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Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Copolymerization Studies of Vinyl Chloride and Vinyl Acetate with Ethylene Using a Transition-Metal Catalyst  

E-Print Network [OSTI]

monomers with polar functionality (such as vinyl acetate (VA), vinyl chloride (VC), and acrylates).1 OverCopolymerization Studies of Vinyl Chloride and Vinyl Acetate with Ethylene Using a Transition-Flory constants were identical (0.81) for the ethylene homopolymerizations and the ethylene/vinyl chloride

Goddard III, William A.

2

Reduction of Vinyl Chloride in Metallic Iron-Water Systems  

E-Print Network [OSTI]

residence time for contaminated ground- water to degrade VC to below its maximum contamination levelReduction of Vinyl Chloride in Metallic Iron-Water Systems B A O L I N D E N G * Department). Remediation of groundwater contaminated with chlori- nated ethylenes, including vinyl chloride, has been chal

Deng, Baolin

3

Degradation of Vinyl Chloride and 1,2-Dichloroethane by Advanced Reduction Processes  

E-Print Network [OSTI]

A new treatment technology, called Advanced Reduction Process (ARP), was developed by combining UV irradiation with reducing reagents to produce highly reactive species that degrade contaminants rapidly. Vinyl chloride (VC) and 1,2-dichloroethane (1...

Liu, Xu

2013-07-27T23:59:59.000Z

4

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents [OSTI]

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M [Stanford, CA; Muller, Jochen A [Baltimore, MD; Rosner, Bettina M [Berlin, DE; Von Abendroth, Gregory [Mannheim, DE; Meshulam-Simon, Galit [Los Angeles, CA; McCarty, Perry L [Stanford, CA

2014-02-11T23:59:59.000Z

5

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents [OSTI]

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M. (Stanford, CA); Muller, Jochen A. (Baltimore, MD); Rosner, Bettina M. (Berlin, DE); Von Abendroth, Gregory (Nannhein, DE); Meshulam-Simon, Galit (Los Altos, CA); McCarty, Perry L (Stanford, CA)

2011-11-22T23:59:59.000Z

6

Genome Sequence of the Ethene- and Vinyl Chloride-Oxidizing Actinomycete Nocardioides sp Strain JS614  

SciTech Connect (OSTI)

Nocardioides sp. strain JS614 grows on ethene and vinyl chloride (VC) as sole carbon and energy sources and is of interest for bioremediation and biocatalysis. Sequencing of the complete genome of JS614 provides insight into the genetic basis of alkene oxidation, supports ongoing research into the physiology and biochemistry of growth on ethene and VC, and provides biomarkers to facilitate detection of VC/ethene oxidizers in the environment. This is the first genome sequence from the genus Nocardioides and the first genome of a VC/ethene-oxidizing bacterium.

Coleman, Nicholas V [University of Sydney, Australia; Wilson, Neil L [University of Sydney, Australia; Barry, Kerrie [U.S. Department of Energy, Joint Genome Institute; Bruce, David [Los Alamos National Laboratory (LANL); Copeland, A [U.S. Department of Energy, Joint Genome Institute; Dalin, Eileen [U.S. Department of Energy, Joint Genome Institute; Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Glavina Del Rio, Tijana [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Hammon, Nancy [U.S. Department of Energy, Joint Genome Institute; Han, Shunsheng [Los Alamos National Laboratory (LANL); Hauser, Loren John [ORNL; Israni, Sanjay [U.S. Department of Energy, Joint Genome Institute; Kim, Edwin [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Lapidus, Alla L. [U.S. Department of Energy, Joint Genome Institute; Larimer, Frank W [ORNL; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Richardson, Paul [U.S. Department of Energy, Joint Genome Institute; Schmutz, Jeremy [Stanford University; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Thompson, Sue [Los Alamos National Laboratory (LANL); Tice, Hope [U.S. Department of Energy, Joint Genome Institute; Spain, Jim C [Georgia Institute of Technology; Gossett, James G [Cornell University; Mattes, Timothy E [University of Iowa

2011-01-01T23:59:59.000Z

7

Reactor-chromatographic determination of vinyl chloride in polyvinyl chloride  

SciTech Connect (OSTI)

The authors carry out a chromatographic study of the volatile products that evolve when various grades of domestic polyvinyl chloride are heated, to determine the concentration of residual monomer. To find vinyl chloride in complex mixtures of air pollutants the authors used sorptive reaction concentration of impurities. This new combination of methods is based on preliminary separation at the sampling stage of impurities that interfere in the analysis, followed by concentration of the desired components in a trap with an adsorbent, and chromatographic determination of the concentrated trace materials. The method obtains low vinyl chloride concentrations (down to 10/sup -4/-10/sup -5/ wt. %) with +/-5 relative error.

Berezkin, V.G.

1986-08-01T23:59:59.000Z

8

VINYL CHLORIDE ACUTE TOXICITY THRESHOLDS IN THE CONTEXT OF CONTROLLING  

E-Print Network [OSTI]

. The "irreversible effects threshold" is the maximum concentration of pollutant in the air for a given exposure timeVINYL CHLORIDE ACUTE TOXICITY THRESHOLDS IN THE CONTEXT OF CONTROLLING URBAN DEVELOPMENT OR LAND of vinyl Chloride , the french procedure to set acute toxicity thresholds in the context of controlling

Boyer, Edmond

9

Study of vinyl chloride formation at landfill sites in California. Final report, 16 July 1985-15 January 1987  

SciTech Connect (OSTI)

The purpose of this study was to determine if vinyl chloride (VC) detected in air above California landfills is produced in situ. Experiments were performed with N and S California landfill samples and anaerobic-digestor sewage sludge. Test materials were incubated with various chlorocarbons and with /sup 13/C-trichloroethylene (TCE) to confirm biological production of /sup 13/C-VC. These experiments confirmed the biological dechlorination of chloroethylenes as the most likely route for VC emission from landfills, rather than chemical or photochemical routes, or PVC degradation. Leaching from PVC could be a minor source of VC, though there was less than 0.1% (estimated) plastic in the landfill samples, containing at most 330 ppm of VC monomer. A landfill sample known to produce VC was used to start an anaerobic chemostat using methanol as sole carbon source. The enriched culture resulting was homogeneous, and when incubated with /sup 13/C-TCE, produced (13)C-VC, confirmed by GC/MS.

Molton, P.M.; Hallen, R.T.; Payne, J.W.

1987-01-01T23:59:59.000Z

10

Reductive Dechlorination of the Vinyl Chloride Surrogate  

E-Print Network [OSTI]

in contaminated groundwater. For this study, E-/Z-chlorofluoroethene (E-/Z-CFE) was evaluated as a surrogate at a TCE-contaminated field site by injecting E-/Z-CFE and monitoring for the formation of fluoroethene (FE) over a period of up to 80 days. The rates for VC transformation to ethene and E-CFE transformation

Semprini, Lewis

11

Why sequence ethene and vinyl chloride-oxidizing Mycobacterium strains?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sequence ethene and vinyl sequence ethene and vinyl chloride-oxidizing Mycobacterium strains? Mycobacteria are known for causing human and animal diseases but they are also important degraders of hard-to-break-down water contaminants such as polyaromatic hydrocarbons (PAHs) and methyl tert-butyl ether (MTBE). So far the handful of bacterial species representing the Mycobacterium genus that have been sequenced all break down PAHs. In this project, researchers focus on the genomes of mycobacterial species isolated from soil, freshwater and marine environments that use the alkene compounds ethene and vinyl chloride as carbon sources. Chlorinated ethene compounds are difficult to remove from contaminated groundwater but necessary because of their toxicity. Additionally these compounds reduce the ozone levels in the atmosphere.

12

Chemical modification of poly(vinyl chloride) with nitrogen nucleophiles assisted by microwave irradiation.  

E-Print Network [OSTI]

??In this work we had performed nucleophilic substitution reactions (Sn2) of some chlorine atoms in commercial samples of poly (vinyl chloride) (PVC), nitrile groups and… (more)

Mauro Vinícius Almeida da Silva

2013-01-01T23:59:59.000Z

13

Vinyl chloride monomer and other contaminants in PVC welding fumes  

SciTech Connect (OSTI)

An investigation into the nature of fumes produced during thermal welding of plasticized PVC sheeting has been carried out with the objective of determining if the known carcinogen vinyl chloride monomer (VCM) is formed and to assess the level of exposure to the operator. The results show that the atmospheric concentrations of VCM are well below accepted occupational exposure limits. This finding is consistent with reports in the technical literature which suggest that VCM is produced during thermal degradation of PVC only at temperatures considerably higher than those encountered during plastic welding.

Williamson, J.; Kavanagh, B.

1987-05-01T23:59:59.000Z

14

Cohort and case-control analyses of workers exposed to vinyl chloride: An update  

SciTech Connect (OSTI)

The mortality in a cohort of workers at a vinyl chloride polymerization plant has been updated, extending the period of observation in the original study from 1974 to 1986. Workers at this plant may have been exposed to vinyl chloride monomer and/or polyvinyl chloride dust, or may have had no exposure to either substance. Seventy-six percent of the work force worked in jobs with potential exposure to vinyl chloride monomer. Among the total cohort, statistically significant excess risks were observed for liver, lung, and brain cancer. For the subcohort of workers exposed to vinyl chloride monomer, the standardized mortality ratio (SMR) for liver cancer was 333 (90% confidence interval (CI) 202 to 521). However, there were no significant excesses of either brain (SMR = 145, 90% CI 78 to 249) or lung cancer (SMR = 115, 90% CI 96 to 141). To investigate dose response, nested case-control studies for liver, brain, and lung cancer were conducted among the total cohort (including the nonexposed). For these studies there were two exposure variables, cumulative dose of vinyl chloride monomer and cumulative dose of polyvinyl chloride dust. Cumulative dose was defined as the product of level and duration of exposure. The only significant association between disease risk and cumulative dose was for liver cancer and cumulative dose of vinyl chloride monomer. Further division of the liver cancers into angiosarcoma (n = 12) and other liver cancers (n = 7), based on review of death certificates and medical records, showed that the dose response existed only for angiosarcomas.

Wu, W.A.; Steenland, K.; Brown, D.; Wells, V.; Jones, J.; Schulte, P.; Halperin, W.

1989-06-01T23:59:59.000Z

15

Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures  

E-Print Network [OSTI]

Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures James D. Van de Ven, unpigmented state are highly transmissive of light in the near-infrared range, thus allowing laser of light detection [2, 3]. Within the near-infrared region nat- ural polymers have nearly no absorption [2

Van de Ven, James D.

16

Evaluation of the association between birth defects and exposure to ambient vinyl chloride  

SciTech Connect (OSTI)

Birth defects incidence for infants born to residents of Shawinigan, Canada in 1966-1979 were significantly higher than in three comparison communities. Since there has been a vinyl chloride polymerization plant in this town since 1943 from which ten cases of angiosarcoma of the liver have been identified, this study explores the possible association between exposure to vinyl chloride monomer (VCM) in ambient air and the occurrence of birth defects in the community. The excess of birth defects fluctuated seasonally in a way that corresponded to changes in VCM concentration in the environment. Mothers who gave birth to malformed children were younger on average in Shawinigan than in the comparison communities. However, there was no excess of still-births in Shawinigan. The excess in birth defects involved most organ systems, and variation in birth-defect rates among school districts could not be accounted for by estimates of VCM in the atmosphere. The occupational and residential histories of parents who gave birth to malformed infants were compared with those of parents of normal infants. The two groups did not differ in occupational exposure or closeness of residence to the vinyl chloride polymerization plant. Some descriptive data from this study raised the hypothesis of an association between VCM in the air and birth defects in the exposed community, but as a whole, within the sample size available, such an association could not be substantiated.

Theriault, G.; Iturra, H.; Gingras, S.

1983-06-01T23:59:59.000Z

17

Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride  

SciTech Connect (OSTI)

Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

1995-12-31T23:59:59.000Z

18

Mortality and cancer morbidity in workers exposed to low levels of vinyl chloride monomer at a polyvinyl chloride processing plant  

SciTech Connect (OSTI)

To study whether exposure to low levels of vinyl chloride monomer (VCM) causes increased risk for cancer morbidity and death from ischemic heart disease, a cohort study was performed among 2,031 male workers at a polyvinyl chloride (PVC) processing plant who had been employed for at least 3 months during the period 1945-1980. An almost significantly increased total mortality (SMR = 116, 95% CI 99-136) was found. Deaths caused by violence or intoxication were significantly increased (SMR = 153, 95% CI 109-213), but not deaths from ischemic heart disease (SMR = 100, 95% CI 73-135). A significant increase in total cancer morbidity was observed (SMR = 128, 95% CI 101-161). Respiratory cancers were significantly increased (SMR = 213, 95% CI 127-346). Furthermore, six brain tumors (vs. 2.6 expected) were observed. This increase, however, was not significant (SMR = 229, 95% CI 84-498). No liver hemangiosarcoma was observed. Applying a latency period of greater than or equal to 10 years from start of employment did not change the risk patterns. There were no significant exposure-response associations between exposure estimates for VCM, asbestos, and plasticizers and cancer morbidity.

Hagmar, L.; Akesson, B.; Nielsen, J.; Andersson, C.; Linden, K.; Attewell, R.; Moeller, T. (University Hospital, Lund (Sweden))

1990-01-01T23:59:59.000Z

19

Osha`s 1974 vinyl chloride standard. Retrospective evaluation of the rulemaking`s feasibility/impact estimates. Case study  

SciTech Connect (OSTI)

This report documents a case study of the Occupational Safety and Health Administration`s (OSHA) permanent health standard of 1974 for workplace exposures to vinyl chloride (monomer). OSHA`s assessment of hazard control options and estimates of compliance costs and other regulatory impacts prepared as part of the rationale for the rulemaking are reviewed and then compared and contrasted with the actual post-promulgation outcomes as affected industries adjusted to the new compliance requirements. This case study has been prepared as part of a larger Office of Technology Assessment (OTA) evaluation of the control technology and regulatory impact analyses that OSHA prepares to support its rulemakings. Congress requested in May 1992 that OTA examine OSHA`s procedures and methods in these regards. The case reported here is one of eight OSHA health and safety standards that have been similarly studied on a pre- and post-promulgation basis.

Boroush, M.A.

1993-11-01T23:59:59.000Z

20

Radiation crosslinking of poly(vinyl chloride) with trimethylolpropanetrimethacrylate. IV. Effect of diundecyl phthalate: dependence of physical properties on composition. [Electron beam ion sources  

SciTech Connect (OSTI)

Blends of poly(vinyl chloride)(PVC) with polyfunctional monomers may be crosslinked by ionizing radiation. The physical properties of PVC blended with trimethylolpropanetrimethacrylate (TMPTMA) and diundecyl phthalate (DUP) were studied. The TMPTMA monomer crosslinked the blend by homopolymerization and/or grafting to PVC. The plasticizer, DUP, was chemically inert under irradiation but, by plasticizing the macromolecules and diluting the monomer, changed the kinetics extensively. Characteristics of the glass transitions and the tensile mechanical properties have been correlated with blend composition and radiation dose. Before irradiation, poly(vinyl chloride) was plasticized by both DUP and TMPTMA monomer. The increase in glass transition temperature and mechanical strength following irradiation to 5 Mrad was correlated with the TMPTMA content of the blend. Both the molecular structure of the network and the DUP content of the blend were factors in determining the physical properties of the final crosslinked blend. The molecular structure was determined by the kinetics of the crosslinking reactions, which in turn were determined by the blend composition. A molecular interpretation consistent with the physical properties, chemical kinetics, and mechanism of the crosslinking system has been presented. 24 figures, 2 tables.

Bowmer, T.N.; Vroom, W.I.

1983-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

The radiation crosslinking of poly(vinyl chloride) with trimethylolpropanetrimethacrylate. III. Effect of diundecyl phthalate: chemical kinetics of a three-component system  

SciTech Connect (OSTI)

The radiation chemistry of poly(vinyl chloride) (PVC) blended with trimethylolpropanetrimethacrylate (TMPTMA) and diundecyl phthalate (DUP) has been examined. This three-component mixture contains a base resin (PVC), a crosslinking sensitizer (TMPTMA), and a physical modifier (DUP). These are the basic components in any radiation-curable coating. The kinetics and mechanism of the crosslinking reactions were studied with reference to the dependence on radiation dose and blend composition. The polyfunctional TMPTMA underwent polymerization incorporating the PVC into a 3-dimensional network. DUP remained chemically inert during the irradiation, not being bound to the network. However, DUP by plasticizing the macromolecules and diluting the monomer, changed the kinetics extensively. DUP enhanced TMPTMA homopolymerization, TMPTMA grafting, and PVC crosslinking reaction rates. The effect of the competition between polymerization, grafting, and degradation reactions was examined in terms of enhanced mobility of the reacting species. The influence of these kinetics considerations in selecting a blend composition for a coating application was discussed.

Bowmer, T.N.; Vroom, W.I.; Hellman, M.Y.

1983-08-01T23:59:59.000Z

22

Chemico-Biological Interactions 166 (2007) 301316 Mortality patterns among industrial workers exposed to  

E-Print Network [OSTI]

of industrial workers exposed to chloroprene (CD) and other substances, including vinyl chloride monomer (VC

Illinois at Chicago, University of

23

primusspring 2010 vol 15 VC 7 reconstruction  

E-Print Network [OSTI]

of Dental Medicine #12;#12;primus2010 1 Contents FROM THE DEAN 3 CHANGES FOR CLINICS: BETTER FOR PATIENTS 4 s spring 2010 vol 15 published annually by the Columbia University College of Dental Medicine #12;To Alumni, radiology and emergency areas on the 7th floor of the Vanderbilt Clinic (VC) building and a complete

Grishok, Alla

24

Acetylene Inhibition of Trichloroethene and Vinyl Chloride  

E-Print Network [OSTI]

and enhanced anaerobic remediation of chloroethenes at contaminated sites. The results also suggest that acetylene produced abiotically by reactions of chlorinated ethenes with zero-valent iron could inhibit water standard (2 µg/L) (3). A variety of biochemical tools have been used to probe the complexity

Semprini, Lewis

25

Preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

Tustin, Gerald Charles (Kingsport, TN); Zoeller, Joseph Robert (Kingsport, TN); Depew, Leslie Sharon (Kingsport, TN)

1998-01-01T23:59:59.000Z

26

Preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

1998-03-24T23:59:59.000Z

27

Altered Tectonic and Hydrothermal Breccias in Corehole VC-1,...  

Open Energy Info (EERE)

we will briefly discuss each of the major deep breccias in VC-l, examine the style, intensity and paragenesis of their hydrothermal alteration, and speculate on their...

28

JOURNAL OF BACTERIOLOGY, Aug. 2009, p. 52245231 Vol. 191, No. 16 0021-9193/09/$08.00 0 doi:10.1128/JB.00085-09  

E-Print Network [OSTI]

in Clostridium kluyveri. Chlorinated organic compounds, such as tetrachloroethene (PCE) and trichloroethene (TCE reductively dechlorinate PCE, TCE, and their daughter compounds di- chloroethene (DCE) and vinyl chloride (VC

Alvarez-Cohen, Lisa

29

E-Print Network 3.0 - acid dehalogenase enzyme Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of halorespi- ration in Desulfitobacterium dehalogenans. J. Biol. Chem... of vinyl chloride (VC) to ethene. Degenerate primers targeting conserved regions in reductive...

30

Inversion versus Retention of Configuration for Nucleophilic Substitution at Vinylic Carbon  

E-Print Network [OSTI]

of Glukhovtsev, Pross, and Radom that the SN2 reaction of Cl- with unactivated vinyl chloride in the gas phase. However, moderately activated dihaloethylenes such as 1-chloro-1-fluoroethylene undergo gas-phase SN2. It is generally assumed that bimolecular SN2 nucleophilic substitution at saturated carbon (sp3) proceeds

Schlegel, H. Bernhard

31

Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts  

E-Print Network [OSTI]

of commercially important materials like vinyl acetate monomer (VAM), cellulose acetate, and acetate esters. MoreAcetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts Yafang Fan Ã? that makes use of the latest advance in methyl chloride production is reported. Acetic acid was produced from

Bao, Xinhe

32

The use and misuse of Vc,max in Earth System Models Alistair Rogers  

E-Print Network [OSTI]

REVIEW The use and misuse of Vc,max in Earth System Models Alistair Rogers Received: 18 November Dordrecht (outside the USA) 2013 Abstract Earth System Models (ESMs) aim to project global change. Central Á Vc,max Á Leaf nitrogen Á Earth System Models Introduction The primary goal of Earth System Models

Rogers, Alistair

33

Rheology of silicon carbide/vinyl ester nanocomposites  

E-Print Network [OSTI]

New York, 1999. SILICON CARBIDE/VINYL ESTER NANOCOMPOSITESRheology of Silicon Carbide/Vinyl Ester NanocompositesABSTRACT: Silicon carbide (SiC) nanoparticles with no

Yong, Virginia; Hahn, H. Thomas

2006-01-01T23:59:59.000Z

34

Low pressure vinylation of aryl and vinyl halides via HeckMizoroki reactions using ethylene  

E-Print Network [OSTI]

Low pressure vinylation of aryl and vinyl halides via Heck­Mizoroki reactions using ethylene Craig with ethylene under ambient pressure (15­30 psi) to give the corresponding vinylarenes. The reactions work of ethylene) of functionalized vinylarenes and 1,3-di- enes.4 When fully developed, we hope, many

RajanBabu, T. V. "Babu"

35

Recycling silver chloride  

Science Journals Connector (OSTI)

Recycling silver chloride ... A simple way to reduce lab cost by recycling silver in the academic lab. ...

Edwin Thall

1981-01-01T23:59:59.000Z

36

Emulsion polymerization of ethylene-vinyl acetate-branched vinyl ester using a pressure reactor system.  

E-Print Network [OSTI]

??A new pressure reactor system was designed to synthesize a novel branched ester-ethylene-vinyl acetate (BEEVA) emulsion polymer. The reactor system was capable of handling pressure… (more)

Tan, Chee Boon

2008-01-01T23:59:59.000Z

37

Process for the preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85.degree. and 200.degree. C. and removing the reaction products from the contact zone.

Tustin, Gerald Charles (Kingsport, TN); Zoeller, Joseph Robert (Kingsport, TN); Depew, Leslie Sharon (Kingsport, TN)

1998-01-01T23:59:59.000Z

38

Process for the preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85 and 200 C and removing the reaction products from the contact zone.

Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

1998-02-17T23:59:59.000Z

39

K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Details Activities (2) Areas (1) Regions (0) Abstract: Seventeen K/Ar dates were obtained on illitic clays within Valles caldera (1.13 Ma) to investigate the impact of hydrothermal alteration on Quaternary to Precambrian intracaldera and pre-caldera rocks in a large,

40

Effects of stereochemistry and ?-substituents on the rates of vinylic SN2 reaction of hypervalent vinyl(phenyl)-?3-iodanes with tetrabutylammonium halides  

Science Journals Connector (OSTI)

Both stereoisomers of ?-(2-phenylethoxy)vinyl-?3-iodane and (Z)-?-aroyloxyvinyl-?3-iodane were prepared stereoselectively. These substituted vinyl-?3-iodanes undergo nucleophilic vinylic substitutions with n-Bu4NX (X=Cl, Br, I) under mild conditions, yielding vinyl halides. The observed inversion of configuration at the ipso vinylic carbon atom is compatible with a concerted vinylic SN2 mechanism. Kinetic measurements indicated that the rates for vinylic SN2 reaction of (Z)-vinyl-?3-iodane are greater than those of the E-isomer, probably because of the higher ground state energy of the Z-isomer. Electronic effects of ?-substituents of vinyl-?3-iodanes in the vinylic SN2 reaction are also discussed.

Kazunori Miyamoto; Takuji Okubo; Masaya Hirobe; Munetaka Kunishima; Masahito Ochiai

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

The impact of improved materials in poly(vinyl chloride)-based endotracheal tubes  

E-Print Network [OSTI]

Endotracheal tubes (ETs) are used to aid artificial ventilation in millions of medical patients every year and are known to invoke the proliferative phase in the cell linings. The technical objective of this work was to ...

Domike, Kristin Rebecca, 1981-

2004-01-01T23:59:59.000Z

42

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

2005) Genome sequence of the PCE-dechlorinating bacteriumlevels and pseudo-steady-state PCE respiration rates inreductive dehalogenases in a PCE-dechlorinating flow column.

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

43

Phosgene in the Thermal Decomposition Products of Poly (Vinyl Chloride): Generation, Detection and Measurement  

Science Journals Connector (OSTI)

......3) an electrical discharge between wires covered...insulation; and (4) electric arc initiated flaming combustion...phosgene is found by the electric arc decomposition, the...PVC generated by an electric discharge show that this substance......

James E. Brown; Merritt M. Birky

1980-01-01T23:59:59.000Z

44

Rate-dependent deformation behavior of poss-filled and plasticized poly(vinyl chloride)  

E-Print Network [OSTI]

Polymers are known to exhibit strong time-dependent mechanical behavior. In different temperatures or frequency regimes, the rate sensitivities of polymers change as various primary and secondary molecular mobility mechanisms ...

Soong, Sharon Yu-Wen

2007-01-01T23:59:59.000Z

45

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

dehalogenation of chlorinated dioxins by an anaerobic14], phenols [15], dibenzo-p-dioxins [16], dibenzofurans,

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

46

A2+ Mass Spectrum in ?+p Interactions at 3.7 GeVc  

Science Journals Connector (OSTI)

A study of the A2+ mass spectrum in ?+p interactions at 3.7 GeVc is presented. For a cut of t?=0.1-2.0 GeV2 and on eliminating the ?++ we find that the three-pion mass spectrum in the A2+ region is fitted by the dipole formula with a confidence level of 53% and a single Breit-Wigner formula with a confidence level of 11%. Our result thus favors A2+ splitting although a single Breit-Wigner fit cannot be ruled out. We also report the A2+ decay branching fractions measured over all t? values. They are 0.78 ± 0.05, 0.15 ± 0.04, 0.06 ± 0.03, and < 0.02 for ??, ??, KK¯, and ?? ?, respectively, in good agreement with other experiments.

K. W. J. Barnham, G. S. Abrams, W. R. Butler, D. G. Coyne, G. Goldhaber, B. H. Hall, J. MacNaughton, and G. H. Trilling

1971-06-14T23:59:59.000Z

47

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect (OSTI)

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

48

First-Principles Study of MetalCarbide/Nitride Adhesion: Al/VC vs. Al/VN Donald J. Siegel  

E-Print Network [OSTI]

-oxide ce- ramics. Within this class, the transition metal carbides and ni- trides are a particularly knowledge, there have been only three studies of adhesion between metals and transition metal carbidesFirst-Principles Study of Metal­Carbide/Nitride Adhesion: Al/VC vs. Al/VN Donald J. Siegel

Adams, James B

49

Research Needs: Glass Solar Reflectance and Vinyl Siding  

SciTech Connect (OSTI)

The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

2011-07-07T23:59:59.000Z

50

Mechanical and morphological characterization of novel vinyl plastisols with epoxidized linseed oil as natural-based plasticizer  

SciTech Connect (OSTI)

Poly(vinyl chloride)(PVC) is one of the most commonly used plastics in the current market due to its low cost and versatility in processing, combined with its satisfactory physical and chemical properties. However, there is an important problem associated to the use of plasticized PVC. This problem is regarding to the toxicity of the most common plasticized used like DOP, DEHP, DINP, due to its possible migration. This problem limits the use of the plasticized PVC in the industry. In this work we have used epoxidized linseed oil (ELO) as a non toxic plasticizer for PVC. This type of natural oil is characterized by acting as both plasticizer and stabilizer of PVC. With this purpose, ELO have been added to PVC. The processing conditions (temperature and time of curing) are vital to determine the final properties of the material. A study of the processing conditions shows the adequate temperature and time to achieve the optimum properties.

Fenollar, O.; Balart, R.; Sanchez-Nacher, L.; Garcia-Sanoguera, D.; Boronat, T. [Institute of Materials Technology (ITM), Polytechnic University of Valencia (UPV), Plaza Ferrandiz y Carbonell s/n, 03801, Alcoy, Alicante (Spain)

2010-06-02T23:59:59.000Z

51

Synthesis of vinyl acetate on palladium-based catalysts  

E-Print Network [OSTI]

Vinyl acetate (VA) is an important monomer used in the production of paints, surface coatings and adhesives. Synthesis of VA is usually carried out over supported Pd alloy catalysts with a selectivity as high as 96% and described as C2H4 + CH3COOH...

Kumar, Dheeraj

2009-06-02T23:59:59.000Z

52

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

930°F) to produce vinyl chloride monomer. VCM is convertedDichloride / Vinyl Chloride Monomer Optimize recycle loopsEthylene dichloride and vinyl chloride monomer. A number of

Neelis, Maarten

2008-01-01T23:59:59.000Z

53

HOSPITAL VENTILATION STANDARDS AND ENERGY CONSERVATION: A SUMMARY OF THE LITERATURE WITH CONCLUSIONS AND RECOMMENDATIONS, FY 78 FINAL REPORT  

E-Print Network [OSTI]

TLV (EEm) ACGIH Vinyl Chloride (Monomer) 5 mg/m ACGIH NPPainters - Solvent Vinyl Chloride (Monomer) Engineering -IUPAC Naming System Vinyl Chloride (monomer) Route of Entry:

DeRoos, R.L.

2011-01-01T23:59:59.000Z

54

Effects of chromium addition on microstructure and properties of TiC–VC reinforced Fe-based laser cladding coatings  

Science Journals Connector (OSTI)

Abstract Effects of different addition of Cr on microstructure and properties (especially the corrosion resistance) of cladding layers were investigated by means of X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), potentio-dynamic polarization and electrochemical impedance spectroscopy (EIS). Results showed that Fe–Ti–V–C alloy powders with different addition of Cr formed good cladding layers without defects such as cracking and porosity. Phases of the cladding layers were ?-Fe, ?-Fe, TiC, VC and TiVC2. A certain amount of long strip Cr3C2 synthesized while the addition of Cr was 12.0% or more. Microhardness and corrosion resistance of cladding layer both improved greatly with a moderate amount of Cr. The cladding layer with 3.0% Cr showed a highest microhardness 1090HV0.2, and the variation tendency of the hardness is not a linearly relationship with increasing the chromium addition. The cladding layer with 12.0% Cr addition showed the best corrosion resistance, which was about 4.5 times than that of the cladding layer without Cr. EIS spectrum of the cladding layer without Cr was composed of an inductive arc at low frequency and a capacitive arc at high frequency. However, the inductive arc at low frequency transformed into a capacitive arc gradually with the addition of Cr increasing.

Hui Zhang; Yong Zou; Zengda Zou; Chuanwei Shi

2014-01-01T23:59:59.000Z

55

Vinyl Kraft Windows and Doors | Open Energy Information  

Open Energy Info (EERE)

Vinyl Kraft Windows and Doors Vinyl Kraft Windows and Doors Jump to: navigation, search Name Vinyl Kraft Windows and Doors Address 3404 Rhodes Ave Place New Boston, Ohio Zip 45662 Sector Buildings, Efficiency, Services Product Business and legal services;Consulting;Energy audits/weatherization; Installation; Maintenance and repair;Manufacturing; Retail product sales and distribution Phone number 740-464-0144 Website http://www.vinylkraft.com Coordinates 38.7456°, -82.9459° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.7456,"lon":-82.9459,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

56

CHLORIDE WASHER PERFORMACE TESTING  

SciTech Connect (OSTI)

Testing was performed to determine the chloride (Cl-) removal capabilities of the Savannah River National Laboratory (SRNL) designed and built Cl- washing equipment intended for HB-Line installation. The equipment to be deployed was tested using a cerium oxide (CeO2) based simulant in place of the 3013 plutonium oxide (PuO2) material. Two different simulant mixtures were included in this testing -- one having higher Cl- content than the other. The higher Cl- simulant was based on K-Area Interim Surveillance Inspection Program (KIS) material with Cl- content approximately equal to 70,000 ppm. The lower Cl- level simulant was comparable to KIS material containing approximately 8,000-ppm Cl- content. The performance testing results indicate that the washer is capable of reducing the Cl- content of both surrogates to below 200 ppm with three 1/2-liter washes of 0.1M sodium hydroxide (NaOH) solution. Larger wash volumes were used with similar results - all of the prescribed test parameters consistently reduced the Cl- content of the surrogate to a value below 200 ppm Cl- in the final washed surrogate material. The washer uses a 20-micron filter to retain the surrogate solids. Tests showed that 0.16-0.41% of the insoluble fraction of the starting mass passed through the 20-micron filter. The solids retention performance indicates that the fissile masses passing through the 20-micron filter should not exceed the waste acceptance criteria for discard in grout to TRU waste. It is recommended that additional testing be pursued for further verification and optimization purposes. It is likely that wash volumes smaller than those tested could still reduce the Cl- values to acceptable levels. Along with reduced wash volumes, reuse of the third wash volume (in the next run processed) should be tested as a wash solution minimization plan. A 67% reduction in the number of grouted paint pails could be realized if wash solution minimization testing returned acceptable results.

Coughlin, J; David Best, D; Robert Pierce, R

2007-11-30T23:59:59.000Z

57

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide  

Science Journals Connector (OSTI)

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide ... Methyl isocyanate 19 is calculated to be the most stable isomer. ... Methods of Calculation ...

Raman Sumathi; Hue Minh Thi Nguyen; Minh Tho Nguyen; Jozef Peeters

2000-02-15T23:59:59.000Z

58

A BRIEF HISTORY OF INDUSTRIAL CATALYSIS  

E-Print Network [OSTI]

HYDROGENATIONS VINYL CHLORIDE MONOMER ( OXYCHLORINA'I'ION)and other monomers, such as vinyl- chloride, which cannot be

Heinemann, Heinz

2013-01-01T23:59:59.000Z

59

E-Print Network 3.0 - acetylenes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science 2 Acetylene Inhibition of Trichloroethene and Vinyl Chloride Summary: Acetylene Inhibition of Trichloroethene and Vinyl Chloride Reductive...

60

Control technology of vinyl chloride in EDC-VCM and PVC plants at main source points and fugitive emissions  

E-Print Network [OSTI]

for the adsorption step and vacuum and indirect steam heating for the regeneration step (see Figure 3). There are two possible mechanisms for thermal cycles; indirect heating by jacket or steam coils, and direct heating with a hot purge gas, which most often... of rupture discs upstream of relief valves, double seals in compressors and pumps, and the establishment of an effective procedure of monitoring to identify leaks, development of an adequate maintenance program, installation of a fixed point monitor...

Parra, Dario Antonio

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Production of anhydrous aluminum chloride composition  

DOE Patents [OSTI]

A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

1981-10-08T23:59:59.000Z

62

Microcontact Imprinting of Algae on Poly(ethylene-co-vinyl alcohol) for Biofuel Cells  

Science Journals Connector (OSTI)

Microcontact Imprinting of Algae on Poly(ethylene-co-vinyl alcohol) for Biofuel Cells ... The roadmap of algae biofuels technology in the U.S. has been elucidated since 2008 (http://www.orau.gov/algae2008/resources.htm). ...

Wen-Janq Chen; Mei-Hwa Lee; James L. Thomas; Po-Hsun Lu; Ming-Huan Li; Hung-Yin Lin

2013-10-06T23:59:59.000Z

63

Liebhold, A.M., W.L. Macdonald, D.Bergdahl, and V.C. Mastro. 1995. Invasion by Exotic Forest Pests: A Threat to Forest Ecosystems. Forest Science Monographs 30. 49 p.  

E-Print Network [OSTI]

Liebhold, A.M., W.L. Macdonald, D.Bergdahl, and V.C. Mastro. 1995. Invasion by Exotic Forest Pests: A Threat to Forest Ecosystems ANDREW M. LIEBHOLD WILLIAM L. MACDONALD DALE BERGDAHL VICTOR C. MASTRO FOREST

Liebhold, Andrew

64

Process for synthesis of beryllium chloride dietherate  

DOE Patents [OSTI]

A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

1991-01-01T23:59:59.000Z

65

Processing Research snd Development of ‘Green’ Polymer Nanoclay Composites Containing a Polyhydroxybutyrate, Vinyl Acetates, and Modified Montmorillonite Clay.  

E-Print Network [OSTI]

??The purpose of this research was to determine the feasibility of direct melt-blending (intercalation) montmorillonite nanoclay to polyhydroxybutyrate along with vinyl acetate, at different weight… (more)

McKirahan, James N. Jr.

2013-01-01T23:59:59.000Z

66

Nucleophilic vinylic substitutions of (Z)-(2-aroyloxyvinyl)phenyl-?3-iodanes with tetrabutylammonium halides: vinylic SN2 reactions and ligand coupling on iodine(III)  

Science Journals Connector (OSTI)

Treatment of (Z)-(?-benzoyloxyvinyl)phenyl-?3-iodanes, readily prepared from ethynyl(phenyl)(tetrafluoroborato)-?3-iodane via stereoselective Michael-type addition of benzoic acids in methanol in the presence of sodium benzoates, with tetrabutylammonium halides in THF at 65 °C results in a vinylic SN2 reaction to give the inverted (E)-?-benzoyloxyvinyl halides in high yields.

Masahito Ochiai; Yoshio Nishi; Masaya Hirobe

2005-01-01T23:59:59.000Z

67

Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic C–H Functionalization  

E-Print Network [OSTI]

A copper(II)-catalyzed oxidative cyclization of enamides to oxazoles via vinylic C–H bond functionalization at room temperature is described. Various 2,5-disubstituted oxazoles bearing aryl, vinyl, alkyl, and heteroaryl ...

Cheung, Chi Wai

68

Hydrothermal brecciation in the Jemez Fault zone, Valles Caldera, New Mexico: Results from CSDP (Continental Scientific Drilling Program) corehole VC-1  

SciTech Connect (OSTI)

Paleozoic and Precambrian rocks intersected deep in Continental Scientific Drilling Program corehole VC-1, adjacent to the late Cenozoic Valles caldera complex, have been disrupted to form a spectacular breccia sequence. The breccias are of both tectonic and hydrothermal origin, and probably formed in the Jemez fault zone, a major regional structure with only normal displacement since mid-Miocene. Tectonic breccias are contorted, crushed, sheared, and granulated; slickensides are commmon. Hydrothermal breccias, by contrast, lack these frictional textures, but arej commonly characterized by fluidized matrix foliation and prominent clast rounding. Fluid inclusions in the hydrothermal breccias are dominantly two-phase, liquid-rich at room temperature, principally secondary, and form two distinctly different compositional groups. Older inclusions, unrelated to brecciation, are highly saline and homogenize to the liquid phase in the temperature range 189 to 246/sup 0/C. Younger inclusions, in part of interbreccia origin, are low-salinity and homogenize (also to liquid) in the range 230 to 283/sup 0/C. Vapor-rich inclusions locally trapped along with these dilute liquid-rich inclusions document periodic boiling. These fluid-inclusion data, together with alteration assemblages and textures as well as the local geologic history, have been combined to model hydrothermal brecciation at the VC-1 site.

Hulen, J.B.; Nielson, D.L.

1987-06-01T23:59:59.000Z

69

Structural and electronic properties of poly(vinyl alcohol) using density functional theory  

SciTech Connect (OSTI)

The first principles calculations have been carried out to investigate the structural, electronic band structure density of states along with the projected density of states for poly(vinyl alcohol). Our structural calculation suggests that the poly(vinyl alcohol) exhibits monoclinic structure. The calculated structural lattice parameters are in excellent agreement with available experimental values. The band structure calculations reveal that the direct and indirect band gaps are 5.55 eV and 5.363 eV respectively in accordance with experimental values.

Dabhi, Shweta, E-mail: shwetadabhi1190@gmail.com; Jha, Prafulla K., E-mail: shwetadabhi1190@gmail.com [Department of Physics, Maharaja Krishnakumasinhji Bhavnagar University, Bhavnagar-364001 (India)

2014-04-24T23:59:59.000Z

70

Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Chloride and Hydrogen Sulfide Hydrogen Chloride and Hydrogen Sulfide Removal Sorbents for High Temperature Gas Streams Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,767,000 entitled "Regenerable Hydrogen Chloride Removal Sorbent and Regenerable Multifunctional Hydrogen Sulfide and Hydrogen Chloride Removal Sorbent for High Temperature Gas Streams." Disclosed in this patent is the invention of a unique regenerable sorbent process that can remove contaminants from gas produced by the gasification of fossil fuels. Specifically, the process removes hydrogen chloride by using the regenerable sorbent and simultaneously extracts hydrogen chloride compounds and hydrogen

71

Absorption media for irreversibly gettering thionyl chloride  

DOE Patents [OSTI]

Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

Buffleben, George (Tracy, CA); Goods, Steven H. (Livermore, CA); Shepodd, Timothy (Livermore, CA); Wheeler, David R. (Albuquerque, NM); Whinnery, Jr., LeRoy (Danville, CA)

2002-01-01T23:59:59.000Z

72

Effect of composite microstructure on electrical and mechanical properties of poly(vinyl acetate) composites with carbon black and clay.  

E-Print Network [OSTI]

The electrical and mechanical behavior of carbon black filled poly(vinyl acetate) latex-based and solution-based polymer composites was examined. A set of experiments were performed to distinguish composites with a segregated network (emulsion...

Miriyala, Sethu M.

2009-05-15T23:59:59.000Z

73

Palladium-Catalyzed Enantioselective ?-Arylation and ?-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand  

E-Print Network [OSTI]

The enantioselective ?-arylation and ?-vinylation of oxindoles catalyzed by Pd and a biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The resultant quaternary carbon stereocenters ...

