National Library of Energy BETA

Sample records for vc vinyl chloride

  1. Reduction of Vinyl Chloride in Metallic Iron-Water Systems

    E-Print Network [OSTI]

    Deng, Baolin

    Reduction of Vinyl Chloride in Metallic Iron-Water Systems B A O L I N D E N G * Department of Mineral and Environmental Engineering, New Mexico Institute of Mining and Technology, Socorro, New Mexico) reduction by metallic iron in aqueous systems were performed. The effects of various iron loadings, VC

  2. Degradation of Vinyl Chloride and 1,2-Dichloroethane by Advanced Reduction Processes 

    E-Print Network [OSTI]

    Liu, Xu

    2013-07-27

    A new treatment technology, called Advanced Reduction Process (ARP), was developed by combining UV irradiation with reducing reagents to produce highly reactive species that degrade contaminants rapidly. Vinyl chloride (VC) and 1,2-dichloroethane (1...

  3. Microbial reductive dehalogenation of vinyl chloride

    DOE Patents [OSTI]

    Spormann, Alfred M. (Stanford, CA); Muller, Jochen A. (Baltimore, MD); Rosner, Bettina M. (Berlin, DE); Von Abendroth, Gregory (Nannhein, DE); Meshulam-Simon, Galit (Los Altos, CA); McCarty, Perry L (Stanford, CA)

    2011-11-22

    Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

  4. Genome Sequence of the Ethene- and Vinyl Chloride-Oxidizing Actinomycete Nocardioides sp Strain JS614

    SciTech Connect (OSTI)

    Coleman, Nicholas V [University of Sydney, Australia; Wilson, Neil L [University of Sydney, Australia; Barry, Kerrie [U.S. Department of Energy, Joint Genome Institute; Bruce, David [Los Alamos National Laboratory (LANL); Copeland, A [U.S. Department of Energy, Joint Genome Institute; Dalin, Eileen [U.S. Department of Energy, Joint Genome Institute; Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Glavina Del Rio, Tijana [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Hammon, Nancy [U.S. Department of Energy, Joint Genome Institute; Han, Shunsheng [Los Alamos National Laboratory (LANL); Hauser, Loren John [ORNL; Israni, Sanjay [U.S. Department of Energy, Joint Genome Institute; Kim, Edwin [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Lapidus, Alla L. [U.S. Department of Energy, Joint Genome Institute; Larimer, Frank W [ORNL; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Richardson, Paul [U.S. Department of Energy, Joint Genome Institute; Schmutz, Jeremy [Stanford University; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Thompson, Sue [Los Alamos National Laboratory (LANL); Tice, Hope [U.S. Department of Energy, Joint Genome Institute; Spain, Jim C [Georgia Institute of Technology; Gossett, James G [Cornell University; Mattes, Timothy E [University of Iowa

    2011-01-01

    Nocardioides sp. strain JS614 grows on ethene and vinyl chloride (VC) as sole carbon and energy sources and is of interest for bioremediation and biocatalysis. Sequencing of the complete genome of JS614 provides insight into the genetic basis of alkene oxidation, supports ongoing research into the physiology and biochemistry of growth on ethene and VC, and provides biomarkers to facilitate detection of VC/ethene oxidizers in the environment. This is the first genome sequence from the genus Nocardioides and the first genome of a VC/ethene-oxidizing bacterium.

  5. Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides

    E-Print Network [OSTI]

    Pan, Jun

    A facile Pd-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) is described. This method allows convenient access to a variety of aryl, heteroaryl, and vinyl halides in good ...

  6. Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides

    E-Print Network [OSTI]

    Shen, Xiaoqiang

    2010-01-01

    The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides ...

  7. Acetylene Inhibition of Trichloroethene and Vinyl Chloride

    E-Print Network [OSTI]

    Semprini, Lewis

    the biological transformation of VC to ethene. Introduction Chlorinated aliphatic hydrocarbons (CAHs lost their ability to degrade PCE. These results suggested that more than two dehalogenating microorganisms were responsible for the complete transformation of PCE to ethene (4). By examining anaerobic

  8. Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides

    SciTech Connect (OSTI)

    McMurdie, Paul J.; Behrens, Sebastien F.; Muller, Jochen A.; Goke, Jonathan; Ritalahti, Kirsti M.; Wagner, Ryan; Goltsman, Eugene; Lapidus, Alla; Holmes, Susan; Loffler, Frank E.; Spormann, Alfred M.

    2009-06-30

    Vinyl chloride (VC) is a human carcinogen and widespread priority pollutant. Here we report the first, to our knowledge, complete genome sequences of microorganisms able to respire VC, Dehalococcoides sp. strains VS and BAV1. Notably, the respective VC reductase encoding genes, vcrAB and bvcAB, were found embedded in distinct genomic islands (GEIs) with different predicted integration sites, suggesting that these genes were acquired horizontally and independently by distinct mechanisms. A comparative analysis that included two previously sequenced Dehalococcoides genomes revealed a contextually conserved core that is interrupted by two high plasticity regions (HPRs) near the Ori. These HPRs contain the majority of GEIs and strain-specific genes identified in the four Dehalococcoides genomes, an elevated number of repeated elements including insertion sequences (IS), as well as 91 of 96 rdhAB, genes that putatively encode terminal reductases in organohalide respiration. Only three core rdhA orthologous groups were identified, and only one of these groups is supported by synteny. The low number of core rdhAB, contrasted with the high rdhAB numbers per genome (up to 36 in strain VS), as well as their colocalization with GEIs and other signatures for horizontal transfer, suggests that niche adaptation via organohalide respiration is a fundamental ecological strategy in Dehalococccoides. This adaptation has been exacted through multiple mechanisms of recombination that are mainly confined within HPRs of an otherwise remarkably stable, syntenic, streamlined genome among the smallest of any free-living microorganism.

  9. ORIGINAL PAPER Natural Fiber Reinforced Poly(vinyl chloride) Composites: Effect

    E-Print Network [OSTI]

    ORIGINAL PAPER Natural Fiber Reinforced Poly(vinyl chloride) Composites: Effect of Fiber Type of Renewable Natural Resources, Louisiana State University Agricultural Center, Baton Rouge, LA 70803, USA e Science+Business Media, LLC 2008 Abstract Poly(vinyl chloride) (PVC) and natural fiber composites were

  10. Hot Pin Welding of Thin Poly(vinyl chloride) Sheet James D. Van de Ven, Arthur G. Erdman

    E-Print Network [OSTI]

    Van de Ven, James D.

    Hot Pin Welding of Thin Poly(vinyl chloride) Sheet James D. Van de Ven, Arthur G. Erdman Mechanical of welding two thin sheets of poly(vinyl chloride) (PVC) with a heated pin, thus allowing construction of a relationship between the weld temperature and weld strength. Constructing a relationship between weld strength

  11. Simultaneous measurement of laser reflection and transmission of poly,,vinyl chloride...

    E-Print Network [OSTI]

    Van de Ven, James D.

    Simultaneous measurement of laser reflection and transmission of poly,,vinyl chloride... James D. Van de Ven Arthur G. Erdman University of Minnesota Mechanical Engineering Department 111 Church. Previous work measuring optical properties for this purpose placed little importance on the light

  12. Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures

    E-Print Network [OSTI]

    Van de Ven, James D.

    Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures James D. Van de Ven, Arthur G. Erdman Mechanical Engineering Department, University of Minnesota, Minneapolis, Minnesota 55305 yields that little work has been done analyzing the relationship between light absorption and temperature

  13. Characterization of poly(vinyl chloride) aged in a bromine containing electrolyte

    SciTech Connect (OSTI)

    Arnold, C. Jr.; Leo, A.; Tarjani, M.

    1988-01-01

    Poly(vinyl chloride) (PVC) is being considered for use as a flow frame material in a developmental zinc/bromine battery. The choice of PVC was based on its low cost and the ease with which it can be molded into complex parts. The electrolyte used in this battery is a highly corrosive mixture of bromine, zinc bromide, zinc chloride, potassium bromide, potassium chloride and a quaternary amine salt. The quaternary salt serves to reduce the concentration of free bromine in the electrolyte by virtue of its complexing capability. It is well known that aqueous bromine is capable of oxidizing organic compounds. The purpose of the current study was to investigate the effect of a bromine electrolyte on two PVC formulations, PVC-1 and PVC-4. PVC-1 is the designation given to one of B.F. Goodrich's commercial formulations and is the present baseline material for the flow frame. PVC-4 is an experimental B.F. Goodrich formulation that was developed especially for battery applications. We sought answers to such questions as (1) does oxidation and/or bromination take place. (2) does bromine penetrate into the sample and, if so, how far. (3) how are the mechanical and morphological properties affected. and (4) are there differences in stability between PVC-1 and PVC-4. To accelerate the aging processes we aged the PVC samples at an elevated temperature in an electrolyte which did not contain any complexing agent. 5 refs., 6 figs.

  14. Control technology of vinyl chloride in EDC-VCM and PVC plants at main source points and fugitive emissions 

    E-Print Network [OSTI]

    Parra, Dario Antonio

    1983-01-01

    of the great quantities of dilute gas in EDC-VCN and PVC plants, the combustion system cannot be self-supported and therefore additional fuel is necessary, resulting in a waste of combustibles and heat. 3. Due to the flame, flares need to be located away...CONTROL TECHNOLOGY OF VINYL CHLORIDE IN EDC-VCM AND PVC PLANTS AT MAIN SOURCE POINTS AND FUGITIVE EMISSIONS A Thesis by DARIO ANTONIO PARRA Submitted to the Graduate College of Texas A6M University in partial fulfillment of the requirements...

  15. Heat Flow in VC-2A and VC-2B, and Constraints on the Thermal...

    Open Energy Info (EERE)

    Heat Flow in VC-2A and VC-2B, and Constraints on the Thermal Regime of the Valles Caldera, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  16. InspiredVC LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13 (Vt.InfinifuelInova Energy Jump to:OpenInspiredVC LLC

  17. VC v. VCG: Inapproximability of Combinatorial Auctions via Generalizations of the VC Dimension

    E-Print Network [OSTI]

    Sandholm, Tuomas W.

    is the paradigmatic problem in computational mech- anism design. It is believed that in many cases good approximations efficiency. However, to date, researchers lack the machinery to prove such results. In this paper, we present the VC-dimension of k-tuples of disjoint sets. We apply this machinery to prove the first computational

  18. Preparation of vinyl acetate

    DOE Patents [OSTI]

    Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

    1998-03-24

    This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

  19. Microthermometry of Fluid Inclusions from the VC-1 Core Hole...

    Open Energy Info (EERE)

    Caldera, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Microthermometry of Fluid Inclusions from the VC-1 Core Hole in Valles...

  20. Patent: Microbial reductive dehalogenation of vinyl chloride | DOEpatents

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding access toSmall Reactor for DeepK.alpha. X-ray imagingMicrobial

  1. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    and Vinyl Siding R. Hart*, C. Curcija, D. Arasteh, H.and Vinyl Siding Robert Hart*, Charlie Curcija, Dariush

  2. Rheology of silicon carbide/vinyl ester nanocomposites

    E-Print Network [OSTI]

    Yong, Virginia; Hahn, H. Thomas

    2006-01-01

    based vinyl ester and 45 wt % styrene mono- mers. The hybridcould copolymerize with styrene monomers in the vinyl ester

  3. sup 3 P Hg, Cd, and Zn photosensitized chemistry of vinyl halides in krypton matrix

    SciTech Connect (OSTI)

    Cartland, H.E.; Pimentel, G.C. )

    1990-01-25

    The reaction of group IIB metals in the {sup 3}P state with vinyl fluoride, chloride, and bromide is studied in krypton matrix. The primary process in all cases is hydrogen halide elimination to form a hydrogen halide/acetylene hydrogen-bonded complex. Insertion of metal atoms into C-Cl and C-Br bonds, but not into C-H and C-F bonds, is also observed. The insertion photochemistry can be explained by a mechanism which requires that the process occur on a triplet surface with the vinyl halide in the planar ground-state conformation.

  4. The use and misuse of Vc,max in Earth System Models Alistair Rogers

    E-Print Network [OSTI]

    Rogers, Alistair

    REVIEW The use and misuse of Vc,max in Earth System Models Alistair Rogers Received: 18 November Dordrecht (outside the USA) 2013 Abstract Earth System Models (ESMs) aim to project global change. Central Á Vc,max Á Leaf nitrogen Á Earth System Models Introduction The primary goal of Earth System Models

  5. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    Extrusion process Improperly processed vinyl siding may be more susceptible to distortions such as oil-

  6. Chemistry of enol ethers. LXXXIV. Condensation of acetals of saturated aldehydes with 2-trimethylsilyloxy-1,3-dienes. Synthesis of /beta/-alkoxy-alkyl vinyl and divinyl ketones

    SciTech Connect (OSTI)

    Makin, S.M.; Nazarova, O.N.; Dymshakova, G.M.; Kundryutskova, L.A.

    1988-11-10

    The addition of the acetals of saturated aldehydes (formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, and isobutyraldehyde) to 2-trimethylsilyloxy-4-methyl-1,3-pentadiene in the presence of aprotic acids (ZnCl/sub 2/, ZnBr/sub 2/, FeCl/sub 3/, SnCl/sub 4/, BF/sub 3/ /times/ OEt/sub 2/) takes place at positions 1, 2 of the diene system with the formation of /beta/-alkoxyalkyl vinyl ketones. The most effective catalysts of this reaction were stannic chloride and zinc bromide. The alkyl derivatives of divinyl ketones are formed when the obtained /beta/-alkoxyalkyl vinyl ketones are heated with p-toluenesulfonic acid.

  7. Process for the preparation of vinyl acetate

    DOE Patents [OSTI]

    Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

    1998-02-17

    This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85 and 200 C and removing the reaction products from the contact zone.

  8. Vinyl Siding Institute (VSI) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin,Village of Wellington, Ohio (UtilityVinyl Kraft Windows

  9. Chloride removal from vitrification offgas

    SciTech Connect (OSTI)

    Slaathaug, E.J. [Westinghouse Hanford Co., Richland, WA (United States)

    1995-06-01

    This study identified and investigated techniques of selectively purging chlorides from the low-level waste (LLW) vitrification process with the purge stream acceptable for burial on the Hanford Site. Chlorides will be present in high concentration in several individual feeds to the LLW Vitrification Plant. The chlorides are highly volatile in combustion type melters and are readily absorbed by wet scrubbing of the melter offgas. The Tank Waste Remediation System (TWRS) process flow sheets show that the resulting chloride rich scrub solution is recycled back to the melter. The chlorides must be purged from the recycle loop to prevent the buildup of excessively high chloride concentrations.

  10. Rate-dependent deformation behavior of poss-filled and plasticized poly(vinyl chloride)

    E-Print Network [OSTI]

    Soong, Sharon Yu-Wen

    2007-01-01

    Polymers are known to exhibit strong time-dependent mechanical behavior. In different temperatures or frequency regimes, the rate sensitivities of polymers change as various primary and secondary molecular mobility mechanisms ...

  11. Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides

    E-Print Network [OSTI]

    McMurdie, Paul J.

    2010-01-01

    package [75] of the R language for statistical computing [R Development Core Team (2009) R: A Language and Environment for Statistical

  12. The impact of improved materials in poly(vinyl chloride)-based endotracheal tubes

    E-Print Network [OSTI]

    Domike, Kristin Rebecca, 1981-

    2004-01-01

    Endotracheal tubes (ETs) are used to aid artificial ventilation in millions of medical patients every year and are known to invoke the proliferative phase in the cell linings. The technical objective of this work was to ...

  13. Abstract ---Computed tomography colonography (CTC) or CT-based virtual colonoscopy (VC) is an emerging tool for detection

    E-Print Network [OSTI]

    . The radiation dose is a major concern for screening application of CTC. In this work, we performed a simulation study to demonstrate a possible ultra low-dose CT technique for VC. The ultra low-dose abdominal CT by a filtered backprojection algorithm for the ultra low-dose CT images. The patient-specific virtual colon

  14. PERFORMANCE ENHANCEMENT OF COMPRESSION MOLDED KENAF FIBER REINFORCED VINYL ESTER COMPOSITES THROUGH RESIN ADDITIVE

    SciTech Connect (OSTI)

    Fifield, Leonard S.; Simmons, Kevin L.; Laddha, Sachin; Kafentzis, Tyler A.

    2010-05-17

    Plant-based bio-fiber has the potential to achieve weight and cost savings over glass fiber in automotive polymer composites if moisture stability and fiber-resin compatibility issues can be solved. This paper describes the compression molding of 50vol% 2 inch random nonwoven mat kenaf fiber vinyl ester composites with and without chemical resin additives intended to improve moisture stability and resin compatibility. The 2wt% addition of n-undecanoyl chloride or 10-undecenoyl chloride to the styrene-based resin prior to molding of the kenaf composites was observed to decrease the 24hr, 25oC moisture uptake of the molded panels by more than 50%. The tensile stiffness and flexural stiffness of the soaked panels containing these additives were seen to increase by more than 30% and 70%, respectively, relative to panels made with no additives. While ‘dry’ panel (50% relative humidity at 25oC) strengths did not significantly change in the presence of the additives, tensile strength was observed to increase by more than 40% and flexural strength more than doubled for the soaked panels.

  15. Enhanced electrocatalytic activity and stability of Pd3V/C nanoparticles with a trace amount of Pt decoration for the oxygen reduction reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Sufen; Han, Lili; Zhu, Jing; Xiao, Weiping; Wang, Jie; Liu, Hongfang; Xin, Huolin; Wang, Deli

    2015-09-14

    In this study, carbon supported Pd3V bimetallic alloy nanoparticles (Pd3V/C) have been successfully synthesized via a simple impregnation–reduction method, followed by high temperature treatment under a H2 atmosphere. Electrochemical tests reveal that the half-wave potential of Pd3V/C-500 shifts positively 40 mV compared with Pd/C. However, the catalytic activity of Pd3V/C-500 suffers from serious degradation after 1k cycles. By a spontaneous displacement reaction or co-reduction method, a trace amount of Pt was decorated on the surface or inside of the Pd3V/C nanoparticles. The catalytic activity and stability of the Pd3V@Pt/C and Pt-Pd3V/C catalysts for the oxygen reduction reaction (ORR) are enhancedmore »significantly, and are comparable to commercial Pt/C. In addition, the Pt mass activity of Pd3V@Pt/C and Pt-Pd3V/C improves by factors of 10.9 and 6.5 at 0.80 V relative to Pt/C. Moreover, Pt-decorated Pd3V/C nanoparticles show almost no obvious morphology change after durability tests, because the Pt-rich shell plays an important role in preventing degradation.« less

  16. Research Needs: Glass Solar Reflectance and Vinyl Siding

    SciTech Connect (OSTI)

    Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

    2011-07-07

    The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

  17. Synthesis of vinyl acetate on palladium-based catalysts 

    E-Print Network [OSTI]

    Kumar, Dheeraj

    2009-06-02

    ACETATE ON PALLADIUM-BASED CATALYSTS A Dissertation by DHEERAJ KUMAR Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY August 2006... Major Subject: Chemistry SYNTHESIS OF VINYL ACETATE ON PALLADIUM-BASED CATALYSTS A Dissertation by DHEERAJ KUMAR Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

  18. Monodisperse SiC/vinyl ester nanocomposites: Dispersant formulation, synthesis, and characterization

    E-Print Network [OSTI]

    Yong, Virginia; Hahn, H. Thomas

    2011-01-01

    polyester copolymerizes with styrene monomers in the vinylbased vinyl ester and 45 wt% styrene monomers. The hybridof methacrylate and styrene. The absorption band in the

  19. Synthesis and Characterization of (Tris(3,5-dimethylpyrazolyl)borato)rhodium Alkyl and Vinyl Chloride Complexes

    E-Print Network [OSTI]

    Jones, William D.

    -reducing side reactions. Additionally, secondary derivatives of normal alkanes cannot be prepared by this method, it is not economical due to the sacrifice of 1 equiv of neopentyl isocyanide. Chambron and co-workers have reported. Powell and co-workers have reported a method for synthesizing a wide range of air-stable Rh

  20. An investigation in the hygrothermal degradation of an E- glass/vinyl-ester composite in humid and immersion environments

    E-Print Network [OSTI]

    Svetlik, Stephanie Laura

    2008-01-01

    of polyethertriamine-cured bisphenol-A-diglycidyl etherstructure of epoxy based bisphenol-A vinyl ester resin [here, an epoxy based bisphenol-A vinyl-ester, may have a

  1. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  2. The use of DRIFTS-MS and kinetic studies to determine the role of acetic acid in the palladium-catalyzed vapor-phase synthesis of vinyl acetate

    SciTech Connect (OSTI)

    Augustine, S.M.; Blitz, J.P. (Quantum Chemical Corp., Cincinnati, OH (United States))

    1993-07-01

    Supported palladium catalyzes the synthesis of vinyl acetate (VA) by oxyacetylation of ethylene. Alkali promoters increase activity and selectivity. The role of acetic acid (HOAc) in these processes is not well understood. Activation energy studies show that HOAc alters the catalyst site and lowers the reaction barrier to VA formation. After correction for this effect, the kinetics reveal that as a reagent HOAc is zero order. This is probably due to a strong adsorption of HOAc and Pd which forms the catalyst active phase. Detailed spectroscopic studies support this conclusion. The surface processes on a supported vinyl acetate catalyst were studied using a method which couples diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) with mass spectrometry (MS). The DRIFTS-MS technique combines the capability of selectively analyzing IR-active surface species with sensitive detection of transient reaction products. By comparing the catalyst with mixtures of palladium acetate powder physically dispersed in potassium chloride, it is determined that the active phase on the catalyst is a form of palladium acetate. Compound formation is consistent with the strong chemisorption of HOAc on Pd. Kinetic analysis of temperature-programmed reaction(TPRxn) data suggests that Pd metal or metal oxide adjacent to the active site is important in the reaction mechanism. 25 refs., 10 figs., 2 tabs.

  3. Vinyl Kraft Windows and Doors | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin,Village of Wellington, Ohio (UtilityVinyl Kraft Windows and

  4. Process for synthesis of beryllium chloride dietherate

    DOE Patents [OSTI]

    Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

    1991-01-01

    A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

  5. Hydrocracking with molten zinc chloride catalyst containing 2-12% ferrous chloride

    DOE Patents [OSTI]

    Zielke, Clyde W. (McMurray, PA); Bagshaw, Gary H. (Library, PA)

    1981-01-01

    In a process for hydrocracking heavy aromatic polynuclear carbonaceous feedstocks to produce hydrocarbon fuels boiling below about 475.degree. C. by contacting the feedstocks with hydrogen in the presence of a molten zinc chloride catalyst and thereafter separating at least a major portion of the hydrocarbon fuels from the spent molten zinc chloride catalyst, an improvement comprising: adjusting the FeCl.sub.2 content of the molten zinc chloride to from about 2 to about 12 mol percent based on the mixture of ferrous chloride and molten zinc chloride.

  6. Measurement of spin effects in p/sub up-arrow/+p/sub up-arrow/. -->. p+p at 18. 5 GeVc

    SciTech Connect (OSTI)

    Crabb, D.G.; Gialas, I.; Krisch, A.D.; Lin, A.M.T.; Peaslee, D.C.; Phelps, R.A.; Raymond, R.S.; Roser, T.; Stewart, J.A.; Terwilliger, K.M.; and others

    1988-06-06

    We measured the analyzing power A and the spin-spin correlation parameter A/sub n//sub n/ in medium-P/sub perpendicular//sup 2/ proton-proton elastic scattering, using a polarized-proton target and the 18.5-GeVc Brookhaven Alternating-Gradient Synchrotron polarized-proton beam. We found sharp dips in both A and A/sub n//sub n/, which occur at different P/sub perpendicular//sup 2/ values. The unexpected sharp structure in the spin-spin force occurs near P/sub perpendicular//sup 2/ = 2.3 (GeVc)/sup 2/ where the elastic cross section has no apparent structure.

  7. Fight chloride corrosion in aqueous systems

    SciTech Connect (OSTI)

    Kirby, G.N.

    1995-02-01

    In iron-based alloys like carbon steel or stainless steel, the chloride ion increases corrosion by increasing the water's conductivity and by penetrating the alloy's protective oxides. It can increase overall or general corrosion, and can cause localized corrosion such as pitting and stress corrosion cracking. The chloride ion occurs naturally in seawater, in ground waters, in potable water, in condensate after incinerating waste materials such as polyvinyl chloride, and from the hydrolysis or decomposition of chlorinated hydrocarbons such as carbon tetrachloride or trichloroethane. Chlorides can also occur as trace impurities in bulk chemicals where they are neither expected nor analyzed for, but nonetheless can cause serious corrosion. This trace effect is worsened by the tendency of chlorides to concentrate in pits and crevices, especially on heated or intermittently wet and dry surfaces, to amounts that can be orders of magnitude greater than the percentage of chlorides in the bulk liquid. In this article the effects of chloride corrosion, as well as corrosion resistance are discussed.

  8. Palladium-Catalyzed Cross-Coupling of Aryl or Vinyl Iodides with Ethyl Diazoacetate

    E-Print Network [OSTI]

    Wang, Jianbo

    Palladium-Catalyzed Cross-Coupling of Aryl or Vinyl Iodides with Ethyl Diazoacetate Cheng PengVersity, Beijing 100871, China Received April 30, 2007; E-mail: wangjb@pku.edu.cn Palladium catalyzed cross

  9. Plug repairs of marine glass fiber / vinyl ester laminates subjected to uniaxial tension

    E-Print Network [OSTI]

    Michelis, Alexandros

    2009-01-01

    Glass fiber/vinyl ester composite laminates are currently being used and proposed for the hulls, bulkheads, and superstructures of large ships. This thesis examines the effectiveness of the repair of such laminates using ...

  10. Ethylene-Vinyl Acetate Potential Problems for Photovoltaic Packaging: Preprint

    SciTech Connect (OSTI)

    Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K. M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

    2006-05-01

    Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support, optical coupling, electrical isolation, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate, it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about ?15 C. Temperatures lower than this can be reached for extended periods of time in some climates. Because of increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL 1703.

  11. Ethylene-Vinyl Acetate Potential Problems for Photovoltaic Packaging

    SciTech Connect (OSTI)

    Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K. M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

    2006-01-01

    Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support, optical coupling, electrical isolation, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate, it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about -15 degC. Temperatures lower than this can be reached for extended periods of time in some climates. Because of increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL1703.

  12. Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic C–H Functionalization

    E-Print Network [OSTI]

    Cheung, Chi Wai

    A copper(II)-catalyzed oxidative cyclization of enamides to oxazoles via vinylic C–H bond functionalization at room temperature is described. Various 2,5-disubstituted oxazoles bearing aryl, vinyl, alkyl, and heteroaryl ...

  13. The adsorption and reaction of vinyl acetate on Au/Pd(100) alloy surfaces

    SciTech Connect (OSTI)

    Li, Zhenjun [Pacific Northwest National Laboratory (PNNL); Calaza, Florencia C [ORNL; Tysoe, Wilfred [University of Wisconsin, Milwaukee

    2012-01-01

    The surface chemistry of vinyl acetate monomer (VAM) is studied on Au/Pd(100) alloys as a function of alloy composition using temperature-programmed desorption and reflection adsorption infrared spectroscopy. VAM adsorbs weakly on isolated palladium sites on the alloy with a heat of adsorption of ~55 kJ/mol, with the plane of the VAM adsorbed close to parallel to the surface. The majority of the VAM adsorbed on isolated sites desorbs molecularly with only a small portion decomposing. At lower gold coverages (below ~0.5 ML of gold), where palladium palladium bridge sites are present, VAM binds to the surface in a distorted geometry via a rehybridized vinyl group. A larger proportion of this VAM decomposes and this reaction is initiated by C\\O bond scission in the VAM to form adsorbed acetate and vinyl species. The implication of this surface chemistry for VAM synthesis on Au/Pd(100) alloys is discussed.

  14. Absorption media for irreversibly gettering thionyl chloride

    DOE Patents [OSTI]

    Buffleben, George (Tracy, CA); Goods, Steven H. (Livermore, CA); Shepodd, Timothy (Livermore, CA); Wheeler, David R. (Albuquerque, NM); Whinnery, Jr., LeRoy (Danville, CA)

    2002-01-01

    Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

  15. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    chloride in superheated geothermal steam. Geothermics 1989,condensate from superheated geothermal steam. Implicationsexpansion of superheated geothermal steam, with implications

  16. FUNDAMENTALSTUDY FOR IMPROVEMENT OF ESTIMATION ACCURACY CHLORIDE CONTENT USING

    E-Print Network [OSTI]

    Boyer, Edmond

    by the electromagnetic wave radar that chloride contents and water contents, and temperature affected the electricalFUNDAMENTALSTUDY FOR IMPROVEMENT OF ESTIMATION ACCURACY CHLORIDE CONTENT USING ELECTROMAGNETIC, Tokyo, Japan mami.uchida.4k@stu.hosei.ac.jp ABSTRACT Chloride contents estimation using electromagnetic

  17. Method for the regeneration of spent molten zinc chloride

    DOE Patents [OSTI]

    Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

    1981-01-01

    In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

  18. Thermochimica Acta 403 (2003) 3741 Glass transition of thin films of poly(2-vinyl pyridine) and

    E-Print Network [OSTI]

    Allen, Leslie H.

    2003-01-01

    Thermochimica Acta 403 (2003) 37­41 Glass transition of thin films of poly(2-vinyl pyridine.1016/S0040-6031(03)00122-9 #12;38 M.Yu. Efremov et al. / Thermochimica Acta 403 (2003) 37­41 polymers

  19. Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani (Morgantown, WV)

    2010-08-03

    Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

  20. Palladium-Catalyzed Enantioselective ?-Arylation and ?-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand

    E-Print Network [OSTI]

    Taylor, Alexander M.

    The enantioselective ?-arylation and ?-vinylation of oxindoles catalyzed by Pd and a biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The resultant quaternary carbon stereocenters ...

  1. Effects of Concentration of Organically Modified Nanoclay on Properties of Sulfonated Poly(vinyl alcohol) Nanocomposite Membranes

    E-Print Network [OSTI]

    Sanglimsuwan, Apiradee

    Electrolyte nanocomposite membranes for proton exchange membrane fuel cells and direct methanol fuel cells were prepared by carrying out a sulfonation of poly(vinyl alcohol) with sulfosuccinic acid and adding a type of ...

  2. First CSDP (Continental Scientific Drilling Program)/thermal regimes core hole project at Valles Caldera, New Mexico (VC-1): Drilling report

    SciTech Connect (OSTI)

    Rowley, J.; Hawkins, W.; Gardner, J. (comps.)

    1987-02-01

    This report is a review and summary of the core drilling operations of the first Valles Caldera research borehole (VC-1) under the Thermal Regimes element of the Continental Scientific Drilling Program (CSDP). The project is a portion of a broader program that seeks to answer fundamental scientific questions about magma, rock/water interactions, and volcanology through shallow (<1-km) core holes at Long Valley, California; Salton Sea, California; and the Valles Caldera, New Mexico. The report emphasizes coring operations with reference to the stratigraphy of the core hole, core quality description, core rig specifications, and performance. It is intended to guide future research on the core and in the borehole, as well as have applications to other areas and scientific problems in the Valles Caldera. The primary objectives of this Valles Caldera coring effort were (1) to study the hydrogeochemistry of a subsurface geothermal outflow zone of the caldera near the source of convective upflow, (2) to obtain structural and stratigraphic information from intracaldera rock formations in the southern ring-fracture zone, and (3) to obtain continuous core samples through the youngest volcanic unit in Valles Caldera, the Banco Bonito rhyolite (approximately 0.1 Ma). All objectives were met. The high percentage of core recovery and the excellent quality of the samples are especially notable. New field sample (core) handling and documentation procedures were successfully utilized. The procedures were designed to provide consistent field handling of the samples and logs obtained through the national CSDP.

  3. Synthesis and characterization of vinyl-bridged polysilsesquioxane sol-gel materials

    SciTech Connect (OSTI)

    Yamanaka, S.A.; Carpenter, J.P.; McClain, M.D.; Loy, D.A.

    1995-08-01

    Vinyl-bridged polysilsesquioxane gels were formed through the use of sol-gel polymerization methods. Acid- and base-catalyzed samples were prepared from both the pure cis-(l) and pure trans-(2) isomers of 1, 2-bis(triethoxysilyl)ethylene. Gelation times of the two isomers were compared. The trans monomer 2 formed gels within a week while the cis monomer I failed to gel-even after several months. Gelation of 1 could be promoted by the addition of a coordinating metal such as palladium. The resulting cis- and trans- vinyl-bridged polysilsesquioxane gels were then processed either by vacuum drying to afford xerogels or by extracting with supercritical carbon dioxide to afford aerogels. These vinylbridged polysilsesquioxanes were characterized by SEM, nitrogen sorption porosimetry, solid State {sub 29}Si and {sub 13}C NMR and x-ray powder diffraction.

  4. Membrane Transport Chloride Transport Across Vesicle and Cell

    E-Print Network [OSTI]

    Smith, Bradley D.

    Membrane Transport Chloride Transport Across Vesicle and Cell Membranes by Steroid-Based Receptors-established that molecules which transport cations across cell membranes (cationophores) can have potent biological effects of biological activity. Indeed, chloride transporters have direct medical potential as treatments for cystic

  5. A virtual rapid chloride permeability test Dale P. Bentz *

    E-Print Network [OSTI]

    Bentz, Dale P.

    A virtual rapid chloride permeability test Dale P. Bentz * Building and Fire Research Laboratory The rapid chloride permeability test (RCPT), as it is commonly called, has been in existence for over 20 years and was standardized by ASTM over 15 years ago. The test is used extensively in the concrete

  6. Method for synthesizing pollucite from chabazite and cesium chloride

    DOE Patents [OSTI]

    Pereira, Candido (Naperville, IL)

    1999-01-01

    A method for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700.degree. C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

  7. Method for synthesizing pollucite from chabazite and cesium chloride

    DOE Patents [OSTI]

    Pereira, C.

