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Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Preconcentrator with high volume chiller for high vapor pressure particle detection  

SciTech Connect (OSTI)

Apparatus and method for collecting particles of both high and low vapor pressure target materials entrained in a large volume sample gas stream. Large volume active cooling provides a cold air supply which is mixed with the sample gas stream to reduce the vapor pressure of the particles. In embodiments, a chiller cools air from ambient conditions to 0-15.degree. C. with the volumetric flow rate of the cold air supply being at least equal to the volumetric flow rate of the sample gas stream. In further embodiments an adsorption media is heated in at least two stages, a first of which is below a threshold temperature at which decomposition products of the high vapor pressure particle are generated.

Linker, Kevin L

2013-10-22T23:59:59.000Z

2

OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR  

E-Print Network [OSTI]

OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR K.J. BACHMANN of computer simulations as an optimal design tool which lessens the costs in time and effort in experimental vapor deposition (HPOMCVD) reactor for use in thin film crystal growth. The advantages of such a reactor

3

VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS  

SciTech Connect (OSTI)

This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

Eric M. Suuberg; Vahur Oja

1997-07-01T23:59:59.000Z

4

To estimate vapor pressure easily  

SciTech Connect (OSTI)

Vapor pressures as functions of temperature for approximately 700 major organic chemical compounds are given. The tabulation also gives the temperature range for which the data are applicable. Minimum and maximum temperatures are denoted by TMIN and TMAX. The Antoine equation that correlates vapor pressure as a function of temperature is described. A representative comparison of calculated and actual data values for vapor pressure is shown for ethyl alcohol. The coefficient tabulation is based on both literature (experimental data) and estimated values.

Yaws, C.L.; Yang, H.C. (Lamar Univ., Beaumont, TX (USA))

1989-10-01T23:59:59.000Z

5

Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects  

E-Print Network [OSTI]

* Department of Chemistry and Biochemistry, University of MissourisSt. Louis, St. Louis, Missouri 63121 Liquid vapor pressure isotope effects have generally been observed, pD > pH.12 Vapor pressure and sublimation

Chickos, James S.

6

Pore evolution during high pressure atomic vapor deposition D. D. Hass Y. Y. Yang H. N. G. Wadley  

E-Print Network [OSTI]

The development of physical vapor deposition systems that employ inert gas jets to entrain and deposit atomic conditions can contain a higher volume fraction of porosity and a different pore morphology to coatings created by conventional, low pressure (\\10-4 Pa) deposition processes. A recent direct simulation Monte

Wadley, Haydn

7

HIGH PRESSURE VAPOR TRANSPORT OF ZnGeP 2 : II. THREEDIMENSIONAL SIMULATION OF GASDYNAMICS UNDER  

E-Print Network [OSTI]

grant #DMS­9201252. 2 To appear in the proceedings of the International Symposium on Experimental for Research in Scientific Computation Department of Mathematics North Carolina State University Raleigh, NC Carolina State University Raleigh, NC, USA Abstract The fluid dynamics in a vertical reactor for high

8

VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA  

E-Print Network [OSTI]

.B. Department of Chemistry, Moscow State University, Moscow, 119899, Russia Bonnell D.W., Hastie J.W. National temperature chemistry situations, vapor pressures are typically less than 100 kPa. The molar volume is p = 101325 Pa). The subscript trs denotes that the changeisfor a transition, typically sublimation

Rudnyi, Evgenii B.

9

The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance by Correlation Gas  

E-Print Network [OSTI]

by Correlation Gas Chromatography Chase Gobble, Nigam Rath, and James Chickos* Department of Chemistry Information ABSTRACT: Vapor pressures, vaporization, and sublimation enthalpies of several pharmaceuticals and boiling temperatures when available. Sublimation enthalpies and vapor pressures are also evaluated for 1

Chickos, James S.

10

Vapor Pressure measurements for dichlorosilane  

E-Print Network [OSTI]

with applications requiring precise control of the placement and thickness of layers of pure silicon. Chlorosilanes are a group of silanes that contain chlorine. Some of the more common chlorosilanes are dichlorosilane (SiH, Cl, ), uichlorosilane (SiHC1... applications is manufactured by reaction of silanes or chlorosilanes to deposit pure silicon. The stringent purity requirements of the semiconductor industry require extremely high purity levels in the manufactured silicon and, as a prerequisite...

Morris, Tony Knimbula

1997-01-01T23:59:59.000Z

11

Atmospheric Pressure Chemical Vapor Deposition of High Silica SiO2-TiO2 Antireflective Thin Films for Glass Based Solar Panels  

SciTech Connect (OSTI)

The atmospheric pressure chemical vapor deposition (APCVD) of SiO2-TiO2 thin films employing [[(tBuO)3Si]2O-Ti(OiPr)2], which can be prepared from commercially available materials, results in antireflective thin films on float glass under industrially relevant manufacturing conditions. It was found that while the deposition temperature had an effect on the SiO2:TiO2 ratio, the thickness was dependent on the time of deposition. This study shows that it is possible to use APCVD employing a single source precursor containing titanium and silicon to produce thin films on float glass with high SiO2:TiO2 ratios.

Klobukowski, Erik R [ORNL; Tenhaeff, Wyatt E [ORNL; McCamy, James [PPG; Harris, Caroline [PPG; Narula, Chaitanya Kumar [ORNL

2013-01-01T23:59:59.000Z

12

Analysis of crude oil vapor pressures at the U.S. Strategic Petroleum Reserve.  

SciTech Connect (OSTI)

Crude oil storage caverns at the U.S. Strategic Petroleum Reserve (SPR) are solution-mined from subsurface salt domes along the U.S. Gulf Coast. While these salt domes exhibit many attractive characteristics for large-volume, long-term storage of oil such as low cost for construction, low permeability for effective fluids containment, and secure location deep underground, they also present unique technical challenges for maintaining oil quality within delivery standards. The vapor pressures of the crude oils stored at SPR tend to increase with storage time due to the combined effects of geothermal heating and gas intrusion from the surrounding salt. This presents a problem for oil delivery offsite because high vapor-pressure oil may lead to excessive atmospheric emissions of hydrocarbon gases that present explosion hazards, health hazards, and handling problems at atmospheric pressure. Recognizing this potential hazard, the U.S. Department of Energy, owner and operator of the SPR, implemented a crude oil vapor pressure monitoring program that collects vapor pressure data for all the storage caverns. From these data, DOE evaluates the rate of change in vapor pressures of its oils in the SPR. Moreover, DOE implemented a vapor pressure mitigation program in which the oils are degassed periodically and will be cooled immediately prior to delivery in order to reduce the vapor pressure to safe handling levels. The work described in this report evaluates the entire database since its origin in 1993, and determines the current levels of vapor pressure around the SPR, as well as the rate of change for purposes of optimizing both the mitigation program and meeting safe delivery standards. Generally, the rate of vapor pressure increase appears to be lower in this analysis than reported in the past and, problematic gas intrusion seems to be limited to just a few caverns. This being said, much of the current SPR inventory exceeds vapor pressure delivery guidelines and must be degassed and cooled in order to meet current delivery standards.

Rudeen, David Keith (GRAM, Inc., Albuquerque, NM); Lord, David L.

2005-08-01T23:59:59.000Z

13

Temperature dependent vapor pressures of chlorinated catechols, syringols, and syringaldehydes  

SciTech Connect (OSTI)

The vapor pressures of nine chlorinated catechols, syringols, and syringaldehydes were determined as a function of temperature with a gas chromatographic retention time technique. The vapor pressures at 298.15 K were in the range of 0.02--1 Pa, and the enthalpies of vaporization, between 68 and 82 kJ/mol. The validity of the technique was established by a calibration involving four chlorinated phenols with well-known vapor pressures. Using these data and previously reported solubility data, Henry`s law constants for these substances and some chlorinated guaiacols and veratrols were estimated. The vapor pressure of these substances tends to decrease with increasing polarity and an increasing number of chlorine atoms. Henry`s law constants decrease sharply with increasing polarity, suggesting that methylation can result in a significant increase in a chemical`s potential for volatilization from water.

Lei, Y.D.; Shiu, W.Y.; Boocock, D.G.B. [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry] [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry; Wania, F. [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)] [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)

1999-03-01T23:59:59.000Z

14

Bilayer graphene growth by low pressure chemical vapor deposition on copper foil  

E-Print Network [OSTI]

Successfully integrating graphene in standard processes for applications in electronics relies on the synthesis of high-quality films. In this work we study Low Pressure Chemical Vapor Deposition (LPCVD) growth of bilayer ...

Fang, Wenjing, S.M. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

15

Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids  

E-Print Network [OSTI]

Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids Joe A. Wilson and James S. Chickos* Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121, United States *S Supporting Information ABSTRACT: Sublimation enthalpies

Chickos, James S.

16

Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography  

E-Print Network [OSTI]

Chromatography Chase Gobble and James Chickos* Department of Chemistry and Biochemistry University of Missouri-St. Louis, St. Louis Missouri 63121, United States Sergey P. Verevkin Department of Physical Chemistry: Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl

Chickos, James S.

17

Evaporation monitoring and composition control of alloy systems with widely differing vapor pressures  

SciTech Connect (OSTI)

Lawrence Livermore National Laboratory is developing sensors and controls to improve and extend electron beam materials processing technology to alloy systems with constituents of widely varying vapor pressure. The approach under development involves using tunable lasers to measure the density and composition of the vapor plume. A laser based vaporizer control system for vaporization of a uranium-iron alloy has been previously demonstrated in multi-hundred hour, high rate vaporization experiments at LLNL. This paper reviews the design and performance of the uranium vaporization sensor and control system and discusses the extension of the technology to monitoring of uranium vaporization. Data is presented from an experiment in which titanium wire was fed into a molten niobium pool. Laser data is compared to deposited film composition and film cross sections. Finally, the potential for using this technique for composition control in melting applications is discussed.

Anklam, T.M.; Berzins, L.V.; Braun, D.G.; Haynam, C.; McClelland, M.A.; Meier, T.

1994-10-01T23:59:59.000Z

18

Evaporation monitoring and composition control of alloy systems with widely differing vapor pressures  

SciTech Connect (OSTI)

Lawrence Livermore National Laboratory is developing sensors and controls to improve and extend electron beam materials processing technology to alloy systems with constituents of widely varying vapor pressure. The approach under development involves using tunable lasers to measure the density and composition of the vapor plume. A laser based vaporizer control system for vaporization of a uranium-iron alloy has been previously demonstrated in multi-hundred hour, high rate vaporization experiments at LLNL. This paper reviews the design and performance of the uranium vaporization sensor and control system and discusses the extension of the technology to monitoring of titanium vaporization. Data is presented from an experiment in which titanium wire was fed into a molten niobium pool. Laser data is compared to deposited film composition and film cross sections. Finally, the potential for using this technique for composition control in melting applications is discussed.

Anklam, T.M.; Berzins, L.V.; Braun, D.G.; Haynam, C.; McClelland, M.A.; Meier, T. [Lawrence Livermore National Lab., CA (United States)

1994-12-31T23:59:59.000Z

19

Temperature and water vapor pressure effects on the friction coefficient of hydrogenated diamondlike carbon films.  

SciTech Connect (OSTI)

Microtribological measurements of a hydrogenated diamondlike carbon film in controlled gaseous environments show that water vapor plays a significant role in the friction coefficient. These experiments reveal an initial high friction transient behavior that does not reoccur even after extended periods of exposure to low partial pressures of H{sub 2}O and O{sub 2}. Experiments varying both water vapor pressure and sample temperature show trends of a decreasing friction coefficient as a function of both the decreasing water vapor pressure and the increasing substrate temperature. Theses trends are examined with regard to first order gas-surface interactions. Model fits give activation energies on the order of 40 kJ/mol, which is consistent with water vapor desorption.

Dickrell, P. L.; Sawyer, W. G.; Eryilmaz, O. L.; Erdemir, A.; Energy Technology; Univ. of Florida

2009-07-01T23:59:59.000Z

20

Method and apparatus to measure vapor pressure in a flow system  

DOE Patents [OSTI]

The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process.

Grossman, Mark W. (Belmont, MA); Biblarz, Oscar (Swampscott, MA)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Correlation for the Vapor Pressure of Heavy Water From the Triple Point to the Critical Point  

E-Print Network [OSTI]

Correlation for the Vapor Pressure of Heavy Water From the Triple Point to the Critical Point Allan the vapor pressure of heavy water (D2O) from its triple point to its critical point. This work takes Institute of Physics. Key words: D2O; heavy water; ITS-90; vapor pressure. Contents 1. Introduction

Magee, Joseph W.

22

VAPOR PRESSURE ISOTOPE EFFECTS IN THE MEASUREMENT OF ENVIRONMENTAL TRITIUM SAMPLES.  

SciTech Connect (OSTI)

Standard procedures for the measurement of tritium in water samples often require distillation of an appropriate sample aliquot. This distillation process may result in a fractionation of tritiated water and regular light water due to the vapor pressure isotope effect, introducing either a bias or an additional contribution to the total tritium measurement uncertainty. The magnitude of the vapor pressure isotope effect is characterized as functions of the amount of water distilled from the sample aliquot and the heat settings for the distillation process. The tritium concentration in the distillate is higher than the tritium concentration in the sample early in the distillation process, it then sharply decreases due to the vapor pressure isotope effect and becomes lower than the tritium concentration in the sample, until the high tritium concentration retained in the boiling flask is evaporated at the end of the process. At that time, the tritium concentration in the distillate again overestimates the sample tritium concentration. The vapor pressure isotope effect is more pronounced the slower the evaporation and distillation process is conducted; a lower heat setting during the evaporation of the sample results in a larger bias in the tritium measurement. The experimental setup used and the fact that the current study allowed for an investigation of the relative change in vapor pressure isotope effect in the course of the distillation process distinguish it from and extend previously published measurements. The separation factor as a quantitative measure of the vapor pressure isotope effect is found to assume values of 1.034 {+-} 0.033, 1.052 {+-} 0.025, and 1.066 {+-} 0.037, depending on the vigor of the boiling process during distillation of the sample. A lower heat setting in the experimental setup, and therefore a less vigorous boiling process, results in a larger value for the separation factor. For a tritium measurement in water samples, this implies that the tritium concentration could be underestimated by 3 - 6%.

Kuhne, W.

2012-12-03T23:59:59.000Z

23

High temperature pressure gauge  

DOE Patents [OSTI]

A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

1981-01-01T23:59:59.000Z

24

High pressure counterflow CHF.  

E-Print Network [OSTI]

This is a report of the experimental results of a program in countercurrent flow critical heat flux. These experiments were performed with Freon 113 at 200 psia in order to model a high pressure water system. An internally ...

Walkush, Joseph Patrick

1975-01-01T23:59:59.000Z

25

Method and apparatus to measure vapor pressure in a flow system  

DOE Patents [OSTI]

The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process. 2 figures.

Grossman, M.W.; Biblarz, O.

1991-10-15T23:59:59.000Z

26

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

Morris, D.E.

1993-09-14T23:59:59.000Z

27

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

28

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

29

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1993-01-01T23:59:59.000Z

30

VAPORIZATION OF TUNGSTEN-METAL IN STEAM AT HIGH TEMPERATURES.  

SciTech Connect (OSTI)

The vaporization of tungsten from the APT spallation target dominates the radiological source term for unmitigated target overheating accidents. Chemical reactions of tungsten with steam which persist to tungsten temperatures as low as 800 C result in the formation of a hydrated tungsten-oxide which has a high vapor pressure and is readily convected in a flowing atmosphere. This low-temperature vaporization reaction essentially removes the oxide film that forms on the tungsten-metal surface as soon as it forms, leaving behind a fresh metallic surface for continued oxidation and vaporization. Experiments were conducted to measure the oxidative vaporization rates of tungsten in steam as part of the effort to quantify the MT radiological source term for severe target accidents. Tests were conducted with tungsten rods (1/8 inch diameter, six inches long) heated to temperatures from approximately 700 C to 1350 C in flowing steam which was superheated to 140 C. A total of 19 experiments was conducted. Fifteen tests were conducted by RF induction heating of single tungsten rods held vertical in a quartz glass retort. Four tests were conducted in a vertically-mounted tube furnace for the low temperature range of the test series. The aerosol which was generated and transported downstream from the tungsten rods was collected by passing the discharged steam through a condenser. This procedure insured total collection of the steam along with the aerosol from the vaporization of the rods. The results of these experiments revealed a threshold temperature for tungsten vaporization in steam. For the two tests at the lowest temperatures which were tested, approximately 700 C, the tungsten rods were observed to oxidize without vaporization. The remainder of the tests was conducted over the temperature range of 800 C to 1350 C. In these tests, the rods were found to have lost weight due to vaporization of the tungsten and the missing weight was collected in the downstream condensate system. The aerosol formed a fine white smoke of tungsten-oxide which was visible to the eye as it condensed in the laminar boundary layer of steam which flowed along the surface of the rod. The aerosol continued to flow as a smoke tube downstream of the rod, flowing coaxially along the centerline axis of the quartz glass tube and depositing by impaction along the outside of a bend and at sudden area contractions in the piping. The vaporization rate data from the 17 experiments which exceeded the vaporization threshold temperature are shown in Figure 5 in the form of vaporization rates (g/cm{sup 2} s) vs. inverse temperature (K{sup {minus}1}). Two correlations to the present data are presented and compared to a published correlation by Kilpatrick and Lott. The differences are discussed.

GREENE,G.A.; FINFROCK,C.C.

2000-10-01T23:59:59.000Z

31

The effects of two levels of water vapor pressure on localized sweat rate in high fit males running at 50% VO? Max  

E-Print Network [OSTI]

, workload and VO& Max by correlative methods. Procedures Twelve male volunteers were selected as subjects from a Physical Education class at Texas A&M University. The criterion for selection -1 . -1 as a subject was a VO Max greater than 57 ml kg min.... Schvartz et al. (70) found subjects with high VO Max values (mean of 60. 1 ml kg min ) to respond better to heat than those with 1 medium and low Y02 Max values (means of 47. 7 and 35. 6 ml ~ kg ' n", . n respectively) with lower heart rates...

Sockler, James Michael

2012-06-07T23:59:59.000Z

32

Atmospheric pressure chemical vapor deposition of TiN from tetrakis(dimethylamido)titanium and ammonia  

E-Print Network [OSTI]

pressure chemical vapor deposition. Experiments were conducted in a belt furnace; static experiments, in particular, is used for tool coating, solar-control films, and micro- electronic applications. Optically

33

Single- and few-layer graphene by ambient pressure chemical vapor deposition on nickel  

E-Print Network [OSTI]

An ambient pressure chemical vapor deposition (APCVD) process is used to fabricate graphene based films consisting of one to several graphene layers across their area. Polycrystalline Ni thin films are used and the graphene ...

Reina Ceeco, Alfonso

2010-01-01T23:59:59.000Z

34

Integrated rig for the production of boron nitride nanotubes via the pressurized vapor-condenser method  

DOE Patents [OSTI]

An integrated production apparatus for production of boron nitride nanotubes via the pressure vapor-condenser method. The apparatus comprises: a pressurized reaction chamber containing a continuously fed boron containing target having a boron target tip, a source of pressurized nitrogen and a moving belt condenser apparatus; a hutch chamber proximate the pressurized reaction chamber containing a target feed system and a laser beam and optics.

Smith, Michael W; Jordan, Kevin C

2014-03-25T23:59:59.000Z

35

High-pressure neutron diffraction  

SciTech Connect (OSTI)

This lecture will cover progress and prospect of applications of high-pressure neutron diffraction techniques to Earth and materials sciences. I will first introduce general high-pressure research topics and available in-situ high-pressure techniques. Then I'll talk about high-pressure neutron diffraction techniques using two types of pressure cells: fluid-driven and anvil-type cells. Lastly, I will give several case studies using these techniques, particularly, those on hydrogen-bearing materials and magnetic transitions.

Xu, Hongwu [Los Alamos National Laboratory

2011-01-10T23:59:59.000Z

36

High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds  

SciTech Connect (OSTI)

The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography.

John C. Chen; Vinayak N. Kabadi

1998-11-12T23:59:59.000Z

37

A new vapor pressure equation originating at the critical point  

E-Print Network [OSTI]

. , and I. J. Lawrenson, "The Vapour Pressure of Water, " J. Chem. Thermod . , 4, "/55 (1972). Ambrose, D. , and C. H. S. Sprake, "Thermodynamic Proper- ties of Organic Oxygen Compounds XXV. Vapour Pressures and Normal Boiling Temperatures of Alipha- tic... Alcohols, " J. Chem. Thermod n. , 2, 631 (1970). Ambrose, D. , C. H. S. Sprake, and R. Townsend, "Thermodynamic Properties of Organic Oxygen Compounds XXXIII. The Vapour Pressure of Acetone, " J. Chem. ~Th r od . , 6, 693 (1976). American Petroleum...

Nuckols, James William

1976-01-01T23:59:59.000Z

38

A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems  

SciTech Connect (OSTI)

In this article we introduce a simple grand canonical screening (GCS) approach to accurately compute vapor pressures from molecular dynamics or Monte Carlo simulations. This procedure entails a screening of chemical potentials using a conventional grand canonical scheme, and therefore it is straightforward to implement for any kind of interface. The scheme is validated against data obtained from Gibbs ensemble simulations for water and argon. Then, it is applied to obtain the vapor pressure of the coarse-grained mW water model, and it is shown that the computed value is in excellent accord with the one formally deduced using statistical thermodynamics arguments. Finally, this methodology is used to calculate the vapor pressure of a water nanodroplet of 94 molecules. Interestingly, the result is in perfect agreement with the one predicted by the Kelvin equation for a homogeneous droplet of that size.

Factorovich, Matías H.; Scherlis, Damián A. [Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, Buenos Aires C1428EHA (Argentina)] [Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, Buenos Aires C1428EHA (Argentina); Molinero, Valeria [Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)] [Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)

2014-02-14T23:59:59.000Z

39

Electrokinetically pumped high pressure sprays  

DOE Patents [OSTI]

An electrokinetic pump capable of producing high pressure is combined with a nozzle having a submicron orifice to provide a high pressure spray device. Because of its small size, the device can be contained within medical devices such as an endoscope for delivering biological materials such as DNA, chemo therapeutic agents, or vaccines to tissues and cells.

Schoeniger, Joseph S. (Oakland, CA); Paul, Phillip H. (Livermore, CA); Schoeniger, Luke (Pittsford, NY)

2002-01-01T23:59:59.000Z

40

Fundamentals of high pressure adsorption  

SciTech Connect (OSTI)

High-pressure adsorption attracts research interests following the world's attention to alternative fuels, and it exerts essential effect on the study of hydrogen/methane storage and the development of novel materials addressing to the storage. However, theoretical puzzles in high-pressure adsorption hindered the progress of application studies. Therefore, the present paper addresses the major theoretical problems that challenged researchers: i.e., how to model the isotherms with maximum observed in high-pressure adsorption; what is the adsorption mechanism at high pressures; how do we determine the quantity of absolute adsorption based on experimental data. Ideology and methods to tackle these problems are elucidated, which lead to new insights into the nature of high-pressure adsorption and progress in application studies, for example, in modeling multicomponent adsorption, hydrogen storage, natural gas storage, and coalbed methane enrichment, was achieved.

Zhou, Y.P.; Zhou, L. [Tianjin University, Tianjin (China). High Pressure Adsorption Laboratory

2009-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

High pressure storage vessel  

DOE Patents [OSTI]

Disclosed herein is a composite pressure vessel with a liner having a polar boss and a blind boss a shell is formed around the liner via one or more filament wrappings continuously disposed around at least a substantial portion of the liner assembly combined the liner and filament wrapping have a support profile. To reduce susceptible to rupture a locally disposed filament fiber is added.

Liu, Qiang

2013-08-27T23:59:59.000Z

42

Steam Oxidation at High Pressure  

SciTech Connect (OSTI)

A first high pressure test was completed: 293 hr at 267 bar and 670{degrees}C; A parallel 1 bar test was done for comparison; Mass gains were higher for all alloys at 267 bar than at 1 bar; Longer term exposures, over a range of temperatures and pressures, are planned to provide information as to the commercial implications of pressure effects; The planned tests are at a higher combination of temperatures and pressures than in the existing literature. A comparison was made with longer-term literature data: The short term exposures are largely consistent with the longer-term corrosion literature; Ferritic steels--no consistent pressure effect; Austenitic steels--fine grain alloys less able to maintain protective chromia scale as pressure increases; Ni-base alloys--more mass gains above 105 bar than below. Not based on many data points.

Holcomb, Gordon R. [NETL; Carney, Casey [URS

2013-07-19T23:59:59.000Z

43

Electrokinetic high pressure hydraulic system  

DOE Patents [OSTI]

A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.

Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

2000-01-01T23:59:59.000Z

44

Graphene chemical vapor deposition at very low pressure: The impact of substrate surface self-diffusion in domain shape  

SciTech Connect (OSTI)

The initial stages of graphene chemical vapor deposition at very low pressures (<10{sup ?5?}Torr) were investigated. The growth of large graphene domains (?up to 100??m) at very high rates (up to 3??m{sup 2} s{sup ?1}) has been achieved in a cold-wall reactor using a liquid carbon precursor. For high temperature growth (>900?°C), graphene grain shape and symmetry were found to depend on the underlying symmetry of the Cu crystal, whereas for lower temperatures (<900?°C), mostly rounded grains are observed. The temperature dependence of graphene nucleation density was determined, displaying two thermally activated regimes, with activation energy values of 6?±?1?eV for temperatures ranging from 900?°C to 960?°C and 9?±?1?eV for temperatures above 960?°C. The comparison of such dependence with the temperature dependence of Cu surface self-diffusion suggests that graphene growth at high temperatures and low pressures is strongly influenced by copper surface rearrangement. We propose a model that incorporates Cu surface self-diffusion as an essential process to explain the orientation correlation between graphene and Cu crystals, and which can clarify the difference generally observed between graphene domain shapes in atmospheric-pressure and low-pressure chemical vapor deposition.

Cunha, T. H. R.; Ek-Weis, J.; Lacerda, R. G.; Ferlauto, A. S., E-mail: ferlauto@fisica.ufmg.br [Department of Physics, Federal University of Minas Gerais, Belo Horizonte 31270-901 (Brazil)

2014-08-18T23:59:59.000Z

45

Electrokinetic high pressure hydraulic system  

DOE Patents [OSTI]

An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based system. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

2003-06-03T23:59:59.000Z

46

Electrokinetic high pressure hydraulic system  

DOE Patents [OSTI]

An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA); Arnold, Don W. (Livermore, CA); Hencken, Kenneth R. (Pleasanton, CA); Schoeniger, Joseph S. (Oakland, CA); Neyer, David W. (Castro Valley, CA)

2001-01-01T23:59:59.000Z

47

High Pressure Hydrogen Materials Compatibility of Piezoelectric...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pressure Hydrogen Materials Compatibility of Piezoelectric Films. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films. Abstract: Abstract: Hydrogen is being...

48

High pressure ceramic joint  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present joint when used with recuperators increases the use of ceramic components which do not react to highly corrosive gases. Thus, the present joint used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present joint is comprised of a first ceramic member, a second ceramic member, a mechanical locking device having a groove defined in one of the first ceramic member and the second ceramic member. The joint and the mechanical locking device is further comprised of a refractory material disposed in the groove and contacting the first ceramic member and the second ceramic member. The present joint mechanically provides a high strength load bearing joint having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures. 4 figures.

Ward, M.E.; Harkins, B.D.

1993-11-30T23:59:59.000Z

49

High pressure ceramic joint  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present joint when used with recuperators increases the use of ceramic components which do not react to highly corrosive gases. Thus, the present joint used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present joint is comprised of a first ceramic member, a second ceramic member, a mechanical locking device having a groove defined in one of the first ceramic member and the second ceramic member. The joint and the mechanical locking device is further comprised of a refractory material disposed in the groove and contacting the first ceramic member and the second ceramic member. The present joint mechanically provides a high strength load bearing joint having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

Ward, Michael E. (Poway, CA); Harkins, Bruce D. (San Diego, CA)

1993-01-01T23:59:59.000Z

50

A study of the mixed association of cholesterol with methyl cholate by vapor pressure osmometry  

E-Print Network [OSTI]

out on a Knauer Vapor Pressure Osmometer equipped w1th the Knauer Universal Temperature Measuring Apparatus (a sensitive Wheatstone bridge with a 10-turn helical potentiometer) and a chart recorder. A thorough discussion of some of the experimental... at the desired temperature. Two themistors are mounted in the chamber and are coupled to the Wheatstone bridge. Using syr1nges, a drop of pure solvent is placed on one themistor and a drop of solution on the other. Because of the lowering of solvent vapor...

Foster, Bruce William

1981-01-01T23:59:59.000Z

51

High Temperature, High Pressure Devices for Zonal Isolation in...  

Broader source: Energy.gov (indexed) [DOE]

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature,...

52

High pressure synthesis gas conversion. Task 3: High pressure profiles  

SciTech Connect (OSTI)

The purpose of this research project was to build and test a high pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system were procured or fabricated and assembled in our laboratory. This system was then used to determine the effects of high pressure on growth and ethanol production by C. 1jungdahlii. The limits of cell concentration and mass transport relationships were found in CSTR and immobilized cell reactors (ICR). The minimum retention times and reactor volumes were found for ethanol production in these reactors.

Not Available

1993-05-01T23:59:59.000Z

53

High pressure neon arc lamp  

DOE Patents [OSTI]

A high pressure neon arc lamp and method of using the same for photodynamic therapies is provided. The high pressure neon arc lamp includes a housing that encloses a quantity of neon gas pressurized to about 500 Torr to about 22,000 Torr. At each end of the housing the lamp is connected by electrodes and wires to a pulse generator. The pulse generator generates an initial pulse voltage to breakdown the impedance of the neon gas. Then the pulse generator delivers a current through the neon gas to create an electrical arc that emits light having wavelengths from about 620 nanometers to about 645 nanometers. A method for activating a photosensitizer is provided. Initially, a photosensitizer is administered to a patient and allowed time to be absorbed into target cells. Then the high pressure neon arc lamp is used to illuminate the target cells with red light having wavelengths from about 620 nanometers to about 645 nanometers. The red light activates the photosensitizers to start a chain reaction that may involve oxygen free radicals to destroy the target cells. In this manner, a high pressure neon arc lamp that is inexpensive and efficiently generates red light useful in photodynamic therapy is provided.

Sze, Robert C.; Bigio, Irving J.

2003-07-15T23:59:59.000Z

54

Observations on vapor pressure in SPR caverns : sources.  

SciTech Connect (OSTI)

The oil of the Strategic Petroleum Reserve (SPR) represents a national response to any potential emergency or intentional restriction of crude oil supply to this country, and conforms to International Agreements to maintain such a reserve. As assurance this reserve oil will be available in a timely manner should a restriction in supply occur, the oil of the reserve must meet certain transportation criteria. The transportation criteria require that the oil does not evolve dangerous gas, either explosive or toxic, while in the process of transport to, or storage at, the destination facility. This requirement can be a challenge because the stored oil can acquire dissolved gases while in the SPR. There have been a series of reports analyzing in exceptional detail the reasons for the increases, or regains, in gas content; however, there remains some uncertainty in these explanations and an inability to predict why the regains occur. Where the regains are prohibitive and exceed the criteria, the oil must undergo degasification, where excess portions of the volatile gas are removed. There are only two known sources of gas regain, one is the salt dome formation itself which may contain gas inclusions from which gas can be released during oil processing or storage, and the second is increases of the gases release by the volatile components of the crude oil itself during storage, especially if the stored oil undergoes heating or is subject to biological generation processes. In this work, the earlier analyses are reexamined and significant alterations in conclusions are proposed. The alterations are based on how the fluid exchanges of brine and oil uptake gas released from domal salt during solutioning, and thereafter, during further exchanges of fluids. Transparency of the brine/oil interface and the transfer of gas across this interface remains an important unanswered question. The contribution from creep induced damage releasing gas from the salt surrounding the cavern is considered through computations using the Multimechanism Deformation Coupled Fracture (MDCF) model, suggesting a relative minor, but potentially significant, contribution to the regain process. Apparently, gains in gas content can be generated from the oil itself during storage because the salt dome has been heated by the geothermal gradient of the earth. The heated domal salt transfers heat to the oil stored in the caverns and thereby increases the gas released by the volatile components and raises the boiling point pressure of the oil. The process is essentially a variation on the fractionation of oil, where each of the discrete components of the oil have a discrete temperature range over which that component can be volatized and removed from the remaining components. The most volatile components are methane and ethane, the shortest chain hydrocarbons. Since this fractionation is a fundamental aspect of oil behavior, the volatile component can be removed by degassing, potentially prohibiting the evolution of gas at or below the temperature of the degas process. While this process is well understood, the ability to describe the results of degassing and subsequent regain is not. Trends are not well defined for original gas content, regain, and prescribed effects of degassing. As a result, prediction of cavern response is difficult. As a consequence of this current analysis, it is suggested that solutioning brine of the final fluid exchange of a just completed cavern, immediately prior to the first oil filling, should be analyzed for gas content using existing analysis techniques. This would add important information and clarification to the regain process. It is also proposed that the quantity of volatile components, such as methane, be determined before and after any degasification operation.

Munson, Darrell Eugene

2010-05-01T23:59:59.000Z

55

High-resolution terahertz atmospheric water vapor continuum measurements  

E-Print Network [OSTI]

High-resolution terahertz atmospheric water vapor continuum measurements David M. Slocum,* Thomas M such as pollution monitoring and the detection of energetic chemicals using remote sensing over long path lengths through the atmosphere. Although there has been much attention to atmospheric effects over narrow

Massachusetts at Lowell, University of

56

Very long single- and few-walled boron nitride nanotubes via the pressurized vapor/condenser method  

SciTech Connect (OSTI)

Boron nitride nanotubes (BNNTs) are desired for their exceptional mechanical, electronic, thermal, structural, textural, optical, and quantum properties. A new method for producing long, small-diameter, single- and few-walled, boron nitride nanotubes (BNNTs) in macroscopic quantities is reported. The pressurized vapor/condenser (PVC) method produces, without catalysts, highly crystalline, very long, small-diameter, BNNTs. Palm-sized, cotton-like masses of BNNT raw material were grown by this technique and spun directly into centimeters-long yarn. Nanotube lengths were observed to be 100 times that of those grown by the most closely related method. Self-assembly and growth models for these long BNNTs are discussed.

Michael W. Smith, Kevin Jordan, Cheol Park, Jae-Woo Kim, Peter Lillehei, Roy Crooks, Joycelyn Harrison

2009-11-01T23:59:59.000Z

57

In-reactor oxidation of zircaloy-4 under low water vapor pressures  

SciTech Connect (OSTI)

Complementary in- and ex-reactor oxidation tests have been performed to evaluate the oxidation and hydrogen absorption performance of Zircaloy-4 (Zr-4) under relatively low partial pressures (300 and 1000 Pa) of water vapor at specified test temperatures (330 and 370 C). Data from these tests will be used to support the fabrication of components intended for isotope-producing targets and provide information regarding the temperature and pressure dependence of oxidation and hydrogen absorption of Zr- 4 over the specified range of test conditions. Comparisons between in- and ex-reactor test results were performed to evaluate the influence of irradiation.

Walter G. Luscher; David J. Senor; Keven K. Clayton; Glen R. Longhurst

2015-01-01T23:59:59.000Z

58

As-deposited low-strain LPCVD (low-pressure, chemical-vapor-deposition) polysilicon  

SciTech Connect (OSTI)

As-deposited polysilicon films with very low residual strain (lower than 5 x 10/sup -5/) are obtained by a low-pressure, chemical-vapor-deposition (LPCVD) process. Straight polysilicon bridges 300 ..mu..m long, 1.2 ..mu..m thick, and 2 to 20 ..mu..m wide, made using this process. No buckling has been observed in any of the nearly one thousand bridges of this type made in two separate process runs. In addition, no problems of sticking between the bridges and the substrate were encountered with these structures. The polysilicon films from which the beams were fabricated were deposited by pyrolyzing silane at 605/degree/C on a phosphosilicate-glass (PSG) layer (8 wt % P). The PSG layer serves as a sacrificial layer to be subsequently etched away to free the bridge. Our research is aimed at obtaining an understanding of these relationships through consideration of the role of interfacial stresses and the kinetics of initial crystalline nucleation. The technique for producing these low-strain films is significant, however, because no high-temperature annealing steps are required to produce them. 4 refs., 4 figs.

Fan, L.S.; Muller, R.S.

1988-08-01T23:59:59.000Z

59

High Temperature, High Pressure Devices for Zonal Isolation in...  

Broader source: Energy.gov (indexed) [DOE]

Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells DOE Geothermal Peer...

60

High average power magnetic modulator for metal vapor lasers  

DOE Patents [OSTI]

A three-stage magnetic modulator utilizing magnetic pulse compression designed to provide a 60 kV pulse to a copper vapor laser at a 4.5 kHz repetition rate is disclosed. This modulator operates at 34 kW input power. The circuit includes a step up auto transformer and utilizes a rod and plate stack construction technique to achieve a high packing factor.

Ball, Don G. (Livermore, CA); Birx, Daniel L. (Oakley, CA); Cook, Edward G. (Livermore, CA); Miller, John L. (Livermore, CA)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Low temperature atmospheric pressure chemical vapor deposition of group 14 oxide films  

SciTech Connect (OSTI)

Depositions of high quality SiO{sub 2} and SnO{sub 2} films from the reaction of homoleptic amido precursors M(NMe{sub 2})4 (M = Si,Sn) and oxygen were carried out in an atmospheric pressure chemical vapor deposition r. The films were deposited on silicon, glass and quartz substrates at temperatures of 250 to 450C. The silicon dioxide films are stoichiometric (O/Si = 2.0) with less than 0.2 atom % C and 0.3 atom % N and have hydrogen contents of 9 {plus_minus} 5 atom %. They are deposited with growth rates from 380 to 900 {angstrom}/min. The refractive indexes of the SiO{sub 2} films are 1.46, and infrared spectra show a possible Si-OH peak at 950 cm{sup {minus}1}. X-Ray diffraction studies reveal that the SiO{sub 2} film deposited at 350C is amorphous. The tin oxide films are stoichiometric (O/Sn = 2.0) and contain less than 0.8 atom % carbon, and 0.3 atom % N. No hydrogen was detected by elastic recoil spectroscopy. The band gap for the SnO{sub 2} films, as estimated from transmission spectra, is 3.9 eV. The resistivities of the tin oxide films are in the range 10{sup {minus}2} to 10{sup {minus}3} {Omega}cm and do not vary significantly with deposition temperature. The tin oxide film deposited at 350C is cassitterite with some (101) orientation.

Hoffman, D.M. [Houston Univ., TX (United States); Atagi, L.M. [Houston Univ., TX (United States)]|[Los Alamos National Lab., NM (United States); Chu, Wei-Kan; Liu, Jia-Rui; Zheng, Zongshuang [Houston Univ., TX (United States); Rubiano, R.R. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Springer, R.W.; Smith, D.C. [Los Alamos National Lab., NM (United States)

1994-06-01T23:59:59.000Z

62

Electokinetic high pressure hydraulic system  

DOE Patents [OSTI]

A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.

Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

2000-01-01T23:59:59.000Z

63

Vapor pressures and heats of vaporization of primary coal tars. Quarterly technical progress report, 1 July 1993--30 September 1993  

SciTech Connect (OSTI)

There is significant current interest in general area of coal pyrolysis, particularly with respect to comprehensive models of this complicated phenomenon. This interest derives from the central role of pyrolysis in all thermally driven coal conversion processes -- gasification, combustion, liquefaction, mild gasification, or thermal benefication. There remain several key data needs in these application areas. Among them is a need for more reliable correlation for prediction of vapor pressure of heavy, primary coal tars. Such information is important in design of all coal conversion processes, in which the volatility of tarry products is of major concern. Only very limited correlations exist, and these are not considered reliable to even an order of magnitude when applied to tars. The present project seeks to address this important gap in the near term by direct measurement of vapor pressures of coal tar fractions, by application of well-established techniques and modifications thereof. The principal objectives of the program are to: (1) obtain data on the vapor pressures and heats of vaporization of tars from a range of ranks of coal, (2) develop correlations based on a minimum set of conveniently measurable characteristics of the tars, (3) develop equipment that would allow performing such measurements in a reliable, straightforward fashion. Results of the literature survey are compiled. The experimental tasks have been concerned with setup and calibration.

Suuberg, E.M.; Oja, V.; Lilly, W.D.

1993-12-31T23:59:59.000Z

64

High-pressure microhydraulic actuator  

DOE Patents [OSTI]

Electrokinetic ("EK") pumps convert electric to mechanical work when an electric field exerts a body force on ions in the Debye layer of a fluid in a packed bed, which then viscously drags the fluid. Porous silica and polymer monoliths (2.5-mm O.D., and 6-mm to 10-mm length) having a narrow pore size distribution have been developed that are capable of large pressure gradients (250-500 psi/mm) when large electric fields (1000-1500 V/cm) are applied. Flowrates up to 200 .mu.L/min and delivery pressures up to 1200 psi have been demonstrated. Forces up to 5 lb-force at 0.5 mm/s (12 mW) have been demonstrated with a battery-powered DC-DC converter. Hydraulic power of 17 mW (900 psi@ 180 uL/min) has been demonstrated with wall-powered high voltage supplies. The force and stroke delivered by an actuator utilizing an EK pump are shown to exceed the output of solenoids, stepper motors, and DC motors of similar size, despite the low thermodynamic efficiency.

Mosier, Bruce P. (San Francisco, CA) [San Francisco, CA; Crocker, Robert W. (Fremont, CA) [Fremont, CA; Patel, Kamlesh D. (Dublin, CA) [Dublin, CA

2008-06-10T23:59:59.000Z

65

atmospheric-pressure chemical vapor: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

studied intensively and has overcome some of the constraints of traditional high-pressure high-temperature (HPHT) diamond synthesis methods (more) Chen, Yu-Chun 2009-01-01 12...

66

Vapor pressure and boiling point elevation of slash pine black liquors: Predictive models with statistical approach  

SciTech Connect (OSTI)

Vapor-liquid equilibria and boiling point elevation of slash pine kraft black liquors over a wide range of solid concentrations (up to 85% solids) has been studied. The liquors are from a statistically designed pulping experiment for pulping slash pine in a pilot scale digester with four cooking variables of effective alkali, sulfidity, cooking time, and cooking temperature. It was found that boiling point elevation of black liquors is pressure dependent, and this dependency is more significant at higher solids concentrations. The boiling point elevation data at different solids contents (at a fixed pressure) were correlated to the dissolved solids (S/(1 {minus} S)) in black liquor. Due to the solubility limit of some of the salts in black liquor, a change in the slope of the boiling point elevation as a function of the dissolved solids was observed at a concentration of around 65% solids. An empirical method was developed to describe the boiling point elevation of each liquor as a function of pressure and solids mass fraction. The boiling point elevation of slash pine black liquors was correlated quantitatively to the pulping variables, using different statistical procedures. These predictive models can be applied to determine the boiling point rise (and boiling point) of slash pine black liquors at processing conditions from the knowledge of pulping variables. The results are presented, and their utility is discussed.

