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1

Contaminants in Vadose Zone Environments | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contaminants in Vadose Zone Environments Contaminants in Vadose Zone Environments Contaminants in Vadose Zone Environments The Deep Vadose Zone - Applied Field Research Initiative has partnered with the Vadose Zone Journal to bring together a special section of the recent issue (November 2012). The section was prepared in association with the Deep Vadose Zone - Applied Field Research Initiative-led symposium at the annual American Chemical Society meeting on "Understanding Behavior and Fate of Contaminants in Vadose Zone Environments." The section consists of 12 papers which present novel approaches to characterize, monitor, remediate, and predict the transport and fate of contaminants in vadose zone environments, many of which highlight recent work at the Hanford site. Contaminants in Vadose Zone Environments

2

Contaminants in Vadose Zone Environments | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contaminants in Vadose Zone Environments Contaminants in Vadose Zone Environments Contaminants in Vadose Zone Environments April 11, 2013 - 12:00pm Addthis The Deep Vadose Zone - Applied Field Research Initiative (DVZ-AFRI) partnered with the Vadose Zone Journal to create a special section of the journal's November 2012 issue. DVZ-AFRI conducted a symposium at the annual American Chemical Society meeting on "Understanding Behavior and Fate of Contaminants in Vadose Zone Environments." They produced 12 papers that present novel approaches to characterize, monitor, remediate and predict the transport and fate of contaminants in vadose zone environments, many of which highlight recent work at the Hanford site. The publications can be accessed here. For more information, contact Skip Chamberlain with the EM's Office of Soil

3

STRATEGIES FOR IMMOBILIZATION OF DEEP VADOSE ZONE CONTAMINANTS AT THE HANFORD CENTRAL PLATEAU  

Science Conference Proceedings (OSTI)

Deep vadose zone contamination poses some of the most difficult remediation challenges for the protection of groundwater at the Hanford Site in Richland, Washington. This paper describes processes and technologies being developed to use in the ongoing effort to remediate the contamination in the deep vadose zone at the Hanford Site.

CHRONISTER GB

2011-01-14T23:59:59.000Z

4

Field evidence for strong chemical separation of contaminants in the Hanford Vadose Zone  

E-Print Network (OSTI)

Chemical Transport in the Hanford vadose zone Conrad et al.Chemical Transport in the Hanford vadose zone Conrad et al.Vadose Zone Pore Fluids at Hanford, Washington: Vadose Zone

Conrad, Mark E.; DePaolo, Donald J.; Maher, Katharine; Gee, Glendon W.; Ward, Anderson L.

2007-01-01T23:59:59.000Z

5

Remedy Evaluation Framework for Inorganic, Non-Volatile Contaminants in the Vadose Zone  

Science Conference Proceedings (OSTI)

Contaminants in the vadose zone may act as a potential long-term source of groundwater contamination and need to be considered in remedy evaluations. In many cases, remediation decisions for the vadose zone will need to be made all or in part based on projected impacts to groundwater. Because there are significant natural attenuation processes inherent in vadose zone contaminant transport, remediation in the vadose zone to protect groundwater is functionally a combination of natural attenuation and use of other remediation techniques, as needed, to mitigate contaminant flux to groundwater. Attenuation processes include both hydrobiogeochemical processes that serve to retain contaminants within porous media and physical processes that mitigate the rate of water flux. In particular, the physical processes controlling fluid flow in the vadose zone are quite different and generally have a more significant attenuation impact on contaminant transport relative to those within the groundwater system. A remedy evaluation framework is presented herein that uses an adaptation of the established EPA Monitored Natural Attenuation (MNA) evaluation approach and a conceptual model based approach focused on identifying and quantifying features and processes that control contaminant flux through the vadose zone. A key concept for this framework is to recognize that MNA will comprise some portion of all remedies in the vadose zone. Thus, structuring evaluation of vadose zone waste sites to use an MNA-based approach provides information necessary to either select MNA as the remedy, if appropriate, or to quantify how much additional attenuation would need to be induced by a remedial action (e.g., technologies considered in a feasibility study) to augment the natural attenuation processes and meet groundwater protection goals.

Truex, Michael J.; Carroll, Kenneth C.

2013-05-01T23:59:59.000Z

6

New Approach to Assess Volatile Contamination in Vadose Zone Provides Path  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Approach to Assess Volatile Contamination in Vadose Zone Approach to Assess Volatile Contamination in Vadose Zone Provides Path Forward for Site Closure New Approach to Assess Volatile Contamination in Vadose Zone Provides Path Forward for Site Closure April 24, 2012 - 12:00pm Addthis Conceptual site model for evaluating soil vapor extraction system performance to determine if the system should be optimized, terminated, or transitioned to another approach. Conceptual site model for evaluating soil vapor extraction system performance to determine if the system should be optimized, terminated, or transitioned to another approach. RICHLAND, Wash. and LOS ALAMOS, N.M. - Through the Deep Vadose Zone-Applied Field Research Initiative (DVZ-AFRI), scientists and engineers from Pacific Northwest National Laboratory, CH2M HILL Plateau Remediation

7

TECHNICAL BASIS FOR EVALUATING SURFACE BARRIERS TO PROTECT GROUNDWATER FROM DEEP VADOSE ZONE CONTAMINATION  

Science Conference Proceedings (OSTI)

The U.S. DOE and its predecessors released nearly 2 trillion liters (450 billion gallons) of contaminated liquid into the vadose zone at the Hanford Site. Some of the contaminants currently reside in the deeper parts of the vadose zone where they are much less accessible to characterization, monitoring, and typical remediation activities. The DOE Richland Operations Office (DOE-RL) prepared a treatability test plan in 2008 to examine remediation options for addressing contaminants in the deep vadose zone; one of the technologies identified was surface barriers (also known as engineered barriers, covers, and caps). In the typical configuration, the contaminants are located relatively close to the surface, generally within 15 m, and thus they are close to the base of the surface barrier. The proximity of the surface barrier under these conditions yielded few concerns about the effectiveness of the barrier at depth, particularly for cases in which the contaminants were in a lined facility. At Hanford, however, some unlined sites have contaminants located well below depths of 15 m. The issue raised about these sites is the degree of effectiveness of a surface barrier in isolating contaminants in the deep vadose zone. Previous studies by Hanford Site and PNNL researchers suggest that surface barriers have the potential to provide a significant degree of isolation of deep vadose zone contaminants. The studies show that the actual degree of isolation is site-specific and depends on many factors, including recharge rates, barrier size, depth of contaminants, geohydrologic properties ofthe sediments, and the geochemical interactions between the contaminants and the sediments. After the DOE-RL treatability test plan was published, Pacific Northwest National Laboratory was contracted to review the information available to support surface barrier evaluation for the deep vadose zone, identify gaps in the information and outcomes necessary to fill the data gaps, and outline tasks to achieve those outcomes. Full understanding of contaminant behavior in the deep vadose zone is constrained by four key data gaps: limited access; limited data; limited time; and the lack of an accepted predictive capability for determining whether surface barriers can effectively isolate deep vadose zone contaminants. Activities designed to fill these data gaps need to have these outcomes: (1) common evaluation methodology that provides a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination; (2) deep vadose zone data that characterize the lithology, the spatial distribution of moisture and contaminants, the physical, chemical, and biological process that affect the mobility of each contaminant, and the impacts to the contaminants following placement of a surface barrier; (3) subsurface monitoring to provide subsurface characterization of initial conditions and changes that occur during and following remediation activities; and (4) field observations that span years to decades to validate the evaluation methodology. A set of six proposed tasks was identified to provide information needed to address the above outcomes. The proposed tasks are: (1) Evaluation Methodology - Develop common evaluation methodology that will provide a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination. (2) Case Studies - Conduct case studies to demonstrate the applicability ofthe common evaluation methodology and provide templates for subsequent use elsewhere. Three sites expected to have conditions that would yield valuable information and experience pertinent to deep vadose zone contamination were chosen to cover a range of conditions. The sites are BC Cribs and Trenches, U Plant Cribs, and the T Farm Interim Cover. (3) Subsurface Monitoring Technologies - Evaluate minimally invasive geophysical approaches for delineating subsurface plumes and monitoring their migration in the deep

FAYER JM; FREEDMAN VL; WARD AL; CHRONISTER GB

2010-02-24T23:59:59.000Z

8

TECHNICAL BASIS FOR EVALUATING SURFACE BARRIERS TO PROTECT GROUNDWATER FROM DEEP VADOSE ZONE CONTAMINATION  

SciTech Connect

The U.S. DOE and its predecessors released nearly 2 trillion liters (450 billion gallons) of contaminated liquid into the vadose zone at the Hanford Site. Some of the contaminants currently reside in the deeper parts of the vadose zone where they are much less accessible to characterization, monitoring, and typical remediation activities. The DOE Richland Operations Office (DOE-RL) prepared a treatability test plan in 2008 to examine remediation options for addressing contaminants in the deep vadose zone; one of the technologies identified was surface barriers (also known as engineered barriers, covers, and caps). In the typical configuration, the contaminants are located relatively close to the surface, generally within 15 m, and thus they are close to the base of the surface barrier. The proximity of the surface barrier under these conditions yielded few concerns about the effectiveness of the barrier at depth, particularly for cases in which the contaminants were in a lined facility. At Hanford, however, some unlined sites have contaminants located well below depths of 15 m. The issue raised about these sites is the degree of effectiveness of a surface barrier in isolating contaminants in the deep vadose zone. Previous studies by Hanford Site and PNNL researchers suggest that surface barriers have the potential to provide a significant degree of isolation of deep vadose zone contaminants. The studies show that the actual degree of isolation is site-specific and depends on many factors, including recharge rates, barrier size, depth of contaminants, geohydrologic properties ofthe sediments, and the geochemical interactions between the contaminants and the sediments. After the DOE-RL treatability test plan was published, Pacific Northwest National Laboratory was contracted to review the information available to support surface barrier evaluation for the deep vadose zone, identify gaps in the information and outcomes necessary to fill the data gaps, and outline tasks to achieve those outcomes. Full understanding of contaminant behavior in the deep vadose zone is constrained by four key data gaps: limited access; limited data; limited time; and the lack of an accepted predictive capability for determining whether surface barriers can effectively isolate deep vadose zone contaminants. Activities designed to fill these data gaps need to have these outcomes: (1) common evaluation methodology that provides a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination; (2) deep vadose zone data that characterize the lithology, the spatial distribution of moisture and contaminants, the physical, chemical, and biological process that affect the mobility of each contaminant, and the impacts to the contaminants following placement of a surface barrier; (3) subsurface monitoring to provide subsurface characterization of initial conditions and changes that occur during and following remediation activities; and (4) field observations that span years to decades to validate the evaluation methodology. A set of six proposed tasks was identified to provide information needed to address the above outcomes. The proposed tasks are: (1) Evaluation Methodology - Develop common evaluation methodology that will provide a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination. (2) Case Studies - Conduct case studies to demonstrate the applicability ofthe common evaluation methodology and provide templates for subsequent use elsewhere. Three sites expected to have conditions that would yield valuable information and experience pertinent to deep vadose zone contamination were chosen to cover a range of conditions. The sites are BC Cribs and Trenches, U Plant Cribs, and the T Farm Interim Cover. (3) Subsurface Monitoring Technologies - Evaluate minimally invasive geophysical approaches for delineating subsurface plumes and monitoring their migration in the deep

FAYER JM; FREEDMAN VL; WARD AL; CHRONISTER GB

2010-02-24T23:59:59.000Z

9

Field-Scale Assessment of Desiccation Implementation for Deep Vadose Zone Contaminants  

Science Conference Proceedings (OSTI)

Desiccation of the vadose zone has the potential to reduce the flux of contaminants to underlying groundwater by removing moisture and decreasing the aqueous-phase permeability of the desiccated zone. However, data to evaluate implementation of desiccation are needed to enable consideration of desiccation as a potential remedy. Implementation of desiccation was field tested by injecting dry nitrogen gas to a target treatment zone and monitoring the spatial and temporal progress of the drying process. Aqueous waste discharges to disposal cribs approximately 50 years ago distributed water and contaminants, including primarily technetium-99 and nitrate, within the 100-m deep vadose zone at the test site. A field test location was selected adjacent to one of the former disposal cribs. The test was conducted in a contaminated portion of the vadose zone dominated by fine sands with lenses of silt material. Desiccation reduced volumetric moisture content to as low as 0.01. The lateral and vertical distribution of drying from the injection well was influenced by the subsurface heterogeneity. However, over time, desiccation occurred in the initially wetter, lower permeability lenses.

Truex, Michael J.; Oostrom, Martinus; Strickland, Christopher E.; Chronister, Glen B.; Benecke, Mark W.; Johnson, Christian D.

2012-11-01T23:59:59.000Z

10

Deep Vadose Zone  

Energy.gov (U.S. Department of Energy (DOE))

The Mission of the Deep Vadose Zone Applied Field Research Initiative is to protect water resources across the DOE complex over the long-term by developing effective solutions to solve DOE’s most...

11

Laboratory investigation of explosives degradation in vadose zone soil using carbon source additions.  

E-Print Network (OSTI)

??Explosives contamination in vadose zone soil presents difficulties in remediation. Because vadose zone contamination can extend deep into the subsurface and underneath existing buildings and… (more)

Radtke, Corey William

2005-01-01T23:59:59.000Z

12

Bioremediation of explosives in vadose zone soil using vapor phase carbon source additions.  

E-Print Network (OSTI)

??Explosives contamination in vadose zone soil presents difficulties in remediation. Because vadose zone contamination can extend deep into the subsurface and underneath existing buildings and… (more)

Radtke, Corey William

2005-01-01T23:59:59.000Z

13

Geochemical Characterization of Chromate Contamination in the 100 Area Vadose Zone at the Hanford Site  

Science Conference Proceedings (OSTI)

The major objectives of the proposed study were to: 1.) determine the leaching characteristics of hexavalent chromium [Cr(VI)] from contaminated sediments collected from 100 Area spill sites; 2.) elucidate possible Cr(VI) mineral and/or chemical associations that may be responsible for Cr(VI) retention in the Hanford Site 100 Areas through the use of i.) macroscopic leaching studies and ii.) microscale characterization of contaminated sediments; and 3.) provide information to construct a conceptual model of Cr(VI) geochemistry in the Hanford 100 Area vadose zone. In addressing these objectives, additional benefits accrued were: (1) a fuller understanding of Cr(VI) entrained in the vadose zone that will that can be utilized in modeling potential Cr(VI) source terms, and (2) accelerating the Columbia River 100 Area corridor cleanup by providing valuable information to develop remedial action based on a fundamental understanding of Cr(VI) vadose zone geochemistry. A series of macroscopic column experiments were conducted with contaminated and uncontaminated sediments to study Cr(VI) desorption patterns in aged and freshly contaminated sediments, evaluate the transport characteristics of dichromate liquid retrieved from old pipelines of the 100 Area; and estimate the effect of strongly reducing liquid on the reduction and transport of Cr(VI). Column experiments used the with the column studies. Cr(VI) is found as ubiquitous coatings on sediment grain surfaces. Small, higher concentration, chromium sites are associated with secondary clay mineral inclusions, with occasional barium chromate minerals, and reduced to Cr(III) in association with iron oxides that are most likely magnetite primary minerals. Within the restricted access domains of sediment matrix, ferrous iron could also diffuse from in situ, high-surface-area minerals to cause the reductive immobilization of chromate. This process may be favored at microscale geochemical zones where ferrous iron could be supplied. Once nucleated, micrometer-scale precipitates are favored as growing locales for further accumulation, causing the formation of discrete zones of Cr(III).

Dresel, P. Evan; Qafoku, Nikolla; McKinley, James P.; Fruchter, Jonathan S.; Ainsworth, Calvin C.; Liu, Chongxuan; Ilton, Eugene S.; Phillips, J. L.

2008-07-16T23:59:59.000Z

14

Geochemical Characterization of Chromate Contamination in the 100 Area Vadose Zone at the Hanford Site  

SciTech Connect

The major objectives of the proposed study were to: 1.) determine the leaching characteristics of hexavalent chromium [Cr(VI)] from contaminated sediments collected from 100 Area spill sites; 2.) elucidate possible Cr(VI) mineral and/or chemical associations that may be responsible for Cr(VI) retention in the Hanford Site 100 Areas through the use of i.) macroscopic leaching studies and ii.) microscale characterization of contaminated sediments; and 3.) provide information to construct a conceptual model of Cr(VI) geochemistry in the Hanford 100 Area vadose zone. In addressing these objectives, additional benefits accrued were: (1) a fuller understanding of Cr(VI) entrained in the vadose zone that will that can be utilized in modeling potential Cr(VI) source terms, and (2) accelerating the Columbia River 100 Area corridor cleanup by providing valuable information to develop remedial action based on a fundamental understanding of Cr(VI) vadose zone geochemistry. A series of macroscopic column experiments were conducted with contaminated and uncontaminated sediments to study Cr(VI) desorption patterns in aged and freshly contaminated sediments, evaluate the transport characteristics of dichromate liquid retrieved from old pipelines of the 100 Area; and estimate the effect of strongly reducing liquid on the reduction and transport of Cr(VI). Column experiments used the < 2 mm fraction of the sediment samples and simulated Hanford groundwater solution. Periodic stop-flow events were applied to evaluate the change in elemental concentration during time periods of no flow and greater fluid residence time. The results were fit using a two-site, one dimensional reactive transport model. Sediments were characterized for the spatial and mineralogical associations of the contamination using an array of microscale techniques such as XRD, SEM, EDS, XPS, XMP, and XANES. The following are important conclusions and implications. Results from column experiments indicated that most of contaminant Cr travels fast through the sediments and appears as Cr(VI) in the effluents. The significance of this for groundwater concentrations would, however, depend on the mass flux of recharge to the water table. adsorption of Cr(VI) to sediments from spiked Cr(VI) solution is low; calculated retardation coefficients are close to one. Calcium polysulfide solutions readily reduced Cr(VI) to Cr(III) in column experiments. However a significant amount of the Cr(VI) was mobilized ahead of the polysulfide solution front. This has significant implications for in-situ reductive remediation techniques. The experiments suggest that it would be difficult to design a remedial measure using infiltration of liquid phase reductants without increasing transport of Cr(VI) toward the water table. The microscopic characterization results are consistent with the column studies. Cr(VI) is found as ubiquitous coatings on sediment grain surfaces. Small, higher concentration, chromium sites are associated with secondary clay mineral inclusions, with occasional barium chromate minerals, and reduced to Cr(III) in association with iron oxides that are most likely magnetite primary minerals. Within the restricted access domains of sediment matrix, ferrous iron could also diffuse from in situ, high-surface-area minerals to cause the reductive immobilization of chromate. This process may be favored at microscale geochemical zones where ferrous iron could be supplied. Once nucleated, micrometer-scale precipitates are favored as growing locales for further accumulation, causing the formation of discrete zones of Cr(III).

Dresel, P. Evan; Qafoku, Nikolla; McKinley, James P.; Fruchter, Jonathan S.; Ainsworth, Calvin C.; Liu, Chongxuan; Ilton, Eugene S.; Phillips, J. L.

2008-07-16T23:59:59.000Z

15

Applied Field Research Initiative Deep Vadose Zone  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Applied Field Research Initiative Applied Field Research Initiative Deep Vadose Zone Located on the Hanford Site in Richland, Washington, the Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources by addressing the challenge of preventing contamination in the deep vadose zone from reaching groundwater. Led by the Pacific Northwest National Laboratory, the Initiative is a collaborative effort that leverages Department of Energy (DOE) investments in basic science and applied research and the work of site contractors to address the complex deep vadose zone contamination challenges. Challenge Many vadose zone environments within the DOE complex consist of complex stratified layers of unconsolidated and water-unsaturated sediments that are, in many places, con-

16

Flow dynamics and potential for Biodegradation of Organic Contaminants in Fractured Rock Vadose Zones  

SciTech Connect

We present an experimental approach for investigating the potential for bioremediation of volatile organic chemicals (VOCs) in fractured-rock vadose zones. This approach is based on the coupling of fluid flow dynamics and biotransformation processes. Fluid flow and distribution within fracture networks may be a significant factor in the ability of microorganisms to degrade VOCs, as they affect the availability of substrate, moisture and nutrients. Biological activity can change liquid surface tension and generate biofilms that may change the nettability of solid surfaces, locally alter fracture permeability and redirect infiltrating liquids. Our approach has four components: (1) establishing a conceptual model for fluid and contaminant distribution in the geologic matrix of interest; (2) physical and numerical experiments of liquid seepage in the fracture plane; (3) non-destructive monitoring of biotransformations on rock surfaces at the micron-scale; and, (4) integration of flow and biological activity in natural rock ''geocosms''. Geocosms are core-scale flow cells that incorporate some aspects of natural conditions, such as liquid seepage in the fracture plane and moisture content. The experimental work was performed with rock samples and indigenous microorganisms from the site of the US Department of Energy's Idaho National Engineering and Environmental Laboratory (INEEL), located in a basalt flow basin where VOC contamination threatens the Snake River Aquifer. The insights gained from this approach should contribute to the design of techniques to monitor and stimulate naturally occurring biological activity and control the spread of organic contaminants.

Geller, J.T.; Holman, H.-Y.; Su, T.-S.; Liou, M.S.; Conrad, M.S.; Pruess, K.; Hunter-Devera, J.C.

1998-12-01T23:59:59.000Z

17

Characterization and Potential Remediation Approaches for Vadose Zone Contamination at Hanford 241-SX Tank Farm  

Science Conference Proceedings (OSTI)

Unplanned releases of radioactive and hazardous wastes have occurred at the 241-SX Tank Farm on the U.S. Department of Energy Hanford Site in southeast Washington State. Interim and long-term mitigation efforts are currently under evaluation for 241-SX Tank Farm. Two contiguous interim surface barriers have been designed for deployment at 241-SX Tank Farm to reduce future moisture infiltration; however, construction of the surface barriers has been deferred to allow testing of alternative technologies for soil moisture reduction and possibly contaminant source term reduction. Previous tests performed by other organizations at the Hanford Site have demonstrated that: vadose zone desiccation using large diameter (greater than 4 inch) boreholes is feasible; under certain circumstances, mobile contaminants may be removed in addition to water vapor; and small diameter (approximately 2 inch) boreholes (such as those placed by the direct push hydraulic hammer) can be used to perform vapor extractions. Evaluation of the previous work combined with laboratory test results have led to the design of a field proof-of-principle test to remove water and possibly mobile contaminants at greater depths, using small boreholes placed with the direct push unit.

Eberlein, Susan J.; Sydnor, Harold A.; Parker, Danny L.; Glaser, Danney R.

2013-01-10T23:59:59.000Z

18

The DOE Vadose Zone Science and Technology Roadmap: A National Program to Address Characeterization, Monitoring and Simulation of Subsurface Contaminant Fate and Transport  

Science Conference Proceedings (OSTI)

The vadose zone comprises the region lying between the earth’s surface and the top of the regional seasonal aquifer. Until recently contamination in the vadose zone was believed to remain relatively immobile. Thus, little attention was paid to understanding the nature of the vadose zone or the potential pathways for contaminants to migrate through it to the water table or other accessible environments. However, recent discoveries of contaminants migrating considerable distances through the vadose zone at several Department of Energy (DOE) sites have changed many assumptions both about the nature and function of the vadose zone and the importance we place on understanding this region. As a result of several vadose zone surprises, DOE Environmental Management (EM) tasked the Idaho National Engineering and Environmental Laboratory (INEEL) to lead the development of a vadose zone science and technology roadmap. The roadmap is focused on identifying research spanning the next 25 years necessary to be able to better predict the fate and transport of contaminants in the vadose zone. This in turn will provide the basis for reducing scientific uncertainty in environmental remediation and, especially, vadose zone related long-term stewardship decisions across the DOE complex. Vadose zone issues are now recognized as a national problem affecting other federal agencies as well as state and municipal sites with similar problems. Over the next few decades, dramatic and fundamental advances in computing, communication, electronics and micro-engineered systems will transform our understanding of many aspects of the scientific and technical challenges we face today. The roadmap will serve to develop a common perspective on possible future science and technology needs in an effort to help make better R&D investment decisions.

Kowall, Stephen Jacob

2001-02-01T23:59:59.000Z

19

Geochemistry and Distribution of Contaminants in the Vadose Zone of the Single-Shell Tank Waste Management Areas at the Hanford Site  

Science Conference Proceedings (OSTI)

This chapter provides a description of the geochemical processes that affect contaminant mobility in the vadose zone at the single-shell tank waste management areas located at the Hanford Site.

Cantrell, Kirk J.

2008-01-17T23:59:59.000Z

20

Reactant Carrier Microfoam Technology for In-Situ Remediation of Radionuclide and Metallic Contaminants in Deep Vadose Zone  

SciTech Connect

The U.S. Department of Energy (DOE) is currently developing advanced remedial technologies for addressing metal and radionuclide (Cr, Tc, and U) contamination in deep vadose zone environments. One of the transformational technology alternatives being considered by the DOE Office of Environmental Management, is the use of Reactant Carrier Microfoams (RCM) as a minimally invasive method for delivery and emplacement of reagents for in-situ immobilization of contaminants. Penetration of low permeability zones deep within the subsurface for Enhance Oil Recovery (EOR) has been well-established. Use of surfactant foams have also been explored for mobilizing DNAPL from sediments. So far, the concept of using RCM for immobilizing labile metal and long-lived radionuclide contaminants in the deep vadose zone has not been explored. We, at the Pacific Northwest National Laboratory (PNNL), conducted studies to develop stable foams as a means to deliver reductive and/or precipitating reactants to the deep subsurface. To test the feasibility of this approach, we developed a preliminary foam formulation consisting of a mixture of an anionic and a nonionic surfactant with a reactant consisting of a 9:1 blend of tripoly- and orthophosphate. The MSE Technology Applications, Inc (MSE) in collaboration with PNNL, conducted a scale-up test to evaluate the efficacy of this reactant carrier foam for in-situ immobilization of U containing sediment zones in a heterogenous sediment matrix. The data indicated that successful immobilization of U contamination is feasible using specifically tailored reactant carrier foam injection technology. Studies are continuing for developing more robust optimized RCM for highly mobile contaminants such as Cr (VI), Tc (VII) in the deep vadose zone.

Mattigod, Shas V.; Zhong, Lirong; Jansik, Danielle P.; Foote, Martin; Hart, Andrea T.; Wellman, Dawn M.

2010-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

DEEP VADOSE ZONE TREATABILITY TEST PLAN  

Science Conference Proceedings (OSTI)

{sm_bullet} Treatability test plan published in 2008 {sm_bullet} Outlines technology treatability activities for evaluating application of in situ technologies and surface barriers to deep vadose zone contamination (technetium and uranium) {sm_bullet} Key elements - Desiccation testing - Testing of gas-delivered reactants for in situ treatment of uranium - Evaluating surface barrier application to deep vadose zone - Evaluating in situ grouting and soil flushing

GB CHRONISTER; MJ TRUEX

2009-07-02T23:59:59.000Z

22

Geochemical Characterization of Chromate Contamination in the 100 Area Vadose Zone at the Hanford Site - Part 2  

Science Conference Proceedings (OSTI)

At the Hanford Site, chromate was used throughout the 100 Areas (100-B, 100-C, 100-D/DR, 100-F, 100-H, and 100 K) as a corrosion inhibitor in reactor cooling water. Chromate was delivered in rail cars, tanker trucks, barrels, and local pipelines as dichromate granular solid or stock solution. In many occasions, chromate was inevitably discharged to surface or near-surface ground through spills during handling, pipeline leaks, or during disposal to cribs. The composition of the liquids that were discharged is not known and it is quite possible that Cr(VI) fate and transport in the contaminated sediments would be a function of the chemical composition of the waste fluids. The major objectives of this investigation which was limited in scope by the financial resources available, were to 1) determine the leaching characteristics of hexavalent chromium [Cr(VI)] from contaminated sediments collected from 100-D Area spill sites; 2) elucidate possible Cr(VI) mineral and/or chemical associations that may be responsible for Cr(VI) retention in the Hanford Site 100 Areas through the use of macroscopic leaching studies, and microscale characterization of contaminated sediments; and 3) provide information to construct a conceptual model of Cr(VI) geochemistry in the Hanford 100 Area vadose zone that can be used for developing options for environmental remediation. The information gathered from this research effort will help to further improve our understanding of Cr(VI) behavior in the vadose zone and will also help in accelerating the 100 Area Columbia River Corridor cleanup by providing valuable information to develop remedial action based on a fundamental understanding of Cr(VI) vadose zone geochemistry. A series of column experiments were conducted with contaminated sediments to study Cr(VI) desorption patterns. Column experiments used the field size fraction of the sediment samples and a simulated Hanford Site groundwater solution. Periodic stop flow events were applied to evaluate the change in elemental concentration during time periods of no flow and greater fluid residence time. Sediments were characterized for the spatial and mineralogical associations of the contamination using some microscale techniques such as X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, and Mössbauer spectroscopy.

Qafoku, Nikolla; Dresel, P. Evan; McKinley, James P.; Ilton, Eugene S.; Um, Wooyong; Resch, Charles T.; Kukkadapu, Ravi K.; Petersen, Scott W.

2011-01-04T23:59:59.000Z

23

Field evidence for strong chemical separation of contaminants inthe Hanford Vadose Zone  

SciTech Connect

Water and chemical transport from a point source withinvadose zone sediments at Hanford were examined with a leak testconsisting of five 3800-liter aliquots of water released at 4.5 m depthevery week over a 4-week period. The third aliquot contained bromide, D2Oand 87Sr. Movement of the tracers was monitored for 9 months by measuringpore water compositions of samples from boreholes drilled 2-8 m from theinjection point. Graded sedimentary layers acting as natural capillarybarriers caused significant lateral spreading of the leak water. D2Oconcentrations>50 percent of the concentration in the tracer aliquotwere detected at 9-11 m depth. However, increased water contents, lowerd18O values, and geophysical monitoring of moisture changes at otherdepths signified high concentrations of leak fluids were added where D2Oconcentrations were<3 percent above background, suggesting limitedmixing between different aliquots of the leak fluids. Initially highbromide concentrations decreased more rapidly over time than D2O,suggesting enhanced transport of bromide due to anion exclusion. Nosignificant increase in 87Sr was detected in the sampled pore water,indicating strong retardation of Sr by the sediments. These resultshighlight some of the processes strongly affecting chemical transport inthe vadose zone and demonstrate the significant separation of contaminantplumes that can occur.

Conrad, Mark E.; DePaolo, Donald J.; Maher, Katharine; Gee,Glendon W.; Ward, Anderson L.

2007-04-10T23:59:59.000Z

24

Deficiencies in Vadose Zone Understanding at the INEEL  

Science Conference Proceedings (OSTI)

Subsurface contamination in the vadose zone, that portion of the subsurface pathway between land surface and an underlying aquifer, poses environmental problems at the Idaho National Engineering and Environmental Laboratory (INEEL) in eastern Idaho and across the U.S. Department of Energy complex. Assessing potential adverse impacts from these contaminated sites requires an understanding of the mechanisms controlling contaminant transport. Currently, vadose zone experts at the INEEL cannot with confidence predict the movement of water and contaminants in the complex, heterogeneous, fractured subsurface at the INEEL, especially within the vadose zone. In the draft version (Revision 1) of the Vadose Zone Deficiencies document, deficiencies in scientific understanding of flow and transport processes in the vadose zone at the INEEL were identified and grouped into 13 categories and recommendations were provided to address each of the deficiencies. The draft document provided the basis for an INEEL Vadose Zone Workshop that was conducted October 20 and 21, 1999, in Idaho Falls, Idaho. The workshop was conducted to group and rank the previously identified deficiencies and for the subsequent development of science plans to address the deficiencies that limit reliable predictions of water and contaminant movement in the subsurface. The workshop participants, comprising INEEL and scientists and project managers and non-INEEL scientists knowledgeable about the vadose zone, developed science- and technology-based recommendations derived through a series of technical sessions at the workshop. In this document, the final version of the Vadose Zone Deficiencies document, the draft document has been incorporated, largely intact, as well as the results from the workshop. The workshop participants grouped the deficiencies in vadose zone understanding at the INEEL into seven categories. These seven categories will be the focus areas of five science plans that are being developed to address the deficiencies. This document lays the foundation for the INEEL Site-wide vadose zone roadmap.