    1999-02-23

    A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

  8. Funding alternatives Angel vs VC

    E-Print Network [OSTI]

    Solem, Jan Erik

    , family & fools) #12;LearningsfromfoundingaComputerVisionStartup Sanity check! Do you really need to raise/20) management fees - partners get ~2% of invested capital carried interest - partners' management company get investors Storytelling ! Problem & solution (technology is secondary) ! Show a market Flickr: akrobat77

  9. Method for the production of uranium chloride salt

    DOE Patents [OSTI]

    Westphal, Brian R.; Mariani, Robert D.

    2013-07-02

    A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

  10. Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte

    SciTech Connect (OSTI)

    Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

    2005-02-28

    A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by ATR-FTIR and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2 percent VEC at 4.1 V showed the presence of a high molecular weight polymer. IR analysis indicated polycarbonate with alkyl carbonate rings linked by aliphatic methylene and methyl branches.

  11. Hydrogen chloride in superheated steam and chloride in deep brine at The Geysers geothermal field, California

    SciTech Connect (OSTI)

    Haizlip, J.R.; Truesdell, A.H.

    1988-01-01

    Chloride (Cl) concentrations of 10-120 ppm{sub w} have been measured in superheated steam produced by wells at The Geysers, a vapor-dominated geothermal field in northern California. Corrosion of the well casing and steam-gathering system has been recognized in some parts of The Geysers, and is apparently related to the presence of Cl. Cl in the steam is in a volatile form, generated with the steam at reservoir temperatures, and probably travels to the wellhead as HCl gas. Published experimental data for partial pressures of HCl in steam over aqueous HCl solutions and for dissociation constants of HCl were used to calculate distribution coefficients for HCl. Reservoir liquid Cl concentrations capable of generating steam with the observed Cl concentrations were then calculated as a function of pH and temperatures from 250 to 350º C. Equilibrium mineral/liquid reactions with the K-mica and K-feldspar assemblage found in the wells limit the reservoir liquid pH values at various Cl concentrations to about 5 to 6 (near neutral at 250 to 350º C). Within this pH range, liquid at 250º C could not produce steam containing the high Cl concentrations observed. However, liquid at higher temperatures (300 to 350º C) with chloride concentrations greater than 10,000 ppm{sub w} could generate steam with 10 to over 200 ppm{sub w} Cl. There is a positive correlation between pH and the chloride concentrations required to generate a given Cl concentration in steam. The concentration of Cl in superheated steam constrains not only the reservoir liquid composition, but the temperature at which the steam last equilibrated with liquid.

  12. Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional...

    Open Energy Info (EERE)

    Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional Geothermal Indicator in Hawaii Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  13. The Salt or Sodium Chloride Content of Feeds 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

    1920-01-01

    STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BIZZELL, Preeident BULLETIN NO. 271 OCTOBER, 1920 DIVISION OF CHEMISTRY THE SALT OR SODIUM CHLORIDE CONTENT OF FEEDS B. YOUNGBLOOD, DIRECTOK COLLEGE STATION, BRAZOS COUNTT, TEXAS I..... ................... Summary ancl conclusions. Page. l1 [Blank Page in Original Bulletin] BULLETIN XO. 271. OCTOBE- '"On THE SALT OR SODIUM CHLORIDE CONTENT OF FEI The Texas feed law requires the statement of the ingredients of many mixed feeds. Common salt or sodium...

  14. Densities in the Liquid Hydrogen Chloride Solvent System Heather Brooks Shapiro and Donald R. Sadoway*

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    Densities in the Liquid Hydrogen Chloride Solvent System Heather Brooks Shapiro and Donald R in the hydrogen chloride solvent system over the normal liquid range of the solvent. In addition to pure hydrogen to be insoluble in liquid hydrogen chloride. Solutions were prepared by condensing hydrogen chloride over solute

  15. Chloride chemical form in various types of fly ash

    SciTech Connect (OSTI)

    Fenfen Zhu; Masaki Takaoka; Kenji Shiota; Kazuyuki Oshita; Yoshinori Kitajima

    2008-06-01

    Chloride content is a critical problem for the reuse of fly ash as a raw material in cement, and the method used by recyclers to reduce the fly ash chloride content depends on the chemical form of the chlorides. However, limited information is available on the quantitative distribution of chlorides and the identity of some chlorides such as Friedel's salt. We examined chloride forms and percentages using X-ray absorption near edge structure and X-ray diffraction analyses, as well as corresponding washing experiments. Approximately 15% of the chlorine in raw fly ash was estimated to be in the form of NaCl, 10% in KCl, 50% in CaCl{sub 2}, and the remainder in the form of Friedel's salt. Fly ash collected in a bag filter with the injection of calcium hydroxide for acid gas removal (CaFA) contained 35% chlorine as NaCl, 11% as KCl, 37% as CaCl{sub 2}, 13% as Friedel's salt, and the remaining 4% as CaClOH. In fly ash collected in a bag filter with the injection of sodium bicarbonate for acid gas removal (NaFA), approximately 79% of chlorine was in NaCl, 12% was in KCl, and 9% was in Friedel's salt. 25 refs., 4 figs., 4 tabs.

  16. Crystallization in the Thin and Ultrathin Films of Poly(ethylene-vinyl acetate) and Linear Low-Density Polyethylene

    E-Print Network [OSTI]

    -Density Polyethylene Y. Wang, S. Ge, M. Rafailovich,*, J. Sokolov, Y. Zou, H. Ade, J. Lu1 ning,§ A. Lustiger, and G(ethylene-vinyl acetate) and linear low-density polyethylene (LLDPE) films spun-cast from the polymer/toluene solutions spherulite to sheaflike ag- gregates in polyethylene thin films at a critical thickness of 400 nm. Scho

  17. Reactive triblock polymers from tandem ring-opening polymerization for nanostructured vinyl thermosets

    SciTech Connect (OSTI)

    Amendt, Mark A.; Pitet, Louis M.; Moench, Sarah; Hillmyer, Marc A.

    2013-03-07

    Multiply functional hydroxyl telechelic poly(cyclooctene-s-5-norbornene-2-methylene methacrylate) was synthesized by ring opening metathesis (co)polymerization of cis-cyclooctene and 5-norbornene-2-methylene methacrylate using the second generation Grubbs catalyst in combination with a symmetric chain transfer agent bearing hydroxyl functionality. The resulting hydroxyl-telechelic polymer was used as a macroinitiator for the ring opening transesterification polymerization of d,l-lactide to form reactive poly(lactide)-b-poly(cyclooctene-s-5-norbornene-2-methylene methacrylate)-b-poly(lactide) triblock polymers. Subsequently, the triblocks were crosslinked by free radical copolymerization with several vinyl monomers including styrene, divinylbenzene, methyl methacrylate, and ethyleneglycol dimethacrylate. Certain conditions led to optically transparent thermosets with mesoscale phase separation as evidenced by small angle X-ray scattering, differential scanning calorimetry and transmission electron microscopy. Disordered, bicontinuous structures with nanoscopic domains were generated in several cases, rendering the samples attractive for size-selective membrane applications.

  18. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  19. Conducting polymer blends: Polypyrrole and polythiophene blends with polystyrene, polycarbonate resin, poly(vinyl alcohol) and poly(vinyl methyl ketone)

    SciTech Connect (OSTI)

    Wang, H.L.

    1992-01-01

    Various aromatic compounds can be polymerized by electrochemical oxidation in solution containing a supporting electrolyte. Most studies have been devoted to polypyrrole and polythiophene. In situ doping during electrochemical polymerization yields free standing conductive polymer film. One major approach to making conducting polymer blends is electrochemical synthesis after coating the host polymer on a platinum electrode. In the electrolysis of pyrrole or thiophene monomer, using (t-Bu[sub 4]N)BF[sub 4] as supporting electrolyte, and acetonitrile as solvent, monomer can diffuse through the polymer film, to produce a polypyrrole or polythiophene blend in the film. Doping occurs along with polymerization to form a conducting polymer alloy. The strongest molecular interaction in polymers, and one that is central to phase behavior, is hydrogen bonding. This mixing at the molecular level enhances the degree of miscibility between two polymers and results in macroscopic properties indicative of single phase behavior. In this dissertation, the authors describes the syntheses of conducting polymer blends: polypyrrole and polythiophene blends with polystyrene, poly(bisphenol-A-carbonate), polyvinyl alcohol and poly(vinyl methyl ketone). The syntheses are performed both electrochemically and chemically. Characterization of these blends was carried out by Fourier Transform Infrared spectroscopy, Differential Scanning Calorimetry, Thermogravimetric Analysis, Scanning Electron Microscopy, and X-ray diffraction. Percolating threshold conductivities occur from 7% to 20% for different polymer blends. The low threshold conductivity is attributed to blend homogeneity enhanced by hydrogen bonding between the carbonyl group in the insulating polymer and the N-H group in polypyrrole. Thermal stability, environmental stability, mechanical properties, crystallinity and morphological structure are also discussed. The authors have also engaged in the polymerization of imidazoles.

  20. Catalytic hydrogenation of an aromatic sulfonyl chloride into thiophenol 

    E-Print Network [OSTI]

    Rouckout, Nicolas Julien

    2009-05-15

    are blocked and an amorphous layer was formed on the surface of the palladium catalyst. Semi-Batch mode experimental data were obtained at 110 °C after 8 hours of reaction time for several aromatic sulfonyl chlorides. A kinetic model has been developed, which...

  1. Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis Lekha Gupta, 2008 Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C protocols with unpurified commercial samples of n-butyl- lithium to prepare LDA or commercially available

  2. Preparation of Genomic DNA from Hawaiian Bobtail Squid (Euprymna scolopes) Tissue by Cesium Chloride Gradient

    E-Print Network [OSTI]

    Ruby, Edward G.

    by Cesium Chloride Gradient Centrifugation Patricia N. Lee1,2 , Margaret J. McFall-Ngai3 , Patrick Callaerts from adult bobtail squid (Euprymna scolopes) tissues by cesium chloride (CsCl) gradient centrifugation

  3. Agronomic differences in growth and yield between BT and conventional cotton treated with mepiquat chloride 

    E-Print Network [OSTI]

    Underbrink, Shelley Marie

    1999-01-01

    Cotton (Gossypium hirsutum L.), an indeterminacy plant, may exhibit rank vegetative growth under conditions of high fertility and high moisture. Traditionally, mepiquat chloride (l,l-dimethylpiperidinium chloride) has been applied to cotton...

  4. CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Vermeulen, T.

    2012-01-01

    CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE T. Vermeulen, C.CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE T. Vermeulen, C.rather than by thermal pyrolysis which requires appreciably

  5. The ultra-high lime with aluminum process for removing chloride from recirculating cooling water 

    E-Print Network [OSTI]

    Abdel-wahab, Ahmed Ibraheem Ali

    2004-09-30

    Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA...

  6. Removal of Chloride from Wastewater by Advanced Softening Process Using Electrochemically Generated Aluminum Hydroxide 

    E-Print Network [OSTI]

    Mustafa, Syed Faisal

    2014-07-23

    solubility. Chloride can be removed from water and wastewater by precipitation as calcium chloroaluminate using advanced softening process. This research was conducted to evaluate chloride removal using electrochemically generated aluminum hydroxide and lime...

  7. Soil stabilization using optimum quantity of calcium chloride with Class F fly ash 

    E-Print Network [OSTI]

    Choi, Hyung Jun

    2006-10-30

    On-going research at Texas A&M University indicated that soil stabilization using calcium chloride filter cake along with Class F fly ash generates high strength. Previous studies were conducted with samples containing calcium chloride filter cake...

  8. Potential Problems with Ethylene-Vinyl Acetate for Photovoltaic Packaging (Poster)

    SciTech Connect (OSTI)

    Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K, M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

    2006-05-01

    Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support electrical isolation, optical coupling, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about -15 C. Temperatures lower than this can be reached for extended periods of time in some climates. Due to increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL 1703.

  9. Transsinusoidal Portal Vein Embolization with Ethylene Vinyl Alcohol Copolymer (Onyx): A Feasibility Study in Pigs

    SciTech Connect (OSTI)

    Smits, Maarten L. J.; Vanlangenhove, Peter Sturm, Emiel J. C.; Bosch, Maurice A. A. J. van den; Hav, Monirath Praet, Marleen; Vente, Maarten A. D.; Snaps, Frederic R.; Defreyne, Luc

    2012-10-15

    Purpose: Portal vein embolization is performed to increase the future liver remnant before liver surgery in patients with liver malignancies. This study assesses the feasibility of a transsinusoidal approach for portal vein embolization (PVE) with the ethylene vinyl alcohol copolymer, Onyx. Methods: Indirect portography through contrast injection in the cranial mesenteric artery was performed in eight healthy pigs. Onyx was slowly injected through a microcatheter from a wedged position in the hepatic vein and advanced through the liver lobules into the portal system. The progression of Onyx was followed under fluoroscopy, and the extent of embolization was monitored by indirect portography. The pigs were euthanized immediately (n = 2), at 7 days (n = 4), or at 21 days postprocedure (n = 2). All pigs underwent necropsy and the ex vivo livers were grossly and histopathologically analyzed. Results: Transsinusoidal PVE was successfully performed in five of eight pigs (63%). In 14 of 21 injections (67%), a segmental portal vein could be filled completely. A mean of 1.6 liver lobes per pig was embolized (range 1-2 lobes). There were no periprocedural adverse events. Focal capsular scarring was visible on the surface of two resected livers, yet the capsules remained intact. Histopathological examination showed no signs of recanalization or abscess formation. Mild inflammatory reaction to Onyx was observed in the perivascular parenchyma. Conclusions: The porcine portal vein can be embolized through injection of Onyx from a wedged position in the hepatic vein. Possible complications of transsinusoidal PVE and the effect on contralateral hypertrophy need further study.

  10. Uranium chloride extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Pierce, R. Dean (Naperville, IL)

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800.degree. C. to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein.

  11. Uranium chloride extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

    1992-08-25

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800 C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein. 1 figure.

  12. ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL

    E-Print Network [OSTI]

    Mobley, David Paul

    2013-01-01

    Co. , "Zinc Halide Hydrocracking Process for Distillatewith Zinc Chloride", Hydrocracking u. S. Dept. of Interior

  13. Polarization and Charge Transfer in the Hydration of Chloride Ions

    E-Print Network [OSTI]

    Zhen Zhao; David M. Rogers; Thomas L. Beck

    2009-12-14

    A theoretical study of the structural and electronic properties of the chloride ion and water molecules in the first hydration shell is presented. The calculations are performed on an ensemble of configurations obtained from molecular dynamics simulations of a single chloride ion in bulk water. The simulations utilize the polarizable AMOEBA force field for trajectory generation, and MP2-level calculations are performed to examine the electronic structure properties of the ions and surrounding waters in the external field of more distant waters. The ChelpG method is employed to explore the effective charges and dipoles on the chloride ions and first-shell waters. The Quantum Theory of Atoms in Molecules (QTAIM) is further utilized to examine charge transfer from the anion to surrounding water molecules. From the QTAIM analysis, 0.2 elementary charges are transferred from the ion to the first-shell water molecules. The default AMOEBA model overestimates the average dipole moment magnitude of the ion compared with the estimated quantum mechanical value. The average magnitude of the dipole moment of the water molecules in the first shell treated at the MP2 level, with the more distant waters handled with an AMOEBA effective charge model, is 2.67 D. This value is close to the AMOEBA result for first-shell waters (2.72 D) and is slightly reduced from the bulk AMOEBA value (2.78 D). The magnitude of the dipole moment of the water molecules in the first solvation shell is most strongly affected by the local water-water interactions and hydrogen bonds with the second solvation shell, rather than by interactions with the ion.

  14. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

  15. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, M.A.; Pereira, C.

    1997-03-18

    A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  16. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, Michele A. (Naperville, IL); Pereira, Candido (Lisle, IL)

    1997-01-01

    A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  17. STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES

    E-Print Network [OSTI]

    Mc Vay, L.

    2011-01-01

    A. Attia, Development of zinc bromide batteries stationaryfrom zinc chloride and zinc bromide electrolytes, JES 130 (is reduced to bromide from the complex. The zinc that was

  18. Chloride improves fruit yield and quality of strawberry (Fragaria × ananassa Duch.)

    E-Print Network [OSTI]

    Bellof, Svenja; Schubert, Sven

    2009-01-01

    symptoms and tolerance of strawberry to salinity in theHomann 1988). Nevertheless, strawberry is characterized as aimproves the yield of strawberry. As an anion, chloride

  19. The effect of freezing on the sulfate-chloride and density-chloride ratios of sea-water 

    E-Print Network [OSTI]

    Burkhalter, Albert Charles

    1967-01-01

    AC AN~2QZZS LIST OF TABLES I. INTRODUCTION II. LITERATURE REVIEN III. STATEMENT OF PROBLEM IV. EXPER33KfiTAL TECRNIQUES V. D3:SCUSSION VI. CONCLUSION AND SUGGESI'IONS BIBLIOGRAPHY APPEHDIX 16 19 B6 LIST OF TABLES I. KARIlJH CHLORIDE...), This hypothesis was tested by Dittmar (1884) when he perform d extensive analyses on seventy seven sea- water samples collected from all oceans and all depths by the Challenger expedition. His findings led to the concept that the ratios of the various ions...

  20. Chloride-catalyzed corrosion of plutonium in glovebox atmospheres

    SciTech Connect (OSTI)

    Burgess, M. [ed.; Haschke, J.M.; Allen, T.H.; Morales, L.A.; Jarboe, D.M.; Puglisi, C.V.

    1998-04-01

    Characterization of glovebox atmospheres and the black reaction product formed on plutonium surfaces shows that the abnormally rapid corrosion of components in the fabrication line is consistent with a complex salt-catalyzed reaction involving gaseous hydrogen chloride (HCl) and water. Analytical data verify that chlorocarbon and HCl vapors are presented in stagnant glovebox atmospheres. Hydrogen chloride concentrations approach 7 ppm at some locations in the glovebox line. The black corrosion product is identified as plutonium monoxide monohydride (PuOH), a product formed by hydrolysis of plutonium in liquid water and salt solutions at room temperature. Plutonium trichloride (PuCl{sub 3}) produced by reaction of HCl at the metal surface is deliquescent and apparently forms a highly concentrated salt solution by absorbing moisture from the glovebox atmosphere. Rapid corrosion is attributed to the ensuing salt-catalyzed reaction between plutonium and water. Experimental results are discussed, possible involvement of hydrogen fluoride (HF) is examined, and methods of corrective action are presented in this report.

  1. Nonlinear optical properties of ZnO/poly (vinyl alcohol) nanocomposite films

    SciTech Connect (OSTI)

    Jeeju, P. P., E-mail: jeejupp@gmail.com [Department of Physics, S N M College, Maliankara, Ernakulam, Kerala (India); Jayalekshmi, S., E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi 682 022 (India); Chandrasekharan, K. [Department of Physics, National Institute of Technology, Calicut, Kerala (India)

    2014-01-28

    Extensive studies have already been reported on the optical characteristics of ZnO/polymer nanocomposite films, using a variety of polymers including transparent polymers such as polystyrene, polymethyl methacrylate etc and many interesting results have been established regarding the non linear optical characteristics of these systems. Poly (vinyl alcohol)(PVA) is a water soluble polymer. Though the structural and optical studies of ZnO/PVA nanocomposite films have already been investigated, there are no detailed reports on the nonlinear optical characteristics of ZnO/PVA nanocomposite films, irrespective of the fact that these nanocomposite films can be synthesized using quite easy and cost effective methods. The present work is an attempt to study in detail the nonlinear optical behaviour of ZnO/PVA nanocomposite films using Z-scan technique. Highly transparent ZnO/PVA nanocomposite films were prepared from the ZnO incorporated PVA solution in water using spin coating technique. The ZnO nanoparticles were synthesized by the simple chemical route at room temperature. High-resolution transmission electron microscopy studies show that the ZnO nanoparticles are of size around 10 nm. The ZnO/PVA nanocomposite films were structurally characterized by X-ray diffraction technique, from which the presence of both PVA and ZnO in the nanocomposite was established. The optical absorptive nonlinearity in the nanocomposite films was investigated using open aperture Z-scan technique. The results indicate optical limiting type nonlinearity in the films due to two photon absorption in ZnO with efficiency more than 50%. These films also show a self defocusing type negative nonlinear refraction in closed aperture Z-scan experiment. The present studies indicate that, highly transparent and homogeneous films of ZnO/PVA nanocomposite can be obtained on glass substrates using simple methods, in a highly cost effective way, since PVA is water soluble. These nanocomposite films offer prospects of application as efficient optical limiters to protect light sensitive devices from the possible damage on exposure to high intensity radiation.

  2. Development of a copper-catalyzed amidation-base-promoted cyclization sequence for the synthesis of 2-aryl- and 2-vinyl1-4 quinolones

    E-Print Network [OSTI]

    Jones, Carrie Preston

    2007-01-01

    A direct two-step method for the preparation of 2-aryl- and 2-vinyl-4-quinolones that utilizes a copper-catalyzed amidation of ortho-halophenones followed by a base-promoted Camps cyclization of the resulting N-(2-keto-aryl)amides ...

  3. Metal-Dinitrosyl Mediated Vinylic C-H Functionalization Chen Zhao, Mark R. Crimmin, F. Dean Toste and Robert G. Bergman

    E-Print Network [OSTI]

    Toste, Dean

    and Robert G. Bergman University of California ­ Berkeley, Berkeley, CA, 94720 Synthesis of RutheniumMetal-Dinitrosyl Mediated Vinylic C-H Functionalization Chen Zhao, Mark R. Crimmin, F. Dean Toste.; Bergman, R. G. Organometallics 1983, 2, 787. (b) Becker, P. N.; Bergman, R. G.; J. Am. Chem. Soc. 1983

  4. Two chloride sources in soils of the McMurdo Dry Valleys, Antarctica Huiming Bao,1

    E-Print Network [OSTI]

    Marchant, David R.

    of two major chloride sources, an airborne sea-salt chloride (SSC) with a d37 Cl value ! $0-ice-till interface at the bottom, differing distinctively from basal tills where there is no salt contribution from unraveling climate, tectonic, and landscape changes archived in MDV soil profiles. Citation: Bao, H., J. D

  5. Binary hard-sphere crystals with the cesium chloride structure A. B. Schofield

    E-Print Network [OSTI]

    Schofield, Andrew B.

    Binary hard-sphere crystals with the cesium chloride structure A. B. Schofield Department The possibility of binary hard-sphere colloids crystallizing with the cesium chloride CsCl structure was examined compressed exceeds the value, /3& 0.74, which applies to fully compressed one-component systems. For cesium

  6. Using Multiconformation Continuum Electrostatics to Compare Chloride Binding Motifs in -Amylase,

    E-Print Network [OSTI]

    Gunner, Marilyn

    Using Multiconformation Continuum Electrostatics to Compare Chloride Binding Motifs in -Amylase electrostatics (MCCE), we show that the changes of chloride binding to -amylase, human serum albumin (HSA) and Omp32 with pH, and of -amylase with mutation agree well with experimental data. The three proteins

  7. Hydrogen and chloride ions effects on the automobile interstitial-free steel corrosion

    E-Print Network [OSTI]

    Volinsky, Alex A.

    1 Hydrogen and chloride ions effects on the automobile interstitial-free steel corrosion L.Q. Guo 1 Abstract The effects of hydrogen and chloride ions on the corrosion behavior of interstitial-free steel and the corrosion potentials drop sharply. Under a given hydrogen charging current density, the drops of the pitting

  8. Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow

    E-Print Network [OSTI]

    Wang, Chao-Yang

    Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow W-dimensional model is developed to simulate discharge of a primary lithium/thionyl chloride battery. The model to the first task with important examples of lead-acid,1-3 nickel-metal hydride,4-8 and lithium-based batteries

  9. A Novel, Green Technology for the Production of Aromatic Thiol from Aromatic Sulfonyl Chloride 

    E-Print Network [OSTI]

    Atkinson, Bradley R.

    2010-01-16

    ....................................................................... 26 3.3 Palladium Catalyst Simulation ............................................................. 27 3.4 Adsorption of Aromatic Sulfonyl Chloride.......................................... 30 3.5 Adsorption of Other Reaction Species... ....................................................... 26 3-3 A diagram of each of the three palladium structures ........................ 30 3-4 The minimized structure of 2,5-dimethylbenzene sulfonyl chloride...

  10. Sergeant Sanders, V.C. of Leeds 

    E-Print Network [OSTI]

    Holroyd, C. W. [author

    2012-03-05

    LEED & GOBAS Commissioning in a LEED & GOBAS Evaluated Green BuildingEvaluated Green Building ??????YongningYongning ZhangZhangSchool of ArchitectureSchool of ArchitectureTsinghuaTsinghua UniversityUniversity November, 2006November, 2006 Commissioning... 44 LEEDLEED???? Evaluated by LEEDEvaluated by LEED ???????? ?????????????????????????????? ???????? To be certified as: Golden or Silver Level!To be certified as: Golden or Silver Level! ??? 811 ????? 17 ?Y ??? 1 ?????????? ?? Y ??? 2 ?????? ?? Y...

  11. COMET TA Floor Plan 100225.vc6

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &BradburyMay 1, 2013, 4:15pmEnergyNovember 12, 2015,and Night |

  12. Vitrification of Polyvinyl Chloride Waste from Korean Nuclear Power Plants

    SciTech Connect (OSTI)

    Sheng, Jiawei [Kyoto University (Japan); Choi, Kwansik [Nuclear Environment Technology Institute (Korea, Republic of); Yang, Kyung-Hwa [Nuclear Environment Technology Institute (Korea, Republic of); Lee, Myung-Chan [Nuclear Environment Technology Institute (Korea, Republic of); Song, Myung-Jae [Nuclear Environment Technology Institute (Korea, Republic of)

    2000-02-15

    Vitrification is considered as an economical and safe treatment technology for low-level radioactive waste (LLW) generated from nuclear power plants (NPPs). Korea is in the process of preparing for its first ever vitrification plant to handle LLW from its NPPs. Polyvinyl chloride (PVC) has the largest volume of dry active wastes and is the main waste stream to treat. Glass formulation development for PVC waste is the focus of study. The minimum additive waste stabilization approach has been utilized in vitrification. It was found that glasses can incorporate a high content of PVC ash (up to 50 wt%), which results in a large volume reduction. A glass frit, KEP-A, was developed to vitrify PVC waste after the optimization of waste loading, melt viscosity, melting temperature, and chemical durability. The KEP-A could satisfactorily vitrify PVC with a waste loading of 30 to 50 wt%. The PVC-frit was tolerant of variations in waste composition.

  13. Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method

    SciTech Connect (OSTI)

    Cooper, Clay A [DRI] [DRI; Hershey, Ronald L [DRI] [DRI; Healey, John M [DRI] [DRI; Lyles, Brad F [DRI] [DRI

    2013-07-01

    Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

  14. Induction of chloride secretory currents across mouse ileal tissues by rotavirus enterotoxic peptide in different age mice 

    E-Print Network [OSTI]

    Cox, Virginia Waters

    2002-01-01

    ) is enterotoxic and induces a chloride efflux across neonatal mouse intestinal mucosa. Chloride ion efflux across mucosal tissue is measured as an electrical current in Ussing chambers and is the predominant electrolyte driving fluid secretion. Until recently a...

  15. Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy

    E-Print Network [OSTI]

    Banerjee, Debjyoti

    chloride salt eutectics for solar thermal-energy storage applications Donghyun Shin, Debjyoti Banerjee December 2010 Keywords: Nanoparticle Specific heat capacity Alkali chloride eutectic Silicon dioxide

  16. Additive Screen HTTM -HR2-138 Scoring Sheet 1. (A1) 0.1 M Barium Chloride

    E-Print Network [OSTI]

    Hill, Chris

    9. (A9) 0.1 M Yttrium Chloride 10. (A10) 0.1 M Zinc Chloride 11. (A11) 0.1 M Ferric (III) Chloride. (C3) 0.1 M Phenol 28. (C4) 30% v/v Dimethyl Sulfoxide 29. (C5) 0.1 M Sodium Bromide 30. (C6) 30% w

  17. Laboratory Hazard Assessment Questionnaire EH&S is available to assist with the recognition, evaluation and control of laboratory hazards. This form is to be used to help evaluate possible hazards reported by members of

    E-Print Network [OSTI]

    Jia, Songtao

    Chloroform Chromium (VI) Ethylene oxide Formaldehyde Isoflurane Lead Mercury Acrylonitrile Crystalline silica Methyl methacrylate Methylene chloride Nitrous oxide Vinyl chloride Other Brief Description

  18. Chloride, bromide and iodide scintillators with europium doping

    DOE Patents [OSTI]

    Zhuravleva, Mariya; Yang, Kan

    2014-08-26

    A halide scintillator material is disclosed where the halide may comprise chloride, bromide or iodide. The material is single-crystalline and has a composition of the general formula ABX.sub.3 where A is an alkali, B is an alkali earth and X is a halide which general composition was investigated. In particular, crystals of the formula ACa.sub.1-yEu.sub.yI.sub.3 where A=K, Rb and Cs were formed as well as crystals of the formula CsA.sub.1-yEu.sub.yX.sub.3 (where A=Ca, Sr, Ba, or a combination thereof and X=Cl, Br or I or a combination thereof) with divalent Europium doping where 0.ltoreq.y.ltoreq.1, and more particularly Eu doping has been studied at one to ten mol %. The disclosed scintillator materials are suitable for making scintillation detectors used in applications such as medical imaging and homeland security.

  19. Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides

    E-Print Network [OSTI]

    Han, Chong

    An efficient palladium-catalyzed process has been developed for Negishi coupling of secondary alkylzinc halides with a wide range of aryl bromides and activated aryl chlorides. A palladium catalyst composed of a new ...

  20. Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides

    E-Print Network [OSTI]

    Biscoe, Mark R.

    Simple, efficient procedures for the monoarylation of acetate esters and aryl methyl ketones using aryl chlorides are presented. Previously, no general method was available to ensure the highly selective monoarylation of ...

  1. Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins

    E-Print Network [OSTI]

    Matsubara, Ryosuke

    Nickel-catalyzed intermolecular benzylation and heterobenzylation of unactivated alkenes to provide functionalized allylbenzene derivatives are described. A wide range of both the benzyl chloride and alkene coupling partners ...

  2. Rapid Conversion of Hindered Arylsulfonates to Alkyl Chlorides with Retention of Configuration

    E-Print Network [OSTI]

    Lepore, Salvatore D.

    Rapid Conversion of Hindered Arylsulfonates to Alkyl Chlorides with Retention of Configuration of highly efficient leaving groups containing chelating units capable of attracting incoming nucleophiles assisting leaving groups (NALGs) that contain a polyether unit (including macrocyclic) attached to the aryl

  3. Contribution of garbage burning to chloride and PM[subscript 2.5] in Mexico City

    E-Print Network [OSTI]

    Li, G.

    The contribution of garbage burning (GB) emissions to chloride and PM[subscript 2.5] in the Mexico City Metropolitan Area (MCMA) has been investigated for the period of 24 to 29 March during the MILAGRO-2006 campaign using ...

  4. Iron (III) Chloride doping of large-area chemical vapor deposition graphene

    E-Print Network [OSTI]

    Song, Yi, S.M. Massachusetts Institute of Technology

    2013-01-01

    Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

  5. Chloride and Lithium Transport in Large Arrays of Undisturbed Silt Loam and Sandy Loam Soil Columns

    E-Print Network [OSTI]

    Chloride and Lithium Transport in Large Arrays of Undisturbed Silt Loam and Sandy Loam Soil Columns al., 1998); and (iii) sloping lay- were extremely variable among columns. Lithium adsorption

  6. STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES

    E-Print Network [OSTI]

    Mc Vay, L.

    2011-01-01

    J. , Flow distribution in the zinc chloride battery, JES,ensures a con- The flow patterns in this battery were stant,and products. flow As a result the battery is separate from

  7. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

    1993-01-01

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  8. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-09-07

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  9. The effect of sodium chloride in the irrigation water on the growth of selected ornamental plants 

    E-Print Network [OSTI]

    Apps, Gary Edward

    1976-01-01

    THE EFFECT OF SODIUM CHLORIDE IN THE IRRIGATION WATER ON THE GROWTH OF SELECTED ORNAMENTAL PLANTS A Thesis by GARY EDWARD APPS Submitted to the Graduate College of Texas A6M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1976 Major Subject: Floriculture THE EFFECT OF SODIUM CHLORIDE IN THE IRRIGATION WATER ON THE GROWTH OF SELECTED ORNAMENTAL PLANTS A Thesis by GARY EDWARD APPS Approved as to style and content by: (Chairman of Committee...

  10. Dissolution testing of a metallic waste form in chloride brine

    SciTech Connect (OSTI)

    Dawn E Janney

    2006-11-01

    This paper is intended for publication in the peer-reviewed proceedings from the Scientific Basis for Nuclear Waste Management (at the Fall 2006 meeting of the Materials Research Society). The same material was presented in a 15-minute talk. Argonne National Laboratory has developed an electrometallurgical process for conditioning spent sodium-bonded metallic reactor fuel from the Experimental Breeder Reactor II (EBR-II). One waste stream from this process consists of a metal waste form (MWF) whose baseline composition is stainless steel alloyed with 15 wt% Zr (SS-15Zr) and whose microstructure is a eutectic intergrowth of iron solid solutions and Fe-Zr-Cr-Ni intermetallics. This paper reports scanning electron microscope (SEM) observations of corrosion products formed during static immersion tests in which coupons of surrogate MWF containing 10 wt% U (SS-15Zr-10U) were immersed in solutions with nominal pH values of 3 and 4 and 1000 ppm added chloride for 70 days at 50 °C. Although the majority of the surface areas of the coupons appear unchanged, linear areas with localized corrosion products apparently consisting of porous materials overlying corrosion-product-filled channels formed on both coupons, cross-cutting phase boundaries in the original eutectic microstructures. Many of the linear areas intersected the sample edge at notches present before the tests or followed linear flaws visible in pre-test images. Compositions of corrosion products differed significantly from the bulk composition, and the maximum observed concentration of U in corrosion products (~25 at%) slightly exceeded the highest reported values in actinide-bearing phases in uncorroded surrogate MWF samples with comparable concentrations of U (~17-19 at%).

