National Library of Energy BETA

Sample records for vanadium zinc total

  1. VANADIUM ALLOYS

    DOE Patents [OSTI]

    Smith, K.F.; Van Thyne, R.J.

    1959-05-12

    This patent deals with vanadium based ternary alloys useful as fuel element jackets. According to the invention the ternary vanadium alloys, prepared in an arc furnace, contain from 2.5 to 15% by weight titanium and from 0.5 to 10% by weight niobium. Characteristics of these alloys are good thermal conductivity, low neutron capture cross section, good corrosion resistance, good welding and fabricating properties, low expansion coefficient, and high strength.

  2. Minerals yearbook, 1992: Vanadium. Annual report

    SciTech Connect (OSTI)

    Hilliard, H.E.

    1993-09-01

    In 1992, steelmaking continued to account for more than 80% of domestic vanadium demand. Consumption showed a modest increase, from 3,300 tons in 1991 to 4,032 tons in 1992. Although overall imports of vanadium raw materials decreased when compared with 1991, imports of ash, residues, and spent catalysts increased. Total U.S. exports of vanadium materials increased from 1,560 tons in 1991 to about 1,700 tons in 1992. The oversupply of vanadium that began in late 1989 persisted throughout 1992 despite reduced production by the world's largest producer, Highveld Steel Vanadium Corp. of the Republic of South Africa. A result of the oversupply was continuously lower prices in 1992.

  3. Total

    Gasoline and Diesel Fuel Update (EIA)

    Product: Total Crude Oil Liquefied Petroleum Gases PropanePropylene Normal ButaneButylene Other Liquids Oxygenates Fuel Ethanol MTBE Other Oxygenates Biomass-based Diesel Other ...

  4. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil Liquefied Petroleum Gases PropanePropylene Normal ButaneButylene Other Liquids Oxygenates Fuel Ethanol MTBE Other Oxygenates Biomass-based Diesel Fuel ...

  5. SUPERCONDUCTING VANADIUM BASE ALLOY

    DOE Patents [OSTI]

    Cleary, H.J.

    1958-10-21

    A new vanadium-base alloy which possesses remarkable superconducting properties is presented. The alloy consists of approximately one atomic percent of palladium, the balance being vanadium. The alloy is stated to be useful in a cryotron in digital computer circuits.

  6. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.9 Q Q Q Heat Pump......7.7 0.3 Q Q Steam or Hot Water System......Census Division Total West Energy Information Administration ...

  7. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.9 Q Q Q Heat Pump......6.2 3.8 2.4 Steam or Hot Water System......Census Division Total Northeast Energy Information ...

  8. Total..........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    . 111.1 20.6 15.1 5.5 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.9 0.5 0.4 500 to 999........................................................... 23.8 4.6 3.6 1.1 1,000 to 1,499..................................................... 20.8 2.8 2.2 0.6 1,500 to 1,999..................................................... 15.4 1.9 1.4 0.5 2,000 to 2,499..................................................... 12.2 2.3 1.7 0.5 2,500 to

  9. Total..........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    5.6 17.7 7.9 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.5 0.3 Q 500 to 999........................................................... 23.8 3.9 2.4 1.5 1,000 to 1,499..................................................... 20.8 4.4 3.2 1.2 1,500 to 1,999..................................................... 15.4 3.5 2.4 1.1 2,000 to 2,499..................................................... 12.2 3.2 2.1 1.1 2,500 to

  10. Total..........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.7 21.7 6.9 12.1 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.9 0.6 Q Q 500 to 999........................................................... 23.8 9.0 4.2 1.5 3.2 1,000 to 1,499..................................................... 20.8 8.6 4.7 1.5 2.5 1,500 to 1,999..................................................... 15.4 6.0 2.9 1.2 1.9 2,000 to 2,499..................................................... 12.2 4.1 2.1 0.7

  11. Total................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    .. 111.1 86.6 2,522 1,970 1,310 1,812 1,475 821 1,055 944 554 Total Floorspace (Square Feet) Fewer than 500............................. 3.2 0.9 261 336 162 Q Q Q 334 260 Q 500 to 999.................................... 23.8 9.4 670 683 320 705 666 274 811 721 363 1,000 to 1,499.............................. 20.8 15.0 1,121 1,083 622 1,129 1,052 535 1,228 1,090 676 1,500 to 1,999.............................. 15.4 14.4 1,574 1,450 945 1,628 1,327 629 1,712 1,489 808 2,000 to

  12. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    .. 111.1 24.5 1,090 902 341 872 780 441 Total Floorspace (Square Feet) Fewer than 500...................................... 3.1 2.3 403 360 165 366 348 93 500 to 999.............................................. 22.2 14.4 763 660 277 730 646 303 1,000 to 1,499........................................ 19.1 5.8 1,223 1,130 496 1,187 1,086 696 1,500 to 1,999........................................ 14.4 1.0 1,700 1,422 412 1,698 1,544 1,348 2,000 to 2,499........................................ 12.7

  13. Total...................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Floorspace (Square Feet) Total Floorspace 1 Fewer than 500............................................ 3.2 0.4 Q 0.6 1.7 0.4 500 to 999................................................... 23.8 4.8 1.4 4.2 10.2 3.2 1,000 to 1,499............................................. 20.8 10.6 1.8 1.8 4.0 2.6 1,500 to 1,999............................................. 15.4 12.4 1.5 0.5 0.5 0.4 2,000 to 2,499............................................. 12.2 10.7 1.0 0.2 Q Q 2,500 to

  14. Total.........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Floorspace (Square Feet) Total Floorspace 2 Fewer than 500.................................................. 3.2 Q 0.8 0.9 0.8 0.5 500 to 999.......................................................... 23.8 1.5 5.4 5.5 6.1 5.3 1,000 to 1,499.................................................... 20.8 1.4 4.0 5.2 5.0 5.2 1,500 to 1,999.................................................... 15.4 1.4 3.1 3.5 3.6 3.8 2,000 to 2,499.................................................... 12.2 1.4 3.2 3.0 2.3 2.3

  15. Total..........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    25.6 40.7 24.2 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.9 0.5 0.9 1.0 500 to 999........................................................... 23.8 4.6 3.9 9.0 6.3 1,000 to 1,499..................................................... 20.8 2.8 4.4 8.6 5.0 1,500 to 1,999..................................................... 15.4 1.9 3.5 6.0 4.0 2,000 to 2,499..................................................... 12.2 2.3 3.2 4.1

  16. Total..........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    7.1 7.0 8.0 12.1 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500................................................... 3.2 0.4 Q Q 0.5 500 to 999........................................................... 23.8 2.5 1.5 2.1 3.7 1,000 to 1,499..................................................... 20.8 1.1 2.0 1.5 2.5 1,500 to 1,999..................................................... 15.4 0.5 1.2 1.2 1.9 2,000 to 2,499..................................................... 12.2 0.7 0.5 0.8 1.4

  17. Total...........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Floorspace (Square Feet) Total Floorspace 1 Fewer than 500.................................... 3.2 0.7 Q 0.3 0.3 0.7 0.6 0.3 Q 500 to 999........................................... 23.8 2.7 1.4 2.2 2.8 5.5 5.1 3.0 1.1 1,000 to 1,499..................................... 20.8 2.3 1.4 2.4 2.5 3.5 3.5 3.6 1.6 1,500 to 1,999..................................... 15.4 1.8 1.4 2.2 2.0 2.4 2.4 2.1 1.2 2,000 to 2,499..................................... 12.2 1.4 0.9

  18. Controlling vanadium from high metals crude oils

    SciTech Connect (OSTI)

    Golden, S.W.; Martin, G.R.

    1995-09-01

    Processing heavier high metals crude oils continues to be an objective of many refiners. Refiners manage the vanadium and other contaminants with hydroprocessing and FCC catalysts that are more tolerant to metals. Although hydroprocessing and FCC catalyst formulations are critical and will be required for the bulk of the metals removal, many times primary distillation impacts on vanadium are ignored. Distillation system designs can significantly impact the metals content of the gas oil pool or the total gas yields for a targeted metals level. Commercial experience shows that total gas oil metals to the hydroprocessing unit can be reduced by 20 to 40% for a given gas yield or the total gas oil yield can be increased for a given metals target by optimizing primary distillation system performance. Total gas oil vanadium content has varied from 5 to 2 weight ppm depending on crude oil metals level, unit process design, distillation unit operation, and equipment design. An actual example using a 22.0 API Bochequero Field blend will be used to illustrate the points covered. The source of the vanadium in the various gas oil pool components will be evaluated and show potential gas oil quality improvements based on primary distillation system design and operation modifications. In the example, the refiner processes 145,000 bpd of crude oil through a conventional integrated atmospheric/vacuum unit and processes the vacuum residue in a delayed coker. The gas oil blend streams consists of atmospheric gas oil, light vacuum gas oil, and heavy vacuum gas oil from the crude unit and heavy coker gas oil from the delayed coker. All the modifications which will be discussed have been operating successfully for several years.

  19. Slag recycling of irradiated vanadium

    SciTech Connect (OSTI)

    Gorman, P.K.

    1995-04-05

    An experimental inductoslag apparatus to recycle irradiated vanadium was fabricated and tested. An experimental electroslag apparatus was also used to test possible slags. The testing was carried out with slag materials that were fabricated along with impurity bearing vanadium samples. Results obtained include computer simulated thermochemical calculations and experimentally determined removal efficiencies of the transmutation impurities. Analyses of the samples before and after testing were carried out to determine if the slag did indeed remove the transmutation impurities from the irradiated vanadium.

  20. Vanadium recycling for fusion reactors

    SciTech Connect (OSTI)

    Dolan, T.J.; Butterworth, G.J.

    1994-04-01

    Very stringent purity specifications must be applied to low activation vanadium alloys, in order to meet recycling goals requiring low residual dose rates after 50--100 years. Methods of vanadium production and purification which might meet these limits are described. Following a suitable cooling period after their use, the vanadium alloy components can be melted in a controlled atmosphere to remove volatile radioisotopes. The aim of the melting and decontamination process will be the achievement of dose rates low enough for ``hands-on`` refabrication of new reactor components from the reclaimed metal. The processes required to permit hands-on recycling appear to be technically feasible, and demonstration experiments are recommended. Background information relevant to the use of vanadium alloys in fusion reactors, including health hazards, resources, and economics, is provided.

  1. How Atomic Vibrations Transform Vanadium Dioxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy November 10, 2014 Contact: Dawn Levy, levyd@ornl.gov, 865.576.6448 Budaivibe Vanadium atoms (blue) have unusually large thermal vibrations that stabilize the metallic state of a vanadium dioxide crystal. Red depicts oxygen atoms. Image credit: Oak Ridge National Laboratory For more than 50 years, scientists have

  2. Vanadium removal from petroleum refinery wastewater

    SciTech Connect (OSTI)

    Nurdogan, Y.; Meyer, C.L.

    1996-11-01

    Although a numerical effluent limit has not been proposed for vanadium, San Francisco Bay Area refineries have been investigating reasonable source control and treatment measures to limit the discharge of vanadium as part of their National Pollution Discharge Elimination System (NPDES) permit requirements because vanadium may contribute to aquatic toxicity. The NPDES permit issued for the Shell Martinez Manufacturing Complex (MMC) by the Regional Water Quality Control Board (CRWQCB) required that in the investigation of control strategies for vanadium, consideration must be given to source control measures that would reduce the discharge to the extent practicable. This paper summarizes the results of bench- and pilot-scale studies to remove vanadium from process effluent of the Shell MMC. This study has resulted in the following conclusions: vanadium in the Shell MMC refinery wastewater is generated by two major sources--the Flexicoker and Stretford processes; ferric and ferrous salts are both effective in removing vanadium from wastewaters; there are tradeoffs between the initial vanadium concentration, the final pH, and the final dissolved vanadium concentration, for both ferrous and ferric reagents; recycle of iron hydroxide sludge can reduce the amount of reagent needed to attain a given vanadium concentration; other things being equal, less ferric than ferrous reagent is required to produce the same removal of vanadium; the dewatered sludge from the pilot plant was tested for its hazardous waste characteristics; a high pH sludge regeneration and reuse process appears to be a promising method of cleaning up the hazardous iron sludge.

  3. American Vanadium | Energy Systems Integration | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    American Vanadium NREL researchers are collaborating with American Vanadium, an integrated energy storage company, to evaluate and demonstrate the first North American CellCube battery management system. Photo of the American Vanadium CellCube device in a laboratory in the Energy Systems Integration Facility Photo by Dennis Schroeder CellCubes can store megawatts of energy, providing an uninterrupted supply of power from solar and wind power stations, no matter the outdoor conditions. Work at

  4. Growth control of the oxidation state in vanadium oxide thin...

    Office of Scientific and Technical Information (OSTI)

    Growth control of the oxidation state in vanadium oxide thin films Prev Next Title: Growth control of the oxidation state in vanadium oxide thin films Authors: Lee, Shinbuhm ...

  5. Practical Thermodynamic Quantities for Aqueous Vanadium- and...

    Office of Scientific and Technical Information (OSTI)

    Practical Thermodynamic Quantities for Aqueous Vanadium- and Iron-Based Flow Batteries. Citation Details In-Document Search Title: Practical Thermodynamic Quantities for Aqueous...

  6. Zinc content of selected tissues and taste perception in rats fed zinc deficient and zinc adequate rations

    SciTech Connect (OSTI)

    Boeckner, L.S.; Kies, C.

    1986-03-05

    The objective of the study was to determine the effects of feeding zinc sufficient and zinc deficient rations on taste sensitivity and zinc contents of selected organs in rats. The 36 Sprague-Dawley male weanling rats were divided into 2 groups and fed zinc deficient or zinc adequate rations. The animals were subjected to 4 trial periods in which a choice of deionized distilled water or a solution of quinine sulfate at 1.28 x 10/sup -6/ was given. A randomized schedule for rat sacrifice was used. No differences were found between zinc deficient and zinc adequate rats in taste preference aversion scores for quinine sulfate in the first three trial periods; however, in the last trial period rats in the zinc sufficient group drank somewhat less water containing quinine sulfate as a percentage of total water consumption than did rats fed the zinc deficient ration. Significantly higher zinc contents of kidney, brain and parotid salivary glands were seen in zinc adequate rats compared to zinc deficient rats at the end of the study. However, liver and tongue zinc levels were lower for both groups at the close of the study than were those of rats sacrificed at the beginning of the study.

  7. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, Leslie D.

    1982-01-01

    A pressure controlled vanadium hydride gas generator to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  8. Methods for making lithium vanadium oxide electrode materials

    DOE Patents [OSTI]

    Schutts, Scott M.; Kinney, Robert J.

    2000-01-01

    A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

  9. Method for preparing high purity vanadium

    DOE Patents [OSTI]

    Schmidt, Frederick; Carlson, O. Norman

    1986-09-09

    A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

  10. Method for preparing high purity vanadium

    DOE Patents [OSTI]

    Schmidt, F.; Carlson, O.N.

    1984-05-16

    A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

  11. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, L.D.

    1980-03-13

    A pressure controlled vanadium hydride gas generator was designed to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  12. Growth control of the oxidation state in vanadium oxide thin...

    Office of Scientific and Technical Information (OSTI)

    Growth control of the oxidation state in vanadium oxide thin films Citation Details In-Document Search Title: Growth control of the oxidation state in vanadium oxide thin films ...

  13. Zinc electrode with cement additive

    DOE Patents [OSTI]

    Charkey, Allen

    1982-06-01

    A zinc electrode having a cement additive, preferably, Portland Cement, distributed in the zinc active material.

  14. Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Rifle Processing Site, Colorado | Department of Energy and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado

  15. Slag remelt purification of irradiated vanadium alloys

    SciTech Connect (OSTI)

    Carmack, W.J.; Smolik, G.R.; McCarthy, K.A.; Gorman, P.K.

    1995-07-01

    This paper describes theoretical and scoping experimental efforts to investigate the decontamination potential of a slag remelting process for decontaminating irradiated vanadium alloys. Theoretical calculations, using a commercial thermochemical computer code HSC Chemistry, determined the potential slag compositions and slag-vanadium alloy ratios. The experiment determined the removal characteristics of four surrogate transmutation isotopes (Ca, Y - to simulate Sc, Mn, and Ar) from a V-5Ti-5Cr alloy with calcium fluoride slag. An electroslag remelt furnace was used in the experiment to melt and react the constituents. The process achieved about a 90 percent removal of calcium and over 99 percent removal of yttrium. Analyses indicate that about 40 percent of the manganese may have been removed. Argon analyses indicates that 99.3% of the argon was released from the vanadium alloy in the first melt increasing to 99.7% during the second melt. Powder metallurgy techniques were used to incorporate surrogate transmutation products in the vanadium. A powder mixture was prepared with the following composition: 90 wt % vanadium, 4.7 wt % titanium, 4.7 wt % chromium, 0.35 wt % manganese, 0.35 wt % CaO, and 0.35 wt % Y{sub 2}O{sub 3}. This mixture was packed into 2.54 cm diameter stainless steel tubes. Argon was introduced into the powder mixture by evacuating and backfilling the stainless steel containers to a pressure of 20 kPa (0.2 atm). The tubes were hot isostatically pressed at 207 MPa (2000 atm) and 1473 K to consolidate the metal. An electroslag remelt furnace (crucible dimensions: 5.1 cm diameter by 15.2 cm length) was used to process the vanadium electrodes. Chemical analyses were performed on samples extracted from the slags and ingots. Ingot analyses results are shown below. Values are shown in percent removal of the four targeted elements of the initial compositions.

  16. Production of zinc pellets

    DOE Patents [OSTI]

    Cooper, J.F.

    1996-11-26

    Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries. 6 figs.

  17. Production of zinc pellets

    DOE Patents [OSTI]

    Cooper, John F.

    1996-01-01

    Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries.

  18. Zinc deposition in acid lakes: the role of diffusion

    SciTech Connect (OSTI)

    Carignan, R.; Tessier, A.

    1985-06-28

    Steep negative concentration gradients of dissolved zinc are present between the overlying waters and the anoxic pore waters of two acid lakes. In the anoxic pore waters, the low zinc concentrations can be explained as due to the formation of relatively insoluble zinc sulfide minerals. Downward diffusive fluxes of dissolved zinc account for at least 50 to 75% of the recent zinc deposition to the sediments of these lakes. This downward diffusion occurs to a depth of 2 to 3 centimeters below the sediment water interface, where pronounced maxima in total zinc are observed. These subsurface peaks in total zinc have been interpreted as an indication of recent lake acidification. The present observations indicate that such subsurface peaks may also result from a diagenetic activity unrelated to recent changes in lake acidity. 22 references, 1 figure, 2 tables.

  19. Modified lithium vanadium oxide electrode materials products and methods

    DOE Patents [OSTI]

    Thackeray, Michael M.; Kahaian, Arthur J.; Visser, Donald R.; Dees, Dennis W.; Benedek, Roy

    1999-12-21

    A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

  20. Fact Sheet: Vanadium Redox Battery Demonstration Program (August...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The City of Painesville, OH, and its partners will demonstrate vanadium redox battery storage capacity at the 32 megawatt (MW), coal-fired Painesville Municipal Electric Plant ...

  1. City of Painesville, Ohio Vanadium Redox Battery Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    City of Painesville, Ohio and its partners will demonstrate vanadium redox battery storage capacity at the 32 megawatt (MW), coal-fired Painesville Municipal Electric Plant (PMEP). ...

  2. Creep properties of vanadium-base alloys

    SciTech Connect (OSTI)

    Chung, H.M.; Loomis, B.A.; Smith, D.L.

    1993-12-01

    Vanadium-base alloys are promising candidate materials for application in fusion reactor structural components because of several important advantages. V-4Cr-4Ti has been identified as one of the most promising candidate alloys and was selected for comprehensive tests and examination. In the present investigation, thermal creep rates and stress-rupture life of V-4Cr-4Ti and V-10Cr-5Ti alloys were determined at 600C. The impurity composition and microstructural characteristics of creep-tested specimens were analyzed and correlated with measured creep. Results show that V-4Cr-4Ti, which contains impurity compositions typical of a commercially fabricated vanadium-based alloy, exhibits creep strength substantially superior to that of V-20Ti, HT-9, or Type 316 stainless steel. The V-10Cr-5Ti alloy exhibits creep strength somewhat higher than that of V-4Cr-4Ti.

  3. Zinc oxyfluoride transparent conductor

    DOE Patents [OSTI]

    Gordon, Roy G.

    1991-02-05

    Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

  4. Vanadium-pumped titanium x-ray laser

    DOE Patents [OSTI]

    Nilsen, Joseph

    1992-01-01

    A resonantly photo-pumped x-ray laser (10) is formed of a vanadium (12) and titanium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state neon-like titanium ions (34) are resonantly photo-pumped by line emission from fluorine-like vanadium ions (32).

  5. Vanadium-pumped titanium x-ray laser

    DOE Patents [OSTI]

    Nilsen, J.

    1992-05-26

    A resonantly photo-pumped x-ray laser is formed of a vanadium and titanium foil combination that is driven by two beams of intense line focused optical laser radiation. Ground state neon-like titanium ions are resonantly photo-pumped by line emission from fluorine-like vanadium ions. 4 figs.

  6. Improved zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21

    The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

  7. Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s

    SciTech Connect (OSTI)

    Fujimoto, Cy H.; Kim, Soowhan; Stains, Ronald; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

    2012-07-01

    Sulfonated Diels Alder poly(phenylene) (SDAPP) was examined for vanadium redox flow battery (VRFB) use. The ion exchange capacity (IEC) was varied from 1.4, 1.6 and 2.0 meq/g in order to tune the proton conductivity and vanadium permeability. Coulombic efficiencies between 92 to 99% were observed, depending on IEC (lower IEC, higher coulombic efficiencies). In all cases the SDAPP displayed comparable energy efficiencies (88 - 90%) to Nafion 117 (88%) at 50mA/cm2. Membrane durability also was dependent on IEC; SDAPP with the highest IEC lasted slightly over 50 cycles while SDAPP with the lowest IEC lasted over 400 cycles and testing was discontinued only due to time constraints. Accelerated vanadium lifetime studies were initialed with SDAPP, by soaking films in a 0.1 M V5+ and 5.0 M total SO4-2 solution. The rate of degradation was also proportional with IEC; the 2 meq/g sample dissolved within 376 hours, the 1.6 meq/g sample dissolved after 860 hours, while the 1.4 meq/g sample broke apart after 1527 hours.

  8. Nuclear reactor fuel element with vanadium getter on cladding

    DOE Patents [OSTI]

    Johnson, Carl E.; Carroll, Kenneth G.

    1977-01-01

    A nuclear reactor fuel element is described which has an outer cladding, a central core of fissionable or mixed fissionable and fertile fuel material and a layer of vanadium as an oxygen getter on the inner surface of the cladding. The vanadium reacts with oxygen released by the fissionable material during irradiation of the core to prevent the oxygen from reacting with and corroding the cladding. Also described is a method for coating the inner surface of small diameter tubes of cladding with a layer of vanadium.

  9. Method to remove uranium/vanadium contamination from groundwater

    SciTech Connect (OSTI)

    Metzler, Donald R.; Morrison, Stanley

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  10. Method to Remove Uranium/Vanadium Contamination from Groundwater

    DOE Patents [OSTI]

    Metzler, Donald R.; Morrison Stanley

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  11. Plasma enhanced chemical vapor deposition (PECVD) method of forming vanadium oxide films and vanadium oxide thin-films prepared thereby

    DOE Patents [OSTI]

    Zhang, Ji-Guang; Tracy, C. Edwin; Benson, David K.; Turner, John A.; Liu, Ping

    2000-01-01

    A method is disclosed of forming a vanadium oxide film on a substrate utilizing plasma enhanced chemical vapor deposition. The method includes positioning a substrate within a plasma reaction chamber and then forming a precursor gas comprised of a vanadium-containing chloride gas in an inert carrier gas. This precursor gas is then mixed with selected amounts of hydrogen and oxygen and directed into the reaction chamber. The amounts of precursor gas, oxygen and hydrogen are selected to optimize the final properties of the vanadium oxide film An rf plasma is generated within the reaction chamber to chemically react the precursor gas with the hydrogen and the oxygen to cause deposition of a vanadium oxide film on the substrate while the chamber deposition pressure is maintained at about one torr or less. Finally, the byproduct gases are removed from the plasma reaction chamber.

  12. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, T.

    1997-02-18

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

  13. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi

    1997-01-01

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

  14. Zinc Speciation in Contaminated Sediments: Quantitative Determination...

    Office of Scientific and Technical Information (OSTI)

    Zinc Speciation in Contaminated Sediments: Quantitative Determination of Zinc Coordination by X-ray Absorption Spectroscopy Citation Details In-Document Search Title: Zinc ...

  15. Zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, Jr., Philip N.

    1989-01-01

    An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

  16. CATALYTIC PROMOTION OF THE ADSORPTION OF VANADIUM ON AN ANIONIC EXCHANGE RESIN

    DOE Patents [OSTI]

    Bailes, R.H.; Ellis, D.A.

    1958-08-26

    An improvement in the process for the recovery of vanadium from acidic phosphatic solutions is presented. In this process the vanadium is first oxidized to the pentavaleat state, and is then separated by contacting such solutions with an anion exchange resin whereby adsorption of the complexed pentavalent vanadium is effected. The improvement lies in the fact that adsorp tion of the vanadium complex by the anion exchange resin is promoted and improved by providing fiuoride ions in solution to be contacted.

  17. Research and development on vanadium alloys for fusion applications

    SciTech Connect (OSTI)

    Zinkle, S.J.; Rowcliffe, A.F.; Matsui, H.; Abe, K.; Smith, D.L.; Osch, E. van; Kazakov, V.A.

    1998-03-01

    The current status of research and development on unirradiated and irradiated V-Cr-Ti alloys intended for fusion reactor structural applications is reviewed, with particular emphasis on the flow and fracture behavior of neutron-irradiated vanadium alloys. Recent progress on fabrication, joining, oxidation behavior, and the development of insulator coatings is also summarized. Fabrication of large (>500 kg) heats of V-4Cr-4Ti with properties similar to previous small laboratory heats has now been demonstrated. Impressive advances in the joining of thick sections of vanadium alloys using GTA and electron beam welds have been achieved in the past two years, although further improvements are still needed.

  18. Zinc titanate sorbents

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1998-02-03

    The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about 750 to about 950 C. The dry blend is formed by mixing between about 0.5 to about 2 parts zinc oxide having a median particle size of less than about 0.5 microns, and about 1 part titanium dioxide having a median particle size of less than about 1 micron. The slurry contains substantially no free silica and may be prepared by the process including (1) preparing an aqueous solution of organic binder, (2) adding the dry blend to the aqueous solution of organic binder, and (3) adding the inorganic binder to the solution of organic binder, and blend. Additional reagents, such as a surfactant, may also be incorporated into the sorbent material. The present invention also provides a process for desulfurizing a gaseous stream. The process includes passing a gaseous stream through a reactor containing an attrition resistant zinc titanate sorbent material of the present invention.

  19. Zinc titanate sorbents

    DOE Patents [OSTI]

    Gupta, Raghubir P.; Gangwal, Santosh K.; Jain, Suresh C.

    1998-01-01

    The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about 750.degree. C. to about 950.degree. C. The dry blend is formed by mixing between about 0.5 to about 2 parts zinc oxide having a median particle size of less than about 0.5 .mu., and about 1 part titanium dioxide having a median particle size of less than about 1 .mu.. The slurry contains substantially no free silica and may be prepared by the process including (1) preparing an aqueous solution of organic binder, (2) adding the dry blend to the aqueous solution of organic binder, and (3) adding the inorganic binder to the solution of organic binder, and blend. Additional reagents, such as a surfactant, may also be incorporated into the sorbent material. The present invention also provides a process for desulfurizing a gaseous stream. The process includes passing a gaseous stream through a reactor containing an attrition resistant zinc titanate sorbent material of the present invention.

  20. Photovoltaic cells employing zinc phosphide

    DOE Patents [OSTI]

    Barnett, Allen M.; Catalano, Anthony W.; Dalal, Vikram L.; Masi, James V.; Meakin, John D.; Hall, Robert B.

    1984-01-01

    A photovoltaic cell having a zinc phosphide absorber. The zinc phosphide can be a single or multiple crystal slice or a thin polycrystalline film. The cell can be a Schottky barrier, heterojunction or homojunction device. Methods for synthesizing and crystallizing zinc phosphide are disclosed as well as a method for forming thin films.

  1. Zinc deposition in acid electrolytes

    SciTech Connect (OSTI)

    McBreen, J.; Gannon, E.

    1981-01-01

    In the past decade, two aqueous zinc/halogen batteries, the zinc/chlorine, and the zinc/bromine systems, have been considered for load-leveling and vehicular applications. Even though considerable progress has been made in engineering these batteries, several problems related to the zinc electrode have yet to be solved. These are related to the growth of dendritic zinc and a maldistribution of the zinc deposit that can occur during cycling. Both problems are exacerbated by recharge of the battery after partial discharge of the zinc deposit. A survey of the literature indicates that a more desireable zinc morphology can be achieved by use of inorganic additives, fluorinated surfactants, and A-C modulation of the charging current. In this investigation, the deposition of zinc from zinc bromide and zinc chloride electrolytes was investigated under conditions that precluded dendrite growth. The techniques used were cyclic voltammetry, the potential step technique and scanning electron microscopy. The variables investigated were the substrate (zinc and dense graphite), electrolyte pH, inorganic additives (Pb/sup + +/ and Bi/sup 3 +/) and A-V modulation of the charging potential by superimposed square waves.

  2. Total Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Imports - Total Imports - Crude Oil Imports - Crude Oil, Commercial Imports - by SPR Imports - into SPR by Others Imports - Total Products Imports - Total Motor Gasoline Imports - Finished Motor Gasoline Imports - Reformulated Gasoline Imports - Reformulated Gasoline Blended w/ Fuel Ethanol Imports - Other Reformulated Gasoline Imports - Conventional Gasoline Imports - Conv. Gasoline Blended w/ Fuel Ethanol Imports - Conv. Gasoline Blended w/ Fuel Ethanol, Ed55 & < Imports -

  3. HYPERFINE STRUCTURE CONSTANTS OF ENERGETICALLY HIGH-LYING LEVELS OF ODD PARITY OF ATOMIC VANADIUM

    SciTech Connect (OSTI)

    Güzelçimen, F.; Yapıcı, B.; Demir, G.; Er, A.; Öztürk, I. K.; Başar, Gö.; Kröger, S.; Tamanis, M.; Ferber, R.; Docenko, D.; Başar, Gü. E-mail: sophie.kroeger@htw-berlin.de

    2014-09-01

    High-resolution Fourier transform spectra of a vanadium-argon plasma have been recorded in the wavelength range of 365-670 nm (15,000-27,400 cm{sup –1}). Optical bandpass filters were used in the experimental setup to enhance the sensitivity of the Fourier transform spectrometer. In total, 138 atomic vanadium spectral lines showing resolved or partially resolved hyperfine structure have been analyzed to determine the magnetic dipole hyperfine structure constants A of the involved energy levels. One of the investigated lines has not been previously classified. As a result, the magnetic dipole hyperfine structure constants A for 90 energy levels are presented: 35 of them belong to the configuration 3d {sup 3}4s4p and 55 to the configuration 3d {sup 4}4p. Of these 90 constants, 67 have been determined for the first time, with 23 corresponding to the configuration 3d {sup 3}4s4p and 44 to 3d {sup 4}4p.

  4. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D.; Bond, Walter D.; Lauf, Robert J.

    1993-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  5. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  6. Zinc sulfide liquefaction catalyst

    DOE Patents [OSTI]

    Garg, Diwakar

    1984-01-01

    A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

  7. Country Total

    U.S. Energy Information Administration (EIA) Indexed Site

    Country Total Percent of U.S. total Canada 61,078 1% China 3,323,297 57% Germany 154,800 3% Japan 12,593 0% India 47,192 1% South Korea 251,105 4% All Others 2,008,612 34% Total 5,858,677 100% Table 7 . Photovoltaic module import shipments by country, 2014 (peak kilowatts) Note: All Others includes Cambodia, Czech Republic, Hong Kong, Malaysia, Mexico, Netherlands, Philippines, Singapore, Taiwan and Turkey Source: U.S. Energy Information Administration, Form EIA-63B, 'Annual Photovoltaic

  8. DOE - Office of Legacy Management -- Vanadium Corp of America - PA 15

    Office of Legacy Management (LM)

    Vanadium Corp of America - PA 15 Site ID (CSD Index Number): PA.15 Site Name: Vanadium Corp. of America Site Summary: Site Link: http://www.lm.doe.gov/canonsburg/Sites.aspx External Site Link: Alternate Name(s): UMTRAP Vicinity Property No. CA-401 Vanadium Corp of America Alternate Name Documents: PA.15-5 Location: Mayer Street - Collier Township , Bridgeville , Pennsylvania Location Documents: PA.15-1 Historical Operations (describe contaminants): Faclility used to grind pitchblende ore during

  9. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J.

