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Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents (OSTI)

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M. (Stanford, CA); Muller, Jochen A. (Baltimore, MD); Rosner, Bettina M. (Berlin, DE); Von Abendroth, Gregory (Nannhein, DE); Meshulam-Simon, Galit (Los Altos, CA); McCarty, Perry L (Stanford, CA)

2011-11-22T23:59:59.000Z

2

Genome Sequence of the Ethene- and Vinyl Chloride-Oxidizing Actinomycete Nocardioides sp Strain JS614  

Science Conference Proceedings (OSTI)

Nocardioides sp. strain JS614 grows on ethene and vinyl chloride (VC) as sole carbon and energy sources and is of interest for bioremediation and biocatalysis. Sequencing of the complete genome of JS614 provides insight into the genetic basis of alkene oxidation, supports ongoing research into the physiology and biochemistry of growth on ethene and VC, and provides biomarkers to facilitate detection of VC/ethene oxidizers in the environment. This is the first genome sequence from the genus Nocardioides and the first genome of a VC/ethene-oxidizing bacterium.

Coleman, Nicholas V [University of Sydney, Australia; Wilson, Neil L [University of Sydney, Australia; Barry, Kerrie [U.S. Department of Energy, Joint Genome Institute; Bruce, David [Los Alamos National Laboratory (LANL); Copeland, A [U.S. Department of Energy, Joint Genome Institute; Dalin, Eileen [U.S. Department of Energy, Joint Genome Institute; Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Glavina Del Rio, Tijana [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Hammon, Nancy [U.S. Department of Energy, Joint Genome Institute; Han, Shunsheng [Los Alamos National Laboratory (LANL); Hauser, Loren John [ORNL; Israni, Sanjay [U.S. Department of Energy, Joint Genome Institute; Kim, Edwin [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Lapidus, Alla L. [U.S. Department of Energy, Joint Genome Institute; Larimer, Frank W [ORNL; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Richardson, Paul [U.S. Department of Energy, Joint Genome Institute; Schmutz, Jeremy [Stanford University; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Thompson, Sue [Los Alamos National Laboratory (LANL); Tice, Hope [U.S. Department of Energy, Joint Genome Institute; Spain, Jim C [Georgia Institute of Technology; Gossett, James G [Cornell University; Mattes, Timothy E [University of Iowa

2011-01-01T23:59:59.000Z

3

Why sequence ethene and vinyl chloride-oxidizing Mycobacterium strains?  

NLE Websites -- All DOE Office Websites (Extended Search)

sequence ethene and vinyl sequence ethene and vinyl chloride-oxidizing Mycobacterium strains? Mycobacteria are known for causing human and animal diseases but they are also important degraders of hard-to-break-down water contaminants such as polyaromatic hydrocarbons (PAHs) and methyl tert-butyl ether (MTBE). So far the handful of bacterial species representing the Mycobacterium genus that have been sequenced all break down PAHs. In this project, researchers focus on the genomes of mycobacterial species isolated from soil, freshwater and marine environments that use the alkene compounds ethene and vinyl chloride as carbon sources. Chlorinated ethene compounds are difficult to remove from contaminated groundwater but necessary because of their toxicity. Additionally these compounds reduce the ozone levels in the atmosphere.

4

VC-dimension and shortest path algorithms  

Science Conference Proceedings (OSTI)

We explore the relationship between VC-dimension and graph algorithm design. In particular, we show that set systems induced by sets of vertices on shortest paths have VC-dimension at most two. This allows us to use a result from learning theory to improve ...

Ittai Abraham; Daniel Delling; Amos Fiat; Andrew V. Goldberg; Renato F. Werneck

2011-07-01T23:59:59.000Z

5

Experimental Pathology Laboratories, Inc. Vinyl Chloride  

E-Print Network (OSTI)

, and Research (CEDR), Phi Delta Kappa International, 1999. 37. Sorenson SB, Peterson JG, Richardson BA. Child

Bandettini, Peter A.

6

Selected data fron continental scientific drilling core holes VC-1 and VC-2a, Valles Caldera, New Mexico  

DOE Green Energy (OSTI)

This report presents geochemical and isotopic data on rocks and water and wellbore geophysical data from the Continental Scientific Drilling Program core holes VC-1 and VC-2a, Valles Caldera, New Mexico. These core holes were drilled as a portion of a broader program that seeks to answer fundamental questions about magma, water/rock interactions, ore deposits, and volcanology. The data in this report will assist the interpretation of the hydrothermal system in the Jemez Mountains and will stimulate further research in magmatic processes, hydrothermal alteration, ore deposits, hydrology, structural geology, and hydrothermal solution chemistry. 37 refs., 36 figs., 28 tabs.

Musgrave, J.A.; Goff, F.; Shevenell, L.; Trujillo, P.E. Jr.; Counce, D.; Luedemann, G.; Garcia, S.; Dennis, B.; Hulen, J.B.; Janik, C.; Tomei, F.A.

1989-02-01T23:59:59.000Z

7

Preparation of vinyl acetate  

DOE Patents (OSTI)

This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

Tustin, Gerald Charles (Kingsport, TN); Zoeller, Joseph Robert (Kingsport, TN); Depew, Leslie Sharon (Kingsport, TN)

1998-01-01T23:59:59.000Z

8

Preparation of vinyl acetate  

DOE Patents (OSTI)

This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

1998-03-24T23:59:59.000Z

9

Vinyl Siding Institute (VSI) | Open Energy Information  

Open Energy Info (EERE)

profile. Create one now Vinyl Siding Institute (VSI) is a company located in Washington, DC. References Retrieved from "http:en.openei.orgwindex.php?titleVinylSidingInstitu...

10

K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles...  

Open Energy Info (EERE)

icon K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Jump to: navigation,...

11

Chloride 2011  

Science Conference Proceedings (OSTI)

Aug 2, 2010 ... Recovery of Precious Metals from Chloride Media Using Microalgae Waste from Biofuel Extraction · Segregation Roasting of a Saprolitic ...

12

K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Details Activities (2) Areas (1) Regions (0) Abstract: Seventeen K/Ar dates were obtained on illitic clays within Valles caldera (1.13 Ma) to investigate the impact of hydrothermal alteration on Quaternary to Precambrian intracaldera and pre-caldera rocks in a large,

13

Research Needs: Glass Solar Reflectance and Vinyl Siding  

NLE Websites -- All DOE Office Websites (Extended Search)

Research Needs: Glass Solar Reflectance and Vinyl Siding Title Research Needs: Glass Solar Reflectance and Vinyl Siding Publication Type Report LBNL Report Number LBNL-5022E Year...

14

Emulsion polymerization of ethylene-vinyl acetate-branched vinyl ester using a pressure reactor system.  

E-Print Network (OSTI)

??A new pressure reactor system was designed to synthesize a novel branched ester-ethylene-vinyl acetate (BEEVA) emulsion polymer. The reactor system was capable of handling pressure… (more)

Tan, Chee Boon.

2008-01-01T23:59:59.000Z

15

Atmospheric Methyl Chloride  

NLE Websites -- All DOE Office Websites (Extended Search)

steel flasks and methyl chloride concentrations were measured using an Electron Capture Gas Chromatograph. Concentrations are reported as mixing ratios in dry air. The...

16

LBNL-5022E Research Needs: Glass Solar Reflectance and Vinyl...  

NLE Websites -- All DOE Office Websites (Extended Search)

022E Research Needs: Glass Solar Reflectance and Vinyl Siding Authors: R. Hart*, C. Curcija, D. Arasteh, H. Goudey, C. Kohler, S. Selkowitz Environmental Energy Technologies...

17

Production of methyl-vinyl ketone from levulinic acid  

DOE Patents (OSTI)

A method for converting levulinic acid to methyl vinyl ketone is described. The method includes the steps of reacting an aqueous solution of levulinic acid, over an acid catalyst, at a temperature of from room temperature to about 1100 K. Methyl vinyl ketone is thereby formed.

Dumesic, James A. (Verona, WI); West; Ryan M. (Madison, WI)

2011-06-14T23:59:59.000Z

18

Environmental sampling and mud sampling program of CSDP (Continental Scientific Drilling Program) core hole VC-2B, Valles Caldera, New Mexico  

DOE Green Energy (OSTI)

An environmental sampling and drilling mud sampling program was conducted during the drilling operations of Continental Scientific Drilling Program (CSDP) core hole VC-2B, Valles caldera, New Mexico. A suite of four springs and creeks in the Sulphur Springs area were monitored on a regular basis to ensure that the VC-2B drilling program was having no environmental impact on water quality. In addition, a regional survey of springs in and around the Jemez Mountains was conducted to provide background data for the environmental monitoring. A drilling mud monitoring program was conducted during the operations to help identify major fluid entries in the core hole. 32 refs., 14 figs., 7 tabs.

Meeker, K.; Goff, F.; Gardner, J.N.; Trujillo, P.E.; Counce, D.

1990-03-01T23:59:59.000Z

19

The impact of improved materials in poly(vinyl chloride)-based endotracheal tubes  

E-Print Network (OSTI)

Endotracheal tubes (ETs) are used to aid artificial ventilation in millions of medical patients every year and are known to invoke the proliferative phase in the cell linings. The technical objective of this work was to ...

Domike, Kristin Rebecca, 1981-

2004-01-01T23:59:59.000Z

20

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network (OSTI)

Conceived and designed the experiments: PJM SFB FEL AMS.Performed the experiments: PJM SFB KMR.Analyzed the data: PJM SFB JAM JG KMR RW EG AL SH FEL AMS.

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

ORIGINAL PAPER Natural Fiber Reinforced Poly(vinyl chloride) Composites: Effect  

E-Print Network (OSTI)

, electric wires, window profiles, siding, etc. Recently, wood fiber reinforced PVC is getting more popular straw, rice husk, and pine fiber) and loading level of styrene-ethylene-butylene-styrene (SEBS) block copolymer on composite properties was investigated. Mechanical analysis showed that storage modulus

22

Chloride removal from vitrification offgas  

Science Conference Proceedings (OSTI)

This study identified and investigated techniques of selectively purging chlorides from the low-level waste (LLW) vitrification process with the purge stream acceptable for burial on the Hanford Site. Chlorides will be present in high concentration in several individual feeds to the LLW Vitrification Plant. The chlorides are highly volatile in combustion type melters and are readily absorbed by wet scrubbing of the melter offgas. The Tank Waste Remediation System (TWRS) process flow sheets show that the resulting chloride rich scrub solution is recycled back to the melter. The chlorides must be purged from the recycle loop to prevent the buildup of excessively high chloride concentrations.

Slaathaug, E.J. [Westinghouse Hanford Co., Richland, WA (United States)

1995-06-01T23:59:59.000Z

23

Life Cycle Management Planning at V.C. Summer Nuclear Plant: Main Condenser, Radiation Monitoring System, and Nuclear Safety-Related HVAC Chilled Water  

Science Conference Proceedings (OSTI)

As the electric power industry becomes more competitive, life cycle management (LCM) of systems, structures, and components (SSCs) becomes very important to keep the plant economically viable throughout its remaining licensed operating term (either a 40-year or 60-year term). This report provides the industry with lessons learned from applying the EPRI LCM planning process to three SSCs at V.C. Summer Generating Station.

2001-12-21T23:59:59.000Z

24

Monodisperse SiC/vinyl ester nanocomposites: Dispersant formulation, synthesis, and characterization  

E-Print Network (OSTI)

Processing and properties of SiC/vinyl ester nanocomposites.design of experiments for SiC/vinyl ester nanocomposites.of nanocrystalline cubic SiC films. Jpn. J. Appl. Phys. 37,

Yong, Virginia; Hahn, H. Thomas

2011-01-01T23:59:59.000Z

25

Research Needs: Glass Solar Reflectance and Vinyl Siding  

DOE Green Energy (OSTI)

The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

2011-07-07T23:59:59.000Z

26

Virtual Rapid Chloride Permeability Test  

Science Conference Proceedings (OSTI)

... final temperature can be manually copied to the final temperature in the test conditions box ... Type of software: Virtual testing of chloride permeability. ...

2013-06-11T23:59:59.000Z

27

Chloride Metallurgy: Process Technology Development  

Science Conference Proceedings (OSTI)

Recovery of Precious Metals from Chloride Media Using Microalgae Waste from Biofuel Extraction · Segregation Roasting of a Saprolitic Laterite Ore: An ...

28

Gas Leak from Vinyl Taped Stainless Steel Dressing Jars  

DOE Green Energy (OSTI)

The leak rates of nitrogen gas from stainless steel dressing jars taped with 2 inch vinyl tape were measured. These results were used to calculate hydrogen leak rates from the same jars. The calculations show that the maximum concentration of hydrogen buildup in this type of container configuration will beat least 3 orders of magnitude below the lower explosion limit for hydrogen in air.

Tim Hayes

1999-03-01T23:59:59.000Z

29

Hydrothermal brecciation in the Jemez Fault zone, Valles Caldera, New Mexico: Results from CSDP (Continental Scientific Drilling Program) corehole VC-1  

DOE Green Energy (OSTI)

Paleozoic and Precambrian rocks intersected deep in Continental Scientific Drilling Program corehole VC-1, adjacent to the late Cenozoic Valles caldera complex, have been disrupted to form a spectacular breccia sequence. The breccias are of both tectonic and hydrothermal origin, and probably formed in the Jemez fault zone, a major regional structure with only normal displacement since mid-Miocene. Tectonic breccias are contorted, crushed, sheared, and granulated; slickensides are commmon. Hydrothermal breccias, by contrast, lack these frictional textures, but arej commonly characterized by fluidized matrix foliation and prominent clast rounding. Fluid inclusions in the hydrothermal breccias are dominantly two-phase, liquid-rich at room temperature, principally secondary, and form two distinctly different compositional groups. Older inclusions, unrelated to brecciation, are highly saline and homogenize to the liquid phase in the temperature range 189 to 246/sup 0/C. Younger inclusions, in part of interbreccia origin, are low-salinity and homogenize (also to liquid) in the range 230 to 283/sup 0/C. Vapor-rich inclusions locally trapped along with these dilute liquid-rich inclusions document periodic boiling. These fluid-inclusion data, together with alteration assemblages and textures as well as the local geologic history, have been combined to model hydrothermal brecciation at the VC-1 site.

Hulen, J.B.; Nielson, D.L.

1987-06-01T23:59:59.000Z

30

Chloride removal from plutonium alloy  

Science Conference Proceedings (OSTI)

SRP is evaluating a program to recover plutonium from a metallic alloy that will contain chloride salt impurities. Removal of chloride to sufficiently low levels to prevent damaging corrosion to canyon equipment is feasible as a head-end step following dissolution. Silver nitrate and mercurous nitrate were each successfully used in laboratory tests to remove chloride from simulated alloy dissolver solution containing plutonium. Levels less than 10 ppM chloride were achieved in the supernates over the precipitated and centrifuged insoluble salts. Also, less than 0.05% loss of plutonium in the +3, +4, or +6 oxidation states was incurred via precipitate carrying. These results provide impetus for further study and development of a plant-scale process to recover plutonium from metal alloy at SRP.

Holcomb, H.P.

1983-01-01T23:59:59.000Z

31

VINYL COATING OF GRAPHITE PLATES FOR ULTRASONIC INSPECTION  

SciTech Connect

A process has been developed for application of a thin, adherent vinyi plastic coating to graphite plates to prevent absorption of coupling fluids'' used in ultrasonic inspection. The plates are preheated and dipped mechanically in a fluid plastisol, and the resulting coating is fused in an infra-red heater. No significant attenuation of ultrasonic impulse results from presence of the coating. After inspection, the vinyl sheath may be easily stripped from the plate. (auth)

Church, J.S.; Bell, J.H. Jr.; Donahoe, J.K.; Faussone, R.A.; Rogers, G.B.; Rowen, J.T.

1958-03-25T23:59:59.000Z

32

Vinyl Kraft Windows and Doors | Open Energy Information  

Open Energy Info (EERE)

Vinyl Kraft Windows and Doors Vinyl Kraft Windows and Doors Jump to: navigation, search Name Vinyl Kraft Windows and Doors Address 3404 Rhodes Ave Place New Boston, Ohio Zip 45662 Sector Buildings, Efficiency, Services Product Business and legal services;Consulting;Energy audits/weatherization; Installation; Maintenance and repair;Manufacturing; Retail product sales and distribution Phone number 740-464-0144 Website http://www.vinylkraft.com Coordinates 38.7456°, -82.9459° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.7456,"lon":-82.9459,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

33

CHLORIDE WASHER PERFORMACE TESTING  

SciTech Connect

Testing was performed to determine the chloride (Cl-) removal capabilities of the Savannah River National Laboratory (SRNL) designed and built Cl- washing equipment intended for HB-Line installation. The equipment to be deployed was tested using a cerium oxide (CeO2) based simulant in place of the 3013 plutonium oxide (PuO2) material. Two different simulant mixtures were included in this testing -- one having higher Cl- content than the other. The higher Cl- simulant was based on K-Area Interim Surveillance Inspection Program (KIS) material with Cl- content approximately equal to 70,000 ppm. The lower Cl- level simulant was comparable to KIS material containing approximately 8,000-ppm Cl- content. The performance testing results indicate that the washer is capable of reducing the Cl- content of both surrogates to below 200 ppm with three 1/2-liter washes of 0.1M sodium hydroxide (NaOH) solution. Larger wash volumes were used with similar results - all of the prescribed test parameters consistently reduced the Cl- content of the surrogate to a value below 200 ppm Cl- in the final washed surrogate material. The washer uses a 20-micron filter to retain the surrogate solids. Tests showed that 0.16-0.41% of the insoluble fraction of the starting mass passed through the 20-micron filter. The solids retention performance indicates that the fissile masses passing through the 20-micron filter should not exceed the waste acceptance criteria for discard in grout to TRU waste. It is recommended that additional testing be pursued for further verification and optimization purposes. It is likely that wash volumes smaller than those tested could still reduce the Cl- values to acceptable levels. Along with reduced wash volumes, reuse of the third wash volume (in the next run processed) should be tested as a wash solution minimization plan. A 67% reduction in the number of grouted paint pails could be realized if wash solution minimization testing returned acceptable results.

Coughlin, J; David Best, D; Robert Pierce, R

2007-11-30T23:59:59.000Z

34

UNDERSTANDING CURE INHIBITION IN CARBON FIBER REINFORCED VINYL ESTER RESIN COMPOSITES.  

E-Print Network (OSTI)

??The effect of neat and oxidized carbon fiber reinforcements on vinyl ester resin free radical polymerization was investigated. First, the free radical polymerization of neat… (more)

Tweed-Kent, Sean

2008-01-01T23:59:59.000Z

35

Method for the abatement of hydrogen chloride  

DOE Patents (OSTI)

A method is described for reducing the amount of hydrogen chloride contained in a gas stream by reacting the hydrogen chloride with ammonia in the gas phase so as to produce ammonium chloride. The combined gas stream is passed into a condensation and collection vessel, and a cyclonic flow is created in the combined gas stream as it passes through the vessel. The temperature of the gas stream is reduced in the vessel to below the condensation temperature of ammonium chloride in order to crystallize the ammonium chloride on the walls of the vessel. The cyclonic flow creates a turbulence which breaks off the larger particles of ammonium chloride which are, in turn, driven to the bottom of the vessel where the solid ammonium chloride can be removed from the vessel. The gas stream exiting from the condensation and collection vessel is further cleaned and additional ammonium chloride is removed by passing through additional filters.

Winston, S.J.; Thomas, T.R.

1975-11-14T23:59:59.000Z

36

Pressure and Temperature Dependence of the Reaction of Vinyl Radical with Alkenes III: Measured Rates and Predicted Product Distributions for Vinyl + Butene  

E-Print Network (OSTI)

This work reports experimental and theoretical first-order rate constants for the reaction of vinyl radical with C4H8 alkenes: 1-butene, 2-butene, and iso-butene. The experiments are performed over a temperature range of ...

Ismail, Huzeifa

37

Enhanced Chloride Monitoring for Steam Condensate Samples  

Science Conference Proceedings (OSTI)

The objective of this project was to develop to the proof-of-concept stage a system that enables the quantification of chloride (Cl) in turbine steam condensate samples. The chloride quantification system is intended to serve as an alternative to online chromatography for chloride concentration monitoring. The conceptual approach was to concentrate the ions in the steam condensate, by a predetermined factor, to a level that allowed accurate detection of chloride by ion selective electrodes (ISEs). The ab...

2012-01-31T23:59:59.000Z

38

REMOVAL OF CHLORIDE FROM AQUEOUS SOLUTIONS  

DOE Patents (OSTI)

The removal of chlorides from aqueons solutions is described. The process involves contacting the aqueous chloride containing solution with a benzene solution about 0.005 M in phenyl mercuric acetate whereby the chloride anions are taken up by the organic phase and separating the organic phase from the aqueous solutions.

Schulz, W.W.

1959-08-01T23:59:59.000Z

39

Modeling acid-gas generation from boiling chloride brines  

E-Print Network (OSTI)

distillation of a calcium-chloride-dominant brine was simulateddistillation of a calcium-chloride-dominated brine is then simulated

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

40

First CSDP (Continental Scientific Drilling Program)/thermal regimes core hole project at Valles Caldera, New Mexico (VC-1): Drilling report  

DOE Green Energy (OSTI)

This report is a review and summary of the core drilling operations of the first Valles Caldera research borehole (VC-1) under the Thermal Regimes element of the Continental Scientific Drilling Program (CSDP). The project is a portion of a broader program that seeks to answer fundamental scientific questions about magma, rock/water interactions, and volcanology through shallow (<1-km) core holes at Long Valley, California; Salton Sea, California; and the Valles Caldera, New Mexico. The report emphasizes coring operations with reference to the stratigraphy of the core hole, core quality description, core rig specifications, and performance. It is intended to guide future research on the core and in the borehole, as well as have applications to other areas and scientific problems in the Valles Caldera. The primary objectives of this Valles Caldera coring effort were (1) to study the hydrogeochemistry of a subsurface geothermal outflow zone of the caldera near the source of convective upflow, (2) to obtain structural and stratigraphic information from intracaldera rock formations in the southern ring-fracture zone, and (3) to obtain continuous core samples through the youngest volcanic unit in Valles Caldera, the Banco Bonito rhyolite (approximately 0.1 Ma). All objectives were met. The high percentage of core recovery and the excellent quality of the samples are especially notable. New field sample (core) handling and documentation procedures were successfully utilized. The procedures were designed to provide consistent field handling of the samples and logs obtained through the national CSDP.

Rowley, J.; Hawkins, W.; Gardner, J. (comps.)

1987-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Improving the thermal performance of vinyl-framed windows  

Science Conference Proceedings (OSTI)

Over the last five years, vinyl-framed windows have gained an increased market share in both new and retrofit residential construction. This success has been mainly due to their low manufacturing cost and relatively good thermal performance (i.e., total window U-values with double glazing between 0.50 Btu/h{center_dot}ft{sup 2}{center_dot}{degree}F [2.86 W/m{sup 2}{center_dot}K] and 0.30 Btu/h{center_dot}ft{sup 2}{center_dot}{degree}F [1.70 W/m{sup 2}{center_dot}K]). Turning such windows into ``superwindows,`` windows with a U-value of 0.20 Btu/h{center_dot}ft{sup 2}{center_dot}{degree}F (1.14 W/m{sup 2}{center_dot}K) or less that can act as passive solar elements even on north-facing orientations in cold climates, requires further significant decreases in heat transfer through both the glazing system and the frame/edge. Three-layer glazing systems (those with two low-emissivity coatings and a low-conductivity gas fill) offer center-of-glass U-values as low as 0.10 Btu/h{center_dot}ft{sup 2}{center_dot}{degree}F (0.57 W/m{sup 2}{center_dot}K); such glazings are being manufactured today and can be incorporated into existing or new vinyl frame profiles. This paper focuses on the use of a state-of the-art infrared imaging system and a two-dimensional finite-difference model to improve the thermal performance of commercially available vinyl profiles and glazing edge systems. Such evaluation tools are extremely useful in identifying exactly which components and design features limit heat transfer and which act as thermal short circuits. Such an analysis is not possible with conventional whole-window testing in hot boxes where testing uncertainties with superwindows are often greater than proposed improvements.

Beck, F.A.; Arasteh, D.

1992-10-01T23:59:59.000Z

42

Improving the thermal performance of vinyl-framed windows  

Science Conference Proceedings (OSTI)

Over the last five years, vinyl-framed windows have gained an increased market share in both new and retrofit residential construction. This success has been mainly due to their low manufacturing cost and relatively good thermal performance (i.e., total window U-values with double glazing between 0.50 Btu/h[center dot]ft[sup 2][center dot][degree]F [2.86 W/m[sup 2][center dot]K] and 0.30 Btu/h[center dot]ft[sup 2][center dot][degree]F [1.70 W/m[sup 2][center dot]K]). Turning such windows into superwindows,'' windows with a U-value of 0.20 Btu/h[center dot]ft[sup 2][center dot][degree]F (1.14 W/m[sup 2][center dot]K) or less that can act as passive solar elements even on north-facing orientations in cold climates, requires further significant decreases in heat transfer through both the glazing system and the frame/edge. Three-layer glazing systems (those with two low-emissivity coatings and a low-conductivity gas fill) offer center-of-glass U-values as low as 0.10 Btu/h[center dot]ft[sup 2][center dot][degree]F (0.57 W/m[sup 2][center dot]K); such glazings are being manufactured today and can be incorporated into existing or new vinyl frame profiles. This paper focuses on the use of a state-of the-art infrared imaging system and a two-dimensional finite-difference model to improve the thermal performance of commercially available vinyl profiles and glazing edge systems. Such evaluation tools are extremely useful in identifying exactly which components and design features limit heat transfer and which act as thermal short circuits. Such an analysis is not possible with conventional whole-window testing in hot boxes where testing uncertainties with superwindows are often greater than proposed improvements.

Beck, F.A.; Arasteh, D.

1992-10-01T23:59:59.000Z

43

Plug repairs of marine glass fiber / vinyl ester laminates subjected to uniaxial tension  

E-Print Network (OSTI)

Glass fiber/vinyl ester composite laminates are currently being used and proposed for the hulls, bulkheads, and superstructures of large ships. This thesis examines the effectiveness of the repair of such laminates using ...

Michelis, Alexandros

2009-01-01T23:59:59.000Z

44

Production of chlorine from chloride salts  

DOE Patents (OSTI)

A process for converting chloride salts and sulfuric acid to sulfate salts and elemental chlorine is disclosed. A chloride salt and sulfuric acid are combined in a furnace where they react to produce a sulfate salt and hydrogen chloride. Hydrogen chloride from the furnace contacts a molten salt mixture containing an oxygen compound of vanadium, an alkali metal sulfate and an alkali metal pyrosulfate to recover elemental chlorine. In the absence of an oxygen-bearing gas during the contacting, the vanadium is reduced, but is regenerated to its active higher valence state by separately contacting the molten salt mixture with an oxygen-bearing gas.

Rohrmann, Charles A. (Kennewick, WA)

1981-01-01T23:59:59.000Z

45

Irreversible gettering of thionyl chloride  

DOE Green Energy (OSTI)

The authors have successfully demonstrated the irreversible gettering of SOCl{sub 2} by ZnO/ASZMTEDA carbon over a modest temperature range. While thionyl chloride decomposition was slow below {minus}20 C, lower temperatures are expected to be less of a problem than at higher temperatures. The approximately 30 cc of thionyl chloride in a typical D-cell would require 50 g of ZnO and 107 g of ASZMTEDA carbon. Fortunately, since it is unlikely to happen at all, it is common practice to assume only one cell will fail (leak) in a given battery pack. So, one charge of getter can protect the whole battery pack. In summary, ZnO/ASZMTEDA carbon fulfills all of the requirements of an ideal getter including: irreversible binding or reaction with SOCl{sub 2}, high volumetric uptake capacity, high efficiency, non-volatile, air stable, insensitive to poisoning, non-toxic, cheap, non-corrosive, and the gettering product is not a liquid or oil that could block further flow or accessibility. Future work in this area includes incorporation of the ZnO and carbon into a structural open-celled porous monolith, as well as, gettering for other types of batteries (e.g., Li/MnO{sub 2}).

LeRoy Whinnery; Steve Goods; George Buffleben; Tim Sheppodd

1999-11-01T23:59:59.000Z

46

Chloride substitution in sodium borohydride  

Science Conference Proceedings (OSTI)

The dissolution of sodium chloride and sodium borohydride into each other resulting in formation of solid solutions of composition Na(BH{sub 4}){sub 1-x}Cl{sub x} is studied. The dissolution reaction is facilitated by two methods: ball milling or combination of ball milling and annealing at 300 deg. C for three days of NaBH{sub 4}-NaCl samples in molar ratios of 0.5:0.5 and 0.75:0.25. The degree of dissolution is studied by Rietveld refinement of synchrotron radiation powder X-ray diffraction (SR-PXD) data. The results show that dissolution of 10 mol% NaCl into NaBH{sub 4}, forming Na(BH{sub 4}){sub 0.9}Cl{sub 0.1}, takes place during ball milling. A higher degree of dissolution of NaCl in NaBH{sub 4} is obtained by annealing resulting in solid solutions containing up to 57 mol% NaCl, i.e. Na(BH{sub 4}){sub 0.43}Cl{sub 0.57}. In addition, annealing results in dissolution of 10-20 mol% NaBH{sub 4} into NaCl. The mechanism of the dissolution during annealing and the decomposition pathway of the solid solutions are studied by in situ SR-PXD. Furthermore, the stability upon hydrogen release and uptake were studied by Sieverts measurements. - Graphical Abstract: Dissolution of sodium chloride and sodium borohydride into each other resulting in formation of solid solutions of composition Na(BH{sub 4}){sub 1-x}Cl{sub x} is studied. Dissolution is facilitated by two methods: ball milling or annealing at 300 deg. C for three days of NaBH{sub 4}-NaCl samples. Sample compositions and dissolution mechanism are studied by Rietveld refinement of synchrotron radiation powder X-ray diffraction data. Highlights: > Studies of dissolution of sodium chloride and sodium borohydride into each other. > Solid state diffusion facilitated by mechanical and thermal treatments. > Dissolution is more efficiently induced by heating than by mechanical treatment. > Mechanism for dissolution studied by Rietveld refinement of in situ SR-PXD data.

Ravnsbaek, Dorthe B.; Rude, Line H. [Center for Materials Crystallography (CMC), Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C (Denmark); Jensen, Torben R., E-mail: trj@chem.au.dk [Center for Materials Crystallography (CMC), Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C (Denmark)

2011-07-15T23:59:59.000Z

47

Process for synthesis of beryllium chloride dietherate  

DOE Green Energy (OSTI)

A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

1991-01-01T23:59:59.000Z

48

An investigation in the hygrothermal degradation of an E- glass/vinyl-ester composite in humid and immersion environments  

E-Print Network (OSTI)

relaxation behavior on sized carbon fiber-vinyl ester matrixaspects of epoxy- carbon fiber composite laminates inaspects of epoxy/carbon fiber composite laminates in

Svetlik, Stephanie Laura

2008-01-01T23:59:59.000Z

49

Ethylene-Vinyl Acetate Potential Problems for Photovoltaic Packaging: Preprint  

DOE Green Energy (OSTI)

Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support, optical coupling, electrical isolation, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate, it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about ?15 C. Temperatures lower than this can be reached for extended periods of time in some climates. Because of increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL 1703.

Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K. M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

2006-05-01T23:59:59.000Z

50

EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky EA-1157: Methyl Chloride via...

51

Synthesis of vinyl acetate on palladium-based catalysts  

E-Print Network (OSTI)

Vinyl acetate (VA) is an important monomer used in the production of paints, surface coatings and adhesives. Synthesis of VA is usually carried out over supported Pd alloy catalysts with a selectivity as high as 96% and described as C2H4 + CH3COOH + ½ O2 -> C2H3OOCCH3 + H2O Although the VA synthesis reaction has been industrially carried out for many years, the nature of the active sites and the reaction mechanism is still unclear. The goal of this study was to acquire a fundamental understanding of the VA reaction mechanism by carrying out detailed kinetic and spectroscopic investigations on single crystals and supported Pd catalysts, and to detail the role of alloying in optimizing the selectivity of this important industrial reaction. A combination of surface science techniques and kinetic measurements has been used to address the mechanism. Supported catalysts, 1 wt% Pd/SiO2 and 5 wt% Pd/SiO2, and 1 wt% Pd-0.5 wt% Au/SiO2, were prepared by an incipient wet-impregnation method and characterized using XRD and TEM. On Pd-only catalysts the reaction rates were found to be: Pd(100) catalysts, which suggests a degree of structure sensitivity of the reaction. There is an increased availability of uncoordinated, edge atoms on small particles. With a Pd single crystal, fewer less-coordinated surface sites are present compared to a comparable area on a small Pd particle on a supported Pd catalyst. The formation of Pd carbide (PdCx) during the synthesis of VA was investigated over Pd/SiO2 catalysts with two different Pd particle sizes, as well as over a Pd-Au/SiO2 mixed-metal catalyst. XRD data indicate that smaller Pd particles show greater resistance to the formation of PdCx. The alloying of Au with Pd is apparently very effective in preventing PdCx formation in Pd-based catalysts for VA synthesis. Addition of Au to Pd/SiO2 catalysts significantly enhances the VA formation rate and selectivity. Infrared reflection absorption spectroscopy (IRAS) of CO on Pd/Au(100) and Pd/Au(111) confirms the presence of Pd as isolated monomers on a Au-rich surface. A pair of Pd monomers is the most favorable active site for the formation of VA. The spacing between the two active isolated Pd atoms is critical and is demonstrated by the relative rates of VA formation on Pd/Au model catalysts, i.e. Pd/Au(111) < Pd/Au(100). The role of Au is to isolate the surface Pd atoms and thus suppress the formation of by products, CO and CO2. A pair of Pd monomers required for VA synthesis is further confirmed by the results from model studies of Sn-Pd.

Kumar, Dheeraj

2006-08-01T23:59:59.000Z

52

Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Chloride and Hydrogen Sulfide Hydrogen Chloride and Hydrogen Sulfide Removal Sorbents for High Temperature Gas Streams Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,767,000 entitled "Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams." Disclosed in this patent is the invention of a unique regenerable sorbent process that can remove contaminants from gas produced by the gasification of fossil fuels. Specifically, the process removes hydrogen chloride by using the regenerable sorbent and simultaneously extracts hydrogen chloride compounds and hydrogen

53

Absorption media for irreversibly gettering thionyl chloride  

DOE Patents (OSTI)

Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

Buffleben, George (Tracy, CA); Goods, Steven H. (Livermore, CA); Shepodd, Timothy (Livermore, CA); Wheeler, David R. (Albuquerque, NM); Whinnery, Jr., LeRoy (Danville, CA)

2002-01-01T23:59:59.000Z

54

Viscosity and density tables of sodium chloride solutions  

DOE Green Energy (OSTI)

A file is presented containing tabulated data extracted from the scientific literature on the density and viscosity of aqueous sodium chloride solutions. Also included is a bibliography of the properties of aqueous sodium chloride solutions. (MHR)

Fair, J.A.; Ozbek, H. (comps.) [comps.

1977-04-01T23:59:59.000Z

55

Effect of incorporating cellulose nanocrystals from corncob on the tensile, thermal and barrier properties of poly(vinyl alcohol) nanocomposites  

Science Conference Proceedings (OSTI)

The effect of incorporating cellulose nanocrystals fromcorncob (CNC) on the tensile, thermal, and barrier properties of poly(vinyl alcohol) (PVA) nanocomposites was evaluated. The CNC were prepared by sulfuric acid hydrolysis at 45°C for 60 minutes, ...

Hudson Alves Silvério, Wilson Pires Flauzino Neto, Daniel Pasquini

2013-01-01T23:59:59.000Z

56

Chloride-Exposed Steel-Reinforced Concrete Service Life ...  

Science Conference Proceedings (OSTI)

Chloride-Exposed Steel-Reinforced Concrete Service Life Prediction Program. Description/Summary: (Return to Cement ...

2013-06-11T23:59:59.000Z

57

Method for the regeneration of spent molten zinc chloride  

DOE Patents (OSTI)

In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

1981-01-01T23:59:59.000Z

58

Solution-Derived, Chloride-Containing Minerals as a Waste Form for Alkali Chlorides  

SciTech Connect

Sodalite [Na8(AlSiO4)6Cl2] and cancrinite [(Na,K)6Ca2Al6Si6O24Cl4] are environmentally stable, chloride-containing minerals and are a logical waste form option for the mixed alkali chloride salt waste stream that is generated from a proposed electrochemical separations process during nuclear fuel reprocessing. Due to the volatility of chloride salts at moderate temperatures, the ideal processing route for these salts is a low-temperature approach such as the sol-gel process. The sodalite structure can be easily synthesized by the sol-gel process; however, it is produced in the form of a fine powder with particle sizes on the order of 1–10 µm. Due to the small particle size, these powders require additional treatment to form a monolith. In this study, the sol-gel powders were pressed into pellets and fired to achieve > 90% of theoretical density. The cancrinite structure, identified as the best candidate mineral form in terms of waste loading capacity, was only produced on a limited basis following the sol-gel process and converted to sodalite upon firing. Here we discuss the sol-gel process specifics, chemical durability of select waste forms, and the steps taken to maximize chloride-containing phases, decrease chloride loss during pellet firing, and increase pellet densities.

Riley, Brian J.; Crum, Jarrod V.; Matyas, Josef; McCloy, John S.; Lepry, William C.

2012-10-01T23:59:59.000Z

59

Index of Semiconductor Process Gases  

Science Conference Proceedings (OSTI)

... Hydrogen Bromide, HBr. Vinyl Fluoride. C 2 H 3 F. Hydrogen Chloride, HCl. Vinyl Chloride. C 2 H 3 Cl. Hydrogen Fluoride, HF. Trimethyl Gallium. ...

2012-07-27T23:59:59.000Z

60

Recovery of Precious Metals from Chloride Media Using Microalgae ...  

Science Conference Proceedings (OSTI)

Presentation Title, Recovery of Precious Metals from Chloride Media Using Microalgae Waste from Biofuel Extraction. Author(s), Katsutoshi Inoue, Kanjana ...

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

VOLATILE CHLORIDE PROCESS FOR THE RECOVERY OF METAL VALUES  

DOE Patents (OSTI)

A process is presented for recovering uranium, iron, and aluminum from centain shale type ores which contain uranium in minute quantities. The ore is heated wiih a chlorinating agent. such as chlorine, to form a volatilized stream of metal chlorides. The chloride stream is then passed through granular alumina which preferentially absorbs the volatile uranium chloride and from which the uranium may later be recovered. The remaining volatilized chlorides, chiefly those of iron and aluminum, are further treated to recover chlorine gas for recycle, and to recover ferric oxide and aluminum oxide as valuable by-products.

Hanley, W.R.

1959-01-01T23:59:59.000Z

62

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

DOE Green Energy (OSTI)

A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by ATR-FTIR and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2 percent VEC at 4.1 V showed the presence of a high molecular weight polymer. IR analysis indicated polycarbonate with alkyl carbonate rings linked by aliphatic methylene and methyl branches.

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-02-28T23:59:59.000Z

63

Effects of ?/? Orientation Relationship on VC Interphase ...  

Science Conference Proceedings (OSTI)

D8: Study of Rack and Chord Assembly Formability for Jack-up Platforms ... Zone of Zr-Ti Microalloyed High-strength High-toughness Offshore Structural Steels.

64

EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

57: Methyl Chloride via Oxyhydrochlorination of Methane: A 57: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky SUMMARY This EA evaluates the environmental impacts for the proposal to advance Oxyhydrochlorination technology to an integrated engineering-scale process. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD September 27, 1996 EA-1157: Finding of No Significant Impact Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas September 27, 1996 EA-1157: Final Environmental Assessment Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for

65

A method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents (OSTI)

A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

Pereira, Candido

1997-08-11T23:59:59.000Z

66

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents (OSTI)

A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

Pereira, C.