  11. Respiratory symptoms among glass bottle makers exposed to stannic chloride solution and other potentially hazardous substances

    SciTech Connect (OSTI)

    Levy, B.S.; Davis, F.; Johnson, B.

    1985-04-01

    Concern about upper respiratory tract irritation and other symptoms among workers at a glass bottle manufacturing plant led to an epidemiologic and an industrial hygiene survey. Questionnaire responses from 35 hot end and 53 cold end workers indicated that the incidence of wheezing, chest pain, dyspnea on exertion, and cough was significantly elevated among hot end workers. Among both smokers and nonsmokers, hot end workers reported higher, but not significantly higher, rates of wheezing and chest pain. Among smokers, hot end workers reported significantly higher rates of dyspnea on exertion and cough than did cold end workers. Data suggest that reported exposure to stannic chloride solution likely caused these symptoms. The industrial hygiene survey, conducted when stannic chloride use had been reduced, cleaning had been done, and ventilation improved, focused on measuring air contaminants that might possibly cause symptoms. Levels of hydrogen chloride, which apparently was formed by the combination of stannic chloride and water in the presence of heat, were elevated. The finding of increased prevalence of respiratory symptoms among hot end workers was consistent with this exposure. Recommendations were made to reduce hazardous exposures at this plant. Individuals responsible for occupational health should be aware that relatively benign substances, such as stannic chloride and water, can combine spontaneously to form hazardous substances.

  12. Experiences with combined corrosion effects on stainless steel due to chlorides and H{sub 2}S

    SciTech Connect (OSTI)

    Russell, M.T.; Wortham, G.M.; Lawson, D.M.

    1999-07-01

    Chloride contamination of amines in contact with stainless steel creates a well known potential for stress corrosion cracking (SCC). A far less recognized hazard of chloride contamination, when sulfides are present, is drastically accelerated generalized corrosion. Chloride induced corrosion can be avoided with an inlet gas reverse flow coalescer and an inlet slug catcher to knock out brine bearing produced water. If the amine is already contaminated with chlorides, steps can be taken to minimize this type of corrosion such as better amine filtration, amine reclamation and using stainless steel with higher nickel contents.

  13. Reactive Surfaces and Interfaces utilizing 2-Vinyl-4,4-Dimethylazlactone (VDMA): An Example of ??Click?? Chemistry

    SciTech Connect (OSTI)

    Messman, Jamie M; Kilbey, II, S Michael; Lokitz, Bradley S; Hinestrosa Salazar, Juan Pablo; Ankner, John Francis

    2009-01-01

    Creating polymer-modified interfaces decorated with biologically-relevant materials V so-called bio-interfaces V with precise control over the nanoscale structure and properties is of increasing technological importance for a large number of advanced materials applications, including adaptive and/or lubricious biomaterial coatings, electro-actuators (synthetic muscles), biosensors with amplified response, coatings for stealth drug delivery, supports for enzymatic catalysts, protein or antibody arrays, and high affinity separation agents. The ability to design and decorate interfaces with biologically-relevant molecules and understand synthesis-structure-function relationships remains a significant challenge. The overarching objective of this research program is to investigate the polymerization and functionalization of a new class of polymeric materials that are capable of serving as a versatile platform from which bio-interfaces for specific applications can be created and evaluated. Stimuli-responsive (co)polymers containing vinyl dimethyl azlactone (VDMA) have been prepared using free radical polymerization techniques (controlled and conventional). Subsequent immobilization of biomolecules (e.g., dansylcadaverine, N ,N -bis(carboxymethyl)-L-lysine hydrate) on PVDMA-containing surface scaffolds affords bio-interfaces. Reaction of nucleophiles with the azlactone moiety proceeds rapidly, quantitatively, and in the absence of byproducts, which are essential criteria governing the click-type nature of this procedure. The conversion of these materials into polyelectrolytes and bioconjugates can be monitored in real-time using infrared spectroscopy. Additionally, pVDMA polymers prepared using reversible addition fragmentation chain transfer (RAFT) polymerization are the basis for creating polymer brushes by a grafting to approach. We will describe how compositional differences and changes in molecular weight affect the solubility and responsiveness of pVDMA-based polymers and surface layers when functionalized with various biomolecules.

  14. Safety evaluation for packaging (onsite) for cesium chloride capsules with type W overpacks

    SciTech Connect (OSTI)

    McCoy, J.C.

    1997-09-15

    This Safety Evaluation for Packaging (SEP) documents the evaluation of a new basket design and overpacked cesium chloride capsule payload for the Beneficial Uses Shipping System (BUSS) Cask in accordance with the onsite transportation requirements of the Hazardous Material Packaging and Shipping manual, WHC-CM-2-14. This design supports the one-time onsite shipment of 16 cesium chloride capsules with Type W overpacks from the 324 Building to the 224T Building at the Waste Encapsulation and Storage Facility (WESF). The SEP is valid for a one-time onsite shipment or until August 1, 1998, whichever occurs first.

  15. The influence of chloride ions on the corrosion of copper in soil 

    E-Print Network [OSTI]

    Hirani, Raju K

    1980-01-01

    THE INFLUENCE OF CHLORIDE IONS ON THE CORROSION OF COPPER IN SOIL A Thesis by RA JU K . H I RAN I Submitted to the Graduate College of Texas ASM University in Partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May... 1980 Major Subject: Chemical Engineering THE INFLUENCE OF CHLORIDE IONS ON THE CORROSION OF COPPER IN SOIL A Thesis by RAJU K. HIRANI Approved as to style and content by: (Chairman of Committee) '(2. (Member ) (Member) (Member) ( ea o Dep...

  16. Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene

    SciTech Connect (OSTI)

    Ajayi, O. A. E-mail: cww2104@columbia.edu; Wong, C. W. E-mail: cww2104@columbia.edu; Anderson, N. C.; Wolcott, A.; Owen, J. S.; Cotlet, M.; Petrone, N.; Hone, J.; Gu, T.; Gesuele, F.

    2014-04-28

    We examine the time-resolved resonance energy transfer of excitons from single n-butyl amine-bound, chloride-terminated nanocrystals to two-dimensional graphene through time-correlated single photon counting. The radiative biexponential lifetime kinetics and blinking statistics of the individual surface-modified nanocrystal elucidate the non-radiative decay channels. Blinking modification as well as a 4× reduction in spontaneous emission were observed with the short chloride and n-butylamine ligands, probing the energy transfer pathways for the development of graphene-nanocrystal nanophotonic devices.

  17. Deformation by dissolution and plastic flow of a single crystal sodium chloride indenter: An experimental study under the confocal

    E-Print Network [OSTI]

    Einat, Aharonov

    Deformation by dissolution and plastic flow of a single crystal sodium chloride indenter. H. Scholz (2008), Deformation by dissolution and plastic flow of a single crystal sodium chloride is undercutting dissolution that reduces the area of the contact, and the second is probably plastic flow

  18. Polyaluminum chloride with high Al30 content as removal agent for arsenic-contaminated well water

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Polyaluminum chloride with high Al30 content as removal agent for arsenic-contaminated well water-established coagulant in water treatment with high removal efficiency for arsenic. A high content of Al30 nanoclusters¨ berlandstrasse 133, 8600 Du¨bendorf, Switzerland c Water Research Institute (IRSA), National Research Council

  19. Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts

    E-Print Network [OSTI]

    Bao, Xinhe

    are not commercialized yet. Current industrial technologies for the production of chemicals from methane are mainly basedAcetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts Yafang Fan Æ attracted much attention as a potential route to obtain chemicals. Methane, the main component of natural

  20. LOW TEMPERATURE OPTICAL STUDY OF MANGANOUS CHLORIDE M. REGIS and Y. FARGE

    E-Print Network [OSTI]

    Boyer, Edmond

    that, in a lot of transparent magnetic materials, the behaviour of the optical spectrum is related of metal atoms are separated by two layers of chlorine atoms. The crystal field D3d on the manganese ions627 LOW TEMPERATURE OPTICAL STUDY OF MANGANOUS CHLORIDE M. REGIS and Y. FARGE Laboratoire de

  1. The rate of hydrolysis of benzoyl chloride as a function of water concentration in acetone 

    E-Print Network [OSTI]

    Kelly, Minton Jones

    1956-01-01

    proposed that uses potassium chloride salt and a high-Z metal to create a two-point calibration for a sodium iodide field gamma spectroscopy instrument. The calibration source was designed in collaboration with Sandia National Laboratory using the Monte...

  2. Insertion of a Two-Dimensional Iron-Chloride Network between Perovskite Blocks. Synthesis and

    E-Print Network [OSTI]

    Spinu, Leonard

    Insertion of a Two-Dimensional Iron-Chloride Network between Perovskite Blocks. Synthesis between the perovskite blocks of a double-layered Dion-Jacobson compound. The product, (FeCl)- LaNb2O7, contains iron coordinated by two apical oxygens from the perovskite layer and four in-plane chlorines

  3. Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride

    E-Print Network [OSTI]

    Mulholland, James A.

    Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride Jae-Yong Ryu, James limited in- vestigation of dibenzo-p-dioxin (DD) chlorination by CuCl2 to form chlorinated DD (CDD 2003 Elsevier Science Ltd. All rights reserved. Keywords: Dibenzofuran; Dibenzo-p-dioxin; CDF; CDD

  4. Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration Devices

    E-Print Network [OSTI]

    Clark, Shirley E.

    Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration in stormwater runoff and a decrease in groundwater recharge. Stormwater runoff contains pollutants (nutrients to the degradation of surface waters below stormwater pipe outfalls. Infiltrating stormwater has been shown

  5. The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride Environments

    E-Print Network [OSTI]

    The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride described in this report details our progress on the beryllium surveillance project during the 1996 fiscal year. Our goals for FY '96 were two-fold: 1) develop a sensor for monitoring the corrosion of beryllium

  6. Growing season methyl bromide and methyl chloride fluxes at a sub-arctic wetland in Sweden 

    E-Print Network [OSTI]

    Hardacre, Catherine J.; Blei, Emanuel; Heal, Mathew R

    2009-01-01

    Methyl bromide and methyl chloride fluxes were measured at several sites in a sub-arctic wetland near Abisko, Sweden (68°28?N 18°49?E) throughout the 2008 growing season. Averaged over 92 flux measurements the sub-arctic ...

  7. Branchial and renal pathology in the fish exposed chronically to methoxy ethyl mercuric chloride

    SciTech Connect (OSTI)

    Gill, T.S.; Pant, J.C.; Tewari, H.

    1988-08-01

    Pathological manifestations causally related to pesticide poisoning have been described in both surficial and internal tissues of the fishes. Among the various organomercurials are phenyl mercuric acetate, methyl mercuric dicyanidiamide, methoxy ethyl mercuric chloride, methoxy ethyl mercuric silicate etc. Of these, the methoxy ethyl mercuric chloride (MEMC) is used in agriculture as an antifungal seed dressing, and its toxicity is primarily manifest in the Hg/sup 2 +/ ion. This report describes pathogenesis of branchial and renal lesions in the common freshwater fish, Puntius conchonius exposed chronically to sublethal levels of MEMC. Prior to this, alterations in the peripheral blood and metabolite levels in response to experimental MEMC poisoning have been demonstrated in this species.

  8. Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides

    SciTech Connect (OSTI)

    Haas, P.A.; Lee, D.D.; Mailen, J.C.

    1991-11-01

    The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

  9. Speciation of aqueous palladium(II) chloride solutions using optical spectroscopies

    SciTech Connect (OSTI)

    Tait, C.D.; Janecky, D.R.; Rogers, P.S.Z. (Los Alamos National Lab., NM (United States))

    1991-05-01

    Spectroscopic measurements of palladium(II) chloride solutions have been performed under ambient to elevated temperature conditions with systematic changes in pH and (Cl{sup {minus}}). Spectral signatures from electronic absorption spectra (Uv/Vis) and Raman vibrational spectra were determined, and these were subsequently used to systematically map out species along several paths of the predominance diagram. The species PdCl{sub x}(H{sub 2}O){sub 4{minus}x}{sup 2{minus}x} (x = 2, 3, or 4) and Pd(OH){sub 2} were observed, along with a precipitation product formed from > 10 {mu}M (Pd{sup 2+}) solutions under near-neutral conditions. The elemental composition of the precipitation product was examined with a scanning electron micrograph (SEM) and was found to contain chloride as well as palladium. While sub-stoichiometric amounts of available OH{sup {minus}} ligand produced UV/Vis solution spectra likely to be from mixed Pd-Cl-OH species, the pH field of these species would be vanishingly small at low, geologically relevant palladium ion concentrations where (OH{sup {minus}}) is no longer the limiting reagent in the transformation. In mildly acidic media, where chloropalladium(II) species predominate, elevated temperatures (up to 90C) cause lower charged palladium-chloride species to be favored, consistent with the lowered dielectric constant of water at higher temperatures.

  10. The Effects of Temperature on the Electrochemical Performance of Sodium-Nickel Chloride Batteries

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

    2012-10-01

    The sodium-nickel chloride (ZEBRA) battery is typically fabricated with a thick tubular ?"-alumina solid electrolyte (BASE) and operated at relatively high temperatures (? 300ºC) to achieve adequate electrochemical performance. In the present work, a planar-type sodium-nickel chloride battery possessing a thin BASE (~600 ?m thick) was tested in order to evaluate the feasibility of the battery operation at low temperatures (?200°C). Electrochemical test results revealed that the battery was able to be cycled at C/3 rate at as low as 175°C despite the higher cell polarization at the reduced temperature. Overall, low operating temperature resulted in a considerable improvement in the stability of cell performance. Cell degradation was negligible at 175°C, while 55% increase in end-of-charge polarization was observed at 280°C after 60 cycles. SEM analysis indicated that the performance degradation at higher temperatures was related to the particle growth of both nickel and sodium chloride in the cathode. The cells tested at lower temperatures (e.g., 175 and 200°C), however, exhibited a sharp drop in cell voltage at the end of discharge due to the diffusion limitation, possibly caused by the limited ionic conductivity of NaAlCl4 melt or the poor wettability of sodium on the BASE. Therefore, improvements in the ionic conductivity of a secondary electrolyte and sodium wetting are desirable to further enhance the battery performance at low temperatures.

  11. Effect of different ratios of sodium to chloride using isokalemic diets for growing and finishing swine raised during hot weather 

    E-Print Network [OSTI]

    Serna-Saldivar, Sergio Othon

    1982-01-01

    ABSTBXCT Effect of Different Ratios of Sodium to Chloride Using Isokalemic Diets for Growing and Pinishing Swine Raised During Hot Weather {Bay 1982) Sergio Othon Serna-Saldivar B. S, Inn tituto Tecnologico y de Estudios Superiores de monterrey...

  12. Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Triflates with Sodium Cyanate: A Practical Synthesis of Unsymmetrical Ureas

    E-Print Network [OSTI]

    Fors, Brett P.

    An efficient method for palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate is reported. The protocol allows for the synthesis of unsymmetrical N,N?-di- and N,N,N?-trisubstituted ureas ...

  13. The effect of competition by chloride and sulfate anions on the adsorption of arsenate ion onto activated alumina 

    E-Print Network [OSTI]

    Janis, Patrick John

    2000-01-01

    Interactions of arsenate ions with sulfate and chloride anions in aqueous solutions containing various amounts of activated alumina were studied in the laboratory on a batch mode basis with the goal of understanding the competition of the anions...

  14. Periadolescent oral manganese exposure affects conditioned place preference by cocaine and conditioned place aversion by lithium chloride in rats 

    E-Print Network [OSTI]

    Lee, Samuel Ming Hin

    2013-02-22

    Manganese neurotoxicity compromises basal ganglia functions that could affect the limbic system and drug sensitivity. Male rats were orally exposed to manganese chloride (0, 100, 200 mg/kg/day Mn) for 15 days starting at postnatal day (PND) 28...

  15. Nickel-catalyzed asymmetric cross-couplings of secondary allylic chlorides and planar-chiral compounds in asymmetric synthesis

    E-Print Network [OSTI]

    Son, Sunghee

    2008-01-01

    In Part I, nickel-catalyzed asymmetric carbon-carbon bond-forming reactions are described. A nickel/Pybox system effectively catalyzes regio- and enantioselective cross-couplings between racemic secondary allylic chlorides ...

  16. Systems and methods for solar cells with CIS and CIGS films made by reacting evaporated copper chlorides with selenium

    DOE Patents [OSTI]

    Albin, David S.; Noufi, Rommel

    2015-06-09

    Systems and methods for solar cells with CIS and CIGS films made by reacting evaporated copper chlorides with selenium are provided. In one embodiment, a method for fabricating a thin film device comprises: providing a semiconductor film comprising indium (In) and selenium (Se) upon a substrate; heating the substrate and the semiconductor film to a desired temperature; and performing a mass transport through vapor transport of a copper chloride vapor and se vapor to the semiconductor film within a reaction chamber.

  17. Generalized chloride mass balance: Forward and inverse solutions for one-dimensional tracer convection under transient flux

    SciTech Connect (OSTI)

    Ginn, T.R.; Murphy, E.M.

    1996-12-01

    Forward and inverse solutions are provided for analysis of inert tracer profiles resulting from one-dimensional convective transport under fluxes which vary with time and space separately. The developments are displayed as an extension of conventional chloride mass balance (CMB) techniques to account for transient as well as space-dependent water fluxes. The conventional chloride mass balance has been used over two decades to estimate recharge over large time scales in arid environments. In this mass balance approach, the chloride concentration in the pore water, originating from atmospheric fallout, is inversely proportional to the flux of water through the sediments. The CMB method is especially applicable to arid and semi-arid regions where evapotranspirative enrichment of the pore water produces a distinct chloride profile in the unsaturated zone. The solutions presented allow incorporation of transient fluxes and boundary conditions in CMB analysis, and allow analysis of tracer profile data which is not constant with depth below extraction zone in terms of a rational water transport model. A closed-form inverse solution is derived which shows uniqueness of model parameter and boundary condition (including paleoprecipitation) estimation, for the specified flow model. Recent expressions of the conventional chloride mass balance technique are derived from the general model presented here; the conventional CMB is shown to be fully compatible with this transient flow model and it requires the steady-state assumption on chloride mass deposition only (and not on water fluxes or boundary conditions). The solutions and results are demonstrated on chloride profile data from west central New Mexico.

  18. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    SciTech Connect (OSTI)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations. Previously developed isohyetal maps were utilized to determine the mean and standard deviation of precipitation within the area. A digital elevation model was obtained to provide elevation information. A geologic model was obtained to provide the spatial distribution of alluvial formations. Both were used to define the lower limit of recharge. In addition, 40 boreholes located in alluvial sediments were drilled and sampled in an attempt to support the argument that the areal distribution of alluvial sediments can be used to define a zone of negligible recharge. The data were compiled in a geographic information system and used in a Monte Carlo analysis to determine recharge occurring within the study area. Results of the analysis yielded estimates of the mean and standard deviation of recharge occurring within the study area (28.168 x 10{sup 6} m{sup 3} yr{sup -1} and 7.008 x 10{sup 6} m{sup 3} yr{sup -1}, and 26.838 x 10{sup 6} m{sup 3} yr{sup -1} and 6.928 x 10{sup 6} m{sup 3} yr{sup -1}) for two sets of simulations using alternate definitions of the lower limit of recharge. A sensitivity analysis determined the recharge estimates were most sensitive to uncertainty associated with the chloride concentration of the spring discharge. The second most sensitive parameter was the uncertainty associated with the mean precipitation within the recharge areas. Comparison of the analysis to previously published estimates of recharge revealed mixed results with the recharge estimates derived during the course of this project generally greater relative to previously published estimates.

  19. Loading effects of sodium chloride solutions on the high frequency titrimeter 

    E-Print Network [OSTI]

    Miller, Benjamin Peter

    1952-01-01

    Solution to 60 ml, M. stilled 1@ter in a 25 naa? Tuhs XX+ Xoadin, , Response to ~ Volumes of Bodiura Chio ride Solutions XXX(a), ~~ Rsaoonas to Sodiun Chloride Solutions in a XXX(h)s Aotivi "y i'uuotioua n' audio"~ ~florida l(a) ~ Loading Carve...!It ie fsd thrown this astor onposed to Rl A C3 Cl C4 C', J. I2 Fi. , I;g c Valses of Circuit Camponants Clq Og 100 mnfd, snrinhle oondsnssr 75 mafd. ~ conden~ C~ C5 0, 01 mfd, mioa aonkmser 100sSR ohm resistor 750 ohm resistor Q ~ R5 10...

  20. Effect of nonlinear absorption on electric field applied lead chloride by Z-scan technique

    SciTech Connect (OSTI)

    Rejeena, I. [International School of Photonics, Cochin University of Science and Technology, Cochin Kerala, India and M.S.M. College, Kayamkulam, Kerala (India); Lillibai,; Nampoori, V. P. N.; Radhakrishnan, P. [International School of Photonics, Cochin University of Science and Technology, Cochin Kerala (India); Rahimkutty, M. H. [M.S.M. College, Kayamkulam, Kerala (India)

    2014-10-15

    The preparation, spectral response and optical nonlinearity of gel grown lead chloride single crystals subjected to electric field of 20V using parallel plate arrangements have been investigated. Optical band gap of the samples were determined using linear absorption spectra. Open aperture z-scan was employed for the determination of nonlinear absorption coefficient of PbCl{sub 2} solution. The normalized transmittance curve exhibits a valley shows reverse saturable absorption. The non linear absorption at different input fluences were recorded using a single Gaussian laser beam in tight focus geometry. The RSA nature of the sample makes it suitable for optical limiting applications.

  1. Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene. 

    E-Print Network [OSTI]

    Scoggins, Lacey E

    1959-01-01

    - alkyl and polyalkyl derivatives. The percentage yield, of monoalkyl derivatives is dependent upon the alcohol, dehydrating agent and. the activation of the aromatic nuclei Anhydrous ferric and alusdnum chloride, hydrogen fluoride with phosphorous...-butyl alcohol with 'benzene in the presence of i'erric chloride and. a 5g yield using aluminum chloride under the same conditions. Simons and. Archer5 reacted t-butyl alcohol with 'benzene using hydrogen fluoride as an alkylation catalyst, obtaining 4Q...

  2. The effects of a stannous chloride-based remediation system in a mercury contaminated stream

    SciTech Connect (OSTI)

    Mathews, Teresa J [ORNL; Looney, Brian [Savannah River National Laboratory (SRNL); BryanJr., Larry [Savannah River Ecology Laboratory; Smith, John G [ORNL; Miller, Carrie L [ORNL; Peterson, Mark J [ORNL

    2015-01-01

    Remediation of mercury (Hg)-contaminated watersheds is often challenging because of the complex nature of Hg biogeochemistry. Stream ecosystems have been shown to be particularly susceptible to Hg contamination and bioaccumulation in fish. Decreasing total Hg loading to stream systems, however, has shown variable performance in decreasing Hg concentrations in fish tissues. In this study, we assess the impacts of an innovative treatment system in reducing releases of Hg to a small stream system in the southeastern United States. The treatment system, installed in 2007, removes Hg from water using tin (Sn) (II) chloride followed by air stripping. Mercury concentrations in the receiving stream, Tims Branch, decreased from > 100 to ~10 ng/L in the four years following treatment, and Hg body burdens in redfin pickerel (Esox americanus) decreased by 70 % at the most contaminated site. Tin concentrations in water and fish increased significantly in the tributary leading to Tims Branch, but concentrations remain below levels of concern for human health or ecological risks. While other studies have shown that Sn may be environmentally methylated and methyltin can transfer its methyl group to Hg, results from our field studies and sediment incubation experiments suggest that the added Sn to the Tims Branch watershed is not contributing to MeHg production and bioaccumulation. The stannous chloride treatment system installed at Tims Branch was effective at removing Hg inputs and reducing Hg bioaccumulation in the stream with minimal impacts on the environment due to the increased Sn in the system.

  3. Crystal growth, structure and characterizations of a new semiorganic nonlinear optical material-{beta}-Alanine zinc chloride

    SciTech Connect (OSTI)

    Anbuchezhiyan, M. [Department of Physics, Valliammai Engineering College, S.R.M. Nagar, Kattankulathur, Chennai 603203 (India)] [Department of Physics, Valliammai Engineering College, S.R.M. Nagar, Kattankulathur, Chennai 603203 (India); Ponnusamy, S., E-mail: suruponnus@gmail.com [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India); Muthamizhchelvan, C. [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India)] [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India); Sivakumar, K. [Department of Physics, Anna University, Chennai 600 025 (India)] [Department of Physics, Anna University, Chennai 600 025 (India)

    2010-08-15

    The title compound, {beta}-alanine zinc chloride-a new semiorganic nonlinear optical crystal was grown by slow evaporation technique. Single crystals of {beta}-alanine zinc chloride have been subjected to X-ray diffraction analysis to determine the crystal structure. The powder X-ray diffractogram of the crystal has also been recorded. The amount of carbon, nitrogen and hydrogen in the crystals was also estimated. Fourier Transform Infrared and Raman spectral measurements have been carried out on the grown crystals in order to identify the functional groups. The presence of hydrogen and carbon in the {beta}-alanine zinc chloride was confirmed by using proton and carbon nuclear magnetic resonance spectral analyses. The percentage of zinc in the crystal was determined by atomic absorption spectroscopy. Optical behavior such as ultraviolet-vis-near infrared transmittance spectrum and second harmonic generation has been investigated. The mechanical strength and thermal behavior of the grown crystal have been analyzed.

  4. Synergistic extraction of trivalent lanthanides and actinides from acidic chloride media by tetra(n-octyl)diglycolamide

    SciTech Connect (OSTI)

    McAlister, D.R.; Horwitz, E. Philip

    2008-07-01

    Ferric chloride has been found to induce a significant synergistic enhancement of the extraction of trivalent lanthanides and actinides by tetra(n-octyl)diglycolamide (TODGA) from acidic chloride media. In this manuscript, results of a thorough investigation of the TODGA-HCl-Fe(III) system using solvent-extraction experiments designed to elucidate the stoichiometry of the synergistic species will be described. Results for Ac(III), Am(III), Eu(III), Pm(III), Y(III), Th(IV), Pu(IV), and U(VI) will be discussed. (authors)

  5. Effect of calcium chloride on pH and availability of zinc and phosphorus in three calcareous soils 

    E-Print Network [OSTI]

    Podisuk, Varangkana

    1976-01-01

    for the degree of MASTER OF SCIENCE May l976 Major Subject: Soil Chemistry EFFECT OF CALCIUM CHLORIDE ON pH AND AVAILABILITY OF ZINC AND PHOSPHORUS IN THREE CALCAREOUS SOILS A Thesis by Varangkana Podisuk Approved as to style and content by: (Chairman... of Committee) (Head of Department) (Member) (Member) May 1976 ABSTRACT Effect of Calcium Chloride on pH and Availability of Zinc and Phosphorus in Three Calcareous Soils (Nay 1976) Varangkana Podisuk, B. S. , Kasetsart University; Chairman of Advisory...

  6. Initial results from VC-1, First Continental Scientific Drilling...

    Open Energy Info (EERE)

    precaldera volcaniclastic breccia, and 523 m of Paleozoic carbonates, sandstones, and shales. A previously unknown obsidian flow was encountered at 160 m depth underlying the...

  7. Altered Tectonic and Hydrothermal Breccias in Corehole VC-1,...

    Open Energy Info (EERE)

    origin. Hydrothermal breccias and associated crackle zones or stockworks created by hydraulic fracturing can provide significant secondary permeability, as demonstrated by...

  8. Initial results from VC-1, First Continental Scientific Drilling Program

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13 (Vt.Infinifuel Biodieself rIngos PresovCore Hole in

  9. Altered Tectonic and Hydrothermal Breccias in Corehole VC-1, Valles

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen5All HomeAlphakat GmbH JumpAlsoAltamount

  10. Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System

    SciTech Connect (OSTI)

    Yongchun Tang; John Ma

    2012-03-23

    The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

  11. A New Redox Flow Battery Using Fe/V Redox Couples in Chloride Supporting Electrolyte

    SciTech Connect (OSTI)

    Wang, Wei; Kim, Soowhan; Chen, Baowei; Nie, Zimin; Zhang, Jianlu; Xia, Guanguang; Li, Liyu; Yang, Zhenguo

    2011-08-22

    A new redox flow battery using Fe2+/Fe3+ and V2+/V3+ redox couples in chloride supporting electrolyte was proposed and investigated for potential stationary energy storage applications. The Fe/V redox flow cell using mixed reactant solutions operated within a voltage window of 0.5-1.35 V with a nearly 100% utilization ratio and demonstrated stable cycling with energy efficiency around 80% at room temperature. Compared with Fe/Cr redox flow battery operating at an elevated temperature of 65 C, the necessity of external heat management is eliminated. Similar performance was also achieved using low-cost hydrocarbon-based ion exchange membranes, which allow for further cost reduction. The improved room temperature electrochemical performance makes the Fe/V redox flow battery a promising option as stationary energy storage device to enable renewable integration and stabilization of electrical grid.

  12. Calcium chloride electron injection/extraction layers in organic electronic devices

    SciTech Connect (OSTI)

    Qu, Bo, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn; Gao, Zhi; Yang, Hongsheng; Xiao, Lixin; Chen, Zhijian; Gong, Qihuang, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China)

    2014-01-27

    Nontoxic calcium chloride (CaCl{sub 2}) was introduced into organic electronic devices as cathode buffer layer (CBL). The turn-on voltage and maximum luminance of organic light-emitting diode (OLED) with 1.5?nm CaCl{sub 2} was 3.5?V and 21 960?cd/m{sup 2}, respectively. OLED with 1.5?nm CaCl{sub 2} possessed comparable electroluminescent characteristics to that of the commonly used LiF. Moreover, the performance of the organic photovoltaic device with 0.5?nm CaCl{sub 2} was comparable to that of the control device with LiF. Therefore, CaCl{sub 2} has the potential to be used as the CBL for organic electronic devices.

  13. Recovery of the actinides by electrochemical methods in molten chlorides using solid aluminium cathode

    SciTech Connect (OSTI)

    Malmbeck, R.; Mendes, E.; Serp, J.; Soucek, P.; Glatz, J.P. [European Commission, JRC, Institute for Transuranium Elements, Postfach 2340, 76125 Karlsruhe (Germany); Cassayre, L. [Laboratoire de Genie Chimique - LGC, Universite Paul Sabatier, UMR 5503, 118 route de Narbonne, 31062 Toulouse Cedex 04 (France)

    2007-07-01

    An electrorefining process in molten chloride salts is being developed at ITU to reprocess the spent nuclear fuel. According to the thermochemical properties of the system, aluminium is the most promising electrode material for the separation of actinides (An) from lanthanides (Ln). The actinides are selectively reduced from the fission products and stabilized by the formation of solid and compact actinide-aluminium alloys with the reactive cathode material. In this work, the maximum loading of aluminium with actinides was investigated by potentiostatic and galvano-static electrorefining of U-Pu- Zr alloys. A very high aluminium capacity was achieved, as the average loading was 1.6 g of U and Pu into 1 g of aluminium and the maximum achieved loading was 2.3 g. For recovery of the actinides from aluminium, a process based on chlorination and a subsequent sublimation of AlCl{sub 3} is proposed. (authors)

  14. Heat Flow in VC-2A and VC-2B, and Constraints on the Thermal Regime of the

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to: navigation, search Equivalent|Corn ProductsAtValles

  15. Substitutes for methylene chloride paint strippers -- performance evaluation and adaptation to aircraft maintenance procedures

    SciTech Connect (OSTI)

    Baker, G.E.; Hollins, E.F.

    1997-12-31

    The US Air Force is conducting a focused review of alternative solvents for use in depainting aircraft. This effort is to provide a replacement for methylene chloride, which is a suspected carcinogen, a listed hazardous air pollutant, presents a serious workplace hazard, and is nearly eliminated from use as a paint stripper by the Aerospace Rule of the National Emissions Standards for Hazardous Air Pollutants. An evaluation of available alternatives was conducted through a background and literature search, laboratory analytical work on a subset of alternative candidates, and actual field testing of alternative solvents on removable components of KC-135 aircraft at Tinker AFB, OK. The literature search and lab analyses resulted in a recommendation for field testing of seven alternative products; one of these emerged as superior in removal power testing and was recommended for full scale prototype testing on a KC-135. The entire effort was conducted to identify and test alternatives for use on polyurethane topcoats with a Koroflex (polyurethane) primer paint system. Additional testing of alternative solvents on panels employing three different primer systems: epoxy, BMS 10-11, and a self-priming topcoat are currently planned for the next steps. This project represents the only Air Force project aimed at finding a chemical replacement for methylene chloride. The experimental design of each phase of the project, the specific analytical and technical criteria used in screening and evaluating each alternative, and the documentation of the results in a series of technical reports have yielded not only several viable alternatives, but, more importantly, a detailed methodology for conducting similar projects.

