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Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Design and Simulation of Passive Thermal Management System for Lithium-ion Battery Packs on an Unmanned Ground Vehicle.  

E-Print Network [OSTI]

?? The transient thermal response of a 15-cell, 48 volt, lithium-ion battery pack for an unmanned ground vehicle was simulated with ANSYS Fluent. Heat generation… (more)

Parsons, Kevin Kenneth

2012-01-01T23:59:59.000Z

2

Efficient Lithium-Ion Battery Pack Electro-Thermal Simulation  

Science Journals Connector (OSTI)

A methodology to derive a computational efficient electro-thermal battery pack model is showed. It is taken ... up of three orders of magnitude for the thermal part. The electrical battery model is implemented an...

L. Kostetzer

2014-01-01T23:59:59.000Z

3

Transient modeling and validation of lithium ion battery pack with air cooled thermal management system for electric vehicles  

Science Journals Connector (OSTI)

A transient numerical model of a lithium ion battery (LiB) pack with air cooled thermal management system is developed and validated for electric vehicle applications. In the battery model, the open circuit volta...

G. Y. Cho; J. W. Choi; J. H. Park; S. W. Cha

2014-08-01T23:59:59.000Z

4

Thermal analysis and two-directional air flow thermal management for lithium-ion battery pack  

Science Journals Connector (OSTI)

Abstract Thermal management is a routine but crucial strategy to ensure thermal stability and long-term durability of the lithium-ion batteries. An air-flow-integrated thermal management system is designed in the present study to dissipate heat generation and uniformize the distribution of temperature in the lithium-ion batteries. The system contains of two types of air ducts with independent intake channels and fans. One is to cool the batteries through the regular channel, and the other minimizes the heat accumulations in the middle pack of batteries through jet cooling. A three-dimensional anisotropic heat transfer model is developed to describe the thermal behavior of the lithium-ion batteries with the integration of heat generation theory, and validated through both simulations and experiments. Moreover, the simulations and experiments show that the maximum temperature can be decreased to 33.1 °C through the new thermal management system in comparison with 42.3 °C through the traditional ones, and temperature uniformity of the lithium-ion battery packs is enhanced, significantly.

Kuahai Yu; Xi Yang; Yongzhou Cheng; Changhao Li

2014-01-01T23:59:59.000Z

5

Thermal Analysis of Lithium-Ion Battery Packs and Thermal Management Solutions.  

E-Print Network [OSTI]

??Lithium ion (Li-ion) batteries have been gaining recognition as the primary technology for energy storage in motive applications due to their improved specific energy densities,… (more)

Bhatia, Padampat Chander

2013-01-01T23:59:59.000Z

6

Pairing in dense lithium  

Science Journals Connector (OSTI)

... of valence electrons. Here we report the results of first-principles calculations, indicating that lithium, the band structure of which is largely free-electron-like at ordinary densities, does ... b.c.c.) becomes unstable to a pairing of the ions. Once paired, lithium possesses an even number of electrons per primitive cell which, although not sufficient, is ...

J. B. Neaton; N. W. Ashcroft

1999-07-08T23:59:59.000Z

7

Development of Production-Intent Plug-In Hybrid Vehicle Using Advanced Lithium-Ion Battery Packs with Deployment to a Demonstration Fleet  

SciTech Connect (OSTI)

The primary goal of this project was to speed the development of one of the first commercially available, OEM-produced plug-in hybrid electric vehicles (PHEV). The performance of the PHEV was expected to double the fuel economy of the conventional hybrid version. This vehicle program incorporated a number of advanced technologies, including advanced lithium-ion battery packs and an E85-capable flex-fuel engine. The project developed, fully integrated, and validated plug-in specific systems and controls by using GM’s Global Vehicle Development Process (GVDP) for production vehicles. Engineering Development related activities included the build of mule vehicles and integration vehicles for Phases I & II of the project. Performance data for these vehicles was shared with the U.S. Department of Energy (DOE). The deployment of many of these vehicles was restricted to internal use at GM sites or restricted to assigned GM drivers. Phase III of the project captured the first half or Alpha phase of the Engineering tasks for the development of a new thermal management design for a second generation battery module. The project spanned five years. It included six on-site technical reviews with representatives from the DOE. One unique aspect of the GM/DOE collaborative project was the involvement of the DOE throughout the OEM vehicle development process. The DOE gained an understanding of how an OEM develops vehicle efficiency and FE performance, while balancing many other vehicle performance attributes to provide customers well balanced and fuel efficient vehicles that are exciting to drive. Many vehicle content and performance trade-offs were encountered throughout the vehicle development process to achieve product cost and performance targets for both the OEM and end customer. The project team completed two sets of PHEV development vehicles with fully integrated PHEV systems. Over 50 development vehicles were built and operated for over 180,000 development miles. The team also completed four GM engineering development Buy-Off rides/milestones. The project included numerous engineering vehicle and systems development trips including extreme hot, cold and altitude exposure. The final fuel economy performance demonstrated met the objectives of the PHEV collaborative GM/DOE project. Charge depletion fuel economy of twice that of the non-PHEV model was demonstrated. The project team also designed, developed and tested a high voltage battery module concept that appears to be feasible from a manufacturability, cost and performance standpoint. The project provided important product development and knowledge as well as technological learnings and advancements that include multiple U.S. patent applications.

No, author

2013-09-29T23:59:59.000Z

8

Conductive lithium storage electrode  

DOE Patents [OSTI]

A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001lithium phosphate that can intercalate lithium or hydrogen. The compound can be used in an electrochemical device including electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

Chiang, Yet-Ming (Framingham, MA); Chung, Sung-Yoon (Incheon, KR); Bloking, Jason T. (Mountain View, CA); Andersson, Anna M. (Vasteras, SE)

2012-04-03T23:59:59.000Z

9

Conductive lithium storage electrode  

DOE Patents [OSTI]

A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z(A.sub.1-aM''.sub.a).s- ub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001lithium phosphate that can intercalate lithium or hydrogen. The compound can be used in an electrochemical device including electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

Chiang, Yet-Ming (Framingham, MA); Chung, Sung-Yoon (Seoul, KR); Bloking, Jason T. (Cambridge, MA); Andersson, Anna M. (Uppsala, SE)

2008-03-18T23:59:59.000Z

10

Manufacturing of Protected Lithium Electrodes for Advanced Lithium...  

Broader source: Energy.gov (indexed) [DOE]

Lithium Electrodes for Advanced Lithium-Air, Lithium-Water, and Lithium-Sulfur Batteries, April 2013 Manufacturing of Protected Lithium Electrodes for Advanced Lithium-Air,...

11

Thermal Behavior and Modeling of Lithium-Ion Cuboid Battery  

Science Journals Connector (OSTI)

Thermal behaviour and model are important items should be considered when designing a battery pack cooling system. Lithium-ion battery thermal behaviour and modelling method are investigated in this paper. The te...

Hongjie Wu; Shifei Yuan

2013-01-01T23:59:59.000Z

12

Hydrogen, lithium, and lithium hydride production  

DOE Patents [OSTI]

A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

2014-03-25T23:59:59.000Z

13

Professional Training Information Pack  

E-Print Network [OSTI]

Intending Professional Training Students Year 2 Information Pack #12;- 1 - Applying for a Professional Training Placement To be allowed to do the Professional Training you must have enrolled on one must talk to Dr J. M. Thompson immediately. General introduction to professional training Students

Davies, Christopher

14

Simplified Heat Generation Model for Lithium ion battery used in Electric Vehicle  

Science Journals Connector (OSTI)

It is known that temperature variations inside a battery may greatly affect its performance, life, and reliability. In an effort to gain a better understanding of the heat generation in Lithium ion batteries, a simple heat generation models were constructed in order to predict the thermal behaviour of a battery pack. The Lithium ion battery presents in this paper is Lithium Iron Phosphate (LiFePO4). The results show that the model can be viewed as an acceptable approximation for the variation of the battery pack temperature at a continuous discharge current from data provided by the manufacturer and literature.

Nur Hazima Faezaa Ismail; Siti Fauziah Toha; Nor Aziah Mohd Azubir; Nizam Hanis Md Ishak; Mohd Khair Hassan; Babul Salam Ksm Ibrahim

2013-01-01T23:59:59.000Z

15

Ball Packings with Periodic Constraints  

Science Journals Connector (OSTI)

We call a periodic ball packing in $$d$$d-dimensional Euclidean space periodically (resp. strictly) jammed with respect to a period lattice $$\\varLambda $$¿ if there are no nontrivial motions of the balls that preserve $$\\varLambda $$¿ (resp. that maintain ... Keywords: 52C17, Ball packings, Jamming, Periodic packings, Rigidity, Tensegrities

Robert Connelly, Jeffrey D. Shen, Alexander D. Smith

2014-12-01T23:59:59.000Z

16

Packed Bed Combustion: An Overview  

E-Print Network [OSTI]

;Packed Bed Combustion - University of Ottawa - CICS 2005 fuel fuel feed air products air fuel Retort) products Underfeed Combustion fuel feed air #12;Packed Bed Combustion - University of Ottawa - CICS 2005 required #12;Packed Bed Combustion - University of Ottawa - CICS 2005 Overfeed Bed fuel motion products air

Hallett, William L.H.

17

An Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 Nanotube Arrays  

E-Print Network [OSTI]

is based on a silicon solar panel and a solid-state lithium battery as the two independent parts, whichAn Integrated Power Pack of Dye-Sensitized Solar Cell and Li Battery Based on Double-Sided TiO2 harvest and storage processes. This power pack incorporates a series-wound dye- sensitized solar cell

Wang, Zhong L.

18

Lithium Iron Phosphate Composites for Lithium Batteries | Argonne...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lithium Iron Phosphate Composites for Lithium Batteries Technology available for licensing: Inexpensive, electrochemically active phosphate compounds with high functionality for...

19

Atoms in Valence Bond. Method, implementation and application.  

E-Print Network [OSTI]

??The Atoms in Valence Bond (AiVB) approach is presented. The main goal was to develop a new and innovative approach, within the existing Valence Bond… (more)

Zielinski, M.L.

2012-01-01T23:59:59.000Z

20

Lithium Insertion into Anatase Nanotubes  

Science Journals Connector (OSTI)

Lithium Insertion into Anatase Nanotubes ... Improving the Performance of Titania Nanotube Battery Materials by Surface Modification with Lithium Phosphate ...

V. Gentili; S. Brutti; L.J. Hardwick; A.R. Armstrong; S. Panero; P.G. Bruce

2012-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

What to Pack for Mars  

E-Print Network [OSTI]

De Weck, O.L. “What to Pack for Mars.” Spectrum, IEEE 46.6 (2009): 39. © 2009 Institute of Electrical and Electronics Engineers

De Weck, Olivier L.

22

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

Raistrick, I.D.; Poris, J.; Huggins, R.A.

1980-07-18T23:59:59.000Z

23

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1982-02-09T23:59:59.000Z

24

The purpose of this pack This pack presents the Forestry  

E-Print Network [OSTI]

staff, so that they are able to communicate the Forestry Commission's key climate change messages questions about climate change, and the answers identified clear areas that required more communication in tackling climate change. Who is this pack aimed at? The pack is primarily aimed at Forestry Commission

25

Convex Optimization Course Welcome Pack  

E-Print Network [OSTI]

1 NATCOR Convex Optimization Course 23rd ­ 27th June 2014 Welcome Pack This pack contains. ABSTRACT Convex optimization is the fundamental process of optimal decision-making. Although mathematically restrictive, many practical problems may be modelled directly as convex optimization problems. Convex

Hall, Julian

26

Lithium Supply Grows  

Science Journals Connector (OSTI)

Military-requirements are of course classified, but there is general speculation that lithium is required for the thermonuclear reactions. ...

1955-11-21T23:59:59.000Z

27

Manufacturing of Protected Lithium Electrodes for Advanced Batteries  

Broader source: Energy.gov [DOE]

Manufacturing of Protected Lithium Electrodes for Advanced Lithium-Air, Lithium-Water, and Lithium-Sulfur Batteries

28

Valve stem and packing assembly  

DOE Patents [OSTI]

A valve stem and packing assembly is provided in which a rotatable valve stem includes a first tractrix surface for sliding contact with a stem packing and also includes a second tractrix surface for sliding contact with a bonnet. Force is applied by means of a spring, gland flange, and gland on the stem packing so the stem packing seals to the valve stem and bonnet. This configuration serves to create and maintain a reliable seal between the stem packing and the valve stem. The bonnet includes a second complementary tractrix surface for contacting the second sliding tractrix surface, the combination serving as a journal bearing for the entire valve stem and packing assembly. The journal bearing so configured is known as a Schiele's pivot. The Schiele's pivot also serves to maintain proper alignment of the valve stem with respect to the bonnet. Vertical wear between the surfaces of the Schiele's pivot is uniform at all points of contact between the second sliding tractrix surface and the second complementary tractrix surface of a bonnet. The valve stem is connected to a valve plug by means of a slip joint. The valve is opened and closed by rotating the valve stem. The slip joint compensates for wear on the Schiele's pivot and on the valve plug. A ledge is provided on the valve bonnet for the retaining nut to bear against. The ledge prevents over tightening of the retaining nut and the resulting excessive friction between stem and stem packing. 2 figures.

Wordin, J.J.

1991-09-03T23:59:59.000Z

29

Valve stem and packing assembly  

DOE Patents [OSTI]

A valve stem and packing assembly is provided in which a rotatable valve stem includes a first tractrix surface for sliding contact with a stem packing and also includes a second tractrix surface for sliding contact with a bonnet. Force is applied by means of a spring, gland flange, and gland on the stem packing so the stem packing seals to the valve stem and bonnet. This configuration serves to create and maintain a reliable seal between the stem packing and the valve stem. The bonnet includes a second complementary tractrix surface for contacting the second sliding tractrix surface, the combination serving as a journal bearing for the entire valve stem and packing assembly. The journal bearing so configured is known as a Schiele's pivot. The Schiele's pivot also serves to maintain proper alignment of the valve stem with respect to the bonnet. Vertical wear between the surfaces of the Schiele's pivot is uniform at all points of contact between the second sliding tractrix surface and the second complementary tractrix surface of a bonnet. The valve stem is connected to a valve plug by means of a slip joint. The valve is opened and closed by rotating the valve stem. The slip joint compensates for wear on the Schiele's pivot and on the valve plug. A ledge is provided on the valve bonnet for the retaining nut to bear against. The ledge prevents overtightening of the retaining nut and the resulting excessive friction between stem and stem packing.

Wordin, John J. (Bingham County, ID)

1991-01-01T23:59:59.000Z

30

Ball Packings with Periodic Constraints  

E-Print Network [OSTI]

We call a periodic ball packing in d-dimensional Euclidean space periodically (strictly) jammed with respect to a period lattice if there are no nontrivial motions of the balls that preserve the period (that maintain some period with smaller or equal volume). In particular, we call a packing consistently periodically (strictly) jammed if it is periodically (strictly) jammed on every one of its periods. After extending a well-known bar framework and stress condition to strict jamming, we prove that a packing with period Lambda is consistently strictly jammed if and only if it is strictly jammed with respect to Lambda and consistently periodically jammed. We next extend a result about rigid unit mode spectra in crystallography to characterize periodic jamming on sublattices. After that, we prove that there are finitely many strictly jammed packings of m unit balls and other similar results. An interesting example shows that the size of the first sublattice on which a packing is first periodically unjammed is not bounded. Finally, we find an example of a consistently periodically jammed packing of low density \\delta = \\frac{4 \\pi}{6 \\sqrt{3} + 11} + \\epsilon ~ 0.59, where \\epsilon is an arbitrarily small positive number. Throughout the paper, the statements for the closely related notions of periodic infinitesimal rigidity and affine infinitesimal rigidity for tensegrity frameworks are also given.

Robert Connelly; Jeffrey D. Shen; Alexander D. Smith

2013-01-04T23:59:59.000Z

31

Argonne, Western Lithium to develop lithium carbonate for multiple...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laboratory as a step toward the commercialization of lithium carbonate from the Company's Kings Valley Lithium Project located in Humboldt County, Nevada, USA. Under the agreement,...

32

Photo-induced Valence Tautomerism in Co Complexes  

Science Journals Connector (OSTI)

Photo-induced Valence Tautomerism in Co Complexes ... His research interests include the development of photomagnets and phototunable photonic crystals and the design of supramolecules exhibiting photo-bistability. ... Photo-induced Valence Tautomerism in Mononuclear Compounds ...

Osamu Sato; Aili Cui; Ryotaro Matsuda; Jun Tao; Shinya Hayami

2007-04-11T23:59:59.000Z

33

Logical Effort of Higher Valency Adders David Harris  

E-Print Network [OSTI]

Logical Effort of Higher Valency Adders David Harris Harvey Mudd College 301 E. Twelfth St. Claremont, CA 91711 David_Harris@hmc.edu Abstract ­ Higher valency parallel prefix adders reduce the number

Harris, David Money

34

Precision Calculations of Atoms with Few Valence Electrons  

E-Print Network [OSTI]

Precision Calculations of Atoms with Few Valence Electrons M. G. KOZLOV Petersburg Nuclear Physics words: atoms; effective Hamiltonian; pair equations; precision calculation; valence electron for valence electrons of an atom. The low-energy part of atomic spectrum is found by solving the eigenvalue

Kozlov, Mikhail G

35

Precision Calculations of Atoms with Few Valence Electrons  

E-Print Network [OSTI]

Precision Calculations of Atoms with Few Valence Electrons M. G. KOZLOV Petersburg Nuclear Physics for valence electrons of an atom. The low-energy part of atomic spectrum is found by solving the eigenvalue­valence correlations. We tested this method on a toy model of a four-electron atom with the core 1s2 . The spectrum

Kozlov, Mikhail G

36

Cylinder valve packing nut studies  

SciTech Connect (OSTI)

The design, manufacture, and use of cylinder valve packing nuts have been studied to improve their resistance to failure from stress corrosion cracking. Stress frozen photoelastic models have been analyzed to measure the stress concentrations at observed points of failure. The load effects induced by assembly torque and thermal expansion of stem packing were observed by strain gaging nuts. The effects of finishing operations and heat treatment were studied by the strain gage hole boring and X-ray methods. Modifications of manufacturing and operation practices are reducing the frequency of stress corrosion failures.

Blue, S.C. [Martin Marietta Energy Systems, Inc., Paducah, KY (United States)

1991-12-31T23:59:59.000Z

37

Cathode material for lithium batteries  

DOE Patents [OSTI]

A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

Park, Sang-Ho; Amine, Khalil

2013-07-23T23:59:59.000Z

38

American Lithium Energy Corp | Open Energy Information  

Open Energy Info (EERE)

Lithium Energy Corp Jump to: navigation, search Name: American Lithium Energy Corp Place: San Marcos, California Zip: 92069 Product: California-based developer of lithium ion...

39

Students & Mental Health Resource Pack  

E-Print Network [OSTI]

Students & Mental Health Resource Pack Produced by - www.rethink.org/at-ease/ SHEFFIELD EARLY://clik.to/eis NORTH EAST SHEFFIELD Northlands Community Health Centre, Southey Hill, Sheffield S5 8BE Tel: 0114 is severe mental illness? 1.4 Treatment and prognosis What is mental health awareness? 2.1 Introduction 2

Stevenson, Mark

40

Lithium metal oxide electrodes for lithium batteries  

DOE Patents [OSTI]

An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Electrocatalysts for Nonaqueous Lithium–Air Batteries:...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges, and Perspective. Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges,...

42

Lithium Ion Accomplishments  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lithium ion Battery Commercialization Lithium ion Battery Commercialization Johnson Controls-Saft Advanced Power Solutions, of Milwaukee, Wisconsin: Johnson Controls-Saft (JCS) will supply lithium-ion batteries to Mercedes for their S Class Hybrid to be introduced in October 2009. Technology developed with DOE support (the VL6P cell) will be used in the S Class battery. In May 2006, the Johnson Controls-Saft Joint Venture was awarded a 24 month $14.4 million contract by the DOE/USABC to develop a 40kW Li ion HEV battery system offering improved safety, low temperature performance, and cost. JCS has reported a 40% cost reduction of the 40kW system being developed in their DOE/USABC contract while maintaining performance. Lithium Ion Battery Material Commercialization Argonne National Laboratory has licensed cathode materials and associated processing

43

Solid-state lithium battery  

DOE Patents [OSTI]

The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

2014-11-04T23:59:59.000Z

44

LITHIUM LITERATURE REVIEW: LITHIUM'S PROPERTIES AND INTERACTIONS  

Office of Scientific and Technical Information (OSTI)

HEDL-TME 78-15 HEDL-TME 78-15 uc-20 LITHIUM LITERATURE REVIEW: LITHIUM'S PROPERTIES AND INTERACTIONS Hanf ord Engineering Development Laboratory -~ - - , . .. . D.W. Jeppson J.L. Ballif W.W. Yuan B.E. Chou - - - . - . - -- r - N O T l C E n ~ h u mpon w prepared as an account of work iponrored by the United States Government. Neither the Unitcd States nor the United Stater Department of Energy. nor any of their employees, nor any of then contractor^, subcontractors. or their employees, maker any warranty, cxprcu or Implied. or anumcs any legal liability or rcrponabllity for the accuracy. cornplctcncs or uvfulnes of any information. apparatus, product or p r o a s ditclorcd. or rcpments that its u s would not infringe pnvatcly owned nghts. April 1978 HANFORD ENGINEERING DEVELOPMENT LABORATORY

45

Quantum Monte Carlo methods and lithium cluster properties  

SciTech Connect (OSTI)

Properties of small lithium clusters with sizes ranging from n = 1 to 5 atoms were investigated using quantum Monte Carlo (QMC) methods. Cluster geometries were found from complete active space self consistent field (CASSCF) calculations. A detailed development of the QMC method leading to the variational QMC (V-QMC) and diffusion QMC (D-QMC) methods is shown. The many-body aspect of electron correlation is introduced into the QMC importance sampling electron-electron correlation functions by using density dependent parameters, and are shown to increase the amount of correlation energy obtained in V-QMC calculations. A detailed analysis of D-QMC time-step bias is made and is found to be at least linear with respect to the time-step. The D-QMC calculations determined the lithium cluster ionization potentials to be 0.1982(14) [0.1981], 0.1895(9) [0.1874(4)], 0.1530(34) [0.1599(73)], 0.1664(37) [0.1724(110)], 0.1613(43) [0.1675(110)] Hartrees for lithium clusters n = 1 through 5, respectively; in good agreement with experimental results shown in the brackets. Also, the binding energies per atom was computed to be 0.0177(8) [0.0203(12)], 0.0188(10) [0.0220(21)], 0.0247(8) [0.0310(12)], 0.0253(8) [0.0351(8)] Hartrees for lithium clusters n = 2 through 5, respectively. The lithium cluster one-electron density is shown to have charge concentrations corresponding to nonnuclear attractors. The overall shape of the electronic charge density also bears a remarkable similarity with the anisotropic harmonic oscillator model shape for the given number of valence electrons.

Owen, R.K.

1990-12-01T23:59:59.000Z

46

Phenomenological theory of a single domain wall in uniaxial trigonal ferroelectrics: Lithium niobate and lithium tantalate  

E-Print Network [OSTI]

Phenomenological theory of a single domain wall in uniaxial trigonal ferroelectrics: Lithium niobate and lithium tantalate David A. Scrymgeour and Venkatraman Gopalan Department of Materials Science, lithium niobate and lithium tantalate. The contributions to the domain- wall energy from polarization

Gopalan, Venkatraman

47

Princeton Plasma Physics Lab - Lithium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lithium Nearly everybody knows about lithium Nearly everybody knows about lithium - a light, silvery alkali metal - used in rechargeable batteries powering everything from laptops to hybrid cars. What may not be so well known is the fact that researchers hoping to harness the energy released in fusion reactions also have used lithium to coat the walls of donut-shaped tokamak reactors. Lithium, it turns out, may help the plasmas fueling fusion reactions to retain heat for longer periods of time. This could improve the chances of producing useful energy from fusion. en COLLOQUIUM: The Lithium Tokamak eXperiment (LTX) http://www.pppl.gov/events/colloquium-lithium-tokamak-experiment-ltx

48

Enhanced EP halftones with hexagonal dot packing  

E-Print Network [OSTI]

Enhanced EP halftones with hexagonal dot packing Tomasz J. Cholewo, Steve Weed, Brian Cooper advantages for electropho- tographic (EP) printing over conventional dot placement on a square grid [1] reported that hexagonal dot packing could have some unique benefits for EP printing. These were

Cholewo, Tomasz

49

Lithium ion conducting electrolytes  

DOE Patents [OSTI]

A liquid, predominantly lithium-conducting, ionic electrolyte is described having exceptionally high conductivity at temperatures of 100 C or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH{sub 3}CN), succinnonitrile (CH{sub 2}CN){sub 2}, and tetraglyme (CH{sub 3}--O--CH{sub 2}--CH{sub 2}--O--){sub 2} (or like solvents) solvated to a Mg{sup +2} cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100 C conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone. 2 figs.

Angell, C.A.; Liu, C.

1996-04-09T23:59:59.000Z

50

Side Reactions in Lithium-Ion Batteries  

E-Print Network [OSTI]

even with excess negative capacity, lithium can deposit ifdeposits lithium and reaches cutoff sooner. electrode excessexcess by 10%, an extension of about 0.4 mm is sufficient to prevent the onset of lithium

Tang, Maureen Han-Mei

2012-01-01T23:59:59.000Z

51

Mixed valence of iron in minerals with cation clusters  

Science Journals Connector (OSTI)

The valence and distribution of iron in vivianite, lazulite, babingtonite, rockbridgeite, acmite, aegirine-augite, hedenbergite,...2+ and Fe3+ in neighboring sites through common edges or faces is observed in all...

Georg Amthauer; George R. Rossman

1984-06-01T23:59:59.000Z

52

Polymer Electrolytes for Advanced Lithium Batteries | Department...  

Broader source: Energy.gov (indexed) [DOE]

Advanced Lithium Batteries Polymer Electrolytes for Advanced Lithium Batteries 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

53

Lithium Metal Anodes for Rechargeable Batteries. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Metal Anodes for Rechargeable Batteries. Lithium Metal Anodes for Rechargeable Batteries. Abstract: Rechargeable lithium metal batteries have much higher energy density than those...

54

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

Gabano, Ed. , Lithium Batteries, Academic Press, New York,K. V. Kordesch, "Primary Batteries 1951-1976," J. Elec- n ~.Rechargeable Lithium Batteries," J. Electrochem. Soc. , [20

Doyle, C.M.

2010-01-01T23:59:59.000Z

55

EERE Partner Testimonials - Phil Roberts, California Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phil Roberts, California Lithium Battery (CalBattery) EERE Partner Testimonials - Phil Roberts, California Lithium Battery (CalBattery) Addthis Text Version The words "Office of...

56

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

Newman, "Thermal Modeling of the LithiumIPolymer Battery I.J. Newman, "Thermal Modeling of the LithiumIPolymer Battery

Doyle, C.M.

2010-01-01T23:59:59.000Z

57

Washington: Graphene Nanostructures for Lithium Batteries Recieves...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Washington: Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award Washington: Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award February...

58

Electrochemical Studies of Packed Iron Powder Electrodes: Effects...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Packed Iron Powder Electrodes: Effects of Common Constituents of Natural Waters on Corrosion Electrochemical Studies of Packed Iron Powder Electrodes: Effects of Common...

59

EV Everywhere Batteries Workshop - Pack Design and Optimization...  

Broader source: Energy.gov (indexed) [DOE]

Pack Design and Optimization Breakout Session Report EV Everywhere Batteries Workshop - Pack Design and Optimization Breakout Session Report Breakout session presentation for the...

60

Lithium-based electrochromic mirrors  

E-Print Network [OSTI]

LITHIUM-BASED ELECTROCHROMIC MIRRORS Thomas J. Richardson*with pure antimony films. Electrochromic cycling speed andand silver. INTRODUCTION Electrochromic devices that exhibit

Richardson, Thomas J.; Slack, Jonathan L.

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

62

Groundwater well with reactive filter pack  

DOE Patents [OSTI]

A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

1998-09-08T23:59:59.000Z

63

A High-Performance PHEV Battery Pack  

Broader source: Energy.gov (indexed) [DOE]

cooling system we have developed in our previous program with respect to mass, volume, cost and power demand. Deliver cells and battery packs to USABC for testing. Tasks OEM...

64

SECONDARY BATTERIES – LITHIUM RECHARGEABLE SYSTEMS – LITHIUM-ION | Overview  

Science Journals Connector (OSTI)

The need to increase the specific energy and energy density of secondary batteries has become more urgent as a result of the recent rapid development of new applications, such as electric vehicles (EVs), load leveling, and various types of portable equipments, including cellular phones, personal computers, camcorders, and digital cameras. Among various types of secondary batteries, rechargeable lithium-ion batteries have been used in a wide variety of portable equipments due to their high energy density. Many researchers have contributed to develop lithium-ion batteries, and their contributions are reviewed from historical aspects onward, including the researches in primary battery with metal lithium anode, and secondary battery with metal lithium negative electrode. Researches of new materials are still very active to develop new lithium-ion batteries with higher performances. The researches of positive and negative electrode active materials and electrolytes are also reviewed historically.

J. Yamaki

2009-01-01T23:59:59.000Z

65

Chapter 16 - Lithium Battery Energy Storage: State of the Art Including Lithium–Air and Lithium–Sulfur Systems  

Science Journals Connector (OSTI)

Abstract Lithium, the lightest and one of the most reactive of metals, having the greatest electrochemical potential (E0 = ?3.045 V), provides very high energy and power densities in batteries. Rechargeable lithium-ion batteries (containing an intercalation negative electrode) have conquered the markets for portable consumer electronics and, recently, for electric vehicles. The electrolyte is usually based on a lithium salt in organic solution. Thin-film batteries use solid oxide or polymer electrolytes. As lithium metal reacts violently with water and can thus cause ignition, modern lithium-ion batteries use carbon negative electrodes and lithium metal oxide positive electrodes. Rechargeable lithium-ion batteries should not be confused with nonrechargeable lithium primary batteries (containing metallic lithium). This chapter covers all aspects of lithium battery chemistry that are pertinent to electrochemical energy storage for renewable sources and grid balancing.

Peter Kurzweil

2015-01-01T23:59:59.000Z

66

SECONDARY BATTERIES – LITHIUM RECHARGEABLE SYSTEMS | Overview  

Science Journals Connector (OSTI)

Rechargeable lithium batteries have conquered the markets for portable consumer electronics and, recently, for electric vehicles. Lithium, the lightest and one of the most reactive of metals, having the greatest electrochemical potential (E°=–3.045 V), provides very high energy and power densities in batteries. As lithium metal reacts violently with water and can ignite into flame, modern lithium-ion batteries use carbon negative electrode and lithium metal oxide positive electrode. The electrolyte is usually based on a lithium salt in organic solution. Thin-film batteries use solid oxide or polymer electrolytes. Rechargeable lithium-ion batteries (containing an intercalation negative electrode) should not be confused with nonrechargeable lithium primary batteries (containing metallic lithium). This article outlines energy storage in lithium batteries, basic cell chemistry, positive electrode materials, negative electrode materials, electrolytes, and state-of-charge (SoC) monitoring.

P. Kurzweil; K. Brandt

2009-01-01T23:59:59.000Z

67

Correlation of conductivity and angle integrated valence band photoemission  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Correlation of conductivity and angle integrated valence band photoemission Correlation of conductivity and angle integrated valence band photoemission characteristics in single crystal iron perovskites for 300 K < T < 800 K: Comparison of surface and bulk sensitive methods Title Correlation of conductivity and angle integrated valence band photoemission characteristics in single crystal iron perovskites for 300 K < T < 800 K: Comparison of surface and bulk sensitive methods Publication Type Journal Article Year of Publication 2010 Authors Braun, Artur, Bongjin S. Mun, Yun Sun, Z. Liu, Oliver Gröning, R. Mäder, Selma Erat, Xueyuan Zhang, Samuel S. Mao, Ekaterina Pomjakushina, Kazimierz Conder, and Thomas Graule Journal Journal of Electron Spectroscopy and Related Phenomena Volume 181 Issue 1 Pagination 56-62 Date Published 07/2013

68

Lithium niobate explosion monitor  

DOE Patents [OSTI]

Monitoring explosive devices is accomplished with a substantially z-cut lithium niobate crystal in abutment with the explosive device. Upon impact by a shock wave from detonation of the explosive device, the crystal emits a current pulse prior to destruction of the crystal. The current pulse is detected by a current viewing transformer and recorded as a function of time in nanoseconds. In order to self-check the crystal, the crystal has a chromium film resistor deposited thereon which may be heated by a current pulse prior to detonation. This generates a charge which is detected by a charge amplifier. 8 figs.

Bundy, C.H.; Graham, R.A.; Kuehn, S.F.; Precit, R.R.; Rogers, M.S.

1990-01-09T23:59:59.000Z

69

Lithium niobate explosion monitor  

DOE Patents [OSTI]

Monitoring explosive devices is accomplished with a substantially z-cut lithium niobate crystal in abutment with the explosive device. Upon impact by a shock wave from detonation of the explosive device, the crystal emits a current pulse prior to destruction of the crystal. The current pulse is detected by a current viewing transformer and recorded as a function of time in nanoseconds. In order to self-check the crystal, the crystal has a chromium film resistor deposited thereon which may be heated by a current pulse prior to detonation. This generates a charge which is detected by a charge amplifier.

Bundy, Charles H. (Clearwater, FL); Graham, Robert A. (Los Lunas, NM); Kuehn, Stephen F. (Albuquerque, NM); Precit, Richard R. (Albuquerque, NM); Rogers, Michael S. (Albuquerque, NM)

1990-01-01T23:59:59.000Z

70

Development of encapsulated lithium hydride thermal energy storage for space power systems  

SciTech Connect (OSTI)

Inclusion of thermal energy storage in a pulsed space power supply will reduce the mass of the heat rejection system. In this mode, waste heat generated during the brief high-power burst operation is placed in the thermal store; later, the heat in the store is dissipated to space via the radiator over the much longer nonoperational period of the orbit. Thus, the radiator required is of significantly smaller capacity. Scoping analysis indicates that use of lithium hydride as the thermal storage medium results in system mass reduction benefits for burst periods as long as 800 s. A candidate design for the thermal energy storage component utilizes lithium hydride encapsulated in either 304L stainless steel or molybdenum in a packed-bed configuration with a lithium or sodium-potassium (NaK) heat transport fluid. Key issues associated with the system design include phase-change induced stresses in the shell, lithium hydride and shell compatibility, lithium hydride dissociation and hydrogen loss from the system, void presence and movement associated with the melt-freeze process, and heat transfer limitations on obtaining the desired energy storage density. 58 refs., 40 figs., 11 tabs.

Morris, D.G.; Foote, J.P.; Olszewski, M.

1987-12-01T23:59:59.000Z

71

Lattice Dynamics of Dense Lithium  

Science Journals Connector (OSTI)

We report low-frequency high-resolution Raman spectroscopy and ab-initio calculations on dense lithium from 40 to 200 GPa at low temperatures. Our experimental results reveal rich first-order Raman activity in the metallic and semiconducting phases of lithium. The computed Raman frequencies are in excellent agreement with the measurements. Free energy calculations provide a quantitative description and physical explanation of the experimental phase diagram only when vibrational effect are correctly treated. The study underlines the importance of zero-point energy in determining the phase stability of compressed lithium.

F. A. Gorelli; S. F. Elatresh; C. L. Guillaume; M. Marqués; G. J. Ackland; M. Santoro; S. A. Bonev; E. Gregoryanz

2012-01-30T23:59:59.000Z

72

Lithium System Operation Dan Lev and David Stein  

E-Print Network [OSTI]

Lithium System Operation Dan Lev and David Stein March 1, 2011 (or Lithium tank for dummies) 1 #12 for Ordering . . . . . . . . . . . . . . . . . 51 9 Lithium Handling 52 9.1 Glove Box for Ordering . . . . . . . . . . . . . . . . . 57 9.2 Lithium Cleaning

73

Method of gravel packing a subterranean well  

SciTech Connect (OSTI)

This patent describes a method of gravel packing a well bore penetrating a subterranean formation. It comprises blocking a first group of apertures in a liner with an immobile gel; positioning the liner within the well bore thereby defining a first annulus between the liner and the well bore; transporting a slurry comprised of gravel suspended in a fluid into the first annulus, the fluid flowing through a second group of apertures in the liner while the gravel is deposited within the first annulus to form a gravel pack; and thereafter removing substantially all of the gel from the first group of apertures.

Not Available

1991-11-05T23:59:59.000Z

74

Mobile linkers on DNA-coated colloids: valency without patches  

E-Print Network [OSTI]

Colloids coated with single-stranded DNA (ssDNA) can bind selectively to other colloids coated with complementary ssDNA. The fact that DNA-coated colloids (DNACCs) can bind to specific partners opens the prospect of making colloidal `molecules'. However, in order to design DNACC-based molecules, we must be able to control the valency of the colloids, i.e. the number of partners to which a given DNACC can bind. One obvious, but not very simple approach is to decorate the colloidal surface with patches of single-stranded DNA that selectively bind those on other colloids. Here we propose a design principle that exploits many-body effects to control the valency of otherwise isotropic colloids. Using a combination of theory and simulation, we show that we can tune the valency of colloids coated with mobile ssDNA, simply by tuning the non-specific repulsion between the particles. Our simulations show that the resulting effective interactions lead to low-valency colloids self-assembling in peculiar open structures, very different from those observed in DNACCs with immobile DNA linkers.

Stefano Angioletti-Uberti; Patrick Varilly; Bortolo M. Mognetti; Daan Frenkel

2014-08-27T23:59:59.000Z

75

Y-12 lithium-6 production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fusion materials on August 12, 1953. The explosion was quickly determined to be a thermonuclear-like test and was also believed to contain lithium. Y-12 chemists and engineers...

76

Pairing of valence electrons as necessary condition for energy minimization in a crystal  

E-Print Network [OSTI]

Pairing of valence electrons can lead to energy minimization of a crystal. It can be proved by use of representation of the valence electrons as plane waves in periodic potential of the crystal.

Dolgopolov Stanislav Olegovich

2014-10-21T23:59:59.000Z

77

Air breathing lithium power cells  

DOE Patents [OSTI]

A cell suitable for use in a battery according to one embodiment includes a catalytic oxygen cathode; a stabilized zirconia electrolyte for selective oxygen anion transport; a molten salt electrolyte; and a lithium-based anode. A cell suitable for use in a battery according to another embodiment includes a catalytic oxygen cathode; an electrolyte; a membrane selective to molecular oxygen; and a lithium-based anode.

