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Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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1

A Stable Vanadium Redox-Flow Battery with High Energy Density...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stable Vanadium Redox-Flow Battery with High Energy Density for Large-scale Energy Storage. A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-scale Energy...

2

Numerical modeling of an all vanadium redox flow battery.  

SciTech Connect (OSTI)

We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.

Clausen, Jonathan R.; Brunini, Victor E.; Moffat, Harry K.; Martinez, Mario J.

2014-01-01T23:59:59.000Z

3

In-situ Investigation of Vanadium Ion Transport in Redox Flow Battery  

SciTech Connect (OSTI)

We will show a new method to differentiate the vanadium transport from concentration gradient and that from electric field. Flow batteries with vanadium and iron redox couples as the electro-active species were employed to investigate the transport behavior of vanadium ions in the presence of electric field. It was shown that electric field accelerated the positive-to-negative and reduced the negative-to-positive vanadium ions transport in charge process and affected the vanadium ions transport in an opposite way in discharge process. In addition, a method was designed to differentiate the concentration gradient-driven vanadium ions diffusion and electric field-driven vanadium ions migration. Simplified mathematical model was established to simulate the vanadium ions transport in real charge-discharge operation of flow battery. The concentration gradient diffusion coefficients and electric-migration coefficients of V2+, V3+, VO2+, and VO2+ across Nafion membrane were obtained by fitting the experimental data.

Luo, Qingtao; Li, Liyu; Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Chen, Baowei; Yang, Zhenguo

2012-06-27T23:59:59.000Z

4

Membraneless Vanadium Redox Fuel Cell Using Laminar Flow Rosaria Ferrigno, Abraham D. Stroock, Thomas D. Clark, Michael Mayer, and  

E-Print Network [OSTI]

Membraneless Vanadium Redox Fuel Cell Using Laminar Flow Rosaria Ferrigno, Abraham D. Stroock This communication describes a small redox fuel cell fabricated using a design that omits the membrane normally used this concept by operating a millimeter-scale redox fuel cell that uses the redox couples V(V)/V(IV) (cathodic

Prentiss, Mara

5

Concentration Dependence of VO2+ Crossover of Nafion for Vanadium Redox Flow Batteries  

SciTech Connect (OSTI)

The VO2+ crossover, or permeability, through Nafion in a vanadium redox flow battery (VRFB) was monitored as a function of sulfuric acid concentration and VO2+ concentration. A vanadium rich solution was flowed on one side of the membrane through a flow field while symmetrically on the other side a blank or vanadium deficit solution was flowed. The blank solution was flowed through an electron paramagnetic resonance (EPR) cavity and the VO2+ concentration was determined from the intensity of the EPR signal. Concentration values were fit using a solution of Fick s law that allows for the effect of concentration change on the vanadium rich side. The fits resulted in permeability values of VO2+ ions across the membrane. Viscosity measurements of many VO2+ and H2SO4 solutions were made at 30 60 C. These viscosity values were then used to determine the effect of the viscosity of the flowing solution on the permeability of the ion. 2013 The Electrochemical Society. [DOI: 10.1149/2.004306jes] All rights reserved.

Lawton, Jamie [University of Tennessee, Knoxville (UTK); Jones, Amanda [University of Tennessee, Knoxville (UTK); Zawodzinski, Thomas A [ORNL

2013-01-01T23:59:59.000Z

6

Investigation of Local Environments in Nafion-SiO2 Composite Membranes used in Vanadium Redox Flow Batteries  

SciTech Connect (OSTI)

The proton conducting polymer composite membranes are of technological interest in many energy devices such as fuel cells and redox flow batteries. In particular, the polymer composite membranes such as SiO2 incorporated Nafion membranes are recently reported as highly promising for the redox flow batteries. However, there is conflicting reports regarding the performance of this Nafion-SiO2 composite membrane in the redox flow cell. This paper presents results of the analysis of the Nafion-SiO2 composite membrane used in a vanadium redox flow battery by nuclear magnetic resonance (NMR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Fourier Transformed Infra Red (FTIR) spectroscopy, and ultraviolet visible spectroscopy. The XPS study reveals the chemical identity and environment of vanadium cations accumulated at the surface. On the other hand, the 19F and 29Si NMR measurement explores the nature of the interaction between the silica particles, Nafion side chains and diffused vanadium cations. The 29Si NMR shows that the silica particles interaction via hydrogen bonds to the sulfonic groups of Nafion and diffused vanadium cations. Based on these spectroscopic studies, the chemical environment of the silica particles inside the Nafion membrane and their interaction with diffusing vanadium cations during flow cell operations are discussed. This study discusses the origin of performance degradation of the Nafion-SiO2 composite membrane materials in vanadium redox flow batteries.

Vijayakumar, M.; Schwenzer, Birgit; Kim, Soowhan; Yang, Zhenguo; Thevuthasan, Suntharampillai; Liu, Jun; Graff, Gordon L.; Hu, Jian Z.

2012-04-01T23:59:59.000Z

7

Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications  

SciTech Connect (OSTI)

Redox flow batteries (RFBs) are capable of reversible conversion between electricity and chemical energy. Potential RFB applications resolve around mitigating the discrepancy between electricity production and consumption to improve the stability and utilization of the power infrastructure and tackling the intermittency of renewables such as photovoltaics or wind turbines to enable their reliable integration [1, 2]. Because the energy is stored in externally contained liquid electrolytes and the energy conversion reactions take place at the electrodes, RFBs hold a unique capability to separate energy and power and thus possess considerable design flexibility to meet either energy management driven or power rating oriented grid applications, which is considered to be a unparalleled advantage over conventional solid-state secondary batteries [3]. Other advantages of RFBs include fast response to load changes, high round-trip efficiency, long calender and cycle lives, safe operations, tolerance to deep discharge, etc. [4]. Among various flow battery chemistries, all-vanadium redox flow battery (VRB) was invented by Maria Skyllas-Kazacos at the University of New South Wales in the 1980s [5, 6] and have attracted substantial attention in both research and industrial communities today [7, 8]. A well-recognized advantage that makes VRB stands out among other redox chemistries is the reduced crossover contamination ascribed to employing four different oxidation states of the same vanadium element as the two redox couples. Recently, great progress has led to remarkably improved energy density of VRB by using sulfuric-chloric mixed acid supporting electrolytes that were stable at 2.5M vanadium and had wider operational temperature window of -5~50oC [9], compared with the traditional sulfuric acid VRB system [10].

Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

2013-04-22T23:59:59.000Z

8

Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for Vanadium Redox Flow Battery  

SciTech Connect (OSTI)

The vanadium (IV) electrolyte solutions with various vanadium concentrations are studied by variable temperature 1H and 17O Nuclear Magnetic Resonance (NMR) spectroscopy. The structure and kinetics of vanadium (IV) species in the electrolyte solutions are explored with respect to vanadium concentration and temperature. It was found that the vanadium (IV) species exist as hydrated vanadyl ion, i.e. [VO(H2O)5]2+ forming an octahedral coordination with vanadyl oxygen in the axial position and the remaining positions occupied by water molecules. This hydrated vanadyl ion structure is stable in vanadium concentrations up to 3M and in the temperature range of 240 to 340 K. The sulfate anions in the electrolyte solutions are found to be weekly bound to this hydrated vanadyl ion and occupies its second coordination sphere. The possible effects of these sulfate anions in proton and water exchange between vanadyl ion and solvent molecules are discussed based on 1H and 17O NMR results.

Vijayakumar, M.; Burton, Sarah D.; Huang, Cheng; Li, Liyu; Yang, Zhenguo; Graff, Gordon L.; Liu, Jun; Hu, Jian Z.; Skyllas-Kazacos, Maria

2010-11-15T23:59:59.000Z

9

Nanoporous Polytetrafluoroethylene/Silica Composite Separator as a High-Performance All-Vanadium Redox Flow Battery Membrane  

SciTech Connect (OSTI)

Driven by the motivation of searching for low-cost membrane alternatives, a novel nanoporous polytetrafluoroethylene/silica composite separator has been prepared and evaluated for its use in all-vanadium mixed-acid redox flow battery. This separator consisting of silica particles enmeshed in a polytetrafluoroethylene fibril matrix has no ion exchange capacity and is featured with unique nanoporous structures, which function as the ion transport channels in redox flow battery operation, with an average pore size of 38nm and a porosity of 48%. This separator has produced excellent electrochemical performance in the all-vanadium mixed-acid system with energy efficiency delivery comparable to Nafion membrane and superior rate capability and temperature tolerance. The separator also demonstrates an exceptional capacity retention capability over extended cycling, offering additional operational latitude towards conveniently mitigating the capacity decay that is inevitable for Nafion. Because of the inexpensive raw materials and simple preparation protocol, the separator is particularly low-cost, estimated to be at least an order of magnitude more inexpensive than Nafion. Plus the proven chemical stability due to the same backbone material as Nafion, this separator possesses a good combination of critical membrane requirements and shows great potential to promote market penetration of the all-vanadium redox flow battery by enabling significant reduction of capital and cycle costs.

Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Chen, Baowei; Simmons, Kevin L.; Sprenkle, Vincent L.; Wang, Wei

2013-09-02T23:59:59.000Z

10

Resolving Losses at the Negative Electrode in All-Vanadium Redox Flow Batteries Using Electrochemical Impedance Spectroscopy  

SciTech Connect (OSTI)

We present an in situ electrochemical technique for the quantitative measurement and resolution of the ohmic, charge transfer and diffusion overvoltages at the negative electrode of an all-vanadium redox flow battery (VRFB) using electrochemical impedance spectroscopy (EIS). The mathematics describing the complex impedance of the V+2/V+3 redox reaction is derived and matches the experimental data. The voltage losses contributed by each process have been resolved and quantified at various flow rates and electrode thicknesses as a function of current density during anodic and cathodic polarization. The diffusion overvoltage was affected strongly by flow rate while the charge transfer and ohmic losses were invariant. On the other hand, adopting a thicker electrode significantly changed both the charge transfer and diffusion losses due to increased surface area. Furthermore, the Tafel plot obtained from the impedance resolved charge transfer overvoltage yielded the geometric exchange current density, anodic and cathodic Tafel slopes (135 5 and 121 5 mV/decade respectively) and corresponding transfer coefficients = 0.45 0.02 and = 0.50 0.02 in an operating cell.

Sun, Che Nan [ORNL] [ORNL; Delnick, Frank M [ORNL] [ORNL; Aaron, D [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Mench, Matthew M [ORNL] [ORNL; Zawodzinski, Thomas A [ORNL] [ORNL

2014-01-01T23:59:59.000Z

11

E-Print Network 3.0 - all-vanadium redox flow Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Redox Poise and Signaling Summary: Chloroplast Redox Poise and Signaling John F. AlIen Lund UnlPerJity, Lllnd, Sweden Chloroplasts... to give carbohydrates. Primary steps in...

12

Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for Vanadium Redox Flow Battery . Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for...

13

Redox Flow Batteries, a Review  

SciTech Connect (OSTI)

Redox flow batteries are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of redox flow batteries with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

U. Tennessee Knoxville; U. Texas Austin; McGill U; Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.; Ross, Philip N.; Gostick, Jeffrey T.; Liu, Qinghua

2011-07-15T23:59:59.000Z

14

Short communication All-vanadium redox photoelectrochemical cell: An approach to store  

E-Print Network [OSTI]

24 May 2014 Keywords: Photoelectrochemical reaction Solar energy storage Vanadium redox Solar energy the commercializable value of 30% under light of 600 nm [4]. Alternatively, solar energy storage can be realizedShort communication All-vanadium redox photoelectrochemical cell: An approach to store solar energy

Liu, Fuqiang

15

Electrochimica Acta 52 (2007) 49424946 High-performance microfluidic vanadium redox fuel cell  

E-Print Network [OSTI]

vanadium redox fuel cell Erik Kjeanga,c, Brenton T. Proctora,c, Alexandre G. Brolob,c, David A. Harringtonb a new microfluidic fuel cell design with high-surface area porous carbon electrodes and high aspect ratio channel, using soluble vanadium redox species as fuel and oxidant. The device exhibits a peak

Brolo, Alexandre G.

2007-01-01T23:59:59.000Z

16

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid Based Redox Flow Battery Electrolytes. Abstract: The Vanadium (V) cation structures in mixed acid based...

17

Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrolytes. Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium Redox Flow Battery Electrolytes. Abstract: The Vanadium (III) cation structure in mixed acid based...

18

Cost and Performance Model for Redox Flow Batteries  

SciTech Connect (OSTI)

A cost model was developed for all vanadium and iron-vanadium redox flow batteries. Electrochemical performance modeling was done to estimate stack performance at various power densities as a function of state of charge. This was supplemented with a shunt current model and a pumping loss model to estimate actual system efficiency. The operating parameters such as power density, flow rates and design parameters such as electrode aspect ratio, electrolyte flow channel dimensions were adjusted to maximize efficiency and minimize capital costs. Detailed cost estimates were obtained from various vendors to calculate cost estimates for present, realistic and optimistic scenarios. The main drivers for cost reduction for various chemistries were identified as a function of the energy to power ratio of the storage system. Levelized cost analysis further guided suitability of various chemistries for different applications.

Viswanathan, Vilayanur V.; Crawford, Aladsair J.; Stephenson, David E.; Kim, Soowhan; Wang, Wei; Li, Bin; Coffey, Greg W.; Thomsen, Edwin C.; Graff, Gordon L.; Balducci, Patrick J.; Kintner-Meyer, Michael CW; Sprenkle, Vincent L.

2014-02-01T23:59:59.000Z

19

Cascade redox flow battery systems  

DOE Patents [OSTI]

A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

2014-07-22T23:59:59.000Z

20

Advanced Redox Flow Batteries for Stationary Electrical Energy Storage  

SciTech Connect (OSTI)

This report describes the status of the advanced redox flow battery research being performed at Pacific Northwest National Laboratories for the U.S. Department of Energy’s Energy Storage Systems Program. The Quarter 1 of FY2012 Milestone was completed on time. The milestone entails completion of evaluation and optimization of single cell components for the two advanced redox flow battery electrolyte chemistries recently developed at the lab, the all vanadium (V) mixed acid and V-Fe mixed acid solutions. All the single cell components to be used in future kW-scale stacks have been identified and optimized in this quarter, which include solution electrolyte, membrane or separator; carbon felt electrode and bi-polar plate. Varied electrochemical, chemical and physical evaluations were carried out to assist the component screening and optimization. The mechanisms of the battery capacity fading behavior for the all vanadium redox flow and the Fe/V battery were discovered, which allowed us to optimize the related cell operation parameters and continuously operate the system for more than three months without any capacity decay.

Li, Liyu; Kim, Soowhan; Xia, Guanguang; Wang, Wei; Yang, Zhenguo

2012-03-19T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Redox flow batteries based on supporting solutions containing chloride  

DOE Patents [OSTI]

Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-01-14T23:59:59.000Z

22

Redox Flow Batteries: An Engineering Perspective  

SciTech Connect (OSTI)

Redox flow batteries are well suited to provide modular and scalable energy storage systems for a wide range of energy storage applications. In this paper, we review the development of redox flow battery technology including recent advances in new redox active materials and systems. We discuss cost, performance, and reliability metrics that are critical for deployment of large flow battery systems. The technology, while relatively young, has the potential for significant improvement through reduced materials costs, improved energy and power efficiency, and significant reduction in the overall system cost.

Chalamala, Babu R.; Soundappan, Thiagarajan; Fisher, Graham R.; Anstey, Mitchell A.; Viswanathan, Vilayanur V.; Perry, Mike L.

2014-10-01T23:59:59.000Z

23

High energy density redox flow device  

DOE Patents [OSTI]

Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan Y; Duduta, Mihai; Limthongkul, Pimpa

2014-05-13T23:59:59.000Z

24

Rebalancing electrolytes in redox flow battery systems  

DOE Patents [OSTI]

Embodiments of redox flow battery rebalancing systems include a system for reacting an unbalanced flow battery electrolyte with a rebalance electrolyte in a first reaction cell. In some embodiments, the rebalance electrolyte may contain ferrous iron (Fe.sup.2+) which may be oxidized to ferric iron (Fe.sup.3+) in the first reaction cell. The reducing ability of the rebalance reactant may be restored in a second rebalance cell that is configured to reduce the ferric iron in the rebalance electrolyte back into ferrous iron through a reaction with metallic iron.

Chang, On Kok; Pham, Ai Quoc

2014-12-23T23:59:59.000Z

25

Fe-V redox flow batteries  

DOE Patents [OSTI]

A redox flow battery having a supporting solution that includes Cl.sup.- anions is characterized by an anolyte having V.sup.2+ and V.sup.3+ in the supporting solution, a catholyte having Fe.sup.2+ and Fe.sup.3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO.sub.4.sup.2- and Cl.sup.- anions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-07-08T23:59:59.000Z

26

High energy density redox flow device  

DOE Patents [OSTI]

Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

Chiang, Yet-Ming; Carter, William Craig; Duduta, Mihai; Limthongkul, Pimpa

2014-05-13T23:59:59.000Z

27

Iron-sulfide redox flow batteries  

DOE Patents [OSTI]

Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

2013-12-17T23:59:59.000Z

28

Fact Sheet: Vanadium Redox Flow Batteries (October 2012)  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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29

Fact Sheet: Vanadium Redox Flow Batteries (October 2012) | Department of  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office of Audit|Department ofof EnergyUnited States- Dataset2012)Fact Sheet:Energy

30

Recent Progress in Redox Flow Battery Research and Development  

SciTech Connect (OSTI)

With the increase need to seamlessly integrate the renewable energy with the current grid which itself is evolving into a more intelligent, efficient, and capable electrical power system, it is envisioned that the energy storage system will play a more prominent role in bridging the gap between the current technology and a clean sustainable future in grid reliability and utilization. Redox flow battery technology is leading the way in this perspective in providing a well balanced approach for current challenges. Recent progress in the research and development of redox flow battery technology is reviewed here with a focus on new chemistries and systems.

Wang, Wei; Luo, Qingtao; Li, Bin; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

2013-02-20T23:59:59.000Z

31

Anthraquinone with Tailored Structure for Nonaqueous Metal-Organic Redox Flow Battery  

SciTech Connect (OSTI)

A nonaqueous, hybrid metal-organic redox flow battery based on tailored anthraquinone structure is demonstrated to have an energy efficiency of {approx}82% and a specific discharge energy density similar to aqueous redox flow batteries, which is due to the significantly improved solubility of anthraquinone in supporting electrolytes.

Wang, Wei; Xu, Wu; Cosimbescu, Lelia; Choi, Daiwon; Li, Liyu; Yang, Zhenguo

2012-06-08T23:59:59.000Z

32

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries  

SciTech Connect (OSTI)

We will present a novel design lithium-organic non-aqueous redox flow battery based on a TEMPO catholyte. This RFB produced desired electrochemical performance exceeding most of the currently reported nonaqueous RFB systems.

Wei, Xiaoliang; Xu, Wu; Vijayakumar, M.; Cosimbescu, Lelia; Liu, Tianbiao L.; Sprenkle, Vincent L.; Wang, Wei

2014-12-03T23:59:59.000Z

33

Redox and ATP control of photosynthetic cyclic electron flow in Chlamydomonas reinhardtii (I) aerobic conditions  

E-Print Network [OSTI]

Redox and ATP control of photosynthetic cyclic electron flow in Chlamydomonas reinhardtii (I, requires the production of ATP and NADPH in a ratio of 3:2. The oxygenic photosynthetic chain can function following two different modes: the linear electron flow which produces reducing power and ATP

34

Vanadium redox-flow batteries Installation at Ris for characterisation measurements  

E-Print Network [OSTI]

and investigating distributed power systems. SYSLAB consists of two wind turbines, a pv-array, a diesel genset features including independent sizing of power and energy capacity, long lifetime, high efficiency and fast in August 2007. Power systems with high penetration of Wind energy/Renewable energy Renewable energy

35

Vanadium-redox flow and lithium-ion battery modelling and performance in wind energy applications.  

E-Print Network [OSTI]

??As wind energy penetration levels increase, there is a growing interest in using storage devices to aid in managing the fluctuations in wind turbine output… (more)

Chahwan, John A.

2007-01-01T23:59:59.000Z

36

A Stable Vanadium Redox-Flow Battery with High Energy Density for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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37

Nanorod Niobium Oxide as Powerful Catalysts for an All Vanadium Redox Flow  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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38

Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium Redox Flow  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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39

Membrane Separator for Redox Flow Batteries that Utilize Anion Radical Mediators.  

SciTech Connect (OSTI)

A Na + ion conducting polyethylene oxide membrane is developed for an organic electrolyte redox flow battery that utilizes anion radical mediators. To achieve high specific ionic conductivity, tetraethyleneglycol dimethylether (TEGDME) is used as a plasticizer to reduce crystallinity and increase the free volume of the gel film. This membrane is physically and chemically stable in TEGDME electrolyte that contains highly reactive biphenyl anion radical mediators.

Delnick, Frank M.

2014-10-01T23:59:59.000Z

40

E-Print Network 3.0 - all-uranium redox flow Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Redox Poise and Signaling Summary: Chloroplast Redox Poise and Signaling John F. AlIen Lund UnlPerJity, Lllnd, Sweden Chloroplasts... to give carbohydrates. Primary steps in...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Application of Flow Battery in Marine Current Turbine System for Daily Power Management  

E-Print Network [OSTI]

focuses on a grid-connected MCT system and proposes using vanadium redox flow battery (VRB) energy storage/energy sizing. In this paper, one grid-connected MCT generation system with battery energy storage system (BESSApplication of Flow Battery in Marine Current Turbine System for Daily Power Management Zhibin Zhou

Brest, Université de

42

Optimization of electrode characteristics for the Br2/H2 redox flow cell  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The Br2/H2 redox flow cell shows promise as a high-power, low-cost energy storage device. The effect of various aspects of material selection, processing, and assembly of electrodes on the operation, performance, and efficiency of the system is determined. In particular, (+) electrode thickness, cell compression, hydrogen pressure, and (?) electrode architecture are investigated. Increasing hydrogen pressure and depositing the (?) catalyst layer on the membrane instead of on the carbon paper backing layers have a large positive impact on performance, enabling a limiting current density above 2 A cm?2 and a peak power density of 1.4 W cm?2. Maximum energy efficiency of 79 % is achieved. In addition, the root cause of limiting-current behavior in this system is elucidated, where it is found that Br? reversibly adsorbs at the Pt (?) electrode for potentials exceeding a critical value, and the extent of Br? coverage is potential-dependent. This phenomenon limits maximum cell current density and must be addressed in system modeling and design. These findings are expected to lower system cost and enable higher efficiency.

Tucker, Michael C.; Cho, Kyu Taek; Weber, Adam Z.; Lin, Guangyu; Nguyen, Trung V.

2014-10-01T23:59:59.000Z

43

The fabrication of a vanadium-stainless steel test section for MHD testing of insulator coatings in flowing lithium  

SciTech Connect (OSTI)

To test the magnetohydrodynamic (MHD) pressure drop reduction performance of candidate insulator coatings for the ITER Vanadium/Lithium Breeding Blanket, a test section comprised of a V- 4Cr-4Ti liner inside a stainless steel pipe was designed and fabricated. Theoretically, the MHD pressure drop reduction benefit resulting, from an electrically insulating coating on a vanadium- lined pipe is identical to the benefit derived from an insulated pipe fabricated of vanadium alone. A duplex test section design consisting of a V alloy liner encased in a SS pressure boundary provided protection for vanadium from atmospheric contamination during operation at high temperature and obviated any potential problems with vanadium welding while also minimizing the amount of V alloy material required. From the MHD and insulator coating- point of view, the test section outer SS wall and inner V alloy liner can be modeled simply as a wall having a sandwich construction. Two 52.3 mm OD x 2.9 m long V-alloy tubes were fabricated by Century Tubes from 64 mm x 200 mm x 1245 mm extrusions produced by Teledyne Wah Chang. The test section`s duplex structure was subsequently fabricated at Century Tubes by drawing down a SS pipe (2 inch schedule 10) over one of the 53.2 mm diameter V tubes.

Reed, C.B.; Mattas, R.F.; Smith, D.L.; Chung, H.; Tsai, H.-C. [Argonne National Lab., IL (United States); Morgan, G.D.; Wille, G.W. [McDonnell Douglas Aerospace, St. Louis, MO (United States). High Energy Systems; Johnson, W.R. [General Atomics, San Diego, CA (United States); Young, C. [Century Tubes, Inc., San Diego, CA (United States)

1996-12-31T23:59:59.000Z

44

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries. TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow Batteries. Abstract: We will...

45

Upgrading the Vanadium Redox Battery | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEM with EDAXUpdated CapitalMichaelUpgrading

46

What's Next for Vanadium Dioxide?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy...

47

Facile synthesized nanorod structured vanadium pentoxide for...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

synthesized nanorod structured vanadium pentoxide for high-rate lithium batteries. Facile synthesized nanorod structured vanadium pentoxide for high-rate lithium batteries....

48

Fact Sheet: Vanadium Redox Battery Demonstration Program (August 2013) |  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomentheATLANTA, GA5 &ofDepartment of Energy On NovemberofGlobal

49

City of Painesville, Ohio Vanadium Redox Battery Demonstration Program  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana. DOCUMENTS AVAILABLE FORSuperior Energy5-1Denver EnergyCity of Painesville,

50

Spectroscopic Investigations of the Fouling Process on Nafion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigations of the Fouling Process on Nafion Membranes in Vanadium Redox Flow Batteries. Spectroscopic Investigations of the Fouling Process on Nafion Membranes in Vanadium...

51

Method for preparing high purity vanadium  

SciTech Connect (OSTI)

A method is described of preparing high-purity, low-silicon vanadium metal from vanadium pentoxide containing silicon, iron and other impurities comprising: mixing the vanadium pentoxide with aluminum to form a reaction mixture, the quantity of aluminum in the mixture being from about stoichiometric to about 10% deficient in the amount necessary to completely reduce the vanadium pentoxide to vanadium metal: heating the mixture under reducing conditions to a temperature sufficient to react the mixture to reduce the vanadium pentoxide and form a vanadium-aluminum alloy containing silicon, iron and from about 0.6 to about 3 weight percent oxygen; heating the alloy under reduced pressure to a temperature sufficient to vaporize the aluminum and iron in the alloy and to react the silicon with some of the oxygen to form volatile silicon monoxide which vaporizes away from the alloy thereby removing aluminum, iron, silicon and some of the oxygen from the vanadium metal, and heating the vanadium metal in the presence of calcium metal to a temperature and for a period of time sufficient for the oxygen to diffuse from the vanadium and react with the calcium to form calcium oxide, thereby removing oxygen from the vanadium metal, forming a high-purity, low-silicon vanadium metal.

Schmidt, F.; Carlson, O.N.

1986-09-09T23:59:59.000Z

52

Redox Flow Batteries, a Review  

E-Print Network [OSTI]

or novel hydrogen-storage materials are is needed. Althoughof storage tank volume, and thus hydrogen compression

Weber, Adam Z.

2013-01-01T23:59:59.000Z

53

Redox Flow Batteries, a Review  

E-Print Network [OSTI]

and water. For a fuel cell, hydrogen oxidizes at the anode5. 2.1.5 Hydrogen-based systems A fuel cell takes a fuel (

Weber, Adam Z.

2013-01-01T23:59:59.000Z

54

Effects of additives on the stability of electrolytes for all...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries. Effects of additives on the stability of electrolytes for all-vanadium redox flow...

55

Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanodispersed Oxides of Vanadium, Titanium, Molybdenum, and Tungsten on Mesoporous Silica using Atomic Layer Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum,...

56

Final Report - Crystal Settling, Redox, and High Temperature Properties of ORP HLW and LAW Glasses, VSL-09R1510-1, Rev. 0, dated 6/18/09  

SciTech Connect (OSTI)

The radioactive tank waste treatment programs at the U. S. Department of Energy (DOE) have featured joule heated ceramic melter technology for the vitrification of high level waste (HLW). The Hanford Tank Waste Treatment and Immobilization Plant (WTP) employs this same basic technology not only for the vitrification of HLW streams but also for the vitrification of Low Activity Waste (LAW) streams. Because of the much greater throughput rates required of the WTP as compared to the vitrification facilities at the West Valley Demonstration Project (WVDP) or the Defense Waste Processing Facility (DWPF), the WTP employs advanced joule heated melters with forced mixing of the glass pool (bubblers) to improve heat and mass transport and increase melting rates. However, for both HLW and LAW treatment, the ability to increase waste loadings offers the potential to significantly reduce the amount of glass that must be produced and disposed and, therefore, the overall project costs. This report presents the results from a study to investigate several glass property issues related to WTP HLW and LAW vitrification: crystal formation and settling in selected HLW glasses; redox behavior of vanadium and chromium in selected LAW glasses; and key high temperature thermal properties of representative HLW and LAW glasses. The work was conducted according to Test Plans that were prepared for the HLW and LAW scope, respectively. One part of this work thus addresses some of the possible detrimental effects due to considerably higher crystal content in waste glass melts and, in particular, the impact of high crystal contents on the flow property of the glass melt and the settling rate of representative crystalline phases in an environment similar to that of an idling glass melter. Characterization of vanadium redox shifts in representative WTP LAW glasses is the second focal point of this work. The third part of this work focused on key high temperature thermal properties of representative WTP HLW and LAW glasses over a wide range of temperatures, from the melter operating temperature to the glass transition.

Kruger, Albert A.; Wang, C.; Gan, H.; Pegg, I. L.; Chaudhuri, M.; Kot, W.; Feng, Z.; Viragh, C.; McKeown, D. A.; Joseph, I.; Muller, I. S.; Cecil, R.; Zhao, W.

2013-11-13T23:59:59.000Z

57

Preparation of high purity vanadium  

SciTech Connect (OSTI)

The paper reviews the various reduction and refining methods that have been used to prepare vanadium metal. Earlier work on metallothermic and carbothermic reduction processes is discussed. Recent work on improving the scaling up the aluminothermic reduction process is described in detail. Iron and silicon are first removed from commercial V/sub 2/O/sub 5/ by an ion exchange separation technique and the purified oxide is then exothermically reduced with aluminum metal. The resulting V-Al ingot is heated in a vacuum to 1700/sup 0/C to remove the aluminum and dissolved oxygen, and the sponge is then electron-beam melted to remove residual volatile impurities to yield vanadium metal of 99.98% purity. Precautions taken during each processing stage to minimize carbon, nitrogen and oxygen contamination are described. Metal containing < 50 ppmw each of C, N and O, < 20 ppmw Si, and < 10 ppmw of Fe and Al has been prepared in kilogram quantities by this method. The hardness of the beam melted is 60 to 70 DPH. Experiments designed to scale up the reduction process and to increase the efficiency of the separation and melting steps are described. Various refining techniques that have been applied to the preparation of high purity vanadium are described and comparisons made between the quality of metal obtained by each.

Carlson, O.N.; Burkholder, H.R.; Martsching, G.A.; Schmidt, F.A.

1981-01-01T23:59:59.000Z

58

Vanadium catalysts break down biomass for fuels  

E-Print Network [OSTI]

- 1 - Vanadium catalysts break down biomass for fuels March 26, 2012 Vanadium catalysts break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose biomass into high-value commodity chemicals. The journal Angewandte Chemie International Edition published

59

Vanadium hydride deuterium-tritium generator  

DOE Patents [OSTI]

A pressure controlled vanadium hydride gas generator to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

Christensen, Leslie D. (Livermore, CA)

1982-01-01T23:59:59.000Z

60

High power density self-cooled lithium-vanadium blanket.  

SciTech Connect (OSTI)

A self-cooled lithium-vanadium blanket concept capable of operating with 2 MW/m{sup 2} surface heat flux and 10 MW/m{sup 2} neutron wall loading has been developed. The blanket has liquid lithium as the tritium breeder and the coolant to alleviate issues of coolant breeder compatibility and reactivity. Vanadium alloy (V-4Cr-4Ti) is used as the structural material because it can accommodate high heat loads. Also, it has good mechanical properties at high temperatures, high neutron fluence capability, low degradation under neutron irradiation, good compatibility with the blanket materials, low decay heat, low waste disposal rating, and adequate strength to accommodate the electromagnetic loads during plasma disruption events. Self-healing electrical insulator (CaO) is utilized to reduce the MHD pressure drop. A poloidal coolant flow with high velocity at the first wall is used to reduce the peak temperature of the vanadium structure and to accommodate high surface heat flux. The blanket has a simple blanket configuration and low coolant pressure to reduce the fabrication cost, to improve the blanket reliability, and to increase confidence in the blanket performance. Spectral shifter, moderator, and reflector are utilized to improve the blanket shielding capability and energy multiplication, and to reduce the radial blanket thickness. Natural lithium is used to avoid extra cost related to the lithium enrichment process.

Gohar, Y.; Majumdar, S.; Smith, D.

1999-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Methods for making lithium vanadium oxide electrode materials  

DOE Patents [OSTI]

A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

Schutts, Scott M. (Menomonie, WI); Kinney, Robert J. (Woodbury, MN)

2000-01-01T23:59:59.000Z

62

Method for preparing high purity vanadium  

DOE Patents [OSTI]

A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

Schmidt, Frederick (Ames, IA); Carlson, O. Norman (Ames, IA)

1986-09-09T23:59:59.000Z

63

Method for preparing high purity vanadium  

DOE Patents [OSTI]

A method for preparing high purity vanadium having a low silicon content has been developed. Vanadium pentoxide is reduced with a stoichiometric, or slightly deficient amount of aluminum to produce a vanadium-aluminum alloy containing an excess of oxygen. Silicon is removed by electron-beam melting the alloy under oxidizing conditions to promote the formation of SiO which is volatile at elevated temperatures. Excess oxygen is removed by heating the alloy in the presence of calcium metal to form calcium oxide.

Schmidt, F.; Carlson, O.N.

1984-05-16T23:59:59.000Z

64

Electrochemical Characterization of Vanadium Oxide Nanostructured Electrode  

E-Print Network [OSTI]

microstructures called aerogels in the case of supercritical or freeze-drying and ambigels in the case of solvent for intercalated ions.7 When cycled between 4.0 and 1.5 V, vanadium oxide aerogels achieved capaci- ties of 410 mAh/g at C/40.6 Baudrin et al. have used the vanadium oxide aerogel structure to access a metastable phase

Sadoway, Donald Robert

65

Vanadium hydride deuterium-tritium generator  

DOE Patents [OSTI]

A pressure controlled vanadium hydride gas generator was designed to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

Christensen, L.D.

1980-03-13T23:59:59.000Z

66

Anisotropic reactive ion etching of vanadium dioxide  

E-Print Network [OSTI]

. Weichold Vanadium dioxide (V02) was anisotropically reactive ion etched using carbon tetrafluoride (CF4) . CF4, as an etch gas, provided the chemistry along with the control needed to achieve an anisotropic etch. This chemistry was practically inert... with vanadium quite easily. This leads to interest in using a fluorine- based chemistry. The goal of this research is to produce a selective anisotropic reactive ion etch for VO2 /photoresist using only carbon tetrafluoride (CFq) . Reactive ion etching...

Radle, Byron K

1990-01-01T23:59:59.000Z

67

Manufacturing development of low activation vanadium alloys  

SciTech Connect (OSTI)

General Atomics is developing manufacturing methods for vanadium alloys as part of a program to encourage the development of low activation alloys for fusion use. The culmination of the program is the fabrication and installation of a vanadium alloy structure in the DIII-D tokamak as part of the Radiative Divertor modification. Water-cooled vanadium alloy components will comprise a portion of the new upper divertor structure. The first step, procuring the material for this program has been completed. The largest heat of vanadium alloy made to date, 1200 kg of V-4Cr-4Ti, has been produced and is being converted into various product forms. Results of many tests on the material during the manufacturing process are reported. Research into potential fabrication methods has been and continues to be performed along with the assessment of manufacturing processes particularly in the area of joining. Joining of vanadium alloys has been identified as the most critical fabrication issue for their use in the Radiative Divertor Program. Joining processes under evaluation include resistance seam, electrodischarge (stud), friction and electron beam welding. Results of welding tests are reported. Metallography and mechanical tests are used to evaluate the weld samples. The need for a protective atmosphere during different welding processes is also being determined. General Atomics has also designed, manufactured, and will be testing a helium-cooled, high heat flux component to assess the use of helium cooled vanadium alloy components for advanced tokamak systems. The component is made from vanadium alloy tubing, machined to enhance the heat transfer characteristics, and joined to end flanges to allow connection to the helium supply. Results are reported.

Smith, J.P.; Johnson, W.R.; Baxi, C.B.

1996-10-01T23:59:59.000Z

68

Sampling, preservation, and analytical methods research plan - liquid redox sulfur recovery technologies: Stretford process. Topical report  

SciTech Connect (OSTI)

GRI has developed a sampling, preservation, and analytical (SPandA) methods research plan for developing and validating analytical methodologies for liquid redox sulfur recovery processes (e.g., Stretford process). The document describes the technical approach which will be used to direct research activities to develop SPandA methodologies to analyze gaseous, aqueous, and solid process streams from the Stretford sulfur recovery process. The primary emphasis is on developing and validating methodologies for analyzing vanadium (IV) and vanadium (V), anthraquinone disulphonic acids (ADA), polysulfide-sulfur, sulfide-sulfur, thiosulfate, sulfate, thiocyanate, total soluble sulfur, alkalinity, pH, total dissolved solids, total suspended solids, and dissolved oxygen in aqueous process streams. The document includes descriptions of the process streams and chemical species, selection of candidate analytical methods, and technical approach for methods development and validation.

Trofe, T.W.

1986-11-01T23:59:59.000Z

69

Redox Flow Batteries - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298,NIST 800-53 RevisionDivision andIon Soft Landing.

70

Modified lithium vanadium oxide electrode materials products and methods  

DOE Patents [OSTI]

A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

Thackeray, Michael M. (Naperville, IL); Kahaian, Arthur J. (Chicago, IL); Visser, Donald R. (Naperville, IL); Dees, Dennis W. (Downers Grove, IL); Benedek, Roy (Western Springs, IL)

1999-12-21T23:59:59.000Z

71

Partitioning of hydrogen in the vanadium-lithium-hydrogen system at elevated temperatures  

SciTech Connect (OSTI)

Equilibrium concentrations of hydrogen in vanadium-base alloys exposed to flowing lithium at temperatures from 350 to 550/degree/C in a forced-circulation loop were measured by residual gas analysis and the vacuum fusion method. Residual gas analysis and removal of material from the surface allowed a determination of the spatial hydrogen distribution in the alloys. These experimental results were compared with calculated thermodynamic distribution coefficients for hydrogen in the vanadium/lithium system. Small amounts of other solutes in the molten lithium and in the alloys affected the solubility, diffusivity, and resultant distribution of hydrogen. Thermodynamic calculations demonstrated the importance of major alloying elements to the partitioning of hydrogen. 12 refs., 5 figs., 2 tabs.

Hull, A.B.; Chopra, O.K.; Loomis, B.A.; Smith, D.L.

1988-09-01T23:59:59.000Z

72

Investigation of Local Environments in Nafion-SiO2 Composite...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Local Environments in Nafion-SiO2 Composite Membranes used in Vanadium Redox Flow Batteries. Investigation of Local Environments in Nafion-SiO2 Composite Membranes used in Vanadium...

73

Short communication Effect of vanadium redox species on photoelectrochemical behavior of TiO2  

E-Print Network [OSTI]

. Alternative and sustainable energy sources such as solar, wind, tidal power, geothermal, hydroelectricity to 1 M. This finding might render this approach a very promising way of solar energy conversion are getting depleted. Among them, solar energy is considered to be the most reliable and inexhaustible source

Liu, Fuqiang

74

Irradiation creep of vanadium-base alloys.  

SciTech Connect (OSTI)

A study of irradiation creep in vanadium-base alloys is underway with experiments in the Advanced Test Reactor (ATR) and the High Flux Isotope Reactor (HFIR) in the US. Test specimens are thin-wall sealed tubes with internal pressure loading. The results from the initial ATR irradiation at low temperature (200-300 C) to a neutron damage level of 4.7 dpa show creep rates ranging from {approx}0 to 1.2 x 10{sup {minus}5}/dpa/MPa for a 500-kg heat of V-4Cr-4Ti alloy. These rates were generally lower than reported from a previous experiment in BR-10. Because both the attained neutron damage levels and the creep strains were low in the present study, however, these creep rates should be regarded as only preliminary. Substantially more testing is required before a data base on irradiation creep of vanadium alloys can be developed and used with confidence.

Tsai, H.; Matsui, H.; Billone, M. C.; Strain, R. V.; Smith, D. L.

1998-05-18T23:59:59.000Z

75

Computation of the Redox and Protonation Properties of Quinones...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Computation of the Redox and Protonation Properties of Quinones: Towards the Prediction of Redox Cycling Natural Products. Computation of the Redox and Protonation Properties of...

76

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

144 Granite Street, Worcester, MA Premium Power Distributed Energy Storage Demonstration for National Grid Install and operate 500 kW Vanadium Redox flow battery at Worcester, MA....

77

Towards Understanding the Poor Thermal Stability of V5+ Electrolyte...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Poor Thermal Stability of V5+ Electrolyte Solution in Vanadium Redox Flow Batteries. Towards Understanding the Poor Thermal Stability of V5+ Electrolyte Solution in...

78

Energy Storage for the Power Grid  

ScienceCinema (OSTI)

The iron vanadium redox flow battery was developed by researchers at Pacific Northwest National Laboratory as a solution to large-scale energy storage for the power grid.

Wang, Wei; Imhoff, Carl; Vaishnav, Dave

2014-06-12T23:59:59.000Z

79

Energy Storage for the Power Grid  

SciTech Connect (OSTI)

The iron vanadium redox flow battery was developed by researchers at Pacific Northwest National Laboratory as a solution to large-scale energy storage for the power grid.

Wang, Wei; Imhoff, Carl; Vaishnav, Dave

2014-04-23T23:59:59.000Z

80

Vanadium-pumped titanium x-ray laser  

DOE Patents [OSTI]

A resonantly photo-pumped x-ray laser is formed of a vanadium and titanium foil combination that is driven by two beams of intense line focused optical laser radiation. Ground state neon-like titanium ions are resonantly photo-pumped by line emission from fluorine-like vanadium ions. 4 figs.

Nilsen, J.

1992-05-26T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Vanadium-pumped titanium x-ray laser  

DOE Patents [OSTI]

A resonantly photo-pumped x-ray laser (10) is formed of a vanadium (12) and titanium (14) foil combination (16) that is driven by two beams (18, 20) of intense line focused (22, 24) optical laser radiation. Ground state neon-like titanium ions (34) are resonantly photo-pumped by line emission from fluorine-like vanadium ions (32).

Nilsen, Joseph (Livermore, CA)

1992-01-01T23:59:59.000Z

82

Holme et al. Soil Redox Sensor Networks RADIO FREQUENCY ENABLED SOIL REDOX POTENTIAL  

E-Print Network [OSTI]

Holme et al. Soil Redox Sensor Networks RADIO FREQUENCY ENABLED SOIL REDOX POTENTIAL SENSOR technologies that may be combined into a cost effective soil redox sensor network, discuss the merits of each as a component of said network, describe a prototype soil redox sensor network and perform basic laboratory

Rubinstein, Benjamin

83

Vanadium catalysts break down biomass for fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II FieldVacancy-InducedCloudPoissonVampire Power IsVanadium

84

Patterns of vanadium accumulation in petroleum and natural bitumen  

SciTech Connect (OSTI)

Vanadium is one of the most abundant metals in oils and natural bitumens, with concentrations ranging from 10/sup -2/ to 1.5 x 10/sup 3/ ppm in oils and to as much as 0.6% in bitumens. Vanadium contents in some oil and bitumen deposits are comparable with those of vanadium-bearing titanomagnetite ores. The authors have examined the distributions of vanadium and associated trace elements (Ni, Mo, Co, etc.) in oils and bitumens for the Volga-Ural and Timan-Pechora basins, which are petroleum-metallogenic provinces of the vanadium-nickel type. The vanadium and nickel concentrations in the oils and bitumens, in bulk and by fractions, have been determined, without ashing the samples, by X-ray fluorescence analysis using /sup 55/Fe and /sup 238/Pu radionuclides and a semiconductor spectrometer. The ash was examined by emission spectrography and X-ray structural methods. The data reveal regularities in the vanadium concentration related to the physicochemical parameters. The authors also used previously published analyses to extend the statistical sample. 16 references.