Taylor, Alexander M.

74

Diffusion of Binary Non-solvent Mixtures in Polymers: Aqueous Ethanol Solutions in Poly(vinyl acetate)  

Science Journals Connector (OSTI)

The diffusion of binary non-solvent mixtures of ethanol and deuterium oxide (D2O) into poly(vinyl acetate) (PVAc) was studied by FT-IR imaging. Initial diffusion rates...

Rafferty, Denise Wade; Koenig, Jack L

2002-01-01T23:59:59.000Z

75

USING THE CHLORIDE MIGRATION RATE TO PREDICT THE CHLORIDE PENETRATION RESISTANCE OF CONCRETE  

Science Journals Connector (OSTI)

An experimental investigation is conducted to study the relationship between the chloride diffusion coefficient and charge passed. In this study, the concrete specimens made with different w/c (ranging from 0....

S.W. Cho; S.C. Chiang

2006-01-01T23:59:59.000Z

76

Modifications in the correlation function in poly(vinyl alcohol)/silica hybrid wet gels  

Science Journals Connector (OSTI)

Small-angle X-ray scattering was used to study modifications in the correlation function in tetraethoxysilane-derived poly(vinyl alcohol)/silica hybrids. An additional scattering at low q was found to overlap the fundamental mass-fractal scattering from the basic silica. The fraction of both contributions to the total correlation function was estimated; this is the first time that such a study has been carried out for mass-fractal structures.

Vollet, D.R.

2008-11-28T23:59:59.000Z

77

Method for the regeneration of spent molten zinc chloride  

DOE Patents [OSTI]

In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

1981-01-01T23:59:59.000Z

78

A study of the effects of nanoparticle modification on the thermal, mechanical and hygrothermal performance of carbon/vinyl ester composites.  

E-Print Network [OSTI]

?? Enhancement of mechanical, thermal and hygrothermal properties of carbon fiber/vinyl ester (CFVE) composites through nanoparticle reinforcement has been investigated. CFVE composites are becoming more… (more)

Powell, Felicia M.

2012-01-01T23:59:59.000Z

79

A study of the effects of nanoparticle modification on the thermal, mechanical and hygrothermal performance of carbon/vinyl ester compounds.  

E-Print Network [OSTI]

??Enhancement of mechanical, thermal and hygrothermal properties of carbon fiber/vinyl ester (CFVE) composites through nanoparticle reinforcement has been investigated. CFVE composites are becoming more and… (more)

Powell, Felicia M.

2012-01-01T23:59:59.000Z

80

Effect of ethylene-vinyl acetate copolymer-based depressants on the low-temperature properties of components of light- and heavy-grade marine fuels  

Science Journals Connector (OSTI)

The possibility of using ethylene copolymers with vinyl acetate as additives for light and heavy distillate marine fuels for improving their low-temperature properties has...

N. K. Kondrasheva

2013-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

E-Print Network 3.0 - acid monomer induced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Vinyl Chloride in Relation to the Low Thermal Stability of Poly(Vinyl Chloride) Summary: to be immediately attached to a monomer molecule, initiating new chain...

82

Probing the role of chloride in Photosystem II from Thermosynechococcus elongatus by exchanging chloride for iodide  

E-Print Network [OSTI]

Center, Ehime University, Bunkyo-cho, Matsuyama Ehime, 790­8577, Japan, and PRESTO, Japan Science 2012 Keywords: Photosystem II Chloride Oxygen evolution The active site for water oxidation in Photosystem II (PSII) goes through five sequential oxidation states (S0 to S4) before O2 is evolved

83

European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3.25 MODELLING THE CURING DYNAMICS OF ETHYLENE-VINYL ACETATE  

E-Print Network [OSTI]

.25 MODELLING THE CURING DYNAMICS OF ETHYLENE-VINYL ACETATE S. Kajari-Schröder1 , U. Eitner1 , C. Oprisoni2 , T Hannover, Germany ABSTRACT: The encapsulation of solar cells in polymeric sheets such as ethylene PV module [1]. Ethylene-vinyl acetate (EVA) is the most common encapsulant in the PV industry

84

XRCC1 and CYP2E1 Polymorphisms as Susceptibility Factors of Plasma Mutant p53 Protein and Anti-p53 Antibody Expression in Vinyl Chloride Monomer-exposed Polyvinyl Chloride Workers  

Science Journals Connector (OSTI)

...sufficient statistical discriminatory power to detect the difference between mutant...working indoor or outdoor, as well as wind direction and velocity. This reconstructed...although there was limited statistical power to note the effect of the CYP2E1 c2c2...

Ruey-Hong Wong; Chung-Li Du; Jung-Der Wang; Chang-Chuan Chan; Jiin-Chyuan J. Luo; and Tsun-Jen Cheng

2002-05-01T23:59:59.000Z

85

XRCC1 and CYP2E1 Polymorphisms as Susceptibility Factors of Plasma Mutant p53 Protein and Anti-p53 Antibody Expression in Vinyl Chloride Monomer-exposed Polyvinyl Chloride Workers  

Science Journals Connector (OSTI)

...sufficient statistical discriminatory power to detect the difference between mutant p53...working indoor or outdoor, as well as wind direction and velocity. This reconstructed...although there was limited statistical power to note the effect of the CYP2E1 c2c2 genotype...

Ruey-Hong Wong; Chung-Li Du; Jung-Der Wang; Chang-Chuan Chan; Jiin-Chyuan J. Luo; and Tsun-Jen Cheng

2002-05-01T23:59:59.000Z

86

European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3.115 NON-LINEAR MECHANICAL PROPERTIES OF ETHYLENE-VINYL ACETATE (EVA) AND ITS  

E-Print Network [OSTI]

.115 1 NON-LINEAR MECHANICAL PROPERTIES OF ETHYLENE-VINYL ACETATE (EVA) AND ITS RELEVANCE ABSTRACT: Polymers such as ethylene-vinyl acetate (EVA) encapsulants are known for their non for PV modules is ethylene-vinyl acetate (EVA). It is thus essential for mechanical module and lamination

87

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence  

E-Print Network [OSTI]

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear molybdenum chloride clusters. Measurements of the probe operating in a 0%­21% gaseous oxygen environment have

Ghosh, Ruby N.

88

EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building  

Broader source: Energy.gov (indexed) [DOE]

57: Methyl Chloride via Oxyhydrochlorination of Methane: A 57: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky SUMMARY This EA evaluates the environmental impacts for the proposal to advance Oxyhydrochlorination technology to an integrated engineering-scale process. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD September 27, 1996 EA-1157: Finding of No Significant Impact Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas September 27, 1996 EA-1157: Final Environmental Assessment Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for

89

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

Pereira, C.

1999-02-23T23:59:59.000Z

90

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700.degree. C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

Pereira, Candido (Naperville, IL)

1999-01-01T23:59:59.000Z

91

E-Print Network 3.0 - acute cadmium chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... CalOSHAReproToxin Benzyl chloride AcutelyHazardousWaste Benzyl violet 4B...

92

The synthesis of symmetrical bis-1,2,5-thiadiazole ligandsq Dean M. Philipp,a  

E-Print Network [OSTI]

for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate there have been no reliable reports of the coordination polymerization of vinyl acetate or vinyl chloride-hydroxy thia- diazole; Vinyl chloride. q Supplementary data associated with this article can be found

Goddard III, William A.

93

Crystallization in the Thin and Ultrathin Films of Poly(ethylene-vinyl acetate) and Linear Low-Density Polyethylene  

E-Print Network [OSTI]

-Density Polyethylene Y. Wang, S. Ge, M. Rafailovich,*, J. Sokolov, Y. Zou, H. Ade, J. Lu1 ning,§ A. Lustiger, and G(ethylene-vinyl acetate) and linear low-density polyethylene (LLDPE) films spun-cast from the polymer/toluene solutions spherulite to sheaflike ag- gregates in polyethylene thin films at a critical thickness of 400 nm. Scho

94

E-Print Network 3.0 - argon chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and 266 nm photoreaction of acetyl chloride in xenon and argon... matrixes. Experimental Section Neat and argon matrix-isolated thin films of acid chlorides are deposited... -gas...

95

Method for the production of uranium chloride salt  

DOE Patents [OSTI]

A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

Westphal, Brian R.; Mariani, Robert D.

2013-07-02T23:59:59.000Z

96

Engineering and Health Impact Methods in Green Design Student projects PH 290 Sec 07  

E-Print Network [OSTI]

materials; process chemistry in producing vinyl chloride monomer; choices of antibacterial agents; need

Iglesia, Enrique

97

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera...  

Open Energy Info (EERE)

in and around the caldera. In order to determine the fluid pathways and the origin of chloride in this system, we measured 36ClCl ratios in waters from high-temperature...

98

Magnesium and Copper (II) Chloride: A Curious Redox Reaction .  

E-Print Network [OSTI]

??The focus of this research is to follow the oxidation-reduction reaction of solid magnesium metal and an aqueous solution of copper (II) chloride (CuCl2), both… (more)

Mannard, Moira

2014-01-01T23:59:59.000Z

99

The Salt or Sodium Chloride Content of Feeds  

E-Print Network [OSTI]

1 EXAS AGRICULTURAL EXPERIMENT STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BIZZELL, Preeident BULLETIN NO. 271 OCTOBER, 1920 DIVISION OF CHEMISTRY THE SALT OR SODIUM CHLORIDE CONTENT OF FEEDS B. YOUNGBLOOD, DIRECTOK COLLEGE.... ............... Salt content of feecls.. ......... Salt content of mixed feeds.. ................... Summary ancl conclusions. Page. l1 [Blank Page in Original Bulletin] BULLETIN XO. 271. OCTOBE- '"On THE SALT OR SODIUM CHLORIDE CONTENT OF FEI The Texas feed...

Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

1920-01-01T23:59:59.000Z

100

Procedures for Harvesting tissue for Genotyping with SolCAP Vinyl mesh (not metal) screen from local hardware store cut in plate size rectangles  

E-Print Network [OSTI]

Procedures for Harvesting tissue for Genotyping with SolCAP Supplies: Vinyl mesh (not metal) screen (Fisher part# 14-387-90) 1 quart Ziploc bags Silca: Fisher part# s161-212 Procedures 1. Label plate

Douches, David S.

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Plug repairs of marine glass fiber / vinyl ester laminates subjected to in-plane shear stress or in-plane bending moment  

E-Print Network [OSTI]

Glass fiber / vinyl ester composite laminates represent an important class of modem fiber composites being proposed or used in state-of-the-art shipbuilding. This thesis examined the effectiveness of chopped strand mat ...

Urrutia Valenzuela, Roberto

2010-01-01T23:59:59.000Z

102

The characteristics of cobalt or copper salt-coordinated poly(4-vinylpyridine-co-2,4-diamino-6-vinyl-s-triazine) membrane for reverse osmosis  

Science Journals Connector (OSTI)

Poly(4-vinylpyridine-co-2,4-diamino-6-vinyl-s-triazine) membranes in which a part of pyridine rings was coordinated with cobalt or copper salt, considerably enhanced salt rejection without appreciable reductio...

Eizo Oikawa; Yoshiji Honda; Yuji Sawada

1981-12-01T23:59:59.000Z

103

Alternate fuels and chemicals from synthesis gas: Vinyl acetate monomer. Final report  

SciTech Connect (OSTI)

There has been a long-standing desire on the part of industry and the U.S. Department of Energy to replace the existing ethylene-based vinyl acetate monomer (VAM) process with an entirely synthesis gas-based process. Although there are a large number of process options for the conversion of synthesis gas to VAM, Eastman Chemical Company undertook an analytical approach, based on known chemical and economic principles, to reduce the potential candidate processes to a select group of eight processes. The critical technologies that would be required for these routes were: (1) the esterification of acetaldehyde (AcH) with ketene to generate VAM, (2) the hydrogenation of ketene to acetaldehyde, (3) the hydrogenation of acetic acid to acetaldehyde, and (4) the reductive carbonylation of methanol to acetaldehyde. This report describes the selection process for the candidate processes, the successful development of the key technologies, and the economic assessments for the preferred routes. In addition, improvements in the conversion of acetic anhydride and acetaldehyde to VAM are discussed. The conclusion from this study is that, with the technology developed in this study, VAM may be produced from synthesis gas, but the cost of production is about 15% higher than the conventional oxidative acetoxylation of ethylene, primarily due to higher capital associated with the synthesis gas-based processes.

Richard D. Colberg; Nick A. Collins; Edwin F. Holcombe; Gerald C. Tustin; Joseph R. Zoeller

1999-01-01T23:59:59.000Z

104

Endovascular Treatment of Acute Arterial Hemorrhage in Trauma Patients Using Ethylene Vinyl Alcohol Copolymer (Onyx)  

SciTech Connect (OSTI)

Purpose: This study was designed to determine the feasibility and efficacy of endovascular embolization with liquid embolic agent ethylene vinyl alcohol copolymer (Onyx) in patients with acute traumatic arterial bleeding. Methods: This is a retrospective review of 13 patients (9 men and 4 women; mean age 45 years) with severe trauma who underwent embolotherapy using Onyx from November 2003 to February 2009. Bleeding was located in the pelvis (5 patients), kidney (3 patients), mesenteric region (2 patients), retroperitoneal space (2 patients), neck (1 patient), and thigh (1 patient). In three cases (23.1%), Onyx was used in conjunction with coils. We evaluate the technical and clinical success, procedural and embolization time, occurrence of rebleeding, and embolotherapy-related complications, such as necrosis or migration of Onyx into nontarget vessels. Results: In all patients, embolotherapy was technically and clinically successful on the first attempt. Control of bleeding could be reached with a mean time of 19 (range, 4-63) min after correct placement of the microcatheter in the feeding artery. No recurrent bleeding was detected. No unintended necrosis or migration of Onyx into a nontarget region was observed. During the follow-up period, three patients (23.1%) died due to severe intracranial hemorrhage, cardiac arrest, and sepsis. Conclusions: Transcatheter embolization with new liquid embolic agent Onyx is technically feasible and effective in trauma patients with acute arterial hemorrhage.

Mueller-Wille, R., E-mail: rene.mueller-wille@klinik.uni-regensburg.de; Heiss, P., E-mail: peter.heiss@klinik.uni-regensburg.de [University Medical Center Regensburg, Department of Radiology (Germany); Herold, T., E-mail: thomas.herold@helios-kliniken.de [Helios Klinikum Berlin-Buch, Department of Radiology (Germany); Jung, E. M., E-mail: ernst-michael.jung@klinik.uni-regensburg.de; Schreyer, A. G., E-mail: andreas.schreyer@klinik.uni-regensburg.de; Hamer, O. W., E-mail: okka.hamer@klinik.uni-regensburg.de; Rennert, J., E-mail: janine.rennert@klinik.uni-regensburg.de; Hoffstetter, P., E-mail: P.hoffstetter@asklepios.com; Stroszczynski, C., E-mail: christian.stros@klinik.uni-regensburg.de [University Medical Center Regensburg, Department of Radiology (Germany); Zorger, N., E-mail: Niels.Zorger@barmherzige-regensburg.de [Krankenhaus Barmherzige Brueder Regensburg, Department of Radiology (Germany)

2012-02-15T23:59:59.000Z

105

Investigation of electrochemical properties of a poly(vinyl alcohol)/poly(acrylic acid) polymer blend  

SciTech Connect (OSTI)

Chemical sensors have wide applications in medicine, environmental monitoring, industrial applications, and others because of their versatility, ruggedness, sensitivity, selectivity, and economy. Electrochemical sensors are constructed by using a conducting medium, in this case graphite, and applying a constant potential while measuring changes in the current. Polymers are used for electrochemical sensors to exclude interferents from the electrode surface, to preconcentrate the analyte near the electrode, and in some cases to provide a matrix for the immobilization of analytes, such as enzymes. These functions of the polymer can serve to improve the detection limit of the sensor. This project involves the evaluation of a new polymer for electrode modification. The poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) polymer was originally developed as an ion exchanger for use in space batteries. It has also been used in wastewater cleanup because it will concentrate heavy metals in the presence of calcium ion. This polymer is also optically clear, so it can potentially be used for an optical sensor. We are interested in investigating the ion exchange properties of the PVA/PAA polymer, as well as the ability of this polymer to preconcentrate and exclude analytes on the basis of size, charge, and hydrophilic/hydrophobic interactions.

DeSantis, C.O.; Seliskar, C.; Heineman, W.R. [Univ. of Cincinnati, OH (United States)

1995-12-31T23:59:59.000Z

106

Polymer Preprints 2004, 45(2), CHARGE DENSITY EFFECTS IN SALT -FREE  

E-Print Network [OSTI]

-methyl-2-vinyl pyridinium chloride (PMVP-Cl) with various charge density and uncharged neutral parent poly of the random copolymers of 2-vinyl pyridine and N- methyl-2-vinyl pyridinium chloride. First, the parent dry P2 by serial dilution. Polymer concentration is reported in moles of monomers (vinyl pyridine or vinyl

Colby, Ralph H.

107

Production of anhydrous aluminum chloride composition and process for electrolysis thereof  

DOE Patents [OSTI]

A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

1983-01-01T23:59:59.000Z

108

The value of urinary chloride measurement in distinguishing surreptitious vomiting from Bartter's syndrome  

Science Journals Connector (OSTI)

Urinary chloride measurement is a simple and common procedure but its value in clinical practice is not extensive. This case report highlights a practical and important use of this test. A patient presented with most of the clinical and metabolic derangements of Bartter's syndrome but was found to have extremely low or absent urinary chloride excretion. Her ability to excrete chloride was, however, intact during a chloride load test. The finding of low urinary chloride excretion did not support the diagnosis of Bartter's syndrome and suggested an extrarenal loss of chloride. This was confirmed when she eventually admitted to surreptitious vomiting.

Teik C. Ooi; Wojciech J. Poznanski; Daylily S. Ooi

1983-01-01T23:59:59.000Z

109

Production and mitigation of acid chlorides in geothermal steam  

SciTech Connect (OSTI)

Measurements of the equilibrium distribution of relatively nonvolatile solutes between aqueous liquid and vapor phases have been made at temperatures to 350{degrees}C for HCl(aq) and chloride salts. These data are directly applicable to problems of corrosive-steam production in geothermal steam systems. Compositions of high-temperature brines which could produce steam having given concentrations of chlorides may be estimated at various boiling temperatures. Effects of mitigation methods (e.g., desuperheating) can be calculated based on liquid-vapor equilibrium constants and solute mass balances under vapor-saturation conditions.

Simonson, J.M.; Palmer, D.A.

1995-06-01T23:59:59.000Z

110

The effect of freezing on the sulfate-chloride and density-chloride ratios of sea-water  

E-Print Network [OSTI]

. It is commoniy hold that tho changes are negligible for most practical purposes, However, Cox and Culkin et al. (1O62) hsvo shown that there arc definite changos in the density-chlorinitv ratio fro? place to place and frcm top to bottom in thc sea... in the sulphate-chloride ratio would be expected to have a corresponi- ingly larger effect, on density than would one of the less abundant iona. CHAPTER II LITERATURE REVIEW Evidence for Sulphate Enricl ment in Ice The sulphate-chloride ratio was studied...

Burkhalter, Albert Charles

2012-06-07T23:59:59.000Z

111

Membrane Transport Chloride Transport Across Vesicle and Cell  

E-Print Network [OSTI]

Membrane Transport Chloride Transport Across Vesicle and Cell Membranes by Steroid-Based Receptors-established that molecules which transport cations across cell membranes (cationophores) can have potent biological effects the formation of an ion pair.[4a­g] Anion transport by purely electroneutral systems is still quite rare.[4j

Smith, Bradley D.

112

E-Print Network 3.0 - arsenic chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

that the chloride anion was responsible for the difference in the effect of CaCO3 and CaCl2 on plant arsenic uptake... depends on plant species and chloride concentration. The...

113

Soil stabilization using optimum quantity of calcium chloride with Class F fly ash  

E-Print Network [OSTI]

On-going research at Texas A&M University indicated that soil stabilization using calcium chloride filter cake along with Class F fly ash generates high strength. Previous studies were conducted with samples containing calcium chloride filter cake...

Choi, Hyung Jun

2006-10-30T23:59:59.000Z

114

Film-forming capacity of alcoholic solutions of iron(III) chloride with acetylacetone  

Science Journals Connector (OSTI)

Processes in which film-forming solutions based on acetylacetonate and iron(III) chloride are produced were subjected to...

S. A. Kuznetsova; I. A. Senokosova

2010-11-01T23:59:59.000Z

115

Polymer Reactor Design, Optimization and Control in Latex Production Technology.  

E-Print Network [OSTI]

?? During continuous emulsion polymerization of many monomers (e.g. vinyl acetate, vinyl chloride), sustained oscillations (limit cycles) occur in conversion and all the latex and… (more)

Penlidis, Alexander

1986-01-01T23:59:59.000Z

116

Nonlinear optical properties of ZnO/poly (vinyl alcohol) nanocomposite films  

SciTech Connect (OSTI)

Extensive studies have already been reported on the optical characteristics of ZnO/polymer nanocomposite films, using a variety of polymers including transparent polymers such as polystyrene, polymethyl methacrylate etc and many interesting results have been established regarding the non linear optical characteristics of these systems. Poly (vinyl alcohol)(PVA) is a water soluble polymer. Though the structural and optical studies of ZnO/PVA nanocomposite films have already been investigated, there are no detailed reports on the nonlinear optical characteristics of ZnO/PVA nanocomposite films, irrespective of the fact that these nanocomposite films can be synthesized using quite easy and cost effective methods. The present work is an attempt to study in detail the nonlinear optical behaviour of ZnO/PVA nanocomposite films using Z-scan technique. Highly transparent ZnO/PVA nanocomposite films were prepared from the ZnO incorporated PVA solution in water using spin coating technique. The ZnO nanoparticles were synthesized by the simple chemical route at room temperature. High-resolution transmission electron microscopy studies show that the ZnO nanoparticles are of size around 10 nm. The ZnO/PVA nanocomposite films were structurally characterized by X-ray diffraction technique, from which the presence of both PVA and ZnO in the nanocomposite was established. The optical absorptive nonlinearity in the nanocomposite films was investigated using open aperture Z-scan technique. The results indicate optical limiting type nonlinearity in the films due to two photon absorption in ZnO with efficiency more than 50%. These films also show a self defocusing type negative nonlinear refraction in closed aperture Z-scan experiment. The present studies indicate that, highly transparent and homogeneous films of ZnO/PVA nanocomposite can be obtained on glass substrates using simple methods, in a highly cost effective way, since PVA is water soluble. These nanocomposite films offer prospects of application as efficient optical limiters to protect light sensitive devices from the possible damage on exposure to high intensity radiation.

Jeeju, P. P., E-mail: jeejupp@gmail.com [Department of Physics, S N M College, Maliankara, Ernakulam, Kerala (India); Jayalekshmi, S., E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi 682 022 (India); Chandrasekharan, K. [Department of Physics, National Institute of Technology, Calicut, Kerala (India)

2014-01-28T23:59:59.000Z

117

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

Thermophysical Properties of Sodium Nitrate and Sodium Chloride Thermophysical Properties of Sodium Nitrate and Sodium Chloride Solutions and Their Effects on Fluid Flow in Unsaturated Media Tianfu Xu and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT. Understanding movement of saline sodium nitrate (NaNO 3 ) waste solutions is important for assessing the contaminant migration near leaking waste storage tanks in the unsaturated zone at the Hanford site (Washington, USA). The purpose of this study is to contribute a basic understanding of effects of the thermophysical behavior of NaNO 3 solutions on fluid flow in unsaturated media. We first present mathematical expressions for the dependence of density, viscosity, solubility and vapor pressure of

118

Uranium chloride extraction of transuranium elements from LWR fuel  

DOE Patents [OSTI]

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800 C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein. 1 figure.

Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

1992-08-25T23:59:59.000Z

119

The formation of PdCx over Pd-based catalysts in vapor-phase vinyl acetate synthesis: does a PdAu alloy catalyst resist carbide formation?  

E-Print Network [OSTI]

­Au alloy catalyst resist carbide formation? Y.-F. Han, D. Kumar, C. Sivadinarayana, A. Clearfield, and D October 2003; accepted 24 February 2004 The formation of Pd carbide (PdCx) during the synthesis of vinyl­Au/SiO2; XRD. 1. Introduction The formation of carbides over supported Pd catalysts was first reported

Goodman, Wayne

120

Development of a copper-catalyzed amidation-base-promoted cyclization sequence for the synthesis of 2-aryl- and 2-vinyl1-4 quinolones  

E-Print Network [OSTI]

A direct two-step method for the preparation of 2-aryl- and 2-vinyl-4-quinolones that utilizes a copper-catalyzed amidation of ortho-halophenones followed by a base-promoted Camps cyclization of the resulting N-(2-keto-aryl)amides ...

Jones, Carrie Preston

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Semiarid unsaturated zone chloride profiles: Archives of past land use change impacts on water resources in the southern High Plains,  

E-Print Network [OSTI]

) was quantified using chloride mass balance calculations. The timing of land use change was estimated using

Scanlon, Bridget R.

122

Modeling acid-gas generation from boiling chloride brines  

SciTech Connect (OSTI)

This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

2009-11-16T23:59:59.000Z

123

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents [OSTI]

A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, M.A.; Pereira, C.

1997-03-18T23:59:59.000Z

124

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents [OSTI]

A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, Michele A. (Naperville, IL); Pereira, Candido (Lisle, IL)

1997-01-01T23:59:59.000Z

125

Removal of Chloride from Wastewater by Advanced Softening Process Using Electrochemically Generated Aluminum Hydroxide  

E-Print Network [OSTI]

, several processes have been employed in removing chloride from water and wastewater. 3 Among these processes are reverse osmosis and electrodialysis [8]. However these technologies are nonselective and expensive. They also produce brine, which has... and other dissolved solids is an important step before reuse of treated wastewater. Furthermore, chloride removal from industrial wastewater can facilitate water reuse and recycle. Reverse osmosis (RO) is widely used for chloride and other dissolved...

Mustafa, Syed Faisal

2014-07-23T23:59:59.000Z

126

Efficient Conversion of Glucose into 5-Hydroxymethylfurfural by Chromium(III) Chloride in Inexpensive Ionic Liquid  

Science Journals Connector (OSTI)

Efficient Conversion of Glucose into 5-Hydroxymethylfurfural by Chromium(III) Chloride in Inexpensive Ionic Liquid ... An efficient process was developed for the conversion of glucose into 5-hydroxymethylfurfural (HMF) in the relatively low-toxicity and inexpensive catalytic system of chromium(III) chloride (CrCl3·6H2O) catalyst and tetraethylammonium chloride (TEAC) ionic liquid. ... Chemoselective Hydrogenation of Biomass-Derived 5-Hydroxymethylfurfural into the Liquid Biofuel 2,5-Dimethylfuran ...

Lei Hu; Yong Sun; Lu Lin

2011-12-20T23:59:59.000Z

127

E-Print Network 3.0 - antimony chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tissuesw Summary: Laboratory Chemicals, Australia) or antimony(III) chloride (Merck, Germany) and potassium hexahydroxoanti... Observations on the measurement of total antimony...

128

E-Print Network 3.0 - aqueous sodium chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cholate... by the addition of sodium chloride or ammonium sulfate salt and then resuspension of the SWNTs... peroxidase (HRP) on single-walled carbon nanotubes (SWNTs) using...

129

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network [OSTI]

zinc and chloride by atomic absorption by the spectroscopy.College The atomic absorption spectroscopy was performed ofrandom error is about atomic absorption spectroscopy. Many

Mc Vay, L.

2011-01-01T23:59:59.000Z

130

E-Print Network 3.0 - americium chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with NIST traceable standards: americium- 241 for alpha and strontium... , chlorobenzene, carbon tetrachloride, methyl chloride, and acetone) are analyzed under this category ......

131

E-Print Network 3.0 - aluminum sodium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

agents Water Acetyl chloride, alkaline and alkaline... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium ... Source: Hall, Sharon J. - School of Life Sciences, Arizona...

132

COMET TA Floor Plan 100225.vc6  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rack Argus Chamber Interaction Chamber Work Station 8 3 0 2 - V B L as phere CL 420mm f rom N i nner wall. Lens h older E f ac e27mm f rom W i nner w all. Parabola CL 534m m from...

133

Charge Density Effects in Salt-Free Polyelectrolyte Solution Rheology  

E-Print Network [OSTI]

of 2-vinyl pyridine and N-methyl-2-vinyl pyridinium chloride random copolymers in ethylene glycol of 2-vinyl pyridine and N- methyl-2-vinyl pyridinium chloride (PMVP-Cl) of any charge density was studied over wide ranges of con- centration and effective charge. The fraction of quaternized monomers

Colby, Ralph H.

134

Gold catalysts for the hydrochlorination of acetylene.  

E-Print Network [OSTI]

??The direct, gas-phase hydrochlorination of acetylene is a method by which vinyl chloride monomer (VCM) is produced industrially. VCM is polymerised to produce poly-vinyl chloride… (more)

Davies, Catherine

2013-01-01T23:59:59.000Z

135

Method of recovering uranium from aqueous solution  

SciTech Connect (OSTI)

Anion exchange resin derived from insoluble crosslinked polymers of vinyl benzyl chloride which are prepared by polymerizing vinyl benzyl chloride and a crosslinking monomer are particularly suitable in the treatment of uranium bearing leach liquors.

Albright, R.L.

1980-01-22T23:59:59.000Z

136

Stereoselective synthesis of trans-olefins by the copper-mediated SN2? reaction of vinyl oxazines with Grignard reagents. Asymmetric synthesis of d-threo-sphingosines  

Science Journals Connector (OSTI)

The SN2? reaction of 6-vinyl-5,6-dihydro-4H-[1,3]oxazines with Grignard reagents in the presence of CuCN was studied, and high trans selectivity for the formation of double bond was observed with a variety of RMgX. The SN2? reaction, coupled with regioselective asymmetric aminohydroxylation reaction, provided a highly efficient route for the asymmetric synthesis of d-threo-N-acetylsphingosine.

Om V. Singh; Hyunsoo Han

2007-01-01T23:59:59.000Z

137

Influence of weather and global warming in chloride ingress into concrete: a stochastic approach  

E-Print Network [OSTI]

Influence of weather and global warming in chloride ingress into concrete: a stochastic approach E the influence of weather conditions and global warming on chloride ingress into concrete. The assessment including seasonal variations and global warming is also proposed in this work. Three scenarios of global

Paris-Sud XI, Université de

138

Investigation of the near-infrared spectral character of putative Martian chloride deposits  

E-Print Network [OSTI]

Investigation of the near-infrared spectral character of putative Martian chloride deposits Heidi B in near-infrared ratio spectra. It is hypothesized that the admixture of anhydrous chlorides or unoxidized of these deposits. Citation: Jensen, H. B., and T. D. Glotch (2011), Investigation of the near-infrared spectral

Glotch, Timothy D.

139

Structural study of 2,4,6-triisopropylbenzenesulfonyl chloride  

SciTech Connect (OSTI)

The structure of 2,4,6-triisopropylbenzenesulfonyl chloride (TPSCl) (I) was studied by X-ray diffraction. Compound I is a highly selective condensing agent first suggested by Khorana for the formation of the C3'-C5' interribonucleotide linkage in the oligo- and polyribonucleotide synthesis. I crystals are orthorhombic. At -120 deg. C, the unit-cell parameters are a = 14.184(4) A, b = 11.344(5) A, c = 19.883(6) A, V = 3199(2) A{sup 3}, d{sub calc} = 1.257 g/cm{sup 3}, Z = 8, sp. gr. Pbca. Molecule I adopts a strongly flattened boat conformation with the carbon atoms C-SO{sub 2}Cl (C{sub 1}) and C-i-Pr (C4) of the benzene ring deviating from the bottom of the boat by 0.065(1) and 0.032(1) A, respectively. Molecule I is sterically overcrowded, resulting in an increase in the bond lengths and bond-angle distortions in the fragment containing the SO{sub 2}Cl group and two ortho-i-Pr groups. Nonbonded contacts that are present in the molecule can be considered weak intramolecular hydrogen bonds (for example, the (CH{sub 3}){sub 2}C-H-O=S bond). There is no rotation of the SO{sub 2}Cl, ortho-i-Pr, and CH{sub 3} groups. The above-mentioned facts are, apparently, responsible for the specific selectivity of TPSCl. New readily available sterically hindered arenesulfonyl chlorides were designed.

Laba, V. I., E-mail: shchem@dol.ru; Sviridova, A. V. [Russian Academy of Sciences, Zelinsky Institute of Organic Chemistry (Russian Federation); Nesterov, V. N. [Russian Academy of Sciences, Nesmeyanov Institute of Organoelement Compounds (Russian Federation)

2009-01-15T23:59:59.000Z

140

Modeling an EDC Cracker using Computational Fluid Dynamics (CFD).  

E-Print Network [OSTI]

?? The process used by the Norwegian company Hydro for making Vinyl Chloride Monomer (VCM) from natural gas and sodium chloride has been studied. A… (more)

Kaggerud, Torbjørn Herder

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method  

SciTech Connect (OSTI)

Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

Cooper, Clay A [DRI] [DRI; Hershey, Ronald L [DRI] [DRI; Healey, John M [DRI] [DRI; Lyles, Brad F [DRI] [DRI

2013-07-01T23:59:59.000Z

142

Chemico-Biological Interactions 166 (2007) 264276 Chemical process-based reconstruction of exposures for an  

E-Print Network [OSTI]

, the chloroprene (CD) and vinyl chloride monomer (VCM) exposures were modeled for plant specific job title classes to chloroprene (CD) and vinyl chloride monomer (VCM), the historical exposure levels were reconstructed of exposures for an epidemiological study Part II. Estimated exposures to chloroprene and vinyl chloride Nurtan

Illinois at Chicago, University of

143

Poly(vinyl alcohol) gel sublayers for reverse osmosis membranes. I. Insolubilization by acid-catalyzed dehydration  

SciTech Connect (OSTI)

Both flat-sheet and tubular composite reverse osmosis (RO) membranes were prepared by depositing aqueous solutions of poly(vinyl alcohol) (PVA) and a dehydration catalyst on asymmetric poly(arylether sulfone) (PES) substrate membranes. The PVA coatings were insolubilized by heat treatment to create stable hydrophilic gel-layer membranes. The influence of variables such as PVA concentration, catalyst concentration, curing time, and curing temperature was investigated. It was shown that a simple manipulation of one or two variables could lead to membranes with widely differing salt retention and water permeability characteristics. The insolubilized PVA coatings were intended to serve as hydrophilic gel sublayers on which ultra thin salt-retention barriers could ultimately be formed by interfacial polycondensation. For this purpose, high-flux gel layers were required, whereas salt-retention capabilities were not regarded as important. However, the promising salt retentions obtained as 2 MPa (up to 85% NaCl retention and 92% MgSO[sub 4] retention) showed that some of these PES-PVA composite membranes could function as medium-retention, medium-flux RO membranes, even in the absence of an interfacially formed salt-retention barrier.

Immelman, E.; Sanderson, R.D.; Jacobs, E.P.; Van Reenan, A.J. (Univ. of Stellenbosch, (South Africa). Inst. of Polymer Science)

1993-11-10T23:59:59.000Z

144

Self-supported poly(methyl methacrylate–acrylonitrile–vinyl acetate)-based gel electrolyte for lithium ion battery  

Science Journals Connector (OSTI)

Self-supported gel polymer electrolyte (GPE) was prepared based on copolymer, poly(methyl methacrylate–acrylonitrile–vinyl acetate) (P(MMA–AN–VAc)). The copolymer P(MMA–AN–VAc) was synthesized by emulsion polymerization and the copolymer membrane was prepared through phase inversion. The structure and the performance of the copolymer, the membrane and the GPE were characterized by FTIR, NMR, SEM, XRD, DSC/TG, LSV, CA, and EIS. It is found that the copolymer was formed through the breaking of double bond CC in each monomer. The membrane has low crystallinity and has low glass transition temperature, 39.1 °C, its thermal stability is as high as 310 °C, and its mechanical strength is improved compared with P(MMA–AN). The GPE is electrochemically stable up to 5.6 V (vs. Li/Li+) and its conductivity is 3.48 × 10?3 S cm?1 at ambient temperature. The lithium ion transference number in the GPE is 0.51 and the conductivity model of the GPE is found to obey the Vogel–Tamman–Fulcher (VTF) equation.

Y.H. Liao; D.Y. Zhou; M.M. Rao; W.S. Li; Z.P. Cai; Y. Liang; C.L. Tan

2009-01-01T23:59:59.000Z

145

Additive Screen HTTM -HR2-138 Scoring Sheet 1. (A1) 0.1 M Barium Chloride  

E-Print Network [OSTI]

Praseodymium (III) Acetate 15. (B3) 1.0 M Ammonium Sulfate 16. (B4) 1.0 M Potassium Chloride 17. (B5) 1.0 M Lithium Chloride 18. (B6) 2.0 M Sodium Chloride 19. (B7) 0.5 M Sodium Fluoride 20. (B8) 1.0 M Sodium

Hill, Chris

146

Effect of chloride salts, curing compounds and heating and freezing on Trichinella spiralis in pork products  

E-Print Network [OSTI]

shoulders were used to make linked pork sausage. Phase one of this study used chloride salt replacements calculated to an ionic strength equivalent to that of sodium chloride (2, 5/). Phase two of this study consisted of sodium chloride replace- ments... to determine the effect of pumping ingredients on the destruction of trichinae during freezing and storage. In phase one of experiment one, the addition of 75 or 150 ppm NO2 had no effect (P&0. 05) on pH of sausages, regardless of chlorzde salt used...

Kayfus, Timothy Jon

2012-06-07T23:59:59.000Z

147

Methylene chloride exposure and birthweight in Monroe County, New York  

SciTech Connect (OSTI)

This study examined the relationship between birthweight and exposure to emissions of methylene chloride (DCM) from manufacturing processes of the Eastman Kodak Company at Kodak Park in Rochester, Monroe County, New York. County census tracts were categorized as exposed to high, moderate, low or no DCM based on the Kodak Air Monitoring Program (KAMP) model, a theoretical dispersion model of DCM developed by Eastman Kodak Company. Birthweight and information on variables known to influence birthweight were obtained from 91,302 birth certificates of white singleton births to Monroe County residents from 1976 to 1987. No significant adverse effects of exposure to DCM on birthweight were found. Adjusted birthweight in high exposure census tracts was 18.7 g less than in areas with no exposure (95% confidence interval for the difference between high and no exposure - 51.6, 14.2 g). Problems inherent in the method of estimation of exposure, which may decrease power or bias the results, are discussed. Better methods to estimate exposure to emissions from multiple industrial point sources are needed.

Bell, B.P.; Franks, P.; Hildreth, N.; Melius, J. (Department of Family Medicine, University of Rochester School of Medicine and Dentistry, New York (USA))

1991-06-01T23:59:59.000Z

148

Conversion of waste polyvinyl chloride (PVC) to useful chemicals  

SciTech Connect (OSTI)

Developments of recycling technologies are expected one of the most important keys for saving energy and resources, and minimization impact for environment. For instance, combustion of waste for power generation and conversion of plastics into liquid fuels have been studying for thermal energy recycling. However, PVC has been excepted from the most of these experiments. Because, heat of combustion of PVC is almost a half of other plastics, hydrogen chloride, which is produced at low temperature, corrodes the combustion chamber, and PVC causes coking reaction during pyrolysis of plastics. Numerous investigations have been conducted on degradation of PVC. However, most of these experiments were done to improve heat resistance of PVC or to study reaction mechanism of PVC degradation. Pyrolysis of PVC into liquid products have been studying since 1960`s from a view of environmental protection. Recently, Y. Maezawa et al. reported PVC was converted into oil at 600 T with sodium hydroxide. However, more than 50 % of hydrocarbon fraction of PVC was converted to residue and gas in their experiment. We are going to develop a new technology to convert of PVC into useful chemicals or liquid fuels at high efficiency by using hydrogen donor solvent.

Kamo, T.; Yamamoto, Y.; Miki, K.; Sato, Y. [National Institute for Resources and Environment, Tsukuba-shi, Ibaraki (Japan)

1995-12-31T23:59:59.000Z

149

Tolerance Test of Eisenia Fetida for Sodium Chloride  

SciTech Connect (OSTI)

Saltwater spills that make soil excessively saline often occur at petroleum exploration and production (E&P) sites and are ecologically damaging. Brine scars appear when produced water from an E&P site is spilled onto surrounding soil, causing loss of vegetation and subsequent soil erosion. Revegetating lands damaged by brine water can be difficult. The research reported here considers earthworms as a bioremedial treatment for increasing the salt mobility in this soil and encouraging plant growth and a healthy balance of soil nutrients. To determine the practical application of earthworms to remediate brine-contaminated soil, a 17-d test was conducted to establish salt tolerance levels for the common compost earthworm (Eisenia fetida) and relate those levels to soil salinity at brine-spill sites. Soil samples were amended with sodium chloride in concentrations ranging from 1 to 15 g/kg, which represent contamination levels at some spill sites. The survival rate of the earthworms was near 90% in all tested concentrations. Also, reproduction was noted in a number of the lower-concentration test replicates but absent above the 3-g/kg concentrations. Information gathered in this investigation can be used as reference in further studies of the tolerance of earthworms to salty soils, as results suggest that E. fetida is a good candidate to enhance remediation at brine-damaged sites.