    1996-12-31

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  10. State Total

    U.S. Energy Information Administration (EIA) Indexed Site

    State Total Percent of U.S. total Alabama 482 0.0% Alaska 81 0.0% Arizona 194,476 3.3% Arkansas 336 0.0% California 3,163,120 53.0% Colorado 47,240 0.8% Connecticut 50,745 0.9% Delaware 6,600 0.1% District of Columbia 751 0.0% Florida 18,593 0.3% Georgia 47,660 0.8% Hawaii 78,329 1.3% Illinois 5,795 0.1% Indiana 37,016 0.6% Iowa 14,281 0.2% Kansas 1,809 0.0% Kentucky 520 0.0% Louisiana 12,147 0.2% Maine 1,296 0.0% Maryland 63,077 1.1% Massachusetts 157,415 2.6% Michigan 4,210 0.1% Minnesota

  11. Insulator-to-Metal Transition of Vanadium Dioxide | U.S. DOE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such as smart windows and ultrafast field effect transistors, exhibits an insulator to ... vanadium dioxide driven by large phonon entropy," Nature 515, 535-539, 2014. DOI: ...

  12. Synthesis, characterization, and thermodynamic parameters of vanadium dioxide

    SciTech Connect (OSTI)

    Qi Ji [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China); Department of Chemical Engineering, Dalian Life Science College, Dalian Nationalities University, 18 Laohe West Road, Dalian 116600 (China); Ning Guiling [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Lin Yuan [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China)

    2008-08-04

    A novel process was developed for synthesizing pure thermochromic vanadium dioxide (VO{sub 2}) by thermal reduction of vanadium pentoxide (V{sub 2}O{sub 5}) in ammonia gas. The process of thermal reduction of V{sub 2}O{sub 5} was optimized by both experiments and modeling of thermodynamic parameters. The product VO{sub 2} was characterized by means of X-ray diffraction (XRD), X-ray photoelectron spectrometry (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TG), and differential scanning calorimetry (DSC). The experimental results indicated that pure thermochromic VO{sub 2} crystal particles were successfully synthesized. The phase transition temperature of the VO{sub 2} is approximately 342.6 K and the enthalpy of phase transition is 44.90 J/g.

  13. Present Status of Vanadium Alloys for Fusion Applications

    SciTech Connect (OSTI)

    Muroga, Takeo; Chen, J. M.; Chernov, V. M.; Kurtz, Richard J.; Le Flem, M.

    2014-12-01

    Vanadium alloys are advanced options for low activation structural materials. After more than two decades of research, V-4Cr-4Ti has been emerged as the leading candidate, and technological progress has been made in reducing the number of critical issues for application of vanadium alloys to fusion reactors. Notable progress has been made in fabricating alloy products and weld joints without degradation of properties. Various efforts are also being made to improve high temperature strength and creep-rupture resistance, low temperature ductility after irradiation, and corrosion resistance in blanket conditions. Future research should focus on clarifying remaining uncertainty in the operating temperature window of V-4Cr-4Ti for application to near to middle term fusion blanket systems, and on further exploration of advanced materials for improved performance for longer-term fusion reactor systems.

  14. ORNUTM-13249 DRAFT AN ECOLOGICAL INVESTIGATION OF A VANADIUM

    Office of Legacy Management (LM)

    ORNUTM-13249 DRAFT AN ECOLOGICAL INVESTIGATION OF A VANADIUM AND URANIUM MILL TAILINGS SITE 1. G. Smith, M. J. Peterson, and M. G. Ryon Biological Monitoring and Abatement Program Environmental Sciences Division Oak RidgeNational Laboratory Oak Ridge, Tennessee May 1996 Prepared for Gretchen A. Pierce Healthand Safety Research Division Environmental Technology Section Oak RidgeNational Laboratory GrandJunction, Colorado Prepared by the Environmental Sciences Division Oak RidgeNational Laboratory

  15. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers...

  16. Aqueous Zinc Bromide Waste Solidification

    SciTech Connect (OSTI)

    Langton, C.A.

    2002-07-23

    The goal of this study was to select one or more commercially available aqueous sorbents to solidify the zinc bromide solution stored in C-Area, identify the polymer to zinc bromide solution ratio (waste loading) for the selected sorbents, and identify processing issues that require further testing in pilot-scale testing.

  17. Theoretical Study of High-Valent Vanadium Oxo-Porphyrins as a Dopant of Crude Oil

    SciTech Connect (OSTI)

    Salcedo, Roberto; Martinez, LMR; Martinez-Magadan, Jose M.

    2001-06-15

    The role played by the vanadyl porphyrinate as a dopant for zeolites in the refinement process of crude oil is analyzed using DFT calculations. The pair formed by the vanadium atom and its bonded oxygen atoms seems to be the responsible items in the dopant reaction. However, the present paper shows the participation of the vanadium atom as being the most important.

  18. Regeneration of zinc chloride hydrocracking catalyst

    DOE Patents [OSTI]

    Zielke, Clyde W.

    1979-01-01

    Improved rate of recovery of zinc values from the solids which are carried over by the effluent vapors from the oxidative vapor phase regeneration of spent zinc chloride catalyst is achieved by treatment of the solids with both hydrogen chloride and calcium chloride to selectively and rapidly recover the zinc values as zinc chloride.

  19. Isotope Effects and Helium Retention Behavior in Vanadium Tritide

    SciTech Connect (OSTI)

    Bowman, Jr., R. C.; Attalla, A.; Craft, B. D.

    1985-04-01

    The relaxation times of the H, T, and 3He nuclei have been measured in vanadium hydride and tritide samples. Substantial isotope effects in both the phase transition temperatures and diffusion parameters have been found. When compared to hydrides, the tritide samples have lower transition temperatures and faster mobilities. The differences in the occupancies of the interstitial sites are largely responsible for these isotope effects. Most of the helium atoms generated by tritium decay remain trapped in microscopic bubbles formed with the VTx lattice. Evidence is presented for the gradual growth of the helium bubbles over periods of hundreds of days.

  20. Vanadium alloys for the radiative divertor program of DIII-D

    SciTech Connect (OSTI)

    Smith, J.P.; Johnson, W.R.; Stambaugh, R.D.; Trester, P.W.; Smith, D.; Bloom, E.

    1995-10-01

    Vanadium alloys provide an attractive solution for fusion power plants as they exhibit a potential for low environmental impact due to low level of activation from neutron fluence and a relatively short half-life. They also have attractive material properties for use in a reactor. General Atomics along with Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL), has developed a plan to utilize vanadium alloys as part of the Radiative Divertor Project (RDP) modification for the DIII-D tokamak. The goal for using vanadium alloys is to provide a meaningful step towards developing advanced materials for fusion power applications by demonstrating the in-service behavior of a vanadium alloy (V-4Cr-4Ti) in a tokamak in conjunction with developing essential fabrication technology for the manufacture of full-scale vanadium alloy components. A phased approach towards utilizing vanadium in DIII-D is being used starting with small coupons and samples, advancing to a small component, and finally a portion of the new double-null, slotted divertor will be fabricated from vanadium alloy product forms. A major portion of the program is research and development to support fabrication and resolve key issues related to environmental effects.

  1. Structural investigation of phosphate - bismuth glasses with vanadium

    SciTech Connect (OSTI)

    Stănescu, R.; Vedeanu, N.; Cozar, I. B.; Măgdaş, A.

    2013-11-13

    The xV{sub 2}O{sub 5}(1−dx)[0.5P{sub 2}O{sub 5}⋅0.5Bi{sub 2}O{sub 3}] glass system with 0 ≤ x ≤ 50 mol% is investigated by IR and Raman spectroscopy. Both P{sub 2}O{sub 5} and Bi{sub 2}O{sub 3} oxides are known as network formers, but Bi{sub 2}O{sub 3} is an unconventional one. At low content of vanadium oxide (x ≤ 5 mol%), both IR and Raman spectra are dominated by vibration bands characteristics to structural groups of phosphate and bismuthate lattices. Due to the network modifier role, vanadium oxide acts mainly on the Bi{sub 2}O{sub 3} network allowing the phosphate groups to impose their characteristics absorption bands in spectra. These bands are strongly reduced for x ≥ 20 mol% due to the phosphate network depolymerization and the appearance of new vibrations characteristic to P-O-V, Bi-O-V and V-O-V groups showing the network former role of V{sub 2}O{sub 5}.

  2. Nitridation under ammonia of high surface area vanadium aerogels

    SciTech Connect (OSTI)

    Merdrignac-Conanec, Odile [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)]. E-mail: odile.merdrignac@univ-rennes1.fr; El Badraoui, Khadija [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France); L'Haridon, Paul [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)

    2005-01-15

    Vanadium pentoxide gels have been obtained from decavanadic acid prepared by ion exchange on a resin from ammonium metavanadate solution. The progressive removal of water by solvent exchange in supercritical conditions led to the formation of high surface area V{sub 2}O{sub 5}, 1.6H{sub 2}O aerogels. Heat treatment under ammonia has been performed on these aerogels in the 450-900 deg. C temperature range. The oxide precursors and oxynitrides have been characterized by XRD, SEM, TGA, BET. Nitridation leads to divided oxynitride powders in which the fibrous structure of the aerogel is maintained. The use of both very low heating rates and high surface area aerogel precursors allows a higher rate and a lower threshold of nitridation than those reported in previous works. By adjusting the nitridation temperature, it has been possible to prepare oxynitrides with various nitrogen enrichment and vanadium valency states. Whatever the V(O,N) composition, the oxidation of the oxynitrides in air starts between 250 and 300 deg. C. This determines their potential use as chemical gas sensors at a maximum working temperature of 250 deg. C.

  3. Novel solar light driven photocatalyst, zinc indium vanadate for photodegradation of aqueous phenol

    SciTech Connect (OSTI)

    Mahapure, Sonali A.; Ambekar, Jalindar D.; Nikam, Latesh K.; Marimuthu, R.; Kulkarni, Milind V.

    2011-05-15

    Graphical abstract: Novel photocatalyst, zinc indium vanadate (ZnIn{sub 2}V{sub 2}O{sub 9}) demonstrated and showed an excellent photocatalytic activity for phenol degradation under visible light. Research highlights: {yields} Designing and identification of a photocatalyst having prospective potential application to be used in visible light (400-800 nm). {yields} Successful synthesis of novel ZnIn{sub 2}V{sub 2}O{sub 9} by solid state route. {yields} Confirmation of the designed product using characterization techniques. {yields} Application study comprising photodegradation of aqueous phenol at visible light despite of UV radiations. -- Abstract: In the present investigation, we have demonstrated the synthesis of novel photocatalyst, zinc indium vanadate (ZIV) by solid-solid state route using respective oxides of zinc, indium and vanadium. This novel photocatalyst was characterized using XRD, FESEM, UV-DRS and FTIR in order to investigate its structural, morphological and optical properties. XRD clearly shows the formation of phase pure ZIV of triclinic crystal structure with good crystallinity. FESEM micrographs showed the clustered morphology having particle size between 0.5 and 1 {mu}m. Since, optical study showed the band gap around 2.8 eV, i.e. in visible region, we have performed the photocatalytic activity of phenol degradation under visible light irradiation. The photodecomposition of phenol by ZIV is studied for the first time and an excellent photocatalytic activity was obtained using this novel photocatalyst. Considering the band gap of zinc indium vanadate in visible region, it will also be the potential candidate for water splitting.

  4. Structure and Electrochemistry of Vanadium-Modified LiFePO4 ...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Structure and Electrochemistry of Vanadium-Modified LiFePO4 Authors: Hong, Jian ; Wang, Xiao-Liang ; Wang, Qi ; Omenya, Fredrick O. ; ...

  5. Can Vanadium Be Substituted into LiFePO[subscript 4]? (Journal...

    Office of Scientific and Technical Information (OSTI)

    the solid solution LiFesub 1-3y2Vsub yPOsub 4, the a and b lattice parameters and cell volume decrease with increasing vanadium content, while the c lattice parameter...

  6. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  7. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D.; Bond, Walter D.; Lauf, Robert J.

    1993-01-01

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  8. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Extracellular Proteins Promote Zinc Sulfide Aggregation Print Wednesday, 26 September 2007 00:00 Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material

  9. Molecular based magnets comprising vanadium tetracyanoethylene complexes for shielding electromagnetic fields

    DOE Patents [OSTI]

    Epstein, A.J.; Morin, B.G.

    1998-10-13

    The invention presents a vanadium tetracyanoethylene solvent complex for electromagnetic field shielding, and a method for blocking low frequency and magnetic fields using these vanadium tetracyanoethylene compositions. The compositions of the invention can be produced at ambient temperature and are light weight, low density and flexible. The materials of the present invention are useful as magnetic shields to block low frequency fields and static fields, and for use in cores in transformers and motors. 21 figs.

  10. Molecular based magnets comprising vanadium tetracyanoethylene complexes for shielding electromagnetic fields

    DOE Patents [OSTI]

    Epstein, Arthur J.; Morin, Brian G.

    1998-01-01

    The invention presents a vanadium tetracyanoethylene solvent complex for electromagnetic field shielding, and a method for blocking low frequency and magnetic fields using these vanadium tetracyanoethylene compositions. The compositions of the invention can be produced at ambient temperature and are light weight, low density and flexible. The materials of the present invention are useful as magnetic shields to block low frequency fields and static fields, and for use in cores in transformers and motors.

  11. Palladium-coated Vanadium-alloy membranes for Hydrogen Separation.

    SciTech Connect (OSTI)

    Paglieri, S. N. (Stephen N.); Pesiri, D. R. (David R.); Dye, R. C. (Robert C.); Birdsell, S. A. (Stephen A.); Snow, R. C. (Ronny C.)

    2005-01-01

    Hydrogen-separating membranes have the potential to generate pure hydrogen from abundant fossil fuel supplies such as coal, for use in fuel cells. Foils of V{sub 0.95}Ti{sub 0.05} and V{sub 0.88}Cu{sub 0.12} (at. %) coated with thin films of Pd or Pd alloy (Pd-Ag) were fabricated and tested for hydrogen permeability and stability during operation at temperatures from 320-450 C. Vanadium-alloy foils were ion-milled and coatings between 50 and 200 nm thick were applied to both sides insitu, via electron beam evaporation PVD. The membranes were completely permselective for hydrogen. Hydrogen flux stability was dependent on palladium coating thickness, with constant flux observed during tests at 350 C, and slow decline observed at 400 C that accelerated at higher temperatures.

  12. Vanadium oxides nanostructures: Hydrothermal synthesis and electrochemical properties

    SciTech Connect (OSTI)

    Mjejri, I.; Etteyeb, N.; Sediri, F.

    2014-12-15

    Highlights: • Vanadium oxides nanostructures were synthesized hydrothermally. • Reversible redox behavior with doping/dedoping process. • Doping/dedoping is easier for Li{sup +} to Na{sup +}. • Energy-related applications such as cathodes in lithium batteries. - Abstract: A facile and template-free one-pot strategy is applied to synthesize nanostructured vanadium oxide particles via a hydrothermal methodology. X-ray diffraction (XRD), scanning electron microscope (SEM), Fourier transforms infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) have been used to characterize the structure and morphology of the samples. The products are gradually changed from sheet-shaped VO{sub 2}(B) to rod-like V{sub 3}O{sub 7}·H{sub 2}O with decreasing cyclohexanediol as both protective and reducing agent. The specific surface area of the VO{sub 2}(B) nanosheets and V{sub 3}O{sub 7}·H{sub 2}O nanorods was found to be 22 and 16 m{sup 2} g{sup −1}, respectively. Thin films of VO{sub 2}(B) and V{sub 3}O{sub 7}·H{sub 2}O deposited on ITO substrates were electrochemically characterized by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The voltammograms show reversible redox behavior with doping/dedoping process corresponding to reversible cation intercalation/de-intercalation into the crystal lattice of the nanorods/nanosheets. This process is easier for the small Li{sup +} cation than larger ones Na{sup +}.

  13. Method for the regeneration of spent molten zinc chloride

    DOE Patents [OSTI]

    Zielke, Clyde W.; Rosenhoover, William A.

    1981-01-01

    In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

  14. Barge Truck Total

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Barge Truck Total delivered cost per short ton Shipments with transportation rates over total shipments Total delivered cost per short ton Shipments with transportation rates over...

  15. Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid Based Redox Flow Battery Electrolytes

    SciTech Connect (OSTI)

    Vijayakumar, M.; Wang, Wei; Nie, Zimin; Sprenkle, Vincent L.; Hu, Jian Z.

    2013-11-01

    The Vanadium (V) cation structures in mixed acid based electrolyte solution were analysed by density functional theory (DFT) based computational modelling and 51V and 35Cl Nuclear Magnetic Resonance (NMR) spectroscopy. The Vanadium (V) cation exists as di-nuclear [V2O3Cl2.6H2O]2+ compound at higher vanadium concentrations (≥1.75M). In particular, at high temperatures (>295K) this di-nuclear compound undergoes ligand exchange process with nearby solvent chlorine molecule and forms chlorine bonded [V2O3Cl2.6H2O]2+ compound. This chlorine bonded [V2O3Cl2.6H2O]2+ compound might be resistant to the de-protonation reaction which is the initial step in the precipitation reaction in Vanadium based electrolyte solutions. The combined theoretical and experimental approach reveals that formation of chlorine bonded [V2O3Cl2.6H2O]2+ compound might be central to the observed higher thermal stability of mixed acid based Vanadium (V) electrolyte solutions.

  16. Can Vanadium Be Substituted into LiFePO[subscript 4]?

    SciTech Connect (OSTI)

    Omenya, Fredrick; Chernova, Natasha A.; Upreti, Shailesh; Zavalij, Peter Y.; Nam, Kyung-Wan; Yang, Xiao-Qing; Whittingham, M. Stanley

    2015-10-15

    Vanadium is shown to substitute for iron in the olivine LiFePO{sub 4} up to at least 10 mol %, when the synthesis is carried out at 550 C. In the solid solution LiFe{sub 1-3y/2}V{sub y}PO{sub 4}, the a and b lattice parameters and cell volume decrease with increasing vanadium content, while the c lattice parameter increases slightly. However, when the synthesis is performed at 650 C, a NASICON phase, Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}, is also formed, showing that solid solution is a function of the synthesis temperature. X-ray absorption near-edge structure indicates vanadium is in the 3+ oxidation state and in an octahedral environment. Magnetic studies reveal a shift of the antiferromagnetic ordering transition toward lower temperatures with increasing vanadium substitution, confirming solid solution formation. The addition of vanadium enhances the electrochemical performance of the materials especially at high current densities.

  17. Numerical modeling of an all vanadium redox flow battery.

    SciTech Connect (OSTI)

    Clausen, Jonathan R.; Brunini, Victor E.; Moffat, Harry K.; Martinez, Mario J.

    2014-01-01

    We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.

  18. Chemical leaching of coal to remove ash, alkali and vanadium

    SciTech Connect (OSTI)

    Smit, F.J.; Huggins, D.K.; Berggren, M.; Anast, K.R.

    1986-04-15

    A process is described for upgrading powdered coal to improve the usefulness thereof as a fuel for internal combustion engines which consists of: (a) pressure-leaching powdered coal having a particle size ranging from about 28 mesh to about 200 mesh in an aqueous caustic solution at a temperature ranging from about 175/sup 0/C, to about 350/sup 0/C., the amount of caustic in the solution ranging from about 5% to about 30% by weight, the amount of coal being sufficient to form a slurry comprising about 10% to 30% by weight of solids, (b) hydrochloric acid leaching the caustic leached coal to dissolve acid-soluble constituents resulting from the caustic leach, (c) pressure leaching the acid-leached coal with a liquid from the group consisting of water and dilute aqueous ammonia to remove sodium and chlorine, and thereafter (d) filtering and washing the pressure leached coal, whereby the coal is characterized by up to about 0.85% by weight of ash, up to about 150 ppm of alkali metals and up to about 4 ppm vanadium.

  19. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for

  20. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for

  1. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for

  2. Directed spatial organization of zinc oxide nanostructures

    DOE Patents [OSTI]

    Hsu, Julia; Liu, Jun

    2009-02-17

    A method for controllably forming zinc oxide nanostructures on a surface via an organic template, which is formed using a stamp prepared from pre-defined relief structures, inking the stamp with a solution comprising self-assembled monolayer (SAM) molecules, contacting the stamp to the surface, such as Ag sputtered on Si, and immersing the surface with the patterned SAM molecules with a zinc-containing solution with pH control to form zinc oxide nanostructures on the bare Ag surface.

  3. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for

  4. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for

  5. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about the relationship of the organic material and metals, particularly how organics affect mobility, and its potential for

  6. Lithiated vanadium oxide (LVO), gamma-lithium vanadium bronze (gamma-LiV2O5) and vanadium dioxide (Vo2) as thermal-battery cathode materials. Technical report

    SciTech Connect (OSTI)

    Richie, A.G.; Warner, K.

    1991-05-01

    Thermal batteries are high temperature reserve batteries, predominantly used in missiles. Modern designs use a lithium (or lithium alloy) anode, an immobilized molten salt electrolyte and an iron-disulphide cathode. These batteries have many advantages: high reliability, long storage life without maintenance, wide temperature range of operation and, sometimes, high power. However, the energy density is rather low and this could be improved if the individual cell voltage could be raised above the present 2.2 V/cell open circuit-voltage for the lithium iron-disulphide couple. A new cathode material, lithiated vanadium oxide (LVO), been invented at RAE with the advantage of the much higher open-circuit voltage of 2.6 V/cell versus lithium. The properties of LVO have been investigated and it has been shown that LVO consists of vanadium dioxide as the major component. Some lithium bromide is also present.

  7. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    can organize sulfide nanoparticles into semiconductor nanowires. The research team used a series of imaging techniques and detectors to analyze aggregates of biogenic zinc sulfide...

  8. Zinc Matrix Power Inc | Open Energy Information

    Open Energy Info (EERE)

    California Zip: 93101 Product: Develops high-performance rechargeable alkaline battery technology for commercial and military markets. References: Zinc Matrix Power Inc1...

  9. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were...

  10. Tinkering with Zinc | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and lack the stability necessary to directly study their role in important catalytic industrial processes. Zinc is not a transition metal, but some of its properties are...

  11. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore National Laboratory analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing...

  12. Solvothermal synthesis of vanadium phosphates in the form of xerogels, aerogels and mesostructures

    SciTech Connect (OSTI)

    Sydorchuk, V.; Zazhigalov, V.; Khalameida, S.; Diyuk, E.; Skubiszewska-Zieba, J.; Leboda, R.; Kuznetsova, L.

    2010-09-15

    Regularities and peculiarities of physicochemical changes, first of all phase transformations, during solvothermal treatment (with conventional and microwave heating) of the vanadium pentoxide and orthophosphoric acid mixture in organic solvents in the presence of reducing agents have been studied. Hemihydrate of vanadium hydrophosphate - the precursor of vanadium pyrophosphate, the active phase for n-butane to maleic anhydride oxidation, and ion exchanger with variable physicochemical characteristics, i.e. crystal structure, specific surface area, crystallite size and acidic properties - has been synthesized in the temperature range 170-200 {sup o}C. The obtained phases were examined using XRD, DTA-TG, SEM, FTIR spectroscopy, nitrogen adsorption as well as gas chromatographic determination of acidity through organic bases adsorption. The catalytic activity of prepared samples for n-butane oxidation has been investigated.

  13. Nanoscale Chemical Imaging of Zinc Oxide Nanowire Corrosion ...

    Office of Scientific and Technical Information (OSTI)

    Nanoscale Chemical Imaging of Zinc Oxide Nanowire Corrosion Citation Details In-Document Search Title: Nanoscale Chemical Imaging of Zinc Oxide Nanowire Corrosion Nanoscale ...

  14. Microsoft Word - 11063858 DVP

    Office of Legacy Management (LM)

    ... Tritium X NA Liquid Scintillation LMG-03 Uranium Vanadium Zinc Total No. of Analytes 2 ... 1, 2011 TO: Mark Plessinger FROM: Jeff Price SUBJECT: Trip Report (Natural Gas and ...

  15. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... 10 pCiL Liquid Scintillation LMR-15 Uranium Vanadium Zinc Total No. of Analytes 4 0 ... 26, 2013 TO: Rick Findlay FROM: Jeff Price SUBJECT: Trip Report (LTHMP Sampling) ...

  16. Strong reduction of V{sup 4+} amount in vanadium oxide/hexadecylamine nanotubes by doping with Co{sup 2+} and Ni{sup 2+} ions: Electron paramagnetic resonance and magnetic studies

    SciTech Connect (OSTI)

    Saleta, M. E.; Troiani, H. E.; Ribeiro Guevara, S.; Ruano, G.; Sanchez, R. D.; Malta, M.; Torresi, R. M.

    2011-05-01

    In this work we present a complete characterization and magnetic study of vanadium oxide/hexadecylamine nanotubes (VO{sub x}/Hexa NT's) doped with Co{sup 2+} and Ni{sup 2+} ions. The morphology of the NT's has been characterized by transmission electron microscopy, while the metallic elements have been quantified by the instrumental neutron activation analysis technique. The static and dynamic magnetic properties were studied by collecting data of magnetization as a function of magnetic field and temperature and by electron paramagnetic resonance. At difference of the majority reports in the literature, we do not observe magnetic dimers in vanadium oxide nanotubes. Also, we observed that the incorporation of metallic ions (Co{sup 2+}, S = 3/2 and Ni{sup 2+}, S = 1) decreases notably the amount of V{sup 4+} ions in the system, from 14-16% (nondoped case) to 2%-4%, with respect to the total vanadium atoms (fact corroborated by XPS experiments) anyway preserving the tubular nanostructure. The method to decrease the amount of V{sup 4+} in the nanotubes improves considerably their potential technological applications as Li-ion batteries cathodes.

  17. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  18. Temperature Dependence of Aliovalent-vanadium Doping in LiFePO4 Cathodes

    SciTech Connect (OSTI)

    Harrison, Katharine L; Bridges, Craig A; Paranthaman, Mariappan Parans; Idrobo Tapia, Juan C; Manthiram, Arumugam; Goodenough, J. B.; Segre, C; Katsoudas, John; Maroni, V. A.

    2013-01-01

    Vanadium-doped olivine LiFePO4 cathode materials have been synthesized by a novel low-temperature microwave-assisted solvothermal (MW-ST) method at 300 oC. Based on chemical and powder neutron/X-ray diffraction analysis, the compositions of the synthesized materials were found to be LiFe1-3x/2Vx x/2PO4 (0 x 0.2) with the presence of a small number of lithium vacancies charge-compensated by V4+, not Fe3+, leading to an average oxidation state of ~ 3.2+ for vanadium. Heating the pristine 15 % V-doped sample in inert or reducing atmospheres led to a loss of vanadium from the olivine lattice with the concomitant formation of a Li3V2(PO4)3 impurity phase; after phase segregation, a partially V-doped olivine phase remained. For comparison, V-doped samples were also synthesized by conventional ball milling and heating, but only ~ 10 % V could be accommodated in the olivine lattice in agreement with previous studies. The higher degree of doping realized with the MW-ST samples demonstrates the temperature dependence of the aliovalent-vanadium doping in LiFePO4.

  19. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, Richard H.

    1986-01-01

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  20. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, R.H.

    1987-04-21

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  1. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1985-05-17

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  2. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, Richard H.

    1987-01-01

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  3. Leaching nickel cobalt molybdenum tungsten and vanadium from spent hydroprocessing catalysts

    SciTech Connect (OSTI)

    Hubred, G. L.

    1985-04-30

    A process for removing nickel, cobalt, molybdenum, and vanadium from spent hydroprocessing catalyst particles by roasting the catalyst at between 400/sup 0/ C. and 600/sup 0/ C. and leaching the catalyst particles with an aqueous solution of ammonia and an ammonium salt.

  4. Partial oxidation of vanadium-containing heavy liquid hydrocarbonaceous and solid carbonaceous fuels

    SciTech Connect (OSTI)

    Najjar, M.S.; Becker, M.W.; Stevenson, J.S.

    1988-03-22

    In a partial oxidation process for the production of gaseous mixtures comprising H/sub 2/+CO in the reaction zone of a down flowing gas generator, the improvements are described comprising: (1) mixing together the following materials to produce a feed mixture (i) a vanadium-containing fuel whose ash includes a minimum of 2.0 weight % of vanadium selected from the group consisting of liquid hydrocarbonaceous fuel, a slurry of solid carbonaceous fuel, and mixtures thereof; (ii) supplemental copper-containing additive; and (iii) at least a portion of the remainder of the copper-containing slag after separation of the coarse slag fraction in (5); (2) reacting by partial oxidation in a refractory-lined free-flow unpacked reaction zone of the gas generator the vanadium-containing feed mixture from (1) with a free-oxygen containing gas in the presence of a temperature moderator and in a reducing atmosphere to produce a hot raw effluent gas stream comprising H/sub 2/+CO along with vanadium-containing molten slag comprising a liquid phase washing agent that collects and transports vanadium-containing laths and spinels and other ash components and refractory out of the reaction zone; (3) passing the hot raw effluent gas stream down through a coaxial discharge passage in the bottom of the reaction zone of the gas generator; (4) passing through the quench tank at least a portion of the hot effluent gas stream leaving the slag separation chamber to produce the gaseous mixture comprising H/sub 2/+CO, and solidifying molten slag; and (5) passing the water and solids from the bottom of the quench tank into a water-solids separation zone.

  5. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C.; McLarnon, Frank R.; Cairns, Elton J.

    1994-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  6. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, T.C.; McLarnon, F.R.; Cairns, E.J.

    1994-04-12

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K[sub 2]CO[sub 3] salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics. 8 figures.

  7. Catalytic hydroprocessing of aromatic compounds: Effects of nickel and vanadium sulfide deposits on reactivities and reaction networks

    SciTech Connect (OSTI)

    Yumoto, Mitsugu |; Kukes, S.G.; Klein, M.T.; Gates, B.C. |

    1996-09-01

    Ni-Mo/{gamma}-Al{sub 2}O{sub 3} hydroprocessing catalysts enriched in nickel and vanadium by contacting with solutions of the respective metal naphthenates were sulfided and tested for hydroprocessing of naphthalene, dibenzothiophene, and quinoline in a batch reactor at 350 C and 165 atm. Approximately reaction networks were determined for each reactant, and the data showed the dependence of the pseudo-first-order rate constants on the catalyst nickel and vanadium contents. The nickel sulfide deposits only slightly affected the rate constants for hydrogenation, but the vanadium sulfide deposits led to decreases in the rate constants for hydrogenation reactions in the naphthalene network and to increases in those for hydrogenation reactions in the dibenzothiophene network. Nickel sulfide deposits led to almost no change in the rate constants for hydrogenolysis of dibenzothiophene, but vanadium sulfide deposits led to decreased rate constant for this reaction. The nickel sulfide deposits have little activity for reactions giving lower-molecular-weight (cracking) products, but the vanadium sulfide deposits have a relatively high activity for cracking, which suggests that they are acidic; the effects are reversed by the presence of the basic quinoline in the reactants. The results indicate a need for representing the nickel and vanadium sulfide deposits separately in process models for heavy oil hydroprocessing.

  8. ANIONIC EXCHANGE PROCESS FOR THE RECOVERY OF URANIUM AND VANADIUM FROM CARBONATE SOLUTIONS

    DOE Patents [OSTI]

    Bailes, R.H.; Ellis, D.A.; Long, R.S.

    1958-12-16

    Uranium and vanadium can be economically purified and recovered from non- salt roast carbonate leach liquors by adsorption on a strongly basic anionic exchange resin and subsequent selective elution by one of three alternative methods. Method 1 comprises selectively eluting uranium from the resin with an ammonium sulfate solution followed by eluting vanadium from the resin with either 5 M NaCl, saturated (NH/sub 4/)/sub 2/CO/sub 3/, saturated NaHCO/sub 3/, 1 M NaOH, or saturated S0/sub 2/ solutions. Method II comprises selectively eluting vanadium from the resin with either concentrated NaCl or S0/sub 2/ solutions subsequent to pretreatment of the column with either S0/sub 2/ gas, 1 N HCl, or 0.1 N H/sub 2/8O/sub 4/ followed by eluting uranium from the resin with solutions containing 0.9 M NH/sub 4/Cl or NaCl and 0.1 Cl. Method III comprises flowing the carbonate leac solutlon through a first column of a strongly basic anlonlc exchange resin untll vanadium breakthrough occurs, so that the effluent solution is enriched ln uranium content and the vanadium is chiefly retalned by the resln, absorbing the uranlum from the enriched effluent solution on a second column of a strongly basic anionic exchange resin, pretreating the first column with either 0.1 N HCl, 0.1 H/sub 2/SO/sub 4/, C0/sub 2/ gas, or ammonium sulfate, selectively eluting the vanadlum from the column with saturated S0/sub 2/ solution, pretreatlng the second column with either 0.1 N HCl or S0/sub 2/ gas, selectively eluting residual vanadium from the column with saturated S0/sub 2/ solution, and then eluting the uranium from the column with either 0.1 N HCl and 1 N NaCl orO.l N HCl and 1 N NH/sub 4/Cl.

  9. Zinc subsea production system: An overview

    SciTech Connect (OSTI)

    Bednar, J.M. )

    1994-04-01

    Exxon Co. U.S.A.'s Zinc development, in 1,460 ft of water in the Gulf of Mexico, uses a subsea production system to produce gas to a host platform 6 miles away. The 10-slot subsea template, designed specifically to accommodate the soft soil conditions at the Zinc site, supports the non-through-flowline (non-TFL) wells, which are controlled by means of an electrohydraulic control system. This paper describes key features of the development.