Zaman, A.A.; McNally, T.W.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States)] [Univ. of Florida, Gainesville, FL (United States)

1998-01-01T23:59:59.000Z

67

NETL- High-Pressure Combustion Research Facility  

SciTech Connect (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2013-07-08T23:59:59.000Z

68

NETL- High-Pressure Combustion Research Facility  

ScienceCinema (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2014-06-26T23:59:59.000Z

69

Soot particle aerosol dynamics at high pressure  

SciTech Connect (OSTI)

The authors have used detailed calculations to analyze the coagulation dynamics of a soot aerosol at high pressures (20 and 50 atm). They find that the soot size distribution is altered compared to lower-pressure conditions because the mean free path at high pressures is reduced to the point that the particles are similar in size to the mean free path. At lower pressures the form of the size distribution becomes constant (self-preserving) in time, allowing optical measurements to be easily interpreted. However, the authors find that at pressures above about 5 atm the shape of the size distribution continually changes. As a result, proper and accurate interpretation of optical data at high pressures is more difficult than at lower pressures.

Harris, S.J. (General Motors Research Labs., Warren, MI (USA). Physics Dept.); Kennedy, I.M. (California Univ., Davis, CA (USA). Dept. of Mechanical Engineering)

1989-12-01T23:59:59.000Z

70

High pressure low heat rate phosphoric acid fuel cell stack  

SciTech Connect (OSTI)

A high pressure phosphoric acid fuel cell stack assembly is described comprising: (a) a stack of fuel cells for producing electricity, the stack including cathode means, anode means, and heat exchange means; (b) means for delivering pressurized air to the cathode means; (c) means for delivering a hydrogen rich fuel gas to the anode means for electrochemically reacting with oxygen in the pressurized air to produce electricity and water; (d) first conduit means connected to the cathode means for exhausting a mixture of oxygen-depleted air and reaction water from the cathode means; (e) second conduit means connected to the first conduit means for delivering a water fog to the first conduit means for entrainment in the mixture of oxygen-depleted air and reaction water to form a two phase coolant having a gaseous air phase and an entrained water droplet phase; (f) means for circulating the coolant to the heat exchange means to cool the stack solely through vaporization of the water droplet phase in the heat exchange means whereby a mixed gas exhaust of air and water vapor is exhausted from the heat exchange means; and (g) means for heating the mixed gas exhaust and delivering the heated mixed gas exhaust at reformer reaction temperatures to an autothermal reformer in the stack assembly for autothermal reaction with a raw fuel to form the hydrogen rich fuel.

Wertheim, R.J.

1987-07-07T23:59:59.000Z

71

Portable high precision pressure transducer system  

DOE Patents [OSTI]

A high precision pressure transducer system is described for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank. Since the response of the pressure transducer is temperature sensitive, it is continually housed in an battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum fluorescent display. 2 figures.

Piper, T.C.; Morgan, J.P.; Marchant, N.J.; Bolton, S.M.

1994-04-26T23:59:59.000Z

72

Portable high precision pressure transducer system  

DOE Patents [OSTI]

A high precision pressure transducer system for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank. Since the response of the pressure transducer is temperature sensitive, it is continually housed in an battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum florescent display.

Piper, Thomas C. (Idaho Falls, ID); Morgan, John P. (Idaho Falls, ID); Marchant, Norman J. (Idaho Falls, ID); Bolton, Steven M. (Pocatello, ID)

1994-01-01T23:59:59.000Z

73

High-pressure studies of ammonia hydrates   

E-Print Network [OSTI]

Ammonia and water are major components of many planetary bodies, from comets and icy moons such as Saturn's Titan to the interiors of the planets Neptune and Uranus. Under a range of high pressures and/or low temperatures known ...

Wilson, Craig W.

2014-06-28T23:59:59.000Z

74

High-pressure synthesis of electronic materials   

E-Print Network [OSTI]

High-pressure techniques have become increasingly important in the synthesis of ceramic and metallic solids allowing the discovery of new materials with interesting properties. In this research dense solid oxides have ...

Penny, George B. S.

2010-01-01T23:59:59.000Z

75

High Pressure Hydrogen Tank Manufacturing  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE and SUSTAINABLEIssues

76

On-line coating of glass with tin oxide by atmospheric pressure chemical vapor deposition.  

SciTech Connect (OSTI)

Atmospheric pressure chemical vapor deposition (APCVD) of tin oxide is a very important manufacturing technique used in the production of low-emissivity glass. It is also the primary method used to provide wear-resistant coatings on glass containers. The complexity of these systems, which involve chemical reactions in both the gas phase and on the deposition surface, as well as complex fluid dynamics, makes process optimization and design of new coating reactors a very difficult task. In 2001 the U.S. Dept. of Energy Industrial Technologies Program Glass Industry of the Future Team funded a project to address the need for more accurate data concerning the tin oxide APCVD process. This report presents a case study of on-line APCVD using organometallic precursors, which are the primary reactants used in industrial coating processes. Research staff at Sandia National Laboratories in Livermore, CA, and the PPG Industries Glass Technology Center in Pittsburgh, PA collaborated to produce this work. In this report, we describe a detailed investigation of the factors controlling the growth of tin oxide films. The report begins with a discussion of the basic elements of the deposition chemistry, including gas-phase thermochemistry of tin species and mechanisms of chemical reactions involved in the decomposition of tin precursors. These results provide the basis for experimental investigations in which tin oxide growth rates were measured as a function of all major process variables. The experiments focused on growth from monobutyltintrichloride (MBTC) since this is one of the two primary precursors used industrially. There are almost no reliable growth-rate data available for this precursor. Robust models describing the growth rate as a function of these variables are derived from modeling of these data. Finally, the results are used to conduct computational fluid dynamic simulations of both pilot- and full-scale coating reactors. As a result, general conclusions are reached concerning the factors affecting the growth rate in on-line APCVD reactors. In addition, a substantial body of data was generated that can be used to model many different industrial tin oxide coating processes. These data include the most extensive compilation of thermochemistry for gas-phase tin-containing species as well as kinetic expressions describing tin oxide growth rates over a wide range of temperatures, pressures, and reactant concentrations.

Allendorf, Mark D.; Sopko, J.F. (PPF Industries, Pittsburgh, PA); Houf, William G.; Chae, Yong Kee; McDaniel, Anthony H.; Li, M. (PPF Industries, Pittsburgh, PA); McCamy, J.W. (PPF Industries, Pittsburgh, PA)

2006-11-01T23:59:59.000Z

77

High pressure ceramic heat exchanger  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the reinforcing member and having a strengthening member wrapped around the refractory material. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

Harkins, Bruce D. (San Diego, CA); Ward, Michael E. (Poway, CA)

1999-01-01T23:59:59.000Z

78

High pressure ceramic heat exchanger  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a strengthening reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the strengthening reinforcing member. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

Harkins, Bruce D. (San Diego, CA); Ward, Michael E. (Poway, CA)

1998-01-01T23:59:59.000Z

79

High pressure ceramic heat exchanger  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a strengthening reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the strengthening reinforcing member. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures. 5 figs.

Harkins, B.D.; Ward, M.E.

1998-09-22T23:59:59.000Z

80

E-Print Network 3.0 - acid vapor pressures Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 22 3b. Thermodynamics of moist air Water phase, water latent heat of vaporization Lv Summary: 3b. Thermodynamics of moist air Water phase, water latent...

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Optimization of multi-pressure himidification-dehumidification desalination using thermal vapor compression and hybridization  

E-Print Network [OSTI]

Humidification-dehumidification (HD or HDH) desalination, and specifically HD driven by a thermal vapor compressor (TVC), is a thermal desalination method that has the potential to produce potable water efficiently in order ...

Mistry, Karan Hemant

82

A combined droplet train and ambient pressure photoemission spectrometer for the investigation of liquid/vapor interfaces  

SciTech Connect (OSTI)

We describe a combined ambient pressure photoelectron spectroscopy/droplet train apparatus for investigating the nature and heterogeneous chemistry of liquid/vapor interfaces. In this instrument a liquid droplet train with typical droplet diameters from 50...150 {micro}m is produced by a vibrating orifice aerosol generator (VOAG). The droplets are irradiated by soft X-rays (100...1500 eV) in front of the entrance aperture of a differentially pumped electrostatic lens system that transfers the emitted electrons into a conventional hemispherical electron analyzer. The photoemission experiments are performed at background pressures of up to several Torr, which allows the study of environmentally important liquid/vapor interfaces, in particular aqueous solutions, under equilibrium conditions. The exposure time of the droplet surface to the background gases prior to the XPS measurement can be varied, which will allow future kinetic measurements of gas uptake on liquid surfaces. As an example, a measurement of the surface composition of a {chi} = 0.21 aqueous methanol solution is presented. The concentration of methanol at the vapor/liquid interface is enhanced by a factor of about 3 over the bulk value, while the expected bulk value is recovered at depths larger than about 1.5 nm.

Starr, David E.; Wong, Ed K.; Worsnop, Douglas R.; Wilson, Kevin R.; Bluhm, Hendrik

2008-05-01T23:59:59.000Z

83

High pressure, high current, low inductance, high reliability sealed terminals  

DOE Patents [OSTI]

The invention is a terminal assembly having a casing with at least one delivery tapered-cone conductor and at least one return tapered-cone conductor routed there-through. The delivery and return tapered-cone conductors are electrically isolated from each other and positioned in the annuluses of ordered concentric cones at an off-normal angle. The tapered cone conductor service can be AC phase conductors and DC link conductors. The center core has at least one service conduit of gate signal leads, diagnostic signal wires, and refrigerant tubing routed there-through. A seal material is in direct contact with the casing inner surface, the tapered-cone conductors, and the service conduits thereby hermetically filling the interstitial space in the casing interior core and center core. The assembly provides simultaneous high-current, high-pressure, low-inductance, and high-reliability service.

Hsu, John S. (Oak Ridge, TN) [Oak Ridge, TN; McKeever, John W. (Oak Ridge, TN) [Oak Ridge, TN

2010-03-23T23:59:59.000Z

84

High pressure chemistry of substituted acetylenes  

SciTech Connect (OSTI)

High pressure in situ synchrotron x-ray diffraction experiments were performed on substituted polyacetylenes: tert-butyl acetylene [TBA: (CH{sub 3}){sub 3}-C{triple_bond}CH] and ethynyl trimethylsilane [ETMS: (CH{sub 3}){sub 3}-Si{triple_bond}CH] to investigate pressure-induced chemical reactions. The starting samples were the low temperature crystalline phases which persisted metastably at room temperature and polymerized beyond 11 GPa and 26 GPa for TBA and ETMS respectively. These reaction onset pressures are considerably higher than what we observed in the shockwave studies (6.1 GPa for TBA and 6.6 GPa for ETMS). Interestingly, in the case of ETMS, it was observed with fluid ETMS as starting sample, reacts to form a semi-crystalline polymer (crystalline domains corresponding to the low-T phase) at pressures less than {approx}2 GPa. Further characterization using vibrational spectroscopy is in progress.

Chellappa, Raja [Los Alamos National Laboratory; Dattelbaum, Dana [Los Alamos National Laboratory; Sheffield, Stephen [Los Alamos National Laboratory; Robbins, David [Los Alamos National Laboratory

2011-01-25T23:59:59.000Z

85

High pressure water jet mining machine  

DOE Patents [OSTI]

A high pressure water jet mining machine for the longwall mining of coal is described. The machine is generally in the shape of a plowshare and is advanced in the direction in which the coal is cut. The machine has mounted thereon a plurality of nozzle modules each containing a high pressure water jet nozzle disposed to oscillate in a particular plane. The nozzle modules are oriented to cut in vertical and horizontal planes on the leading edge of the machine and the coal so cut is cleaved off by the wedge-shaped body.

Barker, Clark R. (Rolla, MO)

1981-05-05T23:59:59.000Z

86

Consider Installing High-Pressure Boilers with BackpressureTurbine...  

Broader source: Energy.gov (indexed) [DOE]

High-Pressure Boilers with Backpressure Turbine-Generators Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators This tip sheet outlines the benefits of...

87

Automated High-Pressure Titration System with In Situ Infrared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Abstract: A...

88

Bonfire Tests of High Pressure Hydrogen Storage Tanks | Department...  

Broader source: Energy.gov (indexed) [DOE]

Bonfire Tests of High Pressure Hydrogen Storage Tanks Bonfire Tests of High Pressure Hydrogen Storage Tanks These slides were presented at the International Hydrogen Fuel and...

89

Bonfire Tests of High Pressure Hydrogen Storage Tanks  

Broader source: Energy.gov (indexed) [DOE]

Bonfire Tests of High Pressure Hydrogen Storage Tanks International Hydrogen Fuel and Pressure Vessel Forum 2010Beijing, P.R. China September 27, 2010 Bonfire Tests of High...

90

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

91

Advanced Diagnostics for High Pressure Spray Combustion.  

SciTech Connect (OSTI)

The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

2014-06-01T23:59:59.000Z

92

Optical pumping and spectroscopy of Cs vapor at high magnetic field  

SciTech Connect (OSTI)

We have measured changes in the ground-state populations of Cs vapor induced by optical pumping at high magnetic field. The 2.7-T field of our experiments is strong enough to decouple the nuclear and electronic spins, allowing us to independently measure each population. The spatial dependence of the Cs populations in small amounts of buffer gas obeys a simple coupled diffusion model and the relative populations reveal the details of relaxation within the vapor cell. Optical pumping can produce high nuclear polarization in the Cs vapor due to perturbations of the hyperfine interaction during collisions with buffer-gas particles and depending on the pumping transition, radiation trapping can strongly influence the electronic and nuclear polarizations in the vapor.

Olsen, B. A.; Patton, B.; Jau, Y.-Y.; Happer, W. [Joseph Henry Laboratory, Department of Physics, Princeton University, Princeton, New Jersey 08544 (United States)

2011-12-15T23:59:59.000Z

93

Dynamics of Low-Pressure and High-Pressure Fuel Cell Air Supply System1  

E-Print Network [OSTI]

comparing the low pressure system with the high- pressure system equipped with a high-speed compressor pressure of the FC that is defined as the pressure at which the reactant hydrogen and oxygen (air) are delivered to the FC stack flow fields. In the case of stored compressed hydrogen the pressure of the cathode

Peng, Huei

94

Viscosities of natural gases at high pressures and high temperatures  

E-Print Network [OSTI]

Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

Viswanathan, Anup

2007-09-17T23:59:59.000Z

95

Z .Thin Solid Films 392 2001 231 235 Atmospheric pressure chemical vapor deposition of  

E-Print Network [OSTI]

of electrochromic tungsten oxide films Roy G. Gordona,U , Sean Barryb , Jeffrey T. Bartona , Randy N.R. Broomhall oxide, WO , is a coloring layer commonly used in electrochromic windows and displays. Successful: Chemical vapor deposition; Tungsten; Oxides; Electrochromism 1. Introduction Tungsten oxide is a key

96

Polymerization of Formic Acid under High Pressure  

SciTech Connect (OSTI)

We report combined Raman, infrared (IR) and x-ray diffraction (XRD) measurements, along with ab initio calculations on formic acid under pressure up to 50 GPa. Contrary to the report of Allan and Clark (PRL 82, 3464 (1999)), we find an infinite chain low-temperature Pna2{sub 1} structure consisting of trans molecules to be a high-pressure phase at room temperature. Our data indicate the symmetrization and a partially covalent character of the intra-chain hydrogen bonds above approximately 20 GPa. Raman spectra and XRD patterns indicate a loss of the long-range order at pressures above 40 GPa with a large hysteresis at decompression. We attribute this behavior to a three-dimensional polymerization of formic acid.

Goncharov, A F; Manaa, M R; Zaug, J M; Fried, L E; Montgomery, W B

2004-08-23T23:59:59.000Z

97

Engine having a high pressure hydraulic system and low pressure lubricating system  

DOE Patents [OSTI]

An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2000-01-01T23:59:59.000Z

98

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect (OSTI)

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

99

High-pressure liquid chromatographic gradient mixer  

DOE Patents [OSTI]

A gradient mixer effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum band-broadening.

Daughton, C.G.; Sakaji, R.H.

1982-09-08T23:59:59.000Z

100

Pb nanowire formation on Al/lead zirconate titanate surfaces in high-pressure hydrogen  

SciTech Connect (OSTI)

Thin films of Al on lead zirconate titanate (PZT) annealed in high-pressure hydrogen at 100C exhibit surface Pb nanowire growth. Wire diameter is approximately 80 nm and length can exceed 100 microns. Based on microstructural analysis using electron microscopy and ion scattering, a vapor-solid scheme with hydrogen as a carrier gas was proposed as a growth mechanism. We expect that these observations may lead to controlled Pb nanowires growth through pattering of the Al film.

Alvine, Kyle J.; Shutthanandan, V.; Arey, Bruce W.; Wang, Chong M.; Bennett, Wendy D.; Pitman, Stan G.

2012-07-12T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Step-coverage simulation for tetraethoxysilane and ozone atmospheric pressure chemical vapor deposition  

SciTech Connect (OSTI)

A simulation model for atmospheric pressure (AP) CVD has bee developed using one-dimensional diffusion and mass conservation equations. The model was applied to trench step-coverage of the tetraethoxysilane (TEOS) and O[sub 3] CVD, in which it was not necessary to consider lateral diffusion because of narrow (and deep) trenches. For nondoped silicate glass (NSG), the step-coverage of a 4.5 aspect ratio trench showed a good fit if a sticking probability of 0.0039 was assumed for the 0.6% ozone (in oxygen) deposition and of 0.0026 for the 6% ozone deposition (both 400 C). The reaction rate constant was compared with the diffusion mass-transfer coefficient, and the reaction proved to be limited by diffusion of the reactant, TEOS, which directly participated in the CVD reaction. For the 2 m/o phosphosilicate glass (PSG) step-coverage, which had a slight overhang, the model matched the obtained results well only when an active growth species with a high sticking probability of 1.0 was added to the growth species of nondoped oxide. This analytical simulation method satisfactorily explains the experimental data.

Fujino, K. (Semiconductor Process Lab., Toyko (Japan)); Egashira, Y.; Shimogaki, Y.; Komiyama, H. (Univ. of Tokyo, (Japan). Dept. of Chemical Engineering)

1993-08-01T23:59:59.000Z

102

Use Vapor Recompression to Recover Low-Pressure Waste Steam (Revised0  

SciTech Connect (OSTI)

This revised ITP tip sheet on recovering low-pressure waste steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2008-03-01T23:59:59.000Z

103

High-rate chemical vapor deposition of nanocrystalline silicon carbide films by radio frequency thermal plasma  

E-Print Network [OSTI]

High-rate chemical vapor deposition of nanocrystalline silicon carbide films by radio frequency Semiconductor, Eden Prairie, MN, USA Received 10 July 2002; accepted 14 July 2002 Abstract Silicon carbide films; Nanomaterials; Silicon carbide; Thermal plasmas; Thin films; Si tetrachlorine precursor Silicon carbide has

Zachariah, Michael R.

104

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

105

High pressure-resistant nonincendive emulsion explosive  

DOE Patents [OSTI]

An improved emulsion explosive composition including hollow microspheres/bulking agents having high density and high strength. The hollow microspheres/bulking agents have true particle densities of about 0.2 grams per cubic centimeter or greater and include glass, siliceous, ceramic and synthetic resin microspheres, expanded minerals, and mixtures thereof. The preferred weight percentage of hollow microspheres/bulking agents in the composition ranges from 3.0 to 10.0 A chlorinated paraffin oil, also present in the improved emulsion explosive composition, imparts a higher film strength to the oil phase in the emulsion. The emulsion is rendered nonincendive by the production of sodium chloride in situ via the decomposition of sodium nitrate, a chlorinated paraffin oil, and sodium perchlorate. The air-gap sensitivity is improved by the in situ formation of monomethylamine perchlorate from dissolved monomethylamine nitrate and sodium perchlorate. The emulsion explosive composition can withstand static pressures to 139 bars and dynamic pressure loads on the order of 567 bars.

Ruhe, Thomas C. (Duquesne, PA); Rao, Pilaka P. (Baghlingampalli, IN)

1994-01-01T23:59:59.000Z

106

A University Consortium on Efficient and Clean High-Pressure...  

Broader source: Energy.gov (indexed) [DOE]

Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines A University Consortium on Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines 2010 DOE Vehicle Technologies and...

107

DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project...  

Broader source: Energy.gov (indexed) [DOE]

Delivery High-Pressure Tanks and Analysis Project Review Meeting DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project Review Meeting On February 8-9, 2005, the Department...

108

Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C21 to C30 at T ) 298.15 K by Correlation Gas Chromatography  

E-Print Network [OSTI]

by Correlation Gas Chromatography James S. Chickos* and William Hanshaw Department of Chemistry and Biochemistry. Sublimation enthalpies for n-C17 to n-C30 are calculated by combining vaporization enthalpies with fusion

Chickos, James S.

109

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

1992-12-01T23:59:59.000Z

110

FORMATION OF COSMIC CRYSTALS IN HIGHLY SUPERSATURATED SILICATE VAPOR PRODUCED BY PLANETESIMAL BOW SHOCKS  

SciTech Connect (OSTI)

Several lines of evidence suggest that fine silicate crystals observed in primitive meteorite and interplanetary dust particles (IDPs) nucleated in a supersaturated silicate vapor followed by crystalline growth. We investigated evaporation of {mu}m-sized silicate particles heated by a bow shock produced by a planetesimal orbiting in the gas in the early solar nebula and condensation of crystalline silicate from the vapor thus produced. Our numerical simulation of shock-wave heating showed that these {mu}m-sized particles evaporate almost completely when the bow shock is strong enough to cause melting of chondrule precursor dust particles. We found that the silicate vapor cools very rapidly with expansion into the ambient unshocked nebular region; for instance, the cooling rate is estimated to be as high as 2000 K s{sup -1} for a vapor heated by a bow shock associated with a planetesimal of radius 1 km. The rapid cooling of the vapor leads to nonequilibrium gas-phase condensation of dust at temperatures much lower than those expected from the equilibrium condensation. It was found that the condensation temperatures are lower by a few hundred K or more than the equilibrium temperatures. This explains the results of the recent experimental studies of condensation from a silicate vapor that condensation in such large supercooling reproduces morphologies similar to those of silicate crystals found in meteorites. Our results strongly suggest that the planetesimal bow shock is one of the plausible sites for formation of not only chondrules but also other cosmic crystals in the early solar system.

Miura, H.; Yamada, J.; Tsukamoto, K.; Nozawa, J. [Department of Earth Sciences, Tohoku University, Aoba 6-3, Aramaki, Aoba-ku, Sendai 980-8578 (Japan); Tanaka, K. K.; Yamamoto, T. [Institute of Low Temperature Science, Hokkaido University, Sapporo 060-0819 (Japan); Nakamoto, T., E-mail: miurah@m.tohoku.ac.j [Earth and Planetary Sciences, Tokyo Institute of Technology, Meguro, Tokyo 152-8551 (Japan)

2010-08-10T23:59:59.000Z

111

Reversible high-pressure carbon nanotube vessel  

E-Print Network [OSTI]

Applying a full pressure loop, i.e., loading and unloading, on a nanocrystal with in situ observation remains a challenge to experimentalists up until now. Using a multiwalled carbon nanotube, we realize the pressure loop ...

Wang, Lifeng

112

Effect of high pressure on structural oddities   

E-Print Network [OSTI]

This thesis describes the effect of pressure on crystal structures that are in some way unusual. The aim was to investigate whether pressure could be used to force these ‘structural oddities’ to conform to more conventional ...

Johnstone, Russell D. L.

2010-01-01T23:59:59.000Z

113

Condensed matter at high shock pressures  

SciTech Connect (OSTI)

Experimental techniques are described for shock waves in liquids: Hugoniot equation-of-state, shock temperature and emission spectroscopy, electrical conductivity, and Raman spectroscopy. Experimental data are reviewed and presented in terms of phenomena that occur at high densities and temperatures in shocked He, Ar, N/sub 2/, CO, SiO/sub 2/-aerogel, H/sub 2/O, and C/sub 6/H/sub 6/. The superconducting properties of Nb metal shocked to 100 GPa (1 Mbar) and recovered intact are discussed in terms of prospects for synthesizing novel, metastable materials. Ultrahigh pressure data for Cu is reviewed in the range 0.3 to 6TPa (3 to 60 Mbar). 56 refs., 9 figs., 1 tab.

Nellis, W.J.; Holmes, N.C.; Mitchell, A.C.; Radousky, H.B.; Hamilton, D.

1985-07-12T23:59:59.000Z

114

High pressure fiber optic sensor system  

DOE Patents [OSTI]

The present application provides a fiber optic sensor system. The fiber optic sensor system may include a small diameter bellows, a large diameter bellows, and a fiber optic pressure sensor attached to the small diameter bellows. Contraction of the large diameter bellows under an applied pressure may cause the small diameter bellows to expand such that the fiber optic pressure sensor may measure the applied pressure.

Guida, Renato; Xia, Hua; Lee, Boon K; Dekate, Sachin N

2013-11-26T23:59:59.000Z

115

accessing high pressure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

place, rem... Liva, Gianluigi; Chiani, Marco 2010-01-01 102 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

116

Organic vapor jet printing system  

DOE Patents [OSTI]

An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

Forrest, Stephen R

2012-10-23T23:59:59.000Z

117

Fundamentals of High Pressure Combustion Chapter in High Pressure Processes in Chemical Engineering, Edited by Maximillian Lackner,  

E-Print Network [OSTI]

[2]. Furthermore, gas turbine combustion pres- sures have been increasing at a near linear rateFundamentals of High Pressure Combustion Chapter in High Pressure Processes in Chemical Engineering of the following chapter is to present an overview of the fundamentals of combustion processes in high pressure

Miller, Richard S.

118

Calibrated vapor generator source  

DOE Patents [OSTI]

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

1995-09-26T23:59:59.000Z

119

Growth of Large-Area Aligned Molybdenum Nanowires by High Temperature Chemical Vapor Deposition: Synthesis, Growth Mechanism, and Device Application  

E-Print Network [OSTI]

, thermogravimetry, and differential scanning calorimetry analysis, as well as structure analysis by electron on the decomposition of MoO2 vapors through condensation of its vapor at high substrate temperatures. The aligned nanowires with H2 gas.6d-f However, the reduction process degrades the crystal- linity of the nanowires

Wang, Zhong L.

120

Automated high pressure cell for pressure jump x-ray diffraction  

SciTech Connect (OSTI)

A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

Brooks, Nicholas J.; Gauthe, Beatrice L. L. E.; Templer, Richard H.; Ces, Oscar; Seddon, John M. [Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Terrill, Nick J. [Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE (United Kingdom); Rogers, Sarah E. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom)

2010-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Particulate removal from high-temperature, high-pressure combustion gases  

SciTech Connect (OSTI)

The adoption by utilities of coal-fired pressurized fluidized-bed/combined cycle combustion systems for electric power generation depends to a large extent on the development of an efficient and economic cleanup system for the high-temperature, high-pressure combustion gases. For adequate turbine protection, these gases must be sufficiently cleaned to bring particulate erosion and alkali vapor corrosion to a level acceptable to gas turbine manufacturers. At the same time, the total particulate content of the flue gas must be reduced to the limit set by the Environmental Protection Agency. To accomplish particulate removal from a dust-laden gas stream, a number of separation devices have been developed. These include conventional and augmented cyclones; porous metal, fiber, fabric, and ceramic filters, as well as fixed, moving, and fluidized-bed granular filters; and electrostatic precipitators. Several other novel separation devices have been proposed and developed to different degrees such as: contactors using molten salt, metal, or glass, dry scrubbers, acoustic agglomerators, as well as cyclones and granular-bed filters with external electrostatic or magnetic fields. Some of these separation devices in various combinations have been tested in process development units or in hot gas simulators by ANL, CPC, CURL, C-W, Exxon, GE, Westinghouse, etc. The results are discussed and evaluated for PFBC applications.

Henry, R.F.; Saxena, S.C.; Podolski, W.F.

1983-10-01T23:59:59.000Z

122

Elasticity of Materials at High Pressure  

E-Print Network [OSTI]

implications for lower mantle mineralogy, Earth Planet. Sci.C.R. (1998), Lower mantle mineralogy and the geophysical,in Ultrahigh-Pressure Mineralogy: Physics and Chemistry of

Gleason, Arianna Elizabeth

2010-01-01T23:59:59.000Z

123

High-Pressure Tube Trailers and Tanks  

Broader source: Energy.gov (indexed) [DOE]

bending stress: continuous fiber vessels and vessels made of replicants Conformable tanks require internal stiffeners (ribs) to efficiently support the pressure and minimize...

124

Evidence of Tetragonal Nanodomains in the high pressure polymorph  

SciTech Connect (OSTI)

The pressure induced P4mm {yields} Pm{bar 3}m phase transition in BaTiO{sub 3} perovskite was investigated by x-ray total scattering. The evolution of the structure was analyzed by fitting pair distribution functions over a pressure range from ambient pressure up to 6.85(7) GPa. Evidence for the existence of tetragonal ferroelectric nanodomains at high pressure was found. The average size of the nanodomains in the high-pressure phase decreases with increasing pressure. Extrapolation of the domain size to pressures higher than studied experimentally suggests a disappearance of the ferroelectric domains at about 9.3(5) GPa and a cubic symmetry of BaTiO{sub 3} high-pressure phase.

Ehm, L.; Borkowski, L.A.; Parise J.B.; Ghose, S.; Chen, Z.

2010-12-17T23:59:59.000Z

125

HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS  

SciTech Connect (OSTI)

It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

Vinayak N. Kabadi

1999-02-20T23:59:59.000Z

126

Oxide vapor distribution from a high-frequency sweep e-beam system  

SciTech Connect (OSTI)

Oxide vapor distributions have been determined as a function of operating parameters of a high frequency sweep e-beam source combined with a programmable sweep controller. We will show which parameters are significant, the parameters that yield the broadest oxide deposition distribution, and the procedure used to arrive at these conclusions. A design-of-experimental strategy was used with five operating parameters: evaporation rate, sweep speed, sweep pattern (pre-programmed), phase speed (azimuthal rotation of the pattern), profile (dwell time as a function of radial position). A design was chosen that would show which of the parameters and parameter pairs have a statistically significant effect on the vapor distribution. Witness flats were placed symmetrically across a 25 inches diameter platen. The stationary platen was centered 24 inches above the e-gun crucible. An oxide material was evaporated under 27 different conditions. Thickness measurements were made with a stylus profilometer. The information will enable users of the high frequency e-gun systems to optimally locate the source in a vacuum system and understand which parameters have a major effect on the vapor distribution.

Chow, R.; Tassano, P.L.; Tsujimoto, N.

1995-03-01T23:59:59.000Z

127

Notes 11. High pressure floating ring seals  

E-Print Network [OSTI]

Floating ring seals for compressors: leakage and force coefficients, seal lock up and effect on rotor stability, recommendations to reduce seal cross-coupled effects. Long oil seals as pressure barriers in industrial mixers: leakage and force...

San Andres, Luis

2009-01-01T23:59:59.000Z

128

High-pressure Magic Angle Spinning Nuclear Magnetic Resonance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

advantage of ceramic cylinders for withstanding very high-pressure utilized, but also plastic bushings can be glued tightly in place so that other plastic sealing mechanisms...

129

Energy Systems High Pressure Test Laboratory (Fact Sheet), NREL...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

National laboratories Contact Us If you are interested in working with NREL's Energy Systems High Pressure Test Laboratory, please contact: ESIF Manager Carolyn Elam...

130

High-pressure Infrared Spectra of Tal and Lawsonite  

SciTech Connect (OSTI)

We present high-pressure infrared spectra of two geologically important hydrous minerals: talc, Mg3Si4O10(OH)2 and lawsonite, CaAl2Si2O7(OH)2{center_dot}H2O,{center_dot}at room temperature. For lawsonite, our data span the far infrared region from 150 to 550 cm-1 and extend to 25 GPa. We combine our new spectroscopic data with previously published high-pressure mid-infrared and Raman data to constrain the Gr{umlt u}neisen parameter and vibrational density of states under pressure. In the case of talc, we present high-pressure infrared data that span both the mid and far infrared from 150 to 3800 cm-1 covering lattice, silicate, and hydroxyl stretching vibrations to a maximum pressure of 30 GPa. Both phases show remarkable metastability well beyond their nominal maximum thermodynamic stability at simultaneous high-pressure and high-temperature conditions.

Scott,H.; Liu, Z.; Hemley, R.; Williams, Q.

2007-01-01T23:59:59.000Z

131

Compatibility tests of low-vapor pressure perfluoropolyether oils with UF/sub 6/  

SciTech Connect (OSTI)

An extensive study has been carried out to evaluate possible use of the perfluoropolyether fluids, obtained from hexafluoropropylene photo-oxidation and specially purified and selected, as lubricants or vacuum-working fluids, in the presence of UF/sub 6/. Some physiochemical properties are reported and the results of the tests experienced on perfluoropolyether cuts put into contact with UF/sub 6/ at different conditions for a long aging time at high temperature in the presence of some typical engineering materials. The results allowed a verification of the long-term compatibility of the perfluoropolyether special fractions against UF/sub 6/ at temperatures up to 130/sup 0/C.

Ciancia, A.; Ascensioni, A.; Caporiccio, G.; Corti, C.

1984-02-01T23:59:59.000Z

132

Variation in rectal temperature, respiratory rate, and pulse rate of cattle as related to variations in solar radiation, air temperature, wind velocity, and vapor pressure  

E-Print Network [OSTI]

VARIATION IN RECTAL TEMPERATURE, RESPIRATORY RATE, AND PULSE RATE GF CATTLE AS RELATED TO VARIATIONS IN SOLAR RADIATION, AIR TEMPERATURE, WIND VELOCITY, AND VAPOR PRESSURE A Dissertation By Mohammad Fazlur Rahim Quazi Approved as to style... Dissertation By Mohammad Fazlur Rahim tyiazi Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY May 1955 Major Subject: Genetics ? ?4...

Quazi, Mohammad Fazlur Rahim

1955-01-01T23:59:59.000Z

133

The Effects of Water Vapor and Hydrogen on the High-Temperature Oxidation of Alloys  

SciTech Connect (OSTI)

Essentially all alloys and coatings that are resistant to corrosion at high temperature require the formation of a protective (slowly-growing and adherent) oxide layer by a process known as selective oxidation. The fundamental understanding of this process has been developed over the years for exposure in pure oxygen or air. However, the atmospheres in most applications contain significant amounts of water vapor which can greatly modify the behavior of protective oxides. The development of oxy-fuel combustion systems in which fossil fuels are burned in a mixture of recirculated flue gas and oxygen, rather than in air, has caused renewed interest in the effects of water vapor and steam on alloy oxidation. The focus of this paper is on the ways the presence of water vapor can directly alter the selective oxidation process. The paper begins with a brief review of the fundamentals of selective oxidation followed by a description of recent experimental results regarding the effect of water vapor on the oxidation of a variety of chromia-forming alloys (Fe- and Ni-base) in the temperature range 600 to 700 °C. The atmospheres include air, air-H{sub 2}O, Ar-H{sub 2}O and Ar-H{sub 2}O-O{sub 2}. Then the behavior of alumina-forming alloys in H{sub 2}O-containing atmospheres is briefly described. As hydrogen is produced during oxidation of alloys in H{sub 2}O, it can be released back into the gas phase or injected into the metal (where it can diffuse through to the other side). Experiments in which hydrogen concentrations have been measured on both sides of thin specimens during oxidation by H{sub 2}O on only one side are described. Finally, it is attempted to catalogue the various experimental observations under a few general principles.

Mu, N.; Jung, K.; Yanar, N. M.; Pettit, F. S; Holcomb, G. R.; Howard, B. H.; Meier, G. H.

2013-06-01T23:59:59.000Z

134

“Multi-temperature” method for high-pressure sorption measurements on moist shales  

SciTech Connect (OSTI)

A simple and effective experimental approach has been developed and tested to study the temperature dependence of high-pressure methane sorption in moist organic-rich shales. This method, denoted as “multi-temperature” (short “multi-T”) method, enables measuring multiple isotherms at varying temperatures in a single run. The measurement of individual sorption isotherms at different temperatures takes place in a closed system ensuring that the moisture content remains constant. The multi-T method was successfully tested for methane sorption on an organic-rich shale sample. Excess sorption isotherms for methane were measured at pressures of up to 25 MPa and at temperatures of 318.1 K, 338.1 K, and 348.1 K on dry and moisture-equilibrated samples. The measured isotherms were parameterized with a 3-parameter Langmuir-based excess sorption function, from which thermodynamic sorption parameters (enthalpy and entropy of adsorption) were obtained. Using these, we show that by taking explicitly into account water vapor as molecular species in the gas phase with temperature-dependent water vapor pressure during the experiment, more meaningful results are obtained with respect to thermodynamical considerations. The proposed method can be applied to any adsorbent system (coals, shales, industrial adsorbents) and any supercritical gas (e.g., CH{sub 4}, CO{sub 2}) and is particularly suitable for sorption measurements using the manometric (volumetric) method.

Gasparik, Matus; Ghanizadeh, Amin; Gensterblum, Yves; Krooss, Bernhard M. [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)] [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)

2013-08-15T23:59:59.000Z

135

Method for controlling corrosion in thermal vapor injection gases  

DOE Patents [OSTI]

An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

1981-01-01T23:59:59.000Z

136

High pressure discharges in cavities formed by microfabrication techniques  

SciTech Connect (OSTI)

High pressure discharges are the basis of small high intensity light sources. In this work, we demonstrate the formation of high pressure discharges, in cavities formed by applying micromachining and integrated circuit techniques to quartz substrates. Cavities containing varying amounts of mercury and argon were fabricated to obtain high pressure discharges. A high pressure mercury discharge was formed in the electrodeless cavities by exciting them with a microwave source, operating at 2.45 GHz and in the electroded cavities by applying a dc voltage. The contraction of the discharge into a high pressure arc was observed. A broad emission spectrum due to self-absorption and collisions between excited atoms and normal atoms, typical of high pressure mercury discharges, was measured. The light output and efficacy increased with increasing pressure. The measured voltage was used to estimate the pressure within the electroded cavities, which is as high as 127 atm for one of the two cavities discussed in this work. Efficacies over 40 lumens per watt were obtained for the electrodeless cavities and over 50 scr(l)m/W for the electroded cavities. {copyright} {ital 1997 American Institute of Physics.}

Khan, B.A.; Cammack, D.A.; Pinker, R.D.; Racz, J. [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)] [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)

1997-07-01T23:59:59.000Z

137

Hydrous silicate melt at high pressure Mainak Mookherjee1  

E-Print Network [OSTI]

LETTERS Hydrous silicate melt at high pressure Mainak Mookherjee1 , Lars Stixrude2 & Bijaya Karki3 The structure and physical properties of hydrous silicate melts and the solubility of water in melts over most in structure to our finding that the water­silicate system becomes increasingly ideal at high pressure: we find

Stixrude, Lars

138

accompanying high-pressure phase: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pressure cryocooling Abstract High-pressure methods for solving Gruner, Sol M. 58 High-pressure studies of ammonia hydrates Edinburgh, University of - Research Archive Summary:...

139

The Effect of High Temperature Annealing on the Grain Characteristics of a Thin Chemical Vapor Deposition Silicon Carbide Layer.  

SciTech Connect (OSTI)

The unique combination of thermo-mechanical and physiochemical properties of silicon carbide (SiC) provides interest and opportunity for its use in nuclear applications. One of the applications of SiC is as a very thin layer in the TRi-ISOtropic (TRISO) coated fuel particles for high temperature gas reactors (HTGRs). This SiC layer, produced by chemical vapor deposition (CVD), is designed to withstand the pressures of fission and transmutation product gases in a high temperature, radiation environment. Various researchers have demonstrated that macroscopic properties can be affected by changes in the distribution of grain boundary plane orientations and misorientations [1 - 3]. Additionally, various researchers have attributed the release behavior of Ag through the SiC layer as a grain boundary diffusion phenomenon [4 - 6]; further highlighting the importance of understanding the actual grain characteristics of the SiC layer. Both historic HTGR fission product release studies and recent experiments at Idaho National Laboratory (INL) [7] have shown that the release of Ag-110m is strongly temperature dependent. Although the maximum normal operating fuel temperature of a HTGR design is in the range of 1000-1250°C, the temperature may reach 1600°C under postulated accident conditions. The aim of this specific study is therefore to determine the magnitude of temperature dependence on SiC grain characteristics, expanding upon initial studies by Van Rooyen et al, [8; 9].

Isabella J van Rooyen; Philippus M van Rooyen; Mary Lou Dunzik-Gougar

2013-08-01T23:59:59.000Z

140

Neutron scattering at high pressure D. B. McWhan  

E-Print Network [OSTI]

715 Neutron scattering at high pressure D. B. McWhan Room 1D-234, Murray Hill, New Jersey 07974, U scattering at steady-state and pulsed sources are reviewed. The pressure cells available at most neutron 10 GPa have been made. For elastic scattering, a comparison is made between neutron scattering and X

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Chemistry of nitromethane at very high pressure  

SciTech Connect (OSTI)

Decomposition of nitromethane is reported over the range of 115- 180/degree/C and 0.6-8.5 GPa. About 5 /mu/g of nitromethane is compressed with a diamond-anvil cell, heated to the point that reaction occurs, and held typically 10-20 minutes at the reaction temperature. The cell is cooled and the volatile contents of the cell are frozen as a thin layer in vacuo and an infrared absorption spectrum is recorded. The three volatile products observed are N/sub 2/O, CO/sub 2/, and water, with N/sub 2/O production peaking at 1.5 GPa, 135/degree/C, and 35% of NME; CO/sub 2/ production peaking at 3.5 GPa, 135/degree/C, and 65% of NME, and water yields at 20-50% of NME at the highest pressure measured, 8.5 GPa and 175/degree/C. Water yields were difficult to quantify due to background contamination. Results indicate three different reactions for solid NME dependent primarily on the pressure of the reaction, and that fluid NME does not decompose at 0.6 GPa and 175/degree/C, although the solid decomposes readily at 1.1 GPa and 120/degree/C. The authors conclude that, while various decomposition mechanisms are possible, the initial step CH/sub 3/NO/sub 2/ /yields/ /center dot/CH/sub 3/ + /center dot/NO/sub 2/ is very unlikely. 14 refs., 5 figs.

Agnew, S.F.; Swanson, B.I.; Kenney, J.; Kenney, I.

1989-01-01T23:59:59.000Z

142

Digital pressure transducer for use at high temperatures  

DOE Patents [OSTI]

A digital pressure sensor for measuring fluid pressures at relatively high temperatures includes an electrically conducting fiber coupled to the fluid by a force disc that causes tension in the fiber to be a function of fluid pressure. The tension causes changes in the mechanical resonant frequency of the fiber, which is caused to vibrate in a magnetic field to produce an electrical signal from a positive-feedback amplifier at the resonant frequency. A count of this frequency provides a measure of the fluid pressure.

Karplus, Henry H. B. (Hinsdale, IL)

1981-01-01T23:59:59.000Z

143

High pressure water jet cutting of sugar cane  

E-Print Network [OSTI]

performance was uniform before cutting. A liquid filled bourdon tube gauge was used to deter- mine the prescribed operating pressures. The gauge measured the oil pressure of the intensifier which had a 20 to 1 ratio (Figure 4 ) ~ The gauge pressure...HIGH PRESSURE WATER JET CUTTING OF SUGAR CANE A Thesis by THOMAS DONALD VALCO Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1977 Major Subject...

