni(II) Sorption on Biogenic Mn-Oxides with Varying Mn  

E-Print Network (OSTI)

Lightsource (SSRL), Menlo Park, CA. EXAFS spectra from Ni(II) organic standards were collected in transmission 11-3 at SSRL. This method is described in detail in Zhu et al. (6). Results Sorption Isotherms,anationaluserfacilityoperatedbyStanfordUniversity on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. The SSRL Structural Molecular

Sparks, Donald L.

358

Ni3Al-based alloys for die and tool application  

SciTech Connect

A novel Ni.sub.3 Al-based alloy exhibits strengths and hardness in excess of the standard base alloy IC-221M at temperatures of up to about 1000.degree. C. The alloy is useful in tool and die applications requiring such temperatures, and for structural elements in engineering systems exposed to such temperatures.

Liu, Chain T. (Oak Ridge, TN); Bloom, Everett E. (Kingston, TN)

2001-01-01T23:59:59.000Z

359

Gentle FUSI NiSi metal gate process for high-k dielectric screening  

Science Conference Proceedings (OSTI)

In this paper, a process flow well suited for screening of novel high-k dielectrics is presented. In vacuo silicon capping of the dielectrics excludes process and handling induced influences especially if hygroscopic materials are investigated. A gentle, ... Keywords: FUSI NiSi, High-k, Material screening, Ultrathin dielectric

H. D. B. Gottlob; M. C. Lemme; M. Schmidt; T. J. Echtermeyer; T. Mollenhauer; H. Kurz; K. Cherkaoui; P. K. Hurley; S. B. Newcomb

2008-10-01T23:59:59.000Z

360

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

SciTech Connect

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Formation of NiGe through germanium oxide on Ge(001) substrate  

Science Conference Proceedings (OSTI)

Germanium based devices are of interest due to their performance potential. The use of germanium as source and drain requires low resistance access achieved by the formation of germanide (metal-germanium compound). The nickel mono-germanide (NiGe) is ...

F. Nemouchi, V. Carron, J. L. LBR, L. Vandroux, Y. Morand, T. Morel, J. P. Barnes

2013-07-01T23:59:59.000Z

362

1999 Toyota RAV 4 EV Performance Characterization: Panasonic NiMH Battery -- Conductive Charging  

Science Conference Proceedings (OSTI)

This report characterizes the performance of the 1998 and 1999 Toyota RAV 4 conductively-charged electric vehicle models equipped with Panasonic Nickel Metal Hydride (NiMH) batteries. The tests performed were: weight certification, range, state of charge meter evaluation, sound level, acceleration, maximum speed, braking, power quality evaluation, and charger performance.

1999-12-16T23:59:59.000Z

363

1999 Toyota RAV 4 EV Performance Characterization: Panasonic NiMH Battery -- Inductive Charging  

Science Conference Proceedings (OSTI)

This report characterizes the performance of a 1999 Toyota RAV 4 inductively-charged electric vehicle equipped with Panasonic Nickel Metal Hydride (NiMH) batteries. The tests performed were weight certification, range, vehicle performance, sound level tests, power quality evaluation, state of charge meter evaluation, and charger performance.

1999-12-15T23:59:59.000Z

364

Three-dimensional microstructural changes in the NiYSZ solid oxide fuel cell anode during operation  

Science Conference Proceedings (OSTI)

Microstructural evolution in solid oxide fuel cell (SOFC) cermet anodes has been investigated using X-ray nanotomography along with differential absorption imaging. SOFC anode supports composed of Ni and yttria-stabilized zirconia (YSZ) were subjected to extended operation and selected regions were imaged using a transmission X-ray microscope. X-ray nanotomography provides unique insight into microstructure changes of all three phases (Ni, YSZ, pore) in three spatial dimensions, and its relation to performance degradation. Statistically significant 3D microstructural changes were observed in the anode Ni phase over a range of operational times, including phase size growth and changes in connectivity, interfacial contact area and contiguous triple-phase boundary length. These observations support microstructural evolution correlated to SOFC performance. We find that Ni coarsening is driven by particle curvature as indicated by the dihedral angles between the Ni, YSZ and pore phases, and hypothesize that growth occurs primarily by means of diffusion and particle agglomeration constrained by a pinning mechanism related to the YSZ phase. The decrease in Ni phase size after extended periods of time may be the result of a second process connected to a mobility-induced decrease in the YSZ phase size or non-uniform curvature resulting in a net decrease in Ni phase size.

Nelson G. J.; Chu Y.; Grew, K.N.; Izzo Jr. J.R.; Lombardo, J.J.; Harris, W.M.; Faes, A.; Hessler-Wyser, A.; Van herle, J.; Wang, S.; Virkar, A.V.; Chiu, W.K.S.

2012-04-07T23:59:59.000Z

365

Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces  

SciTech Connect

The work has focussed on hydrogen induced bond activation in adsorbed organic molecules and intermediates containin C-S and C-N and C-C bonds on Ni(100), Ni(111), and Pt(111) surfaces. Fluorescence Yield Near Edge Spectroscopy (FYNES) above the carbon K edge was used for adsorbed organic reactants and in-situ kinetic studies of bond activation. Results indicate that the activation is enhanced on Ni relative to Pt. Methylthiolate and methylamine adsorbed on Pt(111) were studied.

Gland, J.L.

1992-01-01T23:59:59.000Z

366

Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces  

SciTech Connect

The work has focussed on hydrogen induced bond activation in adsorbed organic molecules and intermediates containin C-S and C-N and C-C bonds on Ni(100), Ni(111), and Pt(111) surfaces. Fluorescence Yield Near Edge Spectroscopy (FYNES) above the carbon K edge was used for adsorbed organic reactants and in-situ kinetic studies of bond activation. Results indicate that the activation is enhanced on Ni relative to Pt. Methylthiolate and methylamine adsorbed on Pt(111) were studied.

Gland, J.L.

1992-12-01T23:59:59.000Z

367

Structural Analysis of a Ni-Methyl Species in Methyl-Coenzyme M Reductase from Methanothermobacter marburgensis  

SciTech Connect

We present the 1.2 {angstrom} resolution X-ray crystal structure of a Ni-methyl species that is a proposed catalytic intermediate in methyl-coenzyme M reductase (MCR), the enzyme that catalyzes the biological formation of methane. The methyl group is situated 2.1 {angstrom} proximal of the Ni atom of the MCR coenzyme F{sub 430}. A rearrangement of the substrate channel has been posited to bring together substrate species, but Ni(III)-methyl formation alone does not lead to any observable structural changes in the channel.

Cedervall, Peder E.; Dey, Mishtu; Li, Xianghui; Sarangi, Ritimukta; Hedman, Britt; Ragsdale, Stephen W.; Wilmot, Carrie M. (Michigan); (SLAC); (UMM)

2012-02-15T23:59:59.000Z

368

Improving the phase stability and oxidation resistance of B-NiAl  

SciTech Connect

High temperature alloys are essential to many industries that require a stable material to perform in harsh oxidative environments. Many of these alloys are suited for specific applications such as jet engine turbine blades where most other materials would either melt or oxidize and crumble (1). These alloys must have a high melting temperature, excellent oxidation resistance, good creep resistance, and decent fracture toughness to be successfully used in such environments. The discovery of Ni based superalloys in the 1940s revolutionized the high temperature alloy industry and there has been continued development of these alloys since their advent (2). These materials are capable of operating in oxidative environments in the presence of combustion gases, water vapor and at temperatures around 1050 C. Demands for increased f uel efficiency, however, has highlighted the need for materials that can be used under similar atmospheres and at temperatures in excess of 1200 C. The current Ni based superalloys are restricted to lower temperatures due to the presence of a number of low melting phases that result in softening of the alloys above 1000 C. Therefore, recent research has been aimed at exploring and developing newer alloy systems that can meet the escalating requirements. This thesis comprises a part of such an effort. The motivation of this work is to develop a novel high temperature alloy system that shows improved performance at higher temperatures than the currently employed alloys. The desired alloy should be in accordance with the requirements established in the National Energy Technology Laboratory (NETL) FutureGen program having an operating temperature around 1300 C. Alloys based on NiAl offer significant potential payoffs as structural materials in gas turbine applications due to a unique range of physical and mechanical properties. Alloying additions to NiAl could be used to further improve the pertinent properties that currently limit this system from replacing Ni based superalloys. Modifications to NiAl were explored to increase the phase stability and oxidation resistance which would allow these alloys to be used at even higher temperatures yielding greater efficiencies. The extended Miedema model was an effective tool that screened all of the potential phase space for ternary substitutions to NiAl and found the few potential systems worth further investigation. After production of the alloys it was determined that Ir, Rh, and Pd were the top candidates for substitution on Ni site up to 12 at%. The melting temperature of NiAl could be increased as much as 150 C with 12 at% Ir and 130 C with 12 at% Rh substitution. Pall adium on the other hand decreased the melting temperature by 50 C at the 12 at% substitution level. The grain size was found to have a profound influence on the oxidation resistance. Both Ir and Rh substitutions resulted in finer grain sizes compared to Pd substitutions or base NiAl. The grain size increased drastically during high temperature annealing with the PGM substitutions hindering grain growth only slightly. However, the addition of 0.05 at% Hf limited the grain growth dramatically during high temperature annealing. NiAl inherently has respectable oxidation resistance up to 1100 C. It was found through experimental testing that both Ir and Rh substitutions improve the oxidation resistance of NiAl at ultra-high temperatures with Ir performing the best. Both PGM substitutions decreased the growth rate as well as forming a more adherent oxide scale. Pd substitutions appeared to have a negligible effect to the oxidation resistance of NiAl. Hafnium addition of 0.05 at% was found to decrease the oxidation rate as well as increase the scale adherence. The combination of both Ir substitution (6-9 at%) and Hf addition (0.05 at%) produced the alloy with the best oxidation resistance. Although improvements in phase stability and oxidation resistance have been made to the NiAl system, more development and testing are still needed. Two major issues yet to be resolved are the low fracture toughn

Brammer, Travis

2011-08-15T23:59:59.000Z

369

PLASMA SPRAYED Ni-Al COATINGS FOR SAFE ENDING HEAT EXCHANGER TUBES  

DOE Green Energy (OSTI)

Brookhaven National Laboratory (BNL) has developed thermally conductive composite liners for corrosion and scale protection in heat exchanger tubes exposed to geothermal brine. The liners cannot withstand roller expansion to connect the tubes to the tubesheet. It is not possible to line the ends of the tubes with the same material after roller expansion due to the nature of the current liner application process. It was requested that BNL evaluate plasma sprayed Ni-Al coatings for safe ending heat exchanger tubes exposed to geothermal brine. The tubes of interest had an internal diameter of 0.875 inches. It is not typical to thermal spray small diameter components or use such small standoff distances. In this project a nozzle extension was developed by Zatorski Coating Company to spray the tube ends as well as flat coupons for testing. Four different Ni-Al coatings were investigated. One of these was a ductilized Ni-AIB material developed at Oak Ridge National Laboratory. The coatings were examined by optical and scanning electron microscopy. In addition, the coatings were analyzed by X-ray diffraction and subjected to corrosion, tensile adhesion, microhardness and field tests in a volcanic pool in New Zealand. It was determined that the Ni-Al coatings could be applied to a depth of two inches on the tube ends. When sprayed on flat coupons the coatings exhibited relatively high adhesion strength and microhardness. Polarization curves showed that the coating performance was variable. Measured corrosion potentials indicated that the Ni-Al coatings are active towards steel coated with thermally conductive polymers, thereby suggesting preferential corrosion. Corrosion also occurred on the coated coupons tested in the volcanic pool. This may have been exacerbated by the difficulty in applying a uniform coating to the coupon edges. The Ni-Al coatings applied to the tubes had significant porosity and did not provide adequate corrosion protection. This is associated with the short standoff distance and is not a reflection of the normal quality of plasma sprayed coatings. Even if coating porosity could be reduced, the coupling of an alloy coating to a polymer-based barrier coating in the same electrolyte is not recommended. Therefore, polymer coatings that can be field applied to the tube ends after roller expansion should be sought.

ALLAN,M.L.; OTTERSON,D.; BERNDT,C.C.

1998-11-01T23:59:59.000Z

370

Finite oscillator models: the Hahn oscillator E.I. Jafarov, N.I. Stoilova and J. Van der Jeugt  

E-Print Network (OSTI)

: Institute of Physics, Azerbaijan National Academy of Sciences, Javid av. 33, AZ-1143 Baku, Azerbaijan fellowship from the Azerbaijan National Academy of Sciences. N.I. Stoilova was supported by project P6

Van der Jeugt, Joris

371

Predicting the Impact of El Niño on Future Temperature Extremes | U.S. DOE  

Office of Science (SC) Website

Predicting the Impact of El Niño on Future Temperature Extremes Predicting the Impact of El Niño on Future Temperature Extremes Biological and Environmental Research (BER) BER Home About Research Facilities Science Highlights Searchable Archive of BER Highlights External link Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC) News & Resources Contact Information Biological and Environmental Research U.S. Department of Energy SC-23/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3251 F: (301) 903-5051 E: sc.ber@science.doe.gov More Information » October 2012 Predicting the Impact of El Niño on Future Temperature Extremes Accurate prediction of El Niño-Southern Oscillation is crucial for simulating extreme maximum temperature. Print Text Size: A A A

372

Advanced gas atomization production of oxide dispersion strengthened (ODS) Ni-base superalloys through process and solidification control.  