Wood, Thomas Ronald; Bates, Dona Louise; Bishop, Carolyn Wagoner; Heard, Robert Eugene; Hubbell, Joel Michael; Hull, Laurence Charles; Lehman, Richard Michael; Magnuson, Swen O; Mattson, Earl Douglas; Mccarthy, James Michael; Porro, Indrek; Ritter, Paul David; Roddy, Michael Scott; Singler, Robert Edward; Smith, Richard Paul

2000-08-01T23:59:59.000Z

25

Conceptual Models for Migration of Key Groundwater Contaminants Through the Vadose Zone and Into the Upper Unconfined Aquifer Below the B-Complex  

Science Conference Proceedings (OSTI)

The B-Complex contains 3 major crib and trench disposal sites and 3 SST farms that have released nearly 346 mega-liters of waste liquids containing the following high groundwater risk drivers: ~14,000 kg of CN, 29,000 kg of Cr, 12,000 kg of U and 145 Ci of Tc-99. After a thorough review of available vadose zone sediment and pore water, groundwater plume, field gamma logging, field electrical resistivity studies, we developed conceptual models for which facilities have been the significant sources of the contaminants in the groundwater and estimated the masses of these contaminants remaining in the vadose zone and currently present in the groundwater in comparison to the totals released. This allowed us to make mass balance calculations on how consistent our knowledge is on the current deep vadose zone and groundwater distribution of contaminants. Strengths and weaknesses of the conceptual models are discussed as well as implications on future groundwater and deep vadose zone remediation alternatives. Our hypothesized conceptual models attribute the source of all of the cyanide and most of the Tc-99 currently in the groundwater to the BY cribs. The source of the uranium is the BX-102 tank overfill event and the source of most of the chromium is the B-7-A&B and B-8 cribs. Our mass balance estimates suggest that there are much larger masses of U, CN, and Tc remaining in the deep vadose zone within ~20 ft of the water table than is currently in the groundwater plumes below the B-Complex. This hypothesis needs to be carefully considered before future remediation efforts are chosen. The masses of these groundwater risk drivers in the the groundwater plumes have been increasing over the last decade and the groundwater plumes are migrating to the northwest towards the Gable Gap. The groundwater flow rate appears to flucuate in response to seasonal changes in hydraulic gradient. The flux of contaminants out of the deep vadose zone from the three proposed sources also appears to be transient such that the evolution of the contaminant plumes is transient.

Serne, R. Jeffrey; Bjornstad, Bruce N.; Keller, Jason M.; Thorne, Paul D.; Lanigan, David C.; Christensen, J. N.; Thomas, Gregory S.

2010-07-01T23:59:59.000Z

26

Deep Vadose Zone Applied Field Research Initiative (DVZ-AFRI) | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Deep Vadose Zone Applied Field Research Initiative (DVZ-AFRI) Deep Vadose Zone Applied Field Research Initiative (DVZ-AFRI) Deep Vadose Zone Applied Field Research Initiative (DVZ-AFRI) Deep Vadose Zone Applied Field Research Initiative (DVZ-AFRI) Located on the Hanford Site in Richland, Washington, the Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources by addressing the challenge of preventing contamination in the deep vadose zone from reaching groundwater. Led by the Pacific Northwest National Laboratory, the Initiative is a collaborative effort that leverages Department of Energy (DOE) investments in basic science and applied research and the work of site contractors to address the complex deep vadose zone contamination challenges. The Mission of the Deep Vadose

27

ESTIMATING FATE AND TRANSPORT OF MULTIPLE CONTAMINANTS IN THE VADOSE ZONE USING A MULTI-LAYERED SOIL COLUMN AND THREE-PHASE EQUILIBRIUM PARTITIONING MODEL  

SciTech Connect

Soils at waste sites must be evaluated for the potential of residual soil contamination to leach and migrate to the groundwater beneath the disposal area. If migration to the aquifer occurs, contaminants can travel vast distances and contaminate drinking water wells, thus exposing human receptors to harmful levels of toxins and carcinogens. To prevent groundwater contamination, a contaminant fate and transport analysis is necessary to assess the migration potential of residual soil contaminates. This type of migration analysis is usually performed using a vadose zone model to account for complex geotechnical and chemical variables including: contaminant decay, infiltration rate, soil properties, vadose zone thickness, and chemical behavior. The distinct advantage of using a complex model is that less restrictive, but still protective, soil threshold levels may be determined avoiding the unnecessary and costly remediation of marginally contaminated soils. However, the disadvantage of such modeling is the additional cost for data collection and labor required to apply these models. In order to allay these higher costs and to achieve a less restrictive but still protective clean-up level, a multiple contaminant and multi layered soil column equilibrium partitioning model was developed which is faster, simpler and less expensive to use.

Rucker, G

2007-05-01T23:59:59.000Z

28

Field evidence for strong chemical separation of contaminants in the Hanford Vadose Zone  

E-Print Network (OSTI)

Zone Transport Field Study, PNNL-13454, Pacific NorthwestZone Transport Field Study, PNNL-13631, Pacific Northwestplan for simulated leak tests. PNNL-13263. Pacific Northwest

Conrad, Mark E.; DePaolo, Donald J.; Maher, Katharine; Gee, Glendon W.; Ward, Anderson L.

2007-01-01T23:59:59.000Z

29

Vadose Zone Transport Field Study: Summary Report  

SciTech Connect

From FY 2000 through FY 2003, a series of vadose zone transport field experiments were conducted as part of the U.S. Department of Energy’s Groundwater/Vadose Zone Integration Project Science and Technology Project, now known as the Remediation and Closure Science Project, and managed by the Pacific Northwest National Laboratory (PNNL). The series of experiments included two major field campaigns, one at a 299-E24-11 injection test site near PUREX and a second at a clastic dike site off Army Loop Road. The goals of these experiments were to improve our understanding of vadose zone transport processes; to develop data sets to validate and calibrate vadose zone flow and transport models; and to identify advanced monitoring techniques useful for evaluating flow-and-transport mechanisms and delineating contaminant plumes in the vadose zone at the Hanford Site. This report summarizes the key findings from the field studies and demonstrates how data collected from these studies are being used to improve conceptual models and develop numerical models of flow and transport in Hanford’s vadose zone. Results of these tests have led to a better understanding of the vadose zone. Fine-scale geologic heterogeneities, including grain fabric and lamination, were observed to have a strong effect on the large-scale behavior of contaminant plumes, primarily through increased lateral spreading resulting from anisotropy. Conceptual models have been updated to include lateral spreading and numerical models of unsaturated flow and transport have revised accordingly. A new robust model based on the concept of a connectivity tensor was developed to describe saturation-dependent anisotropy in strongly heterogeneous soils and has been incorporated into PNNL’s Subsurface Transport Over Multiple Phases (STOMP) simulator. Application to field-scale transport problems have led to a better understanding plume behavior at a number of sites where lateral spreading may have dominated waste migration (e.g. BC Cribs and Trenches). The improved models have been also coupled with inverse models and newly-developed parameter scaling techniques to allow estimation of field-scale and effective transport parameters for the vadose zone. The development and utility of pedotransfer functions for describing fine-scale hydrogeochemical heterogeneity and for incorporating this heterogeneity into reactive transport models was explored. An approach based on grain-size statistics appears feasible and has been used to describe heterogeneity in hydraulic properties and sorption properties, such as the cation exchange capacity and the specific surface area of Hanford sediments. This work has also led to the development of inverse modeling capabilities for time-dependent, subsurface, reactive transport with transient flow fields using an automated optimization algorithm. In addition, a number of geophysical techniques investigated for their potential to provide detailed information on the subtle changes in lithology and bedding surfaces; plume delineation, leak detection. High-resolution resistivity is now being used for detecting saline plumes at several waste sites at Hanford, including tank farms. Results from the field studies and associated analysis have appeared in more than 46 publications generated over the past 4 years. These publications include test plans and status reports, in addition to numerous technical notes and peer reviewed papers.

Ward, Andy L.; Conrad, Mark E.; Daily, William D.; Fink, James B.; Freedman, Vicky L.; Gee, Glendon W.; Hoversten, Gary M.; Keller, Jason M.; Majer, Ernest L.; Murray, Christopher J.; White, Mark D.; Yabusaki, Steven B.; Zhang, Z. F.

2006-07-31T23:59:59.000Z

30

Technologies Provide High-Resolution Subsurface Imaging of Vadose Zone  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technologies Provide High-Resolution Subsurface Imaging of Vadose Technologies Provide High-Resolution Subsurface Imaging of Vadose Zone Contamination at Hanford Site Technologies Provide High-Resolution Subsurface Imaging of Vadose Zone Contamination at Hanford Site May 17, 2012 - 12:00pm Addthis Shown here are high-resolution, three-dimensional ERT images of contaminant distribution Shown here are high-resolution, three-dimensional ERT images of contaminant distribution RICHLAND, Wash. - Cold War waste disposal practices resulted in both planned and unplanned releases of large amounts of radionuclide and heavy metal contamination into the subsurface throughout the DOE complex. Characterizing the distribution of the resulting environmental contamination remains one of the single most significant challenges limiting subsurface remediation and closure, particularly for the

31

Spatially resolved U(VI) partitioning and speciation: Implications for plume scale behavior of contaminant U in the Hanford vadose zone  

E-Print Network (OSTI)

EM/GJ1302- 2006, Stoller Hanford Office, Richland, WA. 2006.characterization of U(VI) in Hanford vadose zone poreUranium Geochemistry at the Hanford Site. Pacific Northwest

Wan, Jiamin

2009-01-01T23:59:59.000Z

32

Mass transport of volatile organic compounds between the saturated and vadose zones. Master`s thesis  

Science Conference Proceedings (OSTI)

Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of a VOC, trichioroethylene, between the saturated and vadose zones under a variety of conditions. The model featured steady-state unsaturated water flow and transient contaminant transport. Transport mechanisms included aqueous phase advection-dispersion and gaseous phase diffusion. Partitioning between the water, gas, and soil compartments were modeled as equilibrium processes. Sensitivity analyses were performed on several variables including soil type (homogeneous and heterogeneous profiles), water infiltration rate and vadose zone depth. Results indicated that recontamination was most significant rate, and vadose zone depth. Results indicated that recontamination was most significant in the presence of heterogeneous soils, low infiltration rates and deep vadose zones.

Harner, M.S.

1996-12-01T23:59:59.000Z

33

GEOPHYSICS AND SITE CHARACTERIZATION AT THE HANFORD SITE THE SUCCESSFUL USE OF ELECTRICAL RESISTIVITY TO POSITION BOREHOLES TO DEFINE DEEP VADOSE ZONE CONTAMINATION - 11509  

SciTech Connect

Historic boreholes confirmed the presence of nitrate and radionuclide contaminants at various intervals throughout a more than 60 m (200 ft) thick vadose zone, and a 2010 electrical resistivity survey mapped the known contamination and indicated areas of similar contaminants, both laterally and at depth; therefore, electrical resistivity mapping can be used to more accurately locate characterization boreholes. At the Hanford Nuclear Reservation in eastern Washington, production of uranium and plutonium resulted in the planned release of large quantities of contaminated wastewater to unlined excavations (cribs). From 1952 until 1960, the 216-U-8 Crib received approximately 379,000,000 L (100,000,000 gal) of wastewater containing 25,500 kg (56,218 lb) uranium; 1,029,000 kg (1,013 tons) of nitrate; 2.7 Ci of technetium-99; and other fission products including strontium-90 and cesium-137. The 216-U-8 Crib reportedly holds the largest inventory of waste uranium of any crib on the Hanford Site. Electrical resistivity is a geophysical technique capable of identifying contrasting physical properties; specifically, electrically conductive material, relative to resistive native soil, can be mapped in the subsurface. At the 216-U-8 Crib, high nitrate concentrations (from the release of nitric acid [HNO{sub 3}] and associated uranium and other fission products) were detected in 1994 and 2004 boreholes at various depths, such as at the base of the Crib at 9 m (30 ft) below ground surface (bgs) and sporadically to depths in excess of 60 m (200 ft) bgs. These contaminant concentrations were directly correlative with the presence of observed low electrical resistivity responses delineated during the summer 2010 geophysical survey. Based on this correlation and the recently completed mapping of the electrically conductive material, additional boreholes are planned for early 2011 to identify nitrate and radionuclide contamination: (a) throughout the entire vertical length of the vadose zone (i.e., 79 m [260 ft] bgs) within the footprint of the Crib, and (b) 15 to 30 m (50 to 100 ft) east of the Crib footprint, where contaminants are inferred to have migrated through relatively permeable soils. Confirmation of the presence of contamination in historic boreholes correlates well with mapping from the 2010 survey, and serves as a basis to site future characterization boreholes that will likely intersect contamination both laterally and at depth.

GANDER MJ; LEARY KD; LEVITT MT; MILLER CW

2011-01-14T23:59:59.000Z

34

Integrated Strategy to Address Hanford’s Deep Vadose Zone Remediation Challenges  

Science Conference Proceedings (OSTI)

A vast majority of Hanford’s remaining in-ground contaminants reside in the vadose zone of the Central Plateau, where reprocessing operations occurred. The vadose zone is comprised of about 75 meters of water-unsaturated sediments above groundwater. These contaminants have, and continue to release into groundwater that discharges to the Columbia River. If left untreated, these contaminants could remain a threat for centuries. Much of this contamination resides deep in the vadose zone, below the effective depth of tradition surface remedy influence. In 2008, the Department of Energy initiated deep vadose zone treatability testing to seek remedies for technetium-99 and uranium contamination. These tests include the application of desiccation for technetium-99 and reactive gas technologies for uranium. To complement these efforts, the Department of Energy has initiated a “defense-in-depth” approach to address the unique challenges for characterization and remediation of the deep vadose zone. This defense-in-depth approach will implement multiple approaches to understand and control contaminant flux from the deep vadose zone to the groundwater. Among these approaches is an increased investment in science and technology solutions to resolve deep vadose zone challenges including characterization, prediction, remediation, and monitoring.

Triplett, Mark B.; Freshley, Mark D.; Truex, Michael J.; Wellman, Dawn M.; Gerdes, Kurt D.; Charboneau, Briant L.; Morse, John G.; Lober, Robert W.; Chronister, Glen B.

2010-10-03T23:59:59.000Z

35

Characterization of Direct Push Vadose Zone Sediments from the T and TY Waste Management Areas  

SciTech Connect

This report contains all the geochemical and selected physical characterization data collected on vadose zone sediment recovered from 5 direct push characterization holes emplaced to investigate vadose zone contamination associated with leaks from tanks 241-TY-105 (UPR-200-W-152) and 241-TY-106 (UPR-200-W-153). Tank 241-TY-105 is estimated to have leaked 35,000 gal of tributyl phosphate (TBP) waste from the uranium recovery process to the vadose zone in 1960. Tank 241-TY-106 is estimated to have leaked 20,000 gal of TBP-uranium recovery waste to the vadose zone in 1959. Although several drywells in the vicinity of tank 241-TY-106 contain measurable quantities of cesium-137 and/or cobalt-60, their relatively low concentrations indicate that the contaminant inventory in the vadose zone around tank 241-TY-106 is quite small. Additionally, this report contains all the geochemical and selected physical characterization data collected on vadose zone sediment recovered from 7 direct push characterization holes emplaced to investigate vadose zone contamination associated with an overfill event and leak from tank 241-T-101.

Brown, Christopher F.; Valenta, Michelle M.; Serne, R. Jeffrey; Bjornstad, Bruce N.; Lanigan, David C.; Iovin, Cristian; Clayton, Ray E.; Geiszler, Keith N.; Clayton, Eric T.; Kutnyakov, Igor V.; Baum, Steven R.; Lindberg, Michael J.; Orr, Robert D.

2007-06-08T23:59:59.000Z

36

Evaluation of Soil Flushing for Application to the Deep Vadose Zone in the Hanford Central Plateau  

SciTech Connect

Soil flushing was included in the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau as a technology with the potential to remove contaminants from the vadose zone. Soil flushing operates through the addition of water, and if necessary an appropriate mobilizing agent, to mobilize contaminants and flush them from the vadose zone and into the groundwater where they are subsequently captured by a pump-and-treat system. There are uncertainties associated with applying soil flushing technology to contaminants in the deep vadose zone at the Hanford Central Plateau. The modeling and laboratory efforts reported herein are intended to provide a quantitative assessment of factors that impact water infiltration and contaminant flushing through the vadose zone and into the underlying groundwater. Once in the groundwater, capture of the contaminants would be necessary, but this aspect of implementing soil flushing was not evaluated in this effort. Soil flushing was evaluated primarily with respect to applications for technetium and uranium contaminants in the deep vadose zone of the Hanford Central Plateau.

Truex, Michael J.; Oostrom, Martinus; Zhang, Z. F.; Carroll, Kenneth C.; Schramke, Janet A.; Wietsma, Thomas W.; Tartakovsky, Guzel D.; Gordon, Kathryn A.; Last, George V.

2010-11-01T23:59:59.000Z

37

Influence of Wetting and Mass Transfer Properties of Organic Chemical Mixtures in Vadose Zone Materials on Groundwater Contamination by Nonaqueous Phase Liquids  

Science Conference Proceedings (OSTI)

Previous studies have found that organic acids, organic bases, and detergent-like chemicals change surface wettability. The wastewater and NAPL mixtures discharged at the Hanford site contain such chemicals, and their proportions likely change over time due to reaction-facilitated aging. The specific objectives of this work were to (1) determine the effect of organic chemical mixtures on surface wettability, (2) determine the effect of organic chemical mixtures on CCl4 volatilization rates from NAPL, and (3) accurately determine the migration, entrapment, and volatilization of organic chemical mixtures. Five tasks were proposed to achieve the project objectives. These are to (1) prepare representative batches of fresh and aged NAPL-wastewater mixtures, (2) to measure interfacial tension, contact angle, and capillary pressure-saturation profiles for the same mixtures, (3) to measure interphase mass transfer rates for the same mixtures using micromodels, (4) to measure multiphase flow and interphase mass transfer in large flow cell experiments, all using the same mixtures, and (5) to modify the multiphase flow simulator STOMP in order to account for updated P-S and interphase mass transfer relationships, and to simulate the impact of CCl4 in the vadose zone on groundwater contamination. Results and findings from these tasks and summarized in the attached final report.

Charles J Werth; Albert J Valocchi, Hongkyu Yoon

2011-05-21T23:59:59.000Z

38

Colloid Facilitated Transport of Radioactive Cations in the Vadose Zone: Field Experiments Oak Ridge  

Science Conference Proceedings (OSTI)

The overarching goal of this study was to improve understanding of colloid-facilitated transport of radioactive cations through unsaturated soils and sediments. We conducted a suite of laboratory experiments and field experiments on the vadose-zone transport of colloids, organic matter, and associated contaminants of interest to the U.S. Department of Energy (DOE). The laboratory and field experiments, together with transport modeling, were designed to accomplish the following detailed objectives: 1. Evaluation of the relative importance of inorganic colloids and organic matter to the facilitation of radioactive cation transport in the vadose zone; 2. Assessment of the role of adsorption and desorption kinetics in the facilitated transport of radioactive cations in the vadose zone; 3. Examination of the effects of rainfall and infiltration dynamics and in the facilitated transport of radioactive cations through the vadose zone; 4. Exploration of the role of soil heterogeneity and preferential flow paths (e.g., macropores) on the facilitated transport of radioactive cations in the vadose zone; 5. Development of a mathematical model of facilitated transport of contaminants in the vadose zone that accurately incorporates pore-scale and column-scale processes with the practicality of predicting transport with readily available parameters.

James E. Saiers

2012-09-20T23:59:59.000Z

39

300 Area Treatability Test: Laboratory Development of Polyphosphate Remediation Technology for In Situ Treatment of Uranium Contamination in the Vadose Zone and Capillary Fringe  

SciTech Connect

This report presents results from bench-scale treatability studies conducted under site-specific conditions to optimize the polyphosphate amendment for implementation of a field-scale technology demonstration to stabilize uranium within the 300 Area vadose and smear zones of the Hanford Site. The general treatability testing approach consisted of conducting studies with site sediment and under site conditions, to develop an effective chemical formulation and infiltration approach for the polyphosphate amendment under site conditions. Laboratory-scale dynamic column tests were used to 1) quantify the retardation of polyphosphate and its degradation products as a function of water content, 2) determine the rate of polyphosphate degradation under unsaturated conditions, 3) develop an understanding of the mechanism of autunite formation via the reaction of solid phase calcite-bound uranium and aqueous polyphosphate remediation technology, 4) develop an understanding of the transformation mechanism, the identity of secondary phases, and the kinetics of the reaction between uranyl-carbonate and -silicate minerals with the polyphosphate remedy under solubility-limiting conditions, and 5) quantify the extent and rate of uranium released and immobilized based on the infiltration rate of the polyphosphate remedy and the effect of and periodic wet-dry cycling on the efficacy of polyphosphate remediation for uranium in the vadose zone and smear zone.

Wellman, Dawn M.; Pierce, Eric M.; Bacon, Diana H.; Oostrom, Martinus; Gunderson, Katie M.; Webb, Samuel M.; Bovaird, Chase C.; Cordova, Elsa A.; Clayton, Eric T.; Parker, Kent E.; Ermi, Ruby M.; Baum, Steven R.; Vermeul, Vincent R.; Fruchter, Jonathan S.

2008-09-30T23:59:59.000Z

40

Colloid-Facilitated Transport of Radionuclides Through The Vadose Zone  

SciTech Connect

The main purpose of this project was to advance the basic scientific understanding of colloid and colloid-facilitated Cs transport of radionuclides in the vadose zone. We focused our research on the hydrological and geochemical conditions beneath the leadking waste tanks at the USDOE Hanford reservation. Specific objectives were (1) to determine the lability and thermodynamic stability of colloidal materials, which form after reacting Hanford sediments with simulated Hanford Tank Waste, (2) to characterize the interactions between colloidal particles and contaminants, i.e., Cs and Eu, (3) to determine the potential of Hanford sediments for in situe mobilization of colloids, (4) to evaluate colloid-facilitated radionuclide transport through sediments under unsaturated flow, (5) to implement colloid-facilitated contaminant transport mechanisms into a transport model, and (6) to improve conceptual characterization of colloid-contaminant-soil interactions and colloid-facilitated transport for clean-up procedures and long-term risk assessment.

Markus Flury; James B. Harsh; John F. McCarthy' Peter C. Lichtner; John M. Zachara

2007-06-22T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Vadose Zone Characterization Techniques Developed by EMSP Research  

Science Conference Proceedings (OSTI)

This paper discusses research contributions made by Environmental Management Science Program (EMSP) research in the area of geophysical characterization of the subsurface. The goal of these EMSP research projects is to develop combined high-resolution measurement and interpretation packages that provide accurate, timely information needed to characterize the vadose zone. Various types of geophysical imaging techniques can be used to characterize the shallow subsurface. Since individual geophysical characterization tools all have specific limitations, many different techniques are being explored to provide more widespread applicability over a range of hydrogeologic settings. A combination of laboratory, field, theoretical, and computational studies are necessary to develop our understanding of how contaminants move through the vadose zone. This entails field tests with field-hardened systems, packaging and calibration of instrumentation, data processing and analysis algorithms, forward and inverse modeling, and so forth. DOE sites are seeking to team with EMSP researchers to leverage the basic science research investment and apply these advances to address subsurface contamination issues that plague many U.S. Department of Energy (DOE) sites.

Guillen, Donna P.

2003-02-24T23:59:59.000Z

42

SOIL DESICCATION TECHNIQUES STRATEGIES FOR IMMOBILIZATION OF DEEP VADOSE CONTAMINANTS AT THE HANFORD CENTRAL PLATEAU  

SciTech Connect

Deep vadose zone contamination poses some of the most difficult remediation challenges for the protection of groundwater at the Hanford Site where processes and technologies are being developed and tested for use in the on-going effort to remediate mobile contamination in the deep vadose zone, the area deep beneath the surface. Historically, contaminants were discharged to the soil along with significant amounts of water, which continues to drive contaminants deeper in the vadose zone toward groundwater. Soil desiccation is a potential in situ remedial technology well suited for the arid conditions and the thick vadose zone at the Hanford Site. Desiccation techniques could reduce the advance of contaminants by removing the pore water to slow the rate of contaminants movement toward groundwater. Desiccation technologies have the potential to halt or slow the advance of contaminants in unsaturated systems, as well as aid in reduction of contaminants from these same areas. Besides reducing the water flux, desiccation also establishes capillary breaks that would require extensive rewetting to resume pore water transport. More importantly, these techniques have widespread application, whether the need is to isolate radio nuclides or address chemical contaminant issues. Three different desiccation techniques are currently being studied at Hanford.

BENECKE MW; CHRONISTER GB; TRUEX MJ

2012-01-30T23:59:59.000Z

43

Vadose zone transport field study: Detailed test plan for simulated leak tests  

Science Conference Proceedings (OSTI)

The US Department of Energy (DOE) Groundwater/Vadose Zone Integration Project Science and Technology initiative was created in FY 1999 to reduce the uncertainty associated with vadose zone transport processes beneath waste sites at DOE's Hanford Site near Richland, Washington. This information is needed not only to evaluate the risks from transport, but also to support the adoption of measures for minimizing impacts to the groundwater and surrounding environment. The principal uncertainties in vadose zone transport are the current distribution of source contaminants and the natural heterogeneity of the soil in which the contaminants reside. Oversimplified conceptual models resulting from these uncertainties and limited use of hydrologic characterization and monitoring technologies have hampered the understanding contaminant migration through Hanford's vadose zone. Essential prerequisites for reducing vadose transport uncertainly include the development of accurate conceptual models and the development or adoption of monitoring techniques capable of delineating the current distributions of source contaminants and characterizing natural site heterogeneity. The Vadose Zone Transport Field Study (VZTFS) was conceived as part of the initiative to address the major uncertainties confronting vadose zone fate and transport predictions at the Hanford Site and to overcome the limitations of previous characterization attempts. Pacific Northwest National Laboratory (PNNL) is managing the VZTFS for DOE. The VZTFS will conduct field investigations that will improve the understanding of field-scale transport and lead to the development or identification of efficient and cost-effective characterization methods. Ideally, these methods will capture the extent of contaminant plumes using existing infrastructure (i.e., more than 1,300 steel-cased boreholes). The objectives of the VZTFS are to conduct controlled transport experiments at well-instrumented field sites at Hanford to: identify mechanisms controlling transport processes in soils typical of the hydrogeologic conditions of Hanford's waste disposal sites; reduce uncertainty in conceptual models; develop a detailed and accurate database of hydraulic and transport parameters for validation of three-dimensional numerical models; identify and evaluate advanced, cost-effective characterization methods with the potential to assess changing conditions in the vadose zone, particularly as surrogates of currently undetectable high-risk contaminants. This plan provides details for conducting field tests during FY 2000 to accomplish these objectives. Details of additional testing during FY 2001 and FY 2002 will be developed as part of the work planning process implemented by the Integration Project.

AL Ward; GW Gee

2000-06-23T23:59:59.000Z

44

EVALUATION OF VADOSE ZONE TREATMENT TECHNOLOGIES TO IMMOBILIZE TECHNETIUM-99  

Science Conference Proceedings (OSTI)

The Hanford Site End State Vision document (DOE/RL-2003-59) states: ''There should be an aggressive plan to develop technology for remediation of the contamination that could get to the groundwater (particularly the technetium [{sup 99}Tc])''. In addition, there is strong support from the public and regulatory agencies for the above statement, with emphasis on investigation of treatment alternatives. In July 2004, PNNL completed a preliminary evaluation of remediation technologies with respect to their effectiveness and implementability for immobilization of {sup 99}Tc beneath the BC Cribs in the 200 West Area (Truex, 2004). As a result of this evaluation, PNNL recommended treatability testing of in situ soil desiccation, because it has the least uncertainty of those technologies evaluated in July 2004 (Treatability Test Outline, September 30, 2004). In 2005, DOE-RL and Fluor Hanford convened an independent technical panel to review alternative remediation technologies, including desiccation, at a three-day workshop in Richland, Washington. The panel was composed of experts in vadose-zone transport, infiltration control, hydrology, geochemistry, environmental engineering, and geology. Their backgrounds include employment in academia, government laboratories, industry, and consulting. Their review, presented in this document, is based upon written reports from Hanford, oral presentations from Hanford staff, and each panel members' years of experience in their particular field of expertise. The purpose of this report is to document the panel's evaluation of various treatment alternatives with potential for minimizing contaminant migration in the deep vadose zone at the Department of Energy Hanford Site. The panel was tasked with assessing the most viable and practical approach and making recommendations for testing. The evaluation of vadose-zone treatment alternatives was conducted to be broadly applicable at a variety of locations at Hanford. However, because of limitations of time, the panel was asked to focus on one example, {sup 99}Tc contamination below the BC Cribs and Trenches. It is well recognized that conditions at BC Cribs and Trenches are not the same as those at other Hanford locations, but it was selected so that the panel could develop an understanding of site conditions at one location. The recommendations in this report are not intended to address the regulatory decision process for this site.

PETERSEN, S.W.

2006-03-15T23:59:59.000Z

45

Vadose Zone Modeling Workshop proceedings, March 29--30, 1993  

Science Conference Proceedings (OSTI)

At the Hanford Site, the record of decision for remediation of CERCLA sites is largely based on results of the baseline risk and performance assessment of the remedial action alternatives. These assessments require the ability to predict the fate and transport of contaminants along appropriate exposure pathways which, in case of the Hanford Site, includes the migration of contaminants through the vadose zone to the water table. Listed below are some of the requirements, as prescribed by the regulators, relative to CERCLA risk and performance assessment at Hanford. A workshop was organized by the Environmental Risk and Performance Assessment Group, Westinghouse Hanford Company on March 29--30, 1993 at the Richland Best Western Tower Inn. During the workshop, an assessment was made of the need for and scope of various tasks being conducted or planned as part of the Hanford Site waste isolation performance assessment/risk assessment activities. Three external, nationally-recognized experts served as part of a review panel for the workshop: (a) Professor Lynn Gelhar of MIT; (b) Professor Peter Wierenga of University of Arizona; and (c) Dr. Rien van Genuchten of US Salinity Laboratory, Riverside, California. The technical experts provided their perspectives on the current state-of-the-art in vadose zone flow and transport modeling. In addition, the technical experts provided an outside independent assessment of the work being performed or planned in support of various activities identified in TPA Milestone M-29-02. This document includes the following: Recommendations from the three peer reviewers; areas of expertise of the three peer reviewers; workshop agenda; copies of viewgraphs (where available) from presenters at the workshop; workshop minutes; and list of workshop attendees.

Khaleel, R.

1993-08-01T23:59:59.000Z

46

A National Roadmap for Vadose Zone Science and Technology  

Science Conference Proceedings (OSTI)

This roadmap is a means of achieving, to the best of our current knowledge, a reasonable scientific understanding of how contaminants of all forms move in the vadose geological environments. This understanding is needed to reduce the present uncertainties in predicting contaminant movement, which in turn will reduce the uncertainties in remediation decisions.

Kowall, Stephen Jacob

2001-08-01T23:59:59.000Z

47

Deep Vadose Zone–Applied Field Research Initiative Fiscal Year 2012 Annual Report  

Science Conference Proceedings (OSTI)

This annual report describes the background of the Deep Vadose Zone-Applied Field Research Initiative, and some of the programmatic approaches and transformational technologies in groundwater and deep vadose zone remediation developed during fiscal year 2012.

Wellman, Dawn M.; Truex, Michael J.; Johnson, Timothy C.; Bunn, Amoret L.; Golovich, Elizabeth C.

2013-03-14T23:59:59.000Z

48

Effects of remediation amendments on vadose zone microorganisms  

SciTech Connect

Surfactant-based foam delivery technology has been studied to remediate Hanford 200 area deep vadose zone sediment. However, the surfactants and remediation amendments have an unknown effect on indigenous subsurface microorganisms. Microbial populations are important factors to consider in remediation efforts due to their potential to alter soil geochemistry. This project focuses on measuring microbial metabolic responses to remediation amendments in batch and column studies using Deep Vadose Zone Sediments. Initial studies of the microbes from Hanford 200 area deep vadose zone sediment showed surfactants sodium dodecyl sulfate (SDS) and cocamidopropyl betaine (CAPB) and remediation amendment calcium polysulfide (CPS) had no affect on microbial growth using BiologTM Ecoplates. To move towards a more realistic field analog, soil columns were packed with Hanford 200 Area sediment. Once microbial growth in the column was verified by observing growth of the effluent solution on tryptic soy agar plates, remedial surfactants were injected into the columns, and the resulting metabolic diversity was measured. Results suggest surfactant sodium dodecyl sulfate (SDS) stimulates microbial growth. The soil columns were also visualized using X-ray microtomography to inspect soil packing and possibly probe for evidence of biofilms. Overall, BiologTM Ecoplates provide a rapid assay to predict effects of remediation amendments on Hanford 200 area deep vadose zone microorganisms.

Miller, Hannah M.; Tilton, Fred A.

