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1

Vanadium Redox Flow Batteries  

Science Conference Proceedings (OSTI)

The vanadium redox flow battery, sometimes abbreviated as VRB, is an energy storage technology with significant potential for application in a wide range of contexts. Vanadium redox batteries have already been used in a number of demonstrations in small-scale utility-scale applications, and it is believed that the technology is close to being viable for more widespread use. This report examines the vanadium redox technology, including technical performance and cost issues that drive its application today...

2007-03-30T23:59:59.000Z

2

Fact Sheet: Vanadium Redox Flow Batteries (October 2012) | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vanadium Redox Flow Batteries (October 2012) Vanadium Redox Flow Batteries (October 2012) Fact Sheet: Vanadium Redox Flow Batteries (October 2012) DOE's Energy Storage Program is funding research to develop next-generation vanadium redox flow batteries (VRBs) that reduce costs by improving energy and power densities, widening the operating temperature window, and simplifying and optimizing stack/system designs. These efforts build on Pacific Northwest National Laboratory research that has developed new redox electrolytes that enable increased VRB operating temperatures and energy storage capabilities. Fact Sheet: Vanadium Redox Flow Batteries (October 2012) More Documents & Publications Energy Storage Systems 2012 Peer Review Presentations - Day 3, Session 2 Energy Storage Systems 2012 Peer Review Presentations - Poster Session 2

3

In-situ Investigation of Vanadium Ion Transport in Redox Flow Battery  

Science Conference Proceedings (OSTI)

We will show a new method to differentiate the vanadium transport from concentration gradient and that from electric field. Flow batteries with vanadium and iron redox couples as the electro-active species were employed to investigate the transport behavior of vanadium ions in the presence of electric field. It was shown that electric field accelerated the positive-to-negative and reduced the negative-to-positive vanadium ions transport in charge process and affected the vanadium ions transport in an opposite way in discharge process. In addition, a method was designed to differentiate the concentration gradient-driven vanadium ions diffusion and electric field-driven vanadium ions migration. Simplified mathematical model was established to simulate the vanadium ions transport in real charge-discharge operation of flow battery. The concentration gradient diffusion coefficients and electric-migration coefficients of V2+, V3+, VO2+, and VO2+ across Nafion membrane were obtained by fitting the experimental data.

Luo, Qingtao; Li, Liyu; Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Chen, Baowei; Yang, Zhenguo

2012-06-27T23:59:59.000Z

4

Advanced Vanadium Redox Flow Batteries with Mixed Acid ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Large-scale energy storage technologies like redox flow batteries have been sought for renewable integration and smart grid applications.

5

Spectroscopic Investigations of the Fouling Process on Nafion Membranes in Vanadium Redox Flow Batteries  

DOE Green Energy (OSTI)

The Nafion-117 membrane used in vanadium redox flow battery (VRFB) is analyzed by X-ray photoelectron spectroscopy (XPS) and nuclear magnetic resonance (NMR) spectroscopy. The XPS study reveals the chemical identity and environment of vanadium cations accumulated at the surface due to their low diffusivity. On the other hand, the 17O NMR spectrum explores the diffused vanadium cation from the bulk part of Nafion and shows the chemical bonding of cation and the host membrane. The 19F NMR shows the basic Nafion structure is not altered due to the presence of diffused vanadium cation. Based on these spectroscopic studies, the chemical environment of diffused vanadium cation in the Nafion membrane is discussed. This study also shed light into the possible cause for the high diffusivity of certain vanadium cations inside the Nafion membranes.

Vijayakumar, M.; Sivakumar, Bhuvaneswari M.; Nachimuthu, Ponnusamy; Schwenzer, Birgit; Kim, Soowhan; Yang, Zhenguo; Liu, Jun; Graff, Gordon L.; Thevuthasan, Suntharampillai; Hu, Jian Z.

2011-01-01T23:59:59.000Z

6

Redox Flow Batteries: a Review  

NLE Websites -- All DOE Office Websites (Extended Search)

1137-1164 Date Published 102011 ISSN 1572-8838 Keywords Flow battery, Flow cell, Redox, Regenerative fuel cell, Vanadium Abstract Redox flow batteries (RFBs) are enjoying a...

7

Investigation of Local Environments in Nafion-SiO2 Composite Membranes used in Vanadium Redox Flow Batteries  

SciTech Connect

The proton conducting polymer composite membranes are of technological interest in many energy devices such as fuel cells and redox flow batteries. In particular, the polymer composite membranes such as SiO2 incorporated Nafion membranes are recently reported as highly promising for the redox flow batteries. However, there is conflicting reports regarding the performance of this Nafion-SiO2 composite membrane in the redox flow cell. This paper presents results of the analysis of the Nafion-SiO2 composite membrane used in a vanadium redox flow battery by nuclear magnetic resonance (NMR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Fourier Transformed Infra Red (FTIR) spectroscopy, and ultraviolet visible spectroscopy. The XPS study reveals the chemical identity and environment of vanadium cations accumulated at the surface. On the other hand, the 19F and 29Si NMR measurement explores the nature of the interaction between the silica particles, Nafion side chains and diffused vanadium cations. The 29Si NMR shows that the silica particles interaction via hydrogen bonds to the sulfonic groups of Nafion and diffused vanadium cations. Based on these spectroscopic studies, the chemical environment of the silica particles inside the Nafion membrane and their interaction with diffusing vanadium cations during flow cell operations are discussed. This study discusses the origin of performance degradation of the Nafion-SiO2 composite membrane materials in vanadium redox flow batteries.

Vijayakumar, M.; Schwenzer, Birgit; Kim, Soowhan; Yang, Zhenguo; Thevuthasan, Suntharampillai; Liu, Jun; Graff, Gordon L.; Hu, Jian Z.

2012-04-01T23:59:59.000Z

8

Fact Sheet: Vanadium Redox Flow Batteries (October 2012)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Breakthrough Breakthrough Researchers at Pacific Northwest National Laboratory have developed a new sulfate (SO 4 2- ) and chloride (Cl - ) mixed solution that is used as the electrolyte. Compared to pure sulfuric acid, the new solution can hold more than 70% more vanadium ions, increasing energy storage capacity by more than 70%. The use of Cl - in the new solution also increases the operating temperature window by 83%, so the battery

9

Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries  

Science Conference Proceedings (OSTI)

The stability of the electrolytes for all-vanadium redox flow battery was investigated with ex-situ heating/cooling treatment and in-situ flow-battery testing methods. The effects of inorganic and organic additives have been studied. The additives containing the ions of potassium, phosphate, and polyphosphate are not suitable stabilizing agents because of their reactions with V(V) ions, forming precipitates of KVSO6 or VOPO4. Of the chemicals studied, polyacrylic acid and its mixture with CH3SO3H are the most promising stabilizing candidates which can stabilize all the four vanadium ions (V2+, V3+, VO2+, and VO2+) in electrolyte solutions up to 1.8 M. However, further effort is needed to obtain a stable electrolyte solution with >1.8 M V5+ at temperatures higher than 40 C.

Zhang, Jianlu; Li, Liyu; Nie, Zimin; Chen, Baowei; Vijayakumar, M.; Kim, Soowhan; Wang, Wei; Schwenzer, Birgit; Liu, Jun; Yang, Zhenguo

2011-10-01T23:59:59.000Z

10

Towards Understanding the Poor Thermal Stability of V5+ Electrolyte Solution in Vanadium Redox Flow Batteries  

DOE Green Energy (OSTI)

The V5+ electrolyte solution from vanadium redox flow batteries was studied by variable temperature 17O and 51V Nuclear Magnetic Resonance (NMR) spectroscopy and DFT based computational modeling. It was found that the V5+ species exist as hydrated penta co-ordinated vanadate ion, i.e. [VO2(H2O)3]1+. This hydrated structure is not stable at elevated temperature and change into neutral H3VO4 molecule via a deprotonation process. H3VO4 species is also knowingly unstable, leading to the observed V2O5 precipitation in V5+ electrolyte solutions.

Vijayakumar, M.; Li, Liyu; Graff, Gordon L.; Liu, Jun; Zhang, Huamin; Yang, Zhenguo; Hu, Jian Z.

2011-04-01T23:59:59.000Z

11

Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s  

Science Conference Proceedings (OSTI)

Sulfonated Diels Alder poly(phenylene) (SDAPP) was examined for vanadium redox flow battery (VRFB) use. The ion exchange capacity (IEC) was varied from 1.4, 1.6 and 2.0 meq/g in order to tune the proton conductivity and vanadium permeability. Coulombic efficiencies between 92 to 99% were observed, depending on IEC (lower IEC, higher coulombic efficiencies). In all cases the SDAPP displayed comparable energy efficiencies (88 - 90%) to Nafion 117 (88%) at 50mA/cm2. Membrane durability also was dependent on IEC; SDAPP with the highest IEC lasted slightly over 50 cycles while SDAPP with the lowest IEC lasted over 400 cycles and testing was discontinued only due to time constraints. Accelerated vanadium lifetime studies were initialed with SDAPP, by soaking films in a 0.1 M V5+ and 5.0 M total SO4-2 solution. The rate of degradation was also proportional with IEC; the 2 meq/g sample dissolved within 376 hours, the 1.6 meq/g sample dissolved after 860 hours, while the 1.4 meq/g sample broke apart after 1527 hours.

Fujimoto, Cy H.; Kim, Soowhan; Stains, Ronald; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

2012-07-01T23:59:59.000Z

12

A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-scale Energy Storage  

SciTech Connect

Low cost, high performance redox flow batteries are highly demanded for up to multi-megawatt levels of renewable and grid energy storage. Here, we report a new vanadium redox flow battery with a significant improvement over the current technologies. This new battery utilizes a sulfate-chloride mixed solution, which is capable of dissolving more than 2.5 M vanadium or about a 70% increase in the energy storage capacity over the current vanadium sulfate system. More importantly, the new electrolyte remains stable over a wide temperature range of -5 to 60oC, potentially eliminating the need of active heat management. Its high energy density, broad operational temperature window, and excellent electrochemical performance would lead to a significant reduction in the cost of energy storage, thus accelerating its market penetration.

Li, Liyu; Kim, Soowhan; Wang, Wei; Vijayakumar, M.; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang; Hu, Jian Z.; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo

2011-05-01T23:59:59.000Z

13

Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane  

SciTech Connect

Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

2013-09-02T23:59:59.000Z

14

High Performance Vanadium Redox Flow Batteries with Optimized Electrode Configuration and Membrane Selection  

Science Conference Proceedings (OSTI)

The performance of a vanadium flow battery with no-gap architecture was significantly improved via several techniques. Specifically, gains arising from variation of the overall electrode thickness, membrane thickness, and electrode thermal treatment were studied. There is a trade-off between apparent kinetic losses, mass transfer losses, and ionic resistance as the electrode thickness is varied at the anode and cathode. Oxidative thermal pretreatment of the carbon paper electrode increased the peak power density by 16%. Results of the pretreatment in air showed greater improvement in peak power density compared to that obtained with pretreatment in an argon environment. The highest peak power density in a VRB yet published to the author s knowledge was achieved at a value of 767 mW cm 2 with optimized membrane and electrode engineering. 2012 The Electrochemical Society. [DOI: 10.1149/2.051208jes] All rights reserved.

Liu, Q. H. [University of Tennessee, Knoxville (UTK); Grim, G. M. [University of Tennessee, Knoxville (UTK); Papandrew, A [University of Tennessee, Knoxville (UTK); Turhan, A. [University of Tennessee, Knoxville (UTK); Zawodzinski, Thomas A [ORNL; Mench, Matthew M [ORNL

2012-01-01T23:59:59.000Z

15

ESS 2012 Peer Review - Painesville Municipal Electric Power Vanadium Redox Battery Demo Project - Jodi Startari, Ashlawn Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electric Power Electric Power Vanadium Redox Battery Demonstration Project Jodi Startari Ashlawn Energy LLC Briefing Overview * Painesville Municipal Electric Power Plant Project Synopsis * Vanadium Redox Flow Battery Technology * City of Painesville Municipal Electric Plant History * Project Multiple Objectives and Additional Detail * Project Risk Analysis presented at previous Peer Review * Project to date progress * Cost Distribution * Summary/Conclusions * Future Tasks * Questions US Produced Vanadium Redox Flow Battery for Bulk Storage, Peak Shaving * 8 MW Hour redox flow battery (1MW 8 hours) * To be installed at Painesville Municipal Electric Plant (PMEP), a 32 MW coal fired facility * Most efficient PMEP operation is steady state at 26 MW (lowest emissions, lowest operating cost)

16

Redox flow batteries: a review  

Science Conference Proceedings (OSTI)

Redox flow batteries (RFBs) are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of RFBs with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

Weber, Adam Z. [Lawrence Berkeley National Laboratory (LBNL); Mench, Matthew M [ORNL; Meyers, Jeremy [University of Texas, Austin; Ross, Philip N. [Lawrence Berkeley National Laboratory (LBNL); Gostick, Jeffrey T. [McGill University, Montreal, Quebec; Liu, Qinghua [University of Tennessee, Knoxville (UTK)

2011-01-01T23:59:59.000Z

17

Advanced Redox Flow Batteries for Stationary Electrical Energy Storage  

SciTech Connect

This report describes the status of the advanced redox flow battery research being performed at Pacific Northwest National Laboratories for the U.S. Department of Energy’s Energy Storage Systems Program. The Quarter 1 of FY2012 Milestone was completed on time. The milestone entails completion of evaluation and optimization of single cell components for the two advanced redox flow battery electrolyte chemistries recently developed at the lab, the all vanadium (V) mixed acid and V-Fe mixed acid solutions. All the single cell components to be used in future kW-scale stacks have been identified and optimized in this quarter, which include solution electrolyte, membrane or separator; carbon felt electrode and bi-polar plate. Varied electrochemical, chemical and physical evaluations were carried out to assist the component screening and optimization. The mechanisms of the battery capacity fading behavior for the all vanadium redox flow and the Fe/V battery were discovered, which allowed us to optimize the related cell operation parameters and continuously operate the system for more than three months without any capacity decay.

Li, Liyu; Kim, Soowhan; Xia, Guanguang; Wang, Wei; Yang, Zhenguo

2012-03-19T23:59:59.000Z

18

A New Hybrid Redox Flow Battery with Multiple Redox Couples  

Science Conference Proceedings (OSTI)

A redox flow battery using V{sup 4+}/V{sup 5+} vs. V{sup 2+}/V{sup 3+} and Fe{sup 2+}/Fe{sup 3+} vs. V{sup 2+}/V{sup 3+} redox couples in chloric/sulphuric mixed acid supporting electrolyte was investigated for potential stationary energy storage applications. The Fe/V hybrid redox flow cell using mixed reactant solutions operated within a voltage window of 0.5-1.7 V demonstrated stable cycling over 100 cycles with energy efficiency {approx}80% and no capacity fading at room temperature. A 66% improvement in the energy density of the Fe/V hybrid cell was achieved compared with the previous reported Fe/V cell using only Fe{sup 2+}/Fe{sup 3+} vs. V{sup 2+}/V{sup 3+} redox couples.

Wang, Wei; Li, Liyu; Nie, Zimin; Chen, Baowei; Luo, Qingtao; Shao, Yuyan; Wei, Xiaoliang; Chen, Feng; Xia, Guanguang; Yang, Zhenguo

2012-05-19T23:59:59.000Z

19

VRB Energy Storage for Voltage Stabilization: Testing and Evaluation of the PacifiCorp Vanadium Redox Battery Energy Storage System at Castle Valley, Utah  

Science Conference Proceedings (OSTI)

Energy storage is a strategic option for utilities to support and optimize operations in generation, transmission and distribution. This report describes a demonstration energy storage facility based on vanadium redox flow battery (VRB) technology. This technology has been installed by PacifiCorp, a distribution utility in the Pacific Northwest, to defer investment in additional distribution assets in an environmentally pristine area in Castle Valley in Southeastern Utah. The technology has substantial p...

2005-03-23T23:59:59.000Z

20

Redox Flow Batteries for Grid-scale Energy Storage - Energy ...  

Though considered a promising large-scale energy storage device, the real-world deployment of redox flow batteries has been limited by their inability ...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

ESS 2012 Peer Review - Single Substance Organic Redox Flow Battery...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2Z Z - + Z + E 0 -2.8V A Single Substance Organic Redox Flow Battery -+- -+- Components Compound Z Tetraethylammonium Tetrafluoroborate (TEA-BF 4 )...

22

ESS 2012 Peer Review - New Generation Aqueous Base Redox Flow...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

New Generation Aqueous Base Redox Flow Battery Component Development Wei Wang, Qingtao Luo, Xiaoliang Wei, Bin Li, Zimin Nie, Baowei Chen, Yuyan Shao, Vijayakumar Murugesan, Amy...

23

ESS 2012 Peer Review - New Generation Redox Flow Battery Prototype...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Next Generation Redox Flow Battery Prototype Development Vincent Sprenkle, Soowhan Kim, Ed Thomsen, Alasdair Crawford, Zimin Nie, Vilayanur Viswanathan, David Stephenson, Qingtao...

24

ESS 2012 Peer Review - Acid Based Blend Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Acid Based Blend Membranes for Redox Flow Batteries Acid Based Blend Membranes for Redox Flow Batteries DOE Grant No: DE-SC0006306 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Prof. Arumugam Manthiram University of Texas, Austin, TX 78712 Prof. Fuqiang Liu University of Texas Arlington, Arlington, TX 76019 Conclusions Lynntech, in conjunction with the University of Texas and the University of Texas at Arlington, developed a new series of low-cost polymer blend membranes with high proton conductivity and ultralow vanadium ion permeability. The proton conductivity and physical properties of these membranes are tunable by adjusting the ratio of acid and base components. Membrane conductivity was found to be more critical to

25

Iron-sulfide redox flow batteries  

Science Conference Proceedings (OSTI)

Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

2013-12-17T23:59:59.000Z

26

ESS 2012 Peer Review - Component Research for Redox Flow Batteries...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Battelle for the Department of Energy Component Research for Redox Flow Batteries Tom Zawodzinski and Che-Nan (Josh) Sun With help from Jamie Lawton, Zhijiang Tang, Doug Aaron,...

27

Electrochemical Model of the Fe/V Redox Flow Battery  

Science Conference Proceedings (OSTI)

This paper presents a mathematical model for the new Fe/V redox flow battery chemistry. The model is designed to be useful for stack development and cost analysis purposes.

Stephenson, David E.; Kim, Soowhan; Chen, Feng; Thomsen, Edwin C.; Viswanathan, Vilayanur V.; Wang, Wei; Sprenkle, Vincent L.

2012-11-05T23:59:59.000Z

28

ESS 2012 Peer Review - Low-Cost, High-Performance Hybrid Membranes for Redox Flow Batteries - Hongxing Hu, Amsen Technologies  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DESIGN © 2008 DESIGN © 2008 www.PosterPresentations.com Low-Cost, High-Performance Hybrid Membranes for Redox Flow Batteries Hongxing Hu, Amsen Technologies LLC DOE SBIR Project, Program Manager at DOE: Dr. Imre Gyuk Objectives and Technical Approach Objectives: This SBIR project aims to develop low-cost, high performance hybrid polymeric PEMs for redox flow batteries (RFBs). Such membranes shall have high chemical stability in RFB electrolytes, high proton conductivity, low permeability of vanadium ions, along with high dimensional stability, high mechanical strength and durability, and lower cost than Nafion membranes. Approach: * Hybrid membranes of sulfonated polymers * Balance between different types of polymers for proton conductivity and chemical stability

29

Recent Progress in Redox Flow Battery Research and Development  

SciTech Connect

With the increase need to seamlessly integrate the renewable energy with the current grid which itself is evolving into a more intelligent, efficient, and capable electrical power system, it is envisioned that the energy storage system will play a more prominent role in bridging the gap between the current technology and a clean sustainable future in grid reliability and utilization. Redox flow battery technology is leading the way in this perspective in providing a well balanced approach for current challenges. Recent progress in the research and development of redox flow battery technology is reviewed here with a focus on new chemistries and systems.

Wang, Wei; Luo, Qingtao; Li, Bin; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

2013-02-20T23:59:59.000Z

30

Microporous Separators for Fe/V Redox Flow Batteries  

Science Conference Proceedings (OSTI)

The Fe/V redox flow battery has demonstrated promising performance that is advantageous over other redox flow battery systems. The less oxidative nature of the Fe(III) species enables use of hydrocarbon - based ion exchange membranes or separators. Daramic(reg. sign) microporous polyethylene separators were tested on Fe/V flow cells using the sulphuric/chloric mixed acid - supporting electrolytes. Among them, Daramic(reg. sign) C exhibited good flow cell cycling performance with satisfactory repeatability over a broad temperature range of 5 - 50 degrees C. Energy efficiency (EE) of C remains above 67% at current densities of 50 - 80 cm{sup -2} in the temperature range from room temperature to 50 degrees C. The capacity decay problem could be circumvented through hydraulic pressure balancing by applying different pump rates to the positive and negative electrolytes. Stable capacity and energy were obtained over 40 cycles at room temperature and 40 degrees C. These results manifest that the extremely low-cost separators ($10/cm2) are applicable in the Fe/V flow battery system at an acceptable sacrifice of energy efficiency. This stands for a remarkable breakthrough in significant reduction of the capital cost of the Fe/V flow battery system, and is promising to promote its market penetration in grid stabilization and renewable integration.

Wei, Xiaoliang; Li, Liyu; Luo, Qingtao; Nie, Zimin; Wang, Wei; Li, Bin; Xia, Guanguang; Miller, Eric; Chambers, Jeff; Yang, Zhenguo

2012-06-28T23:59:59.000Z

31

Transitioning from Fuel Cells to Redox Flow Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Transitioning From Fuel Cells to Redox Transitioning From Fuel Cells to Redox Flow Cells T. Zawodzinski and Matt Mench University of Tennessee and ORNL Managed by UT-Battelle for the Department of Energy 2 Acknowledgments $$ DOE-OE EPRI GCEP NSF EPSCOR (TN SCORE) UTK Governor's Chair Fund Partner in Crime Matt Mench Managed by UT-Battelle for the Department of Energy 'Peeling the Onion' Personalized History of PEM Fuel Cells We May Recapitulate This for RFBs Catalysis Test System * Small Single Cell * Large Single Cell * Stack * System Layers of the Onion Hot Topic du Jour * Water Management, Membranes * Late '80's, early '90's * Reformate Tolerance, DMFC's * Mid '90's * High Temp Membranes * Late '90's * Durability * Early '00's Modeling * Membrane/ Water * Cathode * Impedance

32

Fe/V Redox Flow Battery Electrolyte Investigation and Optimization  

Science Conference Proceedings (OSTI)

Recently invented Fe/V redox flow battery (IVBs) system has attracted more and more attentions due to its long-term cycling stability. In this paper, the factors (such as compositions, state of charge (SOC) and temperatures) influencing the stability of electrolytes in both positive and negative half-cells were investigated by an extensive matrix study. Thus an optimized electrolyte, which can be operated in the temperature ranges from -5oC to 50oC without any precipitations, was identified. The Fe/V flow cells using the optimized electrolytes and low-cost membranes exhibited satisfactory cycling performances at different temperatures. The efficiencies, capacities and energy densities of flow batteries with varying temperatures were discussed in detail.

Li, Bin; Li, Liyu; Wang, Wei; Nie, Zimin; Chen, Baowei; Wei, Xiaoliang; Luo, Qingtao; Yang, Zhenguo; Sprenkle, Vincent L.

2013-05-01T23:59:59.000Z

33

Analysis of performance capabilities of redox-flow storage batteries  

SciTech Connect

Major physical performance parameters and economic factors of a generalized redox-flow storage battery system are analyzed. The system is divided into power-related and energy-related subsystems. The economic factors include plant capital (and other) costs, electrical energy lost by the storage-cycle inefficiency, and a penalty term for failures. Relationships are formulated for the overall system efficiency and system performance parameters (voltages, current density, state-of-charge of the storage liquid, and parasitic losses). Equations for sizing and costing of the battery and the storage tank subsystems are given. Directions for needed research are indicated.

Roy, A.S.; Kaplan, S.I.

1978-01-01T23:59:59.000Z

34

Anthraquinone with Tailored Structure for Nonaqueous Metal-Organic Redox Flow Battery  

Science Conference Proceedings (OSTI)

A nonaqueous, hybrid metal-organic redox flow battery based on tailored anthraquinone structure is demonstrated to have an energy efficiency of {approx}82% and a specific discharge energy density similar to aqueous redox flow batteries, which is due to the significantly improved solubility of anthraquinone in supporting electrolytes.

Wang, Wei; Xu, Wu; Cosimbescu, Lelia; Choi, Daiwon; Li, Liyu; Yang, Zhenguo

2012-06-08T23:59:59.000Z

35

Redox Flow Batteries for Grid-scale Energy Storage - Energy ...  

Wind Energy; Partners (27) Visual Patent Search; Success Stories; News; Events; Startup America Industrial Technologies Energy Storage Redox ...

36

ESS 2012 Peer Review - Acid Based Blend Membranes for Redox Flow...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Acid Based Blend Membranes for Redox Flow Batteries DOE Grant No: DE-SC0006306 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX...

37

R&D Activities of Redox Flow Battery for Energy Storage at DICP  

Science Conference Proceedings (OSTI)

Presentation Title, R&D Activities of Redox Flow Battery for Energy Storage at DICP ... Optimization of Na0.44MnO2 Cathode Material for Use in Aqueous ...

38

High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Title High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Publication Type Journal Article Year of Publication 2012 Authors Cho, Kyu Taek, Paul L. Ridgway, Adam Z. Weber, Sophia Haussener, Vincent S. Battaglia, and Venkat Srinivasan Journal Journal of the Electrochemical Society Volume 159 Issue 11 Pagination A1806 - A1815 Date Published 01/2012 ISSN 0013-4651 Keywords hydrogen/bromine, redox flow battery Abstract The electrochemical behavior of a promising hydrogen/bromine redox flow battery is investigated for grid-scale energy-storage application with some of the best redox-flow-battery performance results to date, including a peak power of 1.4 W/cm(2) and a 91% voltaic efficiency at 0.4 W/cm(2) constant-power operation. The kinetics of bromine on various materials is discussed, with both rotating-disk-electrode and cell studies demonstrating that a carbon porous electrode for the bromine reaction can conduct platinum-comparable performance as long as sufficient surface area is realized. The effect of flow-cell designs and operating temperature is examined, and ohmic and mass-transfer losses are decreased by utilizing a flow-through electrode design and increasing cell temperature. Charge/discharge and discharge-rate tests also reveal that this system has highly reversible behavior and good rate capability.

39

ESS 2012 Peer Review - Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies - Thomas Kodenkandath, ITN Energy Systems  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Innovative, high energy density Mn-V based RFB electrolytes as a Innovative, high energy density Mn-V based RFB electrolytes as a low-cost alternate to all-Vanadium systems * Low-cost membrane technology, based on renewable biopolymer Chitosan with improved proton conduction & chemical stability, adaptable to Mn-V system * Scale-up of electrolyte and membrane technologies in pursuit of ARPA-E's goal for a 2.5kW/10kWh RFB stack with integrated BoS at a total cost of ~$1000/unit and ~1.2 m 3 footprint ITN Energy Systems, Inc., Littleton, CO 2.5kW/10kWh Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies $2.1 M, 33-month program awarded by ARPA-E Sept 7, 2012 Dr. Thomas Kodenkandath High-Performance, Low-cost RFB through Electrolyte & Membrane Innovations Technology Summary

40

Performance and cycling of the iron-ion/hydrogen redox flow cell with  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and cycling of the iron-ion/hydrogen redox flow cell with Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Title Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Publication Type Journal Article Year of Publication 2013 Authors Tucker, Michael C., Venkat Srinivasan, Philip N. Ross, and Adam Z. Weber Journal Journal of Applied Electrochemistry Volume 43 Issue 7 Pagination 637 - 644 Date Published 7/2013 ISSN 0021-891X Keywords battery, Flow battery, iron hydrogen cell, progress, redox flow cell Abstract A redox flow cell utilizing the Fe2+/Fe3+ and H-2/H+ couples is investigated as an energy storage device. A conventional polymer electrolyte fuel cell anode and membrane design is employed, with a cathode chamber containing a carbon felt flooded with aqueous acidic solution of iron salt. The maximum power densities achieved for iron sulfate, iron chloride, and iron nitrate are 148, 207, and 234 mW cm(-2), respectively. It is found that the capacity of the iron nitrate solution decreases rapidly during cycling. Stable cycling is observed for more than 100 h with iron chloride and iron sulfate solutions. Both iron sulfate and iron chloride solutions display moderate discharge polarization and poor charge polarization; therefore, voltage efficiency decreases dramatically with increasing current density. A small self-discharge current occurs when catholyte is circulating through the cathode chamber. As a result, a current density above 100 mA cm(-2) is required to achieve high Coulombic efficiency (> 0.9).

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

ESS 2012 Peer Review - Redox Flow Battery (RFB) with Low-cost...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and 1.2 m 3 footprint ITN Energy Systems, Inc., Littleton, CO 2.5kW10kWh Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies 2.1 M, 33-month program...

42

Vanadium redox-flow batteries Installation at Ris for characterisation measurements  

E-Print Network (OSTI)

and investigating distributed power systems. SYSLAB consists of two wind turbines, a pv-array, a diesel genset Bindner, Wind Energy Department, Risø National Laboratory, DTU, henrik.bindner@risoe.dk Peter Ahm, PA it provides different services to grid including smoothing of wind turbine output, load balancing and similar

43

Vanadium-redox flow and lithium-ion battery modelling and performance in wind energy applications.  

E-Print Network (OSTI)

??As wind energy penetration levels increase, there is a growing interest in using storage devices to aid in managing the fluctuations in wind turbine output… (more)

Chahwan, John A.

2007-01-01T23:59:59.000Z

44

A New Fe/V Redox Flow Battery Using Sulfuric/Chloric Mixed Acid Supporting Electrolyte  

SciTech Connect

A redox flow battery using Fe2+/Fe3+ and V2+/V3+ redox couples in chloric/sulphuric mixed acid supporting electrolyte was investigated for potential stationary energy storage applications. The Fe/V redox flow cell using mixed reactant solutions operated within a voltage window of 0.5-1.35 V with a nearly 100% utilization ratio and demonstrated stable cycling over 100 cycles with energy efficiency > 80% and no capacity fading at room temperature. A 25% improvement in the discharge energy density of the Fe/V cell was achieved compared with the previous reported Fe/V cell using pure chloride acid supporting electrolyte. Stable performance was also achieved in the temperature range between 0 C and 50 C as well as using microporous separator as the membrane. The improved electrochemical performance at room temperature makes the Fe/V redox flow battery a promising option as a stationary energy storage device to enable renewable integration and stabilization of the electrical grid.

Wang, Wei; Nie, Zimin; Chen, Baowei; Chen, Feng; Luo, Qingtao; Wei, Xiaoliang; Xia, Guanguang; Skyllas-Kazacos, Maria; Li, Liyu; Yang, Zhenguo

2012-04-01T23:59:59.000Z

45

ESS 2012 Peer Review - Painesville Municipal Electric Power Vanadium...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Painesville Municipal Electric Power Vanadium Redox Battery Demonstration Project Jodi Startari Ashlawn Energy LLC Briefing Overview * Painesville Municipal Electric Power Plant...

46

ESS 2012 Peer Review - New Generation Aqueous Base Redox Flow Battery Component Development - Wei Wang, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Generation Aqueous Base Redox Flow Generation Aqueous Base Redox Flow Battery Component Development Wei Wang, Qingtao Luo, Xiaoliang Wei, Bin Li, Zimin Nie, Baowei Chen, Yuyan Shao, Vijayakumar Murugesan, Amy Chen, Gordon, Xia, Liyu Li, Gary Z. Yang, Vincent Sprenkle Pacific Northwest National Laboratory 902 Battelle Boulevard P. O. Box 999 Richland, WA 99352, USA DOE Stationary Energy Storage Program Review, Washington, DC Sept. 26-28, 2012 Dr. Imre Gyuk 1 2 Review of previous work 2.5M, ~30Wh/L, -5~50 o C Mixed-acid VRB Double Energy Density Extend temperature window Charge Discharge Charge Discharge Charge Discharge Catholyte: VO 2+ + Cl - + H 2 O - e VO 2 Cl + 2H + ε co =1.0 V Anolyte: V 3+ + e V 2+ ε ao =-0.25 Overall: VO 2+ + Cl

47

ESS 2012 Peer Review - Highly Selective Proton-Conducting Composite Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Membrane for Redox Flow Batteries Membrane for Redox Flow Batteries DOE Grant No: DE-SC0004516 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Introduction * Redox flow batteries (RFBs) are a promising technology to store electrical energy from intermittent renewable sources such as solar and wind power. Although they offer many advantages, RFBs with reduced cost and improved performance (i.e., efficiency and durability) need to be developed to achieve broad market penetration. * Ion exchange membranes in RFBs separate two soluble redox couples should allow rapid proton transport and suppress transport of the reactive species between anode and cathode compartments. Nafion

48

ESS 2012 Peer Review - Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries - Fei Wang, EIC Laboratories  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries Fei Wang, Dharmasena Peramunage, James M. Sylvia, and Monsy M. Jocob EIC Laboratories, Inc. 111 Downey Street, Norwood, MA 02062. www.eiclabs.com Identification of the Problem and Technical Approach Redox flow batteries (RFB) hold great promise for large scale electrochemical energy storage. A critical component of RFB is the membrane which separates anode and cathode compartments. The current state-of-the-art membrane, NAFION is too expensive, lacks selectivity, permitting leakage between anode and cathode electrolyte compartments. EIC is developing a novel bilayer, interpenetrating network membrane. Thin Nafion layer for anode side protection providing oxidative stability. The bulk part of the membrane consists of a block

49

ESS 2012 Peer Review - Single Substance Organic Redox Flow Battery - Paul Rasmussen, Vinazene  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Charging Mechanism Charging Mechanism The Z compound, as described in Vinazene Patent 8,080,327, undergoes the following half reactions during charging: Z Z + + e - E 0 = -1.3V Z + e -  Z - E 0 = -1.5V _____________________ 2Z  Z - + Z + E 0 = -2.8V A Single Substance Organic Redox Flow Battery -+- -+- Components Compound Z Tetraethylammonium Tetrafluoroborate (TEA-BF 4 ) Maintains Electroneutrality Acetonitrile (MeCN) Dielectric and Transport medium Abstract Abundant energy, in the exajoule range, is available everyday from solar and wind flux. However, green sources of this energy are subject to intermittent and/or periodic fluctuations. Mitigation of supply obstacles is possible through the use of cost effective and dispatchable energy storage methods. During Phase I of this SBIR

50

Some Lessons Learned from 20 Years in RedOx Flow Battery R&d  

NLE Websites -- All DOE Office Websites (Extended Search)

lessons learned from 20 years in lessons learned from 20 years in RedOx Flow Battery R&D Dr Steve Clarke, CEO Applied Intellectual Capital, Alameda CAc DOE Workshop Washington DC March 2012 www.apicap.com Contents ● AIC's involvement in RFB R&D ● Some key lessons learned ● Some remaining challenges to be overcome 2 Applied Intellectual Capital ● Technology consulting  Electrochemical and materials focus  Clients include leading industrials, VCs, DOE, DOD and EPA  33,000 ft. facility for laboratory, engineering, rapid prototyping and testing ● Technology venturing (own micro- fund)  IP generated by consulting and R&D  Leverages labs, facilities and consulting successes ● Combined resources  Proven business development team  Start-up to IPO

51

ESS 2012 Peer Review - Component Research for Redox Flow Batteries - Tom Zawodzinski, ORNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Battelle Battelle for the Department of Energy Component Research for Redox Flow Batteries Tom Zawodzinski and Che-Nan (Josh) Sun With help from Jamie Lawton, Zhijiang Tang, Doug Aaron, Alex Papandrew, Qinhua Liu, Matt Mench (UTK) Frank Delnick (SNL) Thanks to Imre Gyuk (OE) and team at UTK Managed by UT-Battelle for the Department of Energy Approach This project is a little different from many others in the portfolio We are not looking into alternative battery chemistries per se We are doing work to guide you in choices of materials and hardware designs to make all RFBs better! Focus on components, diagnostics to drive understanding how to improve Managed by UT-Battelle for the Department of Energy Goals and Tasks 1. Demonstrate improved performance of RFBs in pre-

52

ESS 2012 Peer Review - Estimation of Capital and Levelized Cost for Redox Flow Batteries - Vilayanur Viswanathan, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Estimation of Capital and Levelized Estimation of Capital and Levelized Cost for Redox Flow Batteries V. Viswanathan, A. Crawford, L. Thaller 1 , D. Stephenson, S. Kim, W. Wang, G. Coffey, P. Balducci, Z. Gary Yang 2 , Liyu Li 2 , M. Kintner-Meyer, V. Sprenkle 1 Consultant 2 UniEnergy Technology September 28, 2012 USDOE-OE ESS Peer Review Washington, DC Dr. Imre Gyuk - Energy Storage Program Manager, Office of Electricity Delivery and Energy Reliability 1 What are we trying to accomplish? PNNL grid analytics team has established ESS cost targets for various applications PNNL cost/performance model estimates cost for redox flow battery systems of various chemistries drives research internally to focus on most important components/parameters/metrics for cost reduction and performance improvement

53

VANADIUM ALLOYS  

DOE Patents (OSTI)

This patent deals with vanadium based ternary alloys useful as fuel element jackets. According to the invention the ternary vanadium alloys, prepared in an arc furnace, contain from 2.5 to 15% by weight titanium and from 0.5 to 10% by weight niobium. Characteristics of these alloys are good thermal conductivity, low neutron capture cross section, good corrosion resistance, good welding and fabricating properties, low expansion coefficient, and high strength.

Smith, K.F.; Van Thyne, R.J.

1959-05-12T23:59:59.000Z

54

ESS 2012 Peer Review - Flow Battery Membrane - David Ofer, Tiax  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Flow Battery Membrane Flow Battery Membrane Energy Storage Systems Program (ESS) Peer Review and Update Meeting 2012 Jack Treger treger.jack@tiaxllc.com Washington DC, September 27, 2012 Flow Battery Membrane Background and Purpose 1 Vanadium redox batteries (VRB) for energy storage require improved ion- selective membranes. * Vanadium permeation across current membranes leads to self-discharge and decreases cycling efficiency: - Negative half cell: V 2+ V 3+ + e - E o = -0.255V - Positive half cell: e - + VO 2 + + 2H + VO 2+ + H 2 O E o = 1.00V . * Current perfluorosulfonic acid polymer membranes are costly. * TIAX is developing a novel composite bipolar membrane: - Composite anionic membrane minimizes content of costly perfluorosulfonic acid polymer - Made bipolar by a cationic surface layer to improve selectivity for

55

SUPERCONDUCTING VANADIUM BASE ALLOY  

DOE Patents (OSTI)

A new vanadium-base alloy which possesses remarkable superconducting properties is presented. The alloy consists of approximately one atomic percent of palladium, the balance being vanadium. The alloy is stated to be useful in a cryotron in digital computer circuits.

Cleary, H.J.

1958-10-21T23:59:59.000Z

56

The effect of flow rate on the in-situ gelation of a chrome/redox/polyacrylamide system  

SciTech Connect

This paper presents experimental data on the gelation of a polyacrylamide/thiourea/Cr(VI) gel system in unconsolidated sandpacks at flow rates typical of those encountered beyond the immediate vicinity of a wellbore. At these low rates, in-situ gelation during flow was characterized by an abrupt increase in flow resistance that occurred over a short distance at a specific location along the sandpack. The location of this region was a function of flow rate, and its distance from the inlet increased as flow rate increased. Filtration of gel aggregates appears to be the mechanism causing this behavior.

Marty, L.; Green, D.W.; Willhite, G.P. (University of Kansas (US))

1991-05-01T23:59:59.000Z

57

Slag recycling of irradiated vanadium  

Science Conference Proceedings (OSTI)

An experimental inductoslag apparatus to recycle irradiated vanadium was fabricated and tested. An experimental electroslag apparatus was also used to test possible slags. The testing was carried out with slag materials that were fabricated along with impurity bearing vanadium samples. Results obtained include computer simulated thermochemical calculations and experimentally determined removal efficiencies of the transmutation impurities. Analyses of the samples before and after testing were carried out to determine if the slag did indeed remove the transmutation impurities from the irradiated vanadium.

Gorman, P.K.

1995-04-05T23:59:59.000Z

58

V(V) Electrolytes in a Vanadium Redox Battery  

Science Conference Proceedings (OSTI)

Pd-Based Membrane Reactor for Simultaneous CO2 Sequestration and Hydrogen Production from Syngas Produced from IGCC · Search and Study of a Solid ...

59

Cost Reduction and Materials Optimisation for the Vanadium Redox ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cost Reduction and Materials Optimisation for the ... already been successfully implemented in renewable energy storage applications Japan,

60

Redox Flow Batteries, a Review  

E-Print Network (OSTI)

extend equipment life Cost: $500 per kWh Discharge Duration:and the cost per unit of energy-storage capacity ($/kWh). We

Weber, Adam Z.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Redox Flow Batteries, a Review  

E-Print Network (OSTI)

follows. Typical RFB carbon-fiber-paper or carbon-feltthat briefly heating carbon fiber materials at 300 °C in anlooked at mass transfer in carbon-fiber electrodes [67, 122,

Weber, Adam Z.

2013-01-01T23:59:59.000Z

62

Redox Flow Batteries, a Review  

E-Print Network (OSTI)

to Spur Transition to Smart Grid. Available: http://of storage into the smart grid also promises to enablewidespread adoption of smart grid technologies could yield a

Weber, Adam Z.

2013-01-01T23:59:59.000Z

63

It's Elemental - The Element Vanadium  

NLE Websites -- All DOE Office Websites (Extended Search)

also does not easily absorb neutrons and has some applications in the nuclear power industry. A thin layer of vanadium is used to bond titanium to steel. Nearly 80% of the...

64

Final Report - Crystal Settling, Redox, and High Temperature Properties of ORP HLW and LAW Glasses, VSL-09R1510-1, Rev. 0, dated 6/18/09  

Science Conference Proceedings (OSTI)

The radioactive tank waste treatment programs at the U. S. Department of Energy (DOE) have featured joule heated ceramic melter technology for the vitrification of high level waste (HLW). The Hanford Tank Waste Treatment and Immobilization Plant (WTP) employs this same basic technology not only for the vitrification of HLW streams but also for the vitrification of Low Activity Waste (LAW) streams. Because of the much greater throughput rates required of the WTP as compared to the vitrification facilities at the West Valley Demonstration Project (WVDP) or the Defense Waste Processing Facility (DWPF), the WTP employs advanced joule heated melters with forced mixing of the glass pool (bubblers) to improve heat and mass transport and increase melting rates. However, for both HLW and LAW treatment, the ability to increase waste loadings offers the potential to significantly reduce the amount of glass that must be produced and disposed and, therefore, the overall project costs. This report presents the results from a study to investigate several glass property issues related to WTP HLW and LAW vitrification: crystal formation and settling in selected HLW glasses; redox behavior of vanadium and chromium in selected LAW glasses; and key high temperature thermal properties of representative HLW and LAW glasses. The work was conducted according to Test Plans that were prepared for the HLW and LAW scope, respectively. One part of this work thus addresses some of the possible detrimental effects due to considerably higher crystal content in waste glass melts and, in particular, the impact of high crystal contents on the flow property of the glass melt and the settling rate of representative crystalline phases in an environment similar to that of an idling glass melter. Characterization of vanadium redox shifts in representative WTP LAW glasses is the second focal point of this work. The third part of this work focused on key high temperature thermal properties of representative WTP HLW and LAW glasses over a wide range of temperatures, from the melter operating temperature to the glass transition.