E-Print Network (OSTI)

??A novel gas atomization reaction synthesis (GARS) method was utilized to produce precursor Ni-Cr-Y-Ti powder with a surface oxide and an internal rare earth (RE)-containing (more)

Meyer, John

2013-01-01T23:59:59.000Z

373

NiO nanoparticles synthesis by chemical precipitation and effect of applied surfactant on distribution of particle size  

Science Conference Proceedings (OSTI)

Production of NiO by chemical precipitation is the approach utilized in this work. Materials mainly used in this project are nickel nitrate hex hydrate (as a basic material), sodium hydroxide (as a precipitator material), and the following surfactants ...

Y. Bahari Molla Mahaleh; S. K. Sadrnezhaad; D. Hosseini

2008-01-01T23:59:59.000Z

374

Ni6Cr5MoO18: A compensated half metal predicted from first-principles  

Science Conference Proceedings (OSTI)

NiCrO3 is semiconducting. It contains six molecular units in the conventional cell. By substituting one of the six Cr atoms with Mo in the conventional cell

Jing Wang; Ningning Zu; Zhijian Wu

2013-01-01T23:59:59.000Z

375

Physical Properties of Single-Crystalline Ba8Ni3.5Ge42.1?0.4  

E-Print Network (OSTI)

dependence of the electrical resistivity, q(T), of Ba 8 NiS and the electrical resistivity q are interrelated in anAND DISCUSSION The electrical resistivity q increases with

2010-01-01T23:59:59.000Z

376

Hot electron transmission in metals using epitaxial NiSi{sub 2}/n-Si(111) interfaces  

SciTech Connect

We have investigated hot electron transmission across epitaxial metal-disilicide/n-Si(111) interfaces using ballistic electron emission microscopy (BEEM). Different crystal orientations of epitaxial NiSi{sub 2} were grown on a Si(111) substrate using molecular beam epitaxy. The presence of different interfaces of NiSi{sub 2} on Si(111) were confirmed by high resolution transmission electron microscopy. Electrical transport measurements reveal a clear rectifying Schottky interface with a barrier height of 0.69 eV. However, using BEEM, three different regions with different transmissions and Schottky barrier heights of 0.65 eV, 0.78 eV, and 0.71 eV are found. The addition of a thin Ni film on the NiSi{sub 2} layer strongly reduces the transmission in all the three regions and interestingly, almost equalizes the transmission across them.

Parui, S.; Wit, B.; Wees, B. J. van; Banerjee, T. [Physics of Nanodevices, Zernike Institute for Advanced Materials, University of Groningen (Netherlands); Bignardi, L.; Rudolf, P. [Surfaces and Thin Films, Zernike Institute for Advanced Materials, University of Groningen (Netherlands); Kooi, B. [Nanostructured Materials and Interfaces, Zernike Institute for Advanced Materials, University of Groningen (Netherlands)

2011-07-18T23:59:59.000Z

377

Ni coarsening in the three-phase solid oxide fuel cell anode - a phase-field simulation study  

E-Print Network (OSTI)

Ni coarsening in Ni-yttria stabilized zirconia (YSZ) solid oxide fuel cell anodes is considered a major reason for anode degradation. We present a predictive, quantative modeling framework based on the phase-field approach to systematically examine coarsening kinetics in such anodes. The initial structures for simulations are experimentally acquired functional layers of anodes. Sample size effects and error analysis of contact angles are examined. Three phase boundary (TPB) lengths and Ni surface areas are quantatively identified on the basis of the active, dead-end, and isolated phase clusters throughout coarsening. Tortuosity evolution of the pores is also investigated. We find that phase clusters with larger characteristic length evolve slower than those with smaller length scales. As a result, coarsening has small positive effects on transport, and impacts less on the active Ni surface area than the total counter part. TPBs, however, are found to be sensitive to local morphological features and are only i...

Chen, Hsun-Yi; Cronin, J Scott; Wilson, James R; Barnett, Scott A; Thornton, Katsuyo

2012-01-01T23:59:59.000Z

378

A Ni-Fe Layered Double Hydroxide-Carbon Nanotube Complex for Water Oxidation  

E-Print Network (OSTI)

Highly active, durable and cost-effective electrocatalysts for water oxidation to evolve oxygen gas hold a key to a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel iron layered double hydroxide nanoplates on mildly oxidized multi-walled carbon nanotubes. Incorporation of Fe into the nickel hydroxide induced the formation of NiFe-layered double hydroxide. The nanoplates were covalently attached to a network of nanotubes, affording excellent electrical wiring to the nanoplates. The ultra-thin Ni-Fe layered double hydroxide nanoplates/carbon nanotube complex was found to exhibit unusually high electro-catalytic activity and stability for oxygen evolution and outperformed commercial precious metal Ir catalysts.

Gong, Ming; Wang, Hailiang; Liang, Yongye; Wu, Justin Zachary; Zhou, Jigang; Wang, Jian; Regier, Tom; Wei, Fei; Dai, Hongjie

2013-01-01T23:59:59.000Z

379

High capacitive performance of nanostructured Mn-Ni-Co oxide composites for supercapacitor  

SciTech Connect

Nanostructured Mn-Ni-Co oxide composites (MNCO) were prepared by thermal decomposition of the precursor obtained by chemical co-precipitation of Mn, Ni and Co salts. The chemical composition and morphology were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The electrochemical capacitance of MNCO electrode was examined by cyclic voltammetry, impedance and galvanostatic charge-discharge measurements. The results showed that MNCO electrode exhibited the good electrochemical characteristics. A maximum capacitance value of 1260 F g{sup -1} could be obtained within the potential range of -0.1 to 0.4 V versus saturated calomel electrode (SCE) in 6 mol L{sup -1} KOH electrolyte.

Luo Jianmin [Institute of Applied Chemistry, Xinjiang University, Urumqi 830046 (China); Gao Bo [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Zhang Xiaogang [College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)], E-mail: azhangxg@163.com

2008-05-06T23:59:59.000Z

380

Enhancing hydrogen evolution activities in water splitting by tailoring Li+/Ni(OH){<_2}/Pt interfaces.  

DOE Green Energy (OSTI)

Improving the sluggish kinetics for the electrochemical reduction of water to molecular hydrogen in alkaline environments is one key to reducing the high overpotentials and associated energy losses in water-alkali and chlor-alkali electrolyzers. We found that a controlled arrangement of nanometer-scale Ni(OH){sub 2} clusters on platinum electrode surfaces manifests a factor of 8 activity increase in catalyzing the hydrogen evolution reaction relative to state-of-the-art metal and metal-oxide catalysts. In a bifunctional effect, the edges of the Ni(OH){sub 2} clusters promoted the dissociation of water and the production of hydrogen intermediates that then adsorbed on the nearby Pt surfaces and recombined into molecular hydrogen. The generation of these hydrogen intermediates could be further enhanced via Li{sup +}-induced destabilization of the HO-H bond, resulting in a factor of 10 total increase in activity.

Subbaraman, S.; Tripkovic, D.; Strmcnik, D.; Chang, K-C.; Uchimura, M.; Paulikas, A. P.; Stamenkovic, V.; Markovic, N. M. (Materials Science Division); ( NE); (Nissan Res. Ctr.)

2011-12-02T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Regeneration of Sulfur Deactivated Ni-based Biomass Syngas Cleaning Catalysts  

DOE Green Energy (OSTI)

Nickel-based catalysts have been widely tested in decomposing tar and methane in hot biomass syngas cleanup researches. However these catalysts can be easily deactivated by the sulfur compounds in syngas due to the strong sulfur adsorption effect on the Ni surface. Here we report on a new regeneration process, which can effectively and efficiently regenerate the sulfur-poisoned Ni reforming catalysts. This process consists of four sequential treatments: 1) controlled oxidation at 750oC in 1% O2, 2) decomposition at 900oC in Ar, 3) reduction at 900oC in 2% H2, and 4) reaction at 900oC under reforming condition. The duration of this 4-step regeneration process is only about 8 hours, which is shorter than that of the conventional steaming regeneration treatment.

Li, Liyu; Howard, Christopher J.; King, David L.; Gerber, Mark A.; Dagle, Robert A.; Stevens, Don J.

2010-09-14T23:59:59.000Z

382

Improving the Ni I atomic model for solar and stellar atmospheric models  

E-Print Network (OSTI)

Neutral nickel (Ni I) is abundant in the solar atmosphere and is one of the important elements that contribute to the emission and absorption of radiation in the spectral range between 1900 and 3900 A. Previously, the Solar Radiation Physical Modeling (SRPM) models of the solar atmosphere considered only few levels of this species. Here we improve the Ni I atomic model by taking into account 61 levels and 490 spectral lines. We compute the populations of these levels in full NLTE using the SRPM code and compare the resulting emerging spectrum with observations. The present atomic model improves significantly the calculation of the solar spectral irradiance at near-UV wavelengths that are important for Earth atmo spheric studies, and particularly for ozone chemistry.

Vieytes, Mariela C

2013-01-01T23:59:59.000Z

383

Formation of Mg{sub 2}Ni with enhanced kinetics: Using MgH{sub 2} instead of Mg as a starting material  

Science Conference Proceedings (OSTI)

At a temperature over the decomposition point (375 Degree-Sign C) of MgH{sub 2}, the formation of Mg{sub 2}Ni is greatly enhanced from the 2MgH{sub 2}+Ni system, as compared to the 2Mg+Ni system. In support of this finding, in-situ observation of X-ray absorption fine structure of the two systems indicates that Mg---Ni bonds form faster in the 2MgH{sub 2}+Ni system than in the 2Mg+Ni system. Furthermore, theoretical modeling also shows that Mg atoms are readily released from MgH{sub 2} using much less energy and thus are more available to react with Ni once the dehydrogenation of MgH{sub 2} occurs, as compared to normal Mg. - Graphical Abstract: The formation of Mg{sub 2}Ni is greatly enhanced by using MgH{sub 2} instead of Mg at a temperature higher than the MgH{sub 2} decomposition point. Highlights: Black-Right-Pointing-Pointer A new and efficient synthesis of Mg-based compounds at a reduced temperature. Black-Right-Pointing-Pointer Mg{sub 2}Ni formation is enhanced by using MgH{sub 2} instead of Mg as a starting material. Black-Right-Pointing-Pointer XAFS results show that Mg---Ni bonds are formed faster in 4MgH{sub 2}+Ni than in 4Mg+Ni. Black-Right-Pointing-Pointer DFT calculations show that Mg atoms are released from MgH{sub 2} more readily than from Mg. Black-Right-Pointing-Pointer Mg formed by MgH{sub 2} dehydrogenation is more available to react with Ni than normal Mg.

Zhao Bin [Department of Materials Science, Fudan University, Shanghai 200433 (China); School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002 (China); Fang Fang [Department of Materials Science, Fudan University, Shanghai 200433 (China); Sun Dalin, E-mail: dlsun@fudan.edu.cn [Department of Materials Science, Fudan University, Shanghai 200433 (China); Zhang Qingan [School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002 (China); Wei Shiqiang [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Cao Fenglei; Sun Huai [Department of Chemistry, Shanghai Jiaotong University, Shanghai 200240 (China); Ouyang Liuzhang [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 (China); Zhu Min, E-mail: memzhu@scut.edu.cn [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 (China)

2012-08-15T23:59:59.000Z

384

A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane  

Science Conference Proceedings (OSTI)

A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

2011-12-15T23:59:59.000Z

385

Application of Brazilian kaolinite clay as adsorbent to removal of U(VI) from aqueous solution: Kinetic and thermodynamic of cation-basic interactions  

SciTech Connect

The compound N{sup 1}-[3-(trimethoxysilyl)propyl]diethylenetriamine was anchored onto Amazon kaolinite surface by heterogeneous route. The modified and natural kaolinite samples were characterized by transmission electron microscopy, scanning electron microscopic, X-ray diffraction, and nuclear magnetic nuclei of {sup 29}Si and {sup 13}C. The well-defined peaks obtained in the {sup 13}C NMR spectrum in the 5.0-62.1 ppm region confirmed the attachment of organic functional groups as pendant chains bonded into the porous clay. The ability of these materials to remove U(VI) from aqueous solution was followed by a series of adsorption isotherms adjusted to a Sips equation at room temperature and pH 4.0. The kinetic parameters analyzed by the Lagergren and Elovich models gave a good fit for a pseudo-second order reaction with k{sub 2} values 16.0 and 25.1 mmol g{sup -1} min{sup -1} ranges for natural and modified kaolinite clays, respectively. The energetic effects caused by metal ion adsorption were determined through calorimetric titrations. - Graphical abstract: This investigation reports the use of original and modified kaolinites as alternative absorbents. The compound N-[3-trimethoxysilyl)propyl]diethylenetriamine was anchored onto Amazon kaolinite surface by heterogeneous route.

