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Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
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1

Optimized Anion Exchange Membranes for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; anion exchange membrane; ion exchange capacity; cycling performance; power density ... All electrochemical measurements were conducted using a fully automated redox flow battery testing system (Scribner 857 Redox Flow Cell System). ... Characteristics of a new all-vanadium redox flow battery ...

Dongyang Chen; Michael A. Hickner; Ertan Agar; E. Caglan Kumbur

2013-06-25T23:59:59.000Z

2

Fact Sheet: Vanadium Redox Flow Batteries (October 2012) | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vanadium Redox Flow Batteries (October 2012) Vanadium Redox Flow Batteries (October 2012) Fact Sheet: Vanadium Redox Flow Batteries (October 2012) DOE's Energy Storage Program is funding research to develop next-generation vanadium redox flow batteries (VRBs) that reduce costs by improving energy and power densities, widening the operating temperature window, and simplifying and optimizing stack/system designs. These efforts build on Pacific Northwest National Laboratory research that has developed new redox electrolytes that enable increased VRB operating temperatures and energy storage capabilities. Fact Sheet: Vanadium Redox Flow Batteries (October 2012) More Documents & Publications Energy Storage Systems 2012 Peer Review Presentations - Day 3, Session 2 Energy Storage Systems 2012 Peer Review Presentations - Poster Session 2

3

Nitrogen-Doped Carbon Nanotube/Graphite Felts as Advanced Electrode Materials for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; nitrogen doping; carbon nanotubes; graphite felt ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ...

Shuangyin Wang; Xinsheng Zhao; Thomas Cochell; Arumugam Manthiram

2012-07-27T23:59:59.000Z

4

Influences of Permeation of Vanadium Ions through PVDF-g-PSSA Membranes on Performances of Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

The vanadium redox flow battery (VRB) proposed by Skyllas-Kazacos and co-workers1-3 in 1985 has received considerable attention due to its long cycle life, flexible design, fast response time, deep-discharge capability, and low cost in energy storage. ... Figure 1 Schematic illustration of a vanadium redox flow battery. ... Vanadium Redox Flow Battery Performance. ...

Xuanli Luo; Zhengzhong Lu; Jingyu Xi; Zenghua Wu; Wentao Zhu; Liquan Chen; Xinping Qiu

2005-10-08T23:59:59.000Z

5

Shunt current loss of the vanadium redox flow battery  

Science Journals Connector (OSTI)

The shunt current loss is one of main factors to affect the performance of the vanadium redox flow battery, which will shorten the cycle life and decrease the energy transfer efficiency. In this paper, a stack-level model based on the circuit analog method is proposed to research the shunt current loss of the vanadium redox flow battery, in which the SOC (state of charge) of electrolyte is introduced. The distribution of shunt current is described in detail. The sensitive analysis of shunt current is reported. The shunt current loss in charge/discharge cycle is predicted with the given experimental data. The effect of charge/discharge pattern on the shunt current loss is studied. The result shows that the reduction of the number of single cells in series, the decrease of the resistances of manifold and channel and the increase of the power of single cell will be the further development for the VRFB stack.

Feng Xing; Huamin Zhang; Xiangkun Ma

2011-01-01T23:59:59.000Z

6

Numerical modeling of an all vanadium redox flow battery.  

SciTech Connect

We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.

Clausen, Jonathan R.; Brunini, Victor E.; Moffat, Harry K.; Martinez, Mario J.

2014-01-01T23:59:59.000Z

7

Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Bismuth Nanoparticle Decorating Graphite Felt as a High-Performance Electrode for an All-Vanadium Redox Flow Battery ... Employing electrolytes containing Bi3+, bismuth nanoparticles are synchronously electrodeposited onto the surface of a graphite felt electrode during operation of an all-vanadium redox flow battery (VRFB). ... Energy storage; redox flow battery; electrode; catalyst; vanadium ...

Bin Li; Meng Gu; Zimin Nie; Yuyan Shao; Qingtao Luo; Xiaoliang Wei; Xiaolin Li; Jie Xiao; Chongmin Wang; Vincent Sprenkle; Wei Wang

2013-02-11T23:59:59.000Z

8

In-situ Investigation of Vanadium Ion Transport in Redox Flow Battery  

SciTech Connect

We will show a new method to differentiate the vanadium transport from concentration gradient and that from electric field. Flow batteries with vanadium and iron redox couples as the electro-active species were employed to investigate the transport behavior of vanadium ions in the presence of electric field. It was shown that electric field accelerated the positive-to-negative and reduced the negative-to-positive vanadium ions transport in charge process and affected the vanadium ions transport in an opposite way in discharge process. In addition, a method was designed to differentiate the concentration gradient-driven vanadium ions diffusion and electric field-driven vanadium ions migration. Simplified mathematical model was established to simulate the vanadium ions transport in real charge-discharge operation of flow battery. The concentration gradient diffusion coefficients and electric-migration coefficients of V2+, V3+, VO2+, and VO2+ across Nafion membrane were obtained by fitting the experimental data.

Luo, Qingtao; Li, Liyu; Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Chen, Baowei; Yang, Zhenguo

2012-06-27T23:59:59.000Z

9

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (III): Volumetric Properties of Aqueous VOSO4  

Science Journals Connector (OSTI)

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (III): Volumetric Properties of Aqueous VOSO4 ... The all-vanadium redox flow battery (VRFB) as an effective energy-storage system proposed by Skyllas-Kazacos et al. has been investigated extensively. ... Oriji, G.; Katayama, Y.; Miura, T.Investigation on V(IV)/V(V) species in a vanadium redox flow battery Electrochim. ...

Ye Qin; Jian-Guo Liu; Chuan-Wei Yan

2011-11-22T23:59:59.000Z

10

Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow Battery ... A powerful low-cost electrocatalyst, nanorod Nb2O5, is synthesized using the hydrothermal method with monoclinic phases and simultaneously deposited on the surface of a graphite felt (GF) electrode in an all vanadium flow battery (VRB). ... Flow battery cyclic performance also demonstrates the excellent stability of the as prepared Nb2O5 catalyst enhanced electrode. ...

Bin Li; Meng Gu; Zimin Nie; Xiaoliang Wei; Chongmin Wang; Vincent Sprenkle; Wei Wang

2013-11-26T23:59:59.000Z

11

A three-dimensional model for negative half cell of the vanadium redox flow battery  

Science Journals Connector (OSTI)

A stationary, isothermal, three-dimensional model for negative half cell of the vanadium redox flow battery is developed, which is based on the comprehensive conservation laws, such as charge, mass and momentum, together with a kinetic model for reaction involving vanadium species. The model is validated against the results calculated by the available two-dimensional model. With the given geometry of the negative half cell, the distributions of velocity, concentration, overpotential and transfer current density in the sections that are perpendicular and parallel to the applied current are studied. It is shown that the distribution of the electrolyte velocity in the electrode has significant impact on the distribution of concentration, overpotential and transfer current density. The lower velocity in the electrode will cause the higher overpotential, further result in the side reaction and corrosion of key materials locally. The development of the design of the vanadium redox flow battery is discussed, and the further research is proposed.

Xiangkun Ma; Huamin Zhang; Feng Xing

2011-01-01T23:59:59.000Z

12

Fact Sheet: Vanadium Redox Flow Batteries (October 2012)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Breakthrough Breakthrough Researchers at Pacific Northwest National Laboratory have developed a new sulfate (SO 4 2- ) and chloride (Cl - ) mixed solution that is used as the electrolyte. Compared to pure sulfuric acid, the new solution can hold more than 70% more vanadium ions, increasing energy storage capacity by more than 70%. The use of Cl - in the new solution also increases the operating temperature window by 83%, so the battery

13

In Situ X-ray Near-Edge Absorption Spectroscopy Investigation of the State of Charge of All-Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

all-vanadium flow battery; X-ray near-edge adsorption spectroscopy; synchrotron; in situ; state of charge; electrolyte ... Among different types of RFBs, the all-vanadium redox flow battery (VRB) displays excellent electrochemical activity and reversibility. ... To the best of our knowledge, this is the first report to use the in situ synchrotron techniques to study the redox flow battery. ...

Chuankun Jia; Qi Liu; Cheng-Jun Sun; Fan Yang; Yang Ren; Steve M. Heald; Yadong Liu; Zhe-Fei Li; Wenquan Lu; Jian Xie

2014-09-05T23:59:59.000Z

14

Upgrading the Vanadium Redox Battery | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Upgrading the Vanadium Redox Battery Upgrading the Vanadium Redox Battery New electrolyte mix increases energy storage by 70 percent After developing a more effective...

15

Synergistic Effect of Carbon Nanofiber/Nanotube Composite Catalyst on Carbon Felt Electrode for High-Performance All-Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Synergistic Effect of Carbon Nanofiber/Nanotube Composite Catalyst on Carbon Felt Electrode for High-Performance All-Vanadium Redox Flow Battery ... Carbon nanofiber/nanotube (CNF/CNT) composite catalysts grown on carbon felt (CF), prepared from a simple way involving the thermal decomposition of acetylene gas over Ni catalysts, are studied as electrode materials in a vanadium redox flow battery. ... Energy storage; redox flow battery; electrode; carbon nanofiber; carbon nanotube; catalyst ...

Minjoon Park; Yang-jae Jung; Jungyun Kim; Ho il Lee; Jeaphil Cho

2013-09-11T23:59:59.000Z

16

Development of a Novel Iodine-Vitamin C/Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Abstract A novel (I+/I2)/vitamin C vs. V4+/V5+ semi-vanadium redox flow battery (semi-VRFB) with iodine, vitamin C, and V4+/V5+ redox couples, using multiple electrodes was investigated. The electrodes, Ni-P/carbon paper and Ni-P/TiO2/carbon paper, were modified by the electroless plating method and sol-gel process. The electrochemical characteristics and the performance of the semi-VRFB were verified by the cyclic voltammetry method and a charge-discharge test. This study shows modified electrodes can improve the reversibility and symmetry of the oxidation-reduction reaction of the semi-VRFB system, and effectively raise its storage ability. The coulomb efficiency of the semi-VRFB system is close to 96%, which is higher than the all-VRFB. The semi-VRFB system can reduce the amount of vanadium salt, therefore, it is not only a reduction in cost, but also has a great potential for the development of energy storage systems.

Mei-Ling Chen; Shu-Ling Huang; Chin-Lung Hsieh; Jan- Yen Lee; Tz-Jiun Tsai

2014-01-01T23:59:59.000Z

17

Development of carbon composite bipolar plate (BP) for vanadium redox flow battery (VRFB)  

Science Journals Connector (OSTI)

Abstract A vanadium redox flow battery (VRFB) is one of the most promising energy storage systems (ESSs) due to its safety, durability and scalability. However, high cost of its components has been obstacle for commercialization of VRFB. Especially, bipolar plates (BPs) which are the main components of VRFB, are fabricated using graphite, which increases not only its manufacturing cost, but also decreases the reliability of VFRB, especially for the large area BP due to the brittleness of graphite although the graphite has high electrical conductivity and chemical stability. In this work, a carbon composite BP for the VRFB has been developed optimally considering its electrical as well as chemical stabilities against strong acids. Charge/discharge tests of the VRFB using the developed carbon composite \\{BPs\\} were performed to observe its energy and voltage efficiencies, from which the durability of the composite BP was estimated.

Ki Hyun Kim; Bu Gi Kim; Dai Gil Lee

2014-01-01T23:59:59.000Z

18

Modeling a vanadium redox flow battery system for large scale applications  

Science Journals Connector (OSTI)

A simulation model of a vanadium redox flow battery (VRFB) system based on measurements with a kilowatt scale real life VRFB unit was developed. Various hourly charging and discharging cycles were performed for states of charge (SOC) of 75%, 60%, 40% and 20% at different power values ranging from 2 kW to 10 kW. The dependence of the overall system efficiency in a VRFB unit on the SOC was determined by considering the energy losses at stacks during the electrochemical conversion and by the auxiliary power consumption of the hydraulic circuits as well as the power conversion systems. Using the model, optimal number of modules for certain power levels during charging and discharging operations were estimated for megawatt scale operations.

Burak Turker; Sebastian Arroyo Klein; Eva-Maria Hammer; Bettina Lenz; Lidiya Komsiyska

2013-01-01T23:59:59.000Z

19

Dynamic electro-thermal modeling of all-vanadium redox flow battery with forced cooling strategies  

Science Journals Connector (OSTI)

Abstract The present study focuses on the dynamic electro-thermal modeling for the all-vanadium redox flow battery (VRB) with forced cooling strategies. The Foster network is adopted to dynamically model the heat dissipation of VRB with heat exchangers. The parameters of Foster network are extracted by fitting the step response of it to the results of linearized CFD model. Then a complete electro-thermal model is proposed by coupling the heat generation model, Foster network and electrical model. Results show that the established model has nearly the same accuracy with the nonlinear CFD model in electrolyte temperature prediction but drastically improves the computational efficiency. The modeled terminal voltage is also benchmarked with the experimental data under different current densities. The electrolyte temperature is found to be significantly influenced by the flow rate of coolant. As compared, although the electrolyte flow rate has unremarkable impact on electrolyte temperature, its effect on system pressure drop and battery efficiency is significant. Increasing the electrolyte flow rate improves the coulombic efficiency, voltage efficiency and energy efficiency simultaneously but at the expense of higher pump power demanded. An optimal flow rate exists for each operating condition to maximize the system efficiency.

Zhongbao Wei; Jiyun Zhao; Binyu Xiong

2014-01-01T23:59:59.000Z

20

Properties Investigation of Sulfonated Poly(ether ether ketone)/Polyacrylonitrile Acid–Base Blend Membrane for Vanadium Redox Flow Battery Application  

Science Journals Connector (OSTI)

Acid–base blend membrane prepared from sulfonated poly(ether ether ketone) (SPEEK) and polyacrylonitrile (PAN) was detailedly evaluated for vanadium redox flow battery (VRFB) application. SPEEK/PAN blend membrane exhibited dense and homogeneous cross-...

Zhaohua Li; Wenjing Dai; Lihong Yu; Le Liu; Jingyu Xi; Xinping Qiu; Liquan Chen

2014-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane  

SciTech Connect

Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

2013-09-02T23:59:59.000Z

22

Bio-mass derived mesoporous carbon as super electrode in all vanadium redox flow battery with multicouple reactions  

Science Journals Connector (OSTI)

Abstract We first report the multi-couple reaction in all vanadium redox flow batteries (VRFB) while using bio-mass (coconut shell) derived mesoporous carbon as electrode. The presence of V3+/V4+ redox couple certainly supplies the additional electrons for the electrochemical reaction and subsequently provides improved electrochemical performance of VRFB system. The efficient electro-catalytic activity of such coconut shell derived high surface area mesoporous carbon is believed for the improved cell performance. Extensive power and electrochemical studies are performed for VRFB application point of view and described in detail.

Mani Ulaganathan; Akshay Jain; Vanchiappan Aravindan; Sundaramurthy Jayaraman; Wong Chui Ling; Tuti Mariana Lim; M.P. Srinivasan; Qingyu Yan; Srinivasan Madhavi

2014-01-01T23:59:59.000Z

23

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (II): A Study on Low-Temperature Heat Capacities and Thermodynamic Properties of VOSO4·2.63H2O(s)  

Science Journals Connector (OSTI)

Thermodynamic Investigation of Electrolytes of the Vanadium Redox Flow Battery (II): A Study on Low-Temperature Heat Capacities and Thermodynamic Properties of VOSO4·2.63H2O(s) ... The low-temperature heat capacities of VOSO4·2.63H2O(s) which is a key component in the electrolyte of the vanadium redox flow battery were measured by adiabatic calorimetry in the temperature range of (78 to 388) K, and the experimental values of the molar heat capacities in the temperature regions of (78 to 372) K were fitted to a polynomial equation. ... The vanadium redox flow battery (VRB) was first proposed and investigated by Skyllas-Kazacos et al.,(1, 2) in which the V(II)/V(III) and V(IV)/V(V) redox couples were successfully employed as the negative and positive half-cell electrolytes. ...

Ye Qin; Jian-Guo Liu; You-Ying Di; Chuan-Wei Yan; Chao-Liu Zeng; Jia-Zhen Yang

2009-12-17T23:59:59.000Z

24

ESS 2012 Peer Review - Painesville Municipal Electric Power Vanadium Redox Battery Demo Project - Jodi Startari, Ashlawn Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electric Power Electric Power Vanadium Redox Battery Demonstration Project Jodi Startari Ashlawn Energy LLC Briefing Overview * Painesville Municipal Electric Power Plant Project Synopsis * Vanadium Redox Flow Battery Technology * City of Painesville Municipal Electric Plant History * Project Multiple Objectives and Additional Detail * Project Risk Analysis presented at previous Peer Review * Project to date progress * Cost Distribution * Summary/Conclusions * Future Tasks * Questions US Produced Vanadium Redox Flow Battery for Bulk Storage, Peak Shaving * 8 MW Hour redox flow battery (1MW 8 hours) * To be installed at Painesville Municipal Electric Plant (PMEP), a 32 MW coal fired facility * Most efficient PMEP operation is steady state at 26 MW (lowest emissions, lowest operating cost)

25

Influence of Solvent on Polymer Prequaternization toward Anion-Conductive Membrane Fabrication for All-Vanadium Flow Battery  

Science Journals Connector (OSTI)

Influence of Solvent on Polymer Prequaternization toward Anion-Conductive Membrane Fabrication for All-Vanadium Flow Battery ... The all-vanadium redox flow battery (VFB) can potentially circumvent the mismatch between the generation and end use of renewable but unsteady energies such as photovoltaics and wind turbines. ... 2.3 All-Vanadium Redox Flow Battery (VFB) Performance ...

Fengxiang Zhang; Huamin Zhang; Chao Qu

2012-07-09T23:59:59.000Z

26

Thermo–chemical treatments based on NH3/O2 for improved graphite-based fiber electrodes in vanadium redox flow batteries  

Science Journals Connector (OSTI)

Abstract Electrochemical behavior of the polyacrylonitrile (PAN)-based graphite as a low cost electrode material for vanadium based redox batteries (VFB) in sulfuric acid medium has been improved by means of the successful introduction of nitrogen and oxygen-containing groups at the graphite surface by thermal activation under NH3/O2 (1:1) atmosphere. Influence of the temperature and treatment duration times have been studied towards the positive reaction of VFB. The structure, composition, and electrochemical properties of the treated samples have been characterized with field emission scanning electron microscopy, X-ray photoelectron spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The estimation of electrochemical surface area has also been evaluated. The treatment of PAN graphite material at 773 K for 24-h leads to electrode materials with the best electrochemical activity towards the VO 2 + /VO2+ redox couple. This method produces an increase of the nitrogen and oxygen content at the surface up to 8% and 32%, respectively, and is proved to be a straightforward and cost-effective methodology. This improvement of the electrochemical properties is attributed to the incorporation of the nitrogen and oxygen-containing groups that facilitate the electron transfer through the electrode/electrolyte interface for both oxidation and reduction processes.

Cristina Flox; Javier Rubio-García; Marcel Skoumal; Teresa Andreu; Juan Ramón Morante

2013-01-01T23:59:59.000Z

27

Redox Flow Batteries, a Review  

SciTech Connect

Redox flow batteries are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of redox flow batteries with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

U. Tennessee Knoxville; U. Texas Austin; McGill U; Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.; Ross, Philip N.; Gostick, Jeffrey T.; Liu, Qinghua

2011-07-15T23:59:59.000Z

28

Cascade redox flow battery systems  

DOE Patents (OSTI)

A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

2014-07-22T23:59:59.000Z

29

Advanced Redox Flow Batteries for Stationary Electrical Energy Storage  

SciTech Connect

This report describes the status of the advanced redox flow battery research being performed at Pacific Northwest National Laboratories for the U.S. Department of Energy’s Energy Storage Systems Program. The Quarter 1 of FY2012 Milestone was completed on time. The milestone entails completion of evaluation and optimization of single cell components for the two advanced redox flow battery electrolyte chemistries recently developed at the lab, the all vanadium (V) mixed acid and V-Fe mixed acid solutions. All the single cell components to be used in future kW-scale stacks have been identified and optimized in this quarter, which include solution electrolyte, membrane or separator; carbon felt electrode and bi-polar plate. Varied electrochemical, chemical and physical evaluations were carried out to assist the component screening and optimization. The mechanisms of the battery capacity fading behavior for the all vanadium redox flow and the Fe/V battery were discovered, which allowed us to optimize the related cell operation parameters and continuously operate the system for more than three months without any capacity decay.

Li, Liyu; Kim, Soowhan; Xia, Guanguang; Wang, Wei; Yang, Zhenguo

2012-03-19T23:59:59.000Z

30

Redox flow batteries based on supporting solutions containing chloride  

DOE Patents (OSTI)

Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-01-14T23:59:59.000Z

31

Redox Flow Batteries: An Engineering Perspective  

SciTech Connect

Redox flow batteries are well suited to provide modular and scalable energy storage systems for a wide range of energy storage applications. In this paper, we review the development of redox flow battery technology including recent advances in new redox active materials and systems. We discuss cost, performance, and reliability metrics that are critical for deployment of large flow battery systems. The technology, while relatively young, has the potential for significant improvement through reduced materials costs, improved energy and power efficiency, and significant reduction in the overall system cost.

Chalamala, Babu R.; Soundappan, Thiagarajan; Fisher, Graham R.; Anstey, Mitchell A.; Viswanathan, Vilayanur V.; Perry, Mike L.

2014-10-01T23:59:59.000Z

32

High energy density redox flow device  

DOE Patents (OSTI)

Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan Y; Duduta, Mihai; Limthongkul, Pimpa

2014-05-13T23:59:59.000Z

33

Vanadium Flow Battery for Energy Storage: Prospects and Challenges  

Science Journals Connector (OSTI)

Vanadium Flow Battery for Energy Storage: Prospects and Challenges ... Her work involves investigating the strategy to improve the stability of electrolytes for the vanadium flow battery. ... Dr. Huamin Zhang currently is a tenured Professor at Dalian Institute of Chemical Physics, Chinese Academy of Science; he serves as the head of the energy storage division and chief scientist of the 973 National Project on Flow Battery. ...

Cong Ding; Huamin Zhang; Xianfeng Li; Tao Liu; Feng Xing

2013-03-28T23:59:59.000Z

34

Redox Flow Batteries for Grid-scale Energy Storage - Energy Innovation...  

NLE Websites -- All DOE Office Websites (Extended Search)

and could also improve the electric grid's reliability and help connect more wind turbines and solar panels to the grid. A schematic of an upgraded vanadium redox batter...

35

Rebalancing electrolytes in redox flow battery systems  

DOE Patents (OSTI)

Embodiments of redox flow battery rebalancing systems include a system for reacting an unbalanced flow battery electrolyte with a rebalance electrolyte in a first reaction cell. In some embodiments, the rebalance electrolyte may contain ferrous iron (Fe.sup.2+) which may be oxidized to ferric iron (Fe.sup.3+) in the first reaction cell. The reducing ability of the rebalance reactant may be restored in a second rebalance cell that is configured to reduce the ferric iron in the rebalance electrolyte back into ferrous iron through a reaction with metallic iron.

Chang, On Kok; Pham, Ai Quoc

2014-12-23T23:59:59.000Z

36

Fe-V redox flow batteries  

DOE Patents (OSTI)

A redox flow battery having a supporting solution that includes Cl.sup.- anions is characterized by an anolyte having V.sup.2+ and V.sup.3+ in the supporting solution, a catholyte having Fe.sup.2+ and Fe.sup.3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO.sub.4.sup.2- and Cl.sup.- anions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-07-08T23:59:59.000Z

37

ESS 2012 Peer Review - Acid Based Blend Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Acid Based Blend Membranes for Redox Flow Batteries Acid Based Blend Membranes for Redox Flow Batteries DOE Grant No: DE-SC0006306 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Prof. Arumugam Manthiram University of Texas, Austin, TX 78712 Prof. Fuqiang Liu University of Texas Arlington, Arlington, TX 76019 Conclusions Lynntech, in conjunction with the University of Texas and the University of Texas at Arlington, developed a new series of low-cost polymer blend membranes with high proton conductivity and ultralow vanadium ion permeability. The proton conductivity and physical properties of these membranes are tunable by adjusting the ratio of acid and base components. Membrane conductivity was found to be more critical to

38

High energy density redox flow device  

DOE Patents (OSTI)

Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

Chiang, Yet-Ming; Carter, William Craig; Duduta, Mihai; Limthongkul, Pimpa

2014-05-13T23:59:59.000Z

39

Identifying the Active Site in Nitrogen-Doped Graphene for the VO2+/VO2+ Redox Reaction  

Science Journals Connector (OSTI)

Nitrogen-doped graphene sheets (NGS), synthesized by annealing graphite oxide (GO) with urea at 700–1050 °C, were studied as positive electrodes in a vanadium redox flow battery. ... graphene sheets; nitrogen doping; [VO]2+/[VO2]+ couple reaction; redox flow battery ... (7) Among these energy storage technologies, the vanadium redox flow battery (VRFB) has been considered as a competitive and promising grid energy storage system for renewable energy due to its low cost, high efficiency, and good cycling stability. ...

Jutao Jin; Xiaogang Fu; Qiao Liu; Yanru Liu; Zhiyang Wei; Kexing Niu; Junyan Zhang

2013-05-06T23:59:59.000Z

40

ESS 2012 Peer Review - Low-Cost, High-Performance Hybrid Membranes for Redox Flow Batteries - Hongxing Hu, Amsen Technologies  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DESIGN © 2008 DESIGN © 2008 www.PosterPresentations.com Low-Cost, High-Performance Hybrid Membranes for Redox Flow Batteries Hongxing Hu, Amsen Technologies LLC DOE SBIR Project, Program Manager at DOE: Dr. Imre Gyuk Objectives and Technical Approach Objectives: This SBIR project aims to develop low-cost, high performance hybrid polymeric PEMs for redox flow batteries (RFBs). Such membranes shall have high chemical stability in RFB electrolytes, high proton conductivity, low permeability of vanadium ions, along with high dimensional stability, high mechanical strength and durability, and lower cost than Nafion membranes. Approach: * Hybrid membranes of sulfonated polymers * Balance between different types of polymers for proton conductivity and chemical stability

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Transitioning from Fuel Cells to Redox Flow Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Transitioning From Fuel Cells to Redox Transitioning From Fuel Cells to Redox Flow Cells T. Zawodzinski and Matt Mench University of Tennessee and ORNL Managed by UT-Battelle for the Department of Energy 2 Acknowledgments $$ DOE-OE EPRI GCEP NSF EPSCOR (TN SCORE) UTK Governor's Chair Fund Partner in Crime Matt Mench Managed by UT-Battelle for the Department of Energy 'Peeling the Onion' Personalized History of PEM Fuel Cells We May Recapitulate This for RFBs Catalysis Test System * Small Single Cell * Large Single Cell * Stack * System Layers of the Onion Hot Topic du Jour * Water Management, Membranes * Late '80's, early '90's * Reformate Tolerance, DMFC's * Mid '90's * High Temp Membranes * Late '90's * Durability * Early '00's Modeling * Membrane/ Water * Cathode * Impedance

42

High-Energy Redox-Flow Batteries with Hybrid Metal Foam Electrodes  

Science Journals Connector (OSTI)

A nonaqueous redox-flow battery employing [Co(bpy)3]+/2+ and [Fe(bpy)3]2+/3+ redox couples is proposed for use in large-scale energy-storage applications. ... We successfully demonstrate a redox-flow battery with a practical operating voltage of over 2.1 V and an energy efficiency of 85% through a rational cell design. ... By utilizing carbon-coated Ni-FeCrAl and Cu metal foam electrodes, the electrochemical reactivity and stability of the nonaqueous redox-flow battery can be considerably enhanced. ...

Min-Sik Park; Nam-Jin Lee; Seung-Wook Lee; Ki Jae Kim; Duk-Jin Oh; Young-Jun Kim

2014-06-06T23:59:59.000Z

43

Efficient Solar Energy Storage Using A TiO2/WO3 Tandem Photoelectrode in An All-vanadium Photoelectrochemical Cell  

Science Journals Connector (OSTI)

Abstract Using a photoelectrochemical (PEC) cell to convert solar energy to either electricity or chemical fuels has attracted much attention in the last four decades. However, two major obstacles that hinder wide-spread application of this approach lie in the relatively wide bandgap of chemically stable semiconducotrs, e.g., TiO2, and the rapid recombination of photogenerated charge carriers once they are generated within the semiconductors. We reported herein a method that utilized vanadium redox pairs, which are commonly used in vanadium redox-flow batteries (VRB), to mitigate charge carrier recombination and thus to improve photoresponse in regenerative solar energy storage for the first time. The results showed significant improvement in photocurrent during photo-charging of the all-vanadium PEC storage cell with the addition of a very low morlarity of vanadium redox species (0.01 M) to the acid electrolytes. Additonally, the photocurrent was almost doubled even with a TiO2 electrode when two vanadium redox species were used in a full-cell configuration instead of a half-cell setup. To further enhance the light absorption, a TiO2/WO3 tandem electrode was studied and compared to the TiO2 electrode in various vanadium redox electrolytes. The tandem electrode showed higher photoresponse in all electrolytes investigated. Furthermore, the important role of vanadium redox species and WO3 have been discussed.

Dong Liu; Zi Wei; Chia-jen Hsu; Yi Shen; Fuqiang Liu

2014-01-01T23:59:59.000Z

44

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries  

SciTech Connect

We will present a novel design lithium-organic non-aqueous redox flow battery based on a TEMPO catholyte. This RFB produced desired electrochemical performance exceeding most of the currently reported nonaqueous RFB systems.

Wei, Xiaoliang; Xu, Wu; Vijayakumar, M.; Cosimbescu, Lelia; Liu, Tianbiao L.; Sprenkle, Vincent L.; Wang, Wei

2014-12-03T23:59:59.000Z

45

Practical and commercial issues in the design and manufacture of vanadium flow batteries  

Science Journals Connector (OSTI)

The vanadium flow battery has emerged as one of the most favourable types of flow batteries for a number of reasons, including the lack of cross-contamination that troubled many earlier systems such as the Fe/Cr flow battery. Because the vanadium flow battery employs the same metal ion in both electrolytes, albeit in different oxidation states, there is no cumulative loss in performance, just an effective reversible self-discharge current. The self discharge that occurs in the vanadium flow batteries is limited to the electrolyte volume in the cells. However it can become substantial under low load conditions. The pumps also use power from the battery and may be considered as another source of self discharge. Taking these and maintenance considerations into account the layout of a 10 kW, 100 kWh, 48 V vanadium flow battery was designed as a “Multi-Stage-Operation” system to provide maximum performance at all levels of load, ease of use and optimum maintenance conditions. Experimental A complete energy storage system with 10 kW in power and 100 kWh in energy was designed. It consists of a vanadium flow battery with smart controller and configurable power electronics housed in a weatherproof housing. The battery can be charged and discharged at up to 10 kW and provides up to 100 kWh of energy. The smart controller ensures that the battery operates at maximum efficiency at all times and allows remote observation of various battery parameters, including a reliable state of charge (SOC) measurement. The option of different arrangements of power electronics gives almost complete freedom in specification of electrical output (dc, single or three-phase ac). The battery can also be connected to photovoltaic, wind turbine, diesel/petrol/gas/biogas generators, fuel cells and water turbines to form discrete autonomous power supplies or to be part of a micro-, mini- or smart-grid. The FB10/100 battery for “Multi-Stage-Operation” is comprised of 5 strings of 36–40 cells each in 3 separate fluid circuits. The first fluid circuit, containing a single string, is always actively pumped with electrolyte and electrically connected to the charger and load. The second and third fluid circuits contain 2 strings each and are only actively pumped and electrically connected when the voltage reaches preset limits. When the circuits are in “standby”, i.e. not actively pumped and electrically connected, the self discharge is limited to the small volume of electrolyte in the cells. There is also a significant saving of pumping energy, because 3 pairs of small pumps are used in place of 1 pair of more powerful pumps. Results In “Multi-Stage-Operation” mode, the overall battery performance is improved significantly. This is very important in off-grid installations, where loads are typically small compared to the power levels necessary for charging; i.e. a solar powered telemetric station may use 500 W continuous power but requires fast charging due to the narrow time window when solar energy is available. In example, at a 1 kW load the battery provides 25% more energy when operated in “Multi-Stage-Operation” mode compared to all stacks in operation. Since 2008, several power station have been equipped with FB10/100 storage units and put into operation. Within the presentation a report on the latest results including technical performance and cost issues will be given.

Martha Schreiber; Martin Harrer; Adam Whitehead; Herbert Bucsich; Matthias Dragschitz; Ernst Seifert; Peter Tymciw

2012-01-01T23:59:59.000Z

46

High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Title High Performance Hydrogen/Bromine Redox Flow Battery for Grid-Scale Energy Storage Publication Type Journal Article Year of Publication 2012 Authors Cho, Kyu Taek, Paul L. Ridgway, Adam Z. Weber, Sophia Haussener, Vincent S. Battaglia, and Venkat Srinivasan Journal Journal of the Electrochemical Society Volume 159 Issue 11 Pagination A1806 - A1815 Date Published 01/2012 ISSN 0013-4651 Keywords hydrogen/bromine, redox flow battery Abstract The electrochemical behavior of a promising hydrogen/bromine redox flow battery is investigated for grid-scale energy-storage application with some of the best redox-flow-battery performance results to date, including a peak power of 1.4 W/cm(2) and a 91% voltaic efficiency at 0.4 W/cm(2) constant-power operation. The kinetics of bromine on various materials is discussed, with both rotating-disk-electrode and cell studies demonstrating that a carbon porous electrode for the bromine reaction can conduct platinum-comparable performance as long as sufficient surface area is realized. The effect of flow-cell designs and operating temperature is examined, and ohmic and mass-transfer losses are decreased by utilizing a flow-through electrode design and increasing cell temperature. Charge/discharge and discharge-rate tests also reveal that this system has highly reversible behavior and good rate capability.

47

Redox and ATP control of photosynthetic cyclic electron flow in Chlamydomonas reinhardtii (I) aerobic conditions  

E-Print Network (OSTI)

Redox and ATP control of photosynthetic cyclic electron flow in Chlamydomonas reinhardtii (I, requires the production of ATP and NADPH in a ratio of 3:2. The oxygenic photosynthetic chain can function following two different modes: the linear electron flow which produces reducing power and ATP

48

ESS 2012 Peer Review - Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies - Thomas Kodenkandath, ITN Energy Systems  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Innovative, high energy density Mn-V based RFB electrolytes as a Innovative, high energy density Mn-V based RFB electrolytes as a low-cost alternate to all-Vanadium systems * Low-cost membrane technology, based on renewable biopolymer Chitosan with improved proton conduction & chemical stability, adaptable to Mn-V system * Scale-up of electrolyte and membrane technologies in pursuit of ARPA-E's goal for a 2.5kW/10kWh RFB stack with integrated BoS at a total cost of ~$1000/unit and ~1.2 m 3 footprint ITN Energy Systems, Inc., Littleton, CO 2.5kW/10kWh Redox Flow Battery (RFB) with Low-cost Electrolyte and Membrane Technologies $2.1 M, 33-month program awarded by ARPA-E Sept 7, 2012 Dr. Thomas Kodenkandath High-Performance, Low-cost RFB through Electrolyte & Membrane Innovations Technology Summary

49

Study of the Ce3+/Ce4+ Redox Couple in Mixed-Acid Media (CH3SO3H and H2SO4) for Redox Flow Battery Application  

Science Journals Connector (OSTI)

Study of the Ce3+/Ce4+ Redox Couple in Mixed-Acid Media (CH3SO3H and H2SO4) for Redox Flow Battery Application ... The present paper first reports a kind of supporting electrolyte, mixed-acid media (CH3SO3H and H2SO4), used in redox flow battery (RFB) technology. ... Redox flow battery (RFB) technology(1, 2) has received wide attention in the application for renewable energy storage systems. ...

Zhipeng Xie; Fengjiao Xiong; Debi Zhou

2011-04-19T23:59:59.000Z

50

Vanadium redox-flow batteries Installation at Ris for characterisation measurements  

E-Print Network (OSTI)

in August 2007. Power systems with high penetration of Wind energy/Renewable energy Renewable energy technologies are being installed at an increasing rate in many countries and regions in order to increase the sustainability of the electricity supply. In some power systems is the level of penetration so high

51

Vanadium-redox flow and lithium-ion battery modelling and performance in wind energy applications.  

E-Print Network (OSTI)

??As wind energy penetration levels increase, there is a growing interest in using storage devices to aid in managing the fluctuations in wind turbine output… (more)

Chahwan, John A.

2007-01-01T23:59:59.000Z

52

Performance and cycling of the iron-ion/hydrogen redox flow cell with  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and cycling of the iron-ion/hydrogen redox flow cell with Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Title Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Publication Type Journal Article Year of Publication 2013 Authors Tucker, Michael C., Venkat Srinivasan, Philip N. Ross, and Adam Z. Weber Journal Journal of Applied Electrochemistry Volume 43 Issue 7 Pagination 637 - 644 Date Published 7/2013 ISSN 0021-891X Keywords battery, Flow battery, iron hydrogen cell, progress, redox flow cell Abstract A redox flow cell utilizing the Fe2+/Fe3+ and H-2/H+ couples is investigated as an energy storage device. A conventional polymer electrolyte fuel cell anode and membrane design is employed, with a cathode chamber containing a carbon felt flooded with aqueous acidic solution of iron salt. The maximum power densities achieved for iron sulfate, iron chloride, and iron nitrate are 148, 207, and 234 mW cm(-2), respectively. It is found that the capacity of the iron nitrate solution decreases rapidly during cycling. Stable cycling is observed for more than 100 h with iron chloride and iron sulfate solutions. Both iron sulfate and iron chloride solutions display moderate discharge polarization and poor charge polarization; therefore, voltage efficiency decreases dramatically with increasing current density. A small self-discharge current occurs when catholyte is circulating through the cathode chamber. As a result, a current density above 100 mA cm(-2) is required to achieve high Coulombic efficiency (> 0.9).

53

Transitioning from Fuel Cells to Redox Flow Cells  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Tom Zawodzinski, University of Tennessee and Oak Ridge National Laboratory, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

54

ESS 2012 Peer Review - New Generation Aqueous Base Redox Flow Battery Component Development - Wei Wang, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Generation Aqueous Base Redox Flow Generation Aqueous Base Redox Flow Battery Component Development Wei Wang, Qingtao Luo, Xiaoliang Wei, Bin Li, Zimin Nie, Baowei Chen, Yuyan Shao, Vijayakumar Murugesan, Amy Chen, Gordon, Xia, Liyu Li, Gary Z. Yang, Vincent Sprenkle Pacific Northwest National Laboratory 902 Battelle Boulevard P. O. Box 999 Richland, WA 99352, USA DOE Stationary Energy Storage Program Review, Washington, DC Sept. 26-28, 2012 Dr. Imre Gyuk 1 2 Review of previous work 2.5M, ~30Wh/L, -5~50 o C Mixed-acid VRB Double Energy Density Extend temperature window Charge Discharge Charge Discharge Charge Discharge Catholyte: VO 2+ + Cl - + H 2 O - e VO 2 Cl + 2H + ε co =1.0 V Anolyte: V 3+ + e V 2+ ε ao =-0.25 Overall: VO 2+ + Cl

55

Membrane Separator for Redox Flow Batteries that Utilize Anion Radical Mediators.  

SciTech Connect

A Na + ion conducting polyethylene oxide membrane is developed for an organic electrolyte redox flow battery that utilizes anion radical mediators. To achieve high specific ionic conductivity, tetraethyleneglycol dimethylether (TEGDME) is used as a plasticizer to reduce crystallinity and increase the free volume of the gel film. This membrane is physically and chemically stable in TEGDME electrolyte that contains highly reactive biphenyl anion radical mediators.

Delnick, Frank M.

2014-10-01T23:59:59.000Z

56

ESS 2012 Peer Review - Highly Selective Proton-Conducting Composite Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Membrane for Redox Flow Batteries Membrane for Redox Flow Batteries DOE Grant No: DE-SC0004516 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Introduction * Redox flow batteries (RFBs) are a promising technology to store electrical energy from intermittent renewable sources such as solar and wind power. Although they offer many advantages, RFBs with reduced cost and improved performance (i.e., efficiency and durability) need to be developed to achieve broad market penetration. * Ion exchange membranes in RFBs separate two soluble redox couples should allow rapid proton transport and suppress transport of the reactive species between anode and cathode compartments. Nafion

57

ESS 2012 Peer Review - Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries - Fei Wang, EIC Laboratories  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries Low Cost and Highly Selective Composite Membrane for Redox Flow Batteries Fei Wang, Dharmasena Peramunage, James M. Sylvia, and Monsy M. Jocob EIC Laboratories, Inc. 111 Downey Street, Norwood, MA 02062. www.eiclabs.com Identification of the Problem and Technical Approach Redox flow batteries (RFB) hold great promise for large scale electrochemical energy storage. A critical component of RFB is the membrane which separates anode and cathode compartments. The current state-of-the-art membrane, NAFION is too expensive, lacks selectivity, permitting leakage between anode and cathode electrolyte compartments. EIC is developing a novel bilayer, interpenetrating network membrane. Thin Nafion layer for anode side protection providing oxidative stability. The bulk part of the membrane consists of a block

58

Some Lessons Learned from 20 Years in RedOx Flow Battery R&d  

NLE Websites -- All DOE Office Websites (Extended Search)

lessons learned from 20 years in lessons learned from 20 years in RedOx Flow Battery R&D Dr Steve Clarke, CEO Applied Intellectual Capital, Alameda CAc DOE Workshop Washington DC March 2012 www.apicap.com Contents ● AIC's involvement in RFB R&D ● Some key lessons learned ● Some remaining challenges to be overcome 2 Applied Intellectual Capital ● Technology consulting  Electrochemical and materials focus  Clients include leading industrials, VCs, DOE, DOD and EPA  33,000 ft. facility for laboratory, engineering, rapid prototyping and testing ● Technology venturing (own micro- fund)  IP generated by consulting and R&D  Leverages labs, facilities and consulting successes ● Combined resources  Proven business development team  Start-up to IPO

59

ESS 2012 Peer Review - Component Research for Redox Flow Batteries - Tom Zawodzinski, ORNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Battelle Battelle for the Department of Energy Component Research for Redox Flow Batteries Tom Zawodzinski and Che-Nan (Josh) Sun With help from Jamie Lawton, Zhijiang Tang, Doug Aaron, Alex Papandrew, Qinhua Liu, Matt Mench (UTK) Frank Delnick (SNL) Thanks to Imre Gyuk (OE) and team at UTK Managed by UT-Battelle for the Department of Energy Approach This project is a little different from many others in the portfolio We are not looking into alternative battery chemistries per se We are doing work to guide you in choices of materials and hardware designs to make all RFBs better! Focus on components, diagnostics to drive understanding how to improve Managed by UT-Battelle for the Department of Energy Goals and Tasks 1. Demonstrate improved performance of RFBs in pre-

60

ESS 2012 Peer Review - Single Substance Organic Redox Flow Battery - Paul Rasmussen, Vinazene  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Charging Mechanism Charging Mechanism The Z compound, as described in Vinazene Patent 8,080,327, undergoes the following half reactions during charging: Z Z + + e - E 0 = -1.3V Z + e -  Z - E 0 = -1.5V _____________________ 2Z  Z - + Z + E 0 = -2.8V A Single Substance Organic Redox Flow Battery -+- -+- Components Compound Z Tetraethylammonium Tetrafluoroborate (TEA-BF 4 ) Maintains Electroneutrality Acetonitrile (MeCN) Dielectric and Transport medium Abstract Abundant energy, in the exajoule range, is available everyday from solar and wind flux. However, green sources of this energy are subject to intermittent and/or periodic fluctuations. Mitigation of supply obstacles is possible through the use of cost effective and dispatchable energy storage methods. During Phase I of this SBIR

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

ESS 2012 Peer Review - Estimation of Capital and Levelized Cost for Redox Flow Batteries - Vilayanur Viswanathan, PNNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Estimation of Capital and Levelized Estimation of Capital and Levelized Cost for Redox Flow Batteries V. Viswanathan, A. Crawford, L. Thaller 1 , D. Stephenson, S. Kim, W. Wang, G. Coffey, P. Balducci, Z. Gary Yang 2 , Liyu Li 2 , M. Kintner-Meyer, V. Sprenkle 1 Consultant 2 UniEnergy Technology September 28, 2012 USDOE-OE ESS Peer Review Washington, DC Dr. Imre Gyuk - Energy Storage Program Manager, Office of Electricity Delivery and Energy Reliability 1 What are we trying to accomplish? PNNL grid analytics team has established ESS cost targets for various applications PNNL cost/performance model estimates cost for redox flow battery systems of various chemistries drives research internally to focus on most important components/parameters/metrics for cost reduction and performance improvement

62

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox...  

