National Library of Energy BETA

Sample records for vanadium zinc total

  1. Vanadium recycling for fusion reactors

    SciTech Connect (OSTI)

    Dolan, T.J.; Butterworth, G.J.

    1994-04-01

    Very stringent purity specifications must be applied to low activation vanadium alloys, in order to meet recycling goals requiring low residual dose rates after 50--100 years. Methods of vanadium production and purification which might meet these limits are described. Following a suitable cooling period after their use, the vanadium alloy components can be melted in a controlled atmosphere to remove volatile radioisotopes. The aim of the melting and decontamination process will be the achievement of dose rates low enough for ``hands-on`` refabrication of new reactor components from the reclaimed metal. The processes required to permit hands-on recycling appear to be technically feasible, and demonstration experiments are recommended. Background information relevant to the use of vanadium alloys in fusion reactors, including health hazards, resources, and economics, is provided.

  2. Zinc content of selected tissues and taste perception in rats fed zinc deficient and zinc adequate rations

    SciTech Connect (OSTI)

    Boeckner, L.S.; Kies, C.

    1986-03-05

    The objective of the study was to determine the effects of feeding zinc sufficient and zinc deficient rations on taste sensitivity and zinc contents of selected organs in rats. The 36 Sprague-Dawley male weanling rats were divided into 2 groups and fed zinc deficient or zinc adequate rations. The animals were subjected to 4 trial periods in which a choice of deionized distilled water or a solution of quinine sulfate at 1.28 x 10/sup -6/ was given. A randomized schedule for rat sacrifice was used. No differences were found between zinc deficient and zinc adequate rats in taste preference aversion scores for quinine sulfate in the first three trial periods; however, in the last trial period rats in the zinc sufficient group drank somewhat less water containing quinine sulfate as a percentage of total water consumption than did rats fed the zinc deficient ration. Significantly higher zinc contents of kidney, brain and parotid salivary glands were seen in zinc adequate rats compared to zinc deficient rats at the end of the study. However, liver and tongue zinc levels were lower for both groups at the close of the study than were those of rats sacrificed at the beginning of the study.

  3. Chemistry of vanadium and zinc antiviral tetra-aza macrocycles 

    E-Print Network [OSTI]

    Ross, Allison

    2009-01-01

    Some bicyclam compounds are highly active as HIV inhibitor agents with high selectivity for the CXCR4 coreceptor, an important protein receptor for the human immunodeficiency virus. One particular bicyclam, AMD3100 ...

  4. Practical Thermodynamic Quantities for Aqueous Vanadium- and...

    Office of Scientific and Technical Information (OSTI)

    Practical Thermodynamic Quantities for Aqueous Vanadium- and Iron-Based Flow Batteries. Citation Details In-Document Search Title: Practical Thermodynamic Quantities for Aqueous...

  5. The work presented in this thesis studied the synthesis and characterization of a totally solid state polymer electrolyte that is applicable to solid state zinc-air batteries. An

    E-Print Network [OSTI]

    state polymer electrolyte that is applicable to solid state zinc-air batteries. An overview of zinc-air batteries is briefly covered followed by a detailed discussion of the chemical synthesis. The majority that must be known and optimized for the successful design of a zinc-air battery cell. This thesis

  6. Methods for making lithium vanadium oxide electrode materials

    DOE Patents [OSTI]

    Schutts, Scott M. (Menomonie, WI); Kinney, Robert J. (Woodbury, MN)

    2000-01-01

    A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

  7. Electrochemical Characterization of Vanadium Oxide Nanostructured Electrode

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    microstructures called aerogels in the case of supercritical or freeze-drying and ambigels in the case of solvent for intercalated ions.7 When cycled between 4.0 and 1.5 V, vanadium oxide aerogels achieved capaci- ties of 410 mAh/g at C/40.6 Baudrin et al. have used the vanadium oxide aerogel structure to access a metastable phase

  8. Zinc electrode with cement additive

    DOE Patents [OSTI]

    Charkey, Allen (Brookfield, CT)

    1982-06-01

    A zinc electrode having a cement additive, preferably, Portland Cement, distributed in the zinc active material.

  9. Production of zinc pellets

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    1996-01-01

    Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries.

  10. Production of zinc pellets

    DOE Patents [OSTI]

    Cooper, J.F.

    1996-11-26

    Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries. 6 figs.

  11. Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for Vanadium Redox Flow Battery

    SciTech Connect (OSTI)

    Vijayakumar, M.; Burton, Sarah D.; Huang, Cheng; Li, Liyu; Yang, Zhenguo; Graff, Gordon L.; Liu, Jun; Hu, Jian Z.; Skyllas-Kazacos, Maria

    2010-11-15

    The vanadium (IV) electrolyte solutions with various vanadium concentrations are studied by variable temperature 1H and 17O Nuclear Magnetic Resonance (NMR) spectroscopy. The structure and kinetics of vanadium (IV) species in the electrolyte solutions are explored with respect to vanadium concentration and temperature. It was found that the vanadium (IV) species exist as hydrated vanadyl ion, i.e. [VO(H2O)5]2+ forming an octahedral coordination with vanadyl oxygen in the axial position and the remaining positions occupied by water molecules. This hydrated vanadyl ion structure is stable in vanadium concentrations up to 3M and in the temperature range of 240 to 340 K. The sulfate anions in the electrolyte solutions are found to be weekly bound to this hydrated vanadyl ion and occupies its second coordination sphere. The possible effects of these sulfate anions in proton and water exchange between vanadyl ion and solvent molecules are discussed based on 1H and 17O NMR results.

  12. Modified lithium vanadium oxide electrode materials products and methods

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Kahaian, Arthur J. (Chicago, IL); Visser, Donald R. (Naperville, IL); Dees, Dennis W. (Downers Grove, IL); Benedek, Roy (Western Springs, IL)

    1999-12-21

    A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

  13. Zinc oxyfluoride transparent conductor

    DOE Patents [OSTI]

    Gordon, Roy G. (Cambridge, MA)

    1991-02-05

    Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

  14. Effect of neutron irradiation on vanadium alloys

    SciTech Connect (OSTI)

    Braski, D.N.

    1986-01-01

    Neutron-irradiated vanadium alloys were evaluated for their susceptibility to irradiation hardening, helium embrittlement, swelling, and residual radioactivity, and the results were compared with those for the austenitic and ferritic stainless steels. The VANSTAR-7 and V-15Cr-5Ti alloys showed the greatest hardening between 400 and 600/sup 0/C while V-3Ti-1Si and V-20Ti had lower values that were comparable to those of ferritic steels. The V-15Cr-5Ti and VANSTAR-7 alloys were susceptible to helium embrittlement caused by the combination of weakened grain boundaries and irradiation-hardened grain matrices. Specimen fractures were entirely intergranular in the most severe instances of embrittlement. The V-3Ti-1Si and V-20Ti alloys were more resistant to helium embrittlement. Except for VANSTAR-7 irradiated to 40 dpa at 520/sup 0/C, all of the vanadium alloys exhibited low swelling that was similar to the ferritic steels. Swelling was greater in specimens that were preimplanted with helium using the tritium trick. The vanadium alloys clearly exhibit lower residual radioactivity after irradiation than the ferrous alloys.

  15. Improved zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21

    The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

  16. Vanadium-pumped titanium x-ray laser

    DOE Patents [OSTI]

    Nilsen, Joseph (Livermore, CA)

    1992-01-01

    A resonantly photo-pumped x-ray laser (10) is formed of a vanadium (12) and titanium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state neon-like titanium ions (34) are resonantly photo-pumped by line emission from fluorine-like vanadium ions (32).

  17. Vanadium-pumped titanium x-ray laser

    DOE Patents [OSTI]

    Nilsen, J.

    1992-05-26

    A resonantly photo-pumped x-ray laser is formed of a vanadium and titanium foil combination that is driven by two beams of intense line focused optical laser radiation. Ground state neon-like titanium ions are resonantly photo-pumped by line emission from fluorine-like vanadium ions. 4 figs.

  18. Accepted Manuscript Title: Dramatic Performance Gains in Vanadium Redox Flow

    E-Print Network [OSTI]

    Mench, Matthew M.

    ) are a potentially enabling technology for intermittent, renewable energy sources such as wind and solar power [1 contributors to the installed cost of a VRB are the cost of the vanadium, the membranes used and everything else in similar proportion [10]. The vanadium cost is fixed by the required capacity and the purity

  19. Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s

    SciTech Connect (OSTI)

    Fujimoto, Cy H.; Kim, Soowhan; Stains, Ronald; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

    2012-07-01

    Sulfonated Diels Alder poly(phenylene) (SDAPP) was examined for vanadium redox flow battery (VRFB) use. The ion exchange capacity (IEC) was varied from 1.4, 1.6 and 2.0 meq/g in order to tune the proton conductivity and vanadium permeability. Coulombic efficiencies between 92 to 99% were observed, depending on IEC (lower IEC, higher coulombic efficiencies). In all cases the SDAPP displayed comparable energy efficiencies (88 - 90%) to Nafion 117 (88%) at 50mA/cm2. Membrane durability also was dependent on IEC; SDAPP with the highest IEC lasted slightly over 50 cycles while SDAPP with the lowest IEC lasted over 400 cycles and testing was discontinued only due to time constraints. Accelerated vanadium lifetime studies were initialed with SDAPP, by soaking films in a 0.1 M V5+ and 5.0 M total SO4-2 solution. The rate of degradation was also proportional with IEC; the 2 meq/g sample dissolved within 376 hours, the 1.6 meq/g sample dissolved after 860 hours, while the 1.4 meq/g sample broke apart after 1527 hours.

  20. Anisotropic reactive ion etching of vanadium dioxide 

    E-Print Network [OSTI]

    Radle, Byron K

    1990-01-01

    Facility for Submicron Structures, Cornell University, Ithaca, New York [7]. In these studies thin film VO2 was etched with a SF6/CO2 chemistry. SF6 chemistry was chosen because volatile vanadium fluorides can be formed easily. CO2 supplied the carbon... (Silicon Doped GaAs) Semi-Insulating GaAs Metal (AuGe, Ni, Au) Fig. 19. This is a step by step drawn representation of the fabrication procedure. 53 1. Pattern Photo Resist for Optical Stack etch mask. P Etched VOz in CFe plasma. 3. Etched Alz...

  1. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    1997-01-01

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

  2. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, T.

    1997-02-18

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

  3. Method to remove uranium/vanadium contamination from groundwater

    DOE Patents [OSTI]

    Metzler, Donald R. (DeBeque, CO); Morrison, Stanley (Grand Junction, CO)

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  4. Electrical and optical properties of vanadium tellurite glasses 

    E-Print Network [OSTI]

    Flynn, Brian William

    1977-01-01

    Glasses in the system v?o?-Te0? were prepared at intervals throughout the glass-forming composition range. The vanadium valence state was varied for each composition by the addition of elemental tellurium to reduce the ...

  5. Method to Remove Uranium/Vanadium Contamination from Groundwater

    DOE Patents [OSTI]

    Metzler, Donald R.; Morrison Stanley

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  6. Zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, Jr., Philip N. (Kensington, CA)

    1989-01-01

    An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

  7. Plasma enhanced chemical vapor deposition (PECVD) method of forming vanadium oxide films and vanadium oxide thin-films prepared thereby

    DOE Patents [OSTI]

    Zhang, Ji-Guang (Golden, CO); Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO); Turner, John A. (Littleton, CO); Liu, Ping (Lakewood, CO)

    2000-01-01

    A method is disclosed of forming a vanadium oxide film on a substrate utilizing plasma enhanced chemical vapor deposition. The method includes positioning a substrate within a plasma reaction chamber and then forming a precursor gas comprised of a vanadium-containing chloride gas in an inert carrier gas. This precursor gas is then mixed with selected amounts of hydrogen and oxygen and directed into the reaction chamber. The amounts of precursor gas, oxygen and hydrogen are selected to optimize the final properties of the vanadium oxide film An rf plasma is generated within the reaction chamber to chemically react the precursor gas with the hydrogen and the oxygen to cause deposition of a vanadium oxide film on the substrate while the chamber deposition pressure is maintained at about one torr or less. Finally, the byproduct gases are removed from the plasma reaction chamber.

  8. Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries

    E-Print Network [OSTI]

    Davis, Robin M. (Robin Manes)

    2005-01-01

    Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

  9. In-situ Investigation of Vanadium Ion Transport in Redox Flow Battery

    SciTech Connect (OSTI)

    Luo, Qingtao; Li, Liyu; Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Chen, Baowei; Yang, Zhenguo

    2012-06-27

    We will show a new method to differentiate the vanadium transport from concentration gradient and that from electric field. Flow batteries with vanadium and iron redox couples as the electro-active species were employed to investigate the transport behavior of vanadium ions in the presence of electric field. It was shown that electric field accelerated the positive-to-negative and reduced the negative-to-positive vanadium ions transport in charge process and affected the vanadium ions transport in an opposite way in discharge process. In addition, a method was designed to differentiate the concentration gradient-driven vanadium ions diffusion and electric field-driven vanadium ions migration. Simplified mathematical model was established to simulate the vanadium ions transport in real charge-discharge operation of flow battery. The concentration gradient diffusion coefficients and electric-migration coefficients of V2+, V3+, VO2+, and VO2+ across Nafion membrane were obtained by fitting the experimental data.

  10. Imaging mobile zinc in biology

    E-Print Network [OSTI]

    Tomat, Elisa

    Trafficking and regulation of mobile zinc pools influence cellular functions and pathological conditions in multiple organs, including brain, pancreas, and prostate. The quest for a dynamic description of zinc distribution ...

  11. Vanadium redox-flow batteries Installation at Ris for characterisation measurements

    E-Print Network [OSTI]

    Vanadium redox-flow batteries ­ Installation at Risř for characterisation measurements Henrik-flow batteries hold a great promise for storing electric energy on a large scale. They have many attractive of the project is to characterise a vanadium battery as a system component. The vanadium battery

  12. Zinc titanate sorbents

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1998-02-03

    The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about 750 to about 950 C. The dry blend is formed by mixing between about 0.5 to about 2 parts zinc oxide having a median particle size of less than about 0.5 microns, and about 1 part titanium dioxide having a median particle size of less than about 1 micron. The slurry contains substantially no free silica and may be prepared by the process including (1) preparing an aqueous solution of organic binder, (2) adding the dry blend to the aqueous solution of organic binder, and (3) adding the inorganic binder to the solution of organic binder, and blend. Additional reagents, such as a surfactant, may also be incorporated into the sorbent material. The present invention also provides a process for desulfurizing a gaseous stream. The process includes passing a gaseous stream through a reactor containing an attrition resistant zinc titanate sorbent material of the present invention.

  13. Zinc titanate sorbents

    DOE Patents [OSTI]

    Gupta, Raghubir P. (Durham, NC); Gangwal, Santosh K. (Durham, NC); Jain, Suresh C. (Germantown, MD)

    1998-01-01

    The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about 750.degree. C. to about 950.degree. C. The dry blend is formed by mixing between about 0.5 to about 2 parts zinc oxide having a median particle size of less than about 0.5 .mu., and about 1 part titanium dioxide having a median particle size of less than about 1 .mu.. The slurry contains substantially no free silica and may be prepared by the process including (1) preparing an aqueous solution of organic binder, (2) adding the dry blend to the aqueous solution of organic binder, and (3) adding the inorganic binder to the solution of organic binder, and blend. Additional reagents, such as a surfactant, may also be incorporated into the sorbent material. The present invention also provides a process for desulfurizing a gaseous stream. The process includes passing a gaseous stream through a reactor containing an attrition resistant zinc titanate sorbent material of the present invention.

  14. Zinc deposition in acid electrolytes

    SciTech Connect (OSTI)

    McBreen, J.; Gannon, E.

    1981-01-01

    In the past decade, two aqueous zinc/halogen batteries, the zinc/chlorine, and the zinc/bromine systems, have been considered for load-leveling and vehicular applications. Even though considerable progress has been made in engineering these batteries, several problems related to the zinc electrode have yet to be solved. These are related to the growth of dendritic zinc and a maldistribution of the zinc deposit that can occur during cycling. Both problems are exacerbated by recharge of the battery after partial discharge of the zinc deposit. A survey of the literature indicates that a more desireable zinc morphology can be achieved by use of inorganic additives, fluorinated surfactants, and A-C modulation of the charging current. In this investigation, the deposition of zinc from zinc bromide and zinc chloride electrolytes was investigated under conditions that precluded dendrite growth. The techniques used were cyclic voltammetry, the potential step technique and scanning electron microscopy. The variables investigated were the substrate (zinc and dense graphite), electrolyte pH, inorganic additives (Pb/sup + +/ and Bi/sup 3 +/) and A-V modulation of the charging potential by superimposed square waves.

  15. Photovoltaic cells employing zinc phosphide

    DOE Patents [OSTI]

    Barnett, Allen M. (Newark, DE); Catalano, Anthony W. (Wilmington, DE); Dalal, Vikram L. (Newark, DE); Masi, James V. (Wilbraham, MA); Meakin, John D. (Newark, DE); Hall, Robert B. (Newark, DE)

    1984-01-01

    A photovoltaic cell having a zinc phosphide absorber. The zinc phosphide can be a single or multiple crystal slice or a thin polycrystalline film. The cell can be a Schottky barrier, heterojunction or homojunction device. Methods for synthesizing and crystallizing zinc phosphide are disclosed as well as a method for forming thin films.

  16. Membrane Development for Vanadium Redox Flow Batteries

    SciTech Connect (OSTI)

    Schwenzer, Birgit; Zhang, Jianlu; Kim, Soowhan; Li, Liyu; Liu, Jun; Yang, Zhenguo

    2011-10-17

    Large-scale energy storage has become a main bottleneck for increasing the percentage of renewable energy in our electricity grids. Redox flow batteries are considered to be among the best options for electricity storage in the megawatt range, and large demonstration systems have already been installed. Although the full technological potential of these systems has not been reached yet, currently the main problem hindering more widespread commercialization is the high cost of redox flow batteries. Nafion{reg_sign} as the preferred membrane material is responsible for {approx}11% of the overall cost of a 1 MW/8 MWh system. Therefore in recent years two main membrane-related research threads have emerged: (a) chemical and physical modification of Nafion membranes to optimize their properties with regard to vanadium redox flow battery (VRFB) application; and (b) replacement of the Nafion membranes with different, less expensive materials. This review summarizes the underlying basic science issues associated with membrane use in VRFBs and presents an overview of membrane-related research approaches aimed at improving the efficiency of VRFBs and making the technology cost-competitive. Promising research strategies and materials are identified and suggestions are provided on how materials issues could be overcome.

  17. Zinc sulfide liquefaction catalyst

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA)

    1984-01-01

    A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

  18. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  19. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  20. HYPERFINE STRUCTURE CONSTANTS OF ENERGETICALLY HIGH-LYING LEVELS OF ODD PARITY OF ATOMIC VANADIUM

    SciTech Connect (OSTI)

    Güzelçimen, F.; Yap?c?, B.; Demir, G.; Er, A.; Öztürk, I. K.; Ba?ar, Gö.; Kröger, S.; Tamanis, M.; Ferber, R.; Docenko, D.; Ba?ar, Gü. E-mail: sophie.kroeger@htw-berlin.de

    2014-09-01

    High-resolution Fourier transform spectra of a vanadium-argon plasma have been recorded in the wavelength range of 365-670 nm (15,000-27,400 cm{sup –1}). Optical bandpass filters were used in the experimental setup to enhance the sensitivity of the Fourier transform spectrometer. In total, 138 atomic vanadium spectral lines showing resolved or partially resolved hyperfine structure have been analyzed to determine the magnetic dipole hyperfine structure constants A of the involved energy levels. One of the investigated lines has not been previously classified. As a result, the magnetic dipole hyperfine structure constants A for 90 energy levels are presented: 35 of them belong to the configuration 3d {sup 3}4s4p and 55 to the configuration 3d {sup 4}4p. Of these 90 constants, 67 have been determined for the first time, with 23 corresponding to the configuration 3d {sup 3}4s4p and 44 to 3d {sup 4}4p.

  1. VACUUM PUMPING STUDY OF TITANIUM-ZIRCONIUM-VANADIUM THIN FILMS*

    E-Print Network [OSTI]

    ERL 03-8 VACUUM PUMPING STUDY OF TITANIUM-ZIRCONIUM-VANADIUM THIN FILMS* Yulin Li# and Simon Ho, LEPP, Cornell University, Ithaca, NY 14853, USA Abstract* Vacuum pumping via non-evaporable getter (NEG) thin film deposited directly onto the interior of a vacuum chamber is a novel way to achieve extreme

  2. Synthesis and Enhanced Intercalation Properties of Nanostructured Vanadium Oxides

    E-Print Network [OSTI]

    Cao, Guozhong

    intercalation properties of nanostructured vanadium oxides for energy storage as well as other applications-volume, and environment friendly energy storage/conversion devices are developed, and nanomaterials are attracting great-18 The nanostructured form of this material has been employed in FETs,19 sensors,20,21 spintronic devices,22

  3. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    1996-12-31

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  4. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analyzed biofilm samples rich in zinc sulfide and dominated by sulfate-reducing bacteria, which were collected from lead-zinc mine waters. The researchers were curious about...

  5. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Extracellular Proteins Promote Zinc Sulfide Aggregation Print Wednesday, 26 September 2007 00:00 Researchers from the ALS,...

  6. Spectroscopic Investigations of the Fouling Process on Nafion Membranes in Vanadium Redox Flow Batteries

    SciTech Connect (OSTI)

    Vijayakumar, M.; Sivakumar, Bhuvaneswari M.; Nachimuthu, Ponnusamy; Schwenzer, Birgit; Kim, Soowhan; Yang, Zhenguo; Liu, Jun; Graff, Gordon L.; Thevuthasan, Suntharampillai; Hu, Jian Z.

    2011-01-01

    The Nafion-117 membrane used in vanadium redox flow battery (VRFB) is analyzed by X-ray photoelectron spectroscopy (XPS) and nuclear magnetic resonance (NMR) spectroscopy. The XPS study reveals the chemical identity and environment of vanadium cations accumulated at the surface due to their low diffusivity. On the other hand, the 17O NMR spectrum explores the diffused vanadium cation from the bulk part of Nafion and shows the chemical bonding of cation and the host membrane. The 19F NMR shows the basic Nafion structure is not altered due to the presence of diffused vanadium cation. Based on these spectroscopic studies, the chemical environment of diffused vanadium cation in the Nafion membrane is discussed. This study also shed light into the possible cause for the high diffusivity of certain vanadium cations inside the Nafion membranes.

  7. Relating the biogeochemistries of zinc, cobalt, and phosphorus to phytoplankton activities in the sea

    E-Print Network [OSTI]

    Wisniewski, Rachel J. (Rachel Jane), 1978-

    2006-01-01

    This thesis explores the potential of zinc, cobalt, and phosphorus to influence primary production in the subarctic North Pacific, the Bering Sea, and the North Atlantic Ocean. In the North Pacific and Bering Sea, total ...

  8. Aqueous Zinc Bromide Waste Solidification

    SciTech Connect (OSTI)

    Langton, C.A.

    2002-07-23

    The goal of this study was to select one or more commercially available aqueous sorbents to solidify the zinc bromide solution stored in C-Area, identify the polymer to zinc bromide solution ratio (waste loading) for the selected sorbents, and identify processing issues that require further testing in pilot-scale testing.

  9. Zinc-bromine cell design

    SciTech Connect (OSTI)

    Bellows, R.

    1983-11-30

    A set of slides is reproduced which illustrates the design of a zinc-bromine circulating battery. Low-cost manufacturing techniques and scale-up rationale are outlined, and design parameters are listed. Also outlined is a computer model of the zinc-bromine battery. (LEW)

  10. Insulator-to-Metal Transition of Vanadium Dioxide | U.S. DOE...

    Office of Science (SC) Website

    Insulator-to-Metal Transition of Vanadium Dioxide Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities Science Highlights Benefits of ASCR Funding...

  11. Synthesis, characterization, and thermodynamic parameters of vanadium dioxide

    SciTech Connect (OSTI)

    Qi Ji [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China); Department of Chemical Engineering, Dalian Life Science College, Dalian Nationalities University, 18 Laohe West Road, Dalian 116600 (China); Ning Guiling [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Lin Yuan [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China)

    2008-08-04

    A novel process was developed for synthesizing pure thermochromic vanadium dioxide (VO{sub 2}) by thermal reduction of vanadium pentoxide (V{sub 2}O{sub 5}) in ammonia gas. The process of thermal reduction of V{sub 2}O{sub 5} was optimized by both experiments and modeling of thermodynamic parameters. The product VO{sub 2} was characterized by means of X-ray diffraction (XRD), X-ray photoelectron spectrometry (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TG), and differential scanning calorimetry (DSC). The experimental results indicated that pure thermochromic VO{sub 2} crystal particles were successfully synthesized. The phase transition temperature of the VO{sub 2} is approximately 342.6 K and the enthalpy of phase transition is 44.90 J/g.

  12. Present Status of Vanadium Alloys for Fusion Applications

    SciTech Connect (OSTI)

    Muroga, Takeo; Chen, J. M.; Chernov, V. M.; Kurtz, Richard J.; Le Flem, M.

    2014-12-01

    Vanadium alloys are advanced options for low activation structural materials. After more than two decades of research, V-4Cr-4Ti has been emerged as the leading candidate, and technological progress has been made in reducing the number of critical issues for application of vanadium alloys to fusion reactors. Notable progress has been made in fabricating alloy products and weld joints without degradation of properties. Various efforts are also being made to improve high temperature strength and creep-rupture resistance, low temperature ductility after irradiation, and corrosion resistance in blanket conditions. Future research should focus on clarifying remaining uncertainty in the operating temperature window of V-4Cr-4Ti for application to near to middle term fusion blanket systems, and on further exploration of advanced materials for improved performance for longer-term fusion reactor systems.

  13. High performance electrodes in vanadium redox flow batteries through oxygen-enriched thermal activation

    E-Print Network [OSTI]

    Mench, Matthew M.

    National Laboratory, Oak Ridge, TN 37831, USA h i g h l i g h t s Thermal activation of carbon paper: Vanadium redox flow battery Carbon paper Kinetics Surface area Thermal activation Electrode a b s t r a cHigh performance electrodes in vanadium redox flow batteries through oxygen-enriched thermal

  14. Short communication All-vanadium redox photoelectrochemical cell: An approach to store

    E-Print Network [OSTI]

    Liu, Fuqiang

    Short communication All-vanadium redox photoelectrochemical cell: An approach to store solar energy Zi Wei, Dong Liu, Chiajen Hsu, Fuqiang Liu Department of Materials Science and Engineering 24 May 2014 Keywords: Photoelectrochemical reaction Solar energy storage Vanadium redox Solar energy

  15. STUDIES ON ZINC NODULES ELECTRODEPOSITED FROM ACID ELECTROLYTES

    E-Print Network [OSTI]

    Anderson, R.

    2011-01-01

    LBL Workshop on the Electrochemistry of Zinc/Halogen Bat-and E. Cairns, "The Electrochemistry Zinc Electrode," inon the Proceed- of Electrochemistry Zinc/Halogen Batteries,

  16. Kinetic model of whole-body vanadium metabolism: studies in sheep

    SciTech Connect (OSTI)

    Patterson, B.W.; Hansard, S.L. II; Ammerman, C.B.; Henry, P.R.; Zech, L.A.; Fisher, W.R.

    1986-08-01

    A compartmental model for vanadium metabolism in sheep has been proposed. The model is consistent with data obtained from sheep fed a control diet (2.6 ppm vanadium) containing 0 or 200 ppm supplemental vanadium. Sheep were administered UYV dioxovanadium either orally or intravenously. Blood feces, and urine radioactivity were monitored for 6 days postdosing. Several new insights regarding vanadium metabolism are suggested and tested against the data using the model. Some of these include 1) significant absorption of UYV occurs from the upper gastrointestinal tract; 2) an in vivo process is necessary in order for UYV dioxovanadium to be converted into a more biologically reactive species; 3) at steady state the upper and lower gastrointestinal tracts contain at least 10- and 100-fold more mass of vanadium, respectively, than does blood. No statistically significant differences in transport rate constants were found between animals receiving 0 and 200 ppm supplemental dietary vanadium. The availability of a model will enable the refinement of future studies regarding vanadium metabolism in the ruminant.

  17. Nitridation under ammonia of high surface area vanadium aerogels

    SciTech Connect (OSTI)

    Merdrignac-Conanec, Odile [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)]. E-mail: odile.merdrignac@univ-rennes1.fr; El Badraoui, Khadija [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France); L'Haridon, Paul [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)

    2005-01-15

    Vanadium pentoxide gels have been obtained from decavanadic acid prepared by ion exchange on a resin from ammonium metavanadate solution. The progressive removal of water by solvent exchange in supercritical conditions led to the formation of high surface area V{sub 2}O{sub 5}, 1.6H{sub 2}O aerogels. Heat treatment under ammonia has been performed on these aerogels in the 450-900 deg. C temperature range. The oxide precursors and oxynitrides have been characterized by XRD, SEM, TGA, BET. Nitridation leads to divided oxynitride powders in which the fibrous structure of the aerogel is maintained. The use of both very low heating rates and high surface area aerogel precursors allows a higher rate and a lower threshold of nitridation than those reported in previous works. By adjusting the nitridation temperature, it has been possible to prepare oxynitrides with various nitrogen enrichment and vanadium valency states. Whatever the V(O,N) composition, the oxidation of the oxynitrides in air starts between 250 and 300 deg. C. This determines their potential use as chemical gas sensors at a maximum working temperature of 250 deg. C.

  18. Characterisation of endogenous KRAB zinc finger proteins 

    E-Print Network [OSTI]

    Crawford, Catherine

    2009-01-01

    The Krüppel-associated box (KRAB) zinc finger protein (ZFP) genes comprise one of the largest gene families in the mammalian genome, encoding transcription factors with an N-terminal KRAB domain and C-terminal zinc ...

  19. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  20. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  1. Total Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8,Product: Total Crude

  2. Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

  3. STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES

    E-Print Network [OSTI]

    Mc Vay, L.

    2011-01-01

    A. Attia, Development of zinc bromide batteries stationaryfrom zinc chloride and zinc bromide electrolytes, JES 130 (is reduced to bromide from the complex. The zinc that was

  4. Molecular based magnets comprising vanadium tetracyanoethylene complexes for shielding electromagnetic fields

    DOE Patents [OSTI]

    Epstein, A.J.; Morin, B.G.

    1998-10-13

    The invention presents a vanadium tetracyanoethylene solvent complex for electromagnetic field shielding, and a method for blocking low frequency and magnetic fields using these vanadium tetracyanoethylene compositions. The compositions of the invention can be produced at ambient temperature and are light weight, low density and flexible. The materials of the present invention are useful as magnetic shields to block low frequency fields and static fields, and for use in cores in transformers and motors. 21 figs.

  5. Molecular based magnets comprising vanadium tetracyanoethylene complexes for shielding electromagnetic fields

    DOE Patents [OSTI]

    Epstein, Arthur J. (Columbus, OH); Morin, Brian G. (Columbus, OH)

    1998-01-01

    The invention presents a vanadium tetracyanoethylene solvent complex for electromagnetic field shielding, and a method for blocking low frequency and magnetic fields using these vanadium tetracyanoethylene compositions. The compositions of the invention can be produced at ambient temperature and are light weight, low density and flexible. The materials of the present invention are useful as magnetic shields to block low frequency fields and static fields, and for use in cores in transformers and motors.