2012-08-10T23:59:59.000Z

49

Spectroscopic Evidence for Uranium Bearing Precipitates in Vadose Zone  

E-Print Network (OSTI)

Spectroscopic Evidence for Uranium Bearing Precipitates in Vadose Zone Sediments at the Hanford 300 collected beneath the former North Process Pond (NPP) in the 300 Area of the Hanford site (Washington the Hanford site in the state of Washington (U.S.). The 300 Area is one of many

50

Deep Vadose Zone-Applied Field Research Initiative Fiscal Year 2011 Annual Report  

SciTech Connect

This annual report describes the background of the Deep Vadose Zone-Applied Field Research Initiative, and some of the programmatic approaches and transformational technologies in groundwater and deep vadose zone remediation developed during fiscal year 2011. The Department of Energy (DOE) Office of Technology Innovation and Development's (OTID) mission is to transform science into viable solutions for environmental cleanup. In 2010, OTID developed the Impact Plan, Science and Technology to Reduce the Life Cycle Cost of Closure to outline the benefits of research and development of the lifecycle cost of cleanup across the DOE complex. This plan outlines OTID's ability to reduce by $50 billion, the $200 billion life-cycle cost in waste processing, groundwater and soil, nuclear materials, and deactivation and decommissioning. The projected life-cycle costs and return on investment are based on actual savings realized from technology innovation, development, and insertion into remedial strategies and schedules at the Fernald, Mound, and Ashtabula sites. To achieve our goals, OTID developed Applied Field Research Initiatives to facilitate and accelerate collaborative development and implementation of new tools and approaches that reduce risk, cost and time for site closure. The primary mission of the Deep Vadose Zone-Applied Field Research Initiative (DVZ-AFRI) is to protect our nation's water resources, keeping them clean and safe for future generations. The DVZ-AFRI was established for the DOE to develop effective, science-based solutions for remediating, characterizing, monitoring, and predicting the behavior and fate of deep vadose zone contamination. Subsurface contaminants include radionuclides, metals, organics, and liquid waste that originated from various sources, including legacy waste from the nation's nuclear weapons complexes. The DVZ-AFRI project team is translating strategy into action by working to solve these complex challenges in a collaborative environment that leverages technology and scientific expertise from DOE, Pacific Northwest National Laboratory, CH2M HILL Plateau Remediation Company, and the broad scientific research community. As project manager for the DVZ-AFRI, I have had the privilege this past year to team with creative, talented members of the scientific community nationwide to develop effective long-term solutions to address deep vadose zone contamination. This report highlights how the DVZ-AFRI project team is delivering results by achieving significant programmatic accomplishments, and developing and field-testing transformational technologies to address the nation's most pressing groundwater and vadose zone contamination problems.

Wellman, Dawn M.; Johnson, Timothy C.; Smith, Ronald M.; Truex, Michael J.; Matthews, Hope E.

2011-10-01T23:59:59.000Z

51

Deep Vadose Zone-Applied Field Research Initiative Fiscal Year 2011 Annual Report  

SciTech Connect

This annual report describes the background of the Deep Vadose Zone-Applied Field Research Initiative, and some of the programmatic approaches and transformational technologies in groundwater and deep vadose zone remediation developed during fiscal year 2011. The Department of Energy (DOE) Office of Technology Innovation and Development's (OTID) mission is to transform science into viable solutions for environmental cleanup. In 2010, OTID developed the Impact Plan, Science and Technology to Reduce the Life Cycle Cost of Closure to outline the benefits of research and development of the lifecycle cost of cleanup across the DOE complex. This plan outlines OTID's ability to reduce by $50 billion, the $200 billion life-cycle cost in waste processing, groundwater and soil, nuclear materials, and deactivation and decommissioning. The projected life-cycle costs and return on investment are based on actual savings realized from technology innovation, development, and insertion into remedial strategies and schedules at the Fernald, Mound, and Ashtabula sites. To achieve our goals, OTID developed Applied Field Research Initiatives to facilitate and accelerate collaborative development and implementation of new tools and approaches that reduce risk, cost and time for site closure. The primary mission of the Deep Vadose Zone-Applied Field Research Initiative (DVZ-AFRI) is to protect our nation's water resources, keeping them clean and safe for future generations. The DVZ-AFRI was established for the DOE to develop effective, science-based solutions for remediating, characterizing, monitoring, and predicting the behavior and fate of deep vadose zone contamination. Subsurface contaminants include radionuclides, metals, organics, and liquid waste that originated from various sources, including legacy waste from the nation's nuclear weapons complexes. The DVZ-AFRI project team is translating strategy into action by working to solve these complex challenges in a collaborative environment that leverages technology and scientific expertise from DOE, Pacific Northwest National Laboratory, CH2M HILL Plateau Remediation Company, and the broad scientific research community. As project manager for the DVZ-AFRI, I have had the privilege this past year to team with creative, talented members of the scientific community nationwide to develop effective long-term solutions to address deep vadose zone contamination. This report highlights how the DVZ-AFRI project team is delivering results by achieving significant programmatic accomplishments, and developing and field-testing transformational technologies to address the nation's most pressing groundwater and vadose zone contamination problems.

Wellman, Dawn M.; Johnson, Timothy C.; Smith, Ronald M.; Truex, Michael J.; Matthews, Hope E.

2011-10-01T23:59:59.000Z

52

Vadose Zone Hydrogeology Data Package for Hanford Assessments  

SciTech Connect

This data package documents the technical basis for selecting physical and geochemical parameters and input values that will be used in vadose zone modeling for Hanford assessments. This work was originally conducted as part of the Characterization of Systems Task of the Groundwater Remediation Project managed by Fluor Hanford, Inc., Richland, Washington, and revised as part of the Characterization of Systems Project managed by the Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy, Richland Operations Office (DOE-RL). This data package describes the geologic framework, the physical, hydrologic, and contaminant transport properties of the geologic materials, and deep drainage (i.e., recharge) estimates, and builds on the general framework developed for the initial assessment conducted using the System Assessment Capability (SAC) (Bryce et al. 2002). The general approach for this work was to update and provide incremental improvements over the previous SAC data package completed in 2001. As with the previous SAC data package, much of the data and interpreted information were extracted from existing documents and databases. Every attempt was made to provide traceability to the original source(s) of the data or interpretations.

Last, George V.; Freeman, Eugene J.; Cantrell, Kirk J.; Fayer, Michael J.; Gee, Glendon W.; Nichols, William E.; Bjornstad, Bruce N.; Horton, Duane G.

2006-06-01T23:59:59.000Z

53

Colloid-Facilitated Transport of Radionuclides through the Vadose Zone  

SciTech Connect

The main purpose of this project was to advance the basic scientific understanding of colloid and colloid-facilitated Cs transport of radionuclides in the vadose zone. We focused our research on the hydrological and geochemical conditions beneath the leaking waste tanks at the USDOE Hanford reservation. Specific objectives were (1) to determine the lability and thermodynamic stability of colloidal materials, which form after reacting Hanford sediments with simulated Hanford Tank Waste, (2) to characterize the interactions between colloidal particles and contaminants, i.e., Cs and Eu, (3) to determine the potential of Hanford sediments for \\textit{in situ} mobilization of colloids, (4) to evaluate colloid-facilitated radionuclide transport through sediments under unsaturated flow, (5) to implement colloid-facilitated contaminant transport mechanisms into a transport model, and (6) to improve conceptual characterization of colloid-contaminant-soil interactions and colloid-facili\\-tated transport for clean-up procedures and long-term risk assessment. We have previously shown that upon contact with simulated waste tank solutions, Hanford sediments change their mineralogical composition. Certain minerals, i.e., quartz, smectite, and kaolinite, are partially dissolved, and new mineral phases, i.e., the feldspathoids cancrinite and sodalite, are formed. We have characterized these mineral transformations and clarified the mineral transformation pathways. The new minerals were mainly in the colloidal size fraction (diameter less than 2 mum), had a negative surface charge, and were microporous, meaning they contained small pores. When Cs was present during the formation of the minerals, contaminants, like Cs, could be trapped inside the mineral structure. Transport experiments under water saturated and unsaturated conditions showed that the colloids were mobile in Hanford sediments. As the water saturation of the sediments decreased, the amount of colloids transported also decreased. The colloids had the ability to enhance the migration of the radionuclide Cs; however, Cs initially sorbed to colloids was desorbed during transport through uncontaminated Hanford sediments. The finding that Cs was stripped off the colloids during the transport through uncontaminated sediments implies that colloids will likely not be an effective carrier for Cs, unless the Cs is incorporated into the mineral structure of the colloids such that the radionuclide cannot desorb from the colloids. Nevertheless, it appears that the amount of Cs that can be transported by mobile colloids beneath Hanford waste tanks is limited. Colloids will not be able to move the bulk mass of Cs through the vadose zone at Hanford. Colloid stability studies indicate that Hanford sediment form stable colloidal suspensions when suspended in Hanford sediment pore waters. Colloid stability was assessed by determination of the critical coagulation concentration, i.e., the chemical electrolyte concentration at which colloidal suspensions flocculate and settle out (become unstable). Although in the stable mode, Hanford colloids will settle out of solution after extended periods of time (months to years). Given the low recharge rates at Hanford range, which from near 0 to more than 100 mm/year, and the long travel times for rainwater to reach the groundwater of more than 40 years, it appears that colloidal transport is unlikely to occur if colloids are initially to be suspended close to the soil surface by infiltrating rainwater. However, if preferential flow or transient flow occurs, then colloidal transport may become more important. The results of this project have also led to improvements of our fundamental understanding of colloid transport and mobilization under unsaturated flow conditions in porous media. We have found that colloid attachment to the liquid-gas interface is not that relevant and that colloids rather attached near the triple phase interface where air, water, and solid phases meet. We have also found that capillary forces are the most dominant forces governing

Markus Flury; James B. Harsh; John F. McCarthy; Peter C. Lichtner; John M. Zachara

2006-11-21T23:59:59.000Z

54

Colloid-Facilitated Transport of Radionuclides through the Vadose Zone  

Science Conference Proceedings (OSTI)

The main purpose of this project was to advance the basic scientific understanding of colloid and colloid-facilitated Cs transport of radionuclides in the vadose zone. We focused our research on the hydrological and geochemical conditions beneath the leaking waste tanks at the USDOE Hanford reservation. Specific objectives were (1) to determine the lability and thermodynamic stability of colloidal materials, which form after reacting Hanford sediments with simulated Hanford Tank Waste, (2) to characterize the interactions between colloidal particles and contaminants, i.e., Cs and Eu, (3) to determine the potential of Hanford sediments for \\textit{in situ} mobilization of colloids, (4) to evaluate colloid-facilitated radionuclide transport through sediments under unsaturated flow, (5) to implement colloid-facilitated contaminant transport mechanisms into a transport model, and (6) to improve conceptual characterization of colloid-contaminant-soil interactions and colloid-facili\\-tated transport for clean-up procedures and long-term risk assessment. We have previously shown that upon contact with simulated waste tank solutions, Hanford sediments change their mineralogical composition. Certain minerals, i.e., quartz, smectite, and kaolinite, are partially dissolved, and new mineral phases, i.e., the feldspathoids cancrinite and sodalite, are formed. We have characterized these mineral transformations and clarified the mineral transformation pathways. The new minerals were mainly in the colloidal size fraction (diameter less than 2 mum), had a negative surface charge, and were microporous, meaning they contained small pores. When Cs was present during the formation of the minerals, contaminants, like Cs, could be trapped inside the mineral structure. Transport experiments under water saturated and unsaturated conditions showed that the colloids were mobile in Hanford sediments. As the water saturation of the sediments decreased, the amount of colloids transported also decreased. The colloids had the ability to enhance the migration of the radionuclide Cs; however, Cs initially sorbed to colloids was desorbed during transport through uncontaminated Hanford sediments. The finding that Cs was stripped off the colloids during the transport through uncontaminated sediments implies that colloids will likely not be an effective carrier for Cs, unless the Cs is incorporated into the mineral structure of the colloids such that the radionuclide cannot desorb from the colloids. Nevertheless, it appears that the amount of Cs that can be transported by mobile colloids beneath Hanford waste tanks is limited. Colloids will not be able to move the bulk mass of Cs through the vadose zone at Hanford. Colloid stability studies indicate that Hanford sediment form stable colloidal suspensions when suspended in Hanford sediment pore waters. Colloid stability was assessed by determination of the critical coagulation concentration, i.e., the chemical electrolyte concentration at which colloidal suspensions flocculate and settle out (become unstable). Although in the stable mode, Hanford colloids will settle out of solution after extended periods of time (months to years). Given the low recharge rates at Hanford range, which from near 0 to more than 100 mm/year, and the long travel times for rainwater to reach the groundwater of more than 40 years, it appears that colloidal transport is unlikely to occur if colloids are initially to be suspended close to the soil surface by infiltrating rainwater. However, if preferential flow or transient flow occurs, then colloidal transport may become more important. The results of this project have also led to improvements of our fundamental understanding of colloid transport and mobilization under unsaturated flow conditions in porous media. We have found that colloid attachment to the liquid-gas interface is not that relevant and that colloids rather attached near the triple phase interface where air, water, and solid phases meet. We have also found that capillary forces are the most dominant forces governing

Markus Flury; James B. Harsh; John F. McCarthy; Peter C. Lichtner; John M. Zachara

2006-11-21T23:59:59.000Z

55

Vadose zone characterization project at the Hanford Tank Farms: BY Tank Farm report  

SciTech Connect

The US Department of Energy Grand Junction Office (GJO) was tasked by the DOE Richland Operations Office (DOE-RL) to perform a baseline characterization of the contamination distributed in the vadoze zone sediment beneath and around the single-shell tanks (SSTs) at the Hanford Site. The intent of this characterization is to determine the nature and extent of the contamination, to identify contamination sources, and to develop a baseline of the contamination distribution that will permit future data comparisons. This characterization work also allows an initial assessment of the impacts of the vadose zone contamination as required by the Resource Conservation and Recovery Act (RCRA). This characterization project involves acquiring information about the vadose zone contamination with borehole geophysical logging methods and documenting that information in a series of reports. Data from boreholes surrounding each tank are compiled into individual Tank Summary Data Reports. The data from each tank farm are then compiled and summarized in a Tank Farm Report. This document is the Tank Farm Report for the BY Tank Farm.

Kos, S.E.

1997-02-01T23:59:59.000Z

56

DEEP VADOSE ZONE APPLIED FIELD RESEARCH CENTER: TRANSFORMATIONAL TECHNOLOGY DEVELOPMENT FOR ENVIRONMENTAL REMEDIATION  

SciTech Connect

DOE-EM, Office of Groundwater and Soil Remediation and DOE Richland, in collaboration with the Hanford site and Pacific Northwest National Laboratory, have established the Deep Vadose Zone Applied Field Research Center (DVZ-AFRC). The DVZ-AFRC leverages DOE investments in basic science from the Office of Science, applied research from DOE EM Office of Technology Innovation and Development, and site operation (e.g., site contractors [CH2M HILL Plateau Remediation Contractor and Washington River Protection Solutions], DOE-EM RL and ORP) in a collaborative effort to address the complex region of the deep vadose zone. Although the aim, goal, motivation, and contractual obligation of each organization is different, the integration of these activities into the framework of the DVZ-AFRC brings the resources and creativity of many to provide sites with viable alternative remedial strategies to current baseline approaches for persistent contaminants and deep vadose zone contamination. This cooperative strategy removes stove pipes, prevents duplication of efforts, maximizes resources, and facilitates development of the scientific foundation needed to make sound and defensible remedial decisions that will successfully meet the target cleanup goals for one of DOE EM's most intractable problems, in a manner that is acceptable by regulators.

Wellman, Dawn M.; Triplett, Mark B.; Freshley, Mark D.; Truex, Michael J.; Gephart, Roy E.; Johnson, Timothy C.; Chronister, Glen B.; Gerdes, Kurt D.; Chamberlain, Skip; Marble, Justin; Ramirez, Rosa

2011-02-27T23:59:59.000Z

57

Vadose Zone Transport Field Study: Detailed Test Plan for Simulated Leak Tests  

Science Conference Proceedings (OSTI)

This report describes controlled transport experiments at well-instrumented field tests to be conducted during FY 2000 in support of DOE?s Vadose Zone Transport Field Study (VZTFS). The VZTFS supports the Groundwater/Vadose Zone Integration Project Science and Technology Initiative. The field tests will improve understanding of field-scale transport and lead to the development or identification of efficient and cost-effective characterization methods. These methods will capture the extent of contaminant plumes using existing steel-cased boreholes. Specific objectives are to 1) identify mechanisms controlling transport processes in soils typical of the hydrogeologic conditions of Hanford?s waste disposal sites; 2) reduce uncertainty in conceptual models; 3) develop a detailed and accurate data base of hydraulic and transport parameters for validation of three-dimensional numerical models; and 4) identify and evaluate advanced, cost-effective characterization methods with the potential to assess changing conditions in the vadose zone, particularly as surrogates of currently undetectable high-risk contaminants. Pacific Northwest National Laboratory (PNNL) manages the VZTFS for DOE.

Ward, Anderson L.; Gee, Glendon W.

2000-06-23T23:59:59.000Z

58

Experimental and Numerical Investigations of Soil Desiccation for Vadose Zone Remediation: Report for Fiscal Year 2007  

SciTech Connect

Apart from source excavation, the options available for the remediation of vadose zone metal and radionuclide contaminants beyond the practical excavation depth (0 to 15 m) are quite limited. Of the available technologies, very few are applicable to the deep vadose zone with the top-ranked candidate being soil desiccation. An expert panel review of the work on infiltration control and supplemental technologies identified a number of knowledge gaps that would need to be overcome before soil desiccation could be deployed. The report documents some of the research conducted in the last year to fill these knowledge gaps. This work included 1) performing intermediate-scale laboratory flow cell experiments to demonstrate the desiccation process, 2) implementing a scalable version of Subsurface Transport Over Multiple Phases–Water-Air-Energy (STOMP-WAE), and 3) performing numerical experiments to identify the factors controlling the performance of a desiccation system.

Ward, Andy L.; Oostrom, Mart; Bacon, Diana H.

2008-02-04T23:59:59.000Z

59

Characterization of Vadose Zone Sediments from C Waste Management Area: Investigation of the C-152 Transfer Line Leak  

Science Conference Proceedings (OSTI)

The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in January 2007. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc., tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within waste management area (WMA) C. Specifically, this report contains all the geologic, geochemical, and selected physiochemical characterization data compiled on vadose zone sediment recovered from direct-push samples collected around the site of an unplanned release (UPR), UPR-200-E-82, adjacent to the 241-C-152 Diversion Box located in WMA C.

Brown, Christopher F.; Serne, R. Jeffrey; Bjornstad, Bruce N.; Valenta, Michelle M.; Lanigan, David C.; Vickerman, Tanya S.; Clayton, Ray E.; Geiszler, Keith N.; Iovin, Cristian; Clayton, Eric T.; Kutnyakov, Igor V.; Baum, Steven R.; Lindberg, Michael J.; Orr, Robert D.

2008-09-11T23:59:59.000Z

60

Vadose zone characterization project at the Hanford Tank Farms: U Tank Farm Report  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy Grand Junction Office (DOE-GJO) was tasked by the DOE Richland Operations Office (DOE-RL) to perform a baseline characterization of the gamma-ray-emitting radionuclides that are distributed in the vadose zone sediments beneath and around the single-shell tanks (SSTs) at the Hanford Site. The intent of this characterization is to determine the nature and extent of the contamination, to identify contamination sources when possible, and to develop a baseline of the contamination distribution that will permit future data comparisons. This characterization work also allows an initial assessment of the impacts of the vadose zone contamination as required by the Resource Conservation and Recovery Act (RCRA). This characterization project involves acquiring information regarding vadose zone contamination with borehole geophysical logging methods and documenting that information in a series of reports. This information is presently limited to detection of gamma-emitting radionuclides from both natural and man-made sources. Data from boreholes surrounding each tank are compiled into individual Tank Summary Data Reports. The data from each tank in a tank farm are then compiled and summarized in a Tank Farm Report. This document is the Tank Farm Report for the U Tank Farm. Logging operations used high-purity germanium detection systems to acquire laboratory-quality assays of the gamma-emitting radionuclides in the sediments around and below the tanks. These assays were acquired in 59 boreholes that surround the U Tank Farm tanks. Logging of all boreholes was completed in December 1995, and the last Tank Summary Data Report for the U Tank Farm was issued in September 1996.

NONE

1997-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Simulations of Groundwater Flow and Radionuclide Transport in the Vadose and Saturated Zones beneath Area G, Los Alamos National Laboratory  

Science Conference Proceedings (OSTI)

Numerical simulations are used to predict the migration of radionuclides from the disposal units at Material Disposal Area G through the vadose zone and into the main aquifer in support of a radiological performance assessment and composite analysis for the site. The calculations are performed with the finite element code, FEHM. The transport of nuclides through the vadose zone is computed using a three-dimensional model that describes the complex mesa top geology of the site. The model incorporates the positions and inventories of thirty-four disposal pits and four shaft fields located at Area G as well as those of proposed future pits and shafts. Only three nuclides, C-14, Tc-99, and I-129, proved to be of concern for the groundwater pathway over a 10,000-year period. The spatial and temporal flux of these three nuclides from the vadose zone is applied as a source term for the three-dimensional saturated zone model of the main aquifer that underlies the site. The movement of these nuclides in the aquifer to a downstream location is calculated, and aquifer concentrations are converted to doses. Doses related to aquifer concentrations are six or more orders of magnitude lower than allowable Department of Energy performance objectives for low-level radioactive waste sites. Numerical studies were used to better understand vadose-zone flow through the dry mesa-top environment at Area G. These studies helped define the final model used to model flow and transport through the vadose zone. The study of transient percolation indicates that a steady flow vadose-zone model is adequate for computing contaminant flux to the aquifer. The fracture flow studies and the investigation of the effect of basalt and pumice properties helped us define appropriate hydrologic properties for the modeling. Finally, the evaporation study helped to justify low infiltration rates.

Kay H. Birdsell; Kathleen M. Bower; Andrew V. Wolfsberg; Wendy E. Soll; Terry A. Cherry; Tade W. Orr

1999-07-01T23:59:59.000Z

62

Potential for Microbial Stimulation in Deep Vadose Zone Sediments by Gas-Phase Nutrients  

Science Conference Proceedings (OSTI)

Viable microbial populations are low, typically 10{sup 4} cells per gram, in deep vadose zones in arid climates. There is evidence that microbial distribution in these environments is patchy. In addition, infiltration or injection of nutrient-laden water has the potential to spread and drive contaminants downward to the saturated zone. For these reasons, there are uncertainties regarding the feasibility of bioremediation of recalcitrant contaminants in deep vadose zones. The objectives of this study were to investigate the occurrence of denitrifying activity and gaseous carbon-utilizing activity in arid-climate deep vadose zone sediments contaminated with, and/or affected by past exposure to, carbon tetrachloride (CT). These metabolisms are known to degrade CT and/or its breakdown product chloroform under anoxic conditions. A second objective was to determine if CT would be degraded in these sediments under unsaturated, bulk-phase aerobic incubation conditions. Both denitrifier population (determined by MPN) and microbial heterotrophic activity (measured by mineralization of 14-C labeled glucose and acetate) were relatively low and the sediments with greater in situ moisture (10-21% versus 2-7%) tended to have higher activities. When sediments were amended with gaseous nutrients (nitrous oxide and triethyl/tributyl phosphate) and gaseous C sources (a mixture of methane, ethane, propylene, propane, and butane) and incubated for 6 months, approximately 50% of the samples showed removal of one or more gaseous C sources, with butane most commonly used (44% of samples), followed by propylene (42%), propane (31%), ethane (22%), and methane (4%). Gaseous N and gaseous P did not stimulate removal of gaseous C substrates compared to no addition of N and P. CT and gaseous C sources were spiked into the sediments that removed gaseous C sources to determine if hydrocarbon-degraders have the potential to degrade CT under unsaturated conditions. In summary, gaseous C sources--particularly butane and propylene--have promise for increasing the numbers and activity of indigenous microbial populations in arid-climate deep vadose zone sediments.

Li, S.W.; Plymale, A. E.; Brockman, F.J.

2006-04-05T23:59:59.000Z

63

A Hybrid Hydrologic-Geophysical Inverse Technique for the Assessment and Monitoring of Leachates in the Vadose Zone  

SciTech Connect

The objective of this study is to develop and field test a new, integrated Hybrid Hydrologic-Geophysical Inverse Technique (HHGIT) for characterization of the vadose zone at contaminated sites. This new approach to site characterization and monitoring can provide detailed maps of hydrogeological heterogeneity and the extent of contamination by combining information from 3D electric resistivity tomography (ERT) and/or 2D cross borehole ground penetrating radar (XBGPR) surveys, statistical information about heterogeneity and hydrologic processes, and sparse hydrologic data. Because the electrical conductivity and dielectric constant of the vadose zone (from the ERT and XBGPR measurements, respectively) can be correlated to the fluid saturation and/or contaminant concentration, the hydrologic and geophysical measurements are related.

ALUMBAUGH,DAVID L.; YEH,JIM; LABRECQUE,DOUG; GLASS,ROBERT J.; BRAINARD,JAMES; RAUTMAN,CHRIS

1999-06-15T23:59:59.000Z

64

Perface: Research advances in vadose zone hydrology throughsimulations with the TOUGH codes  

DOE Green Energy (OSTI)

Numerical simulators are playing an increasingly important role in advancing our fundamental understanding of hydrological systems. They are indispensable tools for managing groundwater resources, analyzing proposed and actual remediation activities at contaminated sites, optimizing recovery of oil, gas, and geothermal energy, evaluating subsurface structures and mining activities, designing monitoring systems, assessing the long-term impacts of chemical and nuclear waste disposal, and devising improved irrigation and drainage practices in agricultural areas, among many other applications. The complexity of subsurface hydrology in the vadose zone calls for sophisticated modeling codes capable of handling the strong nonlinearities involved, the interactions of coupled physical, chemical and biological processes, and the multiscale heterogeneities inherent in such systems. The papers in this special section of ''Vadose Zone Journal'' are illustrative of the enormous potential of such numerical simulators as applied to the vadose zone. The papers describe recent developments and applications of one particular set of codes, the TOUGH family of codes, as applied to nonisothermal flow and transport in heterogeneous porous and fractured media (http://www-esd.lbl.gov/TOUGH2). The contributions were selected from presentations given at the TOUGH Symposium 2003, which brought together developers and users of the TOUGH codes at the Lawrence Berkeley National Laboratory (LBNL) in Berkeley, California, for three days of information exchange in May 2003 (http://www-esd.lbl.gov/TOUGHsymposium). The papers presented at the symposium covered a wide range of topics, including geothermal reservoir engineering, fracture flow and vadose zone hydrology, nuclear waste disposal, mining engineering, reactive chemical transport, environmental remediation, and gas transport. This Special Section of ''Vadose Zone Journal'' contains revised and expanded versions of selected papers from the symposium, with special attention to issues related to the vadose zone and unsaturated flow systems. The first paper, written by the original developer of TOUGH, Karsten Pruess, provides an overview of the history of the TOUGH codes, the main physical processes considered, their mathematical and numerical implementation, and case studies. That paper is followed by a review article summarizing inverse modeling applications performed by iTOUGH2. A subsequent group of papers deals with diverse unsaturated zone systems, highlighting the versatility of the code to handle a variety of processes in different geologic settings. Simulation capabilities of the TOUGH codes are increasingly used for geologic carbon sequestration studies as testified by the next group of papers. The final series of papers demonstrates the use of the TOUGH codes in support of remediation and engineering applications. These studies discuss biological and reactive chemical transport simulations, the design of clean-up operations and landfill management, and the analysis of engineered soil stabilization. As guest editors, we thank the authors for their interesting contributions, and the many reviewers for their careful and constructive review comments. Finally, on behalf of all of the authors and ourselves, we express our sincerest appreciation to Rien van Genuchten for providing the opportunity to publish these papers together in a Special Section of ''Vadose Zone Journal''.

Finsterle, Stefan; Oldenburg, Curtis M.

2004-07-12T23:59:59.000Z

65

DE FG02-06ER64193: Final Technical Report Nucleation and Precipitation Processes in the Vadose Zone during Contaminant Transport  

SciTech Connect

The report describes results of experiments to synthesize and characterize uranium(VI)-silicates from solutions containing dissolved U(VI), Si, Na, and nitrate as a function of solution pH and Si:U ratio under ambient conditions. Solids characterization was accomplished by X-ray diffraction, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and high-energy X-ray scattering (HEXS) analysis. The purpose was to develop a framework for describing the formation of U(VI)-silicate solids that might form in contaminated soils and sediments under oxidizing conditions in the presence of aqueous uranium, and are known to exist naturally in geologic uranium deposits.

Kathryn L. Nagy

2012-07-06T23:59:59.000Z

66

Effects of Porous Medium Heterogeneity on Vadose Zone Desiccation: Intermediate-scale Laboratory Experiments and Simulations  

Science Conference Proceedings (OSTI)

Soil desiccation (drying), involving water evaporation induced by dry gas injection, is a potentially robust vadose zone remediation process to limit contaminant transport through the vadose zone. A series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media. The permeability ratios of porous medium layers ranged from about five to almost two orders of magnitude. The insulated flow cell was equipped with twenty humidity and temperature sensors and a dual-energy gamma system was used to determine water saturations at various times. The multiphase code STOMP was used to simulate the desiccation process. Results show that injected dry gas flowed predominantly in the higher permeability layer and delayed water removal from the lower permeability material. For the configurations tested, water vapor diffusion from the lower to the higher permeability zone was considerable over the duration of the experiments, resulting in much larger relative humidity values of the outgoing air than based on permeability ratios alone. Acceptable numerical matches with the experimental data were obtained when an extension of the saturation-capillary pressure relation below the residual water saturation was used. The agreements between numerical and experimental results suggest that the correct physics are implemented in the simulator and that the thermal and hydraulic properties of the porous media, flow cell wall and insulation materials were properly represented.

Oostrom, Martinus; Freedman, Vicky L.; Wietsma, Thomas W.; Dane, Jacob H.; Truex, Michael J.

2012-11-01T23:59:59.000Z

67

An Experimental Study of Diffusivity of Technetium-99 in Hanford Vadose Zone Sediments  

Science Conference Proceedings (OSTI)

One of the methods being considered at the Hanford site in Washington for safely disposing of low-level radioactive wastes (LLW) is to encase the waste in concrete and entomb the packages in the Hanford vadose zone sediments. The current plan for waste isolation consists of stacking low-level waste packages on a trench floor, surrounding the stacks with reinforced steel, and encasing these packages with concrete. Any failure of the concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The mobilized radionuclides may escape from the encased concrete by mass flow and/or diffusion and move into the surrounding subsurface sediments. It is therefore necessary to conduct an assessment of the performance of the concrete encasement structure and the surrounding soil’s ability to retard radionuclide migration. The retardation factors for radionuclides contained in the waste packages can be determined from measurements of diffusion coefficients for these contaminants through concrete and fill material. Because of their anionic nature in aqueous solutions, the radionuclides, 99Tc and 129I were identified as long-term dose contributors in LLW. The leachability and/or diffusion of these radionuclide species must be measured in order to assess the long-term performance of waste grouts when contacted with vadose-zone porewater or groundwater. To measure the diffusivity, a set of experiments were conducted using 99Tc-spiked concrete (with 0 and 4% metallic iron additions) in contact with unsaturated soil half-cells that reflected the typical moisture contents of Hanford vadose zone sediments. The 99Tc diffusion profiles in the soil half cells were measured after a time lapse of ~1.9 yr. Using the concentration profiles, the 99Tc diffusivity coefficients were calculated based on Fick’s Second Law.

Mattigod, Shas V.; Bovaird, Chase C.; Wellman, Dawn M.; Parker, Kent E.; Wood, Marcus I.

2012-11-01T23:59:59.000Z

68

Implementation Plan for the Deep Vadose Zone-Applied Field Research Center  

SciTech Connect

The Long-Range Deep Vadose Zone Program Plan was published in October 2010. It summarized the U.S. Department of Energy’s (DOE’s) state-of-knowledge about the contaminant remediation challenges facing the deep vadose zone (DVZ) beneath the Central Plateau of the Hanford Site and their approach to solving those challenges. Developing an implementation plan is the next step to address the knowledge and capabilities required to solve DVZ challenges when needed. This multi-year plan (FY-11 through FY-20) identifies the short to long-term research, management, and execution plans required to solve those problems facing the DVZ-Applied Field Research Center (DVZ-AFRC). The schedule supporting implementation overlies existing activities and milestones from Hanford’s DOE-Environmental Management (EM) end-user projects. Success relies upon multi-project teams focused on coordinated subsurface projects undertaken across the DOE Complex combined with facilitated, problem-focused, research investments implemented through the DVZ-AFRC.

Wellman, Dawn M.; Truex, Michael J.; Freshley, Mark D.; Gephart, Roy E.; Triplett, Mark B.; Johnson, Timothy C.

2011-02-11T23:59:59.000Z

69

Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Soil Desiccation Pilot Test Results  

Science Conference Proceedings (OSTI)

This report describes results of a pilot test of soil desiccation conducted as part of the Deep Vadose Zone Treatability Test program. The report is written in CERCLA treatabilty test report format.

Truex, Michael J.; Oostrom, Martinus; Strickland, Christopher E.; Johnson, Timothy C.; Freedman, Vicky L.; Johnson, Christian D.; Greenwood, William J.; Ward, Anderson L.; Clayton, Ray E.; Lindberg, Michael J.; Peterson, John E.; Hubbard, Susan; Chronister, Glen B.; Benecke, Mark W.