NLE Websites -- All DOE Office Websites (Extended Search)

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries. TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries. Abstract: We will...

63

Some Lessons Learned from 20 Years in RedOx Flow Battery R&d  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Steve Clarke, Applied Intellectual Capital, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

64

What's Next for Vanadium Dioxide?  

NLE Websites -- All DOE Office Websites (Extended Search)

How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy...

65

ESS 2012 Peer Review - Flow Battery Membrane - David Ofer, Tiax  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Flow Battery Membrane Flow Battery Membrane Energy Storage Systems Program (ESS) Peer Review and Update Meeting 2012 Jack Treger treger.jack@tiaxllc.com Washington DC, September 27, 2012 Flow Battery Membrane Background and Purpose 1 Vanadium redox batteries (VRB) for energy storage require improved ion- selective membranes. * Vanadium permeation across current membranes leads to self-discharge and decreases cycling efficiency: - Negative half cell: V 2+ V 3+ + e - E o = -0.255V - Positive half cell: e - + VO 2 + + 2H + VO 2+ + H 2 O E o = 1.00V . * Current perfluorosulfonic acid polymer membranes are costly. * TIAX is developing a novel composite bipolar membrane: - Composite anionic membrane minimizes content of costly perfluorosulfonic acid polymer - Made bipolar by a cationic surface layer to improve selectivity for

66

Facile synthesized nanorod structured vanadium pentoxide for...  

NLE Websites -- All DOE Office Websites (Extended Search)

synthesized nanorod structured vanadium pentoxide for high-rate lithium batteries. Facile synthesized nanorod structured vanadium pentoxide for high-rate lithium batteries....

67

Redox Flow Batteries, a Review  

E-Print Network (OSTI)

and water. For a fuel cell, hydrogen oxidizes at the anode5. 2.1.5 Hydrogen-based systems A fuel cell takes a fuel (

Weber, Adam Z.

2013-01-01T23:59:59.000Z

68

Enthalpy of Solution for Anhydrous VOSO4 and Estimated Enthalpy of Reaction for Formation of the Ion Pair [VOSO4]0  

Science Journals Connector (OSTI)

The vanadium redox flow battery (VRB) is showing great promise as an efficient new energy-storage system for a wide range of applications. ... Oriji, G.; Katayama, Y.; Miura, T. Investigation on V(IV)/V(V) species in a vanadium redox flow battery Electrochim. ... Investigation on V(IV)/V(V) species in a vanadium redox flow battery ...

Jian-Guo Liu; Wei-Feng Xue; Ye Qin; Chuan-Wei Yan; Jia-Zhen Yang

2009-04-01T23:59:59.000Z

69

Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum...  

NLE Websites -- All DOE Office Websites (Extended Search)

Vanadium, Titanium, Molybdenum, and Tungsten on Mesoporous Silica using Atomic Layer Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum, and Tungsten on...

70

Vanadium catalysts break down biomass for fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

Vanadium catalysts break down biomass into useful components Breaking down biomass could help in converting biomass to fuels. March 26, 2012 Biomass Due to diminishing petroleum...

71

Magnetism in small vanadium clusters  

Science Journals Connector (OSTI)

Using the self-consistent-field molecular-orbital theory and the density-functional approximation, we show that vanadium could become magnetic if its size and dimension were constrained. This is illustrated for vanadium forming clusters with body-centered-cubic (bcc) geometry as well as for linear chains. The magnetic moment of the bcc clusters is found to vanish abruptly as the size increases, while the clusters always retain their moment in the linear-chain configurations. The moments are also found to be finite for large interatomic spacings irrespective of the cluster topology, and tend to vanish when the interatomic distances are reduced. The results are explained by using a simple Stoner criterion.

Feng Liu; S. N. Khanna; P. Jena

1991-04-01T23:59:59.000Z

72

Vanadium catalysts break down biomass for fuels  

E-Print Network (OSTI)

- 1 - Vanadium catalysts break down biomass for fuels March 26, 2012 Vanadium catalysts break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose biomass into high-value commodity chemicals. The journal Angewandte Chemie International Edition published

73

High power density self-cooled lithium-vanadium blanket.  

SciTech Connect

A self-cooled lithium-vanadium blanket concept capable of operating with 2 MW/m{sup 2} surface heat flux and 10 MW/m{sup 2} neutron wall loading has been developed. The blanket has liquid lithium as the tritium breeder and the coolant to alleviate issues of coolant breeder compatibility and reactivity. Vanadium alloy (V-4Cr-4Ti) is used as the structural material because it can accommodate high heat loads. Also, it has good mechanical properties at high temperatures, high neutron fluence capability, low degradation under neutron irradiation, good compatibility with the blanket materials, low decay heat, low waste disposal rating, and adequate strength to accommodate the electromagnetic loads during plasma disruption events. Self-healing electrical insulator (CaO) is utilized to reduce the MHD pressure drop. A poloidal coolant flow with high velocity at the first wall is used to reduce the peak temperature of the vanadium structure and to accommodate high surface heat flux. The blanket has a simple blanket configuration and low coolant pressure to reduce the fabrication cost, to improve the blanket reliability, and to increase confidence in the blanket performance. Spectral shifter, moderator, and reflector are utilized to improve the blanket shielding capability and energy multiplication, and to reduce the radial blanket thickness. Natural lithium is used to avoid extra cost related to the lithium enrichment process.

Gohar, Y.; Majumdar, S.; Smith, D.

1999-07-01T23:59:59.000Z

74

Vanadium catalysts break down biomass for fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

Vanadium catalysts break down biomass for fuels Vanadium catalysts break down biomass for fuels Vanadium catalysts break down biomass into useful components Breaking down biomass could help in converting biomass to fuels. March 26, 2012 Biomass Due to diminishing petroleum reserves, non-food biomass (lignocellulose) is an attractive alternative as a feedstock for the production of renewable chemicals and fuels. Get Expertise Researcher Susan Hanson Inorganic Isotope & Actinide Chem Email Researcher Ruilian Wu Bioenergy & Environmental Science Email Researcher Louis "Pete" Silks Bioenergy & Environmental Science Email Vanadium is an inexpensive, earth-abundant metal that is well suited for promoting oxidations in air. Vanadium catalysts break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose) is

75

Methods for making lithium vanadium oxide electrode materials  

DOE Patents (OSTI)

A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

Schutts, Scott M. (Menomonie, WI); Kinney, Robert J. (Woodbury, MN)

2000-01-01T23:59:59.000Z

76

A coupled-physics model for the vanadium oxygen fuel cell  

Science Journals Connector (OSTI)

Abstract A stationary two-dimensional model for the vanadium oxygen fuel cell is developed. The model consists of a single cell with two membranes, set up as of two half-cells and an intermediate chamber. The transport and balance of mass, momentum and charge are linked to the electrochemical reaction kinetics of the vanadium species and oxygen. The kinetic model for the cathode half-cell is extended by an empirical logistic function to describe the transient behavior of the half-cell. Additionally, experiments are conducted on a single vanadium oxygen fuel cell with 40 cm2 active membrane area. The experimental results are used to validate the simulation data. The effects of constant current discharging, polarization behavior and different flow rates on the cathode overpotential are studied by means of this model.

F.T. Wandschneider; M. Küttinger; J. Noack; P. Fischer; K. Pinkwart; J. Tübke; H. Nirschl

2014-01-01T23:59:59.000Z

77

Method for preparing high purity vanadium  

DOE Patents (OSTI)

A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

Schmidt, Frederick (Ames, IA); Carlson, O. Norman (Ames, IA)

1986-09-09T23:59:59.000Z

78

Vanadium Respiration by Geobacter metallireducens: Novel Strategy for In Situ Removal of Vanadium from Groundwater  

Science Journals Connector (OSTI)

...and can be found in uranium-bearing minerals...reductive precipitation of uranium from contaminated groundwater...a former vanadium and uranium ore processing facility...liter (6 muM) human health risk-based concentration...vanadium(V) became depleted, with a generation time...

Irene Ortiz-Bernad; Robert T. Anderson; Helen A. Vrionis; Derek R. Lovley

2004-05-01T23:59:59.000Z

79

An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions  

Open Energy Info (EERE)

Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Details Activities (0) Areas (0) Regions (0) Abstract: Reactive chemical transport occurs in a variety of geochemical environments, and over a broad range of space and time scales. Efficiency of the chemical speciation and water-rock-gas interaction calculations is important for modeling field-scale multidimensional reactive transport problems. An improved efficient model, REACT, for simulating water-rock-gas interaction under equilibrium and kinetic conditions, has been developed.

80

In Charge of the World: Electrochemical Energy Storage  

Science Journals Connector (OSTI)

In a Perspective in this issue, Ding et al. provide a survey of the current understanding of vanadium RFBs from materials to stacks (Ding, C.; Zhang, H.; Li, X.; Liu, T.; Xing, F. Vanadium Flow Battery for Energy Storage: Prospects and Challenges. ... Rychcik, M.; Skyllas-Kazacos, M.Characteristics of a New All-Vanadium Redox Flow Battery J. Power Sources 1988, 22, 59– 67 ... Characteristics of a new all-vanadium redox flow battery ...

Arumugam Manthiram; Yongzhu Fu; Yu-Sheng Su

2013-04-18T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Towards Understanding the Poor Thermal Stability of V5+ Electrolyte...  

NLE Websites -- All DOE Office Websites (Extended Search)

the Poor Thermal Stability of V5+ Electrolyte Solution in Vanadium Redox Flow Batteries. Towards Understanding the Poor Thermal Stability of V5+ Electrolyte Solution in...

82

Cellstrom | Open Energy Information  

Open Energy Info (EERE)

Zip: 2345 Sector: Solar Product: Austria based developer of vanadium redox flow batteries for solar plants. References: Cellstrom1 This article is a stub. You can help...

83

Energy Storage for the Power Grid  

ScienceCinema (OSTI)

The iron vanadium redox flow battery was developed by researchers at Pacific Northwest National Laboratory as a solution to large-scale energy storage for the power grid.

Wang, Wei; Imhoff, Carl; Vaishnav, Dave

2014-06-12T23:59:59.000Z

84

Short communication Effect of vanadium redox species on photoelectrochemical behavior of TiO2  

E-Print Network (OSTI)

. Alternative and sustainable energy sources such as solar, wind, tidal power, geothermal, hydroelectricity implementation is hydrogen handling. Although molecular hydrogen has very high energy density on a mass basis and TiO2/WO3 photo-electrodes Dong Liu a , Fuqiang Liu a,*, Jianguo Liu b a Electrochemical Energy Lab

Liu, Fuqiang

85

Irradiation creep of vanadium-base alloys.  

SciTech Connect

A study of irradiation creep in vanadium-base alloys is underway with experiments in the Advanced Test Reactor (ATR) and the High Flux Isotope Reactor (HFIR) in the US. Test specimens are thin-wall sealed tubes with internal pressure loading. The results from the initial ATR irradiation at low temperature (200-300 C) to a neutron damage level of 4.7 dpa show creep rates ranging from {approx}0 to 1.2 x 10{sup {minus}5}/dpa/MPa for a 500-kg heat of V-4Cr-4Ti alloy. These rates were generally lower than reported from a previous experiment in BR-10. Because both the attained neutron damage levels and the creep strains were low in the present study, however, these creep rates should be regarded as only preliminary. Substantially more testing is required before a data base on irradiation creep of vanadium alloys can be developed and used with confidence.

Tsai, H.; Matsui, H.; Billone, M. C.; Strain, R. V.; Smith, D. L.

1998-05-18T23:59:59.000Z

86

Vanadium-pumped titanium x-ray laser  

DOE Patents (OSTI)

A resonantly photo-pumped x-ray laser is formed of a vanadium and titanium foil combination that is driven by two beams of intense line focused optical laser radiation. Ground state neon-like titanium ions are resonantly photo-pumped by line emission from fluorine-like vanadium ions. 4 figs.

Nilsen, J.

1992-05-26T23:59:59.000Z

87

Vanadium-pumped titanium x-ray laser  

DOE Patents (OSTI)

A resonantly photo-pumped x-ray laser (10) is formed of a vanadium (12) and titanium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state neon-like titanium ions (34) are resonantly photo-pumped by line emission from fluorine-like vanadium ions (32).

Nilsen, Joseph (Livermore, CA)

1992-01-01T23:59:59.000Z

88

Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado  

Energy.gov (U.S. Department of Energy (DOE))

Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado

89

Method to Remove Uranium/Vanadium Contamination from Groundwater  

DOE Patents (OSTI)

A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

Metzler, Donald R.; Morrison Stanley

2004-07-27T23:59:59.000Z

90

Scientists capture 'redox moments' in living cells | EMSL  

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Scientists capture 'redox moments' in living cells Scientists capture 'redox moments' in living cells Better understanding of hardy bacteria enhances tool for biofuel creation...

91

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared...  

NLE Websites -- All DOE Office Websites (Extended Search)

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft Landing. Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft...

92

Plasma enhanced chemical vapor deposition (PECVD) method of forming vanadium oxide films and vanadium oxide thin-films prepared thereby  

DOE Patents (OSTI)

A method is disclosed of forming a vanadium oxide film on a substrate utilizing plasma enhanced chemical vapor deposition. The method includes positioning a substrate within a plasma reaction chamber and then forming a precursor gas comprised of a vanadium-containing chloride gas in an inert carrier gas. This precursor gas is then mixed with selected amounts of hydrogen and oxygen and directed into the reaction chamber. The amounts of precursor gas, oxygen and hydrogen are selected to optimize the final properties of the vanadium oxide film An rf plasma is generated within the reaction chamber to chemically react the precursor gas with the hydrogen and the oxygen to cause deposition of a vanadium oxide film on the substrate while the chamber deposition pressure is maintained at about one torr or less. Finally, the byproduct gases are removed from the plasma reaction chamber.

Zhang, Ji-Guang (Golden, CO); Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO); Turner, John A. (Littleton, CO); Liu, Ping (Lakewood, CO)

2000-01-01T23:59:59.000Z

93

Interactions of vanadium-rich slags with crucible materials during viscosity measurements  

Science Journals Connector (OSTI)

Petroleum coke (petcoke) ash can contain high concentrations of vanadium ... Vanadium oxide is a major impurity in the petcoke slags which is not found in coal ... gasification of coal–petroleum coke blended feed...

Alexander Y. Ilyushechkin; Marc A. Duchesne; San S. Hla…

2013-02-01T23:59:59.000Z

94

ORNUTM-13249 DRAFT AN ECOLOGICAL INVESTIGATION OF A VANADIUM  

Office of Legacy Management (LM)

ORNUTM-13249 ORNUTM-13249 DRAFT AN ECOLOGICAL INVESTIGATION OF A VANADIUM AND URANIUM MILL TAILINGS SITE 1. G. Smith, M. J. Peterson, and M. G. Ryon Biological Monitoring and Abatement Program Environmental Sciences Division Oak RidgeNational Laboratory Oak Ridge, Tennessee May 1996 Prepared for Gretchen A. Pierce Healthand Safety Research Division Environmental Technology Section Oak RidgeNational Laboratory GrandJunction, Colorado Prepared by the Environmental Sciences Division Oak RidgeNational Laboratory Oak Ridge, Tennessee 37831 Managed by LOCKHEED MARTIN ENERGY RESEARCH CORP. for the U. S. DEPARTMENT OF ENERGY under contract DE-AC05-960R22464 I. INTRODUCTION From 1942 through 1946, the Vanadium Corporation of America operated a vanadium and uranium mill in Monticello, Utah (Rust Geotech 1995a). In 1948, the U. S. Atomic Energy Commission (AEC) purchased the mill site

95

Measurement of Lattice Vibrations in Vanadium by Neutron Scattering  

Science Journals Connector (OSTI)

The energy spectrum of slow neutrons inelastically scattered by vanadium metal has been measured by the time-of-flight technique. The neutrons gain energy by absorbing quanta of lattice vibration energy (phonons). As the nuclear scattering amplitude of vanadium is incoherent, the energy distribution of scattered neutrons is directly related to the frequency distribution of lattice vibrations. The measured neutron energy spectrum, as well as the derived frequency distribution, shows a clearly resolved double peak. This structure, which is distinctly different from the simple Debye distribution, but expected on the basis of detailed calculations, has heretofore not been amenable to direct measurement. The measured frequency distribution is compared with calculations for a body-centered cubic lattice by the Born-von Kármán theory and qualitative agreement is obtained. A more exact comparison awaits measurement of the elastic constants of vanadium.

C. M. Eisenhauer; I. Pelah; D. J. Hughes; H. Palevsky

1958-02-15T23:59:59.000Z

96

MICROSCALE METABOLIC, REDOX AND ABIOTIC REACTIONS IN HANFORD 300 AREA SUBSURFACE SEDIMENTS  

SciTech Connect

The Hanford 300 Area is a unique site due to periodic hydrologic influence of river water resulting in changes in groundwater elevation and flow direction. This area is also highly subject to uranium remobilization, the source of which is currently believed to be the region at the base of the vadose zone that is subject to period saturation due to the changes in the water levels in the Columbia River. We found that microbial processes and redox and abiotic reactions which operate at the microscale were critical to understanding factors controlling the macroscopic fate and transport of contaminants in the subsurface. The combined laboratory and field research showed how microscale conditions control uranium mobility and how biotic, abiotic and redox reactions relate to each other. Our findings extended the current knowledge to examine U(VI) reduction and immobilization using natural 300 Area communities as well as selected model organisms on redox-sensitive and redox-insensitive minerals. Using innovative techniques developed specifically to probe biogeochemical processes at the microscale, our research expanded our current understanding of the roles played by mineral surfaces, bacterial competition, and local biotic, abiotic and redox reaction rates on the reduction and immobilization of uranium.

Beyenal, Haluk [WSU] [WSU; McLEan, Jeff [JCVI] [JCVI; Majors, Paul [PNNL] [PNNL; Fredrickson, Jim [PNNL] [PNNL

2013-11-14T23:59:59.000Z

97

ET Kinetics of Bifunctional Redox Protein Maquettes  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetics of Bifunctional Redox Protein Maquettes Kinetics of Bifunctional Redox Protein Maquettes Mitchell W. Mutz, James F. Wishart and George L. McLendon Adv. Chem Ser. 254, Ch. 10, pp. 145-159 Abstract: We prepared three bifunctional redox protein maquettes based on 12-, 16-, and 20-mer three-helix bundles. In each case, the helix was capped with a Co(III) tris-bipyridyl electron acceptor and also functionalized with a C-terminal viologen (1-ethyl-1'-ethyl-4,4'-bipyridinium) donor. Electron transfer (ET) was initiated by pulse radiolysis and flash photolysis and followed spectrometrically to determined average, concentration-independent, first-order rates for the 16-mer and 20-mer maquettes. For the 16-mer bundle, the alpha-helical content was adjusted by the addition of urea or trifluoroethanol to solutions containing the metalloprotein. This

98

Determination of Volume Properties of Aqueous Vanadyl Sulfate at 283.15 to 323.15 K  

Science Journals Connector (OSTI)

(1) The all vanadium redox flow battery (VRFB), an effective energy-storage system proposed by Skyllas–Kazacos et al.(2-4) is one of the promising candidates. ... Zhao, P.; Zhang, H.-M.; Zhou, H.-T.; Chen, J.; Gao, S.-J; Yi, B.-L.Characteristics and performance of 10 kW class all-vanadium redox-flow battery stack J. Power Sources 2006, 162 ( 2) 1416– 1420 ... Characteristics and performance of 10 kW class all-vanadium redox-flow battery stack ...

Wei-Guo Xu; Ye Qin; Fei Gao; Jian-Guo Liu; Chuan-Wei Yan; Jia-Zhen Yang

2014-04-03T23:59:59.000Z

99

Computing Redox Potentials in Solution: Density Functional Theory as A Tool for Rational Design of Redox Agents  

E-Print Network (OSTI)

of Redox Agents Mu-Hyun Baik and Richard A. Friesner* Department of Chemistry and Center for Biomolecular in an industrial setting,8 lies in understanding and controlling the redox properties of the reactive species. Thus methods for predicting redox potentials in solution phase and give a systematic assessment of the required

Baik, Mu-Hyun

100

Isobutane oxidation in the presence of a soluble propylene glycol/vanadium catalyst  

SciTech Connect

A method is described for oxidizing isobutane with an oxygen-containing material in the presence of an effective amount of a soluble propylene glycol/vanadium catalyst.

Sanderson, J.R.; Marquis, E.T.

1989-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

High-throughput synthesis and characterization of vanadium mixed metal oxide pigments using synchroton radiation.  

E-Print Network (OSTI)

??UNA range of inorganic vanadium mixed metal oxides, with potential applications as inorganic pigments, have been synthesised and characterised in terms of their crystal structure,… (more)

Russu, Sergio

2008-01-01T23:59:59.000Z

102

E-Print Network 3.0 - aluminia supported vanadium Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

sively studied... of the less expen- sive apparatus and its versatility. As an electrochromic material, however, vanadium Source: Artuso, Florinda - Department of Environment,...

103

Vanadium pentoxide modified polycrystalline silicon anode for active-matrix organic light-emitting diodes  

E-Print Network (OSTI)

Vanadium pentoxide modified polycrystalline silicon anode for active-matrix organic light to be an efficient anode for organic light-emitting diode OLED X. L. Zhu, J. X. Sun, H. J. Peng, Z. G. Meng, M. Wong an ultrathin vanadium pentoxide V2O5 layer on the p-Si anode, the performance of the OLED can be greatly

104

Organometallics 1987, 6, 2551-2556 2551 Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis  

E-Print Network (OSTI)

, with sodium naphthalenide in thf under carbon monoxide gives the titanium(0) carbonyl [~-BUSOrganometallics 1987, 6, 2551-2556 2551 Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis of the fourfold and threefold faces; the titanium and vanadium structures may also be described in terms of a face

Girolami, Gregory S.

105

TITANIUM AND VANADIUM CHEMISTRY IN LOW-MASS DWARF STARS Katharina Lodders  

E-Print Network (OSTI)

. The most profound effect of a decrease in temperature is that carbon monoxide (CO) con- verts to methaneTITANIUM AND VANADIUM CHEMISTRY IN LOW-MASS DWARF STARS Katharina Lodders Planetary Chemistry The equilibrium gas and condensation chemistry of titanium and vanadium in M, L, and T dwarf atmos- pheres

Fegley Jr., Bruce

106

Factors Controlling Redox Speciation of Plutonium and Neptunium in Extraction Separation Processes  

SciTech Connect

The objective of the project was to examine the factors controlling redox speciation of plutonium and neptunium in UREX+ extraction in terms of redox potentials, redox mechanism, kinetics and thermodynamics. Researchers employed redox-speciation extractions schemes in parallel to the spectroscopic experiments. The resulting distribution of redox species w studied uring spectroscopic, electrochemical, and spectro-electrochemical methods. This work reulted in collection of data on redox stability and distribution of redox couples in the nitric acid/nitrate electrolyte and the development of redox buffers to stabilize the desired oxidation state of separated radionuclides. The effects of temperature and concentrations on the redox behavior of neptunium were evaluated.

Paulenova, Alena [Principal Investigator; Vandegrift, III, George F. [Collaborator

2013-09-24T23:59:59.000Z

107

Multifunktionales Batteriespeichersystem  

Science Journals Connector (OSTI)

Die Pilotanlage besteht aus einer Vanadium-Redox-Flow-Batterie (VRF-Batterie) des Typs CellCube FB 10-100 mit einer Speicherkapazität von...9]) (Abb. 1). Abb. 1. ...

Roland Sterrer; Wolfgang Prüggler

2013-09-01T23:59:59.000Z

108

Simple and accurate correlation of experimental redox potentials...  

NLE Websites -- All DOE Office Websites (Extended Search)

redox potentials and DFT-calculated HOMOLUMO energies of polycyclic aromatic hydrocarbons Authors: Mndez-Hernndez, D.D,, Tarakeshwar, P., Gust, D,. Moore,T.A., Moore,...

109

Redox shuttles for lithium ion batteries  

DOE Patents (OSTI)

Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

2014-11-04T23:59:59.000Z

110

Microstructure Change of SOFC Anode Caused by Electrochemical Redox Cycles  

E-Print Network (OSTI)

Microstructure Change of SOFC Anode Caused by Electrochemical Redox Cycles Norikazu Takagi@thtlab.t.u-tokyo.ac.jp Abstract During SOFC operation with typical Ni-YSZ anode, Ni is always subjected to the risk of oxidation the effect of redox cycles on anode performance has been intensively investigated, quantitative change

Kasagi, Nobuhide

111

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal  

E-Print Network (OSTI)

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal Interlinked Protein Folding.10.011 SUMMARY Disruption of protein folding in the endoplasmic reticulum (ER) causes unfolded proteins to accumu is active. Because ER redox po- tential is optimized for oxidative protein folding, we reasoned

Mullins, Dyche

112

E-Print Network 3.0 - altered redox homeostasis Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

redox cycling in hyper alkaline sediment-water systems. Ian Burke, Rob Mortimer and Doug Stewart (Civil Engineering) Summary: Biogeochemical redox cycling in hyper alkaline...

113

DOE - Office of Legacy Management -- Vanadium Corp of America - PA 15  

Office of Legacy Management (LM)

Vanadium Corp of America - PA 15 Vanadium Corp of America - PA 15 FUSRAP Considered Sites Site: Vanadium Corp. of America (PA.15) Eliminated from further consideration under FUSRAP. Designated Name: Not Designated Alternate Name: UMTRAP Vicinity Property No. CA-401 PA.15-5 Location: Mayer Street - Collier Township , Bridgeville , Pennsylvania PA.15-1 Evaluation Year: 1985 PA.15-2 Site Operations: Faclility used to grind pitchblende ore during the early 1940's for processing by Vitro at Canonsburg. Conducted research and developed processes for concentration of Colorado Plateau ores (uranium-vanadium) PA.15-3 Site Disposition: Eliminated - site cleaned up as a vicinity property of the Canonsburg Site in 1986 under the Uranium Mill Tailings Remedial Action Program (UMTRAP). PA.15-5

114

Effect of manganese addition on hydrogen storage performance of vanadium-based BCC hydrogen storage alloys  

Science Journals Connector (OSTI)

The effect of manganese addition on hydrogen storage performance of vanadium-based BCC alloys was ... plateau pressure and a reverse effect on maximum hydrogen storage capacity. However, an effective hydrogen storage

Chan-Yeol Seo; Zhao-Liang Zhang; Jin-Ho Kim…

2002-07-01T23:59:59.000Z

115

Structure and properties of a rapidly solidified dispersion strengthened aluminum-iron-vanadium-silicon alloy  

E-Print Network (OSTI)

STRUCTURE AND PROPERTIES OF A RAPIDLY SOLIDIFIED DISPERSION STRENGTHENED ALUMINUM-IRON-VANADIUM-SILICON ALLOY A Thesis by STAFFORD DEAN LITTLE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Mechanical Engineering STRUCTURE AND PROPERTIES OF A RAPIDLY SOLIDIFIED DISPERSION STRENGTHENED ALUMINUM-IRON-VANADIUM-SILICON ALLOY A Thesis by STAFFORD DEAN LITTLE Approved...

Little, Stafford Dean

2012-06-07T23:59:59.000Z

116

Removal of Vanadium(IV) from Aqueous Solutions by Adsorption Process with Aluminum-Pillared Bentonite  

Science Journals Connector (OSTI)

The objective of this research work is to investigate the possibility of using a natural bentonite clay as a precursor to produce aluminum-pillared clay (Al?PILC) for the removal of vanadium(IV) from aqueous solutions. ... The original bentonite and Al?PILC were characterized with the help of surface area analyzer, X-ray diffraction, scanning electron microscopy, and potentiometric titration. ... The adsorption of vanadium(IV) onto Al?PILC has been dynamically and thermodynamically investigated. ...

D. M. Manohar; B. F. Noeline; T. S. Anirudhan

2005-07-08T23:59:59.000Z

117

Tantalum and vanadium response to shock-wave loading at normal and elevated temperatures. Non-monotonous decay of the elastic wave in vanadium  

SciTech Connect

The evolution of the elastic precursor waves in pure tantalum and vanadium is presented at normal and elevated temperatures over propagation distances that ranged from 0.125 to 3?mm. Measurements were performed in order to obtain experimental data about the temperature-rate dependence of the yield stress of the two metals. With increasing propagation distance, the rate of the decay of elastic precursor decreases, as the shear stress in the elastic precursor wave approaches the Peierls stresses. It has been found that the decay, with propagation distance, of the post-spike minimum of the spike-like elastic precursor wave in vanadium is essentially non-monotonous. The experiments also revealed that annealing of tantalum and vanadium increases their Hugoniot elastic limit. The anomalous increase of the high strain rate yield stress with temperature, as observed earlier for some FCC and HCP metals, has not been detected in these measurements.

Zaretsky, E. B. [Department of Mechanical Engineering, Ben Gurion University, 84105 Beer Sheva (Israel); Kanel, G. I. [Joint Institute for High Temperatures RAS, Izhorskaya 13, bld.2, 125412 Moscow (Russian Federation)

2014-06-28T23:59:59.000Z

118

Iron Cycling and Redox Evolution in the Precambrian  

E-Print Network (OSTI)

Green, W.J. , 2002. Rare earth elements in the water columnVangaans, P. , 1988. Rare-Earth Element Distributions inRedox cycling of rare earth elements in the suboxic zone of

Planavsky, Noah John

2012-01-01T23:59:59.000Z

119

Redox Active Catalysts Utilizing Earth Abundant Metals | Center...  

NLE Websites -- All DOE Office Websites (Extended Search)

Redox Active Catalysts Utilizing Earth Abundant Metals 14 Mar 2014 Ryan Trovitch has recently joined the team of the BISfuel PIs. He is an Assistant Professor at the Department of...

120

An evaluation of the acute toxicity of vanadium to five estuarine species: Penaeus aztecus, Rangia cuneata, Cyprinodon variegatus, Neanthes arenaceodentata and Brachionus plicatilis / b  

E-Print Network (OSTI)

through the use of blank tissue samples spiked with known quantities of the vanadium standard. Instrumental neutron activation analysis (INAA) was used both to check the validity of the vanadium standard used for spectrophotometric analysis... is shown in Figure 2. The working region of the standard curve used for routine analysi. . of vanadium was the region between 0. 02 and 1 . 06 absorbance units or I to 40 micrograms of' vanadium per gram of sample. It was also determined that +he...

Hobson, David Wayne

1978-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Under Pressure, Vanadium Won't Turn Down the Volume | Advanced Photon  

NLE Websites -- All DOE Office Websites (Extended Search)

New Nanoscale Engineering Breakthrough Points to Hydrogen-Powered Vehicles New Nanoscale Engineering Breakthrough Points to Hydrogen-Powered Vehicles Patterning High-density Arrays of Nanospheres with Self Assembly Cells Forming Blood Vessels Send Their Copper to the Edge A Molecular Cause for One Form of Deafness Water Theory is Watertight Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Under Pressure, Vanadium Won't Turn Down the Volume MARCH 7, 2007 Bookmark and Share The upper panel is the diffraction pattern of vanadium recorded on an image plate at 18 GPa under hydrostatic conditions. The indexing is based on a body centered cubic lattice. The lower panel is the diffraction pattern of vanadium at 73 GPa. Inserts are zoomed images showing the splitting of 110,

122

Study of hydrogen isotopes super permeation through vanadium membrane on 'Prometheus' setup  

SciTech Connect

To develop the membrane pumping technology by means of superpermeable membranes at RFNC-VNIIEF in the 'Prometheus' setup, the experiments on superpermeation of hydrogen isotopes through metal membranes were carried out. The experimental results on superpermeation of thermal atoms of hydrogen isotopes including tritium through a cylindrical vanadium membrane are presented. The possibility of effective pumping, compression and recuperation of hydrogen isotopes by means of superpermeable membrane was demonstrated. The evaluation of membrane pumping rates and asymmetry degree of pure vanadium membrane was given. The work was performed under the ISTC-2854 project. (authors)

Musyaev, R. K.; Yukhimchuk, A. A.; Lebedev, B. S. [Russian Federal Nuclear Center-All-Russian Research Inst. of Experimental Physics RFNC-VNIIEF, 607188, Sarov, Nizhny Novgorod Region (Russian Federation); Busnyuk, A. O.; Notkin, M. E.; Samartsev, A. A.; Livshits, A. I. [St. Peterburg State Univ. of Telecommunications SUT, St. Peterburg (Russian Federation)

2008-07-15T23:59:59.000Z

123

Redox reactions with empirical potentials: Atomistic battery discharge simulations  

E-Print Network (OSTI)

Batteries are pivotal components in overcoming some of today's greatest technological challenges. Yet to date there is no self-consistent atomistic description of a complete battery. We take first steps toward modeling of a battery as a whole microscopically. Our focus lies on phenomena occurring at the electrode-electrolyte interface which are not easily studied with other methods. We use the redox split-charge equilibration (redoxSQE) method that assigns a discrete ionization state to each atom. Along with exchanging partial charges across bonds, atoms can swap integer charges. With redoxSQE we study the discharge behavior of a nano-battery, and demonstrate that this reproduces the generic properties of a macroscopic battery qualitatively. Examples are the dependence of the battery's capacity on temperature and discharge rate, as well as performance degradation upon recharge.

Dapp, Wolf B

2013-01-01T23:59:59.000Z

124

Energy-Density Enhancement of Carbon-Nanotube-Based Supercapacitors with Redox Couple in Organic Electrolyte  

Science Journals Connector (OSTI)

Energy-Density Enhancement of Carbon-Nanotube-Based Supercapacitors with Redox Couple in Organic Electrolyte ... The redox molecule also contributes to increasing the cell capacitance by a faradaic redox reaction, and therefore the energy density of the supercapacitor can be significantly increased. ... More specifically, the addition of redox-active decamethylferrocene in an organic electrolyte results in an approximately 27-fold increase in the energy density of carbon-nanotube-based supercapacitors. ...

Jinwoo Park; Byungwoo Kim; Young-Eun Yoo; Haegeun Chung; Woong Kim

2014-11-16T23:59:59.000Z

125

Redox Properties of Cytochrome c Adsorbed on Self-Assembled Monolayers: A Probe for Protein  

E-Print Network (OSTI)

Redox Properties of Cytochrome c Adsorbed on Self-Assembled Monolayers: A Probe for Protein Received May 21, 2002 The redox behavior of cytochrome c (cyt c) adsorbed to gold electrodes modified) groups and from an aromatic thiol (6). The redox potentials of cyt c adsorbed on SAMs of 1 and 5

Prentiss, Mara

126

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1987-01-01T23:59:59.000Z

127

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1985-05-17T23:59:59.000Z

128

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1987-04-21T23:59:59.000Z

129

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents (OSTI)

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1986-01-01T23:59:59.000Z

130

The Displacive Phase Transition of Vanadium Dioxide and the Effect of Doping with Tungsten  

Science Journals Connector (OSTI)

However, comparison of the two structures in Figure 1 showed that it was possible to construct the tetragonal structure using the lower-symmetry but equivalent unit cell indicated by the green quadrilateral (each of whose corners is midway between two vanadium ions) in Figure 1a. ... Woodley, S. M.; Battle, P. D.; Catlow, C. R. A.; Gale, J. D. J. Phys. ...

Makondelele Netsianda; Phuti E. Ngoepe; C. Richard A. Catlow; Scott M. Woodley

2008-02-15T23:59:59.000Z

131

Materials Science and Engineering B88 (2002) 7378 Processing and properties of vanadium doped strontium niobate  

E-Print Network (OSTI)

strontium niobate Seana Seraji, Yun Wu, Steven Limmer, Tammy Chou, Caroyln Nguyen, Mike Forbess, G.Z. Cao October 2001 Abstract Strontium niobate was doped with vanadium and the resulting effects a relatively high vapor pressure [5]. Strontium niobate (Sr2Nb2O7) is a very promising candidate

Cao, Guozhong

132

Comparison of a microstructure evolution model with experiments on irradiated vanadium  

E-Print Network (OSTI)

Comparison of a microstructure evolution model with experiments on irradiated vanadium S. Sharafat vacancy ¯ux to grow matrix and precipitate-axed bubbles. The direct formation of vacancy and interstitial and its alloys are now considered as candidate structural materials in fu- sion reactors, because

Ghoniem, Nasr M.

133

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke  

Science Journals Connector (OSTI)

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke ... The ash pits have since gone through an extensive remedial process. ... The other metals investigated (i.e., Fe, Cu, Zn, and Pb) also were present predominantly as sulfates. ...

L. Jia; E. J. Anthony; J. P. Charland

2002-02-27T23:59:59.000Z

134

Hydrogen-impurity binding energy in vanadium and niobium A. Mokrani and C. Demangeat  

E-Print Network (OSTI)

2243 Hydrogen-impurity binding energy in vanadium and niobium A. Mokrani and C. Demangeat IPCMS, UM by the hydrogen) contribution, ii) the band structure contribution, iii) the electron-electron interaction without. Strong H-H repulsion is observed when the hydrogen atoms are at first nearest neighbouring positions

Boyer, Edmond

135

Thermodynamics of strained vanadium dioxide single crystals Yijia Gu,1,a  

E-Print Network (OSTI)

Thermodynamics of strained vanadium dioxide single crystals Yijia Gu,1,a Jinbo Cao,2 Junqiao Wu,2 condition plays an important role. To investigate the strain contribution, a phenomenological thermodynamic films. In order to control and manipulate the MIT, it is necessary to understand the thermodynamics

Wu, Junqiao

136

Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic compression  

E-Print Network (OSTI)

Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic form 16 September 2003; accepted 9 October 2003 Abstract We have processed fully dense, nano that the grain size of the consolidated V is around 100 nm. Mechanical properties of the nano-structured V were

Wei, Qiuming

137

Redox Shuttle Additive, Wins 2014 R&D 100 Award  

Office of Energy Efficiency and Renewable Energy (EERE)

Sandia National Laboratory and the Argonne National Laboratory have developed a chemical solution, known as a redox shuttle additive, a chemical that prevents overcharging by electrochemically “locking in” a maximum voltage that is dependent on the chemical structure of the additive and the nature of the battery material.

138

Electrochemical biosensor based on immobilized enzymes and redox polymers  

DOE Patents (OSTI)

The present invention relates to an electrochemical enzyme biosensor for use in liquid mixtures of components for detecting the presence of, or measuring the amount of, one or more select components. The enzyme electrode of the present invention is comprised of an enzyme, an artificial redox compound covalently bound to a flexible polymer backbone and an electron collector.

Skotheim, Terje A. (Shoreham, NY); Okamoto, Yoshiyuki (Fort Lee, NJ); Hale, Paul D. (Northport, NY)

1992-01-01T23:59:59.000Z

139

Effect of the metal-semiconductor phase transition on the rate of hydrogen penetration into vanadium dioxide thin films  

Science Journals Connector (OSTI)

The rates of hydrogen penetration from an aqueous solution of glycerin into ... compared. It has been found that the rate of hydrogen penetration into the metal phase of vanadium dioxide ... order of magnitude hi...

V. N. Andreev; V. A. Klimov

2010-03-01T23:59:59.000Z

140

Role of vanadium pentoxide hole-extracting nanolayer in rubrene/C70-based small molecule organic solar cells  

Science Journals Connector (OSTI)

Vanadium pentoxide (V2O5) was inserted between the donor layer and the anode as a hole-extracting nanolayer. Compared with devices without a hole-extracting layer, short-circuit current density (JSC), open-circuit ...

Zhen Zhan, Jing Cao, Weiguang Xie, Lintao Hou, Qin Ye, Pengyi Liu

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Redox-driven regulation of microbial community morphogenesis Chinweike Okegbe, Alexa Price-Whelan and Lars EP Dietrich  

E-Print Network (OSTI)

Redox-driven regulation of microbial community morphogenesis Chinweike Okegbe, Alexa Price that fuels life is derived from electron transfer (redox) reactions. Changes in electron availability alter- isms are also important during more subtle variations in redox potential. Redox balance -- the relative

Dietrich, Lars

142

Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium  

E-Print Network (OSTI)

The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

E. I. Sharapov; C. L. Morris; M. Makela; A. Saunders; Evan R. Adamek; Yelena Bagdasarova; L. J. Broussard; C. B. Cude-Woods; Deon E Fellers; Peter Geltenbort; S. I. Hasan; K. P. Hickerson; G. Hogan; A. T. Holley; Chen-Yu Liu; M. P. Mendenhall; J. Ortiz; R. W. Pattie Jr.; D. G. Phillips; J. Ramsey; D. J. Salvat; S. J. Seestrom; E. Shaw; Sky Sjue; W. E. Sondheim; B. VornDick; Z. Wang; T. L. Womack; A. R. Young; B. A. Zeck

2013-06-05T23:59:59.000Z

143

Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium  

E-Print Network (OSTI)

The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

Sharapov, E I; Makela, M; Saunders, A; Adamek, Evan R; Bagdasarova, Yelena; Broussard, L J; Cude-Woods, C B; Fellers, Deon E; Geltenbort, Peter; Hasan, S I; Hickerson, K P; Hogan, G; Holley, A T; Liu, Chen-Yu; Mendenhall, M P; Ortiz, J; Pattie, R W; Phillips, D G; Ramsey, J; Salvat, D J; Seestrom, S J; Shaw, E; Sjue, Sky; Sondheim, W E; VornDick, B; Wang, Z; Womack, T L; Young, A R; Zeck, B A

2013-01-01T23:59:59.000Z

144

Catalytic pyrolysis of straight-run gasoline on a promoted vanadium catalyst  

SciTech Connect

Over the years the catalytic pyrolysis has been studied of various hydrocarbon materials - from gaseous (ethane, propane and n-butane) to heavy petroleum fractions with an end boiling point higher than 500/sup 0/C. The process indices for all the raw materials studied were significantly better than those from thermal pyrolysis. Improvement of operational properties for the vanadium catalyst for pyrolysis involved the selecting a better acceptor and the use of promotor additives which inhibit coke formation.

Chernykh, S.P.; Adel'son, S.V.; Rudyk, E.M.; Zhagfarov, F.G.; Motorina, I.A.; Nikonov, V.I.; Mukhina, T.N.; Barabanov, N.L.; Pyatiletov, V.I.