Farmer, Joseph C.

2014-07-15T23:59:59.000Z

78

Lithium Technology Corporation | Open Energy Information  

Open Energy Info (EERE)

Corporation Corporation Jump to: navigation, search Name Lithium Technology Corporation Place Plymouth Meeting, Pennsylvania Zip PA 19462 Sector Vehicles Product Pennsylvania-based lithium secondary battery company manufacturing rechargeable batteries for plug-in and hybrid vehicles and for custom military and industrial applications. References Lithium Technology Corporation[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Lithium Technology Corporation is a company located in Plymouth Meeting, Pennsylvania . References ↑ "Lithium Technology Corporation" Retrieved from "http://en.openei.org/w/index.php?title=Lithium_Technology_Corporation&oldid=348412"

79

An algorithm for packing connectors J. Keijsper  

E-Print Network [OSTI]

(a set of edges covering all vertices). An S--T connector is a common spanning set of two graphic maAn algorithm for packing connectors J. Keijsper University of Amsterdam Department of MathematicsS; Tg of V , an S--T connector is a set of edges F ` E such that every component of the subgraph (V; F

Keijsper, Judith

80

Packing frustration in dense confined fluids  

E-Print Network [OSTI]

Packing frustration for confined fluids, i.e., the incompatibility between the preferred packing of the fluid particles and the packing constraints imposed by the confining surfaces, is studied for a dense hard-sphere fluid confined between planar hard surfaces at short separations. The detailed mechanism for the frustration is investigated via an analysis of the anisotropic pair distributions of the confined fluid, as obtained from integral equation theory for inhomogeneous fluids at pair correlation level within the anisotropic Percus-Yevick approximation. By examining the mean forces that arise from interparticle collisions around the periphery of each particle in the slit, we calculate the principal components of the mean force for the density profile - each component being the sum of collisional forces on a particle's hemisphere facing either surface. The variations of these components with the slit width give rise to rather intricate changes in the layer structure between the surfaces, but, as shown in this paper, the basis of these variations can be easily understood qualitatively and often also semi-quantitatively. It is found that the ordering of the fluid is in essence governed locally by the packing constraints at each single solid-fluid interface. A simple superposition of forces due to the presence of each surface gives surprisingly good estimates of the density profiles, but there remain nontrivial confinement effects that cannot be explained by superposition, most notably the magnitude of the excess adsorption of particles in the slit relative to bulk.

Kim Nygård; Sten Sarman; Roland Kjellander

2014-09-04T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Introduction The AdenoPACK 100 adenovirus  

E-Print Network [OSTI]

an excellent performance in small scale virus purification. However, they are also scalable and confirm to cIntroduction The AdenoPACK 100 adenovirus purification and concentration kit is intended-vitro transfections. The kit includes all reagents and devices necessary for clarification, purification

Lebendiker, Mario

82

Electron delocalization in mixed-valence Keggin polyoxometalates. Ab initio calculation of the local e ective  

E-Print Network [OSTI]

Electron delocalization in mixed-valence Keggin polyoxometalates. Ab initio calculation evaluation of the in uence of the electron trans- fer on the magnetic properties of mixed-valence polyoxometalates reduced by two electrons. For that purpose, we extract from valence-spectroscopy ab initio

83

Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters  

SciTech Connect (OSTI)

Only limited information is available regarding the manner in which cyclic carbonate and ester solvents coordinate Li+ cations in electrolyte solutions for lithium batteries. One approach to gleaning significant insight into these interactions is to examine crystalline solvate structures. To this end, eight new solvate structures are reported with ethylene carbonate, ?-butyrolactone and ?-valerolactone: (EC)3:LiClO4, (EC)2:LiClO4, (EC)2:LiBF4, (GBL)4:LiPF6, (GBL)1:LiClO4, (GVL)1:LiClO4, (GBL)1:LiBF4 and (GBL)1:LiCF3SO3. The crystal structure of (EC)1:LiCF3SO3 is also re-reported for comparison. These structures enable the factors which govern the manner in which the ions are coordinated and the ion/solvent packing—in the solid-state—to be scrutinized in detail.

Seo, D. M.; Afroz, Taliman; Allen, Joshua L.; Boyle, Paul D.; Trulove, Paul C.; De Long, Hugh C.; Henderson, Wesley A.

2014-11-13T23:59:59.000Z

84

Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations  

E-Print Network [OSTI]

). It is pertinent to mention that lithium bases were previously used to deprotonate the acetal 3, albeit at lower1 Deprotonative metallation of ferrocenes using mixed lithium-zinc and lithium-cadmium combinations on the web Xth XXXXXXXXX 200X DOI: 10.1039/b000000x A mixed lithium-cadmium amide and a combination

Boyer, Edmond

85

Energy Saving in Distillation Using Structured Packing and Vapor Recompression  

E-Print Network [OSTI]

% of the world's styrene capac ty is now processed through columns filled with Flex pac? or Mellapak structured packings. In conventio al column operation, energy savings of 20 to 30% re obtained by replacing trays or dumped packings Other benefits...% of the world's styrene capac ty is now processed through columns filled with Flex pac? or Mellapak structured packings. In conventio al column operation, energy savings of 20 to 30% re obtained by replacing trays or dumped packings Other benefits...

Hill, J.H.

86

Khalil Amine on Lithium-air Batteries  

ScienceCinema (OSTI)

Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

Khalil Amine

2010-01-08T23:59:59.000Z

87

Novel Electrolytes for Lithium Ion Batteries  

SciTech Connect (OSTI)

We have been investigating three primary areas related to lithium ion battery electrolytes. First, we have been investigating the thermal stability of novel electrolytes for lithium ion batteries, in particular borate based salts. Second, we have been investigating novel additives to improve the calendar life of lithium ion batteries. Third, we have been investigating the thermal decomposition reactions of electrolytes for lithium-oxygen batteries.

Lucht, Brett L

2014-12-12T23:59:59.000Z

88

Multi-layered, chemically bonded lithium-ion and lithium/air batteries  

SciTech Connect (OSTI)

Disclosed are multilayer, porous, thin-layered lithium-ion batteries that include an inorganic separator as a thin layer that is chemically bonded to surfaces of positive and negative electrode layers. Thus, in such disclosed lithium-ion batteries, the electrodes and separator are made to form non-discrete (i.e., integral) thin layers. Also disclosed are methods of fabricating integrally connected, thin, multilayer lithium batteries including lithium-ion and lithium/air batteries.

Narula, Chaitanya Kumar; Nanda, Jagjit; Bischoff, Brian L; Bhave, Ramesh R

2014-05-13T23:59:59.000Z

89

Measurement of valence band structure in arbitrary dielectric films  

SciTech Connect (OSTI)

A new way of measuring the band structure of various dielectric materials using the secondary electron emission from Auger neutralization of ions is introduced. The first example of this measurement scheme is the magnesium oxide (MgO) films with respect to the application of the films in the display industries. The density of state in the valence bands of MgO film and MgO film with a functional layer (FL) deposited over a dielectric surface reveals that the density peak of film with a FL is considerably less than that of film, thereby indicating a better performance of MgO film with functional layer in display devices. The second example of the measurement is the boron-zinc oxide (BZO) films with respect to the application of the films to the development of solar cells. The measurement of density of state in BZO film suggests that a high concentration of boron impurity in BZO films may enhance the transition of electrons and holes through the band gap from the valence to the conduction band in zinc oxide crystals; thereby improving the conductivity of the film. Secondary electron emission by the Auger neutralization of ions is highly instrumental for the determination of the density of states in the valence band of dielectric materials.

Uhm, Han S., E-mail: hsuhm@kw.ac.kr [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of); Choi, Eun H. [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of)] [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of)

2012-10-15T23:59:59.000Z

90

Solid composite electrolytes for lithium batteries  

DOE Patents [OSTI]

Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a ceramic-ceramic composite electrolyte is provided containing lithium nitride and lithium phosphate. The ceramic-ceramic composite is also preferably annealed and exhibits an activation energy of about 0.1 eV.

Kumar, Binod (Dayton, OH); Scanlon, Jr., Lawrence G. (Fairborn, OH)

2000-01-01T23:59:59.000Z

91

Anode materials for lithium-ion batteries  

DOE Patents [OSTI]

An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.

Sunkara, Mahendra Kumar; Meduri, Praveen; Sumanasekera, Gamini

2014-12-30T23:59:59.000Z

92

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

kg/m3) ! ef excess capacity of lithium foil ! rcn density ofU I read * ef ! excess capacity of lithium foil read * rcn !lx,f6.3,' ef, excess capacity of lithium foil' &/lx,f6.1,'

Doyle, C.M.

2010-01-01T23:59:59.000Z

93

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-13T23:59:59.000Z

94

Significant influence of insufficient lithium on electrochemical performance of lithium-rich layered oxide cathodes for lithium ion batteries  

Science Journals Connector (OSTI)

Abstract With an aim to broaden the understanding of the factors that govern electrochemical performance of lithium-rich layered oxide, the influences of insufficient lithium on reversible capacity, cyclic stability and rate capability of the oxide as cathode of lithium ion battery are investigated in this study. Various concentrations of lithium precursor are introduced to synthesize a target composition Li[Li0.13Ni0.30Ni0.57]O2, and the resulting products are characterized with inductively coupled plasma spectrum, scanning electron microscope, X-ray diffraction, Raman spectroscopy, and electrochemical measurements. The results indicate that the lithium content in the resulting oxide decreases with reducing the concentration of lithium precursor from 10wt%-excess lithium to stoichiometric lithium, due to insufficient compensation for lithium volatilization during synthesis process at high temperature. However, all these oxides still exhibit typically structural and electrochemical characteristics of lithium-rich layered oxides. Interestingly, with decreasing the Li content in the oxide, its reversible capacity increases due to relatively higher content of active transition-metal ions, while the cyclic stability degrades severely because of structural instability induced by higher content of Mn3+ ions and deeper lithium extraction.

Xingde Xiang; Weishan Li

2014-01-01T23:59:59.000Z

95

Thin-film Lithium Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thin-Film Battery with Lithium Anode Courtesy of Oak Ridge National Laboratory, Materials Science and Technology Division Thin-Film Lithium Batteries Resources with Additional Information The Department of Energy's 'Oak Ridge National Laboratory (ORNL) has developed high-performance thin-film lithium batteries for a variety of technological applications. These batteries have high energy densities, can be recharged thousands of times, and are only 10 microns thick. They can be made in essentially any size and shape. Recently, Teledyne licensed this technology from ORNL to make batteries for medical devices including electrocardiographs. In addition, new "textured" cathodes have been developed which have greatly increased the peak current capability of the batteries. This greatly expands the potential medical uses of the batteries, including transdermal applications for heart regulation.'

96

Thin-film Rechargeable Lithium Batteries  

DOE R&D Accomplishments [OSTI]

Thin film rechargeable lithium batteries using ceramic electrolyte and cathode materials have been fabricated by physical deposition techniques. The lithium phosphorous oxynitride electrolyte has exceptional electrochemical stability and a good lithium conductivity. The lithium insertion reaction of several different intercalation materials, amorphous V{sub 2}O{sub 5}, amorphous LiMn{sub 2}O{sub 4}, and crystalline LiMn{sub 2}O{sub 4} films, have been investigated using the completed cathode/electrolyte/lithium thin film battery.

Dudney, N. J.; Bates, J. B.; Lubben, D.

1995-06-00T23:59:59.000Z

97

Imaging Lithium Air Electrodes | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Neutron Imaging Reveals Lithium Distribution in Lithium-Air Electrodes Neutron Imaging Reveals Lithium Distribution in Lithium-Air Electrodes Agatha Bardoel - January 01, 2013 Image produced by neutron-computed tomography. The next step in revolutionizing electric vehicle capacity Research Contacts: Hassina Bilheux, Jagjit Nanda, and S. Pannala Using neutron-computed tomography, researchers at the CG-1D neutron imaging instrument at Oak Ridge National Laboratory's High Flux Isotope Reactor (HFIR) have successfully mapped the three-dimensional spatial distribution of lithium products in electrochemically discharged lithium-air cathodes. Lithium-air chemistry promises very high-energy density that, if successful, would revolutionize the world of electric vehicles by extending their range to 500 miles or more. The high-energy density comes from

98

Solid solution lithium alloy cermet anodes  

DOE Patents [OSTI]

A metal-ceramic composite ("cermet") has been produced by a chemical reaction between a lithium compound and another metal. The cermet has advantageous physical properties, high surface area relative to lithium metal or its alloys, and is easily formed into a desired shape. An example is the formation of a lithium-magnesium nitride cermet by reaction of lithium nitride with magnesium. The reaction results in magnesium nitride grains coated with a layer of lithium. The nitride is inert when used in a battery. It supports the metal in a high surface area form, while stabilizing the electrode with respect to dendrite formation. By using an excess of magnesium metal in the reaction process, a cermet of magnesium nitride is produced, coated with a lithium-magnesium alloy of any desired composition. This alloy inhibits dendrite formation by causing lithium deposited on its surface to diffuse under a chemical potential into the bulk of the alloy.

Richardson, Thomas J.

2013-07-09T23:59:59.000Z

99

Novel thermal management system design methodology for power lithium-ion battery  

Science Journals Connector (OSTI)

Abstract Battery packs conformed by large format lithium-ion cells are increasingly being adopted in hybrid and pure electric vehicles in order to use the energy more efficiently and for a better environmental performance. Safety and cycle life are two of the main concerns regarding this technology, which are closely related to the cell's operating behavior and temperature asymmetries in the system. Therefore, the temperature of the cells in battery packs needs to be controlled by thermal management systems (TMSs). In the present paper an improved design methodology for developing \\{TMSs\\} is proposed. This methodology involves the development of different mathematical models for heat generation, transmission, and dissipation and their coupling and integration in the battery pack product design methodology in order to improve the overall safety and performance. The methodology is validated by comparing simulation results with laboratory measurements on a single module of the battery pack designed at IK4-IKERLAN for a traction application. The maximum difference between model predictions and experimental temperature data is 2 °C. The models developed have shown potential for use in battery thermal management studies for EV/HEV applications since they allow for scalability with accuracy and reasonable simulation time.

Nerea Nieto; Luis Díaz; Jon Gastelurrutia; Francisco Blanco; Juan Carlos Ramos; Alejandro Rivas

2014-01-01T23:59:59.000Z

100

Transparent lithium-ion batteries  

Science Journals Connector (OSTI)

...computers). Typically, a battery is composed of electrode...nanotubes (5, 7), graphene (11), and organic...is not suitable for batteries, because, to our knowledge...production of 30-inch graphene films for transparent electrodes...rechargeable lithium batteries . Nature 414 : 359 – 367...

Yuan Yang; Sangmoo Jeong; Liangbing Hu; Hui Wu; Seok Woo Lee; Yi Cui

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Synthesis and structural properties of lithium titanium oxide powder  

Science Journals Connector (OSTI)

Recently, lithium titanium oxide material has gained renewed interest in electrodes for lithium ion rechargeable batteries. We investigated the influence of excess Li on the structural characteristics of lithium ...

Soo Ho Kim; Kwang Hoon Lee; Baek Seok Seong…

2006-11-01T23:59:59.000Z

102

High purity lithium iron phosphate/carbon composites prepared by using secondary lithium source  

Science Journals Connector (OSTI)

Abstract Various lithium salts including lithium carbonate, lithium hydroxide, lithium acetate and lithium citrate were used as secondary lithium sources for the synthesis of lithium iron phosphate/carbon composites with cheap iron sources in the form of Fe and FePO4. Samples were characterized by X-ray diffraction, scanning electron microscopy, cyclic voltammetry and constant-current charge–discharge tests. The results showed that lithium carbonate derived product generated a high purity LiFePO4 phase with high tap densities. Furthermore, satisfactory electrochemical performance with an initial discharge capacity of 146.1 mAh g? 1 at 0.5 C rate and good capacity retention of 95.2% after 50 cycles were achieved.

Jinhan Yao; Xiaohui Wang; Pinjie Zhang; Jianbo Wang; Jian Xie; Kondo-Francois Aguey-Zinsou; Chun'An Ma; Lianbang Wang

2013-01-01T23:59:59.000Z

103

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

SciTech Connect (OSTI)

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

104

Packed bed carburization of tantalum and tantalum alloy  

DOE Patents [OSTI]

Packed bed carburization of a tantalum or tantalum alloy object. A method for producing corrosion-resistant tantalum or tantalum alloy objects is described. The method includes the steps of placing the object in contact with a carburizing pack, heating the packed object in vacuum furnace to a temperature whereby carbon from the pack diffuses into the object forming grains with tantalum carbide along the grain boundaries, and etching the surface of the carburized object. This latter step removes tantalum carbides from the surface of the carburized tantalum object while leaving the tantalum carbide along the grain boundaries.

Lopez, Peter C. (Espanola, NM); Rodriguez, Patrick J. (Espanola, NM); Pereyra, Ramiro A. (Medanales, NM)

1999-01-01T23:59:59.000Z

105

New ORNL electric vehicle technology packs more punch in smaller...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ORNL electric vehicle technology packs more punch in smaller package ORNL's 30-kilowatt power inverter offers greater reliability and power in a compact package. ORNL's 30-kilowatt...

106

Packed bed carburization of tantalum and tantalum alloy  

DOE Patents [OSTI]

Packed bed carburization of a tantalum or tantalum alloy object is disclosed. A method for producing corrosion-resistant tantalum or tantalum alloy objects is described. The method includes the steps of placing the object in contact with a carburizing pack, heating the packed object in vacuum furnace to a temperature whereby carbon from the pack diffuses into the object forming grains with tantalum carbide along the grain boundaries, and etching the surface of the carburized object. This latter step removes tantalum carbides from the surface of the carburized tantalum object while leaving the tantalum carbide along the grain boundaries. 4 figs.

Lopez, P.C.; Rodriguez, P.J.; Pereyra, R.A.

1999-06-29T23:59:59.000Z

107

Lithium Metal Oxide Electrodes For Lithium Cells And Batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-20T23:59:59.000Z

108

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

2008-12-23T23:59:59.000Z

109

designer phase transitions in lithium-based spinels  

SciTech Connect (OSTI)

When electrons in a metal become correlated with each other, new cooperative behavior can arise. This correlation is magnified when the metal has magnetic ions embedded in it. These atomic magnets try to line up with each other, but in doing so actually create a correlation between the motions of conduction electrons. In turn, these correlated electron motions prevent the magnetic ions from aligning, even at zero Kelvin. When this competition is strongest (at the so-called quantum critical point-QCP) the response of the system can no longer be described using the text book theory for metals. In addition, a range of new phenomena has been seen to emerge in the vicinity of a QCP, such as heavy-fermion superconductivity, coexistence of magnetism and superconductivity and hyper-scaling. The main goal of our research is to try to unravel the details of the feedback mechanism between electron motion and magnetism that lies at the heart of this new physics. We have chosen lithium-based spinel structures as the most promising family of systems to achieve our goal. Known lithium-based spinels Li{sub x}M{sub 2}O{sub 4} [M=V, Ti and Mn] show a variety of ground states: heavy-fermion, superconducting, or geometrically frustrated local moment systems. Li{sub x}M{sub 2}O{sub 4} should be ideal systems for studying QCPs since their properties can easily be fine-tuned, simply by extracting some Li [which can be done without introducing disorder in the immediate surroundings of the magnetic ions]. The premise of the proposal was that since this Li-extraction can be done both in the metallic as well as in insulating compounds, that we can expand the types of quantum phase transitions that can be studied to beyond transitions in magnetic metals. The project called for developing a better understanding of quantum phase transitions by measuring all aspects of the electronic response of Li{sub x}M{sub 2}O{sub 4} by means of neutron scattering, giving microscopic information about the behavior of the individual magnetic moments and their interactions, as well as by macroscopic measurements. In addition, the aim was to synthesize new lithium-based spinel compounds by using other transition metals that exhibit both 3{sup +} and 4{sup +} valencies. Here we report on the progress we have made during the course of this grant both towards the stated goals and on new avenues that developed as a direct result of the data we collected during this grant.

Wouter Montfrooij

2011-09-12T23:59:59.000Z

110

Polymers For Advanced Lithium Batteries | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Polymers For Advanced Lithium Batteries Polymers For Advanced Lithium Batteries 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and...

111

Polymers For Advanced Lithium Batteries | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Polymers For Advanced Lithium Batteries Polymers For Advanced Lithium Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and...

112

Vehicle Technologies Office Merit Review 2014: High Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

High Energy Lithium Batteries for PHEV Applications Vehicle Technologies Office Merit Review 2014: High Energy Lithium Batteries for PHEV Applications Presentation given by...

113

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

114

Development of Polymer Electrolytes for Advanced Lithium Batteries...  

Broader source: Energy.gov (indexed) [DOE]

Development of Polymer Electrolytes for Advanced Lithium Batteries Development of Polymer Electrolytes for Advanced Lithium Batteries 2013 DOE Hydrogen and Fuel Cells Program and...

115

Electrolytes - R&D for Advanced Lithium Batteries. Interfacial...  

Broader source: Energy.gov (indexed) [DOE]

R&D for Advanced Lithium Batteries. Interfacial Behavior of Electrolytes Electrolytes - R&D for Advanced Lithium Batteries. Interfacial Behavior of Electrolytes 2012 DOE Hydrogen...

116

Manipulating the Surface Reactions in Lithium Sulfur Batteries...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode...

117

Interface Modifications by Anion Acceptors for High Energy Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Modifications by Anion Acceptors for High Energy Lithium Ion Batteries. Interface Modifications by Anion Acceptors for High Energy Lithium Ion Batteries. Abstract: Li-rich, Mn-rich...

118

Hierarchically Porous Graphene as a Lithium-Air Battery Electrode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hierarchically Porous Graphene as a Lithium-Air Battery Electrode. Hierarchically Porous Graphene as a Lithium-Air Battery Electrode. Abstract: Functionalized graphene sheets (FGS)...

119

Exploring the interaction between lithium ion and defective graphene...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Exploring the interaction between lithium ion and defective graphene surface using dispersion corrected DFT studies. Exploring the interaction between lithium ion and defective...

120

Addressing the Voltage Fade Issue with Lithium-Manganese-Rich...  

Broader source: Energy.gov (indexed) [DOE]

Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials 2013 DOE...

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Expansion of Novolyte Capacity for Lithium Ion Electrolyte Production...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

15eswise2012p.pdf More Documents & Publications Expansion of Novolyte Capacity for Lithium Ion Electrolyte Production Expansion of Novolyte Capacity for Lithium Ion Electrolyte...

122

Celgard US Manufacturing Facilities Initiative for Lithium-ion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Celgard US Manufacturing Facilities Initiative for Lithium-ion Battery Separator Celgard US Manufacturing Facilities Initiative for Lithium-ion...

123

Expansion of Novolyte Capacity for Lithium Ion Electrolyte Production...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

15eswise2011p.pdf More Documents & Publications Expansion of Novolyte Capacity for Lithium Ion Electrolyte Production Expansion of Novolyte Capacity for Lithium Ion Electrolyte...

124

New lithium-based ionic liquid electrolytes that resist salt...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New lithium-based ionic liquid electrolytes that resist salt concentration polarization New lithium-based ionic liquid electrolytes that resist salt concentration polarization...

125

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrostatic Shield Mechanism . Abstract: Lithium metal batteries are called the “holy grail” of energy storage systems. However, lithium dendrite growth in these...

126

Effects of Carbonate Solvents and Lithium Salts on Morphology...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Efficiency of Lithium Electrode. Abstract: The application of lithium (Li) metal anode in rechargeable batteries is hindered by Li dendrite growth during Li deposition and...

127

High-capacity hydrogen storage in lithium and sodium amidoboranes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

capacity hydrogen storage in lithium and sodium amidoboranes. High-capacity hydrogen storage in lithium and sodium amidoboranes. Abstract: A substantial effort worldwide has been...

128

Lithium Metal Anodes for Rechargeable Batteries  

SciTech Connect (OSTI)

Rechargeable lithium metal batteries have much higher energy density than those of lithium ion batteries using graphite anode. Unfortunately, uncontrollable dendritic lithium growth inherent in these batteries (upon repeated charge/discharge cycling) and limited Coulombic efficiency during lithium deposition/striping has prevented their practical application over the past 40 years. With the emerging of post Li-ion batteries, safe and efficient operation of lithium metal anode has become an enabling technology which may determine the fate of several promising candidates for the next generation of energy storage systems, including rechargeable Li-air battery, Li-S battery, and Li metal battery which utilize lithium intercalation compounds as cathode. In this work, various factors which affect the morphology and Coulombic efficiency of lithium anode will be analyzed. Technologies used to characterize the morphology of lithium deposition and the results obtained by modeling of lithium dendrite growth will also be reviewed. At last, recent development in this filed and urgent need in this field will also be discussed.

Xu, Wu; Wang, Jiulin; Ding, Fei; Chen, Xilin; Nasybulin, Eduard N.; Zhang, Yaohui; Zhang, Jiguang

2014-02-28T23:59:59.000Z

129

Ternary compound electrode for lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

Raistrick, I.D.; Godshall, N.A.; Huggins, R.A.

1980-07-30T23:59:59.000Z

130

Block copolymer electrolytes for lithium batteries  

E-Print Network [OSTI]

connecting to the solid-state lithium battery. c. An opticalbattery (discounting packaging, tabs, etc. ) demonstrate the advantage of the solid-state

Hudson, William Rodgers

2011-01-01T23:59:59.000Z

131

Volatile Components from Packing Matrials, Rev. 2  

SciTech Connect (OSTI)

An outgassing study was conducted on five packing materials, comprising two experiments. These materials comprised 277-4 borated concrete, Borobond4 concrete, polyethylene bags, silica-filled silicone rubber seals, and silicone foam padding. The purpose was measure the volume of gases which diffuse from packaging materials when sealed in containers. Two heating profiles were used to study the offgassing quantities in a set of accelerated aging tests. It was determined that the concretes contain a large quantity of water. The plastic materials hold much less moisture, with the silicone materials even consuming water, possibly due to the presence of silica filler. Polyethylene tends to degrade as the temperature is elevated and the foam stiffens.

Smith, R. A.

2006-03-01T23:59:59.000Z

132

LITHIUM-BASED ELECTROCHROMIC MIRRORS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

870 870 rd Presented at the 203 Meeting of the Electrochemical Society, April 28-30, 2003 in Paris, France and published in the Proceedings. Lithium-Based Electrochromic Mirrors Thomas J. Richardson and Jonathan L. Slack Lawrence Berkeley National Laboratory April 2003 This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Building Technology, State and Community Programs, Office of Building Research and Standards of the U.S. Department of Energy under Contract No. DE-AC03-76SF00098. LITHIUM-BASED ELECTROCHROMIC MIRRORS Thomas J. Richardson* and Jonathan L. Slack Building Technologies Department Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, California 94720, USA

133

Electrolytes for lithium ion batteries  

SciTech Connect (OSTI)

A family of electrolytes for use in a lithium ion battery. The genus of electrolytes includes ketone-based solvents, such as, 2,4-dimethyl-3-pentanone; 3,3-dimethyl 2-butanone(pinacolone) and 2-butanone. These solvents can be used in combination with non-Lewis Acid salts, such as Li.sub.2[B.sub.12F.sub.12] and LiBOB.

Vaughey, John; Jansen, Andrew N.; Dees, Dennis W.

2014-08-05T23:59:59.000Z

134

Lithium batteries for pulse power  

SciTech Connect (OSTI)

New designs of lithium batteries having bipolar construction and thin cell components possess the very low impedance that is necessary to deliver high-intensity current pulses. The R D and understanding of the fundamental properties of these pulse batteries have reached an advanced level. Ranges of 50--300 kW/kg specific power and 80--130 Wh/kg specific energy have been demonstrated with experimental high-temperature lithium alloy/transition-metal disulfide rechargeable bipolar batteries in repeated 1- to 100-ms long pulses. Other versions are designed for repetitive power bursts that may last up to 20 or 30 s and yet may attain high specific power (1--10 kW/kg). Primary high-temperature Li-alloy/FeS{sub 2} pulse batteries (thermal batteries) are already commercially available. Other high-temperature lithium systems may use chlorine or metal-oxide positive electrodes. Also under development are low-temperature pulse batteries: a 50-kW Li/SOCl{sub 2} primary batter and an all solid-state, polymer-electrolyte secondary battery. Such pulse batteries could find use in commercial and military applications in the near future. 21 refs., 8 figs.

Redey, L.

1990-01-01T23:59:59.000Z

135

ET Parameters for Mixed-Valence Ru Complexes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Convergence of Spectroscopic and Kinetic Electron Transfer Parameters for Convergence of Spectroscopic and Kinetic Electron Transfer Parameters for Mixed-Valence Binuclear Dipyridylamide Ruthenium Ammine Complexes Alison J. Distefano, James F. Wishart, and Stephan S. Isied Coord. Chem. Rev. 249, 507-516 (2005). [Find paper at Elsevier Science Direct] Abstract: A series of binuclear ruthenium(II,III) pentaammine complexes bridged by 4-pyridyl isonicotinamide (iso-apy) and methyl, 4-pyridyl isonicotinamide (iso-mapy), and their mononuclear congeners, were studied by spectroscopic and kinetic techniques. The amide functionality provides asymmetry between the electronic environments of the metal ions bound to the aminopyridine (apy) and pyridine carbonyl (iso) ends. The resulting difference is observed in the charge transfer spectra and the

136

Nature of the Frequency Shift of Hydrogen Valence Vibrations  

E-Print Network [OSTI]

The physical nature of a frequency shift of hydrogen valence vibrations in a water molecule due to its interaction with neighbor molecules has been studied. Electrostatic forces connected with the multipole moments of molecules are supposed to give a dominating contribution to the intermolecular interaction. The frequency shift was calculated in the case where two neighbor molecules form a dimer. The obtained result is in qualitative agreement with the frequency shifts observed for water vapor, hexagonal ice, and liquid water, as well as for aqueous solutions of alcohols. This fact testifies to the electrostatic nature of H-bonds used to describe both the specific features of the intermolecular interaction in water and the macroscopic properties of the latter.

Zhyganiuk, I V

2015-01-01T23:59:59.000Z

137

CONCRETE OPTIMISATION WITH REGARD TO PACKING DENSITY AND RHEOLOGY  

E-Print Network [OSTI]

/organizers): .............. Keywords: packing density, rheology, grading curve, optimisation, self-compacting concrete, roller-compactedCONCRETE OPTIMISATION WITH REGARD TO PACKING DENSITY AND RHEOLOGY François de Larrard LCPC Centre concrete. Author contacts Authors E-Mail Fax Postal address LCPC Centre de Nantes François de Larrard

Paris-Sud XI, Université de

138

Relating protein conformational changes to packing efficiency and disorder  

E-Print Network [OSTI]

Relating protein conformational changes to packing efficiency and disorder Nitin Bhardwaj1 and Mark are most likely to change packing. Finally, by relating protein disorder to motions, we show 2009 proteinscience.org Abstract: Changes in protein conformation play key roles in facilitating

Gerstein, Mark

139

Procedure for Packing Weather Files for DOE-2e  

E-Print Network [OSTI]

ESL-TR-10-09-03 Procedure for Packing Weather Files for DOE-2e Kee Han Kim Juan-Carlos Baltazar-Cervantes, Ph.D. September 2010 ESL-TR-10-09-03 TABLE OF CONTENTS CHAPTER 1... ................................................................................................................................................. 7 1. OVERVIEW ..................................................................................................................................... 7 2. PROCESS OF PACKING WEATHER DATA FOR DOE-2e SIMULATION ............................... 8 2...

Kim, K. H.; Baltazar-Cervantes, J. C.

140

Configuration interaction calculation of the specific mass shift for atoms with few valence electrons.  

E-Print Network [OSTI]

) calculation. If technically Electronic address: mgk@MF1309.spb.edu possible, we allow all configurations two valence electrons. II. DETAILS OF THE CALCULATIONS In this work we calculated SMS for the low-valence correlations were included. Si II, which has a ground state configuration 3s2 3p was calculated in [1] as a one-electron

Kozlov, Mikhail G

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions  

E-Print Network [OSTI]

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactions A novel coordination polymer of mixed-valence copper(I,II) with 4,4A-bipyridine and in situ oxidized and crystallographically char- acterized to be a laminated structure via weak copper(II)­ oxygen interactions. Extended

Li, Jing

142

Evolving Design Rules for the Inverse Granular Packing Problem  

E-Print Network [OSTI]

If a collection of identical particles is poured into a container, different shapes will fill to different densities. But what is the shape that fills a container as close as possible to a pre-specified, desired density? We demonstrate a solution to this inverse-packing problem by framing it in the context of artificial evolution. By representing shapes as bonded spheres, we show how shapes may be mutated, simulated, and selected to produce particularly dense or loose packing aggregates, both with and without friction. Moreover, we show how motifs emerge linking these shapes together. The result is a set of design rules that function as an effective solution to the inverse packing problem for given packing procedures and boundary conditions. Finally, we show that these results are verified by experiments on 3D-printed prototypes used to make packings in the real world.

Marc Z. Miskin; Heinrich M. Jaeger

2014-03-17T23:59:59.000Z

143

Liquid Lithium Divertor and Scrape-Off-Layer Interactions on the National Spherical Torus Experiment: 2010 ? 2013 Progress Report  

SciTech Connect (OSTI)

The implementation of the liquid Lithium Divertor (LLD) in NSTX presented a unique opportunity in plasma-material interactions studies. A high density Langmuir Probe (HDLP) array utilizing a dense pack of triple Langmuir probes was built at PPPL and the electronics designed and built by UIUC. It was shown that the HDLP array could be used to characterize the modification of the EEDF during lithium experiments on NSTX as well as characterize the transient particle loads during lithium experiments as a means to study ELMs. With NSTX being upgraded and a new divertor being installed, the HDLP array will not be used in NSTX-U. However UIUC is currently helping to develop two new systems for depositing lithium into NSTX-U, a Liquid Lithium Pellet Dripper (LLPD) for use with the granular injector for ELM mitigation and control studies as well as an Upward-Facing Lithium Evaporator (U-LITER) based on a flash evaporation system using an electron beam. Currently UIUC has Daniel Andruczyk Stationed at PPPL and is developing these systems as well as being involved in preparing the Materials Analysis Particle Probe (MAPP) for use in LTX and NSTX-U. To date the MAPP preparations have been completed. New sample holders were designed by UIUC?s Research Engineer at PPPL and manufactured at PPPL and installed. MAPP is currently being used on LTX to do calibration and initial studies. The LLPD has demonstrated that it can produce pellets. There is still some adjustments needed to control the frequency and particle size. Equipment for the U-LITER has arrived and initial test are being made of the electron beam and design of the U-LITER in progress. It is expected to have these ready for the first run campaign of NSTX-U.

None

2013-08-27T23:59:59.000Z

144

Characterization of penetration induced thermal runaway propagation process within a large format lithium ion battery module  

Science Journals Connector (OSTI)

Abstract This paper investigates the mechanisms of penetration induced thermal runaway (TR) propagation process within a large format lithium ion battery pack. A 6-battery module is built with 47 thermocouples installed at critical positions to record the temperature profiles. The first battery of the module is penetrated to trigger a TR propagation process. The temperature responses, the voltage responses and the heat transfer through different paths are analyzed and discussed to characterize the underlying physical behavior. The temperature responses show that: 1) Compared with the results of TR tests using accelerating rate calorimetry (ARC) with uniform heating, a lower onset temperature and a shorter TR triggering time are observed in a penetration induced TR propagation test due to side heating. 2) The maximum temperature difference within a battery can be as high as 791.8 °C in a penetration induced TR propagation test. The voltage responses have a 5-stage feature, indicating that the TR happens in sequence for the two pouch cells packed inside a battery. The heat transfer analysis shows that: 1) 12% of the total heat released in TR of a battery is enough to trigger the adjacent battery to TR. 2) The heat transferred through the pole connector is only about 1/10 of that through the battery shell. 3) The fire has little influence on the TR propagation, but may cause significant damage on the accessories located above the battery. The results can enhance our understandings of the mechanisms of TR propagation, and provide important guidelines in pack design for large format lithium ion battery.

Xuning Feng; Jing Sun; Minggao Ouyang; Fang Wang; Xiangming He; Languang Lu; Huei Peng

2015-01-01T23:59:59.000Z

145

Electronic states of lithium passivated germanium nanowires: An ab-initio study  

SciTech Connect (OSTI)

A study of the electronic and structural properties of germanium nanowires (GeNWs) was performed using the ab-initio Density Functional Theory within the generalized gradient approximation where electron-ion interactions are described by ultrasoft pseudopotentials. To study the effects of the lithium in the surface of the GeNWs we compare the electronic band structures of Hydrogen passivated GeNWs with those of partial and totally Li passivated GeNWs. The nanowires were constructed in the [001], [111] and [110] directions, using the supercell model to create different wire diameters. The results show that in the case of partial Li passivation there are localized orbitals near the valence band maximum, which would create a p-doped-kind of state. The total Li passivation created metallic states for all the wires.

Trejo, A.; Carvajal, E.; Vázquez-Medina, R.; Cruz-Irisson, M. [Instituto Politécnico Nacional, ESIME-Culhuacan, Av. Santa Ana 1000, 04430 D.F. (Mexico)

2014-05-15T23:59:59.000Z

146

Jeff Chamberlain on Lithium-air batteries  

ScienceCinema (OSTI)

Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

Chamberlain, Jeff

2013-04-19T23:59:59.000Z

147

Jeff Chamberlain on Lithium-air batteries  

SciTech Connect (OSTI)

Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

Chamberlain, Jeff

2009-01-01T23:59:59.000Z

148

Discovery of pre-galactic lithium  

Science Journals Connector (OSTI)

... so these combined in nuclear reactions to make deuterium, helium-3, helium-4 and lithium-7, production of heavier elements being aborted by the absence of stable nuclei at ... other hand, is totally destroyed in matter cycled through stars, and helium-3 and lithium-7 can be both created and destroyed, so that the net effect of stellar ...

Bernard Pagel

1982-06-10T23:59:59.000Z

149

Advanced Electrolyte Additives for PHEV/EV Lithium-ion Battery  

Broader source: Energy.gov (indexed) [DOE]

calculation method and provide insights for the next step research of advanced additives. 5 Pristine Lithium uptake Lithium removal Lithium anodes - Instantaneous...

150

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries  

E-Print Network [OSTI]

Li-Rich Layered Oxides for Lithium Batteries. Nano Lett. 13,O 2 Cathode Material in Lithium Ion Batteries. Adv. Energysolvent decomposition in lithium ion batteries: first-

Lin, Feng

2014-01-01T23:59:59.000Z

151

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

E-Print Network [OSTI]

indicates that some of the excess lithium is indeed presentneither the presence of excess lithium on 3b sites nor ansamples not containing excess lithium. To minimize kinetic

Kam, Kinson

2011-01-01T23:59:59.000Z

152

How should findings on antisuicidal effects of lithium be integrated into practical treatment decisions?  