2012-05-01T23:59:59.000Z

70

Characterization of Vadose Zone Sediments Below the C Tank Farm: Borehole C4297 and RCRA Borehole 299-E27-22  

SciTech Connect

This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.7 and 4.25. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in September 2006. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at the Hanford Site. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory (PNNL) to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) C. This report is the first of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physiochemical characterization data collected on vadose zone sediment recovered from borehole C4297, installed adjacent to tank C-105, and from borehole 299-E27-22, installed directly north of the C Tank Farm. This report also presents the interpretation of data in the context of sediment types, the vertical extent of contamination, the migration potential of the contaminants, and the likely source of the contamination in the vadose zone below the C Tank Farm. The information presented in this report supports the WMA A-AX, C, and U field investigation report in preparation by CH2M HILL Hanford Group, Inc.

Brown, Christopher F.; Serne, R. Jeffrey; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Clayton, Ray E.; Valenta, Michelle M.; Vickerman, Tanya S.; Kutnyakov, Igor V.; Geiszler, Keith N.; Baum, Steven R.; Parker, Kent E.; Lindberg, Michael J.

2008-09-11T23:59:59.000Z

71

Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site  

SciTech Connect

This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan; Krupka, Kenneth M.; Serne, R. Jeffrey

2007-09-28T23:59:59.000Z

72

Characterization of Vadose Zone Sediment: Borehole 299-E33-45 Near BX-102 in the B-BX-BY Waste Management Area  

Science Conference Proceedings (OSTI)

This report was revised in September 2008 to remove acid-extractable sodium data from Table 4.22. The data was removed due to potential contamination introduced during the acid extraction process. The remaining text is unchanged from the original report issued in 2002. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities. To meet this goal, CH2M HILL Hanford Group, Inc., asked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area B-BX-BY. This report is the first in a series of four reports to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from borehole 299-E33-45 installed northeast of tank BX-102.

Serne, R. Jeffrey; Last, George V.; Gee, Glendon W.; Schaef, Herbert T.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Orr, Robert D.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Brown, Christopher F.; Valenta, Michelle M.; Vickerman, Tanya S.

2008-09-11T23:59:59.000Z

73

T-TY Tank Farm Interim Surface Barrier Demonstration—Vadose Zone Monitoring Plan  

SciTech Connect

The Hanford Site has 149 underground single-shell tanks that store hazardous radioactive waste. Many of these tanks and their associated infrastructure (e.g., pipelines, diversion boxes) have leaked. Some of the leaked waste has entered the groundwater. The largest known leak occurred from the T-106 Tank of the 241-T Tank Farm in 1973. Five tanks are assumed to have leaked in the TY Farm. Many of the contaminants from those leaks still reside within the vadose zone within the T and TY Tank Farms. The Department of Energy’s Office of River Protection seeks to minimize the movement of these contaminant plumes by placing interim barriers on the ground surface. Such barriers are expected to prevent infiltrating water from reaching the plumes and moving them further. The soil water regime is monitored to determine the effectiveness of the interim surface barriers. Soil-water content and water pressure are monitored using off-the-shelf equipment that can be installed by the hydraulic hammer technique. Four instrument nests were installed in the T Farm in fiscal year (FY) 2006 and FY2007; two nests were installed in the TY Farm in FY2010. Each instrument nest contains a neutron probe access tube, a capacitance probe, and four heat-dissipation units. A meteorological station has been installed at the north side of the fence of the T Farm. This document summarizes the monitoring methods, the instrument calibration and installation, and the vadose zone monitoring plan for interim barriers in T farm and TY Farm.

Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

2010-09-27T23:59:59.000Z

74

Characterization of Vadose Zone Sediment: Slant Borehole SX-108 in the S-SX Waste Management Area  

Science Conference Proceedings (OSTI)

This report was revised in September 2008 to remove acid-extractable sodium data from Table 4.17. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in February 2002. The overall goal of the of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities. To meet this goal, CH2M HILL Hanford Group, Inc., asked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediment from within the S-SX Waste Management Area. This report is the fourth in a series of four reports to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from a slant borehole installed beneath tank SX-108 (or simply SX-108 slant borehole).

Serne, R. Jeffrey; Last, George V.; Schaef, Herbert T.; Lanigan, David C.; Lindenmeier, Clark W.; Ainsworth, Calvin C.; Clayton, Ray E.; Legore, Virginia L.; O'Hara, Matthew J.; Brown, Christopher F.; Orr, Robert D.; Kutnyakov, Igor V.; Wilson, Teresa C.; Wagnon, Kenneth B.; Williams, Bruce A.; Burke, Deborah S.

2008-09-11T23:59:59.000Z

75

Characterization of Vadose Zone Sediment: Borehole 41-09-39 in the S-SX Waste Management Area  

Science Conference Proceedings (OSTI)

This report was revised in September 2008 to remove acid-extractable sodium data from Table 5.15. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in February 2002. The overall goal of the of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities. To meet this goal, CH2M HILL Hanford Group, Inc., asked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediment from within the S-SX Waste Management Area. This report is one in a series of four reports to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from borehole 41-09-39 installed adjacent to tank SX-109.

Serne, R. Jeffrey; Last, George V.; Schaef, Herbert T.; Lanigan, David C.; Lindenmeier, Clark W.; Ainsworth, Calvin C.; Clayton, Ray E.; Legore, Virginia L.; O'Hara, Matthew J.; Brown, Christopher F.; Orr, Robert D.; Kutnyakov, Igor V.; Wilson, Teresa C.; Wagnon, Kenneth B.; Williams, Bruce A.; Burke, Deborah S.

2008-09-11T23:59:59.000Z

76

Evaluation of In Situ Grouting as a Potential Remediation Method for the Hanford Central Plateau Deep Vadose Zone  

SciTech Connect

The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau report identifies in situ grouting as a potential remediation technology for the deep vadose zone and includes a planned effort to evaluate in situ grouting to provide information for future feasibility studies. This report represents the first step in this evaluation effort.

Truex, Michael J.; Pierce, Eric M.; Nimmons, Michael J.; Mattigod, Shas V.

2011-01-11T23:59:59.000Z

77

The impact of climate change on vadose zone pore waters and its implication for long-term monitoring  

Science Conference Proceedings (OSTI)

Protecting groundwater is of growing interest as pressure on these resources grows. Recharge of groundwater takes place through the vadose zone, where complex interactions between thermal-hydrological-geochemical processes affect water quality. Monitoring ... Keywords: climate change, massively parallel computers, monitoring, nuclear waste disposal, pore water chemistry, reactive transport, vadose zone

William E. Glassley; John J. Nitao; Charles W. Grant; James W. Johnson; Carl I. Steefel; James R. Kercher

2003-04-01T23:59:59.000Z

78

Perched-Water Evaluation for the Deep Vadose Zone Beneath the B, BX, and BY Tank Farms Area of the Hanford Site  

SciTech Connect

Perched-water conditions have been observed in the vadose zone above a fine-grained zone that is located a few meters above the water table within the B, BX, and BY Tank Farms area. The perched water contains elevated concentrations of uranium and technetium-99. This perched-water zone is important to consider in evaluating the future flux of contaminated water into the groundwater. The study described in this report was conducted to examine the perched-water conditions and quantitatively evaluate 1) factors that control perching behavior, 2) contaminant flux toward groundwater, and 3) associated groundwater impact.

Truex, Michael J.; Oostrom, Martinus; Carroll, KC; Chronister, Glen B.

2013-06-28T23:59:59.000Z

79

Rate-limited U(VI) desorption during a small-scale tracer test in a hetereogeneous uranium contaminated aquifer  

E-Print Network (OSTI)

of Contaminants in the Hanford Vadose Zone, Vadose Zone J. ,transport in a contaminated Hanford sediment, Environ. Sci.of U(VI) observed in Hanford sediment column experiments. A

Fox, P.M.

2013-01-01T23:59:59.000Z

80

Characterization of Vadose Zone Sediments Below the TX Tank Farm: Probe Holes C3830, C3831, C3832 and 299-W10-27  

Science Conference Proceedings (OSTI)

Pacific Northwest National Laboratory performed detailed analyses on vadose zone sediments from within Waste Management Area T-TX-TY. This report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from three probe holes (C3830, C3831, and C3832) in the TX Tank Farm, and from borehole 299-W-10-27. Sediments from borehole 299-W-10-27 are considered to be uncontaminated sediments that can be compared with contaminated sediments. This report also presents our interpretation of the sediment lithologies, the vertical extent of contamination, the migration potential of the contaminants, and the likely source of the contamination in the vadose zone and groundwater below the TX Tank Farm. Sediment from the probe holes was analyzed for: moisture, radionuclide and carbon contents;, one-to-one water extracts (soil pH, electrical conductivity, cation, trace metal, and anion data), and 8 M nitric acid extracts. Overall, our analyses showed that common ion exchange is a key mechanism that influences the distribution of contaminants within that portion of the vadose zone affected by tank liquor. We did not observe significant indications of caustic alteration of the sediment mineralogy or porosity, or significant zones of slightly elevated pH values in the probe holes. The sediments do show that sodium-, nitrate-, and sulfate-dominated fluids are present. The fluids are more dilute than tank fluids observed below tanks at the SX and BX Tank Farms. Three primary stratigraphic units were encountered in each probe hole: (1) backfill material, (2) the Hanford formation, and (3) the Cold Creek unit. Each of the probe holes contain thin fine-grained layers in the Hanford H2 stratigraphic unit that may impact the flow of leaked fluids and effect irregular and horizontal flow. The probe holes could not penetrate below the enriched calcium carbonate strata of the Cold Creek lower subunit; therefore, we did not identify the maximum vertical penetration of the tank related plumes. However, the more elevated portions of the electrical conductivity (EC) profile at probe hole C3830 currently resides at the bottom of a fine-grained thin lens in the Hanford H2 unit at 87 ft bgs. At C3831, we lack good sample coverage to ascertain whether the salt plume has significantly descended into the Cold Creek Unit. There is strong indication at probe hole C3832 that the saline plume has descended into the Cold Creek Unit. The profiles do collectively suggest that the deepest penetration of tank related fluids is found in probe hole C3832. The water potential data from 299-W10-27?s H2 unit, the unit where most of the contaminants reside in the TX probe holes, are consistent with a draining profile. Despite the evidence that elevated EC values may be present in all three probe holes to their depth of refusal, the concentrations of long-term risk drivers are not large. The inventories of potential contaminants of concern, nitrate, technetium-99, uranium, and chromium, are provided. In addition, in situ desorption Kd values for these contaminants are provided. For conservative modeling purposes, we recommend using Kd values of 0 mL/g for nitrate and technetium-99, a value of 1 mL/g for uranium, and 10 mL/g for chromium to represent the entire vadose zone profile from the bottoms of the tanks to the water table. These conservative Kd values along with the provided inventories in the vadose zone sediments obtained from the three probe holes can be used in long-term risk projections that rely on estimates of water recharge and vadose zone and aquifer transport calculations.

Serne, R JEFFREY.; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; LeGore, Virginia L.; Orr, Robert D.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Valenta, Michelle M.; Vickerman, Tanya S.

2004-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

A Long-Term Strategic Plan for Hanford Sediment Physical Property and Vadose Zone Hydraulic Parameter Databases  

Science Conference Proceedings (OSTI)

Physical property data and unsaturated hydraulic parameters are critical input for analytic and numerical models used to predict transport and fate of contaminants in variably saturated porous media and to assess and execute remediation alternatives. The Remediation Decision Support (RDS) project, managed by the Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) and the CH2M Hill Plateau Remediation Company (CHPRC), has been compiling physical and hydraulic property data and parameters to support risk analyses and waste management decisions at Hanford. Efforts have been initiated to transfer sediment physical property data and vadose zone hydraulic parameters to CHPRC for inclusion in HEIS-Geo, a new instance of the Hanford Environmental Information System database that is being developed for borehole geologic data. This report describes these efforts and a strategic plan for continued updating and improvement of these datasets.

Rockhold, Mark L.; Last, George V.; Middleton, Lisa A.

2009-09-30T23:59:59.000Z

82

Characterization of Vadose Zone Sediments Below the T Tank Farm: Boreholes C4104, C4105, 299-W10-196, and RCRA Borehole 299-W11-39  

Science Conference Proceedings (OSTI)

This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.8, 4.28, and 4.52. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in September 2004. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) T-TX-TY. This report is the second of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from boreholes C4104 and C4105 in the T Tank Farm, and from borehole 299-W-11-39 installed northeast of the T Tank Farm. Finally, the measurements on sediments from borehole C4104 are compared with a nearby borehole drilled in 1993, 299- W10-196, through the tank T-106 leak plume.

Serne, R. Jeffrey; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Schaef, Herbert T.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Geiszler, Keith N.; Baum, Steven R.; Valenta, Michelle M.; Kutnyakov, Igor V.; Vickerman, Tanya S.; Orr, Robert D.; Brown, Christopher F.

2008-09-11T23:59:59.000Z

83

Characterization of Vadose Zone Sediment: Borehole 299-E33-46 Near B 110 in the B BX-BY Waste Management Area  

SciTech Connect

This report was revised in September 2008 to remove acid-ectractable sodium data from Table 4.17. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in December 2002. The overall goal of the of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities. To meet this goal, CH2M HILL Hanford Group, Inc., asked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediment from within the B-BX-BY Waste Management Area. This report is the third in a series of three reports to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from a borehole installed approximately 4.5 m (15 ft) northeast of tank B- 110 (borehole 299-E33-46).

Serne, R. Jeffrey; Bjornstad, Bruce N.; Gee, Glendon W.; Schaef, Herbert T.; Lanigan, David C.; mccain, r. G.; Lindenmeier, Clark W.; Orr, Robert D.; Legore, Virginia L.; Clayton, Ray E.; Lindberg, Michael J.; Kutynakov, I. V.; Baum, Steven R.; Geiszler, Keith N.; Valenta, Michelle M.; Vickerman, Tanya S.; Royack, Lisa J.

2008-09-11T23:59:59.000Z

84

Characterization of Vadose Zone Sediments Below the TX Tank Farm: Boreholes C3830, C3831, C3832 and RCRA Borehole 299-W10-27  

Science Conference Proceedings (OSTI)

This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.8, 4.28,4.43, and 4.59. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in April 2004. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) T-TX-TY. This report is the first of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from boreholes C3830, C3831, and C3832 in the TX Tank Farm, and from borehole 299-W-10-27 installed northeast of the TY Tank Farm.

Serne, R. Jeffrey; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Orr, Robert D.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Valenta, Michelle M.; Vickerman, Tanya S.

2008-09-11T23:59:59.000Z

85

An Investigation of Linked Physical And Biogeochemical Processes In Heterogeneous Soils In The Vadose Zone  

E-Print Network (OSTI)

Chemical dynamics in the vadose zone are poorly understood due to the transient nature of chemical and hydrologic conditions, but are nonetheless critical to understanding contaminant fate and transport. This work explored the effects of soil structure (i.e. layers, lenses) on linked geochemical, hydrological, and microbiological processes under changing hydrologic conditions (e.g. rainfall, introduction of groundwater, and fluctuating water table heights). A homogenized medium-grained sand, homogenized organic-rich loam and a sand-over-loam layered column were constructed for the first series of experiments. The second series of experiments employed two soil columns with lenses that were packed identically with sterilized and untreated sediments. Each consisted of two lenses of organic-rich loam in a medium-grained sand matrix. Lenses were located at different vertical depths and were horizontally offset. In-situ collocated probes collected soil hydrologic and chemical data. In the layered column, enhanced biogeochemical cycling was observed over the texturally homogeneous soil columns. Enumerations of Fe(III) and SO42- reducing microorganisms also show 1-2 orders of magnitude greater community numbers in the layered column. The greatest concentrations of aqueous FeS clusters (FeSaq) were observed in close proximity to the soil interface. To our knowledge, this was the first documentation of FeSaq in partially saturated sediments. Mineral and soil aggregate composite layers were also most abundant near the soil layer interface; the presence of which, likely contributed to an order of magnitude decrease of hydraulic conductivity. In the live lens column, Fe-oxide bands formed at the fringes of the lenses that retarded water flow rates by an order of magnitude compared to the sterilized column. Microbial activity also produced insoluble gases and that led to the creation of a separate gas phase that reduced hydraulic conductivity. This limited the interaction between groundwater with soil-pore waters that led to the formation of geochemically distinct water masses in relatively close proximity to one another. No such changes were observed in the sterilized column. When compared to homogenous columns, the presence of soil heterogeneities altered biogeochemical and hydrologic processes considerably which highlights the need to consider soil heterogeneity in contaminant fate and transport models. These findings suggest that quantifying coupled hydrologic-biogeochemical processes occurring at small scale soil interfaces is critical to accurately describing and predicting chemical changes at the larger system scale.

Hansen, David Joseph

2011-08-01T23:59:59.000Z

86

Geophysical Monitoring of Foam used to Deliver Remediation Treatments within the Vadose Zone  

Science Conference Proceedings (OSTI)

Foam is a promising vehicle for delivering amendments into the vadose zone for in situ remediation; it is an approach being considered for in situ treatment and stabilization of metals and radionuclides located within the deep vadose zone of the Department of Energy (DOE) Hanford site, WA. A central aspect of evaluating the effectiveness of this approach is the ability to monitor foam distribution, its transformation, and the reactions that it induces in the subsurface, ideally in a non-invasive manner. In this study, we performed laboratory experiments to evaluate the potential of geophysical methods (complex resistivity and time domain reflectometry, TDR) as tools for monitoring foam assisted amendment delivery in the deep vadose zone. Our results indicated great sensitivity of electrical methods to foam transportation and evolution in unsaturated porous media that were related to foam bubble coalescence and drainage processes. Specifically, we observed (1) a decrease of electrical resistivity (increase of electrical conductivity) by over an order of magnitude in both silica sand and natural sediment matrices during foam transportation; (2) an increase of resistivity (decrease of conductivity) by over two fold during foam coalescence and drainage; (3) a distinct phase and imaginary conductivity signature related to the evolution of water films on sediment grains during foam injection and evolution processes. To assist with the interpretation of these data, TDR measurements were used to monitor moisture content, which provided complementary information about foam distribution and drainage. Our results clearly demonstrated the sensitivity of electrical and TDR signals to foam transportation and evolution in unsaturated porous media and suggested the potential of these methods for monitoring the response of a system to foam based remediation treatments at field scales.

Wu, Yuxin; Hubbard, Susan; Wellman, Dawn M.

2012-11-01T23:59:59.000Z

87

Characterization of Vadose Zone Sediments Below the C Tank Farm: Borehole C4297 and RCRA Borehole 299-E27-22  

SciTech Connect

The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) C. This report is the first of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from borehole C4297, installed adjacent to Tank C-105, and from borehole 299-E27-22, installed directly north of the C Tank Farm. Sediments from borehole 299-E27-22 were considered to be background uncontaminated sediments against which to compare contaminated sediments for the C Tank Farm characterization effort. This report also presents our interpretation of the data in the context of sediment types, the vertical extent of contamination, the migration potential of the contaminants, and the likely source of the contamination in the vadose zone and groundwater below the C Tank Farm. The information presented in this report supports the A-AX, C and U Waste Management Area field investigation report(a) in preparation by CH2M HILL Hanford Group, Inc. A core log was generated for both boreholes and a geologic evaluation of all core samples was performed at the time of opening. Aliquots of sediment from the borehole core samples were analyzed and characterized in the laboratory for the following parameters: moisture content, gamma-emitting radionuclides, one-to-one water extracts (which provide soil pH, electrical conductivity, cation, trace metal, and anion data), total carbon and inorganic carbon content, and 8 M nitric acid extracts (which provide a measure of the total leachable sediment content of contaminants). Two key radiocontaminants, technetium-99 and uranium-238, along with other trace metals were determined in acid and water extracts by inductively coupled plasma mass spectrometry.

Brown, Christopher F.; Serne, R. JEFFREY; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Clayton, Ray E.; Valenta, Michelle M.; Vickerman, Tanya S.; Kutnyakov, Igor V.; Geiszler, Keith N.; Baum, Steven R.; Parker, Kent E.; Lindberg, Michael J.

2006-10-18T23:59:59.000Z

88

Implementation of variably saturated flow into PHREEQC for the simulation of biogeochemical reactions in the vadose zone  

Science Conference Proceedings (OSTI)

A software tool for the simulation of one-dimensional unsaturated flow and solute transport together with biogeochemical reactions in the vadose zone was developed by integrating a numerical solution of Richards' equation into the geochemical modelling ... Keywords: Cation exchange, Geochemical modelling, Hydraulic properties, Reactive transport, Surface complexation, Unsaturated flow

L. Wissmeier; D. A. Barry

2010-04-01T23:59:59.000Z

89

EVALUATION OF A TECHNETIUM-99 DETECTOR BASED ON LABORATORY TESTING FOR USE IN IN-SITU VADOSE ZONE APPLICATIONS  

SciTech Connect

This document evaluates the feasibility of in-situ detection of technetium-99 in Hanford Site vadose zone soils (the soils between the surface and groundwater) using laboratory tests. The detector system performs adequately for high technetium concentration, but more development and laboratory testing is needed before field demonstration is performed.

MANN FM; MYERS DA

2009-09-11T23:59:59.000Z

90

Baseline mapping study of the Steed Pond aquifer and vadose zone beneath A/M Area, Savannah River Site, Aiken, South Carolina  

SciTech Connect

This report presents the second phase of a baseline mapping project conducted for the Environmental Restoration Department (ERD) at Savannah River Site. The purpose of this second phase is to map the structure and distribution of mud (clay and silt-sized sediment) within the vadose zone beneath A/M Area. The results presented in this report will assist future characterization and remediation activities in the vadose zone and upper aquifer zones in A/M Area.

Jackson, D.G. Jr.

2000-01-27T23:59:59.000Z

91

Characterization of Vadose Zone Sediment: RCRA Borehole 299-E33-338 Located Near the B-BX-BY Waste Management Area  

SciTech Connect

This report was revised in September 2008 to remove acid-extractable sodium data from Table 4.8. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in June 2003. The overall goals of the of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., are: 1) to define risks from past and future single-shell tank farm activities, 2) to identify and evaluate the efficacy of interim measures, and 3) to aid via collection of geotechnical information and data, future decisions that must be made by the U.S. Department of Energy (DOE) regarding the near-term operations, future waste retrieval, and final closure activities for the single-shell tank waste management areas. For a more complete discussion of the goals of the Tank Farm Vadose Zone Project, see the overall work plan, Phase 1 RCRA Facility Investigation/Corrective Measures Study Work Plan for the Single-Shell Tank Waste Management Areas (DOE 1999). Specific details on the rationale for activities performed at the B-BX-BY tank farm waste management area are found in CH2M HILL (2000).

Lindenmeier, Clark W.; Serne, R. Jeffrey; Bjornstad, Bruce N.; Gee, Glendon W.; Schaef, Herbert T.; Lanigan, David C.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Kutnyakov, Igor V.; Baum, Steven R.; Geiszler, Keith N.; Brown, Christopher F.; Valenta, Michelle M.; Vickerman, Tanya S.; Royack, Lisa J.

2008-09-11T23:59:59.000Z

92

Quantifying the effects of small-scale heterogeneities on fl ow and transport in undisturbed cores from the Hanford formation. Vadose Zone J  

E-Print Network (OSTI)

ABSTRACT more than 4 million liters of hazardous and radioactive Accelerated migration of contaminants in the vadose zone has waste in the vadose zone. Relatively mobile radionuclides such as 99Tc, 129I, U, and 3 been observed beneath tank farms at the U.S. Department of Energy’s H have traveled further Hanford Reservation, Richland, WA. This paper focuses on quantify- than predicted by current models and have been deing hydrologic processes that control the fate and transport of contami- tected in the groundwater, which eventually flows to nants in the unsaturated sediments beneath the Hanford tank farms. the Columbia River (Dirkes and Hanf, 1997; Hartman The experimental approach involved the use of field relevant, longterm unsaturated nonreactive transport experiments in undisturbed sediments from the Hanford Formation. Undisturbed sediment cores were collected from a laminated fine-grained sand unit within the Hanford Formation in both the vertical direction (flow cross bedding) and the horizontal direction (flow bedding parallel). Laboratory-scale saturated and unsaturated flow experiments were conducted using multiple nonreactive tracers to investigate hydrologic processes controlling

M. N. Pace; M. A. Mayes; P. M. Jardine; T. L. Mehlhorn; J. M. Zachara; B. N. Bjornstad

2004-01-01T23:59:59.000Z

93

T-TY Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY10 Report  

SciTech Connect

The U.S. Department of Energy’s Office of River Protection has constructed interim surface barriers over a portion of the T and TY tank farms as part of the Interim Surface Barrier Demonstration Project. The interim surface barriers (hereafter referred to as the surface barriers or barriers) are designed to minimize the infiltration of precipitation into the soil zones containing radioactive contaminants and minimize the movement of the contaminants. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barriers at reducing soil moisture. Solar-powered systems were installed to continuously monitor soil water conditions at four locations in the T (i.e., instrument Nests TA, TB, TC, and TD) and the TY (i.e., instrument Nests TYA and TYB) Farms beneath the barriers and outside the barrier footprint as well as site meteorological conditions. Nests TA and TYA are placed in the area outside the barrier footprint and serve as controls, providing subsurface conditions outside the influence of the surface barriers. Nest TB provides subsurface measurements to assess surface-barrier edge effects. Nests TC, TD, and TYB are used to assess changes in soil-moisture conditions beneath the interim surface barriers. Except for occasional times for TC and TD and planned dates for TYB, during FY10, the battery voltage at the TMS and instrument Nests in both T and TY tank farms remained above 12.0 V, denoting that the battery voltages were sufficient for the stations to remain functional. All the HDUs were functioning normally, but some pressure-head values were greater than the upper measurement limit. The values that exceeded the upper limit may indicate wet soil conditions and/or measurement error, but they do not imply a malfunction of the sensors. Similar to FY07 through FY09, in FY10, the soil under natural conditions in the T Farm (Nest TA) was generally recharged during the winter period (October–March), and they discharged during the summer period (April–September). Soil water conditions above about 1.5-m to 2-m depth from all three types of measurements (i.e., CP, NP, and HDU) showed relatively large variation during the seasonal wetting-drying cycle. For the soil below 2-m depth, the seasonal variation of soil water content was relatively small. The construction of the TISB was completed in April 2008. In the soil below the TISB (Nests TC and TD), the CP-measured water content showed that ? at the soil between 0.6-m and 2.3-m depths was stable, indicating no climatic impacts on soil water conditions beneath the barrier. The NP-measured water content in the soil between about 3.4 m (11 ft) and 12.2 m (40 ft) since the completion of the barrier decreased by 0.007 to 0.014 m3 m-3. The HDU-measured soil-water pressure at 1-m, 2-m, and 5-m depths decreased by 0.7 to 2.4 m, indicating soil water drainage at these depths of the soil. In the soil below the edge of the TISB (Nest TB), the CP-measured water content was relatively stable through the year; the NP-measured water content showed that soil water drainage was occurring in the soil between about 3.4 m (11 ft) and 12.2 m (40 ft) but at a slightly smaller magnitude than in Nests TC and TD; the HDU-measurements show that the pressure head changes at Nest TB since the completion of the barrier were generally less than those at TC and TD, but more than those at TA. These results indicate that the TISB is performing as expected by intercepting the meteoric water from infiltrating into the soil, and the soil is becoming drier gradually. The barrier also had some effects on the soil below the barrier edge, but at a reduced magnitude. There was no significant difference in soil-water regime between the two nests in the TY tank farm because the barrier at the TY Farm was just completed one month before the end of the FY.

Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

2011-01-24T23:59:59.000Z

94

Geochemical Characterization Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site  

SciTech Connect

This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank (SST) farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical information available for the vadose zone beneath the SST farms and the Integrated Disposal Facility (IDF).

Cantrell, Kirk J.; Brown, Christopher F.; Serne, R. Jeffrey; Krupka, Kenneth M.

2008-01-07T23:59:59.000Z

95

Remediation of Uranium in the Hanford Vadose Zone Using Gas-Transported Reactants: Laboratory Scale Experiments in Support of the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau  

Science Conference Proceedings (OSTI)

This laboratory-scale investigation is focused on decreasing mobility of uranium in subsurface contaminated sediments in the vadose zone by in situ geochemical manipulation at low water content. This geochemical manipulation of the sediment surface phases included reduction, pH change (acidic and alkaline), and additions of chemicals (phosphate, ferric iron) to form specific precipitates. Reactants were advected into 1-D columns packed with Hanford 200 area U-contaminated sediment as a reactive gas (for CO2, NH3, H2S, SO2), with a 0.1% water content mist (for NaOH, Fe(III), HCl, PO4) and with a 1% water content foam (for PO4). Uranium is present in the sediment in multiple phases that include (in decreasing mobility): aqueous U(VI) complexes, adsorbed U, reduced U(IV) precipitates, rind-carbonates, total carbonates, oxides, silicates, phosphates, and in vanadate minerals. Geochemical changes were evaluated in the ability to change the mixture of surface U phases to less mobile forms, as defined by a series of liquid extractions that dissolve progressively less soluble phases. Although liquid extractions provide some useful information as to the generalized uranium surface phases (and are considered operational definitions of extracted phases), positive identification (by x-ray diffraction, electron microprobe, other techniques) was also used to positively identify U phases and effects of treatment. Some of the changes in U mobility directly involve U phases, whereas other changes result in precipitate coatings on U surface phases. The long-term implication of the U surface phase changes to alter U mass mobility in the vadose zone was then investigated using simulations of 1-D infiltration and downward migration of six U phases to the water table. In terms of the short-term decrease in U mobility (in decreasing order), NH3, NaOH mist, CO2, HCl mist, and Fe(III) mist showed 20% to 35% change in U surface phases. Phosphate addition (mist or foam advected) showed inconsistent change in aqueous and adsorbed U, but significant coating (likely phosphates) on U-carbonates. The two reductive gas treatments (H2S and SO2) showed little change. For long-term decrease in U reduction, mineral phases created that had low solubility (phosphates, silicates) were desired, so NH3, phosphates (mist and foam delivered), and NaOH mist showed the greatest formation of these minerals. In addition, simulations showed the greatest decrease in U mass transport time to reach groundwater (and concentration) for these silicate/phosphate minerals. Advection of reactive gasses was the easiest to implement at the laboratory scale (and presumably field scale). Both mist and foam advection show promise and need further development, but current implementation move reactants shorter distances relative to reactive gasses. Overall, the ammonia and carbon dioxide gas had the greatest overall geochemical performance and ability to implement at field scale. Corresponding mist-delivered technologies (NaOH mist for ammonia and HCl mist for carbon dioxide) performed as well or better geochemically, but are not as easily upscaled. Phosphate delivery by mist was rated slightly higher than by foam delivery simply due to the complexity of foam injection and unknown effect of U mobility by the presence of the surfactant.

Szecsody, James E.; Truex, Michael J.; Zhong, Lirong; Williams, Mark D.; Resch, Charles T.; McKinley, James P.

2010-01-04T23:59:59.000Z

96

Quantifying Deep Vadose Zone Soil Water Potential Changes At A Waste Disposal Site  

Science Conference Proceedings (OSTI)

Recent advances in moisture monitoring using tensiometers has allowed long-duration, high quality data sets from within the deep vadose zone. A network of about 30 advanced tensiometers in 18 wells provided field-scale data to monitor moisture conditions and movement in the subsurface in and around a mixed waste disposal site at depths ranging from 6 to over 67 m below land surface (bls). Sensors are located in both sediments and fractured rock within the geologic profile and some have been in operation for over 10 years. The moisture monitoring was able to detect long term declines in moisture content presumably in response to lower than normal precipitation and resultant infiltration over the time period from 2000 to 2004. This trend was reversed in 2005 and 2006 in more than half of the monitoring sites over the 6 to 33 m depth interval and in several monitoring sites from 33 to 67 m, in response to normal to above normal precipitation. This tensiometer data can be used to evaluate the appropriateness of the current conceptual model of flow at this site. It also shows that a moisture monitoring system should be effective to rapidly validate that a proposed remedial action (such as placement of an ET cover) would be effective in reducing the moisture movement to levels similar to those in undisturbed sites outside of the disposal area. This paper will describe the instrument design, how the instruments were installed, and the resultant data from this monitoring system.