  6. Elastic properties of vanadium pentoxide aggregates and topological defects

    E-Print Network [OSTI]

    L. V. Elnikova

    2008-11-07

    We study the aqueous solution of vanadium pentoxide by using topology methods. The experiments by Zocher, Kaznacheev, and Dogic exhibited, that in the sol phases of $V_2O_5-H_2O$, the tactoid droplets of $V_2O_5$ can coalesce. In the magnetic field, this effect is associated with a gauge field action, viz. we consider coalescence (in the topologically more convenient term, "junction") of droplets as annihilation of topological defects, concerning with the tactoid geometry. We have shown, that in the magnetic field, the tactoid junction is mainly caused by non-Abelian monopoles (vortons), whereas the Abelian defects almost do not annihilate. Taking into account this annihilation mechanism, the estimations of time-aging of the $V_2O_5-H_2O$ sols may be specified

  7. Development of vanadium redox flow battery for photovoltaic generation system

    SciTech Connect (OSTI)

    Shibata, Akira; Sato, Kanji; Nakajima, Masato

    1994-12-31

    Photovoltaic power generation system (PV) requires a battery for night and rainy day. A redox flow battery has advantage over a lead acid one on this application for the capability of deep discharge and needlessness of equalized charge. The authors have developed the high performance vanadium redox flow battery for this purpose and inexpensive production technology of electrolyte which occupies the majority in the battery cost by chemical reduction from boiler plant by-product. The 2 kW (10 kWh) battery, the minimum unit for practical size battery (50 kW x 50 h), achieved 1.2 kW/cm{sup 2}-electrode area at the 100 mA/cm{sup 2} current density.

  8. Palladium-coated Vanadium-alloy membranes for Hydrogen Separation.

    SciTech Connect (OSTI)

    Paglieri, S. N. (Stephen N.); Pesiri, D. R. (David R.); Dye, R. C. (Robert C.); Birdsell, S. A. (Stephen A.); Snow, R. C. (Ronny C.)

    2005-01-01

    Hydrogen-separating membranes have the potential to generate pure hydrogen from abundant fossil fuel supplies such as coal, for use in fuel cells. Foils of V{sub 0.95}Ti{sub 0.05} and V{sub 0.88}Cu{sub 0.12} (at. %) coated with thin films of Pd or Pd alloy (Pd-Ag) were fabricated and tested for hydrogen permeability and stability during operation at temperatures from 320-450 C. Vanadium-alloy foils were ion-milled and coatings between 50 and 200 nm thick were applied to both sides insitu, via electron beam evaporation PVD. The membranes were completely permselective for hydrogen. Hydrogen flux stability was dependent on palladium coating thickness, with constant flux observed during tests at 350 C, and slow decline observed at 400 C that accelerated at higher temperatures.

  9. Dispenser Printed Zinc Microbattery with an Ionic Liquid Gel Electrolyte

    E-Print Network [OSTI]

    Ho, Christine Chihfan

    2010-01-01

    Electrically Conductive Oxide Aerogels: New Materials in2003). Electrochemical Properties of Vanadium Oxide Aerogelsand Aerogel Nanocomposites . Journal of Sol-Gel Science and

  10. EFFECT OF VANADIUM ON STRUCTURE-PROPERTY RELATIONS OF DUAL PHASE Fe/Mn/Si/0.lC STEELS

    E-Print Network [OSTI]

    Nakagawa, Alvin

    2014-01-01

    After intercritical annealing at 800°C, the steels with andsteel did not contain martensite, indicates that more vanadium carbides dissolve after 900°C than 800°C annealing.

  11. Method for the regeneration of spent molten zinc chloride

    DOE Patents [OSTI]

    Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

    1981-01-01

    In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

  12. The Integration of a Structural Water Gas Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device

    SciTech Connect (OSTI)

    Barton, Thomas; Argyle, Morris; Popa, Tiberiu

    2009-06-30

    This project is in response to a requirement for a system that combines water gas shift technology with separation technology for coal derived synthesis gas. The justification of such a system would be improved efficiency for the overall hydrogen production. By removing hydrogen from the synthesis gas stream, the water gas shift equilibrium would force more carbon monoxide to carbon dioxide and maximize the total hydrogen produced. Additional benefit would derive from the reduction in capital cost of plant by the removal of one step in the process by integrating water gas shift with the membrane separation device. The answer turns out to be that the integration of hydrogen separation and water gas shift catalysis is possible and desirable. There are no significant roadblocks to that combination of technologies. The problem becomes one of design and selection of materials to optimize, or at least maximize performance of the two integrated steps. A goal of the project was to investigate the effects of alloying elements on the performance of vanadium membranes with respect to hydrogen flux and fabricability. Vanadium was chosen as a compromise between performance and cost. It is clear that the vanadium alloys for this application can be produced, but the approach is not simple and the results inconsistent. For any future contracts, large single batches of alloy would be obtained and rolled with larger facilities to produce the most consistent thin foils possible. Brazing was identified as a very likely choice for sealing the membranes to structural components. As alloying was beneficial to hydrogen transport, it became important to identify where those alloying elements might be detrimental to brazing. Cataloging positive and negative alloying effects was a significant portion of the initial project work on vanadium alloying. A water gas shift catalyst with ceramic like structural characteristics was the second large goal of the project. Alumina was added as a component of conventional high temperature water gas shift iron oxide based catalysts. The catalysts contained Fe-Al-Cr-Cu-O and were synthesized by co-precipitation. A series of catalysts were prepared with 5 to 50 wt% Al2O3, with 8 wt% Cr2O3, 4 wt% CuO, and the balance Fe2O3. All of the catalysts were compared to a reference WGS catalyst (88 wt% FeOx, 8 wt% Cr2O3, and 4 wt% CuO) with no alumina. Alumina addition to conventional high temperature water gas shift catalysts at concentrations of approximately 15 wt% increased CO conversion rates and increase thermal stability. A series of high temperature water gas shift catalysts containing iron, chromia, and copper oxides were prepared with small amounts of added ceria in the system Fe-Cr-Cu-Ce-O. The catalysts were also tested kinetically under WGS conditions. 2-4 wt% ceria addition (at the expense of the iron oxide content) resulted in increased reaction rates (from 22-32% higher) compared to the reference catalyst. The project goal of a 10,000 liter per day WGS-membrane reactor was achieved by a device operating on coal derived syngas containing significant amounts of carbon monoxide and hydrogen sulfide. The membrane flux was equivalent to 52 scfh/ft2 based on a 600 psi syngas inlet pressure and corresponded to membranes costing $191 per square foot. Over 40 hours of iv exposure time to syngas has been achieved for a double membrane reactor. Two modules of the Chart reactor were tested under coal syngas for over 75 hours with a single module tested for 50 hours. The permeance values for the Chart membranes were similar to the REB reactor though total flux was reduced due to significantly thicker membranes. Overall testing of membrane reactors on coal derived syngas was over 115 hours for all reactors tested. Testing of the REB double membrane device exceeded 40 hours. Performance of the double membrane reactor has been similar to the results for the single reactor with good maintenance of flux even after these long exposures to hydrogen sulfide. Of special interest is that the flux is highest at the start of each e

  13. Zinc and zinc alloys as protective coatings. (Latest citations from the Compendex database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    The bibliography contains citations concerning the corrosion protection of materials by means of zinc and zinc coatings, exclusive of electroplating and electrodeposition. Zinc rich paints and metallization are discussed, as well as polymeric coatings based on zinc. Major applications include structural steel work, oil and gas pipes, pipe joints, and offshore structures. Conversion coatings and conversion coating processes are examined in a separate bibliography. (Contains a minimum of 199 citations and includes a subject term index and title list.)

  14. Directed spatial organization of zinc oxide nanostructures

    DOE Patents [OSTI]

    Hsu, Julia (Albuquerque, NM); Liu, Jun (Richland, WA)

    2009-02-17

    A method for controllably forming zinc oxide nanostructures on a surface via an organic template, which is formed using a stamp prepared from pre-defined relief structures, inking the stamp with a solution comprising self-assembled monolayer (SAM) molecules, contacting the stamp to the surface, such as Ag sputtered on Si, and immersing the surface with the patterned SAM molecules with a zinc-containing solution with pH control to form zinc oxide nanostructures on the bare Ag surface.

  15. A NEW CONCEPT IN AN ELECTRICALLY RECHARGEABLE ZINC-AIR ALKALINE BATTERY

    E-Print Network [OSTI]

    Ross, P.N.

    2010-01-01

    flow-thru porous zinc electrode with recirculating supersaturated zincate solution. An alkaline zinc battery

  16. Regulation of Zinc Transport in the Choroid Plexus 

    E-Print Network [OSTI]

    Aquino, Mayra

    2014-07-21

    regulation of zinc transporters with metallothionein as the choroid plexus epithelium adapts to increases or decreases in extracellular zinc. My first objective was to characterize time-dependent changes in zinc transporter and MT-1 expression...

  17. Extracellular Proteins Promote Zinc Sulfide Aggregation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extracellular Proteins Promote Zinc Sulfide Aggregation Print Researchers from the ALS, Berkeley Lab's National Center for Electron Microscopy (NCEM), and Lawrence Livermore...

  18. The marine biogeochemistry of zinc isotopes

    E-Print Network [OSTI]

    John, Seth G

    2007-01-01

    Zinc (Zn) stable isotopes can record information about important oceanographic processes. This thesis presents data on Zn isotopes in anthropogenic materials, hydrothermal fluids and minerals, cultured marine phytoplankton, ...

  19. Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid Based Redox Flow Battery Electrolytes

    SciTech Connect (OSTI)

    Vijayakumar, M.; Wang, Wei; Nie, Zimin; Sprenkle, Vincent L.; Hu, Jian Z.

    2013-11-01

    The Vanadium (V) cation structures in mixed acid based electrolyte solution were analysed by density functional theory (DFT) based computational modelling and 51V and 35Cl Nuclear Magnetic Resonance (NMR) spectroscopy. The Vanadium (V) cation exists as di-nuclear [V2O3Cl2.6H2O]2+ compound at higher vanadium concentrations (?1.75M). In particular, at high temperatures (>295K) this di-nuclear compound undergoes ligand exchange process with nearby solvent chlorine molecule and forms chlorine bonded [V2O3Cl2.6H2O]2+ compound. This chlorine bonded [V2O3Cl2.6H2O]2+ compound might be resistant to the de-protonation reaction which is the initial step in the precipitation reaction in Vanadium based electrolyte solutions. The combined theoretical and experimental approach reveals that formation of chlorine bonded [V2O3Cl2.6H2O]2+ compound might be central to the observed higher thermal stability of mixed acid based Vanadium (V) electrolyte solutions.

  20. Temperature dependence of the damage microstructures in neutron-irradiated vanadium

    SciTech Connect (OSTI)

    Horton, L.L.; Farrell, K.

    1983-01-01

    Vanadium and vanadium with boron carbide additions (V-B/sub 4/C) were irradiated to approx. 1 dpa in the Oak Ridge Research Reactor at controlled temperatures ranging from 455 to 925 K. The V-B/sub 4/C alloy was enriched in /sup 10/B, which produced approx. 3900 at. ppM helium. In the vanadium specimens, the dislocation microstructures varied from clusters of small (< 50 nm diam) dislocation loops (455 to 625 K) to larger, homogeneously distributed loops at higher temperatures. Their Burgers vectors were a/2<111>. The V-B/sub 4/C specimens contained only tangled dislocation segments. Cavities were observed in all specimens. The cavity concentration decrease and the average diameter increased with increasing irradiation temperature. At 725 K, the maximum swelling was observed in both the vanadium (0.1%) and V-B/sub 4/C (1.4%). At comparable temperatures the cavities in the V-B/sub 4/C specimens were smaller and more numerous than those in the vanadium specimens. Helium bubbles were found on the grain boundaries in all of the V-B/sub 4/ specimens.

  1. (HPO4)4?enH?H2O: a mixed-valence vanadium phosphate with an open framework

    E-Print Network [OSTI]

    vanadium provides potential for redox catalytic properties. 1 Introduction Organically templated transition. The solid product, a mixture of dark green powder and unreacted vanadium, was filtered out, washed, and dried. Although boron is not present in the product, all attempts to synthesize the compound without

  2. Chemical leaching of coal to remove ash, alkali and vanadium

    SciTech Connect (OSTI)

    Smit, F.J.; Huggins, D.K.; Berggren, M.; Anast, K.R.

    1986-04-15

    A process is described for upgrading powdered coal to improve the usefulness thereof as a fuel for internal combustion engines which consists of: (a) pressure-leaching powdered coal having a particle size ranging from about 28 mesh to about 200 mesh in an aqueous caustic solution at a temperature ranging from about 175/sup 0/C, to about 350/sup 0/C., the amount of caustic in the solution ranging from about 5% to about 30% by weight, the amount of coal being sufficient to form a slurry comprising about 10% to 30% by weight of solids, (b) hydrochloric acid leaching the caustic leached coal to dissolve acid-soluble constituents resulting from the caustic leach, (c) pressure leaching the acid-leached coal with a liquid from the group consisting of water and dilute aqueous ammonia to remove sodium and chlorine, and thereafter (d) filtering and washing the pressure leached coal, whereby the coal is characterized by up to about 0.85% by weight of ash, up to about 150 ppm of alkali metals and up to about 4 ppm vanadium.

  3. Numerical modeling of an all vanadium redox flow battery.

    SciTech Connect (OSTI)

    Clausen, Jonathan R.; Brunini, Victor E.; Moffat, Harry K.; Martinez, Mario J.

    2014-01-01

    We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.

  4. Stress evolution during growth in direct-current-sputtered zinc...

    Office of Scientific and Technical Information (OSTI)

    IONS; RADIOWAVE RADIATION; SEMICONDUCTOR MATERIALS; SPUTTERING; STOICHIOMETRY; SURFACE COATING; THICKNESS; THIN FILMS; VARIATIONS; ZINC; ZINC OXIDES Word Cloud More Like This Full...

  5. Solvothermal synthesis of vanadium phosphates in the form of xerogels, aerogels and mesostructures

    SciTech Connect (OSTI)

    Sydorchuk, V.; Zazhigalov, V.; Khalameida, S.; Diyuk, E.; Skubiszewska-Zieba, J.; Leboda, R.; Kuznetsova, L.

    2010-09-15

    Regularities and peculiarities of physicochemical changes, first of all phase transformations, during solvothermal treatment (with conventional and microwave heating) of the vanadium pentoxide and orthophosphoric acid mixture in organic solvents in the presence of reducing agents have been studied. Hemihydrate of vanadium hydrophosphate - the precursor of vanadium pyrophosphate, the active phase for n-butane to maleic anhydride oxidation, and ion exchanger with variable physicochemical characteristics, i.e. crystal structure, specific surface area, crystallite size and acidic properties - has been synthesized in the temperature range 170-200 {sup o}C. The obtained phases were examined using XRD, DTA-TG, SEM, FTIR spectroscopy, nitrogen adsorption as well as gas chromatographic determination of acidity through organic bases adsorption. The catalytic activity of prepared samples for n-butane oxidation has been investigated.

  6. Rational Design of Zinc Phosphide Heterojunction Photovoltaics

    E-Print Network [OSTI]

    Winfree, Erik

    Rational Design of Zinc Phosphide Heterojunction Photovoltaics Thesis by Jeffrey Paul Bosco would meet me with the same energy and enthusiasm regarding the topic of zinc phosphide photovoltaics to the field of earth-abundant photovoltaics has been indispensable to my work. Greg also made a great mentor

  7. Strong reduction of V{sup 4+} amount in vanadium oxide/hexadecylamine nanotubes by doping with Co{sup 2+} and Ni{sup 2+} ions: Electron paramagnetic resonance and magnetic studies

    SciTech Connect (OSTI)

    Saleta, M. E.; Troiani, H. E.; Ribeiro Guevara, S.; Ruano, G.; Sanchez, R. D.; Malta, M.; Torresi, R. M.

    2011-05-01

    In this work we present a complete characterization and magnetic study of vanadium oxide/hexadecylamine nanotubes (VO{sub x}/Hexa NT's) doped with Co{sup 2+} and Ni{sup 2+} ions. The morphology of the NT's has been characterized by transmission electron microscopy, while the metallic elements have been quantified by the instrumental neutron activation analysis technique. The static and dynamic magnetic properties were studied by collecting data of magnetization as a function of magnetic field and temperature and by electron paramagnetic resonance. At difference of the majority reports in the literature, we do not observe magnetic dimers in vanadium oxide nanotubes. Also, we observed that the incorporation of metallic ions (Co{sup 2+}, S = 3/2 and Ni{sup 2+}, S = 1) decreases notably the amount of V{sup 4+} ions in the system, from 14-16% (nondoped case) to 2%-4%, with respect to the total vanadium atoms (fact corroborated by XPS experiments) anyway preserving the tubular nanostructure. The method to decrease the amount of V{sup 4+} in the nanotubes improves considerably their potential technological applications as Li-ion batteries cathodes.

  8. Zinc-bromine batteries for bulk energy storage

    SciTech Connect (OSTI)

    Bellows, R.J.; Elspass, C.; Einstein, H.; Grimes, P.; Kantner, E.; Malachesky, P.; Newby, K.

    1983-01-01

    The design, testing, operation, and state of development of zinc-bromine batteries are discussed. (LEW)

  9. ZINC--2001 85.1 By Jozef Plachy

    E-Print Network [OSTI]

    ZINC--2001 85.1 ZINC By Jozef Plachy Domestic survey data and tables were prepared by Aaron J, international data coordinator. In 2001, domestic zinc mine production, expressed in zinc content of ore, which reflected oversupply and excess production capacity worldwide. By the end of 2001, only 12 mines

  10. ZINC--1999 85.1 By Jozef Plachy

    E-Print Network [OSTI]

    ZINC--1999 85.1 ZINC By Jozef Plachy Domestic survey data and tables were prepared by Brandon P, international data coordinator. In 1999, domestic zinc mine production, expressed in zinc content of ore, followed by, in descending order, Tennessee, Missouri, and New York. In 1999, as in every year since

  11. ZINC MITIGATION INTERIM REPORT - THERMODYNAMIC STUDY

    SciTech Connect (OSTI)

    Korinko, P.

    2010-12-17

    An experimental program was initiated in order to develop and validate conditions that will effectively trap Zn vapors that are released during extraction. The proposed work is broken down into three tasks. The first task is to determine the effectiveness of various pore sizes of filter elements. The second task is to determine the effect of filter temperature on zinc vapor deposition. The final task is to determine whether the zinc vapors can be chemically bound. The approach for chemically binding the zinc vapors has two subtasks, the first is a review of literature and thermodynamic calculations and the second is an experimental approach using the best candidates. This report details the results of the thermodynamic calculations to determine feasibility of chemically binding the zinc vapors within the furnace module, specifically the lithium trap (1). A review of phase diagrams, literature, and thermodynamic calculations was conducted to determine if there are suitable materials to capture zinc vapor within the lithium trap of the extraction basket. While numerous elements exist that form compounds with zinc, many of these also form compounds with hydrogen or the water that is present in the TPBARs. This relatively comprehensive review of available data indicates that elemental cobalt and copper and molybdenum trioxide (MoO3) may have the requisite properties to capture zinc and yet not be adversely affected by the extraction gases and should be considered for testing.

  12. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1985-05-17

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  13. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, Richard H. (Berkeley, CA)

    1987-01-01

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  14. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, R.H.

    1987-04-21

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  15. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, Richard H. (Berkeley, CA)

    1986-01-01

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  16. Better than crystalline: amorphous vanadium oxide for sodium-ion batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    Better than crystalline: amorphous vanadium oxide for sodium-ion batteries E. Uchaker, Y. Z. Zheng and investigated as cathodes for sodium- ion batteries. Amorphous V2O5 demonstrated superior electro- chemical development.1,2 Among commercially available energy storage media, lithium-ion (Li-ion) batteries constitute

  17. Temperature Dependence of Aliovalent-vanadium Doping in LiFePO4 Cathodes

    SciTech Connect (OSTI)

    Harrison, Katharine L; Bridges, Craig A; Paranthaman, Mariappan Parans; Idrobo Tapia, Juan C; Manthiram, Arumugam; Goodenough, J. B.; Segre, C; Katsoudas, John; Maroni, V. A.

    2013-01-01

    Vanadium-doped olivine LiFePO4 cathode materials have been synthesized by a novel low-temperature microwave-assisted solvothermal (MW-ST) method at 300 oC. Based on chemical and powder neutron/X-ray diffraction analysis, the compositions of the synthesized materials were found to be LiFe1-3x/2Vx x/2PO4 (0 x 0.2) with the presence of a small number of lithium vacancies charge-compensated by V4+, not Fe3+, leading to an average oxidation state of ~ 3.2+ for vanadium. Heating the pristine 15 % V-doped sample in inert or reducing atmospheres led to a loss of vanadium from the olivine lattice with the concomitant formation of a Li3V2(PO4)3 impurity phase; after phase segregation, a partially V-doped olivine phase remained. For comparison, V-doped samples were also synthesized by conventional ball milling and heating, but only ~ 10 % V could be accommodated in the olivine lattice in agreement with previous studies. The higher degree of doping realized with the MW-ST samples demonstrates the temperature dependence of the aliovalent-vanadium doping in LiFePO4.

  18. Chemical and Mechanical Degradation of Sulfonated Poly(sulfone) Membranes in Vanadium Redox Flow Batteries

    SciTech Connect (OSTI)

    Kim, Soowhan; Tighe, Timothy B.; Schwenzer, Birgit; Yan, Jingling; Zhang, Jianlu; Liu, Jun; Yang, Zhenguo; Hickner, Michael A.

    2011-10-01

    A sulfonated poly(sulfone) (S-Radel{reg_sign}) membrane with high proton conductivity and low vanadium ion diffusion showed high initial performance in a vanadium redox flow battery (VRFB) but suffered damage during charge/discharge cycling. The S-Radel membrane had different degradation behaviors in flow cell cycling and ex-situ vanadium ion immersion tests. The S-Radel membrane immersed in V5+ solution cracked into small pieces, but in the VRFB cell, the membrane underwent internal delamination preferentially on the side of the membrane that faced the positive electrode. A vanadium-rich interface was observed near the membrane surface that experienced delamination and Raman spectroscopic analysis of the surfaces of the membrane indicated a slightly depressed 1026 cm-1 band corresponding to the sulfonate SO2 stretch for the degraded surface. Even though the S-Radel membrane underwent severe mechanical damage during the flow cell cycling, significant chemical degradation was not obvious from the spectroscopic analyses. For the VRFB containing an S-Radel membrane, an increase in membrane resistance caused an abnormal voltage depression during the discharge cycle. The reversible increase in membrane resistance and severe mechanical degradation of the membrane during cycling may be attributed repeated formation and dissolution of particles inside the membrane. The mechanical stresses imposed by the particles coupled with a small amount of chemical degradation of the polymer by V5+, are likely degradation mechanisms of the S-Radel membrane in VRFBs under high state-of-charge conditions.

  19. Concentration Dependence of VO2+ Crossover of Nafion for Vanadium Redox Flow Batteries

    SciTech Connect (OSTI)

    Lawton, Jamie [University of Tennessee, Knoxville (UTK); Jones, Amanda [University of Tennessee, Knoxville (UTK); Zawodzinski, Thomas A [ORNL

    2013-01-01

    The VO2+ crossover, or permeability, through Nafion in a vanadium redox flow battery (VRFB) was monitored as a function of sulfuric acid concentration and VO2+ concentration. A vanadium rich solution was flowed on one side of the membrane through a flow field while symmetrically on the other side a blank or vanadium deficit solution was flowed. The blank solution was flowed through an electron paramagnetic resonance (EPR) cavity and the VO2+ concentration was determined from the intensity of the EPR signal. Concentration values were fit using a solution of Fick s law that allows for the effect of concentration change on the vanadium rich side. The fits resulted in permeability values of VO2+ ions across the membrane. Viscosity measurements of many VO2+ and H2SO4 solutions were made at 30 60 C. These viscosity values were then used to determine the effect of the viscosity of the flowing solution on the permeability of the ion. 2013 The Electrochemical Society. [DOI: 10.1149/2.004306jes] All rights reserved.

  20. Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic compression

    E-Print Network [OSTI]

    Wei, Qiuming

    Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic compression Q. Wei a,*, T. Jiao a , K.T. Ramesh a , E. Ma b a Department of Mechanical Engineering, The Johns that the grain size of the consolidated V is around 100 nm. Mechanical properties of the nano-structured V were

  1. Thermodynamics of strained vanadium dioxide single crystals Yijia Gu,1,a

    E-Print Network [OSTI]

    Wu, Junqiao

    Thermodynamics of strained vanadium dioxide single crystals Yijia Gu,1,a Jinbo Cao,2 Junqiao Wu,2 condition plays an important role. To investigate the strain contribution, a phenomenological thermodynamic films. In order to control and manipulate the MIT, it is necessary to understand the thermodynamics

  2. Hydrogen-impurity binding energy in vanadium and niobium A. Mokrani and C. Demangeat

    E-Print Network [OSTI]

    Boyer, Edmond

    2243 Hydrogen-impurity binding energy in vanadium and niobium A. Mokrani and C. Demangeat IPCMS, UM by the hydrogen) contribution, ii) the band structure contribution, iii) the electron-electron interaction without. Strong H-H repulsion is observed when the hydrogen atoms are at first nearest neighbouring positions

  3. Electrochimica Acta 52 (2007) 49424946 High-performance microfluidic vanadium redox fuel cell

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    2007-01-01

    vanadium redox fuel cell Erik Kjeanga,c, Brenton T. Proctora,c, Alexandre G. Brolob,c, David A. Harringtonb a new microfluidic fuel cell design with high-surface area porous carbon electrodes and high aspect-effective and rapid fabrication, and would be applicable to most microfluidic fuel cell architectures. © 2007 Elsevier

  4. Study of lithium diffusion in RF sputtered Nickel/Vanadium mixed oxides thin films

    E-Print Network [OSTI]

    Artuso, Florinda

    Study of lithium diffusion in RF sputtered NickelÁ/Vanadium mixed oxides thin films F. Artuso a lithium insertion inside RF sputtered Ni/V mixed oxides thin films have been investigated employing, showed three steps clearly involved in the intercalation mechanism of lithium in the oxide films: (i

  5. Vanadium pentoxide modified polycrystalline silicon anode for active-matrix organic light-emitting diodes

    E-Print Network [OSTI]

    to be an efficient anode for organic light-emitting diode OLED X. L. Zhu, J. X. Sun, H. J. Peng, Z. G. Meng, M. Wong of Physics. DOI: 10.1063/1.2099520 Organic light-emitting diodes OLEDs have attracted wide attention dueVanadium pentoxide modified polycrystalline silicon anode for active-matrix organic light

  6. Zinc-bromine battery technology

    SciTech Connect (OSTI)

    Bellows, R.; Grimes, P.; Malachesky, P.

    1983-01-01

    Some progress in the field of zinc-bromine batteries is reviewed, and a number of successes and some difficulties are related. The direction of work includes, among other areas, testing of parametric and large batteries. The program includes the control of electrode planarity through electrode thickness and electrode support, improved cathode activation coatings to increase and maintain performance near the end of battery capacity, reduced retention of bromine in the battery cell stock at shutdown to lower capacity loss and improve sealing techniques. Projected factory cost should be competitive with lead-acid batteries. Progress has been demonstrated in scale-up and performance, as well as improving the life of the system. (LEW)

  7. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Cairns, Elton J. (Walnut Creek, CA)

    1994-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  8. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, T.C.; McLarnon, F.R.; Cairns, E.J.

    1994-04-12

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K[sub 2]CO[sub 3] salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics. 8 figures.

  9. Zinc subsea production system: An overview

    SciTech Connect (OSTI)

    Bednar, J.M. )

    1994-04-01

    Exxon Co. U.S.A.'s Zinc development, in 1,460 ft of water in the Gulf of Mexico, uses a subsea production system to produce gas to a host platform 6 miles away. The 10-slot subsea template, designed specifically to accommodate the soft soil conditions at the Zinc site, supports the non-through-flowline (non-TFL) wells, which are controlled by means of an electrohydraulic control system. This paper describes key features of the development.

  10. Hyper-dendritic nanoporous zinc foam anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chamoun, Mylad; Hertzberg, Benjamin J.; Gupta, Tanya; Davies, Daniel; Bhadra, Shoham; Van Tassell, Barry.; Erdonmez, Can; Steingart, Daniel A.

    2015-04-24

    The low cost, significant reducing potential, and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1 - 96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrastmore »to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~ 88% at full depth-of-discharge at various rates indicating a superb rate-capability. The rechargeability of Zn?/Zn˛? showed significant capacity retention over 100 cycles at a 40% depth-of-discharge to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge-discharge cycling and presented superior performance compared to bulk zinc electrodes.« less

  11. Hyper-dendritic nanoporous zinc foam anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chamoun, Mylad [Brookhaven National Lab. (BNL), Upton, NY (United States); Hertzberg, Benjamin J. [Princeton Univ., NJ (United States); Gupta, Tanya [Princeton Univ., NJ (United States); Davies, Daniel [Princeton Univ., NJ (United States); Bhadra, Shoham [Princeton Univ., NJ (United States); Van Tassell, Barry. [City College of New York, NY (United States); Erdonmez, Can [Brookhaven National Lab. (BNL), Upton, NY (United States); Steingart, Daniel A. [Princeton Univ., NJ (United States)

    2015-04-24

    The low cost, significant reducing potential, and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1 - 96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrast to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~ 88% at full depth-of-discharge at various rates indicating a superb rate-capability. The rechargeability of Zn?/Zn˛? showed significant capacity retention over 100 cycles at a 40% depth-of-discharge to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge-discharge cycling and presented superior performance compared to bulk zinc electrodes.

  12. SUMMARY REPORT FOR ZINC 65 CONTAMINATION CONTROL

    SciTech Connect (OSTI)

    Korinko, P.

    2011-07-14

    Radioactive zinc, {sup 65}Zn, was detected after extraction of 215 TPBARs in from TVA reactor fuel cycle 6. A team consisting of Tritium Engineering, Tritium Operations, Tritium Radiation Control, and Savannah River National Laboratory personnel evaluated the risk and response and developed short, medium and long term goals for contamination control. One of the goals was incorporated into site Performance Based Incentive CO 3.4, to optimize the filter geometry and operating conditions for the Tritium Extraction Facility. This goal included a scoping study to determine if the contamination could be contained within the high radiation environment of the furnace module as well. In order to optimize the filters studies were conducted to independently evaluate the effect of pore size on pumping efficiency and zinc trapping efficiency (1). A study was also conducted to evaluate the effect of temperature on the trapping efficiency and adhesion (2). In addition, the potential for chemically trapping zinc in the lithium trap was evaluated using a thermodynamic study (3) followed by preliminary experimental testing (4). Based on the work that was completed it is determined that a 20 {mu}m filter heated to between 120 and 200 C will act as an effective physical trap for zinc vapors. It may be possible to chemically react zinc with copper or cobalt to form zinc intermetallic compounds or alloys but additional work under more prototypic conditions are required.