Kruger, Albert A.; Wang, C.; Gan, H.; Pegg, I. L.; Chaudhuri, M.; Kot, W.; Feng, Z.; Viragh, C.; McKeown, D. A.; Joseph, I.; Muller, I. S.; Cecil, R.; Zhao, W.

2013-11-13T23:59:59.000Z

65

Scientists Crack Materials Mystery of Vanadium Dioxide  

Science Conference Proceedings (OSTI)

Dec 1, 2010 ... Using a condensed physics theory to explain the observed phase behaviors of vanadium dioxide, ORNL scientists have discovered that the ...

66

Vanadium hydride deuterium-tritium generator  

DOE Patents (OSTI)

A pressure controlled vanadium hydride gas generator to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

Christensen, Leslie D. (Livermore, CA)

1982-01-01T23:59:59.000Z

67

Vanadium catalysts break down biomass for fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

Vanadium catalysts break down biomass for fuels Vanadium catalysts break down biomass for fuels Vanadium catalysts break down biomass into useful components Breaking down biomass could help in converting biomass to fuels. March 26, 2012 Biomass Due to diminishing petroleum reserves, non-food biomass (lignocellulose) is an attractive alternative as a feedstock for the production of renewable chemicals and fuels. Get Expertise Researcher Susan Hanson Inorganic Isotope & Actinide Chem Email Researcher Ruilian Wu Bioenergy & Environmental Science Email Researcher Louis "Pete" Silks Bioenergy & Environmental Science Email Vanadium is an inexpensive, earth-abundant metal that is well suited for promoting oxidations in air. Vanadium catalysts break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose) is

68

Methods for making lithium vanadium oxide electrode materials  

DOE Patents (OSTI)

A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

Schutts, Scott M. (Menomonie, WI); Kinney, Robert J. (Woodbury, MN)

2000-01-01T23:59:59.000Z

69

Method for preparing high purity vanadium  

DOE Patents (OSTI)

A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

Schmidt, F.; Carlson, O.N.

1984-05-16T23:59:59.000Z

70

Method for preparing high purity vanadium  

DOE Patents (OSTI)

A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

Schmidt, Frederick (Ames, IA); Carlson, O. Norman (Ames, IA)

1986-09-09T23:59:59.000Z

71

Vanadium hydride deuterium-tritium generator  

DOE Patents (OSTI)

A pressure controlled vanadium hydride gas generator was designed to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

Christensen, L.D.

1980-03-13T23:59:59.000Z

72

X-Ray Absorption Studies of Vanadium-Containing Metal Oxide Nanocrystals  

Science Conference Proceedings (OSTI)

Metal oxide nanocrystals offer significant potential for use as catalysts or catalyst supports due to their high surface areas and unique chemical properties that result from the high number of exposed corners and edges. However, little is known about the catalytic activity of these materials, especially as oxidation catalysts. This research focused on the preparation, characterization and use of vanadium-containing nanocrystals as selective oxidation catalysts. Three vanadium-containing nanocrystals were prepared using a modified sol-gel procedure: V/MgO, V/SiO2, and vanadium phosphate (VPO). These represent active oxidation catalysts for a number of industrially relevant reactions. The catalysts were characterized by x-ray diffraction and Raman, UV-VIS, infrared and x-ray absorption spectroscopies with the goal of determining the primary structural and chemical differences between nanocrystals and microcrystals. The catalytic activity of these catalysts was also studied in oxidative dehydrogenation of butane and methanol oxidation to formaldehyde. V/MgO nanocrystals were investigated for activity in oxidative dehydrogenation of butane and compared to conventional V/MgO catalysts. Characterization of V/MgO catalysts using Raman spectroscopy and x-ray absorption spectroscopy showed that both types of catalysts contained magnesium orthovanadate at vanadium loadings below 15 weight%, but above that loading, magnesium pyrovanadate may have been present. In general, MgO nanocrystals had roughly half the crystal size and double the surface area of the conventional MgO. In oxidative dehydrogenation of butane, nanocrystalline V/MgO gave higher selectivity to butene than conventional V/MgO at the same conversion. This difference was attributed to differences in vanadium domain size resulting from the higher surface areas of the nanocrystalline support, since characterization suggested that similar vanadium phases were present on both types of catalysts. Experiments in methanol oxidation were used to probe the chemical differences between sol-gel prepared and conventionally prepared metal oxides. Both V/MgO and V/SiO2 were studied. For both catalysts, similar product selectivities were noted for either preparation method, suggesting similar acid/base and redox properties for the catalysts. At lower weight loadings (butane oxidation to maleic anhydride. In this method vanadium (V) triisopropoxide was reacted with orthophosphoric acid in THF to form a gel. Drying this gel under air resulted in an intercalated VOPO4 compound, where solvent molecules were trapped between layers of the vanadium phosphate compound. Higher surface areas could be achieved by drying this gel at high pressure in an autoclave. The amount of solvent (THF) placed in the autoclave was important in this process. Low amounts of solvent led to a lower surface area, as the solvent evaporated before reaching the critical point and collapsed the gel's pores. In addition, vanadium reduction occurred in the autoclave due to reaction of isopropanol with the vanadium phosphate. Higher amounts of THF reduced the concentration of isopropanol, leading to less reduction. Surfaces areas in excess of 100 m2/g were achieved with this method, and the product was confirmed through XPS and IR to be VOHPO4*0.5H2O, the common precursor for industrial VPO catalysts. Furthermore, this product displayed a platelet morphology, which is desirable for butane oxidation. Further work showed that this material could be transformed to (VO)2P2O7 (the industrial catalyst for butane oxidation to maleic anhydride) by heating under nitrogen without losing much surface are

Hohn, Keith, L.

2006-01-09T23:59:59.000Z

73

An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions  

Open Energy Info (EERE)

Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Details Activities (0) Areas (0) Regions (0) Abstract: Reactive chemical transport occurs in a variety of geochemical environments, and over a broad range of space and time scales. Efficiency of the chemical speciation and water-rock-gas interaction calculations is important for modeling field-scale multidimensional reactive transport problems. An improved efficient model, REACT, for simulating water-rock-gas interaction under equilibrium and kinetic conditions, has been developed.

74

Redox Flow Batteries - Energy Innovation Portal  

Technology Marketing Summary The need for large, grid-scale electrochemical storage is being realized as a critical part of integrating large ...

75

Slag remelt purification of irradiated vanadium alloys  

Science Conference Proceedings (OSTI)

This paper describes theoretical and scoping experimental efforts to investigate the decontamination potential of a slag remelting process for decontaminating irradiated vanadium alloys. Theoretical calculations, using a commercial thermochemical computer code HSC Chemistry, determined the potential slag compositions and slag-vanadium alloy ratios. The experiment determined the removal characteristics of four surrogate transmutation isotopes (Ca, Y - to simulate Sc, Mn, and Ar) from a V-5Ti-5Cr alloy with calcium fluoride slag. An electroslag remelt furnace was used in the experiment to melt and react the constituents. The process achieved about a 90 percent removal of calcium and over 99 percent removal of yttrium. Analyses indicate that about 40 percent of the manganese may have been removed. Argon analyses indicates that 99.3% of the argon was released from the vanadium alloy in the first melt increasing to 99.7% during the second melt. Powder metallurgy techniques were used to incorporate surrogate transmutation products in the vanadium. A powder mixture was prepared with the following composition: 90 wt % vanadium, 4.7 wt % titanium, 4.7 wt % chromium, 0.35 wt % manganese, 0.35 wt % CaO, and 0.35 wt % Y{sub 2}O{sub 3}. This mixture was packed into 2.54 cm diameter stainless steel tubes. Argon was introduced into the powder mixture by evacuating and backfilling the stainless steel containers to a pressure of 20 kPa (0.2 atm). The tubes were hot isostatically pressed at 207 MPa (2000 atm) and 1473 K to consolidate the metal. An electroslag remelt furnace (crucible dimensions: 5.1 cm diameter by 15.2 cm length) was used to process the vanadium electrodes. Chemical analyses were performed on samples extracted from the slags and ingots. Ingot analyses results are shown below. Values are shown in percent removal of the four targeted elements of the initial compositions.

Carmack, W.J.; Smolik, G.R.; McCarthy, K.A.; Gorman, P.K.

1995-07-01T23:59:59.000Z

76

Flow, Li-Air, and Other Batteries  

Science Conference Proceedings (OSTI)

Oct 18, 2011 ... Large-scale energy storage technologies like redox flow batteries have been sought for renewable integration and smart grid applications.

77

Binder-Free LiFePO4 Coated with Nanocarbon Cathodes for ...  

Science Conference Proceedings (OSTI)

Advanced Vanadium Redox Flow Batteries with Mixed Acid Supporting Electrolyte · Aligned TiO2 Nanotubes as Long Durability Anodes for Lithium-Ion Batteries.

78

Performance and Characterization of a Novel Self-Segregating ...  

Science Conference Proceedings (OSTI)

The battery utilizes three liquid layers as the positive electrode, electrolyte, ... Cost Reduction and Materials Optimisation for the Vanadium Redox Flow Battery.

79

Design of LiFePO4/Carbon Hybrid Structure for Improving ...  

Science Conference Proceedings (OSTI)

Advanced Vanadium Redox Flow Batteries with Mixed Acid Supporting Electrolyte ... Behavior of Li-Mg Alloy Anodes for High Capacity Lithium Batteries.

80

Partitioning of hydrogen in the vanadium-lithium-hydrogen system at elevated temperatures  

DOE Green Energy (OSTI)

Equilibrium concentrations of hydrogen in vanadium-base alloys exposed to flowing lithium at temperatures from 350 to 550/degree/C in a forced-circulation loop were measured by residual gas analysis and the vacuum fusion method. Residual gas analysis and removal of material from the surface allowed a determination of the spatial hydrogen distribution in the alloys. These experimental results were compared with calculated thermodynamic distribution coefficients for hydrogen in the vanadium/lithium system. Small amounts of other solutes in the molten lithium and in the alloys affected the solubility, diffusivity, and resultant distribution of hydrogen. Thermodynamic calculations demonstrated the importance of major alloying elements to the partitioning of hydrogen. 12 refs., 5 figs., 2 tabs.

Hull, A.B.; Chopra, O.K.; Loomis, B.A.; Smith, D.L.

1988-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Modified lithium vanadium oxide electrode materials products and methods  

DOE Patents (OSTI)

A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

Thackeray, Michael M. (Naperville, IL); Kahaian, Arthur J. (Chicago, IL); Visser, Donald R. (Naperville, IL); Dees, Dennis W. (Downers Grove, IL); Benedek, Roy (Western Springs, IL)

1999-12-21T23:59:59.000Z

82

Methane oxidation over dual redox catalysts  

SciTech Connect

The objective of this research is to develop approaches to direct catalytic oxidation of methane over oxides that are doubly doped with transition metal ions. The desired process aims at employing a double redox mechanism, where one redox couple is utilized for activation of oxygen and another for the trapping of CH{sub 3} radicals. The methyl radicals can either recombine, giving C{sub 2} hydrocarbons, or be converted, via electron transfer reaction, to carbocations. The latter species can react with surface OH{sup {minus}} groups to form methanol or formaldehyde. To choose from several possible catalytic systems, this research initially involved the characterization of the micromorphology and crystalline dimensions of zinc oxide catalysts doped with Cu, Fe, and Sn by scanning electron microscopy. In addition, the determination of surface composition and oxidation states by X-ray photoelectron spectroscopy was carried out. A newly constructed high temperature catalytic testing system has been calibrated (flow meters and temperature controllers), tested for possible gas leaks and integrated with a gas chromatographic analytical unit. A preliminary catalytic test study over a Cu/Fe/ZnO sample was performed. The following products of the methane coupling reaction was found: C{sub 2}H{sub 6}, C{sub 2}H{sub 4} and H{sub 2}O together with CO{sub 2}. The maximum space time yield of 14 mmol C{sub 2} hydrocarbons/g cat/h was obtained at 848{degrees}C.

Klier, K.; Herman, R.G.; Sojka, Z.

1989-09-01T23:59:59.000Z

83

Extraction of Titanium and Vanadium by Chloride Leach Processes  

Science Conference Proceedings (OSTI)

... extraction of vanadium from different sources such as ilmenite and oil shales. ... of Ammonium Heptamolybdate Tetrahydrate in Air and Inert Gas Atmospheres.

84

Determination of Vanadium/Nickel Proportionality in the Asphaltene...  

NLE Websites -- All DOE Office Websites (Extended Search)

Determination of VanadiumNickel Proportionality in the Asphaltene Fraction of Crude Oil Using Thin-Layer Chromatography with Femtosecond Laser Ablation-Inductively Coupled...

85

Leaching of Uranium and Vanadium from Korean Domestic Ore  

Science Conference Proceedings (OSTI)

ISASMELT™ for Recycling of Valuable Elements Contributing to a More Sustainable Society · Leaching of Uranium and Vanadium from Korean Domestic Ore.

86

Ultrasonic-assisted alkaline leaching of vanadium from stone coal  

Science Conference Proceedings (OSTI)

... used to extract vanadium from the stone coal, with alkali as leaching reagent. ... of low grade copper sulfide ore(Chalcopyrite) of Sarcheshmeh copper mine.

87

Hydrogen Embrittlement in Vanadium-based Hydrogen Separation ...  

Science Conference Proceedings (OSTI)

One of the important materials that face a challenge to overcome the hydrogen embrittlement is vanadium-based hydrogen separation membranes for an ...

88

Study on the Bond Mechanism of Vanadium Titano-magnetite ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The bond mechanism of vanadium titano-magnetite pellets mixed with coal powder by rotary hearth furnace was studied under the condition of ...

89

X-Ray Absorption Studies of Vanadium-Containing Metal Oxide Nanocrystals  

SciTech Connect

Metal oxide nanocrystals offer significant potential for use as catalysts or catalyst supports due to their high surface areas and unique chemical properties that result from the high number of exposed corners and edges. However, little is known about the catalytic activity of these materials, especially as oxidation catalysts. This research focused on the preparation, characterization and use of vanadium-containing nanocrystals as selective oxidation catalysts. Three vanadium-containing nanocrystals were prepared using a modified sol-gel procedure: V/MgO, V/SiO2, and vanadium phosphate (VPO). These represent active oxidation catalysts for a number of industrially relevant reactions. The catalysts were characterized by x-ray diffraction and Raman, UV-VIS, infrared and x-ray absorption spectroscopies with the goal of determining the primary structural and chemical differences between nanocrystals and microcrystals. The catalytic activity of these catalysts was also studied in oxidative dehydrogenation of butane and methanol oxidation to formaldehyde. V/MgO nanocrystals were investigated for activity in oxidative dehydrogenation of butane and compared to conventional V/MgO catalysts. Characterization of V/MgO catalysts using Raman spectroscopy and x-ray absorption spectroscopy showed that both types of catalysts contained magnesium orthovanadate at vanadium loadings below 15 weight%, but above that loading, magnesium pyrovanadate may have been present. In general, MgO nanocrystals had roughly half the crystal size and double the surface area of the conventional MgO. In oxidative dehydrogenation of butane, nanocrystalline V/MgO gave higher selectivity to butene than conventional V/MgO at the same conversion. This difference was attributed to differences in vanadium domain size resulting from the higher surface areas of the nanocrystalline support, since characterization suggested that similar vanadium phases were present on both types of catalysts. Experiments in methanol oxidation were used to probe the chemical differences between sol-gel prepared and conventionally prepared metal oxides. Both V/MgO and V/SiO2 were studied. For both catalysts, similar product selectivities were noted for either preparation method, suggesting similar acid/base and redox properties for the catalysts. At lower weight loadings (<5%), activity was also similar, but at higher weight loadings the sol-gel prepared catalysts were more active. This was attributed to the greater dispersion of vanadium on sol-gel prepared catalysts, and it was suggested that small vanadium oxide domains were more active in methanol oxidation than polymeric and bulk domains. A novel sol-gel method was developed for preparation of VPO catalysts, which are used industrially in butane oxidation to maleic anhydride. In this method vanadium (V) triisopropoxide was reacted with orthophosphoric acid in THF to form a gel. Drying this gel under air resulted in an intercalated VOPO4 compound, where solvent molecules were trapped between layers of the vanadium phosphate compound. Higher surface areas could be achieved by drying this gel at high pressure in an autoclave. The amount of solvent (THF) placed in the autoclave was important in this process. Low amounts of solvent led to a lower surface area, as the solvent evaporated before reaching the critical point and collapsed the gel's pores. In addition, vanadium reduction occurred in the autoclave due to reaction of isopropanol with the vanadium phosphate. Higher amounts of THF reduced the concentration of isopropanol, leading to less reduction. Surfaces areas in excess of 100 m2/g were achieved with this method, and the product was confirmed through XPS and IR to be VOHPO4*0.5H2O, the common precursor for industrial VPO catalysts. Furthermore, this product displayed a platelet morphology, which is desirable for butane oxidation. Further work showed that this material could be transformed to (VO)2P2O7 (the industrial catalyst for butane oxidation to maleic anhydride) by heating under nitrogen without losing much surface are

Hohn, Keith, L.

2006-01-09T23:59:59.000Z

90

ANIONIC EXCHANGE PROCESS FOR THE RECOVERY OF URANIUM AND VANADIUM FROM CARBONATE SOLUTIONS  

DOE Patents (OSTI)

Uranium and vanadium can be economically purified and recovered from non- salt roast carbonate leach liquors by adsorption on a strongly basic anionic exchange resin and subsequent selective elution by one of three alternative methods. Method 1 comprises selectively eluting uranium from the resin with an ammonium sulfate solution followed by eluting vanadium from the resin with either 5 M NaCl, saturated (NH/sub 4/)/sub 2/CO/sub 3/, saturated NaHCO/sub 3/, 1 M NaOH, or saturated S0/sub 2/ solutions. Method II comprises selectively eluting vanadium from the resin with either concentrated NaCl or S0/sub 2/ solutions subsequent to pretreatment of the column with either S0/sub 2/ gas, 1 N HCl, or 0.1 N H/sub 2/8O/sub 4/ followed by eluting uranium from the resin with solutions containing 0.9 M NH/sub 4/Cl or NaCl and 0.1 Cl. Method III comprises flowing the carbonate leac solutlon through a first column of a strongly basic anlonlc exchange resin untll vanadium breakthrough occurs, so that the effluent solution is enriched ln uranium content and the vanadium is chiefly retalned by the resln, absorbing the uranlum from the enriched effluent solution on a second column of a strongly basic anionic exchange resin, pretreating the first column with either 0.1 N HCl, 0.1 H/sub 2/SO/sub 4/, C0/sub 2/ gas, or ammonium sulfate, selectively eluting the vanadlum from the column with saturated S0/sub 2/ solution, pretreatlng the second column with either 0.1 N HCl or S0/sub 2/ gas, selectively eluting residual vanadium from the column with saturated S0/sub 2/ solution, and then eluting the uranium from the column with either 0.1 N HCl and 1 N NaCl orO.l N HCl and 1 N NH/sub 4/Cl.

Bailes, R.H.; Ellis, D.A.; Long, R.S.

1958-12-16T23:59:59.000Z

91

Vanadium-pumped titanium x-ray laser  

DOE Patents (OSTI)

A resonantly photo-pumped x-ray laser (10) is formed of a vanadium (12) and titanium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state neon-like titanium ions (34) are resonantly photo-pumped by line emission from fluorine-like vanadium ions (32).

Nilsen, Joseph (Livermore, CA)

1992-01-01T23:59:59.000Z

92

Vanadium-pumped titanium x-ray laser  

DOE Patents (OSTI)

A resonantly photo-pumped x-ray laser is formed of a vanadium and titanium foil combination that is driven by two beams of intense line focused optical laser radiation. Ground state neon-like titanium ions are resonantly photo-pumped by line emission from fluorine-like vanadium ions.

Nilsen, J.

1991-02-13T23:59:59.000Z

93

Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado  

Energy.gov (U.S. Department of Energy (DOE))

Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado

94

Novel alkylimidazolium/vanadium pentoxide intercalation compounds with excellent adsorption performance for methylene blue  

SciTech Connect

Novel alkylimidazolium-intercalated V{sub 2}O{sub 5} compounds were synthesized by a redox reaction between iodide ion and V{sub 2}O{sub 5}. The X-ray photoelectron spectroscopy and the diffuse reflectance UV-vis spectrometry experiments reveal that the vanadium in the intercalated V{sub 2}O{sub 5} products was partially reduced by an iodide ion and the resultant iodine can be removed in the final products. The transmission electron microscope observation and X-ray diffraction analysis testify that the prepared alkylimidazolium/V{sub 2}O{sub 5} intercalation compounds have typical lamellar structure with different d{sub 100} interlayer spacing values and the special straw-like nanofiber morphology with the length of 0.5-10 {mu}m. Systematic investigation indicates that new intercalation compounds possess the extraordinary adsorption performance for methylene blue in an aqueous solution. -- Graphical abstract: The alkylimidazolium-intercalated V{sub 2}O{sub 5} compounds with special straw-like nanofiber morphology were synthesized by a redox reaction between iodide ion and V{sub 2}O{sub 5}, which show the excellent adsorption performance for methylene blue in an aqueous medium. Display Omitted Research highlights: {yields} Novel alkylimidazolium-intercalated V{sub 2}O{sub 5} compounds. {yields} A simple preparation method by a redox reaction between iodide ion in ionic liquid and V{sub 2}O{sub 5}. {yields} The excellent adsorption performance for methylene blue in an aqueous medium.

Kong Aiguo; Ding Yongjie; Wang Ping; Zhang Hengqiang; Yang Fan [Department of Chemistry, East China Normal University, ShangHai City 200062 (China); Shan Yongkui, E-mail: ykshan@chem.ecnu.edu.c [Department of Chemistry, East China Normal University, ShangHai City 200062 (China)

2011-02-15T23:59:59.000Z

95

Interstitial embrittlement in vanadium laser welds  

DOE Green Energy (OSTI)

Efficiencies of interstitial absorption during pulsed ND:YAG laser welding of vanadium were compared for nitrogen, oxygen, hydrogen, and water vapor. Influence of interstitial levels on the embrittlement of vanadium laser welds was also measured. For 1000 ppM contaminant levels in the weld atmosphere, weld hydrogen content increased 9 ppM, nitrogen content increased 190 ppM, and oxygen content increased from 500 ppM relative to baseplate levels. Welds in ultrahigh-purity argon atmospheres contained 3 ppM hydrogen, 40 ppM nitrogen, and 250 ppM oxygen. Longitudinal all-weld tensile specimens and notched-plate specimens were used to measure weld metal tensile properties at {minus}55C. All of the laser weld notch-strength ratios exceeded unity and weld metal tensile strengths all exceeded the baseplate values. For 1000 ppM atmosphere contaminant levels, the only significant decrease in ductility, as measured by reduction-in-area at fracture was for the weld atmosphere containing oxygen. Weld atmospheres containing 1% nitrogen also reduced the weld ductility, and resulted in the onset of cleavage fracture.

Strum, M.J.; Wagner, L.M.

1992-02-24T23:59:59.000Z

96

Interstitial embrittlement in vanadium laser welds  

DOE Green Energy (OSTI)

Efficiencies of interstitial absorption during pulsed ND:YAG laser welding of vanadium were compared for nitrogen, oxygen, hydrogen, and water vapor. Influence of interstitial levels on the embrittlement of vanadium laser welds was also measured. For 1000 ppM contaminant levels in the weld atmosphere, weld hydrogen content increased 9 ppM, nitrogen content increased 190 ppM, and oxygen content increased from 500 ppM relative to baseplate levels. Welds in ultrahigh-purity argon atmospheres contained 3 ppM hydrogen, 40 ppM nitrogen, and 250 ppM oxygen. Longitudinal all-weld tensile specimens and notched-plate specimens were used to measure weld metal tensile properties at [minus]55C. All of the laser weld notch-strength ratios exceeded unity and weld metal tensile strengths all exceeded the baseplate values. For 1000 ppM atmosphere contaminant levels, the only significant decrease in ductility, as measured by reduction-in-area at fracture was for the weld atmosphere containing oxygen. Weld atmospheres containing 1% nitrogen also reduced the weld ductility, and resulted in the onset of cleavage fracture.

Strum, M.J.; Wagner, L.M.

1992-02-24T23:59:59.000Z

97

Redox Shuttle Additives | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

available for licensing: A series of novel redox shuttle additives for lithium-ion batteries for the purpose of overcharge protection and increased battery safety redoxshuttles...

98

Layered Vanadium and Molybdenum Oxides: Batteries and Electrochromics  

DOE Green Energy (OSTI)

The layered oxides of vanadium and molybdenum have been studied for close to 40 years as possible cathode materials for lithium batteries or electrochromic systems. The highly distorted metal octahedra naturally lead to the formation of a wide range of layer structures, which can intercalate lithium levels exceeding 300 Ah/kg. They have found continuing success in medical devices, such as pacemakers, but many challenges remain in their application in long-lived rechargeable devices. Their high-energy storage capability remains an encouragement to researchers to resolve the stability concerns of vanadium dissolution and the tendency of lithium and vanadium to mix changing the crystal structure on cycling the lithium in and out. Nanomorphologies have enabled higher reactivities to be obtained for both vanadium and molybdenum oxides, and with the latter show promise for electrochromic displays.

Chernova, N. A.; Roppolo, M.; Dillon, A. C.; Whittingham, M. S.

2009-01-01T23:59:59.000Z

99

Method to Remove Uranium/Vanadium Contamination from Groundwater  

DOE Patents (OSTI)

A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

Metzler, Donald R.; Morrison Stanley

2004-07-27T23:59:59.000Z

100

Pressure Acid Leaching Vanadium from Stone coal - Programmaster ...  

Science Conference Proceedings (OSTI)

Vanadium extraction from stone-coal was investigated by pressure acid ... The results show that with the leaching time for 3~4h, temperature at 150?, sulfuric acid consumption of 25%~30%, ... Calcium Reductants – A historical review.

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Method to remove uranium/vanadium contamination from groundwater  

DOE Patents (OSTI)

A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

Metzler, Donald R. (DeBeque, CO); Morrison, Stanley (Grand Junction, CO)

2004-07-27T23:59:59.000Z

102

Study on leaching vanadium from roasted residue of stone coal  

SciTech Connect

In China, the total reserves of vanadium, reported as V{sub 2}O{sub 5}, in stone coal is 118 Mt (130 million st). Recovering vanadium from such a large resource is very important to China's vanadium industry. The technology now being used to recover vanadium from stone coal has the following two problems in the leaching process: a low recovery of vanadium and high acid consumption. To resolve these problems, a new leaching technology is proposed. The effects of factors such as H{sub 2}SO{sub 4} concentration, liquid-solid ratio, temperature and time, and the types and additions of additives were studied. By adding 1.5% (by weight) CaF2 and leaching the roasted residue of stone coal with 5.4% (by weight) sulfuric acid at 90{sup o}C for 12 hours at a liquid-solid ratio of 2 mL/g, the leaching degree of vanadium reached 83.10%. This proposed leaching technology gives a feasible alternative for the processing of roasting residue of stone coal and can be applied in the comprehensive utilization of stone coal ores in China.

He, D.; Feng, Q.; Zhang, G.; Luo, W.; Ou, L. [Central South University, Changsha (China)

2008-11-15T23:59:59.000Z

103

Plasma enhanced chemical vapor deposition (PECVD) method of forming vanadium oxide films and vanadium oxide thin-films prepared thereby  

DOE Green Energy (OSTI)

A method is disclosed of forming a vanadium oxide film on a substrate utilizing plasma enhanced chemical vapor deposition. The method includes positioning a substrate within a plasma reaction chamber and then forming a precursor gas comprised of a vanadium-containing chloride gas in an inert carrier gas. This precursor gas is then mixed with selected amounts of hydrogen and oxygen and directed into the reaction chamber. The amounts of precursor gas, oxygen and hydrogen are selected to optimize the final properties of the vanadium oxide film An rf plasma is generated within the reaction chamber to chemically react the precursor gas with the hydrogen and the oxygen to cause deposition of a vanadium oxide film on the substrate while the chamber deposition pressure is maintained at about one torr or less. Finally, the byproduct gases are removed from the plasma reaction chamber.

Zhang, Ji-Guang (Golden, CO); Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO); Turner, John A. (Littleton, CO); Liu, Ping (Lakewood, CO)

2000-01-01T23:59:59.000Z

104

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion Batteries Technology available for licensing: Electrolytes containing novel redox shuttles (electron transporters) for...

105

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network (OSTI)

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

106

Impact of Vanadium Addition on API X100 Steel - Programmaster.org  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Tubular Processing & Technology. Presentation Title, Impact of Vanadium ...

107

CATALYTIC PROMOTION OF THE ADSORPTION OF VANADIUM ON AN ANIONIC EXCHANGE RESIN  

DOE Patents (OSTI)

An improvement in the process for the recovery of vanadium from acidic phosphatic solutions is presented. In this process the vanadium is first oxidized to the pentavaleat state, and is then separated by contacting such solutions with an anion exchange resin whereby adsorption of the complexed pentavalent vanadium is effected. The improvement lies in the fact that adsorp tion of the vanadium complex by the anion exchange resin is promoted and improved by providing fiuoride ions in solution to be contacted.

Bailes, R.H.; Ellis, D.A.

1958-08-26T23:59:59.000Z

108

Selective oxidation of n-butane and butenes over vanadium-containing catalysts  

Science Conference Proceedings (OSTI)

The oxidative dehydrogenation (OXDH) of n-butane, 1-butene, and trans-2-butene on different vanadia catalysts has been compared. MgO, alumina, and Mg-Al mixed oxides with Mg/(Al + Mg) ratios of 0.25 and 0.75 were used as supports. The catalytic data indicate that the higher the acid character of catalysts the lower is both the selectivity to C{sub 4}-olefins from n-butane and the selectivity to butadiene from both 1-butene or trans-2-butene. Thus, OXDH reactions are mainly observed from n-butane and butenes on basic catalysts. The different catalytic performance of both types of catalysts is a consequence of the isomerization of olefins on acid sites, which appears to be a competitive reaction with the selective way, i.e., the oxydehydrogenation process by a redox mechanism. Infrared spectroscopy data of 1-butene adsorbed on supported vanadium oxide catalysts suggest the presence of different adsorbed species. O-containing species (carbonyl and alkoxide species) are observed on catalysts with acid sites while adsorbed butadiene species are observed on catalysts with basic sites. According to these results a reaction network for the oxydehydrogenation of n-butane is proposed with parallel and consecutive reactions.

Nieto, J.M.L.; Concepcion, P.; Dejoz, A.; Knoezinger, H.; Melo, F.; Vazquez, M.I.

2000-01-01T23:59:59.000Z

109

Redox polymer electrodes for advanced batteries  

DOE Patents (OSTI)

Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene. 2 figs.

Gregg, B.A.; Taylor, A.M.

1998-11-24T23:59:59.000Z

110

Redox polymer electrodes for advanced batteries  

DOE Patents (OSTI)

Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene.

Gregg, Brian A. (Golden, CO); Taylor, A. Michael (Golden, CO)

1998-01-01T23:59:59.000Z

111

Can Vanadium Be Substituted into LiFePO4  

DOE Green Energy (OSTI)

Vanadium is shown to substitute for iron in the olivine LiFePO{sub 4} up to at least 10 mol %, when the synthesis is carried out at 550 C. In the solid solution LiFe{sub 1-3y/2}V{sub y}PO{sub 4}, the a and b lattice parameters and cell volume decrease with increasing vanadium content, while the c lattice parameter increases slightly. However, when the synthesis is performed at 650 C, a NASICON phase, Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}, is also formed, showing that solid solution is a function of the synthesis temperature. X-ray absorption near-edge structure indicates vanadium is in the 3+ oxidation state and in an octahedral environment. Magnetic studies reveal a shift of the antiferromagnetic ordering transition toward lower temperatures with increasing vanadium substitution, confirming solid solution formation. The addition of vanadium enhances the electrochemical performance of the materials especially at high current densities.

Omenya F.; Nam K.; Chernova N.A.; Upreti S.; Zavalij P.Y.; Nam K.-W.; Yang X.-Q.; Whittingham M.S.

2011-11-08T23:59:59.000Z

112

ORNUTM-13249 DRAFT AN ECOLOGICAL INVESTIGATION OF A VANADIUM  

Office of Legacy Management (LM)

ORNUTM-13249 ORNUTM-13249 DRAFT AN ECOLOGICAL INVESTIGATION OF A VANADIUM AND URANIUM MILL TAILINGS SITE 1. G. Smith, M. J. Peterson, and M. G. Ryon Biological Monitoring and Abatement Program Environmental Sciences Division Oak RidgeNational Laboratory Oak Ridge, Tennessee May 1996 Prepared for Gretchen A. Pierce Healthand Safety Research Division Environmental Technology Section Oak RidgeNational Laboratory GrandJunction, Colorado Prepared by the Environmental Sciences Division Oak RidgeNational Laboratory Oak Ridge, Tennessee 37831 Managed by LOCKHEED MARTIN ENERGY RESEARCH CORP. for the U. S. DEPARTMENT OF ENERGY under contract DE-AC05-960R22464 I. INTRODUCTION From 1942 through 1946, the Vanadium Corporation of America operated a vanadium and uranium mill in Monticello, Utah (Rust Geotech 1995a). In 1948, the U. S. Atomic Energy Commission (AEC) purchased the mill site

113

Synthesis and Enhanced Intercalation Properties of Nanostructured Vanadium Oxides  

DOE Green Energy (OSTI)

Nanomaterials lie at the heart of the fundamental advances in efficient energy storage/conversion and other types of nanodevices in which the surface process and transport kinetics play determining roles. This review describes some recent developments in the synthesis and characterizations of various vanadium oxide nanostructures including nanowires, nanorolls, nanobelts, and ordered arrays of nanorods, nanotubes, and nanocables for significantly enhanced intercalation properties. The major topic of this article is to highlight the lithium ion intercalation properties of nanostructured vanadium oxides for energy storage as well as other applications in sensors, actuators, and transistors.

Wang, Ying; Cao, Guozhong

2006-05-12T23:59:59.000Z

114

Features of vanadium impurity states in lead telluride  

Science Conference Proceedings (OSTI)

Temperature dependences of resistivity, magnetic susceptibility, and charge-carrier concentration and mobility in single-crystalline PbTe:V samples with a varied impurity content are investigated. It is shown that vanadium forms a donor level located {approx}20 meV below the conduction-band bottom. The electron mobility is as high as 10{sup 5} cm{sup 2} V{sup -1} s{sup -1} in the samples with N{sub V} {electron transport in PbTe:V may be caused by a variable vanadium valence and by the effect of interimpurity correlations.

Artamkin, A. I.; Dobrovolsky, A. A.; Vinokurov, A. A.; Zlomanov, V. P. [Moscow State University (Russian Federation); Gavrilkin, S. Y.; Ivanenko, O. M.; Mitzen, K. V. [Russian Academy of Sciences, Lebedev Physical Institute (Russian Federation); Ryabova, L. I.; Khokhlov, D. R., E-mail: khokhlov@mig.phys.msu.su [Moscow State University (Russian Federation)

2010-12-15T23:59:59.000Z

115

MICROSCALE METABOLIC, REDOX AND ABIOTIC REACTIONS IN HANFORD 300 AREA SUBSURFACE SEDIMENTS  

SciTech Connect

The Hanford 300 Area is a unique site due to periodic hydrologic influence of river water resulting in changes in groundwater elevation and flow direction. This area is also highly subject to uranium remobilization, the source of which is currently believed to be the region at the base of the vadose zone that is subject to period saturation due to the changes in the water levels in the Columbia River. We found that microbial processes and redox and abiotic reactions which operate at the microscale were critical to understanding factors controlling the macroscopic fate and transport of contaminants in the subsurface. The combined laboratory and field research showed how microscale conditions control uranium mobility and how biotic, abiotic and redox reactions relate to each other. Our findings extended the current knowledge to examine U(VI) reduction and immobilization using natural 300 Area communities as well as selected model organisms on redox-sensitive and redox-insensitive minerals. Using innovative techniques developed specifically to probe biogeochemical processes at the microscale, our research expanded our current understanding of the roles played by mineral surfaces, bacterial competition, and local biotic, abiotic and redox reaction rates on the reduction and immobilization of uranium.

Beyenal, Haluk [WSU] [WSU; McLEan, Jeff [JCVI] [JCVI; Majors, Paul [PNNL] [PNNL; Fredrickson, Jim [PNNL] [PNNL

2013-11-14T23:59:59.000Z

116

H[sub 2]S--Conclusion: Options narrowed to Claus or redox processes  

SciTech Connect

Depending on the gas flow rate and the produced tons of sulfur/day, the amine/Claus and Redox processes meet the requirements of a proposed CO[sub 2] EOR gas processing plant near Welch, Tex. In the low gas flow range and sulfur tonnage above 8 long tons/day, amine/Claus was best while for the high gas flow range and sulfur tonnage below 15 long tons/day, Redox was more economical. Five different sulfur recovery processes were evaluated for OXY USA Inc.'s CO[sub 2] enhanced oil recovery project (EOR) in West Texas. Part 1 described the overall processes selected. This concluding part will detail the sulfur recovery options.

Johnson, J.E. (Pritchard Corp., Overland, KS (United States)); Tzap, S.J.; Kelley, R.E. (Raytheon Engineers and Constructors, Denver, CO (United States)); Laczko, L.P. (OXY USA Inc., Midland, TX (United States))

1993-11-22T23:59:59.000Z

117

A New Redox Flow Battery Using Fe/V Redox Couples in Chloride ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Energy Storage: Materials, Systems and Applications. Presentation Title, A ...

118

A Kinetics Study on the Hydrometallurgical Recovery of Vanadium ...  

Science Conference Proceedings (OSTI)

In this research, recovery of vanadium from LD converter slag of steelmaking plant ... of the Chemical Changes and Surface Properties of Carbonated Waste Cement ... Flux for Basic Oxygen Steel Making Using Waste Oxides of Steel Plant ... Heat Treatment of Black Dross for the Production of a Value Added Material - A

119

ET Kinetics of Bifunctional Redox Protein Maquettes  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetics of Bifunctional Redox Protein Maquettes Kinetics of Bifunctional Redox Protein Maquettes Mitchell W. Mutz, James F. Wishart and George L. McLendon Adv. Chem Ser. 254, Ch. 10, pp. 145-159 Abstract: We prepared three bifunctional redox protein maquettes based on 12-, 16-, and 20-mer three-helix bundles. In each case, the helix was capped with a Co(III) tris-bipyridyl electron acceptor and also functionalized with a C-terminal viologen (1-ethyl-1'-ethyl-4,4'-bipyridinium) donor. Electron transfer (ET) was initiated by pulse radiolysis and flash photolysis and followed spectrometrically to determined average, concentration-independent, first-order rates for the 16-mer and 20-mer maquettes. For the 16-mer bundle, the alpha-helical content was adjusted by the addition of urea or trifluoroethanol to solutions containing the metalloprotein. This

120

Methods for using redox liposome biosensors  

DOE Patents (OSTI)

The present invention provides methods and compositions for detecting the presence of biologically-important analytes by using redox liposome biosensors. In particular, the present invention provides liposome/sol-gel electrodes suitable for the detection of a wide variety of organic molecules, including but not limited to bacterial toxins.

Cheng, Quan (SF, CA); Stevens, Raymond C. (La Jolla, CA)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Electrochemical kinetics of thin film vanadium pentoxide cathodes for lithium batteries  

E-Print Network (OSTI)

Electrochemical experiments were performed to investigate the processing-property-performance relations of thin film vanadium pentoxide cathodes used in lithium batteries. Variations in microstructures were achieved via ...

Mui, Simon C., 1976-

2005-01-01T23:59:59.000Z

122

Optimum Condition of Vanadium Recovery from Power Plant Fly-ash ...  

Science Conference Proceedings (OSTI)

Abstract Scope, In this study, recovery of vanadium from power plant fly-ash was developed using a hydro metallurgical process consisted of acidic leaching ...

123

Sol-gel synthesis of vanadium phosphorous oxides for the partial oxidation of n-butane to maleic anhydride.  

E-Print Network (OSTI)

??Vanadium phosphorous oxide (VPO) is traditionally manufactured from solid vanadium oxides by synthesizing VOHPO[4subscript][dot in middle of line]0.5H[2subscript]O (the precursor) followed by in-situ activation to… (more)

Salazar, Juan Manuel

2007-01-01T23:59:59.000Z

124

Anion permselective membrane. [For redox fuel cells  

DOE Green Energy (OSTI)

Experimental anion permeselective membranes were improved and characterized for use as separators in a chemical redox, power storage cell being developed at the NASA Lewis Research Center. The goal of minimal Fe/sup +3/ ion transfer was achieved for each candidate membrane system. Minimal membrane resistivity was demonstrated by reduction of film thickness using synthetic backing materials but usefulness of thin membranes was limited by the scarcity of compatible fabrics. The most durable and useful backing fabrics were modacrylics. One membrane, a copolymer of 4 vinylpyridine and vinyl benzylchloride was outstanding in overall electrochemical and physical properties. Long term (1000 hrs) membrane chemical and thermal durability in redox environment was shown by three candidate polymers and two membranes. The remainder had good durability at ambient temperature. Manufacturing capability was demonstrated for large scale production of membrane sheets 5.5 ft/sup 2/ in area for two candidate systems.

Alexander, S.S.; Hodgdon, R.B.

1978-01-01T23:59:59.000Z

125

Cellstrom | Open Energy Information  

Open Energy Info (EERE)

Austria Zip 2345 Sector Solar Product Austria based developer of vanadium redox flow batteries for solar plants. References Cellstrom1 LinkedIn Connections CrunchBase Profile No...

126

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A New Vanadium Redox Flow Battery Using Mixed Acid Electrolytes November 2, 2010 US DOE Energy Storage Systems (ESS) Program Review Washington DC Liyu Li, Soowhan Kim, Wei Wang, M....

127

Redox shuttles for safer lithium-ion batteries.  

DOE Green Energy (OSTI)

Overcharge protection is not only critical for preventing the thermal runaway of lithium-ion batteries during operation, but also important for automatic capacity balancing during battery manufacturing and repair. A redox shuttle is an electrolyte additive that can be used as intrinsic overcharge protection mechanism to enhance the safety characteristics of lithium-ion batteries. The advances on stable redox shuttles are briefly reviewed. Fundamental studies for designing stable redox shuttles are also discussed.