Guerra, Denis L., E-mail: denis@cpd.ufmt.b [Universidade Federal de Mato Grosso, UFMT, Centro de Recursos Minerais, Cuiaba 78060 900, Mato Grosso (Brazil); Leidens, Victor L.; Viana, Rubia R. [Universidade Federal de Mato Grosso, UFMT, Centro de Recursos Minerais, Cuiaba 78060 900, Mato Grosso (Brazil); Airoldi, Claudio [Chemistry Institute, State University of Campinas, P.O. Box 6154, 13084-971 Campinas, Sao Paulo (Brazil)

2010-05-15T23:59:59.000Z

386

Apparatus for forming thin-film heterojunction solar cells employing materials selected from the class of I-III-VI.sub.2 chalcopyrite compounds  

DOE Patents (OSTI)

Apparatus for forming thin-film, large area solar cells having a relatively high light-to-electrical energy conversion efficiency and characterized in that the cell comprises a p-n-type heterojunction formed of: (i) a first semiconductor layer comprising a photovoltaic active material selected from the class of I-III-VI.sub.2 chalcopyrite ternary materials which is vacuum deposited in a thin "composition-graded" layer ranging from on the order of about 2.5 microns to about 5.0 microns (.congruent.2.5 .mu.m to .congruent.5.0 .mu.m) and wherein the lower region of the photovoltaic active material preferably comprises a low resistivity region of p-type semiconductor material having a superimposed region of relatively high resistivity, transient n-type semiconductor material defining a transient p-n homojunction; and (ii), a second semiconductor layer comprising a low resistivity n-type semiconductor material wherein interdiffusion (a) between the elemental constituents of the two discrete juxtaposed regions of the first semiconductor layer defining a transient p-n homojunction layer, and (b) between the transient n-type material in the first semiconductor layer and the second n-type semiconductor layer, causes the transient n-type material in the first semiconductor layer to evolve into p-type material, thereby defining a thin layer heterojunction device characterized by the absence of voids, vacancies and nodules which tend to reduce the energy conversion efficiency of the system.

Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

1983-01-01T23:59:59.000Z

387

Coupled Biogeochemical Processes Governing the Stability of Bacteriogenic Uraninite and Release of U(VI) in Heterogeneous Media: Molecular to Meter Scales  

SciTech Connect

In-situ reductive biotransformation of subsurface U(VI) to U(IV) (as ?UO2?) has been proposed as a bioremediation method to immobilize uranium at contaminated DOE sites. The chemical stability of bacteriogenic ?UO2? is the seminal issue governing its success as an in-situ waste form in the subsurface. The structure and properties of chemically synthesized UO2+x have been investigated in great detail. It has been found to exhibit complex structural disorder, with nonstoichiometry being common, hence the designation ?UO2+x?, where 0 < x < 0.25. Little is known about the structures and properties of the important bacteriogenic analogs, which are believed to occur as nanoparticles in the environment. Chemically synthesized UO2+x exhibits an open fluorite structure and is known to accommodate significant doping of divalent cations. The extent to which bacteriogenic UO2+x incorporates common ground water cations (e.g., Ca2+) has not been investigated, and little is known about nonstoichiometry and structure defects in the bacteriogenic material. Particle size, nonstoichiometry, and doping may significantly alter the reactivity, and hence stability, of bacteriogenic UO2+x in the subsurface. The presence of associated sulfide minerals, and solid phase oxidants such as bacteriogenic Mn oxides may also affect the longevity of bacteriogenic UO2 in the subsurface.

Bargar, John R.

2006-11-15T23:59:59.000Z

388

Chromium Grain-boundary Segregation and Effect of Ion Beam Cleaning on Fe-Ni-Cr Alloys  

SciTech Connect

The grain boundaries play important role to control the mechanical strength of ternary alloys. From spacecrafts to naval vessels to nuclear reactors, stress corrosion cracking, brittleness, oxidation mostly originates at the grain boundaries and cause long term structural stability problems in most of the metallic structures [1]. Fe-Ni-Cr based ternary metal alloys have been widely studied for more than fifty years [2, 3]. Despite of vast amount of research, chromium diffusion in stainless steel or other Ni-Fe-Cr based ternary alloys is still an open scientific problem with challenges in structural stability and corrosion resistance [4]. Particularly, austenite Fe-Ni-Cr is looked upon favorably in space and jet engine industry for their improved resistance to stress corrosion cracking [5]. In solid oxide fuel cells (SOFC), Ni-alloys are frequently used as interconnects and seals [6]. In this communication, simultaneous energy dispersive spectroscopy (EDS) and electron backscatter diffraction (EBSD) mapping is utilized to study chemical and structural aspects of chromium segregation in Fe-Ni-Cr alloy. A focused Ga-ion beam is also utilized to study the effect of ion beam cleaning on EBSD image quality (IQ) and inverse pole figure (IPF) maps of Fe-Ni-Cr alloy.

Saraf, Laxmikant V.

2011-04-01T23:59:59.000Z

389

Duplex Oxide Formation during Transient Oxidation of Cu-5%Ni(001) Investigated by In situ UHV-TEM and XPS  

Science Conference Proceedings (OSTI)

The transient oxidation stage of a model metal alloy thin film was characterized with in situ ultra-high vacuum (UHV) transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and analytic high-resolution TEM. We observed the formations of nanosized NiO and Cu{sub 2}O islands when Cu-5a5%Ni(100) was exposed to oxygen partial pressure, pO{sub 2} = 1 x 10{sup -4} Torr and various temperatures in situ. At 350 C epitaxial Cu{sub 2}O islands formed initially and then NiO islands appeared on the surface of the Cu{sub 2}O island, whereas at 750 C NiO appeared first. XPS and TEM was used to reveal a sequential formation of NiO and then Cu{sub 2}O islands at 550 C. The temperature-dependant oxide selection may be due to an increase of the diffusivity of Ni in Cu with increasing temperature.

Yang, J.C.; Starr, D.; Kang, Y.; Luo, L.; Tong, X.; Zhou, G.

2012-05-20T23:59:59.000Z

390

Biological availability of nickel arsenides: toxic effects of particulate Ni/sub 5/As/sub 2/  

SciTech Connect

Considerations of (1) oil shale retort operating conditions, (2) oil shale elemental composition, (3) nickel and arsenic physico-chemical properties, and (4) oil shale matrix structure lead to the suggestion that nickel arsenides may be formed during the oil shale retorting process. The biological effects of nickel arsenides have not been previously studied. However, similarities between nickel subarsenide and nickel subsulfide and nickel subselenimide, both of which are known potent carcinogens, have caused concern that nickel arsenides may have adverse effects on biological systems. To determine if fugitive nickel arsenides from an oil shale retort could pose a threat to personnel in the workplace or to other living organisms in the environment, a program to study the toxicity of nickel arsenides has been initiated. Five stable nickel arsenides (Ni/sub 5/As/sub 2/, Ni/sub 2/As, Ni/sub 11/As/sub 8/, NiAs, and NiAs/sub 2/) and nickel arsenic sulfide (NiAsS) are considered possible species for study.

Gurley, L.R.; Tobey, R.A.; Valdez, J.G.; Halleck, M.S.; Barham, S.S.

1981-01-01T23:59:59.000Z

391

Structural studies of two novel La-Sn compounds: La30Sn30 and La32Ni2Sn35  

Science Conference Proceedings (OSTI)

Two novel intermetallic compounds containing lanthanum and tin have been obtained for the first time. Single crystal structures of these two phases, La{sub 30}Sn{sub 30} and La{sub 32}Ni{sub 2}Sn{sub 35} have been studied by X-ray crystallography. La{sub 30}Sn{sub 30} is a new 1:1 binary containing La and Sn and has been refined in the Cmmm space group. This phase was made at high temperatures ( 1200 C) and refined in the 14/mmm space group. It belongs to the USi structure type in which the Ni/Sn atoms occupy the Si sites, and La/Sn atoms occupy the U sites. The crystal structure of La{sub 32}Ni{sub 2}Sn{sub 35} consists of buckled sheets made from La-centered, corner-shared octahedra of Sn. These sheets are intraconnected through Ni-Sn-Ni bonds along the c-axis. The crystals are not air sensitive, unlike La{sub 30}Sn{sub 30}, which can be attributed to the presence of Ni in the crystal structure.

Yang, Amie S.

2005-05-01T23:59:59.000Z

392

Catalytic partial oxidation of methane to synthesis gas over Ni-based catalysts. 1: Catalyst performance characteristics  

SciTech Connect

The catalytic partial oxidation of methane to synthesis gas was studied over various Ni-based catalysts. It was found that, in contrast to conventional Ni catalysts which show continuous deactivation with time on stream, the Ni/La{sub 2}O{sub 3} catalyst exhibits good activity and excellent stability, using the stoichiometric ratio of CH{sub 4}/O{sub 2} (=2). Kinetic results indicate that the reaction over the Ni/La{sub 2}O{sub 3} catalyst follows mainly the sequence of total oxidation to CO{sub 2} and H{sub 2}O, followed by reforming reactions to synthesis gas, while CO formation via the direct route is observed at very low oxygen partial pressures. Chemisorption and FTIR studies show that the enhanced stability of the Ni/La{sub 2}O{sub 3} catalyst is related to decoration of the Ni crystallites with lanthanum species, primarily oxycarbonates, which favor removal of excess carbon deposition and impart the catalyst its stability characteristics.

Tsipouriari, V.A.; Zhang, Z.; Verykios, X.E. [Univ. of Patras (Greece). Dept. of Chemical Engineering

1998-10-01T23:59:59.000Z

393

Corrosion Behavior of NiCrFe Alloy 600 in High Temperature, Hydrogenated Water  

SciTech Connect

The corrosion behavior of Alloy 600 (UNS N06600) is investigated in hydrogenated water at 260 C. The corrosion kinetics are observed to be parabolic, the parabolic rate constant being determined by chemical descaling to be 0.055 mg dm{sup -2} hr{sup -1/2}. A combination of scanning and transmission electron microscopy, supplemented by energy dispersive X-ray spectroscopy and grazing incidence X-ray diffraction, are used to identify the oxide phases present (i.e., spinel) and to characterize their morphology and thickness. Two oxide layers are identified: an outer, ferrite-rich layer and an inner, chromite-rich layer. X-ray photoelectron spectroscopy with argon ion milling and target factor analysis is applied to determine spinel stoichiometry; the inner layer is (Ni{sub 0.7}Fe{sub 0.3})(Fe{sub 0.3}Cr{sub 0.7}){sub 2}O{sub 4}, while the outer layer is (Ni{sub 0.9}Fe{sub 0.1})(Fe{sub 0.85}Cr{sub 0.15}){sub 2}O{sub 4}. The distribution of trivalent iron and chromium cations in the inner and outer oxide layers is essentially the same as that found previously in stainless steel corrosion oxides, thus confirming their invariant nature as solvi in the immiscible spinel binary Fe{sub 3}O{sub 4}-FeCr{sub 2}O{sub 4} (or NiFe{sub 2}O{sub 4}-NiCr{sub 2}O{sub 4}). Although oxidation occurred non-selectively, excess quantities of nickel(II) oxide were not found. Instead, the excess nickel was accounted for as recrystallized nickel metal in the inner layer, as additional nickel ferrite in the outer layer, formed by pickup of iron ions from the aqueous phase, and by selective release to the aqueous phase.

SE Ziemniak; ME Hanson

2004-11-02T23:59:59.000Z

394

Mn deposition on Ni{sub 2}MnGa(100)  

Science Conference Proceedings (OSTI)

We report the study of Mn adlayers on a Mn deficient Ni{sub 2}MnGa(100) surface by using low energy electron diffraction (LEED). The spot profile analysis indicates that after 0.2 monolayer (ML) deposition, the LEED spots become very sharp. This pattern indicates the removal of Mn vacancies formed on the surface due to Mn deficiency. But with further growth of Mn layers on this surface, the LEED spots become broad.

Nayak, J.; Rai, Abhishek; D'Souza, S. W.; Maniraj, M.; Barman, S. R. [UGC-DAE Consortium for Scientific Research, Khandwa Road, Indore, 452001, M.P. (India)

2012-06-05T23:59:59.000Z

395

Formation and Stability of Ni-Al Hydroxide Phases in Soils  

E-Print Network (OSTI)

Formation and Stability of Ni-Al Hydroxide Phases in Soils E D W A R D P E L T I E R , § , * , D A N I E L V A N D E R L E L I E , A N D D O N A L D L . S P A R K S Environmental Soil Chemistry Research Group, Department of Plant and Soil Sciences and Delaware Environmental Institute, 152 Townsend

Sparks, Donald L.

396

Synthesis of mesoporous NiO doped TiO{sub 2} submicrosphere via spray hydrolysis  

Science Conference Proceedings (OSTI)

NiO doped TiO{sub 2} submicrosphere have been prepared via spray hydrolysis. The doping concentration has been varied form 2 wt% to 15 wt%. Morphology of the submicrospheres has been investigated using small-angle neutron scattering and scanning electron microscopy. Elemental analysis has been carried out by energy dispersive X-ray analysis which confirms the doping concentrations. The mesopores in submicrospheres possess cylindrical morphology.