Kerr, M.; Stewart, A.J.

2003-01-01T23:59:59.000Z

150

Chloride, bromide and iodide scintillators with europium doping  

DOE Patents [OSTI]

A halide scintillator material is disclosed where the halide may comprise chloride, bromide or iodide. The material is single-crystalline and has a composition of the general formula ABX.sub.3 where A is an alkali, B is an alkali earth and X is a halide which general composition was investigated. In particular, crystals of the formula ACa.sub.1-yEu.sub.yI.sub.3 where A=K, Rb and Cs were formed as well as crystals of the formula CsA.sub.1-yEu.sub.yX.sub.3 (where A=Ca, Sr, Ba, or a combination thereof and X=Cl, Br or I or a combination thereof) with divalent Europium doping where 0.ltoreq.y.ltoreq.1, and more particularly Eu doping has been studied at one to ten mol %. The disclosed scintillator materials are suitable for making scintillation detectors used in applications such as medical imaging and homeland security.

Zhuravleva, Mariya; Yang, Kan

2014-08-26T23:59:59.000Z

151

Development of high performance sodium/metal chloride cells  

SciTech Connect (OSTI)

Sodium/metal chloride (MCl{sub 2}) cells and batteries are being studied at Argonne National Laboratory (ANL) for stationary energy storage and transportation applications. The work is being directed toward (1) development of thin, high-capacity density electrodes and inexpensive {beta}{double prime}-alumina-glass composite electrolyte materials to replace {beta}{double prime}-alumina and (2) the development of models to project MCl{sub 2} system performances. In our NiCl{sub 2} electrode work, the effects of charge/discharge rates, temperature, electrode porosity, and sulfur content on electrode performance were determined using annular electrodes fabricated in the uncharged state. Of all electrode design parameters mentioned, electrode porosity, sulfur content, and charge rates have the greatest effect on utilization and on the area-specific impedance. The {beta}{double prime}-alumina-glass composite electrolyte work has led to the development of a highly conductive (3.3 {times} 10{sup {minus}2}S/cm at 250{degree}C) composite material. Preliminary modeling studies indicate that the performance of the MCl{sub 2} electrodes can be fitted by a mathematic model very successfully and that cell electrolyte configurations of either multiple tubes joined at a header or compartmented flat structures of either {beta}{double prime}-alumina or of the composite material would result in high-performance batteries with power-to-energy ratios of about 5. 15 refs., 8 figs., 4 tabs.

Vissers, D.R.; Bloom, I.D.; Hash, M.C.; Redey, L.; Hammer, C.L.; Dees, D.W.; Nelson, P.A.

1990-01-01T23:59:59.000Z

152

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New  

Open Energy Info (EERE)

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Mexico- A 36Cl Study Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Mexico- A 36Cl Study Abstract The Valles caldera in New Mexico hosts a high-temperature geothermal system, which is manifested in a number of hot springs discharging in and around the caldera. In order to determine the fluid pathways and the origin of chloride in this system, we measured 36Cl/Cl ratios in waters from high-temperature drill holes and from surface springs in this region. The waters fall into two general categories: recent meteoric water samples with low Cl- concentrations (< 10 mg/L) and relatively high 36Cl/Cl ratios

153

Iron (III) Chloride doping of large-area chemical vapor deposition graphene  

E-Print Network [OSTI]

Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

Song, Yi, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

154

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

the loss of Zn to the coal ash (which appears to invoLve ionhydrocracking is the catalyst/coal ash interaction typifiedof chlorides of metals found in coal ash is of interest, and

Holten, R.R.

2010-01-01T23:59:59.000Z

155

Monolayer cuprous chloride dispersed on pillared clays for olefin-paraffin separations by ?-complexation  

Science Journals Connector (OSTI)

New adsorbents containing cuprous chloride dispersed on pillared interlayered clays (PILC) have been prepared and studied for olefin-paraffin separations. High surface-area PILC's were synthesized with different ...

Linda S. Cheng; Ralph T. Yang

1995-01-01T23:59:59.000Z

156

E-Print Network 3.0 - anhydrous magnesium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

magnesium ion concentration dependence of strand exchange... M Tris-acetate or Tris-HCI (pH 7.5), IO mM magnesium acetate or magnesium chloride, 3.7% glycerol, 1 m... and...

157

Multiple pathways are involved in radioprotective effects of lithium chloride in the hippocampal neurons  

Science Journals Connector (OSTI)

...Volume 47, 2006 Multiple pathways are involved in radioprotective effects of lithium chloride in the hippocampal neurons Dinesh Kumar Thotala Eugenia M. Yazlovitskaya Allie Fu Dennis E. Hallahan Vanderbilt university, Nashville, TN [Proc Amer Assoc...

Dinesh Kumar Thotala; Eugenia M. Yazlovitskaya; Allie Fu; and Dennis E. Hallahan

2006-04-15T23:59:59.000Z

158

CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

3% Zn and 14% CH oH (50 g coal 9 300 g melt) Atomic TempVermeulen, "High-Yield Coal Conversion in a Zinc Chloride/H. Shinn, and T. Vermeulen, "Coal Lic;uefaction Catalysis by

Vermeulen, T.

2012-01-01T23:59:59.000Z

159

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate Solutions  

E-Print Network [OSTI]

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate. The copper exchange capacity (CuEC) and Na-Cu exchange reactions on Wyoming montmo- rillonite were studied

Sparks, Donald L.

160

Density, Viscosity, Refractive Index and Conductivity of 1-Allyl-3-methylimidazolium Chloride + Water Mixture  

Science Journals Connector (OSTI)

Density, Viscosity, Refractive Index and Conductivity of 1-Allyl-3-methylimidazolium Chloride + Water Mixture† ... The data obtained will play an important supplementary function in completion of the ionic liquids database. ...

Di Wu; Bo Wu; Yu M. Zhang; Hua P. Wang

2009-10-22T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Determination of transport parameters from coincident chloride and tritium plumes at the Idaho National Engineering Laboratory  

E-Print Network [OSTI]

wells from the ICPP tritium plume. 41 42 Sets of simulated tritium concentrations for selected wells. 44 Insensitivity of steady-state concentrations to the longitudinal dispersivity nx for an ideal radionuclide plume... the ICPP chloride plume. Simulated contour map of the ICPP chloride plume. 34 38 12 Iteration diagram for Y source size versus the trans- verse dispersivity ny from the ICPP tritium plume. Total monthly quantities of (a) tritium and (b) waste- water...

Fryar, Alan Ernest

2012-06-07T23:59:59.000Z

162

Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes  

DOE Patents [OSTI]

The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

1993-01-01T23:59:59.000Z

163

Raman spectroscopic studies of chemical speciation in calcium chloride melts  

SciTech Connect (OSTI)

Raman spectroscopy was applied to CaCl2 melts at 900 degrees C under both non-electrolyzed and electrolyzed conditions. The later used titania cathodes supplied by TIMET, Inc. and graphite anodes. Use of pulse-gating to collect the Raman spectra successfully eliminated any interference from black-body radiation and other stray light. The spectrum of molten CaCl2 exhibited no distinct, resolvable bands that could be correlated with a calcium chloride complex similar to MgCl42- in MgCl2 melts. Rather, the low frequency region of the spectrum was dominated by a broad “tail” arising from collective oscillations of both charge and mass in the molten salt “network.” Additions of both CaO and Ca at concentrations of a percent or two resulted in no new features in the spectra. Addition of CO2, both chemically and via electrolysis at concentrations dictated by stability and solubility at 900 degrees C and 1 bar pressure, also produced no new bands that could be correlated with either dissolved CO2 or the carbonate ion. These results indicated that Raman spectroscopy, at least under the conditions evaluated in the research, was not well suited for following the reactions and coordination chemistry of calcium ions, nor species such as dissolved metallic Ca and CO2 that are suspected to impact current efficiency in titanium electrolysis cells using molten CaCl2. Raman spectra of TIMET titania electrodes were successfully obtained as a function of temperature up to 900 degrees C, both in air and in-situ in CaCl2 melts. However, spectra of these electrodes could only be obtained when the material was in the unreduced state. When reduced, either with hydrogen or within an electrolysis cell, the resulting electrodes exhibited no measurable Raman bands under the conditions used in this work.

Windisch, Charles F.; Lavender, Curt A.

2005-02-01T23:59:59.000Z

164

Reaction of Cp*(CO)2ReRe(CO)2Cp* with Alkynes Produces Dimetallacyclopentenones Cp*(CO)2Re(?-?1,?3-CRCR‘CO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes  

Science Journals Connector (OSTI)

Reaction of Cp*(CO)2ReRe(CO)2Cp* with Alkynes Produces Dimetallacyclopentenones Cp*(CO)2Re(?-?1,?3-CRCR‘CO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes ... Cp*(CO)2ReRe(CO)2Cp* reacted with terminal alkynes HC?CR to produce dimetallacyclopentenones Cp*(CO)2Re(?-?1,?3-CHCRCO)Re(CO)Cp*. ... Protonation of the dimetallacyclopentenones with CF3CO2H produced (?-vinyl)dirhenium cations [Cp*(CO)2Re(?-?1,?2-CHCHR)Re(CO)2Cp*]+. ...

Charles P. Casey; Ronald S. Cariño; Hiroyuki Sakaba

1997-02-04T23:59:59.000Z

165

Chloride-mass-balance for predicting increased recharge after land-use change  

SciTech Connect (OSTI)

The chloride-mass-balance (CMB) method has been used extensively to estimate recharge in arid and semi-arid environments. Required data include estimates of annual precipitation, total chloride input (from dry fallout and precipitation), and pore-water chloride concentrations. Typically, CMB has been used to estimate ancient recharge but recharge from recent land-use change has also been documented. Recharge rates below a few mm/yr are reliably detected with CMB; however, estimates above a few mm/yr appear to be less reliable. We tested the CMB method against 26 years of drainage from a 7.6-m-deep lysimeter at a simulated waste-burial ground, located on the Department of Energy s Hanford Site in southeastern Washington State, USA where land-use change has increased recharge rates. Measured drainage from the lysimeter for the past 26 years averaged 62 mm/yr. Precipitation averaged 190 mm/yr with an estimated chloride input of 0.225 mg/L. Initial pore-water chloride concentration was 88 mg/L and decreased to about 6 mg/L after 26 years, while the drainage water decreased to less than 1 mg/L. A recharge estimate made using chloride concentrations in drain water was within 20 percent of the measured drainage rate. In contrast, recharge estimates using 1:1 (water: soil) extracts were lower than actual by factors ranging from 2 to 8 or more. The results suggest that when recharge is above a few mm/yr, soil water extracts can lead to unreliable estimates of recharge. For conditions of elevated recharge, direct sampling of pore water is the preferred method, because chloride concentrations are often 20 to 50 times higher in directly-sampled pore water than in pore-water extracts.

Gee, G.W.; Zhang, Z.F.; Tyler, S.W.; Albright, W.H.; Singleton, M.J.

2004-02-23T23:59:59.000Z

166

Free energy, enthalpy, and entropy changes for the transference of zinc chloride from enthylene glycol to water solutions  

E-Print Network [OSTI]

in ethylene glycol is coupled with a silver-silver chloride half-cell, also containing zinc chloride dissolved in ethylene glycol, and if a similar cell with zinc chloride in aqueous solution are put back to back by use of a common amalgam reservoir...FREE ENERGY, ENTlDKPY, AND ENTROPY CHANGES FOR THE TRANCE OF ZINC CHLORIDE FROM ETHYLENE GLYCOL TO WATER SOLUTIONS A Thesis JOHN NICHOLAS'8 LOMONTE Submitted to the Graduate School of' the Agricultural and. Mechanical College of' Texas...

Lomonte, John Nicholas

1960-01-01T23:59:59.000Z

167

Northern Tool + Equipment Find the Right Fitting for Your Pressure Washer at Northern Tool! NorthernTool.com/PressureWashers Pristine Pressure Pressure/power washing in Maryland Vinyl siding cleaned, decks cleaned www.pristinepressure.com  

E-Print Network [OSTI]

ability to clean while saving on our most important resources, water and energy." In recognition! NorthernTool.com/PressureWashers Pristine Pressure Pressure/power washing in Maryland Vinyl siding cleaned, decks cleaned www.pristinepressure.com Siding Cleaning Bring back the life to your siding! Estimates

Sóbester, András

168

DOEEA-1157 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLOFUNATION OF METHANE:  

Broader source: Energy.gov (indexed) [DOE]

57 57 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLOFUNATION OF METHANE: A BUILDING BLOCK FOR CHEMICALS AND FUELS FROM NATURAL GAS DOW CORNING CORPORATION CARROLLTON, KENTUCKY SEPTEMBER 1996 U.S. DEPARTMENT OF ENERGY PITTSBURGH ENERGY TECHNOLOGY CENTER CUM ~~~~~~~~ DOEEA-1157 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLORINATION OF METHANE: A BUILDING BLOCK FOR CHEMICALS AND FUELS FROM NATURAL GAS DOW CORNING CORPORATION CARROLLTON, KENTUCKY SEPTEMBER 1996 U.S. DEPARTMENT OF ENERGY PITTSBURGH ENERGY TECHNOLOGY CENTER Portions of this document may be illegible in electronic image products. Image are produced from the best available original document. &E/,Etq --,/s7 FINDING OF NO SIGNIFICANT IMPACT FOR THE PROPOSED METHYL CHLORIDE V

169

Current techniques in acid-chloride corrosion control and monitoring at The Geysers  

SciTech Connect (OSTI)

Acid chloride corrosion of geothermal well casings, production piping and power plant equipment has resulted in costly corrosion damage, frequent curtailments of power plants and the permanent shut-in of wells in certain areas of The Geysers. Techniques have been developed to mitigate these corrosion problems, allowing continued production of steam from high chloride wells with minimal impact on production and power generation facilities.The optimization of water and caustic steam scrubbing, steam/liquid separation and process fluid chemistry has led to effective and reliable corrosion mitigation systems currently in routine use at The Geysers. When properly operated, these systems can yield steam purities equal to or greater than those encountered in areas of The Geysers where chloride corrosion is not a problem. Developments in corrosion monitoring techniques, steam sampling and analytical methodologies for trace impurities, and computer modeling of the fluid chemistry has been instrumental in the success of this technology.

Hirtz, Paul; Buck, Cliff; Kunzman, Russell

1991-01-01T23:59:59.000Z

170

An investigation of the transfer of alkali metal chlorides from dimethyl sulfoxide to water  

E-Print Network [OSTI]

-to-back' with water as the solvent in one cell and a non- aqueous solvent in the other. The two cells used in this investigation were each composed of silver-silver chloride electrodes in the same solution with dropping alkali metal amalgam electrodes. The solute.... The dropping amalgam electrodes are written only once since they were connected by a common amalgam reservoir. When the external circuit between the two silver-silver chloride electrodes was closed a current flowed and the net result oi the electrode...

Williams, Roger

1966-01-01T23:59:59.000Z

171

A description of the vapor phase in the lithium thionyl chloride battery  

E-Print Network [OSTI]

A DESCRIPTION OF TIIE YAPOP, PHASE IN THF. LITHIUM THIONYI. CHLORIDE BATTERY A Thesis by RODOLFO MORALES, JR. Submitted to the Graduate College of Texas AEzM University in partial fulfrHment of the requirement for the degree oi' MASTER... OF SCIENCE August 1988 Major Subject: Chemical Engineering A DESCRIPTION OF THE VAPOR PHASE IN THE LITHIUM THIONYL CHLORIDE BATTERY A Thesis bv RODOLFO 'vIORALES, JR. Approved as to style and content by: Ralph E. White (Chairman of Committee) James...

Morales, Rodolfo

1988-01-01T23:59:59.000Z

172

Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene  

SciTech Connect (OSTI)

We examine the time-resolved resonance energy transfer of excitons from single n-butyl amine-bound, chloride-terminated nanocrystals to two-dimensional graphene through time-correlated single photon counting. The radiative biexponential lifetime kinetics and blinking statistics of the individual surface-modified nanocrystal elucidate the non-radiative decay channels. Blinking modification as well as a 4× reduction in spontaneous emission were observed with the short chloride and n-butylamine ligands, probing the energy transfer pathways for the development of graphene-nanocrystal nanophotonic devices.

Ajayi, O. A., E-mail: oaa2114@columbia.edu, E-mail: cww2104@columbia.edu; Wong, C. W., E-mail: oaa2114@columbia.edu, E-mail: cww2104@columbia.edu [Optical Nanostructures Laboratory, Center for Integrated Science and Engineering, Solid-State Science and Engineering, Columbia University, New York, New York 10027 (United States); Department of Mechanical Engineering, Columbia University, New York, New York 10027 (United States); Anderson, N. C.; Wolcott, A.; Owen, J. S. [Department of Chemistry, Columbia University, New York, New York 10027 (United States); Cotlet, M. [Brookhaven National Laboratory, Upton, New York, New York 11973 (United States); Petrone, N.; Hone, J. [Department of Mechanical Engineering, Columbia University, New York, New York 10027 (United States); Gu, T.; Gesuele, F. [Optical Nanostructures Laboratory, Center for Integrated Science and Engineering, Solid-State Science and Engineering, Columbia University, New York, New York 10027 (United States)

2014-04-28T23:59:59.000Z

173

The influence of chloride ions on the corrosion of copper in soil  

E-Print Network [OSTI]

THE INFLUENCE OF CHLORIDE IONS ON THE CORROSION OF COPPER IN SOIL A Thesis by RA JU K . H I RAN I Submitted to the Graduate College of Texas ASM University in Partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May... 1980 Major Subject: Chemical Engineering THE INFLUENCE OF CHLORIDE IONS ON THE CORROSION OF COPPER IN SOIL A Thesis by RAJU K. HIRANI Approved as to style and content by: (Chairman of Committee) '(2. (Member ) (Member) (Member) ( ea o Dep...

Hirani, Raju K

2012-06-07T23:59:59.000Z

174

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride  

Science Journals Connector (OSTI)

...photochemically active gases. Particularly surprising...in medieval churches in Cyprus . Atmos Environ 41 : 9018...of inorganic chlorine gases other than hydrogen chloride...from anthropogenic and natural sources: Reactive chlorine...Christian TJ ( 2009 ) Trace gas and particle emissions from domestic...

Jonathan D. Raff; Bosiljka Njegic; Wayne L. Chang; Mark S. Gordon; Donald Dabdub; R. Benny Gerber; Barbara J. Finlayson-Pitts

2009-01-01T23:59:59.000Z

175

Evaluation of toxicity and biodegradability of choline chloride based deep eutectic solvents  

Science Journals Connector (OSTI)

Abstract Deep eutectic solvents (DESs) have been dramatically expanding in popularity as a new generation of environmentally friendly solvents with possible applications in various industrial fields, but their ecological footprint has not yet been thoroughly investigated. In the present study, three choline chloride-based \\{DESs\\} with glucose, glycerol and oxalic acid as hydrogen bond donors were evaluated for in vitro toxicity using fish and human cell line, phytotoxicity using wheat and biodegradability using wastewater microorganisms through closed bottle test. Obtained in vitro toxicity data on cell lines indicate that choline chloride: glucose and choline chloride:glycerol possess low cytotoxicity (EC50>10 mM for both cell lines) while choline chloride:oxalic acid possess moderate cytotoxicity (EC50 value 1.64 mM and 4.19 mM for fish and human cell line, respectively). Results on phytotoxicity imply that tested \\{DESs\\} are non-toxic with seed germination EC50 values higher than 5000 mg l?1. All tested \\{DESs\\} were classified as?readily biodegradable? based on their high levels of mineralization (68–96%). These findings indicate that \\{DESs\\} have a green profile and a good prospect for a wider use in the field of green technologies.

Kristina Radoševi?; Marina Cvjetko Bubalo; Višnje Gaurina Sr?ek; Dijana Grgas; Tibela Landeka Dragi?evi?; Ivana Radoj?i? Redovnikovi?

2015-01-01T23:59:59.000Z

176

EFFECT OF INITIAL SCARIFICATION AND OVERLAY TREATMENT1 TIMING ON CHLORIDE CONCENTRATIONS  

E-Print Network [OSTI]

.nolan@kiewit.com and Dale P. Bentz Chemical Engineer Inorganic Materials Group Materials and Construction Research Division 8615 Gaithersburg, MD 20899 (301) 975-5865 Voice (301) 990-6891 Fax dale.bentz@nist.gov Transportation of reinforcing steel due to chloride ingress. Given the need to develop guidelines for the initial timing of SO

Bentz, Dale P.

177

Hydrogen and chloride ions effects on the automobile interstitial-free steel corrosion  

E-Print Network [OSTI]

1 Hydrogen and chloride ions effects on the automobile interstitial-free steel corrosion L.Q. Guo 1 abilities of deep formability and fatigue resistance [1,2]. As the main material of the automobile's body. The high susceptibility to atmospheric corrosion limits the automobile steel applications. Although

Volinsky, Alex A.

178

Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies  

E-Print Network [OSTI]

1 Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies is introduced which employs a linear relationship between nanotube cohesive energies determined via Density between ionic and cohesive bonding energies indicate that, as the nanotubes become longer, ionic bonding

Hanusa, Christopher

179

Photochemistry of Matrix-Isolated and Thin Film Acid Chlorides: Quantum Yields and Product Structures  

E-Print Network [OSTI]

the differences between gas- and condensed-phase photochemistry strengthens our understanding of many, and well-known gas-phase reaction mechanisms are often modified in the condensed phase or completely the photoreaction of condensed acid chloride samples by comparison of reaction quantum yields for acetyl (CH3COCl

Ellison, Barney

180

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion of Silver  

E-Print Network [OSTI]

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion The corrosion of Ag contaminated with NaCl particles in gaseous environments containing humidity and ozone analyzed using a coulometric reduction technique. The atmospheric corrosion of Ag was greatly accelerated

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride  

E-Print Network [OSTI]

Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride Jae-Yong Ryu, James limited in- vestigation of dibenzo-p-dioxin (DD) chlorination by CuCl2 to form chlorinated DD (CDD 2003 Elsevier Science Ltd. All rights reserved. Keywords: Dibenzofuran; Dibenzo-p-dioxin; CDF; CDD

Mulholland, James A.

182

Aqueous phase catalytic conversion of agarose to 5-hydroxymethylfurfural by metal chlorides  

SciTech Connect (OSTI)

Abstract: 5-HMF is a key intermediate for producing chemicals and fuels that can substitute for today’s petroleum-derived feedstocks. A series of metal chlorides, including NaCl, CaCl2, MgCl2, ZnCl2, CuCl2, FeCl3, and CrCl3, were comparatively investigated to catalyze agarose degradation for production of 5-HMF at temperature 180 oC, 200 oC, and 220 oC for 30 min, with catalyst concentration of 0.5% (w/w), 1% (w/w) and 5% (w/w), and substrate concentration of 2% (w/w). Our results revealed that alkali metal chlorides and alkali earth metal chlorides such as NaCl, CaCl2 and MgCl2 gave better 5-HMF yield compared with transition metal chlorides including ZnCl2, CrCl3, CuCl2 and FeCl3. 1% (w/w) MgCl2 was the more favorable catalyst for 5-HMF production from agarose, and resulted in 40.7% 5-HMF yield but no levulinic acid or lactic acid at 200 oC, 35 min. The reaction pathways of agarose degradation catalyzed by MgCl2 were also discussed.

Yan, Lishi; Laskar, Dhrubojyoti D.; Lee, Suh-Jane; Yang, Bin

2013-12-14T23:59:59.000Z

183

Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators  

E-Print Network [OSTI]

Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators Reza Loloee1@msu.edu Abstract--Dissolved oxygen concentration is considered the most important water quality variable in fish culture. Reliable and continuous (24/7) oxygen monitoring of dissolved oxygen (DO) in the 1 ­ 11 mg

Ghosh, Ruby N.

184

New route for degradation of chlorinated ethylenes in exhaust gases from ground water remediation  

Science Journals Connector (OSTI)

On the basis of an approximate finite-size description, a UV photoreactor was devised and constructed for studying the photooxidation of the chlorinated ethylenes perchloroethylene (PCE), trichloroethylene (TCE), 1,2-dichloroethylenes (DCE), vinyl chloride (VC) and several saturated chlorinated hydrocarbons (CHC). In the cases of PCE and TCE, the efficiency of the photooxidation using irradiation by a 222 nm excimer lamp and subsequent photolysis for the initiation of the process was found to be sufficiently high so that a scaling up to an industrial purification plant of exhaust gases from ground water remediation can be hopefully envisaged. Thanks to consecutive reactions with the chain-sustaining chlorine atoms, this degradation route proves capable of decomposing the other chlorinated ethylenes which are not amenable to photolysis in a direct way. For saturated CHC the utilisability of this approach is limited.

Lutz Prager; Eberhard Hartmann

2001-01-01T23:59:59.000Z

185

Ultraviolet irradiation selectively disrupts the gamma-aminobutyric acid/benzodiazepine receptor-linked chloride ionophore  

SciTech Connect (OSTI)

The ability of UV light to affect radioligand binding and 36Cl-uptake at the gamma-aminobutyric acidA (GABAA) receptor-chloride channel complex was examined. Exposure to 302 nm UV light produced a rapid (t1/2 = 4 min) reduction in (35S)t-butylbicyclo-phosphorothionate binding (assayed in the presence of 200 mM chloride) to sites associated with the GABAA receptor-coupled chloride ionophore. Saturation analysis revealed that this effect could be attributed entirely to a decrease in the maximum number of binding sites. Exposure to UV irradiation at lower (254 nm) and higher (366 nm) wavelengths also inhibited (35S)t-butylbicy-clophosphorothionate binding, but the respective rates of inactivation were 8- and 27-fold slower, compared with 302 nm. Other anion-dependent interactions at the GABAA receptor complex were disrupted in a similar manner. In the absence of permeant anion, (3H)flunitrazepam binding to benzodiazepine receptors was unaffected by 302 nm UV irradiation, whereas chloride-enhanced (3H)flunitrazepam binding was inhibited markedly. In the presence of 250-500 mM chloride, (3H)methyl-6,7-dimethoxy-4-ethyl-beta-carboline-3-carboxylate binding to benzodiazepine receptors was also inhibited after UV exposure. Basal 36Cl- uptake into synaptoneurosomes was nearly doubled after 15 min of exposure to 302 nm light, whereas pentobarbital- and muscimol-stimulated 36Cl- uptake were reduced significantly. UV irradiation at 302 nm appears to disrupt selectively the anion-dependent functional interactions at the GABAA receptor complex. The apparent wavelength specificity suggests that the gating structure (channel) may contain tryptophan and/or tyrosine residues vital to the regulation of anion movement through the ionophore portion of this supramolecular receptor-ion channel complex.

Evoniuk, G.; Moody, E.J.; Skolnick, P. (National Institute of Diabetes and Digestive and Kidney Diseases, Bethesda, MD (USA))

1989-05-01T23:59:59.000Z

186

Rapid Fixation of Methylene Chloride by a Macrocyclic Amine Jung-Jae Lee, Keith J. Stanger, Bruce C. Noll, Carlos Gonzalez, Manuel Marquez, and  

E-Print Network [OSTI]

with the macrocyclic ether oxygens.4 The macrocyclic nitrogen attacks the methylene chloride with a classic SN2 by methylene chloride, but the reaction is very slow with half-lives of many weeks to several months.2 Here, we to give the quaternary ammonium salt 2. Initially, we studied the reaction using methylene chloride

Smith, Bradley D.

187

Two-dimensional free-energy surface on the exchange reaction of alkyl chloride/chloride using the QM/MM-MC method  

SciTech Connect (OSTI)

Two-dimensional free-energy surfaces are calculated for alkyl chloride/chloride exchange/inversion reactions: Cl- + RCl (R = Me and t-Bu) surrounded by one hundred H2O molecules as a model of solvent. The methodology of free-energy calculation by perturbation theory based on a mixed-Hamiltonian model (QM/MM) combined with Monte Carlo sampling of the solvent configurations was used to obtain the changes in solvation free energy. We devised a special procedure to analyze the two-dimensional free-energy surfaces to gain unique insight into the differences in the reaction mechanisms between the two systems. The inversion reaction path for R = t-Bu on the free-energy surface is found to proceed in an asynchronous way within a concerted framework via the ion-pair region. This is in contrast to the R = Me system that proceeds as a typical SN2 reaction. This work was supported by the U.S. Department of Energy's (DOE) Office of Basic Energy Sciences, Chemical Sciences program. The Pacific Northwest National Laboratory is operated by Battelle for DOE.

Ohisa, M.; Yamataka, H.; Dupuis, Michel; Aida, Misako

2007-12-05T23:59:59.000Z

188

Uses of chloride/bromide ratios in studies of potable water  

SciTech Connect (OSTI)

In natural ground water systems, both chlorine and bromine occur primarily as monovalent anions, chloride and bromide. Although dissolution or precipitation of halite, biological activity in the root zone, anion sorption, and exchange can affect chloride/bromide ratios in some settings, movement of the ions in potable ground water is most often conservative. Atmospheric precipitation will generally have mass ratios between 50 and 150; shallow ground water, between 100 and 200; domestic sewage, between 300 and 600; water affected by dissolution of halite, between 1,000 and 10,000; and summer runoff from urban streets, between 10 and 100. These, and other distinctive elemental ratios, are useful in the reconstruction of the origin and movement of ground water, as illustrated by case studies investigating sources of salinity in ground water from Alberta, Kansas, and Arizona, and infiltration rates and pathways at Yucca Mountain, Nevada.

Davis, S.N. [Univ. of Arizona, Tucson, AZ (United States). Dept. of Hydrology and Water Resources; Whittemore, D.O. [Univ. of Kansas, Lawrence, KS (United States). Kansas Geological Survey; Fabryka-Martin, J. [Los Alamos National Lab., NM (United States)

1998-03-01T23:59:59.000Z

189

Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural  

SciTech Connect (OSTI)

Sugars were converted to hydroxymethylfurfural (HMF) at high yield in ionic liquids without the addition of Bronsted acids. Very small amount of certain metal halides significantly reduced the fructose dehydration barrier in ionic liquids producing HMF at high yields. Most remarkably, glucose, a common sugar molecule, was selectively converted to HMF in good yield in ionic liquids containing a small amount of CrCl2. Thus CrCl2 is unique among metal chlorides tested for its effectiveness in both isomerizing glucose as well as dehydrating fructose. Only negligble amount of levulinic acid was formed in the reactions. The catalytic activity of metal chlorides for sugar conversion in ionic liquids is perhaps related to hydroxyl group of the sugar forming metal complexes with the unsaturated metal center.

Zhao, Haibo; Holladay, John E.; Brown, Heather M.; Zhang, Z. Conrad

2007-06-15T23:59:59.000Z

190

Evaporation of water from sodium chloride solutions under controlled climatic conditions  

E-Print Network [OSTI]

EVAPORATION OF WATER FROM SODIUM CELORIDE SOLUTIONS UNDER CONTROLLED CLIMATIC CONDITIONS A Thesis by Jaroy Moore Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE January 1967 Haj or Subject: Soil Physics EVAPORATION OF WATER FROM SODIUM CHLORIDE SOLUTIONS UNDER CONTROLLED CLIMATIC CONDITIONS A Thesis by Jaroy Moore Approved as to style and content by: (Ch+jman of Committee) (Member) (, j. (Head...

Moore, Jaroy

2012-06-07T23:59:59.000Z

191

Low effluent processing in the pulp and paper industry: Electrodialysis for continuous selective chloride removal  

SciTech Connect (OSTI)

Pollution prevention is currently a major focus of the United States pulp and paper industry. Significant process changes are inevitable to implement low effluent processing. The kraft pulping process is prevalent for the production of wood pulp. About 50 million tons of wood pulp are produced annually in the United States alone using the kraft process. Water consumption is currently roughly between 30 and 200 m{sup 3} of water per ton of air dry bleached kraft pulp. In-process recycling of water is now being implemented by many mills to reduce the use of increasingly scarce water resources and to reduce the need for waste-water treatment. Mass balance considerations and industrial experience show that nonprocess elements, which are detrimental to the kraft process, such as chloride and potassium, will quickly build up once water use is significantly reduced. High concentrations of chloride and potassium can cause corrosion and lead to more frequent mill shutdowns due to fouling of heat exchanger surfaces in the kraft recovery furnace. Electrodialysis will monovalent selective anion and cation exchange membranes was explored here to selectively remove chlorine as sodium and potassium chloride from a feed stream with very high ionic strength. Experiments with model solutions and extended tests with the actual pulp mill materials were performed. Very good selectivities and current efficiencies were observed for chloride over sulfate. The outstanding performance of the process with actual mill materials containing organic and inorganic contamination shows great promise for rapid transfer to the pilot scale. This work is an example of the usefulness of membrane separations as a kidney in low effluent industrial processing.

Pfromm, P.H. [Institute of Paper Science and Technology, Atlanta, GA (United States)

1997-12-01T23:59:59.000Z

192

A study of the reaction between antimony (V) chloride and organic amine hydrochlorides  

E-Print Network [OSTI]

. The mercury turned grey and formed. very small droplets when the reduction was proceeding properly. 12 The addition of a small amount of mercuric iona to the sample solution aided the reduction process for those compounds that were difficult to start... Chloride content of the salts was determined potentio- metrically using a silver indicating electrode and a mercury- mercurous sulfate reference electrode. Duplicate samples of approximately 0. 2 gram of each com- pound, weighed to the nearest 0. 1...

Bier, Harold Dean

1962-01-01T23:59:59.000Z

193

Concrete cover cracking with reinforcement corrosion of RC beam during chloride-induced corrosion process  

SciTech Connect (OSTI)

This paper deals with the evolution of the corrosion pattern based on two beams corroded by 14 years (beam B1CL1) and 23 years (beam B2CL1) of conservation in a chloride environment. The experimental results indicate that, at the cracking initiation stage and the first stage of cracking propagation, localized corrosion due to chloride ingress is the predominant corrosion pattern and pitting corrosion is the main factor that influences the cracking process. As corrosion cracking increases, general corrosion develops rapidly and gradually becomes predominant in the second stage of cracking propagation. A comparison between existing models and experimental results illustrates that, although Vidal et al.'s model can better predict the reinforcement corrosion of beam B1CL1 under localized corrosion, it cannot predict the corrosion of beam B2CL1 under general corrosion. Also, Rodriguez's model, derived from the general corrosion due to electrically accelerated corrosion experiments, cannot match natural chloride corrosion irrespective of whether corrosion is localized or general. Thus, for natural general corrosion in the second stage of cracking propagation, a new model based on the parameter of average steel cross-section loss is put forward to predict steel corrosion from corrosion cracking.

Zhang Ruijin, E-mail: rjzhang@mail.neu.edu.c [Modern Design and Analysis Research Institute, Northeastern University, Shenyang (China); Castel, Arnaud; Francois, Raoul [LMDC - Laboratoire Materiaux et Durabilite des Constructions, Universite de Toulouse, UPS, INSA, Toulouse (France)

2010-03-15T23:59:59.000Z

194

Storage of dissolved inorganic nutrients in seawater: poisoning with mercuric chloride  

Science Journals Connector (OSTI)

Seawater samples were poisoned with mercuric chloride to assess its suitability for the long-term storage measurement of inorganic nutrients. Two series of seawater samples from the open ocean were taken, and nitrate, silicate, phosphate, nitrite and ammonium measured immediately on board. The same samples were poisoned by adding 105 ?g of mercuric chloride per milliliter of sample (total sample volume 50 ml) and measured again after about 1 and 2 years storage. The results show that the poisoning with mercuric chloride is a suitable method for the storage of inorganic nutrients. For nitrate, silicate and phosphate a good accordance was found between the direct measurements and those after 1 and 2 years storage. The results of the determinations coincided with, or were very close to the optimal 1:1 relationship. The variations for nitrite were higher, but due to the generally low concentrations in the oceans these differences will cause no serious problems for the nitrate determination. In contrast, ammonium data, obtained after long storage periods, should be taken with care.

Gerhard Kattner

1999-01-01T23:59:59.000Z

195

Periadolescent oral manganese exposure affects conditioned place preference by cocaine and conditioned place aversion by lithium chloride in rats  

E-Print Network [OSTI]

Manganese neurotoxicity compromises basal ganglia functions that could affect the limbic system and drug sensitivity. Male rats were orally exposed to manganese chloride (0, 100, 200 mg/kg/day Mn) for 15 days starting at postnatal day (PND) 28...

Lee, Samuel Ming Hin

2013-02-22T23:59:59.000Z

196

EFFECT OF CHLORIDE AND SULFATE CONCENTRATION ON PROBABLITY BASED CORROSION CONTROL FOR LIQUID WASTE TANKS- PART IV  

SciTech Connect (OSTI)

A series of cyclic potentiodynamic polarization tests was performed on samples of A537 carbon steel in support of a probability-based approach to evaluate the effect of chloride and sulfate on corrosion susceptibility. Testing solutions were chosen to build off previous experimental results from FY07, FY08, FY09 and FY10 to systemically evaluate the influence of the secondary aggressive species, chloride, and sulfate. The FY11 results suggest that evaluating the combined effect of all aggressive species, nitrate, chloride, and sulfate, provides a consistent response for determining corrosion susceptibility. The results of this work emphasize the importance for not only nitrate concentration limits, but also chloride and sulfate concentration limits as well.

Hoffman, E.

2012-08-23T23:59:59.000Z

197

Firmness and cell wall characteristics of pasteurized jalapeno pepper rings affected by acetic acid, calcium chloride and preheating  

E-Print Network [OSTI]

pasteurization and storage, especially when high acid brines are used. Development of treatments to retard softening may result in a higher quality product. This study was undertaken to investigate the effects of calcium chloride (CaCI2), acetic acid...

Burma, Prashanthi V

2012-06-07T23:59:59.000Z

198

Infrared and visible laser double resonance studies of vibrational energy transfer processes in polyatomic molecules. [Chromyl chloride solutions  

SciTech Connect (OSTI)

A study of the spectroscopy of chromyl chloride (CrO{sub 2}Cl{sub 2} ) in dilute solutions has been initiated. A discussion is given of its spectra and emission bands. 17 refs, 5 figs, 1 tab. (DLC)

Bhatnagar, R. (Texas Southern Univ., Houston, TX (United States). Dept. of Chemistry)

1991-01-01T23:59:59.000Z

199

The Effect of Continuous and Pulse Dose Ammonium Chloride Regimens on the Urine pH of Goats  

E-Print Network [OSTI]

i THE EFFECT OF CONTINUOUS AND PULSE DOSE AMMONIUM CHLORIDE REGIMENS ON THE URINE PH OF GOATS A Thesis by PHILIPPA MAY SPRAKE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 2012 Major Subject: Biomedical Sciences ii The effect of continuous and pulse dose ammonium chloride regimens on the urine pH of goats. Copyright...

Sprake, Philippa May

2012-10-19T23:59:59.000Z

200

Poly vinyl acetate used as a binder for the fabrication of a LiFePO4-based composite cathode for lithium-ion batteries  

Science Journals Connector (OSTI)

ABSTRACT This paper describes a method for the preparation of composite cathodes for lithium ion-batteries by using poly vinyl acetate (PVAc) as a binder. \\{PVAc\\} is a non-fluorinated water dispersible polymer commonly used in a large number of industrial applications. The main advantages for using of this polymer are related to its low cost and negligible toxicity. Furthermore, since the \\{PVAc\\} is water processable, its use allows to replace the organic solvent, employed to dissolve the fluorinated polymer normally used as a binder in lithium battery technology, with water. In such a way it is possible to decrease the hazardousness of the preparation process as well as the production costs of the electrodes. In the paper the preparation, characterization and electrochemical performance of a LiFePO4 electrode based on \\{PVAc\\} as the binder is described. Furthermore, to assess the effect of the \\{PVAc\\} binder on the electrode properties, its performance is compared to that of a conventional electrode employing PVdF-HFP as a binder.

Pier Paolo Prosini; Maria Carewska; Cinzia Cento; Amedeo Masci

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Polyamide woven fabrics with 2,3,5-triphenyltetrazolium chloride or nitro blue tetrazolium chloride as 2D ionizing radiation dosimeters  

Science Journals Connector (OSTI)

The development of flat woven fabric-based ionizing radiation 2D dosimeters is reported in this work. Polyamide fabric was surface modified with radiation-sensitive 2,3,5-triphenyltetrazolium chloride (TTC) or nitro blue tetrazolium chloride (NBT). These samples responded to gamma radiation of 60Co through a colour change: red and blue for TTC and NBT, respectively. The tinge intensity was observed to depend on the absorbed dose, which allowed for the reflectance of light (R) measurements and calculation of the calibration parameters: dose range, quasi-linear range, threshold dose and sensitivity. Oxygen was shown to be an important factor determining the dose response of the samples. For this reason, a range of additional modifications to the TTC- and NBT-polyamide fabric was proposed which lead to a decrease in the threshold dose and increase in the sensitivity to irradiation of the samples. For instance, a dosimeter made of polyamide fabric modified with 10 g/dm3 TTC, 0.5 mol/dm3 tert-butyl alcohol, 7.5% gelatine hydrogel at pH 10 (vacuum packed) showed the lowest dose threshold (50 Gy), dose range up to 2.8 kGy and the highest sensitivity to irradiation (?0.0396%/Gy) among the compositions studied. In consequence, this dosimeter was examined in terms of response to inhomogeneous irradiation from a 192Ir brachytherapy radiation source. The relative dose distribution profiles across the source's longitudinal axis were calculated. This showed potential of the textile dosimeters for 2D dose distribution measurements; however, further modifications towards improvement of the dosimeter's low dose response can be considered.