Chen, Z.; Qin, Y.; Amine, K.; Chemical Sciences and Engineering Division

2009-10-01T23:59:59.000Z

128

Isotope Effects and Helium Retention Behavior in Vanadium Tritide  

SciTech Connect

The relaxation times of the H, T, and 3He nuclei have been measured in vanadium hydride and tritide samples. Substantial isotope effects in both the phase transition temperatures and diffusion parameters have been found. When compared to hydrides, the tritide samples have lower transition temperatures and faster mobilities. The differences in the occupancies of the interstitial sites are largely responsible for these isotope effects. Most of the helium atoms generated by tritium decay remain trapped in microscopic bubbles formed with the VTx lattice. Evidence is presented for the gradual growth of the helium bubbles over periods of hundreds of days.

Bowman, Jr., R. C.; Attalla, A., and Craft, B. D.

1985-04-01T23:59:59.000Z

129

Electromigration of hydrogen and deuterium in vanadium, niobium, and tantalum  

DOE Green Energy (OSTI)

The electric mobility and effective valence of hydrogen and deuterium in vanadium, niobium, tantalum and three niobium-tantalum alloys were measured. A resistance technique was used to directly determine the electric mobility of hydrogen and deuterium at 30/sup 0/C while a steady-state method was used to measure the effective valence. The use of mass spectrographic techniques on a single specimen which contained both hydrogen and deuterium greatly increased the precision with which the isotope effect in the effective valence could be measured.

Jensen, C. L.

1977-10-01T23:59:59.000Z

130

Faster, More Efficient Redox Cycle to Split Water or ...  

heating or cooling is required between the respective ... using concentrated solar energy to provide thermal ... More Efficient Redox Cycle to Split W ...

131

Progress in understanding uranium redox processes in biologically...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Office of Science SSRL Phone List People Search Maps Progress in understanding uranium redox processes in biologically reduced sediments Wednesday, April 24, 2013 - 3:00pm...

132

Lithium Redox Process for Thermochemical Water-Splitting as ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Thermochemical water-splitting by Li redox process consists of three ... A21: First-Principles Molecular Dynamics Simulation of Chemical ...

133

Ultracompact Vanadium Dioxide Dual-Mode Plasmonic Waveguide Electroabsorption Modulator  

E-Print Network (OSTI)

Subwavelength modulators play an indispensable role in integrated photonic-electronic circuits. Due to weak light-matter interactions, it is always a challenge to develop a modulator with a nanometer scale footprint, low switching energy, low insertion loss and large modulation depth. In this paper, we propose the design of a vanadium dioxide dual-mode plasmonic waveguide electroabsorption modulator using a metal-insulator-VO$_2$-insulator-metal (MIVIM) waveguide platform. By varying the index of vanadium dioxide, the modulator can route plasmonic waves through the low-loss dielectric insulator layer during the "on" state and high-loss VO$_2$ layer during the "off" state, thereby significantly reducing the insertion loss while maintaining a large modulation depth. This ultracompact waveguide modulator, for example, can achieve a large modulation depth of ~10dB with an active size of only 200x50x220nm$^3$ (or ~{\\lambda}$^3$/1700), requiring a drive-voltage of ~4.6V. This high performance plasmonic modulator co...

Ooi, Kelvin J A; Chu, Hong Son; Ang, Lay Kee

2013-01-01T23:59:59.000Z

134

DOE - Office of Legacy Management -- Vanadium Corp of America - PA 15  

Office of Legacy Management (LM)

Vanadium Corp of America - PA 15 Vanadium Corp of America - PA 15 FUSRAP Considered Sites Site: Vanadium Corp. of America (PA.15) Eliminated from further consideration under FUSRAP. Designated Name: Not Designated Alternate Name: UMTRAP Vicinity Property No. CA-401 PA.15-5 Location: Mayer Street - Collier Township , Bridgeville , Pennsylvania PA.15-1 Evaluation Year: 1985 PA.15-2 Site Operations: Faclility used to grind pitchblende ore during the early 1940's for processing by Vitro at Canonsburg. Conducted research and developed processes for concentration of Colorado Plateau ores (uranium-vanadium) PA.15-3 Site Disposition: Eliminated - site cleaned up as a vicinity property of the Canonsburg Site in 1986 under the Uranium Mill Tailings Remedial Action Program (UMTRAP). PA.15-5

135

Metal-Semiconductor Transitions in Nanoscale Vanadium Dioxide - Thin Films, Subwavelength Holes, and Nanoparticles.  

E-Print Network (OSTI)

??Large-volume (bulk) vanadium dioxide (VO2) is an unusual material that undergoes a critical transition from insulating-like to metal-like when the temperature is raised above approximately… (more)

Donev, Eugenii U.

2008-01-01T23:59:59.000Z

136

SOLVENT EXTRACTION RECOVERY OF VANADIUM (AND URANIUM) FROM ACID LIQUORS WITH DI(2-ETHYLHEXYL) PHOSPHORIC ACID  

SciTech Connect

Bench-scale studies were made on use of di(2ethylhexyl)-phosphoric acid in an organic diluent (Dapex process) for solvent extraction recovery of vanadium from acid leach liquors. Vanadium may be stripped from the solvent by either acidic or alkaline reagents, the former having been studied in considerably greater detail. A process for single-cycle recovery and separation of uranium and vanadium from sulfate leach liquors was shown to be attractive both from the standpoint of operation and chemical costs. Process schemes for recovery of vanadium from uranium-barren liquors are also described. On the basis of the encouraging laboratory results, pilot scale tests for specific applications are recommended. (auth)

Crouse, D.J.; Brown, K.B.

1959-11-25T23:59:59.000Z

137

Molten salt synthesis and localized surface plasmon resonance study of vanadium dioxide nanopowders  

SciTech Connect

Rutile-type vanadium dioxide nanopowders with four different sizes were successfully synthesized by carbothermal reducing V{sub 2}O{sub 5} in KCl-LiCl molten salt. XRD and TEM characterizations suggested that vanadium dioxide particles formed by a broken and reunited process of vanadium oxide. Molten salt and organic carbon sources are crucial to the size of final particles. In the presence of the molten salt, the organic carbon with a shorter chain length would induce smaller particles. The UV-VIS-IR spectral measurements for as-prepared vanadium dioxide announced an obvious localized surface plasmon resonance band in the near infrared region at 90 deg. C. - Graphical abstract: Schematic illustration of the formation mechanism of VO{sub 2}(M) nanoparticles in molten salt, particles size can be controlled by choosing organic carbon sources with different chain length.

Wang Fu [Key Laboratory of Photochemical Conversion and Optoelectronic Materials of Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Zhongguancun, Beijing 100190 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100806 (China); Liu Yun [Key Laboratory of Photochemical Conversion and Optoelectronic Materials of Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Zhongguancun, Beijing 100190 (China); Liu Chunyan, E-mail: cyliu@mail.ipc.ac.c [Key Laboratory of Photochemical Conversion and Optoelectronic Materials of Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Zhongguancun, Beijing 100190 (China)

2009-12-15T23:59:59.000Z

138

Development of vanadium base alloys for fusion first-wall/blanket applications  

SciTech Connect

Vanadium alloys have been identified as a leading candidate material for fusion first-wall/blanket applications. Certain vanadium alloys exhibit favorable safety and environmental characteristics, good fabricability, high temperature and heat load capability, good compatibility with liquid metals and resistance to irradiation damage effects. The current focus is on vanadium alloys with (3-5)% Cr and (3-5)% Ti with a V-4Cr-4Ti alloy as the leading candidate. Preliminary results indicate that the crack-growth rates of certain alloys are not highly sensitive to irradiation. Results from the Dynamic Helium Charging Experiment (DHCE) which simulates fusion relevant helium/dpa ratios are similar to results from neutron irradiated material. This paper presents an overview of the recent results on the development of vanadium alloys for fusion first wall/blanket applications.

Smith, D.L.; Chung, H.M.; Loomis, B.A. [Argonne National Lab., IL (United States); Matsui, H. [Tohoku Univ., Sendai (Japan); Votinov, S. [Bochvar Institute of Inorganic Materials (Russia); VanWitzenburg, W. [Netherlands Energy Research Foundation (ECN), Petten (Netherlands)

1994-09-01T23:59:59.000Z

139

Molecular based magnets comprising vanadium tetracyanoethylene complexes for shielding electromagnetic fields  

DOE Patents (OSTI)

The invention presents a vanadium tetracyanoethylene solvent complex for electromagnetic field shielding, and a method for blocking low frequency and magnetic fields using these vanadium tetracyanoethylene compositions. The compositions of the invention can be produced at ambient temperature and are light weight, low density and flexible. The materials of the present invention are useful as magnetic shields to block low frequency fields and static fields, and for use in cores in transformers and motors.

Epstein, Arthur J. (Columbus, OH); Morin, Brian G. (Columbus, OH)

1998-01-01T23:59:59.000Z

140

Molecular based magnets comprising vanadium tetracyanoethylene complexes for shielding electromagnetic fields  

DOE Patents (OSTI)

The invention presents a vanadium tetracyanoethylene solvent complex for electromagnetic field shielding, and a method for blocking low frequency and magnetic fields using these vanadium tetracyanoethylene compositions. The compositions of the invention can be produced at ambient temperature and are light weight, low density and flexible. The materials of the present invention are useful as magnetic shields to block low frequency fields and static fields, and for use in cores in transformers and motors. 21 figs.

Epstein, A.J.; Morin, B.G.

1998-10-13T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Growth and surface structure of vanadium oxide on anatase (001)  

Science Conference Proceedings (OSTI)

Oxygen plasma assisted molecular beam epitaxy (OPA-MBE) of vanadium oxide on (1?4)-reconstructed anatase (001) thin films was studied using reflection high energy electron diffraction (RHEED), low energy electron diffraction (LEED), x-ray and ultraviolet photoelectron spectroscopy (XPS and UPS), x-ray diffraction (XRD), and transmission electron microscopy (TEM). XPS and UPS results showed that the vanadium was predominantly in the 5+ oxidation state after deposition of a monolayer at 525 K. After 1 ML of vanadia was deposited, the anatase (1?4)/(4?1) LEED and RHEED patterns were replaced by (1?1) patterns indicating that the vanadia lifts the reconstruction and suggesting that the monolayer is pseudomorphic. At 525 K, the V?? oxidation state predominated in thicker films, however, no discernible LEED or RHEED patterns were seen after a few monolayers were deposited indicating that V?O? epitaxy cannot be continued beyond 1 ML. When the growth temperature was increased to 750 K, RHEED patterns indicated no change in the surface structure after more than 20 ML of vanadia were deposited. Under these conditions, XPS peak positions were consistent with VO?. After growth at 775 K a c(2x2) LEED pattern attributed to half a monolayer of adsorbed oxygen on the VO? surface was observed. The surface characterization data all pointed towards pseudomorphic growth of VO? with a half monolayer of capping oxygen allowing the monolayer to achieve the V?O? stoichiometry while maintaining the anatase structure. Bulk XRD data, however, were consistent with VO? (B), V?O??, and rutile VO? none of which expose surfaces with the periodicity observed with RHEED and LEED. The reasons for the differences between the surface and bulk characterization are discussed.

Gao, Weiwei; Wang, Chong M.; Wang, Huiqiong; Henrich, Victor E.; Altman, Eric I.

2004-06-20T23:59:59.000Z

142

Preparation of redox polymer cathodes for thin film rechargeable batteries  

DOE Patents (OSTI)

The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

1994-11-08T23:59:59.000Z

143

Alternative Evaluation for the REDOX (202-S) Plutonium Loadout Hood  

Science Conference Proceedings (OSTI)

Located in the 200 Areas is the inactive 202-S Reduction Oxidation (REDOX) Facility, which is managed by the Bechtel Hanford, Inc. Surveillance/Maintenance and Transition project. This facility is contaminated from nuclear material processes related to nuclear material separation from Hanford Site facility operations. This alternative evaluation report describes the alternatives and selection criteria based on the necessary protective requirements to maintain the REDOX Plutonium Loadout Hood in a safe and stable condition awaiting a final waste response action.

N. R. Kerr

1999-09-20T23:59:59.000Z

144

Under Pressure, Vanadium Won't Turn Down the Volume | Advanced Photon  

NLE Websites -- All DOE Office Websites (Extended Search)

New Nanoscale Engineering Breakthrough Points to Hydrogen-Powered Vehicles New Nanoscale Engineering Breakthrough Points to Hydrogen-Powered Vehicles Patterning High-density Arrays of Nanospheres with Self Assembly Cells Forming Blood Vessels Send Their Copper to the Edge A Molecular Cause for One Form of Deafness Water Theory is Watertight Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Under Pressure, Vanadium Won't Turn Down the Volume MARCH 7, 2007 Bookmark and Share The upper panel is the diffraction pattern of vanadium recorded on an image plate at 18 GPa under hydrostatic conditions. The indexing is based on a body centered cubic lattice. The lower panel is the diffraction pattern of vanadium at 73 GPa. Inserts are zoomed images showing the splitting of 110,

145

Hydrogen Release from Irradiated Vanadium Alloy V-4Cr-4Ti  

DOE Green Energy (OSTI)

The present work is an attempt to obtain data concerning the influence of neutron and ? irradiation upon hydrogen retention in V-4Cr-4Ti vanadium alloy. The experiments on in-pile loading of vanadium alloy specimens at the neutron flux density 1014 n/cm2s, hydrogen pressure of 80 Pa, and temperatures of 563, 613, and 773 K were carried out using the IVG.1M reactor of the Kazakhstan National Nuclear Center. A preliminary set of loading/degassing experiments with non-irradiated material has been carried out to obtain data on hydrogen interaction with vanadium alloy. The, data presented in this work are related both to non-irradiated and irradiated samples.

Klepikov, A. Kh.; Romanenko, O. G.; Chikhray, E. V.; Tazhibaeva, I. L.; Shestakov, V. P.; Longhurst, Glen Reed

1999-09-01T23:59:59.000Z

146

Thermodynamic Analyses of Iron Oxides Redox Reactions  

Science Conference Proceedings (OSTI)

To clarify such confusions, the elementary thermodynamic data of various iron ... and water vapor are used to calculate the changes of thermodynamic quantities such as .... Heat Transfer Characteristic in a Slag Heat Recovery Chamber ... Numerical Simulation of Electro-magnetic Flow Control Phenomenon in a Tundish.

147

Methane oxidation over dual redox catalysts. Quarterly technical progress report, July--September 1989  

SciTech Connect

The objective of this research is to develop approaches to direct catalytic oxidation of methane over oxides that are doubly doped with transition metal ions. The desired process aims at employing a double redox mechanism, where one redox couple is utilized for activation of oxygen and another for the trapping of CH{sub 3} radicals. The methyl radicals can either recombine, giving C{sub 2} hydrocarbons, or be converted, via electron transfer reaction, to carbocations. The latter species can react with surface OH{sup {minus}} groups to form methanol or formaldehyde. To choose from several possible catalytic systems, this research initially involved the characterization of the micromorphology and crystalline dimensions of zinc oxide catalysts doped with Cu, Fe, and Sn by scanning electron microscopy. In addition, the determination of surface composition and oxidation states by X-ray photoelectron spectroscopy was carried out. A newly constructed high temperature catalytic testing system has been calibrated (flow meters and temperature controllers), tested for possible gas leaks and integrated with a gas chromatographic analytical unit. A preliminary catalytic test study over a Cu/Fe/ZnO sample was performed. The following products of the methane coupling reaction was found: C{sub 2}H{sub 6}, C{sub 2}H{sub 4} and H{sub 2}O together with CO{sub 2}. The maximum space time yield of 14 mmol C{sub 2} hydrocarbons/g cat/h was obtained at 848{degrees}C.

Klier, K.; Herman, R.G.; Sojka, Z.

1989-09-01T23:59:59.000Z

148

Redox reactions with empirical potentials: Atomistic battery discharge simulations  

E-Print Network (OSTI)

Batteries are pivotal components in overcoming some of today's greatest technological challenges. Yet to date there is no self-consistent atomistic description of a complete battery. We take first steps toward modeling of a battery as a whole microscopically. Our focus lies on phenomena occurring at the electrode-electrolyte interface which are not easily studied with other methods. We use the redox split-charge equilibration (redoxSQE) method that assigns a discrete ionization state to each atom. Along with exchanging partial charges across bonds, atoms can swap integer charges. With redoxSQE we study the discharge behavior of a nano-battery, and demonstrate that this reproduces the generic properties of a macroscopic battery qualitatively. Examples are the dependence of the battery's capacity on temperature and discharge rate, as well as performance degradation upon recharge.

Dapp, Wolf B

2013-01-01T23:59:59.000Z

149

Evaluation of vanadium carbide for mitigating fuel cladding chemical ...  

Science Conference Proceedings (OSTI)

... Materials and Fuels for the Current and Advanced Nuclear Reactors III ... L38: A Theoretical Model of Corrosion Rate Distribution in Liquid LBE Flow Loop at ...

150

Metal-ligand redox interaction in the multielectron chemistry of porphyrinogen coordination compounds  

E-Print Network (OSTI)

Metal complexes of the macrocycle porphyrinogen (calix[4]pyrrole) are studied with an emphasis on the redox activity ("non-innocence") of the ligand (Chapter I). Porphyrinogen complexes of spherical, redox-inert metal ...

Bachmann, Julien

2006-01-01T23:59:59.000Z

151

Temperature Dependence of Aliovalent-vanadium Doping in LiFePO4 Cathodes  

Science Conference Proceedings (OSTI)

Vanadium-doped olivine LiFePO4 cathode materials have been synthesized by a novel low-temperature microwave-assisted solvothermal (MW-ST) method at 300 oC. Based on chemical and powder neutron/X-ray diffraction analysis, the compositions of the synthesized materials were found to be LiFe1-3x/2Vx x/2PO4 (0 x 0.2) with the presence of a small number of lithium vacancies charge-compensated by V4+, not Fe3+, leading to an average oxidation state of ~ 3.2+ for vanadium. Heating the pristine 15 % V-doped sample in inert or reducing atmospheres led to a loss of vanadium from the olivine lattice with the concomitant formation of a Li3V2(PO4)3 impurity phase; after phase segregation, a partially V-doped olivine phase remained. For comparison, V-doped samples were also synthesized by conventional ball milling and heating, but only ~ 10 % V could be accommodated in the olivine lattice in agreement with previous studies. The higher degree of doping realized with the MW-ST samples demonstrates the temperature dependence of the aliovalent-vanadium doping in LiFePO4.

Harrison, Katharine L [University of Texas at Austin; Bridges, Craig A [ORNL; Paranthaman, Mariappan Parans [ORNL; Idrobo Tapia, Juan C [ORNL; Manthiram, Arumugam [University of Texas at Austin; Goodenough, J. B. [University of Texas at Austin; Segre, C [Illinois Institute of Technology; Katsoudas, John [Illinois Institute of Technology; Maroni, V. A. [Argonne National Laboratory (ANL)

2013-01-01T23:59:59.000Z

152

Study of lithium diffusion in RF sputtered Nickel/Vanadium mixed oxides thin films  

E-Print Network (OSTI)

Study of lithium diffusion in RF sputtered NickelÁ/Vanadium mixed oxides thin films F. Artuso a lithium insertion inside RF sputtered Ni/V mixed oxides thin films have been investigated employing, showed three steps clearly involved in the intercalation mechanism of lithium in the oxide films: (i

Artuso, Florinda

153

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1986-01-01T23:59:59.000Z

154

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1987-01-01T23:59:59.000Z

155

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1987-04-21T23:59:59.000Z

156

Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic compression  

E-Print Network (OSTI)

Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic form 16 September 2003; accepted 9 October 2003 Abstract We have processed fully dense, nano that the grain size of the consolidated V is around 100 nm. Mechanical properties of the nano-structured V were

Wei, Qiuming

157

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1985-05-17T23:59:59.000Z

158

Development and application of a redox indicator method for the kinetics of oxidation of vanadium(II) ions by hydrogen peroxide and alkyl hydroperoxides  

SciTech Connect

The addition of the methyl viologen radical cation (PQ/sup .+/) to solutions of V(H/sub 2/O)/sub 6//sup 2 +/ and hydrogen peroxide or alkyl hydroperoxide provides a method for measuring the initial reaction rate. The kinetic data so obtained are consistent with the rate equation -d(peroxide)/dt = k/sub 1/(V/sup 2 +/)(peroxide). Kinetic data are given for H/sub 2/O/sub 2/ (k/sub 1/ = 15.4 M/sup -1/ s/sup -1/ at 25.0/sup 0/C) and for RC(CH/sub 3/)/sub 2/OOH, with R = CH/sub 3/ (3.0 M/sup -1/ s/sup -1/), C/sub 2/H/sub 5/ (5.2 M/sup -1/ s/sup -1/), and CH/sub 2/C/sub 6/H/sub 5/ (4.8 M/sup -1/ s/sup -1/). 27 references, 2 figures, 2 tables.

Kim, H.P.; Espenson, J.H.; Bakac, A.

1987-12-02T23:59:59.000Z

159

Biogeochemical Redox Processes and their Impact on Contaminant Dynamics  

E-Print Network (OSTI)

of biogeochemical redox processes is crucial for predicting and protecting environmental health and can provide new the chemical speciation, bioavailability, toxicity, and mobility of many major and trace elements including Fe, and mobility of these elements in the environment are directly affected by reduction and oxidation. In addition

Sparks, Donald L.

160

Redox mediation and hydrogen-generation with bipyridinium reagents  

SciTech Connect

A variety of redox mediating agents employing bipyridinium reagents and such reagents in conjunction with dispersed noble metals, such as platinium, are disclosed as coatings for substrates and electrodes. The agents may be charged by an applied voltage or by photoelectric effects or may be equilibrated with hydrogen. The agents are useful in reducing biological materials and electrolytic hydrogen production.

Wrighton, Mark S. (Winchester, MA); Bookbinder, Dana C. (East Greenwich, RI); Bruce, James A. (Somerville, MA); Dominey, Raymond N. (Pensacola, FL); Lewis, Nathan S. (Palo Alto, CA)

1984-03-27T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Carbon nanotube-induced preparation of vanadium oxide nanorods: Application as a catalyst for the partial oxidation of n-butane  

SciTech Connect

A vanadium oxide-carbon nanotube composite was prepared by solution-based hydrolysis of NH{sub 4}VO{sub 3} in the presence of carbon nanotubes. The carbon nanotubes induce the nucleation of the 1D vanadium oxide nanostructures, with the nuclei growing into long freestanding nanorods. The vanadium oxide nanorods with the lengths up to 20 {mu}m and the widths of 5-15 nm exhibit a well-ordered crystalline structure. Catalytic tests show that the composite with nanostructured vanadium oxide is active for the partial oxidation of n-butane to maleic anhydride at 300 deg. C.

Chen Xiaowei [Department of Inorganic Chemistry, Fritz-Haber-Institute of MPG, Faradayweg 4-6, D-14195 Berlin (Germany); Zhu Zhenping [Department of Inorganic Chemistry, Fritz-Haber-Institute of MPG, Faradayweg 4-6, D-14195 Berlin (Germany); Haevecker, Michael [Department of Inorganic Chemistry, Fritz-Haber-Institute of MPG, Faradayweg 4-6, D-14195 Berlin (Germany); Su Dangsheng [Department of Inorganic Chemistry, Fritz-Haber-Institute of MPG, Faradayweg 4-6, D-14195 Berlin (Germany)]. E-mail: dangsheng@fhi-berlin.mpg.de; Schloegl, Robert [Department of Inorganic Chemistry, Fritz-Haber-Institute of MPG, Faradayweg 4-6, D-14195 Berlin (Germany)

2007-02-15T23:59:59.000Z

162

Redox shuttle additives for overcharge protection in lithium batteries  

DOE Green Energy (OSTI)

Seven new redox shuttle additives with shuttle current onset potentials above 4.2 V vs Li/Li+ are reported, along with diffusion coefficients for the neutral additives. The dependence of the limiting shuttle current on the respective diffusion coefficients of the oxidized and reduced forms of an additive is clarified. Overcharge protection in liquid electrolyte Li/LiMn{sub 2}O{sub 4} cells is demonstrated.

Richardson, Thomas J.; Ross Jr., P.N.

1999-11-11T23:59:59.000Z

163

In situ redox manipulation treatability test -- waste management plan  

DOE Green Energy (OSTI)

This Waste Management Plan provides guidance for the management of waste generated from groundwater well installations in the 100-HR-3 Operable Unit. The well installations are necessary to implement the In Situ Redox Manipulation Treatability Test to determine methods for in situ remedial efforts to prevent discharge of hexavalent chromium at levels above those considered protective of aquatic life in the Columbia River and riverbed sediments

A. J. Knepp

1997-12-31T23:59:59.000Z

164

Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium  

E-Print Network (OSTI)

The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

E. I. Sharapov; C. L. Morris; M. Makela; A. Saunders; Evan R. Adamek; Yelena Bagdasarova; L. J. Broussard; C. B. Cude-Woods; Deon E Fellers; Peter Geltenbort; S. I. Hasan; K. P. Hickerson; G. Hogan; A. T. Holley; Chen-Yu Liu; M. P. Mendenhall; J. Ortiz; R. W. Pattie Jr.; D. G. Phillips; J. Ramsey; D. J. Salvat; S. J. Seestrom; E. Shaw; Sky Sjue; W. E. Sondheim; B. VornDick; Z. Wang; T. L. Womack; A. R. Young; B. A. Zeck

2013-06-05T23:59:59.000Z

165

PROCESS FOR RECOVERY OF URANIUM AND VANADIUM FROM CARBONATE SOLUTIONS BY REDUCTION-PRECIPITATION  

DOE Patents (OSTI)

A process employing carbonate leaching of ores and an advantageous methcd of recovering the uranium and vanadium from the leach solution is described. The uranium and vanadium can be precipitated from carbonate leach solutions by reaction with sodium amalgam leaving the leach solution in such a condition that it is economical to replenish for recycling. Such a carbonate leach solution is treated with a dilute sodium amalgam having a sodium concentration within a range of about 0.01 to 0.5% of sodium. Efficiency of the treatment is dependent on at least three additional factors, intimacy of contact of the amalgam with the leach solution, rate of addition of the amalgam and exclusion of oxygen (air).

Ellis, D.A.; Lindblom, R.O.

1957-09-24T23:59:59.000Z

166

Facile synthesized nanorod structured vanadium pentoxide for high-rate lithium batteries  

Science Conference Proceedings (OSTI)

Nano-structured vanadium oxide (V2O5) is fabricated via facile thermal-decomposition of a vanadium precursor and vanadyl oxalate produced by reacting micro-sized V2O5 with oxalic acid. The V2O5 nanorods produced by this method exhibit much better electrochemical performance than commercial micro-sized V2O5. The optimized-nanorod electrodes with a high density of (001) planar defects give the best specific discharge capacities of 270 mAh g-1 at C/2 (147 mA g-1) coupled with good cycle stability with only 0.32% fading per cycle. Even at a high rate of 4C (1176 mA g-1), the nanorod electrode still delivers 198 mAh g-1. These results suggest that the nanostructured V2O5 is a good cathode for high-rate, lithium-ion battery applications.

Pan, Anqiang; Zhang, Jiguang; Nie, Zimin; Cao, Guozhong H.; Arey, Bruce W.; Li, Guosheng; Liang, Shu-quan; Liu, Jun

2010-04-23T23:59:59.000Z

167

Characterization of vanadium/silica and copper/silica aerogel catalysts  

DOE Green Energy (OSTI)

Vanadium/silica and copper/silica aerogels have been prepared using the sol-gel method followed by CO{sub 2} exchange and supercritical extraction. Structural properties of samples supercritically dried, oxidized and used in reactions studies conducted with a feed representing the average composition of automobile exhaust from a lean burn engine were investigated using laser Raman spectroscopy and temperature-programmed reduction. No evidence of crystalline V{sub 2}O{sub 5} was found for the vanadium/silica aerogel, freshly extracted, oxidized or following exposure to reaction conditions using these techniques. However, results obtained for the copper/silica sample indicate that changes in the structure of the copper species had occurred as the sample was oxidized and exposed to reaction conditions.

Owens, L.; Tillotson, T.M.; Hair, L.M. [Lawrence Livermore National Lab., CA (United States). Chemistry and Materials Science Dept.

1995-09-01T23:59:59.000Z

168

Studies of hydrogen isotope separation using vanadium hydride in a temperature cycling process  

DOE Green Energy (OSTI)

Separations of gaseous HT-H/sub 2/ mixtures on vanadium monohydride were carried out using a two-column temperature cycling process similar to parametric pumping. An equilibrium theory of process operation is presented which was in qualitative agreement with experimental results. Failure to achieve complete removal of HT from the cold column effluent as predicted was ascribed to the finite rates of the exchange reaction and to the presence and operation of an isotope effect in the rate of hydrogen absorption.

Wong, Y.W.; Chan, Y.N.I.; Hill, F.B.

1979-01-01T23:59:59.000Z

169

Electrical and optical properties of sputtered amorphous vanadium oxide thin films  

Science Conference Proceedings (OSTI)

Amorphous vanadium oxide (VO{sub x}) is a component found in composite nanocrystalline VO{sub x} thin films. These types of composite films are used as thermistors in pulsed biased uncooled infrared imaging devices when containing face centered cubic vanadium monoxide phase crystallites, and substantial fractions of amorphous material in the composite are necessary to optimize device electrical properties. Similarly, optoelectronic devices exploiting the metal-to-semiconductor transition contain the room-temperature monoclinic or high-temperature (>68 deg. C) rutile vanadium dioxide phase. Thin films of VO{sub x} exhibiting the metal-to-semiconductor transition are typically polycrystalline or nanocrystalline, implying that significant amounts of disordered, amorphous material is present at grain boundaries or surrounding the crystallites and can impact the overall optical or electronic properties of the film. The performance of thin film material for either application depends on both the nature of the crystalline and amorphous components, and in this work we seek to isolate and study amorphous VO{sub x}. VO{sub x} thin films were deposited by pulsed dc reactive magnetron sputtering to produce amorphous materials with oxygen contents {>=}2, which were characterized electrically by temperature dependent current-voltage measurements and optically characterized by spectroscopic ellipsometry. Film resistivity, thermal activation energy, and complex dielectric function spectra from 0.75 to 6.0 eV were used to identify the impact of microstructural variations including composition and density.

Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Gauntt, B. D. [Materials Characterization Department, Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Motyka, M. A.; Horn, M. W. [Department of Engineering Science and Mechanics, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Dickey, E. C. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

2012-04-01T23:59:59.000Z

170

Hydrogen transport and embrittlement for palladium coated vanadium-chromium-titanium alloys  

DOE Green Energy (OSTI)

Vanadium based alloys have been identified as a leading candidate material for fusion first-wall blanket structure application because they exhibit favorable safety and environmental characteristics, good fabricability, potential for high performance and long-time operation lifetime in a fusion environment. As part of a study of the thermodynamics, kinetics and embrittlement properties of hydrogen in vanadium based alloys, experiments were conducted to determine the rate of hydrogen transport through the vanadium reference alloys, V-7.5Cr-15Ti and V-4Cr-4Ti, and to determine these alloys` hydrogen embrittlement, they were exposed to hydrogen pressures of 3 and 300 kPa (0.03--3 atm) at temperatures between 380 and 475 C. To facilitate hydrogen entry and egress, tubes of these alloys were coated with palladium on the inside and outside faces. Observed permeabilities were 0.015 to 0.065 {micro}moles/(m{sup 2}sPa{sup 0.5}) for the V-7.5Cr-15Ti alloy and 0.02 to 0.05 {micro}moles/m{sup 2}sPa{sup 0.5} for the V-4Cr-4Ti alloy depending on the quality of the coat and the operating temperature. At 1.7 atm hydrogen, V-7.5Cr-15Ti embrittled at temperatures below 380 C while V-4Cr-4Ti embrittled around 330 C.

Buxbaum, R.E.; Subramanian, R. [REB Research and Consulting, Ferndale, MI (United States); Park, J.H.; Smith, D.L. [Argonne National Lab., IL (United States). Fusion Power Program

1995-09-01T23:59:59.000Z

171

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

DOE Green Energy (OSTI)

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

172

Redox Kinetics and Diffusion in Lithium Niobate by Optical In Situ ...  

Science Conference Proceedings (OSTI)

Redox kinetics upon oxygen activity jumps and the associated chemical diffusion coefficients are found in close agreement at a given temperature, indicating a ...

173

Metal Ferrite Spinels for Solar-thermal Water Splitting REDOX Cycles  

Science Conference Proceedings (OSTI)

Presentation Title, Metal Ferrite Spinels for Solar-thermal Water Splitting REDOX Cycles. Author(s), Alan Weimer. On-Site Speaker (Planned), Alan Weimer.

174

Progress on Technology of Redox Flow Battery and Its Application in ...  

Science Conference Proceedings (OSTI)

Electrochemical Charge/Discharge Behavior of Li-Mg Alloy Anodes for High Capacity Lithium Batteries · Electronic Conductivity Enhancement of CNT Dispersed ...

175

Appendix F Stream Flow.xls  

Office of Legacy Management (LM)

Stream Flow Measurement Results Since 2000 Stream Flow Measurement Results Since 2000 This page intentionally left blank Appendix F Stream Flow Measurement Results Since 2000 Collect Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where gradient steepens/lined. 4/14/2000 SW00-01 0.44 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 4/14/2000 SW00-02 0.74 Pipe outfall at east end of millsite

176

Flow Cells for Energy Storage Workshop Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop Summary Report Workshop Summary Report Prepared for: U. S. Department of Energy Prepared by: Dr. Adam Z. Weber Lawrence Berkeley National Laboratory Organizing Committee: Michael Perry, UTRC Tom Zawodzinski, UTK and ORNL Ned Stetson, DOE EERE Mark Johnson, DOE ARPA-E Imre Gyuk, DOE OEDER i Executive Summary An essentially identical technology to a reversible fuel cell is that of a redox flow cell (RFC) or redox flow battery (RFB), where a RFC can be seen as merging the concepts of RFBs with recent improvements in fuel cells. To investigate how a RFC can be a grid-scale electrical- energy-storage (EES) system and the associated technological needs, this workshop was held. The specific objectives of the workshop were to understand the needs for applied research in RFCs; identify the grand challenges and prioritize R&D needs; and gather input for future

177

An Improved Equilibrium-Kinetics Speciation Algorithm For Redox...  

Open Energy Info (EERE)

Flow Systems Details Activities (0) Areas (0) Regions (0) Abstract: Reactive chemical transport occurs in a variety of geochemical environments, and over a broad range of...

178

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mössbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mössbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

179

Method of reduction of nitroaromatics by enzymatic reaction with redox enzymes  

DOE Patents (OSTI)

A method for the controlled reduction of nitroaromatic compounds such as nitrobenzene and 2,4,6-trinitrotoluene by enzymatic reaction with redox enzymes, such as Oxyrase (Trademark of Oxyrase, Inc., Mansfield, Ohio).

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

180

Consequences of redox-active phenazines on the physiology of the opportunistic pathogen Pseudomonas aeruginosa  

E-Print Network (OSTI)

Phenazines are redox-active small molecules produced by bacteria. Although phenazines have been studied extensively for their roles as toxins, how phenazines benefit producing organisms is still being uncovered. Pseudomonas ...

Kern, Suzanne E

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Transimination of Quinone Imines: A Mechanism for Embedding Exogenous Redox Activity into the Nucleosome  

E-Print Network (OSTI)

Aminophenols can redox cycle through the corresponding quinone imines to generate ROS. The electrophilic quinone imine intermediate can react with protein thiols as a mechanism of immobilization in vivo. Here, we describe ...

Ye, Wenjie

182

Thermodynamic Basis for Redox Regulation of the Yap1 Signal Transduction Pathway  

E-Print Network (OSTI)

-like enzyme, oxidant receptor protein (Orp1). We were unable to obtain satisfactory redox titration data for Orp1 at pH 7.0, but if the redox-active disulfide of Orp1 exhibits the -59 mV per pH unit dependence for Em typical of protein disulfides in this pH region, an Em value of -315 mV can be estimated for Orp1

Wood, Matthew J.

183

Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium  

E-Print Network (OSTI)

The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} heating by thermal excitations in solids.

Sharapov, E I; Makela, M; Saunders, A; Adamek, Evan R; Bagdasarova, Yelena; Broussard, L J; Cude-Woods, C B; Fellers, Deon E; Geltenbort, Peter; Hasan, S I; Hickerson, K P; Hogan, G; Holley, A T; Liu, Chen-Yu; Mendenhall, M P; Ortiz, J; Pattie, R W; Phillips, D G; Ramsey, J; Salvat, D J; Seestrom, S J; Shaw, E; Sjue, Sky; Sondheim, W E; VornDick, B; Wang, Z; Womack, T L; Young, A R; Zeck, B A

2013-01-01T23:59:59.000Z

184

Microstructural evolution of thin film vanadium oxide prepared by pulsed-direct current magnetron sputtering  

Science Conference Proceedings (OSTI)

Vanadium oxide (VO{sub x}) thin films have been deposited by pulsed-DC magnetron sputtering using a metallic vanadium target in a reactive argon and oxygen environment. While the process parameters (power, total pressure, oxygen-to-argon ratio) remained constant, the deposition time was varied to produce films between 75 {+-} 6 and 2901 {+-} 30 A thick, which were then optically and electrically characterized. The complex dielectric function spectra ({epsilon} = {epsilon}{sub 1} + i{epsilon}{sub 2}) of the films from 0.75 to 5.15 eV were extracted by ex situ, multiple-angle spectroscopic ellipsometry (SE) measurements for the series of varied thickness VO{sub x} samples. Significant changes in {epsilon} and resistivity occur as a function of thickness, indicating the correlations exist between the electrical and the optical properties over this spectral range. In addition, in situ measurements via real time SE (RTSE) were made on the film grown to the largest thickness to track optical property and structural variations during growth. RTSE was also used to characterize changes in the film occurring after growth was completed, namely during post sputtering in the presence of argon and oxygen while the sample is shielded, and atmospheric exposure. RTSE indicates that the exposure of the film to the argon and oxygen environment, regardless of the shutter isolating the target, causes up to 200 A of the top surface of the deposited film to become more electrically resistive as evidenced by variations in {epsilon}. Exposure of the VO{sub x} thin film to atmospheric conditions introduces a similar change in {epsilon}, but this change occurs throughout the bulk of the film. A combination of these observations with RTSE results indicates that thinner, less ordered VO{sub x} films are more susceptible to drastic changes due to atmospheric exposure and that microstructural variations in this material ultimately control its environmental stability.

Motyka, M. A.; Horn, M. W. [Department of Engineering Science and Mechanics, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Gauntt, B. D. [Sandia National Laboratories, P.O. Box 5800-1411, Albuquerque, New Mexico 87185-1411 (United States); Dickey, E. C. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27606 (United States); Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States)

2012-11-01T23:59:59.000Z

185

1: Redox chemistry of bimetallic fulvalene complexes; 2: Oligocyclopentadienyl complexes  

Science Conference Proceedings (OSTI)

The electrochemistry of the heterobimetallic complexes (fulvalene)WFe(CO){sub 5} (30) and (fulvalene)WRu(CO){sub 5} (31) has been investigated. Compound 30 is reduced in two one-electron processes, and this behavior was exploited synthetically to prepare a tetranuclear dimer by selective metal reduction. Complex 31 displayed a distinction between the metals upon reoxidation of the dianion, allowing the formation of a dimer by selective metal anion oxidation. The redox behavior of 30 led to an investigation of the use of electrocatalysis to effect metal-specific ligand substitution. It was found that reduction of 30 with a catalytic amount of CpFe(C{sub 6}Me{sub 6}) (97) in the presence of excess P(OMe){sub 3} or PMe{sub 3} led to the formation of the zwitterions (fulvalene)[W(CO){sub 3}{sup {minus}}][Fe(CO)PR{sub 3}{sup +}] (107, R = P(OMe){sub 3}; 108, R = PMe{sub 3}). Compound 31 also displayed unique behavior with different reducing agents, as the monosubstituted zwitterion (fulvalene)[W(CO){sub 3}{sup {minus}}][Ru(CO){sub 2}(PMe{sub 3}){sup +}] was obtained when 97 was used while the disubstituted complex (fulvalene) [W(CO){sub 3}{sup {minus}}] [Ru(CO)(PMe{sub 3}){sub 2}{sup +}] was produced when Cp*Fe(C{sub 6}Me{sub 6}) was the catalyst. Potential synthetic routes to quatercyclopentadienyl complexes were also explored. Various attempts to couple heterobimetallic fulvalene compounds proved to be unsuccessful. 138 refs.

Brown, D.S. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States). Chemical Sciences Div.

1993-11-01T23:59:59.000Z

186

Lithium-vanadium advanced blanket development. ITER final report on U.S. contribution: Task T219/T220  

SciTech Connect

The objective of this task is to develop the required data base and demonstrate the performance of a liquid lithium-vanadium advanced blanket design. The task has two main activities related to vanadium structural material and liquid lithium system developments. The vanadium alloy development activity included four subtasks: (1.1) baseline mechanical properties of non irradiated base metal and weld metal joints; (1.2) compatibility with liquid lithium; (1.3) material irradiation tests; and (1.4) development of material manufacturing and joining methods. The lithium blanket technology activity included four subtasks: (2.1) electrical insulation development and testing for liquid metal systems; (2.2) MHD pressure drop and heat transfer study for self-cooled liquid metal systems; (2.3) chemistry of liquid lithium; and (2.4) design, fabrication and testing of ITER relevant size blanket mockups. A summary of the progress and results obtained during the period 1995 and 1996 in each of the subtask areas is presented in this report.

Smith, D.L.; Mattas, R.F. [comps.] [comps.

1997-07-01T23:59:59.000Z

187

Development of Advanced Flow-Through External Pressure-Balanced Reference Electrode for Temperatures up to 400 degrees C.  

Science Conference Proceedings (OSTI)

Development of an advanced flow-through external pressure-balanced reference electrode opens the door for more accurate measurements of corrosion potential, redox potential, and pH in power plant waters at temperatures up to 400 degrees C. Such measurements allow a more accurate assessment of an environment's corrosivity and promote more effective corrosion control.

1998-01-29T23:59:59.000Z

188

Final Technical Report  

Science Conference Proceedings (OSTI)

The overall goal of this project was to design, evaluate, and engineer a Vanadium Red-Ox Flow Battery's integration into an existing wind site and micro-grid environment to determine if it is possible to achieve a fifteen percent reduction of diesel fuel usage during periods of peak load and otherwise stabilize the grid in potential high wind penetration systems. The bulk of the work was done by modeling the existing hybrid wind-diesel system and the proposed system with added flow battery storage. The flow battery was changed from a Vanadium Red-Ox to a Zinc Bromine flow battery by a different manufacturer during the modeling process. Several complications arose, but modeling proved to be successful and is ongoing. The development of a modeling platform for flow battery energy storage is a key element in evaluating both economic benefits and dispatch strategies for high penetration in micro-grid wind-diesel systems.