Science Journals Connector (OSTI)

Beyond its prophylactic efficacy lithium has demonstrated possibly specific antisuicidal effects. Lithium significantly reduces the high excess mortality of patients with affective disorders. Appropriate lithium ...

Prof.Dr.med. B. Müller-Oerlinghausen

2003-06-01T23:59:59.000Z

153

E-Print Network 3.0 - au-implanted lithium niobate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lithium niobate crystals Summary: O-doped lithium niobate crystals C. L. Sonesa Optoelectronics Research Centre, University of Southampton... lithium niobate crystals induced by...

154

The hierarchical properties of contact networks in granular packings  

E-Print Network [OSTI]

The topological structure resulting from the network of contacts between grains (contact network) is studied for very large samples of disorderly-packed monosized spheres with densities ranging from 0.58 to 0.64. The hierarchical organization of such a structure is studied by means of a topological map which starts from a given sphere and moves outwards in concentric shells through the contact network. We find that the topological density of disordered sphere packing is larger than the topological density of equivalent lattice sphere packings.

T. Aste; T. J. Senden

2005-04-14T23:59:59.000Z

155

Doubly Excited States in Lithium  

Science Journals Connector (OSTI)

Doubly and triply excited states of lithium are considered in an effort to identify the energy levels responsible for the several narrow lines present in the optical spectrum of that element which are not classifiable in the normal singly excited spectra of that atom. Since most of these states are coupled to continuum states through the electrostatic interaction of the electrons and will thus have extremely short lifetimes, a majority of the multiply excited states can be excluded from consideration in identifying these narrow lines. The observed narrow spectral lines can be plasuibly identified on the basis of screening-theory estimates of the energies.

J. D. Garcia and J. E. Mack

1965-05-17T23:59:59.000Z

156

Modeling of passive thermal management for electric vehicle battery packs with PCM between cells  

Science Journals Connector (OSTI)

Abstract A passive thermal management system is examined for an electric vehicle battery pack. Phase change material (PCM) is infused in foam layers separating the lithium-ion (Li-ion) cells. Known operating conditions lead to selecting a suitable PCM for the application, n-octadecane wax. Suitable porous foam for infusion is decided on through experimentation. Finite volume based simulations are conducted to study the thermal behavior of a 4 cell sub-module. The effect of different discharge rates are compared for this sub-module, with and without the PCM's presence. The results show that the maximum temperature in the system is decreased up to 7.3 K by replacing dry foam with PCM-soaked “wet foam”. The addition of PCM also makes the temperature distribution more uniform across the cells. The modeling results give indication of the quantity of PCM required, show the influence of the transient melt behavior under dynamic operating conditions, and examine design constraints associated with this approach.

N. Javani; I. Dincer; G.F. Naterer; G.L. Rohrauer

2014-01-01T23:59:59.000Z

157

Leaders of the Fuel Cell Pack | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Leaders of the Fuel Cell Pack Leaders of the Fuel Cell Pack Leaders of the Fuel Cell Pack February 17, 2012 - 10:32am Addthis Fuel cell forklifts like the one shown here are used by leading companies across the U.S. as part of their daily business operations. | Energy Department file photo. Fuel cell forklifts like the one shown here are used by leading companies across the U.S. as part of their daily business operations. | Energy Department file photo. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What does the report show? The 34 companies profiled used more than 250 fuel cells totaling 30+ MW of stationary power -- enough to supply electricity for over 21,000 households. What do WalMart, Coca-Cola, Sysco, and Whole Foods have in common? They're leading the pack when it comes to hydrogen and fuel cells.

158

Leaders of the Fuel Cell Pack | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Leaders of the Fuel Cell Pack Leaders of the Fuel Cell Pack Leaders of the Fuel Cell Pack February 17, 2012 - 10:32am Addthis Fuel cell forklifts like the one shown here are used by leading companies across the U.S. as part of their daily business operations. | Energy Department file photo. Fuel cell forklifts like the one shown here are used by leading companies across the U.S. as part of their daily business operations. | Energy Department file photo. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What does the report show? The 34 companies profiled used more than 250 fuel cells totaling 30+ MW of stationary power -- enough to supply electricity for over 21,000 households. What do WalMart, Coca-Cola, Sysco, and Whole Foods have in common? They're leading the pack when it comes to hydrogen and fuel cells.

159

LEDS Collaboration in Action Workshop Participant Pack | Open Energy  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » LEDS Collaboration in Action Workshop Participant Pack Jump to: navigation, search LEDSGP Logo.png Advancing climate-resilient low emission development around the world Home About Tools Expert Assistance Events Publications Join Us ACDS Workshop Participant Pack Agenda Accommodations Participants Location Arrival Form Open Space Sessions Speakers Presentations Links Contact Us Participant Pack Pack.pdf Powered by OpenEI ledsgp.org is built on the same platform as the popular Wikipedia site. Like Wikipedia, it is a "wiki" or website developed collaboratively by a community of users. Thanks to our unique relationship with OpenEI.org, you

160

A hybrid bin-packing heuristic to multiprocessor scheduling  

E-Print Network [OSTI]

A hybrid bin-packing heuristic to multiprocessor scheduling. Adriana Alvim (alvim ***at*** inf.puc-rio.br) Celso Ribeiro (celso ***at*** inf.puc-rio.br). Abstract: The ...

Adriana Alvim

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Lawrence Pack, train conductor, and Y-12s uranium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lawrence Pack, train conductor, and Y-12's uranium? Trains were the primary means of long haul transportation in the 1940's. Many trains brought building materials to Y-12 and...

162

Hazardous Waste: Resource Pack for Trainers and Communicators | Open Energy  

Open Energy Info (EERE)

Hazardous Waste: Resource Pack for Trainers and Communicators Hazardous Waste: Resource Pack for Trainers and Communicators Jump to: navigation, search Tool Summary Name: Hazardous Waste: Resource Pack for Trainers and Communicators Agency/Company /Organization: International Solid Waste Association (ISWA), United Nations Development Programme (UNDP), United Nations Industrial Development Organization (UNIDO) Sector: Energy, Land, Water Focus Area: Renewable Energy, - Waste to Energy Phase: Evaluate Options Topics: Adaptation, Implementation, Low emission development planning, -LEDS Resource Type: Guide/manual, Training materials Website: www.trp-training.info/ Cost: Paid Language: English References: Training Resource Pack[1] "The new TRP+ provides a structured package of notes, technical summaries, visual aids and other training material concerning the (hazardous) waste

163

Performance characterization of a packed bed electro-filter  

E-Print Network [OSTI]

PERFORMANCE CHARACTERIZATION OF A PACKED BED ELECTRO-FILTER A Thesis by A JAY NARAYANAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... December 1990 Major Subject: Safety Engineering PERFORMANCE CHARACTERIZATION OF A PACKED BED ELECTRO-FILTER A Thesis by AJAY NARAYANAN Approved as to style and content by: John P. Wagn (Ch ' of the Com ittee) Aydin Akgerman (Member) Ri ard B...

Narayanan, Ajay

2012-06-07T23:59:59.000Z

164

Random packing of lines in a lattice cube  

Science Journals Connector (OSTI)

A study is made of the random sequential packing of complete lines in a cube of integer lattice points, with side N. For N?15 exact packing fractions are computed. It is found that if line occupation attempts arrive as a spatial Poisson process the packing has two distinct phases; initially where large numbers of potential adsorption sites are blocked, and subsequently where no further blocking occurs so that filling is exponential in time. It is shown that the ratio of the durations of the blocking to the nonblocking phases falls to zero as N??. In this limit, the packing fraction at time t is ?(t)=34(1?e?t). The rapid switch between phases in large systems creates a dramatic fall in the packing rate at the start of the process. This becomes a discontinuity as N?? and is a consequence of the high aspect ratio of the packing objects. It provides a physical explanation for the diverging coefficients in expansions of ?(t) about t=0 for objects with diverging aspect ratio. After considering the three-dimensional case, the analysis is extended to d-dimensional cubes, for which it is conjectured that ?=d/2d?1 in the limit N??.

D. J. Burridge

2010-03-09T23:59:59.000Z

165

Ab initio valence-bond cluster model for ionic solids: Alkaline-earth oxides  

Science Journals Connector (OSTI)

A linear M-O-M (M=metal, O=oxygen) cluster embedded in a Madelung field, and also including the quantum effects of the neighboring ions, is used to represent the alkaline-earth oxides. For this model an ab initio wave function is constructed as a linear combination of Slater determinants written in an atomic orbital basis set, i.e., a valence-bond wave function. Each valence-bond determinant (or group of determinants) corresponds to a resonating valence-bond structure. We have obtained ab initio valence-bond cluster-model wave functions for the electronic ground state and the excited states involved in the optical-gap transitions. Numerical results are reasonably close to the experimental values. Moreover, the model contains the ionic model as a limiting case and can be readily extended and improved.

A. Lorda; F. Illas; J. Rubio; J. B. Torrance

1993-03-15T23:59:59.000Z

166

Frontal brain electrical activity (EEG) distinguishes valence and intensity of musical emotions  

E-Print Network [OSTI]

Frontal brain electrical activity (EEG) distinguishes valence and intensity of musical emotions (i.e., positive vs. negative) and intensity (i.e., intense vs. calm) in a group of under- graduates

Trainor, Laurel J.

167

A rapid method for the determination of lithium transference numbers  

SciTech Connect (OSTI)

Lithium ion-conducting polymer electrolytes are of increasing interest for use in lithium-polymer batteries. Lithium transference numbers, the net fraction of current carried by lithium in a cell, are key figures of merit for potential lithium battery electrolytes. The authors describe the Electrophoretic NMR (ENMR) method for the determination of lithium ion transference numbers (T{sub Li}). The work presented is a proof-of-concept of the application of the ENMR method to lithium ion transference measurements for several different lithium salts in gelled electrolytes. The NMR method allows accurate determination of T{sub Li} values, as indicated by the similarity of T{sub Li} in the gelled electrolytes to those in aqueous electrolyte solutions at low salt concentration. Based on calculated tradeoffs of various experimental parameters, they also discuss some conclusions concerning the range of applicability of the method to other electrolytes with lower lithium mobility.

Zawodzinski, T.A. Jr.; Dai, H.; Sanderson, S.; Davey, J.; Uribe, F. [Los Alamos National Lab., NM (United States). Electronics Materials and Device Research Group

1997-05-01T23:59:59.000Z

168

A Material Change: Bringing Lithium Production Back to America | Department  

Broader source: Energy.gov (indexed) [DOE]

A Material Change: Bringing Lithium Production Back to America A Material Change: Bringing Lithium Production Back to America A Material Change: Bringing Lithium Production Back to America June 29, 2012 - 5:34pm Addthis The Rockwood Lithium manufacturing facility in Kings Mountain, North Carolina. | Photo courtesy of Rockwood Lithium. The Rockwood Lithium manufacturing facility in Kings Mountain, North Carolina. | Photo courtesy of Rockwood Lithium. Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs Between 1980 and 2009, the global demand for lithium has tripled. This metal is a key material in a number of growing industries -- including advanced vehicle batteries and consumer electronics. But more specifically, lithium-ion batteries are a vital component in electric vehicles and other rechargeable batteries for consumer electronics, and are used to produce

169

Lithium-cation conductivity and crystal structure of lithium diphosphate  

SciTech Connect (OSTI)

The electrical conductivity of lithium diphosphate Li{sub 4}P{sub 2}O{sub 7} has been measured and jump-like increasing of ionic conductivity at 913 K has been found. The crystal structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction at 300–1050 K. At 913 K low temperature triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one, space group P2{sub 1}/n, a=8.8261(4) Å, b=5.2028(4) Å, c=13.3119(2) Å, ?=104.372(6)°. The migration maps of Li{sup +} cations based on experimental data implemented into program package TOPOS have been explored. It was found that lithium cations in both low- and high temperature forms of Li{sub 4}P{sub 2}O{sub 7} migrate in three dimensions. Cross sections of the migrations channels extend as the temperature rises, but at the phase transition point have a sharp growth showing a strong “crystal structure – ion conductivity” correlation. -- Graphical abstract: Crystal structure of Li{sub 4}P{sub 2}O{sub 7} at 950 K. Red balls represent oxygen atoms; black lines show Li{sup +} ion migration channels in the layers perpendicular to [001] direction. Highlights: • Structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction. • At 913 K triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one. • The migration maps of Li{sup +} implemented into program package TOPOS have been explored. • Cross sections of the migrations channels at the phase transition have a sharp growth.

Voronin, V.I., E-mail: voronin@imp.uran.ru [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Sherstobitova, E.A. [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Blatov, V.A., E-mail: blatov@samsu.ru [Samara Center for Theoretical Materials Science (SCTMS), Samara State University, Ac.Pavlov Street 1, 443011 Samara (Russian Federation); Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia); Shekhtman, G.Sh., E-mail: shekhtman@ihte.uran.ru [Institute of High Temperature Electrochemistry Urals Branch RAS, Akademicheskaya 20, 620990 Ekaterinburg (Russian Federation)

2014-03-15T23:59:59.000Z

170

The Saft Lithium — Silver Chromate Battery Performances of the LI 210 Type  

Science Journals Connector (OSTI)

After being involved in lithium power sources research since 1964, SAFT perfected in 1970 a new couple: lithium...

G. Lehmann; M. Broussely; P. Lenfant

1978-01-01T23:59:59.000Z

171

Categorical Exclusion 4497: Lithium Wet Chemistry Project  

Broader source: Energy.gov (indexed) [DOE]

8/2012 07:36 8/2012 07:36 8655749041 ENVIRONMENTAL COMPL U.S. Department of Energy Categorical Exclusion Detennination Form Proposed Action Tills: Lithium W@t Chemistry Project (4597) Program or Fi~ld Oftke: Y-12 Site Office L&cationfs) (CiWLCount:r/State): Oak Ridge, Anderson County; Tennessee Proposed Action Description: PAGE 03/04 r: :;: :: !: s .a : brnl, i ~ y. : $ ~-rtl~il : t·:~::;J The proposed action is to develop a small lithium wet chemistry operation for the following purposes: (1) to capture wet chemistry operations, (2) to provide processing path for Lithium materials such as machine dust, (3) to provide lithium based materials, and (4) to produce the littlium hydroxide needed to support production. CategQrj~l Exclusion(s) Applied

172

California Lithium Battery, Inc. | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

California California Lithium Battery, Inc. America's Next Top Energy Innovator Challenge 626 likes California Lithium Battery, Inc. Argonne National Laboratory California Lithium Battery ("CALBattery") is a start-up California company established in 2011 to develop and manufacture a breakthrough high energy density and long cycle life lithium battery for utility energy storage, transportation, and defense industries. The company is a joint venture between California-based Ionex Energy Storage Systems and CALiB Power. US production of this advanced Very Large Format (400Ah+) si-graphene LI-ion battery is scheduled to start in California in 2014. Plans are to produce the initial batteries for CALBattery JV partner Ionex Energy Storage Systems for use in 1-100MW grid scale energy storage

173

Argonne Transportation - Lithium Battery Technology Patents  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Awarded Lithium Battery Technology Patents Awarded Lithium Battery Technology Patents "Composite-structure" material is a promising battery electrode for electric vehicles Argonne National Laboratory has been granted two U.S. patents (U.S. Pat. 6,677,082 and U.S. Pat. 6,680,143) on new "composite-structure" electrode materials for rechargeable lithium-ion batteries. Electrode compositions of this type are receiving worldwide attention. Such electrodes offer superior cost and safety features over state-of-the-art LiCoO2 electrodes that power conventional lithium-ion batteries. Moreover, they demonstrate outstanding cycling stability and can be charged and discharged at high rates, making them excellent candidates to replace LiCoO2 for consumer electronic applications and hybrid electric vehicles.

174

Towards Safer Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Towards Safer Lithium-Ion Batteries Towards Safer Lithium-Ion Batteries Speaker(s): Guoying Chen Date: October 25, 2007 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan Safety problems associated with rechargeable lithium batteries are now well recognized. Recent spectacular fires involving cell phones, laptops, and (here at LBNL) AA cells have made the news. These events are generally caused by overcharging and subsequent development of internal shorts. Before these batteries can be used in vehicle applications, improvement in cell safety is a must. We have been active in the area of lithium battery safety for many years. For example, a versatile, inexpensive overcharge protection approach developed in our laboratory, uses an electroactive polymer to act as a reversible, self-actuating, low resistance internal

175

Rotation, inflation, and lithium in the Pleiades  

E-Print Network [OSTI]

The rapidly rotating cool dwarfs of the Pleiades are rich in lithium relative to their slowly rotating counterparts. Motivated by observations of inflated radii in young, active stars, and by calculations showing that radius inflation inhibits pre-main sequence (pre-MS) Li destruction, we test whether this pattern could arise from a connection between stellar rotation rate and radius inflation on the pre-MS. We demonstrate that pre-MS radius inflation can efficiently suppress lithium destruction by rotationally induced mixing, and that the net effect of inflation and rotational mixing is a pattern where rotation correlates with lithium abundance for $M_{*} {\\rm M}_{\\odot}$, similar to the empirical trend in the Pleiades. Next, we adopt different prescriptions for the dependence of inflation on rotation, and compare their predictions to the Pleiades lithium/rotation pattern. A connection between rotation and radius inflation naturally and generically reproduces the important qualitative features of this patte...

Somers, Garrett

2014-01-01T23:59:59.000Z

176

Layered electrodes for lithium cells and batteries  

DOE Patents [OSTI]

Lithium metal oxide compounds of nominal formula Li.sub.2MO.sub.2, in which M represents two or more positively charged metal ions, selected predominantly and preferably from the first row of transition metals are disclosed herein. The Li.sub.2MO.sub.2 compounds have a layered-type structure, which can be used as positive electrodes for lithium electrochemical cells, or as a precursor for the in-situ electrochemical fabrication of LiMO.sub.2 electrodes. The Li.sub.2MO.sub.2 compounds of the invention may have additional functions in lithium cells, for example, as end-of-discharge indicators, or as negative electrodes for lithium cells.

Johnson, Christopher S. (Naperville, IL); Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Kahaian, Arthur J. (Chicago, IL); Kim, Jeom-Soo (Naperville, IL)

2008-04-15T23:59:59.000Z

177

Side Reactions in Lithium-Ion Batteries  

E-Print Network [OSTI]

2.8 V vs. lithium suggests Tafel kinetics, but the bend in? a gives the slope of the Tafel region, k eff affects itsincreases, the slope of the Tafel region remains constant,

Tang, Maureen Han-Mei

2012-01-01T23:59:59.000Z

178

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

A New Rechargeable Plastic Li-Ion Battery," Lithium Batteryion battery developed at Bellcore in Red Bank, NJ.1-6 The experimental prototYpe cell has the configuration: Li

Doyle, C.M.

2010-01-01T23:59:59.000Z

179

California Lithium Battery, Inc. | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

California California Lithium Battery, Inc. America's Next Top Energy Innovator Challenge 626 likes California Lithium Battery, Inc. Argonne National Laboratory California Lithium Battery ("CALBattery") is a start-up California company established in 2011 to develop and manufacture a breakthrough high energy density and long cycle life lithium battery for utility energy storage, transportation, and defense industries. The company is a joint venture between California-based Ionex Energy Storage Systems and CALiB Power. US production of this advanced Very Large Format (400Ah+) si-graphene LI-ion battery is scheduled to start in California in 2014. Plans are to produce the initial batteries for CALBattery JV partner Ionex Energy Storage Systems for use in 1-100MW grid scale energy storage

180

California Lithium Battery, Inc. | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

California California Lithium Battery, Inc. America's Next Top Energy Innovator Challenge 626 likes California Lithium Battery, Inc. Argonne National Laboratory California Lithium Battery ("CALBattery") is a start-up California company established in 2011 to develop and manufacture a breakthrough high energy density and long cycle life lithium battery for utility energy storage, transportation, and defense industries. The company is a joint venture between California-based Ionex Energy Storage Systems and CALiB Power. US production of this advanced Very Large Format (400Ah+) si-graphene LI-ion battery is scheduled to start in California in 2014. Plans are to produce the initial batteries for CALBattery JV partner Ionex Energy Storage Systems for use in 1-100MW grid scale energy storage

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Maximum and minimum stable random packings of Platonic solids Jessica Baker and Arshad Kudrolli  

E-Print Network [OSTI]

of steel ball bearings 3 . In fact, work in the last decade has shown that random packing itself of the tetrahedrons 8,9 . In the case of tetrahedrons, disordered wagon-wheel packings were initially found to pack were said to be 0.76 .02 if the observed packings were extrapolated to infinite systems, but the pro

Kudrolli, Arshad

182

On Optimizing Sensor Placement for Spatio-Temporal Temperature Estimation in Large Battery Packs  

E-Print Network [OSTI]

of battery pack thermal dynamics. Monitoring and controlling battery pack temperature dy- namics. One important challenge with such battery packs is that an individual cell may become thermally management systems [2], [3], [4]. CFD modeling, model reduction, and analysis of battery pack thermal

Krstic, Miroslav

183

Design and simulation of lithium rechargeable batteries  

SciTech Connect (OSTI)

Lithium -based rechargeable batteries that utilize insertion electrodes are being considered for electric-vehicle applications because of their high energy density and inherent reversibility. General mathematical models are developed that apply to a wide range of lithium-based systems, including the recently commercialized lithium-ion cell. The modeling approach is macroscopic, using porous electrode theory to treat the composite insertion electrodes and concentrated solution theory to describe the transport processes in the solution phase. The insertion process itself is treated with a charge-transfer process at the surface obeying Butler-Volmer kinetics, followed by diffusion of the lithium ion into the host structure. These models are used to explore the phenomena that occur inside of lithium cells under conditions of discharge, charge, and during periods of relaxation. Also, in order to understand the phenomena that limit the high-rate discharge of these systems, we focus on the modeling of a particular system with well-characterized material properties and system parameters. The system chosen is a lithium-ion cell produced by Bellcore in Red Bank, NJ, consisting of a lithium-carbon negative electrode, a plasticized polymer electrolyte, and a lithium-manganese-oxide spinel positive electrode. This battery is being marketed for consumer electronic applications. The system is characterized experimentally in terms of its transport and thermodynamic properties, followed by detailed comparisons of simulation results with experimental discharge curves. Next, the optimization of this system for particular applications is explored based on Ragone plots of the specific energy versus average specific power provided by various designs.

Doyle, C.M.

1995-08-01T23:59:59.000Z

184

Predissociation dynamics of lithium iodide  

E-Print Network [OSTI]

The predissociation dynamics of lithium iodide (LiI) in the first excited A-state is investigated for molecules in the gas phase and embedded in helium nanodroplets, using femtosecond pump-probe photoionization spectroscopy. In the gas phase, the transient Li+ and LiI+ ion signals feature damped oscillations due to the excitation and decay of a vibrational wave packet. Based on high-level ab initio calculations of the electronic structure of LiI and simulations of the wave packet dynamics, the exponential signal decay is found to result from predissociation predominantly at the lowest avoided X-A potential curve crossing, for which we infer a coupling constant V=650(20) reciprocal cm. The lack of a pump-probe delay dependence for the case of LiI embedded in helium nanodroplets indicates fast droplet-induced relaxation of the vibrational excitation.

Schmidt, H; Stienkemeier, F; Bogomolov, A S; Baklanov, A V; Reich, D M; Skomorowski, W; Koch, C P; Mudrich, M

2015-01-01T23:59:59.000Z

185

Electrode for a lithium cell  

DOE Patents [OSTI]

This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Dees, Dennis W. (Downers Grove, IL)

2008-10-14T23:59:59.000Z

186

Glass for sealing lithium cells  

DOE Patents [OSTI]

Glass compositions resistant to corrosion by lithium cell electrolyte and having an expansion coefficient of 45 to 85 x 10/sup -70/C/sup -1/ have been made with SiO/sub 2/, 25 to 55% by weight; B/sub 2/O/sub 3/, 5 to 12%; Al/sub 2/O/sub 3/, 12 to 35%; CaO, 5 to 15%; MgO, 5 to 15%; SrO, 0 to 10%; and La/sub 2/O/sub 3/, 0 to 5%. Preferred compositions within that range contain 3 to 8% SrO and 0.5 to 2.5% La/sub 2/O/sub 3/.

Leedecke, C.J.

1981-08-28T23:59:59.000Z

187

An experimental study of heat pipe thermal management system with wet cooling method for lithium ion batteries  

Science Journals Connector (OSTI)

Abstract An effective battery thermal management (BTM) system is required for lithium-ion batteries to ensure a desirable operating temperature range with minimal temperature gradient, and thus to guarantee their high efficiency, long lifetime and great safety. In this paper, a heat pipe and wet cooling combined BTM system is developed to handle the thermal surge of lithium-ion batteries during high rate operations. The proposed BTM system relies on ultra-thin heat pipes which can efficiently transfer the heat from the battery sides to the cooling ends where the water evaporation process can rapidly dissipate the heat. Two sized battery packs, 3 Ah and 8 Ah, with different lengths of cooling ends are used and tested through a series high-intensity discharges in this study to examine the cooling effects of the combined BTM system, and its performance is compared with other four types of heat pipe involved BTM systems and natural convection cooling method. A combination of natural convection, fan cooling and wet cooling methods is also introduced to the heat pipe BTM system, which is able to control the temperature of battery pack in an appropriate temperature range with the minimum cost of energy and water spray.

Rui Zhao; Junjie Gu; Jie Liu

2015-01-01T23:59:59.000Z

188

Reducing Foreign Lithium Dependence through Co-Production of Lithium from Geothermal Brine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Foreign Lithium Dependence through Co-Production of Lithium from Foreign Lithium Dependence through Co-Production of Lithium from Geothermal Brine Kerry Klein 1 , Linda Gaines 2 1 New West Technologies LLC, Washington, DC, USA 2 Center for Transportation Research, Argonne National Laboratory, Argonne, IL, USA KEYWORDS Mineral extraction, zinc, silica, strategic metals, Imperial Valley, lithium ion batteries, electric- drive vehicles, battery recycling ABSTRACT Following a 2009 investment of $32.9 billion in renewable energy and energy efficiency research through the American Recovery and Reinvestment Act, President Obama in his January 2011 State of the Union address promised deployment of one million electric vehicles by 2015 and 80% clean energy by 2035. The United States seems poised to usher in its bright energy future,

189

Sorption of lithium from a geothermal brine by pelletized mixed aluminum-lithium hydrous oxides  

SciTech Connect (OSTI)

An inorganic ion exchanger was evaluated by the Bureau of Mines for recovering lithium from geothermal brines. The ion exchanger or sorbent was mixed hydrous oxide of aluminum and lithium that had been dried at 100 C. The dried precipitate was pelletized with a sodium silicate binder to improve flow rates in sorption tests. The sorbent was loaded to 2 mg Li/g of pellets and sorption from the solution was independent of the concentrations of Ca, Fe, Mn, and Zn. Manganese and zinc were sorbed by the pellets but did not suppress lithium sorption. Lithium was desorbed with water, but none of the washing solutions investigated removed entrained brine without stripping lithium. The complex nature of the sorption mechanisms is discussed.

Schultze, L.E.; Bauer, D.J.

1985-01-01T23:59:59.000Z

190

Molecular Structures of Polymer/Sulfur Composites for Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long Cycle Life. Molecular Structures of PolymerSulfur Composites for Lithium-Sulfur Batteries with Long...

191

Direct Evidence of Lithium-Induced Atomic Ordering in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Evidence of Lithium-Induced Atomic Ordering in Amorphous TiO2 Nanotubes . Direct Evidence of Lithium-Induced Atomic Ordering in Amorphous TiO2 Nanotubes . Abstract: In this paper,...

192

Promises and Challenges of Lithium- and Manganese-Rich Transition...  

Broader source: Energy.gov (indexed) [DOE]

Promises and Challenges of Lithium- and Manganese-Rich Transition-Metal Layered-Oxide Cathodes Promises and Challenges of Lithium- and Manganese-Rich Transition-Metal Layered-Oxide...

193

Development of Large Format Lithium Ion Cells with Higher Energy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500WhL Development of Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500WhL 2012 DOE...

194

Mitigating Performance Degradation of High-Energy Lithium-Ion...  

Broader source: Energy.gov (indexed) [DOE]

Mitigating Performance Degradation of High-Energy Lithium-Ion Cells Mitigating Performance Degradation of High-Energy Lithium-Ion Cells 2013 DOE Hydrogen and Fuel Cells Program and...

195

Two Studies Reveal Details of Lithium-Battery Function  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Studies Reveal Details of Lithium-Battery Function Two Studies Reveal Details of Lithium-Battery Function Print Wednesday, 27 February 2013 00:00 Our way of life is deeply...

196

Shell Model for Atomistic Simulation of Lithium Diffusion in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed MnTi Oxides. Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed MnTi Oxides. Abstract: Mixed...

197

Microplasticity and fatigue of some magnesium-lithium alloys  

Science Journals Connector (OSTI)

Cyclic stress-strain curves have been obtained for a series of magnesium-lithium alloys with lithium contents up to 12. 5wt%. The ... hardening exponents for stresses leading to failure in excess of 104...cycles ...

R. E. Lee; W. J. D. Jones

1974-03-01T23:59:59.000Z

198

Lithium-ion batteries having conformal solid electrolyte layers  

DOE Patents [OSTI]

Hybrid solid-liquid electrolyte lithium-ion battery devices are disclosed. Certain devices comprise anodes and cathodes conformally coated with an electron insulating and lithium ion conductive solid electrolyte layer.

Kim, Gi-Heon; Jung, Yoon Seok

2014-05-27T23:59:59.000Z

199

Nature of Bridging Bonds in Lithium and Potassium Acetate Dimers  

Science Journals Connector (OSTI)

The structures of lithium and potassium acetates were studied by the RHF/6-31G*...3COOLi)2 and (CH3COOK)2 are electrostatic in nature. The bridging lithium bond is intermediate between hydrogen and ionic, ... of ...

I. A. Panteleev; S. G. Semenov; D. N. Glebovskii

200

Loading of emulsions stacks with aqueous solutions of lithium acetate  

Science Journals Connector (OSTI)

It has been shown that thick pellicles can be loaded with lithium acetate solutions still maintaining all the desirable geometrical ... purpose of the method, that of introducing lithium atoms in the emulsion, th...

D. H. Davis; R. Levi Setti; M. Raymund; G. Tomasini

1962-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Lithium carbide is prospective material for breeder of fusion reactor  

Science Journals Connector (OSTI)

It is shown that lithium carbide is a prospective material for breeder of fusion reactor. The lithium carbide equivalent dose rate reaches...?5...Sv/h) one minute after the irradiation with fusion reactor neutron...

M. V. Alenina; V. P. Kolotov; Yu. M. Platov

2014-03-01T23:59:59.000Z

202

Electrolytes - R&D for Advanced Lithium Batteries. Interfacial...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Electrolytes - R&D for Advanced Lithium Batteries. Interfacial Behavior of Electrolytes Interfacial Behavior of Electrolytes...

203

Methods for making lithium vanadium oxide electrode materials  

DOE Patents [OSTI]

A method of making vanadium oxide formulations is presented. In one method of preparing lithium vanadium oxide for use as an electrode material, the method involves: admixing a particulate form of a lithium compound and a particulate form of a vanadium compound; jet milling the particulate admixture of the lithium and vanadium compounds; and heating the jet milled particulate admixture at a temperature below the melting temperature of the admixture to form lithium vanadium oxide.

Schutts, Scott M. (Menomonie, WI); Kinney, Robert J. (Woodbury, MN)

2000-01-01T23:59:59.000Z

204

A study of a cooling tower with variable packing heights  

E-Print Network [OSTI]

I, tower of eight feet by ei, . ht feet section. . W. W. Smith (18) reported in 1&56, his results and con- clusions for mass transfer and resistance to air flow for three redwood packihg styles having essent1ally the same vert1cal projected area, made... the time to ~efinitel. ?; sta. e that the redwood packing of re tangulor section (width-hei~ht ratio '). g(~) is the best packin? typo. 'Ihe field is till open for experimentation with packings of other avail, ble mat- erials and packins f...

Khan, A. M. M. Farid

2012-06-07T23:59:59.000Z

205

Capture of carbon dioxide over porous solid adsorbents lithium silicate, lithium aluminate and magnesium aluminate at pre-combustion temperatures  

Science Journals Connector (OSTI)

The capturing process for carbon dioxide over porous solid adsorbents such as ... resonance (NMR), and surface area. The capturing of carbon dioxide over lithium silicate, lithium aluminate, ... as exposure time,...

P. V. Korake; A. G. Gaikwad

2011-06-01T23:59:59.000Z

206

Use of Lithium Hexafluoroisopropoxide as a Mild Base for  

E-Print Network [OSTI]

Use of Lithium Hexafluoroisopropoxide as a Mild Base for Horner-Wadsworth-Emmons Olefination The weak base lithium 1,1,1,3,3,3-hexafluoroisopropoxide (LiHFI) is shown to be highly effective of base-sensitive substrates, leading to the discovery that lithium 1,1,1,3,3,3-hexafluoroisopropoxide (Li

207

RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR  

E-Print Network [OSTI]

RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR By SCOTT RUSSELL WAITUKAITIS A Thesis Submitted: #12;Abstract I describe a study of Faraday rotation in a hot lithium vapor. I begin by dis- cussing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.3 The Lithium Oven and Solenoid . . . . . . . . . . . . . . . . . 7 3 Theoretical Framework

Cronin, Alex D.

208

Proposal on Lithium Wall Experiment (LWX) on PBXM 1  

E-Print Network [OSTI]

Proposal on Lithium Wall Experiment (LWX) on PBX­M 1 Leonid E. Zakharov, Princeton University; OUTLINE 1. Mini­conference on Lithium walls and low recycling regime. 2. PBX­M Capabilities. 3. Motivation "Lithium covered walls and low recycling regimes in toka­ maks". APS meeting, October 23­27, 2000, Quebec

Zakharov, Leonid E.

209

Mechanism of Acylation of Lithium Phenylacetylide with a Weinreb Amide  

E-Print Network [OSTI]

with the excess lithium acetylide and a 1:3 (alkox- ide-rich) mixed tetramer. The stabilities of the mixedMechanism of Acylation of Lithium Phenylacetylide with a Weinreb Amide Bo Qu and David B. CollumVersity, Ithaca, New York 14853-1301 dbc6@cornell.edu ReceiVed June 14, 2006 Additions of lithium phenylacetylide

Collum, David B.

210

Lithium Ion Batteries DOI: 10.1002/anie.201103163  

E-Print Network [OSTI]

Lithium Ion Batteries DOI: 10.1002/anie.201103163 LiMn1Ã?xFexPO4 Nanorods Grown on Graphene Sheets for Ultrahigh- Rate-Performance Lithium Ion Batteries** Hailiang Wang, Yuan Yang, Yongye Liang, Li-Feng Cui cathode materials for rechargeable lithium ion batteries (LIBs) owing to their high capacity, excellent

Cui, Yi

211

Mechanical Properties of Lithium-Ion Battery Separator Materials  

E-Print Network [OSTI]

Mechanical Properties of Lithium-Ion Battery Separator Materials Patrick Sinko B.S. Materials Science and Engineering 2013, Virginia Tech John Cannarella PhD. Candidate Mechanical and Aerospace and motivation ­ Why study lithium-ion batteries? ­ Lithium-ion battery fundamentals ­ Why study the mechanical

Petta, Jason

212

Lithium intercalated graphite : experimental Compton profile for stage one  

E-Print Network [OSTI]

L-301 Lithium intercalated graphite : experimental Compton profile for stage one G. Loupias, J différence des profils Compton est compatible avec un transfert total de l'électron de conduction du lithium électronique due à l'insertion. Abstract. 2014 Electron momentum distribution of the first stage lithium

Paris-Sud XI, Université de

213

Lithium Niobate Devices in Switching and Multiplexing [and Discussion  

Science Journals Connector (OSTI)

28 September 1989 research-article Lithium Niobate Devices in Switching and Multiplexing...Thylen Integrated-optics devices in lithium niobate have reached a significant maturity...in fibre-optic transmission systems, lithium niobate devices currently offer the only...

1989-01-01T23:59:59.000Z

214

LITHIUM--2002 46.1 By Joyce A. Ober  

E-Print Network [OSTI]

recycling operation in Trail, British Columbia, Canada. Another ToxCo subsidiary, Ozark Fluorine Specialties, the concentration of the brine increases through solar evaporation to 6,000 ppm lithium. When the lithium chloride carbonate production. Australia, Canada, and Zimbabwe were important sources of lithium concentrates

215

Evaporated Lithium Surface Coatings in NSTX  

SciTech Connect (OSTI)

Two lithium evaporators were used to evaporate more than 100 g of lithium on to the NSTX lower divertor region. Prior to each discharge, the evaporators were withdrawn behind shutters, where they also remained during the subsequent HeGDC applied for periods up to 9.5 min. After the HeGDC, the shutters were opened and the LITERs were reinserted to deposit lithium on the lower divertor target for 10 min, at rates of 10-70 mg/min, prior to the next discharge. The major improvements in plasma performance from these lithium depositions include: (1) plasma density reduction as a result of lithium deposition; (2) suppression of ELMs; (3) improvement of energy confinement in a low-triangularity shape; (4) improvement in plasma performance for standard, high-triangularity discharges: (5) reduction of the required HeGDC time between discharges; (6) increased pedestal electron and ion temperature; (7) reduced SOL plasma density; and (8) reduced edge neutral density. (C) 2009 Elsevier B.V. All rights reserved

Kugel, H. W. [Princeton Plasma Physics Laboratory (PPPL); Mansfield, D. [Princeton Plasma Physics Laboratory (PPPL); Maingi, Rajesh [ORNL; Bell, M. G. [Princeton Plasma Physics Laboratory (PPPL); Bell, R. E. [Princeton Plasma Physics Laboratory (PPPL); Allain, J. P. [Purdue University; Gates, D. [Princeton Plasma Physics Laboratory (PPPL); Gerhardt, S. P. [Princeton Plasma Physics Laboratory (PPPL); Kaita, R. [Princeton Plasma Physics Laboratory (PPPL); Kallman, J. [Princeton Plasma Physics Laboratory (PPPL); Kaye, S. [Princeton Plasma Physics Laboratory (PPPL); LeBlanc, B. P. [Princeton Plasma Physics Laboratory (PPPL); Majeski, R. [Princeton Plasma Physics Laboratory (PPPL); Menard, J. [Princeton Plasma Physics Laboratory (PPPL); Mueller, D. [Princeton Plasma Physics Laboratory (PPPL); Ono, M. [Princeton Plasma Physics Laboratory (PPPL); Paul, S. [Princeton Plasma Physics Laboratory (PPPL); Raman, R. [University of Washington, Seattle; Roquemore, A. L. [Princeton Plasma Physics Laboratory (PPPL); Ross, P. W. [Princeton Plasma Physics Laboratory (PPPL); Sabbagh, S. A. [Columbia University; Schneider, H. [Princeton Plasma Physics Laboratory (PPPL); Skinner, C. H. [Princeton Plasma Physics Laboratory (PPPL); Soukhanovskii, V. [Lawrence Livermore National Laboratory (LLNL); Stevenson, T. [Princeton Plasma Physics Laboratory (PPPL); Timberlake, J. [Princeton Plasma Physics Laboratory (PPPL); Wampler, W. R. [Sandia National Laboratories (SNL); Wilgen, John B [ORNL; Zakharov, L. E. [Princeton Plasma Physics Laboratory (PPPL)

2009-01-01T23:59:59.000Z

216

Evaporated Lithium Surface Coatings in NSTX  

SciTech Connect (OSTI)

Two lithium evaporators were used to evaporate more than 100 g of lithium on to the NSTX lower divertor region. Prior to each discharge, the evaporators were withdrawn behind shutters, where they also remained during the subsequent HeGDC applied for periods up to 9.5 min. After the HeGDC, the shutters were opened and the LITERs were reinserted to deposit lithium on the lower divertor target for 10 min, at rates of 10-70 mg/min, prior to the next discharge. The major improvements in plasma performance from these lithium depositions include: 1) plasma density reduction as a result of lithium deposition; 2) suppression of ELMs; 3) improvement of energy confinement in a low-triangularity shape; 4) improvement in plasma performance for standard, high-triangularity discharges; 5) reduction of the required HeGDC time between discharges; 6) increased pedestal electron and ion temperature; 7) reduced SOL plasma density; and 8) reduced edge neutral density.