  10. Hyper-dendritic nanoporous zinc foam anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chamoun, Mylad; Hertzberg, Benjamin J.; Gupta, Tanya; Davies, Daniel; Bhadra, Shoham; Van Tassell, Barry.; Erdonmez, Can; Steingart, Daniel A.

    2015-04-24

    The low cost, significant reducing potential, and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1 - 96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrastmore » to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~ 88% at full depth-of-discharge at various rates indicating a superb rate-capability. The rechargeability of Zn⁰/Zn²⁺ showed significant capacity retention over 100 cycles at a 40% depth-of-discharge to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge-discharge cycling and presented superior performance compared to bulk zinc electrodes.« less

  11. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  12. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  13. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  14. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Commercial Buildings Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration...

  15. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  16. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  17. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Revised: December, 2008 Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other All Buildings...

  18. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other All Buildings*...

  19. Carbon nanotube-induced preparation of vanadium oxide nanorods: Application as a catalyst for the partial oxidation of n-butane

    SciTech Connect (OSTI)

    Chen Xiaowei; Zhu Zhenping; Haevecker, Michael; Su Dangsheng . E-mail: dangsheng@fhi-berlin.mpg.de; Schloegl, Robert

    2007-02-15

    A vanadium oxide-carbon nanotube composite was prepared by solution-based hydrolysis of NH{sub 4}VO{sub 3} in the presence of carbon nanotubes. The carbon nanotubes induce the nucleation of the 1D vanadium oxide nanostructures, with the nuclei growing into long freestanding nanorods. The vanadium oxide nanorods with the lengths up to 20 {mu}m and the widths of 5-15 nm exhibit a well-ordered crystalline structure. Catalytic tests show that the composite with nanostructured vanadium oxide is active for the partial oxidation of n-butane to maleic anhydride at 300 deg. C.

  20. Phase-selective vanadium dioxide (VO{sub 2}) nanostructured thin films by pulsed laser deposition

    SciTech Connect (OSTI)

    Masina, B. N. E-mail: slafane@cdta.dz; Lafane, S. E-mail: slafane@cdta.dz; Abdelli-Messaci, S.; Kerdja, T.; Wu, L.; Akande, A. A.; Mwakikunga, B.

    2015-10-28

    Thin films of monoclinic nanostructured vanadium dioxide are notoriously difficult to produce in a selective manner. To date, post-annealing, after pulsed laser deposition (PLD), has been used to revert the crystal phase or to remove impurities, and non-glass substrates have been employed, thus reducing the efficacy of the transparency switching. Here, we overcome these limitations in PLD by optimizing a laser-ablation and deposition process through optical imaging of the laser-induced plasma. We report high quality monoclinic rutile-type vanadium dioxide (VO{sub 2}) (M1) nanoparticles without post-annealing, and on a glass substrate. Our samples demonstrate a reversible metal-to-insulator transition at ∼43 °C, without any doping, paving the way to switchable transparency in optical materials at room temperature.

  1. PROCESS FOR RECOVERY OF URANIUM AND VANADIUM FROM CARBONATE SOLUTIONS BY REDUCTION-PRECIPITATION

    DOE Patents [OSTI]

    Ellis, D.A.; Lindblom, R.O.

    1957-09-24

    A process employing carbonate leaching of ores and an advantageous methcd of recovering the uranium and vanadium from the leach solution is described. The uranium and vanadium can be precipitated from carbonate leach solutions by reaction with sodium amalgam leaving the leach solution in such a condition that it is economical to replenish for recycling. Such a carbonate leach solution is treated with a dilute sodium amalgam having a sodium concentration within a range of about 0.01 to 0.5% of sodium. Efficiency of the treatment is dependent on at least three additional factors, intimacy of contact of the amalgam with the leach solution, rate of addition of the amalgam and exclusion of oxygen (air).

  2. Phase transition and strength of vanadium under shock compression up to 88 GPa

    SciTech Connect (OSTI)

    Yu, Yuying Tan, Ye; Dai, Chengda; Li, Xuemei; Li, Yinghua; Wu, Qiang; Tan, Hua

    2014-11-17

    A series of reverse-impact experiments were performed on vanadium at shock pressure ranging from 32 GPa to 88 GPa. Particle velocity profiles measured at sample/LiF window interface were used to estimate the sound velocities, shear modulus, and yield stress in shocked vanadium. A phase transition at ∼60.5 GPa that may be the body-centered cubic (BCC) to rhombohedral structure was identified by the discontinuity of the sound velocity against shock pressure. This transition pressure is consistent with the results from diamond anvil cell (DAC) experiments and first-principle calculations. However, present results show that the rhombohedral phase has higher strength and shear modulus than the BCC phase, which is contrast to the findings from DAC experiments and theoretical work.

  3. Zinc air refuelable battery: alternative zinc fuel morphologies and cell behavior

    SciTech Connect (OSTI)

    Cooper, J.F.; Krueger, R.

    1997-01-01

    Multicell zinc/air batteries have been tested previously in the laboratory and as part of the propulsion system of an electric bus; cut zinc wire was used as the anode material. This battery is refueled by a hydraulic transport of 0.5-1 mm zinc particles into hoppers above each cell. We report an investigation concerning alternative zinc fuel morphologies, and energy losses associated with refueling and with overnight or prolonged standby. Three types of fuel pellets were fabricated, tested and compared with results for cut wire: spheres produced in a fluidized bed electrolysis cell; elongated particles produced by gas-atomization; and pellets produced by chopping 1 mm porous plates made of compacted zinc fines. Relative sizes of the particles and cell gap dimensions are critical. All three types transported within the cell 1553 and showed acceptable discharge characteristics, but a fluidized bed approach appears especially attractive for owner/user recovery operations.

  4. Zinc halogen battery electrolyte composition with lead additive

    DOE Patents [OSTI]

    Henriksen, Gary L.

    1981-01-01

    This disclosure relates to a zinc halogen battery electrolyte composition containing an additive providing improved zinc-on-zinc recyclability. The improved electrolyte composition involves the use of a lead additive to inhibit undesirable irregular plating and reduce nodular or dendritic growth on the electrode surface. The lead-containing electrolyte composition of the present invention appears to influence not only the morphology of the base plate zinc, but also the morphology of the zinc-on-zinc replate. In addition, such lead-containing electrolyte compositions appear to reduce hydrogen formation.

  5. Parallel Total Energy

    Energy Science and Technology Software Center (OSTI)

    2004-10-21

    This is a total energy electronic structure code using Local Density Approximation (LDA) of the density funtional theory. It uses the plane wave as the wave function basis set. It can sue both the norm conserving pseudopotentials and the ultra soft pseudopotentials. It can relax the atomic positions according to the total energy. It is a parallel code using MP1.

  6. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    SciTech Connect (OSTI)

    Hudak, Nicholas S.

    2013-12-31

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron–vanadium, and iron–chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantities measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. As a result, proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.

  7. X-Ray Absorption Studies of Vanadium-Containing Metal Oxide Nanocrystals

    SciTech Connect (OSTI)

    Hohn, Keith, L.

    2006-01-09

    Metal oxide nanocrystals offer significant potential for use as catalysts or catalyst supports due to their high surface areas and unique chemical properties that result from the high number of exposed corners and edges. However, little is known about the catalytic activity of these materials, especially as oxidation catalysts. This research focused on the preparation, characterization and use of vanadium-containing nanocrystals as selective oxidation catalysts. Three vanadium-containing nanocrystals were prepared using a modified sol-gel procedure: V/MgO, V/SiO2, and vanadium phosphate (VPO). These represent active oxidation catalysts for a number of industrially relevant reactions. The catalysts were characterized by x-ray diffraction and Raman, UV-VIS, infrared and x-ray absorption spectroscopies with the goal of determining the primary structural and chemical differences between nanocrystals and microcrystals. The catalytic activity of these catalysts was also studied in oxidative dehydrogenation of butane and methanol oxidation to formaldehyde. V/MgO nanocrystals were investigated for activity in oxidative dehydrogenation of butane and compared to conventional V/MgO catalysts. Characterization of V/MgO catalysts using Raman spectroscopy and x-ray absorption spectroscopy showed that both types of catalysts contained magnesium orthovanadate at vanadium loadings below 15 weight%, but above that loading, magnesium pyrovanadate may have been present. In general, MgO nanocrystals had roughly half the crystal size and double the surface area of the conventional MgO. In oxidative dehydrogenation of butane, nanocrystalline V/MgO gave higher selectivity to butene than conventional V/MgO at the same conversion. This difference was attributed to differences in vanadium domain size resulting from the higher surface areas of the nanocrystalline support, since characterization suggested that similar vanadium phases were present on both types of catalysts. Experiments in

  8. Joint perpendicular anisotropy and strong interlayer exchange coupling in systems with thin vanadium spacers

    SciTech Connect (OSTI)

    Devolder, T. Le Goff, A.; Eimer, S.; Adam, J.-P.

    2015-04-28

    We study the influence of the insertion of a vanadium spacer layer between an FeCoB layer and a [Co/Ni] multilayer in an MgO substrate-based system mimicking the reference system of a perpendicular anisotropy magnetic tunnel junction. The anisotropy of the [Co/Ni] multilayer gradually improves with the vanadium thicknesses t, up to an optimized state for t = 8 Å, with little influence of the thermal annealing. The interlayer exchange coupling is ferromagnetic and very strong for t≤6 Å. It can be adjusted by thermal treatment at t = 8 Å from no coupling in the as-grown state to more than 2 mJ/m{sup 2} after 250 °C annealing. For this spacer thickness, the magnetic properties are consistent with the occurrence of a bcc (001) to an fcc (111) crystalline structure transition at the vanadium spacer. The remaining interlayer exchange coupling at t = 8 Å is still substantially higher than the one formerly obtained with a Tantalum spacer, which holds promise for further optimization of the reference layers of tunnel junctions meant for magnetic random access memories.

  9. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hudak, Nicholas S.

    2013-12-31

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron–vanadium, and iron–chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantitiesmore » measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. As a result, proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.« less

  10. U.S. Total Exports

    Gasoline and Diesel Fuel Update (EIA)

    Total to Chile Sabine Pass, LA Total to China Kenai, AK Sabine Pass, LA Total to Egypt ... Sabine Pass, LA Total to Russia Total to South Korea Freeport, TX Sabine Pass, LA Total ...

  11. Summary Max Total Units

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summary Max Total Units *If All Splits, No Rack Units **If Only FW, AC Splits 1000 52 28 28 2000 87 59 35 3000 61 33 15 4000 61 33 15 Totals 261 153 93 ***Costs $1,957,500.00 $1,147,500.00 $697,500.00 Notes: added several refrigerants removed bins from analysis removed R-22 from list 1000lb, no Glycol, CO2 or ammonia Seawater R-404A only * includes seawater units ** no seawater units included *** Costs = (total units) X (estimate of $7500 per unit) 1000lb, air cooled split systems, fresh water

  12. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Survey: Energy End-Use Consumption Tables Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other...

  13. ARM - Measurement - Total carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total carbon The total concentration of carbon in all its organic and non-organic forms. Categories Atmospheric Carbon, Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  14. Ion flotation of zinc using ethylhexadecyldimethylammonium bromide

    SciTech Connect (OSTI)

    McDonald, C.W.; Ogunkeye, O.A.

    1981-01-01

    Zinc ions react with the surfactant ethylhexadecyldimethylammonium bromide (EHDABr) to form a surface active sublate which can be removed from aqueous chloride solutions by ion flotation. A typical ion flotation procedure involves passing air through a 235-ml solution containing 5 ppM Zn/sup 2 +/, 2.0 M HCl, and 2.5 x 10/sup -3/ M EHDABr at a flow rate of 40 ml/min for 150 min. The procedure is simple and rapid. Cadmium, copper, lead, and nickel ions cause reductions of zinc flotation efficiencies of less than 2.5% under the experimental conditions. 5 tables.

  15. Total DOE/NNSA

    National Nuclear Security Administration (NNSA)

    8 Actuals 2009 Actuals 2010 Actuals 2011 Actuals 2012 Actuals 2013 Actuals 2014 Actuals 2015 Actuals Total DOE/NNSA 4,385 4,151 4,240 4,862 5,154 5,476 7,170 7,593 Total non-NNSA 3,925 4,017 4,005 3,821 3,875 3,974 3,826 3765 Total Facility 8,310 8,168 8,245 8,683 9,029 9,450 10,996 11,358 non-NNSA includes DOE offices and Strategic Parternship Projects (SPP) employees NNSA M&O Employee Reporting

  16. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C.; McLarnon, Frank R.; Cairns, Elton J.

    1995-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing one or more hydroxides having the formula M(OH), one or more fluorides having the formula MF, and one or more carbonates having the formula M.sub.2 CO.sub.3, where M is a metal selected from the group consisting of alkali metals. The electrolyte inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  17. A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-scale Energy Storage

    SciTech Connect (OSTI)

    Li, Liyu; Kim, Soowhan; Wang, Wei; Vijayakumar, M.; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang; Hu, Jian Z.; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo

    2011-05-01

    Low cost, high performance redox flow batteries are highly demanded for up to multi-megawatt levels of renewable and grid energy storage. Here, we report a new vanadium redox flow battery with a significant improvement over the current technologies. This new battery utilizes a sulfate-chloride mixed solution, which is capable of dissolving more than 2.5 M vanadium or about a 70% increase in the energy storage capacity over the current vanadium sulfate system. More importantly, the new electrolyte remains stable over a wide temperature range of -5 to 60oC, potentially eliminating the need of active heat management. Its high energy density, broad operational temperature window, and excellent electrochemical performance would lead to a significant reduction in the cost of energy storage, thus accelerating its market penetration.

  18. Zinc-bromine batteries with improved electrolyte

    SciTech Connect (OSTI)

    Kantner, E.

    1985-01-01

    The coulombic efficiency of aqueous zinc bromine batteries can be increased if, in addition to the bromide ions required to be present in the electrolyte to charge the cell to rated capacity, chloride ions are added to the electrolyte in amounts sufficient to reduce the amount of free bromine present in the electrolyte during operation of the cell.

  19. Zinc bromide battery development. Final report

    SciTech Connect (OSTI)

    Leo, A.

    1986-01-01

    Earlier EPRI work demonstrated the potential of zinc bromide batteries to provide long-life, low-cost energy storage for utilities. The latest developments, summarized in this report, include improvements in electrode, separator, and other components, as well as successful testing of cell stacks.

  20. Zinc Bromide Waste Solution Treatment Options

    SciTech Connect (OSTI)

    Langston, C.A.

    2001-01-16

    The objective of this effort was to identify treatment options for 20,000 gallons of low-level radioactively contaminated zinc bromide solution currently stored in C-Area. These options will be relevant when the solutions are declared waste.

  1. Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

    2013-04-22

    Redox flow batteries (RFBs) are capable of reversible conversion between electricity and chemical energy. Potential RFB applications resolve around mitigating the discrepancy between electricity production and consumption to improve the stability and utilization of the power infrastructure and tackling the intermittency of renewables such as photovoltaics or wind turbines to enable their reliable integration [1, 2]. Because the energy is stored in externally contained liquid electrolytes and the energy conversion reactions take place at the electrodes, RFBs hold a unique capability to separate energy and power and thus possess considerable design flexibility to meet either energy management driven or power rating oriented grid applications, which is considered to be a unparalleled advantage over conventional solid-state secondary batteries [3]. Other advantages of RFBs include fast response to load changes, high round-trip efficiency, long calender and cycle lives, safe operations, tolerance to deep discharge, etc. [4]. Among various flow battery chemistries, all-vanadium redox flow battery (VRB) was invented by Maria Skyllas-Kazacos at the University of New South Wales in the 1980s [5, 6] and have attracted substantial attention in both research and industrial communities today [7, 8]. A well-recognized advantage that makes VRB stands out among other redox chemistries is the reduced crossover contamination ascribed to employing four different oxidation states of the same vanadium element as the two redox couples. Recently, great progress has led to remarkably improved energy density of VRB by using sulfuric-chloric mixed acid supporting electrolytes that were stable at 2.5M vanadium and had wider operational temperature window of -5~50oC [9], compared with the traditional sulfuric acid VRB system [10].

  2. Preparation of ionic membranes for zinc/bromine storage batteries

    SciTech Connect (OSTI)

    Assink, R.A.; Arnold, C. Jr.

    1991-01-01

    Zinc/bromine flow batteries are being developed for vehicular and utility load leveling applications. During charge, an aqueous zinc bromide salt is electolyzed to zinc metal and molecular bromine. During discharge, the zinc and bromine react to again form the zinc bromide salt. One serious disadvantage of the microporous separators presently used in the zinc/bromine battery is that modest amounts of bromine and negatively charged bromine moieties permeate through these materials and react with the zinc anode. This results in partial self-discharge of the battery and low coulombic efficiencies. Our approach to this problem is to impregnate the microporous separators with a soluble cationic polyelectrolyte. In laboratory screening tests a sulfonated polysulfone resin and fully fluorinated sulfonic acid polymer substantially reduced bromine permeation with only modest increases in the area resistance. 5 refs., 6 figs., 11 tabs.

  3. Process for preparing zinc oxide-based sorbents

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar; Turk, Brian Scott; Gupta, Raghubir Prasad

    2011-06-07

    The disclosure relates to zinc oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  4. Chemical structure of vanadium-based contact formation on n-AlN

    SciTech Connect (OSTI)

    Pookpanratana, S.; France, R.; Blum, M.; Bell, A.; Bar, M.; Weinhardt, L.; Zhang, Y.; Hofmann, T.; Fuchs, O.; Yang, W.; Denlinger, J. D.; Mulcahy, S.; Moustakas, T. D.; Heske, Clemens

    2010-05-17

    We have investigated the chemical interaction between a Au/V/Al/V layer structure and n-type AlN epilayers using soft x-ray photoemission, x-ray emission spectroscopy, and atomic force microscopy. To understand the complex processes involved in this multicomponent system, we have studied the interface before and after a rapid thermal annealing step. We find the formation of a number of chemical phases at the interface, including VN, metallic vanadium, aluminum oxide, and metallic gold. An interaction mechanism for metal contact formation on the entire n-(Al,Ga)N system is proposed.

  5. Effects of irradiation to 4 dpa at 390 C on the fracture toughness of vanadium alloys

    SciTech Connect (OSTI)

    Gruber, E.E.; Galvin, T.M.; Chopra, O.K.

    1998-09-01

    Fracture toughness J-R curve tests were conducted at room temperature on disk-shaped compact-tension DC(T) specimens of three vanadium alloys having a nominal composition of V-4Cr-4Ti. The alloys in the nonirradiated condition showed high fracture toughness; J{sub IC} could not be determined but is expected to be above 600 kJ/m{sup 2}. The alloys showed very poor fracture toughness after irradiation to 4 dpa at 390 C, e.g., J{sub IC} values of {approx}10 kJ/m{sup 2} or lower.

  6. Heterogeneous nucleation and growth dynamics in the light-induced phase transition in vanadium dioxide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brady, Nathaniel F.; Appavoo, Kannatassen; Seo, Minah; Nag, Joyeeta; Prasankumar, Rohit P.; Haglund, Richard F.; Hilton, David J.

    2016-03-02

    Here we report on ultrafast optical investigations of the light-induced insulator-to-metal phase transition in vanadium dioxide with controlled disorder generated by substrate mismatch. These results reveal common dynamics of this optically-induced phase transition that are independent of this disorder. Lastly, above the fluence threshold for completing the transition to the rutile crystalline phase, we find a common time scale, independent of sample morphology, of 40.5 ± 2 ps that is consistent with nucleation and growth dynamics of the R phase from the parent M1 ground state.

  7. Simultaneous determination of thorium, niobium, lead, and zinc by photon-induced x-ray fluorescence of lateritic material

    SciTech Connect (OSTI)

    LaBrecque, J.J.; Adames, D.; Parker, W.C.

    1981-01-01

    A rapid method is presented for the simultaneous determinations of thorium, niobium, lead, and zinc in lateritic material from Cerro Impacto, Estado Bolivar, Venezuela. This technique uses a PDP - 11/05 processor - based photon induced x-ray fluorescence system. The total variations of approximately 5% for concentrations of approximately 1 and 10% for concentrations of approximately 0.1% were obtained with only 500 s of fluorescent time. The values obtained by this method were in agreement with values measured by conventional flame atomic absorption spectroscopy for lead and zinc. The values for thorium measured were in agreement with the reported values for the reference materials supplied by NBL.

  8. TOTAL WORKFORCE Males

    National Nuclear Security Administration (NNSA)

    76 Females Male Female Male Female Male Female Male Female Male Female 27 24 86 134 65 24 192 171 1189 423 PAY PLAN SES 96 EX 4 EJ/EK 60 EN 05 39 EN 04 159 EN 03 21 EN 00 8 NN (Engineering) 398 NQ (Prof/Tech/Admin) 1165 NU (Tech/Admin Support) 54 NV (Nuc Mat Courier) 325 GS 15 3 GS 14 1 GS 13 1 GS 10 1 Total includes 2318 permanent and 17 temporary employees. DIVERSITY 2335 1559 66.8% American Indian Alaska Native African American Asian American Pacific Islander Hispanic White 33.2% National

  9. Spontaneous and reversible interaction of vanadium(V) oxyanions with amine derivatives

    SciTech Connect (OSTI)

    Crans, D.C.; Shin, P.K.

    1988-05-18

    The interaction between vanadate and tri- or tetradentate ethanolamine derivatives has been studied by using /sup 51/V NMR spectroscopy. The reactions occur spontaneously in aqueous solutions, at ambient temperatures and in the physiological pH range. In addition to one amine group and one hydroxyl group, the ethanolamine derivative should contain a third and/or fourth functionality that is an alcohol, a carboxylic acid, a phosphonium acid, or an amine. The reactions are highly dependent on pH, concentrations of monomeric vanadate, amine. The stability constants for the complexes are minimum orders of magnitude greater than those found for vanadate derivatives of corresponding ether derivatives, and the high stability is associated with the central nitrogen. Only one vanadium complex is formed in substantial amounts in the reaction of ethanolamine derivatives with vanadate, and that complex is mononuclear in vanadium. Several of the ethanolamine derivatives that form complexes are commonly used buffers in biological and biomedical studies in vitro. 22 refs., 10 figs., 7 tabs.

  10. Understanding Aqueous Electrolyte Stability through Combined Computational and Magnetic Resonance Spectroscopy: A Case Study on Vanadium Redox Flow Battery Electrolytes

    SciTech Connect (OSTI)

    Vijayakumar, M.; Nie, Zimin; Walter, Eric D.; Hu, Jian Z.; Liu, Jun; Sprenkle, Vincent L.; Wang, Wei

    2015-02-01

    Redox flow battery (RFB) is a promising candidate for energy storage component in designing resilient grid scale power supply due to the advantage of the separation of power and energy. However, poorly understood chemical and thermal stability issues of electrolytes currently limit the performance of RFB. Designing of high performance stable electrolytes requires comprehensive knowledge about the molecular level solvation structure and dynamics of their redox active species. The molecular level understanding of detrimental V2O5 precipitation process led to successful designing of mixed acid based electrolytes for vanadium redox flow batteries (VRFB). The higher stability of mixed acid based electrolytes is attributed to the choice of hydrochloric acid as optimal co-solvent, which provides chloride anions for ligand exchange process in vanadium solvation structure. The role of chloride counter anion on solvation structure and dynamics of vanadium species were studied using combined magnetic resonance spectroscopy and DFT based theoretical methods. Finally, the solvation phenomenon of multiple vanadium species and their impact on VRFB electrolyte chemical stability were discussed.

  11. Electrolyte for zinc bromine storage batteries

    SciTech Connect (OSTI)

    Ando, Y.; Ochiai, T.

    1985-04-09

    A negative electrolyte for electrolyte circulation-type storage batteries has a composition basically comprising zinc bromide as an active material and this active material is mixed with specified amounts of quaternary ammonium bromides of heterocyclic compounds such as morpholine, pyridine and pyrrolidine or ammonia as a bromine complexing agent and a dendrite inhibitor with or without specified amounts of Sn/sup 2 +/ and Pb/sup 2 +/.

  12. Aluminum-doped Zinc Oxide Nanoink

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2014-08-15

    Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative to the widely used transparent conductive oxide (TCO) indium tin oxide while offering comparable optical and electronic properties. TCOs are used in devices such as flat screen displays, photovoltaic cells, photochromic windows, chemical sensors, and biosensors....

  13. Aluminum doped zinc oxide for organic photovoltaics

    SciTech Connect (OSTI)

    Murdoch, G. B.; Hinds, S.; Sargent, E. H.; Tsang, S. W.; Mordoukhovski, L.; Lu, Z. H.

    2009-05-25

    Aluminum doped zinc oxide (AZO) was grown via magnetron sputtering as a low-cost alternative to indium tin oxide (ITO) for organic photovoltaics (OPVs). Postdeposition ozone treatment resulted in devices with lower series resistance, increased open-circuit voltage, and power conversion efficiency double that of devices fabricated on untreated AZO. Furthermore, cells fabricated using ozone treated AZO and standard ITO displayed comparable performance.

  14. Chemical enhancement of metallized zinc anode performance

    SciTech Connect (OSTI)

    Bennett, J.

    1998-12-31

    Galvanic current delivered to reinforced concrete by a metallized zinc anode was studied relative to the humidity of its environment and periodic direct wetting. Current decreased quickly at low humidity to values unlikely to meet accepted cathodic protection criteria, but could be easily restored by direct wetting of the anode. Thirteen chemicals were screened for their ability to enhance galvanic current. Such chemicals, when applied to the exterior surface of the anode, are easily transported by capillary action to the anode-concrete interface where they serve to maintain the interface conductive and the zinc electrochemically active. The most effective chemicals were potassium and lithium bromide, acetate, chloride and nitrate, which increased galvanic current by a factor of 2--15, depending on relative humidity and chloride contamination of the concrete. This new technique is expected to greatly expand the number of concrete structures which can be protected by simple galvanic cathodic protection, The use of lithium-based chemicals together with metallized zinc anode is also proposed for mitigation of existing problems due to ASR. In this case, lithium which prevents or inhibits expansion due to ASR can be readily injected into the concrete. A new process, electrochemical maintenance of concrete (EMC), is also proposed to benefit reinforced concrete structures suffering from chloride-induced corrosion.

  15. Occupational hypersensitivity pneumonitis in a smelter exposed to zinc fumes

    SciTech Connect (OSTI)

    Ameille, J.; Brechot, J.M.; Brochard, P.; Capron, F.; Dore, M.F. )

    1992-03-01

    A smelter exposed to zinc fumes reported severe recurrent episodes of cough, dyspnea and fever. Bronchoalveolar lavage showed a marked increase in lymphocytes count with predominance of CD8 T-lymphocytes. Presence of zinc in alveolar macrophages was assessed by analytic transmission electron microscopy. This is the first case of recurrent bronchoalveolitis related to zinc exposure in which the clinical picture and BAL results indicate a probable hypersensitivity pneumonitis.

  16. Excitation Energies of Zinc Porphyrin in Aqueous Solution Using...

    Office of Scientific and Technical Information (OSTI)

    Theory Citation Details In-Document Search Title: Excitation Energies of Zinc Porphyrin in Aqueous Solution Using Long-Range Corrected Time-Dependent Density Functional Theory ...

  17. Weldability of cast and heat treated uranium-0.25% vanadium alloy

    SciTech Connect (OSTI)

    Sunwoo, A.

    1997-09-01

    Weldability of a grain refined cast uranium-0.2% vanadium (U-0.2% V) alloy is a concern since the alloy is reported to be sensitive to delay weld cracking. Welding of unalloyed wrought U is not free of weld defects. Deep, single-pass electron beam welds in U have been plagued by cold-shuts in the fusion zone. Cold-shuts have not been observed in the cast U-0.2% V alloy. The purpose of this work was to address the weldability concern for a cast and helium isothermally transformed U-0.25% V alloy and to determine the effects of welding on the weldment properties.

  18. Characterization of vanadium ion uptake in sulfonated diels alder poly(phenylene) membranes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lawton, Jamie; Jones, Amanda; Tang, Zhijiang; Lindsey, Melanie; Zawodzinski, Thomas A

    2015-11-28

    Sulfonated diels alder poly(phenylene) (SDAPP), alternative aromatic hydrocarbon membranes for vanadium redox flow batteries (VRFBs) are characterized using electron paramagnetic resonance (EPR). Membranes soaked in sulfuric acid and vanadyl sulfate are analyzed to determine the membrane environment in which the vanadyl ion (VO2+) diffuses in the membranes. These results are compared to Nafion 117 membranes. In contrast to Nafion, the VO2+ in SDAPP membranes exists in two different environments. The results of analysis of rotational diffusion determined from fits the EPR spectral lineshapes in comparison with previously reported permeation studies and measurements of partitioning functions reported here suggest that themore » diffusion pathways in SDAPP are very different than in Nafion.« less

  19. Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics

    SciTech Connect (OSTI)

    Sathish, M.; Eraiah, B.

    2014-04-24

    Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

  20. Characterization of vanadium ion uptake in sulfonated diels alder poly(phenylene) membranes

    SciTech Connect (OSTI)

    Lawton, Jamie; Jones, Amanda; Tang, Zhijiang; Lindsey, Melanie; Zawodzinski, Thomas A

    2015-11-28

    Sulfonated diels alder poly(phenylene) (SDAPP), alternative aromatic hydrocarbon membranes for vanadium redox flow batteries (VRFBs) are characterized using electron paramagnetic resonance (EPR). Membranes soaked in sulfuric acid and vanadyl sulfate are analyzed to determine the membrane environment in which the vanadyl ion (VO2+) diffuses in the membranes. These results are compared to Nafion 117 membranes. In contrast to Nafion, the VO2+ in SDAPP membranes exists in two different environments. The results of analysis of rotational diffusion determined from fits the EPR spectral lineshapes in comparison with previously reported permeation studies and measurements of partitioning functions reported here suggest that the diffusion pathways in SDAPP are very different than in Nafion.

  1. Thermally driven analog of the Barkhausen effect at the metal-insulator transition in vanadium dioxide

    SciTech Connect (OSTI)

    Huber-Rodriguez, Benjamin; Ji, Heng; Chen, Chih-Wei; Kwang, Siu Yi; Hardy, Will J.; Morosan, Emilia; Natelson, Douglas

    2014-09-29

    The physics of the metal-insulator transition (MIT) in vanadium dioxide remains a subject of intense interest. Because of the complicating effects of elastic strain on the phase transition, there is interest in comparatively strain-free means of examining VO{sub 2} material properties. We report contact-free, low-strain studies of the MIT through an inductive bridge approach sensitive to the magnetic response of VO{sub 2} powder. Rather than observing the expected step-like change in susceptibility at the transition, we argue that the measured response is dominated by an analog of the Barkhausen effect, due to the extremely sharp jump in the magnetic response of each grain as a function of time as the material is cycled across the phase boundary. This effect suggests that future measurements could access the dynamics of this and similar phase transitions.

  2. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  3. Zinc electrode morphology in acid electrolytes. Annual report, March 15, 1982-March 15, 1983

    SciTech Connect (OSTI)

    McBreen, J.; Gannon, E.

    1983-07-01

    The zinc electrode is common to both zinc/chlorine and zinc/bromine flow batteries. Although considerable progress has been made in engineering these batteries, there are still problems with the zinc electrode. The objective of this work is to elucidate the mechanism of zinc deposition in acid electrolytes and to devise methods to control zinc electrode morphology. In this subcontract, work focused on obtaining baseline data in ultra pure zinc chloride and zinc bromide electrolytes. Emphasis was on the initial stages of electrocrystallization. In addition, the effect of modified charging methods, organic surfactants, inorganic additives and substrates was investigated.

  4. Multiple Redox Modes in the Reversible Lithiation of High-Capacity, Peierls-Distorted Vanadium Sulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Britto, Sylvia; Leskes, Michal; Hua, Xiao; Hébert, Claire-Alice; Shin, Hyeon Suk; Clarke, Simon; Borkiewicz, Olaf; Chapman, Karena W.; Seshadri, Ram; Cho, Jaephil; et al

    2015-06-08

    Vanadium sulfide VS4 in the patronite mineral structure, is a linear chain compound comprising vanadium atoms coordinated by disulfide anions [S2]2–. 51V NMR shows that the material, despite having V formally in the d1 configuration, is diamagnetic, suggesting potential dimerization through metal-metal bonding associated with a Peierls distortion of the linear chains. This is supported by density functional calculations, and is also consistent with the observed alternation in V-V distances of 2.8 Å and 3.2 Å along the chains. Partial lithiation results in reduction of the disulfide ions to sulfide S2–, including via an internal redox process whereby an electronmore » from V4+ is transferred to [S2]2– resulting in oxidation of V4+ to V5+ and reduction of the [S2]2– to S2- to form Li3VS4 containing tetrahedral [VS4]3– anions. On further lithiation this is followed by reduction of the V5+ in Li3VS4 to form Li3+xVS4 (x=0.5-1), a mixed valent V4+/V5+ compound. Eventually reduction to Li2S plus elemental V occurs. Despite the complex redox processes involving both the cation and the anion occurring in this material, the system is found to be partially reversible between 0 and 3 V. In conclusion, the unusual redox processes in this system are elucidated using a suite of short range characterization tools including 51V Nuclear Magnetic Resonance spectroscopy (NMR), S Kedge X-ray Absorption Near Edge Spectroscopy (XANES) and Pair Distribution Function (PDF) Analysis of X-ray data.« less

  5. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  6. EFFECTIVENESS OF COPPER AND BRONZE FOR ZINC CAPTURE

    SciTech Connect (OSTI)

    Korinko, P. S.