Joel M. Hubbell; Deborah L. McElroy

2007-10-01T23:59:59.000Z

97

Summary of Uranium Solubility Studies in Concrete Waste Forms and Vadose Zone Environments  

SciTech Connect

One of the methods being considered for safely disposing of Category 3 low-level radioactive wastes is to encase the waste in concrete. Concrete encasement would contain and isolate the waste packages from the hydrologic environment and act as an intrusion barrier. The current plan for waste isolation consists of stacking low-level waste packages on a trench floor, surrounding the stacks with reinforced steel, and encasing these packages in concrete. These concrete-encased waste stacks are expected to vary in size with maximum dimensions of 6.4 m long, 2.7 m wide, and 4 m high. The waste stacks are expected to have a surrounding minimum thickness of 15 cm of concrete encasement. These concrete-encased waste packages are expected to withstand environmental exposure (solar radiation, temperature variations, and precipitation) until an interim soil cover or permanent closure cover is installed and to remain largely intact thereafter. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. This report presents the results of investigations elucidating the uranium mineral phases controlling the long-term fate of uranium within concrete waste forms and the solubility of these phases in concrete pore waters and alkaline, circum-neutral vadose zone environments.

Golovich, Elizabeth C.; Wellman, Dawn M.; Serne, R. Jeffrey; Bovaird, Chase C.

2011-09-30T23:59:59.000Z

98

Using Nitrogen and Oxygen Isotope Compositions of Nitrate to Distinguish Contaminant Sources in Hanford Soil and Groundwater  

E-Print Network (OSTI)

stable isotopes at the Hanford Site, WA: Environ. Sci.Contaminant Transport at the Hanford Site, WA: Vadose ZoneRev. 0, Lockheed Martin Hanford Corporation, Richland, WA.

Conrad, Mark

2008-01-01T23:59:59.000Z

99

Long-Term Colloid Mobilization And Colloid-Facilitated Transport Of Radionuclides In A Semi-Arid Vadose Zone  

Science Conference Proceedings (OSTI)

The main purpose of this project was to improve the fundamental mechanistic understanding and quantification of long-term colloid mobilization and colloid-facilitated transport of radionuclides in the vadose zone, with special emphasis on the semi-arid Hanford site. While we focused some of the experiments on hydrogeological and geochemical conditions of the Hanford site, many of our results apply to colloid and colloid-facilitated transport in general. Specific objectives were (1) to determine the mechanisms of colloid mobilization and colloid-facilitated radionuclide transport in undisturbed Hanford sediments under unsaturated flow, (2) to quantify in situ colloid mobilization and colloid-facilitated radionuclide transport from Hanford sediments under field conditions, and (3) to develop a field-scale conceptual and numerical model for colloid mobilization and transport at the Hanford vadose zone, and use that model to predict long-term colloid and colloid- facilitated radionuclide transport. To achieve these goals and objectives, we have used a combination of experimental, theoretical, and numerical methods at different spatial scales, ranging from microscopic investigations of single particle attachment and detachment to larger-scale field experiments using outdoor lysimeters at the Hanford site. Microscopic and single particle investigations provided fundamental insight into mechanisms of colloid interactions with the air-water interface. We could show that a moving air water interface (such as a moving water front during infiltration and drainage) is very effective in removing and mobilizing particles from a stationary surface. Field experiment using a vadose zone lysimeter facility at the Hanford site showed that surface-applied Eu colloids can be translocated rapidly under natural precipitation as well as artificial irrigation. Small amounts of applied colloids were translocated from the surface to a depth of two meters within two months and only 20 mm of cumulative infiltration. Large water infiltration events, mimicking snow melt, enhanced movement of Eu colloids. Nonetheless the majority of Eu colloids remained in the top 30 cm of the soil after 3.5 years of monitoring. These results suggest that colloid and radionuclide transport can occur in the near-surface vadose zone at Hanford under field conditions, but that the magnitude of the transport is less than what has been reported from laboratory studies. We further studied colloid mobilization from undisturbed sediment cores under a flow rate of 18 mm/year, a typical low flow rate at Hanford. Under this low flow rate, we observed continuous colloid mobilization from the sediments, although the total amounts of colloids mobilized are small, only 0.5% of available colloids were mobilized during 5 years of observations. These results demonstrate that colloidal particles are mobile even under the low recharge rates found in a semi-arid site like Hanford. Under higher flow rates, we would expect colloid transport to be even more pronounced. These results of our study are particularly relevant for colloid mobilization and transport related to three process in the vadose zone at Hanford: (1) water infiltration into sediments during rainfall or snowmelt events, (2) groundwater fluctuations as caused by river stage fluctuations, and (3) steady-state, low-flow recharge in deep vadose zone sediments. Transient water flow, like during infiltration or groundwater level fluctuations, are most conducive for colloid mobilization, but even during steady-state, low-flow recharge, colloids can be mobile, although to a much lesser extent. The results of this project have led to a comprehensive and fundamental understanding of colloid transport and mobilization under unsaturated flow conditions at the Hanford site.

Flury, Markus; Harsh, James B; Zhang, Fred; Gee, Glendon W; Mattson, Earl D; Lichtner, Peter C

2012-11-05T23:59:59.000Z

100

Characterization of Direct-Push Vadose Zone Sediments from the 241-B and 241-BX Tank Farms  

SciTech Connect

Geochemical tests provide evidence for the transit of a plume of caustic waste solution through the sediment column at the Hanford 241-B and -BX Tank Farms. Direct-push samples recovered from boreholes surrounding Tanks 241-B-110 and 241-BX-102 and related waste transfer lines and diversion boxes included sediments typical of those previously recovered from other localities on the Hanford Site. The Hanford formation sediments are dominantly quartzo-feldspathic sands strewn with lithic fragments, displaying a range of particle size distributions and sorting characteristics. Some moderately well-sorted, fine-grained lithologies are interpreted as lenticular bodies irregularly dispersed in coarser-grained, more poorly sorted sediments. Tier I tests conducted on the vadose zone sediments revealed an inverse correlation between moisture content and sediment size fraction (i.e., there is greater moisture content in finer-grained sediments). The Tier I tests also showed that the pore water solutions were likely sodium-rich, moderately saline, and possessed higher pH values than background (untainted) sediments. These data are characteristic of sediments that have encountered sodium-rich, saline, caustic waste solution, as documented in other reports at other suspect contamination sites around Hanford. Analyses of solutions from 1:1 water extracts reveal relatively balanced cation and anion concentrations, indicating that most of the geochemical species have been accounted for. The water extract data for affected sediments also indicate unusually high concentrations of aluminum, iron, and phosphorus. The relatively high concentrations of aluminum and iron may be the result of dissolution of secondary amorphous phases that precipitated after a reactive plume partially dissolved aluminum- and iron-bearing phases as it migrated through the sediment column. On the other hand, the presence of elevated concentrations of phosphorous may be the tell-tale signature of wastes derived from the bismuth phosphate separation process. Elements typically mobile in the geosphere, such as technetium-99, are present at either low concentrations or are below the analytical detection limit. However, we expect that the mobile elements would be present mainly along a narrow plume front, and if this front had passed deeper into the sediment profile than depths sampled, the retention of these elements would be minor. On the other hand for the direct push sediments from around BX Tank Farm, uranium-238 was detected in nearly all sediment specimens (by acid extract experiments) at concentrations above the natural crustal average (0.763 pCi/g), and we also detected the presence of several anthropogenic radioisotopes, such as cobalt-60, cesium-137, europium-154, and europium-155 (by gamma energy analysis). These data are direct confirmation of contamination of the sediments.

Brown, Christopher F.; Icenhower, Jonathan P.; Um, Wooyong; Bjornstad, Bruce N.; Valenta, Michelle M.; Iovin, Cristian; Lanigan, David C.; Clayton, Ray E.; Geiszler, Keith N.; Clayton, Eric T.; Kutnyakov, Igor V.; Baum, Steven R.; Lindberg, Michael J.; Orr, Robert D.

2007-12-21T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

LONG-TERM COLLOID MOBILIZATION AND COLLOID-FACILITATED TRANSPORT OF RADIONUCLIDES IN A SEMI-ARID VADOSE ZONE  

Science Conference Proceedings (OSTI)

The main purpose of this project was to improve the fundamental mechanistic understanding and quantification of long-term colloid mobilization and colloid-facilitated transport of radionuclides in the vadose zone, with special emphasis on the semi-arid Hanford site. While we focused some of the experiments on hydrogeological and geochemical conditions of the Hanford site, many of our results apply to colloid and colloid-facilitated transport in general. Specific objectives were (1) to determine the mechanisms of colloid mobilization and colloid-facilitated radionuclide transport in undisturbed Hanford sediments under unsaturated flow, (2) to quantify in situ colloid mobilization and colloid-facilitated radionuclidetransport from Hanford sediments under field conditions, and (3) to develop a field-scale conceptual and numerical model for colloid mobilization and transport at the Hanford vadose zone, and use that model to predict long-term colloid and colloid- facilitated radionuclide transport. To achieve these goals and objectives, we have used a combination of experimental, theoretical, and numerical methods at different spatial scales, ranging from microscopic investigationsof single particle attachment and detachment to larger-scale field experiments using outdoor lysimeters at the Hanford site. Microscopic and single particle investigations provided fundamental insight into mechanisms of colloid interactions with the air-water interface. We could show that a moving air water interface (such as a moving water front during infiltration and drainage) is very effective in removing and mobilizing particles from a stationary surface. We further demonstrated that it is particularly the advancing air-water interface which is mainly responsible for colloid mobilization. Forces acting on the colloids calculated from theory corroborated our experimental results, and confirm that the detachment forces (surface tension forces) during the advancing air-water interface movement were stronger than during the receding movement. Theory indicates that, for hydrophilic colloids, the advancing interface movement generally exerts a stronger detachment force than the receding, except when the hysteresis of the colloid-air-water contact angle is small. These results of our study are particularly relevant for colloid mobilization and transport related to three process in the vadose zone at Hanford: (1) water infiltration into sediments during rainfall or snowmelt events, (2) groundwater fluctuations as caused by river stage fluctuations, and (3) steady-state, low-flow recharge in deep vadose zone sediments. Transient water flow, like during infiltration or groundwater level fluctuations, are most conducive for colloid mobilization, but even during steady-state, low-flow recharge, colloids can be mobile, although to a much lesser extent. The results of this project have led to a comprehensive and fundamental understanding of colloid transport and mobilization under unsaturated flow conditions at the Hanford site.

Markus Flury; James B. Harsh; Fred Zhang; Glendon W. Gee; Earl D. Mattson; Peter C. L

2012-08-01T23:59:59.000Z

102

Influence of Sources on Plutonium Mobility and Oxidation State Transformations in Vadose Zone Sediments  

Science Conference Proceedings (OSTI)

Well-defined solid sources of Pu(III) (PuCl3), Pu(IV) (Pu (NO3)4 and Pu (C2O4)2), and Pu(VI) (PuO2(NO3)2) were placed in lysimeters containing vadose zone sediments and exposed to natural weather conditions for 2 or 11 years. The objective of this study was to measure the release rate of Pu and the changes in the Pu oxidation states from these Pu sources with the intent to develop a reactive transport model source-term. Pu(III) and Pu(IV) sources had identical Pu concentration depth profiles and similar Pu release rates. Source release data indicate that PuIV(C2O4)2 was the least mobile, whereas PuVIO2(NO3)2 was the most mobile. Synchrotron X-ray fluorescence (SXRF) revealed that Pu was very unevenly distributed on the sediment and Mn concentrations were too low (630 mg kg-1) and perhaps of the wrong mineralogy to influence Pu distribution. The high stability of sorbed Pu(IV) is proposed to be due to the formation of a stable hydrolyzed Pu(IV) surface species. Plutonium X-ray absorption near-edge spectroscopy (XANES) analysis conducted on sediment recovered at the end of the study from the PuIV(NO3)4- and PuIIICl3-amended lysimeters contained essentially identical Pu distributions: approximately 37% Pu(III), 67% Pu(IV), 0% Pu(V), and 0% Pu(VI). These results were similar to those using a wet chemistry Pu oxidation state assay, except the latter method did not detect any Pu(III) present on the sediment but instead indicated that 93-98% of the Pu existed as Pu(IV). This discrepancy was likely attributable to incomplete extraction of sediment Pu(III) by the wet chemistry method. Although Pu has been known to exist in the +3 oxidation state under microbially induced reducing conditions for decades, to our knowledge, this is the first observation of steady-state Pu(III) in association with natural sediments. On the basis of thermodynamic considerations, Pu(III) has a wide potential distribution, especially in acidic environments, and as such may warrant further investigation.

Kaplan,D.; Powell, B.; Duff, M.; Demirkanli, D.; Denham, M.; Fjeld, R.; Molz, F.

2007-01-01T23:59:59.000Z

103

Electrical Resistivity Correlation to Vadose Zone Sediment and Pore-Water Composition for the BC Cribs and Trenches Area  

SciTech Connect

This technical report documents the results of geochemical and soil resistivity characterization of sediment obtained from four boreholes drilled in the BC Cribs and Trench area. Vadose zone sediment samples were obtained at a frequency of about every 2.5 ft from approximately 5 ft bgs to borehole total depth. In total, 505 grab samples and 39 six-inch long cores were obtained for characterization. The pore-water chemical composition data, laboratory-scale soil resistivity and other ancillary physical and hydrologic measurements and analyses described in this report are designed to provide a crucial link between direct measurements on sediments and the surface-based electrical-resistivity information obtained via field surveys. A second goal of the sediment characterization was to measure the total and water-leachable concentrations of key contaminants of concern as a function of depth and distance from the footprints of inactive disposal facilities. The total and water-leachable concentrations of key contaminants will be used to update contaminant distribution conceptual models and to provide more data for improving base-line risk predictions and remedial alternative selections. The ERC “ground truthing” exercise for the individual boreholes showed mixed results. In general, the high concentrations of dissolved salts in the pore waters of sediments from C5923, C5924 and C4191 produced a low resistivity “target” in the processed resistivity field surveys, and variability could be seen in the resistivity data that could relate to the variability in pore- water concentrations but the correlations (regression R2 were mediocre ranging from 0.2 to 0.7 at best; where perfect correlation is 1.0). The field-based geophysical data also seemed to suffer from a sort of vertigo, where looking down from the ground surface, the target (e.g., maximum pore-water salt concentration) depth was difficult to resolve. The best correlations between the field electrical resistivity surveys and borehole pore water data sets were obtained when focusing on areal extent of the salt plume. Lateral resolution of the geophysical field data is best conducted by comparing an aggregated set of geophysical data on all boreholes together. When assembling the pore-water data for all four boreholes in an aerial view, the field ERC data produce a reasonable aerial picture of where high salt plumes exist below the BC Cribs and Trenches area. Future work that relies on more laboratory soil resistivity and incorporation of other field data (spectral gamma, neutron moisture and soil density logs) and physical and hydraulic measurements on samples obtained from the boreholes will used develop a more detailed petrophysical model of the sediments below BC Cribs and Trenches. This more detailed model can be used as a more realistic “earth model” in the inversion process to better manipulate the raw field survey data. It is also recommended that one more borehole be drilled after a thorough vetting of the current data with geophysics experts and other Hanford stakeholder to optimize where to place the borehole, what electrical and other geophysical surveys should be conducted , where to take sediment samples and what parameters should be measured on the sediments to attempt one more “ground truthing” exercise.

Serne, R. Jeffrey; Ward, Anderson L.; Um, Wooyong; Bjornstad, Bruce N.; Rucker, Dale F.; Lanigan, David C.; Benecke, Mark W.

2009-06-01T23:59:59.000Z

104

Hanford Tank Farms Vadose Zone, Addendum to the TX Tank Farm Report  

Science Conference Proceedings (OSTI)

This addendum to the TX Tank Farm Report (GJO-97-13-TAR, GJO-HAN-11) published in September 1997 incorporates the results of high-rate and repeat logging activities along with shape factor analysis of the logging data. A high-rate logging system was developed and deployed in the TX Tank Farm to measure cesium-137 concentration levels in high gamma flux zones where the spectral gamma logging system was unable to collect usable data because of high dead times and detector saturation. This report presents additional data and revised visualizations of subsurface contaminant distribution in the TX Tank Farm at the DOE Hanford Site in the state of Washington.

Spatz, R.

2000-08-01T23:59:59.000Z

105

ReproducedfromVadoseZoneJournal.PublishedbySoilScienceSocietyofAmerica.Allcopyrightsreserved. Colloid Transport in the Subsurface: Past, Present, and Future Challenges  

E-Print Network (OSTI)

VadoseZoneJournal.PublishedbySoilScienceSocietyofAmerica.Allcopyrightsreserved. Colloid Transport in the Subsurface: Past, Present, and Future Challenges John F. McCarthy* and Larry D between wells and septic fieldssection on colloid transport within a more general perspective) for individual homes, subsurface systems. The focus will be on the transport of colloidal were based on empirical

McCarthy, John F.

106

T Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY09 Report  

SciTech Connect

DOE’s Office of River Protection constructed a temporary surface barrier over a portion of the T Tank Farm as part of the T Farm Interim Surface Barrier Demonstration Project. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barrier at reducing soil moisture. A solar-powered system was installed to continuously monitor soil water conditions at four locations (i.e., instrument Nests A, B, C, and D) beneath the barrier and outside the barrier footprint as well as site meteorological conditions. Nest A is placed in the area outside the barrier footprint and serves as a control, providing subsurface conditions outside the influence of the surface barrier. Nest B provides subsurface measurements to assess surface-barrier edge effects. Nests C and D are used to assess changes in soil-moisture conditions beneath the interim surface barrier. Each instrument nest is composed of a capacitance probe (CP) with multiple sensors, multiple heat-dissipation units (HDUs), and a neutron probe (NP) access tube. The monitoring results in FY09 are summarized below. The solar panels functioned normally and could provide sufficient power to the instruments. The CP in Nest C after September 20, 2009, was not functional. The CP sensors in Nest B after July 13 and the 0.9-m CP sensor in Nest D before June 10 gave noisy data. Other CPs were functional normally. All the HDUs were functional normally but some pressure-head values measured by HDUs were greater than the upper measurement-limit. The higher-than-upper-limit values might be due to the very wet soil condition and/or measurement error but do not imply the malfunction of the sensors. Similar to FY07 and FY08, in FY09, the soil under natural conditions (Nest A) was generally recharged during the winter period (October-March) and discharged during the summer period (April-September). Soil water conditions above about 1.5-m to 2-m depth from all three types of measurements (i.e., CP, NP and HDU) showed relatively large variation during the seasonal wetting-drying cycle. For the soil below 2-m depth, the seasonal variation of soil water content was relatively small. The construction of the surface barrier was completed in April 2008. In the soil below the surface barrier (Nests C and D), the CP measurements showed that water content at the soil between 0.6-m and 2.3-m depths was very stable, indicating no climatic impacts on soil water condition beneath the barrier. The NP-measured water content showed that soil water drainage seemed occurring in the soil between about 3.4 m (11 ft) and 9.1 m (30 ft) in FY09. The HDU-measured water pressure decreased consistently in the soil above 5-m depth, indicating soil water drainage at these depths of the soil. In the soil below the edge of the surface barrier (Nest B), the CP-measured water content was relatively stable through the year except at the 0.9-m depth; the NP-measured water content showed that soil water drainage was occurring in the soil between about 3.4 m (11 ft) and 9.1 m (30 ft) but at a slightly smaller magnitude than those in Nests C and D; the HDU-measurements show that the pressure head changes in FY09 in Nest B were less than those for C and D but more than those for A. The soil-water-pressure head was more sensitive to soil water regime changes under dry conditions. In the soil beneath the barrier, the theoretical steady-state values of pressure head is equal to the negative of the distance to groundwater table. Hence, it is expected that, in the future, while the water content become stable, the pressure head will keep decreasing for a long time (e.g., many years). These results indicate that the T Tank Farm surface barrier was performing as expected by intercepting the meteoric water from infiltrating into the soil and the soil was becoming drier gradually. The barrier also has some effects on the soil below the barrier edge but at a reduced magnitude.

Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

2010-01-01T23:59:59.000Z

107

Characterization of Vadose Zone Sediments Below the T Tank Farm: Boreholes C4104, C4105, 299-W10-196 and RCRA Borehole 299-W11-39  

Science Conference Proceedings (OSTI)

This report contains geologic, geochemical, and physical characterization data collected on sediment recovered from boreholes C4104 and C4105 in the T Tank Farm, and 299-W-11-39 installed northeast of the T Tank Farm. The measurements on sediments from borehole C4104 are compared to a nearby borehole 299-W10-196 placed through the plume from the 1973 T-106 tank leak. This report also presents the data in the context of sediment types, the vertical extent of contamination, the migration potential of the contaminants, and the likely source of the contamination in the vadose zone and groundwater below the T Tank Farm. Sediment samples were characterized for: moisture content, gamma-emission radionuclides, one-to-one water extracts (which provide soil pH, electrical conductivity, cation, trace metal, radionuclide and anion data), total carbon and inorganic carbon content, and 8 M nitric acid extracts (which provide a measure of the total leachable sediment content of contaminants). Overall, our analyses showed that common ion exchange is a key mechanism that influences the distribution of contaminants within that portion of the vadose zone affected by tank liquor. We observed slight elevated pH values in samples from borehole C4104. The sediments from the three boreholes, C4104, C4105, and 299-W10-196 do show that sodium-, nitrate-, and sulfate-dominated fluids are present below tank T-106 and have formed a salt plume. The fluids are more dilute than tank fluids observed below tanks at the SX and BX Tank Farms and slightly less than those from the most saline porewater found in contaminated TX tank farm sediments. The boreholes could not penetrate below the gravel-rich strata of the Ringold Formation Wooded Island member (Rwi) (refusal was met at about 130 ft bgs); therefore, we could not identify the maximum vertical penetration of the tank related plumes. The moisture content, pH, electrical conductivity, nitrate, and technetium-99 profiles versus depth in the three contaminated boreholes around T-106 do not clearly identify the leading edge of the plume. However, the profiles do collectively suggest that bulk of tank-related fluids (center of mass) still resides in Ringold Formation Taylor Flats member fine-grained sediments. Most of the chemical data, especially the nitrate and technetium-99 distributions with depth, support a flow conceptual model that suggests vertical percolation through the Hanford formation H2 unit near T-106 and then a strong horizontal spreading within the CCUu unit followed by more slow vertical percolation, perhaps via diffusion, into the deeper strata. Slow flushing by enhanced recharge and rapid snow melt events (Feb. 1979) appear to lead to more horizontal movement of the tank fluids downgradient towards C4105. The inventories as a function of depth of potential contaminants of concern, nitrate, technetium, uranium, and chromium, are provided. In-situ Kd values were calculated from water and acid extract measurements. For conservative modeling purposes we recommend using Kd values of 0 mL/g for nitrate, Co-60, and technetium-99, a value of 0.1 mL/g for uranium near borehole C4104 and 10 mL/g for U near borehole C4105, and 1 mL/g for chromium to represent the entire vadose zone profile from the bottoms of the tanks to the water table. A technetium-99 groundwater plume exists northeast and east of T WMA. The highest technetium-99 concentration in fiscal year 2003 was 9,200 pCi/L in well 299-W11-39. The most probable source for the technetium-99 is the T waste management area. Groundwater from wells in the west (upgradient) and north of WMA T appear to be highly influenced by wastes disposed to the cribs and trenches on the west side of the WMA. Groundwater from wells at the northeast corner and the east side of the WMA appears to be evolving towards tank waste that has leaked from T-101 or T-106.

Serne, R JEFFREY.; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; LeGore, Virginia L.; Geiszler, Keith N.; Baum, Steven R.; Valenta, Michelle M.; Kutnyakov, Igor V.; Vickerman, Tanya S.; Orr, Robert D.; Brown, Christopher F.

2004-09-01T23:59:59.000Z

108

www.VadoseZoneJournal.org | 12011, Vol. 10 Flow Processes in the Dry  

E-Print Network (OSTI)

(OBM). In the case of tight-gas sands, our method explains the marginal productivity of deeply invaded partially-depleted hydrocarbon-bearing sands and tight-gas sands. SIMULATION METHOD Petrophysical Analysis example considers a tight-gas sand invaded with WBM. The second example considers an oil-bearing zone

Wildenschild, Dorthe

109

Remediation of Uranium in the Hanford Vadose Zone Using Ammonia Gas: FY 2010 Laboratory-Scale Experiments  

SciTech Connect

This investigation is focused on refining an in situ technology for vadose zone remediation of uranium by the addition of ammonia (NH3) gas. Objectives are to: a) refine the technique of ammonia gas treatment of low water content sediments to minimize uranium mobility by changing uranium surface phases (or coat surface phases), b) identify the geochemical changes in uranium surface phases during ammonia gas treatment, c) identify broader geochemical changes that occur in sediment during ammonia gas treatment, and d) predict and test injection of ammonia gas for intermediate-scale systems to identify process interactions that occur at a larger scale and could impact field scale implementation.Overall, NH3 gas treatment of low-water content sediments appears quite effective at decreasing aqueous, adsorbed uranium concentrations. The NH3 gas treatment is also fairly effective for decreasing the mobility of U-carbonate coprecipitates, but shows mixed success for U present in Na-boltwoodite. There are some changes in U-carbonate surface phases that were identified by surface phase analysis, but no changes observed for Na-boltwoodite. It is likely that dissolution of sediment minerals (predominantly montmorillonite, muscovite, kaolinite) under the alkaline conditions created and subsequent precipitation as the pH returns to natural conditions coat some of the uranium surface phases, although a greater understanding of these processes is needed to predict the long term impact on uranium mobility. Injection of NH3 gas into sediments at low water content (1% to 16% water content) can effectively treat a large area without water addition, so there is little uranium mobilization (i.e., transport over cm or larger scale) during the injection phase.

Szecsody, James E.; Truex, Michael J.; Zhong, Lirong; Qafoku, Nikolla; Williams, Mark D.; McKinley, James P.; Wang, Zheming; Bargar, John; Faurie, Danielle K.; Resch, Charles T.; Phillips, Jerry L.

2010-12-01T23:59:59.000Z

110

Modeling non-steady state radioisotope transport in the vadose zone--A case study using uranium isotopes at Pena Blanca, Mexico  

SciTech Connect

Current models using U- and Th-series disequilibria to study radioisotope transport in groundwater systems mostly consider a steady-state situation. These models have limited applicability to the vadose zone (UZ) where the concentration and migratory behavior of radioisotopes in fluid are often transitory. We present here, as a first attempt of its kind, a model simulating the non-steady state, intermittent fluid transport in vadose layers. It provides quantitative constraints on in-situ migration of dissolved and colloidal radioisotopes in terms of retardation factor and rock-water interaction (or water transit) time. For uranium, the simulation predicts that intermittent flushing in the UZ leads to a linear relationship between reciprocal U concentration and {sup 234}U/{sup 238}U ratio in percolating waters, with the intercept and slope bearing information on the rates of dissolution and {alpha}-recoil of U isotopes, respectively. The general validity of the model appears to be borne out by the measurement of uranium isotopes in UZ waters collected at various times over a period during 1995-2006 from a site in the Pena Blanca mining district, Mexico, where the Nopal I uranium deposit is located. Enhanced {sup 234}U/{sup 238}U ratios in vadose-zone waters resulting from lengthened non-flushing time as prescribed by the model provide an interpretative basis for using {sup 234}U/{sup 238}U in cave calcites to reconstruct the regional changes in hydrology and climate. We also provide a theoretical account of the model's potential applications using radium isotopes.

Ku, T. L.; Luo, S.; Goldstein, S. J.; Murrell, M. T.; Chu, W. L.; Dobson, P. F.

2009-06-01T23:59:59.000Z

111

Remediation of chromium(VI) in the vadose zone: stoichiometry and kinetics of chromium(VI) reduction by sulfur dioxide  

E-Print Network (OSTI)

Immobilization and detoxification of chromium in the vadose zone is made possible by the existence of an effective reductant, SO2, that exists in a gaseous form at room temperature. Experimental studies were designed to characterize stoichiometry and kinetics of chromium reduction both in aqueous solutions at pH values near neutrality and in soil. First, batch experiments and elemental analyses were conducted to characterize the stoichiometry and kinetics of Cr(VI) reduction in water. The stoichiometric ratio of S(IV) removed to Cr(VI) removed ranged between 1.6 and 1.8. The overall reaction is believed to be the result of a linear combination of two reactions in which dithionate is an intermediate and sulfate is the stable oxidized product. The reaction was also rapid, with the half-time of about 45 minutes at pH 6 and about 16 hours at pH 7. A two-step kinetic model was developed to describe changes in concentrations of Cr(VI), S(IV), and S(V). Nonlinear regression was applied to obtain the kinetic parameters. The rate of reaction was assumed to be second-order with respect to [Cr(VI)] and first-order with respect to [S(IV)], and [S(V)]. The values for the rate coefficient for the first reaction (k1) were found to be 4.5 (?10%), 0.25 (?9.4%) (mM-2h-1) at pH 6 and 7, respectively. The values of the rate coefficient for the second reaction (k2) were 25 (?29%), 1.1 (? 30%) (mM-2h-1) at pH 6 and 7, respectively. The reaction rate decreased as pH increased. Experiments showed that the rate at pH 7 was lower than that at pH 6 by one order of magnitude. Second, batch experiments and elemental analyses were conducted to characterize the stoichiometry and kinetics of Cr(VI) reduction in soil. The stoichiometric ratio of S(IV) removed to Cr(VI) removed was almost 2, which is slightly higher than that for the reaction in water. This higher value may be due to S(IV) oxidation by soil-derived Fe(III). The reaction was rapid, with the half-time less than 2 minutes, which is faster than in water. The rate coefficients, k1 and k2, were 22 (?41%) and 13 (?77%) (M-2h-1), respectively.

Ahn, Min

2003-08-01T23:59:59.000Z

112

Appraisal of nuclear waste isolation in the vadose zone in arid and semiarid regions (with emphasis on the Nevada Test Site)  

SciTech Connect

An appraisal was made of the concept of isolating high-level radioactive waste in the vadose zone of alluvial-filled valleys and tuffaceous rocks of the Basin and Range geomorphic province. Principal attributes of these terranes are: (1) low population density, (2) low moisture influx, (3) a deep water table, (4) the presence of sorptive rocks, and (5) relative ease of construction. Concerns about heat effects of waste on unsaturated rocks of relatively low thermal conductivity are considered. Calculations show that a standard 2000-acre repository with a thermal loading of 40 kW/acre in partially saturated alluvium or tuff would experience an average temperature rise of less than 100{sup 0}C above the initial temperature. The actual maximum temperature would depend strongly on the emplacement geometry. Concerns about seismicity, volcanism, and future climatic change are also mitigated. The conclusion reached in this appraisal is that unsaturated zones in alluvium and tuff of arid regions should be investigated as comprehensively as other geologic settings considered to be potential repository sites.

Wollenberg, H.A.; Wang, J.S.Y.; Korbin, G.

1983-05-01T23:59:59.000Z

113

Coupled Vadose Zone and Atmospheric Surface-Layer Transport of CO2 from Geologic Carbon Sequestration Sites  

E-Print Network (OSTI)

1999. Reichle, D. et al. , Carbon sequestration research andfrom geologic carbon sequestration sites: unsaturated zoneCO 2 from a geologic carbon sequestration site showing the

Oldenburg, Curtis M.; Unger, Andre J.A.

2004-01-01T23:59:59.000Z

114

Assessment of Groundwater Vulnerability to Contamination Using Capture Zone Delineation in Shenzhen City, China  

Science Conference Proceedings (OSTI)

As a result of the large risk associated with the contamination of aquifers, it becomes imperative to protect groundwater supply areas. One of the practical methods that is projected for the protection of aquifers is to zone a boundary around current ... Keywords: MODPATH, capture zones, delineation, groundwater contamination, vulnerability

Chiha Aida; Aiguo Zhou; Jianwei Zhou; ShaoGang Dong

2009-07-01T23:59:59.000Z

115

Application of a modified denitrifying bacteria method for analyzing groundwater and vadose zone pore water nitrate at the Hanford Site, WA, USA.  

E-Print Network (OSTI)

zone pore water nitrate at the Hanford Site, WA, USA. Woods,and Conrad, Mark The Hanford Site in southern WashingtonL have been reported for Hanford groundwaters, where nitrate

Woods, Katharine N.; Singleton, Michael J.; Conrad, Mark

2003-01-01T23:59:59.000Z

116

In-situ remediation system for contaminated groundwater  

DOE Patents (OSTI)

A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume is described. The fluid enables the volatile contaminants to be volatilized and carried through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like. 3 refs., 3 figs.

Corey, J.C.; Looney, B.B.; Kaback, D.S.

1988-08-25T23:59:59.000Z

117

In-situ remediation system and method for contaminated groundwater  

DOE Patents (OSTI)

A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume. The fluid enables the volatile contaminants to be volatilized and carried therewith through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone, respectively. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like.

Corey, John C. (Aiken, SC); Looney, Brian B. (Aiken, SC); Kaback, Dawn S. (Aiken, SC)

1989-01-01T23:59:59.000Z

118

In-situ remediation system and method for contaminated groundwater  

DOE Patents (OSTI)

A system for removing volatile contaminants from a subsurface plume of contamination comprising two sets of wells, a well for injecting a fluid into a saturated zone on one side of the plume and an extracting well for collecting the fluid together with volatilized contaminants from the plume on the other side of the plume. The fluid enables the volatile contaminants to be volatilized and carried therewith through the ground to the extracting well. Injecting and extracting wells are preferably horizontal wells positioned below the plume in the saturated zone and above the plume in the vadose zone, respectively. The fluid may be air or other gas or a gas and liquid mixture depending on the type of contaminant to be removed and may be preheated to facilitate volatilization. Treatment of the volatilized contamination may be by filtration, incineration, atmospheric dispersion or the like. 3 figs.

