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1

Transport phenomena in metal-halide lamps a poly-diagnostic study  

E-Print Network [OSTI]

/ spectroscopie. Subject headings: gas discharges / metal-halide lamps / plasma diagnostics / plasma properties-halide arc lamps . . . . . . . . . . . 7 1.3 Scope of ThesisTransport phenomena in metal-halide lamps a poly-diagnostic study Tanya Nimalasuriya #12;Copyright

Eindhoven, Technische Universiteit

2

Wick for metal vapor laser  

DOE Patents [OSTI]

An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

Duncan, David B. (Livermore, CA)

1992-01-01T23:59:59.000Z

3

Spatial and time-dependent distribution of plasma parameters in the metal-halide arc lamp.  

E-Print Network [OSTI]

Spatial and time-dependent distribution of plasma parameters in the metal-halide arc lamp. A. Khakhaev, L. Luizova, K. Ekimov and A. Soloviev Petrozavodsk State University, Russia The metal-halide arc lamp is an effective light source and its investigation has a long history, but even at present some

Paris-Sud XI, Université de

4

Spectroscopic effects of disorder and vibrational localization in mixed-halide metal-halide chain solids  

SciTech Connect (OSTI)

Resonance Raman techniques, together with lattice-dynamics and Peierls-Hubbard modelling, are used to explore the electronic and vibrational dynamics of the quasi-one-dimensional metal-halogen chain solids [Pt(en){sub 2}][R(en){sub 2}X{sub 2}](ClO{sub 4}){sub 4}, (en = C{sub 2}H{sub 8}N{sub 2} and X=Cl, Br), abbreviated ``PLX.`` The mixed-halide materials PtCl{sub 1-x}Br{sub x} and PtCl{sub 1-x}I{sub x} consist of long mixed chains with heterojunctions between segments of the two constituent materials. Thus, in addition to providing mesoscale modulation of the chain electronic states, they serve as prototypes for elucidating the properties to be expected for macroscopic heterojunctions of these highly nonlinear materials. Once a detailed understanding of the various local vibrational modes occurring in these disordered solids is developed, the electronic structure of the chain segments and junctions can be probed by tuning the Raman excitation through their various electronic resonances.

Love, S.P.; Scott, B.; Worl, L.A.; Huckett, S.C.; Saxena, A.; Huang, X.Z.; Bishop, A.R.; Swanson, B.I.

1993-02-01T23:59:59.000Z

5

Spatial and time-dependent distribution of plasma parameters in the metal-halide arc lamp  

E-Print Network [OSTI]

It was shown by several authors that closed high pressure arc a.c. discharge in mercury vapors with addition of metal halide cannot be described in frames of the local thermodynamic equilibrium (LTE) model. However some plasma parameters (electron and high lying excited states densities as well as Hg metastable levels densities) are assumed to be in equilibrium with electron temperature and these assumptions are applied in plasma diagnostics. To verify these supposition the method of local plasma spectroscopy based on spatial and temporal distribution of spectral line profiles was developed. The experimental set up is based on diffraction spectrometer with large aperture, spatial scanning device and photodetector, which allows to carry out the measurements in chosen phases of current period. The software for data acquisition and processing is based on LabVIEW system. The original method of joint data processing was applied to data arrays containing spatial, spectral and temporal distribution of a source surfa...

Khakhaev, A; Ekimov, K; Soloviev, A; Khakhaev, Anatoly; Luizova, Lidia; Ekimov, Konstantin; Soloviev, Alexey

2004-01-01T23:59:59.000Z

6

Spectroscopic effects of disorder and vibrational localization in mixed-halide metal-halide chain solids  

SciTech Connect (OSTI)

Resonance Raman techniques, together with lattice-dynamics and Peierls-Hubbard modelling, are used to explore the electronic and vibrational dynamics of the quasi-one-dimensional metal-halogen chain solids [Pt(en)[sub 2

Love, S.P.; Scott, B.; Worl, L.A.; Huckett, S.C.; Saxena, A.; Huang, X.Z.; Bishop, A.R.; Swanson, B.I.

1993-01-01T23:59:59.000Z

7

Stability diagrams for fourfold coordination of polyvalent metal ions in molten mixtures of halide salts  

SciTech Connect (OSTI)

The stability of local fourfold coordination for divalent and trivalent metal ions in liquid mixtures of polyvalent metal halides and alkali halides is classified by means of structural coordinates obtained from properties of the elements. In parallel with earlier classifications of compound crystal structures and molecular shapes, the elemental properties are taken from first-principles calculations of valence electron orbitals in atoms, in the form of (i) the nodal radii of Andreoni, Baldereschi and Guizzetti or (ii) the pseudopotential radii or Zunger and Cohen. As a third alternative a classification based on Pettifor's phenomenological chemical scale of the elements is also considered. The alternative structural classification schemes that are developed from these elemental properties are generally successfully in distinguishing molten mixtures in which the available experimental evidence indicates long-lived fourfold coordination of polyvalent metal ions. In addition, Pettifor's chemical scale scheme is useful in sorting out finer details of local coordination in the liquid state. 3 figs., 71 refs.

Akdeniz, Z. (International Centre for Theoretical Physics, Trieste (Italy) Istanbul Univ. (Turkey). Dept. of Physics); Tosi, M.P. (Trieste Univ. (Italy). Dipt. di Fisica Teorica Argonne National Lab., IL (USA))

1988-11-01T23:59:59.000Z

8

Chemical vapor deposition of group IIIB metals  

DOE Patents [OSTI]

Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

Erbil, A.

1989-11-21T23:59:59.000Z

9

Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids  

SciTech Connect (OSTI)

Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 ± 0.5) × 106 M?1 s?1) and with FeBr2+ (k = (3.0 ± 0.5) × 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

2012-03-14T23:59:59.000Z

10

190 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 30, NO. 1, FEBRUARY 2002 Gap Closure in a Cold Metal Halide Lamp  

E-Print Network [OSTI]

lamp has been investigated using a two-dimensional, plasma transport model. Im- ages are presented- charge devices, lighting, plasma applications. METAL halide high-intensity-discharge (HID) lamps op- erate as high-pressure thermal arcs [1]. The cold fills of HID lamps are typically 50­100 torr of a rare

Kushner, Mark

11

New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce Carbon Pollution  

Office of Energy Efficiency and Renewable Energy (EERE)

As part of the Energy Department’s efforts to develop efficiency standards that cut carbon pollution and save money by saving energy, U.S. Energy Secretary Ernest Moniz announced that the Department has finalized new energy efficiency standards for metal halide lamp fixtures.

12

Injection locked oscillator system for pulsed metal vapor lasers  

DOE Patents [OSTI]

An injection locked oscillator system for pulsed metal vapor lasers is disclosed. The invention includes the combination of a seeding oscillator with an injection locked oscillator (ILO) for improving the quality, particularly the intensity, of an output laser beam pulse. The present invention includes means for matching the first seeder laser pulses from the seeding oscillator to second laser pulses of a metal vapor laser to improve the quality, and particularly the intensity, of the output laser beam pulse.

Warner, Bruce E. (Livermore, CA); Ault, Earl R. (Dublin, CA)

1988-01-01T23:59:59.000Z

13

Preparation of cerium halide solvate complexes  

DOE Patents [OSTI]

Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.

Vasudevan, Kalyan V; Smith, Nickolaus A; Gordon, John C; McKigney, Edward A; Muenchaussen, Ross E

2013-08-06T23:59:59.000Z

14

D/sup -/ production by charge transfer in metal vapors  

SciTech Connect (OSTI)

Fast D/sup -/ ions can be produced from D/sup +/ by multiple charge-transfer collisions in a metal-vapor target. Experimental cross sections and thick-target D/sup -/ yields are presented and discussed. The high D/sup -/ yield experimentally observed from charge transfer in cesium vapor is consistent with recent low-energy cross-section calculations and measurements.

Schlachter, A.S.

1980-10-01T23:59:59.000Z

15

Method for the generation of variable density metal vapors which bypasses the liquidus phase  

DOE Patents [OSTI]

The present invention provides a method for producing a metal vapor that includes the steps of combining a metal and graphite in a vessel to form a mixture; heating the mixture to a first temperature in an argon gas atmosphere to form a metal carbide; maintaining the first temperature for a period of time; heating the metal carbide to a second temperature to form a metal vapor; withdrawing the metal vapor and the argon gas from the vessel; and separating the metal vapor from the argon gas. Metal vapors made using this method can be used to produce uniform powders of the metal oxide that have narrow size distribution and high purity.

Kunnmann, Walter (Stony Brook, NY); Larese, John Z. (Rocky Point, NY)

2001-01-01T23:59:59.000Z

16

Method for removing metal vapor from gas streams  

DOE Patents [OSTI]

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

Ahluwalia, R. K. (6440 Hillcrest Dr., Burr Ridge, IL 60521); Im, K. H. (925 Lehigh Cir., Naperville, IL 60565)

1996-01-01T23:59:59.000Z

17

Vapor deposition of tantalum and tantalum compounds  

SciTech Connect (OSTI)

Tantalum, and many of its compounds, can be deposited as coatings with techniques ranging from pure, thermal chemical vapor deposition to pure physical vapor deposition. This review concentrates on chemical vapor deposition techniques. The paper takes a historical approach. The authors review classical, metal halide-based techniques and current techniques for tantalum chemical vapor deposition. The advantages and limitations of the techniques will be compared. The need for new lower temperature processes and hence new precursor chemicals will be examined and explained. In the last section, they add some speculation as to possible new, low-temperature precursors for tantalum chemical vapor deposition.

Trkula, M. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.

1996-04-01T23:59:59.000Z

18

Method of physical vapor deposition of metal oxides on semiconductors  

DOE Patents [OSTI]

A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

Norton, David P. (Knoxville, TN)

2001-01-01T23:59:59.000Z

19

VAPORIZATION OF TUNGSTEN-METAL IN STEAM AT HIGH TEMPERATURES.  

SciTech Connect (OSTI)

The vaporization of tungsten from the APT spallation target dominates the radiological source term for unmitigated target overheating accidents. Chemical reactions of tungsten with steam which persist to tungsten temperatures as low as 800 C result in the formation of a hydrated tungsten-oxide which has a high vapor pressure and is readily convected in a flowing atmosphere. This low-temperature vaporization reaction essentially removes the oxide film that forms on the tungsten-metal surface as soon as it forms, leaving behind a fresh metallic surface for continued oxidation and vaporization. Experiments were conducted to measure the oxidative vaporization rates of tungsten in steam as part of the effort to quantify the MT radiological source term for severe target accidents. Tests were conducted with tungsten rods (1/8 inch diameter, six inches long) heated to temperatures from approximately 700 C to 1350 C in flowing steam which was superheated to 140 C. A total of 19 experiments was conducted. Fifteen tests were conducted by RF induction heating of single tungsten rods held vertical in a quartz glass retort. Four tests were conducted in a vertically-mounted tube furnace for the low temperature range of the test series. The aerosol which was generated and transported downstream from the tungsten rods was collected by passing the discharged steam through a condenser. This procedure insured total collection of the steam along with the aerosol from the vaporization of the rods. The results of these experiments revealed a threshold temperature for tungsten vaporization in steam. For the two tests at the lowest temperatures which were tested, approximately 700 C, the tungsten rods were observed to oxidize without vaporization. The remainder of the tests was conducted over the temperature range of 800 C to 1350 C. In these tests, the rods were found to have lost weight due to vaporization of the tungsten and the missing weight was collected in the downstream condensate system. The aerosol formed a fine white smoke of tungsten-oxide which was visible to the eye as it condensed in the laminar boundary layer of steam which flowed along the surface of the rod. The aerosol continued to flow as a smoke tube downstream of the rod, flowing coaxially along the centerline axis of the quartz glass tube and depositing by impaction along the outside of a bend and at sudden area contractions in the piping. The vaporization rate data from the 17 experiments which exceeded the vaporization threshold temperature are shown in Figure 5 in the form of vaporization rates (g/cm{sup 2} s) vs. inverse temperature (K{sup {minus}1}). Two correlations to the present data are presented and compared to a published correlation by Kilpatrick and Lott. The differences are discussed.

GREENE,G.A.; FINFROCK,C.C.

2000-10-01T23:59:59.000Z

20

Universal scaling of potential energy functions describing intermolecular interactions. II. The halide-water and alkali metal-water interactions  

SciTech Connect (OSTI)

The scaled forms of the newly introduced generalized potential energy functions (PEFs) describing intermolecular interactions [J. Chem. Phys. xx, yyyyy (2011)] have been used to fit the ab-initio minimum energy paths (MEPs) for the halide- and alkali metal-water systems X-(H2O), X=F, Cl, Br, I, and M+(H2O), M=Li, Na, K, Rb, Cs. These generalized forms produce fits to the ab-initio data that are between one and two orders of magnitude better in the ?2 than the original forms of the PEFs. They were found to describe both the long-range, minimum and repulsive wall of the potential energy surface quite well. Overall the 4-parameter extended Morse (eM) and generalized Buckingham exponential-6 (gB-e6) potentials were found to best fit the ab-initio data. Furthermore, a single set of parameters of the reduced form was found to describe all candidates within each class of interactions. The fact that in reduced coordinates a whole class of interactions can be represented by a single PEF, yields the simple relationship between the molecular parameters associated with energy (well depth, ?), structure (equilibrium distance, rm) and spectroscopy (anharmonic frequency, ?):€? = A? (? /?)1/ 2 /rm + B?? /rm 3 , where A and B are constants depending on the underlying PEF. This more general case of Badger’s rule has been validated using the experimentally measured frequencies of the hydrogen bonded OH stretching vibrations in the halide-water series.

Werhahn, Jasper C.; Akase, Dai; Xantheas, Sotiris S.

2014-08-14T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Inelastic Scattering of 20-kev Electrons in Metal Vapors  

Science Journals Connector (OSTI)

The low-energy losses of 20-kev electrons passing through the vapors of Zn, Cd, Hg, Na, K, Mg, Ca, Sb, Pb, and KCl, have been measured by using an electrostatic analyzer previously used for measuring electron energy losses in thin metal films. The atomic transitions corresponding to the measured energy losses are in many cases fairly easily established. However, there remain some which are questionable due to the fact that there is more than one feasible transition with energy differences of the order of the given energy loss. It is established that the principal interaction results in the excitation from the ground state of the neutral atom to the first excited level—the resonance excitation. It is also found that dipole excitations predominate

Lewis B. Leder

1957-09-15T23:59:59.000Z

22

E-Print Network 3.0 - alkali-metal vapor density Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physics 65 nature physics | VOL 3 | APRIL 2007 | www.nature.comnaturephysics 227 REVIEW ARTICLE Summary: in a high-density alkali-metal vapor in low magnetic fields. Phys....

23

High average power magnetic modulator for metal vapor lasers  

DOE Patents [OSTI]

A three-stage magnetic modulator utilizing magnetic pulse compression designed to provide a 60 kV pulse to a copper vapor laser at a 4.5 kHz repetition rate is disclosed. This modulator operates at 34 kW input power. The circuit includes a step up auto transformer and utilizes a rod and plate stack construction technique to achieve a high packing factor.

Ball, Don G. (Livermore, CA); Birx, Daniel L. (Oakley, CA); Cook, Edward G. (Livermore, CA); Miller, John L. (Livermore, CA)

1994-01-01T23:59:59.000Z

24

Actinide halide complexes  

SciTech Connect (OSTI)

A compound of the formula MX{sub n}L{sub m} wherein M = Th, Pu, Np,or Am thorium, X = a halide atom, n = 3 or 4, L is a coordinating ligand selected from the group consisting of aprotic Lewis bases having an oxygen-, nitrogen-, sulfur-, or phosphorus-donor, and m is 3 or 4 for monodentate ligands or is 2 for bidentate ligands, where n + m = 7 or 8 for monodentate ligands or 5 or 6 for bidentate ligands, a compound of the formula MX{sub n} wherein M, X, and n are as previously defined, and a process of preparing such actinide metal compounds including admixing the actinide metal in an aprotic Lewis base as a coordinating solvent in the presence of a halogen-containing oxidant, are provided.

Avens, L.R.; Zwick, B.D.; Sattelberger, A.P.; Clark, D.L.; Watkin, J.G.

1991-02-07T23:59:59.000Z

25

Evolution of Light-Induced Vapor Generation at a Liquid-Immersed Metallic Nanoparticle  

E-Print Network [OSTI]

Evolution of Light-Induced Vapor Generation at a Liquid-Immersed Metallic Nanoparticle Zheyu Fang nanoparticle in a liquid medium is illuminated with resonant light of sufficient intensity, a nanometer scale- known process of liquid boiling, occurring at a single nanoparticle nucleation site, resulting from

Polman, Albert

26

E-Print Network 3.0 - absorbable organic halides Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 64 386 JACKHALPERN VOl. 3 xidative-AdditionReactions of Transition Metal Complexes Summary: peroxide, as well as various organic halides and metal...

27

Aerosol chemical vapor deposition of metal oxide films  

DOE Patents [OSTI]

A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate.

Ott, K.C.; Kodas, T.T.

1994-01-11T23:59:59.000Z

28

E-Print Network 3.0 - alkali metal nitrate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

METAL-ALKALI HALIDE Summary: CONDUCTIVITY OF ALKALI METAL-ALKALI HALIDE SOLUTIONS R. GILBERT and G. J. MORGAN The Physics Department... to liquid alkali metals electrons are...

29

Formation of amorphous metal alloys by chemical vapor deposition  

DOE Patents [OSTI]

Amorphous alloys are deposited by a process of thermal dissociation of mixtures of organometallic compounds and metalloid hydrides,e.g., transition metal carbonyl, such as nickel carbonyl and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit. 1 fig.

Mullendore, A.W.

1988-03-18T23:59:59.000Z

30

Actinide halide complexes  

DOE Patents [OSTI]

A compound is described of the formula MX[sub n]L[sub m] wherein M is a metal atom selected from the group consisting of thorium, plutonium, neptunium or americium, X is a halide atom, n is an integer selected from the group of three or four, L is a coordinating ligand selected from the group consisting of aprotic Lewis bases having an oxygen-, nitrogen-, sulfur-, or phosphorus-donor, and m is an integer selected from the group of three or four for monodentate ligands or is the integer two for bidentate ligands, where the sum of n+m equals seven or eight for monodentate ligands or five or six for bidentate ligands. A compound of the formula MX[sub n] wherein M, X, and n are as previously defined, and a process of preparing such actinide metal compounds are described including admixing the actinide metal in an aprotic Lewis base as a coordinating solvent in the presence of a halogen-containing oxidant.

Avens, L.R.; Zwick, B.D.; Sattelberger, A.P.; Clark, D.L.; Watkin, J.G.

1992-11-24T23:59:59.000Z

31

Vapor-Particle Separation Using Microporous Metallic Membrane in Crossflow Filtration  

SciTech Connect (OSTI)

Simultaneous separation of vapor and particles in industrial processes could be a key step toward manufacturing of high-quality goods. The separation is critical for successful measurement of volatile or semi-volatile aerosol particles, which no reliable technique exists. We have developed a technique for separation of vapor and particles simultaneously using a specialty microporous metallic membrane. The separator allows the thermally denuded particles traverse straight through the membrane tube, while the vapor molecules permeate through the membrane, separate from the particles and are removed subsequently. The separation technique virtually eliminates the possibility of contamination by vapor re- condensation. We tested the prototype of the vapor-particle separator (VPS) using aerosols prepared from sodium chloride to represent non-volatile aerosols. Chemical like dioctyl phthalate was chosen to represent volatile particles. The test aerosol particles were generated by an atomizer followed by a tandem differential mobility analyser to produce a stream of monodisperse particles in the size range of 10 to 100 nm. In real world particles, we tested the VPS using diesel engine particles that is a mixture of complex chemical composition. Number concentration of the nonvolatile particles reduced as the temperature increased, but the mode diameter of the aerosol population remained unchanged. Number concentration of the volatile particles was also reduced as the temperature increased, but their mode diameters became smaller as particles shrunk in diameter. Differences in the thermal behaviour of the particles were attributed to its transition energy barrier and evaporation rate. Mass balance analysis suggests the separation of vapor and test particles was reasonably complete. Thus, we conclude the VPS could provide an effective means for quantitative characterization of aerosol volatility and separation of vapors from particles.

Cheng, Mengdawn [ORNL] [ORNL

2013-01-01T23:59:59.000Z

32

Life cycle cost study for coated conductor manufacture by metal organic chemical vapor deposition  

SciTech Connect (OSTI)

The purpose of this report is to calculate the cost of producing high temperature superconducting wire by the Metal Organic Chemical Vapor Deposition (MOCVD) process. The technology status is reviewed from the literature and a plant conceptual design is assumed for the cost calculation. The critical issues discussed are the high cost of the metal organic precursors, the material utilization efficiency and the capability of the final product as measured by the critical current density achieved. Capital, operating and material costs are estimated and summed as the basis for calculating the cost per unit length of wire. Sensitivity analyses of key assumptions are examined to determine their effects on the final wire cost. Additionally, the cost of wire on the basis of cost per kiloampere per meter is calculated for operation at lower temperatures than the liquid nitrogen boiling temperature. It is concluded that this process should not be ruled out on the basis of high cost of precursors alone.

Chapman, J.N.

1999-07-13T23:59:59.000Z

33

Lanthanide-halide based humidity indicators  

DOE Patents [OSTI]

The present invention discloses a lanthanide-halide based humidity indicator and method of producing such indicator. The color of the present invention indicates the humidity of an atmosphere to which it is exposed. For example, impregnating an adsorbent support such as silica gel with an aqueous solution of the europium-containing reagent solution described herein, and dehydrating the support to dryness forms a substance with a yellow color. When this substance is exposed to a humid atmosphere the water vapor from the air is adsorbed into the coating on the pore surface of the silica gel. As the water content of the coating increases, the visual color of the coated silica gel changes from yellow to white. The color change is due to the water combining with the lanthanide-halide complex on the pores of the gel.

Beitz, James V. (Hinsdale, IL); Williams, Clayton W. (Chicago, IL)

2008-01-01T23:59:59.000Z

34

An inverted cylindrical sputter magnetron as metal vapor supply for electron cyclotron resonance ion sources  

SciTech Connect (OSTI)

An inverted cylindrical sputter magnetron device has been developed. The magnetron is acting as a metal vapor supply for an electron cyclotron resonance (ECR) ion source. FEM simulation of magnetic flux density was used to ensure that there is no critical interaction between both magnetic fields of magnetron and ECR ion source. Spatially resolved double Langmuir probe and optical emission spectroscopy measurements show an increase in electron density by one order of magnitude from 1 × 10{sup 10} cm{sup ?3} to 1 × 10{sup 11} cm{sup ?3}, when the magnetron plasma is exposed to the magnetic mirror field of the ECR ion source. Electron density enhancement is also indicated by magnetron plasma emission photography with a CCD camera. Furthermore, photographs visualize the formation of a localized loss-cone - area, when the magnetron is operated at magnetic mirror field conditions. The inverted cylindrical magnetron supplies a metal atom load rate of R > 1 × 10{sup 18} atoms/s for aluminum, which meets the demand for the production of a milliampere Al{sup +} ion beam.

Weichsel, T., E-mail: tim.weichsel@fep.fraunhofer.de; Hartung, U.; Kopte, T. [Fraunhofer Institute for Electron Beam and Plasma Technology, 01277 Dresden (Germany)] [Fraunhofer Institute for Electron Beam and Plasma Technology, 01277 Dresden (Germany); Zschornack, G. [Institute of Solid State Physics, Dresden University of Technology, 01062 Dresden, Germany and Helmholtz-Zentrum Dresden-Rossendorf e.V., Institute of Ion Beam Physics and Materials Research, Dresden (Germany)] [Institute of Solid State Physics, Dresden University of Technology, 01062 Dresden, Germany and Helmholtz-Zentrum Dresden-Rossendorf e.V., Institute of Ion Beam Physics and Materials Research, Dresden (Germany); Kreller, M.; Silze, A. [DREEBIT GmbH, 01900 Grossroehrsdorf (Germany)] [DREEBIT GmbH, 01900 Grossroehrsdorf (Germany)

2014-05-15T23:59:59.000Z

35

E-Print Network 3.0 - ammonium halides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

POCl3, SOCl2, SO2Cl2 Anhydrous metal halides, such as AlCl3, TiCl4, ZrCl4, SnCl4... Phosphorus pentoxide Calcium carbide Organic acid halides and anhydrides of low molecular...

36

Aluminum Nitride Micro-Channels Grown via Metal Organic Vapor Phase Epitaxy for MEMs Applications  

SciTech Connect (OSTI)

Aluminum nitride (AlN) is a promising material for a number of applications due to its temperature and chemical stability. Furthermore, AlN maintains its piezoelectric properties at higher temperatures than more commonly used materials, such as Lead Zirconate Titanate (PZT) [1, 2], making AlN attractive for high temperature micro and nanoelectromechanical (MEMs and NEMs) applications including, but not limited to, high temperature sensors and actuators, micro-channels for fuel cell applications, and micromechanical resonators. This work presents a novel AlN micro-channel fabrication technique using Metal Organic Vapor Phase Epitaxy (MOVPE). AlN easily nucleates on dielectric surfaces due to the large sticking coefficient and short diffusion length of the aluminum species resulting in a high quality polycrystalline growth on typical mask materials, such as silicon dioxide and silicon nitride [3,4]. The fabrication process introduced involves partially masking a substrate with a silicon dioxide striped pattern and then growing AlN via MOVPE simultaneously on the dielectric mask and exposed substrate. A buffered oxide etch is then used to remove the underlying silicon dioxide and leave a free standing AlN micro-channel. The width of the channel has been varied from 5 ìm to 110 ìm and the height of the air gap from 130 nm to 800 nm indicating the stability of the structure. Furthermore, this versatile process has been performed on (111) silicon, c-plane sapphire, and gallium nitride epilayers on sapphire substrates. Reflection High Energy Electron Diffraction (RHEED), Atomic Force Microscopy (AFM), and Raman measurements have been taken on channels grown on each substrate and indicate that the substrate is influencing the growth of the AlN micro-channels on the SiO2 sacrificial layer.

Rodak, L.E.; Kuchibhatla, S.; Famouri, P.; Ting, L.; Korakakis, D.

2008-01-01T23:59:59.000Z

37

Collision cross sections and equilibrium fractions of ions and atoms in metal vapor targets. Project progress report, June 1, 1979-May 31, 1980  

SciTech Connect (OSTI)

The objective of this program is to measure atomic collision cross sections and equilibrium fractions of ions and atoms in metal vapor targets. The goal is to obtain experimental information on atomic collision processes relevant to the Magnetic Fusion Energy Program. In particular, in connection with the development of double charge exchange D/sup -/ ion sources, we are measuring D/sup -/ formation cross sections in alkaline-earth metal vapor targets. During the period covered in this report we have measured electron transfer cross sections for 3-40 keV D/sup +/ ions and D/sup 0/ atoms in collision with calcium vapor.

Morgan, T J

1980-01-01T23:59:59.000Z

38

Pressure dependence of phonons and excitons in InSe films prepared by metal-organic chemical vapor deposition  

Science Journals Connector (OSTI)

The pressure dependence of the Raman spectra of phase-pure InSe thin films prepared by the low-pressure metal-organic chemical vapor deposition technique has been studied using a diamond-anvil high-pressure cell. Enhancement in the intensities of the Raman modes has been observed as a result of pressure-induced “tuning” of the energy of the M1-type hyperbolic exciton in InSe at ?2.54 eV through discrete incident laser photon energies. The pressure coefficients of the phonon modes and of the hyperbolic exciton in InSe have been determined.

In-Hwan Choi and Peter Y. Yu

2003-10-27T23:59:59.000Z

39

Vitrification of IFR and MSBR halide salt reprocessing wastes  

SciTech Connect (OSTI)

Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

Siemer, D.D. [Idaho National Laboratory, 12N 3167E, Idaho Falls, ID 83402 (United States)

2013-07-01T23:59:59.000Z

40

Metal organic chemical vapor deposition of 111-v compounds on silicon  

DOE Patents [OSTI]

Expitaxial composite comprising thin films of a Group III-V compound semiconductor such as gallium arsenide (GaAs) or gallium aluminum arsenide (GaAlAs) on single crystal silicon substrates are disclosed. Also disclosed is a process for manufacturing, by chemical deposition from the vapor phase, epitaxial composites as above described, and to semiconductor devices based on such epitaxial composites. The composites have particular utility for use in making light sensitive solid state solar cells.

Vernon, Stanley M. (Wellesley, MA)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

E-Print Network 3.0 - alkali-metal vapor cells Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dispenser source Timothy M. Roach and Dwayne Henclewood Summary: pressurized storage tank, or by laser ablation, or, most typically for rubidium and other alkali metals......

42

The growth of CdTe/GaAs heteroepitaxial films by metal–organic chemical vapor deposition  

Science Journals Connector (OSTI)

A process for the growth of CdTe/GaAs heteroepitaxialfilms using metal–organic chemical vapor deposition(MOCVD) has been developed. The initial results of the determination of the deposition mechanism are reported. A pilot production demonstration using experimentally determined operating conditions has been completed. This is the first reported pilot production of CdTe/GaAs using 2 in. diam GaAs substrates in a multiple slice commercially manufactured MOCVD system. The results reported therein demonstrate that MOCVD is a reliable reproducible production worthy process for preparation of CdTe/GaAs heterostructures. These results are applicable to a wide variety of CdTe based device technologies including IR detection fiber optics solar cells and others.

Philip L. Anderson

1986-01-01T23:59:59.000Z

43

Laboratory Measurements of Alkali Metal Containing Vapors Released during Biomass Combustion  

Science Journals Connector (OSTI)

Alkali metals, in particular potassium. have been implicated as key ingredients for enhancing fouling and slagging of heat transfer surfaces in power generating facilities that convert biomass to electricity. Whe...

David C. Dayton; Thomas A. Milne

1996-01-01T23:59:59.000Z

44

Laser vaporization clusters from metal loaded graphite used for SWNT generation  

E-Print Network [OSTI]

, these metal-carbon clusters were proved to be very reactive. 40 60 80 100 Number of Carbon Atoms Intensity of Carbon Atoms Intensity(arbitrary) (a) Positive (b) Negative Fig2. Enlargement of C70 to C73 C74 C76 C72, The Univ. of Tokyo In order to study the generation mechanism of SWNTs, we have studied metal-carbon binary

Maruyama, Shigeo

45

Clustering of metal atoms in organic media. 9. High-activity Ni/MgO catalysts prepared by metal vapor methods. Surface area and particle size effects  

SciTech Connect (OSTI)

A metal vapor method was employed to prepare highly dispersed Ni metal catalysts (solvated metal atom dispersed = SMAD catalyst) supported on MgO. Compared with conventional Ni/MgO compositions, the SMAD catalysts showed much greater activities for all reactions studied (hydrogenolysis of methylcyclopentane, MCP; hydrogenation/hydrogenolysis of toluene, TOL; methanation of carbon monoxide, CO; dehydration of isopropyl alcohol, IPA). These high activities for the SMAD catalysts are attributed to the high surface area of Ni on MgO and the high percentage of this Ni in a zero-valent state (reduction degree). Conventional methods for preparing Ni/MgO catalysts did not yield nearly such favorable surface areas or reduction degrees. Nickel particle size effects were observed during hydrogenolysis studies of MCP and hydrogenation studies of TOL. These phenomena are explained by assuming the size of an active Ni particle to be largest for hydrogenolysis of MCP > hydrogenation of TOL > methanation of CO approx. = dehydrogenation of IPA. 8 figures, 2 tables.

Matsuo, K.; Klabunde, K.J.

1982-02-01T23:59:59.000Z

46

Light narrowing of magnetic resonance lines in dense, optically pumped alkali-metal vapor  

Science Journals Connector (OSTI)

A new and unusual phenomenon which we call light narrowing is reported and discussed in this paper. We discovered this effect in dense, spin-polarized cesium vapor optically pumped with a cw blue dye laser beam tuned to the second resonance D1 line (4593 Å). We observe a significant narrowing of the radio-frequency power-broadened magnetic resonance lines (linewidths narrow by as much as a factor of 2.5) when the intensity of the circularly polarized incident dye laser beam is increased by either focusing the beam or by the removal of attenuating filters from the focused beam. The magnetic resonance linewidths in spin-polarized cesium vapor were measured over a wide range of cesium number densities (5×1012 cm-3 ?[Cs]?1×1016 cm-3). This corresponds to cesium spinexchange rates of 4.5×103 to 9×106 sec-1. For low cesium number densities (5×1012 1×1015 cm-3) this light-narrowing effect almost completely disappears. In the limit of low-radio-frequency power the magnetic resonance linewidths for focused and unfocused dye laser beam are nearly the same. Experimental observations on this new effect are presented in detail. In the latter part of this paper a self-contained theoretical treatment of the light-narrowing effect is developed. Using Bloch equations in the presence of optical pumping, spin relaxation (diffusion, electron randomization), rapid spin exchange, and radio-frequency magnetic field, expressions for magnetic resonance line shapes are derived. In general, we find good agreement between our experimental results and the theory.

N. D. Bhaskar; J. Camparo; W. Happer; A. Sharma

1981-06-01T23:59:59.000Z

47

Modeling metallic nanoparticle synthesis in a magnetron-based nanocluster source by gas condensation of a sputtered vapor  

SciTech Connect (OSTI)

Copper nanoparticles (NPs) were synthesized by inert-gas condensation of a sputtered metallic vapor using a dedicated commercial reactor. By controlling the time of residence of NPs in the carrier gas phase via the tuning of the collision path length, Cu NPs were produced. They exhibit various and well controlled diameters (3-10 nm) and a relatively narrow size dispersion. On the basis of these experimental results, a detailed modeling of NP nucleation and growth based on the classical nucleation theory was developed. It takes into account the peculiar geometry and thermal profile of the NP reactor. The simulated curves, calculated by a MATLAB program developed for that purpose, exhibit a good qualitative agreement with experiment. Moreover, they highlight the role of process parameters and the strong influence of the reactor temperature profile on the NP size distribution. In the future, such calculations could be used for the optimization of the NP source design in order to increase its efficiency and reproducibility.

Quesnel, E; Pauliac-Vaujour, E; Muffato, V [CEA-G/DRT/LITEN/DTNM, rue des Martyrs, 38054 Grenoble Cedex 9 (France)

2010-03-15T23:59:59.000Z

48

Thermal treatment induced change of diluted oxygen doped ZnTe films grown by metal-organic chemical vapor deposition  

Science Journals Connector (OSTI)

In this paper the authors report the growth of diluted oxygen doped ZnTe films (ZnTe:O) by metal-organic chemical vapor deposition (MOCVD). The effect of a post thermal annealing on the properties of the highly mismatched films has been investigated. It is found that the in-situ doping leads to an effective incorporation of oxygen into ZnTe films with different occupation configurations either on Zn or on Te site. The subsequent annealing process in a vacuum ambient leads to an enhancement of the oxygen incorporation into the ZnTe:O films due to the diffusion of the residual oxygen while the annealing with the same as-grown sample covered on top of the surface (denoted as “face-to-face” annealing in the text) is beneficial to the improvement of the film quality with manifest intermediate band emission at around 1.9?eV as revealed by the low-temperature photoluminescence. This study indicates that the mass-productive MOCVD technique may be suitable for the growth of highly mismatched ZnTe:O films for the application of the intermediate band solar cell.

2014-01-01T23:59:59.000Z

49

Lanthanide doped strontium barium mixed halide scintillators  

DOE Patents [OSTI]

The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped strontium barium mixed halide useful for detecting nuclear material.