1999-02-23T23:59:59.000Z

67

CHLORIDE DEPOSITION FROM STEAM ONTO SUPERHEATER FUEL CLAD MATERIALS  

SciTech Connect

Experimemts using Cl/sup 36/ in a steam test loop were conducted to study the deposition behavior of chlorides on BONUS superheater fuel assembly materials. The moisture content of the steam was varied between 0 and 0.5 wt%, and superheat was added up to 15 deg F before the steam passed over the test cartridge heater. The effects of vaiiables on the chloride deposition on the heater were studied in detail. Chloride deposition from moist steam was found to result in heavy, adherent deposits which are conducive to severe chloride stress corrosion of austenitic steels, while removal of all moisture from the incoming steam reduces the chloride deposition and minimizes the chloride stress corrosion. The heater surface condition was found to be a very important variable; deposition is increased by surface defects and pits. Neither the temperature of steam or heater nor the amount of superheat had an appreciable effect on the deposition, when no moisture existed in the steam. However, low steam velocities and spacer protoberances increase the deposition. Different clad materials (Inconel and Type 304 and 347 stainless steel) with similar surface conditions did not affect the deposition, although subsequent corrosion effects do modify the deposition behavior. Recommendations are given for the control of chloride deposition in nuclear superheater reactor systems. (D.L.C.)

Bevilacqua, F.; Brown, G.M.

1963-10-18T23:59:59.000Z

68

Method for the production of uranium chloride salt  

DOE Patents (OSTI)

A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

Westphal, Brian R.; Mariani, Robert D.

2013-07-02T23:59:59.000Z

69

What’s in Your Water?  

E-Print Network (OSTI)

vinyl chloride, and carbon dioxide under methanogenicof  nitrogen  and  carbon   dioxide,  to  maintain  an  

Polasko, Alexandra

2013-01-01T23:59:59.000Z

70

Hydrogen chloride in superheated steam and chloride in deep brine at The Geysers geothermal field, California  

SciTech Connect

Chloride (Cl) concentrations of 10-120 ppm{sub w} have been measured in superheated steam produced by wells at The Geysers, a vapor-dominated geothermal field in northern California. Corrosion of the well casing and steam-gathering system has been recognized in some parts of The Geysers, and is apparently related to the presence of Cl. Cl in the steam is in a volatile form, generated with the steam at reservoir temperatures, and probably travels to the wellhead as HCl gas. Published experimental data for partial pressures of HCl in steam over aqueous HCl solutions and for dissociation constants of HCl were used to calculate distribution coefficients for HCl. Reservoir liquid Cl concentrations capable of generating steam with the observed Cl concentrations were then calculated as a function of pH and temperatures from 250 to 350º C. Equilibrium mineral/liquid reactions with the K-mica and K-feldspar assemblage found in the wells limit the reservoir liquid pH values at various Cl concentrations to about 5 to 6 (near neutral at 250 to 350º C). Within this pH range, liquid at 250º C could not produce steam containing the high Cl concentrations observed. However, liquid at higher temperatures (300 to 350º C) with chloride concentrations greater than 10,000 ppm{sub w} could generate steam with 10 to over 200 ppm{sub w} Cl. There is a positive correlation between pH and the chloride concentrations required to generate a given Cl concentration in steam. The concentration of Cl in superheated steam constrains not only the reservoir liquid composition, but the temperature at which the steam last equilibrated with liquid.

Haizlip, J.R.; Truesdell, A.H.

1988-01-01T23:59:59.000Z

71

Chloridizing Roasting-Smelting Reduction Methods Applied to ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy · Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

72

Automatic electrochemical ambient air monitor for chloride and chlorine  

DOE Patents (OSTI)

An electrochemical monitoring system has been provided for determining chloride and chlorine in air at levels of from about 10-1000 parts per billion. The chloride is determined by oxidation to chlorine followed by reduction to chloride in a closed system. Chlorine is determined by direct reduction at a platinum electrode in 6 M H.sub.2 SO.sub.4 electrolyte. A fully automated system is utilized to (1) acquire and store a value corresponding to electrolyte-containing impurities, (2) subtract this value from that obtained in the presence of air, (3) generate coulometrically a standard sample of chlorine mixed with air sample, and determine it as chlorine and/or chloride, and (4) calculate, display, and store for permanent record the ratio of the signal obtained from the air sample and that obtained with the standard.

Mueller, Theodore R. (Oak Ridge, TN)

1976-07-13T23:59:59.000Z

73

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera...  

Open Energy Info (EERE)

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Mexico- A 36Cl Study Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

74

Plug repairs of marine glass fiber / vinyl ester laminates subjected to in-plane shear stress or in-plane bending moment  

E-Print Network (OSTI)

Glass fiber / vinyl ester composite laminates represent an important class of modem fiber composites being proposed or used in state-of-the-art shipbuilding. This thesis examined the effectiveness of chopped strand mat ...

Urrutia Valenzuela, Roberto

2010-01-01T23:59:59.000Z

75

Effect of irradiation on the surface microhardness of pure poly(vinyl fluoride), poly(vinylidene fluoride) and their isomorphic blends  

Science Conference Proceedings (OSTI)

Many widely used polymers suffer main chain scission or crosslinking depending upon various physical parameters when exposed to radiation. Crosslinking and scission are two opposite consequences of irradiation. The preparation of pure Poly(vinyl fluoride) ...

A. K. Gupta; R. Bajpai; J. M. Keller

2007-01-01T23:59:59.000Z

76

The effects of nitric acid and silane surface treatments on carbon fibers and carbon/vinyl ester composites before and after seawater exposure.  

E-Print Network (OSTI)

??This research focuses on carbon fiber treatment by nitric acid and 3- (trimethoxysilyl)propyl methacrylate silane, and how this affects carbon/vinyl ester composites. These composites offer… (more)

Langston, Tye A.

2008-01-01T23:59:59.000Z

77

Reversibly Bound Chloride in the Atrial Natriuretic Peptide Receptor Hormone Binding Domain: Possible Allosteric Regulation and a Conserved Structural Motif for the Chloride-binding Site  

SciTech Connect

The binding of atrial natriuretic peptide (ANP) to its receptor requires chloride, and it is chloride concentration dependent. The extracellular domain (ECD) of the ANP receptor (ANPR) contains a chloride near the ANP-binding site, suggesting a possible regulatory role. The bound chloride, however, is completely buried in the polypeptide fold, and its functional role has remained unclear. Here, we have confirmed that chloride is necessary for ANP binding to the recombinant ECD or the full-length ANPR expressed in CHO cells. ECD without chloride (ECD(-)) did not bind ANP. Its binding activity was fully restored by bromide or chloride addition. A new X-ray structure of the bromide-bound ECD is essentially identical to that of the chloride-bound ECD. Furthermore, bromide atoms are localized at the same positions as chloride atoms both in the apo and in the ANP-bound structures, indicating exchangeable and reversible halide binding. Far-UV CD and thermal unfolding data show that ECD(-) largely retains the native structure. Sedimentation equilibrium in the absence of chloride shows that ECD(-) forms a strongly associated dimer, possibly preventing the structural rearrangement of the two monomers that is necessary for ANP binding. The primary and tertiary structures of the chloride-binding site in ANPR are highly conserved among receptor-guanylate cyclases and metabotropic glutamate receptors. The chloride-dependent ANP binding, reversible chloride binding, and the highly conserved chloride-binding site motif suggest a regulatory role for the receptor bound chloride. Chloride-dependent regulation of ANPR may operate in the kidney, modulating ANP-induced natriuresis.

Ogawa, H.; Qiu, Y; Philo, J; Arakawa, T; Ogata, C; Misono, K

2010-01-01T23:59:59.000Z

78

Potential Problems with Ethylene-Vinyl Acetate for Photovoltaic Packaging (Poster)  

DOE Green Energy (OSTI)

Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support electrical isolation, optical coupling, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about -15 C. Temperatures lower than this can be reached for extended periods of time in some climates. Due to increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL 1703.

Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K, M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

2006-05-01T23:59:59.000Z

79

Alternate fuels and chemicals from synthesis gas: Vinyl acetate monomer. Final report  

DOE Green Energy (OSTI)

There has been a long-standing desire on the part of industry and the U.S. Department of Energy to replace the existing ethylene-based vinyl acetate monomer (VAM) process with an entirely synthesis gas-based process. Although there are a large number of process options for the conversion of synthesis gas to VAM, Eastman Chemical Company undertook an analytical approach, based on known chemical and economic principles, to reduce the potential candidate processes to a select group of eight processes. The critical technologies that would be required for these routes were: (1) the esterification of acetaldehyde (AcH) with ketene to generate VAM, (2) the hydrogenation of ketene to acetaldehyde, (3) the hydrogenation of acetic acid to acetaldehyde, and (4) the reductive carbonylation of methanol to acetaldehyde. This report describes the selection process for the candidate processes, the successful development of the key technologies, and the economic assessments for the preferred routes. In addition, improvements in the conversion of acetic anhydride and acetaldehyde to VAM are discussed. The conclusion from this study is that, with the technology developed in this study, VAM may be produced from synthesis gas, but the cost of production is about 15% higher than the conventional oxidative acetoxylation of ethylene, primarily due to higher capital associated with the synthesis gas-based processes.

Richard D. Colberg; Nick A. Collins; Edwin F. Holcombe; Gerald C. Tustin; Joseph R. Zoeller

1999-01-01T23:59:59.000Z

80

Repassivation Potential of Alloy 22 in Sodium and Calcium Chloride Brines  

SciTech Connect

A comprehensive matrix of 60 tests was designed to explore the effect of calcium chloride vs. sodium chloride and the ratio R of nitrate concentration over chloride concentration on the repassivation potential of Alloy 22. Tests were conducted using the cyclic potentiodynamic polarization (CPP) technique at 75 C and at 90 C. Results show that at a ratio R of 0.18 and higher nitrate was able to inhibit the crevice corrosion in Alloy 22 induced by chloride. Current results fail to show in a consistent way a different effect on the repassivation potential of Alloy 22 for calcium chloride solutions than for sodium chloride solutions.

Rebak, R B; Ilevbare, G O; Carranza, R M

2007-08-11T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis  

E-Print Network (OSTI)

Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis Lekha Gupta, 2008 Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C protocols with unpurified commercial samples of n-butyl- lithium to prepare LDA or commercially available

Collum, David B.

82

Oxidation of phosphine by iron(III) chloride complexes supported on activated charcoal  

SciTech Connect

It has been discovered that iron(III) chloride complexes supported on activated charcoal oxidize phosphine under normal conditions. The process accelerates as the concentration of the chloride ions and the proton acid increases.

Rakitskaya, T.L.; Kostyukova, I.S.; Red'ko, T.D.

1988-06-01T23:59:59.000Z

83

The ultra-high lime with aluminum process for removing chloride from recirculating cooling water  

E-Print Network (OSTI)

Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA). The research program was conducted to study equilibrium characteristics and kinetics of chloride removal by UHLA process, study interactions between chloride and sulfate or silica, and develop a model for multicomponent removal by UHLA. Kinetics of chloride removal with UHLA was investigated. Chloride removal was found to be fast and therefore, removal kinetics should not be a limitation to applying the UHLA process. Equilibrium characteristics of chloride removal with UHLA were characterized. Good chloride removal was obtained at reasonable ranges of lime and aluminum doses. However, the stoichiometry of chloride removal with UHLA deviated from the theoretical stoichiometry of calcium chloroaluminate precipitation. Equilibrium modeling of experimental data and XRD analysis of precipitated solids indicated that this deviation was due to the formation of other solid phases such as tricalcium hydroxyaluminate and tetracalcium hydroxyaluminate. Effect of pH on chloride removal was characterized. Optimum pH for maximum chloride removal was pH 12 ± 0.2. Results of equilibrium experiments at different temperatures indicated that final chloride concentrations slightly increased when water temperature increased at temperatures below 40oC. However, at temperatures above 40oC, chloride concentration substantially increased with increasing water temperature. An equilibrium model was developed to describe chemical behavior of chloride removal from recycled cooling water using UHLA. Formation of a solid solution of calcium chloroaluminate, tricalcium hydroxyaluminate, and tetracalcium hydroxyaluminate was found to be the best mechanism to describe the chemical behavior of chloride removal with UHLA. Results of experiments that studied interactions between chloride and sulfate indicated that sulfate is preferentially removed over chloride. Final chloride concentration increased with increasing initial sulfate concentration. Silica was found to have only a small effect on chloride removal. The equilibrium model was modified in order to include sulfate and silica reactions along with chloride in UHLA process and it was able to accurately predict the chemical behavior of simultaneous removal of chloride, sulfate, and silica with UHLA.

Abdel-wahab, Ahmed Ibraheem Ali

2005-05-01T23:59:59.000Z

84

Properties of thermo-chemically surface treated carbon fibers and of their epoxy and vinyl ester composites  

SciTech Connect

High strength carbon fibers were surface treated by a continuous gas phase thermo-chemical surface treatment. The surface and the mechanical properties of the fibers were investigated before and after treatment and compared to the properties obtained with a conventional industrial electro-chemical surface treatment. An increase of the oxygen atomic content from 3 % to 20 % with a preferential generation of carboxylic acid functionalities and hydroxyl groups was highlighted after the thermo-chemical surface treatment, compared to an oxygen atomic content of 7 % and a wide variety of oxygen moieties with the electro-chemical surface treatment. The tensile strength of the fibers increased slightly after the thermo-chemical surface treatment and remained the same after the electro-chemical surface treatment. Short beam shear and 90 flexural tests of composites revealed that the improvement of interfacial adhesion with a vinyl ester matrix was limited, revealing that oxidation of the carbon fiber surface alone cannot tremendously improve the mechanical properties of carbon fiber-vinyl ester composites. Atomic force microscopy showed that the creation of roughness with both surface treatments at a nanometric scale. Although the surface is slightly rougher after the electro-chemical surface treatment and is expected to lead to higher adhesion due to mechanical interlocking between the fiber surface and the matrix, the effect of covalent bonding coming from the high concentration of chemical groups on the surface results in higher adhesion strength, as obtained with the thermo-chemical surface treatment.

Vautard, Frederic [ORNL; Ozcan, Soydan [ORNL; Meyer III, Harry M [ORNL

2012-01-01T23:59:59.000Z

85

Poly(vinyl alcohol)-based buffering membranes for isoelectric trapping separations  

E-Print Network (OSTI)

Isoelectric trapping (IET) in multicompartment electrolyzers (MCE) has been widely used for the electrophoretic separation of ampholytic compounds such as proteins. In IET, the separation occurs in the buffering membranes that form a step-wise pH gradient in the MCE. Typically, buffering membranes have been made by copolymerizing acrylamide with Immobiline compounds, which are acidic and basic acylamido buffers. One major problem, however, is that these buffering membranes are not stable when exposed to high concentrations of acid and base due to hydrolysis of the amide bonds. Poly(vinyl alcohol)-based, or PVA-based, membranes were made as an alternative to the polyacrylamide-based membranes since they provide more hydrolytic and mechanical stability. Four mid-pH, PVA-based buffering membranes that contain single ampholytes were synthesized. These buffering membranes were used to trap small molecular weight pI markers for up to three hours, and were also used in desalting experiments to remove strong electrolytes from a solution of ampholytes. Additionally, the membranes were used in IET experiments to separate mixtures of pI markers, and to fractionate the major proteins in chicken egg white. The membranes did not show any degradation when stored in 3 M NaOH for up to 6 months and were shown to tolerate current densities as high as 16 mA/cm2. In addition, six series of PVA-based membranes, whose pH values can be tuned over the 3 < pH < 10 range, were synthesized by covalently binding aminodicarboxylic acids, and monoamines or diamines to the PVA matrix. These tunable buffering membranes were used in trapping experiments to trap ampholytes for up to three hours, and in desalting experiments to remove strong electrolytes from a solution of ampholytes. These tunable buffering membranes were also used in IET experiments to separate proteins, some with pI values that differ by only 0.1 pH unit. The tunable buffering membranes did not show any signs of degradation when exposed to 3 M NaOH for up to 3 months, and could be used in IET experiments with current densities as high as 20 mA/cm2. These tunable buffering membranes are expected to broaden the application areas of isoelectric trapping separations.

Craver, Helen C.

2007-05-01T23:59:59.000Z

86

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

Thermophysical Properties of Sodium Nitrate and Sodium Chloride Thermophysical Properties of Sodium Nitrate and Sodium Chloride Solutions and Their Effects on Fluid Flow in Unsaturated Media Tianfu Xu and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT. Understanding movement of saline sodium nitrate (NaNO 3 ) waste solutions is important for assessing the contaminant migration near leaking waste storage tanks in the unsaturated zone at the Hanford site (Washington, USA). The purpose of this study is to contribute a basic understanding of effects of the thermophysical behavior of NaNO 3 solutions on fluid flow in unsaturated media. We first present mathematical expressions for the dependence of density, viscosity, solubility and vapor pressure of

87

Mathematical Model of a Lithium/Thionyl Chloride Battery  

DOE Green Energy (OSTI)

A mathematical model of a spirally wound lithium/thionyl chloride primary battery has been developed ~d used for parameter estimation and design studies. The model formulation is based on the fimdarnental Consemation laws using porous electrode theory and concentrated solution theory. The model is used to estimate the difision coefficient and the kinetic parameters for the reactions at the anode and the cathode as a function of temperature. These parameters are obtained by fitting the simulated capacity and average cell voltage to experimental data over a wide range of temperatures (-55 to 49"C) and discharge loads (10 to 250 ohms). The experiments were performed on D-sized, cathode-limited, spirally wound lithium/thionyl chloride cells. The model is also used to study the effkct of cathode thickness on the cell capacity as a finction of temperature, and it was found that the optimum thickness for the cathode- limited design is temperature and load dependent.

Jain, M.; Jungst, R.G.; Nagasubramanian, G.; Weidner, J.W.

1998-11-24T23:59:59.000Z

88

Thionyl-chloride-induced lung injury and bronchiolitis obliterans  

SciTech Connect

Thionyl-chloride (TCl) is used in the manufacture of lithium batteries, producing SO2 and HCl fumes on contact with water. We report two cases of accidental TCl exposure resulting in lung injury that may vary from a relatively mild and reversible interstitial lung disease to a severe form of bronchiolitis obliterans causing, after a latent period, an acute/chronic respiratory failure as well as other complications (spontaneous pneumothorax and bronchopleural fistula), previously unreported in TCl fume inhalation.

Konichezky, S.; Schattner, A.; Ezri, T.; Bokenboim, P.; Geva, D. (Kaplan Hospital, Rehovot (Israel))

1993-09-01T23:59:59.000Z

89

Plutonium metal and alloy preparation by molten chloride reduction  

Science Conference Proceedings (OSTI)

Satisfactory reduction of molten plutonium trichloride (pure and in combination with 20 wt % sodium chloride) by calcium, lanthanum, and cerium has been demonstrated on the 10-g scale. The yields were satisfactory for this scale of operation, and it is indicated that these reductions may be useful for large-scale operations. Significant separations of plutonium from rare earth impurities was demonstrated for lanthanum and cerium reductions. Preparation of plutonium-cerium and plutonium-cerium-cobalt alloys during reduction was also demonstrated.

Reavis, J.G.

1984-01-01T23:59:59.000Z

90

Development of the Zinc-Chloride Battery for Utility Applications  

Science Conference Proceedings (OSTI)

This report reviews progress in Phase 2 (April 1978-March 1980) of a program to develop the zinc-chloride battery for utility load-leveling applications. Tasks in this phase included refurbishment of a 45-kWh module to increase capacity and efficiency, cycle testing of a 1.7-kWh battery, and development of a 50-kWh module to serve as the building block for the 4-MWh battery for the Battery Energy Test Facility.

1980-05-01T23:59:59.000Z

91

Uranium chloride extraction of transuranium elements from LWR fuel  

DOE Patents (OSTI)

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800 C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein. 1 figure.

Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

1992-08-25T23:59:59.000Z

92

Uranium chloride extraction of transuranium elements from LWR fuel  

DOE Patents (OSTI)

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800.degree. C. to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein.

Miller, William E. (Naperville, IL); Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Pierce, R. Dean (Naperville, IL)

1992-01-01T23:59:59.000Z

93

Uptake of chloride and carbonate ions by calcium monosulfoaluminate hydrate  

Science Conference Proceedings (OSTI)

Decommissioning of old nuclear reactors may produce waste streams containing chlorides and carbonates, including radioactive {sup 36}Cl{sup -} and {sup 14}CO{sub 3}{sup 2-}. Their insolubilization by calcium monosulfoaluminate hydrate was investigated. Carbonates were readily depleted from the solution, giving at thermodynamic equilibrium monocarboaluminate, monocarboaluminate + calcite, or calcite only, depending on the initial ratio between the anion and calcium monosulfoaluminate hydrate. Chloride ions reacted more slowly and were precipitated as Kuzel's salt, Kuzel's and Friedel's salts, or Friedel's salt only. Rietveld refinement of X-Ray powder diffraction patterns was successfully used to quantify the phase distributions, which were compared to thermodynamic calculations. Moreover, analysing the lattice parameters of Kuzel's salt as a function of its chloride content showed the occurrence of a restricted solid solution towards the sulfate side with general formula 3CaO{center_dot}Al{sub 2}O{sub 3}{center_dot}xCaCl{sub 2}{center_dot}(1 - x)CaSO{sub 4}{center_dot}(12 - 2x){center_dot}H{sub 2}O (0.36 {<=} x {<=} 0.50).

Mesbah, Adel [Commissariat a l'Energie Atomique et aux Energies Alternatives, CEA DEN/DTCD/SPDE, F-30207 Bagnols sur Ceze (France); Clermont Universite, ENSCCF, Laboratoire des Materiaux Inorganiques, BP 10448, F-63000 Clermont-Ferrand (France); Cau-dit-Coumes, Celine, E-mail: celine.cau-dit-coumes@cea.fr [Commissariat a l'Energie Atomique et aux Energies Alternatives, CEA DEN/DTCD/SPDE, F-30207 Bagnols sur Ceze (France); Renaudin, Guillaume [Clermont Universite, ENSCCF, Laboratoire des Materiaux Inorganiques, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6002, F-63177 Aubiere (France); Frizon, Fabien [Commissariat a l'Energie Atomique et aux Energies Alternatives, CEA DEN/DTCD/SPDE, F-30207 Bagnols sur Ceze (France); Leroux, Fabrice [Clermont Universite, Universite Blaise Pascal, Laboratoire des Materiaux Inorganiques, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6002, F-63177 Aubiere (France)

2012-08-15T23:59:59.000Z

94

Uranium chloride extraction of transuranium elements from LWR fuel  

Science Conference Proceedings (OSTI)

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800{degrees}C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein.

Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

1991-12-31T23:59:59.000Z

95

Development of a copper-catalyzed amidation-base-promoted cyclization sequence for the synthesis of 2-aryl- and 2-vinyl1-4 quinolones  

E-Print Network (OSTI)

A direct two-step method for the preparation of 2-aryl- and 2-vinyl-4-quinolones that utilizes a copper-catalyzed amidation of ortho-halophenones followed by a base-promoted Camps cyclization of the resulting N-(2-keto-aryl)amides ...

Jones, Carrie Preston

2007-01-01T23:59:59.000Z

96

Modeling acid-gas generation from boiling chloride brines  

Science Conference Proceedings (OSTI)

This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

2009-11-16T23:59:59.000Z

97

Method of preparing sodalite from chloride salt occluded zeolite A  

DOE Patents (OSTI)

A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistance sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1,000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, M.A.; Pereira, C.

1995-12-31T23:59:59.000Z

98

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents (OSTI)

A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, M.A.; Pereira, C.

1997-03-18T23:59:59.000Z

99

Development of a Novel High-Chloride Circuit for the Starfield ...  

Science Conference Proceedings (OSTI)

Recovery of Precious Metals from Chloride Media Using Microalgae Waste from Biofuel Extraction · Segregation Roasting of a Saprolitic Laterite Ore: An ...

100

Influence of Chloride Content on Dielectric Behavior of C 3 A  

Science Conference Proceedings (OSTI)

Although this reaction has been widely studied, their electrical changes still require ... The results of the experimental work suggest that chloride ions modify the ...

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Chloride-mass-balance for predicting increased recharge after land-use change  

E-Print Network (OSTI)

Key Words: precipitation, dry fallout, lysimeter, drainage,chloride input (from dry fallout and precipitation), andthan precipitation and fallout is likely the explanation for

Gee, G.W.; Zhang, Z.F.; Tyler, S.W.; Albright, W.H.; Singleton, M.J.

2004-01-01T23:59:59.000Z

102

The Dissolution Behavior of TiCxO1-x Solid Solutions in Chloride Melt  

Science Conference Proceedings (OSTI)

Recovery of Precious Metals from Chloride Media Using Microalgae Waste from Biofuel Extraction · Segregation Roasting of a Saprolitic Laterite Ore: An ...

103

Synthesis of TiO2 by an Innovative Atmospheric Mixed Chloride ...  

Science Conference Proceedings (OSTI)

Recovery of Precious Metals from Chloride Media Using Microalgae Waste from Biofuel Extraction · Segregation Roasting of a Saprolitic Laterite Ore: An ...

104

Optimizing Reinjection Strategy at Palinpinon, Philippines Based on Chloride Data  

DOE Green Energy (OSTI)

One of the guidelines established for the safe and efficient management of the Palinpinon Geothermal Field is to adopt a production and well utilization strategy such that the rapid rate and magnitude of reinjection fluid returns leading to premature thermal breakthrough would be minimized. To help achieve this goal, sodium fluorescein and radioactive tracer tests have been conducted to determine the rate and extent of communication between the reinjection and producing sectors of the field. The first objective of this paper is to show how the results of these tests, together with information on field geometry and operating conditions were used in algorithms developed in Operations Research to allocate production and reinjection rates among the different Palinpinon wells. Due to operational and economic constraints, such tracer tests were very limited in number and scope. This prevents obtaining information on the explicit interaction between each reinjection well and the producing wells. Hence, the chloride value of the producing well, was tested to determine if use of this parameter would enable identifying fast reinjection paths among different production/reinjection well pairs. The second aim, therefore, of this paper is to show the different methods of using the chloride data of the producing wells and the injection flow rates of the reinjection wells to provide a ranking of the pair of wells and, thereby, optimize the reinjection strategy of the field.

Urbino, Ma. Elena G.; Horne, Roland N.

1992-03-24T23:59:59.000Z

105

Optimizing reinjection strategy at Palinpinon, Philippines based on chloride data  

DOE Green Energy (OSTI)

One of the guidelines established for the safe and efficient management of the Palinpinon Geothermal Field is to adopt a production and well utilization strategy such that the rapid rate and magnitude of reinjection fluid returns leading to premature thermal breakthrough would be minimized. To help achieve this goal, sodium fluorescein and radioactive tracer tests have been conducted to determine the rate and extent of communication between the reinjection and producing sectors of the field. The first objective of this paper is to show how the results of these tests, together with information on field geometry and operating conditions were used in algorithms developed in Operations Research to allocate production and reinjection rates among the different Palinpinon wells. Due to operational and economic constraints, such tracer tests were very limited in number and scope. This prevents obtaining information on the explicit interaction between each reinjection well and the producing wells. Hence, the chloride value of the producing well, was tested to determine if use of this parameter would enable identifying fast reinjection paths among different production/reinjection well pairs. The second aim, therefore, of this paper is to show the different methods of using the chloride data of the producing wells and the injection flow rates of the reinjection wells to provide a ranking of the pair of wells and, thereby, optimize the reinjection strategy of the field.

Urbino, Ma. Elena G.; Horne, Roland N.

1991-01-01T23:59:59.000Z

106

High-temperature sodium nickel chloride battery for electric vehicles  

DOE Green Energy (OSTI)

Although the sodium-nickel chloride cell couple has a high voltage (2.59 V) and a high specific energy (790 Wh/kg), the performance of present incarnations of this battery tend to be limited by their power. Because the nickel chloride electrode dominates the resistance and weight of the cell, research on this cell couple at Argonne National Laboratory (ANL) has been primarily directed toward improving both the specific power and energy of the NiCl{sub 2} electrodes. During the course of these investigations a major breakthrough was achieved in lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. This improved Ni/NiCl{sub 2} electrode has excellent performance characteristics, wide-temperature operation and fast recharge capability. Modeling studies done on this electrode indicate that a fully developed Na/NiCl{sub 2} battery based on ANL-single tube and bipolar designs would surpass the mid-term and approach the long-term goals of the US Advanced Battery Consortium.

Prakash, J.; Redey, L.; Nelson, P.A.; Vissers, D.R. [Argonne National Lab., IL (United States). Electrotechnical Technology Program

1996-07-01T23:59:59.000Z

107

Liquid Calcium Chloride Solar Storage: Concept and Analysis  

Science Conference Proceedings (OSTI)

Aqueous calcium chloride has a number of potential advantages as a compact and long-term solar storage medium compared to sensibly heated water. The combination of sensible and chemical binding energy of the liquid desiccant provides higher energy densities and lower thermal losses, as well as a temperature lift during discharge via an absorption heat pump. Calcium chloride is an excellent choice among desiccant materials because it is relatively inexpensive, non-toxic, and environmentally safe. This paper provides an overview of its application for solar storage and presents a novel concept for storing the liquid desiccant in a single storage vessel. The storage system uses an internal heat exchanger to add and discharge thermal energy and to help manage the mass, momentum, and energy transfer in the tank. The feasibility of the proposed concept is demonstrated via a computational fluid dynamic study of heat and mass transfer in the system over a range of Rayleigh, Lewis, Prandtl, and buoyancy ratio numbers expected in practice.

Quinnell, J. A.; Davidson, J. H.; Burch, J.

2010-01-01T23:59:59.000Z

108

Program on Technology Innovation: Chloride Attack-Induced Aging of Concrete Structures in the Energy Industry  

Science Conference Proceedings (OSTI)

Corrosion of embedded steel elements (reinforcement, liner, pre- or post-tensioning device) is a major cause of structure dysfunction resulting in large maintenance and repair costs worldwide. This report focuses on chloride attack–induced aging of concrete structures in the energy industry. Chloride attack is a common aging issue caused by marine environment, the extensive ...

2012-11-30T23:59:59.000Z

109

Sodium Chloride Hideout In a Simulated Steam Generator Tube and Tube Support Place Crevice  

Science Conference Proceedings (OSTI)

Localized corrosion of steam generator (SG) tubing in PWRs has been a serious problem that limits the life of this component. Preliminary measurements of sodium chloride hideout in simulated PWR SG crevices have shown that hideout rate increases with heat flux and concentration of sodium chloride in the bulk water.

1998-06-30T23:59:59.000Z

110

The Preparation and Property of Few-Layered Graphene/Benzalkonium Chloride Composite  

Science Conference Proceedings (OSTI)

In order to research and development a novel antibacterial material which is used to deal with the drinking water, few-layered grapheme/benzalkonium chloride composite was prepared by introducing different content of quaternary ammonium salt into layered ... Keywords: graphene, benzalkonium chloride, antibacterial, water treatment

A-gui Xie; Xiang Cai; Shao-zao Tan

2010-12-01T23:59:59.000Z

111

Self-discharge rate of lithium thionyl-chloride cells  

DOE Green Energy (OSTI)

Our low-rate lithium/thionyl-chloride ``D`` cell is required to provide power continuously for up to 10 years. The cell was designed at Sandia National Laboratories and manufactured at Eagle-Picher Industries, Joplin, Missouri. We have conducted accelerated aging studies at elevated temperatures to predict long-term performance of cells fabricated in 1992. Cells using 1.0M LiAlCl{sub 4} electrolyte follow Arrhenius kinetics with an activation energy of 14.6 Kcal/mol. This results in an annual capacity loss to self-discharge of 0.13 Ah at 25 C. Cells using a 1.0M LiAlCl{sub 4}{sm_bullet}SO{sub 2} electrolyte do not follow Arrhenius behavior. The performance of aged cells from an earlier fabrication lot is variable.

Cieslak, W.R.

1993-12-31T23:59:59.000Z

112

Development of mercury and chloride monitors for coal gasifiers  

DOE Green Energy (OSTI)

Ames Laboratory will develop an integrated sampling and analysis system suitable for on-line monitoring of mercury (Hg) and hydrogen chloride (HCl) in advanced coal-based gasifiers. The objectives of this project are to (1) summarize current technology for monitoring Hg and HCl in gaseous effluents; (2) identify analytical techniques for such determinations in high-temperature, high-pressure gases from coal-based systems for producing electrical power; (3) evaluate promising analytical approaches, and (4) produce reliable on-line monitors which are adaptable to plant-scale diagnostics and process control. For HG, the techniques selected for further consideration were atomic absorption and atomic fluorescence. For HCl, non-dispersive infrared absorption, a dry colorimetric procedure, and ion mobility spectroscopy were selected for testing in the laboratory. Results to date are described.

Buttermore, W.H.; Norton, G.A.; Chriswell, C.D.; Eckels, D.E.; Peters, R.E.

1996-12-31T23:59:59.000Z

113

Continuous extraction of molten chloride salts with liquid cadmium alloys  

Science Conference Proceedings (OSTI)

A pyrochemical method is being developed at Argonne National Laboratory (ANL) to provide contnuous multistage extractions between molten chloride salts and liquid cadmium alloys at 500{degrees}C. The extraction method will be used to recover transuranic (TRU) elements from the process salt in the electroretiner used in the pyrochemical reprocessing of spent fuel from the Integral Fast Reactor (IFR). The IFR is one of the Department of Energy`s advanced power reactor concepts. The recovered TRU elements are returned to the electrorefiner. The extracted salt undergoes further processing to remove rare earths and other fission products so that most of the purified salt can also be returned to the electrorefiner, thereby extending the useful life of the process salt many times.

Chow, L.S.; Basco, J.K.; Ackerman, J.P.; Johnson, T.R.

1993-09-01T23:59:59.000Z

114

TESTING OF 304L STAINLESS STEEL IN NITRIC ACID ENVIRONMENTS WITH FLUORIDES AND CHLORIDES  

Science Conference Proceedings (OSTI)

Impure radioactive material processed in nitric acid solutions resulted in the presence of chlorides in a dissolver fabricated from 304L stainless steel. An experimental program was conducted to study the effects of chloride in nitric acid/fluoride solutions on the corrosion of 304L stainless steel. The test variables included temperature (80, 95, and 110 C) and the concentrations of nitric acid (6, 12, and 14 M), fluoride (0.01, 0.1, and 0.2 M) and chloride (100, 350, 1000, and 2000 ppm). The impact of welding was also investigated. Results showed that the chloride concentration alone was not a dominant variable affecting the corrosion, but rather the interaction of chloride with fluoride significantly affected corrosion.

Mickalonis, J.

2010-10-04T23:59:59.000Z

115

Corrosive gas generation potential from chloride salt radiolysis in plutonium environments  

Science Conference Proceedings (OSTI)

The specific goal of this project was to evaluate the magnitude and practical significance of radiation effects involving mixtures of chloride salts and plutonium dioxide (PuO{sub 2}) sealed in stainless steel containers and stored for up to 50 yr, after stabilization at 950 C and packaging according to US Department of Energy (DOE) standards. The potential for generating chemically aggressive molecular chlorine (and hydrogen chloride by interaction with adsorbed water or hydrogen gas) by radiolysis of chloride ions was studied. To evaluate the risks, an annotated bibliography on chloride salt radiolysis was created with emphasis on effects of plutonium alpha radiation. The authors present data from the material identification and surveillance (MIS) project obtained from examination and analysis of representative PuO{sub 2} items from various DOE sites, including the headspace gas analysis data of sealed mixtures of PuO{sub 2} and chloride salts following long-term storage.

Tandon, L.; Allen, T.H.; Mason, R.E.; Penneman, R.A.

1999-07-01T23:59:59.000Z

116

Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method  

SciTech Connect

Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

Cooper, Clay A [DRI] [DRI; Hershey, Ronald L [DRI] [DRI; Healey, John M [DRI] [DRI; Lyles, Brad F [DRI] [DRI

2013-07-01T23:59:59.000Z

117

VC-Dimension Analysis of Object Recognition Tasks  

Science Conference Proceedings (OSTI)

We analyze the amount of data needed to carry out various model-based recognition tasks in the context of a probabilistic data collection model. We focus on objects that may be described as semi-algebraic subsets of a Euclidean space. This is a very ... Keywords: PAC, Vapnik-Chervonenkis dimension, computer vision, learning theory, localization, model-based recognition

Michael Lindenbaum; Shai Ben-David

1999-01-01T23:59:59.000Z

118

Leveraging Government, University and VC Funding to Bring ...  

Science Conference Proceedings (OSTI)

... 10 History of Technology • Lawrence Livermore National Lab (LLNL), mid 1990's ... Learning as quickly as possible – Seek JHU and LLNL licenses ...

2010-07-27T23:59:59.000Z

119

Chloride removal from plutonium-aluminum alloy dissolver solution prior to purex solvent extraction  

Science Conference Proceedings (OSTI)

The Savannah River Plant (SRP), operated by E. I. du Pont de Nemours Co. for the United States Department of Energy, has successfully recovered plutonium from plutonium-aluminum alloy processed through the F-Canyon Separations facility. The alloy, produced at the Rocky Flats Plant, results from recovery of plutonium residues from spent chloride salts from pyrochemical processing. The alloy, termed scrub alloy'' or Rocky Flats scrub alloy'' (RFSA), contains up to 15 weight percent chloride impurity prior to mercuric ion catalyzed dissolution with fluoride-containing nitric acid. Solutions containing 850 to 3000 {mu}g/mL (parts per million) of chloride result. During subsequent Purex solvent extraction of this solution with 30% tri-n-butyl phosphate in normal paraffin diluent, chloride is rejected to the aqueous waste stream. This stream is eventually evaporated for waste treatment and acid recovery. Chloride concentrations in the product streams, subject to further processing, must be less than 100 {mu}g/mL to prevent excessive corrosion of equipment. This paper describes scrub alloy production at RFP, its dissolution and head end treatment to remove chloride, chloride values in subsequent processing streams including environmental discharges, and the turbidimetric analysis technique. 2 tabs.

Holcomb, H.P.

1990-01-01T23:59:59.000Z

120

Probing Oxygen Activation Sites in Two Flavoprotein Oxidases Using Chloride as an Oxygen Surrogate  

SciTech Connect

A single basic residue above the si-face of the flavin ring is the site of oxygen activation in glucose oxidase (GOX) (His516) and monomeric sarcosine oxidase (MSOX) (Lys265). Crystal structures of both flavoenzymes exhibit a small pocket at the oxygen activation site that might provide a preorganized binding site for superoxide anion, an obligatory intermediate in the two-electron reduction of oxygen. Chloride binds at these polar oxygen activation sites, as judged by solution and structural studies. First, chloride forms spectrally detectable complexes with GOX and MSOX. The protonated form of His516 is required for tight binding of chloride to oxidized GOX and for rapid reaction of reduced GOX with oxygen. Formation of a binary MSOX-chloride complex requires Lys265 and is not observed with Lys265Met. Binding of chloride to MSOX does not affect the binding of a sarcosine analogue (MTA, methylthioactetate) above the re-face of the flavin ring. Definitive evidence is provided by crystal structures determined for a binary MSOX-chloride complex and a ternary MSOX-chloride-MTA complex. Chloride binds in the small pocket at a position otherwise occupied by a water molecule and forms hydrogen bonds to four ligands that are arranged in approximate tetrahedral geometry: Lys265:NZ, Arg49:NH1, and two water molecules, one of which is hydrogen bonded to FAD:N5. The results show that chloride (i) acts as an oxygen surrogate, (ii) is an effective probe of polar oxygen activation sites, and (iii) provides a valuable complementary tool to the xenon gas method that is used to map nonpolar oxygen-binding cavities.

Kommoju, Phaneeswara-Rao; Chen, Zhi-wei; Bruckner, Robert C.; Mathews, F. Scott; Jorns, Marilyn Schuman (Drexel-MED); (St. Louis-MED); (WU-MED)

2011-08-16T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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121

The faradaic efficiency of the lithium-thionyl chloride battery  

DOE Green Energy (OSTI)

The efficiency of converting chemical energy into electrical energy has been studied for the case of D-size, low and medium rate lithium-thionyl chloride (Li/TC) cells, under DC and various pulsed loads. Microcalorimetric monitoring of the heat output during discharge allowed the direct measurement of the faradaic efficiency, and showed that self-discharge is far more pervasive than previously acknowledged by researchers and battery manufacturers. Evaluations of the cell dynamics prove that current load and temperature fluctuations combine to disrupt the lithium passivation and to greatly enhance self-discharge. Typical faradaic efficiencies for DC range from abut 30% at low current density to 90% at moderate and 75% at high current density. Pulsed current further depresses these efficiency levels, except at very low average current densities. The decreased faradaic efficiency of Li/TC batteries in certain pulse situations needs to be studied further to define the range of applications for which it can be successfully used.