  16. 5-Cyano-2,3-ditolyl tetrazolium chloride (CTC) reduction in a mesophilic anaerobic digester: Measuring redox behavior,

    E-Print Network [OSTI]

    Pace, Norman

    5-Cyano-2,3-ditolyl tetrazolium chloride (CTC) reduction in a mesophilic anaerobic digester in microcosms containing active anaerobic digester biomass, propylene glycol, and settled sewage centrate. In addition, activity assessment in anaerobic digesters using FISH and CTC reduction assays may be comparable

  17. Postdepositional losses of methane sulfonate, nitrate, and chloride at the European Project for Ice Coring in Antarctica

    E-Print Network [OSTI]

    Fischer, Hubertus

    ) drilling site in Dronning Maud Land (DML) (75°S, 0°E). Analyses of four intermediate deep firn cores and 13 Coring in Antarctica deep-drilling site in Dronning Maud Land, Antarctica R. Weller,1 F. Traufetter,1,2 H, and chloride at the European Project for Ice Coring in Antarctica deep-drilling site in Dronning Maud Land

  18. Investigations on the electrical, thermal and optical properties of the nonlinear optical allylthiourea mercury chloride single crystals

    SciTech Connect (OSTI)

    Sreekanth, G. [Department of Physics, St. Thomas College Pala, Kottayam 686574, Kerala (India)] [Department of Physics, St. Thomas College Pala, Kottayam 686574, Kerala (India); Chandralingam, S. [Department of Physics, Jawaharlal Nehru Technological University, Hyderabad 500085 (India)] [Department of Physics, Jawaharlal Nehru Technological University, Hyderabad 500085 (India); Philip, Jacob; Jayalakshmy, M.S. [Department of instrumentation, Cochin University of Science and Technology, Cochin, Kerala (India)] [Department of instrumentation, Cochin University of Science and Technology, Cochin, Kerala (India); Philip, Reji; Sridharan, Kishore [Raman research institute, Bangalore, Karnataka 560080 (India)] [Raman research institute, Bangalore, Karnataka 560080 (India); Santhosh Kumar, R. [Department of Physics, St. George's College Aruvithura, Kottayam 686122, Kerala (India)] [Department of Physics, St. George's College Aruvithura, Kottayam 686122, Kerala (India); Joseph, Ginson P., E-mail: ginsonpj@gmail.com [Department of Physics, St. Thomas College Pala, Kottayam 686574, Kerala (India)

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? The single crystals of dimension 10 × 5 × 5 mm{sup 3} of allylthiourea mercury chloride are synthesized using slow evaporation technique. ? The bandgap of allylthiourea mercury chloride crystal is found to be about 3.18 eV. ? The optical nonlinearity of the crystal sample are studied using the open aperture Z-scan technique employing a nanosecond laser at 532 nm, and three photon absorption effect has been found. ? An improved photo pyroelectric is used to find the thermal parameters of the crystal. ? The piezoelectric charge coefficient is determined. -- Abstract: Single crystals of dimension 10 × 5 × 5 mm{sup 3} of allylthiourea mercury chloride were synthesized from aqueous solution using slow evaporation technique at ambient temperature. The grown crystals are confirmed by elemental analysis. The band gap of Allylthiourea mercury chloride crystal was found to be about 3.18 eV. The optical nonlinearity of the crystal sample was studied using the open aperture Z-scan technique employing a nanosecond laser at 532 nm, and a three-photon absorption effect has been found. The electrical properties such as dielectric constant, dielectric loss and ac conductivity of the sample were carried out by Agillent E 4980 A LCR meter at different temperatures. An improved photopyroelectric technique was used to find the thermal parameters of the crystal. The piezo electric charge coefficient is also determined.

  19. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE AND CHLORIDE FROM LEGACY FISSILE MATERIALS

    SciTech Connect (OSTI)

    Pierce, R.; Peters, T.

    2011-11-01

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and the Savannah River Site (SRS) HB-Line Facility designed, developed, tested, and successfully deployed a production-scale system for the distillation of sodium chloride (NaCl) and potassium chloride (KCl) from plutonium oxide (PuO{sub 2}). Subsequent efforts adapted the vacuum salt distillation (VSD) technology for the removal of chloride and fluoride from less-volatile halide salts at the same process temperature and vacuum. Calcium chloride (CaCl{sub 2}), calcium fluoride (CaF{sub 2}), and plutonium fluoride (PuF{sub 3}) were of particular concern. To enable the use of the same operating conditions for the distillation process, SRNL employed in situ exchange reactions to convert the less-volatile halide salts to compounds that facilitated the distillation of halide without removal of plutonium. SRNL demonstrated the removal of halide from CaCl{sub 2}, CaF{sub 2} and PuF{sub 3} below 1000 C using VSD technology.

  20. Mathematical Programming Models and Solution Strategies for the

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    1 Mathematical Programming Models and Solution Strategies for the Synthesis of Process Systems Ignacio E. Grossmann Center for Advanced Process Decision-making Dept of Chemical Engineering, Carnegie: Process Systems Engineering Oxygen Air Ethylene Chlorine Vinyl Chloride Hydrogen Chloride Ethylene

  1. Membrane Transport Behavior and the Lability of Chloride on Polyphosphazenes Bearing Bulky Substituents

    SciTech Connect (OSTI)

    Frederick F. Stewart; John R. Klaehn; Christopher J. Orme

    2007-08-01

    Polyphosphazenes are an intriguing class of inorganic polymers where much of their functionality is derived from pendant groups attached to phosphorus. The backbone of the polymer consists of alternating phosphorus and nitrogen atoms where the bonding is conventionally drawn as alternating double and single bonds. Orbital nodes are located at each phosphorus atom resulting in electron delocalization between phosphorus atoms, but not through them. Thus, the polymer backbone has a high degree of flexibility where halogens or other leaving groups can be effectively displaced with nucleophiles. In this paper, the first known example of a polyphosphazene with large quantities of non-labile chloride substituents induced by neighboring group steric effects will be discussed. This example is the result of the substitution of poly[bis-chlorophosphazene] with the sodium salt of 3,5-di-tert-butylphenol where only 60% of the chlorines were displaced. This contrasts with the 100% substitution observed with other phenols (phenol, 4-tert-butylphenol, 3-methylphenol, etc.).

  2. Novel Ternary Molten Salt Electrolytes for intermediate-temperature sodium/nickel chloride batteries

    SciTech Connect (OSTI)

    Li, Guosheng; Lu, Xiaochuan; Coyle, Christopher A.; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

    2012-12-15

    The sodium-nickel chloride (ZEBRA) battery is typically operated at relatively high temperature (250~350°C) to achieve adequate electrochemical performance. Reducing the operating temperature in the range of 150 to 200°C can lead to enhanced cycle life by suppressing temperature related degradation mechanisms. The reduced temperature range also allows for lower cost materials of construction such as elastomeric sealants and gaskets. To achieve adequate electrochemical performance at lower operating temperatures requires an overall reduction in ohmic losses associated with temperature. This includes reducing the ohmic resistance of ?”-alumina solid electrolyte (BASE) and the incorporation of low melting point molten salt as the secondary electrolyte. In present work, planar-type Na/NiCl2 cells with a thin flat plate BASE (600 ?m) and low melting point secondary electrolyte were evaluated at reduced temperatures. Molten salt formulation for use as secondary electrolytes were fabricated by the partial replace of NaCl in the standard secondary electrolyte (NaAlCl4) with other lower melting point alkali metal salts such as NaBr, LiCl, and LiBr. Electrochemical characterization of the ternary molten salts demonstrated , improved ionic conductivity, and sufficient electrochemical window at reduced temperatures. Furthermore, Na/NiCl2 cells with 50 mol% NaBr-containing secondary electrolyte exhibited reduced polarizations at 175°C compared to the cell with the standard NaAlCl4 catholyte. The cells also exhibited stable cycling performance even at 150oC.

  3. Appendix A: The Names of Polymers and Polymeric

    E-Print Network [OSTI]

    Hall, Christopher

    -butadiene-styrene CA cellulose acetate acetate CAB cellulose acetate butyrate butyrate CF cresol-formaldehyde CMC or methylpentene polymethylpentene vinyl chloride poly(vinyl chloride) co-aminocaproic poly(co-aminocaproic acid acid) [nylon 6] Where the monomer name consists of two words, it should be bracketed in the polymer

  4. Long-Term Hydrologic Responses To Shrub Removal In A SW Texas Rangeland: Using Soil Chloride To Estimate Deep Drainage 

    E-Print Network [OSTI]

    Barre, David Anthony

    2010-10-12

    of vegetation; yet root biomass unexpectedly increased due to successful grass establishment during the first five years after treatment. Soil properties did not vary between treatments, indicating that the majority of chloride differences seen were a... (b); grasses (c); forbs (d); saplings (e); and small cacti (f)??..??????????????...?????...24 Figure 1-4 Differences between fine roots (biomass for 5-Yr, 15-Yr and Control treatments in g/m2 to the depth of soil core...

  5. Rapid Fixation of Methylene Chloride by a Macrocyclic Amine Jung-Jae Lee, Keith J. Stanger, Bruce C. Noll, Carlos Gonzalez, Manuel Marquez, and

    E-Print Network [OSTI]

    Smith, Bradley D.

    chloride is a volatile but relatively inert organic liquid that is used extensively as a solvent in small and large scale synthesis and extraction processes.1 In addition, it is employed industrially as a paint

  6. Accelerated quantification of critical parameters for predicting the service life and life cycle costs of chloride-laden reinforced concrete structures 

    E-Print Network [OSTI]

    Pillai Gopalakrishnan, Radhakrishna

    2003-01-01

    The use of corrosion resistant steels (instead of conventional carbon steels) and/or high performance concrete can increase the overall service life and can reduce the life cycle cost (LCC) of reinforced concrete (RC) structures exposed to chloride...

  7. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    SciTech Connect (OSTI)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at SRI and RTI to conduct tests at high-temperature, high-pressure conditions (HTHP). The HTHP tests confirmed the ability of nahcolite pellets and granules to reduce the HCl vapor levels to less than 1 ppm levels with a very high sorbent utilization for chloride capture. The effect of several operating variables such as temperature, pressure, presence of hydrogen sulfide, and sorbent preparation methods was studied on the efficacy of HCl removal by the sorbent. Pilot-scale tests were performed in the fluidized-bed mode at the gasifier facility at the GE-CRD. Sorbent exposure tests were also conducted using a hot coal gas stream from the DOE/FETC's fluidized-bed gasifier at Morgantown, WV. These tests confirmed the results obtained at SRI and RTI. A preliminary economic assessment showed that the cost of HCl removal in a commercial IGCC system will be about $0.001/kWh (1 mills/kWh).

  8. Exposure to methylene chloride from controlled use of a paint remover in residences

    SciTech Connect (OSTI)

    Hodgson, A.T.; Girman, J.R.

    1987-06-01

    A recent laboratory investigation characterized personal exposures to methylene chloride (CH/sub 2/Cl/sub 2/) for simulated typical uses of paint removers and aerosol finishes containing CH/sub 2/Cl/sub 2/ in a room-size environmental chamber at two ventilation rates. Because paint removers produced relatively large exposures to CH/sub 2/Cl/sub 2/ in these experiments, the present investigation was undertaken to measure exposures to CH/sub 2/Cl/sub 2/ for standardized use of a paint remover in a variety of residential environments. A total of 21 experiments were conducted outdoors and indoors in a garage, a basement workshop, and large and small rooms of a house. In the indoor work areas, ventilation patterns and rates were varied by opening windows and doors and by the use of a household fan. Finishes were removed from uniformly-prepared panels and from chairs. The personal exposure of the worker was determined from the continuous measurement of CH/sub 2/Cl/sub 2/ concentration in a pumped breathing-zone sample. Personal exposures resulting from the outdoor use of paint remover were very low (6 to 36 ppM.h). Exposures resulting from the use of paint remover indoors without mechanical exhaust ventilation were considerably higher (190 to 2090 ppM-h). In each indoor location, an open window or exterior door (11 to 142 ppM.h). A single-equation mass-balance model was used to produce estimates of theoretical exposures for experiments conducted indoors. The efficacy of the model for predicting exposures was evaluated by comparing theoretical and measured personal exposures. The model performed best for small-volume work areas with low ventilation rates. In general, the model had an accuracy of +-50 percent when applied to experiments conducted in enclosed work areas without an exhaust fan.

  9. Instrumentation for the detection of halocarbons in ground water. Final report, January 1, 1989 to December 31, 1989. Draft report

    SciTech Connect (OSTI)

    Sammells, A.F.

    1990-05-01

    An instrumentation strategy has been identified for eventually achieving the reliable and quantitative detection of trace halocarbons in groundwater samples. The instrumentation approach relies upon the initial photoelectrochemical (PEC) degradation of the halocarbon to be detected, immediately followed by its potentiometric electrochemical detection as chloride species. Initial PEC degradation of trace halocarbons was achieved using illuminated n-TiO2 (anatase). Two illumination sources (365 and 254nm) were simultaneously used to promote electron excitation from the anatase valence to conduction band to obtain comparative halocarbon degradation rates. PEC degradation rates for the halocarbons trichloroethylene (TCE) and vinyl chloride (VC) were found to progressively decrease with time. The observation suggested that the initial halocarbon concentration, prior to the inception of PEC degradation, might be determined from the measured degradation rate after a defined photolysis time. The expectation was confirmed by comparing halocarbon degradation rates for simulated contaminated groundwater containing known amounts of halocarbons. As might be expected, PEC degradation rates for halocarbons occurred more rapidly at shorter wavelengths. Such differences in photodegradation rates suggested a means of differentiating between these two halocarbons.

  10. Thermal Analysis of Surrogate Simulated Molten Salts with Metal Chloride Impurities for Electrorefining Used Nuclear Fuel

    SciTech Connect (OSTI)

    Toni Y. Gutknecht; Guy L. Fredrickson; Vivek Utgikar

    2012-04-01

    This project is a fundamental study to measure thermal properties (liquidus, solidus, phase transformation, and enthalpy) of molten salt systems of interest to electrorefining operations, which are used in both the fuel cycle research & development mission and the spent fuel treatment mission of the Department of Energy. During electrorefining operations the electrolyte accumulates elements more active than uranium (transuranics, fission products and bond sodium). The accumulation needs to be closely monitored because the thermal properties of the electrolyte will change as the concentration of the impurities increases. During electrorefining (processing techniques used at the Idaho National Laboratory to separate uranium from spent nuclear fuel) it is important for the electrolyte to remain in a homogeneous liquid phase for operational safeguard and criticality reasons. The phase stability of molten salts in an electrorefiner may be adversely affected by the buildup of fission products in the electrolyte. Potential situations that need to be avoided are: (i) build up of fissile elements in the salt approaching the criticality limits specified for the vessel (ii) freezing of the salts due to change in the liquidus temperature and (iii) phase separation (non-homogenous solution) of elements. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This work describes the experimental results of typical salts compositions, consisting of chlorides of strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium (as a surrogate for both uranium and plutonium), used in the processing of used nuclear fuels. Differential scanning calorimetry was used to analyze numerous salt samples providing results on the thermal properties. The property of most interest to pyroprocessing is the liquidus temperature. It was previously known the liquidus temperature of the molten salt would change as spent fuel is processed through the Mk-IV electrorefiner. However, the extent of the increase in liquidus temperature was not known. This work is first of its kind in determining thermodynamic properties of a molten salt electrolyte containing transuranics, fission products and bond sodium. Experimental data concluded that the melting temperature of the electrolyte will become greater than the operating temperature of the Mk-IV ER during current fuel processing campaigns. Collected data also helps predict when the molten salt electrolyte will no longer be able to support electrorefining operations.

  11. Equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride

    SciTech Connect (OSTI)

    Majumdar, A.; Mahmoodaghdam, E.; Bishnoi, P.R.

    2000-02-01

    Natural gas components such as hydrogen sulfide, carbon dioxide, and ethane form gas hydrates of structure I under suitable temperature and pressure conditions. Information on such conditions is vital to the oil and gas industry in order to design and operate processing equipment and pipelines so that hydrate formation is avoided. Incipient equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride were experimentally obtained in the temperature range 264--290 K and the pressure range 0.23--3.18 MPa. A variable-volume sapphire cell was used for the measurements.

  12. Natrix -Scoring Sheet 1. 0.01 M Mg Chloride, 0.05 M MES pH 5.6, 2.0 M Lithium Sulfate

    E-Print Network [OSTI]

    Hill, Chris

    Natrix - Scoring Sheet 1. 0.01 M Mg Chloride, 0.05 M MES pH 5.6, 2.0 M Lithium Sulfate 2. 0.01 M Mg Acetate, 0.05 M MES pH 5.6, 2.5 M Ammonium Sulfate 3. 0.1 M Mg Acetate, 0.05 M MES pH 5.6, 20% MPD 4. 0 Ammonium Acetate, 0.05 M MES pH 6.0, 0.6 M NaCl 9. 0.1 M K Chloride, 0.01 M Mg Chloride, 0.05 M MES pH 6

  13. Radiation Stability of Benzyl Tributyl Ammonium Chloride Towards Technetium-99 Extraction

    SciTech Connect (OSTI)

    Jared Horkley; Audrey Roman; Keri Campbell; Ana Nunez; Amparo Espartero

    2013-02-01

    A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning process, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, low nitric acid concentration in the aqueous phase of a UREX based process will co-extract U(VI) and Tc(VII) by tri-n-butyl phosphate (TBP). Technetium (Tc-99) is recognized to be one of the most abundant, long-lived radiotoxic isotopes in UNF (half-life, t1/2 = 2.13 × 105 years), and as such, it is targeted in UNF separation strategies for isolation and encapsulation in solid waste forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flow sheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste forms for ultimate disposal. Furthermore, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macrocompounds such as crown-ethers, aza-crown ethers, and resorcinarenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO4- by benzyltributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand’s matrix conditions and concentration, as well as varying the organic phase composition (i.e., diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using external Co-60 source. Post-irradiation solvent extraction measurements will be discussed.

  14. The effect of different dietary ratios of sodium and chloride on the physiological responses of lactating dairy cattle in hot weather 

    E-Print Network [OSTI]

    Grant, Pamela Ann

    1980-01-01

    THE EFFECT OF DIFFERENT DIETARY RATIOS OF SODIUM AND CHLORIDE ON THE PHYSIOLOGICAL RESPONSES OF LACTATING DAIRY CATTLE IN HOT WEATHER A Thesis by PAMELA ANN GRANT Submitted to the Graduate College of Texas A8cM Univers' ty in partial... fulfillme'nt of the requirement for the degree of MASTER OF SCIENCE May 1980 Major Subject: Animal Nutrition THE EFFECT OF DIFFERENT DIETARY RATIOS OF SODIUM AND CHLORIDE ON THE PHYSIOLOGICAL RESPONSES OF LACTATING DAIRY CATTLE IN HOT WEATHER A Thesis...

  15. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

    1997-12-02

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

  16. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, Ralph H. (San Ramon, CA); Schaffers, Kathleen I. (Pleasanton, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA); Beach, Raymond J. (Livermore, CA)

    1997-01-01

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 .mu.m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 .mu.m. Related halide materials, including bromides and iodides, are also useful. The Dy.sup.3+ -doped metal chlorides can be pumped with laser diodes and yield 1.3 .mu.m signal gain levels significantly beyond those currently available.

  17. Formation of boron fluoro-chloride in the separation of boron isotopes by multiphoton absorption of BCl/sub 3/

    SciTech Connect (OSTI)

    Li, L.; Chen, G.; Zhang, R.; Kang, N.

    1982-04-01

    The reaction products in the process of boron isotope separation by multiphoton absorption of BCl/sub 3/ have been studied. When oxygen was used as the scavenger, the stable solid product was B/sub 2/O/sub 3/, while (BOCl)/sub 3/ was not found. Our experiments have shown that when irradiated by a focused TEA CO/sub 2/ laser beam, BCl/sub 3/ reacted with fluorocarbon grease to form boron fluoro-chloride and boron trifluoride. A possible mechanism for the reaction between BCl/sub 3/ and fluorocarbon grease has been proposed. It seems that BCl/sub 3/ was first dissociated into BCl/sub 2/ and Cl under the intense IR laser action, and BCl/sub 2/ then reacted with fluorocarbon grease to form BFCl/sub 2/. Besides, BF/sub 2/Cl and BF/sub 3/ were formed from BFCl/sub 2/.

  18. Sodium Chloride interaction with solvated and crystalline cellulose : sodium ion affects the tetramer and fibril in aqueous solution

    E-Print Network [OSTI]

    Bellesia, Giovanni

    2013-01-01

    Inorganic salts are a natural component of biomass which have a significant effect on the product yields from a variety of biomass conversion processes. Understanding their effect on biomass at the microscopic level can help discover their mechanistic role. We present a study of the effect of aqueous sodium chloride (NaCl) on the largest component of biomass, cellulose, focused on the thermodynamic and structural effect of a sodium ion on the cellulose tetramer, and fibril. Replica exchange molecular dynamics simulations of a cellulose tetramer reveal a number of preferred cellulose-Na contacts and bridging positions. Large scale MD simulations on a model cellulose fibril find that Na+ perturbs the hydroxymethyl rotational state population and consequently disrupts the "native" hydrogen bonding network.

  19. A Systematic Study of Chloride Ion Solvation in Water using van der Waals Inclusive Hybrid Density Functional Theory

    E-Print Network [OSTI]

    Bankura, Arindam; DiStasio, Robert A; Swartz, Charles W; Klein, Michael L; Wu, Xifan

    2015-01-01

    In this work, the solvation and electronic structure of the aqueous chloride ion solution was investigated using Density Functional Theory (DFT) based \\textit{ab initio} molecular dynamics (AIMD). From an analysis of radial distribution functions, coordination numbers, and solvation structures, we found that exact exchange ($E_{\\rm xx}$) and non-local van der Waals (vdW) interactions effectively \\textit{weaken} the interactions between the Cl$^-$ ion and the first solvation shell. With a Cl-O coordination number in excellent agreement with experiment, we found that most configurations generated with vdW-inclusive hybrid DFT exhibit 6-fold coordinated distorted trigonal prism structures, which is indicative of a significantly disordered first solvation shell. By performing a series of band structure calculations on configurations generated from AIMD simulations with varying DFT potentials, we found that the solvated ion orbital energy levels (unlike the band structure of liquid water) strongly depend on the un...

  20. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  1. Using a Vadose Zone Model to Predict the Migration Depth of Zinc and Sodium Chloride in Soils beneath Stormwater Infiltration Devices

    E-Print Network [OSTI]

    Clark, Shirley E.

    1 Using a Vadose Zone Model to Predict the Migration Depth of Zinc and Sodium Chloride in Soils pollutants interact with the soils in the unsaturated zone as they migrate towards the groundwater prevalence, solubility, and differing migration rates. Through the use of the SESOIL model, factors

  2. Long-term high frequency measurements of ethane, benzene and methyl chloride at Ragged Point, Barbados: Identification of long-range transport events.

    E-Print Network [OSTI]

    Archibald, A. T.; Witham, C. S.; Ashfold, M. J.; Manning, A. J.; O'Doherty, S.; Greally, B. R.; Young, D.; Shallcross, D. E.

    2015-01-01

    Here we present high frequency long-term observations of ethane, benzene and methyl chloride from the AGAGE Ragged Point, Barbados, monitoring station made using a custom built GC-MS system. Our analysis focuses on the first three years of data...

  3. VICKERY, JOHN D. Fundamental Properties and Bond Characteristics of Chlorinated Polyvinyl Chloride and SS340 Adhesive for Evaluation of Steel Tank Linings. (Under

    E-Print Network [OSTI]

    Chloride and SS340 Adhesive for Evaluation of Steel Tank Linings. (Under the Direction of Dr. Sami Rizkalla. Adhesive materials play a major role in the effectiveness of the liner. The main objective of this research and paper industry. This research will focus on the behavior of the selected Structural Adhesive Series 340

  4. Development and Construction of Low-Cracking High-Performance Concrete (LC-HPC) Bridge Decks: Construction Methods, Specifications, and Resistance to Chloride Ion Penetration

    E-Print Network [OSTI]

    McLeod, Heather Anne Kirkvold

    2009-08-22

    is divided into three parts covering (1) an evaluation of the chloride penetration into concrete using long-term salt-ponding tests, (2) a comprehensive discussion of specifications for LC-HPC construction and standard practices in Kansas, and (3...

  5. Corrosion of 304 Stainless Steel Exposed To Nitric Acid -Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson

    E-Print Network [OSTI]

    Corrosion of 304 Stainless Steel Exposed To Nitric Acid - Chloride Environments D.G. Kolman, DCl, and temperature on the general corrosion behavior of 304 stainless steel (SS), electrochemical studies were vessels, are typically composed of AISI 304 stainless steel (SS). However, the corrosion resistance of 304

  6. A Systematic Study of Chloride Ion Solvation in Water using van der Waals Inclusive Hybrid Density Functional Theory

    E-Print Network [OSTI]

    Arindam Bankura; Biswajit Santra; Robert A. DiStasio Jr.; Charles W. Swartz; Michael L. Klein; Xifan Wu

    2015-03-25

    In this work, the solvation and electronic structure of the aqueous chloride ion solution was investigated using Density Functional Theory (DFT) based \\textit{ab initio} molecular dynamics (AIMD). From an analysis of radial distribution functions, coordination numbers, and solvation structures, we found that exact exchange ($E_{\\rm xx}$) and non-local van der Waals (vdW) interactions effectively \\textit{weaken} the interactions between the Cl$^-$ ion and the first solvation shell. With a Cl-O coordination number in excellent agreement with experiment, we found that most configurations generated with vdW-inclusive hybrid DFT exhibit 6-fold coordinated distorted trigonal prism structures, which is indicative of a significantly disordered first solvation shell. By performing a series of band structure calculations on configurations generated from AIMD simulations with varying DFT potentials, we found that the solvated ion orbital energy levels (unlike the band structure of liquid water) strongly depend on the underlying molecular structures. In addition, these orbital energy levels were also significantly affected by the DFT functional employed for the electronic structure; as the fraction of $E_{\\rm xx}$ was increased, the gap between the highest occupied molecular orbital of Cl$^-$ and the valence band maximum of liquid water steadily increased towards the experimental value.

  7. Effect of hydrogen sulfide partial pressure, pH, and chloride content on the SSC resistance of martensitic stainless steels and martensitic precipitation hardening stainless steels

    SciTech Connect (OSTI)

    Vitale, D.D.

    1999-11-01

    Centrifugal compressor applications require the use of martensitic stainless and martensitic precipitation hardening stainless steels at high hydrogen sulfide partial pressures. These materials do not perform well when tested with standard TM0177 test solutions. This paper describes the effect of hydrogen sulfide partial pressure, pH, and chloride content on their SSC resistance and explains their successful field operational experience. Environmental limits are determined for several materials and heat treat conditions.

  8. Carbon Film Electrodes For Super Capacitor Applications

    DOE Patents [OSTI]

    Tan, Ming X. (Livermore, CA)

    1999-07-20

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

  9. Method for making carbon films

    DOE Patents [OSTI]

    Tan, Ming X. (Livermore, CA)

    1999-01-01

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

  10. Method for making carbon films

    DOE Patents [OSTI]

    Tan, M.X.

    1999-07-29

    A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area ([approx equal]1000 m[sup 2] /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160 C for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750 C in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750--850 C for between 1--6 hours. 2 figs.

  11. EAST CAROLINA UNIVERSITY HAZARDOUS CHEMICAL USE GRANT REVIEW FORM ECU policy requires that all grant proposals involving the use of hazardous chemicals be reviewed by an institutional review committee or

    E-Print Network [OSTI]

    -benezene 4-Aminodiphenyl Asbestos Coal tar pitch volatiles Methyl chloromethyl ether Formaldehyde Vinyl chloride Coke oven emissions 1,2-dibromo-3-chloropropane Lead Cadmium Benzene Cotton dust Chromium VI

  12. EAST CAROLINA UNIVERSITY HAZARDOUS CHEMICAL USE GRANT REVIEW FORM ECU policy requires that all grant proposals involving the use of hazardous chemicals be reviewed by an institutional review committee or

    E-Print Network [OSTI]

    Gopalakrishnan, K.

    tar pitch volatiles Methyl chloromethyl ether Formaldehyde Vinyl chloride Coke oven emissions 1 materials. DOT Class 1 Explosive DOT Class 6 Poison Toxic DOT Class 2 Gas DOT Class 8 Corrosive Highly Toxic

  13. Characterization of the influence of 1-butyl-3-methylimidazolium chloride on the structure and thermal stability of green fluorescent protein

    SciTech Connect (OSTI)

    Heller, William T [ORNL; O'Neill, Hugh Michael [ORNL; Zhang, Qiu [ORNL; Baker, Gary A [ORNL

    2010-01-01

    Ionic liquids (ILs) are finding a vast array of applications as novel solvents for a wide variety of processes that include enzymatic chemistry, particularly as more biocompatible ILs are designed and discovered. While it is assumed that a native or near-native structure is required for enzymatic activity, there is some evidence that ILs alter protein structure and oligomerization states in a manner than can negatively impact function. The IL 1-butyl-3-methylimidazolium chloride, [bmim]Cl, is a well-studied, water-miscible member of the popular 1-alkyl-3-methylimidazolium IL family. To improve our understanding of the impact of water-miscible ILs on proteins, we have characterized the structure and oligomerization state of green fluorescent protein (GFP) in aqueous solutions containing 25 and 50 vol % [bmim]Cl using a combination of optical spectroscopy and small-angle neutron scattering (SANS). Measurements were also performed as a function of temperature to provide insight into the effect of the IL on the thermal stability of GFP. While GFP exists as a dimer in water, the presence of 25 vol % [bmim]Cl causes GFP to transition to a monomeric state. The SANS data indicate that GFP is a great deal less compact in 50 vol % [bmim]Cl than in neat water, indicative of unfolding from the native structure. The oligomerization state of the protein in IL-containing aqueous solution changes from a dimer to a monomer in response to the IL, but does not change as a function of temperature in the IL-containing solution. The SANS and spectroscopic results also demonstrate that the addition of [bmim]Cl to the solution decreases the thermal stability of GFP, allowing the protein to unfold at lower temperatures than in aqueous solution.

  14. "Kohn-Shamification" of the classical density-functional theory of inhomogeneous polar molecular liquids with application to liquid hydrogen chloride

    E-Print Network [OSTI]

    Johannes Lischner; T. A. Arias

    2008-06-27

    The Gordian knot of density-functional theories for classical molecular liquids remains finding an accurate free-energy functional in terms of the densities of the atomic sites of the molecules. Following Kohn and Sham, we show how to solve this problem by considering noninteracting molecules in a set of effective potentials. This shift in perspective leads to an accurate and computationally tractable description in terms of simple three-dimensional functions. We also treat both the linear- and saturation- dielectric responses of polar systems, presenting liquid hydrogen chloride as a case study.

  15. MembFac -Scoring Sheet 1. 12% MPD, 0.1 M Na Acetate pH 4.6, 0.1 M Sodium Chloride

    E-Print Network [OSTI]

    Hill, Chris

    Phosphate, 0.1 M Na Acetate pH 4.6, 0.1 M Lithium Sulfate 10. 12% PEG 6000, 0.1 M Na Acetate pH 4.6, 0.1 MMembFac - Scoring Sheet 1. 12% MPD, 0.1 M Na Acetate pH 4.6, 0.1 M Sodium Chloride 2. 12% PEG 4000, 0.1 M Na Acetate pH 4.6, 0.1 M Zinc Acetate 3. 10% PEG 4000, 0.1 M Na Acetate pH 4.6, 0.2 M Ammonium

  16. Low pour crude oil compositions

    SciTech Connect (OSTI)

    Motz, K.L.; Latham, R.A.; Statz, R.J.

    1990-05-22

    This patent describes and improvement in the process of transporting waxy crude oils through a pipeline. It comprises: incorporating into the crude oil an effective pour point depressant amount of an additive comprising a polymer selected from the group consisting of copolymers of ethylene and acrylonitrile, and terpolymers of ethylene, acrylonitrile and a third monomer selected from the group consisting of vinyl acetate, carbon monoxide, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, vinyl chloride, vinyl fluoride, acrylic acid, and methacrylic acid, wherein the amount of third monomer in the terpolymer ranges from about 0.1 to about 10.0 percent by weight.

  17. K-Ar Dates Of Hydrothermal Clays From Core Hole VC-2B, Valles...

    Open Energy Info (EERE)

    However, the range of ages obtained from illites in Permian sands and pebbles and from Precambrian crystalline rocks indicates that Valles hydrothermal activity is overwhelming...

  18. Scientific Core Hole Valles Caldera No. 2B (VC-2B), New Mexico...

    Open Energy Info (EERE)

    Dennis L. Nielson, Pisto Larry, C.W. Criswell, R. Gribble, K. Meeker, J.A. Musgrave, T. Smith and D. Wilson Conference GRC Annual Meeting; Santa Rosa, CA; 19890101 Published...