Gol'dberg, I.S.; Kaplan, Z.G.; Ponomarev, V.S.

1986-06-01T23:59:59.000Z

85

Vanadium-base alloys for fusion reactor applications  

SciTech Connect (OSTI)

Vanadium-base alloys offer potentially significant advantages over other candidate alloys as a structural material for fusion reactor first wall/blanket applications. Although the data base is more limited than that for the other leading candidate structural materials, viz., austenitic and ferritic steels, vanadium-base alloys exhibit several properties that make them particularly attractive for the fusion reactor environment. This paper presents a review of the structural material requirements, a summary of the materials data base for selected vanadium-base alloys, and a comparison of projected performance characteristics compared to other candidate alloys. Also, critical research and development (R and D) needs are defined.

Smith, D.L.; Loomis, B.A.; Diercks, D.R.

1984-10-01T23:59:59.000Z

86

Method to remove uranium/vanadium contamination from groundwater  

DOE Patents [OSTI]

A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

Metzler, Donald R. (DeBeque, CO); Morrison, Stanley (Grand Junction, CO)

2004-07-27T23:59:59.000Z

87

Overview of the vanadium alloy researches for fusion reactors  

SciTech Connect (OSTI)

Various vanadium alloys are being developed as one of the options of structural materials for advanced blankets of fusion reactors. Besides the large heats made in Japan and US, a 110 kg V-4Cr-4Ti ingot was produced in RF recently. Development of advanced vanadium alloys were also carried out, such as the ultra-fine grain alloys containing Y and that with W and TiC strengthening particles. Investigations were performed for further widening of temperature and mechanical application windows of the reference V-4Cr-4Ti alloy by plastic deformation and heat treatments. Neutron irradiation effects combined with lithium corrosion were studied. In addition, some efforts are oriented to issues related to DEMO blanket manufacturing technology, such as W coating for first wall protection and the welding technologies to fabricate large vanadium component. This paper highlights the recent activities of these vanadium alloy researches, discusses the critical issues and summarizes the remaining issues to be addressed.

Chen, J. M.; Chernov, V. M.; Kurtz, Richard J.; Muroga, Takeo

2011-03-05T23:59:59.000Z

88

Method to Remove Uranium/Vanadium Contamination from Groundwater  

DOE Patents [OSTI]

A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

Metzler, Donald R.; Morrison Stanley

2004-07-27T23:59:59.000Z

89

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network [OSTI]

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

90

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Redox Shuttles for Overcharge Protection of Lithium-Ion Batteries Technology available for licensing: Electrolytes containing novel redox shuttles (electron transporters) for...

91

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft Landing. Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft...

92

Redox reactions of reduced flavin mononucleotide (FMN), riboflavin...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Redox reactions of reduced flavin mononucleotide (FMN), riboflavin (RBF), and anthraquinone-2,6-disulfonate (AQDS) with Redox reactions of reduced flavin mononucleotide (FMN),...

93

Electroslag remelting of a vanadium alloy  

SciTech Connect (OSTI)

The Bureau of Mines, in cooperation with the Idaho National Engineering Laboratory, has electroslag melted a V-5Ti-5Cr alloy using a fused CaF{sub 2} flux. The alloy is a candidate for use in future fusion reactors. One objective of this research was to evaluate the feasibility of the electroslag melting process in separating simulated radioactive isotopes from the V alloy to demonstrate recyclability. Small amounts of Ca, Y, and Mn were added as surrogates for radioactive isotopes. Results showed that this vanadium alloy can be electroslag melted satisfactorily. The impurities added intentionally were removed or decreased successfully. Among the major alloying constituents, Cr was retained but there were some Ti losses. The latter may be controlled with process refinements. This research suggests that the electroslag melting process could be a suitable method for recycling V alloys after use in future fusion reactors, or for processing other reactive metal alloys with more immediate applications. 3 refs., 1 fig., 5 tabs.

Nafziger, R.H. [Bureau of Mines, Albany, OR (United States); Smolik, G.R.; Carmack, W.J. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

1996-12-31T23:59:59.000Z

94

Redox polymer electrodes for advanced batteries  

DOE Patents [OSTI]

Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene.

Gregg, Brian A. (Golden, CO); Taylor, A. Michael (Golden, CO)

1998-01-01T23:59:59.000Z

95

Sorption preconcentration of vanadium for its determination in sea water  

SciTech Connect (OSTI)

This work is devoted to a study of the conditions of vanadium sorption by a fibrous sorbent with a view to evolving a procedure for its determination in sea water. The sorbent was the same as used by them earlier for molybdenum preconcentration. It is a fiber based on polyethylenepolyamine-modified polyacrylonitrile. The sorbent contained 80% tertiary and approx. = 20% primary and secondary amino groups. Static exchange capacity of the sorbent relative to HCl 2 mmole/g, swelling 34%, fiber diameter 0.016 mm. The vanadium content was determined photometrically using acidic chromium blue K.

Andreeva, I.Yu.; Lebedeva, L.I.; Izotova, Yu.A.; Danilova, E.Ya.

1987-08-10T23:59:59.000Z

96

Pollution of Natural Waters 1. Redox chemistry  

E-Print Network [OSTI]

. Eutrophication 4. Water treatment 1. Redox chemistry #15; Principle of equilibration of chemical system R Keq;sh and other aquatic life { Shift to anaerobic metabolic mechanisms #15; Eutrophication: agin

Schofield, Jeremy

97

MICROSCALE METABOLIC, REDOX AND ABIOTIC REACTIONS IN HANFORD 300 AREA SUBSURFACE SEDIMENTS  

SciTech Connect (OSTI)

The Hanford 300 Area is a unique site due to periodic hydrologic influence of river water resulting in changes in groundwater elevation and flow direction. This area is also highly subject to uranium remobilization, the source of which is currently believed to be the region at the base of the vadose zone that is subject to period saturation due to the changes in the water levels in the Columbia River. We found that microbial processes and redox and abiotic reactions which operate at the microscale were critical to understanding factors controlling the macroscopic fate and transport of contaminants in the subsurface. The combined laboratory and field research showed how microscale conditions control uranium mobility and how biotic, abiotic and redox reactions relate to each other. Our findings extended the current knowledge to examine U(VI) reduction and immobilization using natural 300 Area communities as well as selected model organisms on redox-sensitive and redox-insensitive minerals. Using innovative techniques developed specifically to probe biogeochemical processes at the microscale, our research expanded our current understanding of the roles played by mineral surfaces, bacterial competition, and local biotic, abiotic and redox reaction rates on the reduction and immobilization of uranium.

Beyenal, Haluk [WSU] [WSU; McLEan, Jeff [JCVI] [JCVI; Majors, Paul [PNNL] [PNNL; Fredrickson, Jim [PNNL] [PNNL

2013-11-14T23:59:59.000Z

98

Investigation of redox processes at semiconductor electrode liquid junctions  

SciTech Connect (OSTI)

Research in fundamental aspects of photoelectrochemical cells has been in the following areas: chemical probes for hot carrier processes, electrostatic theory for describing electrical interactions at interfaces, and kinetics of electron transfer at ideal semiconductor solution interfaces. Our goal is to achieve a better understanding of dark and photo-induced current flow at the semiconductor electrode/redox electrolyte interface (SEI) so that devices and processes utilizing this interface for solar energy conversion can be developed or improved. Our most important accomplishment has been the development of a redox system capable of detecting hot electrons at the p-InP/acetonitrile interface. Also, we have examined electrostatic theory for the image potential of an ion as a function of distance from the SEI. Finally, our group was one of the first to realize that the 2-dimensional metal chalcogenides (MC) are excellent materials for fundamental studies of electron transfer at the SEI. One of the chief potential advantages for use of MC's is the formation of semiconductor/liquid junctions with nearly ideal electrochemical properties. 27 refs., 1 fig.

Koval, C.A.

1990-08-01T23:59:59.000Z

99

Electrochemical kinetics of thin film vanadium pentoxide cathodes for lithium batteries  

E-Print Network [OSTI]

Electrochemical experiments were performed to investigate the processing-property-performance relations of thin film vanadium pentoxide cathodes used in lithium batteries. Variations in microstructures were achieved via ...

Mui, Simon C., 1976-

2005-01-01T23:59:59.000Z

100

E-Print Network 3.0 - aluminia supported vanadium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sively studied... of the less expen- sive apparatus and its versatility. As an electrochromic material, however, vanadium Source: Artuso, Florinda - Department of Environment,...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

E-Print Network 3.0 - aqueous vanadium pentoxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hybrid Summary: properties of the hybrid aerogel. 2. Experimental Vanadium pentoxide aerogels containing PPy were synthesized... involved addition of an aqueous dispersion of...

102

Temperature relationship of the elastic constants of vanadium  

SciTech Connect (OSTI)

Information on the elastic constants of vanadium and their temperature relationship is limited and ambiguous. This article gives the values of these characteristics for VEL-2 electron beam remelted vanadium with a purity of about 99.8%. The elastic properties were measured in heating from 20 to 1600/sup 0/C in a vacuum. The relationship of the modulus of elasticity to temperature has two almost linear portions in the 20-300 and 300-1350/sup 0/C ranges and then a more intense reduction in it is observed. The shear modulus drops sharply starting with 800/sup 0/C and decreases to G = 36 kN/mm/sup 2/ at 1600/sup 0/C. Poisson's ratio has values close to 0.3. Its most significant increase starts with 1400/sup 0/C.e

Belousov, O.K.

1987-09-01T23:59:59.000Z

103

(This is a sample cover image for this issue. The actual cover is not yet available at this time.) This article appeared in a journal published by Elsevier. The attached  

E-Print Network [OSTI]

this problem [1]. Among various existing energy-storage techniques, the all-vana- dium redox flow battery (VRFB Numerical investigations of flow field designs for vanadium redox flow batteries Q. Xu, T.S. Zhao , P fields is numerically simulated. " A power-based efficiency is defined and calculated for different flow

Zhao, Tianshou

104

Organometallics 1987, 6, 2551-2556 2551 Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis  

E-Print Network [OSTI]

, with sodium naphthalenide in thf under carbon monoxide gives the titanium(0) carbonyl [~-BUSOrganometallics 1987, 6, 2551-2556 2551 Seven-Coordinate Titanium and Vanadium Carbonyls. Synthesis of the fourfold and threefold faces; the titanium and vanadium structures may also be described in terms of a face

Girolami, Gregory S.

105

TITANIUM AND VANADIUM CHEMISTRY IN LOW-MASS DWARF STARS Katharina Lodders  

E-Print Network [OSTI]

. The most profound effect of a decrease in temperature is that carbon monoxide (CO) con- verts to methaneTITANIUM AND VANADIUM CHEMISTRY IN LOW-MASS DWARF STARS Katharina Lodders Planetary Chemistry The equilibrium gas and condensation chemistry of titanium and vanadium in M, L, and T dwarf atmos- pheres

Fegley Jr., Bruce

106

Materials for Use with Aqueous Redox Flow Batteries | Argonne National  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale LandscapeImports 5.90Materials Porous

107

Structural investigation of phosphate - bismuth glasses with vanadium  

SciTech Connect (OSTI)

The xV{sub 2}O{sub 5}(1?dx)[0.5P{sub 2}O{sub 5}?0.5Bi{sub 2}O{sub 3}] glass system with 0 ? x ? 50 mol% is investigated by IR and Raman spectroscopy. Both P{sub 2}O{sub 5} and Bi{sub 2}O{sub 3} oxides are known as network formers, but Bi{sub 2}O{sub 3} is an unconventional one. At low content of vanadium oxide (x ? 5 mol%), both IR and Raman spectra are dominated by vibration bands characteristics to structural groups of phosphate and bismuthate lattices. Due to the network modifier role, vanadium oxide acts mainly on the Bi{sub 2}O{sub 3} network allowing the phosphate groups to impose their characteristics absorption bands in spectra. These bands are strongly reduced for x ? 20 mol% due to the phosphate network depolymerization and the appearance of new vibrations characteristic to P-O-V, Bi-O-V and V-O-V groups showing the network former role of V{sub 2}O{sub 5}.

St?nescu, R. [Babes-Bolyai University, Faculty of Physics, Kogalniceanu 1, 400084 Cluj-Napoca (Romania)] [Babes-Bolyai University, Faculty of Physics, Kogalniceanu 1, 400084 Cluj-Napoca (Romania); Vedeanu, N. [Iuliu Hatieganu University of Medicine and Pharmacy, Biophysics Department, Faculty of Pharmacy, RO-400023 Cluj-Napoca (Romania)] [Iuliu Hatieganu University of Medicine and Pharmacy, Biophysics Department, Faculty of Pharmacy, RO-400023 Cluj-Napoca (Romania); Cozar, I. B.; M?gda?, A. [National Institute for Research and Development of Isotopic and Molecular Technologies, RO-400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, RO-400293 Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

108

Nitridation under ammonia of high surface area vanadium aerogels  

SciTech Connect (OSTI)

Vanadium pentoxide gels have been obtained from decavanadic acid prepared by ion exchange on a resin from ammonium metavanadate solution. The progressive removal of water by solvent exchange in supercritical conditions led to the formation of high surface area V{sub 2}O{sub 5}, 1.6H{sub 2}O aerogels. Heat treatment under ammonia has been performed on these aerogels in the 450-900 deg. C temperature range. The oxide precursors and oxynitrides have been characterized by XRD, SEM, TGA, BET. Nitridation leads to divided oxynitride powders in which the fibrous structure of the aerogel is maintained. The use of both very low heating rates and high surface area aerogel precursors allows a higher rate and a lower threshold of nitridation than those reported in previous works. By adjusting the nitridation temperature, it has been possible to prepare oxynitrides with various nitrogen enrichment and vanadium valency states. Whatever the V(O,N) composition, the oxidation of the oxynitrides in air starts between 250 and 300 deg. C. This determines their potential use as chemical gas sensors at a maximum working temperature of 250 deg. C.

Merdrignac-Conanec, Odile [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)]. E-mail: odile.merdrignac@univ-rennes1.fr; El Badraoui, Khadija [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France); L'Haridon, Paul [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)

2005-01-15T23:59:59.000Z

109

Factors Controlling Redox Speciation of Plutonium and Neptunium in Extraction Separation Processes  

SciTech Connect (OSTI)

The objective of the project was to examine the factors controlling redox speciation of plutonium and neptunium in UREX+ extraction in terms of redox potentials, redox mechanism, kinetics and thermodynamics. Researchers employed redox-speciation extractions schemes in parallel to the spectroscopic experiments. The resulting distribution of redox species w studied uring spectroscopic, electrochemical, and spectro-electrochemical methods. This work reulted in collection of data on redox stability and distribution of redox couples in the nitric acid/nitrate electrolyte and the development of redox buffers to stabilize the desired oxidation state of separated radionuclides. The effects of temperature and concentrations on the redox behavior of neptunium were evaluated.

Paulenova, Alena [Principal Investigator; Vandegrift, III, George F. [Collaborator

2013-09-24T23:59:59.000Z

110

Review of flow battery testing at Sandia  

SciTech Connect (OSTI)

Sandia National Laboratories is evaluating prototype zinc/bromine, Redox, and zinc/ferricyanide flowing electrolyte batteries and cells. This paper will update previous reports of test results of two Exxon zinc/bromine batteries and one NASA Redox iron/chromium battery. Two 60-sq. cm. zinc/ferricyanide cells from Lockheed Missiles and Space Co. are also being evaluated. Performance, life, and operating data will be described for these batteries and cells.

Butler, P.C.; Miller, D.W.; Robinson, C.E.; Rodriguez, G.P.

1984-01-01T23:59:59.000Z

111

Redox shuttles for lithium ion batteries  

SciTech Connect (OSTI)

Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

2014-11-04T23:59:59.000Z

112

Indium-Vanadium Oxides Deposited by Radio Frequency Sputtering: New Thin Film Transparent  

E-Print Network [OSTI]

in many works, metal/vanadium mixed oxides have favorable properties when used as charge storage, 144 (No. 12), 4099. (2) Opara Krasovec, U.; Orel, B.; Reisfeld, R. Electrochem. Solid- State Let

Artuso, Florinda

113

Spectrophotometric determination of vanadium in metallurgical products with carminic acid and cetyltrimethylammonium chloride  

SciTech Connect (OSTI)

According to the authors, there is an increasing demand for sensitive, selective, and rapid methods of determining low levels of vanadium in metallurgical products, and solvent-extraction methods do not meet the requirements. The authors used an anthraquinone dye carminic acid (CA) as a chromophoric organic reagent: 1, 3, 4, 6-tetrahydroxy-2-R-5carboxy-8-methylanthra-9, 10-quinone. The CSA was cetyltrimethylammonium chloride CTA. The three-component system was examined in order to devise a reasonably sensitive and rapid method of determining vanadium in metallurgical products. A study is made of the complexing in the system formed by vanadium (IV) with CA and the CSA. The optimum conditions for the formation of the complex have been established together with the spectrophotometric characteristics. A spectrophotometric method has been devised for determining from 0.05 to 5% of vanadium in metallurgical products with a relative standard deviation of not more than 0.04.

Babenko, N.L.; Blokh, M. Sh.; Guseva, T.D.

1985-11-01T23:59:59.000Z

114

Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides  

E-Print Network [OSTI]

Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

Iglesia, Enrique

115

Tantalum and vanadium response to shock-wave loading at normal and elevated temperatures. Non-monotonous decay of the elastic wave in vanadium  

SciTech Connect (OSTI)

The evolution of the elastic precursor waves in pure tantalum and vanadium is presented at normal and elevated temperatures over propagation distances that ranged from 0.125 to 3?mm. Measurements were performed in order to obtain experimental data about the temperature-rate dependence of the yield stress of the two metals. With increasing propagation distance, the rate of the decay of elastic precursor decreases, as the shear stress in the elastic precursor wave approaches the Peierls stresses. It has been found that the decay, with propagation distance, of the post-spike minimum of the spike-like elastic precursor wave in vanadium is essentially non-monotonous. The experiments also revealed that annealing of tantalum and vanadium increases their Hugoniot elastic limit. The anomalous increase of the high strain rate yield stress with temperature, as observed earlier for some FCC and HCP metals, has not been detected in these measurements.

Zaretsky, E. B. [Department of Mechanical Engineering, Ben Gurion University, 84105 Beer Sheva (Israel); Kanel, G. I. [Joint Institute for High Temperatures RAS, Izhorskaya 13, bld.2, 125412 Moscow (Russian Federation)

2014-06-28T23:59:59.000Z

116

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal  

E-Print Network [OSTI]

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal Interlinked Protein Folding.10.011 SUMMARY Disruption of protein folding in the endoplasmic reticulum (ER) causes unfolded proteins to accumu is active. Because ER redox po- tential is optimized for oxidative protein folding, we reasoned

Mullins, Dyche

117

Methane oxidation over dual redox catalysts  

SciTech Connect (OSTI)

Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C[sub 2] hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C[sub 2] hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe[sup III] or Sn[sup IV], was found to be essential for the selectivity switch from C[sub 2] coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu[sup II](ion exchanged) Fe[sup III](framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La[sub 2]O[sub 3] has been discovered for potentially commercially attractive process for the conversion of methane to C[sub 2] hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C[sub 2] hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

1992-06-01T23:59:59.000Z

118

Study to establish cost projections for production of redox chemicals  

SciTech Connect (OSTI)

A cost study of four proposed manufacturing processes for redox chemicals for the NASA REDOX Energy Storage System yielded favorable selling prices in the range $0.99 to $1.91/kg of chromic chloride, anhydrous basis, including ferrous chloride. The prices corresponded to specific energy storage costs from under $9 to $17/kWh. A refined and expanded cost analysis of the most favored process yielded a price estimate corresponding to a storage cost of $11/kWh. The findings supported the potential economic viability of the NASA REDOX system.

Walther, J.F.; Greco, C.C.; Rusinko, R.N.; Wadsworth, A.L. III

1982-11-01T23:59:59.000Z

119

An evaluation of the acute toxicity of vanadium to five estuarine species: Penaeus aztecus, Rangia cuneata, Cyprinodon variegatus, Neanthes arenaceodentata and Brachionus plicatilis / b  

E-Print Network [OSTI]

through the use of blank tissue samples spiked with known quantities of the vanadium standard. Instrumental neutron activation analysis (INAA) was used both to check the validity of the vanadium standard used for spectrophotometric analysis... is shown in Figure 2. The working region of the standard curve used for routine analysi. . of vanadium was the region between 0. 02 and 1 . 06 absorbance units or I to 40 micrograms of' vanadium per gram of sample. It was also determined that +he...

Hobson, David Wayne

1978-01-01T23:59:59.000Z

120

Redox shuttles for overcharge protection of lithium batteries  

DOE Patents [OSTI]

The present invention is generally related to electrolytes containing novel redox shuttles for overcharge protection of lithium-ion batteries. The redox shuttles are capable of thousands hours of overcharge tolerance and have a redox potential at about 3-5.5 V vs. Li and particularly about 4.4-4.8 V vs. Li. Accordingly, in one aspect the invention provides electrolytes comprising an alkali metal salt; a polar aprotic solvent; and a redox shuttle additive that is an aromatic compound having at least one aromatic ring with four or more electronegative substituents, two or more oxygen atoms bonded to the aromatic ring, and no hydrogen atoms bonded to the aromatic ring; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.

Amine, Khalil (Downers Grove, IL); Chen, Zonghai (Downers Grove, IL); Wang, Qingzheng (San Jose, CA)

2010-12-14T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Iron Cycling and Redox Evolution in the Precambrian  

E-Print Network [OSTI]

Green, W.J. , 2002. Rare earth elements in the water columnVangaans, P. , 1988. Rare-Earth Element Distributions inRedox cycling of rare earth elements in the suboxic zone of

Planavsky, Noah John

2012-01-01T23:59:59.000Z

122

Preparation of redox polymer cathodes for thin film rechargeable batteries  

DOE Patents [OSTI]

The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

1994-11-08T23:59:59.000Z

123

Solvothermal synthesis of vanadium phosphates in the form of xerogels, aerogels and mesostructures  

SciTech Connect (OSTI)

Regularities and peculiarities of physicochemical changes, first of all phase transformations, during solvothermal treatment (with conventional and microwave heating) of the vanadium pentoxide and orthophosphoric acid mixture in organic solvents in the presence of reducing agents have been studied. Hemihydrate of vanadium hydrophosphate - the precursor of vanadium pyrophosphate, the active phase for n-butane to maleic anhydride oxidation, and ion exchanger with variable physicochemical characteristics, i.e. crystal structure, specific surface area, crystallite size and acidic properties - has been synthesized in the temperature range 170-200 {sup o}C. The obtained phases were examined using XRD, DTA-TG, SEM, FTIR spectroscopy, nitrogen adsorption as well as gas chromatographic determination of acidity through organic bases adsorption. The catalytic activity of prepared samples for n-butane oxidation has been investigated.

Sydorchuk, V.; Zazhigalov, V. [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine)] [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine); Khalameida, S., E-mail: svkhal@ukr.net [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine); Diyuk, E. [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine)] [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine); Skubiszewska-Zieba, J.; Leboda, R. [Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, 20-031 Lublin (Poland)] [Faculty of Chemistry, Maria Curie-Sklodowska University, Maria Curie-Sklodowska Sq. 3, 20-031 Lublin (Poland); Kuznetsova, L. [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine)] [Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, 13 General Naumov Str., Kyiv 03164 (Ukraine)

2010-09-15T23:59:59.000Z

124

A review of flow battery testing at Sandia  

SciTech Connect (OSTI)

Sandia National Laboratories is evaluating prototype zinc/bromine, Redox, and zinc/ferricyanide flowing electrolyte batteries and cells. This paper updates previous reports of test results of two Exxon zinc/bromine batteries and one NASA Redox iron/chromium battery. Two 60sq. cm. zinc/ferricyanide cells from Lockheed Missiles and Space Co. are also being evaluated. Performance, life, and operating data are described for these batteries and cells.

Butler, P.C.; Miller, D.W.; Robinson, C.E.; Rodriguez, G.P.

1984-08-01T23:59:59.000Z

125

Study of lithium diffusion in RF sputtered Nickel/Vanadium mixed oxides thin films  

E-Print Network [OSTI]

Study of lithium diffusion in RF sputtered NickelÁ/Vanadium mixed oxides thin films F. Artuso a lithium insertion inside RF sputtered Ni/V mixed oxides thin films have been investigated employing, showed three steps clearly involved in the intercalation mechanism of lithium in the oxide films: (i

Artuso, Florinda

126

Materials Science and Engineering B88 (2002) 7378 Processing and properties of vanadium doped strontium niobate  

E-Print Network [OSTI]

strontium niobate Seana Seraji, Yun Wu, Steven Limmer, Tammy Chou, Caroyln Nguyen, Mike Forbess, G.Z. Cao October 2001 Abstract Strontium niobate was doped with vanadium and the resulting effects a relatively high vapor pressure [5]. Strontium niobate (Sr2Nb2O7) is a very promising candidate

Cao, Guozhong

127

Thermodynamic considerations for the use of vanadium alloys with ceramic breeder materials  

SciTech Connect (OSTI)

Fusion energy is considered to be an attractive energy form because of its minimal environmental impact. In order to maintain this favorable status, every effort needs to be made to use low activation materials wherever possible. The tritium breeder blanket is a focal point of system design engineers who must design environmentally attractive blankets through the use of low activation materials. Of the several candidate lithium-containing ceramics being considered for use in the breeder blanket, Li{sub 2}O, Li{sub 2}TiO{sub 3}, are attractive choices because of their low activation. Also, low activation materials like the vanadium alloys are being considered for use as structural materials in the blanket. The suitability of vanadium alloys for containment of lithium ceramics is the subject of this study. Thermodynamic evaluations are being used to estimate the compatibility and stability of candidate ceramic breeder materials (Li{sub 2}O, Li{sub 2}TiO{sub 3}, and Li{sub 2}ZrO{sub 3}) with vanadium and vanadium alloys. This thermodynamic evaluation will focus first on solid-solid interactions. As a tritium breeding blanket will use a purge gas for tritium recovery, gas-solid systems will also receive attention.

Johnson, C.E.; Johnson, I.; Kopasz, J.P.

1995-12-31T23:59:59.000Z

128

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents [OSTI]

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1987-01-01T23:59:59.000Z

129

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents [OSTI]

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1985-05-17T23:59:59.000Z

130

Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer  

DOE Patents [OSTI]

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, R.H.

1987-04-21T23:59:59.000Z

131

Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids  

DOE Patents [OSTI]

Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1986-01-01T23:59:59.000Z

132

Comparison of a microstructure evolution model with experiments on irradiated vanadium  

E-Print Network [OSTI]

Comparison of a microstructure evolution model with experiments on irradiated vanadium S. Sharafat vacancy ¯ux to grow matrix and precipitate-axed bubbles. The direct formation of vacancy and interstitial and its alloys are now considered as candidate structural materials in fu- sion reactors, because

Ghoniem, Nasr M.

133

Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic compression  

E-Print Network [OSTI]

Nano-structured vanadium: processing and mechanical properties under quasi-static and dynamic form 16 September 2003; accepted 9 October 2003 Abstract We have processed fully dense, nano that the grain size of the consolidated V is around 100 nm. Mechanical properties of the nano-structured V were

Wei, Qiuming

134

Hydrogen-impurity binding energy in vanadium and niobium A. Mokrani and C. Demangeat  

E-Print Network [OSTI]

2243 Hydrogen-impurity binding energy in vanadium and niobium A. Mokrani and C. Demangeat IPCMS, UM by the hydrogen) contribution, ii) the band structure contribution, iii) the electron-electron interaction without. Strong H-H repulsion is observed when the hydrogen atoms are at first nearest neighbouring positions

Boyer, Edmond

135

Redox reactions with empirical potentials: Atomistic battery discharge simulations  

E-Print Network [OSTI]

Batteries are pivotal components in overcoming some of today's greatest technological challenges. Yet to date there is no self-consistent atomistic description of a complete battery. We take first steps toward modeling of a battery as a whole microscopically. Our focus lies on phenomena occurring at the electrode-electrolyte interface which are not easily studied with other methods. We use the redox split-charge equilibration (redoxSQE) method that assigns a discrete ionization state to each atom. Along with exchanging partial charges across bonds, atoms can swap integer charges. With redoxSQE we study the discharge behavior of a nano-battery, and demonstrate that this reproduces the generic properties of a macroscopic battery qualitatively. Examples are the dependence of the battery's capacity on temperature and discharge rate, as well as performance degradation upon recharge.

Dapp, Wolf B

2013-01-01T23:59:59.000Z

136

Production and fabrication of vanadium alloys for the radiative divertor program of DIII-D  

SciTech Connect (OSTI)

V-4Cr-4-Ti alloy has been recently selected for use in the manufacture of a portion of the DIII-D Radiative Divertor modification, as part of an overall DIII-D vanadium alloy deployment effort developed by General Atomics (GA) in conjunction with the Argonne and Oak Ridge National Laboratories (ANL or ORNL). The goal of this work is to produce a production-scale heat of the alloy and fabricate it into product forms for the manufacture of a portion of the Radiative Divertor (RD) for the DIII-D tokamak, to develop the fabrications technology for manufacture of the vanadium alloy radiative Divertor components, and to determine the effects of typical tokamak environments in the behavior of the vanadium alloy. The production of a {approx}1300-kg heat of V-4Cr-4Ti alloy is currently in progress at Teledyne Wah Chang of Albany, oregon (TWCA) to provide sufficient material for applicable product forms. Two unalloyed vanadium ingots for the alloy have already been produced by electron beam melting of raw processes vanadium. Chemical compositions of one ingot and a portion of the second were acceptable, and Charpy V-Notch (CVN) impact test performed on processed ingot samples indicated ductile behavior. Material from these ingots are currently being blended with chromium and titanium additions, and will be vacuum-arc remelted into a V-4Cr-4Ti alloy ingot and converted into product forms suitable for components of the DIII-D RD structure. Several joining methods selected for specific applications in fabrication of the RD components are being investigated, and preliminary trials have been successful in the joining of V-alloy to itself by both resistance and inertial welding processes and to Inconel 625 by inertial welding.

Johnson, W.R.; Smith, J.P.; Stambaugh, R.D.

1996-04-01T23:59:59.000Z

137

Development and application of a redox indicator method for the kinetics of oxidation of vanadium(II) ions by hydrogen peroxide and alkyl hydroperoxides  

SciTech Connect (OSTI)

The addition of the methyl viologen radical cation (PQ/sup .+/) to solutions of V(H/sub 2/O)/sub 6//sup 2 +/ and hydrogen peroxide or alkyl hydroperoxide provides a method for measuring the initial reaction rate. The kinetic data so obtained are consistent with the rate equation -d(peroxide)/dt = k/sub 1/(V/sup 2 +/)(peroxide). Kinetic data are given for H/sub 2/O/sub 2/ (k/sub 1/ = 15.4 M/sup -1/ s/sup -1/ at 25.0/sup 0/C) and for RC(CH/sub 3/)/sub 2/OOH, with R = CH/sub 3/ (3.0 M/sup -1/ s/sup -1/), C/sub 2/H/sub 5/ (5.2 M/sup -1/ s/sup -1/), and CH/sub 2/C/sub 6/H/sub 5/ (4.8 M/sup -1/ s/sup -1/). 27 references, 2 figures, 2 tables.

Kim, H.P.; Espenson, J.H.; Bakac, A.

1987-12-02T23:59:59.000Z

138

Metal-ligand redox interaction in the multielectron chemistry of porphyrinogen coordination compounds  

E-Print Network [OSTI]

Metal complexes of the macrocycle porphyrinogen (calix[4]pyrrole) are studied with an emphasis on the redox activity ("non-innocence") of the ligand (Chapter I). Porphyrinogen complexes of spherical, redox-inert metal ...

Bachmann, Julien

2006-01-01T23:59:59.000Z

139

DNA binding shifts the redox potential of the transcription factor SoxR  

E-Print Network [OSTI]

DNA binding shifts the redox potential of the transcription factor SoxR Alon A. Gorodetsky , Lars E-modified electrodes are used to probe the effects of binding to DNA on the redox potential of SoxR, a transcription in the absence of DNA. Using Redmond red as a covalently bound redox reporter affixed above the SoxR binding site

Dietrich, Lars

140

Species-specific residues calibrate SoxR sensitivity to redox-active molecules  

E-Print Network [OSTI]

to viologens, which have redox potentials below -350 mV. Using a mutagenic approach, we pin- pointed threeSpecies-specific residues calibrate SoxR sensitivity to redox-active molecules Rebecca Sheplock,1, the transcription factor SoxR triggers a global stress response by sensing a broad spectrum of redox

Dietrich, Lars

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Redox Shuttles DOI: 10.1002/anie.201002181  

E-Print Network [OSTI]

(dicarbollide) Redox Shuttles in Dye-Sensitized Solar Cells** Alexander M. Spokoyny, Tina C. Li, Omar K. Farha, Charles* Dye-sensitized solar cells (DSCs) are potential next-gener- ation solar electricity sources since molecular dyes to increase light absorption,[3] evaluation of alternative semiconducting photoanodes

142

Adaptive changes in renal mitochondrial redox status in diabetic nephropathy  

SciTech Connect (OSTI)

Nephropathy is a serious and common complication of diabetes. In the streptozotocin (STZ)-treated rat model of diabetes, nephropathy does not typically develop until 30 to 45 days post-injection, although hyperglycemia occurs within 24 h. We tested the hypothesis that chronic hyperglycemia results in a modest degree of oxidative stress that is accompanied by compensatory changes in certain antioxidants and mitochondrial redox status. We propose that as kidneys progress to a state of diabetic nephropathy, further adaptations occur in mitochondrial redox status. Basic parameters of renal function in vivo and several parameters of mitochondrial function and glutathione (GSH) and redox status in isolated renal cortical mitochondria from STZ-treated and age-matched control rats were examined at 30 days and 90 days post-injection. While there was no effect of diabetes on blood urea nitrogen, measurement of other, more sensitive parameters, such as urinary albumin and protein, and histopathology showed significant and progressive worsening in diabetic rats. Thus, renal function is compromised even prior to the onset of frank nephropathy. Changes in mitochondrial respiration and enzyme activities indicated existence of a hypermetabolic state. Higher mitochondrial GSH content and rates of GSH transport into mitochondria in kidneys from diabetic rats were only partially due to changes in expression of mitochondrial GSH carriers and were mostly due to higher substrate supply. Although there are few clear indicators of oxidative stress, there are several redox changes that occur early and change further as nephropathy progresses, highlighting the complexity of the disease. Highlights: ?Adaptive changes in renal mitochondrial and redox status in diabetic rats. ?Modest renal dysfunction even prior to onset of nephropathy. ?Elevated concentrations of mitochondrial GSH in diabetic kidneys. ?Change in GSH due partly to increased protein expression of transporter. ?Oxidatively modified proteins in renal mitochondria from diabetic rats.

Putt, David A.; Zhong, Qing; Lash, Lawrence H., E-mail: l.h.lash@wayne.edu

2012-01-15T23:59:59.000Z

143

Tungsten Coating on Low Activation Vanadium Alloy by Plasma Spray Process  

SciTech Connect (OSTI)

Tungsten (W) coating on fusion candidate V-4Cr-4Ti (NIFS-HEAT-2) substrate was demonstrated with plasma spray process for the purpose of applying to protection of the plasma facing surface of a fusion blanket. Increase in plasma input power and temperature of the substrate was effective to reduce porosity of the coating, but resulted in hardening of the substrate and degradation of impact property at 77 K. The hardening seemed to be due to contamination with gaseous impurities and deformation by thermal stress during the coating process. Since all the samples showed good ductility at room temperature, further heating seems to be acceptable for the vanadium substrate. The fracture stress of the W coating was estimated from bending tests as at least 313 MPa, which well exceeds the design stress for the vanadium structure in fusion blanket.

Nagasaka, Takuya [National Institute for Fusion Science (Japan); Muroga, Takeo [National Institute for Fusion Science (Japan); Noda, Nobuaki [National Institute for Fusion Science (Japan); Kawamura, Masashi [Kawasaki Heavy Industries, LTD (Japan); Ise, Hideo [Kawasaki Heavy Industries, LTD (Japan); Kurishita, Hiroaki [Tohoku University (Japan)

2005-05-15T23:59:59.000Z

144

Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium  

E-Print Network [OSTI]

The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

E. I. Sharapov; C. L. Morris; M. Makela; A. Saunders; Evan R. Adamek; Yelena Bagdasarova; L. J. Broussard; C. B. Cude-Woods; Deon E Fellers; Peter Geltenbort; S. I. Hasan; K. P. Hickerson; G. Hogan; A. T. Holley; Chen-Yu Liu; M. P. Mendenhall; J. Ortiz; R. W. Pattie Jr.; D. G. Phillips; J. Ramsey; D. J. Salvat; S. J. Seestrom; E. Shaw; Sky Sjue; W. E. Sondheim; B. VornDick; Z. Wang; T. L. Womack; A. R. Young; B. A. Zeck

2013-06-05T23:59:59.000Z

145

Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium  

E-Print Network [OSTI]

The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

Sharapov, E I; Makela, M; Saunders, A; Adamek, Evan R; Bagdasarova, Yelena; Broussard, L J; Cude-Woods, C B; Fellers, Deon E; Geltenbort, Peter; Hasan, S I; Hickerson, K P; Hogan, G; Holley, A T; Liu, Chen-Yu; Mendenhall, M P; Ortiz, J; Pattie, R W; Phillips, D G; Ramsey, J; Salvat, D J; Seestrom, S J; Shaw, E; Sjue, Sky; Sondheim, W E; VornDick, B; Wang, Z; Womack, T L; Young, A R; Zeck, B A

2013-01-01T23:59:59.000Z

146

Multiplier, moderator, and reflector materials for lithium-vanadium fusion blankets.  

SciTech Connect (OSTI)

The self-cooled lithium-vanadium fusion blanket concept has several attractive operational and environmental features. In this concept, liquid lithium works as the tritium breeder and coolant to alleviate issues of coolant breeder compatibility and reactivity. Vanadium alloy (V-4Cr-4Ti) is used as the structural material because of its superior performance relative to other alloys for this application. However, this concept has poor attenuation characteristics and energy multiplication for the DT neutrons. An advanced self-cooled lithium-vanadium fusion blanket concept has been developed to eliminate these drawbacks while maintaining all the attractive features of the conventional concept. An electrical insulator coating for the coolant channels, spectral shifter (multiplier, and moderator) and reflector were utilized in the blanket design to enhance the blanket performance. In addition, the blanket was designed to have the capability to operate at high loading conditions of 2 MW/m{sup 2} surface heat flux and 10 MW/m{sup 2} neutron wall loading. This paper assesses the spectral shifter and the reflector materials and it defines the technological requirements of this advanced blanket concept.

Gohar, Y.; Smith, D. L.

1999-10-07T23:59:59.000Z

147

NOVEL COMPUTATIONAL SIMULATION OF REDOX REACTIONS WITHIN A METAL ELECTROSPRAY EMITTER  

SciTech Connect (OSTI)

To further both our fundamental understanding implications of the electrolytic nature of the electrospray and our understanding of the analytical ion source, in the context of electrospray mass spectrometry (ES-MS), a computational simulation of the oxidation of chemical species inside a metal emitter has been developed. The analysis code employs a boundary integral method for the solution of the Laplace equation for the electric potential and current, and incorporates standard activation and concentration polarization functions for the redox active species in the system to define the boundary conditions. The specific system modeled consisted of a 100 {mu}m i .d., inert metal capillary CHICN/H2O (90/10 V/V). ES emitter and a spray solution comprised of an analyte dissolved in Variable parameters included the concentration (i.e., 5, 10, 20, and 50 ~M) of the easily oxidized analyte ferrocene (Fe, dicyclopentadienyl iron) in the solution, and solution conductivities of 1.9, 3.8, and 7.6 x 107 Mho/cm. ES currents were on the order of 0.05 {mu}A and the flow rate was 5 @A_nin. Under these defined conditions, the two most prominent reactions at the emitter metakolution interface were assumed to be H20 oxidation (2H20 = 02 + 4H+ + 4e") and Fe oxidation (Fe = Fe' +e-). Using this model it was possible to predict the inter-facial potentials, as well as the current density for each of the reactions, as a function of axial position from the emitter spray tip back upstream, under the various operational conditions. Computational fluid dynamics (CFD) calculations showed that the imposed flow rate through the emitter was adequate to prevent significant back-diffusion of Fe+ into the emitter against the flow direction. The computational simulations predict the same behavior for the ES ion source as has been observed experimentally and is consistent with the controlled-current electrolytic cell analogy of Van Berkel and Zhou (Anal. Chem. 1995, 67,.2916-2923). Furthermore, the simulations demonstrate that the majority of the current involved in the redox reactions originated within a 200- 300 ~m region near the spray tip.

BULLOCK, J.S.IV; GILES, G.E.; GRAY, L.J.; VAN BERKEL, G.J.

1999-01-13T23:59:59.000Z

148

Live Cell Chemical Profiling of Temporal Redox Dynamics in a Photoautotrophic Cyanobacterium  

SciTech Connect (OSTI)

Protein reduction-oxidation (redox) modification is an important mechanism that allows microorganisms to sense environmental changes and initiate cellular responses. We have developed a quantitative chemical probe approach for live cell labeling of proteins that are sensitive to redox modifications. We utilize this in vivo strategy to identify 176 proteins undergoing ~5-10 fold dynamic redox change in response to nutrient limitation and subsequent replenishment in the photoautotrophic cyanobacterium, Synechococcus sp. PCC 7002. We detect redox changes in as little as 30 seconds after nutrient perturbation, and oscillations in reduction and oxidation for 60 minutes following the perturbation. Many of the proteins undergoing dynamic redox transformations participate in the major components for the production (photosystems and electron transport chains) or consumption (Calvin-Benson cycle and protein synthesis) of reductant and/or energy in photosynthetic organisms. Thus, our in vivo approach reveals new redox-susceptible proteins, in addition to validating those previously identified in vitro.

Sadler, Natalie C.; Melnicki, Matthew R.; Serres, Margrethe H.; Merkley, Eric D.; Chrisler, William B.; Hill, Eric A.; Romine, Margaret F.; Kim, Sangtae; Zink, Erika M.; Datta, Suchitra; Smith, Richard D.; Beliaev, Alex S.; Konopka, Allan; Wright, Aaron T.

2014-01-01T23:59:59.000Z

149

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

SciTech Connect (OSTI)

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

150

E-Print Network 3.0 - auto-protective redox buffering Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

redox processes analogous to those responsible for water oxidation... in the oxygen-evolving complex (OEC) of photosystem II (PSII). DFT B3LYP free energy calculations of...

151

E-Print Network 3.0 - abundant redox proteins Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

real time visual- ization... of such destruc- tive assays is very poor. Redox-sensitive green fluorescent ... Source: Tsien, Roger Y. - Department of Chemistry and Biochemistry,...