Gundiah, Gautam; Bizarri, Gregory; Hanrahan, Stephen M; Bourret-Courchesne, Edith; Derenzo, Stephen E

2013-07-16T23:59:59.000Z

50

Vapor phase modifiers for oxidative coupling  

DOE Patents [OSTI]

Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

Warren, Barbara K. (Charleston, WV)

1991-01-01T23:59:59.000Z

51

Vaporization of bulk metals into single-digit nanoparticles by non-thermal plasma filaments in atmospheric pressure dielectric barrier discharges  

Science Journals Connector (OSTI)

Abstract A compact, inexpensive and simple dielectric barrier discharge (DBD) design is presented with related electro-thermal properties for the production of metal nanoparticles. Nanoparticle formation and growth mechanisms are depicted from size distributions and chemical analyses of particles collected just after the 70 kHz DBD in nitrogen. At first, it is confirmed that the initial local vapor flux is produced from the spots of interaction between plasma filaments and different metal electrodes (Au, Ag, and Cu). Amorphous and crystalline pure metal primary nanoparticles with diameters below 5 nm are then produced by physical nucleation in expanding vapors jets. Finally, some small agglomerates with diameters still below 5 nm are also formed by ballistic agglomeration of a fraction of these primary particles. This happens at the end of the vapor jet expansion, as well as after the production during the transit between subsequent filaments in the DBD. The first local agglomeration step can be limited at reduced energy per filament by lowering the initial vapor flux in smaller gaps, while the second growth step depends on the transit time in the DBD. Hence, such “low” energy plasma filaments (up to a few tens of µJ) lower the initial vapor flux to control the agglomeration. DBD were thus successfully tested for the production of tailored nanoparticles with tunable size, controlled morphology of spherical agglomerates and the same composition as the metal electrode. The production per unit energy (mol J?1) is related to both plasma and material properties. Besides, neglecting vapor and nanoparticles losses, the mass production rate (g s?1) depends on the input power related to the product of the energy controlling the production per filament times the number of filaments per second, for any given material. This non-thermal plasma process presents great potentialities for nano-technologies since it is performed at atmospheric pressure and can be used to reach size-dependent properties of nano-materials, without any gaseous precursor or solvent.

J.-P. Borra; N. Jidenko; J. Hou; A. Weber

2015-01-01T23:59:59.000Z

52

E-Print Network 3.0 - actinide metal complexes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

metal actinide complex halides: thermochemical and structural Summary: on the thermodynamics of the actinide halogeno-complexes with alkali metal ions is reviewed, with...

53

Selective Solid-Liquid Extraction of Lithium Halide Salts Using a Ditopic Macrobicyclic Receptor  

E-Print Network [OSTI]

pairs. The receptor can transport these salts from an aqueous phase through a liquid organic membrane and membrane transport, almost all reported efforts have focused on the transfer of lithium salts from this by binding the salts as contact ion pairs. Receptor 1 can also transport alkali metal halide salts out

Smith, Bradley D.

54

The optimization of interfaces in InAsSb/InGaAs strained-layer superlattices grown by metal-organic chemical vapor deposition  

SciTech Connect (OSTI)

We have prepared InAsSb/InGaAs strained-layer superlattice (SLS) semiconductors by metal-organic chemical vapor deposition (MOCVD) under a variety of conditions. Presence of an InGaAsSb interface layer is indicated by x-ray diffraction patterns. Optimized growth conditions involved the use of low pressure, short purge times, and no reactant flow during the purges. MOCVD was used to prepare an optically pumped, single heterostructure InAsSb/InGaAs SLS/InPSb laser which emitted at 3.9 {mu}m with a maximum operating temperature of approximately 100 K.

Biefeld, R.M.; Baucom, K.C.; Kurtz, S.R.

1993-12-31T23:59:59.000Z

55

Vapor phase modifiers for oxidative coupling  

DOE Patents [OSTI]

Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

Warren, B.K.

1991-12-17T23:59:59.000Z

56

InGaAs heterostructure formation in catalyst-free GaAs nanopillars by selective-area metal-organic vapor phase epitaxy  

SciTech Connect (OSTI)

We investigate axial GaAs/InGaAs/GaAs heterostructures embedded in GaAs nanopillars via catalyst-free selective-area metal-organic chemical vapor deposition. Structural characterization by transmission electron microscopy with energy dispersive x-ray spectroscopy (EDS) indicates formation of axial In{sub x}Ga{sub 1-x}As (x{approx}0.20) inserts with thicknesses from 36 to 220 nm with {+-}10% variation and graded Ga:In transitions controlled by In segregation. Using the heterointerfaces as markers, the vertical growth rate is determined to increase linearly during growth. Photoluminescence from 77 to 290 K and EDS suggest the presence of strain in the shortest inserts. This capability to control the formation of axial nanopillar heterostructures is crucial for optimized device integration.

Shapiro, J. N.; Lin, A.; Wong, P. S.; Scofield, A. C.; Tu, C.; Senanayake, P. N.; Mariani, G.; Liang, B. L.; Huffaker, D. L. [Department of Electrical Engineering and California Nano-Systems Institute, University of California at Los Angeles, Los Angeles, California 90095 (United States)

2010-12-13T23:59:59.000Z

57

Optimization of InAsSb/InGaAs strained-layer superlattice growth by metal-organic chemical vapor deposition for use in infrared emitters  

SciTech Connect (OSTI)

We have prepared InAsSb/InGaAs strained-layer superlattices (SLSs) by metal-organic chemical vapor deposition using a variety of growth conditions. Presence of an InGaAsSb interface layer was indicated by x-ray diffraction. This interface effect was minimized by optimizing the purge times, reactant flows, and growth conditions. The optimized growth conditions involved the use of low pressure, short purge times between the growth of the layers, and no reactant flow during the purges. Electron diffraction indicates that CuPt-type compositional ordering occurs in InAs{sub 1{minus}x}Sb{sub x} alloys and SLSs which explains an observed bandgap reduction from previously accepted alloy values.

Biefeld, R.M.; Baucom, K.C.; Follstaedt, D.M.; Kurtz, S.R.

1994-08-01T23:59:59.000Z

58

Epitaxial growth of CdTe thin film on cube-textured Ni by metal-organic chemical vapor deposition  

SciTech Connect (OSTI)

CdTe thin film has been grown by metalorganic chemical vapor deposition (MOCVD) on Ni(100) substrate. Using x-ray pole figure measurements we observed the epitaxial relationship of {111}CdTe// {001}Ni with [110]CdTe//[010]Ni and [112] CdTe//[100]Ni. The 12 diffraction peaks in the (111) pole figure of CdTe film and their relative positions with respect to the four peak positions in the (111) pole figure of Ni substrate are consistent with four equivalent orientational domains of CdTe with three to four superlattice match of about 0.7% in the [110] direction of CdTe and the [010] direction of Ni. The electron backscattered diffraction (EBSD) images show that the CdTe domains are 30 degrees orientated from each other.

GIARE, C [Rensselaer Polytechnic Institute (RPI); RAO, S [Rensselaer Polytechnic Institute (RPI); RILEY, M [Rensselaer Polytechnic Institute (RPI); CHEN, L [Rensselaer Polytechnic Institute (RPI); Goyal, Amit [ORNL; BHAT, I [Rensselaer Polytechnic Institute (RPI); LU, T [Rensselaer Polytechnic Institute (RPI); WANG, G [Rensselaer Polytechnic Institute (RPI)

2012-01-01T23:59:59.000Z

59

Interaction between (La, Sr)MnO3 cathode and Ni–Mo–Cr metallic interconnect with suppressed chromium vaporization for solid oxide fuel cells  

Science Journals Connector (OSTI)

Interaction between (La0.8Sr0.2)0.90MnO3 (LSM) cathode and newly developed Ni–Mo–Cr metallic interconnect is investigated at 900 °C under operation conditions of solid oxide fuel cells (SOFCs). The results show that chromium deposition on the LSM cathodes in the presence of Ni–Mo–Cr interconnect is remarkably reduced as compared to that in the presence of a conventional Fe–Cr metallic interconnect (RA446). In contact with the Ni–Mo-Cr interconnect the overpotential, ?, for the O2 reduction reaction on LSM cathode decreased from 529 to 111 mV during the 1200 min current passage at 200 mA/cm2. In contrast, ? increased from 464 to 561 mV for the reaction in the presence of a RA446 interconnect. The decrease in ? clearly indicates that chromium poisoning effect of the Ni–Mo–Cr interconnect is also significantly suppressed as compared to that with conventional Fe–Cr interconnect materials. The suppressed Cr deposition and poisoning effects observed on the LSM cathodes demonstrate promising potential of the Ni–Mo–Cr alloy as new interconnect materials with significant suppressed chromium vaporization and deposition for SOFCs.

Xinbing Chen; Bin Hua; Jian Pu; Jian Li; Lan Zhang; San Ping Jiang

2009-01-01T23:59:59.000Z

60

Faster Dissociation: Aryl Halide Radical Anions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Faster Dissociation: Measured Rates and Computed Effects on Barriers in Faster Dissociation: Measured Rates and Computed Effects on Barriers in Aryl Halide Radical Anions Norihiko Takeda, Pavel V. Poliakov, Andrew R. Cook, and John R. Miller J. Am. Chem. Soc. 126, 4301-4309 (2004). [Find paper at ACS Publications] Abstract: Carbon-halogen bond dissociation rates for a series of aryl halide radical anions (ArX-·: X = Cl, Br) in NMP were measured at room temperature by pulse radiolysis with 10-11 s time resolution. To obtain accurate dissociation rates, care was taken to measure and correct for competing decay channels. The observed rates correlated well with activation energies computed in the gas phase by density functional (DFT) calculations. The rates did not correlate well with electron affinities or dissociation energies obtained by the same computational methods, although such

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Studies of non-proportionality in alkali halide and strontium iodide scintillators using SLYNCI  

E-Print Network [OSTI]

in Alkali Halide and Strontium Iodide Scintillators Usingof europium doping level in strontium iodide. Directions offor several alkali halides, strontium iodide, and lanthanum

Ahle, Larry

2011-01-01T23:59:59.000Z

62

E-Print Network 3.0 - alkali halide crystals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

STUDIES IN ALKALI HALIDES Summary: of the alkali halides (KC1) the introduction of vacancies by thermal quenching of unirra- diated crystals has... ANNIHILATION STUDIES IN...

63

Vapor deposition of hardened niobium  

DOE Patents [OSTI]

A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

Blocher, Jr., John M. (Columbus, OH); Veigel, Neil D. (Columbus, OH); Landrigan, Richard B. (Columbus, OH)

1983-04-19T23:59:59.000Z

64

Gas-Phase Identity SN2 Reactions of Halide Anions and Methyl Halides with Retention of Configuration  

E-Print Network [OSTI]

Gas-Phase Identity SN2 Reactions of Halide Anions and Methyl Halides with Retention back-side and front-side SN2 reactions are found to involve the same ion-molecule complex (X-,,,H3CX of a front-side SN2 reaction with retention of configuration at saturated carbon. Analysis of our

Schlegel, H. Bernhard

65

Magnetic polarizations of electrons at dislocations in alkali halides  

E-Print Network [OSTI]

interval. 25 NAGNETIC POLARIZATIONS OF ELECTRONS AT DISLOCATIONS IN ALKALI HALIDES 1. INTRODUCTION. The new magnetic effects observed in our laboratory on a number of single crystals of alkali halides are thought to be caused by electrons trapped... on d1slocations. The magnet1c properties are perhaps more interesting as a bas1c contribution to the sc1ence of magnetism than to a knowledge of d. islocations 1n these very pure, optically clear, s1ngle crystals of alkal1 halides. The gross magnet...

McClurg, Gene Roark

2012-06-07T23:59:59.000Z

66

Alkylaluminum Halide Induced Reactions of Carbonyl Compounds with Unactivated Alkenes  

Science Journals Connector (OSTI)

Aldehydes, ketones and ?,?-unsaturated aldehydes and ketones undergo a wide variety of reactions with unactivated alkenes in the presence of alkylaluminum halide catalysts. Ene reactions, Diels-Alder reactions...

Barry B. Snider

1989-01-01T23:59:59.000Z

67

NREL Investigates Critical Properties of Perovskite Halides Solar...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organometallic halide perovskites (e.g., CH 3 NH 3 PbI 3 ) are a novel class of light- absorbing materials that have demon- strated exceptional progress in solar cell...

68

Explosive composition with group VIII metal nitroso halide getter  

DOE Patents [OSTI]

An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1,500 and 10,000 meters per second and a minor amount of a getter additive comprising a non-explosive compound or mixture of non-explosive compounds capable of chemically reacting with free radicals or ions under shock initiation conditions of 2,000 calories/cm.sup.2 or less of energy fluence.

Walker, Franklin E. (18 Shadow Oak Rd., Danville, CA 94526); Wasley, Richard J. (4290 Colgate Way, Livermore, CA 94550)

1982-01-01T23:59:59.000Z

69

Explosive composition with group VIII metal nitroso halide getter  

DOE Patents [OSTI]

An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1,500 and 10,000 meters per second and a minor amount of a getter additive comprising a non-explosive compound or mixture of non-explosive compounds capable of chemically reacting with free radicals or ions under shock initiation conditions of 2,000 calories/cm[sup 2] or less of energy fluence.

Walker, F.E.; Wasley, R.J.

1982-06-22T23:59:59.000Z

70

Project Profile: Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature Heat Transfer Fluids  

Broader source: Energy.gov [DOE]

The University of Arizona along with partners at Arizona State University and Georgia Institute of Technology, under the 2012 Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids funding opportunity, is investigating the use of halide salts with oxy-halide additives as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures greater than 800°C. By allowing higher temperature operation, CSP systems can achieve greater efficiencies and thereby reduce the overall system cost.

71

Vapor spill pipe monitor  

DOE Patents [OSTI]

The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

Bianchini, G.M.; McRae, T.G.

1983-06-23T23:59:59.000Z

72

Calibrated vapor generator source  

DOE Patents [OSTI]

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

1995-09-26T23:59:59.000Z

73

Photoinduced Giant Dielectric Constant in Lead Halide Perovskite Solar Cells  

Science Journals Connector (OSTI)

Perovskite solar cells have emerged as a major topic of research in photovoltaics because of the promising properties of the solution processed, low cost, and high efficiency solar cells for large-scale solar energy production. ... Illumination of the perovskite samples produces a significant increase of charge carrier density in the perovskite layer due to the high extinction coefficient of organic–inorganic lead halide perovskite. ... The effect of electron- and hole-selective contacts in the final cell performance of hybrid lead halide perovskite, CH3NH3PbI3, solar cells has been systematically analyzed by impedance spectroscopy. ...

Emilio J. Juarez-Perez; Rafael S. Sanchez; Laura Badia; Germá Garcia-Belmonte; Yong Soo Kang; Ivan Mora-Sero; Juan Bisquert

2014-06-23T23:59:59.000Z

74

TRANSMISSION ELECTRON MICROSCOPY OF WEAKLY DEFORMED ALKALI HALIDE CRYSTALS  

E-Print Network [OSTI]

377 TRANSMISSION ELECTRON MICROSCOPY OF WEAKLY DEFORMED ALKALI HALIDE CRYSTALS H. STRUNK Max'importance croissante du durcissement de la solution solide. Abstract. 2014 Transmission electron microscopy (TEM Abstracts 7j66 - 7 I' 1. Introduction. - It is only some years ago that transmission electron microscopy

Boyer, Edmond

75

Method for providing adhesion to a metal surface  

DOE Patents [OSTI]

A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

Harrah, L.A.; Allred, R.E.; Wilson, K.V. Jr.

1992-02-18T23:59:59.000Z

76

The Catalytic Conversion of d-Glucose to 5-Hydroxymethylfurfural in DMSO Using Metal Salts  

Science Journals Connector (OSTI)

A wide range of metal halides and triflates were examined for the conversion of d-glucose to HMF in DMSO. Chromium and aluminium salts were identified as the most promising catalysts. The effect of process variab...

C. B. Rasrendra; J. N. M. Soetedjo; I. G. B. N. Makertihartha…

2012-07-01T23:59:59.000Z

77

ARM Water Vapor IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ARM Water Vapor IOP The SGP CART site will host the third ARM water vapor IOP on September 18-October 8, 2000. The CART site is home to a powerful array of instruments capable of...

78

Synthesis and Characterization of Magnetic Nanowires Prepared by Chemical Vapor Deposition.  

E-Print Network [OSTI]

??Various metal silicide and germanide magnetic nanowires were synthesized using a home-built CVD [chemical vapor deposition] system. The morphology, composition, and magnetic properties of the… (more)

Tang, Siwei

2014-01-01T23:59:59.000Z

79

Summary of Substitution and Elimination Reactions of Alkyl Halides Polar protic solvent  

E-Print Network [OSTI]

will come from E2 and/or SN2, or there will be no reaction, depending upon the structure of the alkyl halide­X E2, SN2, E1/SN1 First, you need to know which products to expect from each mechanism. Second, you: 1) 1° halides will give SN2 unless the halide is hindered on the backside by branching

Walba, David

80

E-Print Network 3.0 - alkali halides irradiated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

U ET ASSOCIATIONS DE CENTRES COLORES ATOMIC HYDROGEN CENTRES IN IONIC CRYSTALS Summary: . Abstract. - Experimental and theoretical work on atomic hydrogen centres in alkali halides...

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature Heat Transfer Fluids  

Broader source: Energy.gov [DOE]

This fact sheet details a SunShot-funded solar project led by the University of Arizona to using ab initio computational modeling along with rapid material screening methods to identify halide salt mixtures with a melting point below 250°C that are stable at temperatures well above 800°C. This research has the potential to help concentrating solar power systems achieve greater efficiencies and reduce overall costs.

82

Vapor spill monitoring method  

DOE Patents [OSTI]

Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

1985-01-01T23:59:59.000Z

83

ARM - Water Vapor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Vapor Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global...

84

Apparatus and method for removing mercury vapor from a gas stream  

DOE Patents [OSTI]

A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

Ganesan, Kumar (Butte, MT)

2008-01-01T23:59:59.000Z

85

Oxide Film Aging on Alloy 22 in Halide Containing Solutions  

SciTech Connect (OSTI)

Passive and corrosion behaviors of Alloy 22 in chloride and fluoride containing solutions, changing the heat treatment of the alloy, the halide concentration and the pH of the solutions at 90 deg. C, was investigated. The study was implemented using electrochemical techniques, which included open circuit potential monitoring over time, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements carried out at open circuit and at passivity potentials. Corrosion rates obtained by EIS measurements after 24 h immersion in naturally aerated solutions were below 0.5 {mu}m/year. The corrosion rates were practically independent of solution pH, alloy heat treatment and halide ion nature and concentration. EIS low frequency resistance values increased with applied potential in the passive domain and with polarization time in pH 6 - 1 M NaCl at 90 deg. C. This effect was attributed to an increase in the oxide film thickness and oxide film aging. High frequency capacitance measurements indicated that passive oxide on Alloy 22 presented a double n-type/p-type semiconductor behavior in the passive potential range. (authors)

Rodriguez, Martin A.; Carranza, Ricardo M. [Dept. Materiales, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, Villa Maipu, 1650 (Argentina); Rebak, Raul B. [Lawrence Livermore National Laboratory, 7000 East Ave, L-631, Livermore, CA, 94550-9698 (United States)

2007-07-01T23:59:59.000Z

86

Ionized physical vapor deposition of integrated circuit interconnects* J. Hopwood,a)  

E-Print Network [OSTI]

alloy silicide gate level and several metal-SiO2 interlayer dielectric ILD levels joined together metal layers. By the year 2007 it is predicted that logic circuits will use 6 to 7 interconnected metal physical vapor deposition I-PVD . The technique economically creates a unidirectional flux of metal which

87

Resistivity measurements of halide-salt/MgO separators for thermal cells  

SciTech Connect (OSTI)

Resistivities of 20 compositions of halide-salt/MgO mixtures (various selections and percentages of LiF, LiCl, LiBr, KCl, KBr, CsBr, and MgO) to be used in Li-alloy/metal sulfide cells have been measured at temperatures between the melting point of a particular mixture and 500{degrees}C. The resistivities were determined with cold-pressed electrolyte-binder pellets by using a special cell and DC measuring technique. Temperature, salt composition, and MgO content were found to have a strong influence on resistivity. These factors are listed in decreasing order of the magnitude of the effect. The fabrication density (porosity) of the pellet also has some effect on resistivity. These measured resistivities provide a data base to select optimum compositions of electrolyte-binder pellets for LiSi/FeS{sub 2} thermal batteries and to calculate area-specific resistances of these components for battery modeling and optimization. 5 refs., 7 figs.

Redey, L.; McParland, M. (Argonne National Lab., IL (USA)); Guidotti, R. (Sandia National Labs., Albuquerque, NM (USA))

1990-01-01T23:59:59.000Z

88

Recombination Study of Combined Halides (Cl, Br, I) Perovskite Solar Cells  

Science Journals Connector (OSTI)

Recombination Study of Combined Halides (Cl, Br, I) Perovskite Solar Cells ... We report on the preparation of a series of solution-processed perovskite solar cells based on methylammonium (MA) lead halide derivatives, MAPbX3, which show tunable optical properties depending on the nature and ratio of the halides employed (X = Cl, Br, and I). ... These results highlight the crucial role of the charge-recombination processes on the performance of the perovskite solar cells and pave the way for further progress on this field. ...

Belen Suarez; Victoria Gonzalez-Pedro; Teresa S. Ripolles; Rafael S. Sanchez; Luis Otero; Ivan Mora-Sero

2014-04-17T23:59:59.000Z

89

Fabrication of alkali halide UV photocathodes by pulsed laser deposition  

SciTech Connect (OSTI)

A technique has been proposed for the fabrication of atmospheric corrosion resistant alkali halide UV photocathodes by pulsed laser deposition. We produced photocathodes with a highly homogeneous photoemissive layer well-adherent to the substrate. The photocathodes were mounted in a vacuum photodiode, and a tungsten grid was used as an anode. Using pulsed UV lasers, we carried out experiments aimed at evaluating the quantum efficiency of the photocathodes. With a dc voltage applied between the photocathode and anode grid, we measured a shunt signal proportional to the total charge emitted by the cathode exposed to UV laser light. The proposed deposition technique enables one to produce photocathodes with photoemissive layers highly uniform in quantum efficiency, which is its main advantage over thin film growth by resistive evaporation. (laser technologies)

Brendel', V M; Bukin, V V; Garnov, Sergei V; Bagdasarov, V Kh; Denisov, N N; Garanin, Sergey G; Terekhin, V A; Trutnev, Yurii A

2012-12-31T23:59:59.000Z

90

Gasoline vapor recovery  

SciTech Connect (OSTI)

In a gasoline distribution network wherein gasoline is drawn from a gasoline storage tank and pumped into individual vehicles and wherein the gasoline storage tank is refilled periodically from a gasoline tanker truck, a method of recovering liquid gasoline from gasoline vapor that collects in the headspace of the gasoline storage tank as the liquid gasoline is drawn therefrom, said method comprising the steps of: (a) providing a source of inert gas; (b) introducing inert gas into the gasoline storage tank as liquid gasoline is drawn therefrom so that liquid gasoline drawn from the tank is displaced by inert gas and gasoline vapor mixes with the inert gas in the headspace of the tank; (c) collecting the inert gas/gasoline vapor mixture from the headspace of the gasoline storage tank as the tank is refilled from a gasoline tanker truck; (d) cooling the inert gas/gasoline vapor mixture to a temperature sufficient to condense the gasoline vapor in the mixture to liquid gasoline but not sufficient to liquify the inert gas in the mixture; (e) separating the condensed liquid gasoline from the inert gas; and delivering the condensed liquid gasoline to a remote location for subsequent use.

Lievens, G.; Tiberi, T.P.

1993-06-22T23:59:59.000Z

91

Methods for synthesizing alane without the formation of adducts and free of halides  

DOE Patents [OSTI]

A process is provided to synthesize an alane without the formation of alane adducts as a precursor. The resulting product is a crystallized .alpha.-alane and is a highly stable product and is free of halides.

Zidan, Ragaiy; Knight, Douglas A; Dinh, Long V

2013-02-19T23:59:59.000Z

92

Electrolyte vapor condenser  

DOE Patents [OSTI]

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

1983-02-08T23:59:59.000Z

93

Electrolyte vapor condenser  

DOE Patents [OSTI]

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

Sederquist, Richard A. (Newington, CT); Szydlowski, Donald F. (East Hartford, CT); Sawyer, Richard D. (Canton, CT)

1983-01-01T23:59:59.000Z

94

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

1986-01-01T23:59:59.000Z

95

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA); Zymboly, Gregory E. (Penn Hills Township, Allegheny County, PA)

1985-01-01T23:59:59.000Z

96

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

1987-01-01T23:59:59.000Z

97

Organic vapor jet printing system  

SciTech Connect (OSTI)

An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

Forrest, Stephen R

2012-10-23T23:59:59.000Z

98

Precision micro drilling with copper vapor lasers  

SciTech Connect (OSTI)

The authors have developed a copper vapor laser based micro machining system using advanced beam quality control and precision wavefront tilting technologies. Micro drilling has been demonstrated through percussion drilling and trepanning using this system. With a 30 W copper vapor laser running at multi-kHz pulse repetition frequency, straight parallel holes with size varying from 500 microns to less than 25 microns and with aspect ratio up to 1:40 have been consistently drilled on a variety of metals with good quality. For precision trepanned holes, the hole-to-hole size variation is typically within 1% of its diameter. Hole entrance and exit are both well defined with dimension error less than a few microns. Materialography of sectioned holes shows little (sub-micron scale) recast layer and heat affected zone with surface roughness within 1--2 microns.

Chang, J.J.; Martinez, M.W.; Warner, B.E.; Dragon, E.P.; Huete, G.; Solarski, M.E.

1994-09-02T23:59:59.000Z

99

Rare-earth neutral metal injection into an electron beam ion trap plasma  

SciTech Connect (OSTI)

We have designed and implemented a neutral metal vapor injector on the SuperEBIT high-energy electron beam ion trap at the Lawrence Livermore National Laboratory. A horizontally directed vapor of a europium metal is created using a thermal evaporation technique. The metal vapor is then spatially collimated prior to injection into the trap. The source's form and quantity constraints are significantly reduced making plasmas out of metal with vapor pressures ?10{sup ?7} Torr at ?1000?°C more obtainable. A long pulsed or constant feed metal vapor injection method adds new flexibility by varying the timing of injection and rate of material being introduced into the trap.

Magee, E. W., E-mail: magee1@llnl.gov; Beiersdorfer, P.; Brown, G. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hell, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Dr. Remeis-Sternwarte and ECAP, Universität Erlangen-Nürnberg, 96049 Bamberg (Germany)

2014-11-15T23:59:59.000Z

100

Mercury Vapor | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor Mercury Vapor Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Mercury Vapor Details Activities (23) Areas (23) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Anomalously high concentrations can indicate high permeability or conduit for fluid flow Hydrological: Field wide soil sampling can generate a geometrical approximation of fluid circulation Thermal: High concentration in soils can be indicative of active hydrothermal activity Dictionary.png Mercury Vapor: Mercury is discharged as a highly volatile vapor during hydrothermal

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Self-Limiting Chemical Vapor Deposition Growth of Monolayer Graphene from Ethanol  

E-Print Network [OSTI]

carbide,8 to chemical vapor deposition (CVD) of hydrocarbon precursors on transition metals,9-13 economic up to wafer scale,14,15 nickel and copper are the two most commonly used metal substrates. DueC) restricts the growth of graphene to the metal surface.12,17 The uniformity and high quality of the resultant

Maruyama, Shigeo

102

Stratified vapor generator  

DOE Patents [OSTI]

A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

2008-05-20T23:59:59.000Z

103

Vapor Barriers or Vapor Diffusion Retarders | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Home Air Sealing for New Home Construction Insulation Types of Insulation Insulation and Air Sealing Products and Services External Resources Find a Local AirVapor Barrier...

104

Optical properties of lanthanide-containing halide-modified zinc tellurite glasses  

SciTech Connect (OSTI)

As part of an ongoing investigation to characterize the properties and structure of Zn halide-Te oxide glasses, we report preliminary measurements of the optical properties of several Nd- and Er-doped tellurites. Measurements include fluorescence lifetimes and estimates of the theoretical radiative lifetimes (from traditional Judd-Ofelt analysis of optical absorption spectra) as well as phonon sideband studies sensitive to vibrational characteristics near the rare earth ion. Response of these optical features to the substitution of alternative halides is examined.

Sidebottom, D.L.; Hruschka, M.A. [New Mexico Univ., Albuquerque, NM (United States); Potter, B.G.; Brow, R.K.; Hudgens, J.J. [Sandia National Labs., Albuquerque, NM (United States)

1996-12-31T23:59:59.000Z

105

Hybrid Vapor Compression Adsorption System: Thermal Storage Using Hybrid Vapor Compression Adsorption System  

SciTech Connect (OSTI)

HEATS Project: UTRC is developing a new climate-control system for EVs that uses a hybrid vapor compression adsorption system with thermal energy storage. The targeted, closed system will use energy during the battery-charging step to recharge the thermal storage, and it will use minimal power to provide cooling or heating to the cabin during a drive cycle. The team will use a unique approach of absorbing a refrigerant on a metal salt, which will create a lightweight, high-energy-density refrigerant. This unique working pair can operate indefinitely as a traditional vapor compression heat pump using electrical energy, if desired. The project will deliver a hot-and-cold battery that provides comfort to the passengers using minimal power, substantially extending the driving range of EVs.

None

2012-01-04T23:59:59.000Z

106

Growth of manganese filled carbon nanofibers in the vapor phase  

Science Journals Connector (OSTI)

We report the vapor phase growth of partially filled graphitic fibers, 20-30 nm in diameter and up to a micron in length, during a manganese catalyzed carbon electric arc discharge. The fiber morphology resembles that of catalytic chemical vapor deposited carbon filaments but the inside hollow contains intermittent precipitates and continuous filling of Mn that at times occupy >50% of fiber lengths. Transmission electron microscopy and electron energy loss line spectra show that the fillings form as solid cores and may correspond to pure metal.

P. M. Ajayan; C. Colliex; J. M. Lambert; P. Bernier; L. Barbedette; M. Tence; O. Stephan

1994-03-14T23:59:59.000Z

107

Hydrogen Cars and Water Vapor  

E-Print Network [OSTI]

. This cycle is currently under way with hydrogen fuel cells. As fuel cell cars are suggested as a solutionHydrogen Cars and Water Vapor D.W.KEITHANDA.E.FARRELL'S POLICY FORUM "Rethinking hydrogen cars" (18 misidentified as "zero-emissions vehicles." Fuel cell vehicles emit water vapor. A global fleet could have

Colorado at Boulder, University of

108

Fuel vapor control device  

SciTech Connect (OSTI)

A fuel vapor control device is described having a valve opening and closing a passage connecting a carburetor and a charcoal canister according to a predetermined temperature. A first coil spring formed by a ''shape memory effect'' alloy is provided to urge the valve to open the passage when the temperature is high. A second coil spring urges the valve to close the passage. A solenoid is provided to urge an armature against the valve to close the passage against the force of the first coil spring when the engine is running. The solenoid heats the first coil spring to generate a spring force therein when the engine is running. When the engine is turned off, the solenoid is deactivated, and the force of the first spring overcomes the force of the second spring to open the passage until such time as the temperature of the first spring drops below the predetermined temperature.

Ota, I.; Nishimura, Y.; Nishio, S.; Yogo, K.

1987-10-20T23:59:59.000Z

109

The Dust Settles on Water Vapor Feedback  

Science Journals Connector (OSTI)

...To understand water vapor feedback...shifts in the atmospheric circulation...caused a positive water vapor feedback...temperature. Condensation, evaporation...shifts in the atmospheric circulation...caused a positive water vapor feedback...temperature. Condensation, evaporation...

Anthony D. Del Genio

2002-04-26T23:59:59.000Z

110

Transport of Alkali Halides through a Liquid Organic Membrane Containing a Ditopic Salt-Binding Receptor  

E-Print Network [OSTI]

in the solid state as contact ion pairs. Transport experiments, using a supported liquid membrane and high saltTransport of Alkali Halides through a Liquid Organic Membrane Containing a Ditopic Salt and anion receptors. All transport systems exhibit the same qualitative order of ion selectivity; that is

Smith, Bradley D.

111

Csp3–Csp3 Homocoupling Reaction of Benzyl Halides Catalyzed by Rhodium  

Science Journals Connector (OSTI)

A highly reactive alkylrhodium complex was formed from Me2Zn and RhCl(PPh3)3 and effectively catalyzed a Csp3–Csp3 homocoupling reaction of benzyl halides. A Csp3–Csp3 coupling reaction using Rh catalyst has not been reported up to now. The reaction ...

Kazuyuki Sato; Yuichi Inoue; Tomohisa Mori; Atsushi Sakaue; Atsushi Tarui; Masaaki Omote; Itsumaro Kumadaki; Akira Ando

2014-06-30T23:59:59.000Z

112

Low pressure vinylation of aryl and vinyl halides via HeckMizoroki reactions using ethylene  

E-Print Network [OSTI]

Low pressure vinylation of aryl and vinyl halides via Heck­Mizoroki reactions using ethylene Craig with ethylene under ambient pressure (15­30 psi) to give the corresponding vinylarenes. The reactions work of ethylene) of functionalized vinylarenes and 1,3-di- enes.4 When fully developed, we hope, many

RajanBabu, T. V. "Babu"

113

Dramatic Acceleration of the Menschutkin Reaction and Distortion of Halide Leaving-Group Order  

E-Print Network [OSTI]

-butylbenzyl halides are 4-t-BuBnCl (62 000 M) > 4-t-BuBnBr (2200 M) > 4-t-BuBnI (35 M); thus, the free energy.; Sola, M. H. In Progress in Physical Organic Chemistry; Taft, R. W., Ed.; Wiley: New York, 1993; Vol. 19

Smith, Bradley D.

114

Whitesides et al. f Reaction ctfAlkyl Halides with Magnesiunt Mechanismof Formationof GrignardReagents.  

E-Print Network [OSTI]

carbanionsand carbonium ionsare not intermediates,and tliat the transition-itut. structuredoesnot resemblean SN2.rnagncsiumatom at the mctal surface(or possibly in solution) rrrrghtdisplacehelidefrotncarbonin an SN2-likc rcuctionor inrcrlWhitesides et al. f Reaction ctfAlkyl Halides with Magnesiunt Mechanismof Formationof Grignard

Prentiss, Mara

115

Category:Mercury Vapor | Open Energy Information  

Open Energy Info (EERE)

search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Mercury Vapor page? For detailed information on Mercury Vapor as exploration techniques,...

116

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, M.; Wai, C.M.; Nagy, Z.

1983-08-15T23:59:59.000Z

117

Extraction of trace metals from fly ash  

DOE Patents [OSTI]

A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

1984-01-01T23:59:59.000Z

118

Fabrication of large-volume, low-cost ceramic lanthanum halide scintillators for gamma ray detection : final report for DHS/DNDO/TRDD project TA-01-SL01.  