    2012-11-02

    A series of experiments was conducted to determine the efficacy of using copper and bronze sheet and screen under high vacuum conditions to capture zinc vapor. The experiments were conducted in a parametric manner using a fixed zinc vaporization temperature (350°C) but varying the filter temperature from ambient to 550°C. Consistent with previous work, metallic zinc was deposited at low temperatures, but the deposit was non‐adherent. At an intermediate temperature range (350‐450°C), the deposit formed an alloy with both copper and bronze materials. At higher temperatures (> 500°C) the zinc did not deposit on the surfaces likely due to its high vapor pressure. Additional testing to optimize the zinc 'getter' chemistry and surface condition is warranted.

  7. U.S. Total Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    Barbados Total To Brazil Freeport, TX Sabine Pass, LA Total to Canada Eastport, ID Calais, ME Detroit, MI Marysville, MI Port Huron, MI Crosby, ND Portal, ND Sault St. Marie, MI St. Clair, MI Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Morgan, MT Sherwood, ND Pittsburg, NH Buffalo, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Sweetgrass, MT Total to Chile Sabine Pass, LA Total to China Kenai, AK Sabine Pass, LA Total to Egypt Freeport, TX Total to India

  8. Cadmium, copper, cobalt, nickel, lead, and zinc in the water column of the Weddell Sea, Antarctica

    SciTech Connect (OSTI)

    Westerlund, S.; Oehman, P. Chalmers Univ. of Technology, Goeteborg )

    1991-08-01

    This paper presents results from the first complete investigation of the dissolved and suspended trace metals cadmium, copper, cobalt, nickel, lead, and zinc in the water column of the Weddell Sea, Antarctica. A total of 35 stations was covered in the central Weddell Sea and the shelf areas around the Filchner Depression and Dronning Mauds Land. Snow samples were collected from the sea ice and from the Antarctic continent to evaluate the importance of the fresh water influence on the Weddell Sea. Oceanographic data, i.e., salinity, temperature, and nutrients, are used to link the trace metal results to the different water masses. The general range found is for cadmium, 0.5-0.8 nM; copper, 2.0-2.9 nM; cobalt, 20-40 nM; nickel, 6-7 nM; lead, 10 pM; zinc, 3-7 nM. The suspended trace metals are a small fraction, but considerably higher than in other oceans. The lowest concentrations of cadmium, copper, and zinc are found in the surface layer and in the whole water column at the Filchner Depression. Cobalt shows an increase in the surface water compared to the deep water. This is suggested to be generated by the terrogent material from the Antarctic continent from the melting of the ice. No evidence of anthropogenic lead can be seen in the lead profile. Nutrient trace metal relations found show poor statistical correlation in contrast to what is found in other oceans. This assumes that cadmium, copper, and zinc are not directly linked to the bioproduction cycle. However, the nutrient trace metal ratios found support the theory that the Weddell Sea is the ultimate source for generation of the nutrient trace metal ratios in the Pacific Ocean.

  9. Electrochemical Aging of Thermal-Sprayed Zinc Anodes on Concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Bullard, S.J.; Covino, B.S. Jr.; Cramer, S.D.; Cryer, C.B.; McGill, G.E.

    1996-10-01

    Thermal-sprayed zinc anodes are used in impressed current cathodic protection systems for some of Oregon's coastal reinforced concrete bridges. Electrochemical aging of zinc anodes results in physical and chemical changes at the zinc-concrete interface. Concrete surfaces heated prior to thermal-spraying had initial adhesion strengths 80 pct higher than unheated surfaces. For electrochemical aging greater than 200 kC/m{sup 2} (5.2 A h/ft{sup 2}), there was no difference in adhesion strengths for zinc on preheated and unheated concrete. Adhesion strengths decreased monotonically after about 400 to 600 kC/m{sup 2} (10.4 to 15.6 A-h/ft{sup 2}) as a result of the reaction zones at the zinc-concrete interface. A zone adjacent to the metallic zinc (and originally part of the zinc coating) was primarily zincite (ZnO), with minor constituents of wulfingite (Zn(OH){sub 2}), simonkolleite (Zn{sub 5}(OH) {sub 8}C{sub l2}{sup .}H{sub 2}O), and hydrated zinc hydroxide sulfates (Zn{sub 4}SO{sub 4}(OH){sub 6}{sup .}xH{sub 2}O). This zone is the locus for cohesive fracture when the zinc coating separates from the concrete during adhesion tests. Zinc ions substitute for calcium in the cement paste adjacent to the coating as the result of secondary mineralization. The initial estimate of the coating service life based on adhesion strength measurements in accelerated impressed current cathodic protection tests is about 27 years.

  10. Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries

    SciTech Connect (OSTI)

    Pezeshki, Alan M.; Fujimoto, Cy; Sun, Che -Nan; Mench, Matthew M.; Zawodzinski, Thomas A.; Tang, Z. J.

    2015-11-14

    In this paper, we report on the performance of Diels Alder poly(phenylene) membranes in vanadium redox flow batteries. The membranes were functionalized with quaternary ammonium groups to form an anion exchange membrane (QDAPP) and with sulfonic acid groups to form a cation exchange membrane (SDAPP). Both membrane classes showed similar conductivities in the battery environment, suggesting that the ion conduction mechanism in the material is not strongly affected by the moieties along the polymer backbone. The resistance to vanadium permeation in QDAPP was not improved relative to SDAPP, further suggesting that the polarity of the functional groups do not play a significant role in the membrane materials tested. Both QDAPP and SDAPP outperformed Nafion membranes in cycling tests, with both achieving voltage efficiencies above 85% while maintaining 95% coulombic efficiency while at a current density of 200 mA/cm2.

  11. Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pezeshki, Alan M.; Fujimoto, Cy; Sun, Che -Nan; Mench, Matthew M.; Zawodzinski, Thomas A.; Tang, Z. J.

    2015-11-14

    In this paper, we report on the performance of Diels Alder poly(phenylene) membranes in vanadium redox flow batteries. The membranes were functionalized with quaternary ammonium groups to form an anion exchange membrane (QDAPP) and with sulfonic acid groups to form a cation exchange membrane (SDAPP). Both membrane classes showed similar conductivities in the battery environment, suggesting that the ion conduction mechanism in the material is not strongly affected by the moieties along the polymer backbone. The resistance to vanadium permeation in QDAPP was not improved relative to SDAPP, further suggesting that the polarity of the functional groups do not playmore » a significant role in the membrane materials tested. Both QDAPP and SDAPP outperformed Nafion membranes in cycling tests, with both achieving voltage efficiencies above 85% while maintaining 95% coulombic efficiency while at a current density of 200 mA/cm2.« less

  12. Total Eolica | Open Energy Information

    Open Energy Info (EERE)

    Eolica Jump to: navigation, search Name: Total Eolica Place: Spain Product: Project developer References: Total Eolica1 This article is a stub. You can help OpenEI by expanding...

  13. Neutron and Charged-Particle Induced Cross Sections for Radiochemistry for Isotopes of Scandium, Titanium, Vanadium, Chromium, Manganese, and Iron

    SciTech Connect (OSTI)

    Kelley, K; Hoffman, R D; Dietrich, F S; Bauer, R; Mustafa, M

    2004-11-30

    We have developed a set of modeled nuclear reaction cross sections for use in radiochemical diagnostics. Local systematics for the input parameters required by the Hauser-Feshbach statistical model were developed and used to calculate neutron and proton induced nuclear reaction cross sections in the mass region of scandium, titanium, vanadium, chromium, manganese, and iron (21 {le} Z {le} 26, 20 {le} N {le} 32).

  14. Lithium-vanadium advanced blanket development. ITER final report on U.S. contribution: Task T219/T220

    SciTech Connect (OSTI)

    Smith, D.L.; Mattas, R.F.

    1997-07-01

    The objective of this task is to develop the required data base and demonstrate the performance of a liquid lithium-vanadium advanced blanket design. The task has two main activities related to vanadium structural material and liquid lithium system developments. The vanadium alloy development activity included four subtasks: (1.1) baseline mechanical properties of non irradiated base metal and weld metal joints; (1.2) compatibility with liquid lithium; (1.3) material irradiation tests; and (1.4) development of material manufacturing and joining methods. The lithium blanket technology activity included four subtasks: (2.1) electrical insulation development and testing for liquid metal systems; (2.2) MHD pressure drop and heat transfer study for self-cooled liquid metal systems; (2.3) chemistry of liquid lithium; and (2.4) design, fabrication and testing of ITER relevant size blanket mockups. A summary of the progress and results obtained during the period 1995 and 1996 in each of the subtask areas is presented in this report.

  15. Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

    2013-09-02

    Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

  16. Total..............................................

    U.S. Energy Information Administration (EIA) Indexed Site

    111.1 86.6 2,720 1,970 1,310 1,941 1,475 821 1,059 944 554 Census Region and Division Northeast.................................... 20.6 13.9 3,224 2,173 836 2,219 1,619 583 903 830 Q New England.......................... 5.5 3.6 3,365 2,154 313 2,634 1,826 Q 951 940 Q Middle Atlantic........................ 15.1 10.3 3,167 2,181 1,049 2,188 1,603 582 Q Q Q Midwest...................................... 25.6 21.0 2,823 2,239 1,624 2,356 1,669 1,336 1,081 961 778 East North

  17. Total............................................................

    U.S. Energy Information Administration (EIA) Indexed Site

  18. Total..............................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ,171 1,618 1,031 845 630 401 Census Region and Division Northeast................................................... 20.6 2,334 1,664 562 911 649 220 New England.......................................... 5.5 2,472 1,680 265 1,057 719 113 Middle Atlantic........................................ 15.1 2,284 1,658 670 864 627 254 Midwest...................................................... 25.6 2,421 1,927 1,360 981 781 551 East North Central.................................. 17.7 2,483 1,926 1,269

  19. Total...............................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    20.6 25.6 40.7 24.2 Personal Computers Do Not Use a Personal Computer ........... 35.5 6.9 8.1 14.2 6.4 Use a Personal Computer......................... 75.6 13.7 17.5 26.6 17.8 Number of Desktop PCs 1.......................................................... 50.3 9.3 11.9 18.2 11.0 2.......................................................... 16.2 2.9 3.5 5.5 4.4 3 or More............................................. 9.0 1.5 2.1 2.9 2.5 Number of Laptop PCs

  20. Total...............................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.7 21.7 6.9 12.1 Personal Computers Do Not Use a Personal Computer ........... 35.5 14.2 7.2 2.8 4.2 Use a Personal Computer......................... 75.6 26.6 14.5 4.1 7.9 Number of Desktop PCs 1.......................................................... 50.3 18.2 10.0 2.9 5.3 2.......................................................... 16.2 5.5 3.0 0.7 1.8 3 or More............................................. 9.0 2.9 1.5 0.5 0.8 Number of Laptop PCs

  1. Total...............................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    26.7 28.8 20.6 13.1 22.0 16.6 38.6 Personal Computers Do Not Use a Personal Computer ........... 35.5 17.1 10.8 4.2 1.8 1.6 10.3 20.6 Use a Personal Computer......................... 75.6 9.6 18.0 16.4 11.3 20.3 6.4 17.9 Number of Desktop PCs 1.......................................................... 50.3 8.3 14.2 11.4 7.2 9.2 5.3 14.2 2.......................................................... 16.2 0.9 2.6 3.7 2.9 6.2 0.8 2.6 3 or More............................................. 9.0 0.4 1.2

  2. Total...............................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    47.1 19.0 22.7 22.3 Personal Computers Do Not Use a Personal Computer ........... 35.5 16.9 6.5 4.6 7.6 Use a Personal Computer......................... 75.6 30.3 12.5 18.1 14.7 Number of Desktop PCs 1.......................................................... 50.3 21.1 8.3 10.7 10.1 2.......................................................... 16.2 6.2 2.8 4.1 3.0 3 or More............................................. 9.0 2.9 1.4 3.2 1.6 Number of Laptop PCs

  3. Total.................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    49.2 15.1 15.6 11.1 7.0 5.2 8.0 Have Cooling Equipment............................... 93.3 31.3 15.1 15.6 11.1 7.0 5.2 8.0 Use Cooling Equipment................................ 91.4 30.4 14.6 15.4 11.1 6.9 5.2 7.9 Have Equipment But Do Not Use it............... 1.9 1.0 0.5 Q Q Q Q Q Do Not Have Cooling Equipment................... 17.8 17.8 N N N N N N Air-Conditioning Equipment 1, 2 Central System............................................. 65.9 3.9 15.1 15.6 11.1 7.0 5.2 8.0 Without a Heat

  4. Total.................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Do Not Have Space Heating Equipment........ 1.2 N Q Q 0.2 0.4 0.2 0.2 Q Have Main Space Heating Equipment........... 109.8 14.7 7.4 12.4 12.2 18.5 18.3 17.1 9.2 Use Main Space Heating Equipment............. 109.1 14.6 7.3 12.4 12.2 18.2 18.2 17.1 9.1 Have Equipment But Do Not Use It............... 0.8 Q Q Q Q 0.3 Q N Q Main Heating Fuel and Equipment Natural Gas................................................... 58.2 9.2 4.9 7.8 7.1 8.8 8.4 7.8 4.2 Central

  5. Total..................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    . 111.1 14.7 7.4 12.5 12.5 18.9 18.6 17.3 9.2 Do Not Have Cooling Equipment..................... 17.8 3.9 1.8 2.2 2.1 3.1 2.6 1.7 0.4 Have Cooling Equipment................................. 93.3 10.8 5.6 10.3 10.4 15.8 16.0 15.6 8.8 Use Cooling Equipment.................................. 91.4 10.6 5.5 10.3 10.3 15.3 15.7 15.3 8.6 Have Equipment But Do Not Use it................. 1.9 Q Q Q Q 0.6 0.4 0.3 Q Type of Air-Conditioning Equipment 1, 2 Central

  6. Total...................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    15.2 7.8 1.0 1.2 3.3 1.9 For Two Housing Units............................. 0.9 Q N Q 0.6 N Heat Pump.................................................. 9.2 7.4 0.3 Q 0.7 0.5 Portable Electric Heater............................... 1.6 0.8 Q Q Q 0.3 Other Equipment......................................... 1.9 0.7 Q Q 0.7 Q Fuel Oil........................................................... 7.7 5.5 0.4 0.8 0.9 0.2 Steam or Hot Water System........................ 4.7 2.9 Q 0.7 0.8 N For One Housing

  7. Total...................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Air-Conditioning Equipment 1, 2 Central System............................................... 65.9 47.5 4.0 2.8 7.9 3.7 Without a Heat Pump.................................. 53.5 37.8 3.4 2.2 7.0 3.1 With a Heat Pump....................................... 12.3 9.7 0.6 0.5 1.0 0.6 Window/Wall Units.......................................... 28.9 14.9 2.3 3.5 6.0 2.1 1 Unit........................................................... 14.5 6.6 1.0 1.6 4.2 1.2 2

  8. Total.......................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.6 15.1 5.5 Personal Computers Do Not Use a Personal Computer ................... 35.5 6.9 5.3 1.6 Use a Personal Computer................................ 75.6 13.7 9.8 3.9 Number of Desktop PCs 1.................................................................. 50.3 9.3 6.8 2.5 2.................................................................. 16.2 2.9 1.9 1.0 3 or More..................................................... 9.0 1.5 1.1 0.4 Number of Laptop PCs

  9. Total.......................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    5.6 17.7 7.9 Personal Computers Do Not Use a Personal Computer ................... 35.5 8.1 5.6 2.5 Use a Personal Computer................................ 75.6 17.5 12.1 5.4 Number of Desktop PCs 1.................................................................. 50.3 11.9 8.4 3.4 2.................................................................. 16.2 3.5 2.2 1.3 3 or More..................................................... 9.0 2.1 1.5 0.6 Number of Laptop PCs

  10. Total.......................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    4.2 7.6 16.6 Personal Computers Do Not Use a Personal Computer ................... 35.5 6.4 2.2 4.2 Use a Personal Computer................................ 75.6 17.8 5.3 12.5 Number of Desktop PCs 1.................................................................. 50.3 11.0 3.4 7.6 2.................................................................. 16.2 4.4 1.3 3.1 3 or More..................................................... 9.0 2.5 0.7 1.8 Number of Laptop PCs

  11. Total........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    25.6 40.7 24.2 Do Not Have Space Heating Equipment............... 1.2 Q Q Q 0.7 Have Main Space Heating Equipment.................. 109.8 20.5 25.6 40.3 23.4 Use Main Space Heating Equipment.................... 109.1 20.5 25.6 40.1 22.9 Have Equipment But Do Not Use It...................... 0.8 N N Q 0.6 Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 11.4 18.4 13.6 14.7 Central Warm-Air Furnace................................ 44.7 6.1

  12. Total........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    5.6 17.7 7.9 Do Not Have Space Heating Equipment............... 1.2 Q Q N Have Main Space Heating Equipment.................. 109.8 25.6 17.7 7.9 Use Main Space Heating Equipment.................... 109.1 25.6 17.7 7.9 Have Equipment But Do Not Use It...................... 0.8 N N N Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 18.4 13.1 5.3 Central Warm-Air Furnace................................ 44.7 16.2 11.6 4.7 For One Housing

  13. Total........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.7 21.7 6.9 12.1 Do Not Have Space Heating Equipment............... 1.2 Q Q N Q Have Main Space Heating Equipment.................. 109.8 40.3 21.4 6.9 12.0 Use Main Space Heating Equipment.................... 109.1 40.1 21.2 6.9 12.0 Have Equipment But Do Not Use It...................... 0.8 Q Q N N Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 13.6 5.6 2.3 5.7 Central Warm-Air Furnace................................ 44.7 11.0 4.4

  14. Total........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    7.1 7.0 8.0 12.1 Do Not Have Space Heating Equipment............... 1.2 Q Q Q 0.2 Have Main Space Heating Equipment.................. 109.8 7.1 6.8 7.9 11.9 Use Main Space Heating Equipment.................... 109.1 7.1 6.6 7.9 11.4 Have Equipment But Do Not Use It...................... 0.8 N Q N 0.5 Main Heating Fuel and Equipment Natural Gas.......................................................... 58.2 3.8 0.4 3.8 8.4 Central Warm-Air Furnace................................ 44.7 1.8 Q 3.1 6.0

  15. Total...........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.6 15.1 5.5 Do Not Have Cooling Equipment............................. 17.8 4.0 2.4 1.7 Have Cooling Equipment.......................................... 93.3 16.5 12.8 3.8 Use Cooling Equipment........................................... 91.4 16.3 12.6 3.7 Have Equipment But Do Not Use it.......................... 1.9 0.3 Q Q Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 6.0 5.2 0.8 Without a Heat

  16. Total...........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    5.6 17.7 7.9 Do Not Have Cooling Equipment............................. 17.8 2.1 1.8 0.3 Have Cooling Equipment.......................................... 93.3 23.5 16.0 7.5 Use Cooling Equipment........................................... 91.4 23.4 15.9 7.5 Have Equipment But Do Not Use it.......................... 1.9 Q Q Q Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 17.3 11.3 6.0 Without a Heat

  17. Total...........................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    4.2 7.6 16.6 Do Not Have Cooling Equipment............................. 17.8 10.3 3.1 7.3 Have Cooling Equipment.......................................... 93.3 13.9 4.5 9.4 Use Cooling Equipment........................................... 91.4 12.9 4.3 8.5 Have Equipment But Do Not Use it.......................... 1.9 1.0 Q 0.8 Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 10.5 3.9 6.5 Without a Heat

  18. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Do Not Have Cooling Equipment............................... 17.8 4.0 2.1 1.4 10.3 Have Cooling Equipment............................................ 93.3 16.5 23.5 39.3 13.9 Use Cooling Equipment............................................. 91.4 16.3 23.4 38.9 12.9 Have Equipment But Do Not Use it............................ 1.9 0.3 Q 0.5 1.0 Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 6.0 17.3 32.1 10.5 Without a Heat

  19. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day......................................... 8.2 1.2 1.0 0.2 2 Times A Day...................................................... 24.6 4.0 2.7 1.2 Once a Day........................................................... 42.3 7.9 5.4 2.5 A Few Times Each Week...................................... 27.2 6.0 4.8 1.2 About Once a Week.............................................. 3.9 0.6 0.5 Q Less Than Once a

  20. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day......................................... 8.2 1.4 1.0 0.4 2 Times A Day...................................................... 24.6 5.8 3.5 2.3 Once a Day........................................................... 42.3 10.7 7.8 2.9 A Few Times Each Week...................................... 27.2 5.6 4.0 1.6 About Once a Week.............................................. 3.9 0.9 0.6 0.3 Less Than Once a

  1. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Do Not Have Cooling Equipment............................... 17.8 2.1 1.8 0.3 Have Cooling Equipment............................................ 93.3 23.5 16.0 7.5 Use Cooling Equipment............................................. 91.4 23.4 15.9 7.5 Have Equipment But Do Not Use it............................ 1.9 Q Q Q Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 17.3 11.3 6.0 Without a Heat

  2. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Do Not Have Cooling Equipment............................... 17.8 1.4 0.8 0.2 0.3 Have Cooling Equipment............................................ 93.3 39.3 20.9 6.7 11.8 Use Cooling Equipment............................................. 91.4 38.9 20.7 6.6 11.7 Have Equipment But Do Not Use it............................ 1.9 0.5 Q Q Q Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 32.1 17.6 5.2 9.3 Without a Heat

  3. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day......................................... 8.2 2.6 0.7 1.9 2 Times A Day...................................................... 24.6 6.6 2.0 4.6 Once a Day........................................................... 42.3 8.8 2.9 5.8 A Few Times Each Week...................................... 27.2 4.7 1.5 3.1 About Once a Week.............................................. 3.9 0.7 Q 0.6 Less Than Once a

  4. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Do Not Have Cooling Equipment............................... 17.8 10.3 3.1 7.3 Have Cooling Equipment............................................ 93.3 13.9 4.5 9.4 Use Cooling Equipment............................................. 91.4 12.9 4.3 8.5 Have Equipment But Do Not Use it............................ 1.9 1.0 Q 0.8 Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 10.5 3.9 6.5 Without a Heat

  5. Total.............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Do Not Have Cooling Equipment............................... 17.8 8.5 2.7 2.6 4.0 Have Cooling Equipment............................................ 93.3 38.6 16.2 20.1 18.4 Use Cooling Equipment............................................. 91.4 37.8 15.9 19.8 18.0 Have Equipment But Do Not Use it............................ 1.9 0.9 0.3 0.3 0.4 Type of Air-Conditioning Equipment 1, 2 Central System........................................................ 65.9 25.8 10.9 16.6 12.5 Without a Heat

  6. Total..............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    20.6 25.6 40.7 24.2 Do Not Have Cooling Equipment................................ 17.8 4.0 2.1 1.4 10.3 Have Cooling Equipment............................................. 93.3 16.5 23.5 39.3 13.9 Use Cooling Equipment.............................................. 91.4 16.3 23.4 38.9 12.9 Have Equipment But Do Not Use it............................. 1.9 0.3 Q 0.5 1.0 Air-Conditioning Equipment 1, 2 Central System........................................................... 65.9 6.0 17.3 32.1 10.5

  7. Total..............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    0.7 21.7 6.9 12.1 Do Not Have Cooling Equipment................................ 17.8 1.4 0.8 0.2 0.3 Have Cooling Equipment............................................. 93.3 39.3 20.9 6.7 11.8 Use Cooling Equipment.............................................. 91.4 38.9 20.7 6.6 11.7 Have Equipment But Do Not Use it............................. 1.9 0.5 Q Q Q Air-Conditioning Equipment 1, 2 Central System........................................................... 65.9 32.1 17.6 5.2 9.3 Without a

  8. Total..............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    111.1 7.1 7.0 8.0 12.1 Personal Computers Do Not Use a Personal Computer .......................... 35.5 3.0 2.0 2.7 3.1 Use a Personal Computer....................................... 75.6 4.2 5.0 5.3 9.0 Number of Desktop PCs 1......................................................................... 50.3 3.1 3.4 3.4 5.4 2......................................................................... 16.2 0.7 1.1 1.2 2.2 3 or More............................................................ 9.0 0.3

  9. Total..............................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    7.1 19.0 22.7 22.3 Do Not Have Cooling Equipment................................ 17.8 8.5 2.7 2.6 4.0 Have Cooling Equipment............................................. 93.3 38.6 16.2 20.1 18.4 Use Cooling Equipment.............................................. 91.4 37.8 15.9 19.8 18.0 Have Equipment But Do Not Use it............................. 1.9 0.9 0.3 0.3 0.4 Air-Conditioning Equipment 1, 2 Central System........................................................... 65.9 25.8 10.9 16.6 12.5

  10. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    25.6 40.7 24.2 Personal Computers Do Not Use a Personal Computer.................................. 35.5 6.9 8.1 14.2 6.4 Use a Personal Computer.............................................. 75.6 13.7 17.5 26.6 17.8 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 10.4 14.1 20.5 13.7 Laptop Model............................................................. 16.9 3.3 3.4 6.1 4.1 Hours Turned on Per Week Less than 2

  11. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    5.6 17.7 7.9 Personal Computers Do Not Use a Personal Computer.................................. 35.5 8.1 5.6 2.5 Use a Personal Computer.............................................. 75.6 17.5 12.1 5.4 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 14.1 10.0 4.0 Laptop Model............................................................. 16.9 3.4 2.1 1.3 Hours Turned on Per Week Less than 2

  12. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day................................................. 8.2 3.0 1.6 0.3 1.1 2 Times A Day.............................................................. 24.6 8.3 4.2 1.3 2.7 Once a Day................................................................... 42.3 15.0 8.1 2.7 4.2 A Few Times Each Week............................................. 27.2 10.9 6.0 1.8 3.1 About Once a Week..................................................... 3.9

  13. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Personal Computers Do Not Use a Personal Computer.................................. 35.5 14.2 7.2 2.8 4.2 Use a Personal Computer.............................................. 75.6 26.6 14.5 4.1 7.9 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 20.5 11.0 3.4 6.1 Laptop Model............................................................. 16.9 6.1 3.5 0.7 1.9 Hours Turned on Per Week Less than 2

  14. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    4.2 7.6 16.6 Personal Computers Do Not Use a Personal Computer.................................. 35.5 6.4 2.2 4.2 Use a Personal Computer.............................................. 75.6 17.8 5.3 12.5 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 13.7 4.2 9.5 Laptop Model............................................................. 16.9 4.1 1.1 3.0 Hours Turned on Per Week Less than 2

  15. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Cooking Appliances Frequency of Hot Meals Cooked 3 or More Times A Day................................................. 8.2 3.7 1.6 1.4 1.5 2 Times A Day.............................................................. 24.6 10.8 4.1 4.3 5.5 Once a Day................................................................... 42.3 17.0 7.2 8.7 9.3 A Few Times Each Week............................................. 27.2 11.4 4.7 6.4 4.8 About Once a Week.....................................................

  16. Total....................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    111.1 47.1 19.0 22.7 22.3 Personal Computers Do Not Use a Personal Computer.................................. 35.5 16.9 6.5 4.6 7.6 Use a Personal Computer.............................................. 75.6 30.3 12.5 18.1 14.7 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 22.9 9.8 14.1 11.9 Laptop Model............................................................. 16.9 7.4 2.7 4.0 2.9 Hours Turned on Per Week Less than 2

  17. Total.........................................................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ..... 111.1 7.1 7.0 8.0 12.1 Personal Computers Do Not Use a Personal Computer...................................... 35.5 3.0 2.0 2.7 3.1 Use a Personal Computer.................................................. 75.6 4.2 5.0 5.3 9.0 Most-Used Personal Computer Type of PC Desk-top Model............................................................. 58.6 3.2 3.9 4.0 6.7 Laptop Model................................................................. 16.9 1.0 1.1 1.3 2.4 Hours Turned on Per Week Less

  18. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Basements Basement in Single-Family Homes and Apartments in 2-4 Unit Buildings ... Attics Attic in Single-Family Homes and Apartments in 2-4 Unit Buildings ...

  19. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Climate region 3 Very coldCold 31,898 30,469 28,057 28,228 21,019 30,542 25,067 Mixed-humid 27,873 26,716 24,044 26,365 21,026 27,096 22,812 Mixed-dryHot-dry 12,037 10,484 7,628 ...

  20. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Air-Conditioning Equipment 1, 2 Central System......Central Air-Conditioning...... 65.9 1.1 6.4 6.4 ...

  1. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Income Relative to Poverty Line Below 100 Percent......1.3 1.2 0.8 0.4 1. Below 150 percent of poverty line or 60 percent of median State ...

  2. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Below Poverty Line Eligible for Federal Assistance 1 80,000 or More 60,000 to 79,999 ... Below Poverty Line Eligible for Federal Assistance 1 80,000 or More 60,000 to 79,999 ...

  3. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Table HC7.4 Space Heating Characteristics by Household Income, 2005 Below Poverty Line ... Below Poverty Line Eligible for Federal Assistance 1 80,000 or More Space Heating ...

  4. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    ... Table HC7.7 Air-Conditioning Usage Indicators by Household Income, 2005 Below Poverty Line ... Table HC7.7 Air-Conditioning Usage Indicators by Household Income, 2005 Below Poverty Line ...

  5. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Living Space Characteristics Below Poverty Line Eligible for Federal Assistance 1 Million ... Living Space Characteristics Below Poverty Line Eligible for Federal Assistance 1 Million ...

  6. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Table HC7.12 Home Electronics Usage Indicators by Household Income, 2005 Below Poverty ... Table HC7.12 Home Electronics Usage Indicators by Household Income, 2005 Below Poverty ...

  7. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Table HC7.10 Home Appliances Usage Indicators by Household Income, 2005 Below Poverty Line ... Below Poverty Line Eligible for Federal Assistance 1 40,000 to 59,999 60,000 to 79,999 ...

  8. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    1,001 to 5,000 2,777 8,041 10,232 2.9 786 56 5,001 to 10,000 1,229 8,900 9,225 7.2 965 62 10,001 to 25,000 884 14,105 14,189 16.0 994 65 25,001 to 50,000 332 11,917 11,327 35.9 1,052 72 50,001 to 100,000 199 13,918 12,345 69.9 1,127 80 100,001 to 200,000 90 12,415 11,310 137.9 1,098 89 200,001 to 500,000 38 10,724 10,356 284.2 1,035 99 Over 500,000 8 7,074 9,196 885.0 769 117 Principal building activity Education 389 12,239 10,885 31.5 1,124 53 Food sales 177 1,252 1,172 7.1 1,067 121 Food

  9. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    1,001 to 5,000 2,777 8,041 10,232 2.9 786 56 5,001 to 10,000 1,229 8,900 9,225 7.2 965 62 10,001 to 25,000 884 14,105 14,189 16.0 994 65 25,001 to 50,000 332 11,917 11,327 35.9 1,052 72 50,001 to 100,000 199 13,918 12,345 69.9 1,127 80 100,001 to 200,000 90 12,415 11,310 137.9 1,098 89 200,001 to 500,000 38 10,724 10,356 284.2 1,035 99 Over 500,000 8 7,074 9,196 885.0 769 117 Principal building activity Education 389 12,239 10,885 31.5 1,124 53 Food sales 177 1,252 1,172 7.1 1,067 121 Food

  10. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    1,001 to 5,000 2,777 8,041 10,232 2.9 786 56 5,001 to 10,000 1,229 8,900 9,225 7.2 965 62 10,001 to 25,000 884 14,105 14,189 16.0 994 65 25,001 to 50,000 332 11,917 11,327 35.9 1,052 72 50,001 to 100,000 199 13,918 12,345 69.9 1,127 80 100,001 to 200,000 90 12,415 11,310 137.9 1,098 89 200,001 to 500,000 38 10,724 10,356 284.2 1,035 99 Over 500,000 8 7,074 9,196 885.0 769 117 Principal building activity Education 389 12,239 10,885 31.5 1,124 53 Food sales 177 1,252 1,172 7.1 1,067 121 Food

  11. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    Median square feet per building (thousand) Median square feet per worker Median operating hours per week Median age of buildings (years) All buildings 5,557 87,093 88,182 5.0 1,029 50 32 Building floorspace (square feet) 1,001 to 5,000 2,777 8,041 10,232 2.8 821 49 37 5,001 to 10,000 1,229 8,900 9,225 7.0 1,167 50 31 10,001 to 25,000 884 14,105 14,189 15.0 1,444 56 32 25,001 to 50,000 332 11,917 11,327 35.0 1,461 60 29 50,001 to 100,000 199 13,918 12,345 67.0 1,442 60 26 100,001 to 200,000 90

  12. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Housing Units (millions) UrbanRural Location (as Self-Reported) Living Space ... Housing Units (millions) UrbanRural Location (as Self-Reported) Living Space ...

  13. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Housing Units (millions) UrbanRural Location (as Self-Reported) City Town Suburbs Rural ... Housing Units (millions) UrbanRural Location (as Self-Reported) City Town Suburbs Rural ...

  14. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Living Space Characteristics Detached Attached Energy Information Administration 2005 Residential Energy Consumption Survey: Preliminary Housing Characteristics Tables Table HC3.2 ...