152

Chemical structure of vanadium-based contact formation on n-AlN  

SciTech Connect (OSTI)

We have investigated the chemical interaction between a Au/V/Al/V layer structure and n-type AlN epilayers using soft x-ray photoemission, x-ray emission spectroscopy, and atomic force microscopy. To understand the complex processes involved in this multicomponent system, we have studied the interface before and after a rapid thermal annealing step. We find the formation of a number of chemical phases at the interface, including VN, metallic vanadium, aluminum oxide, and metallic gold. An interaction mechanism for metal contact formation on the entire n-(Al,Ga)N system is proposed.

Pookpanratana, S.; France, R.; Blum, M.; Bell, A.; Bar, M.; Weinhardt, L.; Zhang, Y.; Hofmann, T.; Fuchs, O.; Yang, W.; Denlinger, J. D.; Mulcahy, S.; Moustakas, T. D.; Heske, Clemens

2010-05-17T23:59:59.000Z

153

Continuum Level Formulation and Implementation of a Multi-scale Model for Vanadium  

SciTech Connect (OSTI)

A multi-scale approach is used to construct a continuum strength model for vanadium. The model is formulated assuming plastic deformation by dislocation motion and strain hardening due to dislocation interactions. Dislocation density is adopted as the state variable in the model. Information from molecular statics, molecular dynamics and dislocation dynamics simulations is combined to create kinetic relations for dislocation motion, strain hardening relations and evolution equations for the dislocation density. Implicit time integration of the constitutive equations is described in the context of implementation in a finite element code. Results are provided illustrating the strain, strain rate, temperature and pressure dependence of the constitutive model.

Lawrence Livermore National Laboratory

2009-08-17T23:59:59.000Z

154

Nanoscale structural evolution of electrically driven insulator to metal transition in vanadium dioxide  

SciTech Connect (OSTI)

The structural evolution of tensile strained vanadium dioxide thin films was examined across the electrically driven insulator-to-metal transition by nanoscale hard X-ray diffraction. A metallic filament with rutile (R) structure was found to be the dominant conduction pathway for an electrically driven transition, while the majority of the channel area remained in the monoclinic M1 phase. The filament dimensions were estimated using simultaneous electrical probing and nanoscale X-ray diffraction. Analysis revealed that the width of the conducting channel can be tuned externally using resistive loads in series, enabling the M1/R phase ratio in the phase coexistence regime to be tuned.

Freeman, Eugene, E-mail: exf181@psu.edu; Shukla, Nikhil; Datta, Suman [Department of Electrical Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States)] [Department of Electrical Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Stone, Greg; Engel-Herbert, Roman; Gopalan, Venkatraman [Department of Materials Science and Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States)] [Department of Materials Science and Engineering, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Paik, Hanjong [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States)] [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Moyer, Jarrett A. [Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)] [Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Cai, Zhonghou; Wen, Haidan [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Schlom, Darrell G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States) [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

2013-12-23T23:59:59.000Z

155

DOE - Office of Legacy Management -- Vanadium Corp of America - PA 15  

Office of Legacy Management (LM)

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156

Controlled Chemical Doping of Semiconductor Nanocrystals Using Redox Buffers  

SciTech Connect (OSTI)

Semiconductor nanocrystal solids are attractive materials for active layers in next-generation optoelectronic devices; however, their efficient implementation has been impeded by the lack of precise control over dopant concentrations. Herein we demonstrate a chemical strategy for the controlled doping of nanocrystal solids under equilibrium conditions. Exposing lead selenide nanocrystal thin films to solutions containing varying proportions of decamethylferrocene and decamethylferrocenium incrementally and reversibly increased the carrier concentration in the solid by 2 orders of magnitude from their native values. This application of redox buffers for controlled doping provides a new method for the precise control of the majority carrier concentration in porous semiconductor thin films.

Engel, Jesse H.; Surendranath, Yogesh; Alivisatos, Paul

2013-07-09T23:59:59.000Z

157

Redox-Reactive Membrane Vesicles produced by Shewanella. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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158

Transient light-induced intracellular oxidation revealed by redox biosensor  

SciTech Connect (OSTI)

Highlights: •Time-resolved live cell imaging revealed light-induced oxidation. •Only the roGFP probe fused with glutaredoxin reveals photooxidation. •The transient oxidation is rapidly reduced by the cytosolic antioxidant system. •Intracellular photooxidation is media-dependent. •Oxidation is triggered exclusively by exposure to short wavelength excitation. -- Abstract: We have implemented a ratiometric, genetically encoded redox-sensitive green fluorescent protein fused to human glutaredoxin (Grx1-roGFP2) to monitor real time intracellular glutathione redox potentials of mammalian cells. This probe enabled detection of media-dependent oxidation of the cytosol triggered by short wavelength excitation. The transient nature of light-induced oxidation was revealed by time-lapse live cell imaging when time intervals of less than 30 s were implemented. In contrast, transient ROS generation was not observed with the parental roGFP2 probe without Grx1, which exhibits slower thiol-disulfide exchange. These data demonstrate that the enhanced sensitivity of the Grx1-roGFP2 fusion protein enables the detection of short-lived ROS in living cells. The superior sensitivity of Grx1-roGFP2, however, also enhances responsiveness to environmental cues introducing a greater likelihood of false positive results during image acquisition.

Kolossov, Vladimir L., E-mail: viadimer@illinois.edu [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States); Beaudoin, Jessica N. [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States) [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States); Department of Animal Sciences, University of Illinois at Urbana-Champaign, 1207 W. Gregory Drive, Urbana, IL 61801 (United States); Hanafin, William P. [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States)] [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States); DiLiberto, Stephen J. [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States) [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States); Department of Animal Sciences, University of Illinois at Urbana-Champaign, 1207 W. Gregory Drive, Urbana, IL 61801 (United States); Kenis, Paul J.A. [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States) [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States); Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, 600 S. Mathews Avenue, Urbana, IL 61801 (United States); Rex Gaskins, H. [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States) [Institute for Genomic Biology, University of Illinois at Urbana-Champaign, 1206 W. Gregory Drive, Urbana, IL 61801 (United States); Department of Animal Sciences, University of Illinois at Urbana-Champaign, 1207 W. Gregory Drive, Urbana, IL 61801 (United States); Department of Pathobiology, University of Illinois at Urbana-Champaign, 2001 S. Lincoln Avenue, Urbana, IL 61801 (United States); Division of Nutritional Sciences, University of Illinois at Urbana-Champaign, 905 S. Goodwin Avenue, Urbana, IL 61801 (United States)

2013-10-04T23:59:59.000Z

159

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect (OSTI)

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

160

Photocurrent generation by photosystem 1 integrated in crosslinked redox Adrian Badura,a  

E-Print Network [OSTI]

Photocurrent generation by photosystem 1 integrated in crosslinked redox hydrogels Adrian Badura on a gold electrode surface via an Os complex containing redox polymer hydrogel which simultaneously is used as immobilisation matrix and as electron donor for PS1. On addition of methyl viologen as sacrificial electron

Roegner, Matthias

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox  

E-Print Network [OSTI]

Early diagenesis of carbohydrates and lignin in mangrove sediments subject to variable redox Abstract A comparative study of lignin and neutral carbohydrate compositions, combined with C, N and 13C and lignin in brackish to hypersaline fine-grained mangrove sediments characterized by great changes in redox

Paris-Sud XI, Université de

162

Direct Observation of Nanoscale Peltier and Joule Effects at Metal-Insulator Domain Walls in Vanadium Dioxide Nanobeams  

E-Print Network [OSTI]

Direct Observation of Nanoscale Peltier and Joule Effects at Metal- Insulator Domain Walls localized alternating Peltier heating and cooling as well as Joule heating concentrated at the M-I domain the monoclinic phase identification. KEYWORDS: Vanadium dioxide, thermoreflectance microscopy, Peltier effect

Wu, Junqiao

163

Methane oxidation over dual redox catalysts. Final report  

SciTech Connect (OSTI)

Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C{sub 2} hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C{sub 2} hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe{sup III} or Sn{sup IV}, was found to be essential for the selectivity switch from C{sub 2} coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu{sup II}(ion exchanged) Fe{sup III}(framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La{sub 2}O{sub 3} has been discovered for potentially commercially attractive process for the conversion of methane to C{sub 2} hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C{sub 2} hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

1992-06-01T23:59:59.000Z

164

Sorption of redox-sensitive elements: critical analysis  

SciTech Connect (OSTI)

The redox-sensitive elements (Tc, U, Np, Pu) discussed in this report are of interest to nuclear waste management due to their long-lived isotopes which have a potential radiotoxic effect on man. In their lower oxidation states these elements have been shown to be highly adsorbed by geologic materials occurring under reducing conditions. Experimental research conducted in recent years, especially through the Waste Isolation Safety Assessment Program (WISAP) and Waste/Rock Interaction Technology (WRIT) program, has provided extensive information on the mechanisms of retardation. In general, ion-exchange probably plays a minor role in the sorption behavior of cations of the above three actinide elements. Formation of anionic complexes of the oxidized states with common ligands (OH/sup -/, CO/sup - -//sub 3/) is expected to reduce adsorption by ion exchange further. Pertechnetate also exhibits little ion-exchange sorption by geologic media. In the reduced (IV) state, all of the elements are highly charged and it appears that they form a very insoluble compound (oxide, hydroxide, etc.) or undergo coprecipitation or are incorporated into minerals. The exact nature of the insoluble compounds and the effect of temperature, pH, pe, other chemical species, and other parameters are currently being investigated. Oxidation states other than Tc (IV,VII), U(IV,VI), Np(IV,V), and Pu(IV,V) are probably not important for the geologic repository environment expected, but should be considered especially when extreme conditions exist (radiation, temperature, etc.). Various experimental techniques such as oxidation-state analysis of tracer-level isotopes, redox potential measurement and control, pH measurement, and solid phase identification have been used to categorize the behavior of the various valence states.

Strickert, R.G.

1980-12-01T23:59:59.000Z

165

Some lessons learned from 20 years in RedOx Flow Battery R&D  

E-Print Network [OSTI]

of many biological processes Closed loop processes Batteries, DSSC, bio-tech Electrochemical balancing pressure (low p) Materials Novel nano-structured non- carbon electrodes Novel low cost discharging Materials that are robust in discharge reactions often fail under charging - e.g carbon Good

166

Transitioning from Fuel Cells to Redox Flow Cells | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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167

TEMPO-based Catholyte for High Energy Density Nonaqueous Redox Flow  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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168

Redox Flow Batteries for Grid-scale Energy Storage - Energy Innovation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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169

Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics  

SciTech Connect (OSTI)

Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400°C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

Sathish, M., E-mail: sathishphy79@gmail.com [Department of Physics, GOVT first grade College, Doddaballapur-561203 (India); Eraiah, B., E-mail: eraiah@rediffmail.com [Department of Physics, Bangalore University, Bangalore-560056, India (India)

2014-04-24T23:59:59.000Z

170

Hot gas desulfurization with sorbents containing oxides of zinc, iron, vanadium and copper  

SciTech Connect (OSTI)

The main objective of this research is to evaluate the desulfurization performance of novel sorbents consisting of different combinations of zinc, iron, vanadium and copper oxides; and to develop a sorbent which can reduce H{sub 2}S levels to less than 1 ppmv, which can stabilize zinc, making operations above 650{degrees}C possible, and which can produce economically recoverable amounts of elemental sulfur during regeneration. This objective will be accomplished by evaluating the sorbent performance using fixed-bed and TGA experiments supported by sorbent characterization at various reaction extents. In the seventh quarter, the screening of the promoted sorbents in the packed bed reactor was continued. The results of this work were presented at the 1992 University Coal Research Contractors, Review Conference at Pittsburgh, PA.

Akyurtlu, A.; Akyurtlu, J.F.

1992-01-01T23:59:59.000Z

171

EPR Study of Vanadium Ion in Zinc-Boro-Vanadate Glasses  

SciTech Connect (OSTI)

This paper describes EPR studies on x V{sub 2}O{sub 5}-(40-x)ZnO-60B{sub 2}O{sub 3}(where x 5, 10, 15 and 20 mol %) glass system. These studies indicate a strong compositional dependent trend and existence of characteristic boro-vanadate groups in these glasses. The EPR spectra show a distinct hyperfine structure of {sup 51}V. Spectral analysis shows that the vanadium is present in the glass as vanadyl ion [VO]{sup 2+} at tetragonally distorted octahedral site. The decrease of A{sub ||} and A{sub perpendicular} with increase of V{sub 2}O{sub 5} concentration suggests an increase in the covalence between the central atom and the surrounding oxygen ligands.

Renuka, C. [Department of Physics, Atria Institute of Technology, Bangalore 560021 (India); Gowda, V. C. Veeranna [Department of Physics, Govt. College for Woman, Chintamani 563125 (India); Chakradhar, R. P. S. [Scientist, Surface Engineering Division, National Aerospace Laboratories, Bangalore 560017 (India); Reddy, C. Narayana [Department of Physics, Maharani's Science College for woman (P G Centre, Bangalore University), Bangalore 560001 (India)

2011-07-15T23:59:59.000Z

172

Cotton flow  

E-Print Network [OSTI]

Using the conformally invariant Cotton tensor, we define a geometric flow, the "Cotton flow", which is exclusive to three dimensions. This flow tends to evolve the initial metrics into conformally flat ones, and is somewhat orthogonal to the Yamabe flow, the latter being a flow within a conformal class. We define an entropy functional, and study the flow of nine homogeneous spaces both numerically and analytically. In particular, we show that the arbitrarily deformed homogeneous 3-sphere flows into the round 3-sphere. Two of the nine homogeneous geometries, which are degenerated by the Ricci flow, are left intact by the Cotton flow.

Ali Ulas Ozgur Kisisel; Ozgur Sarioglu; Bayram Tekin

2008-06-17T23:59:59.000Z

173

Reactivity studies of a pseudo three-coordinate vanadium(II) complex: Synthesis of terminal oxo and sulfido complexes of vanadium(IV) and S?S and Se?Se reductive bond cleavage reactions  

SciTech Connect (OSTI)

Terminal oxo and sulfido complexes in the form of (nacnac)V=E(Ntol{sub 2}) (nacnac = [ArNC(CH{sub 3})]{sub 2}CH{sup -}, Ar = 2,6-(CHMe{sub 2}){sub 2}C{sub 6}H{sub 3}, Ntol{sub 2} = {sup -}N(C{sub 6}H{sub 4}-4-Me), E = O (1), S (2)) were isolated from treatment of the masked three-coordinate vanadium(II) complex, (nacnac)V(Ntol{sub 2}), with C{sub 5}H{sub 5}NO and S{sub 8}, respectively. Both vanadium(IV) species, 1 and 2, have been characterized by room temperature X-band EPR spectroscopic studies, and in the case of complex 1, a single crystal molecular structure confirmed the presence of a terminal oxo moiety. Moreover, reaction of (nacnac)V(Ntol{sub 2}) with diphenyl-disulfide and diphenyl-diselenide results in the reductive cleavage of these compounds to produce the vanadium(III) complexes (nacnac)V(XPh)(Ntol{sub 2}) (X = S, (3), Se (4)). A molecular structure of the phenylsulfide complex, 3, confirmed formation of the d{sup 2} complex resulting from reductive cleavage of the S-S bond.

Tran, Ba L.; Chen, Chun-Hsing; Mindiola, Daniel J. (Indiana)

2012-02-07T23:59:59.000Z

174

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect (OSTI)

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mössbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mössbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

175

Anaerobic Redox Cycling of Iron by Freshwater Sediment Microorganisms  

SciTech Connect (OSTI)

The potential for microbially-mediated anaerobic redox cycling of iron (Fe) was examined in a first-generation enrichment culture of freshwater wetland sediment microorganisms. MPN enumerations revealed the presence of significant populations of Fe(III)-reducing (ca. 108 cells mL-1) and Fe(II)-oxidizing, nitrate-reducing organisms (ca. 105 cells mL-1) in the sediment used to inoculate the enrichment cultures. Nitrate reduction commenced immediately following inoculation of acetate-containing (ca. 1 mM) medium with a small quantity (1% vol/vol) of wetland sediment, and resulted in the transient accumulation of NO2- and production of a mixture of end-products including NH4+. Fe(III) oxide (high surface area goethite) reduction took place - after NO3- was depleted and continued until all the acetate was utilized. Addition of NO3 after Fe(III) reduction ceased resulted in the immediate oxidation of Fe(II) coupled to reduction of + NO3-to NH4 . No significant NO2- accumulation was observed during nitrate-dependent Fe(II) oxidation. No Fe(II) oxidation occurred in pasteurized controls. Microbial community structure in the enrichment was monitored by DGGE analysis of PCR amplified 16s rDNA and RT-PCR amplified 16S rRNA, as well as by construction of 16S rDNA clone libraries for four different time points during the experiment. Strong similarities in dominant members of the microbial community were observed in the Fe(III) reduction and nitrate-dependent Fe(II) oxidation phases of the experiment, specifically the common presence of organisms closely related (= 95% sequence similarity) to the genera Geobacter and Dechloromonas. These results indicate that the wetland sediments contained organisms such as Geobacter sp. which are capable of both + dissimilatory Fe(III) reduction and oxidation of Fe(II) with reduction of NO3-reduction to NH4 . Our findings suggest that microbially-catalyzed nitrate-dependent Fe(II) oxidation has the potential to contribute to a dynamic anaerobic Fe redox cycle in freshwater sediments.

Weber, Karrie A.; Urrutia, Matilde M.; Churchill, Perry F.; Kukkadapu, Ravi K.; Roden, Eric E.

2006-01-01T23:59:59.000Z

176

Molecular cloning and characterization of important stress and redox regulatory genes from Hydra vulgaris  

E-Print Network [OSTI]

In this research, important stress and redox regulatory genes present in Hydra vulgaris were isolated and characterized to facilitate our understanding of the evolution and mechanisms of stress response. H. vulgaris heat shock protein 70 (HvHSP70...

Dash, Bhagirathi

2007-04-25T23:59:59.000Z

177

Hybrid density functional calculations of redox potentials and formation energies of transition metal compounds  

E-Print Network [OSTI]

We compare the accuracy of conventional semilocal density functional theory (DFT), the DFT+U method, and the Heyd-Scuseria-Ernzerhof (HSE06) hybrid functional for structural parameters, redox reaction energies, and formation ...

Ceder, Gerbrand

178

Consequences of redox-active phenazines on the physiology of the opportunistic pathogen Pseudomonas aeruginosa  

E-Print Network [OSTI]

Phenazines are redox-active small molecules produced by bacteria. Although phenazines have been studied extensively for their roles as toxins, how phenazines benefit producing organisms is still being uncovered. Pseudomonas ...

Kern, Suzanne E

2013-01-01T23:59:59.000Z

179

The role of Ncb5or in fatty acid metabolism and redox homeostasis  

E-Print Network [OSTI]

The endoplasmic reticulum (ER)-associated NADH cytochrome b5 oxidoreductase (Ncb5or) is widely distributed in animal tissues. It contains two redox domains that are homologous to microsomal cytochrome b5 (Cyb5A) at the N ...

Xu, Ming

2011-12-31T23:59:59.000Z

180

Redox states of Desulfovibrio vulgaris DsrC, a key protein in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Venceslau SS, JR Cort, ES Baker, RK Chu, EW Robinson, C Dahl, LM Saraiva, and IA Pereira.2013."Redox states of Desulfovibrio vulgaris DsrC, a key protein in dissimilatory...

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

In a report published in Chemical Reviews, PNNL  

E-Print Network [OSTI]

temperature range for the vanadium redox flow battery. Such advances are critical to achieve necessary life cycle costs and lifetimes for grid-related storage systems. This artist's rendering of an upgradedIn a report published in Chemical Reviews, PNNL researchers say future batteries used by the energy

182

Lithium-vanadium advanced blanket development. ITER final report on U.S. contribution: Task T219/T220  

SciTech Connect (OSTI)

The objective of this task is to develop the required data base and demonstrate the performance of a liquid lithium-vanadium advanced blanket design. The task has two main activities related to vanadium structural material and liquid lithium system developments. The vanadium alloy development activity included four subtasks: (1.1) baseline mechanical properties of non irradiated base metal and weld metal joints; (1.2) compatibility with liquid lithium; (1.3) material irradiation tests; and (1.4) development of material manufacturing and joining methods. The lithium blanket technology activity included four subtasks: (2.1) electrical insulation development and testing for liquid metal systems; (2.2) MHD pressure drop and heat transfer study for self-cooled liquid metal systems; (2.3) chemistry of liquid lithium; and (2.4) design, fabrication and testing of ITER relevant size blanket mockups. A summary of the progress and results obtained during the period 1995 and 1996 in each of the subtask areas is presented in this report.

Smith, D.L.; Mattas, R.F. [comps.

1997-07-01T23:59:59.000Z

183

Single-crystal structure of vanadium-doped La{sub 2}Mo{sub 2}O{sub 9}  

SciTech Connect (OSTI)

A high-precision X-ray diffraction study of single crystals of two compositions-La{sub 2}Mo{sub 1.78}V{sub 0.22}O{sub 8.89} and La{sub 2}Mo{sub 1.64}V{sub 0.36}O{sub 8.82}-was performed. In the vanadium-doped compounds, as in the structure of the metastable {beta}{sub ms} phase of pure La{sub 2}Mo{sub 2}O{sub 9}, the La and Mo atoms and one of the three oxygen atoms are displaced from the threefold axis, on which they are located in the high-temperature {beta} phase. The structure contains two partially occupied oxygen sites. It was shown that molybdenum atoms are partially replaced by vanadium atoms, which are not involved in the disordering, are located on the threefold axis, and are shifted toward one of the oxygen atoms. This is consistent with the temperature-induced changes in the structure of La{sub 2}Mo{sub 2}O{sub 9} and the changes in the properties of these crystals caused by the introduction of vanadium atoms into the structure.

Alekseeva, O. A., E-mail: olalex@ns.crys.ras.ru; Antipin, A. M. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Gagor, A.; Pietraszko, A. [Polish Academy of Sciences, Trzebiatowski Institute of Low Temperature and Structure Research (Poland)] [Polish Academy of Sciences, Trzebiatowski Institute of Low Temperature and Structure Research (Poland); Novikova, N. E.; Sorokina, N. I. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Kharitonova, E. P.; Voronkova, V. I. [Moscow State University (Russian Federation)] [Moscow State University (Russian Federation)

2013-11-15T23:59:59.000Z

184

Redox reaction and foaming in nuclear waste glass melting  

SciTech Connect (OSTI)

This document was prepared by Pacific Northwest Laboratory (PNL) and is an attempt to analyze and estimate the effects of feed composition variables and reducing agent variables on the expected chemistry of reactions occurring in the cold cap and in the glass melt in the nuclear waste glass Slurry-fed, joule-heated melters as they might affect foaming during the glass-making process. Numerous redox reactions of waste glass components and potential feed additives, and the effects of other feed variables on these reactions are reviewed with regard to their potential effect on glass foaming. A major emphasis of this report is to examine the potential positive or negative aspects of adjusting feed with formic acid as opposed to other feed modification techniques including but not limited to use of other reducing agents. Feed modification techniques other than the use of reductants that should influence foaming behavior include control of glass melter feed pH through use of nitric acid. They also include partial replacement of sodium salts by lithium salts. This latter action (b) apparently lowers glass viscosity and raises surface tension. This replacement should decrease foaming by decreasing foam stability.

Ryan, J.L.

1995-08-01T23:59:59.000Z

185

100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater  

SciTech Connect (OSTI)

A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the 100 D Area of the U. S. Department of Energy's Hanford Site. The target contaminant was dissolved chromate in groundwater. The ISRM technology creates a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron to ferrous iron within the aquifer sediments, which is accomplished by injecting aqueous sodium dithionite into the aquifer and then withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in spring 1997; the first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998. The remaining four dithionite injections were carried out in May through July of 1998.These five injections created a reduced zone in the Hanford unconfined aquifer approximately 150 feet in length (perpendicular to groundwater flow) and 50 feet wide. The reduced zone extended over the thickness of the unconfined zone. Analysis of post-emplacement groundwater samples showed concentrations of chromate, in the reduced zone decreased from approximately 1.0 mg/L before the tests to below analytical detection limits (<0.007 mg/L). Chromate concentrations also declined in downgradient monitoring wells to as low as 0.020 mg/L. These data, in addition to results from pre-test reducible iron characterization, indicate the barrier should be effective for 20 to 25 years. The 100-D Area ISRM barrier is being expanded to a length of up to 2,300 ft to capture a larger portion of the chromate plume.

Williams, Mark D.; Vermeul, Vincent R.; Szecsody, James E.; Fruchter, Jonathan S.

2000-10-12T23:59:59.000Z

186

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of the longwave ICRCCM3:ElseBased Redox

187

A New Direction in Dye-Sensitized Solar Cells Redox Mediator Development: In Situ Fine-Tuning of the Cobalt(II)/(III) Redox  

E-Print Network [OSTI]

A New Direction in Dye-Sensitized Solar Cells Redox Mediator Development: In Situ Fine 3168, Australia *S Supporting Information ABSTRACT: Dye-sensitized solar cells (DSCs) are an attractive to tackle present and future energy challenges. Dye-sensitized solar cells (DSCs) are considered

188

Carbon-carbon bond cleavage of 1,2-hydroxy ethers b7 vanadium(V) dipicolinate complexes  

SciTech Connect (OSTI)

The development of alternatives to current petroleum-based fuels and chemicals is becoming increasingly important due to concerns over climate change, growing world energy demand, and energy security issues. Using non-food derived biomass to produce renewable feedstocks for chemicals and fuels is a particularly attractive possibility. However, the majority of biomass is in the form of lignocellulose, which is often not fully utilized due to difficulties associated with breaking down both lignin and cellulose. Recently, a number of methods have been reported to transform cellulose directly into more valuable materials such as glucose, sorbitol, 5-(chloromethyl)furfural, and ethylene glycol. Less progress has been made with selective transformations of lignin, which is typically treated in paper and forest industries by kraft pulping (sodium hydroxide/sodium sulfide) or incineration. Our group has begun investigating aerobic oxidative C-C bond cleavage catalyzed by dipicolinate vanadium complexes, with the idea that a selective C-C cleavage reaction of this type could be used to produce valuable chemicals or intermediates from cellulose or lignin. Lignin is a randomized polymer containing methoxylated phenoxy propanol units. A number of different linkages occur naturally; one of the most prevalent is the {beta}-O-4 linkage shown in Figure 1, containing a C-C bond with 1,2-hydroxy ether substituents. While the oxidative C-C bond cleavage of 1,2-diols has been reported for a number of metals, including vanadium, iron, manganese, ruthenium, and polyoxometalate complexes, C-C bond cleavage of 1,2-hydroxy ethers is much less common. We report herein vanadium-mediated cleavage of C-C bonds between alcohol and ether functionalities in several lignin model complexes. In order to explore the scope and potential of vanadium complexes to effect oxidative C-C bond cleavage in 1,2-hydroxy ethers, we examined the reactivity of the lignin model complexes pinacol monomethyl ether (A), 2-phenoxyethanol (B), and 1,2-diphenyl-2-methoxyethanol (C) (Figure 1). Reaction of (dipic)V{sup V}(O)O{sup i}Pr (1a) or (dipic)V{sup v}(O)OEt (lb) with A, B, or C in acetonitrile yielded new vanadium(V) complexes where the alcohol-ether ligand was bound in a chelating fashion. From the reaction of 1b with pinacol monomethyl ether (A) in acetonitrile solution, (dipic)V{sup v}(O)(pinOMe) (2) (PinOMe = 2,3-dimethyl-3-methoxy-2-butanoxide) was isolated in 61 % yield. Reaction of 1b with 2-phenoxyethanol (B) in acetonitrile gave the new complex (dipic)V{sup v}(O)(OPE) (3) (OPE = 2-phenoxyethoxide), which was isolated in 76% yield. In a similar fashion, 1a reacted with 1,2-diphenyl-2-methoxyethanol (C) to give (dipic)V(O)(DPME) (4) (DPME = 1,2-diphenyl-2-methoxyethoxide), which was isolated in 39% yield. Complexes 2, 3, and 4 were characterized by {sup 1}H NMR and IR spectroscopy, elemental analysis, and X-ray crystallography. Compared to the previously reported vanadium(V) pinacolate complex (dipic)V(O)(pinOH) the X-ray structure of complex 2 reveals a slightly shorter V = O bond, 1.573(2) {angstrom} vs 1.588(2) {angstrom} for the pinOH structure. Complexes 3 and 4 display similar vanadium oxo bond distances of 1.568(2) {angstrom} and 1.576(2) {angstrom}, respectively. All three complexes show longer bonds to the ether-oxygen trans to the oxo (2.388(2) {angstrom} for 2, 2.547(2) {angstrom} for 3, and 2.438(2) {angstrom} for 4) than to the hydroxy-oxygen in the pinOH structure (2.252(2) {angstrom}).

Hanson, Susan K [Los Alamos National Laboratory; Gordon, John C [Los Alamos National Laboratory; Thorn, David L [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory; Baker, R Tom [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

189

In situ characterization of nanoscale catalysts during anodic redox processes  

SciTech Connect (OSTI)

Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

Sharma, Renu [National Institute of Standards and Technology] National Institute of Standards and Technology; Crozier, Peter [Arizona State University] Arizona State University; Adams, James [Arizona State University] Arizona State University

2013-09-19T23:59:59.000Z

190

The Integration of a Structural Water Gas Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device  

SciTech Connect (OSTI)

This project is in response to a requirement for a system that combines water gas shift technology with separation technology for coal derived synthesis gas. The justification of such a system would be improved efficiency for the overall hydrogen production. By removing hydrogen from the synthesis gas stream, the water gas shift equilibrium would force more carbon monoxide to carbon dioxide and maximize the total hydrogen produced. Additional benefit would derive from the reduction in capital cost of plant by the removal of one step in the process by integrating water gas shift with the membrane separation device. The answer turns out to be that the integration of hydrogen separation and water gas shift catalysis is possible and desirable. There are no significant roadblocks to that combination of technologies. The problem becomes one of design and selection of materials to optimize, or at least maximize performance of the two integrated steps. A goal of the project was to investigate the effects of alloying elements on the performance of vanadium membranes with respect to hydrogen flux and fabricability. Vanadium was chosen as a compromise between performance and cost. It is clear that the vanadium alloys for this application can be produced, but the approach is not simple and the results inconsistent. For any future contracts, large single batches of alloy would be obtained and rolled with larger facilities to produce the most consistent thin foils possible. Brazing was identified as a very likely choice for sealing the membranes to structural components. As alloying was beneficial to hydrogen transport, it became important to identify where those alloying elements might be detrimental to brazing. Cataloging positive and negative alloying effects was a significant portion of the initial project work on vanadium alloying. A water gas shift catalyst with ceramic like structural characteristics was the second large goal of the project. Alumina was added as a component of conventional high temperature water gas shift iron oxide based catalysts. The catalysts contained Fe-Al-Cr-Cu-O and were synthesized by co-precipitation. A series of catalysts were prepared with 5 to 50 wt% Al2O3, with 8 wt% Cr2O3, 4 wt% CuO, and the balance Fe2O3. All of the catalysts were compared to a reference WGS catalyst (88 wt% FeOx, 8 wt% Cr2O3, and 4 wt% CuO) with no alumina. Alumina addition to conventional high temperature water gas shift catalysts at concentrations of approximately 15 wt% increased CO conversion rates and increase thermal stability. A series of high temperature water gas shift catalysts containing iron, chromia, and copper oxides were prepared with small amounts of added ceria in the system Fe-Cr-Cu-Ce-O. The catalysts were also tested kinetically under WGS conditions. 2-4 wt% ceria addition (at the expense of the iron oxide content) resulted in increased reaction rates (from 22-32% higher) compared to the reference catalyst. The project goal of a 10,000 liter per day WGS-membrane reactor was achieved by a device operating on coal derived syngas containing significant amounts of carbon monoxide and hydrogen sulfide. The membrane flux was equivalent to 52 scfh/ft2 based on a 600 psi syngas inlet pressure and corresponded to membranes costing $191 per square foot. Over 40 hours of iv exposure time to syngas has been achieved for a double membrane reactor. Two modules of the Chart reactor were tested under coal syngas for over 75 hours with a single module tested for 50 hours. The permeance values for the Chart membranes were similar to the REB reactor though total flux was reduced due to significantly thicker membranes. Overall testing of membrane reactors on coal derived syngas was over 115 hours for all reactors tested. Testing of the REB double membrane device exceeded 40 hours. Performance of the double membrane reactor has been similar to the results for the single reactor with good maintenance of flux even after these long exposures to hydrogen sulfide. Of special interest is that the flux is highest at the start of each e

Barton, Thomas; Argyle, Morris; Popa, Tiberiu

2009-06-30T23:59:59.000Z

191

Poly(3,4-ethylenedioxypyrrole) Modified Emitter Electrode for Substitution of Homogeneous Redox Buffer Agent Hydroquinone in Electrospray Ionization Mass Spectrometry  

SciTech Connect (OSTI)

The electrolysis inherent to the operation of the electrospray ionization (ESI) source used with mass spectrometry (MS) is a well-known attendant effect of generating unipolar spray droplets and may affect the analysis of the analyte of interest. Undesirable electrolysis of an analyte may be prevented by limiting the emitter electrode current and/or the mass transport characteristics of the system. However, these ways to avoid analyte electrolysis may not be applcable in all ESI-MS experiments. For example, in the case of specific nanospray systems (e.g. the wire-in-a-capillary bulk-loaded or chip-based tip-loaded nanospray configurations), the solution flow rate is fixed in the 50-500 nL/min range and the electrode surface to volume ratio is large presenting a very effcient analyte to electrode mass transport configuration. In these situations, control over the interfacial potential of the working electrode via homogeneous or traditional heterogeneous (sacrificial metal) redox buffering is a possible way to prevent analyte electrolysis. However, byproducts of these redox buffering approaches can appear in the mass spectra and/or they can chemically alter the analyte. For example, the main reason for using hydroquinone as a homogeneous redox buffer, in addition to its relatively low oxidation potential, is that neither the original compound nor its oxidation product benzoquinone can be detected directly by ESI-MS. However, benzoquinone can alter analytes with thiol functional groups by reacting with those groups via a 1,4-Michael addition.

Peintler-Krivan, Emese [ORNL; Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

2010-01-01T23:59:59.000Z

192

Structural insights into the modulation of the redox properties of two Geobacter sulfurreducens homologous triheme cytochromes.  

SciTech Connect (OSTI)

The redox properties of a periplasmic triheme cytochrome, PpcB from Geobacter sulfurreducens, were studied by NMR and visible spectroscopy. The structure of PpcB was determined by X-ray diffraction. PpcB is homologous to PpcA (77% sequence identity), which mediates cytoplasmic electron transfer to extracellular acceptors and is crucial in the bioenergetic metabolism of Geobacter spp. The heme core structure of PpcB in solution, probed by 2D-NMR, was compared to that of PpcA. The results showed that the heme core structures of PpcB and PpcA in solution are similar, in contrast to their crystal structures where the heme cores of the two proteins differ from each other. NMR redox titrations were carried out for both proteins and the order of oxidation of the heme groups was determined. The microscopic properties of PpcB and PpcA redox centers showed important differences: (1) the order in which hemes become oxidized is III-I-IV for PpcB, as opposed to I-IV-III for PpcA; (2) the redox-Bohr effect is also different in the two proteins. The different redox features observed between PpcB and PpcA suggest that each protein uniquely modulates the properties of their co-factors to assure effectiveness in their respective metabolic pathways. The origins of the observed differences are discussed.

Morgado, L.; Bruix, M.; Orshonsky, V.; Londer, Y. Y.; Duke, N. E. C.; Yang, X.; Pokkuluri, P. R.; Schiffer, M.; Salgueiro, C. A.; Biosciences Division; Univ. Nova de Lisboa; Insti. de Quimica-Fisica

2008-09-01T23:59:59.000Z

193

Gapless Spin Liquid Ground State in the S 1=2 Vanadium Oxyfluoride Kagome Antiferromagnet NH42C7H14NV7O6F18  

E-Print Network [OSTI]

7H14N½V7O6F18 L. Clark,1 J. C. Orain,2 F. Bert,2 M. A. De Vries,1 F. H. Aidoudi,3 R. E. Morris,3 P, France (Received 12 February 2013; published 16 May 2013) The vanadium oxyfluoride ½NH42½C7H14N½V7O6F1842½C7H14N½V7O6F18 [dia- mmonium quinuclidinium vanadium(III,IV) oxyfluoride; DQVOF] [15

Paris-Sud 11, Université de

194

An analysis of a back-fed porous electrode for the bromine/bromide redox reaction  

E-Print Network [OSTI]

AN ANALYSIS OF A BACK-FED POROUS ELECTRODE FOR THE BROMINE/BROMIDE REDOX REACTION A Thesis by JOHN WILLIAM VAN ZEE Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1982 Major Subject: Chemical Engineering AN ANALYSIS OF A BACK-FED POROUS ELECTRODE FOR THE BROMINE/BROMIDE REDOX REACTION A Thesis by JOHN WILLIAM VAN ZEE Approved as to style and content by: (Chai man of Committee) (Member...

Van Zee, John William

2012-06-07T23:59:59.000Z

195

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial  

E-Print Network [OSTI]

The redox nature of copper is utilized in a large number of enzymatic processes, including that catalysed by mitochondrial cytochrome c oxidase, which makes copper an essential element for all aerobic organisms (Soloman and Lowery, 1993). However, the redox properties of copper can cause rapid generation

Grosell, Martin

196

Final Technical Report  

SciTech Connect (OSTI)

The overall goal of this project was to design, evaluate, and engineer a Vanadium Red-Ox Flow Battery's integration into an existing wind site and micro-grid environment to determine if it is possible to achieve a fifteen percent reduction of diesel fuel usage during periods of peak load and otherwise stabilize the grid in potential high wind penetration systems. The bulk of the work was done by modeling the existing hybrid wind-diesel system and the proposed system with added flow battery storage. The flow battery was changed from a Vanadium Red-Ox to a Zinc Bromine flow battery by a different manufacturer during the modeling process. Several complications arose, but modeling proved to be successful and is ongoing. The development of a modeling platform for flow battery energy storage is a key element in evaluating both economic benefits and dispatch strategies for high penetration in micro-grid wind-diesel systems.

Logan, Jesse, L; Witmer, Dennis, PhD

2012-07-29T23:59:59.000Z

197

Optical switching and photoluminescence in erbium-implanted vanadium dioxide thin films  

SciTech Connect (OSTI)

Vanadium dioxide (VO{sub 2}) is under intensive consideration for optical switching due to its reversible phase transition, which features a drastic and rapid shift in infrared reflectivity. Classified as an insulator–to–metal transition, the phase transition in VO{sub 2} can be induced thermally, electrically, and optically. When induced optically, the transition can occur on sub-picosecond time scales. It is interesting to dope VO{sub 2} with erbium ions (Er{sup 3+}) and observe their combined properties. The first excited-state luminescence of Er{sup 3+} lies within the wavelength window of minimal transmission-loss in silicon and has been widely utilized for signal amplification and generation in silicon photonics. The incorporation of Er{sup 3+} into VO{sub 2} could therefore result in a novel photonic material capable of simultaneous optical switching and amplification. In this work, we investigate the optical switching and photoluminescence in Er-implanted VO{sub 2} thin films. Thermally driven optical switching is demonstrated in the Er-implanted VO{sub 2} by infrared reflectometry. Photoluminescence is observed in the thin films annealed at ?800?°C or above. In addition, Raman spectroscopy and a statistical analysis of switching hysteresis are carried out to assess the effects of the ion implantation on the VO{sub 2} thin films. We conclude that Er-implanted VO{sub 2} can function as an optical switch and amplifier, but with reduced switching quality compared to pure VO{sub 2}.

Lim, Herianto, E-mail: mail@heriantolim.com; Stavrias, Nikolas; Johnson, Brett C.; McCallum, Jeffrey C. [School of Physics, University of Melbourne, Parkville, Victoria 3010 (Australia); Marvel, Robert E.; Haglund, Richard F. [Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37240 (United States)

2014-03-07T23:59:59.000Z

198

Characterization of protein redox dynamics induced during light-to-dark transitions and nutrient limitation in cyanobacteria  

SciTech Connect (OSTI)

Protein redox chemistry constitutes a major void in knowledge pertaining to photoautotrophic system regulation and signaling processes. We have employed a chemical biology approach to analyze redox sensitive proteins in live Synechococcus sp. PCC 7002 cells in both light and dark periods, and to understand how cellular redox balance is disrupted during nutrient perturbation. The present work identified several novel putative redox-sensitive proteins that are involved in the generation of reductant, macromolecule synthesis, and carbon flux through central metabolic pathways, and may be involved in cell signaling and response mechanisms. Furthermore, our research suggests that dynamic redox changes in response to specific nutrient limitations contribute to the regulatory changes driven by a shift from light to dark. Taken together, these results contribute to the high-level understanding of post-translational mechanisms regulating flux distributions and therefore present potential metabolic engineering targets for redirecting carbon towards biofuel precursors.

Ansong, Charles; Sadler, Natalie C.; Hill, Eric A.; Lewis, Michael P.; Zink, Erika M.; Smith, Richard D.; Beliaev, Alex S.; Konopka, Allan; Wright, Aaron T.

2014-07-03T23:59:59.000Z

199

Redox reactions of reduced flavin mononucleotide (FMN), riboflavin (RBF), and anthraquinone-2,6-disulfonate (AQDS) with ferrihydrite and lepidocrocite  

SciTech Connect (OSTI)

Flavins are secreted by the dissimilatory iron-reducing bacterium Shewanella and can function as endogenous electron transfer mediators (ETM). In order to assess the potential importance of flavins in Fe(III) bioreduction, we investigated the redox reaction kinetics of reduced flavins (FMNH2 and RBFH2) with ferrihydrite and lepidocrocite. The organic reductants rapidly reduced and dissolved ferrihydrite and lepidocrocite in the pH range 4-8. The rate constant k for 2-line ferrihydrite reductive dissolution by FMNH2 was 87.5 ? 3.5 M-1?s-1 at pH 7.0 in batch reactors, and the k was similar for RBFH2. For lepidocrocite, the k was 500 ? 61 M-1?s-1 for FMNH2, and 236 ? 22 M-1?s-1 for RBFH2. The surface area normalized initial reaction rates (ra) were between 0.08 and 77 ?moles?m-2?s-1 for various conditions in stopped-flow experiments. Initial rates (ro) were first-order with respect to Fe(III) oxide concentration, and ra increased with decreasing pH. Poorly crystalline 2-line ferrihydrite yielded the highest ra, followed by more crystalline 6-line ferrihydrite, and crystalline lepidocrocite. Compared to a previous whole-cell study with Shewanella oneidensis strain MR-1, our findings suggest that ETM reduction by the Mtr pathway coupled to lactate oxidation are rate limiting, rather than heterogeneous electron transfer to the Fe(III) oxide.

Shi, Zhi; Zachara, John M.; Shi, Liang; Wang, Zheming; Moore, Dean A.; Kennedy, David W.; Fredrickson, Jim K.

2012-11-01T23:59:59.000Z

200

Paper Offer #: 031CES-216 PlanarArray REDOX Cells and pH Sensors  

E-Print Network [OSTI]

, is below one pM which is needed for water quality measurements. The richness of the detectable speciesPaper Offer #: 031CES-216 PlanarArray REDOX Cells and pH Sensors for ISS Water Quality and Microbe which exposes these elements to steam at 121°C for 30 minutes. INTRODUCTION The goal of this effort

Kounaves, Samuel P.