Bahadur, J.; Sen, D.; Prakash, J.; Singh, Ripandeep; Paul, B.; Mazumder, S.; Sathiyamoorthy, D. [Solid State Physics Division Bhabha Atomic Research Centre, Mumbai, 400085, India (India); Powder Metallurgy Division Bhabha Atomic Research Centre, Mumbai, 400085 (India); Solid State Physics, Division Bhabha Atomic Research Centre, Mumbai, 400085 (India); Materials Processing Division Bhabha Atomic Research Centre, Mumbai, 400085 (India); Solid State Physics Division Bhabha Atomic Research Centre, Mumbai, 400085 (India); Powder Metallurgy Division Bhabha Atomic Research Centre, Mumbai, 400085 (India)

2012-06-05T23:59:59.000Z

397

Plasma Sprayed Ni-Al Coatings for Safe Ending Heat Exchanger Tubes  

DOE Green Energy (OSTI)

Brookhaven National Laboratory (BNL) has developed thermally conductive composite liners for corrosion and scale protection in heat exchanger tubes exposed to geothermal brine. The liners cannot withstand roller expansion to connect the tubes to the tubesheet. It is not possible to line the ends of the tubes with the same material after roller expansion due to the nature of the current liner application process. It was requested that BNL evaluate plasma sprayed Ni-Al coatings for safe ending heat exchanger tubes exposed to geothermal brine. The tubes of interest had an internal diameter of 0.875 inches. It is not typical to thermal spray small diameter components or use such small standoff distances. In this project a nozzle extension was developed by Zatorski Coating Company to spray the tube ends as well as flat coupons for testing. Four different Ni-Al coatings were investigated. One of these was a ductilized Ni-AlB material developed at Oak Ridge National Laboratory. The coatings were examined by optical and scanning electron microscopy. In addition, the coatings were analyzed by X-ray diffraction and subjected to corrosion, tensile adhesion, microhardness and field tests in a volcanic pool in New Zealand.

Allen, M.L.; Berndt, C.C.; Otterson, D.

1998-11-01T23:59:59.000Z

398

High Energy Density Na-S/NiCl2 Hybrid Battery  

SciTech Connect

High temperature (250-350C) sodium-beta alumina batteries (NBBs) are attractive energy storage devices for renewable energy integration and other grid related applications. Currently, two technologies are commercially available in NBBs, e.g., sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries. In this study, we investigated the combination of these two chemistries with a mixed cathode. In particular, the cathode of the cell consisted of molten NaAlCl4 as a catholyte and a mixture of Ni, NaCl and Na2S as active materials. During cycling, two reversible plateaus were observed in cell voltage profiles, which matched electrochemical reactions for Na-S and Na-NiCl2 redox couples. An irreversible reaction between sulfur species and Ni was identified during initial charge at 280C, which caused a decrease in cell capacity. The final products on discharge included Na2Sn with 1< n < 3, which differed from Na2S3 found in traditional Na-S battery. Reduction of sulfur in the mixed cathode led to an increase in overall energy density over ZEBRA batteries. Despite of the initial drop in cell capacity, the mixed cathode demonstrated relatively stable cycling with more than 95% of capacity retained over 60 cycles under 10mA/cm2. Optimization of the cathode may lead to further improvements in battery performance.

Lu, Xiaochuan; Lemmon, John P.; Kim, Jin Yong; Sprenkle, Vincent L.; Yang, Zhenguo (Gary) [Gary

2013-02-15T23:59:59.000Z

399

Investigation of Modified Ni-Cr-Mn Base Alloys for SOFC Interconnect Applications  

Science Conference Proceedings (OSTI)

Two Ni-Cr-W-Mn base alloys based on Haynes 230 were developed and evaluated against criteria relevant to SOFC interconnect applications, which included oxidation behavior under SOFC operating conditions, scale electrical conductivity, and thermal expansion. It was found that, similar to the ferritic stainless steel Crofer22 APU, additions of Mn led to the formation of a unique scale that was comprised of a M3O4 (M=Mn, Cr, Ni, ) spinel-rich top layer and Cr2O3-rich sub-layer. The modified alloys demonstrated reasonable oxidation resistance under SOFC operating conditions, though the Mn additions increased the scale growth rate and thus sacrificed to some extent the oxidation resistance of the base alloy (Haynes 230). The formation of a spinel-rich top layer improved the scale conductivity, especially during the early stages of oxidation, but the higher scale growth rate resulted in a higher rate of increase in the area-specific electrical resistance. Due to their FCC crystal structure, the Ni-Cr-W-Mn base alloys demonstrated a CTE that was higher than that of anode-supported cells and candidate ferritic stainless steels such as Crofer22 APU.

Yang, Z Gary; Singh, Prabhakar; Stevenson, Jeffry W.; Xia, Gordon

2006-09-01T23:59:59.000Z

400

Computational study of hydrocarbon adsorption in metal-organic framework Ni2(dhtp)  

SciTech Connect

Molecular dynamic simulations were carried out to study the sorption, structural properties, and diffusivities of n-hexane and cyclohexane adsorbed in Ni2(dhtp). The results indicated strong interactions between the alkanes and the host material. The free energy perturbation method was employed to investigate the adsorption free energies of methane, ethane, n-butane, n-hexane and cyclohexane. For linear alkanes, the free energy lowered as the length of the carbon chain increased. Also, the adsorption of n-hexane was preferred over cyclohexane, due to its ability to rearrange its structure to maximize contacts with the host. Furthermore, due to the large pore size of Ni2(dhtp), higher loadings of alkanes did not significantly affect the alkane structure, and enhanced the free energy of adsorption for subsequent alkanes being loaded. According to our studies, Ni2(dhtp) has a very promising potential for adsorption and storage of alkanes. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Sun, Xiuquan; Wick, Collin D.; Thallapally, Praveen K.; McGrail, B. Peter; Dang, Liem X.

2011-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
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401

Bimetallic IrNi Core Platinum Monolayer Shell Electrocatalysts for the Oxygen Reduction Reaction  

DOE Green Energy (OSTI)

We synthesized a low-Pt content electrocatalyst consisting of a Pt monolayer placed on carbon-supported thermally treated IrNi core-shell structured nanoparticles using galvanic displacement of a Cu monolayer deposited at underpotentials. The Pt mass activity of the Pt{sub ML}/IrNi/C electrocatalyst obtained in a scale-up synthesis is approximately 3 times higher than that of the commercial Pt/C electrocatalyst. The electronic and geometrical effects of the IrNi substrate on the Pt monolayer result in its higher catalytic activity than that of Pt nanoparticles. The structure and composition of the core-shell nanoparticles were verified using transmission electron microscopy and in situ X-ray absorption spectroscopy, while a potential cycling test was employed to confirm the stability of the electrocatalyst. Our experimental results, supported by the density functional calculations using a sphere-like model, demonstrate an effective way of using Pt that can resolve key problems of cathodic oxygen reduction hampering fuel cell commercialization.

Kuttiyiel K. A.; Sasaki, K.; Choi, Y.M.; Su, D.; Liu, P.; Adzic, R.R.

2012-01-01T23:59:59.000Z

402

Single-photon emission from Ni-related color centers in CVD diamond  

E-Print Network (OSTI)

Color centers in diamond are very promising candidates among the possible realizations for practical single-photon sources because of their long-time stable emission at room temperature. The popular nitrogen-vacancy center shows single-photon emission, but within a large, phonon-broadened spectrum (~100nm), which strongly limits its applicability for quantum communication. By contrast, Ni-related centers exhibit narrow emission lines at room temperature. We present investigations on single color centers consisting of Ni and Si created by ion implantation into single crystalline IIa diamond. We use systematic variations of ion doses between 10^8/cm^2 and 10^14/cm^2 and energies between 30keV and 1.8MeV. The Ni-related centers show emission in the near infrared spectral range (~770nm to 787nm) with a small line-width (~3nm FWHM). A measurement of the intensity correlation function proves single-photon emission. Saturation measurements yield a rather high saturation count rate of 77.9 kcounts/s. Polarization dependent measurements indicate the presence of two orthogonal dipoles.

David Steinmetz; Elke Neu; Christian Hepp; Roland Albrecht; Wolfgang Bolse; Jan Meijer; Detlef Rogalla; Christoph Becher

2010-03-17T23:59:59.000Z

403

Laser power beaming to extend lives of GSO NiCd satellites  

DOE Green Energy (OSTI)

It is proposed that a ground-based laser can beam power to commercial communication satellites in geosynchronous orbit and reduce battery depth-of-discharge during eclipses. Two laser system designs are presented which have the capability of reducing battery discharge by 100%. Both utilize a steerable beam director, with a mirror diameter of 4 meters in one case and 8 meters in the other. Both also use an adaptive optics unit within the beam train to provide real-time corrections for wavefront distortions caused by atmospheric turbulence. The required system power output is in the range of 100 to 200 kW for a transmitted wavelength just under 900 nm. Laser power beaming can nearly double the remaining lifetime of a satellite that uses NiCd batteries. However, by the time such lasers become available, nearly all NiCd satellites will be replaced by NiH{sub 2} satellites, which stand to benefit much less from power beaming.

Monroe, D.K.

1993-12-31T23:59:59.000Z

404

The influence of FeTi and NiTi intermetallide additions on high-temperature oxidation of permalloy alloy  

Science Conference Proceedings (OSTI)

As a rule powder metallurgy Permalloy alloys are used in production of parts for electronic instruments. For the purpose of controlling the magnetic and electrical properties and also the wear (in the case of production of magnetic heads) and corrosion resistance appropriate additions of metals or such compounds as carbides and oxides are added to the alloy. In this work use of FeTi and NiTi intermetallides produced by reaction sintering of powders of pure metals in a protective atmosphere as alloying additions to Permalloy is recommended. The size of the original powders is less than 100 {mu}m. For reaction sintering at temperature 50{degrees}C above the eutectic temperature in the Ti-TiFe and TiNi-Ni systems was selected. The contents of titanium, iron, and oxygen in the FeTi alloy is 51.9, 45.7, and 2.4 wt.%, respectively, and of titanium, nickel, and oxygen in the NiTi alloy 59.6, 31.9, and 4.6 wt.%. High-temperature oxidation in air up to 1300{degrees}C with a rate of change in temperature of 15{degrees}C of type 78N Permalloy with additions of FeTi and NiTi alloys was investigated with use of methods of differential thermal and differential thermogravimetric analyses on an OD-103 derivatograph under nonisothermal conditions. The reaction products were studied by x-ray diffraction phase analysis on a DRON-3 instrument in CoK{sub {alpha}}-radiation. Pure 78N alloy powder with a composition of 78.1% Ni + 19.3% Fe (specimen 1) and also with additions of 1% FeTi (specimen 2) and 1% NiTi (specimen 3) were subjected to oxidation.

Klimenko, V.N.; Lavrenko, V.A.; Panasyuk, O.A.; Blasova, O.V.; Protsenko, T.G. [Inst. of Materials Science, Kiev (Ukraine)

1995-11-01T23:59:59.000Z

405

Structural studies of two novel La-Sn compounds: La30Sn30 and La32Ni2Sn35  

SciTech Connect

Two novel intermetallic compounds containing lanthanum and tin have been obtained for the first time. Single crystal structures of these two phases, La{sub 30}Sn{sub 30} and La{sub 32}Ni{sub 2}Sn{sub 35} have been studied by X-ray crystallography. La{sub 30}Sn{sub 30} is a new 1:1 binary containing La and Sn and has been refined in the Cmmm space group. This phase was made at high temperatures (<1200 C) from a loaded composition of La{sub 68}Sn{sub 70}. Unlike the reported 1:1 binary, LaSn which crystallizes in the Cmcm space group (only powder X-ray diffraction studies reported), La{sub 30}Sn{sub 30} forms good crystals for structural determination. The crystal structure of La{sub 30}Sn{sub 30} show Sn-Sn dimers and Sn-centered, face-sharing biaugmented triangular prisms composed of La atoms. La{sub 30}Sn{sub 30} does not belong to any known structure-type. La{sub 32}Ni{sub 2}Sn{sub 35} was obtained in high yields at high temperatures (> 1200 C) and refined in the 14/mmm space group. It belongs to the USi structure type in which the Ni/Sn atoms occupy the Si sites, and La/Sn atoms occupy the U sites. The crystal structure of La{sub 32}Ni{sub 2}Sn{sub 35} consists of buckled sheets made from La-centered, corner-shared octahedra of Sn. These sheets are intraconnected through Ni-Sn-Ni bonds along the c-axis. The crystals are not air sensitive, unlike La{sub 30}Sn{sub 30}, which can be attributed to the presence of Ni in the crystal structure.

Yang, Amie S.

2005-05-01T23:59:59.000Z

406

Computer simulation of sputtering at the low index (1 0 0), (1 1 0) and (1 1 1) surfaces of Ni3Al in a STEM  

Science Conference Proceedings (OSTI)

The present study is relevant to the preferential Al sputtering and/or enhancement of the Ni/Al ratio in Ni3Al observed by the scanning transmission electron microscopy fitted with a field emission gun (FEG STEM). Atomic recoil events at the low index (1 0 0), (1 1 0) and (1 1 1) surfaces of Ni3Al through elastic collisions between electrons and atoms are simulated using molecular dynamics (MD) methods. The threshold energy for sputtering, Esp, and adatom creation, Ead, are determined as a function of recoil direction. Based on the MD determined Esp, the sputtering cross-sections for Ni and Al atoms in these surfaces are calculated with the previous proposed model. It is found that the sputtering cross-section for Al atoms is about 78 times higher than that for Ni, indicating the preferential sputtering of Al in Ni3Al, in good agreement with experiments. It is also found that the sputtering cross-sections for Ni atoms are almost the same in these three surfaces, suggesting that they are independent of surface orientation. Thus, the sputtering process is almost independent of the surface orientation in Ni3Al, as it is controlled by the sputtering of Ni atoms with a lower sputtering rate.