  13. Investigation of Local Environments in Nafion-SiO2 Composite Membranes used in Vanadium Redox Flow Batteries

    SciTech Connect (OSTI)

    Vijayakumar, M.; Schwenzer, Birgit; Kim, Soowhan; Yang, Zhenguo; Thevuthasan, Suntharampillai; Liu, Jun; Graff, Gordon L.; Hu, Jian Z.

    2012-04-01

    The proton conducting polymer composite membranes are of technological interest in many energy devices such as fuel cells and redox flow batteries. In particular, the polymer composite membranes such as SiO2 incorporated Nafion membranes are recently reported as highly promising for the redox flow batteries. However, there is conflicting reports regarding the performance of this Nafion-SiO2 composite membrane in the redox flow cell. This paper presents results of the analysis of the Nafion-SiO2 composite membrane used in a vanadium redox flow battery by nuclear magnetic resonance (NMR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Fourier Transformed Infra Red (FTIR) spectroscopy, and ultraviolet visible spectroscopy. The XPS study reveals the chemical identity and environment of vanadium cations accumulated at the surface. On the other hand, the 19F and 29Si NMR measurement explores the nature of the interaction between the silica particles, Nafion side chains and diffused vanadium cations. The 29Si NMR shows that the silica particles interaction via hydrogen bonds to the sulfonic groups of Nafion and diffused vanadium cations. Based on these spectroscopic studies, the chemical environment of the silica particles inside the Nafion membrane and their interaction with diffusing vanadium cations during flow cell operations are discussed. This study discusses the origin of performance degradation of the Nafion-SiO2 composite membrane materials in vanadium redox flow batteries.

  14. Zinc halogen battery electrolyte composition with lead additive

    DOE Patents [OSTI]

    Henriksen, Gary L. (Troy, MI)

    1981-01-01

    This disclosure relates to a zinc halogen battery electrolyte composition containing an additive providing improved zinc-on-zinc recyclability. The improved electrolyte composition involves the use of a lead additive to inhibit undesirable irregular plating and reduce nodular or dendritic growth on the electrode surface. The lead-containing electrolyte composition of the present invention appears to influence not only the morphology of the base plate zinc, but also the morphology of the zinc-on-zinc replate. In addition, such lead-containing electrolyte compositions appear to reduce hydrogen formation.

  15. ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL

    E-Print Network [OSTI]

    Mobley, David Paul

    2013-01-01

    Co. , "Zinc Halide Hydrocracking Process for Distillatewith Zinc Chloride", Hydrocracking u. S. Dept. of Interior

  16. Carbon nanotube-induced preparation of vanadium oxide nanorods: Application as a catalyst for the partial oxidation of n-butane

    SciTech Connect (OSTI)

    Chen Xiaowei; Zhu Zhenping; Haevecker, Michael; Su Dangsheng . E-mail: dangsheng@fhi-berlin.mpg.de; Schloegl, Robert

    2007-02-15

    A vanadium oxide-carbon nanotube composite was prepared by solution-based hydrolysis of NH{sub 4}VO{sub 3} in the presence of carbon nanotubes. The carbon nanotubes induce the nucleation of the 1D vanadium oxide nanostructures, with the nuclei growing into long freestanding nanorods. The vanadium oxide nanorods with the lengths up to 20 {mu}m and the widths of 5-15 nm exhibit a well-ordered crystalline structure. Catalytic tests show that the composite with nanostructured vanadium oxide is active for the partial oxidation of n-butane to maleic anhydride at 300 deg. C.

  17. Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium

    E-Print Network [OSTI]

    E. I. Sharapov; C. L. Morris; M. Makela; A. Saunders; Evan R. Adamek; Yelena Bagdasarova; L. J. Broussard; C. B. Cude-Woods; Deon E Fellers; Peter Geltenbort; S. I. Hasan; K. P. Hickerson; G. Hogan; A. T. Holley; Chen-Yu Liu; M. P. Mendenhall; J. Ortiz; R. W. Pattie Jr.; D. G. Phillips; J. Ramsey; D. J. Salvat; S. J. Seestrom; E. Shaw; Sky Sjue; W. E. Sondheim; B. VornDick; Z. Wang; T. L. Womack; A. R. Young; B. A. Zeck

    2013-06-05

    The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

  18. Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium

    E-Print Network [OSTI]

    Sharapov, E I; Makela, M; Saunders, A; Adamek, Evan R; Bagdasarova, Yelena; Broussard, L J; Cude-Woods, C B; Fellers, Deon E; Geltenbort, Peter; Hasan, S I; Hickerson, K P; Hogan, G; Holley, A T; Liu, Chen-Yu; Mendenhall, M P; Ortiz, J; Pattie, R W; Phillips, D G; Ramsey, J; Salvat, D J; Seestrom, S J; Shaw, E; Sjue, Sky; Sondheim, W E; VornDick, B; Wang, Z; Womack, T L; Young, A R; Zeck, B A

    2013-01-01

    The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

  19. Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries

    SciTech Connect (OSTI)

    Zhang, Jianlu; Li, Liyu; Nie, Zimin; Chen, Baowei; Vijayakumar, M.; Kim, Soowhan; Wang, Wei; Schwenzer, Birgit; Liu, Jun; Yang, Zhenguo

    2011-10-01

    The stability of the electrolytes for all-vanadium redox flow battery was investigated with ex-situ heating/cooling treatment and in-situ flow-battery testing methods. The effects of inorganic and organic additives have been studied. The additives containing the ions of potassium, phosphate, and polyphosphate are not suitable stabilizing agents because of their reactions with V(V) ions, forming precipitates of KVSO6 or VOPO4. Of the chemicals studied, polyacrylic acid and its mixture with CH3SO3H are the most promising stabilizing candidates which can stabilize all the four vanadium ions (V2+, V3+, VO2+, and VO2+) in electrolyte solutions up to 1.8 M. However, further effort is needed to obtain a stable electrolyte solution with >1.8 M V5+ at temperatures higher than 40 °C.

  20. Structure and properties of a rapidly solidified dispersion strengthened aluminum-iron-vanadium-silicon alloy 

    E-Print Network [OSTI]

    Little, Stafford Dean

    1991-01-01

    of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Mechanical Engineering STRUCTURE AND PROPERTIES OF A RAPIDLY SOLIDIFIED DISPERSION STRENGTHENED ALUMINUM-IRON-VANADIUM-SILICON ALLOY A Thesis by STAFFORD DEAN LITTLE Approved... Al-Fe-V-Si alloys II Three Component PUCOT Equations III Four Component PUCOT Equations 16 16 IV Melt Spinning Variables 19 V Young's Modulus Determined by PUCOT 27 VI Tensile Test Data VII Microhardness Measurements at Room Temperature 29...

  1. Targeted sensors for investigating mobile Zinc in biology

    E-Print Network [OSTI]

    Chyan, Wen, S.B. Massachusetts Institute of Technology

    2013-01-01

    Chapter 1. Sensing Strategies for Detection of Mobile Zinc. Mobile zinc plays important physiological roles in areas such as the hippocampus, prostate, and pancreas. A better understanding of the distribution of intracellular ...

  2. Production of zinc substituted hydroxyapatite using various precipitation routes

    E-Print Network [OSTI]

    Shepherd, David; Best, Serena Michelle

    2013-01-01

    pH sufficiently high for the production of stoichiometric hydroxyapatite using a reaction between calcium nitrate, zinc nitrate and ammonium phosphate. X-ray fluorescence (XRF) analysis showed that a significant proportion of the zinc added, did...

  3. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  4. X-Ray Absorption Studies of Vanadium-Containing Metal Oxide Nanocrystals

    SciTech Connect (OSTI)

    Hohn, Keith, L.

    2006-01-09

    Metal oxide nanocrystals offer significant potential for use as catalysts or catalyst supports due to their high surface areas and unique chemical properties that result from the high number of exposed corners and edges. However, little is known about the catalytic activity of these materials, especially as oxidation catalysts. This research focused on the preparation, characterization and use of vanadium-containing nanocrystals as selective oxidation catalysts. Three vanadium-containing nanocrystals were prepared using a modified sol-gel procedure: V/MgO, V/SiO2, and vanadium phosphate (VPO). These represent active oxidation catalysts for a number of industrially relevant reactions. The catalysts were characterized by x-ray diffraction and Raman, UV-VIS, infrared and x-ray absorption spectroscopies with the goal of determining the primary structural and chemical differences between nanocrystals and microcrystals. The catalytic activity of these catalysts was also studied in oxidative dehydrogenation of butane and methanol oxidation to formaldehyde. V/MgO nanocrystals were investigated for activity in oxidative dehydrogenation of butane and compared to conventional V/MgO catalysts. Characterization of V/MgO catalysts using Raman spectroscopy and x-ray absorption spectroscopy showed that both types of catalysts contained magnesium orthovanadate at vanadium loadings below 15 weight%, but above that loading, magnesium pyrovanadate may have been present. In general, MgO nanocrystals had roughly half the crystal size and double the surface area of the conventional MgO. In oxidative dehydrogenation of butane, nanocrystalline V/MgO gave higher selectivity to butene than conventional V/MgO at the same conversion. This difference was attributed to differences in vanadium domain size resulting from the higher surface areas of the nanocrystalline support, since characterization suggested that similar vanadium phases were present on both types of catalysts. Experiments in methanol oxidation were used to probe the chemical differences between sol-gel prepared and conventionally prepared metal oxides. Both V/MgO and V/SiO2 were studied. For both catalysts, similar product selectivities were noted for either preparation method, suggesting similar acid/base and redox properties for the catalysts. At lower weight loadings (<5%), activity was also similar, but at higher weight loadings the sol-gel prepared catalysts were more active. This was attributed to the greater dispersion of vanadium on sol-gel prepared catalysts, and it was suggested that small vanadium oxide domains were more active in methanol oxidation than polymeric and bulk domains. A novel sol-gel method was developed for preparation of VPO catalysts, which are used industrially in butane oxidation to maleic anhydride. In this method vanadium (V) triisopropoxide was reacted with orthophosphoric acid in THF to form a gel. Drying this gel under air resulted in an intercalated VOPO4 compound, where solvent molecules were trapped between layers of the vanadium phosphate compound. Higher surface areas could be achieved by drying this gel at high pressure in an autoclave. The amount of solvent (THF) placed in the autoclave was important in this process. Low amounts of solvent led to a lower surface area, as the solvent evaporated before reaching the critical point and collapsed the gel's pores. In addition, vanadium reduction occurred in the autoclave due to reaction of isopropanol with the vanadium phosphate. Higher amounts of THF reduced the concentration of isopropanol, leading to less reduction. Surfaces areas in excess of 100 m2/g were achieved with this method, and the product was confirmed through XPS and IR to be VOHPO4*0.5H2O, the common precursor for industrial VPO catalysts. Furthermore, this product displayed a platelet morphology, which is desirable for butane oxidation. Further work showed that this material could be transformed to (VO)2P2O7 (the industrial catalyst for butane oxidation to maleic anhydride) by heating under nitrogen without losing much surface are

  5. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hudak, Nicholas S.

    2013-12-31

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron–vanadium, and iron–chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantitiesmore »measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. As a result, proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.« less

  6. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    SciTech Connect (OSTI)

    Hudak, Nicholas S.

    2013-12-31

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron–vanadium, and iron–chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantities measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. As a result, proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.

  7. Electrical and optical properties of sputtered amorphous vanadium oxide thin films

    SciTech Connect (OSTI)

    Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Gauntt, B. D. [Materials Characterization Department, Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Motyka, M. A.; Horn, M. W. [Department of Engineering Science and Mechanics, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Dickey, E. C. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2012-04-01

    Amorphous vanadium oxide (VO{sub x}) is a component found in composite nanocrystalline VO{sub x} thin films. These types of composite films are used as thermistors in pulsed biased uncooled infrared imaging devices when containing face centered cubic vanadium monoxide phase crystallites, and substantial fractions of amorphous material in the composite are necessary to optimize device electrical properties. Similarly, optoelectronic devices exploiting the metal-to-semiconductor transition contain the room-temperature monoclinic or high-temperature (>68 deg. C) rutile vanadium dioxide phase. Thin films of VO{sub x} exhibiting the metal-to-semiconductor transition are typically polycrystalline or nanocrystalline, implying that significant amounts of disordered, amorphous material is present at grain boundaries or surrounding the crystallites and can impact the overall optical or electronic properties of the film. The performance of thin film material for either application depends on both the nature of the crystalline and amorphous components, and in this work we seek to isolate and study amorphous VO{sub x}. VO{sub x} thin films were deposited by pulsed dc reactive magnetron sputtering to produce amorphous materials with oxygen contents {>=}2, which were characterized electrically by temperature dependent current-voltage measurements and optically characterized by spectroscopic ellipsometry. Film resistivity, thermal activation energy, and complex dielectric function spectra from 0.75 to 6.0 eV were used to identify the impact of microstructural variations including composition and density.

  8. Ion flotation of zinc using ethylhexadecyldimethylammonium bromide

    SciTech Connect (OSTI)

    McDonald, C.W.; Ogunkeye, O.A.

    1981-01-01

    Zinc ions react with the surfactant ethylhexadecyldimethylammonium bromide (EHDABr) to form a surface active sublate which can be removed from aqueous chloride solutions by ion flotation. A typical ion flotation procedure involves passing air through a 235-ml solution containing 5 ppM Zn/sup 2 +/, 2.0 M HCl, and 2.5 x 10/sup -3/ M EHDABr at a flow rate of 40 ml/min for 150 min. The procedure is simple and rapid. Cadmium, copper, lead, and nickel ions cause reductions of zinc flotation efficiencies of less than 2.5% under the experimental conditions. 5 tables.

  9. Zinc and zinc alloys as protective coatings. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    The bibliography contains citations concerning the corrosion protection of materials by means of zinc and zinc coatings, exclusive of electroplating and electrodeposition. Zinc rich paints and metallization are discussed, as well as polymeric coatings based on zinc. Major applications include structural steel work, oil and gas pipes, pipe joints, and offshore structures. Conversion coatings and conversion coating processes are examined in a separate bibliography. (Contains a minimum of 249 citations and includes a subject term index and title list.)

  10. Zinc and zinc alloys as protective coatings. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The bibliography contains citations concerning the corrosion protection of materials by means of zinc and zinc coatings, exclusive of electroplating and electrodeposition. Zinc rich paints and metallization are discussed, as well as polymeric coatings based on zinc. Major applications include structural steel work, oil and gas pipes, pipe joints, and offshore structures. Conversion coatings and conversion coating processes are examined in a separate bibliography. (Contains 250 citations and includes a subject term index and title list.)

  11. The total synthesis of depsipeptide antibiotics

    E-Print Network [OSTI]

    Wohlrab, Aaron M.

    2007-01-01

    at this temperature. Zinc Bromide (4.32 g, 19.19 mmol) was1.00 g, 4.36mmol) and zinc bromide (0.982 g, 4.36 mmol) in

  12. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Cairns, Elton J. (Walnut Creek, CA)

    1995-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing one or more hydroxides having the formula M(OH), one or more fluorides having the formula MF, and one or more carbonates having the formula M.sub.2 CO.sub.3, where M is a metal selected from the group consisting of alkali metals. The electrolyte inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  13. Zinc-bromine batteries with improved electrolyte

    SciTech Connect (OSTI)

    Kantner, E.

    1985-01-01

    The coulombic efficiency of aqueous zinc bromine batteries can be increased if, in addition to the bromide ions required to be present in the electrolyte to charge the cell to rated capacity, chloride ions are added to the electrolyte in amounts sufficient to reduce the amount of free bromine present in the electrolyte during operation of the cell.

  14. Zinc bromide battery development. Final report

    SciTech Connect (OSTI)

    Leo, A.

    1986-01-01

    Earlier EPRI work demonstrated the potential of zinc bromide batteries to provide long-life, low-cost energy storage for utilities. The latest developments, summarized in this report, include improvements in electrode, separator, and other components, as well as successful testing of cell stacks.

  15. Zinc Bromide Waste Solution Treatment Options

    SciTech Connect (OSTI)

    Langston, C.A.

    2001-01-16

    The objective of this effort was to identify treatment options for 20,000 gallons of low-level radioactively contaminated zinc bromide solution currently stored in C-Area. These options will be relevant when the solutions are declared waste.

  16. Preparation of ionic membranes for zinc/bromine storage batteries

    SciTech Connect (OSTI)

    Assink, R.A.; Arnold, C. Jr.

    1991-01-01

    Zinc/bromine flow batteries are being developed for vehicular and utility load leveling applications. During charge, an aqueous zinc bromide salt is electolyzed to zinc metal and molecular bromine. During discharge, the zinc and bromine react to again form the zinc bromide salt. One serious disadvantage of the microporous separators presently used in the zinc/bromine battery is that modest amounts of bromine and negatively charged bromine moieties permeate through these materials and react with the zinc anode. This results in partial self-discharge of the battery and low coulombic efficiencies. Our approach to this problem is to impregnate the microporous separators with a soluble cationic polyelectrolyte. In laboratory screening tests a sulfonated polysulfone resin and fully fluorinated sulfonic acid polymer substantially reduced bromine permeation with only modest increases in the area resistance. 5 refs., 6 figs., 11 tabs.

  17. Process for preparing zinc oxide-based sorbents

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasad (Durham, NC)

    2011-06-07

    The disclosure relates to zinc oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  18. A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-scale Energy Storage

    SciTech Connect (OSTI)

    Li, Liyu; Kim, Soowhan; Wang, Wei; Vijayakumar, M.; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang; Hu, Jian Z.; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo

    2011-05-01

    Low cost, high performance redox flow batteries are highly demanded for up to multi-megawatt levels of renewable and grid energy storage. Here, we report a new vanadium redox flow battery with a significant improvement over the current technologies. This new battery utilizes a sulfate-chloride mixed solution, which is capable of dissolving more than 2.5 M vanadium or about a 70% increase in the energy storage capacity over the current vanadium sulfate system. More importantly, the new electrolyte remains stable over a wide temperature range of -5 to 60oC, potentially eliminating the need of active heat management. Its high energy density, broad operational temperature window, and excellent electrochemical performance would lead to a significant reduction in the cost of energy storage, thus accelerating its market penetration.

  19. Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

    2013-04-22

    Redox flow batteries (RFBs) are capable of reversible conversion between electricity and chemical energy. Potential RFB applications resolve around mitigating the discrepancy between electricity production and consumption to improve the stability and utilization of the power infrastructure and tackling the intermittency of renewables such as photovoltaics or wind turbines to enable their reliable integration [1, 2]. Because the energy is stored in externally contained liquid electrolytes and the energy conversion reactions take place at the electrodes, RFBs hold a unique capability to separate energy and power and thus possess considerable design flexibility to meet either energy management driven or power rating oriented grid applications, which is considered to be a unparalleled advantage over conventional solid-state secondary batteries [3]. Other advantages of RFBs include fast response to load changes, high round-trip efficiency, long calender and cycle lives, safe operations, tolerance to deep discharge, etc. [4]. Among various flow battery chemistries, all-vanadium redox flow battery (VRB) was invented by Maria Skyllas-Kazacos at the University of New South Wales in the 1980s [5, 6] and have attracted substantial attention in both research and industrial communities today [7, 8]. A well-recognized advantage that makes VRB stands out among other redox chemistries is the reduced crossover contamination ascribed to employing four different oxidation states of the same vanadium element as the two redox couples. Recently, great progress has led to remarkably improved energy density of VRB by using sulfuric-chloric mixed acid supporting electrolytes that were stable at 2.5M vanadium and had wider operational temperature window of -5~50oC [9], compared with the traditional sulfuric acid VRB system [10].

  20. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Revised: December, 2008 Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other All Buildings...

  1. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other All Buildings*...

  2. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  3. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  4. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  5. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  6. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  7. Electrolyte for zinc bromine storage batteries

    SciTech Connect (OSTI)

    Ando, Y.; Ochiai, T.

    1985-04-09

    A negative electrolyte for electrolyte circulation-type storage batteries has a composition basically comprising zinc bromide as an active material and this active material is mixed with specified amounts of quaternary ammonium bromides of heterocyclic compounds such as morpholine, pyridine and pyrrolidine or ammonia as a bromine complexing agent and a dendrite inhibitor with or without specified amounts of Sn/sup 2 +/ and Pb/sup 2 +/.

  8. Aluminum-doped Zinc Oxide Nanoink

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2014-08-15

    Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative to the widely used transparent conductive oxide (TCO) indium tin oxide while offering comparable optical and electronic properties. TCOs are used in devices such as flat screen displays, photovoltaic cells, photochromic windows, chemical sensors, and biosensors....

  9. Chemical enhancement of metallized zinc anode performance

    SciTech Connect (OSTI)

    Bennett, J.

    1998-12-31

    Galvanic current delivered to reinforced concrete by a metallized zinc anode was studied relative to the humidity of its environment and periodic direct wetting. Current decreased quickly at low humidity to values unlikely to meet accepted cathodic protection criteria, but could be easily restored by direct wetting of the anode. Thirteen chemicals were screened for their ability to enhance galvanic current. Such chemicals, when applied to the exterior surface of the anode, are easily transported by capillary action to the anode-concrete interface where they serve to maintain the interface conductive and the zinc electrochemically active. The most effective chemicals were potassium and lithium bromide, acetate, chloride and nitrate, which increased galvanic current by a factor of 2--15, depending on relative humidity and chloride contamination of the concrete. This new technique is expected to greatly expand the number of concrete structures which can be protected by simple galvanic cathodic protection, The use of lithium-based chemicals together with metallized zinc anode is also proposed for mitigation of existing problems due to ASR. In this case, lithium which prevents or inhibits expansion due to ASR can be readily injected into the concrete. A new process, electrochemical maintenance of concrete (EMC), is also proposed to benefit reinforced concrete structures suffering from chloride-induced corrosion.

  10. Occupational hypersensitivity pneumonitis in a smelter exposed to zinc fumes

    SciTech Connect (OSTI)

    Ameille, J.; Brechot, J.M.; Brochard, P.; Capron, F.; Dore, M.F. )

    1992-03-01

    A smelter exposed to zinc fumes reported severe recurrent episodes of cough, dyspnea and fever. Bronchoalveolar lavage showed a marked increase in lymphocytes count with predominance of CD8 T-lymphocytes. Presence of zinc in alveolar macrophages was assessed by analytic transmission electron microscopy. This is the first case of recurrent bronchoalveolitis related to zinc exposure in which the clinical picture and BAL results indicate a probable hypersensitivity pneumonitis.

  11. Spontaneous and reversible interaction of vanadium(V) oxyanions with amine derivatives

    SciTech Connect (OSTI)

    Crans, D.C.; Shin, P.K.

    1988-05-18

    The interaction between vanadate and tri- or tetradentate ethanolamine derivatives has been studied by using /sup 51/V NMR spectroscopy. The reactions occur spontaneously in aqueous solutions, at ambient temperatures and in the physiological pH range. In addition to one amine group and one hydroxyl group, the ethanolamine derivative should contain a third and/or fourth functionality that is an alcohol, a carboxylic acid, a phosphonium acid, or an amine. The reactions are highly dependent on pH, concentrations of monomeric vanadate, amine. The stability constants for the complexes are minimum orders of magnitude greater than those found for vanadate derivatives of corresponding ether derivatives, and the high stability is associated with the central nitrogen. Only one vanadium complex is formed in substantial amounts in the reaction of ethanolamine derivatives with vanadate, and that complex is mononuclear in vanadium. Several of the ethanolamine derivatives that form complexes are commonly used buffers in biological and biomedical studies in vitro. 22 refs., 10 figs., 7 tabs.

  12. Fluorescent chemosensors for exploring zinc metalloneurochemistry and detecting mercury in aqueous solution

    E-Print Network [OSTI]

    Nolan, Elizabeth M. (Elizabeth Marie), 1978-

    2006-01-01

    Chapter 1. An Introduction to Zinc Metalloneurochemistry and Zinc Detection in Biology. This chapter presents an overview of zinc neurophysiology and pathology, which provides motivation for the design of new tools and ...

  13. DEVELOPMENT OF A MICROPATTERNED ELECTRODE FOR STUDIES OF ZINC ELECTRODEPOSITION

    E-Print Network [OSTI]

    Sutija, D.P.

    2011-01-01

    involve a flow system, but the chloride battery design iszinc flow heat Figure l.la. Zinc/chlorine battery [21].

  14. Experimental and theoretical studies of reactions of neutral vanadium and tantalum oxide clusters with NO and NH3

    E-Print Network [OSTI]

    Rocca, Jorge J.

    . doi:10.1063/1.3497652 I. INTRODUCTION Selective catalytic reduction SCR of nitric oxide by ammonia, and then the reaction proceeds with the activation of nitric oxide from the gas phase;6­23 how- ever, the adsorptionExperimental and theoretical studies of reactions of neutral vanadium and tantalum oxide clusters

  15. Ethane Oxidative Dehydrogenation Pathways on Vanadium Oxide Catalysts Morris D. Argyle, Kaidong Chen, Alexis T. Bell,* and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Ethane Oxidative Dehydrogenation Pathways on Vanadium Oxide Catalysts Morris D. Argyle, Kaidong to determine the identity and reversibility of elementary steps involved in ethane oxidative dehydrogenation concurrent formation of C2H6-xDx or C2H4-xDx isotopomers, suggesting that C-H bond cleavage in ethane

  16. Direct Observation of Nanoscale Peltier and Joule Effects at Metal-Insulator Domain Walls in Vanadium Dioxide Nanobeams

    E-Print Network [OSTI]

    Wu, Junqiao

    Direct Observation of Nanoscale Peltier and Joule Effects at Metal- Insulator Domain Walls localized alternating Peltier heating and cooling as well as Joule heating concentrated at the M-I domain the monoclinic phase identification. KEYWORDS: Vanadium dioxide, thermoreflectance microscopy, Peltier effect

  17. Membraneless Vanadium Redox Fuel Cell Using Laminar Flow Rosaria Ferrigno, Abraham D. Stroock, Thomas D. Clark, Michael Mayer, and

    E-Print Network [OSTI]

    Mayer, Michael

    Membraneless Vanadium Redox Fuel Cell Using Laminar Flow Rosaria Ferrigno, Abraham D. Stroock This communication describes a small redox fuel cell fabricated using a design that omits the membrane normally used this concept by operating a millimeter-scale redox fuel cell that uses the redox couples V(V)/V(IV) (cathodic

  18. Behavior of Aluminum, Arsenic, and Vanadium during the Neutralization of Red Mud Leachate by HCl, Gypsum, or Seawater

    E-Print Network [OSTI]

    Burke, Ian

    Behavior of Aluminum, Arsenic, and Vanadium during the Neutralization of Red Mud Leachate by HCl ABSTRACT: Red mud leachate (pH 13) collected from Ajka, Hungary is neutralized to via surface adsorption of As onto the Al oxyhydroxides. Gypsum addition to red mud leachate results

  19. Zinc electrode morphology in acid electrolytes. Annual report, March 15, 1982-March 15, 1983

    SciTech Connect (OSTI)

    McBreen, J.; Gannon, E.

    1983-07-01

    The zinc electrode is common to both zinc/chlorine and zinc/bromine flow batteries. Although considerable progress has been made in engineering these batteries, there are still problems with the zinc electrode. The objective of this work is to elucidate the mechanism of zinc deposition in acid electrolytes and to devise methods to control zinc electrode morphology. In this subcontract, work focused on obtaining baseline data in ultra pure zinc chloride and zinc bromide electrolytes. Emphasis was on the initial stages of electrocrystallization. In addition, the effect of modified charging methods, organic surfactants, inorganic additives and substrates was investigated.

  20. Total Space Heat-

    Gasoline and Diesel Fuel Update (EIA)

    Survey: Energy End-Use Consumption Tables Total Space Heat- ing Cool- ing Venti- lation Water Heat- ing Light- ing Cook- ing Refrig- eration Office Equip- ment Com- puters Other...

  1. Total Synthesis of (?)-Himandrine

    E-Print Network [OSTI]

    Movassaghi, Mohammad

    We describe the first total synthesis of (?)-himandrine, a member of the class II galbulimima alkaloids. Noteworthy features of this chemistry include a diastereoselective Diels?Alder reaction in the rapid synthesis of the ...

  2. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  3. Glutamine and zinc methionine supplementation to dairy calves 

    E-Print Network [OSTI]

    Simon, Robin Renee

    1999-01-01

    Glutamine and zinc play an important role in immune functions of animals. The objective of this research was to determine the effects of L-glutamine or zinc methionine supplementation on 1) plasma concentrations of minerals in dairy calves, and 2...

  4. Piezoelectric Characterization of Individual Zinc Oxide Nanobelt Probed

    E-Print Network [OSTI]

    Wang, Zhong L.

    nanobelt is a promising piezoelectric material for nanosensor and nano- actuator applications due to itsPiezoelectric Characterization of Individual Zinc Oxide Nanobelt Probed by Piezoresponse Force piezoelectric coefficient (d33) of an individual (0001) surface dominated zinc oxide nanobelt lying

  5. EFFECTIVENESS OF COPPER AND BRONZE FOR ZINC CAPTURE

    SciTech Connect (OSTI)

    Korinko, P. S.

    2012-11-02

    A series of experiments was conducted to determine the efficacy of using copper and bronze sheet and screen under high vacuum conditions to capture zinc vapor. The experiments were conducted in a parametric manner using a fixed zinc vaporization temperature (350°C) but varying the filter temperature from ambient to 550°C. Consistent with previous work, metallic zinc was deposited at low temperatures, but the deposit was non?adherent. At an intermediate temperature range (350?450°C), the deposit formed an alloy with both copper and bronze materials. At higher temperatures (> 500°C) the zinc did not deposit on the surfaces likely due to its high vapor pressure. Additional testing to optimize the zinc 'getter' chemistry and surface condition is warranted.

  6. Intermolecular CH bond activation of benzene and pyridines by a vanadium(III) alkylidene including a stepwise conversion of benzene to

    E-Print Network [OSTI]

    Baik, Mu-Hyun

    Intermolecular C­H bond activation of benzene and pyridines by a vanadium(III) alkylidene including a stepwise conversion of benzene to a vanadium-benzyne complex Jose G. Andino,a Uriah J. Kilgore,a Maren Pink of benzene and pyridine is observed with (PNP)V(CH2tBu)2 (1), and in the case of benzene, the formation

  7. High Performance Vanadium Redox Flow Batteries with Optimized Electrode Configuration and Membrane Selection

    SciTech Connect (OSTI)

    Liu, Q. H. [University of Tennessee, Knoxville (UTK); Grim, G. M. [University of Tennessee, Knoxville (UTK); Papandrew, A [University of Tennessee, Knoxville (UTK); Turhan, A. [University of Tennessee, Knoxville (UTK); Zawodzinski, Thomas A [ORNL; Mench, Matthew M [ORNL

    2012-01-01

    The performance of a vanadium flow battery with no-gap architecture was significantly improved via several techniques. Specifically, gains arising from variation of the overall electrode thickness, membrane thickness, and electrode thermal treatment were studied. There is a trade-off between apparent kinetic losses, mass transfer losses, and ionic resistance as the electrode thickness is varied at the anode and cathode. Oxidative thermal pretreatment of the carbon paper electrode increased the peak power density by 16%. Results of the pretreatment in air showed greater improvement in peak power density compared to that obtained with pretreatment in an argon environment. The highest peak power density in a VRB yet published to the author s knowledge was achieved at a value of 767 mW cm 2 with optimized membrane and electrode engineering. 2012 The Electrochemical Society. [DOI: 10.1149/2.051208jes] All rights reserved.