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase  

E-Print Network [OSTI]

The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

Feng, Jian

2005-08-29T23:59:59.000Z

202

Antibiotics induce redox-related physiological alterations as part of their lethality  

E-Print Network [OSTI]

and death, thus supporting an evolving, expanded model of antibiotic lethality. reactive oxygen species Center of Synthetic Biology, Boston University, Boston, MA 02215; Departments of d Chemistry and e antibiotics elevate oxygen consumption, indicating significant alterations to bacterial redox physiology. We

203

Redox states of Desulfovibrio vulgaris DsrC, a key protein in dissimilatory sulfite reduction  

SciTech Connect (OSTI)

Highlights: •DsrC is known to interact with the dissimilatory sulfite reductase enzyme (DsrAB). •We show that, however, most cellular DsrC is not associated with DsrAB. •A gel-shift assay was developed that allows monitoring of the DsrC redox state. •The DsrC intramolecularly oxidized state could only be produced by arginine treatment. -- Abstract: Dissimilatory reduction of sulfite is carried out by the siroheme enzyme DsrAB, with the involvement of the protein DsrC, which has two conserved redox-active cysteines. DsrC was initially believed to be a third subunit of DsrAB. Here, we report a study of the distribution of DsrC in cell extracts to show that, in the model sulfate reducer Desulfovibrio vulgaris, the majority of DsrC is not associated with DsrAB and is thus free to interact with other proteins. In addition, we developed a cysteine-labelling gel-shift assay to monitor the DsrC redox state and behaviour, and procedures to produce the different redox forms. The oxidized state of DsrC with an intramolecular disulfide bond, which is proposed to be a key metabolic intermediate, could be successfully produced for the first time by treatment with arginine.

Venceslau, Sofia S. [Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Oeiras (Portugal)] [Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Oeiras (Portugal); Cort, John R.; Baker, Erin S. [Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352 (United States)] [Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Chu, Rosalie K.; Robinson, Errol W. [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352 (United States)] [Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Dahl, Christiane [Institut für Mikrobiologie and Biotechnologie, Rheinische Friedrich-Wilhelms-Universität Bonn, Meckenheimer Allee 168, D-53115 Bonn (Germany)] [Institut für Mikrobiologie and Biotechnologie, Rheinische Friedrich-Wilhelms-Universität Bonn, Meckenheimer Allee 168, D-53115 Bonn (Germany); Saraiva, Lígia M. [Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Oeiras (Portugal)] [Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Oeiras (Portugal); Pereira, Inês A.C., E-mail: ipereira@itqb.unl.pt [Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Oeiras (Portugal)

2013-11-29T23:59:59.000Z

204

A Modular Approach to Redox-active Multimetallic Amphiphiles of Discotic Topology  

SciTech Connect (OSTI)

A new modular [Fe{sup II}(Fe{sup III}L{sup 2}){sub 3}](PF{sub 6}){sub 2} species with discoid (disk-like) topology exhibits redox and surfactant properties and points to a new approach for multimetallic Langmuir film precursors.

F Lesh; R Shanmugam; M Allard; M Lanznaster; M Hegg; M Rodgers; J Shearer; C Verani

2011-12-31T23:59:59.000Z

205

J.F. ALLEN, K. ALEXCIEV AND G. HAKANSSON Regulation by redox signalling  

E-Print Network [OSTI]

,5] confirms this suspicion, and shows that redox control over photo- synthesis genes is exerted by two new', phosphorylated on aspar- tate by transfer of a phosphate from its partner, RegB. RegB is a 'sensor kinase; the genes reside in just two operons. It has long been known that the photo- synthetic apparatus

Allen, John F.

206

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus  

E-Print Network [OSTI]

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus and Frauke Gra, China ABSTRACT Mechanical force applied along a disulfide bond alters its rate of reduction. We here within proteins by point mutations. INTRODUCTION Similar to thermal or light energy, mechanical force can

Gräter, Frauke

207

Redox-linked conformational changes of a multiheme cytochrome from Geobacter sulfurreducens  

SciTech Connect (OSTI)

Multiheme c-type cytochromes from members of the Desulfovibrionacea and Geobactereacea families play crucial roles in the bioenergetics of these microorganisms. Thermodynamic studies using NMR and visible spectroscopic techniques on tetraheme cytochromes c {sub 3} isolated from Desulfovibrio spp. and more recently on a triheme cytochrome from Geobacter sulfurreducens showed that the properties of each redox centre are modulated by the neighbouring redox centres enabling these proteins to perform energy transduction and thus contributing to cellular energy conservation. Electron/proton transfer coupling relies on redox-linked conformational changes that were addressed for some multiheme cytochromes from the comparison of protein structure of fully reduced and fully oxidised forms. In this work, we identify for the first time in a multiheme cytochrome the simultaneous presence of two different conformations in solution. This was achieved by probing the different oxidation stages of a triheme cytochrome isolated from G. sulfurreducens using 2D-NMR techniques. The results presented here will be the foundations to evaluate the modulation of the redox centres properties by conformational changes that occur during the reoxidation of a multiheme protein.

Morgado, Leonor [Requimte - CQFB, Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Bruix, Marta [Departamento de Espectroscopia y Estructura Molecular, Instituto de Quimica-Fisica 'Rocasolano', CSIC, Serrano 119, 28006 Madrid (Spain); Londer, Yuri Y. [Biosciences Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Pokkuluri, P. Raj [Biosciences Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Schiffer, Marianne [Biosciences Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Salgueiro, Carlos A. [Requimte - CQFB, Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal)]. E-mail: csalgueiro@dq.fct.unl.pt

2007-08-17T23:59:59.000Z

208

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions  

E-Print Network [OSTI]

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions A novel coordination polymer of mixed-valence copper(I,II) with 4,4A-bipyridine and in situ oxidized and crystallographically char- acterized to be a laminated structure via weak copper(II)­ oxygen interactions. Extended

Li, Jing

209

Quantification of rapid environmental redox processes with quick-scanning x-ray absorption  

E-Print Network [OSTI]

Quantification of rapid environmental redox processes with quick-scanning x-ray absorption. Here we apply quick-scanning x-ray absorption spectroscopy (Q-XAS), at sub-second time that can be measured using x-ray absorption spectroscopy. arsenic extended x-ray absorption fine structure

Sparks, Donald L.

210

Flow chamber  

DOE Patents [OSTI]

A flow chamber having a vacuum chamber and a specimen chamber. The specimen chamber may have an opening through which a fluid may be introduced and an opening through which the fluid may exit. The vacuum chamber may have an opening through which contents of the vacuum chamber may be evacuated. A portion of the flow chamber may be flexible, and a vacuum may be used to hold the components of the flow chamber together.

Morozov, Victor (Manassas, VA)

2011-01-18T23:59:59.000Z

211

Geological flows  

E-Print Network [OSTI]

In this paper geology and planetology are considered using new conceptual basis of high-speed flow dynamics. Recent photo technics allow to see all details of a flow, 'cause the flow is static during very short time interval. On the other hand, maps and images of many planets are accessible. Identity of geological flows and high-speed gas dynamics is demonstrated. There is another time scale, and no more. All results, as far as the concept, are new and belong to the author. No formulae, pictures only.

Yu. N. Bratkov

2008-11-19T23:59:59.000Z

212

In Situ Redox Manipulation Proof-of-Principle Test at the Fort Lewis Logistics Center: Final Report  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) conducted a proof-of-principle test at the Fort Lewis Logistics Center to determine the feasibility of using the In Situ Redox Manipulation (ISRM) technology for remediating groundwater contaminated with dissolved trichloroethylene (TCE). ISRM creates a permeable treatment zone in the subsurface to remediate redox-sensitive contaminants in groundwater. The permeable treatment zone is formed by injecting a chemical reducing agent (sodium dithionite with pH buffers) into the aquifer through a well to reduce the naturally occurring ferric iron in the sediments to ferrous iron. Once the reducing agent is injected and given sufficient time to react with aquifer sediments, residual chemicals and reaction products are withdrawn from the aquifer through the same well used for the injection. Redox-sensitive contaminants such as TCE, moving through the treatment zone under natural groundwater flow conditions, are destroyed. TCE is degraded via reductive dechlorination within the ISRM treatment zone to benign degradation products (i.e., acetylene, ethylene). Prior to the proof-of-principle field test, the ISRM technology was successfully demonstrated in laboratory experiments for the reductive dechlorination of dissolved TCE using sediments from the Fort Lewis site. The Logistics Center was placed on the National Priorities List in December 1989 because of TCE contamination in groundwater beneath the site. A Federal Facilities Agreement between the Army, the U.S. Environmental Protection Agency, and the Washington State Department of Ecology became effective in January 1990, and a Record of Decision (ROD) was signed in September 1990. The major components of the ROD included installation of two pump-and-treat systems for the upper aquifer and further investigation of the lower aquifer and other potential sources of contamination. The pump-and-treat systems became operational in August 1995. Fort Lewis asked PNNL to provide technical support in accelerating Installation Restoration Program site remediation and significantly reducing site life-cycle costs at the Logistics Center. In support of this program, ISRM was selected as an innovative technology for bench and field-scale demonstration. Emplacement of the ISRM treatment zone was accomplished through a series of four separate dithionite injection tests conducted between November 10, 1998 and March 29,2000. An extensive program of chemical monitoring was also performed before, during, and after each injection to evaluate the performance of ISRM. Prior to emplacement of the ISRM treatment zone, the site was extensively characterized with respect to geologic, hydrologic, and geochemical properties. Sediment core samples collected for the characterization studies were analyzed in bench-scale column tests at PNNL to determine reducible iron content. These site-specific hydrogeologic and geochemical data were used to develop the emplacement design of the pilot-scale (i.e., single injection well) ISRM treatment zone. Performance data obtained from the proof-of-principle test indicate that field-scale reductive dechlorination of TCE using the ISRM technology is feasible. A treatment zone was created in the subsurface that reduced TCE concentrations as much as 92% on the downgradient side of the reduced zone, from a background concentration of approximately 140 ppb to approximately 11 ppb. The appearance of the principal degradation product, acetylene, also confirmed that TCE destruction was occurring. Analysis of sediment samples collected from post-test boreholes showed a high degree of iron reduction, which helped to confirm the effectiveness of the treatment zone emplacement. Another important goal of the testing program was to provide assurances that chemical treatment of the subsurface did not result in undesirable secondary effects, including formation of toxic TCE degradation products, mobilization of trace elements, and degradation of hydraulic performance. Results obtained from the Fort Lewis ISRM proof-of-principle test, which are c

VR Vermeul; MD Williams; JC Evans; JE Szecsody; BN Bjornstad; TL Liikala

2000-10-25T23:59:59.000Z

213

Synthesis and characterization of vanadium oxide aerogels. Technical report No. 2, 1 June 1994-31 May 1995  

SciTech Connect (OSTI)

Vanadium pentoxide aerogels were synthesized by supercritical drying with CO2. The aerogels were prepared using a variety of sol compositions from the system VO(OC3H7)3/H2O/acetone. The materials were found to be of fairly low density (0.04g/cu cm to 0.lg/cu cm) with surface areas in the range of 300 to 400 meters squared/g. Chemical and structural studies indicate that the aerogels are hydrated oxides of composition V2O5 nH2O with n = 2.0 to 2.2 and possess a fibrous morphology. When partially dehydrated, the vanadate aerogels exhibit electron transport with conductivity and activation energy values comparable to those of aerogels. Electrochemical measurements demonstrate that lithium can be intercalated reversibly into the structure.

Chaput, F.; Dunn, B.; Fuqua, P.; Salloux, K.

1995-07-14T23:59:59.000Z

214

Hot gas desulfurization with sorbents containing oxides of zinc, iron, vanadium and copper. Quarterly technical progress report, July 1992  

SciTech Connect (OSTI)

The main objective of this research is to evaluate the desulfurization performance of novel sorbents consisting of different combinations of zinc, iron, vanadium and copper oxides; and to develop a sorbent which can reduce H{sub 2}S levels to less than 1 ppmv, which can stabilize zinc, making operations above 650{degrees}C possible, and which can produce economically recoverable amounts of elemental sulfur during regeneration. This objective will be accomplished by evaluating the sorbent performance using fixed-bed and TGA experiments supported by sorbent characterization at various reaction extents. In the seventh quarter, the screening of the promoted sorbents in the packed bed reactor was continued. The results of this work were presented at the 1992 University Coal Research Contractors, Review Conference at Pittsburgh, PA.

Akyurtlu, A.; Akyurtlu, J.F.

1992-09-01T23:59:59.000Z

215

Redox states of Desulfovibrio vulgaris DsrC, a key protein in dissimilatory sulfite reduction  

SciTech Connect (OSTI)

Dissimilatory reduction of sulfite is carried out by the siroheme enzyme DsrAB, with the involvement of the protein DsrC having two conserved cysteine residues. Here, we report a study of the distribution of DsrC in cell extracts, a cysteine-labelling gel-shift assay to monitor its redox state and behaviour, and procedures to produce the different redox forms. We show that, in the model sulfate reducer Desulfovibrio vulgaris, the majority of DsrC is not associated with DsrAB and is thus free to interact with other proteins. In addition, we successfully produced DsrC with an intramolecular disulfide bond (oxidized state) by treatment with arginine.

Venceslau, Sofia S.; Cort, John R.; Baker, Erin Shammel; Chu, Rosalie K.; Robinson, Errol W.; Dahl, Christiane; Saraiva, Ligia M.; Pereira, Ines Ac

2013-11-29T23:59:59.000Z

216

Cooling Flows or Heating Flows?  

E-Print Network [OSTI]

It is now clear that AGN heat cooling flows, largely by driving winds. The winds may contain a relativistic component that generates powerful synchrotron radiation, but it is not clear that all winds do so. The spatial and temporal stability of the AGN/cooling flow interaction are discussed. Collimation of the winds probably provides spatial stability. Temporal stability may be possible only for black holes with masses above a critical value. Both the failure of cooling flows to have adiabatic cores and the existence of X-ray cavities confirm the importance of collimated outflows. I quantify the scale of the convective flow that the AGN Hydra would need to drive if it balanced radiative inward flow by outward flow parallel to the jets. At least in Virgo any such flow must be confined to r<~20 kpc. Hydrodynamical simulations suggest that AGN outbursts cannot last longer than ~25 Myr. Data for four clusters with well studied X-ray cavities suggests that heating associated with cavity formation approximately balances radiative cooling. The role of cosmic infall and the mechanism of filament formation are briefly touched on.

James Binney

2003-10-08T23:59:59.000Z

217

Redox Shuttle Additive, Wins 2014 R&D 100 Award | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: AlternativeEnvironment,Institutes and Launches theResidentialRecovery ActInvestmentPolicyRedox

218

Accelerated search kinetics mediated by redox reactions of DNA repair enzymes  

E-Print Network [OSTI]

A Charge Transport (CT) mechanism has been proposed in several papers (e.g., Yavin, et al. PNAS, v102 3546 (2005)) to explain the localization of Base Excision Repair (BER) enzymes to lesions on DNA. The CT mechanism relies on redox reactions of iron-sulfur cofactors that modify the enzyme's binding affinity. These redox reactions are mediated by the DNA strand and involve the exchange of electrons between BER enzymes along DNA. We propose a mathematical model that incorporates enzyme binding/unbinding, electron transport, and enzyme diffusion along DNA. Analysis of our model within a range of parameter values suggests that the redox reactions can increase desorption of BER enzymes not already bound to their targets, allowing the enzymes to be recycled, thus accelerating the overall search process. This acceleration mechanism is most effective when enzyme copy numbers and enzyme diffusivity along the DNA are small. Under such conditions, we find that CT BER enzymes find their targets more quickly than simple "passive" enzymes that simply attach to the DNA without desorbing.

Pak-Wing Fok; Tom Chou

2009-05-20T23:59:59.000Z

219

100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater: FY 1998 Year-End Report  

SciTech Connect (OSTI)

A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the US Department of Energy's Hanford, Washington 100D Area. The target contaminant was dissolved chromate [Cr(VI)] in groundwater. The ISRM technology involves creating a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron [Fe(III)] to ferrous iron [Fe(II)] within the aquifer sediments. This is accomplished by injecting aqueous sodium dithionite into the aquifer and withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in the spring of 1997. The first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998; the remaining four dithionite injections were carried out in May through July of 1998. These five injections created a reduced zone in the Hanford unconfined aquifer 150 feet in length (perpendicular to groundwater flow) by 50 feet wide. The reduced zone extended over the thickness of the unconfined zone, which is approximately 15 feet. Analysis of recent groundwater sampling events shows that the concentrations of chromate [Cr(VI)] in groundwater in the reduced zone have been decreased from starting concentrations of approximately 900 ppb to below analytical detection limits (<7 ppb). Chromate concentrations are also declining in some downgradient monitoring wells. Laboratory analysis of iron in the soil indicates that the barrier should remain in place for approximately 20 to 25 years. These measurements will be confirmed by analysis of sediment cores in FY 1999.

Williams, M.D.; Vermeul, V.R.; Szecsody, J.E.; Fruchter, J.S.; Cole, C.R.

1999-04-15T23:59:59.000Z

220

Workshop on electrodes for flowing solution batteries. Summary report  

SciTech Connect (OSTI)

The electrochemical technology of aqueous secondary cells with flowing electrolyte solutions was the subject of a workshop sponsored by EPRI with the cooperation of DOE. The workshop was held in Tampa, Florida, 5-7 November 1979, and was attended by a select group drawn from advanced battery developers, government agencies, universities, and research organizations. The workshop general objectives were to look at the significant parameters believed to govern the performance of the two basic types of electrodes now in use; namely, a porous flow-through electrode (PFTE), and an impervious flow-by electrode. Progress, problems, and prospects were informally discussed. Brief critical reviews were given by session chairmen as a means of introducing each of the key topics (Current Distribution in FTPE, Conversion Efficiency, Segmented FTPE Studies, General Discussion on FTPF Parameters, Surface Activation, Application of FTPE to Waste Recovery, Exxon Zinc-Bromine Flow-By System, FTPE In NASA Redox Energy Storage, and Application of FTPE In Lockheed Zinc/Ferricyanide Redox System). The interaction of this diverse group of engineers and scientists was said by all to be of great benefit in widening understanding of the problems and possible future approaches to new work. The main needs for future work that were identified in the final discussion session among the participants were: (1) engineering analysis, (2) porous structures, (3) materials characteristics, and (4) chemical characteristics. In generally comparing flow-through to flow-by electrodes, there were some surprising differences arising from experimental results that did not fit conventional thinking.

Nanis, L.

1981-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Received 11 Jan 2013 | Accepted 29 Apr 2013 | Published 13 Jun 2013 Cyclic electron flow is redox-controlled  

E-Print Network [OSTI]

. Correspondence and requests for materials should be addressed to F.R. (email: Fabrice.Rappaport@ibpc.fr). NATURE Publishers Limited. All rights reserved. #12;T he injection of energy into the biosphere relies-containing stroma lamellae, thereby balancing the excitonic flux between the two photosystems10. In the unicellular

222

Some Lessons Learned from 20 Years in RedOx Flow Battery R&d | Department  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartmentScoping Study |4Solid-State TechnologiesEnergyof

223

Flow cytometer  

DOE Patents [OSTI]

A Faraday cage is described which encloses the flow chamber of a cytometer. Ground planes associated with each field deflection plate inhibit electric fields from varying the charge on designated events/droplets and further concentrates. They also increase forces applied to a passing charged event for accurate focus while concomitantly inhibiting a potential shock hazard. 4 figs.

Van den Engh, G.

1995-11-07T23:59:59.000Z

224

Redox buffered hydrofluoric acid etchant for the reduction of galvanic attack during release etching of MEMS devices having noble material films  

DOE Patents [OSTI]

Etchant solutions comprising a redox buffer can be used during the release etch step to reduce damage to the structural layers of a MEMS device that has noble material films. A preferred redox buffer comprises a soluble thiophosphoric acid, ester, or salt that maintains the electrochemical potential of the etchant solution at a level that prevents oxidation of the structural material. Therefore, the redox buffer preferentially oxidizes in place of the structural material. The sacrificial redox buffer thereby protects the exposed structural layers while permitting the dissolution of sacrificial oxide layers during the release etch.

Hankins, Matthew G. (Albuquerque, NM)

2009-10-06T23:59:59.000Z

225

Silver vanadium diphosphate Ag{sub 2}VP{sub 2}O{sub 8}: Electrochemistry and characterization of reduced material providing mechanistic insights  

SciTech Connect (OSTI)

Silver vanadium phosphorous oxides (Ag{sub w}V{sub x}P{sub y}O{sub z}) are notable battery cathode materials due to their high energy density and demonstrated ability to form in-situ Ag metal nanostructured electrically conductive networks within the cathode. While analogous silver vanadium diphosphate materials have been prepared, electrochemical evaluations of these diphosphate based materials have been limited. We report here the first electrochemical study of a silver vanadium diphosphate, Ag{sub 2}VP{sub 2}O{sub 8}, where the structural differences associated with phosphorous oxides versus diphosphates profoundly affect the associated electrochemistry. Reminiscent of Ag{sub 2}VO{sub 2}PO{sub 4} reduction, in-situ formation of silver metal nanoparticles was observed with reduction of Ag{sub 2}VP{sub 2}O{sub 8}. However, counter to Ag{sub 2}VO{sub 2}PO{sub 4} reduction, Ag{sub 2}VP{sub 2}O{sub 8} demonstrates a significant decrease in conductivity upon continued electrochemical reduction. Structural analysis contrasting the crystallography of the parent Ag{sub 2}VP{sub 2}O{sub 8} with that of the proposed Li{sub 2}VP{sub 2}O{sub 8} reduction product is employed to gain insight into the observed electrochemical reduction behavior, where the structural rigidity associated with the diphosphate anion may be associated with the observed particle fracturing upon deep electrochemical reduction. Further, the diphosphate anion structure may be associated with the high thermal stability of the partially reduced Ag{sub 2}VP{sub 2}O{sub 8} materials, which bodes well for enhanced safety of batteries incorporating this material. - Graphical abstract: Structure and galvanostatic intermittent titration-type test data for silver vanadium diphosphate, Ag{sub 2}VP{sub 2}O{sub 8}. Highlights: ? First electrochemical study of a silver vanadium diphosphate, Ag{sub 2}VP{sub 2}O{sub 8}. ? In-situ formation of Ag{sup 0} nanoparticles was observed upon electrochemical reduction. ? Structural analysis used to provide insight of the electrochemical behavior.

Takeuchi, Esther S., E-mail: esther.takeuchi@stonybrook.edu [Department Materials Science and Engineering, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Global and Regional Solutions Directorate, Brookhaven National Laboratory, Upton, NY 11973 (United States); Department of Chemistry, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Lee, Chia-Ying; Cheng, Po-Jen [Department of Chemical and Biological Engineering, University at Buffalo (SUNY), Buffalo, NY 14260 (United States); Menard, Melissa C. [Department Materials Science and Engineering, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Marschilok, Amy C., E-mail: amy.marschilok@stonybrook.edu [Department Materials Science and Engineering, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Department of Chemistry, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States); Takeuchi, Kenneth J., E-mail: kenneth.takeuchi.1@stonybrook.edu [Department of Chemistry, Stony Brook University (SUNY), Stony Brook, NY 11794 (United States)

2013-04-15T23:59:59.000Z

226

High-energy mechanical synthesis of nanophase fluorite-structured mixed oxide catalysts with a high redox activity  

SciTech Connect (OSTI)

A series of nanostructured, highly defective, ternary solid solutions containing CeO{sub 2}, ZrO{sub 2}, and MnO{sub 2} or CuO were prepared by high-energy mechanical milling of individual components. Morphological and redox properties were studied by XRD, HRTEM and temperature-programmed reduction techniques. It was shown that the introduction of small amounts of copper and manganese strongly promotes the redox behavior of cerium at lower temperatures in comparison with CeO{sub 2} and CeO{sub 2}-ZrO{sub 2}. High temperature treatment of up to 1,400 K was also shown to further promote overall redox capacity without affecting low-temperature redox behavior. Moreover, evidence is provided to show that Cu and Mn are dissolved within the CeO{sub 2} lattice structure. Addition of dopants enhances catalytic redox properties in the oxidation of CO at low temperatures, which is associated with the high concentration of oxygen vacancies that form on the introduction of aliovalent elements into the ceria-zirconia lattice.

Primavera, A.; Trovarelli, A.; Terribile, D.; Leitenburg, C. de; Dolcetti, G. [Univ. di Udine (Italy). Dipt. di Scienze e Tecnologie Chimiche; Llorca, J. [Univ. de Barcelona (Spain). Dept. de Quimica Inorganica

1997-12-31T23:59:59.000Z

227

Effects of Redox Cycling of Iron in Nontronite on Reduction of Technetium.  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed NewcatalystNeutronEnvironmentZIRKLE FRUITYearEffect0/2002catalysts:| EMSL Redox

228

SFTEL: Flow Cell | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flow Cell EMSL's Subsurface Flow and Transport Experimental Laboratory offers several meter-scale flow cells and columns for research in saturated and unsaturated porous media....

229

Influence of pH and Redox Conditions on Copper Leaching  

SciTech Connect (OSTI)

The Toxicity Characteristic Leaching Procedure (TCLP) is a regulatory leach test in the RCRA programs. It was developed to determine the leaching potential of landfilled waste in order to assess the hazards associated with the leachates. The test was developed to study concentration of hazardous materials in leachates, under a mismanagement scenario, when they are co-disposed with municipal waste. The test uses leaching of waste at either of two acidic pH values i.e., 2.8 and 4.93. While low pH leachant can extract many metals, some metals soluble at higher pH values are either underestimated or totally unaccounted for. The method also has limitations for application to different waste matrices. The procedure does not take into account the effect of redox conditions on leaching. Leaching studies are, therefore, being conducted to determine the effect of combinations of Eh and pH on the leaching potential of mineral and organic wastes. The goal of this study is to propose alternate methods applicable for a variety of waste matrices. The presentation will discuss the effects of combinations of pH and redox conditions on the leaching behavior of copper from a mineral processing waste.

Kavanaugh, Rathi; Al-Abed, Souhail R.; Purandare, Jaydeep; Allen, Derrick

2004-03-31T23:59:59.000Z

230

To be published in IEEE Aerospace Conference Proceedings, 2003, Cat No. 0-7803-7651-X/03/$17.00 2003 IEEE Planar REDOX and Conductivity Sensors  

E-Print Network [OSTI]

/$17.00 © 2003 IEEE Planar REDOX and Conductivity Sensors for ISS Water Quality Measurements1 Martin G. Buehler REDOX and conductivity sensors that are used to detect ionic species in solution by measuring the electrochemical cell current as the voltage is scanned. The simplicity and robustness of these sensors allows

Kounaves, Samuel P.

231

Molybdenum in Nuclear Waste Glasses -Incorporation and Redox state R.J. Short, R.J. Hand, N.C. Hyatt,  

E-Print Network [OSTI]

Molybdenum in Nuclear Waste Glasses - Incorporation and Redox state R.J. Short, R.J. Hand, N form in simulated high level nuclear waste (HLW) glass melts have been studied. It was found less attention has been paid to the effects of redox on nuclear waste glasses. One particular element

Sheffield, University of

232

Membranes and separators for flowing electrolyte batteries-a review  

SciTech Connect (OSTI)

Flowing electrolyte batteries are rechargeable electrochemical storage devices in which externally stored electrolytes are circulated through the cell stack during charge or discharge. The potential advantages that flow batteries offer compared to other secondary batteries include: 1) ease of thermal and electrolyte management, 2) simple electrochemistry, 3) deep cycling capability, and 4) minimal loss of capacity with cycling. However, flow batteries are more complex than other secondary batteries and consequently may cost more and may be less reliable. Flow batteries are being developed for utility load leveling, electric vehicles, solar photovoltaic and wind turbine application. The status of flow batteries has recently been reviewed by Clark et al. The flowing electrolyte batteries place rigorous demands on the performance of separators and membranes. The operating characteristics of the iron/chromium redox battery were changed in order to accommodate the limitations in membrane performance. Low cost alternatives to the presently used membrane must be found before the zinc/ferricyanide battery can be economically feasible. The zinc/bromine battery's efficiency could be improved if a suitably selective membrane were available. It is anticipated that better and less costly membranes to meet these needs will be developed as more is learned about their preparation and performance.

Arnold, C.; Assink, R.A.

1983-01-01T23:59:59.000Z

233

Ni(III)/(IV) Bis(dicarbollide) as a Fast, Noncorrosive Redox Shuttle for Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

Ni(III)/(IV) Bis(dicarbollide) as a Fast, Noncorrosive Redox Shuttle for Dye-Sensitized Solar Cells-marks@northwestern.edu; chadnano@northwestern.edu The favorable energetics of dye-sensitized solar cell (DSC) constituents have. Marks,*,, and Joseph T. Hupp*,,,§ Department of Chemistry, Argonne-Northwestern Solar Energy Research

234

Mobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox conditions  

E-Print Network [OSTI]

). Typically, it comprises residual iron oxides, quartz, sodium aluminosilicates, titanium dioxide, calciumMobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox elements, including arsenic. Aerobic and anaer- obic batch experiments were prepared using soils from near

Burke, Ian

235

DOI: 10.1002/ejic.201000555 Flexible and Redox-Active Coordination Polymer: Control of the Network  

E-Print Network [OSTI]

*[a] Keywords: Coordination polymers / Flexible networks / Macrocyles / Palladium / Nickel The coordination[3a] as well as in the fourfold interpenetrating dia- mondoid network[11] by the reaction of organicFULL PAPER DOI: 10.1002/ejic.201000555 Flexible and Redox-Active Coordination Polymer: Control

Paik Suh, Myunghyun

236

Use of Dissolved H2 Concentrations To Determine Distribution of Microbially Catalyzed Redox Reactions in Anoxic Groundwater  

E-Print Network [OSTI]

similartothe HZconcentrationsthat havepreviously been reported for aquatic sedimentswith the same TEAPs. In two aquifers contaminated with petroleum products, it was impossible with standard geochemical analyses actuallyexist (i.e.,there arenofreeelectrons); (2) the redox status of most natural waters cannot be accurately

Lovley, Derek

237

Redox Control For Hanford HLW Feeds VSL-12R2530-1, REV 0  

SciTech Connect (OSTI)

The principal objectives of this work were to investigate the effects of processing simulated Hanford HLW at the estimated maximum concentrations of nitrates and oxalates and to identify strategies to mitigate any processing issues resulting from high concentrations of nitrates and oxalates. This report provides results for a series of tests that were performed on the DM10 melter system with simulated C-106/AY-102 HLW. The tests employed simulated HLW feeds containing variable amounts of nitrates and waste organic compounds corresponding to maximum concentrations proj ected for Hanford HLW streams in order to determine their effects on glass production rate, processing characteristics, glass redox conditions, melt pool foaming, and the tendency to form secondary phases. Such melter tests provide information on key process factors such as feed processing behavior, dynamic effects during processing, processing rates, off-gas amounts and compositions, foaming control, etc., that cannot be reliably obtained from crucible melts.

Kruger, A. A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Kot, Wing K. [The Catholic University of America, Washington, DC (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States)

2012-12-13T23:59:59.000Z

238

Solar Thermochemical Fuels Production: Solar Fuels via Partial Redox Cycles with Heat Recovery  

SciTech Connect (OSTI)

HEATS Project: The University of Minnesota is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. The University of Minnesota is envisioning producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration. This new technology will allow for the effective use of vast domestic solar resources to produce precursors to synthetic fuels that could replace gasoline.

None

2011-12-19T23:59:59.000Z

239

Micelle formation and surface activity of functional redox relays: viologens substituted by a long alkyl chain  

SciTech Connect (OSTI)

Viologens are receiving increasing attention from 2 major domains. First, photo- and electroreproductive processes are being developed which exploit the pronounced chromophore effect associated with the one-electron reduction of the viologens: the 2+ state is practically colorless, while the 1+ state has an intense color. However, the most prominent impact in viologen-related research arises from their use as mediators, sometimes referred to as electron relays, in the photionduced generation of hydrogen from water. Photobiologists had discovered earlier that methyl viologen in chloroplast suspensions is suited to act as a Hill reagent which can be coupled with hydrogenase to yield H/sub 2/ under illumination. More recently, in vitro systems have been developed in which synthetic dyes replace the chloroplasts as redox sensitizers. These have been shown to be remarkably effective in H/sub 2/ production. The surfactant and micellar properties of a series of potent candidates, i.e., long-chain-substituted viologens are investigated.

Krieg, M.; Pileni, M.P.; Braun, A.M.; Gratzel, M.

1981-09-01T23:59:59.000Z

240

Electrocatalytic hydrogenation using precious metal microparticles in redox-active polymer films  

SciTech Connect (OSTI)

Glassy carbon felt electrodes have been modified by electrodeposition of poly(pyrrole-viologen) films (derived from N,N{prime}-dialkyl-4,4{prime}-bipyridinium salts), followed by electroprecipitation of precious metal (Pt, Pd, Rh, or Ru) microparticles. The resulting electrodes have been proved to be active for the electrocatalytic hydrogenation of conjugated enones (2-cyclohexen-1-one, cryptone, carvone, isophorone), styrene, and benzonitrile in aqueous media (pH 1). Despite low loadings of metal catalysts, high electric and products yields and a long term stability of these cathodes have been observed. The influence of the metal loading and the polymer structure on the catalytic efficiency as well as the selectivity obtained according to the metal catalyst used have been studied. Comparison with results previously reported for other catalytic cathodes like Pt/Pt, Pd/C, or Raney nickel electrodes proves the high efficiency of these metal microparticles within redox polymer film based electrodes.

Coche, L.; Ehui, B.; Limosin, D.; Moutet, J.C. (Univ. Joseph Fourier, Grenoble (France))

1990-11-09T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The complementary redox properties of viologens and pyromellitimides: A new class of organic conductors  

SciTech Connect (OSTI)

Organic charge-transfer (CT) salts have been of interest for some years, especially since the discovery of the metallic conductivity of the TTF-TCNQ salt. The authors have begun an investigation of the charge-transfer chemistry of viologens and pyromellitimides, based on their complementary redox properties, with the intention of proceeding from intermolecular examples to intramolecular CT salts and finally to examples in which the viologens and pyromellitimides are incorporated in a polymer. They report progress in the first two stages of this investigation, including isolation of a new, highly conductive intermolecular CT salt and electrochemical characterization of a covalently linked viologen/pyromellitimide. These studies point to an interesting new class of organic solid-state materials.

Buchwalter, S.L.; Iyengar, R.; Viehbeck, A.; O'Toole, T.R. (Thomas J. Watson Research Center, Yorktown Heights, NY (USA))

1991-01-02T23:59:59.000Z

242

Mechanism and Site Requirements for Ethanol Oxidation on Vanadium Oxide Domains Beata Kilos, Alexis T. Bell,* and Enrique Iglesia*  

E-Print Network [OSTI]

was then heated in dry air (Praxair, zero grade) flowing at 0.83 cm3 s-1 g-1 . The temperature was raised at 0

Bell, Alexis T.

243

Low volume flow meter  

DOE Patents [OSTI]

The low flow monitor provides a means for determining if a fluid flow meets a minimum threshold level of flow. The low flow monitor operates with a minimum of intrusion by the flow detection device into the flow. The electrical portion of the monitor is externally located with respect to the fluid stream which allows for repairs to the monitor without disrupting the flow. The electronics provide for the adjustment of the threshold level to meet the required conditions. The apparatus can be modified to provide an upper limit to the flow monitor by providing for a parallel electronic circuit which provides for a bracketing of the desired flow rate.

Meixler, Lewis D. (East Windsor, NJ)

1993-01-01T23:59:59.000Z

244

Synthesis of Nanostructured Carbides of Titanium and Vanadium from Metal Oxides and Ferroalloys Through High-energy Mechanical Milling and Heat Treatment  

SciTech Connect (OSTI)

Carbides of Ti and V have been synthesized directly from their oxides and ferroalloys through mechanical milling and heat treatment. The powder mixtures are milled in a planetary ball mill from 15-80 hours and subsequently heat treated at 1000-1300 deg. C for TiO{sub 2}-C mixtures, at 500-550 deg. C for V{sub 2}O{sub 5}-C mixtures and at 600-1000 deg. C for (Fe-V)-C mixtures. The milled and heat treated powders are characterized by SEM, EDAX, XRD, and BET techniques. Nanostructured TiC has been successfully synthesized under suitable processing conditions. However, carbides of vanadium is unidentified even though possibilities of V{sub 2}O{sub 5}-C reaction are indicated with an extent of induced amorphism in the powder mixture. Density, specific surface area and particle size of the milled and heat treated mixtures are correlated with heat treatment temperatures. Similar attempts are also made to synthesize vanadium carbides from industrial grade Fe-V.

Basu, P.; Jian, P. F.; Seong, K. Y.; Seng, G. S.; Hussain, Z.; Aziz, A. [School of Materials and Minerals Resources Engineering, Universiti Sains Malaysia (USM), Engineering Campus, 14300 Nibong Tebal, Pulau Pinang (Malaysia); Masrom, A. K. [Advanced Materials Research Centre (AMREC), SIRIM Bhd, Kulim Hi-Tech Park, Kulim 09000 (Malaysia)

2010-03-11T23:59:59.000Z

245

Propeller Flow Meter  

E-Print Network [OSTI]

Propeller flow meters are commonly used to measure water flow rate. They can also be used to estimate irrigation water use. This publication explains how to select, install, read and maintain propeller flow meters....

Enciso, Juan; Santistevan, Dean; Hla, Aung K.

2007-10-01T23:59:59.000Z

246

Dispersed flow film boiling  

E-Print Network [OSTI]

Dispersed flow consists of small liquid droplets entrained in a flowing vapor. This flow regime can occur in cryogenic equipment, in steam generators, and during nuclear reactor loss of coolant accidents. A theoretical ...

Yoder, Graydon L.

1980-01-01T23:59:59.000Z

247

Bacteria in shear flow  

E-Print Network [OSTI]

Bacteria are ubiquitous and play a critical role in many contexts. Their environment is nearly always dynamic due to the prevalence of fluid flow: creeping flow in soil, highly sheared flow in bodily conduits, and turbulent ...

Marcos, Ph.D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

248

Experimental and theoretical studies of reactions of neutral vanadium and tantalum oxide clusters with NO and NH3  

E-Print Network [OSTI]

molecules on the respective clusters. A gas mixture of NO:NH3 9:1 is also added into the fast flow reactor oxide clusters with NO, NH3, and an NO/NH3 mixture in a fast flow reactor are investigated by time, a complete elucidation of the reaction mechanism has not been achieved, and very few, if any, gas phase

Rocca, Jorge J.

249

Multiphase flow calculation software  

DOE Patents [OSTI]

Multiphase flow calculation software and computer-readable media carrying computer executable instructions for calculating liquid and gas phase mass flow rates of high void fraction multiphase flows. The multiphase flow calculation software employs various given, or experimentally determined, parameters in conjunction with a plurality of pressure differentials of a multiphase flow, preferably supplied by a differential pressure flowmeter or the like, to determine liquid and gas phase mass flow rates of the high void fraction multiphase flows. Embodiments of the multiphase flow calculation software are suitable for use in a variety of applications, including real-time management and control of an object system.

Fincke, James R. (Idaho Falls, ID)

2003-04-15T23:59:59.000Z

250

Flow Distances on Open Flow Networks  

E-Print Network [OSTI]

Open flow network is a weighted directed graph with a source and a sink, depicting flux distributions on networks in the steady state of an open flow system. Energetic food webs, economic input-output networks, and international trade networks, are open flow network models of energy flows between species, money or value flows between industrial sectors, and goods flows between countries, respectively. Flow distances (first-passage or total) between any given two nodes $i$ and $j$ are defined as the average number of transition steps of a random walker along the network from $i$ to $j$ under some conditions. They apparently deviate from the conventional random walk distance on a closed directed graph because they consider the openness of the flow network. Flow distances are explicitly expressed by underlying Markov matrix of a flow system in this paper. With this novel theoretical conception, we can visualize open flow networks, calculating centrality of each node, and clustering nodes into groups. We apply fl...

Guo, Liangzhu; Shi, Peiteng; Wang, Jun; Huang, Xiaohan; Zhang, Jiang

2015-01-01T23:59:59.000Z

251

GEOC R Lee Penn Sunday, March 25, 2012 12 -Biogeochemical transformation of Fe-and Mn-along a redox gradient: Implications for carbon sequestration  

E-Print Network [OSTI]

a redox gradient: Implications for carbon sequestration within the Christina River Basin Critical Zone States Organic carbon (C)-mineral complexation mechanism is crucial in C sequestration. It is a function

Sparks, Donald L.

252

Probing Ligand Effects on the Redox Energies of [4Fe-4S] Clusters Using Broken-Symmetry Density Functional Theory  

SciTech Connect (OSTI)

A central issue in understanding redox properties of iron-sulfur proteins is determining the factors that tune the reduction potentials of the Fe-S clusters. Recently, Solomon and coworkers have shown that the Fe-S bond covalency of protein analogs measured by %L, the percent ligand character of the Fe 3d orbitals, from ligand K-edge X-ray absorption spectroscopy (XAS) correlates with the electrochemical redox potentials. Also, Wang and coworkers have measured electron detachment energies for iron-sulfur clusters without environmental perturbations by gas-phase photoelectron spectroscopy (PES). Here the correlations of the ligand character with redox energy and %L character are examined in [Fe?S?L?]2? clusters with different ligands by broken symmetry density functional theory (BS-DFT) calculations using the B3LYP functional together with PES and XAS experimental results. These gas-phase studies assess ligand effects independently of environmental perturbations and thus provide essential information for computational studies of iron-sulfur proteins. The B3LYP oxidation energies agree well with PES data, and the %L character obtained from natural bond orbital analysis correlates with XAS values, although it systematically underestimates them because of basis set effects. The results show that stronger electron-donating terminal ligands increase %Lt, the percent ligand character from terminal ligands, but decrease %Sb, the percent ligand character from the bridging sulfurs. Because the oxidized orbital has significant Fe-Lt antibonding character, the oxidation energy correlates well with %Lt. However, because the reduced orbital has varying contributions of both Fe-Lt and Fe-Sb antibonding character, the reduction energy does not correlate with either %Lt or %Sb. Overall, BSDFT calculations together with XAS and PES experiments can unravel the complex underlying factors in the redox energy and chemical bonding of the [4Fe-4S] clusters in iron-sulfur proteins.

Niu, Shuqiang; Ichiye, Toshiko

2009-05-14T23:59:59.000Z

253

In Situ Redox Manipulation Proof-of-Principle Test at the Fort Lewis Logistics Center: Final Report  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory conducted a proof-of-principle test at the Fort Lewis Logistics Center to determine the feasibility of using the innovative remedial technology In Situ Redox Manipulation (ISRM) to treat groundwater contaminated with dissolved TCE. ISRM creates a permeable treatment zone in the subsurface to remediate redox-sensitive contaminants in groundwater. The permeable treatment zone is created by injecting a chemical reducing agent (sodium dithionite with pH buffers) into the aquifer through a well to chemically reduce the naturally occurring ferric iron in the sediments to ferrous iron. Once the reducing agent has been given sufficient time to react with aquifer sediments, residual chemicals and reaction products are withdrawn through the same well. Redox-sensitive contaminants such as TCE, moving in a dissolved-phase plume through the treatment zone, are destroyed. TCE is degraded via reductive dechlorination within the treatment zone to benign degradation products (acetylene, ehtylene). Analyses of sediment samples collected from post-test boreholes showed a high degree of iron reduction, which confirmed the effectiveness of the treatment zone.

Vermeul, Vincent R.; Williams, Mark D.; Evans, John C.; Szecsody, James E.; Bjornstad, Bruce N.; Liikala, Terry L.