Valco, Thomas Donald

2012-06-07T23:59:59.000Z

144

Energy Systems High Pressure Test Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Energy Systems High Pressure Test Laboratory at the Energy Systems Integration Facility. The purpose of the Energy Systems High Pressure Test Laboratory at NREL's Energy Systems Integration Facility (ESIF) is to provide space where high pressure hydrogen components can be safely tested. High pressure hydrogen storage is an integral part of energy storage technology for use in fuel cell and in other distributed energy scenarios designed to effectively utilize the variability inherent with renewable energy sources. The high pressure storage laboratory is co-located with energy storage activities such as ultra-capacitors, super conducting magnetic flywheel and mechanical energy storage systems laboratories for an integrated approach to system development and demonstration. Hazards associated with hydrogen storage at pressures up to 10,000 psi include oxygen displacement, combustion, explosion, and pressurization of room air due to fast release and physical hazards associated with burst failure modes. A critical understanding of component failure modes is essential in developing reliable, robust designs that will minimize failure risk beyond the end of service life. Development of test protocol for accelerated life testing to accurately scale to real world operating conditions is essential for developing regulations, codes and standards required for safe operation. NREL works closely with industry partners in providing support of advanced hydrogen technologies. Innovative approaches to product design will accelerate commercialization into new markets. NREL works with all phases of the product design life cycle from early prototype development to final certification testing. High pressure tests are performed on hydrogen components, primarily for the validation of developing new codes and standards for high pressure hydrogen applications. The following types of tests can be performed: Performance, Component and system level efficiency, Strength of materials and hydrogen compatibility, Safety demonstration, Model validation, and Life cycle reliability.

Not Available

2011-10-01T23:59:59.000Z

145

Performance Assessment of Pressurized Stairs in High Rise Buildings   

E-Print Network [OSTI]

Pressurized stair cases are an important part of the fire safety strategy of high rise buildings. Long egress times are compensated by creating safe environments within egress staircases allowing the displacement time ...

Bellido, Carlos; Quiroz, Antonio; Panizo, Alfonso; Torero, Jose L

2008-12-17T23:59:59.000Z

146

Design of a continuous fiber ceramic composite heat exchanger for high-temperature, high-pressure applications  

SciTech Connect (OSTI)

A conceptual design of a continuous fiber ceramic composite (CFCC) heat exchanger for high-temperature, high-pressure applications is presented. The CFCC materials under consideration are SiC reinforced with SiC fibers manufactured using the continuous vapor infiltration process and alumina reinforced with SiC or alumina fibers manufactured using the directed metal oxidation process. These composite materials are highly resistant to high-temperature corrosive environment and possess a greater creep strength than metallic materials. Heat exchangers constructed of CFCC material may be utilized for high-temperature, high-pressure applications such as air/gas heaters in advanced energy systems and high-temperature energy recovery systems. This paper presents a design of a gas-to-air CFCC heat exchanger for the high temperature advanced furnace (HITAF) in the high-performance power system (HIPPS). The 1.38 MPa (200 psia) air is heated from 760 C (1,400 F) to 982 C (1,800 F) using the combustion products at 1,650 C (3,000 F). The heat exchanger is of a cross-parallel/counter flow type in which the tube-side air flow makes a combined parallel and counter flow arrangement with a cross-flowing combustion gas in such a way that the maximum CFCC tube temperature will not exceed a 1,260 C (2,300 F) design limit. The main heat transfer mechanism from the external hot gas to the tube-side air is that of gaseous radiation for the first few rows of the tubes, followed by convective heat transfer across the remainder of the tube bundle. The design characteristics of this high-temperature, high-pressure CFCC heat exchanger with supporting thermal, flow, structural, and vibrational analyses are presented in detail in the paper.

Cho, S.M.; Seltzer, A.H.; Narayanan, T.V. [Foster Wheeler Development Corp., Livingston, NJ (United States); Shah, A.C.; Weddell, J.K. [DuPont Lanxide Composites Inc., Newark, DE (United States)

1996-12-31T23:59:59.000Z

147

Low Cost, High Efficiency, High Pressure Hydrogen Storage  

SciTech Connect (OSTI)

A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high strength required as well as low weight. For the 10,000 psi tanks, carbon fiber is the largest portion of their cost. Quantum Technologies is a tier one hydrogen system supplier for automotive companies around the world. Over the course of the program Quantum focused on development of technology to allow the compressed hydrogen storage tank to meet DOE goals. At the start of the program in 2004 Quantum was supplying systems with a specific energy of 1.1-1.6 kWh/kg, a volumetric capacity of 1.3 kWh/L and a cost of $73/kWh. Based on the inequities between DOE targets and Quantum’s then current capabilities, focus was placed first on cost reduction and second on weight reduction. Both of these were to be accomplished without reduction of the fuel system’s performance or reliability. Three distinct areas were investigated; optimization of composite structures, development of “smart tanks” that could monitor health of tank thus allowing for lower design safety factor, and the development of “Cool Fuel” technology to allow higher density gas to be stored, thus allowing smaller/lower pressure tanks that would hold the required fuel supply. The second phase of the project deals with three additional distinct tasks focusing on composite structure optimization, liner optimization, and metal.

Mark Leavitt

2010-03-31T23:59:59.000Z

148

Poisson's Ratio and the Densification of Glass under High Pressure  

SciTech Connect (OSTI)

Because of a relatively low atomic packing density, (C{sub g}) glasses experience significant densification under high hydrostatic pressure. Poisson's ratio ({nu}) is correlated to C{sub g} and typically varies from 0.15 for glasses with low C{sub g} such as amorphous silica to 0.38 for close-packed atomic networks such as in bulk metallic glasses. Pressure experiments were conducted up to 25 GPa at 293 K on silica, soda-lime-silica, chalcogenide, and bulk metallic glasses. We show from these high-pressure data that there is a direct correlation between {nu} and the maximum post-decompression density change.

Rouxel, T.; Ji, H. [Applied Mechanics Laboratory of the University of Rennes 1, LARMAUR, Universite de Rennes 1, Campus de Beaulieu, 35042 Rennes cedex (France); Hammouda, T. [Laboratoire Magmas et Volcans, CNRS-OPG , Universite Blaise Pascal, 5 rue Kessler, 63038 Clermont-Ferrand cedex (France); Moreac, A. [IPR, CNRS-Universite de Rennes 1, Campus de Beaulieu, 35042 Rennes cedex (France)

2008-06-06T23:59:59.000Z

149

Experimental Analysis of Water Based Drilling Fluid Aging Processes at High Temperature and High Pressure Conditions  

E-Print Network [OSTI]

! ! EXPERIMENTAL ANALYSIS OF WATER BASED DRILLING FLUID AGING PROCESSES AT HIGH TEMPERATURE AND HIGH PRESSURE CONDITIONS A Thesis by BRANDON SCOTT ZIGMOND Submitted to the Office of Graduate Studies of Texas A&M University... Temperature and High Pressure Conditions Copyright 2012 Brandon Scott Zigmond ! ! EXPERIMENTAL ANALYSIS OF WATER BASED DRILLING FLUID AGING PROCESSES AT HIGH TEMPERATURE AND HIGH PRESSURE CONDITIONS A Thesis by BRANDON SCOTT ZIGMOND Submitted...

Zigmond, Brandon

2012-10-19T23:59:59.000Z

150

Confinement of hydrogen at high pressure in carbon nanotubes  

DOE Patents [OSTI]

A high pressure hydrogen confinement apparatus according to one embodiment includes carbon nanotubes capped at one or both ends thereof with a hydrogen-permeable membrane to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough. A hydrogen confinement apparatus according to another embodiment includes an array of multi-walled carbon nanotubes each having first and second ends, the second ends being capped with palladium (Pd) to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough as a function of palladium temperature, wherein the array of carbon nanotubes is capable of storing hydrogen gas at a pressure of at least 1 GPa for greater than 24 hours. Additional apparatuses and methods are also presented.

Lassila, David H. (Aptos, CA); Bonner, Brian P. (Livermore, CA)

2011-12-13T23:59:59.000Z

151

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

152

Vapor-transport growth of high optical quality WSe{sub 2} monolayers  

SciTech Connect (OSTI)

Monolayer transition metal dichalcogenides are atomically thin direct-gap semiconductors that show a variety of novel electronic and optical properties with an optically accessible valley degree of freedom. While they are ideal materials for developing optical-driven valleytronics, the restrictions of exfoliated samples have limited exploration of their potential. Here, we present a physical vapor transport growth method for triangular WSe{sub 2} sheets of up to 30 ?m in edge length on insulating SiO{sub 2} substrates. Characterization using atomic force microscopy and optical microscopy reveals that they are uniform, monolayer crystals. Low temperature photoluminescence shows well resolved and electrically tunable excitonic features similar to those in exfoliated samples, with substantial valley polarization and valley coherence. The monolayers grown using this method are therefore of high enough optical quality for routine use in the investigation of optoelectronics and valleytronics.

Clark, Genevieve [Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Wu, Sanfeng; Rivera, Pasqual; Finney, Joseph; Nguyen, Paul; Cobden, David H. [Department of Physics, University of Washington, Seattle, Washington 98195 (United States); Xu, Xiaodong, E-mail: xuxd@uw.edu [Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Department of Physics, University of Washington, Seattle, Washington 98195 (United States)

2014-10-01T23:59:59.000Z

153

Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology  

SciTech Connect (OSTI)

Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

2013-11-01T23:59:59.000Z

154

High-Pressure Flame Speed Measurements  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame and Droplet

155

A diamond-window XAFS cell for studies of high-temperature, high-pressure aqueous solutions  

SciTech Connect (OSTI)

We describe a method to collect x-ray absorption fine structure (XAFS) spectra of ions in a supercritical water solvent. Supercritical water (SCW), at temperatures above water{close_quote}s critical point of 374{degree}C, is an interesting solvent for chemical reactions and hazardous waste destruction due to the high solubility of organics and the aggressive oxidizing environment. XAFS may provide a better understanding of the solvent environment in SCW. The XAFS cell used in these studies was composed of a block of high-nickel alloy, Hastelloy C-22, containing two windows for transmission of the x-ray beam and a single optical view window. All internal wetted surfaces were platinum plated. The maximum operating conditions for this design were 500{degree}C and 700 bar. The x-ray transmission windows consisted of CVD (chemical vapor deposition) diamond windows (3 mm diameter {times}0.5 mm thick) that were brazed to the tip of a standard 1/4-in. high-pressure, coned-shape fitting. Spectra are reported for strontium and rubidium ions in a supercritical water solvent. This cell design could be used for a variety of other solvent systems at high temperatures and high pressures. {copyright} {ital 1996 American Institute of Physics.}

Fulton, J.L.; Pfund, D.M. [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States)] [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States); Ma, Y. [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)] [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)

1996-09-01T23:59:59.000Z

156

Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear  

DOE Patents [OSTI]

Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

1997-01-14T23:59:59.000Z

157

Department of Energy Workshop High Pressure Hydrogen Tank Manufacturing  

E-Print Network [OSTI]

Department of Energy Workshop High Pressure Hydrogen Tank Manufacturing Mark Leavitt Quantum Fuel for integrated module including in-tank regulator · Developed high efficiency H2 fuel storage systems for DOE tank efficiency, the highest weight efficiency ever demonstrated, in partnership with Lawrence

158

Numerical Model Investigation for Potential Methane Explosion and Benzene Vapor Intrusion Associated with High-Ethanol Blend  

E-Print Network [OSTI]

Associated with High-Ethanol Blend Releases Jie Ma, Hong Luo, George E. DeVaull,§ William G. Rixey, and Pedro ABSTRACT: Ethanol-blended fuel releases usually stimulate methanogenesis in the subsurface, which could conditions exist. Ethanol- derived methane may also increase the vapor intrusion potential of toxic fuel

Alvarez, Pedro J.

159

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

160

Ultra-high pressure water jet: Baseline report  

SciTech Connect (OSTI)

The ultra-high pressure waterjet technology was being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The ultra-high pressure waterjet technology acts as a cutting tool for the removal of surface substrates. The Husky{trademark} pump feeds water to a lance that directs the high pressure water at the surface to be removed. The safety and health evaluation during the testing demonstration focused on two main areas of exposure. These were dust and noise. The dust exposure was found to be minimal, which would be expected due to the wet environment inherent in the technology, but noise exposure was at a significant level. Further testing for noise is recommended because of the outdoor environment where the testing demonstration took place. In addition, other areas of concern found were arm-hand vibration, ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, fall hazards, slipping hazards, hazards associated with the high pressure water, and hazards associated with air pressure systems.

NONE

1997-07-31T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

A combined droplet train and ambient pressure photoemission spectrometer for the investigation of liquid/vapor interfaces  

E-Print Network [OSTI]

A combined droplet train and ambient pressure photoemissionspectroscopy/droplet train apparatus for investigating thethis instrument a liquid droplet train with typical droplet

Starr, David E.

2008-01-01T23:59:59.000Z

162

An experimental investigation of high temperature, high pressure paper drying  

E-Print Network [OSTI]

CONCLUSIONS RECOMMENDATIONS 50 51 REFERENCES APPENDIX A EXPERIMENTAL DATA 52 54 VITA 105 vail LIST OF FIGURES Page Fig. 1 Schematic of test facility 13 Fig. 2 Comparison of Texas A&M drying facility operating ranges to other drying processes... of number of drying passes for drying temperatures of 93, 149, and 204 'C (200, 300, and 400 'F), a contact pressure of 1. 4 MPa (200 psi), a basis weight of 25 g/m' (0. 005 lb/ft'), and contact times between 20 to 180 msec with same side drying...

Patel, Kamal Raoji

2012-06-07T23:59:59.000Z

163

Microhole High-Pressure Jet Drill for Coiled Tubing  

SciTech Connect (OSTI)

Tempress Small Mechanically-Assisted High-Pressure Waterjet Drilling Tool project centered on the development of a downhole intensifier (DHI) to boost the hydraulic pressure available from conventional coiled tubing to the level required for high-pressure jet erosion of rock. We reviewed two techniques for implementing this technology (1) pure high-pressure jet drilling and (2) mechanically-assisted jet drilling. Due to the difficulties associated with modifying a downhole motor for mechanically-assisted jet drilling, it was determined that the pure high-pressure jet drilling tool was the best candidate for development and commercialization. It was also determined that this tool needs to run on commingled nitrogen and water to provide adequate downhole differential pressure and to facilitate controlled pressure drilling and descaling applications in low pressure wells. The resulting Microhole jet drilling bottomhole assembly (BHA) drills a 3.625-inch diameter hole with 2-inch coil tubing. The BHA consists of a self-rotating multi-nozzle drilling head, a high-pressure rotary seal/bearing section, an intensifier and a gas separator. Commingled nitrogen and water are separated into two streams in the gas separator. The water stream is pressurized to 3 times the inlet pressure by the downhole intensifier and discharged through nozzles in the drilling head. The energy in the gas-rich stream is used to power the intensifier. Gas-rich exhaust from the intensifier is conducted to the nozzle head where it is used to shroud the jets, increasing their effective range. The prototype BHA was tested at operational pressures and flows in a test chamber and on the end of conventional coiled tubing in a test well. During instrumented runs at downhole conditions, the BHA developed downhole differential pressures of 74 MPa (11,000 psi, median) and 90 MPa (13,000 psi, peaks). The median output differential pressure was nearly 3 times the input differential pressure available from the coiled tubing. In a chamber test, the BHA delivered up to 50 kW (67 hhp) hydraulic power. The tool drilled uncertified class-G cement samples cast into casing at a rate of 0.04 to 0.17 m/min (8 to 33 ft/hr), within the range projected for this tool but slower than a conventional PDM. While the tool met most of the performance goals, reliability requires further improvement. It will be difficult for this tool, as currently configured, to compete with conventional positive displacement downhole motors for most coil tubing drill applications. Mechanical cutters on the rotating nozzle head would improve cutting. This tool can be easily adapted for well descaling operations. A variant of the Microhole jet drilling gas separator was further developed for use with positive displacement downhole motors (PDM) operating on commingled nitrogen and water. A fit-for-purpose motor gas separator was designed and yard tested within the Microhole program. Four commercial units of that design are currently involved in a 10-well field demonstration with Baker Oil Tools in Wyoming. Initial results indicate that the motor gas separators provide significant benefit.

Ken Theimer; Jack Kolle

2007-06-30T23:59:59.000Z

164

Large volume high-pressure cell with supported moissanite anvils  

SciTech Connect (OSTI)

The recently developed moissanite anvil cell (MAC) has become a useful device for achieving both high-pressure and large sample volume in an anvil cell. We describe two improvements in the basic design of the MAC. First, the loading environment has been optimized by centering the load. Second, a variety of supported systems have been examined to provide anvil stability at high loads with large anvils. Sample volumes that are nearly three orders magnitude greater than allowed by conventional diamond anvil cells can be pressurized and characterized at {approx}50 GPa.

Xu, J.; Mao, H.-k.; Hemley, R.J.; Hines , E. (CIW/GL)

2010-11-16T23:59:59.000Z

165

High Pressure Hydrogen Materials Compatibility of Piezoelectric Films  

SciTech Connect (OSTI)

Abstract: Hydrogen is being considered as a next-generation clean burning fuel. However, hydrogen has well known materials issues, including blistering and embrittlement in metals. Piezoelectric materials are used as actuators in hydrogen fuel technology. We present studies of materials compatibility of piezoelectric films in a high pressure hydrogen environment. Absorption of high pressure hydrogen was studied with Elastic Recoil Detection Analysis (ERDA) and Rutherford Back Scattering (RBS) in lead zirconate titanate (PZT) and barium titanate (BTO) thin films. Hydrogen surface degradation in the form of blistering and Pb mixing was also observed.

Alvine, Kyle J.; Shutthanandan, V.; Bennett, Wendy D.; Bonham, Charles C.; Skorski, Daniel C.; Pitman, Stan G.; Dahl, Michael E.; Henager, Charles H.

2010-12-02T23:59:59.000Z

166

Capillary toroid cavity detector for high pressure NMR  

DOE Patents [OSTI]

A Toroid Cavity Detector (TCD) is provided for implementing nuclear magnetic resonance (NMR) studies of chemical reactions under conditions of high pressures and temperatures. A toroid cavity contains an elongated central conductor extending within the toroid cavity. The toroid cavity and central conductor generate an RF magnetic field for NMR analysis. A flow-through capillary sample container is located within the toroid cavity adjacent to the central conductor to subject a sample material flowing through the capillary to a static magnetic field and to enable NMR spectra to be recorded of the material in the capillary under a temperature and high pressure environment.

Gerald, II, Rex E. (Brookfield, IL); Chen, Michael J. (Downers Grove, IL); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Honer Glen, IL); ter Horst, Marc (Chapel Hill, NC)

2007-09-11T23:59:59.000Z

167

Ultra-high pressure water jet: Baseline report; Summary  

SciTech Connect (OSTI)

The Husky{trademark} is an ultra high pressure waterjet cutting tool system. The pump is mounted on a steel tube frame which includes slots for transport by a forklift. The Husky{trademark} features an automatic shutdown for several conditions such as low oil pressure and high oil temperature. Placement of the Husky{trademark} must allow for a three foot clearance on all sides for operation and service access. At maximum continuous operation, the output volume is 7.2 gallons per minute with an output pressure of 40,000 psi. A diesel engine provides power for the system. The safety and health evaluation during the human factors assessment focused on two main areas: noise and dust.

NONE

1997-07-31T23:59:59.000Z

168

Guest disorder and high pressure behavior of argon hydrates  

SciTech Connect (OSTI)

The structure of argon hydrate was studied at ambient pressure and low temperature, and between 1.7 and 4.2 GPa at 295 K. This analysis produced a single Ar guest atom, positionally disordered off-center in the large cages of sII. Above 1.7 GPa Ar clathrate transformed to a mixture of a body-centered orthorhombic filled-ice phase, which can be viewed as a polytype of ice-Ih, and high pressure forms of pure ice. The guest disorder is further substantiated by analysis of the guest to host ratio in this high pressure filled-ice structure. The bulk modulus of Ar filled-ice found to be 11.7 {+-} 0.4 GPa.

Yang, L.; Tulk, C.A.; Klug, D.D.; Chakoumakos, B.C.; Ehm, L.; Molaison, J.J.; Parise, J.B.; Simonson, J.M. (NRCC); (SBU); (ORNL)

2010-03-29T23:59:59.000Z

169

Combined technologies enable high-pressure slickline work  

SciTech Connect (OSTI)

Operators conducting wireline operations can combine the attributes of the slickline grease head and conventional stuffing box to enable work in gas wells at wellhead pressures above 15,000 psi. Wireline/slickline work in high-pressure wells requires meeting the dual challenges of well control and freedom of movement (up and down) for the lines. In a notable application of the combined-technology technique, an operator offshore Louisiana attempted to conduct wireline operations in an 18,000-ft gas and condensate well with 15,600 psi wellhead pressure, using a standard slickline stuffing box to contain the pressure. The standard equipment could not perform the needed function, which involved several trips to depths of 5,000 ft and 18,000 ft. Using a combined-technology, flow-tube stuffing box, the operator was able to conduct the wireline operation without incident; the control arrangement resulted in use of only 3 gal of lubricating oil throughout the job. Post-job analysis of the packing showed only the minimal wear normally associated with low-pressure wireline operations. Although slickline work can be performed in low-pressure gas wells without using the flow-tube stuffing box, the device and the oil used with it isolate the stuffing-box packing from the dry gases, reducing friction swell. This isolation speeds up the operation and reduces packing wear.

Davis, G. [Halliburton Energy Services Inc., Dallas, TX (United States); West, T. [Halliburton Energy Services Inc., Houma, LA (United States)

1998-10-01T23:59:59.000Z

170

Low pressure high speed Stirling air engine. Final technical report  

SciTech Connect (OSTI)

The purpose of this project was to design, construct and test a simple, appropriate technology low pressure, high speed, wood-fired Stirling air engine of 100 W output. The final design was a concentric piston/displacer engine of 454 in. bore and 1 in. stroke with a rhombic drive mechanism. The project engine was ultimately completed and tested, using a propane burner for all tests as a matter of convenience. The 100 W aim was exceeded, at atmospheric pressure, over a wide range of engine speed with the maximum power being 112 W at 1150 rpm. A pressure can was constructed to permit pressurization; however the grant funds were running out, and the only pressurized power test attempted was unsuccessful due to seal difficulties. This was a disappointment because numerous tests on the 4 cubic inch engine suggested power would be more than doubled with pressurization at 25 psig. A manifold was designed and constructed to permit operation of the engine over a standard No. 40 pot bellied stove. The engine was run successfully, but at reduced speed and power, over this stove. The project engine started out being rather noisy in operation, but modifications ultimately resulted in a very quiet engine. Various other difficulties and their solutions also are discussed. (LCL)

Ross, M.A.

1980-06-16T23:59:59.000Z

171

High Temperature, High Pressure Devices for Zonal Isolation in...  

Open Energy Info (EERE)

remotely and autonomous deployable structures for space and our high temperature composite technology developed for downhole applications. These devices offer several...

172

A temperature compensated pressure transducer for high temperature, high pressure applications  

E-Print Network [OSTI]

will work only if the cliange in deflectiou due to tenrperature ivas constant for all pressures. which is uot the case. At 0 ksi, the rliaphragni deflection is constant (zerol for all possible temperatures. At 40 ksi. however, the deflection is much... temperature. 3, 3 Basic Dimensioning After selecting the basic configuration and material for the transclucer body a diaphragm cap, it ivas next necessary to determine the actual defle& tion of the diaphragni and any thermally induced affects. Prior to a...

Lippka, Sandra Margaret

1991-01-01T23:59:59.000Z

173

Millimeter-wave Radiometer for High Sensitivity Water Vapor Profiling in Arid Regions  

SciTech Connect (OSTI)

Abstract - ProSensing Inc. has developed a G-band (183 GHz) water Vapor Radiometer (GVR) for long-term, unattended measurements of low concentrations of atmospheric water vapor and liquid water. Precipitable water vapor and liquid water path are estimated from zenith brightness temperatures measured from four double-sideband receiver channels, centered at 183.31 1, 3 and 7, and 14 GHz. A prototype ground-based version of the instrument was deployed at the DOE ARM program?s North Slope of Alaska site near Barrow AK in April 2005, where it collected data continuously for one year. A compact, airborne version of this instrument, packaged to operate from a standard 2-D PMS probe canister, has been tested on the ground and is scheduled for test flights in the summer of 2006. This paper presents design details, laboratory test results and examples of retrieved precipitable water vapor and liquid water path from measured brightness temperature data.

Pazmany, Andrew

2006-11-09T23:59:59.000Z

174

Film boiling of saturated liquid flowing upward through a heated tube : high vapor quality range  

E-Print Network [OSTI]

Film boiling of saturated liquid flowing upward through a uniformly heated tube has been studied for the case in which pure saturated liquid enters the tube and nearly saturated vapor is discharged. Since a previous study ...

Laverty, W. F.

1964-01-01T23:59:59.000Z

175

High-temperature pressure-coupled ultrasonic waveguide  

DOE Patents [OSTI]

A pressure coupled ultrasonic waveguide is provided to which one end may be attached a transducer and at the other end a high temperature material for continuous ultrasonic testing of the material. The ultrasonic signal is coupled from the waveguide into the material through a thin, dry copper foil.

Caines, M.J.

1981-02-11T23:59:59.000Z

176

Dissociation of methane under high pressure Guoying Gao,1,a  

E-Print Network [OSTI]

Dissociation of methane under high pressure Guoying Gao,1,a Artem R. Oganov,2,a Yanming Ma,1,b Hui Received 15 May 2010; accepted 18 August 2010; published online 12 October 2010 Methane is an extremely of methane under extreme conditions are of great fundamental interest. Using the ab initio evolutionary

Oganov, Artem R.

177

Numerical simulation of transient, incongruent vaporization induced by high power laser  

SciTech Connect (OSTI)

A mathematical model and numerical calculations were developed to solve the heat and mass transfer problems specifically for uranum oxide subject to laser irradiation. It can easily be modified for other heat sources or/and other materials. In the uranium-oxygen system, oxygen is the preferentially vaporizing component, and as a result of the finite mobility of oxygen in the solid, an oxygen deficiency is set up near the surface. Because of the bivariant behavior of uranium oxide, the heat transfer problem and the oxygen diffusion problem are coupled and a numerical method of simultaneously solving the two boundary value problems is studied. The temperature dependence of the thermal properties and oxygen diffusivity, as well as the highly ablative effect on the surface, leads to considerable non-linearities in both the governing differential equations and the boundary conditions. Based on the earlier work done in this laboratory by Olstad and Olander on Iron and on Zirconium hydride, the generality of the problem is expanded and the efficiency of the numerical scheme is improved. The finite difference method, along with some advanced numerical techniques, is found to be an efficient way to solve this problem.

Tsai, C.H.

1981-01-01T23:59:59.000Z

178

High-temperature stress measurement on chemical-vapor-deposited tungsten silicide and tungsten films  

SciTech Connect (OSTI)

Stresses in chemical-vapor-deposited tungsten silicide and tungsten films at high temperatures were measured. Tungsten silicide films were formed from WF/sub 6/ and SiH/sub 4/ or Si/sub 2/H/sub 6/. Tungsten films were formed from WF/sub 6/ and H/sub 2/. The stress in tungsten silicide films is tensile and in the order of 10/sup 9/--10/sup 10/ dynes/cm/sup 2/. For a composition ratio of Si/Wless than or equal to2.6, the stress of a film of more than 1000 A has a maximum at about 500 /sup 0/C. On the other hand, for a composition Si/W>2.9, the stress has no maximum. The maximum of the stress is caused by crystallization of the film. The stress has two components. One component is related to the difference of the thermal expansion coefficients between the film and the Si substrate. Another is related to the film crystallization. It was found that the stress concentrates in the portion of the film nearest the substrate. The stress in tungsten films also reaches a maximum at 550 /sup 0/C, similar to the tungsten silicide films. However, the cause of this behavior is not clear.

Shioya, Y.; Ikegami, K.; Maeda, M.; Yanagida, K.

1987-01-15T23:59:59.000Z

179

Absolute integrated intensities of vapor-phase hydrogen peroxide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Absolute integrated intensities of vapor-phase hydrogen peroxide (H202) in the mid-infrared at atmospheric pressure. Absolute integrated intensities of vapor-phase hydrogen...

180

Surface roughening of superalloys by high pressure pure waterjet  

SciTech Connect (OSTI)

A high pressure waterjet has been used to study the surface roughening of superalloys as preparation for thermal spraying. Designed experiments for Mar-M 509 and Rene 80 were carried out for the effects of jet pressure and mass of water delivered per unit area. Comparisons were made of several superalloys in terms of erosion, surface roughness and topology. The mechanism of jet erosion of Rene 80 was studied in relation to its metallurgical microstructure. An MCrAlY coating by shrouded plasma spray was made over a waterjet prepared surface with excellent bonding and having an ideally clean interface.

Taylor, T.A. [Praxair Surface Technologies Inc., Indianapolis, IN (United States)

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Experimental Investigation on High-pressure, High-temperature Viscosity of Gas Mixtures  

E-Print Network [OSTI]

Modeling the performance of high-pressure, high-temperature (HPHT) natural gas reservoirs requires the understanding of gas behavior at such conditions. In particular, gas viscosity is an important fluid property that directly affects fluid flow...

Davani, Ehsan

2012-02-14T23:59:59.000Z

182

Effects of pressure, temperature, and hydrogen during graphene growth on SiC(0001) using propane-hydrogen chemical vapor deposition  

SciTech Connect (OSTI)

Graphene growth from a propane flow in a hydrogen environment (propane-hydrogen chemical vapor deposition (CVD)) on SiC differentiates from other growth methods in that it offers the possibility to obtain various graphene structures on the Si-face depending on growth conditions. The different structures include the (6{radical}3 Multiplication-Sign 6{radical}3)-R30 Degree-Sign reconstruction of the graphene/SiC interface, which is commonly observed on the Si-face, but also the rotational disorder which is generally observed on the C-face. In this work, growth mechanisms leading to the formation of the different structures are studied and discussed. For that purpose, we have grown graphene on SiC(0001) (Si-face) using propane-hydrogen CVD at various pressure and temperature and studied these samples extensively by means of low energy electron diffraction and atomic force microscopy. Pressure and temperature conditions leading to the formation of the different structures are identified and plotted in a pressure-temperature diagram. This diagram, together with other characterizations (X-ray photoemission and scanning tunneling microscopy), is the basis of further discussions on the carbon supply mechanisms and on the kinetics effects. The entire work underlines the important role of hydrogen during growth and its effects on the final graphene structure.

Michon, A.; Vezian, S.; Roudon, E.; Lefebvre, D.; Portail, M. [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France)] [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France); Zielinski, M.; Chassagne, T. [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)] [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)

2013-05-28T23:59:59.000Z

183

Aging study of boiling water reactor high pressure injection systems  

SciTech Connect (OSTI)

The purpose of high pressure injection systems is to maintain an adequate coolant level in reactor pressure vessels, so that the fuel cladding temperature does not exceed 1,200{degrees}C (2,200{degrees}F), and to permit plant shutdown during a variety of design basis loss-of-coolant accidents. This report presents the results of a study on aging performed for high pressure injection systems of boiling water reactor plants in the United States. The purpose of the study was to identify and evaluate the effects of aging and the effectiveness of testing and maintenance in detecting and mitigating aging degradation. Guidelines from the United States Nuclear Regulatory Commission`s Nuclear Plant Aging Research Program were used in performing the aging study. Review and analysis of the failures reported in databases such as Nuclear Power Experience, Licensee Event Reports, and the Nuclear Plant Reliability Data System, along with plant-specific maintenance records databases, are included in this report to provide the information required to identify aging stressors, failure modes, and failure causes. Several probabilistic risk assessments were reviewed to identify risk-significant components in high pressure injection systems. Testing, maintenance, specific safety issues, and codes and standards are also discussed.

Conley, D.A.; Edson, J.L.; Fineman, C.F. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

1995-03-01T23:59:59.000Z

184

Covered Product Category: Industrial Luminaires (High/Low Bay...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

requirements shown in Table 1. Other high-intensity discharge lamp types, such as mercury-vapor and low-pressure sodium, have very poor color rendition. Mercury-vapor...

185

High Pressure Burn Rate Measurements on an Ammonium Perchlorate Propellant  

SciTech Connect (OSTI)

High pressure deflagration rate measurements of a unique ammonium perchlorate (AP) based propellant are required to design the base burn motor for a Raytheon weapon system. The results of these deflagration rate measurements will be key in assessing safety and performance of the system. In particular, the system may experience transient pressures on the order of 100's of MPa (10's kPSI). Previous studies on similar AP based materials demonstrate that low pressure (e.g. P < 10 MPa or 1500 PSI) burn rates can be quite different than the elevated pressure deflagration rate measurements (see References and HPP results discussed herein), hence elevated pressure measurements are necessary in order understand the deflagration behavior under relevant conditions. Previous work on explosives have shown that at 100's of MPa some explosives will transition from a laminar burn mechanism to a convective burn mechanism in a process termed deconsolidative burning. The resulting burn rates that are orders-of-magnitude faster than the laminar burn rates. Materials that transition to the deconsolidative-convective burn mechanism at elevated pressures have been shown to be considerably more violent in confined heating experiments (i.e. cook-off scenarios). The mechanisms of propellant and explosive deflagration are extremely complex and include both chemical, and mechanical processes, hence predicting the behavior and rate of a novel material or formulation is difficult if not impossible. In this work, the AP/HTPB based material, TAL-1503 (B-2049), was burned in a constant volume apparatus in argon up to 300 MPa (ca. 44 kPSI). The burn rate and pressure were measured in-situ and used to calculate a pressure dependent burn rate. In general, the material appears to burn in a laminar fashion at these elevated pressures. The experiment was reproduced multiple times and the burn rate law using the best data is B = (0.6 {+-} 0.1) x P{sup (1.05{+-}0.02)} where B is the burn rate in mm/s and P is the pressure in units of MPa. Details of the experimental method, results and data analysis are discussed herein and briefly compared to other AP based materials that have been measured in this apparatus.

Glascoe, E A; Tan, N

2010-04-21T23:59:59.000Z

186

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE andHighWells | Department

187

Modified approaches for high pressure filtration of fine clean coal  

SciTech Connect (OSTI)

Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

1995-12-31T23:59:59.000Z

188

High pressure argon ionization chamber systems for the measurement of environmental radiation exposure rates  

E-Print Network [OSTI]

High pressure argon ionization chamber systems for the measurement of environmental radiation exposure rates

DeCampo, J A; Raft, P D

1972-01-01T23:59:59.000Z

189

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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190

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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191

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

192

Thermodynamic properties of hydrocarbon liquids at high pressures and temperatures  

SciTech Connect (OSTI)

Understanding the organic/inorganic interface in the Earth's crust requires values of the thermodynamic properties of hydrocarbon species in crude oil, coal, and natural gas at elevated temperatures and pressures. Values of the apparent standard partial molal Gibbs free energies and enthalpies of formation and the standard partial molal entropies and heat capacities of these organic species can be computed as a function of temperature at 1 bar using the equations of state adopted by Helgeson et al (1991). The pressure dependence of the thermodynamic properties can be calculated from a modified version of the Parameters From Group Contributions (PFGC) equation of state. To improve the accuracy of these predictions, critical evaluation of high-pressure density experiments reported in the literature was used in the present study to characterize b[sub j] as a function of pressure and temperature. The revised PFGC equation of state permits accurate calculation of the standard partial molal volumes of the major hydrocarbon species in the aliphatic, aromatic, and naphthenic fractions of crude oil, as well as fatty acids, phenols, and naphthenic acids at temperatures and pressures to 500 C and 5 kbar. Combining the revised PFGC equation of state and parameters with the standard partial molal properties of these species at one bar and those of aqueous species and minerals permits calculation of the apparent standard partial molal Gibbs Free energies of reaction, and thus equilibrium constants for a wide variety of chemical equilibria among organic liquids, solids, and gases, aqueous species, and minerals at temperatures and pressures characteristic of both diagenetic and low-grade metamorphic processes in the Earth's crust.

Aagaard, P. (Univ. of Oslo (Norway). Dept. of Geology); Oelkers, E.H. (Univ. Paul Sabatier, Toulouse (France). Lab. de Geochimie); Helgeson, H.C. (Univ. of California, Berkeley, CA (United States). Dept. of Geology and Geophysics)

1992-01-01T23:59:59.000Z

193

Novel Low Cost Organic Vapor Jet Printing of Striped High Efficiency Phosphorescent OLEDs for White Lighting  

SciTech Connect (OSTI)

In this program, Universal Display Corporation and University of Michigan proposed to integrate three innovative concepts to meet the DOE's Solid State Lighting (SSL) goals: (1) high-efficiency phosphorescent organic light emitting device (PHOLED{trademark}) technology, (2) a white lighting design that is based on a series of red, green and blue OLED stripes, and (3) the use of a novel cost-effective, high rate, mask-less deposition process called organic vapor jet printing (OVJP). Our PHOLED technology offers up to four-times higher power efficiency than other OLED approaches for general lighting. We believe that one of the most promising approaches to maximizing the efficiency of OLED lighting sources is to produce stripes of the three primary colors at such a pitch (200-500 {mu}m) that they appear as a uniform white light to an observer greater than 1 meter (m) away from the illumination source. Earlier work from a SBIR Phase 1 entitled 'White Illumination Sources Using Striped Phosphorescent OLEDs' suggests that stripe widths of less than 500 {mu}m appear uniform from a distance of 1m without the need for an external diffuser. In this program, we intend to combine continued advances in this PHOLED technology with the striped RGB lighting design to demonstrate a high-efficiency, white lighting source. Using this background technology, the team has focused on developing and demonstrating the novel cost-effective OVJP process to fabricate these high-efficiency white PHOLED light sources. Because this groundbreaking OVJP process is a direct printing approach that enables the OLED stripes to be printed without a shadow mask, OVJP offers very high material utilization and high throughput without the costs and wastage associated with a shadow mask (i.e. the waste of material that deposits on the shadow mask itself). As a direct printing technique, OVJP also has the potential to offer ultra-high deposition rates (> 1,000 Angstroms/second) for any size or shaped features. As a result, we believe that this work will lead to the development of a cost-effective manufacturing solution to produce very-high efficiency OLEDs. By comparison to more common ink-jet printing (IJP), OVJP can also produce well-defined patterns without the need to pattern the substrate with ink wells or to dry/anneal the ink. In addition, the material set is not limited by viscosity and solvent solubility. During the program we successfully demonstrated a 6-inch x 6-inch PHOLED lighting panel consisting of fine-featured red, green and blue (R-G-B) stripes (1mm width) using an OVJP deposition system that was designed, procured and installed into UDC's cleanroom as part of this program. This project will significantly accelerate the DOE's ability to meet its 2015 DOE SSL targets of 70-150 lumens/Watt and less than $10 per 1,000 lumens for high CRI lighting index (76-90). Coupled with a low cost manufacturing path through OVJP, we expect that this achievement will enable the DOE to achieve its 2015 performance goals by the year 2013, two years ahead of schedule. As shown by the technical work performed under this program, we believe that OVJP is a very promising technology to produce low cost, high efficacy, color tunable light sources. While we have made significant progress to develop OVJP technology and build a pilot line tool to study basic aspects of the technology and demonstrate a lighting panel prototype, further work needs to be performed before its full potential and commercial viability can be fully assessed.

Mike Hack

2008-12-31T23:59:59.000Z

194

Intermittently-fed high-pressure gasifier process  

DOE Patents [OSTI]

An improved gasifier adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications.

Bailey, John M. (Dunlap, IL); Zadoks, Abraham L. (Peoria, IL)

1993-11-30T23:59:59.000Z

195

Intermittently-fed high-pressure gasifier process  

DOE Patents [OSTI]

An improved gasifier is described which is adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications. 3 figures.

Bailey, J.M.; Zadoks, A.L.

1993-11-30T23:59:59.000Z

196

High pressure liquid chromatographic method for CP amide analysis  

SciTech Connect (OSTI)

A method has been developed for the analysis of the 5-carboxamidotetrazolatopentaamminecobalt(III) perchlorate contaminant of the explosive CP (2-(5-cyanotetrazolato)-pentaamminecobalt(III) perchlorate). The analysis utilizes a Zn/Hg reduction of the cobalt (III) complexes to allow a high pressure liquid chromatographic (HPLC) analysis of the reaction products; the product analysis is directly related to the weight percent of impurity present in the explosive. The technique is described and shortcomings pointed out.

Loyola, V. M.; Womelsduff, J. E.

1981-02-01T23:59:59.000Z

197

Toroid cavities as NMR detectors in high pressure probes  

SciTech Connect (OSTI)

A cylindrical toroid cavity has been developed for application as an NMR detector for high sensitivity and high resolution spectroscopy in metal vessel probes. Those probes are used for in situ investigations at high temperature and pressure. Since the transmitted r.f. field is completely confined within the torus, the cavity can be placed inside the pressurized system without magnetic coupling to the metal vessel. Resonance frequencies up to 400 MHz make the toroid cavity detector especially suited for use in {sup 1}H and {sup 19}F spectroscopy. Typically achieved static {sup 1}H linewidths, measured on CHCl{sub 3} using cavities in Be-Cu pressure vessels, are 2.0 Hz. On the basis of theoretical considerations that include the radial dependence of the r.f. field within cylindrical or circular toroid detectors, equations were evolved to predict the signal intensity as a function of the pulse width. The equations precisely describe the deviations from the sinusoidal approximation, which is generally used for signal intensities derived from Helmholtz or solenoid coils.

Woelk, K.; Rathke, J.W.; Klingler, R.J.

1993-03-01T23:59:59.000Z

198

Devices and process for high-pressure magic angle spinning nuclear magnetic resonance  

DOE Patents [OSTI]

A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.

Hoyt, David W; Sears, Jr., Jesse A; Turcu, Romulus V.F.; Rosso, Kevin M; Hu, Jian Zhi

2014-04-08T23:59:59.000Z

199

Synthesis of high-quality monolayer and bilayer graphene on copper using chemical vapor deposition  

E-Print Network [OSTI]

exfoliation of graphite [1], sublimation of epitaxial SiC [4], and catalyst-assisted chemical vapor deposition (CVD) [5­9]. However, mechanical exfoliation of graphite can only supply small-size graphene (see Fig than that of graphene obtained via exfoli- ation of graphite as summarized in Fig. 1. While many

200

Practical features of illumination with high pressure sodium lamps  

SciTech Connect (OSTI)

A number of concerns raised about the health effects of high pressure sodium lamps (HPS) are discussed. The notion of a ''natural'' human photic environment based on sunlight is disputed. Humans are better adapted to the ''greenish'' spectral composition of forest light than to direct sunlight. It is ironic that the artificial light source which has received the most disapproval, cool white flourescent lamp, has a spectral composition similar to that of forest light. HPS is also available in a full range of colors. Some successful examples of HPS--from North Division High School, in Milwaukee, Wisconsin, to museum exhibits at National Geographic in Washington--are listed.

Corth, R.

1983-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame andHigh-Pressure

202

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlameHigh-Pressure MOF

203

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlameHigh-Pressure

204

Optical coatings of variable refractive index and high laser-resistance from physical-vapor-deposited perfluorinated amorphous polymer  

DOE Patents [OSTI]

Variable index optical single-layers, optical multilayer, and laser-resistant coatings were made from a perfluorinated amorphous polymer material by physical vapor deposition. This was accomplished by physically vapor depositing a polymer material, such as bulk Teflon AF2400, for example, to form thin layers that have a very low refractive index (.about.1.10-1.31) and are highly transparent from the ultra-violet through the near infrared regime, and maintain the low refractive index of the bulk material. The refractive index can be varied by simply varying one process parameter, either the deposition rate or the substrate temperature. The thus forming coatings may be utilized in anti-reflectors and graded anti-reflection coatings, as well as in optical layers for laser-resistant coatings at optical wavelengths of less than about 2000 nm.