  19. Scientific Core Hole Valles Caldera No. 2B (VC-2B), New Mexico: Drilling

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk,SageScheuco International JumpSchuylkill County,Schwenksville,and

  20. Selected Data from Continental Scientific Drilling Core Holes VC-1 and

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk,SageScheucoSedco Hills, California:Sekisui

  1. Microthermometry of Fluid Inclusions from the VC-1 Core Hole in Valles

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPRO isMickey HotMicrosemiMicrosol PowerCaldera,

  2. K-Ar Dates Of Hydrothermal Clays From Core Hole VC-2B, Valles Caldera, New

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder atHills,New York:Just Hot Resources

  3. K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:onItron (California)JointJosephine,

  4. Density functional theory study of the interaction of vinyl radical, ethyne, and ethene with benzene, aimed to define an affordable computational level to investigate stability trends in large van der Waals complexes

    SciTech Connect (OSTI)

    Maranzana, Andrea E-mail: anna.giordana@hotmail.com E-mail: mauro.causa@unina.it Giordana, Anna E-mail: anna.giordana@hotmail.com E-mail: mauro.causa@unina.it Indarto, Antonius Tonachini, Glauco; Barone, Vincenzo E-mail: anna.giordana@hotmail.com E-mail: mauro.causa@unina.it; Causà, Mauro E-mail: anna.giordana@hotmail.com E-mail: mauro.causa@unina.it; Pavone, Michele E-mail: anna.giordana@hotmail.com E-mail: mauro.causa@unina.it

    2013-12-28

    Our purpose is to identify a computational level sufficiently dependable and affordable to assess trends in the interaction of a variety of radical or closed shell unsaturated hydro-carbons A adsorbed on soot platelet models B. These systems, of environmental interest, would unavoidably have rather large sizes, thus prompting to explore in this paper the performances of relatively low-level computational methods and compare them with higher-level reference results. To this end, the interaction of three complexes between non-polar species, vinyl radical, ethyne, or ethene (A) with benzene (B) is studied, since these species, involved themselves in growth processes of polycyclic aromatic hydrocarbons (PAHs) and soot particles, are small enough to allow high-level reference calculations of the interaction energy ?E{sub AB}. Counterpoise-corrected interaction energies ?E{sub AB} are used at all stages. (1) Density Functional Theory (DFT) unconstrained optimizations of the A?B complexes are carried out, using the B3LYP-D, ?B97X-D, and M06-2X functionals, with six basis sets: 6-31G(d), 6-311 (2d,p), and 6-311++G(3df,3pd); aug-cc-pVDZ and aug-cc-pVTZ; N07T. (2) Then, unconstrained optimizations by Møller-Plesset second order Perturbation Theory (MP2), with each basis set, allow subsequent single point Coupled Cluster Singles Doubles and perturbative estimate of the Triples energy computations with the same basis sets [CCSD(T)//MP2]. (3) Based on an additivity assumption of (i) the estimated MP2 energy at the complete basis set limit [E{sub MP2/CBS}] and (ii) the higher-order correlation energy effects in passing from MP2 to CCSD(T) at the aug-cc-pVTZ basis set, ?E{sub CC-MP}, a CCSD(T)/CBS estimate is obtained and taken as a computational energy reference. At DFT, variations in ?E{sub AB} with basis set are not large for the title molecules, and the three functionals perform rather satisfactorily even with rather small basis sets [6-31G(d) and N07T], exhibiting deviation from the computational reference of less than 1 kcal mol{sup ?1}. The zero-point vibrational energy corrected estimates ?(E{sub AB}+ZPE), obtained with the three functionals and the 6-31G(d) and N07T basis sets, are compared with experimental D{sub 0} measures, when available. In particular, this comparison is finally extended to the naphthalene and coronene dimers and to three ??? associations of different PAHs (R, made by 10, 16, or 24 C atoms) and P (80 C atoms)

  5. 40 CFR Ch. I (7101 Edition) 61.71 61.71 Recordkeeping.

    E-Print Network [OSTI]

    chloride measured, analyzed, and recorded by the vinyl chloride detector, the loca- tion of each measurement and the date and approximate time of each measure- ment. (2) A record of the leaks detected dur- ing routine monitoring with the port- able hydrocarbon detector and the ac- tion taken to repair

  6. An experimental investigation of the effect of sodium chloride on talc solubility and complexing of aqueous magnesium in supercritical hydrothermal fluids 

    E-Print Network [OSTI]

    Grabman, Kenneth Bryan

    1989-01-01

    N snszoA &51ntyo rotd 6 ambry f+8N heal/8[ow L 9 5 t p 1- 00'0 10'0 ZO'0 00'0 3oOOL 00'0 30 700'C 8 8 8 8 m = 2. 74 + 1. 14 -1. 4 -1. 3 -1. 2 log a(Cl-) -1. 0 -0. 9 Figure 11. Plot of log mMg, ?versus log act- at 700'C. 0. 04 0. 03 700... the occurrance of higher order chloride complexes of the type MC1 ?" (n = 1, 2, 3, or 4) for Ag, and MC1 ?" for Pb and Zn. Fahlquist and Popp (1989) noted a significant increase in bunsenite (NiO) solubility at 550-750'C, 2 kbar over that in the NaCl...

  7. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  8. The environmental chemical tributyltin chloride (TBT) shows both estrogenic and adipogenic activities in mice which might depend on the exposure dose

    SciTech Connect (OSTI)

    Penza, M.; Jeremic, M.; Marrazzo, E. [Laboratory of Biotechnology and Department of Laboratory Medicine, Civic Hospital of Brescia (Italy); Maggi, A.; Ciana, P. [Centre of Excellence on Neurodegenerative Diseases, University of Milan (Italy); Rando, G. [Center for Integrative Genomics, University of Lausanne (Switzerland); Grigolato, P.G. [Human Pathology, School of Medicine, University of Brescia (Italy); Di Lorenzo, D., E-mail: dilorenzodiego@yahoo.it [Laboratory of Biotechnology and Department of Laboratory Medicine, Civic Hospital of Brescia (Italy)

    2011-08-15

    Exposure during early development to chemicals with hormonal action may be associated with weight gain during adulthood because of altered body homeostasis. It is known that organotins affect adipose mass when exposure occurs during fetal development, although no knowledge of effects are available for exposures after birth. Here we show that the environmental organotin tributyltin chloride (TBT) exerts adipogenic action when peripubertal and sexually mature mice are exposed to the chemical. The duration and extent of these effects depend on the sex and on the dose of the compound, and the effects are relevant at doses close to the estimated human intake (0.5 {mu}g/kg). At higher doses (50-500 {mu}g/kg), TBT also activated estrogen receptors (ERs) in adipose cells in vitro and in vivo, based on results from acute and longitudinal studies in ERE/luciferase reporter mice. In 3T3-L1 cells (which have no ERs), transiently transfected with the ERE-dependent reporter plus or minus ER{alpha} or ER{beta}, TBT (in a dose range of 1-100 nM) directly targets each ER subtype in a receptor-specific manner through a direct mechanism mediated by ER{alpha} in undifferentiated preadipocytic cells and by ER{beta} in differentiating adipocytes. The ER antagonist ICI-182,780 inhibits this effect. In summary, the results of this work suggest that TBT is adipogenic at all ages and in both sexes and that it might be an ER activator in fat cells. These findings might help to resolve the apparent paradox of an adipogenic chemical being also an estrogen receptor activator by showing that the two apparently opposite actions are separated by the different doses to which the organism is exposed. - Research Highlights: > The environmental organotin tributyltin chloride shows dose-dependent estrogenic and adipogenic activities in mice. > The duration and extent of these effects depend on the sex and the dose of the compound. > The estrogenic and adipogenic effects of TBT occur at doses closed to the estimated human intake. > TBT activates the estrogen receptors (ER{alpha} and ER{beta}) in 3T3-L1 cells at nM concentrations.

  9. Synthesis and Rheological Characterization of Poly (vinyl acetate-b-vinyl

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System inStatusandArticle) |Hydrogen Storage Materials

  10. Reactions of Ethyl Groups on a Model Chromia Surface: Ethyl Chloride on Stoichiometric Alpha-Cr2O3(1012)

    SciTech Connect (OSTI)

    Brooks, J.; Ma, Q; Cox, D

    2009-01-01

    The reaction of CH3CH2Cl over the nearly-stoichiometric ?-Cr2O3 (1 0 View the MathML source 2) surface yields gas phase CH2double bond; length as m-dashCH2, CH3CH3, H2 and surface chlorine adatoms. The decomposition reaction is initiated via C-Cl bond cleavage to give a surface ethyl (CH3CH2-) intermediate. A rate-limiting ?-hydride elimination from the surface ethyl species produces gas phase CH2double bond; length as m-dashCH2 and surface hydrogen atoms. Two parallel competing reactions form CH3CH3, via ?-hydride addition to remaining surface ethyl species (reductive elimination), and H2, via the combination of two surface hydrogen atoms. The chlorine freed from the dissociation of CH3CH2Cl binds at the five-coordinate surface Cr3+ sites on the stoichiometric surface and inhibits the surface chemistry via simple site blocking. No surface carbon deposition is observed from the thermal reaction of ethyl chloride, suggesting that ethyl intermediates are not primary coke forming intermediates in the dehydrogenation of ethane over (1 0 View the MathML source 2) facets of ?-Cr2O3.

  11. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  12. Anisotropy Characterization of I-125 Seed with Attached Encapsulated Cobalt Chloride Complex Contrast Agent Markers for MRI-Based Prostate Brachytherapy

    SciTech Connect (OSTI)

    Frank, Steven J., E-mail: sjfrank@mdanderson.or [Department of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Tailor, Ramesh C.; Kudchadker, Rajat J. [Department of Radiation Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Martirosyan, Karen S. [Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX (United States); Stafford, R. Jason; Elliott, Andrew M. [Department of Imaging Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Swanson, David A. [Department of Urology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Sing, David; Choi, Jonathan [Department of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Mourtada, Firas; Ibbott, Geoffrey S. [Department of Radiation Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States)

    2011-07-01

    We have developed a novel MRI marker for prostate brachytherapy. The purpose of this study was to evaluate the changes in anisotropy when cobalt chloride complex contrast agent encapsulated contrast agent markers (C4-ECAM) were placed adjacent to an iodine-125 (I-125) titanium seed, and to verify that the C4-ECAMs were visible on magnetic resonance imaging (MRI) after radiation exposure. Two C4-ECAMs were verified to be MRI visible in a phantom before radiation exposure. The C4-ECAMs were then attached to each end of a 12.7-U (10-mCi) I-125 titanium seed in a polymer tube. Anisotropy was measured and analyzed with the seed alone and with attached C4-ECAMs by suspending thermoluminescent dosimeters in a water phantom in 2 circles surrounding the radioactive source with radius of 1 or 2 cm. A T1-weighted MRI evaluation of C4-ECAMs was then performed after exposure to the amount of radiation typically delivered during 1 month of prostate brachytherapy. Measured values of the anisotropy function F(r, {theta}) for the I-125 seed with and without the C4-ECAMs were mutually statistically indistinguishable (standard error of the mean <4.2%) and agreed well with published TG-43 values for the bare seed. As expected, the anisotropy function {phi}{sub an}(r) for the 2 datasets (with and without C4-ECAMs) derived from the measured F(r, {theta}) did not exhibit statistically measurable difference. Both datasets showed agreement with the published TG-43 {phi}{sub an}(r) for the bare seed. The C4-ECAMs were well visualized by MRI after 1 month of radiation exposure. There were no changes in anisotropy when the C4-ECAMs were placed next to an I-125 radioactive seed, and the C4-ECAMs were visualized after radiation exposure.

  13. Rare earth element geochemistry of acid-sulphate and acid-sulphate-chloride geothermal systems from Yellowstone National Park, Wyoming, USA

    SciTech Connect (OSTI)

    Lewis, A.J.; Palmer, M.R.; Kemp, A.J. [Bristol Univ. (United Kingdom)] [Bristol Univ. (United Kingdom); Sturchio, N.C. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

    1997-02-01

    Rare earth element (REE) concentrations have been determined by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) in acid-sulphate and acid-sulphate-chloride waters and the associated sinters and volcanic rocks from the Yellowstone National Park (YNP), Wyoming, USA, geothermal system. REE concentrations in the volcanic rocks range from 222 to 347 ppm: their chondrite-normalised REE patterns are typical of upper continental crust, with LREE > HREE and negative Eu anomalies. Total REE concentrations in the fluids range from 3 to 1133 nmol kg{sup -1} ({ge}162 ppm), and {Sigma}REE concentrations in sinter are {ge}181 ppm. REE abundances and patterns in drill core material from YNP indicate some REE mobility. Relative to the host rocks the REE patterns of the fluids are variably depleted in HREEs and LREEs, and usually have a pronounced positive Eu anomaly. This decoupling of Eu from the REE suite suggests that (1) Eu has been preferentially removed either from the host rock glass or from the host rock minerals, or (2) the waters are from a high temperature or reducing environment where Eu{sup 2+} is more soluble than the trivalent REEs. Since the latter is inconsistent with production of acid-sulphate springs in a low temperature, oxidising near-surface environment, we suggest that the positive Eu anomalies in the fluids result from preferential dissolution of a Eu-rich phase in the host rock. Spatial and temporal variations in major element chemistry and pH of the springs sampled from Norris Geyser Basin and Crater Hills accompany variations in REE concentrations and patterns of individual geothermal springs. These are possibly related to changes in subsurface plumbing, which results in variations in mixing and dilution of the geothermal fluids and may have lead to changes in the extent and nature of REE complexing. 37 refs., 7 figs., 4 tabs.

  14. Gold(I) chloride adducts of 1,3-bis(di-2-pyridylphosphino)propane: synthesis, structural studies and antitumour activity

    SciTech Connect (OSTI)

    Humphreys, Anthony S.; Filipovska, Aleksandra; Berners-Price, Susan J.; Koutsantonis, George A.; Skelton, Brian W.; White, Allan H.

    2008-06-30

    The novel water soluble bidentate phosphine ligand 1,3-bis(di-2-pyridylphosphino)propane (d2pypp) has been synthesized by a convenient route involving treatment of 2-pyridyllithium with Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} and isolation in crystalline form as the hydrochloride salt. The synthesis of the precursor Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} has been optimized by the use of triphosgene as the chlorinating agent. The 2:1 and 1:2 AuCl:d2pypp adducts have been synthesized and characterized by NMR spectroscopy and single crystal X-ray studies, and shown to be of the form (AuCl){sub 2}({mu}-d2pypp-P,P{prime}) and Au(d2pypp-P,P{prime}){sub 2}Cl(-3.75H{sub 2}O), respectively. The latter is more lipophilic than analogous 1:2 adducts of gold(I) chloride with the diphosphine ligands 1,2-bis(di-n-pyridylphosphino)ethane (dnpype) for n = 2, 3 and 4, based on measurement of the n-octanol-water partition coefficient (log P = -0.46). A single crystal structure determination of the 1:2 Au(I) complex of the 3-pyridyl ethane ligand shows it to be of the form [Au(d3pype-P,P{prime}){sub 2}]Cl {center_dot} 5H{sub 2}O. The in vitro cytotoxic activity of [Au(d2pypp){sub 2}]Cl was assessed in human normal and cancer breast cells and selective toxicity to the cancer cells found. The significance of these results to the antitumour properties of chelated 1:2 Au(I) diphosphine complexes is discussed.

  15. nh Gi Thit Hi Ti Nguyn Thin Nhin ca V Trn Du Deepwater Horizon Cc D n Khu Vc

    E-Print Network [OSTI]

    Sinh Vnh St. Joseph thuc Qun Gulf, và có th thêm c khu Bo Tn Thy Sinh Cng Alligator thuc Qun Franklin hi ti ba Khu Bo Tn Thy Sinh (Vnh St. Joseph, Cng Alligator, và St. Andrews). Bc tip theo s bao gm vic bin báo mang tính giáo dc và cp các t ri ti các li h tàu ti Vnh St. Joseph, Cng Alligator, and Vnh St

  16. Men-Tzung Lo Engineering Building V-C Room 304 Tel: +886-3-426-9734

    E-Print Network [OSTI]

    from National Taiwan University for his works on biomedical signal and image processing as well University, Taipei · Major in biomedical signal and image processing, biomedical imaging and drug delivery Medical Center for applying novel nonlinear signal analysis to multiple biomedical signals from different

  17. Technical and economic feasibility of salt-gradient solar ponds at the Truscott Brine Lake of the Red River Chloride Control Project. A report to the House-Senate Committee on Appropriations of the Ninety-Seventh Congress

    SciTech Connect (OSTI)

    Not Available

    1982-09-01

    The Truscott Brine Lake is being constructed to impound highly brackish water from a number of sources which would normally flow into the Wichita River, a tributary of the Red River in Knox County, Texas. A 35.4-km (22-mile) pipeline is being constructed to carry the brines from their primary source to the Truscott Brine Lake site. The reservoir is designed to contain 100 years of brine emissions from three chloride emission areas in the Wichita River Basin. The solar ponds and power generating facilities would be located in the Bluff Creek Arm of Truscott Brine Lake. The Truscott Brine Lake study includes: survey of suitability of Truscott Lake site, review of solar pond technology, preconceptual design of solar salt pond power plant, and economic evaluation.

  18. Zevenhoven & Kilpinen List of Abbreviations 13.4.2002 Abb.-1 List of abbreviations

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Packaging-derived fuel #12;Zevenhoven & Kilpinen List of Abbreviations 13.4.2002 Abb.-3 PFBC Pressurised parts per million ppmv parts per million by volume PVC Poly vinyl chloride RDF Refuse-derived fuel RE bar) TBBPA Tetrabromo bisphenol A TDF Tyre-derived fuel (i.e. car tyre scrap) TEF Toxicity equivalence

  19. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    build-up and permanent distortion Property Description Total solarbuild-up and permanent distortion; and factors that determine the properties of reflected solarbuild-up (ASTM 1998). A black object absorbs most visible incident solar

  20. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    Data Sheet ID: GP-31B. LBNL Heat Island Group. 2010. http://of the siding surface. The heat island effect is anexample of this (LBNL Heat Island Group 2010). Physical

  1. The Palladium-Catalyzed Trifluoromethylation of Vinyl Sulfonates

    E-Print Network [OSTI]

    Cho, Eun Jin

    A method for the palladium-catalyzed trifluoromethylation of cyclohexenyl sulfonates has been developed. Various cyclohexenyl triflates and nonaflates underwent trifluoromethylation under mild reaction conditions using a ...

  2. Methods for the synthesis of deuterated vinyl pyridine monomers

    DOE Patents [OSTI]

    Hong, Kunlun; Yang, Jun; Bonnesen, Peter V

    2014-02-25

    Methods for synthesizing deuterated vinylpyridine compounds of the Formula (1), wherein the method includes: (i) deuterating an acyl pyridine of the Formula (2) in the presence of a metal catalyst and D.sub.2O, wherein the metal catalyst is active for hydrogen exchange in water, to produce a deuterated acyl compound of Formula (3); (ii) reducing the compound of Formula (3) with a deuterated reducing agent to convert the acyl group to an alcohol group, and (iii) dehydrating the compound produced in step (ii) with a dehydrating agent to afford the vinylpyridine compound of Formula (1). The resulting deuterated vinylpyridine compounds are also described.

  3. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    sun. Figure 2 shows peak modeled global solar irradiance on a vertical, solar tracking,tracking surface in Golden, CO. Figure 3. Apparent position of sun

  4. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    Report SERI/TR-642-761, Solar Energy Research Institute,radiation Direct reflected solar energy from smooth surfaceshighest in the sky. The solar energy incident on a receiving

  5. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    Hart, Robert

    2012-01-01

    to varying levels solar radiation, and quantify theirproperties of reflected solar radiation from glass surfaces,siding surface. Direct solar radiation to siding, reflected

  6. Sr{sub 4}Ru{sub 6}ClO{sub 18}, a new Ru{sup 4+/5+} oxy-chloride, solved by precession electron diffraction: Electric and magnetic behavior

    SciTech Connect (OSTI)

    Roussel, Pascal; Palatinus, Lukas; Belva, Frédéric; Daviero-Minaud, Sylvie; Mentre, Olivier; Huve, Marielle

    2014-04-01

    The crystal structure of Sr{sub 4}Ru{sub 6}ClO{sub 18}, a new Ru{sup 4+/5+} oxo-chloride, has been determined from Precession Electron Diffraction (PED) data acquired on a nanocrystal in a transmission electron microscope using the technique of electron diffraction tomography. This approach is described in details following a pedagogic route and a systematic comparison is made of this rather new method with other experimental methods of electron diffraction, and with the standard single crystal X-ray diffraction technique. Both transport and magnetic measurements, showed a transition at low temperature that may be correlated to Ru{sup 4+}/Ru{sup 5+} charge ordering. - Graphical abstract: Structure of Sr{sub 4}Ru{sub 6}ClO{sub 18}, determined using Precession Electron Diffraction data. - Highlights: • Structure of Sr{sub 4}Ru{sub 6}ClO{sub 18} was solved ab initio using precession electron diffraction. • This was done both on a nanometric sample and on a micrometric one. • Different type of experimental methods of electron diffraction are compared. • Single crystal X-ray diffraction was used to confirm the results. • Transport properties were characterized and show “exotic” behavior.

  7. Passivation-free solid state battery

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Peramunage, Dharmasena (Norwood, MA)

    1998-01-01

    This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

  8. Chloride Depletion in Aged Sea Salt Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acids reacted with the particles through a unique mechanism that had been overlooked in atmospheric chemistry. The reactions release volatile HCl into the atmosphere, but because...

  9. W. Ng, V.C. Storey, and J. Trujillo (Eds.): ER 2013, LNCS 8217, pp. 463470, 2013. Springer-Verlag Berlin Heidelberg 2013

    E-Print Network [OSTI]

    Wieringa, Roel

    - cation of a foundational ontology named UFO, which is used as a semantically coherent reference model

  10. i Hc James Cook (JCU) l trng i hc hng u ca c nm trong khu vc vnh ai nhit i.

    E-Print Network [OSTI]

    ma nhit i thuc Vùng nhit i m t Wet Tropics cng nh thành ph quc gia sôi ng Singapore. Các thành ph nhit i và y t cng ng. Là trng i hc nghiên cu hàng u, JCU em li cho sinh viên iu kin c s vt cht tt nht

  11. Rogers, V.C., K.K. Nielson, 1991, "Multiphase Radon Generation and Transport in Porous Minerals," Health Physics Vol. 60, No. 6, 807-813.

    E-Print Network [OSTI]

    Radioactivity (TENR) Cause by Non-Uranium Mining, October 16-19, Szczyrk, Poland. Usman, S.S., H.Spitz, and J Limited presented at the Nuclear Regulatory Commission Uranium Recovery Licensing Workshop, January 11 to Monitor Radon Emissions from Uranium Tailings," Contract Number EP-D-05-002, Work Assignment No. 4

  12. A Thermodynamic Model for Predicting Mineral Reactivity in Supercritical Carbon Dioxide: I. Phase Behavior of Carbon Dioxide - Water - Chloride Salt Systems Across the H2O-Rich to the CO2-Rich Regions

    SciTech Connect (OSTI)

    Springer, Ronald D.; Wang, Zheming; Anderko, Andre; Wang, Peiming; Felmy, Andrew R.

    2012-09-05

    Phase equilibria in mixtures containing carbon dioxide, water, and chloride salts have been investigated using a combination of solubility measurements and thermodynamic modeling. The solubility of water in the CO2-rich phase of ternary mixtures of CO2, H2O and NaCl or CaCl2 was determined, using near infrared spectroscopy, at 90 atm and 40 to 100 °C. These measurements fill a gap in the experimental database for CO2 water salt systems, for which phase composition data have been available only for the H2O-rich phases. A thermodynamic model for CO2 water salt systems has been constructed on the basis of the previously developed Mixed-Solvent Electrolyte (MSE) framework, which is capable of modeling aqueous solutions over broad ranges of temperature and pressure, is valid to high electrolyte concentrations, treats mixed-phase systems (with both scCO2 and water present) and can predict the thermodynamic properties of dry and partially water-saturated supercritical CO2 over broad ranges of temperature and pressure. Within the MSE framework the standard-state properties are calculated from the Helgeson-Kirkham-Flowers equation of state whereas the excess Gibbs energy includes a long-range electrostatic interaction term expressed by a Pitzer-Debye-Hückel equation, a virial coefficient-type term for interactions between ions and a short-range term for interactions involving neutral molecules. The parameters of the MSE model have been evaluated using literature data for both the H2O-rich and CO2-rich phases in the CO2 - H2O binary and for the H2O-rich phase in the CO2 - H2O - NaCl / KCl / CaCl2 / MgCl2 ternary and multicompontent systems. The model accurately represents the properties of these systems at temperatures from 0°C to 300 °C and pressures up to ~4000 atm. Further, the solubilities of H2O in CO2-rich phases that are predicted by the model are in agreement with the new measurements for the CO2 - H2O - NaCl and CO2 - H2O - CaCl2 systems. Thus, the model can be used to predict the effect of various salts on the water content and water activity in CO2-rich phases on the basis of parameters determined from the properties of aqueous systems. Given the importance of water activity in CO2-rich phases for mineral reactivity, the model can be used as a foundation for predicting mineral transformations across the entire CO2/H2O composition range from aqueous solution to anhydrous scCO2. An example application using the model is presented which involves the transformation of forsterite to nesquehonite as a function of temperature and water content in the CO2-rich phase.

  13. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, M.; Abraham, K.M.

    1993-10-12

    This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

  14. Microbial based chlorinated ethene destruction

    DOE Patents [OSTI]

    Bagwell, Christopher E. (Aiken, SC); Freedman, David L. (Clemson, SC); Brigmon, Robin L. (North Augusta, SC); Bratt, William B. (Atlanta, GA); Wood, Elizabeth A. (Marietta, GA)

    2009-11-10

    A mixed culture of Dehalococcoides species is provided that has an ability to catalyze the complete dechlorination of polychlorinated ethenes such as PCE, TCE, cDCE, 1,1-DCE and vinyl chloride as well as halogenated ethanes such as 1,2-DCA and EDB. The mixed culture demonstrates the ability to achieve dechlorination even in the presence of high source concentrations of chlorinated ethenes.

  15. Heavy metals emission from controlled combustion of PVC 

    E-Print Network [OSTI]

    El-Ayyoubi, Mohammed A.

    1989-01-01

    such as direct heating and uv radiation exposure e (IZ). The PVC polymer chain contains weak sites that represent the initiating sites of chemical deter ioration. These sites are formed during polymerization of the vinyl chloride monomer. Thus attempts...HEAVY METALS EMISSION FROM CONTROLLED COMBUSTION OF PVC A Thesis by MOHAMMED A. EL-AYYOUBI Submitted to the Office of Graduate Studies of Texas Ag M University in partial fulfillment of the requirement for the degas ee of' MASTER OF SCIENCE...

  16. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

    1993-01-01

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  17. Decomposition of chlorinated ethylenes and ethanes in an electron beam generated plasma reactor

    SciTech Connect (OSTI)

    Vitale, S.A.

    1996-02-01

    An electron beam generated plasma reactor (EBGPR) is used to determine the plasma chemistry kinetics, energetics and decomposition pathways of six chlorinated ethylenes and ethanes: 1,1,1-trichloroethane, 1,1-dichloroethane, ethyl chloride, trichloroethylene, 1,1-dichloroethylene, and vinyl chloride. A traditional chemical kinetic and chemical engineering analysis of the data from the EBGPR is performed, and the following hypothesis was verified: The specific energy required for chlorinated VOC decomposition in the electron beam generated plasma reactor is determined by the electron attachment coefficient of the VOC and the susceptibility of the molecule to radical attack. The technology was demonstrated at the Hanford Reservation to remove VOCs from soils.

  18. Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly(diallyldimethylammonium chloride)s

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly to be used in a Solid Alkaline Fuel Cell (SAFC) needs to (i) be insoluble in both aqueous solutions,10% > 320 °C). When used in a fuel cell as a binder in the membrane-electrodes assembly (MEA

  19. The effect of marbling and subcutaneous fat on the microbiological and sensory characteristics of beef strip loin steaks 

    E-Print Network [OSTI]

    Correale, Karen Kross

    1986-01-01

    in polyvinyl chloride (PVC) and high-oxygen barrier (HOB) film and stored at 4+ice in the dark for up to 6 or 28 days, respectively. In a second experiment, beef strip loins of U. S. Choice were fabricated into steaks with subcutaneous fat present... characteristics of beef strip loin steaks packaged and stored in pVC or HOB film. Microbial distributions were dominated by Pseudomonas spp. on PVC-wrapped samples and by Lactobacillus spp. on samples packaged in HOB film by the end of the storage periods. Nean...

  20. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, E.D. Jr.

    1995-07-11

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

  1. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle D. (Golden, CO)

    1995-01-01

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

  2. Molecular analysis of Streptococcus pyogenes M1 protein

    E-Print Network [OSTI]

    McNamara, Case W.

    2006-01-01

    III) chloride holmium (III) chloride lutetium (III)acetate lutetium (III)chloride gadolinium (III) chloride

  3. Magnetic Resonance Imaging Analysis of Molecular Mobility during Dissolution of Poly(vinyl alcohol) in Water

    E-Print Network [OSTI]

    Peppas, Nicholas A.

    for recycling,4 the semiconductor industry,5 and packaging.6 The dissolution of a polymer in a solvent involves-dimensional water concentration profiles were measured as a function of distance from the polymer-solvent interface of the polymer. Self-diffusion coefficient values within the dissolving polymer increase with increasing

  4. DOI: 10.1002/adfm.200700419 Autonomic Healing of Epoxy Vinyl Esters via Ring Opening

    E-Print Network [OSTI]

    Sottos, Nancy R.

    the Grubbs' catalyst is encapsulated in paraffin wax microspheres.[5] These wax micro- spheres serve the dual. Protecting the catalyst from aggressive curing agents by encapsulation in wax microspheres increases chemistry, and demonstrate a viable healing system follow- ing wax protection of the catalyst. The size

  5. Synthetic Approaches to Skeletally Diverse Sultams Using Vinyl- and ?-Halo Benzenesulfonamides

    E-Print Network [OSTI]

    Jeon, KyuOk

    2012-08-31

    The development of new chemical methods to generate novel and diverse structures to probe chemical space is an important aspect of early phase drug discovery. Diversity-Oriented Synthesis (DOS) is a powerful strategy that ...

  6. Short communication Poly(vinyl alcohol) separators improve the coulombic efficiency of

    E-Print Network [OSTI]

    microorgan- isms [1] to generate electricity from biomass have received much at- tention as a promising materials and architectures that maintain high cell performance is important for wide-spread deployment

  7. Solution thermodynamics of poly(vinyl pyrrolidone) in ethanol/CCl{sub 4} mixtures

    SciTech Connect (OSTI)

    Schwager, F.; Marand, E.; Davis, R.M. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1996-12-31

    The Gibbs free energy, the enthalpy, and the entropy of mixing of ethanol with the polymer polyvinylpyrrolidone, PVP, and with its low molecular weight analogue, N-ethylpyrrolidone, NEP were calculated. The calculation of the free energy of mixing was achieved with the thermodynamic model for hydrogen bonded polymer systems developed by Painter, Coleman, and Graf. This model, based on the use of an association model, gives the free energy of mixing as a function of the Flory-Huggins interaction parameter, the composition of the mixture, and the association equilibrium constants. The self-association of the ethanol molecules was described by two equilibrium constants, one for the formation of dimers and one for the formation of multimers. The equilibrium constants of inter-association of PVP or NEP with ethanol were determined from the quantitative analysis of NEP/ethanol and PVP/ethanol FTIR spectra at various temperatures and compositions. The values of the equilibrium constants were then used to calculate the theoretical Gibbs free energy of mixing as a function of the composition. The enthalpic and entropic contributions to mixing were compared for the NEP/ethanol and PVP/ethanol mixtures.

  8. CuO nanoparticle filled vinyl-ester resin nanocomposites: Fabrication, characterization and property analysis

    E-Print Network [OSTI]

    Guo, John Zhanhu

    Angeles, CA 90095, USA Received 28 August 2006; received in revised form 4 November 2006; accepted 30 such as photovoltaic (solar) cells [11,12] and magnetic data storage. The func- tional groups of the polymer are normally steric interaction forces, van der Waals forces, or Lewis acid­base interactions. However, in situ

  9. Poly(vinyl alcohol)-based buffering membranes for isoelectric trapping separations 

    E-Print Network [OSTI]

    Craver, Helen C.

    2009-05-15

    Isoelectric trapping (IET) in multicompartment electrolyzers (MCE) has been widely used for the electrophoretic separation of ampholytic compounds such as proteins. In IET, the separation occurs in the buffering membranes that form a step-wise p...

  10. Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide Raman Sumathi

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    effect by nitric oxide on the acetylene pyrolysis is of interest in combustion chemistry, only a few and a fractional order dependence (0.24) on NO. The third study was the single pulse shock tube study by Ogura8

  11. Effect of thermal history on the molecular orientation in polystyrene/poly(vinyl methyl ether) blends

    E-Print Network [OSTI]

    Pezolet, Michel

    volume and mechanical deformation of polyimides and polycarbonate [16,17]. Wang et al. have reported

  12. Solute Diffusion in Poly(vinyl alcohol)/Poly(acrylic acid) Interpenetrating Networks

    E-Print Network [OSTI]

    Peppas, Nicholas A.

    increasingly important for use in separation processes including microfiltration, ultra- filtration, gas on the charges on the membrane and solute.9,10 Solute transport through hydrogels has been exten- sively studied) and poly(acrylic acid) (PAA) by varying the content of PAA in the hydrogel membrane. We also compared

  13. Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton dissociation of vinyl

    E-Print Network [OSTI]

    Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton the rovibra- tional energy distributions of fragmentsl formed in the infrared multiphoton dissociation (IRMPD energies of the frag- ment can be well characterized in terms of a Boltzmann distribution with a single

  14. Synthesis and Characterization of Hydrogels Based on Poly (N-vinyl formamide)

    E-Print Network [OSTI]

    Aziz, Vara

    2010-04-27

    by conducting tensile tests to measure fracture stress, fracture strain, Young's modulus (E) and shear modulus (G). Young's modulus of PNVF gels increased from 138 kPa to 609 kPa, shear modulus increased from 49 to 212 kPa, fracture stress increased from 17...

  15. The effect of temperature and relative humidity levels upon charcoal tube sampling for vinyl choloride 

    E-Print Network [OSTI]

    McCaskill, Gerald Daniel

    1983-01-01

    hygienist involves sorbent tubes. '~(hen correctly applied, samples collected in this manner yield time- weighted average values for airborne concentrations to which the individual of interest is exposed. To correctly use the results of this sampling.... This is a significant finding due to the fact that as the ambient air tem- perature rises, so does its capability to hoId water vapor. At 90! relative humidity, the amount of water vapor in the air virtually doubles when the ambient air temperature...