1983-04-01T23:59:59.000Z

145

NOVEL COMPUTATIONAL SIMULATION OF REDOX REACTIONS WITHIN A METAL ELECTROSPRAY EMITTER  

SciTech Connect

To further both our fundamental understanding implications of the electrolytic nature of the electrospray and our understanding of the analytical ion source, in the context of electrospray mass spectrometry (ES-MS), a computational simulation of the oxidation of chemical species inside a metal emitter has been developed. The analysis code employs a boundary integral method for the solution of the Laplace equation for the electric potential and current, and incorporates standard activation and concentration polarization functions for the redox active species in the system to define the boundary conditions. The specific system modeled consisted of a 100 {mu}m i .d., inert metal capillary CHICN/H2O (90/10 V/V). ES emitter and a spray solution comprised of an analyte dissolved in Variable parameters included the concentration (i.e., 5, 10, 20, and 50 ~M) of the easily oxidized analyte ferrocene (Fe, dicyclopentadienyl iron) in the solution, and solution conductivities of 1.9, 3.8, and 7.6 x 107 Mho/cm. ES currents were on the order of 0.05 {mu}A and the flow rate was 5 @A_nin. Under these defined conditions, the two most prominent reactions at the emitter metakolution interface were assumed to be H20 oxidation (2H20 = 02 + 4H+ + 4e") and Fe oxidation (Fe = Fe' +e-). Using this model it was possible to predict the inter-facial potentials, as well as the current density for each of the reactions, as a function of axial position from the emitter spray tip back upstream, under the various operational conditions. Computational fluid dynamics (CFD) calculations showed that the imposed flow rate through the emitter was adequate to prevent significant back-diffusion of Fe+ into the emitter against the flow direction. The computational simulations predict the same behavior for the ES ion source as has been observed experimentally and is consistent with the controlled-current electrolytic cell analogy of Van Berkel and Zhou (Anal. Chem. 1995, 67,.2916-2923). Furthermore, the simulations demonstrate that the majority of the current involved in the redox reactions originated within a 200- 300 ~m region near the spray tip.

BULLOCK, J.S.IV; GILES, G.E.; GRAY, L.J.; VAN BERKEL, G.J.

1999-01-13T23:59:59.000Z

146

Electrodialysis of vanadium(III) and iron(II) ions from a simulated decontamination solution  

SciTech Connect

The transport of vanadium(III) and iron(II) ions through the Nafion 117 cation-exchange membrane in the presence of picolinic acid was investigated by simulating the equilibrium distribution of ionic species as a function of pH, and by electrodialyzing the simulated waste solution. From distribution calculations of the model reaction systems it could be predicted that at pH 1.6 most vanadium ions exist predominantly in the form of the V{sup III}(Pic{sup {minus}}){sub 2}{sup +} complex, and this form of complex permeates across the cation-exchange membrane during electrodialysis. The experimental results, including variations in the color and cation concentrations of the catholyte, confirm the existence of the vanadium(III) picolinate complex. Iron ions permeated into the catholyte were converted to their hydroxide precipitates, which could be formed at the high pH condition resulting from the reduction of hydrogen ions and the production of OH{sup {minus}} ions by water electrolysis at the cathode. It was also found that the in-situ precipitation of iron in the electrodialyzer could be self-modulated by shifting the catholyte pH from the acidic state to the alkaline state during electrodialysis operation.

Shim, J.B.; Oh, W.Z.; Lee, B.J.; Park, H.S. [Korea Atomic Energy Research Inst., Taejon (Korea, Republic of)] [Korea Atomic Energy Research Inst., Taejon (Korea, Republic of); Kim, J.D. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Chemical Engineering] [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Chemical Engineering

1999-07-01T23:59:59.000Z

147

Research on pollution prevention and control technologies in the industry of vanadium extraction from stone coal  

Science Journals Connector (OSTI)

The technology of pollution prevention and control in the industry of vanadium extraction from stone coal acts as a key factor in deciding whether the vanadium can be extracted from stone coal effectively. This paper focuses on analysing related pollutants, including their features, and major problems existing in field of vanadium extraction, as well as investigating the technology used to prevent and control the pollutants in wastewater, gas and slag. In accordance with the current efforts of pollution prevention, it can be concluded that this industry must reduce its resources, energy consumption and pollutant discharge strength, enhance pollution prevention, guarantee ecology safety and human health so that improvement in production capacity, craft and pollution abatement technique can be promoted. Therefore, concrete proposals and expectations on technological control are offered, including building up a real-time monitoring system and a decision support system. This study can help the research and development staff to understand technologies related to reducing the environmental pollution clearly and to achieve sustainable development simultaneously.

Jia Li; Yimin Zhang; Tao Liu

2014-01-01T23:59:59.000Z

148

Multiplier, moderator, and reflector materials for lithium-vanadium fusion blankets.  

SciTech Connect

The self-cooled lithium-vanadium fusion blanket concept has several attractive operational and environmental features. In this concept, liquid lithium works as the tritium breeder and coolant to alleviate issues of coolant breeder compatibility and reactivity. Vanadium alloy (V-4Cr-4Ti) is used as the structural material because of its superior performance relative to other alloys for this application. However, this concept has poor attenuation characteristics and energy multiplication for the DT neutrons. An advanced self-cooled lithium-vanadium fusion blanket concept has been developed to eliminate these drawbacks while maintaining all the attractive features of the conventional concept. An electrical insulator coating for the coolant channels, spectral shifter (multiplier, and moderator) and reflector were utilized in the blanket design to enhance the blanket performance. In addition, the blanket was designed to have the capability to operate at high loading conditions of 2 MW/m{sup 2} surface heat flux and 10 MW/m{sup 2} neutron wall loading. This paper assesses the spectral shifter and the reflector materials and it defines the technological requirements of this advanced blanket concept.

Gohar, Y.; Smith, D. L.

1999-10-07T23:59:59.000Z

149

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

SciTech Connect

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

150

Ilmenite Activation during Consecutive Redox Cycles in Chemical-Looping Combustion  

Science Journals Connector (OSTI)

Ilmenite Activation during Consecutive Redox Cycles in Chemical-Looping Combustion ... Industrial & Engineering Chemistry Research2014 53 (42), 16341-16348 ...

Juan Adánez; Ana Cuadrat; Alberto Abad; Pilar Gayán; Luis F. de Diego; Francisco García-Labiano

2010-01-07T23:59:59.000Z

151

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox  

E-Print Network (OSTI)

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox Abstract A comparative study of lignin and neutral carbohydrate compositions, combined with C, N and 13C and lignin in brackish to hypersaline fine-grained mangrove sediments characterized by great changes in redox

Paris-Sud XI, Université de

152

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta, Lital (San Diego, CA); Schultz, Peter G. (La Jolla, CA); Zhang, Zhiwen (Austin, TX)

2011-08-30T23:59:59.000Z

153

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta, Lital (San Diego, CA); Schultz, Peter G. (La Jolla, CA); Zhang, Zhiwen (San Diego, CA)

2009-02-24T23:59:59.000Z

154

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta; Lital (San Diego, CA), Schultz; Peter G. (La Jolla, CA), Zhang; Zhiwen (San Diego, CA)

2010-10-12T23:59:59.000Z

155

Site-specific incorporation of redox active amino acids into proteins  

DOE Patents (OSTI)

Compositions and methods of producing components of protein biosynthetic machinery that include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, and orthogonal pairs of tRNAs/synthetases, which incorporate redox active amino acids into proteins are provided. Methods for identifying these orthogonal pairs are also provided along with methods of producing proteins with redox active amino acids using these orthogonal pairs.

Alfonta, Lital (San Diego, CA); Schultz, Peter G. (La Jolla, CA); Zhang, Zhiwen (San Diego, CA)

2012-02-14T23:59:59.000Z

156

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes  

E-Print Network (OSTI)

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes Alex and Aerospace Engineering Background Solid oxide fuel cells lose mechanical stability and functionality when oxidize (redox reaction) instead of the hydrogen fuel [2]. This conversion to NiO exerts a volumetric

Petta, Jason

157

Nanoscale imaging of the electronic and structural transitions in vanadium dioxide.  

SciTech Connect

We investigate the electronic and structural changes at the nanoscale in vanadium dioxide (VO{sub 2}) in the vicinity of its thermally driven phase transition. Both electronic and structural changes exhibit phase coexistence leading to percolation. In addition, we observe a dichotomy between the local electronic and structural transitions. Nanoscale x-ray diffraction reveals local, nonmonotonic switching of the lattice structure, a phenomenon that is not seen in the electronic insulator-to-metal transition mapped by near-field infrared microscopy.

Qazilbash, M. M.; Tripathi, A.; Schafgans, A. A.; Kim, B.-J.; Kim, H.-T.; Cai, Z.; Holt, M. V.; Maser, J. M.; Keilmann, F.; Shpyrko, O. G.; Basov, D. N. (X-Ray Science Division); ( CNM); (Univ. of California at San Diego); (Electronics and Telecommunications Research IInst.); (Univ. of Science and Technology); (Munich Centre for Advanced Photonics and Center for NanoScience)

2011-04-13T23:59:59.000Z

158

Nanoscale structural evolution of electrically driven insulator to metal transition in vanadium dioxide  

SciTech Connect

The structural evolution of tensile strained vanadium dioxide thin films was examined across the electrically driven insulator-to-metal transition by nanoscale hard X-ray diffraction. A metallic filament with rutile (R) structure was found to be the dominant conduction pathway for an electrically driven transition, while the majority of the channel area remained in the monoclinic M1 phase. The filament dimensions were estimated using simultaneous electrical probing and nanoscale X-ray diffraction. Analysis revealed that the width of the conducting channel can be tuned externally using resistive loads in series, enabling the M1/R phase ratio in the phase coexistence regime to be tuned.

Freeman, Eugene, E-mail: exf181@psu.edu; Shukla, Nikhil; Datta, Suman [Department of Electrical Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States)] [Department of Electrical Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Stone, Greg; Engel-Herbert, Roman; Gopalan, Venkatraman [Department of Materials Science and Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States)] [Department of Materials Science and Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Paik, Hanjong [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States)] [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Moyer, Jarrett A. [Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)] [Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Cai, Zhonghou; Wen, Haidan [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Schlom, Darrell G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States) [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

2013-12-23T23:59:59.000Z

159

Sorption of redox-sensitive elements: critical analysis  

SciTech Connect

The redox-sensitive elements (Tc, U, Np, Pu) discussed in this report are of interest to nuclear waste management due to their long-lived isotopes which have a potential radiotoxic effect on man. In their lower oxidation states these elements have been shown to be highly adsorbed by geologic materials occurring under reducing conditions. Experimental research conducted in recent years, especially through the Waste Isolation Safety Assessment Program (WISAP) and Waste/Rock Interaction Technology (WRIT) program, has provided extensive information on the mechanisms of retardation. In general, ion-exchange probably plays a minor role in the sorption behavior of cations of the above three actinide elements. Formation of anionic complexes of the oxidized states with common ligands (OH/sup -/, CO/sup - -//sub 3/) is expected to reduce adsorption by ion exchange further. Pertechnetate also exhibits little ion-exchange sorption by geologic media. In the reduced (IV) state, all of the elements are highly charged and it appears that they form a very insoluble compound (oxide, hydroxide, etc.) or undergo coprecipitation or are incorporated into minerals. The exact nature of the insoluble compounds and the effect of temperature, pH, pe, other chemical species, and other parameters are currently being investigated. Oxidation states other than Tc (IV,VII), U(IV,VI), Np(IV,V), and Pu(IV,V) are probably not important for the geologic repository environment expected, but should be considered especially when extreme conditions exist (radiation, temperature, etc.). Various experimental techniques such as oxidation-state analysis of tracer-level isotopes, redox potential measurement and control, pH measurement, and solid phase identification have been used to categorize the behavior of the various valence states.

Strickert, R.G.

1980-12-01T23:59:59.000Z

160

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Direct Observation of Nanoscale Peltier and Joule Effects at Metal-Insulator Domain Walls in Vanadium Dioxide Nanobeams  

E-Print Network (OSTI)

Direct Observation of Nanoscale Peltier and Joule Effects at Metal- Insulator Domain Walls localized alternating Peltier heating and cooling as well as Joule heating concentrated at the M-I domain the monoclinic phase identification. KEYWORDS: Vanadium dioxide, thermoreflectance microscopy, Peltier effect

Wu, Junqiao

162

Cotton flow  

E-Print Network (OSTI)

Using the conformally invariant Cotton tensor, we define a geometric flow, the "Cotton flow", which is exclusive to three dimensions. This flow tends to evolve the initial metrics into conformally flat ones, and is somewhat orthogonal to the Yamabe flow, the latter being a flow within a conformal class. We define an entropy functional, and study the flow of nine homogeneous spaces both numerically and analytically. In particular, we show that the arbitrarily deformed homogeneous 3-sphere flows into the round 3-sphere. Two of the nine homogeneous geometries, which are degenerated by the Ricci flow, are left intact by the Cotton flow.

Ali Ulas Ozgur Kisisel; Ozgur Sarioglu; Bayram Tekin

2008-06-17T23:59:59.000Z

163

Redox states of Desulfovibrio vulgaris DsrC, a key protein in...  

NLE Websites -- All DOE Office Websites (Extended Search)

Venceslau SS, JR Cort, ES Baker, RK Chu, EW Robinson, C Dahl, LM Saraiva, and IA Pereira.2013."Redox states of Desulfovibrio vulgaris DsrC, a key protein in dissimilatory...

164

Molecular cloning and characterization of important stress and redox regulatory genes from Hydra vulgaris  

E-Print Network (OSTI)

In this research, important stress and redox regulatory genes present in Hydra vulgaris were isolated and characterized to facilitate our understanding of the evolution and mechanisms of stress response. H. vulgaris heat shock protein 70 (HvHSP70...

Dash, Bhagirathi

2007-04-25T23:59:59.000Z

165

Method of reduction of nitroaromatics by enzymatic reaction with redox enzymes  

DOE Patents (OSTI)

A method for the controlled reduction of nitroaromatic compounds such as nitrobenzene and 2,4,6-trinitrotoluene by enzymatic reaction with redox enzymes, such as Oxyrase (Trademark of Oxyrase, Inc., Mansfield, Ohio).

Shah, Manish M. (Richland, WA)

2000-01-01T23:59:59.000Z

166

The role of Ncb5or in fatty acid metabolism and redox homeostasis  

E-Print Network (OSTI)

The endoplasmic reticulum (ER)-associated NADH cytochrome b5 oxidoreductase (Ncb5or) is widely distributed in animal tissues. It contains two redox domains that are homologous to microsomal cytochrome b5 (Cyb5A) at the N ...

Xu, Ming

2011-12-31T23:59:59.000Z

167

Transcriptional Regulation of Central Carbon and Energy Metabolism in Bacteria by Redox-Responsive Repressor Rex  

Science Journals Connector (OSTI)

...experimental techniques allow us to identify these and...its orthologs allowed us to predict a conserved...key enzymes involved in energy metabolism and redox status balance. Conservation...functional categories: (i) energy metabolism, including...

Dmitry A. Ravcheev; Xiaoqing Li; Haythem Latif; Karsten Zengler; Semen A. Leyn; Yuri D. Korostelev; Alexey E. Kazakov; Pavel S. Novichkov; Andrei L. Osterman; Dmitry A. Rodionov

2011-12-30T23:59:59.000Z

168

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mössbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mössbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

169

Studying the semiconductor-metal phase transition in nanoscale vanadium dioxide, doped with ions of 3d-elements on a silicon surface  

Science Journals Connector (OSTI)

Nanoscale vanadium dioxide doped with chromium and iron is obtained via molecular layering method on the surface of a single-crystal silicon. The qualitative and quantitative composition of the samples is dete...

D. V. Nazarov; O. M. Osmolowskaya…

2013-03-01T23:59:59.000Z

170

Characterization and catalytic performance of vanadium supported on sulfated Ti-PILC catalysts issued from different Ti-precursors in selective catalytic reduction of nitrogen oxide by ammonia  

Science Journals Connector (OSTI)

Vanadium supported on sulfated Ti-pillared clay catalysts (STi-PILCs) issued from different Ti-precursors were investigated for selective catalytic reduction (SCR) of NO by NH3 in the presence of O2. The STi-PILC...

J. Arfaoui; L. Khalfallah Boudali; A. Ghorbel; G. Delahay

2009-12-01T23:59:59.000Z

171

Development of Vanadium Phosphaate Catalysts for Methanol Production by Selective Oxidation of Methane.  

SciTech Connect

This DOE sponsored study of methane partial oxidation was initiated at Amax Research and Development in Golden, CO in October of 1993. Shortly thereafter the management of Amax closed this R&D facility and the PI moved to the Colorado School of Mines. The project was begun again after contract transfer via a novation agreement. Experimental work began with testing of vandyl pyrophosphate (VPO), a well known alkane selective oxidation catalyst. It was found that VPO was not a selective catalyst for methane conversion yielding primarily CO. However, promotion of VPO with Fe, Cr, and other first row transition metals led to measurable yields for formaldehyde, as noted in the summary table. Catalyst characterization studies indicated that the role of promoters was to stabilize some of the vanadium in the V{sup 5+} oxidation state rather than the V{sup 4+} state formally expected for (VO){sub 2}P{sub 2}O{sub 7}.

McCormick, R.L.

1997-10-01T23:59:59.000Z

172

Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics  

SciTech Connect

Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400°C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

Sathish, M., E-mail: sathishphy79@gmail.com [Department of Physics, GOVT first grade College, Doddaballapur-561203 (India); Eraiah, B., E-mail: eraiah@rediffmail.com [Department of Physics, Bangalore University, Bangalore-560056, India (India)

2014-04-24T23:59:59.000Z

173

Flow Cells for Energy Storage Workshop Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop Summary Report Workshop Summary Report Prepared for: U. S. Department of Energy Prepared by: Dr. Adam Z. Weber Lawrence Berkeley National Laboratory Organizing Committee: Michael Perry, UTRC Tom Zawodzinski, UTK and ORNL Ned Stetson, DOE EERE Mark Johnson, DOE ARPA-E Imre Gyuk, DOE OEDER i Executive Summary An essentially identical technology to a reversible fuel cell is that of a redox flow cell (RFC) or redox flow battery (RFB), where a RFC can be seen as merging the concepts of RFBs with recent improvements in fuel cells. To investigate how a RFC can be a grid-scale electrical- energy-storage (EES) system and the associated technological needs, this workshop was held. The specific objectives of the workshop were to understand the needs for applied research in RFCs; identify the grand challenges and prioritize R&D needs; and gather input for future

174

Appendix F Stream Flow.xls  

Office of Legacy Management (LM)

Stream Flow Measurement Results Since 2000 Stream Flow Measurement Results Since 2000 This page intentionally left blank Appendix F Stream Flow Measurement Results Since 2000 Collect Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where gradient steepens/lined. 4/14/2000 SW00-01 0.44 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 4/14/2000 SW00-02 0.74 Pipe outfall at east end of millsite

175

Redox-dependent solubility of technetium in low activity waste...  

NLE Websites -- All DOE Office Websites (Extended Search)

as H 3 BO 3 ), fused, and then crushed to a fine, free flowing powder in a tungsten carbide mill. The crushed glass is not particularly hygroscopic and does not generate gas...

176

Influence of pyridine and compounds of vanadium, iron, and molybdenum on the carbonylation of azo and nitro compounds in the presence of RhCl3-4H2O  

Science Journals Connector (OSTI)

Rhodium trichloride tetrahydrate without promoters catalyzes the synthesis of isocyanates by the carbonylation of azobenzenes. Pyridine, compounds of vanadium, molybdenum, and iron acetylacetonate inhibit this re...

V. I. Manov-Yuvenskii; K. B. Petrovskii…

1983-03-01T23:59:59.000Z

177

Electromagnetic Borehole Flowmeter Surveys at Selected In Situ Redox Manipulation Barrier Wells, Zero-Valent Iron Site, Hanford, Washington  

SciTech Connect

Ambient (i.e., static) and dynamic (i.e., pumping-induced) electromagnetic borehole flowmeter (EBF) surveys were performed in 10 selected In Situ Redox Manipulation (ISRM) barrier wells to characterize the distribution of in-well vertical flow conditions and to infer the relative hydraulic conductivity distribution in the upper-part of the unconfined aquifer. These wells are located in two areas where the aquifer is targeted for testing of zero-valent iron injection to mend a failed portion of the ISRM barrier at the 100 D Area, Hanford Site. Each of these two areas consists of a group of five wells, one group to the southwest and one group to the northeast. The upper ~15 to 20 ft (~4.6 to 6.1 m) of the unconfined aquifer was characterized for in-well vertical flow conditions and vertical profile information regarding relative hydraulic conductivity. At some well site locations, the upper ~2 to 3 ft (~0.6 to 1 m) of the well-screen interval could not be characterized under pumping (dynamic) conditions because of the presence of the pump.

Newcomer, Darrell R.

2009-02-09T23:59:59.000Z

178

Reactivity studies of a pseudo three-coordinate vanadium(II) complex: Synthesis of terminal oxo and sulfido complexes of vanadium(IV) and S?S and Se?Se reductive bond cleavage reactions  

SciTech Connect

Terminal oxo and sulfido complexes in the form of (nacnac)V=E(Ntol{sub 2}) (nacnac = [ArNC(CH{sub 3})]{sub 2}CH{sup -}, Ar = 2,6-(CHMe{sub 2}){sub 2}C{sub 6}H{sub 3}, Ntol{sub 2} = {sup -}N(C{sub 6}H{sub 4}-4-Me), E = O (1), S (2)) were isolated from treatment of the masked three-coordinate vanadium(II) complex, (nacnac)V(Ntol{sub 2}), with C{sub 5}H{sub 5}NO and S{sub 8}, respectively. Both vanadium(IV) species, 1 and 2, have been characterized by room temperature X-band EPR spectroscopic studies, and in the case of complex 1, a single crystal molecular structure confirmed the presence of a terminal oxo moiety. Moreover, reaction of (nacnac)V(Ntol{sub 2}) with diphenyl-disulfide and diphenyl-diselenide results in the reductive cleavage of these compounds to produce the vanadium(III) complexes (nacnac)V(XPh)(Ntol{sub 2}) (X = S, (3), Se (4)). A molecular structure of the phenylsulfide complex, 3, confirmed formation of the d{sup 2} complex resulting from reductive cleavage of the S-S bond.

Tran, Ba L.; Chen, Chun-Hsing; Mindiola, Daniel J. (Indiana)

2012-02-07T23:59:59.000Z

179

1: Redox chemistry of bimetallic fulvalene complexes; 2: Oligocyclopentadienyl complexes  

SciTech Connect

The electrochemistry of the heterobimetallic complexes (fulvalene)WFe(CO){sub 5} (30) and (fulvalene)WRu(CO){sub 5} (31) has been investigated. Compound 30 is reduced in two one-electron processes, and this behavior was exploited synthetically to prepare a tetranuclear dimer by selective metal reduction. Complex 31 displayed a distinction between the metals upon reoxidation of the dianion, allowing the formation of a dimer by selective metal anion oxidation. The redox behavior of 30 led to an investigation of the use of electrocatalysis to effect metal-specific ligand substitution. It was found that reduction of 30 with a catalytic amount of CpFe(C{sub 6}Me{sub 6}) (97) in the presence of excess P(OMe){sub 3} or PMe{sub 3} led to the formation of the zwitterions (fulvalene)[W(CO){sub 3}{sup {minus}}][Fe(CO)PR{sub 3}{sup +}] (107, R = P(OMe){sub 3}; 108, R = PMe{sub 3}). Compound 31 also displayed unique behavior with different reducing agents, as the monosubstituted zwitterion (fulvalene)[W(CO){sub 3}{sup {minus}}][Ru(CO){sub 2}(PMe{sub 3}){sup +}] was obtained when 97 was used while the disubstituted complex (fulvalene) [W(CO){sub 3}{sup {minus}}] [Ru(CO)(PMe{sub 3}){sub 2}{sup +}] was produced when Cp*Fe(C{sub 6}Me{sub 6}) was the catalyst. Potential synthetic routes to quatercyclopentadienyl complexes were also explored. Various attempts to couple heterobimetallic fulvalene compounds proved to be unsuccessful. 138 refs.

Brown, D.S. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Chemical Sciences Div.

1993-11-01T23:59:59.000Z

180

Resuspension studies in cylindrical microcosms: Effects of stirring velocity on the dynamics of redox sensitive elements in a coastal sediment  

Science Journals Connector (OSTI)

Effects of resuspension on the release of dissolved, redox sensitive ... At current velocities below the threshold velocity for resuspension (37 cm s-1), Mn release...

Mario Hose Calado Laima; Henning Matthiesen; Lars Chresten Lund-Hansen…

1998-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Redox Properties of Structural Fe in Clay Minerals. 1. Electrochemical Quantification of Electron-Donating and -Accepting Capacities of Smectites  

Science Journals Connector (OSTI)

The Fe2+/Fe3+ redox couple is an important redox buffer in the environment that affects biogeochemical element and nutrient cycling and controls the partitioning and redox transformations of organic and inorganic contaminants. ... (14-18) These changes can alter the fate and (bio)availability of redox-inactive contaminants and nutrients (e.g., K+, Ca2+)(18) as well as dictate the viability of clay minerals in engineered systems (e.g., clay mineral backfill in radioactive waste repositories). ... In this approach, an electrochemical cell containing a pH-buffered solution is set to a constant EH-value while the current is measured over time. ...

Christopher A. Gorski; Michael Aeschbacher; Daniela Soltermann; Andreas Voegelin; Bart Baeyens; Maria Marques Fernandes; Thomas B. Hofstetter; Michael Sander

2012-07-24T23:59:59.000Z

182

Poly(3,4-ethylenedioxypyrrole) Modified Emitter Electrode for Substitution of Homogeneous Redox Buffer Agent Hydroquinone in Electrospray Ionization Mass Spectrometry  

SciTech Connect

The electrolysis inherent to the operation of the electrospray ionization (ESI) source used with mass spectrometry (MS) is a well-known attendant effect of generating unipolar spray droplets and may affect the analysis of the analyte of interest. Undesirable electrolysis of an analyte may be prevented by limiting the emitter electrode current and/or the mass transport characteristics of the system. However, these ways to avoid analyte electrolysis may not be applcable in all ESI-MS experiments. For example, in the case of specific nanospray systems (e.g. the wire-in-a-capillary bulk-loaded or chip-based tip-loaded nanospray configurations), the solution flow rate is fixed in the 50-500 nL/min range and the electrode surface to volume ratio is large presenting a very effcient analyte to electrode mass transport configuration. In these situations, control over the interfacial potential of the working electrode via homogeneous or traditional heterogeneous (sacrificial metal) redox buffering is a possible way to prevent analyte electrolysis. However, byproducts of these redox buffering approaches can appear in the mass spectra and/or they can chemically alter the analyte. For example, the main reason for using hydroquinone as a homogeneous redox buffer, in addition to its relatively low oxidation potential, is that neither the original compound nor its oxidation product benzoquinone can be detected directly by ESI-MS. However, benzoquinone can alter analytes with thiol functional groups by reacting with those groups via a 1,4-Michael addition.

Peintler-Krivan, Emese [ORNL; Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

2010-01-01T23:59:59.000Z

183

Pouring flows  

Science Journals Connector (OSTI)

Free surface flows of a liquid poured from a container are calculated numerically for various configurations of the lip. The flow is assumed to be steady two dimensional and irrotational; the liquid is treated as inviscid and incompressible; and gravity is taken into account. It is shown that there are jetlike flows with two free surfaces and other flows with one free surface which follow along the underside of the lip or spout. The latter flows occur in the well?known ‘‘teapot effect ’’ which was treated previously without including gravity. Some of the results are applicable also to flows over weirs and spillways.

Jean?Marc Vanden?Broeck; Joseph B. Keller

1986-01-01T23:59:59.000Z

184

Redox Energetics and Kinetics of Uranyl Coordination Complexes in Aqueous Solution  

Science Journals Connector (OSTI)

The redox chemistry of uranium is remarkably rich and diverse as a consequence of the number of readily accessible oxidation states (III?VI) and the sensitivity of the redox potentials to the coordination environment around the metal. ... 1-3 In aqueous environments, the most stable oxidation state for uranium is the hexavalent state for which the dominant species is the uranyl ion, UO22+.1-3 The redox chemistry of uranyl has been extensively investigated and manipulated, particularly for separations and process chemistry relating to the nuclear fuel cycle and other defense-related applications. ... The aquo, carbonato, acetato, and chloro complexes of uranyl are all known or potentially relevant species in environmental groundwaters, and the hydroxo and carbonato complexes are relevant species in alkaline high-level radioactive waste storage tanks associated with nuclear fuel processing. ...

David E. Morris

2002-05-31T23:59:59.000Z

185

In Situ Redox Manipulation Field Injection Test Report - Hanford 100-H Area  

SciTech Connect

This report presents results of an In Situ Redox Manipulation (ISRM) Field Injection Withdrawal Test performed at the 100-H Area of the US. Department of Energy`s (DOE`s) Hanford Site in Washington State in Fiscal Year 1996 by researchers at Pacific Northwest National Laboratory (PNNL). The test is part of the overall ISRM project, the purpose of which is to determine the potential for remediating contaminated groundwater with a technology based on in situ manipulation of subsurface reduction-oxidation (redox) conditions. The ISRM technology would be used to treat subsurface contaminants in groundwater zones at DOE sites.

Fruchter, J.S.; Amonette, J.E.; Cole, C.R. [and others

1996-11-01T23:59:59.000Z

186

Redox instability, mechanical deformation, and heterogeneous damage accumulation in solid oxide fuel cell anodes  

Science Journals Connector (OSTI)

Mechanical integrity and damage tolerance represent two key challenges in the design of solid oxide fuel cells(SOFCs). In particular reduction and oxidation(redox) cycles and the associated large transformation strains have a notable impact on the mechanical stability and failure mode of SOFCanodes. In this study the deformation behavior under redox cycling is investigated computationally with an approach that provides a detailed microstructurally based view of heterogeneous damage accumulation behavior within an experimentally obtained nickel/yttria stabilized zirconia SOFCanode microstructure. Simulation results underscore the critical role that the microstructure plays in the mechanical deformation behavior of and failure within such materials.

F. Abdeljawad; G. J. Nelson; W. K. S. Chiu; M. Haataja

2012-01-01T23:59:59.000Z

187

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial  

E-Print Network (OSTI)

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial cytochrome c oxidase, which makes copper an essential element for all aerobic organisms (Soloman and Lowery, 1993). However, the redox properties of copper can cause rapid generation

Grosell, Martin

188

Static Recrystallization and Precipitation Behavior of a Weathering Steel Microalloyed with Vanadium  

Science Journals Connector (OSTI)

The static recrystallization (SRX) and precipitation behavior of a weathering steel microalloyed with vanadium were investigated through double-pass compression tests under controlled conditions using the MMS-300 thermal-mechanical simulator. The deformation temperatures ranged from 800 °C to 1000 °C, and the inter-pass time from 1 s to 500 s. The simulation results showed that SRX occurred after 5–10 s at the first compression deformation. The softening fraction of SRX was found to increase with increasing the deformation temperature and the pre-strain. However, the softening fraction scarcely changed during the process of strain-induced precipitation. In addition, the kinetics of SRX was described by the Avrami equation, and the Avrami exponent appeared to be closely associated with the deformation temperature. The microstructure evolution was investigated at the initiation and completion of recrystallization. The amount and distribution of the precipitates were analyzed. The relationship between the driving force of SRX and the pinning force of precipitation was discussed. Besides, the recrystallization inhibition was detected at the early stage of precipitation, and the pinning forces were found to be of a magnitude comparable to the driving force. Moreover, the pinning forces were found to increase with the degree of precipitation and reach a peak at the intermediate stage of precipitation, and finally reduce as the particles coarsened.

Hongyan Wu; Linxiu Du; Zhengrong Ai; Xianghua Liu

2013-01-01T23:59:59.000Z

189

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Power Power Vanadium Redox Battery Demonstration Project Joseph F. Startari Ashlawn Energy Funded in part by the Energy Storage Systems Program of the U.S. Department Of Energy through National Energy Technology Laboratory US Produced Vanadium Redox Flow Battery for Bulk Storage, Peak Shaving * 8 MWh redox flow battery (1MW 8 hours) * To be installed at Painesville Municipal Electric Plant (PMEP), a 32 MW coal fired facility * Most efficient PMEP operation is steady state at 26 MW (lowest emissions, lowest operating cost) * Nominal PMEP power demand ranges from 19 MW to 37 MW * 8 MWh battery to demonstrate benefits of energy storage at PMEP Painesville Battery Layout Project has Multiple Related Objectives * Establish/Use US Manufacturing Base - Stack components/stack fabrication

190

Influence of uranyl speciation and iron oxides on uranium biogeochemical redox reactions  

SciTech Connect

Uranium is a pollutant of concern to both human and ecosystem health. Uranium's redox state often dictates its partitioning between the aqueous- and solid-phases, and thus controls its dissolved concentration and, coupled with groundwater flow, its migration within the environment. In anaerobic environments, the more oxidized and mobile form of uranium (UO{sub 2}{sup 2+} and associated species) may be reduced, directly or indirectly, by microorganisms to U(IV) with subsequent precipitation of UO{sub 2}. However, various factors within soils and sediments may limit biological reduction of U(VI), inclusive of alterations in U(VI) speciation and competitive electron acceptors. Here we elucidate the impact of U(VI) speciation on the extent and rate of reduction with specific emphasis on speciation changes induced by dissolved Ca, and we examine the impact of Fe(III) (hydr)oxides (ferrihydrite, goethite and hematite) varying in free energies of formation on U reduction. The amount of uranium removed from solution during 100 h of incubation with S. putrefaciens was 77% with no Ca or ferrihydrite present but only 24% (with ferrihydrite) and 14% (no ferrihydrite) were removed for systems with 0.8 mM Ca. Imparting an important criterion on uranium reduction, goethite and hematite decrease the dissolved concentration of calcium through adsorption and thus tend to diminish the effect of calcium on uranium reduction. Dissimilatory reduction of Fe(III) and U(VI) can proceed through different enzyme pathways, even within a single organism, thus providing a potential second means by which Fe(III) bearing minerals may impact U(VI) reduction. We quantify rate coefficients for simultaneous dissimilatory reduction of Fe(III) and U(VI) in systems varying in Ca concentration (0 to 0.8 mM), and using a mathematical construct implemented with the reactive transport code MIN3P, we reveal the predominant influence of uranyl speciation, specifically the formation of uranyl-calcium-carbonato complexes, and ferrihydrite on the rate and extent of uranium reduction in complex geochemical systems.

Stewart, B.D.; Amos, R.T.; Nico, P.S.; Fendorf, S.

2010-03-15T23:59:59.000Z

191

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft Landing  

SciTech Connect

Soft landing (SL) of mass-selected ions is used to introduce catalytically-active metal complexes complete with organic ligands into the gas phase and then to transfer them as ions onto an inert surface. This is part of an effort to prepare materials with defined active sites and thus achieve molecular design of surfaces in a highly controlled way. Solution-phase electrochemical studies have shown that VIVO(salen) reacts in the presence of acid to form VVO(salen)+ and the deoxygenated VIII(salen)+ complex -- a key intermediate in the four electron reduction of O2 by vanadium-salen. In this work, the VVO(salen)+ and [NiII(salen)+H]+ complexes were generated by electrospray ionization and mass-selected before being deposited into an inert fluorinated self-assembled monolayer (FSAM) surface on gold. A time dependence study after ion deposition showed loss of O from VVO(salen)+ forming VIII(salen)+ over a four-day period, indicating a slow interfacial reduction process. Similar results were obtained when other protonated molecules were co-deposited with VVO(salen)+ on the FSAM surface. In all these experiments oxidation of the VIII(salen)+ product occurred upon exposure to oxygen or to air. The cyclic regeneration of VVO(salen)+ upon exposure to molecular oxygen and its subsequent reduction to VIII(salen)+ in vacuum completes the catalytic cycle of O2 reduction by the immobilized vanadium-salen species. Moreover, our results represent the first evidence of formation of reactive organometallic complexes on substrates in the absence of solvent. Remarkably, deoxygenation of the oxo-vanadium complex, previously observed only in highly acidic non-aqueous solvents, occurs on the surface in the UHV environment using an acid which is deposited into the inert monolayer. This acid can be a protonated metal complex, e.g. [NiII(salen)+H]+ or an organic acid such as protonated diaminododecane.

Peng, Wen-Ping; Johnson, Grant E.; Fortmeyer, Ivy C.; Wang, Peng; Hadjar, Omar; Cooks, Robert G.; Laskin, Julia

2011-01-01T23:59:59.000Z

192

An Inner Membrane Cytochrome Required Only for Reduction of High Redox Potential Extracellular Electron Acceptors  

Science Journals Connector (OSTI)

...and offer different amounts of available energy. Despite this, metal-reducing bacteria...strategies to take advantage of these energy differences. Disruption of imcH, encoding...to generation of different amounts of energy for growth. The redox potentials that...

Caleb E. Levar; Chi Ho Chan; Misha G. Mehta-Kolte; Daniel R. Bond

2014-12-01T23:59:59.000Z

193

A Modular Approach to Redox-active Multimetallic Amphiphiles of Discotic Topology  

SciTech Connect

A new modular [Fe{sup II}(Fe{sup III}L{sup 2}){sub 3}](PF{sub 6}){sub 2} species with discoid (disk-like) topology exhibits redox and surfactant properties and points to a new approach for multimetallic Langmuir film precursors.

F Lesh; R Shanmugam; M Allard; M Lanznaster; M Hegg; M Rodgers; J Shearer; C Verani

2011-12-31T23:59:59.000Z

194

Redmond Red as a Redox Probe for the DNA-Mediated Detection of Abasic Sites  

Science Journals Connector (OSTI)

Redmond Red, a fluoropore containing a redox-active phenoxazine core, has been explored as a new electrochemical probe for the detection of abasic sites in double-stranded DNA. The electrochemical behavior of Redmond Red-modified DNA at gold surfaces ...

Marisa C. Buzzeo; Jacqueline K. Barton

2008-10-03T23:59:59.000Z

195

Redox Potentials and Acidity Constants from Density Functional Theory Based Molecular Dynamics  

E-Print Network (OSTI)

. If the solvent response is linear, as assumed in Marcus theory, ?O = ?R As a result eU? = 1/2(IPR + EAO). The redox level is midway between the ?IPR and ?EAO level. The FEP method converts vertical to adiabatic energies by a coupling parameter integral. The end...

Cheng, Jun; Liu, Xiandong; VandeVondele, Joost; Sulpizi, Marialore; Sprik, Michiel

2014-01-01T23:59:59.000Z

196

Paper Offer #: 031CES-216 PlanarArray REDOX Cells and pH Sensors  

E-Print Network (OSTI)

, is below one pM which is needed for water quality measurements. The richness of the detectable speciesPaper Offer #: 031CES-216 PlanarArray REDOX Cells and pH Sensors for ISS Water Quality and Microbe which exposes these elements to steam at 121°C for 30 minutes. INTRODUCTION The goal of this effort

Kounaves, Samuel P.

197

Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase  

E-Print Network (OSTI)

The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

Feng, Jian

2005-08-29T23:59:59.000Z

198

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus  

E-Print Network (OSTI)

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus and Frauke Gra, China ABSTRACT Mechanical force applied along a disulfide bond alters its rate of reduction. We here within proteins by point mutations. INTRODUCTION Similar to thermal or light energy, mechanical force can

Gräter, Frauke

199

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions  

E-Print Network (OSTI)

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions A novel coordination polymer of mixed-valence copper(I,II) with 4,4A-bipyridine and in situ oxidized and crystallographically char- acterized to be a laminated structure via weak copper(II)­ oxygen interactions. Extended

Li, Jing

200

Siliconized Triarylamines As Redox Mediator in Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

Siliconized Triarylamines As Redox Mediator in Dye-Sensitized Solar Cells ... We thank the Canadian Foundation for Innovation (CFI) and the Natural Sciences and Engineering Research Council of Canada (NSERC), York University (S.M.), and University of Toronto (T.P.B.) for their financial support. ...

Ali Sepehrifard; Brett A. Kamino; Timothy P. Bender; Sylvie Morin

2012-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Flow chamber  

DOE Patents (OSTI)

A flow chamber having a vacuum chamber and a specimen chamber. The specimen chamber may have an opening through which a fluid may be introduced and an opening through which the fluid may exit. The vacuum chamber may have an opening through which contents of the vacuum chamber may be evacuated. A portion of the flow chamber may be flexible, and a vacuum may be used to hold the components of the flow chamber together.

Morozov, Victor (Manassas, VA)

2011-01-18T23:59:59.000Z

202

Effect of Reducing Groundwater on the Retardation of Redox-Sensitive Radionuclides  

SciTech Connect

Laboratory batch sorption experiments were used to investigate variations in the retardation behavior of redox-sensitive radionuclides. Water-rock compositions used during these experiments were designed to simulate subsurface conditions at the Nevada Test Site (NTS), where a suite of radionuclides were deposited as a result of underground nuclear testing. Experimental redox conditions were controlled by varying the oxygen content inside an enclosed glove box and by adding reductants into the testing solutions. Under atmospheric (oxidizing) conditions, the radionuclide distribution coefficients varied with the mineralogical composition of the sorbent and the water chemistry. Under reducing conditions, distribution coefficients showed marked increases for {sup 99}Tc and {sup 237}Np in devitrified tuff, but much smaller variations in alluvium, carbonate rock, and zeolitic tuff. This effect was particularly important for {sup 99}Tc, which tends to be mobile under oxidizing conditions. Unlike other redox-sensitive radionuclides, iodine sorption may decrease under reducing conditions when I{sup -} is the predominant species. Overall, sorption of U to alluvium, devitrified tuff, and zeolitic tuff under atmospheric conditions was less than in the glove-box tests. However, the mildly reducing conditions achieved here were not likely to result in substantial U(VI) reduction to U(IV). Sorption of Pu was not affected by the decreasing redox conditions achieved in this study, as the predominant sorbed Pu species in all conditions was expected to be the low-solubility and strongly sorbing Pu(OH){sub 4}. Depending on the aquifer lithology, the occurrence of reducing conditions along a groundwater flowpath could potentially contribute to the retardation of redox-sensitive radionuclides {sup 99}Tc and {sup 237}Np, which are commonly identified as long-term dose contributors in the risk assessment in various nuclear facilities.

Hu, Q; Zavarin, M; Rose, T P

2008-04-21T23:59:59.000Z

203

Fate of Sulfur, Chlorine, Alkali Metal, and Vanadium Species during High-Temperature Gasification of Canadian Tar Sand Products  

Science Journals Connector (OSTI)

Co-feed of alternative fuels, e.g., petcoke, gains increasing importance for energy conversion in not only Germany but also worldwide. ... The aim of this work was to obtain detailed information on the influence of fuel composition of the refinery product line tar sand, bitumen, and petcoke in comparison to the standard fuel hard coal on the release of sodium, potassium, chlorine, sulfur, and vanadium species during high-temperature gasification. ... In addition to the pure fuels, blends of hard coal and petcoke were gasified in lab-scale experiments in a helium/oxygen atmosphere at 1500 °C. ...

Marc Bläsing; Kaveh Nazeri; Michael Müller

2014-10-01T23:59:59.000Z

204

Optical switching and photoluminescence in erbium-implanted vanadium dioxide thin films  

SciTech Connect

Vanadium dioxide (VO{sub 2}) is under intensive consideration for optical switching due to its reversible phase transition, which features a drastic and rapid shift in infrared reflectivity. Classified as an insulator–to–metal transition, the phase transition in VO{sub 2} can be induced thermally, electrically, and optically. When induced optically, the transition can occur on sub-picosecond time scales. It is interesting to dope VO{sub 2} with erbium ions (Er{sup 3+}) and observe their combined properties. The first excited-state luminescence of Er{sup 3+} lies within the wavelength window of minimal transmission-loss in silicon and has been widely utilized for signal amplification and generation in silicon photonics. The incorporation of Er{sup 3+} into VO{sub 2} could therefore result in a novel photonic material capable of simultaneous optical switching and amplification. In this work, we investigate the optical switching and photoluminescence in Er-implanted VO{sub 2} thin films. Thermally driven optical switching is demonstrated in the Er-implanted VO{sub 2} by infrared reflectometry. Photoluminescence is observed in the thin films annealed at ?800?°C or above. In addition, Raman spectroscopy and a statistical analysis of switching hysteresis are carried out to assess the effects of the ion implantation on the VO{sub 2} thin films. We conclude that Er-implanted VO{sub 2} can function as an optical switch and amplifier, but with reduced switching quality compared to pure VO{sub 2}.