Corey, J.C.; Looney, B.B.; Kaback, D.S.

1989-05-23T23:59:59.000Z

119

Advanced Vadose Zone Simulations Using TOUGH  

E-Print Network (OSTI)

multiphase flow and multicomponent transport in porous andmultiphase, multicomponent fluids in permeable (fractured and porous)multiphase fluid flow, heat transfer, and deformation in fractured porous

2008-01-01T23:59:59.000Z

120

Advanced Vadose Zone Simulations Using TOUGH  

E-Print Network (OSTI)

for modeling fluid and heat flow in fractured porous media.flows of multiphase, multicomponent fluids in permeable (fractured and porous) media (

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Advanced Vadose Zone Simulations Using TOUGH  

E-Print Network (OSTI)

Technology. Within the ice phase (to T = 50 K and P ? 200the phase transition from liquid or gas to ice and viceand ice-liquid equilibrium lines of the water phase diagram)

2008-01-01T23:59:59.000Z

122

Spatially resolved U(VI) partitioning and speciation: Implications for plume scale behavior of contaminant U in the Hanford vadose zone  

E-Print Network (OSTI)

and Technology 2006, 40, Sandia National Laboratories,Technol. 2004, 38, 5591-5597. Sandia National Laboratories,

Wan, Jiamin

2009-01-01T23:59:59.000Z

123

Spatially resolved U(VI) partitioning and speciation: Implications for plume scale behavior of contaminant U in the Hanford vadose zone  

E-Print Network (OSTI)

B-BX-BY waste management area. PNNL-14083; Pacific NorthwestNorthwest National Laboratory, PNNL- Jones, T. E. ; Simpson,Fate of Fission Products. PNNL-14120, Pacific Northwest

Wan, Jiamin

2009-01-01T23:59:59.000Z

124

AN EVALUATION OF HANFORD SITE TANK FARM SUBSURFACE CONTAMINATION FY2007  

Science Conference Proceedings (OSTI)

The Tank Farm Vadose Zone (TFVZ) Project conducts activities to characterize and analyze the long-term environmental and human health impacts from tank waste releases to the vadose zone. The project also implements interim measures to mitigate impacts, and plans the remediation of waste releases from tank farms and associated facilities. The scope of this document is to report data needs that are important to estimating long-term human health and environmental risks. The scope does not include technologies needed to remediate contaminated soils and facilities, technologies needed to close tank farms, or management and regulatory decisions that will impact remediation and closure. This document is an update of ''A Summary and Evaluation of Hanford Site Tank Farm Subsurface Contamination''. That 1998 document summarized knowledge of subsurface contamination beneath the tank farms at the time. It included a preliminary conceptual model for migration of tank wastes through the vadose zone and an assessment of data and analysis gaps needed to update the conceptual model. This document provides a status of the data and analysis gaps previously defined and discussion of the gaps and needs that currently exist to support the stated mission of the TFVZ Project. The first data-gaps document provided the basis for TFVZ Project activities over the previous eight years. Fourteen of the nineteen knowledge gaps identified in the previous document have been investigated to the point that the project defines the current status as acceptable. In the process of filling these gaps, significant accomplishments were made in field work and characterization, laboratory investigations, modeling, and implementation of interim measures. The current data gaps are organized in groups that reflect Components of the tank farm vadose zone conceptual model: inventory, release, recharge, geohydrology, geochemistry, and modeling. The inventory and release components address residual wastes that will remain in the tanks and tank-farm infrastructure after closure and potential losses from leaks during waste retrieval. Recharge addresses the impacts of current conditions in the tank farms (i.e. gravel covers that affect infiltration and recharge) as well as the impacts of surface barriers. The geohydrology and geochemistry components address the extent of the existing subsurface contaminant inventory and drivers and pathways for contaminants to be transported through the vadose zone and groundwater. Geochemistry addresses the mobility of key reactive contaminants such as uranium. Modeling addresses conceptual models and how they are simulated in computers. The data gaps will be used to provide input to planning (including the upcoming C Farm Data Quality Objective meetings scheduled this year).

MANN, F.M.

2007-07-10T23:59:59.000Z

125

Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquife  

SciTech Connect

Localized zones or lenses of naturally reduced sediments have the potential to play a significant role in the fate and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology and redox processes that occur in these zones, several cores from a region of naturally occurring reducing conditions in a U-contaminated aquifer (Rifle, CO) were examined. Sediment samples from a transect of cores ranging from oxic/suboxic Rifle aquifer sediment to naturally reduced sediment were analyzed for U and Fe content, oxidation state, and mineralogy; reduced S phases; and solid-phase organic C content using a suite of analytical and spectroscopic techniques on bulk sediment and size fractions. Solid-phase U concentrations were higher in the naturally reduced zone, with a high proportion of the U present as U(IV). The sediments were also elevated in reduced S phases and Fe(II), indicating it is very likely that U(VI), Fe(III), and SO4 reduction has occurred or is occurring in the sediment. The microbial community was assessed using lipid- and DNA-based techniques, and statistical redundancy analysis was performed to determine correlations between the microbial community and the geochemistry. Increased concentrations of solid-phase organic C and biomass in the naturally reduced sediment suggests that natural bioreduction is stimulated by a zone of increased organic C concentration associated with fine-grained material and lower permeability to groundwater flow. Characterization of the naturally bioreduced sediment provides an understanding of the natural processes that occur in the sediment under reducing conditions and how they may impact natural attenuation of radionuclides and other redox sensitive materials. Results also suggest the importance of recalcitrant organic C for maintaining reducing conditions and U immobilization.

Campbell, K M; K Kukkadapu, R K; Qafoku, N P; Peacock, A D; Lesher, E; Williams, K H; Bargar, J R; Wilkins, M J; Figueroa, L; Ranville, J; Davis, J A; Long, P E

2012-05-23T23:59:59.000Z

126

Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquifer  

SciTech Connect

Localized zones or lenses of naturally reduced sediments have the potential to play a significant role in the fate and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology, and redox processes that occur in these zones, we examined several cores from a region of naturally occurring reducing conditions in a uranium-contaminated aquifer (Rifle, CO). Sediment samples from a transect of cores ranging from oxic/suboxic Rifle aquifer sediment to naturally reduced sediment were analyzed for uranium and iron content, oxidation state, and mineralogy, reduced sulfur phases, and solid phase organic carbon content using a suite of analytical and spectroscopic techniques on bulk sediment and size fractions. Solid-phase uranium concentrations were higher in the naturally reduced zone, with a high proportion of the uranium present as reduced U(IV). The sediments were also elevated in reduced sulfur phases and Fe(II), indicating it is very likely that U(VI), Fe(III), and sulfate reduction occurred or is occurring in the sediment. The microbial community was assessed using lipid- and DNA-based techniques, and statistical redundancy analysis was performed to determine correlations between the microbial community and the geochemistry. Increased concentration of solid phase organic carbon and biomass in the naturally reduced sediment suggests that natural bioreduction is stimulated by a zone of increased organic carbon concentration associated with fine-grained material and lower permeability to groundwater flow. Characterization of the naturally bioreduced sediment provides an understanding of the natural processes that occur in the sediment under reducing conditions and how they may impact natural attenuation of radionuclides and other redox sensitive materials. Results also suggest the importance of recalcitrant organic carbon for maintaining reducing conditions and uranium immobilization.

Campbell, Kate M.; Kukkadapu, Ravi K.; Qafoku, Nikolla; Peacock, Aaron D.; Lesher, E.; Williams, Kenneth H.; Bargar, John R.; Wilkins, Michael J.; Figueroa, Linda A.; Ranville, James; Davis, James; Long, Philip E.

2012-05-23T23:59:59.000Z

127

in situ Calcite Precipitation for Contaminant Immobilization  

SciTech Connect

in situ Calcite Precipitation for Contaminant Immobilization Yoshiko Fujita (Yoshiko.fujita@inl.gov) (Idaho National Laboratory, Idaho Falls, Idaho, USA) Robert W. Smith (University of Idaho-Idaho Falls, Idaho Falls, Idaho, USA) Subsurface radionuclide and trace metal contaminants throughout the U.S. Department of Energy (DOE) complex pose one of DOE’s greatest challenges for long-term stewardship. One promising stabilization mechanism for divalent trace ions, such as the short-lived radionuclide strontium-90, is co-precipitation in calcite. Calcite, a common mineral in the arid western U.S., can form solid solutions with trace metals. The rate of trace metal incorporation is susceptible to manipulation using either abiotic or biotic means. We have previously demonstrated that increasing the calcite precipitation rate by stimulating the activity of urea hydrolyzing microorganisms can result in significantly enhanced Sr uptake. Urea hydrolysis causes the acceleration of calcium carbonate precipitation (and trace metal co-precipitation) by increasing pH and alkalinity, and also by liberating the reactive cations from the aquifer matrix via exchange reactions involving the ammonium ion derived from urea: H2NCONH2 + 3H2O ? 2NH4+ + HCO3- + OH- urea hydrolysis >X:2Ca + 2NH4+ ? 2>X:NH4 + Ca2+ ion exchange Ca2+ + HCO3- + OH- ? CaCO3(s) + H2O calcite precipitation where >X: is a cation exchange site on the aquifer matrix. This contaminant immobilization approach has several attractive features. Urea hydrolysis is catalyzed by the urease enzyme, which is produced by many indigenous subsurface microorganisms. Addition of foreign microbes is unnecessary. In turn the involvement of the native microbes and the consequent in situ generation of reactive components in the aqueous phase (e.g., carbonate and Ca or Sr) can allow dissemination of the reaction over a larger volume and/or farther away from an amendment injection point, as compared to direct addition of the reactants at a well (which can lead to clogging). A final particularly attractive characteristic of this approach is its long-term sustainability; the remediation scheme is geared toward environments that are already saturated with respect to calcite, and in such systems the bulk of any newly precipitated calcite will remain stable once engineered manipulations cease. This means that the co-precipitated contaminants will be effectively sequestered over the long term. We are currently conducting integrated field, laboratory, and computational research to evaluate a) the relationships between urea hydrolysis rate, calcite precipitation rate, and trace metal partitioning under environmentally relevant conditions; and b) the coupling between flow/flux manipulations and calcite precipitate distribution and metal uptake. We are also assessing the application of geophysical and molecular biological tools to monitor the relevant chemical and physical processes. The primary emphasis is on field-scale processes, with the laboratory and modeling activities designed specifically to support the field studies. Field experiments are being conducted in perched water (vadose zone) at the Vadose Zone Research Park (VZRP) at the Idaho National Laboratory; the VZRP provides an uncontaminated setting that is an analog of the 90Sr-contaminated vadose zone at the Idaho Nuclear Technology and Engineering Center. A summary of results to date will be presented.

Yoshiko Fujita; Robert W. Smith

2009-08-01T23:59:59.000Z

128

TOUGH +: Modeling Fluid and Heat Flow in Porous and Fractured ...  

geologic carbon sequestration sites; saline and freshwater aquifers (including the vadose zone) sites contaminated by radionuclides or volatile organic compounds;

129

Sampling and Analysis Instruction for Installation of UPR-100-N-17 Bioremediation Wells and Performance of Bioventing Pilot Tests  

SciTech Connect

Sampling and analytical requirements for in situ bioremediation pilot study for remediation of vadose zone petroleum hydrocarbon contamination.

W. S. Thompson

2008-12-30T23:59:59.000Z

130

THE SCENARIOS APPROACH TO ATTENUATION-BASED REMEDIES FOR INORGANIC AND RADIONUCLIDE CONTAMINANTS  

SciTech Connect

Guidance materials based on use of conceptual model scenarios were developed to assist evaluation and implementation of attenuation-based remedies for groundwater and vadose zones contaminated with inorganic and radionuclide contaminants. The Scenarios approach is intended to complement the comprehensive information provided in the US EPA's Technical Protocol for Monitored Natural Attenuation (MNA) of Inorganic Contaminants by providing additional information on site conceptual models and extending the evaluation to consideration of Enhanced Attenuation approaches. The conceptual models incorporate the notion of reactive facies, defined as units with hydrogeochemical properties that are different from surrounding units and that react with contaminants in distinct ways. The conceptual models also incorporate consideration of biogeochemical gradients, defined as boundaries between different geochemical conditions that have been induced by waste disposal or other natural phenomena. Gradients can change over time when geochemical conditions from one area migrate into another, potentially affecting contaminant mobility. A recognition of gradients allows the attenuation-affecting conditions of a site to be projected into the future. The Scenarios approach provides a stepwise process to identify an appropriate category of conceptual model and refine it for a specific site. Scenario materials provide links to pertinent sections in the EPA technical protocol and present information about contaminant mobility and important controlling mechanism for attenuation-based remedies based on the categories of conceptual models.

Vangelas, K.; Rysz, M.; Truex, M.; Brady, P.; Newell, C.; Denham, M.

2011-08-04T23:59:59.000Z

131

Uranium Contamination in the 300 Area: Emergent Data and their Impact on the Source Term Conceptual Model  

SciTech Connect

The primary objectives of this characterization activity were to: 1) determine the extent of uranium contamination in the sediments, 2) quantify the leachable (labile) concentration of uranium in the sediments, and 3) create a data set that could be used to correlate the present data to existing 300 Area data. In order to meet these objectives, sediments collected from wells 399-2-5 (C5708), 299-3-22 (C5706) and 299-4-14 (C5707) were analyzed for moisture content, 1:1 sediment:water extracts (which provide soil pH, electrical conductivity [EC], cation, and anion data), total carbon and inorganic carbon content, 8 M nitric acid extracts (which provide a measure of the total leachable sediment content of the contaminants), microwave-assisted digestion (which results in total digestion of the sediment), and carbonate leaches (which provide an assessment of the concentration of labile uranium present in the sediments). Additionally, pore waters present in select samples were extracted using ultracentrifugation. The mobility characteristics of uranium vary within the multiple subsurface zones that contain residual contaminant uranium. Principal subsurface zones include 1) the vadose zone, 2) a zone through which the water table rises and falls, 3) the aquifer, and 4) a zone where groundwater and river water interact beneath the river shoreline. Principal controls on mobilization include the form of the residual uranium (e.g., crystalline minerals, amorphous precipitates/coatings, sorbed onto sediment), the transporting medium (e.g., water infiltration from the land surface, groundwater), and the rate of exchange between the form and transporting medium. The bicarbonate content of aqueous media strongly influences the rate of exchange, with relatively higher content enhancing mobility. Groundwater has a higher bicarbonate content than river water or other freshwater sources, such as utility and potable water systems. The variety of processes affecting the mobility of uranium in the subsurface, along with the numerous potential compartments where residual contamination may be located, presents challenges for predicting uranium movement through environmental pathways. The processes responsible for the persistence of the plume may involve cycling of uranium between the aquifer and overlying zone through which the water table fluctuates. Contaminated groundwater is moved upward into the lower vadose zone, and when the water table subsequently falls, contaminated moisture is left behind. Some of the uranium in groundwater may become sorbed to sediment in that zone, to subsequently slowly release. Also, near the Columbia River in the zone of groundwater/river water interaction, where the bicarbonate content is lowered because of infiltrating river water, the tendency for uranium to adsorb onto sediment is enhanced, thus slowing dissipation via the groundwater pathway. Fluctuations in the Columbia River stage are the driving mechanism for the rise and fall of the water table beneath the 300 Area, and also for creating the dynamic hydraulic and geochemical environment found in the zone of interaction beneath the shoreline.

Brown, Christopher F.; Um, Wooyong; Serne, R. Jeffrey

2008-09-30T23:59:59.000Z

132

V12-0159.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

VadoseZoneJournal.org VadoseZoneJournal.org Contaminants in Vadose Zone Environments Contaminants in vadose zone environments pose a long-term source and threat to groundwater resources, human health, and the environment. A number of technical, regulatory, and policy challenges and opportuni es are associated with contamina on in vadose zone environments, par cularly in remedia on. In this special sec on, 12 papers present novel approaches to characterize, monitor, remediate, and predict the transport and fate of contaminants in vadose zone environments. Abbrevia ons: LNAPL, light nonaqueous phase liquid. Vadose zone contamina on is a signifi cant global issue for protection of ground- water resources. While much of the focus is generally on arid and semiarid regions, vadose

133

Prototype Database and User's Guide of Saturated Zone Hydraulic Properties forthe Hanford Site  

SciTech Connect

Predicting the movement of contaminants in groundwater beneath the Hanford Site is important for both understanding the impacts of these contaminants and for planning effective cleanup activities. These predictions are based on knowledge of the distribution of hydraulic properties within the aquifers underlying the Hanford Site. The Characterization of Systems (CoS) Task, under the Groundwater/Vadose Integration Project, is responsible for establishing a consistent set of data, parameters, and conceptual models to support estimates contaminant migration and impact.

Thorne, Paul D.; Newcomer, Darrell R.

2002-09-01T23:59:59.000Z

134

MODELING U TRANSPORT IN THE UNSATURATED ZONE AT PENA BLANCA, MEXICO  

SciTech Connect

We present a quantitative model to describe transport of radionuclides underground. Applicable to unsaturated (vadose) as well as saturated (phreatic) layers, the model provides constraints on the in-situ migratory behavior of radioisotopes in dissolved and colloidal pools of a groundwater system. It shows, for examples, that uranium in water percolating through the vadose zone will have its concentration and ratio {sup 234}U/{sup 238}U linearly correlated under the ideal condition of a constant removal of the two U isotopes from vadose-zone solids. The intercept and slope of the linearity serve to constrain removal rates of the two uranium isotopes from solids to the solution through dissolution and alpha recoil. The model also allows estimation of the fluid transit time in the vadose zone. At Pena Blanca, the uneven distribution of rainfall between winter (wet) and summer (dry) results in a conspicuous seasonal variability in uranium removal rate, hence dissolved uranium signals, within the unsaturated zone. Our data indicate a much higher uranium dissolution rate during the dry season than during the wet season, possibly reflecting a condition of increased oxygenation in the zone during the dry period.

T.L. Ku; S. Luo; M. Murrell; S. Goldstein

2005-07-01T23:59:59.000Z

135

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Subsurface Imaging of Vadose Zone Contamination at Hanford Site RICHLAND, Wash. - Cold War waste disposal practices resulted in both planned and unplanned releases of...

136

In Situ Characterization of Unsaturated Soil Hydraulic Properties at the Maricopa Environmental Monitoring Site.  

E-Print Network (OSTI)

??Characterization of the unsaturated hydraulic properties is fundamental in modeling soil water flow and contaminant transport in the vadose zone. The objective of this study… (more)

Graham, Aaron Robert.

2004-01-01T23:59:59.000Z

137

Hydrogeophysics  

E-Print Network (OSTI)

BC Cribs and Trenches Site, Hanford. Vadose Zone Journal 6:Department of Energy (DOE) Hanford Reservation in Washingtonarea of the contaminated Hanford, Washington Reservation,

Hubbard, S.S.

2011-01-01T23:59:59.000Z

138

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to provide scientifically defensible end states for environmental remediation of volatile organic contaminants in the vadose zone. http:energy.govemarticles...

139

BaroBall  

Barometric pumping is a remediation technique that removes volatile contaminants from soil in the vadose zone, above the water table.  The BaroBall ...

140

Multiphase Reactive Transport modeling of Stable Isotope Fractionation of Infiltrating Unsaturated Zone Pore Water and Vapor Using TOUGHREACT  

Science Conference Proceedings (OSTI)

Numerical simulations of transport and isotope fractionation provide a method to quantitatively interpret vadose zone pore water stable isotope depth profiles based on soil properties, climatic conditions, and infiltration. We incorporate the temperature-dependent equilibration of stable isotopic species between water and water vapor, and their differing diffusive transport properties into the thermodynamic database of the reactive transport code TOUGHREACT. These simulations are used to illustrate the evolution of stable isotope profiles in semiarid regions where recharge during wet seasons disturbs the drying profile traditionally associated with vadose zone pore waters. Alternating wet and dry seasons lead to annual fluctuations in moisture content, capillary pressure, and stable isotope compositions in the vadose zone. Periodic infiltration models capture the effects of seasonal increases in precipitation and predict stable isotope profiles that are distinct from those observed under drying (zero infiltration) conditions. After infiltration, evaporation causes a shift to higher 18O and D values, which are preserved in the deeper pore waters. The magnitude of the isotopic composition shift preserved in deep vadose zone pore waters varies inversely with the rate of infiltration.

Singleton, Michael J.; Sonnenthal, Eric L.; Conrad, Mark E.; DePaolo, Donald J.

2003-08-28T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Limited hydrologic response to Pleistocene climate change in deep vadose zones --Yucca Mountain, Nevada  

E-Print Network (OSTI)

regulations for radiation releases from the planned permanent U.S. nuclear-waste repository in Yucca Mountain releases from the proposed U.S. nuclear-waste repository in Yucca Mountain, Nevada.1 E.P.A. recommended these guarantees for Yucca Mountain. Instead E.P.A. recommends changes both in the exposure-limits and in how

Holliday, Vance T.

142

MODELING LONG-TERM PLUTONIUM TRANSPORT IN THE SAVANNAH RIVER SITE VADOSE ZONE.  

E-Print Network (OSTI)

??The natural climate created a dynamic hydrologic system for the lysimeter experiments. Thus, for the purpose of evaluating the effects of flow dynamics on Pu… (more)

Demirkanli, Deniz

143

Geochemical and Geophysical Changes during Ammonia Gas Treatment of Vadose Zone Sediments for Uranium Remediation  

SciTech Connect

NH3 gas treatment of low water content sediments resulted in a significant decrease in aqueous and adsorbed uranium, which is attributed to incorporation into precipitates. Uranium associated with carbonates showed little change. Uranium associated with hydrous silicates such as Na-boltwoodite showed a significant decrease in mobility but no change in Na-boltwoodite concentration (by EXAFS/XANES), so is most likely caused by non-U precipitate coatings. Complex resistivity changes occurred in the sediment during NH3 and subsequent N2 gas injection, indicating ERT/IP could be used at field scale for injection monitoring.

Szecsody, James E.; Truex, Michael J.; Zhong, Lirong; Johnson, Timothy C.; Qafoku, Nikolla; Williams, Mark D.; Greenwood, William J.; Wallin, Erin L.; Bargar, John R.; Faurie, Danielle K.

2012-10-30T23:59:59.000Z

144

SPECIAL SECTION: HANFORD SITE Hanford Site Vadose Zone Studies: An Overview  

E-Print Network (OSTI)

a sparsely populated area in the rain shadow of the Cascade Mountains, adjacent to the Columbia River in southeastern Washington State (Fig. 1). The Hanford Site was set aside in the early 1940s by the U.S. Government to perform a top-secret mission, the Manhattan Project, for production of plutonium for atomic weapons used to end World War II and later to support the Cold War with the Soviet Union. Starting in 1943– 1945, Hanford employed thousands of workers on the largest construction project in the world at that time. The workers built a series of nuclear reactors along with large monolithic concrete buildings used to reprocess wastes. Plutonium production continued at Hanford for over 40 yr. During the late 1980s, in the aftermath of the Chernobyl accident, plutonium production was suspended at Hanford (Gephart, 2003). Since then, efforts at

G. W. Gee; M. Oostrom; M. D. Freshley; M. L. Rockhold; J. M. Zachara

2006-01-01T23:59:59.000Z

145

Geophysical monitoring of foam used to deliver remediation treatments within the vadose zone  

E-Print Network (OSTI)

transport in the hanford sediments under hyperalkalinethe Department of Energy (DOE) Hanford site, WA. A centralThe Department of Energy (DOE) Hanford site and elsewhere (

Wu, Y.

2013-01-01T23:59:59.000Z

146

Tensiometer for shallow or deep measurements including vadose zone and aquifers  

DOE Patents (OSTI)

A two cell tensiometer is described in which water level in the lower cell is maintained at a relatively constant height, and in equilibrium with the water pressure of materials that surround the tensiometer. An isolated volume of air in the lower cell changes pressure proportionately to the changing water pressure of the materials that surround the tensiometer. The air pressure is measured remotely. The tensiometer can be used in drying as well as wetting cycles above and below the water table.

Faybishenko, Boris (Berkeley, CA)

1999-01-01T23:59:59.000Z

147

Final draft 20-01-2004 For submittal to Vadose Zone Journal  

E-Print Network (OSTI)

-tortuosity tensor for conduction of water in anisotropi c unsaturated soils. Peter A.C. Raats1 , Z. Fred Zhang2 to stratified soils. Theoretical analysis based on stochastic methods (Yeh et al., 1985) suggests head and water content of the soil decrease. Using the stochastic approach, Polmann et al. (1991

Eindhoven, Technische Universiteit

148

A Hydrologic-geophysical Method for Characterizing Flow and Transport Processes Within The Vadose Zone  

SciTech Connect

The primary purpose of this project was to employ two geophysical imaging techniques, electrical resistivity tomography and cross-borehole ground penetrating radar, to image a controlled infiltration of a saline tracer under unsaturated flow conditions. The geophysical techniques have been correlated to other more traditional hydrologic measurements including neutron moisture measurements and induction conductivity logs. Images that resulted during two successive infiltrations indicate the development of what appear to be preferential pathways through the finer grained materials, although the results could also be produced by cationic capture of free ions in clays. In addition the site as well as the developing solute plume exhibits electrical anisotropy which is likely related to flow properties. However the geologic significance of this phenomenon is still under investigation.

David Alumbaugh; Douglas LaBrecque; James Brainard; T.C. (Jim) Yeh

2004-01-22T23:59:59.000Z

149

Uranium Geochemistry in Vadose Zone and Aquifer Sediments from the 300 Area Uranium Plume  

Science Conference Proceedings (OSTI)

This report documents research conducted by the RCS Project to update the record of decision for the 300-FF-5 Operable Unit on the Hanford Site.

Zachara, John M.; Davis, Jim A.; Liu, Chongxuan; McKinley, James P.; Qafoku, Nik; Wellman, Dawn M.; Yabusaki, Steven B.

2005-07-21T23:59:59.000Z

150

Geophysical monitoring of foam used to deliver remediation treatments within the vadose zone  

E-Print Network (OSTI)

long electrode electrical resistivity. Journal of Applied1991. Hysteresis in the electrical resistivity of partiallyG.E. 1942. The electrical resistivity log as an aid in

Wu, Y.

2013-01-01T23:59:59.000Z

151

INTRODUCTION The remediation of organic chemicals in the vadose zone has been  

E-Print Network (OSTI)

program entitled KU Mix, (2) free-shrinkage tests to evaluate potential LC-HPC mixtures developed for use.......................................................................68 CHAPTER 2: EXPERIMENTAL PROGRAM....................................................69 2.1 GENERAL.....................................................................................................81 #12;vii 2.8 FREE SHRINKAGE TEST PROGRAMS................................................82 2

Hazen, Terry

152

Deep vadose zone hydrology demonstrates fate of nitrate in eastern San Joaquin Valley  

E-Print Network (OSTI)

the experimental site. Sandy loam is the most fre­ quentare: SL1 — recent Hanford sandy loam C — clay, very thinVar2 — various textures, sandy loam to clay loam S — medium

2005-01-01T23:59:59.000Z

153

Vadose Zone Monitoring System Installation Report for McClellan AFB  

E-Print Network (OSTI)

100 ft but the cuttings indicated sandy sediment. The mostwas the predominance of sandy silt in the top 30 ft ofat 0942 • in field: 0 ppm SANDY SILT (ML), with interlayered

Zawislanski, Peter

2010-01-01T23:59:59.000Z

154

OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY  

E-Print Network (OSTI)

.03 0.04 0.05 Sr SAND SILT CLAY Fate and Transport of Sr2+ in Partially-Saturated, Heterogeneous Hanford in Hanford vadose zone inhibits prediction of contaminant mobility, e.g., 90Sr Sr2+ is introduced and other contaminants have migrated into the vadose zone beneath leaking storage tanks at the DOE's Hanford

155

Simulating groundwater transport process using a vertical heterogeneity model: a case study  

Science Conference Proceedings (OSTI)

It is important to simulate a groundwater transport process, e.g., pollutant migration, through the vadose zone and subsequent mixing within the saturated zone to assess potential impacts of contaminants in the subsurface in preliminary stages. It is ...

Samuel S. Lee; Hoh Peter In

2004-10-01T23:59:59.000Z

156

Dorchester County- Renewable Zoning  

Energy.gov (U.S. Department of Energy (DOE))

Dorchester County zoning codes specifically permit solar arrays and small wind turbines in many zoning districts.

157

Student Zone  

NLE Websites -- All DOE Office Websites (Extended Search)

Student Zone Student Zone Homework Helpers All About Atoms - Learn about the parts of the atom! Virginia State Standards of Learning Practice Tests - Practice taking the SOL tests! Subjects currently include algebra, math, science and technology. Table of Elements - Basic physical and historical information about the elements! [Printable Version] Questions and Answers - Have a question? Need an answer? Check here first! Glossary of Science Terms - Definitions of some of the terms used on this site. Jefferson Lab Virtual Tour - How do scientists explore inside atoms? Video Resources Frostbite Theater - Short science experiments using liquid nitrogen, static electricity and more! Physics Out Loud - Jefferson Lab scientists and other experts explain some of the common words and terms used in nuclear physics research.

158

FATE AND TRANSPORT OF RADIONUCLIDES [U(VI), Sr, Cs] IN VADOSE ZONE SEDIMENTS AT THE HANFORD SITE  

E-Print Network (OSTI)

Conference Center (NCC) Lansdowne, Virginia Environmental Remediation Sciences Program (ERSP) This work Hanford IFRC--Zachara ..................................................................................................101 Hanford IFRC

Flury, Markus

159

Coupled Vadose Zone and Atmospheric Surface-Layer Transport of CO2 from Geologic Carbon Sequestration Sites  

E-Print Network (OSTI)

editors, Dense Gas Dispersion, Chemical EngineeringResearch Forum (PERF) Dense Gas Dispersion Modeling Project,on the problem of dense gas dispersion in the surface layer.

Oldenburg, Curtis M.; Unger, Andre J.A.

2004-01-01T23:59:59.000Z

160

FATE AND TRANSPORT OF RADIONUCLIDES [U(VI), Sr, Cs] IN VADOSE ZONE SEDIMENTS AT THE HANFORD SITE .  

E-Print Network (OSTI)

??Physical and chemical heterogeneities are inherent in subsurface environments due to varying: mineralogy, pore geometry, solution saturation, and solute concentration. The goals of this research… (more)

[No author

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

ReproducedfromVadoseZoneJournal.PublishedbySoilScienceSocietyofAmerica.Allcopyrightsreserved. Analytical Solutions for Vertical Flow in Unsaturated, Rooted Soils  

E-Print Network (OSTI)

analytical solutions may be divided into two classes;describe the distribution of pressure head, water for the hydraulic ner, 1958; Warrick, 1975; Lomen and Warrick, 1978; Sri- conductivity and water content as function of the pressure head are vastava and Yeh, 1991; Basha, 2000; Chen et al., 2003), exponential, (ii) the initial

Lu, Zhiming

162

Treatability Test Report: Characterization of Vadose Zone Carbon Tetrachloride Source Strength Using Tomographic Methods at the 216-Z-9 Site  

Science Conference Proceedings (OSTI)

A treatability test was conducted in 2011 at the 216-Z-9 Trench to evaluate methods for collecting characterization information that supports refined assessment of SVE performance goals based on impact to groundwater. The characterization information can also provide input to operational strategies for continued SVE operation and decisions regarding closure of the SVE system or transition to other remedies, if necessary.

Truex, Michael J.; Carroll, Kenneth C.; Rohay, Virginia J.; Mackley, Rob D.; Parker, Kyle R.

2012-09-28T23:59:59.000Z

163

Nuclear-waste isolation in the unsaturated zone of arid regions  

Science Conference Proceedings (OSTI)

The vadose zone in arid regions is considered as a possible environment for geologic isolation of nuclear waste. There are several topographic and lithologic combinations in the vadose zone of arid regions that may lend themselves to waste isolation considerations. In some cases, topographic highs such as mesas and interbasin ranges - comprised of several rock types, may contain essentially dry or partially saturated conditions favorable for isolation. The adjacent basins, especially in the far western and southwestern US, may have no surface or subsurface hydrologic connections with systems ultimately leading to the ocean. Some rock types may have the favorable characteristics of very low permeability and contain appropriate minerals for the strong chemical retardation of radionuclides. Environments exhibiting these hydrologic and geochemical attributes are the areas underlain by tuffaceous rocks, relatively common in the Basin and Range geomorphic province. Adjacent valley areas, where tuffaceous debris makes up a significant component of valley fill alluvium, may also contain thick zones of unsaturated material, and as such also lend themselves to strong consideration as respository environments. This paper summarizes the aspects of nuclear waste isolation in unsaturated regimes in alluvial-filled valleys and tuffaceous rocks of the Basin and Range province.