M. Kozicki; E. S?siadek

2012-01-01T23:59:59.000Z

202

E-Print Network 3.0 - aspect ratio domains Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University of California, Irvine Collection: Mathematics 73 Weld line strength of poly(vinyl chloride)polyethylene blends , J.W. Summersb Summary: Image Analysis System. The...

203

E-Print Network 3.0 - active polymeric functional Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Biology and Medicine ; Environmental Sciences and Ecology 39 Poly(vinyl chloride) (PVC) is one of the most successful modern synthetic materials. Because of its...

204

E-Print Network 3.0 - anomalous bcd mrk Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of peracetylated b-Cyclodextrin (perBCD) on the suspension... polymerization of vinyl chloride was studied. Addition of perBCD resulted in larger particles with broader......

205

Guidance Document Carcinogenic Substances  

E-Print Network [OSTI]

Mustard gas (bis(2-chloroethyl)sulfide) Formaldehyde (gas) Vinyl chloride Acetaldehyde Carbon tetrachloride 1,4-Dioxane Chloroform Ethyl carbamate (uret 3-Chloro-2-methylpropene Hexamethylphosphor 1

206

Data Qualification Report: Precipitation Chloride Data for Use on the Yucca Mountain Project  

SciTech Connect (OSTI)

The data covered by this qualification report have been cited in analysis/model reports (AMRs) to support the Site Recommendation in determining the suitability of Yucca Mountain as a repository for high level nuclear waste. Those analyses cited both qualified and unqualified hydrochemical data. This report evaluates unqualified precipitation chloride data based on the pedigree of the data and within the context of supporting analyses on the Yucca Mountain Project (YMP). The following AMRs use the unqualified chloride data considered in this report: (1) AMR S0040, ''Geochemical and Isotopic Constraints on Groundwater Flow Directions, Mixing and Recharge at Yucca Mountain'' (ANL-NBS-HS-000021) (Kwicklis 2000)--an analysis of groundwater recharge rates, flow directions and velocities, and mixing proportions of water from different source areas based on groundwater geochemical and isotopic data. (2) AMR U0085, ''Analysis of Geochemical Data for the Unsaturated Zone'' (ANL-NBS-HS-000017) (Fabryka-Martin 2000)--identifies fluid geochemical parameters for the unsaturated zone, local precipitation, and surface water; discusses the occurrence and origins of fracture minerals; and presents a thermal history of the unsaturated zone. These data are being evaluated for inclusion in technical products to include AMRs and Process Modeling Reports (PMRs) that support the Site Recommendation and that may also be used to support the License Application. A finding that the precipitation chloride data are qualified means that the data are adequate for generalized use and can be appropriately used in a wide variety of applications, so long as consideration is given to limitations on the accuracy, precision and representativeness of the data for an intended use in a technical product.

C. Wilson

2000-09-30T23:59:59.000Z

207

Strategies for continuous monitoring of hydrogen chloride emissions from municipal solid-waste incinerators  

SciTech Connect (OSTI)

The paper presents a discussion of sampling and analytical techniques for continuous monitoring of hydrogen chloride (HCl) emissions from incineration sources. The discussion focuses on commercially available systems for sample conditioning and measurement. Six HCl continuous-emission monitors were evaluated at a municipal facility for solid-waste incineration. Field-test results indicate that several techniques for continuous monitoring of HCl concentrations are available. Most of the analyzers tested, regardless of the detection or calibration techniques, indicated the same trend in the effluent HCl concentrations and produced data that was in good agreement with wet-chemistry results.

Jernigan, J.R.; Shanklin, S.; Rollins, R.; Logan, T.J.; Midgett, M.R.

1988-04-01T23:59:59.000Z

208

Ion beam sputter etching of galliumnitride grown by chloride transport LP–CVD  

Science Journals Connector (OSTI)

Galliumnitrid (GaN) layers, grown by chloride transport LP–CVD, were etched by ion beam sputtering with carbon dioxide (CO2). Before etching all samples were masked by electron beam evaporated titanium. We report on the dependence of the etch rate on the angle of incidence of the ion beam. Furthermore we present structural examinations of the surface before and after ion etching as well as an analysis of masking effects. Surface roughening and structural defects were investigated by optical microscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

Michael Topf; Fehmi Cavas; Bruno K Meyer; Bertilo Kempf; Walter Betz; Peter Veit

1999-01-01T23:59:59.000Z

209

The use of synthetic hydrocalcite as a chloride-ion getter for a barrier aluminum anodization process  

SciTech Connect (OSTI)

Chloride ion contamination at parts per billion concentrations plaques electrochemists studying barrier anodic aluminum oxide film growth and anodic aluminum oxide capacitor manufacturers. Chloride ion contamination slows film growth and reduces film quality. We have demonstrated that synthetic hydrocalcite substantially reduces the detrimental effects of chloride ion contamination in an aqueous electrolyte commonly used to grow barrier anodic aluminum oxide. We have determined that problems arise if precautions are not taken when using synthetic hydrocalcite as a chloride-ion getter in an aqueous electrolyte. Synthetic hydrocalcite is somewhat hydrophobic. If this powder is added directly to an aqueous electrolyte, some powder disperses; some floats to the top of the bath and forms scum that locally impedes anodic film formation. Commercially available powder contains a wide range of particle sizes including submicrometer-sized particles that can escape through filters into the electrolyte and cause processing problems. These problems can be over come if (1) the getter is placed in filter bags, (2) a piece of filter paper is used to skim trace amounts of getter floating on the top of the bath, (3) dummy runs are performed to scavenge chloride-ion loaded getter micelles dispersed in the bath, and (4) substrates are rinsed with a strong stream of deionized water to remove trace amounts of powder after anodization.

Panitz, J.K.G.; Sharp, D.J.

1995-11-01T23:59:59.000Z

210

VC and JP contributed equally to this work.  

E-Print Network [OSTI]

with sickle cell disease. We investigated the interaction between circulating leukocytes and red blood cells and Methods Blood samples from patients with sickle cell disease (n=25) and healthy subjects (n=5) were with sickle cell disease. The aggregation rate was 10-fold higher in these patients than in control subjects

Paris-Sud XI, Université de

211

Initial results from VC-1, First Continental Scientific Drilling...  

Open Energy Info (EERE)

to obtain structural and stratigraphie information near the intersection of the ring fracture zone and the precaldera Jemez fault zone, arid to core the youngest volcanic unit...

212

Recovering lithium chloride from a geothermal brine. Report of investigations/1984  

SciTech Connect (OSTI)

The Bureau of Mines has devised techniques to recover lithium from geothermal brines as the chloride. More than 99 pct of the lithium was precipitated from a brine containing 170 mg/L Li by adding a solution of A1C13 and increasing the pH to 7.5 with lime slurry. The Li-Al precipitate was dissolved in HCl and sparged with gaseous HC1 to recover the A1C13; this resulted in a solution containing LiCl and CaC12. The solution was evaporated at 100C to obtain a mixture of the chlorides from which 97 pct of the lithium was recovered and 90 pct of the calcium was rejected by leaching with tetrahydrofuran. The LiC1 recovered by evaporation of the tetrahydrofuran was purified by dissolution in water and treatment with oxalic acid. The final LiC1 solution contained 89 pct of the lithium originally present in the brine and had a purity of 99.9 pct.

Schultze, L.E.; Bauer, D.J.

1984-01-01T23:59:59.000Z

213

Chemical interactions at polymer interfaces: poly(p-xylylene-?-tetrahydrothiophene-bromide, chloride) on indium–tin-oxide  

Science Journals Connector (OSTI)

Chemical interactions, at the interface between a precursor polymer for poly(p-phenylenevinylene), namely poly(p-xylylene-?-tetrahydrothiophene-chloride), and an indium–tin-oxide transparent electrode, are identified using X-ray photoelectron spectroscopy. The \\{HCl\\} eliminated in the conversion process interacts with the surface of the indium–tin-oxide substrate leading to the formation of indium chloride which then diffuses into the polymer. It appears that indium–tin-oxide, or possibly the indium chloride generated at the interface, acts as a catalyst for the thermal elimination reaction. The results show unequivocally that interfacial interactions are of major importance in understanding, and ultimately improving, the performance of polymer-based electro-luminescent devices.

A Andersson; Th Kugler; M Lögdlund; A.B Holmes; X Li; W.R Salaneck

1999-01-01T23:59:59.000Z

214

Kinetic studies on chromium-catalyzed conversion of glucose into 5-hydroxymethylfurfural in alkylimidazolium chloride ionic liquid  

Science Journals Connector (OSTI)

Abstract 5-Hydroxymethylfurfural (HMF) is a promising green platform chemical derived from biomass. Kinetic studies were performed on chromium chloride-catalyzed conversion of glucose into HMF in alkylimidazolium chloride ionic liquids. The main by-products are disaccharides, fructose, glyceraldehyde, formic acid, and humins. The formation of HMF is strongly affected by reaction temperature and initial glucose concentration. The reaction is second order in glucose, with an activation energy of 134.9 kJ mol?1. The order in chromium is first, indicating that the rate-determining isomerization reaction is catalyzed by a mononuclear chromium species. The observed glucose conversion rate constant decreases as initial glucose concentration increases, suggesting that the catalytic activity of the chloride anion is significantly restrained by the hydrogen bonding with hydroxyl groups. A simplified kinetic model is developed to describe the behaviors of glucose conversion and HMF formation. This model is in good agreement with the experimental results.

Jian Zhang; Yan Cao; Huiquan Li; Xinbin Ma

2014-01-01T23:59:59.000Z

215

Subscriber access provided by University Libraries | University of Notre Dame Organic Letters is published by the American Chemical Society. 1155 Sixteenth  

E-Print Network [OSTI]

primarily for use as a precursor monomer for poly(vinyl chloride).5 More reactive chloroalkanes are em NH residues which greatly accelerate N-alkylation by activating the chloride leaving group

Smith, Bradley D.

216

A preliminary study of extraction solvents for CW-agents and their decomposition products [3:1 (methylene chloride:isopropanol) vs. methylene chloride  

SciTech Connect (OSTI)

The major focus of this study was to explore the possibility of using different extraction solvents (or solvent combinations) to isolate CW agents and their degradation products from environmental and industrial samples. The general approach for extracting, e.g. water samples, required the use of a 3:1 (methylene chloride:isopropanol) extraction solvent. Although the 3:1 solvent extraction work-up methods provided excellent results in several Inter-laboratory Comparison Tests, the implementation of these methods for CW on-site analysis exercises was difficult (the methods require cumbersome equipment and are labor intensive). However, due to the time, power, and size restraints set forth by the Chemical Warfare Convention (CWC) for a CW on-site inspection, LLNL developed new sample work-up methods. The approach selected by LLNL incorporated solid phase extraction (SPE) techniques. It is evident from this preliminary study that new or previously used extraction solvents should be re-investigated. It was determined that care must be taken in handling the samples prior to NMR measurements. Also, it was determined that the four target compounds used in this study were extracted on average 18% higher with 3:1 (CH{sub 2}Cl{sub 2}: IPA) vs. CH{sub 2}Cl{sub 2}. However, additional target compounds need to be investigated using this extraction solvent to determine which classes of compounds are better extracted by the use of a 3:1 solvent system. This preliminary study clearly reveals that a mixed solvent system can yield better extraction efficiencies for mixture of compounds in aqueous samples.

Alcaraz, A.; Ward, R.L.; Hulsey, S.S.; Andresen, B.D.

1994-09-15T23:59:59.000Z

217

Seismic reliability analysis of reinforced concrete framed buildings deteriorated by chloride ingress  

Science Journals Connector (OSTI)

The main purpose of this study is to propose an evaluation method that can be used for analysing the time-dependent seismic reliability of reinforced concrete (RC) buildings located in a corrosive environment with high seismic hazard. In this study, several models have been developed to investigate the deterioration induced by chloride ingress in order to estimate the initiation stage and rate of corrosion and to analyse the structural capacity of columns and beams with corroded reinforcing bars; then, the seismic evaluation for RC framed buildings was used for calculating the story shear capacity of each floor in a building. In addition, the hazard curve of the story shear demand for each floor obtained from the seismic hazard analysis was adopted; consequently, a Monte Carlo simulation was carried out for estimating the annual failure probability and seismic reliability index of the concerned building; in other words, a time-dependent seismic reliability function could be built.

Chien-Kuo Chiu; Wen-Yu Jean

2013-01-01T23:59:59.000Z

218

Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System  

SciTech Connect (OSTI)

The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

Yongchun Tang; John (Qisheng) Ma

2012-03-23T23:59:59.000Z

219

Calcium chloride electron injection/extraction layers in organic electronic devices  

SciTech Connect (OSTI)

Nontoxic calcium chloride (CaCl{sub 2}) was introduced into organic electronic devices as cathode buffer layer (CBL). The turn-on voltage and maximum luminance of organic light-emitting diode (OLED) with 1.5?nm CaCl{sub 2} was 3.5?V and 21 960?cd/m{sup 2}, respectively. OLED with 1.5?nm CaCl{sub 2} possessed comparable electroluminescent characteristics to that of the commonly used LiF. Moreover, the performance of the organic photovoltaic device with 0.5?nm CaCl{sub 2} was comparable to that of the control device with LiF. Therefore, CaCl{sub 2} has the potential to be used as the CBL for organic electronic devices.

Qu, Bo, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn; Gao, Zhi; Yang, Hongsheng; Xiao, Lixin; Chen, Zhijian; Gong, Qihuang, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China)

2014-01-27T23:59:59.000Z

220

DECONTAMINATION OF PLUTONIUM FOR FLUORIDE AND CHLORIDE DURING OXALATE PRECIPITATION, FILTRATION AND CALCINATION PROCESSES  

SciTech Connect (OSTI)

Due to analytical limitations for the determination of fluoride (F) and chloride (Cl) in a previous anion exchange study, an additional study of the decontamination of Pu from F and Cl by oxalate precipitation, filtration and calcination was performed. Anion product solution from the previous impurity study was precipitated as an oxalate, filtered, and calcined to produce an oxide for analysis by pyrohydrolysis for total Cl and F. Analysis of samples from this experiment achieved the purity specification for Cl and F for the proposed AFS-2 process. Decontamination factors (DF's) for the overall process (including anion exchange) achieved a DF of {approx}5000 for F and a DF of {approx}100 for Cl. Similar experiments where both HF and HCl were spiked into the anion product solution to a {approx}5000 {micro}g /g Pu concentration showed a DF of 5 for F and a DF of 35 for Cl across the combined precipitation-filtration-calcination process steps.

Kyser, E.

2012-07-25T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
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221

Selective Reduction of Active Metal Chlorides from Molten LiCl-KCl using Lithium Drawdown  

SciTech Connect (OSTI)

In support of optimizing electrorefining technology for treating spent nuclear fuel, lithium drawdown has been investigated for separating actinides from molten salt electrolyte. Drawdown reaction selectivity is a major issue that needs to be investigated, since the goal is to remove actinides while leaving the fission products in the salt. A series of lithium drawdown tests with surrogate fission product chlorides was run to obtain selectivity data with non-radioactive salts, develop a predictive model, and draw conclusions about the viability of using this process with actinide-loadd salt. Results of tests with CsCl, LaCl3, CeCl3, and NdCl3 are reported here. An equilibrium model has been formulated and fit to the experimental data. Excellent fits to the data were achieved. Based on analysis and results obtained to date, it is concluded that clean separation between minor actinides and lanthanides will be difficult to achieve using lithium drawdown.

Michael F. Simpson; Daniel LaBrier; Michael Lineberry; Tae-Sic Yoo

2012-10-01T23:59:59.000Z

222

Behavior of copper in acidic sulfate solution: Comparison with acidic chloride  

SciTech Connect (OSTI)

The anodic polarization behavior of copper in a 0.1 M sulfuric acid (H{sub 2}SO{sub 4}) + 1 M sodium sulfate (Na{sub 2}SO{sub 4}) solution (pH = 2.0) was studied at room temperature under quiescent and stirred conditions. The behavior was compared with aqueous equilibria via construction of a potential-vs-pH (E-pH) diagram for the copper-sulfate-water (Cu-SO{sub 4}{sup 2}-H{sub 2}O) system. Interpretation of the behavior was aided by comparison with aqueous equilibria and polarization studies of copper in a 0.2 M hydrochloric acid (HCl) + 1 M sodium chloride (NaCl) solution(pH = 0.8). The initial anodic dissolution region in the acidic sulfate solution exhibited Tafel behavior with a slope consistent with formation of cupric ions (Cu{sup 2+}) whose rate of formation was charge-transfer controlled. At higher potentials, limiting current density (i{sub L}) behavior was observed under E-pH conditions that were consistent with formation of a film of copper sulfate pentahydrate (CuSO{sub 4} {degree} 5H{sub 2}O). Comparison of experimental i{sub L} values with those predicted by mass transport-controlled processes, using estimates of the diffusion layer thickness obtained from the mass transfer-influenced region of apparent Tafel behavior in the acidic chloride solution, were in sufficient agreement to indicate i{sub L} was controlled by the rate of dissolution of the CuSO{sub 4} {degree} 5H{sub 2}O film via transport of Cu{sup 2+} from the film-electrolyte interface into the bulk solution.

Tromans, D.; Silva, J.C. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Metals and Materials Engineering

1997-03-01T23:59:59.000Z

223

APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE AND CHLORIDE FROM LEGACY FISSILE MATERIALS  

SciTech Connect (OSTI)

Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and the Savannah River Site (SRS) HB-Line Facility designed, developed, tested, and successfully deployed a production-scale system for the distillation of sodium chloride (NaCl) and potassium chloride (KCl) from plutonium oxide (PuO{sub 2}). Subsequent efforts adapted the vacuum salt distillation (VSD) technology for the removal of chloride and fluoride from less-volatile halide salts at the same process temperature and vacuum. Calcium chloride (CaCl{sub 2}), calcium fluoride (CaF{sub 2}), and plutonium fluoride (PuF{sub 3}) were of particular concern. To enable the use of the same operating conditions for the distillation process, SRNL employed in situ exchange reactions to convert the less-volatile halide salts to compounds that facilitated the distillation of halide without removal of plutonium. SRNL demonstrated the removal of halide from CaCl{sub 2}, CaF{sub 2} and PuF{sub 3} below 1000 C using VSD technology.

Pierce, R.; Peters, T.

2011-11-01T23:59:59.000Z

224

Experimental Investigation of Hydrogen Chloride Bonding with Calcium Hydroxide in the Furnace of a Stoker-Fired Boiler  

Science Journals Connector (OSTI)

The paper presents the results of experimental technical investigations to limit the mobility of chlorine released in the form of hydrogen chloride from the fuel in a stoker-fired boiler furnace. In the combustion process, hydrated lime was used as the ...

S?awomir Poskrobko; Jan ?ach; Danuta Król

2010-03-04T23:59:59.000Z

225

The effect of competition by chloride and sulfate anions on the adsorption of arsenate ion onto activated alumina  

E-Print Network [OSTI]

for adsorption sites on the activated alumina. The results of this study showed that the presence of 15 meq/L chloride anion depresses the ability of the arsenate to be adsorbed by F-1 activated alumina initial liquid phase arsenate ion concentration of 5 mg...

Janis, Patrick John

2012-06-07T23:59:59.000Z

226

Voltage-and calcium-dependent gating of TMEM16A/Ano1 chloride channels are physically  

E-Print Network [OSTI]

Voltage- and calcium-dependent gating of TMEM16A/Ano1 chloride channels are physically coupled by the first intracellular loop Qinghuan Xiaoa , Kuai Yua , Patricia Perez-Cornejob , Yuanyuan Cuia , Jorge in the first intracellular loop that is crucial for both Ca2+ and voltage sensing. Deleting 448EAVK

227

Solvation of Magnesium Dication: Molecular Dynamics Simulation and Vibrational Spectroscopic Study of Magnesium Chloride in Aqueous Solutions  

E-Print Network [OSTI]

Solvation of Magnesium Dication: Molecular Dynamics Simulation and Vibrational Spectroscopic Study of Magnesium Chloride in Aqueous Solutions Karen M. Callahan, Nadia N. Casillas-Ituarte, Martina Roeselova 26, 2010 Magnesium dication plays many significant roles in biochemistry. While it is available

228

Cation sorption on the muscovite (001) surface in chloride solutions using high-resolution X-ray reflectivity  

E-Print Network [OSTI]

Cation sorption on the muscovite (001) surface in chloride solutions using high-resolution X of cation sorption at the (001) muscovite-water interface were investigated in 0.01 and 0.5 m KCl, Cs negative charge arising from structural heteroionic substitutions. This charge is balanced by the sorption

Jacobsen, Steven D.

229

Reactions of r-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms and the  

E-Print Network [OSTI]

Reactions of r-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms (SN2) and base-induced elimination (E2). As the extent of substitution in the neutral reactants through a traditional SN2 transition state, followed by an elimination step in the SN2 product ion

Lineberger, W. Carl

230

Vinyls: Expansion Is the Word  

Science Journals Connector (OSTI)

Resins entered billion-pound class in 1959 and new development should push them to even greater heights ...

1960-01-04T23:59:59.000Z

231

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 0099-2240/98/$04.00 0  

E-Print Network [OSTI]

Acceptors for Anaerobic Microbial Oxidation of Vinyl Chloride and Dichloroethene PAUL M. BRADLEY,1 * FRANCIS Received 24 March 1998/Accepted 4 June 1998 Anaerobic oxidation of [1,2-14 C]vinyl chloride and [1,2-14 C. The chlorinated solvents tetrachloroethene (PCE) and tri- chloroethene (TCE) are common groundwater contaminants

Lovley, Derek

232

Appendix A: The Names of Polymers and Polymeric  

E-Print Network [OSTI]

or methylpentene polymethylpentene vinyl chloride poly(vinyl chloride) co-aminocaproic poly(co-aminocaproic acid MATERIALS For homopolymers Monomer name Polymer name X polyX XY poiy(XY) for example ethylene polyethylene acid) [nylon 6] Where the monomer name consists of two words, it should be bracketed in the polymer

Hall, Christopher

233

Degradation of pyrene in cetylpyridinium chloride-aided soil washing wastewater by pyrite Fenton reaction  

Science Journals Connector (OSTI)

Abstract Degradation of pyrene by pyrite Fenton reaction in synthetic cetylpyridinium chloride (CPC)-aided soil washing wastewater (SWW) was investigated in a closed batch reactor. Pyrene in the presence of CPC was gradually degraded in the pyrite Fenton system by 96% in 180 min at initial pH 7 showing pseudo-first-order reaction kinetics (0.0194 min?1), while the concentration of pyrene in the absence of CPC decreased abruptly by 91% in 5 min and then did not significantly decrease by the end of sampling time (180 min). In a classic Fenton system, pyrene in the presence of CPC was degraded by 35% in 180 min at initial pH 3. The sustainable reactivity of pyrite Fenton was attributed to slow but continuous dissolution of Fe(II) from the pyrite surface leading to continuous production of reactive radicals during the reaction. Pyrene in the presence of CPC was mainly degraded by OH radicals. Its product study showed that the pyrite Fenton system can successfully degrade pyrene in the CPC-aided SWW without accumulating toxic oxy-pyrenes such as 1,6-pyrenequinone and 1,8-pyrenequinone. CPC was also successfully degraded (95%) in the pyrite Fenton system, forming carbon dioxide and ammonium as main degradation products.

Kyunghoon Choi; Sungjun Bae; Woojin Lee

2014-01-01T23:59:59.000Z

234

Induction of chloride secretory currents across mouse ileal tissues by rotavirus enterotoxic peptide in different age mice  

E-Print Network [OSTI]

INDUCTION OF CHLORIDE SECRETORY CURRENTS ACROSS MOUSE ILEAL TISSUES BY A ROTAVIRUS ENTEROTOXIC PEPTIDE IN DIFFERENT AGE MICE A Thesis by VIRGINIA WATERS COX Submitted to the Office of Graduate Studies of Texas Ak M University in partial... by VIRGINIA WATERS COX Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style and content by: Judith M. Ball (Chair of Committee) Julian Lei os z (Member) Friedhelm...

Cox, Virginia Waters

2002-01-01T23:59:59.000Z

235

X?ray diffraction study of concentrated chromium (III) chloride solutions. I. Complex formation analysis in equilibrium conditions  

Science Journals Connector (OSTI)

Concentrated chromium (III) chloride solutions both acidic and neutral have been examined by x?ray diffraction in equilibrium conditions; i.e. a long period of time after their preparation. Complex formation between Cr3+ and Cl? ions have been quantitatively analyzed through direct comparison of experimental and calculated structure functions. The average number of chloride ions bonded to chromium in each solution has been determined. The values obtained are consistent with the indications given by the distribution curves and in good agreement with those expected on the grounds of equilibrium constants. The average aggregation numbers were determined by assuming the presence in neutral solutions of the charged species Cr(H2O)3+ 6 Cr(H2O)5Cl2+ and Cr(H2O)4Cl+ 2. In addition experimental evidence of the neutral species Cr(H2O)3Cl3 in the acidic solution has been obtained. Octahedral water coordination for chloride ions has been confirmed. Well defined second coordination shell around Cr3+ ions is strongly supported by the structural parameters obtained for water molecules belonging to two subsequent hydration shells of the cations.

Mauro Magini

1980-01-01T23:59:59.000Z

236

Recovery of acids and sodium hydroxide from solutions of sodium sulfate and sodium chloride with the use of bipolar membranes  

SciTech Connect (OSTI)

The authors examined the kinetic laws governing the electrodialysis recovery of hydrochloric acid and sulfuric acid, as well as sodium hydroxide, from 1M sodium chloride and 0.5 M sodium sulfate solutions and from a mixture of these salts with the use of the MB-1, MB-2, and MB-3 bipolar membranes. Kinetic plots of the current density and the concentration of the acid and the base in the chambers next to the bipolar membranes during the electrodialysis treatment of 1M sodium chloride, 0.5 M sodium sulfate, and solutions are presented. It was established that it is better to use the MB-3 membrane for the electrodialysis conversion of sodium chloride and sodium sulfate into acids and sodium hydroxide owing to the high rate and current efficiency and low expenditure of electrical energy and degree of contamination of the products obtained by the salts. It was also established that the resistance of the MB-1 and MB-2 bipolar membranes is almost an order of magnitude higher than that of the MB-3 membrane.

Bobrinskaya, G.A.; Pavlova, T.V.; Shatalov, A.Ya.

1985-09-01T23:59:59.000Z

237

A structural variability of copper(I) chloride-tetrahydrothiophene adducts crystallizing in polymeric forms and exhibiting polymorphism: The role of the solvent  

Science Journals Connector (OSTI)

The function of the solvent in the self-assembling mode of [CuCl] with tetrahydrothiophene is reported. Copper(l) chloride has... n , which is slightly soluble in the most common...

Euro Solari; Stefania De Angelis; Mario Latronico…

1996-12-01T23:59:59.000Z

238

Hydrolysis of cellulose to produce glucose with solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) with sequential water addition  

Science Journals Connector (OSTI)

Selective glucose production by cellulose hydrolysis with initial or sequential water addition in the presence of solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) under microwave irra...

Kaori Ishida; Shiho Matsuda; Masaru Watanabe…

2014-12-01T23:59:59.000Z

239

Simultaneous Determination of the Binding of Amantadine and Its Analogues to Synthetic Melanin by Liquid Chromatography After Precolumn Derivatization with Dansyl Chloride  

Science Journals Connector (OSTI)

......2-adamantanamine (2-ADA), memantine (MEM), and rimantadine (RIM) in...2-adamantanamine (2-ADA), memantine (MEM), and rimantadine (RIM) in...13392-28-4 Rimantadine 19982-08-2 Memantine 605-65-2 dansyl chloride 768-94-5......

Yasuhiko Higashi; Youichi Fujii

2005-04-01T23:59:59.000Z

240

Prospects for using the copolymer of N,N-dimethyl-N,N-diallylammonium chloride with acrylamide in production of butadiene-styrene rubber  

Science Journals Connector (OSTI)

The flocculating performance of a cationic polyelectrolyte, copolymer of N,N-dimethyl-N,N-diallylammonium chloride with acrylamide, in the recovery of butadiene-styrene rubber from latex was studied in relation t...

S. S. Nikulin; T. N. Poyarkova; V. M. Misin

2011-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Accelerated quantification of critical parameters for predicting the service life and life cycle costs of chloride-laden reinforced concrete structures  

E-Print Network [OSTI]

The use of corrosion resistant steels (instead of conventional carbon steels) and/or high performance concrete can increase the overall service life and can reduce the life cycle cost (LCC) of reinforced concrete (RC) structures exposed to chloride...

Pillai Gopalakrishnan, Radhakrishna

2012-06-07T23:59:59.000Z

242

The Behaviour of Electrolytes in Mixed Solvents. Part I. The Free Energies and Heat Contents of Hydrogen Chloride in Water-Ethyl Alcohol Solutions  

Science Journals Connector (OSTI)

1 November 1929 research-article The Behaviour of Electrolytes in Mixed Solvents. Part I. The Free Energies and Heat Contents of Hydrogen Chloride in Water-Ethyl Alcohol Solutions J. A. V. Butler C. M. Robertson The Royal Society...

1929-01-01T23:59:59.000Z

243

Light transmission of glass, fiberglass, polyethylene, and polyvinyl chloride greenhouse covers as related to growth of Lycopersicon esculentum Mill. variety Homestead 24  

E-Print Network [OSTI]

LIGHT TRANSMISSION OF GLASS~ FIBERGLASS& POLYETHYLENEe AND POLYVINYL CHLORIDE GREENHOUSE COVERS AS RELATED TO GROWTH OF LYCOPERSICON ESCULENTUM MILL, VARIETY HOMESTEAD 24 A Thesis By VICTOR CLEMENS ESCHE Submitted to the Graduate College... of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August, 1966 Major Subject: Horticulture LIGHT TRANSMISSION OF GLASS, FIBERGLASS~ POLYETHYLENE, AND POLYVINYL CHLORIDE GREENHOUSE COVERS AS RELATED...

Esche, Victor Clemens

2012-06-07T23:59:59.000Z

244

Study of the Susceptibility of Oxygen-Free Phosphorous Doped Copper to Corrosion in Simulated Groundwater in the Presence of Chloride and Sulfide  

SciTech Connect (OSTI)

Oxygen free high conductivity copper, doped with phosphorus (Cu OFP) has been chosen as the material for the fabrication of high level nuclear waste containers in Sweden. This material will be the corrosion barrier for spent fuel in the environment of a deep geological repository in granitic rock. The service life of this container is expected to exceed 1,000,000 years. During this time, which includes several glaciations, water of different compositions, including high concentration of chloride ions, will contact the copper surface. This work reports a study of the susceptibility of Cu OFP to corrosion when chloride ions are present, in deionized water (DW) and in synthetic groundwater (SGW). The techniques used were electrochemical methods such as corrosion potential evolution and Tafel curves. The system was studied with Electrochemical Impedance Spectroscopy (EIS). We also used as characterization techniques Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS). The main conclusions are that copper is more susceptible to corrosion at high chloride ion concentration. When the chloride concentration is low, it is possible to form copper chloride crystals, but at the highest concentration, copper chloride complexes are formed, leaving the copper surface without deposits. When the chloride concentration is low (<0.1 M) the corrosion process is mainly controlled by diffusion, while at higher concentrations (0.1 M to 1 M) corrosion is controlled by charge transfer processes. At low concentration of sulfide (<3 . 10{sup -5} M), copper corrosion in the presence of chloride is controlled by diffusional processes, while at higher concentrations corrosion is controlled by charge transfer processes. (authors)

Escobar, Ivan; Lamas, Claudia [Chilean Commission for Nuclear Energy, Amunategui No 95, Santiago, 834-0701 (Chile); Werme, Lars [Svensk Kaernbraenslehantering AB (SKB), Stockholm (Sweden)]|[Department of Physics, Uppsala University, Uppsala (Sweden); Oversby, Virginia [VMO Konsult, Stockholm (Sweden)

2007-07-01T23:59:59.000Z

245

The effect of iron chloride and glutamate on glutamine synthetase activity in primary cultured rat cortical astrocytes: a model for epileptic induction  

E-Print Network [OSTI]

THE EFFECT OF IRON CHLORIDE AND GLUTAMATE ON GLUTAMINE SYNTHETASE ACTIVITY IN PRIMARY CULTURED RAT CORTICAL ASTROCYTES: A MODEL POR EPILEPTIC INDUCTION A Thesis by JULIE ANN ROBERTS Submitted to the Graduate College of Texas ARM University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1986 Major Subject: Veterinary Anatomy THE EFFECT OF IRON CHLORIDE AND GLUTAMATE ON GLUTAMINE SYNTHETASE ACTIVITY IN PRIMARY CULTURED RAT CORTICAL ASTROCYTES: A...

Roberts, Julie Ann

1986-01-01T23:59:59.000Z

246

Low-temperature stress corrosion cracking of alloy 601 in thiosulfate and chloride solutions  

SciTech Connect (OSTI)

The stress corrosion cracking (SCC) susceptibility of unsensitized and sensitized alloy 601 (UNS N06601) was studied in sodium thiosulfate (Na{sub 2}S{sub 2}O{sub 3}) and sodium chloride (NaCl) solutions using slow strain rate testing (SSRT). Specimens were tested in the as-received condition (mill-annealed) after solution annealing at 1,050 C for 30 min and after solution annealing and sensitizing for 2, 5, 24, or 772 h at 700 for 30 min. Environments included Na{sub 2}S{sub 2}O{sub 3} and NaCl at different concentrations ranging from 0.01 M to 1.0 M at 25 C and 95 C. Double-loop electrochemical potentiokinetic reactivation (DL-EPR) tests in 0.01 M sulfuric acid (H{sub 2}SO{sub 4}) + 0.001 M potassium thiocyanate (KSCN) and immersion tests in boiling 25% nitric acid (HNO{sub 3}) solution were used to evaluate the effect of heat treatment on the degree of sensitization (DOS) and on intergranular corrosion (IGC) of alloy 601. In all environments tested, the unsensitized alloy was immune to SCC and showed only ductile failure. The alloy sensitized for 24 h showed the highest degree of susceptibility to SCC in 0.1 M Na{sub 2}S{sub 2}O{sub 3}, followed by the alloys sensitized for 72, 5, and 2 h, followed by the as-received and solution-annealed alloys. Except for the other times of sensitization, ductility for the specimen sensitized for 24 h was always lower at 25 C than at 95 C. The modified Huey and the DL-EPR tests also revealed the highest susceptibility to IGC for specimens sensitized for 24 h. This susceptibility did not change as Na{sub 2}S{sub 2}O{sub 3} concentration decreased from 0.5 M to 0.01 M, but ductility decreased as solution pH was increased from 3 to 7. Addition of NaCl to Na{sub 2}S{sub 2}O{sub 3} did not have a clear effect on susceptibility to SCC of the sensitized alloy since ductility sometimes increased but at other times decreased.

Gonzalez-Rodriguez, J.G. [U.A.E.M., Cuernavaca (Mexico). Facultad de Ciencias Quimicas e Ingenieria; Salinas-Bravo, V.M. [I.I.E., Cuernavaca (Mexico); Martinez-Villafane, A. [CIMAV, Chihuahua (Mexico)

1999-01-01T23:59:59.000Z

247

Thermal Analysis of Surrogate Simulated Molten Salts with Metal Chloride Impurities for Electrorefining Used Nuclear Fuel  

SciTech Connect (OSTI)

This project is a fundamental study to measure thermal properties (liquidus, solidus, phase transformation, and enthalpy) of molten salt systems of interest to electrorefining operations, which are used in both the fuel cycle research & development mission and the spent fuel treatment mission of the Department of Energy. During electrorefining operations the electrolyte accumulates elements more active than uranium (transuranics, fission products and bond sodium). The accumulation needs to be closely monitored because the thermal properties of the electrolyte will change as the concentration of the impurities increases. During electrorefining (processing techniques used at the Idaho National Laboratory to separate uranium from spent nuclear fuel) it is important for the electrolyte to remain in a homogeneous liquid phase for operational safeguard and criticality reasons. The phase stability of molten salts in an electrorefiner may be adversely affected by the buildup of fission products in the electrolyte. Potential situations that need to be avoided are: (i) build up of fissile elements in the salt approaching the criticality limits specified for the vessel (ii) freezing of the salts due to change in the liquidus temperature and (iii) phase separation (non-homogenous solution) of elements. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This work describes the experimental results of typical salts compositions, consisting of chlorides of strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium (as a surrogate for both uranium and plutonium), used in the processing of used nuclear fuels. Differential scanning calorimetry was used to analyze numerous salt samples providing results on the thermal properties. The property of most interest to pyroprocessing is the liquidus temperature. It was previously known the liquidus temperature of the molten salt would change as spent fuel is processed through the Mk-IV electrorefiner. However, the extent of the increase in liquidus temperature was not known. This work is first of its kind in determining thermodynamic properties of a molten salt electrolyte containing transuranics, fission products and bond sodium. Experimental data concluded that the melting temperature of the electrolyte will become greater than the operating temperature of the Mk-IV ER during current fuel processing campaigns. Collected data also helps predict when the molten salt electrolyte will no longer be able to support electrorefining operations.

Toni Y. Gutknecht; Guy L. Fredrickson; Vivek Utgikar

2012-04-01T23:59:59.000Z

248

Autoimmune response in MRL+/+ mice following treatment with dichloroacetyl chloride or dichloroacetic anhydride  

SciTech Connect (OSTI)

Dichloroacetyl chloride (DCAC) is formed from trichloroethene (TCE), which is implicated in inducing/accelerating autoimmune response. Due to its potent acylating activity, DCAC may convert proteins to neo-antigens and thus could induce autoimmune responses. Dichloroacetic anhydride (DCAA), which is a similar acylating agent, might also induce autoimmune responses. To evaluate if chloroacylation plays a role in the induction of autoimmunity, we have measured the autoimmune responses following treatment with DCAC or DCAA in autoimmune-prone MRL+/+ mice. Five-week-old female mice were injected intraperitoneally (twice weekly) with 0.2 mmol/kg of DCAC or DCAA in corn oil for 6 weeks. Total serum IgG, IgG1, and IgE levels were significantly increased in DCAC-treated mice as compared to controls. These increases corresponded with increases in DCAC-specific IgG and IgG1 levels. Total serum IgM was decreased in both DCAC- and DCAA-treated mice. Antinuclear antibodies, measured as an indication of systemic autoimmune responses, were increased in both DCAC- and DCAA-treated mice. Of eight Th1/Th2 cytokines measured in the serum, only IL-5 was significantly decreased in both treatment groups. The cytokine secretion patterns of splenic lymphocytes after stimulation with antibodies against CD3 (T cell receptor-mediated signal) and CD28 (costimulatory signal) differed between treatment and control groups. Levels of IL-1, IL-3, IL-6, IFN-{gamma}, G-CSF, and KC were higher in cultures of stimulated splenocytes from either DCAC- or DCAA-treated mice than from controls. The level of IL-17 was only increased in cultures from DCAC-treated mice. Increased lymphocytic populations were found in the red pulp of spleens following treatment with either DCAC or DCAA. In addition, thickening of the alveolar septa in the lungs of DCAC- or DCAA-treated mice was observed. The lung histopathology in exposed mice was consistent with the symptomology observed in welders exposed to DCAC/phosgene. Thickening was more pronounced in DCAC-treated mice. Our data suggest that DCAC and DCAA elicit autoimmune responses in MRL+/+ mice that might be reflective of their chloroacylation potential in vivo.

Cai Ping [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555-0609 (United States); Koenig, Rolf [Department of Microbiology and Immununology, University of Texas Medical Branch, Galveston, TX 77555 (United States); Khan, M. Firoze [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555-0609 (United States); Qiu, Suimin [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555-0609 (United States); Kaphalia, Bhupendra S. [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555-0609 (United States); Ansari, G.A.S. [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555-0609 (United States)]. E-mail: sansari@utmb.edu

2006-10-15T23:59:59.000Z

249

Hydrogen embrittlement of type 410 stainless steel in sodium chloride, sodium sulfate, and sodium hydroxide environments at 90 C  

SciTech Connect (OSTI)

Susceptibility of martensitic type 410 (UNS S41000) stainless steel (SS) to environmental cracking was evaluated at 90 C in concentrated sodium chloride, sodium sulfate and sodium hydroxide solutions, all of which are environments related to steam turbine conditions, using the slow strain rate testing (SSRT) technique. In NaCl, the effects of solution pH, concentration, and anodic and cathodic polarization were investigated. Tests were supplemented by detailed electron fractography and hydrogen permeation measurements. A clear correlation was found between the degree of embrittlement and the amount of hydrogen permeating the steel, suggesting a hydrogen-induced cracking mechanism.