Chow, Robert (Livermore, CA); Loomis, Gary E. (Livermore, CA); Thomas, Ian M. (Livermore, CA)

1999-01-01T23:59:59.000Z

205

Optical coatings of variable refractive index and high laser-resistance from physical-vapor-deposited perfluorinated amorphous polymer  

DOE Patents [OSTI]

Variable index optical single-layers, optical multilayer, and laser-resistant coatings were made from a perfluorinated amorphous polymer material by physical vapor deposition. This was accomplished by physically vapor depositing a polymer material, such as bulk Teflon AF2400, for example, to form thin layers that have a very low refractive index (ca. 1.10--1.31) and are highly transparent from the ultra-violet through the near infrared regime, and maintain the low refractive index of the bulk material. The refractive index can be varied by simply varying one process parameter, either the deposition rate or the substrate temperature. The thus forming coatings may be utilized in anti-reflectors and graded anti-reflection coatings, as well as in optical layers for laser-resistant coatings at optical wavelengths of less than about 2000 nm. 2 figs.

Chow, R.; Loomis, G.E.; Thomas, I.M.

1999-03-16T23:59:59.000Z

206

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

A high pressure apparatus constructed for measuring the rates of reactions in liquids under pressures ranging from 1 atm to 2000 atm has been used to measure the complexation kinetics of molybdenum hexacarbonyl reacting with 2,2-bipyridine, 4,4{prime}-dimethyl-2-2{prime}-bipyridine and 4,4{prime}-diphenyl-2-2{prime} bipyridine in toluene. Pentacarbonyl reaction intermediates are created by a 10 nsec flash of frequency tripled Nd:YAG laser light. Measured activation volumes for chelate ligand ring closure indicate a change in mechanism from associative interchange to dissociative interchange as steric hindrance increases. A similar high pressure kinetics study of molybdenum carbonyl complexation by several substituted phenanthrolines is now well advanced that indicates that with the more rigid phenanthroline ligands steric effects from bulky substituents have less effect on the ring closure mechanism than in the case of the bipyridine ligands. An experimental concentration dependence of the fluorescence quantum yield of cresyl violet has been harmonized with previously published contradictory reports. Fluorescence of cresyl violet in various solvents and in micellar systems has also been systematically explored.

Eyring, E.M.

1991-11-25T23:59:59.000Z

207

Design and development of a high resolution differential pressure transducer for use at high temperature and high pressure  

E-Print Network [OSTI]

are multiple diaphragms attached at the edges. Flat and corrugated diaphragms are discussed at length by Giovanni (1982). The three most common detection systems are strain gauges, capacitance gauges, and linear variable differential transformers (LVDT... be necessary to connect the resistor and ratio transformer to. the same secondary coil to balance the voltage of the . two secondary coils. Samplers Inlet Inert Fluid Inlet Pressure Housing Electrical Feedthrough LVDT Coils Magnetic Core Pressure...

Childers, Laren Paul

1984-01-01T23:59:59.000Z

208

High pressure behavior of otavite (CdCo3)  

SciTech Connect (OSTI)

The high-pressure, room temperature behavior of otavite (CdCO{sub 3}) was investigated by angle-dispersive synchrotron radiation powder diffraction up to 40 GPa, Raman spectroscopy up to 23 GPa and quantum mechanical calculations based on density functional theory. The calcite-type structure of CdCO{sub 3} is stable up to at least {approx}19 GPa as shown by Raman spectroscopy. The compression mechanism was obtained from structure refinements against the diffraction data. The quantum mechanical calculations propose a calcite-aragonite phase transition to occur at about 30 GPa. The existence of a pressure-induced phase transition is supported by the Raman and diffraction experiments. Evidence for the transformation is given by broadening of X-ray reflections and external Raman bands starting from about 19 GPa in both experiments.

Minch, R.; Ehm, L.; Seoung, D.H.; Winkler, B.; Knorr, K.; Peters, L.; Borkowski, L.A.; Parise, J.B.; Lee, Y.; Dubrovinsky, L.; Depmeier, W.

2010-08-24T23:59:59.000Z

209

High pressure generation by hot electrons driven ablation  

SciTech Connect (OSTI)

A previous model [Piriz et al. Phys. Plasmas 19, 122705 (2012)] for the ablation driven by the hot electrons generated in collisionless laser-plasma interactions in the framework of shock ignition is revisited. The impact of recent results indicating that for a laser wavelength ? = 0.35 ?m the hot electron temperature ?{sub H} would be independent of the laser intensity I, on the resulting ablation pressure is considered. In comparison with the case when the scaling law ?{sub H}?(I?{sup 2}){sup 1/3} is assumed, the generation of the high pressures needed for driving the ignitor shock may be more demanding. Intensities above 10{sup 17} W/cm{sup 2} would be required for ?{sub H}=25?30 keV.

Piriz, A. R. [E.T.S.I. Industriales, CYTEMA, and Instituto de Investigaciones Energéticas, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain)] [E.T.S.I. Industriales, CYTEMA, and Instituto de Investigaciones Energéticas, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain); Piriz, S. A. [Facultad de Ciencias Físicas, Universidad Complutense de Madrid, 28040 Madrid (Spain)] [Facultad de Ciencias Físicas, Universidad Complutense de Madrid, 28040 Madrid (Spain); Tahir, N. A. [GSI Helmholtzzentrum für Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany)] [GSI Helmholtzzentrum für Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany)

2013-11-15T23:59:59.000Z

210

FRICTION FACTOR IN HIGH PRESSURE NATURAL GAS PIPELINES FROM ROUGHNESS MEASUREMENTS  

E-Print Network [OSTI]

FRICTION FACTOR IN HIGH PRESSURE NATURAL GAS PIPELINES FROM ROUGHNESS MEASUREMENTS DETERMINATION DU and Technology, Norway ABSTRACT Pressure drop experiments on natural gas flow at 80 to 120 bar pressure and high of natural gas at typical operating pressures (100-180 bar). At such Reynolds numbers the classical Colebrook

Gudmundsson, Jon Steinar

211

Dislocations and Plasticity in bcc Transition Metals at High Pressure  

SciTech Connect (OSTI)

Using first-principles electronic structure calculations, quantum-based atomistic simulations and atomistically informed dislocation dynamics (DD) simulations, we have studied individual dislocation behavior and the multiscale modeling of single-crystal plasticity in the prototype bcc transition metals Ta, Mo and V under both ambient and high pressure conditions. The primary focus in this work is on the pressure-dependent structure, mobility and interaction of a/2<111> screw dislocations, which dominate the plastic deformation properties of these materials. At the electronic scale, first-principles calculations of elasticity, ideal strength and generalized stacking fault energy surfaces have been used to validate quantum-based multi-ion interatomic potentials. At the atomistic scale, these potentials have been used in flexible Green's function boundary condition simulations to study the core structure, Peierls stress {tau}{sub P}, thermally activated kink-pair formation and mobility below {tau}{sub P}, and phonon-drag mobility above {tau}{sub P}. These results have then been distilled into analytic velocity laws and used directly in predictive microscale DD simulations of flow stress and resolved yield stress over wide ranges of pressure, temperature and strain rate.

Yang, L H; Tang, M; Moriarty, J A

2009-01-23T23:59:59.000Z

212

System Study: High-Pressure Core Spray 1998–2012  

SciTech Connect (OSTI)

This report presents an unreliability evaluation of the high-pressure core spray (HPCS) at 8 U.S. commercial boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPCS results.

T. E. Wierman

2013-10-01T23:59:59.000Z

213

System Study: High-Pressure Safety Injection 1998–2012  

SciTech Connect (OSTI)

This report presents an unreliability evaluation of the high-pressure safety injection system (HPSI) at 69 U.S. commercial nuclear power plants. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPSI results.

T. E. Wierman

2013-10-01T23:59:59.000Z

214

Low-Cost High-Pressure Hydrogen Generator  

SciTech Connect (OSTI)

Electrolysis of water, particularly in conjunction with renewable energy sources, is potentially a cost-effective and environmentally friendly method of producing hydrogen at dispersed forecourt sites, such as automotive fueling stations. The primary feedstock for an electrolyzer is electricity, which could be produced by renewable sources such as wind or solar that do not produce carbon dioxide or other greenhouse gas emissions. However, state-of-the-art electrolyzer systems are not economically competitive for forecourt hydrogen production due to their high capital and operating costs, particularly the cost of the electricity used by the electrolyzer stack. In this project, Giner Electrochemical Systems, LLC (GES) developed a low cost, high efficiency proton-exchange membrane (PEM) electrolysis system for hydrogen production at moderate pressure (300 to 400 psig). The electrolyzer stack operates at differential pressure, with hydrogen produced at moderate pressure while oxygen is evolved at near-atmospheric pressure, reducing the cost of the water feed and oxygen handling subsystems. The project included basic research on catalysts and membranes to improve the efficiency of the electrolysis reaction as well as development of advanced materials and component fabrication methods to reduce the capital cost of the electrolyzer stack and system. The project culminated in delivery of a prototype electrolyzer module to the National Renewable Energy Laboratory for testing at the National Wind Technology Center. Electrolysis cell efficiency of 72% (based on the lower heating value of hydrogen) was demonstrated using an advanced high-strength membrane developed in this project. This membrane would enable the electrolyzer system to exceed the DOE 2012 efficiency target of 69%. GES significantly reduced the capital cost of a PEM electrolyzer stack through development of low cost components and fabrication methods, including a 60% reduction in stack parts count. Economic analysis indicates that hydrogen could be produced for $3.79 per gge at an electricity cost of $0.05/kWh by the lower-cost PEM electrolyzer developed in this project, assuming high-volume production of large-scale electrolyzer systems.

Cropley, Cecelia C.; Norman, Timothy J.

2008-04-02T23:59:59.000Z

215

Stationary High-Pressure Hydrogen Storage | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartmentScopingOverviewFranklin M. Orr,EnergyHigh-Pressure

216

System Study: High-Pressure Coolant Injection 1998-2012  

SciTech Connect (OSTI)

This report presents an unreliability evaluation of the high-pressure coolant injection system (HPCI) at 69 U.S. commercial nuclear power plants. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPCI results.

T. E. Wierman

2013-10-01T23:59:59.000Z

217

Acceptance test procedure for High Pressure Water Jet System  

SciTech Connect (OSTI)

The overall objective of the acceptance test is to demonstrate a combined system. This includes associated tools and equipment necessary to perform cleaning in the 105 K East Basin (KE) for achieving optimum reduction in the level of contamination/dose rate on canisters prior to removal from the KE Basin and subsequent packaging for disposal. Acceptance tests shall include necessary hardware to achieve acceptance of the cleaning phase of canisters. This acceptance test procedure will define the acceptance testing criteria of the high pressure water jet cleaning fixture. The focus of this procedure will be to provide guidelines and instructions to control, evaluate and document the acceptance testing for cleaning effectiveness and method(s) of removing the contaminated surface layer from the canister presently identified in KE Basin. Additionally, the desired result of the acceptance test will be to deliver to K Basins a thoroughly tested and proven system for underwater decontamination and dose reduction. This report discusses the acceptance test procedure for the High Pressure Water Jet.

Crystal, J.B.

1995-05-30T23:59:59.000Z

218

Very low pressure high power impulse triggered magnetron sputtering  

DOE Patents [OSTI]

A method and apparatus are described for very low pressure high powered magnetron sputtering of a coating onto a substrate. By the method of this invention, both substrate and coating target material are placed into an evacuable chamber, and the chamber pumped to vacuum. Thereafter a series of high impulse voltage pulses are applied to the target. Nearly simultaneously with each pulse, in one embodiment, a small cathodic arc source of the same material as the target is pulsed, triggering a plasma plume proximate to the surface of the target to thereby initiate the magnetron sputtering process. In another embodiment the plasma plume is generated using a pulsed laser aimed to strike an ablation target material positioned near the magnetron target surface.

Anders, Andre; Andersson, Joakim

2013-10-29T23:59:59.000Z

219

Smart Onboard Inspection of High Pressure Gas Fuel Cylinders  

SciTech Connect (OSTI)

The use of natural gas as an alternative fuel in automotive applications is not widespread primarily because of the high cost and durability of the composite storage tanks. Tanks manufactured using carbon fiber are desirable in weight critical passenger vehicles because of the low density of carbon fiber. The high strength of carbon fiber also translates to a weight reduction because thinner wall designs are possible to withstand the internal pressure loads. However, carbon fiber composites are prone to impact damage that over the life of the storage tank may lead to an unsafe condition for the vehicle operator. A technique that potentially may be a reliable indication of developing hazardous conditions in composite fuel tanks is imbedded fiber optics. The applicability of this technique to onboard inspection is discussed and results from preliminary lab testing indicate that fiber optic sensors can reliably detect impact damage.

Beshears, D.L.; Starbuck, J.M.

1999-09-27T23:59:59.000Z

220

Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b  

E-Print Network [OSTI]

Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b , Shun 2009 Editor: L. Stixrude Keywords: electrical conductivity wadsleyite oxygen fugacity frequency water The electrical conductivity of wadsleyite aggregates has been determined under the broad range of thermodynamic

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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221

High- and low-temperature-stable thermite composition for producing high-pressure, high-velocity gases  

DOE Patents [OSTI]

A high- and low-temperature-stable thermite composition for producing high-pressure and high-velocity gases comprises an oxidizable metal, an oxidizing reagent, and a high-temperature-stable gas-producing additive selected from the group consisting of metal carbides and metal nitrides.

Halcomb, Danny L. (Camden, OH); Mohler, Jonathan H. (Spring Valley, OH)

1990-10-16T23:59:59.000Z

222

High-pressure coal fuel processor development. Final report  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

1992-12-01T23:59:59.000Z

223

Pressure Resistance Welding of High Temperature Metallic Materials  

SciTech Connect (OSTI)

Pressure Resistance Welding (PRW) is a solid state joining process used for various high temperature metallic materials (Oxide dispersion strengthened alloys of MA957, MA754; martensitic alloy HT-9, tungsten etc.) for advanced nuclear reactor applications. A new PRW machine has been installed at the Center for Advanced Energy Studies (CAES) in Idaho Falls for conducting joining research for nuclear applications. The key emphasis has been on understanding processing-microstructure-property relationships. Initial studies have shown that sound joints can be made between dissimilar materials such as MA957 alloy cladding tubes and HT-9 end plugs, and MA754 and HT-9 coupons. Limited burst testing of MA957/HT-9 joints carried out at various pressures up to 400oC has shown encouraging results in that the joint regions do not develop any cracking. Similar joint strength observations have also been made by performing simple bend tests. Detailed microstructural studies using SEM/EBSD tools and fatigue crack growth studies of MA754/HT-9 joints are ongoing.

N. Jerred; L. Zirker; I. Charit; J. Cole; M. Frary; D. Butt; M. Meyer; K. L. Murty

2010-10-01T23:59:59.000Z

224

A multi-purpose modular system for high-resolution microscopy at high hydrostatic pressure  

E-Print Network [OSTI]

We have developed a modular system for high-resolution microscopy at high hydrostatic pressure. The system consists of a pressurised cell of volume ~100 microlitres, a temperature controlled holder, a ram and a piston. We have made each of these components in several versions which can be interchanged to allow a wide range of applications. Here, we report two pressure cells with pressure ranges 0.1-700MPa and 0.1-100MPa, which can be combined with hollow or solid rams and pistons. Our system is designed to work with fluorescent samples (using a confocal or epifluorescence microscope), but also allows for transmitted light microscopy via the hollow ram and piston. The system allows precise control of pressure and temperature [-20-70C], as well as rapid pressure quenching. We demonstrate its performance and versatility with two applications: time-resolved imaging of colloidal phase transitions caused by pressure changes between 0.1MPa and 101MPa, and imaging the growth of Escherichia coli bacteria at 50MPa. We ...

Vass, Hugh; Herzig, Eva M; Ward, F Bruce; Clegg, Paul S; Allen, Rosalind J

2009-01-01T23:59:59.000Z

225

GFOC Project results: High Temperature / High Pressure, Hydrogen Tolerant Optical Fiber  

SciTech Connect (OSTI)

Tests results are given for exposure of multimode optical fiber to high temperatures (300 deg. C) and high partial pressure (15 bar) hydrogen. These results demonstrate that fluorine down doped optical fibers are much more hydrogen tolerant than traditional germanium doped multimode optical fibers. Also demonstrated is the similar hydrogen tolerance of carbon coated and non-carbon coated fibers. Model for reversible H2 impact in fiber versus T{sup o}C and H2 pressure is given. These results have significant impact for the longevity of use for distributed temperature sensing applications in harsh environments such as geothermal wells.

E. Burov; A. Pastouret; E. Aldea; B. Overton; F. Gooijer; A. Bergonzo

2012-02-12T23:59:59.000Z

226

On the atomic line profiles in high pressure plasmas  

SciTech Connect (OSTI)

In a previous contribution to this journal [H. P. Stormberg, J. Appl. Phys. 51(4), 1963 (1980)], Stormberg presented an analytical expression for the convolution of Lorentz and Levy line profiles, which models atomic radiative transitions in high pressure plasmas. Unfortunately, the derivations are flawed with errors and the final expression, while correct, is accompanied by misguiding comments about the meaning of the symbols used therein, in particular the “complex error function.” In this paper, we discuss the broadening mechanisms that give rise to Stormberg's model and present a correct derivation of his final result. We will also provide an alternative expression, based on the Faddeeva function, which has decisive computational advantages and emphasizes the real-valuedness of the result. The MATLAB/Octave scripts of our implementation have been made available on the publisher's website for future reference.

Janssen, J. F. J.; Gnybida, M.; Rijke, A. J.; Dijk, J. van [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)] [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Suijker, J. L. G. [Philips Lighting R and D Category Professional Lamps, P.O. Box 80020, 5600 JM Eindhoven (Netherlands)] [Philips Lighting R and D Category Professional Lamps, P.O. Box 80020, 5600 JM Eindhoven (Netherlands)

2013-11-14T23:59:59.000Z

227

High pressure studies on nanocrystalline aurivillius oxides lead and mercury chalcogenides;.  

E-Print Network [OSTI]

??The high pressure and high temperature play a vital role in newlineunderstanding the physical properties of the solids including such classes of newlinematerials like semiconductors… (more)

Freny joy K M

2015-01-01T23:59:59.000Z

228

anomalous high-pressure behavior: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

than recently predicted. McMahon, Jeffrey M 2011-01-01 105 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

229

Three precision differential pressure indicators for operation at high temperatures and pressures  

E-Print Network [OSTI]

, the design did have a 7 Pa sensitivity which is especially imoortant as the sensing transformer was located outside the pressure containment. This feature eliminates the need for electrical feedthroughs which usually limit the operating conditions... was constructed and the sensitivity increased to ? 5 -1 2x10 Pa using the same transformer. Based on the designs tested, a new differential pressure indicator was proposed. Using a diaphragm with a linear variable differential transformer outside the pressure...

Osburn, Douglas Clayton

1981-01-01T23:59:59.000Z

230

Equations of state of ice VI and ice VII at high pressure and high temperature  

SciTech Connect (OSTI)

High-pressure H{sub 2}O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H{sub 2}O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give V{sub 0} = 14.17(2) cm{sup 3}?mol{sup ?1}, K{sub 0} = 14.05(23) GPa, and ?{sub 0} = 14.6(14) × 10{sup ?5} K{sup ?1} for ice VI and V{sub 0} = 12.49(1) cm{sup 3}?mol{sup ?1}, K{sub 0} = 20.15(16) GPa, and ?{sub 0} = 11.6(5) × 10{sup ?5} K{sup ?1} for ice VII.

Bezacier, Lucile; Hanfland, Michael [European Synchrotron Radiation Facility, 6 rue Jules Horowitz, 38000 Grenoble (France); Journaux, Baptiste; Perrillat, Jean-Philippe; Cardon, Hervé; Daniel, Isabelle [Laboratoire de Géologie de Lyon, UMR 5276 CNRS, Ecole Normale Supérieure de Lyon – Université Claude Bernard Lyon 1, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex (France)

2014-09-14T23:59:59.000Z

231

High-pressure cell for neutron diffraction with in situ pressure control at cryogenic temperatures  

SciTech Connect (OSTI)

Pressure generation at cryogenic temperatures presents a problem for a wide array of experimental techniques, particularly neutron studies due to the volume of sample required. We present a novel, compact pressure cell with a large sample volume in which load is generated by a bellow. Using a supply of helium gas up to a pressure of 350 bar, a load of up to 78 kN is generated with leak-free operation. In addition, special fiber ports added to the cryogenic center stick allow for in situ pressure determination using the ruby pressure standard. Mechanical stability was assessed using finite element analysis and the dimensions of the cell have been optimized for use with standard cryogenic equipment. Load testing and on-line experiments using NaCl and BiNiO{sub 3} have been done at the WISH instrument of the ISIS pulsed neutron source to verify performance.

Jacobsen, Matthew K.; Ridley, Christopher J.; Bocian, Artur; Kamenev, Konstantin V., E-mail: k.kamenev@ed.ac.uk [School of Engineering and CSEC, University of Edinburgh, Edinburgh (United Kingdom); Kirichek, Oleg; Manuel, Pascal; Khalyavin, Dmitry [ISIS, Rutherford Appleton Laboratory, Harwell Oxford (United Kingdom)] [ISIS, Rutherford Appleton Laboratory, Harwell Oxford (United Kingdom); Azuma, Masaki [Materials and Structures Laboratory, Tokyo Institute of Technology, Tokyo (Japan)] [Materials and Structures Laboratory, Tokyo Institute of Technology, Tokyo (Japan); Attfield, J. Paul [School of Chemistry and CSEC, University of Edinburgh, Edinburgh (United Kingdom)] [School of Chemistry and CSEC, University of Edinburgh, Edinburgh (United Kingdom)

2014-04-15T23:59:59.000Z

232

High Performance Fuel Desing for Next Generation Pressurized Water Reactors  

SciTech Connect (OSTI)

The use of internally and externally cooled annular fule rods for high power density Pressurized Water Reactors is assessed. The assessment included steady state and transient thermal conditions, neutronic and fuel management requirements, mechanical vibration issues, fuel performance issues, fuel fabrication methods and econmic assessment. The investigation was donducted by a team from MIT, Westinghouse, Gamma Engineering, Framatome ANP, and AECL. The analyses led to the conclusion that raising the power density by 50% may be possible with this advanced fuel. Even at the 150% power level, the fuel temperature would be a few hundred degrees lower than the current fuel temperatre. Significant economic and safety advantages can be obtained by using this fuel in new reactors. Switching to this type of fuel for existing reactors would yield safety advantages, but the economic return is dependent on the duration of plant shutdown to accommodate higher power production. The main feasiblity issue for the high power performance appears to be the potential for uneven splitting of heat flux between the inner and outer fuel surfaces due to premature closure of the outer fuel-cladding gap. This could be overcome by using a very narrow gap for the inner fuel surface and/or the spraying of a crushable zirconium oxide film at the fuel pellet outer surface. An alternative fuel manufacturing approach using vobropacking was also investigated but appears to yield lower than desirable fuel density.

Mujid S. Kazimi; Pavel Hejzlar

2006-01-31T23:59:59.000Z

233

High Temperature Electrolysis Pressurized Experiment Design, Operation, and Results  

SciTech Connect (OSTI)

A new facility has been developed at the Idaho National Laboratory for pressurized testing of solid oxide electrolysis stacks. Pressurized operation is envisioned for large-scale hydrogen production plants, yielding higher overall efficiencies when the hydrogen product is to be delivered at elevated pressure for tank storage or pipelines. Pressurized operation also supports higher mass flow rates of the process gases with smaller components. The test stand can accommodate planar cells with dimensions up to 8.5 cm x 8.5 cm and stacks of up to 25 cells. It is also suitable for testing other cell and stack geometries including tubular cells. The pressure boundary for these tests is a water-cooled spool-piece pressure vessel designed for operation up to 5 MPa. Pressurized operation of a ten-cell internally manifolded solid oxide electrolysis stack has been successfully demonstrated up 1.5 MPa. The stack is internally manifolded and operates in cross-flow with an inverted-U flow pattern. Feed-throughs for gas inlets/outlets, power, and instrumentation are all located in the bottom flange. The entire spool piece, with the exception of the bottom flange, can be lifted to allow access to the internal furnace and test fixture. Lifting is accomplished with a motorized threaded drive mechanism attached to a rigid structural frame. Stack mechanical compression is accomplished using springs that are located inside of the pressure boundary, but outside of the hot zone. Initial stack heatup and performance characterization occurs at ambient pressure followed by lowering and sealing of the pressure vessel and subsequent pressurization. Pressure equalization between the anode and cathode sides of the cells and the stack surroundings is ensured by combining all of the process gases downstream of the stack. Steady pressure is maintained by means of a backpressure regulator and a digital pressure controller. A full description of the pressurized test apparatus is provided in this report. Results of initial testing showed the expected increase in open-cell voltage associated with elevated pressure. However, stack performance in terms of area-specific resistance was enhanced at elevated pressure due to better gas diffusion through the porous electrodes of the cells. Some issues such as cracked cells and seals were encountered during testing. Full resolution of these issues will require additional testing to identify the optimum test configurations and protocols.

J.E. O'Brien; X. Zhang; G.K. Housley; K. DeWall; L. Moore-McAteer

2012-09-01T23:59:59.000Z

234

Microdischarge-assisted ignition of dielectric-barrier high-pressure glow discharges  

E-Print Network [OSTI]

in the ignition of high-pressure arc lamps8 and volume dc discharges.6 Here, we employ a hybrid discharge source of uniform, nonequilibrium glow plasmas for a variety of applications at pressures of 100

Raja, Laxminarayan L.

235

An apparatus for studying scintillator properties at high isostatic pressures  

SciTech Connect (OSTI)

We describe the design and operation of a unique hydraulic press for the study of scintillator materials under isostatic pressure. This press, capable of developing a pressure of a gigapascal, consists of a large sample chamber pressurized by a two-stage hydraulic amplifier. The optical detection of the scintillation light emitted by the sample is performed, through a large aperture optical port, by a photodetector located outside the pressure vessel. In addition to providing essential pressure-dependent studies on the emission characteristics of radioluminescent materials, this apparatus is being developed to elucidate the mechanisms behind the recently observed dependency of light-yield nonproportionality on electronic band structure. The variation of the light output of a Tl:CsI crystal under 511-keV gamma excitation and hydrostatic pressure is given as an example.

Gaume, R. M. [College of Optics and Photonics (CREOL) and NanoScience Technology Center, University of Central Florida, Orlando, Florida 32816 (United States); Lam, S.; Gascon, M.; Feigelson, R. S. [Department of Materials Science and Engineering, Stanford University, Stanford, California 94305 (United States); Setyawan, W. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Curtarolo, S. [Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708 (United States)

2013-01-15T23:59:59.000Z

236

Plasma etching of cavities into diamond anvils for experiments at high pressures and high temperatures  

SciTech Connect (OSTI)

We describe a method for precisely etching small cavities into the culets of diamond anvils for the purpose of providing thermal insulation for samples in experiments at high pressures and high temperatures. The cavities were fabricated using highly directional oxygen plasma to reactively etch into the diamond surface. The lateral extent of the etch was precisely controlled to micron accuracy by etching the diamond through a lithographically fabricated tungsten mask. The performance of the etched cavities in high-temperature experiments in which the samples were either laser heated or electrically heated is discussed.

Weir, S.T.; Cynn, H.; Falabella, S.; Evans, W.J.; Aracne-Ruddle, C.; Farber, D.; Vohra, Y.K. (LLNL); (UAB)

2012-10-23T23:59:59.000Z

237

Instrumentation development for neutron scattering at high pressure.  

E-Print Network [OSTI]

??Neutron scattering at extremes of pressure is a powerful tool for studying the response of structural and magnetic properties of materials on microscopic level to… (more)

Fang, Junwei

2012-01-01T23:59:59.000Z

238

Experiment Hazard Class 5.3 High Pressure Vessels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stresses calculated using ASME Code Case 2286 July 17 1998. Verify that pressure relief devices have ASME "UV" certification or documentation of operability tests demonstrating...

239

High voltage ignition of high pressure microwave powered UV light sources  

SciTech Connect (OSTI)

Industrial microwave powered (electrodeless) light sources have been limited to quiescent pressures of {approximately}300 Torr of buffer gas and metal-halide fills. The predominant reason for such restrictions has been the inability to microwave ignite the plasma due to the collisionality of higher pressure fills and/or the electronegativity of halide bulb chemistries. Commercially interesting bulb fills require electric fields for ionization that are often large multiples of the breakdown voltage for air. Many auxiliary ignition methods are evaluated for efficiency and practicality before the choice of a high-voltage system with a retractable external electrode. The scheme utilizes a high voltage pulse power supply and a novel field emission source. Acting together they create localized condition of pressure reduction and high free electron density. This allows the normal microwave fields to drive this small region into avalanche, ignite the bulb, and heat the plasma to its operating point (T{sub e} {approx} 0.5 eV). This process is currently being used in a new generation of lamps, which are using multi-atmospheric excimer laser chemistries and pressure and constituent enhanced metal-halide systems. At the present time, production prototypes produce over 900 W of radiation in a 30 nm band, centered at 308 nm. Similarly, these prototypes when loaded with metal-halide bulb fills produce over 1 kW of radiation in 30 nm wide bands, centered about the wavelength of interest.

Frank, J.D.; Cekic, M.; Wood, C.H. [Fusion U.V. Curing Systems Corp., Gaithersburg, MD (United States)

1997-12-31T23:59:59.000Z

240

The effect of condensate dropout on pressure transient analysis of a high-pressure gas condensate well  

E-Print Network [OSTI]

'or the degree of MASTER OF SCIENCE August 1986 Major Subject : Petr oleum Engineering THE EFFECT OF CONDENSATE DROPOUT ON PRESSURE TRANSIENT ANALYSIS OF A HIGH-PRESSURE GAS CONDENSATE WELL A thesis by FREDERIC JEAN-LOUiS SRIENS Approved as to style... Condensate Well. (August 1986) Frederic Jean~Louis Briens, ingenieur Ecole Centrale Chairman of Advisory Committee: Dr. Ching H. Wu Pressure transient analysis techniques are often used to determine the i'low proper ties of gas wells. Through the analysis...

Briens, Frederic Jean-Louis

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Hydride vapor phase epitaxy and characterization of high-quality ScN epilayers  

SciTech Connect (OSTI)

The heteroepitaxial growth of ScN films was investigated on various substrates by hydride vapor phase epitaxy (HVPE). Single crystalline mirror-like ScN(100) and ScN(110) layers were successfully deposited on r- and m-plane sapphire substrates, respectively. Homogeneous stoichiometric films (N/Sc ratio 1.01?±?0.10) up to 40??m in thickness were deposited. Their mosaicity drastically improved with increasing the film thickness. The band gap was determined by optical methods to be 2.06?eV. Impurity concentrations including H, C, O, Si, and Cl were investigated through energy dispersive X-ray spectrometry and secondary ion mass spectrometry. As a result, it was found that the presence of impurities was efficiently suppressed in comparison with that of HVPE-grown ScN films reported in the past, which was possible thanks to the home-designed corrosion-free HVPE reactor. Room-temperature Hall measurements indicated that the residual free electron concentrations ranged between 10{sup 18}–10{sup 20}?cm{sup ?3}, which was markedly lower than the reported values. The carrier mobility increased monotonically with the decreasing in carrier concentration, achieving the largest value ever reported, 284?cm{sup 2}?V{sup ?1}?s{sup ?1} at n?=?3.7?×?10{sup 18}?cm{sup ?3}.

Oshima, Yuichi, E-mail: OSHIMA.Yuichi@nims.go.jp; Víllora, Encarnación G.; Shimamura, Kiyoshi [Environment and Energy Materials Research Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

2014-04-21T23:59:59.000Z

242

Flash High-Pressure Condensate to Regenerate Low-Pressure Steam  

SciTech Connect (OSTI)

This revised ITP tip sheet on regenerating low-pressure steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

243

Technical and economic evaluation of ten high temperature, high pressure particulate cleanup systems for pressurized fluidized bed combustion  

SciTech Connect (OSTI)

The objective of this analysis was to provide a technical and economic evaluation of the ten high temperature, high pressure (HTHP) systems for the purpose of prioritizing them according to performance, cost, and general viability of achieving commercial status. The scope primarily included reviewing/normalizing test experience to date, normalizing commercial designs, developing normalized capital and operating costs for each system, performing trade-off studies, and performing an evaluation utilizing in-house and outside inputs. The HTHP particulate cleanup system must be capable of the same stringent operating requirements as a conventional system, except it must do so at HTHP conditions. Utilities will demand nearly the same reliability as found in conventional equipment. Regarding particulate cleanup, the system must meet NSPS requirements at the stack, and also meet turbine inlet requirements. The ten devices evaluated were: Electrostatic Precipitator - Cottrell Environmental Sciences (CES); Ceramic Felt Filter - Acurex Corporation; Ceramic Cross Flow Filter - Westinghouse; Shallow Static Granular Bed Filter - Ducon/Westinghouse; Electrostatic Granular Bed Filter - General Electric (GE); Moving Granular Bed Filter - Combustion Power Company (CPC); Dry Plate Scrubber - Air Pollution Technology (APT); Magnetic Granular Bed Filter - Exxon; Electrocyclone - General Electric; and Acoustic Agglomerator - Aerojet/Pennsylvania State University (PSU). The test data for the ten devices were normalized to standard conditions with a reference inlet particle loading and size distribution. The purpose of system design normalization is to provide, for each of the HTHP concepts, a scaled-up commercial design which reflects a consistent design approach. 104 figures, 136 tables.

Rubow, L.N.; Borden, M.; Buchanan, T.L.; Cramp, J.A.C.; Fischer, W.H.; Klett, M.G.; Maruvada, S.M.; Nelson, E.T.; Weinstein, R.E.; Zaharchuk, R.

1984-07-01T23:59:59.000Z

244

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

Experiments have been developed for measuring the rates of chemical reactions liquids and in supercritical Co[sub 2]. A pulsed (Q-switch) Nd:YAG laser at 355 nm was the pump beam for laser flash photolysis studies of molybdenum and tungsten hexacarbonyls undergoing ligand displacement reactions by bidentate chelating agents such as 2,2[prime]-bipyridine in toluene. Experiments were carried out at 0.1 to 150 MPa. In the case of molybdenum complexes, the reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2[prime]-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Similar high pressure flash photolysis experiments with tungsten hexacarbonyl have also been completed. The concentration dependence of the fluorescence and nonradiative decay quantum yields for cresyl violet in several solvent have been reported as well as stability constants for the complexation of lithium ion by four different crown ethers dissolved in a room temperature molten salt.

Eyring, E.M.

1993-06-21T23:59:59.000Z

245

A Flow-Through High-Pressure Electrical Conductance Cell for Determining of Ion Association of Aqueous Electrolyte Solutions at High Temperature and Pressure  

SciTech Connect (OSTI)

A flow-through high-pressure electrical conductance cell was designed and constructed to measure limiting molar conductances and ion association constants of dilute aqueous solutions with high precision at high temperatures and pressures. The basic concept of the cell employs the principle developed at the University of Delaware in 1995, but overall targets higher temperatures (to 600 C) and pressures (to 300 MPa). At present the cell has been tested by measuring aqueous NaCl and LiOH solutions (10{sup {minus}3} to 10{sup {minus}5} mol.kg{sup {minus}1}) to 405 C and 33 MPa with good results.

Bianchi, H.; Ho, P.C.; Palmer, D.A.; Wood, R.H.

1999-09-12T23:59:59.000Z

246

High-pressure gasification of Montana subbituminous coal  

SciTech Connect (OSTI)

A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

Goyal, A.; Bryan, B.; Rehmat, A.

1991-01-01T23:59:59.000Z

247

Materials for High-Pressure Fuel Injection Systems  

SciTech Connect (OSTI)

The high-level goal of this multi-year effort was to facilitate the Advanced Combustion Engine goal of 20% improvement (compared to 2009 baseline) of commercial engine efficiency by 2015. A sub-goal is to increase the reliability of diesel fuel injectors by investigating modelbased scenarios that cannot be achieved by empirical, trial and error methodologies alone. During this three-year project, ORNL developed the methodology to evaluate origins and to record the initiation and propagation of fatigue cracks emanating from holes that were electrodischarge machined (EDM), the method used to form spray holes in fuel injector tips. Both x-ray and neutron-based methods for measuring residual stress at four different research facilities were evaluated to determine which, if any, was most applicable to the fuel injector tip geometry. Owing to the shape and small volumes of material involved in the sack area, residual stress data could only be obtained in the walls of the nozzle a few millimeters back from the tip, and there was a hint of only a small compressive stress. This result was consistent with prior studies by Caterpillar. Residual stress studies were suspended after the second year, reserving the possibility of pursuing this in the future, if and when methodology suitable for injector sacks becomes available. The smooth specimen fatigue behavior of current fuel injector steel materials was evaluated and displayed a dual mode initiation behavior. At high stresses, cracks started at machining flaws in the surface; however, below a critical threshold stress of approximately 800 MPa, cracks initiated in the bulk microstructure, below the surface. This suggests that for the next generation for high-pressure fuel injector nozzles, it becomes increasingly important to control the machining and finishing processes, especially if the stress in the tip approaches or exceeds that threshold level. Fatigue tests were also conducted using EDM notches in the gage sections. Compared to the smooth specimens, EDM notching led to a severe reduction in total fatigue life. A reduction in fatigue life of nearly four orders of magnitude can occur at an EDM notch the approximate size of fuel injector spray holes. Consequently, the initiation and propagation behavior of cracks from small spray holes is relevant for generation of design quality data for the next generation diesel fuel injection devices. This is especially true since the current design methodologies usually rely on the less conservative smooth specimen fatigue testing results, and since different materials can have varying levels of notch fatigue resistance.

Blau, P.; Shyam, A.; Hubbard, C.; Howe, J.; Trejo, R.; Yang, N. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center; Pollard, M. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center

2011-09-30T23:59:59.000Z

248

Structure and elasticity of serpentine at high-pressure Mainak Mookherjee a,  

E-Print Network [OSTI]

volcanoes, high electrical conductivities, magnetic and seismic anomalies. Using theoretical methods, we. Evidence of pressure- induced hydrogen bonding is absent in serpentine, as evident from reduction of O K is the bulk modulus, prime indicates pressure derivatives, and O refers to zero pressure. Our best

Stixrude, Lars

249

Effect of high-pressure on molecular magnetism   

E-Print Network [OSTI]

The effect of pressure on a number of magnetically interesting compounds such as single-molecule magnets and dimeric copper and manganese molecules has been investigated to probe the validity of ambient magneto-structural ...

Prescimone, Alessandro

2010-01-01T23:59:59.000Z

250

Instrumentation development for neutron scattering at high pressure   

E-Print Network [OSTI]

Neutron scattering at extremes of pressure is a powerful tool for studying the response of structural and magnetic properties of materials on microscopic level to applied stresses. However, experimental neutron studies ...

Fang, Junwei

2012-11-29T23:59:59.000Z

251

anultra high pressure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

c. Y Christian P Burger (i&Iember) Randall Getger ( Member) 5wc Fr. Walter F. Bradley (Head of Department) May 1991 ABSTRACT A Temperature Compensated Pressure Transducer for...

252

Modeling and simulation of a high pressure hydrogen storage tank with dynamic wall.  

E-Print Network [OSTI]

??Hydrogen storage is one of the divisions of hydrogen powered vehicles technology. To increase performances of high pressure hydrogen storage tanks, a multilayered design is… (more)

Cumalioglu, Ilgaz

2005-01-01T23:59:59.000Z

253

Modeling and simulation of a high pressure hydrogen storage tank with Dynamic Wall.  

E-Print Network [OSTI]

??Hydrogen storage is one of the divisions of hydrogen powered vehicles technology. To increase performances of high pressure hydrogen storage tanks, a multilayered design is… (more)

Cumalioglu, Ilgaz

2005-01-01T23:59:59.000Z

254

An in situ tensile test apparatus for polymers in high pressure hydrogen  

SciTech Connect (OSTI)

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.

Alvine, K. J., E-mail: kyle.alvine@pnnl.gov; Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)

2014-10-15T23:59:59.000Z

255

An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen  

SciTech Connect (OSTI)

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

2014-10-10T23:59:59.000Z

256

Split stream boilers for high-temperature/high-pressure topping steam turbine combined cycles  

SciTech Connect (OSTI)

Research and development work on high-temperature and high-pressure (up to 1,500 F TIT and 4,500 psia) topping steam turbines and associated steam generators for steam power plants as well as combined cycle plants is being carried forward by DOE, EPRI, and independent companies. Aeroderivative gas turbines and heavy-duty gas turbines both will require exhaust gas supplementary firing to achieve high throttle temperatures. This paper presents an analysis and examples of a split stream boiler arrangement for high-temperature and high-pressure topping steam turbine combined cycles. A portion of the gas turbine exhaust flow is run in parallel with a conventional heat recovery steam generator (HRSG). This side stream is supplementary fired opposed to the current practice of full exhaust flow firing. Chemical fuel gas recuperation can be incorporated in the side stream as an option. A significant combined cycle efficiency gain of 2 to 4 percentage points can be realized using this split stream approach. Calculations and graphs show how the DOE goal of 60 percent combined cycle efficiency burning natural gas fuel can be exceeded. The boiler concept is equally applicable to the integrated coal gas fuel combined cycle (IGCC).

Rice, I.G. [Rice (I.G.), Spring, TX (United States)

1997-04-01T23:59:59.000Z

257

Development of Designer Diamond Technology for High Pressure High Temperature Experiments in Support of Stockpile Stewardship Program  

SciTech Connect (OSTI)

The role of nitrogen in the fabrication of designer diamond was systematically investigated by adding controlled amount of nitrogen in hydrogen/methane/oxygen plasma. This has led to a successful recipe for reproducible fabrication of designer diamond anvils for high-pressure high-temperature research in support of stockpile stewardship program. In the three-year support period, several designer diamonds fabricated with this new growth chemistry were utilized in high-pressure experiments at UAB and Lawrence Livermore National Laboratory. The designer diamond anvils were utilized in high-pressure studies on heavy rare earth metals, high pressure melting studies on metals, and electrical resistance measurements on iron-based layered superconductors under high pressures. The growth chemistry developed under NNSA support can be adapted for commercial production of designer diamonds.

Vohra, Yogesh, K.

2009-10-28T23:59:59.000Z

258

High Pressure Neutron Powder Diffraction Study of Superhydrated Natrolite  

SciTech Connect (OSTI)

Neutron powder diffraction data were collected on a sample of natrolite and a 1:1 (v/v) mixture of perdeuterated methanol and water at a pressure of 1.87(11) GPa. The natrolite sample was superhydrated, with a water content double that observed at ambient pressure. All of the water deuterium atoms were located and the nature and extent of the hydrogen bonding elucidated for the first time. This has allowed the calculation of bond valence sums for the water oxygen atoms, and from this, it can be deduced that the key energetic factor leading to loss of the additional water molecule upon pressure release is the poor coordination to sodium cations within the pores.

Colligan,M.; Lee, Y.; Vogt, T.; Celestian, A.; Parise, J.; Marshall, W.; Hriljac, J.

2005-01-01T23:59:59.000Z

259

Constant pressure high throughput membrane permeation testing system  

DOE Patents [OSTI]

The disclosure relates to a membrane testing system for individual evaluation of a plurality of planar membranes subjected to a feed gas on one side and a sweep gas on a second side. The membrane testing system provides a pressurized flow of a feed and sweep gas to each membrane testing cell in a plurality of membrane testing cells while a stream of retentate gas from each membrane testing cell is ported by a retentate multiport valve for sampling or venting, and a stream of permeate gas from each membrane testing cell is ported by a permeate multiport valve for sampling or venting. Back pressure regulators and mass flow controllers act to maintain substantially equivalent gas pressures and flow rates on each side of the planar membrane throughout a sampling cycle. A digital controller may be utilized to position the retentate and permeate multiport valves cyclically, allowing for gas sampling of different membrane cells over an extended period of time.