Hoier, S.N.; Eisenmann, E.T. [Sandia National Labs., Albuquerque, NM (United States). Battery Research Dept.

1996-04-01T23:59:59.000Z

122

FIRST DETECTION OF HYDROGEN CHLORIDE TOWARD PROTOSTELLAR SHOCKS  

Science Conference Proceedings (OSTI)

We present the first detection of hydrogen chloride in a protostellar shock by observing the fundamental transition at 626 GHz with the HIFI spectrometer. We detected two of the three hyperfine lines from which we derived a line opacity {15 K, and density >3 Multiplication-Sign 10{sup 5} cm{sup -3}. Combining these with the Herschel HIFI CO(5-4) observations allows us to further constrain the gas density and temperature, 10{sup 5}-10{sup 6} cm{sup -3} and 120-250 K, respectively, as well as the HCl column density, 2 Multiplication-Sign 10{sup 13} cm{sup -2}, and, finally, the abundance {approx}3-6 Multiplication-Sign 10{sup -9}. The estimated HCl abundance is consistent with that previously observed in low- and high-mass protostars. This puzzling result in the L1157-B1 shock, where species from volatile and refractory grain components are enhanced, suggests either that HCl is not the main reservoir of chlorine in the gas phase, which goes against previous chemical model predictions, or that the elemental chlorine abundance is low in L1157-B1. Astrochemical modeling suggests that HCl is in fact formed in the gas phase at low temperatures prior to the occurrence of the shock; the latter does not enhance its abundance.

Codella, C.; Vasta, M. [INAF, Osservatorio Astrofisico di Arcetri, Largo Enrico Fermi 5, I-50125 Firenze (Italy); Ceccarelli, C.; Lefloch, B.; Faure, A.; Wiesenfeld, L. [UJF-Grenoble 1/CNRS-INSU, Institut de Planetologie et d'Astrophysique de Grenoble (IPAG) UMR 5274, Grenoble, F-38041 (France); Bottinelli, S.; Caux, E. [Universite de Toulouse (France); UPS-OMP, CNRS, IRAP, Toulouse, BP 44346, F-31028 (France); Salez, M.; Cabrit, S. [Observatoire de Paris-Meudon, LERMA UMR CNRS 8112, Meudon (France); Viti, S., E-mail: codella@rcetri.astro.it [Department of Physics and Astronomy, University College London, London (United Kingdom)

2012-01-10T23:59:59.000Z

123

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New  

Open Energy Info (EERE)

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Mexico- A 36Cl Study Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Mexico- A 36Cl Study Abstract The Valles caldera in New Mexico hosts a high-temperature geothermal system, which is manifested in a number of hot springs discharging in and around the caldera. In order to determine the fluid pathways and the origin of chloride in this system, we measured 36Cl/Cl ratios in waters from high-temperature drill holes and from surface springs in this region. The waters fall into two general categories: recent meteoric water samples with low Cl- concentrations (< 10 mg/L) and relatively high 36Cl/Cl ratios

124

Heat storage material comprising calcium chloride-hexahydrate and a nucleating agent  

SciTech Connect

The utility of calcium chloride-hexahydrate as a heat storage material is improved when barium carbonate, strontium carbonate, barium fluoride, barium fluoride-hydrofluoride and/or strontium fluoride is used as a nucleating agent to prevent supercooling.

Gawron, K.; Schroder, J.

1980-02-19T23:59:59.000Z

125

Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins  

E-Print Network (OSTI)

Nickel-catalyzed intermolecular benzylation and heterobenzylation of unactivated alkenes to provide functionalized allylbenzene derivatives are described. A wide range of both the benzyl chloride and alkene coupling partners ...

Matsubara, Ryosuke

126

Contribution of garbage burning to chloride and PM[subscript 2.5] in Mexico City  

E-Print Network (OSTI)

The contribution of garbage burning (GB) emissions to chloride and PM[subscript 2.5] in the Mexico City Metropolitan Area (MCMA) has been investigated for the period of 24 to 29 March during the MILAGRO-2006 campaign using ...

Li, G.

127

Electrochemical Preparation of Ti2AlC in Molten Chloride Bath  

Science Conference Proceedings (OSTI)

Cathodic Behavior of Silicon (?) in BaF2-CaF2 –SiO2 Melts ... Electrochemical Impedance Spectroscopy of Uranium Chloride in Molten LiCl-KCl Eutectic.

128

Iron (III) Chloride doping of large-area chemical vapor deposition graphene  

E-Print Network (OSTI)

Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

Song, Yi, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

129

Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes  

DOE Patents (OSTI)

The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

1993-01-01T23:59:59.000Z

130

Raman spectroscopic studies of chemical speciation in calcium chloride melts  

DOE Green Energy (OSTI)

Raman spectroscopy was applied to CaCl2 melts at 900 degrees C under both non-electrolyzed and electrolyzed conditions. The later used titania cathodes supplied by TIMET, Inc. and graphite anodes. Use of pulse-gating to collect the Raman spectra successfully eliminated any interference from black-body radiation and other stray light. The spectrum of molten CaCl2 exhibited no distinct, resolvable bands that could be correlated with a calcium chloride complex similar to MgCl42- in MgCl2 melts. Rather, the low frequency region of the spectrum was dominated by a broad “tail” arising from collective oscillations of both charge and mass in the molten salt “network.” Additions of both CaO and Ca at concentrations of a percent or two resulted in no new features in the spectra. Addition of CO2, both chemically and via electrolysis at concentrations dictated by stability and solubility at 900 degrees C and 1 bar pressure, also produced no new bands that could be correlated with either dissolved CO2 or the carbonate ion. These results indicated that Raman spectroscopy, at least under the conditions evaluated in the research, was not well suited for following the reactions and coordination chemistry of calcium ions, nor species such as dissolved metallic Ca and CO2 that are suspected to impact current efficiency in titanium electrolysis cells using molten CaCl2. Raman spectra of TIMET titania electrodes were successfully obtained as a function of temperature up to 900 degrees C, both in air and in-situ in CaCl2 melts. However, spectra of these electrodes could only be obtained when the material was in the unreduced state. When reduced, either with hydrogen or within an electrolysis cell, the resulting electrodes exhibited no measurable Raman bands under the conditions used in this work.

Windisch, Charles F.; Lavender, Curt A.

2005-02-01T23:59:59.000Z

131

Lithium: Thionyl chloride battery state-of-the-art assessment  

DOE Green Energy (OSTI)

Models of the performance of primary Li/SOCl{sub 2} cells can provide for realistic comparisons between technical information from different sources, and set standards that electronic circuit designers may refer to in the generation of high-quality products. Data from various investigators were used to derive mathematical- statistical relationships with physical design features (e.g. size and materials), operating parameters (e.g. current and temperature) and storage conditions (time and temperature). These efforts were substantially promoted by normalization procedures. For example, current loads were converted into current densities, or if appropriate, into current per unit cathode volume. Similarly, cell capacities were standardized with the maximum values observed at low current and also with respect to the cathode volume. Particular emphasis was placed on evaluations of voltage-delay, cell capacity and self-discharge, for which several equations were established. In spite of a considerable expenditure in time to find high-quality datasets, the reality is that all of the reviewed studies are flawed in one way or another. Specifically, all datasets are afflicted with sizable experimental errors and the precision of the regression equations is much lower than is deemed necessary for a universal model of the lithium thionyl chloride cell. Each of the equations has some definite truth content, but is generally incapable of bridging the gap between different studies. The basic failure to come up with a unifying model for Li/SOCl{sub 2} batteries leaves only one benefit of the present analysis, namely to provide guidance for future investigations. Several recommendations are made based on the insight gained during the search for good data in the relevant literature.

Eisenmann, E.T.

1996-03-01T23:59:59.000Z

132

Liver Hypertrophy After Percutaneous Portal Vein Embolization: Comparison of N-Butyl-2-Cyanocrylate Versus Sodium Acrylate-Vinyl Alcohol Copolymer Particles in a Swine Model  

Science Conference Proceedings (OSTI)

Purpose: Percutaneous portal vein embolization (PPVE) induces hypertrophy of the future liver remnant before hepatic resection. The ideal embolic material has not yet been determined. We compared N-butyl-2-cyanocrylate (NBCA) with sodium acrylate-vinyl alcohol copolymer particles using a swine model. Materials and Methods: Twelve pigs underwent PPVE. Six pigs (group A) were embolized with NBCA, and 6 pigs (group B) were embolized with sodium acrylate-vinyl alcohol copolymer particles. Computed tomographic volumetry of the embolized lobe (EL) and the nonembolized lobe (NEL), along with liver function tests, was performed before and at 14 and 28 days after embolization. Tissue samples from both lobes were taken 14 and 28 days after PPVE. Results: NEL-volume and NEL-ratio increases were significantly higher in group A at 14 and 28 days after PPVE (78 and 52% and 91 and 66%, respectively) than in group B (32 and 12% and 28 and 10%, respectively) (p < 0.05). Percent change of the EL-volume was significantly higher for group A at 28 days after PPVE. No statistically significant difference was found between the groups regarding hepatocyte proliferation on the NEL and apoptosis on the EL at both time intervals. Conclusion: PPVE using NBCA is more efficient and causes more NEL hypertrophy than microspheres.

Tsoumakidou, Georgia, E-mail: gtsoumakidou@yahoo.com [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece); Theocharis, Stamatis, E-mail: theocharis@ath.forthnet.gr [National and Kapodistrian University of Athens, Department of Forensic Medicine and Toxicology, Medical School (Greece); Ptohis, Nikolaos, E-mail: nikptohis@yahoo.gr; Alexopoulou, Efthimia, E-mail: ealex64@hotmail.com [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece); Mantziaras, George, E-mail: gmantziaras@yahoo.com [Academy of Athens, Biomedical Research Foundation (Greece); Kelekis, Nikolaos L., E-mail: kelnik@med.uoa.gr; Brountzos, Elias N., E-mail: ebrountz@med.uoa.gr [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece)

2011-10-15T23:59:59.000Z

133

Effect of chloride content of molten nitrate salt on corrosion of A516 carbon steel.  

SciTech Connect

The corrosion behavior of A516 carbon steel was evaluated to determine the effect of the dissolved chloride content in molten binary Solar Salt. Corrosion tests were conducted in a molten salt consisting of a 60-40 weight ratio of NaNO{sub 3} and KNO{sub 3} at 400{sup o}C and 450{sup o}C for up to 800 hours. Chloride concentrations of 0, 0.5 and 1.0 wt.% were investigated to determine the effect on corrosion of this impurity, which can be present in comparable amounts in commercial grades of the constituent salts. Corrosion rates were determined by descaled weight losses, corrosion morphology was examined by metallographic sectioning, and the types of corrosion products were determined by x-ray diffraction. Corrosion proceeded by uniform surface scaling and no pitting or intergranular corrosion was observed. Corrosion rates increased significantly as the concentration of dissolved chloride in the molten salt increased. The adherence of surface scales, and thus their protective properties, was degraded by dissolved chloride, fostering more rapid corrosion. Magnetite was the only corrosion product formed on the carbon steel specimens, regardless of chloride content or temperature.

Bradshaw, Robert W.; Clift, W. Miles

2010-11-01T23:59:59.000Z

134

DOEEA-1157 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLOFUNATION OF METHANE:  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

57 57 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLOFUNATION OF METHANE: A BUILDING BLOCK FOR CHEMICALS AND FUELS FROM NATURAL GAS DOW CORNING CORPORATION CARROLLTON, KENTUCKY SEPTEMBER 1996 U.S. DEPARTMENT OF ENERGY PITTSBURGH ENERGY TECHNOLOGY CENTER CUM ~~~~~~~~ DOEEA-1157 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLORINATION OF METHANE: A BUILDING BLOCK FOR CHEMICALS AND FUELS FROM NATURAL GAS DOW CORNING CORPORATION CARROLLTON, KENTUCKY SEPTEMBER 1996 U.S. DEPARTMENT OF ENERGY PITTSBURGH ENERGY TECHNOLOGY CENTER Portions of this document may be illegible in electronic image products. Image are produced from the best available original document. &E/,Etq --,/s7 FINDING OF NO SIGNIFICANT IMPACT FOR THE PROPOSED METHYL CHLORIDE V

135

Current techniques in acid-chloride corrosion control and monitoring at The Geysers  

DOE Green Energy (OSTI)

Acid chloride corrosion of geothermal well casings, production piping and power plant equipment has resulted in costly corrosion damage, frequent curtailments of power plants and the permanent shut-in of wells in certain areas of The Geysers. Techniques have been developed to mitigate these corrosion problems, allowing continued production of steam from high chloride wells with minimal impact on production and power generation facilities.The optimization of water and caustic steam scrubbing, steam/liquid separation and process fluid chemistry has led to effective and reliable corrosion mitigation systems currently in routine use at The Geysers. When properly operated, these systems can yield steam purities equal to or greater than those encountered in areas of The Geysers where chloride corrosion is not a problem. Developments in corrosion monitoring techniques, steam sampling and analytical methodologies for trace impurities, and computer modeling of the fluid chemistry has been instrumental in the success of this technology.

Hirtz, Paul; Buck, Cliff; Kunzman, Russell

1991-01-01T23:59:59.000Z

136

LOW TEMPERATURE PROCESS FOR THE REMOVAL AND RECOVERY OF CHLORIDES AND NITRATES FROM AQUEOUS NITRATE SOLUTIONS  

DOE Patents (OSTI)

A method is described for reducing the chloride content of a solution derived from the dissolution of a stainless steel clad nuclear fuel element with an aqua regia dissolution medium. The solutlon is adjusted to a nitric acid concentration in the range 5 to 10 M and is countercurrently contacted at room temperature with a gaseous oxide of nitrogen selected from NO, NO/sub 2/, N/sub 2/ O/sub 3/, and N/sub 2/O/sub 4/. Chlo ride is recovered from the contacted solution as nitrosyl chloride. After reduction of the chloride content, the solution is then contacted with gaseous NO to reduce the nitric acid molarity to a desired level. (AEC)

Savolainen, J.E.

1963-01-29T23:59:59.000Z

137

Method for determining trace quantities of chloride in polymeric materials using ion selective electrodes: Final report  

Science Conference Proceedings (OSTI)

A method for determining trace quantities of chloride in polymeric materials has been developed. Ion-selective electrodes and the standard addition method were used in all the analyses. The ion-selective electrode method was compared with neutron activation, ion chromatography and chloridometer titration. The ion-selective electrode technique results for chloride were similar to those of neutron activation, which is the acknowledged referee method. This ion-selective electrode method showed the highest standard recovery when compared with the ion chromatography and chloridometer titration methods.

Salary, J.

1987-02-01T23:59:59.000Z

138

Method of electrode fabrication and an electrode for metal chloride battery  

DOE Patents (OSTI)

A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 [Omega]cm[sup 2] than those resistivity values of approximately 1.0-1.5 [Omega]cm[sup 2] exhibited by currently available electrodes.

Bloom, I.D.; Nelson, P.A.; Vissers, D.R.

1993-03-16T23:59:59.000Z

139

Method of electrode fabrication and an electrode for metal chloride battery  

DOE Patents (OSTI)

A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 {Omega}cm{sup 2} than those resistivity values of approximately 1.0--1.5 {Omega}cm{sup 2} exhibited by currently available electrodes.

Bloom, I.D.; Nelson, P.A.; Vissers, D.R.

1990-10-09T23:59:59.000Z

140

Method of electrode fabrication and an electrode for metal chloride battery  

SciTech Connect

A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 .OMEGA.cm.sup.2 than those resistivity values of approximately 1.0-1.5 .OMEGA.cm.sup.2 exhibited by currently available electrodes.

Bloom, Ira D. (Bolingbrook, IL); Nelson, Paul A. (Wheaton, IL); Vissers, Donald R. (Naperville, IL)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Current Status of Health and Safety Issues of Sodium/Metal Chloride (Zebra) Batteries  

DOE Green Energy (OSTI)

This report addresses environmental, health, and safety (EH&S) issues associated with sodium/ metal chloride batteries, in general, although most references to specific cell or battery types refer to units developed or being developed under the Zebra trademark. The report focuses on issues pertinent to sodium/metal chloride batteries and their constituent components; however, the fact that some ''issues'' arise from interaction between electric vehicle (EV) and battery design compels occasional discussion amid the context of EV vehicle design and operation. This approach has been chosen to provide a reasonably comprehensive account of the topic from a cell technology perspective and an applications perspective.

Trickett, D.

1998-12-15T23:59:59.000Z

142

Reliability, Availability, and Maintainability Assessment of a Zinc Chloride Battery System  

Science Conference Proceedings (OSTI)

UNIRAM analyses guided the design of an advanced energy storage system for load leveling and management. The study showed that, in comparison with competing technologies that are available approximately 90% of the time, a 2-MW system of zinc chloride batteries would have an availability greater than 98%.

1986-12-10T23:59:59.000Z

143

Low coverage spontaneous etching and hyperthermal desorption of aluminum chlorides from Cl2 Al,,111...  

E-Print Network (OSTI)

spectrometry has been used to monitor the desorption of aluminum chloride (AlxCly) etch products from the Al-probable velocity of 517 22 m/s at an Al 111 surface temperature of 100 K. This corresponds to 22 times the expected thermal desorption translational energy for AlCl3 . Cl2 sticking probability measurements and AlxCly etch

Kummel, Andrew C.

144

Lithium chloride protects retinal neurocytes from nutrient deprivation by promoting DNA non-homologous end-joining  

SciTech Connect

Lithium chloride is a therapeutic agent for treatment of bipolar affective disorders. Increasing numbers of studies have indicated that lithium has neuroprotective effects. However, the molecular mechanisms underlying the actions of lithium have not been fully elucidated. This study aimed to investigate whether lithium chloride produces neuroprotective function by improving DNA repair pathway in retinal neurocyte. In vitro, the primary cultured retinal neurocytes (85.7% are MAP-2 positive cells) were treated with lithium chloride, then cultured with serum-free media to simulate the nutrient deprived state resulting from ischemic insult. The neurite outgrowth of the cultured cells increased significantly in a dose-dependent manner when exposed to different levels of lithium chloride. Genomic DNA electrophoresis demonstrated greater DNA integrity of retinal neurocytes when treated with lithium chloride as compared to the control. Moreover, mRNA and protein levels of Ligase IV (involved in DNA non-homologous end-joining (NHEJ) pathway) in retinal neurocytes increased with lithium chloride. The end joining activity assay was performed to determine the role of lithium on NHEJ in the presence of extract from retinal neurocytes. The rejoining levels in retinal neurocytes treated with lithium were significantly increased as compared to the control. Furthermore, XRCC4, the Ligase IV partner, and the transcriptional factor, CREB and CTCF, were up-regulated in retinal cells after treating with 1.0 mM lithium chloride. Therefore, our data suggest that lithium chloride protects the retinal neural cells from nutrient deprivation in vitro, which may be similar to the mechanism of cell death in glaucoma. The improvement in DNA repair pathway involving in Ligase IV might have an important role in lithium neuroprotection. This study provides new insights into the neural protective mechanisms of lithium chloride.

Zhuang Jing; Li Fan; Liu Xuan; Liu Zhiping; Lin Jianxian [State Key Laboratory of Ophthalmology, Zhongshan Ophthalmic Center, Sun Yat-sen University, 54 S Xianlie Road, Guangzhou, Guangdong 510060 (China); Ge Yihong [Department of Stomatology, the Southern Medical University (China); Kaminski, Joseph M. [National Institute of Allergy and Infectious Diseases, Division of Allergy, Immunology, and Transplantation, University of South Alabama (United States); Summers, James Bradley [Department of Radiology, University of South Alabama (United States); Wang Zhichong [State Key Laboratory of Ophthalmology, Zhongshan Ophthalmic Center, Sun Yat-sen University, 54 S Xianlie Road, Guangzhou, Guangdong 510060 (China); Ge Jian [State Key Laboratory of Ophthalmology, Zhongshan Ophthalmic Center, Sun Yat-sen University, 54 S Xianlie Road, Guangzhou, Guangdong 510060 (China)], E-mail: gejian@mail.sysu.edu.cn; Yu Keming [State Key Laboratory of Ophthalmology, Zhongshan Ophthalmic Center, Sun Yat-sen University, 54 S Xianlie Road, Guangzhou, Guangdong 510060 (China)], E-mail: yukeming@mail.sysu.edu.cn

2009-03-13T23:59:59.000Z

145

LOCALIZED CORROSION OF AUSTENITIC STAINLESS STEELEXPOSED TO MIXTURES OF PLUTONIUM OXIDE AND CHLORIDE SALTS  

SciTech Connect

Laboratory corrosion tests were conducted to investigate the corrosivity of moist plutonium oxide/chloride (PuO{sub 2}/Cl-) salt mixtures on 304L and 316L stainless steel coupons. The tests exposed flat coupons for pitting evaluation and 'teardrop' stressed coupons for stress corrosion cracking (SCC) evaluation at room temperature to various mixtures of PuO{sub 2} and chloride-bearing salts for periods up to 500 days. The two flat coupons were placed so that the solid oxide/salt mixture contacted about one half of the coupon surface. One teardrop coupon was placed in contact with solid mixture; the second teardrop was in contact with the headspace gas only. The mixtures were loaded with nominally 0.5 wt % water under a helium atmosphere. Observations of corrosion ranged from superficial staining to pitting and SCC. The extent of corrosion depended on the total salt concentration and on the composition of the salt. The most significant corrosion was found in coupons that were exposed to 98 wt % PuO{sub 2}, 2 wt % chloride salt mixtures that contained calcium chloride. SCC was observed in two 304L stainless steel teardrop coupons exposed in solid contact to a mixture of 98 wt % PuO{sub 2}, 0.9 wt % NaCl, 0.9 wt % KCl, and 0.2 wt % CaCl{sub 2}. The cracking was associated with the heat-affected zone of an autogenous weld that ran across the center of the coupon. Cracking was not observed in coupons exposed to the headspace gas, nor in coupons exposed to other mixtures with either 0.92 wt% CaCl{sub 2} or no CaCl{sub 2}. The corrosion results point to the significance of the interaction between water loading and the concentration of the hydrating salt CaCl{sub 2} in the susceptibility of austenitic stainless steels to corrosion.

Zapp, P; Kerry Dunn, K; Jonathan Duffey, J; Ron Livingston, R; Zane Nelson, Z

2008-11-21T23:59:59.000Z

146

Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides  

SciTech Connect

The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

Haas, P.A.; Lee, D.D.; Mailen, J.C.

1991-11-01T23:59:59.000Z

147

THE PREPARATION OF URANIUM DIOXIDE FROM A MOLTEN SALT SOLUTION OF URANYL CHLORIDE  

DOE Green Energy (OSTI)

Uranium oxides in a molten eutectic mixture of NaClKCl were chlorinated by bubbling chlorine gas through the mixture. The reaction product, uranyl chloride. was soluble in the molten salt. Although UO/sub 2/ was the most common oxide used, the reaction was similar in the other oxides. Phosgene and aluminum chloride were also used as chlorinating agents. A dense, crystalline precipitate of pure UO/sub 2/ was prepared by the reduction of the uranyl chloride contained in the molten salt solution. The reduction was accomplished by contacting the salt solution with any of several metals, by reaction with hydrogen or dry ammonia gas, or by electrolysis. Several kilograms of UO/sub 2/ were prepared by electrolysis using graphite electrodes. The physical properties of the material made it potentially useful as a ceramic fuel material. The initial high particle density of the "as-produced" UO/sub 2/ was considered of great potential advantage for adapting this process to the refabrication of irradiated UO/sub 2/ into recycle fuel elements. (M.C.G.)

Lyon, W.L.; Voiland, E.E.

1959-10-20T23:59:59.000Z

148

The Effects of Temperature on the Electrochemical Performance of Sodium-Nickel Chloride Batteries  

Science Conference Proceedings (OSTI)

The sodium-nickel chloride (ZEBRA) battery is typically fabricated with a thick tubular ?"-alumina solid electrolyte (BASE) and operated at relatively high temperatures (? 300ºC) to achieve adequate electrochemical performance. In the present work, a planar-type sodium-nickel chloride battery possessing a thin BASE (~600 ?m thick) was tested in order to evaluate the feasibility of the battery operation at low temperatures (?200°C). Electrochemical test results revealed that the battery was able to be cycled at C/3 rate at as low as 175°C despite the higher cell polarization at the reduced temperature. Overall, low operating temperature resulted in a considerable improvement in the stability of cell performance. Cell degradation was negligible at 175°C, while 55% increase in end-of-charge polarization was observed at 280°C after 60 cycles. SEM analysis indicated that the performance degradation at higher temperatures was related to the particle growth of both nickel and sodium chloride in the cathode. The cells tested at lower temperatures (e.g., 175 and 200°C), however, exhibited a sharp drop in cell voltage at the end of discharge due to the diffusion limitation, possibly caused by the limited ionic conductivity of NaAlCl4 melt or the poor wettability of sodium on the BASE. Therefore, improvements in the ionic conductivity of a secondary electrolyte and sodium wetting are desirable to further enhance the battery performance at low temperatures.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2012-10-01T23:59:59.000Z

149

Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems. Progress report  

DOE Green Energy (OSTI)

Hydrothermal experiments on the partitioning of HCl and copper chloride in the system silicate melt-hydrosaline liquid-aqueous vapor are described. Modelling of the aqueous phase evolution process is discussed. (MHR)

Not Available

1990-12-31T23:59:59.000Z

150

Optimal estimation of the surface fluxes of methyl chloride using a 3-D global chemical transport model  

E-Print Network (OSTI)

Methyl chloride (CH3Cl) [CH subscript 3 Cl] is a chlorine-containing trace gas in the atmosphere contributing significantly to stratospheric ozone depletion. Large uncertainties in estimates of its source and sink magnitudes ...

Xiao, Xue

151

Nickel-catalyzed asymmetric cross-couplings of secondary allylic chlorides and planar-chiral compounds in asymmetric synthesis  

E-Print Network (OSTI)

In Part I, nickel-catalyzed asymmetric carbon-carbon bond-forming reactions are described. A nickel/Pybox system effectively catalyzes regio- and enantioselective cross-couplings between racemic secondary allylic chlorides ...

Son, Sunghee

2008-01-01T23:59:59.000Z

152

EFFECT OF CHLORIDE AND SULFATE CONCENTRATION ON PROBABLITY BASED CORROSION CONTROL FOR LIQUID WASTE TANKS- PART IV  

SciTech Connect

A series of cyclic potentiodynamic polarization tests was performed on samples of A537 carbon steel in support of a probability-based approach to evaluate the effect of chloride and sulfate on corrosion susceptibility. Testing solutions were chosen to build off previous experimental results from FY07, FY08, FY09 and FY10 to systemically evaluate the influence of the secondary aggressive species, chloride, and sulfate. The FY11 results suggest that evaluating the combined effect of all aggressive species, nitrate, chloride, and sulfate, provides a consistent response for determining corrosion susceptibility. The results of this work emphasize the importance for not only nitrate concentration limits, but also chloride and sulfate concentration limits as well.

Hoffman, E.

2012-08-23T23:59:59.000Z

153

Generalized chloride mass balance: Forward and inverse solutions for one-dimensional tracer convection under transient flux  

Science Conference Proceedings (OSTI)

Forward and inverse solutions are provided for analysis of inert tracer profiles resulting from one-dimensional convective transport under fluxes which vary with time and space separately. The developments are displayed as an extension of conventional chloride mass balance (CMB) techniques to account for transient as well as space-dependent water fluxes. The conventional chloride mass balance has been used over two decades to estimate recharge over large time scales in arid environments. In this mass balance approach, the chloride concentration in the pore water, originating from atmospheric fallout, is inversely proportional to the flux of water through the sediments. The CMB method is especially applicable to arid and semi-arid regions where evapotranspirative enrichment of the pore water produces a distinct chloride profile in the unsaturated zone. The solutions presented allow incorporation of transient fluxes and boundary conditions in CMB analysis, and allow analysis of tracer profile data which is not constant with depth below extraction zone in terms of a rational water transport model. A closed-form inverse solution is derived which shows uniqueness of model parameter and boundary condition (including paleoprecipitation) estimation, for the specified flow model. Recent expressions of the conventional chloride mass balance technique are derived from the general model presented here; the conventional CMB is shown to be fully compatible with this transient flow model and it requires the steady-state assumption on chloride mass deposition only (and not on water fluxes or boundary conditions). The solutions and results are demonstrated on chloride profile data from west central New Mexico.

Ginn, T.R.; Murphy, E.M.

1996-12-01T23:59:59.000Z

154

Flexible polyvinyl chloride neutron guides for transporting ultracold and very cold neutrons  

SciTech Connect

The transmission of ultracold neutrons (UCNs) through flexible polyvinyl chloride (PVC) tubes with lengths of up to 3 m and an internal diameter of 6-8 mm has been studied. High UCN transmission is found even for arbitrarily bent tubes (single bend, double bend, triple bend, figure eight, etc.). The transmission can be improved significantly by coating the inner surface of the tube with a thin layer of liquid fluorine polymer. The prospects of these neutron guides in fundamental and applied research are discussed.

Arzumanov, S. S., E-mail: sarzumanov@yandex.ru; Bondarenko, L. N. [Russian Research Center Kurchatov Institute (Russian Federation); Geltenbort, P. [Institut Laue-Langevin (France); Morozov, V. I. [Russian Research Center Kurchatov Institute (Russian Federation); Nesvizhevsky, V. V. [Institut Laue-Langevin (France); Panin, Yu. N.; Strepetov, A. N.; Chuvilin, D. Yu. [Russian Research Center Kurchatov Institute (Russian Federation)

2011-12-15T23:59:59.000Z

155

Development of Disposable Sorbents for Chloride Removal from High-Temperature Coal-Derived Gases  

Science Conference Proceedings (OSTI)

The integrated coal-gasification combined-cycle approach is an efficient process for producing electric power from coal by gasification, followed by high-temperature removal of gaseous impurities, then electricity generation by gas turbines. Alternatively, molten carbonate fuel cells (MCFC) may be used instead of gas turbine generators. The coal gas must be treated to remove impurities such as hydrogen chloride (HCl), a reactive, corrosive, and toxic gas, which is produced during gasification from chloride species in the coal. HCl vapor must be removed to meet environmental regulations, to protect power generation equipments such as fuel cells or gas turbines, and to minimize deterioration of hot coal gas desulfurization sorbents. The objectives of this study are to: (1) investigate methods to fabricate reactive sorbent pellets or granules that are capable of reducing HCl vapor in high-temperature coal gas streams to less than 1 ppm in the temperature range 400{degrees}C to 650{degrees}C and the pressure range 1 to 20 atm; (2) testing their suitability in bench-scale fixed- or fluidized-bed reactors; (3) testing a superior sorbent in a circulating fluidized- bed reactor using a gas stream from an operating coal gasifier; and (4) updating the economics of high temperature HCl removal.

Krishnan, G.N.; Canizales, A. [SRI International, Menlo Park, CA (United States); Gupta, R. [Research Triangle Inst., Research Triangle Park, NC (United States); Ayala, R. [General Electric Co., Schenectady, NY (United States). Corporate Research and Development Center

1996-12-31T23:59:59.000Z

156

Open cycle lithium chloride cooling system. Final report, March 1, 1982-May 28, 1983  

DOE Green Energy (OSTI)

A lithium chloride open cycle absorption chiller has been designed, built and tested. Solution reconcentration takes place in a small counter-current packed column supplied with solar heated air. Removal of non-condensable gases that enter the chiller dissolved in the strong solution and the make-up refrigerant streams is accomplished by a liquid-jet ejector and a small vacuum pump. Cooling capacities approaching 1.4 tons and COP levels of 0.58 have been achieved at non-optimum operating conditions. Test results from preliminary system operation suggest that mass transfer processes in both the packed column reconcentrator and the absorber are controlled by concentration gradients in the lithium chloride solution. Liquid phase controlled mass transfer dictates an operating strategy different from the previously assumed gas phase controlled process to obtain maximum rates of evaporation in the packed column. Determination of optimal operating conditions leading to decreased electrical power consumption and improved cooling capacity and coefficient of performance will require further analysis and testing.

Lenz, T. G.; Loef, G. O.G.; Iyer, R.; Wenger, J.

1983-05-01T23:59:59.000Z

157

Molecular Dynamics Simulation of the Transport Properties of Molten Transuranic Chloride Salts  

E-Print Network (OSTI)

The Accelerator Research Laboratory at Texas A&M is proposing a design for accelerator-driven subcritical fission in molten salt (ADSMS), a system that destroys the transuranic elements in used nuclear fuel. The transuranics (TRU) are the most enduring hazard of nuclear power. TRU contain high radiotoxicity and have half-lives of a thousand to a million years. The ADSMS core is fueled by a homogeneous chloride-based molten salt mixture containing TRUCl3 and NaCl. Certain thermodynamic properties are critical to modeling both the neutronics and heat transfer of an ADSMS system. There is a lack of experimental data on the density, heat capacity, electrical and thermal conductivities, and viscosity of TRUCl3 salt systems. Molecular dynamics simulations using a polarizable ion model (PIM) are employed to determine the density and heat capacity of these melts as a function of temperature. Green-Kubo methods are implemented to calculate the electrical conductivity, thermal conductivity, and viscosity of the salt using the outputs of the simulations. Results for pure molten salt systems are compared to experimental data when possible to validate the potentials used. Here I discuss chloride salt systems of interest, their calculated properties, and possible sources of error for our simulations.

Baty, Austin Alan

2013-05-01T23:59:59.000Z

158

DECONTAMINATION OF PLUTONIUM FOR FLUORIDE AND CHLORIDE DURING OXALATE PRECIPITATION, FILTRATION AND CALCINATION PROCESSES  

SciTech Connect

Due to analytical limitations for the determination of fluoride (F) and chloride (Cl) in a previous anion exchange study, an additional study of the decontamination of Pu from F and Cl by oxalate precipitation, filtration and calcination was performed. Anion product solution from the previous impurity study was precipitated as an oxalate, filtered, and calcined to produce an oxide for analysis by pyrohydrolysis for total Cl and F. Analysis of samples from this experiment achieved the purity specification for Cl and F for the proposed AFS-2 process. Decontamination factors (DF's) for the overall process (including anion exchange) achieved a DF of {approx}5000 for F and a DF of {approx}100 for Cl. Similar experiments where both HF and HCl were spiked into the anion product solution to a {approx}5000 {micro}g /g Pu concentration showed a DF of 5 for F and a DF of 35 for Cl across the combined precipitation-filtration-calcination process steps.

Kyser, E.

2012-07-25T23:59:59.000Z

159

Selective Reduction of Active Metal Chlorides from Molten LiCl-KCl using Lithium Drawdown  

SciTech Connect

In support of optimizing electrorefining technology for treating spent nuclear fuel, lithium drawdown has been investigated for separating actinides from molten salt electrolyte. Drawdown reaction selectivity is a major issue that needs to be investigated, since the goal is to remove actinides while leaving the fission products in the salt. A series of lithium drawdown tests with surrogate fission product chlorides was run to obtain selectivity data with non-radioactive salts, develop a predictive model, and draw conclusions about the viability of using this process with actinide-loadd salt. Results of tests with CsCl, LaCl3, CeCl3, and NdCl3 are reported here. An equilibrium model has been formulated and fit to the experimental data. Excellent fits to the data were achieved. Based on analysis and results obtained to date, it is concluded that clean separation between minor actinides and lanthanides will be difficult to achieve using lithium drawdown.

Michael F. Simpson; Daniel LaBrier; Michael Lineberry; Tae-Sic Yoo

2012-10-01T23:59:59.000Z

160

Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System  

SciTech Connect

The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

Yongchun Tang; John (Qisheng) Ma

2012-03-23T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Tellurite glass as a waste form for a simulated mixed chloride waste stream: Candidate materials selection and initial testing  

Science Conference Proceedings (OSTI)

Tellurite glasses have been researched widely for the last 60 years since they were first introduced by Stanworth. These glasses have been primarily used in research applications as glass host materials for lasers and as non-linear optical materials, though many other uses exist in the literature. Tellurite glasses have long since been used as hosts for various, and even sometimes mixed, halogens (i.e., multiple chlorides or even chlorides and iodides). Thus, it was reasonable to expect that these types of glasses could be used as a waste form to immobilize a combination of mixed chlorides present in the electrochemical separations process involved with fuel separations and processing from nuclear reactors. Many of the properties related to waste forms (e.g., chemical durability, maximum chloride loading) for these materials are unknown and thus, in this study, several different types of tellurite glasses were made and their properties studied to determine if such a candidate waste form could be fabricated with these glasses. One of the formulations studied was a lead tellurite glass, which had a low sodium release and is on-par with high-level waste silicate glass waste forms.

Riley, Brian J.; Rieck, Bennett T.; McCloy, John S.; Crum, Jarrod V.; Sundaram, S. K.; Vienna, John D.

2012-02-02T23:59:59.000Z

162

APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE AND CHLORIDE FROM LEGACY FISSILE MATERIALS  

Science Conference Proceedings (OSTI)

Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and the Savannah River Site (SRS) HB-Line Facility designed, developed, tested, and successfully deployed a production-scale system for the distillation of sodium chloride (NaCl) and potassium chloride (KCl) from plutonium oxide (PuO{sub 2}). Subsequent efforts adapted the vacuum salt distillation (VSD) technology for the removal of chloride and fluoride from less-volatile halide salts at the same process temperature and vacuum. Calcium chloride (CaCl{sub 2}), calcium fluoride (CaF{sub 2}), and plutonium fluoride (PuF{sub 3}) were of particular concern. To enable the use of the same operating conditions for the distillation process, SRNL employed in situ exchange reactions to convert the less-volatile halide salts to compounds that facilitated the distillation of halide without removal of plutonium. SRNL demonstrated the removal of halide from CaCl{sub 2}, CaF{sub 2} and PuF{sub 3} below 1000 C using VSD technology.

Pierce, R.; Peters, T.

2011-11-01T23:59:59.000Z

163

Utility Cycle Testing of a 500-kWh Zinc Chloride Battery at the Battery Energy Storage Test (BEST) Facility  

Science Conference Proceedings (OSTI)

A 500-kWh zinc chloride battery test system completed an entire schedule of 80 simulated utility and customer application cycles--the most diverse and severe known to be successfully performed by any advanced battery system. Encouraged by these results, researchers plan to have a 2-MW demonstration battery system ready for testing in 1986.

1985-10-09T23:59:59.000Z

164

ENGINEERING EXPERIENCE AT BROOKHAVEN NATIONAL LABORATORY IN HANDLING FUSED CHLORIDE SALTS  

SciTech Connect

Two fused chloride salt eutectics, binary LiCl-KCl and ternary NaCl- KCl- MgCl/sub 2/, were used in fuel processing studies as part of the Liquid Metal Fuel Reactor research and development program. Results of engineering work done at Brookhaven since 1950 are summarized. It was demonstrated that fused chloride salt technology is sufficiently developed so that loops and other experimental equipment can be designed and operated at 500 deg C with a high degree of confidence. The equipment, which was operated for many hours, included a large forced-circulation loop and many thermal-convection loops and tanks. The specifications used for the fabrication, cleaning, and testing of equipment for salt service are described. All welded systems, welded by the usual inert-arc procedures, are preferred, but ring type joint stainless-steel flanged connections were found satisfactory, mainly for connecting melt tanks to experimental equipment and for mounting orifice flowmeters. The surfaces of equipment to be used with fused salts were cleaned satisfactorily prior to assembly by several different methods, but sandblasting was found applicable to all types of equipment. Radiography was used to check all welds in contact with fused salt for flaws and, during operation, to locate and determine the cause of any malfunction. Components tested at the normal operating temperature of 500 deg C included pumps, valves, agitators, sightports, samplers, and filtens. Salt samples were usually taken by the thief method. Both stationary and movable resistance type, liquid-level probes were used and were reliable so long as the salt surface remained quiescent; otherwise, splashing and short-circuiting occurred. Nullmatic, pilot-operated pressure transmitters gave good service in conjunction with both orifice and Venturi flowmeters. A procedure is described for preparing pound quantities of pure eutectics, which, in the case of the ternary eutectic, differs from that used in preparing gram quantities. Both eutectics were pretreated with a Bi- Mg-U solution to remove oxidizing impurities before use in corrosion and processing experiments. The results of physical property measurements on the two eutectics are included. (auth)

Raseman, C.J.; Susskind, H.; Farber, G.; McNulty, W.E.; Salzano, F.J.