Gonzalez-Rodriguez, J.G.; Salinas-Bravo, V.M. [Inst. de Investigaciones Electricas, Cuernavaca (Mexico). Dept. Fisico Quimica Aplicada; Martinez-Villafane, A. [Centro de Investigaciones en Materiales Avanzados Leon Tolstoi, Chihuahua (Mexico)

1997-06-01T23:59:59.000Z

250

Chloride anion exchange coprocessing for recovery of plutonium from pyrochemical residues and Cs sub 2 PuCl sub 6 filtrate  

SciTech Connect (OSTI)

Continuing studies of plutonium recovery from direct oxide reduction (DOR) and electrorefining (ER) pyrochemical process residues show that chloride anion exchange coprocessing is useful and effective. Coprocessing utilizes DOR residue salt as a reagent to supply the bulk of chloride ion needed for the chloride anion exchange process and to improve ER residue salt solubility. ER residue salt and ER scrapeout can be successfully treated, either alone or together, using coprocessing. In addition, chloride anion exchange at 2.0M acidity results in improved process performance by greatly reducing disproportionation of plutonium(IV), eliminating restrictions on oxidation time compared to operation at 1.0M acidity. Laboratory-scale experiments show that below-discard effluent plutonium losses are obtained. Resin capacity was 30 g Pu/{ell} or greater. Furthermore, it is feasible to perform chloride anion exchange recovery of plutonium from filtrate resulting from precipitation of dicesium hexachloroplutonate (Cs{sub 2}PuCl{sub 6}, an oxidant salt to be used in the molten salt extraction process) and integration of its preparation with recovery of DOR salts. 10 refs., 9 figs., 10 tabs.

Muscatello, A.C.; Killion, M.E.

1990-12-07T23:59:59.000Z

251

Test and evaluation of the Chloride Spegel S1P108/30 electric vehicle battery charger  

SciTech Connect (OSTI)

The Chloride Spegel Model S1P108/30 electric vehicle battery charger was tested by the Tennessee Valley Authority (TVA) as an account of work sponsored by the Electric Power Research Institute (EPRI). Charger input/output voltage, current, and power characteristics and input waveform distortion were measured; and induced electromagnetic interference was evaluated as the charger recharged a lead-acid battery pack. Electrical quantities were measured with precision volt-ampere-watt meters, frequency counters, a digital-storage oscilloscope, and a spectrum analyzer. THe Chloride charger required 8.5 hours to recharge a 216V tubular plate lead-acid battery from 100 percent depth of discharge (DOD). Energy efficiency was 83 percent, specific power was 37.4 W/kg (17.0 W/lb), input current distortion varied from 22.4 to 34.1 percent, and electromagnetic interference was observed on AM radio. Tests were conducted with the battery at initial DOD of 100, 75, 50, and 25 percent. Charge factor was 1.14 from 100-percent DOD, increasing to 1.39 from 25-percent DOD.

Driggans, R.L.; Keller, A.S.

1985-09-01T23:59:59.000Z

252

Effect of lithium chloride on spectral, optical, thermal and mechanical behaviour of bis thiourea zinc acetate crystals  

Science Journals Connector (OSTI)

Single crystals of pure bis thiourea zinc acetate (BTZA) and lithium chloride (LiCl) doped BTZA have been synthesized and grown successfully from aqueous solutions by slow evaporation technique. The single crystals thus grown were characterized by different techniques such as single crystal XRD, AAS, FT-IR, UV–Vis, TG/DTA and SHG test. The single crystal XRD study proved that the dopant has not changed the structure of the parent crystal. The AAS study confirmed the presence of lithium in the doped crystal. The FTIR study ascertained the metal coordination of lithium chloride doped BTZA through thiourea. The optical behavior of the doped crystal has been examined by UV spectral analysis. Thermal studies TGA & DTA of the doped crystal have been investigated and found that the doped crystal is thermally more stable than the pure crystal. The SHG test using Nd: YAG Laser confirmed the NLO activity of the pure and doped crystal. The obtained results are presented and discussed.

L. Ruby Nirmala; J. Thomas Joseph Prakash

2012-01-01T23:59:59.000Z

253

Radiation Stability of Benzyl Tributyl Ammonium Chloride towards Technetium-99 Extraction - 13016  

SciTech Connect (OSTI)

A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning processes, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, the UREX process has been developed in the United States to co-extract hexavalent uranium (U) and hepta-valent technetium (Tc) by tri-n-butyl phosphate (TBP). Tc-99 is recognized to be one of the most abundant, long-lived radio-toxic isotopes in UNF (half-life, t{sub 1/2} = 2.13 x 10{sup 5} years), and as such, is targeted in UNF separation strategies for isolation and encapsulation in solid waste-forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste-form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flowsheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste-forms for ultimate disposal. In addition, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste-forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macro-compounds such as crown-ethers, aza-crown ethers, quaternary ammonium salts, and resorcin-arenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO{sub 4}{sup -} by benzyl tributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand's matrix conditions and concentration, as well as varying the organic phase composition (i.e. diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using an external Co-60 source. Post-irradiation solvent extraction measurements will be discussed. (authors)

Paviet-Hartmann, Patricia; Horkley, Jared; Campbell, Keri [Idaho National Laboratory, 2525 Fremont Street, Idaho Falls, ID 83402 (United States)] [Idaho National Laboratory, 2525 Fremont Street, Idaho Falls, ID 83402 (United States); Roman, Audrey [University of Nevada - Las Vegas, Harry Reid Center, 4505 S. Maryland Pkwy, Box 4009, Las Vegas, NV 89154-4009 (United States)] [University of Nevada - Las Vegas, Harry Reid Center, 4505 S. Maryland Pkwy, Box 4009, Las Vegas, NV 89154-4009 (United States); Nunez, Ana; Espartero, Amparo [CIEMAT, Avda Complutense, 40, 28040- Madrid (Spain)] [CIEMAT, Avda Complutense, 40, 28040- Madrid (Spain)

2013-07-01T23:59:59.000Z

254

Radiation Stability of Benzyl Tributyl Ammonium Chloride Towards Technetium-99 Extraction  

SciTech Connect (OSTI)

A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning process, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, low nitric acid concentration in the aqueous phase of a UREX based process will co-extract U(VI) and Tc(VII) by tri-n-butyl phosphate (TBP). Technetium (Tc-99) is recognized to be one of the most abundant, long-lived radiotoxic isotopes in UNF (half-life, t1/2 = 2.13 × 105 years), and as such, it is targeted in UNF separation strategies for isolation and encapsulation in solid waste forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flow sheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste forms for ultimate disposal. Furthermore, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macrocompounds such as crown-ethers, aza-crown ethers, and resorcinarenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO4- by benzyltributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand’s matrix conditions and concentration, as well as varying the organic phase composition (i.e., diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using external Co-60 source. Post-irradiation solvent extraction measurements will be discussed.

Jared Horkley; Audrey Roman; Keri Campbell; Ana Nunez; Amparo Espartero

2013-02-01T23:59:59.000Z

255

Natrix -Scoring Sheet 1. 0.01 M Mg Chloride, 0.05 M MES pH 5.6, 2.0 M Lithium Sulfate  

E-Print Network [OSTI]

Natrix - Scoring Sheet 1. 0.01 M Mg Chloride, 0.05 M MES pH 5.6, 2.0 M Lithium Sulfate 2. 0.01 M Mg Acetate, 0.05 M MES pH 5.6, 2.5 M Ammonium Sulfate 3. 0.1 M Mg Acetate, 0.05 M MES pH 5.6, 20% MPD 4. 0 Ammonium Acetate, 0.05 M MES pH 6.0, 0.6 M NaCl 9. 0.1 M K Chloride, 0.01 M Mg Chloride, 0.05 M MES pH 6

Hill, Chris

256

Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials  

DOE Patents [OSTI]

Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

1997-12-02T23:59:59.000Z

257

Corrosion mitigation of N-(2-hydroxy-3-trimethyl ammonium)propyl chitosan chloride as inhibitor on mild steel  

Science Journals Connector (OSTI)

Abstract The biopolymer N-(2-hydroxy-3-trimethyl ammonium)propyl chitosan chloride (HTACC) was synthesised and its influence as a novel corrosion inhibitor on mild steel in 1 M \\{HCl\\} was studied using gravimetric and electrochemical experiments. The compound obtained was characterised using FTIR and NMR studies. The inhibition efficiency increased with the increase in concentration and reached a maximum of 98.9% at 500 ppm concentration. Polarisation studies revealed that HTACC acts both as anodic and cathodic inhibitor. Electrochemical impedance studies confirmed that the inhibition is through adsorption on the metal surface. The extent of inhibition exhibits a negative trend with increase in temperature. Langmuir isotherm provides the best description on the adsorption nature of the inhibitor. SEM analysis indicated the presence of protective film formed by the inhibitor on the metal surface.

Y. Sangeetha; S. Meenakshi; C. SairamSundaram

2015-01-01T23:59:59.000Z

258

Kinetics of Ion Removal from an Iron-Rich Industrial Coproduct: I. Chloride Yigal Salingar, Donald L. Sparks,* Masoud Ghodrati, and Gerald J. Hendricks  

E-Print Network [OSTI]

% of the Cl was removed with the first pore volume. Additionally, the salt removal decreased the electrolyteKinetics of Ion Removal from an Iron-Rich Industrial Coproduct: I. Chloride Yigal Salingar, Donald for Cl removal. This study was conducted to determine the mechanism of Cl retention, and to ascertain

Sparks, Donald L.

259

VICKERY, JOHN D. Fundamental Properties and Bond Characteristics of Chlorinated Polyvinyl Chloride and SS340 Adhesive for Evaluation of Steel Tank Linings. (Under  

E-Print Network [OSTI]

Chloride and SS340 Adhesive for Evaluation of Steel Tank Linings. (Under the Direction of Dr. Sami Rizkalla.) Tank linings are used to extend the service life of tanks and to avoid replacement of damaged tanks is to understand the behavior of the different materials proposed for lining typical bleach tanks used in the pulp

260

HYPERSONIC INVESTIGATION OF THE A -T y p E PHASE TRANSITION IN AMMONIUM-CHLORIDE M. GROSS -D. GERLICH -and S. SZAPIRO  

E-Print Network [OSTI]

HYPERSONIC INVESTIGATION OF THE A - T y p E PHASE TRANSITION IN AMMONIUM-CHLORIDE M. GROSS - D method.The hypersonic sound velocities and elastic constants have been measured in the immediate vicinity measurements. The difference between the present hypersonic measurement and previous ultrasonic results

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

MOSSBAUER STUDY OF Fe(ll) DOPED ALKALI CHLORIDE CRYSTALS AND DEFECT STRUCTURE Y. Takashima, N. Kai, T. Nishida and L. Chandler*  

E-Print Network [OSTI]

to the a-hematite species. This means that excess iron in the sample reacted with a small amount of oxygen for a lithium ion located in a perfectly cubic site with no vacancies nearby. This is justified by the fact that there is no change in the X-ray dif- fraction lines between the pure and doped lithium chlorides. Although

Paris-Sud XI, Université de

262

In Vivo Antitumor Activity and in Vitro Cytotoxic Properties of Bis[1,2-bis(diphenylphosphino)ethane]gold(I) Chloride  

Science Journals Connector (OSTI)

...Chloride Susan J. Berners-Price, Christopher K. Mirabelli...3. The complex with a cw-ethylene bridging alkene also was very...be medi- 4S. J. Berners-Price and P. J. Sadler. Manuscript...preparation. *S. J. Berners-Price and P. J. Sadler. Gold...

Susan J. Berners-Price; Christopher K. Mirabelli; Randall K. Johnson; Michael R. Mattern; Francis L. McCabe; Leo F. Faucette; Chiu-Mei Sung; Shau-Ming Mong; Peter J. Sadler; and Stanley T. Crooke

1986-11-01T23:59:59.000Z

263

Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy  

E-Print Network [OSTI]

91D magnesium alloy R. AMBAT, N.N. AUNG and W. ZHOU School of Mechanical and Production Engineering in revised form 20 January 2000 Key words: AZ91D alloy, chloride ion, corrosion, die-cast, ingot, magnesium of morphology. The corrosion product consisted of magnesium hydroxide, fallen b particles and magnesium

Zhou, Wei

264

Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy  

E-Print Network [OSTI]

chloride salt eutectics for solar thermal-energy storage applications Donghyun Shin, Debjyoti Banerjee for the anoma- lous enhancement of thermal conductivity over that of the neat solvent. Eastman et al. [5] reported thermal conductivity enhance- ment of 30% and 60% for water based nanofluids of Al2O3 and Cu

Banerjee, Debjyoti

265

Intern experience at the Conoco VCM plant: an internship report  

E-Print Network [OSTI]

's position in the organization of the plant. Major projects assigned during the internship are defined. The problem of occupational exposure to vinyl chloride, a toxic chemical, is addressed and a system for monitoring employee exposure...

Hall, James Josiah

2013-03-13T23:59:59.000Z

266

Effect of SiO2 and nanoclay on the properties of wood polymer nanocomposite  

Science Journals Connector (OSTI)

Wood polymer composite (WPC) were developed by using solution blended high density polyethylene, low density polyethylene, polypropylene, poly(vinyl chloride), Phragmites karka wood flour and polyethylene-co...-g...

Biplab K. Deka; Tarun K. Maji

2013-02-01T23:59:59.000Z

267

Methods Development for On-Line Gas Chromatography  

Science Journals Connector (OSTI)

......contractual specifications. Used to determine value and sale price of product. Monitors liquid or gas effluent wastes for loss...vinyl chloride on dioctylsebacate and Car- bowax 550. (A) ethylene, (B) propane, (C) propylene, (D) isobutane, (E......

Richard Villalobos

1990-07-01T23:59:59.000Z

268

EAST CAROLINA UNIVERSITY HAZARDOUS CHEMICAL USE GRANT REVIEW FORM ECU policy requires that all grant proposals involving the use of hazardous chemicals be reviewed by an institutional review committee or  

E-Print Network [OSTI]

-benezene 4-Aminodiphenyl Asbestos Coal tar pitch volatiles Methyl chloromethyl ether Formaldehyde Vinyl chloride Coke oven emissions 1,2-dibromo-3-chloropropane Lead Cadmium Benzene Cotton dust Chromium VI

269

A Review of NCI's Extramural Grant Portfolio: Identifying Opportunities for Future Research in Genes and Environment in Cancer  

Science Journals Connector (OSTI)

...vinyl chloride, benzidine, diesel exhaust particles, polycyclic...energy balance, methods, or general. Specific environmental terms...more than a single funding cycle and our goal was to evaluate the funding cycle included in this report, publications...

Armen A. Ghazarian; Naoko I. Simonds; Kelly Bennett; Camilla B. Pimentel; Gary L. Ellison; Elizabeth M. Gillanders; Sheri D. Schully; and Leah E. Mechanic

2013-04-01T23:59:59.000Z

270

Enhanced phytoremediation of volatile environmental pollutants with transgenic trees  

E-Print Network [OSTI]

trichloroethylene, vinyl chloride, carbon tetrachloride, benzene, and chloroform, are com- mon environmental conventional techniques. CYP2E1 P450 poplar trichloroethylene carbon tetrachloride Phytoremediation is the use greater public approval. Phytoremediation also yields other benefits including carbon sequestration, soil

271

Nano-web structures constructed with a cellulose acetate/lithium chloride/polyethylene oxide hybrid: Modeling, fabrication and characterization  

Science Journals Connector (OSTI)

Abstract Electrospun nano-web structures (ENWSs) were successfully fabricated from ionized binary solution of celluloseMn30/polyethylene oxideMn200 (CA/PEO of 0.5–1.5). Final concentration of polymers was 12% (w/v) in the solution, and lithium chloride was used as ionizing agent. Response surface methodology (RSM) was applied to the optimize fabrication of ENWSs. Results of multiple linear regression analysis revealed that the solution properties and \\{ENWSs\\} morphology were strongly influenced by CA/PEO. An increase in PEO amount increased the viscosity which is a function of molecular weight, and as a result raised the entanglement of polymeric solution but decreased the surface tension that all support nanofibers fabrication. The size of nanofibers decreased with reducing PEO and LiCl concentration. Increasing the content of LiCl promoted the electrical conductivity (EC) value; however, junction zones were formed. The overall optimum region was found to be at combined level of 1.5% CA/PEO and 0.49% (w/v) LiCl.

Atefeh Broumand; Zahra Emam-Djomeh; Faramarz Khodaiyan; Sasan Mirzakhanlouei; Driush Davoodi; Ali A. Moosavi-Movahedi

2015-01-01T23:59:59.000Z

272

Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)  

SciTech Connect (OSTI)

Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

Solehudin, Agus, E-mail: asolehudin@upi.edu [Department of Mechanical Engineering Education, Indonesia University of Education (UPI), Bandung, West Java (Indonesia); Nurdin, Isdiriayani [Department of Chemical Engineering, Bandung Institute of Technology, Bandung, West Java (Indonesia)

2014-03-24T23:59:59.000Z

273

Underpotential Deposition of Lead on Cu(100) in the Presence of Chloride:? Ex-Situ Low-Energy Electron Diffraction, Auger Electron Spectroscopy, and Electrochemical Studies  

Science Journals Connector (OSTI)

Département de Chimie, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1 ... 14-18 characterized the structure of chloride/chlorine adsorbed from HCl on Cu(100) and Cu(111) both in solution (by emersion and transfer to UHV) and from gas-phase dosing using low-energy electron diffraction (LEED) and Auger electron spectroscopy (AES). ... E. Zenati acknowledges her fellowship from the Canadian International Development Agency, ACDI Marocco. ...

Gessie M. Brisard; Entissar Zenati; Hubert A. Gasteiger; Nenad M. Markovi?; Philip N. Ross, Jr.

1997-04-16T23:59:59.000Z

274

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network [OSTI]

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

275

Diagnosis of sources of current inefficiency in industrial molten salt electrolysis cells by Raman spectroscopy: A topical report on chlorides: Topical report, June 1982-June 1987  

SciTech Connect (OSTI)

Molten salt electrolysis, a very energy-intensive process, is used in the extraction of light metals. Aluminum production by the Hall process and magnesium production in the Dow and I.G. Farbenindustrie cells constitute the major commercial applications of metal electrowinning from molten-salt media at present. The energy input into the electrolysis cell is in the form of direct current, and the energy efficiencies in the magnesium or aluminum processes are only in the 30 to 40% range. Major energy reductions are achieved by reducing the cell voltage or by increasing the current efficiency. Goal of the research is to identify the sources of the current losses occurring in molten salt electrolysis. This research worked on the systems of I.G. Farben magnesium chloride and Alcoa smelting aluminum chloride processes. Raman spectra were measured and analyzed for each component or their mixtures of the electrolyte for magnesium and aluminum reduction in chloride melts. Raman measurements were also conducted on the melts of industrial composition for aluminum and magnesium electrolysis. In laboratory-scale cells which imitated industrial practice, Raman spectra were measured in situ during electrolysis in attempts to identify the streamers, coloration of electrolyte, and any subvalent species. They were known to occur only during electrolysis, and they have been reported to be possible current losses. Cyclic voltammetry was conducted to obtain information about the generation of subvalent species which were not detected by Raman measurement. These were thought to be kinetic entities present only during electrolysis. Results of Raman spectroscopy and electrochemistry of magnesium and aluminum reduction from molten chloride bath are presented. The results would be useful to establish the basis for the study of electrolysis of aluminum from molten fluoride media. 119 refs., 66 figs.

Sadoway, D. R.

1987-06-01T23:59:59.000Z

276

Quantitative determination of memantine in human plasma by GC using negative ion chemical ionization MS detection after derivatization with a new reagent, o-(pentafluorobenzyloxycarbonyl)-2,3,4,5-tetrafluorobenzoyl chloride  

Science Journals Connector (OSTI)

A method is presented for the quantitative determination of memantine in plasma by use of the derivatization ... pentafluorobenzyloxycarbonyl)-2,3,4,5-tetrafluorobenzoyl chloride. Memantine can be quantitatively ...

Hans J. Leis; Werner Windischhofer

2012-11-01T23:59:59.000Z

277

Structures of disordered alkali chlorides in normal and compressed states: An isothermal-isobaric molecular-dynamics study  

Science Journals Connector (OSTI)

Isothermal-isobaric molecular-dynamics simulations have been performed to investigate the glassy and liquid structures of two alkali chloride systems [mixture (LiCl)0.50(KCl)0.40(CsCl)0.10 and pure LiCl]. With the use of an ionic interaction model, the basic thermodynamic properties of the crystalline, liquid, and glassy states are successfully reproduced in the simulations. At normal pressure (101.3 MPa), it is found that the predominant short-range order in both systems is the LiCl4 tetrahedral units, each pair of which is mutually connected by sharing not only the vertices but also the edges of the tetrahedra. In the glassy and liquid states of LiCl-KCl-CsCl, the network structure is formed by polytetrahedral medium-range order (LiLi4) consisting of five connected LiCl4 tetrahedra. Some portions of this network are truncated by the K+ and Cs+ ions adjacent to the vertex Cl- ions. On the other hand, liquid and glassy LiCl has a disordered structure approximately analogous to zinc-blende structure, also including the wurtzitelike ionic arrangement. For LiCl in the amorphous and crystalline states, we performed isothermal-compression simulations up to 30 GPa. As in the experimental findings, no structural transformation occurs for the rocksalt LiCl crystal. The compression causes the crystallization of amorphous LiCl into rocksalt structure at more than 3–10 GPa with continuous structural change. This structural transformation is analogous to the pressure-induced polymorphic transition (zinc blende?rocksalt) that occurs in the crystals of more covalent compounds such as CdS.

Kenichi Kinugawa

1993-10-01T23:59:59.000Z

278

Low pour crude oil compositions  

SciTech Connect (OSTI)

This patent describes and improvement in the process of transporting waxy crude oils through a pipeline. It comprises: incorporating into the crude oil an effective pour point depressant amount of an additive comprising a polymer selected from the group consisting of copolymers of ethylene and acrylonitrile, and terpolymers of ethylene, acrylonitrile and a third monomer selected from the group consisting of vinyl acetate, carbon monoxide, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, vinyl chloride, vinyl fluoride, acrylic acid, and methacrylic acid, wherein the amount of third monomer in the terpolymer ranges from about 0.1 to about 10.0 percent by weight.

Motz, K.L.; Latham, R.A.; Statz, R.J.

1990-05-22T23:59:59.000Z

279

On the preparation of TiAl alloy by direct reduction of the oxide mixtures in calcium chloride melt  

SciTech Connect (OSTI)

In recent years, TiAl-based intermetallic alloys are being increasingly considered for application in areas such as (i) automobile/transport sector (passenger cars, trucks and ships) (ii) aerospace industry (jet engines and High Speed Civil Transport propulsion system) and (iii) industrial gas turbines. These materials offer excellent (i) high temperature properties (at higher than 6000C) (ii) mechanical strength and (iii) resistance to corrosion and as a result have raised renewed interest. The combination of these properties make them possible replacement materials for traditional nickel-based super-alloys, which are nearly as twice as dense (than TiAl based alloys). Since the microstructures of these intermetallic alloys affect, to a significant extent, their ultimate performance, further improvements (by way of alteration/modification of these microstructures), have been the subject matter of intense research investigations. It has now been established that the presence of alloy additives, such as niobium, tantalum, manganese, boron, chromium, silicon, nickel and yttrium etc, in specific quantities, impart marked improvement to the properties, viz. fatigue strength, fracture toughness, oxidation resistance and room temperature ductility, of these alloys. From a number of possible alloy compositions, {gamma}-TiAl and Ti-Al-Nb-Cr have, of late, emerged as two promising engineering alloys/materials. . The conventional fabrication process of these alloys include steps such as melting, forging and heat treatment/annealing of the alloy compositions. However, an electrochemical process offers an attractive proposition to prepare these alloys, directly from the mixture of the respective oxides, in just one step. The experimental approach, in this new process, was, therefore, to try to electrochemically reduce the (mixed) oxide pellet to an alloy phase. The removal of oxygen, from the (mixed) oxide pellet, was effected by polarizing the oxide pellet against a graphite electrode in a pool of molten calcium chloride at a temperature of 9000C. The dominant mechanism of the oxygen removal was the ionization of oxygen followed by its subsequent discharge, as CO2/CO, at the anode surface. The removal of oxygen from the oxide mixture helped form the alloy in situ. The presentation shall cover the detailed experimental results pertaining to the preparation, evaluation and characterization of Ti-47Al-2Nb-2Cr (atom%) alloy.

Prabhat K. Tripathy; Derek J. Fray

2011-11-01T23:59:59.000Z

280

Study of the dependence of the specific output power of a copper chloride laser on the radial temperature profile of a gas plasma  

SciTech Connect (OSTI)

The design of a copper chloride laser is described, and the laser is optimised by studying the dependence of its output power on the buffer gas type. The voltage and current of the laser discharge at the optimum buffer gas pressure are measured. The influence of the diaphragm diameter on the specific output power is studied after optimisation of switch parameters. When an diaphragm producing the optimal temperature gradient in the laser gas-discharge tube, the record specific output power of 123 W L{sup -1} is obtained without any admixtures. (lasers)

Sadighi-Bonabi, R; Mohammadpour, R; Tavakoli, M [Physics Department, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Soltanmoradi, F [Bonab Research Center, Bonab, Azerbaijan province (Iran, Islamic Republic of); Zand, M [Laser Research Center, Tehran (Iran, Islamic Republic of)

2007-04-30T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

"Kohn-Shamification" of the classical density-functional theory of inhomogeneous polar molecular liquids with application to liquid hydrogen chloride  

E-Print Network [OSTI]

The Gordian knot of density-functional theories for classical molecular liquids remains finding an accurate free-energy functional in terms of the densities of the atomic sites of the molecules. Following Kohn and Sham, we show how to solve this problem by considering noninteracting molecules in a set of effective potentials. This shift in perspective leads to an accurate and computationally tractable description in terms of simple three-dimensional functions. We also treat both the linear- and saturation- dielectric responses of polar systems, presenting liquid hydrogen chloride as a case study.

Johannes Lischner; T. A. Arias

2008-06-27T23:59:59.000Z

282

MembFac -Scoring Sheet 1. 12% MPD, 0.1 M Na Acetate pH 4.6, 0.1 M Sodium Chloride  

E-Print Network [OSTI]

Phosphate, 0.1 M Na Acetate pH 4.6, 0.1 M Lithium Sulfate 10. 12% PEG 6000, 0.1 M Na Acetate pH 4.6, 0.1 MMembFac - Scoring Sheet 1. 12% MPD, 0.1 M Na Acetate pH 4.6, 0.1 M Sodium Chloride 2. 12% PEG 4000, 0.1 M Na Acetate pH 4.6, 0.1 M Zinc Acetate 3. 10% PEG 4000, 0.1 M Na Acetate pH 4.6, 0.2 M Ammonium

Hill, Chris

283

Data Acquisition System for Electric Vehicle's Driving Motor Test Bench Based on VC++  

Science Journals Connector (OSTI)

In order to solve such problems as great labor intensity, high cost, low efficiency and accuracy during the performance experiment for driving motor system of electric vehicles, and realize data acquisition automatically and synchronously, a data acquisition system for driving motor test bench based on visual instruments is designed. This data acquisition system can be used to obtain the driving motor's parameters of currents and voltages at the same time. This system's hardware is based on electric vehicle's motor test bench in Beijing Institute of Technology, and combined with PXI2010 data acquisition card from ADLINK Company. Visual c++ software is adopted as development tool. In this paper, the design and realization of the hardware and software are presented. Experiment results show that this system improves the efficiency and quality of testing task with high utility. And experiment data can be obtained accurately.

Song Qiang; Lv Chenguang

2012-01-01T23:59:59.000Z

284

K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles...  

Open Energy Info (EERE)

zone. Six illitic clays within Quaternary caldera-fill debris flow, tuffaceous sediment, and ash-flow tuff (48 to 587 m depth) yield ages from 0.35 to 1.09 Ma. Illite from...

285

Scientific Core Hole Valles Caldera No. 2B (VC-2B), New Mexico...  

Open Energy Info (EERE)

Dennis L. Nielson, Pisto Larry, C.W. Criswell, R. Gribble, K. Meeker, J.A. Musgrave, T. Smith and D. Wilson Conference GRC Annual Meeting; Santa Rosa, CA; 19890101 Published...

286

Influence of plasticizer molecular weight on plasticizer retention in PVC geomembranes  

E-Print Network [OSTI]

, the repeating unit is the vinyl chloride monomer. The chemical and structural Geosynthetics In. Geosynthetics International, 12, No. 2, 000- 000. 1. INTRODUCTION Polyvinyl chloride (PVC) is one of the oldest by a series of small and simple repeating chemical units. These repeating units are called monomers. In PVC

287

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

288

Nonaqueous composition for slip casting or cold forming refractory material into solid shapes  

SciTech Connect (OSTI)

A composition is described for slip casting or cold forming non-oxide refractory material(s) into solid shape comprising finely divided solid refractory materials selected from the group consisting of metal boride, refractory carbide, nitride, silicide and a refractory metal of tungsten, molybdenum, tantalum and chromium suspended in a nonaqueous liquid slip composition consisting essentially of a deflocculent composed of a vinyl chloride-vinyl acetate resin dissolved in an organic solvent.

Montgomery, L.C.

1993-08-24T23:59:59.000Z

289

Surface-enhanced Raman scattering and atomic force microscopy of brass electrodes in sulfuric acid solution containing benzotriazole and chloride ion  

SciTech Connect (OSTI)

Three different methods were used to roughen brass (Cu/Zn = 67/33) electrodes in 0.5 M H[sub 2]SO[sub 4] containing 1.0 mM benzotriazole (BTAH): (1) polarization at +0.05 V vs. saturated calomel for 5 min; (2) immersion in the above solution for six hours; and (3) oxidation-reduction cycling in the presence of chloride ion. The surfaces prepared by the first two methods exhibited surface-enhanced Raman scattering (SERS) spectra of the polymeric complex [Cu(I)BTA][sub s]. The SERS spectrum obtained from electrodes prepared by the third method is very similar to that of [Cu(I)CIBTAH][sub 4]. Examination of the electrodes by atomic force microscopy (AFM) showed that a large number of grain boundary sites are formed by the roughening processes. This effect is attributed to the loss of zinc, which occurs during corrosion of the mirror-like, polished brass electrode surface in the sulfuric acid solution. 11 refs., 5 figs.

Rubim, J.C.; Kim, J.; Henderson, E.; Cotton, T.M. (Instituto de Quimica da Universidade de Sao Paulo (Brazil) Ames Lab., IA (United States) Iowa State Univ., Ames (United States))

1993-01-01T23:59:59.000Z

290

Reactions of Ethyl Groups on a Model Chromia Surface: Ethyl Chloride on Stoichiometric Alpha-Cr2O3(1012)  

SciTech Connect (OSTI)

The reaction of CH3CH2Cl over the nearly-stoichiometric ?-Cr2O3 (1 0 View the MathML source 2) surface yields gas phase CH2double bond; length as m-dashCH2, CH3CH3, H2 and surface chlorine adatoms. The decomposition reaction is initiated via C-Cl bond cleavage to give a surface ethyl (CH3CH2-) intermediate. A rate-limiting ?-hydride elimination from the surface ethyl species produces gas phase CH2double bond; length as m-dashCH2 and surface hydrogen atoms. Two parallel competing reactions form CH3CH3, via ?-hydride addition to remaining surface ethyl species (reductive elimination), and H2, via the combination of two surface hydrogen atoms. The chlorine freed from the dissociation of CH3CH2Cl binds at the five-coordinate surface Cr3+ sites on the stoichiometric surface and inhibits the surface chemistry via simple site blocking. No surface carbon deposition is observed from the thermal reaction of ethyl chloride, suggesting that ethyl intermediates are not primary coke forming intermediates in the dehydrogenation of ethane over (1 0 View the MathML source 2) facets of ?-Cr2O3.

Brooks, J.; Ma, Q; Cox, D

2009-01-01T23:59:59.000Z

291

Mechanism of 1-(1-propylsulfonic)-3-methylimidazolium chloride catalyzed transformation of d-glucose to 5-hydroxymethylfurfural in DMSO: an NMR study  

Science Journals Connector (OSTI)

Abstract The conversion of d-glucose to 5-hydroxymethylfurfural (HMF) in the presence of 5.48 mol % 1-(1-propylsulfonic)-3-methylimidazolium chloride acidic ionic liquid catalyst in DMSO at 150 °C was studied using 1H, 13C NMR, and visible spectroscopy. The HMF yield rapidly increases in the first 100 min of reaction, however yield drops beyond 100 min and levels off to a maximum yield of about 15.7% around 600 min. The visible spectroscopy study of the reaction mixture suggests that rate of HMF formation slows down after 100 min due to increase in the rate of humin formation after first 100 min. A mechanism has been proposed and key intermediates in the pathway could be identified by studying the 13C NMR spectra of acidic ionic liquid catalyzed transformations of C-1 and C-2 13C labeled d-glucose under identical conditions. The proposed mechanism involves the isomerization of d-glucose to d-fructose via the complexation of the open chain sugar with the imidazolium cation of the acidic ionic liquid catalyst.

Ananda S. Amarasekara; Ashfaqur Razzaq

2014-01-01T23:59:59.000Z

292

CO2-H2O Mixtures in the Geological Sequestration of CO2. II. Partitioning in Chloride Brines at 12-100 °C and 1-600 bar.  

Office of Scientific and Technical Information (OSTI)

CO CO 2 -H 2 O Mixtures in the Geological Sequestration of CO 2 . II. Partitioning in Chloride Brines at 12-100°C and up to 600 bar. Nicolas Spycher and Karsten Pruess Lawrence Berkeley National Laboratory, MS 90-1116, 1 Cyclotron Road, Berkeley, California, USA September 2004 ABSTRACT Correlations presented by Spycher et al. (2003) to compute the mutual solubilities of CO 2 and H 2 O are extended to include the effect of chloride salts in the aqueous phase. This is accomplished by including, in the original formulation, activity coefficients for aqueous CO 2 derived from several literature sources, primarily for NaCl solutions. Best results are obtained when combining the solubility correlations of Spycher et al. (2003) with the activity coefficient formulation of Rumpf et al. (1994) and Duan and Sun (2003), which

293

Preparation and characterization of a novel hybrid magnetic semiconductor containing rare, one-dimensional mixed-iodide/chloride anion of lead(II)  

SciTech Connect (OSTI)

A new hybrid inorganic-organic magnetic semiconductor [Ni(bipy){sub 3}Pb{sub 2}I{sub 4.84}Cl{sub 1.16}.DMF]{sub n} (bipy=2,2'-bipyridine) containing novel one-dimensional mixed-halide anion of lead(II) was synthesized by reactions of PbI{sub 2}, NaI, NiCl{sub 2} and bipy in DMF solution, and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the space group C2/c with a=29.260(8) A, b=15.602(4) A, c=23.695(6) A, {beta}=126.815({sup o}), Z=8, V=8660(4) A{sup 3} and consists of a magnetic cation [Ni(bipy){sub 3}]{sup 2+} in addition to one-dimensional mixed-halide anion, which is built up of face-sharing [PbX{sub 6}] octahedra. Of the seven crystallographically independent halide sites in this anion, one and five are occupied by Cl and I, respectively, the remaining one has mixed-iodide and -chloride occupancy. The title yellow compound has an optical bandgap of 2.59 eV, and the variable-temperature magnetic susceptibility measurement indicates paramagnetic behavior. - Graphical abstract: Based upon magnetic metal-organic complex as template, a novel one-dimensional haloplumbate containing mixed-halide anion has been successfully synthesized. Its structural characteristics, optical bandgap, magnetic and thermal properties are reported.

Fan Leqing [Key Laboratory for Functional Materials of Fujian Higher Education, Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, Fujian 362021 (China)], E-mail: lqfan@hqu.edu.cn; Wu Jihuai [Key Laboratory for Functional Materials of Fujian Higher Education, Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, Fujian 362021 (China)], E-mail: jhwu@hqu.edu.cn; Huang Yunfang [Key Laboratory for Functional Materials of Fujian Higher Education, Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, Fujian 362021 (China)

2007-12-15T23:59:59.000Z

294

Effect of bicarbonate ion additives on pitting corrosion of type 316L stainless steel in aqueous 0.5 M sodium chloride solution  

SciTech Connect (OSTI)

The effect of bicarbonate ions (HCO{sub 3}{sup {minus}}) on pitting corrosion of type 316L stainless steel (SS, UNS S3 1603) was investigated in aqueous 0.5 M sodium chloride (NaCl) solution using potentiodynamic polarization, the abrading electrode technique, alternating current (AC) impedance spectroscopy combined with x-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). Addition of HCO{sub 3}{sup {minus}} ions to NaCl solutions extended the passive potential region in width and, at the same time, raised the pitting potential in value on the potentiodynamic polarization curve. Potentiostatic current transients obtained from the moment just after interrupting the abrading action showed the repassivation rate of propagating pits increased and that the pit growth rate decreased with increasing HCO{sub 3}{sup {minus}} ion concentration. Over the whole applied potential, the oxide film resistance was higher in the presence of HCO{sub 3}{sup {minus}} ions. The pit number density decreased with increasing HCO{sub 3}{sup {minus}} ion concentration. Moreover, addition of HCO{sub 3}{sup {minus}} ions to NaCl solutions retarded lateral pit growth, while promoting downward pit growth from the surface. The bare surface of the specimen repassivated preferentially along the pit mouth and walls, compared to the pit bottom, as a result of formation of a surface film with a high content of protective mixed ferrous-chromous carbonate ([Fe,Cr]CO{sub 3}) that formed from preferential adsorption of HCO{sub 3}{sup {minus}} ions.

Park, J.J.; Pyun, S.I.; Lee, W.J. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering; Kim, H.P. [Korea Atomic Energy Research Inst., Taejon (Korea, Republic of)

1999-04-01T23:59:59.000Z

295

nh Gi Thit Hi Ti Nguyn Thin Nhin ca V Trn Du Deepwater Horizon Cc D n Khu Vc  

E-Print Network [OSTI]

Lng Sò ip Nhm Tng C Hi ánh Bt Gii Trí Trong Vùng Cán Xong Florida s c thc hin Qun Bay (h thng Vnh St Okaloosa và Walton. Lý tng ra thì bng cách thc hin d án này,s lng sò ip ti các a im c can thip cui cùng có th s tng lên ti các mc t duy trì bn vng c cho vic ánh bt gii trí. S lng sò ip các Qun Gulf và

296

TVIATERIALS e VC H Ver l agsgesel l schaftm bH , W ei nhei m /Ber gstr . 1995  

E-Print Network [OSTI]

in Surface Science and Catalysis,Vol.58 (Eds: H. van Bckkum. E. M. Flanigen,J. C. Jansen Scienceand Catalysis. Vol.85 (Eds: J. C. Jansen.M. Stocker. H. G. Karge. J. Weitkamp). Elsevier.113. [13] J. C. Jansen.W. Nugroho,H. van Bekkum,in Pror'.9thInt. ZeoliteConf., Montrettl 1992 (Eds. R. van

Prentiss, Mara

297

Methods for the synthesis of deuterated vinyl pyridine monomers  

DOE Patents [OSTI]

Methods for synthesizing deuterated vinylpyridine compounds of the Formula (1), wherein the method includes: (i) deuterating an acyl pyridine of the Formula (2) in the presence of a metal catalyst and D.sub.2O, wherein the metal catalyst is active for hydrogen exchange in water, to produce a deuterated acyl compound of Formula (3); (ii) reducing the compound of Formula (3) with a deuterated reducing agent to convert the acyl group to an alcohol group, and (iii) dehydrating the compound produced in step (ii) with a dehydrating agent to afford the vinylpyridine compound of Formula (1). The resulting deuterated vinylpyridine compounds are also described.

Hong, Kunlun; Yang, Jun; Bonnesen, Peter V

2014-02-25T23:59:59.000Z

298

Research Needs: Glass Solar Reflectance and Vinyl Siding  

E-Print Network [OSTI]

mm MPa NFRC PIB psi PVC SHGC sq ft U.S. USDA of Agriculturesolar heat gain coefficient (SHGC) requirements insulating

Hart, Robert

2012-01-01T23:59:59.000Z

299

Precision measurements of binary and multicomponent diffusion coefficients in protein solutions relevant to crystal growth: Lysozyme chloride in water and aqueous NaCl at pH 4.5 and 25{degree}C  

SciTech Connect (OSTI)

Accurate models of protein diffusion are important in a number of applications, including liquid-liquid phase separation and growth of protein crystals for X-ray diffraction studies. In concentrated multicomponent protein systems, significant deviations from pseudobinary behavior can be expected. Rayleigh interferometry is used to measure the four elements (D{sub if}){sub v} of the ternary diffusion coefficient matrix for the extensively investigated protein, hen egg-white lysozyme (component 1) in aqueous NaCl (component 2) at pH 4.5 and 25 C. These are the first multicomponent diffusion coefficients measured for any protein system at concentrations high enough to be relevant to modeling and prediction of crystal growth or other phase transitions, and the first for a system involving lysozyme at any concentration. The four ternary diffusion coefficients for the system lysozyme chloride/NaCl/water are reported for lysozyme chloride at 0.60 mM (8.6 mg/mL) and NaCl at concentrations of 0.25, 0.50, 0.65, 0.90, and 1.30 M (1.4, 2.8, 3.7, 5.1, and 7.2 wt %), with the latter two compositions being supersaturated. One cross-term, (D{sub 21}){sub v}, is 80--259 times larger than the main term (D{sub 11}){sub v} and 7--18 times larger than (D{sub 22}){sub v}. Standard interferometric diagnostic tests indicate that aggregation is unimportant in the experiments. The authors also present binary diffusion coefficients D{sub v} for lysozyme chloride/water at concentrations from 0.43 to 3.08 mM (6.2--44.1 mg/mL), at the same pH and temperature. The precision of the results is about 0.1% for the binary diffusion coefficients and diagonal ternary diffusion coefficients, and about 1--2% for the cross-terms. For the ternary systems investigated, they show that a single pseudobinary diffusion coefficient does not accurately describe diffusive transport, and predictions by simple models such as the Nernst-Hartley equations are inaccurate at the higher concentrations considered here. Finally, dynamic light-scattering diffusion coefficients, differing form both the interferometrically measured (D{sub ij}){sub v} and a theoretical prediction of light-scattering diffusion coefficients in multicomponent systems, are reported for the same solutions used for the ternary experiments at 1.30 M.