  15. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    Table HC4.2 Living Space Characteristics by Renter-Occupied Housing Units, 2005 2 to 4 Units 5 or More Units Mobile Homes Energy Information Administration 2005 Residential Energy ...

  16. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Per Household Member Average Square Feet Energy Information Administration 2005 Residential Energy Consumption Survey: Preliminary Housing Characteristics Tables Table HC1.2.2 ...

  17. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 111.1 20.6 15.1 5.5 Do Not Have Cooling Equipment...... 17.8 4.0 2.4 1.7 Have Cooling Equipment...... 93.3 ...

  18. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 41.8 2,603 2,199 1,654 941 795 598 1-Car Garage...... 9.5 2,064 1,664 1,039 775 624 390 2-Car Garage......

  19. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Average Square Feet per Apartment in a -- Apartments (millions) Major Outside Wall Construction Siding (Aluminum, Vinyl, Steel)...... 35.3 3.5 1,286 1,090 325 852 786 461 ...

  20. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Type of Renter-Occupied Housing Unit Housing Units (millions) Single-Family Units ... At Home Behavior Home Used for Business Yes......

  1. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Type of Owner-Occupied Housing Unit U.S. Housing Units (millions) Single-Family Units ... At Home Behavior Home Used for Business Yes......

  2. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Housing Characteristics Tables Single-Family Units Detached Type of Housing Unit Table ... At Home Behavior Home Used for Business Yes......

  3. Electrochemical synthesis and characterization of zinc oxalate nanoparticles

    SciTech Connect (OSTI)

    Shamsipur, Mojtaba; Roushani, Mahmoud; Pourmortazavi, Seied Mahdi

    2013-03-15

    Highlights: ? Synthesis of zinc oxalate nanoparticles via electrolysis of a zinc plate anode in sodium oxalate solutions. ? Design of a Taguchi orthogonal array to identify the optimal experimental conditions. ? Controlling the size and shape of particles via applied voltage and oxalate concentration. ? Characterization of zinc oxalate nanoparticles by SEM, UVvis, FT-IR and TGDTA. - Abstract: A rapid, clean and simple electrodeposition method was designed for the synthesis of zinc oxalate nanoparticles. Zinc oxalate nanoparticles in different size and shapes were electrodeposited by electrolysis of a zinc plate anode in sodium oxalate aqueous solutions. It was found that the size and shape of the product could be tuned by electrolysis voltage, oxalate ion concentration, and stirring rate of electrolyte solution. A Taguchi orthogonal array design was designed to identify the optimal experimental conditions. The morphological characterization of the product was carried out by scanning electron microscopy. UVvis and FT-IR spectroscopies were also used to characterize the electrodeposited nanoparticles. The TGDTA studies of the nanoparticles indicated that the main thermal degradation occurs in two steps over a temperature range of 350430 C. In contrast to the existing methods, the present study describes a process which can be easily scaled up for the production of nano-sized zinc oxalate powder.

  4. Zinc-bromine battery development, Sandia Contract 48-8838

    SciTech Connect (OSTI)

    Richards, L.; Vanschalwijk, W.; Albert, G.; Tarjanyi, M.; Leo, A. ); Lott, S. )

    1990-05-01

    This report describes development activities on the zinc-bromine battery system conducted by Energy Research Corporation (ERC). The project was a cost-shared program supported by the US Department of Energy and managed through Sandia. The project began in September 1985 and ran through January 1990. The zinc-bromine battery has been identified as a promising alternative to conventional energy storage options for many applications. The low cost of the battery reactants and the potential for long life make the system an attractive candidate for bulk energy storage applications, such as utility load leveling. The battery stores energy by the electrolysis of an aqueous zinc bromide salt to zinc metal and dissolved bromine. Zinc is plated as a layer on the electrode surface while bromine is dissolved in the electrolyte and carried out of the stack. The bromine is then extracted from the electrolyte with an organic complexing agent in the positive electrolyte storage tank. On discharge the zinc and bromine are consumed, regenerating the zinc bromide salt. 5 refs., 44 figs.

  5. Zinc surface complexes on birnessite: A density functional theory study

    SciTech Connect (OSTI)

    Kwon, Kideok D.; Refson, Keith; Sposito, Garrison

    2009-01-05

    Biogeochemical cycling of zinc is strongly influenced by sorption on birnessite minerals (layer-type MnO2), which are found in diverse terrestrial and aquatic environments. Zinc has been observed to form both tetrahedral (Zn{sup IV}) and octahedral (Zn{sup VI}) triple-corner-sharing surface complexes (TCS) at Mn(IV) vacancy sites in hexagonal birnessite. The octahedral complex is expected to be similar to that of Zn in the Mn oxide mineral, chalcophanite (ZnMn{sub 3}O{sub 7} {center_dot} 3H{sub 2}O), but the reason for the occurrence of the four-coordinate Zn surface species remains unclear. We address this issue computationally using spin-polarized Density Functional Theory (DFT) to examine the Zn{sub IV}-TCS and Zn{sup VI}-TCS species. Structural parameters obtained by DFT geometry optimization were in excellent agreement with available experimental data on Zn-birnessites. Total energy, magnetic moments, and electron-overlap populations obtained by DFT for isolated Zn{sup IV}-TCS revealed that this species is stable in birnessite without a need for Mn(III) substitution in the octahedral sheet and that it is more effective in reducing undersaturation of surface O at a Mn vacancy than is Zn{sub VI}-TCS. Comparison between geometry-optimized ZnMn{sub 3}O{sub 7} {center_dot} 3H{sub 2}O (chalcophanite) and the hypothetical monohydrate mineral, ZnMn{sub 3}O{sub 7} {center_dot} H{sub 2}O, which contains only tetrahedral Zn, showed that the hydration state of Zn significantly affects birnessite structural stability. Finally, our study also revealed that, relative to their positions in an ideal vacancy-free MnO{sub 2}, Mn nearest to Zn in a TCS surface complex move toward the vacancy by 0.08-0.11 {angstrom}, while surface O bordering the vacancy move away from it by 0.16-0.21 {angstrom}, in agreement with recent X-ray absorption spectroscopic analyses.

  6. Multiple Redox Modes in the Reversible Lithiation of High-Capacity, Peierls-Distorted Vanadium Sulfide

    SciTech Connect (OSTI)

    Britto, Sylvia; Leskes, Michal; Hua, Xiao; Hébert, Claire-Alice; Shin, Hyeon Suk; Clarke, Simon; Borkiewicz, Olaf; Chapman, Karena W.; Seshadri, Ram; Cho, Jaephil; Grey, Clare P.

    2015-06-08

    Vanadium sulfide VS4 in the patronite mineral structure, is a linear chain compound comprising vanadium atoms coordinated by disulfide anions [S2]2–. 51V NMR shows that the material, despite having V formally in the d1 configuration, is diamagnetic, suggesting potential dimerization through metal-metal bonding associated with a Peierls distortion of the linear chains. This is supported by density functional calculations, and is also consistent with the observed alternation in V-V distances of 2.8 Å and 3.2 Å along the chains. Partial lithiation results in reduction of the disulfide ions to sulfide S2–, including via an internal redox process whereby an electron from V4+ is transferred to [S2]2– resulting in oxidation of V4+ to V5+ and reduction of the [S2]2– to S2- to form Li3VS4 containing tetrahedral [VS4]3– anions. On further lithiation this is followed by reduction of the V5+ in Li3VS4 to form Li3+xVS4 (x=0.5-1), a mixed valent V4+/V5+ compound. Eventually reduction to Li2S plus elemental V occurs. Despite the complex redox processes involving both the cation and the anion occurring in this material, the system is found to be partially reversible between 0 and 3 V. In conclusion, the unusual redox processes in this system are elucidated using a suite of short range characterization tools including 51V Nuclear Magnetic Resonance spectroscopy (NMR), S Kedge X-ray Absorption Near Edge Spectroscopy (XANES) and Pair Distribution Function (PDF) Analysis of X-ray data.

  7. Zinc oxide thin film acoustic sensor

    SciTech Connect (OSTI)

    Mohammed, Ali Jasim; Salih, Wafaa Mahdi; Hassan, Marwa Abdul Muhsien; Nusseif, Asmaa Deiaa; Kadhum, Haider Abdullah; Mansour, Hazim Louis

    2013-12-16

    This paper reports the implementation of (750 nm) thickness of Zinc Oxide (ZnO) thin film for the piezoelectric pressure sensors. The film was prepared and deposited employing the spray pyrolysis technique. XRD results show that the growth preferred orientation is the (002) plane. A polycrystalline thin film (close to mono crystallite like) was obtained. Depending on the Scanning Electron Microscopy photogram, the film homogeneity and thickness were shown. The resonance frequency measured (about 19 kHz) and the damping coefficient was calculated and its value was found to be about (2.5538), the thin film be haves as homogeneous for under and over damped. The thin film pressure sensing was approximately exponentially related with frequency, the thin film was observed to has a good response for mechanical stresses also it is a good material for the piezoelectric properties.

  8. Cadmium zinc sulfide by solution growth

    DOE Patents [OSTI]

    Chen, Wen S.

    1992-05-12

    A process for depositing thin layers of a II-VI compound cadmium zinc sulfide (CdZnS) by an aqueous solution growth technique with quality suitable for high efficiency photovoltaic or other devices which can benefit from the band edge shift resulting from the inclusion of Zn in the sulfide. A first solution comprising CdCl.sub.2 2.5H.sub.2 O, NH.sub.4 Cl, NH.sub.4 OH and ZnCl.sub.2, and a second solution comprising thiourea ((NH.sub.2).sub.2 CS) are combined and placed in a deposition cell, along with a substrate to form a thin i.e. 10 nm film of CdZnS on the substrate. This process can be sequentially repeated with to achieve deposition of independent multiple layers having different Zn concentrations.

  9. Carbon-carbon bond cleavage of 1,2-hydroxy ethers b7 vanadium(V) dipicolinate complexes

    SciTech Connect (OSTI)

    Hanson, Susan K; Gordon, John C; Thorn, David L; Scott, Brian L; Baker, R Tom

    2009-01-01

    The development of alternatives to current petroleum-based fuels and chemicals is becoming increasingly important due to concerns over climate change, growing world energy demand, and energy security issues. Using non-food derived biomass to produce renewable feedstocks for chemicals and fuels is a particularly attractive possibility. However, the majority of biomass is in the form of lignocellulose, which is often not fully utilized due to difficulties associated with breaking down both lignin and cellulose. Recently, a number of methods have been reported to transform cellulose directly into more valuable materials such as glucose, sorbitol, 5-(chloromethyl)furfural, and ethylene glycol. Less progress has been made with selective transformations of lignin, which is typically treated in paper and forest industries by kraft pulping (sodium hydroxide/sodium sulfide) or incineration. Our group has begun investigating aerobic oxidative C-C bond cleavage catalyzed by dipicolinate vanadium complexes, with the idea that a selective C-C cleavage reaction of this type could be used to produce valuable chemicals or intermediates from cellulose or lignin. Lignin is a randomized polymer containing methoxylated phenoxy propanol units. A number of different linkages occur naturally; one of the most prevalent is the {beta}-O-4 linkage shown in Figure 1, containing a C-C bond with 1,2-hydroxy ether substituents. While the oxidative C-C bond cleavage of 1,2-diols has been reported for a number of metals, including vanadium, iron, manganese, ruthenium, and polyoxometalate complexes, C-C bond cleavage of 1,2-hydroxy ethers is much less common. We report herein vanadium-mediated cleavage of C-C bonds between alcohol and ether functionalities in several lignin model complexes. In order to explore the scope and potential of vanadium complexes to effect oxidative C-C bond cleavage in 1,2-hydroxy ethers, we examined the reactivity of the lignin model complexes pinacol monomethyl ether (A

  10. Regeneration of zinc halide catalyst used in the hydrocracking of polynuclear hydrocarbons

    DOE Patents [OSTI]

    Gorin, Everett

    1978-01-01

    Improved recovery of spent molten zinc halide hydro-cracking catalyst is achieved in the oxidative vapor phase regeneration thereof by selective treatment of the zinc oxide carried over by the effluent vapors from the regeneration zone with hydrogen halide gas under conditions favoring the reaction of the zinc oxide with the hydrogen halide, whereby regenerated zinc halide is recovered in a solids-free state with little loss of zinc values.

  11. Thin-film encapsulation of the air-sensitive organic-based ferrimagnet vanadium tetracyanoethylene

    SciTech Connect (OSTI)

    Froning, I. H.; Harberts, M.; Yu, H.; Johnston-Halperin, E.; Lu, Y.; Epstein, A. J.

    2015-03-23

    The organic-based ferrimagnet vanadium tetracyanoethylene (V[TCNE]{sub x∼2}) has demonstrated potential for use in both microwave electronics and spintronics due to the combination of high temperature magnetic ordering (T{sub C} > 600 K), extremely sharp ferromagnetic resonance (peak to peak linewidth of 1 G), and low-temperature conformal deposition via chemical vapor deposition (deposition temperature of 50 °C). However, air-sensitivity leads to the complete degradation of the films within 2 h under ambient conditions, with noticeable degradation occurring within 30 min. Here, we demonstrate encapsulation of V[TCNE]{sub x∼2} thin films using a UV-cured epoxy that increases film lifetime to over 710 h (30 days) as measured by the remanent magnetization. The saturation magnetization and Curie temperature decay more slowly than the remanence, and the coercivity is unchanged after 340 h (14 days) of air exposure. Fourier transform infrared spectroscopy indicates that the epoxy does not react with the film, and magnetometry measurements show that the presence of the epoxy does not degrade the magnetic properties. This encapsulation strategy directly enables a host of experimental protocols and investigations not previously feasible for air-sensitive samples and lays the foundation for the development of practical applications for this promising organic-based magnetic material.

  12. Selective oxidation of n-butane and butenes over vanadium-containing catalysts

    SciTech Connect (OSTI)

    Nieto, J.M.L.; Concepcion, P.; Dejoz, A.; Knoezinger, H.; Melo, F.; Vazquez, M.I.

    2000-01-01

    The oxidative dehydrogenation (OXDH) of n-butane, 1-butene, and trans-2-butene on different vanadia catalysts has been compared. MgO, alumina, and Mg-Al mixed oxides with Mg/(Al + Mg) ratios of 0.25 and 0.75 were used as supports. The catalytic data indicate that the higher the acid character of catalysts the lower is both the selectivity to C{sub 4}-olefins from n-butane and the selectivity to butadiene from both 1-butene or trans-2-butene. Thus, OXDH reactions are mainly observed from n-butane and butenes on basic catalysts. The different catalytic performance of both types of catalysts is a consequence of the isomerization of olefins on acid sites, which appears to be a competitive reaction with the selective way, i.e., the oxydehydrogenation process by a redox mechanism. Infrared spectroscopy data of 1-butene adsorbed on supported vanadium oxide catalysts suggest the presence of different adsorbed species. O-containing species (carbonyl and alkoxide species) are observed on catalysts with acid sites while adsorbed butadiene species are observed on catalysts with basic sites. According to these results a reaction network for the oxydehydrogenation of n-butane is proposed with parallel and consecutive reactions.

  13. Growth of oriented vanadium pentaoxide nanostructures on transparent conducting substrates and their applications in photocatalysis

    SciTech Connect (OSTI)

    Liu, Hongjiang; Gao, Yanfeng; Zhou, Jiadong; Liu, Xinling; Chen, Zhang; Cao, Chuanxiang; Luo, Hongjie; Kanehira, Minoru

    2014-06-01

    A novel, hydrothermal and hard-template-free method was developed for the first time to grow oriented, single-crystalline monoclinic VO{sub 2} (B) flower-like nanorod films on transparent conductive fluorine-doped tin oxide (FTO) substrates. The length and morphology of the nanorods can be tuned by changing the growth parameters, such as growth time and initial precursor concentration. The flower-like V{sub 2}O{sub 5} films were obtained after post-calcination treatment of VO{sub 2} (B) films. The photocatalytic activity of V{sub 2}O{sub 5} films was investigated by the degradation of methylene blue (MB) under UV and visible light. The prepared V{sub 2}O{sub 5} film exhibited good photocatalytic performance (74.6% and 63% under UV and visible light for 210 min, respectively) and more practical application in industry. - Graphical abstract: Flower nanostructured vanadium oxide film was prepared by hydrothermal reaction for photocatalysis application. - Highlights: Monoclinic VO{sub 2} nanorod array and flower-like nanostructure were directly grown on FTO substrate by hydrothermal reaction. The growth mechanism was analyzed by FESEM at different time. V{sub 2}O{sub 5} flower-like nanostructure film was obtained after calcining VO{sub 2} film. V{sub 2}O{sub 5} film exhibited good light activity and potential application in photocatalysis.

  14. Additive agent for zinc alloy electrolyte and process

    SciTech Connect (OSTI)

    Bammel, B.D.

    1986-07-01

    An aqueous acidic electrolyte is described suitable for electrodepositing zinc alloys on a substrate comprising zinc ions and at least one additional metal ion selected from the group consisting nickel, cobalt, iron and mixtures thereof present in an amount sufficient to electrodeposit a zinc alloy, and, for providing improved grain-refinement and enhancing the codeposition of the alloying metals in the zinc alloy deposit. An effective amount of an additive agent consists of a bath-soluble anionic carboxylated polyoxyalkylene compound derived from the carboxylation of: (a) the polymerization of alkylene oxides selected from the group consisting of ethylene oxide, propylene oxide, glycidol, butylene oxide and mixtures thereof; and (b) the alkoxylation of mono and polyhydroxy compounds selected from the group consisting of hydroxyl containing alkyl, alkenyl, alkynyl, aryl, as well as mixtures thereof.

  15. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization...

    Office of Scientific and Technical Information (OSTI)

    in a Fixed-Bed Reactor Citation Details In-Document Search Title: Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor You are ...

  16. Aluminum-doped Zinc Oxide Nanoink - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Industrial Technologies Industrial Technologies Building Energy Efficiency Building Energy Efficiency Find More Like This Return to Search Aluminum-doped Zinc Oxide Nanoink Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative

  17. Acetone sensor based on zinc oxide hexagonal tubes

    SciTech Connect (OSTI)

    Hastir, Anita Singh, Onkar Anand, Kanika Singh, Ravi Chand

    2014-04-24

    In this work hexagonal tubes of zinc oxide have been synthesized by co-precipitation method. For structural, morphological, elemental and optical analysis synthesized powders were characterized by using x-ray diffraction, field emission scanning microscope, EDX, UV-visible and FTIR techniques. For acetone sensing thick films of zinc oxide have been deposited on alumina substrate. The fabricated sensors exhibited maximum sensing response towards acetone vapour at an optimum operating temperature of 400°C.

  18. Characteristics RSE Column Factor: Total

    U.S. Energy Information Administration (EIA) Indexed Site

    and 1994 Vehicle Characteristics RSE Column Factor: Total 1993 Family Income Below Poverty Line Eli- gible for Fed- eral Assist- ance 1 RSE Row Factor: Less than 5,000 5,000...

  19. ARM - Measurement - Total cloud water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total cloud water The total concentration (mass/vol) of ice and liquid water particles in a cloud; this includes condensed water content (CWC). Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a

  20. Simultaneous recovery of vanadium and nickel from power plant fly-ash: Optimization of parameters using response surface methodology

    SciTech Connect (OSTI)

    Nazari, E.; Rashchi, F. Saba, M.; Mirazimi, S.M.J.

    2014-12-15

    Highlights: • Leaching of vanadium and nickel from fly ash (14.43% V and 5.19% Ni) in sulfuric acid was performed. • Optimization of leaching parameters was carried out using a response surface methodology. • Using optimum conditions, 94.28% V and 81.01% Ni “actual recovery” was obtained. - Abstract: Simultaneous recovery of vanadium (V) and nickel (Ni), which are classified as two of the most hazardous metal species from power plant heavy fuel fly-ash, was studied using a hydrometallurgical process consisting of acid leaching using sulfuric acid. Leaching parameters were investigated and optimized in order to maximize the recovery of both vanadium and nickel. The independent leaching parameters investigated were liquid to solid ratio (S/L) (5–12.5 wt.%), temperature (45–80 °C), sulfuric acid concentration (5–25 v/v%) and leaching time (1–5 h). Response surface methodology (RSM) was used to optimize the process parameters. The most effective parameter on the recovery of both elements was found to be temperature and the least effective was time for V and acid concentration for Ni. Based on the results, optimum condition for metals recovery (actual recovery of ca.94% for V and 81% for Ni) was determined to be solid to liquid ratio of 9.15 wt.%, temperature of 80 °C, sulfuric acid concentration of 19.47 v/v% and leaching time of 2 h. The maximum V and Ni predicted recovery of 91.34% and 80.26% was achieved.

  1. Role of vanadium(V) in the aging of the organic phase in the extraction of uranium(VI) by Alamine 336 from acidic sulfate leach liquors

    SciTech Connect (OSTI)

    Chagnes, A.; Cote, G.; Courtaud, B.; Thiry, J.

    2008-07-01

    The present work is focussed on the chemical degradation of Alamine 336-tridecanol-n-dodecane solvent which used in the recovery of uranium by solvent extraction. Degradation occurs due to the presence of vanadium(V), an oxidant, in the feed solution. After a brief overview of the chemistry of vanadium, the kinetics of degradation of the solvent when contacted with acidic sulfate leach liquor was investigated and interpreted by the Michelis-Menten mechanism. GCMS analyses evidenced the presence of tridecanoic acid and dioctylamine as degradation products. A mechanism of degradation is discussed. (authors)

  2. A statistical study of the macroepidemiology of air pollution and total mortality

    SciTech Connect (OSTI)

    Lipfert, F.W.; Malone, R.G.; Daum, M.L.; Mendell, N.R.; Yang, Chin-Chun

    1988-04-01

    A statistical analysis of spatial patterns of 1980 US urban total mortality (all causes) was performed, evaluating demographic, socioeconomic and air pollution factors as predictors. Specific mortality predictors included cigarette smoking, drinking water hardness, heating fuel use, and 1978-1982 annual concentrations of the following air pollutants: ozone, carbon monoxide, sulfate aerosol, particulate concentrations of lead, iron, cadmium, manganese, vanadium, as well as total and fine particle mass concentrations from the inhalable particulate network (dichotomous samplers). In addition, estimates of sulfur dioxide, oxides of nitrogen, and sulfate aerosol were made for each city using the ASTRAP long-range transport diffusion model, and entered into the analysis as independent variables. Because the number of cities with valid air quality and water hardness data varied considerably by pollutant, it was necessary to consider several different data sets, ranging from 48 to 952 cities. The relatively strong associations (ca. 5--10%) shown for 1980 pollution with 1980 total mortality are generally not confirmed by independent studies, for example, in Europe. In addition, the US studies did not find those pollutants with known adverse health effects at the concentrations in question (such as ozone or CO) to be associated with mortality. The question of causality vs. circumstantial association must therefore be regarded as still unresolved. 59 refs., 20 figs., 40 tabs.

  3. Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery

    SciTech Connect (OSTI)

    Li, Bin; Gu, Meng; Nie, Zimin; Wei, Xiaoliang; Wang, Chong M.; Sprenkle, Vincent L.; Wang, Wei

    2014-01-01

    Graphite felts (GFs), as typical electrode materials for all vanadium redox flow batteries (VRBs), limit the cell operation to low current density because of their poor kinetic reversibility and electrochemical activity. Here, in order to address this issue we report an electrocatalyst, Nb2O5, decorating the surface of GFs to reduce the activation barrier for redox conversion. Nb2O5 nanofibers with monoclinic phases are synthesized by hydrothermal method and deposited on GFs, which is confirmed to have catalytic effects towards redox couples of V(II)/V(III) at the negative side and V(IV)/V(V) at the positive side, and thus applied in both electrodes of VRB cells. Due to the low conductivity of Nb2O5, the performance of electrodes heavily depends on the nano size and uniform distribution of catalysts on GFs surfaces. The addition of the water-soluble compounds containing W element into the precursor solutions facilitates the precipitation of nanofibers on the GFs. Accordingly, an optimal amount of W-doped Nb2O5 nanofibers with weaker agglomeration and better distribution on GFs surfaces are obtained, leading to significant improvement of the electrochemical performances of VRB cells particularly under the high power operation. The corresponding energy efficiency is enhanced by 10.7 % under the operation of high charge/discharge current density (150 mA•cm-2) owing to faster charge transfer as compared with that without catalysts. These results suggest that Nb2O5 based nanofibers-decorating GFs hold great promise as high-performance electrodes for VRB applications.

  4. Zinc Bromide Combustion: Implications for the Consolidated Incinerator Facility

    SciTech Connect (OSTI)

    Oji, L.N.

    1998-12-16

    In the nuclear industry, zinc bromide (ZnBr2) is used for radiation shielding. At Savannah River Site (SRS) zinc bromide solution, in appropriate configurations and housings, was used mainly for shielding in viewing windows in nuclear reactor and separation areas. Waste stream feeds that will be incinerated at the CIF will occasionally include zinc bromide solution/gel matrices.The CIF air pollution systems control uses a water-quench and steam atomizer scrubber that collects salts, ash and trace metals in the liquid phase. Water is re-circulated in the quench unit until a predetermined amount of suspended solids or dissolved salts are present. After reaching the threshold limit, "dirty liquid", also called "blowdown", is pumped to a storage tank in preparation for treatment and disposal. The air pollution control system is coupled to a HEPA pre-filter/filter unit, which removes particulate matter from the flue gas stream (1).The objective of this report is to review existing literature data on the stability of zinc bromide (ZnBr2) at CIF operating temperatures (>870 degrees C (1600 degrees F) and determine what the combustion products are in the presence of excess air. The partitioning of the combustion products among the quencher/scrubber solution, bottom ash and stack will also be evaluated. In this report, side reactions between zinc bromide and its combustion products with fuel oil were not taken into consideration.

  5. Thin film cadmium telluride and zinc phosphide solar cells

    SciTech Connect (OSTI)

    Chu, T.

    1984-10-01

    This report describes research performed from June 1982 to October 1983 on the deposition of cadmium telluride films by direct combination of the cadmium and tellurium vapor on foreign substrates. Nearly stoichiometric p-type cadmium telluride films and arsenic-doped p-type films have been prepared reproducibly. Major efforts were directed to the deposition and characterization of heterojunction window materials, indium tin oxide, fluorine-doped tin oxide, cadmium oxide, and zinc oxide. A number of heterojunction solar cells were prepared, and the best thin-film ITO/CdTe solar cells had an AMl efficiency of about 7.2%. Zinc phosphide films were deposited on W/steel substrates by the reaction of zinc and phosphine in a hydrogen flow. Films without intentional doping had an electrical resistivity on the order of 10/sup 6/ ohm-cm, and this resistivity may be reduced to about 5 x 10/sup 4/ ohm-cm by adding hydrogen chloride or hydrogen bromide to the reaction mixture. Lower resistivity films were deposited by adding a controlled amount of silver nitrate solution on to the substrate surface. Major efforts were directed to the deposition of low-resistivity zinc selenide in order to prepare ZnSe/An/sub 3/P/sub 2/ heterojunction thin-film solar cells. However, zinc selenide films deposited by vacuum evaporation and chemical vapor deposition techniques were all of high resistivity.

  6. CATEGORY Total Procurement Total Small Business Small Disadvantaged

    National Nuclear Security Administration (NNSA)

    CATEGORY Total Procurement Total Small Business Small Disadvantaged Business Woman Owned Small Business HubZone Small Business Veteran-Owned Small Business Service Disabled Veteran Owned Small Business FY 2013 Dollars Accomplished $1,049,087,940 $562,676,028 $136,485,766 $106,515,229 $12,080,258 $63,473,852 $28,080,960 FY 2013 % Accomplishment 54.40% 13.00% 10.20% 1.20% 6.60% 2.70% FY 2014 Dollars Accomplished $868,961,755 $443,711,175 $92,478,522 $88,633,031 $29,867,820 $43,719,452 $26,826,374

  7. Kinetic study of the oxidation of n-butane on vanadium oxide supported on Al/Mg mixed oxide

    SciTech Connect (OSTI)

    Dejoz, A.; Vazquez, I.; Nieto, J.M.L.; Melo, F.

    1997-07-01

    The reaction kinetics of the oxidative dehydrogenation (ODH) of n-butane over vanadia supported on a heat-treated Mg/Al hydrotalcite (37.3 wt % of V{sub 2}O{sub 5}) was investigated by both linear and nonlinear regression techniques. A reaction network including the formation of butenes (1-, 2-cis-, and 2-trans-butene), butadiene, and carbon oxides by parallel and consecutive reactions, at low and high n-butane conversions, has been proposed. Langmuir-Hinshelwood (LH) models can be used as suitable models which allows reproduction of the global kinetic behavior, although differences between oxydehydrogenation and deep oxidation reactions have been observed. Thus, the formation of oxydehydrogenation products can be described by a LH equation considering a dissociative adsorption of oxygen while the formation of carbon oxides is described by a LH equation with a nondissociative adsorption of oxygen. Two different mechanisms operate on the catalyst: (i) a redox mechanism responsible of the formation of olefins and diolefins and associated to vanadium species, which is initiated by a hydrogen abstraction; (ii) a radical mechanism responsible of the formation of carbon oxides from n-butane and butenes and associated to vanadium-free sites of the support. On the other hand, the selectivity to oxydehydrogenation products increases with the reaction temperature. This catalytic performance can be explained taking into account the low reducibility of V{sup 5+}-sites and the higher apparent activation energies of the oxydehydrogenation reactions with respect to deep oxidation reactions.

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 New Hampshire - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle ...

  9. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  10. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  11. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, D.S.

    1984-02-16

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  16. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, David S.; Yao, Neng-Ping

    1985-01-01

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  17. Embrittlement of stainless steel welds by contamination with zinc-rich paint

    SciTech Connect (OSTI)

    Johnson, J.M.; Gutzeit, J.

    1985-01-01

    Contamination of Type 321 stainless steel heater tubes with zinc-rich paint can lead to failures by zinc embrittlement. Following a review of the mechanism of zinc embrittlement, the failure mode is discussed in some detail. Results of laboratory tests are presented, which confirm field observations. Finally a proper cleaning procedure is recommended to alleviate the problem.

  18. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  19. Thin film cadmium telluride, zinc telluride, and mercury zinc telluride solar cells

    SciTech Connect (OSTI)

    Chu, T.L. )

    1992-04-01

    This report describes research to demonstrate (1) thin film cadmium telluride solar cells with a quantum efficiency of 75% or higher at 0. 44 {mu}m and a photovoltaic efficiency of 11.5% or greater, and (2) thin film zinc telluride and mercury zinc telluride solar cells with a transparency to sub-band-gap radiation of 65% and a photovoltaic conversion efficiency of 5% and 8%, respectively. Work was directed at (1) depositing transparent conducting semiconductor films by solution growth and metal-organic chemical vapor deposition (MOCVD) technique, (2) depositing CdTe films by close-spaced sublimation (CSS) and MOCVD techniques, (3) preparing and evaluating thin film CdTe solar cells, and (4) preparing and characterizing thin film ZnTe, CD{sub 1-x}Zn{sub 1-x}Te, and Hg{sub 1-x}Zn{sub x}Te solar cells. The deposition of CdS films from aqueous solutions was investigated in detail, and their crystallographic, optical, and electrical properties were characterized. CdTe films were deposited from DMCd and DIPTe at 400{degrees}C using TEGa and AsH{sub 3} as dopants. CdTe films deposited by CSS had significantly better microstructures than those deposited by MOCVD. Deep energy states in CdTe films deposited by CSS and MOCVD were investigated. Thin films of ZnTe, Cd{sub 1- x}Zn{sub x}Te, and Hg{sub 1-x}Zn{sub x}Te were deposited by MOCVD, and their crystallographic, optical, and electrical properties were characterized. 67 refs.

  20. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    Performance Period Total Fee Paid FY2008 $134,832 FY2009 $142,578 FY2010 $299,878 FY2011 $169,878 Cumulative Fee Paid $747,166 Contract Period: September 2007 - October 2012 $31,885,815 C/P/E Environmental Services, LLC DE-AM09-05SR22405/DE-AT30-07CC60011/SL14 Contractor: Contract Number: Contract Type: Cost Plus Award Fee $357,223 $597,797 $894,699 EM Contractor Fee Site: Stanford Linear Accelerator Center (SLAC) Contract Name: SLAC Environmental Remediation December 2012 $1,516,646 Fee

  1. Design Storm for Total Retention.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Title: Design Storm for "Total Retention" under Individual Permit, Poster, Individual ... International. Environmental Programs Design Storm for "Total Retention" under ...

  2. U.S. Total Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    St. Clair, MI International Falls, MN Noyes, MN Warroad, MN Babb, MT Havre, MT Port of Del Bonita, MT Port of Morgan, MT Sweetgrass, MT Whitlash, MT Portal, ND Sherwood, ND Pittsburg, NH Champlain, NY Grand Island, NY Massena, NY Niagara Falls, NY Waddington, NY Sumas, WA Highgate Springs, VT North Troy, VT U.S. Pipeline Total from Mexico Ogilby, CA Otay Mesa, CA Alamo, TX El Paso, TX Galvan Ranch, TX Hidalgo, TX McAllen, TX Penitas, TX LNG Imports from Algeria Cove Point, MD Everett, MA Lake

  3. Internal Electric Field Behavior of Cadmium Zinc Telluride Radiation Detectors Under High Carrier Injection

    SciTech Connect (OSTI)

    Yang, G.; Bolotnikov, A.E.; Camarda, G.S.; Cui, Y.; Hossain, A.; Kim, K.H.; Gul, R.; and James, R.B.