2000-10-25T23:59:59.000Z

254

Portable wastewater flow meter  

DOE Patents [OSTI]

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under fill pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1999-02-02T23:59:59.000Z

255

Portable wastewater flow meter  

DOE Patents [OSTI]

A portable wastewater flow meter particularly adapted for temporary use at a single location in measuring the rate of liquid flow in a circular entrance conduit of a sewer manhole both under free flow and submerged, open channel conditions and under full pipe, surcharged conditions, comprising an apparatus having a cylindrical external surface and an inner surface that constricts the flow through the apparatus in such a manner that a relationship exists between (1) the difference between the static pressure head of liquid flowing through the entrance of the apparatus and the static pressure head of liquid flowing through the constriction, and (2) the rate of liquid flow through the apparatus.

Hunter, Robert M. (320 S. Wilson Ave., Bozeman, MT 59715)

1990-01-01T23:59:59.000Z

256

Effects of Protonation State on a Tyrosine?Histidine Bioinspired Redox Mediator  

SciTech Connect (OSTI)

The conversion of tyrosine to the corresponding tyrosyl radical in photosytem II (PSII) is an example of proton-coupled electron transfer. Although the tyrosine moiety (Tyr{sub Z}) is known to function as a redox mediator between the photo-oxidized primary donor (P680{sup •+}) and the Mn-containing oxygen-evolving complex, the protonation states involved in the course of the reaction remain an active area of investigation. Herein, we report on the optical, structural, and electrochemical properties of tyrosine?histidine constructs, which model the function of their naturally occurring counterparts in PSII. Electrochemical studies show that the phenoxyl/phenol couple of the model is chemically reversible and thermodynamically capable of water oxidation. Studies under acidic and basic conditions provide clear evidence that an ionizable proton controls the electrochemical potential of the tyrosine?histidine mimic and that an exogenous base or acid can be used to generate a low-potential or high-potential mediator, respectively. The phenoxyl/phenoxide couple associated with the low-potential mediator is thermodynamically incapable of water oxidation, whereas the relay associated with the high-potential mediator is thermodynamically incapable of reducing an attached photoexcited porphyrin. These studies provide insight regarding the mechanistic role of the tyrosine?histidine complex in water oxidation and strategies for making use of hydrogen bonds to affect the coupling between proton and electron transfer in artificial photosynthetic systems.

Moore, Gary F.; Hambourger, Michael; Kodis, Gerdenis; Michl, Weston; Gust, Devens; Moore, Thomas A.; Moore, Ana L.

2010-01-01T23:59:59.000Z

257

Redox-Dependent Solubility of Technetium in Low Activity Waste Glass  

SciTech Connect (OSTI)

The solubility of technetium was measured in a Hanford low activity waste glass simulant. The simulant glass was melted, quenched and pulverized to make a stock of powdered glass. A series of glass samples were prepared using the powdered glass and varying amounts of solid potassium pertechnetate. Samples were melted at 1000°C in sealed fused quartz ampoules. After cooling, the bulk glass and the salt phase above the glass (when present) were sampled for physical and chemical characterization. Technetium was found in the bulk glass up to 2000 ppm (using the glass as prepared) and 3000 ppm (using slightly reducing conditions). The chemical form of technetium obtained by x-ray absorption near edge spectroscopy can be mainly assigned to isolated Tc(IV), with a minority of Tc(VII) in some glasses and TcO2 in two glasses. The concentration and speciation of technetium depends on glass redox and amount of technetium added. Solid crystals of pertechnetate salts were found in the salt cake layer that formed at the top of some glasses during the melt.

Soderquist, Chuck Z.; Schweiger, Michael J.; Kim, Dong-Sang; Lukens, Wayne W.; Mccloy, John S.

2014-03-01T23:59:59.000Z

258

JUPITER-II Molten Salt Flibe Research: An Update On Tritium, Mobilization and Redox Chemistry Experiments  

SciTech Connect (OSTI)

The second Japan/US Program on Irradiation Tests for Fusion Research (JUPITER-II) began on April 1, 2001. Part of the collaborative research centers on studies of the molten salt 2LiF2–BeF2 (also known as Flibe) for fusion applications. Flibe has been proposed as a self-cooled breeder in both magnetic and inertial fusion power plant designs over the last 25 years. The key feasibility issues associated with the use of Flibe are the corrosion of structural material by the molten salt, tritium behavior and control in the molten salt blanket system, and safe handling practices and releases from Flibe during an accidental spill. These issues are all being addressed under the JUPITER-II program at the Idaho National Laboratory in the Safety and Tritium Applied Research (STAR) facility. In this paper, we review the program to date in the area of tritium/deuterium behavior, Flibe mobilization under accident conditions and testing of Be as a redox agent to control corrosion. Future activities planned through the end of the collaboration are also presented.

D.A. Petti; D. A. Petti; G. R. Smolik; Michael F. Simpson; John P. Sharpe; R. A. Anderl; S. Fukada; Y. Hatano; Masanori Hara; Y. Oya; T. Terai; D.-K. Sze; S. Tanaka

2005-05-01T23:59:59.000Z

259

Macroscopic Properties of Restacked, Redox-Liquid Exfoliated Graphite and Graphite Mimics Produced in Bulk Quantities  

SciTech Connect (OSTI)

The excellent properties exhibited by monolayer graphene have spurred the development of exfoliation techniques using bulk graphite to produce large quantities of pristine monolayer sheets. Development of simple chemistry to exfoliate and intercalate graphite and graphite mimics in large quantities is required for numerous applications. To determine the macroscopic behavior of restacked, exfoliated bulk materials, a systematic approach is presented using a simple, redox-liquid sonication process along to obtain large quantities of 2D and 3D hexagonally layered graphite, molybdenum disulfi de, and boron nitride, which are subsequently characterized to observe chemical and structural changes. For MoS 2 sonicated with the antioxidant sodium bisulfi te, results from Raman spectroscopy, X-ray diffraction, and electron microscopy indicate the presence of distorted phases from different polymorphs, and apparent nanotube structures in the bulk, restacked powder. Furthermore, using thermograviemtric analysis, the antioxidant enhances the resistance to oxidative degradation of MoS 2 , upon thermal treatment up to 900 C. The addition of the ionic antioxidant decreased dispersion stability in non-polar solvent, suggesting decreased compatibility with non-polar systems. Using simple chemical methods, the ability to generate tailored multidimensional layered materials with unique macroscopic properties is critical for numerous applications, including electrical devices, reinforced polymer composites, lithium ion capacitors, and chemical sensing.

Srivastava, Vikram K [ORNL; Quinlan, Ronald [ORNL; Agapov, Alexander L [ORNL; Dunlap, John R [ORNL; Nelson, Kimberly M [ORNL; Duranty, Edward R [ORNL; Sokolov, Alexei P [ORNL; Bhat, Gajanan [ORNL; Mays, Jimmy [ORNL

2014-01-01T23:59:59.000Z

260

Stable-isotope probe of nano-scale mineral-fluid redox interactions  

SciTech Connect (OSTI)

The project examined how stable isotopes fractionate at an aqueous/solid interface during electrochemical reduction reactions. Measurements in a wide variety of metal deposition systems including Fe, Zn, Li, Mo, and Cu, have led to observations of large isotope fractionations which strongly vary as a function of rate and temperature. For the Fe, Zn, and Li systems, our electrochemical deposition methods provide the largest single-pass fractionation factors that are observed for these systems. Based on these and other experiments and theory showing and predicting significant and rate-dependent fractionations of isotopes at reacting interfaces, we have developed a simple statistical mechanics framework that predicts the kinetic isotope effect accompanying phase transformations in condensed systems. In addition, we have begun to extend our studies of mineral-fluid redox interactions to high pressures and temperatures in the diamond anvil cell. We performed a series of experiments to determine solubilities of Cu and Ni at elevated pressure and temperature conditions relevant to ore-formation.

Kavner, Abby

2014-11-26T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Electron Transfer Reactivity Patterns at Chemically Modified Electrodes: Fundamentals and Application to the Optimization of Redox Recycling Amplification Systems  

SciTech Connect (OSTI)

Electroanalytical chemistry is often utilized in chemical analysis and Fundamental studies. Important advances have been made in these areas since the advent of chemically modified electrodes: the coating of an electrode with a chemical film in order to impart desirable, and ideally, predictable properties. These procedures enable the exploitation of unique reactivity patterns. This dissertation presents studies that investigate novel reaction mechanisms at self-assembled monolayers on gold. In particular, a unique electrochemical current amplification scheme is detailed that relies on a selective electrode to enable a reactivity pattern that results in regeneration of the analyte (redox recycling). This regenerating reaction can occur up to 250 times for each analyte molecule, leading to a notable enhancement in the observed current. The requirements of electrode selectivity and the resulting amplification and detection limit improvements are described with respect to the heterogeneous and homogeneous electron transfer rates that characterize the system. These studies revealed that the heterogeneous electrolysis of the analyte should ideally be electrochemically reversible, while that for the regenerating agent should be held to a low level. Moreover, the homogeneous reaction that recycles the analyte should occur at a rapid rate. The physical selectivity mechanism is also detailed with respect to the properties of the electrode and redox probes utilized. It is shown that partitioning of the analyte into/onto the adlayer leads to the extraordinary selectivity of the alkanethiolate monolayer modified electrode. Collectively, these studies enable a thorough understanding of the complex electrode mechanism required for successful redox recycling amplification systems, Finally, in a separate (but related) study, the effect of the akyl chain length on the heterogeneous electron transfer behavior of solution-based redox probes is reported, where an odd-even oscillation (with respect to the number of methylene units in the alkyl chain) was observed. Characterization of the adlayers by infrared reflection spectroscopy, ellipsometry, and wetting revealed odd-even effects in the orientation of the terminal methyl group and hydrophobic character of the adlayers. Using these structural characterizations as a basis, several possible mechanisms that can account for the odd-even effect in the heterogeneous electron transfer rates of solution-based redox couples are discussed.

Adam Johan Bergren

2006-05-01T23:59:59.000Z

262

Liquid-phase oxidation of anthracene by hydrogen peroxide in the presence of vanadium oxide bronzes Cu{sub x}V{sub 2}O{sub 5}  

SciTech Connect (OSTI)

Vanadium oxide bronzes of the general formula Cu{sub x}V{sub 2}O{sub 5}, where 0

Men`shikov, S.Yu.; Vurasko, A.V.; Petrov, L.A.; Volkov, V.L.; Novoselova, A.A. [Inst. of Chemistry, Sverdlovsk (Russian Federation)

1992-12-31T23:59:59.000Z

263

Zirconium vanadium chromium alloy  

DOE Patents [OSTI]

A ternary intermetallic compound having the formula Zr(V/sub 1-x/Cr/sub x/)/sub 2/ where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200/sup 0/C, at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

Mendelsohn, M.H.; Gruen, D.M.

1980-10-14T23:59:59.000Z

264

Redox-active tyrosine residue in the microcin J25 molecule  

SciTech Connect (OSTI)

Research highlights: {yields} Cyclic voltammetry measurements showed irreversible oxidation of MccJ25 and MccJ25 (Y9F). {yields} Infrared spectroscopy studies showed that only Tyr9 could be deprotonated upon chemical oxidation. {yields} Formation of a long-lived tyrosyl radical in the native MccJ25 oxidized by H{sub 2}O{sub 2} was demonstrated. {yields} Tyr9 but not Tyr20 can be easily oxidized and form a tyrosyl radical. -- Abstract: Microcin J25 (MccJ25) is a 21 amino acid lasso-peptide antibiotic produced by Escherichia coli and composed of an 8-residues ring and a terminal 'tail' passing through the ring. We have previously reported two cellular targets for this antibiotic, bacterial RNA polymerase and the membrane respiratory chain, and shown that Tyr9 is essential for the effect on the membrane respiratory chain which leads to superoxide overproduction. In the present paper we investigated the redox behavior of MccJ25 and the mutant MccJ25 (Y9F). Cyclic voltammetry measurements showed irreversible oxidation of both Tyr9 and Tyr20 in MccJ25, but infrared spectroscopy studies demonstrated that only Tyr9 could be deprotonated upon chemical oxidation in solution. Formation of a long-lived tyrosyl radical in the native MccJ25 oxidized by H{sub 2}O{sub 2} was demonstrated by Electron Paramagnetic Resonance Spectroscopy; this radical was not detected when the reaction was carried out with the MccJ25 (Y9F) mutant. These results show that the essential Tyr9, but not Tyr20, can be easily oxidized and form a tyrosyl radical.

Chalon, Miriam C. [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)] [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina); Wilke, Natalia [CIQUIBIC, Dpto. de Quimica Biologica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Pabellon Argentina, Ciudad Universitaria, X5000HUA, Cordoba (Argentina)] [CIQUIBIC, Dpto. de Quimica Biologica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Pabellon Argentina, Ciudad Universitaria, X5000HUA, Cordoba (Argentina); Pedersen, Jens; Rufini, Stefano [Department of Biology, University of Rome Tor Vergata 00133, Rome (Italy)] [Department of Biology, University of Rome Tor Vergata 00133, Rome (Italy); Morero, Roberto D.; Cortez, Leonardo; Chehin, Rosana N.; Farias, Ricardo N. [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)] [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina); Vincent, Paula A., E-mail: pvincent@fbqf.unt.edu.ar [Departamento de Bioquimica de la Nutricion, Instituto Superior de Investigaciones Biologicas (Consejo Nacional de Investigaciones Cientificas y Tecnicas-Universidad Nacional de Tucuman) and Instituto de Quimica Biologica 'Dr Bernabe Bloj', Chacabuco 461, 4000 San Miguel de Tucuman, Tucuman (Argentina)

2011-03-18T23:59:59.000Z

265

Ultrasonic flow metering system  

DOE Patents [OSTI]

A system for determining the density, flow velocity, and mass flow of a fluid comprising at least one sing-around circuit that determines the velocity of a signal in the fluid and that is correlatable to a database for the fluid. A system for determining flow velocity uses two of the inventive circuits with directional transmitters and receivers, one of which is set at an angle to the direction of flow that is different from the others.

Gomm, Tyler J. (Meridian, ID); Kraft, Nancy C. (Idaho Falls, ID); Mauseth, Jason A. (Pocatello, ID); Phelps, Larry D. (Pocatello, ID); Taylor, Steven C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

266

Elbow mass flow meter  

DOE Patents [OSTI]

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

1994-01-01T23:59:59.000Z

267

Structural, Spectroscopic, And Theoretical Elucidation of a Redox-Active Pincer-Type Ancillary Applied in Catalysis  

SciTech Connect (OSTI)

Pincer-type ligands are believed to be very robust scaffolds that can support multifarious functionalities as well as highly reactive metal motifs applied in organometallic chemistry, especially in the realm of catalysis. In this paper, we describe the redox and, therefore, noninnocent behavior of a PNP (PNP{sup -} = N[2-P(CHMe{sub 2}){sub 2}-4-methylphenyl]{sub 2}) pincer ancillary bound to nickel. A combination of structural, spectroscopic, and theoretical techniques suggests that this type of framework can house an electron hole when coordinated to Ni(II).

Adhikari, D.; Mossin, S.; Basuli, F.; Huffman, J.C.; Szilagyi, R.K.; Meyer, K.; Mindiola, D.J.

2009-05-11T23:59:59.000Z

268

Strong reduction of V{sup 4+} amount in vanadium oxide/hexadecylamine nanotubes by doping with Co{sup 2+} and Ni{sup 2+} ions: Electron paramagnetic resonance and magnetic studies  

SciTech Connect (OSTI)

In this work we present a complete characterization and magnetic study of vanadium oxide/hexadecylamine nanotubes (VO{sub x}/Hexa NT's) doped with Co{sup 2+} and Ni{sup 2+} ions. The morphology of the NT's has been characterized by transmission electron microscopy, while the metallic elements have been quantified by the instrumental neutron activation analysis technique. The static and dynamic magnetic properties were studied by collecting data of magnetization as a function of magnetic field and temperature and by electron paramagnetic resonance. At difference of the majority reports in the literature, we do not observe magnetic dimers in vanadium oxide nanotubes. Also, we observed that the incorporation of metallic ions (Co{sup 2+}, S = 3/2 and Ni{sup 2+}, S = 1) decreases notably the amount of V{sup 4+} ions in the system, from 14-16% (nondoped case) to 2%-4%, with respect to the total vanadium atoms (fact corroborated by XPS experiments) anyway preserving the tubular nanostructure. The method to decrease the amount of V{sup 4+} in the nanotubes improves considerably their potential technological applications as Li-ion batteries cathodes.

Saleta, M. E.; Troiani, H. E.; Ribeiro Guevara, S.; Ruano, G.; Sanchez, R. D. [Centro Atomico Bariloche, CNEA, (8400) S. C. de Bariloche (Argentina); Malta, M. [Depto. de Cs. Exatas e da Terra, Univ. do Estado da Bahia, Cabula Salvador CP 2555 (Brazil); Torresi, R. M. [Instituto de Quimica, Universidad de Sao Paulo, Sao Paulo CP 26077, 05513-970 (Brazil)

2011-05-01T23:59:59.000Z

269

Pore-Scale Characterization of Biogeochemical Controls on Iron and Uranium Speciation under Flow Conditions  

SciTech Connect (OSTI)

Etched silicon microfluidic pore network models (micromodels) with controlled chemical and redox gradients, mineralogy, and microbiology under continuous flow conditions are used for the incremental development of complex microenvironments that simulate subsurface conditions. We demonstrate the colonization of micromodel pore spaces by an anaerobic Fe(III)-reducing bacterial species (Geobacter sulfurreducens) and the enzymatic reduction of a bioavailable Fe(III) phase within this environment. Using both X-ray Microprobe and X-ray Absorption Spectroscopy, we investigate the combined effects of the precipitated Fe(III) phases and the microbial population on uranium biogeochemistry under flow conditions. Precipitated Fe(III) phases within the micromodel were most effectively reduced in the presence of an electron shuttle (AQDS), and Fe(II) ions adsorbed onto the precipitated mineral surface without inducing any structural change. In the absence of Fe(III), U(VI) was effectively reduced by the microbial population to insoluble U(IV), which was precipitated in discrete regions associated with biomass. In the presence of Fe(III) phases, however, both U(IV) and U(VI) could be detected associated with biomass, suggesting re-oxidation of U(IV) by localized Fe(III) phases. These results demonstrate the importance of the spatial localization of biomass and redox active metals, and illustrate the key effects of pore-scale processes on contaminant fate and reactive transport.

Pearce, Carolyn I.; Wilkins, Michael J.; Zhang, Changyong; Heald, Steve M.; Fredrickson, Jim K.; Zachara, John M.

2012-09-17T23:59:59.000Z

270

A New Approach to Computing Max Flows using Electrical Flows  

E-Print Network [OSTI]

A New Approach to Computing Max Flows using Electrical Flows Yin Tat Lee (MIT) Satish Rao (UC-Kelner-Madry-Spielman-Teng'11]: approximate flow in time Uses electrical flows. 7 #12;Electrical Flows 3 1 S t 8 #12;Electrical Flows Identify Graph with Resistor Network R(e)=1/w(e) 1/3 S t 1 9 #12;Electrical Flows Electrical flow

Rajamani, Sriram K.

271

Low flow fume hood  

DOE Patents [OSTI]

A fume hood is provided having an adequate level of safety while reducing the amount of air exhausted from the hood. A displacement flow fume hood works on the principal of a displacement flow which displaces the volume currently present in the hood using a push-pull system. The displacement flow includes a plurality of air supplies which provide fresh air, preferably having laminar flow, to the fume hood. The displacement flow fume hood also includes an air exhaust which pulls air from the work chamber in a minimally turbulent manner. As the displacement flow produces a substantially consistent and minimally turbulent flow in the hood, inconsistent flow patterns associated with contaminant escape from the hood are minimized. The displacement flow fume hood largely reduces the need to exhaust large amounts of air from the hood. It has been shown that exhaust air flow reductions of up to 70% are possible without a decrease in the hood's containment performance. The fume hood also includes a number of structural adaptations which facilitate consistent and minimally turbulent flow within a fume hood.

Bell, Geoffrey C. (Pleasant Hill, CA); Feustel, Helmut E. (Albany, CA); Dickerhoff, Darryl J. (Berkeley, CA)

2002-01-01T23:59:59.000Z

272

Coupled modeling of groundwater flow solute transport, chemical reactions and microbial processes in the 'SP' island  

SciTech Connect (OSTI)

The Redox Zone Experiment was carried out at the Aespoe HRL in order to study the redox behavior and the hydrochemistry of an isolated vertical fracture zone disturbed by the excavation of an access tunnel. Overall results and interpretation of the Redox Zone Project were reported by /Banwart et al, 1995/. Later, /Banwart et al, 1999/ presented a summary of the hydrochemistry of the Redox Zone Experiment. Coupled groundwater flow and reactive transport models of this experiment were carried out by /Molinero, 2000/ who proposed a revised conceptual model for the hydrogeology of the Redox Zone Experiment which could explain simultaneously measured drawdown and salinity data. The numerical model was found useful to understand the natural system. Several conclusions were drawn about the redox conditions of recharge waters, cation exchange capacity of the fracture zone and the role of mineral phases such as pyrite, calcite, hematite and goethite. This model could reproduce the measured trends of dissolved species, except for bicarbonate and sulfate which are affected by microbially-mediated processes. In order to explore the role of microbial processes, a coupled numerical model has been constructed which accounts for water flow, reactive transport and microbial processes. The results of this model is presented in this report. This model accounts for groundwater flow and reactive transport in a manner similar to that of /Molinero, 2000/ and extends the preliminary microbial model of /Zhang, 2001/ by accounting for microbially-driven organic matter fermentation and organic matter oxidation. This updated microbial model considers simultaneously the fermentation of particulate organic matter by yeast and the oxidation of dissolved organic matter, a product of fermentation. Dissolved organic matter is produced by yeast and serves also as a substrate for iron-reducing bacteria. Model results reproduce the observed increase in bicarbonate and sulfate concentration, thus adding additional evidence for the possibility of organic matter oxidation as the main source of bicarbonate. Model results indicate that pH and Eh are relatively stable. The dissolution-precipitation trends of hematite, pyrite and calcite also coincide with those indicated by the conceptual model. A thorough sensitivity analysis has been performed for the most relevant microbial parameters as well as for initial and boundary POC and DOC concentrations. The results of such analysis indicate that computed concentrations of bicarbonate, sulfate and DOC are sensitive to most of the microbial parameters, including specific growth rates, half-saturation constants, proportionality coefficients and yield coefficients. Model results, however, are less sensitive to the yield coefficient of DOC to iron-reducer bacteria. The sensitivity analysis indicates that changes in fermentation microbial parameters affect the growth of the iron-reducer, thus confirming the interconnection of both microbial processes. Computed concentrations of bicarbonate and sulfate are found to be sensitive to changes in the initial concentration of POC and the boundary concentration of DOC, but they lack sensitivity to the initial concentration of DOC and the boundary concentration of POC. The explanation for such result is related to the fact that POC has a low mobility due to its large molecular weight. DOC, however, can migrate downwards. Although a coupled hydro-bio-geochemical 1-D model can reproduce the observed ''unexpected'' increase of concentrations of bicarbonate and sulfate at a depth of 70 m, further modeling work is required in order to obtain a similar conclusion under the more realistic two dimensional conditions of the fracture zone.

Samper, Javier; Molinero, Jorg; Changbing, Yang; Zhang, Guoxiang

2003-12-01T23:59:59.000Z

273

Electrochemical DNA biosensor for detection of porcine oligonucleotides using ruthenium(II) complex as intercalator label redox  

SciTech Connect (OSTI)

A DNA biosensor detection of oligonucleotides via the interactions of porcine DNA with redox active complex based on the electrochemical transduction is described. A ruthenium(II) complex, [Ru(bpy){sub 2}(PIP)]{sup 2+}, (bpy = 2,2?bipyridine, PIP = 2-phenylimidazo[4,5-f[[1,10-phenanthroline]) as DNA label has been synthesized and characterized by 1H NMR and mass spectra. The study was carried out by covalent bonding immobilization of porcine aminated DNA probes sequences on screen printed electrode (SPE) modified with succinimide-acrylic microspheres and [Ru(bpy){sub 2}(PIP)]{sup 2+} was used as electrochemical redox intercalator label to detect DNA hybridization event. Electrochemical detection was performed by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) over the potential range where the ruthenium (II) complex was active. The results indicate that the interaction of [Ru(bpy){sub 2}(PIP)]{sup 2+} with hybridization complementary DNA has higher response compared to single-stranded and mismatch complementary DNA.

Halid, Nurul Izni Abdullah; Hasbullah, Siti Aishah; Heng, Lee Yook; Karim, Nurul Huda Abd [School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia); Ahmad, Haslina; Harun, Siti Norain [Chemistry Department, Faculty of Science, Universiti Putra Malaysia, 43400, Serdang, Selangor (Malaysia)

2014-09-03T23:59:59.000Z

274

Turbulent flow in graphene  

E-Print Network [OSTI]

We demonstrate the possibility of a turbulent flow of electrons in graphene in the hydrodynamic region, by calculating the corresponding turbulent probability density function. This is used to calculate the contribution of the turbulent flow to the conductivity within a quantum Boltzmann approach. The dependence of the conductivity on the system parameters arising from the turbulent flow is very different from that due to scattering.

Kumar S. Gupta; Siddhartha Sen

2010-06-05T23:59:59.000Z

275

Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites  

SciTech Connect (OSTI)

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan. • Characterizing the homogenized sample groups. • Performing parametric leaching testing on each group for compounds of interest. • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form of gibbsite, and its impact on filtration. The initial sample was diluted with a liquid simulant to simulate the receiving concentration of retrieved tank waste into the UFP2 vessel (< 10 wt% undissolved solids). Filtration testing was performed on the dilute waste sample and dewatered to a higher solids concentration. Filtration testing was then performed on the concentrated slurry. Afterwards, the slurry was caustic leached to remove aluminum present in the undissolved solid present in the waste. The leach was planned to simulate leaching conditions in the UFP2 vessel. During the leach, slurry supernate samples were collected to measure the dissolution rate of aluminum in the waste. After the slurry cooled down from the elevated leach temperature, the leach liquor was dewatered from the solids. The remaining slurry was rinsed and dewatered with caustic solutions to remove a majority of the dissolved aluminum from the leached slurry. The concentration of sodium hydroxide in the rinse solutions was high enough to maintain the solubility of the aluminum in the dewatered rinse solutions after dilution of the slurry supernate. Filtration tests were performed on the final slurry to compare to filtration performance before and after caustic leaching.

Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-03-02T23:59:59.000Z

276

Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 10, July 1, 1995--September 31, 1995  

SciTech Connect (OSTI)

This document is the tenth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities focused on testing of additional modified and promoted catalysts and characterization of these materials. Attempts at improving the sensitivity of our GC based analytical systems were also made with some success. Methanol oxidation studies were initiated. These results are reported. Specific accomplishments include: (1) Methane oxidation testing of a suite of catalysts promoted with most of the first row transition metals was completed. Several of these materials produced low, difficult to quantify yields of formaldehyde. (2) Characterization of these materials by XRD and FTIR was performed with the goal of correlating activity and selectivity with catalyst properties. (3) We began to characterize catalysts prepared via modified synthesis methods designed to enhance acidity using TGA measurements of acetonitrile chemisorption and methanol dehydration to dimethyl ether as a test reaction. (4) A catalyst prepared in the presence of naphthalene methanol as a structural disrupter was tested for activity in methane oxidation. It was found that this material produced low yields of formaldehyde which were difficult to quantify. (5) Preparation of catalysts with no Bronsted acid sites. This was accomplished by replacement of exchangeable protons with potassium, and (6) Methanol oxidation studies were initiated to provide an indication of catalyst activity for decomposition of this desired product and as a method of characterizing the catalyst surface.

McCormick, R.L.

1995-12-07T23:59:59.000Z

277

Status of flow-battery research in the United States  

SciTech Connect (OSTI)

Flow batteries are defined as electrochemical energy storage devices in which at least one of the active materials is stored external to the power converting cell-stack, and in which this soluble active material is circulated via the electrolyte, through the cell-stack during system charge or discharge. Although intensive development of some of these systems has been underway for some time, they were only classified as a distinct category in the United States recently. Of the projects on flow batteries which are still being conducted, the work on the zinc/chlorine system (EDA) has been in progress since 1968; programs on zinc/bromine (Exxon, Gould), on iron/chromium Redox (NASA-Lewis Research Center), and on the iron/ferric-ferrous chloride system (NRG/GEL) have all been underway about seven years; research on the zinc/ferro-ferricyanide battery (Lockheed) has been conducted since 1978. The present paper, which reviews the 1982 status of these battery programs, appears timely since, except for the Lockheed system, the developments have all reached the stage where multi-kilowatt-hour batteries are under test.

Clark, R.P.; Chamberlin, J.L.; Saxton, H.J.; Symons, P.C.

1982-01-01T23:59:59.000Z

278

Productivity & Energy Flow  

E-Print Network [OSTI]

1 Productivity & Energy Flow Ecosystem approach, focuses: on flow of energy, water, and nutrients (capture) of energy by autotrophs Gross (total) Net (total ­ costs) Secondary productivity- capture of energy by herbivores http://sciencebitz.com/?page_id=204 What Controls the Primary Productivity

Mitchell, Randall J.

279

Elbow mass flow meter  

DOE Patents [OSTI]

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16T23:59:59.000Z

280

Microelectromechanical flow control apparatus  

DOE Patents [OSTI]

A microelectromechanical (MEM) flow control apparatus is disclosed which includes a fluid channel formed on a substrate from a first layer of a nonconducting material (e.g. silicon nitride). A first electrode is provided on the first layer of the nonconducting material outside the flow channel; and a second electrode is located on a second layer of the nonconducting material above the first layer. A voltage applied between the first and second electrodes deforms the fluid channel to increase its cross-sectional size and thereby increase a flow of a fluid through the channel. In certain embodiments of the present invention, the fluid flow can be decreased or stopped by applying a voltage between the first electrode and the substrate. A peristaltic pumping of the fluid through the channel is also possible when the voltage is applied in turn between a plurality of first electrodes and the substrate. A MEM flow control assembly can also be formed by providing one or more MEM flow control devices on a common substrate together with a submicron filter. The MEM flow control assembly can optionally include a plurality of pressure sensors for monitoring fluid pressure and determining flow rates through the assembly.

Okandan, Murat (NE Albuquerque, NM)

2009-06-02T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Nox2 redox signaling maintains essential cell populations in the Bryan C Dickinson1, Joseph Peltier2, Daniel Stone2, David V Schaffer2, and Christopher J  

E-Print Network [OSTI]

Nox2 redox signaling maintains essential cell populations in the brain Bryan C Dickinson1, Joseph Peltier2, Daniel Stone2, David V Schaffer2, and Christopher J Chang1,3 1Department of Chemistry indicator for hydrogen peroxide (H2O2), we show that adult hippocampal stem/progenitor cells (AHPs) generate

Schaffer, David V.

282

Structural basis of inter-domain electron transfer in Ncb5or, a redox enzyme implicated in diabetes and lipid metabolism  

E-Print Network [OSTI]

NADH cytochrome b5 oxidoreductase (Ncb5or) is a multi-domain redox enzyme found in all animal tissues and associated with the endoplasmic reticulum (ER). Ncb5or contains (from N-terminus to C terminus) a novel N-terminal region, the b5 domain (Ncb5...

Deng, Bin

2011-12-31T23:59:59.000Z

283

Elliptic flow phenomenon at ATLAS  

E-Print Network [OSTI]

We summarize measurements of elliptic flow and higher order flow harmonics performed by the ATLAS experiment at the LHC. Results on event-averaged flow measurements and event-plane correlations in Pb+Pb collisions are discussed along with the event-by-event flow measurements. Further, we summarize results on flow in p+Pb collisions.

Martin Spousta

2014-06-20T23:59:59.000Z

284

Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same  

DOE Patents [OSTI]

A lithium/organosulfur redox cell is disclosed which comprises a solid lium anode, a liquid organosulfur cathode, and a barrier layer formed adjacent a surface of the solid lithium anode facing the liquid organosulfur cathode consisting of a reaction product of the lithium anode with the organosulfur cathode. The organosulfur cathode comprises a material having the formula (R(S).sub.y).sub.N where y=1 to 6, n=2 to 20 and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the linear chain may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

De Jonghe, Lutgard C. (Berkeley, CA); Visco, Steven J. (Berkeley, CA); Liu, Meilin (Albany, CA); Mailhe, Catherine C. (Vevey, CH)

1990-01-01T23:59:59.000Z

285

FINAL REPORT INTEGRATED DM1200 MELTER TESTING OF REDOX EFFECTS USING HLW AZ-101 AND C-106/AY-102 SIMULANTS VSL-04R4800-1 REV 0 5/6/  

SciTech Connect (OSTI)

This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 and C-106/AY-102 HLW simulants. The tests reported herein are a subset of three tests from a larger series of tests described in the Test Plan for the work; results from the remaining tests will be reported separately. Three nine day tests, one with AZ-101 and two with C-106/AY-102 feeds were conducted with variable amounts of added sugar to address the effects of redox. The test with AZ-101 included ruthenium spikes to also address the effects of redox on ruthenium volatility. One of tests addressed the effects of increased flow-sheet nitrate levels using C-106/AY-102 feeds. With high nitrate/nitrite feeds (such as WTP LAW feeds), reductants are required to prevent melt foaming and deleterious effects on glass production rates. Sugar is the baseline WTP reductant for this purpose. WTP HLW feeds typically have relatively low nitrate/nitrite content in comparison to the organic carbon content and, therefore, have typically not required sugar additions. However, HLW feed variability, particularly with respect to nitrate levels, may necessitate the use of sugar in some instances. The tests reported here investigate the effects of variable sugar additions to the melter feed as well as elevated nitrate levels in the waste. Variables held constant to the extent possible included melt temperature, bubbling rate, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW feeds with variable amounts of added sugar and increased nitrate levels; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table.

KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; LUTZE W; BIZOT PM; CALLOW RA; BRANDYS M; KOT WK; PEGG IL

2011-12-29T23:59:59.000Z

286

Redox cycle stability of mixed oxides used for hydrogen generation in the cyclic water gas shift process  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Fe{sub 2}O{sub 3} modified with CaO, SiO{sub 2} and Al{sub 2}O{sub 3} was studied in cyclic water gas shift reactor. • For the first time stability of such oxides were tested for 100 redox cycles. • Optimally added oxides significantly improved the activity and the stability of Fe{sub 2}O{sub 3}. • Increased stability was attributed to the impediment of neck formation. - Abstract: Repeated cycles of the reduction of Fe{sub 3}O{sub 4} with reductive gas, e.g. hydrogen and subsequent oxidation of the reduced iron material with water vapor can be harnessed as a process for the production of pure hydrogen. The redox behavior of iron oxide modified with various amounts of SiO{sub 2}, CaO and Al{sub 2}O{sub 3} was investigated in the present study. The total amount of the additional metal oxides was always below 15 wt%. The samples were prepared by co-precipitation using urea hydrolysis method. The influence of various metal oxides on the hydrogen production capacity and the material stability was studied in detail in terms of temperature-programmed reduction (TPR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET analysis. Furthermore, the activity and the stability of the samples were tested in repeated reduction with diluted H{sub 2} and re-oxidation cycles with H{sub 2}O. The results indicate that combination of several oxides as promoter increases the stability of the iron oxide material by mitigating the sintering process. The positive influence of the oxides in stabilizing the iron oxide material is attributed to the impediment of neck formation responsible for sintering.

Datta, Pradyot, E-mail: pradyot.datta@gmail.com

2013-10-15T23:59:59.000Z

287

Controlled Assembly of Heterobinuclear Sites on Mesoporous Silica: Visible Light Charge-Transfer Units with Selectable Redox Properties  

SciTech Connect (OSTI)

Mild synthetic methods are demonstrated for the selective assembly of oxo-bridged heterobinuclear units of the type TiOCrIII, TiOCoII, and TiOCeIII on mesoporous silica support MCM-41. One method takes advantage of the higher acidity and, hence, higher reactivity of titanol compared to silanol OH groups towards CeIII or CoII precursor. The procedure avoids the customary use of strong base. The controlled assembly of the TiOCr system exploits the selective redox reactivity of one metal towards another (TiIII precursor reacting with anchored CrVI centers). The observed selectivity for linking a metal precursor to an already anchored partner versus formation of isolated centers ranges from a factor of six (TiOCe) to complete (TiOCr, TiOCo). Evidence for oxo bridges and determination of the coordination environment of each metal centers is based on K-edge EXAFS (TiOCr), L-edge absorption spectroscopy (Ce), and XANES measurements (Co, Cr). EPR, optical, FT-Raman and FT-IR spectroscopy furnish additional details on oxidation state and coordination environment of donor and acceptor metal centers. In the case of TiOCr, the integrity of the anchored group upon calcination (350 oC) and cycling of the Cr oxidation state is demonstrated. The binuclear units possess metal-to-metal charge-transfer transitions that absorb deep in the visible region. The flexible synthetic method for assembling the units opens up the use of visible light charge transfer pumps featuring donor or acceptor metals with selectable redox potential.

Frei, Heinz; Han, Hongxian; Frei, Heinz

2008-06-04T23:59:59.000Z

288

Shroud leakage flow discouragers  

DOE Patents [OSTI]

A turbine assembly includes a plurality of rotor blades comprising a root portion, an airfoil having a pressure sidewall and a suction sidewall, and a top portion having a cap. An outer shroud is concentrically disposed about said rotor blades, said shroud in combination with said tip portions defining a clearance gap. At least one circumferential shroud leakage discourager is disposed within the shroud. The leakage discourager(s) increase the flow resistance and thus reduce the flow of hot gas flow leakage for a given pressure differential across the clearance gap to improve overall turbine efficiency.

Bailey, Jeremy Clyde (Middle Grove, NY); Bunker, Ronald Scott (Niskayuna, NY)

2002-01-01T23:59:59.000Z

289

Bypass Flow Study  

SciTech Connect (OSTI)

The purpose of the fluid dynamics experiments in the MIR (Matched Index of-Refraction) flow system at Idaho National Laboratory (INL) is to develop benchmark databases for the assessment of Computational Fluid Dynamics (CFD) solutions of the momentum equations, scalar mixing, and turbulence models for the flow ratios between coolant channels and bypass gaps in the interstitial regions of typical prismatic standard fuel element (SFE) or upper reflector block geometries of typical Modular High-temperature Gas-cooled Reactors (MHTGR) in the limiting case of negligible buoyancy and constant fluid properties. The experiments use Particle Image Velocimetry (PIV) to measure the velocity fields that will populate the bypass flow study database.

Richard Schultz

2011-09-01T23:59:59.000Z

290

Magnetically stimulated fluid flow patterns  

ScienceCinema (OSTI)

Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

Martin, Jim; Solis, Kyle

2014-08-06T23:59:59.000Z

291

Optical flow switching  

E-Print Network [OSTI]

Present-day networks are being challenged by dramatic increases in bandwidth demand of emerging applications. We will explore a new transport, ldquooptical flow switchingrdquo, that will enable significant growth and ...

Chan, Vincent W. S.

292

Olefin Autoxidation in Flow  

E-Print Network [OSTI]

Handling hazardous multiphase reactions in flow brings not only safety advantages but also significantly improved performance, due to better mass transfer characteristics. In this paper, we present a continuous microreactor ...

Neuenschwander, Ulrich

293

Parallel flow diffusion battery  

DOE Patents [OSTI]

A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

Yeh, H.C.; Cheng, Y.S.

1984-01-01T23:59:59.000Z

294

Section 13: Flow control 1 Section 13: Flow control  

E-Print Network [OSTI]

Geometries for Energyefficient Flow Around Bodies Abstract 14:30 ­ 14:50: Elfriede Friedmann (Universität

Kohlenbach, Ulrich

295

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry  

E-Print Network [OSTI]

Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I.Skillicorn 1 Azimuthal asymmetry using energy flow method Azimuthal angle distribution at Q2 >100 GeV2 Energy flow method.Ukleja on behalf of the ZEUS Collaboration #12; Energy Flow Energy Flow Energy Flow A.Ukleja, T.Tymieniecka, I

296

Evaluation of flow hood measurements for residential register flows  

SciTech Connect (OSTI)

Flow measurement at residential registers using flow hoods is becoming more common. These measurements are used to determine if the HVAC system is providing adequate comfort, appropriate flow over heat exchangers and in estimates of system energy losses. These HVAC system performance metrics are determined by using register measurements to find out if individual rooms are getting the correct airflow, and in estimates of total air handler flow and duct air leakage. The work discussed in this paper shows that commercially available flow hoods are poor at measuring flows in residential systems. There is also evidence in this and other studies that flow hoods can have significant errors even when used on the non-residential systems they were originally developed for. The measurement uncertainties arise from poor calibrations and the sensitivity of exiting flow hoods to non-uniformity of flows entering the device. The errors are usually large--on the order of 20% of measured flow, which is unacceptably high for most applications. Active flow hoods that have flow measurement devices that are insensitive to the entering airflow pattern were found to be clearly superior to commercially available flow hoods. In addition, it is clear that current calibration procedures for flow hoods may not take into account any field application problems and a new flow hood measurement standard should be developed to address this issue.

Walker, I.S.; Wray, C.P.; Dickerhoff, D.J.; Sherman, M.H.

2001-09-01T23:59:59.000Z

297

Piezoelectric axial flow microvalve  

SciTech Connect (OSTI)

This invention is directed to a fuel cell operable with a quantity of fuel and a quantity of an oxidizer to produce electrical power, the fuel cell including a fuel cell body including a labyrinth system structured to permit the fuel and the oxidizer to flow therethrough; at least a first catalyst in fluid communication with the labyrinth; and at least a first microvalve operably disposed within at least a portion of the labyrinth. The microvalve utilizes a deflectable member operable upon the application of a voltage from a voltage source. The microvalve includes an elongated flow channel formed therein and extending substantially longitudinally between the first and second ends to permit substantially longitudinal flow of the fluid therethrough and between the first and second ends; and the deflectable member disposed on the valve body, the deflectable member including at least a first piezoelectric portion that is piezoelectrically operable to deflect the deflectable member between an open position and a closed position upon the application of a voltage, the deflectable member in the closed position being operable to resist the flow of the fluid through the flow channel.

Gemmen, Randall; Thornton, Jimmy; Vipperman, Jeffrey S.; Clark, William W.

2007-01-09T23:59:59.000Z

298

copyrisht@ree2bythen-""i"",,R3il:'J[$H#"",i*tTy"t"*r1"'J?rt;""mission orthecopyrightowner. Toward Orthogonal Self-Assembly of Redox Active  

E-Print Network [OSTI]

Orthogonal Self-Assembly of Redox Active Molecules on Pt and Au: Selective Reaction of Disulfide with Au.; Uphaus,R. A. Microchem.J.1990,42, 44, and referencestherein on viologen monolayer electrochemistry. (5

Prentiss, Mara

299

Electrocapturing flow cell  

DOE Patents [OSTI]

A flow cell for electrophoretically-assisted capturing analytes from a flow. The flow cell includes a specimen chamber, a first membrane, a second membrane, a first electrode chamber, and a second electrode chamber. The specimen chamber may have a sample inlet and a sample outlet. A first portion of the first membrane may be coupled to a first portion of the specimen chamber. A first portion of the second membrane may be coupled to a second portion of the specimen chamber. The first electrode chamber may be configured to accept a charge. A portion of the first electrode chamber may be coupled to a second portion of the first membrane. A second electrode chamber may be configured to accept an opposite charge. A portion of the second electrode chamber may be coupled to a second portion of the second membrane.