Lim, Herianto, E-mail: mail@heriantolim.com; Stavrias, Nikolas; Johnson, Brett C.; McCallum, Jeffrey C. [School of Physics, University of Melbourne, Parkville, Victoria 3010 (Australia); Marvel, Robert E.; Haglund, Richard F. [Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37240 (United States)

2014-03-07T23:59:59.000Z

205

Slug flow  

E-Print Network (OSTI)

Introduction: When two phases flow concurrently in a pipe, they can distribute themselves in a number of different configurations. The gas could be uniformly dispersed throughout the liquid in the form of small bubbles. ...

Griffith, P.

1959-01-01T23:59:59.000Z

206

A Mechanistic Study of the Influence of Proton Transfer Processes on the Behavior of Thiol/Disulfide Redox Couples  

Science Journals Connector (OSTI)

3 This facilitation of the DMcT redox process comprises an important finding, because, even though the thermodynamics of thiol/disulfide redox processes are quite attractive from the perspective of lithium cathode materials, their kinetics are typically very slow at room temperature. ... Because these elementary steps are thermodynamically interrelated, their equilibrium constants (for chemical reactions) and E° values (for electrochemical reactions) cannot be varied independently, providing some constraints on the number of independent variables in the simulation. ...

Eiichi Shouji; Daniel A. Buttry

1999-03-06T23:59:59.000Z

207

Thermochemical Solar Energy Storage Via Redox Oxides: Materials and Reactor/Heat Exchanger Concepts  

Science Journals Connector (OSTI)

Abstract Thermochemical Storage of solar heat exploits the heat effects of reversible chemical reactions for the storage of solar energy. Among the possible reversible gas-solid chemical reactions, the utilization of a pair of redox reactions of multivalent solid oxides can be directly coupled to CSP plants employing air as the heat transfer fluid bypassing the need for a separate heat exchanger. The present work concerns the development of thermochemical storage systems based on such oxide-based redox materials and in particular on cobalt oxide; in the one hand by tailoring their heat storage/release capability and on the other hand via their incorporation in proper reactor/heat exchanger devices. In this respect the first stage of the work involved parametric testing of cobalt oxide compositions via Thermo-Gravimetric Analysis to comparatively investigate the temperature range for cyclic oxidation-reduction and optimize the cycle conditions for maximum reduction and re-oxidation extent. Subsequently, two reactor concepts for the coupling of solar energy to the redox reactions have been implemented and tested. These reactor concepts include in one hand structured ceramic reactors/heat exchangers based on redox-oxide-coated honeycombs and on the other hand powder-fed, solar-heated, rotary kiln reactors. The two reactor concepts were tested within non-solar-aided lab-scale and solar- aided campaigns, respectively. The feasibility of both concepts was shown and good chemical conversions were achieved. The experiments pointed out the challenging points related to the manufacture of pilot-scale reactors/heat exchangers with enhanced heat storage capacity. A numerical model using commercial CFD software is developed to define optimal geometrical characteristics and operating conditions and refine the pilot scale design in order to achieve efficient, long-term off-sun operation.

S. Tescari; C. Agrafiotis; S. Breuer; L. de Oliveira; M. Neises-von Puttkamer; M. Roeb; C. Sattler

2014-01-01T23:59:59.000Z

208

Impacts of Shallow Geothermal Energy Production on Redox Processes and Microbial Communities  

Science Journals Connector (OSTI)

Impacts of Shallow Geothermal Energy Production on Redox Processes and Microbial Communities ... Thermophilic sulfate reduction, however, had a higher activation energy (100–160 kJ mol–1) than mesophilic sulfate reduction (30–60 kJ mol–1), which might be due to a trade-off between enzyme stability and activity with thermostable enzymes being less efficient catalysts that require higher activation energies. ...

Matthijs Bonte; Wilfred F. M. Röling; Egija Zaura; Paul W. J. J. van der Wielen; Pieter J. Stuyfzand; Boris M. van Breukelen

2013-11-22T23:59:59.000Z

209

Microstructural coarsening effects on redox instability and mechanical damage in solid oxide fuel cell anodes  

Science Journals Connector (OSTI)

In state-of-the-art high temperature solid oxide fuel cells (SOFCs) a porous composite of nickel and yttria stabilized zirconia (Ni/YSZ) is employed as the anode. The rapid oxidation of Ni into NiO is regarded as the main cause of the so-called reduction-oxidation (redox) instability in Ni/YSZ anodes due to the presence of extensive bulk volume changes associated with this reaction. As a consequence the development of internal stresses can lead to performance degradation and/or structural failure. In this study we employ a recently developed continuum formalism to quantify the mechanical deformation behavior and evolution of internal stresses in Ni/YSZ porous anodes due to re-oxidation. In our approach a local failure criterion is coupled to the continuum framework in order to account for the heterogeneous damage accumulation in the YSZ phase. The hallmark of our approach is the ability to track the spatial evolution of mechanical damage and capture the interaction of YSZ damaged regions with the local microstructure. Simulation results highlight the importance of the microstructure characterized by Ni to YSZ particle size ratio on the redox behavior and damage accumulation in as-synthesized SOFC anode systems. Moreover a redox-strain-to-failure criterion is developed to quantify the degree by which coarsened anode microstructures become more susceptible to mechanical damage during re-oxidation.

F. Abdeljawad; M. Haataja

2013-01-01T23:59:59.000Z

210

100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater: FY 1998 Year-End Report  

SciTech Connect

A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the US Department of Energy's Hanford, Washington 100D Area. The target contaminant was dissolved chromate [Cr(VI)] in groundwater. The ISRM technology involves creating a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron [Fe(III)] to ferrous iron [Fe(II)] within the aquifer sediments. This is accomplished by injecting aqueous sodium dithionite into the aquifer and withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in the spring of 1997. The first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998; the remaining four dithionite injections were carried out in May through July of 1998. These five injections created a reduced zone in the Hanford unconfined aquifer 150 feet in length (perpendicular to groundwater flow) by 50 feet wide. The reduced zone extended over the thickness of the unconfined zone, which is approximately 15 feet. Analysis of recent groundwater sampling events shows that the concentrations of chromate [Cr(VI)] in groundwater in the reduced zone have been decreased from starting concentrations of approximately 900 ppb to below analytical detection limits (<7 ppb). Chromate concentrations are also declining in some downgradient monitoring wells. Laboratory analysis of iron in the soil indicates that the barrier should remain in place for approximately 20 to 25 years. These measurements will be confirmed by analysis of sediment cores in FY 1999.

Williams, M.D.; Vermeul, V.R.; Szecsody, J.E.; Fruchter, J.S.; Cole, C.R.

1999-04-15T23:59:59.000Z

211

Append_F_Stream Flow.xls  

Office of Legacy Management (LM)

Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where gradient steepens/lined. 4/14/2000 SW00-01 0.44 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 4/14/2000 SW00-02 0.74 Pipe outfall at east end of millsite 4/17/2000 SW94-01 2.11 4/17/2000 SW92-08 0.85 4/17/2000 SW00-04 0.95 4/18/2000 Sorenson 0.72 4/18/2000 SW00-03 0.58 6/21/2000 SW00-01 0.32 MONTEZUMA CREEK, culvert pair under road on millsite just east of

212

Workshop on electrodes for flowing solution batteries. Summary report  

SciTech Connect

The electrochemical technology of aqueous secondary cells with flowing electrolyte solutions was the subject of a workshop sponsored by EPRI with the cooperation of DOE. The workshop was held in Tampa, Florida, 5-7 November 1979, and was attended by a select group drawn from advanced battery developers, government agencies, universities, and research organizations. The workshop general objectives were to look at the significant parameters believed to govern the performance of the two basic types of electrodes now in use; namely, a porous flow-through electrode (PFTE), and an impervious flow-by electrode. Progress, problems, and prospects were informally discussed. Brief critical reviews were given by session chairmen as a means of introducing each of the key topics (Current Distribution in FTPE, Conversion Efficiency, Segmented FTPE Studies, General Discussion on FTPF Parameters, Surface Activation, Application of FTPE to Waste Recovery, Exxon Zinc-Bromine Flow-By System, FTPE In NASA Redox Energy Storage, and Application of FTPE In Lockheed Zinc/Ferricyanide Redox System). The interaction of this diverse group of engineers and scientists was said by all to be of great benefit in widening understanding of the problems and possible future approaches to new work. The main needs for future work that were identified in the final discussion session among the participants were: (1) engineering analysis, (2) porous structures, (3) materials characteristics, and (4) chemical characteristics. In generally comparing flow-through to flow-by electrodes, there were some surprising differences arising from experimental results that did not fit conventional thinking.

Nanis, L.

1981-02-01T23:59:59.000Z

213

The Integration of a Structural Water-Gas-Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 The InTegraTIon of a STrucTural WaTer- gaS-ShIfT caTalyST WITh a VanadIum alloy hydrogen TranSporT deVIce Description The purpose of this project is to produce a scalable device that simultaneously performs both water-gas-shift (WGS) and hydrogen separation from a coal-derived synthesis gas stream. The justification of such a system is the improved efficiency for the overall production of hydrogen. Removing hydrogen from the synthesis gas (syngas) stream allows the WGS reaction to convert more carbon monoxide (CO) to carbon dioxide (CO 2 ) and maximizes the total hydrogen produced. An additional benefit is the reduction in capital cost of plant construction due to the removal of one step in the process by integrating WGS with the membrane separation device.

214

Slide 1  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vanadium Redox Flow Battery Vanadium Redox Flow Battery Using Mixed Acid Electrolytes November 2, 2010 US DOE Energy Storage Systems (ESS) Program Review Washington DC Liyu Li, Soowhan Kim, Wei Wang, M. Vijayakumar, Zimin Nie, Baowei Chen, Jianlu Zhang, Jianzhi Hu, Gordon Graff, Jun Liu, Gary Yang * Funded by the Energy Storage Systems Program of the U.S. Department Of Energy through Pacific Northwest National Laboratories Redox Flow Battery (RFB)  A redox flow battery is a promising technology for large scale energy storage . Potential RFB Systems -1.0 -0.5 0.0 0.5 1.0 1.5 2.0 Standard potential (V) of redox couples H 2 evolution O 2 evolution V 3+ /V 2+ VO 2 + /VO 2+ VO 2+ /V 3+ Fe 3+ /Fe 2+ Mn 3+ /Mn 2+ MnO 4 - /MnO 2 Ce 4+ /Ce 3+ Co 3+ /Co 2+ Cu 2+ /Cu + TiOH 3+ /Ti 3+ Ti 3+ /Ti 2+ Cr 3+ /Cr 2+ Zn 2+ /Zn

215

Electron flow in multiheme bacterial cytochromes is a balancing act between heme electronic interaction and redox potentials  

Science Journals Connector (OSTI)

...substrates within the cell, but expanding...saturated by a dummy hydrogen atom and the axial...saturated with a hydrogen at the {beta...production in microbial fuel cells . Biosens Bioelectron...scheme for hybrid Car-Parrinello molecular...

Marian Breuer; Kevin M. Rosso; Jochen Blumberger

2014-01-01T23:59:59.000Z

216

Anoxic Plume Attenuation in a Fluctuating Water Table System: Impact of 100-D Area In Situ Redox Manipulation on Downgradient Dissolved Oxygen Concentrations  

SciTech Connect

Anoxic Plume Attenuation in a Fluctuating Water Table System: Impact of 100-D Area In Situ Redox Manipulation on Downgradient Dissolved Oxygen Concentrations

Williams, Mark D.; Vermeul, Vincent R.; Oostrom, Martinus; Evans, John C.; Fruchter, Jonathan S.; Istok, J. D.; Humphrey, M. D.; Lanigan, David C.; Szecsody, James E.; White, Mark D.; Wietsma, Thomas W.; Cole, Charles R.

1999-06-14T23:59:59.000Z

217

High-energy mechanical synthesis of nanophase fluorite-structured mixed oxide catalysts with a high redox activity  

SciTech Connect

A series of nanostructured, highly defective, ternary solid solutions containing CeO{sub 2}, ZrO{sub 2}, and MnO{sub 2} or CuO were prepared by high-energy mechanical milling of individual components. Morphological and redox properties were studied by XRD, HRTEM and temperature-programmed reduction techniques. It was shown that the introduction of small amounts of copper and manganese strongly promotes the redox behavior of cerium at lower temperatures in comparison with CeO{sub 2} and CeO{sub 2}-ZrO{sub 2}. High temperature treatment of up to 1,400 K was also shown to further promote overall redox capacity without affecting low-temperature redox behavior. Moreover, evidence is provided to show that Cu and Mn are dissolved within the CeO{sub 2} lattice structure. Addition of dopants enhances catalytic redox properties in the oxidation of CO at low temperatures, which is associated with the high concentration of oxygen vacancies that form on the introduction of aliovalent elements into the ceria-zirconia lattice.

Primavera, A.; Trovarelli, A.; Terribile, D.; Leitenburg, C. de; Dolcetti, G. [Univ. di Udine (Italy). Dipt. di Scienze e Tecnologie Chimiche; Llorca, J. [Univ. de Barcelona (Spain). Dept. de Quimica Inorganica

1997-12-31T23:59:59.000Z

218

SFTEL: Flow Cell | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow Cell EMSL's Subsurface Flow and Transport Experimental Laboratory offers several meter-scale flow cells and columns for research in saturated and unsaturated porous media....

219

Membranes and separators for flowing electrolyte batteries-a review  

SciTech Connect

Flowing electrolyte batteries are rechargeable electrochemical storage devices in which externally stored electrolytes are circulated through the cell stack during charge or discharge. The potential advantages that flow batteries offer compared to other secondary batteries include: 1) ease of thermal and electrolyte management, 2) simple electrochemistry, 3) deep cycling capability, and 4) minimal loss of capacity with cycling. However, flow batteries are more complex than other secondary batteries and consequently may cost more and may be less reliable. Flow batteries are being developed for utility load leveling, electric vehicles, solar photovoltaic and wind turbine application. The status of flow batteries has recently been reviewed by Clark et al. The flowing electrolyte batteries place rigorous demands on the performance of separators and membranes. The operating characteristics of the iron/chromium redox battery were changed in order to accommodate the limitations in membrane performance. Low cost alternatives to the presently used membrane must be found before the zinc/ferricyanide battery can be economically feasible. The zinc/bromine battery's efficiency could be improved if a suitably selective membrane were available. It is anticipated that better and less costly membranes to meet these needs will be developed as more is learned about their preparation and performance.

Arnold, C.; Assink, R.A.

1983-01-01T23:59:59.000Z

220

To be published in IEEE Aerospace Conference Proceedings, 2003, Cat No. 0-7803-7651-X/03/$17.00 2003 IEEE Planar REDOX and Conductivity Sensors  

E-Print Network (OSTI)

/$17.00 © 2003 IEEE Planar REDOX and Conductivity Sensors for ISS Water Quality Measurements1 Martin G. Buehler REDOX and conductivity sensors that are used to detect ionic species in solution by measuring the electrochemical cell current as the voltage is scanned. The simplicity and robustness of these sensors allows

Kounaves, Samuel P.

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Molybdenum in Nuclear Waste Glasses -Incorporation and Redox state R.J. Short, R.J. Hand, N.C. Hyatt,  

E-Print Network (OSTI)

Molybdenum in Nuclear Waste Glasses - Incorporation and Redox state R.J. Short, R.J. Hand, N form in simulated high level nuclear waste (HLW) glass melts have been studied. It was found less attention has been paid to the effects of redox on nuclear waste glasses. One particular element

Sheffield, University of

222

Silver vanadium diphosphate Ag{sub 2}VP{sub 2}O{sub 8}: Electrochemistry and characterization of reduced material providing mechanistic insights  

SciTech Connect

Silver vanadium phosphorous oxides (Ag{sub w}V{sub x}P{sub y}O{sub z}) are notable battery cathode materials due to their high energy density and demonstrated ability to form in-situ Ag metal nanostructured electrically conductive networks within the cathode. While analogous silver vanadium diphosphate materials have been prepared, electrochemical evaluations of these diphosphate based materials have been limited. We report here the first electrochemical study of a silver vanadium diphosphate, Ag{sub 2}VP{sub 2}O{sub 8}, where the structural differences associated with phosphorous oxides versus diphosphates profoundly affect the associated electrochemistry. Reminiscent of Ag{sub 2}VO{sub 2}PO{sub 4} reduction, in-situ formation of silver metal nanoparticles was observed with reduction of Ag{sub 2}VP{sub 2}O{sub 8}. However, counter to Ag{sub 2}VO{sub 2}PO{sub 4} reduction, Ag{sub 2}VP{sub 2}O{sub 8} demonstrates a significant decrease in conductivity upon continued electrochemical reduction. Structural analysis contrasting the crystallography of the parent Ag{sub 2}VP{sub 2}O{sub 8} with that of the proposed Li{sub 2}VP{sub 2}O{sub 8} reduction product is employed to gain insight into the observed electrochemical reduction behavior, where the structural rigidity associated with the diphosphate anion may be associated with the observed particle fracturing upon deep electrochemical reduction. Further, the diphosphate anion structure may be associated with the high thermal stability of the partially reduced Ag{sub 2}VP{sub 2}O{sub 8} materials, which bodes well for enhanced safety of batteries incorporating this material. - Graphical abstract: Structure and galvanostatic intermittent titration-type test data for silver vanadium diphosphate, Ag{sub 2}VP{sub 2}O{sub 8}. Highlights: ? First electrochemical study of a silver vanadium diphosphate, Ag{sub 2}VP{sub 2}O{sub 8}. ? In-situ formation of Ag{sup 0} nanoparticles was observed upon electrochemical reduction. ? Structural analysis used to provide insight of the electrochemical behavior.

Takeuchi, Esther S., E-mail: esther.takeuchi@stonybrook.edu [Department Materials Science and Engineering, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Global and Regional Solutions Directorate, Brookhaven National Laboratory, Upton, NY 11973 (United States); Department of Chemistry, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Lee, Chia-Ying; Cheng, Po-Jen [Department of Chemical and Biological Engineering, University at Buffalo (SUNY), Buffalo, NY 14260 (United States); Menard, Melissa C. [Department Materials Science and Engineering, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Marschilok, Amy C., E-mail: amy.marschilok@stonybrook.edu [Department Materials Science and Engineering, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Department of Chemistry, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Takeuchi, Kenneth J., E-mail: kenneth.takeuchi.1@stonybrook.edu [Department of Chemistry, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States)

2013-04-15T23:59:59.000Z

223

Use of Dissolved H2 Concentrations To Determine Distribution of Microbially Catalyzed Redox Reactions in Anoxic Groundwater  

E-Print Network (OSTI)

similartothe HZconcentrationsthat havepreviously been reported for aquatic sedimentswith the same TEAPs. In two aquifers contaminated with petroleum products, it was impossible with standard geochemical analyses actuallyexist (i.e.,there arenofreeelectrons); (2) the redox status of most natural waters cannot be accurately

Lovley, Derek

224

Hyporheic Exchange and Fulvic Acid Redox Reactions in an Alpine Stream/Wetland Ecosystem, Colorado Front Range  

Science Journals Connector (OSTI)

Hyporheic Exchange and Fulvic Acid Redox Reactions in an Alpine Stream/Wetland Ecosystem, Colorado Front Range ... Fluxes of dissolved organic carbon (DOC) in mountain catchments of the western United States vary with hydrograph stage (1, 2) and inter-annual climate variation (3). ...

Matthew P. Miller; Diane M. McKnight; Rose M. Cory; Mark W. Williams; Robert L. Runkel

2006-08-23T23:59:59.000Z

225

Quercetin and Dietary Lipids Alter the Cellular Redox Environment of the Colonocyte in the Promotion Stage of Colon Carcinogenesis.  

E-Print Network (OSTI)

the beneficial effects of FO by counteracting FO effects on colonocyte redox status. To test this, we provided 40 rats with FO or CO (fiber = pectin) diets with Q being 0 or 0.45% of the diet for 10 wk. All rats were injected with azoxymethane (AOM) on d 21...

Paulhill, Kimberly Jones

2009-05-15T23:59:59.000Z

226

Redox-Responsive Magnetic Nanoparticle for Targeted Convection-Enhanced Delivery of O6-Benzylguanine to Brain Tumors  

Science Journals Connector (OSTI)

Redox-Responsive Magnetic Nanoparticle for Targeted Convection-Enhanced Delivery of O6-Benzylguanine to Brain Tumors ... In vivo, CED of NPCP-BG-CTX produced an excellent volume of distribution (Vd) within the brain of mice bearing orthotopic human primary GBM xenografts. ...

Zachary R. Stephen; Forrest M. Kievit; Omid Veiseh; Peter A. Chiarelli; Chen Fang; Kui Wang; Shelby J. Hatzinger; Richard G. Ellenbogen; John R. Silber; Miqin Zhang

2014-09-23T23:59:59.000Z

227

Mobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox conditions  

E-Print Network (OSTI)

). Typically, it comprises residual iron oxides, quartz, sodium aluminosilicates, titanium dioxide, calciumMobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox elements, including arsenic. Aerobic and anaer- obic batch experiments were prepared using soils from near

Burke, Ian

228

Research Program to Determine Redox Reactions and Their Effects on Speciation and Mobility of Plutonium in DOE Wastes  

SciTech Connect

Plutonium in geologic matrices undergoes a variety of complex reactions which complicate its environmental behavior. These complexities in plutonium chemistry whereby a large variety of precipitation, dissolution, adsorption/desorption, and redox reactions control plutonium speciation and concentrations, result in the need for a rather large amount of reliable, fundamental data to predict Pu behavior in geologic media. These data are also needed for evaluation of remediation strategies that involve removing most of the contaminants by selective methods, followed by in situ immobilization of residual contaminants. Two areas were studied during this project: (1) thermodynamic data for Th(IV) and Pu(IV) complexes of EDTA and for Pu(V) interactions with chloride; (2) kinetic data for redox reactions of Pu in the presence of common redox agents (e.g., H{sub 2}O{sub 2}, MnO{sub 2}, and NaOCl) encountered under waste disposal conditions. These studies are relevant to understanding Pu behavior in wastes disposed of in diverse geologic conditions (e.g., at the WIPP and YUCCA Mountain repositories and in contaminated sediments at many different DOE sites) and also for developing effective remediation strategies (e.g., processing of high level waste tanks). These studies have yielded data to address redox reactions of plutonium in the presence of environmentally important agents (e.g. organic and inorganic oxidants/reductants).

Choppin, G.R.; Rai, D.

2000-10-01T23:59:59.000Z

229

An Arabidopsis Glutathione Peroxidase Functions as Both a Redox Transducer and a Scavenger in Abscisic Acid and Drought Stress Responses  

Science Journals Connector (OSTI)

...Functions as Both a Redox Transducer and a Scavenger in Abscisic Acid and Drought Stress Responses [W] Yuchen Miao a b Dong Lv a Pengcheng Wang a Xue-Chen Wang b Jia Chen b Chen Miao a Chun-Peng Song a 1 1 To whom correspondence should be addressed. E-mail...

Yuchen Miao; Dong Lv; Pengcheng Wang; Xue-Chen Wang; Jia Chen; Chen Miao; Chun-Peng Song

2006-09-22T23:59:59.000Z

230

Solar Thermochemical Fuels Production: Solar Fuels via Partial Redox Cycles with Heat Recovery  

SciTech Connect

HEATS Project: The University of Minnesota is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. The University of Minnesota is envisioning producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration. This new technology will allow for the effective use of vast domestic solar resources to produce precursors to synthetic fuels that could replace gasoline.

None

2011-12-19T23:59:59.000Z

231

A review on solar thermal syngas production via redox pair-based water/carbon dioxide splitting thermochemical cycles  

Science Journals Connector (OSTI)

Abstract The high power density, ease of transportation and storage and many years of development of internal combustion engine technologies have put liquid hydrocarbon fuels at a privileged position in our energy mix. Therefore processes that use renewable energy sources to produce liquid hydrocarbon fuels from H2O and CO2 are of crucial importance. Concentrated Solar Power (CSP) can be employed as the only energy source for the renewable production of hydrogen from water either indirectly, e.g. by supplying the electricity for electrolysis, or directly by supplying the necessary heat for thermochemically producing hydrogen. Among the various thermochemical cycles tested so far for CSP-driven hydrogen production via water splitting (WS), those based on redox-pair oxide systems, are directly adaptable to carbon dioxide splitting (CDS) and/or combined CO2/H2O splitting for the production of CO or syngas, respectively. The acknowledgement of this fact has recently revived the interest of the scientific community on such technologies. The current article presents the development, evolution and current status of CSP-aided syngas production via such redox-pair-based thermochemical cycles. At first the various redox oxide material compositions tested for water/carbon dioxide splitting are presented and their redox chemistries are discussed. Then the selection of suitable solar reactors is addressed in conjunction with the boundary conditions imposed by the redox systems as well as the heat demands, technical peculiarities and requirements of the cycle steps. The various solar reactor concepts proposed and employed for such reactions and their current status of development are presented. Finally, topics where further work is needed for commercialization of the technology are identified and discussed.

Christos Agrafiotis; Martin Roeb; Christian Sattler

2015-01-01T23:59:59.000Z

232

Low volume flow meter  

DOE Patents (OSTI)

The low flow monitor provides a means for determining if a fluid flow meets a minimum threshold level of flow. The low flow monitor operates with a minimum of intrusion by the flow detection device into the flow. The electrical portion of the monitor is externally located with respect to the fluid stream which allows for repairs to the monitor without disrupting the flow. The electronics provide for the adjustment of the threshold level to meet the required conditions. The apparatus can be modified to provide an upper limit to the flow monitor by providing for a parallel electronic circuit which provides for a bracketing of the desired flow rate.

Meixler, Lewis D. (East Windsor, NJ)

1993-01-01T23:59:59.000Z

233

Propeller Flow Meter  

E-Print Network (OSTI)

Propeller flow meters are commonly used to measure water flow rate. They can also be used to estimate irrigation water use. This publication explains how to select, install, read and maintain propeller flow meters....

Enciso, Juan; Santistevan, Dean; Hla, Aung K.

2007-10-01T23:59:59.000Z

234

Dispersed flow film boiling  

E-Print Network (OSTI)

Dispersed flow consists of small liquid droplets entrained in a flowing vapor. This flow regime can occur in cryogenic equipment, in steam generators, and during nuclear reactor loss of coolant accidents. A theoretical ...

Yoder, Graydon L.

1980-01-01T23:59:59.000Z

235

Bacteria in shear flow  

E-Print Network (OSTI)

Bacteria are ubiquitous and play a critical role in many contexts. Their environment is nearly always dynamic due to the prevalence of fluid flow: creeping flow in soil, highly sheared flow in bodily conduits, and turbulent ...

Marcos, Ph.D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

236

Electrical current suppression in Pd-doped vanadium pentoxide nanowires caused by reduction in PdO due to hydrogen exposure  

SciTech Connect

Pd nanoparticle-doped vanadium pentoxide nanowires (Pd-VONs) were synthesized. Electrical current suppression was observed when the Pd-VON was exposed to hydrogen gas, which cannot be explained by the work function changes mentioned in previous report such as Pd-doped carbon nanotubes and SnO{sub 2} nanowires. Using the x-ray photoelectron spectroscopy, we found that the reduction in PdO due to hydrogen exposure plays an important role in the current suppression of the Pd-VON.

Kim, Byung Hoon; Oh, Soon-Young; Yu, Han Young; Yun, Yong Ju; Kim, Yark Yeon; Hong, Won G. [Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Jeong, Hu Young; Lee, Jeong Yong [Department of Materials Science and Engineering, KAIST, Daejeon 305-701 (Korea, Republic of); Kim, Hae Jin [Korea Basic Science Institute, Daejeon 305-333 (Korea, Republic of)

2010-04-19T23:59:59.000Z

237

The strong reactions of Lewis-base noble-metals with vanadium and other acidic transition metals  

SciTech Connect

The noble metals often thought of as unreactive solids,react strongly with nearly 40% of the elements in the periodictable: group IIIB-VB transition metals, lanthanides, theactinides, and group IIIA-IVA non-transition metals. These strong reactions arise from increased bonding/electron transfer fromnonbonding electrons d electron pairs on the noble metal tovacant orbitals on V, etc. This effect is a generalized Lewis acid-base interaction. The partial Gibbs energy of V in the noblemetals has been measured as a function of concentration at a temperature near 1000C. Thermodynamics of the intermetallics are determined by ternary oxide equilibria, ternary carbide equilibria, and the high-temperature galvanic cell technique. These experimental methods use equilibrated solid composite mixtures in which grains of V oxides or of V carbides are interspersed with grains of V-NM(noble-metal) alloys. In equilibrium the activity of V in the oxide or the carbide equals the activity in the alloy. Consequently, the thermodynamics available in the literature for the V oxides and V carbides are reviewed. Test runs on the galvanic cell were attempted. The V oxide electrode reacts with CaF[sub 2], ThO[sub 2], YDT(0.85ThO[sub 2]-0.15YO[sub 1.5]), and LDT(0.85ThO[sub 2]- 0.15LaO[sub 1.5]) to interfere with the measured data observed toward the beginning of a galvanic cell experiment are the most accurate. The interaction of vanadium at infinite dilution in the noble-metals was determined.

Ebbinghaus, B.B.

1991-05-01T23:59:59.000Z

238

The strong reactions of Lewis-base noble-metals with vanadium and other acidic transition metals  

SciTech Connect

The noble metals often thought of as unreactive solids,react strongly with nearly 40% of the elements in the periodictable: group IIIB-VB transition metals, lanthanides, theactinides, and group IIIA-IVA non-transition metals. These strong reactions arise from increased bonding/electron transfer fromnonbonding electrons d electron pairs on the noble metal tovacant orbitals on V, etc. This effect is a generalized Lewis acid-base interaction. The partial Gibbs energy of V in the noblemetals has been measured as a function of concentration at a temperature near 1000C. Thermodynamics of the intermetallics are determined by ternary oxide equilibria, ternary carbide equilibria, and the high-temperature galvanic cell technique. These experimental methods use equilibrated solid composite mixtures in which grains of V oxides or of V carbides are interspersed with grains of V-NM(noble-metal) alloys. In equilibrium the activity of V in the oxide or the carbide equals the activity in the alloy. Consequently, the thermodynamics available in the literature for the V oxides and V carbides are reviewed. Test runs on the galvanic cell were attempted. The V oxide electrode reacts with CaF{sub 2}, ThO{sub 2}, YDT(0.85ThO{sub 2}-0.15YO{sub 1.5}), and LDT(0.85ThO{sub 2}- 0.15LaO{sub 1.5}) to interfere with the measured data observed toward the beginning of a galvanic cell experiment are the most accurate. The interaction of vanadium at infinite dilution in the noble-metals was determined.

Ebbinghaus, B.B.

1991-05-01T23:59:59.000Z

239

Flow Distances on Open Flow Networks  

E-Print Network (OSTI)

Open flow network is a weighted directed graph with a source and a sink, depicting flux distributions on networks in the steady state of an open flow system. Energetic food webs, economic input-output networks, and international trade networks, are open flow network models of energy flows between species, money or value flows between industrial sectors, and goods flows between countries, respectively. Flow distances (first-passage or total) between any given two nodes $i$ and $j$ are defined as the average number of transition steps of a random walker along the network from $i$ to $j$ under some conditions. They apparently deviate from the conventional random walk distance on a closed directed graph because they consider the openness of the flow network. Flow distances are explicitly expressed by underlying Markov matrix of a flow system in this paper. With this novel theoretical conception, we can visualize open flow networks, calculating centrality of each node, and clustering nodes into groups. We apply fl...

Guo, Liangzhu; Shi, Peiteng; Wang, Jun; Huang, Xiaohan; Zhang, Jiang

2015-01-01T23:59:59.000Z

240

Mechanism and Site Requirements for Ethanol Oxidation on Vanadium Oxide Domains Beata Kilos, Alexis T. Bell,* and Enrique Iglesia*  

E-Print Network (OSTI)

was then heated in dry air (Praxair, zero grade) flowing at 0.83 cm3 s-1 g-1 . The temperature was raised at 0

Bell, Alexis T.

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

GEOC R Lee Penn Sunday, March 25, 2012 12 -Biogeochemical transformation of Fe-and Mn-along a redox gradient: Implications for carbon sequestration  

E-Print Network (OSTI)

a redox gradient: Implications for carbon sequestration within the Christina River Basin Critical Zone States Organic carbon (C)-mineral complexation mechanism is crucial in C sequestration. It is a function

Sparks, Donald L.

242

Methane-water redox reaction on A2SnO4 (A=Mg, Ca, Sr, Ba) oxide to produce C2 hydrocarbons  

Science Journals Connector (OSTI)

A2BO4...type oxides consisting of an alkali earth metal and tin showed high selectivity (>99%) and activity for the oxidative coupling of methane at 1023 K in a methane-water redox system where active oxygen spec...

K. Omata; T. Ehara; I. Kawai; M. Yamada

243

Probing Ligand Effects on the Redox Energies of [4Fe-4S] Clusters Using Broken-Symmetry Density Functional Theory  

SciTech Connect

A central issue in understanding redox properties of iron-sulfur proteins is determining the factors that tune the reduction potentials of the Fe-S clusters. Recently, Solomon and coworkers have shown that the Fe-S bond covalency of protein analogs measured by %L, the percent ligand character of the Fe 3d orbitals, from ligand K-edge X-ray absorption spectroscopy (XAS) correlates with the electrochemical redox potentials. Also, Wang and coworkers have measured electron detachment energies for iron-sulfur clusters without environmental perturbations by gas-phase photoelectron spectroscopy (PES). Here the correlations of the ligand character with redox energy and %L character are examined in [Fe?S?L?]2? clusters with different ligands by broken symmetry density functional theory (BS-DFT) calculations using the B3LYP functional together with PES and XAS experimental results. These gas-phase studies assess ligand effects independently of environmental perturbations and thus provide essential information for computational studies of iron-sulfur proteins. The B3LYP oxidation energies agree well with PES data, and the %L character obtained from natural bond orbital analysis correlates with XAS values, although it systematically underestimates them because of basis set effects. The results show that stronger electron-donating terminal ligands increase %Lt, the percent ligand character from terminal ligands, but decrease %Sb, the percent ligand character from the bridging sulfurs. Because the oxidized orbital has significant Fe-Lt antibonding character, the oxidation energy correlates well with %Lt. However, because the reduced orbital has varying contributions of both Fe-Lt and Fe-Sb antibonding character, the reduction energy does not correlate with either %Lt or %Sb. Overall, BSDFT calculations together with XAS and PES experiments can unravel the complex underlying factors in the redox energy and chemical bonding of the [4Fe-4S] clusters in iron-sulfur proteins.

Niu, Shuqiang; Ichiye, Toshiko

2009-05-14T23:59:59.000Z

244

Synthesis of Nanostructured Carbides of Titanium and Vanadium from Metal Oxides and Ferroalloys Through High-energy Mechanical Milling and Heat Treatment  

SciTech Connect

Carbides of Ti and V have been synthesized directly from their oxides and ferroalloys through mechanical milling and heat treatment. The powder mixtures are milled in a planetary ball mill from 15-80 hours and subsequently heat treated at 1000-1300 deg. C for TiO{sub 2}-C mixtures, at 500-550 deg. C for V{sub 2}O{sub 5}-C mixtures and at 600-1000 deg. C for (Fe-V)-C mixtures. The milled and heat treated powders are characterized by SEM, EDAX, XRD, and BET techniques. Nanostructured TiC has been successfully synthesized under suitable processing conditions. However, carbides of vanadium is unidentified even though possibilities of V{sub 2}O{sub 5}-C reaction are indicated with an extent of induced amorphism in the powder mixture. Density, specific surface area and particle size of the milled and heat treated mixtures are correlated with heat treatment temperatures. Similar attempts are also made to synthesize vanadium carbides from industrial grade Fe-V.

Basu, P.; Jian, P. F.; Seong, K. Y.; Seng, G. S.; Hussain, Z.; Aziz, A. [School of Materials and Minerals Resources Engineering, Universiti Sains Malaysia (USM), Engineering Campus, 14300 Nibong Tebal, Pulau Pinang (Malaysia); Masrom, A. K. [Advanced Materials Research Centre (AMREC), SIRIM Bhd, Kulim Hi-Tech Park, Kulim 09000 (Malaysia)

2010-03-11T23:59:59.000Z

245

Portable wastewater flow meter  

DOE Patents (OSTI)

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under fill pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1999-02-02T23:59:59.000Z

246

Portable wastewater flow meter  

DOE Patents (OSTI)

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under full pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1990-01-01T23:59:59.000Z

247

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions  

SciTech Connect

The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state Li4+xTi5O12/LiPON/LixV2O5 cell and examine in situ the chemistry of Li-O2 reaction products on LixV2O5 as a function of applied voltage under ultra high vacuum (UHV) and near ambient-pressure of oxygen using X-ray photoelectron spectroscopy (APXPS). Oxygen reduction and evolution reactions take place on the surface of the mixed electronic and Li+ ionic conductor, LixV2O5, which eliminate parasitic reactions between oxygen reduction/evolution reaction intermediates and aprotic electrolytes used in Li-O2 batteries reported to date. Under UHV, reversible lithium intercalation and de-intercalation from LixV2O5 was noted, where the changes in the vanadium valence state revealed from XPS in this study were comparable to that reported previously from Li/LixV2O5 thin film batteries. In presence of oxygen near ambient pressure, the LixV2O5 surface was covered gradually by the reaction product of oxygen reduction, namely lithium peroxide (Li2O2) (approximately 1-2 unit cells) upon discharge. Interestingly, the LixV2O5 surface became re-exposed upon charging, and the oxidation of Li2O2 began at much lower overpotentials (~240 mV) than the charge overpotentials of Li-O2 cells (~1000 mV) with aprotic electrolytes, which can be attributed to subnanometer-thick Li2O2 with surfaces free of contaminants such as carbonate species. Our study provides first evidence of reversible lithium peroxide formation and decomposition in situ on an oxide surface using a solid-state cell, and new insights into the reaction mechanism of Li-O2 chemistry.

Lu, Yi-chun [Massachusetts Institute of Technology (MIT); Crumlin, Ethan [Massachusetts Institute of Technology (MIT); Veith, Gabriel M [ORNL; Harding, Jonathon [Massachusetts Institute of Technology (MIT); Dudney, Nancy J [ORNL; Liu, Zhi [Lawrence Berkeley National Laboratory (LBNL); Shao-Horn, Yang [Massachusetts Institute of Technology (MIT)

2012-01-01T23:59:59.000Z

248

JOURNAL DE PHYSIQUE CoZZoque C8, suppZ6ment au n08, Tome 41, aoGt 1980, page C8-163 STUDY OF LIQUID NICKEL-VANADIUM ALLOYS BY NEUTRON DIFFRACTION AND MODEL SIMULATION  

E-Print Network (OSTI)

, 28 i s the scattering angle, X the neutron wave- length, Q = 4n the modulus of the scattering vector NICKEL-VANADIUM ALLOYS BY NEUTRON DIFFRACTION AND MODEL SIMULATION J.L. Lemarchand, J. Bletry and P with model c a l c u l a t i o ~can lead to a quantitative interpreta- tion. In this paper, neutron

Boyer, Edmond

249

Effects of Protonation State on a Tyrosine?Histidine Bioinspired Redox Mediator  

SciTech Connect

The conversion of tyrosine to the corresponding tyrosyl radical in photosytem II (PSII) is an example of proton-coupled electron transfer. Although the tyrosine moiety (Tyr{sub Z}) is known to function as a redox mediator between the photo-oxidized primary donor (P680{sup •+}) and the Mn-containing oxygen-evolving complex, the protonation states involved in the course of the reaction remain an active area of investigation. Herein, we report on the optical, structural, and electrochemical properties of tyrosine?histidine constructs, which model the function of their naturally occurring counterparts in PSII. Electrochemical studies show that the phenoxyl/phenol couple of the model is chemically reversible and thermodynamically capable of water oxidation. Studies under acidic and basic conditions provide clear evidence that an ionizable proton controls the electrochemical potential of the tyrosine?histidine mimic and that an exogenous base or acid can be used to generate a low-potential or high-potential mediator, respectively. The phenoxyl/phenoxide couple associated with the low-potential mediator is thermodynamically incapable of water oxidation, whereas the relay associated with the high-potential mediator is thermodynamically incapable of reducing an attached photoexcited porphyrin. These studies provide insight regarding the mechanistic role of the tyrosine?histidine complex in water oxidation and strategies for making use of hydrogen bonds to affect the coupling between proton and electron transfer in artificial photosynthetic systems.

Moore, Gary F.; Hambourger, Michael; Kodis, Gerdenis; Michl, Weston; Gust, Devens; Moore, Thomas A.; Moore, Ana L.

2010-01-01T23:59:59.000Z

250

Chelant extraction and REDOX manipulation for mobilization of heavy metals from contaminated soils  

SciTech Connect

Was the result of open burning and open detonation of chemical agents and munitions in the Toxic Burning Pits area at J-Field, located in the Edgewood Area of Aberdeen Proving Ground in Harford County, Maryland, soils have been contaminated with heavy metals. Simultaneous extraction is complicated because of the multitude of contaminant forms that exist. This paper uses data from a treatability study performed at Argonne National Laboratory to discuss and compare several treatment methods that were evaluated for remediating metals-contaminated soils. J-Field soils were subjected to a series of treatability experiments designed to determine the feasibility of using soil washing/soil flushing, enhancements to soil washing/soil flushing, solidification/stabilization, and electrokinetics for remediating soils contaminated with metals. Chelating and mobilizing agents evaluated included ammonium acetate, ethylenediaminetetraacetic acid, citric acid, Citranox, gluconic acid, phosphoric acid, oxalic acid, and nitrilotriacetic acid, in addition to pH-adjusted water. REDOX manipulation can maximize solubilities, increase desorption, and promote removal of heavy metal contaminants. Reducing agents that were studied included sodium borohydride, sodium metabisulfite, and thiourea dioxide. The oxidants studied included hydrogen peroxide, sodium percarbonate, sodium hypochlorite, and potassium permanganate. This paper summaries the results from the physical/chemical characterization, soil washing/soil flushing, and enhancements to soil washing/soil flushing portions of the study.

Brewster, M.D.; Peters, R.W.; Miller, G.A.; Patton, T.L.; Martino, L.E.

1994-12-01T23:59:59.000Z

251

Degradation of yttria-stabilized zirconia thermal barrier coatings by vanadium pentoxide, phosphorous pentoxide, and sodium sulfate  

SciTech Connect

The presence of vanadium, phosphorus, and sodium impurities in petcoke and coal/petcoke blends used in integrated gasification combined cycle (IGCC) plants warrants a clear understanding of high-temperature material degradation for the development of fuel-flexible gas turbines. In this study, degradation reactions of free-standing air plasma-sprayed (APS) yttria-stabilized zirconia (YSZ) in contact with V{sub 2}O{sub 5}, P{sub 2}O{sub 5}, and Na{sub 2}SO{sub 4} were investigated at temperatures up to 1200{sup o}C. Phase transformations and microstructural development were examined using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Molten V{sub 2}O{sub 5} reacted with solid YSZ to form ZrV{sub 2}O{sub 7} at temperatures below 747{sup o}C. However, at temperatures above 747{sup o}C, molten V{sub 2}O{sub 5} reacted with YSZ to form yttrium vanadate (YVO{sub 4}). The formation of YVO{sub 4} led to the depletion of the Y2O{sub 3} stabilizer and deleterious transformation to the monoclinic ZrO{sub 2} phase. In addition, studies on YSZ degradation by Na{sub 2}SO{sub 4} and a Na{sub 2}SO{sub 4}+V{sub 2}O{sub 5} mixture (50-50 mol%) showed that Na{sub 2}SO{sub 4} itself had no effect on the degradation of YSZ. However, in the presence of V{sub 2}O{sub 5} at high temperatures, Na{sub 2}SO{sub 4} forms vanadate compounds having a lower melting point such as sodium metavanadate (610{sup o}C), which was found to degrade YSZ by the formation of YVO{sub 4} at a relatively lower temperature of 700{sup o}C. P{sub 2}O{sub 5} was found to react with APS YSZ by the formation of ZrP{sub 2}O{sub 7} at all the temperatures studied. At temperatures as low as 200{sup o}C and as high as 1200{sup o}C, molten P{sub 2}O{sub 5} was observed to react with solid YSZ to yield ZrP{sub 2}O{sub 7}, which led to the depletion of ZrO{sub 2} in YSZ that promoted the formation of the fluorite-cubic ZrO{sub 2} phase.