    2010-10-26

    The behavior of the internal electric-field of nuclear-radiation detectors substantially affects the detector's performance. We investigated the distribution of the internal field in cadmium zinc telluride (CZT) detectors under high carrier injection. We noted the build-up of a space charge region near the cathode that produces a built-in field opposing the applied field. Its presence entails the collapse of the electric field in the rest of detector, other than the portion near the cathode. Such a space-charge region originates from serious hole-trapping in CZT. The device's operating temperature greatly affects the width of the space-charge region. With increasing temperature from 5 C to 35 C, its width expanded from about 1/6 to 1/2 of the total depth of the detector.

  4. Process for fabricating doped zinc oxide microsphere gel

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D.; Bond, Walter D.; Lauf, Robert J.

    1991-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  5. Process for fabricating doped zinc oxide microsphere gel

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1991-11-05

    Disclosed are a new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  6. Interfacial electron transfer dynamics of photosensitized zinc oxide nanoclusters

    SciTech Connect (OSTI)

    Murakoshi, Kei; Yanagida, Shozo; Capel, M.

    1997-06-01

    The authors have prepared and characterized photosensitized zinc oxide (ZnO) nanoclusters, dispersed in methanol, using carboxylated coumarin dyes for surface adsorption. Femtosecond time-resolved emission spectroscopy allows the authors to measure the photo-induced charge carrier injection rate constant from the adsorbed photosensitizer to the n-type semiconductor nanocluster. These results are compared with other photosensitized semiconductors.

  7. Chemical vapor deposition of fluorine-doped zinc oxide

    DOE Patents [OSTI]

    Gordon, Roy G.; Kramer, Keith; Liang, Haifan

    2000-06-06

    Fims of fluorine-doped zinc oxide are deposited from vaporized precursor compounds comprising a chelate of a dialkylzinc, such as an amine chelate, an oxygen source, and a fluorine source. The coatings are highly electrically conductive, transparent to visible light, reflective to infrared radiation, absorbing to ultraviolet light, and free of carbon impurity.

  8. Zinc oxide-based sorbents and processes for preparing and using same

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar; Turk, Brian Scott; Gupta, Raghubir Prasad

    2005-10-04

    Zinc oxide-based sorbents, and processes for preparing and using them are provided, wherein the sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents contain an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2 O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, containing a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  9. Zinc-oxide-based sorbents and processes for preparing and using same

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar; Turk, Brian Scott; Gupta, Raghubir Prasael

    2010-03-23

    Zinc oxide-based sorbents, and processes for preparing and using them are provided. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  10. Transient fluctuations of intracellular zinc ions in cell proliferation

    SciTech Connect (OSTI)

    Li, Yuan; Maret, Wolfgang; Department of Anesthesiology, The University of Texas Medical Branch, Galveston, TX 77555

    2009-08-15

    Zinc is essential for cell proliferation, differentiation, and viability. When zinc becomes limited for cultured cells, DNA synthesis ceases and the cell cycle is arrested. The molecular mechanisms of actions of zinc are believed to involve changes in the availability of zinc(II) ions (Zn{sup 2+}). By employing a fluorescent Zn{sup 2+} probe, FluoZin-3 acetoxymethyl ester, intracellular Zn{sup 2+} concentrations were measured in undifferentiated and in nerve growth factor (NGF)-differentiated rat pheochromocytoma (PC12) cells. Intracellular Zn{sup 2+} concentrations are pico- to nanomolar in PC12 cells and are higher in the differentiated than in the undifferentiated cells. When following cellular Zn{sup 2+} concentrations for 48 h after the removal of serum, a condition that is known to cause cell cycle arrest, Zn{sup 2+} concentrations decrease after 30 min but, remarkably, increase after 1 h, and then decrease again to about one half of the initial concentration. Cell proliferation, measured by an MTT [3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide] assay, decreases after both serum starvation and zinc chelation. Two peaks of Zn{sup 2+} concentrations occur within one cell cycle: one early in the G1 phase and the other in the late G1/S phase. Thus, fluctuations of intracellular Zn{sup 2+} concentrations and established modulation of phosphorylation signaling, via an inhibition of protein tyrosine phosphatases at commensurately low Zn{sup 2+} concentrations, suggest a role for Zn{sup 2+} in the control of the cell cycle. Interventions targeted at these picomolar Zn{sup 2+} fluctuations may be a way of controlling cell growth in hyperplasia, neoplasia, and diseases associated with aberrant differentiation.

  11. Total Imports of Residual Fuel

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S. Total 9,010 5,030 8,596 6,340 4,707 8,092 1936-2016 PAD District 1 3,127 2,664 2,694 1,250 1,327 2,980 1981-2016 Connecticut 1995-2015 Delaware 280 1995-2016 Florida 858 649 800 200 531 499 1995-2016 Georgia 210 262 149 106 1995-2016 Maine 1995-2015 Maryland 84 1995-2016 Massachusetts 1995-2015 New Hampshire 1995-2015 New Jersey 1,283 843 1,073 734 355 1,984 1995-2016 New York 234 824 210 196 175 1995-2016 North Carolina 1995-2011

  12. Total quality management implementation guidelines

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    These Guidelines were designed by the Energy Quality Council to help managers and supervisors in the Department of Energy Complex bring Total Quality Management to their organizations. Because the Department is composed of a rich mixture of diverse organizations, each with its own distinctive culture and quality history, these Guidelines are intended to be adapted by users to meet the particular needs of their organizations. For example, for organizations that are well along on their quality journeys and may already have achieved quality results, these Guidelines will provide a consistent methodology and terminology reference to foster their alignment with the overall Energy quality initiative. For organizations that are just beginning their quality journeys, these Guidelines will serve as a startup manual on quality principles applied in the Energy context.

  13. Total Imports of Residual Fuel

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History U.S. Total 133,646 119,888 93,672 82,173 63,294 68,265 1936-2015 PAD District 1 88,999 79,188 59,594 33,566 30,944 33,789 1981-2015 Connecticut 220 129 1995-2015 Delaware 748 1,704 510 1,604 2,479 1995-2015 Florida 15,713 11,654 10,589 8,331 5,055 7,013 1995-2015 Georgia 5,648 7,668 6,370 4,038 2,037 1,629 1995-2015 Maine 1,304 651 419 75 317 135 1995-2015 Maryland 3,638 1,779 1,238 433 938 539 1995-2015 Massachusetts 123 50 78 542 88 1995-2015 New

  14. Total Adjusted Sales of Kerosene

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Residential Commercial Industrial Farm All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 269,010 305,508 187,656 81,102 79,674 137,928 1984-2014 East Coast (PADD 1) 198,762 237,397 142,189 63,075 61,327 106,995 1984-2014 New England (PADD 1A) 56,661 53,363 38,448 15,983 15,991 27,500 1984-2014 Connecticut 8,800 7,437

  15. Visible light photocatalytic degradation of 4-chlorophenol using vanadium and nitrogen co-doped TiO{sub 2}

    SciTech Connect (OSTI)

    Jaiswal, R.; Kothari, D. C.; Patel, N.; Miotello, A.

    2013-02-05

    Vanadium and Nitrogen were codoped in TiO{sub 2} photocatalyst by Sol-gel method to utilize visible light more efficiently for photocatalytic reactions. A noticeable shift of absorption edge to visible light region was obtained for the singly-doped namely V-TiO{sub 2}, N-TiO{sub 2} and codoped V-N-TiO{sub 2} samples in comparison with undoped TiO{sub 2}, with smallest band gap obtained with codoped-TiO{sub 2}. The photocatalytic activities for all TiO{sub 2} photocatalysts were tested by 4-chlorophenol (organic pollutant) degradation under visible light irradiation. It was found that codoped TiO{sub 2} exhibits the best photocatalytic activity, which could be attributed to the synergistic effect produced by V and N dopants.

  16. Synthesis and characterization of vanadium oxide aerogels. Technical report No. 2, 1 June 1994-31 May 1995

    SciTech Connect (OSTI)

    Chaput, F.; Dunn, B.; Fuqua, P.; Salloux, K.

    1995-07-14

    Vanadium pentoxide aerogels were synthesized by supercritical drying with CO2. The aerogels were prepared using a variety of sol compositions from the system VO(OC3H7)3/H2O/acetone. The materials were found to be of fairly low density (0.04g/cu cm to 0.lg/cu cm) with surface areas in the range of 300 to 400 meters squared/g. Chemical and structural studies indicate that the aerogels are hydrated oxides of composition V2O5 nH2O with n = 2.0 to 2.2 and possess a fibrous morphology. When partially dehydrated, the vanadate aerogels exhibit electron transport with conductivity and activation energy values comparable to those of aerogels. Electrochemical measurements demonstrate that lithium can be intercalated reversibly into the structure.

  17. Total quality management program planning

    SciTech Connect (OSTI)

    Thornton, P.T.; Spence, K.

    1994-05-01

    As government funding grows scarce, competition between the national laboratories is increasing dramatically. In this era of tougher competition, there is no for resistance to change. There must instead be a uniform commitment to improving the overall quality of our products (research and technology) and an increased focus on our customers` needs. There has been an ongoing effort to bring the principles of total quality management (TQM) to all Energy Systems employees to help them better prepare for future changes while responding to the pressures on federal budgets. The need exists for instituting a vigorous program of education and training to an understanding of the techniques needed to improve and initiate a change in organizational culture. The TQM facilitator is responsible for educating the work force on the benefits of self-managed work teams, designing a program of instruction for implementation, and thus getting TQM off the ground at the worker and first-line supervisory levels so that the benefits can flow back up. This program plan presents a conceptual model for TQM in the form of a hot air balloon. In this model, there are numerous factors which can individually and collectively impede the progress of TQM within the division and the Laboratory. When these factors are addressed and corrected, the benefits of TQM become more visible. As this occurs, it is hoped that workers and management alike will grasp the ``total quality`` concept as an acceptable agent for change and continual improvement. TQM can then rise to the occasion and take its rightful place as an integral and valid step in the Laboratory`s formula for survival.

  18. Total-derivative supersymmetry breaking

    SciTech Connect (OSTI)

    Haba, Naoyuki; Uekusa, Nobuhiro

    2010-05-15

    On an interval compactification in supersymmetric theory, boundary conditions for bulk fields must be treated carefully. If they are taken arbitrarily following the requirement that a theory is supersymmetric, the conditions could give redundant constraints on the theory. We construct a supersymmetric action integral on an interval by introducing brane interactions with which total-derivative terms under the supersymmetry transformation become zero due to a cancellation. The variational principle leads equations of motion and also boundary conditions for bulk fields, which determine boundary values of bulk fields. By estimating mass spectrum, spontaneous supersymmetry breaking in this simple setup can be realized in a new framework. This supersymmetry breaking does not induce a massless R axion, which is favorable for phenomenology. It is worth noting that fermions in hyper-multiplet, gauge bosons, and the fifth-dimensional component of gauge bosons can have zero-modes (while the other components are all massive as Kaluza-Klein modes), which fits the gauge-Higgs unification scenarios.

  19. Total Space Heating Water Heating Cook-

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Commercial Buildings Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing...

  20. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 1,870 1,276...

  1. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All...

  2. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 1,602 1,397...

  3. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings ... 2,037...

  4. ,"West Virginia Natural Gas Total Consumption (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","West Virginia Natural Gas Total Consumption ... AM" "Back to Contents","Data 1: West Virginia Natural Gas Total Consumption (MMcf)" ...

  5. ,"Total Crude Oil and Petroleum Products Exports"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Total Crude Oil and Petroleum Products ... "Back to Contents","Data 1: Total Crude Oil and Petroleum Products Exports" ...

  6. ,"New Mexico Natural Gas Total Consumption (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","New Mexico Natural Gas Total Consumption ... AM" "Back to Contents","Data 1: New Mexico Natural Gas Total Consumption (MMcf)" ...

  7. ,"North Dakota Natural Gas Total Consumption (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Dakota Natural Gas Total Consumption ... 9:10:34 AM" "Back to Contents","Data 1: North Dakota Natural Gas Total Consumption ...

  8. ,"North Carolina Natural Gas Total Consumption (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","North Carolina Natural Gas Total Consumption ... 9:10:33 AM" "Back to Contents","Data 1: North Carolina Natural Gas Total Consumption ...

  9. Solvothermal routes for synthesis of zinc oxide nanorods.

    SciTech Connect (OSTI)

    Bell, Nelson Simmons

    2005-03-01

    Control of the synthesis of nanomaterials to produce morphologies exhibiting quantized properties will enable device integration of several novel applications including biosensors, catalysis, and optical devices. In this work, solvothermal routes to produce zinc oxide nanorods are explored. Much previous work has relied on the addition of growth directing/inhibiting agents to control morphology. It was found in coarsening studies that zinc oxide nanodots will ripen to nanorod morphologies at temperatures of 90 to 120 C. The resulting nanorods have widths of 9-12 nm average dimension, which is smaller than current methods for nanorod synthesis. Use of nanodots as nuclei may be an approach that will allow for controlled growth of higher aspect ratio nanorods.

  10. Electrolyte optimization for cathodic growth of zinc oxide films

    SciTech Connect (OSTI)

    Izaki, Masanobu; Omi, Takashi

    1996-03-01

    Zinc oxide is of considerable interest to the optical and electronic industries, because of its electrical, optical, and acoustic characteristics. ZnO films can be prepared by several techniques, such as radio frequency (RF) magnetron sputtering, chemical vapor deposition, and molecular beam epitaxy. Preparation of oxide films by electrodeposition from aqueous solutions has several potential advantages over the other techniques. However, the formation of oxide films through electrochemical reactions have been demonstrated only on thallic oxide by Switzer and zirconium oxide by Gal-Or. In this work, the authors have prepared transparent ZnO films with optical bandgap energy of 3.3 eV by electrodeposition from an aqueous, 0.1 mol/liter zinc nitrate electrolyte. The deposition technology is still being developed. This paper reports the effects of the electrolyte concentration on the electrodeposition and properties of the ZnO films.

  11. Characterization of transparent zinc oxide films prepared by electrochemical reaction

    SciTech Connect (OSTI)

    Izaki, Masanobu; Omi, Takashi

    1997-06-01

    Transparent zinc oxide (ZnO) films have been grown by galvanostatic cathodic deposition onto conductive glasses from a simple aqueous zinc nitrate electrolyte maintained at 335 K. The as-deposited ZnO films were characterized with Fourier transform infrared absorption spectroscopy, x-ray diffraction, scanning electron microscopy, optical transmission and absorption studies, and measurement of sheet resistivity as a function of cathodic current density. The ZnO films prepared had a wurtzite structure and exhibited an optical bandgap energy of 3.3 eV which is characteristic of ZnO. At a low cathodic current density of 0.05 mA/cm{sup 2}, ZnO films with excellent electrical characteristics have been obtained. A 2 {micro}m thick ZnO film with an optical transmittance of 72% was deposited by electrolysis for approximately 20 min at a cathodic current density of 10 mA/cm{sup 2}.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research Development Center (AMAX R D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  13. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  14. Accumulation of zinc in rainbow trout (Oncorhynchus mykiss) after waterborne and dietary exposure

    SciTech Connect (OSTI)

    Koeck, G.; Bucher, F.

    1997-02-01

    Zinc is a potential toxicant to fish with water hardness and pH constituting the principal modifying factors of Zn toxicity. Major toxic effects of elevated concentrations of waterborne Zn are disturbances of acid-base and ionoregulation (e.g., impairment of the branchial uptake of Ca{sup 2+}), disruption of gill tissue and hypoxia. Even at sublethal concentrations, chronic effects such as decreased reproduction, reduced growth and histopathological alterations in various tissues may occur. Zinc can be accumulated via the gills and/or the digestive tract. However, the relative roles of water and food as sources of Zn uptake are not yet fully elucidated. The aim of the experimental study presented in this paper was to find an explanation for the unexpected results of a field investigation of a Zn-polluted Austrian river, where despite very high total Zn concentrations in the water and in the sediment (water: mean value 1.6 mg{center_dot}L{sup -1}, extreme values up to 4.9 mg{center_dot}L{sup -1}, sediment: 30 g{center_dot}L{sup -1}, dry weight), Zn levels in organs of rainbow trout were within the range of concentrations found in fish from a control site and similar to those reported in the literature for fish from low-contaminated waters. Furthermore, only minor histopathological changes in rainbow trout could be found. In consequence, this study involved a laboratory experiment to study Zn uptake from both Zn-contaminated water and diet at Zn concentrations found in the field study. 22 refs., 1 tab.

  15. Sessile drop studies on polybromide/zinc-bromine battery electrolyte

    SciTech Connect (OSTI)

    Kinoshita, K.; Leach, S.C.

    1982-08-01

    Improvements in the performance of zinc-bromine batteries have been observed with electrolytes containing a quaternary ammonium salt that complexes the bromine to reduce the concentration of free bromine in solution. A variety of quaternary ammonium salts that complex bromine to form a so-called polybromide oil have been considered. Various papers have discussed measurements of the physicochemical properties of the two-component system of bromine-quaternary ammonium bromide in an aqueous medium. The purpose of this paper is to investigate the interfacial tension of polybromide oils on the electrolytes for zinc-bromine batteries by reporting a study of the interfacial tension and contact angle of polybromide oil drops in which the sessile drop method is used. The interfacial tensions for the polybromide phases are found to be considerably lower than the values commonly reported for two-phase systems containing organic and aqueous phases. However, several two-phase systems, such as benzyl alcohol/water, furfural/water, and ethyl acetate/water have low interfacial tension comparable to that of the polybromide/electrolyte system. The low interfacial tension of the polybromide oil phase has important practical implications for the zinc-bromine battery. A stable emulsion can be produced very readily; small drops of the polybromide-oil phase can thus be stabilized with the electrolyte phase and can be expected to enhance the mass transfer of bromine from the polybromide to the electrode.

  16. " Level: National Data and Regional Totals...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... by" "petroleum refineries, rather than purchased ... ,,"Total United States" ,"RSE Column ... 324,"Petroleum and Coal ...

  17. Studies on photocatalytic activity of zinc ferrite catalysts synthesized by shock waves

    SciTech Connect (OSTI)

    Liu, J; Lu, G.; Xu, T.; Xu, K.; He, H.; Tan, H.

    1996-09-01

    The photocatalytic activity in the photodehydrogenation of H{sub 2}S of zinc ferrites synthesized by shock wave loading is investigated and compared with that of zinc ferrites prepared by calcination. It is shown that photocatalytic activity of zinc ferrites prepared by shock wave treatment is much higher and that this activity increases with the increase of shock wave pressure. XRD, TEM, and electron diffraction methods were used to characterize the catalysts. Possible reasons for the enhancement of photocatalytic activity are discussed.

  18. Electronic and structural characteristics of zinc-blende wurtzite biphasic homostructure GaN nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jacobs, Benjamin W.; Ayres, Virginia M.; Petkov, Mihail P.; Halpern, Joshua B.; He, Maoqi; Baczewski, Andrew D.; McElroy, Kaylee; Crimp, Martin A.; Zhang, Jiaming; Shaw, Harry C.

    2016-02-01

    Here, we report a new biphasic crystalline wurtzite/zinc-blende homostructure in gallium nitride nanowires. Cathodoluminescence was used to quantitatively measure the wurtzite and zinc-blende band gaps. High-resolution transmission electron microscopy was used to identify distinct wurtzite and zinc-blende crystalline phases within single nanowires through the use of selected area electron diffraction, electron dispersive spectroscopy, electron energy loss spectroscopy, and fast Fourier transform techniques. A mechanism for growth is identified.

  19. Hydrocracking with molten zinc chloride catalyst containing 2-12% ferrous chloride

    DOE Patents [OSTI]

    Zielke, Clyde W.; Bagshaw, Gary H.

    1981-01-01

    In a process for hydrocracking heavy aromatic polynuclear carbonaceous feedstocks to produce hydrocarbon fuels boiling below about 475.degree. C. by contacting the feedstocks with hydrogen in the presence of a molten zinc chloride catalyst and thereafter separating at least a major portion of the hydrocarbon fuels from the spent molten zinc chloride catalyst, an improvement comprising: adjusting the FeCl.sub.2 content of the molten zinc chloride to from about 2 to about 12 mol percent based on the mixture of ferrous chloride and molten zinc chloride.

  20. Regeneration and Durability of Advanced Zinc Ferrite Sorbent for Hot Coal Gas Desulfurization

    SciTech Connect (OSTI)

    Shirai, H.; Kobayashi, M.; Nunokawa, M.; Noda, N.

    2002-09-19

    In this study, we investigate the regeneration characteristics, desulfurization performance after regeneration and the durability of zinc ferrite sorbent in the desulfurization/regeneration cycles.

  1. Total Space Heating Water Heating Cook-

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 634 578 46 1 Q 116.4 106.3...

  2. Total System Performance Assessment Peer Review Panel

    Broader source: Energy.gov [DOE]

    Total System Performance Assessment (TSPA) Peer Review Panel for predicting the performance of a repository at Yucca Mountain.

  3. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Alaska - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S2. Summary statistics for natural gas - Alaska, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 269 277 185 R 159 170 Production (million cubic feet) Gross Withdrawals From Gas Wells 127,417 112,268

  4. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 District of Columbia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S9. Summary statistics for natural gas - District of Columbia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells

  5. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Indiana - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S16. Summary statistics for natural gas - Indiana, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 620 914 819 R 921 895 Production (million cubic feet) Gross Withdrawals From Gas Wells 6,802 9,075

  6. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Massachusetts - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S23. Summary statistics for natural gas - Massachusetts, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0

  7. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Nebraska - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S29. Summary statistics for natural gas - Nebraska, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 276 322 270 R 357 310 Production (million cubic feet) Gross Withdrawals From Gas Wells 2,092 1,854

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    50 North Dakota - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S36. Summary statistics for natural gas - North Dakota, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 188 239 211 200 200 Production (million cubic feet) Gross Withdrawals From Gas Wells

  9. Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery

    SciTech Connect (OSTI)

    Li, Bin; Gu, Meng; Nie, Zimin; Shao, Yuyan; Luo, Qingtao; Wei, Xiaoliang; Li, Xiaolin; Xiao, Jie; Wang, Chong M.; Sprenkle, Vincent L.; Wang, Wei

    2013-02-04

    The selection of electrode materials plays a great role in improving performances of all vanadium redox flow batteries (VRBs). Low-cost graphite felt (GF) as traditional electrode material has to be modified to address its issue of low electrocatalytic activity. In our paper, low-cost and highly conductive bismuth nanoparticles, as a powerful alternative electrocatalyst to noble metal, are proposed and synchronously electro-deposited onto the surface of GF while running flow cells employing the electrolytes containing suitable Bi3+. Although bismuth is proved to only take effect on the redox reaction of V(II)/V(III) and present at negative half-cell side, the whole cell electrochemical performances are significantly improved. In particular, the energy efficiency is increased by 11% owing to faster charge transfer as compared with one without Bi at high charge/discharge rate of 150 mA/cm2, which is prone to reduce stack size, thus dramatically reducing the cost. The excellent results show great promise of Bi nano-catalysts in the commercialization of VRBs in terms of product cost as well as electrochemical properties.

  10. Resolving Losses at the Negative Electrode in All-Vanadium Redox Flow Batteries Using Electrochemical Impedance Spectroscopy

    SciTech Connect (OSTI)

    Sun, Che Nan; Delnick, Frank M; Aaron, D; Mench, Matthew M; Zawodzinski, Thomas A

    2014-01-01

    We present an in situ electrochemical technique for the quantitative measurement and resolution of the ohmic, charge transfer and diffusion overvoltages at the negative electrode of an all-vanadium redox flow battery (VRFB) using electrochemical impedance spectroscopy (EIS). The mathematics describing the complex impedance of the V+2/V+3 redox reaction is derived and matches the experimental data. The voltage losses contributed by each process have been resolved and quantified at various flow rates and electrode thicknesses as a function of current density during anodic and cathodic polarization. The diffusion overvoltage was affected strongly by flow rate while the charge transfer and ohmic losses were invariant. On the other hand, adopting a thicker electrode significantly changed both the charge transfer and diffusion losses due to increased surface area. Furthermore, the Tafel plot obtained from the impedance resolved charge transfer overvoltage yielded the geometric exchange current density, anodic and cathodic Tafel slopes (135 5 and 121 5 mV/decade respectively) and corresponding transfer coefficients = 0.45 0.02 and = 0.50 0.02 in an operating cell.

  11. The kinetic significance of V{sup 5+} in n-butane oxidation catalyzed by vanadium phosphates

    SciTech Connect (OSTI)

    Coulston, G.W.; Harlow, R.; Herron, N.

    1997-01-10

    Maleic anhydride, a precursor to polyester resins, is made by oxidation of n-butane over vanadium phosphate catalysts. This system is of general interest because it is the only heterogeneously catalyzed, alkane-selective oxidation reaction in commercial use. Time-resolved in situ x-ray absorption spectroscopy shows that when either {alpha}{sub 1}-VOPO{sub 4}/SiO{sub 2} or (VO){sub 2}P{sub 2}O{sub 7}/SiO{sub 2} catalysts are exposed to n-butane, the rate of maleic anhydride formation is proportional to the rate of decay of V{sup 5+} species in the catalyst. Thus V{sup 5+} species are kinetically significant for the production of maleic anhydride and not just for the production of by-products. The results also suggest that V{sup 5+} species in the catalyst. Thus V{sup 5+} species are kinetically significant for the production of maleic anhydride and not just for the production of by-products. The results also suggest that V{sup 5+} species may play a role in the initial hydrogen abstraction from n-butane, the rate-determining step in the reaction sequence. V{sup 4+} sites appear to be responsible for by-product formation.

  12. Wetting and Mechanical Performance of Zirconia Brazed with Silver/Copper Oxide and Silver/Vanadium Oxide Alloys

    SciTech Connect (OSTI)

    Sinnamon, Kathleen E.; Meier, Alan; Joshi, Vineet V.

    2014-12-01

    The wetting behavior and mechanical strength of silver/copper oxide and silver/vanadium oxide braze alloys were investigated for both magnesia-stabilized and yttria-stabilized (Mg-PSZ and Y-TZP) transformation toughened zirconia substrates. The temperatures investigated were 1000 to 1100°C, with oxide additions of 1 to 10 weight percent V2O5 or CuO, and hold times of 0.9 to 3.6 ks. Increasing either the isothermal hold temperature or time had a distinctly negative effect on the joint strength. The maximum strengths for both braze alloys were obtained for 5 wt. % oxide additions at 1050°C with a hold time of 0.9 ks. The Mg-PSZ/Ag-CuO system exhibited a average fracture strength of 255 MPa (45% of the reported monolithic strength), and the Y-TZP/Ag-CuO system had an average fracture strength of 540 MPa (30% of the reported monolithic strength). The fracture strengths were lower for the Ag-V2O5 braze alloys, with fracture strengths of approximately 180 MPa (30% of the monolithic strength) for Mg-PSZ versus approximately 160 MPa (10% of the monolithic strength) for Y-TZP. No interfacial products were observed in low magnification SEM analysis for the brazing alloys containing V2O5 additions, while there were interfacial products present for brazes prepared with CuO additions in the braze alloy.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  14. Recent progress on Exxon's circulating zinc bromine battery system

    SciTech Connect (OSTI)

    Bellows, R.J.

    1981-01-01

    The design, performance, and factory cost of Exxon's circulating zinc bromine batteries are described. The Exxon system has demonstrated stable performance in scale-ups to 3- and 10-kWh sub-modules. Cost studies based on recently demonstrated extrusion and injection molding techniques, have shown that this battery, with plastic electrodes, bipolar stacks, Br/sub 2/ complexation, and circulating electrolytes, could be produced (20 kWh units, 100,000 units/year) at a factory cost of $28/kWh (excluding R.O.I., and various indirect overheads).

  15. Analysis of Zinc 65 Contamination after Vacuum Thermal Process

    SciTech Connect (OSTI)

    Korinko, Paul S.; Tosten, Michael H.

    2013-01-01

    Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

  16. Structural characterization of impurified zinc oxide thin films

    SciTech Connect (OSTI)

    Trinca, L. M.; Galca, A. C. Stancu, V. Chirila, C. Pintilie, L.

    2014-11-05

    Europium doped zinc oxide (Eu:ZnO) thin films have been obtained by pulsed laser deposition (PLD). 002 textured thin films were achieved on glass and silicon substrates, while hetero-epilayers and homo-epilayers have been attained on single crystal SrTiO{sub 3} and ZnO, respectively. X-ray Diffraction (XRD) was employed to characterize the Eu:ZnO thin films. Extended XRD studies confirmed the different thin film structural properties as function of chosen substrates.

  17. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  18. Chemical Vapor Deposited Zinc Sulfide. SPIE Press Monograph

    SciTech Connect (OSTI)

    McCloy, John S.; Tustison, Randal W.

    2013-04-22

    Zinc sulfide has shown unequaled utility for infrared windows that require a combination of long-wavelength infrared transparency, mechanical durability, and elevated-temperature performance. This book reviews the physical properties of chemical vapor deposited ZnS and their relationship to the CVD process that produced them. An in-depth look at the material microstructure is included, along with a discussion of the material's optical properties. Finally, because the CVD process itself is central to the development of this material, a brief history is presented.

  19. An algebraic model for a zinc/bromine flow cell

    SciTech Connect (OSTI)

    Simpson, G.D.; White, R.E. . Dept. of Chemical Engineering)

    1989-08-01

    An algebraic model for a parallel plate, zinc/bromine flow cell is presented and used to predict various performance quantities, which are compared to those predicted by using previously published differential equation models. The results presented compare well with previous work. The model is based on the concept of using well-mixed zones and linear concentration and potential profiles for the diffusion layers and the separator. The Butler-Volmer equation is used for the electro chemical reactions, and the homogeneous reaction between bromine and bromide is included.

  20. Laser Raman spectroscopy study of the zinc and bromide ion complex equilibrium in zinc/bromine battery electrolytes. [2M ZnBr/sub 2/ and 1M KBr solution

    SciTech Connect (OSTI)

    Grimes, P.G.; Larrabee, J.A.

    1985-01-01

    Laser Raman spectroscopy was used to study the zinc and bromide ion complex equilibrium in zinc bromine battery model electrolytes. Solutions of zinc bromide with added KBr, HBr and N-methyl, N-ethyl morpholinium (MEM) bromide were examined and compared. Solutions studied ranged from 1 to 3 molar in zinc and from 2.5 to 8 molar in bromide. A typical Raman spectrum of a zinc bromide solution is shown in Figure 1. Each of the zinc species is identified, Zn/sup + +/ (aq), ZnBr/sup +/, ZnBr/sub 2/ (aq), ZnBr/sub 3//sup -/ and ZnBr/sub 4//sup 2 -/. By the use of peak heights or deconvolution/integration along with published Raman cross sections, the amount of each zinc species could be quantitatively determined. The addition of bromide ions to the zinc bromide solutions will shift the equilibrium toward higher bromide complexes. The added cations will influence the shifts. It has been noted that the conductivity of the electrolyte decreases when the quaternary ammonium ions are present compared to cations such as potassium or hydrogen. Significantly more free zinc is present in zinc bromide solutions with added KBr than with either MEMBr or HBr. Shifts are also noted with the other zinc ion containing species. It appears that the quaternary ammonium ions and possibly the pH could have a stabilizing effect on zinc bromide complex ion formation. 2 figs.

  1. Use of underpotential deposition of zinc to mitigate hydrogen absorption into Monel K500

    SciTech Connect (OSTI)

    Zheng, G.; Popov, B.N.; White, R.E. . Dept. of Chemical Engineering)

    1994-05-01

    Polarization experiments and a potentiostatic pulse technique have been used to show that a monolayer coverage of zinc effectively inhibits the absorption of hydrogen into Monel K500. By depositing a monolayer of zinc on Monel K500 the hydrogen, evolution reaction and hydrogen ingress flux rate were reduced by 60%.

  2. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents and methods of use thereof

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2006-06-27

    Reduced sulfur gas species (e.g., H.sub.2S, COS and CS.sub.2) are removed from a gas stream by compositions wherein a zinc titanate ingredient is associated with a metal oxide-aluminate phase material in the same particle species. Nonlimiting examples of metal oxides comprising the compositions include magnesium oxide, zinc oxide, calcium oxide, nickel oxide, etc.

  3. Thermal-sprayed zinc anodes for cathodic protection of steel-reinforced concrete bridges

    SciTech Connect (OSTI)

    Bullard, Sophie J.; Covino, Bernard S., Jr.; Cramer, Stephen D.; McGill, Galen E.