Morozov, Victor (Manassas, VA)

2011-04-05T23:59:59.000Z

300

Workshop on hypersonic flow  

SciTech Connect (OSTI)

An overview is given of research activity on the application of computational fluid dynamics (CDF) for hypersonic propulsion systems. After the initial consideration of the highly integrated nature of air-breathing hypersonic engines and airframe, attention is directed toward computations carried out for the components of the engine. A generic inlet configuration is considered in order to demonstrate the highly three dimensional viscous flow behavior occurring within rectangular inlets. Reacting flow computations for simple jet injection as well as for more complex combustion chambers are then discussed in order to show the capability of viscous finite rate chemical reaction computer simulations. Finally, the nozzle flow fields are demonstrated, showing the existence of complex shear layers and shock structure in the exhaust plume. The general issues associated with code validation as well as the specific issue associated with the use of CFD for design are discussed. A prognosis for the success of CFD in the design of future propulsion systems is offered.

Povinelli, L.A.

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

[Unsegmented continuous-flow sample processing and electrochemical detection of gaseous species  

SciTech Connect (OSTI)

Goals were a continuous-flow, unsegmented, all-gas carrier and/or a segmented liquid/gas interface system for sample introduction and transport to detection/determination point; a regenerable electrode probe base on redox reactions of Fe(II) and Fe(III) complexes with 1, 10-phenanthroline and related ligands; and amperometric/coulometric current measurements providing analyte signals. Gases to be detected included NO[sub x] and SO[sub 2]. This report is divided into 3 parts: preparation of new ligands of 1,10-phenanthroline family; glassy carbon surfaces coated with polymeric films prepared from monomeric units of tris[5-amino-1,10-phenanthroline]iron(II); and sulfite oxidase/hexacyanoferrate modified C paste electrode.

Mottola, H.A.

1991-01-01T23:59:59.000Z

302

Multiphase cooling flows  

E-Print Network [OSTI]

I discuss the multiphase nature of the intracluster medium whose neglect can lead to overestimates of the baryon fraction of clusters by up to a factor of two. The multiphase form of the cooling flow equations are derived and reduced to a simple form for a wide class of self-similar density distributions. It is shown that steady-state cooling flows are \\emph{not} consistent with all possible emissivity profiles which can therefore be used as a test of the theory. In combination, they provide strong constraints on the mass distribution within the cooling radius.

Peter A. Thomas

1996-08-20T23:59:59.000Z

303

Synthesis and charge-transport properties of polymers derived from the oxidation of 1-hydro-1'-(6-(pyrrol-1-yl)hexyl)-4,4'-bipyridium Bis(hexafluorophosphate) and demonstration of pH-sensitive microelectrochemical transistor derived from the redox properties of a conventional redox center  

SciTech Connect (OSTI)

This article describes the synthesis and electrochemical properties of redox polymers, having a polypyrrole backbone and viologen subunits, derived from oxidative electropolymerization of 1-methyl-1'-(6-(pyrrol-1-yl)hexyl)-4,4'-bipyridinium (P-V-Me/sup 2 +/) and 1-hydro-1'-(6-(pyrrol-1-yl)hexyl)-4,4'-bipyridinium (P-V-H/sup 2 +/). Closely spaced (approx. 1.5 ..mu..M) Au microelectrode arrays (approx. 2.5 ..mu..m wide /times/ 50 ..mu..m long /times/ 0.1 ..mu..m high) modified with the polymers can be used to study aspects of the charge-transport behavior of the viologen redox system. Poly(P-V-Me/sup 2 +/) have been used to investigate the characteristics of microelectrochemical transistors based on a viologen redox center and a similar redox center, protonated, monoquaternized bipyridinium, which is pH dependent. The interesting properties from poly(P-V-Me/sup 2 +/) and poly(P-V-H/sup 2 +/) stem from behavior of the pendant viologen redox centers. The device based on poly(P-V-Me/sup 2 +/) has a narrow region (approx. 200 mV) of gate voltage, V/sub G/, where the source-drain current, I/sub D/, is nonzero and has a sharp, pH-independent peak in the I/sub D/-V/sub G/ plot at approx. 0.53 V versus SCE associated with the reversible, one-electron reduction of viologen. This result is consistent with electron self-exchange between redox centers being the mechanism for charge transport. The device based on poly(P-V-H/sup 2 +/) shows a pH-dependent I/sub D/ at fixed V/sub G/, as expected from the electrochemical behavior from reversible protonation of the terminal N of the bipyridinium group of poly(P-V-H/sup 2 +/). The microelectrochemical transistor based on poly(P-V-H/sup 2 +/) illustrates the design of chemically sensitive, molecule-based devices using conventional redox materials.

Shu, C.F.; Wrighton, M.S.

1988-09-08T23:59:59.000Z

304

The role of nanopores on U(VI) sorption and redox behavior in U(VI)-contaminated subsurface sediments  

SciTech Connect (OSTI)

Most reactive surfaces in clay-dominated sediments are present within nanopores (pores of nm dimension). The behavior of geological fluids and minerals in nanopores is significantly different from those in normal non-nanoporous environments. The effect of nanopore surfaces on U(VI) sorption/desorption and reduction is likely to be significant in clay-rich subsurface environments. Our research results from both model nanopore system and natural sediments from both model system (synthetic nanopore alumina) and sediments from the ORNL Field Research Center prove that U(VI) sorption on nanopore surfaces can be greatly enhanced by nanopore confinement environments. The results from the project provide advanced mechanistic, quantitative information on the physiochemical controls on uranium sorption and redox behavior in subsurface sediments. The influence of nanopore surfaces on coupled uranium sorption/desorption and reduction processes is significant in virtually all subsurface environments, because most reactive surfaces are in fact nanopore surfaces. The results will enhance transfer of our laboratory-based research to a major field research initiative where reductive uranium immobilization is being investigated. Our results will also provide the basic science for developing in-situ colloidal barrier of nanoporous alumina in support of environmental remediation and long term stewardship of DOE sites.

Xu, Huifang; Roden, Eric E.; Kemner, Kenneth M.; Jung, Hun-Bok; Konishi, Hiromi; Boyanov, Maxim; Sun, Yubing; Mishra, Bhoopesh

2013-10-16T23:59:59.000Z

305

Electrostatic binding of bicarbonate and formate in viologen-based redox polymers: importance in catalytic reduction of bicarbonate to formate  

SciTech Connect (OSTI)

The relative importance of electrostatic binding of CO3H and HCO2 in a redox polymer derived from an N,N'-dialkyl-4,4'-bipyridinium monomer has been investigated by Fourier transform infrared (FTIR) spectroscopy. At 298 K and a total concentration of C-containing species of 0.1 M the two species are equally firmly bound in a polymer immobilized on a single-crystal Si electrode surface. When the concentration of C-containing species is 1.0 M, the CO3H ion is more firmly bound by about a factor of 2.5, and at a total concentration of 3.0 M the CO3H ion is about 7 times more firmly bound than the HCO2 ion. The HCO2 and Cl anions are equally firmly bound at 1.0 M total anion concentration. On the basis of the lack of change in the cyclic voltammetry response of a derivatized electrode in 1.0 M Na(CO3H) or Na(HCO2) compared to 1.0 M NaCl, the exchange rate of the C-containing anions does not appear to be a factor that would limit the rate of reduction of the CO3H ion at an electrode modified with the polymer and impregnated with Pd(0).

Andre, J.F.; Wrighton, M.S.

1985-12-04T23:59:59.000Z

306

Photoinduced and redox-induced transmembrane processes with vesicle-stabilized colloidal cadmium sulfide and multicharged viologen derivatives  

SciTech Connect (OSTI)

Colloidal cadmium sulfide (CdS) and methylviologen (MV{sup 2+}) or new viologen derivatives carrying more positive charges were placed at specific sites of dihexadecyl phosphate (DHP) vesicles. Benzyl alcohol was used as a sacrificial electron donor to promote reduction of the viologens by photoexcited CdS colloid majority carriers. Transmission electron microscopy, {sup 13}C nuclear magnetic resonance, and differential scanning calorimetry were used for physical characterization. Photochemical events were followed by in situ optical and electrochemical monitoring. Redox-induced transmembrane diffusion, which had been found with MV{sup 2+}, could be reduced by a factor 18 by using a triply charged viologen derivative and by a further factor of 30 in a configuration involving transmembrane electron transfer. In that case the quantum yield was ca. 0.05 at 410 nm, while virtually no reduced viologen leaking could be observed during at least 10 min. Physical evidence was found for a partial penetration of the CdS colloids into the DHP membrane.

Tricot, Y.M.; Porat, Z.; Manassen, J. (Weizmann Inst. of Science, Rehovot (Israel))

1991-04-18T23:59:59.000Z

307

Photoinduced redox reactions in aqueous micelles. Quenching, back-reaction, and competing processes for tetraanionic porphyrins with alkylviologens  

SciTech Connect (OSTI)

Photoinduced redox reactions employing the anionic porphyrins meso-tetrakis(p-sulfonatophenyl)porphyrin (1) and its palladium(II) complex (2) as excited substrates and various alkylviologens as quenchers have been studied in homogeneous aqueous solution and in the presence of the charged detergents sodium dodecyl sulfate (SDS) and cetyltrimethylammonium chloride (CTAC) above the critical micelle concentration (cmc). In homogeneous solution strong ground-state association between the porphyrins and the viologens occurs; even dynamic quenching processes result in no separation of electron transfer product ions. Addition of either SDS or CTAC reduces the quenching rates but allows the detection of product ions surviving up to ca. 100 ms in some cases. The back-reactions are sensitive to a variety of factors including added electrolyte, hydrophobicity of the viologen and its one-electron reduction product, and the charge on the surfactant. The long-lived products can be selectively intercepted by a variety of reagents. In the case of quenching of the palladium porphyrin (2) by methylviologen, the oxidized porphyrin can be reduced by iodide while the reduced viologen can be oxidized via either a colloidal catalyst or reaction with molecular oxygen. These reactions illustrate the possibility for obtaining net chemical conversion in a process whereby both the light-absorbing substrate and the quencher are recycled.

Schmehl, R.H.; Whitten, D.G.

1981-11-12T23:59:59.000Z

308

Status of cross-section data for gas production from vanadium and {sup 26}AL from silicon carbide in a D-T fusion reactor.  

SciTech Connect (OSTI)

Current designs of fusion-reactor systems seek to use radiation-resistant, low-activation materials that support long service lifetimes and minimize radioactive-waste problems after decommissioning. Reliable assessment of fusion materials performance requires accurate neutron-reaction cross sections and radioactive-decay constants. The problem areas usually involve cross sections since decay parameters tend to be better known. The present study was motivated by two specific questions: (i) Why are the {sup 51}V(n,np){sup 50}Ti cross section values in the ENDF/B-VI library so large (a gas production issue)? (ii) How well known are the cross sections associated with producing 7.4 x 10{sup 5} y {sup 26}Al in silicon carbide by the process {sup 28}Si(n,np+d){sup 27} Al(n,2n){sup 26}Al (a long-lived radioactivity issue)? The energy range 14-15 MeV of the D-T fusion neutrons is emphasized. Cross-section error bars are needed so that uncertainties in the gas and radioactivity generated over the lifetime of a reactor can be estimated. We address this issue by comparing values obtained from prominent evaluated cross-section libraries. Small differences between independent evaluations indicate that a physical quantity is well known while the opposite signals a problem. Hydrogen from {sup 51}V(n,p){sup 51}Ti and helium from {sup 51}V(n,{alpha}){sup 48}Sc are also important sources of gas in vanadium, so they too were examined. We conclude that {sup 51}V(n,p){sup 51}Ti is adequately known but {sup 51}V(n,np+d){sup 50}Ti is not. The status for helium generation data is quite good. Due to recent experimental work, {sup 27}Al(n,2n){sup 26}Al seems to be fairly well known. However, the situation for {sup 28}Si(n,np+d){sup 27}Al remains unsatisfactory.

Gomes, I. C.

1998-08-11T23:59:59.000Z

309

ENERGY FLOWS CLIMATE CHANGE  

E-Print Network [OSTI]

ENERGY FLOWS FORCINGS CLIMATE CHANGE A REALLY TOUGH PROBLEM Stephen E. Schwartz, BNL, 7-20-11 www average temperature 15°C or 59°F #12;ATMOSPHERIC RADIATION Power per area Energy per time per area Unit" temperature to radiative flux. #12;GLOBAL ENERGY BALANCE Global and annual average energy fluxes in watts per

Schwartz, Stephen E.

310

Flow cytometry apparatus  

DOE Patents [OSTI]

An obstruction across the flow chamber creates a one dimensional convergence of a sheath fluid. A passageway in the construction directs flat cells near to the area of one dimensional convergence in the sheath fluid to provide proper orientation of flat cells at fast rates.

Pinkel, Daniel (Walnut Creek, CA)

1991-01-01T23:59:59.000Z

311

AGN and Cooling Flows  

E-Print Network [OSTI]

For two decades the steady-state cooling-flow model has dominated the literature of cluster and elliptical-galaxy X-ray sources. For ten years this model has been in severe difficulty from a theoretical point of view, and it is now coming under increasing pressure observationally. For two decades the steady-state cooling-flow model has dominated the literature of cluster and elliptical-galaxy X-ray sources. For ten years this model has been in severe difficulty from a theoretical point of view, and it is now coming under increasing pressure observationally. A small number of enthusiasts have argued for a radically different interpretation of the data, but had little impact on prevailing opinion because the unsteady heating picture that they advocate is extremely hard to work out in detail. Here I explain why it is difficult to extract robust observational predictions from the heating picture. Major problems include the variability of the sources, the different ways in which a bi-polar flow can impact on X-ray emission, the weakness of synchrotron emission from sub-relativistic flows, and the sensitivity of synchrotron emission to a magnetic field that is probably highly localized.

James Binney

2001-03-23T23:59:59.000Z

312

Analysis of flow patterns and flow mechanisms in soils  

E-Print Network [OSTI]

Analysis of flow patterns and flow mechanisms in soils Dissertation Co-directed by the University of paths, varying flow mechanism or changing soil physical properties (stratification). Thus, in stratified-28Jan2010 #12;This doctoral thesis was prepared at the Department of Soil Physics, University

Paris-Sud XI, Université de

313

Radial flow pulse jet mixer  

DOE Patents [OSTI]

The disclosure provides a pulse jet mixing vessel for mixing a plurality of solid particles. The pulse jet mixing vessel is comprised of a sludge basin, a flow surface surrounding the sludge basin, and a downcoming flow annulus between the flow surface and an inner shroud. The pulse jet mixing vessel is additionally comprised of an upper vessel pressurization volume in fluid communication with the downcoming flow annulus, and an inner shroud surge volume separated from the downcoming flow annulus by the inner shroud. When the solid particles are resting on the sludge basin and a fluid such as water is atop the particles and extending into the downcoming flow annulus and the inner shroud surge volume, mixing occurs by pressurization of the upper vessel pressurization volume, generating an inward radial flow over the flow surface and an upwash jet at the center of the sludge basin.

VanOsdol, John G.

2013-06-25T23:59:59.000Z

314

The Big Flow  

E-Print Network [OSTI]

The late infall of cold dark matter onto an isolated galaxy, such as our own, produces streams and caustics in its halo. The outer caustics are topological spheres whereas the inner caustics are rings. The self-similar model of galactic halo formation predicts that the caustic ring radii $a_n$ follow the approximate law $a_n \\sim 1/n$. In a study of 32 extended and well-measured external galactic rotation curves evidence was found for this law. In the case of the Milky Way, the locations of eight sharp rises in the rotation curve fit the prediction of the self-similar model at the 3% level. Moreover, a triangular feature in the IRAS map of the galactic plane is consistent with the imprint of a ring caustic upon the baryonic matter. These observations imply that the dark matter in our neighborhood is dominated by a single flow. Estimates of that flow's density and velocity vector are given.

P. Sikivie

2001-12-04T23:59:59.000Z

315

Structural power flow measurement  

SciTech Connect (OSTI)

Previous investigations of structural power flow through beam-like structures resulted in some unexplained anomalies in the calculated data. In order to develop structural power flow measurement as a viable technique for machine tool design, the causes of these anomalies needed to be found. Once found, techniques for eliminating the errors could be developed. Error sources were found in the experimental apparatus itself as well as in the instrumentation. Although flexural waves are the carriers of power in the experimental apparatus, at some frequencies longitudinal waves were excited which were picked up by the accelerometers and altered power measurements. Errors were found in the phase and gain response of the sensors and amplifiers used for measurement. A transfer function correction technique was employed to compensate for these instrumentation errors.

Falter, K.J.; Keltie, R.F.

1988-12-01T23:59:59.000Z

316

Neutrino Factory Mercury Flow Loop  

E-Print Network [OSTI]

Neutrino Factory Mercury Flow Loop V. GravesV. Graves C. Caldwell IDS-NF Videoconference March 9, 2010 #12;Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94 2 liter/min 24 9 gpm)mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment showed that a pump

McDonald, Kirk

317

Orifice flow measurement uncertainty  

SciTech Connect (OSTI)

A computer program is now available from Union Carbide that evaluates the total flow uncertainty of orifice flowmeter systems. Tolerance values for every component in the system and the sensitivity of the measured flowrate to each component can be established using historical data and published hardware specifications. Knowing the tolerance and sensitivity values, a total measurement uncertainty can be estimated with a 95% confidence level. This computer program provides a powerful design tool to ensure correct component matching and total metering system optimization.

Samples, C.R.

1984-04-01T23:59:59.000Z

318

CX-006145: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

The Painesville Municipal Power Vanadium Redox Battery Demonstration ProgramCX(s) Applied: B3.6Date: 07/14/2011Location(s): Painesville, OhioOffice(s): Electricity Delivery and Energy Reliability, National Energy Technology Laboratory

319

Convective heat flow probe  

DOE Patents [OSTI]

A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

Dunn, J.C.; Hardee, H.C.; Striker, R.P.

1984-01-09T23:59:59.000Z

320

Spectroscopic study of a Cu/CeO{sub 2} catalyst subjected to redox treatments in carbon monoxide and oxygen  

SciTech Connect (OSTI)

Redox processes induced by interaction of a calcined Cu/CeO{sub 2} catalyst with CO and reoxidation with O{sub 2} have been investigated by CO-TPR, EPR, FTIR of adsorbed CO, and XPS. The initial calcined samples shows the presence of dispersed Cu{sup 2+} species, which give rise in the EPR spectrum to signals due to isolated entities, a somewhat more aggregated Cu{sup 2+}-containing phase, and copper ionic pairs, in coexistence with an EPR-silent CuO-type phase, revealed by XPS. A significant reduction of copper is produced already by contact with CO at room temperature, EPR results suggesting that reducibility of Cu{sup 2+} species decreases with their aggregation degree. Simultaneously, the ceria surface is also reduced by this interaction, copper acting as a strong promoter of this process. A singular consequence of the synergistic reduction of both components is observed by subjecting the catalyst to CO at T{sub r} {ge} 473 K, at which the CO adsorption capability of copper is apparently suppressed, in view of the absence of copper carbonyls in the FTIR spectrum. This is attributed to the establishment of electronic interactions between reduced ceria and small metallic copper particles generated by the reduction process. Contact of the CO-reduced sample with O{sub 2} at room or higher temperature produces an important reoxidation of both copper and ceria, revealed by FTIR and EPR. The synergetic effects between copper and ceria in the reduction process and the easy reoxidation of deeply reduced ceria are thought to be crucial to explaining the high catalytic activity shown by this system for CO oxidation.

Martinez-Arias, A.; Fernandez-Garcia, M.; Soria, J.; Conesa, J.C. [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica] [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica

1999-03-10T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Redox Exchange Induced MnO2 Nanoparticle Enrichment in Poly(3,4-ethylenedioxythiophene) Nanowires for Electrochemical Energy Storage  

SciTech Connect (OSTI)

MnO{sub 2} nanoparticle enriched poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires are fabricated by simply soaking the PEDOT nanowires in potassium permanganate (KMnO{sub 4}) solution. The structures of these MnO{sub 2} nanoparticle enriched PEDOT nanowires are characterized by SEM and TEM, which show that the MnO{sub 2} nanoparticles have uniform sizes and are finely dispersed in the PEDOT matrix. The chemical constituents and bonding of these composite nanowires are characterized by energy-dispersive X-ray analysis, X-ray photoelectron spectroscopy, and infrared spectroscopy, which indicate that the formation and dispersion of these MnO{sub 2} nanoparticles into the nanoscale pores of the PEDOT nanowires are most likely triggered by the reduction of KMnO{sub 4} via the redox exchange of permanganate ions with the functional group on PEDOT. Varying the concentrations of KMnO{sub 4} and the reaction time controls the loading amount and size of the MnO{sub 2} nanoparticles. Cyclic voltammetry and galvanostatic charge?discharge are used to characterize the electrochemical properties of these MnO{sub 2} nanoparticle loaded PEDOT nanowires. Due to their extremely high exposed surface area with nanosizes, the pristine MnO{sub 2} nanoparticles in these MnO{sub 2} nanoparticle enriched PEDOT nanowires show very high specific capacitance (410 F/g) as the supercapacitor electrode materials as well as high Li+ storage capacity (300 mAh/g) as cathode materials of Li ion battery, which boost the energy storage capacity of PEDOT nanowires to 4 times without causing excessive volume expansion in the polymer. The highly conductive and porous PEDOT matrix facilitates fast charge/discharge of the MnO{sub 2} nanoparticles and prevents them from agglomerating. These synergic properties enable the MnO{sub 2} nanoparticle enriched PEDOT nanowires to be promising electrode materials for supercapacitors and lithium ion batteries.

Liu, R; Duay, Jonathon; Lee, Sang Bok

2010-01-01T23:59:59.000Z

322

Viologen (2+/1+) and viologen(1+/0) electron-self-exchange reactions in a redox polymer  

SciTech Connect (OSTI)

An analysis is given of the electron-self-exchange reactions responsible for the steady-state redox conductivity of thin films of the electropolymerized monomer N,N{prime}-bis(3-pyrrol-1-yl-propyl)-4,4{prime}-bipyridinium tetrafluoroborate, sandwiched between two electrodes. Concentration-gradient-driven electron self-exchange in the liquid-acetonitrile-bathed viologen(2+/1+) mixed-valent state of this polymer, k{sub ex} = 8 {times} 10{sup 3} M{sup {minus}1}s{sup {minus}1}, is much slower than that for the viologen (1+/0) mixed-valent state, k{sub ek} = 1.6 {times} 10{sup 5} M{sup {minus}1} s{sup {minus}1}, which has a smaller activation barrier. Neither self-exchange reaction responds to use of alternative counteranions except that both rates decrease in polymer containing tosylate counterions. The rate constant found for the electrical-gradient-driven viologen (1+/0) electron self-exchange, k{sub ex} = 1.1 {times} 10{sup 5} M{sup {minus}1} s{sup {minus}1}, observed in dry, N{sub 2}-bathed polymer where ClO{sub 4}{sup {minus}} counterion mobility is quenched, is nearly the same as the acetonitrile-bathed value. The rate constants appear to be dominated by characteristics of the polymer phase rather than the bathing environment of the polymer. Estimates are made of the counteranion diffusivity in acetonitrile-bathed films and of how it effects transient electron transport measurements.

Dalton, E.F.; Murray, R.W. (Univ. of North Carolina, Chapel Hill (United States))

1991-08-08T23:59:59.000Z

323

Numerical Investigations of Magnetohydrodynamic Hypersonic Flows.  

E-Print Network [OSTI]

??Numerical simulations of magnetohydrodynamic (MHD) hypersonic flow are presented for both laminar and turbulent flow over a cylinder and flow entering a scramjet inlet. ANSYS… (more)

Guarendi, Andrew N

2013-01-01T23:59:59.000Z

324

UZ Flow Models and Submodels  

SciTech Connect (OSTI)

The purpose of this report is to document the unsaturated zone (UZ) flow models and submodels, as well as the flow fields that have been generated using the UZ flow model(s) of Yucca Mountain, Nevada. In this report, the term ''UZ model'' refers to the UZ flow model and the several submodels, which include tracer transport, temperature or ambient geothermal, pneumatic or gas flow, and geochemistry (chloride, calcite, and strontium) submodels. The term UZ flow model refers to the three-dimensional models used for calibration and simulation of UZ flow fields. This work was planned in the ''Technical Work Plan (TWP) for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Section 1.2.7). The table of included Features, Events, and Processes (FEPs), Table 6.2-11, is different from the list of included FEPs assigned to this report in the ''Technical Work Plan for: Unsaturated Zone Flow Analysis and Model Report Integration'' (BSC 2004 [DIRS 169654], Table 2.1.5-1), as discussed in Section 6.2.6. The UZ model has revised, updated, and enhanced the previous UZ model (BSC 2001 [DIRS 158726]) by incorporating the repository design with new grids, recalibration of property sets, and more comprehensive validation effort. The flow fields describe fracture-fracture, matrix-matrix, and fracture-matrix liquid flow rates, and their spatial distributions as well as moisture conditions in the UZ system. These three-dimensional UZ flow fields are used directly by Total System Performance Assessment (TSPA). The model and submodels evaluate important hydrogeologic processes in the UZ as well as geochemistry and geothermal conditions. These provide the necessary framework to test hypotheses of flow and transport at different scales, and predict flow and transport behavior under a variety of climatic conditions. In addition, the limitations of the UZ model are discussed in Section 8.11.

Y. Wu

2004-11-01T23:59:59.000Z

325

What's Next for Vanadium Dioxide?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout PrintableBlenderWhat Makes Clouds Form,How Atomic

326

Similarity of the Surface Reactivity of Hydrous Ferric Oxide and Hematite: Sorption and Redox of U(VI) and Fe(II)  

SciTech Connect (OSTI)

Hydrous Ferric Oxide (HFO) vs. Hematite--Thermodynamically distinctive bulk phases, but the surfaces could be similar due to hydration of the interface. Hypothesis--The surface of HFO is energetically similar to the surface of hematite. Objective--Compare the reactions of HFO and hematite with U(VI) and Fe(II). Experimental--The reactions of interests were (1) preparation of sub-micron hematite, (2) sorption of U(VI), and (3) redox of U(VI) and Fe(II) with HFO or hematite.

Je-Hun Jang; Dempsey, Brian A.; Burgos, William D.; Yeh, George; Roden, Eric

2004-03-17T23:59:59.000Z

327

Aqueous Transition Metal Cations as Impurities in a Wide Gap Oxide: The Cu^2+/Cu^1+ and Ag^2+/Ag^1+ Redox Couples Revisited  

E-Print Network [OSTI]

of 10ps. The longitudinal relaxation is more than a magnitude faster. Results and analysis Gas-phase Table 1 lists the calculated M-O bond lengths in the four gas-phase complexes we have investigated (see fig. 1). One can see that for the same number... containing a fraction of Hartree-Fock exchange. These calculations make use of recent progress in DFTMD technology enabling us to include sp core polarization and Hartree-Fock exchange in condensed phase model systems. Keywords Aqueous redox chemistry...

Liu, Xiandong; Cheng, Jun; Sprik, Michiel

2014-11-11T23:59:59.000Z

328

Fluid flow monitoring device  

DOE Patents [OSTI]

A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

1993-11-30T23:59:59.000Z

329

Fluid flow monitoring device  

DOE Patents [OSTI]

A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

McKay, Mark D. (1426 Socastee Dr., North Augusta, SC 29841); Sweeney, Chad E. (3600 Westhampton Dr., Martinez, GA 30907-3036); Spangler, Jr., B. Samuel (2715 Margate Dr., Augusta, GA 30909)

1993-01-01T23:59:59.000Z

330

Radial flow heat exchanger  

DOE Patents [OSTI]

A radial flow heat exchanger (20) having a plurality of first passages (24) for transporting a first fluid (25) and a plurality of second passages (26) for transporting a second fluid (27). The first and second passages are arranged in stacked, alternating relationship, are separated from one another by relatively thin plates (30) and (32), and surround a central axis (22). The thickness of the first and second passages are selected so that the first and second fluids, respectively, are transported with laminar flow through the passages. To enhance thermal energy transfer between first and second passages, the latter are arranged so each first passage is in thermal communication with an associated second passage along substantially its entire length, and vice versa with respect to the second passages. The heat exchangers may be stacked to achieve a modular heat exchange assembly (300). Certain heat exchangers in the assembly may be designed slightly differently than other heat exchangers to address changes in fluid properties during transport through the heat exchanger, so as to enhance overall thermal effectiveness of the assembly.

Valenzuela, Javier (Hanover, NH)

2001-01-01T23:59:59.000Z

331

Annular flow diverter valve  

DOE Patents [OSTI]

A valve for diverting flow from the center of two concentric tubes to the annulus between the tubes or, operating in the reverse direction, for mixing fluids from concentric tubes into a common tube and for controlling the volume ratio of said flow consists of a toroidal baffle disposed in sliding engagement with the interior of the inner tube downstream of a plurality of ports in the inner tube, a plurality of gates in sliding engagement with the interior of the inner tube attached to the baffle for movement therewith, a servomotor having a bullet-shaped plug on the downstream end thereof, and drive rods connecting the servomotor to the toroidal baffle, the servomotor thereby being adapted to move the baffle into mating engagement with the bullet-shaped plug and simultaneously move the gates away from the ports in the inner tube and to move the baffle away from the bullet-shaped plug and simultaneously move the gates to cover the ports in the inner tube.

Rider, Robert L. (Walkersville, MD)

1980-01-01T23:59:59.000Z

332

Poly(pyridine)ruthenium(II)-photoinduced redox reactions of bipyridinium cations, poly(pyridine)rhodium complexes, and osmium ammines  

SciTech Connect (OSTI)

The quenching of *RuL/sub 3//sup 2 +/ (L is a 2,2'-bipyridine or 1,10-phenanthroline derivative) emissions by three classes of oxidants Q has been examined. The results are discussed in terms of the Marcus electron-transfer model recast in a preequilibrium formalism. Substituted bipyridinium cations (methyl viologen and related compounds) undergo thermodynamically favorable reduction with a driving force ranging from 0.1 to 0.7 eV and rate constants in the range (0.4-2.0) x 10/sup 9/ M/sup -1/s/sup -1/, consistent with a diffusion rate constant of 2.0 x 10/sup 9/ M/sup -1/s/sup -1/ and an exchange rate constant of approx.10/sup 6/ M/sup -1/s/sup -1/ for the Q-Q couples. The yields of the separated redox products RuL/sub 3//sup 3 +/ and Q/sup -/ (typically 0.1 mol einstein/sup -1/ per quenching act) require K/sub 30/, the ''intramolecular'' back-reaction rate constant (to re-form ground-state RuL/sub 3//sup 2 +/ and Q), to be (2-4) x 10/sup 10/ s/sup -1/. Since K/sub 30/ increases weakly with driving force in this series, there is no evidence for inverted behavior despite the fact the ..delta..G/sup 0//sub 30/ is approx.-2 eV. With Q = Rh(4,4'-(CH/sub 3/)/sub 2/bpy)/sub 3//sup 3 +/, the quenching rate constants, k/sub q/ = (0.001-1.0) x 10/sup 9/ M/sup -1/s/sup -1/, exhibit a great sensitivity to the reducing power of *RuL/sub 3//sup 2 +/ and have been fitted to k/sub 11/ approx. = 2 x 10/sup 9/ M/sup -1/s/sup -1/ and E/sup 0//sub Q,Q/sup -// = -0.97 V for the RhL/sub 3//sup 3 +/-RhL/sub 3//sup 2 +/ couple. This E/sup 0/ value is strikingly similar to that (-0.9 V vs. aqueous SCE) obtained via cyclic voltammetry in acetonitrile. The cyclic voltammetry of the RhL/sub 3//sup 3 +/ complexes in water has been reexamined, and it is concluded that the irreversibility observed is due to ligand loss from rhodium(I).

Creutz, C.; Keller, A.D.; Sutin, N.; Zipp, A.P.

1982-06-30T23:59:59.000Z

333

Reduction of a Redox-Active Ligand Drives Switching in a Cu(I) Pseudorotaxane by a Bimolecular Mechanism  

SciTech Connect (OSTI)

The reduction of a redox-active ligand is shown to drive reversible switching of a Cu(I) [2]pseudorotaxane ([2]PR{sup 2+}) into the reduced [3]pseudorotaxane ([3]PR{sup 2+}) by a bimolecular mechanism. The unreduced pseudorotaxanes [2]PR{sup 2+} and [3]PR{sup 2+} are initially self-assembled from the binucleating ligand, 3,6-bis(5-methyl-2-pyridine)-1,2,4,5-tetrazine (Me2BPTZ), and a preformed copper-macrocycle moiety (Cu-M{sup 2+}) based on 1,10-phenanthroline. X-ray crystallography revealed a syn geometry of the [3]PR{sup 2+}. The UV-vis-NIR spectra show low-energy metal-to-ligand charge-transfer transitions that red shift from 808 nm for [2]PR{sup 2+} to 1088 nm for [3]PR{sup 2+}. Quantitative analysis of the UV-vis-NIR titration shows the stepwise formation constants to be K{sub 1} = 8.9 x 10{sup 8} M{sup -1} and K{sub 2} = 3.1 x 10{sup 6} M{sup -1}, indicative of negative cooperativity. The cyclic voltammetry (CV) and coulometry of Me{sub 2}BPTZ, [2]PR{sup 2+}, and [3]PR{sup 2+} shows the one-electron reductions at E{sub 1/2} = -0.96, -0.65, and -0.285 V, respectively, to be stabilized in a stepwise manner by each Cu{sup 2+} ion. CVs of [2]PR{sup 2+} show changes with scan rate consistent with an EC mechanism of supramolecular disproportionation after reduction: [2]PR{sup 0} + [2]PR{sup 2+} = [3]PR{sup 2+} + Me{sub 2}BPTZ{sup 0} (K*{sub D}, k{sub d}). UV-vis-NIR spectroelectrochemistry was used to confirm the 1:1 product stoichiometry for [3]PR{sup 2+}:Me{sub 2}BPTZ. The driving force ({Delta}G*{sub D} = -5.1 kcal mol{sup -1}) for the reaction is based on the enhanced stability of the reduced [3]PR{sup 2+} over reduced [2]PR{sup 0} by 365 mV (8.4 kcal mol{sup -1}). Digital simulations of the CVs are consistent with a bimolecular pathway (k{sub d} = 12,000 s{sup -1} M{sup -1}). Confirmation of the mechanism provides a basis to extend this new switching modality to molecular machines.

McNitt, Kristy A.; Parimal, Kumar; Share, Andrew I.; Fahrenbach, Albert C.; Witlicki, Edward H.; Pink, Maren; Bediako, D. Kwabena; Plaisier, Christina L.; Le, Nga; Heeringa, Lee P.; Vander Griend, Douglas A.; Flood, Amar H.; (Calvin); (Indiana)

2009-04-02T23:59:59.000Z

334

Active combustion flow modulation valve  

DOE Patents [OSTI]

A flow modulation valve has a slidably translating hollow armature with at least one energizable coil wound around and fixably attached to the hollow armature. The energizable coil or coils are influenced by at least one permanent magnet surrounding the hollow armature and supported by an outer casing. Lorentz forces on the energizable coils which are translated to the hollow armature, increase or decrease the flow area to provide flow throttling action. The extent of hollow armature translation depends on the value of current supplied and the direction of translation depends on the direction of current flow. The compact nature of the flow modulation valve combined with the high forces afforded by the actuator design provide a flow modulation valve which is highly responsive to high-rate input control signals.

Hensel, John Peter; Black, Nathaniel; Thorton, Jimmy Dean; Vipperman, Jeffrey Stuart; Lambeth, David N; Clark, William W

2013-09-24T23:59:59.000Z

335

[Unsegmented continuous-flow sample processing and electrochemical detection of gaseous species]. Final report, March 1, 1985--February 28, 1991  

SciTech Connect (OSTI)

Goals were a continuous-flow, unsegmented, all-gas carrier and/or a segmented liquid/gas interface system for sample introduction and transport to detection/determination point; a regenerable electrode probe base on redox reactions of Fe(II) and Fe(III) complexes with 1, 10-phenanthroline and related ligands; and amperometric/coulometric current measurements providing analyte signals. Gases to be detected included NO{sub x} and SO{sub 2}. This report is divided into 3 parts: preparation of new ligands of 1,10-phenanthroline family; glassy carbon surfaces coated with polymeric films prepared from monomeric units of tris[5-amino-1,10-phenanthroline]iron(II); and sulfite oxidase/hexacyanoferrate modified C paste electrode.

Mottola, H.A.

1991-12-31T23:59:59.000Z

336

Differential probes aid flow measurement  

SciTech Connect (OSTI)

Nonconstricting differential pressure flow probes which help solve the problems of clogging, wear, and pressure loss at the Seawater Filtration Facility in Saudi Arabia are described. Treated seawater is pumped into oil-bearing formations for secondary recovery. Figures showing principle of operation for probes, installation schematic and long-term accuracy results (flow probes vs. orifice meters) are presented. The new diamond-shaped design flow sensor offers accurate flow measurement with low permanent pressure loss, which translates into cost savings for the operator.

Mesnard, D.R.

1982-07-01T23:59:59.000Z

337

Comparative Study on Redox Properties of Nanosized CeO2 and CuO/Ce2 Under CO/O2  

SciTech Connect (OSTI)

Nanosized CeO{sub 2} and CuO/CeO{sub 2} samples, active for CO-PROX or related processes were comparatively examined by O{sub 2} probe electron paramagnetic resonance and in situ Raman and X-ray diffraction techniques. Their behavior toward CO reduction, as well as the oxygen-handling properties of the CO-reduced samples, was explored. An appreciable reduction of the ceria bulk was detected on treatment under CO at 473 K. On the basis of the analysis of the evolution of different oxygen-derived species (superoxide, peroxide, O-) on low-temperature (77-300 K) oxygen chemisorption on the CO-reduced samples, a general picture of the redox properties of the samples is presented. Results demonstrate that the presence of copper promotes completion of the redox cycle under CO/O{sub 2} by favoring both ceria reduction and oxidation. This can be relevant to explaining the remarkable oxidation activity and synergetic effects observed for catalysts combining CuO and CeO{sub 2}.

Martinez-Arias,A.; Gamarra, D.; Fernandez-Garcia, M.; Wang, X.; Hanson, J.; Rodriguez, J.

2006-01-01T23:59:59.000Z

338

Section 11: Interfacial flows 1 Section 11: Interfacial flows  

E-Print Network [OSTI]

Abstract 15:10 ­ 15:30: Martin Lübke, Olaf Wünsch (Universität Kassel): Two-Phase Flow in Single- Screw Extruders Abstract S11.4: Capillary Flows Wed, 16:00­18:00 Chair: Dieter Bothe S1|03­123 16:00 ­ 16:20: K

Kohlenbach, Ulrich

339

Analysis of flow patterns and flow mechanisms in soils  

E-Print Network [OSTI]

Analysis of flow patterns and flow mechanisms in soils Dissertation Co-directed by the University mechanism or changing soil physical properties (stratification). Thus, in stratified soil, we restricted was prepared at the Department of Soil Physics, University of Bayreuth, and at the Hydrogeological Laboratory

Avignon et des Pays de Vaucluse, Université de

340

Effect of flow fluctuations and nonflow on elliptic flow methods  

SciTech Connect (OSTI)

We discuss how the different estimates of elliptic flow are influenced by flow fluctuations and nonflow effects. It is explained why the event-plane method yields estimates between the two-particle correlation methods and the multiparticle correlation methods. It is argued that nonflow effects and fluctuations cannot be disentangled without other assumptions. However, we provide equations where, with reasonable assumptions about fluctuations and nonflow, all measured values of elliptic flow converge to a unique mean v_2,PP elliptic flow in the participant plane and, with a Gaussian assumption on eccentricity fluctuations, can be converted to the mean v_2,RP in the reaction plane. Thus, the 20percent spread in observed elliptic flow measurements from different analysis methods is no longer mysterious.

Ollitrault, Jean-Yves; Poskanzer, Arthur M.; Voloshin, Sergei A.

2009-04-16T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Network Flow Optimization under Uncertainty  

E-Print Network [OSTI]

Network model in words Minimize the cost of satisfying demands for electric energy By: imports, exports and electricity Subject to: conservation of energy flows (net after losses), lower and upper bounds on flows is a reactive approach: how would the optimal solution have changed if I'd only known? · Proactive approaches

Tesfatsion, Leigh

342

Vertical flow chemical detection portal  

DOE Patents [OSTI]

A portal apparatus is described for screening objects or persons for the presence of trace amounts of chemical substances such as illicit drugs or explosives. The apparatus has a test space, in which a person may stand, defined by two generally upright sides spanned by a horizontal transom. One or more fans in the transom generate a downward air flow (uni-directional) within the test space. The air flows downwardly from a high pressure upper zone, past the object or person to be screened. Air moving past the object dislodges from the surface thereof both volatile and nonvolatile particles of the target substance. The particles are entrained into the air flow which continues flowing downward to a lower zone of reduced pressure, where the particle-bearing air stream is directed out of the test space and toward preconcentrator and detection components. The sides of the portal are specially configured to partially contain and maintain the air flow. 3 figs.

Linker, K.L.; Hannum, D.W.; Conrad, F.J.

1999-06-22T23:59:59.000Z

343

Wavy flow cooling concept for turbine airfoils  

DOE Patents [OSTI]

An airfoil including an outer wall and a cooling cavity formed therein. The cooling cavity includes a leading edge flow channel located adjacent a leading edge of the airfoil and a trailing edge flow channel located adjacent a trailing edge of the airfoil. Each of the leading edge and trailing edge flow channels define respective first and second flow axes located between pressure and suction sides of the airfoil. A plurality of rib members are located within each of the flow channels, spaced along the flow axes, and alternately extending from opposing sides of the flow channels to define undulating flow paths through the flow channels.

Liang, George (Palm City, FL)

2010-08-31T23:59:59.000Z

344

Pertechnetate (TcO4-) reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Hanford Site, USA  

SciTech Connect (OSTI)

Technetium is an important environmental contaminant introduced by the processing and disposal of irradiated nuclear fuel and atmospheric nuclear tests. Under oxic conditions technetium is soluble and exists as pertechnatate anion (TcO4-), while under anoxic conditions Tc is usually insoluble and exists as precipitated Tc(IV). Here we investigated abiotic Tc(VII) reduction in mineralogically heterogeneous, Fe(II)-containing sediments. The sediments were collected from a 55 m borehole that sampled a semi-confined aquifer at the Hanford Site, USA that contained a dramatic redox transition zone. One oxic facies (18.0-18.3 m) and five anoxic facies (18.3-18.6 m, 30.8-31.1 m, 39.0-39.3 m, 47.2-47.5 m and 51.5-51.8 m) were selected for this study. Chemical extractions, X-ray diffraction, electron microscopy, and Mössbauer spectroscopy were applied to characterize the Fe(II) mineral suite that included: Fe(II)-phyllosilicates, pyrite, magnetite and siderite. The Fe(II) mineral phase distribution differed between the sediments. Sediment suspensions were adjusted to the same 0.5 M HCl extracted Fe(II) concentration (0.6 mM) for Tc(VII) reduction experiments. Aqueous Fe was low in all sediment suspensions (<2 ?M) and below the Fe(II)aq detection limit (10 ?M). Technetium(VII) reduction occurred in all anoxic sediments at depths greater than 18.3 m and reaction time differed significantly between the sediments (8-219 d). Mössbauer analysis of the Tc-reacted, 30.8-31.1 m sediment confirmed that Tc(VII) was reduced by solid-phase Fe(II), with siderite and Fe(II)-containing phyllosilicates implicated as redox reactive phases. Technetium-XAS analysis demonstrated that Tc associated with sediments was in the Tc(IV) valence state and immobilized as clusters of a TcO2·nH2O-like phase. The speciation of redox product Tc(IV) was not affected by reduction rate or Fe(II) mineralogy.