1960-06-01T23:59:59.000Z

165

Membrane Transport Behavior and the Lability of Chloride on Polyphosphazenes Bearing Bulky Substituents  

SciTech Connect

Polyphosphazenes are an intriguing class of inorganic polymers where much of their functionality is derived from pendant groups attached to phosphorus. The backbone of the polymer consists of alternating phosphorus and nitrogen atoms where the bonding is conventionally drawn as alternating double and single bonds. Orbital nodes are located at each phosphorus atom resulting in electron delocalization between phosphorus atoms, but not through them. Thus, the polymer backbone has a high degree of flexibility where halogens or other leaving groups can be effectively displaced with nucleophiles. In this paper, the first known example of a polyphosphazene with large quantities of non-labile chloride substituents induced by neighboring group steric effects will be discussed. This example is the result of the substitution of poly[bis-chlorophosphazene] with the sodium salt of 3,5-di-tert-butylphenol where only 60% of the chlorines were displaced. This contrasts with the 100% substitution observed with other phenols (phenol, 4-tert-butylphenol, 3-methylphenol, etc.).

Frederick F. Stewart; John R. Klaehn; Christopher J. Orme

2007-08-01T23:59:59.000Z

166

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride)  

DOE Green Energy (OSTI)

A long-chain polyelectrolyte, poly(diallyldimethylammonium chloride) (PDDA), has been employed to stabilize platinum nanoparticles for oxygen reduction in polymer electrolyte membrane (PEM) fuel cells. Pt nanoparticles were synthesized by reducing H2PtCl6 with NaBH4 in the presence of PDDA and then deposited on carbon support (PDDA-Pt/C). Transmission electron microscope images showed that Pt nanoparticles of PDDA-Pt/C are uniformly dispersed on carbon support with a mean size of about 2.2 nm (2.1 nm for commercial Etek-Pt/C). PDDA-Pt/C exhibited a higher activity towards oxygen reduction reaction (ORR) than Etek-Pt/C. The durability of PDDA-Pt/C was improved by a factor of 2 as compared with Etek-Pt/C. X-ray photoelectron spectroscopy characterization of PDDA-Pt/C revealed the interaction between Pt nanoparticles and PDDA, which increased Pt oxidation potential. PDDA-Nafion ionic crosslinking "entraps" Pt nanoparticles and prevents Pt nanoparticles from migrating/agglomerating on or detaching from carbon support. This provides a promising strategy to improve both the durability and activity of electrocatalysts for fuel cells.

Zhang, Sheng; Shao, Yuyan; Yin, Geping; Lin, Yuehe

2009-10-29T23:59:59.000Z

167

Bench-scale studies of in-duct mercury capture using cupric chloride-impregnated carbons  

Science Conference Proceedings (OSTI)

A brominated activated carbon (Darco Hg-LH) and cupric chloride-impregnated activated carbon (CuCl{sub 2}-ACs) sorbent have been tested in a bench-scale entrained-flow reactor system which was developed for simulating in-flight mercury capture in ducts upstream of particulate matter control devices. The bench-scale experimental system has been operated with the conditions of a residence time of 0.75 s and a gas temperature of 140{sup o}C to simulate typical conditions in the duct of coal-fired exhaust gas. In addition, sorbent deposition on walls which can occur in a laboratory-scale system more than in a full-scale system was significantly reduced so that additional mercury capture by the deposited sorbent was minimized. In the entrained-flow system, CuCl{sub 2}-ACs demonstrated similar performance in Hg adsorption and better performance in Hg{sup 0} oxidation than Darco Hg-LH. In addition, the carbon content of those sorbents was found to determine their Hg adsorption capability in the entrained-flow system. The bench-scale entrained-flow system was able to demonstrate the important Hg adsorption and oxidation characteristics of the tested sorbents. 18 refs., 9 figs., 1 tab.

Sang-Sup Lee; Joo-Youp Lee; Tim C. Keener [University of Cincinnati, Cincinnati, OH (United States). Department of Civil and Environmental Engineering

2009-04-15T23:59:59.000Z

168

Novel Ternary Molten Salt Electrolytes for intermediate-temperature sodium/nickel chloride batteries  

SciTech Connect

The sodium-nickel chloride (ZEBRA) battery is typically operated at relatively high temperature (250~350°C) to achieve adequate electrochemical performance. Reducing the operating temperature in the range of 150 to 200°C can lead to enhanced cycle life by suppressing temperature related degradation mechanisms. The reduced temperature range also allows for lower cost materials of construction such as elastomeric sealants and gaskets. To achieve adequate electrochemical performance at lower operating temperatures requires an overall reduction in ohmic losses associated with temperature. This includes reducing the ohmic resistance of ?”-alumina solid electrolyte (BASE) and the incorporation of low melting point molten salt as the secondary electrolyte. In present work, planar-type Na/NiCl2 cells with a thin flat plate BASE (600 ?m) and low melting point secondary electrolyte were evaluated at reduced temperatures. Molten salt formulation for use as secondary electrolytes were fabricated by the partial replace of NaCl in the standard secondary electrolyte (NaAlCl4) with other lower melting point alkali metal salts such as NaBr, LiCl, and LiBr. Electrochemical characterization of the ternary molten salts demonstrated , improved ionic conductivity, and sufficient electrochemical window at reduced temperatures. Furthermore, Na/NiCl2 cells with 50 mol% NaBr-containing secondary electrolyte exhibited reduced polarizations at 175°C compared to the cell with the standard NaAlCl4 catholyte. The cells also exhibited stable cycling performance even at 150oC.

Li, Guosheng; Lu, Xiaochuan; Coyle, Christopher A.; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2012-12-15T23:59:59.000Z

169

DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES  

DOE Green Energy (OSTI)

Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at SRI and RTI to conduct tests at high-temperature, high-pressure conditions (HTHP). The HTHP tests confirmed the ability of nahcolite pellets and granules to reduce the HCl vapor levels to less than 1 ppm levels with a very high sorbent utilization for chloride capture. The effect of several operating variables such as temperature, pressure, presence of hydrogen sulfide, and sorbent preparation methods was studied on the efficacy of HCl removal by the sorbent. Pilot-scale tests were performed in the fluidized-bed mode at the gasifier facility at the GE-CRD. Sorbent exposure tests were also conducted using a hot coal gas stream from the DOE/FETC's fluidized-bed gasifier at Morgantown, WV. These tests confirmed the results obtained at SRI and RTI. A preliminary economic assessment showed that the cost of HCl removal in a commercial IGCC system will be about $0.001/kWh (1 mills/kWh).

Gopala Krishnan; Raghubir Gupta

1999-09-01T23:59:59.000Z

170

Neural Network Modeling of the Lithium/Thionyl Chloride Battery System  

DOE Green Energy (OSTI)

Battery systems have traditionally relied on extensive build and test procedures for product realization. Analytical models have been developed to diminish this reliance, but have only been partially successful in consistently predicting the performance of battery systems. The complex set of interacting physical and chemical processes within battery systems has made the development of analytical models a significant challenge. Advanced simulation tools are needed to more accurately model battery systems which will reduce the time and cost required for product realization. Sandia has initiated an advanced model-based design strategy to battery systems, beginning with the performance of lithiumhhionyl chloride cells. As an alternative approach, we have begun development of cell performance modeling using non-phenomenological models for battery systems based on artificial neural networks (ANNs). ANNs are inductive models for simulating input/output mappings with certain advantages over phenomenological models, particularly for complex systems. Among these advantages is the ability to avoid making measurements of hard to determine physical parameters or having to understand cell processes sufficiently to write mathematical functions describing their behavior. For example, ANN models are also being studied for simulating complex physical processes within the Li/SOC12 cell, such as the time and temperature dependence of the anode interracial resistance. ANNs have been shown to provide a very robust and computationally efficient simulation tool for predicting voltage and capacity output for Li/SOC12 cells under a variety of operating conditions. The ANN modeling approach should be applicable to a wide variety of battery chemistries, including rechargeable systems.

Ingersoll, D.; Jungst, R.G.; O'Gorman, C.C.; Paez, T.L.

1998-10-29T23:59:59.000Z

171

Complete detoxification of short chain chlorinated aliphatic compounds: Isolation of halorespiring organisms and biochemical studies of the dehalogenating enzyme systems. 1998 annual progress report  

SciTech Connect

'Widespread use and careless handling, storage and disposal practices, have lead to the dissemination of chlorinated short chain aliphatics into groundwater systems. These compounds are toxic and the presence of chlorinated ethenes and chlorinated propanes in the environment is of public concern. Halorespiration is a newly recognized anaerobic process by which certain bacteria use chlorinated compounds as terminal electron acceptors in their energy metabolism. In contrast to co-metabolic dechlorination, which is fortuitous, slow, and without benefit to the organisms, halorespiration, characterized by high dechlorination rates, is a specific metabolic process beneficial to the organism. The goals are to isolate and characterize organisms which use chlorinated ethenes (including tetrachloroethene [PCE], trichloroethene [TCE], cis-dichloroethene [cis-DCE], and vinyl chloride [VC], or 1,2-dichloropropane [1,2-D]) as electron acceptors in their energy metabolism. Better understanding of the physiology and phylogeny of the halorespiring organisms as well as the biochemistry of the dehalogenating enzyme systems, will greatly enhance the authors knowledge of how these organisms can successfully be employed in the bioremediation of contaminated sites. This report summarizes the results of 1.5 years of a 2-year project. Anaerobic microcosms were established using a variety of geographically distinct sediments. In several microcosms complete dechlorination of PCE to ethene (ETH), and 1,2-D to propene was observed. Upon subsequent transfers to anaerobic medium, four sediment-free, methanogenic enrichment cultures were obtained that dechlorinated PCE to ETH, and two cultures that dechlorinated 1,2-D to propene. 2-Bromoethanesulfonate (BES), a well known inhibitor of methanogens, did not inhibit the dechlorination of 1,2-D to propene or the dechlorination of PCE to cis-DCE. However, the complete dechlorination of PCE to VC and ETH was severely inhibited. They could also show that BES inhibited the dechlorination of chloroethenes in cultures without methanogens. Therefore, BES should not be used to attribute dechlorination activities to methanogens.'

Tiedje, J.M.

1998-06-01T23:59:59.000Z

172

Selected genomic and phenotypic responses of Salmonella serovars to chlorine, chlorine dioxide, and cetylpyridinium chloride  

E-Print Network (OSTI)

Non-typhoidal Salmonella enterica serovars continue to be the leading cause of foodborne illnesses in United States. Chlorine, chlorine related, and quaternary compounds are generally used for disinfecting carcasses and equipment in processing industries. The current study was aimed at understanding the inactivation kinetics of four Salmonella serovars to chlorine, chlorine dioxide and cetylpyridinium chloride (CPC). The transcriptomic responses to oxidative stress was investigated in stationary and log phase cells of S. Typhimurium. The study was also aimed at understanding the effect of the chemicals on the expression of virulence genes associated with the Salmonella Pathogenecity Island 1 (SPI1). The possible induction of the viable but nonculturable (VBNC) state in Salmonella due to CPC was also investigated. The inactivation parameters for each serovar and the chemical were estimated based on the Hom's model, ln (N/N0) = -k C^n T^m and it appeared that while disinfectant contact time was significant, biocide concentration in the overall disinfection was insignificant. This was true especially for chlorine and CPC with subtle differences observed between the serovars. The inactivation efficacy was, however, dependent on both concentration and the exposure time for chlorine dioxide. The highest degree of inactivation was obtained with chlorine followed by chlorine dioxide and CPC. Transcriptomic responses of S. Typhimurium revealed significant downregulation of several metabolic processes such as tricarboxylic acid cycle, oxidative phosphorylation, and amino acid biosynthesis in both log and stationary phase cells. Several stress related genes such as usp, rpoS and ompR were upregulated in the stationary phase cells. Majority of the virulence genes associated with the SPI1 were found to be downregulated for all the treatments. While treatment with chlorine and CPC caused downregulation of all the virulence genes, treatment with chlorine dioxide caused significant upregulation of few (hilC, invC, sipA and sipB) genes associated with the SPI1. Finally, the induction of VBNC state was not concluded as a result of treatment with CPC. However, significant percentage of cells (45 percent) with intact membrane was established based on the BacLight assayTM.

Kakani, Grihalakshmi

2011-05-01T23:59:59.000Z

173

Thermal Analysis of Surrogate Simulated Molten Salts with Metal Chloride Impurities for Electrorefining Used Nuclear Fuel  

SciTech Connect

This project is a fundamental study to measure thermal properties (liquidus, solidus, phase transformation, and enthalpy) of molten salt systems of interest to electrorefining operations, which are used in both the fuel cycle research & development mission and the spent fuel treatment mission of the Department of Energy. During electrorefining operations the electrolyte accumulates elements more active than uranium (transuranics, fission products and bond sodium). The accumulation needs to be closely monitored because the thermal properties of the electrolyte will change as the concentration of the impurities increases. During electrorefining (processing techniques used at the Idaho National Laboratory to separate uranium from spent nuclear fuel) it is important for the electrolyte to remain in a homogeneous liquid phase for operational safeguard and criticality reasons. The phase stability of molten salts in an electrorefiner may be adversely affected by the buildup of fission products in the electrolyte. Potential situations that need to be avoided are: (i) build up of fissile elements in the salt approaching the criticality limits specified for the vessel (ii) freezing of the salts due to change in the liquidus temperature and (iii) phase separation (non-homogenous solution) of elements. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This work describes the experimental results of typical salts compositions, consisting of chlorides of strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium (as a surrogate for both uranium and plutonium), used in the processing of used nuclear fuels. Differential scanning calorimetry was used to analyze numerous salt samples providing results on the thermal properties. The property of most interest to pyroprocessing is the liquidus temperature. It was previously known the liquidus temperature of the molten salt would change as spent fuel is processed through the Mk-IV electrorefiner. However, the extent of the increase in liquidus temperature was not known. This work is first of its kind in determining thermodynamic properties of a molten salt electrolyte containing transuranics, fission products and bond sodium. Experimental data concluded that the melting temperature of the electrolyte will become greater than the operating temperature of the Mk-IV ER during current fuel processing campaigns. Collected data also helps predict when the molten salt electrolyte will no longer be able to support electrorefining operations.

Toni Y. Gutknecht; Guy L. Fredrickson; Vivek Utgikar

2012-04-01T23:59:59.000Z

174

An In-depth Investigation of an Aluminum Chloride Retarded Mud Acid System on Sandstone Reservoirs  

E-Print Network (OSTI)

Sandstone acidizing using mud acid is a quick and complex process where dissolution and precipitation occur simultaneously. Retarded mud acids are less reactive with the rock reducing the reaction rate hence increased penetration into the formation to remove deep damage. To understand thoroughly the retarded mud acid system, an in-depth investigation of the reaction of HF (hydrofluoric) and H2SiF6 (fluorosilic acid) with alumino silicates and the retarded system is undertaken using coreflood analysis and mineralogy analysis using the inductively coupled plasma. Coreflood analysis is used to understand and investigate the permeability changes in the sandstone rock as the retarded mud acid is injected at different conditions and the inductively coupled plasma (ICP) is used to investigate the effluent samples from the coreflood analysis to properly understand this system. Several issues that have not been addressed previously in literature are identified and discussed, including an optimum flowrate when sandstone is acidized, by acidizing the sandstone rock with a retarded acid system at various flowrates and determining the initial and final permeabilities. Also investigated is the retarded acids compatibility with ferric iron and a comparison of the retarded acid system to regular acid to consequently enable a thorough understanding of the retarded mud acid system using aluminum chloride (AlRMHF). Based on the work done, it is found that the absence of a hydrochloric (HCl) preflush is very detrimental to the sandstone core as calcium fluoride is precipitated and the retarded acid system is found to be compatible with iron(III) as an impurity. The regular acid (RMHF) dissolves considerably more silicon and produces more fines than the AlRMHF. 1cc/min is found to be the optimum flowrate when a sandstone core is acidized with AlRMHF. At this low flowrate, less silicon is dissolved, more aluminum is seen in the effluent and more calcium is dissolved. The retarded aluminum acid system considerably reduces the rate of reaction as evidenced in the dissolution reaction when compared to a regular mud acid system. This reduced rate of reaction implies deeper acid penetration and ultimately deeper damage removal.

Aneto, Nnenna

2012-05-01T23:59:59.000Z

175

Spectroscopy and decay kinetics of Pr{sup 3+}-doped chloride crystals for 1300-nm optical amplifiers  

Science Conference Proceedings (OSTI)

Several Pr{sup 3+}-doped chloride crystals have been tested spectroscopically for suitability as 1300-nm optical amplifiers operating on the {sup 1}G{sub 4} - {sup 3}H{sub 5} transition. {sup 1}G{sub 4} lifetimes are much longer than in fluoride hosts, ranging up to 1300 {mu}sec and suggesting a near-unity luminescence quantum yield. Emission spectra are typically broad (FWHM {approximately} 70 nm) and include the 1310-nm zero-dispersion wavelength of standard telecommunications fiber.

Page, R.H.; Schaffers, K.I.; Wilke, G.D. [and others

1995-03-09T23:59:59.000Z

176

Effect of Organic Acid Additions on the General and Localized Corrosion Susceptibility of Alloy 22 in Chloride Solutions  

Science Conference Proceedings (OSTI)

Electrochemical studies such as cyclic potentiodynamic polarization (CPP) and electrochemical impedance spectroscopy (EIS) were performed to determine the corrosion behavior of Alloy 22 (N06022) in 1M NaCl solutions at various pH values from acidic to neutral at 90 C. All the tested material was wrought Mill Annealed (MA). Tests were also performed in NaCl solutions containing weak organic acids such as oxalic, acetic, citric and picric. Results show that the corrosion rate of Alloy 22 was significantly higher in solutions containing oxalic acid than in solutions of pure NaCl at the same pH. Citric and picric acids showed a slightly higher corrosion rate, and acetic acid maintained the corrosion rate of pure chloride solutions at the same pH. Organic acids revealed to be weak inhibitors for crevice corrosion. Higher concentration ratios, compared to nitrate ions, were needed to completely inhibit crevice corrosion in chloride solutions. Results are discussed considering acid dissociation constants, buffer capacity and complex formation constants of the different weak acids.

Carranza, R M; Giordano, C M; Rodr?guez, M A; Ilevbare, G O; Rebak, R B

2007-08-28T23:59:59.000Z

177

Radiation Stability of Benzyl Tributyl Ammonium Chloride Towards Technetium-99 Extraction  

SciTech Connect

A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning process, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, low nitric acid concentration in the aqueous phase of a UREX based process will co-extract U(VI) and Tc(VII) by tri-n-butyl phosphate (TBP). Technetium (Tc-99) is recognized to be one of the most abundant, long-lived radiotoxic isotopes in UNF (half-life, t1/2 = 2.13 × 105 years), and as such, it is targeted in UNF separation strategies for isolation and encapsulation in solid waste forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flow sheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste forms for ultimate disposal. Furthermore, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macrocompounds such as crown-ethers, aza-crown ethers, and resorcinarenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO4- by benzyltributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand’s matrix conditions and concentration, as well as varying the organic phase composition (i.e., diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using external Co-60 source. Post-irradiation solvent extraction measurements will be discussed.

Jared Horkley; Audrey Roman; Keri Campbell; Ana Nunez; Amparo Espartero

2013-02-01T23:59:59.000Z

178

Bioremediation of Trichloroethylene-Contaminated Sediments Augmented with a Dehalococcoides Consortia  

DOE Green Energy (OSTI)

At the Department of Energy's (DOE) Savannah River Site (SRS) in Aiken, SC there are a number of sites contaminated with Chlorinated Ethenes (CE) due to past disposal practices. Sediments from two CE contaminated SRS locations were evaluated for trichloroethylene (TCE) biodegradation through anaerobic laboratory microcosms. The testing included addition of amendments and bioaugmentation of sediments. The anaerobic microcosms were first amended with substrates including acetate, lactate, molasses, soybean oil, methanol, sulfate, yeast extract, Regenesis HRC(R), and MEAL (methanol, ethanol, acetate, lactate mixture). Microcosms were analyzed after biostimulation for 9 months and no significant TCE biodegradation was observed. At 10 months, additional TCE, fresh amendments, and a mixed culture containing Dehalococcoides ethenogenes were added to active microcosms. A significant decrease in TCE concentrations and an increase in biodegradation products cis-dichloroethylene (cDCE) and vinyl chloride (VC) were noted within 2 weeks of bioaugmentation. Microcosms amended with lactate and sulfate showed complete transformation of TCE (3 ppm) to ethene within 40 days after bioaugmentation. Microcosms amended with other substrates - soybean oil, acetate, yeast extract, and methanol - also show enhanced biodegradation of TCE to ethene. Microcosms amended with molasses and Regenesis HRC showed limited TCE transformation. No TCE transformation was seen in killed control microcosms. On the basis of these successful results, plans are underway for field-scale in-situ deployment of biostimulation/bioaugmentation at SRS.

McKinsey, P.C.

2003-02-20T23:59:59.000Z

179

Synthesis and characterization of chloride doped polyaniline by bulk oxidative chemical polymerization.Doping effect on electrical conductivity  

E-Print Network (OSTI)

Conductive polymers or "organic metals" are highly engineered nanostructured materials made from organic building blocks. They are candidates as molecular wires for nanotechnology applications in molecular electronics. The conduction in these polymers is due to the presence of delocalized molecular orbitals. In this work, we present the synthesis of chloride doped polyaniline by bulk oxidative chemical polymerization using a solid aniline salt as a monomer instead of liquid aniline to diminish toxic hazards. The FTIR and UV-visible spectra confirmed the expected structure of the polymer. The electrical conductivity measured using a four-probe method was 1.7 S/cm. The dependence of impedance modulus on frequency was measured using an HP impedance analyzer in the range 10 kHz-13 MHz. The influence of doping and the preparation temperature on the electrical conductivity were also investigated.

Yomen Atassi; Mohammad Tally; Mazen Ismail

2008-09-21T23:59:59.000Z

180

Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy  

E-Print Network (OSTI)

chloride salt eutectics for solar thermal-energy storage applications Donghyun Shin, Debjyoti Banerjee solution, resulting in degradation of the thermal properties. Solar energy conversion to electricity is achieved primarily by using (a) photovoltaic technology, or (b) by harnessing solar thermal-energy

Banerjee, Debjyoti

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181

Cl atom recombination on silicon oxy-chloride layers deposited on chamber walls in chlorine-oxygen plasmas  

SciTech Connect

Chlorine atom recombination coefficients were measured on silicon oxy-chloride surfaces deposited in a chlorine inductively coupled plasma (ICP) with varying oxygen concentrations, using the spinning wall technique. A small cylinder embedded in the walls of the plasma reactor chamber was rapidly rotated, repetitively exposing its surface to the plasma chamber and a differentially pumped analysis chamber housing a quadruple mass spectrometer for line-of-sight desorbing species detection, or an Auger electron spectrometer for in situ surface analysis. The spinning wall frequency was varied from 800 to 30 000 rpm resulting in a detection time, t (the time a point on the surface takes to rotate from plasma chamber to the position facing the mass or Auger spectrometer), of {approx}1-40 ms. Desorbing Cl{sub 2}, due to Langmuir-Hinshelwood (LH) Cl atom recombination on the reactor wall surfaces, was detected by the mass spectrometer and also by a pressure rise in one of the differentially pumped chambers. LH Cl recombination coefficients were calculated by extrapolating time-resolved desorption decay curves to t = 0. A silicon-covered electrode immersed in the plasma was either powered at 13 MHz, creating a dc bias of -119 V, or allowed to electrically float with no bias power. After long exposure to a Cl{sub 2} ICP without substrate bias, slow etching of the Si wafer coats the chamber and spinning wall surfaces with an Si-chloride layer with a relatively small amount of oxygen (due to a slow erosion of the quartz discharge tube) with a stoichiometry of Si:O:Cl = 1:0.38:0.38. On this low-oxygen-coverage surface, any Cl{sub 2} desorption after LH recombination of Cl was below the detection limit. Adding 5% O{sub 2} to the Cl{sub 2} feed gas stopped etching of the Si wafer (with no rf bias) and increased the oxygen content of the wall deposits, while decreasing the Cl content (Si:O:Cl = 1:1.09:0.08). Cl{sub 2} desorption was detectable for Cl recombination on the spinning wall surface coated with this layer, and a recombination probability of {gamma}{sub Cl} = 0.03 was obtained. After this surface was conditioned with a pure oxygen plasma for {approx}60 min, {gamma}{sub Cl} increased to 0.044 and the surface layer was slightly enriched in oxygen fraction (Si:O:Cl = 1:1.09:0.04). This behavior is attributed to a mechanism whereby Cl LH recombination occurs mainly on chlorinated oxygen sites on the silicon oxy-chloride surface, because of the weak Cl-O bond compared to the Cl-Si bond.

Khare, Rohit; Srivastava, Ashutosh; Donnelly, Vincent M. [Department of Chemical and Biomolecular Engineering, University of Houston, Houston, Texas 77204 (United States)

2012-09-15T23:59:59.000Z

182

Method for making carbon films  

DOE Patents (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area ([approx equal]1000 m[sup 2] /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160 C for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750 C in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750--850 C for between 1--6 hours. 2 figs.

Tan, M.X.

1999-07-29T23:59:59.000Z

183

Method for making carbon films  

DOE Patents (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

Tan, Ming X. (Livermore, CA)

1999-01-01T23:59:59.000Z

184

Carbon Film Electrodes For Super Capacitor Applications  

DOE Patents (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area (.apprxeq.1000 m.sup.2 /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160.degree. C. for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750.degree. C. in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750-850.degree. C. for between 1-6 hours.

Tan, Ming X. (Livermore, CA)

1999-07-20T23:59:59.000Z

185

Speciality conference on: toxic substances in the air environment  

SciTech Connect

Papers presented are divided into the following categories: toxic substances legislation; arsenic; vinyl chloride; and emerging problems in toxic emission. Seven papers were abstracted and indexed individually for ERA/EDB. (JGB)

1977-01-01T23:59:59.000Z

186

Electrolytic regeneration of acid cupric chloride printed circuit board etchant. Final report, August 1, 1995--October 31, 1996  

SciTech Connect

The overall objective of this ERIP program was to make substantial progress in further developing a process for electrolytic regeneration of acid cupric chloride etchant - a process which was initially demonstrated in in-house studies and EPA Phase I and Phase II SBIRs. Specific objectives of the work were: (1) to define optimum system operating conditions by conducting a systematic study of process parameters, (2) to develop or find a superior electrolyic cell separator material, (3) to determine an optimum activation procedure for the flow-through carbon/graphite felt electrodes which are so critical to process performance, (4) to demonstrate - on the pre-prototype scale - electrolytic compensation for oxygen ingress - which causes etchant solution growth, and (5) to begin engineering design work on a prototype-scale regeneration unit. Parametric studies looked at the effect that key plating parameters have on copper deposit quality. Parameters tested included (a) velocity past the plating cathodes, (b) copper concentration in the catholyte solution from which the copper is being plated, (c) plating current density, and (d) catholyte cupric ion concentration. The most significant effects were obtained for velocity changes. The work showed that catholyte velocities above 0.5 ft/sec were needed to get adequate plating at 77.5 mA/cm{sup 2} and higher currents, and that even higher flow was better.

Oxley, J.E.; Smialek, R.J.

1997-04-18T23:59:59.000Z

187

The Influence of Lewis Acid/Base Chemistry on the Removal of Gallium by Volatility from Weapons-Grade Plutonium Dissolved in Molten Chlorides  

Science Conference Proceedings (OSTI)

It has been proposed that GaCl{sub 3} can be removed by direct volatilization from a Pu-Ga alloy that is dissolved in a molten chloride salt. Although pure GaCl{sub 3} is quite volatile (boiling point: 201 deg. C), the behavior of GaCl{sub 3} dissolved in chloride salts is quite different because of solution effects and is critically dependent upon the composition of the solvent salt (i.e., its Lewis acid/base character). In this technical note, the behavior of gallium in prototypical Lewis acid and Lewis base salts is contrasted. It is found that gallium volatility is suppressed in basic melts and promoted in acidic melts. These results have an important influence on the potential for simple gallium removal in molten salt systems.

Williams, David F.; Cul, Guillermo D. del [Oak Ridge National Laboratory (United States); Toth, Louis M. [Electrochemical Systems (United States); Collins, Emory D. [Oak Ridge National Laboratory (United States)

2001-12-15T23:59:59.000Z

188

Natrix -Scoring Sheet 1. 0.01 M Mg Chloride, 0.05 M MES pH 5.6, 2.0 M Lithium Sulfate  

E-Print Network (OSTI)

Natrix - Scoring Sheet 1. 0.01 M Mg Chloride, 0.05 M MES pH 5.6, 2.0 M Lithium Sulfate 2. 0.01 M Mg Cacodylate pH 6.0, 1.0 M Lithium Sulfate 12. 0.01 M Mg Sulfate, 0.05 M Na Cacodylate pH 6.0, 1.8 M Lithium pH 6.5, 1.3 M Lithium Sulfate 19. 0.01 M Mg Sulfate, 0.05 M Na Cacodylate pH 6.5, 2.0 M Ammonium

Hill, Chris

189

"Kohn-Shamification" of the classical density-functional theory of inhomogeneous polar molecular liquids with application to liquid hydrogen chloride  

E-Print Network (OSTI)

The Gordian knot of density-functional theories for classical molecular liquids remains finding an accurate free-energy functional in terms of the densities of the atomic sites of the molecules. Following Kohn and Sham, we show how to solve this problem by considering noninteracting molecules in a set of effective potentials. This shift in perspective leads to an accurate and computationally tractable description in terms of simple three-dimensional functions. We also treat both the linear- and saturation- dielectric responses of polar systems, presenting liquid hydrogen chloride as a case study.

Johannes Lischner; T. A. Arias

2008-06-27T23:59:59.000Z

190

[Characterization of historical infiltration in the unsaturated zone at the Nevada Test Site using chloride, bromide, and chlorine-36 as environmental tracers]; [Final subcontract report  

SciTech Connect

This document is an end-of-contract report, prepared by Hydro Geo Chem for Los Alamos National Laboratory under contract number 9-XDD-6329F-1. The ultimate goal of this work is to characterize historical infiltration and unsaturated flow in the Yucca Mountain area of the Nevada Test Site. Work on this contract has focused on using chloride, bromide, stable chlorine isotopes, and chlorine-36 distributions to evaluate the depth of infiltration in the unsaturated zone. Effort in support of this work has included developing analytical procedures, exploring ways in which to separate the. meteoric component from the rock component, and meeting quality assurance requirements.

NONE

1991-05-17T23:59:59.000Z

191

Zn-Doped RuO2 Electrocatalyts for Selective Oxygen Evolution: Relationship Between Local Structure and Electrocatalytic Behavior in Chloride Containing Media  

SciTech Connect

Nanocrystalline electrocatalytically active materials of chemical composition Ru{sub 1-x}Zn{sub x}O{sub 2} (0 < x < 0.3) were synthesized by freeze-drying technique. The diffraction patterns of the prepared samples corresponded to single-phase rutile type oxides.Local structure of the Ru{sub 1-x}Zn{sub x}O{sub 2} based on refinement of Ru K and Zn K edge EXAFS functions shows clustering of the Zn ions in the blocks with ilmenite structure intergrowing with Ru-rich rutile blocks. Ru{sub 1-x}Zn{sub x}O{sub 2} oxides are selective catalysts for anodic oxygen evolution. The selectivity toward oxygen evolution in the presence of chlorides is affected by the actual Zn content and can be ascribed to structural hindrance of the formation of the surface peroxo group based active sites for chlorine evolution. The selectivity toward oxygen evolution in presence of chlorides is accompanied by the drop of the total activity, which gets more pronounced with increasing Zn content.

V Petrykin; K Macounova; J Franc; O Shlyakhtin; M Klementova; S Mukerjee; p Krtil

2011-12-31T23:59:59.000Z

192

A glass-encapsulated calcium phosphate wasteform for the immobilization of actinide-, fluoride-, and chloride-containing radioactive wastes from the pyrochemical reprocessing of plutonium metal  

SciTech Connect

The presence of halide anions in four types of wastes arising from the pyrochemical reprocessing of plutonium required an immobilization process to be developed in which not only the actinide cations but also the halide anions were immobilized in a durable waste form. At AWE, we have developed such a process using Ca3(PO4)2 as the host material. Successful trials of the process with actinide- and Cl-bearing Type I waste were carried out at PNNL where the immobilization of the waste in a form resistant to aqueous leaching was confirmed. Normalized mass losses determined at 40°C and 28 days were 12 x 10-6 g?m-2 and 2.7 x 10-3 g?m-2 for Pu and Cl, respectively. Accelerated radiation-induced damage effects are being determined with specimens containing 238Pu. No changes in the crystalline lattice have been detected with XRD after the 239Pu equivalent of 400 years ageing. Confirmation of the process for Type II waste (a oxyhydroxide-based waste) is currently underway at PNNL. Differences in the ionic state of Pu in the four types of waste have required different surrogates to be used. Samarium chloride was used successfully as a surrogate for both Pu(III) and Am(III) chlorides. Initial investigations into the use of HfO2 as the surrogate for Pu(IV) oxide in Type II waste indicated no significant differences.

Donald, Ian W.; Metcalfe, Brian; Fong, Shirley K.; Gerrard, Lee A.; Strachan, Denis M.; Scheele, Randall D.

2007-03-31T23:59:59.000Z

193

Technology Evaluations Related to Mercury, Technetium, and Chloride in Treatment of Wastes at the Idaho Nuclear Technology and Engineering Center of the Idaho National Engineering and Environmental Laboratory  

SciTech Connect

The Idaho High-Level Waste and Facility Disposition Environmental Impact Statement defines alternative for treating and disposing of wastes stored at the Idaho Nuclear Technology and Engineering Center. Development is required for several technologies under consideration for treatment of these wastes. This report contains evaluations of whether specific treatment is needed and if so, by what methods, to remove mercury, technetium, and chlorides in proposed Environmental Impact Statement treatment processes. The evaluations of mercury include a review of regulatory requirements that would apply to mercury wastes in separations processes, an evaluation of the sensitivity of mercury flowrates and concentrations to changes in separations processing schemes and conditions, test results from laboratory-scale experiments of precipitation of mercury by sulfide precipitation agents from the TRUEX carbonate wash effluent, and evaluations of methods to remove mercury from New Waste Calcining Facility liquid and gaseous streams. The evaluation of technetium relates to the need for technetium removal and alternative methods to remove technetium from streams in separations processes. The need for removal of chlorides from New Waste Calcining Facility scrub solution is also evaluated.

C. M. Barnes; D. D. Taylor; S. C. Ashworth; J. B. Bosley; D. R. Haefner

1999-10-01T23:59:59.000Z

194

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

195

Hydrogen chloride in diffuse interstellar clouds along the line of sight to W31C (G10.6-0.4)  

E-Print Network (OSTI)

We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight towards the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H35Cl and H37Cl, are observed using the 1b receiver of the Heterodyne Instrument for the Far-Infrared (HIFI) aboard the Herschel Space Observatory. The HCl line is detected in absorption, over a wide range of velocities associated with di?use clouds along the line of sight to W31C. The analysis of the absorption strength yields a total HCl column density of few 10^13 cm^-2, implying that HCl accounts for ~0.6 % of the total gasphase chlorine, which exceeds by a factor of ~6 the theoretical model predictions. This result is comparable to those obtained from the chemically-related species H2Cl+ and HCl+, for which large column densities have also been reported on the same line of sight. The source of discrepancy between models and observations is still unknown; however, the detection of these Cl-bearing molecu...

Monje, R R; Roueff, E; Gerin, M; De Luca, M; Neufeld, D A; Godard, B; Phillips, T G

2013-01-01T23:59:59.000Z

196

CO2-H2O Mixtures in the Geological Sequestration of CO2. II. Partitioning in Chloride Brines at 12-100 °C and 1-600 bar.  

Office of Scientific and Technical Information (OSTI)

CO CO 2 -H 2 O Mixtures in the Geological Sequestration of CO 2 . II. Partitioning in Chloride Brines at 12-100°C and up to 600 bar. Nicolas Spycher and Karsten Pruess Lawrence Berkeley National Laboratory, MS 90-1116, 1 Cyclotron Road, Berkeley, California, USA September 2004 ABSTRACT Correlations presented by Spycher et al. (2003) to compute the mutual solubilities of CO 2 and H 2 O are extended to include the effect of chloride salts in the aqueous phase. This is accomplished by including, in the original formulation, activity coefficients for aqueous CO 2 derived from several literature sources, primarily for NaCl solutions. Best results are obtained when combining the solubility correlations of Spycher et al. (2003) with the activity coefficient formulation of Rumpf et al. (1994) and Duan and Sun (2003), which

197

Determination of the adsorptive capacity and adsorption isotherm of vapor-phase mercury chloride on powdered activated carbon using thermogravimetric analysis  

Science Conference Proceedings (OSTI)

This study investigated the use of thermogravimetric analysis (TGA) to determine the adsorptive capacity and adsorption isotherm of vapor-phase mercury chloride on powdered activated carbon (PAC). The technique is commonly applied to remove mercury-containing air pollutants from gas streams emitted from municipal solid waste incinerators. An alternative form of powdered activated carbon derived from a pyrolyzed tire char was prepared for use herein. The capacity of waste tire-derived PAC to adsorb vapor-phase HgCl{sub 2} was successfully measured using a self-designed TGA adsorption system. Experimental results showed that the maximum adsorptive capacities of HgCl{sub 2} were 1.75, 0.688, and 0.230 mg of HgCl{sub 2} per gram of powdered activated carbon derived from carbon black at 30, 70, and 150{sup o} for 500 {mu}g/m{sup 3} of HgCl{sub 2}, respectively. Four adsorption isotherms obtained using the Langmuir, Freundlich, Redlich-Peterson, and Brunauer-Emmett-eller (BET) models were used to simulate the adsorption of HgCl{sub 2}. The comparison of experimental data associated with the four adsorption isotherms indicated that BET fit the experimental results better than did the other isotherms at 30{sup o}, whereas the Freundlich isotherm fit the experimental results better at 70 and 150{sup o}. Furthermore, the calculations of the parameters associated with Langmuir and Freundlich isotherms revealed that the adsorption of HgCl{sub 2} by PAC-derived carbon black favored adsorption at various HgCl{sub 2} concentrations and temperatures. 35 refs., 7 figs., 3 tabs.

Hsun-Yu Lin; Chung-Shin Yuan; Wei-Ching Chen; Chung-Hsuang Hung [National Sun Yat-Sen University, Taiwan (China). Institute of Environmental Engineering

2006-11-15T23:59:59.000Z

198

Anisotropy Characterization of I-125 Seed with Attached Encapsulated Cobalt Chloride Complex Contrast Agent Markers for MRI-Based Prostate Brachytherapy  

Science Conference Proceedings (OSTI)

We have developed a novel MRI marker for prostate brachytherapy. The purpose of this study was to evaluate the changes in anisotropy when cobalt chloride complex contrast agent encapsulated contrast agent markers (C4-ECAM) were placed adjacent to an iodine-125 (I-125) titanium seed, and to verify that the C4-ECAMs were visible on magnetic resonance imaging (MRI) after radiation exposure. Two C4-ECAMs were verified to be MRI visible in a phantom before radiation exposure. The C4-ECAMs were then attached to each end of a 12.7-U (10-mCi) I-125 titanium seed in a polymer tube. Anisotropy was measured and analyzed with the seed alone and with attached C4-ECAMs by suspending thermoluminescent dosimeters in a water phantom in 2 circles surrounding the radioactive source with radius of 1 or 2 cm. A T1-weighted MRI evaluation of C4-ECAMs was then performed after exposure to the amount of radiation typically delivered during 1 month of prostate brachytherapy. Measured values of the anisotropy function F(r, {theta}) for the I-125 seed with and without the C4-ECAMs were mutually statistically indistinguishable (standard error of the mean <4.2%) and agreed well with published TG-43 values for the bare seed. As expected, the anisotropy function {phi}{sub an}(r) for the 2 datasets (with and without C4-ECAMs) derived from the measured F(r, {theta}) did not exhibit statistically measurable difference. Both datasets showed agreement with the published TG-43 {phi}{sub an}(r) for the bare seed. The C4-ECAMs were well visualized by MRI after 1 month of radiation exposure. There were no changes in anisotropy when the C4-ECAMs were placed next to an I-125 radioactive seed, and the C4-ECAMs were visualized after radiation exposure.