Wollenberg, H.A.; Wang, J.S.Y.; Korbin, G.

1982-05-01T23:59:59.000Z

164

V12-0159.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

the results of a fi eld test at a 100-m-deep vadose zone test site contaminated with technetium-99 and nitrate. Th e fi eld test confi rmed the results of laboratory...

165

Technology Zones (Virginia)  

Energy.gov (U.S. Department of Energy (DOE))

Virginia’s 26 designated Technology Zones offer tax relief in the form of abatements, credits, deductions, deferrals, exemptions, or rebates. Local governments may designate technology zones to...

166

Enterprise Zone Program (Illinois)  

Energy.gov (U.S. Department of Energy (DOE))

The Enterprise Zone Program provides eligible businesses that relocate or expand to a designated zone with tax incentives such as: 1) an investment tax credit; 2) a job tax credit for each job...

167

MODIFIED ZONE METHOD CALCULATOR  

NLE Websites -- All DOE Office Websites (Extended Search)

Zone Method is recommended for R-value calculations in steel stud walls by the 1997 ASHRAE Handbook of Fundamentals ASHRAE 1997. The Modified Zone Method is similar to the...

168

Reinvestment Zones (Texas)  

Energy.gov (U.S. Department of Energy (DOE))

Reinvestment Zones a local economic development tool used by municipalities and counties throughout the state of Texas. These zones can be created for the purpose of granting local businesses ad...

169

ASHRAE Climate Zones | Open Energy Information  

Open Energy Info (EERE)

ASHRAE Climate Zones Jump to: navigation, search Subtype A Subtype B Subtype C Climate Zone Number 1 Zone 1A Zone 1B NA Climate Zone Number 2 Zone 2A Zone 2B NA Climate Zone...

170

Resources Process Contaminants  

Science Conference Proceedings (OSTI)

General Information on process contaminants(3-MCPD). Reference list included. Resources Process Contaminants 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants dete

171

Process Contaminants (3-MCPD)  

Science Conference Proceedings (OSTI)

General information on process contaminants(3-MCPD). Reference list included. Process Contaminants (3-MCPD) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants deter

172

Method of removing oxidized contaminants from water  

DOE Patents (OSTI)

The present invention is a method for removing oxidized contaminant(s) from water. More specifically, the invention has the steps of contacting water containing the oxidized contaminant(s) with a layered aluminosilicate having Fe(II). The aluminosilicate may contain naturally occurring Fe(II), or the Fe(II) may be produced by reducing Fe(III) that is initially present. Reduction may be either by exposure to a chemical or biological reductant. Contacting the water containing oxidized contaminant(s) may be by (1) injection of Fe(II)-containing layered aluminosilicate, via a well, into a saturated zone where it is likely to intercept the contaminated water; (2) injection of contaminated water into a vessel containing the Fe(II)-bearing layered aluminosilicate; and (3) first reducing Fe(III) in the layered aluminosilicate to Fe(II) by injection of a biological or chemical reductant, into an aquifer or vessel having sufficient Fe(III)-bearing aluminosilicate to produce the necessary Fe(II). 8 figs.

Amonette, J.E.; Fruchter, J.S.; Gorby, Y.A.; Cole, C.R.; Cantrell, K.J.; Kaplan, D.I.

1998-07-21T23:59:59.000Z

173

Method of removing oxidized contaminants from water  

DOE Patents (OSTI)

The present invention is a method for removing oxidized contaminant(s) from water. More specifically, the invention has the steps of contacting water containing the oxidized contaminant(s) with a layered aluminosilicate having Fe(II). The aluminosilicate may contain naturally occurring Fe(II), or the Fe(II) may be produced by reducing Fe(III) that is initially present. Reduction may be either by exposure to a chemical or biological reductant. Contacting the water containing oxidized contaminant(s) may be by (1) injection of Fe(II)-containing layered aluminosilicate, via a well, into a saturated zone where it is likely to intercept the contaminated water; (2) injection of contaminated water into a vessel containing the Fe(II)-bearing layered aluminosilicate; and (3) first reducing Fe(III) in the layered aluminosilicate to Fe(II) by injection of a biological or chemical reductant, into an aquifer or vessel having sufficient Fe(III)-bearing aluminosilicate to produce the necessary Fe(II).

Amonette, James E. (Richland, WA); Fruchter, Jonathan S. (Richland, WA); Gorby, Yuri A. (Richland, WA); Cole, Charles R. (West Richmond, WA); Cantrell, Kirk J. (West Richmond, WA); Kaplan, Daniel I. (Richland, WA)

1998-01-01T23:59:59.000Z

174

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

11 - 15020 of 28,560 results. 11 - 15020 of 28,560 results. Download High Level Waste Corporate Board Charter http://energy.gov/em/downloads/high-level-waste-corporate-board-charter Page Attachment A.1: Summary of Mandatory Language Provisions 1. Regulatory and non-regulatory activities http://energy.gov/em/attachment-a1-summary-mandatory-language-provisions Download Contaminants in Vadose Zone Environments The Deep Vadose Zone - Applied Field Research Initiative has partnered with the Vadose Zone Journal to bring together a special section of the recent issue (November 2012). The section was prepared... http://energy.gov/em/downloads/contaminants-vadose-zone-environments Rebate Interconnection Guidelines '''''Note: Delaware law ([http://delcode.delaware.gov/title26/c010/index.shtml#1014 26 Del. C. §

175

U-PLANT GEOGRAPHIC ZONE CLEANUP PROTOTYPE  

Science Conference Proceedings (OSTI)

The U Plant geographic zone (UPZ) occupies 0.83 square kilometers on the Hanford Site Central Plateau (200 Area). It encompasses the U Plant canyon (221-U Facility), ancillary facilities that supported the canyon, soil waste sites, and underground pipelines. The UPZ cleanup initiative coordinates the cleanup of the major facilities, ancillary facilities, waste sites, and contaminated pipelines (collectively identified as ''cleanup items'') within the geographic zone. The UPZ was selected as a geographic cleanup zone prototype for resolving regulatory, technical, and stakeholder issues and demonstrating cleanup methods for several reasons: most of the area is inactive, sufficient characterization information is available to support decisions, cleanup of the high-risk waste sites will help protect the groundwater, and the zone contains a representative cross-section of the types of cleanup actions that will be required in other geographic zones. The UPZ cleanup demonstrates the first of 22 integrated zone cleanup actions on the Hanford Site Central Plateau to address threats to groundwater, the environment, and human health. The UPZ contains more than 100 individual cleanup items. Cleanup actions in the zone will be undertaken using multiple regulatory processes and decision documents. Cleanup actions will include building demolition, waste site and pipeline excavation, and the construction of multiple, large engineered barriers. In some cases, different cleanup actions may be taken at item locations that are immediately adjacent to each other. The cleanup planning and field activities for each cleanup item must be undertaken in a coordinated and cohesive manner to ensure effective execution of the UPZ cleanup initiative. The UPZ zone cleanup implementation plan (ZCIP) was developed to address the need for a fundamental integration tool for UPZ cleanup. As UPZ cleanup planning and implementation moves forward, the ZCIP is intended to be a living document that will provide a focal point for integrating UPZ actions, including field cleanup activities, waste staging and handling, and post-cleanup monitoring and institutional controls.

ROMINE, L.D.

2006-02-01T23:59:59.000Z

176

Geothermal: Educational Zone  

NLE Websites -- All DOE Office Websites (Extended Search)

GEOTHERMAL TECHNOLOGIES LEGACY COLLECTION - Educational Zone Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us | Admin Log On HomeBasic Search About...

177

Renaissance Zones (North Dakota)  

Energy.gov (U.S. Department of Energy (DOE))

Renaissance Zones allow qualifying businesses and individuals to claim one or more tax incentives for purchasing, leasing, or making improvements to real property located in a North Dakota...

178

Resources for Process Contaminants  

Science Conference Proceedings (OSTI)

Detailed information regarding 3-MCPD esters and a reference list by topic. Resources for Process Contaminants 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certified chemists chloropropanediol contaminants de

179

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Green Energy (OSTI)

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

180

Development Opportunity Zone Credit  

Energy.gov (U.S. Department of Energy (DOE))

The Development Opportunity Zone Credits incent new and expanding businesses in the Cities of Beloit, Janesville and Kenosha by providing non-refundable tax credits to assist with the creation and...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Keystone Opportunity Zones (Pennsylvania)  

Energy.gov (U.S. Department of Energy (DOE))

Keystone Opportunity Zones allows businesses located within designated areas to qualify for a tax exemption, deduction, credit, or abatement of state and local taxes such as sales and use tax,...

182

Estimation of field-scale soil hydraulic and dielectric parameters through joint inversion of GPR and hydrological data  

E-Print Network (OSTI)

Zone Hydraulic Properties for the Hanford Site, Report PNNL-Percolation Theory: Tests of Hanford Site Soils, Vadose Zone200 East Vadose Test Site Hanford, Washington, Electrical

2005-01-01T23:59:59.000Z

183

Queen Anne's County- Solar Zoning  

Energy.gov (U.S. Department of Energy (DOE))

Queen Anne's County zoning code allows for ground mounted solar arrays in areas zoned as "open space," "agricultural," and "countryside" districts.

184

Earth Sciences Division Research Summaries 2006-2007  

E-Print Network (OSTI)

contaminant transport at the Hanford Site, WA. LBNL-61935.contaminant uranium in vadose Hanford formation sediments atthe 200 Area and 300 Area, Hanford Site, Washington. Vadose

DePaolo, Donald

2008-01-01T23:59:59.000Z

185

Isotopic Tracers for Waste Fluid Tracking and Fluid-Soil Interactions: Hanford, Washington  

DOE Green Energy (OSTI)

The objective of this research is to develop and advance isotopic approaches for characterizing fluid flow and chemical transport through the vadose zone to groundwater. Previous research has been concentrated on developing and comparing different isotopic systems (e.g., hydrogen, oxygen and strontium isotopes) for determining fluid infiltration rates and pathways in the vadose zone (e.g., Maher et al., 2003; DePaolo et al., 2004; Singleton et al., in press). The results demonstrate the unique advantage of studies of multiple isotopic systems for distinguishing short-term versus long-term processes. The focus of our current efforts is on using the isotopic compositions of different chemical phases (e.g., uranium, nitrate) to track their movement through the vadose zone. Preliminary results indicate that this will be a powerful tool for assessing environmental risks associated with vadose zone contamination.

DePaolo, Donald J.

2004-06-01T23:59:59.000Z

186

Isotopic Tracers for Waste Fluid Tracking and Fluid-Soil Interactions: Hanford, Washington  

DOE Green Energy (OSTI)

The objective of this research is to develop and advance isotopic methods for characterizing fluid flow and chemical transport through the vadose zone to groundwater. Previous research has been concentrated on developing and comparing different isotopic systems (e.g., hydrogen, oxygen and strontium isotopes) for determining fluid infiltration rates and pathways in the vadose zone (e.g., Maher et al., 2003; DePaolo et al., 2004; Singleton et al., in press). The focus of our current efforts is on using the isotopic compositions of different chemical phases (e.g., uranium, nitrate) to track their movement through the vadose zone. Preliminary results indicate that this will be a powerful tool for assessing environmental risks associated with vadose zone contamination.

DePaolo, Donald J.

2005-06-01T23:59:59.000Z

187

A New Definition of the Virtual Temperature, Valid for the Atmosphere and the CO2-Rich Air of the Vadose Zone  

Science Conference Proceedings (OSTI)

In speleological environments, partial pressures of carbon dioxide (CO2) are often large enough to affect overall air density. Excluding this gas when defining the gas constant for air, a new definition is proposed for the virtual temperature T? ...

Andrew S. Kowalski; Enrique Pérez Sánchez-Cañete

2010-08-01T23:59:59.000Z

188

Hydraulic properties of the vadose zone at two typical sites in the Western Cape for the assessment of groundwater vulnerability to pollution.  

E-Print Network (OSTI)

?? Aquifer vulnerability assessment is increasingly becoming a very significant basis in order to fulfill the water demands in South Africa. Knowledge of soil hydraulic… (more)

Samuels, Donovan.

2007-01-01T23:59:59.000Z

189

Modeling non-steady state radioisotope transport in the vadose zone--A case study using uranium isotopes at Pena Blanca, Mexico  

E-Print Network (OSTI)

seepage at the Nopal I Uranium mine, Chihuahua, Mexico. In:mine adit are composed of welded tuffs that host the uraniumuranium isotopic systematics, we have made additional measurements of U concentrations and 234 U/ 238 U ratios in waters from the mine

Ku, T. L.

2010-01-01T23:59:59.000Z

190

IN-SITU ASSAY OF TRANSURANIC RADIONUCLIDES IN THE VADOSE ZONE USING HIGH-RESOLUTION SPECTRAL GAMMA LOGGING - A HANFORD CASE STUDY  

Science Conference Proceedings (OSTI)

High-resolution spectral gamma logging in steel-cased boreholes is used to detect and quantify transuranic radionuclides in the subsurface. Pu-239, Pu-241, Am-241, and Np-237 are identified based on characteristic decay gammas. Typical minimum detectable levels are on the order of 20 to 40 nCi/g. In intervals of high transuranic concentrations, gamma rays from other sources may complicate analysis and interpretation. Gamma rays detected in the borehole may originate from three sources: decay of the parent transuranic radionuclide or a daughter; alpha interactions; and interactions with neutrons resulting from either spontaneous fission or alpha particle interactions.

ROHAY VJ; HENWOOD P; MCCAIN R

2009-11-30T23:59:59.000Z

191

Modeling non-steady state radioisotope transport in the vadose zone--A case study using uranium isotopes at Pena Blanca, Mexico  

E-Print Network (OSTI)

T.L. (2000) In-situ radionuclide transport and preferentialseries constraints on radionuclide transport and groundwater1998) Assessing in-situ radionuclide migration from natural

Ku, T. L.

2010-01-01T23:59:59.000Z

192

Subduction Zone | Open Energy Information  

Open Energy Info (EERE)

Subduction Zone Subduction Zone Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Subduction Zone Dictionary.png Subduction Zone: A tectonic process in which one tectonic plate is forced beneath another and sinks into the mantle as the plates converge Other definitions:Wikipedia Reegle Tectonic Settings List of tectonic settings known to host modern geothermal systems: Extensional Tectonics Subduction Zone Rift Zone Hot Spot Non-Tectonic Strike-Slip A classic cartoon illustrating a typical simplified subduction zone. http://www.columbia.edu/~vjd1/subd_zone_basic.htm Subduction zones occur where one tectonic plate is pulled under another. Most often the subducting plate is oceanic crust and contains many hydrous minerals. As the oceanic plate subducts it dewaters into the mantle,

193

Tritium Surface Contamination  

SciTech Connect

Glovebox wipe surveys were conducted to correlate surface tritium contamination with atmospheric tritium levels. Surface contamination was examined as a function of tritium concentration and of tritium form, HT/T2 and HTO. The relationship between atmospheric HTO concentration and cleanup time was also investigated.

Sienkiewicz, Charles J.

1985-04-01T23:59:59.000Z

194

Contamination Control Techniques  

SciTech Connect

Welcome to a workshop on contamination Control techniques. This work shop is designed for about two hours. Attendee participation is encouraged during the workshop. We will address different topics within contamination control techniques; present processes, products and equipment used here at Hanford and then open the floor to you, the attendees for your input on the topics.

EBY, J.L.

2000-05-16T23:59:59.000Z

195

Bioremediation of contaminated groundwater  

DOE Patents (OSTI)

Disclosed is an apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid (NF) is selected to simulated the growth and reproduction of indigenous subsurface microorganisms capable of degrading the contaminants; an oxygenated fluid (OF) is selected to create an aerobic environment with anaerobic pockets. NF is injected periodically while OF is injected continuously and both are extracted so that both are drawn across the plume. NF stimulates microbial colony growth; withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is acceptable. NF can be methane and OF be air, for stimulating production of methanotrophs to break down chlorohydrocarbons, especially TCE and tetrachloroethylene.

Hazen, T.C.; Fliermans, C.B.

1994-01-01T23:59:59.000Z

196

Accommodation Zone | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » Accommodation Zone Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Accommodation Zone Dictionary.png Accommodation Zone: Accommodation zones occur at fault intersections consisting of belts of interlocking, oppositely dipping normal faults. Multiple subsurface fault intersections in these zones are a favorable host for geothermal activity. Other definitions:Wikipedia Reegle Controlling Structures List of controlling structures typically associated with geothermal systems: Major Normal Fault Termination of a Major Normal Fault Stepover or Relay Ramp in Normal Fault Zones

197

Simulating the Upper Barren Zone and the Ore Zone tests performed with the EMC logging tool  

SciTech Connect

The primary purpose of the Multispectral Nuclear Logging project is to assess the effectiveness of applying nuclear borehole-logging techniques to the Department of Energy`s (DOE) Environmental Restoration (ER) program, adapt the technology to improve these capabilities, and transfer that technology to industry. The purpose of the Monte Carlo simulations using MCNP is to predict the minimum concentration levels for environmental contaminants that could be detected by Multispectral Logging (MSL). The Monte Carlo code used for this type of simulation, MCNP, should be benchmarked against experimental data to show that the user can accurately reproduce the proper gamma-ray spectrum. Experimental data was obtained from Westinghouse-Hanford Company using the Environmental Measurements Corp. (EMC) logging tool in the Upper Barren Zone (UBZ) and Ore Zone (OZ) calibration models at Grand Junction. This paper continues the discussion of benchmarking MCNP using the UBZ and OZ data.

Frankle, S.C.

1994-09-01T23:59:59.000Z

198

Building Technologies Office: Climate Zones  

NLE Websites -- All DOE Office Websites (Extended Search)

Climate Zones to Climate Zones to someone by E-mail Share Building Technologies Office: Climate Zones on Facebook Tweet about Building Technologies Office: Climate Zones on Twitter Bookmark Building Technologies Office: Climate Zones on Google Bookmark Building Technologies Office: Climate Zones on Delicious Rank Building Technologies Office: Climate Zones on Digg Find More places to share Building Technologies Office: Climate Zones on AddThis.com... About Take Action to Save Energy Partner With DOE Activities Solar Decathlon Building America Research Innovations Research Tools Building Science Education Climate-Specific Guidance Solution Center Partnerships Meetings Publications Home Energy Score Home Performance with ENERGY STAR Better Buildings Neighborhood Program Challenge Home Guidelines for Home Energy Professionals

199

Rift Zone | Open Energy Information  

Open Energy Info (EERE)

Rift Zone Rift Zone Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Rift Zone Dictionary.png Rift Zone: A divergent plate boundary within a continent Other definitions:Wikipedia Reegle Tectonic Settings List of tectonic settings known to host modern geothermal systems: Extensional Tectonics Subduction Zone Rift Zone Hot Spot Non-Tectonic Strike-Slip The Rio Grande Rift exemplifies rift zone tectonics - increased volcanic activity and the formation of graben structures (reference: science-art.com) Rift valleys occur at divergent plate boundaries, resulting in large graben structures and increased volcanism. The East African Rift is an example of a continental rift zone with increased volcanism, while the Atlantic's spreading Mid-Ocean Ridge is host to an enormous amount of geothermal

200

The Enterprise Zone (Rhode Island)  

Energy.gov (U.S. Department of Energy (DOE))

The Enterprise Zone offers tax incentives to business expanding their workforce by 5% at facilities in designated enterprise zones. The tax credit is equal to 50% of the annual wages paid to a new...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Radiant zone heated particulate filter  

DOE Patents (OSTI)

A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

Gonze, Eugene V [Pinckney, MI

2011-12-27T23:59:59.000Z

202

The Bladon Lysimeter: An Innovative Environmental Characterization Technology  

SciTech Connect

Chemical analysis of groundwater samples is the baseline method of characterizing and monitoring groundwater contamination in the vadose (unsaturated) zone at most waste sites. Contamination moving from the surface to the water table passes through an unsaturated zone that can range in thickness from a few inches to hundreds of feet at a give site. Lysimeters are samplers that are designed to apply suction to the subsurface and are typically used to collect groundwater in the unsaturated zone.

Eddy-Dilek, C.A.

2000-12-15T23:59:59.000Z

203

CO2 Emissions - Panama Canal Zone  

NLE Websites -- All DOE Office Websites (Extended Search)

Panama Canal Zone Graphics CO2 Emissions from Panama Canal Zone Data graphic Data CO2 Emissions from Panama Canal Zone...

204

Transition Zone Geothermal Region | Open Energy Information  

Open Energy Info (EERE)

Transition Zone Geothermal Region (Redirected from Transition Zone) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Transition Zone Geothermal Region edit Details...

205

Modeling for Airborne Contamination  

SciTech Connect

The objective of Modeling for Airborne Contamination (referred to from now on as ''this report'') is to provide a documented methodology, along with supporting information, for estimating the release, transport, and assessment of dose to workers from airborne radioactive contaminants within the Monitored Geologic Repository (MGR) subsurface during the pre-closure period. Specifically, this report provides engineers and scientists with methodologies for estimating how concentrations of contaminants might be distributed in the air and on the drift surfaces if released from waste packages inside the repository. This report also provides dose conversion factors for inhalation, air submersion, and ground exposure pathways used to derive doses to potentially exposed subsurface workers. The scope of this report is limited to radiological contaminants (particulate, volatile and gaseous) resulting from waste package leaks (if any) and surface contamination and their transport processes. Neutron activation of air, dust in the air and the rock walls of the drift during the preclosure time is not considered within the scope of this report. Any neutrons causing such activation are not themselves considered to be ''contaminants'' released from the waste package. This report: (1) Documents mathematical models and model parameters for evaluating airborne contaminant transport within the MGR subsurface; and (2) Provides tables of dose conversion factors for inhalation, air submersion, and ground exposure pathways for important radionuclides. The dose conversion factors for air submersion and ground exposure pathways are further limited to drift diameters of 7.62 m and 5.5 m, corresponding to the main and emplacement drifts, respectively. If the final repository design significantly deviates from these drift dimensions, the results in this report may require revision. The dose conversion factors are further derived by using concrete of sufficient thickness to simulate the drift walls. The gamma-ray scattering properties of concrete are sufficiently similar to those of the host rock and proposed insert material; use of concrete will have no significant impact on the conclusions. The information in this report is presented primarily for use in performing pre-closure radiological safety evaluations of radiological contaminants, but it may also be used to develop strategies for contaminant leak detection and monitoring in the MGR. Included in this report are the methods for determining the source terms and release fractions, and mathematical models and model parameters for contaminant transport and distribution within the repository. Various particle behavior mechanisms that affect the transport of contaminant are included. These particle behavior mechanisms include diffusion, settling, resuspension, agglomeration and other deposition mechanisms.

F.R. Faillace; Y. Yuan

2000-08-31T23:59:59.000Z

206

Bioremediation of contaminated groundwater  

DOE Patents (OSTI)

The present invention relates to a method for in situ bioremediation of contaminated soil and groundwater. In particular, the invention relates to remediation of contaminated soil and groundwater by the injection of nutrients to stimulate growth of pollutant-degrading microorganisms. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

Hazen, T.C.; Fliermans, C.B.

1992-12-31T23:59:59.000Z

207

Field testing plan for unsaturated zone monitoring and field studies  

Science Conference Proceedings (OSTI)

The University of Arizona, in cooperation with the Bureau of Economic Geology at The University of Texas at Austin, and Stephens and Associates in Albuquerque, New Mexico has developed a field testing plan for evaluating subsurface monitoring systems. The U.S. Nuclear Regulatory Commission has requested development of these testing plans for low-level radioactive waste disposal sites (LLW) and for monitoring at decommissioned facilities designated under the {open_quotes}Site Decommissioning Management Plan{close_quotes} (SDMP). The tests are conducted on a 50 m by 50 m plot on the University of Arizona`s Maricopa Agricultural Center. Within the 50 m by 50 m plot one finds: (1) an instrumented buried trench, (2) monitoring islands similar to those proposed for the Ward Valley, California LLW Facility, (3) deep borehole monitoring sites, (4) gaseous transport monitoring, and (5) locations for testing non-invasive geophysical measurement techniques. The various subplot areas are instrumented with commercially available instruments such as neutron probes, time domain reflectometry probes, tensiometers, psychrometers, heat dissipation sensors, thermocouples, solution samplers, and cross-hole geophysics electrodes. Measurement depths vary from ground surface to 15 m. The data from the controlled flow and transport experiments, conducted over the plot, will be used to develop an integrated approach to long-term monitoring of the vadose zone at waste disposal sites. The data will also be used to test field-scale flow and transport models. This report describes in detail the design of the experiment and the methodology proposed for evaluating the data.

Young, M.H.; Wierenga, P.J.; Warrick, A.W. [and others

1996-10-01T23:59:59.000Z

208

Liquid zone seal  

DOE Patents (OSTI)

A seal assembly that provides a means for establishing multiple pressure zones within a system. The seal assembly combines a plate extending from the inner wall of a housing or inner enclosure that intersects with and is immersed in the fluid contained in a well formed in a tray contained within the enclosure. The fluid is a low vapor pressure oil, chemically inert and oxidation resistant. The use of a fluid as the sealing component provides a seal that is self-healing and mechanically robust not subject to normal mechanical wear, breakage, and formation of cracks or pinholes and decouples external mechanical vibrations from internal structural members.

Klebanoff, Leonard E. (Dublin, CA)

2001-01-01T23:59:59.000Z

209

Laboratory and Modeling Evaluations in Support of Field Testing for Desiccation at the Hanford Site  

SciTech Connect

The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau includes testing of the desiccation technology as a potential technology to be used in conjunction with surface infiltration control to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. Laboratory and modeling efforts were conducted to investigate technical uncertainties related to the desiccation process and its impact on contaminant transport. This information is intended to support planning, operation, and interpretation of a field test for desiccation in the Hanford Central Plateau.

Truex, Michael J.; Oostrom, Martinus; Freedman, Vicky L.; Strickland, Christopher E.; Wietsma, Thomas W.; Tartakovsky, Guzel D.; Ward, Anderson L.

2011-02-23T23:59:59.000Z

210

HTO Contamination on Polymeric Materials  

Science Conference Proceedings (OSTI)

Contamination and Waste / Proceedings of the Ninth International Conference on Tritium Science and Technology

Yasunori Iwai; Kazuhiro Kobayashi; Toshihiko Yamanishi

211

Climate Zone 5C | Open Energy Information  

Open Energy Info (EERE)

Climate Zone 5C Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 5 and Climate Zone Subtype C. Climate Zone...

212

Areawide chemical contamination  

SciTech Connect

Nine case histories illustrate the mounting problems owing to chemical contamination that often extends beyond the workplace into the community. The effects include not only carcinogenesis and teratogenesis, so much in the public's mind, but also severe neurological and gonadal disabilities immediately after exposure. Recognition of causal relationships is often made by astute clinicians. The experience of the Atomic Bomb Casualty Commission in studying Japanese survivors in Hiroshima and Nagasaki serves as a model for future studies of communities exposed to unusual environmental contamination.

Miller, R.W.

1981-04-17T23:59:59.000Z

213

Breathing zone air sampler  

DOE Patents (OSTI)

A sampling apparatus is provided which comprises a sampler for sampling air in the breathing zone of a wearer of the apparatus and a support for the sampler preferably in the form of a pair of eyeglasses. The sampler comprises a sampling assembly supported on the frame of the eyeglasses and including a pair of sample transport tubes which are suspended, in use, centrally of the frame so as to be disposed on opposite sides of the nose of the wearer and which each include an inlet therein that, in use, is disposed adjacent to a respective nostril of the nose of the wearer. A filter holder connected to sample transport tubes supports a removable filter for filtering out particulate material in the air sampled by the apparatus. The sample apparatus is connected to a pump for drawing air into the apparatus through the tube inlets so that the air passes through the filter.

Tobin, John (Bethel Park, PA)

1989-01-01T23:59:59.000Z

214

Western Renewable Energy Zones (Presentation)  

DOE Green Energy (OSTI)

This presentation summarizes recent developments and trends pertaining to competitive renewable energy zones, transmission planning and the integration of renewable generation resources.

Hein, J.

2011-06-01T23:59:59.000Z

215

DOE Solar Decathlon: Comfort Zone  

NLE Websites -- All DOE Office Websites (Extended Search)

Decathlon Comfort Zone Contest, teams design their houses to keep temperature and humidity steady, uniform, and comfortable. Full points are awarded for maintaining narrow...

216

Interfacial Transition Zone Bibliography Database  

Science Conference Proceedings (OSTI)

... Saito, M., and Kawamura, M., Effect of Fly Ash and Slag on the Interfacial Zone Between Cement and Aggregate , in ACI SP 114: Fly Ash, Silica ...

2013-05-14T23:59:59.000Z

217

EM News | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

April 24, 2012 April 24, 2012 Conceptual site model for evaluating soil vapor extraction system performance to determine if the system should be optimized, terminated, or transitioned to another approach. New Approach to Assess Volatile Contamination in Vadose Zone Provides Path Forward for Site Closure RICHLAND, Wash. and LOS ALAMOS, N.M. - Through the Deep Vadose Zone-Applied Field Research Initiative (DVZ-AFRI), scientists and engineers from Pacific Northwest National Laboratory, CH2M HILL Plateau Remediation Company, federal agencies, and the scientific community are collaborating to develop effective, science-based solutions for remediating, characterizing, monitoring, and predicting the behavior and fate of deep vadose zone contamination. April 23, 2012 A controlled, phased

218

Laboratory Activities  

Science Conference Proceedings (OSTI)

This chapter summarizes the laboratory activities performed by PNNL’s Vadose Zone Characterization Project in support of the Tank Farm Vadose Zone Program, led by CH2M HILL Hanford Group, Inc. The results of these studies are contained in numerous reports (Lindenmeier et al. 2002; Serne et al. 2002a, 2002b, 2002c, 2002d, 2002e; Lindenmeier et al. 2003; Serne et al. 2004a, 2004b; Brown et al. 2005, 2006a, 2007; Serne et al. 2007) and have generated much of the data reported in Chapter 22 (Geochemistry-Contaminant Movement), Appendix G (Geochemistry-Contaminant Movement), and Cantrell et al. (2007, SST WMA Geochemistry Data Package – in preparation). Sediment samples and characterization results from PNNL’s Vadose Zone Characterization Project are also shared with other science and technology (S&T) research projects, such as those summarized in Chapter 12 (Associated Science Activities).

Brown, Christopher F.; Serne, R. Jeffrey

2008-01-17T23:59:59.000Z

219

Mercury contamination extraction  

DOE Patents (OSTI)

Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

Fuhrmann, Mark (Silver Spring, MD); Heiser, John (Bayport, NY); Kalb, Paul (Wading River, NY)

2009-09-15T23:59:59.000Z

220

Subsurface Contamination Control  

Science Conference Proceedings (OSTI)

There are two objectives of this report, ''Subsurface Contamination Control''. The first is to provide a technical basis for recommending limiting radioactive contamination levels (LRCL) on the external surfaces of waste packages (WP) for acceptance into the subsurface repository. The second is to provide an evaluation of the magnitude of potential releases from a defective WP and the detectability of the released contents. The technical basis for deriving LRCL has been established in ''Retrieval Equipment and Strategy for Wp on Pallet'' (CRWMS M and O 2000g, 6.3.1). This report updates the derivation by incorporating the latest design information of the subsurface repository for site recommendation. The derived LRCL on the external surface of WPs, therefore, supercede that described in CRWMS M and O 2000g. The derived LRCL represent the average concentrations of contamination on the external surfaces of each WP that must not be exceeded before the WP is to be transported to the subsurface facility for emplacement. The evaluation of potential releases is necessary to control the potential contamination of the subsurface repository and to detect prematurely failed WPs. The detection of failed WPs is required in order to provide reasonable assurance that the integrity of each WP is intact prior to MGR closure. An emplaced WP may become breached due to manufacturing defects or improper weld combined with failure to detect the defect, by corrosion, or by mechanical penetration due to accidents or rockfall conditions. The breached WP may release its gaseous and volatile radionuclide content to the subsurface environment and result in contaminating the subsurface facility. The scope of this analysis is limited to radioactive contaminants resulting from breached WPs during the preclosure period of the subsurface repository. This report: (1) documents a method for deriving LRCL on the external surfaces of WP for acceptance into the subsurface repository; (2) provides a table of derived LRCL for nuclides of radiological importance; (3) Provides an as low as is reasonably achievable (ALARA) evaluation of the derived LRCL by comparing potential onsite and offsite doses to documented ALARA requirements; (4) Provides a method for estimating potential releases from a defective WP; (5) Provides an evaluation of potential radioactive releases from a defective WP that may become airborne and result in contamination of the subsurface facility; and (6) Provides a preliminary analysis of the detectability of a potential WP leak to support the design of an airborne release monitoring system.