SciTech Connect (OSTI)

This project uses advanced ceramic processes to fabricate large, optical-quality, polycrystalline lanthanum halide scintillators to replace small single crystals produced by the conventional Bridgman growth method. The new approach not only removes the size constraint imposed by the growth method, but also offers the potential advantages of both reducing manufacturing cost and increasing production rate. The project goal is to fabricate dense lanthanum halide ceramics with a preferred crystal orientation by applying texture engineering and solid-state conversion to reduce the thermal mechanical stress in the ceramic and minimize scintillation light scattering at grain boundaries. Ultimately, this method could deliver the sought-after high sensitivity and <3% energy resolution at 662 keV of lanthanum halide scintillators and unleash their full potential for advanced gamma ray detection, enabling rapid identification of radioactive materials in a variety of practical applications. This report documents processing details from powder synthesis, seed particle growth, to final densification and texture development of cerium doped lanthanum bromide (LaBr{sub 3}:Ce{sup +3}) ceramics. This investigation demonstrated that: (1) A rapid, flexible, cost efficient synthesis method of anhydrous lanthanum halides and their solid solutions was developed. Several batches of ultrafine LaBr{sub 3}:Ce{sup +3} powder, free of oxyhalide, were produced by a rigorously controlled process. (2) Micron size ({approx} 5 {micro}m), platelet shape LaBr{sub 3} seed particles of high purity can be synthesized by a vapor phase transport process. (3) High aspect-ratio seed particles can be effectively aligned in the shear direction in the ceramic matrix, using a rotational shear-forming process. (4) Small size, highly translucent LaBr{sub 3} (0.25-inch diameter, 0.08-inch thick) samples were successfully fabricated by the equal channel angular consolidation process. (5) Large size, high density, translucent LaBr{sub 3} ceramics samples (3-inch diameter, > 1/8-inch thick) were fabricated by hot pressing, demonstrating the superior manufacturability of the ceramic approach over single crystal growth methods in terms of size capability and cost. (6) Despite all these advances, evidence has shown that LaBr{sub 3} is thermally unstable at temperatures required for the densification process. This is particularly true for material near the surface where lattice defects and color centers can be created as bromine becomes volatile at high temperatures. Consequently, after densification these samples made using chemically prepared ultrafine powders turned black. An additional thermal treatment in a flowing bromine condition proved able to reduce the darkness of the surface layer for these densified samples. These observations demonstrated that although finer ceramic powders are desirable for densification due to a stronger driving force from their large surface areas, the same desirable factor can lead to lattice defects and color centers when these powders are densified at higher temperatures where material near the surface becomes thermally unstable.

Boyle, Timothy J.; Ottley, Leigh Anna M.; Yang, Pin; Chen, Ching-Fong; Sanchez, Margaret R.; Bell, Nelson Simmons

2008-10-01T23:59:59.000Z

119

Adsorbate-induced corrosion: anodic dissolution of palladium induced by chemisorbed iodine in halide-free acid solutions  

E-Print Network [OSTI]

ADSORBATE-INDUCED CORROSION: ANODIC DISSOLUTION OF PALLADIUM INDUCED BY CHEMISORBED IODINE IN HALIDE-FREE ACID SOLUTIONS A Thesis JANEMARIE A. SCHIMPF Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Chemistry ADSORBATE-INDUCED CORROSION: ANODIC DISSOLUTION OF PALLADIUM INDUCED BY CHEMISORBED IODINE IN HALIDE-FREE ACID SOLUTIONS A Thesis JANEMARIE A. SCHIMPF Approved...

Schimpf, Janemarie A

2012-06-07T23:59:59.000Z

120

Chemical vapor deposition sciences  

SciTech Connect (OSTI)

Chemical vapor deposition (CVD) is a widely used method for depositing thin films of a variety of materials. Applications of CVD range from the fabrication of microelectronic devices to the deposition of protective coatings. New CVD processes are increasingly complex, with stringent requirements that make it more difficult to commercialize them in a timely fashion. However, a clear understanding of the fundamental science underlying a CVD process, as expressed through computer models, can substantially shorten the time required for reactor and process development. Research scientists at Sandia use a wide range of experimental and theoretical techniques for investigating the science of CVD. Experimental tools include optical probes for gas-phase and surface processes, a range of surface analytic techniques, molecular beam methods for gas/surface kinetics, flow visualization techniques and state-of-the-art crystal growth reactors. The theoretical strategy uses a structured approach to describe the coupled gas-phase and gas-surface chemistry, fluid dynamics, heat and mass transfer of a CVD process. The software used to describe chemical reaction mechanisms is easily adapted to codes that model a variety of reactor geometries. Carefully chosen experiments provide critical information on the chemical species, gas temperatures and flows that are necessary for model development and validation. This brochure provides basic information on Sandia`s capabilities in the physical and chemical sciences of CVD and related materials processing technologies. It contains a brief description of the major scientific and technical capabilities of the CVD staff and facilities, and a brief discussion of the approach that the staff uses to advance the scientific understanding of CVD processes.

NONE

1992-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance by Correlation Gas  

E-Print Network [OSTI]

by Correlation Gas Chromatography Chase Gobble, Nigam Rath, and James Chickos* Department of Chemistry Information ABSTRACT: Vapor pressures, vaporization, and sublimation enthalpies of several pharmaceuticals and boiling temperatures when available. Sublimation enthalpies and vapor pressures are also evaluated for 1

Chickos, James S.

122

Enhancing the Sensitivity of Chemical Sensors for Chlorinated Hydrocarbons in Water by the Use of Tapered Silver Halide Fibers and Tunable Diode Lasers  

Science Journals Connector (OSTI)

Tapered silver halide fibers were used for the first time for high-sensitivity fiber evanescent wave spectroscopic (FEWS) measurements of chlorinated hydrocarbons (CHCs) in water at...

Göbel, Roman; Krska, Rudolf; Kellner, Robert; Kastner, Joachim; Lambrecht, Armin; Tacke, Maurus; Katzir, Abraham

1995-01-01T23:59:59.000Z

123

VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA  

E-Print Network [OSTI]

.B. Department of Chemistry, Moscow State University, Moscow, 119899, Russia Bonnell D.W., Hastie J.W. National temperature chemistry situations, vapor pressures are typically less than 100 kPa. The molar volume is p = 101325 Pa). The subscript trs denotes that the changeisfor a transition, typically sublimation

Rudnyi, Evgenii B.

124

Vacuum vapor deposition gun assembly  

DOE Patents [OSTI]

A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

Zeren, Joseph D. (Boulder, CO)

1985-01-01T23:59:59.000Z

125

LNG Vaporizer Utilizing Vacuum Steam Condensing  

Science Journals Connector (OSTI)

This report concerns the field test results of a new type of peak-shaving LNG vaporizer (VSV) whose heat source is ... heat of vacuum steam to vaporize and superheat LNG within heat transfer tubes. Prior to the.....

Y. Miyata; M. Hanamure; H. Kujirai; Y. Sato…

1991-01-01T23:59:59.000Z

126

Running-Film Vaporizer for LNG  

Science Journals Connector (OSTI)

Advances in welding technology and steel fabrication techniques have permitted the development of a new concept in cryogenic vaporizers—the running-film plate vaporizer. Although similar in heat transfer philosop...

H. H. West; G. L. Puckett

1975-01-01T23:59:59.000Z

127

Vapor Retarder Classification- Building America Top Innovation  

Broader source: Energy.gov [DOE]

This Building America Innovations profile describes research in vapor retarders. Since 2006 the IRC has permitted Class III vapor retarders like latex paint (see list above) in all climate zones under certain conditions thanks to research by Building America teams.

128

Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing  

SciTech Connect (OSTI)

An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500{degree}C. The method comprises positioning a solid Li-Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

Gay, E.C.

1993-12-23T23:59:59.000Z

129

Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing  

DOE Patents [OSTI]

An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500.degree. C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

Gay, Eddie C. (Park Forest, IL)

1995-01-01T23:59:59.000Z

130

Vapor Pressures and Heats of Vaporization of Primary Coal Tars  

Office of Scientific and Technical Information (OSTI)

/ PC92544-18 / PC92544-18 VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS FINAL REPORT Grant Dates: August, 1992 - November, 1996 Principal Authors: Eric M. Suuberg (PI) and Vahur Oja Report Submitted: April, 1997 Revised: July, 1997 Grant Number: DE-FG22-92PC92544 Report Submitted by: ERIC M. SUUBERG DIVISION OF ENGINEERING BROWN UNIVERSITY PROVIDENCE, RI 02912 TEL. (401) 863-1420 Prepared For: U. S. DEPT. OF ENERGY FEDERAL ENERGY TECHNOLOGY CENTER P.O. BOX 10940 PITTSBURGH, PA 15236 DR. KAMALENDU DAS, FETC, MORGANTOWN , WV TECHNICAL PROJECT OFFICER "US/DOE Patent Clearance is not required prior to the publication of this document" ii United States Government Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any

131

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents [OSTI]

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

1989-01-01T23:59:59.000Z

132

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents [OSTI]

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Riley, B.; Szreders, B.E.

1988-04-26T23:59:59.000Z

133

Nucleophilic vinylic substitutions of (Z)-(2-aroyloxyvinyl)phenyl-?3-iodanes with tetrabutylammonium halides: vinylic SN2 reactions and ligand coupling on iodine(III)  

Science Journals Connector (OSTI)

Treatment of (Z)-(?-benzoyloxyvinyl)phenyl-?3-iodanes, readily prepared from ethynyl(phenyl)(tetrafluoroborato)-?3-iodane via stereoselective Michael-type addition of benzoic acids in methanol in the presence of sodium benzoates, with tetrabutylammonium halides in THF at 65 °C results in a vinylic SN2 reaction to give the inverted (E)-?-benzoyloxyvinyl halides in high yields.

Masahito Ochiai; Yoshio Nishi; Masaya Hirobe

2005-01-01T23:59:59.000Z

134

Advances in the growth of alkaline-earth halide single crystals for scintillator detectors  

SciTech Connect (OSTI)

Alkaline-earth scintillators such as strontium iodide and other alkaline-earth halides activated with divalent europium represent some of the most efficient and highest energy resolution scintillators for use as gamma-ray detectors in a wide range of applications. These applications include the areas of nuclear nonproliferation, homeland security, the detection of undeclared nuclear material, nuclear physics and materials science, medical diagnostics, space physics, high energy physics, and radiation monitoring systems for first responders, police, and fire/rescue personnel. Recent advances in the growth of large single crystals of these scintillator materials hold the promise of higher crystal yields and significantly lower detector production costs. In the present work, we describe new processing protocols that, when combined with our molten salt filtration methods, have led to advances in achieving a significant reduction of cracking effects during the growth of single crystals of SrI2:Eu2+. In particular, we have found that extended pumping on the molten crystal-growth charge under vacuum for time periods extending up to 48 hours is generally beneficial in compensating for variations in the alkaline-earth halide purity and stoichiometry of the materials as initially supplied by commercial sources. These melt-pumping and processing techniques are now being applied to the purification of CaI2:Eu2+ and some mixed-anion europium-doped alkaline-earth halides prior to single-crystal growth by means of the vertical Bridgman technique. The results of initial studies of the effects of aliovalent doping of SrI2:Eu2+ on the scintillation characteristics of this material are also described.

Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Kolopus, James A [ORNL; Neal, John S [ORNL; Cherepy, Nerine [Lawrence Livermore National Laboratory (LLNL); Payne, Stephen A. [Lawrence Livermore National Laboratory (LLNL); Beck, P [Lawrence Livermore National Laboratory (LLNL); Burger, Arnold [Fisk University, Nashville; Rowe, E [Fisk University, Nashville; Bhattacharya, P. [Fisk University, Nashville

2014-01-01T23:59:59.000Z

135

Specific Mass Estimates for A Vapor Core Reactor With MHD  

SciTech Connect (OSTI)

This study investigated the development of a system concept for space power generation and nuclear electric propulsion based on a vapor core reactor (VCR) with magnetohydrodynamic (MHD) power conversion system, coupled to a magnetoplasma-dynamic (MPD) thruster. The VCR is a liquid-vapor core reactor concept operating with metallic uranium or uranium tetrafluoride (UF{sub 4}) vapor as the fissioning fuel and alkali metals or their fluorides as working fluid in a closed Rankine cycle with MHD energy conversion. Gaseous and liquid-vapor core reactors can potentially provide the highest reactor and cycle temperature among all existing or proposed fission reactor designs. This unique feature makes this reactor concept a very natural and attractive candidate for very high power (10 to 1000 MWe) and low specific mass (0.4 to 5 kg/kWe) nuclear electric propulsion (NEP) applications since the MHD output could be coupled with minimal power conditioning to MPD thrusters or other types of thruster for producing thrust at very high specific impulse (I{sub sp} 1500 to 10,000 s). The exceptional specific mass performance of an optimized VCRMHD- NEP system could lead to a dramatic reduction in the cost and duration of manned or robotic interplanetary as well as interstellar missions. The VCR-MHD-NEP system could enable very efficient Mars cargo transfers or short (<8 month) Mars round trips with less initial mass in low Earth orbit (IMLEO). The system could also enable highly efficient lunar cargo transfer and rapid missions to other destinations throughout the solar system. (authors)

Knight, Travis; Smith, Blair; Anghaie, Samim [Innovative Nuclear Space Power and Propulsion Institute (INSPI), PO Box 116502, University of Florida, Gainesville, FL 32611-6502 (United States)

2002-07-01T23:59:59.000Z

136

Means and method for vapor generation  

DOE Patents [OSTI]

A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid--starting as "feedwater" heating where no vapors are present, progressing to "nucleate" heating where vaporization begins and some vapors are present, and concluding with "film" heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10-30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

Carlson, Larry W. (Oswego, IL)

1984-01-01T23:59:59.000Z

137

An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes  

E-Print Network [OSTI]

An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes M Growth of carbon nanotubes during transition-metal particles catalytically-assisted thermal decomposition of various nanotube surface and edge reactions (e.g. adsorption of hydrocarbons and hydrogen onto the surface

Grujicic, Mica

138

Patterned growth of single-walled carbon nanotube arrays from a vapor-deposited Fe catalyst  

E-Print Network [OSTI]

Patterned growth of single-walled carbon nanotube arrays from a vapor-deposited Fe catalyst H. B deposition using low-coverage vacuum-deposited iron as a catalyst. Ordered arrays of suspended nanotubes constructed directly on contacting metal electrodes of Pt/Cr patterned with catalysts. Patterning with solid

Golovchenko, Jene A.

139

Formation of Nickel Silicide from Direct-Liquid-Injection Chemical-Vapor-Deposited Nickel Nitride Films  

E-Print Network [OSTI]

. Published April 28, 2010. Metal silicides such as TiSi2 and CoSi2 have been commonly used as the contactsFormation of Nickel Silicide from Direct-Liquid-Injection Chemical-Vapor-Deposited Nickel Nitride as the intermediate for subsequent conversion into nickel silicide NiSi , which is a key material for source, drain

140

Understanding the effect of halide poisoning in CO oxidation over Au/TiO[subscript 2  

SciTech Connect (OSTI)

The effect of halide poisoning of Au/TiO{sub 2} catalysts in low temperature CO oxidation was investigated using bromide as the poison and a combination of X-ray absorption spectroscopy (XANES and EXAFS), quantitative CO adsorption, and catalytic measurements. It was found that halide prevented full reduction of cationic Au by displacing oxyhydroxy ligands and remaining bound to Au during low temperature reduction, causing a reduction in catalytic activity. On reduced Au samples, bromide (likely as NaBr molecule) was preferentially adsorbed on Au and not on TiO{sub 2}, and suppressed both the adsorption of CO and the catalytic activity. At low Br contents, each adsorbed Br suppressed adsorption of three CO, suggesting that Br was adsorbed on three-fold sites but the effect decreased with increasing Br content possibly due to crowding of adsorbed Br. When 5--10% of the Au was bound to Br, the catalytic activity was completely blocked, although {approx}35% of the original CO adsorption capacity remained. The data suggest that not all CO adsorption sites are catalytic active sites, and are consistent with the perimeter Au atoms at/near the particle-support interface (perimeter) being active sites.

Oxford, S.M.; Henao, J.D.; Yang, J.H.; Kung, M.C.; Kung, H.H. (NWU)

2008-07-08T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Non-Vapor Compression HVAC Technologies Report  

Broader source: Energy.gov [DOE]

While vapor-compression technologies have served heating, ventilation, and air-conditioning (HVAC) needs very effectively, and have been the dominant HVAC technology for close to 100 years, the conventional refrigerants used in vapor-compression equipment contribute to global climate change when released to the atmosphere. The Building Technologies Office is evaluating low-global warming potential (GWP) alternatives to vapor-compression technologies.

142

Ambient-temperature superconductor symetrical metal-dihalide bis-(ethylenedithio)-tetrathiafulvalene compounds  

DOE Patents [OSTI]

A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K. which is high for organic superconductors.

Williams, Jack M. (Downers Grove, IL); Wang, Hsien-Hau (Willowbrook, IL); Beno, Mark A. (Woodridge, IL)

1987-01-01T23:59:59.000Z

143

Mercury Vapor (Kooten, 1987) | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor (Kooten, 1987) Mercury Vapor (Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor (Kooten, 1987) Exploration Activity Details Location Unspecified Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes Surface soil-mercury surveys are an inexpensive and useful exploration tool for geothermal resources. ---- Surface geochemical surveys for mercury were conducted in 16 areas in 1979-1981 by ARCO Oil and Gas Company as part of its geothermal evaluation program. Three techniques used together have proved satisfactory in evaluating surface mercury data. These are contouring, histograms and cumulative frequency plots of the data. Contouring geochemical data and constructing histograms are standard

144

Sewage sludge dewatering using flowing liquid metals  

DOE Patents [OSTI]

A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

Carlson, Larry W. (Oswego, IL)

1986-01-01T23:59:59.000Z

145

Near real time vapor detection and enhancement using aerosol adsorption  

SciTech Connect (OSTI)

A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

Novick, Vincent J.; Johnson, Stanley A.

1997-12-01T23:59:59.000Z

146

Near real time vapor detection and enhancement using aerosol adsorption  

DOE Patents [OSTI]

A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

Novick, V.J.; Johnson, S.A.

1999-08-03T23:59:59.000Z

147

Near real time vapor detection and enhancement using aerosol adsorption  

DOE Patents [OSTI]

A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

Novick, Vincent J. (Downers Grove, IL); Johnson, Stanley A. (Countryside, IL)

1999-01-01T23:59:59.000Z

148

G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product  

SciTech Connect (OSTI)

The G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) value-added product (VAP) computes precipitable water vapor using neural network techniques from data measured by the GVR. The GVR reports time-series measurements of brightness temperatures for four channels located at 183.3 ± 1, 3, 7, and 14 GHz.

Koontz, A; Cadeddu, M

2012-12-05T23:59:59.000Z

149

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 9 HigH Permeability ternary Palladium alloy membranes witH imProved sulfur and Halide tolerance Description A critical step in the transition to the hydrogen economy is the separation of hydrogen from coal gasification gases (syngas) or methane. This is typically accomplished through membrane separation. Past research has shown that palladium (Pd) alloys possess great potential as robust and economical membranes. However, the search for the optimal binary or ternary alloys is an involved and costly process due to the immense number of alloy variations that could be prepared and tested. Recent modeling work at Georgia Institute of Technology using density functional theory (DFT) identified several promising ternary alloy compositions with improved

150

Quantitative organic vapor-particle sampler  

DOE Patents [OSTI]

A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

1998-01-01T23:59:59.000Z

151

LNG fire and vapor control system technologies  

SciTech Connect (OSTI)

This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

1982-06-01T23:59:59.000Z

152

Development of protective polymer coatings for silver halide fibers and their application as threshold level sensors for chlorinated hydrocarbons in sea water  

Science Journals Connector (OSTI)

The stability of silver halide fibers in artificial sea water (ASW) with and without a protective ... sensor system for the quantitative detection of chlorinated hydrocarbons (CHC) also in sea water.

R. Göbel; R. Krska; R. Kellner; A. Katzir

153

ARM - Field Campaign - Water Vapor IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govCampaignsWater Vapor IOP govCampaignsWater Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP 2000.09.18 - 2000.10.08 Lead Scientist : Henry Revercomb Data Availability Yes For data sets, see below. Description Scientific hypothesis: 1. Microwave radiometer (MWR) observations of the 22 GHz water vapor line can accurately constrain the total column amount of water vapor (assuming a calibration accuracy of 0.5 degC or better, which translates into 0.35 mm PWV). 2. Continuous profiling by Raman lidar provides a stable reference for handling sampling problems and observes a fixed column directly above the site only requiring a single height- independent calibration factor. 3. Agreement between the salt-bath calibrated in-situ probes, chilled

154

Stabilization of Electrocatalytic Metal Nanoparticles at Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

155

Energy balance in laser-irradiated vaporizing droplets  

Science Journals Connector (OSTI)

The interactions of vaporizing aerosols with a high energy laser beam are analyzed in the diffusive vaporization regime. This is the regime in which diffusive mass transport and...

Zardecki, Andrew; Armstrong, Robert L

1988-01-01T23:59:59.000Z

156

Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et...  

Open Energy Info (EERE)

Vapor (Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et...

157

Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

158

Recovering hydrocarbons from hydrocarbon-containing vapors  

DOE Patents [OSTI]

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

1980-09-30T23:59:59.000Z

159

Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides  

DOE Patents [OSTI]

A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

Ramkumar, Shwetha; Fan, Liang-Shih

2013-07-30T23:59:59.000Z

160

Efficient Destruction of CF4 through In Situ Generation of Alkali Metals from Heated Alkali Halide Reducing Mixtures  

Science Journals Connector (OSTI)

The atm. lifetimes of the fluorinated gases CF4, C2F6, c-C4F8, (CF3)2c-C4F6, C5F12, C6F14, C2F5Cl, C2F4Cl2, CF3Cl, and SF6 are of concern because of the effects that these long-lived compds. ... CF4 is an extremely stable gas which strongly absorbs IR radiation at ?8 ?m, and therefore is capable of influencing the greenhouse effect. ... Measurements of CF4 concns. in the atm. ...

Myung Churl Lee; Wonyong Choi

2002-02-14T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Aerogel composites using chemical vapor infiltration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aerogel composites using chemical vapor infiltration Aerogel composites using chemical vapor infiltration Title Aerogel composites using chemical vapor infiltration Publication Type Journal Article Year of Publication 1995 Authors Hunt, Arlon J., Michael R. Ayers, and Wanqing Cao Journal Journal of Non-Crystalline Solids Volume 185 Pagination 227-232 Abstract A new method to produce novel composite materials based on the use of aerogels as a starting material is described. Using chemical vapor infiltration, a variety of solid materials were thermally deposited into the open pore structure of aerogel. The resulting materials possess new and unusual properties including photoluminescence, magnetism and altered optical properties. An important characteristic of this preparation process is the very small size of the deposits that gives rise to new behaviors. Silicon deposits exhibit photoluminescence, indicating quantum confinement. Two or more phases may be deposited simultaneously and one or both chemically or thermally reacted to produce new structures.

162

Chemical vapor detection using nanomechanical platform  

Science Journals Connector (OSTI)

For high sensitive and multiplexed chemical analysis, an opto-mechanical detection platform has been built. To check the performance of the platform, we performed water vapor response measurements for ... sensors...

S. H. Lim

2007-11-01T23:59:59.000Z

163

Chemical vapor deposition of functionalized isobenzofuran polymers  

E-Print Network [OSTI]

This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

Olsson, Ylva Kristina

2007-01-01T23:59:59.000Z

164

Vapor Power Systems MAE 4263 Final Exam  

E-Print Network [OSTI]

Vapor Power Systems MAE 4263 Final Exam Wednesday, May 5, 2004 Prof. P.M. Moretti Key Instructions, then think, then write! 1. What is the dewpoint of the exhaust of your car, if the gasoline consists2 so that the mole fraction of water vapor is yH2 O = 9 9 + 8 + 47 = 0:14063 pH2 O = 0:14063 14

165

Metal Aminoboranes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Metal Aminoboranes Metal Aminoboranes Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. June 25, 2013 Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Available for thumbnail of Feynman Center (505) 665-9090 Email Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit. U.S. Patent No.: 7,713,506 (DOE S-112,798)

166

Optical monitor for water vapor concentration  

DOE Patents [OSTI]

A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma. 5 figs.

Kebabian, P.

1998-06-02T23:59:59.000Z

167

Optical monitor for water vapor concentration  

DOE Patents [OSTI]

A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

Kebabian, Paul (Acton, MA)

1998-01-01T23:59:59.000Z

168

Characterization of isothermal vapor phase epitaxial (Hg,Cd)Te  

Science Journals Connector (OSTI)

We report on the characterization of mercury cadmium telluride (Hg 1?x Cd x Te) film grown by the isothermal vapor phase epitaxial method (ISOVPE) and on the surface conversion of bulk Hg 1?xCd x Te to larger bandgap material. The crystal perfection is evaluated using defect etching electron beam and electrolyte electroreflectance (EBER and EER) and Rutherford backscattering spectrometry (RBS). Hall measurements are used to measure carrier densities and mobilities. Surface concentrations and concentration profiles are measured for the ISOVPE grown layers by transmission Fourier transform infrared spectroscopy (FTIR) and electron?probe microanalysis (EPMA) to establish quantitative informations about composition control. Metal–insulator?semiconductor (MIS) structures were made and the properties important to device performance such as compositional uniformity storage time and carrier concentration are measured. The ISOVPE layers are compared in quality to films grown by other methods and show promise for MIS devices.

S. B. Lee; L. K. Magel; M. F. S. Tang; D. A. Stevenson; J. H. Tregilgas; M. W. Goodwin; R. L. Strong

1990-01-01T23:59:59.000Z

169

Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural  

SciTech Connect (OSTI)

Sugars were converted to hydroxymethylfurfural (HMF) at high yield in ionic liquids without the addition of Bronsted acids. Very small amount of certain metal halides significantly reduced the fructose dehydration barrier in ionic liquids producing HMF at high yields. Most remarkably, glucose, a common sugar molecule, was selectively converted to HMF in good yield in ionic liquids containing a small amount of CrCl2. Thus CrCl2 is unique among metal chlorides tested for its effectiveness in both isomerizing glucose as well as dehydrating fructose. Only negligble amount of levulinic acid was formed in the reactions. The catalytic activity of metal chlorides for sugar conversion in ionic liquids is perhaps related to hydroxyl group of the sugar forming metal complexes with the unsaturated metal center.

Zhao, Haibo; Holladay, John E.; Brown, Heather M.; Zhang, Z. Conrad

2007-06-15T23:59:59.000Z

170

Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids  

E-Print Network [OSTI]

Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids Joe A. Wilson and James S. Chickos* Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121, United States *S Supporting Information ABSTRACT: Sublimation enthalpies

Chickos, James S.

171

Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography  

E-Print Network [OSTI]

Chromatography Chase Gobble and James Chickos* Department of Chemistry and Biochemistry University of Missouri-St. Louis, St. Louis Missouri 63121, United States Sergey P. Verevkin Department of Physical Chemistry: Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl

Chickos, James S.

172

Metal boiling under the action of an electron-beam heat source  

Science Journals Connector (OSTI)

The dynamics of vapor bubble growth in a metal alloy under the action of a volume heat source are considered. The possibility of existence of a threshold superheating value below which the boiling process is i...

G. E. Gorelik; A. S. Lerman; N. V. Pavlyukevich…

1975-10-01T23:59:59.000Z

173

E-Print Network 3.0 - actinide halide complexes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

It has been observed that complexes of lanthanide, actinide, and transition metal activate... that these actinide alkyl complexes undergo interesting C-H and C-N bond...

174

ARM - Field Campaign - Water Vapor IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govCampaignsWater Vapor IOP govCampaignsWater Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP 1996.09.10 - 1996.09.30 Lead Scientist : Henry Revercomb For data sets, see below. Summary SCHEDULE This IOP will be conducted from September 10 - 30, 1996 (coincident with the Fall ARM-UAV IOP). Instruments that do not require supervision will be operated continuously during this period. Instruments that do require supervision are presently planned to be operated for 8-hour periods each day. Because it is necessary to cover as broad a range of environmental conditions as possible, the daily 8-hour period will be shifted across the diurnal cycle as deemed appropriate during the IOP (but will be maintained as a contiguous 8-hour block).

175

atmospheric water vapor | OpenEI  

Open Energy Info (EERE)

atmospheric water vapor atmospheric water vapor Dataset Summary Description (Abstract): Monthly Average Solar Resource for 2-axis tracking concentrating collectors for Mexico, Central America, and the Caribbean Islands. (Purpose): Provide information on the solar resource potential for the data domain. The insolation values represent the average solar energy available to a concentrating collector, such as a dish collector, which tracks the sun continuously. Source NREL Date Released July 31st, 2006 (8 years ago) Date Updated October 30th, 2007 (7 years ago) Keywords atmospheric water vapor Carribean Islands Central America DNI GIS Mexico NREL GEF solar SWERA UNEP Data application/zip icon Download Shapefile (zip, 247.8 KiB) text/csv icon Download Data (csv, 370.6 KiB) Quality Metrics Level of Review Some Review

176

atmoshperic water vapor | OpenEI  

Open Energy Info (EERE)

atmoshperic water vapor atmoshperic water vapor Dataset Summary Description (Abstract): Monthly Average Solar Resource for flat-plate collectors tilted at latitude for China. Source NREL Date Released April 12th, 2005 (9 years ago) Date Updated October 30th, 2007 (7 years ago) Keywords atmoshperic water vapor China GEF GIS NREL solar SWERA TILT UNEP Data application/zip icon Download Shapefile (zip, 625.6 KiB) text/csv icon Download Data (csv, 704.1 KiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency Time Period 01/01/1985 - 12/31/1991 License License Open Data Commons Public Domain Dedication and Licence (PDDL) Comment Rate this dataset Usefulness of the metadata Average vote Your vote Usefulness of the dataset Average vote Your vote Ease of access

177

Method of making an electrode  

DOE Patents [OSTI]

Disclosed is a method of coating an electrode on a solid oxygen conductive oxide layer. A coating of particles of an electronic conductor is formed on one surface of the oxide layer and a source of oxygen is applied to the opposite surface of the oxide layer. A metal halide vapor is applied over the electronic conductor and the oxide layer is heated to a temperature sufficient to induce oxygen to diffuse through the oxide layer and react with the metal halide vapor. This results in the growing of a metal oxide coating on the particles of electronic conductor, thereby binding them to the oxide layer.

Isenberg, Arnold O. (Forest Hills Boro, PA)

1986-01-01T23:59:59.000Z

178

Vapor characterization of Tank 241-C-103  

SciTech Connect (OSTI)

The Westinghouse Hanford Company Tank Vapor Issue Resolution Program has developed, in cooperation with Northwest Instrument Systems, Inc., Oak Ridge National Laboratory, Oregon Graduate Institute of Science and Technology, Pacific Northwest Laboratory, and Sandia National Laboratory, the equipment and expertise to characterize gases and vapors in the high-level radioactive waste storage tanks at the Hanford Site in south central Washington State. This capability has been demonstrated by the characterization of the tank 241-C-103 headspace. This tank headspace is the first, and for many reasons is expected to be the most problematic, that will be characterized (Osborne 1992). Results from the most recent and comprehensive sampling event, sample job 7B, are presented for the purpose of providing scientific bases for resolution of vapor issues associated with tank 241-C-103. This report is based on the work of Clauss et al. 1994, Jenkins et al. 1994, Ligotke et al. 1994, Mahon et al. 1994, and Rasmussen and Einfeld 1994. No attempt has been made in this report to evaluate the implications of the data presented, such as the potential impact of headspace gases and vapors to tank farm workers health. That and other issues will be addressed elsewhere. Key to the resolution of worker health issues is the quantitation of compounds of toxicological concern. The Toxicology Review Panel, a panel of Pacific Northwest Laboratory experts in various areas, of toxicology, has chosen 19 previously identified compounds as being of potential toxicological concern. During sample job 7B, the sampling and analytical methodology was validated for this preliminary list of compounds of toxicological concern. Validation was performed according to guidance provided by the Tank Vapor Conference Committee, a group of analytical chemists from academic institutions and national laboratories assembled and commissioned by the Tank Vapor Issue Resolution Program.

Huckaby, J.L. [Westinghouse Hanford Co., Richland, WA (United States); Story, M.S. [Northwest Instrument Systems, Inc. Richland, WA (United States)

1994-06-01T23:59:59.000Z

179

Thermal electric vapor trap arrangement and method  

DOE Patents [OSTI]

A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

Alger, T.

1988-03-15T23:59:59.000Z

180

Diode pumped alkali vapor fiber laser  

DOE Patents [OSTI]

A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

2006-07-26T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Diode pumped alkali vapor fiber laser  

DOE Patents [OSTI]

A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

2007-10-23T23:59:59.000Z

182

Environmental Chemistry at Vapor/Water Interfaces  

E-Print Network [OSTI]

Environmental Chemistry at Vapor/Water Interfaces: Insights from Vibrational Sum Frequency Generation Spectroscopy Aaron M. Jubb, Wei Hua, and Heather C. Allen Department of Chemistry, The Ohio State/0505-0107$20.00 Keywords salts, lipids, atmospheric chemistry, ion binding, oxidation Abstract The chemistry that occurs

183

Advancing Explosives Detection Capabilities: Vapor Detection  

ScienceCinema (OSTI)

A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

Atkinson, David

2014-07-24T23:59:59.000Z

184

Program performs vapor-liquid equilibrium calculations  

SciTech Connect (OSTI)

A program designed for the Hewlett-Packard HP-41CV or 41C calculators solves basic vapor-liquid equilibrium problems, including figuring the dewpoint, bubblepoint, and equilibrium flash. The algorithm uses W.C. Edmister's method for predicting ideal-solution K values.

Rice, V.L.

1982-06-28T23:59:59.000Z

185

Metal inks  

DOE Patents [OSTI]

Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

2014-02-04T23:59:59.000Z

186

Synchroton X-Ray Studies of Liquid-Vapor Interfaces  

Science Journals Connector (OSTI)

The variation of density across the liquid-vapor interface from essentially zero density far out in the vapor phase to a homogeneous density deep in the liquid phase can be determined by X-ray reflectivity mea...

J. Als-Nielsen

1988-01-01T23:59:59.000Z

187

Vapor intrusion modeling : limitations, improvements, and value of information analyses  

E-Print Network [OSTI]

Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

Friscia, Jessica M. (Jessica Marie)

2014-01-01T23:59:59.000Z

188

Estimating the Atmospheric Water Vapor Content from Sun Photometer Measurements  

Science Journals Connector (OSTI)

The differential absorption technique for estimating columnar water vapor values from the analysis of sunphotometric measurements with wide- and narrowband interferential filters centered near 0.94 ?m is discussed and adapted. Water vapor line ...

Artemio Plana-Fattori; Michel Legrand; Didier Tanré; Claude Devaux; Anne Vermeulen; Philippe Dubuisson

1998-08-01T23:59:59.000Z

189

OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL  

E-Print Network [OSTI]

given by U.S. Department of Energy, Geothermal Division. #12;vii Table of Contents ABSTRACTOPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL RESERVOIRS CONSIDERING ADSORPTION governing the behavior of vapor- dominated geothermal reservoirs. These mechanisms affect both

Stanford University

190

Elastic Metal Alloy Refrigerants: Thermoelastic Cooling  

SciTech Connect (OSTI)

BEETIT Project: UMD is developing an energy-efficient cooling system that eliminates the need for synthetic refrigerants that harm the environment. More than 90% of the cooling and refrigeration systems in the U.S. today use vapor compression systems which rely on liquid to vapor phase transformation of synthetic refrigerants to absorb or release heat. Thermoelastic cooling systems, however, use a solid-state material—an elastic shape memory metal alloy—as a refrigerant and a solid to solid phase transformation to absorb or release heat. UMD is developing and testing shape memory alloys and a cooling device that alternately absorbs or creates heat in much the same way as a vapor compression system, but with significantly less energy and a smaller operational footprint.

None

2010-10-01T23:59:59.000Z

191

Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing  

DOE Patents [OSTI]

An electrochemical method is described for separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500 C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode. 3 figs.

Gay, E.C.