Kugel, H. W.; Mansfield, D.; Maingi, R.; Bel, M. G.; Bell, R. E.; Allain, J. P.; Gates, D.; Gerhardt, S.; Kaita, R.; Kallman, J.; Kaye, S.; LeBlanc, B.; Majeski, R.; Menard, J.; Mueller, D.; Ono, M.

2009-04-09T23:59:59.000Z

217

Evaporated lithium surface coatings in NSTX.  

SciTech Connect (OSTI)

Two lithium evaporators were used to evaporate more than 100 g of lithium on to the NSTX lower divertor region. Prior to each discharge, the evaporators were withdrawn behind shutters, where they also remained during the subsequent HeGDC applied for periods up to 9.5 min. After the HeGDC, the shutters were opened and the LITERs were reinserted to deposit lithium on the lower divertor target for 10 min, at rates of 10-70 mg/min, prior to the next discharge. The major improvements in plasma performance from these lithium depositions include: (1) plasma density reduction as a result of lithium deposition; (2) suppression of ELMs; (3) improvement of energy confinement in a low-triangularity shape; (4) improvement in plasma performance for standard, high-triangularity discharges; (5) reduction of the required HeGDC time between discharges; (6) increased pedestal electron and ion temperature; (7) reduced SOL plasma density; and (8) reduced edge neutral density.

Zakharov, L. (Princeton Plasma Physics Laboratory, Princeton, NJ); Gates, D. (Princeton Plasma Physics Laboratory, Princeton, NJ); Menard, J. (Princeton Plasma Physics Laboratory, Princeton, NJ); Maingi, R. (Oak Ridge National Laboratory, Oak Ridge, TN); Schneider, H. (Princeton Plasma Physics Laboratory, Princeton, NJ); Mueller, D. (Princeton Plasma Physics Laboratory, Princeton, NJ); Wampler, William R.; Roquemore, A. L. (Princeton Plasma Physics Laboratory, Princeton, NJ); Kallman, Jeffrey K. (Princeton Plasma Physics Laboratory, Princeton, NJ); Sabbagh, S. (Columbia University, New York, NY); LeBlanc, B. (Princeton Plasma Physics Laboratory, Princeton, NJ); Raman, R. (University of Washington, Seattle, WA); Ono, M. (Princeton Plasma Physics Laboratory, Princeton, NJ); Wilgren, J. (Oak Ridge National Laboratory, Oak Ridge, TN); Allain, J.P. (Purdue University, West Lafayette, IN); Timberlake, J. (Princeton Plasma Physics Laboratory, Princeton, NJ); Stevenson, T. (Princeton Plasma Physics Laboratory, Princeton, NJ); Ross, P. W. (Princeton Plasma Physics Laboratory, Princeton, NJ); Majeski, R. (Princeton Plasma Physics Laboratory, Princeton, NJ); Kugel, Henry W. (Princeton Plasma Physics Laboratory, Princeton, NJ); Skinner, C. H. (Princeton Plasma Physics Laboratory, Princeton, NJ); Gerhardt, S. (Princeton Plasma Physics Laboratory, Princeton, NJ); Paul, S. (Princeton Plasma Physics Laboratory, Princeton, NJ); Bell, R. (Princeton Plasma Physics Laboratory, Princeton, NJ); Kaye, S. M. (Princeton Plasma Physics Laboratory, Princeton, NJ); Kaita, R. (Princeton Plasma Physics Laboratory, Princeton, NJ); Soukhanovskii, V. (Lawrence Livermore National Laboratory, Livermore, CA); Bell, Michael G. (Princeton Plasma Physics Laboratory, Princeton, NJ); Mansfield, D. (Princeton Plasma Physics Laboratory, Princeton, NJ)

2008-08-01T23:59:59.000Z

218

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions  

SciTech Connect (OSTI)

The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state Li4+xTi5O12/LiPON/LixV2O5 cell and examine in situ the chemistry of Li-O2 reaction products on LixV2O5 as a function of applied voltage under ultra high vacuum (UHV) and near ambient-pressure of oxygen using X-ray photoelectron spectroscopy (APXPS). Oxygen reduction and evolution reactions take place on the surface of the mixed electronic and Li+ ionic conductor, LixV2O5, which eliminate parasitic reactions between oxygen reduction/evolution reaction intermediates and aprotic electrolytes used in Li-O2 batteries reported to date. Under UHV, reversible lithium intercalation and de-intercalation from LixV2O5 was noted, where the changes in the vanadium valence state revealed from XPS in this study were comparable to that reported previously from Li/LixV2O5 thin film batteries. In presence of oxygen near ambient pressure, the LixV2O5 surface was covered gradually by the reaction product of oxygen reduction, namely lithium peroxide (Li2O2) (approximately 1-2 unit cells) upon discharge. Interestingly, the LixV2O5 surface became re-exposed upon charging, and the oxidation of Li2O2 began at much lower overpotentials (~240 mV) than the charge overpotentials of Li-O2 cells (~1000 mV) with aprotic electrolytes, which can be attributed to subnanometer-thick Li2O2 with surfaces free of contaminants such as carbonate species. Our study provides first evidence of reversible lithium peroxide formation and decomposition in situ on an oxide surface using a solid-state cell, and new insights into the reaction mechanism of Li-O2 chemistry.

Lu, Yi-chun [Massachusetts Institute of Technology (MIT); Crumlin, Ethan [Massachusetts Institute of Technology (MIT); Veith, Gabriel M [ORNL; Harding, Jonathon [Massachusetts Institute of Technology (MIT); Dudney, Nancy J [ORNL; Liu, Zhi [Lawrence Berkeley National Laboratory (LBNL); Shao-Horn, Yang [Massachusetts Institute of Technology (MIT)

2012-01-01T23:59:59.000Z

219

Mixed valency and site-preference chemistry for cerium and its compounds: A predictive density-functional theory study  

SciTech Connect (OSTI)

Cerium and its technologically relevant compounds are examples of anomalous mixed valency, originating from two competing oxidation states—itinerant Ce4+ and localized Ce3+. Under applied stress, anomalous transitions are observed but not well understood. Here we treat mixed valency as an “alloy” problem involving two valences with competing and numerous site-occupancy configurations. We use density-functional theory with Hubbard U (i.e., DFT+U) to evaluate the effective valence and predict properties, including controlling the valence by pseudoternary alloying. For Ce and its compounds, such as (Ce,La)2(Fe,Co)14B permanent magnets, we find a stable mixed-valent ? state near the spectroscopic value of ?s=3.53. Ce valency in compounds depends on its steric volume and local chemistry. For La doping, Ce valency shifts towards ?-like Ce3+, as expected from steric volume; for Co doping, valency depends on local Ce-site chemistry and steric volume. Our approach captures the key origins of anomalous valency and site-preference chemistry in complex compounds.

Alam, Aftab [Ames Laboratory; Johnson, Duane D. [Ames Laboratory

2014-06-01T23:59:59.000Z

220

Magnetic moment of atomic lithium  

Science Journals Connector (OSTI)

Bound-state relativistic contributions to the gJ factor of ground-state atomic lithium are calculated and compared with the experimental value gJ(Li)ge=1-(8.9±0.4)×10-6, where ge is the free-electron g factor. This comparison is taken as the basis for judging the accuracy of several different Li wave functions taken from the literature. Most of these wave functions give agreement with the experimental value within the experimental uncertainty. A more precise experimental measurement would be desirable in order to provide a more stringent test. A wave function of the restricted Hartree-Fock type, however, leads to a value which is in disagreement with the experimental value. This is attributed to the inability of the restricted Hartree-Fock function to account for the exchange polarization of the 1s2 core electrons; the latter are found to contribute about -1.2 × 10-6 to gJ(Li)ge, or about 13% of the total relativistic correction. In addition to the dominant relativistic corrections of order ?2, radiative corrections (order ?3), and nuclear-mass corrections (order ?2mM) are also calculated. An isotopic shift gJ(Li6)gJ(Li7)=1+3.0×10-11 is predicted. The experimental measurements for Li are not yet precise enough to test these higher-order corrections.

Roger A. Hegstrom

1975-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

A New Method for Quantitative Marking of Deposited Lithium via Chemical Treatment on Graphite Anodes in Lithium-Ion Cells  

E-Print Network [OSTI]

A New Method for Quantitative Marking of Deposited Lithium via Chemical Treatment on Graphite Anodes in Lithium-Ion Cells Yvonne Krämer*[a] , Claudia Birkenmaier[b] , Julian Feinauer[a,c] , Andreas*[e] and Thomas Schleid[f] Abstract: A novel approach for the marking of deposited lithium on graphite anodes from

Schmidt, Volker

222

New model for the mixed-valence phenomenon in rare-earth materials  

Science Journals Connector (OSTI)

A model of a single rare-earth atom in a transition metal is derived, and terms describing screening of charge fluctuations in the resonant l=3 scattering channels by the l=2 channels are included. Using the Tomonaga approximation, in which charge fluctuations are represented by bosons, the screening channels are replaced by a boson field, and the model takes on a particularly simple form, the Anderson model of a magnetic impurity, now coupled to the boson field. The mean-field theory of this model suggests that, unlike in the original Anderson model, the impurity can be in a state of slowly fluctuating valence, which we identify with the mixed-valence phenomenon in certain rare-earth materials. These results suggest that the mixed-valence effect may be purely electronic in origin.

F. D. M. Haldane

1977-03-01T23:59:59.000Z

223

CO{sub 2} capture properties of lithium silicates with different ratios of Li{sub 2}O/SiO{sub 2}: an ab initio thermodynamic and experimental approach  

SciTech Connect (OSTI)

The lithium silicates have attracted scientific interest due to their potential use as high-temperature sorbents for CO{sub 2} capture. The electronic properties and thermodynamic stabilities of lithium silicates with different Li{sub 2}O/SiO{sub 2} ratios (Li{sub 2}O, Li{sub 8}SiO{sub 6}, Li{sub 4}SiO{sub 4}, Li{sub 6}Si{sub 2}O{sub 7}, Li{sub 2}SiO{sub 3}, Li{sub 2}Si{sub 2}O{sub 5}, Li{sub 2}Si{sub 3}O{sub 7}, and a-SiO{sub 2}) have been investigated by combining first-principles density functional theory with lattice phonon dynamics. All these lithium silicates examined are insulators with band-gaps larger than 4.5 eV. By decreasing the Li{sub 2}O/SiO{sub 2} ratio, the first valence bandwidth of the corresponding lithium silicate increases. Additionally, by decreasing the Li{sub 2}O/SiO{sub 2} ratio, the vibrational frequencies of the corresponding lithium silicates shift to higher frequencies. Based on the calculated energetic information, their CO{sub 2} absorption capabilities were extensively analyzed through thermodynamic investigations on these absorption reactions. We found that by increasing the Li{sub 2}O/SiO{sub 2} ratio when going from Li{sub 2}Si{sub 3}O{sub 7} to Li{sub 8}SiO{sub 6}, the corresponding lithium silicates have higher CO{sub 2} capture capacity, higher turnover temperatures and heats of reaction, and require higher energy inputs for regeneration. Based on our experimentally measured isotherms of the CO{sub 2} chemisorption by lithium silicates, we found that the CO{sub 2} capture reactions are two-stage processes: (1) a superficial reaction to form the external shell composed of Li{sub 2}CO{sub 3} and a metal oxide or lithium silicate secondary phase and (2) lithium diffusion from bulk to the surface with a simultaneous diffusion of CO{sub 2} into the shell to continue the CO{sub 2} chemisorption process. The second stage is the rate determining step for the capture process. By changing the mixing ratio of Li{sub 2}O and SiO{sub 2}, we can obtain different lithium silicate solids which exhibit different thermodynamic behaviors. Based on our results, three mixing scenarios are discussed to provide general guidelines for designing new CO{sub 2} sorbents to fit practical needs.

Yuhua Duan, Yuhua; Pfeiffer, Heriberto; Li, Bingyun, Romero-Ibarra, Issis C; Sorescu, Dan C; Luebke, David; Halley, J Woods

2013-06-05T23:59:59.000Z

224

Power Consumption Prediction and Power-Aware Packing in Consolidated  

E-Print Network [OSTI]

Power Consumption Prediction and Power-Aware Packing in Consolidated Environments Jeonghwan Choi the power consumption of groups of colocated applications. Such characterization is crucial for effective prediction and enforcement of appropriate limits on power consumption--power budgets--within the data center

Urgaonkar, Bhuvan

225

Packing Hamilton Cycles in Random and Pseudo-Random Hypergraphs  

E-Print Network [OSTI]

Packing Hamilton Cycles in Random and Pseudo-Random Hypergraphs Alan Frieze Michael Krivelevich February 16, 2011 Abstract We say that a k-uniform hypergraph C is a Hamilton cycle of type , for some 1 Hamilton cycles. A slightly weaker result is given for = k/2. We also provide sufficient conditions

Krivelevich, Michael

226

Packing tight Hamilton cycles in 3-uniform hypergraphs Alan Frieze  

E-Print Network [OSTI]

Packing tight Hamilton cycles in 3-uniform hypergraphs Alan Frieze Michael Krivelevich Po-Shen Loh Abstract Let H be a 3-uniform hypergraph with n vertices. A tight Hamilton cycle C H of H can be covered by edge-disjoint tight Hamilton cycles, for n divisible by 4. Consequently, we

Frieze, Alan

227

Packing tight Hamilton cycles in 3-uniform hypergraphs Alan Frieze  

E-Print Network [OSTI]

Packing tight Hamilton cycles in 3-uniform hypergraphs Alan Frieze Carnegie Mellon University alan ploh@cmu.edu Abstract Consider a 3-uniform hypergraph H with n vertices. A tight Hamilton cycle C H by edge- disjoint tight Hamilton cycles, for n divisible by 4. Consequently, random 3-uniform hypergraphs

Krivelevich, Michael

228

Hydrogen Bonding Increases Packing Density in the Protein Interior  

E-Print Network [OSTI]

Hydrogen Bonding Increases Packing Density in the Protein Interior David Schell,1,2 Jerry Tsai,1 J System Health Science Center, College Station, Texas 77843-1114 ABSTRACT The contribution of hydrogen to the stability, but experimental studies show that bury- ing polar groups, especially those that are hydrogen

229

Moisture Transport in Silica Gel Packed Beds: II. Experimental Study  

SciTech Connect (OSTI)

Experiments have been performed to obtain the transient response of a thin adiabatic packed bed of silica gel after a step change in inlet air conditions, comparisons are made with predictions using a solid-side resistance model and a pseudo-gas-side controlled model and better agreement obtained with the former model.

Pesaran, A. A.; Mills, A. F.

1986-08-01T23:59:59.000Z

230

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents [OSTI]

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

231

Paramagnon picture of the low-temperature susceptibility of some intermediate-valence compounds  

SciTech Connect (OSTI)

We show that the low-temperature susceptibility of Ce(In,Sn)/sub 3/ compounds has a quadratic temperature dependence with positive coefficient. We demonstrate that this behavior is well accounted for by a generalization to arbitrary band shapes of the paramagnon theory, which has been applied previously to liquid /sup 3/He. This result is relevant to the whole class of mixed-valence materials. We conclude that the previously proposed phenomenology that treats valence-fluctuation materials as heavy, nearly magnetic Fermi liquids finds further support in the present analysis.

Beal-Monod, M.T.; Lawrence, J.M.

1980-06-01T23:59:59.000Z

232

Lithium-based Technologies | Y-12 National Security Complex  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lithium-based Technologies Lithium-based Technologies Lithium-based Technologies Y-12's 60 years of rich lithium operational history and expertise make it the clear choice for deployment of new lithium-based technologies and capabilities. There is no other U.S. site, government or commercial, that comes close to the breadth of Y-12's lithium expertise and capabilities. The Y-12 National Security Complex supplies lithium, in unclassified forms, to customers worldwide through the DOE Office of Science, Isotope Business Office. Historically, the typical order of 6Li was only gram quantities used in research and development. However, over the past three years demand has increased steadily with typical orders of around 10-20 kg each. Such increase in demand is a direct result of the use of

233

Lithium Surface Coatings for Improved Plasma Performance in NSTX  

SciTech Connect (OSTI)

NSTX high-power divertor plasma experiments have shown, for the first time, significant and frequent benefits from lithium coatings applied to plasma facing components. Lithium pellet injection on NSTX introduced lithium pellets with masses 1 to 5 mg via He discharges. Lithium coatings have also been applied with an oven that directed a collimated stream of lithium vapor toward the graphite tiles of the lower center stack and divertor. Lithium depositions from a few mg to 1 g have been applied between discharges. Benefits from the lithium coating were sometimes, but not always seen. These improvements sometimes included decreases plasma density, inductive flux consumption, and ELM frequency, and increases in electron temperature, ion temperature, energy confinement and periods of MHD quiescence. In addition, reductions in lower divertor D, C, and O luminosity were measured.

Kugel, H W; Ahn, J -W; Allain, J P; Bell, R; Boedo, J; Bush, C; Gates, D; Gray, T; Kaye, S; Kaita, R; LeBlanc, B; Maingi, R; Majeski, R; Mansfield, D; Menard, J; Mueller, D; Ono, M; Paul, S; Raman, R; Roquemore, A L; Ross, P W; Sabbagh, S; Schneider, H; Skinner, C H; Soukhanovskii, V; Stevenson, T; Timberlake, J; Wampler, W R

2008-02-19T23:59:59.000Z

234

Nanostructured lithium-aluminum alloy electrodes for lithium-ion batteries.  

SciTech Connect (OSTI)

Electrodeposited aluminum films and template-synthesized aluminum nanorods are examined as negative electrodes for lithium-ion batteries. The lithium-aluminum alloying reaction is observed electrochemically with cyclic voltammetry and galvanostatic cycling in lithium half-cells. The electrodeposition reaction is shown to have high faradaic efficiency, and electrodeposited aluminum films reach theoretical capacity for the formation of LiAl (1 Ah/g). The performance of electrodeposited aluminum films is dependent on film thickness, with thicker films exhibiting better cycling behavior. The same trend is shown for electron-beam deposited aluminum films, suggesting that aluminum film thickness is the major determinant in electrochemical performance regardless of deposition technique. Synthesis of aluminum nanorod arrays on stainless steel substrates is demonstrated using electrodeposition into anodic aluminum oxide templates followed by template dissolution. Unlike nanostructures of other lithium-alloying materials, the electrochemical performance of these aluminum nanorod arrays is worse than that of bulk aluminum.

Hudak, Nicholas S.; Huber, Dale L.

2010-12-01T23:59:59.000Z

235

Lithium pellet production (LiPP): A device for the production of small spheres of lithium  

SciTech Connect (OSTI)

With lithium as a fusion material gaining popularity, a method for producing lithium pellets relatively quickly has been developed for NSTX. The Lithium Pellet Production device is based on an injector with a sub-millimeter diameter orifice and relies on a jet of liquid lithium breaking apart into small spheres via the Plateau-Rayleigh instability. A prototype device is presented in this paper and for a pressure difference of {Delta}P= 5 Torr, spheres with diameters between 0.91 < D < 1.37 mm have been produced with an average diameter of D= 1.14 mm, which agrees with the developed theory. Successive tests performed at Princeton Plasma Physics Laboratory with Wood's metal have confirmed the dependence of sphere diameter on pressure difference as predicted.

Fiflis, P.; Andrucyzk, D.; McGuire, M.; Curreli, D.; Ruzic, D. N. [Center for Plasma Material Interactions, Department of Nuclear, Plasma, and Radiological Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Roquemore, A. L. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08540 (United States)

2013-06-15T23:59:59.000Z

236

An Advanced Lithium-Ion Battery Based on a Graphene Anode and a Lithium Iron Phosphate Cathode  

Science Journals Connector (OSTI)

An Advanced Lithium-Ion Battery Based on a Graphene Anode and a Lithium Iron Phosphate Cathode ... To the best of our knowledge, complete, graphene-based, lithium ion batteries having performances comparable with those offered by the present technology are rarely reported; hence, we believe that the results disclosed in this work may open up new opportunities for exploiting graphene in the lithium-ion battery science and development. ... A full Li-ion battery (Figure 4a) is obtained by coupling the Cu-supported graphene nanoflake anode with a lithium iron phosphate, LiFePO4, that is, a cathode commonly used in commercial batteries. ...

Jusef Hassoun; Francesco Bonaccorso; Marco Agostini; Marco Angelucci; Maria Grazia Betti; Roberto Cingolani; Mauro Gemmi; Carlo Mariani; Stefania Panero; Vittorio Pellegrini; Bruno Scrosati

2014-07-15T23:59:59.000Z

237

Modeling the lubrication of the piston ring pack in internal combustion engines using the deterministic method  

E-Print Network [OSTI]

Piston ring packs are used in internal combustion engines to seal both the high pressure gas in the combustion chamber and the lubricant oil in the crank case. The interaction between the piston ring pack and the cylinder ...

Chen, Haijie

2011-01-01T23:59:59.000Z

238

Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CellPack Level Models for Automotive Li-Ion Batteries with Experimental Validation Development of CellPack Level Models for Automotive Li-Ion Batteries with Experimental...

239

Determinants of Backbone Packing in Globular Proteins: an Analysis of Spatial Neighbours  

Science Journals Connector (OSTI)

The pattern and variability of backbone packing density in protein structures are examined. An interesting correlation between the average percentage composition of amino acids and the percentage composition in regions corresponding to different levels of packing density has been observed.

Panjikar, S.K.

1997-11-01T23:59:59.000Z

240

Effects of lubricant viscosity and surface texturing on ring-pack performance in internal combustion engines  

E-Print Network [OSTI]

The piston ring-pack contributes approximately 25% of the mechanical losses in an internal combustion engine. Both lubricant viscosity and surface texturing were investigated in an effort to reduce this ring-pack friction ...

Takata, Rosalind (Rosalind Kazuko), 1978-

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The effect of surface finish on piston ring-pack performance in advanced reciprocating engine systems  

E-Print Network [OSTI]

Frictional losses in the piston ring-pack of an engine account for approximately 20% of the total frictional losses within an engine. Methods of surface texture optimization were investigated to reduce piston ring-pack ...

Jocsak, Jeffrey (Jeffrey Alan)

2005-01-01T23:59:59.000Z

242

Muon Spin Relaxation Studies of Lithium Nitridometallate Battery Materials: Muon Trapping and Lithium Ion Diffusion  

Science Journals Connector (OSTI)

Muon Spin Relaxation Studies of Lithium Nitridometallate Battery Materials: Muon Trapping and Lithium Ion Diffusion ... The muons themselves are quasi-static, most probably located in a 4h site between the [Li2N] plane and the Li(1)/Ni layer. ... The initial fall in ? results from an increase in muon hopping as the temperature is raised, while the subsequent rise originates from an increasing proportion of trapped and therefore static muons. ...

Andrew S. Powell; James S. Lord; Duncan H. Gregory; Jeremy J. Titman

2009-10-27T23:59:59.000Z

243

New packing in absorption systems for trapping benzene from coke-oven gas  

SciTech Connect (OSTI)

The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

244

Novel synthesis process and structure refinements of Li4Mn5O12 for rechargeable lithium batteries  

Science Journals Connector (OSTI)

Well-crystallized Li4Mn5O12 powder with grain size of 0.1–0.4 ?m was prepared by heating a eutectic mixture of lithium acetate (LiOAc), and manganese nitrate (Mn(NO3)2), in an oxygen atmosphere. The structure of Li4Mn5O12 crystallites was found to be a cubic spinel using Rietveld refinement of both neutron and X-ray powder diffraction data. We confirmed that lithium ions occupy both the tetrahedral 8a sites, and part of the octahedral 16d sites, but not the 16c sites in the space group Fd3m, while all the manganese ions occupy the 16d sites. The lattice parameter was found to be sensitive to the synthesis temperature as a result of the variation in manganese valence. Samples prepared at 500 °C showed better electrode performance. A rechargeable capacity of about 135 mAh/g for the cell Li/Li4Mn5O12 was obtained in the 2.5–3.6 V range of cell voltages.

Toshimi Takada; Hiroshi Hayakawa; Etsuo Akiba; Fujio Izumi; Bryan C. Chakoumakos

1997-01-01T23:59:59.000Z

245

Lithium: Will Short Supply Constrain Energy Technologies?  

Science Journals Connector (OSTI)

...developments have improved the storage capacity and lifetime...century. Utility electric storage-a projected 1000 units...parts per million are pumped to the surface, concentrated...area currently being pumped. Kunasz says that the...recovering lithium from seawater, although few geologists...

ALLEN L. HAMMOND

1976-03-12T23:59:59.000Z

246

Nanocarbon Networks for Advanced Rechargeable Lithium Batteries  

Science Journals Connector (OSTI)

His research focuses on energy storage and conversion with batteries, fuel cells, and solar cells. ... As an important type of secondary battery, lithium-ion batteries (LIBs) have quickly dominated the market for consumer electronics and become one of key technologies in the battery industry after their first release by Sony Company in the early 1990s. ...

Sen Xin; Yu-Guo Guo; Li-Jun Wan

2012-09-06T23:59:59.000Z

247

Rechargeable thin-film lithium batteries  

SciTech Connect (OSTI)

Rechargeable thin-film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. These include Li-TiS{sub 2}, Li-V{sub 2}O{sub 5}, and Li-Li{sub x}Mn{sub 2}O{sub 4} cells with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The realization of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46}and a conductivity at 25 C of 2 {mu}S/cm. The thin-film cells have been cycled at 100% depth of discharge using current densities of 5 to 100 {mu}A/cm{sup 2}. Over most of the charge-discharge range, the internal resistance appears to be dominated by the cathode, and the major source of the resistance is the diffusion of Li{sup +} ions from the electrolyte into the cathode. Chemical diffusion coefficients were determined from ac impedance measurements.

Bates, J.B.; Gruzalski, G.R.; Dudney, N.J.; Luck, C.F.; Yu, X.

1993-09-01T23:59:59.000Z

248

Thin-film Rechargeable Lithium Batteries  

DOE R&D Accomplishments [OSTI]

Rechargeable thin films batteries with lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. The cathodes include TiS{sub 2}, the {omega} phase of V{sub 2}O{sub 5}, and the cubic spinel Li{sub x}Mn{sub 2}O{sub 4} with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The development of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25 C of 2 {mu}S/cm. Thin film cells have been cycled at 100% depth of discharge using current densities of 2 to 100 {mu}A/cm{sup 2}. The polarization resistance of the cells is due to the slow insertion rate of Li{sup +} ions into the cathode. Chemical diffusion coefficients for Li{sup +} ions in the three types of cathodes have been estimated from the analysis of ac impedance measurements.

Bates, J. B.; Gruzalski, G. R.; Dudney, N. J.; Luck, C. F.; Yu, X.

1993-11-00T23:59:59.000Z

249

NSTX plasma response to lithium coated divertor  

SciTech Connect (OSTI)

NSTX experiments have explored lithium evaporated on a graphite divertor and other plasma-facing components in both L- and H- mode confinement regimes heated by high-power neutral beams. Improvements in plasma performance have followed these lithium depositions, including a reduction and eventual elimination of the HeGDC time between discharges, reduced edge neutral density, reduced plasma density, particularly in the edge and the SOL, increased pedestal electron and ion temperature, improved energy confinement and the suppression of ELMs in the H-mode. However, with improvements in confinement and suppression of ELMs, there was a significant secular increase in the effective ion charge Z(eff) and the radiated power in H-mode plasmas as a result of increases in the carbon and medium-Z metallic impurities. Lithium itself remained at a very low level in the plasma core, < 0.1%. Initial results are reported from operation with a Liquid Lithium Divertor (LLD) recently installed. (C) 2010 Elsevier B.V. All rights reserved.

Kugel, H. W. [Princeton Plasma Physics Laboratory (PPPL); Bell, M. G. [Princeton Plasma Physics Laboratory (PPPL); Allain, J. P. [Purdue University; Bell, R. E. [Princeton Plasma Physics Laboratory (PPPL); Ding, S. [Academia Sinica, Institute of Plasma Physics, Hefei, China; Gerhardt, S. P. [Princeton Plasma Physics Laboratory (PPPL); Jaworski, M. A. [Princeton Plasma Physics Laboratory (PPPL); Kaita, R. [Princeton Plasma Physics Laboratory (PPPL); Kallman, J. [Princeton Plasma Physics Laboratory (PPPL); Kaye, S. M. [Princeton Plasma Physics Laboratory (PPPL); LeBlanc, B. P. [Princeton Plasma Physics Laboratory (PPPL); Maingi, Rajesh [ORNL; Majeski, R. [Princeton Plasma Physics Laboratory (PPPL); Maqueda, R. J. [Princeton Plasma Physics Laboratory (PPPL); Mansfield, D.K. [Princeton Plasma Physics Laboratory (PPPL); Mueller, D. [Princeton Plasma Physics Laboratory (PPPL); Nygren, R. E. [Sandia National Laboratories (SNL); Paul, S. F. [Princeton Plasma Physics Laboratory (PPPL); Raman, R [University of Washington, Seattle; Roquemore, A. L. [Princeton Plasma Physics Laboratory (PPPL); Sabbagh, S. A. [Columbia University; Schneider, H. [Princeton Plasma Physics Laboratory (PPPL); Skinner, C. H. [Princeton Plasma Physics Laboratory (PPPL); Soukhanovskii, V. A. [Lawrence Livermore National Laboratory (LLNL); Taylor, C. N. [Purdue University; Timberlake, J. [Princeton Plasma Physics Laboratory (PPPL); Wampler, W. R. [Sandia National Laboratories (SNL); Zakharov, L. E. [Princeton Plasma Physics Laboratory (PPPL); Zweben, S. J. [Princeton Plasma Physics Laboratory (PPPL)

2011-01-01T23:59:59.000Z

250

Electrothermal Analysis of Lithium Ion Batteries  

SciTech Connect (OSTI)

This report presents the electrothermal analysis and testing of lithium ion battery performance. The objectives of this report are to: (1) develop an electrothermal process/model for predicting thermal performance of real battery cells and modules; and (2) use the electrothermal model to evaluate various designs to improve battery thermal performance.

Pesaran, A.; Vlahinos, A.; Bharathan, D.; Duong, T.

2006-03-01T23:59:59.000Z

251

Mixed valence and spin fluctuations in Ce(Ni, Co)/sub 2/ and related systems  

SciTech Connect (OSTI)

The pseudobinary alloys Ce(Ni/sub x/Co/sub 1-x/)/sub 2/, (Ce/sub x/La/sub 1-x/)Ni/sub 2/ and (Ce/sub x/Y/sub 1-x/)Ni/sub 2/, where 0 < x < 1, were studied. The room-temperature lattice constant, the magnetic susceptibility in the 6 to 300 K temperature range, the low-temperature specific heat in the 0.4 to 25 K range, and the electrical resistivity in the 0.4 to 300 K range were measured. Additionally, x-ray absorption around the L/sub 3/ edge was studied using the synchroton radiation. Both thermodynamic and L/sub 3/ probes yield similar results for the changes of valence of Ce across these systems. It was established that Ce is in the saturated valence state in the Ce(Ni/sub x/Co/sub 1-x/)/sub 2/ for x < 0.25. The valence decreases with x in the 0.25 to 1 concentration range. Similarly, the valence of Ce decreases in the (Ce, Y)Ni/sub 2/ systems upon substitution of Y for Ce. The results obtained for the (Ce/sub x/La/sub 1-x/)Ni/sub 2/ system are interpreted in terms of changes of the Ce/sup 3 +/ impurity levels. Spin fluctuations due to the 3d electrons play an important role in these systems

Andraka, B.

1986-01-01T23:59:59.000Z

252

Light hadron spectroscopy using domain wall valence quarks on an asqtad sea  

E-Print Network [OSTI]

We calculate the light hadron spectrum in full QCD using two plus one flavor asqtad sea quarks and domain wall valence quarks. Meson and baryon masses are calculated on a lattice of spatial size L?2.5??fm, and a lattice ...

Walker-Loud, A.

253

Mixed-Valence Minerals of Iron and Titanium: Correlations of Structural, Mössbauer and Electronic Spectral Data  

Science Journals Connector (OSTI)

A large cariety of mixed-valence silicate and oxide minerals occur in rocks from the Earth, Moon and Meteorites, They frequently contain Fe2+ -Fe3+, Ti3+ -Ti4+ and Fe2+ -Ti4+ assemblages and often display anomalo...

Roger G. Burns; D. A. Nolet; K. M. Parkin; C. A. McCammon…

1980-01-01T23:59:59.000Z

254

Composition dependent valence band order in c-oriented wurtzite AlGaN layers  

SciTech Connect (OSTI)

The valence band order of polar wurtzite aluminum gallium nitride (AlGaN) layers is analyzed for a dense series of samples, grown heteroepitaxially on sapphire substrates, covering the complete composition range. The excitonic transition energies, found by temperature dependent photoluminescence (PL) spectroscopy, were corrected to the unstrained state using input from X-ray diffraction. k?p theory yields a critical relative aluminum concentration x{sub c}=(0.09±0.05) for the crossing of the uppermost two valence bands for strain free material, shifting to higher values for compressively strained samples, as supported by polarization dependent PL. The analysis of the strain dependent valence band crossing reconciles the findings of other research groups, where sample strain was neglected. We found a bowing for the energy band gap to the valence band with ?{sub 9} symmetry of b{sub ?{sub 9}}=0.85eV, and propose a possible bowing for the crystal field energy of b{sub cf}=?0.12eV. A comparison of the light extraction efficiency perpendicular and parallel to the c axis of Al{sub x}Ga{sub 1-x}N/Al{sub y}Ga{sub 1-y}N quantum well structures is discussed for different compositions.

Neuschl, B., E-mail: benjamin.neuschl@uni-ulm.de; Helbing, J.; Knab, M.; Lauer, H.; Madel, M.; Thonke, K. [Institute of Quantum Matter / Semiconductor Physics Group, University of Ulm, Albert-Einstein-Allee 45, 89069 Ulm (Germany); Meisch, T.; Forghani, K.; Scholz, F. [Institute of Optoelectronics, University of Ulm, Albert-Einstein-Allee 45, 89069 Ulm (Germany); Feneberg, M. [Institut für Experimentelle Physik, Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, 39106 Magdeburg (Germany)

2014-09-21T23:59:59.000Z

255

Mapping the Valence States of Transition-Metal Elements Using Energy-Filtered Transmission Electron Microscopy  

E-Print Network [OSTI]

spectrum of MnO2 acquired at 200 kV using a Hitachi HF-2000 transmission electron microscope equipped lines observed in electron energy-loss spectroscopy in a transmission electron microscope (TEMMapping the Valence States of Transition-Metal Elements Using Energy-Filtered Transmission Electron

Wang, Zhong L.

256

Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy  

Science Journals Connector (OSTI)

...overabsorption, many of the references were run in total electron yield mode. For others...the slope of the valence = f (energy) straight line. Therefore, the only way to improve...methylcyclopentadienyl) manganese tricarbonyl-added gasolines using XANES spectroscopy. Environmental...

Alain Manceau; Matthew A. Marcus; Sylvain Grangeon

257

Implications of NSTX Lithium Results for Magnetic Fusion Research  

SciTech Connect (OSTI)

Lithium wall coating techniques have been experimentally explored on NSTX for the last five years. The lithium experimentation on NSTX started with a few milligrams of lithium injected into the plasma as pellets and it has evolved to a lithium evaporation system which can evaporate up to ~ 100 g of lithium onto the lower divertor plates between lithium reloadings. The unique feature of the lithium research program on NSTX is that it can investigate the effects of lithium in H-mode divertor plasmas. This lithium evaporation system thus far has produced many intriguing and potentially important results; the latest of these are summarized in a companion paper by H. Kugel. In this paper, we suggest possible implications and applications of the NSTX lithium results on the magnetic fusion research which include electron and global energy confinement improvements, MHD stability enhancement at high beta, ELM control, H-mode power threshold reduction, improvements in radio frequency heating and non-inductive plasma start-up performance, innovative divertor solutions and improved operational efficiency.

M. Ono, M.G. Bell, R.E. Bell, R. Kaita, H.W. Kugel, B.P. LeBlanc, J.M. Canik, S. Diem, S.P.. Gerhardt, J. Hosea, S. Kaye, D. Mansfield, R. Maingi, J. Menard, S. F. Paul, R. Raman, S.A. Sabbagh, C.H. Skinner, V. Soukhanovskii, G. Taylor, and the NSTX Research Team

2010-01-14T23:59:59.000Z

258

A study of a cooling tower with variable packing geometries  

E-Print Network [OSTI]

of the Meohanioal Engineering Department~ for giving generously of his time, advioey and experi ense. STMKRY Three redwood packing styles -- rectangular~ square and triangular, having the same projected, area ? were tested under the same controlled conditions... of this wozk is to study the influence of the paoking geometries on water cooling tower performance oh raoteristics. To fulfill the purpose, thz ee different redwood paoking , . eometz'ies were tested and oompared. These ere z ectangular, square...