Mohan, P.; Yuan, B.; Patterson, T.; Desai, V.H.; Sohn, Y.H. [University of Central Florida, Orlando, FL (United States)

2007-11-15T23:59:59.000Z

252

Redox-active tyrosine residue in the microcin J25 molecule  

SciTech Connect

Research highlights: {yields} Cyclic voltammetry measurements showed irreversible oxidation of MccJ25 and MccJ25 (Y9F). {yields} Infrared spectroscopy studies showed that only Tyr9 could be deprotonated upon chemical oxidation. {yields} Formation of a long-lived tyrosyl radical in the native MccJ25 oxidized by H{sub 2}O{sub 2} was demonstrated. {yields} Tyr9 but not Tyr20 can be easily oxidized and form a tyrosyl radical. -- Abstract: Microcin J25 (MccJ25) is a 21 amino acid lasso-peptide antibiotic produced by Escherichia coli and composed of an 8-residues ring and a terminal 'tail' passing through the ring. We have previously reported two cellular targets for this antibiotic, bacterial RNA polymerase and the membrane respiratory chain, and shown that Tyr9 is essential for the effect on the membrane respiratory chain which leads to superoxide overproduction. In the present paper we investigated the redox behavior of MccJ25 and the mutant MccJ25 (Y9F). Cyclic voltammetry measurements showed irreversible oxidation of both Tyr9 and Tyr20 in MccJ25, but infrared spectroscopy studies demonstrated that only Tyr9 could be deprotonated upon chemical oxidation in solution. Formation of a long-lived tyrosyl radical in the native MccJ25 oxidized by H{sub 2}O{sub 2} was demonstrated by Electron Paramagnetic Resonance Spectroscopy; this radical was not detected when the reaction was carried out with the MccJ25 (Y9F) mutant. These results show that the essential Tyr9, but not Tyr20, can be easily oxidized and form a tyrosyl radical.

Chalon, Miriam C. [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)] [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina); Wilke, Natalia [CIQUIBIC, Dpto. de Quimica Biologica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Pabellon Argentina, Ciudad Universitaria, X5000HUA, Cordoba (Argentina)] [CIQUIBIC, Dpto. de Quimica Biologica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Pabellon Argentina, Ciudad Universitaria, X5000HUA, Cordoba (Argentina); Pedersen, Jens; Rufini, Stefano [Department of Biology, University of Rome Tor Vergata 00133, Rome (Italy)] [Department of Biology, University of Rome Tor Vergata 00133, Rome (Italy); Morero, Roberto D.; Cortez, Leonardo; Chehin, Rosana N.; Farias, Ricardo N. [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)] [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina); Vincent, Paula A., E-mail: pvincent@fbqf.unt.edu.ar [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)

2011-03-18T23:59:59.000Z

253

Plastic Flow in Glass  

Science Journals Connector (OSTI)

...1964 research-article Plastic Flow in Glass D. M. Marsh The classical brittle fracture...account for the mechanical properties of glasses, but the widespread evidence of plastic flow in all glass fracture phenomena even at room temperature...

1964-01-01T23:59:59.000Z

254

Ultrasonic flow metering system  

DOE Patents (OSTI)

A system for determining the density, flow velocity, and mass flow of a fluid comprising at least one sing-around circuit that determines the velocity of a signal in the fluid and that is correlatable to a database for the fluid. A system for determining flow velocity uses two of the inventive circuits with directional transmitters and receivers, one of which is set at an angle to the direction of flow that is different from the others.

Gomm, Tyler J. (Meridian, ID); Kraft, Nancy C. (Idaho Falls, ID); Mauseth, Jason A. (Pocatello, ID); Phelps, Larry D. (Pocatello, ID); Taylor, Steven C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

255

Elbow mass flow meter  

DOE Patents (OSTI)

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

1994-01-01T23:59:59.000Z

256

Low-temperature oriented growth of vanadium dioxide films on CoCrTa metal template on Si and vertical metal-insulator transition  

SciTech Connect

The authors achieved oriented growth of vanadium dioxide (VO{sub 2}) films on CoCrTa metal template grown on an Si substrate. Low-temperature ({approx}250 Degree-Sign C) deposition of VO{sub 2} films using inductively coupled-plasma-assisted sputtering technique realized an abrupt interface between VO{sub 2} and CoCrTa layers, suppressing the oxidation and diffusion of metal components. The films revealed a metal-insulator transition with resistance change of over 2 orders of magnitude. The CoCrTa film, in which Co hexagonal crystalline grains with c-axis orientation were surrounded by segregated Cr and Ta, serves for the oriented growth of VO{sub 2} crystalline film, enabling higher orders of transition in resistance and low voltage switching, even for the vertical (out-of-plane) direction.

Okimura, Kunio; Mian, Md.Suruz [School of Engineering, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan)

2012-09-15T23:59:59.000Z

257

Thermodynamic Analysis of Syngas Production via the Solar Thermochemical Cerium Oxide Redox Cycle with Methane-Driven Reduction  

Science Journals Connector (OSTI)

Thermodynamic Analysis of Syngas Production via the Solar Thermochemical Cerium Oxide Redox Cycle with Methane-Driven Reduction ... Of particular interest is the storage of solar energy in chemical bonds via the splitting of water and carbon dioxide to produce hydrogen and carbon monoxide, referred to collectively as syngas. ... The coupled cycle produces high-quality syngas by the partial oxidation of methane in the ceria reduction step in addition to the carbon monoxide and hydrogen produced by splitting carbon dioxide and water in the oxidation step. ...

Peter T. Krenzke; Jane H. Davidson

2014-05-16T23:59:59.000Z

258

A New Approach to Computing Max Flows using Electrical Flows  

E-Print Network (OSTI)

A New Approach to Computing Max Flows using Electrical Flows Yin Tat Lee (MIT) Satish Rao (UC-Kelner-Madry-Spielman-Teng'11]: approximate flow in time Uses electrical flows. 7 #12;Electrical Flows 3 1 S t 8 #12;Electrical Flows Identify Graph with Resistor Network R(e)=1/w(e) 1/3 S t 1 9 #12;Electrical Flows Electrical flow

Rajamani, Sriram K.

259

Low flow fume hood  

DOE Patents (OSTI)

A fume hood is provided having an adequate level of safety while reducing the amount of air exhausted from the hood. A displacement flow fume hood works on the principal of a displacement flow which displaces the volume currently present in the hood using a push-pull system. The displacement flow includes a plurality of air supplies which provide fresh air, preferably having laminar flow, to the fume hood. The displacement flow fume hood also includes an air exhaust which pulls air from the work chamber in a minimally turbulent manner. As the displacement flow produces a substantially consistent and minimally turbulent flow in the hood, inconsistent flow patterns associated with contaminant escape from the hood are minimized. The displacement flow fume hood largely reduces the need to exhaust large amounts of air from the hood. It has been shown that exhaust air flow reductions of up to 70% are possible without a decrease in the hood's containment performance. The fume hood also includes a number of structural adaptations which facilitate consistent and minimally turbulent flow within a fume hood.

Bell, Geoffrey C. (Pleasant Hill, CA); Feustel, Helmut E. (Albany, CA); Dickerhoff, Darryl J. (Berkeley, CA)

2002-01-01T23:59:59.000Z

260

Zirconium vanadium chromium alloy  

DOE Patents (OSTI)

A ternary intermetallic compound having the formula Zr(V/sub 1-x/Cr/sub x/)/sub 2/ where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200/sup 0/C, at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

Mendelsohn, M.H.; Gruen, D.M.

1980-10-14T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

FLOW CONDITIONING DESIGN IN TURBULENT  

E-Print Network (OSTI)

for HYLIFE-II · Measure loss coefficient across the flow conditioner / nozzle assembly for different flow conditioner configurations #12;5 Flow Loop A Pump H 400 gal tank B Bypass line I Butterfly valve C Flow meter

262

Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells  

SciTech Connect

A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

2011-12-11T23:59:59.000Z

263

ESS 2012 Peer Review - Advanced Materials for Flow Batteries - Travis Anderson, SNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Materials for Advanced Materials for Flow Batteries Friday, September 28, 2012 Travis M. Anderson and Harry D. Pratt III Sandia National Laboratories Ionic Liquid Flow Batteries MetIL - + MetIL * 59 mV/n separation (ideally n > 1) * Viscosity < 500 cP * Conductivity > 0.5 mS cm -1 * Open Circuit Potential > 1.5 V Problem: Getting high concentrations of redox active species. MetILs * Transition Metal Cation * Weakly Coordinating Anions * Alkanolamine Ligands * Negligible Vapor Pressure * Non-toxic 2 FY12 Milestones Approach: Design electrolytes with charge storage species as part of their chemical composition. Energy Density/Costs SNL APPROACH: Consider a compound CuL 2 BF 4 (L = methanolamine, MW = 47 g/mol), measured density 1.6 g/mL, formula weight,

264

Turbulent flow in graphene  

E-Print Network (OSTI)

We demonstrate the possibility of a turbulent flow of electrons in graphene in the hydrodynamic region, by calculating the corresponding turbulent probability density function. This is used to calculate the contribution of the turbulent flow to the conductivity within a quantum Boltzmann approach. The dependence of the conductivity on the system parameters arising from the turbulent flow is very different from that due to scattering.

Kumar S. Gupta; Siddhartha Sen

2009-11-03T23:59:59.000Z

265

Muffler Theory Considering Flow  

Science Journals Connector (OSTI)

The effect of a steady subsonic flow component upon the acoustical properties of pipes and of laminar and turbulent flow resistances is accounted for in an elementary fashion. The effect of the alternating or acoustic component upon the steady?flow properties is treated likewise. Acoustic transmission loss referred to the end radiation from a pipe is related to back pressure (increase in steady pressure due to the muffler). Equivalent circuits and diagrams of transmission loss vs back pressure are presented for some simple arrangements of pipes volumes irises and flow resistances.

Ewald Eichler

1962-01-01T23:59:59.000Z

266

Strong reduction of V{sup 4+} amount in vanadium oxide/hexadecylamine nanotubes by doping with Co{sup 2+} and Ni{sup 2+} ions: Electron paramagnetic resonance and magnetic studies  

SciTech Connect

In this work we present a complete characterization and magnetic study of vanadium oxide/hexadecylamine nanotubes (VO{sub x}/Hexa NT's) doped with Co{sup 2+} and Ni{sup 2+} ions. The morphology of the NT's has been characterized by transmission electron microscopy, while the metallic elements have been quantified by the instrumental neutron activation analysis technique. The static and dynamic magnetic properties were studied by collecting data of magnetization as a function of magnetic field and temperature and by electron paramagnetic resonance. At difference of the majority reports in the literature, we do not observe magnetic dimers in vanadium oxide nanotubes. Also, we observed that the incorporation of metallic ions (Co{sup 2+}, S = 3/2 and Ni{sup 2+}, S = 1) decreases notably the amount of V{sup 4+} ions in the system, from 14-16% (nondoped case) to 2%-4%, with respect to the total vanadium atoms (fact corroborated by XPS experiments) anyway preserving the tubular nanostructure. The method to decrease the amount of V{sup 4+} in the nanotubes improves considerably their potential technological applications as Li-ion batteries cathodes.

Saleta, M. E.; Troiani, H. E.; Ribeiro Guevara, S.; Ruano, G.; Sanchez, R. D. [Centro Atomico Bariloche, CNEA, (8400) S. C. de Bariloche (Argentina); Malta, M. [Depto. de Cs. Exatas e da Terra, Univ. do Estado da Bahia, Cabula Salvador CP 2555 (Brazil); Torresi, R. M. [Instituto de Quimica, Universidad de Sao Paulo, Sao Paulo CP 26077, 05513-970 (Brazil)

2011-05-01T23:59:59.000Z

267

Elbow mass flow meter  

DOE Patents (OSTI)

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16T23:59:59.000Z

268

Instream Flow Project  

Energy.gov (U.S. Department of Energy (DOE))

As a part of the Department of Energy’s Water Power Program, the Instream Flow Project was carried out by Oak Ridge National Laboratory, Pacific Northwest National Laboratory, and Argonne National Laboratory to develop tools aimed at defining environmental flow needs for hydropower operations.

269

Productivity & Energy Flow  

E-Print Network (OSTI)

1 Productivity & Energy Flow Ecosystem approach, focuses: on flow of energy, water, and nutrients (capture) of energy by autotrophs Gross (total) Net (total ­ costs) Secondary productivity- capture of energy by herbivores http://sciencebitz.com/?page_id=204 What Controls the Primary Productivity

Mitchell, Randall J.

270

Scalable High-Power Redox Capacitors with Aligned Nanoforests of Crystalline MnO2 Nanorods by High Voltage Electrophoretic Deposition  

Science Journals Connector (OSTI)

Scalable High-Power Redox Capacitors with Aligned Nanoforests of Crystalline MnO2 Nanorods by High Voltage Electrophoretic Deposition ... The scalable nanomanufacturing process is demonstrated by roll-printing an aligned forest of ?-MnO2 nanorods on a large flexible substrate (1 inch by 1 foot). ...

Sunand Santhanagopalan; Anirudh Balram; Dennis Desheng Meng

2013-02-01T23:59:59.000Z

271

Digital Deposition of Ultrathin Pd Films on Well-Defined Pt(111) Electrodes via Surface-Limited Redox Replacement Reaction: An Electron Spectroscopy-Electrochemistry Study  

E-Print Network (OSTI)

In this study, ultrathin (submonolayer to eight-monolayer) Pd films were deposited one layer at a time on well-defined Pt(111) surfaces via a process known as surface-limited redox replacement reaction (SLR^3). In this digital-deposition method, one...

Hossain, Mohammad

2010-12-04T23:59:59.000Z

272

Solar Syngas Production via H2O/CO2-Splitting Thermochemical Cycles with Zn/ZnO and FeO/Fe3O4 Redox Reactions  

Science Journals Connector (OSTI)

Solar Syngas Production via H2O/CO2-Splitting Thermochemical Cycles with Zn/ZnO and FeO/Fe3O4 Redox Reactions† ... The first step, driven by concentrated solar radiation, is the endothermic thermolysis of ZnO producing a gaseous mixture of O2 and ... ...

A. Stamatiou; P. G. Loutzenhiser; A. Steinfeld

2009-08-28T23:59:59.000Z

273

Structural basis of inter-domain electron transfer in Ncb5or, a redox enzyme implicated in diabetes and lipid metabolism  

E-Print Network (OSTI)

NADH cytochrome b5 oxidoreductase (Ncb5or) is a multi-domain redox enzyme found in all animal tissues and associated with the endoplasmic reticulum (ER). Ncb5or contains (from N-terminus to C terminus) a novel N-terminal region, the b5 domain (Ncb5...

Deng, Bin

2011-12-31T23:59:59.000Z

274

Multiple Factors Affecting Cellular Redox Status and Energy Metabolism Modulate Hypoxia-Inducible Factor Prolyl Hydroxylase Activity In Vivo and In Vitro  

Science Journals Connector (OSTI)

...use of these cells allowed us to monitor GHO hydroxylation status without using proteasome inhibitors...found that MitoQ could not help us to distinguish between these...factors affecting cellular redox status and energy metabolism modulate hypoxia-inducible...

Yi Pan; Kyle D. Mansfield; Cara C. Bertozzi; Viktoriya Rudenko; Denise A. Chan; Amato J. Giaccia; M. Celeste Simon

2006-11-13T23:59:59.000Z

275

Elliptic flow phenomenon at ATLAS  

E-Print Network (OSTI)

We summarize measurements of elliptic flow and higher order flow harmonics performed by the ATLAS experiment at the LHC. Results on event-averaged flow measurements and event-plane correlations in Pb+Pb collisions are discussed along with the event-by-event flow measurements. Further, we summarize results on flow in p+Pb collisions.

Martin Spousta

2014-06-20T23:59:59.000Z

276

Electron Flow in Multiheme Bacterial Cytochromes is a Balancing...  

NLE Websites -- All DOE Office Websites (Extended Search)

cofactors in the recently crystallized outer membrane cytochrome MtrF. The combination of electronic coupling matrix elements with free energy calculations of heme redox potentials...

277

Hydrogen Production via Chemical Looping Redox Cycles Using Atomic Layer Deposition-Synthesized Iron Oxide and Cobalt Ferrites  

Science Journals Connector (OSTI)

Hydrogen Production via Chemical Looping Redox Cycles Using Atomic Layer Deposition-Synthesized Iron Oxide and Cobalt Ferrites ... Unlike solution and line-of-sight methods used to synthesize metal-substituted ferrites, including solution combustion synthesis,(6) aerial oxidation of aqueous suspensions,(5) sol?gel process,(8) laser molecular beam epitaxy,(21) sputtering,(22) and chemical vapor deposition (CVD),(23) ALD can produce conformal thin films on porous materials. ... The drop in peak H2 production rate is accompanied by a ?55% decrease in the total amount of H2 produced (see Table 1) and a similar decrease in the time required to achieve 95% conversion, suggesting a loss of accessible iron in this material. ...

Jonathan R. Scheffe; Mark D. Allendorf; Eric N. Coker; Benjamin W. Jacobs; Anthony H. McDaniel; Alan W. Weimer

2011-03-24T23:59:59.000Z

278

Redox cycle stability of mixed oxides used for hydrogen generation in the cyclic water gas shift process  

SciTech Connect

Graphical abstract: - Highlights: • Fe{sub 2}O{sub 3} modified with CaO, SiO{sub 2} and Al{sub 2}O{sub 3} was studied in cyclic water gas shift reactor. • For the first time stability of such oxides were tested for 100 redox cycles. • Optimally added oxides significantly improved the activity and the stability of Fe{sub 2}O{sub 3}. • Increased stability was attributed to the impediment of neck formation. - Abstract: Repeated cycles of the reduction of Fe{sub 3}O{sub 4} with reductive gas, e.g. hydrogen and subsequent oxidation of the reduced iron material with water vapor can be harnessed as a process for the production of pure hydrogen. The redox behavior of iron oxide modified with various amounts of SiO{sub 2}, CaO and Al{sub 2}O{sub 3} was investigated in the present study. The total amount of the additional metal oxides was always below 15 wt%. The samples were prepared by co-precipitation using urea hydrolysis method. The influence of various metal oxides on the hydrogen production capacity and the material stability was studied in detail in terms of temperature-programmed reduction (TPR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET analysis. Furthermore, the activity and the stability of the samples were tested in repeated reduction with diluted H{sub 2} and re-oxidation cycles with H{sub 2}O. The results indicate that combination of several oxides as promoter increases the stability of the iron oxide material by mitigating the sintering process. The positive influence of the oxides in stabilizing the iron oxide material is attributed to the impediment of neck formation responsible for sintering.

Datta, Pradyot, E-mail: pradyot.datta@gmail.com

2013-10-15T23:59:59.000Z

279

Controlled Assembly of Heterobinuclear Sites on Mesoporous Silica: Visible Light Charge-Transfer Units with Selectable Redox Properties  

SciTech Connect

Mild synthetic methods are demonstrated for the selective assembly of oxo-bridged heterobinuclear units of the type TiOCrIII, TiOCoII, and TiOCeIII on mesoporous silica support MCM-41. One method takes advantage of the higher acidity and, hence, higher reactivity of titanol compared to silanol OH groups towards CeIII or CoII precursor. The procedure avoids the customary use of strong base. The controlled assembly of the TiOCr system exploits the selective redox reactivity of one metal towards another (TiIII precursor reacting with anchored CrVI centers). The observed selectivity for linking a metal precursor to an already anchored partner versus formation of isolated centers ranges from a factor of six (TiOCe) to complete (TiOCr, TiOCo). Evidence for oxo bridges and determination of the coordination environment of each metal centers is based on K-edge EXAFS (TiOCr), L-edge absorption spectroscopy (Ce), and XANES measurements (Co, Cr). EPR, optical, FT-Raman and FT-IR spectroscopy furnish additional details on oxidation state and coordination environment of donor and acceptor metal centers. In the case of TiOCr, the integrity of the anchored group upon calcination (350 oC) and cycling of the Cr oxidation state is demonstrated. The binuclear units possess metal-to-metal charge-transfer transitions that absorb deep in the visible region. The flexible synthetic method for assembling the units opens up the use of visible light charge transfer pumps featuring donor or acceptor metals with selectable redox potential.

Frei, Heinz; Han, Hongxian; Frei, Heinz

2008-06-04T23:59:59.000Z

280

Multiphase Flow Modeling Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Science Chris Guenther, Director Computational Science Division RUA Spring Meeting, Morgantown, WV March 2013 2 NETL's Multiphase Flow Science Team * The Multiphase Flow Science Team develops physics-based simulation models to conduct applied scientific research. - Development of new theory - Extensive on-site and collaborative V&V efforts and testing - Engages in technology transfer - Applies the models to industrial scale problems. 3 Why is Multiphase Flow Science Needed? * Industry is increasingly relying on multiphase technologies to produce clean and affordable energy with carbon capture. * Unfortunately, the presence of a solid phase reduces the operating capacity of a typical energy device from its original design on average by 40% [1].

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Shroud leakage flow discouragers  

DOE Patents (OSTI)

A turbine assembly includes a plurality of rotor blades comprising a root portion, an airfoil having a pressure sidewall and a suction sidewall, and a top portion having a cap. An outer shroud is concentrically disposed about said rotor blades, said shroud in combination with said tip portions defining a clearance gap. At least one circumferential shroud leakage discourager is disposed within the shroud. The leakage discourager(s) increase the flow resistance and thus reduce the flow of hot gas flow leakage for a given pressure differential across the clearance gap to improve overall turbine efficiency.

Bailey, Jeremy Clyde (Middle Grove, NY); Bunker, Ronald Scott (Niskayuna, NY)

2002-01-01T23:59:59.000Z

282

Bypass Flow Study  

SciTech Connect

The purpose of the fluid dynamics experiments in the MIR (Matched Index of-Refraction) flow system at Idaho National Laboratory (INL) is to develop benchmark databases for the assessment of Computational Fluid Dynamics (CFD) solutions of the momentum equations, scalar mixing, and turbulence models for the flow ratios between coolant channels and bypass gaps in the interstitial regions of typical prismatic standard fuel element (SFE) or upper reflector block geometries of typical Modular High-temperature Gas-cooled Reactors (MHTGR) in the limiting case of negligible buoyancy and constant fluid properties. The experiments use Particle Image Velocimetry (PIV) to measure the velocity fields that will populate the bypass flow study database.

Richard Schultz

2011-09-01T23:59:59.000Z

283

Magnetically stimulated fluid flow patterns  

ScienceCinema (OSTI)

Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

Martin, Jim; Solis, Kyle

2014-08-06T23:59:59.000Z

284

Elementary steps of the catalytic NO{sub x} reduction with NH{sub 3}: Cluster studies on reaction paths and energetics at vanadium oxide substrate  

SciTech Connect

We consider different reaction scenarios of the selective catalytic reduction (SCR) of NO in the presence of ammonia at perfect as well as reduced vanadium oxide surfaces modeled by V{sub 2}O{sub 5}(010) without and with oxygen vacancies. Geometric and energetic details as well as reaction paths are evaluated using extended cluster models together with density-functional theory. Based on earlier work of adsorption, diffusion, and reaction of the different surface species participating in the SCR we confirm that at Brønsted acid sites (i.e., OH groups) of the perfect oxide surface nitrosamide, NH{sub 2}NO, forms a stable intermediate. Here adsorption of NH{sub 3} results in NH{sub 4} surface species which reacts with gas phase NO to produce the intermediate. Nitrosamide is also found as intermediate of the SCR near Lewis acid sites of the reduced oxide surface (i.e., near oxygen vacancies). However, here the adsorbed NH{sub 3} species is dehydrogenated to surface NH{sub 2} before it reacts with gas phase NO to produce the intermediate. The calculations suggest that reaction barriers for the SCR are overall higher near Brønsted acid sites of the perfect surface compared with Lewis acid sites of the reduced surface, examined for the first time in this work. The theoretical results are consistent with experimental findings and confirm the importance of surface reduction for the SCR process.

Gruber, M.; Hermann, K. [Inorganic Chemistry Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin (Germany)] [Inorganic Chemistry Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin (Germany)

2013-12-28T23:59:59.000Z

285

Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 10, July 1, 1995--September 31, 1995  

SciTech Connect

This document is the tenth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities focused on testing of additional modified and promoted catalysts and characterization of these materials. Attempts at improving the sensitivity of our GC based analytical systems were also made with some success. Methanol oxidation studies were initiated. These results are reported. Specific accomplishments include: (1) Methane oxidation testing of a suite of catalysts promoted with most of the first row transition metals was completed. Several of these materials produced low, difficult to quantify yields of formaldehyde. (2) Characterization of these materials by XRD and FTIR was performed with the goal of correlating activity and selectivity with catalyst properties. (3) We began to characterize catalysts prepared via modified synthesis methods designed to enhance acidity using TGA measurements of acetonitrile chemisorption and methanol dehydration to dimethyl ether as a test reaction. (4) A catalyst prepared in the presence of naphthalene methanol as a structural disrupter was tested for activity in methane oxidation. It was found that this material produced low yields of formaldehyde which were difficult to quantify. (5) Preparation of catalysts with no Bronsted acid sites. This was accomplished by replacement of exchangeable protons with potassium, and (6) Methanol oxidation studies were initiated to provide an indication of catalyst activity for decomposition of this desired product and as a method of characterizing the catalyst surface.

McCormick, R.L.

1995-12-07T23:59:59.000Z

286

RMOTC - Testing - Flow Assurance  

NLE Websites -- All DOE Office Websites (Extended Search)

Flow Assurance Flow Assurance RMOTC Flow Loop Facility Layout Notice: As of July 15th 2013, the Department of Energy announced the intent to sell Naval Petroleum Reserve Number 3 (NPR3). The sale of NPR-3 will also include the sale of all equipment and materials onsite. A decision has been made by the Department of Energy to complete testing at RMOTC by July 1st, 2014. RMOTC will complete testing in the coming year with the currently scheduled testing partners. For more information on the sale of NPR-3 and sale of RMOTC equipment and materials please join our mailing list here. Over a decade ago, RMOTC began cooperatively building a full-scale facility to test new flow assurance technology, mainly in the areas of hydrates and paraffins. Today, RMOTC's test facility consists of five individual loop

287

Holographic supersymmetric membrane flows  

Science Journals Connector (OSTI)

The M-theory lift of SU(3) ? U(1)R-invariant RG flow via a combinatorical use of the four-dimensional flow and 11-dimensional Einstein–Maxwell equations was found previously. By taking the three internal coordinates differently and preserving only the SU(3) symmetry from the CP2 space, we find a new 11-dimensional solution of the SU(3)-invariant RG flow interpolating from the SO(8)-invariant UV fixed point to the SU(3) ? U(1)R-invariant IR fixed point in four dimensions. We describe how the corresponding three-dimensional superconformal Chern–Simons matter theory deforms. By replacing the above CP2 space with the Einstein–Kahler twofold, we also find out a new 11-dimensional solution of the SU(2) ? U(1)-invariant RG flow connecting the above two fixed points in four dimensions.

Changhyun Ahn; Kyungsung Woo

2010-01-01T23:59:59.000Z

288

Optical flow switching  

E-Print Network (OSTI)

Present-day networks are being challenged by dramatic increases in bandwidth demand of emerging applications. We will explore a new transport, ldquooptical flow switchingrdquo, that will enable significant growth and ...

Chan, Vincent W. S.

289

Olefin Autoxidation in Flow  

E-Print Network (OSTI)

Handling hazardous multiphase reactions in flow brings not only safety advantages but also significantly improved performance, due to better mass transfer characteristics. In this paper, we present a continuous microreactor ...

Neuenschwander, Ulrich

290

Energy Storage Systems 2014 Peer Review Presentations - Session...  

Energy Savers (EERE)

in PNNL's Mixed Acid Redox Flow Battery Stack - David Reed, PNNL Redox Flow Battery Optimization - Tom Zawodzinski, ORNL Ionic Liquid Flow Battery - Travis Anderson, Sandia...

291

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry  

E-Print Network (OSTI)

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry using energy flow method Azimuthal angle distribution at Q2 >100 GeV2 Energy flow method.Ukleja on behalf of the ZEUS Collaboration #12; Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I

292

Two-phase flow studies  

SciTech Connect

The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow problems of relevance to the geothermal industry. An important feature of the facility is that it is dedicated to two-phase flow of a single substance (including evaporation and condensation) as opposed to the case of a two-component two-phase flow. This facility can be operated with horizontal or vertical test sections of constant diameter or with step changes in diameter to simulate a geothermal well profile.

Hanold, R.J.

1983-12-01T23:59:59.000Z

293

Evaluation of flow hood measurements for residential register flows  

SciTech Connect

Flow measurement at residential registers using flow hoods is becoming more common. These measurements are used to determine if the HVAC system is providing adequate comfort, appropriate flow over heat exchangers and in estimates of system energy losses. These HVAC system performance metrics are determined by using register measurements to find out if individual rooms are getting the correct airflow, and in estimates of total air handler flow and duct air leakage. The work discussed in this paper shows that commercially available flow hoods are poor at measuring flows in residential systems. There is also evidence in this and other studies that flow hoods can have significant errors even when used on the non-residential systems they were originally developed for. The measurement uncertainties arise from poor calibrations and the sensitivity of exiting flow hoods to non-uniformity of flows entering the device. The errors are usually large--on the order of 20% of measured flow, which is unacceptably high for most applications. Active flow hoods that have flow measurement devices that are insensitive to the entering airflow pattern were found to be clearly superior to commercially available flow hoods. In addition, it is clear that current calibration procedures for flow hoods may not take into account any field application problems and a new flow hood measurement standard should be developed to address this issue.

Walker, I.S.; Wray, C.P.; Dickerhoff, D.J.; Sherman, M.H.

2001-09-01T23:59:59.000Z

294

Flow Test | Open Energy Information  

Open Energy Info (EERE)

Flow Test Flow Test Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Flow Test Details Activities (38) Areas (33) Regions (1) NEPA(3) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Testing Techniques Parent Exploration Technique: Well Testing Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Flow tests provide information on permeability, recharge rates, reservoir pressures, fluid chemistry, and scaling. Thermal: Flow tests can measure temperature variations with time to estimate characteristics about the heat source. Dictionary.png Flow Test: Flow tests are typically conducted shortly after a well has been drilled to test its productivity. The well is opened and fluids are released, the

295

The effects of water radiolysis on local redox conditions in the Oklo, Gabon, natural fission reactors 10 and 16  

SciTech Connect

In an underground nuclear waste repository, the chemical behavior of some stored fission products and actinides depends on the redox conditions during their long-term evolution. In this respect, radiolysis is an important phenomenon which can significantly modify the local redox conditions. The Oklo natural fission zones are good examples where the effect of radiolysis can be deduced from a mineralogical and geochemical study. Zones 10 and 16 were studied because they are located at depth of 270 m in an area devoid of any recent water circulation and not subject to the effect of the lateritic alteration occurring elsewhere in this area. In zone 10, there is a marked evolution of the U-Pb-Fe-S mineralogy from the center to the periphery of the reactor zone. In the center, uraninite shows silicification and coffinitisation with the formation of galena and native lead; the PbO content of uraninite can be as much as 20 wt%. In the periphery of the reactor zone, some radiogenic lead is present as minimum (Pb{sub 3}O{sub 4}) and in Pb-bearing calcite. In the surrounding sandstones, hematite is widespread. In zone 16, the mineral paragenesis is generally comparable with that of zone 10 but with some differences. Galena is the only Pb-bearing mineral associated with uraninite crystals. The PbO content of uraninite is always <7 wt%. In the periphery of the alteration zone, barite partly replaces quartz. In the reactor zone, hematite is sometimes replaced by pyrite. In an area where the fission zone 10 is in contact with sandstones devoid of organic matter, H{sub 2}O-H{sub 2} {+-} CH{sub 4} inclusions were observed in healed microcracks in the detrital quartz grains. Based on microthermometric measurements, the salinity of the aqueous solution ranges from 0.2 to 18 wt% eq. NaCl. Raman analysis of the gas phase indicates that the hydrogen to oxygen ratio differs from an inclusion to the other. 41 refs., 15 figs., 3 tabs.

Savary, V.; Pagel, M. [CREGU and G.R. CNRS-CREGU, Vandoeuvre-les-Nancy (France)] [CREGU and G.R. CNRS-CREGU, Vandoeuvre-les-Nancy (France)

1997-11-01T23:59:59.000Z

296

Reduction of pertechnetate [Tc(VII)] by aqueous Fe(II) and the nature of solid phase redox products  

Science Journals Connector (OSTI)

The subsurface behaviour of 99Tc, a contaminant resulting from nuclear fuels reprocessing, is dependent on its valence (e.g., IV or VII). Abiotic reduction of soluble Tc(VII) by Fe(II)(aq) in pH 6–8 solutions was investigated under strictly anoxic conditions using an oxygen trap (<7.5 × 10?9 atm O2). The reduction kinetics were strongly pH dependent. Complete and rapid reduction of Tc(VII) to a precipitated Fe/Tc(IV) form was observed when 11 ?mol/L of Tc(VII) was reacted with 0.4 mmol/L Fe(II) at pH 7.0 and 8.0, while no significant reduction was observed over 1 month at pH 6.0. Experiments conducted at pH 7.0 with Fe(II)(aq) = 0.05–0.8 mmol/L further revealed that Tc(VII) reduction was a combination of homogeneous and heterogeneous reaction. Heterogeneous reduction predominated after approximately 0.01 mmol/L of Fe(II) was oxidized. The heterogeneous reaction was more rapid, and was catalyzed by Fe(II) that adsorbed to the Fe/Tc(IV) redox product. Wet chemical and Fe–X-ray absorption near edge spectroscopy measurements (XANES) showed that Fe(II) and Fe(III) were present in the Fe/Tc(IV) redox products after reaction termination. 57Fe-Mössbauer, extended X-ray adsorption fine structure (EXAFS), and transmission electron microscopy (TEM) measurements revealed that the Fe/Tc(IV) solid phase was poorly ordered and dominated by Fe(II)-containing ferrihydrite with minor magnetite. Tc(IV) exhibited homogeneous spatial distribution within the precipitates. According to Tc-EXAFS measurements and structural modeling, its molecular environment was consistent with an octahedral Tc(IV) dimer bound in bidentate edge-sharing mode to octahedral Fe(III) associated with surface or vacancy sites in ferrihydrite. The precipitate maintained Tc(IV)aq concentrations that were slightly below those in equilibrium with amorphous Tc(IV)O2·nH2O(s). The oxidation rate of sorbed Tc(IV) in the Fe/Tc precipitate was considerably slower than Tc(IV)O2·nH2O(s) as a result of its intraparticle/intragrain residence. Precipitates of this nature may form in anoxic sediments or groundwaters, and the intraparticle residence of sorbed/precipitated Tc(IV) may limit 99Tc remobilization upon the return of oxidizing conditions.

John M. Zachara; Steve M. Heald; Byong-Hun Jeon; Ravi K. Kukkadapu; Chongxuan Liu; James P. McKinley; Alice C. Dohnalkova; Dean A. Moore

2007-01-01T23:59:59.000Z

297

Electrocapturing flow cell  

DOE Patents (OSTI)

A flow cell for electrophoretically-assisted capturing analytes from a flow. The flow cell includes a specimen chamber, a first membrane, a second membrane, a first electrode chamber, and a second electrode chamber. The specimen chamber may have a sample inlet and a sample outlet. A first portion of the first membrane may be coupled to a first portion of the specimen chamber. A first portion of the second membrane may be coupled to a second portion of the specimen chamber. The first electrode chamber may be configured to accept a charge. A portion of the first electrode chamber may be coupled to a second portion of the first membrane. A second electrode chamber may be configured to accept an opposite charge. A portion of the second electrode chamber may be coupled to a second portion of the second membrane.

Morozov, Victor (Manassas, VA)

2011-04-05T23:59:59.000Z

298

Workshop on hypersonic flow  

SciTech Connect

An overview is given of research activity on the application of computational fluid dynamics (CDF) for hypersonic propulsion systems. After the initial consideration of the highly integrated nature of air-breathing hypersonic engines and airframe, attention is directed toward computations carried out for the components of the engine. A generic inlet configuration is considered in order to demonstrate the highly three dimensional viscous flow behavior occurring within rectangular inlets. Reacting flow computations for simple jet injection as well as for more complex combustion chambers are then discussed in order to show the capability of viscous finite rate chemical reaction computer simulations. Finally, the nozzle flow fields are demonstrated, showing the existence of complex shear layers and shock structure in the exhaust plume. The general issues associated with code validation as well as the specific issue associated with the use of CFD for design are discussed. A prognosis for the success of CFD in the design of future propulsion systems is offered.

Povinelli, L.A.

1990-01-01T23:59:59.000Z

299

Multiphase cooling flows  

E-Print Network (OSTI)

I discuss the multiphase nature of the intracluster medium whose neglect can lead to overestimates of the baryon fraction of clusters by up to a factor of two. The multiphase form of the cooling flow equations are derived and reduced to a simple form for a wide class of self-similar density distributions. It is shown that steady-state cooling flows are \\emph{not} consistent with all possible emissivity profiles which can therefore be used as a test of the theory. In combination, they provide strong constraints on the mass distribution within the cooling radius.

Peter A. Thomas

1996-08-20T23:59:59.000Z

300

Hierarchical 3D micro-/nano-V2O5 (vanadium pentoxide) spheres as cathode materials for high-energy and high-power lithium ion-batteries  

Science Journals Connector (OSTI)

Abstract We facilely fabricate hierarchical 3D microspheres consisting of 2D V2O5 (vanadium pentoxide) nanosheets by a low temperature hydrothermal method and use it to structure hierarchical 3D micro-/nano-LIBs (lithium ion batteries) cathode. This is a template-free and facile method easy for scale-up production of hierarchical 3D micro-/nano-structured V2O5 spheres beneficial for high performance \\{LIBs\\} applications. Such a facile method resulted hierarchical 3D micro-/nano-V2O5 possess many unique features good for LIBs: (1) 2D V2O5 nanosheets facilitate the Li+ diffusions and electron transports; (2) hierarchical 3D micro-/nano-cathode structure built up by V2O5 nanosheet spheres will lead to the close and sufficient contact between electrolytes and activate materials and at the same time will create buffer volume to accommodate the volume change during discharging/charging process; and (3) micro-scale V2O5 spheres are easy to result in high cell packing density beneficial for high power battery. As revealed by the experimental results, the micro-/nano-V2O5 electrode demonstrates high initial discharge and charge capacities with no irreversible loss, high rate capacities at different currents and long-lasting lifespan. The high-energy and high-power performances of the micro-/nano-V2O5 electrode is ascribed to the unique hierarchical micro-/nano-structure merits of V2O5 spheres as abovementioned. In view of the advantages of facile fabrication method and unique features of 3D micro-/nano-V2O5 spheres for high power and high energy LIB battery, it is of great significance to beneficially broaden the applications of high-energy and high-power \\{LIBs\\} with creating novel hierarchical micro-/nano-structured V2O5 cathode materials.

Hongwei Bai; Zhaoyang Liu; Darren Delai Sun; Siew Hwa Chan

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Brassinosteroid-induced CO{sub 2} assimilation is associated with increased stability of redox-sensitive photosynthetic enzymes in the chloroplasts in cucumber plants  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Activity of certain Calvin cycle enzymes and CO{sub 2} assimilation are induced by BRs. Black-Right-Pointing-Pointer BRs upregulate the activity of the ascorbate-glutathione cycle in the chloroplasts. Black-Right-Pointing-Pointer BRs increase the chloroplast thiol reduction state. Black-Right-Pointing-Pointer A BR-induced reducing environment increases the stability of photosynthetic enzymes. -- Abstract: Brassinosteroids (BRs) play important roles in plant growth, development, photosynthesis and stress tolerance; however, the mechanism underlying BR-enhanced photosynthesis is currently unclear. Here, we provide evidence that an increase in the BR level increased the quantum yield of PSII, activities of Rubisco activase (RCA) and fructose-1,6-bisphosphatase (FBPase), and CO{sub 2} assimilation. BRs upregulated the transcript levels of genes and activity of enzymes involved in the ascorbate-glutathione cycle in the chloroplasts, leading to an increased ratio of reduced (GSH) to oxidized (GSSG) glutathione in the chloroplasts. An increased GSH/GSSG ratio protected RCA from proteolytic digestion and increased the stability of redox-sensitive enzymes in the chloroplasts. These results strongly suggest that BRs are capable of regulating the glutathione redox state in the chloroplasts through the activation of the ascorbate-glutathione cycle. The resulting increase in the chloroplast thiol reduction state promotes CO{sub 2} assimilation, at least in part, by enhancing the stability and activity of redox-sensitive photosynthetic enzymes through post-translational modifications.

Jiang, Yu Ping; Cheng, Fei; Zhou, Yan Hong; Xia, Xiao Jian; Mao, Wei Hua; Shi, Kai [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China)] [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China); Chen, Zhi Xiang [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China) [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China); Department of Botany and Plant Pathology, Purdue University, West Lafayette, IN 47907-2054 (United States); Yu, Jing Quan, E-mail: jqyu@zju.edu.cn [Department of Horticulture, Zijingang Campus, Zhejiang University, Yuhangtang Road 866, Hangzhou 310058 (China); Key Laboratory of Horticultural Plants Growth, Development and Quality Improvement, Ministry of Agriculture of China, Yuhangtang Road 866, Hangzhou 310058 (China)

2012-09-28T23:59:59.000Z

302

The role of nanopores on U(VI) sorption and redox behavior in U(VI)-contaminated subsurface sediments  

SciTech Connect

Most reactive surfaces in clay-dominated sediments are present within nanopores (pores of nm dimension). The behavior of geological fluids and minerals in nanopores is significantly different from those in normal non-nanoporous environments. The effect of nanopore surfaces on U(VI) sorption/desorption and reduction is likely to be significant in clay-rich subsurface environments. Our research results from both model nanopore system and natural sediments from both model system (synthetic nanopore alumina) and sediments from the ORNL Field Research Center prove that U(VI) sorption on nanopore surfaces can be greatly enhanced by nanopore confinement environments. The results from the project provide advanced mechanistic, quantitative information on the physiochemical controls on uranium sorption and redox behavior in subsurface sediments. The influence of nanopore surfaces on coupled uranium sorption/desorption and reduction processes is significant in virtually all subsurface environments, because most reactive surfaces are in fact nanopore surfaces. The results will enhance transfer of our laboratory-based research to a major field research initiative where reductive uranium immobilization is being investigated. Our results will also provide the basic science for developing in-situ colloidal barrier of nanoporous alumina in support of environmental remediation and long term stewardship of DOE sites.

Xu, Huifang; Roden, Eric E.; Kemner, Kenneth M.; Jung, Hun-Bok; Konishi, Hiromi; Boyanov, Maxim; Sun, Yubing; Mishra, Bhoopesh

2013-10-16T23:59:59.000Z

303

Planetary heat flow measurements  

Science Journals Connector (OSTI)

...ESA's Rosetta mission towards comet Churyumov-Gerasimenko. It...Heat flow measurements on comets have a different motivation...penetrator is by no means limited to comets; it has also been tested in...measurement. Currently, a landing on Mercury within the framework...

2005-01-01T23:59:59.000Z

304

The Flow of Water  

Science Journals Connector (OSTI)

... for ice-covered streams become of very great importance wlieii a stream is required for hydroelectric power production. An appendix is attached of fifty - two well- selected problems relating ... The remaining chapters dealing with flow in pipes and channels and with centrifugal pumps and turbines call for no particular comment. It is of interest to find a chapter dealing ...