Albenze, Erik J.; Hopkinson, David P.; Luebke, David R.

2014-09-02T23:59:59.000Z

260

High-temperature fiber optic cubic-zirconia pressure sensor - article no. 124402  

SciTech Connect (OSTI)

There is a critical need for pressure sensors that can operate reliably at high temperatures in many industrial segments such as in the combustion section of gas turbine engines for both transportation and power generation, coal gasifiers, coal fired boilers, etc. Optical-based sensors are particularly attractive for the measurement of a wide variety of physical and chemical parameters in high-temperature and high-pressure industrial environments due to their small size and immunity to electromagnetic interference. A fiber optic pressure sensor utilizing single-crystal cubic zirconia as the sensing element is reported. The pressure response of this sensor has been measured at temperatures up to 1000{sup o}C. Additional experimental results show that cubic zirconia could be used for pressure sensing at temperatures over 1000{sup o}C. This study demonstrates the feasibility of using a novel cubic-zirconia sensor for pressure measurement at high temperatures.

Peng, W.; Pickrell, G.R.; Wang, A.B. [Virginia Polytechnic Institute & State University, Blacksburg, VA (United States)

2005-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Engine with hydraulic fuel injection and ABS circuit using a single high pressure pump  

DOE Patents [OSTI]

An engine system comprises a hydraulically actuated fuel injection system and an ABS circuit connected via a fluid flow passage that provides hydraulic fluid to both the fuel injection system and to the ABS circuit. The hydraulically actuated system includes a high pressure pump. The fluid control passage is in fluid communication with an outlet from the high pressure pump.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2001-01-01T23:59:59.000Z

262

High explosives vapor detection by atmospheric sampling glow discharge ionization/tandem mass spectrometry  

SciTech Connect (OSTI)

The combination of atmospheric sampling glow discharge ionization with tandem mass spectrometry for the detection of traces of high explosives is described. Particular emphasis is placed on use of the quadrupole ion trap as the type of tandem mass spectrometer. Atmospheric sampling glow discharge provides a simple, rugged, and efficient means for anion formation while the quadrupole ion trap provides for efficient tandem mass spectrometry. Mass selective ion accumulation and non-specific ion activation methods can be used to overcome deleterious effects arising from ion/ion interactions. Such interactions constitute the major potential technical barrier to the use of the ion trap for real-time monitoring of targeted compounds in uncontrolled and highly variable matrices. Tailored waveforms can be used to effect both mass selective ion accumulation and ion activation. Concatenated tailored waveforms allow for both functions in a single experiment thereby providing the capability for monitoring several targeted species simultaneously. The combination of atmospheric sampling glow discharge ionization with a state-of-the-art analytical quadrupole ion trap is a highly sensitive and specific detector for traces of high explosives. The combination is also small and inexpensive relative to virtually any other form of tandem mass spectrometry. The science and technology underlying the glow discharge/ion trap combination is sufficiently mature to form the basis for an engineering effort to make the detector portable. 85 refs.

McLuckey, S.A.; Goeringer, D.E.; Asano, K.G. [Oak Ridge National Lab., TN (United States). Chemical and Analytical Sciences Div.

1996-02-01T23:59:59.000Z

263

Instrumentation development for magneto-transport and neutron scattering measurements at high pressure and low temperature   

E-Print Network [OSTI]

High pressure, high magnetic field and low temperature techniques are required to investigate magnetic transitions and quantum critical behaviour in different ferromagnetic materials to elucidate how novel forms of ...

Wang, Weiwei

2013-07-01T23:59:59.000Z

264

High-temperature, high-pressure bonding of nested tubular metallic components  

DOE Patents [OSTI]

This invention is a tool for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

Quinby, Thomas C. (Kingston, TN)

1980-01-01T23:59:59.000Z

265

An Innovative High-Temperature High-Pressure Measurement While Drilling (MWD) Tool  

SciTech Connect (OSTI)

Measurement while drilling (MWD) tools specified to 150 C (302 F) that provide wellbore surveys, real-time inclination, and natural gamma ray detection are a commodity item in the oilfield services industry. MWD tools specified to 175 C (347 F) that routinely demonstrate highly reliable operation are available from only a few service companies. Commercial MWD tools that reliably operate to 200 C (392 F) for extended periods of time and offer features like real-time gamma ray, retrievability, and reseatability are nonexistent. Need for these higher temperature tools will increase as wells become hotter in the search for new oil and gas resources. The goal of this project was to design a retrievable and reseatable high-pressure/high-temperature MWD tool with real-time continuous inclination, vibration detection, annular pressure, and gamma ray detection. This report describes the development of such a tool from concept, through feasibility, and into field testing and preliminary development planning. It describes the challenges encountered in the design of the tool, along with testing results and decisions about the commercial viability of the tool in the configuration in which it was developed. The decision was made not to commercialize the tool developed under this project because of a combination of battery technology problems and modulation power consumption at the required depths.

Brian Boling

2007-06-01T23:59:59.000Z

266

Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels  

SciTech Connect (OSTI)

Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

Gardiner, D.; Bardon, M.; Pucher, G.

2008-10-01T23:59:59.000Z

267

Speed of sound in liquids at high pressure  

E-Print Network [OSTI]

In this paper, a new general formula for the sound speed in adiabatic conditions ( S = const ) has been established. The sound speed depends on the mass density {\\rho} (p,T ) and the internal energy per unit mass E(p,T ), both expressed as functions of the pressure p and the temperature T . This formula has been compared with experimental data on the example of triolein over the pressure range up to 450 MPa. For experimental data, phenomenological approximate formulas have been proposed. Those formulas have two versions, depending on the 2 and 3 parameters. Both versions have been developed with the help of the new expression (Eq.8) for the sound speed. The explicit form of both approximate curves can be regarded as the result of purely phenomenological modeling. However, in this paper, these new analytical expressions have been obtained by applying the heuristic procedure described in Appendix.

P., Kielczynski; S, Piekarski

2013-01-01T23:59:59.000Z

268

Solid Nitrogen at Extreme Conditions of High Pressure and Temperature  

SciTech Connect (OSTI)

We review the phase diagram of nitrogen in a wide pressure and temperature range. Recent optical and x-ray diffraction studies at pressures up to 300 GPa and temperatures in excess of 1000 K have provided a wealth of information on the transformation of molecular nitrogen to a nonmolecular (polymeric) semiconducting and two new molecular phases. These newly found phases have very large stability (metastability) range. Moreover, two new molecular phases have considerably different orientational order from the previously known phases. In the iota phase (unlike most of other known molecular phases), N{sub 2} molecules are orientationally equivalent. The nitrogen molecules in the theta phase might be associated into larger aggregates, which is in line with theoretical predictions on polyatomic nitrogen.

Goncharov, A; Gregoryanz, E

2004-04-05T23:59:59.000Z

269

Electron Matter Wave Interferences at High Vacuum Pressures  

E-Print Network [OSTI]

The ability to trap and guide coherent electrons is gaining importance in fundamental as well as in applied physics. In this regard novel quantum devices are currently developed that may operate under low vacuum conditions. Here we study the loss of electron coherence with increasing background gas pressure. Thereby optionally helium, hydrogen or nitrogen is introduced in a biprism interferometer where the interference contrast is a measure for the coherence of the electrons. The results indicate a constant contrast that is not decreasing in the examined pressure range between $10^{-9}$ mbar and $10^{-4}$ mbar. Therefore no decoherence was observed even under poor vacuum conditions. Due to scattering of the electron beam with background H$_2$-molecules a signal loss of 94 % was determined. The results may lower the vacuum requirements for novel quantum devices with free coherent electrons.

Schütz, Georg; Pooch, Andreas; Stibor, Alexander

2015-01-01T23:59:59.000Z

270

High-Pressure Tube Trailers and Tanks | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGHBraytonMaterials forPressure

271

Heat transfer and pressure drop data for high heat flux densities to water at high subcritical pressures  

E-Print Network [OSTI]

Local surface ooeffioients of heat t-ansfer, overall pressure drop data and mean friction factor are presented for heat flamms up to 3.52106 BtuAr ft2 for water flowing in a nickel tabe isder the following conditions: mass ...

Rohsenow, Warren M.

1951-01-01T23:59:59.000Z

272

Overview of Hanford Site High-Level Waste Tank Gas and Vapor Dynamics  

SciTech Connect (OSTI)

Hanford Site processes associated with the chemical separation of plutonium from uranium and other fission products produced a variety of volatile, semivolatile, and nonvolatile organic and inorganic waste chemicals that were sent to high-level waste tanks. These chemicals have undergone and continue to undergo radiolytic and thermal reactions in the tanks to produce a wide variety of degradation reaction products. The origins of the organic wastes, the chemical reactions they undergo, and their reaction products have recently been examined by Stock (2004). Stock gives particular attention to explaining the presence of various types of volatile and semivolatile organic species identified in headspace air samples. This report complements the Stock report by examining the storage of volatile and semivolatile species in the waste, their transport through any overburden of waste to the tank headspaces, the physical phenomena affecting their concentrations in the headspaces, and their eventual release into the atmosphere above the tanks.

Huckaby, James L.; Mahoney, Lenna A.; Droppo, James G.; Meacham, Joseph E.

2004-08-31T23:59:59.000Z

273

Vapor pressures of mixtures of CFC-114 with the potential replacement coolants C{sub 4}F{sub 10} and c-C{sub 4}F{sub 8}  

SciTech Connect (OSTI)

The U.S. Enrichment Corporation`s production of isotopically enriched uranium depends solely on two plants which utilize the gaseous diffusion process. This process uses large quantities of CFC-114 as an evaporative coolant. CFC-114, however, will be phased out of production at the end of 1995 due to its potential to deplete stratospheric ozone. A search has been underway for substitutes for a number of years. The initial search (1988-89) for an ozone-friendly, commercially available, chemically compatible substitute yielded two candidates, FC-c318 (c-C{sub 4}F{sub 8}) and FC-3110 (C{sub 4}F{sub 10}). The intended mode of replacing coolant was to stage the new coolant into independent subsystems of the plants, so that some systems would continue to operate on CFC-114, and an increasing number would operate on the new coolant. During that changeover process, the possibility of coolant mixing arises in variety of scenarios. This work was intended to generate sufficient experimental information to be able to predict the vapor pressure of coolant mixtures over the range of operating conditions likely to be found in the diffusion plants. Specifically, vapor pressures were measured over the temperature range 322 to 355 K (120{degrees}F to 180{degrees}F) and over the full range of mole fractions for binary mixtures of CFC-114 with FC-3110, and of CFC-114 with FC-c318.

Trowbridge, L.D. [Oak Ridge K-25 Site, TN (United States); Otey, M.G. [Paducah Gaseous Diffusion Plant, KY (United States)

1994-09-01T23:59:59.000Z

274

Development of a High-Pressure/High-Temperature Downhole Turbine Generator  

SciTech Connect (OSTI)

The objective of this project as originally outlined has been to achieve a viable downhole direct current (DC) power source for extreme high pressure, high temperature (HPHT) environments of >25,000 psi and >250 C. The Phase I investigation posed and answered specific questions about the power requirements, mode of delivery and form factor the industry would like to see for downhole turbine generator tool for the HPHT environment, and noted specific components, materials and design features of that commercial system that will require upgrading to meet the HPHT project goals. During the course of Phase I investigation the scope of the project was HPHT downhole DC power. Phase I also investigated the viability of modifying a commercial expanded, without additional cost expected to the project, to include the addition of HT batteries to the power supply platform.

Timothy F. Price

2007-02-01T23:59:59.000Z

275

High pressure testing of see-through labyrinth seals  

E-Print Network [OSTI]

of labyrinth tooth Impedance Inches of water [UT'] [L) [L) [FT/L] [FT/L] [FT/L] [FT/L] [L] [L] [F] [F] [UT ] [L] [F/L] [L] K;; m, N NT pe PR PS R Direct stiffness Cross-coupled stiffness Stiffness Coefficient Seal Length Stator... the exit-labyrinth seals. Section A-A in Figure 4 gives the location of swirl brakes. Btmor Inlet Annulus Back Pr'asnua Anfsrlur Shaker Btmgars (2 (9 90 ) Thmmomuple Pressure Traraduccfs (2 e sf ) et Prrmnlrf Btrg Pmmum Therm ocormles Transducers...

Picardo, Arthur Michael

2003-01-01T23:59:59.000Z

276

High-Pressure Hydrogen Tanks | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGHBraytonMaterials forPressure Hydrogen

277

Lithium pellet injection into high pressure magnetically confined plasmas  

E-Print Network [OSTI]

The ablation of solid pellets injected into high temperature magnetically confined plasmas is characterized by rapid oscillations in the ablation rate, and the formation of field aligned filaments in the ablatant. High ...

Böse, Brock (Brock Darrel)

2010-01-01T23:59:59.000Z

278

Electrolyte vapor condenser  

DOE Patents [OSTI]

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

1983-02-08T23:59:59.000Z

279

Electrolyte vapor condenser  

DOE Patents [OSTI]

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

Sederquist, Richard A. (Newington, CT); Szydlowski, Donald F. (East Hartford, CT); Sawyer, Richard D. (Canton, CT)

1983-01-01T23:59:59.000Z

280

Development test report for the high pressure water jet system nozzles  

SciTech Connect (OSTI)

The high pressure water jet nozzle tests were conducted to identify optimum water pressure, water flow rate, nozzle orifice size and fixture configuration needed to effectively decontaminate empty fuel storage canisters in KE-Basin. This report gives the tests results and recommendations from the these tests.

Takasumi, D.S.

1995-09-28T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Alternated high-and low-pressure nitriding of austenitic stainless steel: Mechanisms and results  

E-Print Network [OSTI]

Alternated high- and low-pressure nitriding of austenitic stainless steel: Mechanisms and results G a gas mixture of (N2 /H2):(50/50) in pressure, was applied to stainless-steel AISI 304. In the first or plasma nitriding of metal parts, in par- ticular those made of steel and cast iron, is extensively ap

282

Persistent global proton aurora caused by high solar wind dynamic pressure  

E-Print Network [OSTI]

Persistent global proton aurora caused by high solar wind dynamic pressure K. M. Laundal1 and N] Global images of the proton aurora taken with the SI-12 camera onboard the IMAGE satellite reveal a very direct relationship between the solar wind dynamic pressure and the intensity of the global proton aurora

Bergen, Universitetet i

283

Fermi Surface of Uranium at Ambient Pressure Gregory S. Boebinger, National High Magnetic Field Laboratory  

E-Print Network [OSTI]

Fermi Surface of ­Uranium at Ambient Pressure Gregory S. Boebinger, National High Magnetic Field Laboratory DMR-Award 0654118 DC Field Facility User Program The fermi surface of ­Uranium has been measured surface of alpha-uranium at ambient pressure, Phys. Rev. B Rapid Commun., 80, 241101 (2009). B//c-axis B

Weston, Ken

284

Fractal characterisation of high-pressure and hydrogen-enriched CH4air turbulent premixed flames  

E-Print Network [OSTI]

Fractal characterisation of high-pressure and hydrogen-enriched CH4­air turbulent premixed flames measurements were performed to obtain the flame front images, which were further analyzed for fractal of the flame front curvature as a function of the pressure. Fractal dimension showed a strong dependence

Gülder, �mer L.

285

SOLAR RADIATION PRESSURE EFFECTS ON VERY HIGH-ECCENTRIC FORMATION J. Fontdecaba Baig1  

E-Print Network [OSTI]

SOLAR RADIATION PRESSURE EFFECTS ON VERY HIGH-ECCENTRIC FORMATION FLYING J. Fontdecaba Baig1 , G. M this particular relative motion is the scoop of this paper. Main perturbation in HEO orbits are solar radiation. Key words: formation flying, HEO orbits, solar radiation pressure. 1. INTRODUCTION Formation flying

Paris-Sud XI, Université de

286

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH  

E-Print Network [OSTI]

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

Stixrude, Lars

287

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

A laser flash photolysis kinetic study of 2,2{prime}-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO{sub 4} have also been investigated.

Eyring, E.M.

1992-09-22T23:59:59.000Z

288

APPLICATION OF CERAMICS TO HIGH PRESSURE FUEL SYSTEMS  

SciTech Connect (OSTI)

Diesel fuel systems are facing increased demands as engines with reduced emissions are developed. Injection pressures have increased to provide finer atomization of fuel for more efficient combustion, Figure 1. This increases the mechanical loads on the system and requires tighter clearances between plungers and bores to prevent leakage. At the same time, fuel lubricity has decreased as a byproduct of reducing the sulfur levels in fuel. Contamination of fuel by water and debris is an ever-present problem. For oil-lubricated fuel system components, increased soot loading in the oil results in increased wear rates. Additionally, engine manufacturers are lengthening warranty periods for engines and systems. This combination of factors requires the development of new materials to counteract the harsher tribological environment.

Mandler, Jr., William F.

2000-08-20T23:59:59.000Z

289

Integrated-fin gasket for palm cubic-anvil high pressure apparatus  

SciTech Connect (OSTI)

We described an integrated-fin gasket technique for the palm cubic-anvil apparatus specialized for the high-pressure and low-temperature measurements. By using such a gasket made from the semi-sintered MgO ceramics and the tungsten-carbide anvils of 2.5 mm square top, we successfully generate pressures over 16 GPa at both room and cryogenic temperatures down to 0.5 K. We observed a pressure self-increment for this specific configuration and further characterized the thermally induced pressure variation by monitoring the antiferromagnetic transition temperature of chromium up to 12 GPa. In addition to enlarge the pressure capacity, such a modified gasket also improves greatly the surviving rate of electrical leads hanging the sample inside a Teflon capsule filled with the liquid pressure-transmitting medium. These improvements should be attributed to the reduced extrusion of gasket materials during the initial compression.

Cheng, J.-G. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Matsubayashi, K.; Nagasaki, S.; Hisada, A.; Hirayama, T.; Uwatoko, Y. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Hedo, M. [Faculty of Science, University of Ryukyus, Senbaru, Nishihara, Okinawa 903-0213 (Japan); Kagi, H. [Graduate School of Science, University of Tokyo, 7-3-1, Hongo Bunkyo-Ku, Tokyo 113-0033 (Japan)

2014-09-15T23:59:59.000Z

290

Vapor-liquid equilibrium of water-acetone-air at ambient temperatures and pressures. An analysis of different VLE-fitting methods  

SciTech Connect (OSTI)

The availability of accurate equilibrium data is of high importance in chemical engineering practice both for design and research purposes. It appeared that for the gas absorption system water-acetone-air in the range of special interest for absorption and desorption operations, neither literature data nor calculations following UNIFAC gave a sufficient accuracy. An experimental program was set up to determine equilibrium data with an accuracy within 2% for low acetone concentrations (up to 7 wt % gas phase) at ambient temperature (16-30/sup 0/C) and atmospheric pressure (740-860 mmHg). From experiments the activity coefficient at infinite dilution of acetone ..gamma.. is found to be 6.79 (0.01) at 20/sup 0/C and 7.28 (0.01) at 25/sup 0/C, while the total error in ..gamma.. is 1.5%. The equilibrium constant can be calculated from ..gamma.. and shows the same error. The experimental data-fitting with procedures of Margules (two parameters) and Van Laar were successful, but NRTL, Wilson, and UNIQUAC failed, probably because of the small concentration range used.

Lichtenbelt, J.H.; Schram, B.J.

1985-04-01T23:59:59.000Z

291

Robofurnace: A semi-automated laboratory chemical vapor deposition system for high-throughput nanomaterial synthesis and process discovery  

SciTech Connect (OSTI)

Laboratory research and development on new materials, such as nanostructured thin films, often utilizes manual equipment such as tube furnaces due to its relatively low cost and ease of setup. However, these systems can be prone to inconsistent outcomes due to variations in standard operating procedures and limitations in performance such as heating and cooling rates restrict the parameter space that can be explored. Perhaps more importantly, maximization of research throughput and the successful and efficient translation of materials processing knowledge to production-scale systems, relies on the attainment of consistent outcomes. In response to this need, we present a semi-automated lab-scale chemical vapor deposition (CVD) furnace system, called “Robofurnace.” Robofurnace is an automated CVD system built around a standard tube furnace, which automates sample insertion and removal and uses motion of the furnace to achieve rapid heating and cooling. The system has a 10-sample magazine and motorized transfer arm, which isolates the samples from the lab atmosphere and enables highly repeatable placement of the sample within the tube. The system is designed to enable continuous operation of the CVD reactor, with asynchronous loading/unloading of samples. To demonstrate its performance, Robofurnace is used to develop a rapid CVD recipe for carbon nanotube (CNT) forest growth, achieving a 10-fold improvement in CNT forest mass density compared to a benchmark recipe using a manual tube furnace. In the long run, multiple systems like Robofurnace may be linked to share data among laboratories by methods such as Twitter. Our hope is Robofurnace and like automation will enable machine learning to optimize and discover relationships in complex material synthesis processes.

Oliver, C. Ryan; Westrick, William; Koehler, Jeremy; Brieland-Shoultz, Anna; Anagnostopoulos-Politis, Ilias; Cruz-Gonzalez, Tizoc [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States)] [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Hart, A. John, E-mail: ajhart@mit.edu [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2013-11-15T23:59:59.000Z

292

High-pressure cell for neutron reflectometry of supercritical and subcritical fluids at solid interfaces  

SciTech Connect (OSTI)

A new high-pressure cell design for use in neutron reflectometry (NR) for pressures up to 50 MPa and a temperature range of 300 473 K is described. The cell design guides the neutron beam through the working crystal without passing through additional windows or the bulk fluid, which provides for a high neutron transmission, low scattering background, and low beam distortion. The o-ring seal is suitable for a wide range of subcritical and supercritical fluids and ensures high chemical and pressure stability. Wafers with a diameter of 5.08 cm (2 in.) and 5 mm or 10 mm thickness can be used with the cells, depending on the required pressure and momentum transfer range. The fluid volume in the sample cell is very small at about 0.1 ml, which minimizes scattering background and stored energy. The cell design and pressure setup for measurements with supercritical fluids are described. NR data are shown for silicon/silicon oxide and quartz wafers measured against air and subsequently within the high-pressure cell to demonstrate the neutron characteristics of the high-pressure cell. Neutron reflectivity data for supercritical CO2 in contact with quartz and Si/SiO2 wafers are also shown.

Carmichael, Justin R [ORNL; Rother, Gernot [ORNL; Browning, Jim [ORNL; Ankner, John Francis [ORNL; Banuelos, Jose Leo [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Wesolowski, David J [ORNL; Cole, David [Ohio State University

2012-01-01T23:59:59.000Z

293

Radiochemical Transformation of High Pressure Methane under Gamma, Electron, and Neutron Irradiation  

E-Print Network [OSTI]

The chemical effects of irradiation on high pressure methane and noble gas mixtures were investigated using gamma, electron beam, and neutron irradiation sources. The gamma source used was the La-140 source from the Nuclear Science Center (NSC...

Clemens, Jeffrey Tyler

2014-05-01T23:59:59.000Z

294

Design strategies for optimizing high burnup fuel in pressurized water reactors  

E-Print Network [OSTI]

This work is focused on the strategy for utilizing high-burnup fuel in pressurized water reactors (PWR) with special emphasis on the full array of neutronic considerations. The historical increase in batch-averaged discharge ...

Xu, Zhiwen, 1975-

2003-01-01T23:59:59.000Z

295

Microplasma Discharges in High Pressure Gases Scaling Towards the Sub-micron Regime  

E-Print Network [OSTI]

Atmospheric pressure microplasmas are uniquely characterized by their very high energy densities and also by their small discharge sizes. These properties allow for unique applications in plasma processing technologies. We have investigated...

Chitre, Aditya Rajeev

2012-02-14T23:59:59.000Z

296

Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators  

SciTech Connect (OSTI)

This revised ITP tip sheet on installing high-pressure boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

297

Innovative fuel designs for high power density pressurized water reactor  

E-Print Network [OSTI]

One of the ways to lower the cost of nuclear energy is to increase the power density of the reactor core. Features of fuel design that enhance the potential for high power density are derived based on characteristics of ...

Feng, Dandong, Ph. D. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

298

High Pressure PEM Electrolysis: Status, Key Issues, and Challenges  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE and SUSTAINABLEIssuesHigh

299

Design of high pressure metering and regulating stations  

SciTech Connect (OSTI)

Metering and regulating stations effectively serve as the cash registers of the natural gas industry. While the potential for lost revenue resulting from improper design is a serious consideration, it is not the only one. The potential exists for problems such as excessive noise levels, inaccurate reflection of lost and unaccounted-for gas, and numerous potentially hazardous situations. The best time to limit the potential for problems is during the design process. This, together with the critical nature of these stations, dictates that proper design is imperative. Proper design of metering and regulating stations is a constantly changing and extremely complicated subject. There are virtually an infinite number of situations that the designer can encounter in evaluating his design. In view of this, it is impossible to develop a cookbook method of designing these stations that covers all possible situations. The emphasis of this paper is to briefly touch on the major aspects of metering and regulating station design. Steps involved in station design are: 1. Collection of data on the proposed station. 2. Determination of piping configuration. 3. Selection of measurement equipment. 4. Selection of pressure regulating and overpressure protection equipment. 5. Communication of the final design to field personnel.

Rehler, D.A. [Oklahoma Natural Gas Co., Enid, OK (United States)

1995-12-01T23:59:59.000Z

300

Vehicle having hydraulic and power steering systems using a single high pressure pump  

DOE Patents [OSTI]

A vehicle comprises a plurality of wheels attached to a vehicle housing. Also attached to the vehicle housing is a power steering system, including a fluid flow circuit, which is operably coupled to a number of the wheels. An internal combustion engine attached to the vehicle housing is connected to a hydraulically actuated system that includes a high pressure pump. An outlet of the high pressure pump is in fluid communication with the fluid flow circuit.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2001-06-22T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

DEVELOPMENT OF ASME SECTION X CODE RULES FOR HIGH PRESSURE COMPOSITE HYDROGEN PRESSURE VESSELS WITH NON-LOAD SHARING LINERS  

SciTech Connect (OSTI)

The Boiler and Pressure Vessel Project Team on Hydrogen Tanks was formed in 2004 to develop Code rules to address the various needs that had been identified for the design and construction of up to 15000 psi hydrogen storage vessel. One of these needs was the development of Code rules for high pressure composite vessels with non-load sharing liners for stationary applications. In 2009, ASME approved new Appendix 8, for Section X Code which contains the rules for these vessels. These vessels are designated as Class III vessels with design pressure ranging from 20.7 MPa (3,000 ps)i to 103.4 MPa (15,000 psi) and maximum allowable outside liner diameter of 2.54 m (100 inches). The maximum design life of these vessels is limited to 20 years. Design, fabrication, and examination requirements have been specified, included Acoustic Emission testing at time of manufacture. The Code rules include the design qualification testing of prototype vessels. Qualification includes proof, expansion, burst, cyclic fatigue, creep, flaw, permeability, torque, penetration, and environmental testing.

Rawls, G.; Newhouse, N.; Rana, M.; Shelley, B.; Gorman, M.

2010-04-13T23:59:59.000Z

302

High Temperature and Pressure reactive flows through porous media.  

E-Print Network [OSTI]

of Ceramic Matrix Composite (CMC), used as high temperature material for combustion chamber or stagnation and chemical composition (Gas Chromatograph, Mass Spectrometer, Infra-Red spectrometer) in stationary and transient conditions. The tests on metallic and composite samples have been conducted with N2, CH4, H2+CH4

Boyer, Edmond

303

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures  

SciTech Connect (OSTI)

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalization in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K. [Physics, University of Alabama at Birmingham (UAB), 310 Campbell Hall, 1300 University Boulevard, Birmingham, AL, 35294-1170 (United States); Hope, Kevin M. [Biology, Chemistry, and Mathematics, University of Montevallo, Harman Hall, Station 6480, Montevallo, AL, 35115 (United States)

2008-07-01T23:59:59.000Z

304

THE PLASMA WINDOW: A WINDOWLESS HIGH PRESSURE VACUUM INTERFACE FOR VARIOUS ACCELERATOR APPLICATIONS.  

SciTech Connect (OSTI)

The Plasma Window is a stabilized plasma arc used as an interface between accelerator vacuum and pressurized targets. There is no solid material introduced into the beam and thus it is also capable of transmitting particle beams and electromagnetic radiation with low loss and of sustaining high beam currents without damage. Measurements on a prototype system with a 3 mm diameter opening have shown that pressure differences of more than 2.5 atmospheres can be sustained with an input pressure of {approx} 10{sup -6} Torr. The system is capable of scaling to higher-pressure differences and larger apertures. Various plasma window applications for synchrotron light sources, high power lasers, internal targets, high current accelerators such as the HAWK, ATW, APT, DARHT, spallation sources, as well as for a number of commercial applications, will be discussed.

HERSHCOVITCH,A.I.; JOHNSON,E.D.; LANZA,R.C.

1999-03-29T23:59:59.000Z

305

Predictive modeling and high-pressure-high-temperature synthesis of perovskites containing monovalent silver  

SciTech Connect (OSTI)

The program POTATO, which was developed to model distorted perovskite structures, has been used to assess the stability of hypothetical compositions and guide the synthesis of new materials at high pressures and high temperatures. The initial result of this effort is the synthesis of two new perovskites, Ca{sub 2}NdAgTi{sub 4}O{sub 12} and NdAgTi{sub 2}O{sub 6}, which were synthesized at 14--14.5 GPa and 1000 C using the uniaxial split sphere anvil type press (USSA-2000). Both compounds are perovskites distorted from the ideal cubic structure by octahedral tilting distortions. Ca{sub 2}NdAgTi{sub 4}O{sub 12} contains a random distribution of Ca{sup 2+}/Nd{sup 3+}/Ag{sup +} ions on the A-site, whereas NdAgTi{sub 2}O{sub 6} has a partially ordered distribution of Nd{sup 3+}/Ag{sup +} ions. Ca{sub 2}NdAgTi{sub 4}O{sub 12} adopts the GdFeO{sub 3} structure. NdAgTi{sub 2}O{sub 6} belongs to the tetragonal space group P4/nbm. This structure can be derived from the simple cubic perovskite structure by rotations of the octahedra about the c-axis and partial ordering of Nd{sup 3+} and Ag{sup +} ions into alternating layers, perpendicular to the c-axis.

Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Woodward, P.M. [Brookhaven National Lab., Upton, NY (United States). Physics Dept.] [Brookhaven National Lab., Upton, NY (United States). Physics Dept.

1998-10-01T23:59:59.000Z

306

Behavior of a hollow core photonic crystal fiber under high radial pressure for downhole application  

SciTech Connect (OSTI)

Pressure fiber sensors play an important role in downhole high pressure measurements to withstand long term operation. The purpose of this paper is to present an application of hollow core photonic crystal fiber (HC-PCF) as a high pressure sensor head for downhole application based on dispersion variation. We used a high pressure stainless steel unit to exert pressure on the sensor. The experimental results show that different wavelengths based on sagnac loop interferometer have additive sensitivities from 5?×?10{sup ?5}?nm/psi at 1480?nm to 1.3?×?10{sup ?3}?nm/psi at 1680?nm. We developed a simulation to understand the reason for difference in sensitivity of wavelengths and also the relationship between deformation of HC-PCF and dispersion variation under pressure. For this purpose, by using the finite element method, we investigated the effect of structural variation of HC-PCF on spectral transformation of two linear polarizations under 1000?psi pressure. The simulation and experimental results show exponential decay behavior of dispersion variation from ?3.4?×?10{sup ?6} 1/psi to ?1.3?×?10{sup ?6} 1/psi and from ?5?×?10{sup ?6} 1/psi to ?1.8?×?10{sup ?6} 1/psi, respectively, which were in a good accordance with each other.

Sadeghi, J., E-mail: j-sadeghi@sbu.ac.ir; Chenari, Z.; Ziaee, F. [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Latifi, H., E-mail: latifi@sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Department of Physics, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Santos, J. L., E-mail: josantos@fc.up.pt [INESC Porto—Instituto de Engenharia de Sistemas e Computadores do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Departamento de Física, da Faculdade de Ciências, da Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

2014-02-17T23:59:59.000Z

307

Compensator Control For Chemical Vapor Deposition Film Growth Using Reduced Order Design Models  

E-Print Network [OSTI]

in a high pressure chemical vapor deposition (HPCVD) reactor that in­ cludes multiple species and controls optoelectronic integrated circuits. This can sometimes be addressed, in part, through open­loop optimization [7 reactor with real­time sensing and control as an innovative feature of this proto­ type reactor. Previous

308

Working with SRNL - Our Facilities- High Pressure Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and MaterialsWenjun1 Table 1.14Working WithGloveboxMetalGammaHigh

309

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame and

310

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame

311

Progress Report for UNLV High Pressure Science and Engineering Center  

SciTech Connect (OSTI)

In this report we present results of an in-depth analysis of the SP error densities for 29 satellites. These satellites were divided into three groups--Low Earth Orbit (LEO), Near Circular Orbit (NCO) and Highly Eccentric Orbit (HEO). Included in the first group were those satellites with eccentricities of less than 0.2 and perigees below 450km. The second group included satellites in near circular orbits (eccentricities of less than 0.015) and perigees from 700km to 1500km. The third group consisted of those satellites that were in highly eccentric orbits, namely those with eccentricities greater than 0.2. These satellites have perigees far into the thermosphere. Table 1 contains a summary of the orbit characteristics for the 29 satellites. In our study we attempted to unravel and elucidate the networks of relationships above. The satellite groupings and the report are organized in a way that reflects these efforts. We begin in Section 2 with a summary of the methods used in our analysis. One objective in this study was to establish a baseline for future work in satellite orbit propagators. Section 2 contains descriptions of the SP, truth orbits, and the satellite observation data used to establish this baseline. In the report we show how satellite error densities evolve in time up to thirty-six hours. We present error profiles, error histograms, rms errors and 95/9970 confidence limits for the along-track cross-track, and radial axes of motion for satellites in each of the three groupings. We present results of a regression analysis that establishes a physical model of the error densities. We also link the errors in the various regimes to the quality and quantity of the observational data.

Mailhiot, C.; Pepper, D.; Lindle, D.; Nicol, M.

1998-11-20T23:59:59.000Z

312

The Progress on Low-Cost, High-Quality, High-Temperature Superconducting Tapes Deposited by the Combustion Chemical Vapor Deposition Process  

SciTech Connect (OSTI)

The innovative Combustion Chemical Vapor Deposition (CCVD) process is a non-vacuum technique that is being investigated to enable next generation products in several application areas including high-temperature superconductors (HTS). In combination with the Rolling Assisted Biaxially Textured Substrate (RABiTS) technology, the CCVD process has significant promise to provide low-cost, high-quality lengths of YBCO coated conductor. Over 100 meter lengths of both Ni and Ni-W (3 at. Wt.%) substrates with a surface roughness of 12-18 nm were produced. The CCVD technology has been used to deposit both buffer layer coatings as well as YBCO superconducting layers. Buffer layer architecture of strontium titanate (SrTiO{sub 3}) and ceria (CeO{sub 2}) have been deposited by CCVD on textured nickel substrates and optimized to appropriate thicknesses and microstructures to provide templates for growing PLD YBCO with a J{sub c} of 1.1 MA/cm{sup 2} at 77 K and self-field. The CCVD buffer layers have been scaled to meter plus lengths with good epitaxial uniformity along the length. A short sample cut from one of the lengths enabled high critical current density PLD YBCO. Films of CCVD YBCO superconductors have been grown on single crystal substrates with critical current densities over 1 MA/cm{sup 2}. In addition, superconducting YBCO films with an I{sub c} of 60 A/cm-width (J{sub c} = 1.5 MA/cm{sup 2}) were grown on ORNL RABiTS (CeO{sub 2}/YSZ/Y{sub 2}O{sub 3}/Ni/Ni-3W) using CCVD process.

Shoup, S.S.; White, M.K.; Krebs, S.L.; Darnell, N.; King, A.C.; Mattox, D.S.; Campbell, I.H.; Marken, K.R.; Hong, S.; Czabaj, B.; Paranthaman, M.; Christen, H.M.; Zhai, H.-Y. Specht, E.

2008-06-24T23:59:59.000Z

313

An RF-only ion-funnel for extraction from high-pressure gases  

E-Print Network [OSTI]

An RF ion-funnel technique has been developed to extract ions from a high-pressure (10 bar) noble-gas environment into vacuum ($10^{-6}$ mbar). Detailed simulations have been performed and a prototype has been developed for the purpose of extracting $^{136}$Ba ions from Xe gas with high efficiency. With this prototype, ions have been extracted for the first time from high-pressure xenon gas and argon gas. Systematic studies have been carried out and compared to the simulations. This demonstration of extraction of ions with mass comparable to that of the gas generating the high-pressure into vacuum has applications to Ba tagging from a Xe-gas time-projection chamber (TPC) for double beta decay as well as to the general problem of recovering trace amounts of an ionized element in a heavy (m$>40$ u) carrier gas.

Thomas Brunner; Daniel Fudenberg; Victor Varentsov; Amanda Sabourov; Giorgio Gratta; Jens Dilling; Ralph DeVoe; David Sinclair; William Fairbank Jr.; Joshua B Albert; David J Auty; Phil S Barbeau; Douglas Beck; Cesar Benitez-Medina; Martin Breidenbach; Guofu F Cao; Christopher Chambers; Bruce Cleveland; Matthew Coon; Adam Craycraft; Timothy Daniels; Sean J Daugherty; Tamar Didberidze; Michelle J Dolinski; Matthew Dunford; Lorenzo Fabris; Jacques Farine; Wolfhart Feldmeier; Peter Fierlinger; Razvan Gornea; Kevin Graham; Mike Heffner; Mitchell Hughes; Michael Jewell; Xiaoshan S Jiang; Tessa N Johnson; Sereres Johnston; Alexander Karelin; Lisa J Kaufman; Ryan Killick; Thomas Koffas; Scott Kravitz; Reiner Kruecken; Alexey Kuchenkov; Krishna S Kumar; Douglas S Leonard; Francois Leonard; Caio Licciardi; Yi-Hsuan H Lin; Jiajie Ling; Ryan MacLellan; Michael G Marino; Brian Mong; David Moore; Allen Odian; Igor Ostrovskiy; Christian Ouellet; Andreas Piepke; Andrea Pocar; Fabrice Retiere; Peter C Rowson; Maria P Rozo; Alexis Schubert; Erica Smith; Victor Stekhanov; Michal Tarka; Tamer Tolba; Delia Tosi; Karl Twelker; Jean-Luc L Vuilleumier; Josiah Walton; Timothy Walton; Manuel Weber; Liangjian J Wen; Ubi Wichoski; Liang Yang; Yung-Ruey Yen

2014-12-03T23:59:59.000Z

314

Development of a High Pressure/High Temperature Down-hole Turbine Generator  

SciTech Connect (OSTI)

As oil & natural gas deposits become more difficult to obtain by conventional means, wells must extend to deeper more heat-intensive environments. The technology of the drilling equipment required to reach these depths has exceeded the availability of electrical power sources needed to operate these tools. Historically, logging while drilling (LWD) and measure while drilling (MWD) devices utilized a wireline to supply power and communication from the operator to the tool. Lithium ion batteries were used in scenarios where a wireline was not an option, as it complicated operations. In current downhole applications, lithium ion battery (LIB) packs are the primary source for electrical power. LIB technology has been proven to supply reliable downhole power at temperatures up to 175 °C. Many of the deeper well s reach ambient temperatures above 200 °C, creating an environment too harsh for current LIB technology. Other downfalls of LIB technology are cost, limitations on charge cycles, disposal issues and possible safety hazards including explosions and fires. Downhole power generation can also be achieved by utilizing drilling fluid flow and converting it to rotational motion. This rotational motion can be harnessed to spin magnets around a series of windings to produce power proportional to the rpm experienced by the driven assembly. These generators are, in most instances, driven by turbine blades or moyno-based drilling fluid pumps. To date, no commercially available downhole power generators are capable of operating at ambient temperatures of 250 °C. A downhole power g enerator capable of operation in a 250 °C and 20,000 psi ambient environment will be an absolute necessity in the future. Dexter Magnetic Technologies’ High-Pressure High-Temperature (HPHT) Downhole Turbine Generator is capable of operating at 250 °C and 20, 000 psi, but has not been tested in an actual drilling application. The technology exists, but to date no company has been willing to test the tool.

Ben Plamp

2008-06-30T23:59:59.000Z

315

Homogeneous carbon doping of magnesium diboride by high-temperature, high-pressure synthesis  

SciTech Connect (OSTI)

We have used high-pressure, high-temperature synthesis at 1500–1700?°C and 10?MPa to create homogeneously C-substituted MgB{sub 2} from a B{sub 4}C + Mg mixture. X-ray diffraction analysis showed large peak-shifts consistent with a decrease in the a lattice parameter for the B{sub 4}C-derived MgB{sub 2} as compared to an undoped sample (0.033–0.037?Å, depending on the sample). Microstructural investigation showed a three-phase mixture in the B{sub 4}C-derived ingots: MgB{sub 2?x}C{sub x} (with 0.178?

Susner, M. A., E-mail: susner.1@osu.edu; Bohnenstiehl, S. D.; Dregia, S. A.; Sumption, M. D.; Yang, Y.; Collings, E. W. [Department of Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Donovan, J. J. [Center for Advanced Materials Characterization in Oregon (CAMCOR), University of Oregon, Eugene, Oregon 97403 (United States)

2014-04-21T23:59:59.000Z

316

Valve assembly for use with high temperature and high pressure fluids  

DOE Patents [OSTI]

The valve assembly for use with high temperature and high pressure fluids has inner and outer spaced shells and a valve actuator support of inner and outer spaced members which are connected at their end portions to the inner and outer shells, respectively, to extend substantially normal to the longitudinal axis of the inner shell. A layer of resilient heat insulating material covers the outer surfaces of the inner shell and the inner actuator support member and is of a thickness to only occupy part of the spaces between the inner and outer shells and inner and outer actuator support members. The remaining portion of the space between the inner and outer shells and the space between the inner and outer members is substantially filled with a body of castable, rigid refractory material. A movable valve member is disposed in the inner shell. A valve actuator assembly is supported in the valve actuator support to extend into the inner shell for connection with the movable valve member for movement of the movable valve member to positions from a fully open to a fully closed position to control flow of fluid through the inner shell. An anchor mneans is disposed adjacent opposite sides of the axis of the valve actuator support and attached to the inner shell so that relative radial movement between the inner and outer shell is permitted by the layer of resilient heat insulating material and relative longitudinal movement of the inner shell to the outer shell is permitted in opposite directions from the anchor means to thereby maintain the functional integrity of the movable valve member by providing an area of the inner shell surrounding the movable valve member longitdinally stationary, but at the same time allowing radial movement.