Logan, Jesse, L; Witmer, Dennis, PhD

2012-07-29T23:59:59.000Z

189

FLOW GATING  

DOE Patents (OSTI)

BS>This invention is a fast gating system for eiectronic flipflop circuits. Diodes connect the output of one circuit to the input of another, and the voltage supply for the receiving flip-flop has two alternate levels. When the supply is at its upper level, no current can flow through the diodes, but when the supply is at its lower level, current can flow to set the receiving flip- flop to the same state as that of the circuit to which it is connected. (AEC)

Poppelbaum, W.J.

1962-12-01T23:59:59.000Z

190

The Integration of a Structural Water Gas Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device  

DOE Green Energy (OSTI)

This project is in response to a requirement for a system that combines water gas shift technology with separation technology for coal derived synthesis gas. The justification of such a system would be improved efficiency for the overall hydrogen production. By removing hydrogen from the synthesis gas stream, the water gas shift equilibrium would force more carbon monoxide to carbon dioxide and maximize the total hydrogen produced. Additional benefit would derive from the reduction in capital cost of plant by the removal of one step in the process by integrating water gas shift with the membrane separation device. The answer turns out to be that the integration of hydrogen separation and water gas shift catalysis is possible and desirable. There are no significant roadblocks to that combination of technologies. The problem becomes one of design and selection of materials to optimize, or at least maximize performance of the two integrated steps. A goal of the project was to investigate the effects of alloying elements on the performance of vanadium membranes with respect to hydrogen flux and fabricability. Vanadium was chosen as a compromise between performance and cost. It is clear that the vanadium alloys for this application can be produced, but the approach is not simple and the results inconsistent. For any future contracts, large single batches of alloy would be obtained and rolled with larger facilities to produce the most consistent thin foils possible. Brazing was identified as a very likely choice for sealing the membranes to structural components. As alloying was beneficial to hydrogen transport, it became important to identify where those alloying elements might be detrimental to brazing. Cataloging positive and negative alloying effects was a significant portion of the initial project work on vanadium alloying. A water gas shift catalyst with ceramic like structural characteristics was the second large goal of the project. Alumina was added as a component of conventional high temperature water gas shift iron oxide based catalysts. The catalysts contained Fe-Al-Cr-Cu-O and were synthesized by co-precipitation. A series of catalysts were prepared with 5 to 50 wt% Al{sub 2}O{sub 3}, with 8 wt% Cr{sub 2}O{sub 3}, 4 wt% CuO, and the balance Fe{sub 2}O{sub 3}. All of the catalysts were compared to a reference WGS catalyst (88 wt% FeO{sub x}, 8 wt% Cr{sub 2}O{sub 3}, and 4 wt% CuO) with no alumina. Alumina addition to conventional high temperature water gas shift catalysts at concentrations of approximately 15 wt% increased CO conversion rates and increase thermal stability. A series of high temperature water gas shift catalysts containing iron, chromia, and copper oxides were prepared with small amounts of added ceria in the system Fe-Cr-Cu-Ce-O. The catalysts were also tested kinetically under WGS conditions. 2-4 wt% ceria addition (at the expense of the iron oxide content) resulted in increased reaction rates (from 22-32% higher) compared to the reference catalyst. The project goal of a 10,000 liter per day WGS-membrane reactor was achieved by a device operating on coal derived syngas containing significant amounts of carbon monoxide and hydrogen sulfide. The membrane flux was equivalent to 52 scfh/ft{sup 2} based on a 600 psi syngas inlet pressure and corresponded to membranes costing $191 per square foot. Over 40 hours of exposure time to syngas has been achieved for a double membrane reactor. Two modules of the Chart reactor were tested under coal syngas for over 75 hours with a single module tested for 50 hours. The permeance values for the Chart membranes were similar to the REB reactor though total flux was reduced due to significantly thicker membranes. Overall testing of membrane reactors on coal derived syngas was over 115 hours for all reactors tested. Testing of the REB double membrane device exceeded 40 hours. Performance of the double membrane reactor has been similar to the results for the single reactor with good maintenance of flux even after these long exposures to hydrogen sulfide. Of special in

Thomas Barton; Tiberiu Popa

2009-06-30T23:59:59.000Z

191

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Power Power Vanadium Redox Battery Demonstration Project Joseph F. Startari Ashlawn Energy Funded in part by the Energy Storage Systems Program of the U.S. Department Of Energy through National Energy Technology Laboratory US Produced Vanadium Redox Flow Battery for Bulk Storage, Peak Shaving * 8 MWh redox flow battery (1MW 8 hours) * To be installed at Painesville Municipal Electric Plant (PMEP), a 32 MW coal fired facility * Most efficient PMEP operation is steady state at 26 MW (lowest emissions, lowest operating cost) * Nominal PMEP power demand ranges from 19 MW to 37 MW * 8 MWh battery to demonstrate benefits of energy storage at PMEP Painesville Battery Layout Project has Multiple Related Objectives * Establish/Use US Manufacturing Base - Stack components/stack fabrication

192

Flow cytometer  

DOE Patents (OSTI)

A Faraday cage enclosing the flow chamber of a cytometer and ground planes associated with each field deflection plate in concert therewith inhibit electric fields from varying the charge on designated events/droplets and further concentrates and increases forces applied to a charged event passing therethrough for accurate focus thereof while concomitantly inhibiting a potential shock hazard.

van den Engh, Ger (Seattle, WA)

1995-01-01T23:59:59.000Z

193

Flow cytometer  

DOE Patents (OSTI)

A Faraday cage is described which encloses the flow chamber of a cytometer. Ground planes associated with each field deflection plate inhibit electric fields from varying the charge on designated events/droplets and further concentrates. They also increase forces applied to a passing charged event for accurate focus while concomitantly inhibiting a potential shock hazard. 4 figs.

Van den Engh, G.

1995-11-07T23:59:59.000Z

194

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft Landing  

SciTech Connect

Soft landing (SL) of mass-selected ions is used to introduce catalytically-active metal complexes complete with organic ligands into the gas phase and then to transfer them as ions onto an inert surface. This is part of an effort to prepare materials with defined active sites and thus achieve molecular design of surfaces in a highly controlled way. Solution-phase electrochemical studies have shown that VIVO(salen) reacts in the presence of acid to form VVO(salen)+ and the deoxygenated VIII(salen)+ complex -- a key intermediate in the four electron reduction of O2 by vanadium-salen. In this work, the VVO(salen)+ and [NiII(salen)+H]+ complexes were generated by electrospray ionization and mass-selected before being deposited into an inert fluorinated self-assembled monolayer (FSAM) surface on gold. A time dependence study after ion deposition showed loss of O from VVO(salen)+ forming VIII(salen)+ over a four-day period, indicating a slow interfacial reduction process. Similar results were obtained when other protonated molecules were co-deposited with VVO(salen)+ on the FSAM surface. In all these experiments oxidation of the VIII(salen)+ product occurred upon exposure to oxygen or to air. The cyclic regeneration of VVO(salen)+ upon exposure to molecular oxygen and its subsequent reduction to VIII(salen)+ in vacuum completes the catalytic cycle of O2 reduction by the immobilized vanadium-salen species. Moreover, our results represent the first evidence of formation of reactive organometallic complexes on substrates in the absence of solvent. Remarkably, deoxygenation of the oxo-vanadium complex, previously observed only in highly acidic non-aqueous solvents, occurs on the surface in the UHV environment using an acid which is deposited into the inert monolayer. This acid can be a protonated metal complex, e.g. [NiII(salen)+H]+ or an organic acid such as protonated diaminododecane.

Peng, Wen-Ping; Johnson, Grant E.; Fortmeyer, Ivy C.; Wang, Peng; Hadjar, Omar; Cooks, Robert G.; Laskin, Julia

2011-01-01T23:59:59.000Z

195

PEGylated Nanoceria as Radical Scavenger with Tunable Redox Chemistry  

DOE Green Energy (OSTI)

Cerium oxide nanoparticles (CNPs) have shown tremendous potential in various applications such as water gas shift catalysis, chemical mechanical planarization (CMP), solid oxide fuel cells (SOFC), solar cells4 and high temperature oxidation protection coatings1. Recently, CNPs have been demonstrated to protect biological tissues against radiation induced damage, scavenging of superoxide anions, prevention of laser induced retinal damage, reduction of spinal injury in a tissue culture model, prevention of cardiovascular myopathy, pH dependent antioxidant properties, as a tool for immunoassays as well as other inflammatory diseases2. In most biomedical applications it is speculated that nanoceria is a regenerative radical scavenger with the ability to regenerate its active 3+ oxidation state for radical scavenging. Thus far there are no reports to control the regeneration of Ce3+ oxidation state which is the most important parameter in the application of CNPs as a reliable and regenerative radical scavenger. Thus, there is an imminent need to increase the potency of CNPs to achieve higher degree of protection against reactive oxygen species (ROS), to increase the residence time of CNPs in body and to control the regeneration of 3+ oxidation state. PEG has been reported to increase the residence time of nanoparticles and proteins inside cells and provide biocompatibility3. PEGylated counterparts of the SOD enzymes have shown improved performance over non-PEGylated enzymes. Herein, we report our efforts to synthesize CNPs directly in polyethylene glycol (mol wt 600) solution and determine the effect of increasing concentration of PEG (PEG vol % as 5, 10, 20, 40, 60 and 80) on the SOD mimetic properties exhibited by nanoceria. We also report how the active Ce3+ oxidation state can be regenerated or further tuned to regenerate at faster rate. We further demonstrate the role of PEG on the redox chemistry of CNPs catalyzed by hydrogen peroxide. Several complexes of PEGs with lanthanides have been reported and characterized4. To evaluate the effect of PEG concentration on the complexation of cerium, UV-Vis spectra of the precursor salt of cerium (cerium nitrate hexahydrate) in different solutions of PEG were obtained (SI-1). It was observed that all PEG solutions showed an increase in absorption relative to the water based solution of cerium nitrate but the observed non specific trend cannot be ascribed to a systematic decrease in the solvent polarity or dielectric constant. This observation is in contrast to Uekawa et al5 who reported a red shift upon addition of cerium nitrate in PEG however, they ruled out the charge transfer between Ce4+ and oxygen. The above observation confirms the complexation of PEG with cerium ions. The CNPs were then synthesized as described in the experimental details (SI-2). High resolution transmission electron micrograph (Figure 1a) demonstrates that PEG coats as an amorphous layer on CNPs as observed from an amorphous background behind the crystalline core. To confirm further CNPs synthesized in PEG were dialyzed using a 3500 MWCO cellulose membrane and the FTIR spectrum was collected from the isolated powder. Figure 1b confirms the presence of PEG on the nanoceria particles. To facilitate the explanation, only representative spectrum from 20% PEG solution is shown.

Karakoti, Ajay S.; Singh, Sanjay; Kumar, Amit; Malinska, M.; Kuchibhatla, Satyanarayana V N T; Wozniak, K.; Self, William; Seal, Sudipta

2009-10-14T23:59:59.000Z

196

Redox reactions of reduced flavin mononucleotide (FMN), riboflavin (RBF), and anthraquinone-2,6-disulfonate (AQDS) with ferrihydrite and lepidocrocite  

SciTech Connect

Flavins are secreted by the dissimilatory iron-reducing bacterium Shewanella and can function as endogenous electron transfer mediators (ETM). In order to assess the potential importance of flavins in Fe(III) bioreduction, we investigated the redox reaction kinetics of reduced flavins (FMNH2 and RBFH2) with ferrihydrite and lepidocrocite. The organic reductants rapidly reduced and dissolved ferrihydrite and lepidocrocite in the pH range 4-8. The rate constant k for 2-line ferrihydrite reductive dissolution by FMNH2 was 87.5 ? 3.5 M-1?s-1 at pH 7.0 in batch reactors, and the k was similar for RBFH2. For lepidocrocite, the k was 500 ? 61 M-1?s-1 for FMNH2, and 236 ? 22 M-1?s-1 for RBFH2. The surface area normalized initial reaction rates (ra) were between 0.08 and 77 ?moles?m-2?s-1 for various conditions in stopped-flow experiments. Initial rates (ro) were first-order with respect to Fe(III) oxide concentration, and ra increased with decreasing pH. Poorly crystalline 2-line ferrihydrite yielded the highest ra, followed by more crystalline 6-line ferrihydrite, and crystalline lepidocrocite. Compared to a previous whole-cell study with Shewanella oneidensis strain MR-1, our findings suggest that ETM reduction by the Mtr pathway coupled to lactate oxidation are rate limiting, rather than heterogeneous electron transfer to the Fe(III) oxide.

Shi, Zhi; Zachara, John M.; Shi, Liang; Wang, Zheming; Moore, Dean A.; Kennedy, David W.; Fredrickson, Jim K.

2012-11-01T23:59:59.000Z

197

Role of vanadium(V) in the aging of the organic phase in the extraction of uranium(VI) by Alamine 336 from acidic sulfate leach liquors  

Science Conference Proceedings (OSTI)

The present work is focussed on the chemical degradation of Alamine 336-tridecanol-n-dodecane solvent which used in the recovery of uranium by solvent extraction. Degradation occurs due to the presence of vanadium(V), an oxidant, in the feed solution. After a brief overview of the chemistry of vanadium, the kinetics of degradation of the solvent when contacted with acidic sulfate leach liquor was investigated and interpreted by the Michelis-Menten mechanism. GCMS analyses evidenced the presence of tridecanoic acid and dioctylamine as degradation products. A mechanism of degradation is discussed. (authors)

Chagnes, A.; Cote, G. [Ecole Nationale Superieure de Chimie de Paris - ENSCP Universite Pierre et Marie Curie - Paris 6 - Laboratoire d'Electrochimie et de Chimie Analytique - UMR 7575 CNRS-ENSCP-Paris 6 ENSCP, 11 Rue Pierre et Marie Curie, 75231 Paris Cedex 05 (France); Courtaud, B.; Thiry, J. [AREVA-NC, Service d'Etudes de Procedes et d'Analyses (SEPA), B.P. No 71, 87250 Bessines sur Gartempe (France)

2008-07-01T23:59:59.000Z

198

Microfabricated capillary electrophoresis chip and method for simultaneously detecting multiple redox labels  

DOE Patents (OSTI)

This invention relates to a microfabricated capillary electrophoresis chip for detecting multiple redox-active labels simultaneously using a matrix coding scheme and to a method of selectively labeling analytes for simultaneous electrochemical detection of multiple label-analyte conjugates after electrophoretic or chromatographic separation.

Mathies, Richard A. (Moraga, CA); Singhal, Pankaj (Berkeley, CA); Xie, Jin (Walnut Creek, CA); Glazer, Alexander N. (Orinda, CA)

2002-01-01T23:59:59.000Z

199

Append_F_Stream Flow.xls  

Office of Legacy Management (LM)

Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where gradient steepens/lined. 4/14/2000 SW00-01 0.44 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 4/14/2000 SW00-02 0.74 Pipe outfall at east end of millsite 4/17/2000 SW94-01 2.11 4/17/2000 SW92-08 0.85 4/17/2000 SW00-04 0.95 4/18/2000 Sorenson 0.72 4/18/2000 SW00-03 0.58 6/21/2000 SW00-01 0.32 MONTEZUMA CREEK, culvert pair under road on millsite just east of

200

Phosphorus Flow Analysis for Food Production and Consumption  

Science Conference Proceedings (OSTI)

ISASMELT™ for Recycling of Valuable Elements Contributing to a More Sustainable Society · Leaching of Uranium and Vanadium from Korean Domestic Ore.

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Improved Fluid Flow Measurements: Feedwater Flow  

Science Conference Proceedings (OSTI)

This report describes the combined results of a utility survey and site visits concerning feedwater flow measurement in fossil-fueled power plants. In addition, a summary is provided of the technologies available to measure the volumetric feedwater flow rate in plants. This volumetric flow rate can be converted to a mass flow rate by knowing the pressure and temperature of the flow media. Velocity meters, differential pressure meters, and other closed-conduit flowmeters are discussed along with ...

2012-11-28T23:59:59.000Z

202

Microbially-enhanced redox solution reoxidation for sweetening sour natural gas  

SciTech Connect

About twenty five percent of natural gas produced in the United States is sour containing significant volumes of hydrogen sulfide and other contaminants. Liquid redox processes remove hydrogen sulfide from natural gas. Aqueous solution of chelated ferric ions oxidize the hydrogen sulfide to elemental sulfur. The reduced iron chelate is then oxidized by contact with air and recycled. This requires expensive equipment for regeneration, costly chemicals and the process is usually energy intensive. Recent studies show that the ferric ion regeneration rates are substantially enhanced in presence of acidophilic bacteria. The specific objectives of this project are to advance the technology and improve the economics of the commercial iron-based chelate processes utilizing biologically-enhanced reoxidation of the redox solutions used in these processes, such as LO-CAT II and SulFerox.

Rai, C.

1995-06-01T23:59:59.000Z

203

EVALUATION OF AMENDMENTS FOR MENDING THE INSITU REDOX MANIPULATION (ISRM) BARRIER  

SciTech Connect

In May of 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from DOE Headquarters EM-23 to provide a team of technical experts to evaluate likely chemical/biological amendments for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site. This request was a follow-on to an earlier request for assistance regarding the cause of chromium (Cr) breakthrough and recommendations for mending the barrier (March 2004 workshop). This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)] was discovered along the Columbia River shoreline and in the 100-D Area. Between 1999 and 2003, a reactive barrier using the ISRM technology, was installed at a distance of 680 meters along the river to reduce the Cr(VI) in the groundwater. The ISRM technology creates a treatment zone within the aquifer by injection of sodium dithionite, a strong reducing agent that scavenges dissolved oxygen (DO) from the aquifer and reduces ferric iron [Fe(III)], related metals, and oxy-ions. Bench-scale and field-scale treatability tests were conducted to demonstrate proof-of principle and to estimate barrier longevity, calculated to be in excess of twenty years. However, several years after initial and secondary treatment, groundwater in approximately 17 wells has been found to contain elevated Cr concentrations. The March 2004 technical assistance team (TAT) identified potential causes of Cr breakthrough as likely related to physical and chemical heterogeneity within the aquifer (including loss of reductive capacity within preferential flow paths) and the presence of other oxidants (DO and nitrate) significantly affecting the reductive capacity of the treated aquifer. These aquifer characteristics may limit the ability of alternative amendments to extend the reducing capacity of the barrier. A 2001 Bechtel Hanford report and evaluation of the ISRM performance data and barrier longevity assessment corroborate the observations and findings of the March 2004 TAT. The March 2004 TAT recommended the collection of new aquifer characterization data in combination with the interpretation of existing data to develop a conceptual model of aquifer heterogeneity to enable design of the most appropriate barrier mending system. The current TAT was convened to examine the most promising amendment that could be applied to mend the ISRM barrier. The Technical Assistance Team (TAT) performed the following activities: (1) Evaluate the most appropriate single or combination of chemical/biological amendments suitable for increasing the reductive capacity of the ISRM barrier; (2) Evaluate the most practicable means of introducing chemical/biological amendments in the target zones along the current BRM barrier; (3) Provide recommendations for laboratory treatability-testing protocol development to evaluate the type and delivery mechanisms of amendments in the current ISRM barrier location. Sections of this report present analyses and recommendations of potential amendments and delivery options to improve performance of the ISRM barrier. The report covers the spectrum of passive barrier mending to chemical and biological amendments that have been shown to perform more efficiently in more active remedial design approaches. Because DOE/RL is considering significant aquifer characterization studies as additional time and cost investment to mending the barrier, the TAT strongly recommends that DOE/RL conduct cost-benefit analyses of alternative designs to mend the barrier. In this way, the value and extent of characterization studies, compared to passive amendment delivery, compared to engineering redesign, can be quantitatively estimated for decision-making purposes.

PETERSEN, S.W.

2006-02-07T23:59:59.000Z

204

Structural Basis for NADH/NAD+ Redox Sensing by a Rex Family Repressor  

SciTech Connect

Nicotinamide adenine dinucleotides have emerged as key signals of the cellular redox state. Yet the structural basis for allosteric gene regulation by the ratio of reduced NADH to oxidized NAD{sup +} is poorly understood. A key sensor among Gram-positive bacteria, Rex represses alternative respiratory gene expression until a limited oxygen supply elevates the intracellular NADH:NAD{sup +} ratio. Here we investigate the molecular mechanism for NADH/NAD{sup +} sensing among Rex family members by determining structures of Thermus aquaticus Rex bound to (1) NAD{sup +}, (2) DNA operator, and (3) without ligand. Comparison with the Rex/NADH complex reveals that NADH releases Rex from the DNA site following a 40{sup o} closure between the dimeric subunits. Complementary site-directed mutagenesis experiments implicate highly conserved residues in NAD-responsive DNA-binding activity. These rare views of a redox sensor in action establish a means for slight differences in the nicotinamide charge, pucker, and orientation to signal the redox state of the cell.

McLaughlin, K.J.; Soares, A.; Strain-Damerell, C. M.; Xie, K.; Brekasis, D.; Pagent, M. S. B.; Kielkopf, C. L.

2010-05-28T23:59:59.000Z

205

Radiation-induced non-equilibrium redox chemistry of plutonium: implications for environmental migration  

SciTech Connect

Static concentrations of plutonium oxidation states in solution and at surfaces in oxide-water systems are identified as non-equilibrium steady states. These kinetically controlled systems are described by redox cycles based on irreversible disproportionation of Pu(IV), Pu(V), and Pu(VI) in OH-bridged intermediate complexes and at OH-covered oxide surfaces. Steady state is fixed by continuous redox cycles driven by radioactivity-promoted electron-transfer and energetically favorable reactions of Pu(III) and Pu(VII) disproportionation products with H2O. A model based on the redox cycles accounts for the high steady-state [Pu] coexisting with Pu(IV) hydrous oxide at pH 0-15 and for predominance of Pu(V) and Pu(VI) in solution. The steady-state [Pu] depends on pH and the surface area of oxide in solution, but not on the initial Pu oxidation state. PuO{sub 2+x} formation is attributed to high Pu(V) concentrations existing at water-exposed oxide surfaces. Results infer that migration of Pu in an aqueous environment is controlled by kinetic factors unique to that site and that the predominant oxidation states in solution are Pu(V) and Pu(VI).

Haschke, J M; Siekhaus, W J

2009-02-11T23:59:59.000Z

206

100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater: FY 1998 Year-End Report  

Science Conference Proceedings (OSTI)

A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the US Department of Energy's Hanford, Washington 100D Area. The target contaminant was dissolved chromate [Cr(VI)] in groundwater. The ISRM technology involves creating a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron [Fe(III)] to ferrous iron [Fe(II)] within the aquifer sediments. This is accomplished by injecting aqueous sodium dithionite into the aquifer and withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in the spring of 1997. The first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998; the remaining four dithionite injections were carried out in May through July of 1998. These five injections created a reduced zone in the Hanford unconfined aquifer 150 feet in length (perpendicular to groundwater flow) by 50 feet wide. The reduced zone extended over the thickness of the unconfined zone, which is approximately 15 feet. Analysis of recent groundwater sampling events shows that the concentrations of chromate [Cr(VI)] in groundwater in the reduced zone have been decreased from starting concentrations of approximately 900 ppb to below analytical detection limits (<7 ppb). Chromate concentrations are also declining in some downgradient monitoring wells. Laboratory analysis of iron in the soil indicates that the barrier should remain in place for approximately 20 to 25 years. These measurements will be confirmed by analysis of sediment cores in FY 1999.

Williams, M.D.; Vermeul, V.R.; Szecsody, J.E.; Fruchter, J.S.; Cole, C.R.

1999-04-15T23:59:59.000Z

207

Effects of Redox Cycling of Iron in Nontronite on Reduction of Technetium  

Science Conference Proceedings (OSTI)

In situ technetium-99 (99Tc) immobilization by Fe(II) associated with clay minerals has been studied and is a potential cost-effective method for Tc remediation at the United States Department of Energy (DOE) sites. Fe redox cycling are common in sedimentary environments, however their effect on Tc reduction and immobilization has not yet been investigated. The objective of this project was therefore to study how multiple cycles of reduction-reoxidation of Fe-rich clay mineral, nontronite, affected its reactivity toward Tc (VII) reduction. Iron-rich nontronite NAu-2 was used as a model clay mineral. NAu-2 suspension was first bioreduced by Shewanella putrefaciens CN32, which consequently was re-oxidized by air. Three cycles of reduction-oxidation were conducted and bioreduced NAu-2 samples from all three cycles were collected and used for Tc(VII) reduction experiments. Each redox cycle resulted in a small fraction of dissolution of small size and/or poorly crystalline NAu-2. The released Fe(II) from the dissolution was likely adsorbed onto NAu-2 surface/edge sites with a high reactivity. Upon exposure to O2, this reactive Fe(II) fraction was oxidized more rapidly than structural Fe(II) and may have accounted for a two-step reoxidation kinetics of NAu-2 associated Fe(II): rapid oxidation over first few hours followed by slow oxidation. Progressive increase of this reactive fraction of Fe(II), from increased dissolution, accounted for the successively higher rate of bioreduction and reoxidation with increased redox cycles. The same Fe redistribution accounted for two-step Tc(VII) reduction kinetics as well. Rapid Tc(VII) reduction in the first few hours may be attributed to a small fraction of highly reactive Fe(II) at the NAu-2 surface/edge sites, and more steady Tc(VII) reduction over longer time may be carried out by structural Fe(II). Similar to the increased rates of Fe(III) reduction and Fe(II) oxidation, the Tc(VII) reduction rate also increased with redox cycles and could be explained by progressive increase of the reactive Fe(II) on NAu-2 surface/edges. These results suggest that iron-rich clay minerals undergo important changes after redox cycles, but eventually reach a steady state with continued reactivity toward heavy metals.

Yang, Junjie; Kukkadapu, Ravi K.; Dong, Hailiang; Shelobolina, Evgenya S.; Zhang, Jing; Kim, Jinwook

2012-01-06T23:59:59.000Z

208

The Integration of a Structural Water-Gas-Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 The InTegraTIon of a STrucTural WaTer- gaS-ShIfT caTalyST WITh a VanadIum alloy hydrogen TranSporT deVIce Description The purpose of this project is to produce a scalable device that simultaneously performs both water-gas-shift (WGS) and hydrogen separation from a coal-derived synthesis gas stream. The justification of such a system is the improved efficiency for the overall production of hydrogen. Removing hydrogen from the synthesis gas (syngas) stream allows the WGS reaction to convert more carbon monoxide (CO) to carbon dioxide (CO 2 ) and maximizes the total hydrogen produced. An additional benefit is the reduction in capital cost of plant construction due to the removal of one step in the process by integrating WGS with the membrane separation device.

209

Enhanced electrical and noise properties of nanocomposite vanadium oxide thin films by reactive pulsed-dc magnetron sputtering  

SciTech Connect

Thin films of VO{sub x} (1.3 {<=} x {<=} 2) were deposited by reactive pulsed-dc magnetron sputtering of a vanadium metal target while RF-biasing the substrate. Rutherford back scattering, glancing angle x-ray, and cross-sectional transmission electron microscopy measurements revealed the formation of nanocolumns with nanotwins within VO{sub x} samples. The resistivity of nanotwinned VO{sub x} films ranged from 4 m{Omega}{center_dot}cm to 0.6 {Omega}{center_dot}cm and corresponding temperature coefficient of resistance between -0.1% and -2.6% per K, respectively. The 1/f electrical noise was analyzed in these VO{sub x} samples using the Hooge-Vandamme relation. These VO{sub x} films are comparable or surpass commercial VO{sub x} films deposited by ion beam sputtering.

Basantani, H. A.; Kozlowski, S. [Department of Engineering Sciences and Mechanics, Penn State University, University Park, Pennsylvania 16802 (United States); Lee, Myung-Yoon [Department of Electrical Engineering, Penn State University, University Park, Pennsylvania 16802 (United States); Li, J.; Dickey, E. C. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Jackson, T. N. [Department of Electrical Engineering, Penn State University, University Park, Pennsylvania 16802 (United States); Materials Research Institute, Penn State University, University Park, Pennsylvania 16802 (United States); Bharadwaja, S. S. N. [Materials Research Institute, Penn State University, University Park, Pennsylvania 16802 (United States); Horn, M. [Department of Engineering Sciences and Mechanics, Penn State University, University Park, Pennsylvania 16802 (United States); Materials Research Institute, Penn State University, University Park, Pennsylvania 16802 (United States)

2012-06-25T23:59:59.000Z

210

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vanadium Redox Flow Battery Vanadium Redox Flow Battery Using Mixed Acid Electrolytes November 2, 2010 US DOE Energy Storage Systems (ESS) Program Review Washington DC Liyu Li, Soowhan Kim, Wei Wang, M. Vijayakumar, Zimin Nie, Baowei Chen, Jianlu Zhang, Jianzhi Hu, Gordon Graff, Jun Liu, Gary Yang * Funded by the Energy Storage Systems Program of the U.S. Department Of Energy through Pacific Northwest National Laboratories Redox Flow Battery (RFB)  A redox flow battery is a promising technology for large scale energy storage . Potential RFB Systems -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 Standard potential (V) of redox couples H 2 evolution O 2 evolution V 3+ /V 2+ VO 2 + /VO 2+ VO 2+ /V 3+ Fe 3+ /Fe 2+ Mn 3+ /Mn 2+ MnO 4 - /MnO 2 Ce 4+ /Ce 3+ Co 3+ /Co 2+ Cu 2+ /Cu + TiOH 3+ /Ti 3+ Ti 3+ /Ti 2+ Cr 3+ /Cr 2+ Zn 2+ /Zn

211

flow_measurements_cryogenic  

Science Conference Proceedings (OSTI)

... A dynamic weighing system is used to measure ... using liquid nitrogen at flow rates of 1 ... For volumetric flow rate measurement, the uncertainty in fluid ...

2013-06-17T23:59:59.000Z

212

Multiphase flow calculation software  

DOE Patents (OSTI)

Multiphase flow calculation software and computer-readable media carrying computer executable instructions for calculating liquid and gas phase mass flow rates of high void fraction multiphase flows. The multiphase flow calculation software employs various given, or experimentally determined, parameters in conjunction with a plurality of pressure differentials of a multiphase flow, preferably supplied by a differential pressure flowmeter or the like, to determine liquid and gas phase mass flow rates of the high void fraction multiphase flows. Embodiments of the multiphase flow calculation software are suitable for use in a variety of applications, including real-time management and control of an object system.

Fincke, James R. (Idaho Falls, ID)

2003-04-15T23:59:59.000Z

213

Multiphase Flow Modeling Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Chris Guenther, Director Computational Science Division RUA Spring Meeting, Morgantown, WV March 2013 2 NETL's Multiphase Flow Science Team * The Multiphase Flow Science...

214

Redox Reactions of Metalloporphyrins and their Role in Catalyzed Reduction of Carbon Dioxide  

Science Conference Proceedings (OSTI)

Pulse radiolysis and laser photolysis are used to study redox processes of metalloporphyrins and related complexes in order to evaluate these light absorbing molecules as sensitizers and intermediates in solar energy conversion schemes. The main thrust of the current studies is to investigate the role of reduced metalloporphyrins as intermediates in the catalyzed reduction of carbon dioxide. Studies involve cobalt and iron porphyrins, phthalocyanines, corroles, and corrins as homogeneous catalysts for reduction of carbon dioxide in solution. The main aim is to understand the mechanisms of these photochemical schemes in order to facilitate their potential utilization.

Neta, P.

2002-09-01T23:59:59.000Z

215

The influence of thallium on the redox reaction CrT /CrS  

Science Conference Proceedings (OSTI)

Investigations on the kinetics and electrocatalysis of the CrT /CrS reaction were carried out. By means of cyclic voltammetry, it was discovered that the addition of thallium-I-chloride not only accelerates the CrT /CrS reaction in HC1 electrolytes catalytically, using graphite electrodes with small amounts of Au, but also raises th hydrogen overvoltage more than lead and bismuth, the heavy metal catalysts already tested in the practical redox cells. Investigations concerning the reaction rate, the influence of chrome ion concentrations, the electrolyte storage time, temperature, and the presence of iron are being conducted.

Cheng, D. Sh.; Hollax, E.

1985-02-01T23:59:59.000Z

216

Portable wastewater flow meter  

DOE Patents (OSTI)

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under fill pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1999-02-02T23:59:59.000Z

217

Portable wastewater flow meter  

DOE Patents (OSTI)

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under full pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1990-01-01T23:59:59.000Z

218

Redox-dependent structure change and hyperfine nuclear magnetic resonance shifts in cytochrome c  

SciTech Connect

Proton nuclear magnetic resonance assignments for reduced and oxidized equine cytochrome c show that many individual protons exhibit different chemical shifts in the two protein forms, reflecting diamagnetic shift effects due to structure change, and in addition contact and pseudocontact shifts that occur only in the paramagnetic oxidized form. To evaluate the chemical shift differences for structure change, the authors removed the pseudocontact shift contribution by a calculation based on knowledge of the electron spin g tensor. The g-tensor calculation, when repeated using only 12 available C{sub {alpha}}H proton resonances for cytochrom c from tuna, proved to be remarkably stable. The derived g tensor was then used together with spatial coordinates for the oxidized form to calculate the pseudocontact shift contribution to proton resonances at 400 identifiable sites throughout the protein, so that the redox-dependent chemical shift discrepancy, could be evaluated. Large residual changes in chemical shift define the Fermi contact shifts, where are found as expected to be limited to the immediate covalent structure of the heme and its ligands and to be asymmetrically distributed over the heme. The chemical shift discrepancies observed appear in the main to reflect structure-dependent diamagnetic shifts rather than hyperfine effects due to displacements in the pseudocontact shift field. Although 51 protons in 29 different residues exhibit significant chemical shift changes, the general impressions one of small structural adjustments to redox-dependent strain rather than sizeable structural displacements or rearrangements.

Feng, Yiquing; Roder, H.; Englander, S.W. (Univ. of Pennsylvania, Philadelphia (USA))

1990-04-10T23:59:59.000Z

219

Redox Active Layer-by-Layer Structures containing MnO2 Nanoparticles  

Science Conference Proceedings (OSTI)

Nanoscale materials provide unique properties that will enable new technologies and enhance older ones. One area of intense activity in which nanoscale materials are being used is in the development of new functional materials for battery applications. This effort promises superior materials with properties that circumvent many of the problems associated with traditional battery materials. Previously we have worked on several approaches for using nanoscale materials for application as cathode materials in rechargeable Li batteries. Our recent work has focused on synthesizing MnO2 nanoparticles and using these in layer-by-layer (LbL) structures to probe the redox properties of the nanoparticles. We show that the aqueous colloidal nanoparticles produced by butanol reduction of tetramethylammonium permanganate can be trapped in thin films using a layer-by-layer deposition approach, and that these films are both redox active and exhibit kinetically facile electrochemical responses. We show cyclic voltammetry of MnO2 colloidal nanoparticles entrapped in a LbL thin film at an ITO electrode surface using poly(diallyldimethylammonium chloride) (PDDA). CV experiments demonstrate that Li+ insertion accompanies Mn(IV) reduction in LiClO4 supporting electrolytes, and that reduction is hindered in supporting electrolytes containing only tetrabutylammonium cations. We also show that electron propagation through multilayer films is facile, suggesting that electrons percolate through the films via electron exchange between nanoparticles.

Bazito, Fernanda; O'Brien, Robert; Buttry, Daniel A.

2005-02-01T23:59:59.000Z

220

Unsteady flow volumes  

SciTech Connect

Flow volumes are extended for use in unsteady (time-dependent) flows. The resulting unsteady flow volumes are the 3 dimensional analog of streamlines. There are few examples where methods other than particle tracing have been used to visualize time varying flows. Since particle paths can become convoluted in time there are additional considerations to be made when extending any visualization technique to unsteady flows. We will present some solutions to the problems which occur in subdivision, rendering, and system design. We will apply the unsteady flow volumes to a variety of field types including moving multi-zoned curvilinear grids.

Becker, B.G.; Lane, D.A.; Max, N.L.

1995-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

JOM: The Member Journal of TMS - JOM Monthly  

Science Conference Proceedings (OSTI)

Mar 18, 2011 ... Though considered a promising large-scale energy storage device, the vanadium redox battery's use has been limited by its high cost and ...

222

Full Size Image - Energy Innovation Portal  

A schematic of an upgraded vanadium redox batter shows how using both hydrochloric and sulfuric acids in the electrolyte significantly improves the ...

223

CX-006145: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination The Painesville Municipal Power Vanadium Redox Battery Demonstration Program CX(s) Applied: B3.6 Date: 07142011 Location(s): Painesville,...

224

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Painesville Municipal Power Vanadium Redox Battery Demonstration Project Joseph F. Startari Ashlawn Energy Funded in part by the Energy Storage Systems Program of the U.S....

225

Preparation and discharge characteristics of solid redox polymerization electrodes employing disulfide polymers and copolymers  

Science Conference Proceedings (OSTI)

Recent work in our laboratory on polymeric organodisulfides has shown these materials to perform well as positive electrodes in solid-state batteries. The polymeric materials have been named solid redox polymerization electrodes (SRPE's) due to the reversible polymerization/depolymerization reaction that occurs on charge/discharge of the electrode. The cell radiation for SRPE-based cells can be described for a simple case as, 2n M + (SRS){sub n} = n M{sub 2}SRS, where M is an alkali metal (Li, Na, K) and R is an organic group. In the broader sense SRPE's can have more than two S groups per monomer R unit, and are reversible to other monovalent and divalent metals. In the fully charged state SRPE's consist of polydisulfide polymers and are depolymerized on discharge by scission of sulfur-sulfur bonds, leading to the formation of dithiolate salts in the fully discharged cell. SRPE's are easy to synthesize, are air stable, and should be very inexpensive in bulk quantities. Depending on the redox potential of the polydisulfide and reaction condition, many disulfides can be copolymerized by oxidizing a mixture of dithiols, x HSRSH + y HSR'SH + (x+y)l{sub 2} = (SRS){sub x}(Sr'S){sub y} + 2(x+y) Hl, allowing modification of the physical and/or redox properties of the SRPE's. A series of simple aliphatic dithiols including (HSCH{sub 2}CH{sub 2}SH), (HSCH{sub 2}CH{sub 2}OCH{sub 2}CH{sub 2}SH), and (HSCH{sub 2}CH{sub 2}SCH{sub 2}CH{sub 2}SH) have been oxidized to polydisulfides and mixtures of the dithiols have been copolymerized. All of the resulting polymers and copolymers were evaluated in solid-state lithium cells, with some of the new materials demonstrating high levels of performance. The utilization of available capacity in the positive electrode was observed to be independent of electrode thickness for a number of SRPE's of loading levels up to 45% by weight. 8 refs., 5 figs. 2 tabs.

Lerner, M.M. (Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry); Visco, S.J.; Doeff, M.M.; Dejonghe, L.C. (Lawrence Berkeley Lab., CA (United States)); Ue, M. (Mitsubishi Petrochemical Co. Ltd., Tokyo (Japan))

1991-01-01T23:59:59.000Z

226

Structure of Offshore Flow  

Science Conference Proceedings (OSTI)

The horizontal and vertical structure of the mean flow and turbulent fluxes are examined using aircraft observations taken near a barrier island on the east coast of the United States during offshore flow periods. The spatial structure is ...

Dean Vickers; L. Mahrt; Jielun Sun; Tim Crawford

2001-05-01T23:59:59.000Z

227

Discovery of agglutinated benthic foraminifera in Devonian black shales and their relevance for the redox state of ancient seas  

E-Print Network (OSTI)

Discovery of agglutinated benthic foraminifera in Devonian black shales and their relevance Received in revised form 4 October 2008 Accepted 31 October 2008 Keywords: Black shale Redox Devonian. The discovery that they occur widely in Late Devonian black shales has a bearing on the boundary conditions

Polly, David

228

Ultrasonic flow metering system  

DOE Patents (OSTI)

A system for determining the density, flow velocity, and mass flow of a fluid comprising at least one sing-around circuit that determines the velocity of a signal in the fluid and that is correlatable to a database for the fluid. A system for determining flow velocity uses two of the inventive circuits with directional transmitters and receivers, one of which is set at an angle to the direction of flow that is different from the others.

Gomm, Tyler J. (Meridian, ID); Kraft, Nancy C. (Idaho Falls, ID); Mauseth, Jason A. (Pocatello, ID); Phelps, Larry D. (Pocatello, ID); Taylor, Steven C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

229

Redox Control For Hanford HLW Feeds VSL-12R2530-1, REV 0  

SciTech Connect

The principal objectives of this work were to investigate the effects of processing simulated Hanford HLW at the estimated maximum concentrations of nitrates and oxalates and to identify strategies to mitigate any processing issues resulting from high concentrations of nitrates and oxalates. This report provides results for a series of tests that were performed on the DM10 melter system with simulated C-106/AY-102 HLW. The tests employed simulated HLW feeds containing variable amounts of nitrates and waste organic compounds corresponding to maximum concentrations proj ected for Hanford HLW streams in order to determine their effects on glass production rate, processing characteristics, glass redox conditions, melt pool foaming, and the tendency to form secondary phases. Such melter tests provide information on key process factors such as feed processing behavior, dynamic effects during processing, processing rates, off-gas amounts and compositions, foaming control, etc., that cannot be reliably obtained from crucible melts.

Kruger, A. A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Kot, Wing K. [The Catholic University of America, Washington, DC (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States)

2012-12-13T23:59:59.000Z

230

Solar Thermochemical Fuels Production: Solar Fuels via Partial Redox Cycles with Heat Recovery  

SciTech Connect

HEATS Project: The University of Minnesota is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. The University of Minnesota is envisioning producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration. This new technology will allow for the effective use of vast domestic solar resources to produce precursors to synthetic fuels that could replace gasoline.

None

2011-12-19T23:59:59.000Z

231

Elbow mass flow meter  

SciTech Connect

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

1994-01-01T23:59:59.000Z

232

Neutral and Cationic Main Group Lewis Acids - Synthesis, Anion Complexation and Redox Properties  

E-Print Network (OSTI)

The primary goal of this research concerns the synthesis and characterization of hybrid main group Lewis acids. Initially, the focus of this work was on the synthesis of derivatives possessing unusual bonding interactions enforced by a rigid 1,8- naphthalenediyl scaffold. After discovering a route to a new dilithio reagent, silicon based derivatives featuring R3Si-F->CR3 + and R3C-H->SiFR3 interactions of 2.703(2) and 2.32(2) Angstrom respectively were successfully synthesized and fully characterized. Another hybrid Lewis acid based on the 1,8-naphthalenediyl scaffold that was studied was a trinuclear B2/Hg Lewis acid. This molecule has been shown to bind two fluoride anions sequentially, and the binding events can be followed by differential pulsed votammetry. The final part of this work concerns the reactivity and redox behavior of main group systems. It has been shown that the p-phenylene linker in 4-dimesitylboryl-1- diarylmethylium benzenes effectively reduces electrochemical communication between the carbocation and borane moieties when compared to systems without the linker. Reduction of these species produces a derivative whose EPR signal is only slightly influenced by the ^11 B center. These findings have been further substantiated by theoretical calculations. Finally, the redox properties of alpha-phosphonio- and alpha- phosphonyl-carbocations have been studied. Chemical reduction of both species leads to a predominately carbon centered radical with coupling to the ^31P center of 18 and 19.7 G respectively. The alpha-phosphonio carbocations, however, also undergo ligand exchange reactions with pyridine derivatives suggesting that these species can also be referred to as ligand stabilized carbodications.