  8. Cycling performance and efficiency of sulfonated poly(sulfone) membranes in vanadium redox flow batteries

    SciTech Connect (OSTI)

    Kim, Soowhan; Yan, Jingling; Schwenzer, Birgit; Zhang, Jianlu; Li, Liyu; Liu, Jun; Yang, Zhenguo; Hickner, Michael A.

    2010-11-30

    As an alternative to the expensive Nafion® ion exchange membrane, an inexpensive commercially-available Radel® polymer was sulfonated, fabricated into a thin membrane, and evaluated for its performance in a vanadium redox flow battery (VRFB). The sulfonated Radel (S-Radel) membrane showed almost an order of magnitude lower permeability of V (IV) ions (2.07×10-7 cm2/min), compared to Nafion 117 (1.29×10-6 cm2/min), resulting in better coulombic efficiency (~98% vs. 95% at 50 mA/cm2) and lower capacity loss per cycle. Even though the S-Radel membrane had slightly higher membrane resistance, the energy efficiency of the VRFB with the S-Radel membrane was comparable to that of Nafion due to its better coulombic efficiency. The S-Radel membrane exhibited good performance up to 40 cycles, but a decay in performance at later cycles was observed.

  9. Nitrogen-doped mesoporous carbon for energy storage in vanadium redox flow batteries

    SciTech Connect (OSTI)

    Shao, Yuyan; Wang, Xiqing; Engelhard, Mark H.; Wang, Chong M.; Dai, Sheng; Liu, Jun; Yang, Zhenguo; Lin, Yuehe

    2010-03-22

    We demonstrate a novel electrode material?nitrogen-doped mesoporous carbon (NMC)?for vanadium redox flow batteries. Mesoporous carbon (MC) is prepared using a soft-template method and doped with nitrogen by heat-treating MC in NH3. NMC is characterized with X-ray photoelectron spectroscopy and transmission electron microscopy. The redox reaction of VO2+/VO2+ is characterized with cyclic voltammetry and electrochemical impedance spectroscopy. The electrocatalytic kinetics of the redox couple VO2+/VO2+ is significantly enhanced on NMC electrode compared with MC and graphite electrodes. The reversibility of the redox couple VO2+/VO2+ is greatly improved on NMC (0.61 for NMC vs. 0.34 for graphite). Nitrogen doping facilitates the electron transfer on the electrode/electrolyte interface for both oxidation and reduction processes. NMC is a promising electrode material for redox flow batteries.

  10. Effect of neutron irradiation on the tensile properties and microstructure of several vanadium alloys

    SciTech Connect (OSTI)

    Braski, D.N.

    1986-01-01

    Specimens of V-15Cr-5Ti, VANSTAR-7, and V-3Ti-1Si were encapsulated in TZM tubes containing /sup 7/Li to prevent interstitial pickup and irradiated in FFTF (MOTA experiment) to a damage level of 40 dpa. The irradiation temperatures were 420, 520, and 600/sup 0/C. For a better simulation of fusion reactor conditions, helium was preimplanted in some specimens using a modified version of the ''tritium trick.'' The V-15Cr-5Ti alloy was most susceptible to irradiation hardening and helium embrittlement, followed by VANSTAR-7 and V-3Ti-1Si. VANSTAR-7 exhibited a relatively high maximum void swelling of approx.6% at 520/sup 0/C while V-15Cr-5Ti and V-3Ti-1Si had values of less than 0.3% at all three temperatures. The V-3Ti-1Si clearly outperformed the other two vanadium alloys in resisting the effects of neutron irradiation.

  11. Thermally driven analog of the Barkhausen effect at the metal-insulator transition in vanadium dioxide

    SciTech Connect (OSTI)

    Huber-Rodriguez, Benjamin; Ji, Heng; Chen, Chih-Wei [Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States); Kwang, Siu Yi [Department of Physics, National University of Singapore, Singapore 117551 (Singapore); Hardy, Will J. [Applied Physics Program, Rice Quantum Institute, Rice University, Houston, Texas 77005 (United States); Morosan, Emilia [Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States); Department of Chemistry, Rice University, Houston, Texas 77005 (United States); Department of Materials Science and Nanoengineering, Rice University, Houston, Texas 77005 (United States); Natelson, Douglas [Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States); Department of Materials Science and Nanoengineering, Rice University, Houston, Texas 77005 (United States); Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States)

    2014-09-29

    The physics of the metal-insulator transition (MIT) in vanadium dioxide remains a subject of intense interest. Because of the complicating effects of elastic strain on the phase transition, there is interest in comparatively strain-free means of examining VO{sub 2} material properties. We report contact-free, low-strain studies of the MIT through an inductive bridge approach sensitive to the magnetic response of VO{sub 2} powder. Rather than observing the expected step-like change in susceptibility at the transition, we argue that the measured response is dominated by an analog of the Barkhausen effect, due to the extremely sharp jump in the magnetic response of each grain as a function of time as the material is cycled across the phase boundary. This effect suggests that future measurements could access the dynamics of this and similar phase transitions.

  12. Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics

    SciTech Connect (OSTI)

    Sathish, M.; Eraiah, B.

    2014-04-24

    Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400°C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

  13. Electrochemical Aging of Thermal-Sprayed Zinc Anodes on Concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Bullard, S.J.; Covino, B.S. Jr.; Cramer, S.D.; Cryer, C.B.; McGill, G.E.

    1996-10-01

    Thermal-sprayed zinc anodes are used in impressed current cathodic protection systems for some of Oregon's coastal reinforced concrete bridges. Electrochemical aging of zinc anodes results in physical and chemical changes at the zinc-concrete interface. Concrete surfaces heated prior to thermal-spraying had initial adhesion strengths 80 pct higher than unheated surfaces. For electrochemical aging greater than 200 kC/m{sup 2} (5.2 A h/ft{sup 2}), there was no difference in adhesion strengths for zinc on preheated and unheated concrete. Adhesion strengths decreased monotonically after about 400 to 600 kC/m{sup 2} (10.4 to 15.6 A-h/ft{sup 2}) as a result of the reaction zones at the zinc-concrete interface. A zone adjacent to the metallic zinc (and originally part of the zinc coating) was primarily zincite (ZnO), with minor constituents of wulfingite (Zn(OH){sub 2}), simonkolleite (Zn{sub 5}(OH) {sub 8}C{sub l2}{sup .}H{sub 2}O), and hydrated zinc hydroxide sulfates (Zn{sub 4}SO{sub 4}(OH){sub 6}{sup .}xH{sub 2}O). This zone is the locus for cohesive fracture when the zinc coating separates from the concrete during adhesion tests. Zinc ions substitute for calcium in the cement paste adjacent to the coating as the result of secondary mineralization. The initial estimate of the coating service life based on adhesion strength measurements in accelerated impressed current cathodic protection tests is about 27 years.

  14. UV irradiation-induced zinc dissociation from commercial zinc oxide sunscreen and its action in human epidermal keratinocytes

    E-Print Network [OSTI]

    Li, Yang V.

    UV irradiation-induced zinc dissociation from commercial zinc oxide sunscreen and its actionO in commercial sunscreens under ultraviolet type B light (UVB) irradiation and assessed the cytotoxicity of Zn2 a significant increase in Zn2+ when ZnO sunscreens were irradiated by UVB light. The amount of Zn2+ increase

  15. Hybrid Zinc Phthalocyanine/Zinc Oxide System for Photovoltaic De-vices: a DFT and TDDFPT Theoretical Investigation

    E-Print Network [OSTI]

    Giannozzi, Paolo

    Hybrid Zinc Phthalocyanine/Zinc Oxide System for Photovoltaic De- vices: a DFT and TDDFPT in the functioning of hybrid photovoltaic devices. The molecule-surface interactions are also characterized-inorganic photovoltaic devices (OPV and HPV, respectively) have received enormous re- search attention in the last years

  16. Development of alkaline zinc/ferricyanide battery

    SciTech Connect (OSTI)

    Hollandsworth, R.P.; Adams, G.B.; Webber

    1983-08-01

    The zinc/ferro-ferricyanide battery system is intended for utility load leveling and solar photovoltaic/wind applications with advantages of high cyclic efficiency, high cell voltage, random cycling without zinc strip cycles and with switching times of less than 5 ms from load to insolation or vice versa. Self-discharge has been measured at 1.6%/day. The system demonstrates excellent electrochemical performance. Cell voltages are 1.88 V OCV and 1.61 V discharge at 35 mA/cm/sup 2/ or 57 mW/cm/sup 2/ in 2N NaOH at 40/sup 0/C (Nafion N-125 separator). Cell polarization losses are almost entirely resistive and within the separator. Over 800 4-hr cycles have been demonstrated in cell of 60-cm/sup 2/ nominal area (70 mA.h/cm/sup 2/ capacity) with mean energy efficiency of 76.6 + or - 2.1 percent). Similarly, a 60-cm/sup 2/ cell has demonstrated over 220, 11 to 17 hour cycles (255 + or - 48 mA.h/cm/sup 2/ capacity) with a mean energy efficiency of 75.3 + or - 5.1 percent.

  17. TOTAL ANNUAL Rent / Mortgage $

    E-Print Network [OSTI]

    Snider, Barry B.

    etc.) $ Child Care Expenses $ Educational Loans taken out in parent's name $ Other (itemize below): $ $ RESOURCES TOTAL ANNUAL AMOUNT Parent 1 Wages $ Parent 2 Wages $ Interest and/or Dividend Income $ Net Income $ Contributions to tax deferred plans(401K) $ Non Educational Veterans' Benefits $ Unemployment Compensation

  18. Total Sustainability Humber College

    E-Print Network [OSTI]

    Thompson, Michael

    1 Total Sustainability Management Humber College November, 2012 SUSTAINABILITY SYMPOSIUM Green An Impending Global Disaster #12;3 Sustainability is NOT Climate Remediation #12;Our Premises "We cannot, you cannot improve it" (Lord Kelvin) "First rule of sustainability is to align with natural forces

  19. Zinc surface complexes on birnessite: A density functional theory study

    SciTech Connect (OSTI)

    Kwon, Kideok D.; Refson, Keith; Sposito, Garrison

    2009-01-05

    Biogeochemical cycling of zinc is strongly influenced by sorption on birnessite minerals (layer-type MnO2), which are found in diverse terrestrial and aquatic environments. Zinc has been observed to form both tetrahedral (Zn{sup IV}) and octahedral (Zn{sup VI}) triple-corner-sharing surface complexes (TCS) at Mn(IV) vacancy sites in hexagonal birnessite. The octahedral complex is expected to be similar to that of Zn in the Mn oxide mineral, chalcophanite (ZnMn{sub 3}O{sub 7} {center_dot} 3H{sub 2}O), but the reason for the occurrence of the four-coordinate Zn surface species remains unclear. We address this issue computationally using spin-polarized Density Functional Theory (DFT) to examine the Zn{sub IV}-TCS and Zn{sup VI}-TCS species. Structural parameters obtained by DFT geometry optimization were in excellent agreement with available experimental data on Zn-birnessites. Total energy, magnetic moments, and electron-overlap populations obtained by DFT for isolated Zn{sup IV}-TCS revealed that this species is stable in birnessite without a need for Mn(III) substitution in the octahedral sheet and that it is more effective in reducing undersaturation of surface O at a Mn vacancy than is Zn{sub VI}-TCS. Comparison between geometry-optimized ZnMn{sub 3}O{sub 7} {center_dot} 3H{sub 2}O (chalcophanite) and the hypothetical monohydrate mineral, ZnMn{sub 3}O{sub 7} {center_dot} H{sub 2}O, which contains only tetrahedral Zn, showed that the hydration state of Zn significantly affects birnessite structural stability. Finally, our study also revealed that, relative to their positions in an ideal vacancy-free MnO{sub 2}, Mn nearest to Zn in a TCS surface complex move toward the vacancy by 0.08-0.11 {angstrom}, while surface O bordering the vacancy move away from it by 0.16-0.21 {angstrom}, in agreement with recent X-ray absorption spectroscopic analyses.

  20. Zinc-bromine battery development, Sandia Contract 48-8838

    SciTech Connect (OSTI)

    Richards, L.; Vanschalwijk, W.; Albert, G.; Tarjanyi, M.; Leo, A. ); Lott, S. )

    1990-05-01

    This report describes development activities on the zinc-bromine battery system conducted by Energy Research Corporation (ERC). The project was a cost-shared program supported by the US Department of Energy and managed through Sandia. The project began in September 1985 and ran through January 1990. The zinc-bromine battery has been identified as a promising alternative to conventional energy storage options for many applications. The low cost of the battery reactants and the potential for long life make the system an attractive candidate for bulk energy storage applications, such as utility load leveling. The battery stores energy by the electrolysis of an aqueous zinc bromide salt to zinc metal and dissolved bromine. Zinc is plated as a layer on the electrode surface while bromine is dissolved in the electrolyte and carried out of the stack. The bromine is then extracted from the electrolyte with an organic complexing agent in the positive electrolyte storage tank. On discharge the zinc and bromine are consumed, regenerating the zinc bromide salt. 5 refs., 44 figs.

  1. Electrochemical synthesis and characterization of zinc oxalate nanoparticles

    SciTech Connect (OSTI)

    Shamsipur, Mojtaba, E-mail: mshamsipur@yahoo.com [Department of Chemistry, Razi University, Kermanshah (Iran, Islamic Republic of); Roushani, Mahmoud [Department of Chemistry, Razi University, Kermanshah (Iran, Islamic Republic of); Department of Chemistry, Ilam University, Ilam (Iran, Islamic Republic of); Pourmortazavi, Seied Mahdi [Faculty of Material and Manufacturing Technologies, Malek Ashtar University of Technology, Tehran (Iran, Islamic Republic of)

    2013-03-15

    Highlights: ? Synthesis of zinc oxalate nanoparticles via electrolysis of a zinc plate anode in sodium oxalate solutions. ? Design of a Taguchi orthogonal array to identify the optimal experimental conditions. ? Controlling the size and shape of particles via applied voltage and oxalate concentration. ? Characterization of zinc oxalate nanoparticles by SEM, UV–vis, FT-IR and TG–DTA. - Abstract: A rapid, clean and simple electrodeposition method was designed for the synthesis of zinc oxalate nanoparticles. Zinc oxalate nanoparticles in different size and shapes were electrodeposited by electrolysis of a zinc plate anode in sodium oxalate aqueous solutions. It was found that the size and shape of the product could be tuned by electrolysis voltage, oxalate ion concentration, and stirring rate of electrolyte solution. A Taguchi orthogonal array design was designed to identify the optimal experimental conditions. The morphological characterization of the product was carried out by scanning electron microscopy. UV–vis and FT-IR spectroscopies were also used to characterize the electrodeposited nanoparticles. The TG–DTA studies of the nanoparticles indicated that the main thermal degradation occurs in two steps over a temperature range of 350–430 °C. In contrast to the existing methods, the present study describes a process which can be easily scaled up for the production of nano-sized zinc oxalate powder.

  2. Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium Redox Flow Battery Electrolytes

    SciTech Connect (OSTI)

    Vijayakumar, M.; Li, Liyu; Nie, Zimin; Yang, Zhenguo; Hu, Jian Z.

    2012-05-09

    The Vanadium (III) cation structure in mixed acid based electrolyte solution from vanadium redox flow batteries were studied by 17O and 35/37Cl Nuclear Magnetic Resonance (NMR) spectroscopy, electronic spectroscopy and density functional theory (DFT) based computational modeling. Both computational and experimental results reveals that the V(III) species can complex with counter anions (sulfate/chlorine) 10 depend on the composition of its solvation sphere. By analyzing the powder precipitate it was found that the formation of sulfate complexed V(III) species is the crucial process in the precipitation reaction. The precipitation occurs through nucleation of neutral species formed through deprotonation and ion-pair formation process. However, the powder precipitate shows a multiphase nature which warrants multiple reaction pathways for precipitation reaction.

  3. Regeneration of zinc halide catalyst used in the hydrocracking of polynuclear hydrocarbons

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA)

    1978-01-01

    Improved recovery of spent molten zinc halide hydro-cracking catalyst is achieved in the oxidative vapor phase regeneration thereof by selective treatment of the zinc oxide carried over by the effluent vapors from the regeneration zone with hydrogen halide gas under conditions favoring the reaction of the zinc oxide with the hydrogen halide, whereby regenerated zinc halide is recovered in a solids-free state with little loss of zinc values.

  4. Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

    2013-09-02

    Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

  5. Cadmium zinc sulfide by solution growth

    DOE Patents [OSTI]

    Chen, Wen S. (Seattle, WA)

    1992-05-12

    A process for depositing thin layers of a II-VI compound cadmium zinc sulfide (CdZnS) by an aqueous solution growth technique with quality suitable for high efficiency photovoltaic or other devices which can benefit from the band edge shift resulting from the inclusion of Zn in the sulfide. A first solution comprising CdCl.sub.2 2.5H.sub.2 O, NH.sub.4 Cl, NH.sub.4 OH and ZnCl.sub.2, and a second solution comprising thiourea ((NH.sub.2).sub.2 CS) are combined and placed in a deposition cell, along with a substrate to form a thin i.e. 10 nm film of CdZnS on the substrate. This process can be sequentially repeated with to achieve deposition of independent multiple layers having different Zn concentrations.

  6. Zinc oxide thin film acoustic sensor

    SciTech Connect (OSTI)

    Mohammed, Ali Jasim; Salih, Wafaa Mahdi; Hassan, Marwa Abdul Muhsien; Nusseif, Asmaa Deiaa; Kadhum, Haider Abdullah [Department of Physics , College of Science, Al-Mustansiriyah University, Baghdad (Iraq); Mansour, Hazim Louis [Department of Physics , College of Education, Al-Mustansiriyah University, Baghdad (Iraq)

    2013-12-16

    This paper reports the implementation of (750 nm) thickness of Zinc Oxide (ZnO) thin film for the piezoelectric pressure sensors. The film was prepared and deposited employing the spray pyrolysis technique. XRD results show that the growth preferred orientation is the (002) plane. A polycrystalline thin film (close to mono crystallite like) was obtained. Depending on the Scanning Electron Microscopy photogram, the film homogeneity and thickness were shown. The resonance frequency measured (about 19 kHz) and the damping coefficient was calculated and its value was found to be about (2.5538), the thin film be haves as homogeneous for under and over damped. The thin film pressure sensing was approximately exponentially related with frequency, the thin film was observed to has a good response for mechanical stresses also it is a good material for the piezoelectric properties.

  7. Development of alkaline zinc/ferricyanide battery

    SciTech Connect (OSTI)

    Hollandsworth, R.P.; Adams, G.B.; Webber, B.D.

    1983-01-01

    The zinc/ferro-ferricyanide battery system is intended for utility load leveling and solar photovoltaic/wind applications with advantages of high cyclic efficiency, high cell voltage, near-ambient temperature operation, flowing alkaline electrolyte, low toxicity, potentially long cycle life and low projected capital costs. The system demonstrates excellent electrochemical performance. Cell voltages are 1.88 V OCV and 1.61 V discharge at 35 mA/cm/sup 2/ or 57 mW/cm/sup 2/ in 2N NaOH at 40/sup 0/C (Nafion N-125 separator). Cell polarization losses are almost entirely resistive, and, within the separator. Over 800 4-h cycles have been demonstrated in cell of 60-cm/sup 2/ nominal area (70 ma.h/cm/sup 2/ capacity) with mean energy efficiency of 76.6 +- 2.1%. Similarly, a 60-cm/sup 2/ cell has demonstrated over 220, 11 to 17 hour cycles (255 +- 48 mA.h/cm/sup 2/ capacity) with a mean energy efficiency of 75.3+-5.1%. Solar acceptability has been demonstrated with random cycling without zinc strip cycles and with typical switching times of less than 5 ms for switching from load to insolation or vice versa. The self-discharge rate has been measured at 1.6%/day. Criteria for separator selection have been established and compatibility with alkaline ferricyanide has been found to be the factor determining membrane life with resistance and electrolyte transference rate, as secondary factors.

  8. Total Crude by Pipeline

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearbyWithdrawalsHome6,672(MillionFeet)Product: Total

  9. Zinc-catalyzed copolymerization of carbon dioxide and propylene oxide 

    E-Print Network [OSTI]

    Katsurao, Takumi

    1994-01-01

    The zinc-catalyzed copolymerization of carbon dioxide and propylene oxide, which is one of the promising reactions for the utilization of carbon dioxide, has been investigated from various aspects. Above all, considering ...

  10. The effects of alcohol use on zinc status 

    E-Print Network [OSTI]

    Chapman, Lisa Louise

    1998-01-01

    Alcohol consumption has been shown to have adverse affects on bone growth and maintenance, although the mechanism has not been elucidated. The objective of this research was to look at the relationship between zinc and alcohol as a possible...

  11. DEVELOPMENT OF A MICROPATTERNED ELECTRODE FOR STUDIES OF ZINC ELECTRODEPOSITION

    E-Print Network [OSTI]

    Sutija, D.P.

    2011-01-01

    1976), pp. 44-50. Pourbaix, M. Atlas of Electrochemicalmixture According to Pourbaix, "a protective coating,. ofZ XBL 8611-9285 Zinc Pourbaix diagramo a) without carbonate

  12. Acetone sensor based on zinc oxide hexagonal tubes

    SciTech Connect (OSTI)

    Hastir, Anita, E-mail: anitahastir@gmail.com; Singh, Onkar, E-mail: anitahastir@gmail.com; Anand, Kanika, E-mail: anitahastir@gmail.com; Singh, Ravi Chand, E-mail: anitahastir@gmail.com [Department of Physics, Guru Nanak Dev University, Amritsar-143005, Punjab (India)

    2014-04-24

    In this work hexagonal tubes of zinc oxide have been synthesized by co-precipitation method. For structural, morphological, elemental and optical analysis synthesized powders were characterized by using x-ray diffraction, field emission scanning microscope, EDX, UV-visible and FTIR techniques. For acetone sensing thick films of zinc oxide have been deposited on alumina substrate. The fabricated sensors exhibited maximum sensing response towards acetone vapour at an optimum operating temperature of 400°C.

  13. Selective oxidation of n-butane and butenes over vanadium-containing catalysts

    SciTech Connect (OSTI)

    Nieto, J.M.L.; Concepcion, P.; Dejoz, A.; Knoezinger, H.; Melo, F.; Vazquez, M.I.

    2000-01-01

    The oxidative dehydrogenation (OXDH) of n-butane, 1-butene, and trans-2-butene on different vanadia catalysts has been compared. MgO, alumina, and Mg-Al mixed oxides with Mg/(Al + Mg) ratios of 0.25 and 0.75 were used as supports. The catalytic data indicate that the higher the acid character of catalysts the lower is both the selectivity to C{sub 4}-olefins from n-butane and the selectivity to butadiene from both 1-butene or trans-2-butene. Thus, OXDH reactions are mainly observed from n-butane and butenes on basic catalysts. The different catalytic performance of both types of catalysts is a consequence of the isomerization of olefins on acid sites, which appears to be a competitive reaction with the selective way, i.e., the oxydehydrogenation process by a redox mechanism. Infrared spectroscopy data of 1-butene adsorbed on supported vanadium oxide catalysts suggest the presence of different adsorbed species. O-containing species (carbonyl and alkoxide species) are observed on catalysts with acid sites while adsorbed butadiene species are observed on catalysts with basic sites. According to these results a reaction network for the oxydehydrogenation of n-butane is proposed with parallel and consecutive reactions.

  14. Thin-film encapsulation of the air-sensitive organic-based ferrimagnet vanadium tetracyanoethylene

    SciTech Connect (OSTI)

    Froning, I. H.; Harberts, M.; Yu, H.; Johnston-Halperin, E.; Lu, Y.; Epstein, A. J.

    2015-03-23

    The organic-based ferrimagnet vanadium tetracyanoethylene (V[TCNE]{sub x?2}) has demonstrated potential for use in both microwave electronics and spintronics due to the combination of high temperature magnetic ordering (T{sub C}?>?600?K), extremely sharp ferromagnetic resonance (peak to peak linewidth of 1?G), and low-temperature conformal deposition via chemical vapor deposition (deposition temperature of 50?°C). However, air-sensitivity leads to the complete degradation of the films within 2?h under ambient conditions, with noticeable degradation occurring within 30 min. Here, we demonstrate encapsulation of V[TCNE]{sub x?2} thin films using a UV-cured epoxy that increases film lifetime to over 710 h (30 days) as measured by the remanent magnetization. The saturation magnetization and Curie temperature decay more slowly than the remanence, and the coercivity is unchanged after 340 h (14 days) of air exposure. Fourier transform infrared spectroscopy indicates that the epoxy does not react with the film, and magnetometry measurements show that the presence of the epoxy does not degrade the magnetic properties. This encapsulation strategy directly enables a host of experimental protocols and investigations not previously feasible for air-sensitive samples and lays the foundation for the development of practical applications for this promising organic-based magnetic material.

  15. Composite blend polymer membranes with increased proton selectivity and lifetime for vanadium redox flow batteries

    SciTech Connect (OSTI)

    Chen, Dongyang; Kim, Soowhan; Sprenkle, Vincent L.; Hickner, Michael A.

    2013-06-01

    Composite membranes based on sulfonated fluorinated poly(arylene ether) (SFPAE) and poly(vinylidene fluoride-co-hexafluoropropene) (P(VDF-co-HFP)) were prepared with various contents of P(VDF-co-HFP) for vanadium redox flow battery (VRFB) applications. The compatibility and interaction of SFPAE and P(VDF-co-HFP) were characterized by atomic force microscopy, differential scanning calorimetry, and Fourier transform infrared spectroscopy. The water uptake, mechanical properties, thermal property, proton conductivity, VO2+ permeability and cell performance of the composite membranes were investigated in detail and compared to the pristine SFPAE membrane. It was found that SFPAE had good compatibility with P(VDF-co-HFP) and the incorporation of P(VDF-co-HFP) increased the mechanical properties, thermal property, and proton selectivity of the materials effectively. An SFPAE composite membrane with 10 wt.% P(VDF-co-HFP) exhibited a 44% increase in VRFB cell lifetime as compared to a cell with a pure SFPAE membrane. Therefore, the P(VDF-co-HFP) blending approach is a facile method for producing low-cost, high-performance VRFB membranes.

  16. Nitrogen-doped mesoporous carbon for energy storage in vanadium redox flow batteries

    SciTech Connect (OSTI)

    Dai, Sheng [ORNL; Shao, Yuyan [Pacific Northwest National Laboratory (PNNL); Wang, Xiqing [ORNL; Engelhard, Mark H [Pacific Northwest National Laboratory (PNNL); Wang, Congmin [ORNL; Liu, Jun [Pacific Northwest National Laboratory (PNNL); YANG, ZHENGUO [Pacific Northwest National Laboratory (PNNL); Lin, Yuehe [ORNL

    2010-01-01

    We demonstrate an excellent performance of nitrogen-doped mesoporous carbon (N-MPC) for energy storage in vanadium redox flow batteries. Mesoporous carbon (MPC) is prepared using a soft-template method and doped with nitrogen by heat-treating MPC in NH{sub 3}. N-MPC is characterized with X-ray photoelectron spectroscopy and transmission electron microscopy. The redox reaction of [VO]{sup 2+}/[VO{sub 2}]{sup +} is characterized with cyclic voltammetry and electrochemical impedance spectroscopy. The electrocatalytic kinetics of the redox couple [VO]{sup 2+}/[VO{sub 2}]{sup +} is significantly enhanced on N-MPC electrode compared with MPC and graphite electrodes. The reversibility of the redox couple [VO]{sup 2+}/[VO{sub 2}]{sup +} is greatly improved on N-MPC (0.61 for N-MPC vs. 0.34 for graphite), which is expected to increase the energystorage efficiency of redoxflowbatteries. Nitrogen doping facilitates the electron transfer on electrode/electrolyte interface for both oxidation and reduction processes. N-MPC is a promising material for redoxflowbatteries. This also opens up new and wider applications of nitrogen-doped carbon.

  17. Growth of oriented vanadium pentaoxide nanostructures on transparent conducting substrates and their applications in photocatalysis

    SciTech Connect (OSTI)

    Liu, Hongjiang; Gao, Yanfeng; Zhou, Jiadong; Liu, Xinling; Chen, Zhang; Cao, Chuanxiang; Luo, Hongjie; Kanehira, Minoru

    2014-06-01

    A novel, hydrothermal and hard-template-free method was developed for the first time to grow oriented, single-crystalline monoclinic VO{sub 2} (B) flower-like nanorod films on transparent conductive fluorine-doped tin oxide (FTO) substrates. The length and morphology of the nanorods can be tuned by changing the growth parameters, such as growth time and initial precursor concentration. The flower-like V{sub 2}O{sub 5} films were obtained after post-calcination treatment of VO{sub 2} (B) films. The photocatalytic activity of V{sub 2}O{sub 5} films was investigated by the degradation of methylene blue (MB) under UV and visible light. The prepared V{sub 2}O{sub 5} film exhibited good photocatalytic performance (74.6% and 63% under UV and visible light for 210 min, respectively) and more practical application in industry. - Graphical abstract: Flower nanostructured vanadium oxide film was prepared by hydrothermal reaction for photocatalysis application. - Highlights: • Monoclinic VO{sub 2} nanorod array and flower-like nanostructure were directly grown on FTO substrate by hydrothermal reaction. • The growth mechanism was analyzed by FESEM at different time. • V{sub 2}O{sub 5} flower-like nanostructure film was obtained after calcining VO{sub 2} film. • V{sub 2}O{sub 5} film exhibited good light activity and potential application in photocatalysis.

  18. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  19. EFFECT OF FILTER TEMPERATURE ON TRAPPING ZINC VAPOR

    SciTech Connect (OSTI)

    Korinko, P.

    2011-03-25

    To address the {sup 65}Zn contamination issue in the TEF, a multi-task experimental program was initiated. The first experimental task was completed and is reported in Ref. 1. The results of the second experimental task are reported here. This task examined the effect of filter temperature on trapping efficiency and deposit morphology. Based on the first experimental tasks that examined filter pore size and trapping efficiency, stainless steel filter media with a 20 {micro}m pore size was selected. A series of experiments using these filters was conducted during this second task to determine the effect of filter temperature on zinc vapor trapping efficiency, adhesion and morphology. The tests were conducted with the filters heated to 60, 120, and 200 C; the zinc source material was heated to 400 C for all the experiments to provide a consistent zinc source. The samples were evaluated for mass change, deposit adhesion and morphology. As expected from the physical vapor deposition literature, a difference in deposit morphology and appearance was observed between the three filter temperatures. The filter held at 60 C had the largest average mass gain while the 120 and 200 C filters exhibited similar but lower weight gains. The standard deviations were large and suggest that all three temperatures exhibited comparable gains. No zinc was detected on the backside surface of the filters indicating high efficiency for front and internal trapping. A zinc rich deposit was formed on the surface of the 60 C filter. Based on a simple tape adhesion test, the surface zinc was readily removed from the 60 C filter while less zinc deposit was removed from the 120 and 200 C filter samples. It is surmised that the higher temperatures enable the zinc to deposit within the filter media rather than on the surface. Based on the findings that all three statistically trapped the same quantity of zinc vapor and that the higher temperatures resulted in a more adherent/better trapped product, operating the filters at 120 to 200 C is recommended.