    1996-01-01

    Thermal-sprayed zinc anodes are being used in Oregon in impressed current cathodic protection (ICCP) systems for reinforced concrete bridges. The U.S. Department of Energy, Albany Research Center, is collaborating with the Oregon Department of Transportation (ODOT) to evaluate the long-term performance and service life of these anodes. Laboratory studies were conducted on concrete slabs coated with 0.5 mm (20 mil) thick, thermal-sprayed zinc anodes. The slabs were electrochemically aged at an accelerated rate using an anode current density of 0.032 A/m2 (3mA/ft2). Half the slabs were preheated before thermal-spraying with zinc; the other half were unheated. Electrochemical aging resulted in the formation at the zinc-concrete interface of a thin, low pH zone (relative to cement paste) consisting primarily of ZnO and Zn(OH)2, and in a second zone of calcium and zinc aluminates and silicates formed by secondary mineralization. Both zones contained elevated concentrations of sulfate and chloride ions. The original bond strength of the zinc coating decreased due to the loss of mechanical bond to the concrete with the initial passage of electrical charge (aging). Additional charge led to an increase in bond strength to a maximum as the result of secondary mineralization of zinc dissolution products with the cement paste. Further charge led to a decrease in bond strength and ultimately coating disbondment as the interfacial reaction zones continued to thicken. This occurred at an effective service life of 27 years at the 0.0022 A/m2 (0.2 mA/ft2) current density typically used by ODOT in ICCP systems for coastal bridges. Zinc coating failure under tensile stress was primarily cohesive within the thickening reaction zones at the zinc-concrete interface. There was no difference between the bond strength of zinc coatings on preheated and unheated concrete surfaces after long service times.

  4. Two-stage regeneration of zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-06-28

    The Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE) is interested in the potential of using a two-step process for regenerating the zinc ferrite desulfurization sorbent. In the first regeneration step, a gas mixture consisting of 12 percent SO{sub 2}, 2 percent O{sub 2}, and 86 percent N{sub 2} is used to convert zinc and iron sulfides to their sulfate forms using a sorbent bed inlet temperature of about 850{degrees}F (454{degrees}C). For the second step, the temperature is raised to about 1400{degrees}F (760{degrees}C), and the sulfates are decomposed to oxides with the concurrent release of sulfur dioxide. The same gas composition used for first step is also used for the second step. The proposed technique would require no steam and also has the advantage of producing a regeneration gas rich in sulfur dioxide. In a commercial operation, recirculating regeneration gas would be supplemented with air as required to supply the necessary oxygen. A bleed stream from regeneration (concentrated SO{sub 2} gas in nitrogen) would constitute feed to sulfur recovery.

  5. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Alabama - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S1. Summary statistics for natural gas - Alabama, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7,026 7,063 6,327 R 6,165 6,118 Production (million cubic feet) Gross Withdrawals From Gas Wells

  6. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Arkansas - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S4. Summary statistics for natural gas - Arkansas, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7,397 8,388 8,538 R 9,843 10,150 Production (million cubic feet) Gross Withdrawals From Gas Wells

  7. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 California - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S5. Summary statistics for natural gas - California, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 1,580 1,308 1,423 R 1,335 1,118 Production (million cubic feet) Gross Withdrawals From Gas

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Colorado - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S6. Summary statistics for natural gas - Colorado, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 28,813 30,101 32,000 R 32,468 38,346 Production (million cubic feet) Gross Withdrawals From Gas

  9. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Florida - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S10. Summary statistics for natural gas - Florida, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 17,182 16,459 19,742

  10. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Georgia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S11. Summary statistics for natural gas - Georgia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells

  11. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Idaho - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S14. Summary statistics for natural gas - Idaho, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells 0 0

  12. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Illinois - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S15. Summary statistics for natural gas - Illinois, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 50 40 40 R 34 36 Production (million cubic feet) Gross Withdrawals From Gas Wells E 1,697 2,114

  13. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Iowa - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S17. Summary statistics for natural gas - Iowa, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells 0 0 0

  14. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Kansas - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S18. Summary statistics for natural gas - Kansas, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 22,145 25,758 24,697 R 23,792 24,354 Production (million cubic feet) Gross Withdrawals From Gas Wells

  15. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Kentucky - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S19. Summary statistics for natural gas - Kentucky, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 17,670 14,632 17,936 R 19,494 19,256 Production (million cubic feet) Gross Withdrawals From Gas

  16. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Louisiana - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S20. Summary statistics for natural gas - Louisiana, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 19,137 21,235 19,792 R 19,528 19,251 Production (million cubic feet) Gross Withdrawals From Gas

  17. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Maine - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S21. Summary statistics for natural gas - Maine, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells 0 0

  18. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Michigan - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S24. Summary statistics for natural gas - Michigan, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 10,100 11,100 10,900 R 10,550 10,500 Production (million cubic feet) Gross Withdrawals From Gas

  19. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Mississippi - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S26. Summary statistics for natural gas - Mississippi, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 1,979 5,732 1,669 R 1,967 1,645 Production (million cubic feet) Gross Withdrawals From Gas

  20. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Missouri - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S27. Summary statistics for natural gas - Missouri, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 53 100 R 26 28 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 R 8 8 From

  1. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Montana - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S28. Summary statistics for natural gas - Montana, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 6,059 6,477 6,240 5,754 5,754 Production (million cubic feet) Gross Withdrawals From Gas Wells

  2. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Nevada - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S30. Summary statistics for natural gas - Nevada, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 R 4 4 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 3 From Oil Wells

  3. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    4 New Mexico - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S33. Summary statistics for natural gas - New Mexico, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 44,748 32,302 28,206 R 27,073 27,957 Production (million cubic feet) Gross Withdrawals From

  4. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 New York - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S34. Summary statistics for natural gas - New York, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 6,736 6,157 7,176 R 6,902 7,119 Production (million cubic feet) Gross Withdrawals From Gas Wells

  5. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Ohio - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S37. Summary statistics for natural gas - Ohio, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 34,931 46,717 35,104 R 32,664 32,967 Production (million cubic feet) Gross Withdrawals From Gas Wells

  6. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Oklahoma - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S38. Summary statistics for natural gas - Oklahoma, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 44,000 41,238 40,000 39,776 40,070 Production (million cubic feet) Gross Withdrawals From Gas

  7. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Oregon - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S39. Summary statistics for natural gas - Oregon, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 26 24 27 R 26 28 Production (million cubic feet) Gross Withdrawals From Gas Wells 1,407 1,344 770 770

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Pennsylvania - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S40. Summary statistics for natural gas - Pennsylvania, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 44,500 54,347 55,136 R 53,762 70,400 Production (million cubic feet) Gross Withdrawals

  9. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Tennessee - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S44. Summary statistics for natural gas - Tennessee, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 230 210 212 R 1,089 1,024 Production (million cubic feet) Gross Withdrawals From Gas Wells 5,144

  10. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Texas - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S45. Summary statistics for natural gas - Texas, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 95,014 100,966 96,617 97,618 98,279 Production (million cubic feet) Gross Withdrawals From Gas Wells

  11. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    0 Utah - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S46. Summary statistics for natural gas - Utah, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 6,075 6,469 6,900 R 7,030 7,275 Production (million cubic feet) Gross Withdrawals From Gas Wells 328,135

  12. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Virginia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S48. Summary statistics for natural gas - Virginia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7,470 7,903 7,843 R 7,956 7,961 Production (million cubic feet) Gross Withdrawals From Gas Wells

  13. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    8 West Virginia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S50. Summary statistics for natural gas - West Virginia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 52,498 56,813 50,700 R 54,920 60,000 Production (million cubic feet) Gross Withdrawals

  14. Electrical current suppression in Pd-doped vanadium pentoxide nanowires caused by reduction in PdO due to hydrogen exposure

    SciTech Connect (OSTI)

    Kim, Byung Hoon; Oh, Soon-Young; Yu, Han Young; Yun, Yong Ju; Kim, Yark Yeon; Hong, Won G.; Jeong, Hu Young; Lee, Jeong Yong; Kim, Hae Jin

    2010-04-19

    Pd nanoparticle-doped vanadium pentoxide nanowires (Pd-VONs) were synthesized. Electrical current suppression was observed when the Pd-VON was exposed to hydrogen gas, which cannot be explained by the work function changes mentioned in previous report such as Pd-doped carbon nanotubes and SnO{sub 2} nanowires. Using the x-ray photoelectron spectroscopy, we found that the reduction in PdO due to hydrogen exposure plays an important role in the current suppression of the Pd-VON.

  15. Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.; Carciello, N.R.

    1987-04-21

    This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80 C. The polyelectrolyte or the precoat is present in about 0.5--5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150 C to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2 [times] 10[sup 5] gave improved ductility modulus effect. 5 figs.

  16. Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate

    DOE Patents [OSTI]

    Sugama, Toshifumi; Kukacka, Lawrence E.; Carciello, Neal R.

    1987-01-01

    This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80.degree. C. The polyelectrolyte or the precoat is present in about 0.5-5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150.degree. C. to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2.times.10.sup.5 gave improved ductility modulus effect.

  17. 2009 Total Energy Production by State | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Total Energy Production by State 2009 Total Energy Production by State 2009 Total Energy Production by State...

  18. Modular synthetic inverters from zinc finger proteins and small RNAs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hsia, Justin; Holtz, William J.; Maharbiz, Michel M.; Arcak, Murat; Keasling, Jay D.; Rao, Christopher V.

    2016-02-17

    Synthetic zinc finger proteins (ZFPs) can be created to target promoter DNA sequences, repressing transcription. The binding of small RNA (sRNA) to ZFP mRNA creates an ultrasensitive response to generate higher effective Hill coefficients. Here we combined three “off the shelf” ZFPs and three sRNAs to create new modular inverters in E. coli and quantify their behavior using induction fold. We found a general ordering of the effects of the ZFPs and sRNAs on induction fold that mostly held true when combining these parts. We then attempted to construct a ring oscillator using our new inverters. In conclusion, our chosenmore » parts performed insufficiently to create oscillations, but we include future directions for improvement upon our work presented here.« less

  19. Electricity in the production of metals: From aluminum to zinc

    SciTech Connect (OSTI)

    Evans, J.W.

    1995-04-01

    This article treats some electrometallurgical and electromagnetic metals. but it opens with an examination of whether there is ``electricity`` (i.e., vitality) in the primary metals industries, particularly within the United States of America. That question is examined in terms of the economics of two examples: aluminum and zinc. Then, three examples are provided of potential improvements in the production of metals arising front industrial and university research: use of new electrode materials in Hall-Heroult cells to reduce energy consumption in aluminum smelting, the fluidized bed electrowinning of copper and other metals, and the employment of electromagnetic forces in metals processing, particularly electromagnetic casting. The article concludes with observations on the paucity of United States support for research and development (R and D) in primary metals production, compared with that of the industrial activities and of other nations. and suggests a prognosis for the future of arcade research and teaching in extractive and process metallurgy.

  20. Zinc oxysulfide ternary alloy nanocrystals: A bandgap modulated photocatalyst

    SciTech Connect (OSTI)

    Pandey, Shiv K.; Nanotechnology Application Centre, University of Allahabad, Allahabad ; Pandey, Shipra; Pandey, Avinash C.; Mehrotra, G. K.

    2013-06-10

    Herein, we report a green economic route for the synthesis of a series of Zinc Oxysulfide (ZOS) (ZnO{sub 1-x}S{sub x}; 0 {<=} x {>=} 1; x = Sulfur) alloys nanoparticles. The crystallographic features of ZnO, ZOS, and ZnS confirmed by X-Ray Diffraction and validated by Transmission Electron Microscopy reveal the variation of lattice spacing in binary and ternary compositions with homogenous elemental distribution. The photocatalytic analysis of ZOS (0.4) is performed and compared with Degussa P25 to ascertain its photocatalytic activity against methyl orange under irradiation of 365 nm UV-Vis light. A bandgap of 2.7 eV for ZOS (0.4) aptly establishes its prospects for sunlight driven photocatalysis.

  1. Development of Thin Section Zinc Die Casting Technology

    SciTech Connect (OSTI)

    Goodwin, Frank

    2013-10-31

    A new high fluidity zinc high pressure die casting alloy, termed the HF alloy, was developed during laboratory trials and proven in industrial production. The HF alloy permits castings to be achieved with section thicknesses of 0.3 mm or less. Technology transfer activities were conducted to develop usage of the HF high fluidity alloy. These included production of a brochure and a one-hour webinar on the HF alloy. The brochure was then sent to 1,184 product designers in the Interzinc database. There was excellent reception to this mailing, and from this initial contact 5 technology transfer seminars were conducted for 81 participants from 30 companies across a wide range of business sectors. Many of the successful applications to date involve high quality surface finishes. Design and manufacturing assistance was given for development of selected applications.

  2. Cell Total Activity Final Estimate.xls

    Office of Legacy Management (LM)

    WSSRAP Cell Total Activity Final Estimate (calculated September 2002, Fleming) (Waste streams & occupied cell volumes from spreadsheet titled "cell waste volumes-8.23.02 with macros.xls") Waste Stream a Volume (cy) Mass (g) 2 Radiological Profile 3 Nuclide Activity (Ci) 4 Total % of Total U-238 U-234 U-235 Th-228 Th-230 Th-232 Ra-226 Ra-228 Rn-222 5 Activity if > 1% Raffinate Pits Work Zone (Ci) Raffinate processed through CSS Plant 1 159990 1.49E+11 Raffinate 6.12E+01 6.12E+01

  3. TotalView Parallel Debugger at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The performance of the GUI can be greatly improved if used in conjunction with free NX software. The TotalView documentation web page is a good resource for learning more...

  4. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    -3,826 Total Supply 854,673 908,380 892,923 R 900,232 828,785 See footnotes at end of ... Gas Annual 165 Table S43. Summary statistics for natural gas - South Dakota, ...

  5. Total Ore Processing Integration and Management

    SciTech Connect (OSTI)

    Leslie Gertsch; Richard Gertsch

    2004-06-30

    This report outlines the technical progress achieved for project DE-FC26-03NT41785 (Total Ore Processing Integration and Management) during the period 01 April through 30 June of 2004.

  6. EQUUS Total Return Inc | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: EQUUS Total Return Inc Place: Houston, Texas Product: A business development company and VC investor that trades as a closed-end fund. EQUUS is...

  7. Million Cu. Feet Percent of National Total

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    as known volumes of natural gas that were the result of leaks, damage, accidents, migration, andor blow down. Notes: Totals may not add due to independent rounding. Prices are...

  8. ARM - Measurement - Net broadband total irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsNet broadband total irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Net broadband total irradiance The difference between upwelling and downwelling, covering longwave and shortwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  9. ARM - Measurement - Shortwave broadband total downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total downwelling irradiance The total diffuse and direct radiant energy that comes from some continuous range of directions, at wavelengths between 0.4 and 4 {mu}m, that is being emitted downwards. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  10. High-Quality Manganese-Doped Zinc Sulfide Quantum Rods with Tunable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Quality Manganese-Doped Zinc Sulfide Quantum Rods with Tunable Dual-Color and Multiphoton Emissions Authors: Deng, Z., Tong, L., Flores, M., Lin, S., Cheng, J.-X., Yan, H.,...

  11. Spin-dependent electron transport in zinc- and manganese-doped adenine molecules

    SciTech Connect (OSTI)

    Simchi, Hamidreza; Esmaeilzadeh, Mahdi Mazidabadi, Hossein

    2014-01-28

    The spin-dependent electron transport properties of zinc- and manganese-doped adenine molecules connected to zigzag graphene leads are studied in the zero bias regime using the non-equilibrium Green's function method. The conductance of the adenine molecule increased and became spin-dependent when a zinc or manganese atom was doped into the molecules. The effects of a transverse electric field on the spin-polarization of the transmitted electrons were investigated and the spin-polarization was controlled by changing the transverse electric field. Under the presence of a transverse electric field, both the zinc- and manganese-doped adenine molecules acted as spin-filters. The maximum spin-polarization of the manganese-doped adenine molecule was greater than the molecule doped with zinc.

  12. A 1.3-Å Structure of Zinc-bound N-terminal Domain of Calmodulin...

    Office of Scientific and Technical Information (OSTI)

    Ion-binding Step Citation Details In-Document Search Title: A 1.3- Structure of Zinc-bound N-terminal Domain of Calmodulin Elucidates Potential Early Ion-binding Step Authors: ...

  13. EFFECT OF THERMAL PROCESSES ON COPPER-TIN ALLOYS FOR ZINC GETTERING

    SciTech Connect (OSTI)

    Korinko, P.; Golyski, M.

    2013-11-01

    A contamination mitigation plan was initiated to address the discovery of radioactive zinc‐65 in a glovebox. A near term solution was developed, installation of heated filters in the glovebox piping. This solution is effective at retaining the zinc in the currently contaminated area, but the gamma emitting contaminant is still present in a system designed for tritium beta. A project was initiated to develop a solution to contain the {sup 65}Zn in the furnace module. Copper and bronze (a Cu/Sn alloy) were found to be candidate materials to combine with zinc‐65 vapor, using thermodynamic calculations. A series of binary Cu/Sn alloys were developed (after determining that commercial alloys were unacceptable), that were found to be effective traps of zinc vapor. The task described in this report was undertaken to determine if the bronze substrates would retain their zinc gettering capability after being exposed to simulated extraction conditions with oxidizing and reducing gases. Pure copper and three bronze alloys were prepared, exposed to varying oxidation conditions from 250 to 450{degree}C, then exposed to varying reduction conditions in He-H{sub 2} from 250-450{degree}C, and finally exposed to zinc vapor at 350{degree}C for four hours. The samples were characterized using scanning electron microscopy, X-ray diffraction, differential thermal analysis, mass change, and visual observation. It was observed that the as fabricated samples and the reduced samples all retained their zinc gettering capacity while samples in the "as-oxidized" condition exhibited losses in zinc gettering capacity. Over the range of conditions tested, i.e., composition, oxidation temperature, and reduction temperature, no particular sample composition appeared better. Samples reduced at 350{degree}C exhibited the greatest zinc capacity, although there were some testing anomalies associated with these samples. This work clearly demonstrated that the zinc gettering was not adversely

  14. Material and Energy Flows Associated with Select Metals in GREET 2. Molybdenum, Platinum, Zinc, Nickel, Silicon

    SciTech Connect (OSTI)

    Benavides, Pahola T.; Dai, Qiang; Sullivan, John L.; Kelly, Jarod C.; Dunn, Jennifer B.

    2015-09-01

    In this work, we analyzed the material and energy consumption from mining to production of molybdenum, platinum, zinc, and nickel. We also analyzed the production of solar- and semiconductor-grade silicon. We described new additions to and expansions of the data in GREET 2. In some cases, we used operating permits and sustainability reports to estimate the material and energy flows for molybdenum, platinum, and nickel, while for zinc and silicon we relied on information provided in the literature.

  15. Successful removal of zinc sulfide scale restriction from a hot, deep, sour gas well

    SciTech Connect (OSTI)

    Kenrick, A.J.; Ali, S.A.

    1997-07-01

    Removal of zinc sulfide scale with hydrochloric acid from a hot, deep, Norphlet Sandstone gas well in the Gulf of Mexico resulted in a 29% increase in the production rates. The zinc sulfide scale was determined to be in the near-wellbore area. The presence of zinc sulfide is explained by the production of 25 ppm H{sub 2}S gas, and the loss of 50--100 bbl of zinc bromide fluid to the formation. Although zinc sulfide scale has been successfully removed with hydrochloric acid in low-to-moderate temperature wells, no analogous treatment data were available for high temperature, high pressure (HTHP) Norphlet wells. Therefore laboratory testing was initiated to identify suitable acid systems for scale removal, and select a high quality corrosion inhibitor that would mitigate detrimental effects of the selected acid on downhole tubulars and surface equipment. This case history presents the first successful use of hydrochloric acid in removing zinc sulfide scale from a HTHP Norphlet sour gas well.

  16. Zinc protects human peripheral blood lymphocytes from Cr(III)(phenanthroline){sub 3}-induced apoptosis

    SciTech Connect (OSTI)

    Sankaramanivel, Sundararaj; Rajaram, Anantanarayanan; Rajaram, Rama

    2010-03-15

    We have studied the effect of Cr(III)(phen){sub 3} [(tris(1,10-phenanthroline) chromium(III) chloride)] on lymphocytes in order to find out if metallothioneins (MTs) are produced in the process. We also investigated whether zinc pretreatment is able to protect cells from apoptosis reported to occur for this compound. Our results indicate that MT synthesis is induced by Cr(III)(phen){sub 3}, and it has been identified as the MT-3 isoform through RT-PCR which has not been reported earlier. By zinc pretreatment, this apoptosis is reversed as inferred from cytotoxicity studies, Annexin-V/PI staining, ethidium bromide/acridine orange staining and DNA fragmentation pattern and ultrastructural investigations using TEM and SEM. The zinc pretreatment reduces the amount of ROS produced by Cr(III)(phen){sub 3} . The MT-1a and 1b synthesized by zinc (also evidenced through RT-PCR experiments) is possibly able to scavenge ROS which is one of the early signaling molecules that lead to apoptosis. Zinc pretreatment also reverses the changes in downstream signaling events such as mitochondrial membrane potential, ATP levels and the activation of caspase-3. This is the first report on the induction of MT-3 in lymphocytes due to a metal stress or any other stimuli. Even though MT-3 is synthesized here, apoptosis still occurs due to ROS production on Cr(III)(phen){sub 3} exposure when the cells have not been primed with zinc.

  17. ARM - Measurement - Shortwave spectral total downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    total downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral total downwelling irradiance The rate at which radiant energy, at specrally-resolved wavelengths between 0.4 and 4 {mu}m, is being emitted upwards and downwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments

  18. Ordered Nucleation Sites for the Growth of Zinc Oxide Nanofibers

    SciTech Connect (OSTI)

    Wang, J.; Ginley, D.S.; Shaheen, S.

    2006-01-01

    Organic photovoltaics (OPVs) offer a promising route to low cost photovoltaic (PV) technology that can be inexpensively manufactured on a large scale for use in power generation and commercial products. Solar power conversion efficiencies of laboratory scale OPV devices have recently reached ~5%; however, projected efficiencies of at least 10% will be required for commercialization. An analogous approach that has arisen recently that can potentially increase efficiencies employs metal oxide semiconductors as the electron acceptor, creating a hybrid organic-inorganic device. This approach offers the advantage that the conduction band of the oxide can be tuned in a systematic way through doping, thus potentially achieving higher photovoltages in the device. Additionally, nanostructures of these materials can be easily grown from precursor solutions, providing a technique to precisely control the nanoscale geometry. This work focuses on using ZnO, which is known to have high electron mobility (>100 cm2/Vs), as the electron acceptor. Nanofibers of ZnO can be grown from precursors such as zinc acetate or zinc nitrate to form arrays of nanofibers into which a conjugated polymer can be intercalated to form a composite PV device. The morphology of the nanofiber array is critical to the performance of the device, but current methods of nanofiber growth from a flat, polycrystalline nucleation layer allow for little morphological control. To overcome this limitation, we have created ordered arrays of ZnO nucleation sites with controllable size and spacing. Toluene solutions of diblock copolymer micelles with ZnCl2 incorporated into the micellar cores were spin-coated onto glass substrates and etched with an O2 plasma to yield hexagonally ordered arrays of ZnO nanoparticles that functioned as nucleation sites. Changing the concentration of ZnCl2 and the molecular weight and ratio of the diblock copolymer resulted in systematic variation in the size and spacing of the

  19. Total internal reflection laser tools and methods

    DOE Patents [OSTI]

    Zediker, Mark S.; Faircloth, Brian O.; Kolachalam, Sharath K.; Grubb, Daryl L.

    2016-02-02

    There is provided high power laser tools and laser heads that utilize total internal reflection ("TIR") structures to direct the laser beam along a laser beam path within the TIR structure. The TIR structures may be a TIR prism having its hypotenuse as a TIR surface.

  20. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) Indexed Site

    R 196 184 Total Supply 2,627 2,619 2,689 R 2,855 2,928 See footnotes at end of table. 0 ... Gas Annual 105 Table S13. Summary statistics for natural gas - Hawaii, 2010-2014 - ...

  1. The Leica TCRA1105 Reflectorless Total Station

    SciTech Connect (OSTI)

    Gaudreault, F.

    2005-09-06

    This poster provides an overview of SLAC's TCRA1105 reflectorless total station for the Alignment Engineering Group. This instrument has shown itself to be very useful for planning new construction and providing quick measurements to difficult to reach or inaccessible surfaces.

  2. Total pressing Indonesian gas development, exports

    SciTech Connect (OSTI)

    Not Available

    1994-01-24

    Total is on track to become Indonesia's leading gas exporter by the turn of the century. Total's aggressive development of its Mahakam Delta acreage in East Kalimantan is intended to keep pace with growing liquefied natural gas demand, mainly from Japan but also increasingly from South Korea and Taiwan. A frantic scramble is under way among natural gas suppliers in the Pacific Rim region, particularly those with current LNG export facilities, to accommodate projections of soaring natural gas demand in the region. Accordingly, Total's Indonesian gas production goal is the centerpiece of a larger strategy to become a major player in the Far East Asia gas scene. Its goals also fall in line with Indonesia's. Facing flat or declining oil production while domestic oil demand continues to soar along with a rapidly growing economy, Indonesia is heeding some studies that project the country could become a net oil importer by the turn of the century. The paper describes Total's Far East strategy, the Mahakam acreage which it operates, the shift to gas development, added discoveries, future development, project spending levels, and LNG export capacity.

  3. Quantitative study on the chemical solution deposition of zinc oxysulfide

    SciTech Connect (OSTI)

    Reinisch, Michael; Perkins, Craig L.; Steirer, K. Xerxes

    2015-11-21

    Zinc Oxysulfide (ZnOS) has demonstrated potential in the last decade to replace CdS as a buffer layer material since it is a wide-band-gap semiconductor with performance advantages over CdS (Eg = 2.4 eV) in the near UV-range for solar energy conversion. However, questions remain on the growth mechanisms of chemical bath deposited ZnOS. In this study, a detailed model is employed to calculate solubility diagrams that describe simple conditions for complex speciation control using only ammonium hydroxide without additional base. For these conditions, ZnOS is deposited via aqueous solution deposition on a quartz crystal microbalance in a continuous flow cell. Data is used to analyze the growth rate dependence on temperature and also to elucidate the effects of dimethylsulfoxide (DMSO) when used as a co-solvent. Activation energies (EA) of ZnOS are calculated for different flow rates and solution compositions. As a result, the measured EA relationships are affected by changes in the primary growth mechanism when DMSO is included.

  4. Quantitative study on the chemical solution deposition of zinc oxysulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reinisch, Michael; Perkins, Craig L.; Steirer, K. Xerxes

    2015-11-21

    Zinc Oxysulfide (ZnOS) has demonstrated potential in the last decade to replace CdS as a buffer layer material since it is a wide-band-gap semiconductor with performance advantages over CdS (Eg = 2.4 eV) in the near UV-range for solar energy conversion. However, questions remain on the growth mechanisms of chemical bath deposited ZnOS. In this study, a detailed model is employed to calculate solubility diagrams that describe simple conditions for complex speciation control using only ammonium hydroxide without additional base. For these conditions, ZnOS is deposited via aqueous solution deposition on a quartz crystal microbalance in a continuous flow cell.more » Data is used to analyze the growth rate dependence on temperature and also to elucidate the effects of dimethylsulfoxide (DMSO) when used as a co-solvent. Activation energies (EA) of ZnOS are calculated for different flow rates and solution compositions. As a result, the measured EA relationships are affected by changes in the primary growth mechanism when DMSO is included.« less

  5. Experimental and computational studies on stacking faults in zinc titanate

    SciTech Connect (OSTI)

    Sun, W.; Ageh, V.; Mohseni, H.; Scharf, T. W. E-mail: Jincheng.Du@unt.edu; Du, J. E-mail: Jincheng.Du@unt.edu

    2014-06-16

    Zinc titanate (ZnTiO{sub 3}) thin films grown by atomic layer deposition with ilmenite structure have recently been identified as an excellent solid lubricant, where low interfacial shear and friction are achieved due to intrafilm shear velocity accommodation in sliding contacts. In this Letter, high resolution transmission electron microscopy with electron diffraction revealed that extensive stacking faults are present on ZnTiO{sub 3} textured (104) planes. These growth stacking faults serve as a pathway for dislocations to glide parallel to the sliding direction and hence achieve low interfacial shear/friction. Generalized stacking fault energy plots also known as ?-surfaces were computed for the (104) surface of ZnTiO{sub 3} using energy minimization method with classical effective partial charge potential and verified by using density functional theory first principles calculations for stacking fault energies along certain directions. These two are in qualitative agreement but classical simulations generally overestimate the energies. In addition, the lowest energy path was determined to be along the [451{sup }] direction and the most favorable glide system is (104) ?451{sup }? that is responsible for the experimentally observed sliding-induced ductility.

  6. Zinc-chlorine battery plant system and method

    DOE Patents [OSTI]

    Whittlesey, Curtis C.; Mashikian, Matthew S.

    1981-01-01

    A zinc-chlorine battery plant system and method of redirecting the electrical current around a failed battery module. The battery plant includes a power conditioning unit, a plurality of battery modules connected electrically in series to form battery strings, a plurality of battery strings electrically connected in parallel to the power conditioning unit, and a bypass switch for each battery module in the battery plant. The bypass switch includes a normally open main contact across the power terminals of the battery module, and a set of normally closed auxiliary contacts for controlling the supply of reactants electrochemically transformed in the cells of the battery module. Upon the determination of a failure condition, the bypass switch for the failed battery module is energized to close the main contact and open the auxiliary contacts. Within a short time, the electrical current through the battery module will substantially decrease due to the cutoff of the supply of reactants, and the electrical current flow through the battery string will be redirected through the main contact of the bypass switch.

  7. Controlled Co(II) Doping of Zinc Oxide Nanocrystals

    SciTech Connect (OSTI)

    S Bohle; C Spina

    2011-12-31

    Dopants are non-native atoms commonly used to modify the properties of bulk semiconductors. In this paper we demonstrate that by controlling the addition of cobalt(II) to growing zinc oxide nanocrystals (ZnO NCs) it is possible to modulate the resulting properties. We show that the environment of cobalt may be controlled by varying the synthetic conditions, mainly through varying the time of dopant-precursor addition and concentration. These conditions prove critical to the resulting Co(II) configuration, which affects both the luminescent and photocatalytic properties of the ZnO NCs. Presynthetic doping with 2% Co(II) results in a 98% quenching of the visible emission of ZnO, whereas the same quantity doped post synthesis results in only a 60% quenching. The environment of cobalt in the ZnO wurtzite lattice is identified through UV-vis spectroscopy. The wurtzite structure of the ZnO lattice for all nanocrystalline species is confirmed through X-ray diffraction patterns obtained from a synchrotron radiation source. Postsynthetically doped Co(II) in ZnO NC is demonstrated to have potential applications as an 'on-off' sensor, as exemplified with nitric oxide.

  8. Synthesis and studies on microhardness of alkali zinc borate glasses

    SciTech Connect (OSTI)

    Subhashini, Bhattacharya, Soumalya Shashikala, H. D. Udayashankar, N. K.

    2014-04-24

    The mixed alkali effect on zinc borate glasses have been reported. The glass systems of nominal composition 10Zn+xLi{sub 2}O+yNa{sub 2}O+80B{sub 2}O{sub 3} (x = y = 0, 5, 10, 15 mol%) were prepared using standard melt quenching method. The structural, physical and mechanical properties of the samples have been studied using X-ray diffraction(XRD), density measurement and Vickers hardness measurement, respectively. A consistent increase in the density was observed, which explains the role of the modifiers (Li{sub 2}O and Na{sub 2}O) in the network modification of borate structure. The molar volume is decreasing linearly with the alkali concentration, which is attributed to the conversion of tetrahedral boron (BO{sub 4/2}){sup −} into (BO{sub 3/2}){sup −}. The microhardness studies reveals the anisotropy nature of the material. It further confirms that the samples belong to hard glass category.

  9. Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit

    DOE Patents [OSTI]

    McQuaid, James H.; Lavietes, Anthony D.

    1998-05-29

    A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radio nuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components.

  10. Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit

    DOE Patents [OSTI]

    McQuaid, J.H.; Lavietes, A.D.

    1998-05-26

    A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector is disclosed. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radionuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components. 9 figs.

  11. Country/Continent Total Percent of U.S. Total Africa/Europe

    U.S. Energy Information Administration (EIA) Indexed Site

    peak kilowatts Country/Continent Total Percent of U.S. Total Africa/Europe 53,898 29% Asia/Australia 107,460 59% South/Central America 11,692 6% Canada 4,378 2% Mexico 5,556 3% Total 182,984 100% Table 8. Destination of photovoltaic module export shipments, 2014 Source: U.S. Energy Information Administration, Form EIA-63B, 'Annual Photovoltaic Cell/Module Shipments Report.'

  12. Tensile properties of vanadium-base alloys irradiated in the Fusion-1 low-temperature experiment in the BOR-60 reactor

    SciTech Connect (OSTI)

    Tsai, H.; Gazda, J.; Nowicki, L.J.; Billone, M.C.; Smith, D.L.

    1998-09-01

    The irradiation has been completed and the test specimens have been retrieved from the lithium-bonded capsule at the Research Institute of Atomic Reactors (RIAR) in Russia. During this reporting period, the Argonne National Laboratory (ANL) tensile specimens were received from RIAR and initial testing and examination of these specimens at ANL has been completed. The results, corroborating previous findings showed a significant loss of work hardening capability in the materials. There appears to be no significant difference in behavior among the various heats of vanadium-base alloys in the V-(4-5)Cr-(4-5)Ti composition range. The variations in the preirradiation annealing conditions also produced no notable differences.