Albright, J.G.; Annunziata, O. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; Miller, D.G. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; [Lawrence Livermore National Lab., CA (United States); Paduano, L. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; [Univ. di Napoli, Naples (Italy). Dipt. di Chimica; Pearlstein, A.J. [Univ. of Illinois, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering] [Univ. of Illinois, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering

1999-04-14T23:59:59.000Z

300

Electrophilic Metal Alkyl Chemistry in New Ligand Environments  

SciTech Connect (OSTI)

The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

Jordan, Richard F. [University of Chicago] University of Chicago

2013-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

ARC-coal acetylene process development program. Phase 1B. Final technical progress report, 15 September 1979-31 September 1980  

SciTech Connect (OSTI)

For many years, acetylene was a major feedstock in the chemical industry, being used for the manufacture of such important large-volume chemicals as vinyl chloride, vinyl acetate, acrylonitrile, acetaldehyde, and several others chemicals. Since the mid-1960's, however, acetylene has been largely replaced by olefins like ethylene and propylene. These olefins, though sometimes less suitable as feedstocks than acetylene, became more economical as they became readily available at prices considerably lower than acetylene. The successful development of the Arc-Coal process appears to offer a new competitive option to ethylene while reducing the risk of feedstock shortage by relying on the vast coal resources within the US. The Arc-Coal Acetylene process has been tested successfully at both the 100 kW and 1 MW levels, clearly demonstrating that acetylene can be economically produced from coal in a one-step reaction, and that the current reactor design approach is capable of being scaled up to commercial size. The process is shown to be commercially competitive with the currently available process for acetylene manufacture and, more importantly, competes attractively with ethylene in the manufacture of vinyl chloride and vinyl acetate. With the commercial advent of the arc-coal acetylene process, it will become possible to manufacture acetylene more economically than by conventional process. Substantial ethylene price increases tied closely to, and driven by, higher crude oil and natural gas prices are a clear long-term trend which appears certain to continue well into the foreseeable future with periodic market variations. This situation will make the Arc-coal Acetylene process a leading contender for the production of chemicals such as vinyl chloride and vinyl acetate, substituting a coal feedstock process for the current liquid hydrocarbon-fed ethylene-to-vinyl monomers processes.

Not Available

1980-10-30T23:59:59.000Z

302

Shrink Sleeve Flexo Inks Veronika Pekarovicova*, Alexandra Pekarovicova*, and Paul D. Fleming III*  

E-Print Network [OSTI]

containing monomers such as amide, ester, and/or ethylene/vinyl acetate are also frequently used. Shrink rate as the substrates. Several film materials are available such as polyvinyl chloride (PVC), oriented be also formed from polymers and copolymers of olefin monomers containing from 2 to about 12 carbon atoms

Fleming, Paul D. "Dan"

303

Plasmachemical Amine Functionalization of Porous Polystyrene Spheres: The Importance of Particle Size  

E-Print Network [OSTI]

dissolving stabilizers (2 g of poly- (vinyl alcohol) and 2 g of sodium chloride) in 400 mL of hot water. Upon polymer structure by copolymerization of monomers.8 However, the number of commercial monomers is limited by the addition of a mixture of monomer (5 mL of styrene), cross-linker (45 mL of divinylbenzene), porogen (50 m

Davis, Ben G.

304

Synthesis of an A/B/C Triblock Copolymer for Battery Materials Applications  

E-Print Network [OSTI]

Section tert-Butylamine, cobalt chloride, and ethyl vinyl ether were purchased from Aldrich. Butyllithium incorporate metal salts. The organocobalt monomer was chosen due to the difficulty of polymerizing a lithium- containing monomer. The electrochemical reaction shown in reaction 1 is different from other lithium battery

Rubloff, Gary W.

305

Peroxide grafted PDMS: hydrosilylation reaction study and thiol-ene chemistry as an alternative pathway  

E-Print Network [OSTI]

of azobiscyanopentanoyl chloride with amino terminated polysiloxane1 , and peroxycarbamate groups were introduced) groups were inserted in a polydimethylsiloxane backbone by hydrosilylation of a vinyl functional silaneBAP with mercaptopropylsilane monomer (DM3PSi) affords functionalized monomer (BP3DM2Si). Polycondensation of this monomer

Paris-Sud XI, Université de

306

Glossary of Colloid and Polymer Science Adrian R. Rennie, 2008.1 Glossary of Terms in Colloid and  

E-Print Network [OSTI]

are based on olefinic and other monomers that react like this such as styrene, vinyl chloride, butadiene etc that occurs by addition of a monomer to a double bond between two carbon atoms. The reaction will remove © Adrian R. Rennie, 2008.3 An alternating copolymer is a polymer formed from two monomers in a regular

Rennie, Adrian

307

Proton-conducting polymer electrolyte membranes based on fluoropolymers incorporating perfluorovinyl ether sulfonic acids and fluoroalkenes  

E-Print Network [OSTI]

acids. A novel synthetic route describing the preparation of perfluorovinyl ether monomer containing. The radical (co) and terpolymerization of 4-[(,,-trifluorovinyl)oxy]benzene sulfonyl chloride (TFVOBSC) with 1,1-difluoroethylene (or vinylidene fluoride, VDF), hexafluoropropene (HFP), and perfluoromethyl vinyl ether (PMVE

Paris-Sud XI, Université de

308

Random and Sequential Radical Cotelomerizations of 3,3,3-Trifluoropropene (TFP, H2C=CHCF3) with Vinylidene  

E-Print Network [OSTI]

is quite reactive in contrast to longer perfluorinated chain vinyl-type monomers (e.g. CnF2n+1-CH=CH2, benzyl chloride, under redox complexes (e.g. Fe(CO)5), UV or gamma rays initiatons.7-19 In addition

Paris-Sud XI, Université de

309

ADVERTISERS' INDEX:  

Science Journals Connector (OSTI)

......Wildwood Rd. Toledo, Ohio 43614, or call 419/882-1643 Price $400.00 ppd U.S. Abstractors Desired Preston Publications...IO-IIH) times compared with FID- to I'l'li levels for ethylene oxide and sub Pf'H levels for vinyl chloride Detects I'l'li......

Advertisers' Index

1982-11-01T23:59:59.000Z

310

Solute structuring in iron(III) chloride solutions. II. Evidence of polynuclear complex formation in the FeCl3?6H2O melt by the ‘‘isoelectronic solutions’’ method  

Science Journals Connector (OSTI)

Two iron(III) chloride solutions prepared in suitable chemical conditions have been examined by the x?ray diffraction technique. The two solutions are isoelectronic (i.e. they have the same average scattering power per chlorine atom) with the hydrated FeCl3?6H2O melt previously examined [J. Chem. Phys. 71 4255 (1979)]. A comparison of the radial distribution function of the melt with those of the two solutions (reference solutions) leads to the conclusion that polynuclear complex formation occurs in the melt and that a bitetrahedral Fe2Cl6 molecule is the most probable polynuclear species formed in this system. An analysis of the Fe–Cl association in the reference solutions has been also performed and the results substantially agree with those obtained previously.

Mauro Magini

1982-01-01T23:59:59.000Z

311

Water Content and Buildup of Poly(diallyldimethylammonium chloride)/ Poly(sodium 4-styrenesulfonate) and Poly(allylamine hydrochloride)/ Poly(sodium 4-styrenesulfonate) Polyelectrolyte Multilayers Studied by an in Situ Combination of a Quartz Crystal Micr  

E-Print Network [OSTI]

ABSTRACT: The buildup of polyelectrolyte multilayers (PEMs), fabricated by the layer-by-layer (LBL) assembly, was followed in situ by the combination of a quartz crystal microbalance with dissipation monitoring (QCM-D) and spectroscopic ellipsometry in a single device. PEMs composed of poly(allylamine hydrochloride) (PAH) and poly(sodium 4-styrenesulfonate) (PSS) polyelectrolyte pairs and of poly-(diallyldimethyl ammonium chloride) (PDADMAC) and PSS were built up to 17 layers. The combination of ellipsometry andQCM-D allowed simultaneous determination of the acousticmass, which comprises both the mass of the polymer and solvent, and the optical mass which corresponds to the polymer mass alone. From these parameters, the hydration of the PEMwas calculated layer by layer. The linearly growing PAH/ PSS PEMs showed a constant absolute content of water throughout the assembly, while the relative contribution of water to the PEM mass content approached zero, when grown in 0.5 M NaCl. Rinses with water between polyelectrolyte deposition steps resulted in a hydration of approximately 40%. The supralinearly growing PDADMAC/PSS PEMs exhibited a remarkable dependence of the hydration on the polyelectrolyte that was deposited last. Implications for the mechanism of assembly of the PEMs are discussed.

Jagoba J. Iturri Ramos; Stefan Stahl; Ralf P. Richter; Sergio E. Moya

2010-01-01T23:59:59.000Z

312

High temperature corrosion of boiler waterwalls induced by chlorides and bromides. Part 1: Occurrence of the corrosive ash forming elements in a fluidised bed boiler co-firing solid recovered fuel  

Science Journals Connector (OSTI)

In waste fired boilers high temperature corrosion has often been attributed to zinc and lead chlorides. In addition, bromine induced high temperature corrosion has been earlier observed in a bubbling fluidised bed (BFB) boiler co-firing solid recovered fuel (SRF) with bark and wastewater sludge. In Part 1 of this work a measurement campaign was undertaken to determine the occurrence of Cl, Br, Zn and Pb in the fuel, in the combustion gases as well as in the deposits on the boiler waterwalls. It was observed that Cl, Br, Zn and Pb originate to a large extent from the SRF, they are vaporised in the furnace, and may form waterwall deposits. This, complemented by fluctuations between oxidising and reducing atmosphere resulted in rapid corrosion of the waterwall tubes. Concentrations of Cl, Br, Zn and Pb in the fuel, in the furnace vapours and in the deposits are reported in this work. As there is lack of published data on the bromine induced high temperature corrosion, laboratory scale corrosion tests were carried out to determine the relative corrosiveness of chlorine and bromine and these results will be reported in Part 2 of this work. Furthermore, the forms of Cl, Br, Zn and Pb in the combustion gases as well as in the waterwall deposits were estimated by means of thermodynamic equilibrium modelling and these results will also be discussed in Part 2.

P. Vainikka; D. Bankiewicz; A. Frantsi; J. Silvennoinen; J. Hannula; P. Yrjas; M. Hupa

2011-01-01T23:59:59.000Z

313

Passivation-free solid state battery  

DOE Patents [OSTI]

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li{sub 4}Ti{sub 5}O{sub 12} anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2} and LiV{sub 2}O{sub 5} and their derivatives. 5 figs.

Abraham, K.M.; Peramunage, D.

1998-06-16T23:59:59.000Z

314

Passivation-free solid state battery  

DOE Patents [OSTI]

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

Abraham, Kuzhikalail M. (Needham, MA); Peramunage, Dharmasena (Norwood, MA)

1998-01-01T23:59:59.000Z

315

Iron porphyrin polymer films: Materials for the modification of electrode surfaces and the detection of nitric oxide  

SciTech Connect (OSTI)

We are currently investigating a new method for the detection and quantification of nitric oxide (NO) based on a carbon electrode chemically modified with an iron porphyrin polymer film. Commercially available vinyl-substituted iron porphyrin monomers can be polymerized directly onto electrode surfaces through a published electrochemical polymerization process. We are also developing a synthesis for a new vinyl-substituted monomer, iron 5,10,15-triphenyl-20-vinyl porphyrin chloride, in hopes of improving polymer film stability. The electrochemistry of NO is also being investigated at electrodes chemically modified with an iron porphyrin polymer film. We are studying the catalytic oxidation of iron porphyrin bound NO to nitrate by molecular oxygen. The reaction with molecular oxygen is preceded by a one electron reduction of the iron porphyrin-NO complex. If currents proportional to nitric oxide concentration can be measured, a new NO electrochemical sensor will be designed.

McGuire, M.; Drew, S.M. [Carleton College, Northfield, MN (United States)

1996-10-01T23:59:59.000Z

316

The physical characterization of dimethyldioctadecylammonium chloride vesicles  

E-Print Network [OSTI]

that liposomes are indeed single bilayers and sealed by selective line broadening experiments. When paramagnetic ions, such as Mn, are added to sonicated lipid-water solutions the proton +2 signals of 70%%d of the ii(CH3)3 broadened out. The signal broadened.... 0 0 O. ??? O O. l- t3 0 5- CG O U 0 tJ ??- O ??? O O? O O O ) ??l ??l ?P ??? C3 O O. ?D 5 O ?g E ?U tl ?A 5 ??l O? ?? 0 III 0. 0 CL I- 0 0l I- CJ t3 n5 Ql 0 0 CL 0 N I- nl I? nl Vl lI- 0 EU ln 0 Ql I...

Klahn, Patricia Lynn

2012-06-07T23:59:59.000Z

317

Aluminum: Reducing chloride emissions from aluminum production  

SciTech Connect (OSTI)

Reynolds Metals Company (RMC), with assistance from a NICE{sup 3} grant, is developing for commercialization a closed-loop control process that greatly reduces chlorine emissions and increases plant efficiency while maintaining metal quality. The process still utilizes chlorine to remove impurities during aluminum processing, but is more effective than current methods. With the new technology chlorine in the stack is monitored and input chlorine is adjusted continuously. This optimization of chlorine use results in substantially less waste because less chlorine has to be bought or produced by aluminum manufacturers. This innovation is a significant improvement over conventional aluminum treatments, in which chlorine is injected in a more costly and wasteful manner. By the year 2010, the new technology has the potential to reduce the energy it takes to create chlorine by 8.4 billion Btu per year and to cut greenhouse gas emissions by 1,377 tons per year.

Simon, P.

1999-09-29T23:59:59.000Z

318

Brillouin scattering study of molten zinc chloride  

Science Journals Connector (OSTI)

Polarized and depolarized Brillouin scattering experiments on molten ZnCl2 were performed between 300 and 600 °C in different geometries. VV spectra measured in backscattering and small angle scattering were analyzed with conventional viscoelastic theory using either a Debye or a Cole-Davidson model for the memory function. We also analyzed in the same way the temperature dependence of the transverse Brillouin lines detected in a 90° VH geometry. We show that the Cole-Davidson memory function yields a consistent interpretation of all the spectra. The resulting shear and longitudinal relaxation times are equal within their error bars, and are about 2.5 times smaller than the ? relaxation time previously determined. The static shear viscosity values deduced from the analysis of the propagating transverse waves agree, at all temperatures, with the measured viscosity values.

C. Dreyfus; M. J. Lebon; F. Vivicorsi; A. Aouadi; R. M. Pick; H. Z. Cummins

2001-03-29T23:59:59.000Z

319

Rogers, V.C., K.K. Nielson, 1991, "Multiphase Radon Generation and Transport in Porous Minerals," Health Physics Vol. 60, No. 6, 807-813.  

E-Print Network [OSTI]

Radioactivity (TENR) Cause by Non-Uranium Mining, October 16-19, Szczyrk, Poland. Usman, S.S., H.Spitz, and J Limited presented at the Nuclear Regulatory Commission Uranium Recovery Licensing Workshop, January 11 to Monitor Radon Emissions from Uranium Tailings," Contract Number EP-D-05-002, Work Assignment No. 4

320

Discoloration resistant, flexible, radiation curable coating compositions  

SciTech Connect (OSTI)

A low dosage radiation polymerizable protective and decorative coating composition or paint, coated articles bearing such a protective coating and processess for preparing such articles. The radiation polymerizable coating composition comprises an organic resin/monomer mixture of: (A) between about 97 and about 3 weight percent alphabeta olefinically unsaturated organic resin containing between about 0.5 and about 5 vinyl unsaturation units per 1000 molecular weight of said resin, and (B) between about 3 and about 97 weight percent vinyl monomers polymerizable with said resin upon exposure to radiation, characterized in that said vinyl monomers include N-vinyl-2-pyrrolidone in an amount of from about 3 and up to about 10 weight percent based on the total weight of (A) and (B). The flexible coating exhibits excellent physical qualtities and good adhesion to a variety of substrates being particularly suitable for use on vinyl chloride fabric, wherein it is discoloration resistant after heat aging. Preferred articles bearing such a coating, which may comprise large amounts of pigment, are preferably cured by exposure to electron beam radiation.

Cassatta, J.C.; Garrett, D.L. Jr.; Van Oene, H.

1984-10-16T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Optimum energy and by-product recovery in chlorinated hydrocarbon disposal systems  

SciTech Connect (OSTI)

This paper covers the three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer facility. These are the incineration, the energy recovery system, and the by-product recovery system. It is shown that the overall efficiency of the energy and by-product recovery systems is dependent on the optimization of the primary combustor (incineration system). 11 refs.

Santoleri, J.J.

1982-01-01T23:59:59.000Z

322

Microbial based chlorinated ethene destruction  

DOE Patents [OSTI]

A mixed culture of Dehalococcoides species is provided that has an ability to catalyze the complete dechlorination of polychlorinated ethenes such as PCE, TCE, cDCE, 1,1-DCE and vinyl chloride as well as halogenated ethanes such as 1,2-DCA and EDB. The mixed culture demonstrates the ability to achieve dechlorination even in the presence of high source concentrations of chlorinated ethenes.

Bagwell, Christopher E. (Aiken, SC); Freedman, David L. (Clemson, SC); Brigmon, Robin L. (North Augusta, SC); Bratt, William B. (Atlanta, GA); Wood, Elizabeth A. (Marietta, GA)

2009-11-10T23:59:59.000Z

323

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Second quarter 1993  

SciTech Connect (OSTI)

Groundwater monitoring continued at the Savannah River Plant. During second quarter 1993, nine constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread constituents. Chloroethene (vinyl chloride), dichloromethane (methylene chloride), 1,1-dichloroethylene, gross alpha, lead, nonvolatile beta, or tetrachloroethylene also exceeded standards in one or more wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1993-09-01T23:59:59.000Z

324

Synthesis of poly(vinyl alcohol)-graft-poly(-caprolactone) and poly(vinyl alcohol)-graft-poly(lactide) in melt with magnesium hydride as catalyst  

E-Print Network [OSTI]

)-graft-poly(lactide) in melt with magnesium hydride as catalyst Nadia Guerrouani, André Mas* , François Schué UMR 5253 CNRS-UM2%) was investigated using MgH2 environmental catalyst and melt-grown ring opening polymerization (ROP) of -caprolactone (CL) and L- lactide (LA), that avoiding undesirable toxic catalyst and solvent. The ability of Mg

Paris-Sud XI, Université de

325

Transition Metal Chlorides Are Lewis Acids toward Terminal Chloride Attached to Late Transition Metals  

Science Journals Connector (OSTI)

In summary, the polymer chain in Figure 3 is decorated by substituent Cu3 hanging outward from the chain, like a Christmas tree string of lights. ... This sheds new light on the classification of the types of core structure accessible which, in turn, provides a useful means for developing the so-far missing magneto-structural correlation algorithm for these finite 0-D systems. ...

Alice K. Hui; Brian J. Cook; Daniel J. Mindiola; Kenneth G. Caulton

2014-03-10T23:59:59.000Z

326

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, E.D. Jr.

1995-07-11T23:59:59.000Z

327

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

328

Alkyl Fumarate?Vinyl Acetate Copolymer as Flow Improver for High Waxy Indian Crude Oils  

Science Journals Connector (OSTI)

Regional Research Laboratory, Jorhat 785006, Assam, India ... The efficacy of these copolymers as flow improvers (FI)/pour point depressants (PPD) was tested on Indian crude oils having similar wax (points is a well-established phenomenon. ...

A. Borthakur; D. Chanda; S. R. Dutta Choudhury; K. V. Rao; B. Subrahmanyam

1996-05-21T23:59:59.000Z

329

Synthetic Approaches to Skeletally Diverse Sultams Using Vinyl- and ?-Halo Benzenesulfonamides  

E-Print Network [OSTI]

of the corresponding benzothiazepine (n = 1)/benzothiazocine (n = 2) 1,1-dioxides as governing factors in this notable thermodynamic equilibration of atropdiastereomers. Current efforts are focused on the computational calculation for the energy barrier between two...

Jeon, KyuOk

2012-08-31T23:59:59.000Z

330

Neutron Scattering Study of Vermiculite?Poly(vinyl methyl ether) Mixtures  

Science Journals Connector (OSTI)

Neutrons scattered by the gel samples were recorded on a two-dimensional area detector, software coded as 128 × 128 pixels, situated 1.5 m behind the samples, covering the approximate q range between 0.2 and 2 nm-1, where the wavenumber q is defined by the equation with ? being the scattering angle. ... The quartz sample cells used were practically transparent to neutrons at the wavelength utilized on the SANS-J, and the small angle neutron scattering from D2O was of low intensity and completely unstructured over the q range studied. ...

H. Jinnai; M. V. Smalley; T. Hashimoto; S. Koizumi

1996-03-06T23:59:59.000Z

331

Determination of properties of PVE lubricants with HFC refrigerants[PolyVinylEther  

SciTech Connect (OSTI)

Polyalkyleneglycol (PAG) and polyol ester (POE) have been developed as refrigeration lubricants, used with HFC134a. PAG is used for automotive air conditioning systems and POE is used for domestic reciprocating refrigerators and for A/C systems. Although PAG exhibits good lubricity performance, it is difficult to use for domestic reciprocating refrigerators due to its low dielectric property. POE is difficult to use for automotive A/C systems, due to hydrolysis and poor lubricity performance. Polyvinylether (PVE) can be used in place of PAG and POE with HFC refrigerants. PVE is used for A/C systems as well as refrigerator and freezer applications. PVE is an ideal lubricant for use with HFCs.

Kaneko, Masato; Sakanoue, Shuichi; Tazaki, Toshihiro; Tominaga, Shoichi; Takagi, Minoru; Goodin, M.

1999-07-01T23:59:59.000Z

332

Poly(vinyl alcohol)-based buffering membranes for isoelectric trapping separations  

E-Print Network [OSTI]

Isoelectric trapping (IET) in multicompartment electrolyzers (MCE) has been widely used for the electrophoretic separation of ampholytic compounds such as proteins. In IET, the separation occurs in the buffering membranes that form a step-wise p...

Craver, Helen C.

2009-05-15T23:59:59.000Z

333

Energetics of Homogeneous Intermolecular Vinyl and Allyl Carbon-Hydrogen Bond Activation by the  

E-Print Network [OSTI]

of alkanes for both industrial and synthetic applications. While the goal of catalytic activation-H bonds,4 few have allowed for quantification of activated products crucial to the assessment of a C-H bond to a coordinatively unsaturated late-metal center (d8 Rh and Ir), generating a relatively

Jones, William D.

334

E-Print Network 3.0 - acid-labile cholesterol-vinyl ether-peg...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystallization of Recombinant Crithidia fasciculata Tryparedoxin Summary: of 30% polyethylene glycol monomethyl ether (PEG MME) 2000, 0.1 M TrisHCl, pH 8.2, 1% dimethyl Source:...

335

Accelerated Ovarian Failure Induced by 4-Vinyl Cyclohexene Diepoxide in Nrf2 Null Mice  

Science Journals Connector (OSTI)

...Exposure to 2-bromopropane at the work place...sensitive than rats to VCH ovotoxicity...euthanized by CO2 inhalation. The liver and...4-vinylcyclohexene in rat and mouse liver...containing 2-bromopropane. Scand. J...1999. 2-Bromopropane causes ovarian...oocytes in female rats. Toxicol. Appl...

Xiaoming Hu; Jenny R. Roberts; Patrick L. Apopa; Yuet Wai Kan; Qiang Ma

2006-02-01T23:59:59.000Z

336

Geometry-Selective Synthesis of E or ZN-Vinyl Ureas (N-Carbamoyl Enamines)  

Science Journals Connector (OSTI)

Julien Lefranc , Daniel J. Tetlow , Morgan Donnard , Alberto Minassi , Erik Gálvez , and Jonathan Clayden * ... Violette, A.; Averlant-Petit, M. C.; Semetey, V.; Hemmerlin, C.; Casimir, R.; Graff, R.; Marraud, M.; Briand, J.-P.; Rognan, D.; Guichard, G. J. Org. ...

Julien Lefranc; Daniel J. Tetlow; Morgan Donnard; Alberto Minassi; Erik Ga?lvez; Jonathan Clayden

2010-12-17T23:59:59.000Z

337

The effect of temperature and relative humidity levels upon charcoal tube sampling for vinyl choloride  

E-Print Network [OSTI]

. O cart-per-million (ppm), and a ceiling 5. 0 ppm averaged over any period not exceeding 15 (5) minutes. ' In an effo rt to determine a worker's TWA for UCM, a tube packed with activated carbon is used as an adsorbent. The accumulated samole.... Organic vapors, as far back as the 1950's have been successfully collected on solid adsorbents followed by desorption into a GC-FID. The chromatograph is able to separate a mixture into components, and quantitatively measure each one, making it superior...

McCaskill, Gerald Daniel

2012-06-07T23:59:59.000Z

338

Synthesis and Properties of Biodegradable Poly(vinyl alcohol)/Organo-nanoclay Bionanocomposites  

Science Journals Connector (OSTI)

Biodegradable nanocomposites comprising of biodegradable polymers and bioactive organically modified layered silicates commonly reveal extremely enhanced mechanical and various other properties when compared to t...

Shadpour Mallakpour; Mohammad Dinari

2012-09-01T23:59:59.000Z

339

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

340

Synthesis and Modification of Alternating Copolymers Based on Vinyl Ethers, Chlorotrifluoroethylene, and  

E-Print Network [OSTI]

, in dynamic mode, under air, showed decomposition temperatures (Td,10%) higher than 200 °C. Electrochemical recent fuel cells technology, combining the best of both alkaline batteries and solid polymer electrolyte-exchange membranes, do not require noble metals (Pt, Ru...) as catalysts to function, which is one of the main

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Tetrahedron: Asymmetry report number 86 a-Vinylic amino acids: occurrence, asymmetric synthesis,  

E-Print Network [OSTI]

-Substituted . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 871 2.3. c-Substituted . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 871 2.3.1. MVG . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 871 2.3.2. AVG

Berkowitz, David

342

Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton dissociation of vinyl  

E-Print Network [OSTI]

Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton of laser intensity on the production of fragment energy distribu- tions. Laser induced fluorescence (LIF pumping is pro- portional to the light intensity, the final energy of the parent molecule

Zare, Richard N.

343

Facile monomer stabilization approach to fabricate iron/vinyl ester resin nanocomposites  

E-Print Network [OSTI]

such as photovol- taic (solar) cells [11], polymer-electrolyte membrane fuel cells [12], and magnetic data storage in the marine (Naval sub- marine) industry [18] due to its good mechanical properties such as large Young

Guo, John Zhanhu

344

Solute Diffusion in Poly(vinyl alcohol)/Poly(acrylic acid) Interpenetrating Networks  

E-Print Network [OSTI]

) and poly(acrylic acid) (PAA) by varying the content of PAA in the hydrogel membrane. We also compared the permeation of solutes through interpen- etrating polymer networks (IPNs) at pH 3 (below the pKa of PAA) and pH 6 (above the pKa of PAA) and determined that permeation is a function of size exclu- sion parameters

Peppas, Nicholas A.

345

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network [OSTI]

Ethylene Carbonate in Li-Ion Battery Electrolyte Guoyingof a commercial Li-ion battery electrolyte containing 2 %are an important part of Li-ion battery technology yet their

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

346

Synthesis and thermal chemistry of selected N-vinylisoquinuclidenes  

E-Print Network [OSTI]

. wi th thi onyl 0 Ph I 0 H02C H02C / N 0 CH 0 C CH 02C Ph g=0 OCH3 CH302C CH3 2 =0 27 chloride in anhydrous methanol at 25'C t'o furnish, in 81K yield, an interesting product g. This new product contained not only the desired..., 690 cm 1 UV (CH3CN) ~ 287 nm (c 20, 900; H-NMR (CDC13)6 3. 75 (m, 2H, H-5 and H-6), 4. 1 (m, 1H, H-4), 4. 0 (s, 6H, OCH3), 5. 4 (m, 1H, H-l), 6. 4 (d, 1H, J=16 Hz, N-vinyl), 6. 9 (m, 2H, H-7 and H-8 vinyl), 7. 6 (m, SH, aromatic), 7. 8 (d, 1H, J=16...

Beamer, Ralph Lewis

1978-01-01T23:59:59.000Z

347

Synthesis and characterization of several molybdenum chloride cluster compounds  

SciTech Connect (OSTI)

Investigation into the direct synthesis of Mo/sub 4/Cl/sub 8/(P(C/sub 2/H/sub 5/)/sub 3/)/sub 4/ from Mo/sub 2/(OAc)/sub 4/ led to a synthetic procedure that produces yields greater than 80%. The single-crystal structure disclosed a planar rectangular cluster of molybdenum atoms. Metal-metal bond distances suggest that the long edges of the rectangular cluster should be considered to be single bonds and the short metal-metal bonds to be triple bonds. This view is reinforced by an extended Hueckel calculation. Attempts to add a metal atom to Mo/sub 4/Cl/sub 8/(PR/sub 3/)/sub 4/ to form Mo/sub 5/Cl/sub 10/(PR/sub 3/)/sub 3/ led instead to a compound with the composition Mo/sub 8/Cl/sub 16/(PR/sub 3/)/sub 4/. Solution and reflectance uv-visible spectra and x-ray photoelectron spectra suggest that tetranuclear molybdenum units are present. The facile reaction between Mo/sub 8/Cl/sub 16/(PR/sub 3/)/sub 4/ and PR/sub 3/ imply that the linkage between tetrameric units is weak.

Beers, W.W.

1983-06-01T23:59:59.000Z

348

Water content and morphology of sodium chloride aerosol particles  

E-Print Network [OSTI]

to explain the H2O content. The model in which the NaCl particles contain pockets of aqueous NaCl solution was found to be most consistent with the spectroscopic observations. The relevance of salt particle morphology and water content to atmospheric aerosol...

Weis, David D.; Ewing, George E.

1999-09-20T23:59:59.000Z

349

Redox flow batteries based on supporting solutions containing chloride  

DOE Patents [OSTI]

Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-01-14T23:59:59.000Z

350

An automated method for determination of chloride and sulfate in ...  

Science Journals Connector (OSTI)

Jan 28, 1974 ... for hydrogen ions yielding an acidic solution of HCl, H2SOh, and usually a small amount of HN03, all of which are dissociated, and.

2000-01-02T23:59:59.000Z

351

Catalytic hydrogenation of an aromatic sulfonyl chloride into thiophenol  

E-Print Network [OSTI]

data collected in a continuous process mode show that the catalyst is deactivated during an experiment when the process time equal to two to three times the residence time of the liquid within the reactor. XRD analysis shows that the active sites...

Rouckout, Nicolas Julien

2009-05-15T23:59:59.000Z

352

Toluene pyrolysis studies and high temperature reactions of propargyl chloride  

SciTech Connect (OSTI)

The main focus of this program is to investigate the thermal decompositions of fuels that play an important role in the pre-particle soot formation process. It has been demonstrated that the condition of maximum soot yield is established when the reaction conditions of temperature and pressure are sufficient to establish a radical pool to support the production of polyaromatic hydrocarbon species and the subsequent formation of soot particles. However, elevated temperatures result in lower soot yields which are attributed to thermolyses of aromatic ring structures and result in the bell-shaped dependence of soot yield on temperature. The authors have selected several acyclic hydrocarbons to evaluate the chemical thermodynamic and kinetic effects attendant to benzene formation. To assess the thermal stability of the aromatic ring, the authors have studied the pyrolyses of benzene, toluene, ethylbenzene, chlorobenzene and pyridine. Time-of-flight mass spectrometry (TOF) is employed to analyze the reaction zone behind reflected shock waves. Reaction time histories of the reactants, products, and intermediates are constructed and mechanisms are formulated to model the experimental data. The TOF work is often performed with use of laser schlieren densitometry (LS) to measure density gradients resulting from the heats of various reactions involved in a particular pyrolytic system. The two techniques, TOF and LS, provide independent and complementary information about ring formation and ring rupture reactions.

Kern, R.D.; Chen, H.; Qin, Z. [Univ. of New Orleans, LA (United States)

1993-12-01T23:59:59.000Z

353

Modeling acid-gas generation from boiling chloride brines  

E-Print Network [OSTI]

of the unsaturated zone at Yucca Mountain, Nevada. J. ofwaste emplacement tunnels at Yucca Mountain, Nevada. J. ofScale Heater Test at Yucca Mountain. International Journal

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

354

Thermal diffusion processes in aqueous sodium chloride solutions  

SciTech Connect (OSTI)

The experimental results for the Soret coefficients are variable, but suggest a trend with NaCl concentration that is consistent with electrolyte solution behavior. The temperature dependence of the Soret coefficients is in approximate agreement with previous measurements obtained using other techniques. In general, the Soret coefficient values are best interpreted based on the expansion of the fluid inclusion migration fields. The high temperature values for {sigma} at 1.0 N NaCl concentration suggest an expansion of the migration field to smaller inclusion sizes, which for a single halite crystal at these conditions, approach a dimension of one micron. The corresponding fluid inclusion size for the polycrystalline material, where grain boundaries retard the migration, is approximately 10 microns. Although the Soret results obtained in the present study provide additional data for high temperature applications in nuclear waste isolation, more experimentation and new equipment design are required in order to obtain data at temperatures above 80{degree}C. The experimental approach utilized in this study is limited in that respect. The almost immeasurable nature of the thermal diffusion process for the brines as examined in the laboratory, suggests that this effect will be insignificant (outside of fluid inclusion migration) in most rock-water interactions associated with a rocksalt nuclear waste repository. Other effects, such as convective fluid transport, pressure solution, and groundwater flow, will be orders-of-magnitude more important in evaluating the critical nature of brine migration, waste canister corrosion, and the potential for leaching radioisotopes from waste repositories.

Cygan, R.T. [Sandia National Labs., Albuquerque, NM (United States); Jarrell, G.D. [ManTech Environmental Technology, Inc., Corvallis, OR (United States)

1992-08-18T23:59:59.000Z

355

Modeling acid-gas generation from boiling chloride brines  

E-Print Network [OSTI]

Factor 1E-1 b) CaCl:2H2O Halite Sylvite Fluorite Salt (KNO 3 ), soda niter (NaNO 3 ), halite (NaCl), sylvite (KCl),the precipitation of halite at a concentration factor around

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

356

A Novel Low-Cost Sodium-Zinc Chloride Battery  

SciTech Connect (OSTI)

The sodium-metal halide (ZEBRA) battery has been considered as one of the most attractive energy storage systems for stationary and transportation applications. Even though Na-NiCl2 battery has been widely investigated, there is still a need to develop a more economical system to make this technology more attractive for commercialization. In the present work, a novel low-cost Na-ZnCl2 battery with a thin planar ??-Al2O3 solid electrolyte (BASE) was proposed, and its electrochemical reactions and battery performance were investigated. Compared to the Na-NiCl2 chemistry, the ZnCl2-based chemistry was more complicated, in which multiple electrochemical reactions including liquid-phase formation occurred at temperatures above 253°C. During the first stage of charge, NaCl reacted with Zn to form Na in the anode and Na2ZnCl4 in the cathode. Once all the residual NaCl was consumed, further charging led to the formation of a NaCl-ZnCl2 liquid phase. At the end of charge, the liquid phase reacted with Zn to produce solid ZnCl2. To identify the effects of liquid-phase formation on electrochemical performance, button cells were assembled and tested at 280°C and 240°C. At 280°C where the liquid phase formed during cycling, cells revealed quite stable cyclability. On the other hand, more rapid increase in polarization was observed at 240°C where only solid-state electrochemical reactions occurred. SEM analysis indicated that the stable performance at 280°C was due to the suppressed growth of Zn and NaCl particles, which were generated from the liquid phase during discharge of each cycle.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2013-02-28T23:59:59.000Z

357

Methylene II. Gas Phase Reactions with Ethyl Chloride  

Science Journals Connector (OSTI)

27 August 1968 research-article Methylene II. Gas Phase Reactions...free-radical mechanism in which CH abstracts a chlorine or a hydrogen atom from C...in electronic structure rather than energy content. The Royal Society is collaborating...

1968-01-01T23:59:59.000Z

358

Fate and effects of methylene chloride in activated sludge.  

Science Journals Connector (OSTI)

...domestic wastewater treatment plant. Approximately...material balance at each time...Bedford, Mass.). A 5-ml...synthetic aerobic wastewater treatment plant. nal concen...standard wastewater treatment design factor...approximation, a mass balance for the reactor...

G M Klecka

1982-09-01T23:59:59.000Z

359

Method for making a uranium chloride salt product  

DOE Patents [OSTI]

The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

2004-10-05T23:59:59.000Z

360

Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence  

E-Print Network [OSTI]

in oxygen atmospheres 0%­21% were obtained with a signal to noise ratio better than 150. Photobleaching physical principles, electrochemistry or luminescence. Electrochemical devices result in analyte

Ghosh, Ruby N.

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Depolarized light-scattering study of molten zinc chloride  

Science Journals Connector (OSTI)

Depolarized light-scattering experiments on molten ZnCl2 have been performed in the frequency range 1–4000 GHz between 300 and 650 °C. The ? relaxation was observed up to 650 °C. Comparison with mode coupling theory was attempted but gave inconclusive results due to the strong boson peak. The crossover temperature Tc was found to be in the range 270–310 °C. The thermal evolution of the boson peak in the liquid phase was followed up to 650 °C.

M. J. Lebon; C. Dreyfus; G. Li; A. Aouadi; H. Z. Cummins; R. M. Pick

1995-05-01T23:59:59.000Z

362

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network [OSTI]

ix Introduction. A. Coal Liquefaction Overview B.L ZnCl 2-catalyzed Coal Liquefaction . . . . . . . . . • ,Results. . . • . ZnC1 2/MeOH Coal liquefaction Process

Joyce, Peter James

2011-01-01T23:59:59.000Z

363

Triphenyltetrazolium Chloride as a Dye for Vital Tissues  

Science Journals Connector (OSTI)

...The Pennsylvania State College Triphenyltetrazolium...Leptospirosis in Micronesia F. W. HARTMANN...man. Since the United States now has control...it was one of the territories mandated to Japan...The Pennsylvania State College The use...

A. M. MATTSON; C. O. JENSEN; R. A. DUTCHER

1947-09-26T23:59:59.000Z

364

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides  

E-Print Network [OSTI]

The trifluoromethyl group can dramatically influence the properties of organic molecules, thereby increasing their applicability as pharmaceuticals, agrochemicals, or building blocks for organic materials. Despite the ...

Cho, Eun Jin

365

Formation of films in hydrolysing ferric chloride solutions  

Science Journals Connector (OSTI)

... a solution of 0.01 M FeCls solution is sprayed onto an asbestos mesh or micro-grid, due to the drying of droplets of solution caught in the holes of the ... , due to the drying of droplets of solution caught in the holes of the micro-grid or between the asbestos fibres. Drying promotes the hydrolysis into the small polymeric molecules, ...

T. M. ARMITAGE; A. M. POSNER

1978-03-30T23:59:59.000Z

366

Lithium-Thionyl Chloride Batteries for the Mars Pathfinder Microrover  

SciTech Connect (OSTI)

A discussion of the power requirements for the Mars Pathfinder Mission is given. Topics include: battery requirements; cell design; battery design; test descriptions and results. A summary of the results is also included.

Deligiannis, F.; Frank, H.; Staniewicz, R.J.; Willson, J. [SAFT America, Inc., Cockeysville, MD (United States)

1996-02-01T23:59:59.000Z

367

Health assessment for H and H Incorporated Burn Site, Farrington, Virginia, Region 3. CERCLIS No. VAD980539878. Preliminary report  

SciTech Connect (OSTI)

The H H Incorporated Burn Site, located in Hanover County, Virginia, contains a pit where dry printing ink residues were disposed of. Groundwater contaminants of concern (and maximum concentrations) include benzene (25 ppb), toluene (1180 ppb), chromium (110 ppb), barium (1,300 ppb), beryllium (20 ppb). Organics, including phthalates (131,000 ppb), vinyl chloride (3,600 ppb), toluene (82 ppb), and xylenes (45 ppb), were detected in leachate and/or runoff, presumably emanating from the pit area. The site is considered to be of potential public health concern because of the risk to human health caused by the possibility of human exposure to hazardous substances.

Not Available

1988-05-05T23:59:59.000Z

368

Fluorescence emission as a probe to investigate electrochemical polymerization of 9-vinylanthracene  

SciTech Connect (OSTI)

The cationic polymerization of 9-vinylanthracene can be initiated at a transparent SnO/sub 2/ electrode with the application of anodic potentials (E > 1.1 V vs. saturated sodium chloride calomel electrode) in acetonitrile solutions. The excimer emission (emission maximum approx.500 nm) of poly(9-vinyl-anthracene) which is distinguishable from the monomer fluorescence emission (emission maxima 410, 430 nm) has been used to probe the electrochemical polymerization process directly. The in situ spectroelectrochemical technique, which would be useful in obtaining kinetic and mechanistic information of the electropolymerization process, is described.

Kamat, P.V.