Frank, Steven J., E-mail: sjfrank@mdanderson.or [Department of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Tailor, Ramesh C.; Kudchadker, Rajat J. [Department of Radiation Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Martirosyan, Karen S. [Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX (United States); Stafford, R. Jason; Elliott, Andrew M. [Department of Imaging Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Swanson, David A. [Department of Urology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Sing, David; Choi, Jonathan [Department of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Mourtada, Firas; Ibbott, Geoffrey S. [Department of Radiation Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States)

2011-07-01T23:59:59.000Z

199

Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles. Volume 3, Transport of sodium-sulfur and sodium-metal-chloride batteries  

DOE Green Energy (OSTI)

This report examines the shipping regulations that govern the shipment of dangerous goods. Since the elemental sodium contained in both sodium-sulfur and sodium-metal-chloride batteries is classified as a dangerous good, and is listed on both the national and international hazardous materials listings, both national and international regulatory processes are considered in this report The interrelationships as well as the differences between the two processes are highlighted. It is important to note that the transport regulatory processes examined in this report are reviewed within the context of assessing the necessary steps needed to provide for the domestic and international transport of sodium-beta batteries. The need for such an assessment was determined by the Shipping Sub-Working Group (SSWG) of the EV Battery Readiness Working Group (Working Group), created in 1990. The Working Group was created to examine the regulatory issues pertaining to in-vehicle safety, shipping, and recycling of sodium-sulfur batteries, each of which is addressed by a sub-working group. The mission of the SSWG is to establish basic provisions that will ensure the safe and efficient transport of sodium-beta batteries. To support that end, a proposal to the UN Committee of Experts was prepared by the SSWG, with the goal of obtaining a proper shipping name and UN number for sodium-beta batteries and to establish the basic transport requirements for such batteries (see the appendix for the proposal as submitted). It is emphasized that because batteries are large articles containing elemental sodium and, in some cases, sulfur, there is no existing UN entry under which they can be classified and for which modal transport requirements, such as the use of packaging appropriate for such large articles, are provided for. It is for this reason that a specific UN entry for sodium-beta batteries is considered essential.

Hammel, C.J.

1992-09-01T23:59:59.000Z

200

Toxicometabolomics approach to urinary biomarkers for mercuric chloride (HgCl{sub 2})-induced nephrotoxicity using proton nuclear magnetic resonance ({sup 1}H NMR) in rats  

Science Conference Proceedings (OSTI)

The primary objective of this study was to determine and characterize surrogate biomarkers that can predict nephrotoxicity induced by mercuric chloride (HgCl{sub 2}) using urinary proton nuclear magnetic resonance ({sup 1}H NMR) spectral data. A procedure for {sup 1}H NMR urinalysis using pattern recognition was proposed to evaluate nephrotoxicity induced by HgCl{sub 2} in Sprague-Dawley rats. HgCl{sub 2} at 0.1 or 0.75 mg/kg was administered intraperitoneally (i.p.), and urine was collected every 24 h for 6 days. Animals (n = 6 per group) were sacrificed 3 or 6 days post-dosing in order to perform clinical blood chemistry tests and histopathologic examinations. Urinary {sup 1}H NMR spectroscopy revealed apparent differential clustering between the control and HgCl{sub 2} treatment groups as evidenced by principal component analysis (PCA) and partial least square (PLS)-discriminant analysis (DA). Time- and dose-dependent separation of HgCl{sub 2}-treated animals from controls was observed by PCA of {sup 1}H NMR spectral data. In HgCl{sub 2}-treated rats, the concentrations of endogenous urinary metabolites of glucose, acetate, alanine, lactate, succinate, and ethanol were significantly increased, whereas the concentrations of 2-oxoglutarate, allantoin, citrate, formate, taurine, and hippurate were significantly decreased. These endogenous metabolites were selected as putative biomarkers for HgCl{sub 2}-induced nephrotoxicity. A dose response was observed in concentrations of lactate, acetate, succinate, and ethanol, where severe disruption of the concentrations of 2-oxoglutarate, citrate, formate, glucose, and taurine was observed at the higher dose (0.75 mg/kg) of HgCl{sub 2}. Correlation of urinary {sup 1}H NMR PLS-DA data with renal histopathologic changes suggests that {sup 1}H NMR urinalysis can be used to predict or screen for HgCl{sub 2}-induced nephrotoxicity{sub .}

Kim, Kyu-Bong, E-mail: kyubong@inje.ac.k [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Department of Pharmaceutical Engineering, Inje University, Obang-dong, Gimhae, Gyungnam 621-749 (Korea, Republic of); Um, So Young, E-mail: syum@kfda.go.k [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Chung, Myeon Woo, E-mail: mwchung@kfda.go.k [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Jung, Seung Chul, E-mail: ipipe4@nate.co [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Oh, Ji Seon, E-mail: aquajs24@nate.co [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Kim, Seon Hwa, E-mail: hwa2003@kfda.go.k [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Na, Han Sung, E-mail: nhk1515@korea.k [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of); Lee, Byung Mu, E-mail: bmlee@skku.ed [College of Pharmacy, Sungkyunkwan University, 300 Cheoncheon-dong, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Choi, Ki Hwan, E-mail: hyokwa11@korea.k [Korea Food and Drug Administration, 5-Nokbun-dong, Eunpyung-gu, Seoul 122-704 (Korea, Republic of)

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Dehydration of Magnesium Chloride Hexahydrate  

Science Conference Proceedings (OSTI)

Transfer and Consumption of Oxygen in Gold-bearing Sulfide Ores: Agnico-eagle Mines Trials · Tundish Process Performance Improvement: Some Indian Case ...

202

Final report from VFL Technologies for the pilot-scale thermal treatment of lower East Fork Poplar Creek floodplain soils. LEFPC appendices, Volume 4, Appendix V-C  

Science Conference Proceedings (OSTI)

This is the the final verification run data package for pilot scale thermal treatment of lower East Fork Poplar Creek floodplain soils. Included are data on volatiles, semivolatiles, and TCLP volatiles.

NONE

1994-09-01T23:59:59.000Z

203

Research Needs: Glass Solar Reflectance and Vinyl Siding  

E-Print Network (OSTI)

properties of reflected solar radiation from glass surfaces,transfer at the siding surface. Direct solar radiation tosiding, reflected solar radiation from nearby surfaces,

Hart, Robert

2012-01-01T23:59:59.000Z

204

Research Needs: Glass Solar Reflectance and Vinyl Siding  

E-Print Network (OSTI)

of the University of California, nor any of their employees,of the University of California. The views and opinions ofof the University of California. Research Needs: Glass Solar

Hart, Robert

2012-01-01T23:59:59.000Z

205

Technical and economic feasibility of salt-gradient solar ponds at the Truscott Brine Lake of the Red River Chloride Control Project. A report to the House-Senate Committee on Appropriations of the Ninety-Seventh Congress  

DOE Green Energy (OSTI)

The Truscott Brine Lake is being constructed to impound highly brackish water from a number of sources which would normally flow into the Wichita River, a tributary of the Red River in Knox County, Texas. A 35.4-km (22-mile) pipeline is being constructed to carry the brines from their primary source to the Truscott Brine Lake site. The reservoir is designed to contain 100 years of brine emissions from three chloride emission areas in the Wichita River Basin. The solar ponds and power generating facilities would be located in the Bluff Creek Arm of Truscott Brine Lake. The Truscott Brine Lake study includes: survey of suitability of Truscott Lake site, review of solar pond technology, preconceptual design of solar salt pond power plant, and economic evaluation.

Not Available

1982-09-01T23:59:59.000Z

206

[CuCln](2-n) Ion-Pair Species in 1-Ethyl-3-Methylimidazolium Chloride Ionic Liquid-Water Mixtures: Ultraviolet-Visible, X-ray Absorbtion Fine Structure, and Density Functional Theory Characterization  

DOE Green Energy (OSTI)

We report details of the coordination environment about Cu(II) in a pure ionic liquid, 1- ethyl-3-methylimidazolium chloride ([EMIM]Cl) and in mixtures containing varying amounts of water from 0-100% of the [EMIM]Cl. There are many stages in the ion pairing of the divalent cation, Cu(II) including the contact ion pairing of Cu2+ with multiple Cl- to form various CuCln (2-n) polyanions. Thereis also the subsequent solvation and ion pairing of the polychlorometallate anion with the EMIM+ cation. Using a combination of x-ray absorption fine structure (XAFS), UV-Vis spectroscopy and electronic structure calculations (TDDFT) we are able to follow the detailed structural changes about Cu(II). Ion pair formation is strongly promoted in [EMIM]Cl by the low dielectric constant and by the extensive breakdown of the water hydrogen bond network in [EMIM]Cl/water mixtures. In the [EMIM]Cl solvent the CuCl4 2- species dominates and it’s geometry is quite similar to gas-phase structure. These results are important in understanding catalysis and separation processes involving transition metals in ionic liquid systems.

Li, Guosheng; Camaioni, Donald M.; Amonette, James E.; Zhang, Z. Conrad; Johnson, Timothy J.; Fulton, John L.

2010-10-07T23:59:59.000Z

207

Passivation-free solid state battery  

DOE Patents (OSTI)

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li{sub 4}Ti{sub 5}O{sub 12} anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2} and LiV{sub 2}O{sub 5} and their derivatives. 5 figs.

Abraham, K.M.; Peramunage, D.

1998-06-16T23:59:59.000Z

208

Passivation-free solid state battery  

DOE Patents (OSTI)

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

Abraham, Kuzhikalail M. (Needham, MA); Peramunage, Dharmasena (Norwood, MA)

1998-01-01T23:59:59.000Z

209

Chloride Depletion in Aged Sea Salt Particles  

NLE Websites -- All DOE Office Websites (Extended Search)

of how they formed, they transform as they are transported by the wind, showing signs of age by increasing in size, chemical complexity, and oxidation, as well as becoming more...

210

Fluid Bed Dehydration of Magnesium Chloride  

Science Conference Proceedings (OSTI)

... is provided based on open literature sources, including papers and patents. ... Demonstration of Solar-Pumped Laser-Induced Magnesium Production from ...

211

Martian Methyl Chloride. A lesson in uncertainty  

E-Print Network (OSTI)

The MSL Lander Curiosity has recently detected methyl halides coming from heated samples of Martian soil. This is reminiscent of similar findings in the Viking Lander spacecraft. In the 1970s a consensus developed quickly explaining the methyl halides as contamination originating from the spacecraft, and ignoring lines of evidence that the two compounds originated from Mars, and that they could not have originated from the proposed spacecraft chemistry. I discuss why this consensus developed from the understanding of biochemistry and geochemistry of 1976, despite its implausibility. Subsequent explanations for the Viking methyl halides are more plausible but still not proven. The Curiosity rover results are also being explained as a result of on-spacecraft chemistry. I urge caution in this interpretation, in light of the historical Viking example: it is better to leave unexplained data unexplained than to lock in an explanation that precludes future developments.

Bains, William

2013-01-01T23:59:59.000Z

212

Electrochemical Impedance Spectroscopy of Uranium Chloride in ...  

Science Conference Proceedings (OSTI)

Author(s), Kerry Neil Allahar, Michael Shaltry, Mark E Orazem, Darryl P Butt, Supathorn Phongikaroon, Michael Simpson. On-Site Speaker (Planned), Kerry Neil ...

213

Solid polymer electrolyte lithium batteries  

DOE Patents (OSTI)

This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

1993-01-01T23:59:59.000Z

214

Solid polymer electrolyte lithium batteries  

DOE Patents (OSTI)

This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

Alamgir, M.; Abraham, K.M.

1993-10-12T23:59:59.000Z

215

Replication of N[superscript 2],3-Ethenoguanine by DNA Polymerases  

SciTech Connect

The unstable DNA adduct N2,3-ethenoguanine, a product of both exposure to the carcinogen vinyl chloride and of oxidative stress, was built into an oligonucleotide, using an isostere strategy to stabilize the glycosidic bond. This modification was then used to examine the cause of mutations by DNA polymerases, in terms of both the biochemistry of the lesion and a structure of the lesion within a polymerase.

Zhao, Linlin; Christov, Plamen P.; Kozekov, Ivan D.; Pence, Matthew G.; Pallan, Pradeep S.; Rizzo, Carmelo J.; Egli, Martin; Guengerich, F. Peter (Vanderbilt)

2012-06-27T23:59:59.000Z

216

Microbial based chlorinated ethene destruction  

DOE Patents (OSTI)

A mixed culture of Dehalococcoides species is provided that has an ability to catalyze the complete dechlorination of polychlorinated ethenes such as PCE, TCE, cDCE, 1,1-DCE and vinyl chloride as well as halogenated ethanes such as 1,2-DCA and EDB. The mixed culture demonstrates the ability to achieve dechlorination even in the presence of high source concentrations of chlorinated ethenes.

Bagwell, Christopher E. (Aiken, SC); Freedman, David L. (Clemson, SC); Brigmon, Robin L. (North Augusta, SC); Bratt, William B. (Atlanta, GA); Wood, Elizabeth A. (Marietta, GA)

2009-11-10T23:59:59.000Z

217

A Thermodynamic Model for Predicting Mineral Reactivity in Supercritical Carbon Dioxide: I. Phase Behavior of Carbon Dioxide - Water - Chloride Salt Systems Across the H2O-Rich to the CO2-Rich Regions  

Science Conference Proceedings (OSTI)

Phase equilibria in mixtures containing carbon dioxide, water, and chloride salts have been investigated using a combination of solubility measurements and thermodynamic modeling. The solubility of water in the CO2-rich phase of ternary mixtures of CO2, H2O and NaCl or CaCl2 was determined, using near infrared spectroscopy, at 90 atm and 40 to 100 °C. These measurements fill a gap in the experimental database for CO2 water salt systems, for which phase composition data have been available only for the H2O-rich phases. A thermodynamic model for CO2 water salt systems has been constructed on the basis of the previously developed Mixed-Solvent Electrolyte (MSE) framework, which is capable of modeling aqueous solutions over broad ranges of temperature and pressure, is valid to high electrolyte concentrations, treats mixed-phase systems (with both scCO2 and water present) and can predict the thermodynamic properties of dry and partially water-saturated supercritical CO2 over broad ranges of temperature and pressure. Within the MSE framework the standard-state properties are calculated from the Helgeson-Kirkham-Flowers equation of state whereas the excess Gibbs energy includes a long-range electrostatic interaction term expressed by a Pitzer-Debye-Hückel equation, a virial coefficient-type term for interactions between ions and a short-range term for interactions involving neutral molecules. The parameters of the MSE model have been evaluated using literature data for both the H2O-rich and CO2-rich phases in the CO2 - H2O binary and for the H2O-rich phase in the CO2 - H2O - NaCl / KCl / CaCl2 / MgCl2 ternary and multicompontent systems. The model accurately represents the properties of these systems at temperatures from 0°C to 300 °C and pressures up to ~4000 atm. Further, the solubilities of H2O in CO2-rich phases that are predicted by the model are in agreement with the new measurements for the CO2 - H2O - NaCl and CO2 - H2O - CaCl2 systems. Thus, the model can be used to predict the effect of various salts on the water content and water activity in CO2-rich phases on the basis of parameters determined from the properties of aqueous systems. Given the importance of water activity in CO2-rich phases for mineral reactivity, the model can be used as a foundation for predicting mineral transformations across the entire CO2/H2O composition range from aqueous solution to anhydrous scCO2. An example application using the model is presented which involves the transformation of forsterite to nesquehonite as a function of temperature and water content in the CO2-rich phase.

Springer, Ronald D.; Wang, Zheming; Anderko, Andre; Wang, Peiming; Felmy, Andrew R.

2012-09-05T23:59:59.000Z

218

Method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, E.D. Jr.

1995-07-11T23:59:59.000Z

219

Method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

220

Dispersant optimization using design of experiments for SiC/vinyl ester nanocomposites  

E-Print Network (OSTI)

×, respectively. Strain 0.5 wt. % SiC with MPS and W966 #1 (didn't break) 0.5 wt. % SiC with MPS and W966 #2 neat #1 (bend test Strain 1 vol. % SiC with 1-octanol and decane

Yong, V; Hahn, H T

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network (OSTI)

R.A. Sutula, F. McLamon, Battery Rsearch Pograms of theof Energy, in Selected Battery Topics. Proceedings of theEthylene Carbonate in Li-Ion Battery Electrolyte Guoying

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

222

Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton dissociation of vinyl  

E-Print Network (OSTI)

Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton the rovibra- tional energy distributions of fragmentsl formed in the infrared multiphoton dissociation (IRMPD energies of the frag- ment can be well characterized in terms of a Boltzmann distribution with a single

Zare, Richard N.

223

Monodisperse SiC/vinyl ester nanocomposites: Dispersant formulation, synthesis, and characterization  

E-Print Network (OSTI)

and S.F. Zhandarov: Carbon fibers and composites with epoxyepoxy resin com- posites, 22 carbon fiber filled epoxy resin

Yong, Virginia; Hahn, H. Thomas

2011-01-01T23:59:59.000Z

224

Poly(vinyl alcohol) (PVA)/sulfonated polyhedral oligosilsesquioxane (sPOSS) hybrid membranes  

E-Print Network (OSTI)

(HY-2006-I). REFERENCES 1. Surampudi S, Narayanan SR, Vamos E, Frank H, Halpert G, LaConti A, Kosek J

Mather, Patrick T.

225

NMED COMMENTS ITEM 3 REVISE VOLATILE ORGANIC COMPOUND (VOC) TARGET...  

NLE Websites -- All DOE Office Websites (Extended Search)

* Hydrogen and Methane Data Validation Checklist (WP 12-VC3209) * EDD Review and Data Package Validation Table (WP 12-VC3209) * VacuumPressure Comparison between Field and...

226

Life-Cycle Water Impacts of U.S. Transportation Fuels  

E-Print Network (OSTI)

U.S. Geological Survey Vapor Compression Withdrawals Westernelectrodialysis (ED) (5%), vapor compression (VC) (5%), and

Scown, Corinne Donahue

2010-01-01T23:59:59.000Z

227

CHLORIDE, IN CALCIUM, IN pH ARSENIC, IN  

E-Print Network (OSTI)

LITER PHAST--A Program for Simulating Ground-Water Flow, Solute Transport, and Multicomponent;COVER ILLUSTRATION: Results of PHAST simulation of the evolution of water chemistry in the CentralH ARSENIC, IN MILLIGRAMS PER LITER MILLIGRAMS PER LITER MICROGRAMS PER LITER #12;PHAST--A Program

228

Modeling of the influence of transverse cracking on chloride ...  

Science Conference Proceedings (OSTI)

... effective diffusion coefficients of concrete bridge decks in Utah [20], likely due to their higher moisture content. 2.3. COMSOL modeling approach ...

2013-08-09T23:59:59.000Z

229

Modeling acid-gas generation from boiling chloride brines  

E-Print Network (OSTI)

of the unsaturated zone at Yucca Mountain, Nevada. J. ofwaste emplacement tunnels at Yucca Mountain, Nevada. J. ofScale Heater Test at Yucca Mountain. International Journal

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

230

Extraction of Titanium and Vanadium by Chloride Leach Processes  

Science Conference Proceedings (OSTI)

... extraction of vanadium from different sources such as ilmenite and oil shales. ... of Ammonium Heptamolybdate Tetrahydrate in Air and Inert Gas Atmospheres.

231

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network (OSTI)

ix Introduction. A. Coal Liquefaction Overview B.L ZnCl 2-catalyzed Coal Liquefaction . . . . . . . . . • ,Results. . . • . ZnC1 2/MeOH Coal liquefaction Process

Joyce, Peter James

2011-01-01T23:59:59.000Z

232

Chloride Ion Diffusion in Cement-Based Materials ...  

Science Conference Proceedings (OSTI)

... into Hardened Cement Paste , Fly Ash, Silica Fume ... Diffusion Cell: Effects of Material and Test ... LJ, and Yu, SW, Diffusion in Cementitious Materials: II ...

2012-02-23T23:59:59.000Z

233

A COMPREHENSIVE SURVEY OF HYDROGEN CHLORIDE IN THE GALAXY  

SciTech Connect

We report new observations of the fundamental J = 1-0 transition of HCl (at 625.918 GHz) toward a sample of 27 galactic star-forming regions, molecular clouds, and evolved stars, carried out using the Caltech Submillimeter Observatory. Fourteen sources in the sample are also observed in the corresponding H{sup 37}Cl J = 1-0 transition (at 624.978 GHz). We have obtained clear detections in all but four of the targets, often in emission. Absorptions against bright background continuum sources are also seen in nine cases, usually involving a delicate balance between emission and absorption features. From RADEX modeling, we derive gas densities and HCl column densities for sources with HCl emission. HCl is found in a wide range of environments, with gas densities ranging from 10{sup 5} to 10{sup 7} cm{sup -3}. The HCl abundance relative to H{sub 2} is in the range of (3-30) x 10{sup -10}. Comparing with the chlorine abundance in the solar neighborhood, this corresponds to a chlorine depletion factor of up to {approx}400, assuming that HCl accounts for one-third of the total chlorine in the gas phase. The [{sup 35}Cl]/[{sup 37}Cl] isotopic ratio is rather varied, from unity to {approx}5, mostly lower than the terrestrial value of 3.1. Such variation is highly localized, and could be generated by the nucleosynthesis in supernovae, which predicts a {sup 37}Cl deficiency in most models. The lower ratios seen in W3IRS4 and W3IRS5 likely confine the progenitors of the supernovae to stars with relatively large mass ({approx}>25 M{sub sun}) and high metallicity (Z {approx} 0.02).

Peng Ruisheng; Yoshida, Hiroshige; Chamberlin, Richard A. [Caltech Submillimeter Observatory, 111 Nowelo Street, Hilo, HI 96720 (United States); Phillips, Thomas G.; Lis, Dariusz C. [Division of Physics, Mathematics, and Astronomy, 320-47, California Institute of Technology, Pasadena, CA 91125 (United States); Gerin, Maryvonne, E-mail: peng@submm.caltech.ed, E-mail: hiro@submm.caltech.ed, E-mail: cham@astro.caltech.ed, E-mail: tgp@submm.caltech.ed, E-mail: dcl@submm.caltech.ed, E-mail: gerin@lra.ens.f [LERMA-LRA, CNRS, Observatoire de Paris and Ecole Normale Sup'erieure, 24 Rue Lhomond, F 75231 Paris Cedex 05 (France)

2010-11-01T23:59:59.000Z

234

Dual role of nickel in sodium/nickel chloride batteries  

DOE Green Energy (OSTI)

Corrosion of Ni metal in chloroaluminate melts containing sulfur additive was investigated in order to see whether Ni could be used not only as active material but also as current collector and cell- case material. Three layers were found after three days; they comprised NiCl{sub 2}, Ni sulfide, and NaAlCl{sub 4}. Ni-200 wires were also tested under tension in NaAlCl{sub 4} + 2 wt%S at 300 C; no stress corrosion was observed. Results show that Ni metal is very stable. 9 refs, 3 figs. (DLC)

Prakash, J.; Redey, L.; Skocypec, R.; Lowrey, R.; Vissers, D.

1992-01-01T23:59:59.000Z

235

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network (OSTI)

farth- est along is the Exxon Donor Solvent process, whichCoal, I and II Process Exxon Donor Solvent B. ZnC1 2-mentioned above~ the Exxon development has included the use

Joyce, Peter James

2011-01-01T23:59:59.000Z

236

A Novel Low-Cost Sodium-Zinc Chloride Battery  

Science Conference Proceedings (OSTI)

The sodium-metal halide (ZEBRA) battery has been considered as one of the most attractive energy storage systems for stationary and transportation applications. Even though Na-NiCl2 battery has been widely investigated, there is still a need to develop a more economical system to make this technology more attractive for commercialization. In the present work, a novel low-cost Na-ZnCl2 battery with a thin planar ??-Al2O3 solid electrolyte (BASE) was proposed, and its electrochemical reactions and battery performance were investigated. Compared to the Na-NiCl2 chemistry, the ZnCl2-based chemistry was more complicated, in which multiple electrochemical reactions including liquid-phase formation occurred at temperatures above 253°C. During the first stage of charge, NaCl reacted with Zn to form Na in the anode and Na2ZnCl4 in the cathode. Once all the residual NaCl was consumed, further charging led to the formation of a NaCl-ZnCl2 liquid phase. At the end of charge, the liquid phase reacted with Zn to produce solid ZnCl2. To identify the effects of liquid-phase formation on electrochemical performance, button cells were assembled and tested at 280°C and 240°C. At 280°C where the liquid phase formed during cycling, cells revealed quite stable cyclability. On the other hand, more rapid increase in polarization was observed at 240°C where only solid-state electrochemical reactions occurred. SEM analysis indicated that the stable performance at 280°C was due to the suppressed growth of Zn and NaCl particles, which were generated from the liquid phase during discharge of each cycle.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2013-02-28T23:59:59.000Z

237

Modeling acid-gas generation from boiling chloride brines  

E-Print Network (OSTI)

first drop" of condensate from superheated geothermal steam.from the steam flowing above the condensate. Incompletecondensate that forms at dew-point temperature through expansion of superheated geothermal steam,

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

238

Method for Making a Uranium Chloride Salt Product  

DOE Patents (OSTI)

The subject apparatus provides a means to produce UCl3, in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl2 is formed. Due to is lower density, the CdCl2 rises through the Cd layer into a layer of molten LiCl-KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl2 reacts with the uranium to form UCl, and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl3 combines with the molten salt. During production the temperature is maintained at about 600 degrees C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl-KCl-30 mol% UCl3 is solidified.

Miller, William F.; Tomczuk, Zygmunt

2004-10-05T23:59:59.000Z

239

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network (OSTI)

II. c. High Yield Batch Reactor Results. . . • .Objectives •. Slurry Reactors . . . . . . .A. StudiesSystems. D. Slurry Reactor Theory. General. . Application to

Joyce, Peter James

2011-01-01T23:59:59.000Z

240

The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer  

E-Print Network (OSTI)

No.W-7405-eng~48B TIiE THERMODYNAMICS OF GASEOUS" CUPROUSCu(s) + HCl::= I Thermodynamics of Vaporization to Monomeric

Brewer, Leo

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Modeling acid-gas generation from boiling chloride brines  

E-Print Network (OSTI)

when steam flows through a condenser with incomplete or pooral. [6]). A water-cooled condenser was attached at the topin both the flask and condenser. Towards the end of the

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

242

Chloride Leaching of Spent Lead-Acid Battery Paste  

Science Conference Proceedings (OSTI)

Abstract Scope, In this study leaching of spent lead acid-battery paste in sodium ... Cost, Energy, Emissions, and Resource Assessment of the Production of ...

243

C1 Technology of Molten salt Electrolysis of Magnesium Chloride  

Science Conference Proceedings (OSTI)

D14 Gold Nanoparticles in Red Ruby Glasses Used for Decoration in Thailand · D15 Soft Magnetic Properties of Nanocrystalline Fe-based P/M Cores Mixed ...

244

Influence of Chloride Ions as Contaminants on the Corrosion ...  

Science Conference Proceedings (OSTI)

Crack Growth Rates of Irradiated Commercial Stainless Steels in BWR and PWR ... Detailed Root Cause Analysis of SG Tube ODSCC Indications within the Tube Sheets of NPP Biblis Unit A .... Radiation Damage in Fe-C-Met Model Alloys ... Stress Corrosion Cracking Behavior near the Fusion Boundary of Dissimilar Weld

245

Gold Preg-Robbing by Silicates in Chloride Media  

Science Conference Proceedings (OSTI)

Evolution of Gold Gravity Recovery in Grinding Circuits - A Critical Review ... Selective Separations of Gold and Contaminants from Various Gold and Silver ...

246

Uranium chloride extraction of transuranium elements from LWR ...  

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal ...

247

Modeling chloride transport in cracked concrete: a 3-D image ...  

Science Conference Proceedings (OSTI)

... and Technology, 100 Bureau Drive 8615, Gaithersburg ... package implements the UMFPACK direct solver ... on a rotating anode generator and capillary ...

2013-01-07T23:59:59.000Z

248

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network (OSTI)

of noble gases in molten salts, which also provide a modeln Hexane B2 275°C. Hydrogen-Molten Salt WI (dynes/em) WI PI

Joyce, Peter James

2011-01-01T23:59:59.000Z

249

Method for making a uranium chloride salt product  

DOE Patents (OSTI)

The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

2004-10-05T23:59:59.000Z

250

Electrochemical Studies and Analysis of Uranium Chloride in Molten ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The redox reactions of uranium on a tungsten electrode versus reference ... Cathodic Behavior of Silicon (?) in BaF2-CaF2 –SiO2 Melts.

251

An integrated model of the lithium/thionyl chloride battery  

DOE Green Energy (OSTI)

The desire to reduce the time and cost of design engineering on new components or to validate existing designs in new applications is stimulating the development of modeling and simulation tools. The authors are applying a model-based design approach to low and moderate rate versions of the Li/SOCl{sub 2} D-size cell with success. Three types of models are being constructed and integrated to achieve maximum capability and flexibility in the final simulation tool. A phenomenology based electrochemical model links performance and the cell design, chemical processes, and material properties. An artificial neural network model improves computational efficiency and fills gaps in the simulation capability when fundamental cell parameters are too difficult to measure or the forms of the physical relationships are not understood. Finally, a PSpice-based model provides a simple way to test the cell under realistic electrical circuit conditions. Integration of these three parts allows a complete link to be made between fundamental battery design characteristics and the performance of the rest of the electrical subsystem.

Jungst, R.G.; Nagasubramanian, G.; Ingersoll, D.; O`Gorman, C.C.; Paez, T.L. [Sandia National Labs., Albuquerque, NM (United States); Jain, M.; Weidner, J.W. [Univ. of South Carolina, Columbia, SC (United States)

1998-06-08T23:59:59.000Z

252

Electrochemical and Thermal Properties of Rare-Earth Chlorides in ...  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom  ...

253

Spouted Bed Electrowinning of Zinc from Chloride Electrolytes  

Science Conference Proceedings (OSTI)

Aug 1, 2000 ... Current efficiencies, for the cell with the SBE, have been as high as 90% and DC energy consumption as Iow as 2.8 kWh/kg zinc deposited.

254

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Fourth quarter 1993 and 1993 summary  

Science Conference Proceedings (OSTI)

During fourth quarter 1993, 10 constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Carbon tetrachloride, chloroform, chloroethane (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. Elevated constituents were found in numerous Aquifer Zone 2B{sub 2} (Water Table) and Aquifer Zone 2B{sub 1}, (Barnwell/McBean) wells and in two Aquifer Unit 2A (Congaree) wells. The groundwater flow direction and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Butler, C.T.

1994-03-01T23:59:59.000Z

255

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network (OSTI)

Roman Symbols a i Vapor heat capacity/enthalpy coefficientkg ? C a ¯ i Liquid heat capacity/enthalpy coefficient forspecies i b i Vapor heat capacity/enthalpy coefficient for

Tu, TungSheng

2013-01-01T23:59:59.000Z

256

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network (OSTI)

well as two byproducts: carbon dioxide (CO 2 ) and water (Hoperation units. The carbon dioxide removal unit and thekmol/min enters the carbon dioxide removal system where the

Tu, TungSheng

2013-01-01T23:59:59.000Z

257

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network (OSTI)

Compressor, heat exchanger, heaters andtemperature of the heat exchanger, and the pressure drop inreactor (RCT ), a heat exchanger (HX), a separator (SEP ), a

Tu, TungSheng

2013-01-01T23:59:59.000Z

258

Effects of POSS fiber sizing on the mechanical and thermal properties of carbon/vinyl ester composites.  

E-Print Network (OSTI)

??The degradation of polymer composites in moist environments is a limiting factor in the advancement of composite technology. The key to mitigate this degradation is… (more)

Powell, Felicia M.

2009-01-01T23:59:59.000Z

259

Grafting onto wool. XX. Graft copolymerization of vinyl monomers by use of redox initiators. Comparison of monomer reactivities  

SciTech Connect

Methyl methacrylate (MMA) and ethylacrylate (EA) have been graft copolymerized onto Himachali wool in aqueous medium by using a ferrous ammonium sulfate-hydrogen peroxide (FAS-H/sub 2/O/sub 2/) system as redox initiator. Percentage of grafting has been determined as functions of concentration of monomer, molar ratio of (FAS)/(H/sub 2/O/sub 2/), time, and temperature. Percentage of grafting is found to depend upon the molar ratio of (FAS)/(H/sub 2/O/sub 2/). An attempt has been made to compare the reactivities of the acceptor monomer (MMA and EA) with that of the donor monomer (VAc) toward grafting onto wool.

Misra, B.N.; Singha, A.S.; Sharma, R.K.

1982-04-01T23:59:59.000Z

260

Mechanical behavior of nanostructured hybrids based on poly(vinyl alcohol)/bioactive glass reinforced with functionalized carbon nanotubes  

Science Conference Proceedings (OSTI)

This study reports the synthesis and characterization of novel tridimensional porous hybrids based on PVA combined with bioactive glass and reinforced by chemically functionalized carbon nanotubes (CNT) for potential use in bone tissue engineering. The ...

H. S. Mansur, M. M. Pereira, H. S. Costa, A. A. P. Mansur

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network (OSTI)

of a continuous catalytic distillation process. Journal ofof the azeotropic distillation column using a feed-forwardand the azeotropic distillation in Figure 2.1 are assumed to

Tu, TungSheng

2013-01-01T23:59:59.000Z

262

Mixed Waste Management Facility (MWMF) Groundwater Monitoring Report: Fourth quarter 1991 and 1991 summary  

SciTech Connect

During fourth quarter 1991, tritium, trichloroethylene, tetrachloroethylene, chloroethene (vinyl chloride), total radium, mercury, and lead exceeded the US Environmental Protection Agency primary drinking water standards (PDWS) in groundwater samples from monitoring wells at the Mixed Waste Management Facility (MWMF) and adjacent facilities. Tritium and trichloroethylene were the most widespread contaminants; 55 (49%) wells exhibited elevated tritium activities, and 24 (21%) wells exhibited elevated trichloroethylene concentrations. Tritium and trichloroethylene levels exceeding the PDWS also occurred in several wells in Aquifer Unit IIA (Congaree). Levels of manganese, total organic halogens, nickel, iron, 1,1-dichloroethane, aluminum, nonvolatile beta, and trichlorofluoromethane that exceeded Flag 2 criteria were found in one or more wells beneath the MWMF. Downgradient wells in the three hydrostratigraphic units at the MWMF contained elevated levels of tritium, trichloroethylene, tetrachloroethylene, total radium, chloroethene (vinyl chloride), lead, mercury, manganese, total organic halogens, nickel, iron, 1,1-dichloroethane, aluminum, nonvolatile beta, or trichlorofluoromethane. Groundwater samples from 81 (72%) of the monitoring wells at the MWMF and adjacent facilities contained elevated levels of several contaminants.

Thompson, C.Y.

1992-03-01T23:59:59.000Z

263

Geothermal: Sponsored by OSTI -- Selected data fron continental...  

Office of Scientific and Technical Information (OSTI)

Selected data fron continental scientific drilling core holes VC-1 and VC-2a, Valles Caldera, New Mexico Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us...

264

Solar powered desalination system  

E-Print Network (OSTI)

MSF plant MGD Vapor compression (VC): takes advantage ofwater comes from the compression of vapor rather than the

Mateo, Tiffany Alisa

2011-01-01T23:59:59.000Z

265

What Motivates People to Purchase Digital Items on Virtual Community Websites? The Desire for Online Self-Presentation  

Science Conference Proceedings (OSTI)

The sale of digital items, such as avatars and decorative objects, is becoming an important source of revenue for virtual community (VC) websites. However, some websites are unable to leverage this source of revenue, and there is a corresponding lack ... Keywords: VC involvement, VC norms, desire for online self-presentation, digital item purchase, online presentation self-efficacy, virtual community

Hee-Woong Kim; Hock Chuan Chan; Atreyi Kankanhalli

2012-12-01T23:59:59.000Z

266

Acidic Ion Exchange Membrane - Energy Innovation Portal  

Technology Marketing Summary In this invention we report the synthesis of a copolymer of vinyl phosphonic acid (VPA) and vinyl zirconium phosphorous (VZP) acid has ...

267

Program or Field Office: Office of Legacy Management Project Title and I.D. No.: Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida, Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida, LM 13-13 Location: Largo, Florida Proposed Action or Project Description: DOE proposes to use a Geoprobe to inject emulsified edible soybean oil (EEO) and anaerobic microbial solution into the surficial aquifer at the 4.5 Acre Site adjacent to the DOE Young - Rainey STAR Center (Pinellas Site) in Largo, Florida. The proposed action would enhance naturally occurring anaerobic biodegradation, thereby reducing vinyl chloride contamination along the southwest boundary of the 4.5 Acre Site. Dehalococcoides ethenogenes (DHE) is a type of microbe that occurs naturally in the aquifer. Bioaugmentation with a commercially available DHE culture used in conjunction with the EEO would maximize the efficiency of contaminant biodegradation. No genetically engineered or

268

The Risk Assessment Information System  

NLE Websites -- All DOE Office Websites (Extended Search)

2-DICHLOROETHANE 2-DICHLOROETHANE NOTE: Although the toxicity values presented in these toxicity profiles were correct at the time they were produced, these values are subject to change. Users should always refer to the Toxicity Value Database for the current toxicity values. May 1994 Prepared by Dennis M. Opresko, Ph.D., Chemical Hazard Evaluation and Communication Program, Biomedical and Environmental Information Analysis Section, Health Sciences Research Division, *, Oak Ridge, Tennessee. Prepared for OAK RIDGE RESERVATION ENVIRONMENTAL RESTORATION PROGRAM. *Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy under contract No. DE-AC05-84OR21400. 1,2-Dichloroethane is used primarily in the manufacture of vinyl chloride, as well as in the synthesis of tetrachloroethylene, trichloroethylene,

269

Waste management health risk assessment: A case study of a solid waste landfill in South Italy  

Science Conference Proceedings (OSTI)

An integrated risk assessment study has been performed in an area within 5 km from a landfill that accepts non hazardous waste. The risk assessment was based on measured emissions and maximum chronic population exposure, for both children and adults, to contaminated air, some foods and soil. The toxic effects assessed were limited to the main known carcinogenic compounds emitted from landfills coming both from landfill gas torch combustion (e.g., dioxins, furans and polycyclic aromatic hydrocarbons, PAHs) and from diffusive emissions (vinyl chloride monomer, VCM). Risk assessment has been performed both for carcinogenic and non-carcinogenic effects. Results indicate that cancer and non-cancer effects risk (hazard index, HI) are largely below the values accepted from the main international agencies (e.g., WHO, US EPA) and national legislation ( and ).

Davoli, E., E-mail: enrico.davoli@marionegri.i [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy); Fattore, E.; Paiano, V.; Colombo, A.; Palmiotto, M. [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy); Rossi, A.N.; Il Grande, M. [Progress S.r.l., Via Nicola A. Porpora 147, 20131 Milano (Italy); Fanelli, R. [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy)

2010-08-15T23:59:59.000Z

270

Sanitary landfill groundwater monitoring report. Fourth quarter 1994 and 1994 summary  

Science Conference Proceedings (OSTI)

Eighty-nine wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Waste Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Dichloromethane, a common laboratory contaminant, and trichloroethylene were the most widespread constituents exceeding standards during 1994. Benzene, chloroethene (vinyl chloride), 1,2-dichloroethane, 1,1-dichloroethylene, 1,2-dichloropropane, gross alpha, mercury, nonvolatile beta, tetrachloroethylene, and tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill was to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 140 ft/year during first and fourth quarters 1994.