  20. Role of vanadium(V) in the aging of the organic phase in the extraction of uranium(VI) by Alamine 336 from acidic sulfate leach liquors

    SciTech Connect (OSTI)

    Chagnes, A.; Cote, G.; Courtaud, B.; Thiry, J.

    2008-07-01

    The present work is focussed on the chemical degradation of Alamine 336-tridecanol-n-dodecane solvent which used in the recovery of uranium by solvent extraction. Degradation occurs due to the presence of vanadium(V), an oxidant, in the feed solution. After a brief overview of the chemistry of vanadium, the kinetics of degradation of the solvent when contacted with acidic sulfate leach liquor was investigated and interpreted by the Michelis-Menten mechanism. GCMS analyses evidenced the presence of tridecanoic acid and dioctylamine as degradation products. A mechanism of degradation is discussed. (authors)

  1. Zinc Bromide Combustion: Implications for the Consolidated Incinerator Facility

    SciTech Connect (OSTI)

    Oji, L.N.

    1998-12-16

    In the nuclear industry, zinc bromide (ZnBr2) is used for radiation shielding. At Savannah River Site (SRS) zinc bromide solution, in appropriate configurations and housings, was used mainly for shielding in viewing windows in nuclear reactor and separation areas. Waste stream feeds that will be incinerated at the CIF will occasionally include zinc bromide solution/gel matrices.The CIF air pollution systems control uses a water-quench and steam atomizer scrubber that collects salts, ash and trace metals in the liquid phase. Water is re-circulated in the quench unit until a predetermined amount of suspended solids or dissolved salts are present. After reaching the threshold limit, "dirty liquid", also called "blowdown", is pumped to a storage tank in preparation for treatment and disposal. The air pollution control system is coupled to a HEPA pre-filter/filter unit, which removes particulate matter from the flue gas stream (1).The objective of this report is to review existing literature data on the stability of zinc bromide (ZnBr2) at CIF operating temperatures (>870 degrees C (1600 degrees F) and determine what the combustion products are in the presence of excess air. The partitioning of the combustion products among the quencher/scrubber solution, bottom ash and stack will also be evaluated. In this report, side reactions between zinc bromide and its combustion products with fuel oil were not taken into consideration.

  2. Thin film cadmium telluride and zinc phosphide solar cells

    SciTech Connect (OSTI)

    Chu, T.

    1984-10-01

    This report describes research performed from June 1982 to October 1983 on the deposition of cadmium telluride films by direct combination of the cadmium and tellurium vapor on foreign substrates. Nearly stoichiometric p-type cadmium telluride films and arsenic-doped p-type films have been prepared reproducibly. Major efforts were directed to the deposition and characterization of heterojunction window materials, indium tin oxide, fluorine-doped tin oxide, cadmium oxide, and zinc oxide. A number of heterojunction solar cells were prepared, and the best thin-film ITO/CdTe solar cells had an AMl efficiency of about 7.2%. Zinc phosphide films were deposited on W/steel substrates by the reaction of zinc and phosphine in a hydrogen flow. Films without intentional doping had an electrical resistivity on the order of 10/sup 6/ ohm-cm, and this resistivity may be reduced to about 5 x 10/sup 4/ ohm-cm by adding hydrogen chloride or hydrogen bromide to the reaction mixture. Lower resistivity films were deposited by adding a controlled amount of silver nitrate solution on to the substrate surface. Major efforts were directed to the deposition of low-resistivity zinc selenide in order to prepare ZnSe/An/sub 3/P/sub 2/ heterojunction thin-film solar cells. However, zinc selenide films deposited by vacuum evaporation and chemical vapor deposition techniques were all of high resistivity.

  3. First-principle study of geometric stabilities, electronic and magnetic properties of low coverage vanadium adsorption on graphene

    SciTech Connect (OSTI)

    Abdullahi, Yusuf Zuntu [Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia and Department of Physics, Faculty of Science, Kaduna State University, P.M.B. 2339, Kaduna State (Nigeria); Rahman, Md. Mahmudur, E-mail: mahmudur@upm.edu.my [Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia); Zainuddin, H. [Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia and Institute for Mathematical Research, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia); Abubakar, Shamsu [Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia and Department of Physics, Faculty of Science, Yobe State University, P.M.B. 1144, Yobe State (Nigeria)

    2014-03-05

    Stable geometries, electronic and magnetic properties of low coverage vanadium (V) atoms adsorption on graphene sheet have been investigated by first principles calculations, using generalized gradient approximation. Calculation shows that center of the ring is energetically favorable for both V adatom and perpendicular dimer after relaxation. Moreover, the proportion of orbital contribution of C-V bonding are mainly dominated by 2p{sub z} orbital of C and partially occupied by the 3d like states of V. It is also found that the low coverage V atom adsorbed graphene system is metallic and magnetic, and has demonstrated additional hint on its usefulness in magnetic devices.

  4. A NEW CONCEPT IN AN ELECTRICALLY RECHARGEABLE ZINC-AIR ALKALINE BATTERY

    E-Print Network [OSTI]

    Ross, P.N.

    2010-01-01

    Study of a New Zinc-Air Battery Concept Using Flowingdiagram of the zinc-air battery single cell prototype usedDivision . Presented at the Battery and Electrochemical

  5. U.S. Total Exports

    Gasoline and Diesel Fuel Update (EIA)

    Total to Spain Cameron, LA Sabine Pass, LA Total to United Kingdom Sabine Pass, LA LNG Exports from Babb, MT LNG Exports from Buffalo, NY LNG Exports from Kenai, AK LNG Exports...

  6. Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery

    SciTech Connect (OSTI)

    Li, Bin; Gu, Meng; Nie, Zimin; Wei, Xiaoliang; Wang, Chong M.; Sprenkle, Vincent L.; Wang, Wei

    2014-01-01

    Graphite felts (GFs), as typical electrode materials for all vanadium redox flow batteries (VRBs), limit the cell operation to low current density because of their poor kinetic reversibility and electrochemical activity. Here, in order to address this issue we report an electrocatalyst, Nb2O5, decorating the surface of GFs to reduce the activation barrier for redox conversion. Nb2O5 nanofibers with monoclinic phases are synthesized by hydrothermal method and deposited on GFs, which is confirmed to have catalytic effects towards redox couples of V(II)/V(III) at the negative side and V(IV)/V(V) at the positive side, and thus applied in both electrodes of VRB cells. Due to the low conductivity of Nb2O5, the performance of electrodes heavily depends on the nano size and uniform distribution of catalysts on GFs surfaces. The addition of the water-soluble compounds containing W element into the precursor solutions facilitates the precipitation of nanofibers on the GFs. Accordingly, an optimal amount of W-doped Nb2O5 nanofibers with weaker agglomeration and better distribution on GFs surfaces are obtained, leading to significant improvement of the electrochemical performances of VRB cells particularly under the high power operation. The corresponding energy efficiency is enhanced by 10.7 % under the operation of high charge/discharge current density (150 mA•cm-2) owing to faster charge transfer as compared with that without catalysts. These results suggest that Nb2O5 based nanofibers-decorating GFs hold great promise as high-performance electrodes for VRB applications.

  7. Zinc-bromine batteries for bulk energy storage

    SciTech Connect (OSTI)

    Bellows, R.J.; Einstein, H.; Elspass, C.; Grimes, P.; Katner, E.; Malachesky, P.; Newby, K.

    1983-08-01

    The development of a utility bulk energy market has been severely limited by the lack of better energy storage batteries. Lead acid batteries presently dominate the market. However, lead acid batteries suffer various limitations in the area of cost, maintenance, etc. Design projections for zinc-bromine batteries are attractive for bulk energy storage (BES) and electric vehicle (EV) applications in terms of low manufacturing costs and good performance characteristics. Zinc-bromine battery projections compare favorably with both current lead acid batteries and other advanced battery candidates. In recent years, Exxon's zinc-bromine battery program has shown rapid progress in terms of solving system problems and demonstrating both rapid scale-up of the system and competitively low cost manufacturing techniques.

  8. PRELIMINARY STUDY OF METHODS TO CHEMICALLY BIND ZINC

    SciTech Connect (OSTI)

    Korinko, P.

    2011-06-10

    To address the {sup 65}Zn contamination issue in the TEF, a multi-task experimental program was initiated. The first two experimental tasks were completed. The results of the third experimental task are reported here. This task was conducted to determine if the zinc vapors could be chemically bound on two non hydrogen active substrates. Based on a thermodynamic study copper and cobalt were the most favorable for capturing zinc without forming hydrides. Within the experimental parameters tested, which include temperatures of 350, 400, and 450 C at pressures of nominally 20-40 millitorr, the zinc deposited on the both copper screen and cobalt rods but did not react to form a compound. The conditions that were tested are not prototypic and additional testing under higher vacuum conditions, i.e., .01 millitorr, may enhance the reactivity of the surfaces and is recommended.

  9. Separation and Purification Technology 40 (2004) 251257 Copper and zinc sorption by treated oil shale ash

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    2004-01-01

    Jordanian oil shale ash was used as an adsorbent for the removal of copper and zinc from aqueous solution.V. All rights reserved. Keywords: Oil shale; Ash; Adsorption; Copper and zinc removal 1. IntroductionSeparation and Purification Technology 40 (2004) 251­257 Copper and zinc sorption by treated oil

  10. Embrittlement of stainless steel welds by contamination with zinc-rich paint

    SciTech Connect (OSTI)

    Johnson, J.M.; Gutzeit, J.

    1985-01-01

    Contamination of Type 321 stainless steel heater tubes with zinc-rich paint can lead to failures by zinc embrittlement. Following a review of the mechanism of zinc embrittlement, the failure mode is discussed in some detail. Results of laboratory tests are presented, which confirm field observations. Finally a proper cleaning procedure is recommended to alleviate the problem.

  11. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  16. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  17. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, D.S.

    1984-02-16

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  18. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, David S. (Naperville, IL); Yao, Neng-Ping (Clarendon Hills, IL)

    1985-01-01

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  19. Zinc sorption by iron oxides and soil samples 

    E-Print Network [OSTI]

    Yli-Halla, Markku Juhani

    1989-01-01

    'r Subject: Soil Science ZINC SORPTION BY IRON OXIDES AND SOIL SAMPLES A Thesis by MARKKU JUHANI YLI-HALLA Approved as to style and content by: Richard H. Loeppert (Chair of Committee) A. Clearfield (Membe ) Joe B. Dixon (Member) E. C. A. Runge... (Head of Department) May 1989 ABSTRACT Zinc Sorption by Iron Oxides and Soil Samples. (May 1989) Markku Juhani Yli-Halla, M. S. University of Helsinki, Finland Chair of Advisory Committee: Dr. Richard H. Loeppert Zn sorption by synthetic Fe oxide...

  20. Thin film cadmium telluride, zinc telluride, and mercury zinc telluride solar cells

    SciTech Connect (OSTI)

    Chu, T.L. )

    1992-04-01

    This report describes research to demonstrate (1) thin film cadmium telluride solar cells with a quantum efficiency of 75% or higher at 0. 44 {mu}m and a photovoltaic efficiency of 11.5% or greater, and (2) thin film zinc telluride and mercury zinc telluride solar cells with a transparency to sub-band-gap radiation of 65% and a photovoltaic conversion efficiency of 5% and 8%, respectively. Work was directed at (1) depositing transparent conducting semiconductor films by solution growth and metal-organic chemical vapor deposition (MOCVD) technique, (2) depositing CdTe films by close-spaced sublimation (CSS) and MOCVD techniques, (3) preparing and evaluating thin film CdTe solar cells, and (4) preparing and characterizing thin film ZnTe, CD{sub 1-x}Zn{sub 1-x}Te, and Hg{sub 1-x}Zn{sub x}Te solar cells. The deposition of CdS films from aqueous solutions was investigated in detail, and their crystallographic, optical, and electrical properties were characterized. CdTe films were deposited from DMCd and DIPTe at 400{degrees}C using TEGa and AsH{sub 3} as dopants. CdTe films deposited by CSS had significantly better microstructures than those deposited by MOCVD. Deep energy states in CdTe films deposited by CSS and MOCVD were investigated. Thin films of ZnTe, Cd{sub 1- x}Zn{sub x}Te, and Hg{sub 1-x}Zn{sub x}Te were deposited by MOCVD, and their crystallographic, optical, and electrical properties were characterized. 67 refs.

  1. Kinetic study of the oxidation of n-butane on vanadium oxide supported on Al/Mg mixed oxide

    SciTech Connect (OSTI)

    Dejoz, A.; Vazquez, I.; Nieto, J.M.L.; Melo, F.

    1997-07-01

    The reaction kinetics of the oxidative dehydrogenation (ODH) of n-butane over vanadia supported on a heat-treated Mg/Al hydrotalcite (37.3 wt % of V{sub 2}O{sub 5}) was investigated by both linear and nonlinear regression techniques. A reaction network including the formation of butenes (1-, 2-cis-, and 2-trans-butene), butadiene, and carbon oxides by parallel and consecutive reactions, at low and high n-butane conversions, has been proposed. Langmuir-Hinshelwood (LH) models can be used as suitable models which allows reproduction of the global kinetic behavior, although differences between oxydehydrogenation and deep oxidation reactions have been observed. Thus, the formation of oxydehydrogenation products can be described by a LH equation considering a dissociative adsorption of oxygen while the formation of carbon oxides is described by a LH equation with a nondissociative adsorption of oxygen. Two different mechanisms operate on the catalyst: (i) a redox mechanism responsible of the formation of olefins and diolefins and associated to vanadium species, which is initiated by a hydrogen abstraction; (ii) a radical mechanism responsible of the formation of carbon oxides from n-butane and butenes and associated to vanadium-free sites of the support. On the other hand, the selectivity to oxydehydrogenation products increases with the reaction temperature. This catalytic performance can be explained taking into account the low reducibility of V{sup 5+}-sites and the higher apparent activation energies of the oxydehydrogenation reactions with respect to deep oxidation reactions.

  2. The Critical Role of Phosphate in Vanadium Phosphate Oxide for the Catalytic Activation and Functionalization of nButane to Maleic

    E-Print Network [OSTI]

    Goddard III, William A.

    The Critical Role of Phosphate in Vanadium Phosphate Oxide for the Catalytic Activation studies, the mechanism of the catalytic oxidation reaction remains under debate. Some suggest steps for this catalytic system. We propose that the first step of the reaction is the oxidation of (VO

  3. Sol-Gel Synthesis of Vanadium Oxide within a Block Copolymer Elsa A. Olivetti, Jong Hak Kim, Donald R. Sadoway, Ayse Asatekin, and Anne M. Mayes*

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    -transparent. Introduction Hybrid organic/inorganic nanocomposite materials are widely being developed for drug delivery,1Sol-Gel Synthesis of Vanadium Oxide within a Block Copolymer Matrix Elsa A. Olivetti, Jong Hak Kim, Donald R. Sadoway, Ayse Asatekin, and Anne M. Mayes* Department of Materials Science and Engineering

  4. Reactions of Sulfur Dioxide with Neutral Vanadium Oxide Clusters in the Gas Phase. II. Experimental Study Employing Single-Photon Ionization

    E-Print Network [OSTI]

    Rocca, Jorge J.

    presented in part I (J. Phys. Chem. A 2007, 111, 13339). A weak feature at the SO3 mass channel (80 amu to SO3 facilitated by condensed-phase vanadium oxides as catalysts are suggested. I. Introduction for oxidation of SO2 to SO3 (sulfuric acid production, SO2 removal), selective reduction of NOx with NH3

  5. MUJERES TOTAL BIOLOGIA 21 32

    E-Print Network [OSTI]

    Autonoma de Madrid, Universidad

    CIENCIAS ECON�MICAS Y EMPRESARIALES TOTAL DERECHO Nº de tesis leídas y aprobadas por centro y departamento en el año 2014 CENTRO DEPARTAMENTO Nº DE TESIS CIENCIAS MEDICINA TOTAL MEDICINA #12;MUJERES TOTAL Nº de tesis leídas y aprobadas por centro y departamento en el año 2014 CENTRO DEPARTAMENTO Nº DE TESIS

  6. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    1.4 0.4 0.5 1.0 1.2 1.4 2.1 1.3 Table HC5.2 Living Space Characteristics by Year of Construction, 2005 Living Space Characteristics 1970 to 1979 1980 to 1989 1990 to 1999 2000 to...

  7. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    Table HC7.7 Air-Conditioning Usage Indicators by Household Income, 2005 Below Poverty Line Eligible for Federal Assistance 1 2005 Household Income Housing Units (millions)...

  8. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 65.9 3.9 15.1 15.6 11.1 7.0 5.2 8.0 Without a Heat Pump... 53.5 3.5 12.9 12.7 8.6 5.5 4.2 6.2 With a Heat...

  9. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    em... 65.9 51.7 43.9 2.5 0.7 1.6 3.1 Without a Heat Pump... 53.5 41.1 34.8 2.1 0.5 1.2 2.6 With a Heat...

  10. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 65.9 11.0 16.5 13.5 8.7 16.1 6.4 17.2 Without a Heat Pump... 53.5 9.4 13.6 10.7 7.1 12.7 5.4 14.5 With a Heat...

  11. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    1.5 2.3 3.0 6.0 For Two Housing Units... 0.9 0.3 0.4 Q Q N Q 0.4 Heat Pump... 9.2 1.2 2.2 2.0 1.3 2.4 0.6 1.9...

  12. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 65.9 3.7 2.6 6.1 6.8 11.2 13.2 13.9 8.2 Without a Heat Pump... 53.5 3.6 2.3 5.5 5.8 9.5 10.1 10.3 6.4 With a...

  13. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    tem... 65.9 14.1 3.6 1.5 2.1 6.4 0.6 Without a Heat Pump... 53.5 12.4 3.1 1.3 1.8 5.7 0.6 With a Heat...

  14. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    75.6 9.6 18.0 16.4 11.3 20.3 6.4 17.9 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 7.6 14.2 13.1 9.2 14.6 5.0 14.5 Laptop...

  15. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    75.6 30.3 12.5 18.1 14.7 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 22.9 9.8 14.1 11.9...

  16. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 75.6 17.5 12.1 5.4 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 14.1 10.0 4.0...

  17. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    75.6 13.7 17.5 26.6 17.8 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 10.4 14.1 20.5 13.7...

  18. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 75.6 26.6 14.5 4.1 7.9 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 20.5 11.0 3.4 6.1...

  19. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    ... 0.7 Q Q Q Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 11.4 8.1 3.3 Flat-panel...

  20. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    ... 0.7 Q Q Q 0.3 Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 7.9 11.4 15.4 10.2 Flat-panel...

  1. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    ... 0.7 Q Q Q Q Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 2.3 2.5 3.1 4.8...

  2. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    ... 0.7 Q Q Q Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 7.9 5.6 2.4 Flat-panel...

  3. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... 0.7 Q Q Q Q Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 15.4 7.9 2.8 4.8 Flat-panel...

  4. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    ... 0.7 0.3 Q Q Q Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 17.7 7.5 10.2 9.6 Flat-panel...

  5. Total..........................................................

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 75.6 17.8 5.3 12.5 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 13.7 4.2 9.5 Laptop...

  6. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... 0.7 0.3 Q Q Type of Monitor Used on Most-Used PC Desk-top CRT (Standard Monitor)... 45.0 10.2 3.2 7.0 Flat-panel...

  7. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... 75.6 4.2 5.0 5.3 9.0 Most-Used Personal Computer Type of PC Desk-top Model... 58.6 3.2 3.9 4.0 6.7...

  8. Total..........................................................

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1.2 0.5 0.9 3 or More... 0.6 Q Q Q Q Q N Q Plasma Television Sets... 3.6 0.6 0.8 0.5 0.6 1.2 0.3 0.9...

  9. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Q 0.4 3 or More Units... 5.4 0.3 Q Q Central Air-Conditioning Usage Air-Conditioned Floorspace (Square Feet)...

  10. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 1.9 1.1 Q Q 0.3 Q Do Not Use Central Air-Conditioning... 45.2 24.6 3.6 5.0 8.8 3.2 Use a Programmable...

  11. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3 2.9 Q Q Q N For Two Housing Units... 1.4 Q Q 0.5 0.8 N Central Warm-Air Furnace... 2.8 2.4 Q Q Q 0.2 Other...

  12. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 or More Units... 5.4 2.4 1.4 0.7 0.9 Central Air-Conditioning Usage Air-Conditioned Floorspace (Square Feet)...

  13. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    s... 58.2 9.2 4.9 7.8 7.1 8.8 8.4 7.8 4.2 Central Warm-Air Furnace... 44.7 5.2 3.1 5.6 5.2 7.1 7.4 7.3 3.9 For...

  14. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 or More Units... 5.4 2.3 1.7 0.6 Central Air-Conditioning Usage Air-Conditioned Floorspace (Square Feet)...

  15. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 or More Units... 5.4 2.1 0.9 0.2 1.0 Central Air-Conditioning Usage Air-Conditioned Floorspace (Square Feet)...

  16. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    38.9 12.9 Have Equipment But Do Not Use it... 1.9 0.3 Q 0.5 1.0 Air-Conditioning Equipment 1, 2 Central System......

  17. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.3 3 or More Units... 5.4 0.7 0.5 Q Central Air-Conditioning Usage Air-Conditioned Floorspace (Square Feet)...

  18. Total..........................................................

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 or More Units... 5.4 2.3 0.7 2.1 0.3 Central Air-Conditioning Usage Air-Conditioned Floorspace (Square Feet)...

  19. Total..............................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1 86.6

  20. Total................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1

  1. Total........................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1 111.1

  2. Total..........................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1

  3. Total...........................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1Q

  4. Total...........................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1QQ

  5. Total...........................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6 111.1QQ14.7

  6. Total...........................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4 12.55.6

  7. Total............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4

  8. Total............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.4

  9. Total.............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8 20.6 13.1

  10. Total..............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8 20.6

  11. Total..............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8 20.6Do Not

  12. Total...............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8 20.6Do

  13. Total...............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8 20.6Do0.7

  14. Total...............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8

  15. Total...............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do Not Have

  16. Total...............................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do Not

  17. Total................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do Not

  18. Total.................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do Not49.2

  19. Total.................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do

  20. Total.................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do26.7 28.8

  1. Total..................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do26.7

  2. Total..................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do26.733.0

  3. Total..................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7 28.8Do26.733.0.

  4. Total...................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.7

  5. Total...................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.8 1.0 1.2

  6. Total...................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.8 1.0

  7. Total...................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.8 1.0Type

  8. Total...................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.8

  9. Total....................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.814.7 7.4

  10. Total.......................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.814.7

  11. Total.......................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2 7.814.75.6

  12. Total.......................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.2

  13. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.225.6 40.7

  14. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.225.6

  15. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.225.65.6 17.7

  16. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.225.65.6

  17. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7 7.426.715.225.65.64.2

  18. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.7

  19. Total........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.7 22.3 Do

  20. Total.........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.7 22.3

  1. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.7 22.325.6

  2. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.7 22.325.6.

  3. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.7

  4. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.70.7 21.7

  5. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.70.7 21.74.2

  6. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.70.7

  7. Total..........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.70.77.1 19.0

  8. Total...........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.70.77.1

  9. Total...........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0 22.70.77.15.6

  10. Total...........................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0

  11. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0Do Not Have

  12. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0Do Not

  13. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0Do NotCooking

  14. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0Do NotCookingDo

  15. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0Do

  16. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0DoCooking

  17. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0DoCookingDo Not

  18. Total.............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0DoCookingDo

  19. Total..............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 19.0DoCookingDo20.6

  20. Total..............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1

  1. Total..............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1 7.0 8.0

  2. Total..............................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1 7.0 8.07.1

  3. Total.................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1 7.0

  4. Total.................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1 7.07.1 7.0

  5. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1 7.07.1

  6. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1 7.07.15.6

  7. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1

  8. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1Personal

  9. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 7.1Personal4.2

  10. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1

  11. Total....................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 111.1 47.1

  12. Total.........................................................................................

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1 14.77.1 111.1 111.1

  13. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearbyWithdrawalsHome6,672(MillionFeet) Oil4)5,Product:

  14. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearbyWithdrawalsHome6,672(MillionFeet)

  15. RF sputtered piezoelectric zinc oxide thin film for transducer applications

    E-Print Network [OSTI]

    Tang, William C

    parameters that could influence the quality of the resulting films include RF power, the ratio of argon depen- dency of the c-axis zinc oxide growth in radio-frequency sputtering system. Different deposition on the piezoelectric and crystalline qualities of the ZnO thin films. Experimental results showed that the multilayer

  16. Parametric behavior of the circulating zinc-bromine battery

    SciTech Connect (OSTI)

    Kantner, E.; Bellows, R.; Einstein, H.; Grimes, P.; Malachesky, P.; Newby, K.

    1981-01-01

    Graphs are presented depicting polarization data of bipolar batteries of varying capacity ratings, battery voltage vs c/d time of bipolar batteries of varying capacity ratings, Coulomb efficiency vs zinc loading, Coulomb efficiency vs c/d rate, voltage efficiency vs c/d rate, and energy efficiency vs c/d rate.

  17. Process for fabricating doped zinc oxide microsphere gel

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1991-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  18. Chemical vapor deposition of fluorine-doped zinc oxide

    DOE Patents [OSTI]

    Gordon, Roy G. (Cambridge, MA); Kramer, Keith (Avon Lake, OH); Liang, Haifan (Santa Clara, CA)

    2000-06-06

    Fims of fluorine-doped zinc oxide are deposited from vaporized precursor compounds comprising a chelate of a dialkylzinc, such as an amine chelate, an oxygen source, and a fluorine source. The coatings are highly electrically conductive, transparent to visible light, reflective to infrared radiation, absorbing to ultraviolet light, and free of carbon impurity.

  19. Rechargeable alkaline zinc/ferricyanide hybrid redox battery

    SciTech Connect (OSTI)

    Adams, G.B.; Hollandsworth, R.P.; Littauer, E.L.

    1981-01-01

    The zinc/ferricyanide battery system is described for utility load leveling and solar photovoltaic/wind applications, with advantages of high cell voltage, near-ambient temperature operation, flowing alkaline electrolyte, low-cost reactant storage, low toxicity, potentially long cycle life and low projected capital costs. 13 refs.

  20. Process for fabricating doped zinc oxide microsphere gel

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1991-11-05

    Disclosed are a new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  1. Interfacial electron transfer dynamics of photosensitized zinc oxide nanoclusters

    SciTech Connect (OSTI)

    Murakoshi, Kei; Yanagida, Shozo; Capel, M.

    1997-06-01

    The authors have prepared and characterized photosensitized zinc oxide (ZnO) nanoclusters, dispersed in methanol, using carboxylated coumarin dyes for surface adsorption. Femtosecond time-resolved emission spectroscopy allows the authors to measure the photo-induced charge carrier injection rate constant from the adsorbed photosensitizer to the n-type semiconductor nanocluster. These results are compared with other photosensitized semiconductors.

  2. Zinc Adsorption Effects on Arsenite Oxidation Kinetics at the

    E-Print Network [OSTI]

    Sparks, Donald L.

    Zinc Adsorption Effects on Arsenite Oxidation Kinetics at the Birnessite-Water Interface L A U R(III) oxidation. Accordingly, the effects of adsorbed and nonadsorbed Zn on arsenite (As(III)) oxidation kinetics Arsenic often occurs in aquatic/terrestrial environments because of anthropogenic inputs (e.g., use

  3. Zinc-oxide-based sorbents and processes for preparing and using same

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasael (Durham, NC)

    2010-03-23

    Zinc oxide-based sorbents, and processes for preparing and using them are provided. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  4. Zinc oxide-based sorbents and processes for preparing and using same

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar; Turk, Brian Scott; Gupta, Raghubir Prasad

    2005-10-04

    Zinc oxide-based sorbents, and processes for preparing and using them are provided, wherein the sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents contain an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2 O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, containing a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  5. Transient fluctuations of intracellular zinc ions in cell proliferation

    SciTech Connect (OSTI)

    Li, Yuan; Maret, Wolfgang; Department of Anesthesiology, The University of Texas Medical Branch, Galveston, TX 77555

    2009-08-15

    Zinc is essential for cell proliferation, differentiation, and viability. When zinc becomes limited for cultured cells, DNA synthesis ceases and the cell cycle is arrested. The molecular mechanisms of actions of zinc are believed to involve changes in the availability of zinc(II) ions (Zn{sup 2+}). By employing a fluorescent Zn{sup 2+} probe, FluoZin-3 acetoxymethyl ester, intracellular Zn{sup 2+} concentrations were measured in undifferentiated and in nerve growth factor (NGF)-differentiated rat pheochromocytoma (PC12) cells. Intracellular Zn{sup 2+} concentrations are pico- to nanomolar in PC12 cells and are higher in the differentiated than in the undifferentiated cells. When following cellular Zn{sup 2+} concentrations for 48 h after the removal of serum, a condition that is known to cause cell cycle arrest, Zn{sup 2+} concentrations decrease after 30 min but, remarkably, increase after 1 h, and then decrease again to about one half of the initial concentration. Cell proliferation, measured by an MTT [3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide] assay, decreases after both serum starvation and zinc chelation. Two peaks of Zn{sup 2+} concentrations occur within one cell cycle: one early in the G1 phase and the other in the late G1/S phase. Thus, fluctuations of intracellular Zn{sup 2+} concentrations and established modulation of phosphorylation signaling, via an inhibition of protein tyrosine phosphatases at commensurately low Zn{sup 2+} concentrations, suggest a role for Zn{sup 2+} in the control of the cell cycle. Interventions targeted at these picomolar Zn{sup 2+} fluctuations may be a way of controlling cell growth in hyperplasia, neoplasia, and diseases associated with aberrant differentiation.

  6. MUJERES ( * ) TOTAL BIOLOGA 16 22

    E-Print Network [OSTI]

    Autonoma de Madrid, Universidad

    13 INGENIERÍA INFORMÁTICA 2 11 TOTAL ESCUELA POLITÉCNICA SUPERIOR 2 11 ANTROPOLOGÍA SOCIAL Y TEORÍA DEL ARTE 1 1 LINGÜISTICA 4 7 MÚSICA 1 3 PREHISTORIA Y ARQUEOLOGÍA 0 1 TOTAL FILOSOFÍA Y LETRAS 22 Y EMPRESARIALES Fuente: Centro de Estudios de Posgrado, a 9 de Julio del 2010 DERECHO ESCUELA

  7. Visible light photocatalytic degradation of 4-chlorophenol using vanadium and nitrogen co-doped TiO{sub 2}

    SciTech Connect (OSTI)

    Jaiswal, R.; Kothari, D. C.; Patel, N.; Miotello, A.