1995-10-03T23:59:59.000Z

192

The pressure induced B1-B2 phase transition of alkaline halides and alkaline earth chalcogenides. A first principles investigation  

SciTech Connect (OSTI)

In this work, we considered the pressure induced B1-B2 phase transition of AB compounds. The DFT calculations were carried out for 11 alkaline halides, 11 alkaline earth chalcogenides and the lanthanide pnictide CeP. For both the B1 and the B2 structures of each compound, the energy was calculated as a function of the cell volume. The transition pressure, the bulk moduli and their pressure derivatives were obtained from the corresponding equations of state. The transition path of the Buerger mechanism was described using roots of the transition matrix. We correlated the computed enthalpies of activation to some structure defining properties of the compounds. A fair correlation to Pearsons hardness of the ions was observed. -- Graphical abstract: Pressure induced transition from the B1 structure (left) via the transition state (middle) to the B2 structure (right). Display Omitted highlights: > Pressure induced phase transitions in AB compounds were considered. > Alkaline halides and alkaline earth chalcogenides were treated. > DFT calculations with periodic boundary conditions were applied. > The transition path was described by roots of the transition matrix. > The enthalpy of activation was calculated for numerous compounds.

Potzel, Oliver, E-mail: oliver.potzel@uni-ulm.d [Institute of Theoretical Chemistry, D-89069 Ulm (Germany); Taubmann, Gerhard, E-mail: gerhard.taubmann@uni-ulm.d [Institute of Theoretical Chemistry, D-89069 Ulm (Germany)

2011-05-15T23:59:59.000Z

193

Elkhorn Rural Public Pwr Dist | Open Energy Information  

Open Energy Info (EERE)

Rural Public Pwr Dist Rural Public Pwr Dist Jump to: navigation, search Name Elkhorn Rural Public Pwr Dist Place Nebraska Utility Id 5780 Utility Location Yes Ownership P NERC Location SPP NERC SPP Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Mercury Vapor Lamp 175 Watt Lighting Mercury Vapor Lamp 250 Watt Lighting Mercury Vapor Lamp 400 Watt Lighting Metal Halide 1000 Watt Lighting Metal Halide 1500 Watt Lighting Metal Halide 400 Watt Lighting RATE 1,3- Farm Residential, Commercial, Cabins, Seasonal--Single Phase Commercial RATE 12, 69- Urban Commercial Electric Space Heating, Single Phase

194

Apparent Temperature Dependence on Localized Atmospheric Water Vapor  

E-Print Network [OSTI]

Apparent Temperature Dependence on Localized Atmospheric Water Vapor Matthew Montanaroa, Carl), hence water vapor is the primary constituent of concern. The tower generates a localized water vapor, Office B108, Aiken, SC, USA ABSTRACT The atmosphere is a critical factor in remote sensing. Radiance from

Salvaggio, Carl

195

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

196

Investigations of chemical vapor deposition of GaN using synchrotron radiation  

SciTech Connect (OSTI)

The authors apply synchrotron x-ray analysis techniques to probe the surface structure of GaN films during synthesis by metal-organic chemical vapor deposition (MOCVD). Their approach is to observe the evolution of surface structure and morphology in real time using grazing incidence x-ray scattering (GIXS). This technique combines the ability of x-rays to penetrate the chemical vapor deposition environment for in situ measurements, with the sensitivity of GIXS to atomic scale structure. In this paper they present examples from some of their studies of growth modes and surface evolution as a function of process conditions that illustrate the capabilities of synchrotron x-ray analysis during MOCVD growth. They focus on studies of the homoepitaxial growth mode, island coarsening dynamics, and effects of impurities.

Thompson, C.; Stephenson, G. B.; Eastman, J. A.; Munkholm, A.; Auciello, O.; Murty, M. V. R.; Fini, P.; DenBaars, S. P.; Speck, J. S.

2000-05-25T23:59:59.000Z

197

Silicone metalization  

DOE Patents [OSTI]

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2006-12-05T23:59:59.000Z

198

Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank  

Broader source: Energy.gov [DOE]

Case study covering Compact Membrane Systems, Inc. and its membrane vapor processor that recovers fuel vapors from gasoline refueling.

199

Halide, Chromate, and Phosphate Impacts on LAW Glass for Dynamic Flowsheet 24590-WTP-MCR-PET-09-0037, Rev. 1  

SciTech Connect (OSTI)

Revision 1 of this Model Change Request changed Equation 6 in Attachment Al only. Melter studies have shown that halide, chromium, and phosphates can cause precipitation of solids that can interfer the melting process. Pilot melter data now shows what concentrations LAW glass can tolerate. These limits shall be incorporated into the existing LAW glass algorithm per Attachment Al.

Gimpel, Rodney F.; Kruger, Albert A.

2013-12-16T23:59:59.000Z

200

City of Elberton, Georgia (Utility Company) | Open Energy Information  

Open Energy Info (EERE)

Elberton, Georgia (Utility Company) Elberton, Georgia (Utility Company) Jump to: navigation, search Name City of Elberton Place Georgia Utility Id 5730 Utility Location Yes Ownership M NERC Location SERC NERC SERC Yes Activity Distribution Yes Activity Bundled Services Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 1000W Metal Halide Flood Lighting 1500W Metal Halide Flood Lighting 175W Mercury Vapor Lighting 250W Metal Halide Flood Lighting 400W Metal Halide Flood Lighting Commercial Service, Demand Commercial Commercial Service, Non-Demand Commercial Industrial Service, Schedule 1 Industrial

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Copper vapor laser modular packaging assembly  

DOE Patents [OSTI]

A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

1992-01-01T23:59:59.000Z

202

Gas: A Neglected Phase in Remediation of Metals and Radionuclides  

SciTech Connect (OSTI)

The gas phase is generally ignored in remediation of metals and radionuclides because it is assumed that there is no efficient way to exploit it. In the literal sense, all remediations involve the gas phase because this phase is linked to the liquid and solid phases by vapor pressure and thermodynamic relationships. Remediation methods that specifically use the gas phase as a central feature have primarily targeted volatile organic contaminants, not metals and radionuclides. Unlike many organic contaminants, the vapor pressure and Henry's Law constants of metals and radionuclides are not generally conducive to direct air stripping of dissolved contaminants. Nevertheless, the gas phase can play an important role in remediation of inorganic contaminants and provide opportunities for efficient, cost effective remediation. The objective here is to explore ways in which manipulation of the gas phase can be used to facilitate remediation of metals and radionuclides.

Denham, Miles E.; Looney, Brian B

2005-09-28T23:59:59.000Z

203

Synthesis of rare gas-halide mixtures resulting in efficient XeF(C. -->. A) laser oscillation  

SciTech Connect (OSTI)

Significantly improved XeF(C..-->..A) laser performance has been achieved using electron beam excitation of complex, multicomponent gas mixtures specifically tailored so as to reduce medium transient absorption in the blue-green region. Use of Ar and Kr together as the effective rare gas buffer-energy transfer species, along with a combination of NF/sub 3/ and F/sub 2/ to produce the desired F-donor molecule characteristics, has permitted synthesis of near optimum medium properties for which XeF(C) is produced efficiently while transient absorption is minimized. With this technique we have achieved laser pulse energy density and intrinsic efficiency of 2.2 +- 0.3 J/l and approx.1.5%, respectively, values that are comparable to those of the B..-->..X rare gas-halide lasers.

Nighan, W.L.; Tittel, F.K.; Wilson W.L. Jr.; Nishida, N.; Zhu, Y.; Sauerbrey, R.

1984-11-01T23:59:59.000Z

204

Optimization of the Catalytic Chemical Vapor Deposition Synthesis of Multiwall Carbon Nanotubes on FeCo(Ni)/SiO2 Aerogel Catalysts by Statistical Design of Experiments  

Science Journals Connector (OSTI)

We report on optimizing the catalytic chemical vapor deposition synthesis of multiwall carbon nanotubes (MWCNTs) from ethene over supported transition metal SiO2 nanocomposite aerogels using the statistical design of experiments (DOE) approach. ... The NIST/SEMATECH e-Handbook of Statistical Methods, http://www.itl.nist.gov/div898/handbook/ is acknowledged for DoE-related information. ...

László Vanyorek; Danilo Loche; Hajnalka Katona; Maria Francesca Casula; Anna Corrias; Zoltán Kónya; Ákos Kukovecz; Imre Kiricsi

2011-03-10T23:59:59.000Z

205

Photochemical vapor deposition of amorphous silicon photovoltaic devices. Semiannual subcontract report, 1 May 1985-31 October 1985  

SciTech Connect (OSTI)

Intrinsic, p-type, and n-type hydrogenated amorphous silicon thin-films have been deposited by mercury-sensitized photochemical vapor deposition (photo-CVD) from disilane. The photochemical reactor design includes two chambers separated by a movable uv-transparent Teflon curtain to eliminate deposition on the reactor window. Glass/TCO/p-i-n/metal photovoltaic devices were fabricated by photo-CVD. The efficiency at 87.5 MW/cm/sup 2/(ELH) was 5.1%.

Baron, B.N.; Rocheleau, R.E.; Hegedus, S.S.

1986-06-01T23:59:59.000Z

206

Ambipolar silicon nanowire FETs with stenciled-deposited metal gate Davide Sacchetto  

E-Print Network [OSTI]

Ambipolar silicon nanowire FETs with stenciled-deposited metal gate Davide Sacchetto , Veronica Keywords: Schottky barrier Ambipolarity Si nanowire Stencil lithography FET Silicide a b s t r a c t We chemical vapor deposition (LPCVD) of amorphous Si (a-Si) and SiO2 layers as well as metal gate patterning

De Micheli, Giovanni

207

Tunable carbon nanotube-tungsten carbide nanoparticles heterostructures by vapor deposition  

SciTech Connect (OSTI)

A simple, versatile route for the synthesis of carbon nanotube (CNT)-tungsten carbide nanoparticles heterostructures was set up via vapor deposition process. For the first time, amorphous CNTs (?-CNTs) were used to immobilized tungsten carbide nanoparticles. By adjusting the synthesis and annealing temperature, ?-CNTs/amorphous tungsten carbide, ?-CNTs/W{sub 2}C, and CNTs/W{sub 2}C/WC heterostructures were prepared. This approach provides an efficient method to attach other metal carbides and other nanoparticles to carbon nanotubes with tunable properties.

Xia, Min; Guo, Hongyan; Ge, Changchun [Institute of Special Ceramics and Powder Metallurgy, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing (China); Institute of Powder Metallurgy and Advanced Ceramics, Southwest Jiaotong University, 111, 1st Section, Northern 2nd Ring Road, Chengdu (China); Yan, Qingzhi, E-mail: qzyan@ustb.edu.cn; Lang, Shaoting [Institute of Special Ceramics and Powder Metallurgy, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing (China)

2014-05-14T23:59:59.000Z

208

Treating process wastewater employing vacuum distillation using mechanical vapor recompression  

SciTech Connect (OSTI)

Process wastewater has been successfully treated using an enhanced variable vacuum distillation system (VVDS). The removal of contaminants is achieved initially by degassing the liquid under an intense vacuum which removes the volatile organic compounds. The resulting liquid is then distilled under a vacuum using mechanical vapor recompression. The system was invented by Derald McCabe. This innovative treatment system removes virtually all of the contaminants, such as TSS, TDS, BOD{sub 5}, COD, heavy metals and mineral compounds. The resultant aqueous portion normally returns to a neutral pH. Due to the unique system operation, scaling problems (often encountered in conventional distillation) have not been detected in this system. The VVDS is extremely energy efficiency because the heat for distillation is generated and recycled mechanically. Using electricity as the energy source, the approximate operating cost, based on $0.05 KWH, may vary from $0.005 to $0.01 per gallon depending on the size and capacity of the equipment. Based on applications in waste streams performed to-date, the VVDS process has yielded a distilled water stream and the concentrated solids have been used as a byproduct or as a concentrated non-dischargeable waste for disposal.

McCabe, D.L. [Brandt, Houston, TX (United States)] [Brandt, Houston, TX (United States); Vivona, M.A. [ICF Kaiser Engineers, Inc., Houston, TX (United States). Water and Wastewater Dept.] [ICF Kaiser Engineers, Inc., Houston, TX (United States). Water and Wastewater Dept.

1999-05-01T23:59:59.000Z

209

Development of New Biphasic Metal Organic Working Fluids for Subcritical  

Open Energy Info (EERE)

Biphasic Metal Organic Working Fluids for Subcritical Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Development of New Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Working Fluids for Binary Power Plants Project Description In binary-cycle plants the cycle efficiency improves as pumping energy is reduced and from maximizing the enthalpy gain of the working fluid for a given amount of heat extracted from the geothermal source brine. Enthalpy gain of the working fluid in the heat exchanger occurs principally from sensible heat gained while passing through the heat exchanger in the liquid state and from vaporization of the organic working fluid near the exit of the heat exchanger. Additional heat transfer is limited after the vapor phase transition due the low thermal conductivity and heat capacity of the vapor. Also, operating pressures and temperatures are constrained by the bulk phase behavior and thermodynamic properties of the working fluid (boiling point, latent heat of vaporization, density, heat capacity, etc.). The fundamental underlying goal of this project is to overcome the cycle efficiency limitations imposed by the bulk thermodynamic proper-ties of the working fluid by introducing a metal-organic heat carrier (MOHC) into the system.

210

PLATINUM-GROUP METALS (Platinum, palladium, rhodium, ruthenium, iridium, osmium)  

E-Print Network [OSTI]

are also used in other air pollution abatement processes to remove organic vapors, odors, or carbon platinum-group metals (PGM) mine. The mine, located near Nye, MT, processed more than 400,000 metric tons and biomedical devices. Salient Statistics--United States: 1995 1996 1997 1998 1999e Mine production:1 Platinum 1

211

Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials  

DOE Patents [OSTI]

Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

1997-12-02T23:59:59.000Z

212

KINETIC CONDENSATION AND EVAPORATION OF METALLIC IRON AND IMPLICATIONS FOR METALLIC IRON DUST FORMATION  

SciTech Connect (OSTI)

Metallic iron is one of the most abundant condensing materials in systems of solar abundance. Because metallic iron is responsible for the continuum opacity of dust particles, it has a large contribution to the thermal structure of circumstellar environments and hence to dust evolution itself. In order to understand the formation processes of metallic iron in circumstellar environments, condensation and evaporation kinetics of metallic iron were studied experimentally. Metallic iron condenses at the maximum rate with the condensation coefficient (a parameter ranging from 0 to 1 to represent kinetic hindrance for surface reaction) of unity under high supersaturation conditions, and evaporates nearly ideally (evaporation coefficient of unity) in vacuum. On the other hand, evaporation of metallic iron takes place with more kinetic hindrance in the presence of metallic iron vapor. It is also found that metallic iron atoms nucleate heterogeneously on Al{sub 2}O{sub 3}. Metallic iron does not necessarily condense homogeneously in circumstellar environments, but might condense through heterogeneous nucleation on pre-existing dust. Metallic iron formation proceeds with little kinetic hindrance for highly unequilibrated conditions, but the effects of kinetic hindrance may appear for evaporation and condensation occurring near equilibrium with a timescale of months to years in protoplanetary disks.

Tachibana, Shogo; Nagahara, Hiroko; Ozawa, Kazuhito; Ikeda, Youhei; Nomura, Ryuichi; Tatsumi, Keisuke; Joh, Yui, E-mail: tachi@eps.s.u-tokyo.ac.jp [Department of Earth and Planetary Science, University of Tokyo, 7-3-1 Hongo, Tokyo 113-0033 (Japan)

2011-07-20T23:59:59.000Z

213

Nuclear design of the burst power ultrahigh temperature UF4 vapor core reactor system  

Science Journals Connector (OSTI)

Static and dynamic neutronic analyses are being performed as part of an integrated series of studies on an innovative burst power UF4 Ultrahigh Temperature Vapor Core Reactor (UTVR)/Disk Magnetohydrodynamic (MHD) generator for space nuclear power applications. This novel reactor concept operates on a direct closed Rankine cycle in the burst power mode (hundreds of MWe for thousands of seconds). The fuel/working fluid is a mixture of UF4 and metal fluoride. Preliminary calculations indicate high overall system efficiencies (?20%) small radiator size (?5 m2/MWe) and high specific power (?5 kWe/kg). Neutronic analysis has revealed a number of attractive features for this novel reactor concept. These include some unique and very effective inherent negative reactivity control mechanisms such as the vapor?fuel density power coefficient of reactivity the direct neutronic coupling among the multiple fissioning core regions (the central vapor core and the surrounding boiler columns) and the mass flow coupling feedback between the fissioning cores.

Samer D. Kahook; Edward T. Dugan

1991-01-01T23:59:59.000Z

214

ARM - Field Campaign - Fall 1997 Water Vapor IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Vapor IOP Water Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Fall 1997 Water Vapor IOP 1997.09.15 - 1997.10.05 Lead Scientist : Henry Revercomb For data sets, see below. Summary The Water Vapor IOP was conducted as a follow-up to a predecessor IOP on water vapor held in September 1996. This IOP relied heavily on both ground-based guest and CART instrumentation and in-situ aircraft and tethered sonde/kite measurements. Primary operational hours were from 6 p.m. Central until at least midnight, with aircraft support normally from about 9 p.m. until midnight when available. However, many daytime measurements were made to support this IOP. The first Water Vapor IOP primarily concentrated on the atmosphere's lowest

215

G-Band Vapor Radiometer Profiler (GVRP) Handbook  

SciTech Connect (OSTI)

The G-Band Vapor Radiometer Profiler (GVRP) provides time-series measurements of brightness temperatures from 15 channels between 170 and 183.310 GHz. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. Channels between 170.0 and 176.0 GHz are particularly sensitive to the presence of liquid water. The sensitivity to water vapor of the 183.31-GHz line is approximately 30 times higher than at the frequencies of the two-channel microwave radiometer (MWR) for a precipitable water vapor (PWV) amount of less than 2.5 mm. Measurements from the GVRP instrument are therefore especially useful during low-humidity conditions (PWV < 5 mm). In addition to integrated water vapor and liquid water, the GVRP can provide low-resolution vertical profiles of water vapor in very dry conditions.

Caddeau, MP

2010-06-23T23:59:59.000Z

216

Vapor port and groundwater sampling well  

DOE Patents [OSTI]

A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

217

Chemical vapor deposition of epitaxial silicon  

DOE Patents [OSTI]

A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

Berkman, Samuel (Florham Park, NJ)

1984-01-01T23:59:59.000Z

218

Storing images in warm atomic vapor  

E-Print Network [OSTI]

Reversible and coherent storage of light in atomic medium is a key-stone of future quantum information applications. In this work, arbitrary two-dimensional images are slowed and stored in warm atomic vapor for up to 30 $\\mu$s, utilizing electromagnetically induced transparency. Both the intensity and the phase patterns of the optical field are maintained. The main limitation on the storage resolution and duration is found to be the diffusion of atoms. A techniqueanalogous to phase-shift lithography is employed to diminish the effect of diffusion on the visibility of the reconstructed image.

M. Shuker; O. Firstenberg; R. Pugatch; A. Ron; N. Davidson

2008-06-17T23:59:59.000Z

219

Recovery of benzene in an organic vapor monitor  

E-Print Network [OSTI]

solid adsorbents available (silica gel, activated alumina, etc. ), activated charcoal is most frequently utilized. Activated charcoal has retentivity for sorbed vapors several times that of silica gel and it displays a selectivity for organic vapors... (diffusion rate) of the vapor molecules to the sur- face of the adsorbent. The adsorption process determine how effective the adsorbent collects and holds the contam- inant on the surface of the activated charcoal. Recovery of the contaminant from...

Krenek, Gregory Joel

2012-06-07T23:59:59.000Z

220

Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Exploration Activity Details Location Haleakala Volcano Area Exploration Technique Mercury Vapor Activity Date Usefulness not indicated DOE-funding Unknown Notes The field survey program on the northwest rift zone consisted of soil mercury and radon emanometry surveys, groundwater temperature and chemistry studies, Schlumberger resistivity soundings and self-potential profiles. Geophysical and geochemical surveys along this rift (southwest) were limited by difficult field conditions and access limitations. The geophysical program consisted of one Schlumberger sounding, one

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Mercury Vapor At Vale Hot Springs Area (Varekamp & Buseck, 1983...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Vale Hot Springs Area (Varekamp & Buseck, 1983) Exploration Activity Details...

222

Mercury Vapor At Breitenbush Hot Springs Area (Varekamp & Buseck...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Breitenbush Hot Springs Area (Varekamp & Buseck, 1983) Exploration Activity...

223

Mercury Vapor At Mickey Hot Springs Area (Varekamp & Buseck,...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mickey Hot Springs Area (Varekamp & Buseck, 1983) Exploration Activity...

224

Mercury Vapor At Desert Peak Area (Varekamp & Buseck, 1983) ...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Desert Peak Area (Varekamp & Buseck, 1983) Exploration Activity Details...

225

Mercury Vapor At Socorro Mountain Area (Kooten, 1987) | Open...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Socorro Mountain Area (Kooten, 1987) Exploration Activity Details Location...

226

Mercury Vapor At Lassen Volcanic National Park Area (Varekamp...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lassen Volcanic National Park Area (Varekamp & Buseck, 1983) Exploration...

227

Thermal Performance of a Double-Tube Type Lng Vaporizer  

Science Journals Connector (OSTI)

This report concerns the confirmed test results and method of analysis of the thermal performance of a double-tube type LNG vaporizer (DTV). The DTV is a...

Y. Miyata; T. Miura; S. Kasahara; H. Shohtani…

1994-01-01T23:59:59.000Z

228

Optimal Control of Vapor Extraction of Heavy Oil.  

E-Print Network [OSTI]

??Vapor extraction (Vapex) process is an emerging technology for viscous oil recovery that has gained much attention in the oil industry. However, the oil production… (more)

Muhamad, Hameed (Author)

2012-01-01T23:59:59.000Z

229

Geographic Information System At Cove Fort Area - Vapor (Nash...  

Open Energy Info (EERE)

navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geographic Information System At Cove Fort Area - Vapor (Nash, Et Al., 2002) Exploration Activity Details...

230

Raman Lidar Measurements of Aerosols and Water Vapor During the...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

modifications reduced but could not eliminate these adverse effects. The Raman lidar water vapor (aerosol extinction) measurements produced by these modified algorithms were,...

231

Thermal Gradient Holes At Cove Fort Area - Vapor (Warpinski,...  

Open Energy Info (EERE)

Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Cove Fort Area - Vapor (Warpinski, Et Al.,...

232

Ground Magnetics At Cove Fort Area - Vapor (Warpinski, Et Al...  

Open Energy Info (EERE)

Vapor (Warpinski, Et Al., 2004) Exploration Activity Details Location Cove Fort Geothermal Area Exploration Technique Ground Magnetics Activity Date Usefulness useful DOE-funding...

233

Spray structures and vaporizing characteristics of a GDI fuel spray  

Science Journals Connector (OSTI)

The spray structures and distribution characteristics of liquid and vapor phases in non-evaporating and evaporating Gasoline Direct Injection (GDI) fuel sprays were investigated using Laser Induced...

Dong-Seok Choi; Gyung-Min Choi; Duck-Jool Kim

2002-07-01T23:59:59.000Z

234

Metal oxide films on metal  

DOE Patents [OSTI]

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

235

Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Integration of Global Positioning System and Scanning Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates V. Mattioli and P. Basili Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado Introduction In recent years the Global Positioning System (GPS) has proved to be a reliable instrument for measuring precipitable water vapor (PWV) (Bevis et al. 1992), offering an independent source of information on water vapor when compared with microwave radiometers (MWRs), and/or radiosonde

236

Vapor and gas sampling of Single-Shell Tank 241-T-111 using the vapor sampling system  

SciTech Connect (OSTI)

This document presents sampling data resulting from the January 20, 1995, sampling of SST 241-T-111 using the vapor sampling system.

Caprio, G.S.

1995-09-01T23:59:59.000Z

237

Vapor and gas sampling of single-shell tank 241-BY-112 using the vapor sampling system  

SciTech Connect (OSTI)

This document presents sampling data from the November 18, 1994, sampling of SST 241-BY-112 using the vapor sampling system.

Caprio, G.S.

1995-09-20T23:59:59.000Z

238

Metal Toxicity  

Science Journals Connector (OSTI)

Problems posed to plants by metal toxicity in the soils of the world are basically of two kinds. The first kind are of natural origin. These arise either as a consequence of the nature of the parent material f...

T. McNeilly

1994-01-01T23:59:59.000Z

239

Testing of candidate materials for their resistance to alkali-vapor adsorption in PFBC and gasification environments. Final report  

SciTech Connect (OSTI)

Laboratory-scale studies were performed to identify metallic material(s) having no, or limited, affinity for alkali vapors in an environment of either the off-gas from pressurized fluidized-bed combustion (PFBC) or the fuel gas from coal gasification. Such materials would be potential candidates for use as components in advanced coal-utilization systems. The following materials were tested for adsorption of NaCl vapor at 870--875 C and atmospheric pressure in a simulated PFBC off-gas (oxidizing) doped with 80 ppmW NaCl vapor: iron-based Type 304 stainless steel (304 SS), nickel-based Hastelloy C-276 and Hastelloy X alloys, cobalt-based Haynes No. 188 alloy, noble-metal-coated 304 SS, aluminized 304 SS, and ZrO{sub 2}-coated 304 SS. The Haynes No. 188 alloy and the aluminized 304 SS were also tested for their NaCl-vapor adsorption in a simulated gasification fuel gas (reducing) under the same test conditions as in the PFBC off-gas test. After 100 h of testing, the specimens were analyzed with a SEM equipped with an energy dispersive X-ray analyzer, and by an AES. The aluminized 304 SS had the least tendency to adsorb NaCl vapor, as well as an excellent resistance to corrosion as a result of the formation of a protective layer of Al{sub 2}O{sub 3} on its surface. In the reducing environment, however, the aluminized 304 SS was badly corroded by H{sub 2}S attack. The Haynes No. 188 showed virtually no NaCl-vapor adsorption and only limited H{sub 2}S attack. The authors recommend further long-term parametric studies to quantitate alkali-vapor adsorption as a function of operating variables for (1) the aluminized 304 SS in the PFBC off-gas environment and (2) the Haynes No. 188 in the gasification fuel gas environment.

Lee, S.H.D.; Natesan, K.; Swift, W.M.

1995-08-01T23:59:59.000Z

240

Dendritic metal nanostructures  

DOE Patents [OSTI]

Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2010-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-  

E-Print Network [OSTI]

I BNL- 62834 Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-· [D VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY- A DISCUSSION OF TECHNICAL FEASIBILITY Concept MONEY --A DISCUSSION OF TECHNICAL FEASffiILITY Russell N. Dietz, Head Tracer Technology Center

242

RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR  

E-Print Network [OSTI]

RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR By SCOTT RUSSELL WAITUKAITIS A Thesis Submitted: #12;Abstract I describe a study of Faraday rotation in a hot lithium vapor. I begin by dis- cussing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.3 The Lithium Oven and Solenoid . . . . . . . . . . . . . . . . . 7 3 Theoretical Framework

Cronin, Alex D.

243

FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS  

Office of Scientific and Technical Information (OSTI)

Bulletin 627 Bulletin 627 BUREAU o b MINES FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS By Michael G. Zabetakis DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement,

244

New Regenerative Cycle for Vapor Compression Refrigeration  

Office of Scientific and Technical Information (OSTI)

SCIENTIFIC REPORT SCIENTIFIC REPORT Title Page Project Title: New Regenerative Cycle for Vapor Compression Refrigeration DOE Award Number: DE-FG36-04GO14327 Document Title: Final Scientific Report Period Covered by Report: September 30, 2004 to September 30, 2005 Name and Address of Recipient Organization: Magnetic Development, Inc., 68 Winterhill Road, Madison, CT 06443, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Contact Information: Mark J. Bergander, Ph.D., P.E., Principal Investigator, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Project Objective (as stated in the proposal): The main objective of this project is to confirm on a well-instrumented prototype the theoretically derived claims of higher efficiency and coefficient

245

Kinetics of wet sodium vapor complex plasma  

SciTech Connect (OSTI)

In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

2014-04-15T23:59:59.000Z

246

Photo-Electric Ionization of Caesium Vapor  

Science Journals Connector (OSTI)

Measurement of photo-electric ionization in gases.—The current from a filament, normally limited by space change, is increased by the presence of positive ions. As shown by Kingdon this effect may be greatly magnified if a small cathode is practically enclosed by the anode so that the ions are imprisoned. This method was used for the detection of photo-electric ionization. Besides possessing extreme sensitivity it is unaffected by photo-electric emission from the electrodes.Photo-electric effect in caesium vapor.—The change in thermionic current with the unresolved radiation from a mercury arc was measured as functions of the applied voltage, filament temperature, and vapor pressure. Then the photo-electric effect as a function of wave-length was studied using a monochromatic illuminator to disperse light from the arc or a Mazda lamp. The ionization per unit flux was found to increase with increasing wave-length to a sharp maximum at the limit 1s=3184A of the principal series, as is required by the Bohr theory. For longer wave-lengths the ionization decreased to about 10 percent at 3400A. Photo-excitation. The simple theory does not admit of ionization by wave-lengths greater than 3184A but the data are in qualitative agreement with the hypothesis that such radiation produces excited atoms which upon collision with other atoms acquire sufficient additional energy to become ionized. Hence, unlike an x-ray limit, the photo-ionization effect for a valence electron is not sharply discontinuous at the true threshold for direct ionization.Photo-ionization photometer and intensitometer. A tube of the type described, with suitable gases for the range of wave-length involved, may be used as a photometer or may be calibrated to measure intensity of radiation directly.

Paul D. Foote and F. L. Mohler

1925-08-01T23:59:59.000Z

247

Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes  

DOE Patents [OSTI]

A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

2003-06-03T23:59:59.000Z

248

E-Print Network 3.0 - atomic vapor laser Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with the exception of pagination. IEEE TRANSACTIONS ON PLASMA SCIENCE 1 Summary: vapor, atomic physics and vapor ionization, absorption reflection in a heated plasma layer, and...

249

E-Print Network 3.0 - atom vapor cells Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

rotation in the vapor cell due to inten- sity-induced birefringence in the rubidium atomic vapor. While... Super efficient absorption filter for quantum memory using atomic...

250

Dry halide method for separating the components of spent nuclear fuels  

DOE Patents [OSTI]

The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission- and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200.degree. C. to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400.degree. C.; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164.degree. C. to 2.degree. C.; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic.

Christian, Jerry Dale (Idaho Falls, ID); Thomas, Thomas Russell (Rigby, ID); Kessinger, Glen F. (Idaho Falls, ID)

1998-01-01T23:59:59.000Z

251

Electrophilic Metal Alkyl Chemistry in New Ligand Environments  

SciTech Connect (OSTI)

The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

Jordan, Richard F. [University of Chicago] University of Chicago

2013-06-30T23:59:59.000Z

252

Preliminary assessment of halogenated alkanes as vapor-phase tracers  

SciTech Connect (OSTI)

New tracers are needed to evaluate the efficiency of injection strategies in vapor-dominated environments. One group of compounds that seems to meet the requirements for vapor-phase tracing are the halogenated alkanes (HCFCs). HCFCs are generally nontoxic, and extrapolation of tabulated thermodynamic data indicate that they will be thermally stable and nonreactive in a geothermal environment. The solubilities and stabilities of these compounds, which form several homologous series, vary according to the substituent ratios of fluorine, chlorine, and hydrogen. Laboratory and field tests that will further define the suitability of HCFCs as vapor-phase tracers are under way.

Adams, Michael C.; Moore, Joseph N.; Hirtz, Paul

1991-01-01T23:59:59.000Z

253

Mercury Vapor At Medicine Lake Area (Kooten, 1987) | Open Energy  

Open Energy Info (EERE)

Kooten, 1987) Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Medicine Lake Area (Kooten, 1987) Exploration Activity Details Location Medicine Lake Area Exploration Technique Mercury Vapor Activity Date Usefulness could be useful with more improvements DOE-funding Unknown References Gerald K. Van Kooten (1987) Geothermal Exploration Using Surface Mercury Geochemistry Retrieved from "http://en.openei.org/w/index.php?title=Mercury_Vapor_At_Medicine_Lake_Area_(Kooten,_1987)&oldid=386431" Category: Exploration Activities What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation:

254

Composite metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

255

Composite metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

1998-04-14T23:59:59.000Z

256

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents [OSTI]

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

257

Laser techniques for studying chemical vapor deposition  

SciTech Connect (OSTI)

Chemical vapor deposition (CVD) is widely used to produce thin films for microelectronics, protective coatings and other materials processing applications. Despite the large number of applications, however, little is known about the fundamental chemistry and physics of most CVD processes. CVD recipes have generally been determined empirically, but as process requirements become more stringent, a more basic understanding will be needed to improve reactor design and speed process optimization. In situ measurements of the reacting gas are important steps toward gaining such an understanding, both from the standpoint of characterizing the reactor and testing models of a CVD process. Our work, a coordinated program of experimental and theoretical research in the fundamental mechanisms of CVD, illustrates the application of laser techniques to the understanding of a CVD system. We have used a number of laser-based techniques to probe CVD systems and have compared our measurements with predictions from computer models, primarily for the silane CVD system. The silane CVD model solves the two-dimensional, steady-state boundary layer equations of fluid flow coupled to 26 elementary chemical reactions describing the thermal decomposition of silane and the subsequent reactions of intermediate species that result in the deposition of a silicon film.

Ho, P.; Breiland, W.G.; Coltrin, M.E.

1990-01-01T23:59:59.000Z

258

City of Elizabethton, Tennessee (Utility Company) | Open Energy Information  

Open Energy Info (EERE)

Elizabethton, Tennessee (Utility Company) Elizabethton, Tennessee (Utility Company) Jump to: navigation, search Name City of Elizabethton Place Tennessee Utility Id 5763 Utility Location Yes Ownership M NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 100 Watt High Pressure Sodium Lighting 1000 Watt Mercury Vapor Lighting 1000 Watt Metal Halide Lighting 150 Watt High Pressure Sodium Lighting 175 Watt Mercury Vapor Lighting 250 Watt High Pressure Sodium Lighting 250 Watt Mercury Vapor Lighting 400 Watt Mercury Vapor Lighting 400 Watt Metal Halide Lighting

259

New River Light & Power Co | Open Energy Information  

Open Energy Info (EERE)

New River Light & Power Co New River Light & Power Co Place North Carolina Utility Id 13482 Utility Location Yes Ownership S NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 100 Watt SV TOB Lighting 150 Watt SV TOB Lighting 150 Watt Sodium Vapor Lighting 175 Watt MV TOB Lighting 175 Watt Mercury Vapor Lighting 250 Watt Metal Halide Lighting 250 Watt SV TOB Lighting 250 Watt Sodium Vapor Lighting 400 Watt MV TOB Lighting 400 Watt Mercury Vapor Lighting 400 Watt Metal Halide Lighting 400 Watt SV TOB Lighting 750 Watt SV TOB Lighting

260

ARM - Field Campaign - Arctic Winter Water Vapor IOP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govCampaignsArctic Winter Water Vapor IOP govCampaignsArctic Winter Water Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Arctic Winter Water Vapor IOP 2004.03.09 - 2004.04.09 Lead Scientist : Ed Westwater Data Availability http://www.etl.noaa.gov/programs/2004/wviop/data will contain quicklooks of all of the data. For data sets, see below. Summary During the IOP, the Ground-based Scanning Radiometer of NOAA/ETL, and the ARM MicroWave Radiometer and Microwave Profiler, yielded excellent data over a range of conditions. In all, angular-scanned and calibrated radiometric data from 22.345 to 380 GHz were taken. The Precipitable Water Vapor varied about an order of magnitude from 1 to 10 mm, and surface temperatures varied from about -10 to -40 deg. Celcius. Vaisala RS90

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Overview of the ARM/FIRE Water Vapor Overview of the ARM/FIRE Water Vapor Experiment (AFWEX) D. C. Tobin, H. E. Revercomb, and D. D. Turner University of Wisconsin-Madison Madison, Wisconsin Introduction An overview of the ARM/FIRE Water Vapor Experiment (AFWEX) is given. This field experiment was conducted during November-December 2000 near the central ground-based Atmospheric Radiation Measurement (ARM) site in north central Oklahoma, and was sponsored jointly by the ARM, the National Aeronautics and Space Administration (NASA) First ISCCP Regional Experiment (FIRE), and the National Polar-orbiting Operational Environmental Satellite System (NPOESS) programs. Its primary goal was to collect accurate measurements of upper-level (~8 to 12 km) water vapor near the ground-based ARM site. These data are being used to determine the accuracy of measurements that are

262

Initiated chemical vapor deposition of functional polyacrylic thin films  

E-Print Network [OSTI]

Initiated chemical vapor deposition (iCVD) was explored as a novel method for synthesis of functional polyacrylic thin films. The process introduces a peroxide initiator, which can be decomposed at low temperatures (<200?C) ...