1927-12-31T23:59:59.000Z

305

ENERGY FLOWS CLIMATE CHANGE  

E-Print Network (OSTI)

absorption of solar radiation. #12;AEROSOLS AS SEEN FROM SPACE Fire plumes from southern Mexico transportedENERGY FLOWS FORCINGS CLIMATE CHANGE A REALLY TOUGH PROBLEM Stephen E. Schwartz, BNL, 7-20-11 www average temperature 15°C or 59°F #12;ATMOSPHERIC RADIATION Power per area Energy per time per area Unit

Schwartz, Stephen E.

306

US energy flow, 1991  

SciTech Connect

Trends in energy consumption and assessment of energy sources are discussed. Specific topics discussed include: energy flow charts; comparison of energy use with 1990 and earlier years; supply and demand of fossil fuels (oils, natural gas, coal); electrical supply and demand; and nuclear power.

Borg, I.Y.; Briggs, C.K.

1992-06-01T23:59:59.000Z

307

Self-Organized Network Flows  

E-Print Network (OSTI)

A model for traffic flow in street networks or material flows in supply networks is presented, that takes into account the conservation of cars or materials and other significant features of traffic flows such as jam formation, spillovers, and load-dependent transportation times. Furthermore, conflicts or coordination problems of intersecting or merging flows are considered as well. Making assumptions regarding the permeability of the intersection as a function of the conflicting flows and the queue lengths, we find self-organized oscillations in the flows similar to the operation of traffic lights.

Helbing, D; Lämmer, S; Helbing, Dirk; Siegmeier, Jan; L\\"{a}mmer, Stefan

2007-01-01T23:59:59.000Z

308

flow_loop.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

FLOW ASSURANCE TEST LOOP FLOW ASSURANCE TEST LOOP Objective O ver a decade ago, RMOTC began cooperatively building a full-scale facility to test new fl ow assurance technology, mainly in the areas of hydrates and paraffi ns. Today, RMOTC's test facility consists of fi ve individual loop sections, including chilling and heated pipe-in-pipe water sections, bare lines, and a mixing section. The facility was designed to represent typical deepwater production systems in order to simulate full-scale tests and apply the results to fl ow assurance fi eld applications and technology. The current facility design consists of a 6" x 3,600 maximum allowable operating pressure test pipeline in fi ve separate loops. The test loops begin and ter- minate at a central location just north

309

Structural power flow measurement  

SciTech Connect

Previous investigations of structural power flow through beam-like structures resulted in some unexplained anomalies in the calculated data. In order to develop structural power flow measurement as a viable technique for machine tool design, the causes of these anomalies needed to be found. Once found, techniques for eliminating the errors could be developed. Error sources were found in the experimental apparatus itself as well as in the instrumentation. Although flexural waves are the carriers of power in the experimental apparatus, at some frequencies longitudinal waves were excited which were picked up by the accelerometers and altered power measurements. Errors were found in the phase and gain response of the sensors and amplifiers used for measurement. A transfer function correction technique was employed to compensate for these instrumentation errors.

Falter, K.J.; Keltie, R.F.

1988-12-01T23:59:59.000Z

310

Modeling Turbulent Flow  

National Nuclear Security Administration (NNSA)

Turbulent Turbulent Flow with Implicit LES L.G. Margolin 1 Proceedings of the Joint Russian-American Five Laboratory Conference on Computational Mathematics/Physics 19-23 June, 2005 Vienna, Austria 1 Applied Physics Division, Los Alamos National Laboratory, Los Alamos, NM 87545, len@lanl.gov 1 Abstract Implicit large eddy simulation (ILES) is a methodology for modeling high Reynolds' num- ber flows that combines computational efficiency and ease of implementation with predictive calculations and flexible application. Although ILES has been used for more than fifteen years, it is only recently that significant effort has gone into providing a physical rationale that speaks to its capabilities and its limitations. In this talk, we will present new theoret- ical results aimed toward building a justification and discuss some remaining gaps in our understanding and our practical

311

Neutrino Factory Mercury Flow Loop  

E-Print Network (OSTI)

Neutrino Factory Mercury Flow Loop V. GravesV. Graves C. Caldwell IDS-NF Videoconference March 9, 2010 #12;Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94 2 liter/min 24 9 gpm)mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment showed that a pump

McDonald, Kirk

312

Orifice flow measurement uncertainty  

SciTech Connect

A computer program is now available from Union Carbide that evaluates the total flow uncertainty of orifice flowmeter systems. Tolerance values for every component in the system and the sensitivity of the measured flowrate to each component can be established using historical data and published hardware specifications. Knowing the tolerance and sensitivity values, a total measurement uncertainty can be estimated with a 95% confidence level. This computer program provides a powerful design tool to ensure correct component matching and total metering system optimization.

Samples, C.R.

1984-04-01T23:59:59.000Z

313

Convective heat flow probe  

DOE Patents (OSTI)

A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

Dunn, J.C.; Hardee, H.C.; Striker, R.P.

1984-01-09T23:59:59.000Z

314

Numerical Investigations of Magnetohydrodynamic Hypersonic Flows.  

E-Print Network (OSTI)

??Numerical simulations of magnetohydrodynamic (MHD) hypersonic flow are presented for both laminar and turbulent flow over a cylinder and flow entering a scramjet inlet. ANSYS… (more)

Guarendi, Andrew N

2013-01-01T23:59:59.000Z

315

Spectroscopic study of a Cu/CeO{sub 2} catalyst subjected to redox treatments in carbon monoxide and oxygen  

SciTech Connect

Redox processes induced by interaction of a calcined Cu/CeO{sub 2} catalyst with CO and reoxidation with O{sub 2} have been investigated by CO-TPR, EPR, FTIR of adsorbed CO, and XPS. The initial calcined samples shows the presence of dispersed Cu{sup 2+} species, which give rise in the EPR spectrum to signals due to isolated entities, a somewhat more aggregated Cu{sup 2+}-containing phase, and copper ionic pairs, in coexistence with an EPR-silent CuO-type phase, revealed by XPS. A significant reduction of copper is produced already by contact with CO at room temperature, EPR results suggesting that reducibility of Cu{sup 2+} species decreases with their aggregation degree. Simultaneously, the ceria surface is also reduced by this interaction, copper acting as a strong promoter of this process. A singular consequence of the synergistic reduction of both components is observed by subjecting the catalyst to CO at T{sub r} {ge} 473 K, at which the CO adsorption capability of copper is apparently suppressed, in view of the absence of copper carbonyls in the FTIR spectrum. This is attributed to the establishment of electronic interactions between reduced ceria and small metallic copper particles generated by the reduction process. Contact of the CO-reduced sample with O{sub 2} at room or higher temperature produces an important reoxidation of both copper and ceria, revealed by FTIR and EPR. The synergetic effects between copper and ceria in the reduction process and the easy reoxidation of deeply reduced ceria are thought to be crucial to explaining the high catalytic activity shown by this system for CO oxidation.

Martinez-Arias, A.; Fernandez-Garcia, M.; Soria, J.; Conesa, J.C. [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica] [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica

1999-03-10T23:59:59.000Z

316

Status of cross-section data for gas production from vanadium and {sup 26}AL from silicon carbide in a D-T fusion reactor.  

SciTech Connect

Current designs of fusion-reactor systems seek to use radiation-resistant, low-activation materials that support long service lifetimes and minimize radioactive-waste problems after decommissioning. Reliable assessment of fusion materials performance requires accurate neutron-reaction cross sections and radioactive-decay constants. The problem areas usually involve cross sections since decay parameters tend to be better known. The present study was motivated by two specific questions: (i) Why are the {sup 51}V(n,np){sup 50}Ti cross section values in the ENDF/B-VI library so large (a gas production issue)? (ii) How well known are the cross sections associated with producing 7.4 x 10{sup 5} y {sup 26}Al in silicon carbide by the process {sup 28}Si(n,np+d){sup 27} Al(n,2n){sup 26}Al (a long-lived radioactivity issue)? The energy range 14-15 MeV of the D-T fusion neutrons is emphasized. Cross-section error bars are needed so that uncertainties in the gas and radioactivity generated over the lifetime of a reactor can be estimated. We address this issue by comparing values obtained from prominent evaluated cross-section libraries. Small differences between independent evaluations indicate that a physical quantity is well known while the opposite signals a problem. Hydrogen from {sup 51}V(n,p){sup 51}Ti and helium from {sup 51}V(n,{alpha}){sup 48}Sc are also important sources of gas in vanadium, so they too were examined. We conclude that {sup 51}V(n,p){sup 51}Ti is adequately known but {sup 51}V(n,np+d){sup 50}Ti is not. The status for helium generation data is quite good. Due to recent experimental work, {sup 27}Al(n,2n){sup 26}Al seems to be fairly well known. However, the situation for {sup 28}Si(n,np+d){sup 27}Al remains unsatisfactory.

Gomes, I. C.

1998-08-11T23:59:59.000Z

317

Attractor Flows from Defect Lines  

E-Print Network (OSTI)

Deforming a two dimensional conformal field theory on one side of a trivial defect line gives rise to a defect separating the original theory from its deformation. The Casimir force between these defects and other defect lines or boundaries is used to construct flows on bulk moduli spaces of CFTs. It turns out, that these flows are constant reparametrizations of gradient flows of the g-functions of the chosen defect or boundary condition. The special flows associated to supersymmetric boundary conditions in N=(2,2) superconformal field theories agree with the attractor flows studied in the context of black holes in N=2 supergravity.

Ilka Brunner; Daniel Roggenkamp

2010-02-12T23:59:59.000Z

318

This  

NLE Websites -- All DOE Office Websites (Extended Search)

Vanadium and chromium redox behavior in borosilicate nuclear waste glasses D.A. McKeown , I.S. Muller, H. Gan, Z. Feng, Carol Viragh, I.L. Pegg Vitreous State Laboratory,...

319

UZ Flow Models and Submodels  

SciTech Connect

The purpose of this report is to document the unsaturated zone (UZ) flow models and submodels, as well as the flow fields that have been generated using the UZ flow model(s) of Yucca Mountain, Nevada. In this report, the term ''UZ model'' refers to the UZ flow model and the several submodels, which include tracer transport, temperature or ambient geothermal, pneumatic or gas flow, and geochemistry (chloride, calcite, and strontium) submodels. The term UZ flow model refers to the three-dimensional models used for calibration and simulation of UZ flow fields. This work was planned in the ''Technical Work Plan (TWP) for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.7). The table of included Features, Events, and Processes (FEPs), Table 6.2-11, is different from the list of included FEPs assigned to this report in the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Table 2.1.5-1), as discussed in Section 6.2.6. The UZ model has revised, updated, and enhanced the previous UZ model (BSC 2001 [DIRS 158726]) by incorporating the repository design with new grids, recalibration of property sets, and more comprehensive validation effort. The flow fields describe fracture-fracture, matrix-matrix, and fracture-matrix liquid flow rates, and their spatial distributions as well as moisture conditions in the UZ system. These three-dimensional UZ flow fields are used directly by Total System Performance Assessment (TSPA). The model and submodels evaluate important hydrogeologic processes in the UZ as well as geochemistry and geothermal conditions. These provide the necessary framework to test hypotheses of flow and transport at different scales, and predict flow and transport behavior under a variety of climatic conditions. In addition, the limitations of the UZ model are discussed in Section 8.11.

Y. Wu

2004-11-01T23:59:59.000Z

320

Similarity of the Surface Reactivity of Hydrous Ferric Oxide and Hematite: Sorption and Redox of U(VI) and Fe(II)  

SciTech Connect

Hydrous Ferric Oxide (HFO) vs. Hematite--Thermodynamically distinctive bulk phases, but the surfaces could be similar due to hydration of the interface. Hypothesis--The surface of HFO is energetically similar to the surface of hematite. Objective--Compare the reactions of HFO and hematite with U(VI) and Fe(II). Experimental--The reactions of interests were (1) preparation of sub-micron hematite, (2) sorption of U(VI), and (3) redox of U(VI) and Fe(II) with HFO or hematite.

Je-Hun Jang; Dempsey, Brian A.; Burgos, William D.; Yeh, George; Roden, Eric

2004-03-17T23:59:59.000Z

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321

Reversible Three-Electron Redox Behaviors of FeF3 Nanocrystals as High-Capacity Cathode-Active Materials for Li-Ion Batteries  

Science Journals Connector (OSTI)

Reversible Three-Electron Redox Behaviors of FeF3 Nanocrystals as High-Capacity Cathode-Active Materials for Li-Ion Batteries ... Three types of FeF3 nanocrystals were synthesized by different chemical routes and investigated as a cathode-active material for rechargeable lithium batteries. ... (1-3) Though many types of metal oxides and phosphates have been tested as alternative cathode materials,(4, 5) no real breakthrough has been achieved in capacity, especially for intercalation cathodes, the capacity-determining electrode in the present LIBs systems. ...

Ting Li; Lei Li; Yu L. Cao; Xin P. Ai; Han X. Yang

2010-01-28T23:59:59.000Z

322

Annular flow diverter valve  

DOE Patents (OSTI)

A valve for diverting flow from the center of two concentric tubes to the annulus between the tubes or, operating in the reverse direction, for mixing fluids from concentric tubes into a common tube and for controlling the volume ratio of said flow consists of a toroidal baffle disposed in sliding engagement with the interior of the inner tube downstream of a plurality of ports in the inner tube, a plurality of gates in sliding engagement with the interior of the inner tube attached to the baffle for movement therewith, a servomotor having a bullet-shaped plug on the downstream end thereof, and drive rods connecting the servomotor to the toroidal baffle, the servomotor thereby being adapted to move the baffle into mating engagement with the bullet-shaped plug and simultaneously move the gates away from the ports in the inner tube and to move the baffle away from the bullet-shaped plug and simultaneously move the gates to cover the ports in the inner tube.

Rider, Robert L. (Walkersville, MD)

1980-01-01T23:59:59.000Z

323

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

1993-11-30T23:59:59.000Z

324

Fluid flow monitoring device  

DOE Patents (OSTI)

A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

McKay, Mark D. (1426 Socastee Dr., North Augusta, SC 29841); Sweeney, Chad E. (3600 Westhampton Dr., Martinez, GA 30907-3036); Spangler, Jr., B. Samuel (2715 Margate Dr., Augusta, GA 30909)

1993-01-01T23:59:59.000Z

325

Reduction of a Redox-Active Ligand Drives Switching in a Cu(I) Pseudorotaxane by a Bimolecular Mechanism  

SciTech Connect

The reduction of a redox-active ligand is shown to drive reversible switching of a Cu(I) [2]pseudorotaxane ([2]PR{sup 2+}) into the reduced [3]pseudorotaxane ([3]PR{sup 2+}) by a bimolecular mechanism. The unreduced pseudorotaxanes [2]PR{sup 2+} and [3]PR{sup 2+} are initially self-assembled from the binucleating ligand, 3,6-bis(5-methyl-2-pyridine)-1,2,4,5-tetrazine (Me2BPTZ), and a preformed copper-macrocycle moiety (Cu-M{sup 2+}) based on 1,10-phenanthroline. X-ray crystallography revealed a syn geometry of the [3]PR{sup 2+}. The UV-vis-NIR spectra show low-energy metal-to-ligand charge-transfer transitions that red shift from 808 nm for [2]PR{sup 2+} to 1088 nm for [3]PR{sup 2+}. Quantitative analysis of the UV-vis-NIR titration shows the stepwise formation constants to be K{sub 1} = 8.9 x 10{sup 8} M{sup -1} and K{sub 2} = 3.1 x 10{sup 6} M{sup -1}, indicative of negative cooperativity. The cyclic voltammetry (CV) and coulometry of Me{sub 2}BPTZ, [2]PR{sup 2+}, and [3]PR{sup 2+} shows the one-electron reductions at E{sub 1/2} = -0.96, -0.65, and -0.285 V, respectively, to be stabilized in a stepwise manner by each Cu{sup 2+} ion. CVs of [2]PR{sup 2+} show changes with scan rate consistent with an EC mechanism of supramolecular disproportionation after reduction: [2]PR{sup 0} + [2]PR{sup 2+} = [3]PR{sup 2+} + Me{sub 2}BPTZ{sup 0} (K*{sub D}, k{sub d}). UV-vis-NIR spectroelectrochemistry was used to confirm the 1:1 product stoichiometry for [3]PR{sup 2+}:Me{sub 2}BPTZ. The driving force ({Delta}G*{sub D} = -5.1 kcal mol{sup -1}) for the reaction is based on the enhanced stability of the reduced [3]PR{sup 2+} over reduced [2]PR{sup 0} by 365 mV (8.4 kcal mol{sup -1}). Digital simulations of the CVs are consistent with a bimolecular pathway (k{sub d} = 12,000 s{sup -1} M{sup -1}). Confirmation of the mechanism provides a basis to extend this new switching modality to molecular machines.

McNitt, Kristy A.; Parimal, Kumar; Share, Andrew I.; Fahrenbach, Albert C.; Witlicki, Edward H.; Pink, Maren; Bediako, D. Kwabena; Plaisier, Christina L.; Le, Nga; Heeringa, Lee P.; Vander Griend, Douglas A.; Flood, Amar H.; (Calvin); (Indiana)

2009-04-02T23:59:59.000Z

326

A New Model for Electron Flow for Sulfate Reduction in Desulfovibrio alaskensis G20  

SciTech Connect

To understand the energy conversion activities of the anaerobic sulfate-reducing bacteria, it is necessary to identify the components involved in electron flow. The importance of the abundant type I tetraheme cytochrome c3 (TpIc3) as an electron carrier during sulfate respiration was questioned by the previous isolation of a null mutation in the encoding gene, cycA, in Desulfovibrio alaskensis G20. Whereas respiratory growth of the CycA mutant with lactate and sulfate was little affected, growth with pyruvate and sulfate was significantly impaired. We have explored the phenotype of the CycA mutant through physiological tests and transcriptomic and proteomic analyses. Data reported here show that electrons from pyruvate oxidation do not reach adenylyl sulfate reductase, the enzyme catalyzing the first redox reaction during sulfate reduction, in the absence of either CycAor the type I cytochrome c3:menaquinone oxidoreductase, QrcABCD transmembrane complex. In contrast to the wild type, neither CycA and QrcA mutants do not grow with H2 or formate and sulfate as electron acceptor. Transcriptomic and proteomic analyses of the CycA mutant showed that transcripts and enzymes for the pathway from pyruvate to succinate were strongly decreased in the CycA mutant regardless of growth mode. Neither the CycA nor the QrcA mutant grew on fumarate alone, consistent with the omics results and a redox regulation of gene expression. We conclude that TpIc3 and the Qrc complex are essential D. alaskensis components for transfer of electrons released in the periplasm to reach the cytoplasmic adenylyl sulfate reductase and present a model that may explain the CycA phenotype through confurcation of electrons.

Keller, Kimberly L [University of Missouri, Columbia] [University of Missouri, Columbia; Rapp-Giles, Barbara J [University of Missouri, Columbia] [University of Missouri, Columbia; Semkiw, Elizabeth M. [University of Missouri] [University of Missouri; Porat, Iris [ORNL] [ORNL; Brown, Steven D [ORNL] [ORNL; Wall, Judy D. [University of Missouri] [University of Missouri

2013-01-01T23:59:59.000Z

327

New Model for Electron Flow for Sulfate Reduction in Desulfovibrio alaskensis G20  

SciTech Connect

To understand the energy conversion activities of the anaerobic sulfate-reducing bacteria, it is necessary to identify the components involved in electron flow. The importance of the abundant type I tetraheme cytochrome c3 (TpIc3) as an electron carrier during sulfate respiration was questioned by the previous isolation of a null mutation in the gene encoding TpIc3, cycA, in Desulfovibrio alaskensis G20. Whereas respiratory growth of the CycA mutant with lactate and sulfate was little affected, growth with pyruvate and sulfate was significantly impaired. We have explored the phenotype of the CycA mutant through physiological tests and transcriptomic and proteomic analyses. Data reported here show that electrons from pyruvate oxidation do not reach adenylyl sulfate reductase, the enzyme catalyzing the first redox reaction during sulfate reduction, in the absence of either CycA or the type I cytochrome c3:menaquinone oxidoreductase transmembrane complex, QrcABCD. In contrast to the wild type, the CycA and QrcA mutants did not grow with H2 or formate and sulfate as the electron acceptor. Transcriptomic and proteomic analyses of the CycA mutant showed that transcripts and enzymes for the pathway from pyruvate to succinate were strongly decreased in the CycA mutant regardless of the growth mode. Neither the CycA nor the QrcA mutant grew on fumarate alone, consistent with the omics results and a redox regulation of gene expression. We conclude that TpIc3 and the Qrc complex are D. alaskensis components essential for the transfer of electrons released in the periplasm to reach the cytoplasmic adenylyl sulfate reductase and present a model that may explain the CycA phenotype through confurcation of electrons.

Rapp-Giles, Barbara J [University of Missouri, Columbia] [University of Missouri, Columbia; Keller, Kimberly L [University of Missouri, Columbia] [University of Missouri, Columbia; Porat, Iris [ORNL] [ORNL; Brown, Steven D [ORNL] [ORNL; Semkiw, Elizabeth M. [University of Missouri] [University of Missouri; Wall, Judy D. [University of Missouri] [University of Missouri

2014-01-01T23:59:59.000Z

328

Active combustion flow modulation valve  

DOE Patents (OSTI)

A flow modulation valve has a slidably translating hollow armature with at least one energizable coil wound around and fixably attached to the hollow armature. The energizable coil or coils are influenced by at least one permanent magnet surrounding the hollow armature and supported by an outer casing. Lorentz forces on the energizable coils which are translated to the hollow armature, increase or decrease the flow area to provide flow throttling action. The extent of hollow armature translation depends on the value of current supplied and the direction of translation depends on the direction of current flow. The compact nature of the flow modulation valve combined with the high forces afforded by the actuator design provide a flow modulation valve which is highly responsive to high-rate input control signals.

Hensel, John Peter; Black, Nathaniel; Thorton, Jimmy Dean; Vipperman, Jeffrey Stuart; Lambeth, David N; Clark, William W

2013-09-24T23:59:59.000Z

329

Das Redox-Potential  

Science Journals Connector (OSTI)

Da jeder Oxydationsvorgang in der Weise abläuft, daß ein Oxydationsmittel von einem Reduktionsmittel reduziert wird, also jede Oxydation prinzipiell mit einer Reduktion gekoppelt ist, spricht man allgemeiner von

Prof. Dr. W. Heimann; Dr. K. Wisser

1965-01-01T23:59:59.000Z

330

Differential probes aid flow measurement  

SciTech Connect

Nonconstricting differential pressure flow probes which help solve the problems of clogging, wear, and pressure loss at the Seawater Filtration Facility in Saudi Arabia are described. Treated seawater is pumped into oil-bearing formations for secondary recovery. Figures showing principle of operation for probes, installation schematic and long-term accuracy results (flow probes vs. orifice meters) are presented. The new diamond-shaped design flow sensor offers accurate flow measurement with low permanent pressure loss, which translates into cost savings for the operator.

Mesnard, D.R.

1982-07-01T23:59:59.000Z

331

Module bay with directed flow  

DOE Patents (OSTI)

A module bay requires less cleanroom airflow. A shaped gas inlet passage can allow cleanroom air into the module bay with flow velocity preferentially directed toward contaminant rich portions of a processing module in the module bay. Preferential gas flow direction can more efficiently purge contaminants from appropriate portions of the module bay, allowing a reduced cleanroom air flow rate for contaminant removal. A shelf extending from an air inlet slit in one wall of a module bay can direct air flowing therethrough toward contaminant-rich portions of the module bay, such as a junction between a lid and base of a processing module.

Torczynski, John R. (Albuquerque, NM)

2001-02-27T23:59:59.000Z

332

UZ Flow Models and Submodels  

SciTech Connect

The purpose of this Model Report is to document the unsaturated zone (UZ) fluid flow and tracer transport models and submodels as well as the flow fields generated utilizing the UZ Flow and Transport Model of Yucca Mountain (UZ Model), Nevada. This work was planned in ''Technical Work Plan (TWP) for: Performance Assessment Unsaturated Zone'' (BSC 2002 [160819], Section 1.10, Work Package AUZM06). The UZ Model has revised, updated, and enhanced the previous UZ Flow Model REV 00 ICN 01 (BSC 2001 [158726]) by incorporation of the conceptual repository design with new grids, recalibration of property sets, and more comprehensive validation effort. The flow fields describe fracture-fracture, matrix-matrix, and fracture-matrix liquid flow rates and their spatial distributions as well as moisture conditions in the UZ system. These 3-D UZ flow fields are used directly by Performance Assessment (PA). The model and submodels evaluate important hydrogeologic processes in the UZ as well as geochemistry and geothermal conditions. These provide the necessary framework to test conceptual hypotheses of flow and transport at different scales and predict flow and transport behavior under a variety of climatic conditions. In addition, this Model Report supports several PA activities, including abstractions, particle-tracking transport simulations, and the UZ Radionuclide Transport Model.

P. Dixon

2004-02-11T23:59:59.000Z

333

Flow Batteries: A Historical Perspective  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Robert Savinell, Case Western Reserve University, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

334

Flow Relationships in Reverse Osmosis  

Science Journals Connector (OSTI)

Flow Relationships in Reverse Osmosis ... Effects of Hydrolysis on Cellulose Acetate Reverse-Osmosis Transport Coefficients ... Effects of Hydrolysis on Cellulose Acetate Reverse-Osmosis Transport Coefficients ...

Ulrich Merten

1963-08-01T23:59:59.000Z

335

Financing Program Implementation Process Flow  

Energy.gov (U.S. Department of Energy (DOE))

The implementation process flow for financing with two models: a generic option for primary markets and a conceptual option for secondary markets.

336

Comparative Study on Redox Properties of Nanosized CeO2 and CuO/Ce2 Under CO/O2  

SciTech Connect

Nanosized CeO{sub 2} and CuO/CeO{sub 2} samples, active for CO-PROX or related processes were comparatively examined by O{sub 2} probe electron paramagnetic resonance and in situ Raman and X-ray diffraction techniques. Their behavior toward CO reduction, as well as the oxygen-handling properties of the CO-reduced samples, was explored. An appreciable reduction of the ceria bulk was detected on treatment under CO at 473 K. On the basis of the analysis of the evolution of different oxygen-derived species (superoxide, peroxide, O-) on low-temperature (77-300 K) oxygen chemisorption on the CO-reduced samples, a general picture of the redox properties of the samples is presented. Results demonstrate that the presence of copper promotes completion of the redox cycle under CO/O{sub 2} by favoring both ceria reduction and oxidation. This can be relevant to explaining the remarkable oxidation activity and synergetic effects observed for catalysts combining CuO and CeO{sub 2}.

Martinez-Arias,A.; Gamarra, D.; Fernandez-Garcia, M.; Wang, X.; Hanson, J.; Rodriguez, J.

2006-01-01T23:59:59.000Z

337

Effects of the iron content and redox state on the structure of sodium borosilicate glasses: A Raman, Moessbauer and boron K-edge XANES spectroscopy study  

SciTech Connect

The structure of iron-bearing sodium borosilicate glasses with up to 10 mol% FeO has been investigated in the range 0.15 ? Fe{sup 3+}/SFe ? 0.95. According to Moessbauer spectroscopy, Fe{sup 3+} and Fe{sup 2+} are mainly in tetrahedral and octahedral coordination, respectively, although other coordination states exist for both cations. From XANES experiments, we conclude that increasing Fe content and varying redox states have only a minor effect on the relative proportions of BO{sub 3} and BO{sub 4} units. In Raman spectra, a decrease of the proportion of BO{sub 4} species present in danburite-like units (Na{sub 2}O.B{sub 2}O{sub 3}.2SiO{sub 2}) is found upon increasing iron content and oxidizing state. Whereas the insensitivity of the overall boron speciation to iron content and redox state points to weak interactions between boron and iron, the changes affecting BO{sub 4} species do indicate a more subtle interplay between Fe{sup 3+} and the other tetrahedrally coordinated cations (Si,B) because of the competition between tetrahedral Fe{sup 3+} and B{sup 3+} for charge compensation by Na{sup +}. (authors)

Cochain, B. [CEA, DEN, SECM, LDMC, Bagnols Sur Ceze, (France); IPGP-CNRS, Universite Paris 7, Sorbonne Paris Cite Paris, (France); Geology Department, University of Toronto, Toronto, (Canada); Neuville, D.R.; Richet, P. [Univ Paris 07, IPGP CNRS, Paris, (France); Henderson, G.S. [Univ Toronto, Dept Geol, Toronto, ON, (Canada); McCammon, C.A. [Univ Bayreuth, Bayer Geoinst, Bayreuth, (Germany)

2012-03-15T23:59:59.000Z

338

Crystal Structures of the Reduced, Sulfenic Acid, and Mixed Disulfide Forms of SarZ, a Redox Active Global Regulator in Staphylococcus aureus  

SciTech Connect

SarZ is a global transcriptional regulator that uses a single cysteine residue, Cys{sup 13}, to sense peroxide stress and control metabolic switching and virulence in Staphylococcus aureus. SarZ belongs to the single-cysteine class of OhrR-MgrA proteins that play key roles in oxidative resistance and virulence regulation in various bacteria. We present the crystal structures of the reduced form, sulfenic acid form, and mixed disulfide form of SarZ. Both the sulfenic acid and mixed disulfide forms are structurally characterized for the first time for this class of proteins. The Cys{sup 13} sulfenic acid modification is stabilized through two hydrogen bonds with surrounding residues, and the overall DNA-binding conformation is retained. A further reaction of the Cys{sup 13} sulfenic acid with an external thiol leads to formation of a mixed disulfide bond, which results in an allosteric change in the DNA-binding domains, disrupting DNA binding. Thus, the crystal structures of SarZ in three different states provide molecular level pictures delineating the mechanism by which this class of redox active regulators undergoes activation. These structures help to understand redox-mediated virulence regulation in S. aureus and activation of the MarR family proteins in general.

Poor, Catherine B.; Chen, Peng R.; Duguid, Erica; Rice, Phoebe A.; He, Chuan; (UC)

2010-01-20T23:59:59.000Z

339

Redox-sensitive structural change in the A-domain of HMGB1 and its implication for the binding to cisplatin modified DNA  

SciTech Connect

Highlights: •The structure of the oxidized A-domain of human HMGB1 was solved. •Phe38 ring was flipped in the oxidized structure from that in the reduced form. •The flipped ring disables the intercalation into the cisplatinated lesions. •The functionally relevant redox-dependent structural change was described. -- Abstract: HMGB1 (high-mobility group B1) is a ubiquitously expressed bifunctional protein that acts as a nuclear protein in cells and also as an inflammatory mediator in the extracellular space. HMGB1 changes its functions according to the redox states in both intra- and extra-cellular environments. Two cysteines, Cys23 and Cys45, in the A-domain of HMGB1 form a disulfide bond under oxidative conditions. The A-domain with the disulfide bond shows reduced affinity to cisplatin modified DNA. We have solved the oxidized A-domain structure by NMR. In the structure, Phe38 has a flipped ring orientation from that found in the reduced form; the phenyl ring in the reduced form intercalates into the platinated lesion in DNA. The phenyl ring orientation in the oxidized form is stabilized through intramolecular hydrophobic contacts. The reorientation of the Phe38 ring by the disulfide bond in the A-domain may explain the reduced HMGB1 binding affinity towards cisplatinated DNA.

Wang, Jing [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan)] [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Tochio, Naoya [Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)] [Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan); Takeuchi, Aya [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan)] [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Uewaki, Jun-ichi [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan) [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan); Kobayashi, Naohiro [Protein Research Institute, Osaka University, 3-2 Yamadaoka, Suita 565-0871 (Japan)] [Protein Research Institute, Osaka University, 3-2 Yamadaoka, Suita 565-0871 (Japan); Tate, Shin-ichi, E-mail: tate@hiroshima-u.ac.jp [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan) [Department of Mathematical and Life Sciences, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526 (Japan); Research Center for the Mathematics on Chromatin Live Dynamics (RcMcD), Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526 (Japan)

2013-11-29T23:59:59.000Z

340

Effect of flow fluctuations and nonflow on elliptic flow methods  

SciTech Connect

We discuss how the different estimates of elliptic flow are influenced by flow fluctuations and nonflow effects. It is explained why the event-plane method yields estimates between the two-particle correlation methods and the multiparticle correlation methods. It is argued that nonflow effects and fluctuations cannot be disentangled without other assumptions. However, we provide equations where, with reasonable assumptions about fluctuations and nonflow, all measured values of elliptic flow converge to a unique mean v_2,PP elliptic flow in the participant plane and, with a Gaussian assumption on eccentricity fluctuations, can be converted to the mean v_2,RP in the reaction plane. Thus, the 20percent spread in observed elliptic flow measurements from different analysis methods is no longer mysterious.

Ollitrault, Jean-Yves; Poskanzer, Arthur M.; Voloshin, Sergei A.

2009-04-16T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Capacitive and Solution Resistance Effects on Voltammetric Responses of a Thin Redox Layer Attached to Disk Microelectrodes  

Science Journals Connector (OSTI)

E*(r,t) is the effective potential across the interface between the metal conductor and its adjacent solution at the distance r from the electrode center: where E is the applied potential; di(r,?t) is the overall current through the elementary ring; dRe(r) is the resistance of the current tube associated with the same ring. ... It shows that the derivative of the overall current (with respect to time) flowing through an electrode surface element (being an infinitesimally thin ring for the disk electrode) is given by the difference between the increment of the capacitive current when the faradaic process is absent (dCdl(r)v) and that flowing (dicap(r,??t)) in the system, related to the elementary time constant (dRe(r)?dCdl(r)) of the surface element. ... Figure 4. Equivalent electric circuit. ...

Christian Amatore; Alexander Oleinick; Irina Svir

2008-10-01T23:59:59.000Z

342

What's Next for Vanadium Dioxide?  

NLE Websites -- All DOE Office Websites (Extended Search)

physicist Rudolf Peierls, that atomic vibrations and distortions trumped all. Now a team led by the Department of Energy's Oak Ridge National Laboratory (ORNL) has made an...

343

Cytology Automation by Flow Cytometry  

Science Journals Connector (OSTI)

...measured individually at rates of several hundred/sec...sured individually at rates of several hundred/sec...individually by flow cytometry at rates of several hundred/sec...flow cytometer (Bio/ Physics Systems Cytofluono graf...instrument and are made to pass through a 250-@rn-diameter...

Myron R. Melamed; Zbigniew Darzynkiewicz; Frank Traganos; and Thomas Sharpless

1977-08-01T23:59:59.000Z

344

Earth's Crust: Heat Flow Relationships  

Science Journals Connector (OSTI)

... of heat flow through the Earth's surface at any point requires two measurements, the geothermal gradient itself and the thermal conductivity of the adjacent rocks. In the oceanic crust, ... variations in heat flow from point to point are governed essentially by variations in the geothermal gradient. In continents, however, the story is different. Correlation and regression analyses carried ...

Our Geomagnetism Correspondent

1970-07-11T23:59:59.000Z

345

Flow Duration Curve Load Duration Curve  

E-Print Network (OSTI)

given flow and concentration data--select appropriate conversion factors 3. Develop Load Duration Curve 4. Plot observed data with Load Duration Curve #12;What are they? How do you make one? #12;DescribesRangeFlows LowFlows 40 % of the time there has been no flow at this site #12;Gather daily flow rate data Load

346

Main Title 32pt  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electroactive Ionic Liquids: Electroactive Ionic Liquids: A New Approach to Flow Batteries 2. Gallium Nitride Substrates for Power Electronics: Electrochemical Solution Growth Karen Waldrip, PhD Advanced Power Sources R&D Sandia National Labs, Albuquerque, NM knwaldr@sandia.gov Sandia National Laboratories' Programs Electroactive Ionic Liquids: A New Approach To Flow Batteries Date Travis Anderson David Ingersoll Chad Staiger Karen Waldrip Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Flow Batteries *No cross contamination *Flexible layout *High cycle life *Large, tunable capacity *Low maintenance vanadium redox couples are

347

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Hanford Site, USA  

SciTech Connect

Technetium is an important environmental contaminant introduced by the processing and disposal of irradiated nuclear fuel and atmospheric nuclear tests. Under oxic conditions technetium is soluble and exists as pertechnatate anion (TcO4-), while under anoxic conditions Tc is usually insoluble and exists as precipitated Tc(IV). Here we investigated abiotic Tc(VII) reduction in mineralogically heterogeneous, Fe(II)-containing sediments. The sediments were collected from a 55 m borehole that sampled a semi-confined aquifer at the Hanford Site, USA that contained a dramatic redox transition zone. One oxic facies (18.0-18.3 m) and five anoxic facies (18.3-18.6 m, 30.8-31.1 m, 39.0-39.3 m, 47.2-47.5 m and 51.5-51.8 m) were selected for this study. Chemical extractions, X-ray diffraction, electron microscopy, and Mössbauer spectroscopy were applied to characterize the Fe(II) mineral suite that included: Fe(II)-phyllosilicates, pyrite, magnetite and siderite. The Fe(II) mineral phase distribution differed between the sediments. Sediment suspensions were adjusted to the same 0.5 M HCl extracted Fe(II) concentration (0.6 mM) for Tc(VII) reduction experiments. Aqueous Fe was low in all sediment suspensions (<2 ?M) and below the Fe(II)aq detection limit (10 ?M). Technetium(VII) reduction occurred in all anoxic sediments at depths greater than 18.3 m and reaction time differed significantly between the sediments (8-219 d). Mössbauer analysis of the Tc-reacted, 30.8-31.1 m sediment confirmed that Tc(VII) was reduced by solid-phase Fe(II), with siderite and Fe(II)-containing phyllosilicates implicated as redox reactive phases. Technetium-XAS analysis demonstrated that Tc associated with sediments was in the Tc(IV) valence state and immobilized as clusters of a TcO2·nH2O-like phase. The speciation of redox product Tc(IV) was not affected by reduction rate or Fe(II) mineralogy.

Peretyazhko, Tetyana; Zachara, John M.; Kukkadapu, Ravi K.; Heald, Steve M.; Kutnyakov, Igor V.; Resch, Charles T.; Arey, Bruce W.; Wang, Chong M.; Kovarik, Libor; Phillips, Jerry L.; Moore, Dean A.

2012-09-01T23:59:59.000Z

348

The transition from two phase bubble flow to slug flow  

E-Print Network (OSTI)

The process of transition from bubble to slug flow in a vertical pipe has been studied analytically and experimentally. An equation is presented which gives the agglomeration time as a function of void fraction, channel ...

Radovcich, Nick A.

1962-01-01T23:59:59.000Z

349

Journal of the Geological Society, London, Vol. 168, 2011, pp. 805815. doi: 10.1144/0016-76492010-132. Hydrothermal origin of elevated iron, manganese and redox-sensitive trace  

E-Print Network (OSTI)

.1144/0016-76492010-132. 805 Hydrothermal origin of elevated iron, manganese and redox-sensitive trace elements in the c. 635 Ma Doushantuo cap carbonate JING HUANG1,2 , XUELEI CHU1,2 *, GANQING JIANG3 , LIANJUN FENG1 & HUAJIN, including REE, concentrations of the Doushantuo cap carbonate (c. 635 Ma) in South China show enrichment

Jiang, Ganqing

350

Gas flow characterization of restrictive flow orifice devices  

SciTech Connect

A restrictive flow orifice (RFO) can be used to limit the uncontrolled release of system media upon component or line failure in a gas handling system and can thereby enhance the system safety. This report describes a new RFO product available from the Swagelok Companies and specifies the gas flow characteristics of this device. A family of four different sizes of RFO devices is documented.

Shrouf, R.G. [Sandia National Labs., Albuquerque, NM (United States). Safety Engineering Dept.; Page, S.R. [Albuquerque Valve and Fitting Co., NM (United States)

1997-07-01T23:59:59.000Z

351

Proper planning improves flow drilling  

SciTech Connect

Underbalanced operations reduce formation damage, especially in horizontal wells where zones are exposed to mud for longer time periods. Benefits, risks, well control concerns, equipment and issues associated with these operations are addressed in this paper. Flow drilling raises many concerns, but little has been published on horizontal well control and flow drilling operations. This article covers planning considerations for flow drilling, but does not address horizontal ''overbalanced'' drilling because considerations and equipment are the same as in vertical overbalanced drilling and many references address that subject. The difference in well control between vertical and horizontal overbalanced drilling is fluid influx behavior and how that behavior affects kill operations.

Collins, G.J. (Marathon Oil Co., Houston, TX (United States))

1994-10-01T23:59:59.000Z

352

Zonal flow as pattern formation  

SciTech Connect

Zonal flows are well known to arise spontaneously out of turbulence. We show that for statistically averaged equations of the stochastically forced generalized Hasegawa-Mima model, steady-state zonal flows, and inhomogeneous turbulence fit into the framework of pattern formation. There are many implications. First, the wavelength of the zonal flows is not unique. Indeed, in an idealized, infinite system, any wavelength within a certain continuous band corresponds to a solution. Second, of these wavelengths, only those within a smaller subband are linearly stable. Unstable wavelengths must evolve to reach a stable wavelength; this process manifests as merging jets.

Parker, Jeffrey B.; Krommes, John A. [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States)

2013-10-15T23:59:59.000Z

353

Two phase flow in capillary tubes  

E-Print Network (OSTI)

The flow of two phases, gas and liquid, has been studied in horizontal tubes of capillary diameter. The flow has been primarily studied in the regime where the gas flows as long bubbles separated from the wall of the tube ...

Suo, Mikio

1963-01-01T23:59:59.000Z

354

Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer,...

355

The lattice Boltzmann method for complex flows.  

E-Print Network (OSTI)

??This thesis presents the extension of the lattice Boltzmann equation (LBE) to several well-known flows. First, the flow over a cylinder is studied using the… (more)

Reis, Tim

2007-01-01T23:59:59.000Z

356

COMMON SENSE REASONING ABOUT PETROLEUM FLOW  

E-Print Network (OSTI)

SENSE REASONING ABOUT . PETROLEUM FLOW Steven Rosenberg I 'Sense Reasoning about Petroleum Flow By Steven Rosenbergand reasoning in a petroleum resources domain. A basic model

Rosenberg, Steven

2014-01-01T23:59:59.000Z

357

Category:Flow Test | Open Energy Information  

Open Energy Info (EERE)

| Sign Up Search Category Edit History Facebook icon Twitter icon Category:Flow Test Jump to: navigation, search Geothermalpower.jpg Looking for the Flow Test page? For...

358

Acoustic concentration of particles in fluid flow  

SciTech Connect

An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

Ward, Michael D. (Los Alamos, NM); Kaduchak, Gregory (Los Alamos, NM)

2010-11-23T23:59:59.000Z

359

Acoustic Concentration Of Particles In Fluid Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. Available for thumbnail of...

360

Coal flows | OpenEI  

Open Energy Info (EERE)

Coal flows Coal flows Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 142, and contains only the reference case. The dataset uses million short tons. The data is broken down into steam coal exports to Europe, Asia and America. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords 2011 AEO Coal flows countries EIA exporting importing Data application/vnd.ms-excel icon AEO2011: World Steam Coal Flows By Importing Regions and Exporting Countries- Reference Case (xls, 103.7 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Multiscale modeling in granular flow  

E-Print Network (OSTI)

Granular materials are common in everyday experience, but have long-resisted a complete theoretical description. Here, we consider the regime of slow, dense granular flow, for which there is no general model, representing ...

Rycroft, Christopher Harley

2007-01-01T23:59:59.000Z

362

Studies of Flows in Plasmas  

SciTech Connect

Note a pdf document "DOE-flow-final-report' should be attached. If it somehow is not please notify Walter Gekelman (gekelman@physics.ucla.edu) who will e mail it directly

Gekelman, Walter; Morales, George; Maggs, James

2009-03-07T23:59:59.000Z

363

Fluid Flow Modeling in Fractures  

E-Print Network (OSTI)

In this paper we study fluid flow in fractures using numerical simulation and address the challenging issue of hydraulic property characterization in fractures. The methodology is based on Computational Fluid Dynamics, ...