Dorsey, Christopher L.

2009-05-01T23:59:59.000Z

233

Lateral flow strip assay  

DOE Patents (OSTI)

A lateral flow strip assay apparatus comprising a housing; a lateral flow strip in the housing, the lateral flow strip having a receiving portion; a sample collection unit; and a reagent reservoir. Saliva and/or buccal cells are collected from an individual using the sample collection unit. The sample collection unit is immersed in the reagent reservoir. The tip of the lateral flow strip is immersed in the reservoir and the reagent/sample mixture wicks up into the lateral flow strip to perform the assay.

Miles, Robin R. (Danville, CA); Benett, William J. (Livermore, CA); Coleman, Matthew A. (Oakland, CA); Pearson, Francesca S. (Livermore, CA); Nasarabadi, Shanavaz L. (Livermore, CA)

2011-03-08T23:59:59.000Z

234

Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report No. 9, April 1995--June 1995  

DOE Green Energy (OSTI)

This document is the ninth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities were focused on fine tuning of the microreactor system by elimination of transport effects and improvements in the analytical system. Process variable studies were conducted on vanadyl pyrophosphate and screening studies were conducted on several modified catalyst. One additional catalyst was prepared and characterization studies continued. These results are reported.

McCormick, R.L.

1995-09-14T23:59:59.000Z

235

Electrical current suppression in Pd-doped vanadium pentoxide nanowires caused by reduction in PdO due to hydrogen exposure  

SciTech Connect

Pd nanoparticle-doped vanadium pentoxide nanowires (Pd-VONs) were synthesized. Electrical current suppression was observed when the Pd-VON was exposed to hydrogen gas, which cannot be explained by the work function changes mentioned in previous report such as Pd-doped carbon nanotubes and SnO{sub 2} nanowires. Using the x-ray photoelectron spectroscopy, we found that the reduction in PdO due to hydrogen exposure plays an important role in the current suppression of the Pd-VON.

Kim, Byung Hoon; Oh, Soon-Young; Yu, Han Young; Yun, Yong Ju; Kim, Yark Yeon; Hong, Won G. [Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Jeong, Hu Young; Lee, Jeong Yong [Department of Materials Science and Engineering, KAIST, Daejeon 305-701 (Korea, Republic of); Kim, Hae Jin [Korea Basic Science Institute, Daejeon 305-333 (Korea, Republic of)

2010-04-19T23:59:59.000Z

236

The strong reactions of Lewis-base noble-metals with vanadium and other acidic transition metals  

SciTech Connect

The noble metals often thought of as unreactive solids,react strongly with nearly 40% of the elements in the periodictable: group IIIB-VB transition metals, lanthanides, theactinides, and group IIIA-IVA non-transition metals. These strong reactions arise from increased bonding/electron transfer fromnonbonding electrons d electron pairs on the noble metal tovacant orbitals on V, etc. This effect is a generalized Lewis acid-base interaction. The partial Gibbs energy of V in the noblemetals has been measured as a function of concentration at a temperature near 1000C. Thermodynamics of the intermetallics are determined by ternary oxide equilibria, ternary carbide equilibria, and the high-temperature galvanic cell technique. These experimental methods use equilibrated solid composite mixtures in which grains of V oxides or of V carbides are interspersed with grains of V-NM(noble-metal) alloys. In equilibrium the activity of V in the oxide or the carbide equals the activity in the alloy. Consequently, the thermodynamics available in the literature for the V oxides and V carbides are reviewed. Test runs on the galvanic cell were attempted. The V oxide electrode reacts with CaF{sub 2}, ThO{sub 2}, YDT(0.85ThO{sub 2}-0.15YO{sub 1.5}), and LDT(0.85ThO{sub 2}- 0.15LaO{sub 1.5}) to interfere with the measured data observed toward the beginning of a galvanic cell experiment are the most accurate. The interaction of vanadium at infinite dilution in the noble-metals was determined.

Ebbinghaus, B.B.

1991-05-01T23:59:59.000Z

237

The strong reactions of Lewis-base noble-metals with vanadium and other acidic transition metals  

SciTech Connect

The noble metals often thought of as unreactive solids,react strongly with nearly 40% of the elements in the periodictable: group IIIB-VB transition metals, lanthanides, theactinides, and group IIIA-IVA non-transition metals. These strong reactions arise from increased bonding/electron transfer fromnonbonding electrons d electron pairs on the noble metal tovacant orbitals on V, etc. This effect is a generalized Lewis acid-base interaction. The partial Gibbs energy of V in the noblemetals has been measured as a function of concentration at a temperature near 1000C. Thermodynamics of the intermetallics are determined by ternary oxide equilibria, ternary carbide equilibria, and the high-temperature galvanic cell technique. These experimental methods use equilibrated solid composite mixtures in which grains of V oxides or of V carbides are interspersed with grains of V-NM(noble-metal) alloys. In equilibrium the activity of V in the oxide or the carbide equals the activity in the alloy. Consequently, the thermodynamics available in the literature for the V oxides and V carbides are reviewed. Test runs on the galvanic cell were attempted. The V oxide electrode reacts with CaF[sub 2], ThO[sub 2], YDT(0.85ThO[sub 2]-0.15YO[sub 1.5]), and LDT(0.85ThO[sub 2]- 0.15LaO[sub 1.5]) to interfere with the measured data observed toward the beginning of a galvanic cell experiment are the most accurate. The interaction of vanadium at infinite dilution in the noble-metals was determined.

Ebbinghaus, B.B.

1991-05-01T23:59:59.000Z

238

Solids mass flow determination  

DOE Patents (OSTI)

Method and apparatus for determining the mass flow rate of solids mixed with a transport fluid to form a flowing mixture. A temperature differential is established between the solids and fluid. The temperature of the transport fluid prior to mixing, the temperature of the solids prior to mixing, and the equilibrium temperature of the mixture are monitored and correlated in a heat balance with the heat capacities of the solids and fluid to determine the solids mass flow rate.

Macko, Joseph E. (Hempfield Township, Westmoreland County, PA)

1981-01-01T23:59:59.000Z

239

Turbulent flow in graphene  

E-Print Network (OSTI)

We demonstrate the possibility of a turbulent flow of electrons in graphene in the hydrodynamic region, by calculating the corresponding turbulent probability density function. This is used to calculate the contribution of the turbulent flow to the conductivity within a quantum Boltzmann approach. The dependence of the conductivity on the system parameters arising from the turbulent flow is very different from that due to scattering.

Kumar S. Gupta; Siddhartha Sen

2009-11-03T23:59:59.000Z

240

Multiple sort flow cytometer  

DOE Patents (OSTI)

A flow cytometer utilizes multiple lasers for excitation and respective fluorescence of identified dyes bonded to specific cells or events to identify and verify multiple events to be sorted from a sheath flow and droplet stream. Once identified, verified and timed in the sheath flow, each event is independently tagged upon separation from the flow by an electrical charge of +60, +120, or +180 volts and passed through oppositely charged deflection plates with ground planes to yield a focused six way deflection of at least six events in a narrow plane.

Van den Engh, Ger (Seattle, WA); Esposito, Richard J. (Seattle, WA)

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Droplet Laden Flow Data  

Science Conference Proceedings (OSTI)

... Flow Past a Heated Cylinder, Atomization and Sprays, 2006, 16(6 ... Numerical Modeling and Experimental Measurements of Water Spray Impact and ...

2013-07-15T23:59:59.000Z

242

Black String Flow  

E-Print Network (OSTI)

We give an exact description of the steady flow of a black string into a planar horizon. The event horizon is out of equilibrium and provides a simple, exact instance of a `flowing black funnel' in any dimension D>=5. It is also an approximation to a smooth intersection between a black string and a black hole, in the limit in which the black hole is much larger than the black string thickness. The construction extends easily to more general flows, in particular charged flows.

Emparan, Roberto

2013-01-01T23:59:59.000Z

243

Visualization of Fluid Flow  

Science Conference Proceedings (OSTI)

... Goujon and J. Devaney, Large Scale Simulations of Single and Multi- Component Flow in Porous Media in Proceedings of SPIE: The International ...

2010-12-15T23:59:59.000Z

244

Microbially-Enhanced Redox Solution Reoxidation for Sour Natural Gas Sweetening  

DOE Green Energy (OSTI)

The specific objective of this project are to advance the technology and improve the economics of the commercial iron-based chelate processes such as LO-CAT II and SulFerox process utilizing biologically enhanced reoxidation of the redox solutions used in these processes. The project is based on the use of chelated ferric iron as the catalyst for the production of elemental sulfur, and then oxidizing bacteria, such as Thiobacillus Ferrooxidans (ATCC 23270) as an oxidizer. The regeneration of Fe{sup 3+} - chelate is accomplished by the use of these same microbes under mild conditions at 25-30 C and at atmospheric pressure to minimize the chelate degradation process. The pH of the redox solution was observed to be a key process parameter. Other parameters such as temperature, total iron concentration, gas to liquid ratio and bacterial cell densities also influence the overall process. The second part of this project includes experimental data and a kinetic model of microbial H{sub 2}S removal from sour natural gas using thiobacillus species. In the experimental part, a series of experiments were conducted with a commercial chelated iron catalyst at pH ranges from 8.7 to 9.2 using a total iron concentration range from 925 ppm to 1050 ppm in the solution. Regeneration of the solution was carried out by passing air through the solution. Iron oxidizing bacteria were used at cell densities of 2.3 x 10{sup 7}cells/ml for optimum effective performance. In the modeling part, oxidation of Fe{sup 2+} ions by the iron oxidizing bacteria - Thiobacillus Ferrooxidans was studied for application to a continuous stirred tank reactor (CSTR). The factors that can directly affect the oxidation rate such as dilution rate, temperature, and pH were analyzed. The growth of the microorganism was assumed to follow Monod type of growth kinetics. Dilution rate had influence on the rate of oxidation of ferrous iron. Higher dilution rates caused washout of the biomass. The oxidation rate was highly pH sensitive. Specific growth is a function of pH of the both. The specific growth rate had a maximum value at around 2.2. A dynamic model for a packed bed fluid reactor is also developed and simulated. A feedback control loop is proposed to control the production under feed disturbances.

Kenneth Brezinsky

2008-01-15T23:59:59.000Z

245

Stability of uranium incorporated into Fe(hydr)oxides under fluctuating redox conditions  

SciTech Connect

Reaction pathways resulting in uranium bearing solids that are stable (i.e., having limited solubility) under both aerobic and anaerobic conditions will limit dissolved concentrations and migration of this toxin. Here we examine the sorption mechanism and propensity for release of uranium reacted with Fe (hydr)oxides under cyclic oxidizing and reducing conditions. Upon reaction of ferrihydrite with Fe(II) under conditions where aqueous Ca-UO{sub 2}-CO{sub 3} species predominate (3 mM Ca and 3.8 mM CO{sub 3}-total), dissolved uranium concentrations decrease from 0.16 mM to below detection limit (BDL) after 5 to 15 d, depending on the Fe(II) concentration. In systems undergoing 3 successive redox cycles (15 d of reduction followed by 5 d of oxidation) and a pulsed decrease to 0.15 mM CO{sub 3}-total, dissolved uranium concentrations varied depending on the Fe(II) concentration during the initial and subsequent reduction phases - U concentrations resulting during the oxic 'rebound' varied inversely with the Fe(II) concentration during the reduction cycle. Uranium removed from solution remains in the oxidized form and is found both adsorbed on and incorporated into the structure of newly formed goethite and magnetite. Our 15 results reveal that the fate of uranium is dependent on anaerobic/aerobic conditions, aqueous uranium speciation, and the fate of iron.

Stewart, B.D.; Nico, P.S.; Fendorf, S.

2009-04-01T23:59:59.000Z

246

Remediating explosive-contaminated groundwater by in situ redox manipulation (ISRM) of aquifer sediments  

Science Conference Proceedings (OSTI)

In situ chemical reduction of clays and iron oxides in subsurface environments is an emerging technology for treatment of contaminated groundwater. Our objective was to determine the efficacy of dithionite-reduced sediments from the perched Pantex Aquifer (Amarillo, TX) to abiotically degrade the explosives RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), HMX (octahydro-1,3,5,7-tetranitro- 1,3,5,7-tetrazocine), and TNT (2,4,6-trinitrotoluene). The effects of dithionite/buffer concentrations, sediments-solution ratios, and the contribution of Fe(II) were evaluated in batch experiments. Results showed that reduced Pantex sediments were highly effective in degrading all three high explosives. Degradation rates increased with increasing dithionite/buffer concentrations and soil to solution ratios (1:80–1:10 w/v). When Fe(II) was partially removed from the reduced sediments by washing (citrate-bicarbonate buffer), RDX degradation slowed, but degradation efficiency could be restored by adding Fe(II) back to the treated sediments and maintaining an alkaline pH. These data support in situ redox manipulation as a remedial option for treating explosive-contaminated groundwater at the Pantex site.

Boparai, Hardiljeet K.; Comfort, Steve; Shea, Phyllis J.; Szecsody, James E.

2008-03-01T23:59:59.000Z

247

Alterations in mitochondrial respiratory functions, redox metabolism and apoptosis by oxidant 4-hydroxynonenal and antioxidants curcumin and melatonin in PC12 cells  

Science Conference Proceedings (OSTI)

Cellular oxidative stress and alterations in redox metabolisms have been implicated in the etiology and pathology of many diseases including cancer. Antioxidant treatments have been proven beneficial in controlling these diseases. We have recently shown that 4-hydroxynonenal (4-HNE), a by-product of lipid peroxidation, induces oxidative stress in PC12 cells by compromising the mitochondrial redox metabolism. In this study, we have further investigated the deleterious effects of 4-HNE on mitochondrial respiratory functions and apoptosis using the same cell line. In addition, we have also compared the effects of two antioxidants, curcumin and melatonin, used as chemopreventive agents, on mitochondrial redox metabolism and respiratory functions in these cells. 4-HNE treatment has been shown to cause a reduction in glutathione (GSH) pool, an increase in reactive oxygen species (ROS), protein carbonylation and apoptosis. A marked inhibition in the activities of the mitochondrial respiratory enzymes, cytochrome c oxidase and aconitase was observed after 4-HNE treatment. Increased nuclear translocation of NF-kB/p65 protein was also observed after 4-HNE treatment. Curcumin and melatonin treatments, on the other hand, maintained the mitochondrial redox and respiratory functions without a marked effect on ROS production and cell viability. These results suggest that 4-HNE-induced cytotoxicity may be associated, at least in part, with the altered mitochondrial redox and respiratory functions. The alterations in mitochondrial energy metabolism and redox functions may therefore be critical in determining the difference between cell death and survival.

Raza, Haider [Department of Biochemistry, Faculty of Medicine and Health Sciences, UAE University, POBox 17666, Al Ain (United Arab Emirates)], E-mail: h.raza@uaeu.ac.ae; John, Annie [Department of Biochemistry, Faculty of Medicine and Health Sciences, UAE University, POBox 17666, Al Ain (United Arab Emirates); Brown, Eric M. [Department of Anatomy, FMHS, Al Ain, UAE University (United Arab Emirates); Benedict, Sheela [Department of Internal Medicine, FMHS, Al Ain, UAE University (United Arab Emirates); Kambal, Amr [Tawam Hospital/Johns Hopkins Medicine International, Al Ain (United Arab Emirates)

2008-01-15T23:59:59.000Z

248

Capabilities for information flow  

Science Conference Proceedings (OSTI)

This paper presents a capability-based mechanism for permissive yet secure enforcement of information-flow policies. Language capabilities have been studied widely, and several popular implementations, such as Caja and Joe-E, are available. By making ... Keywords: capabilities, information flow control

Arnar Birgisson; Alejandro Russo; Andrei Sabelfeld

2011-06-01T23:59:59.000Z

249

Elbow mass flow meter  

DOE Patents (OSTI)

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16T23:59:59.000Z

250

Degradation of yttria-stabilized zirconia thermal barrier coatings by vanadium pentoxide, phosphorous pentoxide, and sodium sulfate  

Science Conference Proceedings (OSTI)

The presence of vanadium, phosphorus, and sodium impurities in petcoke and coal/petcoke blends used in integrated gasification combined cycle (IGCC) plants warrants a clear understanding of high-temperature material degradation for the development of fuel-flexible gas turbines. In this study, degradation reactions of free-standing air plasma-sprayed (APS) yttria-stabilized zirconia (YSZ) in contact with V{sub 2}O{sub 5}, P{sub 2}O{sub 5}, and Na{sub 2}SO{sub 4} were investigated at temperatures up to 1200{sup o}C. Phase transformations and microstructural development were examined using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Molten V{sub 2}O{sub 5} reacted with solid YSZ to form ZrV{sub 2}O{sub 7} at temperatures below 747{sup o}C. However, at temperatures above 747{sup o}C, molten V{sub 2}O{sub 5} reacted with YSZ to form yttrium vanadate (YVO{sub 4}). The formation of YVO{sub 4} led to the depletion of the Y2O{sub 3} stabilizer and deleterious transformation to the monoclinic ZrO{sub 2} phase. In addition, studies on YSZ degradation by Na{sub 2}SO{sub 4} and a Na{sub 2}SO{sub 4}+V{sub 2}O{sub 5} mixture (50-50 mol%) showed that Na{sub 2}SO{sub 4} itself had no effect on the degradation of YSZ. However, in the presence of V{sub 2}O{sub 5} at high temperatures, Na{sub 2}SO{sub 4} forms vanadate compounds having a lower melting point such as sodium metavanadate (610{sup o}C), which was found to degrade YSZ by the formation of YVO{sub 4} at a relatively lower temperature of 700{sup o}C. P{sub 2}O{sub 5} was found to react with APS YSZ by the formation of ZrP{sub 2}O{sub 7} at all the temperatures studied. At temperatures as low as 200{sup o}C and as high as 1200{sup o}C, molten P{sub 2}O{sub 5} was observed to react with solid YSZ to yield ZrP{sub 2}O{sub 7}, which led to the depletion of ZrO{sub 2} in YSZ that promoted the formation of the fluorite-cubic ZrO{sub 2} phase.

Mohan, P.; Yuan, B.; Patterson, T.; Desai, V.H.; Sohn, Y.H. [University of Central Florida, Orlando, FL (United States)

2007-11-15T23:59:59.000Z

251

Coupled modeling of groundwater flow solute transport, chemical reactions and microbial processes in the 'SP' island  

Science Conference Proceedings (OSTI)

The Redox Zone Experiment was carried out at the Aespoe HRL in order to study the redox behavior and the hydrochemistry of an isolated vertical fracture zone disturbed by the excavation of an access tunnel. Overall results and interpretation of the Redox Zone Project were reported by /Banwart et al, 1995/. Later, /Banwart et al, 1999/ presented a summary of the hydrochemistry of the Redox Zone Experiment. Coupled groundwater flow and reactive transport models of this experiment were carried out by /Molinero, 2000/ who proposed a revised conceptual model for the hydrogeology of the Redox Zone Experiment which could explain simultaneously measured drawdown and salinity data. The numerical model was found useful to understand the natural system. Several conclusions were drawn about the redox conditions of recharge waters, cation exchange capacity of the fracture zone and the role of mineral phases such as pyrite, calcite, hematite and goethite. This model could reproduce the measured trends of dissolved species, except for bicarbonate and sulfate which are affected by microbially-mediated processes. In order to explore the role of microbial processes, a coupled numerical model has been constructed which accounts for water flow, reactive transport and microbial processes. The results of this model is presented in this report. This model accounts for groundwater flow and reactive transport in a manner similar to that of /Molinero, 2000/ and extends the preliminary microbial model of /Zhang, 2001/ by accounting for microbially-driven organic matter fermentation and organic matter oxidation. This updated microbial model considers simultaneously the fermentation of particulate organic matter by yeast and the oxidation of dissolved organic matter, a product of fermentation. Dissolved organic matter is produced by yeast and serves also as a substrate for iron-reducing bacteria. Model results reproduce the observed increase in bicarbonate and sulfate concentration, thus adding additional evidence for the possibility of organic matter oxidation as the main source of bicarbonate. Model results indicate that pH and Eh are relatively stable. The dissolution-precipitation trends of hematite, pyrite and calcite also coincide with those indicated by the conceptual model. A thorough sensitivity analysis has been performed for the most relevant microbial parameters as well as for initial and boundary POC and DOC concentrations. The results of such analysis indicate that computed concentrations of bicarbonate, sulfate and DOC are sensitive to most of the microbial parameters, including specific growth rates, half-saturation constants, proportionality coefficients and yield coefficients. Model results, however, are less sensitive to the yield coefficient of DOC to iron-reducer bacteria. The sensitivity analysis indicates that changes in fermentation microbial parameters affect the growth of the iron-reducer, thus confirming the interconnection of both microbial processes. Computed concentrations of bicarbonate and sulfate are found to be sensitive to changes in the initial concentration of POC and the boundary concentration of DOC, but they lack sensitivity to the initial concentration of DOC and the boundary concentration of POC. The explanation for such result is related to the fact that POC has a low mobility due to its large molecular weight. DOC, however, can migrate downwards. Although a coupled hydro-bio-geochemical 1-D model can reproduce the observed ''unexpected'' increase of concentrations of bicarbonate and sulfate at a depth of 70 m, further modeling work is required in order to obtain a similar conclusion under the more realistic two dimensional conditions of the fracture zone.

Samper, Javier; Molinero, Jorg; Changbing, Yang; Zhang, Guoxiang

2003-12-01T23:59:59.000Z

252

Electron Transfer Reactivity Patterns at Chemically Modified Electrodes: Fundamentals and Application to the Optimization of Redox Recycling Amplification Systems  

SciTech Connect

Electroanalytical chemistry is often utilized in chemical analysis and Fundamental studies. Important advances have been made in these areas since the advent of chemically modified electrodes: the coating of an electrode with a chemical film in order to impart desirable, and ideally, predictable properties. These procedures enable the exploitation of unique reactivity patterns. This dissertation presents studies that investigate novel reaction mechanisms at self-assembled monolayers on gold. In particular, a unique electrochemical current amplification scheme is detailed that relies on a selective electrode to enable a reactivity pattern that results in regeneration of the analyte (redox recycling). This regenerating reaction can occur up to 250 times for each analyte molecule, leading to a notable enhancement in the observed current. The requirements of electrode selectivity and the resulting amplification and detection limit improvements are described with respect to the heterogeneous and homogeneous electron transfer rates that characterize the system. These studies revealed that the heterogeneous electrolysis of the analyte should ideally be electrochemically reversible, while that for the regenerating agent should be held to a low level. Moreover, the homogeneous reaction that recycles the analyte should occur at a rapid rate. The physical selectivity mechanism is also detailed with respect to the properties of the electrode and redox probes utilized. It is shown that partitioning of the analyte into/onto the adlayer leads to the extraordinary selectivity of the alkanethiolate monolayer modified electrode. Collectively, these studies enable a thorough understanding of the complex electrode mechanism required for successful redox recycling amplification systems, Finally, in a separate (but related) study, the effect of the akyl chain length on the heterogeneous electron transfer behavior of solution-based redox probes is reported, where an odd-even oscillation (with respect to the number of methylene units in the alkyl chain) was observed. Characterization of the adlayers by infrared reflection spectroscopy, ellipsometry, and wetting revealed odd-even effects in the orientation of the terminal methyl group and hydrophobic character of the adlayers. Using these structural characterizations as a basis, several possible mechanisms that can account for the odd-even effect in the heterogeneous electron transfer rates of solution-based redox couples are discussed.

Adam Johan Bergren

2006-05-01T23:59:59.000Z

253

ESS 2012 Peer Review - Advanced Materials for Flow Batteries - Travis Anderson, SNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Materials for Advanced Materials for Flow Batteries Friday, September 28, 2012 Travis M. Anderson and Harry D. Pratt III Sandia National Laboratories Ionic Liquid Flow Batteries MetIL - + MetIL * 59 mV/n separation (ideally n > 1) * Viscosity < 500 cP * Conductivity > 0.5 mS cm -1 * Open Circuit Potential > 1.5 V Problem: Getting high concentrations of redox active species. MetILs * Transition Metal Cation * Weakly Coordinating Anions * Alkanolamine Ligands * Negligible Vapor Pressure * Non-toxic 2 FY12 Milestones Approach: Design electrolytes with charge storage species as part of their chemical composition. Energy Density/Costs SNL APPROACH: Consider a compound CuL 2 BF 4 (L = methanolamine, MW = 47 g/mol), measured density 1.6 g/mL, formula weight,

254

Heat flow of Oregon  

DOE Green Energy (OSTI)

An extensive new heat flow and geothermal gradient data set for the State of Oregon is presented on a contour map of heat flow at a scale of 1:1,000,000 and is summarized in several figures and tables. The 1:1,000,000 scale heat flow map is contoured at 20 mW/m/sup 2/ (0.5 HFU) intervals. Also presented are maps of heat flow and temperature at a depth of 1 km averaged for 1/sup 0/ x 1/sup 0/ intervals. Histograms and averages of geothermal gradient and heat flow for the State of Oregon and for the various physiographic provinces within Oregon are also included. The unweighted mean flow for Oregon is 81.3 +- 2.7 mW/m/sup 2/ (1.94 +- 0.06 HFU). The average unweighted geothermal gradient is 65.3 +- 2.5/sup 0/C/km. The average heat flow value weighted on the basis of geographic area is 68 +- 5 mW/m/sup 2/ (1.63 +- 0.12 HFU) and the average weighted geothermal gradient is 55.0 +- 5/sup 0/C/km.

Blackwell, D.D.; Hull, D.A.; Bowen, R.G.; Steele, J.L.

1978-01-01T23:59:59.000Z

255

Multiphase Flow Modeling Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Science Chris Guenther, Director Computational Science Division RUA Spring Meeting, Morgantown, WV March 2013 2 NETL's Multiphase Flow Science Team * The Multiphase Flow Science Team develops physics-based simulation models to conduct applied scientific research. - Development of new theory - Extensive on-site and collaborative V&V efforts and testing - Engages in technology transfer - Applies the models to industrial scale problems. 3 Why is Multiphase Flow Science Needed? * Industry is increasingly relying on multiphase technologies to produce clean and affordable energy with carbon capture. * Unfortunately, the presence of a solid phase reduces the operating capacity of a typical energy device from its original design on average by 40% [1].

256

Shroud leakage flow discouragers  

SciTech Connect

A turbine assembly includes a plurality of rotor blades comprising a root portion, an airfoil having a pressure sidewall and a suction sidewall, and a top portion having a cap. An outer shroud is concentrically disposed about said rotor blades, said shroud in combination with said tip portions defining a clearance gap. At least one circumferential shroud leakage discourager is disposed within the shroud. The leakage discourager(s) increase the flow resistance and thus reduce the flow of hot gas flow leakage for a given pressure differential across the clearance gap to improve overall turbine efficiency.

Bailey, Jeremy Clyde (Middle Grove, NY); Bunker, Ronald Scott (Niskayuna, NY)

2002-01-01T23:59:59.000Z

257

RMOTC - Testing - Flow Assurance  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow Assurance Flow Assurance RMOTC Flow Loop Facility Layout Notice: As of July 15th 2013, the Department of Energy announced the intent to sell Naval Petroleum Reserve Number 3 (NPR3). The sale of NPR-3 will also include the sale of all equipment and materials onsite. A decision has been made by the Department of Energy to complete testing at RMOTC by July 1st, 2014. RMOTC will complete testing in the coming year with the currently scheduled testing partners. For more information on the sale of NPR-3 and sale of RMOTC equipment and materials please join our mailing list here. Over a decade ago, RMOTC began cooperatively building a full-scale facility to test new flow assurance technology, mainly in the areas of hydrates and paraffins. Today, RMOTC's test facility consists of five individual loop

258

Maple Sap Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

I know a little about this topic even though I am from Illinois which is far from the heart of maple syrup country. Sap flows from a maple tree by internal pressure caused by the...

259

Modons in Shear Flow  

Science Conference Proceedings (OSTI)

Modons in shear flow are computed as equilibrium solutions of the equivalent barotropic vorticity equation using a numerical Newton–Kantorovich iterative technique with double Fourier spectral expansion. The model is given a first guess of an ...

Sue Ellen Haupt; James C. McWilliams; Joseph J. Tribbia

1993-05-01T23:59:59.000Z

260

Stochastically scalable flow control  

Science Conference Proceedings (OSTI)

Recent advances in the mathematical analysis of flow control have prompted the creation of the Scalable TCP (STCP) and Exponential RED (E-RED) algorithms. These are designed to be scalable under the popular deterministic delay ...

Thomas Voice

2009-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

RG flows and instantons  

Science Conference Proceedings (OSTI)

In these two lectures I discuss RG flow solutions in (1,0) six dimensional supergravity involving SU(2) Yang-Mills instantons. in the conformally flat part of the 6D metric. The solutions interpolate between two (4,0) supersymmetric AdS{sub 3} Multiplication-Sign S{sup 3} backgrounds with different values of AdS{sub 3} and S{sup 3} radii and describe RG flows in the dual 2D SCFT. The flows described are of v.e.v. type, driven by a vacuum expectation value of a (not exactly) marginal operator of dimension 2 in the UV. We give an interpretation of the supergravity solution in terms of the D1/D5 system in type I string theory on K3, whose effective field theory is expected to flow to a (4,0) SCFT in the infrared.

Gava, Edi [INFN, Trieste (Italy)

2012-09-24T23:59:59.000Z

262

Parallel flow diffusion battery  

DOE Patents (OSTI)

A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

Yeh, Hsu-Chi (Albuquerque, NM); Cheng, Yung-Sung (Albuquerque, NM)

1984-08-07T23:59:59.000Z

263

Islands in Zonal Flow  

Science Conference Proceedings (OSTI)

The impact of a meridional gradient in sea surface temperature (warm toward the equator, cold toward the pole) on the circulation around an island is investigated. The upper-ocean eastward geostrophic flow that balances such a meridional gradient ...

Michael A. Spall

2003-12-01T23:59:59.000Z

264

Parallel flow diffusion battery  

DOE Patents (OSTI)

A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

Yeh, H.C.; Cheng, Y.S.

1984-01-01T23:59:59.000Z

265

Casting Flow Chart  

Science Conference Proceedings (OSTI)

Figure: ...Fig. 1 Simplified flow diagram of the basic operations for producing a steel casting. Similar diagrams can be applied to other ferrous and nonferrous alloys produced by sand

266

Three dimensional flow processor  

DOE Patents (OSTI)

The 3D-flow processor is a general purpose programmable data stream pipelined device that allows fast data movement in six directions for digital signal processing applications such as identifying objects in a matrix in a programmable form. The 3D-flow processor can be used in one dimensional, two dimensional, and three dimensional topologies capable of sustaining an input data rate of up to 100 million data (or frames) per second in a parallel processing system.

Crosetto, D.B.

1992-01-01T23:59:59.000Z

267

Increased Power Flow Guidebook  

Science Conference Proceedings (OSTI)

The Increased Power Flow (IPF) Guidebook is a state-of-the-art and best practices guidebook on increasing power flow capacities of existing overhead transmission lines, underground cables, power transformers, and substation equipment without compromising safety and reliability. The Guidebook discusses power system concerns and limiting conditions to increasing capacity, reviews available technology options and methods, illustrates alternatives with case studies, and analyzes costs and benefits of differe...

2005-11-16T23:59:59.000Z

268

Fluid Metrology Calibration Services - Water Flow  

Science Conference Proceedings (OSTI)

Fluid Metrology Calibration Services - Water Flow. Water Flow Calibrations 18020C. ... NIST provides calibration services for water flow meters. ...

2011-10-03T23:59:59.000Z

269

Advanced Flow-Battery Systems  

Science Conference Proceedings (OSTI)

Presentation Title, Advanced Flow-Battery Systems ... Abstract Scope, Flow- battery systems (FBS) were originally developed over 30 years ago and have since ...

270

Meridional Flow Field of Axisymmetric Flows in a Rotating Annulus  

Science Conference Proceedings (OSTI)

Measurements of the flow field were made of the axisymmetric flow in a differentially heated rotating fluid annulus by using a long-term tracking of a tracer particle. Its meridional flow profile is composed of a flow circulating in a large ...

T. Tajima; T. Nakamura

2000-09-01T23:59:59.000Z

271

Grafting onto wool. XX. Graft copolymerization of vinyl monomers by use of redox initiators. Comparison of monomer reactivities  

SciTech Connect

Methyl methacrylate (MMA) and ethylacrylate (EA) have been graft copolymerized onto Himachali wool in aqueous medium by using a ferrous ammonium sulfate-hydrogen peroxide (FAS-H/sub 2/O/sub 2/) system as redox initiator. Percentage of grafting has been determined as functions of concentration of monomer, molar ratio of (FAS)/(H/sub 2/O/sub 2/), time, and temperature. Percentage of grafting is found to depend upon the molar ratio of (FAS)/(H/sub 2/O/sub 2/). An attempt has been made to compare the reactivities of the acceptor monomer (MMA and EA) with that of the donor monomer (VAc) toward grafting onto wool.

Misra, B.N.; Singha, A.S.; Sharma, R.K.

1982-04-01T23:59:59.000Z

272

Formation flow channel blocking  

SciTech Connect

A method is claimed for selectively blocking high permeability flow channels in an underground hydrocarbon material bearing formation having flow channels of high permeability and having flow channels of lesser permeability. The method includes the following steps: introducing a blocking material fluid comprising a blocking material in a carrier into the flow channels through an injection well in communication with the formation; introducing a buffer fluid into the formation through the injection well for the buffer fluid to displace the blocking material fluid away from the injection well; allowing the blocking material to settle in the channels to resist displacement by fluid flowing through the channels; introducing a quantity of an activating fluid into the channels through the injection well at a sufficient rate for the activating fluid to displace the buffer fluid and finger into the high permeability channels to reach the blocking material in the high permeability channels without reaching the blocking material in the low permeability channels, the activating fluid being adapted to activate the blocking material which it reaches to cause blocking of the high permeability channels.

Kalina, A.I.

1982-11-30T23:59:59.000Z

273

Zirconium vanadium chromium alloy  

DOE Patents (OSTI)

A ternary intermetallic compound having the formula Zr(V/sub 1-x/Cr/sub x/)/sub 2/ where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200/sup 0/C, at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

Mendelsohn, M.H.; Gruen, D.M.

1980-10-14T23:59:59.000Z

274

Vanadium Dioxide Microactuators  

Berkeley Lab researchers Junqiao Wu, Kai Liu, and Kevin Wang have developed a powerful new microscale actuator that simultaneously achieves high ...

275

Molecular cloning and characterization of important stress and redox regulatory genes from Hydra vulgaris  

E-Print Network (OSTI)

In this research, important stress and redox regulatory genes present in Hydra vulgaris were isolated and characterized to facilitate our understanding of the evolution and mechanisms of stress response. H. vulgaris heat shock protein 70 (HvHSP70), extracellular copper zinc superoxide dismutase (HvECCuZnSOD), manganese superoxide dismutase (HvMnSOD), phospholipid peroxidase glutathione peroxidase (HvPHGPx) and monofunctional catalase (HvCatalase) were cloned and characterized with regard to stress response, phylogeny and molecular structure. The HSP70 gene isolated from H. vulgaris encodes a polypeptide of 650 amino acids (Mw=710,037) and is interrupted by three intron sequences. The 5' non-coding region of the HvHSP70 possessed the canonical heat shock elements. Phylogenetically HvHSP70 formed a distinct lineage. A molecular model generated for the N-terminal fragment of the HvHSP70 displayed the heat shock protein fold and domains of phosphotransferases. The EC-CuZnSOD cDNA isolated from H. vulgaris encodes a protein of 189 amino acids (Mw=20959.73); the first 19 amino acids constitute the presumed signal peptide. Phylogenetically HvEC-CuZnSOD is grouped with ECCuZnSODs from several organisms. A molecular model generated for the HvEC-CuZnSOD displayed the CuZnSOD (beta)-barrel fold. The MnSOD cDNA isolated from H. vulgaris encodes a protein of 219 amino acids (Mw=24348.75); the first 21 amino acids constitute the presumed mitochondria-targeting signal peptide. Phylogenetically HvMnSOD is clustered with mollusk and crustacean MnSODs. A molecular model generated for the HvMnSOD displayed the N-terminal long alpha antiparallel hairpin and the Cterminal mixed alpha/beta fold characteristic of MnSODs. The PHGPx gene isolated from H. vulgaris encodes a polypeptide of 168 amino acids (Mw=18746.51) including a TGA-encoded selenocysteine at residue 44 and lacks any intron. Phylogenetically HvPHGPx is grouped with PHGPxs from several organisms. A molecular model generated for the HvPHGPx displayed the thioredoxin fold. The 3'-end of a cDNA sequence encoding for 168 amino acids of the Cterminal end of a catalase was isolated from H. vulgaris. Phylogenetically HvCatalase is grouped with heme-containing monofunctional catalases. Hydrae exposed to thermal, starvation, oxidative and metal stress responded by regulating respective mRNA transcriptions suggesting that these genes are involved in stress and (anti)oxidative processes and may have potential as molecular biomarkers for assessing aquatic environment quality.

Dash, Bhagirathi

2005-12-01T23:59:59.000Z

276

Two-phase flow studies  

DOE Green Energy (OSTI)

The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow problems of relevance to the geothermal industry. An important feature of the facility is that it is dedicated to two-phase flow of a single substance (including evaporation and condensation) as opposed to the case of a two-component two-phase flow. This facility can be operated with horizontal or vertical test sections of constant diameter or with step changes in diameter to simulate a geothermal well profile.

Hanold, R.J.

1983-12-01T23:59:59.000Z

277

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry  

E-Print Network (OSTI)

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry using energy flow method Azimuthal angle distribution at Q2 >100 GeV2 Energy flow method.Ukleja on behalf of the ZEUS Collaboration #12; Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I

278

Flow Test | Open Energy Information  

Open Energy Info (EERE)

Flow Test Flow Test Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Flow Test Details Activities (38) Areas (33) Regions (1) NEPA(3) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Flow tests provide information on permeability, recharge rates, reservoir pressures, fluid chemistry, and scaling. Thermal: Flow tests can measure temperature variations with time to estimate characteristics about the heat source. Dictionary.png Flow Test: Flow tests are typically conducted shortly after a well has been drilled to test its productivity. The well is opened and fluids are released, the

279

Microwave fluid flow meter  

DOE Patents (OSTI)

A microwave fluid flow meter is described utilizing two spaced microwave sensors positioned along a fluid flow path. Each sensor includes a microwave cavity having a frequency of resonance dependent upon the static pressure of the fluid at the sensor locations. The resonant response of each cavity with respect to a variation in pressure of the monitored fluid is represented by a corresponding electrical output which can be calibrated into a direct pressure reading. The pressure drop between sensor locations is then correlated as a measure of fluid velocity. In the preferred embodiment the individual sensor cavities are strategically positioned outside the path of fluid flow and are designed to resonate in two distinct frequency modes yielding a measure of temperature as well as pressure. The temperature response can then be used in correcting for pressure responses of the microwave cavity encountered due to temperature fluctuations.

Billeter, Thomas R. (Richland, WA); Philipp, Lee D. (Richland, WA); Schemmel, Richard R. (Lynchburg, VA)

1976-01-01T23:59:59.000Z

280

Mass-Loaded Flows  

E-Print Network (OSTI)

A key process within astronomy is the exchange of mass, momentum, and energy between diffuse plasmas in many types of astronomical sources (including planetary nebulae, wind-blown bubbles, supernova remnants, starburst superwinds, and the intracluster medium) and dense, embedded clouds or clumps. This transfer affects the large scale flows of the diffuse plasmas as well as the evolution of the clumps. I review our current understanding of mass-injection processes, and examine intermediate-scale structure and the global effect of mass-loading on a flow. I then discuss mass-loading in a variety of diffuse sources.

J. M. Pittard

2006-07-13T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

2011-12-11T23:59:59.000Z

282

Flow cytometry apparatus  

DOE Patents (OSTI)

An obstruction across the flow chamber creates a one-dimensional convergence of a sheath fluid. A passageway in the obstruction directs flat cells near to the area of one-dimensional convergence in the sheath fluid to provide proper orientation of flat cells at fast rates. 6 figs.

Pinkel, D.

1987-11-30T23:59:59.000Z

283

Flow cytometry apparatus  

DOE Patents (OSTI)

An obstruction across the flow chamber creates a one dimensional convergence of a sheath fluid. A passageway in the construction directs flat cells near to the area of one dimensional convergence in the sheath fluid to provide proper orientation of flat cells at fast rates.

Pinkel, Daniel (Walnut Creek, CA)

1991-01-01T23:59:59.000Z

284

US energy flow, 1991  

SciTech Connect

Trends in energy consumption and assessment of energy sources are discussed. Specific topics discussed include: energy flow charts; comparison of energy use with 1990 and earlier years; supply and demand of fossil fuels (oils, natural gas, coal); electrical supply and demand; and nuclear power.

Borg, I.Y.; Briggs, C.K.

1992-06-01T23:59:59.000Z

285

Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites  

SciTech Connect

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan. • Characterizing the homogenized sample groups. • Performing parametric leaching testing on each group for compounds of interest. • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form of gibbsite, and its impact on filtration. The initial sample was diluted with a liquid simulant to simulate the receiving concentration of retrieved tank waste into the UFP2 vessel (< 10 wt% undissolved solids). Filtration testing was performed on the dilute waste sample and dewatered to a higher solids concentration. Filtration testing was then performed on the concentrated slurry. Afterwards, the slurry was caustic leached to remove aluminum present in the undissolved solid present in the waste. The leach was planned to simulate leaching conditions in the UFP2 vessel. During the leach, slurry supernate samples were collected to measure the dissolution rate of aluminum in the waste. After the slurry cooled down from the elevated leach temperature, the leach liquor was dewatered from the solids. The remaining slurry was rinsed and dewatered with caustic solutions to remove a majority of the dissolved aluminum from the leached slurry. The concentration of sodium hydroxide in the rinse solutions was high enough to maintain the solubility of the aluminum in the dewatered rinse solutions after dilution of the slurry supernate. Filtration tests were performed on the final slurry to compare to filtration performance before and after caustic leaching.

Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-03-02T23:59:59.000Z

286

Self-Organized Network Flows  

E-Print Network (OSTI)

A model for traffic flow in street networks or material flows in supply networks is presented, that takes into account the conservation of cars or materials and other significant features of traffic flows such as jam formation, spillovers, and load-dependent transportation times. Furthermore, conflicts or coordination problems of intersecting or merging flows are considered as well. Making assumptions regarding the permeability of the intersection as a function of the conflicting flows and the queue lengths, we find self-organized oscillations in the flows similar to the operation of traffic lights.