Mao, Yu, 1975-

2005-01-01T23:59:59.000Z

263

Low Level Heat Recovery Through Heat Pumps and Vapor Recompression  

E-Print Network [OSTI]

The intent of this paper is to examine the methods and economics of recovering low level heat through heat pumps and vapor recompression. Actual commercially available equipment is considered to determine the near-term and future economic viability...

Gilbert, J.

1980-01-01T23:59:59.000Z

264

Applications of Mechanical Vapor Recompression to Evaporation and Crystallization  

E-Print Network [OSTI]

there is no boiler plant available or when electrical power is priced competitively in comparison to steam. Vapor recompression is accomplished using centrifugal, axial-flow, or positive displacement compressors and these compressors can be powered by electricity...

Outland, J. S.

265

Enabling integration of vapor-deposited polymer thin films  

E-Print Network [OSTI]

Initiated Chemical Vapor Deposition (iCVD) is a versatile, one-step process for synthesizing conformal and functional polymer thin films on a variety of substrates. This thesis emphasizes the development of tools to further ...

Petruczok, Christy D. (Christy Danielle)

2014-01-01T23:59:59.000Z

266

Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

Cronin, Alex D.

267

All graphene electromechanical switch fabricated by chemical vapor deposition  

E-Print Network [OSTI]

We demonstrate an electromechanical switch comprising two polycrystalline graphene films; each deposited using ambient pressure chemical vapor deposition. The top film is pulled into electrical contact with the bottom film ...

Milaninia, Kaveh M.

268

Systems and methods for generation of hydrogen peroxide vapor  

DOE Patents [OSTI]

A system according to one embodiment includes a moisture trap for drying air; at least one of a first container and a second container; and a mechanism for at least one of: bubbling dried air from the moisture trap through a hydrogen peroxide solution in the first container for producing a hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above a hydrogen peroxide solution in the second container for producing a hydrogen peroxide vapor. A method according one embodiment includes at least one of bubbling dried air through a hydrogen peroxide solution in a container for producing a first hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above the hydrogen peroxide solution in a container for producing a second hydrogen peroxide vapor. Additional systems and methods are also presented.

Love, Adam H; Eckels, Joel Del; Vu, Alexander K; Alcaraz, Armando; Reynolds, John G

2014-12-02T23:59:59.000Z

269

Optical Precursors in Rubidium Vapor and Their Relation to Superradiance  

E-Print Network [OSTI]

Optical precursor is the sharp optical pulse front that does not show delay in absorptive media. In this thesis, optical precursor behavior in rubidium (Rb) vapor was investigated in the picoseconds regime. An amplified femtosecond laser was shaped...

Yang, Wenlong

2012-10-19T23:59:59.000Z

270

Photocoupling of Methane in Water Vapor to Saturated Hydrocarbons  

Science Journals Connector (OSTI)

Methane can be converted into alkanes (from C2 to C6) continuously by ultraviolet (185 nm) irradiation in the presence of water vapor. The products from this reaction are alkanes, which is different from the comp...

JunePyo Oh; Taketoshi Matsumoto; Junji Nakamura

2008-08-01T23:59:59.000Z

271

Mercury Vapor At Kawaihae Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor At Kawaihae Area (Thomas, 1986) Mercury Vapor At Kawaihae Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location Kawaihae Area Exploration Technique Mercury Vapor Activity Date Usefulness not useful DOE-funding Unknown Notes The soil geochemistry yielded quite complex patterns of mercury concentrations and radonemanation rates within the survey area (Cox and Cuff, 1981c). Mercury concentrations (Fig. 38) showed a general minimum along the Kawaihae-Waimea roads and a broad trend of increasing mercury concentrations toward both the north and south. There is no correlation apparent between the mercury patterns and either the resistivity sounding data or the surface geology in the area. The radon emanometry data (Fig.

272

Mercury Vapor At Lualualei Valley Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Exploration Activity Details Location Lualualei Valley Area Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes Soil mercury and radon emanation surveys were performed over much of the accessible surface of Lualualei Valley (Cox and Thomas, 1979). The results of these surveys (Figs 7 and 8) delineated several areas in which soil mercury concentrations or radon emanation rates were substantially above normal background values. Some of these areas were apparently coincident with the mapped fracture systems associated with the caldera boundaries.

273

Advanced Chemical Heat Pumps Using Liquid-Vapor Reactions  

E-Print Network [OSTI]

ically feasible systems have significant potential advantage over conventional tech nology. An electric drive reactive heat pump can use smaller heat exchangers and compressor than a vapor-compression machine, and have more flexible operating... are discussed, and performance is bounded. A discussion on liquid-vapor equilibria is included as introduction to the systems I- considered. The electric drive heat pump and TA are promising systems; the TA has potential for higher COP than absorption...

Kirol, L.

274

Tank 241-S-102 headspace gas and vapor characterization results for samples collected in March 1995  

SciTech Connect (OSTI)

Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories

Huckaby, J.L. [Pacific Northwest Lab., Richland, WA (United States); Bratzel, D.R. [Westinghouse Hanford Co., Richland, WA (United States)

1995-09-26T23:59:59.000Z

275

investigating the source, transport, and isotope fractionation of water vapor in the atmospheric boundary layer  

E-Print Network [OSTI]

investigating the source, transport, and isotope fractionation of water vapor in the atmospheric cospectral similarity for temperature and water vapor isotope fluxes. mixing ratio generator Routine field use in water vapor isotope research. The unit generates a stable water vapor mixing ratio by measuring

Minnesota, University of

276

Calculating the vapor pressure of water from the second law of thermodynamics  

Science Journals Connector (OSTI)

Calculating the vapor pressure of water from the second law of thermodynamics ... Thermodynamics ...

M. H. Everdell

1969-01-01T23:59:59.000Z

277

The growth of vapor bubble and relaxation between two-phase bubble flow  

Science Journals Connector (OSTI)

This paper presents the behavior of the bubble growth and relaxation between vapor and superheated...

S. Mohammadein; Rama Subba Reddy Gorla

2003-01-01T23:59:59.000Z

278

Tank Vapor Characterization Project: Annual status report for FY 1996  

SciTech Connect (OSTI)

In Fiscal Year 1996, staff at the Vapor Analytical Laboratory at Pacific Northwest National Laboratory performed work in support of characterizing the vapor composition of the headspaces of radioactive waste tanks at the Hanford Site. Work performed included support for technical issues and sampling methodologies, upgrades for analytical equipment, analytical method development, preparation of unexposed samples, analyses of tank headspaces samples, preparation of data reports, and operation of the tank vapor database. Progress made in FY 1996 included completion and issuance of 50 analytical data reports. A sampling system comparison study was initiated and completed during the fiscal year. The comparison study involved the vapor sampling system (VSS), a truck-based system, and the in situ vapor sampling system (ISVS), a cart-based system. Samples collected during the study were characterized for inorganic, permanent gases, total non-methane organic compounds and organic speciation by SUMMA{trademark} and TST methods. The study showed comparable sampling results between the systems resulting in the program switching from the VSS to the less expensive ISVS methodology in late May 1996. A temporal study was initiated in January 1996 in order to understand the influences seasonal temperatures changes have on the vapors in the headspace of Hanford waste tanks. A holding time study was initiated in the fourth quarter of FY 1996. Samples were collected from tank S-102 and rushed to the laboratory for time zero analysis. Additional samples will be analyzed at 1, 2, 4, 8, 16, and 32 weeks.

Silvers, K.L.; Fruchter, J.S.; Huckaby, J.L.; Almeida, T.L.; Evans, J.C. Jr.; Pool, K.H.; Simonen, C.A.; Thornton, B.M.

1997-01-01T23:59:59.000Z

279

Photochemical vapor deposition of amorphous silicon photovoltaic devices: Annual subcontract report, 1 May 1985-30 April 1986  

SciTech Connect (OSTI)

Intrinsic, p-type, and n-type a-Si:H and p-type a-SiC:H thin-films have been deposited by Hg-sensitized photochemical vapor depositions (photo-CVD) from disilane. The photochemical reactor design includes two chambers separated by a movable uv-transparent Teflon curtain, which eliminates deposition on the reactor window. Photovoltaic devices of the type glass/TCO/p-i-n/metal were fabricated by photo-CVD. The device efficiency obtained at 87.5 mW/cm/sup 2/ and ELH illumination was 6.4%.

Baron, B.N.; Rocheleau, R.E.; Hegedus, S.S.

1987-02-01T23:59:59.000Z

280

Vapor-transport growth of high optical quality WSe{sub 2} monolayers  

SciTech Connect (OSTI)

Monolayer transition metal dichalcogenides are atomically thin direct-gap semiconductors that show a variety of novel electronic and optical properties with an optically accessible valley degree of freedom. While they are ideal materials for developing optical-driven valleytronics, the restrictions of exfoliated samples have limited exploration of their potential. Here, we present a physical vapor transport growth method for triangular WSe{sub 2} sheets of up to 30 ?m in edge length on insulating SiO{sub 2} substrates. Characterization using atomic force microscopy and optical microscopy reveals that they are uniform, monolayer crystals. Low temperature photoluminescence shows well resolved and electrically tunable excitonic features similar to those in exfoliated samples, with substantial valley polarization and valley coherence. The monolayers grown using this method are therefore of high enough optical quality for routine use in the investigation of optoelectronics and valleytronics.

Clark, Genevieve [Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Wu, Sanfeng; Rivera, Pasqual; Finney, Joseph; Nguyen, Paul; Cobden, David H. [Department of Physics, University of Washington, Seattle, Washington 98195 (United States); Xu, Xiaodong, E-mail: xuxd@uw.edu [Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Department of Physics, University of Washington, Seattle, Washington 98195 (United States)

2014-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Chemical vapor deposition of refractory ternary nitrides for advanced diffusion barriers  

SciTech Connect (OSTI)

Refractory ternary nitride films for diffusion barriers in microelectronics have been grown using chemical vapor deposition. Thin films of titanium-silicon-nitride, tungsten-boron-nitride, and tungsten-silicon-nitride of various compositions have been deposited on 150 mm Si wafers. The microstructure of the films are either fully amorphous for the tungsten based films, or nauocrystalline TiN in an amorphous matrix for titanium-silicon-nitride. All films exhibit step coverages suitable for use in future microelectronics generations. Selected films have been tested as diffusion barriers between copper and silicon, and generally perform extremely weH. These fiIms are promising candidates for advanced diffusion barriers for microelectronics applications. The manufacturing of silicon wafers into integrated circuits uses many different process and materials. The manufacturing process is usually divided into two parts: the front end of line (FEOL) and the back end of line (BEOL). In the FEOL the individual transistors that are the heart of an integrated circuit are made on the silicon wafer. The responsibility of the BEOL is to wire all the transistors together to make a complete circuit. The transistors are fabricated in the silicon itself. The wiring is made out of metal, currently aluminum and tungsten, insulated by silicon dioxide, see Figure 1. Unfortunately, silicon will diffuse into aluminum, causing aluminum spiking of junctions, killing transistors. Similarly, during chemical vapor deposition (CVD) of tungsten from ~fj, the reactivity of the fluorine can cause "worn-holes" in the silicon, also destroying transistors. The solution to these problems is a so-called diffusion barrier, which will allow current to pass from the transistors to the wiring, but will prevent reactions between silicon and the metal.

Custer, Jonathan S.; Fleming, James G.; Roherty-Osmun, Elizabeth; Smith, Paul Martin

1998-09-22T23:59:59.000Z

282

Volatile Species Retention During Metallic Fuel Casting  

SciTech Connect (OSTI)

Metallic nuclear fuels are candidate transmutation fuel forms for advanced fuel cycles. Through the operation of the Experimental Breeder Reactor II metallic nuclear fuels have been shown to be robust and easily manufactured. However, concerns have been raised concerning loss of americium during the casting process because of its high vapor pressure. In order to address these concerns a gaseous diffusion model was developed and a series of experiments using both manganese and samarium as surrogates for americium were conducted. The modeling results showed that volatility losses can be controlled to essentially no losses with a modest overpressure. Experimental results also showed volatile species retention down to no detectable losses through overpressure, although the loss values varied from the model results the same trend was seen. Bases on these results it is very probably that americium losses through volatility can be controlled to no detectable losses through application of a modest overpressure during casting.

Randall S. Fielding; Douglas L. Proter

2013-10-01T23:59:59.000Z

283

Direct chemical vapor deposition of graphene on dielectric surfaces  

DOE Patents [OSTI]

A substrate is provided that has a metallic layer on a substrate surface of a substrate. A film made of a two dimensional (2-D) material, such as graphene, is deposited on a metallic surface of the metallic layer. The metallic layer is dewet and/or removed to provide the film on the substrate surface.

Zhang, Yuegang; Ismach, Ariel

2014-04-29T23:59:59.000Z

284

Mechanochemical processing for metals and metal alloys  

DOE Patents [OSTI]

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

2001-01-01T23:59:59.000Z

285

Mercury Source Zone Identification using Soil Vapor Sampling and Analysis  

SciTech Connect (OSTI)

Development and demonstration of reliable measurement techniqes that can detect and help quantify the nature and extent of elemental mercury (Hg(0)) in the subsurface are needed to reduce certainties in the decision making process and increase the effectiveness of remedial actions. We conducted field tests at the Y-12 National Security Complex (NSC) in Oak Ridge, TN, to determine if sampling and analysis of Hg(0) vapors in the shallow subsurface (<0.3 m depth) can be used to as an indicator of the location and extent of Hg(0) releases in the subsurface. We constructed a rigid PVC pushprobe assembly, which was driven into the ground. Soil gas samples were collected through a sealed inner tube of the assembly and analyzed immediately in the field with a Lumex and/or Jerome Hg(0) analyzer. Time-series sampling showed that Hg vapor concentrations were fairly stable over time suggesting that the vapor phase Hg(0) was not being depleted and that sampling results were not dependent on the soil gas purge volume. Hg(0) vapor data collected at over 200 pushprobe locations at 3 different release sites correlated well to areas of known Hg(0) contamination. Vertical profiling of Hg(0) vapor concentrations conducted at 2 locations provided information on the vertical distribution of Hg(0) contamination in the subsurface. We concluded from our studies that soil gas sampling and analysis can be conducted rapidly and inexpensively at a large scale to help identify areas contaminated with Hg(0).

Watson, David B [ORNL] [ORNL; Miller, Carrie L [ORNL] [ORNL; Lester, Brian P [ORNL] [ORNL; Lowe, Kenneth Alan [ORNL] [ORNL; Southworth, George R [ORNL] [ORNL; Bogle, Mary Anna [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Pierce, Eric M [ORNL] [ORNL

2014-01-01T23:59:59.000Z

286

Vapor etching of nuclear tracks in dielectric materials  

DOE Patents [OSTI]

A process involving vapor etching of nuclear tracks in dielectric materials for creating high aspect ratio (i.e., length much greater than diameter), isolated cylindrical holes in dielectric materials that have been exposed to high-energy atomic particles. The process includes cleaning the surface of the tracked material and exposing the cleaned surface to a vapor of a suitable etchant. Independent control of the temperatures of the vapor and the tracked materials provide the means to vary separately the etch rates for the latent track region and the non-tracked material. As a rule, the tracked regions etch at a greater rate than the non-tracked regions. In addition, the vapor-etched holes can be enlarged and smoothed by subsequent dipping in a liquid etchant. The 20-1000 nm diameter holes resulting from the vapor etching process can be useful as molds for electroplating nanometer-sized filaments, etching gate cavities for deposition of nano-cones, developing high-aspect ratio holes in trackable resists, and as filters for a variety of molecular-sized particles in virtually any liquid or gas by selecting the dielectric material that is compatible with the liquid or gas of interest.

Musket, Ronald G. (Danville, CA); Porter, John D. (Berkeley, CA); Yoshiyama, James M. (Fremont, CA); Contolini, Robert J. (Lake Oswego, OR)

2000-01-01T23:59:59.000Z

287

Metal-Organic Heat Carrier Nanofluids  

SciTech Connect (OSTI)

Nanofluids, dispersions of metal or oxide nanoparticles in a base working fluid, are being intensively studied due to improvements they offer in thermal properties of the working fluid. However, these benefits have been erratically demonstrated and proven impacts on thermal conductivity are modest and well described from long-established effective medium theory. In this paper, we describe a new class of metal-organic heat carrier (MOHC) nanofluid that offers potential for a larger performance boost in thermal vapor-liquid compression cycles. MOHCs are nanophase porous coordination solids designed to reversibly uptake the working fluid molecules in which the MOHCs are suspended. Additional heat can be extracted in a heat exchanger or solar collector from the endothermic enthalpy of desorption, which is then released as the nanofluid transits through a power generating device such as a turboexpander. Calculations for an R123 MOHC nanofluid indicated potential for up to 15% increase in power output. Capillary tube experiments show that liquid-vapor transitions occur without nanoparticle deposition on the tube walls provided entrance Reynolds number exceeds approximately 100.

McGrail, B. Peter; Thallapally, Praveen K.; Blanchard, Jeremy; Nune, Satish K.; Jenks, Jeromy WJ; Dang, Liem X.

2013-09-01T23:59:59.000Z

288

Validation of TES Temperature and Water Vapor Retrievals with ARM  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Validation of TES Temperature and Water Vapor Retrievals with ARM Validation of TES Temperature and Water Vapor Retrievals with ARM Observations Cady-Pereira, Karen Atmospheric and Environmental Research, Inc. Shephard, Mark Atmospheric and Environmental Research, Inc. Clough, Shepard Atmospheric and Environmental Research Mlawer, Eli Atmospheric & Environmental Research, Inc. Turner, David University of Wisconsin-Madison Category: Atmospheric State and Surface The primary objective of the TES (Tropospheric Emission Spectrometer) instrument on the Aura spacecraft is the retrieval of trace gases, especially water vapor and ozone. The TES retrievals extremely useful for global monitoring of the atmospheric state, but they must be validated. The ARM sites are well instrumented and provide continuous measurements, which

289

Phase effects for electrons in liquid water and water vapor  

SciTech Connect (OSTI)

The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

1988-01-01T23:59:59.000Z

290

The development of a passive dosimeter for airborne aniline vapors  

E-Print Network [OSTI]

passive sampl1ng dosimeter was designed to measure concen- trat1ons of aniline vapor in air. Diffus1on tubes of 1. 5, 3. 0 and 4. 5 cm lengths were tested under controlled conditions of relative humid1ty, air temperature and vapor concentrations. A... of Measured vs Calculated Concentrations APPENDIX D-Student-t Test on Slopes of Measured vs Calculated Data . APPENDIX E-Statistical Analysis of Four Hour Time- Weighted Average Study on 3. 0 cm Dosimeter VITA ~pa e 42 45 48 59 62 63 65 70 73...

Campbell, James Evan

1977-01-01T23:59:59.000Z

291

Solid–Liquid–Vapor Equilibrium Models for Cryogenic Biogas Upgrading  

Science Journals Connector (OSTI)

In cryogenic upgrading processes involving dry ice formation, accurate predictions of solid–liquid, solid–vapor, and solid–liquid–vapor equilibria are fundamental for a correct design of the heat exchanger surface in order to achieve the desired biomethane purity. ... Moreover, the liquefied biogas production process, particularly interesting for cryogenic upgrading processes due to the low temperature of the obtained biomethane, requires an accurate knowledge of carbon dioxide solubility in liquid methane to avoid solid deposition. ... For some applications demanding a high energy content gas, namely vehicle fuels and injection in the natural gas grid, the biogas has to be upgraded into biomethane. ...

Mauro Riva; Marco Campestrini; Joseph Toubassy; Denis Clodic; Paolo Stringari

2014-10-13T23:59:59.000Z

292

Mass Spectroscopy and Reaction Studies of Laser-Vaporized Clusters from Metal-Doped Carbon Materials  

E-Print Network [OSTI]

C50 + LaC60 + (40) 30 40 50 60 70 Number of Carbon Atoms Intensity(arb.units) (a) Positive La Number of Carbon Atoms Intensity(arbitrary) C43 ­ C44 ­ Mass (amu) LaC32 ­ (a) (b) Fig. 2 Even distribution. 440 460 480 500 36 38 40 42 Number of Carbon Atoms Intensity(arbitrary) (a) as injected (b

Maruyama, Shigeo

293

Epitaxial growth of aligned AlGalnN nanowires by metal-organic chemical vapor deposition  

DOE Patents [OSTI]

Highly ordered and aligned epitaxy of III-Nitride nanowires is demonstrated in this work. <1010> M-axis is identified as a preferential nanowire growth direction through a detailed study of GaN/AlN trunk/branch nanostructures by transmission electron microscopy. Crystallographic selectivity can be used to achieve spatial and orientational control of nanowire growth. Vertically aligned (Al)GaN nanowires are prepared on M-plane AlN substrates. Horizontally ordered nanowires, extending from the M-plane sidewalls of GaN hexagonal mesas or islands demonstrate new opportunities for self-aligned nanowire devices, interconnects, and networks.

Han, Jung (Woodbridge, CT); Su, Jie (New Haven, CT)

2008-08-05T23:59:59.000Z

294

D- PRODUCTION BY MULTIPLE CHARGE-TRANSFER COLLISIONS IN METAL-VAPOR TARGETS  

E-Print Network [OSTI]

li, 1868 (1972)]. A. H. Futch, Jr. and C. C. Damm, Nuc1.H. McFarland and A. H. Futch, Jr. , Phys. Rev. A 1, 1975 (H. McFarland and A. H. Futch, Jr. Proc. VI Int. ConL on

Schlachter, A.S.

2010-01-01T23:59:59.000Z

295

21st Century Locomotive Technology: Quarterly Technical Status Report 21 DOE/AL68284-TSR21  

SciTech Connect (OSTI)

Development of thermal analysis capabilities for a sodium metal halide battery system was initiated.

Lembit Salasoo

2008-04-29T23:59:59.000Z

296

Metal-phosphate binders  

DOE Patents [OSTI]

A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

2009-05-12T23:59:59.000Z

297

Metal Hydrides - Science Needs  

Broader source: Energy.gov (indexed) [DOE]

Storage Grand Challenge Pre-Solicitation Meeting, June 19, 2003 1 Metal Hydrides - Science Needs TRADITIONAL METALLIC HYDRIDES: 1.5 to 2 wt.% H. Well studied. COMPLEX...

298

Probing metal solidification nondestructively  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and...

299

Probing metal solidification nondestructively  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting...

300

Method and making group IIB metal - telluride films and solar cells  

DOE Patents [OSTI]

A technique is disclosed forming thin films (13) of group IIB metal-telluride, such as Cd.sub.x Zn.sub.1-x Te (0.ltoreq.x.ltoreq.1), on a substrate (10) which comprises depositing Te (18) and at least one of the elements (19) of Cd, Zn, and Hg onto a substrate and then heating the elements to form the telluride. A technique is also provided for doping this material by chemically forming a thin layer of a dopant on the surface of the unreacted elements and then heating the elements along with the layer of dopant. A method is disclosed of fabricating a thin film photovoltaic cell which comprises depositing Te and at least one of the elements of Cd, Zn, and Hg onto a substrate which contains on its surface a semiconductor film (12) and then heating the elements in the presence of a halide of the Group IIB metals, causing the formation of solar cell grade Group IIB metal-telluride film and also causing the formation of a rectifying junction, in situ, between the semiconductor film on the substrate and the Group IIB metal-telluride layer which has been formed.

Basol, Bulent M. (Redondo Beach, CA); Kapur, Vijay K. (Northridge, CA)

1990-08-21T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

UNCORRECTEDPROOF 2 Vaporization, fusion and sublimation enthalpies of the  

E-Print Network [OSTI]

UNCORRECTEDPROOF 2 Vaporization, fusion and sublimation enthalpies of the 3 dicarboxylic acids from of Chemistry and Biochemistry, University of Missouri-St. Louis, 8001 Natural Bridge, St. Louis, MO 63121, USA observed previously in the sublimation enthalpies of these compounds. The results are dis- 16 cussed

Chickos, James S.

302

Vapor-side corrosion in thermal desalination plants  

SciTech Connect (OSTI)

This article reports the results of vapor-size corrosion monitoring studies carried out in multistage flash (MSF) desal unit No. 100 of Al-Khafji power and Desalination Plant in Saudi Arabia. Corrosion behavior of 70/30 Cu-Ni alloy, carbon steel (CS), and type 316L stainless steel (SS) was studied in vents and in the vapor size of distillers for 2,000, 4,000, and 9,000 h. Analyses of the experimental data indicated that in addition to O{sub 2}, S-containing compounds evolved during flashing of seawater reacted more with Cu-Ni alloy than with CS and type 316L SS. Explanations for comparatively higher corrosion of alloys exposed to the vapors of the first three (1 to 3) and middle (11 to 13) stages of the MSF plant are given with experimental results. Type 316L SS was found to be the alloy most resistant to vapor-side corrosion in all stages of distillers.

Asrar, N.; Malik, A.U.; Ahmed, S. [Saline Water Conversion Corp. (Saudi Arabia); Al-Khalidi, M.; Al-Moaili, K. [Al-Khafji Desalination Plant (Saudi Arabia)

1999-04-01T23:59:59.000Z

303

Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement  

E-Print Network [OSTI]

This dissertation has two key objectives: the first objective is to develop a method of predicting and quantifying the amount of water that can enter into a pavement system by vapor transport; the second objective is to identify to which extent...

Tong, Yunwei

2013-11-08T23:59:59.000Z

304

The chemical vapor deposition of zirconium carbide onto ceramic substrates  

SciTech Connect (OSTI)

Zirconium carbide is an attractive ceramic material due to its unique properties such as high melting point, good thermal conductivity, and chemical resistance. The controlled preparation of zirconium carbide films of superstoichiometric, stoichiometric, and substoichiometric compositions has been achieved utilizing zirconium tetrachloride and methane precursor gases in an atmospheric pressure high temperature chemical vapor deposition system.

Glass, John A, Jr.; Palmisiano, Nick, Jr.; Welsh, R. Edward

1999-07-01T23:59:59.000Z

305

A transient model for a cesium vapor thermionic converter. [Cs  

SciTech Connect (OSTI)

This paper presents an analytical model for simulating the transient and steady-state operation of cesium vapor thermionic converters. A parametric analysis is performed to assess the transient response of the converter to changes in fission power and width of interelectrode gap. The model optimizes the converter performance for maximum electric power to the load.(AIP)

El-Genk, M.S.; Murray, C.S.; Chaudhuri, S. (Institute for Space Nuclear Power Studies, Department of Chemical and Nuclear Engineering, The University of New Mexico, Albuquerque, New Mexico (USA))

1991-01-10T23:59:59.000Z

306

Experimental Study of Water Vapor Adsorption on Geothermal  

E-Print Network [OSTI]

Geothermal Program under Department of Energy Grant No. DE-FG07-90IDI2934,and by the Department of PetroleumSGP-TR-148 Experimental Study of Water Vapor Adsorption on Geothermal Reservoir Rocks Shubo Shang Engineering, Stanford University Stanford Geothermal Program Interdisciplinary Research in Engineering

Stanford University

307

CVD CNT CNT (Vapor-grown carbon fiber, VGCF)  

E-Print Network [OSTI]

CNT CNT CVD CNT CNT (Vapor-grown carbon fiber, VGCF) 10001300 CNT CVD Smalley CO 24 CCVD 1 #12; 27 mm 3% 200 sccm 800 10 10 Torr 300 sccm Ethanol tank Hot bath boat Ar/H2 Ar or Ethanol tank Hot bath Ethanol tank Hot bath Pressure gauge Maindraintube Subdraintube

Maruyama, Shigeo

308

Sorption and Diffusion of Organic Vapors in Two Fluoroelastomers  

E-Print Network [OSTI]

Sorption and Diffusion of Organic Vapors in Two Fluoroelastomers PING WANG,* NATHANIEL S. SCHNEIDER of II in polar liquids: over 100% (wt/wt) in two ketones and a phosphate ester. Sorption isotherms deter determined from sorption kinetics, corrected for nonisothermal effects, and converted to solvent self

Wang, Ping

309

High-resolution terahertz atmospheric water vapor continuum measurements  

E-Print Network [OSTI]

High-resolution terahertz atmospheric water vapor continuum measurements David M. Slocum,* Thomas M such as pollution monitoring and the detection of energetic chemicals using remote sensing over long path lengths through the atmosphere. Although there has been much attention to atmospheric effects over narrow

Massachusetts at Lowell, University of

310

Method and apparatus to measure vapor pressure in a flow system  

DOE Patents [OSTI]

The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process.

Grossman, Mark W. (Belmont, MA); Biblarz, Oscar (Swampscott, MA)

1991-01-01T23:59:59.000Z

311

Tropical Water Vapor and Cloud Feedbacks in Climate Models: A Further Assessment Using Coupled Simulations  

Science Journals Connector (OSTI)

By comparing the response of clouds and water vapor to ENSO forcing in nature with that in Atmospheric Model Intercomparison Project (AMIP) simulations by some leading climate models, an earlier evaluation of tropical cloud and water vapor ...

De-Zheng Sun; Yongqiang Yu; Tao Zhang

2009-03-01T23:59:59.000Z

312

Metalorganic chemical vapor deposition of carbon-free ZnO using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Metalorganic chemical vapor deposition of carbon-free ZnO using the bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc precursor. Metalorganic chemical vapor deposition of carbon-free...

313

Calculation of rate constants for dissociative attachment of low-energy electrons to hydrogen halides HCl, HBr, and HI and their deuterated analogs  

Science Journals Connector (OSTI)

Calculations of rate constants for the process of dissociative attachment of low-energy electrons to hydrogen halides HCl, HBr, and HI and for the reverse process of associative detachment based on the nonlocal resonance model are reported. The calculated data are of importance for the modeling of plasma processes, environmental chemistry, etc. The calculated dissociative attachment rate constants are found to be in good agreement with existing experimental data. It is shown that at low temperatures the rate constants are very sensitive to small changes of the parameters of the nonlocal resonance model used for the calculation of the rate constants and represent a severe test of the theory. The isotopic effect and its dependence on the temperature is also discussed. The calculations of rate constants for the reverse process of associative detachment are also reported and discussed.

Karel Houfek; Martin ?ížek; Ji?í Horá?ek

2002-12-06T23:59:59.000Z

314

Effects of stereochemistry and ?-substituents on the rates of vinylic SN2 reaction of hypervalent vinyl(phenyl)-?3-iodanes with tetrabutylammonium halides  

Science Journals Connector (OSTI)

Both stereoisomers of ?-(2-phenylethoxy)vinyl-?3-iodane and (Z)-?-aroyloxyvinyl-?3-iodane were prepared stereoselectively. These substituted vinyl-?3-iodanes undergo nucleophilic vinylic substitutions with n-Bu4NX (X=Cl, Br, I) under mild conditions, yielding vinyl halides. The observed inversion of configuration at the ipso vinylic carbon atom is compatible with a concerted vinylic SN2 mechanism. Kinetic measurements indicated that the rates for vinylic SN2 reaction of (Z)-vinyl-?3-iodane are greater than those of the E-isomer, probably because of the higher ground state energy of the Z-isomer. Electronic effects of ?-substituents of vinyl-?3-iodanes in the vinylic SN2 reaction are also discussed.

Kazunori Miyamoto; Takuji Okubo; Masaya Hirobe; Munetaka Kunishima; Masahito Ochiai

2010-01-01T23:59:59.000Z

315

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

316

Supersonic Bare Metal Cluster Beams. Final Report  

DOE R&D Accomplishments [OSTI]

A major portion of the project involved elucidating the relation between reactivity and the electronic structure of transition-metal (TM) clusters of 2--200 atoms, which required the construction and continuous development of two principal apparati; the Fourier Transform-Ion Cyclotron Resonance (FT-ICR) apparatus, and Ultraviolet Photoelectron Spectroscopy (UPS). Together, these machines have enabled the most detailed probing of the structure and chemical reactivity of TM clusters. Clusters of all the transition metals were included in these studies. Fundamental aspects in chemisorption, reactivity, and heterogeneous catalysis have also become better understood as a result of these experiments for important classes of systems such as H{sub 2}, CO, and CO{sub 2} adsorbed onto clusters of many of the metals listed above. In particular, a correlation was found between reactivity of H{sub 2} with Fe, Co, and Ni clusters and differences between the cluster IP and EA. As recounted in a previous technical report, the DOE`s role in the initial discovery of fullerenes at Rice was central, and from the start investigations were made into metal atoms trapped in the fullerenes cage. More recently, the authors have discovered that 2--4 atoms of La, Y, or Sc can be produced by laser vaporization of composite graphite/metal-oxide disks. This work was largely motivated by the prospects of using such endohedral TM metals for their catalytic activity without the well-known difficulties of effective support media and lack of control over particle size. Thus, while it will certainly be important to discover ways to efficiently scale up production (e.g., the solar generation method explored with DOE support), the efforts have concentrated more on characterization, purification, and manipulation of doped fullerenes. For the past two years, much of the group`s effort has involved the production, purification, and characterization of carbon nanotubes.

Smalley, R. E.

1997-10-14T23:59:59.000Z

317

Economic and Technical Tradeoffs Between Open and Closed Cycle Vapor Compression Evaporators  

E-Print Network [OSTI]

and solute. Evaporation tends to be a very energy intensive process. Approximately 1000 BTUs of energy are required to vaporize one pound of water. Many techniques have been developed to reuse energy Within an evaporation system so as to vaporize... Recompression A schematic of an open cycle vapor recompression evaporator is shown in Figure 2. This method uses the vapor in an open cycle for both heating and cooling. Rather than being condensed after the last effect, steam is compressed to a slightly...

Timm, M. L.

318

Quantitative Analysis of Ternary Vapor Mixtures Using a Microcantilever-Based Electronic Nose  

SciTech Connect (OSTI)

The authors report the identification and quantification of the components of a ternary vapor mixture using a microcantilever-based electronic nose. An artificial neural network was used for pattern recognition. Dimethyl methyl phosphonate vapor in ppb concentrations and water and ethanol vapors in ppm concentrations were quantitatively identified either individually or in binary and ternary mixtures at varying concentrations.

Pinnaduwage, Lal A [ORNL; Zhao, Weichang [ORNL; Gehl, Anthony C [ORNL; Allman, Steve L [ORNL

2007-01-01T23:59:59.000Z

319

Sample Vapor Introduction Techniques for Use with Cryofocusing GC Inlet Systems  

Science Journals Connector (OSTI)

......the vapor generator was operated at atmospheric pressure for...condensed water. Other studies...Because the water vapor was...tail of the water peak. Thus...obtained from an atmospheric pressure source...the vapor generator over a 1......