De Feo, Angelo (Totowa, NY)

1982-01-01T23:59:59.000Z

317

Development of high temperature, high pressure rotating shaft seals: Final report  

SciTech Connect (OSTI)

Rotating shaft seals used in coal gasification equipment are exposed to difficult environmental conditions including temperature from 430/sup 0/C to 816/sup 0/C (800/sup 0/F to 1500/sup 0/F), high pressure (to 10 MPa or 1500 psig), and high levels of particulate contamination (50,000 to 100,000 ppM). The program reported upon was designed to develop long-life seals that would not require external flushing or cooling. The approach taken was to develop unbalanced face that would remain closed and prevent particulate entry into the interface. Wear resistant materials and coatings with low friction coefficients are required. Significant results of the program are enumerated: The selected material combination was a rotating runner of Kentanium K162B mating against a non-rotating seal ring of Kentanium K162B. Kentanium is the trade name of a series of hard carbide alloys with pure titanium carbide as the principal ingredient. Nickel and nickel molybdenum are used as binder materials. Kentanium retains most of its strength at temperatures ..mu..p to 1100/sup 0/C (2000/sup 0/F). Since hard materials are required to resist wear and withstand the temperatures, mechanical compliance must be built into the seal configuration for the opposed faces to follow runner nutations and remain closed. Environmental and frictional heating caused the formation of very small particles of titanium oxide which lodged in the face wave formations and acted as an interfacial lubricant. The results of this program provide encouragement and optimism that dry contact face seals can be developed for long unattended operation in the hostile environment of a coal gasification plant. 40 refs., 98 figs., 20 tabs.

Heshmat, H.; Shapiro, W.

1987-06-01T23:59:59.000Z

318

Raman spectroscopy on single and multi-walled nanotubes under high pressure  

E-Print Network [OSTI]

dependence of the high-energy Raman modes in single and multi-walled carbon nanotubes was measuredRaman spectroscopy on single and multi-walled nanotubes under high pressure C. Thomsen, S. Reich, H properties of carbon nanotubes have become of scienti c interest since it was recognized that the low atomic

Nabben, Reinhard

319

Diffraction studies of order?disorder at high pressures and temperatures  

SciTech Connect (OSTI)

Recent developments at synchrotron X-ray beamlines now allow collection of data suitable for structure determination and Rietveld structure refinement at high pressures and temperatures on challenging materials. These include materials, such as dolomite (CaMg(CO{sub 3}){sub 2}) that tends to calcine at high temperatures, and Fe-containing materials, such as the spinel MgFe{sub 2}O{sub 4}, which tend to undergo changes in oxidation state. Careful consideration of encapsulation along with the use of radial collimation produced powder diffraction patterns virtually free of parasitic scattering from the cell in the case of large volume high-pressure experiments. These features have been used to study a number of phase transitions, especially those where superior signal-to-noise discrimination is required to distinguish weak ordering reflections. The structures adopted by dolomite, and CaSO4, anhydrite, were determined from 298 to 1466 K at high pressures. Using laser-heated diamond-anvil cells to achieve simultaneous high pressure and temperature conditions, we have observed CaSO{sub 4} undergo phase transitions to the monazite type and at highest pressure and temperature to crystallize in the barite-type structure. On cooling, the barite structure distorts, from an orthorhombic to a monoclinic lattice, to produce the AgMnO{sub 4}-type structure.

Parise, John B.; Antao, Sytle M.; Martin, Charles D.; Crichton, Wilson (SBU); (ESRF)

2008-06-18T23:59:59.000Z

320

High-pressure behavior of amorphous selenium from ultrasonic measurements and Raman spectroscopy  

SciTech Connect (OSTI)

The high-pressure behavior of melt-quenched amorphous selenium (a-Se) has been investigated via ultrasonic measurements and Raman scattering at room temperature. The ultrasonic measurements were conducted on a-Se in a multi-anvil apparatus with two different sample assemblies at pressures of up to 4.5 and 4.8?GPa. We discovered that similar kinks occur in the slopes of the pressure dependence characteristics of the travel time and the sound velocity in both shear and longitudinal waves in the 2.0–2.5?GPa range. These kinks are independent of the sample assemblies, indicating an intrinsic transformation of the a-Se. Additionally, we deduced the pressure-volume relationship of a-Se from the sound velocity characteristics using the Birch–Murnaghan equation of state, and the results agreed well with those of previous reports. In situ high-pressure Raman scattering measurements of a-Se were conducted in a diamond anvil cell with an 830?nm excitation line up to a pressure of 4.3?GPa. We found that the characteristic band of a-Se at ?250?cm{sup ?1} experienced a smooth shift to a lower frequency with pressure, but a sharp slope change in the band intensity versus pressure occurred near 2.5?GPa. The results of X-ray diffraction and differential scanning calorimetry measurements indicate that the samples remain in their amorphous states after decompression. Thus, we proposed that the abnormal compression behavior of a-Se in the 2.0–2.5?GPa range can be attributed to pressure-induced local atomic reconfiguration, implying an amorphous-amorphous transition of the elementary selenium.

He, Z.; Liu, X. R.; Hong, S. M., E-mail: hpswjtu@gmail.com, E-mail: smhong@home.swjtu.edu.cn [Laboratory of High Pressure Physics, Southwest Jiaotong University, Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Chengdu 610031 (China); Wang, Z. G. [National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, Chinese Academy of Engineering Physics, Mianyang 621900 (China); Zhu, H. Y. [State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012 (China); Peng, J. P. [School of Physical Science and Technology, Southwest Jiaotong University, Chengdu 610031 (China)

2014-07-07T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Standard test method for determination of susceptibility of metals to embrittlement in hydrogen containing environments at high pressure, high temperature, or both  

E-Print Network [OSTI]

Standard test method for determination of susceptibility of metals to embrittlement in hydrogen containing environments at high pressure, high temperature, or both

American Society for Testing and Materials. Philadelphia

1998-01-01T23:59:59.000Z

322

High-resolution thermal expansion measurements under helium-gas pressure  

SciTech Connect (OSTI)

We report on the realization of a capacitive dilatometer, designed for high-resolution measurements of length changes of a material for temperatures 1.4 K Less-Than-Or-Slanted-Equal-To T Less-Than-Or-Slanted-Equal-To 300 K and hydrostatic pressure P Less-Than-Or-Slanted-Equal-To 250 MPa. Helium ({sup 4}He) is used as a pressure-transmitting medium, ensuring hydrostatic-pressure conditions. Special emphasis has been given to guarantee, to a good approximation, constant-pressure conditions during temperature sweeps. The performance of the dilatometer is demonstrated by measurements of the coefficient of thermal expansion at pressures P Asymptotically-Equal-To 0.1 MPa (ambient pressure) and 104 MPa on a single crystal of azurite, Cu{sub 3}(CO{sub 3}){sub 2}(OH){sub 2}, a quasi-one-dimensional spin S = 1/2 Heisenberg antiferromagnet. The results indicate a strong effect of pressure on the magnetic interactions in this system.

Manna, Rudra Sekhar; Wolf, Bernd; Souza, Mariano de; Lang, Michael [Physics Institute, Goethe University Frankfurt(M), SFB/TR49, D-60438 Frankfurt am Main (Germany)

2012-08-15T23:59:59.000Z

323

Detecting and modeling cement failure in high pressure/ high temperature wells using finite-element method  

E-Print Network [OSTI]

conditions and are investigated simultaneously to more accurately predict cement failure. The results of this study show the relevant dependency of stress principles with temperature and pressure. These results clarify the deformation caused by any...

Shahri, Mehdi Abbaszadeh

2006-04-12T23:59:59.000Z

324

Revisit of the relationship between the elastic properties and sound velocities at high pressures  

SciTech Connect (OSTI)

The second-order elastic constants and stress-strain coefficients are defined, respectively, as the second derivatives of the total energy and the first derivative of the stress with respect to strain. Since the Lagrangian and infinitesimal strain are commonly used in the two definitions above, the second-order elastic constants and stress-strain coefficients are separated into two categories, respectively. In general, any of the four physical quantities is employed to characterize the elastic properties of materials without differentiation. Nevertheless, differences may exist among them at non-zero pressures, especially high pressures. Having explored the confusing issue systemically in the present work, we find that the four quantities are indeed different from each other at high pressures and these differences depend on the initial stress applied on materials. Moreover, the various relations between the four quantities depicting elastic properties of materials and high-pressure sound velocities are also derived from the elastic wave equations. As examples, we calculated the high-pressure sound velocities of cubic tantalum and hexagonal rhenium using these nexus. The excellent agreement of our results with available experimental data suggests the general applicability of the relations.

Wang, Chenju; Yan, Xiaozhen [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); Institute of Atomic and Molecular Sciences, Sichuan University, Chengdu 610065 (China); Xiang, Shikai, E-mail: skxiang@caep.ac.cn; Chen, Haiyan [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); Gu, Jianbing; Yu, Yin [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Kuang, Xiaoyu [Institute of Atomic and Molecular Sciences, Sichuan University, Chengdu 610065 (China); International Centre for Materials Physics, Academia Sinica, Shenyang 110016 (China)

2014-09-14T23:59:59.000Z

325

Numerical investigation of high-pressure combustion in rocket engines using Flamelet/Progress-variable models  

E-Print Network [OSTI]

The present paper deals with the numerical study of high pressure LOx/H2 or LOx/hydrocarbon combustion for propulsion systems. The present research effort is driven by the continued interest in achieving low cost, reliable access to space and more recently, by the renewed interest in hypersonic transportation systems capable of reducing time-to-destination. Moreover, combustion at high pressure has been assumed as a key issue to achieve better propulsive performance and lower environmental impact, as long as the replacement of hydrogen with a hydrocarbon, to reduce the costs related to ground operations and increase flexibility. The current work provides a model for the numerical simulation of high- pressure turbulent combustion employing detailed chemistry description, embedded in a RANS equations solver with a Low Reynolds number k-omega turbulence model. The model used to study such a combustion phenomenon is an extension of the standard flamelet-progress-variable (FPV) turbulent combustion model combined ...

Coclite, A; De Palma, P; Pascazio, G

2015-01-01T23:59:59.000Z

326

A primary high-pressure air flow measurement standard in Taiwan  

SciTech Connect (OSTI)

A high-pressure air-flow national measurement standard is constructed in Taiwan with a capacity of 8400 Nm{sup 3}/h and a projected measurement uncertainty of {plus_minus}0.2% in the pressure range of 1 {approximately} 84 bars. it is a blow-down type facility, and its main purpose is to serve as the primary standard of a larger-flowrate natural gas flow measurement facility to be built in the future by Chinese Petroleum Company (CPC). The system has a gyroscopic weighing platform suitable for high precision gravimetric measurements and several sonic nozzles with different throat diameters situated in a chamber to be the reference flow meters. A set of two turbine meters, 50mm and 100mm, are sued as the transfer standard. The facility has two test sections separated by the nozzle chamber and four different calibration modes could be arranged. To make calibration, the storage tank, the temperature control loop, and two sets of pressure regulating valve establish a pressurized air flow with stable temperature and pressure in the test section. The control of the air-flow diversion, connect-disconnect mechanism, sonic nozzle array is made through a hydraulic power unit operating at 200 bars. Real time measurements of temperature, pressure, flow signal, and time are collected through a Honeywell 9000-series PLC and a FIX DMAC data acquisition/control software. This paper describes the key components of the test facility and presents the preliminary results of performance assessment.

Jiunn-Haur Shaw; Fong-Ruey Yang; Yao-Fu Chen [Industrial Technology Research Inst., Hsinchu (Taiwan, Province of China)

1995-12-31T23:59:59.000Z

327

Structural changes in nano-crystalline mackinawite (FeS) at high - pressure.  

SciTech Connect (OSTI)

The high-pressure behavior of nanocrystalline mackinawite (FeS) with particle sizes of 6, 7 and 8 nm has been investigated by high-energy X-ray total scattering and pair distribution function analysis. An irreversible first-order structural phase transition from tetragonal mackinawite to orthorhombic FeS-II was observed at about 3 GPa. The transition is induced by the closure of the van der Waals gap in the layered mackinawite structure. A grain size effect on the transition pressure and the compressibility was observed.

Ehm, L.; Michael, F. M.; Antao, S. M.; Martin, C. D.; Lee, P. L.; Shastri, S. D.; Chupas, P. J.; Parise, J. B.; Stony Brook Univ.

2009-02-01T23:59:59.000Z

328

Rotor Design for High Pressure Magic Angle Spinning Nuclear Magnetic Resonance  

SciTech Connect (OSTI)

High pressure magic angle spinning (MAS) nuclear magnetic resonance (NMR) with a sample spinning rate exceeding 2.1 kHz and pressure greater than 165 bar has never been realized. In this work, a new sample cell design is reported, suitable for constructing cells of different sizes. Using a 7.5 mm high pressure MAS rotor as an example, internal pressure as high as 200 bar at a sample spinning rate of 6 kHz is achieved. The new high pressure MAS rotor is re-usable and compatible with most commercial NMR set-ups, exhibiting low 1H and 13C NMR background and offering maximal NMR sensitivity. As an example of its many possible applications, this new capability is applied to determine reaction products associated with the carbonation reaction of a natural mineral, antigorite ((Mg,Fe2+)3Si2O5(OH)4), in contact with liquid water in water-saturated supercritical CO2 (scCO2) at 150 bar and 50 deg C. This mineral is relevant to the deep geologic disposal of CO2, but its iron content results in too many sample spinning sidebands at low spinning rate. Hence, this chemical system is a good case study to demonstrate the utility of the higher sample spinning rates that can be achieved by our new rotor design. We expect this new capability will be useful for exploring solid-state, including interfacial, chemistry at new levels of high-pressure in a wide variety of fields.

Turcu, Romulus V.F.; Hoyt, David W.; Rosso, Kevin M.; Sears, Jesse A.; Loring, John S.; Felmy, Andrew R.; Hu, Jian Z.

2013-01-01T23:59:59.000Z

329

Methanol vaporization and injection system for internal combustion engine  

SciTech Connect (OSTI)

An engine equipped with an alcohol vaporization injection system operates as a four stroke cycle diesel engine that transfers the heat of exiting exhaust gases and cylinder head walls to the fuel. The engine runs on alcohol. The alcohol becomes vaporized and its pressure is high enough so that when a valve is opened between the high pressure fuel line and the combustion chamber (when it is at the peak of its compression ratio) enough alcohol will enter the combustion chamber to allow proper combustion. The overall advantages to this type of alcohol vaporization injection system is that it adds relatively few new mechanisms to the spark ignition four cycle internal combustion engine to enable it to operate as a diesel engine with a high thermal efficiency. This alcohol injection system exploits the engine's need for greater volumes of alcohol caused by the alcohol's relatively low heat of combustion (When compared to gasoline) by using this greater volume of fuel to return greater quantities of heat back to the engine to a much greater degree than other fuels can.

Bayley, R.I.

1980-05-06T23:59:59.000Z

330

Safety analysis of high pressure 3He-filled micro-channels for thermal neutron detection.  

SciTech Connect (OSTI)

This document is a safety analysis of a novel neutron detection technology developed by Sandia National Laboratories. This technology is comprised of devices with tiny channels containing high pressure {sup 3}He. These devices are further integrated into large scale neutron sensors. Modeling and preliminary device testing indicates that the time required to detect the presence of special nuclear materials may be reduced under optimal conditions by several orders of magnitude using this approach. Also, these devices make efficient use of our {sup 3}He supply by making individual devices more efficient and/or extending the our limited {sup 3}He supply. The safety of these high pressure devices has been a primary concern. We address these safety concerns for a flat panel configuration intended for thermal neutron detection. Ballistic impact tests using 3 g projectiles were performed on devices made from FR4, Silicon, and Parmax materials. In addition to impact testing, operational limits were determined by pressurizing the devices either to failure or until they unacceptably leaked. We found that (1) sympathetic or parasitic failure does not occur in pressurized FR4 devices (2) the Si devices exhibited benign brittle failure (sympathetic failure under pressure was not tested) and (3) the Parmax devices failed unacceptably. FR4 devices were filled to pressures up to 4000 + 100 psig, and the impacts were captured using a high speed camera. The brittle Si devices shattered, but were completely contained when wrapped in thin tape, while the ductile FR4 devices deformed only. Even at 4000 psi the energy density of the compressed gas appears to be insignificant compared to the impact caused by the incoming projectile. In conclusion, the current FR4 device design pressurized up to 4000 psi does not show evidence of sympathetic failure, and these devices are intrinsically safe.

Ferko, Scott M.; Galambos, Paul C.; Derzon, Mark Steven; Renzi, Ronald F.

2008-11-01T23:59:59.000Z

331

A cryogenic high pressure cell for inelastic neutron scattering measurements of quantum fluids and solids  

SciTech Connect (OSTI)

We present our new development of a high pressure cell for inelastic neutron scattering measurements of helium at ultra-low temperatures. The cell has a large sample volume of ~140 cm3, and a working pressure of ~70 bar, with a relatively thin wall-thickness (1.1 mm) - thanks to the high yield strength aluminum used in the design. Two variants of this cell have been developed; one with permanently joined components using electron-beam welding and explosion welding, methods that have little or no impact on the global heat treatment of the cell, and another with modular and interchangeable components, which include a capacitance pressure gauge, that can be sealed using traditional indium wire technique. The performance of the cell has been tested in recent measurements on superfluid liquid helium near the solidification line.

Carmichael, Justin R [ORNL; Omar Diallo, Souleymane [ORNL

2013-01-01T23:59:59.000Z

332

Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection  

SciTech Connect (OSTI)

A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell. Precise reagent additions to the pressurized cell are made with calibrated tubing loops that are filled with reagent and placed in-line with the cell and a syringe pump. The cell’s infrared optics facilitate both transmission and attenuated total reflection (ATR) measurements to monitor bulk-fluid composition and solid-surface phenomena such as adsorption, desorption, complexation, dissolution, and precipitation. Switching between the two measurement modes is accomplished with moveable mirrors that direct radiation from a Fourier transform infrared spectrometer into the cell along transmission or ATR light paths. The versatility of the high-pressure IR titration system is demonstrated with three case studies. First, we titrated water into supercritical CO2 (scCO2) to generate an infrared calibration curve and determine the solubility of water in CO2 at 50 °C and 90 bar. Next, we characterized the partitioning of water between a montmorillonite clay and scCO2 at 50 °C and 90 bar. Transmission-mode spectra were used to quantify changes in the clay’s sorbed water concentration as a function of scCO2 hydration, and ATR measurements provided insights into competitive residency of water and CO2 on the clay surface and in the interlayer. Finally, we demonstrated how time-dependent studies can be conducted with the system by monitoring the carbonation reaction of forsterite (Mg2SiO4) in water-bearing scCO2 at 50 °C and 90 bar. Immediately after water dissolved in the scCO2, a thin film of adsorbed water formed on the mineral surface, and the film thickness increased with time as the forsterite began to dissolve. However, after approximately 2.5 hours, the trend reversed, and a carbonate precipitate began to form on the forsterite surface, exposing dramatic chemical changes in the thin-water film. Collectively, these applications illustrate how the high-pressure IR titration system can provide molecular-level information about the interactions between variably wet scCO2 and minerals relevant to underground storage of CO2 (geologic carbon sequestration). The apparatus could also be utilized to study high-pressure interfacial chemistry in other areas such as catalysis, polymerization, food processing, and oil and gas recovery.

Thompson, Christopher J.; Martin, Paul F.; Chen, Jeffrey; Benezeth, Pascale; Schaef, Herbert T.; Rosso, Kevin M.; Felmy, Andrew R.; Loring, John S.

2014-04-17T23:59:59.000Z

333

Automated high-pressure titration system with in situ infrared spectroscopic detection  

SciTech Connect (OSTI)

A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell. Precise reagent additions to the pressurized cell are made with calibrated tubing loops that are filled with reagent and placed in-line with the cell and a syringe pump. The cell's infrared optics facilitate both transmission and attenuated total reflection (ATR) measurements to monitor bulk-fluid composition and solid-surface phenomena such as adsorption, desorption, complexation, dissolution, and precipitation. Switching between the two measurement modes is accomplished with moveable mirrors that direct the light path of a Fourier transform infrared spectrometer into the cell along transmission or ATR light paths. The versatility of the high-pressure IR titration system was demonstrated with three case studies. First, we titrated water into supercritical CO{sub 2} (scCO{sub 2}) to generate an infrared calibration curve and determine the solubility of water in CO{sub 2} at 50?°C and 90 bar. Next, we characterized the partitioning of water between a montmorillonite clay and scCO{sub 2} at 50?°C and 90 bar. Transmission-mode spectra were used to quantify changes in the clay's sorbed water concentration as a function of scCO{sub 2} hydration, and ATR measurements provided insights into competitive residency of water and CO{sub 2} on the clay surface and in the interlayer. Finally, we demonstrated how time-dependent studies can be conducted with the system by monitoring the carbonation reaction of forsterite (Mg{sub 2}SiO{sub 4}) in water-bearing scCO{sub 2} at 50?°C and 90 bar. Immediately after water dissolved in the scCO{sub 2}, a thin film of adsorbed water formed on the mineral surface, and the film thickness increased with time as the forsterite began to dissolve. However, after approximately 2.5 h, the trend reversed, and a carbonate precipitate began to form on the forsterite surface, exposing dramatic chemical changes in the thin-water film. Collectively, these applications illustrate how the high-pressure IR titration system can provide molecular-level information about the interactions between variably wet scCO{sub 2} and minerals relevant to underground storage of CO{sub 2} (geologic carbon sequestration). The apparatus could also be utilized to study high-pressure interfacial chemistry in other areas such as catalysis, polymerization, food processing, and oil and gas recovery.

Thompson, Christopher J., E-mail: chris.thompson@pnnl.gov; Martin, Paul F.; Chen, Jeffrey; Schaef, Herbert T.; Rosso, Kevin M.; Felmy, Andrew R.; Loring, John S. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States)] [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Benezeth, Pascale [Géosciences Environnement Toulouse (GET), CNRS-Université de Toulouse, 31400 Toulouse (France)] [Géosciences Environnement Toulouse (GET), CNRS-Université de Toulouse, 31400 Toulouse (France)

2014-04-15T23:59:59.000Z

334

Elastic properties, sp{sup 3} fraction, and Raman scattering in low and high pressure synthesized diamond-like boron rich carbides  

SciTech Connect (OSTI)

Dense BC{sub x} phases with high boron concentration are predicted to be metastable, superhard, and conductors or superconductors depending on boron concentration. However, up to this point, diamond-like boron rich carbides BC{sub x} (dl-BC{sub x}) phases have been thought obtainable only through high pressure and high temperature treatment, necessitating small specimen volume. Here, we use electron energy loss spectroscopy combined with transmission electron microscopy, Raman spectroscopy, surface Brillouin scattering, laser ultrasonics (LU) technique, and analysis of elastic properties to demonstrate that low pressure synthesis (chemical vapor deposition) of BC{sub x} phases may also lead to the creation of diamond-like boron rich carbides. The elastic properties of the dl-BC{sub x} phases depend on the carbon sp{sup 2} versus sp{sup 3} content, which decreases with increasing boron concentration, while the boron bonds determine the shape of the Raman spectra of the dl-BC{sub x} after high pressure-high temperature treatment. Using the estimation of the density value based on the sp{sup 3} fraction, the shear modulus ? of dl-BC{sub 4}, containing 10% carbon atoms with sp{sup 3} bonds, and dl-B{sub 3}C{sub 2}, containing 38% carbon atoms with sp{sup 3} bonds, were found to be ??=?19.3?GPa and ??=?170?GPa, respectively. The presented experimental data also imply that boron atoms lead to a creation of sp{sup 3} bonds during the deposition processes.

Zinin, Pavel V.; Burgess, Katherine; Jia, Ruth; Sharma, Shiv; Ming, Li-Chung [Hawaii Institute of Geophysics and Planetology, University of Hawaii, Honolulu, Hawaii 96822 (United States); Liu, Yongsheng [Science and Technology on Thermostructure Composite Materials Laboratory, Northwestern Polytechnical University, Xi'an Shanxi (China); Ciston, Jim [National Center for Electron Microscopy, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Hong, Shiming [Laboratory of High Pressure Physics, Southwest Jiaotong University, Chengdu, Sichuan (China)

2014-10-07T23:59:59.000Z

335

Design, modeling, fabrication and testing of a piezoelectric microvalve for high pressure, high frequency hydraulic applications  

E-Print Network [OSTI]

A piezoelectrically-driven hydraulic amplification microvalve for use in high specific power hydraulic pumping applications was designed, fabricated, and experimentally characterized. High frequency, high force actuation ...

Roberts, David C. (David Christopher)

2002-01-01T23:59:59.000Z

336

ANALYSIS OF HIGH PRESSURE TESTS ON WET GAS FLOW METERING WITH A VENTURI METER  

E-Print Network [OSTI]

ANALYSIS OF HIGH PRESSURE TESTS ON WET GAS FLOW METERING WITH A VENTURI METER P. Gajan , Q, 64018 Pau cedex, France pierre.gajan@onera.fr Abstract This work deals with the flow metering of wet gas on the CEESI facilities are presented. They are performed at 75 bars with 0.6 beta ratio Venturi meter

337

High-pressure phases of FeTiO3 from first principles N. C. Wilson  

E-Print Network [OSTI]

2005; published 19 July 2005 The structural, elastic, and electronic properties of the high-pressure Fe and their interaction with the structural degrees of freedom. Ilmenite, the mineral form of FeTiO3, is commonly found of diamond deposits.2 In addition to ilmenite, two other polymorphs of FeTiO3 are known,3 namely, the lithium

338

Stability of very-high pressure arc discharges against perturbations of the electron temperature  

SciTech Connect (OSTI)

We study the stability of the energy balance of the electron gas in very high-pressure plasmas against longitudinal perturbations, using a local dispersion analysis. After deriving a dispersion equation, we apply the model to a very high-pressure (100 bar) xenon plasma and find instability for electron temperatures, T{sub e}, in a window between 2400 K and 5500-7000 K x 10{sup 3} K, depending on the current density (10{sup 6}-10{sup 8} A/m{sup 2}). The instability can be traced back to the Joule heating of the electron gas being a growing function of T{sub e}, which is due to a rising dependence of the electron-atom collision frequency on T{sub e}. We then analyze the T{sub e} range occurring in very high-pressure xenon lamps and conclude that only the near-anode region exhibits T{sub e} sufficiently low for this instability to occur. Indeed, previous experiments have revealed that such lamps develop, under certain conditions, voltage oscillations accompanied by electromagnetic interference, and this instability has been pinned down to the plasma-anode interaction. A relation between the mechanisms of the considered instability and multiple anodic attachments of high-pressure arcs is discussed.

Benilov, M. S. [Departamento de Fisica, Ciencias Exactas e Engenharia, Universidade da Madeira, Largo do Municipio, Funchal 9000 (Portugal); Hechtfischer, U. [Philips Lighting, BU Automotive Lamps, Technology, Philipsstrasse 8, Aachen 52068 (Germany)

2012-04-01T23:59:59.000Z

339

Ultrafast high-pressure AC electro-osmotic pumps for portable biomedical microfluidics  

E-Print Network [OSTI]

Ultrafast high-pressure AC electro-osmotic pumps for portable biomedical microfluidics Chien details the development of an integrated AC electro-osmotic (ACEO) microfluidic pump for dilute (100 mM) biological solutions in separate microfluidic devices, with potential applications in portable

Bazant, Martin Z.

340

Metastable high-pressure transformations of orthoferrosilite Fs82 Przemyslaw Dera a,e,  

E-Print Network [OSTI]

Metastable high-pressure transformations of orthoferrosilite Fs82 Przemyslaw Dera a,e, , Gregory J Institution of Washington, USA e Hawaii Institute of Geophysics and Planetology, School of Ocean and Earth Science and Technology, University of Hawaii at Manoa, USA a r t i c l e i n f o Article history: Received

Duffy, Thomas S.

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

High pressure studies on uranium and thorium silicide compounds: Experiment S. Yagoubi a,b,c,  

E-Print Network [OSTI]

High pressure studies on uranium and thorium silicide compounds: Experiment and theory S. Yagoubi a, USi3, as well as some non-stoichiometric phases presented in Table 1. Among the thoriumB-type) that a ferromagnetic ordering is reported, with TC = 127 K and a saturated moment of 0.1 lB [3]. Concerning the thorium

Svane, Axel Torstein

342

Acceptance test report for high pressure water jet system feed pump  

SciTech Connect (OSTI)

This document summarizes results of WHC-SD-SNF-ATP-016, Rev. 0 ``Acceptance Test Procedure High Pressure Water Jet System``, conducted on December 20, 1995 and December 22, 1995. This jet supplies water at 15,000 psi @ 15 gpm to nozzles to clean surfaces of empty fuel storage canisters.

Crystal, J.B.

1996-03-12T23:59:59.000Z

343

Thermal conductance of metal-diamond interfaces at high pressure Gregory T. Hohensee  

E-Print Network [OSTI]

are concerned with the exchange of thermal energy across an interface between two materials. This topic-nonmetal interface, a two-temperature model predicts a thermal resistance of Rep = 1/ gL in series with the phononThermal conductance of metal-diamond interfaces at high pressure Gregory T. Hohensee Department

Cahill, David G.

344

Manufacturing and properties of newly developed 9%CrMoVNiNbN high-pressure low-pressure rotor shaft forging  

SciTech Connect (OSTI)

In order to obtain the improved strength and toughness for high-pressure low-pressure rotor shaft forging, fundamental studies using laboratory heats were performed on the 9CrMoV base materials, and effects of chemistry on toughness and creep rupture strength were investigated. From the investigation, it is showed that the superclean 9CrMoVNiNbN steel with reduced Si and Mn contents and Ni addition provides a superior strength versus toughness balance. Based on these fundamental studies, a trial high-pressure low-pressure rotor shaft forging with diameter of low-pressure section of 1,750 mm and diameter of high-pressure section of 1,200 mm was successfully manufactured from the diameter of 1,800 mm, and the weight of 65 ton ESR ingot. From the evaluation test results of this trial rotor forging, homogeneous distribution of chemistry was confirmed and low impurity contents was observed in the whole forging. The superior strength and toughness were confirmed with good creep rupture strength. The FATT at the center of low-pressure section was {minus}3 C with the tensile strength level of 870 MPa. From the results of fracture toughness test, low cycle fatigue test, and isothermal aging test, superior mechanical properties were demonstrated. Thus, the superclean 9CrMoVNiNbN steel with reduced Si and Mn contents and Ni addition, is particularly suitable for the high-pressure low-pressure rotor material for advanced combined cycle power plants.

Azuma, Tsukasa; Tanaka, Yasuhiko; Ishiguro, Tohru; Yoshida, Hajime; Ikeda, Yasumi [Japan Steel Works, Muroran (Japan)

1997-12-31T23:59:59.000Z

345

Innovative high pressure gas MEM's based neutron detector for ICF and active SNM detection.  

SciTech Connect (OSTI)

An innovative helium3 high pressure gas detection system, made possible by utilizing Sandia's expertise in Micro-electrical Mechanical fluidic systems, is proposed which appears to have many beneficial performance characteristics with regards to making these neutron measurements in the high bremsstrahlung and electrical noise environments found in High Energy Density Physics experiments and especially on the very high noise environment generated on the fast pulsed power experiments performed here at Sandia. This same system may dramatically improve active WMD and contraband detection as well when employed with ultrafast (10-50 ns) pulsed neutron sources.

Martin, Shawn Bryan; Derzon, Mark Steven; Renzi, Ronald F.; Chandler, Gordon Andrew

2007-12-01T23:59:59.000Z

346

Vapor Pressures and Heats of Vaporization of Primary Coal Tars  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing, an National Carbon Capture Center at ,iMA-110662 PT6a DynamicV

347

Use of high hydrostatic pressure to produce high quality and safe fresh pork sausage  

E-Print Network [OSTI]

and Functionality Improvement . . . . . . . . . . . . . . . . . . . . . Thermal Processing . Response Surface Methodology 22 22 22 23 23 24 26 26 27 30 32 111 THEORETICAL CONSIDERATIONS 33 31 3. 2 3. 3 Theory of Linear Viscoelasticity 3. 1. 1... with yeast extract (TSA) and Modified oxford agar (MOX) with supplements . . . . . . . . . . . . . . . . 73 5. 2 Survival of three individual strains of L. monocytogenes in fresh pork sausage exposed to a hydrostatic pressure of 414 MPa at 25'C for various...

Huang, Mei

2012-06-07T23:59:59.000Z

348

High Temperature, high pressure equation of state density correlations and viscosity correlations  

SciTech Connect (OSTI)

Global increase in oil demand and depleting reserves has derived a need to find new oil resources. To find these untapped reservoirs, oil companies are exploring various remote and harsh locations such as deep waters in Gulf of Mexico, remote arctic regions, unexplored deep deserts, etc. Further, the depth of new oil/gas wells being drilled has increased considerably to tap these new resources. With the increase in the well depth, the bottomhole temperature and pressure are also increasing to extreme values (i.e. up to 500 F and 35,000 psi). The density and viscosity of natural gas and crude oil at reservoir conditions are critical fundamental properties required for accurate assessment of the amount of recoverable petroleum within a reservoir and the modeling of the flow of these fluids within the porous media. These properties are also used to design appropriate drilling and production equipment such as blow out preventers, risers, etc. With the present state of art, there is no accurate database for these fluid properties at extreme conditions. As we have begun to expand this experimental database it has become apparent that there are neither equations of state for density or transport models for viscosity that can be used to predict these fundamental properties of multi-component hydrocarbon mixtures over a wide range of temperature and pressure. Presently, oil companies are using correlations based on lower temperature and pressure databases that exhibit an unsatisfactory predictive capability at extreme conditions (e.g. as great as {+-} 50%). From the perspective of these oil companies that are committed to safely producing these resources, accurately predicting flow rates, and assuring the integrity of the flow, the absence of an extensive experimental database at extreme conditions and models capable of predicting these properties over an extremely wide range of temperature and pressure (including extreme conditions) makes their task even more daunting.

Tapriyal, D.; Enick, R.; McHugh, M.; Gamwo, I.; Morreale, B.

2012-07-31T23:59:59.000Z

349

The High-Pressure Characterization of Energetic Materials: 2-Methyl-5-Nitramino-2H-Tetrazole  

SciTech Connect (OSTI)

The isothermal structural properties, equation of state, and vibrational dynamics of 2MNT were studied under high-pressure using synchrotron XRD and optical Raman and IR microspectroscopy. Analysis of the XRD patterns revealed no indication of a phase transition to near 15 GPa and the pressure-volume isotherm remained smooth to 15 GPa. Near 15 GPa, significant sample damage was observed from the X-ray beam which precluded the acquisition of patterns above this pressure. XRD and Raman spectroscopic measurements showed the monoclinic ambient condition phase of 2MNT remains the dominant phase to near 20 GPa, although a shift of the NO{sub 2} IR active vibrational modes to lower frequencies suggested a subtle geometry modification not reflected in the XRD data.

J Ciezak

2011-12-31T23:59:59.000Z

350

Autoignition of gasoline surrogates mixtures at intermediate temperatures and high pressures  

SciTech Connect (OSTI)

Ignition times were determined in high-pressure shock-tube experiments for various stoichiometric mixtures of two multicomponent model fuels in air for the validation of ignition delay simulations based on chemical kinetic models. The fuel blends were n-heptane (18%)/isooctane (62%)/ethanol (20%) by liquid volume (14.5%/44.5%/41% by mole fraction) and n-heptane (20%)/toluene (45%)/isooctane (25%)/diisobutylene (10%) by liquid volume (17.5%/55%/19.5%/8.0% by mole fraction). These fuels have octane numbers comparable to a standard European gasoline of 95 RON and 85 MON. The experimental conditions cover temperatures from 690 to 1200 K and pressures at 10, 30, and 50 bar. The obtained ignition time data are scaled with respect to pressure and compared to previous results reported in the literature. (author)

Fikri, M.; Herzler, J.; Starke, R.; Schulz, C.; Roth, P. [IVG, Universitaet Duisburg-Essen, D-47048 Duisburg (Germany); Kalghatgi, G.T. [Shell Global Solutions U.K., P.O. Box 1, Chester CH1 3SH (United Kingdom)

2008-01-15T23:59:59.000Z

351

High-pressure structural and elastic properties of Tl{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The structural properties of Thallium (III) oxide (Tl{sub 2}O{sub 3}) have been studied both experimentally and theoretically under compression at room temperature. X-ray powder diffraction measurements up to 37.7?GPa have been complemented with ab initio total-energy calculations. The equation of state of Tl{sub 2}O{sub 3} has been determined and compared to related compounds. It has been found experimentally that Tl{sub 2}O{sub 3} remains in its initial cubic bixbyite-type structure up to 22.0?GPa. At this pressure, the onset of amorphization is observed, being the sample fully amorphous at 25.2?GPa. The sample retains the amorphous state after pressure release. To understand the pressure-induced amorphization process, we have studied theoretically the possible high-pressure phases of Tl{sub 2}O{sub 3}. Although a phase transition is theoretically predicted at 5.8?GPa to the orthorhombic Rh{sub 2}O{sub 3}-II-type structure and at 24.2?GPa to the orthorhombic ?-Gd{sub 2}S{sub 3}-type structure, neither of these phases were observed experimentally, probably due to the hindrance of the pressure-driven phase transitions at room temperature. The theoretical study of the elastic behavior of the cubic bixbyite-type structure at high-pressure shows that amorphization above 22?GPa at room temperature might be caused by the mechanical instability of the cubic bixbyite-type structure which is theoretically predicted above 23.5?GPa.

Gomis, O., E-mail: osgohi@fis.upv.es; Vilaplana, R. [Centro de Tecnologías Físicas, MALTA Consolider Team, Universitat Politècnica de València, 46022 València (Spain); Santamaría-Pérez, D. [Departamento de Física Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr. Moliner 50, 46100 Burjassot (Spain); Earth Sciences Department, University College London, Gower Street, WC1E 6BT London (United Kingdom); Ruiz-Fuertes, J. [Departamento de Física Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr. Moliner 50, 46100 Burjassot (Spain); Geowissenschaften, Goethe-Universität, Altenhöferallee 1, 60438 Frankfurt am Main (Germany); Sans, J. A.; Manjón, F. J.; Mollar, M. [Instituto de Diseño para la Fabricación y Producción Automatizada, MALTA Consolider Team, Universitat Politècnica de València, 46022 València (Spain); and others

2014-10-07T23:59:59.000Z

352

Phase transition and metallization of FeO at high pressures and temperatures  

SciTech Connect (OSTI)

Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component of the core. Therefore its high pressure-temperature behavior, including its electronic structure, is essential to understanding the nature and evolution of Earth's deep interior. We performed X-ray diffraction and radiometric measurements on wuestite in a laser-heated diamond anvil cell, finding an insulator-metal transition at high pressures and temperatures. Our data show a negative slope for this apparently isostructural phase boundary, which is characterized by a volume decrease and emissivity increase. The metallic phase of FeO is stable at conditions of the lower mantle and core, which has implications for the high P-T character of Fe-O bonds, magnetic field propagation, and lower mantle conductivity.

Fischer, Rebecca A.; Campbell, Andrew J.; Lord, Oliver T.; Shofner, Gregory A.; Dera, Przemyslaw; Prakapenka, Vitali B. (Maryland); (UC); (UCL)

2012-05-10T23:59:59.000Z

353

Breakdown of Angular Momentum Selection Rules in High Pressure Optical Pumping Experiments  

SciTech Connect (OSTI)

We present measurements, by using two complementary methods, of the breakdown of atomic angular momentum selection rules in He-broadened Rb vapor. Atomic dark states are rendered weakly absorbing due to fine-structure mixing during Rb-He collisions. The effect substantially increases the photon demand for optical pumping of dense vapors.

Lancor, B.; Wyllie, R.; Walker, T. G. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Babcock, E. [Juelich Centre for Neutron Science, Garching 85747 (Germany)

2010-08-20T23:59:59.000Z

354

Rigorous Simulation of Accidental Leaks from High-Pressure Storage Vessels  

E-Print Network [OSTI]

of nature. The released chemical can form and disperse as vapor cloud leading to fire, explosion, or toxic exposure. The resulting leak could be single phase or multiphase release, choked or non-choked. These releases could result in liquid spills, vapor...

Alisha, -

2014-07-07T23:59:59.000Z

355

Materials, methods and devices to detect and quantify water vapor concentrations in an atmosphere  

DOE Patents [OSTI]

We have demonstrated that a surface acoustic wave (SAW) sensor coated with a nanoporous framework material (NFM) film can perform ultrasensitive water vapor detection at concentrations in air from 0.05 to 12,000 ppmv at 1 atmosphere pressure. The method is extendable to other MEMS-based sensors, such as microcantilevers, or to quartz crystal microbalance sensors. We identify a specific NFM that provides high sensitivity and selectivity to water vapor. However, our approach is generalizable to detection of other species using NFM to provide sensitivity and selectivity.

Allendorf, Mark D; Robinson, Alex L

2014-12-09T23:59:59.000Z

356

Direct vapor/solid synthesis of mercuric iodide using compounds of mercury and iodine  

SciTech Connect (OSTI)

A process is disclosed for producing high purity mercuric iodide by passing a gaseous source of a mercuric compound through a particulate bed of a low vapor pressure iodide compound which is maintained at an elevated temperature which is the lower of either: (a) just below the melting or volatilization temperature of the iodide compound (which ever is lower); or (b) just below the volatilization point of the other reaction product formed during the reaction; to cause the mercuric compound to react with the iodide compound to form mercuric iodide which then passes as a vapor out of the bed into a cooler condensation region.

Skinner, Nathan L. (Carpinteria, CA)

1990-01-01T23:59:59.000Z

357

Studies of local and intermediate range structure in crystalline and amorphouse materials at high pressure using high-energy x-rays.  

SciTech Connect (OSTI)

The method of high-energy total elastic X-ray scattering to determine the atomic structure of nanocrystalline, highly disordered, and amorphous materials is presented. The current state of the technique, its potential, and limitations are discussed with two successful studies on the pressure induced phase transition in mackinawite (FeS) and the high-pressure behavior of liquid gallium.

Ehm, L.; Antao, M.; Chen, J.; Locke, D. R.; Michel, F. M.; Martin, C. D.; Yu, T.; Lee, P. L.; Chupas, P. J.; Shastri, S. D.; Guo, Q.; Parise, J. B.; Stony Brook Univ.; BNL

2007-06-01T23:59:59.000Z

358

Studies of Local and Intermediate Range Structure in Crystalline and Amorphous Materials at High Pressure Using High-Energy X-rays  

SciTech Connect (OSTI)

The method of high-energy total elastic X-ray scattering to determine the atomic structure of nanocrystalline, highly disordered, and amorphous materials is presented. The current state of the technique, its potential, and limitations are discussed with two successful studies on the pressure induced phase transition in mackinawite (FeS) and the high-pressure behavior of liquid gallium.

Ehm,L.; Antao, S.; Chen, J.; Locke, D.; Michel, F.; Martin, D.; Yu, T.; Parise, J.; Lee, P.; et al.

2007-01-01T23:59:59.000Z

359

Dark Matter Directionality Revisited with a High Pressure Xenon Gas Detector  

E-Print Network [OSTI]

An observation of the anisotropy of dark matter interactions in a direction-sensitive detector would provide decisive evidence for the discovery of galactic dark matter. Directional information would also provide a crucial input to understanding its distribution in the local Universe. Most of the existing directional dark matter detectors utilize particle tracking methods in a low-pressure gas time projection chamber. These low pressure detectors require excessively large volumes in order to be competitive in the search for physics beyond the current limit. In order to avoid these volume limitations, we consider a novel proposal, which exploits a columnar recombination effect in a high-pressure gas time projection chamber. The ratio of scintillation to ionization signals observed in the detector carries the angular information of the particle interactions. In this paper, we investigate the sensitivity of a future directional detector focused on the proposed high-pressure Xenon gas time projection chamber. We study the prospect of detecting an anisotropy in the dark matter velocity distribution. We find that tens of events are needed to exclude an isotropic distribution of dark matter interactions at 95% confidence level in the most optimistic case with head-to-tail information. However, one needs at least 10-20 times more events without head-to-tail information for light dark matter below 50 GeV or one between 200 GeV and 400 GeV. For an intermediate mass range, we find it challenging to observe anisotropy of dark matter distribution.