Helbing, D; Lämmer, S; Helbing, Dirk; Siegmeier, Jan; L\\"{a}mmer, Stefan

2007-01-01T23:59:59.000Z

287

Designing Axial Flow Fan for Flow and Noise  

E-Print Network (OSTI)

A comprehensive finite element methodology is developed to predict the compressible flow performance of a non-symmetric 7-blade axial flow fan, and to quantify the source strength and sound pressure levels at any location in the system. The acoustic and flow performances of the fan are predicted simultaneously using a computational aero-acoustic technique combining transient flow analysis and noise propagation. The calculated sound power levels compare favorably with the measured sound power data per AMCA 300-96 code.

Subrata Roy; Phillip Cho; Fred Périé; International Off-highway

1999-01-01T23:59:59.000Z

288

Lattice Boltzmann modeling of microchannel flow in slip flow regime  

Science Conference Proceedings (OSTI)

We present the lattice Boltzmann equation (LBE) with multiple relaxation times (MRT) to simulate pressure-driven gaseous flow in a long microchannel. We obtain analytic solutions of the MRT-LBE with various boundary conditions for the incompressible ... Keywords: Gas flow through microchannel, Lattice Boltzmann equation with multiple relaxation times, Slip flow

Frederik Verhaeghe; Li-Shi Luo; Bart Blanpain

2009-01-01T23:59:59.000Z

289

Modeling Turbulent Flow  

National Nuclear Security Administration (NNSA)

Turbulent Turbulent Flow with Implicit LES L.G. Margolin 1 Proceedings of the Joint Russian-American Five Laboratory Conference on Computational Mathematics/Physics 19-23 June, 2005 Vienna, Austria 1 Applied Physics Division, Los Alamos National Laboratory, Los Alamos, NM 87545, len@lanl.gov 1 Abstract Implicit large eddy simulation (ILES) is a methodology for modeling high Reynolds' num- ber flows that combines computational efficiency and ease of implementation with predictive calculations and flexible application. Although ILES has been used for more than fifteen years, it is only recently that significant effort has gone into providing a physical rationale that speaks to its capabilities and its limitations. In this talk, we will present new theoret- ical results aimed toward building a justification and discuss some remaining gaps in our understanding and our practical

290

flow_loop.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

FLOW ASSURANCE TEST LOOP FLOW ASSURANCE TEST LOOP Objective O ver a decade ago, RMOTC began cooperatively building a full-scale facility to test new fl ow assurance technology, mainly in the areas of hydrates and paraffi ns. Today, RMOTC's test facility consists of fi ve individual loop sections, including chilling and heated pipe-in-pipe water sections, bare lines, and a mixing section. The facility was designed to represent typical deepwater production systems in order to simulate full-scale tests and apply the results to fl ow assurance fi eld applications and technology. The current facility design consists of a 6" x 3,600 maximum allowable operating pressure test pipeline in fi ve separate loops. The test loops begin and ter- minate at a central location just north

291

TEP process flow diagram  

SciTech Connect

This presentation describes the development of the proposed Process Flow Diagram (PFD) for the Tokamak Exhaust Processing System (TEP) of ITER. A brief review of design efforts leading up to the PFD is followed by a description of the hydrogen-like, air-like, and waterlike processes. Two new design values are described; the mostcommon and most-demanding design values. The proposed PFD is shown to meet specifications under the most-common and mostdemanding design values.

Wilms, R Scott [Los Alamos National Laboratory; Carlson, Bryan [Los Alamos National Laboratory; Coons, James [Los Alamos National Laboratory; Kubic, William [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

292

Momentum Balance of Gravity Flows  

Science Conference Proceedings (OSTI)

A unified scale analysis of the momentum balance of downslope gravity flows is developed to organize previous theories for the case of negligible ambient flow and fixed temperature deficit scale. The values of several nondimensional parameters ...

L. Mahrt

1982-12-01T23:59:59.000Z

293

HYDROLYZED WOOD SLURRY FLOW MODELING  

E-Print Network (OSTI)

LBL-10090 UC-61 HYDROLYZED WOOD SLURRY FLOW MODELING JimLBL-10090 HYDROLYZED WOOD SLURRY FLOW MODELING Jim Wrathallconversion of hydrolyzed wood slurry to fuel oil, Based on

Wrathall, Jim

2012-01-01T23:59:59.000Z

294

Katabatic Wind in Opposing Flow  

Science Conference Proceedings (OSTI)

This paper presents a one-dimensional model of katabatic winds in ambient flow and examines types of possible solutions. Results presented in dimensionless form indicate that 1) cooling along a slope with upslope ambient flow can lead to tranquil ...

David R. Fitzjarrald

1984-04-01T23:59:59.000Z

295

Convective heat flow probe  

DOE Patents (OSTI)

A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

Dunn, J.C.; Hardee, H.C.; Striker, R.P.

1984-01-09T23:59:59.000Z

296

Motivation for a combined data flow-control flow processor  

Science Conference Proceedings (OSTI)

Data flow sequencing and the directed graph program representation provide two important tools for the development of computer architectures which can exploit problem parallelism. Classical (control flow) architecture deal efficiently with other problems such as serial sequences and data storage which are not handled so well by a data flow architecture. A hybrid which incorporates features of a data flow architecture along with features of a control flow architecture has the potential to become an effective parallel architecture for a wide class of problems. 10 references.

Oxley, D.W.

1981-01-01T23:59:59.000Z

297

FINAL REPORT INTEGRATED DM1200 MELTER TESTING OF REDOX EFFECTS USING HLW AZ-101 AND C-106/AY-102 SIMULANTS VSL-04R4800-1 REV 0 5/6/  

SciTech Connect

This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 and C-106/AY-102 HLW simulants. The tests reported herein are a subset of three tests from a larger series of tests described in the Test Plan for the work; results from the remaining tests will be reported separately. Three nine day tests, one with AZ-101 and two with C-106/AY-102 feeds were conducted with variable amounts of added sugar to address the effects of redox. The test with AZ-101 included ruthenium spikes to also address the effects of redox on ruthenium volatility. One of tests addressed the effects of increased flow-sheet nitrate levels using C-106/AY-102 feeds. With high nitrate/nitrite feeds (such as WTP LAW feeds), reductants are required to prevent melt foaming and deleterious effects on glass production rates. Sugar is the baseline WTP reductant for this purpose. WTP HLW feeds typically have relatively low nitrate/nitrite content in comparison to the organic carbon content and, therefore, have typically not required sugar additions. However, HLW feed variability, particularly with respect to nitrate levels, may necessitate the use of sugar in some instances. The tests reported here investigate the effects of variable sugar additions to the melter feed as well as elevated nitrate levels in the waste. Variables held constant to the extent possible included melt temperature, bubbling rate, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW feeds with variable amounts of added sugar and increased nitrate levels; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table.

KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; LUTZE W; BIZOT PM; CALLOW RA; BRANDYS M; KOT WK; PEGG IL

2011-12-29T23:59:59.000Z

298

Information flow analysis for javascript  

Science Conference Proceedings (OSTI)

Modern Web 2.0 pages combine scripts from several sources into a single client-side JavaScript program with almost no isolation. In order to prevent attacks from an untrusted third-party script or cross-site scripting, tracking provenance of data is ... Keywords: eval, hybrid program analysis, implicit flow, information flow control, unstructured control flow

Seth Just; Alan Cleary; Brandon Shirley; Christian Hammer

2011-10-01T23:59:59.000Z

299

Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 10, July 1, 1995--September 31, 1995  

DOE Green Energy (OSTI)

This document is the tenth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities focused on testing of additional modified and promoted catalysts and characterization of these materials. Attempts at improving the sensitivity of our GC based analytical systems were also made with some success. Methanol oxidation studies were initiated. These results are reported. Specific accomplishments include: (1) Methane oxidation testing of a suite of catalysts promoted with most of the first row transition metals was completed. Several of these materials produced low, difficult to quantify yields of formaldehyde. (2) Characterization of these materials by XRD and FTIR was performed with the goal of correlating activity and selectivity with catalyst properties. (3) We began to characterize catalysts prepared via modified synthesis methods designed to enhance acidity using TGA measurements of acetonitrile chemisorption and methanol dehydration to dimethyl ether as a test reaction. (4) A catalyst prepared in the presence of naphthalene methanol as a structural disrupter was tested for activity in methane oxidation. It was found that this material produced low yields of formaldehyde which were difficult to quantify. (5) Preparation of catalysts with no Bronsted acid sites. This was accomplished by replacement of exchangeable protons with potassium, and (6) Methanol oxidation studies were initiated to provide an indication of catalyst activity for decomposition of this desired product and as a method of characterizing the catalyst surface.

McCormick, R.L.

1995-12-07T23:59:59.000Z

300

UZ Flow Models and Submodels  

SciTech Connect

The purpose of this report is to document the unsaturated zone (UZ) flow models and submodels, as well as the flow fields that have been generated using the UZ flow model(s) of Yucca Mountain, Nevada. In this report, the term ''UZ model'' refers to the UZ flow model and the several submodels, which include tracer transport, temperature or ambient geothermal, pneumatic or gas flow, and geochemistry (chloride, calcite, and strontium) submodels. The term UZ flow model refers to the three-dimensional models used for calibration and simulation of UZ flow fields. This work was planned in the ''Technical Work Plan (TWP) for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.7). The table of included Features, Events, and Processes (FEPs), Table 6.2-11, is different from the list of included FEPs assigned to this report in the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Table 2.1.5-1), as discussed in Section 6.2.6. The UZ model has revised, updated, and enhanced the previous UZ model (BSC 2001 [DIRS 158726]) by incorporating the repository design with new grids, recalibration of property sets, and more comprehensive validation effort. The flow fields describe fracture-fracture, matrix-matrix, and fracture-matrix liquid flow rates, and their spatial distributions as well as moisture conditions in the UZ system. These three-dimensional UZ flow fields are used directly by Total System Performance Assessment (TSPA). The model and submodels evaluate important hydrogeologic processes in the UZ as well as geochemistry and geothermal conditions. These provide the necessary framework to test hypotheses of flow and transport at different scales, and predict flow and transport behavior under a variety of climatic conditions. In addition, the limitations of the UZ model are discussed in Section 8.11.

Y. Wu

2004-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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301

Fluid flow monitoring device  

DOE Patents (OSTI)

This invention consists of a flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

McKay, M.D.; Sweeney, C.E.

1991-03-05T23:59:59.000Z

302

Ellipsoidal cell flow system  

SciTech Connect

The disclosure relates to a system incorporating an ellipsoidal flow chamber having light reflective walls for low level light detection in practicing cellular analysis. The system increases signal-to-noise ratio by a factor of ten over prior art systems. In operation, laser light passes through the primary focus of the ellipsoid. A controlled flow of cells simultaneously passes through this focus so that the laser light impinges on the cells and is modulated by the cells. The reflective walls of the ellipsoid reflect the cell-modulated light to the secondary focus of the ellipsoid. A tapered light guide at the secondary focus picks up a substantial portion of modulated reflective light and directs it onto a light detector to produce a signal. The signal is processed to obtain the intensity distribution of the modulated light and hence sought after characteristics of the cells. In addition, cells may be dyed so as to fluoresce in response to the laser light and their fluorescence may be processed as cell-modulated light above described. A light discriminating filter would be used to distinguish reflected modulated laser light from reflected fluorescent light.

Salzman, Gary C. (Los Alamos, NM); Mullaney, Paul F. (Los Alamos, NM)

1976-01-01T23:59:59.000Z

303

Radial flow heat exchanger  

DOE Patents (OSTI)

A radial flow heat exchanger (20) having a plurality of first passages (24) for transporting a first fluid (25) and a plurality of second passages (26) for transporting a second fluid (27). The first and second passages are arranged in stacked, alternating relationship, are separated from one another by relatively thin plates (30) and (32), and surround a central axis (22). The thickness of the first and second passages are selected so that the first and second fluids, respectively, are transported with laminar flow through the passages. To enhance thermal energy transfer between first and second passages, the latter are arranged so each first passage is in thermal communication with an associated second passage along substantially its entire length, and vice versa with respect to the second passages. The heat exchangers may be stacked to achieve a modular heat exchange assembly (300). Certain heat exchangers in the assembly may be designed slightly differently than other heat exchangers to address changes in fluid properties during transport through the heat exchanger, so as to enhance overall thermal effectiveness of the assembly.

Valenzuela, Javier (Hanover, NH)

2001-01-01T23:59:59.000Z

304

Uranyl Nitrate Flow Loop  

Science Conference Proceedings (OSTI)

The objectives of the work discussed in this report were to: (1) develop a flow loop that would simulate the purified uranium-bearing aqueous stream exiting the solvent extraction process in a natural uranium conversion plant (NUCP); (2) develop a test plan that would simulate normal operation and disturbances that could be anticipated in an NUCP; (3) use the flow loop to test commercially available flowmeters for use as safeguards monitors; and (4) recommend a flowmeter for production-scale testing at an NUCP. There has been interest in safeguarding conversion plants because the intermediate products [uranium dioxide (UO{sub 2}), uranium tetrafluoride (UF{sub 4}), and uranium hexafluoride (UF{sub 6})] are all suitable uranium feedstocks for producing special nuclear materials. Furthermore, if safeguards are not applied virtually any nuclear weapons program can obtain these feedstocks without detection by the International Atomic Energy Agency (IAEA). Historically, IAEA had not implemented safeguards until the purified UF{sub 6} product was declared as feedstock for enrichment plants. H. A. Elayat et al. provide a basic definition of a safeguards system: 'The function of a safeguards system on a chemical conversion plant is in general terms to verify that no useful nuclear material is being diverted to use in a nuclear weapons program'. The IAEA now considers all highly purified uranium compounds as candidates for safeguarding. DOE is currently interested in 'developing instruments, tools, strategies, and methods that could be of use to the IAEA in the application of safeguards' for materials found in the front end of the nuclear fuel cycle-prior to the production of the uranium hexafluoride or oxides that have been the traditional starting point for IAEA safeguards. Several national laboratories, including Oak Ridge, Los Alamos, Lawrence Livermore, and Brookhaven, have been involved in developing tools or techniques for safeguarding conversion plants. This study was sponsored by the U.S. Department of Energy (DOE) NA-241, Office of Dismantlement and Transparency.

Ladd-Lively, Jennifer L [ORNL

2008-10-01T23:59:59.000Z

305

Instrumentation for Increased Power Flow  

Science Conference Proceedings (OSTI)

This report is the second Technical Update of the Instrumentation for Managing Increased Power Flow project, part of EPRI's Increased Power Flow (IPF) program. The project, initiated in 2006 and expected to continue for several years, studies the feasibility of new instrumentation to support increased power flow strategies. In 2007 the work focused on two primary developments: the Backscatter Sensor for the real-time measurement of transmission line temperature and current and the Emissivity Test Instrum...

2007-12-06T23:59:59.000Z

306

HYDROCARBON LIQUID FLOW CALIBRATION SERVICE ...  

Science Conference Proceedings (OSTI)

... and is the cross correlation coefficient ... a NIST Hydrocarbon Liquid Flow Calibration Facility ... FED2004-56790, 2004 Heat Transfer/Fluids Engineering ...

2012-05-21T23:59:59.000Z

307

Flow Batteries: A Historical Perspective  

NLE Websites -- All DOE Office Websites (Extended Search)

Marvin Warshay *1976 Shunt Current Model, Paul Prokopius *1976 Interfaced an RFB with solar cells *1977 Electrode-Membrane-Flow Battery Testing *Largest polarization @ negative...

308

EPRI Coal-Flow Loop  

Science Conference Proceedings (OSTI)

This report is targeted at plant personnel responsible for coal-flow measurement and mill balancing that are using or are considering the use of online, in situ measurement technologies. Optimum combustion in a boiler requires careful control of coal and air flow to individual burners. Measuring in near real-time the mass flow rate of pneumatically conveyed pulverized coal in burner feed pipes is a critical element of such control. This report summarizes the findings for two online coal-flow instruments ...

2006-12-01T23:59:59.000Z

309

Patterns in Flowing Sand: Understanding the Physics of Granular Flow  

E-Print Network (OSTI)

Dense granular flows are often unstable and form inhomogeneous structures. Although significant advances have been recently made in understanding simple flows, instabilities of such flows are often not understood. We present experimental and numerical results that show the formation of longitudinal stripes that arise from instability of the uniform flowing state of granular media on a rough inclined plane. The form of the stripes depends critically on the mean density of the flow with a robust form of stripes at high density that consists of fast sliding plug-like regions (stripes) on top of highly agitated boiling material - a configuration reminiscent of the Leidenfrost effect when a droplet of liquid lifted by its vapor is hovering above a hot surface.

Tamas Borzsonyi; Robert E. Ecke; Jim N. McElwaine

2009-10-01T23:59:59.000Z

310

Ethane and n-butane oxidation over supported vanadium oxide catalysts: An in situ UV-visible diffuse reflectance spectroscopic investigation  

SciTech Connect

The coordination/oxidation states of surface vanadium oxide species on several oxide supports (Al{sub 2}O{sub 3}, ZrO{sub 2}, SiO{sub 2}) during ethane and n-butane oxidation were examined by in situ UV-vis diffuse reflectance spectroscopy (DRS). Only a small amount of the surface V(V)cations are reduced to V(IV)/V(III) cations under present steady-state reaction conditions. The extents of reduction of the surface V(V) species are a strong function of the specific oxide support, V{sub 2}O{sub 5}/ZrO{sub 2} {gt} V{sub 2}O{sub 5}/Al{sub 2}O{sub 5}/Al{sub 2}O{sub 3} {gt} V{sub 2}O{sub 5}/SiO{sub 2}, and also correlate with their reactivities (turnover frequencies) for ethane and n-butane oxidation reactions. For ZrO{sub 2}-supported samples, the polymerized surface vanadia species were found to be more easily reduced than the isolated surface vanadia species in reducing environments (i.e., ethane or n-butane in He), but no significant differences in the extents of reduction were observed under present steady-state reaction conditions (i.e., ethane/O{sub 2}/He or n-butane/O{sub 2}/He). This observation is also consistent with the ethane oxidation catalytic study, which revealed that the polymerization degree, the domain size, of the surface vanadia species does not appear to significantly affect the reactivity of the supported vanadia catalysts for ethane oxidation.

Gao, X.; Banares, M.A.; Wachs, I.E.

1999-12-10T23:59:59.000Z

311

Chemical and electrochemical behavior of the Cr(III)/Cr(II) half cell in the NASA Redox Energy Storage System  

DOE Green Energy (OSTI)

The Cr(III) complexes in the NASA Redox Energy Storage System have been isolated and identified as Cr(H/sub 2/O)/sub 6//sup +3/ and Cr(H/sub 2/O)/sub 5/Cl/sup +2/ by ion-exchange chromatography and visible spectrophotometry. The cell reactions during charge-discharge cycles have been followed by means of visible spectrophotometry. The spectral bands were resolved into component peaks and concentrations calculated using Beer's Law. During the charge mode Cr(H/sub 2/O)/sub 5/Cl/sup +2/ is reduced to Cr(H/sub 2/O)/sub 5/Cl/sup +/ and during the discharge mode Cr(H/sub 2/O)/sub 5/Cl/sup +/ is oxidized back to Cr(H/sub 2/O)/sub 5/Cl/sup +2/. Both electrode reactions occur via a chloride-bridge inner-sphere reaction pathway. Hysteresis effects can be explained by the slow attainment of equilibrium between Cr(H/sub 2/O)/sub 6//sup +3/ and Cr(H/sub 2/O)/sub 5/Cl/sup +2/.

Johnson, D.A.; Reid, M.A.

1982-01-01T23:59:59.000Z

312

Subsurface microbial community structure correlates with uranium redox phases during in situ field manipulation in a contaminated aquifer  

Science Conference Proceedings (OSTI)

Long-term field manipulation experiments investigating the effects of subsurface redox conditions on the fate and transport of soluble uranium(VI) were conducted over a 3 year period at the Oak Ridge Integrated Field Research Center (OR-IFRC) in Oak Ridge, TN. In the highly contaminated source zone, introduction of ethanol to the subsurface stimulated native denitrifying, sulfate-reducing, iron-reducing and fermentative microorganisms and reduced U to below 0.03 mg/L. Subsequently, oxygen and nitrate were experimentally re-introduced into the subsurface to examine the potential for re-oxidation and re-mobilization of U(IV). Introduction of oxygen or nitrate caused changes in subsurface geochemistry and re-oxidation of U. After reoxidation, the subsurface experienced several months of starvation conditions before ethanol injection was restored to reduce the treatment zone. Subsurface microorganisms were characterized by community fingerprinting, targeted population analyses, and quantitative PCR of key functional groups in 50 samples taken during multiple phases of field manipulation. Statistical analysis confirmed the hypothesis that the microbial community would co-vary with the shifts in the subsurface geochemistry. The level of hydraulic connectivity of sampling wells to the injection well was readily tracked by microbial community analysis. We demonstrate quantitatively that specific populations, especially Desulfosporosinus, are heavily influenced by geochemical conditions and positively correlate with the immobilization of uranium. Following nitrate reoxidation, populations of Fe(II)-oxidizing, nitrate reducing organisms (Thiobacillus) showed an increase in relative abundance.

Kostka, Joel [Florida State University; Green, Stefan [Florida State University, Tallahassee; Wu, Wei-min [Stanford University; Criddle, Craig [Stanford University; Watson, David B [ORNL; Jardine, Philip M [ORNL

2009-07-01T23:59:59.000Z

313

Evaluation of fall chinook salmon spawning adjacent to the In-Situ Redox Manipulation treatability test site, Hanford Site, Washington  

Science Conference Proceedings (OSTI)

The In Situ Redox Manipulation (ISRM) experiment is being evaluated as a potential method to remove contaminants from groundwater adjacent to the Columbia River near the 100-D Area. The ISRM experiment involves using sodium dithionate (Na{sub 2}O{sub 6}S{sub 2}) to precipitate chromate from the groundwater. The treatment will likely create anoxic conditions in the groundwater down-gradient of the ISRM treatability test site; however, the spatial extent of this anoxic plume is not exactly known. Surveys were conducted in November 1997, following the peak spawning of fall chinook salmon. Aerial surveys documented 210 redds (spawning nests) near the downstream island in locations consistent with previous surveys. Neither aerial nor underwater surveys documented fall chinook spawning in the vicinity of the ISRM treatability test site. Based on measurements of depth, velocity, and substrate, less than 1% of the study area contained suitable fall chinook salmon spawning habitat, indicating low potential for fall chinook salmon to spawn in the vicinity of the ISRM experiment.

Mueller, R.P.; Geist, D.R.

1998-10-02T23:59:59.000Z

314

Split flow gasifier  

DOE Patents (OSTI)

A-moving bed coal gasifier for the production of tar-free, low ammonia fuel gas is described. The gasifier employs a combustion zone in a free-aboard area above the moving bed to burn coal fines to provide hot combustion gases for pyrolyzing and gasifying coal particulates in the moving bed to form fuel gas as the hot gases move co-currently with the downwardly moving coal particulates. The fuel gas contains entrained tars and ammonia compounds which contact hot char and ash in the moving bed and are cracked so that the fuel gas removed from the gasifier at a midpoint off-take is essentially tar-free and of low ammonia content. Concurrently with this gasification reaction, steam and an oxidant are introduced into a region below the moving bed to flow countercurrently to the downwardly moving bed to contact and react with carbon remaining in the char to create additional fuel gas which is also extracted from the gasifier at the mid-point off-take.

Halow, J.S.

1991-12-31T23:59:59.000Z

315

Turbine blade tip flow discouragers  

SciTech Connect

A turbine assembly comprises a plurality of rotating blade portions in a spaced relation with a stationery shroud. The rotating blade portions comprise a root section, a tip portion and an airfoil. The tip portion has a pressure side wall and a suction side wall. A number of flow discouragers are disposed on the blade tip portion. In one embodiment, the flow discouragers extend circumferentially from the pressure side wall to the suction side wall so as to be aligned generally parallel to the direction of rotation. In an alternative embodiment, the flow discouragers extend circumferentially from the pressure side wall to the suction side wall so as to be aligned at an angle in the range between about 0.degree. to about 60.degree. with respect to a reference axis aligned generally parallel to the direction of rotation. The flow discouragers increase the flow resistance and thus reduce the flow of hot gas flow leakage for a given pressure differential across the blade tip portion so as to improve overall turbine efficiency.

Bunker, Ronald Scott (Niskayuna, NY)

2000-01-01T23:59:59.000Z

316

Physics of two-phase flow: choked flow  

DOE Green Energy (OSTI)

It is shown that the basic equations governing the flow of a two-phase fluid, i.e., liquid and vapor, are natural extensions of those equations that describe single-phase flow. The exact form of the equations depends on the particular assumptions used to characterize the two-phase flow, i.e., the equations depend on the model chosen. In general the mathematical model is selected so as to retain as much of the physics of the phenomena as possible while at the same time permitting solutions to be obtained without undue complexity. The following quantities were computed for saturated water substance over the temperature range 100 to 250/sup 0/C and for saturated Refrigerant -114 over the range -20 to +70/sup 0/C: choking velocity, critical or choking flow density, and saturation properties. Tables of the results are given along with graphs of selected functions.

Maeder, P.F.; DiPippo, R.; Delor, M.; Dickinson, D.

1981-05-01T23:59:59.000Z

317

The transition from two phase bubble flow to slug flow  

E-Print Network (OSTI)

The process of transition from bubble to slug flow in a vertical pipe has been studied analytically and experimentally. An equation is presented which gives the agglomeration time as a function of void fraction, channel ...

Radovcich, Nick A.

1962-01-01T23:59:59.000Z

318

HYDROGEN ELECTROLYZER FLOW DISTRIBUTOR MODEL  

DOE Green Energy (OSTI)

The hybrid sulfur process (HyS) hydrogen electrolyzer consists of a proton exchange membrane (PEM) sandwiched between two porous graphite layers. An aqueous solution of sulfuric acid with dissolved SO{sub 2} gas flows parallel to the PEM through the porous graphite layer on the anode side of the electrolyzer. A flow distributor, consisting of a number of parallel channels acting as headers, promotes uniform flow of the anolyte fluid through the porous graphite layer. A numerical model of the hydraulic behavior of the flow distributor is herein described. This model was developed to be a tool to aid the design of flow distributors. The primary design objective is to minimize spatial variations in the flow through the porous graphite layer. The hydraulic data from electrolyzer tests consists of overall flowrate and pressure drop. Internal pressure and flow distributions are not measured, but these details are provided by the model. The model has been benchmarked against data from tests of the current electrolyzer. The model reasonably predicts the viscosity effect of changing the fluid from water to an aqueous solution of 30 % sulfuric acid. The permeability of the graphite layer was the independent variable used to fit the model to the test data, and the required permeability for a good fit is within the range literature values for carbon paper. The model predicts that reducing the number of parallel channels by 50 % will substantially improve the uniformity of the flow in the porous graphite layer, while maintaining an acceptable pressure drop across the electrolyzer. When the size of the electrolyzer is doubled from 2.75 inches square to 5.5 inches square, the same number of channels as in the current design will be adequate, but it is advisable to increase the channel cross-sectional flow area. This is due to the increased length of the channels.

Shadday, M

2006-09-28T23:59:59.000Z

319

Proper planning improves flow drilling  

Science Conference Proceedings (OSTI)

Underbalanced operations reduce formation damage, especially in horizontal wells where zones are exposed to mud for longer time periods. Benefits, risks, well control concerns, equipment and issues associated with these operations are addressed in this paper. Flow drilling raises many concerns, but little has been published on horizontal well control and flow drilling operations. This article covers planning considerations for flow drilling, but does not address horizontal ''overbalanced'' drilling because considerations and equipment are the same as in vertical overbalanced drilling and many references address that subject. The difference in well control between vertical and horizontal overbalanced drilling is fluid influx behavior and how that behavior affects kill operations.

Collins, G.J. (Marathon Oil Co., Houston, TX (United States))

1994-10-01T23:59:59.000Z

320

Definition: Flow Test | Open Energy Information  

Open Energy Info (EERE)

Flow Test Jump to: navigation, search Dictionary.png Flow Test Flow tests are typically conducted shortly after a well has been drilled to test its productivity. The well is opened...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Transitions between Baroclinic Flow Regimes  

Science Conference Proceedings (OSTI)

we use truncated spectral Eady models with two Ekman layers of different strength to investigate the baroclinic flow transitions observed in annulus experiments. Our analysis is both analytical and numerical As the dissipation parameter is varied ...

H-Y. Weng; A. Barcilon; J. Magnan

1986-08-01T23:59:59.000Z

322

Coal flows | OpenEI  

Open Energy Info (EERE)

Coal flows Coal flows Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 142, and contains only the reference case. The dataset uses million short tons. The data is broken down into steam coal exports to Europe, Asia and America. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords 2011 AEO Coal flows countries EIA exporting importing Data application/vnd.ms-excel icon AEO2011: World Steam Coal Flows By Importing Regions and Exporting Countries- Reference Case (xls, 103.7 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License

323

Essays on international capital flows  

E-Print Network (OSTI)

This dissertation consists of three chapters on international capital flows. Chapter 1 emphasizes the importance of innovations in the investment opportunity set, captured by changes in expected asset returns, as an important ...

Brandão, Tatiana Glindmeier Didier

2008-01-01T23:59:59.000Z

324

Lattice splitting under intermittent flows  

E-Print Network (OSTI)

We study the splitting of regular square lattices subject to stochastic intermittent flows. By extensive Monte Carlo simulations we reveal how the time span until the occurence of a splitting depends on various flow patterns imposed on the lattices. Increasing the flow fluctuation frequencies shortens this time span which reaches a minimum before rising again due to inertia effects incorporated in the model. The size of the largest connected component after the splitting is rather independent of the flow fluctuations but sligthly decreases with the link capacities. Our results are relevant for assessing the robustness of real-life systems, such as electric power grids with a large share of renewable energy sources including wind turbines and photovoltaic systems.

Schläpfer, Markus

2010-01-01T23:59:59.000Z

325

Miniaturized flow injection analysis system  

DOE Patents (OSTI)

A chemical analysis technique known as flow injection analysis, wherein small quantities of chemical reagents and sample are intermixed and reacted within a capillary flow system and the reaction products are detected optically, electrochemically, or by other means. A highly miniaturized version of a flow injection analysis system has been fabricated utilizing microfabrication techniques common to the microelectronics industry. The microflow system uses flow capillaries formed by etching microchannels in a silicon or glass wafer followed by bonding to another wafer, commercially available microvalves bonded directly to the microflow channels, and an optical absorption detector cell formed near the capillary outlet, with light being both delivered and collected with fiber optics. The microflow system is designed mainly for analysis of liquids and currently measures 38.times.25.times.3 mm, but can be designed for gas analysis and be substantially smaller in construction.

Folta, James A. (Livermore, CA)

1997-01-01T23:59:59.000Z

326

Miniaturized flow injection analysis system  

DOE Patents (OSTI)

A chemical analysis technique known as flow injection analysis is described, wherein small quantities of chemical reagents and sample are intermixed and reacted within a capillary flow system and the reaction products are detected optically, electrochemically, or by other means. A highly miniaturized version of a flow injection analysis system has been fabricated utilizing microfabrication techniques common to the microelectronics industry. The microflow system uses flow capillaries formed by etching microchannels in a silicon or glass wafer followed by bonding to another wafer, commercially available microvalves bonded directly to the microflow channels, and an optical absorption detector cell formed near the capillary outlet, with light being both delivered and collected with fiber optics. The microflow system is designed mainly for analysis of liquids and currently measures 38{times}25{times}3 mm, but can be designed for gas analysis and be substantially smaller in construction. 9 figs.

Folta, J.A.

1997-07-01T23:59:59.000Z

327

Flow Acceleration and Mountain Drag*  

Science Conference Proceedings (OSTI)

Dynamic explanations of mountain drag usually invoke viscous effects and/or wave momentum flux by either Rossby or internal gravity waves. This paper explores an alternative mechanism in terms of the unsteadiness of the incident flow. The ...

Peter R. Bannon

1985-12-01T23:59:59.000Z

328

Studies of Flows in Plasmas  

SciTech Connect

Note a pdf document "DOE-flow-final-report' should be attached. If it somehow is not please notify Walter Gekelman (gekelman@physics.ucla.edu) who will e mail it directly

Gekelman, Walter; Morales, George; Maggs, James

2009-03-07T23:59:59.000Z

329

Longitudinal dispersion in vegetated flow  

E-Print Network (OSTI)

Vegetation is ubiquitous in rivers, estuaries and wetlands, strongly influencing both water conveyance and mass transport. The plant canopy affects both mean and turbulent flow structure, and thus both advection and ...

Murphy, Enda

2006-01-01T23:59:59.000Z

330

Parabolic flows on complex manifolds  

E-Print Network (OSTI)

Chapter 2 Convergence of the parabolic complex Monge-Amp`ere65] Streets, J. , Tian, G. A parabolic flow of pluriclosedGill, M. Convergence of the parabolic complex Monge-Amp` ere

Gill, Matthew Franklin

2012-01-01T23:59:59.000Z

331

Multiscale modeling in granular flow  

E-Print Network (OSTI)

Granular materials are common in everyday experience, but have long-resisted a complete theoretical description. Here, we consider the regime of slow, dense granular flow, for which there is no general model, representing ...

Rycroft, Christopher Harley

2007-01-01T23:59:59.000Z

332

Subcooled flow boiling of fluorocarbons  

E-Print Network (OSTI)

A study was conducted of heat transfer and hydrodynamic behavior for subcooled flow boiling of Freon-113, one of a group of fluorocarbons suitable for use in cooling of high-power-density electronic components. Problems ...

Murphy, Richard Walter

1971-01-01T23:59:59.000Z

333

2007 Estimated International Energy Flows  

Science Conference Proceedings (OSTI)

An energy flow chart or 'atlas' for 136 countries has been constructed from data maintained by the International Energy Agency (IEA) and estimates of energy use patterns for the year 2007. Approximately 490 exajoules (460 quadrillion BTU) of primary energy are used in aggregate by these countries each year. While the basic structure of the energy system is consistent from country to country, patterns of resource use and consumption vary. Energy can be visualized as it flows from resources (i.e. coal, petroleum, natural gas) through transformations such as electricity generation to end uses (i.e. residential, commercial, industrial, transportation). These flow patterns are visualized in this atlas of 136 country-level energy flow charts.

Smith, C A; Belles, R D; Simon, A J

2011-03-10T23:59:59.000Z

334

Modeling the Geometric Electronic and Redox Properties of Iron(lll)-Containing Amphiphiles with Asymmetric [NNO] Headgroups  

DOE Green Energy (OSTI)

Two iron(III)-containing amphiphiles 1 and 2 have been synthesized with the [NN'O] ligands HL{sup tBu-ODA} (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-di-tert-butylphenol) and HL{sup I-ODA} (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-diiodophenol), respectively. Compound 1 is monometallic, whereas EXAFS data suggest that 2 is a mixture of mono- and bimetallic species. The archetypical [Fe{sup III}(L{sup NN'O}){sub 2}]{sup +} complexes 3-9 have been isolated and characterized in order to understand the geometric, electronic, and redox properties of the amphiphiles. Preference for a monometallic or bimetallic nuclearity is dependent on (i) the nature of the solvent used for synthesis and (ii) the type of the substituent in the phenol moiety. In methanol, the tert-butyl-, methoxy-, and chloro-substituted 3, 4, and 5 are monometallic species, whereas the bromo- and iodo-substituted 6 and 7 form bimetallic complexes taking advantage of stabilizing methoxo bridges generated by solvent deprotonation. In dichloromethane, the bromo- and iodo-substituted 8 and 9 are monometallic species; however, these species favor meridional coordination in opposition to the facial coordination observed for the tert-butyl- and methoxy-substituted compounds. Molecular structures for species 5, 7, 8, and 9 have been solved by X-ray diffraction. Furthermore, the electronic spectrum of the amphiphile 1 was expected to be similar to those of facial/cis archetypes with similar substituents, but close resemblance was observed with the profile for those meridional/cis species, suggesting a similar coordination mode. This trend is discussed based on DFT calculations, where preference for the meridional/cis coordination mode appears related to the presence of tertiary amine nitrogen on the ligand, as when a long alkyl chain is attached to the [NN'O] headgroup.

R Shakya; M Allard; M Johann; M Heeg; E Rentschler; J Shearer; B McGarvey; C Verani

2011-12-31T23:59:59.000Z

335

Status of cross-section data for gas production from vanadium and {sup 26}AL from silicon carbide in a D-T fusion reactor.  

DOE Green Energy (OSTI)

Current designs of fusion-reactor systems seek to use radiation-resistant, low-activation materials that support long service lifetimes and minimize radioactive-waste problems after decommissioning. Reliable assessment of fusion materials performance requires accurate neutron-reaction cross sections and radioactive-decay constants. The problem areas usually involve cross sections since decay parameters tend to be better known. The present study was motivated by two specific questions: (i) Why are the {sup 51}V(n,np){sup 50}Ti cross section values in the ENDF/B-VI library so large (a gas production issue)? (ii) How well known are the cross sections associated with producing 7.4 x 10{sup 5} y {sup 26}Al in silicon carbide by the process {sup 28}Si(n,np+d){sup 27} Al(n,2n){sup 26}Al (a long-lived radioactivity issue)? The energy range 14-15 MeV of the D-T fusion neutrons is emphasized. Cross-section error bars are needed so that uncertainties in the gas and radioactivity generated over the lifetime of a reactor can be estimated. We address this issue by comparing values obtained from prominent evaluated cross-section libraries. Small differences between independent evaluations indicate that a physical quantity is well known while the opposite signals a problem. Hydrogen from {sup 51}V(n,p){sup 51}Ti and helium from {sup 51}V(n,{alpha}){sup 48}Sc are also important sources of gas in vanadium, so they too were examined. We conclude that {sup 51}V(n,p){sup 51}Ti is adequately known but {sup 51}V(n,np+d){sup 50}Ti is not. The status for helium generation data is quite good. Due to recent experimental work, {sup 27}Al(n,2n){sup 26}Al seems to be fairly well known. However, the situation for {sup 28}Si(n,np+d){sup 27}Al remains unsatisfactory.

Gomes, I. C.

1998-08-11T23:59:59.000Z

336

Increased Power Flow Guidebook - 2012  

Science Conference Proceedings (OSTI)

The EPRI Increased Power Flow (IPF) Guidebook is a state-of-the-art and best- practices reference and guidebook on increasing the power flow capacities of existing overhead transmission lines, underground cables, power transformers, and substation equipment, without compromising safety and reliability. The Guidebook discusses power system concerns and limiting conditions to increasing capacity, reviews available technology options and methods, illustrates the alternatives with case ...

2012-12-31T23:59:59.000Z

337

Increased Power Flow Guidebook - 2013  

Science Conference Proceedings (OSTI)

The EPRI Increased Power Flow (IPF) Guidebook is a state-of-the-art and best- practices reference and guidebook on increasing the power flow capacities of existing overhead transmission lines, underground cables, power transformers, and substation equipment, without compromising safety and reliability. The Guidebook discusses power system concerns and limiting conditions to increasing capacity, reviews available technology options and methods, illustrates the alternatives with case ...

2013-11-18T23:59:59.000Z

338

Acoustic concentration of particles in fluid flow  

DOE Patents (OSTI)

An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

Ward, Michael D. (Los Alamos, NM); Kaduchak, Gregory (Los Alamos, NM)

2010-11-23T23:59:59.000Z

339

Accuracy of flow hoods in residential applications  

SciTech Connect

To assess whether houses can meet performance expectations, the new practice of residential commissioning will likely use flow hoods to measure supply and return grille airflows in HVAC systems. Depending on hood accuracy, these measurements can be used to determine if individual rooms receive adequate airflow for heating and cooling, to determine flow imbalances between different building spaces, to estimate total air handler flow and supply/return imbalances, and to assess duct air leakage. This paper discusses these flow hood applications and the accuracy requirements in each case. Laboratory tests of several residential flow hoods showed that these hoods can be inadequate to measure flows in residential systems. Potential errors are about 20% to 30% of measured flow, due to poor calibrations, sensitivity to grille flow non-uniformities, and flow changes from added flow resistance. Active flow hoods equipped with measurement devices that are insensitive to grille airflow patterns have an order of magnitude less error, and are more reliable and consistent in most cases. Our tests also show that current calibration procedures for flow hoods do not account for field application problems. As a result, a new standard for flow hood calibration needs to be developed, along with a new measurement standard to address field use of flow hoods. Lastly, field evaluation of a selection of flow hoods showed that it is possible to obtain reasonable results using some flow hoods if the field tests are carefully done, the grilles are appropriate, and grille location does not restrict flow hood placement.

Wray, Craig P.; Walker, Iain S.; Sherman, Max H.

2002-05-01T23:59:59.000Z

340

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes  

DOE Patents (OSTI)

A electrochemical cell is described comprising an anode, a cathode, a solid polymer electrolyte; and a redox shuttle additive to protect the cell against overcharging and a redox shuttle additive to protect the cell against overcharging selected from the group consisting of: (a) a substituted anisole having the general formula shown in a figure (in an uncharged state): where R{sub 1} is selected from the group consisting of H, 0CH{sub 3}, OCH{sub 2}CH{sub 3}, and OCH{sub 2}phenyl, and R{sub 2} is selected from the group consisting of OCH{sub 3}, OCH{sub 2}CH{sub 3}, OCH{sub 2} phenyl, and O{sup {minus}}Li{sup +}; and (b) a di-anisole compound having the general formula shown in a second figure (in an uncharged state): where R is selected from the group consisting of -OCH{sup 3} and -CH{sub 3}, m is either 1 or 0, n is either 1 or 0, and X is selected from the group consisting of -OCH{sub 3} (methoxy) or its lithium salt -O{sup {minus}}Li{sup +}. The lithium salt of the di-anisole is the preferred form of the redox shuttle additive because the shuttle anion will then initially have a single negative charge, it loses two electrons when it is oxidized at the cathode, and then moves toward the anode as a single positively charged species where it is then reduced to a single negatively charged species by gaining back two electrons.

Kerr, John B.; Tian, Minmin

1998-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Flow assurance and multiphase pumping  

E-Print Network (OSTI)

A robust understanding and planning of production enhancement and flow assurance is required as petroleum E&P activities are targeting deepwaters and long distances. Different flow assurance issues and their solutions are put together in this work. The use of multiphase pumps as a flow assurance solution is emphasized. Multiphase pumping aids flow assurance in different ways. However, the problem causing most concern is sand erosion. This work involved a detection-based sand monitoring method. Our objectives are to investigate the reliability of an acoustic sand detector and analyze the feasibility of gel injection as a method to mitigate sand erosion. Use of a sand detector coupled with twin-screw pumps is studied under varying flow conditions. The feasibility of gel injection to reduce slip and transport produced solids through twin-screw pump is investigated. A unique full-scale laboratory with multiphase pumps was utilized to carry out the experimental tests. The test results indicate that acoustic sand detection works in a narrow window around the calibration signature. An empirical correlation for predicting the twin-screw pump performance with viscous fluids was developed. It shows good agreement in the practical operational limits – 50% to 100% speed. The results indicate that viscous gel injection should be an effective erosion mitigation approach as it reduces slip, the principle cause of erosive wear. To correlate the performance of viscous fluid injection to hydroabrasive wear, further experimental investigation is needed.