Azad, Abul Kalam

2012-06-07T23:59:59.000Z

259

Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperature  

E-Print Network [OSTI]

Protection for 4 V Lithium Batteries at High Rates and LowRechargeable lithium batteries are known for their highBecause lithium ion batteries are especially susceptible to

Chen, Guoying

2010-01-01T23:59:59.000Z

260

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

Linden, D. , Handbook of Batteries. 2nd ed. 1995, New York:rechargeable lithium batteries. Nature, 2001. 414(6861): p.of rechargeable lithium batteries, I. Lithium manganese

Wilcox, James D.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

SURFACE RECONSTRUCTION AND CHEMICAL EVOLUTION OF STOICHIOMETRIC LAYERED CATHODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

CATHODE MATERIALS FOR LITHIUM-ION BATTERIES Feng Lin, 1*As shown in Figure 2, in lithium-metal half-cells, capacitypredominantly occurs along the lithium diffusion channels,

Lin, Feng

2014-01-01T23:59:59.000Z

262

Solid state thin film battery having a high temperature lithium alloy anode  

DOE Patents [OSTI]

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

Hobson, David O. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

263

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

around 3.5 M. A slight excess of lithium (5%) was used tothat there is a slight excess of lithium in materials withto the formation of a lithium excess surface material (Li 1+

Wilcox, James D.

2010-01-01T23:59:59.000Z

264

Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates  

Science Journals Connector (OSTI)

Flexible graphene-based lithium ion batteries with ultrafast charge and...and flexible lithium ion battery made from graphene foam, a three-dimensional...and flexible lithium ion battery made from graphene foam, a three-dimensional...

Na Li; Zongping Chen; Wencai Ren; Feng Li; Hui-Ming Cheng

2012-01-01T23:59:59.000Z

265

Stress fields in hollow core–shell spherical electrodes of lithium ion batteries  

Science Journals Connector (OSTI)

...core-shell spherical electrodes of lithium ion batteries Yingjie Liu 1 Pengyu Lv...System, Department of Mechanics and Engineering Science, College of Engineering...structure design of electrodes of lithium ion batteries. lithium ion battery...

2014-01-01T23:59:59.000Z

266

Correlate the flooding of packed columns a new way  

SciTech Connect (OSTI)

Packed-column pressure-drop and flooding-point prediction has received new attention recently. These publications, like most earlier ones, focus on gas-flow-induced pressure drop, and flooding due to liquid entrainment in the packing. A few years ago, some problems occurred when packing was applied in high-pressure distillation service, such as ethylene and propylene superfractionators. Apparently, the maximum liquid-through-put capacity was lower than predicted from the gas-flow-induced flooding correlations. Such situation exists when predicting the performance of valve trays in similar service: liquid downflow can be limiting before entrainment flooding occurs. The reason for this behavior is the relatively low liquid and high vapor density of these high-pressure services. The liquid/vapor density ratios are typically 10--15:1 for such hydrocarbon systems. In contrast, for low-pressure water/air systems, this ratio is in the range 300--800:1. A large amount of experimental data for low-pressure systems has been used to correlate pressure drop and flooding, but it doesn't cover the technically important region of low liquid and high vapor density. This Article suggests an approach for understanding such liquid-limited systems.

Kaiser, V.

1994-06-01T23:59:59.000Z

267

Polymers with Tailored Electronic Structure for High Capacity Lithium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polymers with Tailored Electronic Structure for High Capacity Lithium Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes Title Polymers with Tailored Electronic Structure for High Capacity Lithium Battery Electrodes Publication Type Journal Article Year of Publication 2011 Authors Liu, Gao, Shidi Xun, Nenad Vukmirovic, Xiangyun Song, Paul Olalde-Velasco, Honghe Zheng, Vince S. Battaglia, Linwang Wang, and Wanli Yang Journal Advanced Materials Volume 23 Start Page 4679 Issue 40 Pagination 4679 - 4683 Date Published 10/2011 Keywords binders, conducting polymers, density funcational theory, lithium batteries, X-ray spectroscopy Abstract A conductive polymer is developed for solving the long-standing volume change issue in lithium battery electrodes. A combination of synthesis, spectroscopy and simulation techniques tailors the electronic structure of the polymer to enable in situ lithium doping. Composite anodes based on this polymer and commercial Si particles exhibit 2100 mAh g-1 in Si after 650 cycles without any conductive additive.

268

Lithium In Tufas Of The Great Basin- Exploration Implications For  

Open Energy Info (EERE)

In Tufas Of The Great Basin- Exploration Implications For In Tufas Of The Great Basin- Exploration Implications For Geothermal Energy And Lithium Resources Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Lithium In Tufas Of The Great Basin- Exploration Implications For Geothermal Energy And Lithium Resources Details Activities (8) Areas (4) Regions (0) Abstract: Lithium/magnesium, lithium/sodium, and to a lesser extent, potassium/magnesium ratios in calcium carbonate tufa columns provide a fingerprint for distinguishing tufa columns formed from thermal spring waters versus those formed from non-thermal spring waters. These ratios form the basis of the Mg/Li, Na/Li, and K/Mg fluid geothermometers commonly used in geothermal exploration, which are based on the fact that at elevated temperatures, due to mineral-fluid equilibria, lithium

269

Synthesis of lithium intercalation materials for rechargeable battery  

Science Journals Connector (OSTI)

Lithium-based oxides (LiMOx, where M=Ni, Co, Mn) are attractive for electrode materials, because they are capable of reversibly intercalating lithium ions for rechargeable battery without altering the main unit. We developed a novel solution-based route for the synthesis of these lithium intercalation oxides, using acetates or oxides as precursors for lithium, manganese, nickel, and cobalt, respectively with proper organic solvents. The evolution of crystal structure of these materials was analyzed by X-ray diffraction. Further analysis of LiMn2O4 samples were carried out using impedance spectroscopy and Raman spectroscopy. These studies indicate that this synthetic route, without using expensive alkoxides of sol–gel process, produces high-quality lithium-based oxides useful for cathode in lithium-ion rechargeable battery.

S. Nieto-Ramos; M.S. Tomar

2001-01-01T23:59:59.000Z

270

E-Print Network 3.0 - accumulateurs au lithium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

au lithium Search Powered by Explorit Topic List Advanced Search Sample search results for: accumulateurs au lithium Page: << < 1 2 3 4 5 > >> 1 ACCUMULATEUR LECTRIQUE...

271

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries 2011 DOE...

272

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries...

273

Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries  

Science Journals Connector (OSTI)

Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries ... Lithium battery; cathode; polymer; graphene; nanocomposite ...

Zhiping Song; Terrence Xu; Mikhail L. Gordin; Ying-Bing Jiang; In-Tae Bae; Qiangfeng Xiao; Hui Zhan; Jun Liu; Donghai Wang

2012-03-26T23:59:59.000Z

274

Insights into the morphological changes undergone by the anode in the lithium sulphur battery system.  

E-Print Network [OSTI]

?? In this thesis, the morphological changes of the anode surface in lithium sulphur cell, during early cycling, were simulated using symmetrical lithium electrode cells… (more)

Yalamanchili, Anurag

2014-01-01T23:59:59.000Z

275

Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with Self-Aligned Nanorod Structure. Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure. Abstract: Suppressing lithium (Li) dendrite growth is one of the most...

276

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

2 H 3 O 2 Li·2H 2 O (lithium acetate, Sigma Aldrich), and HThe iron nitrate and lithium acetate were combined with the

Wilcox, James D.

2010-01-01T23:59:59.000Z

277

Lithium: Measurement of Young's Modulus and Yield Strength  

SciTech Connect (OSTI)

The Lithium Collection Lens is used for anti-proton collection. In analyzing the structural behavior during operation, various material properties of lithium are often needed. properties such as density, coefficient of thermal expansion, thermal conductivity, specific heat, compressability, etc.; are well known. However, to the authors knowledge there is only one published source for Young's Modulus. This paper reviews the results from the testing of Young's Modulus and the yield strength of lithium at room temperature.

Ryan P Schultz

2002-11-07T23:59:59.000Z

278

Facile synthesis of mesoporous lithium titanate spheres for high rate lithium-ion batteries  

Science Journals Connector (OSTI)

Lithium titanate is synthesized from titanium isopropoxide and lithium acetate solution under hydrothermal environment and calcinations. Introducing acidized carbon black during synthesis can produce mesoporous Li4Ti5O12. The crystalline structure and morphological observation of the as-synthesized mesoporous Li4Ti5O12 are characterized by X-ray diffraction (XRD) and scanning electron microscopy, respectively. The mesoporous structure can be directly observed through BEI images of the cross-section sample. Besides, N2 adsorption/desorption isotherm also displays a hysteresis loop, implying the beneficial evidence of mesoporous structure. The pore size distribution of mesoporous lithium titanate evaluated by BJH model is narrow, and the average size of voids is around 4 nm. It is demonstrated that the electrochemical performance is significantly improved by the mesoporous structure. The mesoporous lithium titanate exhibits a stable capacity of 140 mAhg?1 at 0.5 C. Besides, the reversible capacity at 30 C remains over half of that at 0.5 C. The superior C-rate performance is associated with the mesoporous structure, facilitating lithium transportation ability during cycling.

Yu-Sheng Lin; Jenq-Gong Duh

2011-01-01T23:59:59.000Z

279

Visualization of Charge Distribution in a Lithium Battery Electrode  

E-Print Network [OSTI]

Distribution in Thin-Film Batteries. J. Electrochem. Soc.of Lithium Polymer Batteries. J. Power Sources 2002, 110,for Rechargeable Li Batteries. Chem. Mater. 2010, 15. Padhi,

Liu, Jun

2010-01-01T23:59:59.000Z

280

Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single...

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Advanced Materials Find More Like This Return to Search LithiumSulfur Batteries Based on Doped Mesoporous Carbon Oak Ridge National Laboratory Contact ORNL About...

282

Lithium Ion Electrode Production NDE and QC Considerations |...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

QC Considerations Lithium Ion Electrode Production NDE and QC Considerations Review of Oak Ridge process and QC activities by David Wood, Oak Ridge National Laboratory, at the...

283

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for LithiumSulfur Cells Lawrence Berkeley National...

284

Fact #603: December 28, 2009 Where Does Lithium Come From? |...  

Broader source: Energy.gov (indexed) [DOE]

share of lithium reserves and production by country including Chile, China, Australia, Russia, Argentina, U.S. and Bolivia. For more detailed information, see the table below....

285

Physically based Impedance Modelling of Lithium-Ion Cells.  

E-Print Network [OSTI]

??In this book, a new procedure to analyze lithium-ion cells is introduced. The cells are disassembled to analyze their components in experimental cell housings. Then,… (more)

Illig, Jörg

2014-01-01T23:59:59.000Z

286

Binding and Diffusion of Lithium in Graphite: Quantum Monte Carlo...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Binding and Diffusion of Lithium in Graphite: Quantum Monte Carlo Benchmarks and Validation of van der Waals Density Functional Methods P. Ganesh,* , Jeongnim Kim, Changwon...

287

JCESR: Moving Beyond Lithium-Ion | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

JCESR: Moving Beyond Lithium-Ion Share Topic Energy Energy usage Energy storage Batteries Browse By - Any - Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive...

288

Overcoming Processing Cost Barriers of High-Performance Lithium...  

Broader source: Energy.gov (indexed) [DOE]

methods - Tailored Aqueous Colloids for Lithium-Ion Electrodes (TACLE) B.L. Armstrong et al., U.S. Patent Application No. 13651,270. - Surface charge measurement,...

289

The UC Davis Emerging Lithium Battery Test Project  

E-Print Network [OSTI]

lithium titanate oxide in the negative electrode indicate cycle life in excesslithium titanate oxide in the negative electrode indicate cycle life in excess

Burke, Andy; Miller, Marshall

2009-01-01T23:59:59.000Z

290

High capacity nanostructured electrode materials for lithium-ion batteries.  

E-Print Network [OSTI]

??The lithium-ion battery is currently the most widely used electrochemical storage system on the market, with applications ranging from portable electronics to electric vehicles, to… (more)

Seng, Kuok H

2013-01-01T23:59:59.000Z

291

Expanded North Carolina Lithium Facility Opens, Boosting U.S...  

Broader source: Energy.gov (indexed) [DOE]

plug-in hybrids and other advanced clean energy technologies grows worldwide, rare earth elements and other critical materials, including lithium, are facing increasing global...

292

California: Geothermal Plant to Help Meet High Lithium Demand...  

Energy Savers [EERE]

technologies that extract battery materials like lithium, manganese, and zinc from geothermal brines. Simbol has the potential to power 300,000-600,000 electric vehicles per...

293

California Geothermal Power Plant to Help Meet High Lithium Demand...  

Energy Savers [EERE]

brines in California. Batteries from Brine California: Geothermal Plant to Help Meet High Lithium Demand Mineral Recovery Creates Revenue Stream for Geothermal Energy Development...

294

Overcoming Processing Cost Barriers of High-Performance Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cost Barriers of High-Performance Lithium-Ion Battery Electrodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

295

Development of Large Format Lithium Ion Cells with Higher Energy...  

Broader source: Energy.gov (indexed) [DOE]

Overall Project Goal: To research, develop and demonstrate large format lithium ion cells with energy density > 500 WhL Barriers addressed: - Low energy density - Cost -...

296

Sandia National Laboratories: lithium-ion-based solid electrolyte...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lithium-ion-based solid electrolyte battery Sandia Labs, Front Edge Technology, Inc., Pacific Northwest National Lab, Univ. of California-Los Angeles: Micro Power Source On March...

297

Development of Electrolytes for Lithium-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

Battaglia & J. Kerr (LBNL) * M. Payne (Novolyte) * F. Puglia & B. Ravdel (Yardney) * G. Smith & O. Borodin (U. Utah) 3 3 Develop novel electrolytes for lithium ion batteries that...

298

Fundamental Studies of Lithium-Sulfur Cell Chemistry  

Broader source: Energy.gov (indexed) [DOE]

Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

299

Electronic structure of lithium-doped anatase TiO{sub 2} prepared in ultrahigh vacuum  

SciTech Connect (OSTI)

Insertion of lithium in anatase TiO{sub 2}, giving Li{sub x}TiO{sub 2}, is performed under ultrahigh vacuum (UHV) conditions and studied using synchrotron radiation based electron spectroscopy. Core level photoemission spectra are directly compared to results obtained after electrochemical insertion, illustrating the usefulness of the UHV approach. The growth of a state of mainly Ti 3d character in the band gap is monitored and the amount of charge transferred from Li to the band gap state is quantified. The result that the Ti 3d level is occupied by 0.85{+-}0.10 electronic charge is in good agreement with theoretical predictions. Binding energy shifts of the core levels suggest that the population of the Ti 3d states does not follow a simple rigid band behavior. It is concluded that the formation of the Li-poor phase (x<2%) is associated with pinning of the Fermi level to the bottom of the conduction band. The Li-poor phase can therefore be envisaged as related to defects. Changes in the valence photoemission spectrum and O 1s x-ray absorption spectrum are interpreted in terms of a decreased O 2p-Ti 3d interaction upon Li insertion. Shifts in the sample work function are finally found to agree reasonably well with the measured cell voltage for electrochemical Li insertion into a nanoporous anatase film.

Richter, J.H.; Henningsson, A.; Karlsson, P.G.; Siegbahn, H.; Sandell, A. [Department of Physics, Uppsala University, P.O. Box 530, S-751 21 Uppsala (Sweden); Andersson, M.P.; Uvdal, P. [Chemical Physics, Department of Chemistry, Lund University, P.O. Box 124, S-221 00 Lund (Sweden)

2005-06-15T23:59:59.000Z

300

Batteries - Beyond Lithium Ion Breakout session  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BEYOND LITHIUM ION BREAKOUT BEYOND LITHIUM ION BREAKOUT Breakout Session #1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets * 1 - Zn-Air possible either w/ or w/o electric-hybridization; also possible with a solid electrolyte variant * 2 - Multivalent systems (e.g Mg), potentially needing hybrid-battery * 3 - Advanced Li-ion with hybridization @ cell / molecular level for high-energy and high- power * 4 - MH-air, Li-air, Li-S, all show promise * 5 - High-energy density (e.g. Na-metal ) flow battery can meet power and energy goals * 6 - Solid-state batteries (all types) * 7 - New cathode chemistries (beyond S) to increase voltage * 8 - New high-voltage non-flammable electrolytes (both li-ion and beyond li-ion) * 9 - Power to energy ratio of >=12 needed for fast charge (10 min)  So liquid refill capable

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Manganese oxide composite electrodes for lithium batteries  

DOE Patents [OSTI]

An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor of a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Li, Naichao (Croton on Hudson, NY)

2007-12-04T23:59:59.000Z

302

Manganese oxide composite electrodes for lithium batteries  

DOE Patents [OSTI]

An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0.5lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

Johnson, Christopher S. (Naperville, IL); Kang, Sun-Ho (Naperville, IL); Thackeray, Michael M. (Naperville, IL)

2009-12-22T23:59:59.000Z

303

Expanding argon plasma interacting with lithium surface  

Science Journals Connector (OSTI)

Abstract In this thesis, the interaction between Ar Plasma and lithium is studied by Langmuir probe and Spectrometer. We have studied the effects of the applied discharge current, the gas flow rate, the magnetic field on emission spectrum, electron temperature and electron density. The experimental results show that spectrum intensity, electron temperature and electron density all increase with the increasing discharge current, gas flow rate or magnetic field when the other experimental conditions were fixed, and it is also found that the intensity of Li-670.78 nm increases slowly at first and then increases rapidly, at last, it tends to be stable figure at the beginning of experiment. What is more, spectrum of lithium (670.78 nm) is also detected at the first diagnostic window (viewing window).

X. Cao; S. Chen; W. Zhang; X. Xue; M. Lu; C. Wang; J. Wang; F. Gou; D. Yang; Ou Wei

2014-01-01T23:59:59.000Z

304

High-discharge-rate lithium ion battery  

DOE Patents [OSTI]

The present invention provides for a lithium ion battery and process for creating such, comprising higher binder to carbon conductor ratios than presently used in the industry. The battery is characterized by much lower interfacial resistances at the anode and cathode as a result of initially mixing a carbon conductor with a binder, then with the active material. Further improvements in cycleability can also be realized by first mixing the carbon conductor with the active material first and then adding the binder.

Liu, Gao; Battaglia, Vincent S; Zheng, Honghe

2014-04-22T23:59:59.000Z

305

High expansion, lithium corrosion resistant sealing glasses  

DOE Patents [OSTI]

Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

306

Lithium-Polysulfide Flow Battery Demonstration  

SciTech Connect (OSTI)

In this video, Stanford graduate student Wesley Zheng demonstrates the new low-cost, long-lived flow battery he helped create. The researchers created this miniature system using simple glassware. Adding a lithium polysulfide solution to the flask immediately produces electricity that lights an LED. A utility version of the new battery would be scaled up to store many megawatt-hours of energy.

Zheng, Wesley

2014-06-30T23:59:59.000Z

307

Valence- and conduction-band structure of the sapphire (11¯02) surface  

Science Journals Connector (OSTI)

X-ray photoelectron (XPS) and electron-energy-loss spectroscopies have been employed to investigate the valence- and conduction-band densities of states of the sapphire (11¯02) surface. The photoemission spectrum of the valence-band region has been adjusted to remove cross-section effects and compared to the recent theoretical density of states calculated by Ciraci and Batra. The energy-loss data have been used to determine the bulk-plasmon energy of sapphire, 24.0±0.3 eV, as well as the locations of eight regions of high conduction-band–state density within 20 eV above the conduction-band minimum. One of these regions is an empty surface state 4.0 eV below the conduction-band minimum. Several high-binding-energy satellites in the XPS core-level spectra are reported and interpreted in terms of energy losses to plasmons and interband transitions.

W. J. Gignac; R. Stanley Williams; Steven P. Kowalczyk

1985-07-15T23:59:59.000Z

308

Optical Structure near 20 meV in Valence-Fluctuation Compounds  

Science Journals Connector (OSTI)

The first measurement is reported of low-energy (20 meV) structure in the low-temperature dielectric function of two valence-fluctuation materials: CePd3 and YbCu2Si2. The structure is consistent with energy-dependent scattering of electrons off a resonant level whose width and position (relative to the Fermi level) are roughly comparable. No such structure is observed in the integral-valent materials YPd3, DyPd3, and LuCu2Si2. The valence-fluctuation compounds CeCu2Si2 and CeAl3 do not show a resonance above 4 meV.

F. E. Pinkerton; A. J. Sievers; J. W. Wilkins; M. B. Maple; B. C. Sales

1981-10-05T23:59:59.000Z

309

Interatomic decay of inner-valence ionized states in ArXe clusters: Relativistic approach  

SciTech Connect (OSTI)

In this work we investigate interatomic electronic decay processes taking place in mixed argon-xenon clusters upon the inner-valence ionization of an argon center. We demonstrate that both interatomic Coulombic decay and electron-transfer mediated decay (ETMD) are important in larger rare gas clusters as opposed to dimers. Calculated secondary electron spectra are shown to depend strongly on the spin-orbit coupling in the final states of the decay as well as the presence of polarizable environment. It follows from our calculations that ETMD is a pure interface process taking place between the argon-xenon layers. The interplay of all these effects is investigated in order to arrive at a suitable physical model for the decay of inner-valence vacancies taking place in mixed ArXe clusters.

Fasshauer, Elke; Pernpointner, Markus; Gokhberg, Kirill [Theoretische Chemie, Universitaet Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany)

2013-01-07T23:59:59.000Z

310

Deuterium Retention in NSTX with Lithium Conditioning  

SciTech Connect (OSTI)

High (approximate to 90%) deuterium retention was observed in NSTX gas balance measurements both with- and without lithiumization of the carbon plasma-facing components. The gas retained in ohmic discharges was measured by comparing the vessel pressure rise after a discharge to that of a gas-only pulse with the pumping valves closed. For neutral beam heated discharges the gas input and gas pumped by the NB cryopanels were tracked. The discharges were followed by outgassing of deuterium that reduced the retention. The relationship between retention and surface chemistry was explored with a new plasma-material interface probe connected to an in vacuo surface science station that exposed four material samples to the plasma. XPS and TDS analysis demonstrated that binding of D atoms in graphite is fundamentally changed by lithium - in particular atoms are weakly bonded in regions near lithium atoms bound to either oxygen or the carbon matrix. This is in contrast to the strong ionic bonding that occurs between D and pure Li. (C) 2010 Elsevier B.V. All rights reserved.

Skinner, C. H. [Princeton Plasma Physics Laboratory (PPPL); Allain, J. P. [Purdue University; Blanchard, W. [Princeton Plasma Physics Laboratory (PPPL); Kugel, H. W. [Princeton Plasma Physics Laboratory (PPPL); Maingi, Rajesh [ORNL; Roquemore, L. [Princeton Plasma Physics Laboratory (PPPL); Soukhanovskii, V. A. [Lawrence Livermore National Laboratory (LLNL); Taylor, C. N. [Purdue University

2011-01-01T23:59:59.000Z

311

Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone  

SciTech Connect (OSTI)

Graphical abstract: Recovery of valuable metals from scrap batteries of mobile phone. - Highlights: • Recovery of Co and Li from spent LIBs was performed by hydrometallurgical route. • Under the optimum condition, 99.1% of lithium and 70.0% of cobalt were leached. • The mechanism of the dissolution of lithium and cobalt was studied. • Activation energy for lithium and cobalt were found to be 32.4 kJ/mol and 59.81 kJ/mol, respectively. • After metal recovery, residue was washed before disposal to the environment. - Abstract: In view of the stringent environmental regulations, availability of limited natural resources and ever increasing need of alternative energy critical elements, an environmental eco-friendly leaching process is reported for the recovery of lithium and cobalt from the cathode active materials of spent lithium-ion batteries of mobile phones. The experiments were carried out to optimize the process parameters for the recovery of lithium and cobalt by varying the concentration of leachant, pulp density, reductant volume and temperature. Leaching with 2 M sulfuric acid with the addition of 5% H{sub 2}O{sub 2} (v/v) at a pulp density of 100 g/L and 75 °C resulted in the recovery of 99.1% lithium and 70.0% cobalt in 60 min. H{sub 2}O{sub 2} in sulfuric acid solution acts as an effective reducing agent, which enhance the percentage leaching of metals. Leaching kinetics of lithium in sulfuric acid fitted well to the chemical controlled reaction model i.e. 1 ? (1 ? X){sup 1/3} = k{sub c}t. Leaching kinetics of cobalt fitted well to the model ‘ash diffusion control dense constant sizes spherical particles’ i.e. 1 ? 3(1 ? X){sup 2/3} + 2(1 ? X) = k{sub c}t. Metals could subsequently be separated selectively from the leach liquor by solvent extraction process to produce their salts by crystallization process from the purified solution.

Jha, Manis Kumar, E-mail: mkjha@nmlindia.org; Kumari, Anjan; Jha, Amrita Kumari; Kumar, Vinay; Hait, Jhumki; Pandey, Banshi Dhar

2013-09-15T23:59:59.000Z

312

Organic matter in the Paleogene west European rift: Bresse and Valence salt basins (France)  

SciTech Connect (OSTI)

The Bresse and Valence basins are two adjacent segments of the West European rift. They contain thick Paleogene halite sequences including intercalated and interfingering siliciclastic material and carbonate and sulfate deposits. Source rock samples in this study were mainly taken from the depocenters because of maximum sampling coverage. Organic matter (OM) is generally immature and occurs primarily within intercalated nonhalitic beds. The Bresse basin seems to contain more OM in (1) the Intermediate Salt Formation (Priabonian), composed of alternating laminated carbonate and halite beds; (2) the upper part of the Upper Salt Formation (clayey carbonate beds; Rupelian), affected by synsedimentary halite solution; and (3) the solution breccia which immediate overlies the salt sequence. In the Valence basin, the organic-rich layers are concentrated in the Subsalt Formation (carbonate beds; Priabonian), and the upper part of the Lower Salt Formation (laminates; Rupelian). In both basins, type III organic matter is associated with terrigenous facies. Type I is abundant in the Valence basin (laminites), and type II seems to be more abundant in the Bresse basin. The amount of OM varies considerably, and we suppose it is higher toward the basin margins. From studies made in evaporite basins in other region, which are also known to have significant amounts of organic matter, we find a similar range of organic composition. Such studies are of interest because of their petroleum potential and for understanding precise depositional environments and waste disposal problems (gas generation with local heat source).

Curial, A.; Dumas, D.; Moretto, R.

1988-08-01T23:59:59.000Z

313

Liner surface improvements for low friction piston ring packs  

Science Journals Connector (OSTI)

The development of engine components in the automotive industry is governed by several constraints such as environmental legislation and customer expectations. About a half of the frictional losses in an internal combustion engine come from the interactions between the piston assembly and cylinder liner surface. The tribological considerations in the contact between the piston ring and cylinder liner have attracted much attention over the past few decades. Many non-conventional cylinder liner finishes have been, and are being, developed with the aim to reduce friction losses and oil consumption, but the effects of the surface finish on piston ring pack performance is not well understood. One way of reducing friction in the cylinder system is to reduce the tangential load from the piston ring pack, focusing on the oil control ring. However, the side-effect of this is a disappointingly increased oil consumption. In this study a number of different cylinder liner surface specifications were developed and implemented in test engines with the aim of maintaining the level for oil consumption when decreasing the tangential load for the piston ring pack. To improve our understanding of the result, the same surfaces were evaluated in elastic and elasto-plastic rough contact and hydrodynamic flow simulation models. It is shown that oil consumption is strongly related to surface texture on the cylinder liners and at lower speeds (900–1200 rpm), a 'rougher surface' with a high core (e.g. Sk) and valley roughness (e.g. Svk) results in higher oil consumption. At the medium speed range (1200–3600 rpm), oil consumption continues to dominate for the 'rough' surfaces but with a visible influence of a lower oil consumption for a decreased roughness within the 'rough' surface group. 'Smooth' surfaces with a 'smooth' core (Sk), irrespective of the valley component (Svk), show similar oil consumption. For engine speeds above 3600 rpms, an increase in plateau roughness results in higher oil consumption. Throughout the study, standard roughness parameters were computed to compare with the results from engine testing and simulation. Future work will be directed to continuous optimization between oil consumption and friction. Improving the understanding of the functional cylinder system surfaces' ability to form oil films in the cylinder system opens up opportunities, not only in reducing the tangential load of piston ring packs but also in optimizing oil viscosity in order to reduce friction.

C Anderberg; Z Dimkovski; B-G Rosén

2014-01-01T23:59:59.000Z

314

Hydraulically refueled battery employing a packed bed metal particle electrode  

DOE Patents [OSTI]

A secondary zinc air cell, or another selected metal air cell, employing a spouted/packed metal particle bed and an air electrode. More specifically, two embodiments of a cell, one that is capable of being hydraulically recharged, and a second that is capable of being either hydraulically or electrically recharged. Additionally, each cell includes a sloped bottom portion to cause stirring of the electrolyte/metal particulate slurry when the cell is being hydraulically emptied and refilled during hydraulically recharging of the cell.

Siu, Stanley C. (Castro Valley, CA); Evans, James W. (Piedmont, CA)

1998-01-01T23:59:59.000Z

315

Flooding Capacity in Packed Towers:? Database, Correlations, and Analysis  

Science Journals Connector (OSTI)

To provide more insight into the exact influence of operating variables on flooding, several ANN simulations were performed by attributing different values for one studied variable while all of the others were held constant. ... The gas superficial velocity at flooding for the CMR simulation is greater by 1 m/s across the whole liquid velocity range. ... Because of the broadness and diversity of the databases, the proposed correlation has the capability of simulating the flooding capacity in randomly dumped packed beds for any purposes such as absorption and distillation. ...

Simon Piché; Faïçal Larachi; Bernard P. A. Grandjean

2000-11-30T23:59:59.000Z

316

Hydraulically refueled battery employing a packed bed metal particle electrode  

DOE Patents [OSTI]

A secondary zinc air cell, or another selected metal air cell, employing a spouted/packed metal particle bed and an air electrode is described. More specifically, two embodiments of a cell, one that is capable of being hydraulically recharged, and a second that is capable of being either hydraulically or electrically recharged. Additionally, each cell includes a sloped bottom portion to cause stirring of the electrolyte/metal particulate slurry when the cell is being hydraulically emptied and refilled during hydraulically recharging of the cell. 15 figs.

Siu, S.C.; Evans, J.W.

1998-12-15T23:59:59.000Z

317

Power-law friction in closely-packed granular materials  

E-Print Network [OSTI]

In order to understand the nature of friction in closely-packed granular materials, a discrete element simulation on granular layers subjected to isobaric plain shear is performed. It is found that the friction coefficient increases as the power of the shear rate, the exponent of which does not depend on the material constants. Using a nondimensional parameter that is known as the inertial number, the power-law can be cast in a generalized form so that the friction coefficients at different confining pressures collapse on the same curve. We show that the volume fraction also obeys a power-law.

Takahiro Hatano

2006-12-14T23:59:59.000Z

318

Effective thermal conductivity of packed beds of spheres  

E-Print Network [OSTI]

of N are known only for certain types of regular packing, however, an empirical relation for m ) 0. 3 is given as N = 11. 6(l ? m) (22) When a load is applied to a bed of spheres, the contact area between spheres is determined using the Hertz... the authors compared their analytical solutions to has consistently dealt with beds of materials which have a very low thermal conductivity compared to that of the brass and aluminum spheres. These materials have been solid and hollow glass spheres, ceramic...

Duncan, Allen Buchanan

1987-01-01T23:59:59.000Z

319

Size-consistent wave functions for nondynamical correlation energy: The valence active space optimized orbital coupled-cluster  

E-Print Network [OSTI]

Size-consistent wave functions for nondynamical correlation energy: The valence active space 6 July 1998; accepted 15 September 1998 The nondynamical correlation energy may be defined correlation energy, as defined above, involves computational complexity that grows exponentially

Krylov, Anna I.

320

Nucleon structure from mixed action calculations using 2+1 flavors of asqtad sea and domain wall valence fermions  

E-Print Network [OSTI]

We present high statistics results for the structure of the nucleon from a mixed-action calculation using 2+1 flavors of asqtad sea and domain-wall valence fermions. We perform extrapolations of our data based on different ...

Bratt, Jonathan D.

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Characterization of Lithium Stearate: Processing Aid for Filled Elastomers  

SciTech Connect (OSTI)

This topical report presents work completed to characterize lithium stearate so a replacement supplier could be identified. Lithium stearate from Alfa Aesar and Chemtura was obtained and characterized along with the current material from Witco. Multiple methods were used to characterize the materials including Karl Fischer, FT-IR, differential scanning calorimetry, and thermogravimetric analysis.

E. Eastwood; C. Densmore

2007-02-05T23:59:59.000Z

322

Materials Challenges and Opportunities of Lithium Ion Batteries  

Science Journals Connector (OSTI)

His research interests are in the area of materials for lithium ion batteries, fuel cells, and solar cells, including novel synthesis approaches for nanomaterials. ... Lithium–sulfur (Li–S) batteries with a high theoretical energy density of ?2500 Wh kg–1 are considered as one promising rechargeable battery chemistry for next-generation energy storage. ...

Arumugam Manthiram

2011-01-10T23:59:59.000Z

323

Sol–gel synthesis of sodium and lithium based materials  

Science Journals Connector (OSTI)

Sodium and lithium cobaltates are important materials for thermoelectric and ... the sol–gel synthesis of sodium- and lithium-based materials by using acetate precursors. The produced Na2/3CoO2, Li(Ni1/3Mn1/3Co1/...

Sandra Hildebrandt; Andreas Eva…

2012-09-01T23:59:59.000Z

324

Lithium treatment reduces morphine self-administration in addict rats  

Science Journals Connector (OSTI)

... Lithium also has been shown to interact with morphine: it can sometimes reduce morphine-induced ... mice7'8 and potentiate morphine analgesia in rats9. We have therefore investigated the possibility that lithium may affect the amount of voluntary ingestion of morphine by addict rats.

MICHAL TOMKIEWICZ; HANNAH STEINBERG

1974-11-15T23:59:59.000Z

325

Lithium Lorentz Force Accelerator Thruster (LiLFA)  

E-Print Network [OSTI]

Lithium Lorentz Force Accelerator Thruster (LiLFA) Adam Coulon Princeton University Electric originally came from the MAI (Moscow Aviation Institute) Russia · Many Princeton graduate students have #12;LiLFA Thruster · Lithium vapor ionizes in the electric field · A current evolves in the plasma

Petta, Jason

326

Method for immobilizing particulate materials in a packed bed  

DOE Patents [OSTI]

The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

Even, Jr., William R. (Livermore, CA); Guthrie, Stephen E. (Livermore, CA); Raber, Thomas N. (Livermore, CA); Wally, Karl (Lafayette, CA); Whinnery, LeRoy L. (Livermore, CA); Zifer, Thomas (Manteca, CA)

1999-01-01T23:59:59.000Z

327

Local origin of global contact numbers in frictional ellipsoid packings  

E-Print Network [OSTI]

In particulate soft matter systems the average number of contacts $Z$ of a particle is an important predictor of the mechanical properties of the system. Using X-ray tomography, we analyze packings of frictional, oblate ellipsoids of various aspect ratios $\\alpha$, prepared at different global volume fractions $\\phi_g$. We find that $Z$ is a monotonously increasing function of $\\phi_g$ for all $\\alpha$. We demonstrate that this functional dependence can be explained by a local analysis where each particle is described by its local volume fraction $\\phi_l$ computed from a Voronoi tessellation. $Z$ can be expressed as an integral over all values of $\\phi_l$: $Z(\\phi_g, \\alpha, X) = \\int Z_l (\\phi_l, \\alpha, X) \\; P(\\phi_l | \\phi_g) \\; d\\phi_l$. The local contact number function $ Z_l (\\phi_l, \\alpha, X)$ describes the relevant physics in term of locally defined variables only, including possible higher order corrections $X$. The conditional probability $P(\\phi_l | \\phi_g)$ to find a specific value of $\\phi_l$ given a global packing fraction $\\phi_g$ is independent of $\\alpha$ and $X$. An important step in defining $ Z_l (\\phi_l, \\alpha, X)$ is the determination of the local surface area fraction $\\psi_l$.

Fabian M. Schaller; Max Neudecker; Mohammad Saadatfar; Gary Delaney; Gerd E. Schröder-Turk; Matthias Schröter

2013-12-04T23:59:59.000Z

328

Distillation: Energy Savings and Other Benefits From the Use of High Efficiency Packings  

E-Print Network [OSTI]

that competes with distillation for the separation of fluid mixtures. Packed contactors are used in extraction processes where only a few theoretical stages are required.' They are more efficient than empty spray towers because the packing minimizes... efficiency of the various packings as a function of system properties and column geometry [IOJ Nemunaitis, R. R., Eckert, J. S., Forte, E. H., for industrial-scale contactors. and Rollison, L. R., Chern. Eng. Progr., 67 (11), 60 (1971). ~ CONCLUSIONS...

Bravo, J. L.; Fair, J. R.; Humphrey, J. L.

329

Two Studies Reveal Details of Lithium-Battery Function  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Studies Reveal Details of Lithium-Battery Function Print Two Studies Reveal Details of Lithium-Battery Function Print Our way of life is deeply intertwined with battery technologies that have enabled a mobile revolution powering cell phones, laptops, medical devices, and cars. As conventional lithium-ion batteries approach their theoretical energy-storage limits, new technologies are emerging to address the long-term energy-storage improvements needed for mobile systems, electric vehicles in particular. Battery performance depends on the dynamics of evolving electronic and chemical states that, despite advances in material synthesis and structural probes, remain elusive and largely unexplored. At Beamlines 8.0.1 and 9.3.2, researchers studied lithium-ion and lithium-air batteries, respectively, using soft x-ray spectroscopy techniques. The detailed information they obtained about the evolution of electronic and chemical states will be indispensable for understanding and optimizing better battery materials.