Gopolang Mohlabeng; Kyoungchul Kong; Jin Li; Adam Para; Jonghee Yoo

2015-03-13T23:59:59.000Z

360

Study of liquid gallium at high pressure using synchrotron x-ray  

SciTech Connect (OSTI)

Liquid gallium has been studied at high pressure up to 2 GPa and ambient temperature in a diamond anvil cell using high energy synchrotron x-ray beam. The total x-ray scattering data of liquid gallium were collected up to Q = 12 A{sup -1} and analyzed using pair distribution functions (PDF). The results indicate that the first nearest neighbor peak and second nearest neighbor (shoulder) peak of PDF in liquid gallium does not change with pressure, whereas the higher order (i.e., third and fourth) nearest neighbor peaks shift towards shorter distance with increasing pressure. Reverse Monte Carlo modeling based on the observed data shows that the coordination number in the liquid gallium increases with pressure from 10.5 at 0.3 GPa to 11.6 at 2 GPa. An atomic arrangement similar to the crystalline phase of Ga(II) with coordination number of 12 is proposed for the locally dense-packed rigid unit in liquid gallium. The volume compression data derived from the structure modeling yield a bulk modulus of 12.1(6) GPa for liquid gallium.

Yu, Tony; Guo Quanzhong; Parise, John [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); Chen Jiuhua [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); Department of Mechanical and Materials Engineering, Center for the Study of Matters at Extreme Conditions, Florida International University, Miami, Florida 33199 (United States); Ehm, Lars [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States); Huang Shu [Department of Mechanical and Materials Engineering, Center for the Study of Matters at Extreme Conditions, Florida International University, Miami, Florida 33199 (United States); Luo Shengnian [Physics Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2012-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Comparison of high pressure transient PVT measurements and model predictions. Part I.  

SciTech Connect (OSTI)

A series of experiments consisting of vessel-to-vessel transfers of pressurized gas using Transient PVT methodology have been conducted to provide a data set for optimizing heat transfer correlations in high pressure flow systems. In rapid expansions such as these, the heat transfer conditions are neither adiabatic nor isothermal. Compressible flow tools exist, such as NETFLOW that can accurately calculate the pressure and other dynamical mechanical properties of such a system as a function of time. However to properly evaluate the mass that has transferred as a function of time these computational tools rely on heat transfer correlations that must be confirmed experimentally. In this work new data sets using helium gas are used to evaluate the accuracy of these correlations for receiver vessel sizes ranging from 0.090 L to 13 L and initial supply pressures ranging from 2 MPa to 40 MPa. The comparisons show that the correlations developed in the 1980s from sparse data sets perform well for the supply vessels but are not accurate for the receivers, particularly at early time during the transfers. This report focuses on the experiments used to obtain high quality data sets that can be used to validate computational models. Part II of this report discusses how these data were used to gain insight into the physics of gas transfer and to improve vessel heat transfer correlations. Network flow modeling and CFD modeling is also discussed.

Felver, Todd G.; Paradiso, Nicholas Joseph; Evans, Gregory Herbert; Rice, Steven F.; Winters, William Stanley, Jr.

2010-07-01T23:59:59.000Z

362

High pressure pair distribution function studies of Green River oil shale.  

SciTech Connect (OSTI)

The compression behavior of a silicate-rich oil shale from the Green River formation in the pressure range 0.0-2.4 GPa was studied using in situ high pressure X-ray pair distribution function (PDF) measurements for the sample contained within a Paris-Edinburgh cell. The real-space local structural information in the PDF, G(r), was used to evaluate the compressibility of the oil shale. Specifically, the pressure-induced reduction in the medium- to long-range atom distances ({approx}6-20 {angstrom}) yielded an average sample compressibility corresponding to a bulk modulus of ca. 61-67 GPa. A structural model consisting of a three phase mixture of the principal crystalline oil shale components (quartz, albite and Illite) provided a good fit to the ambient pressure PDF data (R {approx} 30.7%). Indeed the features in the PDF beyond {approx} {angstrom}, were similarly well fit by a single phase model of the highest symmetry, highly crystalline quartz component. The factors influencing the observed compression behavior are discussed.

Chapman, K. W.; Chupas, P. J.; Locke, D. R.; Winans, R. E.; Pugmire, R. J.; Univ. of Utah

2008-01-01T23:59:59.000Z

363

Vapor deposition of thin films  

DOE Patents [OSTI]

A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

1992-01-01T23:59:59.000Z

364

Improving the Thermal Output Availability of Reciprocating Engine Cogeneration Systems by Mechanical Vapor Compression  

E-Print Network [OSTI]

LOW?PRESSURE I WASTE STEAM r ... IMPROVING THE THERMAL OUTPUT AVAILABILITY OF RECIPROCATING ENGINE COGENERATION SYSTEMS BY MECHANICAL VAPOR COMPRESSION F.E. Becker and F.A. DiBella Tecogen, Inc., a Subsidiary of Thermo El~ctron Corporation...-user with electric power and process heat that is totally in the form of high-pressure steam. Current recipro cating engine systems can now provide only low pressure steam or hot water from the engine jacket, and this often is not needed or not the most appro...

Becker, F. E.; DiBella, F. A.; Lamphere, F.

365

Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up  

SciTech Connect (OSTI)

Washington University in St. Louis and its project partners are developing a unique pressurized oxy-combustion process that aims to improve efficiency and costs by reducing the recycling of flue gas to near zero. Normally, in the absence of recycled flue gas or another inert gas, combustion of fuel and oxygen results in a dramatic increase in temperature of the combustion products and radiant energy, as compared to combustion in air. High heat flux to the boiler tubes may result in a tube surface temperatures that exceed safe operating limits. In the Staged Pressurized Oxy-Combustion (SPOC) process, this problem is addressed by staging the delivery of fuel and by novel combustion design that allows control of heat flux. In addition, the main mode of heat transfer to the steam cycle is by radiation, as opposed to convection. Therefore, the requirement for recycling large amounts of flue gas, for temperature control or to improve convective heat transfer, is eliminated, resulting in a reduction in auxiliary loads. The following report contains a detailed summary of scientific findings and accomplishments for the period of Oct. 1, 2013 to Sept 30, 2014. Results of ASPEN process and CFD modelling activities aimed at improving the SPOC process and boiler design are presented. The effects of combustion pressure and fuel moisture on the plant efficiency are discussed. Combustor pressure is found to have only a minor impact beyond 16 bar. For fuels with moisture content greater than approx 30%, e.g. coal/water slurries, the amount of latent heat of condensation exceeds that which can be utilized in the steam cycle and plant efficiency is reduced significantly. An improved boiler design is presented that achieves a more uniform heat flux profile. In addition, a fundamental study of radiation in high-temperature, high-pressure, particle-laden flows is summarized which provides a more complete understanding of heat transfer in these unusual conditions and to allow for optimization. The results reveal that for the SPOC design, absorption and emission due to particles is the dominant factor for determining the wall heat flux. The mechanism of “radiative trapping” of energy within the high-temperature flame region and the approach to utilizing this mechanism to control wall heat flux are described. This control arises, by design, from the highly non-uniform (non-premixed) combustion characteristics within the SPOC boiler, and the resulting gradients in temperature and particle concentration. Finally, a simple method for estimating the wall heat flux in pressurized combustion systems is presented.

Axelbaum, Richard; Xia, Fei; Gopan, Akshay; Kumfer, Benjamin

2014-09-30T23:59:59.000Z

366

Apparatus and method for enhanced chemical processing in high pressure and atmospheric plasmas produced by high frequency electromagnetic waves  

DOE Patents [OSTI]

An apparatus and method for creating high temperature plasmas for enhanced chemical processing of gaseous fluids, toxic chemicals, and the like, at a wide range of pressures, especially at atmospheric and high pressures includes an electro-magnetic resonator cavity, preferably a reentrant cavity, and a wave guiding structure which connects an electro-magnetic source to the cavity. The cavity includes an intake port and an exhaust port, each having apertures in the conductive walls of the cavity sufficient for the intake of the gaseous fluids and for the discharge of the processed gaseous fluids. The apertures are sufficiently small to prevent the leakage of the electro-magnetic radiation from the cavity. Gaseous fluid flowing from the direction of the electro-magnetic source through the guiding wave structure and into the cavity acts on the plasma to push it away from the guiding wave structure and the electro-magnetic source. The gaseous fluid flow confines the high temperature plasma inside the cavity and allows complete chemical processing of the gaseous fluids at a wide range of pressures.

Efthimion, Philip C. (Bedminister, NJ); Helfritch, Dennis J. (Flemington, NJ)

1989-11-28T23:59:59.000Z

367

DEVELOPMENT OF A LOW PRESSURE, AIR ATOMIZED OIL BURNER WITH HIGH ATOMIZER AIR FLOW  

SciTech Connect (OSTI)

This report describes technical advances made to the concept of a low pressure, air atomized oil burner for home heating applications. Currently all oil burners on the market are of the pressure atomized, retention head type. These burners have a lower firing rate limit of about 0.5 gallons per hour of oil, due to reliability problems related to small flow passage sizes. High pressure air atomized burners have been shown to be one route to avoid this problem but air compressor cost and reliability have practically eliminated this approach. With the low pressure air atomized burner the air required for atomization can be provided by a fan at 5--8 inches of water pressure. A burner using this concept, termed the Fan-Atomized Burner or FAB has been developed and is currently being commercialized. In the head of the FAB, the combustion air is divided into three parts, much like a conventional retention head burner. This report describes development work on a new concept in which 100% of the air from the fan goes through the atomizer. The primary advantage of this approach is a great simplification of the head design. A nozzle specifically sized for this concept was built and is described in the report. Basic flow pressure tests, cold air velocity profiles, and atomization performance have been measured. A burner head/flame tube has been developed which promotes a torroidal recirculation zone near the nozzle for flame stability. The burner head has been tested in several furnace and boiler applications over the tiring rate range 0.2 to 0.28 gallons per hour. In all cases the burner can operate with very low excess air levels (under 10%) without producing smoke. Flue gas NO{sub x} concentration varied from 42 to 62 ppm at 3% 0{sub 2}. The concept is seen as having significant potential and planned development efforts are discussed.

BUTCHER,T.A.

1998-01-01T23:59:59.000Z

368

Vapor-liquid equilibria for methanol + tetraethylene glycol dimethyl ether  

SciTech Connect (OSTI)

Vapor-liquid equilibrium (P-T-x) for the methanol + tetraethylene glycol dimethyl ether binary system were obtained by the static method in the range of temperatures from 293.15 to 423.15 K at 10 K intervals. The modified vapor pressure apparatus used is described. The Kuczynsky method was used to calculate the liquid and vapor composition and the activity coefficients of methanol from the initial composition of the sample and the measured pressure and temperature. The results were correlated by the NRTL and UNIQUAC temperature dependent activity coefficient models. This system shows nearly ideal behavior at 323.15 K, but positive deviations from ideality at lower temperatures and negative deviations at higher temperatures are observed. The activity coefficients become more negative with the increase in temperature and mole fraction of methanol. The excess molar enthalpy using the Gibss-Helmholtz equation and the NRTL and UNIQUAC parameters were calculated at 303.15 K and compared with experimental data. This binary system shows promise as a working pair for high-temperature heat pump applications.

Esteve, X.; Chaudhari, S.K.; Coronas, A. [Univ. Rovira i Virgili, Tarragona (Spain). Dept. of Electrical and Mechanical Engineering

1995-11-01T23:59:59.000Z

369

Engineering properties of miniature cement - fly ash compacts prepared by high pressure compaction  

E-Print Network [OSTI]

ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY HDOBPvvIi va vGI ge(iD(vI oannItI au NId(R E)L xrP1IeRPvT 9(evP(n uDnuPnnBIrv au vGI eI0DPeIBIrvR uae vGI i...IteII au LEHNFA -M Ho2FYoF EDtDRv 3456 L(7ae HDO7I8v? oP1Pn FrtPrIIePrt ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY E99ea1Ii (R va RvTnI (ri 8arvIrv OT? LP...

Bormann, Jeffrey Ray

1985-01-01T23:59:59.000Z

370

High Pressure Water Jet System Performance Assessment Project A-2A  

SciTech Connect (OSTI)

Performance assessment for canister cleaning system in the KE Basin. Information obtained from this assessment will be used to design any additional equipment used to clean canisters. After thorough review of the design, maintenance history and operational characteristics of the 105 K East (KE) canister cleaning system, Bartlett recommends that the high pressure water jet system (HPWJS) be modified as outlined in section 5.0, and retained for future use. Further, it is recommended that Spent Nuclear Fuel (SNF) Project consider use of a graded approach for canister cleaning, based on individual canister type and characteristics. This approach would allow a simple method to be used on canisters not needing the more rigorous, high-pressure method. Justification is provided in section 5.0. Although Bartlett has provided some preliminary cost estimates, it is recommended that SNF Project perform a detailed cost-benefit analysis to weigh the alternatives presented.

FARWICK, C.C.

1999-12-03T23:59:59.000Z

371

Ground state properties and high pressure behavior of plutonium dioxide: Systematic density functional calculations  

E-Print Network [OSTI]

Plutonium dioxide is of high technological importance in nuclear fuel cycle and is particularly crucial in long-term storage of Pu-based radioactive waste. Using first-principles density-functional theory, in this paper we systematically study the structural, electronic, mechanical, thermodynamic properties, and pressure induced structural transition of PuO$_{2}$. To properly describe the strong correlation in the Pu $5f$ electrons, the local density approximation$+U$ and the generalized gradient approximation$+U$ theoretical formalisms have been employed. We optimize the $U$ parameter in calculating the total energy, lattice parameters, and bulk modulus at the nonmagnetic, ferromagnetic, and antiferromagnetic configurations for both ground state fluorite structure and high pressure cotunnite structure. The best agreement with experiments is obtained by tuning the effective Hubbard parameter $U$ at around 4 eV within the LDA$+U$ approach. After carefully testing the validity of the ground state, we further in...

Zhang, Ping; Zhao, Xian-Geng

2010-01-01T23:59:59.000Z

372

High-Q silica zipper cavity for optical radiation pressure driven MOMS switch  

SciTech Connect (OSTI)

We design a silica zipper cavity that has high optical and mechanical Q (quality factor) values and demonstrate numerically the feasibility of a radiation pressure driven micro opto-mechanical system (MOMS) directional switch. The silica zipper cavity has an optical Q of 4.0 × 10{sup 4} and an effective mode volume V{sub mode} of 0.67?{sup 3} when the gap between two cavities is 34 nm. The mechanical Q (Q{sub m}) is determined by thermo-elastic damping and is 2.0 × 10{sup 6} in a vacuum at room temperature. The opto-mechanical coupling rate g{sub OM} is as high as 100 GHz/nm, which allows us to move the directional cavity-waveguide system and switch 1550-nm light with 770-nm light by controlling the radiation pressure.

Tetsumoto, Tomohiro; Tanabe, Takasumi, E-mail: takasumi@elec.keio.ac.jp [Department of Electronics and Electrical Engineering, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi Kohoku, Yokohama 223-8522 (Japan)

2014-07-15T23:59:59.000Z

373

The NEXT experiment: A high pressure xenon gas TPC for neutrinoless double beta decay searches  

E-Print Network [OSTI]

Neutrinoless double beta decay is a hypothetical, very slow nuclear transition in which two neutrons undergo beta decay simultaneously and without the emission of neutrinos. The importance of this process goes beyond its intrinsic interest: an unambiguous observation would establish a Majorana nature for the neutrino and prove the violation of lepton number. NEXT is a new experiment to search for neutrinoless double beta decay using a radiopure high-pressure xenon gas TPC, filled with 100 kg of Xe enriched in Xe-136. NEXT will be the first large high-pressure gas TPC to use electroluminescence readout with SOFT (Separated, Optimized FuncTions) technology. The design consists in asymmetric TPC, with photomultipliers behind a transparent cathode and position-sensitive light pixels behind the anode. The experiment is approved to start data taking at the Laboratorio Subterr\\'aneo de Canfranc (LSC), Spain, in 2014.

D. Lorca; J. Martín-Albo; F. Monrabal; for the NEXT Collaboration

2012-10-15T23:59:59.000Z

374

Computations of high-pressure steam flow in the turbine bypass valve  

SciTech Connect (OSTI)

The objective of the present study is to investigate the steam flow behavior through the high-pressure turbine bypass valve. Efforts have mainly been directed at investigating the process of steam flow and property variations aforementioned bypass valve as well as to obtain correlations between the flow rate and the valve opening ratio. Modeling of the high-pressure turbulent steam flow was performed on a three-dimensional non-staggered grid system by employing the finite volume method and by solving the three-dimensional, turbulent, compressible Navier-Stokes, and energy equations. Through this research, numerous data have been acquired and analyzed. These efforts enable one to obtain a correlation data set for the valve opening versus flow rate coefficient of the valve. One of the significant accomplishments is to use the model presented here to further improve a design of a turbine bypass flow valve.

Amano, R.S.; Draxler, G.R.

1999-07-01T23:59:59.000Z

375

Engine having hydraulic and fan drive systems using a single high pressure pump  

DOE Patents [OSTI]

An engine comprises a hydraulic system attached to an engine housing that includes a high pressure pump and a hydraulic fluid flowing through at least one passageway. A fan drive system is also attached to the engine housing and includes a hydraulic motor and a fan which can move air over the engine. The hydraulic motor includes an inlet fluidly connected to the at least one passageway.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2000-01-01T23:59:59.000Z

376

Ion current detector for high pressure ion sources for monitoring separations  

DOE Patents [OSTI]

The present invention relates generally to any application involving the monitoring of signal arising from ions produced by electrospray or other high pressure (>100 torr) ion sources. The present invention relates specifically to an apparatus and method for the detection of ions emitted from a capillary electrophoresis (CE) system, liquid chromatography, or other small-scale separation methods. And further, the invention provides a very simple diagnostic as to the quality of the separation and the operation of an electrospray source. 7 figs.

Smith, R.D.; Wahl, J.H.; Hofstadler, S.A.

1996-08-13T23:59:59.000Z

377

Impedance-matching experiments using high-pressure, laser-driven shock waves  

SciTech Connect (OSTI)

A high-power laser was used to produce shock waves with pressures of 300 to 700 GPa. A series of impedance-matching experiments on aluminum-copper systems with 10% accuracy indicate several areas in which the experiment can be improved to reduce the errors. Several such improvements are now being made, including upgrading both the laser and recording systems and modifying the target characterization techniques.

Veeser, L.R.; Reeves, G.A.; Holmes, N.C.; Trainor, R.J.; Anderson, R.A.

1981-01-01T23:59:59.000Z

378

Investigation of a high pressure implosive technique for metal powder compaction  

E-Print Network [OSTI]

Permanent Address ? 314 Brookside Dr. , Bryan, Texas 77801 Donald R. Garrett received his Bachelor of Science degree from the United States Military Academy in 1958. Mr. Garrett was a military training instructor in the U. S. A. F. and a jet aircraft in...INVESTIGATION OF A HIGH PRESSURE IMPLOSIVE TECHNIQUE FOR METAL POWDER COMPACTION A Thesis DONALD RICHARD GARRETT Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER...

Garrett, Donald Richard

1970-01-01T23:59:59.000Z

379

High-R Walls for New Construction Structural Performance: Wind Pressure Testing  

SciTech Connect (OSTI)

This technical report is focused primarily on laboratory testing that evaluates wind pressure performance characteristics for wall systems constructed with exterior insulating sheathing. This research and test activity will help to facilitate the ongoing use of non-structural sheathing options and provide a more in-depth understanding of how wall system layers perform in response to high wind perturbations normal to the surface.

DeRenzis, A.; Kochkin, V.

2013-01-01T23:59:59.000Z

380

Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

Moskovitz, Yevgeny [Middle Tennessee State University; Yang, Hui [Middle Tennessee State University

2015-01-01T23:59:59.000Z

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381

MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.  

SciTech Connect (OSTI)

Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

Dugger, Michael T.; Asay, David B.; Kim, Seong H.

2008-01-01T23:59:59.000Z

382

High-pressure shock behavior of WC and Ta2O5 powders.  

SciTech Connect (OSTI)

Planar shock experiments were conducted on granular tungsten carbide (WC) and tantalum oxide (Ta{sub 2}O{sub 5}) using the Z machine and a 2-stage gas gun. Additional shock experiments were also conducted on a nearly fully dense form of Ta{sub 2}O{sub 5}. The experiments on WC yield some of the highest pressure results for granular materials obtained to date. Because of the high distention of Ta{sub 2}O{sub 5}, the pressures obtained were significantly lower, but the very high temperatures generated led to large contributions of thermal energy to the material response. These experiments demonstrate that the Z machine can be used to obtain accurate shock data on granular materials. The data on Ta{sub 2}O{sub 5} were utilized in making improvements to the P-{lambda} model for high pressures; the model is found to capture the results not only of the Z and gas gun experiments but also those from laser experiments on low density aerogels. The results are also used to illustrate an approach for generating an equation of state using only the limited data coming from nanoindentation. Although the EOS generated in this manner is rather simplistic, for this material it gives reasonably good results.

Knudson, Marcus D. (Sandia National Laboratories, Albuquerque, NM); Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Root, Seth (Sandia National Laboratories, Albuquerque, NM)

2011-10-01T23:59:59.000Z

383

Five-dimensional visualization of phase transition in BiNiO{sub 3} under high pressure  

SciTech Connect (OSTI)

Colossal negative thermal expansion was recently discovered in BiNiO{sub 3} associated with a low density to high density phase transition under high pressure. The varying proportion of co-existing phases plays a key role in the macroscopic behavior of this material. Here, we utilize a recently developed X-ray Absorption Near Edge Spectroscopy Tomography method and resolve the mixture of high/low pressure phases as a function of pressure at tens of nanometer resolution taking advantage of the charge transfer during the transition. This five-dimensional (X, Y, Z, energy, and pressure) visualization of the phase boundary provides a high resolution method to study the interface dynamics of high/low pressure phase.

Liu, Yijin, E-mail: liuyijin@slac.stanford.edu, E-mail: wyang@ciw.edu [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Wang, Junyue; Yang, Wenge, E-mail: liuyijin@slac.stanford.edu, E-mail: wyang@ciw.edu [Center of High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); High Pressure Synergetic Consortium, Geophysical Laboratory, Carnegie Institution of Washington, 9700 S Cass Avenue, Argonne, Illinois 60439 (United States); Azuma, Masaki [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503 (Japan); Mao, Wendy L. [Geological and Environmental Sciences, 450 Serra Mall, Stanford University, Stanford, California 94305 (United States); SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Photon Science, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States)

2014-01-27T23:59:59.000Z

384

Ultra high pressure liquid chromatography column permeability and changes of the eluent properties  

SciTech Connect (OSTI)

The behavior of four similar liquid chromatography columns (2.1 mm i.d. x30, 50, 100, and 150 mm, all packed with fine particles, average d{sub p} {approx} 1.7 {micro}m, of bridged ethylsiloxane/silica hybrid-C{sub 18}, named BEH-C{sub 18}) was studied in wide ranges of temperature and pressure. The pressure and the temperature dependencies of the viscosity and the density of the eluent (pure acetonitrile) along the columns were also derived, using the column permeabilities and applying the Kozeny-Carman and the heat balance equations. The heat lost through the external surface area of the chromatographic column was directly derived from the wall temperature of the stainless steel tube measured with a precision of C in still air and C in the oven compartment. The variations of the density and viscosity of pure acetonitrile as a function of the temperature and pressure was derived from empirical correlations based on precise experimental data acquired between 298 and 373 K and at pressures up to 1.5 kbar. The measurements were made with the Acquity UPLC chromatograph that can deliver a maximum flow rate of 2 mL/min and apply a maximum column inlet pressure of 1038 bar. The average Kozeny-Carman permeability constant of the columns was 144 {+-} 3.5%. The temperature hence the viscosity and the density profiles of the eluent along the column deviate significantly from linear behavior under high-pressure gradients. For a 1000 bar pressure drop, we measured {Delta}T = 25-30 K, ({Delta}{eta}/{eta}) {approx_equal} 100%, and ({Delta}{rho}/{rho}) {approx_equal} 10%. These results show that the radial temperature profiles are never fully developed within 1% for any of the columns, even under still-air conditions. This represents a practical advantage regarding the apparent column efficiency at high flow rates, since the impact of the differential analyte velocity between the column center and the column wall is not maximum. The interpretation of the peak profiles recorded in UPLC is discussed.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

2008-01-01T23:59:59.000Z

385

Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas  

SciTech Connect (OSTI)

Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

Lee, S.H.D.; Swift, W.M.; Johnson, I.

1980-01-01T23:59:59.000Z

386

Effects of high pressure-dependent leakoff and high process-zone stress in coal-stimulation treatments  

SciTech Connect (OSTI)

Hydraulic fracturing in coals has been studied extensively over the last two decades; however, there are factors that were often ignored or incorrectly diagnosed, resulting in screenouts. Assuming that a majority of the perforations are open and there are no problems with the stimulation fluids, screenouts during coal hydraulic-fracture treatments can be attributed to either high pressure-dependent leakoff (PDL), high process-zone stress (PZS) or in some cases both. The objective of this work is to discuss, help identify, and present solutions to address these reservoir-related issues such that screenouts can be avoided in optimized refracture treatments and new well stimulations. The tools for identifying these reservoir-related parameters include a diagnostic fracture-injection test (DFIT) and a grid-oriented fully functional 3D fracture simulator with shear decoupling. An example for each respective case is presented in this paper. In the first example, in which high PZS was considered to be the dominant reason for screenout or pressure out, the well was restimulated successfully by implementing the solutions presented in this paper. In the second example, in which high PDL was considered to be the main reason for screenout, there were several wells in the same project area that exhibited the same behavior resulting in screenouts. After implementing the solutions presented in this paper to address high PDL, all new wells were stimulated successfully without any issues.

Ramurthy, M.; Lyons, B.; Hendrickson, R.B.; Barree, R.D.; Magill, D.R. [Halliburton, Denver, CO (United States)

2009-08-15T23:59:59.000Z

387

High Sensitivity Combined with Extended Structural Coverage of Labile Compounds via Nanoelectrospray Ionization at Subambient Pressures  

SciTech Connect (OSTI)

Subambient pressure ionization with nanoelectrospray (SPIN) has proven to be effective in producing ions with high efficiency and transmitting them to low pressures for high sensitivity mass spectrometry (MS) analysis. Here we present evidence that not only does the SPIN source improve MS sensitivity but also allows for gentler ionization conditions. The gentleness of a conventional heated capillary electrospray ionization (ESI) source and the SPIN source was compared by the liquid chromatography mass spectrometry (LC-MS) analysis of colominic acid. Colominic acid is a mixture of sialic acid polymers of different lengths containing labile glycosidic linkages between monomer units necessitating a gentle ion source. By coupling the SPIN source with high resolution mass spectrometry and using advanced data processing tools, we demonstrate much extended coverage of sialic acid polymer chains as compared to using the conventional ESI source. Additionally we show that SPIN-LC-MS is effective in elucidating polymer features with high efficiency and high sensitivity previously unattainable by the conventional ESI-LC-MS methods. ?

Cox, Jonathan T.; Kronewitter, Scott R.; Shukla, Anil K.; Moore, Ronald J.; Smith, Richard D.; Tang, Keqi

2014-10-07T23:59:59.000Z

388

Apparatus and method for fatigue testing of a material specimen in a high-pressure fluid environment  

DOE Patents [OSTI]

The invention provides fatigue testing of a material specimen while the specimen is disposed in a high pressure fluid environment. A specimen is placed between receivers in an end cap of a vessel and a piston that is moveable within the vessel. Pressurized fluid is provided to compression and tension chambers defined between the piston and the vessel. When the pressure in the compression chamber is greater than the pressure in the tension chamber, the specimen is subjected to a compression force. When the pressure in the tension chamber is greater than the pressure in the compression chamber, the specimen is subjected to a tension force. While the specimen is subjected to either force, it is also surrounded by the pressurized fluid in the tension chamber. In some examples, the specimen is surrounded by hydrogen.

Wang, Jy-An; Feng, Zhili; Anovitz, Lawrence M; Liu, Kenneth C

2013-06-04T23:59:59.000Z

389

Atmospheric pressure plasma jet with high-voltage power supply based on piezoelectric transformer  

SciTech Connect (OSTI)

The dielectric barrier discharge plasma jet, an example of the nonthermal atmospheric pressure plasma jet (APPJ), generates low-temperature plasmas that are suitable for the atomization of volatile species and can also be served as an ionization source for ambient mass and ion mobility spectrometry. A new design of APPJ for mass spectrometry has been built in our group. In these plasma sources magnetic transformers (MTs) and inductors are typically used in power supplies but they present several drawbacks that are even more evident when dealing with high-voltage normally used in APPJs. To overcome these disadvantages, high frequency generators with the absence of MT are proposed in the literature. However, in the case of miniaturized APPJs these conventional power converters, built of ferromagnetic cores and inductors or by means of LC resonant tank circuits, are not so useful as piezoelectric transformer (PT) based power converters due to bulky components and small efficiency. We made and examined a novel atmospheric pressure plasma jet with PT supplier served as ionization source for ambient mass spectrometry, and especially mobile spectrometry where miniaturization, integration of components, and clean plasma are required. The objective of this paper is to describe the concept, design, and implementation of this miniaturized piezoelectric transformer-based atmospheric pressure plasma jet.

Babij, Micha?; Kowalski, Zbigniew W., E-mail: zbigniew.w.kowalski@pwr.wroc.pl; Nitsch, Karol; Gotszalk, Teodor [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27, 50-370 Wroc?aw (Poland)] [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27, 50-370 Wroc?aw (Poland); Silberring, Jerzy [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)] [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)

2014-05-15T23:59:59.000Z

390

Clustering of metal atoms in organic media. 9. High-activity Ni/MgO catalysts prepared by metal vapor methods. Surface area and particle size effects  

SciTech Connect (OSTI)

A metal vapor method was employed to prepare highly dispersed Ni metal catalysts (solvated metal atom dispersed = SMAD catalyst) supported on MgO. Compared with conventional Ni/MgO compositions, the SMAD catalysts showed much greater activities for all reactions studied (hydrogenolysis of methylcyclopentane, MCP; hydrogenation/hydrogenolysis of toluene, TOL; methanation of carbon monoxide, CO; dehydration of isopropyl alcohol, IPA). These high activities for the SMAD catalysts are attributed to the high surface area of Ni on MgO and the high percentage of this Ni in a zero-valent state (reduction degree). Conventional methods for preparing Ni/MgO catalysts did not yield nearly such favorable surface areas or reduction degrees. Nickel particle size effects were observed during hydrogenolysis studies of MCP and hydrogenation studies of TOL. These phenomena are explained by assuming the size of an active Ni particle to be largest for hydrogenolysis of MCP > hydrogenation of TOL > methanation of CO approx. = dehydrogenation of IPA. 8 figures, 2 tables.

Matsuo, K.; Klabunde, K.J.

1982-02-01T23:59:59.000Z

391

High temperature mass spectrometric investigation of the equilibrium vapor composition over three-component mixtures of CsI, NaI, and DyI/sub 3/  

SciTech Connect (OSTI)

The molar composition of the saturated vapor phase over ternary iodides of CsI, NaI, and DyI/sub 3/ at 860 to 1060 K was investigated by means of a mass spectrometer equipped with a Knudsen cell evaporator system. Fragmentation patterns and appearance potentials for the most intense ions were determined. Besides the previously detected fragments in the equilibrium vapor above the two-component systems, fragment ions from the complex molecules NaCsDyI/sub 5/, Na/sub 2/CsDyI/sub 6/, NaCs/sub 2/DyI/sub 6/, and Na/sub 3/Cs/sub 2/DyI/sub 8/ were found. Ion current vs temperature data yielded heats of sublimation: ..delta..H/sub s/ (NaCsDyI/sub 5/)/sub 960K/ = 320 +/- 13 kJ/mol; ..delta..H/sub s/ (Na/sub 2/CsDyI/sub 6/)/sub 960K/ = 325 +/- 11 kJ/mol; ..delta..H/sub s/ (NaCs/sub 2/DyI/sub 6/)/sub 960K/ = 348 +/- 15 kJ/mol; and ..delta..H/sub s/ (Na/sub 3/Cs/sub 2/DyI/sub 8/)/sub 960K/ = 366 +/- 17 kJ/mol. From the various high-temperature equilibrium reactions, one may calculate the following heats of formation: ..delta..H/sub f/ (NaCsDyI/sub 5/)/sub g/ = -863 +/- 23 kJ/mol; ..delta..H/sub f/ (Na/sub 2/CsDyI/sub 6/)/sub g/ = -1170 +/- 31 kJ/mol; ..delta..H/sub f/ (NaCs/sub 2/DyI/sub 6/)/sub g/ = -1235 +/- 33 kJ/mol; and ..delta..H/sub f/ (Na/sub 3/Cs/sub 2/DyI/sub 8/) = -1806 +/- 17 kJ/mol.

Kaposi, O.; Szilagyi, J.; Lelik, L.

1984-10-01T23:59:59.000Z

392

Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle  

DOE Patents [OSTI]

The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

Butcher, Thomas A. (Port Jefferson, NY); Celebi, Yusuf (Middle Island, NY); Fisher, Leonard (Colrain, MA)

2000-09-15T23:59:59.000Z

393

Method of physical vapor deposition of metal oxides on semiconductors  

DOE Patents [OSTI]

A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

Norton, David P. (Knoxville, TN)

2001-01-01T23:59:59.000Z

394

Vapor spill pipe monitor  

DOE Patents [OSTI]

The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

Bianchini, G.M.; McRae, T.G.

1983-06-23T23:59:59.000Z

395

Synthesis, structural characterization and high pressure phase transitions of monolithium hydronium sulfate  

SciTech Connect (OSTI)

A three dimensional lithium hydronium sulfate LiSO{sub 4}{center_dot}H{sub 3}O [1], [space group Pna2{sub 1}a=8.7785(12) A, b=9.1297(12) A, c=5.2799(7) A, V=423.16(10) A{sup 3}] was synthesized via solvothermal methods using 1,5-naphthalenedisulfonic acid (1,5-NSA) as the source of sulfate ions. The structure of [1], determined by single crystal X-ray diffraction techniques, consists of corner sharing LiO{sub 4} and SO{sub 4} tetrahedra, forming an anionic 3-D open framework that is charge balanced by hydronium ions positioned within channels running along [001] and forming strong H-bonding with the framework oxygen atoms. Compound [1] undergoes two reversible phase transitions, involving reorientation of SO{sub 4}{sup 2-} ions at pressures of approximately 2.5 and 5 GPa at room temperature, as evident from characteristic discontinuous frequency drops in the {nu}{sub 1} mode of the Raman spectra. Additionally, compound [1] forms dense {beta}-lithium sulfate at 300 Degree-Sign C, as evident from temperature dependent powder XRD and combined reversible TGA-DSC experiments. - Graphical abstract: Left: View of corner-shared LiO{sub 4} and SO{sub 4} tetrahedra along [001] direction with hydronium ions situated in the channels. Right: (a) Photograph of the loaded DAC (b) Ambient pressure Raman spectrum of compound [1] (c) Evolution of the {nu}{sub 1} mode with the increasing and decreasing pressure indicating transitions to high-pressure phases at {approx}2.5 (red curves) and {approx}5 GPa (blue curves) and at {approx}3.5 GPa upon decompression. Highlights: Black-Right-Pointing-Pointer A 3-D lithium hydronium sulfate is synthesized by solvothermal methods. Black-Right-Pointing-Pointer Two high pressure phase transition occurs due to rotation of sulfate groups. Black-Right-Pointing-Pointer The framework undergoes a high temperature structural transformation, to form {beta}-Li{sub 2}SO{sub 4} phase.

Banerjee, Debasis, E-mail: debasis.banerjee@stonybrook.edu [Department of Chemistry, Stony Brook University, Stony Brook 11794-3400 (United States); Plonka, Anna M. [Department of Geosciences, Stony Brook University, Stony Brook 11794-2100 (United States); Kim, Sun Jin [Nano-Materials Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130-650 (Korea, Republic of); Xu Wenqian [Department of Geosciences, Stony Brook University, Stony Brook 11794-2100 (United States); Parise, John B. [Department of Chemistry, Stony Brook University, Stony Brook 11794-3400 (United States); Mineral Physics Institute, Stony Brook University, Stony Brook, NY 11790-2100 (United States)

2013-01-15T23:59:59.000Z

396

Trace element partitioning between baddeleyite and carbonatite melt at high pressures and high temperatures  

E-Print Network [OSTI]

as the heavy rare earth elements (HREE) prefer to enter baddeleyite rather than carbonate melts (D>1), whereas the light rare earth elements (LREE) and other trace elements behave incompatibly (D in carbonatite melts. Baddeleyite is known to accumulate the high field strength elements (HFSE) and some rare

397

High-temperature treatment of In-doped CZT crystals grown by the high-pressure Bridgman method  

SciTech Connect (OSTI)

We evaluated the effect of high-temperature treatment of Cd0.9Zn0.1Te:In single crystals using Hall-effect measurements, medium- and high-temperature annealing under various deviations from stoichiometry, and infra-red (IR) transmission microscopy Annealing at ~730 K sharply increased the electrical conductivity (by ~1-2 orders-of-magnitude). Plots of the temperature- and cadmium-pressure dependences of the electrical conductivity, carrier concentration, and mobility were obtained. Treating previously annealed Cd-samples under a Te overpressure at 1070 K allowed us to restore their resistance to its initial high values. The main difference in comparing this material with CdTe was its lowered electron density. We explained our results within the framework of Kröger’s theory of quasi-chemical reactions between point defects in solids.

Bolotnikov A.; Fochuk, P.; Nakonechnyi, I.; Kopach, O.; Verzhak, Ye.; Panchuk, O.; Komar, V.; Terzin, I.; Kutnij, V.; Rybka, A.; Nykoniuk, Ye.; Camarda, G.C.; Cui, Y.; Hossain, A.; Kim, K.H.; Yang, G.; James, R.B.

2012-08-12T23:59:59.000Z

398

Method and apparatus for pressurizing vaporous fluids  

DOE Patents [OSTI]

Pump apparatus according to the present invention may comprise a pump body having a bore therein and a piston mounted within the bore so that the piston may be reciprocated within the bore between first and second positions. A sleeve seal assembly mounted to the pump body contacts the piston as the piston moves between the first and second positions. A piston seal assembly mounted to the piston contacts the bore in the pump body and is located on the piston so that the piston seal assembly does not contact the sleeve seal assembly as the piston is reciprocated between the first and second positions within the bore of the pump body.

Bingham, Dennis N. (Idaho Falls, ID); Ferguson, Russell L. (Idaho Falls, ID)

2001-01-01T23:59:59.000Z

399

Complete temperature profiles in ultra-high pressure liquid chromatography columns  

SciTech Connect (OSTI)

The temperature profiles were calculated along and across seven packed columns (lengths 30, 50, 100, and 150 mm, i.d., 1 and 2.1 mm, all packed with Acquity UPLC, BEH-C{sub 18} particles, average d{sub p} {approx} 1.7 {micro}m) and their stainless steel tubes (o.d. 4.53 and 6.35 mm). These columns were kept horizontal and sheltered from forced air convection (i.e., under still air conditions), at room temperature. They were all percolated with pure acetonitrile, either under the maximum pressure drop (1034 bar) or at the maximum flow rate (2 mL/min) permitted by the chromatograph. The heat balance equation of chromatographic columns was discretized and solved numerically with minimum approximation. Both the compressibility and the thermal expansion of the eluent were taken into account. The boundary conditions were determined from the experimental measurements of the column inlet pressure and of the temperature profile along the column wall, which were made with a precision better than {+-}0.1 K. These calculation results provide the 3-D temperature profiles along and across the columns. The axial and radial temperature gradients are discussed in relationship with the experimental conditions used. The temperature map obtained permits a prediction of the chromatographic data obtained under a very high pressure gradient.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

2008-01-01T23:59:59.000Z

400

Use of Z-pinch sources for high-pressure shock wave studies  

SciTech Connect (OSTI)

In this paper, we will discuss the use of z-pinch sources for shock wave studies at multi-Mbar pressures. Experimental plans to use the technique for absolute shock Hugoniot measurements are discussed. Recent developments have demonstrated the use of pulsed power techniques for producing intense radiation sources (Z pinches) for driving planar shock waves in samples with spatial dimensions significantly larger than possible with other radiation sources. Initial indications are that using Z pinch sources for producing Planckian radiation sources in secondary hohlraums can be used to drive shock waves in samples with diameters to a few millimeters and thickness approaching one millimeter in thickness. These dimensions provides the opportunity to measure both shock velocity and the particle velocity behind the shock front with accuracy comparable to that obtained with gun launchers. In addition, the peak hohlraum temperatures of nearly 150 eV that are now possible with Z pinch sources result in shock wave pressures approaching 45 Mbar in high impedance materials such as tungsten and 10-15 Mbar in low impedance materials such as aluminum and plastics. In this paper, we discuss the use of Z pinch sources for making accurate absolute EOS measurements in the megabar pressure range.

Konrad, C.H.; Asay, J.R.; Hall, C.A. [and others

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
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401

Low loss hollow optical-waveguide connection from atmospheric pressure to ultra-high vacuum  

SciTech Connect (OSTI)

A technique for optically accessing ultra-high vacuum environments, via a photonic-crystal fiber with a long small hollow core, is described. The small core and the long bore enable a pressure ratio of over 10{sup 8} to be maintained between two environments, while permitting efficient and unimpeded delivery of light, including ultrashort optical pulses. This delivery can be either passive or can encompass nonlinear optical processes such as optical pulse compression, deep UV generation, supercontinuum generation, or other useful phenomena.

Ermolov, A.; Mak, K. F.; Tani, F.; Hölzer, P.; Travers, J. C. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany)] [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Russell, P. St. J. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany) [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Department of Physics, University of Erlangen-Nuremberg, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany)

2013-12-23T23:59:59.000Z

402

All graphene electromechanical switch fabricated by chemical vapor deposition  

E-Print Network [OSTI]

We demonstrate an electromechanical switch comprising two polycrystalline graphene films; each deposited using ambient pressure chemical vapor deposition. The top film is pulled into electrical contact with the bottom film ...

Milaninia, Kaveh M.

403

Overview of chemical vapor infiltration  

SciTech Connect (OSTI)

Chemical vapor infiltration (CVI) is developing into a commercially important method for the fabrication of continuous filament ceramic composites. Current efforts are focused on the development of an improved understanding of the various processes in CVI and its modeling. New approaches to CVI are being explored, including pressure pulse infiltration and microwave heating. Material development is also proceeding with emphasis on improving the oxidation resistance of the interfacial layer between the fiber and matrix. This paper briefly reviews these subjects, indicating the current state of the science and technology.

Besmann, T.M.; Stinton, D.P.; Lowden, R.A.

1993-06-01T23:59:59.000Z

404

High speed door assembly  

DOE Patents [OSTI]

A high speed door assembly is described, comprising an actuator cylinder and piston rods, a pressure supply cylinder and fittings, an electrically detonated explosive bolt, a honeycomb structured door, a honeycomb structured decelerator, and a structural steel frame encasing the assembly to close over a 3 foot diameter opening within 50 milliseconds of actuation, to contain hazardous materials and vapors within a test fixture.

Shapiro, C.