Peretyazhko, Tetyana; Zachara, John M.; Kukkadapu, Ravi K.; Heald, Steve M.; Kutnyakov, Igor V.; Resch, Charles T.; Arey, Bruce W.; Wang, Chong M.; Kovarik, Libor; Phillips, Jerry L.; Moore, Dean A.

2012-09-01T23:59:59.000Z

345

Turbine blade tip flow discouragers  

DOE Patents [OSTI]

A turbine assembly comprises a plurality of rotating blade portions in a spaced relation with a stationery shroud. The rotating blade portions comprise a root section, a tip portion and an airfoil. The tip portion has a pressure side wall and a suction side wall. A number of flow discouragers are disposed on the blade tip portion. In one embodiment, the flow discouragers extend circumferentially from the pressure side wall to the suction side wall so as to be aligned generally parallel to the direction of rotation. In an alternative embodiment, the flow discouragers extend circumferentially from the pressure side wall to the suction side wall so as to be aligned at an angle in the range between about 0.degree. to about 60.degree. with respect to a reference axis aligned generally parallel to the direction of rotation. The flow discouragers increase the flow resistance and thus reduce the flow of hot gas flow leakage for a given pressure differential across the blade tip portion so as to improve overall turbine efficiency.

Bunker, Ronald Scott (Niskayuna, NY)

2000-01-01T23:59:59.000Z

346

Journal of the Geological Society, London, Vol. 168, 2011, pp. 805815. doi: 10.1144/0016-76492010-132. Hydrothermal origin of elevated iron, manganese and redox-sensitive trace  

E-Print Network [OSTI]

.1144/0016-76492010-132. 805 Hydrothermal origin of elevated iron, manganese and redox-sensitive trace elements in the c. 635 Ma Doushantuo cap carbonate JING HUANG1,2 , XUELEI CHU1,2 *, GANQING JIANG3 , LIANJUN FENG1 & HUAJIN, including REE, concentrations of the Doushantuo cap carbonate (c. 635 Ma) in South China show enrichment

Jiang, Ganqing

347

Multiscale Simulations for Polymeric Flow  

E-Print Network [OSTI]

Multiscale simulation methods have been developed based on the local stress sampling strategy and applied to three flow problems with different difficulty levels: (a) general flow problems of simple fluids, (b) parallel (one-dimensional) flow problems of polymeric liquids, and (c) general (two- or three-dimensional) flow problems of polymeric liquids. In our multiscale methods, the local stress of each fluid element is calculated directly by performing microscopic or mesoscopic simulations according to the local flow quantities instead of using any constitutive relations. For simple fluids (a), such as the Lenard-Jones liquid, a multiscale method combining MD and CFD simulations is developed based on the local equilibrium assumption without memories of the flow history. (b), the multiscale method is extended to take into account the memory effects that arise in hydrodynamic stress due to the slow relaxation of polymer-chain conformations. The memory of polymer dynamics on each fluid element is thus resolved by performing MD simulations in which cells are fixed at the mesh nodes of the CFD simulations.For general (two- or three-dimensional) flow problems of polymeric liquids (c), it is necessary to trace the history of microscopic information such as polymer-chain conformation, which carries the memories of past flow history, along the streamline of each fluid element. A Lagrangian-based CFD is thus implemented to correctly advect the polymer-chain conformation consistently with the flow. On each fluid element, coarse-grained polymer simulations are carried out to consider the dynamics of entangled polymer chains that show extremely slow relaxation compared to microscopic time scales.

Takahiro Murashima; Takashi Taniguchi; Ryoichi Yamamoto; Shugo Yasuda

2011-01-06T23:59:59.000Z

348

The transition from two phase bubble flow to slug flow  

E-Print Network [OSTI]

The process of transition from bubble to slug flow in a vertical pipe has been studied analytically and experimentally. An equation is presented which gives the agglomeration time as a function of void fraction, channel ...

Radovcich, Nick A.

1962-01-01T23:59:59.000Z

349

Flow distribution channels to control flow in process channels  

DOE Patents [OSTI]

The invention describes features that can be used to control flow to an array of microchannels. The invention also describes methods in which a process stream is distributed to plural microchannels.

Tonkovich, Anna Lee; Arora, Ravi; Kilanowski, David

2014-10-28T23:59:59.000Z

350

Gas flow characterization of restrictive flow orifice devices  

SciTech Connect (OSTI)

A restrictive flow orifice (RFO) can be used to limit the uncontrolled release of system media upon component or line failure in a gas handling system and can thereby enhance the system safety. This report describes a new RFO product available from the Swagelok Companies and specifies the gas flow characteristics of this device. A family of four different sizes of RFO devices is documented.

Shrouf, R.G. [Sandia National Labs., Albuquerque, NM (United States). Safety Engineering Dept.; Page, S.R. [Albuquerque Valve and Fitting Co., NM (United States)

1997-07-01T23:59:59.000Z

351

Insertable fluid flow passage bridgepiece and method  

DOE Patents [OSTI]

A fluid flow passage bridgepiece for insertion into an open-face fluid flow channel of a fluid flow plate is provided. The bridgepiece provides a sealed passage from a columnar fluid flow manifold to the flow channel, thereby preventing undesirable leakage into and out of the columnar fluid flow manifold. When deployed in the various fluid flow plates that are used in a Proton Exchange Membrane (PEM) fuel cell, bridgepieces of this invention prevent mixing of reactant gases, leakage of coolant or humidification water, and occlusion of the fluid flow channel by gasket material. The invention also provides a fluid flow plate assembly including an insertable bridgepiece, a fluid flow plate adapted for use with an insertable bridgepiece, and a method of manufacturing a fluid flow plate with an insertable fluid flow passage bridgepiece.

Jones, Daniel O. (Glenville, NV)

2000-01-01T23:59:59.000Z

352

Capillary flows in flexible structures  

E-Print Network [OSTI]

Interactions between capillary and elastic effects are relevant to a variety of applications, from micro- and nano-scale manufacturing to biological systems. In this thesis, we investigate capillary flows in extremely ...

Hoberg, Theresa B. (Theresa Blinn)

2013-01-01T23:59:59.000Z

353

2007 Estimated International Energy Flows  

SciTech Connect (OSTI)

An energy flow chart or 'atlas' for 136 countries has been constructed from data maintained by the International Energy Agency (IEA) and estimates of energy use patterns for the year 2007. Approximately 490 exajoules (460 quadrillion BTU) of primary energy are used in aggregate by these countries each year. While the basic structure of the energy system is consistent from country to country, patterns of resource use and consumption vary. Energy can be visualized as it flows from resources (i.e. coal, petroleum, natural gas) through transformations such as electricity generation to end uses (i.e. residential, commercial, industrial, transportation). These flow patterns are visualized in this atlas of 136 country-level energy flow charts.

Smith, C A; Belles, R D; Simon, A J

2011-03-10T23:59:59.000Z

354

particle flow for nonlinear filters  

E-Print Network [OSTI]

particle flow for nonlinear filters Fred Daum 19 June 2012 Copyright © 2012 Raytheon Company. All rights reserved. Customer Success Is Our Mission is a trademark of Raytheon Company. 1 #12;discrete time

Dobigeon, Nicolas

355

Fluid Flow Modeling in Fractures  

E-Print Network [OSTI]

In this paper we study fluid flow in fractures using numerical simulation and address the challenging issue of hydraulic property characterization in fractures. The methodology is based on Computational Fluid Dynamics, ...

Sarkar, Sudipta

2004-01-01T23:59:59.000Z

356

Mechanical design of flow batteries  

E-Print Network [OSTI]

The purpose of this research is to investigate the design of low-cost, high-efficiency flow batteries. Researchers are searching for next-generation battery materials, and this thesis presents a systems analysis encompassing ...

Hopkins, Brandon J. (Brandon James)

2013-01-01T23:59:59.000Z

357

Field Flows of Dark Energy  

E-Print Network [OSTI]

Field Flows of Dark Energy Robert N. Cahn, Roland de Putter,July 8, 2008) Scalar ?eld dark energy evolving from a longthe key aspects of the dark energy evolution during much of

Cahn, Robert N.

2010-01-01T23:59:59.000Z

358

Longitudinal dispersion in vegetated flow  

E-Print Network [OSTI]

Vegetation is ubiquitous in rivers, estuaries and wetlands, strongly influencing both water conveyance and mass transport. The plant canopy affects both mean and turbulent flow structure, and thus both advection and ...

Murphy, Enda

2006-01-01T23:59:59.000Z

359

Pipe Flow System Holly Guest  

E-Print Network [OSTI]

numbers #12;Pipe Flow System Form #12;Components Form Fitting Loss Coefficient, k Globe valve, fully open 10 Angle valve, fully open 5 Swing check valve, fully open 2.5 Gate valve, fully open .2 Shortradius

Clement, Prabhakar

360

Multiscale modeling in granular flow  

E-Print Network [OSTI]

Granular materials are common in everyday experience, but have long-resisted a complete theoretical description. Here, we consider the regime of slow, dense granular flow, for which there is no general model, representing ...

Rycroft, Christopher Harley

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Subcooled flow boiling of fluorocarbons  

E-Print Network [OSTI]

A study was conducted of heat transfer and hydrodynamic behavior for subcooled flow boiling of Freon-113, one of a group of fluorocarbons suitable for use in cooling of high-power-density electronic components. Problems ...

Murphy, Richard Walter

1971-01-01T23:59:59.000Z

362

Minimum Stream Flow Standards (Connecticut)  

Broader source: Energy.gov [DOE]

These regulations apply to all dams and structures which impound or divert waters on rivers or their tributaries, with some exceptions. The regulations set standards for minimum flow (listed in the...

363

Automation of radiochemical analysis by applying flow  

E-Print Network [OSTI]

of detection systems, including scintillation counting, a-spectrometers, proportional counters, mass spectrometry and spectrophotometry. ª 2010 Published by Elsevier Ltd. Keywords: Flow-analysis technique; Flow

Sánchez, David

364

MODERN DEVELOPMENTS IN MULTIPHASE FLOW & HEAT TRANSFER  

E-Print Network [OSTI]

MODERN DEVELOPMENTS IN MULTIPHASE FLOW & HEAT TRANSFER "ENGINEERING APPLICATIONS OF FRACTAL and multiphase flow & heat transfer will be stressed. This paper will begin by reviewing some important concepts

Lahey, Richard T.

365

Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer,...

366

Equidistribution results for geodesic flows  

E-Print Network [OSTI]

Using the works of Ma\\~n\\'e \\cite{Ma} and Paternain \\cite{Pat} we study the distribution of geodesic arcs with respect to equilibrium states of the geodesic flow on a closed manifold, equipped with a $\\mathcal{C}^{\\infty}$ Riemannian metric. We prove large deviations lower and upper bounds and a contraction principle for the geodesic flow in the space of probability measures of the unit tangent bundle. We deduce a way of approximating equilibrium states for continuous potentials.

Abdelhamid Amroun

2011-09-15T23:59:59.000Z

367

Subcritical dynamos in shear flows  

E-Print Network [OSTI]

Identifying generic physical mechanisms responsible for the generation of magnetic fields and turbulence in differentially rotating flows is fundamental to understand the dynamics of astrophysical objects such as accretion disks and stars. In this paper, we discuss the concept of subcritical dynamo action and its hydrodynamic analogue exemplified by the process of nonlinear transition to turbulence in non-rotating wall-bounded shear flows. To illustrate this idea, we describe some recent results on nonlinear hydrodynamic transition to turbulence and nonlinear dynamo action in rotating shear flows pertaining to the problem of turbulent angular momentum transport in accretion disks. We argue that this concept is very generic and should be applicable to many astrophysical problems involving a shear flow and non-axisymmetric instabilities of shear-induced axisymmetric toroidal velocity or magnetic fields, such as Kelvin-Helmholtz, magnetorotational, Tayler or global magnetoshear instabilities. In the light of several recent numerical results, we finally suggest that, similarly to a standard linear instability, subcritical MHD dynamo processes in high-Reynolds number shear flows could act as a large-scale driving mechanism of turbulent flows that would in turn generate an independent small-scale dynamo.

F. Rincon; G. I. Ogilvie; M. R. E. Proctor; C. Cossu

2008-05-09T23:59:59.000Z

368

Pressure and flow characteristics of restrictive flow orifice devices.  

SciTech Connect (OSTI)

A Restrictive Flow Orifice (RFO) can be used to enhance the safe design of a pressure system in several ways. Pressure systems frequently incorporate a regulator and relief valve to protect the downstream equipment from accidental overpressure caused by regulator failure. Analysis frequently shows that in cases of high-flow regulator failure, the downstream pressure may rise significantly above the set pressure of the relief valve. This is due to limited flow capacity of the relief valve. A different regulator or relief valve may need to be selected. A more economical solution to this problem is to use an RFO to limit the maximum system flow to acceptable limits within the flow capacity of the relief valve, thereby enhancing the overpressure protection of laboratory equipment. An RFO can also be used to limit the uncontrolled release of system fluid (gas or liquid) upon component or line failure. As an example, potential asphyxiation hazards resultant from the release of large volumes of inert gas from a 'house' nitrogen system can be controlled by the use of an RFO. This report describes a versatile new Sandia-designed RFO available from the Swagelok Company and specifies the gas flow characteristics of this device. Two sizes, 0.010 and 0.020 inch diameter RFOs are available. These sizes will allow enhanced safety for many common applications. This new RFO design are now commercially available and provide advantages over existing RFOs: a high pressure rating (6600 psig); flow through the RFO is equal for either forward or reverse directions; they minimize the potential for leakage by incorporating the highest quality threaded connections; and can enhance the safety of pressure systems.

Shrouf, Roger D.

2003-06-01T23:59:59.000Z

369

Stochastic models for turbulent reacting flows  

SciTech Connect (OSTI)

The goal of this program is to develop and apply stochastic models of various processes occurring within turbulent reacting flows in order to identify the fundamental mechanisms governing these flows, to support experimental studies of these flows, and to further the development of comprehensive turbulent reacting flow models.

Kerstein, A. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

370

Flow Duration Curve Load Duration Curve  

E-Print Network [OSTI]

Flow Duration Curve Load Duration Curve 1. Develop Flow Duration Curve 2. Estimate load given flow and concentration data--select appropriate conversion factors 3. Develop Load Duration Curve 4. Plot observed data with Load Duration Curve What are they? How do you make one? Describes the percent of time a flow rate

371

SHORT-TUBE SUBCRITICAL FLOW Enerag Division  

E-Print Network [OSTI]

#12;SHORT-TUBE SUBCRITICAL FLOW Y. C. Mei Enerag Division Oak Ridge National Laboratory Oak Ridge-tube subcritical flow. For short tubes used as refrigerant expansion devices, the orifice model is found inadequate-TUBE SUBCRITICAL FLOW INTRODUCTION Much theoretical and experimental work regarding short tube fluid flow has

Oak Ridge National Laboratory

372

Mach flow angularity probes for scramjet engine flow path diagnostics  

SciTech Connect (OSTI)

Mach-flow angularity (MFA) probes were developed for use in scramjet flow path probe rakes. Prototype probes were fabricated to demonstrate the assembly processes (numerical control machining, furnace brazing, and electron beam welding). Tests of prototype probes confirmed the thermal durability margins and life cycle. Selected probes were calibrated in air at Mach numbers from 1.75 to 6.0. Acceptance criteria for the production probes stressed thermal durability and pressure (and, consequently, Mach number) measurement quality. This new water-cooled MFA probe has 0.397-cm shaft diameter and is capable of withstanding heat fluxes of 2.724 kW/sq cm.

Jalbert, P.A.; Hiers, R.S. Jr. [Sverdrup Technology, Inc., Arnold AFS, TN (United States)

1993-12-31T23:59:59.000Z

373

Mirrored serpentine flow channels for fuel cell  

DOE Patents [OSTI]

A PEM fuel cell having serpentine flow field channels wherein the input/inlet legs of each channel border the input/inlet legs of the next adjacent channels in the same flow field, and the output/exit legs of each channel border the output/exit legs of the next adjacent channels in the same flow field. The serpentine fuel flow channels may be longer, and may contain more medial legs, than the serpentine oxidant flow channels.

Rock, Jeffrey Allan (Rochester, NY)

2000-08-08T23:59:59.000Z

374

Pressure compensated flow control valve  

DOE Patents [OSTI]

The invention is an air flow control valve which is capable of maintaining a constant flow at the outlet despite changes in the inlet or outlet pressure. The device consists of a shell assembly with an inlet chamber and outlet chamber separated by a separation plate. The chambers are connected by an orifice. Also located within the inlet chamber is a port controller assembly. The port controller assembly consists of a differential pressure plate and port cap affixed thereon. The cap is able to slide in and out of the orifice separating the inlet and outlet chambers. When the pressure differential is sufficient, the differential pressure plate rises or falls to maintain a constant air flow. Movement of the port controller assembly does not require the use of seals, diaphragms, tight tolerances, bushings, bearings, hinges, guides, or lubricants.

Minteer, Daniel J. (West Richland, WA)

1999-01-01T23:59:59.000Z

375

Connectivity due to preferential flow controls water flow and solute transport at the hillslope scale  

E-Print Network [OSTI]

feedback, flow through the fractured bedrock, kinematic wave routing and flow through discrete preferentialConnectivity due to preferential flow controls water flow and solute transport at the hillslope the major controls on water flow and solute transport at the hillslope scale remains a major topic

Weiler, Markus

376

Rheo-optical determination of flow birefringence and flow dichroism with the pulsed laser method  

E-Print Network [OSTI]

Rheo-optical determination of flow birefringence and flow dichroism with the pulsed laser method online 29 August 2006 Rheo-optical measurements of the flow birefringence, flow dichroism systems under flow. However, the standard setup of an optical train, using phase modulation for the rheo-optical

377

Interfacial flows in corrugated microchannels: flow regimes, transitions and hysteresis  

E-Print Network [OSTI]

, 1266-1276 (2011), doi:10.1016/j.ijmultiphaseflow.2011.08.003 #12;model, microfluidics, porous media 1 of displacing oil by water in enhanced oil recovery (Marle, 1981; Lenormand et al., 1988). More recently on hy- drodynamic principles and concrete flow mechanisms. In fact, conflicting assumptions have been

Feng, James J.

378

Nuclear reactor downcomer flow deflector  

DOE Patents [OSTI]

A nuclear reactor having a coolant flow deflector secured to a reactor core barrel in line with a coolant inlet nozzle. The flow deflector redirects incoming coolant down an annulus between the core barrel and the reactor vessel. The deflector has a main body with a front side facing the fluid inlet nozzle and a rear side facing the core barrel. The rear side of the main body has at least one protrusion secured to the core barrel so that a gap exists between the rear side of the main body adjacent the protrusion and the core barrel. Preferably, the protrusion is a relief that circumscribes the rear side of the main body.

Gilmore, Charles B. (Greensburg, PA); Altman, David A. (Pittsburgh, PA); Singleton, Norman R. (Murrysville, PA)

2011-02-15T23:59:59.000Z

379

High gas flow alpha detector  

DOE Patents [OSTI]

An alpha detector for application in areas of high velocity gas flows, such as smokestacks and air vents. A plurality of spaced apart signal collectors are placed inside an enclosure, which would include smokestacks and air vents, in sufficient numbers to substantially span said enclosure so that gas ions generated within the gas flow are electrostatically captured by the signal collector means. Electrometer means and a voltage source are connected to the signal collectors to generate an electrical field between adjacent signal collectors, and to indicate a current produced through collection of the gas ions by the signal collectors. 4 figs.

Bolton, R.D.; Bounds, J.A.; Rawool-Sullivan, M.W.

1996-05-07T23:59:59.000Z

380

High gas flow alpha detector  

DOE Patents [OSTI]

An alpha detector for application in areas of high velocity gas flows, such as smokestacks and air vents. A plurality of spaced apart signal collectors are placed inside an enclosure, which would include smokestacks and air vents, in sufficient numbers to substantially span said enclosure so that gas ions generated within the gas flow are electrostatically captured by the signal collector means. Electrometer means and a voltage source are connected to the signal collectors to generate an electrical field between adjacent signal collectors, and to indicate a current produced through collection of the gas ions by the signal collectors.

Bolton, Richard D. (Los Alamos, NM); Bounds, John A. (Los Alamos, NM); Rawool-Sullivan, Mohini W. (Los Alamos, NM)

1996-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Non-Newtonian fluid flow  

E-Print Network [OSTI]

zero and unity. The Ostwald- de Waele Equation (4), commonly known as the power law, is sometimes used to describe fluid behavior of this type. The rheological equation is (4) where the parameters "k" and "n" are constant for a particular fluid... be extended to include Reynolds numbers and the type of flow determined to be laminar and/or turbulent. It is assumed that the transition from laminar to turbulent flow occurs at a Reynolds number of 2100, the numeric distribution of Reynolds numbers...

Osinski, Charles Anthony

1963-01-01T23:59:59.000Z

382

Dynamo action in flows with  

E-Print Network [OSTI]

Dynamo action in flows with cat's eyes A l i c e C o u r v o i s i e r A n d r e w G i l b e r t Y of k for R = 500 and the flow (2.4) and (2.5). nts k = 2.5 and k = 5 are highlighted. Magnetic field). In (a) k = 2.5 and we have 0.5 max Bz (with max Bz 0.6 max |B|), and in (b) k = 5 and the levels .65 max

Li, Yi

383

RAFT: A simulator for ReActive Flow and Transport of groundwater contaminants  

SciTech Connect (OSTI)

This report documents the use of the simulator RAFT for the ReActive flow and Transport of groundwater contaminants. RAFT can be used as a predictive tool in the design and analysis of laboratory and field experiments or it can be used for the estimation of model/process parameters from experiments. RAFT simulates the reactive transport of groundwater contaminants in one, two-, or three-dimensions and it can model user specified source/link configurations and arbitrary injection strategies. A suite of solvers for transport, reactions and regression are employed so that a combination of numerical methods best suited for a problem can be chosen. User specified coupled equilibrium and kinetic reaction systems can be incorporated into RAFT. RAFT is integrated with a symbolic computational language MAPLE, to automate code generation for arbitrary reaction systems. RAFT is expected to be used as a simulator for engineering design for field experiments in groundwater remediation including bioremediation, reactive barriers and redox manipulation. As an integrated tool with both the predictive ability and the ability to analyze experimental data, RAFT can help in the development of remediation technologies, from laboratory to field.

Chilakapati, A.

1995-07-01T23:59:59.000Z

384

NMR Studies of the Vanadium Spin Dynamics and Spin Structure in LiV2O4, CaV2O4, and (LixV1-x)3BO5 (x is almost equal to 0.33, 0.40)  

SciTech Connect (OSTI)

Strong electron correlation is believed to be an essential and unifying factor in diverse properties of condensed matter systems. Ground states that can arise due to electron correlation effects include Mott insulators, heavy fermion, ferromagnetism and antiferromagnetism, spin glasses, and high-temperature superconductivity. The electronic systems in transition metal oxide compounds are often highly correlated. In this thesis, the author presents experimental studies on three strongly correlated vanadium oxide compounds: LiV{sub 2}O{sub 4}, (Li{sub x}V{sub 1-x}){sub 3}BO{sub 5}, and CaV{sub 2}O{sub 4}, which have completely different ground states.

Xiaopeng Zong

2007-12-01T23:59:59.000Z

385

Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide, Lanthanide-Actinide and Lanthanum-Actinide Complexes Possessing Redox-Active Bridging Ligands  

SciTech Connect (OSTI)

A comparative examination of the electronic interactions across a series of trimetallic actinide and mixed lanthanide-actinide and lanthanum-actinide complexes is presented. Using reduced, radical terpyridyl ligands as conduits in a bridging framework to promote intramolecular metal-metal communication, studies containing structural, electrochemical, and X-ray absorption spectroscopy are presented for (C{sub 5}Me{sub 5}){sub 2}An[-N=C(Bn)(tpy-M{l_brace}C{sub 5}Me4R{r_brace}{sub 2})]{sub 2} (where An = Th{sup IV}, U{sup IV}; Bn = CH{sub 2}C{sub 6}H{sub 5}; M = La{sup III}, Sm{sup III}, Yb{sup III}, U{sup III}; R = H, Me, Et) to reveal effects dependent on the identities of the metal ions and R-groups. The electrochemical results show differences in redox energetics at the peripheral 'M' site between complexes and significant wave splitting of the metal- and ligand-based processes indicating substantial electronic interactions between multiple redox sites across the actinide-containing bridge. Most striking is the appearance of strong electronic coupling for the trimetallic Yb{sup III}-U{sup IV}-Yb{sup III}, Sm{sup III}-U{sup IV}-Sm{sup III}, and La{sup III}-U{sup IV}-La{sup III} complexes, [8]{sup -}, [9b]{sup -} and [10b]{sup -}, respectively, whose calculated comproportionation constant K{sub c} is slightly larger than that reported for the benchmark Creutz-Taube ion. X-ray absorption studies for monometallic metallocene complexes of U{sup III}, U{sup IV}, and U{sup V} reveal small but detectable energy differences in the 'white-line' feature of the uranium L{sub III}-edges consistent with these variations in nominal oxidation state. The sum of this data provides evidence of 5f/6d-orbital participation in bonding and electronic delocalization in these multimetallic f-element complexes. An improved, high-yielding synthesis of 4{prime}-cyano-2,2{prime}:6{prime},2{double_prime}-terpyridine is also reported.

Schelter, Eric J.; Wu, Ruilian; Veauthier, Jacqueline M.; Bauer, Eric D.; Booth, Corwin H.; Thomson, Robert K.; Graves, Christopher R.; John, Kevin D.; Scott, Brian L.; Thompson, Joe D.; Morris, David E.; Kiplinger, Jaqueline L.

2010-02-24T23:59:59.000Z

386

Data Flow Testing Neelam Gupta  

E-Print Network [OSTI]

Data Flow Testing Neelam Gupta The University of Arizona, Tucson, Arizona and Rajiv Gupta The University of Arizona, Tucson, Arizona Software testing techniques are designed to execute a program on a set of test cases that provide suÃ?cient coverage under some speci#12;c well-de#12;ned test coverage criterion

Gupta, Rajiv

387

Rinse trough with improved flow  

DOE Patents [OSTI]

Novel rinse troughs accomplish thorough uniform rinsing. The troughs are suitable for one or more essentially planar objects having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs provide uniform rinse fluid flow over the objects` surfaces to accomplish a more thorough rinse than prior art troughs. 5 figs.

O`Hern, T.J.; Grasser, T.W.

1998-08-11T23:59:59.000Z

388

Comments on "Microscale flow visualization"  

E-Print Network [OSTI]

We make comments on the presentation of Sinton's paper (Microfluidics and Nanofluidics {\\bf 1}: 2, 2004) about the microscale flow visualization since the effects of the roughness along the microfabricated wall upon the current macroflow visualization methods could be significant and cannot be neglected in microdomain and even nanodomain.

A. Kwang-Hua Chu

2005-10-22T23:59:59.000Z

389

Superconducting flux flow digital circuits  

DOE Patents [OSTI]

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs) are disclosed. Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics. 8 figs.

Hietala, V.M.; Martens, J.S.; Zipperian, T.E.

1995-02-14T23:59:59.000Z

390

Superconducting flux flow digital circuits  

DOE Patents [OSTI]

A NOR/inverter logic gate circuit and a flip flop circuit implemented with superconducting flux flow transistors (SFFTs). Both circuits comprise two SFFTs with feedback lines. They have extremely low power dissipation, very high switching speeds, and the ability to interface between Josephson junction superconductor circuits and conventional microelectronics.

Hietala, Vincent M. (Placitas, NM); Martens, Jon S. (Sunnyvale, CA); Zipperian, Thomas E. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

391

Flow preconditioner for electrostatic precipitator  

SciTech Connect (OSTI)

A flow preconditioner for an electrostatic precipitator removes particulate matter from a stream of polluted gas immediately after it passes through a tangential inlet at the lower end of a vertical cylindrical housing and straightens and divides the stream into laminations parallel to the axis of the housing. It comprises an annular ledge or choke ring extending inwardly from said housing above the inlet and an assembly of vanes above said ledge extending radially from the axis of the housing and angularly spaced apart. Each of said vanes has a flow receiving edge directed toward said inlet, a curved portion extending upwardly and away from said inlet, and a flat portion extending upwardly from said curved portion in a plane parallel to the housing axis. The curved portion of each vane defines a trough having a camber which gradually decreases along its span from the outer end of the vane towards the axis of the housng, together with means to vary the centrifugal flow distribution relative to the housing to render the preconditioner adjustable for various flow capacities.

Honacker, H.; Drlik, R.J.

1980-01-01T23:59:59.000Z

392

A Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow...  

Open Energy Info (EERE)

Simple Heat-Flow Quality Function And Appraisal Of Heat-Flow Measurements And Heat-Flow Estimates From The Uk Geothermal Catalogue Jump to: navigation, search OpenEI Reference...

393

Liquid metal Flow Meter - Final Report  

SciTech Connect (OSTI)

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

394

Electrochemical characterization of surface-bound redox polymers derived from 1,1'-bis(((3-(triethoxysilyl)propyl)amino)carbonyl)cobaltocenium: charge transport, anion binding, and use in photoelectrochemical hydrogen generation  

SciTech Connect (OSTI)

This paper describes the behavior of electrode-bound redox material derived from the hydrolysis of the -Si(OEt)/sub 3/ groups of 1,1'-bis(((3-(triethoxysilyl)propyl)amino)carbonyl)cobaltocenium (I). Surfaces of the conventional electrodes SnO/sub 2/ and Pt derivatized with I have a reversible electrochemical response in H/sub 2/O/electrolyte; the E/sup 0/' is pH independent at -0.62 V vs. SCE. The photoelectrochemical behavior of p-type Si photocathodes derivatized with I reveals that the photoreduction of the cobaltocenium derivative can be effected at an electrode potential approx. 500 mV more positive than on metallic electrodes, consistent with the known behavior of p-type Si photocathodes. When polymer from I is deposited on p-type Si and subsequently coated with a small amount of Rh or Pd (approx. 10/sup -7/ mol/cm/sup 2/), the photoelectrochemical generation of H/sub 2/ is possible with 632.8-nm (approx. 15 mW/cm/sup 2/) radiation and efficiencies in the vicinity of 2%. The polymer derived from I is more optically transparent and more durable at negative potentials than redox polymers derived from vilogen monomers. Potential-step measurements and steady-state-current measurements for mediated redox processes show that the charge-transport rate for the polymer derived from I is about the same as for polymers from viologen monomers. 32 references, 8 figures.

Simon, R.A.; Mallouk, T.E.; Daube, K.A.; Wrighton, M.S.

1985-09-25T23:59:59.000Z

395

Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology  

SciTech Connect (OSTI)

GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

None

2010-09-01T23:59:59.000Z

396

Characterization and Leach Testing for PUREX Cladding Waste Sludge (Group 3) and REDOX Cladding Waste Sludge (Group 4) Actual Waste Sample Composites  

SciTech Connect (OSTI)

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.(a) The testing program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual wastetesting program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. Two of the eight defined groups—plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR)—are the subjects of this report. Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, requiring caustic leaching. Characterization of the composite Group 3 and Group 4 waste samples confirmed them to be high in gibbsite. The focus of the Group 3 and 4 testing was on determining the behavior of gibbsite during caustic leaching. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

Snow, Lanee A.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Fiskum, Sandra K.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-02-13T23:59:59.000Z

397

Water and Mercury Pipe Flow Simulation in FLUENTSimulation in FLUENT  

E-Print Network [OSTI]

Water and Mercury Pipe Flow Simulation in FLUENTSimulation in FLUENT Yan Zhan, Foluso Ladeinde Stony Brook University thSep.21th , 2010 #12;OutlineOutline · Straight Pipe flowStraight Pipe flow · Curved pipe flow #12;OutlineOutline · Straight Pipe flowStraight Pipe flow · Curved pipe flow #12

McDonald, Kirk

398

Analysis of oscillating flow cooled SMA actuator  

E-Print Network [OSTI]

literature, most of the cooling mechanisms involve unidirectional forced convection. This may not be the most effective method. Oscillating flow in a channel can sometimes enhance heat transfer over a unidirectional flow. One possible explanation...

Pachalla Seshadri, Rajagopal

2005-11-01T23:59:59.000Z

399

A quasionedimensional approach for hypersonic stagnationpoint flows  

E-Print Network [OSTI]

A quasi­onedimensional approach for hypersonic stagnation­point flows Arno Klomfass 1 Lehr­ und An approximate method for the efficient calculation of stagnation streamline quantities in hypersonic flows about

400

GUI for Hypersonic flow solver Master Project  

E-Print Network [OSTI]

GUI for Hypersonic flow solver Master Project Student : Enrique Guzman concerns the design of a GUI for commanding hypersonic flow applications using CFD techniques, as well as its potential applications. These problems are quite complex, since the called hypersonic regime

Diggavi, Suhas

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Smokeless Control of Flare Steam Flow Rate  

E-Print Network [OSTI]

measurement of mass flow rate of flare gas, in spite of the hostile environment. Its use for initiating control of flare steam flow rate and the addition of molecular weight compensation, using specific gravity (relative density) measurement to achieve...

Agar, J.; Balls, B. W.

1979-01-01T23:59:59.000Z

402

Decentralized information flow control on a cluster  

E-Print Network [OSTI]

Information flow control security models can prevent programs from divulging sensitive information in unexpected ways. There has been significant work on tracking information flow between processes in the same computer at ...

Cliffer, Natan Tsvi Cohen

2007-01-01T23:59:59.000Z

403

Electromagnetically Induced Flows Michiel de Reus  

E-Print Network [OSTI]

Electromagnetically Induced Flows in Water Michiel de Reus 8 maart 2013 () Electromagnetically Conclusion and future research () Electromagnetically Induced Flows 2 / 56 #12;1 Introduction 2 Maxwell Navier Stokes equations 5 Simulations 6 Conclusion and future research () Electromagnetically Induced

Vuik, Kees

404

Numerical simulation of electrokinetically driven micro flows  

E-Print Network [OSTI]

Spectral element based numerical solvers are developed to simulate electrokinetically driven flows for micro-fluidic applications. Based on these numerical solvers, basic phenomena and devices for electrokinetic applications in micro and nano flows...

Hahm, Jungyoon

2005-11-01T23:59:59.000Z

405

gtp_flow_power_estimator.xlsx  

Broader source: Energy.gov [DOE]

This simple spreadsheet model estimates either the flow rate required to produce a specified level of power output, or the power output that can be produced from a specified flow rate.

406

Gas flow in barred potentials  

E-Print Network [OSTI]

We use a Cartesian grid to simulate the flow of gas in a barred Galactic potential and investigate the effects of varying the sound speed in the gas and the resolution of the grid. For all sound speeds and resolutions, streamlines closely follow closed orbits at large and small radii. At intermediate radii shocks arise and the streamlines shift between two families of closed orbits. The point at which the shocks appear and the streamlines shift between orbit families depends strongly on sound speed and resolution. For sufficiently large values of these two parameters, the transfer happens at the cusped orbit as hypothesised by Binney et al. over two decades ago. For sufficiently high resolutions the flow downstream of the shocks becomes unsteady. If this unsteadiness is physical, as appears to be the case, it provides a promising explanation for the asymmetry in the observed distribution of CO.

Sormani, Mattia C; Magorrian, John

2015-01-01T23:59:59.000Z

407

Zonal Flow as Pattern Formation  

E-Print Network [OSTI]

In this section, we examine the transition from statistically homogeneous turbulence to inhomogeneous turbulence with zonal flows. Statistical equations of motion can be derived from the quasilinear approximation to the Hasegawa-Mima equation. We review recent work that finds a bifurcation of these equations and shows that the emergence of zonal flows mathematically follows a standard type of pattern formation. We also show that the dispersion relation of modulational instability can be extracted from the statistical equations of motion in a certain limit. The statistical formulation can thus be thought to offer a more general perspective on growth of coherent structures, namely through instability of a full turbulent spectrum. Finally, we offer a physical perspective on the growth of large-scale structures.

Parker, Jeffrey B

2015-01-01T23:59:59.000Z

408

Flow Imaging Using MRI: Quantification and Analysis  

E-Print Network [OSTI]

&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Chair of Committee, Jim Ji Committee Members, Andrew K. Chan Deepa Kundur Yoonsuck Choe Mary P. McDougall Head of Department, Costas N... Committee: Dr. Jim Ji A complex and challenging problem in flow study is to obtain quantitative flow information in opaque systems, for example, blood flow in biological systems and flow channels in chemical reactors. In this regard, MRI is superior...

Jiraraksopakun, Yuttapong

2010-07-14T23:59:59.000Z

409

A theory for radial jet reattachment flow  

E-Print Network [OSTI]

, the velocity profile and mass entrainment are given accordrng to Goertler's t. wo- dimensional free jet theory. His analysrs of a free jet also assumes that. the turbulent eddy viscosity is constant ar ross the jet. (6) For the case of laminar flow... of total jet momentum. Laminar jet flow is approximated using Schlichting's velocity profile, whereas turbulent flow calculations are made assuming Goertler's velocity profile. Momentum integral principles are applied to the flow at reattachment...

Hadden, Lynne Loise

2012-06-07T23:59:59.000Z

410

Anisotropic collective flow of a Lorentz gas  

E-Print Network [OSTI]

Analytical results for the anisotropic collective flow of a Lorentz gas of massless particles scattering on fixed centres are presented.

Nicolas Borghini; Clement Gombeaud

2011-06-30T23:59:59.000Z

411

Building up the elliptic flow: analytical insights  

E-Print Network [OSTI]

In this paper, we present a fully analytical description of the early-stage formation of elliptic flow in relativistic viscous hydrodynamics. We first construct an elliptic deformation of Gubser flow which is a boost invariant solution of the Navier-Stokes equation with a nontrivial transverse profile. We then analytically calculate the momentum anisotropy of the flow as a function of time and discuss the connection with the empirical formula by Bhalerao {\\it et al.} regarding the viscosity dependence of elliptic flow.

Yoshitaka Hatta; Bo-Wen Xiao

2014-07-15T23:59:59.000Z

412

The Cotton tensor and the Ricci flow  

E-Print Network [OSTI]

We compute the evolution equation of the Cotton tensor under the Ricci flow of a three dimensional Riemannian manifold.

Mantegazza, Carlo

2012-01-01T23:59:59.000Z

413

Countercurrent flow absorber and desorber  

DOE Patents [OSTI]

Countercurrent flow absorber and desorber devices are provided for use in absorption cycle refrigeration systems and thermal boosting systems. The devices have increased residence time and surface area resulting in improved heat and mass transfer characteristics. The apparatuses may be incorporated into open cycle thermal boosting systems in which steam serves both as the refrigerant vapor which is supplied to the absorber section and as the supply of heat to drive the desorber section of the system. 9 figs.

Wilkinson, W.H.

1984-10-16T23:59:59.000Z

414

Countercurrent flow absorber and desorber  

DOE Patents [OSTI]

Countercurrent flow absorber and desorber devices are provided for use in absorption cycle refrigeration systems and thermal boosting systems. The devices have increased residence time and surface area resulting in improved heat and mass transfer characteristics. The apparatuses may be incorporated into open cycle thermal boosting systems in which steam serves both as the refrigerant vapor which is supplied to the absorber section and as the supply of heat to drive the desorber section of the system.

Wilkinson, William H. (Columbus, OH)

1984-01-01T23:59:59.000Z

415

Microgravity Flow Regime Transition Modeling  

E-Print Network [OSTI]

apparatus have been used in past flow regime mapping experiments such as Venturi, perforated pipe, annular, and t-junction mixers. The mixing apparatus used in a particular experiment determines the bubble size distribution at the inlet... pressure of 80 kPa was reported, however, the temperature was not. The orientation and location of the test section with respect to the aircraft are unknown. The mixing apparatus used in the experiment was a Venturi mixer. This data set does...

Shephard, Adam M.

2010-07-14T23:59:59.000Z

416

Incompressible flow over delta wings  

E-Print Network [OSTI]

&M University. vi TABLE OF CONTENTS ~Pa e INTRODUCTION REVIEW OF LITERATURE THEORY 12 NUMERICAL APPLICATIONS AND RESULTS Attached Flow Model Calculation of Pressure Distribution Fixed-Wake Model Free-Wake Model CONCLUSIONS 21 21 24 26 32 52...- lation. This theory has been expanded to include spanwise velocity effects and the leading-edge separation associated with delta wings. The numerical technique has made use of both fixed and free wakes. In the fixed-wake model the analytical results...

Nathman, James Kirwin

1976-01-01T23:59:59.000Z

417

Cyclotron resonance in plasma flow  

SciTech Connect (OSTI)

This paper is devoted to the mechanism of particle acceleration via resonant interaction with the electromagnetic circular wave propagating along the inhomogeneous background magnetic field in the presence of a plasma flow. We consider the system where the plasma flow velocity is large enough to change the direction of wave propagation in the rest frame. This system mimics a magnetic field configuration typical for inner structure of a quasi-parallel shock wave. We consider conditions of gyroresonant interaction when the force corresponding to an inhomogeneity of the background magnetic field is compensated by the Lorentz force of the wave-magnetic field. The wave-amplitude is assumed to be about 10% of the background magnetic field. We show that particles can gain energy if kv{sub sw}>?>kv{sub sw}??{sub c} where k is the wave number, v{sub sw} is a plasma flow velocity, and ? and ?{sub c} are the wave frequency and the particle gyrofrequency, respectively. This mechanism of acceleration resembles the gyrosurfing mechanism, but the effect of the electrostatic field is replaced by the effect of the magnetic field inhomogeneity.

Artemyev, A. V.; Agapitov, O. V.; Krasnoselskikh, V. V. [LPC2E/CNRS-University of Orleans, Orleans (France)] [LPC2E/CNRS-University of Orleans, Orleans (France)

2013-12-15T23:59:59.000Z

418

Structural stability of cooling flows  

E-Print Network [OSTI]

Three-dimensional hydrodynamical simulations are used to investigate the structural stability of cooling flows that are episodically heated by jets from a central AGN. The radial profile of energy deposition is controlled by (a) the power of the jets, and (b) the pre-outburst density profile. A delay in the ignition of the jets causes more powerful jets to impact on a more centrally concentrated medium. The net effect is a sufficient increase in the central concentration of energy deposition to cause the post-outburst density profile to be less centrally concentrated than that of an identical cluster in which the outburst happened earlier and was weaker. These results suggest that the density profiles of cooling flows oscillate around an attracting profile, thus explaining why cooling flows are observed to have similar density profiles. The possibility is raised that powerful FR II systems are ones in which this feedback mechanism has broken down and a runaway growth of the source parameters has occurred.

Henrik Omma; James Binney

2003-12-31T23:59:59.000Z

419

Flow Duration Curve Load Duration Curve  

E-Print Network [OSTI]

#12;Flow Duration Curve Load Duration Curve #12;1. Develop Flow Duration Curve 2. Estimate load given flow and concentration data--select appropriate conversion factors 3. Develop Load Duration Curve 4. Plot observed data with Load Duration Curve #12;What are they? How do you make one? #12;Describes

420

A quasionedimensional approach for hypersonic stagnationpoint flows  

E-Print Network [OSTI]

A quasi­onedimensional approach for hypersonic stagnation­point flows Arno Klomfass 1 Lehr­ und An approximate method for the efficient calculation of stagnation streamline quantities in hypersonic flows about­conduction coefficient [W=mK] 2 Introduction The hypersonic flow about a spacecraft entering the atmosphere at orbital

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Optimal Power Flow Incorporating Voltage Collapse Constraints  

E-Print Network [OSTI]

Optimal Power Flow Incorporating Voltage Collapse Constraints William Rosehart Claudio Ca on the current operating con- ditions is presented. Second, an Optimal Power Flow formulation that incorporates: Voltage Collapse, Optimal Power Flow, Bifur- cations. I. Introduction As open-access market principles

Cañizares, Claudio A.