1987-07-01T23:59:59.000Z

369

Resource recovery - a byproduct of hazardous waste incineration  

SciTech Connect (OSTI)

Three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer (VCM) facility are described: the incinerator, the energy-recovery system, and the byproduct-recovery system. The overall efficiency of the energy- and *byproduct-recovery systems is dependent on the optimization of the primary combustor. An example is presented in table form which lists typical waste quantities for the plant and operating costs, including utility requirements for the incinerator system, the quench, absorber and scrubber. Savings that can result by the addition of the energy- and acid-recovery systems can pay for the waste disposal system and return money to the plant.

Santoleri, J.J.

1982-11-01T23:59:59.000Z

370

Temperature-responsive surface-functionalized polyethylene films  

E-Print Network [OSTI]

precursors. PhotograAing on these surfaces (Equation 1) in the presence of various vinyl monomers was found to be very effective, as XPS and ATR-IR data indicated the extent of grafting could be controlled by monomer concentration and the solvent employed... in this case was measured by following the percent quenching of pyrene as these films were suspended in varying concentrations of a quenching agent, such as N-N'-dimethylethanolamine, in solvents such as THF, methylene chloride and ethanol. The value...

Ponder, Bill C.

2012-06-07T23:59:59.000Z

371

Global petrochemical R and D focus on projects that provide a return  

SciTech Connect (OSTI)

Because of tough market conditions, the research and development of new petrochemical products is down along with spending. The paper discusses the new marketing strategy used by petrochemical developers while relenting all blue sky research to academia. The paper discusses developments and research in the four main targeted research areas. These include basic petrochemicals such as ethylene an propylene; petrochemical intermediates such as 1,4 butanediol and vinyl chloride monomer; commodity polymers, notably linear low density polyethylene; and, specialty polymers such as engineering plastics. The advances in production technologies in these areas are then discussed.

Knott, D.

1996-08-26T23:59:59.000Z

372

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Fourth quarter 1993 and 1993 summary  

SciTech Connect (OSTI)

During fourth quarter 1993, 10 constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Carbon tetrachloride, chloroform, chloroethane (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. Elevated constituents were found in numerous Aquifer Zone 2B{sub 2} (Water Table) and Aquifer Zone 2B{sub 1}, (Barnwell/McBean) wells and in two Aquifer Unit 2A (Congaree) wells. The groundwater flow direction and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Butler, C.T.

1994-03-01T23:59:59.000Z

373

Mixed Waste Management Facility (MWMF) groundwater monitoring report: Third quarter 1993  

SciTech Connect (OSTI)

During third quarter 1993, eight constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread constituents Chloroethene (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. The elevated constituents were found in Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1} (Barnwell/McBean) wells. No elevated constituents were exhibited in Aquifer Unit IIA (Congaree) wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1993-12-01T23:59:59.000Z

374

OMV studies ethylene expansion in Germany  

SciTech Connect (OSTI)

OMV(Vienna) is evaluating plans to debottleneck its ethylene plant at Burghausen from 310,000 m.t./year to at least 400,000 m.t./year. Senior v.p. Jochen Berger says OMV is studying the limits to which the cracker can be expanded. {open_quotes}We`re pretty sure we can go to 400,000 m.t./year, but in two months we`ll have a better idea,{close_quotes} says Berger. The expansion will also depend on the future requirements of downstream operations at the Burghausen site, which include OMV plastics subsidiary PCD`s high-density polyethylene and polypropylene units and the vinyl chloride monomer and polyvinyl chloride units operated by Hoechst-Wacker joint venture Vinnolit.

NONE

1996-10-23T23:59:59.000Z

375

Thailand's downstream projects proliferate  

SciTech Connect (OSTI)

Thailand continues to press expansion and modernization of its downstream sector. Among recent developments: Construction of an olefins unit at Thailand's second major petrochemical complex and a worldscale aromatics unit in Thailand is threatened by rising costs. Thailand's National Petrochemical Corp (NPC) let a 9 billion yen contract to Mitsui Engineering and Shipbuilding Co. and C. Itoh and Co. for a dual fuel cogeneration power plant at its Mab Ta Phud, Rayong province, petrochemical complex. Financing is in place to flash a green light for a $530 million Belgian-Thai joint venture sponsoring a worldscale polyvinyl chloride/vinyl chloride monomer plant in Thailand. Work is more than 50% complete on the $345 million second phase expansion of Thai Oil's Sri Racha refinery in Chon Buri province. Petroleum Authority of Thailand (PTT) endorsed a plan to install two more natural gas processing plants in Thailand to meet rapidly growing domestic demand for petroleum gas.

Not Available

1991-06-03T23:59:59.000Z

376

Ambipolar Behavior in All-Carbon-Nanotube Field-Effect Transistors by Poly(Vinyl Alcohol) Coating  

E-Print Network [OSTI]

parameter analyzer (Agilent 4156C) at room temperature under ambient conditions. Fig. 1 Schematic of device including SWNT diameter distribution, capacitances of PVA film, and I-V characteristics when coating. Wang, M. Shim, K. Roy, M. A. Alam and J. A. Rogers, Nature 454, 495 (2008). 2. D. M. Sun, M. Y

Maruyama, Shigeo

377

Durability of E-glass fiber reinforced vinyl ester polymer composites with nanoclay in an alkaline environment.  

E-Print Network [OSTI]

??This study was conducted to determine the effect of clay content in the GFRP (glass fiber reinforced polymer) composite samples as they are aged in… (more)

Ravindran, Naveenkamal.

2005-01-01T23:59:59.000Z

378

Effect of nanoclay on the phase separation behavior of poly(methyl methacrylate)/poly(vinyl acetate) binary polymer blends  

Science Journals Connector (OSTI)

The effect of nanoclay on the phase-separation behavior of poly(...T c and delay time t D of isothermal phase-separation also decrease, and the variation amplitude depends on the m...

Ji-shi Zhao; Min Zuo ??; Chao-ying Lin; Qiang Zheng

2014-11-01T23:59:59.000Z

379

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network [OSTI]

columns. Industrial & Engineering Chemistry, 20:1196–1200,process. Industrial & Engineering Chemistry Research, 42:process. Industrial & Engineering Chemistry Research, 50:

Tu, TungSheng

2013-01-01T23:59:59.000Z

380

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network [OSTI]

both dynamic economic optimization and process control isand R. Amrit. Optimizing process economic performance usingOptimizing chemical processes from an economic perspective

Tu, TungSheng

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Photoredox Vinylation of Amino Acids and NAryl Amines Adam Noble and David W. C. MacMillan*  

E-Print Network [OSTI]

-tert- butoxycarbonyl (N-Boc) -amino acids,7,8 a CO2-extrusion mechanism that has implications for the use of biomass feedstocks in conjugate additions and organometallic couplings. Allylic amines have long been attractive

MacMillan, David W. C.

382

Poly(N-vinyl-2-pyrrolidone) elution from polysulfone dialysis membranes by varying solvent and wall shear stress  

Science Journals Connector (OSTI)

Packed water was collected from both the dialysate and blood sides of the wet-type dialyzer APS-15SA. The dialysate and blood sides of the moist- and dry-type dialyzers CX-1.6U and FX140, respectively...

Koki Namekawa; Masato Matsuda; Makoto Fukuda; Ami Kaneko…

2012-06-01T23:59:59.000Z

383

Blower upkeep, energy savings estimated at $20,000/yr  

SciTech Connect (OSTI)

Vinyl chloride gas must be removed from operating vessels in a polymerization process at Occidental Chemical, Addis, LA. If left intact, the gases can polymerize and form deposits. Considered for this function were reciprocating and liquid ring type compressors. They were rejected, however, because of anticipated high valve maintenance and energy consumption. Since high reliability and leak-free performance are essential, two double-mechanical-sealed, positive displacement blowers were installed with water injection in 1980. The blowers are designed for those special applications where gas leak tightness is required or where continuous, high-pressure or vacuum, single-stage or two-stage is needed. The lobe-type blowers were selected by Occidental because they were considered to be best suited for the low-pressure differential operation. All internal surfaces are specially cleaned to reduce contamination and may be operated with non-hydrocarbon lubricants. A back-up seal on the drive shaft provides protection against leakage of process gas to the atmosphere. Maintenance and energy savings are estimated at $20,000/yr. The blowers were used with the water injection technique because previous experience vinyl chloride monomer indicated that there were major deposits inside the compressors and ring units. The blowers have provided contaminant-free (oil-free) monomer, and the water injection has prevented the polymerization material from sticking to the surfaces of the blowers. This has ensured practically trouble-free operation, and has greatly reduced maintenance and operation downtime, significantly reducing cost.

Diehl, R.; Powers, J.

1987-05-01T23:59:59.000Z

384

An electrocyclic strategy to poly(triarylmethyl radical) polymers: Potential organic ferromagnets  

SciTech Connect (OSTI)

Recent interest in organic ferromagnetism has been stimulated by the idea that large poly(triarylmethyl radical) polymers in which the radical centers are connected by [open quotes]meta[close quotes]-aryl groups may possess ferromagnetic properties. However, synthesis of these polyradicals has been limited by stepwise methods that are unsuitable for the preparation of large polymers. This limitation represents a primary challenge confronting the field. The authors have developed the first polymeric strategy to poly (m-triarylmethyl radical) precursors that involves an electrocyclic formation of the [open quotes]meta[close quotes]-substituted triarylmethyl chloride repeating unit from a polypropynol precursor. Poly[(E)-6-[beta]-chloroethenyl-1,3-phenylene-1-phenylpropynol-1,3-ylene] was prepared by palladium-catalyzed coupling of a bifunctional acetylene-aryl iodide monomer. The stable polymer reacted with thionyl chloride to form an unstable polychloroallene intermediate that underwent an electrocyclic conversion to the polyradical precursor, poly(1-chloro-2,7-naphthalenechlorobenzylidene). The reduced polyradicals exhibited properties of radical-radical coupling, and preparation of a second generation polymer that would overcome this problem has been initiated. The polymeric strategy was based on model studies that showed that (E)-3-(2-[beta]-chloroethenylphenyl)-1,1-diphenylpropynol, when converted to the corresponding chloroallene with thionyl chloride, underwent an electrocyclic conversion to [beta]-(1-chlornaphthyl)diphenylmethyl chloride. The strategy expanded upon the use of triarylpropynes as precursors to triarylmethyl chlorides, and extension of both approaches to higher analogs was demonstrated with dimeric systems. The electrocyclic processes were found to occur only for the trans-vinyl chlorides; the cis-isomers were found to undergo an alternative concerted cyclization to benzofluorene products.

Morelli, J.P.

1992-01-01T23:59:59.000Z

385

Production and sequence validation of a complete full length ORF collection for the pathogenic bacterium Vibrio cholerae  

Science Journals Connector (OSTI)

...VcCD00017918 FLH197666.01F DQ775140 type IV pilus assembly protein PilB VC2425 pilC NP_232055 VcCD00017884 FLH197628.01F DQ775141 type IV pilin biogenesis protein PilC VC2426 pilD NP_232056 VcCD00061226 FLH236445.01F DQ899522 leader peptidase...

Andreas Rolfs; Wagner R. Montor; Sang Sun Yoon; Yanhui Hu; Bhupinder Bhullar; Fontina Kelley; Seamus McCarron; Daniel A. Jepson; Binghua Shen; Elena Taycher; Stephanie E. Mohr; Dongmei Zuo; Janice Williamson; John Mekalanos; Joshua LaBaer

2008-01-01T23:59:59.000Z

386

Assimilation and respiration of radioactive ethylene glycol, in the presence of high sodium chloride concentrations, by a sodium chloride requiring bacterium  

E-Print Network [OSTI]

containing 2 gm ethylene glycol and salts in 250 ml of distilled H20 which was started with a small inoculum of 2 ml suspension (11. 8 mg dry wt) removed 1. 96 gm glycol in 136 hr. Use of a nitrogen-limited medium allowed most of the ethylene glycol... growth on ethylene glycol or propylene glycol favored oxidation of ethylene glycol over glucose while prior growth on glucose favored oxidation of glucose over the iv glycols. Age of the culture had no dramatic effect on the rate of respiration...

Gonzalez, Carlos Francisco

2012-06-07T23:59:59.000Z

387

Program or Field Office: Office of Legacy Management Project Title and I.D. No.: Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida,  

Broader source: Energy.gov (indexed) [DOE]

Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida, Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida, LM 13-13 Location: Largo, Florida Proposed Action or Project Description: DOE proposes to use a Geoprobe to inject emulsified edible soybean oil (EEO) and anaerobic microbial solution into the surficial aquifer at the 4.5 Acre Site adjacent to the DOE Young - Rainey STAR Center (Pinellas Site) in Largo, Florida. The proposed action would enhance naturally occurring anaerobic biodegradation, thereby reducing vinyl chloride contamination along the southwest boundary of the 4.5 Acre Site. Dehalococcoides ethenogenes (DHE) is a type of microbe that occurs naturally in the aquifer. Bioaugmentation with a commercially available DHE culture used in conjunction with the EEO would maximize the efficiency of contaminant biodegradation. No genetically engineered or

388

The Risk Assessment Information System  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2-DICHLOROETHANE 2-DICHLOROETHANE NOTE: Although the toxicity values presented in these toxicity profiles were correct at the time they were produced, these values are subject to change. Users should always refer to the Toxicity Value Database for the current toxicity values. May 1994 Prepared by Dennis M. Opresko, Ph.D., Chemical Hazard Evaluation and Communication Program, Biomedical and Environmental Information Analysis Section, Health Sciences Research Division, *, Oak Ridge, Tennessee. Prepared for OAK RIDGE RESERVATION ENVIRONMENTAL RESTORATION PROGRAM. *Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy under contract No. DE-AC05-84OR21400. 1,2-Dichloroethane is used primarily in the manufacture of vinyl chloride, as well as in the synthesis of tetrachloroethylene, trichloroethylene,

389

Coated metal fiber coalescing cell  

SciTech Connect (OSTI)

A cell is described for coalescing oil droplets dispersed in a water emulsion including an elongated perforated tube core into which the emulsion is injected, layers of oleophilic plastic covered metal mat wound about the core through which the emulsion is forced to pass, the fibers of the metal mat being covered by oleophilic plastic such as vinyl, acrylic, polypropylene, polyethylene, polyvinyl chloride, the metal being in the form of layers of expanded metal or metal fibers, either aluminum or stainless steel. In manufacturing the cell a helix wound wire is formed around the cylindrical plastic coated metal to retain it in place and resist pressure drop of fluid flowing through the metal fibers. In addition, the preferred arrangement includes the use of an outer sleeve formed of a mat of fibrous material such as polyester fibers, acrylic fibers, modacrylic fibers and mixtures thereof.

Rutz, W.D.; Swain, R.J.

1980-12-23T23:59:59.000Z

390

Mixed Waste Management Facility groundwater monitoring report, First quarter 1994  

SciTech Connect (OSTI)

During first quarter 1994, nine constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, the proposed Hazardous Waste/Mixed Waste Disposal Vaults, and the F-Area Sewage Sludge Application Site. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Chloroethene (vinyl chloride), copper, 1,1-dichloroethylene, lead, mercury, nonvolatile beta, or tetrachloroethylene also exceeded standards in one or more wells. Elevated constituents were found in numerous Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1}, (Barnwell/McBean) wells and in one Aquifer Unit IIA (Congaree) well. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1994-06-01T23:59:59.000Z

391

Waste management health risk assessment: A case study of a solid waste landfill in South Italy  

SciTech Connect (OSTI)

An integrated risk assessment study has been performed in an area within 5 km from a landfill that accepts non hazardous waste. The risk assessment was based on measured emissions and maximum chronic population exposure, for both children and adults, to contaminated air, some foods and soil. The toxic effects assessed were limited to the main known carcinogenic compounds emitted from landfills coming both from landfill gas torch combustion (e.g., dioxins, furans and polycyclic aromatic hydrocarbons, PAHs) and from diffusive emissions (vinyl chloride monomer, VCM). Risk assessment has been performed both for carcinogenic and non-carcinogenic effects. Results indicate that cancer and non-cancer effects risk (hazard index, HI) are largely below the values accepted from the main international agencies (e.g., WHO, US EPA) and national legislation ( and ).

Davoli, E., E-mail: enrico.davoli@marionegri.i [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy); Fattore, E.; Paiano, V.; Colombo, A.; Palmiotto, M. [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy); Rossi, A.N.; Il Grande, M. [Progress S.r.l., Via Nicola A. Porpora 147, 20131 Milano (Italy); Fanelli, R. [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy)

2010-08-15T23:59:59.000Z

392

Liver and biliary tract cancer among chemical workers  

SciTech Connect (OSTI)

A recent cohort mortality study of male, hourly wage employees of a large Michigan chemical production and research facility had found a greater than expected number of deaths coded to liver and biliary tract cancer. In response, an additional investigation was then undertaken of the 44 liver and biliary tract cancer deaths observed between 1940 and 1982. A random sample (N = 1,888) of subjects was selected from the total cohort (N = 21,437) to serve as referents. Company work history records were used to classify cases and referents by work area assignment and potential for exposure to 11 selected chemical agents which have been shown to produce cancer of the liver or biliary passages in experimental animals. Statistically significant associations in both positive and negative directions were found for several work areas within the facility. A suggestive association was found for vinyl chloride monomer, based on five cases with presumed exposure.

Bond, G.G.; McLaren, E.A.; Sabel, F.L.; Bodner, K.M.; Lipps, T.E.; Cook, R.R. (Dow Chemical Company, Midland, MI (USA))

1990-01-01T23:59:59.000Z

393

Low-temperature emission spectra of 9-alkylanthracene esters: Dimer photodecomposition and monomer pair interactions in polymer hosts  

SciTech Connect (OSTI)

Effects due to variation in the alkyl chain length of photodimers of 9-alkylanthracene esters on their photodecomposition efficiencies at 12 K and, by implication, the photoproduct migration as a function of temperature within polymer hosts are investigated. It is shown that dimers with longer alkyl chains have a lower photodecomposition efficiency. The extent of photoproduct migration within the polymer following photodecomposition was also studied as a function of alkyl chain length. This migration and its modulation of the interaction between the separating monomers is shown to affect the emission spectrum. Thus, monomer migration was studied in temperature cycling experiments. It was also found, for the polymer hosts investigated - poly(methyl methacrylate), poly(vinyl chloride), and polystyrene - that these properties are host dependent. This result is probably due to the void space differences that exist among these polymers. 17 refs., 10 figs.

Salt, K.; Scott, G.W. (Univ. of California, Riverside, CA (United States))

1994-10-06T23:59:59.000Z

394

Apply reliability centered maintenance to sealless pumps  

SciTech Connect (OSTI)

This paper reports on reliability centered maintenance (RCM) which is considered a crucial part of future reliability engineering. RCM determines the maintenance requirements of plants and equipment in their operating context. The RCM method has been applied to the management of critical sealless pumps in fire/toxic risk services, typical of the petrochemical industry. The method provides advantages from a detailed study of any critical engineering system. RCM is a team exercise and fosters team spirit in the plant environment. The maintenance strategy that evolves is based on team decisions and relies on maximizing the inherent reliability built into the equipment. RCM recommends design upgrades where this inherent reliability is being questioned. Sealless pumps of canned motor design are used as main reactor charge pumps in PVC plants. These pumps handle fresh vinyl chloride monomer (VCM), which is both carcinogenic and flammable.

Pradhan, S. (Exxon Chemicals Canada, Ontario (Canada))

1993-01-01T23:59:59.000Z

395

Revamp of Ukraine VCM plant will boost capacity, reduce emissions  

SciTech Connect (OSTI)

Oriana Concern (formerly P.O. Chlorvinyl) is revamping its 250,000 metric ton/year (mty) vinyl chloride monomer (VCM) plant at Kalusch, Ukraine. At the core of the project area new ethylene dichloride (EDC) cracking furnace and direct chlorination unit, and revamp of an oxychlorination unit to use oxygen rather than air. The plant expansion and modernization will boost capacity to 370,000 mty. New facilities for by-product recycling and recovery, waste water treatment, and emissions reduction will improve the plant`s environmental performance. This paper shows expected feedstock and utility consumption for VCM production. Techmashimport and P.O. Chlorvinyl commissioned the Kalusch plant in 1975. The plant was built by Uhde GmbH, Dortmund, Germany. The paper also provides a schematic of the Hoechst/Uhde VCM process being used for the plant revamp. The diagram is divided into processing sections.

NONE

1996-05-13T23:59:59.000Z

396

Use of tannin anticorrosive reaction primer to improve traditional coating systems  

SciTech Connect (OSTI)

Different anticorrosive schemes applied over plain or previously shot-blasted surfaces of AISI 1010 (UNS G10100) steel plates were compared. Plates were painted with alkydic, vinylic, and epoxy anticorrosive schemes over metal treated previously with pine tannin reaction primer and over its own schemes without previous primer treatment. Anticorrosive tests were conducted in a salt fog chamber according to ASTM B 117-73. Rusting, blistering, and adhesion were assessed over time. The survey was complemented with potentiodynamic scanning tests in sodium chloride (NaCl) solution with a concentration equivalent to seawater. Corrosion currents were determined using Tafel and polarization resistance techniques. Results showed the reaction primer inhibited corrosion by improving adherence. Advantages over traditional conversion primers formulated in a base of zinc chromate in phosphoric medium were evident.

Matamala, G.; Droguett, G. (Universidad de Concepcion (Chile)); Smeltzer, W. (McMaster Univ., Hamilton, Ontario (Canada). Inst. for Materials Research)

1994-04-01T23:59:59.000Z

397

Commodity chemicals from natural gas by methane chlorination  

SciTech Connect (OSTI)

Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

1987-01-01T23:59:59.000Z

398

Thai group set to invest in Chinese petchem complex  

SciTech Connect (OSTI)

A $5-billion refinery and petrochemical complex is planned by Thailand's Charoen Pokphand (Bangkok) at the seaport of Nimpoh, near Shanghai. The company has discussed the project with the central government of China, and state oil and petrochemicals company Sinopec (Beijing) is due to complete a feasibility study within the next two months. Charoen's plastics processing subsidiary, Kuo Shen (Hong Kong), is expected to hold 70% in the venture, Sinopec 20%, and the Chinese government the remaining 10%. Western companies have been invited to participate. Solvay (Brussels), a 49% partner with Charoen Pokphand in the Vinythai polyvinyl chloride (PVC) joint venture at Map Ta Pud, Thailand, has not yet made a commitment. The 5-million m.t./year oil refinery would feed the complex, which will be based on a 450,000-m.t./year ethylene plant, downstream aromatics units, and a range of derivatives plants. The complex, which falls outside the many announced for Thailand's current five-year economic plan, is expcted to be implemented in stages. To begin with, a 120,000-m.t./year PVC plant will be built that will be fed on imported vinyl chloride monomer. Charoen is in discussions with process licensers, including Solvay, European Vinyl Corp., BFGoodrich, and Shinetsu. Half the PVC output will be consumed by Kuo Shen in China, where Charoen has several plastics processing units, including one in Shanghai and one in Nimpoh. Meanwhile, Sinopec's Hong Kong subsidiary is seeking partners to invest in joint venture projects in China. Sinopec president Liu Xuemin says the company is willing to cooperate with overseas companies to establish small petrochemical projects. In addition, Sinopec is negotiating with officials of Dayang in Jiangsu province and the special economic zone of Shen Zhen, near Hong Kong, on joint ventures for plastics and food additives.

Alperowicz, N.

1993-01-06T23:59:59.000Z

399

Vapor-liquid equilibria for copolymer+solvent systems: Effect of intramolecular repulsion  

SciTech Connect (OSTI)

Role of intramolecular interactions in blend miscibility is well documented for polymer+copolymer mixtures. Some copolymer+polymer mixtures are miscible although their corresponding homopolymers are not miscible; for example, over a range of acrylonitrile content, styrene/acrylonitrile copolymers are miscible with poly(methyl methacrylate) but neither polystyrene nor polyacrylonitrile is miscible with poly(methyl methacrylate). Similarly, over a composition range, butadiene/acrylonitrile copolymers are miscible with poly(vinyl chloride) while none of the binary combinations of the homopolymers [polybutadiene, polyacrylonitrile, and poly(vinyl chloride)] are miscible. This behavior has been attributed to ``intramolecular repulsion`` between unlike copolymer segments. We have observed similar behavior in vapor-liquid equilibria (VLE) of copolymer+solvent systems. We find that acrylonitrile/butadiene copolymers have higher affinity for acetonitrile solvent than do polyacrylonitrile or polybutadiene. We attribute this non-intuitive behavior to ``intramolecular repulsion`` between unlike segments of the copolymer. This repulsive interaction is weakened when acetonitrile molecules are in the vicinity of unlike copolymer segments, favoring copolymer+solvent miscibility. We find similar behavior when acetonitrile is replaced by methyl ethyl ketone. To best knowledge, this effect has not been reported previously for VLE. We have obtained VLE data for mixtures containing a solvent and a copolymer as a function of copolymer composition. It appears that, at a given solvent partial pressure, there may be copolymer composition that yields maximum absorption of the solvent. This highly non-ideal VLE phase behavior may be useful for optimum design of a membrane for a separation process.

Gupta, R.B.; Prausnitz, J.M.

1995-03-01T23:59:59.000Z

400

Occupational health and safety regulation in the coal mining industry: public health at the workplace  

SciTech Connect (OSTI)

The strategy for preventing occupational disease and injury in the coal mining industry employs several elements. Standards are set and enforced; technical assistance, research, and development are provided; and surveillance is conducted. Compensation for black lung is a vivid reminder of the consequences of failure to prevent disease. And, workers are represented by a union that encourages active participation in all aspects of this strategy. There are significant problems in each of these elements. Regulatory reform threatens to weaken many standards, there is a decline in government research budgets, surveillance is not well monitored, and compensation for black lung is significantly more difficult to obtain now than in the past. Moreover, the conservative governments of the past decade are not friendly towards unions. Nevertheless, the fundamental structure of disease and injury prevention remains intact and, more importantly, it has a historical record of success. The Mine Safety and Health Act provided for a wide array of basic public health measures to prevent occupational disease and injury in the mining industry. These measures have been effective in reducing both risk of fatal injury and exposure to respirable coal mine dust. They are also associated with temporary declines in productivity. In recent years, however, productivity has increased, while risk of fatal injury and exposure to respirable dust have declined. At individual mines, productivity with longwall mining methods appear to be associated with increases in exposure to respirable dust. These trends are not inconsistent with similar trends following implementation of regulations by OSHA. When OSHA promulgated regulations to control exposure to vinyl chloride monomer, enforcement of the standard promoted significant efficiencies in vinyl chloride production (5).21 references.

Weeks, J.L. (Department of Occupational Health and Safety, United Mine Workers of America, Washington, DC (USA))

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Mechamisms of gas permeation through polymer membranes. Progress report, July 1, 1982-May 31, 1983  

SciTech Connect (OSTI)

The main objective of this study is to assess the validity of a free-volume model of gas permeation through rubbery polymer membranes. Such information is of importance for the development of new membrane processes for the separation of gas mixtures. Steady-state permeability coefficients for N/sub 2/O in polyethylene between 20 and 50/sup 0/C and at pressures up to 15 atm were found to be 45% higher (on the average) than values predicted by the free-volume model. The difference between the experimental and theoretical permeability coefficients for N/sub 2/O is about twice as large as observed with many other gases in polyethylene. Permeability, diffusion time-lags, and absorption measurements were made with n-C/sub 4/H/sub 10/ in poly(eta-butyl methacrylate) at 30/sup 0/C and subatmospheric pressures. The experimental time-lags agreed satisfactorily with values predicted by the free-volume model, using model parameters obtained from gas absorption measurements. However, the experimental permeability coefficients were substantially higher than the theoretical values. This may be due to a non-Fickian transport component because the measurements were made at only 3/sup 0/C above the glass transition temperature of the polymer. This study was recently extended to the solution and transport of gases and vapors in glassy polymers. Satisfactory agreement between experiment and theory was found for the solution, permeation, and diffusion of acetone, benzene, and methanol in ethyl cellulose and water vapor in poly(acrylonitrile) and for the solution of vinyl chloride monomer in poly(vinyl chloride). A generalized model of transport of small molecules in polymers has been developed. The model incorporates free-volume and dual-mode sorption concepts, and should be applicable both to rubbery and glassy polymers.

Stern, S.A.; Mauze, G.R.; Sampat, S.R.

1983-05-01T23:59:59.000Z

402

Cometabolic bioremediation  

E-Print Network [OSTI]

contaminants, e.g. PCE, TCE, MTBE, TNT, dioxane, atrazine,Geobacter, Clavibacter) BTEX, PCE, PAHs, Pyrene, Atrazine,VC, 1,1-DCE, 1,1,1- TCA, MTBE PCE, TCE, DCE, VC, Hexachloro-

Hazen, Terry C.

2010-01-01T23:59:59.000Z

403

Intro to Differential Equations MATH 2070 (Winter 2012)  

E-Print Network [OSTI]

Intro to Differential Equations MATH 2070 (Winter 2012) Solving Linear Systems -- Complex to . 3. Write Yc (t) = et Vc = e(+i)t Vc = et (cos (t) + i sin (t)) (Vre + iVim) where both Vre and Vim

Hagler, Jim

404

Scientific Drilling at Sulphur Springs, Valles Caldera, New Mexico...  

Open Energy Info (EERE)

Hole VC-2A Abstract A scientific core hole has been drilled into the western ring fracture zone of the Valles Caldera, N.Mex. Hole VC-2A, the second scientific core hole in the...

405

Core Log Valles Caldera No. 2A, New Mexico | Open Energy Information  

Open Energy Info (EERE)

2A, New Mexico Abstract Scientific core hole VC-2A was drilled into the western ring-fracture zone at Sulphur Springs in the Valles caldera, New Mexico. VC-2A, the second...

406

Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-  

E-Print Network [OSTI]

, iodoethane, acrylonitrile, methyl vinyl ketone, and acrolein were distilled prior to use. Purified water

Stoltz, Brian M.

407

Tetrahydrofuran Hydrate Crystal Growth Inhibition by Trialkylamine Oxides and Synergism with the Gas Kinetic Hydrate Inhibitor Poly(N-vinyl caprolactam)  

Science Journals Connector (OSTI)

High Pressure Gas Hydrate Rocker Rig Equipment Test Methods ... Solid plugs caused by gas hydrate formation are a menace in various stages of the upstream oil and gas industry such as in production lines, during drilling (especially in deep water), and in work-over operations. ... (1, 4-7) In particular, the design of a new field development with LDHI technology can give large CAPEX savings. ...

Malcolm A. Kelland; Ann Helen Kvæstad; Erik Langeland Astad

2012-06-26T23:59:59.000Z

408

Mechanistic investigation of vinylic carbonfluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF  

E-Print Network [OSTI]

using Cp*2ZrH2 and Cp*2ZrHF Bradley M. Kraft a , Eric Clot b , Odile Eisenstein b , William W behaves similarly [4]. In contrast, Cp*Rh(PMe3)H2 reacts with C6F6 by way of an SNAr2 attack by its conjugate base to give Cp*Rh(PMe3)(C6F5)H and fluoride ion, resulting in an autocatalytic reaction [5]. Cp

Jones, William D.

409

Poly(vinyl alcohol) based hydrogen-bonded multilayers : from pH-controlled multi-stage dissolution to zwitter-wettable surfaces  

E-Print Network [OSTI]

Understanding the mechanisms that govern the structure and function of synthetic polymer thin films is of fundamental and practical significance for developing a diverse range of functional surfaces including antifogging ...

Lee, Hyomin, Ph. D. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

410

A Distributed Evolutionary Method to Design Scheduling Policies for Volunteer Computing  

E-Print Network [OSTI]

of VC projects are: Predictor@Home [21], which predicts protein structures; Folding@Home [16], which

Fuentes, Olac

411

A circuit model of the temporal pattern generator of Caenorhabditis egg-laying behavior  

E-Print Network [OSTI]

establish a negative feedback loop, where depolarization of VC causes egg-laying, which in turn causes termination of the calcium transient and repolarization of the VC neu- ron. VC inhibits HSN in the short term Previous work indicated that the VC... calcium-sensitive fluorescent dyes, giving us an opportunity to directly monitor the transmission and integration of signals in the circuit. Furthermore, mutants with defects in individual cells make it possible to dis- criminate correlated excitation from...

Zhang, Mi; Schafer, William R; Breitling, Rainer

2010-06-07T23:59:59.000Z

412

An in vivo expression technology screen for Vibrio cholerae genes expressed in human volunteers  

Science Journals Connector (OSTI)

...VC2417-19 VC2419 1 integrase/recombinase XerD ( xerD ) 5 † 34 † 6.8 † type IV pilin biogenesis protein PilC (pilC) {Vibrio vulnificus} glutamate-ammonia-ligase adenylyltransferase (glnE) {Escherichia coli} VC2444-5 general...

Mary-Jane Lombardo; Jane Michalski; Hector Martinez-Wilson; Cara Morin; Tamara Hilton; Carlos G. Osorio; James P. Nataro; Carol O. Tacket; Andrew Camilli; James B. Kaper

2007-01-01T23:59:59.000Z

413

Chloride Analysis of the Soils Overlaying the Carrizo-Wilcox Aquifer  

E-Print Network [OSTI]

to thank Dr. West for his time in making this research project possible, and nudging me in the right direction. I would also like to thank Ryan Mushinski and Brandon Cawthon for their help in the field, as well as in the lab. 3 CHAPTER...

Wolf, Emery

2013-09-28T23:59:59.000Z

414

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network [OSTI]

to produce hydrogen for hydrotreating the liquid products orbed hydrocracking, hydrotreating, and reforming as conducted

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

415

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

Holten, R.R.

2010-01-01T23:59:59.000Z

416

Flow Cytometric Analysis of the Effect of Sodium Chloride on Gastric Cancer Risk in the Rat  

Science Journals Connector (OSTI)

...rats by gavage. Twenty-four h later, animals were...The mucosa appears to lift away from the underlying...weight at various time points after treatment with a...treatment at the earlier time points. Analysis of variance...cycle, at various time points after treat ment. Chart...

Gail Charnley and Steven R. Tannenbaum

1985-11-01T23:59:59.000Z

417

Using Caenorhabditis elegans to probe toxicity of 1-alkyl-3-methylimidazolium chloride based ionic liquids  

E-Print Network [OSTI]

are gaining attention as new solvents within the green chemistry community; however this attention has quickly attention as new solvents within the green chemistry community.1 This attention is due in part 35487, USA. E-mail: RDRogers@bama.ua.edu; Fax: 205-348-0823; Tel: 205-348-4323 b Center for Green

Caldwell, Guy

418

Relationships between potassium, chloride, and disease incidence in St. Augustinegrass and bermudagrass  

E-Print Network [OSTI]

on a Tifgreen bermudagrass green showed a strong correlation (r² = 0.9700) of reduction of dollar spot. K applied as K?SO? and Cl applied as CaCl? had little effect. Glasshouse results showed increasing K applied as K?SO? from 0 to 97.6 kg ha?¹ and Cl...

Rider, Larry Ray

2012-06-07T23:59:59.000Z

419

Choline Chloride-Derived ILs for Activation and Conversion of Biomass  

Science Journals Connector (OSTI)

The synthesis of HMF is nowadays one of the most investigated reactions from biomass. HMF is indeed considered as a chemical platforms from which new generations of biofuels (ex ... of intermediates, monomers and...

Karine De Oliveira Vigier; François Jérôme

2014-01-01T23:59:59.000Z

420

VISCOSITY OF AQUEOUS SODIUM CHLORIDE SOLUTIONS FROM 0 - 150oC  

E-Print Network [OSTI]

A. , Fabuss, B.M. , "Viscosities of Binary Aqueous Solutionsof Pressure on the Viscosity of Aqueous NaCl Solutions inF.A. , Kestin, J. , "The Viscosity of NaCl and KCl Solutions

Ozbek, H.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Corrosion initiation and propagation on corrosion resistant alloys embedded in concrete by accelerated chloride transport.  

E-Print Network [OSTI]

??Two duplex stainless steels rebars: UNS32304SS and UNS32101SS, were selected to investigate the corrosion initiation and propagation in reinforced concrete specimens. The investigation is divided… (more)

Gutierrez Tellez, Francisco.

2013-01-01T23:59:59.000Z

422

Development of Mercury and Hydrogen Chloride Emission Monitors for Coal Gasifiers  

SciTech Connect (OSTI)

The gas conditioning issues involved with coal gasification streams are very complex and do not have simple solutions. This is particularly true in view of the fact that the gas conditioning system must deal with tars, high moisture contents, and problems with NH{sub 3} without affecting low ppb levels of Hg, low levels (low ppm or less) of HCl, or the successful operation of conditioner components and analytical systems. Those issues are far from trivial. Trying to develop a non-chemical system for gas conditioning was very ambitious in view of the difficult sampling environment and unique problems associated with coal gasification streams. Although a great deal was learned regarding calibration, sample transport, instrumentation options, gas stream conditioning, and CEM design options, some challenging issues still remain. Sample transport is one area that is often not adequately considered. Because of the gas stream composition and elevated temperatures involved, special attention will need to be given to the choice of materials for the sample line and other plumbing components. When using gas stream oxidation, there will be sample transport regions under oxidizing as well as reducing conditions, and each of those regions will require different materials of construction for sample transport. The catalytic oxidation approach worked well for removal of tars and NH{sub 3} on a short term basis, but durability issues related to using the catalyst tube during extended testing periods still require study.

G. Norton; D. Eckels; C. Chriswell

2001-02-26T23:59:59.000Z

423

Late Pleistocene and Holocene groundwater recharge from the chloride mass balance method and chlorine-36 data  

E-Print Network [OSTI]

rates, estimated from 36 Cl data, were lower in late Pleistocene than Holocene at Yucca Mountain, Nevada Pleistocene. Local recharge rates at Yucca Mountain were estimated from the 36 Cl/Cl ratios and Cl� concentrations in perched waters. The estimated recharge for Yucca Mountain is 5 ± 1 mm/yr for Holocene and 15

Polly, David

424

An In-depth Investigation of an Aluminum Chloride Retarded Mud Acid System on Sandstone Reservoirs  

E-Print Network [OSTI]

Sandstone acidizing using mud acid is a quick and complex process where dissolution and precipitation occur simultaneously. Retarded mud acids are less reactive with the rock reducing the reaction rate hence increased penetration into the formation...

Aneto, Nnenna

2012-07-16T23:59:59.000Z

425

E-Print Network 3.0 - aqueous metal chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Economics Collection: Materials Science ; Chemistry 2 Changes in Solvation of Metal Ions with Temperature: Atomic-level Interactions between Solvent and Solute Summary:...

426

Dietary ammonium chloride and the urinary excretion of chlortetracycline and oxytetracycline  

E-Print Network [OSTI]

concentrated upon the potentiation oi the antibiotics. An antib1ot1c potentiator is any agent or substance which will 1ncrease or enhance ant1b1otic absorp- tion or decrease excret1on, thus maintaining a high blood level of the drug. Finland (1958) states.... Dissertation, Texas AhN University. Finland, N. (1958). Antibiotic blood level enhance- ment. Anti. Ned. and There . 5, 359. Hayes, J. E. , Jr. , and H. G. DuBuy. (1961). A simple method for quantitative estimation of tetracycline antibiotics. Anal. Biochem...

Roberts, Ronald Curtis

1967-01-01T23:59:59.000Z

427

Chloride improves fruit yield and quality of strawberry (Fragaria × ananassa Duch.)  

E-Print Network [OSTI]

concentration in strawberry fruits. Materials and Methods Inwas carried out with ten replicates. After fruit harvest,number of fruits per plant, single fruit weight, fruit

Bellof, Svenja; Schubert, Sven

2009-01-01T23:59:59.000Z

428

A Novel, Green Technology for the Production of Aromatic Thiol from Aromatic Sulfonyl Chloride  

E-Print Network [OSTI]

Functional Theory (DFT), a quantum mechanical method, was used to investigate the new aromatic thiol production technology at the molecular level in aspects including reaction species adsorption and transition state determination. Plant design methods...

Atkinson, Bradley R.

2010-01-16T23:59:59.000Z

429

E-Print Network 3.0 - analyzing polyvinyl chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Incineration of Refuse with 2 Percent and 4 Percent Additions of Four Plastics: Polyethylene, Polyurethane, Summary: : Polyethylene, Polyurethane, Polystyrene and Polyvinyl...

430

Analysis of chlorinated polyvinyl chloride pipe burst problems :Vasquez residence system inspection.  

SciTech Connect (OSTI)

This report documents the investigation regarding the failure of CPVC piping that was used to connect a solar hot water system to standard plumbing in a home. Details of the failure are described along with numerous pictures and diagrams. A potential failure mechanism is described and recommendations are outlined to prevent such a failure.

Black, Billy D.; Menicucci, David F.; Harrison, John (Florida Solar Energy Center)

2005-10-01T23:59:59.000Z

431

Effect of Brush Vegetation on Deep Drainage Using Chloride Mass Balance  

E-Print Network [OSTI]

is comparable to that by herbaceous vegetation (Wilcox, 2005). The canopy of an average-size, mature redberry and ashe juniper can intercept 26% and 37% of the annual precipitation, respectively. Redberry and ashe juniper litter can intercept 40% and 43..., superactive, thermic Pachic Paleustolls. Dominant woody-shrub vegetation cover includes juniper (Juniperus ashei) with other existing vegetation such as little bluestem (Schizachyrium scoparium) and threeawn (Aristida). Site G4 The soil at site G4...

Navarrete Ganchozo, Ronald J.

2011-02-22T23:59:59.000Z

432

Calibration of Yucca Mountain unsaturated zone flow and transport model using porewater chloride data  

E-Print Network [OSTI]

of hydrogeologic units at Yucca Mountain, Nevada. U.S.infiltration for the Yucca Mountain Area, Nevada. Milestonethe unsaturated zone at Yucca Mountain, Nevada. J. Contam.