Lai, Wenshen; Yu, J. J.; Gao, Fei; Bacon, David J.

2009-09-15T23:59:59.000Z

407

High-pressure stability relations, crystal structures, and physical properties of perovskite and post-perovskite of NaNiF{sub 3}  

Science Conference Proceedings (OSTI)

NaNiF{sub 3} perovskite was found to transform to post-perovskite at 16-18 GPa and 1273-1473 K. The equilibrium transition boundary is expressed as P (GPa)=-2.0+0.014 Multiplication-Sign T (K). Structure refinements indicated that NaNiF{sub 3} perovskite and post-perovskite have almost regular NiF{sub 6} octahedra consistent with absence of the first-order Jahn-Teller active ions. Both NaNiF{sub 3} perovskite and post-perovskite are insulators. The perovskite underwent a canted antiferromagnetic transition at 156 K, and the post-perovskite antiferromagnetic transition at 22 K. Magnetic exchange interaction of NaNiF{sub 3} post-perovskite is smaller than that of perovskite, reflecting larger distortion of Ni-F-Ni network and lower dimension of octahedral arrangement in post-perovskite than those in perovskite. - Graphical abstract: Perovskite-post-perovskite transition in NaNiF{sub 3} at high pressure Highlights: Black-Right-Pointing-Pointer NaNiF{sub 3} perovskite (Pv) transforms to post-perovskite (pPv) at 16 GPa and 1300 K. Black-Right-Pointing-Pointer The equilibrium transition boundary is expressed as P (GPa)=-2.0+0.014 T (K). Black-Right-Pointing-Pointer Antiferromagnetic transition occurs at 156 K in Pv and 22 K in pPv.

Shirako, Y. [Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Shi, Y.G. [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Institute of Physics, Chinese Academy of Sciences, 100190 Beijing (China); Aimi, A.; Mori, D.; Kojitani, H. [Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588 (Japan); Yamaura, K. [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Inaguma, Y. [Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588 (Japan); Akaogi, M., E-mail: masaki.akaogi@gakushuin.ac.jp [Department of Chemistry, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588 (Japan)

2012-07-15T23:59:59.000Z

408

Ab initio calculations and synthesis of the off-stoichiometric half-Heusler phase Ni{sub 1-x}Mn{sub 1+x}Sb  

SciTech Connect

We perform a combined theoretical and experimental study of the phase stability and magnetism of the off-stoichiometric Ni{sub 1-x}Mn{sub 1+x}Sb in the half-Heusler crystal phase. Our work is motivated by the need for strategies to engineer the magnetism of potentially half-metallic materials, such as NiMnSb, for improved performance at elevated temperatures. By means of ab initio calculations we investigate Ni{sub 1-x}Mn{sub 1+x}Sb over the whole composition range 0{<=}x{<=}1 of Ni replacing Mn and show that at relevant temperatures, the half-Heusler phase should be thermodynamically stable up to at least x=0.20 with respect to the competing C38 structure of Mn{sub 2}Sb. Furthermore we find that half-Heusler Ni{sub 1-x}Mn{sub 1+x}Sb retains half-metallic band structure over the whole concentration range and that the magnetic moments of substitutional Mn{sub Ni} atoms display magnetic exchange interactions an order of magnitude larger than the Ni-Mn interaction in NiMnSb. We also demonstrate experimentally that the alloys indeed can be created by synthesizing off-stoichiometric Ni{sub 1-x}Mn{sub 1+x}Sb films on MgO substrates by means of magnetron sputtering.

Ekholm, M.; Larsson, P.; Alling, B.; Helmersson, U.; Abrikosov, I. A. [Department of Physics, Chemistry and Biology (IFM), Linkoeping University, SE-58183 Linkoeping (Sweden)

2010-11-15T23:59:59.000Z

409

Low-Temperature Solution-Phase Synthesis of NiAu Alloy Nanoparticles via Butyllithium Reduction: Influences of Synthesis Details and Application as the Precursor to Active Au0NiO/Si02 Catalysts Through Proper Pretreatments  

SciTech Connect

Bimetallic nanoparticles (NPs) have wide applications in electronics, photonics, and catalysis. However, it is particularly challenging to synthesize size-controllable alloy nanoparticles (e.g., NiAu) with bulk immiscible metals as the components. Here we report the synthesis of isolable NiAu alloy nanoparticles with tunable and relatively uniform sizes via a coreduction method employing butyllithium as the reducing agent and trioctylphosphine as the protecting agent. The influences of synthesis conditions (e.g., protecting agent, aging temperature, and the solvent used to wash the product) were investigated, and the synthesis mechanism was preliminarily surveyed. The NiAu alloy nanoparticles obtained were then used as the precursor to prepare an Au-NiO/SiO2 catalyst highly active in low-temperature CO oxidation, and the effects of pretreatment details and catalyst compositions on catalytic activity were studied. Relevant characterization employing XRD, TEM, UV-vis, TG/DTG, and FT-IR was conducted. In addition, the importance of the current synthesis of NiAu alloy NPs and the contribution of the catalyst design were discussed in the context of the literature.

Zhou, Shenghu [ORNL; Ma, Zhen [ORNL; Yin, Hongfeng [ORNL; Wu, Zili [ORNL; Eichhorn, Bryan [University of Maryland; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2009-01-01T23:59:59.000Z

410

Stabilization of Nickel Complexes with Ni0H-N Bonding Interactions Using Sterically Demanding Cyclic Diphosphine Ligands  

Science Conference Proceedings (OSTI)

The series of complexes Ni(P{sub 2}{sup tBu}N{sub 2}{sup R}), [Ni(P{sub 2}{sup tBu}N{sub 2}{sup R}){sub 2}]BF{sub 4}, [HNi(P{sub 2}{sup tBu}N{sub 2}{sup Ph}){sub 2}]BF{sub 4}, and [Co(P{sub 2}{sup tBu}N{sub 2}{sup Ph}){sub 2}]BF{sub 4} (P{sub 2}{sup tBu}N{sub 2}{sup R} = 1,5-dialkyl-3,7-tert-butyl-1,5-diaza-3,7-diphosphacyclooctane; alkyl (R) = phenyl, benzyl) have been synthesized and characterized. Spectroscopic, electrochemical, and X-Ray diffraction studies indicate these complexes are stable as a result of the tetrahedral arrangement of the two diphosphine ligands. Electrochemical oxidation of [HNi(P{sub 2}{sup tBu}N{sub 2}{sup Ph}){sub 2}]BF{sub 4} results in rapid proton transfer from nickel at a rate faster that can be observed on the CV timescale. Double protonation of Ni(P{sub 2}{sup tBu}N{sub 2}{sup BN}){sub 2} forms the endo-endo, endo exo, and exo-exo isomers of [Ni(P{sub 2}{sup tBu}N{sup BN}HN{sup BN}){sub 2}](BF{sub 4}){sub 2}, which were found to be more stable towards loss of H{sub 2} than previously observed for similar complexes. The presence of Ni{sup 0} {hor_ellipsis} HN bonds at the endo-protonation sites of [Ni(P{sub 2}{sup tBu}N{sup Bn}HN{sup BN}){sub 2}](BF{sub 4}){sub 2} results in significant differences in the Ni(I/0) oxidation potentials of each of the isomers. The differences in E{sub 1/2}(I/0) values correspond to bond free energies of 7.4 and 3.7 kcal/mol for the first and second Ni{sup 0} {hor_ellipsis} HN bonds of the endo-exo and endo-endo isomers, respectively. Computational studies of related model complexes reproduce these Ni{sup 0} {hor_ellipsis} HN bonds within 1-2 kcal/mol.

Wiedner, Eric S.; Yang, Jenny Y.; Chen, Shentan; Raugei, Simone; Dougherty, William G.; Kassel, W. S.; Helm, Monte L.; Bullock, R. Morris; Rakowski DuBois, Mary; DuBois, Daniel L.

2012-01-09T23:59:59.000Z

411

Interaction of Metallophthalocyanines (Mpc, M=Co, Ni) on Au(001): Ultraviolet Photoemission Spectroscopy and Low Energy Electron Diffraction Study  

Science Conference Proceedings (OSTI)

Thin films of metallophthalocyanine (MPc,M=Co,Ni) evaporated onto a '5x20' reconstructed Au(001) substrate at room temperature have been investigated by employing low energy electron diffraction (LEED) and ultraviolet photoelectron spectroscopy (UPS). The LEED images from NiPc thin films show that the overlayers are highly ordered with a square unit cell of 12.8x12.8 {angstrom}{sup 2} aligned along the {l_angle}110{r_angle} and {l_angle}1{bar 1}0{r_angle} axes of the Au(001) substrate. For CoPc, the LEED pattern reveals the superposition of multiple rotationally equivalent domains of a 12.9x12.9 {angstrom}{sup 2} square lattice which are rotated by 16{sup o} with respect to each other. The contrast between NiPc and CoPc on Au(001) is further demonstrated in the interfacial electronic structure. UPS studies of the interfacial layers of NiPc deposited on the hexagonally reconstructed gold substrate indicate that NiPc physisorbs on the gold surface as evidenced by a uniform molecular orbital (MO) shift. The CoPc MO's, on the other hand, indicates a charge transfer at the interface, evidenced by the 13a{sub 1g} MO interacting with the Au surface.

Ellis,T.; Park, K.; Ulrich, M.; Hulbert, S.; Rowe, J.

2006-01-01T23:59:59.000Z

412

Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni  

E-Print Network (OSTI)

A study on middle distillate hydrotreatment zeolite catalysts containing Pt/Pd and/or Ni was performed. The effect of the addition of the corresponding CoMo, CoMoPd, CoMoPtPd and CoMoNi in PdNiPt-zeolite, Pt-zeolite, Ni-zeolite, and PdPt-zeolite was studied. The catalysts were characterized physically and chemically by methods and techniques such as Brunauer-Emmett-Teller (BET), Barret-Joyner-Hallenda (BJH), and neutron activation analysis. The structures of the Ni and Pt containing zeolite were studied by X-ray Photoelectron Spectroscopy (XPS). An experimental apparatus was constructed to investigate the activity of the experimental catalysts. The catalysts activity measured in terms of conversion of dibenzothiophene (DBT), substituted dibenzothiophenes (sDBT) and phenanthrene as well as molar-averaged conversion was evaluated in a continuous flow Robinson Mahoney reactor with stationary basket in the hydrodesulfurization and hydrogenation of heavy gas oil which contains sulphur refractory compounds such as 4- methyldibenzotiophene (4-MDBT) and 4,6- dimethyldibenzothiophene (4,6-DMDBT). DBT, 4-MDBT, 3-MDBT, 1-EDBT, 3-EDBT, 4,6-DMDBT, 3,6-DMDBT, 2,8- DMDBT and 4-methylnaphtho[2,1-b]thiophene were selected to calculate the molaraveraged conversion. The conversions of the sulfur containing compounds and phenanthrene were determined as a function of the operating variables: space time (W/Fo DBT), temperature, H2/HC mol ratio and pressure. The Conversions of DBT and 4,6-DMDBT into their reaction products such as Biphenyl (BPH), Cyclohexylbenzene (CHB), Bicyclohexyl (BCH) and 3,4-Dimethylbiyphenyl (3,4-DMBPH) were determined only as a function of space time in the interval of 4000-6000 kgcath/kmol. The results of this work showed that Pt-HY and PdPt-HY are good noble metals catalysts for the hydrodesulfurization of heavy gas oil. Moreover, this study showed that CoMoPd/Pt-HY and CoMoNi/PdPt-HY catalysts are good candidates for deep HDS and hydrogenation of heavy gas oil. It was found that the conversions of sulfur compounds were higher than the conversions provided by the conventional CoMo/Al2O3 catalyst. Also higher hydrogenation of phenanthrene was observed. Deactivation of the catalysts was not observed during the operation. Finally, the study not only contributed to define the technical bases for the preparation of the noble metal catalysts for hydrodesulfurization of heavy gas oil at pilot scale, but also provided technical information for developing the kinetic modeling of the hydrodesulfurization of heavy gas oil with the noble metal catalysts.

Marin-Rosas, Celia

2006-12-01T23:59:59.000Z

413

DOE Challenge Home Verification  

NLE Websites -- All DOE Office Websites (Extended Search)

rgy use Estimated annual energy savings Electric: 10825 kWh Natural Gas: 773 Therms Electr ic: 4081 kWh Natural gas: 1171 Ther ms Ene rgy c o st rate s Estimated annual...

414

Model for projectile fragmentation: case study for Ni on Ta, Be and Xe on Al  

E-Print Network (OSTI)

For projectile fragmentation we work out details of a model whose origin can be traced back to the Bevalac era. The model positions itself between the phenomenological EPAX parametrization and microscopic transport models like "Heavy Ion Phase Space Exploration Model" (HIPSE) and antisymmetrised molecular dynamics(AMD). We apply the model to some recent data of projectile fragmentation of Ni on Ta and Be at beam energy 140 MeV/nucleon and some older data of Xe on Al at beam energy 790 MeV/nucleon. Reasonable values of cross-sections for various composites populated in the reactions are obtained.