  16. Poly(vinyl alcohol) (PVA)/sulfonated polyhedral oligosilsesquioxane (sPOSS) hybrid membranes

    E-Print Network [OSTI]

    Mather, Patrick T.

    for direct methanol fuel cell applications Young-Wook Chang1*, Erdong Wang1y , Geumsig Shin1 , Jung-Eun Han1 exchange membranes in direct methanel fuel cell (DMFC) applications. Fourier transform infrared (FT, fuel cell technologies produce no pollutants, are compact in size, can be easily transported, require

  17. Ferroelectric PLZT thick films grown by poly(1-vinylpyrrolidone-co-vinyl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article) | SciTechSubmitted MoreTrafficFerrin Moore, Senior

  18. Toluene pyrolysis studies and high temperature reactions of propargyl chloride

    SciTech Connect (OSTI)

    Kern, R.D.; Chen, H.; Qin, Z. [Univ. of New Orleans, LA (United States)

    1993-12-01

    The main focus of this program is to investigate the thermal decompositions of fuels that play an important role in the pre-particle soot formation process. It has been demonstrated that the condition of maximum soot yield is established when the reaction conditions of temperature and pressure are sufficient to establish a radical pool to support the production of polyaromatic hydrocarbon species and the subsequent formation of soot particles. However, elevated temperatures result in lower soot yields which are attributed to thermolyses of aromatic ring structures and result in the bell-shaped dependence of soot yield on temperature. The authors have selected several acyclic hydrocarbons to evaluate the chemical thermodynamic and kinetic effects attendant to benzene formation. To assess the thermal stability of the aromatic ring, the authors have studied the pyrolyses of benzene, toluene, ethylbenzene, chlorobenzene and pyridine. Time-of-flight mass spectrometry (TOF) is employed to analyze the reaction zone behind reflected shock waves. Reaction time histories of the reactants, products, and intermediates are constructed and mechanisms are formulated to model the experimental data. The TOF work is often performed with use of laser schlieren densitometry (LS) to measure density gradients resulting from the heats of various reactions involved in a particular pyrolytic system. The two techniques, TOF and LS, provide independent and complementary information about ring formation and ring rupture reactions.

  19. Redox flow batteries based on supporting solutions containing chloride

    DOE Patents [OSTI]

    Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

    2014-01-14

    Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

  20. Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    been obtained, a range suitable for biological and automotive applications. The luminescence signal. S0003-6951 99 01445-X The quantitative detection of oxygen is important for industrial, automotive constant of 10 4 cm2 /s or a diffusion time of 1 s. PTMSP's mechanical properties, environmental stability

  1. The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

    E-Print Network [OSTI]

    Cho, Eun Jin

    The trifluoromethyl group can dramatically influence the properties of organic molecules, thereby increasing their applicability as pharmaceuticals, agrochemicals, or building blocks for organic materials. Despite the ...

  2. MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION

    E-Print Network [OSTI]

    Joyce, Peter James

    2011-01-01

    ix Introduction. A. Coal Liquefaction Overview B.L ZnCl 2-catalyzed Coal Liquefaction . . . . . . . . . • ,Results. . . • . ZnC1 2/MeOH Coal liquefaction Process

  3. Enhanced surface photochemistry in chloride-nitrate ion mixtures.

    E-Print Network [OSTI]

    2008-01-01

    neat POL3 water. UV/Visible spectroscopy measurements The UVthese mixtures. UV/Visible spectroscopy measurements Another

  4. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    mass ratio and the total dissolved Cl- concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m...

  5. Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera...

    Open Energy Info (EERE)

    concentrations (< 10 mgL) and relatively high 36ClCl ratios ((300-1000) 10-15); and geothermal brines with high Cl- concentrations (800-9400 mgL) but low 36ClCl ratios...

  6. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    WAJ: Chemistry and geothermal systems. Academic Press 1977,system corrosion in geothermal systems [11–13]. For thisat the Geysers geothermal system in Northern California.

  7. 1 INTRODUCTION In Spain, Plasticized polyvinyl chloride (PVC-

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    to rapid deterioration. Towards the end of that dec- ade, the former Spanish official standardization body ozone resistance tests on PVC-P geomembranes. In the Spanish Peninsula, the use of PVC-P geomembranes

  8. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    solutions, Journal of nuclear technology 2008, 164:180– 35.Modeling and Analysis. Nuclear Technology 1993, 104: 418- 2.

  9. The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer

    E-Print Network [OSTI]

    Brewer, Leo

    2010-01-01

    No.W-7405-eng~48B TIiE THERMODYNAMICS OF GASEOUS" CUPROUSCu(s) + HCl::= I Thermodynamics of Vaporization to Monomeric

  10. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    of the unsaturated zone at Yucca Mountain, Nevada. J. ofwaste emplacement tunnels at Yucca Mountain, Nevada. J. ofScale Heater Test at Yucca Mountain. International Journal

  11. The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer

    E-Print Network [OSTI]

    Brewer, Leo

    2010-01-01

    48B" with the Atomic Energy Commission in connection withDeclassified Atomic Energy Commission raper, CC-358,5,Common Gases" Atomic Energy Commission Declassified Report.

  12. Electrochemical studies of calcium chloride-based molten salt systems

    SciTech Connect (OSTI)

    Blanchard, T.P. Jr.

    1992-12-01

    Conductance and EMF studies of CaCl{sub 2}-based melts were performed in the temperature range 790--990 C. Conductivity data collected using magnesia tubes and capillaries showed deviations from the data recommended by the National Bureau of Standards. These deviations are attributed to the slow dissolution of magnesia by the CaCl{sub 2}-CaO melt. Conductivity data for molten CaCl{sub 2} using a pyrolytic boron nitride capillary were in reasonable agreement with the recommended data; however, undissolved CaO in CaCl{sub 2} may have caused blockage of the pyrolytic boron nitride capillary, resulting in fluctuations in the measured resistance. The utility of the AgCl/Ag reference electrode in CaCl{sub 2}-AgCl and CaCl{sub 2}-CaO-AgCl melts, using asbestos diaphragms and Vycor glass as reference half-cell membranes, was also investigated. Nernstian behavior was observed using both types of reference half-cell membranes in CaCl{sub 2}-AgCl melts. The AgCl/Ag reference electrode also exhibited Nernstian behavior in CaCl{sub 2}-CaO-AgCl melts using a Vycor reference half-cell membrane and a magnesia crucible. The use of CaCl{sub 2} as a solvent is of interest since it is used in plutonium metal purification, as well as various other commercial applications. 97 refs., 33 figs., 13 tabs.

  13. Cotton responses to mepiquat chloride and PGR-IV treatments 

    E-Print Network [OSTI]

    Biles, Stephen Paul

    1998-01-01

    . The application of MC causes plants to be shorter while PGR-IV treatment often results in taller plants. The use of sequential applications of these PGRs to obtain increased yields and height control has been questioned. The objective of this study...

  14. A Novel Low-Cost Sodium-Zinc Chloride Battery

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

    2013-02-28

    The sodium-metal halide (ZEBRA) battery has been considered as one of the most attractive energy storage systems for stationary and transportation applications. Even though Na-NiCl2 battery has been widely investigated, there is still a need to develop a more economical system to make this technology more attractive for commercialization. In the present work, a novel low-cost Na-ZnCl2 battery with a thin planar ??-Al2O3 solid electrolyte (BASE) was proposed, and its electrochemical reactions and battery performance were investigated. Compared to the Na-NiCl2 chemistry, the ZnCl2-based chemistry was more complicated, in which multiple electrochemical reactions including liquid-phase formation occurred at temperatures above 253°C. During the first stage of charge, NaCl reacted with Zn to form Na in the anode and Na2ZnCl4 in the cathode. Once all the residual NaCl was consumed, further charging led to the formation of a NaCl-ZnCl2 liquid phase. At the end of charge, the liquid phase reacted with Zn to produce solid ZnCl2. To identify the effects of liquid-phase formation on electrochemical performance, button cells were assembled and tested at 280°C and 240°C. At 280°C where the liquid phase formed during cycling, cells revealed quite stable cyclability. On the other hand, more rapid increase in polarization was observed at 240°C where only solid-state electrochemical reactions occurred. SEM analysis indicated that the stable performance at 280°C was due to the suppressed growth of Zn and NaCl particles, which were generated from the liquid phase during discharge of each cycle.

  15. MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION

    E-Print Network [OSTI]

    Joyce, Peter James

    2011-01-01

    labeled for hydrogen, coal, and liquid and gas phase water.is employed to deliver coal- derived liquids to the domesticMultiphase Flow of Gas-Liquid and Gas-Coal Slurry Mixtures

  16. Use of encapsulated zinc particles in a eutectic chloride salt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    agglomeration or other type of particle degradation. The measured enhancement in volumetric thermal storage capacity of the composite with just 10 vol% of coated Zn...

  17. Method for making a uranium chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

    2004-10-05

    The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

  18. Interactions of Lysozyme in Guanidinium Chloride Solutions FromStatic...

    Office of Scientific and Technical Information (OSTI)

    Resource Type: Journal Article Resource Relation: Journal Name: Biotechnology Bioengineering; Journal Volume: 90; Journal Issue: 4; Related Information: Journal Publication...

  19. Interactions of Lysozyme in Guanidinium Chloride Solutions FromStatic

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers(JournalatBaBartheExpansionSciTech ConnectDynamic

  20. Thermophysical Properties of Sodium Nitrate and Sodium Chloride

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. JeffreyThermal Multi-layer4StudyThermophysical

  1. Vol. 132, No. 3 SECONDARY A1 ELECTRODE 601 zolium chloride and aluminum chloride at ambient tem-

    E-Print Network [OSTI]

    Economou, Demetre J.

    -plate electrolyzer. Three systems were investigated: aqueous ferricya- hide, aqueous ferricyanide containing, as by vigorous stirring. In the case of parallel- plate electrolyzers, such strategies include operation

  2. Health assessment for Solvent Savers, Chenango County, Lincklaen, New York, Region 2. CERCLIS No. NYD980421176. Preliminary report

    SciTech Connect (OSTI)

    Not Available

    1989-06-30

    The Solvent Savers site, a National Priorities List site, is located on a rural tract of land, in Lincklaen, Chenango County, New York. Organic chemicals found in groundwater include 1,1,1-trichloroethane, trichloroethylene, benzene, toluene, chloroform, phenol, trans-1,2-dichloroethene, and vinyl chloride. Analysis of one on-site soil sample showed the presence of PCBs. Inorganic chemicals (metals) identified in soil samples include cyanide, lead, arsenic and cadmium. The site poses a potential public health threat to residents on private water supplies adjacent to the site, to persons using Mud Creek (i.e., fishing, swimming), and to on-site workers during any remedial work.

  3. Superfund Record of Decision (EPA Region 7): Des Moines TCE Site, Operable Unit 3, Des Moines, IA. (Second remedial action), September 1992. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-09-18

    The Des Moines TCE site is located southwest of downtown Des Moines, Polk County, Iowa. Land use in the area is predominantly industrial and commercial, and part of the site lies within the floodplain of the Raccoon River. Water from the Des Moines Water Works north infiltration gallery was found to be contaminated with trichloroethylene (TCE), dichloroethylene (DCE), and vinyl chloride at levels above accepted drinking water standards. The ROD addresses OU3, which encompasses potential sources of ground water contamination in an area north of the Raccoon River. The selected remedial action for OU3 includes no action with periodic groundwater monitoring.

  4. Integrated Geochronologic, Geochemical, and Sedimentological Investigation of Proterozoic-Early Paleozoic Strata: From Northern India to Global Perspectives

    E-Print Network [OSTI]

    McKenzie, Neil Ryan

    2012-01-01

    Tiwari,  M. ,  Pant,  C.C. ,  Tewari,  V.C. ,  2000.  Sciences  41,  344-­?354.   Tewari,  V.C. ,  1989.  Upper  Geology  13,  143-­?180.   Tewari,  V.C. ,  Sial,  A.N. ,  

  5. EU FLEGT Update Chatham House, January 20 2010

    E-Print Network [OSTI]

    discussions over past 6 months by VC ·Active internal debate on outstanding issues Malaysia Liberia Indonesia

  6. Effect of composite microstructure on electrical and mechanical properties of poly(vinyl acetate) composites with carbon black and clay. 

    E-Print Network [OSTI]

    Miriyala, Sethu M.

    2009-05-15

    black with a primary particle size of 20 nm (a) and a schematic of networked high structure carbon black (b). Clay Overview Hydrous sodium or aluminium phyllosilicates which are typically less than 2 ?m in diameter are known as clay [44, 45...

  7. Ambipolar Behavior in All-Carbon-Nanotube Field-Effect Transistors by Poly(Vinyl Alcohol) Coating

    E-Print Network [OSTI]

    Maruyama, Shigeo

    parameter analyzer (Agilent 4156C) at room temperature under ambient conditions. Fig. 1 Schematic of device including SWNT diameter distribution, capacitances of PVA film, and I-V characteristics when coating. Wang, M. Shim, K. Roy, M. A. Alam and J. A. Rogers, Nature 454, 495 (2008). 2. D. M. Sun, M. Y

  8. An investigation in the hygrothermal degradation of an E- glass/vinyl-ester composite in humid and immersion environments

    E-Print Network [OSTI]

    Svetlik, Stephanie Laura

    2008-01-01

    polymer and fiber. These results indicate that the filler is, in fact, kaolin clay and not calcium carbonate

  9. Palladium-Catalyzed Completely Linear-Selective Negishi Cross-Coupling of Allylzinc Halides with Aryl and Vinyl Electrophiles

    E-Print Network [OSTI]

    Yang, Yang

    Completely linear: The title reaction provides an effective means to access a wide range of prenylated arenes and “skipped dienes” in a completely linear-selective fashion, as demonstrated by a concise synthesis of the ...

  10. Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate

    E-Print Network [OSTI]

    Tu, TungSheng

    2013-01-01

    columns. Industrial & Engineering Chemistry, 20:1196–1200,process. Industrial & Engineering Chemistry Research, 42:process. Industrial & Engineering Chemistry Research, 50:

  11. Inter-and Intrachain Associations of an Ethylene-Vinyl Acetate Random Copolymer in Dilute 1,2-Dichloroethane Solutions

    E-Print Network [OSTI]

    Wu, Chi

    process, the EVA aggregates are microgel-like particles formed through the winding of the EVA chains and their derivatives to improve the flowing of crude oil, diesel, and other base oils at low tempera- ture,2

  12. Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate

    E-Print Network [OSTI]

    Tu, TungSheng

    2013-01-01

    of the heat exchanger, and the pressure drop in the gasheat exchanger becomes saturated vapor through a pressureexchanger (S9) is partially condensed through a pressure

  13. Photoredox Vinylation of Amino Acids and NAryl Amines Adam Noble and David W. C. MacMillan*

    E-Print Network [OSTI]

    MacMillan, David W. C.

    -tert- butoxycarbonyl (N-Boc) -amino acids,7,8 a CO2-extrusion mechanism that has implications for the use of biomass feedstocks in conjugate additions and organometallic couplings. Allylic amines have long been attractive

  14. Investigation into the potential use of Poly (vinyl alcohol)/Methylglyoxal fibres as antibacterial wound dressing components

    E-Print Network [OSTI]

    Bulman, Sophie E L; Tronci, Giuseppe; Russell, Stephen J; Carr, Chris

    2015-01-01

    As problems of antibiotic resistance increase, a continuing need for effective bioactive wound dressings is anticipated for the treatment of infected chronic wounds. Naturally derived antibacterial agents, such as Manuka honey, consist of a mixture of compounds, more than one of which can influence antimicrobial potency. The non-peroxide bacteriostatic properties of Manuka honey have been previously linked to the presence of methylglyoxal (MGO). The incorporation of MGO as a functional antibacterial additive during fibre production was explored as a potential route for manufacturing wound dressing components. Synthetic MGO and polyvinyl alcohol (PVA) were fabricated into webs of sub-micron fibres by means of electrostatic spinning of an aqueous spinning solution. Composite fabrics were also produced by direct deposition of the PVA-MGO fibres onto a preformed spunbonded nonwoven substrate. Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) and Proton Nuclear Magnetic Resonance (1H-NMR) spectros...

  15. An investigation in the hygrothermal degradation of an E- glass/vinyl-ester composite in humid and immersion environments

    E-Print Network [OSTI]

    Svetlik, Stephanie Laura

    2008-01-01

    Based Divynyl Ester Resin/Styrene Copolymers: CompositionBasted Divynyl Ester Resin/Styrene Copolymers: CompositionBased Divinyl Ester Resin/Styrene Copolymers: Composition

  16. One-Pot Asymmetric Synthesis of Acyclic Chiral Epoxy Alcohols via Tandem Vinylation-Epoxidation with Dioxygen

    E-Print Network [OSTI]

    Walsh, Patrick J.

    , Pennsylvania 19104-6323 pwalsh@sas.upenn.edu Received September 17, 2004 We have developed a one-pot procedure. Chem. 2005, 70, 1262-1268 10.1021/jo048345d CCC: $30.25 © 2005 American Chemical Society Published on Web 01/19/2005

  17. Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate

    E-Print Network [OSTI]

    Tu, TungSheng

    2013-01-01

    optimization and control for intentionally transient processeconomic optimization and process control is economic modelpredictive control and optimization of processes: enabling

  18. An investigation in the hygrothermal degradation of an E- glass/vinyl-ester composite in humid and immersion environments

    E-Print Network [OSTI]

    Svetlik, Stephanie Laura

    2008-01-01

    polymer-matrix composites. ” Composites Science and Technology.polymers exposed to hot, wet conditions. ” Composites Science and Technology.

  19. Water injection as a means for reducing non-condensible and corrosive gases in steam produced from vapor-dominated reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten; Spycher, Nicolas; Kneafsey, Timothy J.

    2008-01-01

    Hydrogen Chloride in Superheated Steam and Chloride in Deepof Chloride in Superheated Geothermal Steam, Geothermics,

  20. Laboratory Fact Sheet: Guidelines for Work with Methylene Chloride Scope: Methylene Chloride (also known as Dichloromethane; CAS# 75-09-2) is a

    E-Print Network [OSTI]

    Nicholson, Bruce J.

    irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. Higher exposure in animals. Repeated exposure may cause bronchitis to develop with coughing, phlegm, and/or shortness

  1. Commodity chemicals from natural gas by methane chlorination

    SciTech Connect (OSTI)

    Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

    1987-01-01

    Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

  2. Fundamentals of fluidized bed chemical processes

    SciTech Connect (OSTI)

    Yates, J.G.

    1983-01-01

    Chemical processes based on the use of fluidized solids, although widely used on an industrial scale for some four decades, are currently increasing in importance as industry looks for improved methods for handling and reacting solid materials. This book provides background necessary for an understanding of the technique of gas-solid fluidization. Contents: Some Fundamental Aspects of Fluidization-General Features of Gas-Solid Fluidization; Minimum Fluidization Velocity; Inter-particle forces; Liquid-Solid Fluidization; Bubbles; Slugging; Entrainment and Elutriation; Particle Movement; Bed Viscosity; Fluidization Under Pressure. Fluidized-Bed Reactor Models-ome Individual Models; Model Comparisons; Multiple Region Models. Catalytic Cracking-Process Developments Riser Cracking; Catalysis; Process Chemistry; Kinetics; Process Models. Combustion and Gasification-Plant Developments; Oil and Gas Combustion; Desulphurization; No/sub x/ Emissions; Coal Gassification. Miscellaneous Processes-Phthalic Anhydride (1,3-isobezofurandione); Acrylonitrile (prop-3-enenitrile); Vinyl Chloride (chloroethene); Titanium Dioxide; Uranium Processing; Sulphide Roasting; Indexes.

  3. Seeds of growth : the challenges of venture capital in the Australian landscape

    E-Print Network [OSTI]

    Lu, Adrian C. (Adrian Chian)

    2012-01-01

    The Australian venture capital (VC) industry is young and relatively immature compared to the United States. Even though the first Australian VC firm appeared in 1970, the industry remained a niche with low levels of ...

  4. Biomechanics of cartilage articulation : effects of degeneration, lubrication, and focal articular defects

    E-Print Network [OSTI]

    Wong, Benjamin L.

    2009-01-01

    In: Basic Orthopaedic Biomechanics, ed. by VC Mow, Hayes WC,In: Basic Orthopaedic Biomechanics and Mechano- Biology, ed.In: Basic Orthopaedic Biomechanics, ed. by VC Mow, Hayes WC,

  5. How Big a Problem is U.S. Corporate Governance?

    E-Print Network [OSTI]

    Kaplan, Steve

    2007-01-01

    VC) fund, private equity or buyout (PE) fund and mutual fundand private equity (PE) or buyout funds. These funds are ofVC) private equity (PE) or buyout funds also has increased

  6. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    July 22, 1974. Project Western Coal: Conversion of Coal Intoand Gasification of Western Coals", in proceedings of ERDA/Investigators' Conference - Coal Research, Colorado School

  7. A General, Practical Palladium-Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides

    E-Print Network [OSTI]

    Senecal, Todd D.

    Playing it safe: The nontoxic cyanide source K[subscript 4][Fe(CN)[subscript 6]?3?H[subscript 2]O can be used for the cyanation of (hetero)aryl halides. The application of palladacycle catalysts prevents poisoning during ...

  8. Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs

    E-Print Network [OSTI]

    Fu, Gregory C.

    The transition metal-catalyzed enantioselective coupling of allylic electrophiles with carbon nucleophiles has been the focus of intense investigation.5 Salient examples include palladium-catalyzed couplings with enolates, ...

  9. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    or gaseous fuels, coal gasification has advanced furthestrapidly. While coal gasification may reach commercializa-5272 (1976). COal Processing - Gasification, Liguefaction,

  10. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    cost 2 over H-Coal process. ZnC1 recovery of 99.6% has beenR) (% C recovery-95)/95 = 0.055 gm incorporated C/gm coal Ccoal with moderate consumption of hydrogen (Z2, 810, WS). A remarkably high recovery (

  11. Flow and morphological conditions associated with the directional solidification of aqueous ammonium chloride

    SciTech Connect (OSTI)

    Magirl, C.S.; Incropera, F.P.

    1993-01-01

    Using 27% aq. NH[sub 4]Cl solutions as transparent analog, shadowgraphy and dye injection were used to observe flow and morphology in unidirectional solidification (UDS) from below. Dendritic crystals that form at the cold surface reject lighter, solute-deficient fluid, and instability is shown by finger-type double-diffusive convection. As the mushy two-phase region grows, perturbations at the liquidus interface cause localized remelting and downward development of channels. Solsutal plumes emanate from the channels, and in time, double-diffusive convection layers also form in the melt. When the solution is chilled at the sides as well as at the bottom, conditions are influenced by detachment and settling of crystals from the sidewall and by plumes from slanted channels. When a slow, oscillatory rocking motion is imposed on UDS, the freckle-type segregates in the final cast is suppressed. Within the melt, plumes and double-diffusive convection are eliminated. Inertially induced convection mixes the melt and produces a dense slurry. Although channels are eliminated from the bottom mushy region, overall heat transfer and macrosegregation in the cavity are unaffected by the slow rocking. Numerical simulations qualitatively predict trends in the field variables and provide insights on interdendritic flows and macrosegregation (freckle-, A-type segregates), although its quantitative predictions are hampered by simplifying assumptions.

  12. Flow and morphological conditions associated with the directional solidification of aqueous ammonium chloride. Annual performance report

    SciTech Connect (OSTI)

    Magirl, C.S.; Incropera, F.P.

    1993-01-01

    Using 27% aq. NH{sub 4}Cl solutions as transparent analog, shadowgraphy and dye injection were used to observe flow and morphology in unidirectional solidification (UDS) from below. Dendritic crystals that form at the cold surface reject lighter, solute-deficient fluid, and instability is shown by finger-type double-diffusive convection. As the mushy two-phase region grows, perturbations at the liquidus interface cause localized remelting and downward development of channels. Solsutal plumes emanate from the channels, and in time, double-diffusive convection layers also form in the melt. When the solution is chilled at the sides as well as at the bottom, conditions are influenced by detachment and settling of crystals from the sidewall and by plumes from slanted channels. When a slow, oscillatory rocking motion is imposed on UDS, the freckle-type segregates in the final cast is suppressed. Within the melt, plumes and double-diffusive convection are eliminated. Inertially induced convection mixes the melt and produces a dense slurry. Although channels are eliminated from the bottom mushy region, overall heat transfer and macrosegregation in the cavity are unaffected by the slow rocking. Numerical simulations qualitatively predict trends in the field variables and provide insights on interdendritic flows and macrosegregation (freckle-, A-type segregates), although its quantitative predictions are hampered by simplifying assumptions.

  13. VISCOSITY OF AQUEOUS SODIUM CHLORIDE SOLUTIONS FROM 0 - 150oC

    E-Print Network [OSTI]

    Ozbek, H.

    2010-01-01

    and evaluate data on geothermal energy for electrical andeconomic aspects of geothermal energy. While the larger workDivision of Geothermal Energy; Office of Environmental

  14. Determination of transport parameters from coincident chloride and tritium plumes at the Idaho National Engineering Laboratory 

    E-Print Network [OSTI]

    Fryar, Alan Ernest

    1986-01-01

    of parameters from the contaminant plume. Evaluation of nuclear -waste tr anspont is complicated due to the necessity of incorporating decay into the transport equation. However, the extended-pulse model has recently been modified to accomodate radioactive... OF FIGURES LIST OF TABLES. INTRODUCTION. THEORETICAL BASES FOR RESEARCH. Development of Mathematical Models The Extended-Pulse Model The Radioactive Formulation. SITE HYDROGEOLOGY Groundwater Hydrology. Waste Disposal and Monitoring, PROCEDURE...

  15. Synthesis of indoles via palladium-catalyzed annulation of aryl chlorides and internal alkynes

    E-Print Network [OSTI]

    Dussault, Daemian David, 1973-

    2005-01-01

    A palladium-catalyzed preparation of 2,3-disubstituted indoles from commercially available and relatively inexpensive reagents, o-chloroacetanilide and internal alkynes, is reported. The system is efficient in delivering ...

  16. Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Chlorides

    E-Print Network [OSTI]

    Zhang, Xumu

    Triazole-Based Monophosphine Ligands for Palladium-Catalyzed Cross-Coupling Reactions of Aryl,3-dipolar cycloaddition of readily available azides and acetylenes. Their palladium complexes provided of sterically hindered amines7 and (1) (a) Heck, R. F. Palladium Reagents in Organic Synthesis; Academic Press

  17. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    iv List of Tables . , I. INTRODUCTION e o Coal Chemistry B.Coal Liquefaction c.Coal Liquefaction a D. II. o Experiment Equipment Summary of

  18. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    Bodily, Stanford Res Inst. , Coal Chemistry Workshop, 1,News, (Aug. 27, 1979). C2 Coal Processing-Gasification,L.W. Vernon, and E.L. Wilson, Coal Liquefaction by the Exxon

  19. Selected genomic and phenotypic responses of Salmonella serovars to chlorine, chlorine dioxide, and cetylpyridinium chloride 

    E-Print Network [OSTI]

    Kakani, Grihalakshmi

    2012-07-11

    with the regulation of the secretory apparatus is followed by the expression of chaperone gene sicA. Other genes sopA, sopB, and sopE 2 associated with the secretion of proteins are expressed soon after. Based on the order of expression of the genes... it is speculated that S. Typhimurium has the highest expression of sopA gene that primarily affects the mitochondrial function (123). This is followed by the dephosphorylation of the phosphate in the lipid membrane by the sopB gene (55, 148) with eventual...

  20. The dynamic shape factor of sodium chloride nanoparticles as regulated by drying rate

    SciTech Connect (OSTI)

    Wang, Z.; Lewis, E.; King, S. M.; Freney, E.; Rosenoern, T.; Smith, M.; Chen, Q.; Kuwata, M.; Poschl, U.; Wang, W.; Buseck, P. R.; Martin, S. T.

    2010-09-01

    The influence of drying rate on the dynamic shape factor {chi} of NaCl particles was investigated. The drying rate at the efflorescence relative humidity (ERH) of 45% was controlled in a laminar flow tube and varied from 5.5 {+-} 0.9 to 101 {+-} 3 RH s{sup -1} at ERH, where RH represents one percent unit of relative humidity. Dry particles having mobility diameters of 23-84 nm were studied, corresponding to aqueous particles of 37-129 nm at the RH (57%) prior to drying. At each mobility diameter and drying rate, the critical supersaturation of cloud-condensation activation was also measured. The mobility diameter and the critical supersaturation were combined in an analysis to determine the value of {chi}. The measured values varied from 1.02 to 1.26. For fixed particle diameter the {chi} value decreased with increasing drying rate. For fixed drying rate, a maximum occurred in {chi} between 35- and 40-nm dry mobility diameter, with a lower {chi} for both smaller and larger particles. The results of this study, in conjunction with the introduced apparatus for obtaining quantified drying rates, can allow the continued development of a more detailed understanding of the morphology of submicron salt particles, with the potential for the follow-on development of quantitative modeling of evaporation and crystal growth at these dimensions.

  1. Polyvinyl chloride film local isometric heat treatment for hidden 3D printing on polymer packaging

    E-Print Network [OSTI]

    Volinsky, Alex A.

    on rigid polyvinyl chlo- ride (PVC) shrink films without any consumables, such as paints, primers reading. The results quantify the rate of internal stress relaxation in PVC shrink films at various stages without thermoplastic consumables by cold or hot stamping using vacuum or blow molding blanks from any

  2. Low coverage spontaneous etching and hyperthermal desorption of aluminum chlorides from Cl2 Al,,111...

    E-Print Network [OSTI]

    Kummel, Andrew C.

    thermal desorption translational energy for AlCl3 . Cl2 sticking probability measurements and AlxCly etch the processes involved in both the thermal and ion-assisted etching of Al 111 by Cl2 .9 Spontaneous high products actually exit the surface at hyperthermal velocities which correspond to 2­30 times thermal energy

  3. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

  4. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    Additional products line gas, LPG, F, phenolsv and ammonia.Purified gas coal 4'JI,. LPG L_J" _ _, Sulfm Fractionatorcooled and separated into LPG and pipeline gas. The residue

  5. The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane 

    E-Print Network [OSTI]

    Hu, Lei

    2012-10-19

    , which was 700 (490 to 920) Gg yr^-1 and -370 (-440 to -280) Gg yr^-1, respectively. The ocean accounts for 10 - 19 % in the global CH3Cl emission and 6 - 9 % in its global sinks. Methane (CH4) is a potent greenhouse gas, which has a warming potential...

  6. An electron spin resonance investigation of irradiated potassium chloride crystals doped with sodium nitroprusside 

    E-Print Network [OSTI]

    Mayers, Richard Ralph

    1968-01-01

    electrons Ferro and. ferrimagnets Imperfections in insulators, which may trap electrons or holes Free rad. icals. 12 Certain paramagnetic solids display electron spin resonance. Among them the strongly paramagnetic salts are likely to have two.... In hyperfine structure the spin and. magnetic moment of the nucleus collaborates with those of the electro~ to produce a ]oint effect. It i" still the electron resonance and must never be confused with the nuclear resonance; but the single resonance peak...

  7. SUPPORTING INFORMATION An MCM modeling study of nitryl chloride (ClNO2) impacts on oxidation,

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    methacrolein 10 10 propanal 90 20 butanal 20 4 ethane 3120 440 propane propane 1940 330 i-butane i-butane 510 70 n-butane n-butane 1200 190 i-pentane 780 100 n-pentane n-petane 350 40 hexane 250 30 nonane 40 2

  8. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    increasing the yield of oil like products. In contrast, Niconversion of coal to oil-like products. The third and finalremoval of the oil-like products from the unreacted products

  9. Cuprous-chloride-modified nanoporous alumina membranes for ethylene-ethane separation

    SciTech Connect (OSTI)

    Lin, Y.S.; Wang, Y.; Ji, W.; Higgins, R.J.

    1999-06-01

    This paper reports an attempt to synthesize a CuCl-modified {gamma}-alumina membrane for separation of ethylene from ethane. CuCl was effectively coated in the 4 nm pore {gamma}-alumina top layers of disk-shaped and tubular alumina membranes by the reservoir method. Permeation of a single gas and binary mixture of ethylene and ethane was measured to characterize separation properties of the modified membranes. Pure ethylene permeance of the CuCl-modified membrane is 10--40% lower than that predicted from the pure ethane permeance by the Knudsen theory. This result is explained by a model based on the adsorbed layer of ethylene via {pi}-complexation. Such an adsorbed layer hinders the diffusion of ethylene in the nanopores of CuCl-modified {gamma}-alumina. Multiple gas permeation measurements on the CuCl-modified membranes show a separation factor for ethylene over ethane larger than the Knudsen value. This confirms a positive contribution of the surface flow of ethylene to the permeance of ethylene in the multiple gas permeation system. A maximum separation factor for ethylene over ethane of 1.4 is obtained for the CuCl-modified membrane at 60 C.

  10. Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

    2013-04-22

    Redox flow batteries (RFBs) are capable of reversible conversion between electricity and chemical energy. Potential RFB applications resolve around mitigating the discrepancy between electricity production and consumption to improve the stability and utilization of the power infrastructure and tackling the intermittency of renewables such as photovoltaics or wind turbines to enable their reliable integration [1, 2]. Because the energy is stored in externally contained liquid electrolytes and the energy conversion reactions take place at the electrodes, RFBs hold a unique capability to separate energy and power and thus possess considerable design flexibility to meet either energy management driven or power rating oriented grid applications, which is considered to be a unparalleled advantage over conventional solid-state secondary batteries [3]. Other advantages of RFBs include fast response to load changes, high round-trip efficiency, long calender and cycle lives, safe operations, tolerance to deep discharge, etc. [4]. Among various flow battery chemistries, all-vanadium redox flow battery (VRB) was invented by Maria Skyllas-Kazacos at the University of New South Wales in the 1980s [5, 6] and have attracted substantial attention in both research and industrial communities today [7, 8]. A well-recognized advantage that makes VRB stands out among other redox chemistries is the reduced crossover contamination ascribed to employing four different oxidation states of the same vanadium element as the two redox couples. Recently, great progress has led to remarkably improved energy density of VRB by using sulfuric-chloric mixed acid supporting electrolytes that were stable at 2.5M vanadium and had wider operational temperature window of -5~50oC [9], compared with the traditional sulfuric acid VRB system [10].