1993-04-27T23:59:59.000Z

405

High speed door assembly  

DOE Patents [OSTI]

A high speed door assembly, comprising an actuator cylinder and piston rods, a pressure supply cylinder and fittings, an electrically detonated explosive bolt, a honeycomb structured door, a honeycomb structured decelerator, and a structural steel frame encasing the assembly to close over a 3 foot diameter opening within 50 milliseconds of actuation, to contain hazardous materials and vapors within a test fixture.

Shapiro, Carolyn (Idaho Falls, ID)

1993-01-01T23:59:59.000Z

406

High-pressure coal fuel processor development. Task 1, Proof of principle testing  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

407

A compact bellows-driven diamond anvil cell for high-pressure, low-temperature magnetic measurements  

SciTech Connect (OSTI)

We present the design of an efficient bellows-controlled diamond anvil cell that is optimized for use inside the bores of high-field superconducting magnets in helium-3 cryostats, dilution refrigerators, and commercial physical property measurement systems. Design of this non-magnetic pressure cell focuses on in situ pressure tuning and measurement by means of a helium-filled bellows actuator and fiber-coupled ruby fluorescence spectroscopy, respectively. We demonstrate the utility of this pressure cell with ac susceptibility measurements of superconducting, ferromagnetic, and antiferromagnetic phase transitions to pressures exceeding 8 GPa. This cell provides an opportunity to probe charge and magnetic order continuously and with high resolution in the three-dimensional Magnetic Field–Pressure–Temperature parameter space.

Feng, Yejun [The Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [The Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States); Silevitch, D. M.; Rosenbaum, T. F. [The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)] [The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)

2014-03-15T23:59:59.000Z

408

Fuel vapor control device  

SciTech Connect (OSTI)

A fuel vapor control device is described having a valve opening and closing a passage connecting a carburetor and a charcoal canister according to a predetermined temperature. A first coil spring formed by a ''shape memory effect'' alloy is provided to urge the valve to open the passage when the temperature is high. A second coil spring urges the valve to close the passage. A solenoid is provided to urge an armature against the valve to close the passage against the force of the first coil spring when the engine is running. The solenoid heats the first coil spring to generate a spring force therein when the engine is running. When the engine is turned off, the solenoid is deactivated, and the force of the first spring overcomes the force of the second spring to open the passage until such time as the temperature of the first spring drops below the predetermined temperature.

Ota, I.; Nishimura, Y.; Nishio, S.; Yogo, K.

1987-10-20T23:59:59.000Z

409

LNG fire and vapor control system technologies  

SciTech Connect (OSTI)

This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

1982-06-01T23:59:59.000Z

410

High-Throughput Thin Film Approach for Screening of Temperature-Pressure-Composition Phase Space  

SciTech Connect (OSTI)

Many solar energy technologies, for example CIGS and CdTe photovoltaics, utilize materials in thin film form. The equilibrium phase diagrams for these and other more novel solar energy materials are not known or are irrelevant because of the non-equilibrium character of the thin film growth processes. We demonstrate a high-throughput thin film approach for screening of temperature-pressure-composition phase diagrams and phase spaces. The examples in focus are novel solar absorbers Cu-N, Cu-O and p-type transparent conductors in the Cr2O3-MnO system. The composition axis of the Cr2O3-MnO phase diagram was screened using a composition spread method. The temperature axis of the Mn-O phase diagram was screened using a temperature spread method. The pressure axes of the Cu-N and Cu-O phase diagrams were screened using rate spread method with the aid of non-equilibrium growth phenomena. Overall these three methods constitute an approach to high-throughput screening of inorganic thin film phase diagrams. This research is supported by U.S. Department of Energy as a part of two NextGen Sunshot projects and an Energy Frontier Research Center.

Zakutayev, A.; Subramaniyan, A.; Caskey, C. M.; Ndione, P. F.; Richards, R. M.; O'Hayre, R.; Ginley, D. S.

2013-01-01T23:59:59.000Z

411

Vapor spill monitoring method  

DOE Patents [OSTI]

Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

1985-01-01T23:59:59.000Z

412

Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle  

SciTech Connect (OSTI)

Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

Hosni, Mohammad H.

2014-03-30T23:59:59.000Z

413

On the Diurnal Cycle of Deep Convection, High-Level Cloud, and Upper Troposphere Water Vapor in the Multiscale Modeling Framework  

SciTech Connect (OSTI)

The Multiscale Modeling Framework (MMF), also called ‘‘superparameterization’’, embeds a cloud-resolving model (CRM) at each grid column of a general circulation model to replace traditional parameterizations of moist convection and large-scale condensation. This study evaluates the diurnal cycle of deep convection, high-level clouds, and upper troposphere water vapor by applying an infrared (IR) brightness temperature (Tb) and a precipitation radar (PR) simulator to the CRM column data. Simulator results are then compared with IR radiances from geostationary satellites and PR reflectivities from the Tropical Rainfall Measuring Mission (TRMM). While the actual surface precipitation rate in the MMF has a reasonable diurnal phase and amplitude when compared with TRMM observations, the IR simulator results indicate an inconsistency in the diurnal anomalies of high-level clouds between the model and the geostationary satellite data. Primarily because of its excessive high-level clouds, the MMF overestimates the simulated precipitation index (PI) and fails to reproduce the observed diurnal cycle phase relationships among PI, high-level clouds, and upper troposphere relative humidity. The PR simulator results show that over the tropical oceans, the occurrence fraction of reflectivity in excess of 20 dBZ is almost 1 order of magnitude larger than the TRMM data especially at altitudes above 6 km. Both results suggest that the MMF oceanic convection is overactive and possible reasons for this bias are discussed. However, the joint distribution of simulated IR Tb and PR reflectivity indicates that the most intense deep convection is found more often over tropical land than ocean, in agreement with previous observational studies.

Zhang, Yunyan; Klein, Stephen A.; Liu, Chuntao; Tian, Baijun; Marchand, Roger T.; Haynes, J. M.; McCoy, Renata; Zhang, Yuying; Ackerman, Thomas P.

2008-08-22T23:59:59.000Z

414

Evolution of Nickel-Manganese-Silicon Dominated Phases in Highly Irradiated Reactor Pressure Vessel Steels  

SciTech Connect (OSTI)

Formation of a high density of Ni-Mn-Si nm-scale precipitates in irradiated reactor pressure vessel steels, both with and without Cu, could lead to severe embrittlement. Models long ago predicted that these precipitates, which are not treated in current embrittlement regulations, would emerge only at high fluence. However, the mechanisms and variables that control Ni-Mn- Si precipitate formation, and their detailed characteristics, have not been well understood. High flux irradiations of six steels with systematic variations in Cu and Ni were carried out at ˜ 295±5°C to high and very high neutron fluences of ˜ 1.3x1020 and 1.1x1021 n/cm2. Atom probe tomography (APT) shows that significant mole fractions of these precipitates form in the Cu bearing steels at ˜ 1.3x1020 n/cm2, while they are only beginning to develop in Cu-free steels. However, large mole fractions, far in excess of those found in previous studies, are observed at 1.1x1021 n/cm2 at all Cu levels. The precipitates diffract, and in one case are compositionally and structurally consistent with the Mn6Ni16Si7 G-phase. At the highest fluence, the large precipitate mole fractions primarily depend on the steel Ni content, rather than Cu, and lead to enormous strength increases up to about 700 MPa. The implications of these results to light water reactor life extension are discussed briefly.

Peter B Wells; Yuan Wu; Tim Milot; G. Robert Odette; Takuya Yamamoto; Brandon Miller; James Cole

2014-11-01T23:59:59.000Z

415

Engineering development of a lightweight high-pressure scarifier for tank waste retrieval  

SciTech Connect (OSTI)

The Retrieval Process Development and Enhancements Program (RPD&E) is sponsored by the U.S. Department of Energy Tanks Focus Area to investigate existing and emerging retrieval processes suitable for the retrieval of high-level radioactive waste inside underground storage tanks. This program, represented by industry, national laboratories, and academia, seeks to provide a technical and cost basis to support site-remediation decisions. Part of this program has involved the development of a high-pressure waterjet dislodging system and pneumatic conveyance integrated as a scarifier. Industry has used high-pressure waterjet technology for many years to mine, cut, clean, and scarify materials with a broad range of properties. The scarifier was developed as an alternate means of retrieving waste inside Hanford single-shell tanks, particularly hard, stubborn waste. Testing of the scarifier has verified its ability to retrieve a wide range of tank waste ranging from extremely hard waste that is resistant to other dislodging means to soft sludge and even supernatant fluid. Since the scarifier expends water at a low rate and recovers most of the water as it is used, the scarifier is well suited for retrieval of tanks that leak and cannot be safely sluiced or applications where significant waste dilution is not acceptable. Although the original scarifier was effective, it became evident that a lighter, more compact version that would be compatible with light weight deployment systems under development, such as the Light Duty Utility Arm, was needed. At the end of FY 95, the Light Weight Scarifier (LWS) was designed to incorporate the features of the original scarifier in a smaller, lighter end effector. During FY 96, the detailed design of the LWS was completed and two prototypes were fabricated.

Hatchell, B.K.

1997-09-01T23:59:59.000Z

416

Rapid Migration of Radionuclides Leaked from High-Level Water Tanks; A Study of Salinity Gradients, Wetted Path Geometry and Water Vapor Transport  

SciTech Connect (OSTI)

The basis of this study was the hypothesis that the physical and chemical properties of hypersaline tank waste could lead to wetting from instability and fingered flow following a tank leak. Thus, the goal of this project was to develop an understanding of the impacts of the properties of hypersaline fluids on transport through the unsaturated zone beneath Hanford's Tank Farms. There were three specific objectives (i) to develop an improved conceptualization of hypersaline fluid transport in laboratory (ii) to identify the degree to which field conditions mimic the flow processes observed in the laboratory and (iii) to provide a validation data set to establish the degree to which the conceptual models, embodied in a numerical simulator, could explain the observed field behavior. As hypothesized, high ionic strength solutions entering homogeneous pre-wetted porous media formed unstable wetting fronts atypical of low ionic strength infiltration. In the field, this mechanism could for ce flow in vertical flow paths, 5-15 cm in width, bypassing much of the media and leading to waste penetration to greater depths than would be predicted by current conceptual models. Preferential flow may lead to highly accelerated transport through large homogeneous units, and must be included in any conservative analysis of tank waste losses through coarse-textured units. However, numerical description of fingered flow using current techniques has been unreliable, thereby precluding tank-scale 3-D simulation of these processes. A new approach based on nonzero, hysteretic contract angles and fluid-dependent liquid entry has been developed for the continuum scale modeling of fingered flow. This approach has been coupled with and adaptive-grid finite-difference solver to permit the prediction of finger formation and persistence form sub centimeter scales to the filed scale using both scalar and vector processors. Although laboratory experiments demonstrated that elevated surface tens ion of imbibing solutions can enhance vertical fingered flow, this phenomenon was not observed in the field. Field tests showed that the fingered flow behavior was overwhelmed by the variability in texture resulting from differences in the depositional environment. Field plumes were characterized by lateral spreading with an average width to depth aspect ratio of 4. For both vertical fingers and lateral flow, the high ionic strength contributed to the vapor phase dilution of the waste, which increased waste volume and pushed the wetting from well beyond what would have occurred if the volume of material had remained unchanged from that initially released into the system. It was also observed that following significant vapor-phase dilution of this waste simulants that streams of colloids were ejected from the sediment surfaces. It was shown that due to the high-sodium content of the tank wastes the colloids were deflocculated below a critical salt concentration in Hanford sediments. Th e released colloids, which at the site would be expected to carry the bulk of the sorbed heavy metals and radioisotopes, were mobile though coarse Hanford sediments, but clogged finer layers. The developments resulting from this study are already being applied at Hanford in the nonisothermal prediction of the hypersaline, high pH waste migration in tank farms and in the development of inverse methods for history matching under DOE's Groundwater/Vadose Zone Integration Project at Hanford.

Anderson l. Ward; Glendon W. Gee; John S. Selker; Clay Cooper

2002-04-24T23:59:59.000Z

417

Rapid Migration of Radionuclides Leaked from High-Level Water Tanks: A Study of Salinity Gradients, Wetted Path Geometry and Water Vapor Transport  

SciTech Connect (OSTI)

The basis of this study was the hypothesis that the physical and chemical properties of hypersaline tank waste could lead to wetting from instability and fingered flow following a tank leak. Thus, the goal of this project was to develop an understanding of the impacts of the properties of hypersaline fluids on transport through the unsaturated zone beneath Hanford's Tank Farms. There were three specific objectives (i) to develop an improved conceptualization of hypersaline fluid transport in laboratory (ii) to identify the degree to which field conditions mimic the flow processes observed in the laboratory and (iii) to provide a validation data set to establish the degree to which the conceptual models, embodied in a numerical simulator, could explain the observed field behavior. As hypothesized, high ionic strength solutions entering homogeneous pre-wetted porous media formed unstable wetting fronts a typical of low ionic strength infiltration. In the field, this mechanism could force flow in vertical flow paths, 5-15 cm in width, bypassing much of the media and leading to waste penetration to greater depths than would be predicted by current conceptual models. Preferential flow may lead to highly accelerated transport through large homogeneous units, and must be included in any conservative analysis of tank waste losses through coarse-textured units. However, numerical description of fingered flow using current techniques has been unreliable, thereby precluding tank-scale 3-D simulation of these processes. A new approach based on nonzero, hysteretic contact angles and fluid-dependent liquid entry has been developed for the continuum scale modeling of fingered flow. This approach has been coupled with and adaptive-grid finite-difference solver to permit the prediction of finger formation and persistence form sub centimeter scales to the filed scale using both scalar and vector processors. Although laboratory experiments demonstrated that elevated surface tension of imbibing solutions can enhance vertical fingered flow, this phenomenon was not observed in the field. Field tests of showed that the fingered flow behavior was overwhelmed by the variability in texture resulting from differences in the depositional environment. Field plumes were characterized by lateral spreading with an average width to depth aspect ratio of 4. For both vertical fingers and lateral flow, the high ionic strength contributed to the vapor phase dilution of the waste, which increased waste volume and pushed the wetting from well beyond what would have occurred if the volume of material had remained unchanged from that initially released into the system. It was also observed that following significant vapor-phase dilution of the waste simulants that streams of colloids were ejected from the sediment surfaces. It was shown that due to the high-sodium content of the tank wastes the colloids were deflocculated below a critical salt concentration in Hanford sediment s. The released colloids, which at the site would be expected to carry the bulk of the sorbed heavy metals and radioisotopes, were mobile though coarse Hanford sediments, but clogged finer layers. The developments resulting from this study are already being applied at Hanford in the nonisothermal prediction of the hypersaline, high pH waste migration in tank farms and in the development of inverse methods for history matching under DOE's Groundwater/Vadose Zone Integration Project at Hanford.

Anderson L. Ward; Glendon W. Gee; John S. Selker; Caly Cooper

2002-04-24T23:59:59.000Z

418

Solid-vapor adsorption refrigeration system development. Final report, October 1987-September 1988  

SciTech Connect (OSTI)

The report describes the feasibility study of several gas-fired refrigeration cycles using ammoniated complex compounds as the working media. The cycles take advantage of the coordinative characteristic of complex compound ligand bonds which result in large coordination spheres with only one degree of freedom. The coordinative bond yields refrigerant concentration plateaus of constant pressure, which in turn result in high thermal-cycle efficiencies and eliminate electrical parasitics and the requirement for moving parts. Media properties of known complex compound materials were verified with respect to vapor-pressure equilibria, coordination properties, and thermal stability. An existing computer model was used to predict heat balances and coefficients of performance.

Rockenfeller, U.

1988-10-01T23:59:59.000Z

419

The deterioration in heat transfer to fluids at supercritical pressure and high heat fluxes  

E-Print Network [OSTI]

At slightly supercritical pressure and in the neighborhood of the pseudo-critical temperature (defined as the temperature corresponding to the peak in specific heat at the operating pressure), the heat transfer coefficient ...

Shiralkar, B. S.

1968-01-01T23:59:59.000Z

420

Experimental observation of standing wave effect in low-pressure very-high-frequency capacitive discharges  

SciTech Connect (OSTI)

Radial uniformity measurements of plasma density were carried out by using a floating double probe in a cylindrical (21?cm in electrode diameter) capacitive discharge reactor driven over a wide range of frequencies (27–220 MHz). At low rf power, a multiple-node structure of standing wave effect was observed at 130?MHz. The secondary density peak caused by the standing wave effect became pronounced and shifts toward the axis as the driving frequency further to increase, indicative of a much more shortened standing-wave wavelength. With increasing rf power, the secondary density peak shift toward the radial edge, namely, the standing-wave wavelength was increased, in good qualitative agreement with the previous theory and simulation results. At higher pressures and high frequencies, the rf power was primarily deposited at the periphery of the electrode, due to the fact that the waves were strongly damped as they propagated from the discharge edge into the center.

Liu, Yong-Xin; Gao, Fei; Liu, Jia; Wang, You-Nian, E-mail: ynwang@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

2014-07-28T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
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421

Energy savings with solid-state ballasted high-pressure sodium lamps  

SciTech Connect (OSTI)

The performance of three types of solid-state ballasts used to operate high-pressure sodium lamps is discussed. Each type of solid-state ballast has been designed to operate an HPS lamp of a different wattage (150, 200, and 400 watts). The performance of these ballasts compared to standard core-coil ballasts operating the same HPS lamps shows that system efficiency improves as much as 17%. The solid-state ballasted HPS system also demonstrates excellent regulation with respect to input voltage and output power. These new ballasts can dim the HPS lamps and reduce flicker from more than 60% to less than 3%. Refitting street lighting with these new HPS systims provides an attractive return on initial capital investment.

Verderber, R.R.; Morse, O.

1981-04-01T23:59:59.000Z

422

Dynamics of multiple double layers in high pressure glow discharge in a simple torus  

SciTech Connect (OSTI)

Parametric characterization of multiple double layers is done during high pressure glow discharge in a toroidal vessel of small aspect ratio. Although glow discharge (without magnetic field) is known to be independent of device geometry, but the toroidal boundary conditions are conducive to plasma growth and eventually the plasma occupy the toroidal volume partially. At higher anode potential, the visibly glowing spots on the body of spatially extended anode transform into multiple intensely luminous spherical plasma blob structures attached to the tip of the positive electrode. Dynamics of multiple double layers are observed in argon glow discharge plasma in presence of toroidal magnetic field. The radial profiles of plasma parameters measured at various toroidal locations show signatures of double layer formation in our system. Parametric dependence of double layer dynamics in presence of toroidal magnetic field is presented here.

Kumar Paul, Manash, E-mail: manashkr@gmail.com [Department of Physics, National Institute of Technology Agartala, Tripura–799 046 (India); Sharma, P. K.; Thakur, A.; Kulkarni, S. V.; Bora, D. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat–382 428 (India)

2014-06-15T23:59:59.000Z

423

Autoignition of toluene reference fuels at high pressures modeled with detailed chemical kinetics  

SciTech Connect (OSTI)

A detailed chemical kinetic model for the autoignition of toluene reference fuels (TRF) is presented. The toluene submechanism added to the Lawrence Livermore Primary Reference Fuel (PRF) mechanism was developed using recent shock tube autoignition delay time data under conditions relevant to HCCI combustion. For two-component fuels the model was validated against recent high-pressure shock tube autoignition delay time data for a mixture consisting of 35% n-heptane and 65% toluene by liquid volume. Important features of the autoignition of the mixture proved to be cross-acceleration effects, where hydroperoxy radicals produced during n-heptane oxidation dramatically increased the oxidation rate of toluene compared to the case when toluene alone was oxidized. Rate constants for the reaction of benzyl and hydroperoxyl radicals previously used in the modeling of the oxidation of toluene alone were untenably high for modeling of the mixture. To model both systems it was found necessary to use a lower rate and introduce an additional branching route in the reaction between benzyl radicals and O{sub 2}. Good agreement between experiments and predictions was found when the model was validated against shock tube autoignition delay data for gasoline surrogate fuels consisting of mixtures of 63-69% isooctane, 14-20% toluene, and 17% n-heptane by liquid volume. Cross reactions such as hydrogen abstractions between toluene and alkyl and alkylperoxy radicals and between the PRF were introduced for completion of chemical description. They were only of small importance for modeling autoignition delays from shock tube experiments, even at low temperatures. A single-zone engine model was used to evaluate how well the validated mechanism could capture autoignition behavior of toluene reference fuels in a homogeneous charge compression ignition (HCCI) engine. The model could qualitatively predict the experiments, except in the case with boosted intake pressure, where the initial temperature had to be increased significantly in order to predict the point of autoignition. (author)

Andrae, J.C.G. [Department of Chemical Engineering and Technology, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Shell Global Solutions, P.O. Box 1, Chester CH1 3SH (United Kingdom); Bjoernbom, P. [Department of Chemical Engineering and Technology, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Cracknell, R.F.; Kalghatgi, G.T. [Shell Global Solutions, P.O. Box 1, Chester CH1 3SH (United Kingdom)

2007-04-15T23:59:59.000Z

424

High-pressure X-ray diffraction and X-ray emission studies on iron-bearing silicate perovskite under high pressures  

SciTech Connect (OSTI)

Iron-bearing silicate perovskite is believed to be the most abundant mineral of the Earth's lower mantle. Recent studies have shown that Fe{sup 2+} exists predominantly in the intermediate-spin state with a total spin number of 1 in silicate perovskite in the lower part of the lower mantle. Here we have measured the spin states of iron and the pressure-volume relation in silicate perovskite [(Mg{sub 0.6},Fe{sub 0.4})SiO{sub 3}] at pressure conditions relevant to the lowermost mantle using in situ X-ray emission and X-ray diffraction in a diamond cell. Our results showed that the intermediate-spin Fe{sup 2+} is stable in the silicate perovskite up to {approx} 125 GPa but starts to transition to the low-spin state at approximately 135 GPa. Concurrent X-ray diffraction measurements showed a decrease of approximately 1% in the unit cell volume in the silicate perovskite [(Mg{sub 0.6},Fe{sub 0.4})SiO{sub 3}], which is attributed to the intermediate-spin to the low-spin transition. The transition pressure coincides with the pressure conditions of the lowermost mantle, raising the possibility of the existence of the silicate perovskite phase with the low-spin Fe{sup 2+} across the transition from the post-perovskite to the perovskite phases in the bottom of the D{double_prime} layer.

Lin, Jung-Fu; Speciale, Sergio; Prakapenka, Vitali B.; Dera, Przemek; Lavina, Babara; Watson, Heather C. (NIU); (UC); (Texas); (GFZ)

2010-06-22T23:59:59.000Z

425

High pressure elastic properties of minerals from ab initio simulations: The case of pyrope, grossular and andradite silicate garnets  

SciTech Connect (OSTI)

A computational strategy is devised for the accurate ab initio simulation of elastic properties of crystalline materials under pressure. The proposed scheme, based on the evaluation of the analytical stress tensor and on the automated computation of pressure-dependent elastic stiffness constants, is implemented in the CRYSTAL solid state quantum-chemical program. Elastic constants and related properties (bulk, shear and Young moduli, directional seismic wave velocities, elastic anisotropy index, Poisson's ratio, etc.) can be computed for crystals of any space group of symmetry. We apply such a technique to the study of high-pressure elastic properties of three silicate garnet end-members (namely, pyrope, grossular, and andradite) which are of great geophysical interest, being among the most important rock-forming minerals. The reliability of this theoretical approach is proved by comparing with available experimental measurements. The description of high-pressure properties provided by several equations of state is also critically discussed.

Erba, A., E-mail: alessandro.erba@unito.it; Mahmoud, A.; Dovesi, R. [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy)] [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy); Belmonte, D. [DISTAV, Università di Genova, Corso Europa 26, 16132 Genoa (Italy)] [DISTAV, Università di Genova, Corso Europa 26, 16132 Genoa (Italy)

2014-03-28T23:59:59.000Z

426

Advanced Production Surface Preparation Technology Development for Ultra-High Pressure Diesel Injection  

SciTech Connect (OSTI)

In 2007, An Ultra High Injection Pressure (UHIP) fueling method has been demonstrated by Caterpillar Fuel Systems - Product Development, demonstrating ability to deliver U.S. Environment Protection Agency (EPA) Tier 4 Final diesel engine emission performance with greatly reduced emissions handling components on the engine, such as without NOx reduction after-treatment and with only a through-flow 50% effective diesel particulate trap (DPT). They have shown this capability using multiple multi-cylinder engine tests of an Ultra High Pressure Common Rail (UHPCR) fuel system with higher than traditional levels of CEGR and an advanced injector nozzle design. The system delivered better atomization of the fuel, for more complete burn, to greatly reduce diesel particulates, while CEGR or high efficiency NOx reduction after-treatment handles the NOx. With the reduced back pressure of a traditional DPT, and with the more complete fuel burn, the system reduced levels of fuel consumption by 2.4% for similar delivery of torque and horsepower over the best Tier 4 Interim levels of fuel consumption in the diesel power industry. The challenge is to manufacture the components in high-volume production that can withstand the required higher pressure injection. Production processes must be developed to increase the toughness of the injector steel to withstand the UHIP pulsations and generate near perfect form and finish in the sub-millimeter size geometries within the injector. This project resulted in two developments in 2011. The first development was a process and a machine specification by which a high target of compressive residual stress (CRS) can be consistently imparted to key surfaces of the fuel system to increase the toughness of the steel, and a demonstration of the feasibility of further refinement of the process for use in volume production. The second development was the demonstration of the feasibility of a process for imparting near perfect, durable geometry to these same feature surfaces to withstand the pulsating UHIP diesel injection without fatigue failure, through the expected life of the fuel system's components (10,000 hours for the pump and common rail, 5000 hours for the injector). The potential to Caterpillar of this fueling approach and the overall emissions reduction system is the cost savings of the fuel, the cost savings of not requiring a full emissions module and other emissions hardware, and the enabling of the use of biodiesel fuel due to the reduced dependency on after-treatment. A proprietary production CRS generating process was developed to treat the interior of the sac-type injector nozzle tip region (particularly for the sac region). Ninety-five tips passed ultra high pulsed pressure fatigue testing with no failures assignable to treated surfaces or materials. It was determined that the CRS impartation method does not weaken the tip internal seat area. Caterpillar Fuel Systems - Product Development accepts that the CRS method initial production technical readiness level has been established. A method to gage CRS levels in production was not yet accomplished, but it is believed that monitoring process parameters call be used to guarantee quality. A precision profiling process for injector seat and sac regions has been shown to be promising but not yet fully confirmed. It was demonstrated that this precision profiling process can achieve form and geometry to well under an aggressively small micron peak-to-valley and that there are no surface flaws that approach an even tighter micron peak-to-valley tolerance. It is planned to purchase machines to further develop and move the process towards production. The system is targeted towards the high-power diesel electric power generators and high-power diesel marine power generators, with displacement from 20 liters to 80 liters and with power from 800 brake horsepower (BHP) to 3200BHP (0.6 megawatts to 2.4 megawatts). However, with market adoption, this system has the potential to meet EPA exhaust standards for all diesel engines nine liters and up, or 300B

Grant, Marion B.

2012-04-30T23:59:59.000Z

427

Advanced Models of LWR Pressure Vessel Embrittlement for Low Flux-HighFluence Conditions  

SciTech Connect (OSTI)

Neutron embrittlement of reactor pressure vessels (RPVs) is an unresolved issue for light water reactor life extension, especially since transition temperature shifts (TTS) must be predicted for high 80-year fluence levels up to approximately 1,020 n/cm{sup 2}, far beyond the current surveillance database. Unfortunately, TTS may accelerate at high fluence, and may be further amplified by the formation of late blooming phases that result in severe embrittlement even in low-copper (Cu) steels. Embrittlement by this mechanism is a potentially significant degradation phenomenon that is not predicted by current regulatory models. This project will focus on accurately predicting transition temperature shifts at high fluence using advanced physically based, empirically validated and calibrated models. A major challenge is to develop models that can adjust test reactor data to account for flux effects. Since transition temperature shifts depend on synergistic combinations of many variables, flux-effects cannot be treated in isolation. The best current models systematically and significantly under-predict transition temperature at high fluence, although predominantly for irradiations at much higher flux than actual RPV service. This project will integrate surveillance, test reactor and mechanism data with advanced models to address a number of outstanding RPV embrittlement issues. The effort will include developing new databases and preliminary models of flux effects for irradiation conditions ranging from very low (e.g., boiling water reactor) to high (e.g., accelerated test reactor). The team will also develop a database and physical models to help predict the conditions for the formation of Mn-Ni-Si late blooming phases and to guide future efforts to fully resolve this issue. Researchers will carry out other tasks on a best-effort basis, including prediction of transition temperature shift attenuation through the vessel wall, remediation of embrittlement by annealing, and fracture toughness master curve issues.

Odette, G. Robert; Yamamoto, Takuya

2013-06-17T23:59:59.000Z

428

High pressure synthesis of late rare earth RFeAs(O,F) superconductors; R = Tb and Dy   

E-Print Network [OSTI]

New TbFeAs(O,F) and DyFeAs(O,F) superconductors with critical temperatures T-c = 46 and 45 K and very high critical fields, >= 100 T, have been prepared at 1100-1150 degrees C and 10-12 GPa, demonstrating that high pressure may be used to synthesise...

Attfield, J.P.; Huxley A.D.; Sokolov D.A.; Rodgers J.A.; Penny G.B.S.; Bos J.W.G.

2008-01-01T23:59:59.000Z

429

ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR OXIDATION  

E-Print Network [OSTI]

ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR) by devolatilizing Pittsburgh #8 coal at #12;ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) high

Fletcher, Thomas H.

430

Real-gas effects in the expansibility factor for subsonic differential-pressure flowmeters at high pressure  

SciTech Connect (OSTI)

Real-gas corrections in the expansibility factor are expressed by an equation of state (EOS). In this paper a virial EOS is introduced, with low-order virial coefficients calculated from a cubic EOS. The approach is composition-independent. EOS-dependent cancellations between real-gas effects are revealed. The current Intl. Organization for Standardization (ISO) standard is not always reliable for high-accuracy orifice measurements of gases with arbitrary composition.

Finjord, J. (Rogaland U. Center (NO))

1991-08-01T23:59:59.000Z

431

High Temperature and Pressure Steam-H2 Interaction with Candidate Advanced LWR Fuel Claddings  

SciTech Connect (OSTI)

This report summarizes the work completed to evaluate cladding materials that could serve as improvements to Zircaloy in terms of accident tolerance. This testing involved oxidation resistance to steam or H{sub 2}-50% steam environments at 800-1350 C at 1-20 bar for short times. A selection of conventional alloys, SiC-based ceramics and model alloys were used to explore a wide range of materials options and provide guidance for future materials development work. Typically, the SiC-based ceramic materials, alumina-forming alloys and Fe-Cr alloys with {ge}25% Cr showed the best potential for oxidation resistance at {ge}1200 C. At 1350 C, FeCrAl alloys and SiC remained oxidation resistant in steam. Conventional austenitic steels do not have sufficient oxidation resistance with only {approx}18Cr-10Ni. Higher alloyed type 310 stainless steel is protective but Ni is not a desirable alloy addition for this application and high Cr contents raise concern about {alpha}{prime} formation. Higher pressures (up to 20.7 bar) and H{sub 2} additions appeared to have a limited effect on the oxidation behavior of the most oxidation resistant alloys but higher pressures accelerated the maximum metal loss for less oxidation resistant steels and less metal loss was observed in a H{sub 2}-50%H{sub 2}O environment at 10.3 bar. As some of the results regarding low-alloyed FeCrAl and Fe-Cr alloys were unexpected, further work is needed to fundamentally understand the minimum Cr and Al alloy contents needed for protective behavior in these environments in order to assist in alloy selection and guide alloy development.

Pint, Bruce A [ORNL

2012-08-01T23:59:59.000Z

432

High-Pressure Micellar Solutions of Symmetric and Asymmetric Styrene?Diene Diblocks in Compressible Near Critical Solvents: Micellization Pressures and Cloud Pressures Respond but Micellar Cloud Pressures Insensitive to Copolymer Molecular Weight, Concentration, and Block Ratio Changes  

SciTech Connect (OSTI)

Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical nonmicellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Concentration-dependent pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size, and ratio. The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

Winoto, Winoto [University of Wyoming, Laramie; Tan, Sugata [University of Wyoming, Laramie; Shen, Youqin [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

2009-01-01T23:59:59.000Z

433

Time resolved optical spectroscopy to examine chemical decomposition of energetic materials under static high pressure and pulsed heating conditions  

SciTech Connect (OSTI)

The study of the deflagration or detonation reactions of energetic materials is challenging due to the high pressure, high temperature, and time domain under which the reactions occur. Experimental measurements are presented that demonstrate the ability to continuously monitor the global reaction times and reaction sequences associated with chemical reactions under these conditions. Time resolved absorption spectroscopy is used in conjunction with a high pressure gem anvil cell to probe the real-time chemical processes during pulsed-heating. Samples are initiated by a rapid thermal jump induced by absorption of a single laser pulse. Time resolved absorption spectroscopy of 3,6 trinitroethylamine tetrazine reaction is demonstrated by the real time measurement of the decrease in the {pi}-{pi}* absorption at 100 ns temporal resolution during laser heating at pressures up to 3.5 GPa.

Russell, T.P. [Naval Research Lab., Washington, DC (United States). Chemistry Div.; Allen, T.M.; Gupta, Y.M. [Washington State Univ., Pullman, WA (United States). Shock Dynamics Center

1996-07-01T23:59:59.000Z

434

High-pressure Storage Vessels for Hydrogen, Natural Gas andHydrogen...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gas and Blends - Materials Testing and Design Requirements for Hydrogen Components and Tanks International Hydrogen Fuel and Pressure Vessel Forum 2010 Proceedings Hydrogen...

435

Energy Saving in Distillation Using Structured Packing and Vapor Recompression  

E-Print Network [OSTI]

difference across the column. VRC uses hot compressed overhead vapors, instead of steam, to heat the reboiler. Cost savings are highest when the pressure ratio for the compressor is low. The pressure ratio depends on the boiling point difference of top...

Hill, J.H.

436

The effect of high-pressure injection of gas on the reservoir volume factor of a crude oil  

E-Print Network [OSTI]

THE EFFECT OF HIGH-PRESSURE INJECTION OF GAS ON THE RESERVOIR VOLUME FACTOR OF A CRUDE OIL A Thesis By+ BAXTER DS'kONEYCUTT o Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August, i957 Major Subject: Petroleum Engineering THE EFFECT OF HIGH-PRESSURE INJECTION OF GAS ON THE RESERVOIR VOLUME FACTOR OF A CRUDE OIL A Thesis By BAXTER D. HONEYCUTT Appro d as to style...

Honeycutt, Baxter Bewitt

1957-01-01T23:59:59.000Z

437

High-Efficiency, Ultra-High Pressure Electrolysis With Direct Linkage to PV Arrays - Phase II SBIR Final Report  

SciTech Connect (OSTI)

In this Phase II SBIR, Avalence LLC met all proposed objectives. Because the original Phase III partner pulled out of the project, several alternative sites/partners were used to achieve the goals. The on-site operation and PV measurements were performed on a smaller unit at General Motors proving grounds in Milford, MI. The actual equipment targeted for AC Transit will be delivered to Robins Air Force Base in September of 2009 to support the fueling of a fuel cell powered fork lift and 'Bobcat'. In addition the Transit Agency Site Requirements and Constraints were performed for the Greater New Haven Transit District (GNHTD) for the Hamden, CT Public Works building that will be the site for a similar fueling station to be delivered in the Spring of 2010. The Detailed Design Package was also based on the Design for the GNHTD unit. The work on this project successfuly demonstrated the potential of Avalence's high pressure technology to address the need for renewably produced hydrogen fuel for transportation applications. Several follow-on projects in a numerber of related applications are now underway as a result of this SBIR project.

Martin A Shimko

2009-08-08T23:59:59.000Z

438

Ceramic-metallic coatings by electron beam physical vapor deposition (EB-PVD) process  

SciTech Connect (OSTI)

Electron Beam Physical Vapor Deposition (EB-PVD) process is considered to be a technology that has overcome some of the difficulties or problems associated with the chemical vapor deposition (CVD), physical vapor deposition (PVD) and metal spray processes. The EB-PVD process offers many desirable characteristics such as relatively high deposition rates (up to 100-150 {mu}m/minute with an evaporation rate {approx}10-15 Kg/hour,) dense coatings, precise compositional control, columnar and poly-crystalline microstructure, low contamination, and high thermal efficiency. Various metallic and ceramic coatings (oxides, carbides, nitrides) can be deposited at relatively low temperatures. Even elements with low vapor pressure such as molybdenum, tungsten, and carbon are readily evaporated by this process. In addition, EB-PVD is capable of producing multi-layered laminated metallic/ceramic coatings on large components by changing the EB-PVD processing conditions such as ingot composition, part manipulation, and electron beam energy. Attachment of an ion assisted beam source to the EB-PVD offers additional benefits such as dense coatings with improved adhesion. In addition, textured coatings can be obtained that are desirable in many applications such as cutting tools. This laboratory has started a new thrust in the coating area by the EB-PVD process. The microstructure of thermal barrier ceramic coatings (i.e., yttria stabilized zirconia) developed by the EB-PVD process will be presented.

Wolfe, D.E.; Singh, J. [Pennsylvania State Univ., State College, PA (United States)

1995-12-31T23:59:59.000Z

439

Novel, fiber optic, hybrid pressure and temperature sensor designed for high-temperature gen-IV reactor applications  

SciTech Connect (OSTI)

A novel, fiber optic, hybrid pressure-temperature sensor is presented. The sensor is designed for reliable operation up to 1050 C, and is based on the high-temperature fiber optic sensors already demonstrated during previous work. The novelty of the sensors presented here lies in the fact that pressure and temperature are measured simultaneously with a single fiber and a single transducer. This hybrid approach will enable highly accurate active temperature compensation and sensor self-diagnostics not possible with other platforms. Hybrid pressure and temperature sensors were calibrated by varying both pressure and temperature. Implementing active temperature compensation resulted in a ten-fold reduction in the temperature-dependence of the pressure measurement. Sensors were also tested for operability in a relatively high neutron radiation environment up to 6.9x10{sup 17} n/cm{sup 2}. In addition to harsh environment survivability, fiber optic sensors offer a number of intrinsic advantages for nuclear power applications including small size, immunity to electromagnetic interference, self diagnostics / prognostics, and smart sensor capability. Deploying fiber optic sensors on future nuclear power plant designs would provide a substantial improvement in system health monitoring and safety instrumentation. Additional development is needed, however, before these advantages can be realized. This paper will highlight recent demonstrations of fiber optic sensors in environments relevant to emerging nuclear power plants. Successes and lessons learned will be highlighted. (authors)

Palmer, M. E.; Fielder, R. S.; Davis, M. A. [Luna Innovations, Incorporated, 2851 Commerce St., Blacksburg, VA 24060 (United States)

2006-07-01T23:59:59.000Z

440

First principle study of elastic and thermodynamic properties of FeB{sub 4} under high pressure  

SciTech Connect (OSTI)

The elastic properties, elastic anisotropy, and thermodynamic properties of the lately synthesized orthorhombic FeB{sub 4} at high pressures are investigated using first-principles density functional calculations. The calculated equilibrium parameters are in good agreement with the available experimental and theoretical data. The obtained normalized volume dependence of high pressure is consistent with the previous experimental data investigated using high-pressure synchrotron x-ray diffraction. The complete elastic tensors and crystal anisotropies of the FeB{sub 4} are also determined in the pressure range of 0–100?GPa. By the elastic stability criteria and vibrational frequencies, it is predicted that the orthorhombic FeB{sub 4} is stable up to 100 GPa. In addition, the calculated B/G ratio reveals that FeB{sub 4} possesses brittle nature in the range of pressure from 0 to 100?GPa. The calculated elastic anisotropic factors suggest that FeB{sub 4} is elastically anisotropic. By using quasi-harmonic Debye model, the compressibility, bulk modulus, the coefficient of thermal expansion, the heat capacity, and the Grüneisen parameter of FeB{sub 4} are successfully obtained in the present work.

Zhang, Xinyu, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn; Ning, Jinliang; Sun, Xiaowei; Li, Xinting; Ma, Mingzhen; Liu, Riping, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Qin, Jiaqian, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn [Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok 10330 (Thailand); State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China)

2013-11-14T23:59:59.000Z

Note: This page contains sample records for the topic "vapor high pressure" from the National Library of EnergyBeta (NLEBeta).
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441

Inter-stage and Performance Tests of a Two-stage High-pressure Turbine  

E-Print Network [OSTI]

traverse system in TPFL. Performance tests were conducted for varying pressure ratio, at fixed rotational speed and for varying rotational speed with fixed pressure ratio and the efficiency was plotted against u/c_0. Each condition was tested and measured...

Sharma, Kapil

2011-08-08T23:59:59.000Z

442

Effect of high pressure homogenization on the physical properties of milk  

E-Print Network [OSTI]

Milk was homogenized at pressures ranging from 17.2 MPa to 100 MPa to determine the effect of homogenization pressure on the fat globule size distribution, viscosity, color, and temperature changes in milk. Milk containing 0, 1.5 and 3.0% milk fat...

Gonzalez De Cossio, Carlos

1994-01-01T23:59:59.000Z

443

An improved measurement of electron-ion recombination in high-pressure xenon gas  

E-Print Network [OSTI]

We report on results obtained with the NEXT-DEMO prototype of the NEXT-100 high-pressure xenon gas time projection chamber (TPC), exposed to an alpha decay calibration source. Compared to our previous measurements with alpha particles, an upgraded detector and improved analysis techniques have been used. We measure event-by-event correlated fluctuations between ionization and scintillation due to electron-ion recombination in the gas, with correlation coeffcients between -0.80 and -0.56 depending on the drift field conditions. By combining the two signals, we obtain a 2.8 % FWHM energy resolution for 5.49 MeV alpha particles and a measurement of the optical gain of the electroluminescent TPC. The improved energy resolution also allows us to measure the specific activity of the radon in the gas due to natural impurities. Finally, we measure the average ratio of excited to ionized atoms produced in the xenon gas by alpha particles to be $0.561\\pm 0.045$, translating into an average energy to produce a primary scintillation photon of $W_{\\rm ex}=(39.2\\pm 3.2)$ eV.

NEXT Collaboration; L. Serra; M. Sorel; V. Álvarez; F. I. G. Borges; M. Camargo; S. Cárcel; S. Cebrián; A. Cervera; C. A. N. Conde; T. Dafni; J. Díaz; R. Esteve; L. M. P. Fernandes; P. Ferrario; A. L. Ferreira; E. D. C. Freitas; V. M. Gehman; A. Goldschmidt; J. J. Gómez-Cadenas; D. González-Díaz; R. M. Gutiérrez; J. Hauptman; J. A. Hernando Morata; D. C. Herrera; I. G. Irastorza; L. Labarga; A. Laing; I. Liubarsky; N. Lopez-March; D. Lorca; M. Losada; G. Luzón; A. Marí; J. Martín-Albo; G. Martínez-Lema; A. Martínez; T. Miller; F. Monrabal; M. Monserrate; C. M. B. Monteiro; F. J. Mora; L. M. Moutinho; J. Muñoz Vidal; M. Nebot-Guinot; D. Nygren; C. A. B. Oliveira; J. Pérez; J. L. Pérez Aparicio; M. Querol; J. Renner; L. Ripoll; A. Rodríguez; J. Rodríguez; F. P. Santos; J. M. F. dos Santos; D. Shuman; A. Simón; C. Sofka; J. F. Toledo; J. Torrent; Z. Tsamalaidze; J. F. C. A. Veloso; J. A. Villar; R. Webb; J. T. White; N. Yahlali

2015-02-03T23:59:59.000Z