S. Mallik; G. Chaudhuri; S. Das Gupta

2010-12-30T23:59:59.000Z

415

High-temperature oxidation of an alumina-coated Ni-base alloy  

Science Conference Proceedings (OSTI)

Alumina coatings were applied to Ni-20Cr (wt%) using combustion chemical vapor deposition (combustion CVD). Combustion CVD is an open air deposition technique performed in a flame. The oxidation kinetics of coated and uncoated specimens were measured by isothermal oxidation tests carried out in pure flowing air at temperatures of 800, 900, 1,000 and 1,100 C. The alumina coatings reduced the oxidation kinetics at all temperatures. The morphologies and compositions of the alumina coatings were characterized by transmission and scanning electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy.

Hendrick, M.R.; Hampikian, J.M.; Carter, W.B.

1996-06-01T23:59:59.000Z

416

Origins of the Doping Asymmetry in Oxides: Hole Doping in NiO versus Electron Doping in ZnO  

Science Conference Proceedings (OSTI)

The doping response of the prototypical transparent oxides NiO (p-type), ZnO (n-type), and MgO (insulating) is caused by spontaneous formation of compensating centers, leading to Fermi-level pinning at critical Fermi energies. We study the doping principles in these oxides by first-principles calculations of carrier-producing or -compensating defects and of the natural band offsets, and identify the dopability trends with the ionization potentials and electron affinities of the oxides. We find that the room-temperature free-hole density of cation-deficient NiO is limited by a too large ionization energy of the Ni vacancy, but it can be strongly increased by extrinsic dopants with shallower acceptor levels.

Lany, S.; Osorio-Guillen, J.; Zunger, A.

2007-01-01T23:59:59.000Z

417

First Principles Calculations of Electrochemically Controlled Hydrogen Mobility and Uptake at the Ni(111)H2O Interface  

DOE Green Energy (OSTI)

The binding of hydrogen on Ni(111) in the presence of an water is considered using both a bilayer and a saturated model of the solvent environment. The presence of a water bilayer did not change the binding energies or geometry of hydrogen on the Ni(111) compared to adsorption in ultra-high vacuum. Using the saturated model (four bilayers over the surface) we also monitored the change in hydrogen binding as a function of electrochemical potential. Binding energies for hydrogen at the hcp and octahedral sites shifted endothermically as the potential was made more anodic, indicating that reductive partial charge transfer occurs. Binding at the tetrahedral site was found to be partially oxidizing. Calculation of vibrational modes allowed the extrapolation of ab initio results to ambient and elevated temperatures. Surface Pourbaix diagrams were constructed illustrating the stability of various phases on the Ni(111) surface as a function of pH and potential.

C Taylor; R Kelly; M Neurock

2005-11-14T23:59:59.000Z

418

Reexamining the Beta Decay of 53,54Ni, 52,53Co, 51Fe, and 50Mn  

Science Conference Proceedings (OSTI)

he decay of 53,54Ni, 52,53Co, 51Fe, and 50Mn was investigated via the fragmentation of a 58Ni primary beam with an energy of 68.6 MeV/u. The proton- coincidences of 53Ni -delayed proton emission were observed. Based on the analysis of the proton- coincidence events, it was inferred that the previous assignment of the excitation energy for the isobaric analog state in 53Co may be problematic. The half-lives of these nuclei were obtained, in which the uncertainty of 52Co half-life was reduced by a factor of 3. The half-lives were evaluated and used as inputs of nucleosynthesis calculations of the rapid proton-capture process in an x-ray burst.

Su, J. [Neutron Scattering Laboratory, China Institute of Atomic Energy, Beijing, China; Liu, W. P. [China Institute of Atomic Energy Collaboration; Collaboration, [China Institute of Atomic Energy Collaboration; Wang, J. S. [Inst. Modern Phys., Chinese Academy of Sciences-Lanzhou; Collaboration, [Inst. Modern Phys., Chinese Academy of Sciences-Lanzhou; Li, X. Q. [Peking University-Beijing; He, C. [Peking University-Beijing; Smith, Michael Scott [ORNL

2013-01-01T23:59:59.000Z

419

Properties of ZrZrCZrC/DLC gradient films on TiNi alloy by the PIIID technique combined with PECVD  

E-Print Network (OSTI)

better corrosion resistance property and higher depression ability for the Ni ion releasing from the Ni the alloy in the body fluid environment because of bio-corrosion or erosion. Thus, it is necessary to modify. However, the high hardness, intrinsic stresses, and poor adhesion strength to the substrate limit its

Zheng, Yufeng

420

Electrodeposition of Ni5Sb2 nanowires array and its application as a high-performance anode material for lithium ion batteries  

Science Conference Proceedings (OSTI)

Single crystal Ni"5Sb"2 nanowires array is synthesized by direct-current electrodeposition technique. The initial specific discharge and charge capacity of the as-produced Ni"5Sb"2 nanowires array electrode as an anode material for lithium-ion batteries ... Keywords: Anode, Array structure, Charge/discharge capacity, Lithium-ion batteries, Nanowires

You-Wen Yang; Tian-Ying Li; Fei Liu; Wen-Bin Zhu; Xue-Liang Li; Yu-Cheng Wu; Ming-Guang Kong

2013-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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421

Hydrogen-Rich Gas Production from Steam Gasification of Palm Oil Wastes Using the Supported Nano-NiO/?-Al2O3 Catalyst  

Science Conference Proceedings (OSTI)

The catalytic steam gasification of palm oil wastes for hydrogen-rich gas production was experimentally investigated in a combined fixed bed reactor using the newly developed nano-NiO/?-Al2O3 catalyst. The results indicated that the nano-NiO/?-Al2O3 ... Keywords: Biomass gasification, palm oil waste, catalyst, hydrogen production

Jianfen Li; Yanfang Yin; Jianjun Liu; Rong Yan

2009-10-01T23:59:59.000Z

422

The influence of helium on mechanical properties of model austenitic alloys, determined using sup 59 Ni isotopic tailoring and fast reactor irradiation  

Science Conference Proceedings (OSTI)

The objective of this effort is to study the separate and synergistic effects of helium and other important variables on the evolution of microstructure and macroscopic properties during irradiation of structural metals. The alloys employed in this study were nominally Fe-15Cr-25Ni, Fe-15Cr-25Ni-0.04P and Fe-15Cr-45Ni (wt %) in both the cold worked and annealed conditions. Tensile testing and microscopy continue on specimens removed from the first, second and third discharges of the {sup 59}Ni isotopic doping experiment. The results to date indicate that helium/dpa ratios typical of fusion reactors (4 to 19 appm/dpa) do not lead to significant changes in the yield strength of model Fe-Cr-Ni alloys. Measurements of helium generated in undoped specimens from the second and third discharges show that the helium/dpa ratio increases during irradiation in FFTF due to the production of {sup 59}Ni. In specimens doped with {sup 59}Ni prior to irradiation, the helium/dpa ratio can increase, decrease or remain the same during the second irradiation interval. This behavior occurs because the cross sections for the production and burnout of {sup 59}Ni are very sensitive to core location and the nature of neighboring components. 14 refs., 5 figs., 3 tabs.

Hamilton, M.L.; Garner, F.A. (Pacific Northwest Lab., Richland, WA (USA)); Oliver, B.M. (Rockwell International Corp., Canoga Park, CA (USA))

1990-11-01T23:59:59.000Z

423

Near-Monodisperse Ni-Cu Bimetallic Nanocrystals of Variable Composition: Controlled Synthesis and Catalytic Activity for H2 Generation  

SciTech Connect

Near-monodisperse Ni{sub 1-x}Cu{sub x} (x = 0.2-0.8) bimetallic nanocrystals were synthesized by a one-pot thermolysis approach in oleylamine/1-octadecene, using metal acetylacetonates as precursors. The nanocrystals form large-area 2D superlattices, and display a catalytic synergistic effect in the hydrolysis of NaBH{sub 4} to generate H{sub 2} at x = 0.5 in a strongly basic medium. The Ni{sub 0.5}Cu{sub 0.5} nanocrystals show the lowest activation energy, and also exhibit the highest H{sub 2} generation rate at 298 K.

Zhang, Yawen; Huang, Wenyu; Habas, Susan E.; Kuhn, John N.; Grass, Michael E.; Yamada, Yusuke; Yang, Peidong; Somorjai, Gabor A.

2008-07-22T23:59:59.000Z

424

Observation of Localized Corrosion of Ni-Based Alloys Using Coupled Orientation Imaging Microscopy and Atomic Force Microscopy  

DOE Green Energy (OSTI)

We present a method for assessing the relative vulnerabilities of distinct classes of grain boundaries to localized corrosion. Orientation imaging microscopy provides a spatial map which identifies and classifies grain boundaries at a metal surface. Once the microstructure of a region of a sample surface has been characterized, a sample can be exposed to repeated cycles of exposure to a corrosive environment alternating with topographic measurement by an atomic force microscope in the same region in which the microstructure had been mapped. When this procedure is applied to Ni and Ni-based alloys, we observe enhanced attack at random grain boundaries relative to special boundaries and twins in a variety of environments.

Bedrossian, P.J.

1999-11-24T23:59:59.000Z

425

Fusion Probability in the Reactions {sup 58}Fe+{sup 244}Pu and {sup 64}Ni+{sup 238}U  

Science Conference Proceedings (OSTI)

Mass-energy distributions, as well as capture cross-section of fission-like fragments for the reactions {sup 64}Ni+{sup 238}U and {sup 58}Fe+{sup 244}Pu leading to the formation of superheavy compound system with Z = 120 and N 182 at energies near the Coulomb barrier have been measured. Fusion-fission cross sections were estimated from the analysis of mass and total kinetic energy distributions. It was found that the fusion probability is about one order of magnitude higher for the reaction {sup 58}Fe+{sup 244}Pu than that for the reaction with {sup 64}Ni-ions.

Knyazheva, G. N.; Bogachev, A. A.; Itkis, I. M.; Itkis, M. G.; Kozulin, E. M. [Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, RU-141980 Dubna, Moscow region (Russian Federation)

2010-04-30T23:59:59.000Z

426

Castability of Traditionally Wrought Ni-Based Superalloys for USC Steam Turbines  

Science Conference Proceedings (OSTI)

The high temperature components within conventional coal fired power plants are manufactured from ferritic/martensitic steels. In order to reduce greenhouse gas emissions the efficiency of pulverized coal steam power plants must be increased. The proposed steam temperature in the Advanced Ultra Supercritical (A-USC) power plant is high enough (760C) that ferritic/martensitic steels will not work due to temperature limitations of this class of materials; thus Ni-based superalloys are being considered. The full size castings are quite substantial: ~4in thick, several feet in diameter and weigh 5-10,000lb each half. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled in order to produce relevant microstructures. A multi-step homogenization heat treatment was developed in order to better deploy the alloy constituents. The castability of two traditionally wrought Ni-based superalloys to which minor alloy adjustments have been made in order to improve foundry performance is further explored.

Jablonski, P D; Cowen, C J; Hawk, J A; Evens, N; Maziasz, P

2011-02-27T23:59:59.000Z

427

Temperature Dependent Electrical Transport Properties of Ni-Cr and Co-Cr Binary Alloys  

Science Conference Proceedings (OSTI)

The temperature dependent electrical transport properties viz. electrical resistivity and thermal conductivity of Ni{sub 10}Cr{sub 90} and Co{sub 20}Cr{sub 80} alloys are computed at various temperatures. The electrical resistivity has been calculated according to Faber-Ziman model combined with Ashcroft-Langreth partial structure factors. In the present work, to include the ion-electron interaction, we have used a well tested local model potential. For exchange-correlation effects, five different forms of local field correction functions due to Hartree (H), Taylor (T), Ichimaru and Utsumi (IU), Farid et al (F) and Sarkar et al (S) are used. The present results due to S function are in good agreement with the experimental data as compared to results obtained using other four functions. The S functions satisfy compressibility sum rule in long wave length limit more accurately as compared to T, IU and F functions, which may be responsible for better agreement of results, obtained using S function. Also, present result confirms the validity of present approach in determining the transport properties of alloys like Ni-Cr and Co-Cr.

Thakore, B. Y.; Khambholja, S. G.; Bhatt, N. K.; Jani, A. R. [Department of Physics, S P University, Vallabh Vidhyanagar, 388 120, Gujarat (India); Suthar, P. H. [Department of Physics, C U Shah Science College, Ahmedabad, 380 014, Gujarat (India); Gajjar, P. N. [Department of Physics, University Schools of Sciences, Gujarat University, Ahmedabad, 380 009, Gujarat (India)

2011-12-12T23:59:59.000Z

428

Shell Structure from 100Sn to 78Ni: Implications for Nuclear Astrophysics  

Science Conference Proceedings (OSTI)

The single-particle structure and shell gap of {sup 100}Sn is inferred from prompt in-beam and delayed {gamma}-ray spectroscopy of seniority and spin-gap isomers. Recent results in {sup 94, 95}Ag and {sup 98}Cd stress the importance of large-scale shell model calculations employing realistic interactions for the isomerism, np-nh excitations and E2 polarization of the {sup 100}Sn core. The strong monopole interaction of the {Delta}l = 0 spin-flip partners {pi}g{sub 9/2-} {nu}g{sub 7/2} in N = 51 isotones below {sup 100}Sn is echoed in the {Delta}l = 1 pf5/2- ?g9/2 pair of nucleons, which is decisive for the persistence of the N = 50 shell gap in {sup 78}Ni. This is corroborated by recent experimental data on {sup 70, 76}Ni, {sup 78}Zn. The importance of monopole driven shell evolution for the appearance of new shell closures in neutron-rich nuclei and implications for r-process abundances near the N = 82 shell is discussed.