422

(Preview Draft) Chapter 3. Stocks and Flows  

E-Print Network [OSTI]

the state over time. It will take some time for the flows to have their effect on the stocks, so the stocks(Preview Draft) Chapter 3. Stocks and Flows: The Building Blocks of System Dynamics Models The best way to construct a model is to start with the stocks, add the flows and then use converters to explain

Ford, Andrew

423

Progress in Grid Scale Flow Batteries  

E-Print Network [OSTI]

Progress in Grid Scale Flow Batteries IMRE GYUK, PROGRAM MANAGER ENERGY STORAGE RESEARCH, DOE Flow;LogMW Renewables (not capacity factor adjusted) 9 8 7 6 5 4 3 Wind Wind (proj) Solar PV Solar PV 2011Year #12;Flow Battery Research at PNNL and Sandia #12

424

Managing talent flow. 2006 Energy and Resources  

E-Print Network [OSTI]

Managing talent flow. 2006 Energy and Resources Talent Pulse Survey Report Consulting #12;Executive ................................................................ 13 Contents #12;1 Managing talent flow 2006 Energy and Resources Talent Pulse Survey Report 2006 strategy. 1 #12;2 Managing talent flow 2006 Energy and Resources Talent Pulse Survey Report Key findings

425

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW  

E-Print Network [OSTI]

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW J. E. Santos1, G. B. Savioli2, J. M. Carcione3, D´e, Argentina SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. I Storage of CO2). SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW ­ p. #12;Introduction. II CO2 is separated from natural

Santos, Juan

426

Setup of Particle Image Velocimetry (PIV) in Hypersonic Flows.  

E-Print Network [OSTI]

??The accuracy of numerical methods in calculating the flow of backward facing steps in turbulent hypersonic flows is limited due to a lack of flow… (more)

Anwar, Moazzam

2008-01-01T23:59:59.000Z

427

WHICH HYDRAULIC MODEL TO USE IN VERTICAL FLOW CONSTRUCTED WETLANDS?  

E-Print Network [OSTI]

WHICH HYDRAULIC MODEL TO USE IN VERTICAL FLOW CONSTRUCTED WETLANDS? Ania Morvannoua , Nicolas-equilibrium model, preferential flow path, vertical flow constructed wetlands INTRODUCTION Constructed wetlands (CWs

Paris-Sud XI, Université de

428

Self-regulating flow control device  

DOE Patents [OSTI]

A variable, self-regulating valve having a hydraulic loss coefficient proportional to a positive exponential power of the flow rate. The device includes two objects in a flow channel and structure which assures that the distance between the two objects is an increasing function of the flow rate. The range of spacing between the objects is such that the hydraulic resistance of the valve is an increasing function of the distance between the two objects so that the desired hydraulic loss coefficient as a function of flow rate is obtained without variation in the flow area.

Humphreys, Duane A. (Pittsburgh, PA)

1984-01-01T23:59:59.000Z

429

Chemical preconcentrator with integral thermal flow sensor  

DOE Patents [OSTI]

A chemical preconcentrator with integral thermal flow sensor can be used to accurately measure fluid flow rate in a microanalytical system. The thermal flow sensor can be operated in either constant temperature or constant power mode and variants thereof. The chemical preconcentrator with integral thermal flow sensor can be fabricated with the same MEMS technology as the rest of the microanlaytical system. Because of its low heat capacity, low-loss, and small size, the chemical preconcentrator with integral thermal flow sensor is fast and efficient enough to be used in battery-powered, portable microanalytical systems.

Manginell, Ronald P. (Albuquerque, NM); Frye-Mason, Gregory C. (Cedar Crest, NM)

2003-01-01T23:59:59.000Z

430

Thorium and uranium redox-active ligand complexes; reversible intramolecular electron transfer in U(dpp-BIAN)2/ U(dpp-BIAN)2(THE)  

SciTech Connect (OSTI)

Actinide complexes of the redox-active ligand dpp-BIAN{sup 2-} (dpp-BIAN = bis(2,6-diisopropylphenyl)acenaphthylene), An(dpp-BIAN){sub 2}(THF){sub n} (An = Th, n = 1; An = U, n = 0, 1) have been prepared. Solid-state magnetic and single-crystal X-ray data for U(dpp-BIAN){sub 2}(THF){sub n} show when n = 0, the complex exists in an f{sup 2}-{pi}*{sup 4} configuration; whereas an intramolecular electron transfer occurs for n = 1, resulting in an f{sup 3}-{pi}*{sup 3} ground configuration. The magnetic data also indicate that interconversion between the two forms of the complex is possible, limited only by the ability of THF vapor to penetrate the solid on cooling of the sample. Spectroscopic data indicate the complex exists solely in the f{sup 2}-{pi}*{sup 4} form in solution, evidenced by the appearance of only small changes in the electronic absorption spectra of the U(dpp-BIAN){sub 2} complex on titration with THF and by measurement of the solution magnetic moment m d{sub 8}-tetrahydrofuran using Evans method. Electrochemistry of the complexes is reported, with small differences observed in wave potentials between metals and in the presence of THF. These data represent the first example of a well-defined, reversible intramolecular electron transfer in an f-element complex and the second example of oxidation state change through dative interaction with a metal ion.

Schelter, Eric John [Los Alamos National Laboratory; Wu, Ruilian [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Batista, Enrique R [Los Alamos National Laboratory; Morris, David E [Los Alamos National Laboratory; Kiplinger, Jaqueline L [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

431

Evolution of flow disturbances in cocurrent gas-liquid flows  

SciTech Connect (OSTI)

Studies of interfacial waves in horizontal gas-liquid flows, close to neutral stability, suggest that the rate of evolution of the interface may be linked to nonlinear interactions between the fundamental mode and the subharmonic -- even if the subharmonic is linearly stable. The rate of evolution increases as the subharmonic becomes more unstable. A comparison of linear stability techniques used to predict the initial behavior of waves reveals similar predictions of growth rates and almost identical speeds between a two layer laminar Orr-Sommerfeld theory and an Orr-Sommerfeld theory when the effect of the (turbulent) gas flow enters as boundary conditions on the liquid layer. However, there is disagreement at small wavenumbers as to the point at which the growth curve crosses 0. This is a significant problem because longwave disturbances, in our case roll waves, form by growth of (initially) small amplitude waves that have frequencies which are 0.5 to 1 Hz, which is in the range where the two theories disagree about the sign of the growth rate. While nonlinear effects are probably involved in the formation of the peak (at least while its amplitude is small), the linear growth rate must play an important role when the amplitude is small.

McCready, M.J.

1992-10-01T23:59:59.000Z

432

Jet quenching and elliptic flow  

E-Print Network [OSTI]

In jet quenching, a hard QCD parton, before fragmenting into a jet of hadrons, deposits a fraction of its energy in the medium, leading to suppressed production of high-$p_T$ hadrons. Assuming that the deposited energy quickly thermalizes, we simulate the subsequent hydrodynamic evolution of the QGP fluid. Explicit simulation of Au+Au collision with and without a quenching jet indicate that elliptic flow is greatly reduced in a jet event. The result can be used to identify the jet events in heavy ion collisions.

A. K. Chaudhuri

2007-08-29T23:59:59.000Z

433

A new precision flow calorimeter  

E-Print Network [OSTI]

differences. With no sample fluid flowing, a supply of electrical power is fed to the inner calorimeter. The reference fluid is evaporated with this electrical power and the thermo-syphon system is brought to controlled steady-state conditions of pressure... calorimeter is kept cooler than the inner calorimeter for reasons discussed in chapter 4. Thus the above mentioned procedure is essential to avoid condensation in Freon@-11 vapor lines. The thermo-syphon ensures a saturated Freon&-11 vapor phase in the top...

Johnson, Mark Gezer

1984-01-01T23:59:59.000Z

434

Potential Flow Calculations of Axisymmetric Ducted Wind Turbines  

E-Print Network [OSTI]

An incompressible potential-flow vortex method has been constructed to analyze the flow field of a ducted

Widnall, Sheila

2009-09-02T23:59:59.000Z

435

Flow shop scheduling with peak power consumption constraints  

E-Print Network [OSTI]

Mar 29, 2012 ... Flow shop scheduling with peak power consumption constraints ... Keywords: scheduling, flow shop, energy, peak power consumption, integer ...

K. Fang

2012-03-29T23:59:59.000Z

436

Controlling the Delay of Small Flows in Datacenters  

E-Print Network [OSTI]

and CAPEX and ignore designs which could help reduce delay of delay sensitive flows. The flow routing

Carra, Damiano

437

Process for retarding fluid flow  

SciTech Connect (OSTI)

A process is described for retarding the flow of fluid in a subterranean formation, comprising: (a) introducing an effective amount of a gel-forming composition into a subterranean formation, the gel-forming composition being operable when gelled in the formation for retarding the flow of fluid therein. The gel-forming composition consists of: i. a first substance dissolved in water to form an aqueous solution, the first substance being selected from the group consisting of polyvivyl alcohols, and mixtures thereof, wherein the gel-forming composition contains an amount of the first substance of from about 0.5 to about 5 weight percent of the gel-forming composition, and ii. an effective amount of glutaraldehyde which is operable for forming a weakly acidic condition having a pH from about 5.5 to less than 7 in the gel-forming composition and also operable for promoting crosslinking of the first substance and glutaraldehyde and for forming a gel from the gel-forming composition under the weakly acidic condition within a period of time no greater than about 5 days without adding an acidic catalyst to the gel-forming composition to lower the pH of the gel-forming composition below about 5.5.

Sandford, B.B.; Zillmer, R.C.

1989-01-10T23:59:59.000Z

438

Proximal bodies in hypersonic flow  

SciTech Connect (OSTI)

Hypersonic flows involving two or more bodies travelling in close proximity to one another are encountered in several important situations, both natural and man-made. The present work seeks to investigate one aspect of the resulting flow problem by exploring the forces experienced by a secondary body when it is within the domain of influence of a primary body travelling at hypersonic speeds. An analytical methodology based on the blast wave analogy is developed and used to predict the secondary force coefficients for simple geometries in both two and three dimensions. When the secondary body is entirely inside the primary shocked region, the nature of the lateral force coefficient is found to depend strongly on the relative size of the two bodies. For two spheres, the methodology predicts that the secondary body will experience an exclusively attractive lateral force if the secondary diameter is larger than one-sixth the primary diameter. The analytical results are compared with those from numerical simulations and reasonable agreement is observed if an appropriate normalization for the lateral displacement is used. Results from a series of experiments in the T5 hypervelocity shock tunnel are also presented and compared with perfect-gas numerical simulations, with good agreement. A new force-measurement technique for short-duration hypersonic facilities, enabling the experimental simulation of the proximal bodies problem, is described. This technique provides two independent means of measurement, and the agreement observed between the two gives a further degree of confidence in the results obtained.

Deiterding, Ralf [ORNL; Laurence, Stuart J [California Institute of Technology, Pasadena; Hornung, Hans G [California Institute of Technology, Pasadena

2007-01-01T23:59:59.000Z

439

A constitutive law for dense granular flows  

E-Print Network [OSTI]

A continuum description of granular flows would be of considerable help in predicting natural geophysical hazards or in designing industrial processes. However, the constitutive equations for dry granular flows, which govern how the material moves under shear, are still a matter of debate. One difficulty is that grains can behave like a solid (in a sand pile), a liquid (when poured from a silo) or a gas (when strongly agitated). For the two extreme regimes, constitutive equations have been proposed based on kinetic theory for collisional rapid flows, and soil mechanics for slow plastic flows. However, the intermediate dense regime, where the granular material flows like a liquid, still lacks a unified view and has motivated many studies over the past decade. The main characteristics of granular liquids are: a yield criterion (a critical shear stress below which flow is not possible) and a complex dependence on shear rate when flowing. In this sense, granular matter shares similarities with classical visco-plastic fluids such as Bingham fluids. Here we propose a new constitutive relation for dense granular flows, inspired by this analogy and recent numerical and experimental work. We then test our three-dimensional (3D) model through experiments on granular flows on a pile between rough sidewalls, in which a complex 3D flow pattern develops. We show that, without any fitting parameter, the model gives quantitative predictions for the flow shape and velocity profiles. Our results support the idea that a simple visco-plastic approach can quantitatively capture granular flow properties, and could serve as a basic tool for modelling more complex flows in geophysical or industrial applications.

Pierre Jop; Yoël Forterre; Olivier Pouliquen

2006-12-05T23:59:59.000Z

440

Cobalt-iron red-ox behavior in nanostructured La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} cathodes  

SciTech Connect (OSTI)

Nano-sized La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) perovskite samples (prepared by a conventional acetate route and a novel acetate synthesis with HMTA additives), were tested simulating a red-ox cycle. The crystallography was studied by X-ray Powder Diffraction (XPD) and the changes in the oxidation state of the perovskite B-site were evaluated by synchrotron X-ray Absorption Near Edge Spectroscopy (XANES). After a reducing treatment, LSFC particles show the appearance of a new phase that coexists with the original one. The structural change is accompanied by a Co and Fe formal oxidation states decrease, although Fe remains always closer to 4+ and Co closer to 3+. The treatment produces a B-site valence average reduction from 3.52+ to 3.26+ and the formation of oxygen vacancies. A re-oxidation treatment under O{sub 2} rich atmosphere at 800 Degree-Sign C for 10 h shows that the change is reversible and independent of the two chemical methods used to synthesize the LSCF nano-particles. - Graphical abstract: XANES and XPD measurements in nanostructured LSCF before (black) and after (red/green) a red/ox cycle. Highlights: Black-Right-Pointing-Pointer Red-ox treatments in LSCF nano-particles cause a reversible reaction. Black-Right-Pointing-Pointer XPD analyses show that a new 'reduced' phase coexist with the oxidize one. Black-Right-Pointing-Pointer The B-site formal oxidation state decreases and the {delta} increases upon reduction. Black-Right-Pointing-Pointer Fe remains in a higher valence (closer to 4+) than Co (close to 3+). Black-Right-Pointing-Pointer The behavior seems to be independent of the synthesis method used.

Soldati, Analia L., E-mail: asoldati@cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Baque, Laura, E-mail: baque.laura@gmail.com [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Napolitano, Federico, E-mail: napolitf@ib.cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Serquis, Adriana, E-mail: aserquis@cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)

2013-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

CFD analysis of laminar oscillating flows  

SciTech Connect (OSTI)

This paper describes a numerical simulations of oscillating flow in a constricted duct and compares the results with experimental and theoretical data. The numerical simulations were performed using the computational fluid dynamics (CFD) code CFX4.2. The numerical model simulates an experimental oscillating flow facility that was designed to test the properties and characteristics of oscillating flow in tapered ducts, also known as jet pumps. Jet pumps are useful devices in thermoacoustic machinery because they produce a secondary pressure that can counteract an unwanted effect called streaming, and significantly enhance engine efficiency. The simulations revealed that CFX could accurately model velocity, shear stress and pressure variations in laminar oscillating flow. The numerical results were compared to experimental data and theoretical predictions with varying success. The least accurate numerical results were obtained when laminar flow approached transition to turbulent flow.

Booten, C. W. Charles W.); Konecni, S. (Snezana); Smith, B. L. (Barton L.); Martin, R. A. (Richard A.)

2001-01-01T23:59:59.000Z

442

Flow characteristics in underground coal gasification  

SciTech Connect (OSTI)

During the Hoe Creek No. 2 (Wyoming) underground-coal-gasification field test, researchers introduced helium pulses to characterize the flow field and to estimate the coefficients in dispersion models of the flow. Flow models such as the axial-dispersion and parallel tanks-in-series models allowed interpretation of the in situ combustion flow field from the residence time distribution of the tracer gas. A quantitative analysis of the Hoe Creek tracer response curves revealed an increasing departure from a plug-flow regime with time, which was due to the combined effects of the free and forced convection in addition to the complex nonuniformity of the flow field. The Peclet number was a function of temperature, pressure, gas recovery, and characteristic velocity, as well as the split of the gas between the parallel streams in the model.

Chang, H.L.; Himmelblau, D.M.; Edgar, T.F.

1982-01-01T23:59:59.000Z

443

Dissipation flow-frames: particle, energy, thermometer  

E-Print Network [OSTI]

We associate the following physical co-mover conditions of to different frame choices: i) Eckart: particle flow, ii) Landau-Lifshitz: energy flow, iii) J\\"uttner: moving thermometer frame. The role of fixing a flow-frame is analysed with respect to local equilibrium concentrating on dissipative currents and forces in single component relativistic fluids. The special role of a "J\\"uttner frame" is explored and contrasted to the more common Eckart and Landau-Lifshitz choices.

Ván, P

2013-01-01T23:59:59.000Z

444

Dissipation flow-frames: particle, energy, thermometer  

E-Print Network [OSTI]

We associate the following physical co-mover conditions of to different frame choices: i) Eckart: particle flow, ii) Landau-Lifshitz: energy flow, iii) J\\"uttner: moving thermometer frame. The role of fixing a flow-frame is analysed with respect to local equilibrium concentrating on dissipative currents and forces in single component relativistic fluids. The special role of a "J\\"uttner frame" is explored and contrasted to the more common Eckart and Landau-Lifshitz choices.

P. Ván; T. S. Biró

2013-05-14T23:59:59.000Z

445

SOLVENT DISPERSION AND FLOW METER CALCULATION RESULTS  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) found that the dispersion numbers for the six combinations of CSSX:Next Generation Solvent (NGS) “blend” and pure NGS versus salt solution, caustic wash, and strip aqueous solutions are all good. The dispersion numbers are indications of processability with centrifugal contactors. A comparison of solvent physical and thermal properties shows that the Intek™ solvent flow meter in the plant has a reading biased high versus calibrated flow when NGS is used, versus the standard CSSX solvent. The flow meter, calibrated for CSSX solvent, is predicted to read 2.8 gpm of NGS in a case where the true flow of NGS is 2.16 gpm.

Nash, C.; Fondeur, F.; Peters, T.

2013-06-21T23:59:59.000Z

446

Applications in MPC and Network Flows  

E-Print Network [OSTI]

This allows for improvement in communication-efficiency. We apply our algorithm to model predictive control (MPC) and to network flow problems and show, ...

2013-05-08T23:59:59.000Z

447

Radionuclide Sensors for Environmental Monitoring: From Flow...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Equilibration-Based Radionuclide Sensors for Environmental Monitoring: From Flow Injection Solid-Phase Absorptiometry to Equilibration-Based Abstract: The development...

448

Flow visualisation in inclined louvered fins  

SciTech Connect (OSTI)

In this study the flow within an interrupted fin design, the inclined louvered fin, is investigated experimentally through visualisation. The inclined louvered fin is a hybrid of the offset strip fin and standard louvered fin, aimed at improved performance at low Reynolds numbers for compact heat exchangers. The flow behaviour is studied in six geometrically different configurations over a range of Reynolds numbers and quantified using the concept of 'fin angle alignment factor'. The transition from steady laminar to unsteady flow was studied in detail. The fin geometry had a very large impact on the transitional flow behaviour, especially on vortex shedding. (author)

T'Joen, C.; De Paepe, M. [Department of Flow, Heat and Combustion Mechanics, Ghent University-UGent, Sint-Pietersnieuwstraat 41, 9000 Gent (Belgium); Jacobi, A. [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 1206 West Green Street, Urbana, IL 61801 (United States)

2009-04-15T23:59:59.000Z

449

Microsphere estimates of blood flow: Methodological considerations  

SciTech Connect (OSTI)

The microsphere technique is a standard method for measuring blood flow in experimental animals. Sporadic reports have appeared outlining the limitations of this method. In this study the authors have systematically assessed the effect of blood withdrawals for reference sampling, microsphere numbers, and anesthesia on blood flow estimates using radioactive microspheres in dogs. Experiments were performed on 18 conscious and 12 anesthetized dogs. Four blood flow estimates were performed over 120 min using 1 {times} 10{sup 6} microspheres each time. The effects of excessive numbers of microspheres pentobarbital sodium anesthesia, and replacement of volume loss for reference samples with dextran 70 were assessed. In both conscious and anesthetized dogs a progressive decrease in gastric mucosal blood flow and cardiac output was observed over 120 min. This was also observed in the pancreas in conscious dogs. The major factor responsible for these changes was the volume loss due to the reference sample withdrawals. Replacement of the withdrawn blood with dextran 70 led to stable blood flows to all organs. The injection of excessive numbers of microspheres did not modify hemodynamics to a greater extent than did the injection of 4 million microspheres. Anesthesia exerted no influence on blood flow other than raising coronary flow. The authors conclude that although blood flow to the gastric mucosa and the pancreas is sensitive to the minor hemodynamic changes associated with the microsphere technique, replacement of volume loss for reference samples ensures stable blood flow to all organs over a 120-min period.

von Ritter, C.; Hinder, R.A.; Womack, W.; Bauerfeind, P.; Fimmel, C.J.; Kvietys, P.R.; Granger, D.N.; Blum, A.L. (Univ. of the Witwatersrand, Johannesburg (South Africa) Louisianna State Univ. Medical Center, Shreveport (USA) Universitaire Vaudois (Switzerland))

1988-02-01T23:59:59.000Z

450

SEISMIC MONITORING OF CARBON DIOXIDE FLUID FLOW  

E-Print Network [OSTI]

SEISMIC MONITORING OF. CARBON DIOXIDE FLUID FLOW. J. E. Santos. 1. , G. B. Savioli. 2. , J. M. Carcione. 3. , D. Gei. 3. 1. CONICET, IGPUBA, Fac.

santos

451

Measurement of thermodynamics using gradient flow  

E-Print Network [OSTI]

We analyze bulk thermodynamics and correlation functions of the energy-momentum tensor in pure Yang-Mills gauge theory using the energy-momentum tensor defined by the gradient flow and small flow time expansion. Our results on thermodynamic observables are consistent with those obtained by the conventional integral method. The analysis of the correlation function of total energy supports the energy conservation. It is also addressed that these analyses with gradient flow require less statistics compared with the previous methods. All these results suggest that the energy-momentum tensor can be successfully defined and observed on the lattice with moderate numerical costs with the gradient flow.

Masakiyo Kitazawa; Masayuki Asakawa; Tetsuo Hatsuda; Takumi Iritani; Etsuko Itou; Hiroshi Suzuki

2014-12-15T23:59:59.000Z

452

Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...  

Broader source: Energy.gov (indexed) [DOE]

Spray, Combustion, & Emission Modeling using KH-ACT Primary Breakup Model & Detailed Chemistry Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling using KH-ACT Primary...

453

Fluid Gravity Engineering Rocket motor flow analysis  

E-Print Network [OSTI]

Fluid Gravity Engineering Capability · Rocket motor flow analysis -Internal (performance) -External young scientists/engineers Fluid Gravity Engineering Ltd #12;

Anand, Mahesh

454

Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...  

Broader source: Energy.gov (indexed) [DOE]

Technologies Program Office Program Manager: Mr. Gurpreet Singh Petrodiesel vs. Biodiesel 2 Primary Breakup Inner Nozzle Flow Influence of Physical and Chemical properties of...

455

Flow characteristics in underground coal gasification  

SciTech Connect (OSTI)

During the underground coal gasification field test at the Hoe Creek site No. 2, Wyoming, helium pulses were introduced to develop information to characterize the flow field, and to estimate the coefficients in dispersion models of the flow. Quantitative analysis of the tracer response curves shows an increasing departure from a plug flow regime with time because of the combined effects of the free and forced convection in addition to the complex non-uniformity of the flow field. The Peclet number was a function of temperature, pressure, gas recovery and characteristic velocity, as well as the split of the gas between the parallel streams in the model. 17 refs.

Chang, H.L.; Himmelblau, D.M.; Edgar, T.F.

1982-01-01T23:59:59.000Z

456

Theoretical uncertainty of orifice flow measurement  

SciTech Connect (OSTI)

Orifice meters are the most common meters used for fluid flow measurement, especially for measuring hydrocarbons. Meters are rugged, mechanically simple, and well suited for field use under extreme weather conditions. Because of their long history of use and dominance in the fluid flow measurement, their designs, installation requirements, and equations for flow rate calculation have been standardized by different organizations in the United States and internationally. These standards provide the guideline for the users to achieve accurate flow measurement. and minimize measurement uncertainty. This paper discusses different factors that contribute to the measurement inaccuracy and provide an awareness to minimize or eliminate these errors. Many factors which influence the overall measurement uncertainty are associated with the orifice meter application. Major contributors to measurement uncertainty include the predictability of flow profile, fluid properties at flowing condition, precision of empirical equation for discharge coefficient, manufacturing tolerances in meter components, and the uncertainty associated with secondary devices monitoring the static line pressure, differential pressure across the orifice plate, flowing temperature, etc. Major factors contributing to the measurement uncertainty for a thin, concentric, square-edged orifice flowmeter are as follows: (a) Tolerances in prediction of coefficient of discharge, (b) Predictability in defining the physical properties of the flowing fluid, (c) Fluid flow condition, (d) Construction tolerances in meter components, (e) Uncertainty of secondary devices/instrumentation, and (f) Data reduction and computation. Different factors under each of the above areas are discussed with precautionary measures and installation procedures to minimize or eliminate measurement uncertainty.

Husain, Z.D. [Daniel Flow Products, Inc., Houston, TX (United States)

1995-12-01T23:59:59.000Z

457

The transition from the annular to the slug flow regime in two-phase flow  

E-Print Network [OSTI]

Experiments were conducted to determine the transition from annular to semiannular flow regimes for two-phase, gas-liquid upflow in vertical tubes. The influencesof liquid flow rate, tube diameter, liquid viscosity, surface ...

Haberstroh, Robert D.

1964-01-01T23:59:59.000Z

458

Tritium flow through a non-symmetrical source. Simulation of gas flow through an injection hole  

E-Print Network [OSTI]

Tritium flow through a non-symmetrical source. Simulation of gas flow through an injection hole of source in injection rarefaction parameter µ0 viscosity of tritium at T0 Pa s 2 #12;Ll = 5074.5 Lr = 5007

Sharipov, Felix

459

Laser Sheet Light Flow Visualization For Evaluating Room Air Flows From  

E-Print Network [OSTI]

LBNL-56483 Laser Sheet Light Flow Visualization For Evaluating Room Air Flows From Registers Iain S using a Planar Laser-Induced Fluorescence (PLIF) measurement technique. Water marked with fluorescent

460

Site-Scale Saturated Zone Flow Model  

SciTech Connect (OSTI)

The purpose of this model report is to document the components of the site-scale saturated-zone flow model at Yucca Mountain, Nevada, in accordance with administrative procedure (AP)-SIII.lOQ, ''Models''. This report provides validation and confidence in the flow model that was developed for site recommendation (SR) and will be used to provide flow fields in support of the Total Systems Performance Assessment (TSPA) for the License Application. The output from this report provides the flow model used in the ''Site-Scale Saturated Zone Transport'', MDL-NBS-HS-000010 Rev 01 (BSC 2003 [162419]). The Site-Scale Saturated Zone Transport model then provides output to the SZ Transport Abstraction Model (BSC 2003 [164870]). In particular, the output from the SZ site-scale flow model is used to simulate the groundwater flow pathways and radionuclide transport to the accessible environment for use in the TSPA calculations. Since the development and calibration of the saturated-zone flow model, more data have been gathered for use in model validation and confidence building, including new water-level data from Nye County wells, single- and multiple-well hydraulic testing data, and new hydrochemistry data. In addition, a new hydrogeologic framework model (HFM), which incorporates Nye County wells lithology, also provides geologic data for corroboration and confidence in the flow model. The intended use of this work is to provide a flow model that generates flow fields to simulate radionuclide transport in saturated porous rock and alluvium under natural or forced gradient flow conditions. The flow model simulations are completed using the three-dimensional (3-D), finite-element, flow, heat, and transport computer code, FEHM Version (V) 2.20 (software tracking number (STN): 10086-2.20-00; LANL 2003 [161725]). Concurrently, process-level transport model and methodology for calculating radionuclide transport in the saturated zone at Yucca Mountain using FEHM V 2.20 are being carried out in the model report, ''Site-Scale Saturated Zone Transport'', MDL-NBS-HS-000010 Rev 01 (BSC 2003 [162419]). The velocity fields are calculated by the flow model, described herein, independent of the transport processes, and are then used as inputs to the transport model. Justification for this abstraction is presented in the model report, ''Saturated Zone Flow and Transport Model Abstraction'', MDL-NBS-HS-000021 (BSC 2003 [164870]).

G. Zyvoloski

2003-12-17T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The effects between two slotted plate flow meter under single, two, three components flow condition  

E-Print Network [OSTI]

THE INTERACTION BETWEEN A TWO SLOTTED PLATE FLOW METER UNDER ONE, TWO, OR THREE COMPONENT FLOW CONDITIONS A Thesis by SANG HYUN PARK Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 2004 Major Subject: Mechanical Engineering THE INTERACTION BETWEEN A TWO SLOTTED PLATE FLOW METER UNDER ONE, TWO, OR THREE COMPONENT FLOW...

Park, Sang Hyan

2005-02-17T23:59:59.000Z

462

Evaluation of a slotted orifice plate flow meter using horizontal two phase flow  

E-Print Network [OSTI]

EVALUATION OF A SLOTTED ORIFICE PLATE FLOW METER USING HORIZONTAL TWO PHASE FLOW A Thesis by ANITA ELENA FLORES Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 2000 Major Subject: Mechanical Engineering EVALUATION OF A SLOTTED ORIFICE PLATE FLOW METER USING HORIZONTAL TWO PHASE FLOW A Thesis by ANITA ELENA FLORES Submitted to Texas A&M University in partial fulfillment...

Flores, Anita Elena

2000-01-01T23:59:59.000Z

463

Fluctuating initial conditions and fluctuations in elliptic and triangular flow  

E-Print Network [OSTI]

In heavy ion collisions, event-by-event fluctuations in participating nucleon positions can lead to triangular flow. With fluctuating initial conditions, flow coefficients will also fluctuate. In a hydrodynamic model, we study the fluctuations in elliptic and triangular flow, due to fluctuating initial conditions. Both elliptic and triangular flow fluctuates strongly, triangular flow more strongly than the elliptic flow. Strong fluctuations greatly reduce the sensitivity of elliptic and triangular flow to viscosity.

A. K. Chaudhuri

2012-02-24T23:59:59.000Z

464

Solyndra Facts vs. Fiction: Cash Flow Modeling  

Broader source: Energy.gov [DOE]

Questions have been raised about a quote selectively pulled from an Aug. 20, 2009 email to make it look like Solyndra would run out of cash by Sept. 2011. To be clear, the analysis addressed in that email did not refer to Solyndra’s corporate cash flow, but rather the cash flow for a subsidiary of Solyndra – the “Fab 2 Project Company.

465

HYPERSONIC FLOW COMPUTATIONS ON UNSTRUCTURED MESHES  

E-Print Network [OSTI]

97--0625 HYPERSONIC FLOW COMPUTATIONS ON UNSTRUCTURED MESHES K. L. Bibb \\Lambda NASA Langley hypersonic flow over complex configurations using unstructured meshes is presented. The unstructured grid for a sphere­cone configuration at Mach numbers of 5.25 and 10.6, and a complex hypersonic re­entry vehicle

Peraire, Jaime

466

Non-Darcy flow in geothermal reservoirs  

SciTech Connect (OSTI)

The effects of non-Darcy flow laws are investigated for two geothermal reservoir types: multiphase and Hot Dry Rock (HDR). Long-term thermal behavior is emphasized as short-term pressure transient behavior is addressed in the oil field literature. Comparisons of Darcy and non-Darcy flow laws are made.

Zyvoloski, G.

1982-01-01T23:59:59.000Z

467

Scaling bounds on dissipation in turbulent flows  

E-Print Network [OSTI]

We present a new rigorous method for estimating statistical quantities in fluid dynamics such as the (average) energy dissipation rate directly from the equations of motion. The method is tested on shear flow, channel flow, Rayleigh--B\\'enard convection and porous medium convection.

Seis, Christian

2015-01-01T23:59:59.000Z

468

Integrable magnetic geodesic flows on Lie groups  

E-Print Network [OSTI]

Right-invariant geodesic flows on manifolds of Lie groups associated with 2-cocycles of corresponding Lie algebras are discussed. Algebra of integrals of motion for magnetic geodesic flows is considered and necessary and sufficient condition of integrability in quadratures is formulated. Canonic forms for 2-cocycles of all 4-dimensional Lie algebras are given and integrable cases among them are separated.

Alexey A. Magazev; Igor V. Shirokov; Yuriy Y. Yurevich

2011-11-03T23:59:59.000Z

469

Conservation Law Models for Traffic Flow  

E-Print Network [OSTI]

Conservation Law Models for Traffic Flow Alberto Bressan Mathematics Department, Penn State University http://www.math.psu.edu/bressan/ Alberto Bressan (Penn State) Scalar Conservation Laws 1 / 117 #12;Review of hyperbolic conservation laws Models of traffic flow, on a single road and on a network of roads

Bressan, Alberto

470

Flow Split Venturi, Axially-Rotated Valve  

SciTech Connect (OSTI)

The present invention provides an axially-rotated valve which permits increased flow rates and lower pressure drop (characterized by a lower loss coefficient) by using an axial eccentric split venturi with two portions where at least one portion is rotatable with respect to the other portion. The axially-rotated valve typically may be designed to avoid flow separation and/or cavitation at full flow under a variety of conditions. Similarly, the valve is designed, in some embodiments, to produce streamlined flow within the valve. An axially aligned outlet may also increase the flow efficiency. A typical cross section of the eccentric split venturi may be non-axisymmetric such as a semicircular cross section which may assist in both throttling capabilities and in maximum flow capacity using the design of the present invention. Such a design can include applications for freeze resistant axially-rotated valves and may be fully-opened and fully-closed in one-half of a complete rotation. An internal wide radius elbow typically connected to a rotatable portion of the eccentric venturi may assist in directing flow with lower friction losses. A valve actuator may actuate in an axial manner yet be uniquely located outside of the axial flow path to further reduce friction losses. A seal may be used between the two portions that may include a peripheral and diametrical seal in the same plane. A seal separator may increase the useful life of the seal between the fixed and rotatable portions.

Walrath, David E. (Laramie, WY); Lindberg, William R. (Laramie, WY); Burgess, Robert K. (Sheridan, WY); LaBelle, James (Murrieta, CA)

2000-02-22T23:59:59.000Z

471

DIFFERENTIAL EQUATIONS FOR FLOW IN RESERVOIRS By ...  

E-Print Network [OSTI]

Darcy's law for each phase with a simple differential material balance for each phase. In this first ... that the pressure declines in the direction of flow. .... lies within some closed curve C across which there is no flow, and fluid injec- tion and ...

2008-08-23T23:59:59.000Z

472

Quantitative supersonic flow visualization by hydraulic analogy  

E-Print Network [OSTI]

The hydraulic analogy, which forms the basis for the phics. current investigation, can be used to study supersonic gas flows with great ease by means of a water table. As a result of the analogy, water heights in free surface water flow correspond...

Rani, Sarma Laxminarasimha

1998-01-01T23:59:59.000Z

473

Geometric solitons of Hamiltonian flows on manifolds  

SciTech Connect (OSTI)

It is well-known that the LIE (Locally Induction Equation) admit soliton-type solutions and same soliton solutions arise from different and apparently irrelevant physical models. By comparing the solitons of LIE and Killing magnetic geodesics, we observe that these solitons are essentially decided by two families of isometries of the domain and the target space, respectively. With this insight, we propose the new concept of geometric solitons of Hamiltonian flows on manifolds, such as geometric Schrödinger flows and KdV flows for maps. Moreover, we give several examples of geometric solitons of the Schrödinger flow and geometric KdV flow, including magnetic curves as geometric Schrödinger solitons and explicit geometric KdV solitons on surfaces of revolution.

Song, Chong, E-mail: songchong@xmu.edu.cn [School of Mathematical Sciences, Xiamen University, Xiamen 361005 (China)] [School of Mathematical Sciences, Xiamen University, Xiamen 361005 (China); Sun, Xiaowei, E-mail: sunxw@cufe.edu.cn [School of Applied Mathematics, Central University of Finance and Economics, Beijing 100081 (China)] [School of Applied Mathematics, Central University of Finance and Economics, Beijing 100081 (China); Wang, Youde, E-mail: wyd@math.ac.cn [Academy of Mathematics and Systems Science, Chinese Academy of Sciences, Beijing 100190 (China)] [Academy of Mathematics and Systems Science, Chinese Academy of Sciences, Beijing 100190 (China)

2013-12-15T23:59:59.000Z

474

Flow through electrode with automated calibration  

DOE Patents [OSTI]

The present invention is an improved automated flow through electrode liquid monitoring system. The automated system has a sample inlet to a sample pump, a sample outlet from the sample pump to at least one flow through electrode with a waste port. At least one computer controls the sample pump and records data from the at least one flow through electrode for a liquid sample. The improvement relies upon (a) at least one source of a calibration sample connected to (b) an injection valve connected to said sample outlet and connected to said source, said injection valve further connected to said at least one flow through electrode, wherein said injection valve is controlled by said computer to select between said liquid sample or said calibration sample. Advantages include improved accuracy because of more frequent calibrations, no additional labor for calibration, no need to remove the flow through electrode(s), and minimal interruption of sampling.

Szecsody, James E [Richland, WA; Williams, Mark D [Richland, WA; Vermeul, Vince R [Richland, WA

2002-08-20T23:59:59.000Z

475

Rapidity Dependence of Elliptic Flow at RHIC  

E-Print Network [OSTI]

The measured elliptic flow (v2) of identified particles as a function of pT and centrality at RHIC suggests the created medium in Au+Au collisions achieves early local thermal equilibrium that is followed by hydrodynamic expansion. It is not known if the eta dependence on v2 is a general feature of elliptic flow or reflects other changes in the particle spectra in going from mid-rapidity to foward rapidities. The BRAHMS experiment provides a unique capability compared to the other RHIC experiments to measure v2 for identified particles over a wide rapidity range. From Run 4 Au+Au collision at sqrt{s_{NN}} = 200GeV, identified elliptic flow is studied using the BRAHMS spectrometers, which cover 0flow and to measure the pT-integrated flow for charged hadrons.

Erik Johnson

2006-01-04T23:59:59.000Z

476

Microstructural examination of irradiated vanadium alloys  

SciTech Connect (OSTI)

Microstructural examination results are reported for a V-5Cr-5Ti unirradiated control specimens of heat BL-63 following annealing at 1050{degrees}C, and V-4Cr-4Ti heat BL-47 irradiated in three conditions from the DHCE experiment: at 425{degrees}C to 31 dpa and 0.39 appm He/dpa, at 600{degrees}C to 18 dpa and 0.54 appm He/dpa and at 600{degrees}C to 18 dpa and 4.17 appm He/dpa.

Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States); Chung, H.M. [Argonne National Lab., IL (United States)

1997-04-01T23:59:59.000Z

477

Oxygen stabilized zirconium vanadium intermetallic compound  

DOE Patents [OSTI]

An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

1982-01-01T23:59:59.000Z

478

Oxygen stabilized zirconium-vanadium-iron alloy  

DOE Patents [OSTI]

An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

1982-01-01T23:59:59.000Z

479

Vanadium Dioxide Microactuators - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II FieldVacancy-InducedCloudPoissonVampire Power Is

480

Valve for controlling solids flow  

DOE Patents [OSTI]

A fluidized solids control valve is disclosed that is particularly well adapted for use with a flow of coal or char that includes both large particles and fines. The particles may or may not be fluidized at various times during the operation. The valve includes a tubular body that terminates in a valve seat covered by a normally closed closure plate. The valve body at the seat and the closure plate is provided with aligned longitudinal slots that receive a pivotally supported key plate. The key plate is positionable by an operator in inserted, intermediate and retracted positions respecting the longitudinal slot in the valve body. The key plate normally closes the slot within the closure plate but is shaped and aligned obliquely to the longitudinal slot within the valve body to provide progressively increasing slot openings between the inserted and retracted positions. Transfer members are provided between the operator, key plate and closure plate to move the closure plate into an open position only when the key plate is retracted from the longitudinal slot within the valve body.

Feldman, David K. (Fairlawn, NJ)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vanadium redox flow" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Cross flow electrofilter and method  

DOE Patents [OSTI]

A filter for clarifying carbonaceous liquids containing finely divided solid particles of, for instance, unreacted coal, ash and other solids discharged from a coal liquefaction process is presented. The filter includes two passageways separated by a porous filter medium. In one preferred embodiment the filter medium is of tubular shape to form the first passageway and is enclosed within an outer housing to form the second passageway within the annulus. An electrode disposed in the first passageway, for instance along the tube axis, is connected to a source of high voltage for establishing an electric field between the electrode and the filter medium. Slurry feed flows through the first passageway tangentially to the surfaces of the filter medium and the electrode. Particles from the feed slurry are attracted to the electrode within the first passageway to prevent plugging of the porous filter medium while carbonaceous liquid filters into the second passageway for withdrawal. Concentrated slurry is discharged from the first passageway at an end opposite to the feed slurry inlet. Means are also provided for the addition of diluent and a surfactant into the slurry to control relative permittivity and the electrophoretic mobility of the particles.

Gidaspow, Dimitri (Northbrook, IL); Lee, Chang H. (Chicago, IL); Wasan, Darsh T. (Westmont, IL)

1981-01-01T23:59:59.000Z

482

Department of Chemical Engineering Thermal and Flow Engineering Laboratory  

E-Print Network [OSTI]

Aug.2013 Department of Chemical Engineering Thermal and Flow Engineering Laboratory Ron Zevenhoven.1 Fluid statics 6.2 Fluid dynamics: viscosity, laminar / turbulent flow, boundary layer 6.3 Fluid dynamics: internal flows / tube flows 6.4 Fluid dynamics: pressure drop & energy dissipation in tube systems 6.5 Flow

Zevenhoven, Ron

483

Department of Chemical Engineering Thermal and Flow Engineering Laboratory  

E-Print Network [OSTI]

August 12 Department of Chemical Engineering Thermal and Flow Engineering Laboratory Ron Zevenhoven.1 Fluid statics 6.2 Fluid dynamics: viscosity, laminar / turbulent flow, boundary layer 6.3 Fluid dynamics: internal flows / tube flows 6.4 Fluid dynamics: pressure drop & energy dissipation in tube systems 6.5 Flow

Zevenhoven, Ron

484

Classification of Two-Phase Flow Patterns by Ultrasonic Sensing  

E-Print Network [OSTI]

in addition to several other factors such as the bulk flow rate, fluid properties, and flow boundary conditions [1]. Characterization of flow patterns and identification of the associ- ated flow regimes instrumentation, both for void fraction identification and flow pattern classification. High-speed photog- raphy

Ray, Asok

485

Microgravity flow pattern identification using void fraction signals  

E-Print Network [OSTI]

Knowledge of the two-phase flow state is fundamental for two-phase flow system design and operation. In traditional two-phase flow studies, the flow regime refers to the physical location of the gas and liquid in a conduit. Flow configuration...

Valota, Luca

2005-08-29T23:59:59.000Z

486

Online Supplement Appendix Flow Anatomy of the TCPC Pathways  

E-Print Network [OSTI]

narrowings that dissipate little power at baseline flows may be sources of significant power loss at increased flows, 2) flow collision between SVC and IVC flows can be a significant source of power loss and usually increases significantly with increasing power loss, 3) increased skewing of the IVC flow toward

Pekkan, Kerem