Liu, Jianchun; Sonnenthal, Eric L.; Bodvarsson, Gudmundur S.

2002-01-01T23:59:59.000Z

433

Studies on expression and function of the TMEM16A calcium-activated chloride channel  

Science Journals Connector (OSTI)

...circular muscle facing down, were captured in time-lapse...saliva and secrete amylase, an enzyme that breaks down starch for glucose production. The...prostaglandin F2 alpha (PGF2{alpha...circular muscle facing down. Muscles were maintained...

Fen Huang; Jason R. Rock; Brian D. Harfe; Tong Cheng; Xiaozhu Huang; Yuh Nung Jan; Lily Yeh Jan

2009-01-01T23:59:59.000Z

434

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network [OSTI]

complexes between nitrogen dioxide, nitric acid, nitrous1992) Indoor ozone and nitrogen dioxide: A potential pathwaybed of SiO 2 pellets. Nitrogen dioxide is introduced from a

2009-01-01T23:59:59.000Z

435

Fisetin Enhances Behavioral Performances and Attenuates Reactive Gliosis and Inflammation During Aluminum Chloride-Induced Neurotoxicity  

Science Journals Connector (OSTI)

Aluminum (Al) is an environmental neurotoxin that affects cerebral functions and causes health complications. However, the role of Al in arbitrating glia homeostasis and pathophysiology remains obscure. Astroc...

Dharmalingam Prakash; Kulasekaran Gopinath…

2013-03-01T23:59:59.000Z

436

E-Print Network 3.0 - alkaline earth chlorides Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of the alkaline earth cations, magnesium, calcium, and barium on the dissolution kinetics of quartz PATRICIAM... and alkaline earth cations in near-neutralpH solutions. We...

437

Insertion of a Two-Dimensional Iron-Chloride Network between Perovskite Blocks. Synthesis and  

E-Print Network [OSTI]

.9985%) with a 25% molar excess of Rb2CO3 (Alfa, 99%) were ground together, annealed in an alumina crucible for 12 h at 850 °C and 24 h at 1050 °C. The excess of Rb2CO3 was added to balance that lost due to volatilization cycles with molten salt; the lithium compound was obtained in a single cycle. Although single-phase

Spinu, Leonard

438

The rate of hydrolysis of benzoyl chloride as a function of water concentration in acetone  

E-Print Network [OSTI]

?XEu K?B ?XWH? gIHXBTHB WHWBWTL gIHgEHBRTBWIH Ij XIuW?Y T?WuE ?TGE gIH? XBTHB hWELuX Ij TL?hL T?WuEV iPWX KEPTGWIR 0TX WHBERmRE? BEu TX mRIIj Ij TH d:L YEgPTHWXY 0WBP TH WIHW?TBWIH XBEm RTBE gIHBRILLWH?? TX jILLI0Xn b CL XLI0 ? Aj BPE XILE m...?RmIXE Ij BPWX WHGEXBW?TBWIH PTu KEEH BPE uEBERYWHTBWIH Ij RETgBWIH YEgPTHWXY? T XWYWLTR BEgP? HW??E gI?Lu PTGE KEEH ?XEu TX XPI0H ELXE0PERE ?et?V oI0? EGER? BPE gPTLLEH?E Ij BPE WHXBR?YEHBTBWIH HEgEXXTRh jIR BPE YETX?REYEHB Ij E?BREYELh RTmWu RTBEX 0WBP...

Kelly, Minton Jones

2013-10-04T23:59:59.000Z

439

The ultra-high lime with aluminum process for removing chloride from recirculating cooling water  

E-Print Network [OSTI]

, reverse osmosis, ion exchange, and electrodialysis (Matson and Harris 1979). With the exception of the high lime softening process, these technologies 3 are very expensive and have many operating problems. The unit price of water treatment... with reverse osmosis is about three times the price of lime softening (You et al. 1999). The conventional lime soda process is used in cooling water systems to minimize or eliminate scale formation by removing calcium and magnesium hardness...

Abdel-wahab, Ahmed Ibraheem Ali

2004-09-30T23:59:59.000Z

440

Evaluation of calcium chloride and ammonium thiosulfate as ammonia volatilization inhibitors for surface-applied urea  

E-Print Network [OSTI]

million tons Total fertilizer Total N NH4NOs Anhydrous NHs N solutions Urea 22. 7 24. 9 42. 5 52. 8 41. 8 50. 1 1. 6 2. 74 8. 60 11. 4 9. 13 11. 1 1. 12 1. 23 2. 80 2. 63 2. 15 2. 19 0. 35 0. 71 4. 02 5. 48 3. 84 4. 71 0. 21 0. 65 4. 11 6. 67 6...-12 10-12 10-12 0-2 12-14 0-2 120 144 96 24 36 24 261 3128 218 1878 225 3104 In general, three major effects were observed: 1) The lag phase of NHs volatilization was delayed or lengthened. 2) The maximum N loss rate occurred later...

Sloan, John J.

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

A comparison of the urea and guanidinium chloride denaturation of four proteins  

E-Print Network [OSTI]

-lactoglobulin was lyophilized and stored below 0 C. until used' 0 2. Ribonuclease. Ribonuclease (Lot No. 99B-8020) lghs obtained in the form of a lyophilized powder (Type III A) from Sigma Chemical Company. Bradbury and King (19) found that sulfate ions are bound to Sigma... significant error. Bradbury and King ( 39, 40) have studied the urea denaturation of lysozyme using NMR and found evidence for the presence of an intermediate state. They pro- posed that a hydrophobic core unfolds only after a more hydrophilic exterior...

Greene, Raymond Franklin

2012-06-07T23:59:59.000Z

442

Effects of Calcium and Magnesium Acetates on the Carcinogenicity of Cadmium Chloride in Wistar Rats  

Science Journals Connector (OSTI)

...cadmium-induced testicular carcinogenesis, it does not appear to be significantly altered...and Asile. M. J. (eds.). CRC Handbook of Chemistry and calcium and zinc in vitro. Fed. Proc., 41:924,1982. Physics, Ed. 60, pp. F-214. Boca Raton...

Lionel A. Poirier; Kazimierz S. Kasprzak; Karen L. Hoover; and Martin L. Wenk

1983-10-01T23:59:59.000Z

443

Ligand-Gated Chloride Channels Are Receptors for Biogenic Amines in C. elegans  

E-Print Network [OSTI]

Biogenic amines such as serotonin and dopamine are intercellular signaling molecules that function widely as neurotransmitters and neuromodulators. We have identified in the nematode Caenorhabditis elegans three ligand-gated ...

Ringstad, Niels

444

An effect of chloride on (Na + K) co-transport in human red blood cells  

Science Journals Connector (OSTI)

... the phloretin- and furosemide-sensitive (Na-Li) counter-transport system identified in RBC by Tosteson and co-workers9. Third, there is the extensive work by Wieth on anion and ...

A. R. Chipperfield

1980-07-17T23:59:59.000Z

445

An electron spin resonance investigation of irradiated potassium chloride crystals doped with sodium nitroprusside  

E-Print Network [OSTI]

's, attention was turned. to a large extent to the topic of organic n-radicals. Electron spin resonance was first observed in free rad1cals in 1907 by Kozyrev and. Salikhov ) in the case of pentaphenyclopentadienyl. In solid penta... radical possesses mainly spin magnetism in accordance with measurements of its static magnetic susceptibility. In l949 a systematic study of electron spin resonance spectra in free radicals was initiated, i. e. molecules in which at least one electron...

Mayers, Richard Ralph

2012-06-07T23:59:59.000Z

446

Antioxidant effects of reduced water produced by electrolysis of sodium chloride solutions  

Science Journals Connector (OSTI)

Antioxidant vitamins and enzymes such as superoxide dismutase, catalase and glutathione peroxidase are considered to function as scavengers against reactive oxygen species and to provide protection against rea...

K. Hanaoka

2001-12-01T23:59:59.000Z

447

The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane  

E-Print Network [OSTI]

of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Chair of Committee, Shari A. Yvon-Lewis Committee Members, John D. Kessler Robert Rhew Gunnar W. Schade... to work with her. I would like to thank my committee members, Drs. John D. Kessler, Robert Rhew and Gunnar W. Schade. I went to two cruises with John and coauthored several papers with him. He gave me a lot of help and inspiration for methane study. He...

Hu, Lei

2012-10-19T23:59:59.000Z

448

Selected genomic and phenotypic responses of Salmonella serovars to chlorine, chlorine dioxide, and cetylpyridinium chloride  

E-Print Network [OSTI]

was significant, biocide concentration in the overall disinfection was insignificant. This was true especially for chlorine and CPC with subtle differences observed between the serovars. The inactivation efficacy was, however, dependent on both concentration...

Kakani, Grihalakshmi

2012-07-11T23:59:59.000Z

449

Phytotoxicity and Efficacy of Cycocel (Chlormequat Chloride) for Growth Control of  

E-Print Network [OSTI]

Program to Address California Needs UC Davis Environmental Horticulture IR4 Center Department of Environmental Horticulture University of California One Shields Ave. Davis, CA 95616 http FORM 1. INVESTIGATOR (Name, Address, Phone#): Dr. Heiner Lieth Department of Environmental Horticulture

Lieth, J. Heinrich

450

E-Print Network 3.0 - aerated sodium chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CONTROL SYSTEM FOR Summary: from this project: Aeration of large-scale municipal wastewater treatment plants: state of the art... , Diego Rosso, Lory E. Larson, Michael K....

451

VISCOSITY OF AQUEOUS SODIUM CHLORIDE SOLUTIONS FROM 0 - 150oC  

E-Print Network [OSTI]

and evaluate data on geothermal energy for electrical andeconomic aspects of geothermal energy. While the larger workDivision of Geothermal Energy; Office of Environmental

Ozbek, H.

2010-01-01T23:59:59.000Z

452

E-Print Network 3.0 - astatine chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine ; Environmental Sciences and Ecology 27 Zevenhoven & Kilpinen Halogens, dioxinsfurans 17.6.2001 7-1 Chapter 7 Halogens, Summary: .1 Introduction The halogens are...

453

The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.  

SciTech Connect (OSTI)

Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

Peter Zalupski; Rocklan McDowell; Guy Dutech

2014-10-01T23:59:59.000Z

454

Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene  

E-Print Network [OSTI]

and Engineering, Solid-State Science and Engineering, Columbia University, New York, New York 10027, USA 2 Department of Mechanical Engineering, Columbia University, New York, New York 10027, USA 3 Department of Chemistry, Columbia University, New York, New York 10027, USA 4 Brookhaven National Laboratory, Upton, New

Hone, James

455

Chloride improves fruit yield and quality of strawberry (Fragaria × ananassa Duch.)  

E-Print Network [OSTI]

1988; 88: 194-199 Martínez Barroso MC, Alvarez CE, Toxicityof 2 dS m -1 (Martínez Barroso and Alvarez 1997). Hypotheses

Bellof, Svenja; Schubert, Sven

2009-01-01T23:59:59.000Z

456

Scalable Methodology for the Catalytic, Asymmetric r-Bromination of Acid Chlorides  

E-Print Network [OSTI]

cycle. The enhanced SN2 reactivity of these optically enriched products versus their chlorinated to good chemical yields with retention of both upon scale-up. The reactions herein are catalyzed reaction that proceeds first by the generation of reactive ketenes via a carbonate/amine shuttle

Lectka, Thomas

457

free energy of desolvation for the larger neo-pentyl system relative to the methyl chloride  

E-Print Network [OSTI]

and ex- plains the difference seen between gas-phase and solution-phase experimental results for the SN2 to the energy of the steric effect. Another choice for the measure of the steric effect ( E*), the SN2 barrier reaction. References and Notes 1. A. W. Hofmann, Ber. Dtsch. Chem. Ges. 5, 704 (1872). 2. , Ber. Dtsch

Saffman, Mark

458

Ultraviolet-B radiation enhancement in dielectric barrier discharge based xenon chloride exciplex source by air  

SciTech Connect (OSTI)

A single barrier dielectric barrier discharge tube of quartz with multi-strip Titanium-Gold (Ti-Au) coatings have been developed and utilized for ultraviolet-B (UV-B) radiation production peaking at wavelength 308?nm. The observed radiation at this wavelength has been examined for the mixtures of the Xenon together with chlorine and air admixtures. The gas mixture composition, chlorine gas content, total gas pressure, and air pressure dependency of the UV intensity, has been analyzed. It is found that the larger concentration of Cl{sub 2} deteriorates the performance of the developed source and around 2% Cl{sub 2} in this source produced optimum results. Furthermore, an addition of air in the xenon and chlorine working gas environment leads to achieve same intensity of UV-B light but at lower working gas pressure where significant amount of gas is air.

Gulati, P., E-mail: pgulati1512@gmail.com [CSIR-Central Electronics Engineering Research Institute (CSIR-CEERI), Pilani, Rajasthan-333031 (India); Department of Physics, Banasthali University, P.O. Banasthali Vidyapith, Rajasthan 304022 (India); Prakash, R.; Pal, U. N.; Kumar, M. [CSIR-Central Electronics Engineering Research Institute (CSIR-CEERI), Pilani, Rajasthan-333031 (India); Vyas, V. [Department of Physics, Banasthali University, P.O. Banasthali Vidyapith, Rajasthan 304022 (India)

2014-07-07T23:59:59.000Z

459

Effect of Mo on pitting corrosion of ferritic steels in bromide and chloride solutions  

SciTech Connect (OSTI)

A model for pitting corrosion of stainless steels, independent of changes of passive film properties, was tested using Fe-18%Cr-x%Mo alloys in bromide and chlorine solutions. In 1M LiCl the pitting potential improved from {minus}50 mV{sub sce} to about 1200 mV{sub sce} on increasing Mo from 2% to 10%. In 1M LiBr the pitting potential increased from 125 to only 560 mV{sub sce}. Active dissolution kinetics of these steels in saturated solutions in a simulated pit were measured. Tafel lines for dissolution moved to more noble potentials with increases in Mo, indicating Mo inhibited dissolution rates. The potential increases were found to be equal to the increases in pitting potential for both halides. Agreement was interpreted in terms maintaining high halide concentrations in the pit by high rates of active metal dissolution. Bromide was less effective suggesting it interacted with Mo adsorbed on the dissolving surface.

Kaneko, M. [Nippon Steel Corp., Futtsu Chiba (Japan). Steel Research Lab; Isaacs, H.S. [Brookhaven National Lab., Upton, NY (United States)

1997-12-01T23:59:59.000Z

460

Iron(III) extraction from chloride media by N,N?-tetrasubstituted malonamides: An interfacial study  

Science Journals Connector (OSTI)

Abstract The interfacial behaviour of two N,N?-tetrasubstituted malonamides, N,N?-dimethyl-N,N?-diphenyl malonamide (DMDPHMA) and N,N?-dimethyl-N,N?-dicyclohexylmalonamide (DMDCHMA), in the liquid–liquid (L/L) extraction of iron(III) from hydrochloric acid solutions, was studied. The experimental results obtained validate the absence of third phases for these systems. The equilibrium adsorption constants and surface excess concentrations, estimated by the Szyszkowski model, explain the experimental extraction efficiency patterns for both malonamides in the two diluents tested, 1,2-dichloroethane (1,2-DCE) and toluene. A solvation type mechanism is in accordance with all the results obtained, accounting for the structural and diluent effects observed.

M. Soledade C.S. Santos; Ana Paula Paiva

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The effect of sodium chloride in the irrigation water on the growth of selected ornamental plants  

E-Print Network [OSTI]

the influence of high salinity on the growth and water content of the plants. After a 4-week preconditioning period, the salts were applied in a complete nutrient solution via a trickle irrigation system. The saline treatments were continued for 6 weeks... ABSTRACT Page ACKNOWLEDGMENTS TABLE OF CONTENTS LIST OF TABLES vi V11 Chapter I. INTRODUCTION II. LITERATURE REVIEW III. MATERIALS AND METHODS 12 Plant Preparation Salt Treatments Harvesting the Plants Statistical Analysis IV. RESULTS...

Apps, Gary Edward

2012-06-07T23:59:59.000Z

462

Molecular Dynamics Simulation of the Transport Properties of Molten Transuranic Chloride Salts  

E-Print Network [OSTI]

The Accelerator Research Laboratory at Texas A&M is proposing a design for accelerator-driven subcritical fission in molten salt (ADSMS), a system that destroys the transuranic elements in used nuclear fuel. The transuranics (TRU) are the most...

Baty, Austin Alan

2013-02-06T23:59:59.000Z

463

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network [OSTI]

iv List of Tables . , I. INTRODUCTION e o Coal Chemistry B.Coal Liquefaction c.Coal Liquefaction a D. II. o Experiment Equipment Summary of

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

464

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network [OSTI]

Bodily, Stanford Res Inst. , Coal Chemistry Workshop, 1,News, (Aug. 27, 1979). C2 Coal Processing-Gasification,L.W. Vernon, and E.L. Wilson, Coal Liquefaction by the Exxon

Onu, Christopher O.

2013-01-01T23:59:59.000Z

465

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

July 22, 1974. Project Western Coal: Conversion of Coal Intoand Gasification of Western Coals", in proceedings of ERDA/Investigators' Conference - Coal Research, Colorado School

Holten, R.R.

2010-01-01T23:59:59.000Z

466

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride  

Science Journals Connector (OSTI)

...also globally distributed, because NO formed in combustion processes is oxidized to NO2, HNO3, N2O5 and a variety of...also globally distributed, because NO formed in combustion processes is oxidized to NO(2), HNO(3), N(2)O...

Jonathan D. Raff; Bosiljka Njegic; Wayne L. Chang; Mark S. Gordon; Donald Dabdub; R. Benny Gerber; Barbara J. Finlayson-Pitts

2009-01-01T23:59:59.000Z

467

E-Print Network 3.0 - acidic chloride media Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CI Acid gases and mists were trapped in 1.5 N aq. NaOH contained in a Greenburg-Smith impinger... following the probe, Fig. 2, was combined with the alkaline collection...

468

Optical spectra and luminescence of REE and TRU for analytical purposes in chloride melts  

SciTech Connect (OSTI)

This paper analyzes absorption spectra of molten salts containing some of the actinide and rare-earth elements (REE) and evaluated the prospects of using the individual transitions to control the composition of the spent molten salts using adsorption and luminescence spectroscopy from the standpoint of the theory of Judd-Ofelt. It is shown that the fluorescent method can be recommended only for the monitoring of the degree of purification of the molten salt from the REE in the final stage, when only trace amounts of fission products are in the molten salt. In this case, the content of REE in the molten process is much smaller than that of the used model samples and that eliminates the problem of a significant decrease in the population levels of fluorescent Eu{sup 3+} by quenching impurities. In addition, the presence of salt in the matrix of americium and curium can cause self-luminescence of Eu{sup 3+} due to alpha disintegration energy of transuranics, which also complicates the quantitative measurement of luminescence for the determination of REE.

Aloy, A.S.; Gorshkov, N.G.; Nekhoroshkov, S.N. [FSUE RPA - V.G. Khlopin Radium Institute - KRI, 2 Murinsky Ave., 28, St. Petersburg, 194021(Russian Federation); Osipenko, A.G.; Mayorshin, A.A. [Federal State Unitary Enterprise - State Scientific Center of RF Research Institute of Atomic Reactors, Dimitrovgrad-10, Ulyanovsk region 43351 (Russian Federation)

2013-07-01T23:59:59.000Z

469

Adaptive Resistance and Differential Protein Expression of Salmonella enterica Serovar Enteritidis Biofilms Exposed to Benzalkonium Chloride  

Science Journals Connector (OSTI)

...were those involved in energy metabolism (TpiA and...facilities and domestic households and as antimicrobial...Nikon Corp., Tokyo, Japan) (20). Fifteen random...PduJ and PduA), energy metabolism (TpiA and...degradation (GarR), energy metabolism (GpmA, FbaA...

Anil K. Mangalappalli-Illathu; Darren R. Korber

2006-08-28T23:59:59.000Z

470

Chloride and Lithium Transport in Large Arrays of Undisturbed Silt Loam and Sandy Loam Soil Columns  

Science Journals Connector (OSTI)

...concentrations of surface-applied agrochemicals in subsurface tile drainage lines or...columns. This means that the soil composition, together with the particular flow...Warington. 1882. On the amount and composition of the rain and drainage water collected...

M. Saleem Akhtar; Tammo S. Steenhuis; Brian K. Richards; Murray B. McBride

471

E-Print Network 3.0 - aqueous ammonium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids, chlorates, nitrites, sulfur, finely... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... Ammonium...

472

The Chemopreventive Agent Resveratrol Stimulates Cyclic AMP–Dependent Chloride Secretion In vitro  

Science Journals Connector (OSTI)

...diarrhea, likely due to an increase in intracellular cyclic...and time-dependent increase in deltaIsc in T84 cells...and dose-dependent increase in deltaIsc as well...effects of moderate red wine consumption on the development...chemicals were of the purest quality available. Cell culture...

Irina Blumenstein; Benjamin Keserü; Freya Wolter; and Jürgen Stein

2005-08-01T23:59:59.000Z

473

Hoechst and Wacker plan joint venture in PVC  

SciTech Connect (OSTI)

Restructuring of Europe's petrochemical industry has taken a further step with the announcement that Hoechst (Frankfurt) and Wacker Chemie (Munich) are planning a joint venture in polyvinyl chloride (PVC). The venture would include production, R D, sales and marketing, plus both companies' PVC recycling activities. However, their vinyl chloride monomer (VCM) plants, and Hoechst's Kalle PVC film business, have been left out. Erich Schnitzler, head of Hoechst's PVC business unit, does not anticipate problems with the European Community's competition directorate. We are both among the middle-sized European PVC producers, and together we would have a 9%-10% market share. Our joint venture would not limit competition. Both partners are hoping for approval from Brussels in first-quarter 1993. Hoechst has 255,000 m.t./year of PVC capacity at Gendorfand Knapsack, while Wacker has 365,000 m.t./year at Burghausen and Cologne. All the units, except Wacker's Cologne plant, are back integrated to VCM. The joint venture would buy VCM from the two parent companies and on the merchant market.

Young, I.

1992-12-02T23:59:59.000Z

474

Ceramic membrane treatment of petrochemical wastewater  

SciTech Connect (OSTI)

Ceramic alumina microfiltration membranes were evaluated for treatment of 3 aqueous streams containing heavy metals, oils, and solids at petrochemical manufacturing facilities. To the best of the author's knowledge, this is the first reported use of ceramic alumina membranes for process water and wastewater treatment in a US petrochemical plant. In a pilot test at a vinyl chloride monomer (VCM) plant, precipitated heavy metal solids were filtered with the membranes. On another stream at that site, the ceramic membrane pilot system successfully treated emulsions of 1,2-dichloroethane (EDC), water, and solids. Membrane filtration of a linear alkyl benzene (LAB) oily wastewater stream produced water with less than 5 ppmw oil and grease, after pretreatment with HCl and ferric chloride. A preliminary financial analysis shows that the installed system cost for a ceramic membrane unit is comparable to other membrane technologies, while operating costs are anticipated to be lower. Specific process conditions that are particularly amenable to treatment by ceramic membrane microfiltration are also given in the paper. 10 refs., 11 figs., 7 tabs.

Lahiere, R.J. (Vista Chemical Co., Houston, TX (United States)); Goodboy, K.P.

1993-05-01T23:59:59.000Z

475

Influence of relaxation transitions on radiation-initiated cationic graft polymerization. [Gamma radiation  

SciTech Connect (OSTI)

Radiation grafting of vinyl n-butyl ether (VBE) to polyvinyl chloride (PVC) over a broad temperature range was investigated. The relaxation transitions in the PVC/VBE system were also determined. Grafting of vinyl alkyl ethers proceeds entirely by a cationic mechanism in a reaction medium that has been dried to a water concentration no greater than 0.1-1.0 ppm. In this connection, the diffusion properties of water in the temperature region were studied. Commercial films of unplasticized PVC (thickness 200 M); were subjected to swelling in two systems: in a 50% solution of VBE in benzene at 25/sup 0/C, and in the pure monomer at 40/sup 0/C. The reaction mixtures were first dried over metallic sodium in a deaerated atmosphere. The specimens were irradiated in a Co gamma-radiation unit to a dose of 10 kGy at a dose rate of 3 Gy/sec. The first reaction mixture was investigated over a range of temperatures from -60/sup 0/ to +70/sup 0/C, and the second from -15/sup 0/ to +50/sup 0/C. The degree of grafting was determined from the increase in weight of the original ungrafted film. The temperature was held to within +/-1/sup 0/C. The relaxation transitions in the swollen polymer systems were determined by two methods, thermostimulated current (TSC) and thermomechanics (TM). It was found that in the region of the glass transition of a swollen PVC-VBE system, radiation-initiated cationic graft polymerization proceeds at a maximal rate, and there are changes in state of the water molecules (the agents of breaking the ion reaction chain) and in their diffusion properties within the matrix.

Kudryavtsev, V.N.; Kabanov, V.Ya.; Chalykh, A.E.; Spitsyn, V.I.

1982-05-01T23:59:59.000Z

476

E-Print Network 3.0 - acid mono-2-ethylhexyl ester Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

B. Magnetic properties a b s t r a c t FeVinyl ester... surfactant or coupling agent. Vinyl ester monomer serves as a coupling agent with one side covalently bound Source: Guo,...

477

Accelerated Wear Tests on Common Floor-covering Materials.  

E-Print Network [OSTI]

materials indicated there are variations in the changes of appearance and wear in these materials. Solid sheet vinyls and rubber tiles showed significantly less wear than asphalt tiles, vinyl- asbestos tiles, linoleums and cork. Asphalt tiles showed... in home installations. Six common floor covering materials-solid .sheet vinyls, rubber tiles, vinyl-asbestos tiles, J linoleums, corks and asphalt tiles-were used to construct 63 test specimens 2 x 2 feet in size. 1 T'ariations in specimens were...

Stewart, B. R.; Kunze, O. R.; Hobgood, Price.

1958-01-01T23:59:59.000Z

478

Prototyping Process and Tools An abbreviated overview of lifecycle  

E-Print Network [OSTI]

Woomoo) · Physical objects ­ cardboard, clay, vinyl, etc. ­ 3D-printed Realistic Interaction · More

Golub, Evan

479

Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins  

SciTech Connect (OSTI)

Electrooxidation in organic solvents of the dimethyl esters of several metalloprotoporphyrins (PP) (Ni/sup II/PP, Zn/sup II/PP, Co/sup II/PP, (Fe/sup III/PP)Cl, (Fe/sup III/PP)/sub 2/O, and (Cr/sup III/PP)/sub 2/O) leads to the deposition of thick (approx. 1000 monolayer equivalents), electroactive porphyrin films, which have been characterized by cyclic voltammetry and absorption spectroscopy on transparent SnO/sub 2/ electrodes. The films are stable toward organic solvents and aqueous acids and bases, but are removed by treatment with hot concentrated acids. The resonance Raman spectrum of the NiPP film indicates that one of the two vinyl groups is saturated on most of the porphyrin units. Deposition continues for some minutes after the current is interrupted. This evidence is consistent with a mechanism involving electroinitiated cationic vinyl polymerization. No film is formed if the metal, rather than the ring, is oxidized. Thus the first oxidation step of Co/sup II/PP, to (Co/sup III/PP)/sup +/, does not support film formation (although the potential is as high as for ring oxidation in ZnPP), but the second step, to (Co/sup III/PP)/sup 2 +/, does. Lack of film formation for (Mn/sup III/PP)Cl and (Cr/sup IV/PP)O suggests metal, rather than ring oxidation, to Mn/sup IV/ and Cr/sup V/. However, (CrPP)/sub 2/O oxidation does produce a film, suggesting ring oxidation, analogous to (FePP)/sub 2/O, which also produces a film. However, while (CrPP)/sub 2/O is incorporated intact into the film, the (FePP)/sub 2/O film contains monomer units. Incorporation of other metal ions can be accomplished by soaking a ZnPP-coated electrode in H/sub 2/SO/sub 4/ followed by contact wtih a solution of the metal dihalide in refluxing DMF. The porphyrin sites are accessible to small ions, as shown by chloride coordination of ZnPP film upon soaking in chloride solution. 49 references, 13 figures, 1 table.

Macor, K.A.; Spiro, T.G.

1983-08-24T23:59:59.000Z

480

Antithrombogenic and antibiotic compositions and methods of preparation thereof  

DOE Patents [OSTI]

Antithrombogenic and antibiotic composition of matter and method of preparation thereof. A random copolymer of a component of garlic and a biocompatible polymer has been prepared and found to exhibit antithrombogenic and antibiotic properties. Polymerization occurs selectively at the vinyl moiety in 2-vinyl-4H-1,3-dithiin when copolymerized with N-vinyl pyrrolidone. 4 figs., 2 tabs.

Hermes, R.E.

1988-04-19T23:59:59.000Z

Note: This page contains sample records for the topic "vc vinyl chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network [OSTI]

by: thiophene (Aldrich), tetrahydrothiophene (MCB) , andresult in observable reaction products. TetrahydrothiopheneTetrahydrothiophene was found to be thermally stable at 325°

Mobley, David Paul

2013-01-01T23:59:59.000Z

482

Derivatization of Alkyl Halides, Acid Chlorides, and Other Electrophiles with Polymer-Immobilized 8-Amino-2-naphthoxide  

Science Journals Connector (OSTI)

......ISKANDARANI A N D T . E . MILLER, JR. S I M U L T A N E O U S...N D E K , U . A . T H . B R I N K M A N , A N D R . W...ORGANICS I N THE E N V I R O N M E N T B Y T A N D E...1 9 8 5 ) . 2 4 . M . E . MCNALLY A N D R . L . GROB. H E A D S P......

Stephen T. Colgan; Ira S. Krull; Craig Dorschel; Brian A. Bidlingmeyer

483

The interrelations of mineral colloids and sodium chloride as measured by pH, conductivity, and water-soluble cations  

E-Print Network [OSTI]

?nos material, then any endothermic or exothermic re- action vill appear on the dehydratfon curve shoving the temperature differences as a function of the tenperature of the reference notarial. Page (43)x and Eendricks and Alexander {19) described equipnent... (exothermic) and a deflection in the opposite direction is noted on the gslvancmeter. Ths deflection on the galvancseter is proportional to e. m. f. created which is dependent upce the amount of heat abaca'bed or liberated in the sample being idcntif ied...

Crozier, Baalis B

1952-01-01T23:59:59.000Z

484

Study of the Cooperative Jahn — Teller Phase Transition in Cesium Copper Chloride by Channeling of He — Ions  

Science Journals Connector (OSTI)

Development of channeling technique has led to a number of important applications in studies of single crystals. We have investigated crystals of CsCuCl3. This compound has a hexagonal perovskite structure and un...

B. John; U. Backes; A. Timm; W. Zimmermann…

1980-01-01T23:59:59.000Z

485

A comparative study of extraction methods for analysis of chloride in plant tissue by means of the Cotlove chloridometer  

E-Print Network [OSTI]

of dried, pulverized mesh tissue. The sample is then stirr ed intermittently for at least five minutes at room temperature (37). It is recommended that the extract be analyzed by potentiometric titration using a silver billet electrode. Hanna (26... analysis indicates four methods which are most commonly used. These include Mohr and Volhard's methods of volumetric analysis (1, 8, 32), potentiometric titration using a silver or platinum electrode (6, 37), potentiometric titration using an ion...

Norris, Richard Eugene

1976-01-01T23:59:59.000Z

486

Gas Chromatographic Determination of Carboxylic Acid Chlorides and Residual Carboxylic Acid Precursors Used in the Production of Some Penicillins  

Science Journals Connector (OSTI)

......than the usual titration methods, which do not differentiate...analysis Chromatography, Gas methods Drug Industry Hydrogen-Ion Concentration Methods Microchemistry Penicillins...Precursors Used in the Production of Some Penicillins R......

R.G. Lauback; D.F. Balitz; D.L. Mays

1976-05-01T23:59:59.000Z

487

Iron Chloride Precipitation of Viruses from Seawater Revision: 25 Mar 2014 Tucson Marine Phage Lab Page 1 of 5  

E-Print Network [OSTI]

waters using iron- based flocculation and large-pore-size filtration, followed by resuspension of virus- containing precipitates in a pH 6 buffer. This Fe-based virus flocculation, filtration and resuspension in the resuspension buffer. Particles lose infectivity if resuspended with ascorbic acid in the buffer. PCR inhibition

Sullivan, Matthew B.

488

Fate of Magnesium Chloride Brine Applied to Suppress Dust from Unpaved Roads at the INEEL Subsurface Disposal Area  

SciTech Connect (OSTI)

Between 1984 and 1993, MgCl2 brine was used to suppress dust on unpaved roads at a radioactive waste subsurface disposal area. Because Cl– might enhance corrosion of buried metals in the waste, we investigated the distribution and fate of Cl– in the vadose zone using pore water samples collected from suction lysimeters and soluble salt concentrations extracted from sediment samples. The Cl/Br mass ratio and the total dissolved Cl– concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m laterally in near-surface sedimentary deposits. Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests formation of perched water and horizontal transport during periods of high recharge. In a few locations, brine migrated to depths of 67 m within 3 to 5 yr. Elevated Cl– concentrations were found to depths of 2 m in roadbed material. In drainage ditches along roads, where runoff accumulates and recharge of surface water is high, Cl– was flushed from the sediments in 3 to 4 yr. In areas of lower recharge, Cl– remained in the sediments after 5 yr. Vertical brine movement is directly related to surface recharge through sediments. The distribution of Cl– in pore water and sediments is consistent with estimates of vadose zone residence times and spatial distribution of surface water recharge from other investigations at the subsurface

Larry Hull; Carolyn Bishop

2004-02-01T23:59:59.000Z

489

Actinide Corroles: Synthesis and Characterization of Thorium(IV) and Uranium(IV) bis(-chloride) Dimers  

SciTech Connect (OSTI)

The first synthesis and structural characterization of actinide corroles is presented. Thorium(IV) and uranium(IV) macrocycles of Mes2(p-OMePh)corrole were synthesised and characterized by single-crystal X-ray diffraction, UV-Visible spectroscopy, variable-temperature 1H NMR, ESI mass spectrometry and cyclic voltammetry.

Ward, Ashleigh L.; Buckley, Heather L.; Gryko, Daniel T.; Lukens, Wayne W.; Arnold, John

2013-12-01T23:59:59.000Z

490

Quantitative analysis of heavy metals emission during the combustion and baling of polyvinyl chloride insulated copper wire  

E-Print Network [OSTI]

was conducted and compared to the airborne dust samples collected during the baling process. From these results, occupational exposures to heavy metals during the reclamation of PVC insulated copper wire were assessed. Bulk ash and dust samples were ?aken...

Pickard, David Paul

1996-01-01T23:59:59.000Z

491

Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene  

DOE Patents [OSTI]

A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1982-03-31T23:59:59.000Z

492

Morphology of GaAs/sub 1-x/P/sub x/ superlattices grown by MOCVD and chloride VPE  

SciTech Connect (OSTI)

Distorted layer growth manifested by nonuniform etching may occur in GaAs/sub 1-x/P/sub x/ superlattices grown by MOCVD and VPE. The distortion was found to be more severe for MOCVD growth than for VPE. The distortion is decreased by decreasing the magnitude of the interlayer strain in the superlattice but does not depend upon the layer thickness. The rate of crystal growth, the temperature of growth and the strain rate in the layer supporting the superlattice also influence the distortion. Several possible causes of the effect are discussed, including nonuniform elastic stress and/or compositional nonuniformity. 12 references, 6 figures.

Blakeslee, A.E.; Kibbler, A.; Wanlass, M.W.

1985-03-01T23:59:59.000Z

493

Estimation of agricultural benefits due to chloride control along the Pease River alluvium in the rolling plains of Texas  

E-Print Network [OSTI]

plants (Maes and Hoffman, 1977). To prevent this accumulation, extra irrigation water is usually applied to "leach" the salts below the active zoot zone. Study Area The entire watershed for the Red River drains some 93, 500 square miles. With its... plants (Maes and Hoffman, 1977). To prevent this accumulation, extra irrigation water is usually applied to "leach" the salts below the active zoot zone. Study Area The entire watershed for the Red River drains some 93, 500 square miles. With its...

Zacharias, Thomas Paul

2012-06-07T23:59:59.000Z

494

Interaction of Ethyl Chloride with Amorphous Solid Water Thin Film on Ru(001) and O/Ru(001) Surfaces  

E-Print Network [OSTI]

demonstrated for several molecules beside N2 such as CCl4,7 CD3Cl,8 and CO2.9 EC was chosen for this study coverage, respectively. Compression of preadsorbed 0.3 ML EC molecules into small islands on the surface developed above 20 ASW BL. A reversed TPD peak shift of the trapped EC molecules occurs from its compressed

Asscher, Micha

495

Solvation Structures and Dynamics of the Magnesium Chloride (Mg2+–Cl–) Ion Pair in Water–Ethanol Mixtures  

Science Journals Connector (OSTI)

E-mail: A.C., anupam.chatterjee@chem.iitb.ac.in; M.K.D., mayankd@chem.iitb.ac.in. ... Jorgensen, W. L.; Chandrasekhar, J.; Madura, J. D.; Impey, R. W.; Klein, M. L.Comparison of Simple Potential Functions for Simulating Liquid Water J. Chem. ...

Anupam Chatterjee; Mayank Kumar Dixit; B. L. Tembe

2013-07-05T23:59:59.000Z

496

A study of the condensation of propene and isobutene with benzene in the presence of anhydrous ferric chloride  

E-Print Network [OSTI]

A STUDT Qt THE OCNZESlSATIQS OP PHQP%SE ASO ZSOSOTESE SZTH EEWZCEE IH THE ~QE Qp ASHTCEOUS WEEHZQ OHX QEISE Lewis Lialea Qarpeater Jwas 1ESS Approval as to style aa4 contest rsec~alehi H Q o t 0 p rtasat o Ohealstrr ma Qh~ A STUDI Of THE O... of the 44rlsaltaral an4 Hsshaaf sal Oolloso ef Texas Partial Falfilmoat of ihs Reqairsasats for the BeSres of Raster of Solsaae Ha Jor Sab)eot s Ohematsal Eagaoerlsg By Loafs Lla4sa OarPsa'tor yea? LOSS ) zzP 7 gest-& The writer ?%shee ae express...

Carpenter, Louis Linden

1938-01-01T23:59:59.000Z

497

Effect of calcium chloride on pH and availability of zinc and phosphorus in three calcareous soils  

E-Print Network [OSTI]

has been shown that the concentration of Ca in the soil solution seriously affects the soil pH. The pH of the CaCO -CO -H 0 system in equilibrium with the CO concentration normally present in the atmosphere has been shown to be 8. 3. How- ever... to be more soluble than calcite which causes a higher pH, HCO3 and Ca concentration in the soil solution. They suggested that in a study of solubility of calcareous soils, measurements of P O, pH, 2 Ca p Mg p HC03 and ionic strength in equilibrium extracts...

Podisuk, Varangkana

1976-01-01T23:59:59.000Z

498

One-pot synthesis of 5-hydroxymethylfurfural directly from cottonseed hull biomass using chromium (III) chloride in ionic liquid  

Science Journals Connector (OSTI)

We studied the direct synthesis of 5-hydroxymethylfurfural (5-HMF) from cottonseed hull biomass...3·6H2O amount, and cottonseed hull loading on the yield of 5-HMF was investigated. As a result, a 5-HMF yield up t...

Shui Wang; Yizhen Du; Ping Zhang; Xiaowei Cheng…

2014-12-01T23:59:59.000Z

499

A study of the effect of chloride on mercury removal in a fluidized bed combustion (FBC) system  

SciTech Connect (OSTI)

Mercury exists in three forms, which are elemental mercury, inorganic mercury compounds, and organic mercury. Each form of mercury has a very different exposure potential. Oxidized mercury is soluble and has a tendency to associate with particles. Nearly all the post-combustion flue gas cleaning systems proposed to remove mercury may be categorized as either scrubbers or adsorbers. Therefore, the mercury sink in the cleaning system will be either the excess water of a wet scrubber or the mercury laden sorbent from an absorber. The major problem for post-combustion mercury capture systems is capturing the practically water-insoluble elemental mercury. Co-firing with high chlorine coal or RDF in utility boiler systems can provide an HCI atmosphere for the oxidation of elemental mercury in flue gas at relatively low temperatures (500--600 C). The objective of this study is to increase the efficiency of mercury emission cleaning methods by using HCl to convert elemental mercury to oxidized mercury species at low monetary costs and lower other toxic air emissions. When high chlorine (0.3--0.5%) coals were burned and a high intensity vortex flow (from secondary air) was used, around 70% of the total mercury in the fuel was condensed and absorbed by the fly ash (including calcium compounds). The remaining 30% of total fuel mercury was emitted in the gas phase in the flue gas. As for the gas phase mercury, about 98% of it exists in an oxidized form with a higher boiling temperature than elemental mercury and can be easily captured by an ESP or FGP apparatus. Only about 0.5% of the total fuel mercury was released to the atmosphere in elemental form.

Liu, K.; Gao, Y.; Li, F.; Pan, W.P.; Riley, J.T.; Mehta, A.K.; Ho, K.K.; Smith, S.R.

2000-07-01T23:59:59.000Z

500

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network [OSTI]

H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

Mobley, David Paul

2013-01-01T23:59:59.000Z