    2013-02-05

    Vanadium and Nitrogen were codoped in TiO{sub 2} photocatalyst by Sol-gel method to utilize visible light more efficiently for photocatalytic reactions. A noticeable shift of absorption edge to visible light region was obtained for the singly-doped namely V-TiO{sub 2}, N-TiO{sub 2} and codoped V-N-TiO{sub 2} samples in comparison with undoped TiO{sub 2}, with smallest band gap obtained with codoped-TiO{sub 2}. The photocatalytic activities for all TiO{sub 2} photocatalysts were tested by 4-chlorophenol (organic pollutant) degradation under visible light irradiation. It was found that codoped TiO{sub 2} exhibits the best photocatalytic activity, which could be attributed to the synergistic effect produced by V and N dopants.

  8. Synthesis and characterization of vanadium oxide aerogels. Technical report No. 2, 1 June 1994-31 May 1995

    SciTech Connect (OSTI)

    Chaput, F.; Dunn, B.; Fuqua, P.; Salloux, K.

    1995-07-14

    Vanadium pentoxide aerogels were synthesized by supercritical drying with CO2. The aerogels were prepared using a variety of sol compositions from the system VO(OC3H7)3/H2O/acetone. The materials were found to be of fairly low density (0.04g/cu cm to 0.lg/cu cm) with surface areas in the range of 300 to 400 meters squared/g. Chemical and structural studies indicate that the aerogels are hydrated oxides of composition V2O5 nH2O with n = 2.0 to 2.2 and possess a fibrous morphology. When partially dehydrated, the vanadate aerogels exhibit electron transport with conductivity and activation energy values comparable to those of aerogels. Electrochemical measurements demonstrate that lithium can be intercalated reversibly into the structure.

  9. Effects of zinc on Salmonella in the layer house environments and laying hens, and the ability of zinc to induce molt in laying hens 

    E-Print Network [OSTI]

    Park, Shinyoung

    2005-02-17

    or anaerobic conditions, the effects of combinating zinc and acidic conditions on the growth kinetics of Salmonella in vitro under aerobic or anaerobic conditions, and the effects of zinc amended feed on the survival of a dry inoculum of Salmonella. The third...

  10. U.S. Total Exports

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Cameron, LA Sabine Pass, LA Total to United Kingdom Freeport, TX Sabine Pass, LA LNG Exports from Cameron, LA LNG Exports from Kenai, AK LNG Exports from Freeport, TX LNG Exports...

  11. MUJERES ( * ) TOTAL BIOLOGA 18 22

    E-Print Network [OSTI]

    Autonoma de Madrid, Universidad

    DE PROFESORADO Y EDUCACI�N CIENCIAS ECON�MICAS Y EMPRESARIALES Nº de tesis leídas y aprobadas por centro y departamento en el año 2010 CENTRO DEPARTAMENTO Nº TESIS CIENCIAS #12;ANATOMÍA PATOL�GICA 0 1 Y DE LA EDUCACI�N 0 2 PSICOLOGÍA SOCIAL Y METODOLOGÍA 3 8 TOTAL PSICOLOGÍA 11 26 TOTAL TESIS LEIDAS

  12. Total transmission and total reflection by zero index materials

    E-Print Network [OSTI]

    Viet Cuong Nguyen; Lang Chen

    2010-07-01

    In this report, we achieved total transmission and reflection in a slab of zero index materials with defect(s). By controlling the defect's radius and dielectric constant, we can obtain total transmission and reflection of EM wave. The zero index materials, in this report, stand for materials with permittivity and permeability which are simultaneously equal to zero or so called matched impedance zero index materials. Along with theoretical calculations and simulation demonstrations, we also discuss about some possible applications for the proposed structure such as shielding or cloaking an object without restricting its view. We also suggest a way to control total transmission and reflection actively by using tunable refractive index materials such as liquid crystal and BST. The physics behind those phenomena is attributed to intrinsic properties of zero index materials: constant field inside zero index slab.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research Development Center (AMAX R D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  14. Zinc-bromine battery design for electric vehicles

    SciTech Connect (OSTI)

    Bellows, R.; Grimes, P.; Einstein, H.; Kantner, E.; Malachesky, P.; Newby, K.

    1982-01-01

    Design projections for zinc-bromine batteries are attractive for electric vehicle applications in terms of low manufacturing costs ($28/kWh) and good performance characteristics. Zinc-bromine batery projections (60 to 80 Wh/kg, 130 to 200 W/kg) compare favorably to both current lead acid batteries and proposed advanced battery candidates. The performance of recently developed battery components with 1200 cm/sup 2/ electrodes in a 120V, 10 kWh module is described. Similarly constructed smaller scale (600 cm/sup 2/) components have shown lifetimes exceeding 400 cycles and the ability to follow both regenerative braking (J227aD) and random cycling regimes. Initial dynamometer evaluations of full scale 20 kWh batteries is expected in early 1984.

  15. Zinc-bromine battery design for electric vehicles

    SciTech Connect (OSTI)

    Bellows, R.J.; Einstein, H.; Grimes, P.; Kantner, E.; Malachesky, P.; Newby, K.

    1983-02-01

    Design projections for zinc-bromine batteries are attractive for electric vehicle applications in terms of low manufacturing costs ($28/kWh) and good performance characteristics. Zinc-bromine battery projections (60-80 Wh/kg, 130-200 W/kg) compare favorably to both current lead acid batteries and proposed advanced battery candidates. The performance of recently developed battery components with 1200 cm/sup 2/ electrodes in a 120V, 10 kWh module is described. Similarly constructed smaller scale (600 cm/sup 2/) components have shown lifetimes exceeding 400 cycles and the ability to follow both regenerative braking (J227aD) and random cycling regimes. Initial dynamometer evaluations of full scale 20 kWh batteries is expected in early 1984.

  16. Structural and magnetic properties of chromium doped zinc ferrite

    SciTech Connect (OSTI)

    Sebastian, Rintu Mary; Thankachan, Smitha; Xavier, Sheena; Mohammed, E. M., E-mail: emmohammed2005@gmail.com [Research Department of Physics, Maharaja's College, Ernakulam, Kerala (India); Joseph, Shaji [Department of Physic, St. Albert's College, Ernakulam, Kerala (India)

    2014-01-28

    Zinc chromium ferrites with chemical formula ZnCr{sub x}Fe{sub 2?x}O{sub 4} (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared by Sol - Gel technique. The structural as well as magnetic properties of the synthesized samples have been studied and reported here. The structural characterizations of the samples were analyzed by using X – Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), and Transmission Electron Microscope (TEM). The single phase spinel cubic structure of all the prepared samples was tested by XRD and FTIR. The particle size was observed to decrease from 18.636 nm to 6.125 nm by chromium doping and induced a tensile strain in all the zinc chromium mixed ferrites. The magnetic properties of few samples (x = 0.0, 0.4, 1.0) were investigated using Vibrating Sample Magnetometer (VSM)

  17. Solvothermal routes for synthesis of zinc oxide nanorods.

    SciTech Connect (OSTI)

    Bell, Nelson Simmons

    2005-03-01

    Control of the synthesis of nanomaterials to produce morphologies exhibiting quantized properties will enable device integration of several novel applications including biosensors, catalysis, and optical devices. In this work, solvothermal routes to produce zinc oxide nanorods are explored. Much previous work has relied on the addition of growth directing/inhibiting agents to control morphology. It was found in coarsening studies that zinc oxide nanodots will ripen to nanorod morphologies at temperatures of 90 to 120 C. The resulting nanorods have widths of 9-12 nm average dimension, which is smaller than current methods for nanorod synthesis. Use of nanodots as nuclei may be an approach that will allow for controlled growth of higher aspect ratio nanorods.

  18. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  19. Sessile drop studies on polybromide/zinc-bromine battery electrolyte

    SciTech Connect (OSTI)

    Kinoshita, K.; Leach, S.C.

    1982-08-01

    Improvements in the performance of zinc-bromine batteries have been observed with electrolytes containing a quaternary ammonium salt that complexes the bromine to reduce the concentration of free bromine in solution. A variety of quaternary ammonium salts that complex bromine to form a so-called polybromide oil have been considered. Various papers have discussed measurements of the physicochemical properties of the two-component system of bromine-quaternary ammonium bromide in an aqueous medium. The purpose of this paper is to investigate the interfacial tension of polybromide oils on the electrolytes for zinc-bromine batteries by reporting a study of the interfacial tension and contact angle of polybromide oil drops in which the sessile drop method is used. The interfacial tensions for the polybromide phases are found to be considerably lower than the values commonly reported for two-phase systems containing organic and aqueous phases. However, several two-phase systems, such as benzyl alcohol/water, furfural/water, and ethyl acetate/water have low interfacial tension comparable to that of the polybromide/electrolyte system. The low interfacial tension of the polybromide oil phase has important practical implications for the zinc-bromine battery. A stable emulsion can be produced very readily; small drops of the polybromide-oil phase can thus be stabilized with the electrolyte phase and can be expected to enhance the mass transfer of bromine from the polybromide to the electrode.

  20. Advances in total scattering analysis

    SciTech Connect (OSTI)

    Proffen, Thomas E [Los Alamos National Laboratory; Kim, Hyunjeong [Los Alamos National Laboratory

    2008-01-01

    In recent years the analysis of the total scattering pattern has become an invaluable tool to study disordered crystalline and nanocrystalline materials. Traditional crystallographic structure determination is based on Bragg intensities and yields the long range average atomic structure. By including diffuse scattering into the analysis, the local and medium range atomic structure can be unravelled. Here we give an overview of recent experimental advances, using X-rays as well as neutron scattering as well as current trends in modelling of total scattering data.

  1. Flexographically Printed Rechargeable Zinc-based Battery for Grid Energy Storage

    E-Print Network [OSTI]

    Wang, Zuoqian

    2013-01-01

    Integration with photovoltaic cells: Research on integrationother printable photovoltaic cells and electronics. 1.2.of printable photovoltaic cell, zinc-based battery as well

  2. Engineering Scalable Combinational Logic in Escherichia coli Using Zinc Finger Proteins

    E-Print Network [OSTI]

    Holtz, William Joseph

    2011-01-01

    Dueber et al. , “Synthetic protein scaffolds provide modularzinc finger DNA-binding proteins,” Methods in Enzymology,Zinc Finger DNA-Binding Proteins†,” Biochemistry, vol. 42,

  3. Hydrocracking with molten zinc chloride catalyst containing 2-12% ferrous chloride

    DOE Patents [OSTI]

    Zielke, Clyde W. (McMurray, PA); Bagshaw, Gary H. (Library, PA)

    1981-01-01

    In a process for hydrocracking heavy aromatic polynuclear carbonaceous feedstocks to produce hydrocarbon fuels boiling below about 475.degree. C. by contacting the feedstocks with hydrogen in the presence of a molten zinc chloride catalyst and thereafter separating at least a major portion of the hydrocarbon fuels from the spent molten zinc chloride catalyst, an improvement comprising: adjusting the FeCl.sub.2 content of the molten zinc chloride to from about 2 to about 12 mol percent based on the mixture of ferrous chloride and molten zinc chloride.

  4. In-situ Analysis of Zinc Electrodeposition within an Ionic Liquid Electrolyte

    E-Print Network [OSTI]

    Keist, Jayme

    2013-01-01

    obtained by Zn based flow battery systems which currentlyAdding flow, however, means that the rechargeable batteryperformance of the battery system. Zinc flow batteries have

  5. TOWARDS ESTIMATING TOTAL ECONOMIC VALUE

    E-Print Network [OSTI]

    Bateman, Ian J.

    TOWARDS ESTIMATING TOTAL ECONOMIC VALUE OF FORESTS IN MEXICO by Neil Adger Katrina Brown Raffaello OF FORESTS IN MEXICO by Neil Adger Katrina Brown Raffaello Cervigni Dominic Moran Centre for Social and SEDESOL for their assistance whilst in Mexico, and David Pearce and Kerry Turner for comments on earlier

  6. MUJERES ( * ) TOTAL BIOLOGA 10 19

    E-Print Network [OSTI]

    Autonoma de Madrid, Universidad

    mujeres que han leído tesis en la UAM en el año 2007 Fuente: Centro de Posgrado de la UAM, a 31 de Diciembre de 2007 FILOSOFÍA Y LETRAS MEDICINA PSICOLOGÍA TOTAL TESIS LEIDAS Y APROBADAS EN EL A�O 2007 EN LA UAM CIENCIAS CIENCIAS ECON�MICAS Y EMPRESARIALES DERECHO ESCUELA POLIT�CNICA SUPERIOR Nº de tesis

  7. Total Energy Outcome City Pilot

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState ofSavings forTitle XVIIof EnergyofTotal Energy

  8. Tris(2-pyridylmethyl)amine (TPA) as a membrane-permeable chelator for interception of biological mobile zinc

    E-Print Network [OSTI]

    Huang, Zhen

    We report the characterization of tris(2-pyridylmethyl)amine (TPA) as a membrane-permeable zinc chelator for intercepting biological mobile zinc. Compared to N,N,N?,N?-tetrakis(2-pyridylmethyl)ethylenediamine (TPEN), TPA ...

  9. Vesicular Zinc Promotes Presynaptic and Inhibits Postsynaptic Long-Term Potentiation of Mossy Fiber-CA3 Synapse

    E-Print Network [OSTI]

    Pan, Enhui

    The presence of zinc in glutamatergic synaptic vesicles of excitatory neurons of mammalian cerebral cortex suggests that zinc might regulate plasticity of synapses formed by these neurons. Long-term potentiation (LTP) is ...

  10. Laser Raman spectroscopy study of the zinc and bromide ion complex equilibrium in zinc/bromine battery electrolytes. [2M ZnBr/sub 2/ and 1M KBr solution

    SciTech Connect (OSTI)

    Grimes, P.G.; Larrabee, J.A.

    1985-01-01

    Laser Raman spectroscopy was used to study the zinc and bromide ion complex equilibrium in zinc bromine battery model electrolytes. Solutions of zinc bromide with added KBr, HBr and N-methyl, N-ethyl morpholinium (MEM) bromide were examined and compared. Solutions studied ranged from 1 to 3 molar in zinc and from 2.5 to 8 molar in bromide. A typical Raman spectrum of a zinc bromide solution is shown in Figure 1. Each of the zinc species is identified, Zn/sup + +/ (aq), ZnBr/sup +/, ZnBr/sub 2/ (aq), ZnBr/sub 3//sup -/ and ZnBr/sub 4//sup 2 -/. By the use of peak heights or deconvolution/integration along with published Raman cross sections, the amount of each zinc species could be quantitatively determined. The addition of bromide ions to the zinc bromide solutions will shift the equilibrium toward higher bromide complexes. The added cations will influence the shifts. It has been noted that the conductivity of the electrolyte decreases when the quaternary ammonium ions are present compared to cations such as potassium or hydrogen. Significantly more free zinc is present in zinc bromide solutions with added KBr than with either MEMBr or HBr. Shifts are also noted with the other zinc ion containing species. It appears that the quaternary ammonium ions and possibly the pH could have a stabilizing effect on zinc bromide complex ion formation. 2 figs.

  11. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  12. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents and methods of use thereof

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2006-06-27

    Reduced sulfur gas species (e.g., H.sub.2S, COS and CS.sub.2) are removed from a gas stream by compositions wherein a zinc titanate ingredient is associated with a metal oxide-aluminate phase material in the same particle species. Nonlimiting examples of metal oxides comprising the compositions include magnesium oxide, zinc oxide, calcium oxide, nickel oxide, etc.

  13. Performance Enhancement of a Graphene-Zinc Phosphide Solar Cell Using the Electric Field-Effect

    E-Print Network [OSTI]

    Javey, Ali

    Performance Enhancement of a Graphene-Zinc Phosphide Solar Cell Using the Electric Field for photovoltaics. We present a field-effect solar cell using graphene to form a tunable junction barrier of photovoltaic devices incorporating graphene. KEYWORDS: Graphene, zinc phosphide, field effect solar cell

  14. Synthesis, characterisation and modelling of zinc and silicate co?substituted hydroxyapatite

    E-Print Network [OSTI]

    Friederichs, Robert J.; Chappell, Helen F.; Shepherd, David V.; Best, Serena M.

    2015-06-19

      of   HA   (P63/m   space   group)   allows   for   ionic  substitution   or   interstitial   site   insertion   depending   on   the   substituting   ion,  thermodynamic  formation  energies,  kinetics  of  ion...  formation,  act  as  an  anti-­?microbial  and  slow  osteoclast  (OC)  resorption.  Yamaguchi  et  al.  found   that   solubilised   zinc   (zinc   sulphate)   between   10-­?6-­?10-­?3   M   increased   bone...

  15. Kinetics of Zinc/ Arsenate Co-Sorption at the Goethite-Water Interface. (5827)

    E-Print Network [OSTI]

    Sparks, Donald L.

    Kinetics of Zinc/ Arsenate Co-Sorption at the Goethite-Water Interface. (5827) Authors: D.L. Sparks, and 1000 mg goethite L-1 solutions at pH 7, collected complimentary As and Zn K-edge EXAFS data after of aging time. Arsenate and zinc formed adamite-like and koettigite-like surface precipitates on goethite

  16. Fuel additives and heat treatment effects on nanocrystalline zinc ferrite phase composition

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Fuel additives and heat treatment effects on nanocrystalline zinc ferrite phase composition Ping Hu October 2010 Keywords: Zinc ferrite Fuel additive Heat treatment Phase composition a b s t r a c considered the influence of fuel additives and heat treatment conditions on the phase composition

  17. An algebraic model for a zinc/bromine flow cell

    SciTech Connect (OSTI)

    Simpson, G.D.; White, R.E. . Dept. of Chemical Engineering)

    1989-08-01

    An algebraic model for a parallel plate, zinc/bromine flow cell is presented and used to predict various performance quantities, which are compared to those predicted by using previously published differential equation models. The results presented compare well with previous work. The model is based on the concept of using well-mixed zones and linear concentration and potential profiles for the diffusion layers and the separator. The Butler-Volmer equation is used for the electro chemical reactions, and the homogeneous reaction between bromine and bromide is included.

  18. Commercial Pecans: Controlling Rosette, Diseases and Zinc Deficiency 

    E-Print Network [OSTI]

    Lee, Thomas A.; Krausz, Joseph P.

    2006-04-13

    to be healthy and vigor- ous and for nut quality and yield to be satisfactory, producers must establish sound disease-management programs. Producers can pre- vent losses from diseases and insuff_i cient zinc by implementing ef_fective grove management... fall. Although the foliage is mature and no longer susceptible to the scab fun- gus, the shucks surrounding the nuts are immature and vulnerable to late-season infections. Factors inf_l uencing disease development As you develop a spray program...

  19. Analysis of Zinc 65 Contamination after Vacuum Thermal Process

    SciTech Connect (OSTI)

    Korinko, Paul S.; Tosten, Michael H.

    2013-01-01

    Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

  20. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  1. Recent progress on Exxon's circulating zinc bromine battery system

    SciTech Connect (OSTI)

    Bellows, R.J.

    1981-01-01

    The design, performance, and factory cost of Exxon's circulating zinc bromine batteries are described. The Exxon system has demonstrated stable performance in scale-ups to 3- and 10-kWh sub-modules. Cost studies based on recently demonstrated extrusion and injection molding techniques, have shown that this battery, with plastic electrodes, bipolar stacks, Br/sub 2/ complexation, and circulating electrolytes, could be produced (20 kWh units, 100,000 units/year) at a factory cost of $28/kWh (excluding R.O.I., and various indirect overheads).

  2. The Zinc Metalloregulatory Protein Synechococcus PCC7942 SmtB Binds a Single Zinc Ion per Monomer with High Affinity in a Tetrahedral Coordination Geometry

    E-Print Network [OSTI]

    Scott, Robert A.

    understood. In contrast to previous results [Kar, S. R., Adams, A. C., Lebowitz, J., Taylor, K. B., and Hall PCC7942 SmtB is a zinc-responsive transcriptional repressor and a member of the ArsR superfamily

  3. ZINC/AIR BATTERY R & D RESEARCH AND DEVELOPMENT OF BIFUNCTIONAL OXYGEN ELECTRODE TASKS I AND II

    E-Print Network [OSTI]

    Klein, M.

    2009-01-01

    ENCE DIVISION ZINC/AIR BATTERY R&D C-.J(~ur.1":! rfS SECTIONLBL-22661 ZINC/AIR BATTERY R&D RESEARCH AND DEVELOPMENT OFTask III - Zinc Air for EV Battery - an engineerin~~~~~Ą! 3!

  4. TotalView Training 2015

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnologyTel:FebruaryEIA's Today8Topo II: AnUsersTotalView

  5. Total Adjusted Sales of Kerosene

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8, 2015End Use: Total

  6. Total Imports of Residual Fuel

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8,Product: Total CrudeMay-15

  7. Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery

    SciTech Connect (OSTI)

    Li, Bin; Gu, Meng; Nie, Zimin; Shao, Yuyan; Luo, Qingtao; Wei, Xiaoliang; Li, Xiaolin; Xiao, Jie; Wang, Chong M.; Sprenkle, Vincent L.; Wang, Wei

    2013-02-04

    The selection of electrode materials plays a great role in improving performances of all vanadium redox flow batteries (VRBs). Low-cost graphite felt (GF) as traditional electrode material has to be modified to address its issue of low electrocatalytic activity. In our paper, low-cost and highly conductive bismuth nanoparticles, as a powerful alternative electrocatalyst to noble metal, are proposed and synchronously electro-deposited onto the surface of GF while running flow cells employing the electrolytes containing suitable Bi3+. Although bismuth is proved to only take effect on the redox reaction of V(II)/V(III) and present at negative half-cell side, the whole cell electrochemical performances are significantly improved. In particular, the energy efficiency is increased by 11% owing to faster charge transfer as compared with one without Bi at high charge/discharge rate of 150 mA/cm2, which is prone to reduce stack size, thus dramatically reducing the cost. The excellent results show great promise of Bi nano-catalysts in the commercialization of VRBs in terms of product cost as well as electrochemical properties.

  8. The kinetic significance of V{sup 5+} in n-butane oxidation catalyzed by vanadium phosphates

    SciTech Connect (OSTI)

    Coulston, G.W.; Harlow, R.; Herron, N.

    1997-01-10

    Maleic anhydride, a precursor to polyester resins, is made by oxidation of n-butane over vanadium phosphate catalysts. This system is of general interest because it is the only heterogeneously catalyzed, alkane-selective oxidation reaction in commercial use. Time-resolved in situ x-ray absorption spectroscopy shows that when either {alpha}{sub 1}-VOPO{sub 4}/SiO{sub 2} or (VO){sub 2}P{sub 2}O{sub 7}/SiO{sub 2} catalysts are exposed to n-butane, the rate of maleic anhydride formation is proportional to the rate of decay of V{sup 5+} species in the catalyst. Thus V{sup 5+} species are kinetically significant for the production of maleic anhydride and not just for the production of by-products. The results also suggest that V{sup 5+} species in the catalyst. Thus V{sup 5+} species are kinetically significant for the production of maleic anhydride and not just for the production of by-products. The results also suggest that V{sup 5+} species may play a role in the initial hydrogen abstraction from n-butane, the rate-determining step in the reaction sequence. V{sup 4+} sites appear to be responsible for by-product formation.

  9. Resolving Losses at the Negative Electrode in All-Vanadium Redox Flow Batteries Using Electrochemical Impedance Spectroscopy

    SciTech Connect (OSTI)

    Sun, Che Nan [ORNL] [ORNL; Delnick, Frank M [ORNL] [ORNL; Aaron, D [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Mench, Matthew M [ORNL] [ORNL; Zawodzinski, Thomas A [ORNL] [ORNL

    2014-01-01

    We present an in situ electrochemical technique for the quantitative measurement and resolution of the ohmic, charge transfer and diffusion overvoltages at the negative electrode of an all-vanadium redox flow battery (VRFB) using electrochemical impedance spectroscopy (EIS). The mathematics describing the complex impedance of the V+2/V+3 redox reaction is derived and matches the experimental data. The voltage losses contributed by each process have been resolved and quantified at various flow rates and electrode thicknesses as a function of current density during anodic and cathodic polarization. The diffusion overvoltage was affected strongly by flow rate while the charge transfer and ohmic losses were invariant. On the other hand, adopting a thicker electrode significantly changed both the charge transfer and diffusion losses due to increased surface area. Furthermore, the Tafel plot obtained from the impedance resolved charge transfer overvoltage yielded the geometric exchange current density, anodic and cathodic Tafel slopes (135 5 and 121 5 mV/decade respectively) and corresponding transfer coefficients = 0.45 0.02 and = 0.50 0.02 in an operating cell.

  10. Wetting and Mechanical Performance of Zirconia Brazed with Silver/Copper Oxide and Silver/Vanadium Oxide Alloys

    SciTech Connect (OSTI)

    Sinnamon, Kathleen E.; Meier, Alan; Joshi, Vineet V.

    2014-12-01

    The wetting behavior and mechanical strength of silver/copper oxide and silver/vanadium oxide braze alloys were investigated for both magnesia-stabilized and yttria-stabilized (Mg-PSZ and Y-TZP) transformation toughened zirconia substrates. The temperatures investigated were 1000 to 1100°C, with oxide additions of 1 to 10 weight percent V2O5 or CuO, and hold times of 0.9 to 3.6 ks. Increasing either the isothermal hold temperature or time had a distinctly negative effect on the joint strength. The maximum strengths for both braze alloys were obtained for 5 wt. % oxide additions at 1050°C with a hold time of 0.9 ks. The Mg-PSZ/Ag-CuO system exhibited a average fracture strength of 255 MPa (45% of the reported monolithic strength), and the Y-TZP/Ag-CuO system had an average fracture strength of 540 MPa (30% of the reported monolithic strength). The fracture strengths were lower for the Ag-V2O5 braze alloys, with fracture strengths of approximately 180 MPa (30% of the monolithic strength) for Mg-PSZ versus approximately 160 MPa (10% of the monolithic strength) for Y-TZP. No interfacial products were observed in low magnification SEM analysis for the brazing alloys containing V2O5 additions, while there were interfacial products present for brazes prepared with CuO additions in the braze alloy.

  11. Thermal-sprayed zinc anodes for cathodic protection of steel-reinforced concrete bridges

    SciTech Connect (OSTI)

    Bullard, Sophie J.; Covino, Bernard S., Jr.; Cramer, Stephen D.; McGill, Galen E.

    1996-01-01

    Thermal-sprayed zinc anodes are being used in Oregon in impressed current cathodic protection (ICCP) systems for reinforced concrete bridges. The U.S. Department of Energy, Albany Research Center, is collaborating with the Oregon Department of Transportation (ODOT) to evaluate the long-term performance and service life of these anodes. Laboratory studies were conducted on concrete slabs coated with 0.5 mm (20 mil) thick, thermal-sprayed zinc anodes. The slabs were electrochemically aged at an accelerated rate using an anode current density of 0.032 A/m2 (3mA/ft2). Half the slabs were preheated before thermal-spraying with zinc; the other half were unheated. Electrochemical aging resulted in the formation at the zinc-concrete interface of a thin, low pH zone (relative to cement paste) consisting primarily of ZnO and Zn(OH)2, and in a second zone of calcium and zinc aluminates and silicates formed by secondary mineralization. Both zones contained elevated concentrations of sulfate and chloride ions. The original bond strength of the zinc coating decreased due to the loss of mechanical bond to the concrete with the initial passage of electrical charge (aging). Additional charge led to an increase in bond strength to a maximum as the result of secondary mineralization of zinc dissolution products with the cement paste. Further charge led to a decrease in bond strength and ultimately coating disbondment as the interfacial reaction zones continued to thicken. This occurred at an effective service life of 27 years at the 0.0022 A/m2 (0.2 mA/ft2) current density typically used by ODOT in ICCP systems for coastal bridges. Zinc coating failure under tensile stress was primarily cohesive within the thickening reaction zones at the zinc-concrete interface. There was no difference between the bond strength of zinc coatings on preheated and unheated concrete surfaces after long service times.

  12. Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.; Carciello, N.R.

    1987-04-21

    This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80 C. The polyelectrolyte or the precoat is present in about 0.5--5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150 C to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2 [times] 10[sup 5] gave improved ductility modulus effect. 5 figs.

  13. Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY); Carciello, Neal R. (Bellport, NY)

    1987-01-01

    This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80.degree. C. The polyelectrolyte or the precoat is present in about 0.5-5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150.degree. C. to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2.times.10.sup.5 gave improved ductility modulus effect.

  14. Two-stage regeneration of zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-06-28

    The Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE) is interested in the potential of using a two-step process for regenerating the zinc ferrite desulfurization sorbent. In the first regeneration step, a gas mixture consisting of 12 percent SO{sub 2}, 2 percent O{sub 2}, and 86 percent N{sub 2} is used to convert zinc and iron sulfides to their sulfate forms using a sorbent bed inlet temperature of about 850{degrees}F (454{degrees}C). For the second step, the temperature is raised to about 1400{degrees}F (760{degrees}C), and the sulfates are decomposed to oxides with the concurrent release of sulfur dioxide. The same gas composition used for first step is also used for the second step. The proposed technique would require no steam and also has the advantage of producing a regeneration gas rich in sulfur dioxide. In a commercial operation, recirculating regeneration gas would be supplemented with air as required to supply the necessary oxygen. A bleed stream from regeneration (concentrated SO{sub 2} gas in nitrogen) would constitute feed to sulfur recovery.

  15. EFFECT OF PORE SIZE ON TRAPPING ZINC VAPORS

    SciTech Connect (OSTI)

    Korinko, P.

    2010-12-17

    A series of experiments were conducted to determine the effect of pore size on pumping efficiency and zinc vapor trapping efficiency. A simple pumping efficiency test was conducted for all five pore diameters where it was observed that evacuation times were adversely affected by reducing the pore size below 5 {micro}m. Common test conditions for the zinc trapping efficiency experiments were used. These conditions resulted in some variability, to ascribe different efficiencies to the filter media. However, the data suggest that there is no significant difference in trapping efficiency for filter media with pores from 0.2 to 20 {micro}m with a thickness of 0.065-inch. Consequently, the 20 {micro}m pore filter media that is currently used at SRS is a suitable filter material for to utilize for future extractions. There is evidence that smaller pore filter will adversely affect the pumping times for the TEF and little evidence to suggest that a smaller pore diameters have significant impact on the trapping efficiency.

  16. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 1,602 1,397...

  17. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Energy Consumption Survey: Energy End-Use Consumption Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All...

  18. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings ... 2,037...

  19. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Released: September, 2008 Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings* ... 1,870 1,276...

  20. Webtrends Archives by Fiscal Year — EERE Totals

    Broader source: Energy.gov [DOE]

    Historical EERE office total reports include only Webtrends archives by fiscal year. EERE total reports dating after FY11 can be accessed in EERE's Google Analytics account.

  1. Total Space Heating Water Heating Cook-

    Gasoline and Diesel Fuel Update (EIA)

    Tables Total Space Heating Water Heating Cook- ing Other Total Space Heating Water Heating Cook- ing Other All Buildings ... 636 580 46 1 Q 114.0...