Sarkar, Sudipta

2004-01-01T23:59:59.000Z

364

Capillary flows in flexible structures  

E-Print Network (OSTI)

Interactions between capillary and elastic effects are relevant to a variety of applications, from micro- and nano-scale manufacturing to biological systems. In this thesis, we investigate capillary flows in extremely ...

Hoberg, Theresa B. (Theresa Blinn)

2013-01-01T23:59:59.000Z

365

Flow assurance and multiphase pumping  

E-Print Network (OSTI)

. LITERATURE REVIEW???????????????????????????????????.. 5 Deepwater Oilfields???????????????????????????????????.. 7 Flow Assurance?????????????????????????????????????.. 9 Hydrate Management??????????????????????????????????. 11 Stranded Gas...???????????????????????????????????????.. 172 Management in Oil and Gas???????????????????????????????. 172 Constraints and Recent Advances????????????????????????????. 173 Optimization for Oilfield Management??????????????????????????. 174 Asset Management...

Nikhar, Hemant G.

2009-05-15T23:59:59.000Z

366

Energy flows, metabolism and translation  

Science Journals Connector (OSTI)

...L. , Pascal, R. 2011 Energy sources, self-organization...E. 1946 What's life. New York, NY: McMillan. 14 Lotka...nonequilibrium systems. New York, NY: Wiley. 17 Morowitz, H. , Smith, E. 2007 Energy flow and the organization...

2011-01-01T23:59:59.000Z

367

Equidistribution results for geodesic flows  

E-Print Network (OSTI)

Using the works of Ma\\~n\\'e \\cite{Ma} and Paternain \\cite{Pat} we study the distribution of geodesic arcs with respect to equilibrium states of the geodesic flow on a closed manifold, equipped with a $\\mathcal{C}^{\\infty}$ Riemannian metric. We prove large deviations lower and upper bounds and a contraction principle for the geodesic flow in the space of probability measures of the unit tangent bundle. We deduce a way of approximating equilibrium states for continuous potentials.

Abdelhamid Amroun

2011-09-15T23:59:59.000Z

368

Subcritical dynamos in shear flows  

E-Print Network (OSTI)

Identifying generic physical mechanisms responsible for the generation of magnetic fields and turbulence in differentially rotating flows is fundamental to understand the dynamics of astrophysical objects such as accretion disks and stars. In this paper, we discuss the concept of subcritical dynamo action and its hydrodynamic analogue exemplified by the process of nonlinear transition to turbulence in non-rotating wall-bounded shear flows. To illustrate this idea, we describe some recent results on nonlinear hydrodynamic transition to turbulence and nonlinear dynamo action in rotating shear flows pertaining to the problem of turbulent angular momentum transport in accretion disks. We argue that this concept is very generic and should be applicable to many astrophysical problems involving a shear flow and non-axisymmetric instabilities of shear-induced axisymmetric toroidal velocity or magnetic fields, such as Kelvin-Helmholtz, magnetorotational, Tayler or global magnetoshear instabilities. In the light of several recent numerical results, we finally suggest that, similarly to a standard linear instability, subcritical MHD dynamo processes in high-Reynolds number shear flows could act as a large-scale driving mechanism of turbulent flows that would in turn generate an independent small-scale dynamo.

F. Rincon; G. I. Ogilvie; M. R. E. Proctor; C. Cossu

2008-05-09T23:59:59.000Z

369

Pressure and flow characteristics of restrictive flow orifice devices.  

SciTech Connect

A Restrictive Flow Orifice (RFO) can be used to enhance the safe design of a pressure system in several ways. Pressure systems frequently incorporate a regulator and relief valve to protect the downstream equipment from accidental overpressure caused by regulator failure. Analysis frequently shows that in cases of high-flow regulator failure, the downstream pressure may rise significantly above the set pressure of the relief valve. This is due to limited flow capacity of the relief valve. A different regulator or relief valve may need to be selected. A more economical solution to this problem is to use an RFO to limit the maximum system flow to acceptable limits within the flow capacity of the relief valve, thereby enhancing the overpressure protection of laboratory equipment. An RFO can also be used to limit the uncontrolled release of system fluid (gas or liquid) upon component or line failure. As an example, potential asphyxiation hazards resultant from the release of large volumes of inert gas from a 'house' nitrogen system can be controlled by the use of an RFO. This report describes a versatile new Sandia-designed RFO available from the Swagelok Company and specifies the gas flow characteristics of this device. Two sizes, 0.010 and 0.020 inch diameter RFOs are available. These sizes will allow enhanced safety for many common applications. This new RFO design are now commercially available and provide advantages over existing RFOs: a high pressure rating (6600 psig); flow through the RFO is equal for either forward or reverse directions; they minimize the potential for leakage by incorporating the highest quality threaded connections; and can enhance the safety of pressure systems.

Shrouf, Roger D.

2003-06-01T23:59:59.000Z

370

SHORT-TUBE SUBCRITICAL FLOW Enerag Division  

E-Print Network (OSTI)

#12;SHORT-TUBE SUBCRITICAL FLOW Y. C. Mei Enerag Division Oak Ridge National Laboratory Oak Ridge-tube subcritical flow. For short tubes used as refrigerant expansion devices, the orifice model is found inadequate-TUBE SUBCRITICAL FLOW INTRODUCTION Much theoretical and experimental work regarding short tube fluid flow has

Oak Ridge National Laboratory

371

Microbial Adhesion in Flow Displacement Systems  

Science Journals Connector (OSTI)

...surface in flow displacement systems...in a flow displacement system contributes...substratum surface, is the...is the contact angle between...established parabolic flow between parallel plates. FIG. 9...more than half the length...and right: After addition...rectangular flow displacement systems Configuration...liquid surface tension...degrees) , contact angle between...wall shear stress (N m2...

Henk J. Busscher; Henny C. van der Mei

2006-01-01T23:59:59.000Z

372

Stochastic models for turbulent reacting flows  

SciTech Connect

The goal of this program is to develop and apply stochastic models of various processes occurring within turbulent reacting flows in order to identify the fundamental mechanisms governing these flows, to support experimental studies of these flows, and to further the development of comprehensive turbulent reacting flow models.

Kerstein, A. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

373

Mach flow angularity probes for scramjet engine flow path diagnostics  

SciTech Connect

Mach-flow angularity (MFA) probes were developed for use in scramjet flow path probe rakes. Prototype probes were fabricated to demonstrate the assembly processes (numerical control machining, furnace brazing, and electron beam welding). Tests of prototype probes confirmed the thermal durability margins and life cycle. Selected probes were calibrated in air at Mach numbers from 1.75 to 6.0. Acceptance criteria for the production probes stressed thermal durability and pressure (and, consequently, Mach number) measurement quality. This new water-cooled MFA probe has 0.397-cm shaft diameter and is capable of withstanding heat fluxes of 2.724 kW/sq cm.

Jalbert, P.A.; Hiers, R.S. Jr. [Sverdrup Technology, Inc., Arnold AFS, TN (United States)

1993-12-31T23:59:59.000Z

374

Renormalization Group and the Ricci flow  

E-Print Network (OSTI)

We discuss from a geometric point of view the connection between the renormalization group flow for non--linear sigma models and the Ricci flow. This offers new perspectives in providing a geometrical landscape for 2D quantum field theories. In particular we argue that the structure of Ricci flow singularities suggests a natural way for extending, beyond the weak coupling regime, the embedding of the Ricci flow into the renormalization group flow.

Mauro Carfora

2010-01-20T23:59:59.000Z

375

Mirrored serpentine flow channels for fuel cell  

DOE Patents (OSTI)

A PEM fuel cell having serpentine flow field channels wherein the input/inlet legs of each channel border the input/inlet legs of the next adjacent channels in the same flow field, and the output/exit legs of each channel border the output/exit legs of the next adjacent channels in the same flow field. The serpentine fuel flow channels may be longer, and may contain more medial legs, than the serpentine oxidant flow channels.

Rock, Jeffrey Allan (Rochester, NY)

2000-08-08T23:59:59.000Z

376

11 - Knowledge Flow in Universities  

Science Journals Connector (OSTI)

In this chapter, a typical American university is chosen as a model for the quantitative analysis for the flow of knowledge in a reasonably well-defined academic setting. Knowledge flow assumes quantifiable patterns and much like the flow and retention of rain water over a given terrain of land; the quality (of teaching) and quantity (number of credit hours) of knowledge retained by students is estimated on a qualitative and quantitative basis. The model presented in this chapter is entirely generic. It can be applied in any center of learning and during any period of training, residency in limited time frame, or even to the evolution of species as they gain survival skills, and build their knowledge potential to survive, another generation, calamity, meteor fall, a catastrophic disaster, or a global nuclear fall-out. Though the probability of outcome is not accurately known, it is still bounded by confidence limits.

Syed V. Ahamed

2014-01-01T23:59:59.000Z

377

Pressure compensated flow control valve  

DOE Patents (OSTI)

The invention is an air flow control valve which is capable of maintaining a constant flow at the outlet despite changes in the inlet or outlet pressure. The device consists of a shell assembly with an inlet chamber and outlet chamber separated by a separation plate. The chambers are connected by an orifice. Also located within the inlet chamber is a port controller assembly. The port controller assembly consists of a differential pressure plate and port cap affixed thereon. The cap is able to slide in and out of the orifice separating the inlet and outlet chambers. When the pressure differential is sufficient, the differential pressure plate rises or falls to maintain a constant air flow. Movement of the port controller assembly does not require the use of seals, diaphragms, tight tolerances, bushings, bearings, hinges, guides, or lubricants.

Minteer, Daniel J. (West Richland, WA)

1999-01-01T23:59:59.000Z

378

Flow optimization in diving helmets  

SciTech Connect

Improved carbon dioxide transport from the annular space between the head and helmet is necessary to reduce fresh gas flow and associated noise. This paper gives an overview of new techniques for investigating this transport, and for optimizing helmet flow to remove CO{sub 2}. An analytical model predicts inhaled carbon dioxide fraction in terms of helmet and respiration characteristics. Fundamental behavior over a wide range of helmet parameters is computed. An experimental model uses Reynolds scaling with water and dye to simulate fresh gas and carbon dioxide respectively. The water/dye model supports measurement of inhaled dye concentration, and flow visualization. Detailed behavior is investigated for one helmet with air/CO{sub 2} and water/dye experiments. Results support validity of the analytic and water models, provide new insight to CO{sub 2} transport mechanisms, and suggest directions for optimizing helmet design.

Camperman, J.M. [Naval Surface Warfare Center, Panama City, FL (United States). Coastal Systems Station; Tennant, J.S. [Florida Atlantic Univ., Boca Raton, FL (United States). Ocean Engineering Dept.

1996-09-01T23:59:59.000Z

379

ESS 2012 Peer Review - Flow Battery Solution for Smart Grid Renewable Energy Applications - Sheri Nevins, Raytheon & Ron Moss, EnerVault  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 1 Sheri Nevins Raytheon Ktech Ron Mosso EnerVault Corporation DEMONSTRATION OF ENERGY STORAGE USING A BREAKTHROUGH REDOX FLOW BATTERY TECHNOLOGY v. 1-0 Copyright ©2012, Raytheon Proprietary and EnerVault Corporation, All Rights Reserved. 2 Disclaimer This material is partially based upon work supported by NYSERDA under PON1200 Project 15880 NYSERDA has not reviewed the information contained herein, and the opinions expressed in this report do not necessarily reflect those of NYSERDA or the State of New York. This material is partially based upon work supported by the Department of Energy under Award Number DE-OE0000225. This report was prepared as an account of work sponsored by an agency of the United States

380

Rheo-optical determination of flow birefringence and flow dichroism with the pulsed laser method  

E-Print Network (OSTI)

Rheo-optical determination of flow birefringence and flow dichroism with the pulsed laser method online 29 August 2006 Rheo-optical measurements of the flow birefringence, flow dichroism systems under flow. However, the standard setup of an optical train, using phase modulation for the rheo-optical

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Nuclear reactor downcomer flow deflector  

DOE Patents (OSTI)

A nuclear reactor having a coolant flow deflector secured to a reactor core barrel in line with a coolant inlet nozzle. The flow deflector redirects incoming coolant down an annulus between the core barrel and the reactor vessel. The deflector has a main body with a front side facing the fluid inlet nozzle and a rear side facing the core barrel. The rear side of the main body has at least one protrusion secured to the core barrel so that a gap exists between the rear side of the main body adjacent the protrusion and the core barrel. Preferably, the protrusion is a relief that circumscribes the rear side of the main body.

Gilmore, Charles B. (Greensburg, PA); Altman, David A. (Pittsburgh, PA); Singleton, Norman R. (Murrysville, PA)

2011-02-15T23:59:59.000Z

382

Dynamo action in flows with  

E-Print Network (OSTI)

Dynamo action in flows with cat's eyes A l i c e C o u r v o i s i e r A n d r e w G i l b e r t Y of k for R = 500 and the flow (2.4) and (2.5). nts k = 2.5 and k = 5 are highlighted. Magnetic field). In (a) k = 2.5 and we have 0.5 max Bz (with max Bz 0.6 max |B|), and in (b) k = 5 and the levels .65 max

Li, Yi

383

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

384

Comments on "Microscale flow visualization"  

E-Print Network (OSTI)

We make comments on the presentation of Sinton's paper (Microfluidics and Nanofluidics {\\bf 1}: 2, 2004) about the microscale flow visualization since the effects of the roughness along the microfabricated wall upon the current macroflow visualization methods could be significant and cannot be neglected in microdomain and even nanodomain.

A. Kwang-Hua Chu

2005-10-22T23:59:59.000Z

385

Rinse trough with improved flow  

DOE Patents (OSTI)

Novel rinse troughs accomplish thorough uniform rinsing. The troughs are suitable for one or more essentially planar objects having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs provide uniform rinse fluid flow over the objects` surfaces to accomplish a more thorough rinse than prior art troughs. 5 figs.

O`Hern, T.J.; Grasser, T.W.

1998-08-11T23:59:59.000Z

386

Shear instabilities in granular flows  

Science Journals Connector (OSTI)

... of sizes were also tested, but these never produced interfacial waves under any conditions. Roughening either side wall by attaching sandpaper had a minimal effect on the flow, indicating ... to 28°. (The shear itself varied by less than 20%.) Second, we roughened the last 10?cm of the chute bottom, thus artificially retarding downstream particles and ...

David J. Goldfarb; Benjamin J. Glasser; Troy Shinbrot

2002-01-17T23:59:59.000Z

387

Superconducting flux flow digital circuits  

DOE Patents (OSTI)

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs) are disclosed. Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics. 8 figs.

Hietala, V.M.; Martens, J.S.; Zipperian, T.E.

1995-02-14T23:59:59.000Z

388

Data Flow Testing Neelam Gupta  

E-Print Network (OSTI)

Data Flow Testing Neelam Gupta The University of Arizona, Tucson, Arizona and Rajiv Gupta The University of Arizona, Tucson, Arizona Software testing techniques are designed to execute a program on a set of test cases that provide suÃ?cient coverage under some speci#12;c well-de#12;ned test coverage criterion

Gupta, Rajiv

389

Hydroplaning of subaqueous debris flows  

Science Journals Connector (OSTI)

...contiguous deposit of a subaqueous flow may be fringed by discrete parcels of debris that appear to have separated from the toe of the...can be introduced at the start of the channel either from a conveyor belt or from a head tank. With the head-tank configuration...

390

Thermodynamics of urban population flows  

Science Journals Connector (OSTI)

Orderliness, reflected via mathematical laws, is encountered in different frameworks involving social groups. Here we show that a thermodynamics can be constructed that macroscopically describes urban population flows. Microscopic dynamic equations and simulations with random walkers underlie the macroscopic approach. Our results might be regarded, via suitable analogies, as a step towards building an explicit social thermodynamics.

A. Hernando and A. Plastino

2012-12-05T23:59:59.000Z

391

Superconducting flux flow digital circuits  

DOE Patents (OSTI)

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs). Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics.

Hietala, Vincent M. (Placitas, NM); Martens, Jon S. (Sunnyvale, CA); Zipperian, Thomas E. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

392

Sedimentation Field Flow Fractionation: Applications  

Science Journals Connector (OSTI)

...FIELD-FLOW FRACTIONATION OF ALKALI-LIBERATED NUCLEAR POLYHEDROSIS-VIRUS FROM GYPSY-MOTH...FRACTIONATION TO RADIOACTIVE-WASTE DISPOSAL, NUCLEAR TECHNOLOGY 51 : 147 ( 1980 ). SOBER...perThe SFFF separation in Fig. 9a was ic dispersant moarbitrarily concluded shortly after...

J. J. Kirkland; W. W. Yau

1982-10-08T23:59:59.000Z

393

Effect of radial transport on compressor tip clearance flow structures and enhancement of stable flow range  

E-Print Network (OSTI)

The relation between tip clearance flow structure and axial compressor stall is interrogated via numerical simulations, to determine how casing treatment can result in improved flow range. Both geometry changes and flow ...

Nolan, Sean Patrick Rock

2005-01-01T23:59:59.000Z

394

A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow...  

Open Energy Info (EERE)

Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Jump to: navigation, search OpenEI Reference...

395

Liquid metal Flow Meter - Final Report  

SciTech Connect

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

396

Flow frictional characteristics of microencapsulated phase change material suspensions flowing through rectangular minichannels  

Science Journals Connector (OSTI)

An experimental investigation was conducted on the laminar flow frictional characteristics of suspensions with microencapsulated phase change material (MEPCM) in water flowing through rectangular...

Yu Rao; Frank Dammel; Peter Stephan…

2006-08-01T23:59:59.000Z

397

Characterization and Leach Testing for PUREX Cladding Waste Sludge (Group 3) and REDOX Cladding Waste Sludge (Group 4) Actual Waste Sample Composites  

SciTech Connect

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.(a) The testing program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual wastetesting program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. Two of the eight defined groups—plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR)—are the subjects of this report. Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, requiring caustic leaching. Characterization of the composite Group 3 and Group 4 waste samples confirmed them to be high in gibbsite. The focus of the Group 3 and 4 testing was on determining the behavior of gibbsite during caustic leaching. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

Snow, Lanee A.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Fiskum, Sandra K.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-02-13T23:59:59.000Z

398

Modulation of redox status and calcium handling by extremely low frequency electromagnetic fields in C2C12 muscle cells: A real-time, single-cell approach  

Science Journals Connector (OSTI)

The biological effects of electric and magnetic fields, which are ubiquitous in modern society, remain poorly understood. Here, we applied a single-cell approach to study the effects of short-term exposure to extremely low frequency electromagnetic fields (ELF-EMFs) on muscle cell differentiation and function using C2C12 cells as an in vitro model of the skeletal muscle phenotype. Our focus was on markers of oxidative stress and calcium (Ca2+) handling, two interrelated cellular processes previously shown to be affected by such radiation in other cell models. Collectively, our data reveal that ELF-EMFs (1) induced reactive oxygen species production in myoblasts and myotubes with a concomitant decrease in mitochondrial membrane potential; (2) activated the cellular detoxification system, increasing catalase and glutathione peroxidase activities; and (3) altered intracellular Ca2+homeostasis, increasing the spontaneous activity of myotubes and enhancing cellular reactivity to a depolarizing agent (KCl) or an agonist (caffeine) of intracellular store Ca2+channels. In conclusion, our data support a possible link between exposure to ELF-EMFs and modification of the cellular redox state, which could, in turn, increase the level of intracellular Ca2+and thus modulate the metabolic activity of C2C12 cells.

Caterina Morabito; Francesca Rovetta; Mariano Bizzarri; Giovanna Mazzoleni; Giorgio Fanò; Maria A. Mariggiò

2010-01-01T23:59:59.000Z

399

A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements  

Open Energy Info (EERE)

Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Details Activities (0) Areas (0) Regions (0) Abstract: A comprehensive database of temperature, heat flow, thermal conductivity and geochemistry is the basis of geothermal modelling. The latest revision (1987) of the UK Geothermal Catalogue (UKGC) contains over 2600 temperatures at over 1150 sites and over 200 observations of heat flow. About 93% of the temperature data are from depths less than 2000 m and about 50% are Bottom Hole Temperatures (BHT). Heat-flow density

400

Numerical simulation of electrokinetically driven micro flows  

E-Print Network (OSTI)

Spectral element based numerical solvers are developed to simulate electrokinetically driven flows for micro-fluidic applications. Based on these numerical solvers, basic phenomena and devices for electrokinetic applications in micro and nano flows...

Hahm, Jungyoon

2005-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Flow in Computer Hacking: A Model  

Science Journals Connector (OSTI)

In this study hackers’ motivation is investigated, using the flow paradigm. It was hypothesized that flow increases with the increase of hackers’ competence in the IT use. An on-line research was administered wit...

Alexander E. Voiskounsky; Olga V. Smyslova

2003-01-01T23:59:59.000Z

402

Analysis of oscillating flow cooled SMA actuator  

E-Print Network (OSTI)

literature, most of the cooling mechanisms involve unidirectional forced convection. This may not be the most effective method. Oscillating flow in a channel can sometimes enhance heat transfer over a unidirectional flow. One possible explanation...

Pachalla Seshadri, Rajagopal

2005-11-01T23:59:59.000Z

403

A quasionedimensional approach for hypersonic stagnationpoint flows  

E-Print Network (OSTI)

A quasi­onedimensional approach for hypersonic stagnation­point flows Arno Klomfass 1 Lehr­ und An approximate method for the efficient calculation of stagnation streamline quantities in hypersonic flows about

404

GUI for Hypersonic flow solver Master Project  

E-Print Network (OSTI)

GUI for Hypersonic flow solver Master Project Student : Enrique Guzman concerns the design of a GUI for commanding hypersonic flow applications using CFD techniques, as well as its potential applications. These problems are quite complex, since the called hypersonic regime

Diggavi, Suhas

405

Information Flow in Ensemble Weather Predictions  

Science Journals Connector (OSTI)

In a weather prediction, information flows from the initial conditions to a later prediction. The uncertainty in the initial conditions implies that such a flow should be quantified with tools from probability theory. Using several recent ...

Richard Kleeman

2007-03-01T23:59:59.000Z

406

Definition: Flow Test | Open Energy Information  

Open Energy Info (EERE)

Flow Test Flow tests are typically conducted shortly after a well has been drilled to test its productivity. The well is opened and fluids are released, the volume of fluids...

407

Floating Robots Track Water Flow With Smartphones  

NLE Websites -- All DOE Office Websites (Extended Search)

Floating Robots Track Water Flow, Stream Data via Smartphones Floating Robots Track Water Flow, Stream Data via Smartphones May 9, 2012 | Tags: Carver Jon Bashor, Jbashor@lbl.gov,...

408

Decentralized information flow control on a cluster  

E-Print Network (OSTI)

Information flow control security models can prevent programs from divulging sensitive information in unexpected ways. There has been significant work on tracking information flow between processes in the same computer at ...

Cliffer, Natan Tsvi Cohen

2007-01-01T23:59:59.000Z

409

Electromagnetically Induced Flows Michiel de Reus  

E-Print Network (OSTI)

Electromagnetically Induced Flows in Water Michiel de Reus 8 maart 2013 () Electromagnetically Conclusion and future research () Electromagnetically Induced Flows 2 / 56 #12;1 Introduction 2 Maxwell Navier Stokes equations 5 Simulations 6 Conclusion and future research () Electromagnetically Induced

Vuik, Kees

410

Elliptic flow of heavy flavors  

E-Print Network (OSTI)

The propagation of charm and bottom quarks through a ellipsoidal domain of quark gluon plasma has been studied within the ambit of non-equilibrium statistical mechanics. Energy dissipation of heavy quarks by both radiative and collisional processes are taken in to account. The experimental data on the elliptic flow of the non-photonic electrons resulting from the semi-leptonic decays of hadrons containing heavy flavours has been reproduced with the same formalism that has been used earlier to reproduce the nuclear suppression factors. The elliptic flow of the non-photonic electron from heavy meson decays produced in nuclear collisions at LHC and low energy RHIC run have also been predicted.

Das, Santosh K

2010-01-01T23:59:59.000Z

411

Elliptic flow of heavy flavors  

E-Print Network (OSTI)

The propagation of charm and bottom quarks through an ellipsoidal domain of quark gluon plasma has been studied within the ambit of non-equilibrium statistical mechanics. Energy dissipation of heavy quarks by both radiative and collisional processes are taken in to account. The experimental data on the elliptic flow of the non-photonic electrons resulting from the semi-leptonic decays of hadrons containing heavy flavours has been reproduced with the same formalism that has been used earlier to reproduce the nuclear suppression factors. The elliptic flow of the non-photonic electron from heavy meson decays produced in nuclear collisions at LHC and low energy RHIC run have also been predicted.

Santosh K Das; Jan-e Alam

2010-08-16T23:59:59.000Z

412

The Cotton tensor and the Ricci flow  

E-Print Network (OSTI)

We compute the evolution equation of the Cotton tensor under the Ricci flow of a three dimensional Riemannian manifold.

Mantegazza, Carlo

2012-01-01T23:59:59.000Z

413

Flow Imaging Using MRI: Quantification and Analysis  

E-Print Network (OSTI)

&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Chair of Committee, Jim Ji Committee Members, Andrew K. Chan Deepa Kundur Yoonsuck Choe Mary P. McDougall Head of Department, Costas N... Committee: Dr. Jim Ji A complex and challenging problem in flow study is to obtain quantitative flow information in opaque systems, for example, blood flow in biological systems and flow channels in chemical reactors. In this regard, MRI is superior...

Jiraraksopakun, Yuttapong

2010-07-14T23:59:59.000Z

414

A theory for radial jet reattachment flow  

E-Print Network (OSTI)

, the velocity profile and mass entrainment are given accordrng to Goertler's t. wo- dimensional free jet theory. His analysrs of a free jet also assumes that. the turbulent eddy viscosity is constant ar ross the jet. (6) For the case of laminar flow... of total jet momentum. Laminar jet flow is approximated using Schlichting's velocity profile, whereas turbulent flow calculations are made assuming Goertler's velocity profile. Momentum integral principles are applied to the flow at reattachment...

Hadden, Lynne Loise

2012-06-07T23:59:59.000Z

415

Anisotropic collective flow of a Lorentz gas  

E-Print Network (OSTI)

Analytical results for the anisotropic collective flow of a Lorentz gas of massless particles scattering on fixed centres are presented.

Nicolas Borghini; Clement Gombeaud

2011-06-30T23:59:59.000Z

416

Anisotropic Flow from RHIC to the LHC  

E-Print Network (OSTI)

Anisotropic flow is recognized as one of the main observables providing information on the early stage of a heavy-ion collision. At RHIC the large observed anisotropic flow and its successful description by ideal hydrodynamics is considered evidence for an early onset of thermalization and almost ideal fluid properties of the produced strongly coupled Quark Gluon Plasma. This write-up discusses some key RHIC anisotropic flow measurements and for anisotropic flow at the LHC some predictions.

Raimond Snellings

2006-10-05T23:59:59.000Z

417

Building up the elliptic flow: analytical insights  

E-Print Network (OSTI)

In this paper, we present a fully analytical description of the early-stage formation of elliptic flow in relativistic viscous hydrodynamics. We first construct an elliptic deformation of Gubser flow which is a boost invariant solution of the Navier-Stokes equation with a nontrivial transverse profile. We then analytically calculate the momentum anisotropy of the flow as a function of time and discuss the connection with the empirical formula by Bhalerao {\\it et al.} regarding the viscosity dependence of elliptic flow.

Yoshitaka Hatta; Bo-Wen Xiao

2014-05-08T23:59:59.000Z

418

NMR Studies of the Vanadium Spin Dynamics and Spin Structure in LiV2O4, CaV2O4, and (LixV1-x)3BO5 (x is almost equal to 0.33, 0.40)  

SciTech Connect

Strong electron correlation is believed to be an essential and unifying factor in diverse properties of condensed matter systems. Ground states that can arise due to electron correlation effects include Mott insulators, heavy fermion, ferromagnetism and antiferromagnetism, spin glasses, and high-temperature superconductivity. The electronic systems in transition metal oxide compounds are often highly correlated. In this thesis, the author presents experimental studies on three strongly correlated vanadium oxide compounds: LiV{sub 2}O{sub 4}, (Li{sub x}V{sub 1-x}){sub 3}BO{sub 5}, and CaV{sub 2}O{sub 4}, which have completely different ground states.

Xiaopeng Zong

2007-12-01T23:59:59.000Z

419

Microgravity Flow Regime Transition Modeling  

E-Print Network (OSTI)

apparatus have been used in past flow regime mapping experiments such as Venturi, perforated pipe, annular, and t-junction mixers. The mixing apparatus used in a particular experiment determines the bubble size distribution at the inlet... pressure of 80 kPa was reported, however, the temperature was not. The orientation and location of the test section with respect to the aircraft are unknown. The mixing apparatus used in the experiment was a Venturi mixer. This data set does...

Shephard, Adam M.

2010-07-14T23:59:59.000Z

420

Countercurrent flow absorber and desorber  

DOE Patents (OSTI)

Countercurrent flow absorber and desorber devices are provided for use in absorption cycle refrigeration systems and thermal boosting systems. The devices have increased residence time and surface area resulting in improved heat and mass transfer characteristics. The apparatuses may be incorporated into open cycle thermal boosting systems in which steam serves both as the refrigerant vapor which is supplied to the absorber section and as the supply of heat to drive the desorber section of the system. 9 figs.

Wilkinson, W.H.

1984-10-16T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

NETL: Gasifipedia - Entrained Flow Gasifiers  

NLE Websites -- All DOE Office Websites (Extended Search)

Entrained Flow Gasifiers Entrained Flow Gasifiers Uhde - Prenflo PRENFLO(tm) is a pressurized (>40 bar), entrained-flow gasification technology first demonstrated in the late 1980s, and currently offered by Uhde (Krupp Koppers merged with Uhde in 1997). Notably, PRENFLO(tm) is the gasification technology used at the world's largest solid feedstock-based gasifier at ELCOGAS's Puertollano IGCC plant in Spain (which is fueled with a 50%/50% mix of petcoke and coal). PRENFLO(tm) is offered in two varieties, the PRENFLO(tm) PSG (with steam generation) depicted in Figures 1 & 2, and PRENFLO(tm) PDQ (direct quench) as depicted in Figures 3 & 4. The gasifier conditions and feed characteristics are similar, but PRENFLO(tm) PSG includes an integrated waste heat boiler and uses compressed recirculated quench gas as illustrated in Figure 2, resulting in relatively low moisture raw syngas at relatively high exit temperature. PRENFLO(tm) PDQ uses direct quench, resulting in considerably lower raw syngas exit temperature (200-250°C) which is saturated. Uhde notes that PDQ has lower investment cost and shorter construction and supply schedule than PSG, though this would be at the performance expense of somewhat lower thermal efficiency and slightly higher concentration of CO2 in raw syngas.

422

Cyclotron resonance in plasma flow  

SciTech Connect

This paper is devoted to the mechanism of particle acceleration via resonant interaction with the electromagnetic circular wave propagating along the inhomogeneous background magnetic field in the presence of a plasma flow. We consider the system where the plasma flow velocity is large enough to change the direction of wave propagation in the rest frame. This system mimics a magnetic field configuration typical for inner structure of a quasi-parallel shock wave. We consider conditions of gyroresonant interaction when the force corresponding to an inhomogeneity of the background magnetic field is compensated by the Lorentz force of the wave-magnetic field. The wave-amplitude is assumed to be about 10% of the background magnetic field. We show that particles can gain energy if kv{sub sw}>?>kv{sub sw}??{sub c} where k is the wave number, v{sub sw} is a plasma flow velocity, and ? and ?{sub c} are the wave frequency and the particle gyrofrequency, respectively. This mechanism of acceleration resembles the gyrosurfing mechanism, but the effect of the electrostatic field is replaced by the effect of the magnetic field inhomogeneity.

Artemyev, A. V.; Agapitov, O. V.; Krasnoselskikh, V. V. [LPC2E/CNRS-University of Orleans, Orleans (France)] [LPC2E/CNRS-University of Orleans, Orleans (France)

2013-12-15T23:59:59.000Z

423

Flow Duration Curve Load Duration Curve  

E-Print Network (OSTI)

and concentration data--select appropriate conversion factors 3. Develop Load Duration Curve 4. Plot observed data there has been no flow at this site #12;Gather daily flow rate data Load data into a spreasheet Sort largest, etc) Calculate percentage of days flow was exceeded: How do you estimate load with given data

424

A quasionedimensional approach for hypersonic stagnationpoint flows  

E-Print Network (OSTI)

A quasi­onedimensional approach for hypersonic stagnation­point flows Arno Klomfass 1 Lehr­ und An approximate method for the efficient calculation of stagnation streamline quantities in hypersonic flows about­conduction coefficient [W=mK] 2 Introduction The hypersonic flow about a spacecraft entering the atmosphere at orbital

425

Setup of Particle Image Velocimetry (PIV) in Hypersonic Flows.  

E-Print Network (OSTI)

??The accuracy of numerical methods in calculating the flow of backward facing steps in turbulent hypersonic flows is limited due to a lack of flow… (more)

Anwar, Moazzam

2008-01-01T23:59:59.000Z

426

Geothermal Heat Flow and Existing Geothermal Plants | Department...  

Energy Savers (EERE)

Geothermal Heat Flow and Existing Geothermal Plants Geothermal Heat Flow and Existing Geothermal Plants Geothermal Heat Flow and Existing Plants With plants in development. Click...

427

WHICH HYDRAULIC MODEL TO USE IN VERTICAL FLOW CONSTRUCTED WETLANDS?  

E-Print Network (OSTI)

WHICH HYDRAULIC MODEL TO USE IN VERTICAL FLOW CONSTRUCTED WETLANDS? Ania Morvannoua , Nicolas-equilibrium model, preferential flow path, vertical flow constructed wetlands INTRODUCTION Constructed wetlands (CWs

Paris-Sud XI, Université de

428

Chemical preconcentrator with integral thermal flow sensor  

DOE Patents (OSTI)

A chemical preconcentrator with integral thermal flow sensor can be used to accurately measure fluid flow rate in a microanalytical system. The thermal flow sensor can be operated in either constant temperature or constant power mode and variants thereof. The chemical preconcentrator with integral thermal flow sensor can be fabricated with the same MEMS technology as the rest of the microanlaytical system. Because of its low heat capacity, low-loss, and small size, the chemical preconcentrator with integral thermal flow sensor is fast and efficient enough to be used in battery-powered, portable microanalytical systems.

Manginell, Ronald P. (Albuquerque, NM); Frye-Mason, Gregory C. (Cedar Crest, NM)

2003-01-01T23:59:59.000Z

429

Self-regulating flow control device  

SciTech Connect

A variable, self-regulating valve having a hydraulic loss coefficient proportional to a positive exponential power of the flow rate. The device includes two objects in a flow channel and structure which assures that the distance between the two objects is an increasing function of the flow rate. The range of spacing between the objects is such that the hydraulic resistance of the valve is an increasing function of the distance between the two objects so that the desired hydraulic loss coefficient as a function of flow rate is obtained without variation in the flow area.

Humphreys, Duane A. (Pittsburgh, PA)

1984-01-01T23:59:59.000Z

430

Thorium and uranium redox-active ligand complexes; reversible intramolecular electron transfer in U(dpp-BIAN)2/ U(dpp-BIAN)2(THE)  

SciTech Connect

Actinide complexes of the redox-active ligand dpp-BIAN{sup 2-} (dpp-BIAN = bis(2,6-diisopropylphenyl)acenaphthylene), An(dpp-BIAN){sub 2}(THF){sub n} (An = Th, n = 1; An = U, n = 0, 1) have been prepared. Solid-state magnetic and single-crystal X-ray data for U(dpp-BIAN){sub 2}(THF){sub n} show when n = 0, the complex exists in an f{sup 2}-{pi}*{sup 4} configuration; whereas an intramolecular electron transfer occurs for n = 1, resulting in an f{sup 3}-{pi}*{sup 3} ground configuration. The magnetic data also indicate that interconversion between the two forms of the complex is possible, limited only by the ability of THF vapor to penetrate the solid on cooling of the sample. Spectroscopic data indicate the complex exists solely in the f{sup 2}-{pi}*{sup 4} form in solution, evidenced by the appearance of only small changes in the electronic absorption spectra of the U(dpp-BIAN){sub 2} complex on titration with THF and by measurement of the solution magnetic moment m d{sub 8}-tetrahydrofuran using Evans method. Electrochemistry of the complexes is reported, with small differences observed in wave potentials between metals and in the presence of THF. These data represent the first example of a well-defined, reversible intramolecular electron transfer in an f-element complex and the second example of oxidation state change through dative interaction with a metal ion.

Schelter, Eric John [Los Alamos National Laboratory; Wu, Ruilian [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Batista, Enrique R [Los Alamos National Laboratory; Morris, David E [Los Alamos National Laboratory; Kiplinger, Jaqueline L [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

431

Energy focusing in bubbly flows  

Science Journals Connector (OSTI)

Sonoluminescence cavitation damage at surfaces and cavitation in accelerating flows are realizations of spectacular levels of energy focusing in nature. In a resonant sound field a single trapped bubble of gas can focus the ambient sound energy by 12 orders of magnitude to generate a clocklike string of picosecond flashes of ultraviolet light. [Barber et al. ‘‘Defining the unknowns of sonoluminescence ’’ Phys. Rep. 281 65 (1977)]. In more complicated geometries a high level of sound leads to the formation of hemispherical bubbles attached to an exposed surface. These bubbles also emit light and in addition damage the surface. Measurements show that the pulsation of these bubbles maintains the hemispherical symmetry [Weninger et al. ‘‘Sonoluminescence from an isolated bubble on a solid surface ’’ Phys. Rev. E 56 6745 (1997)] thus raising the question as to whether cavitation damage is due to (micro)jets or imploding (hemispherical) shock waves. Finally flow through a Venturi tube generates a stream of bubbles which also emit subnanosecond flashes of light [F. B. Peterson and T. P. Anderson Phys. Fluids 10 874 (1967)]. Luminescence from an isolated trapped bubble in water seems to work well with any noble gas whereas luminescence from cavitating flows and surface bubbles is quite dependent on xenon [argon bubbles appear to give no light at all]. The width of the SL flash [Gompf et al. Phys. Rev. Lett. 79 1405 (1997) Hiller et al. Phys. Rev. Lett. 80 1090 (1998)] has been found to be independent of wavelength suggesting that light is emitted from a new high energy phase of matter?probably a cold dense nano?plasma. The key unknowns of SL are the size and temperature of the hot spot from which the light is emitted. Experiments aimed at measuring these quantities will be discussed. [Research supported by the NSF.] a)Present address: CMS Los Alamos National Laboratories Los Alamos NM. b)Present address: Lucent Technologies Murray Hill NJ.

Seth Putterman; Keith Weninger; Robert A. Hiller; Bradley P. Barber

1998-01-01T23:59:59.000Z

432

Enthalpy Diffusion in Multicomponent Flows  

SciTech Connect

The conclusions of this paper are: (1) Enthalpy diffusion preserves the second law. (2) Euler solvers will not produce correct temperatures in mixing regions. (3) Navier-Stokes solvers will only produce correct temperatures if q{sub d} is included. (4) Errors from neglecting enthalpy diffusion are most severe when differences in molecular weights are large. (5) In addition to temperature, enthalpy diffusion affects density, dilatation and other fields in subtle ways. (6) Reacting flow simulations that neglect the term are a dubious proposition. (7) Turbulence models for RANS and LES closures should preserve consistency between energy and species diffusion.

Cook, A W

2009-01-20T23:59:59.000Z

433

Entrainment measurements in annular flow  

SciTech Connect

Air/water and vapor/freon were utilized to scale and simulate annular two-phase flow for high pressure steam/water conditions. A unique vapor/liquid Freon loop was built to obtain the high pressure data. The results were compared with two correlations available in the open literature. The Ishii and Mishima dimensionless group was able to scale the data remarkably well even for vapor/liquid Freon. However, the correlation needs to be adjusted for high Weber numbers of the gas phase.

Assad, A.; Jan, C.; Bertodano, M. de [Purdue Univ., West Lafayette, IN (United States); Beus, S.G. [Bettis Atomic Power Lab., West Mifflin, PA (United States)

1997-07-01T23:59:59.000Z

434

A new precision flow calorimeter  

E-Print Network (OSTI)

differences. With no sample fluid flowing, a supply of electrical power is fed to the inner calorimeter. The reference fluid is evaporated with this electrical power and the thermo-syphon system is brought to controlled steady-state conditions of pressure... calorimeter is kept cooler than the inner calorimeter for reasons discussed in chapter 4. Thus the above mentioned procedure is essential to avoid condensation in Freon@-11 vapor lines. The thermo-syphon ensures a saturated Freon&-11 vapor phase in the top...

Johnson, Mark Gezer

1984-01-01T23:59:59.000Z

435

DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS  

SciTech Connect

In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in which flow regime transition occurs.

X. Wang; X. Sun; H. Zhao

2011-09-01T23:59:59.000Z

436

Potential Flow Calculations of Axisymmetric Ducted Wind Turbines  

E-Print Network (OSTI)

An incompressible potential-flow vortex method has been constructed to analyze the flow field of a ducted

Widnall, Sheila

2009-09-02T23:59:59.000Z

437

Flow shop scheduling with peak power consumption constraints  

E-Print Network (OSTI)

Mar 29, 2012 ... Flow shop scheduling with peak power consumption constraints ... Keywords: scheduling, flow shop, energy, peak power consumption, integer ...

K. Fang

2012-03-29T23:59:59.000Z

438

Heat flow on the southern Colorado Plateau  

Science Journals Connector (OSTI)

Heat-flow data from the study area in the southern Colorado Plateau indicate a pattern of local anomalies having relatively high heat flow superimposed on a regional, intermediate heat-flow setting. While many of the conventional heat-flow data are relatively shallow and may be perturbed by groundwater circulation, bottom-hole temperature data from two relatively deep petroleum exploration drill holes near the southern plateau periphery yield intermediate heat-flow estimates. The mean heat flow within the volcanically active Jemez zone does not appear to be significantly greater than the mean heat flow for the remainder of the study area. This is due to the presence of high heat-flow values outside the Jemez zone. Sites with relatively high heat flow located towards the plateau interior and away from recent volcanic activity of the Jemez zone may reflect magma intrusion and/or groundwater movement along crustal zones of weakness associated with Laramide deformation (monoclines). The heat-flow data are consistent with coal maturation data, which suggest that any regional post-Cretaceous thermal events that may be associated with the southern Plateau boundary have been initiated relatively recently, or are occurring at relatively great depths, or are occurring south of the Jemez lineament.

Jeffrie Minier; Marshall Reiter

1991-01-01T23:59:59.000Z

439

Preserving quality of service guarantees in spite of flow aggregation  

Science Journals Connector (OSTI)

We investigate how quality of service may be guaranteed to a flow of packets in the presence of flow aggregation. For efficiency, multiple flows, known as the constituent flows, are merged together resulting in a single aggregate flow. After the network ... Keywords: Flow aggregation, quality of service, real-time scheduling

Jorge Arturo Cobb

2002-02-01T23:59:59.000Z

440

Proximal bodies in hypersonic flow  

SciTech Connect

Hypersonic flows involving two or more bodies travelling in close proximity to one another are encountered in several important situations, both natural and man-made. The present work seeks to investigate one aspect of the resulting flow problem by exploring the forces experienced by a secondary body when it is within the domain of influence of a primary body travelling at hypersonic speeds. An analytical methodology based on the blast wave analogy is developed and used to predict the secondary force coefficients for simple geometries in both two and three dimensions. When the secondary body is entirely inside the primary shocked region, the nature of the lateral force coefficient is found to depend strongly on the relative size of the two bodies. For two spheres, the methodology predicts that the secondary body will experience an exclusively attractive lateral force if the secondary diameter is larger than one-sixth the primary diameter. The analytical results are compared with those from numerical simulations and reasonable agreement is observed if an appropriate normalization for the lateral displacement is used. Results from a series of experiments in the T5 hypervelocity shock tunnel are also presented and compared with perfect-gas numerical simulations, with good agreement. A new force-measurement technique for short-duration hypersonic facilities, enabling the experimental simulation of the proximal bodies problem, is described. This technique provides two independent means of measurement, and the agreement observed between the two gives a further degree of confidence in the results obtained.