330

A Better Anode Design to Improve Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Better Anode Design to Improve A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve Lithium-Ion Batteries Print Friday, 23 March 2012 13:53 Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds

331

China Lithium Energy Electric Vehicle Investment Group CLEEVIG | Open  

Open Energy Info (EERE)

Investment Group CLEEVIG Investment Group CLEEVIG Jump to: navigation, search Name China Lithium Energy Electric Vehicle Investment Group (CLEEVIG) Place Beijing, China Zip 100101 Product Beijing-based investment company with a focus on Electric Vehicle R&D. References China Lithium Energy Electric Vehicle Investment Group (CLEEVIG)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. China Lithium Energy Electric Vehicle Investment Group (CLEEVIG) is a company located in Beijing, China . References ↑ "[ China Lithium Energy Electric Vehicle Investment Group (CLEEVIG)]" Retrieved from "http://en.openei.org/w/index.php?title=China_Lithium_Energy_Electric_Vehicle_Investment_Group_CLEEVIG&oldid=343507

332

Two Studies Reveal Details of Lithium-Battery Function  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Studies Reveal Details of Lithium-Battery Function Print Two Studies Reveal Details of Lithium-Battery Function Print Our way of life is deeply intertwined with battery technologies that have enabled a mobile revolution powering cell phones, laptops, medical devices, and cars. As conventional lithium-ion batteries approach their theoretical energy-storage limits, new technologies are emerging to address the long-term energy-storage improvements needed for mobile systems, electric vehicles in particular. Battery performance depends on the dynamics of evolving electronic and chemical states that, despite advances in material synthesis and structural probes, remain elusive and largely unexplored. At Beamlines 8.0.1 and 9.3.2, researchers studied lithium-ion and lithium-air batteries, respectively, using soft x-ray spectroscopy techniques. The detailed information they obtained about the evolution of electronic and chemical states will be indispensable for understanding and optimizing better battery materials.

333

Liquid Lithium WindowlessLiquid Lithium Windowless Targets for High Power  

E-Print Network [OSTI]

the accelerator beam line · No solid confinement structure · In vacuum ­ It's possible due to Li's low vapor/s in vacuum. #12;Why Liquid Lithium? Low Z ( = 3 )---good from nuclear considerations Large working temp compatible with accelerator vacuum (10-4 Pa or 10-6 Torr). 1000 ( ) Local peak temperature can be much

McDonald, Kirk

334

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural carbonates  

E-Print Network [OSTI]

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural method for lithium isotope ratio (7 Li/6 Li) determinations with low total lithium consumption ( lithium from all matrix elements using small volume resin (2 ml/3.4 meq AG 50W-X8) and low volume elution

Weston, Ken

335

17 Years of Lithium Brown Dwarfs 10/21/12Ringberg Brown Dwarfs 1  

E-Print Network [OSTI]

17 Years of Lithium Brown Dwarfs 10/21/12Ringberg Brown Dwarfs 1 #12;The Keck Search for Lithium 10/21/12Ringberg Brown Dwarfs 2 Lithium was not seen in objects which should have been comfortably into the brown "lithium dating". This adjustment in age meant that the inferred mass of PPl 15 rose to near the substellar

Joergens, Viki

336

Abstract--This paper describes experimental results aiming at analyzing lithium-ion batteries performances  

E-Print Network [OSTI]

years, Saft has been developing a range of lithium ion cells and batteries to cover the full spectrum. To follow such a characteristic, electrochemical impedance spectroscopy (EIS) measurements on Saft lithium or several cells. II. OVERVIEW OF EXPERIMENT A. Used lithium-ion cells The cells used are lithium-ion Saft

Boyer, Edmond

337

Design of battery pack and internal combustion engine thermal models for hybrid electric vehicles.  

E-Print Network [OSTI]

?? This thesis focuses on the design of computational models, capable of simulating the thermal behaviour of a battery pack and internal combustion engine equipping… (more)

Catacchio, Gabriele

2013-01-01T23:59:59.000Z

338

E-Print Network 3.0 - assisted packed bed Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

WASTES Summary: consolidation of the solid refuse bed took place as a result of gasification. The bulk density of the hand-packed... involving acidic bio leachate production...

339

Lithium Ethylene Dicarbonate Identified as the Primary Product of Chemical and Electrochemical Reduction of EC in EC:EMC/1.2M LiPF6 Electrolyte  

E-Print Network [OSTI]

of synthetic lithium ethylene dicarbonate. Figure 3.structure of lithium ethylene dicarbonate (A) and dimer (B).of: a. ) synthetic lithium ethylene dicarbonate; b. ) EC

Zhuang, Guorong V.; Xu, Kang; Yang, Hui; Jow, T. Richard; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

340

Thermal Property Measurements and Enthalpy Calculation of the Lithium Bromide+Lithium Iodide+1,3-Propanediol+Water System  

Science Journals Connector (OSTI)

The lithium bromide+lithium iodide+1,3-propanediol+water [LiBr/LiI mole ratio=4 and (LiBr+LiI)/HO(CH2)3...OH mass ratio=4] solution is being considered as a potential working fluid for an absorption chiller. Heat...

J.-S. Kim; H.-S. Lee; H. Lee

2000-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

The impact of lithium wall coatings on NSTX discharges and the engineering of the Lithium Tokamak eXperiment (LTX)  

SciTech Connect (OSTI)

Recent experiments on the National Spherical Torus eXperiment (NSTX) have shown the benefits of solid lithium coatings on carbon PFC's to diverted plasma performance, in both L- and H-mode confinement regimes. Better particle control, with decreased inductive flux consumption, and increased electron temperature, ion temperature, energy confinement time, and DD neutron rate were observed. Successive increases in lithium coverage resulted in the complete suppression of ELM activity in H-mode discharges. A liquid lithium divertor (LLD), which will employ the porous molybdenum surface developed for the LTX shell, is being installed on NSTX for the 2010 run period, and will provide comparisons between liquid walls in the Lithium Tokamak eXperiment (LTX) and liquid divertor targets in NSTX. LTX, which recently began operations at the Princeton Plasma Physics Laboratory, is the world's first confinement experiment with full liquid metal plasma-facing components (PFCs). All materials and construction techniques in LTX are compatible with liquid lithium. LTX employs an inner, heated, stainless steel-faced liner or shell, which will be lithium-coated. In order to ensure that lithium adheres to the shell, it is designed to operate at up to 500-600 degrees C to promote wetting of the stainless by the lithium, providing the first hot wall in a tokamak to Operate at reactor-relevant temperatures. The engineering of LTX will be discussed. (c) 2010 Elsevier B.V. All rights reserved.

Majeski, R. [Princeton Plasma Physics Laboratory (PPPL); Kugel, H. [Princeton Plasma Physics Laboratory (PPPL); Kaita, R. [Princeton Plasma Physics Laboratory (PPPL); Avasarala, S. [Princeton Plasma Physics Laboratory (PPPL); Bell, M. G. [Princeton Plasma Physics Laboratory (PPPL); Bell, R. E. [Princeton Plasma Physics Laboratory (PPPL); Berzak, L. [Princeton Plasma Physics Laboratory (PPPL); Beiersdorfer, P. [Lawrence Livermore National Laboratory (LLNL); Gerhardt, S. P. [Princeton Plasma Physics Laboratory (PPPL); Gransted, E. [Princeton Plasma Physics Laboratory (PPPL); Gray, T. [Princeton Plasma Physics Laboratory (PPPL); Jacobson, C. [Princeton Plasma Physics Laboratory (PPPL); Kallman, J. [Princeton Plasma Physics Laboratory (PPPL); Kaye, S. [Princeton Plasma Physics Laboratory (PPPL); Kozub, T. [Princeton Plasma Physics Laboratory (PPPL); LeBlanc, B. P. [Princeton Plasma Physics Laboratory (PPPL); Lepson, J. [Lawrence Livermore National Laboratory (LLNL); Lundberg, D. P. [Princeton Plasma Physics Laboratory (PPPL); Maingi, Rajesh [ORNL; Mansfield, D. [Princeton Plasma Physics Laboratory (PPPL); Paul, S. F. [Princeton Plasma Physics Laboratory (PPPL); Pereverzev, G. V. [Max-Planck-Institut fur Plasmaphysik, EURATOM Association, Garching, Germany; Schneider, H. [Princeton Plasma Physics Laboratory (PPPL); Soukhanovskii, V. [Lawrence Livermore National Laboratory (LLNL); Strickler, T. [Princeton Plasma Physics Laboratory (PPPL); Stotler, D. [Princeton Plasma Physics Laboratory (PPPL); Timberlake, J. [Princeton Plasma Physics Laboratory (PPPL); Zakharov, L. E. [Princeton Plasma Physics Laboratory (PPPL)

2010-01-01T23:59:59.000Z

342

Surface modifications for carbon lithium intercalation anodes  

DOE Patents [OSTI]

A prefabricated carbon anode containing predetermined amounts of passivating film components is assembled into a lithium-ion rechargeable battery. The modified carbon anode enhances the reduction of the irreversible capacity loss during the first discharge of a cathode-loaded cell. The passivating film components, such as Li.sub.2 O and Li.sub.2 CO.sub.3, of a predetermined amount effective for optimal passivation of carbon, are incorporated into carbon anode materials to produce dry anodes that are essentially free of battery electrolyte prior to battery assembly.

Tran, Tri D. (Livermore, CA); Kinoshita, Kimio (Cupertino, CA)

2000-01-01T23:59:59.000Z

343

Penetration depth scaling for impact into wet granular packings  

E-Print Network [OSTI]

We present experimental measurements of penetration depths for the impact of spheres into wetted granular media. We observe that the penetration depth in the liquid saturated case scales with projectile density, size, and drop height in a fashion consistent with the scaling observed in the dry case, but that penetration depths into saturated packings tend to be smaller. This result suggests that, for the range of impact energies observed, the stopping force is set by static contact forces between grains within the bed, and that the presence of liquid serves, primarily, to enhance these contact forces. The enhancement to the stopping force has a complicated dependence on liquid fraction, accompanied by a change in the drop-height dependence, that must be the consequence of accompanying changes in the conformation of the liquid phase in the interstices.

Theodore A. Brzinski III; Jorin Schug; Kelly Mao; Douglas J. Durian

2015-01-25T23:59:59.000Z

344

METHOD TO TEST ISOTOPIC SEPARATION EFFICIENCY OF PALLADIUM PACKED COLUMNS  

SciTech Connect (OSTI)

The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam use, were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages using the test results. The effects of column diameter, metal foam and gas flow rate were identified.

Heung, L; Gregory Staack, G; James Klein, J; William Jacobs, W

2007-06-27T23:59:59.000Z

345

Combustion of textile residues in a packed bed  

SciTech Connect (OSTI)

Textile is one of the main components in the municipal waste which is to be diverted from landfill for material and energy recovery. As an initial investigation for energy recovery from textile residues, the combustion of cotton fabrics with a minor fraction of polyester was investigated in a packed bed combustor for air flow rates ranging from 117 to 1638 kg/m{sup 2} h (0.027-0.371 m/s). Tests were also carried out in order to evaluate the co-combustion of textile residues with two segregated waste materials: waste wood and cardboard. Textile residues showed different combustion characteristics when compared to typical waste materials at low air flow rates below 819 kg/m{sup 2} h (0.186 m/s). The ignition front propagated fast along the air channels randomly formed between packed textile particles while leaving a large amount of unignited material above. This resulted in irregular behaviour of the temperature profile, ignition rate and the percentage of weight loss in the ignition propagation stage. A slow smouldering burn-out stage followed the ignition propagation stage. At air flow rates of 1200-1600 kg/m{sup 2} h (0.272-0.363 m/s), the bed had a maximum burning rate of about 240 kg/m{sup 2} h consuming most of the combustibles in the ignition propagation stage. More uniform combustion with an increased burning rate was achieved when textile residues were co-burned with cardboard that had a similar bulk density. (author)

Ryu, Changkook; Phan, Anh N.; Sharifi, Vida N.; Swithenbank, Jim [Sheffield University Waste Incineration Centre (SUWIC), Department of Chemical and Process Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom)

2007-08-15T23:59:59.000Z

346

Valence-transition-induced 5×5 surface reconstruction of Sm(0001)  

Science Journals Connector (OSTI)

Single-crystal SM(0001) surfaces have been grown epitaxially on Mo(110). At low temperatures LEED shows a 5×5 surface reconstruction. This new type of valence-transition-induced reconstruction corresponds to a 25% expansion of the interatomic distances in the topmost hexagonal surface layer. At room temperature the 5×5 LEED pattern disappears due to a disordering of the surface. This suggests a very low melting temperature for the surface which may have implications for the understanding of the anomalous melting temperature of Sm metal.

A. Stenborg; J. N. Andersen; O. Björneholm; A. Nilsson; N. Mårtensson

1989-07-10T23:59:59.000Z

347

Magnetic dichroism in valence-band x-ray photoemission spectroscopy  

Science Journals Connector (OSTI)

A fully relativistic description of spin-resolved valence-band x-ray photoemission spectroscopy (VB-XPS) of magnetic solids is presented that is based on multiple scattering theory. This approach allows us to investigate possible magnetic dichroism in VB-XPS. As is demonstrated by results for CoxPt1-x, application to disordered alloys is straightforward within the framework of the coherent potential approximation alloy theory. The spin-integrated spectra for unpolarized radiation were found to be in very satisfying agreement with corresponding experimental data. For the spin-resolved spectra a pronounced magnetic circular dichroism is predicted that should be easily observed.

H. Ebert and J. Schwitalla

1997-02-01T23:59:59.000Z

348

Lithium-Ion Battery Teacher Workshop  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lithium Ion Battery Teacher Workshop Lithium Ion Battery Teacher Workshop 2012 2 2 screw eyes 2 No. 14 rubber bands 2 alligator clips 1 plastic gear font 2 steel axles 4 nylon spacers 2 Pitsco GT-R Wheels 2 Pitsco GT-F Wheels 2 balsa wood sheets 1 No. 280 motor Also: Parts List 3 Tools Required 1. Soldering iron 2. Hobby knife or coping saw 3. Glue gun 4. Needlenose pliers 5. 2 C-clamps 6. Ruler 4 1. Using a No. 2 pencil, draw Line A down the center of a balsa sheet. Making the Chassis 5 2. Turn over the balsa sheet and draw Line B ¾ of an inch from one end of the sheet. Making the Chassis 6 3. Draw a 5/8" x ½" notch from 1" from the top of the sheet. Making the Chassis 7 4. Draw Line C 2 ½" from the other end of the same sheet of balsa. Making the Chassis 8 5. Using a sharp utility knife or a coping saw, cut

349

Novel carbonaceous materials for lithium secondary batteries  

SciTech Connect (OSTI)

Carbonaceous materials have been synthesized using pillared clays (PILCs) as templates. The PILC was loaded with organic materials such as pyrene in the liquid and vapor phase, styrene in the vapor phase, trioxane, ethylene and propylene. The samples were then pyrolyzed at 700 C in an inert atmosphere, followed by dissolution of the inorganic template by conventional demineralization methods. X-ray powder diffraction of the carbons showed broad d{sub 002} peaks in the diffraction pattern, indicative of a disordered or turbostratic system. N{sub 2} BET surface areas of the carbonaceous materials range from 10 to 100 m{sup 2}/g. There is some microporosity (r < 1 nm) in the highest surface area carbons. Most of the surface area, however, comes from a mixture of micro and mesopores with radii of 2--5 nm. Electrochemical studies were performed on these carbons. Button cells were fabricated with capacity- limiting carbon pellets electrodes as the cathode a/nd metallic lithium foil as the anode. Large reversible capacities (up to 850 mAh/g) were achieved for most of the samples. The irreversible capacity loss was less than 180 mAh/g after the first cycle, suggesting that these types of carbon materials are very stable to lithium insertion and de-insertion reactions.

Sandi, G.; Winans, R.E.; Carrado, K.A.; Johnson, C.S.

1997-07-01T23:59:59.000Z

350

Energy Consumption Tools Pack Leandro Fontoura Cupertino, Georges DaCosta,  

E-Print Network [OSTI]

Energy Consumption Tools Pack Leandro Fontoura Cupertino, Georges DaCosta, Amal Sayah, Jean Consumption Tools Pack 1 / 23 #12;Outline 1 Introduction Motivation Our proposal 2 Energy Consumption Tools Energy Consumption Library Data Acquisition Tool Data Monitoring Tool Energy Profiler 3 Conclusions

Lefèvre, Laurent

351

The Climate Change Action Pack An interactive teaching supplement designed to  

E-Print Network [OSTI]

#12;The Climate Change Action Pack An interactive teaching supplement designed to: · Increase the understanding among young Nova Scotians and educators of the science and issues of climate change · Equip Nova at home and in their future workplaces. #12;Climate Change Action Pack printed Mar. 2002 TABLE OF CONTENTS

Gunawardena, Arunika

352

Fast Kinetics of Fe2+ Oxidation in Packed-Bed Reactors  

Science Journals Connector (OSTI)

...protein/ml liquid vol of reactor YPlS Yield of product...material was also used for analysis of the total protein...of the packed-bed reactors. Several experimen...effect. The system reliability was evalu- ated with...ion-exchange resin packed-bed reactor by switching the inlet...

Sergei I. Grishin; Olli H. Tuovinen

1988-12-01T23:59:59.000Z

353

A Novel Cross-Flow Cascade Packed Column Design and Simulation  

Science Journals Connector (OSTI)

A Novel Cross-Flow Cascade Packed Column Design and Simulation ... Thus the abundant area for gas flow will decrease gas-phase pressure drop, and it can allow operation at gas velocities above the flooding points of countercurrent packed columns. ...

Fengrong Chen; Rongqi Zhou; Zhanting Duan; Yumei Liu

1999-07-03T23:59:59.000Z

354

Titanium-Coated Silica Spheres Prepared by Self-Assembly Technique for Use as HPLC Packing  

Science Journals Connector (OSTI)

......for Use as HPLC Packing Jin Ge 1 2 Liang Zhao 1 Li-Ren Chen 1 Yan-Ping Shi 1 * * Author to whom...for Use as HPLC Packing Jin Ge1,2, Liang Zhao1, Li-Ren Chen1, and Yan-Ping Shi1,* 1Key Laboratory...dodecyl sulfate (SDS) from Xi'an Chemical Reagent Co......

Jin Ge; Liang Zhao; Li-Ren Chen; Yan-Ping Shi

2010-01-01T23:59:59.000Z

355

(Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: Chile was the leading lithium chemical producer in the world; Argentina, China, and  

E-Print Network [OSTI]

%; primary aluminum production, 6%; continuous casting, 4%; rubber and thermoplastics, 4%; pharmaceuticals, 294 LITHIUM (Data in metric tons of lithium content unless otherwise noted) Domestic Production resources, reported production and value of production were withheld from publication to avoid disclosing

356

Chemical Shuttle Additives in Lithium Ion Batteries  

SciTech Connect (OSTI)

The goals of this program were to discover and implement a redox shuttle that is compatible with large format lithium ion cells utilizing LiNi{sub 1/3}Mn{sub 1/3}Co{sub 1/3}O{sub 2} (NMC) cathode material and to understand the mechanism of redox shuttle action. Many redox shuttles, both commercially available and experimental, were tested and much fundamental information regarding the mechanism of redox shuttle action was discovered. In particular, studies surrounding the mechanism of the reduction of the oxidized redox shuttle at the carbon anode surface were particularly revealing. The initial redox shuttle candidate, namely 2-(pentafluorophenyl)-tetrafluoro-1,3,2-benzodioxaborole (BDB) supplied by Argonne National Laboratory (ANL, Lemont, Illinois), did not effectively protect cells containing NMC cathodes from overcharge. The ANL-RS2 redox shuttle molecule, namely 1,4-bis(2-methoxyethoxy)-2,5-di-tert-butyl-benzene, which is a derivative of the commercially successful redox shuttle 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB, 3M, St. Paul, Minnesota), is an effective redox shuttle for cells employing LiFePO{sub 4} (LFP) cathode material. The main advantage of ANL-RS2 over DDB is its larger solubility in electrolyte; however, ANL-RS2 is not as stable as DDB. This shuttle also may be effectively used to rebalance cells in strings that utilize LFP cathodes. The shuttle is compatible with both LTO and graphite anode materials although the cell with graphite degrades faster than the cell with LTO, possibly because of a reaction with the SEI layer. The degradation products of redox shuttle ANL-RS2 were positively identified. Commercially available redox shuttles Li{sub 2}B{sub 12}F{sub 12} (Air Products, Allentown, Pennsylvania and Showa Denko, Japan) and DDB were evaluated and were found to be stable and effective redox shuttles at low C-rates. The Li{sub 2}B{sub 12}F{sub 12} is suitable for lithium ion cells utilizing a high voltage cathode (potential that is higher than NMC) and the DDB is useful for lithium ion cells with LFP cathodes (potential that is lower than NMC). A 4.5 V class redox shuttle provided by Argonne National Laboratory was evaluated which provides a few cycles of overcharge protection for lithium ion cells containing NMC cathodes but it is not stable enough for consideration. Thus, a redox shuttle with an appropriate redox potential and sufficient chemical and electrochemical stability for commercial use in larger format lithium ion cells with NMC cathodes was not found. Molecular imprinting of the redox shuttle molecule during solid electrolyte interphase (SEI) layer formation likely contributes to the successful reduction of oxidized redox shuttle species at carbon anodes. This helps to understand how a carbon anode covered with an SEI layer, that is supposed to be electrically insulating, can reduce the oxidized form of a redox shuttle.

Patterson, Mary

2013-03-31T23:59:59.000Z

357

Can mirror matter solve the the cosmological lithium problem?  

SciTech Connect (OSTI)

The abundance of lithium-7 confronts cosmology with a long lasting inconsistency between the predictions of standard Big Bang Nucleosynthesis with the baryonic density determined from the Cosmic Microwave Background observations on the one hand, and the spectroscopic determination of the lithium-7 abundance on the other hand. We investigated the influence of the existence of a mirror world, focusing on models in which mirror neutrons can oscillate into ordinary neutrons. Such a mechanism allows for an effective late time neutron injection, which induces an increase of the destruction of beryllium-7and thus a lower final lithium-7 abundance.

Coc, Alain [Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), CNRS/IN2P3, Université Paris Sud 11, UMR 8609, Bâtiment 104, 91405 Orsay Campus (France); Uzan, Jean-Philippe; Vangioni, Elisabeth [Institut d'Astrophysique de Paris, UMR-7095 du CNRS, Université Pierre et Marie Curie, 98 bis bd Arago, 75014 Paris, France and Sorbonne Universités, Institut Lagrange de Paris, 98 bis bd Arago, 75014 Paris (France)

2014-05-02T23:59:59.000Z

358

PROGRESS IN DESIGNING A MUON COOLING RING WITH LITHIUM LENSES.  

SciTech Connect (OSTI)

We discuss particle tracking simulations in a storage ring with lithium lens inserts designed for the six-dimensional phase space cooling of muons by the ionization cooling. The ring design contains one or more lithium lens absorbers for transverse cooling that transmit the beam with very small beta-function values, in addition to liquid-hydrogen wedge-shaped absorbers in dispersive locations for longitudinal cooling. Such a ring could comprise the final component of a cooling system for use in a muon collider. The beam matching between dipole-quadrupole lattices and the lithium lenses is of particular interest.

FUKUI,Y.CLINE,D.B.GARREN,A.A.KIRK,H.G.

2004-03-03T23:59:59.000Z

359

Shortcut computation for the thermal management of a large air-cooled battery pack  

Science Journals Connector (OSTI)

Abstract Thermal management is crucial to maintain the performance of large battery packs in electric vehicles. To this end, we present herein a shortcut computational method to rapidly estimate the flow and temperature profiles in a parallel airflow-cooled large battery pack with wedge-shaped plenums for airflow distribution. The method couples a flow resistance network model with a transient heat transfer model to calculate the temperature distribution in a battery pack as influenced by the airflows within and among battery modules in the pack. The effects of the plate angle of the plenums, the minimal plenum width and the battery unit spacing on the airflow and temperature distributions are presented. Additionally, an example of collective parameter adjustment for acceptable temperature uniformity of a battery pack subjected to total volume constraint is given.

Zhongming Liu; Yuxin Wang; Jun Zhang; Zhibin Liu

2014-01-01T23:59:59.000Z

360

Lithium As Plasma Facing Component for Magnetic Fusion Research  

SciTech Connect (OSTI)

The use of lithium in magnetic fusion confinement experiments started in the 1990's in order to improve tokamak plasma performance as a low-recycling plasma-facing component (PFC). Lithium is the lightest alkali metal and it is highly chemically reactive with relevant ion species in fusion plasmas including hydrogen, deuterium, tritium, carbon, and oxygen. Because of the reactive properties, lithium can provide strong pumping for those ions. It was indeed a spectacular success in TFTR where a very small amount (~ 0.02 gram) of lithium coating of the PFCs resulted in the fusion power output to improve by nearly a factor of two. The plasma confinement also improved by a factor of two. This success was attributed to the reduced recycling of cold gas surrounding the fusion plasma due to highly reactive lithium on the wall. The plasma confinement and performance improvements have since been confirmed in a large number of fusion devices with various magnetic configurations including CDX-U/LTX (US), CPD (Japan), HT-7 (China), EAST (China), FTU (Italy), NSTX (US), T-10, T-11M (Russia), TJ-II (Spain), and RFX (Italy). Additionally, lithium was shown to broaden the plasma pressure profile in NSTX, which is advantageous in achieving high performance H-mode operation for tokamak reactors. It is also noted that even with significant applications (up to 1,000 grams in NSTX) of lithium on PFCs, very little contamination (< 0.1%) of lithium fraction in main fusion plasma core was observed even during high confinement modes. The lithium therefore appears to be a highly desirable material to be used as a plasma PFC material from the magnetic fusion plasma performance and operational point of view. An exciting development in recent years is the growing realization of lithium as a potential solution to solve the exceptionally challenging need to handle the fusion reactor divertor heat flux, which could reach 60 MW/m2 . By placing the liquid lithium (LL) surface in the path of the main divertor heat flux (divertor strike point), the lithium is evaporated from the surface. The evaporated lithium is quickly ionized by the plasma and the ionized lithium ions can provide a strongly radiative layer of plasma ("radiative mantle"), thus could significantly reduce the heat flux to the divertor strike point surfaces, thus protecting the divertor surface. The protective effects of LL have been observed in many experiments and test stands. As a possible reactor divertor candidate, a closed LL divertor system is described. Finally, it is noted that the lithium applications as a PFC can be quite flexible and broad. The lithium application should be quite compatible with various divertor configurations, and it can be also applied to protecting the presently envisioned tungsten based solid PFC surfaces such as the ones for ITER. Lithium based PFCs therefore have the exciting prospect of providing a cost effective flexible means to improve the fusion reactor performance, while providing a practical solution to the highly challenging divertor heat handling issue confronting the steadystate magnetic fusion reactors.

Masayuki Ono

2012-09-10T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Manganese valence and coordination structure in Mn,Mg-codoped {gamma}-AlON green phosphor  

SciTech Connect (OSTI)

The valence and coordination structure of manganese in a Mn,Mg-codoped {gamma}-AlON spinel-type oxynitride green phosphor were studied by synchrotron X-ray diffraction and absorption fine structure measurements. The absorption edge position of the XANES revealed the bivalency of Mn. Two cation sites are available in the spinel structure for cation doping: a tetrahedral site and an octahedral site. The pre-edge of the XANES and the distance to the nearest neighbor atoms obtained from the EXAFS measurement showed that Mn was situated at the tetrahedral site. Rietveld analysis showed that the vacancy occupied the octahedral site. The preferential occupation of the tetrahedral site by Mn and the roles of N and Mg are discussed in relation to the spinel crystal structure. - Graphical Abstract: Fourier transform of EXAFS of Mn K-edge for Mn,Mg-codoped green phosphor and Mn coordination structure. Highlights: Black-Right-Pointing-Pointer Mn, Mg-codoped {gamma}-AlON green phosphor for white LED. Black-Right-Pointing-Pointer The valence of Mn is divalent. Black-Right-Pointing-Pointer Mn occupies the tetrahedral site in the spinel structure.

Takeda, Takashi, E-mail: TAKEDA.Takashi@nims.go.jp [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Xie, Rong-Jun; Hirosaki, Naoto [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [National Institute for Materials Science (NIMS), NIMS-SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)] [National Institute for Materials Science (NIMS), NIMS-SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Honma, Tetuso [Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)] [Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)

2012-10-15T23:59:59.000Z

362

Lithium-Air Battery: High Performance Cathodes for Lithium-Air Batteries  

SciTech Connect (OSTI)

BEEST Project: Researchers at Missouri S&T are developing an affordable lithium-air (Li-Air) battery that could enable an EV to travel up to 350 miles on a single charge. Today’s EVs run on Li-Ion batteries, which are expensive and suffer from low energy density compared with gasoline. This new Li-Air battery could perform as well as gasoline and store 3 times more energy than current Li-Ion batteries. A Li-Air battery uses an air cathode to breathe oxygen into the battery from the surrounding air, like a human lung. The oxygen and lithium react in the battery to produce electricity. Current Li-Air batteries are limited by the rate at which they can draw oxygen from the air. The team is designing a battery using hierarchical electrode structures to enhance air breathing and effective catalysts to accelerate electricity production.

None

2010-08-01T23:59:59.000Z

363

(Data in metric tons of contained lithium, unless otherwise noted) Domestic Production and Use: The United States was the largest producer and consumer of lithium minerals and  

E-Print Network [OSTI]

and greases and in the production of synthetic rubber. Salient Statistics--United States: 1992 1993 1994 199598 LITHIUM (Data in metric tons of contained lithium, unless otherwise noted) Domestic Production worldwide. The value of domestic lithium production was estimated to be about $115 million in 1996. Two

364

(Data in metric tons of contained lithium, unless noted) Domestic Production and Use: The United States was the largest producer and consumer of lithium minerals and  

E-Print Network [OSTI]

and greases and synthetic rubber production. Salient Statistics--United States: 1991 1992 1993 1994 1995e96 LITHIUM (Data in metric tons of contained lithium, unless noted) Domestic Production and Use. The value of domestic lithium production was estimated to be about $115 million in 1995. Two companies

365

PHYSICAL REVIEW B 84, 205446 (2011) First-principles study of the oxygen evolution reaction of lithium peroxide in the lithium-air battery  

E-Print Network [OSTI]

motivation in seeking batteries with higher specific energies and higher energy den- sities. Metal-air of lithium peroxide in the lithium-air battery Yifei Mo, Shyue Ping Ong, and Gerbrand Ceder* Department) The lithium-air chemistry is an interesting candidate for the next-generation batteries with high specific

Ceder, Gerbrand

366

Comparison of H-Mode Plasmas Diverted to Solid and Liquid Lithium Surfaces  

SciTech Connect (OSTI)

Experiments were conducted with a Liquid Lithium Divertor (LLD) in NSTX. Among the goals was to use lithium recoating to sustain deuterium (D) retention by a static liquid lithium surface, approximating the ability of flowing liquid lithium to maintain chemical reactivity. Lithium evaporators were used to deposit lithium on the LLD surface. Improvements in plasma edge conditions were similar to those with lithiated graphite plasma-facing components (PFCs), including an increase in confinement over discharges without lithiumcoated PFCs and ELM reduction during H-modes. With the outer strike point on the LLD, the D retention in the LLD was about the same as that for solid lithium coatings on graphite, or about two times that achieved without lithium PFC coatings. There were also indications of contamination of the LLD surface, possibly due erosion and redeposition of carbon from PFCs. Flowing lithium may thus be needed for chemically active PFCs during long-pulse operation.

R. Kaita, et. al.

2012-07-20T23:59:59.000Z

367

Lithium and magnetic fields in giants. HD 232862 : a magnetic and lithium-rich giant star  

E-Print Network [OSTI]

We report the detection of an unusually high lithium content in HD 232862, a field giant classified as a G8II star, and hosting a magnetic field. With the spectropolarimeters ESPaDOnS at CFHT and NARVAL at TBL, we have collected high resolution and high signal-to-noise spectra of three giants : HD 232862, KU Peg and HD 21018. From spectral synthesis we have inferred stellar parameters and measured lithium abundances that we have compared to predictions from evolutionary models. We have also analysed Stokes V signatures, looking for a magnetic field on these giants. HD 232862, presents a very high abundance of lithium (ALi = 2.45 +/- 0.25 dex), far in excess of the theoretically value expected at this spectral type and for this luminosity class (i.e, G8II). The evolutionary stage of HD 232862 has been precised, and it suggests a mass in the lower part of the [1.0 Msun ; 3.5 Msun ] mass interval, likely 1.5 to 2.0 solar mass, at the bottom of the Red Giant Branch. Besides, a time variable Stokes V signature has...

Lèbre, A; Nascimento, J D do; Konstantinova-Antova, R; Kolev, D; Aurière, M; De Laverny, P; De Medeiros, J R

2009-01-01T23:59:59.000Z

368

Fact #823: June 2, 2014 Hybrid Vehicles use more Battery Packs but Plug-in Vehicles use More Battery Capacity  

Broader source: Energy.gov [DOE]

Of the battery packs used for electrified vehicle powertrains in model year 2013, the greatest number went into conventional hybrid vehicles which use battery packs that average about 1.3 kilowatt...

369

Performance and Characterization of Lithium-Ion Type Polymer Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Performance and Characterization of Lithium-Ion Type Polymer Batteries Performance and Characterization of Lithium-Ion Type Polymer Batteries Speaker(s): Myung D. Cho Date: January 18, 2002 - 12:00pm Location: Bldg. 90 Seminar Host/Point of Contact: Frank McLarnon A new process for the preparation of lithium-polymer batteries with crosslinked gel-polymer electrolyte will be introduced. The new process employs a thermal crosslinking method rather than cell lamination, and is termed "lithium ion type polymer battery (ITPB)". This thermal crosslinking process has many advantages over the standard lamination method, such as fusing the polymer into the electrodes and better adhesion between the electrolyte and electrodes. The new method results in improved high-temperature stability and a simpler process, as well as the improved

370

Students race lithium ion battery powered cars in Pantex competition |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

race lithium ion battery powered cars in Pantex competition | race lithium ion battery powered cars in Pantex competition | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Home > NNSA Blog > Students race lithium ion battery powered cars ... Students race lithium ion battery powered cars in Pantex competition Posted By Greg Cunningham, Pantex Public Affairs

371

Lithium Ion Electrode Production NDE and QC Considerations  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

3 Presentation name New Directions in Lithium Ion Electrode In-Line NDE * Low-cost IR laser thickness measurement (can be done in multiple point scans across the web or an entire...

372

Understanding Why Silicon Anodes of Lithium-Ion Batteries Are...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Understanding Why Silicon Anodes of Lithium-Ion Batteries Are Fast to Discharge but Slow to Charge December 02, 2014 Measured and calculated rate-performance of a Si thin-film (70...

373

Hierarchically Porous Graphene as a Lithium–Air Battery Electrode  

Science Journals Connector (OSTI)

The lithium–air battery is one of the most promising technologies among various electrochemical energy storage systems. We demonstrate that a novel air electrode consisting of an unusual hierarchical arrangement of functionalized graphene sheets (with no ...

Jie Xiao; Donghai Mei; Xiaolin Li; Wu Xu; Deyu Wang; Gordon L. Graff; Wendy D. Bennett; Zimin Nie; Laxmikant V. Saraf; Ilhan A. Aksay; Jun Liu; Ji-Guang Zhang

2011-10-10T23:59:59.000Z

374

Lithium sulfide compositions for battery electrolyte and battery electrode coatings  

SciTech Connect (OSTI)

Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

2014-10-28T23:59:59.000Z

375

Thermo-mechanical Behavior of Lithium-ion Battery Electrodes  

E-Print Network [OSTI]

Developing electric vehicles is widely considered as a direct approach to resolve the energy and environmental challenges faced by the human race. As one of the most promising power solutions to electric cars, the lithium ion battery is expected...

An, Kai

2013-11-25T23:59:59.000Z

376

Generation of thermonuclear energy by fusing hydrogen and lithium atoms  

Science Journals Connector (OSTI)

A method of designing a thermonuclear reactor based on the modified Cockroft-Walton accelerator, where the lithium-proton fusion was first observed, is considered. It...15 W/cm2...to the cathode are determined. T...

V. E. Tyrsa; L. P. Burtseva

2003-07-01T23:59:59.000Z

377

Novel Electrolyte Enables Stable Graphite Anodes in Lithium Ion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(1) A194-A200 (2014). (1,716 KB) Technology Marketing Summary Berkeley Lab researchers led by Gao Liu have developed an improved lithium ion battery electrolyte containing a...

378

Development of Electrolytes for Lithium-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

4.75V(LNMO) 5.30V(LNMO) Similar surface species are observed on Pt to metal oxide, polyethylene carbonate and lithium fluorophosphates The metal oxide does not appear to catalyze...

379

Helium Pumping Wall for a Liquid Lithium Tokamak Richard Majeski...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Helium Pumping Wall for a Liquid Lithium Tokamak Richard Majeski This invention is designed to be a subsystem of a device, a tokamak with walls or plasma facing components of...

380

Manufacturability Study and Scale-Up for Large Format Lithium...  

Broader source: Energy.gov (indexed) [DOE]

contributions out of over 40 in FY1314 * Selected publications 1. J. Li, B.L. Armstrong, J. Kiggans, C. Daniel, and D.L. Wood, "Lithium Ion Cell Performance Enhancement...

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Advances in 3-Volt Lithium Batteries for Electronic Applications  

Science Journals Connector (OSTI)

Significant improvements have been made in recent years in the performance, reliability and operating temperature range of 3-volt primary lithium cell systems. Because of their excellent characteristics, especially their long life, they are not only ...

R. A. Langan; V. Z. Leger; G. R. Tucholski

1985-08-01T23:59:59.000Z

382

Lithium/antiepileptic drugs/naproxen/aripiprazole/memantine interaction  

Science Journals Connector (OSTI)

A 61-year-old man developed cognition disorders during concomitant use of lithium, valproate semisodium, gabapentin, naproxen, aripiprazole and memantine [duration of treatment to reaction onset not clearly state...

2008-05-01T23:59:59.000Z

383

Three-Dimensional Lithium-Ion Battery Model (Presentation)  

SciTech Connect (OSTI)

Nonuniform battery physics can cause unexpected performance and life degradations in lithium-ion batteries; a three-dimensional cell performance model was developed by integrating an electrode-scale submodel using a multiscale modeling scheme.

Kim, G. H.; Smith, K.

2008-05-01T23:59:59.000Z

384

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications  

E-Print Network [OSTI]

Battery safety has been a very important research area over the past decade. Commercially available lithium ion batteries employ low flash point (<80 °C), flammable, and volatile organic electrolytes. These organic based ...