NONE

1995-02-01T23:59:59.000Z

271

Thai group set to invest in Chinese petchem complex  

SciTech Connect

A $5-billion refinery and petrochemical complex is planned by Thailand's Charoen Pokphand (Bangkok) at the seaport of Nimpoh, near Shanghai. The company has discussed the project with the central government of China, and state oil and petrochemicals company Sinopec (Beijing) is due to complete a feasibility study within the next two months. Charoen's plastics processing subsidiary, Kuo Shen (Hong Kong), is expected to hold 70% in the venture, Sinopec 20%, and the Chinese government the remaining 10%. Western companies have been invited to participate. Solvay (Brussels), a 49% partner with Charoen Pokphand in the Vinythai polyvinyl chloride (PVC) joint venture at Map Ta Pud, Thailand, has not yet made a commitment. The 5-million m.t./year oil refinery would feed the complex, which will be based on a 450,000-m.t./year ethylene plant, downstream aromatics units, and a range of derivatives plants. The complex, which falls outside the many announced for Thailand's current five-year economic plan, is expcted to be implemented in stages. To begin with, a 120,000-m.t./year PVC plant will be built that will be fed on imported vinyl chloride monomer. Charoen is in discussions with process licensers, including Solvay, European Vinyl Corp., BFGoodrich, and Shinetsu. Half the PVC output will be consumed by Kuo Shen in China, where Charoen has several plastics processing units, including one in Shanghai and one in Nimpoh. Meanwhile, Sinopec's Hong Kong subsidiary is seeking partners to invest in joint venture projects in China. Sinopec president Liu Xuemin says the company is willing to cooperate with overseas companies to establish small petrochemical projects. In addition, Sinopec is negotiating with officials of Dayang in Jiangsu province and the special economic zone of Shen Zhen, near Hong Kong, on joint ventures for plastics and food additives.

Alperowicz, N.

1993-01-06T23:59:59.000Z

272

Hysteresis mechanism and reduction method in the bottom-contact pentacene thin-film transistors with cross-linked poly,,vinyl alcohol...  

E-Print Network (OSTI)

. Korean Phys. Soc. 44, 181 2004 . 8 R. Schroeder, L. A. Majewski, and M. Grell, Appl. Phys. Lett. 83, 3201 Raoul Schroeder, Leszek A. Majewski, Monika Voigt, and Martin Grell, IEEE Electron Device Lett. 26, 69 2005 . 14 Tingkai Li, Sheng Teng Hsu, Bruce Ulrich, Hong Ying, Lisa Stecker, Dave Evans, Yoshi Ono, Jer

Lee, Jong Duk

273

Laser-induced implantation of silver particles into poly(vinyl alcohol) films and its application to electronic-circuit fabrication on encapsulated organic electronics  

Science Conference Proceedings (OSTI)

In this study, we propose a new laser-induced implantation based approach for embedding electronic interconnects in this study. Direct implantations of silver particles, vaporized by a pulsed laser from a silver film initially pre-coated on a transparent ... Keywords: Embedded electronic circuits, Encapsulation, Laser-induced implantation, Organic thin-film transistors, Polymeric light-emitting diodes

Kun-Tso Chen; Yu-Hsuan Lin; Jeng-Rong Ho; J.-W. John Cheng; Sung-Ho Liu; Jin-Long Liao; Jing-Yi Yan

2010-04-01T23:59:59.000Z

274

Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 10, January 1944--March 1994  

SciTech Connect

In work related to the design and construction of the Process Development Unit (PDU) this quarter involved further detail design and a real start to the construction activities. Status updates are given below for each discipline in the Task 2.0 and 3.0 headings. This work is progressing well. with the caveat of several small slips in the scheduling. On the catalyst development front this quarter was extremely productive. Many catalyst screening experiments were completed and they showed that control of the reaction exotherm is going to be quite challenging under PDU conditions. The presence of much more efficient reactor design and the ability to maintain closer to isothermal conditions is expected to give a significant advantage in actual PDU operation. A major concern at the moment is the cost of La in the catalyst being used. An action plan to remedy this is being put together.

NONE

1994-08-01T23:59:59.000Z

275

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

Rate Data o a o u a a Catalyst Loading • . Reaction Time . •and Pressure Effect of CO-catalysts and Additives .Co-catalysts • • a. Zinc Metal • b. Nickel and Nickel

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

276

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network (OSTI)

Battery Systems Purpose and Scope of this Study .. Literature Review . 13 Recent Historybattery (11) L5 r XBB II. LITERATURE REVIEW Recent History

Mc Vay, L.

2011-01-01T23:59:59.000Z

277

Densities in the Liquid Hydrogen Chloride Solvent System Heather Brooks Shapiro and Donald R. Sadoway*  

E-Print Network (OSTI)

for electrodeposition of several reactive metals and silicon from liquefied halogenous gases at subambient temperatures requires more cooling power than simple dry ice slush baths but much less than standard liquid nitrogen

Sadoway, Donald Robert

278

Calibration of Yucca Mountain unsaturated zone flow and transport model using porewater chloride data  

E-Print Network (OSTI)

of hydrogeologic units at Yucca Mountain, Nevada. U.S.infiltration for the Yucca Mountain Area, Nevada. Milestonethe unsaturated zone at Yucca Mountain, Nevada. J. Contam.

Liu, Jianchun; Sonnenthal, Eric L.; Bodvarsson, Gudmundur S.

2002-01-01T23:59:59.000Z

279

Analysis of chlorinated polyvinyl chloride pipe burst problems :Vasquez residence system inspection.  

DOE Green Energy (OSTI)

This report documents the investigation regarding the failure of CPVC piping that was used to connect a solar hot water system to standard plumbing in a home. Details of the failure are described along with numerous pictures and diagrams. A potential failure mechanism is described and recommendations are outlined to prevent such a failure.

Black, Billy D.; Menicucci, David F.; Harrison, John (Florida Solar Energy Center)

2005-10-01T23:59:59.000Z

280

Regenerable Sorbent Development for Sulfur, Chloride and Ammonia Removal from Coal-Derived Synthesis Gas  

DOE Green Energy (OSTI)

A large number of components in coal form corrosive and toxic compounds during coal gasification processes. DOE’s NETL aims to reduce contaminants to parts per billion in order to utilize gasification gas streams in fuel cell applications. Even more stringent requirements are expected if the fuel is to be utilized in chemical production applications. Regenerable hydrogen sulfide removal sorbents have been developed at NETL. These sorbents can remove the hydrogen sulfide to ppb range at 316 °C and at 20 atmospheres. The sorbent can be regenerated with oxygen. Reactivity and physical durability of the sorbent did not change during the multi-cycle tests. The sorbent development work has been extended to include the removal of other major impurities, such as HCl and NH3. The sorbents for HCl removal that are available today are not regenerable. Regenerable HCl removal sorbents have been developed at NETL. These sorbents can remove HCl to ppb range at 300 °C to 500 °C. The sorbent can be regenerated with oxygen. Results of TGA and bench-scale flow reactor tests with both regenerable and non-regenerable HCl removal sorbents will be discussed in the paper. Bench-scale reactor tests were also conducted with NH3 removal sorbents. The results indicated that the sorbents have a high removal capacity and good regenerability during the multi-cycle tests. Future emphasis of the NETL coal gasification/cleanup program is to develop multi-functional sorbents to remove multiple impurities in order to minimize the steps involved in the cleanup systems. To accomplish this goal, a regenerable sorbent capable of removing both HCl and H2S was developed. The results of the TGA conducted with the sorbent to evaluate the feasibility of both H2S and HCl sorption will be discussed in this paper.

Siriwardane, R.V.; Tian, H.; Simonyi, T.; Webster, T.

2007-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Comparative Neurotoxicity of Methylmercury and Mercuric Chloride In Vivo and In Vitro  

E-Print Network (OSTI)

It is impossible to remove methylmercury (MeHg) from biological systems because MeHg is found throughout our environment in many fresh and salt water fish. The consumption of fish is important to human nutrition and health. The mechanism of MeHg neurotoxicity must be understood to minimize adverse exposure consequences. The dissertation objective was to: 1) compare mechanisms of MeHg neurotoxicity between animals exposed as adults and those exposed during gestation, and 2) develop an in vitro test model of in vivo MeHg exposure. Total mercury (Hg) levels in tissue / cells were determined by combustion / trapping / atomic absorption. Cell death was determined by Fluoro-Jade histochemical staining and activated caspase 3 immunohistochemistry for in vivo studies, and Trypan blue exclusion, lactate dehydrogenase activity, and cytotoxicity assays for in vitro studies. Mitochondrial membrane potential (MMP), intracellular calcium ion concentration ([Ca2+]i), and production of reactive oxygen species (ROS) were determined using fluorescence microscopy or microplate reader assays. Young adult C57Bl/6 mice were exposed to a total dose of 0, 1.0, or 5.0 mg/kg body weight MeHg divided over postnatal days (P)35 to 39. Pregnant female mice were exposed to a total does of 0, 0.1, or 1.0 mg/kg body weight MeHg divided over gestational days (G)8 to 18. SY5Y cells were exposed to 0, 0.01, 0.1, or 1.0 ?M MeHg or HgCl2 for 24, 48, or 72 hours. Total Hg in brains of young adult mice, mouse pups, and SY5Y cells accumulated in a dose-dependent manner. Cell death increased in SY5Y cells exposed to the highest concentrations of MeHg and HgCl2 used in this study. Cell death increased in the molecular and granule cerebellar cell layers of young adult mice exposed to the highest doses of MeHg used in this study. P0 mouse pups showed no increase in cell death within the cerebellum following MeHg exposure. Cerebella of mice at P10 exhibited decreased dying cells only in the external germinal layer. Low concentrations of MeHg affected MMP in both in vivo and in vitro studies, but did not result in decreased MMP typically associated with higher MeHg concentrations. [Ca2+]i was increased throughout the in vivo experiments in an age- , sexand brain region-dependent manner. Generation of ROS was decreased in both in vivo and in vitro studies with both the MeHg and HgCl2 (in vitro) treatments. In summary, low and moderate MeHg exposure, both in vivo and in vitro, altered mitochondrial function, Ca2+ homeostasis, and ROS differently than what is reported in the literature for higher MeHg exposure concentrations. SY5Y cells were sensitive to low-levels of MeHg and HgCl2 and responded similarly to cells in the whole animal studies, thus making SY5Y cells realistic candidates for mechanistic MeHg studies. Cell culture and whole animal neuronal functional studies at chronic low-level MeHg exposure are limited. These data suggest that low-levels of MeHg may affect neuronal function. Therefore, further chronic low-level MeHg neuronal functional studies are warranted.

Thuett, Kerry A.

2009-08-01T23:59:59.000Z

282

Interactions of chlorine plasmas with silicon chloride-coated reactor walls during and after silicon etching  

SciTech Connect

The interplay between chlorine inductively coupled plasmas (ICP) and reactor walls coated with silicon etching products has been studied in situ by Auger electron spectroscopy and line-of-sight mass spectrometry using the spinning wall method. A bare silicon wafer mounted on a radio frequency powered electrode (-108 V dc self-bias) was etched in a 13.56 MHz, 400 W ICP. Etching products, along with some oxygen due to erosion of the discharge tube, deposit a Si-oxychloride layer on the plasma reactor walls, including the rotating substrate surface. Without Si-substrate bias, the layer that was previously deposited on the walls with Si-substrate bias reacts with Cl-atoms in the chlorine plasma, forming products that desorb, fragment in the plasma, stick on the spinning wall and sometimes react, and then desorb and are detected by the mass spectrometer. In addition to mass-to-charge (m/e) signals at 63, 98, 133, and 168, corresponding to SiCl{sub x} (x = 1 - 4), many Si-oxychloride fragments with m/e = 107, 177, 196, 212, 231, 247, 275, 291, 294, 307, 329, 345, 361, and 392 were also observed from what appear to be major products desorbing from the spinning wall. It is shown that the evolution of etching products is a complex 'recycling' process in which these species deposit and desorb from the walls many times, and repeatedly fragment in the plasma before being detected by the mass spectrometer. SiCl{sub 3} sticks on the walls and appears to desorb for at least milliseconds after exposure to the chlorine plasma. Notably absent are signals at m/e = 70 and 72, indicating little or no Langmuir-Hinshelwood recombination of Cl on this surface, in contrast to previous studies done in the absence of Si etching.

Khare, Rohit; Srivastava, Ashutosh; Donnelly, Vincent M. [Department of Chemical and Biomolecular Engineering, University of Houston, Houston, Texas 77204 (United States)

2012-09-15T23:59:59.000Z

283

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network (OSTI)

the rechargeable zinc/chlorine and zinc/bromine batteriesthis section. The zinc/chlorine and zinc/bromine batteriesare high: 2.32 V for the chlorine (12) and tions are 1.85 V

Mc Vay, L.

2011-01-01T23:59:59.000Z

284

A New Redox Flow Battery Using Fe/V Redox Couples in Chloride ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Energy Storage: Materials, Systems and Applications. Presentation Title, A ...

285

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

2-1 Figure Schematic of the Exxon Donor Solvent Process forL.W. , and Wilson, E.L. Exxon Donor Solvent Process 1 CEP 1commercialization are (1) the Exxon Donor Solvent process, (

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

286

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

1978) Richardson, F.W. Oil from Coal, Chemical TechnologyStatus of Coal and Oil Shale Conversion, University of Utah,of increasing the yield of oil like products. In contrast,

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

287

The Role of Boron-Chloride and Noble Gas Isotope Ratios in TVZ Geothermal Systems  

DOE Green Energy (OSTI)

The model of the geothermal system in which deep circulating groundwater containing noble gases, at air saturated water concentrations, mixes with hot fluids of mantle origin at depth, is extended to include the effect of interaction of the ascending fluid with both solid and gaseous phases of basement (or other) rocks en route to the surface. It is demonstrated that this interaction is responsible for most of the CO{sub 2} in the Taupo Volcanic Zone (TVZ) geothermal systems. It is proposed that the modeling of this interaction might be accomplished by techniques similar to those used for the understanding of the oxygen isotope shift found in geothermal systems. The water rock interaction experiments of Ellis and Mahon (1964, 1967) provides some data on the kinetic rates for B and Cl dissolution from rocks likely to be encountered in the geothermal system, but further information on the behavior of B may be needed. If these problems can be overcome this modeling technique has promise for the estimation of the recharge of geothermal systems and hence the sustainability of these systems.

Hulston, J.R.

1995-01-01T23:59:59.000Z

288

Palladium chloride to palladium metal two-dimensional nucleation and growth phenomena  

SciTech Connect

The reduction of a monolayer of surface-bound Pd(II) to Pd(0) on a palladium substrate reveals two-dimensional nucleation and growth phenomena. Using well-known 2D nucleation-growth theories, this reduction is shown to proceed by an instantaneous nucleation and growth mechanism. However, when a submonolayer of Pd(II) is present, this mechanism fails to account for the experimentally observed high cathodic currents seen at zero time. A model incorporating preexisting Pd(0) cylindrical sites on the partially oxidized Pd(0) surface has been successfully applied to account for the discrepancy between the experimental results and current 2D theories. Using this modified 2D model, values for the mathematical product of cylindrical growth rate and the square root of the nucleation site densities have been determined, and the overpotential dependence of the growth rate has been confirmed and quantified. These 2D nucleation-growth phenomena have practical consequences on the performance of the Pd(II)/Pd(0) system as a faradaic supercapacitor, and probably on the performance of other 2D faradaic supercapacitor systems. In addition, because many electrodes undergo monolayer surface oxidation-reduction reactions in other solvent systems, especially aqueous electrolytes, these 2D nucleation-growth phenomena may play a role in these important surface-modifying redox systems as well.

Long, H.C. de; Carlin, R.T. [Air Force Academy, CO (United States). Frank J. Seiler Research Lab.

1995-08-01T23:59:59.000Z

289

Ions on the Electrodeposition of Titanium in Molten Fluoride-chloride ...  

Science Conference Proceedings (OSTI)

Electrochemical Behavior of Calcium-Lead Alloys in Molten Salt Electrolytes ... on the Corrosion of Ni-Cased Alloys (NiCrW and NiCrMo) in Molten Fluorides.

290

CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE  

E-Print Network (OSTI)

blending and reaction conditions would be less than 10 centipoises, the effective viscosity of the melt/coal

Vermeulen, T.

2012-01-01T23:59:59.000Z

291

Pilot Evaluation of the Impact of Chloride on Selective Catalytic Reduction (SCR) Mercury Oxidation  

Science Conference Proceedings (OSTI)

This study investigated the effect of blending Powder River Basin (PRB) coal with an Eastern bituminous coal on the speciation of Hg across a selective catalytic reduction (SCR) catalyst. A pilot-scale coal combustor equipped with an SCR reactor for NOx control was used to evaluate the effect of coal blending on improving Hg oxidation across an SCR catalyst. Several parameters such as the ratio of PRB/bituminous coal blend and the concentrations of hydrogen halides (HCl, HBr, and HF) and halogens (Cl2 an...

2008-03-19T23:59:59.000Z

292

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Racemic Secondary Allylic Chlorides with Alkylzincs  

E-Print Network (OSTI)

The transition metal-catalyzed enantioselective coupling of allylic electrophiles with carbon nucleophiles has been the focus of intense investigation.5 Salient examples include palladium-catalyzed couplings with enolates, ...

Fu, Gregory C.

293

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network (OSTI)

for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

Holten, R.R.

2010-01-01T23:59:59.000Z

294

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

Conference on Coal Gasification, Lique- faction, andInternational Symposium on Gasification and Liquefaction,coal, go to a gasification facility for conversion to

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

295

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network (OSTI)

of char and gases. The Fischer-Tropsch process is an exampleprocess economics, the Fischer-Tropsch process has not beenevaluations for a Fischer-Tropsch plant in the United

Holten, R.R.

2010-01-01T23:59:59.000Z

296

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

volume of liquids. Fischer-Tropsch synthesis is an indirecthydrocarbons. The Fischer- Tropsch synthesis method produces

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

297

EVIDENCE OF CORROSIVE GAS FORMED BY RADIOLYSIS OF CHLORIDE SALTS IN PLUTONIUM-BEARING MATERIALS  

SciTech Connect

Corrosion and pitting have been observed in headspace regions of stainless steel containers enclosing plutonium oxide/salt mixtures. These observations are consistent with the formation of a corrosive gas, probably HCl, and transport of that gas to the headspace regions of sealed containers. The NH{sub 4}Cl films found on the walls of the sealed containers is also indicative of the presence of HCl gas. Radiolysis of hydrated alkaline earth salts is the probable source of HCl.

Dunn, K.; Louthan, M.

2010-02-01T23:59:59.000Z

298

Low Temperature (T<100°C) Regeneration of HCl from the Chloride ...  

Science Conference Proceedings (OSTI)

Characterization of Indonesia Rare Earth Minerals and their Potential Processing Techniques · Characterization of Rare Earth Minerals with Field Emission ...

299

The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride Environments  

E-Print Network (OSTI)

Oldani, LLNL Gary Devine, LLNL Janet Hauber, LLNL Bill Moddeman, PANTEX #12;ii Executive Summary The work

300

006- Does Addition of Fly Ash Decrease the Chloride Diffusivities of ...  

Science Conference Proceedings (OSTI)

085- Highly Efficient Comprehensive Utilization of Kaolin Tailings from ... 086- Improvement in Gas Tightness of YSZ Coatings Produced by Atmospheric Plasma Spraying ... 145- The Synergy of XRD and XRF in a Shale and Slate Analysis.

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Recovery of Lead and Silver from Zinc Plant Residue by Chloride ...  

Science Conference Proceedings (OSTI)

Selective Recovery of Gold from E-wastes by Using Cellulosic Wastes · Stabilization of Chromium-Based Slags with FeS2 and FeSO4 · Sulphide Precipitation ...

302

Stereoconvergent Amine-Directed Alkyl–Alkyl Suzuki Reactions of Unactivated Secondary Alkyl Chlorides  

E-Print Network (OSTI)

A new family of stereoconvergent cross-couplings of unactivated secondary alkyl electrophiles has been developed, specifically, arylamine-directed alkyl–alkyl Suzuki reactions. This represents the first such investigation ...

Lu, Zhe

303

Spinning Carbon Fiber Precursors from 1-Butyl-3-Methylimidazolium Chloride Cellulose Solutions.  

E-Print Network (OSTI)

??Cellulose is an abundant natural renewable polymer that is used in the production of many materials. However, limited processibility and reduced solubility have restricted its… (more)

Gelderloos-Sammons, Rhea J

2007-01-01T23:59:59.000Z

304

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network (OSTI)

Howlett & A .. Gamache, Silviculture Biomass Farms; Vol. IV,a Potential Source of Biomass, Georgia Pacific Corp. MitreR.E. Inman, Silviculture Biomass Farms; Vol. 1 Summary,

Onu, Christopher O.

2013-01-01T23:59:59.000Z

305

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network (OSTI)

July 22, 1974. Project Western Coal: Conversion of Coal Intoand Gasification of Western Coals", in proceedings of ERDA/Investigators' Conference - Coal Research, Colorado School

Holten, R.R.

2010-01-01T23:59:59.000Z

306

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network (OSTI)

iv List of Tables . , I. INTRODUCTION e o Coal Chemistry B.Coal Liquefaction c.Coal Liquefaction a D. II. o Experiment Equipment Summary of

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

307

Development of Mercury and Hydrogen Chloride Emission Monitors for Coal Gasifiers  

SciTech Connect

The gas conditioning issues involved with coal gasification streams are very complex and do not have simple solutions. This is particularly true in view of the fact that the gas conditioning system must deal with tars, high moisture contents, and problems with NH{sub 3} without affecting low ppb levels of Hg, low levels (low ppm or less) of HCl, or the successful operation of conditioner components and analytical systems. Those issues are far from trivial. Trying to develop a non-chemical system for gas conditioning was very ambitious in view of the difficult sampling environment and unique problems associated with coal gasification streams. Although a great deal was learned regarding calibration, sample transport, instrumentation options, gas stream conditioning, and CEM design options, some challenging issues still remain. Sample transport is one area that is often not adequately considered. Because of the gas stream composition and elevated temperatures involved, special attention will need to be given to the choice of materials for the sample line and other plumbing components. When using gas stream oxidation, there will be sample transport regions under oxidizing as well as reducing conditions, and each of those regions will require different materials of construction for sample transport. The catalytic oxidation approach worked well for removal of tars and NH{sub 3} on a short term basis, but durability issues related to using the catalyst tube during extended testing periods still require study.

G. Norton; D. Eckels; C. Chriswell

2001-02-26T23:59:59.000Z

308

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network (OSTI)

of biomass utilization and conversion facilities. ChemicalChemical Structures of Biomass Components Chemical Liquefaction of Wood and l'lood Components Biomass Conversion

Onu, Christopher O.

2013-01-01T23:59:59.000Z

309

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network (OSTI)

pores of coal. c~n pene- Molten salts, particularly SnC1 2 ,the selection of ZnC1 2 as the molten salt catalyst for coalis very necessary. Molten salts have demonstrated catalytic

Onu, Christopher O.

2013-01-01T23:59:59.000Z

310

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network (OSTI)

Liquefaction Chemistry B. Molten Salt Catalysis RationaleUsed Equipment and Procedure Molten Salt a. b. c. Treat~entEquipment and Procedure Molten Salt Treatment a. Equipment

Holten, R.R.

2010-01-01T23:59:59.000Z

311

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network (OSTI)

Bodily, Stanford Res Inst. , Coal Chemistry Workshop, 1,News, (Aug. 27, 1979). C2 Coal Processing-Gasification,L.W. Vernon, and E.L. Wilson, Coal Liquefaction by the Exxon

Onu, Christopher O.

2013-01-01T23:59:59.000Z

312

Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts  

E-Print Network (OSTI)

on an indirect route via synthesis gas (syngas), i.e., methane is first con- verted to syngas before it is further transformed into other useful products [6]. However, the production of syngas from methane) 130:286­290 DOI 10.1007/s10562-009-0017-9 #12;[12], which is produced from syngas feedstock with Cu

Bao, Xinhe

313

Thailand's downstream projects proliferate  

SciTech Connect

Thailand continues to press expansion and modernization of its downstream sector. Among recent developments: Construction of an olefins unit at Thailand's second major petrochemical complex and a worldscale aromatics unit in Thailand is threatened by rising costs. Thailand's National Petrochemical Corp (NPC) let a 9 billion yen contract to Mitsui Engineering and Shipbuilding Co. and C. Itoh and Co. for a dual fuel cogeneration power plant at its Mab Ta Phud, Rayong province, petrochemical complex. Financing is in place to flash a green light for a $530 million Belgian-Thai joint venture sponsoring a worldscale polyvinyl chloride/vinyl chloride monomer plant in Thailand. Work is more than 50% complete on the $345 million second phase expansion of Thai Oil's Sri Racha refinery in Chon Buri province. Petroleum Authority of Thailand (PTT) endorsed a plan to install two more natural gas processing plants in Thailand to meet rapidly growing domestic demand for petroleum gas.

1991-06-03T23:59:59.000Z

314

Development studies for a novel wet oxidation process  

SciTech Connect

A catalytic wet oxidation process (DETOX), which uses an acidic iron solution to oxidize organic compounds to carbon dioxide, water, and other simple products, was investigated as a potential method for the treatment of multicomponent hazardous and mixed wastes. The organic compounds picric acid, poly(vinyl chloride), tetrachlorothiophene, pentachloropyridine, Aroclor 1260 (a polychlorinated biphenyl), and hexachlorobenzene were oxidized in 125 ml reaction vessels. The metals arsenic, barium, beryllium, cadmium, cerium (as a surrogate for plutonium), chromium, lead, mercury, neodymium (as a surrogate for uranium), nickel, and vanadium were tested in the DETOX solution. Barium, beryllium, cerium, chromium, mercury, neodymium, nickel, and vanadium were all found to be very soluble (>100 g/l) in the DETOX chloride-based solution. Arsenic, barium, cadmium, and lead solubilities were lower. Lead could be selectively precipitated from the DETOX solution. Chromium(VI) was reduced to relatively non-toxic chromium(III) by the solution. Six soils were contaminated with arsenic, barium, beryllium, chromium, lead, and neodymium oxides at approximately 0.1% by weight, and benzene, trichloroethene, mineral oil, and Aroclor 1260 at approximately 5% by weight total, and 5.g amounts treated with the DETOX solution in unstirred 125. ml reaction bombs. It is felt that soil treatment in a properly designed system is entirely possible despite incomplete oxidation of the less volatile organic materials in these unstirred tests.

Dhooge, P.M.; Hakim, L.B.

1994-01-01T23:59:59.000Z

315

LS-69 DEVELOPING PULSE WIDTH MODULATED POWER SUPPLY FOR THE GeV...  

NLE Websites -- All DOE Office Websites (Extended Search)

A L magnet inductance, H L. load filter inductance, H Ll leakage inductance of transformer referred to the primary, H Lm commutation inductance, H Vc voltage of the...

316

Workbook Contents  

U.S. Energy Information Administration (EIA) Indexed Site

,"Release Date:","12122013" ,"Next Release Date:","172014" ,"Excel File Name:","ngconssumaepg0vc0mmcfm.xls" ,"Available from Web Page:","http:www.eia.govdnavng...

317

Workbook Contents  

U.S. Energy Information Administration (EIA) Indexed Site

,"Release Date:","12122013" ,"Next Release Date:","172014" ,"Excel File Name:","ngsumlsumaepg0vc0mmcfm.xls" ,"Available from Web Page:","http:www.eia.govdnavng...

318

Core Routing on Dynamic Time-Dependent Road Networks  

E-Print Network (OSTI)

contracted graph GC = (VC,AC) has been computed, it is merged with the ..... Unfortunately, we are not aware of a continental-sized publicly available real- world.

319

Sonne Wind Beteiligungen AG | Open Energy Information  

Open Energy Info (EERE)

search Name Sonne+Wind Beteiligungen AG Place Berlin, Germany Zip 10715 Sector Efficiency, Solar, Wind energy Product Berlin-based VC firm focusing on wind, solar and...

320

Statistics of interstate natural gas pipeline companies, 1990  

Science Conference Proceedings (OSTI)

This report presents financial and operating information of all major interstate natural gas pipeline companies that operated in the United States during 1990. (VC)

Not Available

1992-04-09T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Jan Obrzut  

Science Conference Proceedings (OSTI)

... 1989). Structural characterization of vinylidene fluoride vinyl fluoride copolymers, Guerra, G; Didino, G; Centore, R, et al. ...

2012-10-01T23:59:59.000Z

322

Slide 1  

NLE Websites -- All DOE Office Websites (Extended Search)

QWR 172.5 MHz vc0.28 HWR 345 MHz vc0.4 double-spoke The Technology beam beam 9 Beta v c 0 0.5 1.0 Surface Magnetic Field (kGauss) 0.5 1.0 Heavy-ion ...Proton Linacs...

323

Digital Filter Algorithm Based on Whistle Sound Suppression System Design  

Science Conference Proceedings (OSTI)

System uses the voice codec chip analog voice signals TLV320AIC23 A/D conversion, digital audio is passed to the DSP chip TMS320VC5409 sequence processing, DSP algorithms using FFT and CZT transform algorithm the number of sequences of audio spectrum ... Keywords: Acoustic feedback, FFT transform, CZT transform, IIR filter, TMS320VC5409

Lei Liu; Honggang Li; Xiaochen Hu

2012-08-01T23:59:59.000Z

324

Antithrombogenic and antibiotic composition and methods of preparation thereof  

SciTech Connect

Antithrombogenic and antibiotic composition of matter and method of preparation thereof. A random copolymer of a component of garlic and a biocompatible polymer has been prepared and found to exhibit antithrombogenic and antibiotic properties. Polymerization occurs selectively at the vinyl moiety in 2-vinyl-4H-1,3-dithiin when copolymerized with N-vinyl pyrrolidone.

Hermes, Robert E. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

325

Impact of Vehicular Communications Security on Transportation Safety  

E-Print Network (OSTI)

Transportation safety, one of the main driving forces of the development of vehicular communication (VC) systems, relies on high-rate safety messaging (beaconing). At the same time, there is consensus among authorities, industry, and academia on the need to secure VC systems. With specific proposals in the literature, a critical question must be answered: can secure VC systems be practical and satisfy the requirements of safety applications, in spite of the significant communication and processing overhead and other restrictions security and privacy-enhancing mechanisms impose? To answer this question, we investigate in this paper the following three dimensions for secure and privacy-enhancing VC schemes: the reliability of communication, the processing overhead at each node, and the impact on a safety application. The results indicate that with the appropriate system design, including sufficiently high processing power, applications enabled by secure VC can be in practice as effective as those enabled by uns...

Papadimitratos, Panos; Hubaux, Jean-Pierre; Lioy, Antonio

2008-01-01T23:59:59.000Z

326

Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems  

DOE Green Energy (OSTI)

The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

Not Available

1991-01-01T23:59:59.000Z

327

Atmospheric variability of methyl chloride during the last 300 years from an Antarctic ice core and firn air  

E-Print Network (OSTI)

as a low-pass filter, smoothing variations in the atmospheric composition of a gas over decadal time scales core measurements from Siple Dome provide evidence for a cyclic natural variability on the order of 10 increase measured in firn air may largely be a result of natural processes, which may continue to affect

Saltzman, Eric

328

Time-course analysis of the Shewanella amazonensis SB2B proteome in response to sodium chloride shock  

SciTech Connect

Organisms in the genus Shewanella have become models for response to environmental stress. One of the most important environmental stresses is change in osmolarity. In this study, we experimentally determine the response mechanisms of Shewanella amazonensis SB2B during osmotic stress. Osmotic stress in SB2B was induced through exposure to NaCl, and the time-course proteomics response was measured using liquid chromatography mass spectrometry. Protein trends were qualitatively compared to gene expression trends and to phenotypic characterization. Osmotic stress affects motility, and has also been associated with a change in the membrane fatty acid composition (due to induction of branched chain amino acid degradation pathways); however, we show this is not the case for SB2B. Although proteins and genes involved with branched chain amino acid degradation are induced, fatty acid degradation pathways are not induced and no change in the fatty acid profile occurs in SB2B as a result of osmotic shock. The most extensive response of SB2B over the time course of acclimation to high salt involves an orchestrated sequence of events comprising increased expression of signal transduction associated with motility and restricted cell division and DNA replication. After SB2B has switched to increased branched chain amino acid degradation, motility, and cellular replication proteins return to pre-perturbed levels.

Parnell, John J.; Callister, Stephen J.; Rompato, Giovanni; Nicora, Carrie D.; Pasa-Tolic, Ljiljana; Williamson, Ashley; Pfrender, Michael E.

2011-06-29T23:59:59.000Z

329

Experimental and theoretical investigation of the production of HCI and some metal chlorides in magmatic/hydrothermal systems  

DOE Green Energy (OSTI)

Progress in modifying a model in which the halogen (Cl and F) concentration in the mineral apatite in mid-crustal silicic plutonic systems can be used to make estimates of magmatic Cl and F concentrations at the time apatite was crystallizing is reviewed briefly. (MHR)

Piccoli, P.

1993-01-01T23:59:59.000Z

330

Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene  

DOE Patents (OSTI)

A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1982-03-31T23:59:59.000Z

331

Regulation of the sodium/potassium/chloride cotransporter by calcium and cyclic AMP in cultured vascular smooth muscle cells  

SciTech Connect

The activity of the Na/K/Cl cotransporter in smooth muscle cells cultured from rat aorta was assayed by measuring the initial rate of furosemide-inhibitable /sup 86/Rb influx or efflux. Five uM furosemide or 0.2 uM bumetanide inhibited influx by 50%. Furosemide-inhibitable /sup 86/Rb influx depended on the presence of all 3 ions in the external medium. The dependence on Na and K was hyperbolic with apparent Km values of 45 and 5 mM, respectively. The dependence on Cl was sigmoidal. Assuming a stoichiometry of 1:1:2 for Na:K:Cl, a Km for Cl of 60 mM was obtained from a Hofstee plot of the data. Rapidly growing cells had 3 fold higher cotransport activity than quiescent cells. Angiotensin II (ANG) stimulated furosemide-inhibitable /sup 86/Rb efflux by 2 fold. An ANG receptor antagonist prevented ANG from increasing cotransport activity. Two calcium ionophores, A23187 and ionomycin, increased cotransport activity by 2 fold. Phorbol myristate acetate had no effect on cotransport activity. Isoproterenol, dibutyryl cyclic AMP, cholera toxin, or methylisobutylxanthine inhibited furosemide-sensitive /sup 86/Rb influx by 35 to 50%. From these findings they conclude that increasing cytoplasmic free calcium stimulates cotransport activity, whereas increasing cellular cyclic AMP inhibits the cotransporter.

Higgins, B.L.; Smith, L.; Smith, J.B.

1987-05-01T23:59:59.000Z

332

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network (OSTI)

H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

Mobley, David Paul

2013-01-01T23:59:59.000Z

333

Impacts of Venturi Turbulent Mixing on the Size Distribution of Sodium Chloride and Dioctyl-Phthalate Aerosols  

DOE Green Energy (OSTI)

Internal combustion engines are a major source of airborne particulate matter (PM). The size of the engine PM is in the sub-micrometer range. The number of engine particles per unit volume is high, normally in the range of 10{sup 12} to 10{sup 14}. To measure the size distribution of the engine particles dilution of an aerosol sample is required. A diluter utilizing a venturi ejector mixing technique is commercially available and tested. The purpose of this investigation was to determine if turbulence created by the ejector in the mini-dilutor changes the size of particles passing through it.

Cheng, M.-D.; Wainman, T.; Storey, J.

2000-08-01T23:59:59.000Z

334

Impacts of Venturi Turbulent Mixing on the Size Distributions of Sodium Chloride and Dioctyl-Phthalate Aerosols  

DOE Green Energy (OSTI)

Internal combustion engines are a major source of airborne particulate matter (PM). The size of the engine PM is in the sub-micrometer range. The number of engine particles per unit volume is high, normally in the range of 10{sup 12} to 10{sup 14}. To measure the size distribution of the engine particles dilution of an aerosol sample is required. A diluter utilizing a venturi ejector mixing technique is commercially available and tested. The purpose of this investigation was to determine if turbulence created by the ejector in the mini-dilutor changes the size of particles passing through it. The results of the NaCl aerosol experiments show no discernible difference in the geometric mean diameter and geometric standard deviation of particles passing through the ejector. Similar results were found for the DOP particles. The ratio of the total number concentrations before and after the ejector indicates that a dilution ratio of approximately 20 applies equally for DOP and NaCl particles. This indicates the dilution capability of the ejector is not affected by the particle composition. The statistical analysis results of the first and second moments of a distribution indicate that the ejector may not change the major parameters (e.g., the geometric mean diameter and geometric standard deviation) characterizing the size distributions of NaCl and DOP particles. However, when the skewness was examined, it indicates that the ejector modifies the particle size distribution significantly. The ejector could change the skewness of the distribution in an unpredictable and inconsistent manner. Furthermore, when the variability of particle counts in individual size ranges as a result of the ejector is examined, one finds that the variability is greater for DOP particles in the size range of 40-150 nm than for NaCl particles in the size range of 30 to 350 nm. The numbers or particle counts in this size region are high enough that the Poisson counting errors are small (<10%) compared with the tail regions. This result shows that the ejector device could have a higher bin-to-bin counting uncertainty for ''soft'' particles such as DOP than for a solid dry particle like NaCl. The results suggest that it may be difficult to precisely characterize the size distribution of particles ejected from the mini-dilution system if the particle is not solid.

Cheng, M-D.

2000-08-23T23:59:59.000Z

335

European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3.115 NON-LINEAR MECHANICAL PROPERTIES OF ETHYLENE-VINYL ACETATE (EVA) AND ITS  

E-Print Network (OSTI)

that address the issue of reliability and long-term stability need adequate models that incorporate these non of EVA rises by 2 orders of magnitude. Keywords: Encapsulation, Mechanics, PV Module, Modeling, Polymer mechanical analyses (DMA) and relaxation/creep experiments. Mechanical investigations of PV modules

336

Use of Sequential Injection Analysis to construct a Potentiometric Electronic Tongue: Application to the Multidetermination of Heavy Metals  

SciTech Connect

An automated potentiometric electronic tongue (ET) was developed for the quantitative determination of heavy metal mixtures. The Sequential Injection Analysis (SIA) technique was used in order to automate the obtaining of input data, and the combined response was modeled by means of Artificial Neural Networks (ANN). The sensor array was formed by four sensors: two based on chalcogenide glasses Cd sensor and Cu sensor, and the rest on poly(vinyl chloride) membranes Pb sensor and Zn sensor. The Ion Selective Electrode (ISE) sensors were first characterized with respect to one and two analytes, by means of high-dimensionality calibrations, thanks to the use of the automated flow system; this characterization enabled an interference study of great practical utility. To take profit of the dynamic nature of the sensor's response, the kinetic profile of each sensor was compacted by Fast Fourier Transform (FFT) and the extracted coefficients were used as inputs for the ANN in the multidetermination applications. In order to identify the ANN which provided the best model of the electrode responses, some of the network parameters were optimized. Finally analyses were performed employing synthetic samples and water samples of the river Ebro; obtained results were compared with reference methods.