Deiterding, Ralf [ORNL; Laurence, Stuart J [California Institute of Technology, Pasadena; Hornung, Hans G [California Institute of Technology, Pasadena

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Modeling Biogeochemistry and Flow within Heterogeneous Formations in Variably-Saturated Media  

E-Print Network (OSTI)

.) increases biogeochemical activity around that interface. Hydrologic conditions, rainfall events, drainage patterns, and pH variations are also dominant controls on redox processes and thereby affect contaminant distribution and migration. An inherent...

Arora, Bhavna

2012-10-19T23:59:59.000Z

442

Effect of a co?flowing annular outer flow on the flow and acoustics in a porous tube.  

Science Journals Connector (OSTI)

One of the most important aspects of flow in a gas turbine combustor is the cooling airflow introduced through the combustor liner. The co?flowing annular cooling air affects the flow and the acoustic field of the main combustor. A generic study is in progress to study the effect of a co?flowing annular outer flow on the flow and acoustics in a porous tube. This work is an idealization of the actual gas turbine combustor flow. The results generated here will be used to validate the computational codes currently being used by the gas turbine industry to calculate these flow fields. In the present experimental work a 6?in.?diam tube made out of perforated sheet is located coaxially in an 8?in.?diam outer tube. Airflows in the inner perforated tube as well as in the annular space between the two tubes. Detailed measurements of the turbulence structure using hot wire anemometry and of the acoustic field using microphonetransducers are being made. Effects of parameters such as porosity of the tube relative areas of annular space and cross section of inner tube and flow Reynolds number on the turbulence quantities and the acoustic field will be reported.

Sundar Ramamoorthy; Fariborz Khodabakhsh; Sastry Munukutla

1992-01-01T23:59:59.000Z

443

Cobalt-iron red-ox behavior in nanostructured La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} cathodes  

SciTech Connect

Nano-sized La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) perovskite samples (prepared by a conventional acetate route and a novel acetate synthesis with HMTA additives), were tested simulating a red-ox cycle. The crystallography was studied by X-ray Powder Diffraction (XPD) and the changes in the oxidation state of the perovskite B-site were evaluated by synchrotron X-ray Absorption Near Edge Spectroscopy (XANES). After a reducing treatment, LSFC particles show the appearance of a new phase that coexists with the original one. The structural change is accompanied by a Co and Fe formal oxidation states decrease, although Fe remains always closer to 4+ and Co closer to 3+. The treatment produces a B-site valence average reduction from 3.52+ to 3.26+ and the formation of oxygen vacancies. A re-oxidation treatment under O{sub 2} rich atmosphere at 800 Degree-Sign C for 10 h shows that the change is reversible and independent of the two chemical methods used to synthesize the LSCF nano-particles. - Graphical abstract: XANES and XPD measurements in nanostructured LSCF before (black) and after (red/green) a red/ox cycle. Highlights: Black-Right-Pointing-Pointer Red-ox treatments in LSCF nano-particles cause a reversible reaction. Black-Right-Pointing-Pointer XPD analyses show that a new 'reduced' phase coexist with the oxidize one. Black-Right-Pointing-Pointer The B-site formal oxidation state decreases and the {delta} increases upon reduction. Black-Right-Pointing-Pointer Fe remains in a higher valence (closer to 4+) than Co (close to 3+). Black-Right-Pointing-Pointer The behavior seems to be independent of the synthesis method used.

Soldati, Analia L., E-mail: asoldati@cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Baque, Laura, E-mail: baque.laura@gmail.com [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Napolitano, Federico, E-mail: napolitf@ib.cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Serquis, Adriana, E-mail: aserquis@cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)

2013-02-15T23:59:59.000Z

444

Fact Sheets | Department of Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Fact Sheets Fact Sheets Fact Sheets Brief overviews of specific, and sometimes complex, topics. ADVANCED CABLES AND CONDUCTORS Fault Current Limiters CONTROL SYSTEMS SECURITY National SCADA Test Bed EMERGENCY PREPAREDNESS Energy Sector Specific Plan ESF - 12 Annex Federal Partners and Functions EMERGENCY RESPONSE ESF - 12 Annex Federal Partners and Functions ENERGY STORAGE Award-Winning Silicon Carbide Power Electronics (Oct 2012) Carbon-Enhanced Lead-Acid Batteries (Oct 2012) Lithium-Ion Batteries for Stationary Energy Storage (Oct 2012) Sodium-Beta Batteries (Oct 2012) Vanadium Redox Flow Batteries (Oct 2012) Energy Storage Database (Oct 2012) Energy Storage Technology Advancement Partnership (Oct 2012) Energy Storage Testing and Validation (Oct 2012) ES-Select: A Decision Support Tool (Oct 2012)

445

Energy Storage Systems 2010 Update Conference Presentations - Day 1,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0 Update Conference Presentations - Day 0 Update Conference Presentations - Day 1, Session 2 Energy Storage Systems 2010 Update Conference Presentations - Day 1, Session 2 The U.S. DOE Energy Storage Systems Program (ESS) conducted a record-breaking Update Conference at the Washington DC Marriott Hotel on Nov. 2 - 4, 2010, with more than 500 attendees. The 2010 agenda reflected increased national interest in energy storage issues. The 3-day conference included 11 sessions plus a poster session on the final day. Presentations from the second session of Day 1, chaired by SNL's Terry Aselage, are below. ESS 2010 Update Conference - Advanced Stationary Electrical Energy Storage R&D at PNNL - Z Gary Yang, PNNL.pdf ESS 2010 Update Conference - A New Vanadium Redox Flow Battery Using Mixed Acid Electrolytes - Liyu Li, PNNL.pdf

446

Energy Storage Systems 2012 Peer Review Presentations - Day 1, Session 3 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3 3 Energy Storage Systems 2012 Peer Review Presentations - Day 1, Session 3 The U.S. DOE Energy Storage Systems Program (ESS) conducted a peer review and update meeting in Washington, DC on Sept. 26 - 28, 2012. The 3-day conference included 9 sessions plus two poster sessions. Presentations from the third session of Day 1, chaired by Bill Capp of Grid Storage Consulting, are below. ESS 2012 Peer Review - Flow Battery Solution for Smart Grid Renewable Energy Applications - Sheri Nevins, Raytheon & Ron Moss, EnerVault ESS 2012 Peer Review - Painesville Municipal Electric Power Vanadium Redox Battery Demo Project - Jodi Startari, Ashlawn Energy ESS 2012 Peer Review - Energy Storage Controls for Grid Stability - Ray Byrne, SNL ESS 2012 Peer Review - Secondary Use of Vehicle Batteries in Power Systems

447

Energy Storage Systems 2012 Peer Review Presentations - Day 1, Session 3 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1, 1, Session 3 Energy Storage Systems 2012 Peer Review Presentations - Day 1, Session 3 The U.S. DOE Energy Storage Systems Program (ESS) conducted a peer review and update meeting in Washington, DC on Sept. 26 - 28, 2012. The 3-day conference included 9 sessions plus two poster sessions. Presentations from the third session of Day 1, chaired by Bill Capp of Grid Storage Consulting, are below. ESS 2012 Peer Review - Flow Battery Solution for Smart Grid Renewable Energy Applications - Sheri Nevins, Raytheon & Ron Moss, EnerVault ESS 2012 Peer Review - Painesville Municipal Electric Power Vanadium Redox Battery Demo Project - Jodi Startari, Ashlawn Energy ESS 2012 Peer Review - Energy Storage Controls for Grid Stability - Ray Byrne, SNL ESS 2012 Peer Review - Secondary Use of Vehicle Batteries in Power Systems

448

LLNL Energy Flow Charts | Open Energy Information  

Open Energy Info (EERE)

LLNL Energy Flow Charts LLNL Energy Flow Charts Jump to: navigation, search Tool Summary Name: LLNL Energy Flow Charts Agency/Company /Organization: Lawrence Livermore National Lab Sector: Energy Focus Area: Renewable Energy Topics: Pathways analysis References: LLNL Energy Flow Charts [1] Decision makers have long recognized the importance of visualizing energy and material flows in a way that distinguishes between resources, transformations and services. Research priorities can be defined in terms of changes to the flows, and the consequences of policy or technology shifts can be traced both upstream and downstream. The usefulness of this top-down view is limited by the level of detail that can be conveyed in a single image. We use two techniques to balance information content with readability. First we employe visualization

449

CFD analysis of laminar oscillating flows  

SciTech Connect

This paper describes a numerical simulations of oscillating flow in a constricted duct and compares the results with experimental and theoretical data. The numerical simulations were performed using the computational fluid dynamics (CFD) code CFX4.2. The numerical model simulates an experimental oscillating flow facility that was designed to test the properties and characteristics of oscillating flow in tapered ducts, also known as jet pumps. Jet pumps are useful devices in thermoacoustic machinery because they produce a secondary pressure that can counteract an unwanted effect called streaming, and significantly enhance engine efficiency. The simulations revealed that CFX could accurately model velocity, shear stress and pressure variations in laminar oscillating flow. The numerical results were compared to experimental data and theoretical predictions with varying success. The least accurate numerical results were obtained when laminar flow approached transition to turbulent flow.

Booten, C. W. Charles W.); Konecni, S. (Snezana); Smith, B. L. (Barton L.); Martin, R. A. (Richard A.)

2001-01-01T23:59:59.000Z

450

Multiphase Flow in Geometrically Simple Fracture Intersections  

SciTech Connect

A two-dimensional lattice Boltzmann (LB) model with fluid-fluid and solid-fluid interaction potentials was used to Study gravity-driven flow in geometrically simple fracture intersections. simulated scenarios included fluid dripping from a fracture aperture, two-phase flow through intersecting fractures and thin-filin flow oil smooth and undulating solid surfaces. Qualitative comparisons with recently published experimental findings indicate that for these scenarios the LB model captured the underlying physics reasonably well.

Hakan Basagaoglu; Paul Meakin; Sauro Succi; Timothy R. Ginn

2006-03-01T23:59:59.000Z

451

Multiphase flow in geometrically simple fracture intersection  

SciTech Connect

A two-dimensional lattice Boltzmann (LB) model with fluid-fluid and solid-fluid interaction potentials was used to study gravity-driven flow in geometrically simple fracture intersections. Simulated scenarios included fluid dripping from a fracture aperture, two-phse flow through intersecting fractures, and thin-film flow on smooth and undulating solid surfaces. Qualititative comparisons with recently published experimental findings indicate that for these scenarios the LB model captured the underlying physics reasonably well.

H. Basagaoglu; P. Meakin; M. Mathew

2006-03-01T23:59:59.000Z

452

Dissipation flow-frames: particle, energy, thermometer  

E-Print Network (OSTI)

We associate the following physical co-mover conditions of to different frame choices: i) Eckart: particle flow, ii) Landau-Lifshitz: energy flow, iii) J\\"uttner: moving thermometer frame. The role of fixing a flow-frame is analysed with respect to local equilibrium concentrating on dissipative currents and forces in single component relativistic fluids. The special role of a "J\\"uttner frame" is explored and contrasted to the more common Eckart and Landau-Lifshitz choices.

Ván, P

2013-01-01T23:59:59.000Z

453

Dissipation flow-frames: particle, energy, thermometer  

E-Print Network (OSTI)

We associate the following physical co-mover conditions of to different frame choices: i) Eckart: particle flow, ii) Landau-Lifshitz: energy flow, iii) J\\"uttner: moving thermometer frame. The role of fixing a flow-frame is analysed with respect to local equilibrium concentrating on dissipative currents and forces in single component relativistic fluids. The special role of a "J\\"uttner frame" is explored and contrasted to the more common Eckart and Landau-Lifshitz choices.

P. Ván; T. S. Biró

2013-05-14T23:59:59.000Z

454

Theoretical uncertainty of orifice flow measurement  

SciTech Connect

Orifice meters are the most common meters used for fluid flow measurement, especially for measuring hydrocarbons. Meters are rugged, mechanically simple, and well suited for field use under extreme weather conditions. Because of their long history of use and dominance in the fluid flow measurement, their designs, installation requirements, and equations for flow rate calculation have been standardized by different organizations in the United States and internationally. These standards provide the guideline for the users to achieve accurate flow measurement. and minimize measurement uncertainty. This paper discusses different factors that contribute to the measurement inaccuracy and provide an awareness to minimize or eliminate these errors. Many factors which influence the overall measurement uncertainty are associated with the orifice meter application. Major contributors to measurement uncertainty include the predictability of flow profile, fluid properties at flowing condition, precision of empirical equation for discharge coefficient, manufacturing tolerances in meter components, and the uncertainty associated with secondary devices monitoring the static line pressure, differential pressure across the orifice plate, flowing temperature, etc. Major factors contributing to the measurement uncertainty for a thin, concentric, square-edged orifice flowmeter are as follows: (a) Tolerances in prediction of coefficient of discharge, (b) Predictability in defining the physical properties of the flowing fluid, (c) Fluid flow condition, (d) Construction tolerances in meter components, (e) Uncertainty of secondary devices/instrumentation, and (f) Data reduction and computation. Different factors under each of the above areas are discussed with precautionary measures and installation procedures to minimize or eliminate measurement uncertainty.

Husain, Z.D. [Daniel Flow Products, Inc., Houston, TX (United States)

1995-12-01T23:59:59.000Z

455

The Boussinesq approximation in rapidly rotating flows  

E-Print Network (OSTI)

In the classical formulation of the Boussinesq approximation centrifugal buoyancy effects related to differential rotation, as well as strong vortices in the flow, are neglected. However, these may play an important role in rapidly rotating flows, such as in astrophysical and geophysical applications, and also in turbulent convection. We here provide a straightforward approach resulting in a Boussinesq-type approximation that consistently accounts for centrifugal effects. We further compare our new approach to the classical one in fluid flows confined between two differentially heated and rotating cylinders. The results justify the need of using the proposed approximation in rapidly rotating flows.

Lopez, Jose M; Avila, Marc

2013-01-01T23:59:59.000Z

456

Sandia National Laboratories: power flow control system  

NLE Websites -- All DOE Office Websites (Extended Search)

power flow control system ECIS-Princeton Power Systems, Inc.: Demand Response Inverter On March 19, 2013, in DETL, Distribution Grid Integration, Energy, Energy Surety, Facilities,...

457

Flow visualisation in inclined louvered fins  

SciTech Connect

In this study the flow within an interrupted fin design, the inclined louvered fin, is investigated experimentally through visualisation. The inclined louvered fin is a hybrid of the offset strip fin and standard louvered fin, aimed at improved performance at low Reynolds numbers for compact heat exchangers. The flow behaviour is studied in six geometrically different configurations over a range of Reynolds numbers and quantified using the concept of 'fin angle alignment factor'. The transition from steady laminar to unsteady flow was studied in detail. The fin geometry had a very large impact on the transitional flow behaviour, especially on vortex shedding. (author)

T'Joen, C.; De Paepe, M. [Department of Flow, Heat and Combustion Mechanics, Ghent University-UGent, Sint-Pietersnieuwstraat 41, 9000 Gent (Belgium); Jacobi, A. [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 1206 West Green Street, Urbana, IL 61801 (United States)

2009-04-15T23:59:59.000Z

458

Measurement of thermodynamics using gradient flow  

E-Print Network (OSTI)

We analyze bulk thermodynamics and correlation functions of the energy-momentum tensor in pure Yang-Mills gauge theory using the energy-momentum tensor defined by the gradient flow and small flow time expansion. Our results on thermodynamic observables are consistent with those obtained by the conventional integral method. The analysis of the correlation function of total energy supports the energy conservation. It is also addressed that these analyses with gradient flow require less statistics compared with the previous methods. All these results suggest that the energy-momentum tensor can be successfully defined and observed on the lattice with moderate numerical costs with the gradient flow.

Masakiyo Kitazawa; Masayuki Asakawa; Tetsuo Hatsuda; Takumi Iritani; Etsuko Itou; Hiroshi Suzuki

2014-12-15T23:59:59.000Z

459

Fractal Networks Explain Regional Myocardial Flow Heterogeneity  

Science Journals Connector (OSTI)

Regional myocardial blood flow is very heterogeneous. This has been found by injection of radioactively labeled microspheres, or the “molecular microsphere” iododesmethylimipramine, and measuring the depositio...

Johannes H. G. M. van Beek; James B. Bassingthwaighte…

1989-01-01T23:59:59.000Z

460

Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Spray, Combustion, & Emission Modeling using KH-ACT Primary Breakup Model & Detailed Chemistry Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling using KH-ACT Primary...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Fluid Gravity Engineering Rocket motor flow analysis  

E-Print Network (OSTI)

Fluid Gravity Engineering Capability · Rocket motor flow analysis -Internal (performance) -External young scientists/engineers Fluid Gravity Engineering Ltd #12;

Anand, Mahesh

462

Fast flow phenomena in a toroidal plasma  

NLE Websites -- All DOE Office Websites (Extended Search)

apparatus. The main body of the paper is a description of the experimental phenomenology of flow and locking, which is discussed in the dynamical context of the torque...

463

NETL: Gasifipedia - Entrained Flow Gasifiers  

NLE Websites -- All DOE Office Websites (Extended Search)

Siemens Gasifier Siemens Gasifier (source: Siemens) Siemens Gasifiers Siemens gasification technology was originally developed by Deutsches Brennstoffinstitut (DBI) in Freiberg, Germany for the gasification of pulverized local brown coal and other solid feedstocks in 1975. The Noell group acquired the technology in 1991 and developed it further to handle liquid residues and wastes. The gasifier also operated under the name of Babcock Borsig and Future Energy before being acquired by Siemens in 2006. Operation The Siemens gasifier is a dry-feed, pressurized, entrained-flow reactor, which can be supplied with either a refractory lining for low ash feedstocks or with a cooling screen in the gasification section of the gasifier. The cooling screen consists of a gas-tight membrane wall

464

Combustion synthesis continuous flow reactor  

DOE Patents (OSTI)

The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor.

Maupin, Gary D. (Richland, WA); Chick, Lawrence A. (West Richland, WA); Kurosky, Randal P. (Maple Valley, WA)

1998-01-01T23:59:59.000Z

465

Thermodynamics with Continuous Information Flow  

Science Journals Connector (OSTI)

We provide a unified thermodynamic formalism describing information transfers in autonomous as well as nonautonomous systems described by stochastic thermodynamics. We demonstrate how information is continuously generated in an auxiliary system and then transferred to a relevant system that can utilize it to fuel otherwise impossible processes. Indeed, while the joint system satisfies the second law, the entropy balance for the relevant system is modified by an information term related to the mutual information rate between the two systems. We show that many important results previously derived for nonautonomous Maxwell demons can be recovered from our formalism and use a cycle decomposition to analyze the continuous information flow in autonomous systems operating at a steady state. A model system is used to illustrate our findings.

Jordan M. Horowitz and Massimiliano Esposito

2014-07-28T23:59:59.000Z

466

Renormalization flows in complex networks  

Science Journals Connector (OSTI)

Complex networks have acquired a great popularity in recent years, since the graph representation of many natural, social, and technological systems is often very helpful to characterize and model their phenomenology. Additionally, the mathematical tools of statistical physics have proven to be particularly suitable for studying and understanding complex networks. Nevertheless, an important obstacle to this theoretical approach is still represented by the difficulties to draw parallelisms between network science and more traditional aspects of statistical physics. In this paper, we explore the relation between complex networks and a well known topic of statistical physics: renormalization. A general method to analyze renormalization flows of complex networks is introduced. The method can be applied to study any suitable renormalization transformation. Finite-size scaling can be performed on computer-generated networks in order to classify them in universality classes. We also present applications of the method on real networks.

Filippo Radicchi; Alain Barrat; Santo Fortunato; José J. Ramasco

2009-02-06T23:59:59.000Z

467

Flow-induced vibration: 1992  

SciTech Connect

A joint program on flow-induced vibration (FIV) as established in July 1988 between Taiwan Power Company (Taipower or TPC) and ANL. The main objectives of the program are to provide a technology transfer program on FIV for Taipower staff and to assist Taipower with various aspects of FIV including evaluation of reports and proposals, review of designs, resolution of design issues, recommendation for design modifications, and selected research studies. During the first two years, the following tasks were accomplished: A technology transfer program on FIV was completed and key Taipower staff members were prepared to handle future problems in the subject area. The modified component cooling water (CCW) heat exchangers were assessed and the basis for a license from the Taiwan Atomic Energy Council (AEC) was established. The seismic reanalysis of Chin Shan spent-fuel racks was assessed and a report was submitted to the Taiwan AEC. Fluid/structure interaction activities were coordinated and provided a list of potential bidders for a fluid transient project and related publications and a recommendation for purchasing technical data on fluid coupling. Flow-induced vibration of tube arrays was reviewed and the needs of Taipower in the area of fluid/structure interaction were identified as were the procedures necessary for Taipower to accomplish its goals. A computer program, ARRAY, was established to compute the added-mass matrices for tube arrays. Taipower expressed interest in extending the joint program so that ANL could provide continuing assistance. The program was extended for several years (May 1, 1991, to June 30, 1994). Work from May 1, 1991, through June 30, 1992, summarized in this report, included technology transfer, assessment of sensing line and valve vibrations, literature survey, and tests on motion-dependent fluid forces acting on tube arrays in crossflow.

Chen, S.S.

1992-09-01T23:59:59.000Z

468

Laser Sheet Light Flow Visualization For Evaluating Room Air Flows From  

E-Print Network (OSTI)

LBNL-56483 Laser Sheet Light Flow Visualization For Evaluating Room Air Flows From Registers Iain S using a Planar Laser-Induced Fluorescence (PLIF) measurement technique. Water marked with fluorescent

469

Groundwater abstraction impacts on spring flow and base flow in the Hillsborough River Basin, Florida, USA  

Science Journals Connector (OSTI)

Groundwater abstraction has resulted in spring flow and groundwater base-flow declines in the Hillsborough River system of central Florida, USA. These declines have resulted in reduction of inflows to the Tamp...

Kenneth A. Weber; Robert G. Perry

2006-11-01T23:59:59.000Z

470

Numerical analysis of the flow field inside an entrained-flow gasifier  

Science Journals Connector (OSTI)

The flow field of an entrained-flow gasifier was numerically simulated to describe coal gasification ... inlet velocity, extension in burner length and gasifier geometry. The calculation results showed that the ....

Young Chan Choi; Xiang Yang Li; Tae Jun Park…

2001-05-01T23:59:59.000Z

471

Site-Scale Saturated Zone Flow Model  

SciTech Connect

The purpose of this model report is to document the components of the site-scale saturated-zone flow model at Yucca Mountain, Nevada, in accordance with administrative procedure (AP)-SIII.lOQ, ''Models''. This report provides validation and confidence in the flow model that was developed for site recommendation (SR) and will be used to provide flow fields in support of the Total Systems Performance Assessment (TSPA) for the License Application. The output from this report provides the flow model used in the ''Site-Scale Saturated Zone Transport'', MDL-NBS-HS-000010 Rev 01 (BSC 2003 [162419]). The Site-Scale Saturated Zone Transport model then provides output to the SZ Transport Abstraction Model (BSC 2003 [164870]). In particular, the output from the SZ site-scale flow model is used to simulate the groundwater flow pathways and radionuclide transport to the accessible environment for use in the TSPA calculations. Since the development and calibration of the saturated-zone flow model, more data have been gathered for use in model validation and confidence building, including new water-level data from Nye County wells, single- and multiple-well hydraulic testing data, and new hydrochemistry data. In addition, a new hydrogeologic framework model (HFM), which incorporates Nye County wells lithology, also provides geologic data for corroboration and confidence in the flow model. The intended use of this work is to provide a flow model that generates flow fields to simulate radionuclide transport in saturated porous rock and alluvium under natural or forced gradient flow conditions. The flow model simulations are completed using the three-dimensional (3-D), finite-element, flow, heat, and transport computer code, FEHM Version (V) 2.20 (software tracking number (STN): 10086-2.20-00; LANL 2003 [161725]). Concurrently, process-level transport model and methodology for calculating radionuclide transport in the saturated zone at Yucca Mountain using FEHM V 2.20 are being carried out in the model report, ''Site-Scale Saturated Zone Transport'', MDL-NBS-HS-000010 Rev 01 (BSC 2003 [162419]). The velocity fields are calculated by the flow model, described herein, independent of the transport processes, and are then used as inputs to the transport model. Justification for this abstraction is presented in the model report, ''Saturated Zone Flow and Transport Model Abstraction'', MDL-NBS-HS-000021 (BSC 2003 [164870]).

G. Zyvoloski

2003-12-17T23:59:59.000Z

472

The effects between two slotted plate flow meter under single, two, three components flow condition  

E-Print Network (OSTI)

THE INTERACTION BETWEEN A TWO SLOTTED PLATE FLOW METER UNDER ONE, TWO, OR THREE COMPONENT FLOW CONDITIONS A Thesis by SANG HYUN PARK Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 2004 Major Subject: Mechanical Engineering THE INTERACTION BETWEEN A TWO SLOTTED PLATE FLOW METER UNDER ONE, TWO, OR THREE COMPONENT FLOW...

Park, Sang Hyan

2005-02-17T23:59:59.000Z

473

Evaluation of a slotted orifice plate flow meter using horizontal two phase flow  

E-Print Network (OSTI)

of MASTER OF SCIENCE December 2000 Major Subject: Mechanical Engineering EVALUATION OF A SLOTTED ORIFICE PLATE FLOW METER USING HORIZONTAL TWO PHASE FLOW A Thesis by ANITA ELENA FLORES Submitted to Texas A&M University in partial fulfillment...: Mechanical Engineering ABSTRACT Fvaluation of a Slotted Orifice Plate Flow Meter Using Horizontal Two Phase Flow. (December 2000) Anita Elena Flores, B. S. , Texas A&M I Jniversitv Chair of Advisory Committee: Dr. Herald L. Morrison In the past several...

Flores, Anita Elena

2012-06-07T23:59:59.000Z

474

Flow characteristics of finite aspect ratio fences in turbulent shear flows  

E-Print Network (OSTI)

FLOW CHARACTERISTICS OF FINITE ASPECT RATIO FENCES IN TURBULENT SHEAR FLOWS A THESIS by JOSEPH RODNEY MATTE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1977 Major. Subject: Aerospace Engineering FLOW CHARACTERISTICS OF FINITE ASPECT RATIO FENCES IN TURBULENT SHEAR FLOWS A Thesis by JOSEPH RODNEY MATTE Approved as to style and content by: (Chairman of Committee) (Head...

Matte, Joseph Rodney

2012-06-07T23:59:59.000Z

475

General single phase wellbore flow model  

SciTech Connect

A general wellbore flow model, which incorporates not only frictional, accelerational and gravitational pressure drops, but also the pressure drop caused by inflow, is presented in this report. The new wellbore model is readily applicable to any wellbore perforation patterns and well completions, and can be easily incorporated in reservoir simulators or analytical reservoir inflow models. Three dimensionless numbers, the accelerational to frictional pressure gradient ratio R{sub af}, the gravitational to frictional pressure gradient ratio R{sub gf}, and the inflow-directional to accelerational pressure gradient ratio R{sub da}, have been introduced to quantitatively describe the relative importance of different pressure gradient components. For fluid flow in a production well, it is expected that there may exist up to three different regions of the wellbore: the laminar flow region, the partially-developed turbulent flow region, and the fully-developed turbulent flow region. The laminar flow region is located near the well toe, the partially-turbulent flow region lies in the middle of the wellbore, while the fully-developed turbulent flow region is at the downstream end or the heel of the wellbore. Length of each region depends on fluid properties, wellbore geometry and flow rate. As the distance from the well toe increases, flow rate in the wellbore increases and the ratios R{sub af} and R{sub da} decrease. Consequently accelerational and inflow-directional pressure drops have the greatest impact in the toe region of the wellbore. Near the well heel the local wellbore flow rate becomes large and close to the total well production rate, here R{sub af} and R{sub da} are small, therefore, both the accelerational and inflow-directional pressure drops can be neglected.

Ouyang, Liang-Biao; Arbabi, S.; Aziz, K.

1997-02-05T23:59:59.000Z

476

INTRODUCTION Few post-wildfire hazards are as potentially devastating as a debris flow. Debris flows  

E-Print Network (OSTI)

INTRODUCTION Few post-wildfire hazards are as potentially devastating as a debris flow. Debris the influence of fire, a wildfire can transform a watershed with no recent history of debris flows are developing new techniques to assess the hazards posed by debris flows after wildfires. These techniques can

477

Quantitative supersonic flow visualization by hydraulic analogy  

E-Print Network (OSTI)

The hydraulic analogy, which forms the basis for the phics. current investigation, can be used to study supersonic gas flows with great ease by means of a water table. As a result of the analogy, water heights in free surface water flow correspond...

Rani, Sarma Laxminarasimha

2012-06-07T23:59:59.000Z

478

Flow Transformations in Particulate Gravity Currents  

Science Journals Connector (OSTI)

...relevant data on the sub-aerial debris flow are that the gradient...627-637. Parker, G., Fukushima, Y., and Pantin, H.M...relevant data on the sub-aerial debris flow are that the gradient...p. 627637. PARKER, G., FUKUSHIMA, Y., AND PANTIN, H.M...

Dave Waltham

479

Integrable magnetic geodesic flows on Lie groups  

E-Print Network (OSTI)

Right-invariant geodesic flows on manifolds of Lie groups associated with 2-cocycles of corresponding Lie algebras are discussed. Algebra of integrals of motion for magnetic geodesic flows is considered and necessary and sufficient condition of integrability in quadratures is formulated. Canonic forms for 2-cocycles of all 4-dimensional Lie algebras are given and integrable cases among them are separated.

Alexey A. Magazev; Igor V. Shirokov; Yuriy Y. Yurevich

2011-11-03T23:59:59.000Z

480

Scaling bounds on dissipation in turbulent flows  

E-Print Network (OSTI)

We present a new rigorous method for estimating statistical quantities in fluid dynamics such as the (average) energy dissipation rate directly from the equations of motion. The method is tested on shear flow, channel flow, Rayleigh--B\\'enard convection and porous medium convection.

Seis, Christian

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
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481

HYPERSONIC FLOW COMPUTATIONS ON UNSTRUCTURED MESHES  

E-Print Network (OSTI)

97--0625 HYPERSONIC FLOW COMPUTATIONS ON UNSTRUCTURED MESHES K. L. Bibb \\Lambda NASA Langley hypersonic flow over complex configurations using unstructured meshes is presented. The unstructured grid for a sphere­cone configuration at Mach numbers of 5.25 and 10.6, and a complex hypersonic re­entry vehicle

Peraire, Jaime

482

Flow through electrode with automated calibration  

DOE Patents (OSTI)

The present invention is an improved automated flow through electrode liquid monitoring system. The automated system has a sample inlet to a sample pump, a sample outlet from the sample pump to at least one flow through electrode with a waste port. At least one computer controls the sample pump and records data from the at least one flow through electrode for a liquid sample. The improvement relies upon (a) at least one source of a calibration sample connected to (b) an injection valve connected to said sample outlet and connected to said source, said injection valve further connected to said at least one flow through electrode, wherein said injection valve is controlled by said computer to select between said liquid sample or said calibration sample. Advantages include improved accuracy because of more frequent calibrations, no additional labor for calibration, no need to remove the flow through electrode(s), and minimal interruption of sampling.

Szecsody, James E [Richland, WA; Williams, Mark D [Richland, WA; Vermeul, Vince R [Richland, WA

2002-08-20T23:59:59.000Z

483

Liquid Crystal Microfluidics for Tunable Flow Shaping  

Science Journals Connector (OSTI)

We explore the flow of a nematic liquid crystal in microfluidic channels with a rectangular cross section through experiments and numerical modeling. The flow profile and the liquid crystal orientational profile show three distinct regimes of weak, medium, and strong flow as the driving pressure is varied. These are identified by comparing polarizing optical microscopy experiments and numerical solutions of the nematofluidic equations of motion. The relative stability of the regimes is related to the de Gennes characteristic shear-flow lengths e1 and e2, together with the channel’s aspect ratio w/d. Finally, we show that the liquid crystalline microfluidic flow can be fully steered from left to right of a simple microchannel by applying transverse temperature gradients.

Anupam Sengupta; Uroš Tkalec; Miha Ravnik; Julia M. Yeomans; Christian Bahr; Stephan Herminghaus

2013-01-25T23:59:59.000Z

484

Rapidity Dependence of Elliptic Flow at RHIC  

E-Print Network (OSTI)

The measured elliptic flow (v2) of identified particles as a function of pT and centrality at RHIC suggests the created medium in Au+Au collisions achieves early local thermal equilibrium that is followed by hydrodynamic expansion. It is not known if the eta dependence on v2 is a general feature of elliptic flow or reflects other changes in the particle spectra in going from mid-rapidity to foward rapidities. The BRAHMS experiment provides a unique capability compared to the other RHIC experiments to measure v2 for identified particles over a wide rapidity range. From Run 4 Au+Au collision at sqrt{s_{NN}} = 200GeV, identified elliptic flow is studied using the BRAHMS spectrometers, which cover 0flow and to measure the pT-integrated flow for charged hadrons.

Erik Johnson

2006-01-04T23:59:59.000Z

485

Commodity Flow Survey | Data.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Commodity Flow Survey Commodity Flow Survey BusinessUSA Data/Tools Apps Challenges Let's Talk BusinessUSA You are here Data.gov » Communities » BusinessUSA » Data Commodity Flow Survey Dataset Summary Description The Commodity Flow Survey provides information on commodities shipped, their value, weight, and mode of transportation, as well as the origin and destination of shipments of commodities from manufacturing, mining, wholesale, and selected retail and services establishments. It is undertaken through a partnership between the Bureau of the Census, U.S. Department of Commerce, and the Bureau of Transportation Statistics, Research and Innovative Technology Administration. Tags {cfc,commodity,flow," federal",state,local,transportation,facilities,services,energy,safety,environment,Mining,Manufacturing,Wholesale,trade,Retail,Services,auxiliary,establishments,warehouses,industries,export,shipment,distance,tons,weight,hazardous,miles,ton-miles,destination,industry,hazard,ship,intrastate,interstate,"UN number",packaging,"TIH number",u.s.,metropolitan}

486

Valve for controlling solids flow  

DOE Patents (OSTI)

A fluidized solids control valve is disclosed that is particularly well adapted for use with a flow of coal or char that includes both large particles and fines. The particles may or may not be fluidized at various times during the operation. The valve includes a tubular body that terminates in a valve seat covered by a normally closed closure plate. The valve body at the seat and the closure plate is provided with aligned longitudinal slots that receive a pivotally supported key plate. The key plate is positionable by an operator in inserted, intermediate and retracted positions respecting the longitudinal slot in the valve body. The key plate normally closes the slot within the closure plate but is shaped and aligned obliquely to the longitudinal slot within the valve body to provide progressively increasing slot openings between the inserted and retracted positions. Transfer members are provided between the operator, key plate and closure plate to move the closure plate into an open position only when the key plate is retracted from the longitudinal slot within the valve body.

Feldman, David K. (Fairlawn, NJ)

1980-01-01T23:59:59.000Z

487

Cross flow electrofilter and method  

DOE Patents (OSTI)

A filter for clarifying carbonaceous liquids containing finely divided solid particles of, for instance, unreacted coal, ash and other solids discharged from a coal liquefaction process is presented. The filter includes two passageways separated by a porous filter medium. In one preferred embodiment the filter medium is of tubular shape to form the first passageway and is enclosed within an outer housing to form the second passageway within the annulus. An electrode disposed in the first passageway, for instance along the tube axis, is connected to a source of high voltage for establishing an electric field between the electrode and the filter medium. Slurry feed flows through the first passageway tangentially to the surfaces of the filter medium and the electrode. Particles from the feed slurry are attracted to the electrode within the first passageway to prevent plugging of the porous filter medium while carbonaceous liquid filters into the second passageway for withdrawal. Concentrated slurry is discharged from the first passageway at an end opposite to the feed slurry inlet. Means are also provided for the addition of diluent and a surfactant into the slurry to control relative permittivity and the electrophoretic mobility of the particles.

Gidaspow, Dimitri (Northbrook, IL); Lee, Chang H. (Chicago, IL); Wasan, Darsh T. (Westmont, IL)

1981-01-01T23:59:59.000Z

488

Classification of Two-Phase Flow Patterns by Ultrasonic Sensing  

E-Print Network (OSTI)

in addition to several other factors such as the bulk flow rate, fluid properties, and flow boundary conditions [1]. Characterization of flow patterns and identification of the associ- ated flow regimes instrumentation, both for void fraction identification and flow pattern classification. High-speed photog- raphy

Ray, Asok

489

Constraints on flow regimes in wide-aperture fractures  

SciTech Connect

In recent years, significant advances have been made in our understanding of the complex flow processes in individual fractures, aided by flow visualization experiments and conceptual modeling efforts. These advances have led to the recognition of several flow regimes in individual fractures subjected to different initial and boundary conditions. Of these, the most important regimes are film flow, rivulet flow, and sliding of droplets. The existence of such significantly dissimilar flow regimes has been a major hindrance in the development of self-consistent conceptual models of flow for single fractures that encompass all the flow regimes. The objective of this study is to delineate the existence of the different flow regimes in individual fractures. For steady-state flow conditions, we developed physical constraints on the different flow regimes that satisfy minimum energy configurations, which enabled us to segregate the wide range of fracture transmissivity (volumetric flow rate per fracture width) into several flow regimes. These are, in increasing order of flow rate, flow of adsorbed films, flow of sliding drops, rivulet flow, stable film flow, and unstable (turbulent) film flow. The scope of this study is limited to wide-aperture fractures with the flow on the opposing sides of fracture being independent.

Ghezzehei, Teamrat A.

2004-02-28T23:59:59.000Z

490

Geothermal Two-Phase Wellbore Flow: Pressure Drop Correlations and Flow Pattern Transitions  

SciTech Connect

In this paper we present some basic concepts of two-phase flow and review the Orkiszewski (1967) correlations which have been suggested by various investigators to perform well for geothermal wellbore flow situations. We also present a flow regime map based on the transition criteria used by Orkiszewski (1967) and show that most geothermal wells flow under slug flow regime. We have rearranged bubble- to slug-flow transition criterion used by Orkiszewski (1967) to show that the transition depends on the dimensionless pipe diameter number in addition to dimensionless liquid and gas velocity numbers. Our aim is also to identify what research may lead to improvements in two-phase pressure drop calculations for geothermal wellbore flow.

Ambastha, A.K.; Gudmundsson, J.S.

1986-01-21T23:59:59.000Z

491

Annular flow control safety valve  

SciTech Connect

A tubular housing having an inner tubular member forms an inner passageway inside of the inner member and an outer passageway between the inner member and the housing. The housing has valve openings leading from the outer passageway to the exterior of the housing and a tubular valve closure member telescopically moves on the interior of the housing. First means move the valve closure member in an upper direction for closing the openings and at least one actuating piston is telescopically movable within and has its longitudinal axis in the wall of the housing and engages the valve closure member. The piston is in communication with a hydraulic passageway adapted to extend to the well surface for actuating the closure member in a direction to open the valve openings. The closure member is positioned whereby upward flow through the outer passageway acts on the closure member to close the valve opening. At least one lockout piston telescopically moves within the housing and is actuated from the surface and is engageable with holding means in the housing for providing a hydraulic lockout for the valve. Shear means may be provided between the lockout piston and the housing for controlling the hydraulic lockout. A single seal is provided between the closure member and the housing and is positioned below the opening and exposed to the pressure on both sides when the valve is opened. Preferably the actuating pistons are connected to the valve closure member but the hydraulic lockout pistons engage but are unconnected to the valve closure member.

Black, P.W.; Pringle, R.E.

1981-06-16T23:59:59.000Z

492

Geologic flow characterization using tracer techniques  

SciTech Connect

A new tracer flow-test system has been developed for in situ characterization of geologic formations. This report describes two sets of test equipment: one portable and one for testing in deep formations. Equations are derived for in situ detector calibration, raw data reduction, and flow logging. Data analysis techniques are presented for computing porosity and permeability in unconfined isotropic media, and porosity, permeability and fracture characteristics in media with confined or unconfined two-dimensional flow. The effects of tracer pulse spreading due to divergence, dispersion, and porous formations are also included.

Klett, R. D.; Tyner, C. E.; Hertel, Jr., E. S.

1981-04-01T23:59:59.000Z

493

Grand valley irrigation return flow case study  

SciTech Connect

Irrigation water supply is furnished annually to about 71,500 acres of land in the Grand Valley of western Colorado. Return flows from that irrigation contribute about 780,000 tpy of salt to the Colorado River, causing an increase of 77 mg/l in the salinity concentration at Imperial Dam. A case study of water quality in this region is focused on: water quality data for irrigation and return flows/ identification of regulations that affect irrigation and return flows/ and a proposed program for controlling salinity levels. (1 map, 9 references, 8 tables)

Keys, J.W.

1981-06-01T23:59:59.000Z

494

Multiphase Flow and Cavern Abandonment in Salt  

SciTech Connect

This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

Ehgartner, Brian; Tidwell, Vince

2001-02-13T23:59:59.000Z

495

Ultrasonic flow imaging system: A feasibility study  

SciTech Connect

This report examines the feasibility and potential problems in developing a real-time ultrasonic flow imaging instrument for on-line monitoring of mixed-phased flows such as coal slurries. State-of-the-art ultrasonic imaging techniques are assessed for this application. Reflection and diffraction tomographies are proposed for further development, including image-reconstruction algorithms and parallel processing systems. A conventional ultrasonic C-scan technique is used to demonstrate the feasibility of imaging the particle motion in a solid/water flow. 13 refs., 11 figs.

Sheen, S.H.; Lawrence, W.P.; Chien, H.T.; Raptis, A.C.

1991-09-01T23:59:59.000Z

496

Mass Dependence of Directed Collective Flow  

SciTech Connect

Sidewards directed fragment flow has been extracted for {sup 84}Kr+{sup 197}Au collisions at {ital E}/{ital A}=200 MeV, using techniques that are free of reaction plane dispersion. The fragment flow per nucleon increases with mass, following a thermal or coalescencelike behavior, and attains roughly constant limiting values at 4{le}{ital A}{le}12. Comparisons of the impact parameter dependences of the measured coalescence-invariant proton flow to Boltzmann-Uehling-Uhlenbeck calculations clearly favor a momentum dependent nuclear mean field. {copyright} {ital 1996 The American Physical Society.}

Huang, M.J.; Lemmon, R.C.; Daffin, F.; Lynch, W.G.; Schwarz, C.; Tsang, M.B.; Williams, C.; Danielewicz, P.; Haglin, K.; Bauer, W.; Carlin, N.; Charity, R.J.; de Souza, R.T.; Gelbke, C.K.; Hsi, W.C.; Kunde, G.J.; Lemaire, M.; Lisa, M.A.; Lynen, U.; Peaslee, G.F.; Pochodzalla, J.; Sann, H.; Sobotka, L.G.; Souza, S.R.; Trautmann, W. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, Michigan 48824 (United States)] [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, Michigan 48824 (United States); [Laboratoire National SATURNE, CEN Saclay, 91191 Gif-sur-Yvette Cedex (France); [Department of Chemistry, Washington University, St. Louis, Missouri 63130 (United States); [Gesellschaft fuer Schwerionenforschung, D-6100 Darmstadt 11 (Germany); [Indiana Universi