  11. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    Qadar, S.A. , Catalytic Hydrocracking of Coal, CEP, CoalE. , Molten Salt Catalysts for Hydrocracking of Polynuclearoil is upgraded by hydrocracking to produce a synthetic

  12. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    essentially inactive for hydrocracking single-ring aromaticions with different hydrocracking functions could be be~

  13. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    Homogeneous Catalytic Hydrocracking Processes for ConversionPag~ Table I Direct Hydrocracking of a Bituminous Coal withMild Conditions Direct Hydrocracking of Bituminous and Sub-

  14. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    Silver nitrate Sodium ferrocyanide Tin metal Toluene UreaAgCl-2.5 CuC1 -6.7 Sodium ferrocyanide-~ NH CJ..-5; Zno-3.8none Bipyridyl Sodium ferrocyanide co +Amounts used are

  15. Petrographic evidence of calcium oxychloride formation in mortars exposed to magnesium chloride solution

    SciTech Connect (OSTI)

    Sutter, Lawrence . E-mail: cee@mtu.edu; Peterson, Karl . E-mail: cee@mtu.edu; Touton, Sayward . E-mail: cee@mtu.edu; Van Dam, Tom . E-mail: cee@mtu.edu; Johnston, Dan . E-mail: Dan.Johnston@state.sd.us

    2006-08-15

    Many researchers have reported chemical interactions between CaCl{sub 2} and MgCl{sub 2} solutions and hardened Portland cement paste. One potentially destructive phase reported in the literature is calcium oxychloride (3CaO.CaCl{sub 2}.15H{sub 2}O). In the past, limited numbers of researchers have reported identification of this phase by X-ray diffraction. In this work, petrographic evidence of oxychloride formation is presented based on optical microscopy, scanning electron microscopy and microanalysis. This evidence indicates that calcium oxychloride does form in mortars exposed to MgCl{sub 2} solutions.

  16. Molecular Dynamics Simulation of the Transport Properties of Molten Transuranic Chloride Salts 

    E-Print Network [OSTI]

    Baty, Austin Alan

    2013-02-06

    The Accelerator Research Laboratory at Texas A&M is proposing a design for accelerator-driven subcritical fission in molten salt (ADSMS), a system that destroys the transuranic elements in used nuclear fuel. The transuranics (TRU) are the most...

  17. Effect of Brush Vegetation on Deep Drainage Using Chloride Mass Balance 

    E-Print Network [OSTI]

    Navarrete Ganchozo, Ronald J.

    2011-02-22

    related to recharge rates: low Clconcentrations indicate high recharge rates as Cl- is leached from the system; high Cl concentrations indicate low recharge rates since Cl- accumulates as a result of evapotranspiration. The objectives were (1) to assess...

  18. An In-depth Investigation of an Aluminum Chloride Retarded Mud Acid System on Sandstone Reservoirs 

    E-Print Network [OSTI]

    Aneto, Nnenna

    2012-07-16

    is very detrimental to the sandstone core as calcium fluoride is precipitated and the retarded acid system is found to be compatible with iron(III) as an impurity. The regular acid (RMHF) dissolves considerably more silicon and produces more fines than...

  19. Chloride levels increase after 13 years of recycled water use in the Salinas Valley

    E-Print Network [OSTI]

    Platts, Belinda E; Grismer, Mark E

    2014-01-01

    wastewater reused for ir- rigation of fodder, fiber, and seed crops requires only primary treatment (

  20. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    18 Effect of React Run No. Coal Type on Cat. /Coal Ratios of300°C P = 2000 ps Run No. Coal Type Wyodak Imp reg- Sol. , %Wyodak Coal, and Illinois #6 Coal Type of Coal Carbon Wyodak

  1. Cationic quaternization of cellulose with methacryloyloxy ethyl trimethyl ammonium chloride via ATRP method

    SciTech Connect (OSTI)

    Supeno [Cenderawasih University, Jayapura, Papua, Indonesia and School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Daik, Rusli, E-mail: rusli@ukm.edu.my [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); El-Sheikh, Said M. [Nano-Structured Materials Division, Advanced Materials Department, Central Metallurgical Research and Development Institute, Cairo (Egypt)

    2014-09-03

    The synthesis of a cationic cellulose copolymer from cellulose macro-initiator (MCC-BiB) and quaternary compound monomer (METMA) via atom transfer radical polymerization (ATRP) was studied. By using dimethylformamide (DMF), the optimum condition for successful synthesis was at the mole ratio of MCC-BIB:Catalyst:METMA = 1:1:26. The highest copolymer recovery was 93.2 % for 6 h and at 40°C. The copolymer was insoluble in weak polar solvents such as THF and DMF but soluble in methanol and water. The chemistry of cellulose copolymer was confirmed by the FTIR and TGA in which the METMA monomer was used as a reference. The absence of CC bond in the CiB-g-METMA spectrum indicated that graft copolymerization occurred.

  2. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    limit on importation of crude oil and the growing oppositionaccuracy of this diagram. Imported crude oil represents 47%of the total crude oil requirement, and nearly 56% of the

  3. Late Pleistocene and Holocene groundwater recharge from the chloride mass balance method and chlorine-36 data

    E-Print Network [OSTI]

    Zhu, Chen

    rates, estimated from 36 Cl data, were lower in late Pleistocene than Holocene at Yucca Mountain, Nevada Pleistocene. Local recharge rates at Yucca Mountain were estimated from the 36 Cl/Cl ratios and ClÀ concentrations in perched waters. The estimated recharge for Yucca Mountain is 5 ± 1 mm/yr for Holocene and 15

  4. Calibration of Yucca Mountain unsaturated zone flow and transport model using porewater chloride data

    E-Print Network [OSTI]

    Liu, Jianchun; Sonnenthal, Eric L.; Bodvarsson, Gudmundur S.

    2002-01-01

    of hydrogeologic units at Yucca Mountain, Nevada. U.S.infiltration for the Yucca Mountain Area, Nevada. Milestonethe unsaturated zone at Yucca Mountain, Nevada. J. Contam.

  5. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    ducing the contribution of the nuclear sector to energy sup-contribution of the nuclear sec- tor to overall energy

  6. Chloride Analysis of the Soils Overlaying the Carrizo-Wilcox Aquifer 

    E-Print Network [OSTI]

    Wolf, Emery

    2013-09-28

    Science Society of America Journal 58(1):6-14. Jones, Scott. "The Carrizo-Wilcox Aquifer in Texas." The Carrizo-Wilcox Aquifer in Texas. Emporia State University, Spring 2008. Web. 08 Sept. 2013. Maliva, Robert, and Thomas Missimer. “Recharge...

  7. Chloride levels increase after 13 years of recycled water use in the Salinas Valley

    E-Print Network [OSTI]

    Platts, Belinda E; Grismer, Mark E

    2014-01-01

    Ayers RS, Westcot DW. 1985. Water Quality for Agri- culture.+ 2.4904 R² = 0.29738 Applied water Cl (meq/L) Engineering-of soil Cl on applied water Cl during study period. Grieve

  8. Correlations between structure, spectra, and thermodynamics in solutions of cobalt chloride in sodium tetrachloroaluminates

    SciTech Connect (OSTI)

    Newman, D.S.; Tumidajski, P.J.; Blander, M.

    1990-01-01

    An EMF technique using the cell Co/CoCl{sub 2} {minus} Na AlCl{sub 4}//(AgCl)x {minus} NaAlCl{sub 4} (x fixed)/Ag was used to measure the solubility of CoCl{sub 2} in NaCl{center dot}AlCl{sub 3} melts. The changes in EMF as a function of changes in melt composition were correlated with changes in the UV-Vis spectra of the dissolved cobalt species. From these data the microscopic structural contributions to the macroscopic thermodynamic properties of the solutions were estimated. 14 refs., 5 figs., 1 tab.

  9. Methyl Chloride Adsorption on Si(001)-Electronic Structure M. Preuss,* W. G. Schmidt, and F. Bechstedt

    E-Print Network [OSTI]

    Schmidt, Wolf Gero

    reactions with metals, hydrogen, oxygen, and halogens have been intensively studied in the past.1 Fueled found interest in the context of silicon carbide film growth. The CH3Cl/Si interface has been

  10. Methyl chloride variability in the Taylor Dome ice core during the Holocene

    E-Print Network [OSTI]

    Verhulst, Kristal R; Aydin, Murat; Saltzman, Eric S

    2013-01-01

    in the Taylor Dome ice core during the Holocene Kristal R.2005GB002680. Lee-Taylor, J. , and K. R. Redeker (2005),

  11. Relationships between potassium, chloride, and disease incidence in St. Augustinegrass and bermudagrass 

    E-Print Network [OSTI]

    Rider, Larry Ray

    2001-01-01

    on a Tifgreen bermudagrass green showed a strong correlation (r² = 0.9700) of reduction of dollar spot. K applied as K?SO? and Cl applied as CaCl? had little effect. Glasshouse results showed increasing K applied as K?SO? from 0 to 97.6 kg ha?¹ and Cl...

  12. Thermodynamic analysis and growth of ZrO2 by chloride chemical vapor deposition

    E-Print Network [OSTI]

    Anderson, Timothy J.

    for the chemical vapor deposition (CVD) of zirconia. The results showed zirconia formation would occur at high) and high temperatures (N800 °C). Using these calculations as a guide, single-phase monoclinic zirconia.46 mg cm-2 h-1 . © 2007 Elsevier B.V. All rights reserved. Keywords: Chemical vapor deposition; Zirconia

  13. The dimethyl sulfide reaction with atomic chlorine and its implications for the budget of methyl chloride

    E-Print Network [OSTI]

    Langer, Sarka; McGovney, Brian T; Finlayson-Pitts, Barbara J; Moore, Robert M

    1996-01-01

    of dimethyl disulfide (DMDS,-0.4%) and ethyl methylchloride. Since EMS and DMDS were observed as impurities inwhether the CI-EMS and CI-DMDS reactions produced CH3CI. No

  14. Preparation and Characterization of High Purity Cobalt (III) Tetrasulfonatophenyl Porphyrin Chloride

    E-Print Network [OSTI]

    Collins, Gary S.

    ) 1180 (s) -SO3 - 3 1122 (s) 1125 (s) -SO3 - 3 1035 (s) 1037 (s) Phenyl3 1009 (s) 1004 (s) (C-N)/(CC)3

  15. Comparative Neurotoxicity of Methylmercury and Mercuric Chloride In Vivo and In Vitro 

    E-Print Network [OSTI]

    Thuett, Kerry A.

    2010-10-12

    studies, and Trypan blue exclusion, lactate dehydrogenase activity, and cytotoxicity assays for in vitro studies. Mitochondrial membrane potential (MMP), intracellular calcium ion concentration ([Ca2+]i), and production of reactive oxygen species (ROS...

  16. CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Vermeulen, T.

    2012-01-01

    for possible extraction of coal liquids from the melt by aLiquid- phase catalysts have proved effective for opening chemical linkages in subbituminous coal andby the coal. A slow internal flow of liquid upward at the

  17. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    Coal: Conversion of Coal Into Liquids - Final Report,for Conversion of Coal to Liquid Fuels, 'Stanford ResearchConversion of Coal to Liquids--Research Opportunities", in

  18. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01

    Coal·: Conversion of Coal into Liquids- Final Rept. Res. andreaction between solid coal and a liquid catalyst depends tomarks the conversion of coal to liquid oil is the hydrogen

  19. The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

    SciTech Connect (OSTI)

    Peter Zalupski; Rocklan McDowell; Guy Dutech

    2014-10-01

    Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

  20. Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSiliciumEnergy Inc JumpPennsylvania:Sound Beach, New|

  1. Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional Geothermal

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR JumpMaine:WestTexas:Chittenango, New York: EnergyIndicator in

  2. Fate of Magnesium Chloride Brine Applied to Suppress Dust from Unpaved

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) |production at a linear(Conference)membranes(Conference)Article)|Roads

  3. Protocol for analytical ultracentrifugation sample preparation: 1. Provide partial specific volume (v-bar) of the proteins. If v-bar is not available, send complete amino acid

    E-Print Network [OSTI]

    Chan, Hue Sun

    -Propanol Acetic Acid Acetone Ammonium chloride Ammonium hydroxide Ammonium sulfate Barium chloride Cadmium chloride Cadmium sulfate Calcium chloride Cesium chloride Citric acid Cobaltous chloride Creatinine Cupric Guanidine hydrochloride Hydrochloric acid Inulin Lactic acid Lactose Lanthanum nitrate Lead nitrate Lithium

  4. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 94, NO. A2, PAGES 1533-1536, FEBRUARY 1, 1989 Lidar Technique for Measuring Ionospheric

    E-Print Network [OSTI]

    Goree, John

    - tralatomvelocityvmustexceedI/c,satisfyingr/mVc·'/2= where r/ is an efficiencywhich dependson competing loss mechanisms

  5. HP Virtual Connect 16Gb 24-Port FC Non-Proprietary Security Policy

    E-Print Network [OSTI]

    boundary. The Virtual Connect Module (VCM) is software embedded on VC-Enet modules outside of the physical

  6. Reaching Rural Communities: Videoconferencing in K-12 Dance Education

    E-Print Network [OSTI]

    Parrish, Mila Dr.

    2009-01-01

    signals to assist VC classroom management. At the start ofstudent safety and classroom management. Hand signals guided

  7. Prototyping Process and Tools An abbreviated overview of lifecycle

    E-Print Network [OSTI]

    Golub, Evan

    , vinyl, etc. ­ 3D-printed Realistic Interaction · More coding-centric tools ­ Javascript, Flash · Video

  8. VC U S C H O O L O F E N G I N E E R I N G R E S E A R C H R E P O R T I Vo l u m e 5 15 "The prospect of

    E-Print Network [OSTI]

    Motai, Yuichi

    Atulasimha,Ph.D magine a day when battery-powered computer processors are a thing of the past. When a smart phone can energy in the U.S. will be attributed to computers and other computing devices such as smart phones, the structural health of a bridge or building could be monitored with a distributed array of processors

  9. VC U S C H O O L O F E N G I N E E R I N G R E S E A R C H R E P O R T I Vo l u m e 5 7 Resorbable Vascular Grafts

    E-Print Network [OSTI]

    Motai, Yuichi

    of electrospinning, using an electrical charge to extract fine fibers from a liquid, has century-old roots engineering professor Gary L. Bowlin, Ph.D. "Electrospinning has been revived from more than 100 years ago replacement." A basic electrospinning system is much like a cotton candy machine, says Bowlin. "You look

  10. Poly(vinyl alcohol) based hydrogen-bonded multilayers : from pH-controlled multi-stage dissolution to zwitter-wettable surfaces

    E-Print Network [OSTI]

    Lee, Hyomin, Ph. D. Massachusetts Institute of Technology

    2014-01-01

    Understanding the mechanisms that govern the structure and function of synthetic polymer thin films is of fundamental and practical significance for developing a diverse range of functional surfaces including antifogging ...

  11. Overall Rate Constant Measurements of the Reaction of Hydroxy-and Chloroalkylperoxy Radicals Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide

    E-Print Network [OSTI]

    Elrod, Matthew J.

    Overall Rate Constant Measurements of the Reaction of Hydroxy- and Chloroalkylperoxy Radicals separate measurement, as were the chloroalkylperoxy + NO rate constants for both methacrolein [(1.17 ( 0) is the dominant non- methane hydrocarbon present in the atmosphere. Isoprene is biogenic in origin (it is emitted

  12. 3 Micro-mechanics based derivation of the materials constitutive 4 relations for carbon-nanotube reinforced poly-vinyl-ester-epoxy

    E-Print Network [OSTI]

    Grujicic, Mica

    and a tensile 67 strength around 8 GPa) relative to those found in the 68 SWCNTs, the lower-cost MWCNTs cost for the SWCNTs, even 61when they are produced using large-scale high-yield A1 M. Grujicic (&) A2 Department of Mechanical Engineering, Clemson A3 University, 241 Engineering Innovation Building, Clemson, A4

  13. Mechanism of Vinylic and Allylic Carbon-Fluorine Bond Activation of Non-Perfluorinated Olefins Using Cp*2ZrH2

    E-Print Network [OSTI]

    Jones, William D.

    Using Cp*2ZrH2 Bradley M. Kraft and William D. Jones* Contribution from the Department of Chemistry, UniVersity of Rochester, Rochester, New York 14627 Received November 16, 2001 Abstract: Cp*2ZrH2 (1) (CpH10) to afford Cp*2ZrHF (2) and hydrodefluorinated products. Experimental evidence suggests

  14. Mechanistic investigation of vinylic carbonfluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF

    E-Print Network [OSTI]

    Jones, William D.

    using Cp*2ZrH2 and Cp*2ZrHF Bradley M. Kraft a , Eric Clot b , Odile Eisenstein b , William W behaves similarly [4]. In contrast, Cp*Rh(PMe3)H2 reacts with C6F6 by way of an SNAr2 attack by its conjugate base to give Cp*Rh(PMe3)(C6F5)H and fluoride ion, resulting in an autocatalytic reaction [5]. Cp

  15. Sanitary Landfill Groundwater Monitoring Report, Fourth Quarter 1999 and 1999 Summary

    SciTech Connect (OSTI)

    Chase, J.

    2000-03-13

    A maximum of thirty eight-wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill Area at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Iron (Total Recoverable), Chloroethene (Vinyl Chloride) and 1,1-Dichloroethane were the most widespread constituents exceeding the Final Primary Drinking Water Standards during 1999. Trichloroethylene, 1,1-Dichloroethylene, 1,2-Dichloroethane, 1,4-Dichlorobenzene, Aluminum (Total Recoverable), Benzene, cis-1,2-Dichloroethylene, Dichlorodifluoromethane, Dichloromethane (Methylene Chloride), Gross Alpha, Mercury (Total Recoverable), Nonvolatile Beta, Tetrachloroethylene, Total Organic Halogens, Trichlorofluoromethane, Tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill is to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 144.175 ft/year during first quarter 1999 and 145.27 ft/year during fourth quarter 1999.

  16. Protocol for analytical ultracentrifugation sample preparation: 1. Provide partial specific volume (v-bar) of the proteins. If v-bar is not available, send

    E-Print Network [OSTI]

    Chan, Hue Sun

    Ammonium chloride Ammonium hydroxide Ammonium sulfate Barium chloride Cadmium chloride Cadmium sulfate Hydrochloric acid Inulin Lactic acid Lactose Lanthanum nitrate Lead nitrate Lithium chloride Magnesium chloride hydroxide Potassium iodide Potassium nitrate Potassium oxalate Potassium permanganate Potassium PO4 di

  17. The interrelations of mineral colloids and sodium chloride as measured by pH, conductivity, and water-soluble cations 

    E-Print Network [OSTI]

    Crozier, Baalis B

    1952-01-01

    is iegebteg to tbe fallortsg for assis'tasse awl gaigance ia tbe yroyaratioa of this thesis. To Dr. E. E. Eseytoa~ Professor of kgr~ aag Ore&eats kgrisor, aod Dr+ J. De Page, Professor of kgrsssaeP for ssyervisioa throaghoat ths staging to Dr. L. C. gay...'~ Professor of AgroaosP~ for belyfal saggasti~j to Professor C D OogbePp Eeaclp De+arts%at of Qeaeticsp for assist ~ ace ia oabiog the statistical emesis ?f resaltsi to Dr. J. E. kha3ss~ Read, Deyartaeat of kgroooay~ for soggesteg iwyrow...

  18. ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL

    E-Print Network [OSTI]

    Mobley, David Paul

    2013-01-01

    H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

  19. A 2000 year atmospheric history of methyl chloride from a South Pole ice core: Evidence for climate-controlled variability

    E-Print Network [OSTI]

    Williams, Margaret B; Aydin, Murat; Tatum, Cheryl; Saltzman, Eric S

    2007-01-01

    M. B. Williams, Atmospheric Chemistry and Dynamics Branch,California, USA. Now at Atmospheric Chemistry and Dynamics

  20. Quantitative analysis of heavy metals emission during the combustion and baling of polyvinyl chloride insulated copper wire 

    E-Print Network [OSTI]

    Pickard, David Paul

    1996-01-01

    was conducted and compared to the airborne dust samples collected during the baling process. From these results, occupational exposures to heavy metals during the reclamation of PVC insulated copper wire were assessed. Bulk ash and dust samples were ?aken...

  1. EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to advance Oxyhydrochlorination technology to an integrated engineering-scale process.

  2. Effects of Methanol on the Thermodynamics of Iron(III) [Tetrakis(pentafluorophenyl)]porphyrin Chloride Dissociation and the

    E-Print Network [OSTI]

    Bell, Alexis T.

    Effects of Methanol on the Thermodynamics of Iron(III) [Tetrakis in acetonitrile but is catalytically active if the solvent contains methanol. It was suggested that the precursor to the active species is (F20TPP)Fe(OCH3) in methanol-containing solvents. The present study was aimed

  3. Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1982-03-31

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

  4. Atmospheric variability of methyl chloride during the last 300 years from an Antarctic ice core and firn air

    E-Print Network [OSTI]

    Saltzman, Eric

    as a low-pass filter, smoothing variations in the atmospheric composition of a gas over decadal time scales core measurements from Siple Dome provide evidence for a cyclic natural variability on the order of 10 increase measured in firn air may largely be a result of natural processes, which may continue to affect

  5. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

  6. ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL

    E-Print Network [OSTI]

    Mobley, David Paul

    2013-01-01

    interest in conversion of coal to liquid fuels. In order tothe conversion of coal to liquid products are not wellE. A. , "Coal Liquefaction in Inorganic- Organic Liquid

  7. The Effect of Continuous and Pulse Dose Ammonium Chloride Regimens on the Urine pH of Goats 

    E-Print Network [OSTI]

    Sprake, Philippa May

    2012-10-19

    (feed additive) consisted of 0.007% NH4Cl as a feed additive. Following this week long regime, the two treatment regimens were designed as a standard ten goat cross-over design. The first treatment regimen (continuous) consisted of daily administration...

  8. Actinide Corroles: Synthesis and Characterization of Thorium(IV) and Uranium(IV) bis(-chloride) Dimers

    SciTech Connect (OSTI)

    Ward, Ashleigh L.; Buckley, Heather L.; Gryko, Daniel T.; Lukens, Wayne W.; Arnold, John

    2013-12-01

    The first synthesis and structural characterization of actinide corroles is presented. Thorium(IV) and uranium(IV) macrocycles of Mes2(p-OMePh)corrole were synthesised and characterized by single-crystal X-ray diffraction, UV-Visible spectroscopy, variable-temperature 1H NMR, ESI mass spectrometry and cyclic voltammetry.

  9. Firmness and cell wall characteristics of pasteurized jalapeno pepper rings affected by acetic acid, calcium chloride and preheating 

    E-Print Network [OSTI]

    Burma, Prashanthi V

    1994-01-01

    Consumption of jalapeno peppers has increased due to the great popularity of Mexican style foods. Fresh jalapenos are noted for their unique flavor, heat and crisp texture. Unfortunately, fresh peppers lose their crisp ...

  10. Enzymatic Synthesis of Unique Thymidine-Containing Polyphenols

    E-Print Network [OSTI]

    Wang, Ping

    including poly(trimethyleneimine),5 poly- (vinyl alcohol)s,6 poly(ethylenimine),7 and poly(vinyl- amine).8 acylation of thymidine at the 5-hydroxyl was achieved in nearly anhydrous CH3CN using the lipase from

  11. Studies of Block Copolymer Thin Films and Mixtures with an Ionic Liquid

    E-Print Network [OSTI]

    Virgili, Justin

    2009-01-01

    lateral order of poly(styrene-block-isoprene) copolymer (PS-The phase behavior of poly(styrene-block-2-vinyl pyridine)mixtures of a poly(styrene-block-2-vinyl pyridine) (S2VP)

  12. Ion Transport in Nanostructured Block Copolymer/Ionic Liquid Membranes

    E-Print Network [OSTI]

    Hoarfrost, Megan Lane

    2012-01-01

    imide ([Im][TFSI]) and poly(styrene-b-2-vinyl pyridine) (PS-behavior of mixtures of poly(styrene-b-2-vinyl pyridine) (thermal properties of poly(styrene-b-2-vinylpyridine) (PS-b-

  13. Observational constraints on the contribution of isoprene oxidation to ozone production on the western slope of the Sierra

    E-Print Network [OSTI]

    Goldstein, Allen

    measurements of isoprene and its oxi- dation products formaldehyde (HCHO), methyl vinyl ketone (MVKObservational constraints on the contribution of isoprene oxidation to ozone production products methacrolein (MACR) and methyl vinyl ketone (MVK) are used to quantify the impact of isoprene

  14. Guidance Document Peroxide-FormingChemicals

    E-Print Network [OSTI]

    months. Acrylic acid Tetrafluoroethylene Acrylonitrile Vinyl acetate 1,3-Butadiene Vinyl acetylene,1,2,3-Tetrachloro-1,3-butadiene Diacetylene Ethylene glycol dimethyl ether (glyme) Tetrahydrofuran

  15. Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency

    SciTech Connect (OSTI)

    Ridgway, Paul; Zheng, Honghe; Liu, Gao; Song, Xiangun; Ross, Philip; Battaglia, Vincent

    2009-05-05

    Vinylene Carbonate (VC) was added to the electrolyte in graphite-lithium half-cells. We report its effect on the coulombic efficiency (as capacity shift) of graphite electrodes under various formation cycling conditions. Cyclic voltammetry on glassy carbon showed that VC passivates the electrode against electrolyte reduction. The dQ/dV plots of the first lithiation of the graphite suggest that VC alters the SEI layer, and that by varying the cell formation rate, the initial ratio of ethylene carbonate to VC in the SEI layer can be controlled. VC was found to decrease first cycle efficiency and reversible capacity (in ongoing cycling) when used to excess. However, experiments with VC additive used with various formation rates did not show any decrease in capacity shift.

  16. Antithrombogenic and antibiotic compositions and methods of preparation thereof

    DOE Patents [OSTI]

    Hermes, R.E.

    1988-04-19

    Antithrombogenic and antibiotic composition of matter and method of preparation thereof. A random copolymer of a component of garlic and a biocompatible polymer has been prepared and found to exhibit antithrombogenic and antibiotic properties. Polymerization occurs selectively at the vinyl moiety in 2-vinyl-4H-1,3-dithiin when copolymerized with N-vinyl pyrrolidone. 4 figs., 2 tabs.

  17. Antithrombogenic and antibiotic composition and methods of preparation thereof

    DOE Patents [OSTI]

    Hermes, R.E.

    1990-04-17

    Antithrombogenic and antibiotic composition of matter and method of preparation are disclosed. A random copolymer of a component of garlic and a biocompatible polymer has been prepared and found to exhibit antithrombogenic and antibiotic properties. Polymerization occurs selectively at the vinyl moiety in 2-vinyl-4H-1,3-dithiin when copolymerized with N-vinyl pyrrolidone. 4 figs.

  18. Ubungsblatt 7 Ubungen zur Theoretischen Physik IV, Universitat Heidelberg, WS 06/07

    E-Print Network [OSTI]

    Heermann, Dieter W.

    Zustandsgleichung in den dimensionslosen Gr¨oßen = T/Tc, = V/Vc und = p/pc schreibt, ist es m¨oglich, die

  19. Example of classification problems Formulating Support Vector Machines

    E-Print Network [OSTI]

    Page Jr., C. David

    discriminate between the two classes #12;Example: Credit Card Application Age (yrs) Income ($) Rent), we have to maximize the margin! VC dimension margin maximize the margin!mar

  20. Commercialization and Deployment at NREL

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercialization Practices VC Advisory BoardIndustry Growth Forum EERE Innovation Portal Privately Funded Tech Transfer Technology Commercialization and Deployment Fund...

  1. Comparison Of Hydrothermal Alteration Of Carboniferous Carbonate...

    Open Energy Info (EERE)

    With Outcrops From The Socorro Caldera, New Mexico Abstract Continental Scientific Drilling Program (CSDP) drill hole VC-2B (total depth 1761.7 m (5780 ft); maximum...

  2. 1. W.Scandale, G.Arduini, M.Butcher, F.Cerutti, S.Gilardoni, A.Lechner, R.Losito, A.Masi, E.Metral, D.Mirarchi, S.Montesano, S.Redaelli, G.Smirnov, E.Bagli, L.Bandiera, S.Baricordi, P.Dalpiaz,

    E-Print Network [OSTI]

    Titov, Anatoly

    V/c proton beam with the help of bent crystals, Physics Letters B 733 (2014) 366­372. 3. W.Scandale, G

  3. Biomechanics of articular cartilage defects

    E-Print Network [OSTI]

    Gratz, Kenneth R.

    2007-01-01

    fluid on cartilage biomechanics during articulation. BMES,In: Basic Orthopaedic Biomechanics and Mechano-Biology, ed.In: Basic Orthopaedic Biomechanics, ed. by VC Mow, Hayes WC,

  4. SUSS-EX CLUB Steering Group Meeting no. 6

    E-Print Network [OSTI]

    Sussex, University of

    there is a list of `great and good' in the VC office. 4. Programme of Events for 2007-08 Planned activity: House

  5. Large-angle production of charged pions by 3 GeV/c - 12.9 GeV/c protons on beryllium, aluminium and lead targets

    E-Print Network [OSTI]

    HARP Collaboration

    2007-09-21

    Measurements of the double-differential $\\pi^{\\pm}$ production cross-section in the range of momentum $100 \\MeVc \\leq p beryllium, proton--aluminium and proton--lead collisions are presented. The data were taken with the HARP detector in the T9 beam line of the CERN PS. The pions were produced by proton beams in a momentum range from 3 \\GeVc to 12.9 \\GeVc hitting a target with a thickness of 5% of a nuclear interaction length. The tracking and identification of the produced particles was performed using a small-radius cylindrical time projection chamber (TPC) placed inside a solenoidal magnet. Incident particles were identified by an elaborate system of beam detectors. Results are obtained for the double-differential cross-sections at six incident proton beam momenta (3 \\GeVc, 5 \\GeVc, 8 \\GeVc, 8.9 \\GeVc (Be only), 12 \\GeVc and 12.9 \\GeVc (Al only)) and compared to previously available data.

  6. An Overview of Hydrothermal Alteration and Vein Mineralization...

    Open Energy Info (EERE)

    Overview of Hydrothermal Alteration and Vein Mineralization in Continental Scientific Drilling Program Core Hole VC-2B, Valles Caldera, New Mexico Jump to: navigation, search...

  7. Stratigraphy, Structure, Hydrothermal Alteration and Ore Mineralizatio...

    Open Energy Info (EERE)

    Stratigraphy, Structure, Hydrothermal Alteration and Ore Mineralization Encountered in CSDP (Continental Scientific Drilling Program) Corehole VC-2A, Sulphur Springs Area, Valles...

  8. Method and architecture design for motion compensated frame interpolation in high-definition video processing

    E-Print Network [OSTI]

    Lee, Yen-Lin

    2009-01-01

    7.3 Proposed Architecture Design for High Frame RateAnalysis and Efficient Architecture Design for VC-1 OverlapProposed Deblocking Filter Architecture and Implementation

  9. Use of Sequential Injection Analysis to construct a Potentiometric Electronic Tongue: Application to the Multidetermination of Heavy Metals

    SciTech Connect (OSTI)

    Mimendia, Aitor; Merkoci, Arben; Valle, Manel del; Legin, Andrey

    2009-05-23

    An automated potentiometric electronic tongue (ET) was developed for the quantitative determination of heavy metal mixtures. The Sequential Injection Analysis (SIA) technique was used in order to automate the obtaining of input data, and the combined response was modeled by means of Artificial Neural Networks (ANN). The sensor array was formed by four sensors: two based on chalcogenide glasses Cd sensor and Cu sensor, and the rest on poly(vinyl chloride) membranes Pb sensor and Zn sensor. The Ion Selective Electrode (ISE) sensors were first characterized with respect to one and two analytes, by means of high-dimensionality calibrations, thanks to the use of the automated flow system; this characterization enabled an interference study of great practical utility. To take profit of the dynamic nature of the sensor's response, the kinetic profile of each sensor was compacted by Fast Fourier Transform (FFT) and the extracted coefficients were used as inputs for the ANN in the multidetermination applications. In order to identify the ANN which provided the best model of the electrode responses, some of the network parameters were optimized. Finally analyses were performed employing synthetic samples and water samples of the river Ebro; obtained results were compared with reference methods.

  10. Investigation of the sensitivity, selectivity, and reversibility of the chemically-sensitive field-effect transistor (CHEMFET) to detect nitrogen dioxide, dimethyl methylphosphonate, and boron trifluoride. Master's thesis

    SciTech Connect (OSTI)

    Hauschild, N.T.

    1993-09-01

    This study investigated the sensitivity, selectivity, and reversibility of a chemically-sensitive field-effect transistor (CHEMFET) gas microsensor. Various physical operating parameters were tested to determine which produced the most significant sensitivity, selectivity, and reversibility which were computed from response changes generated from electrical conductivity modulations when exposed to challenge gases. The variable operating parameters included: thinfilm material, film thickness, challenge gas specie, challenge gas concentration, and operating temperature. Copper phthalocyanine and lead phthalocyanine were used as thin films to detect the following challenge gases: nitrogen dioxide, dimethyl methylphosphonate, boron trifluoride, methanol, carbon monoxide, vinyl chloride, and trichloroethylene. Tests revealed that copper phthalocyanine was the most sensitive to dimethyl methylphosphonate and boron trifluoride, whereas lead phthalocyanine was the most sensitive to the remaining challenge gases. The CHEMFET was selective to the binary challenge gas combinations. The films were most selective for nitrogen dioxide. The CHEMFET was fully reversibly, and the time duration for full reversibility increased with increasing challenge gas concentrations and increasing time of exposure.