  2. Total quality management implementation guidelines

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    These Guidelines were designed by the Energy Quality Council to help managers and supervisors in the Department of Energy Complex bring Total Quality Management to their organizations. Because the Department is composed of a rich mixture of diverse organizations, each with its own distinctive culture and quality history, these Guidelines are intended to be adapted by users to meet the particular needs of their organizations. For example, for organizations that are well along on their quality journeys and may already have achieved quality results, these Guidelines will provide a consistent methodology and terminology reference to foster their alignment with the overall Energy quality initiative. For organizations that are just beginning their quality journeys, these Guidelines will serve as a startup manual on quality principles applied in the Energy context.

  3. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Eddy current sensing of cadmium zinc telluride crystal growth

    E-Print Network [OSTI]

    Wadley, Haydn

    permission. Eddy current sensing of cadmium zinc telluride crystal growth Choi, Byoung-Woo William Pro

  4. Effect of morphology and solvent on two-photon absorption of nano zinc oxide

    SciTech Connect (OSTI)

    Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

    2013-05-15

    Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

  5. Electrical current suppression in Pd-doped vanadium pentoxide nanowires caused by reduction in PdO due to hydrogen exposure

    SciTech Connect (OSTI)

    Kim, Byung Hoon; Oh, Soon-Young; Yu, Han Young; Yun, Yong Ju; Kim, Yark Yeon; Hong, Won G.; Jeong, Hu Young; Lee, Jeong Yong; Kim, Hae Jin

    2010-04-19

    Pd nanoparticle-doped vanadium pentoxide nanowires (Pd-VONs) were synthesized. Electrical current suppression was observed when the Pd-VON was exposed to hydrogen gas, which cannot be explained by the work function changes mentioned in previous report such as Pd-doped carbon nanotubes and SnO{sub 2} nanowires. Using the x-ray photoelectron spectroscopy, we found that the reduction in PdO due to hydrogen exposure plays an important role in the current suppression of the Pd-VON.

  6. Total termination of term rewriting is undecidable

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Total termination of term rewriting is undecidable Hans Zantema Utrecht University, Department Usually termination of term rewriting systems (TRS's) is proved by means of a monotonic well­founded order. If this order is total on ground terms, the TRS is called totally terminating. In this paper we prove that total

  7. Total-derivative supersymmetry breaking

    SciTech Connect (OSTI)

    Haba, Naoyuki; Uekusa, Nobuhiro

    2010-05-15

    On an interval compactification in supersymmetric theory, boundary conditions for bulk fields must be treated carefully. If they are taken arbitrarily following the requirement that a theory is supersymmetric, the conditions could give redundant constraints on the theory. We construct a supersymmetric action integral on an interval by introducing brane interactions with which total-derivative terms under the supersymmetry transformation become zero due to a cancellation. The variational principle leads equations of motion and also boundary conditions for bulk fields, which determine boundary values of bulk fields. By estimating mass spectrum, spontaneous supersymmetry breaking in this simple setup can be realized in a new framework. This supersymmetry breaking does not induce a massless R axion, which is favorable for phenomenology. It is worth noting that fermions in hyper-multiplet, gauge bosons, and the fifth-dimensional component of gauge bosons can have zero-modes (while the other components are all massive as Kaluza-Klein modes), which fits the gauge-Higgs unification scenarios.

  8. Development of Thin Section Zinc Die Casting Technology

    SciTech Connect (OSTI)

    Goodwin, Frank [International Lead Zinc Research Org., Inc.] [International Lead Zinc Research Org., Inc.

    2013-10-31

    A new high fluidity zinc high pressure die casting alloy, termed the HF alloy, was developed during laboratory trials and proven in industrial production. The HF alloy permits castings to be achieved with section thicknesses of 0.3 mm or less. Technology transfer activities were conducted to develop usage of the HF high fluidity alloy. These included production of a brochure and a one-hour webinar on the HF alloy. The brochure was then sent to 1,184 product designers in the Interzinc database. There was excellent reception to this mailing, and from this initial contact 5 technology transfer seminars were conducted for 81 participants from 30 companies across a wide range of business sectors. Many of the successful applications to date involve high quality surface finishes. Design and manufacturing assistance was given for development of selected applications.

  9. Recent progress on Exxon's zinc-bromine battery technology

    SciTech Connect (OSTI)

    Bellows, R.J.

    1982-01-01

    The Exxon zinc-bromine battery design is based on the use of a circulating electrolyte, bromine complexing agents, conductive carbon plastic electrodes, and a bipolar electrode stack using shunt current protection. Manufacturing cost for this design, assuming large scale production is estimated at $28/kWh ($1980). Electrode and electrolyte performance is equivalent to 65 Wh/kg and over 150 w/kg in final designs. Recent program highlights include system scale-up to the 20 kWh level, extension of demonstrated life to over 400 cycles, the ability to follow various cycling regimes, and preparations for a full-scale deliverable during 1983. Program status is outlined. (WHK)

  10. Biochemistry of mobile zinc and nitric oxide revealed by fluorescent sensors

    E-Print Network [OSTI]

    Pluth, Michael D.

    Biological mobile zinc and nitric oxide (NO) are two prominent examples of inorganic compounds involved in numerous signaling pathways in living systems. In the past decade, a synergy of regulation, signaling, and translocation ...

  11. Zinc-dependent Interaction between Dishevelled and the Drosophila Wnt Antagonist Naked Cuticle*

    E-Print Network [OSTI]

    Scott, Matthew

    Zinc-dependent Interaction between Dishevelled and the Drosophila Wnt Antagonist Naked Cuticle development, the naked cuticle (nkd) gene attenuates wingless/Wnt signaling through a negative feedback loop

  12. Flexographically Printed Rechargeable Zinc-based Battery for Grid Energy Storage

    E-Print Network [OSTI]

    Wang, Zuoqian

    2013-01-01

    the Assembled Full Cell…………………………..……66 4.6. Zinc-basedwere then conducted. Full cells consisting of dispenser-hours. Subsequently, a full cell was assembled by placing a

  13. A Novel Imaging Approach for Early Detection of Prostate Cancer Based on Endogenous Zinc Sensing

    E-Print Network [OSTI]

    Ghosh, Subrata K.

    The early detection of prostate cancer is a life-saving event in patients harboring potentially aggressive disease. With the development of malignancy, there is a dramatic reduction in the zinc content of prostate tissue ...

  14. Long-wavelength, reaction-based, fluorescent sensors for HNO and mobile zinc

    E-Print Network [OSTI]

    Wrobel, Alexandra T

    2014-01-01

    Chapter 1. Introduction A variety of inorganic molecules and ions participate in complex biological signaling networks. Three of these species are nitric oxide (NO), nitroxyl (HNO), and mobile zinc. Maintaining the homeostasis ...

  15. Zinc Deficiency Impacts CO2 Assimilation and Disrupts Copper Homeostasis in Chlamydomonas reinhardtii*S

    E-Print Network [OSTI]

    Institute for Genomics and Proteomics, and the **Department of Molecular, Cell and Developmental Biology from bacteria to humans. Over 300 known enzymes utilize zinc as a cofactor, and whole genome surveys

  16. Understanding Zinc Quantification with Existing and Advanced Ditopic Fluorescent Zinpyr Sensors

    E-Print Network [OSTI]

    Buccella, Daniela

    Treatment of aqueous zinc solutions with incremental additions of a ditopic fluorescent sensor of the Zinpyr family, based on pyridine/pyrazine-containing metal recognition units, affords a fluorescence titration curve ...

  17. Using Zinc Finger Nucleases for Targeted Genome Modification in the Zebrafish

    E-Print Network [OSTI]

    McCammon, Jasmine Mali

    2010-01-01

    438. Zou J, Maeder ML, Mali P, Pruett-Miller SM, Thibodeau-in the Zebrafish By Jasmine Mali McCammon A dissertationthe Zebrafish by Jasmine Mali McCammon Abstract Using Zinc

  18. Spin-dependent electron transport in zinc- and manganese-doped adenine molecules

    SciTech Connect (OSTI)

    Simchi, Hamidreza; Esmaeilzadeh, Mahdi Mazidabadi, Hossein

    2014-01-28

    The spin-dependent electron transport properties of zinc- and manganese-doped adenine molecules connected to zigzag graphene leads are studied in the zero bias regime using the non-equilibrium Green's function method. The conductance of the adenine molecule increased and became spin-dependent when a zinc or manganese atom was doped into the molecules. The effects of a transverse electric field on the spin-polarization of the transmitted electrons were investigated and the spin-polarization was controlled by changing the transverse electric field. Under the presence of a transverse electric field, both the zinc- and manganese-doped adenine molecules acted as spin-filters. The maximum spin-polarization of the manganese-doped adenine molecule was greater than the molecule doped with zinc.

  19. STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES

    E-Print Network [OSTI]

    Mc Vay, L.

    2011-01-01

    J. , Flow distribution in the zinc chloride battery, JES,ensures a con- The flow patterns in this battery were stant,and products. flow As a result the battery is separate from

  20. EFFECT OF THERMAL PROCESSES ON COPPER-TIN ALLOYS FOR ZINC GETTERING

    SciTech Connect (OSTI)

    Korinko, P.; Golyski, M.

    2013-11-01

    A contamination mitigation plan was initiated to address the discovery of radioactive zinc‐65 in a glovebox. A near term solution was developed, installation of heated filters in the glovebox piping. This solution is effective at retaining the zinc in the currently contaminated area, but the gamma emitting contaminant is still present in a system designed for tritium beta. A project was initiated to develop a solution to contain the {sup 65}Zn in the furnace module. Copper and bronze (a Cu/Sn alloy) were found to be candidate materials to combine with zinc‐65 vapor, using thermodynamic calculations. A series of binary Cu/Sn alloys were developed (after determining that commercial alloys were unacceptable), that were found to be effective traps of zinc vapor. The task described in this report was undertaken to determine if the bronze substrates would retain their zinc gettering capability after being exposed to simulated extraction conditions with oxidizing and reducing gases. Pure copper and three bronze alloys were prepared, exposed to varying oxidation conditions from 250 to 450{degree}C, then exposed to varying reduction conditions in He-H{sub 2} from 250-450{degree}C, and finally exposed to zinc vapor at 350{degree}C for four hours. The samples were characterized using scanning electron microscopy, X-ray diffraction, differential thermal analysis, mass change, and visual observation. It was observed that the as fabricated samples and the reduced samples all retained their zinc gettering capacity while samples in the "as-oxidized" condition exhibited losses in zinc gettering capacity. Over the range of conditions tested, i.e., composition, oxidation temperature, and reduction temperature, no particular sample composition appeared better. Samples reduced at 350{degree}C exhibited the greatest zinc capacity, although there were some testing anomalies associated with these samples. This work clearly demonstrated that the zinc gettering was not adversely affected by exposure to simulated process conditions and a full scale lithium and zinc trap should be fabricated for testing in the Tritium Extraction Facility.

  1. Material and Energy Flows Associated with Select Metals in GREET 2. Molybdenum, Platinum, Zinc, Nickel, Silicon

    SciTech Connect (OSTI)

    Benavides, Pahola T.; Dai, Qiang; Sullivan, John L.; Kelly, Jarod C.; Dunn, Jennifer B.

    2015-09-01

    In this work, we analyzed the material and energy consumption from mining to production of molybdenum, platinum, zinc, and nickel. We also analyzed the production of solar- and semiconductor-grade silicon. We described new additions to and expansions of the data in GREET 2. In some cases, we used operating permits and sustainability reports to estimate the material and energy flows for molybdenum, platinum, and nickel, while for zinc and silicon we relied on information provided in the literature.

  2. Microprocessor-based control system for flowing-electrolyte zinc-bromine battery systems

    SciTech Connect (OSTI)

    Malachesky, P.A.; Chang, L.S.; Elspass, C.E.; Bellows, R.J.

    1983-01-01

    The zinc-bromine battery system under development at Exxon is based on a bipolar, circulating electrolyte design concept. Such circulating electrolyte systems require a controller to operate and monitor system auxiliaries such as valves and pumps. A 1.2 kWh zinc-bromine battery system controller has been constructed using a single board computer. The design and operation of this controller will be discussed.

  3. JOURNAL DE PHYSIQUE CoZZoque C8, suppZ6ment au n08, Tome 41, aoGt 1980, page C8-163 STUDY OF LIQUID NICKEL-VANADIUM ALLOYS BY NEUTRON DIFFRACTION AND MODEL SIMULATION

    E-Print Network [OSTI]

    Boyer, Edmond

    , 28 i s the scattering angle, X the neutron wave- length, Q = 4n the modulus of the scattering vector NICKEL-VANADIUM ALLOYS BY NEUTRON DIFFRACTION AND MODEL SIMULATION J.L. Lemarchand, J. Bletry and P with model c a l c u l a t i o ~can lead to a quantitative interpreta- tion. In this paper, neutron

  4. Successful removal of zinc sulfide scale restriction from a hot, deep, sour gas well

    SciTech Connect (OSTI)

    Kenrick, A.J.; Ali, S.A.

    1997-07-01

    Removal of zinc sulfide scale with hydrochloric acid from a hot, deep, Norphlet Sandstone gas well in the Gulf of Mexico resulted in a 29% increase in the production rates. The zinc sulfide scale was determined to be in the near-wellbore area. The presence of zinc sulfide is explained by the production of 25 ppm H{sub 2}S gas, and the loss of 50--100 bbl of zinc bromide fluid to the formation. Although zinc sulfide scale has been successfully removed with hydrochloric acid in low-to-moderate temperature wells, no analogous treatment data were available for high temperature, high pressure (HTHP) Norphlet wells. Therefore laboratory testing was initiated to identify suitable acid systems for scale removal, and select a high quality corrosion inhibitor that would mitigate detrimental effects of the selected acid on downhole tubulars and surface equipment. This case history presents the first successful use of hydrochloric acid in removing zinc sulfide scale from a HTHP Norphlet sour gas well.

  5. Zinc protects human peripheral blood lymphocytes from Cr(III)(phenanthroline){sub 3}-induced apoptosis

    SciTech Connect (OSTI)

    Sankaramanivel, Sundararaj; Rajaram, Anantanarayanan; Rajaram, Rama

    2010-03-15

    We have studied the effect of Cr(III)(phen){sub 3} [(tris(1,10-phenanthroline) chromium(III) chloride)] on lymphocytes in order to find out if metallothioneins (MTs) are produced in the process. We also investigated whether zinc pretreatment is able to protect cells from apoptosis reported to occur for this compound. Our results indicate that MT synthesis is induced by Cr(III)(phen){sub 3}, and it has been identified as the MT-3 isoform through RT-PCR which has not been reported earlier. By zinc pretreatment, this apoptosis is reversed as inferred from cytotoxicity studies, Annexin-V/PI staining, ethidium bromide/acridine orange staining and DNA fragmentation pattern and ultrastructural investigations using TEM and SEM. The zinc pretreatment reduces the amount of ROS produced by Cr(III)(phen){sub 3} . The MT-1a and 1b synthesized by zinc (also evidenced through RT-PCR experiments) is possibly able to scavenge ROS which is one of the early signaling molecules that lead to apoptosis. Zinc pretreatment also reverses the changes in downstream signaling events such as mitochondrial membrane potential, ATP levels and the activation of caspase-3. This is the first report on the induction of MT-3 in lymphocytes due to a metal stress or any other stimuli. Even though MT-3 is synthesized here, apoptosis still occurs due to ROS production on Cr(III)(phen){sub 3} exposure when the cells have not been primed with zinc.

  6. Total cost model for making sourcing decisions

    E-Print Network [OSTI]

    Morita, Mark, M.B.A. Massachusetts Institute of Technology

    2007-01-01

    This thesis develops a total cost model based on the work done during a six month internship with ABB. In order to help ABB better focus on low cost country sourcing, a total cost model was developed for sourcing decisions. ...

  7. Total System Performance Assessment Peer Review Panel

    Broader source: Energy.gov [DOE]

    Total System Performance Assessment (TSPA) Peer Review Panel for predicting the performance of a repository at Yucca Mountain.

  8. 8, 31433162, 2008 Total ozone over

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 3143­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Chemistry and Physics Discussions Total column ozone variations over oceanic region around Indian sub­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Abstract Introduction

  9. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  10. 6, 39133943, 2006 Svalbard total ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 3913­3943, 2006 Svalbard total ozone C. Vogler et al. Title Page Abstract Introduction Discussions Re-evaluation of the 1950­1962 total ozone record from Longyearbyen, Svalbard C. Vogler 1 , S. Br total ozone C. Vogler et al. Title Page Abstract Introduction Conclusions References Tables Figures Back

  11. Total Algorithms \\Lambda Gerard Tel y

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Total Algorithms \\Lambda Gerard Tel y Department of Computer Science, University of Utrecht, P and February 1993 Abstract We define the notion of total algorithms for networks of processes. A total algorithm enforces that a ``decision'' is taken by a subset of the processes, and that participation of all

  12. Seasonal persistence of midlatitude total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of midlatitude total ozone anomalies Article Published Version Fioletov, V. E. and Shepherd, T. G. (2003) Seasonal persistence of midlatitude total ozone anomalies. Geophysical Research persistence of midlatitude total ozone anomalies Vitali E. Fioletov Meteorological Service of Canada, Toronto

  13. Ordered Nucleation Sites for the Growth of Zinc Oxide Nanofibers

    SciTech Connect (OSTI)

    Wang, J.; Ginley, D.S.; Shaheen, S.

    2006-01-01

    Organic photovoltaics (OPVs) offer a promising route to low cost photovoltaic (PV) technology that can be inexpensively manufactured on a large scale for use in power generation and commercial products. Solar power conversion efficiencies of laboratory scale OPV devices have recently reached ~5%; however, projected efficiencies of at least 10% will be required for commercialization. An analogous approach that has arisen recently that can potentially increase efficiencies employs metal oxide semiconductors as the electron acceptor, creating a hybrid organic-inorganic device. This approach offers the advantage that the conduction band of the oxide can be tuned in a systematic way through doping, thus potentially achieving higher photovoltages in the device. Additionally, nanostructures of these materials can be easily grown from precursor solutions, providing a technique to precisely control the nanoscale geometry. This work focuses on using ZnO, which is known to have high electron mobility (>100 cm2/Vs), as the electron acceptor. Nanofibers of ZnO can be grown from precursors such as zinc acetate or zinc nitrate to form arrays of nanofibers into which a conjugated polymer can be intercalated to form a composite PV device. The morphology of the nanofiber array is critical to the performance of the device, but current methods of nanofiber growth from a flat, polycrystalline nucleation layer allow for little morphological control. To overcome this limitation, we have created ordered arrays of ZnO nucleation sites with controllable size and spacing. Toluene solutions of diblock copolymer micelles with ZnCl2 incorporated into the micellar cores were spin-coated onto glass substrates and etched with an O2 plasma to yield hexagonally ordered arrays of ZnO nanoparticles that functioned as nucleation sites. Changing the concentration of ZnCl2 and the molecular weight and ratio of the diblock copolymer resulted in systematic variation in the size and spacing of the nucleation sites. Thermal anneal treatment provided further modification of the nucleation layer, from which ZnO nanofibers were successfully grown from solution, although at present it is not known if the geometry of the as-grown ZnO nanofibers precisely reflects that of the underlying nucleation layer. This work provides a simple and useful method for potentially controlling the nucleation of ZnO nanofibers to be used in hybrid ZnO/organic nanocomposite PV devices.

  14. Literature search for the non-aqueous separation of zinc from fuel rod cladding. [After dissolution in liquid metal

    SciTech Connect (OSTI)

    Sandvig, R. L.; Dyer, S. J.; Lambert, G. A.; Baldwin, C. E.

    1980-06-21

    This report reviews the literature of processes for the nonaqueous separation of zinc from dissolved fuel assembly cladding. The processes considered were distillation, pyrochemical processing, and electrorefining. The last two techniques were only qualitatively surveyed while the first, distillation, was surveyed in detail. A survey of available literature from 1908 through 1978 on the distillation of zinc was performed. The literature search indicated that a zinc recovery rate in excess of 95% is possible; however, technical problems exist because of the high temperatures required and the corrosive nature of liquid zinc. The report includes a bibliography of the surveyed literature and a computer simulation of vapor pressures in binary systems. 129 references.

  15. Mineralogical signature of nonsulfide zinc ores at Accha (Peru): A key for recovery Maria Boni a,b,

    E-Print Network [OSTI]

    Boni, Maria

    14 October 2009 Keywords: Nonsulfide zinc Mineralogy Petrography Processing Flowsheet The Accha deposit in Southern Peru is the first case in which an integrated study between mineralogy, petrography

  16. Groundwater Quality and Groundwater Pollution

    E-Print Network [OSTI]

    Pasternack, Gregory B.

    bromide gallium magnesium strontium cadmium gold chromium indium cobalt lanthanum anions phosphate tin rubidium tungsten selenium ytterbium titanium yttrium uranium zirconium vanadium zinc #12;are

  17. Experimental and computational studies on stacking faults in zinc titanate

    SciTech Connect (OSTI)

    Sun, W.; Ageh, V.; Mohseni, H.; Scharf, T. W. E-mail: Jincheng.Du@unt.edu; Du, J. E-mail: Jincheng.Du@unt.edu

    2014-06-16

    Zinc titanate (ZnTiO{sub 3}) thin films grown by atomic layer deposition with ilmenite structure have recently been identified as an excellent solid lubricant, where low interfacial shear and friction are achieved due to intrafilm shear velocity accommodation in sliding contacts. In this Letter, high resolution transmission electron microscopy with electron diffraction revealed that extensive stacking faults are present on ZnTiO{sub 3} textured (104) planes. These growth stacking faults serve as a pathway for dislocations to glide parallel to the sliding direction and hence achieve low interfacial shear/friction. Generalized stacking fault energy plots also known as ?-surfaces were computed for the (104) surface of ZnTiO{sub 3} using energy minimization method with classical effective partial charge potential and verified by using density functional theory first principles calculations for stacking fault energies along certain directions. These two are in qualitative agreement but classical simulations generally overestimate the energies. In addition, the lowest energy path was determined to be along the [451{sup Ż}] direction and the most favorable glide system is (104) ?451{sup Ż}? that is responsible for the experimentally observed sliding-induced ductility.

  18. PROMOTED ZINC CHROMITE CATALYSTS FOR HIGHER ALCOHOL SYNTHESIS

    SciTech Connect (OSTI)

    Ms. Xiaolei Sun; Professor George W. Roberts

    2001-06-15

    This report describes the analytical protocols that were developed during the last two years to analyze ''spent'' THQ (tetrahydroquinoline) slurry liquid. Identification of the components of the ''spent'' THQ should help to understand the influence of the slurry medium on the methanol synthesis reaction, and on other reactions with THQ as the slurry liquid. Silica gel liquid chromatography and high performance liquid chromatography (HPLC) were used to isolate and purify the major compounds in the ''spent'' slurry liquid. Gas chromatography/mass spectroscopy (GC/MS), Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) were applied to identify the major compounds. Methyl-, dimethyl-, and trimethyl-THQ were found to comprise more than 80% of the ''spent'' liquid. The balance was various methylated indoles. A methyl group always is attached to the N atom in the ring structure. Speculative mechanisms are presented that may help to understand the interaction between the catalyst and the alkylated THQ slurry liquid, and the effect of liquid composition on the methanol synthesis reaction. A poster entitled ''Promoted Zinc Chromite Catalyst for Higher Alcohol Synthesis in a Slurry Reactor-2. Spent Liquid Analysis'' was presented at the AIChE National Meeting, Los Angeles, CA, Nov 12-17, 2000.

  19. Zinc-chlorine battery plant system and method

    DOE Patents [OSTI]

    Whittlesey, Curtis C. (Birmingham, MI); Mashikian, Matthew S. (Huntington Woods, MI)

    1981-01-01

    A zinc-chlorine battery plant system and method of redirecting the electrical current around a failed battery module. The battery plant includes a power conditioning unit, a plurality of battery modules connected electrically in series to form battery strings, a plurality of battery strings electrically connected in parallel to the power conditioning unit, and a bypass switch for each battery module in the battery plant. The bypass switch includes a normally open main contact across the power terminals of the battery module, and a set of normally closed auxiliary contacts for controlling the supply of reactants electrochemically transformed in the cells of the battery module. Upon the determination of a failure condition, the bypass switch for the failed battery module is energized to close the main contact and open the auxiliary contacts. Within a short time, the electrical current through the battery module will substantially decrease due to the cutoff of the supply of reactants, and the electrical current flow through the battery string will be redirected through the main contact of the bypass switch.

  20. Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit

    DOE Patents [OSTI]

    McQuaid, J.H.; Lavietes, A.D.

    1998-05-26

    A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector is disclosed. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radionuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components. 9 figs.

  1. Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit

    DOE Patents [OSTI]

    McQuaid, James H. (Livermore, CA); Lavietes, Anthony D. (Hayward, CA)

    1998-05-29

    A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radio nuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components.

  2. Total Space Heating Water Heating Cook-

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2003 Total Fuel Oil Consumption (million gallons) Fuel Oil Energy Intensity (gallonssquare foot) Energy Information Administration 2003 Commercial Buildings Energy Consumption...

  3. Generalized Gravitational Entropy from Total Derivative Action

    E-Print Network [OSTI]

    Dong, Xi

    2015-01-01

    We investigate the generalized gravitational entropy from total derivative terms in the gravitational action. Following the method of Lewkowycz and Maldacena, we find that the generalized gravitational entropy from total derivatives vanishes. We compare our results with the work of Astaneh, Patrushev, and Solodukhin. We find that if total derivatives produced nonzero entropy, the holographic and the field-theoretic universal terms of entanglement entropy would not match. Furthermore, the second law of thermodynamics could be violated if the entropy of total derivatives did not vanish.

  4. Design Storm for Total Retention.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    endorse the viewpoint of a publication or guarantee its technical correctness. Title: Design Storm for "Total Retention" under Individual Permit, Poster, Individual Permit for...

  5. Zinc chromate induces chromosome instability and DNA double strand breaks in human lung cells

    SciTech Connect (OSTI)

    Xie Hong; Holmes, Amie L.; Young, Jamie L.; Qin Qin; Joyce, Kellie; Pelsue, Stephen C.; Peng Cheng; Wise, Sandra S.; Jeevarajan, Antony S.; Wallace, William T.; Hammond, Dianne; Wise, John Pierce E-mail: John.Wise@usm.maine.edu

    2009-02-01

    Hexavalent chromium Cr(VI) is a respiratory toxicant and carcinogen, with solubility playing an important role in its carcinogenic potential. Zinc chromate, a water insoluble or 'particulate' Cr(VI) compound, has been shown to be carcinogenic in epidemiology studies and to induce tumors in experimental animals, but its genotoxicity is poorly understood. Our study shows that zinc chromate induced concentration-dependent increases in cytotoxicity, chromosome damage and DNA double strand breaks in human lung cells. In response to zinc chromate-induced breaks, MRE11 expression was increased and ATM and ATR were phosphorylated, indicating that the DNA double strand break repair system was initiated in the cells. In addition, our data show that zinc chromate-induced double strand breaks were only observed in the G2/M phase population, with no significant amount of double strand breaks observed in G1 and S phase cells. These data will aid in understanding the mechanisms of zinc chromate toxicity and carcinogenesis.

  6. REGULATORY MECHANISMS OF SLC39A4 (ZIP4) AND SLC39A5 (ZIP5) IN THE ADAPTIVE RESPONSE TO ZINC AVAILABILITY

    E-Print Network [OSTI]

    Weaver, Benjamin Patrick

    2009-04-06

    family exports zinc from the cytosol; whereas, the Slc39a (Zrt-Irt-like protein, Zip) transporter family imports zinc into the cytosol. Mutations in several members of these transporter families give rise to distinct diseases. One such disease... transporters to prevent toxicity as discussed below. Less is known about zinc uptake and export during zinc replete but non-toxic conditions. Figure 1.2 provides an overview of the transport systems in gram negative bacteria such as Escherichia coli...

  7. Raman and far ir spectroscopic study of quaternary ammonium polybromide fused salt phases for zinc bromine circulating electrolyte batteries

    SciTech Connect (OSTI)

    Larrabee, J.A.; Graf, K.R.; Grimes, P.G.

    1985-01-01

    The circulating electrolyte zinc bromine battery is an attractive advanced battery system. The electrolyte is a solution of zinc bromide, quaternary ammonium bromides for bromine complexation and added salts to enhance properties. Laser Raman spectroscopy and far infrared spectroscopy were used to characterize the liquid quaternary ammonium polybromide fused salt phases.

  8. Band-Gap Engineering of Zinc Oxide Colloids via Lattice Substitution with Sulfur Leading to Materials with Advanced Properties for

    E-Print Network [OSTI]

    Nabben, Reinhard

    Band-Gap Engineering of Zinc Oxide Colloids via Lattice Substitution with Sulfur Leading requires a precise control over electronic properties. Zinc oxide is favorable for large the full inorganic UV protection are made. KEYWORDS: metal oxides, semiconductors, band gap engineering

  9. Research, development, and demonstration of nickel-zinc batteries for electric vehicle propulsion. Annual report for 1980

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    Progress in the development of nickel-zinc batteries for electric vehicles is reported. Information is presented on nickel electrode preparation and testing; zinc electrode preparation with additives and test results; separator development and the evaluation of polymer-blend separator films; sealed Ni-Zn cells; and the optimization of electric vehicle-type Ni-Zn cells. (LCL)

  10. Atmospheric pressure chemical vapor deposition of transparent conducting films of fluorine doped zinc oxide and their application

    E-Print Network [OSTI]

    crystal flat panel displays, energy efficient windows, gas sensors, surface acoustic wave devices loss or diffusion, which can lead to degra- dation in solar cell efficiency. Zinc oxide is more stable conducting oxides. This suggests zinc oxide may lead to higher solar cell efficiency than tin oxide

  11. Local environment in poly(ethylene oxide)-zinc bromide complexes

    SciTech Connect (OSTI)

    Chintipalli, S.; Frech, R.; Grady, B.

    1996-12-31

    This study examines atomic-level local environments in Poly(ethylene oxide)-zinc bromide+lithium bromide (PEO){sub 20}[(ZnBr{sub 2}){sub 1-x} (LiBr){sub x}] complexes using Raman spectroscopy and x-ray absorption spectroscopy (XAS). Specific features in the Raman spectra were used to show that the zinc bromide species changes from ZnBr{sub 2} to ZnBr{sub 3}{sup -} to ZnBr{sub 4}{sup 2-} when x is varied from 0 to 0.8. XAS showed a similar change in oxygen coordination number from 4 to 0 when x is varied from 0 to 0.8. This study shows that lithium atoms displace zinc atoms from ether oxygen speciation indicating that lithium coordination to ether oxygens is thermodynamically favored. The effect of adding polar plasticizers is also discussed.