Mimendia, Aitor; Merkoci, Arben; Valle, Manel del [Sensors and Biosensors Group, Chemistry Dept., Universitat Autonoma de Barcelona, Edifici Cn, 08193 Bellaterra, Barcelona (Spain); Legin, Andrey [Chemistry Dept, St. Petersburg University, Universitetskaya nab. 7/9, 199034 St. Petersburg (Russian Federation)

2009-05-23T23:59:59.000Z

337

Production of high-energy chemicals using solar energy heat. Project 8999, final report for the period September 1, 1977--May 31, 1978  

DOE Green Energy (OSTI)

The first phase of a study to identify candidate processes and products suitable for future exploitation using high-temperature solar energy is presented. This phase has been principally analytical, consisting of techno-economic studies, thermodynamic assessments of chemical reactions and processes, and the determination of market potentials for major chemical commodities that use significant amounts of fossil resources today. The objective was to identify energy-intensive processes that would be suitable for the production of chemicals and fuels using solar energy process heat. Of particular importance was the comparison of relative costs and energy requirements for the selected solar product versus costs for the product derived from conventional processing. The assessment methodology used a systems analytical approach to identify processes and products having the greatest potential for solar energy-thermal processing. This approach was used to establish the basis for work to be carried out in subsequent phases of development. It has been the intent of the program to divide the analysis and process identification into the following three distinct areas: (1) process selection, (2) process evaluation, and (3) ranking of processes. Four conventional processes were selected for assessment namely, methanol synthesis, styrene monomer production, vinyl chloride monomer production, and terephthalic acid production.

Dafler, J.R.; Sinnott, J.; Novil, M.; Yudow, B.D.; Rackoff, M.G.

1978-12-01T23:59:59.000Z

338

Remedial evaluation of a UST site impacted with chlorinated hydrocarbons  

Science Conference Proceedings (OSTI)

During assessment and remedial planning of an underground storage tank (UST) site, it was discovered that chlorinated hydrocarbons were present. A network of selected wells were sampled for analysis of halogenated volatile organics and volatile organic compounds to determine the extent of constituents not traditionally associated with refined petroleum motor fuel products. The constituents detected included vinyl chloride, tetrachloroethylene (PCE), bromodichloromethane, and 2-chloroethylvinyl ether. These analytical data were evaluated as to what effect the nonpetroleum hydrocarbon constituents may have on the remedial approach utilized the site hydrogeologic properties to its advantage and took into consideration the residential nature of the impacted area. The geometry of the dissolved plume is very flat and broad, emanating from the site and extending downgradient under a residential area situated in a transmissive sand unit. Ground-water pumping was proposed from two areas of the dissolved plume including five wells pumping at a combined rate of 55 gallons per minute (gpm) at a downgradient position, and two wells on-site to remove free product and highly impacted ground water. Also, to assist in remediation of the dissolved plume and to control vapors, a bioventing system was proposed throughout the plume area.

Ilgner, B.; Rainey, E. (Geraghty and Miller, Inc., Oak Ridge, TN (United States)); Ball, M.; Schutt, M.

1993-10-01T23:59:59.000Z

339

Kinetics of thermal de-chlorination of PVC under pyrolytic conditions  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Several tests were performed in DTA/TGA for understanding the thermal behavior of pure PVC. Black-Right-Pointing-Pointer We did a kinetic model for the de-chlorination of PVC molecule. Black-Right-Pointing-Pointer A temperature of 340 Degree-Sign C was defined as the optimum temperature for breaking the bond of chlorine in the PVC molecule. Black-Right-Pointing-Pointer The experimental validation of this temperature, led to a removal rate of 99.9% chlorine. - Abstract: Although PVC-containing wastes are an important potential source of energy they are frequently disposed in landfill. In thermal treatment processes such as pyrolysis and gasification, the presence of poly(vinyl chloride) (PVC), a compound with 56.7% of chlorine, may cause problems concerned with environmental protection, as consequence of the formation of hydrochloric acid, chlorine gas and dioxins, as well as corrosion phenomena of the reactor/equipment materials. Thus, a possible solution may involve a previous removal of the chlorine from PVC containing waste through a pyrolysis process at low temperatures before the material being submitted to a subsequent thermal treatment, for energetic valorization. In this work, a kinetic model for the thermal decomposition of PVC has been developed, in view of its de-chlorination. DTA/TGA testing at different temperatures indicated a first order reaction and an activation energy of 133,800 J/mol. An almost completed de-chlorination reaction was obtained at 340 Degree-Sign C under an inert atmosphere. The resulted material is a C{sub n}H{sub n} type polymer with potential to be used in an energy recovery process. Validation test performed at laboratory scale indicate that the temperature of 340 Degree-Sign C enables the removal of {approx}99.9% of the chlorine present in PVC. The chloride can be fixed in the form of an aqueous solution of HCl or calcium chloride, driving to an alternative full process with environmental benefits and reduction of the costs associated to the PCV - containing materials/wastes management.

Castro, Alexandra, E-mail: acastro@cvresiduos.pt [CVR - Centro para a Valorizacao de Residuos (Center for Waste Valorization), Guimaraes (Portugal); CT2M - Centre for Mechanical and Materials Technologies, Mechanical Engineering Department of Minho University, Guimaraes (Portugal); Soares, Delfim; Vilarinho, Candida; Castro, Fernando [CT2M - Centre for Mechanical and Materials Technologies, Mechanical Engineering Department of Minho University, Guimaraes (Portugal)

2012-05-15T23:59:59.000Z

340

TMS Professional Honors and Awards: EPD Technology Award  

Science Conference Proceedings (OSTI)

T.S. Jordan V.C. Nyman. 1975. Robert W. Bartlett H.H. Haung. 1974 P.H. Thornhill E. Wigstol G. Van Weert. 1973 G.D. Hallett G.C. McKerrow. Peter Tarassoff

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

California, General Catalog  

E-Print Network (OSTI)

, Ltd., pp287-315, 1999. 5. Levenson AS, Tonetti DA and Jordan VC: The oestrogen-like effect of 4 induced by high linear energy transfer radiation in breast epithelial cells. Mol Carcinog 31: 192

California at Santa Cruz, University of

342

QUARTERLY NUCLEAR POWER DEPLOYMENT SUMMARY APRIL 2013 News Updates  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Units 3 and 4 and V.C. Summer Units 2 and 3 have been issued. Vogtle Assembly and welding of unit 3's containment vessel bottom head is complete. Assembly of unit 4's...

343

SmartAHS and SHIFT Enhancements, Persistence and Query Interpretation  

E-Print Network (OSTI)

the PC version of the TCL/TK language, and this constituteslexer and parser tools, Tcl/Tk, gnu C compiler. This effortwith MS VC++ and also uses Tcl/Tk. The Tcl/Tk programming

Misener, Jim

2000-01-01T23:59:59.000Z

344

Predictive modeling of integrated circuit manufacturing variation  

E-Print Network (OSTI)

of three cells in a standard cell row and the resultingtheir orientation in standard-cell rows. In Section V.C ofof three cells in a standard cell row and the resulting

Muddu, Swamy V.

2007-01-01T23:59:59.000Z

345

The Internationalization of Venture Capital and Private Equity*  

E-Print Network (OSTI)

Guler I. and M. F. Guillen (2005), “Knowledge, Institutions,A study by Guler and Guillen (2005) finds that VC firms tend2001), and Guler and Guillen (2005)]. We also find that a

Aizenman, Joshua; Kendall, Jake

2008-01-01T23:59:59.000Z

346

Surge Protection Anthology Development of Standards ...  

Science Conference Proceedings (OSTI)

... However, it is still frequently necessary for Ontario Hydro to make its own test ... range of surge voltages occurring in low- vc!t=ge zc pcwer circnitr car! ...

2013-05-17T23:59:59.000Z

347

BCM 2 Equipment Inventory | Sample Preparation Laboratories  

NLE Websites -- All DOE Office Websites (Extended Search)

(Cold Room) Refrigerated Fisher Marathon 21KBr centrifuge (0-13,300 rpm dependent on rotor). Sanyo VIP Series MDF-U73VC Temperature Control Sanyo VIP Series -86C ultra low...

348

Interaction model of private equity and venture capital developing factors in Chile and Latin America  

E-Print Network (OSTI)

Private equity and venture capital (PE/VC) are efficient resource allocation systems that provide equity capital to selected entrepreneurs, industries or firms that contribute to advance the economic welfare of society. ...

Sevil Esteban, Ángel

2012-01-01T23:59:59.000Z

349

Behavior of two capstone 30kW microturbines operating in parallel with impedance between them  

E-Print Network (OSTI)

Average of 96 Samples: Va = 3.52% THD, 270.0 Volts Vb =3.49% THD, 270.2 Volts Vc =3.51% THD, 271.6 Volts Percent of Fundamental Va Avg Vb Avg

Yinger, Robert J.

2004-01-01T23:59:59.000Z

350

plot_nuclear.eps  

NLE Websites -- All DOE Office Websites (Extended Search)

I , Pb T , Pb I , Fe T , Fe I , C T , C p lab (GeVc) (gcm 2 ) Nuclear interaction and collision lengths for Pb, Fe, and C (Incident p and n cases...

351

Plan and justification for a Proof-of-Concept oil shale facility  

SciTech Connect

The technology being evaluated is the Modified In-Situ (MIS) retorting process for raw shale oil production, combined with a Circulating Fluidized Bed Combustor (CFBC), for the recovery of energy from the mined shale. (VC)

1990-12-01T23:59:59.000Z

352

Plan and justification for a Proof-of-Concept oil shale facility. Final report  

SciTech Connect

The technology being evaluated is the Modified In-Situ (MIS) retorting process for raw shale oil production, combined with a Circulating Fluidized Bed Combustor (CFBC), for the recovery of energy from the mined shale. (VC)

1990-12-01T23:59:59.000Z

353

Activized Learning: Transforming Passive to Active with Improved Label Complexity  

Science Conference Proceedings (OSTI)

We study the theoretical advantages of active learning over passive learning. Specifically, we prove that, in noise-free classifier learning for VC classes, any passive learning algorithm can be transformed into an active learning algorithm with asymptotically ...

Steve Hanneke

2012-06-01T23:59:59.000Z

354

Fermilab Today  

NLE Websites -- All DOE Office Websites (Extended Search)

The CDMS collaboration found that if WIMPs have 100 times the mass of protons (about 100 GeVc2) they collide with one kilogram of germanium less than a few times per year;...

355

Greener Capital | Open Energy Information  

Open Energy Info (EERE)

clean technology VC. References Greener Capital1 LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now This article is a stub. You can help OpenEI...

356

Microphotonic parabolic light directors fabricated by two-photon lithography  

E-Print Network (OSTI)

light directors for producing collimated beams for applications in advanced solar cell and light-emitting diode designs. VC 2011 American Institute of Physics. [doi:10.1063/1.3648115] Planar micro- and nano

Heaton, Thomas H.

357

Design of gasifiers to optimize fuel cell systems  

DOE Green Energy (OSTI)

The objective of this project is to configure coal gasification/carbonate fuel cell systems that can significantly improve the economics, performance, and efficiency of electric power generation systems. (VC)

Not Available

1992-02-01T23:59:59.000Z

358

Static and dynamic virtual channel allocation for high performance, in-order communication in on-chip networks  

E-Print Network (OSTI)

Most routers in on-chip interconnection networks (OCINs) have multiple virtual channels (VCs) to mitigate the effects of head-of-line blocking. Multiple VCs necessitate VC allocation schemes since packets or flows must ...

Shim, Keun Sup

2010-01-01T23:59:59.000Z

359

Comparison of Control Strategy for Double-fed Induction Generator (DFIG)  

Science Conference Proceedings (OSTI)

Vector Control(VC) and Direct Power Control (DPC) of Doubly Fed Induction Generator(DFIG) is studied in this paper. Grid connection and steady state running for DFIG are discussed based on VC and DPC. Two kinds of control strategies of DFIG both have ... Keywords: double-fed induction generator (DFIG), idle load grid-connection, direct power control, vector control, grid voltage orientation

Liu Qizhong; Yu Lan; Wu Guoxiang

2011-01-01T23:59:59.000Z

360

A scalable virtual circuit routing scheme for ATM networks  

Science Conference Proceedings (OSTI)

Abstract: We present a scalable VC routing protocol based on the viewserver hierarchy. Each viewserver maintains a partial view of the network. By querying these viewservers, a source obtains a merged view that contains a path to the destination. The ... Keywords: ATM networks, asynchronous transfer mode, blocking probability, destination, packet switching networks, real-time workload, scalable VC routing protocol, scalable virtual circuit routing, setup request packet, simulation, source, storage, viewserver hierarchy

1995-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency Title Effect of Vinylene Carbonate on Graphite Anode Cycling Efficiency Publication Type Journal Article Year of Publication 2009 Authors Ridgway, Paul L., Honghe Zheng, Xiangyun Song, Gao Liu, Philip N. Ross, and Vincent S. Battaglia Journal Electrochemical Society Volume 19 Start Page 51 Issue 25 Pagination 51-57 Abstract Vinylene Carbonate (VC) was added to the electrolyte in graphite-lithium half-cells. We report its effect on the coulombic efficiency (as capacity shift) of graphite electrodes under various formation cycling conditions. Cyclic voltammetry on glassy carbon showed that VC passivates the electrode against electrolyte reduction. The dQ/dV plots of the first lithiation of the graphite suggest that VC alters the SEI layer, and that by varying the cell formation rate, the initial ratio of ethylene carbonate to VC in the SEI layer can be controlled. VC was found to decrease first cycle efficiency and reversible capacity (in ongoing cycling) when used to excess. However, experiments with VC additive used with various formation rates did not show any decrease in capacity shift.

362

Chemical Emissions of Residential Materials and Products: Review of Available Information  

E-Print Network (OSTI)

of 2-butoxyethanol emissions from selected consumer productsfrom vinyl flooring in the emission cell “FLEC". Atmosphericfrom household product emissions in the presence of ozone: A

Willem, Henry

2010-01-01T23:59:59.000Z

363

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Arasteh, Howdy Goudey, Christian Kohler, and Stephen E. Selkowitz. Research Needs: Glass Solar Reflectance and Vinyl Siding., 2011. 2010 Gustavsen, Arlid, Goce Talev, Dariush K....

364

Christian Kohler  

NLE Websites -- All DOE Office Websites (Extended Search)

Arasteh, Howdy Goudey, Christian Kohler, and Stephen E. Selkowitz. Research Needs: Glass Solar Reflectance and Vinyl Siding., 2011. Download: PDF (1.39 MB) 2010 Gustavsen, Arlid,...

365

Technology Partnerships Office  

Science Conference Proceedings (OSTI)

... NRB) in broadband coherent anti-Stokes Raman scattering (CARS) microscopy to ... photo ablate hydrophilic poly vinyl alcohol (PVA) hydro gels and ...

366

Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units  

E-Print Network (OSTI)

constructed with ?-inch plywood with a vinyl or PVC skin orto the high surface area of plywood paneling, all THUs hadstandards for all plywood and particleboard materials using

Parthasarathy, Srinandini

2011-01-01T23:59:59.000Z

367

EFFECT OF TEMPERATURE AND HUMIDITY ON FORMALDEHYDE EMISSIONS IN TEMPORARY HOUSING UNITS  

E-Print Network (OSTI)

constructed with ?-inch plywood with a vinyl or PVC skin ortile, gypsum board, shiplap, plywood, terracotta brick) thatsamples are all made from plywood. Humidity Equilibration

Parthasarathy, Srinandini

2010-01-01T23:59:59.000Z

368

New Boston, Ohio: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

County, Ohio. It falls under Ohio's 2nd congressional district.12 Registered Energy Companies in New Boston, Ohio Vinyl Kraft Windows and Doors References US Census...

369

Indoor Residential Chemical Emissions as Risk Factors for Children...  

NLE Websites -- All DOE Office Websites (Extended Search)

The identified risk factors include specific organic compounds such as formaldehyde, benzene, and phthalates, as well as indoor materials or finishes such as vinyl flooring,...

370

Techniques and Technologies for Field Detection of Asbestos Containing Materials  

Energy.gov (U.S. Department of Energy (DOE))

Asbestos has been used in numerous applications at DOE sites including sprayed-on fireproofing, asphalt and vinyl floor tile, and asbestos-cement(transite) siding.

371

Window performance for human thermal comfort  

E-Print Network (OSTI)

of Heat Transfer through Windows”. ASHRAE Transactions 93,Performance of Vinyl-framed Windows”. Proc. 5 th Conf. Onet al. 2003b, "Operable Windows, Personal Control & Occupant

Huizenga, C; Zhang, H.; Mattelaer, P.; Yu, T.; Arens, Edward A; Lyons, P.

2006-01-01T23:59:59.000Z

372

Indoor air quality and the emissions of VOCs from interior ...  

U.S. Energy Information Administration (EIA)

How to Cite. Tshudy, J. A. (1995), Indoor air quality and the emissions of VOCs from interior products. J Vinyl Addit Technol, 1: 155–158. doi: ...

373

Field Derived Emission Factors For Formaldehyde and other ...  

U.S. Energy Information Administration (EIA)

Field Derived Emission Factors For Formaldehyde and other ... ORGANIC COMPOUNDS; PHENOL; PLASTICIZERS; ... of TMPB-DIB (a plasticizer found in vinyl . ...

374

Field Derived Emission Factors For Formaldehyde and other ...  

U.S. Energy Information Administration (EIA)

Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3.

375

Choose building products that avoid toxic emissions  

U.S. Energy Information Administration (EIA)

Choose building products that avoid toxic emissions. ... (PVC or vinyl) products have a wide range of chlorine that ... and also the plasticizers in ...

376

Emission Factors For Formaldehyde - Home | Energy Analysis ...  

U.S. Energy Information Administration (EIA)

Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3.

377

Licenses Available in Chemicals | Tech Transfer | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Uses Thereof 201002471 Interfacial controlled fusion of individual femtoliter droplets on demand 201002484 Approach to prepare selectively deuterated vinyl pyridines 201002516...

378

NISTTech  

Science Conference Proceedings (OSTI)

... sized spots using a tunable multi-photon laser coupled to a confocal microscope to photo ablate hydrophilic poly vinyl alcohol (PVA) hydro gels and ...

379

Chloride/magnesium ratio of shallow groundwaters as a regional geothermal indicator in Hawaii. Assessment of geothermal resources in Hawaii: Number 3  

DOE Green Energy (OSTI)

Because of the complex geological and hydrological conditions and the virtual lack of thermal springs, regional geothermal investigations in Hawaii require the use of techniques substantially different from those conventionally applied in other geothermal environments. The large number of hydrological wells in the state provides an appreciable source of groundwater chemical data. However, largely because of the island environment, interpretation of much of these data as geothermal indicators becomes ambiguous. Initially, SiO/sub 2/ and temperature of groundwaters were used to identify thermally anomalous zones, but on a regional basis it has been found that these criteria are not always successful. As a further criterion for assessment, the Cl/Mg ratio of the groundwater has been used. On a state-wide basis, this ratio has been successful in further screening the SiO/sub 2/-temperature selected sites, and in defining more specific areas which warrant further investigation. Temperature, SiO/sub 2/ and Cl/Mg values for nearly 400 groundwater samples are included.

Cox, M.E.; Thomas, D.M.

1979-11-01T23:59:59.000Z

380

Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate  

SciTech Connect

The crystal structure of title compound (Fe[(C{sub 25}H{sub 21}N{sub 7}O{sub 4}S{sub 2})] {center_dot} 4(C{sub 3}NOH{sub 7}), where C{sub 3}NOH{sub 7} is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.6375(7), c = 19.5571(6) A, {beta} = 108.753(2) Degree-Sign . The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms.

Dilek, N., E-mail: nefised@gmail.com [Aksaray University, Department of Physics, Arts and Sciences Faculty (Turkey); Guenes, B. [Gazi University, Department of Physics Education, Gazi Education Faculty (Turkey)] [Gazi University, Department of Physics Education, Gazi Education Faculty (Turkey); Bueyuekguengoer, O. [Ondokuz Mayis University, Department of Physics, Arts and Sciences Faculty (Turkey)] [Ondokuz Mayis University, Department of Physics, Arts and Sciences Faculty (Turkey); Guep, R. [Mugla University, Department of Chemistry, Arts and Sciences Faculty (Turkey)] [Mugla University, Department of Chemistry, Arts and Sciences Faculty (Turkey)

2013-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Comparison of phosgene, chlorine, and hydrogen chloride as reagents for converting molten CaO. CaCl/sub 2/ to CaCl/sub 2/  

Science Conference Proceedings (OSTI)

One method at Los Alamos for preparing impure plutonium metal from the impure oxide is by batch reduction with calcium metal at 850/sup 0/C in a CaCl/sub 2/ solvent. The solvent salt from this reduction is currently discarded as low-level radioactivity waste only because it is saturated with the CaO byproduct. We have demonstrated a pyrochemical technique for converting the CaO to CaCl/sub 2/ thereby incorporating solvent recycling into the batch reduction process. We will discuss the effectiveness of HCl, Cl/sub 2/, and COCl/sub 2/ as chlorinating agents and recycling actual spent process solvent salts. 6 refs., 8 figs.

Fife, K.W.

1985-01-01T23:59:59.000Z

382

Effect of secondary structure on the interactions of peptide T4 LYS (11-36) in mixtures of aqueous sodium chloride and 2,2,2,-Trifluoroethanol  

SciTech Connect

The potential of mean force for protein-protein interactions is key to the development of a statistical-mechanical model for salt-induced protein precipitation and crystallization, and for understanding certain disease states, including cataract formation and {beta}-amyloid pathology in Alzheimer's disease. Fluorescence anisotropy provides a method for quantitative characterization of intermolecular interactions due to reversible association. Monomer-dimer equilibria for the peptide T4 LYS(11-36) were studied by fluorescence anisotropy. This peptide, derived from the {beta}-sheet region of the T4 lysozyme molecule, has the potential to form amyloid fibrils. 2,2,2-trifluoroethanol (TFE) induces a change in peptide secondary structure, and was used in aqueous solutions at concentrations from 0 to 50% (v/v) at 25 and 37 C to examine the role of peptide conformation on peptide-peptide interactions. The association constant for dimerization increased with rising TFE concentration and with falling temperature. The peptide-peptide potential of mean force was computed from these association constants. Circular-dichroism measurements showed that the secondary structure of the peptide plays an important role in these strong attractive interactions due to intermolecular hydrogen-bond formation and hydrophobic interactions.

Anderson, Camille O.; Spiegelberg, Susanne; Prausnitz, John M.; Blanch, Harvey W.

2001-10-01T23:59:59.000Z

383

Structure of Hydronium (H3O+)/Chloride (Cl-) Contact Ion Pairs in Aqueous Hydrochloric Acid Solution: A Zundel-like Local Configuration  

SciTech Connect

Details of the H3O+ and H2O structure in the first solvation shell about Cl- in aqueous HCl solutions are reported from x-ray absorption fine structure (XAFS) measurements. Results show increasing degrees of contact ion pairing between Cl- and H3O+ as the HCl concentration increases from 6.0 m, 10.0 m and finally 16.1 m HCl (concentrated acid). At the highest acid concentration there are on average, approximately 1.6 H3O+ ions and 4.2 H2O’s in the first shell about Cl-. The structure of the Cl-/H3O+ contact ion pair is distinctly different than that of the H2O structure about Cl-. The Cl-O bond length (2.98Å) for Cl-/H3O+ is approximately 0.16 Å shorter than the Cl-/H2O bond. The bridging proton resides at an intermediate position between Cl and O at 1.60 Å from the Cl- and approximately 1.37 Å from the O of the H3O+. The bridging-proton structure of this contact ion pair, [Cl-H-OH2], is similar to structure of the water Zundel ion, [H2O-H-OH2]+. In both cases there is a shortened Cl-O or O-O bond and the intervening proton bond distances are substantially longer than for the covalent bonds of either HCl or H2O. The results further our understanding of the interaction H3O+ with Cl- that is of interest to fundamental physical chemistry and that has consequences in biochemical, geochemical and atmospheric processes.

Fulton, John L.; Balasubramanian, Mahalingam

2010-09-15T23:59:59.000Z

384

INDEPENDENT TECHNICAL REVIEW OF THE BUILDING 100 PLUME, FORMER DOE PINELLAS SITE (YOUNG - RAINEY STAR CENTER), LARGO, FLORIDA  

SciTech Connect

Contaminated groundwater associated with Building 100 at the Young-Rainey Science, Technology, and Research Center, formerly the DOE Pinellas plant, is the primary remedial challenge that remains to be addressed at the site. Currently, Building 100 is an active industrial facility that is now owned and operated by the Pinellas county government. Groundwater samples collected from monitoring wells recently installed near the southern boundary of the site suggest that contaminated groundwater has migrated off the plant site. In response to the challenges presented by the Building 100 plume, the Office of Legacy Management (LM) requested assistance from the DOE Office of Groundwater and Soil Remediation (EM-32) to provide a review team to make technical recommendations so that they can efficiently and effectively address characterization and remediation of the plume. The review team was unanimous in the conclusion that a dynamic strategy that combines a phased implementation of direct push samplers, sensors, and tools can be used to better delineate the extent of contamination, control plume migration, and rapidly remediate the contaminated groundwater at the site. The initial efforts of the team focused on reviewing the site history and data, organizing the information into a conceptual model, identifying appropriate technologies, and recommending an integrated strategy. The current groundwater data from the site indicate a two-lobed plume extending to the east and south. To the east vinyl chloride is the primary contaminant of concern, to the south, vinyl chloride and cis1, 2-DCE are the primary contaminants. The limited data that are available suggest that reductive dechlorination of the TCE is already occurring but is not sufficient to prevent offsite migration of low concentrations of TCE daughter products. The team recommends that DOE pursue a strategy that builds on the natural cleansing capacity of the subsurface with reductive methods including biostimulation and/or bioaugmentation to provide a sustainable remediation system within the flow path of the plume. Additional data will be required to implement this approach and will include: (1) Better delineation of the nature and extent of contamination; (2) Demonstration the plume is currently stable or shrinking; and (3) Demonstration the full reductive dechlorination is occurring. The technical team recommends that DOE use a phased approach to identify residual contamination and to provide rapid installation of remedies. Matrices of characterization and remediation sensors, technologies, and tools were developed by the team in order to match the specific conditions and requirements of the site. The team provides a specific example of remedy that includes the incorporation of a dynamic characterization strategy moving from minimally invasive to more aggressive field techniques, the consideration of multiple complementary remediation approaches based on a spatiotemporally phased approach keyed to the different demands of different parts of the plume, and the integration and sequencing of the characterization and remediation activities.

Eddy-Dilek, C.; Rossabi, J.; Amidon, M.; Riha, B.; Kaback, D.

2010-07-30T23:59:59.000Z

385

Application of fundamental kinetic modeling to industrial chlorination and partial oxidation processes  

E-Print Network (OSTI)

The Fundamental Kinetic Modeling (FKM) method is able to use a growing amount of elementary kinetic rate constant data to simulate industrial reactions and therefore gain insight and predictive capabilities beyond those of traditional empirical kinetic models. Because traditional empirical kinetic models often simplify the underlying kinetics into a single overall reaction, these recently determined values cannot be used directly. In addition to simulating irreducible chemical events as opposed to an overall reaction, the FKM does not make assumptions about microscopic reversibility. To obtain the reverse rate constants, the thermophysical properties for the species are required. Advances in computing technology have made ab initio quantum chemical calculations feasible for oxygenated and chlorinated hydrocarbons. Thermophysical properties for species that cannot be obtained experimentally are now available with greater accuracy than using prior estimating techniques. The FKM method is able to use these values to obtain information about temperature and concentration profiles as well as product distributions and selectivities for a variety of reactor configurations. The application of the FKM method to industrial reactions could be used to optimize existing operating conditions or to predict novel processes. One such chemistry is the oxychlorination of ethane to vinyl chloride. The problem is most easily solved in three steps: the development of a thermal chlorination model, the development of a partial oxidation model, and the combination of the two models with the necessary additional species and reactions. This work focuses on the first two steps. A thermal chlorination model is verified against two sources of experimental data with good quantitative agreement. In addition, differences in product distributions are explained by examining the kinetic pathways. Also, an existing partial oxidation model is combined with newly calculated thermophysical properties. The agreement with two experimental data sources is not as good quantitatively; however, qualitative agreement is observed. Areas for improvement to obtain quantitative agreement are determined.

Han, Joseph Hsiao-Tien

2000-01-01T23:59:59.000Z

386

Responsive copolymers for enhanced petroleum recovery. Second annual report  

SciTech Connect

The authors describe second year efforts in synthesis, characterization, and rheology to develop polymers with significantly improved efficiency in mobility control and conformance. These advanced polymer systems would maintain high viscosities or behave as virtual gels under low shear conditions and at elevated electrolyte concentrations. At high fluid shear rates, associates would deaggregate yielding low viscosity solutions, reducing problems of shear degradation or face plugging during injection. Polymeric surfactants were also developed with potential for use in higher salt, higher temperature reservoirs for mobilization of entrapped oil. Chapters include: Ampholytic terpolymers of acrylamide with sodium 3-acrylamido-3-methylbutanoate and 2-acrylamido-2-methylpropanetrimethylammonium chloride; Hydrophilic sulfobetaine copolymers of acrylamide and 3-(2-acrylamido-methylpropane-dimethylammonio)-1-propanesulfonate; Copolymerization of maleic anhydride and N-vinylformamide; Reactivity ratio of N-vinylformamide with acrylamide, sodium acrylate, and n-butyl acrylate; Effect of the distribution of the hydrophobic cationic monomer dimethyldodecyl(2-acrylamidoethyl)ammonium bromide on the solution behavior of associating acrylamide copolymers; Effect of surfactants on the solution properties of amphipathic copolymers of acrylamide and N,N-dimethyl-N-dodecyl-N-(2-acrylamidoethyl)ammonium bromide; Associative interactions and photophysical behavior of amphiphilic terpolymers prepared by modification of maleic anhydride/ethyl vinyl ether copolymers; Copolymer compositions of high-molecular-weight functional acrylamido water-soluble polymers using direct-polarization magic-angle spinning {sup 13}C NMR; Use of factorial experimental design in static and dynamic light scattering characterization of water soluble polymers; and Porous medium elongational rheometer studies of NaAMB/AM copolymer solutions.

McCormick, C.; Hester, R.

1995-05-01T23:59:59.000Z

387

Water injection as a means for reducing non-condensible and corrosive gases in steam produced from vapor-dominated reservoirs  

E-Print Network (OSTI)

Chloride in Superheated Steam and Chloride in Deep Brine atGas and Chloride in Steam at The Geysers, Trans. , Geoth.Decline Trends in Geothermal Steam Reservoirs, Proceedings,

Pruess, Karsten; Spycher, Nicolas; Kneafsey, Timothy J.

2008-01-01T23:59:59.000Z

388

Load Profiling Based Routing for Guaranteed Bandwidth Flows  

E-Print Network (OSTI)

. To support the stringent Quality of Service (QoS) requirements of real-time (e.g. audio/video) applications in integrated services networks, several routing algorithms that allow for the reservation of the needed bandwidth over a Virtual Circuit (VC), established on one of several candidate routes, have been proposed. Traditionally, such routing is done using the least-loaded concept, and thus results in balancing the load across the set of candidate routes. In this paper, we propose the use of load profiling as an attractive alternative to load balancing for routing guaranteed bandwidth VCs (flows). Load profiling techniques allow the distribution of "available" bandwidth across a set of candidate routes to match the characteristics of incoming VC QoS requests. We thoroughly characterize the performance of VC routing using load profiling and contrast it to routing using load balancing and load packing. We do so both analytically and via extensive simulations of multi-class traffic r...

Ibrahim Matta; Azer Bestavros; Marwan Krunz

1999-01-01T23:59:59.000Z

389

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Install additional injection wells in order to determine the most efficient delivery system for the silver chloride solution. F Area HWMF Silver Chloride Solution Injection Wells...

390

New SRMs  

Science Conference Proceedings (OSTI)

... SRM 1991 Mix Coal Tar/Petroleum Extract in Methylene Chloride ... NIST SRM 1991 Mixed Coal Tar/Petroleum Extract in Methylene Chloride ...

2013-07-30T23:59:59.000Z

391

New SRMs  

Science Conference Proceedings (OSTI)

... SRM 1991 Mix Coal Tar/Petroleum Extract in Methylene Chloride ... NIST SRM 1991 Mixed Coal Tar/Petroleum Extract in Methylene Chloride ...

2013-08-13T23:59:59.000Z

392

New and Renewal NIST SRMs/RMs  

Science Conference Proceedings (OSTI)

... SRM 1991 Mix Coal Tar/Petroleum Extract in Methylene Chloride ... NIST SRM 1991 Mixed Coal Tar/Petroleum Extract in Methylene Chloride ...

2013-07-01T23:59:59.000Z

393

AOCS Official Method Da 9-48  

Science Conference Proceedings (OSTI)

Chlorides AOCS Official Method Da 9-48 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method determines the chlorides in the sample. SCOPE...

394

AOCS Official Method S 4c-64  

Science Conference Proceedings (OSTI)

Methods for Testing Fatty Quaternary Ammonium Chlorides AOCS Official Method S 4c-64 Methods Downloads Methods Downloads DEFINITION   SCOPE Fatty quaternary ammonium chlorides a

395

PRODUCTION OF ELECTROLYTIC THORIUM CELL FEED BY A WET CHEMICAL METHOD. Process Report  

SciTech Connect

In order to produce a substantially oxide-free chloride. a specialized technique, based on the chemical characteristics of the ammonium thorium chloride complexes, has been found optimum. The procedure involves the formation of a solution of thorium chloride and ammonium chloride, evaporation of the solution to form a hydrated ammonium thorium chloride complex, dehydration of the complex by low-temperature drying, and ignition of the complex, after inter-mixture with an alkali chloride, to remove ammonium chloride and to form a thorium alkali chloride mixture for electrolysis. (L.T.W.)

Fisher, C.E.

1955-03-18T23:59:59.000Z

396

Compilation of NIST Higher-Order Methods for the ...  

Science Conference Proceedings (OSTI)

... Re-precipitate the chloride by drop-wise addition of nitric acid (10 % volume ... Load approximately 10 µg of chloride onto each of two rhenium side ...

2011-08-04T23:59:59.000Z

397

Molten Salts, Magnesium and Aluminum  

Science Conference Proceedings (OSTI)

Mar 1, 2011 ... Chloride 2011: Practice and Theory of Chloride-Based Metallurgy: Molten Salts, Magnesium and Aluminum Sponsored by: The Minerals, ...

398

TMS 2011: Proceedings and Publications  

Science Conference Proceedings (OSTI)

... Metals and Materials; Chloride 2011: Practice and Theory of Chloride-Based ... in Next Generation Nuclear Power Plants; Characterization of Nuclear Reactor ...

399

2011 DOE Hydrogen and Fuel Cells Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

85 85 FY 2011 Annual Progress Report DOE Hydrogen and Fuel Cells Program 3M Company V.B.1 Effect of System Contaminants on PEMFC Performance and Durability . . . . . . . . . . . . . . . . . . . . . . . . . . . . 640 V.C.1 Membranes and MEAs for Dry, Hot Operating Conditions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662 V.C.6 Novel Approaches to Immobilized Heteropoly Acid (HPA) Systems for High Temperature, Low Relative Humidity Polymer-Type Membranes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 685 V.D.1 Advanced Cathode Catalysts and Supports for PEM Fuel Cells . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 699 V.D.3 Durable Catalysts for Fuel Cell Protection During Transient Conditions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .714

400

Distinct timing in the activity of cannabinoid-sensitive and cannabinoid-insensitive basket cells  

E-Print Network (OSTI)

depol. Control Recovery 20 pA 4 ms 75 mV 25 pA 4 ms 50 mV b 20pA 20ms 5 µM AM-251 AM-251Control ResidualuniraryIPSC(%) 0 20 40 60 80 100 120 140 =10.2 s After depol. Control Recovery IC VC VC IC CB1R Biocytin (normalized) b a 100 pA 20 ms 100 pA 40 ms Control Recovery After depol. 10 ms AM251 NBQX 10 ms 100 pA 20 ms

Scanziani, Massimo

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Beam Loss Monitors for NSLS-II Storage Ring  

Science Conference Proceedings (OSTI)

The shielding for the NSLS-II storage ring will provide adequate protection for the full injected beam losses in two cells of the ring around the injection point, but the remainder of the ring is shielded for lower losses of Cerenkov light as electrons transit ultra-pure fused silica rods placed close to the inner edge of the VC. The entire length of the rod will collect light from the electrons of the spread out shower resulting from the small glancing angle of the lost beam particles to the VC wall. The design and measurements results of the prototype Cerenkov BLM will be presented.

Kramer, S.L.; Cameron, P.

2011-03-28T23:59:59.000Z

402

Diffusion Coatings for Gas Turbine Engine Hot Section Parts  

Science Conference Proceedings (OSTI)

...ammonium chloride, and alumina was described in 1954 (Ref 12). Siliconizing of nickel and cobalt superalloys

403

Chemical Hygiene and Safety Plan  

E-Print Network (OSTI)

pentafluoride bromine trifluoride carbonyl fluoride chlorinechlorine trifluoride cyanogen cyanogen chloride diboranetrifluoride carbonyl fluoride chlorine chlorine trifluoride

Ricks Editor, R.

2009-01-01T23:59:59.000Z

404

Technical Report Documentation Page 1. Report No.  

E-Print Network (OSTI)

Database (eGRID) #12;Page 2 A calcium chloride solution concentrates (regenerates) while passing over

Texas at Austin, University of

405

Humboldt National Forest East Mormon  

E-Print Network (OSTI)

Vegas Blue Diamond Paradise Trona Spring Valley Searles Valley Tonopah Chloride Searchlight Shoshone

Laughlin, Robert B.

406

Production of aluminum metal by electrolysis of aluminum sulfide  

DOE Patents (OSTI)

Production of metallic aluminum by the electrolysis of Al.sub.2 S.sub.3 at 700.degree.-800.degree. C. in a chloride melt composed of one or more alkali metal chlorides, and one or more alkaline earth metal chlorides and/or aluminum chloride to provide improved operating characteristics of the process.

Minh, Nguyen Q. (Woodridge, IL); Loutfy, Raouf O. (Tucson, AZ); Yao, Neng-Ping (Clarendon Hills, IL)

1984-01-01T23:59:59.000Z

407

Service Life Prediction  

Science Conference Proceedings (OSTI)

Prediction of Service Life of Reinforced Concrete Structure Exposed to Chlorides. Please supply the following parameters ...

2013-09-10T23:59:59.000Z

408

In-situ Analysis of Zinc Electrodeposition within an Ionic Liquid Electrolyte  

E-Print Network (OSTI)

chloride low temperature molten salt. Electrochimica Acta,room temperature molten salt. Journal of the Electrochemical

Keist, Jayme

2013-01-01T23:59:59.000Z

409

C1700098Cu-1.7Be-0.3Co  

Science Conference Proceedings (OSTI)

Table 30   Approximate corrosion resistance of C17000...Potassium sulfate Sodium hydroxide Picric acid Propane Sodium hypochlorite Potassium cyanide Rosin Sodium peroxide Silver chloride Sodium bicarbonate Sodium sulfide Sodium cyanide Sodium chloride Sulfur Stannic chloride Sodium sulfate Sulfur chloride Sulfuric acid, aerated Sulfur dioxide Sulfuric acid,...

410

C17200, C17300  

Science Conference Proceedings (OSTI)

Table 34   Approximate corrosion resistance of C17200 and C17300...Potassium hydroxide Phosphoric acid, aerated Propane Sodium hydroxide Picric acid Rosin Sodium hypochlorite Potassium cyanide Sodium bicarbonate Sodium peroxide Silver chloride Sodium chloride Sodium sulfide Sodium cyanide Sodium sulfate Sulfur Stannic chloride Sulfur dioxide Sulfur chloride Sulfuric...

411

A Versatile Catalyst System for Suzuki?Miyaura Cross-Coupling Reactions of C(sp[superscript 2])-Tosylates and Mesylates  

E-Print Network (OSTI)

A catalyst system for the Suzuki?Miyaura cross-coupling reactions of aryl and vinyl tosylates and mesylates has been developed. This catalyst displays excellent functional group tolerance and allows the coupling of ...