  11. Task 3 - Pyrolysis of Plastic Waste. Semiannual report, November 1, 1996--March 31, 1997

    SciTech Connect (OSTI)

    Ness, Robert O.; Aulich, Ted R.

    1997-12-31

    Over the last 50 years, the U.S. Department of Energy (DOE) has produced a wide variety of radioactive wastes from activities associated with nuclear defense and nuclear power generation. These wastes include low-level radioactive solid wastes, mixed wastes, and transuranic (TRU) wastes. A portion of these wastes consists of high- organic-content materials, such as resins, plastics, and other polymers; synthetic and natural rubbers; cellulosic-based materials; and oils, organic solvents, and chlorinated organic solvents. Many of these wastes contain hazardous and/or pyrophoric materials in addition to radioactive species. Physical forms of the waste include ion-exchange resins used to remove radioactive elements from nuclear reactor cooling water, lab equipment and tools (e.g., measurement and containment vessels, hoses, wrappings, equipment coverings and components, and countertops), oil products (e.g., vacuum pump and lubrication oils), bags and other storage containers (for liquids, solids, and gases), solvents, gloves, lab coats and anti-contamination clothing, and other items. Major polymer and chemical groups found in high-organic-content radioactive wastes include polyvinyl chloride (PVC), low-density polyethylene (LDPE), polypropylene (PP), Teflon(TM), polystyrene (PS), nylon, latex, polyethylene terephthalate (PET), vinyl, high-density polyethylene (HDPE), polycarbonate, nitriles, Tygon(R), butyl, and Tyvec(R).

  12. JOURNAL OF MATERIALS SCIENCE 2012, IN PRESS DOI: 10.1007/S10853-012-6927-8 Viscoelastic properties of hollow glass particle filled vinyl ester matrix syntactic foams: effect of temperature and loading

    E-Print Network [OSTI]

    Gupta, Nikhil

    to generate master curves for storage modulus over a wide frequency range. The room temperature storage vibration response, high temperature mechanical properties, and energy absorption capabilities. Dynamic]. The storage modulus provides a measure of energy stored in the material while loss modulus refers

  13. summer term 2008 University of Heidelberg, Institute of Theoretical Physics Theoretische Physik IV: Statistische Mechanik und Thermodynamik

    E-Print Network [OSTI]

    Heermann, Dieter W.

    ) = p (V ) = 0. (3 points) (b) On writing the equation of state in the dimensionless variables = T/Tc, = V/Vc and = p/pc one can eliminate the constants a and b. First express a and b by Tc, Vc and pc

  14. Anaerobic Reductive Dechlorination of 1-Chloro-1-fluoroethene To Track

    E-Print Network [OSTI]

    Semprini, Lewis

    surrogate for evaluating the rates of VC transformation. Introduction Chlorinated aliphatic hydrocarbons observed in CAH-contaminated groundwater, and this limits the usefulness of anaerobic biotransformation carcinogen and has the lowest drinking water standard (2 µg/L) (3). VC transformation to ethene is generally

  15. On the suitability of applications for GMPLS Malathi Veeraraghavan, Xiuduan Fang, Xuan Zheng

    E-Print Network [OSTI]

    Huang, Wei

    /MPLS interface card Circuit/VC gateway Circuit/VC gateway Controlcard Controlcard SONET/ WDM/ MPLS switch Fig. 1 on to SONET/SDH circuits, WDM lightpaths or MPLS tunnels. Such mapping is performed at nodes we call "circuit-based gateways." As an example of such a gateway, consider Sycamore's SN16000 switch. It can be configured to map

  16. Nickel-Catalyzed Mizoroki-Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products

    E-Print Network [OSTI]

    Tasker, Sarah Z.

    Achieving high selectivity in the Heck reaction of electronically unbiased alkenes has been a longstanding challenge. Using a nickel-catalyzed cationic Heck reaction, we were able to achieve excellent selectivity for ...

  17. A New Class of Easily Activated Palladium Precatalysts for Facile C?N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

    E-Print Network [OSTI]

    Biscoe, Mark R.

    A new class of one-component Pd precatalysts bearing biarylphosphine ligands is described. These precatalysts are air- and thermally stable, are easily activated under normal reaction conditions at or below room temperature, ...

  18. Kinetics of Ion Removal from an Iron-Rich Industrial Coproduct: I. Chloride Yigal Salingar, Donald L. Sparks,* Masoud Ghodrati, and Gerald J. Hendricks

    E-Print Network [OSTI]

    Sparks, Donald L.

    and water quality aspects. Therefore, determining the mechanism and rate of Cl removal by water from the IRM the chamber, and that no chemical kinetics were involved. THE DISPOSAL of industrial byproducts and coproducts and as fertilizer sources. Their disposal, however, is often pre- cluded by a lack of information on the accompanied

  19. Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate

    SciTech Connect (OSTI)

    Dilek, N.; Guenes, B.; Bueyuekguengoer, O.; Guep, R.

    2013-01-15

    The crystal structure of title compound (Fe[(C{sub 25}H{sub 21}N{sub 7}O{sub 4}S{sub 2})] {center_dot} 4(C{sub 3}NOH{sub 7}), where C{sub 3}NOH{sub 7} is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.6375(7), c = 19.5571(6) A, {beta} = 108.753(2) Degree-Sign . The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms.

  20. The effect of iron chloride and glutamate on glutamine synthetase activity in primary cultured rat cortical astrocytes: a model for epileptic induction 

    E-Print Network [OSTI]

    Roberts, Julie Ann

    1986-01-01

    Phillips, Department of Veterinary Public Health for their valuable suggestions, advice and criticisms of the thesis manuscript and for serving as member s of the Advisory Committee. The author is grateful to Dr. Gerald Bratton, Head, Department... for depolarization and r epolarization of the membrane. A pertubation that disrupts the intricate balance could result in a hypersensitive neuron and the genera- tion of an epileptic focus. The resting membrane potential of a neuron is about -60 mV, while...

  1. A study of the condensation of primary, secondary, and tertiary butyl alcohols with benzene in the presence of anhydrous ferric chloride 

    E-Print Network [OSTI]

    Dodson, Ralph Jordan

    1939-01-01

    with aresatio hg4rosoxboas aeso those shish ooataiao4 the QK greay aituate4 aloes be a 4oohlo boa4 (4) yatosse oa4 yileti, Xloyfer, 8K ~ 5I 5btV (1899) (V) 8ohlaa ao4 Kleyfor, Sar, , ~58 5150 (1899) ~ (8} Khstisoht ao4 PoLaositeh, ~, ~ 5104 (1909} (9...) Huetoa oa4 yx4o4ssouai ~ 5995 (1954) ~ Bootes, sosis, oa4 0roh~at, ibb4, ~ 1555 (195t) g Raelea oa4 Lssis, ~. ~ ~55 SSty (1951) g Rsstca os4 Boat, ~, ~ 1505 (1955}} ~ oa4 stsisuoe, ~b. , ~ 481' (1955} g Bustoa 0eamteat ea4 sasOaL11+ ibbL, ~58 4484...

  2. Experimental and Computational Investigations of Candidate Fuel Salt Melt Properties and Corrosion and Irradiation Damage in Nickel for a Molten Chloride Fission System 

    E-Print Network [OSTI]

    Sooby, Elizabeth S

    2014-12-10

    A novel technology for accelerator-driven subcritical fission is being developed. A proton beam produces spallation and drives fission in a molten salt core. The motivation of the development is its capacity to destroy the transuranic elements...

  3. Influence of varying levels of ammonium chloride on urine pH and specific gravity, overall feed conversion, and water consumption in mature wether goats. 

    E-Print Network [OSTI]

    Kennedy, Matthew joseph

    2009-05-15

    cross wethers (n = 24) were stratified by body weight and randomly assigned within strata to one of three treatment groups. Wethers were placed on a common diet containing 2% NH4Cl during the three week collection period. Treatment consisted of daily...

  4. Viscosities of the Mixtures of 1-Ethyl-3-Methylimidazolium Chloride with Water, Acetonitrile and Glucose: A Molecular Dynamics Simulation and Experimental Study

    E-Print Network [OSTI]

    Bell, Alexis

    of biomass are soluble in ionic liquids (ILs), salts that are liquid below 373 K and are green solvent

  5. The involvement of lactic acid in calcium chloride injection of top and bottom rounds further processed into cooked corned beef and cooked beef 

    E-Print Network [OSTI]

    McCleery, Carrie McReynolds

    1995-01-01

    Top and bottom rounds were removed 30 minutes after exsanguination from 8 pure bred Brahman cows. Top and bottom rounds were removed from both sides of the carcass and were divided equally into four treatments: Hot control (HOT); Cold control (COLD...

  6. Magnetic Exchange Coupling in Chloride-Bridged 5f-3d Heterometallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate

    E-Print Network [OSTI]

    Insertion into a Uranium(IV) Dimethylpyrazolate Dimer Stosh A. Kozimor, Bart M. Bartlett, Jeffrey D. Rinehart, and Jeffrey R. Long* Department of Chemistry, UniVersity of California, Berkeley, California additional products were observed: a THF adduct, (Me2Pz)4U(THF), and a salt of the pentapyrazolate uranium

  7. Posting type Historical applies only to downloads before 11/23/09 Subject Under-correction of chloride concentrations for filter blank levels

    E-Print Network [OSTI]

    Fischer, Emily V.

    concentrations were noted by Jenny Hand at CIRA (Figure 1, bottom). It is thus necessary to reprocess 2007 ­ 2008. For consistency, all ion data back to 2005 will be reprocessed following the same procedure used before that year

  8. Moisture Performance of High-R Wall Systems

    Broader source: Energy.gov [DOE]

    Lead Performer: Home Innovation Research Labs—Upper Marlboro, MD Partners: -- American Chemistry Council -- National Association of Home Builders -- USDA Forest Products Lab -- Vinyl Siding Institute

  9. TRL Acid and Solvent Wet Processing Rules and Guidelines

    E-Print Network [OSTI]

    Reif, Rafael

    guards, Trionic gloves (atop the standard gowning vinyl cleanroom gloves cleanroom gloves and safety glasses are required. MSDS sheets for all chemicals

  10. Storm Windows | Department of Energy

    Office of Environmental Management (EM)

    may significantly reduce visibility and degrade over time when exposed to sunlight. Wood, aluminum, and vinyl are the most common storm window frame materials. There are...

  11. Roll Printed Electronics: Development and Scaling of Gravure Printing Techniques

    E-Print Network [OSTI]

    de la Fuente Vornbrock, Alejandro

    2009-01-01

    effect transistors with polyimide gate dielectric layers."methacrylate (PMMA), polyimide (PI), poly(vinyl-alcohol) (styrene, PMMA, and polyimide were the earliest materials to

  12. Window Types | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    its U-factor. There are advantages and disadvantages to all types of frame materials, but vinyl, wood, fiberglass, and some composite frame materials provide greater...

  13. Chemical Emissions of Residential Materials and Products: Review of Available Information

    E-Print Network [OSTI]

    Willem, Henry

    2010-01-01

    glycol monomethyl ether Styrene Tetrachloroethylene Toluenepigments Natural rubber, styrene-butadiene rubber, fillers,4-phenylcyclohexene, styrene, toluene, and vinyl acetate; 2)

  14. Techniques and Technologies for Field Detection of Asbestos Containing Materials

    Broader source: Energy.gov [DOE]

    Asbestos has been used in numerous applications at DOE sites including sprayed-on fireproofing, asphalt and vinyl floor tile, and asbestos-cement(transite) siding.

  15. Weatherstripping | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    (bronze, copper, stainless steel, and aluminum) last for years and are affordable. Metal weatherstripping can also provide a nice touch to older homes where vinyl might seem...

  16. Synthesis and tribological behavior of silicon oxycarbonitride...

    Office of Scientific and Technical Information (OSTI)

    Article: Synthesis and tribological behavior of silicon oxycarbonitride thin films derived from poly(urea)methyl vinyl silazane. Citation Details In-Document Search Title:...

  17. INDEPENDENT TECHNICAL REVIEW OF THE BUILDING 100 PLUME, FORMER DOE PINELLAS SITE (YOUNG - RAINEY STAR CENTER), LARGO, FLORIDA

    SciTech Connect (OSTI)

    Eddy-Dilek, C.; Rossabi, J.; Amidon, M.; Riha, B.; Kaback, D.

    2010-07-30

    Contaminated groundwater associated with Building 100 at the Young-Rainey Science, Technology, and Research Center, formerly the DOE Pinellas plant, is the primary remedial challenge that remains to be addressed at the site. Currently, Building 100 is an active industrial facility that is now owned and operated by the Pinellas county government. Groundwater samples collected from monitoring wells recently installed near the southern boundary of the site suggest that contaminated groundwater has migrated off the plant site. In response to the challenges presented by the Building 100 plume, the Office of Legacy Management (LM) requested assistance from the DOE Office of Groundwater and Soil Remediation (EM-32) to provide a review team to make technical recommendations so that they can efficiently and effectively address characterization and remediation of the plume. The review team was unanimous in the conclusion that a dynamic strategy that combines a phased implementation of direct push samplers, sensors, and tools can be used to better delineate the extent of contamination, control plume migration, and rapidly remediate the contaminated groundwater at the site. The initial efforts of the team focused on reviewing the site history and data, organizing the information into a conceptual model, identifying appropriate technologies, and recommending an integrated strategy. The current groundwater data from the site indicate a two-lobed plume extending to the east and south. To the east vinyl chloride is the primary contaminant of concern, to the south, vinyl chloride and cis1, 2-DCE are the primary contaminants. The limited data that are available suggest that reductive dechlorination of the TCE is already occurring but is not sufficient to prevent offsite migration of low concentrations of TCE daughter products. The team recommends that DOE pursue a strategy that builds on the natural cleansing capacity of the subsurface with reductive methods including biostimulation and/or bioaugmentation to provide a sustainable remediation system within the flow path of the plume. Additional data will be required to implement this approach and will include: (1) Better delineation of the nature and extent of contamination; (2) Demonstration the plume is currently stable or shrinking; and (3) Demonstration the full reductive dechlorination is occurring. The technical team recommends that DOE use a phased approach to identify residual contamination and to provide rapid installation of remedies. Matrices of characterization and remediation sensors, technologies, and tools were developed by the team in order to match the specific conditions and requirements of the site. The team provides a specific example of remedy that includes the incorporation of a dynamic characterization strategy moving from minimally invasive to more aggressive field techniques, the consideration of multiple complementary remediation approaches based on a spatiotemporally phased approach keyed to the different demands of different parts of the plume, and the integration and sequencing of the characterization and remediation activities.

  18. Potentiometric Response Characteristics of Membrane-BasedCs+-Selective Electrodes Containing Ionophore-Functionalized Polymeric Microspheres

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peper, Shane; Gonczy, Chad

    2011-01-01

    Cs+-selective solvent polymeric membrane-based ion-selective electrodes (ISEs) were developed by doping ethylene glycol-functionalized cross-linked polystyrene microspheres (P-EG) into a plasticized poly(vinyl chloride) (PVC) matrix containing sodium tetrakis-(3,5-bis(trifluoromethyl)phenyl) borate (TFPB) as the ion exchanger. A systematic study examining the effects of the membrane plasticizers bis(2-ethylhexyl) sebacate (DOS), 2-nitrophenyl octyl ether (NPOE), and 2-fluorophenyl nitrophenyl ether (FPNPE) on the potentiometric response and selectivity of the corresponding electrodes was performed. Under certain conditions, P-EG-based ion-selective electrodes (ISEs) containing TFPB and plasticized with NPOE exhibited a super-Nernstian response between1×10?3and1×10?4?M Cs+, a response characteristic not observed in analogous membranes plasticized with either DOS or FPNPE.more »Additionally, the performance of P-EG-based ISEs was compared to electrodes based on two mobile ionophores, a neutral lipophilic ethylene glycol derivative (ethylene glycol monooctadecyl ether (U-EG)) and a charged metallacarborane ionophore, sodium bis(dicarbollyl)cobaltate(III) (CC). In general, P-EG-based electrodes plasticized with FPNPE yielded the best performance, with a linear range from 10-1–10-5?M Cs+, a conventional lower detection limit of8.1×10?6?M Cs+, and a response slope of 57.7?mV/decade. The pH response of P-EG ISEs containing TFPB was evaluated for membranes plasticized with either NPOE or FPNPE. In both cases, the electrodes remained stable throughout the pH range 3–12, with only slight proton interference observed below pH 3.« less

  19. Potentiometric Response Characteristics of Membrane-Based Cs + -Selective Electrodes Containing Ionophore-Functionalized Polymeric Microspheres

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peper, Shane; Gonczy, Chad

    2011-01-01

    Cs + -selective solvent polymeric membrane-based ion-selective electrodes (ISEs) were developed by doping ethylene glycol-functionalized cross-linked polystyrene microspheres (P-EG) into a plasticized poly(vinyl chloride) (PVC) matrix containing sodium tetrakis-(3,5-bis(trifluoromethyl)phenyl) borate (TFPB) as the ion exchanger. A systematic study examining the effects of the membrane plasticizers bis(2-ethylhexyl) sebacate (DOS), 2-nitrophenyl octyl ether (NPOE), and 2-fluorophenyl nitrophenyl ether (FPNPE) on the potentiometric response and selectivity of the corresponding electrodes was performed. Under certain conditions, P-EG-based ion-selective electrodes (ISEs) containing TFPB and plasticized with NPOE exhibited a super-Nernstian response between 1 × 10 ? 3 andmore » 1 × 10 ? 4 ?M Cs + , a response characteristic not observed in analogous membranes plasticized with either DOS or FPNPE. Additionally, the performance of P-EG-based ISEs was compared to electrodes based on two mobile ionophores, a neutral lipophilic ethylene glycol derivative (ethylene glycol monooctadecyl ether (U-EG)) and a charged metallacarborane ionophore, sodium bis(dicarbollyl)cobaltate(III) (CC). In general, P-EG-based electrodes plasticized with FPNPE yielded the best performance, with a linear range from 10 -1 –10 -5 ?M Cs + , a conventional lower detection limit of 8.1 × 10 ? 6 ?M Cs + , and a response slope of 57.7?mV/decade. The pH response of P-EG ISEs containing TFPB was evaluated for membranes plasticized with either NPOE or FPNPE. In both cases, the electrodes remained stable throughout the pH range 3–12, with only slight proton interference observed below pH 3. « less

  20. Interaction model of private equity and venture capital developing factors in Chile and Latin America

    E-Print Network [OSTI]

    Sevil Esteban, Ángel

    2012-01-01

    Private equity and venture capital (PE/VC) are efficient resource allocation systems that provide equity capital to selected entrepreneurs, industries or firms that contribute to advance the economic welfare of society. ...

  1. The use of footwarmers in offices for thermal comfort and energy savings in winter

    E-Print Network [OSTI]

    2015-01-01

    JE, Parsons KC. An ergonomics investigation into humanfabric (ECF). Ergonomics Building and Environment.uc/item/7vc2q28k ergonomics problematic due to the low front

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    diffusion (MGFLD) neutrino transport, including all relevant O(vc) terms. Our main motivation for carrying out this study is to compare with recent 2D models produced by other...

  3. TWO-DIMENSIONAL CORE-COLLAPSE SUPERNOVA MODELS WITH MULTI-DIMENSIONAL...

    Office of Scientific and Technical Information (OSTI)

    diffusion (MGFLD) neutrino transport, including all relevant O(vc) terms. Our main motivation for carrying out this study is to compare with recent 2D models produced by other...

  4. Cooperative research program in coal liquefaction. Quarterly report, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-12-31

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  5. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  6. Monthly Energy Review, July 1992

    SciTech Connect (OSTI)

    1992-07-27

    The Monthly Energy Review is prepared by the Energy Information Administration. Topics discussed include: Energy Overview, Energy Consumption, Petroleum, Natural Gas, Oil and Gas Resource Development, Coal, Electricity, Nuclear Energy, Energy Prices, International Energy. (VC)

  7. The use of reduced-moderation light water reactors for transuranic isotope burning in thorium fuel

    E-Print Network [OSTI]

    Lindley, Benjamin A.

    2015-02-03

    -moderation LWRs can improve TRU transmutation performance, but the VC is still severely limiting for these designs. Reduced-moderation pressurized water reactors (RMPWRs) and boiling water reactors (RBWRs) are considered in this study. Using thorium (Th) instead...

  8. Supporting Information Monodisperse PtRu Nanoalloy on Carbon

    E-Print Network [OSTI]

    Kwak, Juhyoun

    Advanced Institute of Science and Technology, Daejeon, 305-701, Korea. E-mail: joontpark.0%, Junsei) at 80 °C for 10 h. The resulting PtRu/Vc catalyst was collected by centrifugation, washed

  9. Laser direct growth of graphene on silicon substrate Dapeng Wei and Xianfan Xua)

    E-Print Network [OSTI]

    Xu, Xianfan

    will provide a new approach and platform for applications of graphene. VC 2012 American Institute of Physics-dimensional atomic-thick crystal with car- bon atoms packed in a honeycomb lattice, is regarded as one of the most

  10. Venture Capital and private equity in India : systems analysis and development framework

    E-Print Network [OSTI]

    Surineni, Shravan Kumar

    2012-01-01

    Venture Capital (VC) has been an important driver of innovation, entrepreneurship and economic growth in the U.S. and around the world for the past few decades. The astounding success of Venture Capital prompted various ...

  11. Mu2e collaboration meeting, August 7, 2009 1 August 7, 2009

    E-Print Network [OSTI]

    Gollin, George

    work · We use MATLAB as the coding environment: ­ good graphics and mathematical capabilities MATLAB used for AØ photoinjector simulations n normalized emittance 11 mmmrad; 1-v/c)-1/2 205

  12. Search for long-lived particles that decay into final states...

    Office of Scientific and Technical Information (OSTI)

    obtained are the most stringent to date. In the specific case of a model in which a Higgs boson in the mass range 125-1000mathrmGeVc2 decays into a pair of long-lived...

  13. Plan and justification for a Proof-of-Concept oil shale facility. Final report

    SciTech Connect (OSTI)

    Not Available

    1990-12-01

    The technology being evaluated is the Modified In-Situ (MIS) retorting process for raw shale oil production, combined with a Circulating Fluidized Bed Combustor (CFBC), for the recovery of energy from the mined shale. (VC)

  14. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    F. ; CERN ; Gilardoni, S. ; CERN ; et al Spectral maxima of parametric X-ray radiation (PXR) produced by 400 GeVc protons in bent silicon crystals aligned with the beam...

  15. Salinity Effects on the Degree of Hydrophobicity and Longevity for Superhydrophobic Fibrous Coatings

    E-Print Network [OSTI]

    Tafreshi, Hooman Vahedi

    -el-Hak Department of Mechanical & Nuclear Engineering, Virginia Commonwealth University, Richmond, Virginia 23284 the technology closer to large-scale submerged bodies such as submarines and ships. VC 2011 Wiley Periodicals

  16. Static and dynamic virtual channel allocation for high performance, in-order communication in on-chip networks

    E-Print Network [OSTI]

    Shim, Keun Sup

    2010-01-01

    Most routers in on-chip interconnection networks (OCINs) have multiple virtual channels (VCs) to mitigate the effects of head-of-line blocking. Multiple VCs necessitate VC allocation schemes since packets or flows must ...

  17. Core Holes At Valles Caldera - Sulphur Springs Geothermal Area...

    Open Energy Info (EERE)

    Dennis L. Nielson, Pisto Larry, C.W. Criswell, R. Gribble, K. Meeker, J.A. Musgrave, T. Smith, D. Wilson (1989) Scientific Core Hole Valles Caldera No. 2B (VC-2B), New Mexico:...

  18. Training and Development

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Training and Development Administration Assistant Vice Chancellor Lori Castro VC Business Senior Manager Conflict Resolution Nancy Heischman Training Coordinator Vacant Principal Technical Training Consultant Frank Widman Health Care Facilitator / Interim Benefits Manager Frank Trueba Disability

  19. Effects of axial plate heat conduction on the thermal performance of a laminar counterflow flat plate heat exchanger 

    E-Print Network [OSTI]

    Demko, Jonathan Alexander

    1980-01-01

    WSION TC (021, 009), T H (021, 009) ~ TS ( 021), WH (021, 009), WC (021, 009), 1PSIH (021, 00 9), PSIC (021, 009), UC (021 009) ~ UH (021, 009) ~ VC (021, 009), 2VH (0 21 ~ 009) DUNPLIST/ABC/K?I? J?TH? PSIH? WH? VH ? VH?PSIC?WC?UC ~ VC?TC C... CONTINUE DO 91 I=i N DO 91 J='I ~ N V H (I J) =- 0. 2 D 0 VC (I, J) = 0 ~ 2D0 UH(Ie J) =0 ~ 2DO UC {I ~ 3) =-0 ~ 2DO DO 76 I=1, H VH (I 1) =0 DO UH {I 1) =0 DO VC (I, N) =0. DO UC(I M) =0%DO INITIALIZE THE TEMPERATURE OP DETERMINE DYE DYS...

  20. Fermilab | Newsroom | Press Releases | March 7, 2012: Tevatron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Higgs boson between 147 and 179 GeVc2 at the 95-percent confidence level. Med Res | Hi Res Blocked from view until 3 a.m. CST. See here: http:tevnphwg.fnal.govresults...

  1. Scientific Drilling at Sulphur Springs, Valles Caldera, New Mexico...

    Open Energy Info (EERE)

    Scientific Drilling at Sulphur Springs, Valles Caldera, New Mexico- Core Hole VC-2A Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Scientific...

  2. Revisions to the Stratigraphy and Volcanology of the Post-0.5...

    Open Energy Info (EERE)

    Revisions to the Stratigraphy and Volcanology of the Post-0.5 Ma Units and the Volcanic Section of VC-1 Core Hole, Valles Caldera, New Mexico Jump to: navigation, search OpenEI...

  3. Design of gasifiers to optimize fuel cell systems

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    The objective of this project is to configure coal gasification/carbonate fuel cell systems that can significantly improve the economics, performance, and efficiency of electric power generation systems. (VC)

  4. Indoor climate control accounts for over 40% of the energy used in US residential buildings1, much of which

    E-Print Network [OSTI]

    Kamat, Vineet R.

    ) Annual Energy Outlook 2011. 2. Li, V.C. "ECC­ Material, Structural, and Durability Performance," ConcreteIndoor climate control accounts for over 40% of the energy used in US residential buildings1, much

  5. Financing Basics for RE Projects

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Developers need to find VC funds or "public funds", or: - Build small; - Use funds from family and friends; and or - Form a consortium of "many", so individual costs are low...

  6. nh gi Tn hi Ti nguyn Thin nhin do Trn du Deep Horizon Khi phc loi chim ng bin ti vng b bin Alabama

    E-Print Network [OSTI]

    ánh giá Tn hi Tài nguyên Thiên nhiên do Tràn du Deep Horizon Khôi phc loài chim ng bin ti vùng b Alabama s hình thành 5 nn làm t ca chim ng dc theo vùng b bin Mobile và Baldwin, Alabama tng c hi làm có th c tìm thy quanh nm ti khu vc b bin Alabama. Chim ng bin òi hi nhng khu vc làm t rng rãi vi

  7. Biotechnology Letters 25: 12031207, 2003. 2003 Kluwer Academic Publishers. Printed in the Netherlands.

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    (ethylene-co-vinyl acetate) or poly(styrene-co-butadiene)). After inoculation with Alcaligenes xylosoxidans, the remaining the characterization and use of two solid polymers, poly(ethylene-co-vinyl acetate), EVA, and poly(styrene diameters of 3.4 mm, and SB (28% styrene, styrene- butadiene-styrene triblock) cylinders (Aldrich) with #12

  8. What is the Real Cost of a Cotton Module Tarp? 

    E-Print Network [OSTI]

    Simpson, Shay; Searcy, Stephen W.

    2006-07-21

    tests, tarps constructed of woven poly, vinyl or fi lm have been shown to repel water. Research at Texas A&M University has shown that vinyl and fi lm tarps resist water penetration after signifi cant exposure. The performance of woven poly tarps...

  9. Polymer Reaction Engineering Laboratory -University of Maryland at College Park Book Chapters

    E-Print Network [OSTI]

    Choi, Kyu Yong

    , New York, 1983. 2. Overview of polymerization technology (K.Y. Choi), in Handbook of Polymer Science), Chapter 11, 275-298, in Handbook of Radical Vinyl Polymerization, Marcel-Dekker, 1998. 6. Technical-365, in Hanbook of Radical Vinyl Polymerization, Marcel- Dekker, 1998. 7. Fundamentals of Polymer Reaction

  10. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01

    NICKEL ARSENIDE SULFIDE NICKEL CARBONYL NICKEL REFINERY DUSTsulfide iodine pentafluoride methyl bromide methyl chloride methyl silane nickel carbonylsulfide iodine pentafluoride methyl bromide methyl chloride methyl silane nickel carbonyl

  11. Studies of the regeneration of activated bauxite used as granular...

    Office of Scientific and Technical Information (OSTI)

    GRANULAR BED FILTERS; HOT GAS CLEANUP; POTASSIUM CHLORIDES; SORPTION; SODIUM CHLORIDES; AIR POLLUTION CONTROL; COAL; FLUIDIZED-BED COMBUSTORS; ALKALI METAL COMPOUNDS; ALUMINIUM...

  12. Under consideration for publication in the Journal of Nonlinear Science 1 Spot Self-Replication and Dynamics for the Schnakenburg

    E-Print Network [OSTI]

    Ward, Michael Jeffrey

    include the ferrocyanide-iodate-sulphite reaction (cf. [28], the chloride- dioxide-malonic acid reaction

  13. Available online at www.sciencedirect.com Honeybee, Apis mellifera, round dance is influenced by

    E-Print Network [OSTI]

    Delaplane, Keith S.

    aversive components such as sodium chloride, hydrochloric acid, and quinine to sucrose solution reduced

  14. Effect of glucose and pH on the microbial flora and sensory characteristics of normal and dark, firm, dry beef steaks displayed in polyvinyl chloride film and in vacuum packages 

    E-Print Network [OSTI]

    Chesser, Linda Kay

    1982-01-01

    either in PVC film or in high-oxygen barr1er f1lm and stored 1n reta11 display cases at 2 + 1 C for 0-6 days and 0-21 days, respectively. Modification of the meat surface had no s1gnificant effect on pH, numbers and types of m1croorganisms, lean color..., odor, or f di i tio. o do aa oo. d s. ~th h cta dom1nant and/or made up a cons1derable part of the microflora of normal and DFD beef steaks, with and without added glucose or acid, stored for 0-6 days in PVC film. Lactic aci d bacteria constituted a...

  15. Hydrolysis of ZrCl4 and HfCl4: The Initial Steps in the High-Temperature Oxidation of Metal Chlorides to Produce ZrO2 and HfO2

    SciTech Connect (OSTI)

    Fang, Zongtang; Dixon, David A.

    2013-03-08

    The gas-phase hydrolysis of MCl4 (M = Zr, Hf) to produce the initial particles on the way to zirconia and hafnia nanoparticles has been studied with electronic structure theory. The potential energy surfaces, the themochemistry of the reaction species, and the reaction paths for the initial steps of MCl4 reacting with H2O have been calculated. The hydrolysis of MCl4 at higher temperatures begins with the formation of oxychlorohydroxides followed by the elimination of HCl instead of the direct production of MOCl2 and HCl or MO2 and HCl due to the substantial endothermicities associated with the formation of gas-phase MO2. The structural properties and heats of formation of the reactants and products are consistent with the available experimental results. A number of metal oxychlorides (oxychlorohydroxides) intermediate clusters have been studied to assess their role in the production of MO2 nanoparticles. The calculated clustering reaction energies of those intermediates are highly exothermic, so they could be readily formed in the hydrolysis process. These intermediate clusters can be formed exothermically from metal oxychlorohydroxides by the elimination of one HCl or H2O molecule. Our calculations show that the mechanisms leading to the formation of MO2 nanoparticles are complicated and are accompanied by the potential production of a wide range of intermediates, as found for the production of TiO2 particles from the high-temperature oxidation of TiCl4.

  16. CO2-H2O Mixtures in the Geological Sequestration of CO2. II. Partitioning in Chloride Brines at 12-100 °C and 1-600 bar.

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby a contractorEnergy, science, and7451 CleanPLASMAS,CO N c

  17. 2 0 10 T H I E M E S T U T T G A R T N E W YO R K 197 Metal-Catalyzed

    E-Print Network [OSTI]

    Charette, André

    allylic alcohols boron­zinc exchange L. E. ZIMMER, A. B. CHARETTE* (UNIVERSITÉ DE MONTRÉAL, CANADA with other couping partners (iodoaryls, vinyl bromide, and styryl iodide). 62­75% yield Reactions with (Z

  18. An Overview of the Louisiana Forest Products Development Center &

    E-Print Network [OSTI]

    with Vinyl Decorating Layer Bio-Fiber/ Polymer Composites Mixed Hardwoods and Comrind OSB #12;New Product Center #12;Wood Quality #12;Recycling Treated Wood #12;Recycling Agricultural/ Wood Residues #12;Wood

  19. The development of palladium-catalysts for organic synthesis

    E-Print Network [OSTI]

    Martinelli, Joseph R

    2007-01-01

    Chapter 1. Suzuki-Miyaura coupling reactions of aryl and heteroaryl halides with aryl-, heteroaryl and vinyl boronic acids proceed in very good to excellent yield with the use of 2-(2',6'-dimethoxybiphenyl)-dicyclohexylphosphine, ...

  20. The effect of moisture on a glass/epoxy composite 

    E-Print Network [OSTI]

    Chatawanich, Candy Suda

    1996-01-01

    Research was done to determine the effect of moisture on the transverse tensile strength and the interfacial shear strength of a glass/epoxy composite. Specimens with two different fiber sizings, one epoxy compatible and one vinyl-ester compatible...