Christine L. Rankin; Richard D. Sacks

1994-01-01T23:59:59.000Z

320

Measurements of atmospheric water vapor above Mauna Kea using an infrared radiometer  

E-Print Network [OSTI]

Measurements of atmospheric water vapor above Mauna Kea using an infrared radiometer David A in atmospheric water vapor that distort the phase coherence of incoming celestial signals. The signal received water vapor, this paper presents results obtained with a second generation IRMA operating at the James

Naylor, David A.

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Studies of metal/carbon surface chemistry. June 1, 1985-August 31, 1985  

SciTech Connect (OSTI)

The purpose of this research is to identify stable surface species formed from molecular adsorption and reaction on metal/carbon surfaces. This research has practical application in improving the fundamental understanding of catalytic coal gasification. Well-defined model catalysts for carbon gasification will be studied by vapor depositing alkali and transition metal atoms on carbon surfaces. Vibrational spectroscopy using HREELS and photoelectron spectroscopy of these surfaces will be used to develop an atomic-level understanding of the chemical bonding, structure, and reactivity of the metal carbon surface and of the adsorbed molecular species. 1 fig.

Koel, B.E.

1985-09-30T23:59:59.000Z

322

Controlled incorporation of mid-to-high Z transition metals in CVD diamond  

SciTech Connect (OSTI)

We report on a general method to fabricate transition metal related defects in diamond. Controlled incorporation of Mo and W in synthetic CVD diamond was achieved by adding volatile metal precursors to the diamond chemical vapor deposition (CVD) growth process. Effects of deposition temperature, grain structure and precursor exposure on the doping level were systematically studied, and doping levels of up to 0.25 at.% have been achieved. The metal atoms are uniformly distributed throughout the diamond grains without any indication of inclusion formation. These results are discussed in context of the kinetically controlled growth process of CVD diamond.

Biener, M M; Biener, J; Kucheyev, S O; Wang, Y M; El-Dasher, B; Teslich, N E; Hamza, A V; Obloh, H; Mueller-Sebert, W; Wolfer, M; Fuchs, T; Grimm, M; Kriele, A; Wild, C

2010-01-08T23:59:59.000Z

323

Ambient air monitoring for organic compounds, acids, and metals at Los Alamos National Laboratory, January 1991  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) contracted Radian Corporation (Radian) to conduct a short-term, intensive air monitoring program whose goal was to estimate the impact of chemical emissions from LANL on the ambient air environment. A comprehensive emission inventory had identified more than 600 potential air contaminants in LANL's emissions. A subset of specific target chemicals was selected for monitoring: 20 organic vapors, 6 metals and 5 inorganic acid vapors. These were measured at 5 ground level sampling sites around LANL over seven consecutive days in January 1991. The sampling and analytical strategy used a combination of EPA and NIOSH methods modified for ambient air applications.

Williams, C.H. (Radian Corp., Austin, TX (United States)); Eberhart, C.F. (Los Alamos National Lab., NM (United States))

1992-01-01T23:59:59.000Z

324

Ambient air monitoring for organic compounds, acids, and metals at Los Alamos National Laboratory, January 1991  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) contracted Radian Corporation (Radian) to conduct a short-term, intensive air monitoring program whose goal was to estimate the impact of chemical emissions from LANL on the ambient air environment. A comprehensive emission inventory had identified more than 600 potential air contaminants in LANL`s emissions. A subset of specific target chemicals was selected for monitoring: 20 organic vapors, 6 metals and 5 inorganic acid vapors. These were measured at 5 ground level sampling sites around LANL over seven consecutive days in January 1991. The sampling and analytical strategy used a combination of EPA and NIOSH methods modified for ambient air applications.

Williams, C.H. [Radian Corp., Austin, TX (United States); Eberhart, C.F. [Los Alamos National Lab., NM (United States)

1992-10-01T23:59:59.000Z

325

Heavy metal biosensor  

DOE Patents [OSTI]

Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

2014-04-15T23:59:59.000Z

326

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

327

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

328

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

329

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

330

C-CAMP, A closed cycle alkali metal power system  

SciTech Connect (OSTI)

A concept is presented for a Closed-Cycle Alkali Metal (C-CAMP) power systems which utilizes the heat of reaction of an alkali metal and halogen compound to vaporize an alkali metal turbine fluid for a Rankine cycle. Unique features of the concept are (1) direct contact (heat exchange) between the reaction products and turbine fluid, and (2) a flow-through chemical reactor/boiler. The principal feasibility issues of the concept relate to the degree of cross-mixing of product and turbine fluid streams within the reactor-boiler. If proven feasible, the concept may be adapted to a range of fuel and turbine fluids and ultimately lead to thermal efficiencies in excess of 35%.

Wichner, R.P.; Hoffman, H.W.

1988-01-01T23:59:59.000Z

331

Carbide and carbonitride surface treatment method for refractory metals  

DOE Patents [OSTI]

A carbide and carbonitride surface treatment method for refractory metals is provided, in steps including, heating a part formed of boron, chromium, hafnium, molybdenum, niobium, tantalum, titanium, tungsten or zirconium, or alloys thereof, in an evacuated chamber and then introducing reaction gases including nitrogen and hydrogen, either in elemental or water vapor form, which react with a source of elemental carbon to form carbon-containing gaseous reactants which then react with the metal part to form the desired surface layer. Apparatus for practicing the method is also provided, in the form of a carbide and carbonitride surface treatment system including a reaction chamber, a source of elemental carbon, a heating subassembly and a source of reaction gases. Alternative methods of providing the elemental carbon and the reaction gases are provided, as well as methods of supporting the metal part, evacuating the chamber with a vacuum subassembly and heating all of the components to the desired temperature. 5 figs.

Meyer, G.A.; Schildbach, M.A.

1996-12-03T23:59:59.000Z

332

High efficiency particulate removal with sintered metal filters  

SciTech Connect (OSTI)

Because of their particle removal efficiencies and durability, sintered metal filters have been chosen for high efficiency particulate air (HEPA) filter protection in the off-gas treatment system for the proposed Idaho National Engineering Laboratory Transuranic Waste Treatment Facility. Process evaluation of sintered metal filters indicated a lack of sufficient process design data to ensure trouble-free operation. Subsequence pilot scale testing was performed with flyash as the test particulate. The test results showed that the sintered metal filters can have an efficiency greater than 0.9999999 for the specific test conditions used. Stable pressure drop characteristics were observed in pulsed and reversed flow blowback modes of operation. Over 4900 hours of operation were obtained with operating conditions ranging up to approximately 90/sup 0/C and 24 vol % water vapor in the gas stream.

Kirstein, B.E.; Paplawsky, W.J.; Pence, D.T.; Hedahl, T.G.

1981-01-01T23:59:59.000Z

333

Process for producing enriched uranium having a {sup 235}U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage  

DOE Patents [OSTI]

An uranium enrichment process capable of producing an enriched uranium, having a {sup 235}U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower {sup 235}U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF{sub 6} tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a {sup 235} U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % {sup 235} U; fluorinating this enriched metallic uranium isotopic mixture to form UF{sub 6}; processing the resultant isotopic mixture of UF{sub 6} in a gaseous diffusion process to produce a final enriched uranium product having a {sup 235}U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low {sup 235}U content UF{sub 6} having a {sup 235}U content of about 0.71 wt. % of the total uranium content of the low {sup 235}U content UF{sub 6}; and converting this low {sup 235}U content UF{sub 6} to metallic uranium for recycle to the atomic vapor laser isotope separation process. 4 figs.

Horton, J.A.; Hayden, H.W. Jr.

1995-05-30T23:59:59.000Z

334

Process for producing enriched uranium having a .sup.235 U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage  

DOE Patents [OSTI]

An uranium enrichment process capable of producing an enriched uranium, having a .sup.235 U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower .sup.235 U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF.sub.6 tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a .sup.235 U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % .sup.235 U; fluorinating this enriched metallic uranium isotopic mixture to form UF.sub.6 ; processing the resultant isotopic mixture of UF.sub.6 in a gaseous diffusion process to produce a final enriched uranium product having a .sup.235 U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low .sup.235 U content UF.sub.6 having a .sup.235 U content of about 0.71 wt. % of the total uranium content of the low .sup.235 U content UF.sub.6 ; and converting this low .sup.235 U content UF.sub.6 to metallic uranium for recycle to the atomic vapor laser isotope separation process.

Horton, James A. (Livermore, CA); Hayden, Jr., Howard W. (Oakridge, TN)

1995-01-01T23:59:59.000Z

335

Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mokapu Penninsula Area (Thomas, 1986) Mokapu Penninsula Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) Exploration Activity Details Location Mokapu Penninsula Area Exploration Technique Mercury Vapor Activity Date Usefulness not useful DOE-funding Unknown Notes The high degree of cultural activity (e.g. residential areas, streets, jet runways, etc.) on Mokapu both limited the extent of the soil geochemical surveys performed and rendered their interpretation much more difficult. Soil mercury concentrations and radon emanometry data on the peninsula showed a few localized high values (Figs 13, 14), but no consistent correlation between the anomalous zones and geologic features could be

336

Detonation wave driven by condensation of supersaturated carbon vapor  

Science Journals Connector (OSTI)

An experimental observation of a detonation wave driven by the energy of condensation of supersaturated carbon vapor is reported. The carbon vapor was formed by the thermal decay of unstable carbon suboxide C3O2 behind shock waves in mixtures containing 10–30% C3O2 in Ar. In the mixture 10% C3O2+Ar the insufficient heat release resulted in a regime of overdriven detonation. In the mixture 20% C3O2+Ar measured values of the pressure and wave velocity coincident with calculated Chapman-Jouguet parameters were attained. In the richest mixture 30% C3O2+Ar an excess heat release caused the slowing down of the condensation rate and the regime of underdriven detonation was observed.

A. Emelianov; A. Eremin; V. Fortov; H. Jander; A. Makeich; H. Gg. Wagner

2009-03-10T23:59:59.000Z

337

Heat Recovery in Distillation by Mechanical Vapor Recompression  

E-Print Network [OSTI]

be classified generally into two types,.aerodynamic and positive displacement (Figure 5). Among the various types of compressors, centrifugal, reciprocating, lobe and screw have been used for vapor recompression. I AXIAL AERODYNAMIC I I CENTRIFUGAL I... speeds of centri fugal compressors make them highly susceptible to erosion from entrained liquid droplets. This ero sion can reduce the efficiency and cause dynamic instability from rotor imbalance and mechanical failure. Next, it is important...

Becker, F. E.; Zakak, A. I.

338

Methanol vaporization and injection system for internal combustion engine  

SciTech Connect (OSTI)

An engine equipped with an alcohol vaporization injection system operates as a four stroke cycle diesel engine that transfers the heat of exiting exhaust gases and cylinder head walls to the fuel. The engine runs on alcohol. The alcohol becomes vaporized and its pressure is high enough so that when a valve is opened between the high pressure fuel line and the combustion chamber (when it is at the peak of its compression ratio) enough alcohol will enter the combustion chamber to allow proper combustion. The overall advantages to this type of alcohol vaporization injection system is that it adds relatively few new mechanisms to the spark ignition four cycle internal combustion engine to enable it to operate as a diesel engine with a high thermal efficiency. This alcohol injection system exploits the engine's need for greater volumes of alcohol caused by the alcohol's relatively low heat of combustion (When compared to gasoline) by using this greater volume of fuel to return greater quantities of heat back to the engine to a much greater degree than other fuels can.

Bayley, R.I.

1980-05-06T23:59:59.000Z

339

Program plan for the resolution of tank vapor issues  

SciTech Connect (OSTI)

Since 1987, workers at the Hanford Site waste tank farms in Richland, Washington, have reported strong odors emanating from the large, underground high-level radioactive waste storage tanks. Some of these workers have complained of symptoms (e.g., headaches, nausea) related to the odors. In 1992, the U.S. Department of Energy, which manages the Hanford Site, and Westinghouse Hanford Company determined that the vapor emissions coming from the tanks had not been adequately characterized and represented a potential health risk to workers in the immediate vicinity of the tanks. At that time, workers in certain areas of the tank farms were required to use full-face, supplied-breathing-air masks to reduce their exposure to the fugitive emissions. While use of supplied breathing air reduced the health risks associated with the fugitive emissions, it introduced other health and safety risks (e.g., reduced field of vision, air-line tripping hazards, and heat stress). In 1992, an aggressive program was established to assure proper worker protection while reducing the use of supplied breathing air. This program focuses on characterization of vapors inside the tanks and industrial hygiene monitoring in the tank farms. If chemical filtration systems for mitigation of fugitive emissions are deemed necessary, the program will also oversee their design and installation. This document presents the plans for and approach to resolving the Hanford Site high-level waste tank vapor concerns. It is sponsored by the Department of Energy Office of Environmental Restoration and Waste Management.

Osborne, J.W.; Huckaby, J.L.

1994-05-01T23:59:59.000Z

340

Metal-Air Batteries  

SciTech Connect (OSTI)

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Bis(pentamethylcyclopentadienyl) ytterbium: Electron-transfer reactions with organotransition metal complexes  

SciTech Connect (OSTI)

The divalent lanthanide complex, (Me{sub 5}C{sub 5}){sub 2}Yb, reacts with methylcopper to produce the base-free, ytterbium-methyl complex, (Me{sub 5}C{sub 5}){sub 2}YbMe. This product forms a asymmetric, methyl-bridged dimer in the solid state. The bulky alkyl complex, (Me{sub 5}C{sub 5}){sub 2}YbCH(SiMe{sub 3}){sub 2}, displays similar chemistry to (Me{sub 5}C{sub 5}){sub 2}YbMe, but at a reduced reaction rate due to the limited accessibility of the metal in (Me{sub 5}C{sub 5}){sub 2}YbCH(SiMe{sub 3}){sub 2}. Copper and silver halide salts react with (Me{sub 5}C{sub 5}){sub 2}V to produce the trivalent halide derivatives, (Me{sub 5}C{sub 5}){sub 2}VX (X + F, Cl, Br, I). The chloride complex, (Me{sub 5}C{sub 5}){sub 2}VCl, reacts with lithium reagents to form the phenyl and borohydride species. Nitrous oxide transfers an oxygen atom to (Me{sub 5}C{sub 5}){sub 2}V producing the vanadium-oxo complex, (Me{sub 5}Ce{sub 5}){sub 2}VO. The trivalent titanium species, (Me{sub 5}C{sub 5}){sub 2}TiX (X = Cl, Br, Me, BH{sub 4}), form bimetallic coordination complexes with (Me{sub 5}C{sub 5}){sub 2}Yb. The magnetic behavior of the products indicates that electron transfer has not occurred. The solid state structures of the chloride and bromide complexes show unusual bend angles for the halide bridges between ytterbium and titanium. A model based on frontier orbital theory has been proposed to account for the bending behavior in these species. The bimetallic methyl complex contains a linear methyl bridge between ytterbium and titanium.

Matsunaga, P.T.

1991-11-01T23:59:59.000Z

342

The influence of prestrained metalorganic vapor phase epitaxial gallium-nitride templates on hydride vapor phase epitaxial growth  

Science Journals Connector (OSTI)

We have varied the strain situation in metalorganic vapor phase epitaxial (MOVPE) grown gallium-nitride (GaN) by exchanging the nucleation layer and by inserting a submono-Si x N y -interlayer in the first few hundred nanometers of growth on sapphire substrates. The influence on the MOVPE template and subsequent hydride vapor phase epitaxial (HVPE) growth could be shown by in-situ measurements of the sample curvature. Using the results of these investigations we have established a procedure to confine the curvature development in MOVPE and HVPE growth to a minimum. By increasing the layer thickness in HVPE we could create self-separated freestanding GaN layers with small remaining curvature.

2014-01-01T23:59:59.000Z

343

Tank 241-TX-118 headspace gas and vapor characterization results for samples collected in September 1994 and December 1994  

SciTech Connect (OSTI)

Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories

Huckaby, J.L. [Pacific Northwest Lab., Richland, WA (United States); Bratzel, D.R. [Westinghouse Hanford Co., Richland, WA (United States)

1995-09-27T23:59:59.000Z

344

Synthesis Of Fluorescent Metal Nanoclusters  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthesis Of Fluorescent Metal Nanoclusters Synthesis Of Fluorescent Metal Nanoclusters Fluorescent metal nanoclusters were prepared. Available for thumbnail of Feynman Center...

345

Metal phthalocyanine catalysts  

DOE Patents [OSTI]

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

346

Headspace vapor characterization of Hanford Waste Tank 241-T-110: Results from samples collected on August 31, 1995. Tank Vapor Characterization Project  

SciTech Connect (OSTI)

This report describes the results of vapor samples taken from the headspace of waste storage tank 241-T-110 (Tank T-110) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) contracted with Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for inorganic and organic analytes collected from the tank headspace and ambient air near the tank. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Tank Vapor Characterization Project. Work performed was based on a sample and analysis plan (SAP) prepared by WHC. The SAP provided job-specific instructions for samples, analyses, and reporting. The SAP for this sample job was {open_quotes}Vapor Sampling and Analysis Plan{close_quotes}, and the sample job was designated S5056. Samples were collected by WHC on August 31, 1995, using the Vapor Sampling System (VSS), a truck-based sampling method using a heated probe inserted into the tank headspace.

McVeety, B.D.; Thomas, B.L.; Evans, J.C. [and others

1996-05-01T23:59:59.000Z

347

Formation of Nickel Silicide from Direct-liquid-injection Chemical-vapor-deposited Nickel Nitride Films  

SciTech Connect (OSTI)

Smooth, continuous, and highly conformal nickel nitride (NiN{sub x}) films were deposited by direct liquid injection (DLI)-chemical vapor deposition (CVD) using a solution of bis(N,N{prime}-di-tert-butylacetamidinato)nickel(II) in tetrahydronaphthalene as the nickel (Ni) source and ammonia (NH{sub 3}) as the coreactant gas. The DLI-CVD NiNx films grown on HF-last (100) silicon and on highly doped polysilicon substrates served as the intermediate for subsequent conversion into nickel silicide (NiSi), which is a key material for source, drain, and gate contacts in microelectronic devices. Rapid thermal annealing in the forming gas of DLI-CVD NiNx films formed continuous NiSi films at temperatures above 400 C. The resistivity of the NiSi films was 15{mu}{Omega} cm, close to the value for bulk crystals. The NiSi films have remarkably smooth and sharp interfaces with underlying Si substrates, thereby producing contacts for transistors with a higher drive current and a lower junction leakage. Resistivity and synchrotron X-ray diffraction in real-time during annealing of NiNx films showed the formation of a NiSi film at about 440 C, which is morphologically stable up to about 650 C. These NiSi films could find applications in future nanoscale complementary metal oxide semiconductor devices or three-dimensional metal-oxide-semiconductor devices such as Fin-type field effect transistors for the 22 nm technology node and beyond.

Li, Z.; Gordon, R; Li, H; Shenai, D; Lavoie, C

2010-01-01T23:59:59.000Z

348

Final Report for ARM Project Measuring 4-D Water Vapor Fields with GPS  

SciTech Connect (OSTI)

Water vapor is a primary element in the Earth’s climate system. Atmospheric water vapor is central to cloud processes, radiation transfer, and the hydrological cycle. Using funding from Department of Energy (DOE) grant DE-FG03-02ER63327, the University Corporation for Atmospheric Research (UCAR) developed new observational techniques to measure atmospheric water vapor and applied these techniques to measure four dimensional water vapor fields throughout the United States Southern Great Plains region. This report summarizes the development of a new observation from ground based Global Positioning System (GPS) stations called Slant Water Vapor (SW) and it’s utilization in retrieving four dimensional water vapor fields. The SW observation represents the integrated amount of water vapor between a GPS station and a transmitting satellite. SW observations provide improved temporal and spatial sampling of the atmosphere when compared to column-integrated quantities such as preciptitable water vapor (PW). Under funding from the DOE Atmospheric Radiation Measurement (ARM) program, GPS networks in the Southern Great Plains (SGP) region were deployed to retrieve SW to improve the characterization of water vapor throughout the region. These observations were used to estimate four dimensional water vapor fields using tomographic approaches and through assimilation into the MM5 numerical weather model.

Braun, John

2006-02-06T23:59:59.000Z

349

MECS 2006- Fabricated Metals  

Broader source: Energy.gov [DOE]

Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006)

350

Emitter tests in an open thermionic converter with vapor injection through the collector  

SciTech Connect (OSTI)

Mo and Pt emitters and a Ni collector with 400 laser-bored holes were used in an ''open'' thermionic converter. The alkali vapor was introduced into the converter through the array of holes in the collector from an adjacent alkali metal reservoir with separately controlled temperature. The overall results from the open thermionic converter are comparable to results from enclosed converters. The results found with a Cs plasma are encouraging, with barrier indices down to below 1.8 eV, at emitter temperatures around 1500 K in the case of a Mo emitter. The output power density was around 3.5 W cm/sup -2/. In the case of a Pt emitter, both Cs and K plasmas were used, with power densities up to 5.7 and 1.8 W cm/sup -2/, respectively close to 1800 K. The structure of the laser-bored collector may have contributed to these results, as well as the efficient removal of impurities in the ''open'' converter.

Wriedt, S.; Moeller, K.; Holmlid, L.

1986-12-15T23:59:59.000Z

351

Deposition of Contiguous Metal Adlayer on Transition Metal Nanostructu...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Abstract Primary Lab Date Application 20100099012 Application 20100099012 Electrocatalyst Synthesized by Depositing a Contiguous Metal Adlayer on Transition Metal...

352

Progress in transition metal-based enantioselective catalysis  

E-Print Network [OSTI]

In Chapter 1, the first enantioselective cross-coupling reactions of racemic secondary benzylic halides are described (eq 1). This method was applied to the syntheses of intermediates employed by other groups in the ...

Arp, Forrest O

2008-01-01T23:59:59.000Z

353

4f-derived photoemission and 4f-ligand hybridization in light rare-earth halides  

Science Journals Connector (OSTI)

We have studied the 4f-derived photoemission spectra of insulating Ce, Pr, and Nd trihalides by resonant photoemission spectroscopy. A double-peak structure is observed in every f spectrum as in metallic Ce, Pr, and Nd compounds and is successfully analyzed in terms of the cluster model. This confirms that the two peaks arise from hybridization between the 4f and ligand p orbitals rather than from two different screening channels of the f hole. The f-ligand hybridization strength is found to decrease on going from the Ce to Pr to Nd compounds, but appears to remain significantly large for heavier rare earths, suggesting the importance of hybridization effects in heavy rare-earth compounds.

A. Fujimori; T. Miyahara; T. Koide; T. Shidara; H. Kato; H. Fukutani; S. Sato

1988-10-15T23:59:59.000Z

354

Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage  

SciTech Connect (OSTI)

Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

2014-08-01T23:59:59.000Z

355

Pulsed laser irradiation of metal multilayers.  

SciTech Connect (OSTI)

Vapor-deposited, exothermic metal-metal multilayer foils are an ideal class of materials for detailed investigations of pulsed laser-ignited chemical reactions. Created in a pristine vacuum environment by sputter deposition, these high purity materials have well-defined reactant layer thicknesses between 1 and 1000 nm, minimal void density and intimate contact between layers. Provided that layer thicknesses are made small, some reactive metal-metal multilayer foils can be ignited at a point by laser irradiation and exhibit subsequent high-temperature, self-propagating synthesis. With this presentation, we describe the pulsed laser-induced ignition characteristics of a single multilayer system (equiatomic Al/Pt) that exhibits self-propagating synthesis. We show that the thresholds for ignition are dependent on (i) multilayer design and (ii) laser pulse duration. With regard to multilayer design effects on ignition, there is a large range of multilayer periodicity over which ignition threshold decreases as layer thicknesses are made small. We attribute this trend of decreased ignition threshold to reduced mass transport diffusion lengths required for rapid exothermic mixing. With regard to pulse duration effects, we have determined how ignition threshold of a single Al/Pt multilayer varies with pulse duration from 10{sup -2} to {approx} 10{sup -13} sec (wavelength and spot size are held constant). A higher laser fluence is required for ignition when using a single laser pulse {approx} 100 fs or 1 ps compared with nanosecond or microsecond exposure, and we attribute this, in part, to the effects of reactive material being ablated when using the shorter pulse durations. To further understand these trends and other pulsed laser-based processes, our discussion concludes with an analysis of the heat-affected depths in multilayers as a function of pulse duration.

Adams, David Price; McDonald, Joel Patrick

2010-11-01T23:59:59.000Z

356

Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity Details Location Salt Wells Area Exploration Technique Mercury Vapor Activity Date - 2005 Usefulness useful DOE-funding Unknown Exploration Basis Adsorbed mercury soil geochemical surveys and radiometric geophysical surveys were carried out in conjunction with geologic mapping to test the application of these ground-based techniques to geothermal exploration at three prospects in Nevada by Henkle Jr. et al. in 2005. Mercury soil vapor surveys were not widely used in geothermal exploration in the western US at the time, although the association of mercury vapors with geothermal

357

MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN THE ARCTIC Cadeddu, Maria Argonne National Laboratory Category: Instruments A new G-band (183 GHz) vapor radiometer (GVR), developed and built by Prosensing Inc. (http://www.prosensing.com), was deployed in Barrow, Alaska, in April 2005. The radiometer was deployed as part of the ongoing Atmospheric Radiation Measurement (ARM) program's effort to improve water vapor retrievals in the cold, dry Arctic environment. The instrument measures brightness temperatures from four double sideband channels centered at 1, 3, 7, and 14 GHz from the 183.31-GHz water vapor line. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. The GVR will remain in Barrow

358

Effect of potassium halide salts on mutual solubility of water + aromatic hydrocarbons liquid–liquid interface studied with surface and interfacial tensions  

Science Journals Connector (OSTI)

Abstract Surface tension (?, mN/m) of benzene, toluene and ethylbenzene (EB) aromatic hydrocarbons (AHCs, low density liquids, LDL) and interfacial tension (IFT, mN/m) both with water and aqueous 0.1, 0.5, 1.0 mol kg? 1 KF, KCl, KBr, KI (high density liquids, HDL) separately at 303.15 K are reported. Contributions of –CH3 and –CH2CH3 of toluene and EB to hydrophobic interactions are calculated from ?toluene–?benzene and ?EB–?benzene, respectively. \\{IFTs\\} of water + AHCs liquid–liquid interfaces (LLI) are as toluene (34.71) > EB (32.35) > benzene (32.32 mN m? 1), with a ~ 32.32 mN m? 1 decrease from 71.40 mN m? 1 of water. \\{AHCs\\} with hyperconjugation (HC) and positive inductive effects (+ ve IE) with toluene and EB LLI have reduced IFT by 39.08, 2.39, ? 1.56 mN m? 1, respectively. The effects of ?-conjugation, –H, –CH3 and –CH2CH3 on surface tension are calculated as ?-conjugation = ?(IFTair–liquid ? IFTAPHS–benzene), –CH3 = ?(IFTAPHS–toluene ? IFTAPHS–benzene). The effects of halide salts on hypercongugation –H(–CH3)/3, –CH2CH3 are obtained from ?(IFTAPHS–EB ? IFTAPHS–benzene).

Man Singh

2014-01-01T23:59:59.000Z

359

Chemical vapor deposition of amorphous semiconductor films. Final subcontract report  

SciTech Connect (OSTI)

Chemical vapor deposition (CVD) from higher order silanes has been studied for fabricating amorphous hydrogenated silicon thin-film solar cells. Intrinsic and doped a-Si:H films were deposited in a reduced-pressure, tubular-flow reactor, using disilane feed-gas. Conditions for depositing intrinsic films at growth rates up to 10 A/s were identified. Electrical and optical properties, including dark conductivity, photoconductivity, activation energy, optical absorption, band-gap and sub-band-gap absorption properties of CVD intrinsic material were characterized. Parameter space for depositing intrinsic and doped films, suitable for device analysis, was identified.

Rocheleau, R.E.

1984-12-01T23:59:59.000Z

360

A thermoacoustic oscillator powered by vaporized water and ethanol  

Science Journals Connector (OSTI)

We measure the temperature difference required to drive a thermoacoustic oscillator containing air water vapor and liquid water as the working fluids. The oscillator is composed of a large tube containing an array of narrow tubes connected at one end to a tank of liquid water. When the water is heated the temperature difference across the tube array increases until thermoacoustic oscillations occur. The temperature difference at the onset of oscillation is measured to be 56 ? ° C significantly smaller (by ? 200 ? ° C ) than the temperature measured when the tank is filled with dry air instead of water. The temperature difference can be further reduced to 47 ? ° C by using ethanol instead of water.

Daisuke Noda; Yuki Ueda

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Io - Are vapor explosions responsible for the 5-micron outbursts  

SciTech Connect (OSTI)

It is proposed that a vapor explosion of a submerged pool of liquid sulfur will remove the crust overlying an area of about 50-km diam. Thermal radiation from the exposed liquid sulfur pool with a surface temperature of 600 K is then presumed to be responsible for the 5-micron outbursts that have been observed. The explosive volcanoes are expected to leave black sulfur calderas, which are, indeed, found on the surface. The 5-micron outburst observed by Sinton (1980), on June 11, 1979 (UT), is identified with a new caldera found on Voyager 2 photographs but which had not been present on Voyager 1 pictures.

Sinton, W.M.

1980-01-01T23:59:59.000Z

362

Optical waveguides in SBN by zinc vapor diffusion  

E-Print Network [OSTI]

at 600'C for a 12. 5 i1m Wide 1000'C Zinc Vapor Diffused SBN:60 Waveguide Measured at X = 0. 81 pm. IV. SBN:60 Amplitude Modulator Results . . . . . V. SBN:60 Mach-Zehnder Interferometer Results. . . . VI. Voltage-Length Product Comparison...: (a) extraordinary (TM), (b) 1. 5 x ordinary (TE). 12. Surface damage on SBN:60 diffused at 1000'C with an SiOz diffusion mask. 13. Zinc in-diffusion in SBN:60 25 . . . . . 26 . . . . . 27 . . . . . 28 29 14. Barium out-diffuison in SBN:60...

Quinn, Jeffrey Dale

1991-01-01T23:59:59.000Z

363

Combustion chemical vapor deposited coatings for thermal barrier coating systems  

SciTech Connect (OSTI)

The new deposition process, combustion chemical vapor deposition, shows a great deal of promise in the area of thermal barrier coating systems. This technique produces dense, adherent coatings, and does not require a reaction chamber. Coatings can therefore be applied in the open atmosphere. The process is potentially suitable for producing high quality CVD coatings for use as interlayers between the bond coat and thermal barrier coating, and/or as overlayers, on top of thermal barrier coatings. In this report, the evaluation of alumina and ceria coatings on a nickel-chromium alloy is described.

Hampikian, J.M.; Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States). School of Materials Science and Engineering

1995-12-31T23:59:59.000Z

364

Unusual thermopower of inhomogeneous graphene grown by chemical vapor deposition  

SciTech Connect (OSTI)

We report on thermopower (TEP) and resistance measurements of inhomogeneous graphene grown by chemical vapor deposition (CVD). Unlike the conventional resistance of pristine graphene, the gate-dependent TEP shows a large electron-hole asymmetry. This can be accounted for by inhomogeneity of the CVD-graphene where individual graphene regions contribute with different TEPs. At the high magnetic field and low temperature, the TEP has large fluctuations near the Dirac point associated with the disorder in the CVD-graphene. TEP measurements reveal additional characteristics of CVD-graphene, which are difficult to obtain from the measurement of resistance alone.

Nam, Youngwoo, E-mail: youngwoo.nam@chalmers.se [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Sun, Jie; Lindvall, Niclas; Yurgens, August [Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Jae Yang, Seung; Rae Park, Chong [Department of Materials Science and Engineering, Seoul National University, Seoul 151-747 (Korea, Republic of); Woo Park, Yung [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of)

2014-01-13T23:59:59.000Z

365

Dosimeter for monitoring vapors and aerosols of organic compounds  

DOE Patents [OSTI]

A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

Vo-Dinh, T.

1987-07-14T23:59:59.000Z

366

The Prospects of Alternatives to Vapor Compression Technology for Space Cooling and Food Refrigeration Applications  

SciTech Connect (OSTI)

Five alternatives to vapor compression technology were qualitatively evaluated to determine their prospects for being better than vapor compression for space cooling and food refrigeration applications. The results of the assessment are summarized in the report. Overall, thermoacoustic and magnetic technologies were judged to have the best prospects for competing with vapor compression technology, with thermotunneling, thermoelectric, and thermionic technologies trailing behind in that order.

Brown, Daryl R.; Dirks, James A.; Fernandez, Nicholas; Stout, Tyson E.

2010-03-31T23:59:59.000Z

367

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents [OSTI]

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, L.T.

1987-03-20T23:59:59.000Z

368

A thermodynamics based analysis of exergy destruction in vapor compression cycle systems.  

E-Print Network [OSTI]

??In the last few decades, vapor-compression cycle systems (VCSs) have undergone many advances in actuation, allowing for variable aperture valves, variable speed compressors, and variable… (more)

Kania, Megan

2013-01-01T23:59:59.000Z

369

Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor  

DOE Patents [OSTI]

The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

2014-03-04T23:59:59.000Z

370

Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor...  

Open Energy Info (EERE)

Stable-Isotope Studies Of Rocks And Secondary Minerals In A Vapor-Dominated Hydrothermal System At The Geysers, Sonoma County, California Jump to: navigation, search GEOTHERMAL...

371

The Patuha geothermal system: a numerical model of a vapor-dominated system.  

E-Print Network [OSTI]

??The Patuha geothermal system is a vapor-dominated reservoir located about 40 kilometers southwest of Bandung on western Java, Indonesia. The geothermal system consists of a… (more)

Schotanus, M.R.J.

2013-01-01T23:59:59.000Z

372

E-Print Network 3.0 - alkali atom vapor Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a vapor cell magneto-optical trap. 1999 American... to the vacuum pumps or due to adsorption of the ... Source: Jin, Deborah - JILA, University of Colorado at Boulder...

373

Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors  

SciTech Connect (OSTI)

A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

2014-10-14T23:59:59.000Z

374

Response of passive organic vapor dosimeters to a mixed gas exposure  

E-Print Network [OSTI]

of Advisory Comm1ttee: Dr. Richard B. Konzen The effects of the sampling order of two chemicals adsorbed onto a DuPont Pro-Tek Organic Vapor Dosimeters were investigated. The dosimeters were exposed to varying known concentrations of methyl methacrylate...-powered pump to draw a known volume of air through a charcoal packed tube. The charcoal adsorbs the organic vapors and separates the small amount of vapor from a large amount of air. The organic vapors are then desorbed and analyzed by means of gas...

Anderson, Scott Merritt

2012-06-07T23:59:59.000Z

375

Low-Cost, Modular Electrothermal Vaporization System for Inductively Coupled Plasma Atomic Emission Spectrometry  

Science Journals Connector (OSTI)

In this investigation, commercially available tungsten filaments were employed to electrothermally vaporize liquid samples prior to their introduction into an inductively coupled...

Levine, Keith; Wagner, Karl A; Jones, Bradley T

1998-01-01T23:59:59.000Z

376

E-Print Network 3.0 - atomic vapor deposited Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Articles Surfactant-Catalyzed Chemical Vapor Deposition of Copper Thin Films Eui Seong Hwang... and demonstrated for deposition of copper thin films from ... Source:...

377

E-Print Network 3.0 - acoustic wave vapor Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(6). While previous systems have demonstrated success in chemical... striking visual identification of a range of ligating vapors (including alcohols, amines, ethers... ,...

378

Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems.  