Grawe, Hubert H [ORNL; Blazhev, A. [Gesellschaft fur Schwerionenforschung (GSI), Germany; Gorska, M. [Gesellschaft fur Schwerionenforschung (GSI), Germany; Mukha, I. [Gesellschaft fur Schwerionenforschung (GSI), Germany; Plettner, C. [Gesellschaft fur Schwerionenforschung (GSI), Germany; Roeckl, E. [Gesellschaft fur Schwerionenforschung (GSI), Germany; Nowacki, F. [IReS, Strasbourg, Cedex, France; Grzywacz, Robert Kazimierz [ORNL; Sawicka, M. [University of Warsaw

2005-09-01T23:59:59.000Z

429

Room temperature ferromagnetism in Mn, Ni and Co ions doped Cu{sub 2}O nanorods  

SciTech Connect

Here we report the synthesis and characterization of Cu{sub 2}O nanorods doped with Mn, Ni and Co transition metal ions and the study of their magnetic properties. Synthesis of the nanorods was carried out by the modified polyol method. Powder X-ray diffraction patterns clearly showed them to be polycrystalline single phase material. They exhibited ferromagnetic behavior at room temperature, however no such behavior was observed for the reference undoped sample, which indicated that unintentionally introduced magnetic impurities were not responsible for the observed phenomenon. Ferromagnetic behavior was found to be dependent on the dopant concentration and increased consistently with its increment in the material. The total magnetic moments contribution was calculated for the dopant concentration and was found to be insignificant to account for the observed ferromagnetism, therefore it was suggested that ferromagnetism could have conjured up from the induced magnetic moment in the defects created as cation vacancies in the material. The presence of the defects was supported by the room temperature photoluminescence study which showed that intensity of the peaks was dependent on the dopant concentration and increased consistently with it. There was strong correlation between the magnitude of the photoluminescence peak and the observed ferromagnetic property in the doped samples. -- Graphical Abstract: Room temperature ferromagnetism was observed in the Cu{sub 2}O nanorods doped with Mn, Ni and Co ions. The origin seems to be the defects of cation vacancies created by the dopant ions. Display Omitted

Ahmed, Asar [Department of Chemistry, SL-214, Southern Lab, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh (India); Gajbhiye, Namdeo S., E-mail: nsg@iitk.ac.i [Department of Chemistry, SL-214, Southern Lab, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh (India)

2010-12-15T23:59:59.000Z

430

Exact Enumeration of the Phase Space of an Ising Model of Ni2MnGa  

Science Conference Proceedings (OSTI)

Exact evaluations of partition functions are generally prohibitively expensive due to exponential growth of phase space with the number of degrees of freedom. For an Ising model with sites the number of possible states is requiring the use of better scaling methods such as importance sampling Monte-Carlo calculations for all but the smallest systems. Yet the ability to obtain exact solutions for as large as possible systems can provide important benchmark results and opportunities for unobscured insight into the underlying physicsofthesystem.HerewepresentanIsingmodelforthemagneticsublatticesoftheimportantmagneto-caloricmaterialNi MnGa and use an exact enumeration algorithm to calculate the number of states for each energy and sublattice magne- tizations and . This allows the efficient calculation of the partition function and derived thermodynamic quantities such as specific heat and susceptibility. Utilizing the jaguarpf system at Oak Ridge we are able to calculate for systems of up to48sites,whichprovidesimportantinsightintothemechanismforthelargemagnet-caloriceffectinNi MnGaaswellasanimportant benchmark for Monte-Carlo (esp. Wang-Landau method).

Eisenbach, Markus [ORNL; Brown, Greg [ORNL; Rusanu, Aurelian [ORNL; Odbadrakh, Khorgolkhuu [ORNL; Nicholson, Don M [ORNL; McCarthy, Carrie V. [University of Georgia, Athens, GA

2013-01-01T23:59:59.000Z

431

Layered manganese oxide intergrowth electrodes for rechargeable lithium batteries: Part 1-substitution with Co or Ni  

DOE Green Energy (OSTI)

Lithium manganese oxides substituted with nickel or cobalt were characterized electrochemically in lithium cell configurations. The compounds studied were either single-phase layered structures with either primarily O2 or O3 stacking arrangements, or O2/O3 intergrowths, prepared from P2, P3 and P2/P3 sodium-containing precursors, respectively. The stacking arrangements are extremely sensitive to the Na/T. M. (T. M. = transition metal) ratios and the level of substitution. Phase diagrams showing the stability regions of the various arrangements for the Na-Ni-Mn-O system are presented. A possible correlation between vacancies and electrochemical performance is suggested. For high levels of substitution with Ni, fewer defects are possible for materials containing more O3 component and higher discharge capacities can be achieved, but spinel conversion upon cycling also occurs more rapidly as the O3 content increases. Intergrowths show intermediate behavior and represent a potential route towards designing stable, high capacity electrodes.

Dolle, Mickael; Patoux, Sebastien; Doeff, Marca M.

2004-09-08T23:59:59.000Z

432

NEUTRON DIFFRACTION STUDY OF A NON-STOICHIOMETRIC Ni-Mn-Ga MSM ALLOY  

SciTech Connect

The structure and chemical order of a Heusler alloy of non-stoichiometric composition Ni-Mn-Ga were studied using constant-wavelength (1.538 ) neutron diffraction at 363K and the diffraction pattern was refined using the FullProf software. At this temperature the structure is austenite (cubic) with Fm-3m space group and lattice constant of a = 5.83913(4) [ ]. The chemical order is of critical importance in these alloys, as Mn becomes antiferromagnetic when the atoms are closer than the radius of the 3d shell. In the studied alloy the refinement of the site occupancy showed that the 4b (Ga site) contained as much as 22% Mn; that significantly alters the distances between the Mn atoms in the crystal and, as a result, also the exchange energy between some of the Mn atoms. Based on the refinement, the composition was determined to be Ni1.91Mn1.29Ga0.8

Ari-Gur, Pnina [Western Michigan University; Garlea, Vasile O [ORNL

2013-01-01T23:59:59.000Z

433

JOURNAL DE PHYSIQUE Colloque C I, supplkment au no 2-3, Tome 32, Fkvrier-Mars 1971, page C 1 -882 MAGNETIC NEUTRON SCATTERING FROM K,NiF4  

E-Print Network (OSTI)

la temperature de tran- sition dans I'antiferromagnetique a deux dimensions K2NiF4. L in the two-dimensional antiferromagnet K2NiF4. Inelastic studies on a triple-axis spectrometer have indicated is structurally composed of NiF, layers separated by two K F layers [I]. The relative isolation of the NiF, layers

Paris-Sud XI, Université de

434

An analysis of the x-ray linear dichroism spectrum for NiO thin films grown on vicinal Ag(001)  

SciTech Connect

Antiferromagnetic (AFM) NiO thin films are grown epitaxially on vicinal Ag(118) substrate and investigated by x-ray linear dichroism (XLD). We find that the NiO AFM spin exhibits an in-plane spin reorientation transition from parallel to perpendicular to the step edges with increasing the NiO film thickness. In addition to the conventional L{sub 2} adsorption edge, x-ray linear dichroism (XLD) effect at the Ni L{sub 3} adsorption edge is also measured and analyzed. The result identifies a small energy shift of the L{sub 3} peak. Temperature-dependent measurement confirms that the observed XLD effect in this system at the normal incidence of the x-rays originates entirely from the NiO magnetic ordering.

Wu, Y.Z.; Zhao, Y.; Arenholz, E.; Young, A.T.; Sinkovic, B.; Qiu, Z.Q.

2008-05-10T23:59:59.000Z

435

LABORATORY VI ELECTRICITY FROM MAGNETISM  

E-Print Network (OSTI)

the magnetic field and its effect on moving charges. You also saw how electric currents could create magnetic the magnetic flux through a coil of wire to produce an electric current. You will investigate the current are necessary for a magnetic field to produce an electric current. · Determine the direction of a current

Minnesota, University of

436

CHAPITRE VI NOMS DE LIEUX  

E-Print Network (OSTI)

personnes) 846. Maison de Lamarre (13 personnes) 847. Maison de Drouilhet Puisné (6 personnes) 848. Maison. Maison de Drouilhet Ainé (4 personnes) 880. Maison de Duhagon (9 personnes) 881. Maison de Caulongue (9

Paris-Sud XI, Université de

437

Dynamic Behavior of Materials VI  

Science Conference Proceedings (OSTI)

Capturing Microstructural Features Related to Dynamic Damage Nucleation ... Structural Alumina during Low Velocity Impact Used in Protective Systems.

438

PR_VI_50mwind  

NLE Websites -- All DOE Office Websites (Extended Search)

using their MesoMap system and historical weather data under contract to Wind Powering AmericaNREL. This map has been validated with available surface data by NREL and...

439

Undirectional Diagonal Order and Three-Dimensional Stacking of Charge Stripes in Orthorhombic Pr1.67Sr0.33NiO4 and Nd1.67Sr0.33NiO4  

SciTech Connect

The interplay between crystal symmetry and charge stripe order in Pr{sub 1.67}Sr{sub 0.33}NiO{sub 4} and Nd{sub 1.67}Sr{sub 0.33}NiO{sub 4} has been studied by means of single crystal x-ray diffraction. In contrast to tetragonal La{sub 1.67}Sr{sub 0.33}NiO{sub 4}, these crystals are orthorhombic. The corresponding distortion of the NiO{sub 2} planes is found to dictate the direction of the charge stripes, similar to the case of diagonal spin stripes in the insulating phase of La{sub 2-x}Sr{sub x}CuO{sub 4}. In particular, diagonal stripes seem to always run along the short a axis, which is the direction of the octahedral tilt axis. In contrast, no influence of the crystal symmetry on the charge stripe ordering temperature itself was observed, with T{sub CO}{approx}240 K for La, Pr, and Nd. The coupling between lattice and stripe degrees of freedom allows one to produce macroscopic samples with unidirectional stripe order. In samples with stoichiometric oxygen content and a hole concentration of exactly 1/3, charge stripes exhibit a staggered stacking order with a period of three NiO{sub 2} layers, previously only observed with electron microscopy in domains of mesoscopic dimensions. Remarkably, this stacking order starts to melt about 40 K below T{sub CO}. The melting process can be described by mixing the ground state, which has a three-layer stacking period, with an increasing volume fraction with a two-layer stacking period.

Hucker,M.; Zimmermann, M.; Klingelar, R.; Kiele, S.; Geck, J.; Bakehe, S.; Zhang, J.; Hill, J.; Revcolevschi, A.; et al.

2006-01-01T23:59:59.000Z

440

Temperature dependence of carrier spin polarization determined from current-induced domain wall motion in a Co/Ni nanowire  

SciTech Connect

We have investigated the temperature dependence of the current-induced magnetic domain wall (DW) motion in a perpendicularly magnetized Co/Ni nanowire at various temperatures and with various applied currents. The carrier spin polarization was estimated from the measured domain wall velocity. We found that it decreased more with increasing temperature from 100 K to 530 K than the saturation magnetization did.

Ueda, K.; Koyama, T.; Hiramatsu, R.; Kobayashi, K.; Ono, T. [Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Chiba, D. [Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); PRESTO, Japan Science and Technology Agency, 4-1-8 Honcho Kawaguchi, Saitama 322-0012 (Japan); Fukami, S. [Green Innovation Research Laboratories, NEC Corporation, 34 Miyukigaoka, Tsukuba, Ibaraki 305-8501 (Japan); Center for Spintronics Integrated Systems, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Tanigawa, H.; Suzuki, T. [RENESAS Electronics Corporation, Sagamihara, Kanagawa 252-5298 (Japan); Ohshima, N. [NEC Energy Device Ltd., 1120 Shimokuzawa, Chuo-ku, Sagamihara, Kanagawa 252-5298 (Japan); Ishiwata, N. [Green Innovation Research Laboratories, NEC Corporation, 34 Miyukigaoka, Tsukuba, Ibaraki 305-8501 (Japan); Nakatani, Y. [University of Electro-communications, Chofu, Tokyo 182-8585 (Japan)

2012-05-14T23:59:59.000Z

Note: This page contains sample records for the topic "vi rgi ni" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Nanopowder synthesis of the SOFC cathode material Nd2NiO4+ by Ultrasonic Spray Pyrolysis  

E-Print Network (OSTI)

1 Nanopowder synthesis of the SOFC cathode material Nd2NiO4+ by Ultrasonic Spray Pyrolysis David to synthesize this material which is of high interest for intermediate temperature solid oxide fuel cells (IT-SOFC-22 (2010) 1015-1023" DOI : 10.1016/j.ssi.2010.05.041 #12;2 I. INTRODUCTION Solid oxide fuel cells (SOFC

Paris-Sud XI, Université de

442

The geometry variation of as-grown carbon coils with Ni layer thickness and hydrogen plasma pretreatment  

Science Conference Proceedings (OSTI)

Carbon coils could be synthesized using C2H2/H2 as source gases and SF6 as an incorporated additive gas under thermal chemical vapor deposition system. Ni layer on SiO2 substrate was used as a catalyst ...