Nikhar, Hemant G.

2006-12-01T23:59:59.000Z

342

Oxygen Absorption in Cooling Flows  

E-Print Network (OSTI)

The inhomogeneous cooling flow scenario predicts the existence of large quantities of gas in massive elliptical galaxies, groups, and clusters that have cooled and dropped out of the flow. Using spatially resolved, deprojected X-ray spectra from the ROSAT PSPC we have detected strong absorption over energies ~0.4-0.8 keV intrinsic to the central ~1 arcmin of the galaxy, NGC 1399, the group, NGC 5044, and the cluster, A1795. These systems have amongst the largest nearby cooling flows in their respective classes and low Galactic columns. Since no excess absorption is indicated for energies below ~0.4 keV the most reasonable model for the absorber is warm, collisionally ionized gas with T=10^{5-6} K where ionized states of oxygen provide most of the absorption. Attributing the absorption only to ionized gas reconciles the large columns of cold H and He inferred from Einstein and ASCA with the lack of such columns inferred from ROSAT, and also is consistent with the negligible atomic and molecular H inferred from HI, and CO observations of cooling flows. The prediction of warm ionized gas as the product of mass drop-out in these and other cooling flows can be verified by Chandra, XMM, and ASTRO-E.

David A. Buote

2000-01-19T23:59:59.000Z

343

Visualization and Diagnostics of Thermal Plasma Flows  

Science Conference Proceedings (OSTI)

Flow visualization is a key tool for the study of thermal plasma flows. Because of their high temperature and associated self emission, standard and high speed photography is commonly used for flow and temperature field visualization. Tracer techniques ... Keywords: d.c. plasma jet, enthalpy probe techniques, induction plasma, laser strobe, photographic techniques, schlieren, thermal plasma flows

M. I. Boulos

2001-01-01T23:59:59.000Z

344

Numerical length estimation for tubular flow reactors  

Science Conference Proceedings (OSTI)

Keywords: free boundary value problems, noniterative and iterative numerical methods, tubular flow reactors

Riccardo Fazio

1992-08-01T23:59:59.000Z

345

Valve for controlling solids flow  

DOE Patents (OSTI)

A valve for controlling the flow of solids comprises a vessel having an overflow point, an inlet line for discharging solids into the vessel positioned within the vessel such that the inlet line's discharge point is lower than the vessel's overflow point, and apparatus for introducing a fluidizing fluid into the vessel. The fluidizing fluid fluidizes the solids within the vessel so that they overflow at the vessel's overflow point. For the removal of nuclear waste product the vessel may be placed within a sealed container having a bottom connected transport line for transporting the solids to storage or other sites. The rate of solids flow is controlled by the flow rate of the fluidizing fluid and by V-notch weirs of different sizes spaced about the top of the vessel.

Staiger, M. Daniel (Idaho Falls, ID)

1985-01-01T23:59:59.000Z

346

Monitoring probe for groundwater flow  

DOE Patents (OSTI)

A monitoring probe for detecting groundwater migration. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow.

Looney, Brian B. (Aiken, SC); Ballard, Sanford (Albuquerque, NM)

1994-01-01T23:59:59.000Z

347

Redox Shuttle Additives  

As the demand for hybrid and electric vehicles continues to grow, so does the demand for lithium-ion batteries that are safer, more powerful, and less expensive. These Argonne additives will help meet that demand.

348

Redox Shuttle Additives  

Reduce cost, and Increase battery reliability. Applications and Industries Electrodes used in batteries for Electric and plug-in hybrid electric ...

349

Flow in geothermal wells. Part IV. Transition criteria for two-phase flow patterns  

DOE Green Energy (OSTI)

Detailed considerations justifying the criteria for transitions between flow patterns are presented. The following are covered: transition from bubble to plug (or slug) flow, transition from plug flow to froth flow, transition from froth to annular mist flow, and model comparisons. (MHR)

Bilicki, Z.; Kestin, J.

1980-12-01T23:59:59.000Z

350

Rinse trough with improved flow  

SciTech Connect

Novel rinse troughs accomplish thorough uniform rinsing. The troughs are suitable for one or more essentially planar objects having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs provide uniform rinse fluid flow over the objects' surfaces to accomplish a more thorough rinse than prior art troughs.

O' Hern, Timothy J. (Albuquerque, NM); Grasser, Thomas W. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

351

Wave–Mean Flow Statistics  

Science Conference Proceedings (OSTI)

A relation between the statistics of large-scale waves and the mean flow is derived from the potential enstrophy equations integrated over an isobaric surface. The difference between time-averaged zonal-mean state and the radiative-dynamical ...

Mark R. Schoeberl

1982-10-01T23:59:59.000Z

352

Shallow Water Flows in Channels  

Science Conference Proceedings (OSTI)

We consider the shallow water equations for flows through channels with arbitrary cross section. The system forms a hyperbolic set of balance laws. Exact steady-state solutions are available and are controlled by the relation between the bottom topography ... Keywords: Balance laws, Hyperbolic conservation laws, Steady-state solutions, Upwind schemes

Gerardo Hernández-Dueñas; Smadar Karni

2011-07-01T23:59:59.000Z

353

Superconducting flux flow digital circuits  

DOE Patents (OSTI)

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs) are disclosed. Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics. 8 figs.

Hietala, V.M.; Martens, J.S.; Zipperian, T.E.

1995-02-14T23:59:59.000Z

354

Superconducting flux flow digital circuits  

DOE Patents (OSTI)

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs). Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics.

Hietala, Vincent M. (Placitas, NM); Martens, Jon S. (Sunnyvale, CA); Zipperian, Thomas E. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

355

Available Technologies: Vanadium Dioxide Microactuators  

REFERENCE NUMBER: IB 2013-013. See More Nano & Micro Technologies. Contact Us. Receive Customized Tech Alerts. Tech Transfer Site Map. Last updated: 05/20/2013.

356

Fluid Flow Within Fractured Porous Media  

Science Conference Proceedings (OSTI)

Fractures provide preferential flow paths to subterranean fluid flows. In reservoir scale modeling of geologic flows fractures must be approximated by fairly simple formulations. Often this is accomplished by assuming fractures are parallel plates subjected to an applied pressure gradient. This is known as the cubic law. An induced fracture in Berea sandstone has been digitized to perform numerical flow simulations. A commercially available computational fluid dynamics software package has been used to solve the flow through this model. Single phase flows have been compared to experimental works in the literature to evaluate the accuracy with which this model can be applied. Common methods of fracture geometry classification are also calculated and compared to experimentally obtained values. Flow through regions of the fracture where the upper and lower fracture walls meet (zero aperture) are shown to induce a strong channeling effect on the flow. This model is expanded to include a domain of surrounding porous media through which the flow can travel. The inclusion of a realistic permeability in this media shows that the regions of small and zero apertures contribute to the greatest pressure losses over the fracture length and flow through the porous media is most prevalent in these regions. The flow through the fracture is shown to be the largest contributor to the net flow through the media. From this work, a novel flow relationship is proposed for flow through fractured media.

Crandall, D.M.; Ahmadi, G. (Clarkson Univ., Potsdam, NY); Smith, D.H.; Bromhal, G.S.

2006-10-01T23:59:59.000Z

357

Main Title 32pt  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electroactive Ionic Liquids: Electroactive Ionic Liquids: A New Approach to Flow Batteries 2. Gallium Nitride Substrates for Power Electronics: Electrochemical Solution Growth Karen Waldrip, PhD Advanced Power Sources R&D Sandia National Labs, Albuquerque, NM knwaldr@sandia.gov Sandia National Laboratories' Programs Electroactive Ionic Liquids: A New Approach To Flow Batteries Date Travis Anderson David Ingersoll Chad Staiger Karen Waldrip Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Flow Batteries *No cross contamination *Flexible layout *High cycle life *Large, tunable capacity *Low maintenance vanadium redox couples are

358

Effect of radial transport on compressor tip clearance flow structures and enhancement of stable flow range  

E-Print Network (OSTI)

The relation between tip clearance flow structure and axial compressor stall is interrogated via numerical simulations, to determine how casing treatment can result in improved flow range. Both geometry changes and flow ...

Nolan, Sean Patrick Rock

2005-01-01T23:59:59.000Z

359

Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology  

SciTech Connect

GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

None

2010-09-01T23:59:59.000Z

360

A laboratory scale supersonic combustive flow system  

DOE Green Energy (OSTI)

A laboratory scale supersonic flow system [Combustive Flow System (CFS)] which utilizes the gaseous products of methane-air and/or liquid fuel-air combustion has been assembled to provide a propulsion type exhaust flow field for various applications. Such applications include providing a testbed for the study of planar two-dimensional nozzle flow fields with chemistry, three-dimensional flow field mixing near the exit of rectangular nozzles, benchmarking the predictive capability of various computational fluid dynamic codes, and the development and testing of advanced diagnostic techniques. This paper will provide a detailed description of the flow system and data related to its operation.

Sams, E.C.; Zerkle, D.K.; Fry, H.A.; Wantuck, P.J.

1995-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Role of structural Fe in nontronite NAu-1 and dissolved Fe(II) in redox transformations of arsenic and antimony  

SciTech Connect

Oxidation state is a major factor affecting the mobility of arsenic (As) and antimony (Sb) in soil and aquatic systems. Metal (hydr)oxides and clay minerals are effective sorbents, and may also promote redox reactions on their surfaces via direct or indirect facilitation of electron transfer. Iron substituted for Al in the octahedral sites of aluminosilicate clay minerals has the potential to be in variable oxidation states and is a key constituent of electron transfer reactions in clay minerals. This experimental work was conducted to determine whether structural Fe in clays can affect the oxidation state of As and Sb adsorbed at the clay surface. Another goal of our study was to compare the reactivity of clay structural Fe(II) with systems containing Fe(II) present in dissolved/adsorbed forms. The experimental systems included batch reactors with various concentrations of As(III), Sb(III), As(V), or Sb(V) equilibrated with oxidized (NAu-1) or partially reduced (NAu-1-Red) nontronite, hydrous aluminum oxide (HAO) and kaolinite (KGa-1b) suspensions under oxic and anoxic conditions. The reaction times ranged from 0.5 to 720 h, and pH was constrained at 5.5 (for As) and at 5.5 or 8.0 (for Sb). The oxidation state of As and Sb in the liquid phase was determined by liquid chromatography in line with an inductively coupled plasma mass spectrometer, and in the solid phase by X-ray absorption spectroscopy. Our findings show that structural Fe(II) in NAu-1-Red was not able to reduce As(V)/Sb(V) under the conditions examined, but reduction was seen when aqueous Fe(II) was present in the systems with kaolinite (KGa-1b) and nontronite (NAu-1). The ability of the structural Fe in nontronite clay NAu-1 to promote oxidation of As(III)/Sb(III) was greatly affected by its oxidation state: if all structural Fe was in the oxidized Fe(III) form, no oxidation was observed; however, when the clay was partially reduced ({approx}20% of structural Fe was reduced to Fe(II)), NAu-1-Red promoted the most extensive oxidation under both oxic and anoxic conditions. Electron balance considerations suggest that structural Fe(III) in the NAu-1-Red was the sole oxidant in the anoxic setup, while dissolved O{sub 2} also contributes in oxic conditions. Long-term batch experiments revealed the complex dynamics of As aqueous speciation in anoxic and oxic systems when reduced arsenic was initially added: rapid disappearance of As(III) was observed due to oxidation to As(V) followed by a slow increase of aqueous As(III). This behavior is explained by two reactions: fast initial oxidation of As(III) by structural Fe(III) (anoxic) or Fe(III) and dissolved O2 (oxic) followed by the slow reduction of As(V) by dissolved Fe(II). The resulting re-mobilization of As due to As(V) reduction by aqueous Fe(II) occurs on time scales on the order of days. These reactions are likely significant in a natural soil or aquifer environment with seasonal cycling or slightly reducing conditions with an abundance of clay minerals and dissolved Fe(II).

Ilgen, Anastasia G.; Foster, Andrea L.; Trainor, Thomas P. (Alaska Fairbanks); (USGS)

2012-11-01T23:59:59.000Z

362

Vertical Flow Wetland Pilot Study  

Science Conference Proceedings (OSTI)

This is an interim report to present the preliminary results of a study conducted by Duke Energy to test the potential effectiveness of vertical flow wetlands (VFWs) for the removal of selenium, mercury, and other related compounds from a flue gas desulfurization (FGD) discharge. These compounds commonly are found in and regulated for coal-fired utility water discharges. There is a widespread need for a cost-effective alternative to physiochemical treatment to maintain compliance for these parameters, on...

2008-12-08T23:59:59.000Z

363

Economics of Increased Power Flow  

Science Conference Proceedings (OSTI)

This report focuses on methodologies for evaluating the costs and benefits of the diverse technologies that can be used either individually or jointly to increase the flow of power through the transmission system. It begins by describing a broad slate of potential technologies and approaches for increasing transmission capacity and improving system efficiency and then provides an overall framework for assessing the benefits and costs of these technologies. Later sections cover the practical implementatio...

2010-12-21T23:59:59.000Z

364

Flow duct for nuclear reactors  

DOE Patents (OSTI)

Improved liquid sodium flow ducts for nuclear reactors are described wherein the improvement comprises varying the wall thickness of each of the walls of a polygonal tubular duct structure so that each of the walls is of reduced cross-section along the longitudinal center line and of a greater cross-section along wall junctions with the other walls to form the polygonal tubular configuration.

Straalsund, Jerry L. (Richland, WA)

1978-01-01T23:59:59.000Z

365

Countercurrent flow absorber and desorber  

DOE Patents (OSTI)

Countercurrent flow absorber and desorber devices are provided for use in absorption cycle refrigeration systems and thermal boosting systems. The devices have increased residence time and surface area resulting in improved heat and mass transfer characteristics. The apparatuses may be incorporated into open cycle thermal boosting systems in which steam serves both as the refrigerant vapor which is supplied to the absorber section and as the supply of heat to drive the desorber section of the system. 9 figs.

Wilkinson, W.H.

1984-10-16T23:59:59.000Z

366

The hidden geometry of ocean flows  

E-Print Network (OSTI)

We introduce a new global Lagrangian descriptor that is applied to flows with general time dependence (altimetric datasets). It succeeds in detecting simultaneously, with great accuracy, invariant manifolds, hyperbolic and non-hyperbolic flow regions.

Carolina Mendoza; Ana M Mancho

2010-03-01T23:59:59.000Z

367

Deep-Flow Variability at Drake Passage  

Science Conference Proceedings (OSTI)

A rotary empirical orthogonal function analysis of the currents measured in central Drake Passage during DRAKE 79 shows that the deep (2500 m) flow has the same spatial and temporal structure as the flow at 500 m, suggesting that current ...

John M. Klinck; Eileen E. Hofmann

1986-07-01T23:59:59.000Z

368

Flow interference in bluff body wakes  

Science Conference Proceedings (OSTI)

This paper presents a two-dimensional numerical simulation of fluid flow around a couple of identical circular cylinders aligned, respectively, along and orthogonal to the main-flow direction, at several distances. A lattice-Boltzmann method (LB) is ...

Rodrigo Surmas; Luís Orlando Emerich Dos Santos; Paulo Cesar Philippi

2003-06-01T23:59:59.000Z

369

Regional Drainage Flows in the Pacific Northwest  

Science Conference Proceedings (OSTI)

An analysis of regional drainage flows in the Pacific Northwest is presented using results from a network of surface observations and a series of simulations carried out with a nested mesoscale model. The flows, which occur regularly in ...

J. C. Doran; S. Zhong

1994-06-01T23:59:59.000Z

370

Preservation of probabilistic information flow under refinement  

Science Conference Proceedings (OSTI)

Information flow properties, which describe confidentiality requirements, are not generally preserved under behavior refinement. This article describes a formal framework for refinement relations between nondeterministic probabilistic processes that ... Keywords: CSP, Confidentiality, Information flow property, Information theory, Process calculus, Refinement, Security

Thomas Santen

2008-02-01T23:59:59.000Z

371

Turbulent Channel Flows on a Rotating Earth  

Science Conference Proceedings (OSTI)

This paper deals with flow in a rectilinear channel on a rotating earth. The flow is directed perpendicular to the background planetary vorticity; both an analytical theory and numerical simulations are employed. The analytical approach assumes ...

Robert A. Handler; Richard P. Mied; Gloria J. Lindemann; Thomas E. Evans

2009-04-01T23:59:59.000Z

372

Information Flow in Ensemble Weather Predictions  

Science Conference Proceedings (OSTI)

In a weather prediction, information flows from the initial conditions to a later prediction. The uncertainty in the initial conditions implies that such a flow should be quantified with tools from probability theory. Using several recent ...

Richard Kleeman

2007-03-01T23:59:59.000Z

373

Turbulent Mixing in Stably Stratified Shear Flows  

Science Conference Proceedings (OSTI)

Vertical mixing of momentum and heat is investigated in turbulent stratified shear flows. It is assumed that the flow has uniform shear and stratification with homogeneous turbulence and that an equilibrium is reached between kinetic and ...

U. Schumann; T. Gerz

1995-01-01T23:59:59.000Z

374

Optical flow using phase information for deblurring  

E-Print Network (OSTI)

This thesis presents a method for reconstructing motion-degraded images by using velocity information generated with a phase-based optical flow calculation. The optical flow method applies a set of frequency-tuned Gabor ...

Texin, Cheryl (Cheryl A.)

2007-01-01T23:59:59.000Z

375

Apparatus for monitoring two-phase flow  

DOE Patents (OSTI)

A method and apparatus for monitoring two-phase flow is provided that is particularly related to the monitoring of transient two-phase (liquid-vapor) flow rates such as may occur during a pressurized water reactor core blow-down. The present invention essentially comprises the use of flanged wire screens or similar devices, such as perforated plates, to produce certain desirable effects in the flow regime for monitoring purposes. One desirable effect is a measurable and reproducible pressure drop across the screen. The pressure drop can be characterized for various known flow rates and then used to monitor nonhomogeneous flow regimes. Another useful effect of the use of screens or plates in nonhomogeneous flow is that such apparatus tends to create a uniformly dispersed flow regime in the immediate downstream vicinity. This is a desirable effect because it usually increases the accuracy of flow rate measurements determined by conventional methods.

Sheppard, John D. (Oak Ridge, TN); Tong, Long S. (Gaithersburg, MD)

1977-03-01T23:59:59.000Z

376

Stratified Tidal Flow over a Bump  

Science Conference Proceedings (OSTI)

The interaction of a stratified flow with an isolated topographic feature can introduce numerous disturbances into the flow, including turbulent wakes, internal waves, and eddies. Measurements made near a “bump” east of Race Rocks, Vancouver ...

Richard Dewey; David Richmond; Chris Garrett

2005-10-01T23:59:59.000Z

377

Large Scale Simulation of Particulate Flows  

Science Conference Proceedings (OSTI)

Simulations of particles in fluid flows are of great interest to numerous industries using sedimentation, fluidization, lubricated transport, and hydraulic fracturing of hydrocarbon reservoirs. Simulating incompressible viscoelastic flows with millions ...

Ahmed H. Sameh; Vivek Sarin

1999-04-01T23:59:59.000Z

378

A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements  

Open Energy Info (EERE)

Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Details Activities (0) Areas (0) Regions (0) Abstract: A comprehensive database of temperature, heat flow, thermal conductivity and geochemistry is the basis of geothermal modelling. The latest revision (1987) of the UK Geothermal Catalogue (UKGC) contains over 2600 temperatures at over 1150 sites and over 200 observations of heat flow. About 93% of the temperature data are from depths less than 2000 m and about 50% are Bottom Hole Temperatures (BHT). Heat-flow density

379

NETL: Gasifipedia - Entrained Flow Gasifiers  

NLE Websites -- All DOE Office Websites (Extended Search)

Entrained Flow Gasifiers Entrained Flow Gasifiers Uhde - Prenflo PRENFLO(tm) is a pressurized (>40 bar), entrained-flow gasification technology first demonstrated in the late 1980s, and currently offered by Uhde (Krupp Koppers merged with Uhde in 1997). Notably, PRENFLO(tm) is the gasification technology used at the world's largest solid feedstock-based gasifier at ELCOGAS's Puertollano IGCC plant in Spain (which is fueled with a 50%/50% mix of petcoke and coal). PRENFLO(tm) is offered in two varieties, the PRENFLO(tm) PSG (with steam generation) depicted in Figures 1 & 2, and PRENFLO(tm) PDQ (direct quench) as depicted in Figures 3 & 4. The gasifier conditions and feed characteristics are similar, but PRENFLO(tm) PSG includes an integrated waste heat boiler and uses compressed recirculated quench gas as illustrated in Figure 2, resulting in relatively low moisture raw syngas at relatively high exit temperature. PRENFLO(tm) PDQ uses direct quench, resulting in considerably lower raw syngas exit temperature (200-250°C) which is saturated. Uhde notes that PDQ has lower investment cost and shorter construction and supply schedule than PSG, though this would be at the performance expense of somewhat lower thermal efficiency and slightly higher concentration of CO2 in raw syngas.

380

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Hanford Site, USA  

Science Conference Proceedings (OSTI)

Technetium is an important environmental contaminant introduced by the processing and disposal of irradiated nuclear fuel and atmospheric nuclear tests. Under oxic conditions technetium is soluble and exists as pertechnatate anion (TcO4-), while under anoxic conditions Tc is usually insoluble and exists as precipitated Tc(IV). Here we investigated abiotic Tc(VII) reduction in mineralogically heterogeneous, Fe(II)-containing sediments. The sediments were collected from a 55 m borehole that sampled a semi-confined aquifer at the Hanford Site, USA that contained a dramatic redox transition zone. One oxic facies (18.0-18.3 m) and five anoxic facies (18.3-18.6 m, 30.8-31.1 m, 39.0-39.3 m, 47.2-47.5 m and 51.5-51.8 m) were selected for this study. Chemical extractions, X-ray diffraction, electron microscopy, and Mössbauer spectroscopy were applied to characterize the Fe(II) mineral suite that included: Fe(II)-phyllosilicates, pyrite, magnetite and siderite. The Fe(II) mineral phase distribution differed between the sediments. Sediment suspensions were adjusted to the same 0.5 M HCl extracted Fe(II) concentration (0.6 mM) for Tc(VII) reduction experiments. Aqueous Fe was low in all sediment suspensions (Technetium(VII) reduction occurred in all anoxic sediments at depths greater than 18.3 m and reaction time differed significantly between the sediments (8-219 d). Mössbauer analysis of the Tc-reacted, 30.8-31.1 m sediment confirmed that Tc(VII) was reduced by solid-phase Fe(II), with siderite and Fe(II)-containing phyllosilicates implicated as redox reactive phases. Technetium-XAS analysis demonstrated that Tc associated with sediments was in the Tc(IV) valence state and immobilized as clusters of a TcO2·nH2O-like phase. The speciation of redox product Tc(IV) was not affected by reduction rate or Fe(II) mineralogy.

Peretyazhko, Tetyana; Zachara, John M.; Kukkadapu, Ravi K.; Heald, Steve M.; Kutnyakov, Igor V.; Resch, Charles T.; Arey, Bruce W.; Wang, Chong M.; Kovarik, Libor; Phillips, Jerry L.; Moore, Dean A.

2012-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Anisotropic collective flow of a Lorentz gas  

E-Print Network (OSTI)

Analytical results for the anisotropic collective flow of a Lorentz gas of massless particles scattering on fixed centres are presented.

Nicolas Borghini; Clement Gombeaud

2011-06-29T23:59:59.000Z

382

Toeplitz CAR flows and type I factorizations  

E-Print Network (OSTI)

Toeplitz CAR flows are a class of E_0-semigroups including the first type III example constructed by R. T. Powers. We show that the Toeplitz CAR flows contain uncountably many mutually non cocycle conjugate E_0-semigroups of type III. We also generalize the type III criterion for Toeplitz CAR flows employed by Powers (and later refined by W. Arveson), and show that Toeplitz CAR flows are always either of type I or type III.

Izumi, Masaki

2009-01-01T23:59:59.000Z

383

Multiphase Turbulent Flow Ken Kiger -UMCP  

E-Print Network (OSTI)

of the dispersion: · Size & geometry · Volume fraction #12;Bubbly Pipe Flow ­ heat exchangers in power plants, A/C units Gas-Liquid Flow #12;Aeration: -produced by wave action - used as reactor in chemical processing delivery Liquid-Gas Flow http://www.mywindpowersystem.com/2009/07/wind-power-when-nature

Gruner, Daniel S.

384

Hydromagnetic Instability in Differentially Rotating Flows  

E-Print Network (OSTI)

We study the stability of a compressible differentially rotating flows in the presence of the magnetic field, and we show that the compressibility profoundly alters the previous results for a magnetized incompressible flow. The necessary condition of newly found instability can be easily satisfied in various flows in laboratory and astrophysical conditions and reads $B_{s} B_{\\phi} \\Omega' \

Bonanno, A

2006-01-01T23:59:59.000Z

385

Pebble Flow Experiments For Pebble Bed Reactors  

E-Print Network (OSTI)

Pebble Flow Experiments For Pebble Bed Reactors Andrew C. Kadak1 Department of Nuclear Engineering of Technology 2nd International Topical Meeting on High Temperature Reactor Technology Institute of Nuclear in such a reactor would conform to granular flow theory which suggested rapid mixing as opposed to linear flow lines

Bazant, Martin Z.

386

Liquid cooled counter flow turbine bucket  

DOE Patents (OSTI)

Means and a method are provided whereby liquid coolant flows radially outward through coolant passages in a liquid cooled turbine bucket under the influence of centrifugal force while in contact with countercurrently flowing coolant vapor such that liquid is entrained in the flow of vapor resulting in an increase in the wetted cooling area of the individual passages.

Dakin, James T. (Schenectady, NY)

1982-09-21T23:59:59.000Z

387

ESS 2012 Peer Review - Flow Battery Solution for Smart Grid Renewable Energy Applications - Sheri Nevins, Raytheon & Ron Moss, EnerVault  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 1 Sheri Nevins Raytheon Ktech Ron Mosso EnerVault Corporation DEMONSTRATION OF ENERGY STORAGE USING A BREAKTHROUGH REDOX FLOW BATTERY TECHNOLOGY v. 1-0 Copyright ©2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 2 Disclaimer This material is partially based upon work supported by NYSERDA under PON1200 Project 15880 NYSERDA has not reviewed the information contained herein, and the opinions expressed in this report do not necessarily reflect those of NYSERDA or the State of New York. This material is partially based upon work supported by the Department of Energy under Award Number DE-OE0000225. This report was prepared as an account of work sponsored by an agency of the United States

388

Flow dynamics and solute transport in unsaturated rock fractures  

E-Print Network (OSTI)

and H. Brenner, Multiphase flow in porous media, Ann. Rev.to describe multiphase flow in porous media, involvingflow in porous media, can be generalized for multiphase flow

Su, G.W.

2011-01-01T23:59:59.000Z

389

Understanding the redox shuttle stability of 3,5-di-tert-butyl-1,2-dimethoxybenzene for overcharge protection of lithium-ion batteries.  

DOE Green Energy (OSTI)

3,5-di-tert-butyl-1,2-dimethoxybenzene (DBDB) has been synthesized as a new redox shuttle additive for overcharge protection of lithium-ion batteries. DBDB can easily dissolve in carbonate-based electrolytes, which facilitates its practical use in lithium-ion batteries; however, it has poor electrochemical stability compared to 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB). The structures of DBDB and DDB were investigated using X-ray crystallography and density functional calculations. The structures differ in the conformations of the alkoxy bonds probably due to the formation of an intramolecular hydrogen bond in the case of DBDB. We investigated reaction energies for decomposition pathways of neutral DBDB and DDB and their radical cations and found little difference in the reaction energies, although it is clear that kinetically, decomposition of DBDB is more favorable.

Zhang, Z.; Zhang, L.; Schlueter, J. A.; Redfern, P. C.; Curtiss, L.; Amine, K.

2010-01-01T23:59:59.000Z

390

Charge-transfer interfaces between metal and redox arylamine molecular films: As probed with anode interfacial engineering approach in single-layer organic diodes  

E-Print Network (OSTI)

We investigate the charge-transfer interfaces between metal and redox arylamine molecular films through studying the current-voltage characteristics of single-layer organic diodes with the aid of anode interfacial engineering method. The diode turn-on voltage is shown to be highly sensitive to the arylamine/metal charge-transfer interfaces and thus can serve as a probe in detecting such organic/metal interfaces. We show that the diode electrical performance could be tuned through engineering the arylamine/metal interfaces via controlling the factors of anode work function, arylamine substitute groups, and active layer surface morphology etc. The conduction mechanism of the diodes is shown to be injection limited, which could be well described with Richardson-Schottky thermonic emission model. Our work may provide some insight into the use of single-layer organic diode and interfacial engineering method to rapidly probe the organic/metal and even organic/organic charge-transfer interfaces.

J. C. Li; S. C. Blackstock; G. J. Szulczewski

2005-08-19T23:59:59.000Z

391

Self-regulating flow control device  

DOE Patents (OSTI)

A variable, self-regulating valve having a hydraulic loss coefficient proportional to a positive exponential power of the flow rate. The device includes two objects in a flow channel and structure which assures that the distance between the two objects is an increasing function of the flow rate. The range of spacing between the objects is such that the hydraulic resistance of the valve is an increasing function of the distance between the two objects so that the desired hydraulic loss coefficient as a function of flow rate is obtained without variation in the flow area.

Humphreys, Duane A. (Pittsburgh, PA)

1984-01-01T23:59:59.000Z

392

Automated flow-temperature-humidity control system  

SciTech Connect

An automated system that controls air flow, temperature, and humidity was developed from a commercially available temperature-humidity indicator and a specially built flow-temperature-humidity control module. Parameters are set using direct-reading dials on the control module. The air flow is maintained using a mass-flow controller while process controllers connected to the indicator regulate humidity and temperature. The system will run indefinitely without need for operator intervention. If the module and indicator are calibrated properly, accurate air flows (+-2% of full scale), temperatures (+-0.3/sup 0/C), and humidities (+-2% RH) can be achieved.

Nelson, G.O.; Taylor, R.D.

1980-10-01T23:59:59.000Z

393

Chemical preconcentrator with integral thermal flow sensor  

DOE Patents (OSTI)

A chemical preconcentrator with integral thermal flow sensor can be used to accurately measure fluid flow rate in a microanalytical system. The thermal flow sensor can be operated in either constant temperature or constant power mode and variants thereof. The chemical preconcentrator with integral thermal flow sensor can be fabricated with the same MEMS technology as the rest of the microanlaytical system. Because of its low heat capacity, low-loss, and small size, the chemical preconcentrator with integral thermal flow sensor is fast and efficient enough to be used in battery-powered, portable microanalytical systems.

Manginell, Ronald P. (Albuquerque, NM); Frye-Mason, Gregory C. (Cedar Crest, NM)

2003-01-01T23:59:59.000Z

394

Liquid hydrogen flow problems in Kiwi reactors  

DOE Green Energy (OSTI)

The Kiwi series of reactors were the first ones tested in the US Rover Program in the development of nuclear rocket engines for space propulsion. The early experiments with liquid hydrogen showed that parallel flow systems were prone to uneven flow distributions and violent fluctuations in pressure and flow that were capable of destroying a reactor core. Kiwi flow distribution problems were solved by using multiple feed lines into the nozzle cooling system and carefully balancing impedance among them. The violent pressure and flow fluctuations were eliminated after their cause was identified as resonance phenomena driven by the response to flow disturbances of heat transfer through a superheated hydrogen layer. Smooth flow operations were assured by rapidly bringing operating pressures beyond several times the critical pressure of hydrogen. After this initial rough start, solid core nuclear rocket engines successfully passed milestones of achievements during the remainder of the Rover program.

Thurston, R.S.

1992-09-01T23:59:59.000Z

395

Momentum Transport in Granular Flows  

E-Print Network (OSTI)

We investigate the error induced by only considering binary collisions in the momentum transport of hard-sphere granular materials, as is done in kinetic theories. In this process, we first present a general microscopic derivation of the momentum transport equation and compare it to the kinetic theory derivation, which relies on the binary collision assumption. These two derivations yield different microscopic expressions for the stress tensor, which we compare using simulations. This provides a quantitative bound on the regime where binary collisions dominate momentum transport and reveals that most realistic granular flows occur in the region of phase space where the binary collision assumption does not apply.

Gregg Lois; Anael Lemaitre; Jean M. Carlson

2006-02-10T23:59:59.000Z

396

DECORRELATION TIMES OF PHOTOSPHERIC FIELDS AND FLOWS  

SciTech Connect

We use autocorrelation to investigate evolution in flow fields inferred by applying Fourier local correlation tracking (FLCT) to a sequence of high-resolution (0.''3), high-cadence ({approx_equal} 2 minute) line-of-sight magnetograms of NOAA active region (AR) 10930 recorded by the narrowband filter imager of the Solar Optical Telescope aboard the Hinode satellite over 2006 December 12 and 13. To baseline the timescales of flow evolution, we also autocorrelated the magnetograms, at several spatial binnings, to characterize the lifetimes of active region magnetic structures versus spatial scale. Autocorrelation of flow maps can be used to optimize tracking parameters, to understand tracking algorithms' susceptibility to noise, and to estimate flow lifetimes. Tracking parameters varied include: time interval {Delta}t between magnetogram pairs tracked, spatial binning applied to the magnetograms, and windowing parameter {sigma} used in FLCT. Flow structures vary over a range of spatial and temporal scales (including unresolved scales), so tracked flows represent a local average of the flow over a particular range of space and time. We define flow lifetime to be the flow decorrelation time, {tau}. For {Delta}t > {tau}, tracking results represent the average velocity over one or more flow lifetimes. We analyze lifetimes of flow components, divergences, and curls as functions of magnetic field strength and spatial scale. We find a significant trend of increasing lifetimes of flow components, divergences, and curls with field strength, consistent with Lorentz forces partially governing flows in the active photosphere, as well as strong trends of increasing flow lifetime and decreasing magnitudes with increases in both spatial scale and {Delta}t.

Welsch, B. T. [Space Sciences Laboratory, University of California, Berkeley, CA 94720-7450 (United States); Kusano, K.; Yamamoto, T. T. [Solar Terrestrial Environment Laboratory, Nagoya University Furo-cho, Chikusa-ku, Nagoya 464-8601 (Japan); Muglach, K. [Code 674, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2012-03-10T23:59:59.000Z

397

The Pandora Particle Flow Algorithm  

E-Print Network (OSTI)

A high-energy e+e- collider, such as the ILC or CLIC, is arguably the best option to complement and extend the LHC physics programme. A lepton collider will allow for exploration of Standard Model Physics, such as precise measurements of the Higgs, top and gauge sectors, in addition to enabling a multitude of New Physics searches. However, physics analyses at such a collider will place unprecedented demands on calorimetry, with a required jet energy resolution of \\sigma(E)/E energy resolution by fully reconstructing the paths of individual particles through the detector. The energies of charged particles can then be extracted from precise inner detector tracker measurements, whilst photon energies will be measured in the ECAL, and only neutral hadron energies (10% of jet energies) will be measured in the HCAL, largely avoiding the typically poor HCAL resolution. This document introduces the Pandora particle flow algorithms, which offer the current state of the art in particle flow calorimetry for the ILC and CLIC. The performance of the algorithms is investigated by examining the reconstructed jet energy resolution and the ability to separate the hadronic decays of W and Z bosons.

J. S. Marshall; M. A. Thomson

2013-08-21T23:59:59.000Z

398

DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS  

SciTech Connect

In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in which flow regime transition occurs.

X. Wang; X. Sun; H. Zhao

2011-09-01T23:59:59.000Z

399

Thin films flowing down inverted substrates: two dimensional flow  

E-Print Network (OSTI)

We consider free surface instabilities of films flowing on inverted substrates within the framework of lubrication approximation. We allow for the presence of fronts and related contact lines, and explore the role which they play in instability development. It is found that a contact line, modeled by a commonly used precursor film model, leads to free surface instabilities of convective type without any additional natural or excited perturbations. A single parameter D=(3Ca)^{1/3}cot\\alpha, where Ca is the capillary number and \\alpha is the inclination angle, is identified as a governing parameter in the problem. This parameter may be interpreted to reflect the combined effect of inclination angle, film thickness, Reynolds number and the fluid flux. Variation of D leads to change of the wave-like properties of the instabilities, allowing to observe traveling wave behavior, mixed waves, and the waves resembling solitary ones.

Lin, Te-sheng

2009-01-01T23:59:59.000Z

400

Advances in gas-liquid flows 1990  

SciTech Connect

Gas-liquid two-phase flows commonly occur in nature and industrial applications. Rain, clouds, geysers, and waterfalls are examples of natural gas-liquid flow phenomena, whereas industrial applications can be found in nuclear reactors, steam generators, boilers, condensers, evaporators, fuel atomization, heat pipes, electronic equipment cooling, petroleum engineering, chemical process engineering, and many others. The household-variety phenomena such as garden sprinklers, shower, whirlpool bath, dripping faucet, boiling tea pot, and bubbling beer provide daily experience of gas-liquid flows. The papers presented in this volume reflect the variety and richness of gas-liquid two-phase flow and the increasing role it plays in modern technology. This volume contains papers dealing with some recent development in gas-liquid flow science and technology, covering basic gas-liquid flows, measurements and instrumentation, cavitation and flashing flows, countercurrent flow and flooding, flow in various components and geometries liquid metals and thermocapillary effects, heat transfer, nonlinear phenomena, instability, and other special and general topics related to gas-liquid flows.

Kim, J.M. (Texas Univ., Austin, TX (United States). Nuclear Reactor Lab.); Rohatgi, U.S. (Brookhaven National Lab., Upton, NY (United States)); Hashemi, A. (Lockheed Missiles and Space Company (US))

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A constitutive law for dense granular flows  

E-Print Network (OSTI)

A continuum description of granular flows would be of considerable help in predicting natural geophysical hazards or in designing industrial processes. However, the constitutive equations for dry granular flows, which govern how the material moves under shear, are still a matter of debate. One difficulty is that grains can behave like a solid (in a sand pile), a liquid (when poured from a silo) or a gas (when strongly agitated). For the two extreme regimes, constitutive equations have been proposed based on kinetic theory for collisional rapid flows, and soil mechanics for slow plastic flows. However, the intermediate dense regime, where the granular material flows like a liquid, still lacks a unified view and has motivated many studies over the past decade. The main characteristics of granular liquids are: a yield criterion (a critical shear stress below which flow is not possible) and a complex dependence on shear rate when flowing. In this sense, granular matter shares similarities with classical visco-plastic fluids such as Bingham fluids. Here we propose a new constitutive relation for dense granular flows, inspired by this analogy and recent numerical and experimental work. We then test our three-dimensional (3D) model through experiments on granular flows on a pile between rough sidewalls, in which a complex 3D flow pattern develops. We show that, without any fitting parameter, the model gives quantitative predictions for the flow shape and velocity profiles. Our results support the idea that a simple visco-plastic approach can quantitatively capture granular flow properties, and could serve as a basic tool for modelling more complex flows in geophysical or industrial applications.

Pierre Jop; Yoël Forterre; Olivier Pouliquen

2006-12-05T23:59:59.000Z

402

Potential Flow Calculations of Axisymmetric Ducted Wind Turbines  

E-Print Network (OSTI)

An incompressible potential-flow vortex method has been constructed to analyze the flow field of a ducted

Widnall, Sheila

2009-09-02T23:59:59.000Z

403

NIST Pipeline-Scale Flow Measurement Standards for Natural ...  

Science Conference Proceedings (OSTI)

Pipeline-Scale Flow Measurement Standards for Natural Gas. Summary: NIST natural gas flow calibrations are performed ...

2013-01-28T23:59:59.000Z

404

Simulation of air flow in the typical boiler windbox segments  

Science Conference Proceedings (OSTI)

Simulation of turbulent air flow distribution in CFBC furnace, wherein primary air is entrained through inlet duct system called windbox, is attempted through state of art CAD/CFD softwares. Establishment of flow in windbox channel, distributed plate ... Keywords: CFBC boiler, air flow, combustor geometry, distributed plate nozzles, multi-block grids, recirculation flow, simulation of flow, unequal air flow, windbox channel

C. Bhasker

2002-12-01T23:59:59.000Z

405

A summary report on feed preparation offgas and glass redox data for Hanford waste vitrification plant: Letter report  

DOE Green Energy (OSTI)

Tests to evaluate feed processing options for the Hanford Waste Vitrification Plant (HWVP) were conducted by a number of investigators, and considerable data were acquired for tests of different scale, including recent full-scale tests. In this report, a comparison was made of the characteristics of feed preparation observed in tests of scale ranging from 57 ml to full-scale of 28,000 liters. These tests included Pacific Northwest Laboratory (PNL) laboratory-scale tests, Kernforschungszentrums Karlsruhe (KfK) melter feed preparation, Research Scale Melter (RSM) feed preparation, Integrated DWPF Melter System (IDMS) feed preparation, Slurry Integrated Performance Testing (SIPT) feed preparation, and formic acid addition to Hanford Neutralized Current Acid Waste (NCAW) care samples.` The data presented herein were drawn mainly from draft reports and include system characteristics such as slurry volume and depth, sweep gas flow rate, headspace, and heating and stirring characteristics. Operating conditions such as acid feed rate, temperature, starting pH, final pH, quantities and type of frit, nitrite, nitrate, and carbonate concentrations, noble metal content, and waste oxide loading were tabulated. Offgas data for CO{sub 2}, NO{sub x}, N{sub 2}O, NO{sub 2}, H{sub 2} and NH{sub 3} were tabulated on a common basis. Observation and non-observation of other species were also noted.

Merz, M.D.