E-Print Network [OSTI]

??The Organic Flash Cycle (OFC) is proposed as a vapor power cycle that could potentially increase power generation and improve the utilization efficiency of renewable… (more)

Ho, Tony

2012-01-01T23:59:59.000Z

379

Towards improved spinnability of chemical vapor deposition generated multi-walled carbon nanotubes  

E-Print Network [OSTI]

P. J. F. 1999 Carbon nanotubes and related structures: newof vapor grown carbon nanotubes and single wall nanotubes, Eto Carbon Materials in Carbon Nanotubes: Preparation and

McKee, Gregg Sturdivant Burke

2008-01-01T23:59:59.000Z

380

Opals infiltrated with a stimuli-responsive hydrogel for ethanol vapor sensing  

Science Journals Connector (OSTI)

We report on a novel class of optical materials for ethanol vapor sensing, based on polystyrene opals infiltrated with an innovative stimuli-responsive hydrogel. We describe the...

Pernice, Riccardo; Adamo, Gabriele; Stivala, Salvatore; Parisi, Antonino; Busacca, Alessandro C; Spigolon, Dario; Sabatino, Maria Antonietta; D’Acquisto, Leonardo; Dispenza, Clelia

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Gas chromatographic-mass spectrometric characterization of an oil aerosol-vapor microbial disinfectant .  

E-Print Network [OSTI]

??"This thesis focuses on chemical characterization studies of disinfectant vapors generated from thermal oxidation of mineral oil and biogenic oil esters. The disinfection technique holds… (more)

Wadhwa, Prakash, 1980-

2005-01-01T23:59:59.000Z

382

Lamar County Elec Coop Assn | Open Energy Information  

Open Energy Info (EERE)

Lamar County Elec Coop Assn Lamar County Elec Coop Assn Place Texas Utility Id 10649 Utility Location Yes Ownership C NERC Location TRE Activity Transmission Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png LARGE COMMERCIAL Commercial LARGE COMMERCIAL PUBLIC BUILDINGS Commercial RESIDENTIAL & PUBLIC BUILDINGS Residential SMALL COMMERCIAL Commercial security light- 100 watt High Pressure Sodium Lighting security light- 400 watt Metal Halide Lighting security light-1000 watt Mercury Vapor Lighting security light-1000 watt Metal Halide Lighting security light-175 watt Mercury Vapor Lighting

383

Tippah Electric Power Assn | Open Energy Information  

Open Energy Info (EERE)

Tippah Electric Power Assn Tippah Electric Power Assn Place Mississippi Utility Id 18943 Utility Location Yes Ownership C NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png GSA 1 General Power Rate 1 Commercial GSA 2 General Power Rate 2 Commercial GSA 3 General Power Rate 3 Commercial LS Lighting High Pressure Sodium 100 Watts Lighting LS Lighting Mercury Vapor 175 Watts Lighting LS Lighting Mercury Vapor 400 Watts Lighting LS Lighting Metal Halide Cobrahead 400 Watts Lighting LS Lighting Metal Halide Floodlight 1000 Watts Lighting

384

Johnson County Rural E M C | Open Energy Information  

Open Energy Info (EERE)

Johnson County Rural E M C Johnson County Rural E M C Place Indiana Utility Id 9778 Utility Location Yes Ownership C NERC Location RFC NERC RFC Yes ISO MISO Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Grain Dryer Service Commercial Large Power Service Industrial Large Power Time of Use Industrial Multi-Phase Commercial Service Commercial Net Metering Sevice Residential Outdoor Lighting: STN, Cobra Head, High Pressure Sodium, 400W Lighting Outdoor Lighting: STN, Directional Flood, Mercury Vapor / Metal Halide, 1000W Lighting Outdoor Lighting: STN, Directional Flood, Mercury Vapor / Metal Halide,

385

Mountain Electric Coop, Inc | Open Energy Information  

Open Energy Info (EERE)

Tennessee Tennessee Utility Id 13027 Utility Location Yes Ownership C NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 100 WATT HPS Lighting 1000 WATT METAL HALIDE FLOOD Lighting 175 WATT MERCURY VAPOR Lighting 250 WATT HPS STREET LIGHT Lighting 250 WATT HPS YARD LIGHT Lighting 400 WATT MERCURY VAPOR Lighting 400 WATT METAL HALIDE FLOOD Lighting Commercial GSA 1-Single-Phase transformer rated Commercial Commercial GSA 1-Three-Phase Self contained Commercial Commercial GSA 1-Three-Phase Transformer Rated Commercial

386

Hickman-Fulton Counties RECC | Open Energy Information  

Open Energy Info (EERE)

Hickman-Fulton Counties RECC Hickman-Fulton Counties RECC Jump to: navigation, search Name Hickman-Fulton Counties RECC Place Kentucky Utility Id 40305 Utility Location Yes Ownership C NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 100 Watt High Pressure Sodium Lighting 100 Watt Metal Halide Light Lighting 175 Watt Mercury Vapor Light Lighting 175 Watt Metal Halide Light Lighting 200 Watt High Pressure Sodium Lighting 400 Watt High Pressure Sodium Lighting 400 Watt Mercury Vapor Light Lighting GSA Part 1 Commercial GSA Part 2 Industrial

387

Nitrogen-Doped Anatase Nanofibers Decorated with Noble Metal Nanoparticles for Photocatalytic Production of Hydrogen  

Science Journals Connector (OSTI)

Nitrogen-Doped Anatase Nanofibers Decorated with Noble Metal Nanoparticles for Photocatalytic Production of Hydrogen ... High-aspect-ratio titanate nanotubes (NT) and nanowires (NW) were produced by the hydrothermal conversion of TiO2 at 400 K. ... Two novel deposition methods were used to synthesize Pt-TiO2 composite photoelectrodes: a tilt-target room temperature sputtering method and aerosol-chemical vapor deposition (ACVD). ...

Ming-Chung Wu; Jussi Hiltunen; András Sápi; Anna Avila; William Larsson; Hsueh-Chung Liao; Mika Huuhtanen; Géza Tóth; Andrey Shchukarev; Noémi Laufer; Ákos Kukovecz; Zoltán Kónya; Jyri-Pekka Mikkola; Riitta Keiski; Wei-Fang Su; Yang-Fang Chen; Heli Jantunen; Pulickel M. Ajayan; Robert Vajtai; Krisztián Kordás

2011-05-13T23:59:59.000Z

388

Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Information  

Open Energy Info (EERE)

Sumitomo Metal Industries Ltd Sumitomo Metals Sumitomo Metal Industries Ltd Sumitomo Metals Jump to: navigation, search Name Sumitomo Metal Industries Ltd (Sumitomo Metals) Place Osaka-shi, Osaka, Japan Zip 540-0041 Sector Solar Product Engaged in the steel, engineering, and electronics businesses; works on fuel cell component technology and manufactures silicon wafers for the solar sector. References Sumitomo Metal Industries Ltd (Sumitomo Metals)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Sumitomo Metal Industries Ltd (Sumitomo Metals) is a company located in Osaka-shi, Osaka, Japan . References ↑ "Sumitomo Metal Industries Ltd (Sumitomo Metals)" Retrieved from "http://en.openei.org/w/index.php?title=Sumitomo_Metal_Industries_Ltd_Sumitomo_Metals&oldid=351744"

389

Prediction of blast damage from vapor cloud explosions  

SciTech Connect (OSTI)

The process industries handle a wide range of different materials and use them in different types of chemical reaction. Of particular concern is the prospect of damage and injury affecting the general public outside the boundary wall of the chemical plant. It is not wise to permit the construction of homes, schools or hospitals so close to chemical plants that they, and the people within, might be damaged or injured should there be an accidental explosion in the plant. The major hazard outside the plant is over-pressure, a consequence of an accidental explosion in a cloud of flammable gas or vapor (Vapor Cloud Explosion or VCE). It is the responsibility of plant management to ensure that any such accidental explosion is not so large as to endanger the public, and of the local planning authorities to ensure that homes, schools or hospitals are not sited so close to chemical plants that they may be endangered by accidental explosion. A vital tool for such authorities is a simple method of assessing the possible consequences of an accidental VCE. In this paper those methods of assessing the consequences are examined.

Phillips, H. [Phillips (H.), Buxton (United Kingdom)

1995-12-31T23:59:59.000Z

390

Absorption profiles of alkali-metal D lines in the presence of a static magnetic field  

Science Journals Connector (OSTI)

When atoms are placed in a static magnetic field, they undergo shifts of their energy levels and changes in their transition probabilities. These two effects must be taken into account when considering absorption profiles of alkali-metal D lines, which result from the contribution of many transitions influenced by the laser spectrum and Doppler broadening. The model presented here gives the D-line absorption coefficients of alkali-metal vapors in the presence of an arbitrary static magneitc field. They are evaluated considering various laser polarizations. Experimental measurements of D-line absorption profiles for Rb85, Rb87, and Cs133 isotopes show excellent agreement with theoretical predictions.

P. Tremblay; A. Michaud; M. Levesque; S. Thériault; M. Breton; J. Beaubien; N. Cyr

1990-09-01T23:59:59.000Z

391

Investigation of Pool Spreading and Vaporization Behavior in Medium-Scale LNG Tests  

Science Journals Connector (OSTI)

Abstract A failure of a Liquefied Natural Gas (LNG) tanker can occur due to collision or loading/unloading operation resulting in spillage of LNG on water. Upon release, a spreading liquid can form a pool with rapid vaporization leading to the formation of a flammable vapor cloud. Safety analysis for the protection of public and property involves the determination of consequences of such accidental releases. To address this complex pool spreading and vaporization phenomenon of LNG, an investigation is performed based on the experimental tests that were conducted by the Mary Kay O’Connor Process Safety Center (MKOPSC) in 2007. The 2007 tests are a part of medium-scale experiments carried out at the Brayton Fire Training Field (BFTF), College Station. The dataset represents a semi-continuous spill on water, where LNG is released on a confined area of water for a specified duration of time. The pool spreading and vaporization behavior are validated using empirical models, which involved determination of pool spreading parameters and vaporization rates with respect to time. Knowledge of the pool diameter, pool height and spreading rate are found to be important in calculating the vaporization rates of the liquid pool. The paper also presents a method to determine the vaporization mass flux of LNG using water temperature data that is recorded in the experiment. The vaporization rates are observed to be high initially and tend to decrease once the pool stopped spreading. The results of the analysis indicated that a vaporization mass flux that is varying with time is required for accurate determination of the vaporization rate. Based on the data analysis, sources of uncertainties in the experimental data were identified to arise from ice formation and vapor blocking.

Nirupama Gopalaswami; R. Mentzer; M. Sam Mannan

2014-01-01T23:59:59.000Z

392

Photoactivated metal removal  

SciTech Connect (OSTI)

The authors propose the use of photochromic dyes as light activated switches to bind and release metal ions. This process, which can be driven by solar energy, can be used in environmental and industrial processes to remove metals from organic and aqueous solutions. Because the metals can be released from the ligands when irradiated with visible light, regeneration of the ligands and concentration of the metals may be easier than with conventional ion exchange resins. Thus, the process has the potential to be less expensive than currently used metal extraction techniques. In this paper, the authors report on their studies of the metal binding of spirogyran dyes and the hydrolytic stability of these dyes. They have prepared a number of spirogyrans and measured their binding constants for calcium and magnesium. They discuss the relationship of the structure of the dyes to their binding strengths. These studies are necessary towards determining the viability of this technique.

Nimlos, M.R.; Filley, J.; Ibrahim, M.A.; Watt, A.S.; Blake, D.M.

1999-07-01T23:59:59.000Z

393

Metal atomization spray nozzle  

DOE Patents [OSTI]

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

394

Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols: The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol,  

E-Print Network [OSTI]

Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols* Department of Chemistry and Biochemistry, University of MissourisSt. Louis, St. Louis, Missouri 63121 sublimation enthalpies. The sublimation enthalpies were compared to existing literature values. Agreement

Chickos, James S.

395

Fabricated Metals (2010 MECS)  

Broader source: Energy.gov [DOE]

Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

396

EMSL - trace metals  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

trace-metals en Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments. http:www.emsl.pnl.govemslwebpublications...

397

Thickness and density of adsorbed additive layer on metal surface in lubricant by neutron reflectometry  

Science Journals Connector (OSTI)

The thickness and density of the adsorbed additive layer on a metal surface in lubricant were directly measured by neutron reflectometry. First, two kinds of metal surfaces, iron and copper, on ultra-flat silicon blocks were prepared by physical vapor deposition. After that, each target surface was analyzed by neutron reflectometry in air, in base oil and in base oil with an additive. Poly-alpha-olefin was used as the base oil, while deuterated acetic acid was used as an additive. Fitting operation based on Parratt's theory showed that the thicknesses of the adsorbed layers on the iron and copper surfaces were quite thin, only 2.0 nm. The friction coefficients of the metal surfaces measured by a ball-on-disk tribometer decreased considerably when the acetic acid was added to the base oil. It was concluded that the additive adsorbed layers on the metal surfaces considerably affected friction properties despite being only several nanometers thick.

Tomoko Hirayama; Takashi Torii; Yohei Konishi; Masayuki Maeda; Takashi Matsuoka; Kazuko Inoue; Masahiro Hino; Dai Yamazaki; Masayasu Takeda

2012-01-01T23:59:59.000Z

398

Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank  

Broader source: Energy.gov (indexed) [DOE]

CMS to develop a membrane CMS to develop a membrane vapor processor that recovers fuel vapors from gasoline refueling with 99 percent efficiency. This membrane system enables gasoline stations to surpass environmental regulations while reducing fuel losses. Compact Membrane Systems, Inc. (CMS) was founded in 1993 in Wilmington, DE, with the acquisition of rights to certain DuPont polymer membrane patents. CMS focuses

399

An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Several Parabens by Correlation Gas  

E-Print Network [OSTI]

An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Several Parabens, Kasetsart University, Bangkane, Bangkok 10900, Thailand 2 Department of Chemistry and Biochemistry.com). DOI 10.1002/jps.22423 ABSTRACT: The vaporization, fusion, and sublimation enthalpies of methyl, ethyl

Chickos, James S.

400

Method and apparatus to measure vapor pressure in a flow system  

DOE Patents [OSTI]

The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process. 2 figures.

Grossman, M.W.; Biblarz, O.

1991-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Determination of effective water vapor diffusion coefficient in pemfc gas diffusion layers  

E-Print Network [OSTI]

route from the cathode catalyst layer to the cathode flow channels. Water can be removed from the cellDetermination of effective water vapor diffusion coefficient in pemfc gas diffusion layers Jacob M: Water vapor diffusion PEMFC Water management GDL Diffusivity MPL a b s t r a c t The primary removal

Kandlikar, Satish

402

Optofluidic ring resonator sensors for rapid DNT vapor detection Greg Frye-Mason,b  

E-Print Network [OSTI]

(OFRR) chemical vapor sensor as a promising platform for explosive detection with the capability and chemical sensing platform.23­27 As illustrated in Fig. 1(A), the OFRR is a thin-walled fused silica shows that the OFRR vapor sensor is a promising platform for the development of a rapid, low

Fan, Xudong "Sherman"

403

Retrieval of water vapor profiles over ocean using SSM/I and SSM/T-2  

E-Print Network [OSTI]

of water vapor profiles, while the SSM/I can be used to retrieve, among other things, the total integrated water vapor (TIWV) in a column of air. It is theoretically possible to use SSM/I data to supplement the SSM/T-2 data, producing more accurate water...

Blankenship, Clay Bruce

2012-06-07T23:59:59.000Z

404

Researchers develop electrodeposition process to deposit coatings on substrates, eliminate the expensive physical vapor  

E-Print Network [OSTI]

the expensive physical vapor deposition step, and improve device quality. CuIn1-xGaxSe2 (CIGS) solar cells have composition was adjusted by physical vapor deposition method. At present, we are fabricating CIGS-based solar). 2 R. N. Bhattacharya, W. Batchelor, J. F. Hiltner, and J. R. Sites, Appl. Phys. Lett., 75, 1431

405

Indium and tellurium doping of CdS crystals in cadmium vapor and their luminescent properties  

Science Journals Connector (OSTI)

A technique is devised for vapor-phase doping of CdS in the quaternary system Cd-In-Te-S. CdS crystals are doped with In and Te via four-zone ... InTe vapors. The luminescence spectra of the CdS?In,Te?[Cd] crysta...

I. N. Odin; M. V. Chukichev; M. E. Rubina

406

Indium and tellurium doping of CdS crystals in cadmium vapor and their luminescent properties  

Science Journals Connector (OSTI)

—A technique is devised for vapor-phase doping of CdS in the quaternary system Cd—In—Te—S. CdS crystals are doped with In and Te via four-zone ... InTe vapors. The luminescence spectra of the CdS?In,Te?[Cd] cryst...

I. N. Odin; M. V. Chukichev; M. E. Rubina

407

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents [OSTI]

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

408

Nickel catalyst faceting in plasma-enhanced direct current chemical vapor deposition of carbon nanofibers  

E-Print Network [OSTI]

1 Nickel catalyst faceting in plasma-enhanced direct current chemical vapor deposition of carbon vapor deposition with Ni catalysts on the top of nanofibers. Transmission electron microscopy was used to study the morphology and crystallography of Ni catalysts, which are essential for the nucleation

Paris-Sud XI, Université de

409

Neural modeling of vapor compression refrigeration cycle with extreme learning machine  

Science Journals Connector (OSTI)

In this paper, a single-hidden layer feed-forward neural network (SLFN) is used to model the dynamics of the vapor compression cycle in refrigeration and air-conditioning systems, based on the extreme learning machine (ELM). It is shown that the assignment ... Keywords: Back propagation, Extreme learning machine, Modeling, Radial basis function, Support vector regression, Vapor compression refrigeration cycle

Lei Zhao; Wen-Jian Cai; Zhi-Hong Man

2014-03-01T23:59:59.000Z

410

Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated  

E-Print Network [OSTI]

Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated Activated Carbon August 25, 1995@ Water vapor adsorption on activated carbon cloth (ACCBO)which has been oxidized% Cl), and ACCBO (4% N), exhibits sigmoidal isotherms with hysteresis loops of varying magnitudes

Cal, Mark P.

411

Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from MODIS  

E-Print Network [OSTI]

Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from such as cloud mask, atmos- pheric profiles, aerosol properties, total precipitable water, and cloud properties vapor amount, aerosol particles, and the subsequently formed clouds [9]. Barnes et al. [2] provide

Sheridan, Jennifer

412

Tunneling characteristics in chemical vapor deposited graphene hexagonal boron nitride graphene junctions  

E-Print Network [OSTI]

1 Tunneling characteristics in chemical vapor deposited graphene ­ hexagonal boron nitride ­ graphene junctions T. Roy1 , L. Liu2 , S. de la Barrera,3 B. Chakrabarti1,4 , Z. R. Hesabi1 , C. A. Joiner1 Abstract: Large area chemical vapor deposited graphene and hexagonal boron nitride was used to fabricate

Feenstra, Randall

413

Computational Analysis and Optimization of a Chemical Vapor Deposition Reactor with  

E-Print Network [OSTI]

Computational Analysis and Optimization of a Chemical Vapor Deposition Reactor with Large and optimization of a three- dimensional model of a horizontal chemical vapor deposition (CVD) reactor used National Laboratories February 9, 2004 Abstract A computational analysis and optimization is presented

414

Optimization of the chemical vapor deposition process for carbon nanotubes fabrication  

E-Print Network [OSTI]

Optimization of the chemical vapor deposition process for carbon nanotubes fabrication M. Grujicica-phase chemistry and surface chemistry model is developed to analyze, at the reactor length scale, chemical vapor (carrier gas) in the presence of cobalt catalytic particles in a cylindrical reactor. The model allows

Grujicic, Mica

415

OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR  

E-Print Network [OSTI]

OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR K.J. BACHMANN of computer simulations as an optimal design tool which lessens the costs in time and effort in experimental vapor deposition (HPOMCVD) reactor for use in thin film crystal growth. The advantages of such a reactor

416

On the optimization of a dc arcjet diamond chemical vapor deposition reactor  

E-Print Network [OSTI]

On the optimization of a dc arcjet diamond chemical vapor deposition reactor S. W. Reevea) and W. A precursor in our dc arcjet reactor.1 Based on conclusions drawn from that work, an optimization strategy diamond film growth in a dc arcjet chemical vapor deposition reactor has been developed. Introducing

Dandy, David

417

Fundamental process and system design issues in CO2 vapor compression systems  

E-Print Network [OSTI]

Fundamental process and system design issues in CO2 vapor compression systems Man-Hoe Kima; CO2 (R-744); Transcritical cycle; Vapor compression system; COP; Air-conditioning; Heat pump recent developments and state of the art for transcritical CO2 cycle technology in various refrigeration

Bahrami, Majid

418

Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry  

DOE Patents [OSTI]

The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

Yeung, E.S.; Chang, Y.C.

1999-06-29T23:59:59.000Z

419

Silicon metal-semiconductor-metal photodetector  

DOE Patents [OSTI]

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

420

Silicon metal-semiconductor-metal photodetector  

DOE Patents [OSTI]

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Symmetry reduction of metal phthalocyanines on metals  

Science Journals Connector (OSTI)

The temperature-dependent adsorption behavior of fourfold symmetric metal phthalocyanines (MPcs) on metals with commensurate and incommensurate symmetries was investigated by scanning tunneling microscopy. On the fourfold symmetric Cu(100) surface, planar and fourfold molecular structures in two equivalent orientations were found for MPcs when prepared at room temperature. In addition, two metastable orientations were identified when prepared at low temperature, which can be depopulated upon annealing. MPcs adsorbed on the sixfold symmetric Cu(111) surface showed a disturbed molecular appearance. The symmetry of molecular structures changed from fourfold to twofold, which is discussed in terms of molecule-substrate interaction.

Shih-Hsin Chang; Stefan Kuck; Jens Brede; Leonid Lichtenstein; Germar Hoffmann; Roland Wiesendanger

2008-12-29T23:59:59.000Z

422

Feasibility of UV lasing without inversion in mercury vapor  

E-Print Network [OSTI]

We investigate the feasibility of UV lasing without inversion at a wavelength of $253.7$ nm utilizing interacting dark resonances in mercury vapor. Our theoretical analysis starts with radiation damped optical Bloch equations for all relevant 13 atomic levels. These master equations are generalized by considering technical phase noise of the driving lasers. From the Doppler broadened complex susceptibility we obtain the stationary output power from semiclassical laser theory. The finite overlap of the driving Gaussian laser beams defines an ellipsoidal inhomogeneous gain distribution. Therefore, we evaluate the intra-cavity field inside a ring laser self-consistently with Fourier optics. This analysis confirms the feasibility of UV lasing and reveals its dependence on experimental parameters.

Martin R. Sturm; Benjamin Rein; Thomas Walther; Reinhold Walser

2014-06-27T23:59:59.000Z

423

Chemical vapor deposition of hydrogenated amorphous silicon from disilane  

SciTech Connect (OSTI)

The authors describe hydrogenated amorphous silicon (a-Si:H) thin films deposited at growth rates of 1 to 30 A/s by chemical vapor deposition (CVD) from disilane source gas at 24 torr total pressure in a tubular reactor. The effects of substrate temperature and gas holding time (flow rate) on film growth rate and effluent gas composition were measured at temperatures ranging from 360{sup 0} to 485{sup 0}C and gas holding times from 3 to 62s. Effluent gases determined by gas chromatography included silane, disilane and other higher order silanes. A chemical reaction engineering model, based on a silylene (SiH/sub 2/) insertion gas phase reaction network and film growth from both SiH/sub 2/ and high molecular weight silicon species, Si/sub n/H/sub 2n/, was developed. The model predictions were in good agreement with experimentally determined growth rates and effluent gas compositions.

Bogaert, R.J.; Russell, T.W.F.; Klein, M.T. (Delaware Univ., Newark, DE (USA). Dept. of Chemical Engineering); Rocheleau, R.E.; Baron, B.N. (Delaware Univ., Newark, DE (USA). Inst. of Energy Conversion)

1989-10-01T23:59:59.000Z

424

Chemical vapor deposition of boron-doped hydrogenated amorphous silicon  

SciTech Connect (OSTI)

Deposition conditions and film properties for a variety of boron-doped hydrogenated amorphous silicon films and silicon-carbon films produced by chemical vapor deposition (CVD) are discussed. Deposition gases include monosilane, disilane, trisilane, and acetylene. Two types of optically wide band-gap p layers are obtained. One of these window p layers (without carbon) has been extensively tested in photovoltaic devices. Remarkably, this p layer can be deposited between about 200 to 300 /sup 0/C. A typical open circuit voltage in an all CVD p-i-n device is 0.70--0.72 V, and in a hybrid device where the i and n layers are deposited by glow discharge, 0.8--0.83 V.

Ellis F.B. Jr.; Delahoy, A.E.

1985-07-15T23:59:59.000Z

425

Adsorption and Diffusion of Alcohol Vapors by Argonne Premium Coals  

Science Journals Connector (OSTI)

Adsorption and Diffusion of Alcohol Vapors by Argonne Premium Coals ... Adsorption of methanol, ethanol, n-propanol, and n-butanol by Pocahontas No. 3, Upper Freeport, Illinois No. 6, and Beulah-Zap Argonne premium coals was investigated to clarify the effect of alkyl group bulk on adsorption and to evaluate the micropore and cross-linked structure of coals. ... Coals are thought to have a large surface area with an interconnected network of slitlike pores.1 However, Larsen et al.2 measured the adsorption of various gases on five Argonne Premium coals and, except for Beulah-Zap lignite, found that the very steep dependence of BET surface area was related to the molecular volume of the gas. ...

Toshimasa Takanohashi; Yuki Terao; Takahiro Yoshida; Masashi Iino

2000-06-17T23:59:59.000Z

426

Homogeneous nucleation rate measurements in supersaturated water vapor  

Science Journals Connector (OSTI)

The rate of homogeneous nucleation in supersaturated vapors of water was studied experimentally using a thermal diffusion cloud chamber. Helium was used as a carrier gas. Our study covers a range of nucleation rates from 3 × 10 ? 1 to 3 × 10 2 cm ? 3 s ? 1 at four isotherms: 290 300 310 and 320 K . The molecular content of critical clusters was estimated from the slopes of experimental data. The measured isothermal dependencies of nucleation rate of water on saturation ratio were compared with the prediction of the classical theory of homogeneous nucleation the empirical prediction of Wölk et al. [J. Chem. Phys.117 10 (2002)] the scaled model of Hale [Phys. Rev. A33 4156 (1986)] and the former nucleation onset data.

David Brus; Vladimír Ždímal; Ji?í Smolík

2008-01-01T23:59:59.000Z

427

Strain relaxation in graphene grown by chemical vapor deposition  

SciTech Connect (OSTI)

The growth of single layer graphene by chemical vapor deposition on polycrystalline Cu substrates induces large internal biaxial compressive strain due to thermal expansion mismatch. Raman backscattering spectroscopy and atomic force microscopy were used to study the strain relaxation during and after the transfer process from Cu foil to SiO{sub 2}. Interestingly, the growth of graphene results in a pronounced ripple structure on the Cu substrate that is indicative of strain relaxation of about 0.76% during the cooling from the growth temperature. Removing graphene from the Cu substrates and transferring it to SiO{sub 2} results in a shift of the 2D phonon line by 27?cm{sup ?1} to lower frequencies. This translates into additional strain relaxation. The influence of the processing steps, used etching solution and solvents on strain, is investigated.

Troppenz, Gerald V., E-mail: gerald.troppenz@helmholtz-berlin.de; Gluba, Marc A.; Kraft, Marco; Rappich, Jörg; Nickel, Norbert H. [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Institut für Silizium Photovoltaik, Kekuléstr. 5, D-12489 Berlin (Germany)

2013-12-07T23:59:59.000Z

428

Field emission properties of chemical vapor deposited individual graphene  

SciTech Connect (OSTI)

Here, we report field emission (FE) properties of a chemical vapor deposited individual graphene investigated by in-situ transmission electron microscopy. Free-standing bilayer graphene is mounted on a cathode microprobe and FE processes are investigated varying the vacuum gap of cathode and anode. The threshold field for 10?nA current were found to be 515, 610, and 870?V/?m for vacuum gap of 400, 300, and 200?nm, respectively. It is observed that the structural stability of a high quality bilayer graphene is considerably stable during emission process. By contacting the nanoprobe with graphene and applying a bias voltage, structural deformation and buckling are observed with significant rise in temperature owing to Joule heating effect. The finding can be significant for practical application of graphene related materials in emitter based devices as well as understanding the contact resistance influence and heating effect.

Zamri Yusop, Mohd [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan); Department of Materials, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor (Malaysia); Kalita, Golap, E-mail: kalita.golap@nitech.ac.jp [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan); Center for Fostering Young and Innovative Researchers, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan); Yaakob, Yazid; Takahashi, Chisato; Tanemura, Masaki [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan)

2014-03-03T23:59:59.000Z

429

EA-0881: Tank 241-c-103 Organic Vapor and Liquid Characterization and  

Broader source: Energy.gov (indexed) [DOE]

81: Tank 241-c-103 Organic Vapor and Liquid Characterization 81: Tank 241-c-103 Organic Vapor and Liquid Characterization and Supporting Activities, Hanford Site, Richland, Washington EA-0881: Tank 241-c-103 Organic Vapor and Liquid Characterization and Supporting Activities, Hanford Site, Richland, Washington SUMMARY This EA evaluates the environmental impacts of a proposal to sample the vapor space and liquid waste and perform other supporting activities in Tank 241-C-103 located in the 241-C Tank Farm on the Hanford Site in Richland, Washington. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD August 10, 1992 EA-0881: Finding of No Significant Impact Tank 241-c-103 Organic Vapor and Liquid Characterization and Supporting Activities, Hanford Site, Richland, Washington August 10, 1992

430

Building America Top Innovations Hall of Fame Profile Â… Vapor Retarder Classification  

Broader source: Energy.gov (indexed) [DOE]

2006 the IRC has permitted Class III 2006 the IRC has permitted Class III vapor retarders like latex paint (see list above) in all climate zones under certain conditions thanks to research by Building America teams. Air-tight and well-insulated homes have little or no tolerance for drying if they get wet; moisture control is critical. That's why Building America research establishing vapor retarder classifications and their appropriate applications has been instrumental in the market transformation to high-performance homes. As buildings have gotten tighter over the past several decades, questions about vapor retarders and vapor barriers have confounded builders and code developers. Vapor barriers have traditionally been installed on the warm in winter side of the wall assembly in an attempt to keep interior moisture from entering the wall cavity

431

WATER VAPOR IN THE PROTOPLANETARY DISK OF DG Tau  

SciTech Connect (OSTI)

Water is key in the evolution of protoplanetary disks and the formation of comets and icy/water planets. While high-excitation water lines originating in the hot inner disk have been detected in several T Tauri stars (TTSs), water vapor from the outer disk, where most water ice reservoirs are stored, was only reported in the nearby TTS TW Hya. We present spectrally resolved Herschel/HIFI observations of the young TTS DG Tau in the ortho- and para-water ground-state transitions at 557 and 1113 GHz. The lines show a narrow double-peaked profile, consistent with an origin in the outer disk, and are {approx}19-26 times brighter than in TW Hya. In contrast, CO and [C II] lines are dominated by emission from the envelope/outflow, which makes H{sub 2}O lines a unique tracer of the disk of DG Tau. Disk modeling with the thermo-chemical code ProDiMo indicates that the strong UV field, due to the young age and strong accretion of DG Tau, irradiates a disk upper layer at 10-90 AU from the star, heating it up to temperatures of 600 K and producing the observed bright water lines. The models suggest a disk mass of 0.015-0.1 M{sub Sun }, consistent with the estimated minimum mass of the solar nebula before planet formation, and a water reservoir of {approx}10{sup 2}-10{sup 3} Earth oceans in vapor and {approx}100 times larger in the form of ice. Hence, this detection supports the scenario of ocean delivery on terrestrial planets by the impact of icy bodies forming in the outer disk.

Podio, L.; Dougados, C.; Thi, W.-F.; Menard, F.; Pinte, C. [UJF-Grenoble 1/CNRS-INSU, Institut de Planetologie et d'Astrophysique de Grenoble (IPAG) UMR 5274, F-38041 Grenoble (France); Kamp, I.; Meijerink, R.; Spaans, M.; Aresu, G. [Kapteyn Astronomical Institute, University of Groningen, Landleven 12, 9747 AD Groningen (Netherlands); Codella, C. [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Florence (Italy); Cabrit, S. [LERMA, UMR 8112 du CNRS, Observatoire de Paris, Ecole Normale Superieure, Universite Pierre et Marie Curie, Universite de Cergy-Pontoise, 61 Av. de l'Observatoire, F-75014 Paris (France); Nisini, B. [INAF-Osservatorio Astronomico di Roma, via di Frascati 33, I-00040 Monte Porzio Catone (Italy); Sandell, G. [SOFIA-USRA, NASA Ames Research Center, MS 232-12, Building N232, Rm. 146, P.O. Box 1, Moffett Field, CA 94035-0001 (United States); Williams, J. P. [Institute for Astronomy (IfA), University of Hawaii, 2680 Woodlawn Dr., Honolulu, HI 96822 (United States); Testi, L. [European Southern Observatory, Karl-Schwarzschild-Strasse 2, D-85748 Garching (Germany); Woitke, P. [SUPA, School of Physics and Astronomy, University of St. Andrews, KY16 9SS (United Kingdom)

2013-03-20T23:59:59.000Z

432

Ash vaporization in circulating fluidized bed coal combustion  

SciTech Connect (OSTI)

In this work, the vaporization of the ash-forming constituents in circulating fluidized bed combustion (CFBC) in a full-scale 80 MW{sub th} unit was studied. Ash vaporization in CFBC was studied by measuring the fly ash aerosols in a full-scale boiler upstream of the electrostatic precipitator (ESP) at the flue gas temperature of 125{degree}C. The fly ash number size distributions showed two distinct modes in the submicrometer size range, at particle diameters 0.02 and 0.3 {mu}m. The concentration of the ultrafine 0.02-{mu}m mode showed a large variation with time and it decreased as the measurements advanced. The concentration of the 0.02-{mu}m mode was two orders of magnitude lower than in the submicrometer mode observed earlier in the bubbling FBC and up to three orders of magnitude lower than in the pulverized coal combustion. Scanning electron micrographs showed few ultrafine particles. The intermediate mode at 0.3 {mu}m consisted of particles irregular in shape, and hence in this mode the particles had not been formed via a gas to particle route. We propose that the 0.3-{mu}m mode had been formed from the partial melting of the very fine mineral particles in the coal. The mass size distribution in the size range 0.01-70 {mu}m was unimodal with maximum at 20 {mu}m. Less than 1% of the fly ash particles was found in the submicrometer size range. 35 refs., 8 figs., 3 tabs.

Lind, T.; Kauppinen, E.I.; Maenhaut, W. [Univ. of Gent (Belgium); Shah, A.; Huggins, F. [Univ. of Kentucky, Lexington, KY (United States)

1996-04-01T23:59:59.000Z

433

PHYTOEXTRACTION OF HEAVY METALS  

E-Print Network [OSTI]

) Type of phytoremediation Cost effective form of environmental remediation (Glass 1999) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al -using hyperaccumulator plant biomass to produce a bio-ore for commercial use -Li et al. look at using Ni

Blouin-Demers, Gabriel

434

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

435

Electroreflectance in Metals  

Science Journals Connector (OSTI)

Calculations have been made which suggest that the prominent maximum in the electroreflectance spectra of metals observed by Feinleib is not due to modulation of the optical constants of the electrolyte, but to modulation of the optical constants of the metal.

Arnold Prostak and Wilford N. Hansen

1967-08-15T23:59:59.000Z

436

Analysis of crude oil vapor pressures at the U.S. Strategic Petroleum Reserve.  