  12. Evaluation of Novel Design Strategies for Developing Zinc Finger Nucleases Tools for Treating Human Diseases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bach, Christian; Sherman, William; Pallis, Jani; Patra, Prabir; Bajwa, Hassan

    2014-01-01

    Zinc finger nucleases (ZFNs) are associated with cell death and apoptosis by binding at countless undesired locations. This cytotoxicity is associated with the binding ability of engineered zinc finger domains to bind dissimilar DNA sequences with high affinity. In general, binding preferences of transcription factors are associated with significant degenerated diversity and complexity which convolutes the design and engineering of precise DNA binding domains. Evolutionary success of natural zinc finger proteins, however, evinces that nature created specific evolutionary traits and strategies, such as modularity and rank-specific recognition to cope with binding complexity that are critical for creating clinical viable toolsmore »to precisely modify the human genome. Our findings indicate preservation of general modularity and significant alteration of the rank-specific binding preferences of the three-finger binding domain of transcription factor SP1 when exchanging amino acids in the 2nd finger.« less

  13. Zirconium vanadium chromium alloy

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1980-10-14

    A ternary intermetallic compound having the formula Zr(V/sub 1-x/Cr/sub x/)/sub 2/ where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200/sup 0/C, at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  14. Vanadium Carbide Coating Process

    Broader source: Energy.gov [DOE]

    Traditional methods of coating steel surfaces with a layer of hard metal carbide require large capital investment, produce toxic and hazardous gases, are costly to operate, and require multiple...

  15. Humectants To Augment Current From Metallized Zinc Cathodic Protection Systems on Concrete

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino Jr., Bernard S.; Cramer, Stephen D.; Russell, James H. Russell; Bullard, Sophie J.; Collins, W. Keith; Bennett, Jack E.; Soltesz, Steven M.; Laylor, H. Martin

    2002-12-01

    Cathodic protection (CP) systems using thermal-sprayed zinc anodes are employed to mitigate the corrosion process in reinforced concrete structures. However, the performance of the anodes is improved by moisture at the anode-concrete interface. Research was conducted to investigate the effect of hydrophilic chemical additives, humectants, on the electrical performance and service life of zinc anodes. Lithium bromide and lithium nitrate were identified as feasible humectants with lithium bromide performing better under galvanic CP and lithium nitrate performing better under impressed current CP. Both humectants improved the electrical operating characteristics of the anode and increased the service life by up to three years.

  16. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, Raghubir P. (Durham, NC); Gangwal, Santosh K. (Durham, NC); Jain, Suresh C. (Morgantown, WV)

    1993-01-01

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.

  17. Recent technology improvements in Exxon's circulating zinc-bromine battery system

    SciTech Connect (OSTI)

    Bellows, R.J.

    1981-01-01

    Recent electrode and electrolyte performance on 500 wH and 3 kWh units indicates that Exxon's circulating zinc-bromine battery in 20 kWh designs will be capable of high energy density (65 to 70 wH/kg), and turn-around efficiency (65 to 70%). This performance, coupled with recent factory cost projections of $28/kWh (exclusive of R.O.I. and various indirect overheads), makes zinc/bromine an attractive advanced battery candidate for not only photovoltaic, but also electric vehicle and bulk energy storage applications. Recent technical developments in this program may be generally useful in other circulating electrolyte systems.

  18. LOW TEMPERATURE VOC COMBUSTION OVER MANGANESE, COBALT AND ZINC ALPO4 MOLECULAR SIEVES

    SciTech Connect (OSTI)

    Rosemarie Szostak

    2003-03-06

    The objective of this project was to prepare microporous aluminophosphates containing magnesium, manganese, cobalt and zinc (MeAPOs) and to evaluate their performance as oxidation catalysts for the removal of low levels of volatile organic compounds (VOCs) from gas streams. The tasks to be accomplished were as follows: (1) To develop reliable synthesis methods for metal aluminophosphates containing manganese, cobalt and zinc in their framework; (2) To characterize these materials for crystallinity, phase purity, the location and nature of the incorporated metal in the framework; and (3) To evaluate the materials for their catalytic activities in the oxidation of volatile organic environmental pollutants.

  19. Fluidizable zinc titanate materials with high chemical reactivity and attrition resistance

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1993-10-19

    Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 [mu]m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO[sub 3]; and then indurating it at 800 to 900 C for a time sufficient to produce attrition-resistant granules.

  20. The V{sup 4}+/V{sup 5+} balance as a criterion of selection of vanadium phosphorus oxide catalysts for n-butane oxidation to maleic anhydride: A proposal to explain the role of Co and Fe dopants

    SciTech Connect (OSTI)

    Sananes-Schulz, M.T.; Tuel, A.; Volta, J.C.; Hutchings, G.J.

    1997-03-01

    Vanadium phosphorous oxide catalysts (VPO) are well known for the oxidation of n-butane to maleic anhydride, and many papers and patents have been published in the literature on this catalytic system. Concerning the valence state of vanadium in the active surface, a V{sup 4+}/V{sup 5+} equilibrium on the surface of a vanadyl pyrophosphate during n-butane oxidation has been demonstrated which is dependent on the time of activation. In the present note, we study the modifications, as determined by {sup 31}P NMR by spin echo mapping, which are induced in the physicochemical characteristics of VPO catalysts which have major differences in their morphologies when doped with iron and cobalt at a low percentage (1%) and the correlation with their catalytic performances. 21 refs., 5 figs., 2 tabs.

  1. Enantioselective Total Synthesis of (?)-Acylfulvene and (?)- Irofulven

    E-Print Network [OSTI]

    Movassaghi, Mohammad

    We report our full account of the enantioselective total synthesis of (?)-acylfulvene (1) and (?)-irofulven (2), which features metathesis reactions for the rapid assembly of the molecular framework of these antitumor ...

  2. Total synthesis of cyclotryptamine and diketopiperazine alkaloids

    E-Print Network [OSTI]

    Kim, Justin, Ph. D. Massachusetts Institute of Technology

    2013-01-01

    I. Total Synthesis of the (+)-12,12'-Dideoxyverticillin A The fungal metabolite (+)-12,12'-dideoxyverticillin A, a cytotoxic alkaloid isolated from a marine Penicillium sp., belongs to a fascinating family of densely ...

  3. TotalView Parallel Debugger at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The performance of the GUI can be greatly improved if used in conjunction with free NX software. The TotalView documentation web page is a good resource for learning more...

  4. Million Cu. Feet Percent of National Total

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    as known volumes of natural gas that were the result of leaks, damage, accidents, migration, andor blow down. Notes: Totals may not add due to independent rounding. Prices are...

  5. Total Energy Management in General Motors 

    E-Print Network [OSTI]

    DeKoker, N.

    1979-01-01

    This paper presents an overview of General Motors' energy management program with special emphasis on energy conservation. Included is a description of the total program organization, plant guidelines, communication and motivation techniques...

  6. Total synthesis and study of myrmicarin alkaloids

    E-Print Network [OSTI]

    Ondrus, Alison Evelynn, 1981-

    2009-01-01

    I. Enantioselective Total Synthesis of Tricyclic Myrmicarin Alkaloids An enantioselective gram-scale synthesis of a key dihydroindolizine intermediate for the preparation of myrmicarin alkaloids is described. Key transformations ...

  7. Ductile polyelectrolyte macromolecule-complexed zinc phosphate conversion crystal pre-coatings and topcoatings embodying a laminate

    DOE Patents [OSTI]

    Sugama, Toshifumi; Kukacka, L.E.; Carciello, N.R.

    1985-11-05

    This invention relates to a precoat, laminate, and method for ductile coatings on steel and non-ferrous metals which comprises applying a zinc phosphating coating solution modified by a solid polyelectrolyte selected from polyacrylic acid (PAA), polymethacrylic acid (PMA), polyitaconic acid (PIA), and poly-L-glutamic acid. The contacting of the resin with the phosphating solution is made for a period of up to 20 hours at about 80/sup 0/C. The polyelectrolyte or the precoat is present in about 0.5 to 5.0% by weight of the total precoat composition and after application, the precoat base is dried for up to 5 hours at about 150/sup 0/C to desiccate. Also, a laminate may be formed where polyurethane (PU) is applied as an elastomeric topcoating or polyfuran resin is applied as a glassy topcoating. It has been found that the use of PAA at a molecular weight of about 2 x 10/sup 5/ gave improved ductility modulus effect.

  8. Advanced zinc phosphate conversion coatings. Final report, June 1996--December 1996

    SciTech Connect (OSTI)

    Handsy, C.I. [ATSTA-TMC, Warren, MI (United States); Sugama, T. [Brookhaven National Lab., Upton, NY (United States)

    1997-04-01

    A SERDP-sponsored program aims at developing environmentally benign zinc phosphate conversion coatings and their process technologies for the electrogalvanized steel (EGS). We succeeded in formulating an environmentally acceptable phosphate solution without Co- and Ni-related additives, and also in replacing a hexavalent Cr acid sealant applied over the zinc phosphate (Zh-Ph) layers with a water-based polysiloxane sealers. The specific advantages of the newly developed Zn-Ph coatings were as follows: (1) there was rapid growth of uniform, dense embryonic Zn-Ph crystals on the EGS surfaces due to the creation of short-circuited cells with Mn acting as the cathode and the galvanized (zinc) coatings as the anode, (2) an excellent protection layer against corrosion was formed, extending the service life of zinc layers as galvanic sacrifice barriers, and (3) adhesion to the electro-deposited polymeric primer coating was improved because of the interaction between the siloxane sealer and primer. A full-scale demonstration to evaluate the reproducibility of this new coating technology on mini-sized automotive door panels made from EGS was carried out in collaboration with the Palnut Company (as industrial coating applicator) in New Jersey. All of the 150 mini-door panels were successfully coated with Zn-Ph.

  9. First Stabilization and Disposal of Radioactive Zinc Bromide at the SRS

    SciTech Connect (OSTI)

    Denny, J.K.

    2003-02-12

    Facilities Disposition Projects (FDP) personnel at Savannah River Site (SRS) implement the Inactive Facility Risk Management Program to drive down risk and costs in SRS inactive facilities. The program includes cost-effective techniques to identify and dispose of hazardous chemicals and radioactive waste from inactive facilities, thereby ensuring adequate protection of the public, workers and the environment. In June 1998, FDP conducted an assessment of the inactive C-Reactor Facility to assure that chemical and radiological hazards had been identified and were being safely managed. The walkdown identified the need to mitigate a significant hazard associated with storing approximately 13,400 gallons of liquid radioactive Zinc Bromide in three aging railcar tankers outside of the facility. No preventive maintenance was being performed on the rusting tankers and a leak could send radioactive Zinc Bromide into an outfall and offsite to the Savannah River. In 2001, DOE-Savannah River (DOE- SR) funded the FDP to eliminate the identified hazard by disposing of the radioactive Zinc Bromide solution and the three contaminated railcar tankers. This paper describes the innovative, cost-effective approaches and technology used to perform the first stabilization and disposal of radioactive Zinc Bromide at SRS.

  10. Copper and zinc balance in exercising horses fed two forms of mineral supplements 

    E-Print Network [OSTI]

    Wagner, Elizabeth Lynn

    2009-05-15

    This study was undertaken to compare the absorption and retention of copper and zinc when supplemented to exercising horses in the form of sulfate or organic-chelate mineral supplements. Nine mature horses were used in a modified-switchback designed...

  11. Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)-Benzenetricarboxylate Network

    E-Print Network [OSTI]

    Yaghi, Omar M.

    solution containing 1,3,5-benzenetricarboxylic acid (H3BTC) and zinc(II) nitrate hexahydrate yields crystalline Zn2(BTC)(NO3),(H2O)(C2H5OH)5, which was formulated by elemental microanalysis, solid-state NMR functionality of BTC imparts rigidity to the structure, consequently allowing the guests to be removed

  12. Ecotoxicology 2, 68-78 (1994) Zinc, among a `cocktail' of metal pollutants, is

    E-Print Network [OSTI]

    Hopkin, Steve

    1994-01-01

    ) contaminated in the laboratory with arange of concentrations of cadmium, copper, lead or zinc. The metals were applied topically to the leaves as nitrates. Growth and survival, numbers of live offspring produced). The relative toxicities of the four metals in the laboratory were compared with concentrations of cadmium

  13. Regulation of Carbonic Anhydrase Expression by Zinc, Cobalt, and Carbon Dioxide in the Marine Diatom

    E-Print Network [OSTI]

    Morel, François M. M.

    Regulation of Carbonic Anhydrase Expression by Zinc, Cobalt, and Carbon Dioxide in the Marine of carbonic anhydrase (CA) in the marine diatom Thalassiosira weissflogii. We have examined the roles for Zn in a CA. Our data also support the conclusion that TWCA1 plays a central role in carbon

  14. Method and apparatus for maintaining the pH in zinc-bromine battery systems

    DOE Patents [OSTI]

    Grimes, Patrick G. (Westfield, NJ)

    1985-09-10

    A method and apparatus for maintaining the pH level in a zinc-bromine battery features reacting decomposition hydrogen with bromine in the presence of a catalyst. The catalyst encourages the formation of hydrogen and bromine ions. The decomposition hydrogen is therefore consumed, alloying the pH of the system to remain substantially at a given value.

  15. Journal of the European Ceramic Society 27 (2007) 941945 Synthesis of nanosized zinc ferrites from liquid

    E-Print Network [OSTI]

    Gubicza, Jenő

    2007-01-01

    as compared to normal spinels.6 Thermal plasmas, such as direct current (dc) arcs8 and radiofrequency9,10 (RF liquid precursors in RF thermal plasma reactor Ilona Mohaia,, Lor´and G´ala, J´anos Sz´epv¨olgyia,c, Jeno thermal plasma conditions. Ethanol solutions of the mixture of zinc- and iron- nitrates were used

  16. Optimization and Characterization of RF Sputtered Piezoelectric Zinc Oxide Thin Film for

    E-Print Network [OSTI]

    Tang, William C

    Oxide (ZnO) thin films had been found to have unique piezoelectric effect for the applicationsOptimization and Characterization of RF Sputtered Piezoelectric Zinc Oxide Thin Film for Transducer Applications Yu-Hsiang Hsu, John Lin, and William C. Tang* Department of Biomedical Engineering University

  17. Field performance of sprayed zinc anodes in controlling corrosion of steel reinforced concrete

    SciTech Connect (OSTI)

    Tinnea, J.

    1998-12-31

    The deterioration of concrete structures often results from the corrosion of their steel reinforcement. Cathodic protection (CP) is a proven means to stop rebar corrosion. One anode material gaining acceptance in the infrastructure corrosion fight is zinc thermal spray coating. This paper discusses an investigation of such CP systems.

  18. Atomic-layer-deposited zinc oxide as tunable uncooled infrared microbolometer material

    E-Print Network [OSTI]

    Akin, Tayfun

    Atomic-layer-deposited zinc oxide as tunable uncooled infrared microbolometer material Enes Battal1 May 2014, accepted 31 May 2014 Published online 7 July 2014 Keywords atomic layer deposition investigate the application potential of atomic-layer-deposited ZnO in uncooled micro- bolometers

  19. Spectroscopic Properties of a Self-Assembled Zinc Porphyrin Tetramer II. Time-Resolved Fluorescence Spectroscopy

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Spectroscopic Properties of a Self-Assembled Zinc Porphyrin Tetramer II. Time-Resolved Fluorescence tetramer [Part I], with a 1 ns rotational correlation time at 10 °C. The initial fluorescence anisotropy of the monomer is found to be 0.1. In the tetramer an additional depolarization process occurs with a correlation

  20. The effect of zinc methionine or copper lysine on stocker calves grazing oat pastures 

    E-Print Network [OSTI]

    Griffeth, Laura Ann

    1993-01-01

    Fourty eight Hereford and Angus stocker steers (average weight 259.7 kg) were placed in twelve, five acre, pastures (four steers per pasture) planted with oat forage for a 91 d grazing trial to determine the effect of supplementing zinc methionine...

  1. Improving Prediction of Zinc Binding Sites by Modeling the Linkage between Residues Close in

    E-Print Network [OSTI]

    Passerini, Andrea

    organisms after iron. In contrast to other transition metal ions, such as copper and iron, zinc(II) does. For this reason, several sites can be identified with high precision just mining regular expression patterns along the protein sequence. The method presented in [8] mines patterns from metalloproteins having known structure

  2. Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration Devices

    E-Print Network [OSTI]

    Clark, Shirley E.

    Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration in stormwater runoff and a decrease in groundwater recharge. Stormwater runoff contains pollutants (nutrients to the degradation of surface waters below stormwater pipe outfalls. Infiltrating stormwater has been shown

  3. Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust

    DOE Patents [OSTI]

    Zaromb, S.; Lawson, D.B.

    1994-02-15

    A process for recovering zinc-rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered by distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10 C, separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream. 1 figure.

  4. Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust

    DOE Patents [OSTI]

    Zaromb, Solomon (95706 William Dr., Hinsdale, IL 60521); Lawson, Daniel B. (925 Putnam Dr., Lockport, IL 60441)

    1994-01-01

    A process for recovering zinc/rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10.degree. C., separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream.

  5. Zinc and mechanical prowess in the jaws of Nereis, a marine worm

    E-Print Network [OSTI]

    Lichtenegger, Helga C.

    Zinc and mechanical prowess in the jaws of Nereis, a marine worm Helga C. Lichtenegger* , Thomas of the marine polychaete worm Nereis sp. High copper levels in the polychaete worm Glycera dibranchiata recently in their jaws, whereas others accumulate Cu (9­12). Polychaete worms live in marine sedi- ment and are common

  6. Synthesis, characterization and photocatalytic properties of novel zinc germanate nano-materials

    SciTech Connect (OSTI)

    Boppana, Venkata Bharat Ram; Hould, Nathan D.; Lobo, Raul F.

    2011-05-15

    We report the first instance of a hydrothermal synthesis of zinc germanate (Zn{sub 2}GeO{sub 4}) nano-materials having a variety of morphologies and photochemical properties in surfactant, template and catalyst-free conditions. A systematic variation of synthesis conditions and detailed characterization using X-ray diffraction, ultraviolet-visible diffuse reflectance spectroscopy, Raman spectroscopy, electron microscopy, X-ray photoelectron spectroscopy and small angle X-ray scattering led to a better understanding of the growth of these particles from solution. At 140 {sup o}C, the zinc germanate particle morphology changes with pH from flower-shaped at pH 6.0, to poly-disperse nano-rods at pH 10 when the Zn to Ge ratio in the synthesis solution is 2. When the Zn to Ge ratio is reduced to 1.25, mono-disperse nano-rods could be prepared at pH 7.5. Nanorod formation is also independent of the addition of cetyltrimethylammonium bromide (CTAB), in contrast to previous reports. Photocatalytic tests show that Zn{sub 2}GeO{sub 4} nano-rods (by weight) and flower shaped (by surface area) are the most active for methylene blue dye degradation among the synthesized zinc germanate materials. -- Graphical abstract: Zinc germanate materials were synthesized possessing unique morphologies dependent on the hydrothermal synthesis conditions in the absence of surfactant, catalyst or template. These novel materials are characterized and evaluated for their photocatalytic activities. Display Omitted highlights: > Zinc germanate synthesized hydrothermally (surfactant free) with unique morphologies. > Flower-shaped, nano-rods, globular particles obtained dependent on synthesis pH. > At 140 {sup o}C, they possess the rhombohedral crystal irrespective of synthesis conditions. > They are photocatalytically active for the degradation of methylene blue. > Potential applications could be photocatalytic water splitting and CO{sub 2} reduction.

  7. The $?^* ?^*$ total cross section in NLA BFKL

    E-Print Network [OSTI]

    Dmitry Yu. Ivanov; Beatrice Murdaca; Alessandro Papa

    2014-11-16

    We study the $\\gamma^* \\gamma^*$ total cross section in the NLA BFKL approach. We have extracted the NLO corrections to the photon impact factor from two recent papers of Balitsky and Chirilli and Chirilli and Kovchegov and used them to build several representations of the total cross section, equivalent within the NLA. We have combined these different representations with two among the most common methods for the optimization of a perturbative series, namely PMS and BLM, and compared their behavior with the energy with the only available experimental data, those from the LEP2 collider.

  8. Total Cross Sections for Neutron Scattering

    E-Print Network [OSTI]

    C. R. Chinn; Ch. Elster; R. M. Thaler; S. P. Weppner

    1994-10-19

    Measurements of neutron total cross-sections are both extensive and extremely accurate. Although they place a strong constraint on theoretically constructed models, there are relatively few comparisons of predictions with experiment. The total cross-sections for neutron scattering from $^{16}$O and $^{40}$Ca are calculated as a function of energy from $50-700$~MeV laboratory energy with a microscopic first order optical potential derived within the framework of the Watson expansion. Although these results are already in qualitative agreement with the data, the inclusion of medium corrections to the propagator is essential to correctly predict the energy dependence given by the experiment.

  9. Total Synthesis of (()-Ginkgolide B Michael T. Crimmins,* Jennifer M. Pace,

    E-Print Network [OSTI]

    of ginkgolide B utilizing the zinc-copper homoenolate9 and double diastereoselective intramolecular [2% overall yield. Addition of ethynylmagnesium bromide to aldehyde 5 gave a 1.2:1 mixture of the syn and anti of the synthesis. Exposure of 7 to the zinc-copper homoenolate 8 [HMPA, THF, Et2O] resulted in the formation of (1

  10. Design and synthesis of novel functionalized sensors for the biological imaging of zinc(II) and nitric oxide

    E-Print Network [OSTI]

    Won, Annie C., 1983-

    2005-01-01

    CHAPTER 1: Fluorescent Sensors for the Biological sensing of Zinc(II) A variety of fluorescent techniques have been developed for the in vivo sensing of Zn2+. This chapter presents a brief overview of techniques used to ...

  11. Effect of Ancillary Ligands on the Reactivity and Structure of Zinc Polysulfido Complexes Robert J. Pafford and Thomas B. Rauchfuss*

    E-Print Network [OSTI]

    Rauchfuss, Thomas B.

    Effect of Ancillary Ligands on the Reactivity and Structure of Zinc Polysulfido Complexes Robert J in ancillary ligands. This aspect has not been examined previously, but the present work shows that ancillary

  12. Crystal growth, structure and characterizations of a new semiorganic nonlinear optical material-{beta}-Alanine zinc chloride

    SciTech Connect (OSTI)

    Anbuchezhiyan, M. [Department of Physics, Valliammai Engineering College, S.R.M. Nagar, Kattankulathur, Chennai 603203 (India)] [Department of Physics, Valliammai Engineering College, S.R.M. Nagar, Kattankulathur, Chennai 603203 (India); Ponnusamy, S., E-mail: suruponnus@gmail.com [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India); Muthamizhchelvan, C. [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India)] [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India); Sivakumar, K. [Department of Physics, Anna University, Chennai 600 025 (India)] [Department of Physics, Anna University, Chennai 600 025 (India)

    2010-08-15

    The title compound, {beta}-alanine zinc chloride-a new semiorganic nonlinear optical crystal was grown by slow evaporation technique. Single crystals of {beta}-alanine zinc chloride have been subjected to X-ray diffraction analysis to determine the crystal structure. The powder X-ray diffractogram of the crystal has also been recorded. The amount of carbon, nitrogen and hydrogen in the crystals was also estimated. Fourier Transform Infrared and Raman spectral measurements have been carried out on the grown crystals in order to identify the functional groups. The presence of hydrogen and carbon in the {beta}-alanine zinc chloride was confirmed by using proton and carbon nuclear magnetic resonance spectral analyses. The percentage of zinc in the crystal was determined by atomic absorption spectroscopy. Optical behavior such as ultraviolet-vis-near infrared transmittance spectrum and second harmonic generation has been investigated. The mechanical strength and thermal behavior of the grown crystal have been analyzed.

  13. The effects of exercise and dietary fat on calcium, magnesium, iron, and zinc on selected tissues in rats 

    E-Print Network [OSTI]

    Nguyen, Thuy Huong

    1989-01-01

    of the requirements for the degree MASTER OF SCIENCE December 1989 Major Subject: Nutrition THE EFFECTS OF EXERCISE AND DIETARY FAT ON CALCIUM, MAGNESIUM, IRON, AND ZINC ON SELECTED TISSUES IN RATS A Thesis by THUY HUONG NGUYEN Approved as to style... and content by: Karen S. ubena (Chair of Committee) L. yne Greene (Member) Barbara C. O' Brien (Member) Gary C. Smith (Head of Department) December 1989 ABSTRACT The Effects of Exercise and Dietary Fat on Calcium, Magnesium, Iron, and Zinc...

  14. Frustrated total internal reflection acoustic field sensor

    DOE Patents [OSTI]

    Kallman, Jeffrey S. (Pleasanton, CA)

    2000-01-01

    A frustrated total internal reflection acoustic field sensor which allows the acquisition of the acoustic field over an entire plane, all at once. The sensor finds use in acoustic holography and acoustic diffraction tomography. For example, the sensor may be produced by a transparent plate with transparent support members tall enough to support one or more flexible membranes at an appropriate height for frustrated total internal reflection to occur. An acoustic wave causes the membrane to deflect away from its quiescent position and thus changes the amount of light that tunnels through the gap formed by the support members and into the membrane, and so changes the amount of light reflected by the membrane. The sensor(s) is illuminated by a uniform tight field, and the reflection from the sensor yields acoustic wave amplitude and phase information which can be picked up electronically or otherwise.

  15. A simple model for a zinc/bromine flow cell and associated storage tanks

    SciTech Connect (OSTI)

    Simpson, G.D.; White, R.E. . Dept. of Chemical Engineering)

    1990-06-01

    A simple model for a parallel plate, zinc/bromine flow cell and associated storage tanks is presented and used to make time-dependent predictions for various quantities in the system. The model is based on a previously published algebraic model of the cell at steady-state and time-dependent, first-order differential equations for the storage tanks. The Butler--Volmer equation is used for the electrochemical reactions, and the homogeneous reaction between bromine and bromide is included. The model predictions indicate that the charging operation of a zinc/bromine battery can be significantly improved by using a storage tank with a larger residence time for the bromine side of the system.

  16. Multi-wavelength Raman scattering of nanostructured Al-doped zinc oxide

    SciTech Connect (OSTI)

    Russo, V.; Ghidelli, M.; Gondoni, P. [Dipartimento di Energia and NEMAS, Center for Nanoengineered Materials and Surfaces, Politecnico di Milano, via Ponzio 34/3, I-20133 Milano (Italy); Casari, C. S.; Li Bassi, A. [Dipartimento di Energia and NEMAS, Center for Nanoengineered Materials and Surfaces, Politecnico di Milano, via Ponzio 34/3, I-20133 Milano (Italy); Center for Nano Science and Technology PoliMI, Istituto Italiano di Tecnologia, Via Pascoli 70/3, I-20133 Milano (Italy)

    2014-02-21

    In this work we present a detailed Raman scattering investigation of zinc oxide and aluminum-doped zinc oxide (AZO) films characterized by a variety of nanoscale structures and morphologies and synthesized by pulsed laser deposition under different oxygen pressure conditions. The comparison of Raman spectra for pure ZnO and AZO films with similar morphology at the nano/mesoscale allows to investigate the relation between Raman features (peak or band positions, width, relative intensity) and material properties such as local structural order, stoichiometry, and doping. Moreover Raman measurements with three different excitation lines (532, 457, and 325?nm) point out a strong correlation between vibrational and electronic properties. This observation confirms the relevance of a multi-wavelength Raman investigation to obtain a complete structural characterization of advanced doped oxide materials.

  17. Isotope effect evidence for the zinc hydroxide mechanism of carbonic anhydrase catalyst

    SciTech Connect (OSTI)

    Paneth, P.; O'Leary, M.H.

    1987-03-24

    The carbon kinetic isotope effect on the enzymatic dehydration of HCO/sub 3//sup -/ ion is k/sup 12//k/sup 13/ = 1.011 and is independent, within experimental error, of the addition of sucrose, substitution of D/sub 2/O for H/sub 2/O, and substitution of enzyme-bound Zn/sup 2 +/ by Co/sup 2 +/. These results are consistent with a ping-pong mechanism in which proton transfer between enzyme and solvent is separated from HCO/sub 3//sup -/ dehydration. For the dehydration half-reaction, diffusional processes are severalfold faster than dehydration, and the rate-determining step is the dehydration itself. The intrinsic isotope effect is approximately 1.011, indicating that hydration of CO/sub 2/ occurs by reaction of zinc-bound OH/sup -/, rather than zinc-bound H/sub 2/O.

  18. Isotope effect evidence for the zinc hydroxide mechanism of carbonic anhydrase catalysis

    SciTech Connect (OSTI)

    Paneth, P.; O'Leary, M.H.

    1987-03-24

    The carbon kinetic isotope effect on the enzymatic dehydration of HCO/sub 3/- ion is k12/k13 = 1.011 and is independent, within experimental error, of the addition of sucrose, substitution of D/sub 2/O for H/sub 2/O, and substitution of enzyme-bound Zn/sup 2 +/ by Co/sup 2 +/. These results are consistent with a ping-pong mechanism in which proton transfer between enzyme and solvent is separated from HCO/sub 3/- dehydration. For the dehydration half-reaction, diffusional processes are severalfold faster than dehydration, and the rate-determining step is the dehydration itself. The intrinsic isotope effect is approximately 1.011, indicating that hydration of CO/sub 2/ occurs by reaction of zinc-bound OH-, rather than zinc-bound H/sub 2/O.

  19. Colloidal infrared reflective and transparent conductive aluminum-doped zinc oxide nanocrystals

    DOE Patents [OSTI]

    Buonsanti, Raffaella; Milliron, Delia J

    2015-02-24

    The present invention provides a method of preparing aluminum-doped zinc oxide (AZO) nanocrystals. In an exemplary embodiment, the method includes (1) injecting a precursor mixture of a zinc precursor, an aluminum precursor, an amine, and a fatty acid in a solution of a vicinal diol in a non-coordinating solvent, thereby resulting in a reaction mixture, (2) precipitating the nanocrystals from the reaction mixture, thereby resulting in a final precipitate, and (3) dissolving the final precipitate in an apolar solvent. The present invention also provides a dispersion. In an exemplary embodiment, the dispersion includes (1) nanocrystals that are well separated from each other, where the nanocrystals are coated with surfactants and (2) an apolar solvent where the nanocrystals are suspended in the apolar solvent. The present invention also provides a film. In an exemplary embodiment, the film includes (1) a substrate and (2) nanocrystals that are evenly distributed on the substrate.

  20. Synthesis and dielectric properties of zinc oxide nanoparticles using a biotemplate

    SciTech Connect (OSTI)

    P, Sharmila P, E-mail: sharmilavishram@gmail.com [Sree Narayana College, Kollam, Kerala, India and T.K Madhva Memorial College, Nangiarkulungara, Alapuzha, Kerala (India); Tharayil, Nisha J., E-mail: nishajohntharayil@gmail.com [Sree Narayana College for Women Kollam, Kerala (India)

    2014-10-15

    Zinc Oxide nanoparticles are synthesized using DNA as capping agent. Zinc oxide nanoparticles are synthesized using DNA as a capping agent. Structural and morphological characterizations are done using SEM, FTIR and XRD. The particle size and lattice parameters are calculated from the diffraction data. The optical properties are studied using UV-Vis absorption spectroscopy and bandgap variation with temperature is determined. The dielectric property of nanoparticles is studied by varying temperature and frequency. The dielectric constant and dispersion parameters are found out. Method of Cole-Cole analysis is used to study the high temperature dispersion of relaxation time. The variation of both AC and DC conductivity are studied and activation energy calculated.