Bhayana, Brijesh

412

Infrared Thermography Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Hollow vs. Foam-Filled Vinyl Windows Hollow vs. Foam-Filled Vinyl Windows Hollow vs. Foam-filled Vinyl Windows (100K) These two windows are the same except for what is inside the vinyl frames. The frame on the left is hollow, while the frame on the right is filled with insulating foam. The units have the same insulated glazing unit, a superwindow with R-8 center of glass. The hollow window frame allows air to circulate inside the frame; this convective effect is observed by noticing the frame temperatures are cooler at the bottom than at the top. The foam-filled window doesnÌt show this effect. These windows are being cooled on the back side with wind at -15°C (5°F). For more information contact: Howdy Goudey Building Technologies Program 510-486-6046 (fax) Return to the IRlab page Building Technologies | Energy & Environment Division | Lawrence Berkeley National Laboratory

413

MOLECULAR BEAM STUDIES OF UNIMOLECULAR REACTIONS: Cl, F + C2H3Br  

E-Print Network (OSTI)

pro~ of fluorine and chlorine atoms with vinyl bromide areheated nickle oven at The chlorine source was similar,the tot&l energy for the chlorine re&ction &nd FWHM ~ 4.2 kJ

Buss, Richard J.

2011-01-01T23:59:59.000Z

414

Supplemental Section 106 Compliance  

NLE Websites -- All DOE Office Websites (Extended Search)

and a flat-roofed ell at the right of the faade. A small deck has been added atop the flat roof. All visible windows have been replaced with vinyl windows. According to County...

415

Techniques for reducing exposures to volatile organic compounds associated with new construction and renovation  

E-Print Network (OSTI)

applied to gypsum board and plywood substrates. This wasapplied to 1.1-m 2 of plywood. The carpet and vinyl flooringThe SGLPs were applied to plywood. The two non-VOC paints,

Hodgson, A.T.; Shimer, D.A.

1999-01-01T23:59:59.000Z

416

ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS – FINAL REPORT  

E-Print Network (OSTI)

Development Hardwood Plywood Lawrence Berkeley Nationalconstructed of 1/8-inch plywood with a vinyl or PVC skin orone material, the Cavalier plywood cabinet wall (490 µg m -2

Maddalena, Randy L.

2008-01-01T23:59:59.000Z

417

The development of palladium-catalysts for organic synthesis  

E-Print Network (OSTI)

Chapter 1. Suzuki-Miyaura coupling reactions of aryl and heteroaryl halides with aryl-, heteroaryl and vinyl boronic acids proceed in very good to excellent yield with the use of 2-(2',6'-dimethoxybiphenyl)-dicyclohexylphosphine, ...

Martinelli, Joseph R

2007-01-01T23:59:59.000Z

418

Direct synthesis of pyridine and pyrimidine derivatives  

E-Print Network (OSTI)

I. Synthesis of Substituted Pyridine Derivatives via the Ruthenium-Catalyzed Cycloisomerization of 3-Azadienynes. The two-step conversion of various N-vinyl and N-aryl amides to the corresponding substituted pyridines and ...

Hill, Matthew D. (Matthew Dennis)

2008-01-01T23:59:59.000Z

419

Green chemistry : dense carbon dioxide and water as environmentally benign reaction media  

E-Print Network (OSTI)

(cont.) was investigated in scCO?, and the cycloaddition between cyclopentadiene and methyl vinyl ketone (MVK) was studied in an scCO?/liquid water environment. Nitrogen chemistry, specifically the synthesis of nitrogen ...

Allen, Andrew J. (Andrew John), 1978-

2004-01-01T23:59:59.000Z

420

Methods for Measuring Friction  

Science Conference Proceedings (OSTI)

Table 1   Selected solid friction tests per ASTM standards...for Coefficient of Friction Vinyl and wool tiles (preparation only) Any apparatus E 303 (E-17 on traveled surfaces) Measuring Surface

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

BEESE ET AL. VOL. 7 ' NO. 4 ' 34343446 ' 2013 www.acsnano.org  

E-Print Network (OSTI)

, spinning from CNT aerogel, and twisting or rolling of CNT films, as summarized in a recent review article coating on the surface of the DWNT bundles interacts strongly with poly(vinyl alcohol) (PVA) through

Espinosa, Horacio D.

422

BEESE ET AL. VOL. XXX ' NO. XX ' 000000 ' XXXX www.acsnano.org  

E-Print Network (OSTI)

, spinning from CNT aerogel, and twisting or rolling of CNT films, as summarized in a recent review article coating on the surface of the DWNT bundles interacts strongly with poly(vinyl alcohol) (PVA) through

Espinosa, Horacio D.

423

An analysis of residential window waterproofing systems  

E-Print Network (OSTI)

The prevalence of vinyl nail-on windows in the North American new home construction market has prompted ASTM International to write ASTM E2112-01 "Standard Practice for Installation of Exterior Windows, Doors and Skylights". ...

Parsons, Austin, 1959-

2004-01-01T23:59:59.000Z

424

Welcome to the Efficient Windows Collaborative  

NLE Websites -- All DOE Office Websites (Extended Search)

Break Metal Non-metal Frames There is a variety of non-metal framing materials for windows including, wood, wood with metalvinyl cladding, vinyl, hybrid, and composites. This...

425

An analysis of residential window waterproofing systems.  

E-Print Network (OSTI)

??The prevalence of vinyl nail-on windows in the North American new home construction market has prompted ASTM International to write ASTM E2112-01 "Standard Practice for… (more)

Parsons, Austin, 1959-

2004-01-01T23:59:59.000Z

426

Treatment of addiction and addiction-related behavior  

DOE Patents (OSTI)

The present invention provides a highly efficient method for treating substance addiction and for changing addiction-related behavior of a primate suffering from substance addiction. The method includes administering to a primate an effective amount of a pharmaceutical composition including gamma vinylGABA. The present invention also provides a method of treatment of nicotine addiction by treating a patient with an effective amount of a composition including gamma vinylGABA.

Dewey, Stephen L. (Manorville, NY); Brodie, Jonathan D. (Cos Cob, CT); Ashby, Jr., Charles R. (Miller Place, NY)

2000-01-01T23:59:59.000Z

427

An approach to catalytic asymmetric electrocyclization  

E-Print Network (OSTI)

petroleum ether 40-60 Ph phenyl ppm parts per million Pr propyl q quartet Rf retention factor rt room temperature s singlet sept septet t triplet t tertiary TBAF tetrabutylammonium fluoride TBS tert... demonstrated by Nelson.73 In this case, we observed the formation of lactone 75 by vinyl nucleophile addition to the corresponding aldehydes 71 and 72. We require a less basic source of vinyl anion, or a bulkier ester such as tert-butyl, to prevent any...

Kothari, Abhishek

2010-02-09T23:59:59.000Z

428

Radiation Measurements 42 (2007) 10291032 www.elsevier.com/locate/radmeas  

E-Print Network (OSTI)

-specific damage in cells exposed to depleted uranium: hprt gene mutation frequency Alexandra C. Millera, , Michael University, 630 W. 168th St. VC11-215, New York, NY 10032, USA Abstract Depleted uranium (DU) is a dense: Depleted uranium; HPRT; Mutagenicity; V79 cells 1. Introduction Several US military personnel participating

429

JOURNAL DE PHYSIQUE IV C3-197 Colloque C3, suppl. au Journal de Physique III, Vol. 1, octobre 1991  

E-Print Network (OSTI)

-specific damage in cells exposed to depleted uranium: hprt gene mutation frequency Alexandra C. Millera, , Michael University, 630 W. 168th St. VC11-215, New York, NY 10032, USA Abstract Depleted uranium (DU) is a dense: Depleted uranium; HPRT; Mutagenicity; V79 cells 1. Introduction Several US military personnel participating

Paris-Sud XI, Université de

430

Evaluation Methodologies for ITS Aplications  

E-Print Network (OSTI)

user and social costs, as well as increase in transportationTransportation Demand & Supply with Congestion rnsc D rnPc C D vc I v c V The difference between marginal social costssocial costs. 4.1.3. Definitions of users, providers, and cornrnunity/society Transportation

Gillen, David; Li, Jianling

1999-01-01T23:59:59.000Z

431

Force spectroscopy of polymer desorption: Theory and Molecular Dynamics simulation  

E-Print Network (OSTI)

Forced detachment of a single polymer chain, strongly-adsorbed on a solid substrate, is investigated by two complementary methods: a coarse-grained analytical dynamical model, based on the Onsager stochastic equation, and Molecular Dynamics (MD) simulations with Langevin thermostat. The suggested approach makes it possible to go beyond the limitations of the conventional Bell-Evans model. We observe a series of characteristic force spikes when the pulling force is measured against the cantilever displacement during detachment at constant velocity $v_c$ (displacement control mode) and find that the average magnitude of this force increases as $v_c$ grows. The probability distributions of the pulling force and the end-monomer distance from the surface at the moment of final detachment are investigated for different adsorption energy $\\epsilon$ and pulling velocity $v_c$. Our extensive MD-simulations validate and support the main theoretical findings. Moreover, the simulation reveals a novel behavior: for a strong-friction and massive cantilever the force spikes pattern is smeared out at large $v_c$. As a challenging task for experimental bio-polymers sequencing in future we suggest the fabrication of stiff, super-light, nanometer-sized AFM probe.

J. Paturej; J. L. A. Dubbeldam; V. G. Rostiashvili; A. Milchev; T. A. Vilgis

2013-10-14T23:59:59.000Z

432

Heat Hyperbolic Diffusion in Planck Gas  

E-Print Network (OSTI)

In this paper we investigate the diffusion of the thermal pulse in Planck Gas. We show that the Fourier diffusion equation gives the speed of diffusion, v > c and breaks the causality of the thermal processes in Planck gas .For hyperbolic heat transport v and causality is valid

Miroslaw Kozlowski; Janina Marciak-Kozlowska

2006-07-06T23:59:59.000Z

433

Engineered Cementitious Composites (ECC) Bendable Concrete Fracture MechanicsExperiments and Observations  

E-Print Network (OSTI)

and normal concrete Figure 3. Tensile stress-strain behavior of fiber reinforced geopolymer [1] V.C. Li , "On reinforced geopolymer Property Fiber reinforced geopolymer Normal concrete Compressive strength (MPa) 17.4 40Engineered Cementitious Composites (ECC) ­ Bendable Concrete Fracture Mechanics

Li, Victor C.

434

ANNUAL REPORT FOR JULY 2008 JUNE 2009  

E-Print Network (OSTI)

and normal concrete Figure 3. Tensile stress-strain behavior of fiber reinforced geopolymer [1] V.C. Li , "On reinforced geopolymer Property Fiber reinforced geopolymer Normal concrete Compressive strength (MPa) 17.4 40Engineered Cementitious Composites (ECC) ­ Bendable Concrete Fracture Mechanics

435

APS Science 2009 ISSN 1931-5015  

E-Print Network (OSTI)

and normal concrete Figure 3. Tensile stress-strain behavior of fiber reinforced geopolymer [1] V.C. Li , "On reinforced geopolymer Property Fiber reinforced geopolymer Normal concrete Compressive strength (MPa) 17.4 40Engineered Cementitious Composites (ECC) ­ Bendable Concrete Fracture Mechanics

Kemner, Ken

436

2006ANNUAL REPORT CHAPTER 1 TABLE OF CONTENTS 2006 NHMFL ANNUAL REPORT  

E-Print Network (OSTI)

and normal concrete Figure 3. Tensile stress-strain behavior of fiber reinforced geopolymer [1] V.C. Li , "On reinforced geopolymer Property Fiber reinforced geopolymer Normal concrete Compressive strength (MPa) 17.4 40Engineered Cementitious Composites (ECC) ­ Bendable Concrete Fracture Mechanics

Weston, Ken

437

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Feb. 2003, p. 9961003 Vol. 69, No. 2 0099-2240/03/$08.00 0 DOI: 10.1128/AEM.69.2.9961003.2003  

E-Print Network (OSTI)

and are regulated by the U.S. Environmental Protection Agency. Of particular concern is the accumulation of VC to ethene is well documented in microcosms, laboratory cul- tures, and bioreactors, the nature analysis. Chloroethenes were measured with a Hewlett-Packard model 6890 gas chromatograph equipped

Löffler, Frank E.

438

Biological conversion of synthesis gas culture development  

DOE Green Energy (OSTI)

Research continues on the conversion of synthesis by shift reactions involving bacteria. Topics discussed here include: biological water gas shift, sulfur gas utilization, experimental screening procedures, water gas shift studies, H{sub 2}S removal studies, COS degradation by selected CO-utilizing bacteria, and indirect COS utilization by Chlorobia. (VC)

Klasson, K.T.; Basu, R.; Johnson, E.R.; Clausen, E.C.; Gaddy, J.L.

1992-03-01T23:59:59.000Z

439

Healy clean coal project. Quarterly technical progress report No. 5, January--March 1992  

SciTech Connect

The objective of the Healy Clean Coal Project is to demonstrate the integration of an advanced combustor and heat recovery system with both high and low temperature emission control processes. The emission levels of SO{sub 2}, NO{sub x}, and particulates are expected to be significantly better then the federal New Source Performance Standards. (VC)

Not Available

1992-05-01T23:59:59.000Z

440

Healy clean coal project  

Science Conference Proceedings (OSTI)

The objective of the Healy Clean Coal Project is to demonstrate the integration of an advanced combustor and heat recovery system with both high and low temperature emission control processes. The emission levels of SO{sub 2}, NO{sub x}, and particulates are expected to be significantly better then the federal New Source Performance Standards. (VC)

Not Available

1992-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Importance of excitonic effects and the question of internal electric fields in stacking faults and crystal phase quantum discs: The model-case of GaN  

E-Print Network (OSTI)

ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi ðze #2; zhÞ2 þ q2 q ) Uex ¼ EexUex; ð1Þ a)Electronic mail: pmc53@cam.ac.uk. 0021-8979/2012/112(5)/053512/5/$30.00 VC 2012 American Institute of Physics112, 053512-1 JOURNAL OF APPLIED PHYSICS 112, 053512 (2012) where ze, zh, and q¼qe#2;qh...

Corfdir, Pierre; Lefebvre, Pierre

2012-01-01T23:59:59.000Z

442

Role of the dielectric mismatch on the properties of donors in semiconductor nanostructures bounded by air  

E-Print Network (OSTI)

: pmc53@cam.ac.uk. 0021-8979/2012/112(10)/106104/3/$30.00 VC 2012 American Institute of Physics112, 106104-1 JOURNAL OF APPLIED PHYSICS 112, 106104 (2012) we obtain a one-dimensional second order differential equa- tion for fe #2; #3;h 2 2me d2feðzeÞ dze...

Corfdir, Pierre; Lefebvre, Pierre

2012-01-01T23:59:59.000Z

443

The Severi problem for rational curves on del Pezzo surfaces  

E-Print Network (OSTI)

Let X be a smooth projective surface and choose a curve C on X. Let VC be the set of all irreducible divisors on X linearly equivalent to C whose normalization is a rational curve. The Severi problem for rational curves ...

Testa, Damiano

2005-01-01T23:59:59.000Z

444

Augmented reality as means for creating shared understanding  

Science Conference Proceedings (OSTI)

The motivation for the work presented in this paper comes primarily from user experience of video-conferencing (v-c) settings in real-life collaboration. The design issues in this context focus on making such settings interactive enough to support natural ... Keywords: common ground, communication, communicative function, deictic reference, interface design, pointing, remote collaboration, shared understanding, videoconferencing

Mirja Lievonen; Duska Rosenberg; Ralf Dörner; Guido Kühn; Swen Walkowski

2009-09-01T23:59:59.000Z

445

A proposed plan for an Advanced Turbine Systems Program  

Science Conference Proceedings (OSTI)

The objective of the advanced turbine systems development program is to develop ultra-high efficiency, environmentally-superior, and cost-competitive gas turbine systems for base-load application in the utility, independent power producer (IPP), and industrial markets. (VC)

Bajura, R.A.; Webb, H.A. Jr.; Parsons, E.L. Jr.

1992-04-01T23:59:59.000Z

446

A proposed plan for an Advanced Turbine Systems Program  

Science Conference Proceedings (OSTI)

The objective of the advanced turbine systems development program is to develop ultra-high efficiency, environmentally-superior, and cost-competitive gas turbine systems for base-load application in the utility, independent power producer (IPP), and industrial markets. (VC)

Bajura, R.A.; Webb, H.A. Jr.; Parsons, E.L. Jr.

1992-01-01T23:59:59.000Z

447

passagerpp.dvi  

NLE Websites -- All DOE Office Websites (Extended Search)

mass MeVc 2 E Incident particle energy Mc 2 MeV T Kinetic energy MeV m e c 2 Electron mass c 2 0.510 998 902(21) MeV r e Classical electron radius 2.817 940 285(31) fm...

448

Refining the M_BH-V_c scaling relation with HI rotation curves of water megamaser galaxies  

E-Print Network (OSTI)

Black hole - galaxy scaling relations provide information about the coevolution of supermassive black holes and their host galaxies. We compare the black hole mass - circular velocity (MBH - Vc) relation with the black hole mass - bulge stellar velocity dispersion (MBH - sigma) relation, to see whether the scaling relations can passively emerge from a large number of mergers, or require a physical mechanism, such as feedback from an active nucleus. We present VLA H I observations of five galaxies, including three water megamaser galaxies, to measure the circular velocity. Using twenty-two galaxies with dynamical MBH measurements and Vc measurements extending to large radius, our best-fit MBH - Vc relation, log MBH = alpha + beta log(Vc /200 km s^-1), yields alpha = 7.43+/-0.13, beta = 3.68+1.23/-1.20, and intrinsic scatter epsilon_int = 0.51+0.11/-0.09. The intrinsic scatter may well be higher than 0.51, as we take great care to ascribe conservatively large observational errors. We find comparable scatter in ...

Sun, Ai-Lei; Impellizzeri, C M Violette; Kuo, Cheng-Yu; Braatz, James A; Tuttle, Sarah

2013-01-01T23:59:59.000Z

449

State energy price projections for the residential sector, 1991--1992  

Science Conference Proceedings (OSTI)

The purpose of this report is to provide projections of State-level residential prices for 1991 and 1992 for the following fuels: electricity, natural gas, heating oil, liquefied petroleum gas (LPG), kerosene, and coal. Prices for 1990 are also included for comparison purposes. This report also explains the methodology used to produce these estimates and the limitations. (VC)

Not Available

1991-11-08T23:59:59.000Z

450

Development of alternative oxygen production source using a zirconia solid electrolyte membrane  

SciTech Connect

The objective of this multiyear effort was the development, fabrication and testing of a zirconia oxygen production module capable of delivering approximately 100 liters/minute (LPM) of oxygen. The work discussed in this report consists of development and improvement of the zirconia cell along with manufacture of cell components, preliminary design of the final plant, additional economic analysis and industrial participation. (VC)

Suitor, J.W.; Clark, D.J.; Losey, R.W.

1990-08-01T23:59:59.000Z

451

Development of alternative oxygen production source using a zirconia solid electrolyte membrane. Final report  

SciTech Connect

The objective of this multiyear effort was the development, fabrication and testing of a zirconia oxygen production module capable of delivering approximately 100 liters/minute (LPM) of oxygen. The work discussed in this report consists of development and improvement of the zirconia cell along with manufacture of cell components, preliminary design of the final plant, additional economic analysis and industrial participation. (VC)

Suitor, J.W.; Clark, D.J.; Losey, R.W.

1990-08-01T23:59:59.000Z

452

Learning with Queries Corrupted by Classification Noise  

E-Print Network (OSTI)

is to get a -admissible value of PGf by an average ESGf over a finite sample S of size m, large enough so-dimension q [19]. Assume the VC dimension of is at most d. Then (2.2) Pm {|ESGf - PG(x, f(x))|

Jackson, Jeffrey

453

AUTOMATIC SCENE RELIGHTING FOR VIDEO CONFERENCING Stephen Mangiat and Jerry Gibson  

E-Print Network (OSTI)

AUTOMATIC SCENE RELIGHTING FOR VIDEO CONFERENCING Stephen Mangiat and Jerry Gibson Electrical by learning the pho- tometric mapping between a lower exposure and desired ex- posure created using High video conferencing (VC) usage has risen dramati- cally in recent years, widespread adoption is still

Liebling, Michael

454

Transition-metal chromophore as a new, sensitive spectroscopic tag for proteins. Selective covalent labeling of histidine residues in cytochromes c with chloro(2,2':6',2''-terpyridine)platinum(II) chloride  

SciTech Connect

Reactivity and selectivity of Pt(trpy)Cl/sup +/ toward proteins are studied with cytochromes c from horse and tuna as examples. The new transition-metal reagent is specific for histidine residues at pH 5. The reaction, facile one-step displacement of the Cl/sup -/ ligand by imidazole, produces good yield. The binding sites, His 26 and His 33 in the horse protein and His 26 in the tuna protein, are identified by UV-vis spectrophotometry and by peptide-mapping experiments. Model complexes with imidazole, histidine, histidine derivatives, and histidine-containing peptides are prepared and characterized. The covalently attached Pt(trpy)/sup 2 +/ labels allow easy separation of the protein derivatives by cation-exchange chromatography. The labels do not perturb the conformation and reduction potential of cytochrome c, as shown by UV-vis spectrophotometry, cyclic voltammetry, differential-pulse voltammetry, EPR spectroscopy, and /sup 1/H NMR spectroscopy. The selectivity of Pt(trpy)Cl/sup +/ is entirely opposite from that of PtCl/sub 4//sup 2 -/ although both of them are platinum(II)-chloro complexes. Owing to an interplay between the steric and electronic effects of the terpyridyl ligand, the new reagent is unreactive toward methionine (a thio ether) and cystine (a disulfide), which are otherwise highly nucleophilic ligands, but very reactive toward imidazole, which is otherwise a relatively weak ligand. Unusual and useful selectivity of preformed transition-metal complexes toward proteins evidently can be achieved by a judicious choice of ancillary ligands.

Ratilla, E.M.A.; Brothers, H.M. II; Kostic, N.M.

1987-07-22T23:59:59.000Z

455

Mercury Measurements Characterizing the Impact of SCR on Mercury: Consol Test Site 3 - Eastern Bituminous Coal-Fired Power Plant Wit h an SCR, ESP, and Wet FGD; Impact of Chloride Addition  

Science Conference Proceedings (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP) - wet flue gas desulfurization (FGD) combination or a spray dyer absorber - fabric filter (SDA-FF) combination. In this program CONSOL is determining mer...

2006-04-26T23:59:59.000Z

456

PERFORMANCE OF LIQUI-CEL EXTRA-FLOW MEMBRANE CONTRACTOR IN A PURE WATER AND IN A 0.2% SODIUM CHLORIDE SOLUTION (SNO-STR-2001-11).  

SciTech Connect

After completion of SNO's first phase measurement of the neutrino charge current, two tons of salt were added into the SNO heavy water to increase the sensitivity of the neutral current measurement (Phase II). Liqui-Cel Extra-Flow Membrane Contactors (simply called Liqui-Cel) are used in the SNO heavy-water circulating system to remove the dissolved gases, such as oxygen, nitrogen, radon, and water vapor from the liquid water. One possible scenario with phase II operation is that the salt may leak through the Liqui-Cel Membrane and come in contact with the vacuum pumps and other metal components of the Heavy-Water Vapor Recovery System. In this scenario, corrosion will damage these components, especially the vacuum pump (Pfeiffer UniDry Pump with cast iron interior), and increase the operational difficulties. A series of tests for the behavior of the Liqui-Cel System in pure water and in salt systems was conducted at the Brookhaven National Laboratory in order to measure the transfer of (a) water vapor and (b) salt, if there is any, through the membrane. Initially a 10-inch by 28-inch Liqui-Cel unit, identical to those used in the SNO heavy-water circulating system, was obtained from SNO site. However, extensive analysis showed that the membrane in this unit was defective: a replacement membrane would cost several thousand dollars. Instead, a smaller, 2.5-inch x 8-inch Liqui-Cel, obtained from Dr. Richard Helmers of the University of British Columbia, was used in this experiment. A comparison of the present experiment with the SNO heavy-water system is done with theoretical calculations. The results are discussed in the following sections.

YEH,M.; BOGER,J.; HAHN,R.L.

2001-11-05T23:59:59.000Z

457

Determining the CH{sub 3}SO{sub 2}{yields}CH{sub 3}+SO{sub 2} barrier from methylsulfonyl chloride photodissociation at 193 nm using velocity map imaging  

Science Conference Proceedings (OSTI)

These imaging experiments study the formation of the methylsulfonyl radical, CH{sub 3}SO{sub 2}, from the photodissociation of CH{sub 3}SO{sub 2}Cl at 193 nm and determine the energetic barrier for the radical's subsequent dissociation to CH{sub 3}+SO{sub 2}. We first state-selectively detect the angular and recoil velocity distributions of the Cl({sup 2}P{sub 3/2}) and Cl({sup 2}P{sub 1/2}) atoms to further refine the distribution of internal energy partitioned to the momentum-matched CH{sub 3}SO{sub 2} radicals. The internal energy distribution of the radicals is bimodal, indicating that CH{sub 3}SO{sub 2} is formed in both the ground state and low-lying excited electronic states. All electronically excited CH{sub 3}SO{sub 2} radicals dissociate, while those formed in the ground electronic state have an internal energy distribution which spans the dissociation barrier to CH{sub 3}+SO{sub 2}. We detect the recoil velocities of the energetically stable methylsulfonyl radicals with 118 nm photoionization. Comparison of the total recoil translational energy distribution for all radicals to the distribution obtained from the detection of stable radicals yields an onset for dissociation at a translational energy of 70{+-}2 kcal/mol. This onset allows us to derive a CH{sub 3}SO{sub 2}{yields}CH{sub 3}+SO{sub 2} barrier height of 14{+-}2 kcal/mol; this determination relies on the S-Cl bond dissociation energy, taken here as the CCSD(T) predicted energy of 65.6 kcal/mol. With 118 nm photoionization, we also detect the velocity distribution of the CH{sub 3} radicals produced in this experiment. Using the velocity distributions of the SO{sub 2} products from the dissociation of CH{sub 3}SO{sub 2} to CH{sub 3}+SO{sub 2} presented in the following paper, we show that our fastest detected methyl radicals are not from these radical dissociation channels, but rather from a primary S-CH{sub 3} bond photofission channel in CH{sub 3}SO{sub 2}Cl. We also present critical points on the ground state potential energy surface of CH{sub 3}SO{sub 2} at the //CCSD(T)/aug-cc-pV(Q+d)ZCCSD(T)/6-311++G(2df,p) level. We include harmonic zero-point vibrational corrections as well as core-valence and scalar-relativistic corrections. The CCSD(T) predicted barrier of 14.6 kcal/mol for CH{sub 3}SO{sub 2}{yields}CH{sub 3}+SO{sub 2} agrees well with our experimental measurement. These results allow us to predict the unimolecular dissociation kinetics of CH{sub 3}SO{sub 2} radicals and critique the analysis of prior time-resolved photoionization studies on this system.

Ratliff, Britni J.; Tang Xiaonan; Butler, Laurie J. [Department of Chemistry and James Franck Institute, University of Chicago, Chicago, Illinois 60637 (United States); Szpunar, David E. [Department of Biological, Chemical, and Physical Sciences, Roosevelt University, Schaumburg, Illinois 60173 (United States); Lau, Kai-Chung [Department of Biology and Chemistry, City University of Hong Kong (Hong Kong)

2009-07-28T23:59:59.000Z

458

The hydration of reactive cement-in-polymer dispersions studied by nuclear magnetic resonance  

Science Conference Proceedings (OSTI)

The behaviour of two novel cement-in-polymer (c/p) dispersions, namely cement-in-poly(vinyl acetate) and cement-in-poly(vinyl alcohol) upon exposure to water at room temperature was investigated by a combination of various NMR methods. The swelling, cracking, and the water ingress were monitored non-destructively using {sup 1}H single point imaging. The hydration of the cement matrix was investigated using {sup 29}Si NMR whilst {sup 13}C CPMAS NMR spectra allowed the quantification of the kinetics of the hydrolysis reaction of poly(vinyl acetate) into poly(vinyl alcohol). The polymer controls the rate of water ingress and swelling which in turn determines the behaviour of the c/p dispersions upon exposure to water. For the cement-in-poly(vinyl alcohol), the rates of water ingress and swelling are much faster than the hydration of the clinker whilst for the cement-in-poly(vinyl acetate) the slow rates of the two processes allow the formation of a cementious matrix which assures the stability of the sample.

Olaru, A.M. [Institut fuer Technische und Makromolekulare Chemie, RWTH Aachen University, Templergraben 55, 52056 Aachen (Germany); Weichold, O. [DWI an der RWTH Aachen, e. V., Pauwelsstrasse 8, 52056 Aachen (Germany); Adams, A., E-mail: aadams@mc.rwth-aachen.de [Institut fuer Technische und Makromolekulare Chemie, RWTH Aachen University, Templergraben 55, 52056 Aachen (Germany)

2011-11-15T23:59:59.000Z

459

Experimental co-digestion of corn stalk and vermicompost to improve biogas production  

SciTech Connect

Anaerobic co-digestion of corn stalk and vermicompost (VC) as well as mono-digestion of corn stalk were investigated. Batch mono-digestion experiments were performed at 35 {+-} 1 {sup o}C and initial total solid loading (TSL) ranged from 1.2% to 6.0%. Batch co-digestion experiments were performed at 35 {+-} 1 {sup o}C and initial TSL of 6% with VC proportions ranged from 20% to 80% of total solid (TS). For mono-digestion of corn stalk, a maximum methane yield of 217.60 {+-} 13.87 mL/g TS{sub added} was obtained at initial TSL of 4.8%, and acidification was found at initial TSL of 6.0% with the lowest pH value of 5.10 on day 4. Co-digestion improved the methane yields by 4.42-58.61% via enhancing volatile fatty acids (VFAs) concentration and pH value compared with mono-digestion of corn stalk. The maximum biogas yield of 410.30 {+-} 11.01 mL/g TS{sub added} and methane yield of 259.35 {+-} 13.85 mL/g TS{sub added} were obtained for 40% VC addition. Structure analysis by X-ray diffractometry (XRD) showed that the lowest crystallinity of 35.04 of digested corn stalk was obtained from co-digestion with 40% VC, which decreased 29.4% compared to 49.6 obtained from un-treated corn stalk. It is concluded that co-digestion with VC is beneficial for improving biodigestibility and methane yield from corn stalk.

Chen Guangyin [State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093 (China); Zheng Zheng, E-mail: zzhenghj@fudan.edu.c [State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093 (China); Department of Environmental Science and Engineering, Fudan University, Shanghai 200433 (China); Yang Shiguan [National Engineering Laboratory of Biomass Power Generation Equipment, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China); Fang Caixia; Zou Xingxing; Luo Yan [State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093 (China)

2010-10-15T23:59:59.000Z

460

Caldera processes and magma-hydrothermal systems continental scientific drilling program: thermal regimes, Valles caldera research, scientific and management plan  

DOE Green Energy (OSTI)

Long-range core-drilling operations and initial scientific investigations are described for four sites in the Valles caldera, New Mexico. The plan concentrates on the period 1986 to 1993 and has six primary objectives: (1) study the origin, evolution, physical/chemical dynamics of the vapor-dominated portion of the Valles geothermal system; (2) investigate the characteristics of caldera fill and mechanisms of caldera collapse and resurgence; (3) determine the physical/chemical conditions in the heat transfer zone between crystallizing plutons and the hydrothermal system; (4) study the mechanism of ore deposition in the caldera environment; (5) develop and test high-temperature drilling techniques and logging tools; and (6) evaluate the geothermal resource within a large silicic caldera. Core holes VC-2a (500 m) and VC-2b (2000 m) are planned in the Sulphur Springs area; these core holes will probe the vapor-dominated zone, the underlying hot-water-dominated zone, the boiling interface and probable ore deposition between the two zones, and the deep structure and stratigraphy along the western part of the Valles caldera fracture zone and resurgent dome. Core hole VC-3 will involve reopening existing well Baca number12 and deepening it from 3.2 km (present total depth) to 5.5 km, this core hole will penetrate the deep-crystallized silicic pluton, investigate conductive heat transfer in that zone, and study the evolution of the central resurgent dome. Core hole VC-4 is designed to penetrate deep into the presumably thick caldera fill in eastern Valles caldera and examine the relationship between caldera formation, sedimentation, tectonics, and volcanism. Core hole VC-5 is to test structure, stratigraphy, and magmatic evolution of pre-Valles caldera rocks, their relations to Valles caldera, and the influences of regional structure on volcanism and caldera formation.

Goff, F.; Nielson, D.L. (eds.)

1986-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

A Study of Advanced Materials for Gas Turbine Coatings at Elevated Temperatures Using Selected Microstructures and Characteristic Environments for Syngas Combustion  

DOE Green Energy (OSTI)

Thermal barrier coatings (TBCs) that can be suitable for use in industrial gas turbine engines have been processed and compared with electron beam physical vapor deposition (EBPVD) microstructures for applications in advanced gas turbines that use coal-derived synthesis gas. Thermo-physical properties have been evaluated of the processed air plasma sprayed TBCs with standard APS-STD and vertically cracked APS-VC coatings samples up to 1300 C. Porosity of these selected coatings with related microstructural effects have been analyzed in this study. Wet and dry thermal cycling studies at 1125 C and spalling resistance thermal cycling studies to 1200 C have also been carried out. Type I and Type II hot corrosion tests were carried out to investigate the effects of microstructure variations and additions of alumina in YSZ top coats in multi-layered TBC structures. The thermal modeling of turbine blade has also been carried out that gives the capability to predict in-service performance temperature gradients. In addition to isothermal high temperature oxidation kinetics analysis in YSZ thermal barrier coatings of NiCoCrAlY bond coats with 0.25% Hf. This can affect the failure behavior depending on the control of the thermally grown oxide (TGO) growth at the interface. The TGO growth kinetics is seen to be parabolic and the activation energies correspond to interfacial growth kinetics that is controlled by the diffusion of O{sub 2} in Al{sub 2}O{sub 3}. The difference between oxidation behavior of the VC and STD structures are attributed to the effects of microstructure morphology and porosity on oxygen ingression into the zirconia and TGO layers. The isothermal oxidation resistance of the STD and VC microstructures is similar at temperatures up to 1200 C. However, the generally thicker TGO layer thicknesses and the slightly faster oxidation rates in the VC microstructures are attributed to the increased ingression of oxygen through the grain boundaries of the vertically cracked microstructures. The plasma sprayed TBC microstructure (VC and STD) with NiCoCrAlY-Hf bond coat are stable up to 1100 C. However, as with other TBC structures, a considerable amount of interdiffusion was observed in the different layers, although the TBC growth was self-limiting and parabolic. The addition of Hf to the VC microstructure appears to have some potential for the future development of robust TBCs with improved isothermal and service temperatures in advanced gas turbines.

Ravinder Diwan; Patrick Mensah; Guoqiang Li; Nalini Uppu; Strphen Akwaboa; Monica Silva; Ebubekir Beyazoglu; Ogad Agu; Naresh Polasa; Lawrence Bazille; Douglas Wolfe; Purush Sahoo

2011-02-10T23:59:59.000Z

462

Aging Studies of VCE Dismantlement Returns  

Science Conference Proceedings (OSTI)

VCE is an ethylene/vinyl acetate/vinyl alcohol terpolymer binder for filled elastomers which is designed to accept high filler loadings. Filled elastomer parts consist of the binder (VCE), a curing agent (Hylene MP, diphenol-4-4{prime}-methylenebis(phenylcarbamate)), a processing aid (LS, lithium stearate), and filler particles (typically 70% fraction by weight). The curing of the filled elastomer parts occurs from the heat-activated reaction between the hydroxyl groups of VCE with the Hylene MP curing agent, resulting in a cross-linked network. The final vinyl acetate content is typically between 34.9 and 37.9%, while the vinyl alcohol content is typically between 1.27 and 1.78%. Surveillance data for this material is both scarce and scattered, complicating the assessment of any aging trends in systems. In addition, most of the initial surveillance efforts focused on mechanical properties such as hardness and tensile strength, and chemical information is therefore lacking. Material characterization and aging studies had been performed on previous formulations of the VCE material but the Ethylene Vinyl Acetate (EVA) starting copolymer is no longer commercially available. New formulations with replacement EVA materials are currently being established and will require characterization as well as updated aging models.

Letant, S; Alviso, C; Pearson, M; Albo, R; Small, W; Wilson, T; Chinn, S; Maxwell, R

2011-10-17T23:59:59.000Z

463

Studies on the Effects of Inorganic Salts on Biochemical Treatment ...  

Science Conference Proceedings (OSTI)

Effects of two inorganic salts (sodium chloride and sodium sulphate) on biochemical ... Numerical Investigation of Heat Transfer Characteristics in Microwave ...

464

Current Efficiency Predictive Model and Its Calibration and Validation  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

465

Modelling  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

466

Latest Results from PFC Investigation in China  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

467

Anodic Electrochemical Behavior in Low Alumina Concentration ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

468

Electrolytic Cell Gas Cooling Upstream of Treatment Center  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

469

Current Distribution and Lorentz Field Modelling Using Cathode ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

470

Busbar Displacement Study of Aluminum Reduction Cell  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

471

DX+, An Optimized Version of DX Technology  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

472

Impacts of Anode Set on the Energy Re-distribution of PB Aluminum ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

473

Pot-Shell Exfoliation behind SiC Sidewall Block in a Cathode of ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

474

Numerical Simulation on Coupled Multi-field of the Perforated ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

475

Impurity Elements in Raw Gas Ultra-Fines from Aluminum ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

476

Specific Molecular Features of Potassium-Containing Cryolite Melts  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

477

Method for Testing Thermal Properties of Reduction Cell Materials  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

478

Visualising the Sources of Potroom Dust in Aluminium Smelters  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

479

Operating Parameters of Aluminum Electrolysis in a KF-AlF 3 Based ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

480

The Restart of Two Idled Pot Lines at Ormet Primary Aluminum  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

AP40  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

482

Prebake Potline Restart after Power Supply Interruption  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

483

About this Abstract  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

484

Building and Fire Publications  

Science Conference Proceedings (OSTI)

... Solar Energy Materials, Vol. ... Carino, NJ; Clifton, JR; Prototype Computer- Integrated Knowledge System: Predicting Service Life of Chloride-Exposed ...

485

Electromagnetic and MHD Study to Improve Cell Performance of an ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

486

Air Amplified Boosted Suction (AABS) System for Pot Flow Control ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

487

Virtual Pot Simulator for aluminum smelting  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

488

Applying Nano Technology to Remove Toxic Sulfur Gases ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

489

Statistical Method to Predict Anode Effect Events  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

490

Two-Phase 3D Model of Reduction Cell  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

491

Thermo-Electro-Mechanical Investigation of Voltage Drop on Anode ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

492

CFD Simulation of Anode Bubble Behavior in Aluminum Reduction ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

493

Liquidus Temperatures of the System Na  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

494

The Study and Applications of Modern Potline Fume Treatment Plant ...  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

495

Behavior Estimation and Control of Aluminum Reduction Cell  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

496

Update on the Development of D18 Cell Technology at Dubal  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

497

Studies of Perfluorocarbon Formation on Anodes in Cryolite Melts  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

498

Optimization of the Thermal Management in Aluminum Smelting Pot  

Science Conference Proceedings (OSTI)

Cryoscopic Data for Hall-Héroult Bath Containing Magnesium Fluoride, Calcium Fluoride, Potassium Cryolite, and Sodium Chloride · Current Distribution and ...

499

DEVELOPMENTS IN AND IMPLEMENTATION OF GAS ...  

Science Conference Proceedings (OSTI)

... fire suppression mechanism (dilution, cooling, and strain ... oxidizers, such as potassium nitrate or potassium ... like coininon table salt, sodium chloride ...

2011-11-01T23:59:59.000Z

500

METHOD OF SEPARATING URANIUM VALUES, PLUTONIUM VALUES AND FISSION PRODUCTS BY CHLORINATION  

DOE Patents (OSTI)

The separation of plutonium and uranium from each other and from other substances is described. In general, the method comprises the steps of contacting the uranium with chlorine in the presence of a holdback material selected from the group consisting of lanthanum oxide and thorium oxide to form a uranium chloride higher than uranium tetrachloride, and thereafter heating the uranium chloride thus formed to a temperature at which the uranium chloride is volatilized off but below the volatilizalion temperature of plutonium chloride.

Brown, H.S.; Seaborg, G.T.

1959-02-24T23:59:59.000Z