Hu, Qichao

385

Improvement in Plasma Performance with Lithium Coatings in NSTX  

SciTech Connect (OSTI)

Lithium as a plasma-facing material has attractive features, including a reduction in the recycling of hydrogenic species and the potential for withstanding high heat and neutron fluxes in fusion reactors. Dramatic effects on plasma performance with lithium-coated plasma-facing components (PFCOs) have been demonstrated on many fusion devices, including TFTR, [1] T-11M, [2] and FT-U. [3] Using a liquid-lithium-filled tray as a limiter, the CDX-U device achieved very significant enhancement in the confinement time of ohmically heated plasmas. [4] The recent NSTX experiments reported here have demonstrated, for the first time, significant and recurring benefits of lithium PFC coatings on divertor plasma performance in both L- and H- mode regimes heated by neutral beams.

Kaita, R; Ahn, J -W; Allain, J P; Bell, M G; Bell, R; Boedo, J; Bush, C; Mansfield, D; Menard, J; Mueller, D; Ono, M; Paul, S; Raman, R; Roquemore, A L; Ross, P W; Sabbagh, S; Schneider, H; Skinner, C H; Soukhanovskii, V; Stevenson, T; Stotler, D; Timberlake, J; Wampler, W R; Wilgen, J B

2008-09-12T23:59:59.000Z

386

Improvement in Plasma Performance with Lithium Coatings in NSTX  

SciTech Connect (OSTI)

Lithium as a plasma-facing material has attractive features, including a reduction in the recycling of hydrogenic species and the potential for withstanding high heat and neutron fluxes in fusion reactors. Dramatic effects on plasma performance with lithium-coated plasma-facing components (PFC's) have been demonstrated on many fusion devices, including TFTR, T-11M, and FT-U. Using a liquid-lithium-filled tray as a limiter, the CDX-U device achieved very significant enhancement in the confinement time of ohmically heated plasmas. The recent NSTX experiments reported here have demonstrated, for the first time, significant and recurring benefits of lithium PFC coatings on divertor plasma performance in both L- and H- mode regimes heated by neutral beams.

Kaita, R

2009-02-17T23:59:59.000Z

387

Process for manufacturing a lithium alloy electrochemical cell  

DOE Patents [OSTI]

A process for manufacturing a lithium alloy, metal sulfide cell tape casts slurried alloy powders in an organic solvent containing a dissolved thermoplastic organic binder onto casting surfaces. The organic solvent is then evaporated to produce a flexible tape removable adhering to the casting surface. The tape is densified to increase its green strength and then peeled from the casting surface. The tape is laminated with a separator containing a lithium salt electrolyte and a metal sulfide electrode to form a green cell. The binder is evaporated from the green cell at a temperature lower than the melting temperature of the lithium salt electrolyte. Lithium alloy, metal sulfide and separator powders may be tape cast.

Bennett, William R. (North Olmstead, OH)

1992-10-13T23:59:59.000Z

388

Graphene-Based Composite Anodes for Lithium-Ion Batteries  

Science Journals Connector (OSTI)

Graphene has emerged as a novel, highly promising ... . As an anode material for lithium-ion batteries, it was shown that it cannot be ... cycling that leads to the failure of the batteries. To resolve this probl...

Nathalie Lavoie; Fabrice M. Courtel…

2013-01-01T23:59:59.000Z

389

The application of graphene in lithium ion battery electrode materials  

Science Journals Connector (OSTI)

Graphene is composed of a single atomic layer ... concept, structure, properties, preparation methods of graphene and its application in lithium ion batteries. A continuous 3D conductive network formed by graphene

Jiping Zhu; Rui Duan; Sheng Zhang; Nan Jiang; Yangyang Zhang; Jie Zhu

2014-10-01T23:59:59.000Z

390

Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

Cronin, Alex D.

391

Challenges and Prospects of Lithium–Sulfur Batteries  

Science Journals Connector (OSTI)

His research interests are in the area of materials for rechargeable batteries, fuel cells, and solar cells, including novel synthesis approaches for nanomaterials. ... Lithium-ion (Li-ion) batteries have the highest energy density among the rechargeable battery chemistries. ...

Arumugam Manthiram; Yongzhu Fu; Yu-Sheng Su

2012-10-25T23:59:59.000Z

392

Rechargeable lithium battery energy storage systems for vehicular applications.  

E-Print Network [OSTI]

??Batteries are used on-board vehicles for broadly two applications – starting-lighting-ignition (SLI) and vehicle traction. This thesis examines the suitability of the rechargeable lithium battery… (more)

HURIA, TARUN

2012-01-01T23:59:59.000Z

393

An improved lithium acetate method for yeast transformation  

Science Journals Connector (OSTI)

We have studied the effect on Saccharomyces cerevisiae...transformation frequency of varying several parameters of the lithium acetate-mediated transformation protocol first reported by Ito et al. (1983 a). We fo...

Stewart D. Finlayson; Christine Fleming; David R. Berry…

394

Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries  

E-Print Network [OSTI]

A new cathode material for batteries of high energy density.high-energy cathode for rechargeable lithium batteries. Advanced Materialsmaterials are promising cathodes, as they can provide high power and high energy,

Zhu, Jianxin

2014-01-01T23:59:59.000Z

395

Development of Large Format Lithium Ion Cells with Higher Energy...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen and Fuel Cells Program Review ES-127 Development of Large Format Lithium Ion Cells with Higher Energy Density Erin O'Driscoll (PI) Han Wu (Presenter) Dow Kokam May 13,...

396

Lithium Source For High Performance Li-ion Cells | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-ion Cells Lithium Source For High Performance Li-ion Cells 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

397

Realization of Bose-Einstein condensation with Lithium-7 atoms  

E-Print Network [OSTI]

This thesis presents our work on developing and improving the techniques of trapping and cooling an ultra-cold cloud of Lithium-7 atoms and the realization of the Bose- Einstein condensate as a first step to study quantum ...

Yu, Yichao

2014-01-01T23:59:59.000Z

398

Lithium-rich stars in the Sloan Digital Sky Survey  

E-Print Network [OSTI]

We report the discovery of 23 lithium-rich post-main-sequence stars, identified from moderate-resolution SDSS spectroscopy and confirmed with high-resolution spectra taken at the Hobby-Eberly Telescope. These new Li-rich stars cover a broad range in mass and evolutionary phase, including bright giants and post-AGB stars. The process responsible for preserving or producing excess lithium in a small fraction of evolved stars remains unclear.

Martell, Sarah L

2012-01-01T23:59:59.000Z

399

Lithium Methyl Carbonate as a Reaction Product of Metallic Lithiumand Dimethyl Carbonate  

SciTech Connect (OSTI)

To improve the understanding of passive film formation on metallic lithium in organic electrolyte, we synthesized and characterized lithium methyl carbonate (LiOCO{sub 2}CH{sub 3}), a prototypical component of the film. The chemical structure of this compound was characterized with Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared Spectroscopy (FTIR), and its thermal stability and decomposition pathway was studied by thermo-gravimetric analysis (TGA). The FTIR spectrum of chemically synthesized compound enabled us to resolve multiple products in the passive film on lithium in dimethyl carbonate (DMC). Lithium methyl carbonate is only one of the components, the others being lithium oxalate and lithium methoxide.

Zhuang, Guorong V.; Yang, Hui; Ross Jr., Philip N.; Xu, Kang; Jow, T. Richard

2005-10-16T23:59:59.000Z

400

Recycling of Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

B. Dunn B. Dunn Center for Transportation Research Argonne National Laboratory Recycling of Lithium-Ion Batteries Plug-In 2013 San Diego, CA October 2, 2013 The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government.

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Recent Liquid Lithium Limiter Experiments in CDX-U  

SciTech Connect (OSTI)

Recent experiments in the Current Drive eXperiment-Upgrade (CDX-U) provide a first-ever test of large area liquid lithium surfaces as a tokamak first wall, to gain engineering experience with a liquid metal first wall, and to investigate whether very low recycling plasma regimes can be accessed with lithium walls. The CDX-U is a compact (R=34 cm, a=22 cm, B{sub toroidal} = 2 kG, I{sub P} =100 kA, T{sub e}(0) {approx} 100 eV, n{sub e}(0) {approx} 5 x 10{sup 19} m{sup -3}) spherical torus at the Princeton Plasma Physics Laboratory. A toroidal liquid lithium pool limiter with an area of 2000 cm{sup 2} (half the total plasma limiting surface) has been installed in CDX-U. Tokamak discharges which used the liquid lithium pool limiter required a fourfold lower loop voltage to sustain the plasma current, and a factor of 5-8 increase in gas fueling to achieve a comparable density, indicating that recycling is strongly reduced. Modeling of the discharges demonstrated that the lithium limited discharges are consistent with Z{sub effective} < 1.2 (compared to 2.4 for the pre-lithium discharges), a broadened current channel, and a 25% increase in the core electron temperature. Spectroscopic measurements indicate that edge oxygen and carbon radiation are strongly reduced.

R. Majeski; S. Jardin; R. Kaita; T. Gray; P. Marfuta; J. Spaleta; J. Timberlake; L. Zakharov; G. Antar; R. Doerner; S. Luckhardt; R. Seraydarian; V. Soukhanovskii; R. Maingi; M. Finkenthal; D. Stutman; D. Rodgers; S. Angelini

2005-05-03T23:59:59.000Z

402

Liquid Lithium Limiter Experiments in CDX-U  

SciTech Connect (OSTI)

Recent experiments in the Current Drive Experiment-Upgrade provide a first-ever test of large area liquid lithium surfaces as a tokamak first wall, to gain engineering experience with a liquid metal first wall, and to investigate whether very low recycling plasma regimes can be accessed with lithium walls. The CDX-U is a compact (R = 34 cm, a = 22 cm, B{sub toroidal} = 2 kG, I{sub P} = 100 kA, T{sub e}(0) = 100 eV, n{sub e}(0) {approx} 5 x 10{sup 19} m{sup -3}) spherical torus at the Princeton Plasma Physics Laboratory. A toroidal liquid lithium tray limiter with an area of 2000 cm{sup 2} (half the total plasma limiting surface) has been installed in CDX-U. Tokamak discharges which used the liquid lithium limiter required a fourfold lower loop voltage to sustain the plasma current, and a factor of 5-8 increase in gas fueling to achieve a comparable density, indicating that recycling is strongly reduced. Modeling of the discharges demonstrated that the lithium-limited discharges are consistent with Z{sub effective} < 1.2 (compared to 2.4 for the pre-lithium discharges), a broadened current channel, and a 25% increase in the core electron temperature. Spectroscopic measurements indicate that edge oxygen and carbon radiation are strongly reduced.

R. Majeski; S. Jardin; R. Kaita; T. Gray; P. Marfuta; J. Spaleta; J. Timberlake; L. Zakharov; G. Antar; R. Doerner; S. Luckhardt; R. Seraydarian; V. Soukhanovskii; R. Maingi; M. Finkenthal; D. Stutman; D. Rodgers

2004-10-28T23:59:59.000Z

403

Application of lithium in molten-salt reduction processes.  

SciTech Connect (OSTI)

Metallothermic reductions have been extensively studied in the field of extractive metallurgy. At Argonne National Laboratory (ANL), we have developed a molten-salt based reduction process using lithium. This process was originally developed to reduce actinide oxides present in spent nuclear fuel. Preliminary thermodynamic considerations indicate that this process has the potential to be adapted for the extraction of other metals. The reduction is carried out at 650 C in a molten-salt (LiCl) medium. Lithium oxide (Li{sub 2}O), produced during the reduction of the actinide oxides, dissolves in the molten salt. At the end of the reduction step, the lithium is regenerated from the salt by an electrowinning process. The lithium and the salt from the electrowinning are then reused for reduction of the next batch of oxide fuel. The process cycle has been successfully demonstrated on an engineering scale in a specially designed pyroprocessing facility. This paper discusses the applicability of lithium in molten-salt reduction processes with specific reference to our process. Results are presented from our work on actinide oxides to highlight the role of lithium and its effect on process variables in these molten-salt based reduction processes.

Gourishankar, K. V.

1998-11-11T23:59:59.000Z

404

HIGH-POWER RF DISTRIBUTION SYSTEMFOR THE 8-PACK PROJECT  

SciTech Connect (OSTI)

The 8-Pack Project at SLAC is a prototype rf system whose goal is to demonstrate the high-power X-band technology developed in the NLC/GLC (Next/Global Linear Collider) program. In its first phase, it has reliably produced a 400 ns rf pulse of over 500 MW using a solidstate modulator, four 11.424 GHz klystrons and a dualmoded SLED-II pulse compressor. In Phase 2, the output power of the system has been delivered into the bunker of the NLCTA (Next Linear Collider Test Accelerator) and divided between several accelerator structures for beam acceleration. The authors describe here the design, cold-test measurements, and processing of this power distribution system. Due to the high power levels and the need for efficiency, overmoded waveguide and components are used. For power transport, the TE{sub 01} mode is used in 7.44 cm and 4.064 cm diameter circular waveguide. Only near the structures is standard WR90 rectangular waveguide employed. Components used to manipulate the rf power include transitional tapers, mode converters, overmoded bends, fractional directional couplers, and hybrids.

Nantista, C

2004-08-24T23:59:59.000Z

405

N-Doped Graphene–VO2(B) Nanosheet-Built 3D Flower Hybrid for Lithium Ion Battery  

Science Journals Connector (OSTI)

N-Doped Graphene–VO2(B) Nanosheet-Built 3D Flower Hybrid for Lithium Ion Battery ... Graphene-based electrode materials for rechargeable lithium batteries ...

C. Nethravathi; Catherine R. Rajamathi; Michael Rajamathi; Ujjal K. Gautam; Xi Wang; Dmitri Golberg; Yoshio Bando

2013-03-13T23:59:59.000Z

406

Similar Energetic Contributions of Packing in the Core of Membrane and Water-Soluble Proteins  

SciTech Connect (OSTI)

A major driving force for water-soluble protein folding is the hydrophobic effect, but membrane proteins cannot make use of this stabilizing contribution in the apolar core of the bilayer. It has been proposed that membrane proteins compensate by packing more efficiently. We therefore investigated packing contributions experimentally by observing the energetic and structural consequences of cavity creating mutations in the core of a membrane protein. We observed little difference in the packing energetics of water and membrane soluble proteins. Our results imply that other mechanisms are employed to stabilize the structure of membrane proteins.

Joh, Nathan H.; Oberai, Amit; Yang, Duan; Whitelegge, Julian P.; Bowie, James U.; (UCLA)

2009-09-15T23:59:59.000Z

407

Strong Coupling between 4f Valence Instability and 3d Ferromagnetism in YbxFe4Sb12 Studied by Resonant X-Ray Emission Spectroscopy  

E-Print Network [OSTI]

electrons tends to stabilize magnetic ordered states. Permanent ferromagnets, such as Nd-Fe-B and SmStrong Coupling between 4f Valence Instability and 3d Ferromagnetism in YbxFe4Sb12 Studied valence is independent of temperature. This evidences a close interplay between the magnetic instability

Lin, Jung-Fu "Afu"

408

A linear-scaling self-consistent generalization of the multistate empirical valence bond method for multiple excess protons in aqueous  

E-Print Network [OSTI]

Grot- thuss who proposed a hydrogen­oxygen shuttling mecha- nism to explain electrolysis of water.20 multiple excess protons within the context of molecular-dynamics simulation. The computational cost molecule and forms a valence bond with that oxygen atom. Meanwhile, one of the valence-bonded hydrogen

Simons, Jack

409

Electron Energy-Loss Safe-Dose Limits for Manganese Valence Measurements in Environmentally Relevant Manganese Oxides  

E-Print Network [OSTI]

19717-1303, United States § U.S. Army Engineer Research & Development Center, 3909 Halls Ferry Road are among the strongest mineral oxidants in the environment and impose significant influence on mobility. INTRODUCTION Mn exists in the 2+, 3+, and 4+ valence states in natural environment and, most of the time, as Mn

Sparks, Donald L.

410

Valence-electron distribution in MgB2 by accurate diffraction measurements and first-principles calculations  

E-Print Network [OSTI]

-principles calculations A great challenge in the studies of condensed matter is to measure the redistribution of electrons on precision electron-diffraction measurements and DFT calculations. (h-i) DFT calculated difference chargeValence-electron distribution in MgB2 by accurate diffraction measurements and first

Homes, Christopher C.

411

Extended Near-Infrared Resonance Raman Investigations of an Organic Mixed-Valence System: Diazatetracyclodiene Radical Cation  

E-Print Network [OSTI]

Extended Near-Infrared Resonance Raman Investigations of an Organic Mixed-Valence System near-infrared region show that six modes are coupled to the intramolecular charge-transfer transition transfer (IVCT) absorption bands in the red to near- infrared region of the spectrum, which are, at least

412

Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nucleation and Growth Process of Li2S2Li2S in Lithium-Sulfur Batteries. Controlled Nucleation and Growth Process of Li2S2Li2S in Lithium-Sulfur Batteries. Abstract:...

413

Synthesis Of Nitrogen-Doped Graphene Films For Lithium Battery Application  

Science Journals Connector (OSTI)

Synthesis Of Nitrogen-Doped Graphene Films For Lithium Battery Application ... Fabrication of Nitrogen-Doped Holey Graphene Hollow Microspheres and Their Use as an Active Electrode Material for Lithium Ion Batteries ...

Arava Leela Mohana Reddy; Anchal Srivastava; Sanketh R. Gowda; Hemtej Gullapalli; Madan Dubey; Pulickel M. Ajayan

2010-10-08T23:59:59.000Z

414

Biologically enhanced cathode design for improved capacity and cycle life for lithium-oxygen batteries  

E-Print Network [OSTI]

Lithium-oxygen batteries have a great potential to enhance the gravimetric energy density of fully packaged batteries by two to three times that of lithium ion cells. Recent studies have focused on finding stable electrolytes ...

Oh, Dahyun

415

Design of Safer High-Energy Density Materials for Lithium-Ion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safer High-Energy Density Materials for Lithium-Ion Cells Design of Safer High-Energy Density Materials for Lithium-Ion Cells 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

416

LITHIUM ISOTOPIC COMPOSITION OF CHONDRITIC METEORITES. W. F. McDonough1 , P. B. Tomascak1  

E-Print Network [OSTI]

LITHIUM ISOTOPIC COMPOSITION OF CHONDRITIC METEORITES. W. F. McDonough1 , F- Z. Teng1 , P. B processes involving aqueous fluids, given the potential solubility of lithium [1]. In this respect, Li

Mcdonough, William F.

417

Thin film lithium-based batteries and electrochromic devices fabricated with nanocomposite electrode materials  

DOE Patents [OSTI]

Thin-film lithium-based batteries and electrochromic devices (10) are fabricated with positive electrodes (12) comprising a nanocomposite material composed of lithiated metal oxide nanoparticles (40) dispersed in a matrix composed of lithium tungsten oxide.

Gillaspie, Dane T; Lee, Se-Hee; Tracy, C. Edwin; Pitts, John Roland

2014-02-04T23:59:59.000Z

418

Post-Test Analysis of Lithium-Ion Battery Materials at Argonne...  

Broader source: Energy.gov (indexed) [DOE]

Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory 2013 DOE Hydrogen...

419

Thermal behaviors of electrolytes in lithium-ion batteries determined by differential scanning calorimeter  

Science Journals Connector (OSTI)

Lithium-ion batteries have been widely used in daily electric ... occurred from time to time. Lithium-ion batteries composed of various electrolytes (containing organic solvents ... to meet safety requirements of...

Yu-Yun Sun; Tsai-Ying Hsieh; Yih-Shing Duh…

2014-06-01T23:59:59.000Z

420

E-Print Network 3.0 - aluminum-lithium alloys processed Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aluminum-lithium alloys, there is a precipitation of metastable, coherent, L1... and fracture toughness of aluminum-lithium alloys can be improved by the addition of zirconium...

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

A new cathode material for batteries of high energy density.art positive electrode materials for high-energy lithium ionwhen exploring new materials for high-energy lithium ion

Wilcox, James D.

2010-01-01T23:59:59.000Z

422

E-Print Network 3.0 - all-solid-state lithium secondary Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SOC and SOH of Lithium-ion Cells A. Zenati1,* , Ph. Desprez1 , H. Razik2 and S. Rael3 1 SAFT... at analyzing lithium-ion batteries performances with aging, for different state of...

423

Modular Approach for Continuous Cell-Level Balancing to Improve Performance of Large Battery Packs: Preprint  

SciTech Connect (OSTI)

Energy storage systems require battery cell balancing circuits to avoid divergence of cell state of charge (SOC). A modular approach based on distributed continuous cell-level control is presented that extends the balancing function to higher level pack performance objectives such as improving power capability and increasing pack lifetime. This is achieved by adding DC-DC converters in parallel with cells and using state estimation and control to autonomously bias individual cell SOC and SOC range, forcing healthier cells to be cycled deeper than weaker cells. The result is a pack with improved degradation characteristics and extended lifetime. The modular architecture and control concepts are developed and hardware results are demonstrated for a 91.2-Wh battery pack consisting of four series Li-ion battery cells and four dual active bridge (DAB) bypass DC-DC converters.

Muneed ur Rehman, M.; Evzelman, M.; Hathaway, K.; Zane, R.; Plett, G. L.; Smith, K.; Wood, E.; Maksimovic, D.

2014-10-01T23:59:59.000Z

424

Lattice Boltzmann Simulation of Mixed Convection in a Driven Cavity Packed with Porous Medium  

Science Journals Connector (OSTI)

The problem of mixed convection in a driven cavity packed with porous medium is studied with lattice Boltzmann method. A lattice Boltzmann model for incompressible flow in porous media and another thermal lattice

Zhenhua Chai; Zhaoli Guo; Baochang Shi

2007-01-01T23:59:59.000Z

425

Experimental Investigation of Chemical-Looping Combustion in Packed Beds: A Parametric Study  

Science Journals Connector (OSTI)

Recently a novel reactor concept for chemical-looping combustion (CLC) has been proposed exploiting dynamically operated packed beds. In this work, an experimental parametric study on this reactor concept has been carried out. The effects of operating ...

S. Noorman; F. Gallucci; M. van Sint Annaland; J. A. M. Kuipers

2011-01-18T23:59:59.000Z

426

Electrostatics and packing in biomolecules : accounting for conformational change in protein folding and binding  

E-Print Network [OSTI]

The role of electrostatics and packing in protein folding and molecular association was assessed in different biomolecular systems. A continuum electrostatic model was applied to long-range electrostatic effects in the ...

Caravella, Justin Andrew, 1974-

2002-01-01T23:59:59.000Z

427

Measuring Frac-pack Conductivity at Reservoir Temperature and High Closure Stress  

E-Print Network [OSTI]

fractures packed with high proppant concentrations. Understanding the behavior of the fracture fluid and proppant is critical to pump such a job successfully and to ensure long term productivity from the fracture. A series of laboratory experiments have been...

Fernandes, Preston X.

2010-10-12T23:59:59.000Z

428

Storage characteristics of fresh fish packed in modified gas atmospheres containing carbon dioxide  

E-Print Network [OSTI]

STORAGE CHARACTERISTICS OF FRESH FISH PACKED IN MODIFIED GAS ATMOSPHERES CONTAINING CARBON DIOXIDE A Thesis by MICHEL LANNELONGUE FAVRE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1980 Major Subject: Food Science and Technology STORAGE CHARACTERISTICS OF FRESH FISH PACKED IN MODIFIED GAS ATMOSPHERES CONTAINING CARBON DIOXIDE A Thesis by MICHEL LANNELONGUE FAVRE Approved as to style...

Lannelongue-Favre, Michel

2012-06-07T23:59:59.000Z

429

The Scaleup of Structured Packing from Distillation Pilot Plant Testing to Commercial Application  

E-Print Network [OSTI]

design bases for a distillation train. The actual pilot plant testing involved a different structured packing type and blocked out operations to simulate a large number of theoretical stages. The pilot plant results verified the thermodynamic data... high efficiency per unit height of this structured packing and its excellent sc~leup characteristics. To pilot the large number of theoretical stages, it was decided to divide the column into two sections and run each section in a blocked out...

Berven, O. J.; Ulowetz, M. A.

430

Investigation of the thermal conductivity of unconsolidated sand packs containing oil, water, and gas  

E-Print Network [OSTI]

INVESTIGATION OF THE THERNAL CONDUCTIVITY OF UNCONSOLIDATED SAND PACKS CONTAINING OIL, WATER, AND GAS A Thesis David E. Gore Submitted to the Graduate School of the Agricultural and Nechanical College oi' Texas in Partial fulfillment.... EXPERIMENTAL EQUIPMENT AND PROCEDURE All tests were performed on unconsolidated sand packs containing either one, two, or three saturating fluids, Phys- ical properties of the sand and saturating fluids are shown in Tables I and II in the Appendix...

Gore, David Eugene

2012-06-07T23:59:59.000Z

431

Advanced Electrolyte Additives for PHEV/EV Lithium-ion Battery...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Electrolyte Additives for PHEVEV Lithium-ion Battery Development of Advanced Electrolytes and Electrolyte Additives...

432

Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperature  

E-Print Network [OSTI]

lithium batteries. Because the stoichiometric spinel LiMn204 exhibits significant capacity fading during charge/discharge cycling, excess

Chen, Guoying

2010-01-01T23:59:59.000Z

433

Packing-Based Approximation Algorithm for the k-Set Cover Problem  

E-Print Network [OSTI]

We present a packing-based approximation algorithm for the $k$-Set Cover problem. We introduce a new local search-based $k$-set packing heuristic, and call it Restricted $k$-Set Packing. We analyze its tight approximation ratio via a complicated combinatorial argument. Equipped with the Restricted $k$-Set Packing algorithm, our $k$-Set Cover algorithm is composed of the $k$-Set Packing heuristic \\cite{schrijver} for $k\\geq 7$, Restricted $k$-Set Packing for $k=6,5,4$ and the semi-local $(2,1)$-improvement \\cite{furer} for 3-Set Cover. We show that our algorithm obtains a tight approximation ratio of $H_k-0.6402+\\Theta(\\frac{1}{k})$, where $H_k$ is the $k$-th harmonic number. For small $k$, our results are 1.8667 for $k=6$, 1.7333 for $k=5$ and 1.5208 for $k=4$. Our algorithm improves the currently best approximation ratio for the $k$-Set Cover problem of any $k\\geq 4$.

Furer, Martin

2011-01-01T23:59:59.000Z

434

Effect of packing material on methane activation in a dielectric barrier discharge reactor  

SciTech Connect (OSTI)

The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using ?-Al{sub 2}O{sub 3} (sphere), ?-Al{sub 2}O{sub 3} (sphere), and ?-Al{sub 2}O{sub 3} (16–20 mesh). Investigations on the surface properties and shape of the three packing materials clearly indicate that methane activation is considerably affected by the material used. Capacitances inside the discharge gap are estimated from charge–voltage plots, and a comparison of the generated and transferred charges for different packing conditions show that the difference in surface properties between ?- and ?-phase Al{sub 2}O{sub 3} affects the discharge characteristics. Moreover, all packing conditions show different charge characteristics that are related to the electron density. Finally, the packing material's shape affects the local electron temperature, which is strongly related to methane conversion. The combined results indicate that both microscale and macroscale variations in a packing material affect the discharge characteristics, and a packing material should be considered carefully for effective methane activation.

Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon [Korea Institute of Machinery and Materials, 156 Gajeongbuk-ro, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)] [Korea Institute of Machinery and Materials, 156 Gajeongbuk-ro, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

2013-12-15T23:59:59.000Z

435

Adaptable Silicon–Carbon Nanocables Sandwiched between Reduced Graphene Oxide Sheets as Lithium Ion Battery Anodes  

Science Journals Connector (OSTI)

Adaptable Silicon–Carbon Nanocables Sandwiched between Reduced Graphene Oxide Sheets as Lithium Ion Battery Anodes ... Despite rapidly growing interest in the application of graphene in lithium ion batteries, the interaction of the graphene with lithium ions and electrolyte species during electrochemical cycling is not fully understood. ...

Bin Wang; Xianglong Li; Xianfeng Zhang; Bin Luo; Meihua Jin; Minghui Liang; Shadi A. Dayeh; S. T. Picraux; Linjie Zhi

2013-01-02T23:59:59.000Z

436

EXPERIMENTAL MEASUREMENTS OF THE INTERFACE THERMAL CONDUCTANCE OF A LITHIUM METATITANATE PEBBLE BED  

E-Print Network [OSTI]

, CA 90095 aliabousena@engineering.ucla.edu The thermal properties of the lithium ceramics pebble beds will help to create a reliable database of the thermal properties of the lithium ceramics pebble beds. I heat is transferred from the hot lithium ceramic pebble beds to the coolant. The thermal properties

Abdou, Mohamed

437

Limited lithium isotopic fractionation during progressive metamorphic dehydration in metapelites: A case study  

E-Print Network [OSTI]

Limited lithium isotopic fractionation during progressive metamorphic dehydration in metapelites-zone metamorphism far removed from the pluton to partially melted rocks adjacent to the pluton. Lithium on the aureole scale. Published by Elsevier B.V. Keywords: Lithium; Isotope fractionation; Metamorphic

Mcdonough, William F.

438

Lithium in Jack Hills zircons: Evidence for extensive weathering of Earth's earliest crust Takayuki Ushikubo a,  

E-Print Network [OSTI]

Lithium in Jack Hills zircons: Evidence for extensive weathering of Earth's earliest crust Takayuki Hills lithium weathering continental crust Hadean In situ Li analyses of 4348 to 3362 Ma detrital of REEs. The Jack Hills zircons also have fractionated lithium isotope ratios (7 Li=-19 to+13) about five

Mcdonough, William F.

439

Extreme lithium isotopic fractionation during continental weathering revealed in saprolites from South Carolina  

E-Print Network [OSTI]

Extreme lithium isotopic fractionation during continental weathering revealed in saprolites from in revised form 6 July 2004 Abstract The lithium concentration and isotopic composition of two saprolites the behavior of lithium isotopes during continental weathering. Both saprolites show a general trend

Rudnick, Roberta L.

440

Lithium in cool stellar atmospheres: Big bang nucleosynthesis and extrasolar planets  

E-Print Network [OSTI]

Lithium in cool stellar atmospheres: Big bang nucleosynthesis and extrasolar planets Matthias Steffen and Elisabetta Caffau Sternphysik In metal-poor stellar atmospheres, the Lithium line at 6707 Ã?-NLTE, respectively. The accurate spectroscopic determination of the Lithium abundance and in particular the 6Li/7Li

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Lithium isotopic composition and concentration of the deep continental crust Fang-Zhen Teng a,  

E-Print Network [OSTI]

Lithium isotopic composition and concentration of the deep continental crust Fang-Zhen Teng a April 2008 Accepted 5 June 2008 Editor: B. Bourdon Keywords: Lithium Isotope fractionation Deep. Lithium concentrations of granulite xenoliths also vary widely (0.5 to 21 ppm) and are, on average, lower

Mcdonough, William F.

442

Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota  

E-Print Network [OSTI]

Lithium isotopic systematics of granites and pegmatites from the Black Hills, South Dakota Fang compositions may reflect Li isotopic fractionation resulting from extensive crystal-melt fractionation. Lithium fractionation in the near­surface environment of > 60 (Tomascak, 2004). Lithium isotopic fractionation has been

Rudnick, Roberta L.

443

Lithium diffusion mechanisms in layered intercalation compounds A. Van der Ven*  

E-Print Network [OSTI]

Lithium diffusion mechanisms in layered intercalation compounds A. Van der Ven* , G. Ceder; accepted 28 December 2000 Abstract We investigate the mechanisms of lithium diffusion in layered intercalation compounds from ®rst-principles. We focus on LixCoO2 and ®nd that lithium diffusion

Ceder, Gerbrand

444

Reply: Lithium and Increased Cortical Gray Matter--More Tissue or More Water?  

E-Print Network [OSTI]

Reply: Lithium and Increased Cortical Gray Matter--More Tissue or More Water? To the Editor: W e cortices, in lithium-treated patients with bipolar disorder, relative to healthy control subjects (1). Dr patients. Although lithium's effects on body water homeostasis (2) are important to consider, the absence

Thompson, Paul

445

Abstract: The deproto-metalation reactions of pyrimidine and pyrazine were regioselectively carried out using lithium  

E-Print Network [OSTI]

carried out using lithium tri(2,2,6,6-tetramethylpiperidino)cadmate in tetrahydrofuran at room temperature instead of 1/3). Key words: Metalations, Cadmium, Lithium, Heterocycles, Iodine. Procedure 1 25 mmol scale metalation of aromatic rings, and various strong bases such as alkylli- thiums and lithium dialkylamides have

Boyer, Edmond

446

Solid state thin film battery having a high temperature lithium alloy anode  

DOE Patents [OSTI]

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

Hobson, D.O.

1998-01-06T23:59:59.000Z

447

Local Electromechanical Response at a Single Ferroelectric Domain Wall in Lithium Niobate  

E-Print Network [OSTI]

-antisites (which are excess Nb atoms at Li locations), and lithium vacancies denoted by Li. The defect equilibriumLocal Electromechanical Response at a Single Ferroelectric Domain Wall in Lithium Niobate DAVID A electromechanical response across a single ferroelectric domain wall in congruent lithium niobate at room

Gopalan, Venkatraman

448

Fabricating Genetically Engineered High-Power Lithium-Ion Batteries Using Multiple Virus Genes  

Science Journals Connector (OSTI)

...system) and a photograph of the battery used to power a green LED...electrode in a lithium-ion battery using lithium metal foil as...nanowires as a lithium-ion battery cathode was evaluated (Fig...expected to bind favorably to the graphene surface via {pi}-stacking...

Yun Jung Lee; Hyunjung Yi; Woo-Jae Kim; Kisuk Kang; Dong Soo Yun; Michael S. Strano; Gerbrand Ceder; Angela M. Belcher

2009-05-22T23:59:59.000Z

449

Understanding structural defects in lithium-rich layered oxide cathodes Karalee A. Jarvis,a  

E-Print Network [OSTI]

the required amounts of lithium, manganese, and nickel acetates were added to this solution. The molar ratioUnderstanding structural defects in lithium-rich layered oxide cathodes Karalee A. Jarvis, Accepted 31st March 2012 DOI: 10.1039/c2jm30575e Planar defects in lithium-rich layered oxides were

Ferreira, Paulo J.

450

Abstract--This paper describes experimental results aiming at analyzing lithium-ion batteries performances  

E-Print Network [OSTI]

several years SAFT has developed a range of lithium ion cells and batteries to cover the full spectrum. To follow such a characteristic, electrochemical impedance spectroscopy (EIS) measurements on SAFT lithium-ion cells The cells used are lithium-ion SAFT power cells: VL30P which outputs a nominal capacity of 30 Ah

Paris-Sud XI, Université de

451

Molecular Structure and Stability of Dissolved Lithium Polysulfide Species  

SciTech Connect (OSTI)

Ability to predict the solubility and stability of lithium polysulfide is vital in realizing longer lasting lithium-sulfur batteries. Herein we report a combined computational and experimental spectroscopic analysis to understand the dissolution mechanism of lithium polysulfide species in an aprotic solvent medium. Multinuclear NMR and sulfur K-edge X-ray absorption (XAS) analysis reveals that the lithium exchange between polysulfide species and solvent molecule constitutes the first step in the dissolution process. Lithium exchange leads to de-lithiated polysulfide ions which subsequently forms highly reactive free radicals through disproportion reaction. The energy required for the disproportion and possible dimer formation reactions of the polysulfide species are analyzed using density functional theory (DFT) calculations. We validate our calculations with variable temperature electron spin resonance (ESR) measurements. Based on these findings, we discuss approaches to optimize the electrolyte in order to control the polysulfide solubility. The energy required for the disproportion and possible dimer formation reactions of the polysulfide species are analyzed using density functional theory (DFT) calculations. We validate our calculations with variable temperature electron spin resonance (ESR) measurements. Based on these findings, we discuss approaches to optimize the electrolyte in order to control the polysulfide solubility.

Vijayakumar, M.; Govind, Niranjan; Walter, Eric D.; Burton, Sarah D.; Shukla, Anil K.; Devaraj, Arun; Xiao, Jie; Liu, Jun; Wang, Chong M.; Karim, Ayman M.; Thevuthasan, Suntharampillai

2014-03-24T23:59:59.000Z

452

Recent advances in lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithium–sulfur (Li–S) batteries have attracted much attention lately because they have very high theoretical specific energy (2500 Wh kg?1), five times higher than that of the commercial LiCoO2/graphite batteries. As a result, they are strong contenders for next-generation energy storage in the areas of portable electronics, electric vehicles, and storage systems for renewable energy such as wind power and solar energy. However, poor cycling life and low capacity retention are main factors limiting their commercialization. To date, a large number of electrode and electrolyte materials to address these challenges have been investigated. In this review, we present the latest fundamental studies and technological development of various nanostructured cathode materials for Li–S batteries, including their preparation approaches, structure, morphology and battery performance. Furthermore, the development of other significant components of Li–S batteries including anodes, electrolytes, additives, binders and separators are also highlighted. Not only does the intention of our review article comprise the summary of recent advances in Li–S cells, but also we cover some of our proposals for engineering of Li–S cell configurations. These systematic discussion and proposed directions can enlighten ideas and offer avenues in the rational design of durable and high performance Li–S batteries in the near future.

Lin Chen; Leon L. Shaw

2014-01-01T23:59:59.000Z

453

A resolution of the cosmic Lithium problem  

E-Print Network [OSTI]

In 1982, Monique and Francois Spite discovered that the 7Li abundance in the atmosphere of old metal-poor dwarf stars in the galactic halo was independent of metallicity and temperature. Since then, 7Li abundance in the Universe has become a subject of intrigue, because there is less of it in Population II dwarf stars (by a factor of 3) than standard big bang nucleosynthesis predicts. Here we show how quark-novae (QNe) occurring in the wake of Pop. III stars, can elegantly produce an A(Li) ~ 2.2 Lithium plateau in Pop. II (low-mass) stars formed in the pristine cloud swept up by the mixed SN+QN ejecta. We also find an increase in the scatter as well as an eventual drop in A(Li) below the Spite plateau values for very low metallicity ([Fe/H] < -3) in excellent agreement with observations. We propose a solution to the discrepancy between the Big Bang Nucleosynthesis 7Li abundance and the Spite plateau and list some implications and predictions of our model.

Rachid Ouyed

2014-02-20T23:59:59.000Z

454

Lithium bromide chiller technology in gas processing  

SciTech Connect (OSTI)

Lithium Bromide (LiBr) Absorption Chillers have been in use for more than half a century, mainly in the commercial air conditioning industry. The Gas Research Institute and EnMark Natural Gas Company co-funded a field test to determine the viability of this commercial air conditioning technology in the gas industry. In 1991, a 10 MMCFC natural gas conditioning plant was constructed in Sherman, Texas. The plant was designed to use a standard, off-the-shelf chiller from Trane with a modified control scheme to maintain tight operating temperature parameters. The main objective was to obtain a 40 F dewpoint natural gas stream to meet pipeline sales specifications. Various testing performed over the past three years has proven that the chiller can be operated economically and on a continuous basis in an oilfield environment with minimal operation and maintenance costs. This paper will discuss how a LiBr absorption chiller operates, how the conditioning plant performed during testing, and what potential applications are available for LiBr chiller technology.