SciTech Connect (OSTI)

Crude oil storage caverns at the U.S. Strategic Petroleum Reserve (SPR) are solution-mined from subsurface salt domes along the U.S. Gulf Coast. While these salt domes exhibit many attractive characteristics for large-volume, long-term storage of oil such as low cost for construction, low permeability for effective fluids containment, and secure location deep underground, they also present unique technical challenges for maintaining oil quality within delivery standards. The vapor pressures of the crude oils stored at SPR tend to increase with storage time due to the combined effects of geothermal heating and gas intrusion from the surrounding salt. This presents a problem for oil delivery offsite because high vapor-pressure oil may lead to excessive atmospheric emissions of hydrocarbon gases that present explosion hazards, health hazards, and handling problems at atmospheric pressure. Recognizing this potential hazard, the U.S. Department of Energy, owner and operator of the SPR, implemented a crude oil vapor pressure monitoring program that collects vapor pressure data for all the storage caverns. From these data, DOE evaluates the rate of change in vapor pressures of its oils in the SPR. Moreover, DOE implemented a vapor pressure mitigation program in which the oils are degassed periodically and will be cooled immediately prior to delivery in order to reduce the vapor pressure to safe handling levels. The work described in this report evaluates the entire database since its origin in 1993, and determines the current levels of vapor pressure around the SPR, as well as the rate of change for purposes of optimizing both the mitigation program and meeting safe delivery standards. Generally, the rate of vapor pressure increase appears to be lower in this analysis than reported in the past and, problematic gas intrusion seems to be limited to just a few caverns. This being said, much of the current SPR inventory exceeds vapor pressure delivery guidelines and must be degassed and cooled in order to meet current delivery standards.

Rudeen, David Keith (GRAM, Inc., Albuquerque, NM); Lord, David L.

2005-08-01T23:59:59.000Z

437

Vaporization modeling of petroleum-biofuel drops using a hybrid multi-component approach  

SciTech Connect (OSTI)

Numerical modeling of the vaporization characteristics of multi-component fuel mixtures is performed in this study. The fuel mixtures studied include those of binary components, biodiesel, diesel-biodiesel, and gasoline-ethanol. The use of biofuels has become increasingly important for reasons of environmental sustainability. Biofuels are often blended with petroleum fuels, and the detailed understanding of the vaporization process is essential to designing a clean and efficient combustion system. In this study, a hybrid vaporization model is developed that uses continuous thermodynamics to describe petroleum fuels and discrete components to represent biofuels. The model is validated using the experimental data of n-heptane, n-heptane-n-decane mixture, and biodiesel. Since biodiesel properties are not universal due to the variation in feedstock, methods for predicting biodiesel properties based on the five dominant fatty acid components are introduced. Good levels of agreement in the predicted and measured drop size histories are obtained. Furthermore, in modeling the diesel-biodiesel drop, results show that the drop lifetime increases with the biodiesel concentration in the blend. During vaporization, only the lighter components of diesel fuel vaporize at the beginning. Biodiesel components do not vaporize until some time during the vaporization process. On the other hand, results of gasoline-ethanol drops indicate that both fuels start to vaporize once the process begins. At the beginning, the lighter components of gasoline have a slightly higher vaporization rate than ethanol. After a certain time, ethanol vaporizes faster than the remaining gasoline components. At the end, the drop reduces to a regular gasoline drop with heavier components. Overall, the drop lifetime increases as the concentration of ethanol increases in the drop due to the higher latent heat. (author)

Zhang, Lei; Kong, Song-Charng [Department of Mechanical Engineering, Iowa State University, 2025 Black Engineering Building, Ames, IA 50011 (United States)

2010-11-15T23:59:59.000Z

438

Building America Technology Solutions for New and Existing Homes: Moisture Durability of Vapor Permeable Insulating Sheathing (Fact Sheet)  

Broader source: Energy.gov [DOE]

In this project, Building America team Building Science Corporation researched some of the ramifications of using exterior, vapor permeable insulation on retrofit walls with vapor permeable cavity insulation. Retrofit strategies are a key factor in reducing exterior building stock consumption.

439

Improving Energy Efficiency and Cost-Effectiveness of Batch Distillation for Separating Wide Boiling Constituents. 1. Vapor Recompression Column  

Science Journals Connector (OSTI)

Although the direct vapor recompression column (VRC) has been known for its application in continuous distillation since the 1960s, the research on vapor recompressed batch distillation (VRBD) started a couple of years ago. In this contribution, a batch ...

Md. Malik Nawaz Khan; G. Uday Bhaskar Babu; Amiya K. Jana

2012-11-05T23:59:59.000Z

440

Production of magnesium metal  

SciTech Connect (OSTI)

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

2010-02-23T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Metal-Nonmetal Transition in Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

A review is given of the properties of metal-ammonia solutions together with a summary of the evidence for the existence of a metal-nonmetal transition.

J. C. THOMPSON

1968-10-01T23:59:59.000Z

442

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

443

Dalton Utilities | Open Energy Information  

Open Energy Info (EERE)

Dalton Utilities Dalton Utilities Jump to: navigation, search Name Dalton Utilities Place Georgia Utility Id 4744 Utility Location Yes Ownership M NERC Location SERC NERC SERC Yes Activity Generation Yes Activity Transmission Yes Activity Distribution Yes Activity Bundled Services Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 100 - Watt Sodium Vapor Lighting 1000 - Watt Metal Halide Directional Type Lighting 150 Watt Mercury Vapor Underground Service Lighting 150 Watt Sodium Vapor Underground Service Lighting 175 - Watt Mercury Vapor Lighting 175 - Watt Sodium Vapor Lighting

444

Town of Waynesville, North Carolina (Utility Company) | Open Energy  

Open Energy Info (EERE)

Waynesville Waynesville Place North Carolina Utility Id 20225 Utility Location Yes Ownership M NERC Location SERC Activity Distribution Yes Activity Retail Marketing Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Area Lighting- 100W Sodium Vapor Lighting Area Lighting- 150W Sodium Vapor Lighting Area Lighting- 175W Mercury Vapor Lighting Area Lighting- 400W Metal Halide Lighting Area Lighting- 400W Sodium Vapor Enclosed Lighting Area Lighting- 400W Sodium Vapor Flood Lighting Commercial Rate- Single Phase Commercial Commercial Rate- Single Phase Demand Commercial Commercial Rate- Three Phase Commercial

445

Partial oxidation process for producing a stream of hot purified gas  

DOE Patents [OSTI]

A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

Leininger, Thomas F. (Chino Hills, CA); Robin, Allen M. (Anaheim, CA); Wolfenbarger, James K. (Torrance, CA); Suggitt, Robert M. (Wappingers Falls, NY)

1995-01-01T23:59:59.000Z

446

Tank 241-BY-104 vapor sampling and analysis tank characterization report. Revision 1  

SciTech Connect (OSTI)

Tank 241-BY-104 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-104 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

Huckaby, J.L.

1995-05-31T23:59:59.000Z

447

Desorption efficiencies of toluene and n-butanol in an organic vapor monitor  

E-Print Network [OSTI]

&jards has become one of the most important industrial hygiene f unct i one e The levei of exposure to many organic vapor;=, is det r- mined by co' lecting the chemical on some type o solid sor- bent. Of the various adsorbents available {silica gel... two of these paramet rs) ~ The objective of this re, . earch wa, . to investigate the effe ts of chemical phase (liquid or vapor) on the desorp- tion efficiencies of toluene and n-buta?ol adsorbed on acti- vated charcoal in organic vapor monitors...

Heaney, Mary Ann

2012-06-07T23:59:59.000Z

448

Tank 241-BY-103 vapor sampling and analysis tank characterization report  

SciTech Connect (OSTI)

Tank 241-BY-103 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-103 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

Huckaby, J.L.

1995-05-05T23:59:59.000Z

449

Tank 241-BY-108 vapor sampling and analysis tank characterization report. Revision 1  

SciTech Connect (OSTI)

Tank 241-BY-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in ``Program Plan for the Resolution of Tank Vapor Issues`` (Osborne and Huckaby 1994). Tank 241-BY-108 was vapor sampled in accordance with ``Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution (Osborne et al., 1994).

Huckaby, J.L.

1995-05-31T23:59:59.000Z

450

Tank 241-BY-105 vapor sampling and analysis tank characterization report. Revision 1  

SciTech Connect (OSTI)

Tank 241-BY-105 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-105 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

Huckaby, J.L.

1995-05-31T23:59:59.000Z

451

Tank 241-BY-107 vapor sampling and analysis tank characterization report. Revision 1  

SciTech Connect (OSTI)

Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

Huckaby, J.L.

1995-05-31T23:59:59.000Z

452

Tank 241-BY-107 vapor sampling and analysis tank characterization report  

SciTech Connect (OSTI)

Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues{close_quotes}. Tank 241-BY-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution{close_quotes}.

Huckaby, J.L.

1995-05-05T23:59:59.000Z

453

Tank 241-BY-106 vapor sampling and analysis tank characterization report. Revision 1  

SciTech Connect (OSTI)

Tank 241-BY-106 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-106 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

Huckaby, J.L.

1995-05-31T23:59:59.000Z

454

Ion-beam-induced epitaxial vapor-phase growth: A molecular-dynamics study  

Science Journals Connector (OSTI)

Low-energy ions which bombard a vapor-deposited film of low adatom mobility during growth mobilize surface atoms in the vicinity of the ion impact, causing a modification in the evolving microstructure. In a two-dimensional molecular-dynamics simulation where inert-gas ions strike a growing film of Lennard-Jones particles, it is demonstrated that ion bombardment during growth causes the filling of voids quenched in during vapor condensation and induces homoepitaxial growth. The dependence of film density and degree of homoepitaxial growth on the ion-to-vapor arrival rate ratio and ion energy is studied in detail.

Karl-Heinz Müller

1987-05-15T23:59:59.000Z

455

Production of higher quality bio-oils by in-line esterification of pyrolysis vapor  

DOE Patents [OSTI]

The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

2014-12-02T23:59:59.000Z

456

Syntheses and Structures of Alkyl and Aryl Halide Complexes of the Type [(PiPr3)2PtH(?1-XR)]BArf and Analogues with Et2O, THF, and H2 Ligands. Halide-to-Metal ? Bonding in Halocarbon Complexes  

Science Journals Connector (OSTI)

Contribution from the Chemical Science and Technology Division, MS C346, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 ... Each band that could be identified was shifted slightly to lower energy relative to those found for free PhI dispersed in mineral oil. ... If a Pt?sulfinic acid species were stable at ?78 °C, we would expect it to be deprotonated by added base to reform starting material. ...

Matthew D. Butts; Brian L. Scott; Gregory J. Kubas

1996-11-27T23:59:59.000Z

457

Divalent metal nanoparticles  

E-Print Network [OSTI]

Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

DeVries, Gretchen Anne

2008-01-01T23:59:59.000Z

458

Nitrided Metallic Bipolar Plates  

Broader source: Energy.gov (indexed) [DOE]

to meet 5000 h automotive durability goal at cost < 5kW Year 1 Goals: Single-cell fuel cell test performance for 25 cm 2 stamped and nitrided metallic bipolar plates...

459

Metal stocks and sustainability  

Science Journals Connector (OSTI)

...dissipated through corrosion and wear, and some enters waste repositories...landfills. Dissipation from wear and corrosion is generally small...dispersion of metals from wear and corrosion is an important...transportation (railroad, marine, aircraft, and aerospace equipment...

R. B. Gordon; M. Bertram; T. E. Graedel

2006-01-01T23:59:59.000Z

460

Oligocyclopentadienyl transition metal complexes  

SciTech Connect (OSTI)

Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

de Azevedo, Cristina G.; Vollhardt, K. Peter C.

2002-01-18T23:59:59.000Z

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Excitons in Metals  

Science Journals Connector (OSTI)

It is shown that exciton states exist in metals, occurring near the interband threshold in optical absorption and substantially altering the shape and strength of the absorption edge. Their relation to the corresponding donor states is discussed.

G. D. Mahan

1967-03-20T23:59:59.000Z

462

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents [OSTI]

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

463

Metallic glass composition  

DOE Patents [OSTI]

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

464

Molten metal reactors  

DOE Patents [OSTI]

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

2013-11-05T23:59:59.000Z

465

City of Lexington, Tennessee (Utility Company) | Open Energy Information  

Open Energy Info (EERE)

Tennessee (Utility Company) Tennessee (Utility Company) Jump to: navigation, search Name City of Lexington Place Tennessee Utility Id 10968 Utility Location Yes Ownership M NERC Location SERC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Area Lighting Metal service(175 Watt Mercury Vapor) Lighting Area Lighting Service(100 Watt High Pressure Sodium) Lighting Area Lighting Service(400 Watt Metal Halide Shoe-Box Single) Lighting Area Lighting Service(400 Watt Metal Halide Shoe-Box Twin) Lighting Area Lighting service(100 Watt Decorative Acorn) Lighting

466

Functionalized Silicone Nanospheres: Synthesis, Transition Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

467

Chemical vapor deposition of amorphous silicon films from disilane  

SciTech Connect (OSTI)

Amorphous silicon films for fabrication of solar cells have been deposited by thermal chemical vapor deposition (CVD) from disilane (Si/sub 2/H/sub 6/) using a tubular flow reactor. A mathematical description for the CVD reactor was developed and solved by a numerical procedure. The proposed chemical reaction network for the model is based on silylene (SiH/sub 2/) insertion in the gas phase and film growth from SiH/sub 2/ and silicon polymers (Si/sub n/N/sub 2n/, n approx. 10). Estimates of the rate constants have been obtained for trisilane decomposition, silicon polymer formation, and polymer dehydrogenation. The silane unimolecular decomposition rate constants were corrected for pressure effects. The model behavior is compared to the experimental results over the range of conditions: reactor temperature (360 to 485/sup 0/C), pressures (2 to 48 torr), and gas holding time (1 to 70 s). Within the above range of conditions, film growth rate varies from 0.01 to 30 A/s. Results indicate that silicon polymers are the main film precursors for gas holding times greater than 3 s. Film growth by silylene only becomes important at short holding times, large inert gas dilution, and positions near the beginning of the reactor hot zone.

Bogaert, R.J.

1986-01-01T23:59:59.000Z

468

Soil Vapor Extraction System Optimization, Transition, and Closure Guidance  

SciTech Connect (OSTI)

Soil vapor extraction (SVE) is a prevalent remediation approach for volatile contaminants in the vadose zone. A diminishing rate of contaminant extraction over time is typically observed due to 1) diminishing contaminant mass, and/or 2) slow rates of removal for contamination in low-permeability zones. After a SVE system begins to show indications of diminishing contaminant removal rate, SVE performance needs to be evaluated to determine whether the system should be optimized, terminated, or transitioned to another technology to replace or augment SVE. This guidance specifically addresses the elements of this type of performance assessment. While not specifically presented, the approach and analyses in this guidance could also be applied at the onset of remediation selection for a site as a way to evaluate current or future impacts to groundwater from vadose zone contamination. The guidance presented here builds from existing guidance for SVE design, operation, optimization, and closure from the U.S. Environmental Protection Agency, U.S. Army Corps of Engineers, and the Air Force Center for Engineering and the Environment. The purpose of the material herein is to clarify and focus on the specific actions and decisions related to SVE optimization, transition, and/or closure.

Truex, Michael J.; Becker, Dave; Simon, Michelle A.; Oostrom, Martinus; Rice, Amy K.; Johnson, Christian D.

2013-02-08T23:59:59.000Z

469

Growth of graphene underlayers by chemical vapor deposition  

SciTech Connect (OSTI)

We present a simple and very convincing approach to visualizing that subsequent layers of graphene grow between the existing monolayer graphene and the copper catalyst in chemical vapor deposition (CVD). Graphene samples were grown by CVD and then transferred onto glass substrates by the bubbling method in two ways, either direct-transfer (DT) to yield poly (methyl methacrylate) (PMMA)/graphene/glass or (2) inverted transfer (IT) to yield graphene/PMMA/glass. Field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM) were used to reveal surface features for both the DT and IT samples. The results from FE-SEM and AFM topographic analyses of the surfaces revealed the underlayer growth of subsequent layers. The subsequent layers in the IT samples are visualized as 3D structures, where the smaller graphene layers lie above the larger layers stacked in a concentric manner. The results support the formation of the so-called “inverted wedding cake” stacking in multilayer graphene growth.

Fabiane, Mopeli; Khamlich, Saleh; Bello, Abdulhakeem; Dangbegnon, Julien; Momodu, Damilola; Manyala, Ncholu, E-mail: ncholu.manyala@up.ac.za [Department of Physics, Institute of Applied Materials, SARChI Chair in Carbon Technology and Materials, University of Pretoria, Pretoria 0028 (South Africa)] [Department of Physics, Institute of Applied Materials, SARChI Chair in Carbon Technology and Materials, University of Pretoria, Pretoria 0028 (South Africa); Charlie Johnson, A. T. [Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)] [Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)

2013-11-15T23:59:59.000Z

470

Charged impurity-induced scatterings in chemical vapor deposited graphene  

SciTech Connect (OSTI)

We investigate the effects of defect scatterings on the electric transport properties of chemical vapor deposited (CVD) graphene by measuring the carrier density dependence of the magneto-conductivity. To clarify the dominant scattering mechanism, we perform extensive measurements on large-area samples with different mobility to exclude the edge effect. We analyze our data with the major scattering mechanisms such as short-range static scatters, short-range screened Coulomb disorders, and weak-localization (WL). We establish that the charged impurities are the predominant scatters because there is a strong correlation between the mobility and the charge impurity density. Near the charge neutral point (CNP), the electron-hole puddles that are induced by the charged impurities enhance the inter-valley scattering, which is favorable for WL observations. Away from the CNP, the charged-impurity-induced scattering is weak because of the effective screening by the charge carriers. As a result, the local static structural defects govern the charge transport. Our findings provide compelling evidence for understanding the scattering mechanisms in graphene and pave the way for the improvement of fabrication techniques to achieve high-quality CVD graphene.

Li, Ming-Yang; Tang, Chiu-Chun [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Ling, D. C. [Department of Physics, Tamkang University, Tamsui Dist., New Taipei 25137, Taiwan (China); Li, L. J. [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 11529, Taiwan (China); Chi, C. C.; Chen, Jeng-Chung [Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu 30013, Taiwan (China)

2013-12-21T23:59:59.000Z

471

Plasma and Ion Assistance in Physical Vapor Deposition: AHistorical Perspective  

SciTech Connect (OSTI)

Deposition of films using plasma or plasma-assist can betraced back surprisingly far, namely to the 18th century for arcs and tothe 19th century for sputtering. However, only since the 1960s thecoatings community considered other processes than evaporation for largescale commercial use. Ion Plating was perhaps the first importantprocess, introducing vapor ionization and substrate bias to generate abeam of ions arriving on the surface of the growing film. Ratherindependently, cathodic arc deposition was established as an energeticcondensation process, first in the former Soviet Union in the 1970s, andin the 1980s in the Western Hemisphere. About a dozen various ion-basedcoating technologies evolved in the last decades, all characterized byspecific plasma or ion generation processes. Gridded and gridless ionsources were taken from space propulsion and applied to thin filmdeposition. Modeling and simulation have helped to make plasma and ionseffects to be reasonably well understood. Yet--due to the complex, oftennon-linear and non-equilibrium nature of plasma and surfaceinteractions--there is still a place for the experience plasma"sourcerer."

Anders, Andre

2007-02-28T23:59:59.000Z

472

Effects of inhaled 1-bromopropane vapor on rat metabolism  

Science Journals Connector (OSTI)

Wistar male rats were exposed to 1-bromopromane (1-BP) vapor for 6 h a day, 5 days a week, for 3 and 4 weeks (1500 ppm) and 1 day, and 4 and 12 weeks (700 ppm). After the exposures, 1-BP and its metabolites were measured temporally. In the samples obtained from the 700 ppm exposures, hematological and biochemical examinations in blood and measurements of hepatic cytochromes P450 were carried out. 1-BP in blood decreased rapidly to the detection limit within 0.7 h. On the other hand, bromine ion persisted longer in both blood and urine; the biological half-life of bromine ion was 4.7–15.0 days in blood and 5.0–7.5 days in urine. Glycidol was detected in the urine samples. Based on the experimental results, the metabolic pathway of 1-BP was discussed. Hepatic cytochromes P450, aspartate aminotransferase (AST) and alanine aminotransferase (ALT) in blood decreased significantly with 1-BP exposure, but other enzyme activities did not differ significantly.

Toru Ishidao; Naoki Kunugita; Yukiko Fueta; Keiichi Arashidani; Hajime Hori

2002-01-01T23:59:59.000Z

473

Water, Vapor, and Salt Dynamics in a Hot Repository  

SciTech Connect (OSTI)

The purpose of this paper is to report the results of a new model study examining the high temperature nuclear waste disposal concept at Yucca Mountain using MULTIFLUX, an integrated in-drift- and mountain-scale thermal-hydrologic model. The results show that a large amount of vapor flow into the drift is expected during the period of above-boiling temperatures. This phenomenon makes the emplacement drift a water/moisture attractor during the above-boiling temperature operation. The evaporation of the percolation water into the drift gives rise to salt accumulation in the rock wall, especially in the crown of the drift for about 1500 years in the example. The deposited salts over the drift footprint, almost entirely present in the fractures, may enter the drift either by rock fall or by water drippage. During the high temperature operation mode, the barometric pressure variation creates fluctuating relative humidity in the emplacement drift with a time period of approximately 10 days. Potentially wet and dry conditions and condensation on salt-laden drift wall sections may adversely affect the storage environment. Salt accumulations during the above-boiling temperature operation must be sufficiently addressed to fully understand the waste package environment during the thermal period. Until the questions are resolved, a below-boiling repository design is favored where the Alloy-22 will be less susceptible to localized corrosion. (authors)

Bahrami, Davood; Danko, George [Department of Mining Engineering, University of Nevada, Reno, 1664 N. Virginia St., Reno, NV, 89557 (United States); Walton, John [Department of Civil Engineering, University of Texas at El Paso, 500 W. University, El Paso, TX, 79968 (United States)

2007-07-01T23:59:59.000Z

474

Effect of dimensionality on vapor-liquid phase transition  

SciTech Connect (OSTI)

Dimensionality play significant role on ‘phase transitions’. Fluids in macroscopic confinement (bulk or 3-Dimensional, 3D) do not show significant changes in their phase transition properties with extent of confinement, since the number of molecules away from the surrounding surfaces is astronomically higher than the number of molecules in close proximity of the confining surfaces. In microscopic confinement (quasi 3D to quasi-2D), however, the number of molecules away from the close proximity of the surface is not as high as is the case with macroscopic (3D) confinement. Hence, under the same thermodynamic conditions ‘phase transition’ properties at microscopic confinement may not remain the same as the macroscopic or 3D values. Phase transitions at extremely small scale become very sensitive to the dimensions as well as the surface characteristics of the system. In this work our investigations reveal the effect of dimensionality on the phase transition from 3D to quasi-2D to 2D behavior. We have used grand canonical transition matrix Monte Carlo simulation to understand the vapor–liquid phase transitions from 3D to quasi-2D behavior. Such studies can be helpful in understanding and controlling the fluid film behaviour confined between solid surfaces of few molecular diameters, for example, in lubrication applications.

Singh, Sudhir Kumar, E-mail: sksingh@thapar.edu [Department Chemical Engineering, Thapar University, Patiala-147004 Punjab (India)

2014-04-24T23:59:59.000Z

475

Tank Vapor Characterization Project: Headspace vapor characterization of Hanford Waste Tank U-204, Results from samples collected on August 8, 1995  

SciTech Connect (OSTI)

This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-U-204 (Tank U-204) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank-farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNL. Analyte concentrations were based on analytical results and, where appropriate, sample volumes provided by WHC. A summary of the results is listed. Detailed descriptions of the analytical results appear in the text.

Clauss, T.W.; Evans, J.C.; McVeety, B.D.; Pool, K.H.; Thomas, B.L.; Olsen, K.B.; Fruchter, J.S.; Ligotke, M.W.

1995-11-01T23:59:59.000Z

476

PCR markers for Triticum speltoides leaf rust resistance gene Lr51 and their use to develop isogenic hard red spring wheat lines  

E-Print Network [OSTI]

greenhouse set at 18 to 21?C with supplemen- tal metal halide lighting.greenhouse set at 18 to 21?C with 8 h of metal halide supplemental lighting

Helguera, M; Vanzetti, L; Soria, M; Khan, I A; Kolmer, J; Dubcovsky, Jorge

2005-01-01T23:59:59.000Z

477

Mercury Vapor At Lahaina-Kaanapali Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Lahaina-Kaanapali Area (Thomas, 1986) Mercury Vapor At Lahaina-Kaanapali Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lahaina-Kaanapali Area (Thomas, 1986) Exploration Activity Details Location Lahaina-Kaanapali Area Exploration Technique Mercury Vapor Activity Date Usefulness not indicated DOE-funding Unknown Notes The soil mercury concentration and radon emanometry patterns observed for the Lahaina prospect were similar to those found in Olowalu. Several localized zones of high mercury concentration or enhanced radon emanation were observed, but showed little relationship to each other or to the recognized geologic structure in the area. The data were interpreted to suggest that there might be a small thermal anomaly to the northeast of the

478

GPS Water Vapor Projects Within the ARM Southern Great Plains Region  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

GPS Water Vapor Projects Within the ARM GPS Water Vapor Projects Within the ARM Southern Great Plains Region J. Braun, T. Van Hove, S. Y. Ha, and C. Rocken GPS Science and Technology Program University Corporation for Atmospheric Research Boulder, Colorado Abstract The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program has a need for an improved capability to measure and characterize the four-dimensional distribution of water vapor within the atmosphere. Applications for this type of data include their use in radiation transfer studies, cloud-resolving and single-column models, and for the establishment of an extended time series of water vapor observations. The University Corporation for Atmospheric Research's (UCAR) GPS Science and Technology (GST) Program is working with ARM to leverage the substantial investment in

479

Mercury Vapor At Hualalai Northwest Rift Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Hualalai Northwest Rift Area (Thomas, 1986) Mercury Vapor At Hualalai Northwest Rift Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Hualalai Northwest Rift Area (Thomas, 1986) Exploration Activity Details Location Hualalai Northwest Rift Area Exploration Technique Mercury Vapor Activity Date Usefulness not indicated DOE-funding Unknown Notes The Hualalai lower northwest rift and southern flank were sampled for soil mercury concentration and radon emanation rates (Cox and Cuff, 1981d). The data generated by these surveys yielded complex patterns of mercury concentrations and radon emanation rates that generally did not show coincident anomalies (Figs 42, 43). References Donald M. Thomas (1 January 1986) Geothermal Resources Assessment In

480

Glenwood Springs Vapor Caves Pool & Spa Low Temperature Geothermal Facility  

Open Energy Info (EERE)

Springs Vapor Caves Pool & Spa Low Temperature Geothermal Facility Springs Vapor Caves Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Glenwood Springs Vapor Caves Pool & Spa Low Temperature Geothermal Facility Facility Glenwood Springs Vapor Caves Sector Geothermal energy Type Pool and Spa Location Glenwood Springs, Colorado Coordinates 39.5505376°, -107.3247762° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

Note: This page contains sample records for the topic "vapor metal halide" from the National Library of EnergyBeta (NLEBeta).
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481

Mercury Vapor At Valley Of Ten Thousand Smokes Region Area (Kodosky, 1989)  

Open Energy Info (EERE)

Mercury Vapor At Valley Of Ten Thousand Smokes Region Area (Kodosky, 1989) Mercury Vapor At Valley Of Ten Thousand Smokes Region Area (Kodosky, 1989) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Valley Of Ten Thousand Smokes Region Area (Kodosky, 1989) Exploration Activity Details Location Valley Of Ten Thousand Smokes Region Area Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes One-hundred twelve samples were collected from relatively unaltered air-fall ejecta along two Novarupta Basin traverse lines (Fig. 5). One hundred eighty-two samples were taken from active/fossil fumaroles in Novarupta Basin (22 sites, Fig. 5), fossil fumaroles (41 sites) and air-fall tephra (2 sites) within and immediately adjacent to the remainder of the VTTS (Fig. 6). In total, 294 samples were collected from 127 sites

482

Fault detection methods for vapor-compression air conditioners using electrical measurements  

E-Print Network [OSTI]

(cont.) This method was experimentally tested and validated on a commercially available air handler and duct system. In the second class of faults studied, liquid refrigerant, rather than vapor, enters the cylinder of a ...

Laughman, Christopher Reed.

2008-01-01T23:59:59.000Z

483

Exergy analysis and experimental study of a vapor compression refrigeration cycle  

Science Journals Connector (OSTI)

This article presents a detailed experimental analysis of 2TR (ton of refrigeration) vapor compression refrigeration cycle for different percentage of refrigerant charge using exergy analysis. An experimental set...

S. Anand; S. K. Tyagi

2012-11-01T23:59:59.000Z

484

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From  

E-Print Network [OSTI]

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2010 William Acree, Jr. Department of Chemistry, University of North Texas, Denton, Texas 76203 James S. Chickosa... Department of Chemistry and Biochemistry

Chickos, James S.

485

Initiated chemical vapor deposition of polymeric thin films : mechanism and applications  

E-Print Network [OSTI]

Initiated chemical vapor deposition (iCVD) is a novel technique for depositing polymeric thin films. It is able to deposit thin films of application-specific polymers in one step without using any solvents. Its uniqueness ...

Chan, Kelvin, Ph. D. Massachusetts Institute of Technology

2005-01-01T23:59:59.000Z

486

Radon Transect Studies in Vapor- and Liquid-Dominated Geothermal Reservoirs  

SciTech Connect (OSTI)

This communication describes the transect analysis conducted at the vapor-dominated reservoirs at The Geysers in California and the liquid-dominated reservoirs at Cerro Prieto in Baja, California.

Semprini, Lewis; Kruger, Paul

1980-12-16T23:59:59.000Z

487

Vapor-liquid critical and interfacial properties of square-well fluids in slit pores  

E-Print Network [OSTI]

Jayant K. Singh,1,a and Sang Kyu Kwak2 1 Department of Chemical Engineering, Indian Institute and the shift of the vapor-liquid critical point. Nevertheless, in recent years, with the discovery of well

Singh, Jayant K.

488

Oxidative chemical vapor deposition of conductive polymers for use in novel photovoltaic device architectures  

E-Print Network [OSTI]

The conductive polymer poly(3,4-ethylenedioxythiophene), (PEDOT), deposited via oxidative chemical vapor deposition (oCVD) has been investigated for use in organic electronic devices. The oCVD process as well as the ...

Howden, Rachel M. (Rachel Mary)

2013-01-01T23:59:59.000Z

489

Iron (III) Chloride doping of large-area chemical vapor deposition graphene  

E-Print Network [OSTI]

Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

Song, Yi, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

490

The kinetics of heterogeneous nucleation in vapor-liquid phase transitions in the presence of ions  

Science Journals Connector (OSTI)

A method for calculating the work of nucleus formation in vapor-liquid phase transitions in the presence of ions was suggested. The method took into account ions localized in the boundary surface layer of...

G. V. Anikin; L. S. Podenko

2008-12-01T23:59:59.000Z

491

CO-CATALYTIC ABSORPTION LAYERS FOR CONTROLLED LASER-INDUCED CHEMICAL VAPOR DEPOSITION OF CARBON NANOTUBES  

E-Print Network [OSTI]

The concept of co-catalytic layer structures for controlled laser-induced chemical vapor deposition of carbon nanotubes is established, in which a thin Ta support layer chemically aids the initial Fe catalyst reduction. This enables a significant...

Michaelis, F.B.; Weatherup, R.S.; Bayer, B.C.; Bock, M.C.D; Sugime, H.; Caneva, S.; Robertson, J.; Baumberg, J.J.; Hofmann, S.

2014-02-24T23:59:59.000Z

492

Single- and few-layer graphene by ambient pressure chemical vapor deposition on nickel  

E-Print Network [OSTI]

An ambient pressure chemical vapor deposition (APCVD) process is used to fabricate graphene based films consisting of one to several graphene layers across their area. Polycrystalline Ni thin films are used and the graphene ...

Reina Ceeco, Alfonso

2010-01-01T23:59:59.000Z

493

Tropospheric Water Vapor Profiles Retrieved from Pressure-Broadened Emission Spectra at 22 GHz  

Science Journals Connector (OSTI)

The authors present the analysis and the evaluation of the retrieval of tropospheric water vapor profiles from pressure-broadened emission spectra at 22 GHz measured with a ground-based microwave spectroradiometer. The spectra have a bandwidth of ...

Alexander Haefele; Niklaus Kämpfer

2010-01-01T23:59:59.000Z

494

Plasma Enhanced Chemical Vapor Deposition on Living Substrates: Development, Characterization, and Biological Applications  

E-Print Network [OSTI]

This dissertation proposed the idea of “plasma-enhanced chemical vapor deposition on living substrates (PECVD on living substrates)” to bridge the gap between the thin film deposition technology and the biological and living substrates. This study...

Tsai, Tsung-Chan 1982-

2012-12-05T23:59:59.000Z

495

Understanding the Nanotube Growth Mechanism: A Strategy to Control Nanotube Chirality during Chemical Vapor Deposition Synthesis  

E-Print Network [OSTI]

during chemical vapor deposition synthesis must focus on controlling the structure of the nucleated nanotube seeds. DFT and RMD simulations demonstrate the viability of using the structures of catalyst particles over which nanotube growth proceeds...

Gomez Gualdron, Diego Armando 1983-

2012-10-26T23:59:59.000Z

496

E-Print Network 3.0 - acid vapor pressures Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 22 3b. Thermodynamics of moist air Water phase, water latent heat of vaporization Lv Summary: 3b. Thermodynamics of moist air Water phase, water latent...

497

Structure/processing relationships in vapor-liquid-solid nanowire epitaxy  

E-Print Network [OSTI]

The synthesis of Si and III-V nanowires using the vapor-liquid-solid (VLS) growth mechanism and low-cost Si substrates was investigated. The VLS mechanism allows fabrication of heterostructures which are not readily ...

Boles, Steven Tyler

2010-01-01T23:59:59.000Z

498

Desalination-of water by vapor-phase transport through hydrophobic nanopores  

E-Print Network [OSTI]

We propose a new approach to desalination of water whereby a pressure difference across a vapor-trapping nanopore induces selective transport of water by isothermal evaporation and condensation across the pore. Transport ...

Lee, Jongho

499

Inexpensive Near-IR Sun Photometer for Measuring Total Column Water Vapor  

Science Journals Connector (OSTI)

An inexpensive two-channel near-IR sun photometer for measuring total atmospheric column water vapor (precipitable water) has been developed for use by the Global Learning and Observations to Benefit the Environment (GLOBE) environmental science ...

David R. Brooks; Forrest M. Mims III; Richard Roettger

2007-07-01T23:59:59.000Z

500

Temperature and water vapor pressure effects on the friction coefficient of hydrogenated diamondlike carbon films.  

SciTech Connect (OSTI)

Microtribological measurements of a hydrogenated diamondlike carbon film in controlled gaseous environments show that water vapor plays a significant role in the friction coefficient. These experiments reveal an initial high friction transient behavior that does not reoccur even after extended periods of exposure to low partial pressures of H{sub 2}O and O{sub 2}. Experiments varying both water vapor pressure and sample temperature show trends of a decreasing friction coefficient as a function of both the decreasing water vapor pressure and the increasing substrate temperature. Theses trends are examined with regard to first order gas-surface interactions. Model fits give activation energies on the order of 40 kJ/mol, which is consistent with water vapor desorption.

Dickrell, P. L.; Sawyer, W. G.; Eryilmaz, O. L.; Erdemir, A.; Energy Technology; Univ. of Florida

2009-07-01T23:59:59.000Z