1996-03-01T23:59:59.000Z

406

LLNL Energy Flow Charts | Open Energy Information  

Open Energy Info (EERE)

LLNL Energy Flow Charts LLNL Energy Flow Charts Jump to: navigation, search Tool Summary Name: LLNL Energy Flow Charts Agency/Company /Organization: Lawrence Livermore National Lab Sector: Energy Focus Area: Renewable Energy Topics: Pathways analysis References: LLNL Energy Flow Charts [1] Decision makers have long recognized the importance of visualizing energy and material flows in a way that distinguishes between resources, transformations and services. Research priorities can be defined in terms of changes to the flows, and the consequences of policy or technology shifts can be traced both upstream and downstream. The usefulness of this top-down view is limited by the level of detail that can be conveyed in a single image. We use two techniques to balance information content with readability. First we employe visualization

407

NETL: Gasifipedia - Entrained Flow Gasifiers  

NLE Websites -- All DOE Office Websites (Extended Search)

Siemens Gasifier Siemens Gasifier (source: Siemens) Siemens Gasifiers Siemens gasification technology was originally developed by Deutsches Brennstoffinstitut (DBI) in Freiberg, Germany for the gasification of pulverized local brown coal and other solid feedstocks in 1975. The Noell group acquired the technology in 1991 and developed it further to handle liquid residues and wastes. The gasifier also operated under the name of Babcock Borsig and Future Energy before being acquired by Siemens in 2006. Operation The Siemens gasifier is a dry-feed, pressurized, entrained-flow reactor, which can be supplied with either a refractory lining for low ash feedstocks or with a cooling screen in the gasification section of the gasifier. The cooling screen consists of a gas-tight membrane wall

408

Phase-sensitive flow cytometer  

DOE Patents (OSTI)

This report describes phase-sensitive flow cytometer (FCM) which provides additional FCM capability to use the fluorescence lifetime of one or more fluorochromes bound to single cells to provide additional information regarding the cells. The resulting fluorescence emission can be resolved into individual fluorescence signals if two fluorochromes are present or can be converted directly to a decay lifetime from a single fluorochrome. The excitation light for the fluorochromes is modulated to produce an amplitude modulated fluorescence pulse as the fluorochrome is excited in the FCM. The modulation signal also forms a reference signal that is phase-shifted a selected amount for subsequent mixing with the output modulated fluorescence intensity signal in phase-sensitive detection circuitry. The output from the phase-sensitive circuitry is then an individual resolved fluorochrome signal or a single fluorochrome decay lifetime, depending on the applied phase shifts.

Steinkamp, J.A.

1992-12-31T23:59:59.000Z

409

Flow cytometer jet monitor system  

DOE Patents (OSTI)

A direct jet monitor illuminates the jet of a flow cytometer in a monitor wavelength band which is substantially separate from the substance wavelength band. When a laser is used to cause fluorescence of the substance, it may be appropriate to use an infrared source to illuminate the jet and thus optically monitor the conditions within the jet through a CCD camera or the like. This optical monitoring may be provided to some type of controller or feedback system which automatically changes either the horizontal location of the jet, the point at which droplet separation occurs, or some other condition within the jet in order to maintain optimum conditions. The direct jet monitor may be operated simultaneously with the substance property sensing and analysis system so that continuous monitoring may be achieved without interfering with the substance data gathering and may be configured so as to allow the front of the analysis or free fall area to be unobstructed during processing.

Van den Engh, Ger (Seattle, WA)

1997-01-01T23:59:59.000Z

410

Phase-sensitive flow cytometer  

DOE Patents (OSTI)

A phase-sensitive flow cytometer (FCM) provides additional FCM capability to use the fluorescence lifetime of one or more fluorochromes bound to single cells to provide additional information regarding the cells. The resulting fluorescence emission can be resolved into individual fluorescence signals if two fluorochromes are present or can be converted directly to a decay lifetime from a single fluorochrome. The excitation light for the fluorochromes is modulated to produce an amplitude modulated fluorescence pulse as the fluorochrome is excited in the FCM. The modulation signal also forms a reference signal that is phase-shifted a selected amount for subsequent mixing with the output modulated fluorescence intensity signal in phase-sensitive detection circuitry. The output from the phase-sensitive circuitry is then an individual resolved fluorochrome signal or a single fluorochrome decay lifetime, depending on the applied phase shifts. 15 figures.

Steinkamp, J.A.

1993-12-14T23:59:59.000Z

411

The gradient flow in a twisted box  

E-Print Network (OSTI)

We study the perturbative behavior of the gradient flow in a twisted box. We apply this information to define a running coupling using the energy density of the flow field. We study the step-scaling function and the size of cutoff effects in SU(2) pure gauge theory. We conclude that the twisted gradient flow running coupling scheme is a valid strategy for step-scaling purposes due to the relatively mild cutoff effects and high precision.

Ramos, A

2013-01-01T23:59:59.000Z

412

Segregation of granular particles in suspension flow  

E-Print Network (OSTI)

An experiment was conducted to investigate the development of longitudinal stripes of granular particles due to instabilities in particle suspension flow. Research was conducted to characterize environmental phenomena ...

Tsay, Jessica, 1983-

2004-01-01T23:59:59.000Z

413

Geothermal: Sponsored by OSTI -- Geologic flow characterization...  

Office of Scientific and Technical Information (OSTI)

Geologic flow characterization using tracer techniques Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us | Admin Log On HomeBasic Search About...

414

Flow-Through Electrode Capacitive Desalination  

LLNL has developed an innovative technology known as flow-through electrode capacitive desalination (FTE-CD) that promises to unlock an almost ...

415

NETL: News Release - Keeping Deepwater Pipelines Flowing  

NLE Websites -- All DOE Office Websites (Extended Search)

remediation problem for offshore oil producers. Wax deposits can restrict the flow of crude oil and natural gas liquids, curtailing operations from offshore platforms that can...

416

Materials Sustainability: Digital Resource Center - Flow Studies ...  

Science Conference Proceedings (OSTI)

Jun 26, 2008 ... This 2004 circular presents the results of flow studies for recycling of 26 metal commodities, including chromium, magnesium, niobium, ...

417

Probabilistic computation of Poiseuille flow velocity fields  

Science Conference Proceedings (OSTI)

... pipe flux in the “analog” flow problem. ... the torsional rigidity and the cross sectional shape ... we note applications involving heat transfer through pipes ...

2013-07-10T23:59:59.000Z

418

Entrained Flow Gasification of Oil Sand Coke.  

E-Print Network (OSTI)

??The effect of blending woody biomass material with fluid coke and coal on the co-pyrolysis process was investigated in an entrained flow gasifier. The SEM… (more)

Vejahati, Farshid

2012-01-01T23:59:59.000Z

419

VALIDATING UNCERTAINTY ANALYSES FOR GAS FLOW ...  

Science Conference Proceedings (OSTI)

... tank volume to obtain the initial and final mass of gas in the tank ... during a crossover test, but laminar flow elements (LFE) and turbine flowmeters are ...

2012-11-03T23:59:59.000Z

420

Concerted Flows: Infrastructure for Terabits Data Networks |...  

NLE Websites -- All DOE Office Websites (Extended Search)

Concerted Flows: Infrastructure for Terabits Data Networks High-performance application use of emerging 100G networks and future terabit networks will require substantial and...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Flow visualisation in inclined louvered fins  

Science Conference Proceedings (OSTI)

In this study the flow within an interrupted fin design, the inclined louvered fin, is investigated experimentally through visualisation. The inclined louvered fin is a hybrid of the offset strip fin and standard louvered fin, aimed at improved performance at low Reynolds numbers for compact heat exchangers. The flow behaviour is studied in six geometrically different configurations over a range of Reynolds numbers and quantified using the concept of 'fin angle alignment factor'. The transition from steady laminar to unsteady flow was studied in detail. The fin geometry had a very large impact on the transitional flow behaviour, especially on vortex shedding. (author)

T'Joen, C.; De Paepe, M. [Department of Flow, Heat and Combustion Mechanics, Ghent University-UGent, Sint-Pietersnieuwstraat 41, 9000 Gent (Belgium); Jacobi, A. [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 1206 West Green Street, Urbana, IL 61801 (United States)

2009-04-15T23:59:59.000Z

422

Algebraic Characterizations of Flow-Network Typings  

E-Print Network (OSTI)

A flow network N is a capacited finite directed graph, with multiple input ports/arcs and multiple output ports/arcs. A flow f in N assigns a non-negative real number to every arc and is feasible if it satisfies flow conservation at every node and respects lower-bound/upper-bound capacities at every arc. We develop an algebraic theory of feasible flows in such networks with several beneficial consequences. We define algorithms to infer, from a given flow network N, an algebraic classification, which we call a typing for N, of all assignments f0 of values to the input and output arcs of N that can be extended to a feasible flow f. We then establish necessary and sufficient conditions on an arbitrary typing T guaranteeing that T is a valid typing for some flow network N. Based on these necessary and sufficient conditions, we define operations on typings that preserve their validity (to be typings for flow networks), and examine the implications for a typing theory of flow networks.

Assaf Kfoury

2012-01-01T23:59:59.000Z

423

Liquid flow through a reactive packed bed.  

E-Print Network (OSTI)

??The flow phenomena of liquid iron and slag in the lower zone of an iron making blast furnace influences the permeability of the coke bed,… (more)

George, Hazem Labib

2013-01-01T23:59:59.000Z

424

Flow Regimes and Transient Dynamics of Two-Dimensional Stratified Flow over an Isolated Mountain Ridge  

Science Conference Proceedings (OSTI)

Four regimes are identified for two-dimensional, unstructured, nonrotating, continuously stratified, hydrostatic, uniform Boussinesq flow over an isolated mountain ridge: (I) flow with neither wave breaking aloft nor upstream blocking (F?1.12, ...

Yuh-Lang Lin; Ting-An Wang

1996-01-01T23:59:59.000Z

425

Effects of Varying RedoxConditions on Natural Attenuation of Inorganic Contaminants from the D-Area Coal Pile Runoff Basin (U)  

Science Conference Proceedings (OSTI)

The objective of this study was to provide geochemical parameters to characterize the D-Area Coal Pile Runoff Basin (DCPRB) sediment as a potential source term. It is anticipated that the measured values will be used in risk calculations and will provide additional technical support for imposing Monitored Natural Attenuation at D-Area. This study provides a detailed evaluation of the DCPRB sediment and is part of another study that quantified the Monitored Natural Attenuation of inorganic contaminants more broadly at the D-Area Expanded Operable Unit, which includes the DCPRB (Powell et al. 2004). Distribution coefficients (K{sub d} values; a solid to liquid contaminant concentration ratio) and the Potentially Leachable Fraction (the percent of the total contaminant concentration in the sediment that can likely contribute to a contaminant plume) were measured in a DCPRB sediment as a function of redox conditions. Redox conditions at the DCPRB are expected to vary greatly as the system undergoes varying drying and flooding conditions. Conservative values; K{sub d} values that err on the side of being too low and Potentially Leachable Fraction values that err on the side of being too high, are presented. The K{sub d} values are high compared to conservative literature values, and underscores the importance of measuring site-specific values to provide estimates of sediments natural attenuation/sorption capacities. The Potentially Leachable Fraction indicates that as little as 27% of the As, but all of the Cu and Tl will be part of the source term. In the case of the As, the remaining 83% will likely never leach out of the sediment, thereby providing a form of natural attenuation. Importantly, Be, Cr, Cu, Ni, and V concentrations in the sediment were less-than twice background levels, indicating this sediment was not a potential source for these contaminants. K{sub d} values generally increased significantly (As, Cd, Co, Cr, Cu, Ni, Se, and Tl) when the sediment was flooded and after 36 days biostimulated through the addition of molasses. However, the contaminants that were newly sorbed tended to bind to weaker binding sites as the system was converted from an oxidizing to a reducing system. This redistribution of contaminants resulted in increased Potentially Leachable Fractions. In conclusion, these tests clearly indicate that the DCPRB sediment has a relatively high affinity to sorb most of the contaminants and that when evaluating the risk associated with this as a source term that only the Potentially Leachable Fraction of the total sediment contaminants concentration be used as the actual source term.

Kaplan, D

2004-05-30T23:59:59.000Z

426

Prediction of flow pattern of gas-liquid flow through circular microchannel using probabilistic neural network  

Science Conference Proceedings (OSTI)

The present study attempts to develop a flow pattern indicator for gas-liquid flow in microchannel with the help of artificial neural network (ANN). Out of many neural networks present in literature, probabilistic neural network (PNN) has been chosen ... Keywords: Hydrodynamics, Microchannel, Microstructure, Multiphase flow, Probabilistic neural network, Transition boundary, Turbulence

Seim Timung; Tapas K. Mandal

2013-04-01T23:59:59.000Z

427

DevoFlow: scaling flow management for high-performance networks  

Science Conference Proceedings (OSTI)

OpenFlow is a great concept, but its original design imposes excessive overheads. It can simplify network and traffic management in enterprise and data center environments, because it enables flow-level control over Ethernet switching and provides global ... Keywords: data center, flow-based networking, switch design

Andrew R. Curtis; Jeffrey C. Mogul; Jean Tourrilhes; Praveen Yalagandula; Puneet Sharma; Sujata Banerjee

2011-08-01T23:59:59.000Z

428

Is the five-flow conjecture almost false?  

Science Conference Proceedings (OSTI)

The number of nowhere zero Z"Q flows on a graph G can be shown to be a polynomial in Q, defining the flow polynomial @F"G(Q). According to Tutte@?s five-flow conjecture, @F"G(5)>0 for any bridgeless G. A conjecture by Welsh that @F"G(Q) has no real roots ... Keywords: Flow polynomial, Flow roots, Nowhere zero flows, Petersen graph, Transfer matrix, Tutte's five-flow conjecture

Jesper Lykke Jacobsen, JesúS Salas

2013-07-01T23:59:59.000Z

429

MONOCULAR OPTICAL FLOW FOR REALTIME VISION SYSTEMS  

E-Print Network (OSTI)

MONOCULAR OPTICAL FLOW FOR REAL­TIME VISION SYSTEMS Stephen M. Benoit and Frank P. Ferrie TR­CIM­96 268510 FAX: (514) 398­7348 Email: cim@cim.mcgill.ca #12; MONOCULAR OPTICAL FLOW FOR REAL­TIME VISION

Dudek, Gregory

430

Passenger Flow Model for Airline Networks  

Science Conference Proceedings (OSTI)

We present a model that rapidly finds an approximation of the expected passenger flow on an airline network, given forecast data concerning (1) the distribution of the demand for each itinerary, seen as a random variable; (2) the time distribution of ... Keywords: airline transportation, equilibrium model, passenger flow, recapture, spill

Jonathan Dumas; François Soumis

2008-05-01T23:59:59.000Z

431

Flow and Plate Motion in Compressor Valves  

E-Print Network (OSTI)

Industry,... Mission: #12;15 Group Engineering Fluid Dynamics Rotating-flow machines ­ Centrifugal pumps Machines · pumps · wind turbines · compressors · propellers EFD-FLOW #12;17 Engineering Fluid Dynamics (HWA, visualisation) · ball-on-disc test rig · Starling Resistor ( lung tubes) · CFD-lab servers, PC

Twente, Universiteit

432

Fuel cell system with coolant flow reversal  

DOE Patents (OSTI)

Method and apparatus for cooling electrochemical fuel cell system components. Periodic reversal of the direction of flow of cooling fluid through a fuel cell stack provides greater uniformity and cell operational temperatures. Flow direction through a recirculating coolant fluid circuit is reversed through a two position valve, without requiring modulation of the pumping component.

Kothmann, Richard E. (Pittsburgh, PA)

1986-01-01T23:59:59.000Z

433

Kingsnorth PF Flow Meter Demonstration Trials  

Science Conference Proceedings (OSTI)

A three-month demonstration project at PowerGen's Kingsnorth Power Station tested several new pulverized fuel (PF) flow measurement technologies in the harsh environment of an operational power station. Although further development may be warranted, current on-line PF flow measurement technologies already meet the basic requirements of coal fired boiler operators.

1999-06-30T23:59:59.000Z

434

Structural analysis of network traffic flows  

Science Conference Proceedings (OSTI)

Network traffic arises from the superposition of Origin-Destination (OD) flows. Hence, a thorough understanding of OD flows is essential for modeling network traffic, and for addressing a wide variety of problems including traffic engineering, traffic ... Keywords: network traffic analysis, principal component analysis, traffic engineering

Anukool Lakhina; Konstantina Papagiannaki; Mark Crovella; Christophe Diot; Eric D. Kolaczyk; Nina Taft

2004-06-01T23:59:59.000Z

435

The Turbulence Structure of Nocturnal Slope Flow  

Science Conference Proceedings (OSTI)

Measurements of the turbulence structure of nocturnal slope flow are used to test the hypothesis that slope flow turbulence in the region above the low-level wind maximum is decoupled from the surface and has a local structure similar to that ...

T. W. Horst; J. C. Doran

1988-02-01T23:59:59.000Z

436

A PV View of Zonal Flow Vacillation  

Science Conference Proceedings (OSTI)

It is suggested here that the zonal flow vacillation of the Southern Hemisphere is caused by a mutual interaction between the barotropic shear of the zonal flow and the evolution of baroclinic eddies during the later stages of their lifecycle. An ...

Dennis L. Hartmann

1995-07-01T23:59:59.000Z

437

A compressible flow model with capillary effects  

Science Conference Proceedings (OSTI)

A quasi-conservative formulation for compressible flows with interfaces including both capillary and viscous effects is developed. The model involves: (i) acoustic and convective transport; (ii) surface tension effects introduced as an extension of the ... Keywords: break-up, coalescence, compressibility, conservative formulation, interface capturing, mixture thermodynamics, surface tension, two-phase flows, viscosity

Guillaume Perigaud; Richard Saurel

2005-10-01T23:59:59.000Z

438

Information-flow types for homomorphic encryptions  

Science Conference Proceedings (OSTI)

We develop a flexible information-flow type system for a range of encryption primitives, precisely reflecting their diverse functional and security features. Our rules enable encryption, blinding, homomorphic computation, and decryption, with selective ... Keywords: confidentiality, cryptography, integrity, non-interference, secure information flow, type systems

Cédric Fournet; Jérémy Planul; Tamara Rezk

2011-10-01T23:59:59.000Z

439

Explaining ML type errors by data flows  

Science Conference Proceedings (OSTI)

We present a novel approach to explaining ML type errors: Since the type system inhibits data flows that would abort the program at run-time, our type checker identifies as explanations those data flows that violate the typing rules. It also detects ...

Holger Gast

2004-09-01T23:59:59.000Z

440

Cross flow electrofilter and method  

DOE Patents (OSTI)

A filter for clarifying carbonaceous liquids containing finely divided solid particles of, for instance, unreacted coal, ash and other solids discharged from a coal liquefaction process is presented. The filter includes two passageways separated by a porous filter medium. In one preferred embodiment the filter medium is of tubular shape to form the first passageway and is enclosed within an outer housing to form the second passageway within the annulus. An electrode disposed in the first passageway, for instance along the tube axis, is connected to a source of high voltage for establishing an electric field between the electrode and the filter medium. Slurry feed flows through the first passageway tangentially to the surfaces of the filter medium and the electrode. Particles from the feed slurry are attracted to the electrode within the first passageway to prevent plugging of the porous filter medium while carbonaceous liquid filters into the second passageway for withdrawal. Concentrated slurry is discharged from the first passageway at an end opposite to the feed slurry inlet. Means are also provided for the addition of diluent and a surfactant into the slurry to control relative permittivity and the electrophoretic mobility of the particles.

Gidaspow, Dimitri (Northbrook, IL); Lee, Chang H. (Chicago, IL); Wasan, Darsh T. (Westmont, IL)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

California energy flow in 1992  

DOE Green Energy (OSTI)

For the past 16 years energy flow diagrams for the State of California have been prepared from available data by members of the Lawrence Livermore National Laboratory. They have proven to be useful tools in graphically expressing energy supply and use in the State as well as illustrating the difference between particular years and between the State and the US as a whole. As far as is possible, similar data sources have been used to prepare the diagrams from year to year and identical assumptions{sup la-le} concerning conversion efficiencies have been made in order to minimize inconsistencies in the data and analyses. Sources of data used in this report are given in Appendix B and C; unavoidably the sources used over the 1976--1993 period have varied as some data bases are no longer available. In addition, we continue to see differences in specific data reported by different agencies for a given year. In particular, reported data on supply and usage in industrial/commercial/residential end-use categories have shown variability amongst the data gathering agencies, which bars detailed comparisons from year to year. Nonetheless, taken overall, valid generalizations can be made concerning gross trends and changes.

Borg, I.Y.; Briggs, C.K.

1994-04-01T23:59:59.000Z

442

Commodity Flow Survey | Data.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Commodity Flow Survey Commodity Flow Survey BusinessUSA Data/Tools Apps Challenges Let's Talk BusinessUSA You are here Data.gov » Communities » BusinessUSA » Data Commodity Flow Survey Dataset Summary Description The Commodity Flow Survey provides information on commodities shipped, their value, weight, and mode of transportation, as well as the origin and destination of shipments of commodities from manufacturing, mining, wholesale, and selected retail and services establishments. It is undertaken through a partnership between the Bureau of the Census, U.S. Department of Commerce, and the Bureau of Transportation Statistics, Research and Innovative Technology Administration. Tags {cfc,commodity,flow," federal",state,local,transportation,facilities,services,energy,safety,environment,Mining,Manufacturing,Wholesale,trade,Retail,Services,auxiliary,establishments,warehouses,industries,export,shipment,distance,tons,weight,hazardous,miles,ton-miles,destination,industry,hazard,ship,intrastate,interstate,"UN number",packaging,"TIH number",u.s.,metropolitan}

443

Flow through electrode with automated calibration  

DOE Patents (OSTI)

The present invention is an improved automated flow through electrode liquid monitoring system. The automated system has a sample inlet to a sample pump, a sample outlet from the sample pump to at least one flow through electrode with a waste port. At least one computer controls the sample pump and records data from the at least one flow through electrode for a liquid sample. The improvement relies upon (a) at least one source of a calibration sample connected to (b) an injection valve connected to said sample outlet and connected to said source, said injection valve further connected to said at least one flow through electrode, wherein said injection valve is controlled by said computer to select between said liquid sample or said calibration sample. Advantages include improved accuracy because of more frequent calibrations, no additional labor for calibration, no need to remove the flow through electrode(s), and minimal interruption of sampling.

Szecsody, James E [Richland, WA; Williams, Mark D [Richland, WA; Vermeul, Vince R [Richland, WA

2002-08-20T23:59:59.000Z

444

Characterization and Leach Testing for PUREX Cladding Waste Sludge (Group 3) and REDOX Cladding Waste Sludge (Group 4) Actual Waste Sample Composites  

SciTech Connect

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.(a) The testing program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual wastetesting program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. Two of the eight defined groups—plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR)—are the subjects of this report. Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, requiring caustic leaching. Characterization of the composite Group 3 and Group 4 waste samples confirmed them to be high in gibbsite. The focus of the Group 3 and 4 testing was on determining the behavior of gibbsite during caustic leaching. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

Snow, Lanee A.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Fiskum, Sandra K.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-02-13T23:59:59.000Z

445

NMR Studies of the Vanadium Spin Dynamics and Spin Structure in LiV2O4, CaV2O4, and (LixV1-x)3BO5 (x is almost equal to 0.33, 0.40)  

SciTech Connect

Strong electron correlation is believed to be an essential and unifying factor in diverse properties of condensed matter systems. Ground states that can arise due to electron correlation effects include Mott insulators, heavy fermion, ferromagnetism and antiferromagnetism, spin glasses, and high-temperature superconductivity. The electronic systems in transition metal oxide compounds are often highly correlated. In this thesis, the author presents experimental studies on three strongly correlated vanadium oxide compounds: LiV{sub 2}O{sub 4}, (Li{sub x}V{sub 1-x}){sub 3}BO{sub 5}, and CaV{sub 2}O{sub 4}, which have completely different ground states.

Xiaopeng Zong

2007-12-01T23:59:59.000Z

446

Breakthrough Flow Battery Cell Stack: Transformative Electrochemical Flow Storage System (TEFSS)  

SciTech Connect

GRIDS Project: UTRC is developing a flow battery with a unique design that provides significantly more power than today's flow battery systems. A flow battery is a cross between a traditional battery and a fuel cell. Flow batteries store their energy in external tanks instead of inside the cell itself. Flow batteries have traditionally been expensive because the battery cell stack, where the chemical reaction takes place, is costly. In this project, UTRC is developing a new stack design that achieves 10 times higher power than today’s flow batteries. This high power output means the size of the cell stack can be smaller, reducing the amount of expensive materials that are needed. UTRC’s flow battery will reduce the cost of storing electricity for the electric grid, making widespread use feasible.

None

2010-09-09T23:59:59.000Z

447

Breakthrough Flow Battery Cell Stack: Transformative Electrochemical Flow Storage System (TEFSS)  

SciTech Connect

GRIDS Project: UTRC is developing a flow battery with a unique design that provides significantly more power than today's flow battery systems. A flow battery is a cross between a traditional battery and a fuel cell. Flow batteries store their energy in external tanks instead of inside the cell itself. Flow batteries have traditionally been expensive because the battery cell stack, where the chemical reaction takes place, is costly. In this project, UTRC is developing a new stack design that achieves 10 times higher power than today’s flow batteries. This high power output means the size of the cell stack can be smaller, reducing the amount of expensive materials that are needed. UTRC’s flow battery will reduce the cost of storing electricity for the electric grid, making widespread use feasible.

2010-09-09T23:59:59.000Z

448

California energy flow in 1989  

DOE Green Energy (OSTI)

California's energy use showed a modest increase (2.2%) in 1989 over 1988 which was in keeping with the steady increase in population that the state has experienced annually during the decade. All end-use sectors (residential, commercial, industrial, transportation, etc.) contributed to the growth. The larger demand was met by increased imports of all major fuels. Only electrical imports remained close to 1988 levels, in part due to increased output from Diablo Canyon nuclear plant whose performance exceeded expectations. California's per capita energy consumption has traditionally been below the national average due to the relatively benign climate associated with its centers of population. The largest single use for energy in the state was for transportation which overtook industrial usage in the 60's. Use of highway fuels continued to grow and reached all time highs in 1989. Highway congestion, a major problem and concern in the state, is anticipated to grow as the number of licensed drivers increases; in 1989 the increase was 3.4%. Output from the The Geysers Geothermal fields, the largest in the world, continued to falter as the steam output fell. Nonetheless new resources at the Coso Geothermal Resource Area and at the Wendel Geothermal field came on line during the year, and other geothermal areas were under active development. Novel sources of renewable energy (solar, wind, etc.) grew; however, collectively they made only a small contribution to the overall energy supply. Cogenerated electricity sold to the utilities by small power producers inexplicably fell in 1989 although estimates of the total capacity available rose. Energy flow diagrams illustrate energy sources and energy consumption.

Borg, I.Y.; Briggs, C.K.

1991-02-06T23:59:59.000Z

449

Thermal laminarization of a stratified pipe flow  

SciTech Connect

The present work constitutes a new program that grew out of a scoping assessment by ANL to determine the propensity for pipe stratification to occur in the reactor outlet nozzles and hot-leg piping of a generic LMFBR during events producing reverse pipe flow. This paper focuses on the role that thermal buoyancy plays relative to being able to laminarize a turbulent stratified shear zone in a horizontal pipe. The preceeding can influence the behavior of a pipe stratified-backflow-recirculation zone (cold plenum water down into the hot pipe flow) which developes as the result of a temperature difference between the pipe flow and the plenum.

Oras, J.J.; Kasza, K.E.

1984-01-01T23:59:59.000Z

450

Ionization based multi-directional flow sensor  

SciTech Connect

A method, system, and apparatus for conducting real-time monitoring of flow (airflow for example) in a system (a hybrid power generation system for example) is disclosed. The method, system and apparatus measure at least flow direction and velocity with minimal pressure drop and fast response. The apparatus comprises an ion source and a multi-directional collection device proximate the ion source. The ion source is configured to generate charged species (electrons and ions for example). The multi-directional collection source is configured to determine the direction and velocity of the flow in real-time.

Chorpening, Benjamin T. (Morgantown, WV); Casleton, Kent H. (Morgantown, WV)

2009-04-28T23:59:59.000Z

451

Multiphase Flow and Cavern Abandonment in Salt  

Science Conference Proceedings (OSTI)

This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

Ehgartner, Brian; Tidwell, Vince

2001-02-13T23:59:59.000Z

452

Energy flow in acoustic black holes  

SciTech Connect

We present the results of an analysis of superradiant energy flow due to scalar fields incident on an acoustic black hole. In addition to providing independent confirmation of the recent results in [E. Berti, V. Cardoso, and J. P. S. Lemos, Phys. Rev. D 70, 124006 (2004).], we determine in detail the profile of energy flow everywhere outside the horizon. We confirm explicitly that in a suitable frame the energy flow is inward at the horizon and outward at infinity, as expected on physical grounds.

Choy, K.; Kruk, T.; Carrington, M.E.; Fugleberg, T.; Zahn, J.; Kobes, R.; Kunstatter, G.; Pickering, D. [Department of Physics, Brandon University, Brandon, Manitoba, R7A 6A9 (Canada) and Winnipeg Institute for Theoretical Physics, Winnipeg, Manitoba (Canada); Department of Physics, University of Winnipeg, Winnipeg, Manitoba, R7A 6A9 (Canada) and Winnipeg Institute for Theoretical Physics, Winnipeg, Manitoba (Canada); Department of Mathematics, Brandon University, Brandon, Manitoba, R7A 6A9 (Canada)

2006-05-15T23:59:59.000Z

453

Hydromagnetic Instability in plane Couette Flow  

E-Print Network (OSTI)

We study the stability of a compressible magnetic plane Couette flow and show that compressibility profoundly alters the stability properties if the magnetic field has a component perpendicular to the direction of flow. The necessary condition of a newly found instability can be satisfied in a wide variety of flows in laboratory and astrophysical conditions. The instability can operate even in a very strong magnetic field which entirely suppresses other MHD instabilities. The growth time of this instability can be rather short and reach $\\sim 10$ shear timescales.

Bonanno, Alfio

2007-01-01T23:59:59.000Z

454

Geologic flow characterization using tracer techniques  

DOE Green Energy (OSTI)

A new tracer flow-test system has been developed for in situ characterization of geologic formations. This report describes two sets of test equipment: one portable and one for testing in deep formations. Equations are derived for in situ detector calibration, raw data reduction, and flow logging. Data analysis techniques are presented for computing porosity and permeability in unconfined isotropic media, and porosity, permeability and fracture characteristics in media with confined or unconfined two-dimensional flow. The effects of tracer pulse spreading due to divergence, dispersion, and porous formations are also included.

Klett, R. D.; Tyner, C. E.; Hertel, Jr., E. S.

1981-04-01T23:59:59.000Z

455

Multiphase Flow Analysis in Hydra-TH  

SciTech Connect

This talk presents an overview of the multiphase flow efforts with Hydra-TH. The presentation begins with a definition of the requirements and design principles for multiphase flow relevant to CASL-centric problems. A brief survey of existing codes and their solution algorithms is presented before turning the model formulation selected for Hydra-TH. The issues of hyperbolicity and wellposedness are outlined, and a three candidate solution algorithms are discussed. The development status of Hydra-TH for multiphase flow is then presented with a brief summary and discussion of future directions for this work.

Christon, Mark A. [Los Alamos National Laboratory; Bakosi, Jozsef [Los Alamos National Laboratory; Francois, Marianne M. [Los Alamos National Laboratory; Lowrie, Robert B. [Los Alamos National Laboratory; Nourgaliev, Robert [Idaho National Laboratory

2012-06-20T23:59:59.000Z

456

Large volume flow-through scintillating detector  

DOE Patents (OSTI)

A large volume flow through radiation detector for use in large air flow situations such as incinerator stacks or building air systems comprises a plurality of flat plates made of a scintillating material arranged parallel to the air flow. Each scintillating plate has a light guide attached which transfers light generated inside the scintillating plate to an associated photomultiplier tube. The output of the photomultiplier tubes are connected to electronics which can record any radiation and provide an alarm if appropriate for the application.

Gritzo, Russ E. (Los Alamos, NM); Fowler, Malcolm M. (Los Alamos, NM)

1995-01-01T23:59:59.000Z

457

Columbia University flow instability experimental program: Volume 3. Single tube parallel flow tests  

SciTech Connect

The coolant in the Savannah River Site (SRS) production nuclear reactor assemblies is circulated as a subcooled liquid under normal operating conditions. This coolant is evenly distributed throughout multiple annular flow channels with a uniform pressure profile across each coolant flow channel. During the postulated Loss of Coolant Accident (LOCA), which is initiated by a hypothetical guillotine pipe break, the coolant flow through the reactor assemblies is significantly reduced. The flow reduction and accompanying power reduction (after shutdown is initiated) occur in the first 1--2 seconds of the LOCA. This portion of the LOCA is referred to as the Flow Instability phase. A series of down flow experiments have been conducted on three different size single tubes. The objective of these experiments was to determine the effect of a parallel flow path on the occurrence of flow instability. In all cases, it has been shown that the point of flow instability (OFI) determined under controlled flow operation does not change when operating in a controlled pressure drop mode (parallel path operation).

Dougherty, T.; Maciuca, C.; McAssey, E.V. Jr.; Reddy, D.G.; Yang, B.W.

1990-06-01T23:59:59.000Z

458

The 8th International Symposium on Flow Visualization: Conference report  

Science Conference Proceedings (OSTI)

The 8th International Symposium on Flow Visualization (8ISFV) was held in Sorrento, Italy, from the 1st to the 4th of September 1998. The Symposium has attracted, by far, the largest number of participants in the history of the meeting. The 313 presented ... Keywords: acoustics, advanced techniques, aircrafts, airfoils, applications, bluff bodies, cavity flows, channel flows, combustion, delta wings, droplets break-up, electrodynamics, engines, flow around cylinders, flow visualization, fluidics, holography, industrial processes, infrared thermography, instability, interferometry, jets, jets in cross flow, liquid crystals, low reynolds number flows, machines, medical applications, multiphase flows, natural convection, numerical visualizations, particle image velocimetry, porous media, rotating fluids, schlieren, shock waves, supersonic flows, three dimensional flows, turbomachines, turbulence, two phase flows, unsteady flow, vortices

G. M. Carlomagno

1999-01-01T23:59:59.000Z

459

Residual Circulations Due to Bottom Roughness Variability under Tidal Flows  

Science Conference Proceedings (OSTI)

Tidal flows over irregular bathymetry are known to produce residual circulation flows due to nonlinear interaction with gradients of depth. Using the depth-averaged vorticity equations, the generation of residual vorticity and residual flows due ...

Thomas F. Gross; Francisco E. Werner

1994-07-01T23:59:59.000Z

460

Global Characteristics of Stream Flow Seasonality and Variability  

Science Conference Proceedings (OSTI)

Monthly stream flow series from 1345 sites around the world are used to characterize geographic differences in the seasonality and year-to-year variability of stream flow. Stream flow seasonality varies regionally, depending on the timing of ...

Michael D. Dettinger; Henry F. Diaz

2000-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

GMINC - A MESH GENERATOR FOR FLOW SIMULATIONS IN FRACTURED RESERVOIRS  

E-Print Network (OSTI)

Simulation of Fluid Flow in Fractured Porous Media, Watergovern fluid flow in fractured porous media. These are (i)for Modeling Fluid and Heat Flow in fractured Porous Media,

Pruess, K.

2010-01-01T23:59:59.000Z

462

Dryout droplet distribution and dispersed flow film boiling  

E-Print Network (OSTI)

Dispersed flow film boiling is characterized by liquid-phase droplets entrained in a continuous vapor-phase flow. In a previous work at MIT, a model of dispersed flow heat transfer was developed, called the Local Conditions ...

Hill, Wayne S.

1982-01-01T23:59:59.000Z

463

Tutorial on Increased Power Flow Guidebook  

Science Conference Proceedings (OSTI)

This project developed an annotated presentation of key material from the Increased Power Flow Guidebook that was published by EPRI in 2006. The presentation includes both power point and acrobat files on a CD accompanying the report.

2006-12-14T23:59:59.000Z

464

Self-potential modeling from primary flows  

DOE Green Energy (OSTI)

A new method for the calculation of self potentials (SP) based on induced current sources is presented. The induced current sources are due to divergences of the convective current which is driven, in turn, by a primary flow, either heat or fluid. Numerical modeling utilizing this method has been implemented using a two-dimensional transmission surface algorithm. When the primary flow is driven by the gradient of a potential, joint modeling of the primary flow and the resultant SP is possible with this algorithm. Examples of simple geometrical models in the presence of point sources for the primary flow are presented and discussed. Lastly, a field example of the joint modeling of temperature and SP data is illustrated with data from Red Hill Hot Spring, Utah.

Sill, W.R.

1981-03-01T23:59:59.000Z

465

Patterns and instability of grannular flow  

Science Conference Proceedings (OSTI)

Dense granular flows are often observed to become unstable and form inhomogeneous structures in nature or industry. Although recently significant advances have been made in understanding simple flows, instabilities are often not understood in detail. We present experimental and numerical results that show the formation of longitudinal stripes. These arise from instability of the uniform flowing state of granular media on a rough inclined plane. The form of the stripes depends critically on the mean density of the flow with a robust form of stripes at high density that consists of fast sliding plug-like regions (stripes) on top of highly agitated boiling material -- a configuration reminiscent of the Leidenfrost effect when a droplet of liquid lifted by its vapor is hovering above a hot surface.

Ecke, Robert E [Los Alamos National Laboratory; Borzsonyi, Tamas [NON LANL; Mcelwaine, Jim N [U. CAMBRIDGE

2009-01-01T23:59:59.000Z

466

Stochastic Forcing of Planetary Scale Flow  

Science Conference Proceedings (OSTI)

Using geopotential height observations we analyze the fluctuations of the barotropic vorticity transfer from synoptic scale flow (zonal wavenumber m > 5) to planetary scales (m ? 5). We hypothesize that this transfer can be seen as a stochastic ...

Joseph Egger; H-D. Schilling

1984-03-01T23:59:59.000Z

467

DOE Hydrogen Analysis Repository: FLOW Model  

NLE Websites -- All DOE Office Websites (Extended Search)

FLOW Model FLOW Model Project Summary Full Title: Chemical Engineering Process Simulation Platform - FLOW Project ID: 131 Principal Investigator: Juan Ferrada Brief Description: FLOW is a steady-state chemical process simulator. Modules have been developed for supply chain calculations, micro-economic calculations, and other calculations. Purpose Simulate steady-state chemical processes to support hydrogen infrastructure and transition analysis. Performer Principal Investigator: Juan Ferrada Organization: Oak Ridge National Laboratory (ORNL) Address: Bethel Valley 1, Bldg 5700, N217 Oak Ridge, TN 37831-6166 Telephone: 865-574-4998 Email: ferradajj@ornl.gov Sponsor(s) Name: Fred Joseck Organization: DOE Hydrogen Program Telephone: 202-586-7932 Email: Fred.Joseck@ee.doe.gov

468

Feedback control of separation in unsteady flows  

E-Print Network (OSTI)

Prandtl (1904) showed that in a steady flow past a bluff body, streamlines separate from the boundary where the skin friction (or wall shear) vanishes and admits a negative gradient. Despite initial suggestions, however, ...

Alam, Mohammad-Reza

2005-01-01T23:59:59.000Z

469

Improved modeling techniques for turbomachinery flow fields  

DOE Green Energy (OSTI)

This program has the objective of developing an improved methodology for modeling turbomachinery flow fields, including the prediction of losses and efficiency. Specifically, the program addresses the treatment of the mixing stress tensor terms attributed to deterministic flow field mechanisms required in steady-state Computational Fluid Dynamic (CFD) models for turbomachinery flow fields. These mixing stress tensors arise due to spatial and temporal fluctuations (in an absolute frame of reference) caused by rotor-stator interaction due to various blade rows and by blade-to-blade variation of flow properties. This will be accomplished in a cooperative program by Penn State University and the Allison Engine Company. These tasks include the acquisition of previously unavailable experimental data in a high-speed turbomachinery environment, the use of advanced techniques to analyze the data, and the development of a methodology to treat the deterministic component of the mixing stress tenor.

Lakshminarayana, B.; Fagan, J.R. Jr.

1995-12-31T23:59:59.000Z

470

Catalyst immobilization techniques for continuous flow synthesis  

E-Print Network (OSTI)

Catalytic processes are ubiquitous in both research and industrial settings. As continuous flow processes continue to gain traction in research labs and fine and pharmaceutical chemical processes, new opportunities exist ...

Nagy, Kevin David

2012-01-01T23:59:59.000Z

471

Historical river flow rates for dose calculations  

Science Conference Proceedings (OSTI)

Annual average river flow rates are required input to the LADTAP Computer Code for calculating offsite doses from liquid releases of radioactive materials to the Savannah River. The source of information on annual river flow rates used in dose calculations varies, depending on whether calculations are for retrospective releases or prospective releases. Examples of these types of releases are: Retrospective - releases from routine operations (annual environmental reports) and short term release incidents that have occurred. Prospective - releases that might be expected in the future from routine or abnormal operation of existing or new facilities (EIS`s, EID`S, SAR`S, etc.). This memorandum provides historical flow rates at the downstream gauging station at Highway 301 for use in retrospective dose calculations and derives flow rate data for the Beaufort-Jasper and Port Wentworth water treatment plants.

Carlton, W.H.

1991-06-10T23:59:59.000Z

472

Pressure balanced drag turbine mass flow meter  

DOE Patents (OSTI)

The density of the fluid flowing through a tubular member may be measured by a device comprising a rotor assembly suspended within the tubular member, a fluid bearing medium for the rotor assembly shaft, independent fluid flow lines to each bearing chamber, and a scheme for detection of any difference between the upstream and downstream bearing fluid pressures. The rotor assembly reacts to fluid flow both by rotation and axial displacement; therefore concurrent measurements may be made of the velocity of blade rotation and also bearing pressure changes, where the pressure changes may be equated to the fluid momentum flux imparted to the rotor blades. From these parameters the flow velocity and density of the fluid may be deduced.

Dacus, Michael W. (Gilbert, AR); Cole, Jack H. (Fayetteville, AR)

1982-01-01T23:59:59.000Z

473

Pressure balanced drag turbine mass flow meter  

DOE Patents (OSTI)

The density of the fluid flowing through a tubular member may be measured by a device comprising a rotor assembly suspended within the tubular member, a fluid bearing medium for the rotor assembly shaft, independent fluid flow lines to each bearing chamber, and a scheme for detection of any difference between the upstream and downstream bearing fluid pressures. The rotor assembly reacts to fluid flow both by rotation and axial displacement; therefore concurrent measurements may be made of the velocity of blade rotation and also bearing pressure changes, where the pressure changes may be equated to the fluid momentum flux imparted to the rotor blades. From these parameters the flow velocity and density of the fluid may be deduced.

Dacus, M.W.; Cole, J.H.

1980-04-23T23:59:59.000Z

474

Verifying a secure information flow analyzer  

Science Conference Proceedings (OSTI)

Denotational semantics for a substantial fragment of Java is formalized by deep embedding in PVS, making extensive use of dependent types. A static analyzer for secure information flow for this language is proved correct, that is, it enforces noninterference.

David A. Naumann

2005-08-01T23:59:59.000Z

475

Development of the in vivo flow cytometer  

E-Print Network (OSTI)

An in vivo flow cytometer has been developed that allows the real-time detection and quantification of circulating cells containing fluorescent proteins or labeled with fluorochrome molecules in live animals, without the ...

Novak, John P. (John Peter), 1957-

2004-01-01T23:59:59.000Z

476

Local Energy Generation in Barotropic Flows  

Science Conference Proceedings (OSTI)

The local growth of disturbances to a steady, nondivergent shear flow is investigated in the context of the barotropic vorticity equation (BVE). A new expression for the instantaneous energy generation rate is derived by using a local coordinate ...

R. Iacono