Huey, M.A.; Leppin, D.

1995-12-31T23:59:59.000Z

455

ABAA - 6th International Conference on Advanced Lithium Batteries for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Greetings! Greetings! Khalil Amine Chairman Khalil Amine Dear Colleagues, Welcome to the website of the 6th International Conference on Advanced Lithium Batteries for Automotive Applications (ABAA6). As Chairman of the ABAA Conference Organizing Committee, it is my great pleasure to cordially invite you to attend ABAA6. Every year, the ABAA Conference Organizing Committee hosts distinguished speakers from all over the world in the field of lithium battery research and development with a focus on automotive applications. ABAA6's primary goal is to provide attendees from both academia and industry an opportunity to meet and exchange information on advances in lithium battery research with the aim of enabling the electrification of vehicles. This year, the conference will focus on:

456

hybrid electric vehicle and lithium polymer nev testing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

P1.2 - Hybrid Electric Vehicle and Lithium Polymer NEV Testing P1.2 - Hybrid Electric Vehicle and Lithium Polymer NEV Testing James Edward Francfort Advanced Vehicle Testing Activity Idaho National Laboratory P.O. Box 1625, Idaho Falls, ID. 83415-3830 james.francfort@inl.gov Abstract: The U.S. Department of Energy's Advanced Vehicle Testing Activity tests hybrid electric, pure electric, and other advanced technology vehicles. As part of this testing, 28 hybrid electric vehicles (HEV) are being tested in fleet, dynamometer, and closed track environments. This paper discusses some of the HEV test results, with an emphasis on the battery performance of the HEVs. It also discusses the testing results for a small electric vehicle with a lithium polymer traction battery. Keywords: hybrid; neighborhood; electric; battery; fuel;

457

Overcharge Protection for the New Generation of Lithium Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Overcharge Protection for the New Generation of Lithium Batteries Overcharge Protection for the New Generation of Lithium Batteries Speaker(s): Thomas Richardson Date: January 18, 2001 - 12:00pm Location: Bldg 90 Seminar Host/Point of Contact: Satkartar K. Kinney Lithium batteries supplied with cellular telephones and other personal electronic devices provide unprecedented power and capacities in very small formats. They are able to deliver such high performance because they incorporate highly reactive materials in both the positive and negative electrodes, resulting in individual cell potentials of nearly 4 V. Exposure to high temperatures or abusive treatment including overcharging can cause catastrophic failure of these batteries, resulting in gas venting, fire, or even explosion. Mechanical and electronic safety devices are employed to

458

Lithium ion batteries with titania/graphene anodes  

DOE Patents [OSTI]

Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

2013-05-28T23:59:59.000Z

459

Microstructure-strength relationships of heavily deformed magnesium-lithium composites containing steel fibers  

SciTech Connect (OSTI)

The successful development of deformation-processed metal-metal composites (DMMC) offers the potential for ductile, high-strength structural materials with high-temperature stability. An infiltration casting process was used to permeate steel wool preforms with molten magnesium-lithium (Mg-Li) alloys. The selected matrix alloys were hexagonal close packed (HCP) Mg-4wt%Li or body centered cubic (BCC) Mg-12wt%Li; the low carbon steel wool fibers were predominantly BCC ferrite. These cast HCP/BCC and BCC/BCC composites were deformed by rolling or by extrusion and swaging. Mechanical properties, microstructure, and texture development of the composites were characterized at various levels of deformation. The HCP/BCC composites had limited formability at temperatures up to 400 C while the BCC/BCC composites had excellent formability during sheet rolling at room temperature but limited formability during swaging at room temperature. The tensile strengths of these HCP/BCC and BCC/BCC composite materials increased moderately with deformation, though less than predicted from rule of mixtures (ROM) calculations. The microstructure was characterized to correlate the filament size to the deformation strain and mechanical properties of the composite material. Stereological measurements of the filament size were used to adjust ROM calculations to reflect the actual deformation strain in the fibers. However, the experimental strengths of these composite materials were still less than ROM predictions, possibly due to the presence of considerably large fibers. Of the many models used to describe the strengthening observed in DMMC materials, the Hall-Petch relationship adequately described the experimental data. Texture development was also characterized to explain the deformation characteristics of the composite materials. Chapters 2, 3 and 4 are not included here. They are being processed separately.

Jensen, J.

1997-10-08T23:59:59.000Z

460

Structural analysis of lithium-excess lithium manganate cathode materials by 7Li magic-angle spinning nuclear magnetic resonance spectroscopy  

Science Journals Connector (OSTI)

The local structures of lithium-excess lithium manganese spinel oxides were studied by high-resolution solid-state 7Li magic-angle spinning (MAS) NMR spectroscopy. Two resonance lines at ?500 and ?555 ppm were observed for the spinels in 7Li MAS NMR spectra. Spinel stability tests in which spinel powder was stored in electrolyte solution were performed to analyze the changes in the lithium local structure after manganese dissolution. After the spinel stability test, the intensity of the resonance at ?500 ppm decreased, whereas new resonance line at 0 ppm was observed. The lithium content of the 0 ppm peak increases with the storage time in electrolyte. SEM and chemical analysis suggested a surface coating of non-spinel lithium compounds, the presence of defects on particles surface and fluorine incorporation into the aged spinel. In addition, about 60–70% of lithium remains in the spinel framework after the storage.

Hideyuki Oka; Senshi Kasahara; Tadashi Okada; Eiichi Iwata; Masaki Okada; Takayuki Shoji; Hiroshi Ohki; Tsutomu Okuda

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

A Car–Parrinello and path integral molecular dynamics study of the intramolecular lithium bond in the lithium 2-pyridyl- N -oxide acetate  

Science Journals Connector (OSTI)

Lithium bonding in lithium 2-pyridyl- N -oxide acetate has been investigated using classic Car–Parrinello molecular dynamics (CPMD) and the path integral approach [path integrals molecular dynamics (PIMD)]. The simulations have been performed in 300 K. Structures energies and lithium trajectories have been determined. The CPMD results show that the lithium atom is generally equidistant between heavy atoms in the ( O ? Li ? O ) bridge. Applying quantum effects through the PIMD leads to similar conclusion. The theoretical lithium 2-pyridyl- N -oxide acetate infrared spectrum has also been determined using the CPMD calculations. This shows very good agreement with available experimental results and reproduces well the broad low-frequency band observed experimentally. In order to gain deeper understanding of the nature of the lithium bonding topological analysis of the electron localization function has been applied.

Piotr Durlak; Zdzis?aw Latajka; S?awomir Berski

2009-01-01T23:59:59.000Z

462

Shear thickening and jamming in densely packed suspensions of different particle shapes  

E-Print Network [OSTI]

We investigated the effects of particle shape on shear thickening in densely packed suspensions. Rods of different aspect ratios and non-convex hooked rods were fabricated. Viscosity curves and normal stresses were measured using a rheometer for a wide range of packing fractions for each shape. Suspensions of each shape exhibit qualitatively similar Discontinuous Shear Thickening. The logarithmic slope of the stress/shear-rate relation increases dramatically with packing fraction and diverges at a critical packing fraction phi_c which depends on particle shape. The packing fraction dependence of the viscosity curves for different convex shapes can be collapsed when the packing fraction is normalized by phi_c. Intriguingly, viscosity curves for non-convex particles do not collapse on the same set as convex particles, showing strong shear thickening over a wider range of packing fraction. The value of phi_c is found to coincide with the onset of a yield stress at the jamming transition, suggesting the jamming transition also controls shear thickening. The yield stress is found to correspond with trapped air in the suspensions, and the scale of the stress can be attributed to interfacial tension forces which dramatically increase above phi_c due to the geometric constraints of jamming. The relationship between shear and normal stresses is found to be linear in both the shear thickening and jammed regimes, indicating that the shear stresses come from friction. In the limit of zero shear rate, normal stresses pull the rheometer plates together due to the surface tension of the liquid below phi_c, but push the rheometer plates apart due to jamming above phi_c.

Eric Brown; Hanjun Zhang; Nicole A. Forman; Benjamin W. Maynor; Douglas E. Betts; Joseph M. DeSimone; Heinrich M. Jaeger

2011-06-30T23:59:59.000Z

463

First-principles study of graphene-lithium structures for battery applications  

Science Journals Connector (OSTI)

In order to identify the best and most promising graphene-lithium structures for battery applications we performed a systematic study of different multilayer graphene-lithium structures using first-principles density-functional theory. The most promising structure identified is a few layer compound which contains a single graphene layer and four lithium layers. In this structure lithium density is six times higher than that of intercalated graphite and high lithium density observed in recent experiments can be due to this structure. In addition we show that electron density distribution around the positive Li ions is very important to design new advanced materials for battery applications.

Alper Buldum; Gulcin Tetiker

2013-01-01T23:59:59.000Z

464

Lithium Isotope Analyses of Inorganic Constituents from the Murchison Meteorite  

Science Journals Connector (OSTI)

Aqueous processes were important modifiers of solid matter during the early stages of solar system history. Lithium isotopes are sensitive indicators of such solid-liquid interactions because 7Li passes preferentially into solution and 6Li remains behind in the solid phase. Lithium isotope ratios of inorganic phases in the Murchison meteorite reveal that the value for the whole rock is simply the average of individual components with widely different isotopic compositions. 7Li content increases from chondrules to phyllosilicate-rich matrices to carbonates, as would be expected from the relative duration each component has spent during aqueous alteration on the parent asteroid.

Mark A. Sephton; Rachael H. James; Philip A. Bland

2004-01-01T23:59:59.000Z

465

Micro-Columnated Loop Heat Pipe: The Future of Electronic Substrates  

E-Print Network [OSTI]

8]; (b) A lithium-ion (Li-ion) battery pack consisting of 488]; (b) A lithium-ion (Li-ion) battery pack consisting of 48

Dhillon, Navdeep Singh

2012-01-01T23:59:59.000Z

466

Impact of solid fuel combustion technology on valence speciation of chromium in fly ash  

Science Journals Connector (OSTI)

Abstract Fly ash (FA) generated in real furnaces was used to evaluate the impact of the kind of the solid fuel burnt and combustion technology on chromium speciation, particularly the presence of Cr(III) and Cr(VI) forms as well as readily and hardly leachable chromium(VI) species in FAs. The \\{FAs\\} originated from a pulverized coal combustion boiler (PCC boiler), a fluidized bed combustion boiler (FBC boiler), a stoker-fired boiler (SF boiler), a municipal solid waste incinerator (MSWI), a cement rotary kiln (CRK) and a modern domestic boiler (DB). The speciation analysis of chromium was carried out by means of extraction followed by catalytic cathodic stripping voltammetry with adsorption of Cr(III)-DTPA complexes (CCSV-DTPA) for determination of Cr(VI) and AAS was used for determination of Cr content. It has been revealed that the antagonistic action of alkali metal compounds and iron oxides plays a crucial role in shaping valence speciation of chromium. According to the proposed transformation path of oxidation of Cr(III) to Cr(VI), hard coal combustion in an SF boiler, an FBC boiler or a domestic boiler will generate \\{FAs\\} with a low Cr(VI) level. Replacing fuel with biomass should create favorable conditions for generating FA enriched with Cr(VI). Relatively high concentrations of Cr(VI) can also be expected in FA generated in the process of high-temperature combustion of coal in PCC boilers.

Ryszard ?wietlik; Marzena Trojanowska; Monika ?o?y?ska; Artur Molik

2014-01-01T23:59:59.000Z

467

Q-dependence of the spin fluctuations in the intermediate valence compound CePd3  

SciTech Connect (OSTI)

We report inelastic neutron scattering experiments on a single crystal of the intermediate valence compound CePd3. At 300 K the magnetic scattering is quasielastic, with half-width G = 23 meV, and is independent of momentum transfer Q. At low temperature, the Q-averaged magnetic spectrum is inelastic, exhibiting a broad peak centered near E-max = 55 meV. These results, together with the temperature dependence of the susceptibility, 4f occupation number, and specific heat, can be fit by the Kondo/Anderson impurity model. The low temperature scattering near Emax, however, shows significant variations with Q, reflecting the coherence of the 4f lattice. The intensity is maximal at (1/2, 1/2, 0), intermediate at (1/2, 0, 0) and (0, 0, 0), and weak at (1/2, 1/2, 1/2). We discuss this Q-dependence in terms of current ideas about coherence in heavy fermion systems.

Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Thompson, J. D.; Booth, C. H.; Christianson, A. D.; Riseborough, P. S.

2014-06-25T23:59:59.000Z

468

LA SPECTROSCOPIE DE PERTE D'ÉNERGIE DES ÉLECTRONS APPLIQUÉE AUX BATTERIES AU LITHIUM : EXPÉRIENCES ET SIMULATIONS AU SEUIL K DU LITHIUM.  

E-Print Network [OSTI]

??Ce travail combine études expérimentales et théoriques au seuil K du lithium dans le but de permettre une meilleure compréhension des propriétés des matériaux pour… (more)

Mauchamp, V.

2006-01-01T23:59:59.000Z

469

Close packing density and fracture strength of adsorbed polydisperse particle layers  

E-Print Network [OSTI]

The close packing density of log-normal and bimodal distributed, surface-adsorbed particles or discs in 2D is studied by numerical simulation. For small spread in particle size, the system orders in a polycrystalline structure of hexagonal domains. The domain size and the packing density both decrease as the spread in particle size is increased up to 10.5+/-0.5%. From this point onwards the system becomes amorphous, and the close packing density increases again with spread in particle size. We argue that the polycrystalline and amorphous regions are separated by a Kosterlitz-Thouless-type phase transition. In the amorphous region we find the close packing density to vary proportional to the logarithm of the friction factor, or cooling rate. We also studied the fracture behaviour of surface layers of sintered particles. Fracture strength increases with spread in particle size, but the brittleness of the layers shows a minimum at the polycrystalline-amorphous transition. We further show that mixing distributions of big and small particles generally leads to weaker and more brittle layers, even though the close packing density is higher than for either of the particle types. We point out applications to foam stability by the Pickering mechanism.

Robert D. Groot; Simeon D. Stoyanov

2012-01-26T23:59:59.000Z

470

TI-59 helps predict IPRs for gravel-packed gas wells  

SciTech Connect (OSTI)

The inflow performance relationship (IPR) is an important tool for reservoir and production engineers. It helps optimize completion, tubing, gas lift, and storm choke design. It facilitates accurate rate predictions that can be used to evaluate field development decisions. The IPR is the first step of the systems analysis that translates reservoir rock and fluid parameters into predictable flow rates. Use of gravel packing for sand control complicates the calculation that predicts a well's IPR curve, particularly in gas wells where high velocities in the formation and through gravel-filled perforation tunnels can cause turbulent flow. The program presented in this article calculates the pressure drop and the flowing bottomhole pressures at varying flow rates for gravel-packed gas wells. The program was written for a Texas Instruments TI-59 programmable calculator with a PC-100 printer. Program features include: Calculations for in-casing gravel packs, open-hole gravel packs, or ungravel packed wells. Program prompts for the required data variables. Easy change of data values to run new cases. Calculates pressures for an unlimited number of flow rates. Results show the total pressure drop and the relative magnitude of its components.

Capdevielle, W.C.

1983-12-01T23:59:59.000Z

471

Fluctuations, structure factor and polytetrahedra in random packings of sticky hard spheres  

E-Print Network [OSTI]

Sequentially-built random sphere-packings have been numerically studied in the packing fraction interval $0.329 designed in order to build about 300 aggregates, containing $10^6$ spheres each one, which allowed a careful study of the local fluctuations and an improved accuracy in the calculations of the pair distribution $P(r)$ and structure factors $S(Q)$ of the aggregates. Among various parameters (Voronoi tessellation, contact coordination number distribution,...), fluctuations were quantitatively evaluated by the direct evaluation of the fluctuations of the local sphere number density, which appears to follow a power law. The FWHM of the Voronoi cells volume shows a regular variation over the whole packing fraction range. Dirac peaks appear on the pair correlation function as the packing fraction of the aggregates decreases, indicating the growth of larger and larger polytetrahedra, which manifest in two ways on the structure factor, at low and large $Q$values. These low PF aggregates have a composite structure made of regular polytetrahedra embedded in a more disordered matrix. Incidentally, the irregularity index of the building tetrahedron appears as a better parameter than the packing fraction to describe various features of the aggregates structure.

Marc Bletry; Jean Bletry

2014-09-08T23:59:59.000Z

472

Ship-pack optimization in a two-echelon distribution system  

Science Journals Connector (OSTI)

In large distribution systems, distribution centers (DC) deliver some merchandize to their retail stores in size-specific packages, also called ship-packs. These ship-packs include cases (e.g., cartons containing 24 or 48 units), inners (packages of 6 or 8 units) or eaches (individual units). For each Stock Keeping Unit (SKU), a retailer can decide which of these ship-pack options to use when replenishing its retail stores. Working with a major US retailer, we have developed a cost model that balances DC handling costs, store handling costs and inventory-related costs at both the DC and the stores, and therefore can help to determine the optimum warehouse ship-pack for each SKU. We implement our model for a sample of 529 SKUs, and show that by changing ship-pack size for about 30 SKUs, the retailer can reduce its total cost by 0.3% - 0.4%. Interestingly, we find that most of the cost savings occurs at the DC level.

Naijun Wen; Stephen C. Graves; Z. Justin Ren

2012-01-01T23:59:59.000Z

473

Molybdenum nitride/nitrogen-doped graphene hybrid material for lithium storage in lithium ion batteries  

Science Journals Connector (OSTI)

Abstract Molybdenum nitride and nitrogen-doped graphene nanosheets (MoN/GNS) hybrid materials are synthesized by a simple hydrothermal method combined with a heat treatment at 800 °C under an ammonia atmosphere. It is found by scanning and transmission electron microscopy that MoN nanoparticles ranging from 20 to 40 nm in diameter are homogeneously anchored to GNS. The electrochemical performance of MoN/GNS as a possible anode material for Li-ion batteries is investigated. Galvanostatic charge/discharge experiments reveal that the hybrid materials exhibit an enhanced lithium storage capacity and excellent rate capacity as a result of its efficient electronic and ionic mixed conducting network. The electrochemical results demonstrate that the weight ratio of GNS and MoN had significant effect on the electrochemical performance.

Botao Zhang; Guanglei Cui; Kejun Zhang; Lixue Zhang; Pengxian Han; Shanmu Dong

2014-01-01T23:59:59.000Z

474

Location and valence state of strontium cations on the framework of a carbon dioxide selective porous silicoaluminophosphate  

SciTech Connect (OSTI)

A Sr{sup 2+}-SAPO-34 material that displays superior CO2 adsorption selectivity and capacity was characterized via XPS and UV-vis spectroscopy to elucidate the valence state of strontium cations and framework silicon environment. Most importantly, the location of the strontium has been estimated from a Rietveld refinement analysis of synchrotron diffraction data. The XPS analysis indicated that the apparent valence state of the strontium is less than 2, an indication of its interaction with the large anionic framework. Furthermore, UV-vis tests pointed to changes in the silicon environment, plausibly related to this valence state or framework faulting. For the refinement, the analysis found that strontium occupied two unique sites: a site Sr1 slightly displaced from six-membered rings and a site Sr2 positioned at the top or bottom of the eight-membered rings. The latter position favors the interaction of the alkaline earth metal with CO{sub 2}, probably resulting in an enhanced electric field-quadrupole moment interaction.

Zhang, Li; Rivera-Ramos, Milton E.; Hernández-Maldonado, Arturo J. (Puerto Rico) [Puerto Rico

2014-05-28T23:59:59.000Z

475

Development and Analysis of a Gravity-Simulated Particle-Packing Algorithm for Modeling Optimized Rocket Propellants  

E-Print Network [OSTI]

homogeneous distributions of spherical particles. Both the Radial Distribution Function (RDF) and the packing fraction were used to evaluate the validity of the invented algorithm....

Stockmyer, Mark

2007-12-13T23:59:59.000Z

476

Internal Heat Transfer Coefficient Determination in a Packed Bed From the Transient Response Due to Solid Phase Induction Heating  

E-Print Network [OSTI]

equations governing fluid flow and heat transfer in porousParticle-to-Fluid Heat and Mass Transfer in Packed Beds,”Systems,” Experimental Heat Transfer, Fluid Mechanics and

Geb, David; Zhou, Feng; Catton, Ivan

2012-01-01T23:59:59.000Z

477

Inferring planar disorder in close-packed structures via -machine spectral reconstruction theory: examples from simulated diffraction patterns  

Science Journals Connector (OSTI)

-Machine spectral reconstruction theory, a method for finding planar disorder in close-packed structures, is applied to four simulated diffraction patterns.

Varn, D.P.

2013-05-17T23:59:59.000Z

478

Pull-Chain "Polymer" Solves Puzzle of Complex Molecular Packing |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Discovering New Talents for Diamond Discovering New Talents for Diamond Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Pull-Chain "Polymer" Solves Puzzle of Complex Molecular Packing MARCH 4, 2010 Bookmark and Share Partial three-dimensional reconstruction, from x-ray tomographic data, of the packing of 2.1-mm ball chains, projected onto a plane. When tightly packed, the chains form nearly circular rigid loops, like the one in the lower right of the image. This behavior may form the basis of a model for better predictions of the rigidity of polymers. (Image courtesy of Ling-Nan Zou and Mark L. Rivers, The University of Chicago) Sometimes the simplest things hold the key to understanding complex

479

Packed bed thermal energy storage model – Generalized approach and experimental validation  

Science Journals Connector (OSTI)

Abstract Packed beds serve as thermal energy storages (TES) and heat exchangers (HEX) in different technological applications. In this paper, a general heterogeneous model of heat transfer in packed beds is developed. It is implemented by lumped element formulation in object-oriented modeling language Modelica and is successful validated with data sets taken from two different experiments reported in literature. The main advantages of the introduced model are the general, theory-based approach and the lumped element formulation in Modelica. The first point mentioned above should allow to simulate a packed bed TES/HEX without the necessity applying measured data for model calibration or to apply specific heat transfer correlations with restricted application. The second point establishes the possibility to integrate the TES/HEX model within plant models of larger scale without increasing the simulation time drastically.

Florian Opitz; Peter Treffinger

2014-01-01T23:59:59.000Z

480

California Geothermal Power Plant to Help Meet High Lithium Demand  

Broader source: Energy.gov [DOE]

Ever wonder how we get the materials for the advanced batteries that power our cell phones, laptops, and even some electric vehicles? The U.S. Department of Energy's Geothermal Technologies Program (GTP) is working with California's Simbol Materials to develop technologies that extract battery materials like lithium, manganese, and zinc from geothermal brines produced during the geothermal production process.

Note: This page contains sample records for the topic "valence lithium pack" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Non-aqueous electrolyte for lithium-ion battery  

DOE Patents [OSTI]

The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.

Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

2014-04-15T23:59:59.000Z

482

Performance Projections For The Lithium Tokamak Experiment (LTX)  

SciTech Connect (OSTI)

Use of a large-area liquid lithium limiter in the CDX-U tokamak produced the largest relative increase (an enhancement factor of 5-10) in Ohmic tokamak confinement ever observed. The confinement results from CDX-U do not agree with existing scaling laws, and cannot easily be projected to the new lithium tokamak experiment (LTX). Numerical simulations of CDX-U low recycling discharges have now been performed with the ASTRA-ESC code with a special reference transport model suitable for a diffusion-based confinement regime, incorporating boundary conditions for nonrecycling walls, with fuelling via edge gas puffing. This model has been successful at reproducing the experimental values of the energy confinement (4-6 ms), loop voltage (<0.5 V), and density for a typical CDX-U lithium discharge. The same transport model has also been used to project the performance of the LTX, in Ohmic operation, or with modest neutral beam injection (NBI). NBI in LTX, with a low recycling wall of liquid lithium, is predicted to result in core electron and ion temperatures of 1-2 keV, and energy confinement times in excess of 50 ms. Finally, the unique design features of LTX are summarized.

Majeski, R.; Berzak, L.; Gray, T.; Kaita, R.; Kozub, T.; Levinton, F.; D.P. Lundberg,,; Manickam, J.; Pereverzev, G. V.; Snieckus, K.; Soukhanovskii, V.; Spaleta, J.; Stotler, D.; Strickler, T.; Timberlake, J.; Yoo, J.; Zakharov, L.

2009-06-17T23:59:59.000Z

483

Novel carbonaceous materials used as anodes in lithium ion cells  

SciTech Connect (OSTI)

The objective of this work is to synthesize disordered carbons used as anodes in lithium ion batteries, where the porosity and surface area are controlled. Both parameters are critical since the irreversible capacity obtained in the first cycle seems to be associated with the surface area (an exfoliation mechanism occurs in which the exposed surface area continues to increase).

Sandi, G.; Winans, R.E.; Carrado, K.A.

1997-09-01T23:59:59.000Z

484

Phosphorous Computer Modeling of Crystalline Electrolytes: Lithium Thiophosphates and Phosphates  

E-Print Network [OSTI]

-search algorithm · Minimum-energy migration paths were determined via the construction of a weighted graph Results: Abstract Recently, lithium thiophosphate materials suitable for usage as solid electrolytes with PAW functionals generated using atompaw, and used in pwscf and abinit) · Formation energies

Holzwarth, Natalie

485

Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries  

E-Print Network [OSTI]

lithium ion batteries. Materials Science & Engineering R-Ion Batteries by Jianxin Zhu Doctor of Philosophy, Graduate Program in Materials Science and EngineeringIon Batteries A Dissertation submitted in partial satisfaction of the requirements for the degree of Doctor of Philosophy in Materials Science and Engineering

Zhu, Jianxin

2014-01-01T23:59:59.000Z

486

Synthesis and electrochemical characterisation of electrospun lithium titanate ultrafine fibres  

Science Journals Connector (OSTI)

Lithium acetate dihydrate (>99.0 %, Sigma-Aldrich ... %, Sigma-Aldrich) were used for the synthesis of Li4Ti5O12. PVP (Aldrich, M w = 3.6 × 105) was used as the base polymer for the electrospinn...

C. P. Sandhya; Bibin John; C. Gouri

2013-09-01T23:59:59.000Z

487

Issue and challenges facing rechargeable thin film lithium batteries  

Science Journals Connector (OSTI)

New materials hold the key to fundamental advances in energy conversion and storage, both of which are vital in order to meet the challenge of global warming and the finite nature of fossil fuels. Nanomaterials in particular offer unique properties or combinations of properties as electrodes and electrolytes in a range of energy devices. Technological improvements in rechargeable solid-state batteries are being driven by an ever-increasing demand for portable electronic devices. Lithium batteries are the systems of choice, offering high energy density, flexible, lightweight design and longer lifespan than comparable battery technologies. We present a brief historical review of the development of lithium-based thin film rechargeable batteries highlight ongoing research strategies and discuss the challenges that remain regarding the discovery of nanomaterials as electrolytes and electrodes for lithium batteries also this article describes the possible evolution of lithium technology and evaluates the expected improvements, arising from new materials to cell technology. New active materials under investigation and electrode process improvements may allow an ultimate final energy density of more than 500 Wh/L and 200 Wh/kg, in the next 5–6 years, while maintaining sufficient power densities. A new rechargeable battery technology cannot be foreseen today that surpasses this. This report will provide key performance results for thin film batteries and highlight recent advances in their development.

Arun Patil; Vaishali Patil; Dong Wook Shin; Ji-Won Choi; Dong-Soo Paik; Seok-Jin Yoon

2008-01-01T23:59:59.000Z

488

High power density self-cooled lithium-vanadium blanket.  

SciTech Connect (OSTI)

A self-cooled lithium-vanadium blanket concept capable of operating with 2 MW/m{sup 2} surface heat flux and 10 MW/m{sup 2} neutron wall loading has been developed. The blanket has liquid lithium as the tritium breeder and the coolant to alleviate issues of coolant breeder compatibility and reactivity. Vanadium alloy (V-4Cr-4Ti) is used as the structural material because it can accommodate high heat loads. Also, it has good mechanical properties at high temperatures, high neutron fluence capability, low degradation under neutron irradiation, good compatibility with the blanket materials, low decay heat, low waste disposal rating, and adequate strength to accommodate the electromagnetic loads during plasma disruption events. Self-healing electrical insulator (CaO) is utilized to reduce the MHD pressure drop. A poloidal coolant flow with high velocity at the first wall is used to reduce the peak temperature of the vanadium structure and to accommodate high surface heat flux. The blanket has a simple blanket configuration and low coolant pressure to reduce the fabrication cost, to improve the blanket reliability, and to increase confidence in the blanket performance. Spectral shifter, moderator, and reflector are utilized to improve the blanket shielding capability and energy multiplication, and to reduce the radial blanket thickness. Natural lithium is used to avoid extra cost related to the lithium enrichment process.

Gohar, Y.; Majumdar, S.; Smith, D.

1999-07-01T23:59:59.000Z

489

Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Title Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Publication Type Journal Article Year of Publication 2012 Authors Ridgway, Paul L., Honghe Zheng, A. F. Bello, Xiangyun Song, Shidi Xun, Jin Chong, and Vincent S. Battaglia Journal Journal of The Electrochemical Society Volume 159 Issue 5 Pagination A520 Date Published 2012 ISSN 00134651 Abstract Battery grade graphite products from major suppliers to the battery industry were evaluated in 2325 coin cells with lithium counter electrodes. First and ongoing cycle efficiency, total and reversible capacity, cycle life and discharge rate performance were measured to compare these anode materials. We then ranked the graphites using a formula which incorporates these performance measures to estimate the cost of the overall system, relative to the cost of a system using MCMB. This analysis indicates that replacing MCMB with CCP-G8 (Conoco Phillips) would add little to no cost, whereas each of the other graphites would lead to a more costly system. Therefore we chose CCP-G8 as the new baseline graphite for the BATT program.

490

High temperature packing test program. First quarterly technical progress report, October 1-December 26, 1981  

SciTech Connect (OSTI)

The program was undertaken to improve the technical understanding of the performance of plunger packings in coal liquefaction pilot plant feed pumps. During the first quarter of FY 1982, visits were made to the H-Coal, EDS and SRC-I pilot plants, where technical discussions were held with maintenance and engineering personnel, and the maintenance records and work orders for the plunger pumps were reviewed. Technical discussions were held with engineering personnel at the manufacturing facilities of three plunger pump manufacturers' companies. Contracts and technical discussions with packing vendors were initiated. Design of the laboratory tests was started.

Not Available

1982-02-12T23:59:59.000Z

491

Sand pack residual oil saturations as affected by extraction with various solvents  

E-Print Network [OSTI]

invalidate the conclusions of Jennings, as his natural cores were obtained using oQ-base muds, Data presented by Shneerson an4 VasOieva sho? that reservoir 7 mineral surfaces made preferentially oil-wst with crude oils could not be altered in wettability..., and air pressure was main tained on the supply reservoirs for a minimum time. Tbe fluids used to saturate the sand packs were tap water, kerosene, Sradford crude and topped East Texas crude oil, Organic solvents used to extract the sand packs were...

Murray, Clarence

1958-01-01T23:59:59.000Z

492

A Better Anode Design to Improve Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries Print A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

493

A Better Anode Design to Improve Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries Print A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

494

A Better Anode Design to Improve Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Better Anode Design to Improve Lithium-Ion Batteries Print Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

495

Modeling of Spherical Torus Plasmas for Liquid Lithium Wall Experiments  

SciTech Connect (OSTI)

Liquid metal walls have the potential to solve first-wall problems for fusion reactors, such as heat load and erosion of dry walls, neutron damage and activation, and tritium inventory and breeding. In the near term, such walls can serve as the basis for schemes to stabilize magnetohydrodynamic (MHD) modes. Furthermore, the low recycling characteristics of lithium walls can be used for particle control. Liquid lithium experiments have already begun in the Current Drive eXperiment-Upgrade (CDX-U). Plasmas limited with a toroidally localized limiter have been investigated, and experiments with a fully toroidal lithium limiter are in progress. A liquid surface module (LSM) has been proposed for the National Spherical Torus Experiment (NSTX). In this larger ST, plasma currents are in excess of 1 MA and a typical discharge radius is about 68 cm. The primary motivation for the LSM is particle control, and options for mounting it on the horizontal midplane or in the divertor region are under consideration. A key consideration is the magnitude of the eddy currents at the location of a liquid lithium surface. During plasma start up and disruptions, the force due to such currents and the magnetic field can force a conducting liquid off of the surface behind it. The Tokamak Simulation Code (TSC) has been used to estimate the magnitude of this effect. This program is a two dimensional, time dependent, free boundary simulation code that solves the MHD equations for an axisymmetric toroidal plasma. From calculations that match actual ST equilibria, the eddy current densities can be determined at the locations of the liquid lithium. Initial results have shown that the effects could be significant, and ways of explicitly treating toroidally local structures are under investigation.

R. Kaita; S. Jardin; B. Jones; C. Kessel; R. Majeski; J. Spaleta; R. Woolley; L. Zakharo; B. Nelson; M. Ulrickson

2002-01-29T23:59:59.000Z

496

Accretion-induced Lithium Line Enhancements in Classical T  

Science Journals Connector (OSTI)

It is widely accepted that much of the stochastic variability of T Tauri stars is due to accretion by a circumstellar disk. The emission-line spectrum as well as the excess continuum emission are common probes of this process. In this communication, we present additional probes of the circumstellar environment in the form of resonance lines of low ionization potential elements. Using a set of 14 high-resolution echelle observations of the classical T Tauri star (CTTS) RW Aur, taken between 1986 and 1996, we carefully measure the continuum veiling at each epoch by comparing more than 500 absorption lines with those of an appropriate template. This allows us to accurately subtract out the continuum emission and to recover the underlying photospheric spectrum. In doing so, we find that selected photospheric lines are enhanced by the accretion process, namely, the resonance lines of Li I and K I. A resonance line of Ti I and a low excitation potential line of Ca I also show weak enhancements. Simple slab models and computed line bisectors lead us to propose that these line enhancements are markers of cool gas at the beginning of the accretion flow which provides an additional source of line opacity. These results suggest that published values of surface lithium abundances of classical T Tauri stars are likely to be overestimated. This would account for the various reports of surface lithium abundances in excess of meteoritic values among the extreme CTTSs. Computing LTE lithium abundances of RW Aur in a low and then high accretion state yields abundances which vary by 1 order of magnitude. The low accretion state lithium abundance is consistent with theoretical predictions for a star of this age and mass, while the high accretion state spectrum yields a supermeteoritic lithium abundance.

N. M. Stout-Batalha; C. C. Batalha; G. S. Basri

2000-01-01T23:59:59.000Z

497

Luminescence from Edge Fracture in Shocked Lithium Fluoride Crystals  

SciTech Connect (OSTI)

Light emitted from a [100] lithium fluoride crystal was characterized under shock wave compression to 28GPa followed by complete stress release at the edges. The light was examined using time-gated optical spectrometry and imaging, time-resolved optical emission measurements, and hydrodynamic modeling. The shock arrival at the circumference of the crystal was delayed relative to the center so that the two regions could be studied at different times. The majority of the light emission originated when the shock waves released at the circumference of the crystal. Unlike previously reported results for shocked lithium fluoride, we found that the light spectrum is not strictly broad band, but has spectral lines associated with atomic lithium in addition to a broad band background. Also, the emission spectrum depends strongly on the gas surrounding the sample. Based on our observations, the line emission appears to be related to fracture of the lithium fluoride crystal from the shock wave releasing at the edges. Experimenters frequently utilize lithium fluoride crystals as transparent windows for observing shock compressed samples. Because of the experimental geometries used, the shock wave in such cases often reaches the circumference of the window at nearly the same moment as when it reaches the center of the sample-window interface. Light generated at the circumference could contaminate the measurement at the interface when this light scatters into the observed region. This background light may be reduced or avoided using experimental geometries which delay the arrival of the shock wave at the edges of the crystal.

Turley, W. D. [NSTec; Stevens, G. D. [NSTec; Capelle, G. A. [NSTec; Grover, M. [NSTec; Holtkamp, D. B. [LANL; LaLone, B. M. [NSTec; Veeser, L. R. [NSTec, LANL

2013-04-01T23:59:59.000Z

498

Upward-facing Lithium Flash Evaporator for NSTX-U  

SciTech Connect (OSTI)

NSTX plasma performance has been significantly enhanced by lithium conditioning [1]. To date, the lower divertor and passive plates have been conditioned by downward facing lithium evaporators (LITER) as appropriate for lower null plasmas. The higher power operation expected from NSTX-U requires double null plasma operation in order to distribute the heat flux between the upper and lower divertors making it desirable to coat the upper divertor region with Li as well. An upward aiming LITER (U-LITER) is presently under development and will be inserted into NSTX-U using a horizontal probe drive located in a 6" upper midplane port. In the retracted position the evaporator will be loaded with up to 300 mg of Li granules utilizing one of the calibrated NSTX Li powder droppers[2]. The evaporator will then be inserted into the vessel in a location within the shadow of the RF limiters and will remain in the vessel during the discharge. About 10 seconds before a discharge, it will be rapidly heated and the lithium completely evaporated onto the upper divertor, thus avoiding the complication of a shutter that prevents evaporation during the shot when the diagnostic shutters are open. The minimal time interval between the evaporation and the start of the discharge will avoid the passivation of the lithium by residual gases and enable the study of the conditioning effects of un-passivated Li surfaces [3]. Two methods are being investigated to accomplish the rapid (few second) heating of the lithium. A resistive method relies on passing a large current through a Li filled crucible. A second method requires using a 3 kW e-beam gun to heat the Li. In this paper the evaporator systems will be described and the pros and cons of each heating method will be discussed.

Roquemore, A. L.

2013-07-09T23:59:59.000Z

499

(Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: Chile was the leading lithium chemical producer in the world; Argentina, China,  

E-Print Network [OSTI]

, vehicles with an internal combustion engine and a battery-powered electric motor. Most commercially that was prone to dangerous overheating. Interest continued in lithium batteries for hybrid electric vehicles lithium batteries were being used increasingly in portable electronic devices and electrical tools

500

(Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: Chile was the leading lithium chemical producer in the world; Argentina, China, and  

E-Print Network [OSTI]

companies were pursuing the development of lithium batteries for hybrid electric vehicles--vehicles with an internal combustion engine and a battery-powered electric motor. Most commercially available hybrid rechargeable lithium batteries were being used increasingly in portable electronic devices and electrical tools