Young-Chul Jeon, Semi Park, Sung-Hoon Kim

2013-01-01T23:59:59.000Z

443

Real Time in situ hard X-ray texture evolution during the annealing of rolled CuNi tapes  

E-Print Network (OSTI)

1 Real Time in situ hard X-ray texture evolution during the annealing of rolled CuNi tapes Antoine monochromators. It uses a white hard X ray beam and works in transmission geometry. The 2D detector allows, used as substrate for high temperature superconductor, is presented. hard X-rays; diffraction; in

Paris-Sud XI, Université de

444

Aging effects in palladium and LaNi{sub 4.25}Al{sub 0.75} tritides  

DOE Green Energy (OSTI)

Palladium and LaNi{sub 5-x}Al{sub x} (x=0.30, 0.75, 0.85), which form reversible hydrides, are used for tritium processing and storage in the Savannah River Site (SRS) tritium facilities. As part of a program to develop technology based on the use of reversible metal hydrides for tritium processing and storage, the effects of aging on the thermodynamic behavior of palladium and LaNi{sub 4.25}Al{sub 0. 75} tritides are under investigation. During aging, the {sup 3}He tritium decay product remains in the tritide lattice and changes the thermodynamics of the tritium-metal tritide system. Aging effects in 755-day-aged palladium and 1423-day-aged LaNi{sub 4.25}Al{sub 0.75} tritides will be reported. Changes in the thermodynamics were determined by measuring tritium desorption isotherms on aging samples. In palladium, aging decreases the desorption isotherm plateau pressure and changes the {alpha}-phase portion of the isotherm. Aging-induced changes in desorption isotherms are more drastic in LaNi{sub 4.25}Al{sub 0.75}. Among the changes noted are: (1) decreased isotherm plateau pressure, (2) increased isotherm plateau slope, and (3) appearance of deep-trapped tritium, removable only by exchange with deuterium.

Nobile, A.; Wermer, J.R.; Walters, R.T.

1991-12-31T23:59:59.000Z

445

Simulation of shock-induced melting of Ni using molecular dynamics coupled to a two-temperature model  

E-Print Network (OSTI)

Simulation of shock-induced melting of Ni using molecular dynamics coupled to a two-temperature and electron-phonon coupling, Pmelt and Tmelt change. For a given pressure, the temperature behind the shock conduction and electron-phonon coupling. The decrease in the temperature behind the shock front is enhanced

Zhigilei, Leonid V.

446

Development of Ni1-xCoxO as the cathode/interconnect contact for solid oxide fuel cells  

Science Conference Proceedings (OSTI)

A new type of material, Ni1-xCoxO, was developed for solid oxide fuel cell (SOFC) cathode/interconnect contact applications. The phase structure, coefficient of thermal expansion, sintering behavior, electrical property, and mechanical bonding strength of these materials were evaluated against the requirements of the SOFC cathode/interconnect contact. A dense cathode/interconnect contact layer was developed through reaction sintering from Ni and Co metal powders. An area specific resistance (ASR) as low as 5.5 mohm.cm2 was observed after 1000 h exposure in air at 800 C for the LSM/Ni0.33Co0.67O/AISI441 assembly. Average mechanical strengths of 6.8 and 5.0 MPa were obtained for the cathode/contact/cathode and interconnect/contact/interconnect structures, respectively. The significantly low ASR was probably due to the dense structure and therefore improved electrical conductivity of the Ni0.33Co0.67O contact and the good bonding of the interfaces between the contact and the cathode, and between the contact and the interconnect.

Lu, Zigui; Xia, Guanguang; Templeton, Joshua D.; Li, Xiaohong S.; Nie, Zimin; Yang, Zhenguo; Stevenson, Jeffry W.

2011-06-01T23:59:59.000Z

447

Quantization of FIR Filters under a Total Integer Cost Ashley J. Llorens, Christoforos N. Hadjicostis and Hen Chi Ni  

E-Print Network (OSTI)

representation for arbitrary quantization sets. We then develop a greedy algorithm which has even lower algorithms in this setting. I. INTRODUCTION The increasing usage of FIR filters and the inherent quantization. Hadjicostis and H. C. Ni are with the Department of Electrical and Computer Engineering at the University

Hadjicostis, Christoforos

448

The adsorption of molecular oxygen on Au/Ni(111) alloys and its oxidation of CO at 85 K  

E-Print Network (OSTI)

Molecular oxygen is observed to adsorb on 0.2 - 0.6 ML Au/Ni(111) surface alloys. Molecular oxygen adsorbates are characterized by their 0-0 stretching frequencies of 740 cm', 851 cm' and 962 cm', as measured by high ...

Fischer, Jonathan David

2010-01-01T23:59:59.000Z

449

SF6432-NI (02-01-12) Fixed Price Former Soviet Union  

NLE Websites -- All DOE Office Websites (Extended Search)

2/01/12 2/01/12 Page 1 of 15 Printed copies of this document are uncontrolled. Retrieve latest version electronically. SF 6432-NI (02/01/12) SECTION II STANDARD TERMS AND CONDITIONS FOR FIXED PRICE CONTRACTS WITH THE NEWLY INDEPENDENT STATES OF THE FORMER SOVIET UNION INDEX OF CLAUSES. THE FOLLOWING CLAUSES APPLY TO REQUESTS FOR QUOTATION AND CONTRACTS AS INDICATED UNLESS SPECIFICALLY DELETED, OR EXCEPT TO THE EXTENT THEY ARE SPECIFICALLY SUPPLEMENTED OR AMENDED IN WRITING IN THE SIGNATURE PAGE OR SECTION I. (CTRL+CLICK ON A LINK BELOW TO ADVANCE DIRECTLY TO THAT SECTION) ACCEPTANCE OF TERMS AND CONDITIONS APPLICABLE LAW ASSIGNMENT BANKRUPTCY (07/11) BREACH OF CONTRACT COMPLIANCE WITH THE LAWS OF THE COUNTRY AND THE UNITED STATES DEFINITIONS

450

INSTALLATION MAG~NiX.ILRI DIVI8ION, CAN.fAN,CONN.  

Office of Legacy Management (LM)

INSTALLATION INSTALLATION MAG~NiX.ILRI DIVI8ION, CAN.fAN,CONN. .PERI,jD Aiq~+ 1, i950 TO: August 31, 195 .:\,.:. ,,., WORK SHEET FOR: I b WSIGNOR I. v DowChemical Go. Velasco, Texas ., Azlterprise Meetala cc Brooklyn, New York Meili $Worthin&m Hatboro, ?'a. LOT NO. '... I [ATERIAL SYnB,fJL KEASURED' NET WT. 100,007~ ( 4;020 I ! 19 ~, ANALYBIS % METAL/100 r, Noi. 23) METAL CONTENT INSTRUCTIONS: This sheet% will be Used.ln.preDarlng Haterlal Balance. 'The totals from the various ltams listed above ~111 be Inserted on the Material Balance Summary Sheet. Shipments ~111 he llated on this Work'Sheet separately With the-ConsIgnor and Consignee of each Shipment noted; Copies Of thls sheet ~111 accompany the naterlal Balance Summary Sheet at the end of the'month.

451

REVERSIBLE AND IRREVERSIBLE PASSIVATION OF A LA-NI-AL ALLOY  

DOE Green Energy (OSTI)

This paper seeks to explore some of the effects of passivating a LaNi{sub 4.25}Al{sub 0.75} sample by air oxidation under controlled conditions. Passivation of this metal hydride alloy seems to have two distinct regimes. The first occurs with air oxidation at 80 C and 20 C. It is characterized by complete reversibility upon hydrogen readsorption, although said readsorption is hindered substantially at room temperature, requiring the material to be heated to produce the reactivation. The second regime is illustrated by 130 C air oxidation and is characterized by irreversible loss of hydrogen absorption capacity. This passivation does not hinder hydrogen readsorption into the remaining hydride material.

Shanahan, K.; Klein, J.

2009-06-25T23:59:59.000Z

452

Xe films on a decagonal Al-Ni-Co quasicrystal surface  

E-Print Network (OSTI)

The grand canonical Monte Carlo method is employed to study the adsorption of Xe on a quasicrystalline Al-Ni-Co surface. The calculation uses a semiempirical gas-surface interaction, based on conventional combining rules and the usual Lennard-Jones Xe-Xe interaction. The resulting adsorption isotherms and calculated structures are consistent with the results of LEED experimental data. In this paper we focus on five features not discussed earlier (Phys. Rev. Lett. 95, 136104 (2005)): the range of the average density of the adsorbate, the order of the transition, the orientational degeneracy of the ground state, the isosteric heat of adsorption of the system, and the effect of the vertical cell dimension.

Wahyu Setyawan; Nicola Ferralis; Renee D. Diehl; Milton W. Cole; Stefano Curtarolo

2006-08-08T23:59:59.000Z

453

Projectile fragmentation of radioactive beams of {sup 68}Ni, {sup 69}Cu, and {sup 72}Zn  

Science Conference Proceedings (OSTI)

The fragment production cross sections of secondary neutron-rich beams of {sup 68}Ni, {sup 69}Cu, and {sup 72}Zn isotopes at energies of about 95A MeV have been measured. We compare the measured cross sections to EPAX, an empirical parametrization of fragmentation cross sections. A reasonable agreement of the experimental data and EPAX predictions suggests that an EPAX parametrization used for stable beams seems to be valid for unstable neutron-rich ion beams. EPAX tends to overestimate the yields of neutron-rich isotopes. This problem is amplified when neutron-rich radioactive beams are employed, leading to overly optimistic estimates of the production of neutron-rich isotopes.

Lukyanov, S.; Lobastov, S. P.; Tarasov, O. B. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, RU-141980 Dubna, Moscow region (Russian Federation); Mocko, M. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Department of Physics and Astronomy, Michigan State University, East Lansing, Michigan 48824 (United States); Andronenko, L.; Andronenko, M. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); PNPI, Gatchina, Leningrad district RU-188300 (Russian Federation); Bazin, D.; Gade, A. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Famiano, M. A. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Department of Physics, Western Michigan University, Kalamazoo, Michigan 49008 (United States); Lynch, W. G.; Rogers, A. M.; Tsang, M. B.; Zegers, R. G. T. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Department of Physics and Astronomy, Michigan State University, East Lansing, Michigan 48824 (United States); Verde, G. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); INFN, Sezione di Catania, 64 Via Santa Sofia, I-95123 Catania (Italy); Wallace, M. S. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2009-07-15T23:59:59.000Z

454

Magnetic motion capture system using LC resonant magnetic marker composed of Ni-Zn ferrite core  

SciTech Connect

We have proposed a magnetic motion capture system using an LC resonant magnetic marker. The proposed system is composed of an exciting coil, an LC marker, and a 5x5-matrix search coil array (25 search coils). The LC marker is small and has a minimal circuit with no battery and can be driven wirelessly by the action of electromagnetic induction. It consists of a Ni-Zn ferrite core (3 mm{phi}x10 mm) with a wound coil and a chip capacitor, forming an LC series circuit with a resonant frequency of 186 kHz. The relative position accuracy of the system is less than 1 mm within the area of 100 mm{sup 3} up to 150 mm from the search coil array. Compared with dc magnetic systems, the proposed system is applicable for precision motion capture in optically isolated spaces without magnetic shielding because the system is not greatly influenced by earth field noise.

Hashi, S.; Toyoda, M.; Ohya, M.; Okazaki, Y.; Yabukami, S.; Ishiyama, K.; Arai, K. I. [Department of Materials Science and Technology, Gifu University, 1-1 Yanagido, Gifu 501-1193 (Japan); Research Institute of Electrical Communication, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2006-04-15T23:59:59.000Z

455

L-shell photoabsorption spectroscopy for solid metals: Ti, V, Cr, Fe, Ni, Cu  

Science Conference Proceedings (OSTI)

Synchrotron radiation measurements of near-threshold and broad-range (400--1500 eV) absolute photoabsorption cross sections were made for five transition metals with {plus minus}10% overall uncertainties. Fine structure details of 2p-3d autoionizing resonances are shown with better than 1.0 eV resolution for solid metals: Ti, V, Cr, Fe, Ni, and Cu. Fine structure similar to what we measured can be produced using a multi-configuration Dirac Fock (MCDF) model if a statistical distribution is assumed for the initial atomic states. Calculations were performed in intermediate coupling with configuration interactions by Mau H. Chen. The results are compared with other experimental work and theoretical methodologies. 18 refs., 7 figs.

Del Grande, N.K. (Lawrence Livermore National Lab., CA (USA))

1989-09-13T23:59:59.000Z

456

Transformation of Sulfur Species during Steam/Air Regeneration on a Ni Biomass Conditioning Catalyst  

DOE Green Energy (OSTI)

Sulfur K-edge XANES identified transformation of sulfides to sulfates during combined steam and air regeneration on a Ni/Mg/K/Al2O3 catalyst used to condition biomass-derived syngas. This catalyst was tested over multiple reaction/regeneration/reduction cycles. Postreaction catalysts showed the presence of sulfides on H2S-poisoned sites. Although H2S was observed to leave the catalyst bed during regeneration, sulfur remained on the catalyst, and a transformation from sulfides to sulfates was observed. Following the oxidative regeneration, the subsequent H2 reduction led to a partial reduction of sulfates back to sulfides, indicating the difficulty and sensitivity in achieving complete sulfur removal during regeneration for biomass-conditioning catalysts.

Yung, M. M.; Cheah, S.; Magrini-Bair, K.; Kuhn, J. N.

2012-07-06T23:59:59.000Z

457