  13. Literature search for the non-aqueous separation of zinc from fuel rod cladding. [After dissolution in liquid metal

    SciTech Connect (OSTI)

    Sandvig, R. L.; Dyer, S. J.; Lambert, G. A.; Baldwin, C. E.

    1980-06-21

    This report reviews the literature of processes for the nonaqueous separation of zinc from dissolved fuel assembly cladding. The processes considered were distillation, pyrochemical processing, and electrorefining. The last two techniques were only qualitatively surveyed while the first, distillation, was surveyed in detail. A survey of available literature from 1908 through 1978 on the distillation of zinc was performed. The literature search indicated that a zinc recovery rate in excess of 95% is possible; however, technical problems exist because of the high temperatures required and the corrosive nature of liquid zinc. The report includes a bibliography of the surveyed literature and a computer simulation of vapor pressures in binary systems. 129 references.

  14. [beta]-BaV[sub 2](P[sub 2]O[sub 7])[sub 2]: A new polymorph of barium vanadium (III) pyrophosphate characterized by intersecting tunnels

    SciTech Connect (OSTI)

    Hwu, Shiou-Jyh; Carroll, R.I.; Serra, D.L. )

    1994-06-01

    Investigation into the synthesis of reduced vanadium phosphate has led to the formation of a new form of the barium vanadium (III) pyrophosphate compound [beta]-BaV[sub 2](P[sub 2]O[sub 7])[sub 2]. It is a polymorph of the previously known BaV[sub 2](P[sub 2]O[sub 7])[sub 2], which is now labeled as the [alpha]-phase. The title compound crystallizes in the P-1 (No. 2) space group with a = 6.269 (1) [angstrom], b = 7.864 (3) [angstrom], c = 6.1592 (9) [angstrom], [alpha] = 101.34 (2)[degree], [beta] = 105.84 (1)[degree], and [gamma] = 96.51 (2)[degree]. The structure consists of corner-shared VO[sub 6] octahedra and PO[sub 4] tetrahedra that are connected in V-O-P-O-V and V-O-P-O-P-O-V bonding arrangements. This interesting three-dimensional framework is characterized by seven types of intersecting tunnels, three of which are occupied by the barium cation, while the others are empty. It is important to know that one of the empty tunnels has a relatively large window with a minimum diagonal distance of 4.4 [angstrom], which facilitates a possible framework for a lithium ion insertion reaction. The barium atom has a 10-coordination sphere, BaO[sub 10], in which the oxygen atoms can be viewed as forming two intersecting pseudohexagonal planes. [beta]-BaV[sub 2](P[sub 2]O[sub 7])[sub 2] appears to form at a relatively higher temperature than its polymorph, [alpha]-BaV[sub 2](P[sub 2]O[sub 7])[sub 2]. A detailed structural analysis and structural comparison with the [alpha]-phase, as well as a brief comparison with SrV[sub 2](P[sub 2]O[sub 7])[sub 2], are presented.

  15. Fractionated total body irradiation for metastatic neuroblastoma

    SciTech Connect (OSTI)

    Kun, L.E.; Casper, J.T.; Kline, R.W.; Piaskowski, V.D.

    1981-11-01

    Twelve patients over one year old with neuroblastoma (NBL) metastatic to bone and bone marrow entered a study of adjuvant low-dose, fractionated total body irradiation (TBI). Six children who achieved a ''complete clinical response'' following chemotherapy (cyclophosphamide and adriamycin) and surgical resection of the abdominal primary received TBI (10 rad/fraction to totals of 100-120 rad/10-12 fx/12-25 days). Two children received concurrent local irradiation for residual abdominal tumor. The intervals from cessation of chemotherapy to documented progression ranged from 2-16 months, not substatially different from patients receiving similar chemotherapy and surgery without TBI. Three additional children with progressive NBL received similar TBI (80-120 rad/8-12 fx) without objective response.

  16. Frustrated total internal reflection acoustic field sensor

    DOE Patents [OSTI]

    Kallman, Jeffrey S.

    2000-01-01

    A frustrated total internal reflection acoustic field sensor which allows the acquisition of the acoustic field over an entire plane, all at once. The sensor finds use in acoustic holography and acoustic diffraction tomography. For example, the sensor may be produced by a transparent plate with transparent support members tall enough to support one or more flexible membranes at an appropriate height for frustrated total internal reflection to occur. An acoustic wave causes the membrane to deflect away from its quiescent position and thus changes the amount of light that tunnels through the gap formed by the support members and into the membrane, and so changes the amount of light reflected by the membrane. The sensor(s) is illuminated by a uniform tight field, and the reflection from the sensor yields acoustic wave amplitude and phase information which can be picked up electronically or otherwise.

  17. Vanadium Carbide Coating Process

    Broader source: Energy.gov [DOE]

    Traditional methods of coating steel surfaces with a layer of hard metal carbide require large capital investment, produce toxic and hazardous gases, are costly to operate, and require multiple...

  18. Zirconium vanadium chromium alloy

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1980-10-14

    A ternary intermetallic compound having the formula Zr(V/sub 1-x/Cr/sub x/)/sub 2/ where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200/sup 0/C, at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  19. Total Crude Oil and Petroleum Products Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter Kerosene and

  20. ARM - Measurement - Shortwave broadband total net irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    net irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total net irradiance The difference between upwelling and downwelling broadband shortwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  1. ARM - Measurement - Shortwave narrowband total downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband total downwelling irradiance The rate at which radiant energy, in narrow bands of wavelengths shorter than approximately 4 {mu}m, passes through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  2. ARM - Measurement - Shortwave narrowband total upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband total upwelling irradiance The rate at which radiant energy, in narrow bands of wavelengths shorter than approximately 4 {mu}m, passes through a horizontal unit area in an upward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments.

  3. Zinc chromate induces chromosome instability and DNA double strand breaks in human lung cells

    SciTech Connect (OSTI)

    Xie Hong; Holmes, Amie L.; Young, Jamie L.; Qin Qin; Joyce, Kellie; Pelsue, Stephen C.; Peng Cheng; Wise, Sandra S.; Jeevarajan, Antony S.; Wallace, William T.; Hammond, Dianne; Wise, John Pierce E-mail: John.Wise@usm.maine.edu

    2009-02-01

    Hexavalent chromium Cr(VI) is a respiratory toxicant and carcinogen, with solubility playing an important role in its carcinogenic potential. Zinc chromate, a water insoluble or 'particulate' Cr(VI) compound, has been shown to be carcinogenic in epidemiology studies and to induce tumors in experimental animals, but its genotoxicity is poorly understood. Our study shows that zinc chromate induced concentration-dependent increases in cytotoxicity, chromosome damage and DNA double strand breaks in human lung cells. In response to zinc chromate-induced breaks, MRE11 expression was increased and ATM and ATR were phosphorylated, indicating that the DNA double strand break repair system was initiated in the cells. In addition, our data show that zinc chromate-induced double strand breaks were only observed in the G2/M phase population, with no significant amount of double strand breaks observed in G1 and S phase cells. These data will aid in understanding the mechanisms of zinc chromate toxicity and carcinogenesis.

  4. Table 6a. Total Electricity Consumption per Effective Occupied...

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Total Electricity Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using Electricity (thousand) Total Electricity Consumption...

  5. ARM - Measurement - Shortwave broadband total upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total upwelling irradiance The rate at which radiant energy, at a wavelength between 0.4 and 4 {mu}m, is being emitted upwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments The above measurement is considered

  6. Total Adjusted Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 55,664,448 58,258,830 59,769,444 57,512,994 58,675,008 61,890,990 1984-2014 East Coast (PADD 1) 18,219,180 17,965,794 17,864,868 16,754,388

  7. Total Adjusted Sales of Residual Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Commercial Industrial Oil Company Electric Power Vessel Bunkering Military All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 7,835,436 8,203,062 7,068,306 5,668,530 4,883,466 3,942,750 1984-2014 East Coast (PADD 1) 3,339,162 3,359,265 2,667,576 1,906,700 1,699,418 1,393,068 1984-2014 New England (PADD 1A) 318,184

  8. Total Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 54,100,092 56,093,645 57,082,558 57,020,840 58,107,155 60,827,930 1984-2014 East Coast (PADD 1) 17,821,973 18,136,965 17,757,005 17,382,566

  9. The solubility of zinc oxide in 0.03 m NaTr as a function of temperature, with in situ pH measurement

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

    1999-05-01

    The solubility of zincite (ZnO) has been measured in noncomplexing solutions over a wide range of pH{sub m} (4--11), and temperature (75--200 C) at 0.03 mol/kg ionic strength in NaTr media (sodium trifluoromethanesulfonate, a noncomplexing 1:1 electrolyte), in a hydrogen electrode concentration cell (HECC), which provided continuous in situ measurement of hydrogen ion molality. Total zinc content was analyzed by atomic absorption using graphite furnace, flame, and inductively coupled plasma (ICP) spectrometers. The direction of approach to the equilibrium saturation state was varied to demonstrate that the system was reversible thermodynamically. Separate experiments were performed in alkaline solutions (0.03 mol/kg NaOH) at 25 and 50 C in polypropylene syringes, and between 50 and 290 C in a Teflon-lined pressure vessel. The aim of these experiments was to reach higher pH{sub m} (>8 depending on the temperature) to determine the thermodynamic properties of the negatively charged species, Zn(OH){sub 3}{sup {minus}}. A least-squares regression of the results obtained at this ionic strength was used to determine the molal solubility products (Q{sub sn}) of zincite. The solubility products (Q{sub sn}) were extrapolated to infinite dilution (K{sub sn}), permitting calculation of the thermodynamic properties of aqueous species of zinc for comparison with previous work.

  10. The V{sup 4}+/V{sup 5+} balance as a criterion of selection of vanadium phosphorus oxide catalysts for n-butane oxidation to maleic anhydride: A proposal to explain the role of Co and Fe dopants

    SciTech Connect (OSTI)

    Sananes-Schulz, M.T.; Tuel, A.; Volta, J.C.; Hutchings, G.J.

    1997-03-01

    Vanadium phosphorous oxide catalysts (VPO) are well known for the oxidation of n-butane to maleic anhydride, and many papers and patents have been published in the literature on this catalytic system. Concerning the valence state of vanadium in the active surface, a V{sup 4+}/V{sup 5+} equilibrium on the surface of a vanadyl pyrophosphate during n-butane oxidation has been demonstrated which is dependent on the time of activation. In the present note, we study the modifications, as determined by {sup 31}P NMR by spin echo mapping, which are induced in the physicochemical characteristics of VPO catalysts which have major differences in their morphologies when doped with iron and cobalt at a low percentage (1%) and the correlation with their catalytic performances. 21 refs., 5 figs., 2 tabs.

  11. Total Ore Processing Integration and Management

    SciTech Connect (OSTI)

    Leslie Gertsch

    2006-01-30

    This report outlines the technical progress achieved for project DE-FC26-03NT41785 (Total Ore Processing Integration and Management) during the period 01 October through 31 December of 2005. Graphical analysis of blast patterns according to drill monitor data is continuing. Multiple linear regression analysis of 16 mine and mill variables (powder factor, two modeled size fractions, liberation index, predicted grind, total crude Fe, Satmagan Fe, sat ratio, DSC, geologic blend, ambient temperature, cobbing hours, feeder plugs, and percent feeder run time-of-mill time) indicates that December variations in plant performance are generally predictable (Figure 1). The outlier on December 28th coincides with low cobbing availability and equipment downtime. Mill productivity appeared to be most influenced, as usual, by ore quality as indicated by the liberation index--the higher the liberation index, the lower the throughput. The upcoming quarter will be concerned with wrapping up the work in progress, such as the detailed statistical analyses, and writing a final report. Hibtac Mine engineers are evaluating neural network software to determine its utility for modeling, and eventually predicting, mill throughput.

  12. Impacts of humidity and temperature on the performance of transparent conducting zinc oxide.

    SciTech Connect (OSTI)

    Granata, Jennifer E.; Yaklin, Melissa A.; Schneider, Duane Allen; Staiger, Chad Lynn; Norman, Kirsten

    2010-06-01

    The impact of humidity and temperature on a zinc oxide based transparent conducting oxide (TCO) was assessed under accelerated aging conditions. An in situ electroanalytical method was used to monitor the electrical properties for a conducting zinc oxide under controlled atmospheric (humidity, temperature and irradiation) conditions. A review of thin film photovoltaic (PV) literature has shown one major failure mode of cells/modules is associated with the ingress of water into modules in the field. Water contamination has been shown to degrade the performance of the TCO in addition to corroding interconnects and other conductive metals/materials associated with the module. Water ingress is particularly problematic in flexible thin film PV modules since traditional encapsulates such as poly(ethyl vinyl acetate) (EVA) have high water vapor transmission rates. The accelerated aging studies of the zinc oxide based TCOs will allow acceleration factors and kinetic parameters to be determined for reliability purposes.

  13. Local environment in poly(ethylene oxide)-zinc bromide complexes

    SciTech Connect (OSTI)

    Chintipalli, S.; Frech, R.; Grady, B.

    1996-12-31

    This study examines atomic-level local environments in Poly(ethylene oxide)-zinc bromide+lithium bromide (PEO){sub 20}[(ZnBr{sub 2}){sub 1-x} (LiBr){sub x}] complexes using Raman spectroscopy and x-ray absorption spectroscopy (XAS). Specific features in the Raman spectra were used to show that the zinc bromide species changes from ZnBr{sub 2} to ZnBr{sub 3}{sup -} to ZnBr{sub 4}{sup 2-} when x is varied from 0 to 0.8. XAS showed a similar change in oxygen coordination number from 4 to 0 when x is varied from 0 to 0.8. This study shows that lithium atoms displace zinc atoms from ether oxygen speciation indicating that lithium coordination to ether oxygens is thermodynamically favored. The effect of adding polar plasticizers is also discussed.

  14. Evaluation of Novel Design Strategies for Developing Zinc Finger Nucleases Tools for Treating Human Diseases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bach, Christian; Sherman, William; Pallis, Jani; Patra, Prabir; Bajwa, Hassan

    2014-01-01

    Zinc finger nucleases (ZFNs) are associated with cell death and apoptosis by binding at countless undesired locations. This cytotoxicity is associated with the binding ability of engineered zinc finger domains to bind dissimilar DNA sequences with high affinity. In general, binding preferences of transcription factors are associated with significant degenerated diversity and complexity which convolutes the design and engineering of precise DNA binding domains. Evolutionary success of natural zinc finger proteins, however, evinces that nature created specific evolutionary traits and strategies, such as modularity and rank-specific recognition to cope with binding complexity that are critical for creating clinical viable toolsmore » to precisely modify the human genome. Our findings indicate preservation of general modularity and significant alteration of the rank-specific binding preferences of the three-finger binding domain of transcription factor SP1 when exchanging amino acids in the 2nd finger.« less

  15. Raman and far ir spectroscopic study of quaternary ammonium polybromide fused salt phases for zinc bromine circulating electrolyte batteries

    SciTech Connect (OSTI)

    Larrabee, J.A.; Graf, K.R.; Grimes, P.G.

    1985-01-01

    The circulating electrolyte zinc bromine battery is an attractive advanced battery system. The electrolyte is a solution of zinc bromide, quaternary ammonium bromides for bromine complexation and added salts to enhance properties. Laser Raman spectroscopy and far infrared spectroscopy were used to characterize the liquid quaternary ammonium polybromide fused salt phases.

  16. Estimated safe zinc and copper levels for chinook salmon, Oncorhynchus tshawytscha, in the upper Sacremento River, California

    SciTech Connect (OSTI)

    Finlayson, B.J.; Verrue, K.M.

    1980-04-01

    Experiments to determine the tolerance levels of chinook salmon, Oncorhynchus tshawytscha, to copper and zinc from acid wastes in a tributary to the Sacremento River are described. Copper-zinc ratios in the acid mine waste in Spring Creek varied between 1:2 and 1:12, with pH ranging from 6.6 to 7.4.

  17. Performance of Nafion® N115, Nafion® NR-212, and Nafion® NR-211 in a 1 kW Class All Vanadium Mixed Acid Redox Flow Battery

    SciTech Connect (OSTI)

    Reed, David M.; Thomsen, Edwin C.; Wang, Wei; Nie, Zimin; Li, Bin; Wei, Xiaoliang; Koeppel, Brian J.; Sprenkle, Vincent L.

    2015-07-01

    Three Nafion membranes of similar composition but different thicknesses were operated in a 3-cell 1kW class all vanadium mixed acid redox flow battery. The influence of current density on the charge/discharge characteristics, coulombic and energy efficiency, capacity fade, operating temperature and pressure drop in the flow circuit will be discussed and correlated to the Nafion membrane thickness. Material costs associated with the Nafion membranes, ease of handling the membranes, and performance impacts will also be discussed.

  18. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1993-10-19

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 [mu]m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO[sub 3]; and then indurating it at 800 to 900 C for a time sufficient to produce attrition-resistant granules.

  19. LOW TEMPERATURE VOC COMBUSTION OVER MANGANESE, COBALT AND ZINC ALPO4 MOLECULAR SIEVES

    SciTech Connect (OSTI)

    Rosemarie Szostak

    2003-03-06

    The objective of this project was to prepare microporous aluminophosphates containing magnesium, manganese, cobalt and zinc (MeAPOs) and to evaluate their performance as oxidation catalysts for the removal of low levels of volatile organic compounds (VOCs) from gas streams. The tasks to be accomplished were as follows: (1) To develop reliable synthesis methods for metal aluminophosphates containing manganese, cobalt and zinc in their framework; (2) To characterize these materials for crystallinity, phase purity, the location and nature of the incorporated metal in the framework; and (3) To evaluate the materials for their catalytic activities in the oxidation of volatile organic environmental pollutants.

  20. Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Authors: Deng, Z., Schulz, O., Lin, S., Ding, B., Liu, X., Wei, X., Ros, R., Liu, Y., Yan, H., and Francis, M. Title: Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Source: Journal of the American

  1. Humectants To Augment Current From Metallized Zinc Cathodic Protection Systems on Concrete

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino Jr., Bernard S.; Cramer, Stephen D.; Russell, James H. Russell; Bullard, Sophie J.; Collins, W. Keith; Bennett, Jack E.; Soltesz, Steven M.; Laylor, H. Martin

    2002-12-01

    Cathodic protection (CP) systems using thermal-sprayed zinc anodes are employed to mitigate the corrosion process in reinforced concrete structures. However, the performance of the anodes is improved by moisture at the anode-concrete interface. Research was conducted to investigate the effect of hydrophilic chemical additives, humectants, on the electrical performance and service life of zinc anodes. Lithium bromide and lithium nitrate were identified as feasible humectants with lithium bromide performing better under galvanic CP and lithium nitrate performing better under impressed current CP. Both humectants improved the electrical operating characteristics of the anode and increased the service life by up to three years.

  2. Different properties of aluminum doped zinc oxide nanostructured thin films prepared by radio frequency magnetron sputtering

    SciTech Connect (OSTI)

    Bidmeshkipour, Samina Shahtahmasebi, Nasser

    2013-06-15

    Aluminium doped zinc oxide (AZO) nanostructured thin films are prepared by radio frequency magnetron sputtering on glass substrate using specifically designed ZnO target containing different amount of Al{sub 2}O{sub 3} powder as the Al doping source. The optical properties of the aluminium doped zinc oxide films are investigated. The topography of the deposited films were investigated by Atomic Force Microscopy. Variation of the refractive index by annealing temperature are considered and it is seen that the refractive index increases by increasing the annealing temperature.

  3. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, Raghubir P.; Gangwal, Santosh K.; Jain, Suresh C.

    1993-01-01

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

  4. Total Supplemental Supply of Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Supplemental Supply Synthetic Propane-Air Refinery Gas Biomass Other Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History U.S. 64,575 60,088 61,366 54,650 59,528 58,555 1980-2015 Alabama 0 0 0 0 0 1967-2014 Alaska 0 0 0 0 0 2004-2014 Arizona 0 0 0 0 0 1967-2014 Arkansas 0 0 0 0 0 1967-2014 Colorado 5,148 4,268 4,412 4,077 4,120

  5. Total Ore Processing Integration and Management

    SciTech Connect (OSTI)

    Leslie Gertsch; Richard Gertsch

    2006-01-30

    This report outlines the technical progress achieved for project DE-FC26-03NT41785 (Total Ore Processing Integration and Management) during the period 01 July through 30 September of 2005. This ninth quarterly report discusses the activities of the project team during the period 1 July through 30 September 2005. Richard Gertsch's unexpected death due to natural causes while in Minnesota to work on this project has temporarily slowed progress. Statistical analysis of the Minntac Mine data set for late 2004 is continuing. Preliminary results raised several questions that could be amenable to further study. Detailed geotechnical characterization is being applied to improve the predictability of mill and agglomerator performance at Hibtac Mine.

  6. State Residential Commercial Industrial Transportation Total

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales (Megawatthours) (Data from forms EIA-861- schedules 4A, 4B, 4D, EIA-861S and EIA-861U) State Residential Commercial Industrial Transportation Total New England 47,211,525 53,107,038 19,107,433 557,463 119,983,459 Connecticut 12,777,579 12,893,531 3,514,798 168,552 29,354,460 Maine 4,660,605 3,984,570 3,357,486 0 12,002,661 Massachusetts 20,071,160 26,076,208 7,960,941 360,983 54,469,292 New Hampshire 4,510,487 4,464,530 1,969,064 0 10,944,081 Rhode Island 3,070,347 3,657,679 887,150 27,928

  7. Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate

    DOE Patents [OSTI]

    Sugama, Toshifumi; Kukacka, L.E.; Carciello, N.R.

    1985-11-05

    This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80/sup 0/C. The polyelectrolyte or the precoat is present in about 0.5 to 5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150/sup 0/C to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2 x 10/sup 5/ gave improved ductility modulus effect.

  8. Total least squares for anomalous change detection

    SciTech Connect (OSTI)

    Theiler, James P; Matsekh, Anna M

    2010-01-01

    A family of difference-based anomalous change detection algorithms is derived from a total least squares (TLSQ) framework. This provides an alternative to the well-known chronochrome algorithm, which is derived from ordinary least squares. In both cases, the most anomalous changes are identified with the pixels that exhibit the largest residuals with respect to the regression of the two images against each other. The family of TLSQ-based anomalous change detectors is shown to be equivalent to the subspace RX formulation for straight anomaly detection, but applied to the stacked space. However, this family is not invariant to linear coordinate transforms. On the other hand, whitened TLSQ is coordinate invariant, and furthermore it is shown to be equivalent to the optimized covariance equalization algorithm. What whitened TLSQ offers, in addition to connecting with a common language the derivations of two of the most popular anomalous change detection algorithms - chronochrome and covariance equalization - is a generalization of these algorithms with the potential for better performance.

  9. Apparatus and method for quantitatively evaluating total fissile and total fertile nuclide content in samples

    DOE Patents [OSTI]

    Caldwell, John T.; Kunz, Walter E.; Cates, Michael R.; Franks, Larry A.

    1985-01-01

    Simultaneous photon and neutron interrogation of samples for the quantitative determination of total fissile nuclide and total fertile nuclide material present is made possible by the use of an electron accelerator. Prompt and delayed neutrons produced from resulting induced fissions are counted using a single detection system and allow the resolution of the contributions from each interrogating flux leading in turn to the quantitative determination sought. Detection limits for .sup.239 Pu are estimated to be about 3 mg using prompt fission neutrons and about 6 mg using delayed neutrons.

  10. New York Natural Gas % of Total Residential Deliveries (Percent...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    New York Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries New York Share of Total U.S. ...

  11. New Mexico Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update (EIA)

    New Mexico Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries New Mexico Share of Total U.S. ...

  12. New Jersey Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update (EIA)

    New Jersey Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries New Jersey Share of Total U.S. ...

  13. Minnesota Natural Gas % of Total Residential Deliveries (Percent...

    Gasoline and Diesel Fuel Update (EIA)

    Minnesota Natural Gas % of Total Residential Deliveries (Percent) Decade Year-0 Year-1 ... Share of Total U.S. Natural Gas Residential Deliveries Minnesota Share of Total U.S. ...

  14. Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust

    DOE Patents [OSTI]

    Zaromb, Solomon; Lawson, Daniel B.

    1994-01-01

    A process for recovering zinc/rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10.degree. C., separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream.

  15. Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust

    DOE Patents [OSTI]

    Zaromb, S.; Lawson, D.B.

    1994-02-15

    A process for recovering zinc-rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered by distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10 C, separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream. 1 figure.

  16. Method and apparatus for maintaining the pH in zinc-bromine battery systems

    DOE Patents [OSTI]

    Grimes, Patrick G.

    1985-09-10

    A method and apparatus for maintaining the pH level in a zinc-bromine battery features reacting decomposition hydrogen with bromine in the presence of a catalyst. The catalyst encourages the formation of hydrogen and bromine ions. The decomposition hydrogen is therefore consumed, alloying the pH of the system to remain substantially at a given value.

  17. First Stabilization and Disposal of Radioactive Zinc Bromide at the SRS

    SciTech Connect (OSTI)

    Denny, J.K.

    2003-02-12

    Facilities Disposition Projects (FDP) personnel at Savannah River Site (SRS) implement the Inactive Facility Risk Management Program to drive down risk and costs in SRS inactive facilities. The program includes cost-effective techniques to identify and dispose of hazardous chemicals and radioactive waste from inactive facilities, thereby ensuring adequate protection of the public, workers and the environment. In June 1998, FDP conducted an assessment of the inactive C-Reactor Facility to assure that chemical and radiological hazards had been identified and were being safely managed. The walkdown identified the need to mitigate a significant hazard associated with storing approximately 13,400 gallons of liquid radioactive Zinc Bromide in three aging railcar tankers outside of the facility. No preventive maintenance was being performed on the rusting tankers and a leak could send radioactive Zinc Bromide into an outfall and offsite to the Savannah River. In 2001, DOE-Savannah River (DOE- SR) funded the FDP to eliminate the identified hazard by disposing of the radioactive Zinc Bromide solution and the three contaminated railcar tankers. This paper describes the innovative, cost-effective approaches and technology used to perform the first stabilization and disposal of radioactive Zinc Bromide at SRS.

  18. Zinc ferrite nanoparticle as a magnetic catalyst: Synthesis and dye degradation

    SciTech Connect (OSTI)

    Mahmoodi, Niyaz Mohammad

    2013-10-15

    Graphical abstract: Photocatalytic degradation of Reactive Red 198 and Reactive Red 120 by the synthesized zinc ferrite nanoparticle. - Highlights: Magnetic zinc ferrite nanoparticle was synthesized and characterized. Photocatalytic dye degradation by magnetic nanoparticle was studied. Formate, acetate and oxalate were detected as dominant dye degradation aliphatic intermediates. Nitrate and sulfate ions were detected as mineralization products of dyes. Zinc ferrite nanoparticle was an effective magnetic photocatalyst to degrade dyes. - Abstract: In this paper, magnetic zinc ferrite (ZnFe{sub 2}O{sub 4}) nanoparticle was synthesized and its photocatalytic dye degradation ability from colored wastewater was studied. Reactive Red 198 (RR198) and Reactive Red 120 (RR120) were used as model dyes. The characteristics of ZnFe{sub 2}O{sub 4} were investigated using Fourier transform infrared (FTIR), X-ray diffraction (XRD) and scanning electron microscope (SEM). Photocatalytic dye degradation by ZnFe{sub 2}O{sub 4} was studied by UVvis spectrophotometer and ion chromatography (IC). The effects of ZnFe{sub 2}O{sub 4} dosage, initial dye concentration and salt on dye degradation were evaluated. Formate, acetate and oxalate anions were detected as dominant aliphatic intermediate. Inorganic anions (nitrate and sulfate anions) were detected as dye mineralization products. The results indicated that ZnFe{sub 2}O{sub 4} could be used as a magnetic photocatalyst to degrade dyes from colored wastewater.

  19. Field performance of sprayed zinc anodes in controlling corrosion of steel reinforced concrete

    SciTech Connect (OSTI)

    Tinnea, J.

    1998-12-31

    The deterioration of concrete structures often results from the corrosion of their steel reinforcement. Cathodic protection (CP) is a proven means to stop rebar corrosion. One anode material gaining acceptance in the infrastructure corrosion fight is zinc thermal spray coating. This paper discusses an investigation of such CP systems.

  20. ,"Crude Oil and Petroleum Products Total Stocks Stocks by Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Crude Oil and Petroleum Products Total Stocks Stocks ... AM" "Back to Contents","Data 1: Crude Oil and Petroleum Products Total Stocks Stocks ...

  1. Table 6b. Relative Standard Errors for Total Electricity Consumption...

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Relative Standard Errors for Total Electricity Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using Electricity (thousand) Total...

  2. ARM: GRAMS: data from the total solar broadband radiometer (TBBR...

    Office of Scientific and Technical Information (OSTI)

    solar broadband radiometer (TBBR) Title: ARM: GRAMS: data from the total solar broadband radiometer (TBBR) GRAMS: data from the total solar broadband radiometer (TBBR) Authors: ...

  3. ARM: GRAMS: calibration information for the total solar broadband...

    Office of Scientific and Technical Information (OSTI)

    solar broadband radiometer (TBBR) Title: ARM: GRAMS: calibration information for the total solar broadband radiometer (TBBR) GRAMS: calibration information for the total solar ...

  4. Table 5a. Total District Heat Consumption per Effective Occupied...

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Total District Heat Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using District Heat (thousand) Total District Heat Consumption...

  5. Total Energy Facilities Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Energy Facilities Biomass Facility Jump to: navigation, search Name Total Energy Facilities Biomass Facility Facility Total Energy Facilities Sector Biomass Facility Type...

  6. Webtrends Archives by Fiscal Year — EERE Totals

    Office of Energy Efficiency and Renewable Energy (EERE)

    Historical EERE office total reports include only Webtrends archives by fiscal year. EERE total reports dating after FY11 can be accessed in EERE's Google Analytics account.

  7. New Jersey Natural Gas Total Consumption (Million Cubic Feet...

    Gasoline and Diesel Fuel Update (EIA)

    Total Consumption (Million Cubic Feet) New Jersey Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption New Jersey Natural Gas Consumption by End Use ...

  8. New York Natural Gas Total Consumption (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Total Consumption (Million Cubic Feet) New York Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption New York Natural Gas Consumption by End Use ...

  9. New Mexico Natural Gas Total Consumption (Million Cubic Feet...

    Gasoline and Diesel Fuel Update (EIA)

    Total Consumption (Million Cubic Feet) New Mexico Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption New Mexico Natural Gas Consumption by End Use ...

  10. Estimation of Anisotoropy from Total Cross Section and Optical...

    Office of Scientific and Technical Information (OSTI)

    Conference: Estimation of Anisotoropy from Total Cross Section and Optical Model Citation Details In-Document Search Title: Estimation of Anisotoropy from Total Cross Section and ...

  11. West Virginia Natural Gas Total Consumption (Million Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Total Consumption (Million Cubic Feet) West Virginia Natural Gas Total Consumption ... Referring Pages: Natural Gas Consumption West Virginia Natural Gas Consumption by End Use ...

  12. Virginia Natural Gas Total Consumption (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Total Consumption (Million Cubic Feet) Virginia Natural Gas Total Consumption (Million ... Referring Pages: Natural Gas Consumption Virginia Natural Gas Consumption by End Use ...

  13. NREL: Building America Total Quality Management - 2015 Peer Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NREL: Building America Total Quality Management - 2015 Peer Review NREL: Building America Total Quality Management - 2015 Peer Review Presenter: Stacey Rothgeb, NREL View the ...

  14. ,"Alaska (with Total Offshore) Natural Gas Liquids Lease Condensate...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alaska (with Total Offshore) Natural Gas Liquids Lease Condensate, ... to Contents","Data 1: Alaska (with Total Offshore) Natural Gas Liquids Lease Condensate, ...

  15. ,"Alaska (with Total Offshore) Coalbed Methane Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alaska (with Total Offshore) Coalbed Methane Proved Reserves ... to Contents","Data 1: Alaska (with Total Offshore) Coalbed Methane Proved Reserves ...

  16. ,"Alaska (with Total Offshore) Natural Gas Plant Liquids, Expected...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alaska (with Total Offshore) Natural Gas Plant Liquids, Expected ... to Contents","Data 1: Alaska (with Total Offshore) Natural Gas Plant Liquids, Expected ...

  17. ,"Alaska (with Total Offshore) Shale Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alaska (with Total Offshore) Shale Proved Reserves (Billion Cubic ... to Contents","Data 1: Alaska (with Total Offshore) Shale Proved Reserves (Billion Cubic ...

  18. Federal Offshore -- Gulf of Mexico Natural Gas Total Consumption...

    U.S. Energy Information Administration (EIA) Indexed Site

    -- Gulf of Mexico Natural Gas Total Consumption (Million Cubic Feet) Federal Offshore -- Gulf of Mexico Natural Gas Total Consumption (Million Cubic Feet) Decade Year-0 Year-1 ...

  19. ,"Total District Heat Consumption (trillion Btu)",,,,,"District...

    U.S. Energy Information Administration (EIA) Indexed Site

    Heat Consumption (trillion Btu)",,,,,"District Heat Energy Intensity (thousand Btusquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  20. ,"Total Natural Gas Consumption (trillion Btu)",,,,,"Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (trillion Btu)",,,,,"Natural Gas Energy Intensity (thousand Btusquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...