Y. Yuan

2001-12-12T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Subsurface Contamination Control  

Science Conference Proceedings (OSTI)

There are two objectives of this report, ''Subsurface Contamination Control''. The first is to provide a technical basis for recommending limiting radioactive contamination levels (LRCL) on the external surfaces of waste packages (WP) for acceptance into the subsurface repository. The second is to provide an evaluation of the magnitude of potential releases from a defective WP and the detectability of the released contents. The technical basis for deriving LRCL has been established in ''Retrieval Equipment and Strategy for Wp on Pallet'' (CRWMS M and O 2000g, 6.3.1). This report updates the derivation by incorporating the latest design information of the subsurface repository for site recommendation. The derived LRCL on the external surface of WPs, therefore, supercede that described in CRWMS M and O 2000g. The derived LRCL represent the average concentrations of contamination on the external surfaces of each WP that must not be exceeded before the WP is to be transported to the subsurface facility for emplacement. The evaluation of potential releases is necessary to control the potential contamination of the subsurface repository and to detect prematurely failed WPs. The detection of failed WPs is required in order to provide reasonable assurance that the integrity of each WP is intact prior to MGR closure. An emplaced WP may become breached due to manufacturing defects or improper weld combined with failure to detect the defect, by corrosion, or by mechanical penetration due to accidents or rockfall conditions. The breached WP may release its gaseous and volatile radionuclide content to the subsurface environment and result in contaminating the subsurface facility. The scope of this analysis is limited to radioactive contaminants resulting from breached WPs during the preclosure period of the subsurface repository. This report: (1) documents a method for deriving LRCL on the external surfaces of WP for acceptance into the subsurface repository; (2) provides a table of derived LRCL for nuclides of radiological importance; (3) Provides an as low as is reasonably achievable (ALARA) evaluation of the derived LRCL by comparing potential onsite and offsite doses to documented ALARA requirements; (4) Provides a method for estimating potential releases from a defective WP; (5) Provides an evaluation of potential radioactive releases from a defective WP that may become airborne and result in contamination of the subsurface facility; and (6) Provides a preliminary analysis of the detectability of a potential WP leak to support the design of an airborne release monitoring system.

Y. Yuan

2001-11-16T23:59:59.000Z

222

Zone refining of plutonium metal  

Science Conference Proceedings (OSTI)

The zone refining process was applied to Pu metal containing known amounts of impurities. Rod specimens of plutonium metal were melted into and contained in tantalum boats, each of which was passed horizontally through a three-turn, high-frequency coil in such a manner as to cause a narrow molten zone to pass through the Pu metal rod 10 times. The impurity elements Co, Cr, Fe, Ni, Np, U were found to move in the same direction as the molten zone as predicted by binary phase diagrams. The elements Al, Am, and Ga moved in the opposite direction of the molten zone as predicted by binary phase diagrams. As the impurity alloy was zone refined, {delta}-phase plutonium metal crystals were produced. The first few zone refining passes were more effective than each later pass because an oxide layer formed on the rod surface. There was no clear evidence of better impurity movement at the slower zone refining speed. Also, constant or variable coil power appeared to have no effect on impurity movement during a single run (10 passes). This experiment was the first step to developing a zone refining process for plutonium metal.

Blau, M.S.

1994-08-01T23:59:59.000Z

223

In-Situ Contained And Of Volatile Soil Contaminants  

DOE Patents (OSTI)

The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

Varvel, Mark Darrell (Idaho Falls, ID)

2005-12-27T23:59:59.000Z

224

In-Situ Containment and Extraction of Volatile Soil Contaminants  

DOE Patents (OSTI)

The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

Varvel, Mark Darrell

2005-12-27T23:59:59.000Z

225

Purifying contaminated water  

DOE Patents (OSTI)

Process for removing biorefractory compounds from contaminated water (e.g., oil shale retort waste-water) by contacting same with fragmented raw oil shale. Biorefractory removal is enhanced by preactivating the oil shale with at least one member of the group of carboxylic, acids, alcohols, aldehydes, ketones, ethers, amines, amides, sulfoxides, mixed ether-esters and nitriles. Further purification is obtained by stripping, followed by biodegradation and removal of the cells.

Daughton, Christian G. (San Pablo, CA)

1983-01-01T23:59:59.000Z

226

Impact of nonaqueous phase liquid (NAPL) source zone architecture on mass removal mechanisms in strongly layered heterogeneous porous media during soil vapor extraction  

Science Conference Proceedings (OSTI)

An existing multiphase flow simulator was modified in order to determine the effects of four mechanisms on NAPL mass removal in a strongly layered heterogeneous vadose zone during soil vapor extraction (SVE): a) NAPL flow, b) diffusion and dispersion from low permeability zones, c) slow desorption from sediment grains, and d) rate-limited dissolution of trapped NAPL. The impact of water and NAPL saturation distribution, NAPL type (i.e., free, residual, or trapped) distribution, and spatial heterogeneity of the permeability field on these mechanisms were evaluated. Two different initial source zone architectures (one with and one without trapped NAPL) were considered and these architectures were used to evaluate seven different SVE scenarios. For all runs, slow diffusion from low permeability zones that gas flow bypassed was a dominant factor for diminished SVE effectiveness at later times. This effect was more significant at high water saturation due to the decrease of gas-phase relative permeability. Transverse dispersion contributed to fast NAPL mass removal from the low permeability layer in both source zone architectures, but longitudinal dispersion did not affect overall mass removal time. Both slow desorption from sediment grains and rate-limited mass transfer from trapped NAPL only marginally affected removal times. However, mass transfer from trapped NAPL did affect mass removal at late time, as well as the NAPL distribution. NAPL flow from low to high permeability zones contributed to faster mass removal from the low permeability layer, and this effect increased when water infiltration was eliminated. These simulations indicate that if trapped NAPL exists in heterogeneous porous media, mass transfer can be improved by delivering gas directly to zones with trapped NAPL and by lowering the water content, which increases the gas relative permeability and changes trapped NAPL to free NAPL.

Yoon, Hongkyu; Werth, Charlie; Valocchi, Albert J.; Oostrom, Martinus

2008-09-26T23:59:59.000Z

227

Contamination control device  

DOE Patents (OSTI)

A contamination control device for use in a gas-insulated transmission bus consisting of a cylindrical center conductor coaxially mounted within a grounded cylindrical enclosure. The contamination control device is electrically connected to the interior surface of the grounded outer shell and positioned along an axial line at the lowest vertical position thereon. The contamination control device comprises an elongated metallic member having a generally curved cross-section in a first plane perpendicular to the axis of the bus and having an arcuate cross-section in a second plane lying along the axis of the bus. Each opposed end of the metallic member and its opposing sides are tapered to form a pair of generally converging and downward sloping surfaces to trap randomly moving conductive particles in the relatively field-free region between the metallic member and the interior surface of the grounded outer shell. The device may have projecting legs to enable the device to be spot welded to the interior of the grounded housing. The control device provides a high capture probability and prevents subsequent release of the charged particles after the capture thereof.

Clark, Robert M. (Ligonier, PA); Cronin, John C. (Greensburg, PA)

1977-01-01T23:59:59.000Z

228

Understanding Contamination; Twenty Years of Simulating Radiological Contamination  

SciTech Connect

A wide variety of simulated contamination methods have been developed by researchers to reproducibly test radiological decontamination methods. Some twenty years ago a method of non-radioactive contamination simulation was proposed at the Idaho National Laboratory (INL) that mimicked the character of radioactive cesium and zirconium contamination on stainless steel. It involved baking the contamination into the surface of the stainless steel in order to 'fix' it into a tenacious, tightly bound oxide layer. This type of contamination was particularly applicable to nuclear processing facilities (and nuclear reactors) where oxide growth and exchange of radioactive materials within the oxide layer became the predominant model for material/contaminant interaction. Additional simulation methods and their empirically derived basis (from a nuclear fuel reprocessing facility) are discussed. In the last ten years the INL, working with the Defense Advanced Research Projects Agency (DARPA) and the National Homeland Security Research Center (NHSRC), has continued to develop contamination simulation methodologies. The most notable of these newer methodologies was developed to compare the efficacy of different decontamination technologies against radiological dispersal device (RDD, 'dirty bomb') type of contamination. There are many different scenarios for how RDD contamination may be spread, but the most commonly used one at the INL involves the dispersal of an aqueous solution containing radioactive Cs-137. This method was chosen during the DARPA projects and has continued through the NHSRC series of decontamination trials and also gives a tenacious 'fixed' contamination. Much has been learned about the interaction of cesium contamination with building materials, particularly concrete, throughout these tests. The effects of porosity, cation-exchange capacity of the material and the amount of dirt and debris on the surface are very important factors. The interaction of the contaminant/substrate with the particular decontamination technology is also very important. Results of decontamination testing from hundreds of contaminated coupons have lead to certain conclusions about the contamination and the type of decontamination methods being deployed. A recent addition to the DARPA initiated methodology simulates the deposition of nuclear fallout. This contamination differs from previous tests in that it has been developed and validated purely to simulate a 'loose' type of contamination. This may represent the first time that a radiologically contaminated 'fallout' stimulant has been developed to reproducibly test decontamination methods. While no contaminant/methodology may serve as a complete example of all aspects that could be seen in the field, the study of this family of simulation methods provides insight into the nature of radiological contamination.

Emily Snyder; John Drake; Ryan James

2012-02-01T23:59:59.000Z

229

Cleaning oil contaminated beaches with chemicals  

SciTech Connect

Oil-dispersing chemicals were treated for cleaning persistent-type crude oil from experimentally contaminated New Jersey coastal beaches and were found to be generally ineffective. Although they completely cleaned the surface of the oiled sand, they removed little of the total oil. Instead they caused the oil to penetrate more deeply into the underlying sand, thereby compounding the pollution problem by expanding the zone of pollution, complicating any subsequent mechanical removal and, possibly, causing the oil to persist longer. Chemical treatment failed to induce quicksand or cause perceptible erosion of beach sand. A decrease in the cohesiveness of the sand was observed, but this also occurred in the presence of oil alone and could not be attributed to the presence of chemical.

1969-08-01T23:59:59.000Z

230

Climate Zone 1B | Open Energy Information  

Open Energy Info (EERE)

search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 1 and Climate Zone Subtype B. Climate Zone 1B is defined as Dry with...

231

Climate Zone 8B | Open Energy Information  

Open Energy Info (EERE)

search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 8 and Climate Zone Subtype B. Climate Zone 8B is defined as Subarctic...

232

Climate Zones | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Residential Buildings » Building America » Climate Zones Residential Buildings » Building America » Climate Zones Climate Zones Building America determines building practices based on climate zones to achieve the most energy savings in a home. This page offers some general guidelines on the definitions of the various climate regions based on heating degree-days, average temperatures, and precipitation. You can also view the Guide to Determining Climate Regions by County. Hot-Humid A hot-humid climate is generally defined as a region that receives more than 20 in. (50 cm) of annual precipitation and where one or both of the following occur: A 67°F (19.5°C) or higher wet bulb temperature for 3,000 or more hours during the warmest 6 consecutive months of the year; or A 73°F (23°C) or higher wet bulb temperature for 1,500 or more

233

Alternative Energy Zone (Ohio) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Alternative Energy Zone (Ohio) Alternative Energy Zone (Ohio) < Back Eligibility Local Government StateProvincial Govt Savings Category Buying & Making Electricity Water Home...

234

Transition Zone Geothermal Region | Open Energy Information  

Open Energy Info (EERE)

Transition Zone Geothermal Region Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Transition Zone Geothermal Region edit Details Areas (5) Power Plants (0) Projects...

235

Table C10A. Consumption and Gross Energy Intensity by Climate Zone ...  

U.S. Energy Information Administration (EIA)

Zone 1 Zone 2 Zone 3 Zone 4 Zone 5 Zone 1 Zone 2 Zone 3 Zone 4 Zone 5 Zone 1 Zone 2 Zone 3 Zone 4 Zone 5 All Buildings ..... 1,086 1,929 1,243 1,386 879 11,529 ...

236

Visual Data Analysis as an Integral Part of Environmental Management  

E-Print Network (OSTI)

to understand and predict the fate of nuclear contaminants and their transport in natural and engineered systems. Geologists, hydrologists, physicists and computer scientists are working together to create models in the direction of a nearby creek [3]. The Deep Vadose Zone (Hanford Site) is located near Richland, Washington [4

Hubbard, Susan

237

DOE/RL-2010-89 Review Copy October 1, 2010  

E-Print Network (OSTI)

investments from different DOE organizations working in basic science, applied research, and site engineering the contaminant cleanup challenges facing the deep vadose zone beneath the Central Plateau of the Hanford Site was the location of Hanford's major uranium fuel reprocessing, waste management, and liquid disposal facilities

Hubbard, Susan

238

VZCOMML©, Version 4.0  

A researcher at the Savannah River Site has developed an analytical software application to simulate contaminant fate and transport through the vadose zone to groundwater.  VZCOMML© (pronounced Vee-Zee-Com-M-L) is a one-dimensional, three-phase ...

239

Contaminated nickel scrap processing  

Science Conference Proceedings (OSTI)

The DOE will soon choose between treating contaminated nickel scrap as a legacy waste and developing high-volume nickel decontamination processes. In addition to reducing the volume of legacy wastes, a decontamination process could make 200,000 tons of this strategic metal available for domestic use. Contaminants in DOE nickel scrap include {sup 234}Th, {sup 234}Pa, {sup 137}Cs, {sup 239}Pu (trace), {sup 60}Co, U, {sup 99}Tc, and {sup 237}Np (trace). This report reviews several industrial-scale processes -- electrorefining, electrowinning, vapormetallurgy, and leaching -- used for the purification of nickel. Conventional nickel electrolysis processes are particularly attractive because they use side-stream purification of process solutions to improve the purity of nickel metal. Additionally, nickel purification by electrolysis is effective in a variety of electrolyte systems, including sulfate, chloride, and nitrate. Conventional electrorefining processes typically use a mixed electrolyte which includes sulfate, chloride, and borate. The use of an electrorefining or electrowinning system for scrap nickel recovery could be combined effectively with a variety of processes, including cementation, solvent extraction, ion exchange, complex-formation, and surface sorption, developed for uranium and transuranic purification. Selected processes were reviewed and evaluated for use in nickel side-stream purification. 80 refs.

Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Johnson, J.S. Jr.; Wilson, D.F.

1994-12-01T23:59:59.000Z

240

JV Task 99-Integrated Risk Analysis and Contaminant Reduction, Watford City, North Dakota  

SciTech Connect

The Energy & Environmental Research Center (EERC) conducted a limited site investigation and risk analyses for hydrocarbon-contaminated soils and groundwater at a Construction Services, Inc., site in Watford City, North Dakota. Site investigation confirmed the presence of free product and high concentrations of residual gasoline-based contaminants in several wells, the presence of 1,2-dichloroethane, and extremely high levels of electrical conductivity indicative of brine residuals in the tank area south of the facility. The risk analysis was based on compilation of information from the site-specific geotechnical investigation, including multiphase extraction pilot test, laser induced fluorescence probing, evaluation of contaminant properties, receptor survey, capture zone analysis and evaluation of well head protection area for municipal well field. The project results indicate that the risks associated with contaminant occurrence at the Construction Services, Inc. site are low and, under current conditions, there is no direct or indirect exposure pathway between the contaminated groundwater and soils and potential receptors.

Jaroslav Solc; Barry W. Botnen

2007-05-31T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Category:ASHRAE Climate Zones | Open Energy Information  

Open Energy Info (EERE)

ASHRAE Climate Zones ASHRAE Climate Zones Jump to: navigation, search Climate Zones defined in the ASHRAE 169-2006 standards. Pages in category "ASHRAE Climate Zones" The following 30 pages are in this category, out of 30 total. C Climate Zone 1A Climate Zone 1B Climate Zone 2A Climate Zone 2B Climate Zone 3A Climate Zone 3B Climate Zone 3C Climate Zone 4A Climate Zone 4B Climate Zone 4C C cont. Climate Zone 5A Climate Zone 5B Climate Zone 5C Climate Zone 6A Climate Zone 6B Climate Zone 7A Climate Zone 7B Climate Zone 8A Climate Zone 8B Climate Zone Number 1 C cont. Climate Zone Number 2 Climate Zone Number 3 Climate Zone Number 4 Climate Zone Number 5 Climate Zone Number 6 Climate Zone Number 7 Climate Zone Number 8 Climate Zone Subtype A Climate Zone Subtype B Climate Zone Subtype C Retrieved from

242

Emission Standards for Contaminants (Iowa)  

Energy.gov (U.S. Department of Energy (DOE))

These regulations list emissions standards for various contaminants, and contain special requirements for anaerobic lagoons. These regulations also describe alternative emissions limits, which may...

243

Interaction between shallow groundwater, saline surface water and contaminant discharge at a seasonally  

E-Print Network (OSTI)

the transport of point-source contaminant plumes across the estuarine transition zone. This paper presents at the site is impacted with dissolved-phase petroleum hydrocarbons, including the BTEX (benzene, toluene approximately 80 m from the river's edge. The plume follows an easterly flow path from the UST source

Clement, Prabhakar

244

EM News Flashes | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

April 11, 2013 April 11, 2013 Contaminants in Vadose Zone Environments The Deep Vadose Zone - Applied Field Research Initiative (DVZ-AFRI) partnered with the Vadose Zone Journal to create a special section of the journal's November 2012 issue. April 10, 2013 EM Rolls Out Fiscal Year 2014 Budget Request WASHINGTON, D.C. - Today EM Senior Advisor David Huizenga rolled out a $5.622 billion budget request for fiscal year 2014 that enables EM progress in all areas of the nuclear cleanup program while maintaining safety and compliance across the complex. April 8, 2013 Spanning 34 acres, the Savannah River Site Biomass Cogeneration Facility is the culmination of 30 months and more than 600,000 hours of labor. EM Exceeds Sustainability Goal by Reducing Carbon Footprint WASHINGTON, D.C. - EM has surpassed another DOE sustainability goal, this

245

Zone refining of plutonium metal  

Science Conference Proceedings (OSTI)

The purpose of this study was to investigate zone refining techniques for the purification of plutonium metal. The redistribution of 10 impurity elements from zone melting was examined. Four tantalum boats were loaded with plutonium impurity alloy, placed in a vacuum furnace, heated to 700{degrees}C, and held at temperature for one hour. Ten passes were made with each boat. Metallographic and chemical analyses performed on the plutonium rods showed that, after 10 passes, moderate movement of certain elements were achieved. Molten zone speeds of 1 or 2 inches per hour had no effect on impurity element movement. Likewise, the application of constant or variable power had no effect on impurity movement. The study implies that development of a zone refining process to purify plutonium is feasible. Development of a process will be hampered by two factors: (1) the effect on impurity element redistribution of the oxide layer formed on the exposed surface of the material is not understood, and (2) the tantalum container material is not inert in the presence of plutonium. Cold boat studies are planned, with higher temperature and vacuum levels, to determine the effect on these factors. 5 refs., 1 tab., 5 figs.

NONE

1997-05-01T23:59:59.000Z

246

Overlap zoned electrically heated particulate filter  

DOE Patents (OSTI)

A system includes a particulate matter (PM) filter that includes an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than or equal to one, and wherein the N zones and the M sub-zones are arranged in P layers, where P is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

Gonze, Eugene V [Pinckney, MI; Chapman, Mark R [Brighton, MI

2011-07-19T23:59:59.000Z

247

Enterprise Zone Program (Louisiana) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Enterprise Zone Program (Louisiana) Enterprise Zone Program (Louisiana) Enterprise Zone Program (Louisiana) < Back Eligibility Commercial Construction Developer Fuel Distributor Industrial Installer/Contractor Institutional Investor-Owned Utility Nonprofit Retail Supplier Systems Integrator Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Louisiana Program Type Corporate Tax Incentive Enterprise Zone Provider Louisiana Economic Development The Enterprise Zone Program is a jobs incentive program providing Louisiana income and franchise tax credits to businesses hiring at least 35% of net, new jobs from targeted groups. Enterprise Zones (EZs) are areas with high unemployment, low income, or a high percentage of residents receiving some

248

Enterprise Zone Program (Alabama) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Alabama) Alabama) Enterprise Zone Program (Alabama) < Back Eligibility Commercial Construction Industrial Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Alabama Program Type Enterprise Zone Provider Alabama Department of Economic and Community Affairs The Enterprise Zone Program provides certain tax incentives to corporations, partnerships and proprietorships that locate or expand within designated Enterprise Zones. In addition to state-level tax incentives, businesses may also receive local tax and non-tax incentives for locating or expanding within a designated Enterprise Zone. Section 5 of the Alabama Enterprise Zone Program offers the following tax incentives: Credit based

249

Renewable Energy Renaissance Zones | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Renewable Energy Renaissance Zones Renewable Energy Renaissance Zones Renewable Energy Renaissance Zones < Back Eligibility Commercial Industrial Local Government Savings Category Bioenergy Solar Buying & Making Electricity Alternative Fuel Vehicles Heating & Cooling Swimming Pool Heaters Water Heating Commercial Heating & Cooling Heating Wind Maximum Rebate None Program Info Start Date 07/12/2006 State Michigan Program Type Industry Recruitment/Support Rebate Amount 100% abatement of Michigan Business Tax, state education tax, personal and real property taxes, and local income taxes Provider Michigan Economic Development Corporation In 2006, Michigan enacted legislation allowing for the creation of Renewable Energy Renaissance Zones (RERZ). Renaissance zones -- renewable energy renaissance zones are just one type -- offer significant tax

250

Unsaturated Zone and Saturated Zone Transport Properties (U0100)  

Science Conference Proceedings (OSTI)

This Analysis/Model Report (AMR) summarizes transport properties for the lower unsaturated zone hydrogeologic units and the saturated zone at Yucca Mountain and provides a summary of data from the Busted Butte Unsaturated Zone Transport Test (UZTT). The purpose of this report is to summarize the sorption and transport knowledge relevant to flow and transport in the units below Yucca Mountain and to provide backup documentation for the sorption parameters decided upon for each rock type. Because of the complexity of processes such as sorption, and because of the lack of direct data for many conditions that may be relevant for Yucca Mountain, data from systems outside of Yucca Mountain are also included. The data reported in this AMR will be used in Total System Performance Assessment (TSPA) calculations and as general scientific support for various Process Model Reports (PMRs) requiring knowledge of the transport properties of different materials. This report provides, but is not limited to, sorption coefficients and other relevant thermodynamic and transport properties for the radioisotopes of concern, especially neptunium (Np), plutonium (Pu), Uranium (U), technetium (Tc), iodine (I), and selenium (Se). The unsaturated-zone (UZ) transport properties in the vitric Calico Hills (CHv) are discussed, as are colloidal transport data based on the Busted Butte UZTT, the saturated tuff, and alluvium. These values were determined through expert elicitation, direct measurements, and data analysis. The transport parameters include information on interactions of the fractures and matrix. In addition, core matrix permeability data from the Busted Butte UZTT are summarized by both percent alteration and dispersion.

J. Conca

2000-12-20T23:59:59.000Z

251

POSSIBLE HEALTH HAZARDS ASSOCIATED WITH THE LAUNDERING OF RADIOACTIVELY CONTAMINATED PROTECTIVE CLOTHING  

SciTech Connect

An engineering study was made at the Brookhaven National Laboratory to evaluate the possible health hazards to laundry personnel and the public connected with the operation of a decontamination laundry. Laboratory clothing was separated into eight groups, ranging from only slight amounts to rather large amounts of contamination. The groups contained from nineteen to thirtyone coveralls each, with all of the garments in the same group containing about the same amount of radioactive contamination. Each group was washed as a separate batch. Air samples were taken at various breathing zones and at various times during the operation to determine the air-borne dust hazard. The waste water was assayed for actlvity, the dryer effluent was monitored and the equipment, building, etc., were checked for contamination during the laundry operation of the eight groups. The data show that the greatest hazard lies in the inhalation of airbonne radioactive dusts. Washwater, laundry equipment, surfaces and floors became contaminated. Clean clothes showed cross contamination if washed with even slightly contaminated clothing. The dryer effluent was invariably contaminated with radioactive lint. It was evident that below 1 to 2 mu c of contamination per garment, one could send radioactive clothing to a commercial laundry without hazard to the laundry operators or to the public. Higher levels can be handled safely by a commercial laundry if the loading and sorting operations are carefully managed. (auth)

Pearsall, S.G.; Gemmell, L.; Breslin, A.

1958-09-01T23:59:59.000Z

252

Enhanced Remedial Amendment Delivery to Subsurface Using Shear Thinning Fluid and Aqueous Foam  

SciTech Connect

A major issue with in situ subsurface remediation is the ability to achieve an even spatial distribution of remedial amendments to the contamination zones in an aquifer or vadose zone. Delivery of amendment to the aquifer using shear thinning fluid and to the vadose zone using aqueous foam has the potential to enhance the amendment distribution into desired locations and improve the remediation. 2-D saturated flow cell experiments were conducted to evaluate the enhanced sweeping, contaminant removal, and amendment persistence achieved by shear thinning fluid delivery. Bio-polymer xanthan gum solution was used as the shear thinning fluid. Unsaturated 1-D column and 2-D flow cell experiments were conducted to evaluate the mitigation of contaminant mobilization, amendment uniform distribution enhancement, and lateral delivery improvement by foam delivery. Surfactant sodium lauryl ether sulfate was used as the foaming agent. It was demonstrated that the shear thinning fluid injection enhanced the fluid sweeping over a heterogeneous system and increased the delivery of remedial amendment into low-permeability zones. The persistence of the amendment distributed into the low-perm zones by the shear thinning fluid was prolonged compared to that of amendment distributed by water injection. Foam delivery of amendment was shown to mitigate the mobilization of highly mobile contaminant from sediments under vadose zone conditions. Foam delivery also achieved more uniform amendment distribution in a heterogeneous unsaturated system, and demonstrated remarkable increasing in lateral distribution of the injected liquid compared to direct liquid injection.

Zhong, Lirong; Szecsody, James E.; Oostrom, Martinus; Truex, Michael J.; Shen, Xin; Li, Xiqing

2011-04-23T23:59:59.000Z

253

Data Center Economizer Contamination and Humidity Study  

NLE Websites -- All DOE Office Websites (Extended Search)

Us Department Contacts Media Contacts Data Center Economizer Contamination and Humidity Study Title Data Center Economizer Contamination and Humidity Study Publication Type...

254

Concerns Regarding Lead Contamination and Radiological Controls...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Home Concerns Regarding Lead Contamination and Radiological Controls at the Nevada Test Site, INS-O-06-02 Concerns Regarding Lead Contamination and Radiological Controls at...

255

The Border Cities Enterprise Zone Program (Minnesota)  

Energy.gov (U.S. Department of Energy (DOE))

The Border Cities Enterprise Zone Program provides business tax credits to businesses that invest, develop, expand, and create jobs in identified Border-Cities Enterprise Zones. Companies may be...

256

Enterprise Zone Real Property Investment Grant (Virginia)  

Energy.gov (U.S. Department of Energy (DOE))

The Enterprise Zone Real Property Investment Grant provides qualified zone investors with cash grants for industrial, commercial or mixed use property. The grant is equal to 20% of the excess...

257

Enterprise Zone Sales Tax Exemption (Kansas)  

Energy.gov (U.S. Department of Energy (DOE))

The Enterprise Zone Sales Tax Exemption offers businesses located in such economic development zones a 100 percent sales tax exemption on the purchase of labor and materials to construct or remodel...

258

Estimation of unsaturated zone traveltimes for Rainier Mesa and Shoshone Mountain, Nevada Test Site, Nevada, using a source-responsive preferential-flow model  

SciTech Connect

Traveltimes for contaminant transport by water from a point in the unsaturated zone to the saturated zone are a concern at Rainier Mesa and Shoshone Mountain in the Nevada Test Site, Nevada. Where nuclear tests were conducted in the unsaturated zone, contaminants must traverse hundreds of meters of variably saturated rock before they enter the saturated zone in the carbonate rock, where the regional groundwater system has the potential to carry them substantial distances to a location of concern. The unsaturated-zone portion of the contaminant transport path may cause a significant delay, in addition to the time required to travel within the saturated zone, and thus may be important in the overall evaluation of the potential hazard from contamination. Downward contaminant transport through the unsaturated zone occurs through various processes and pathways; this can lead to a broad distribution of contaminant traveltimes, including exceedingly slow and unexpectedly fast extremes. Though the bulk of mobile contaminant arrives between the time-scale end members, the fastest contaminant transport speed, in other words the speed determined by the combination of possible processes and pathways that would bring a measureable quantity of contaminant to the aquifer in the shortest time, carries particular regulatory significance because of its relevance in formulating the most conservative hazard-prevention scenarios. Unsaturated-zone flow is usually modeled as a diffusive process responding to gravity and pressure gradients as mediated by the unsaturated hydraulic properties of the materials traversed. The mathematical formulation of the diffuse-flow concept is known as Richards' equation, which when coupled to a solute transport equation, such as the advection-dispersion equation, provides a framework to simulate contaminant migration in the unsaturated zone. In recent decades awareness has increased that much fluid flow and contaminant transport within the unsaturated zone takes place as preferential flow, faster than would be predicted by the coupled Richards' and advection-dispersion equations with hydraulic properties estimated by traditional means. At present the hydrologic community has not achieved consensus as to whether a modification of Richards' equation, or a fundamentally different formulation, would best quantify preferential flow. Where the fastest contaminant transport speed is what needs to be estimated, there is the possibility of simplification of the evaluation process. One way of doing so is by a two-step process in which the first step is to evaluate whether significant preferential flow and solute transport is possible for the media and conditions of concern. The second step is to carry out (a) a basic Richards' and advection-dispersion equation analysis if it is concluded that preferential flow is not possible or (b) an analysis that considers only the fastest possible preferential-flow processes, if preferential flow is possible. For the preferential-flow situation, a recently published model describable as a Source-Responsive Preferential-Flow (SRPF) model is an easily applied option. This report documents the application of this two-step process to flow through the thick unsaturated zones of Rainier Mesa and Shoshone Mountain in the Nevada Test Site. Application of the SRPF model involves distinguishing between continuous and intermittent water supply to preferential flow paths. At Rainier Mesa and Shoshone Mountain this issue is complicated by the fact that contaminant travel begins at a location deep in the subsurface, where there may be perched water that may or may not act like a continuous supply, depending on such features as the connectedness of fractures and the nature of impeding layers. We have treated this situation by hypothesizing both continuous and intermittent scenarios for contaminant transport to the carbonate aquifer and reporting estimation of the fastest speed for both of these end members.

Brian A. Ebel; John R. Nimmo

2009-09-11T23:59:59.000Z

259

Gulf of California Rift Zone Geothermal Region | Open Energy...  

Open Energy Info (EERE)

of California Rift Zone Geothermal Region (Redirected from Gulf of California Rift Zone) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Gulf of California Rift Zone...

260

Allegan County, Michigan ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Allegan County, Michigan ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Allegan County, Michigan ASHRAE Standard ASHRAE 169-2006 Climate Zone...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Becker County, Minnesota ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Becker County, Minnesota ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Becker County, Minnesota ASHRAE Standard ASHRAE 169-2006 Climate Zone...

262

Anchorage Borough, Alaska ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Anchorage Borough, Alaska ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anchorage Borough, Alaska ASHRAE Standard ASHRAE 169-2006 Climate Zone...

263

Benton County, Tennessee ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Tennessee ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Benton County, Tennessee ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate...

264

Arapahoe County, Colorado ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Arapahoe County, Colorado ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Arapahoe County, Colorado ASHRAE Standard ASHRAE 169-2006 Climate Zone...

265

Alfalfa County, Oklahoma ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Alfalfa County, Oklahoma ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alfalfa County, Oklahoma ASHRAE Standard ASHRAE 169-2006 Climate Zone...

266

Augusta County, Virginia ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Augusta County, Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Augusta County, Virginia ASHRAE Standard ASHRAE 169-2006 Climate Zone...

267

Benton County, Minnesota ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Minnesota ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Benton County, Minnesota ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate...

268

Barron County, Wisconsin ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Barron County, Wisconsin ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Barron County, Wisconsin ASHRAE Standard ASHRAE 169-2006 Climate Zone...

269

Bedford County, Tennessee ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Bedford County, Tennessee ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bedford County, Tennessee ASHRAE Standard ASHRAE 169-2006 Climate Zone...

270

Audrain County, Missouri ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Audrain County, Missouri ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Audrain County, Missouri ASHRAE Standard ASHRAE 169-2006 Climate Zone...

271

Anderson County, Kentucky ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Anderson County, Kentucky ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, Kentucky ASHRAE Standard ASHRAE 169-2006 Climate Zone...

272

Adams County, Pennsylvania ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Pennsylvania ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Adams County, Pennsylvania ASHRAE Standard ASHRAE 169-2006 Climate Zone Number...

273

Ballard County, Kentucky ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Ballard County, Kentucky ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Ballard County, Kentucky ASHRAE Standard ASHRAE 169-2006 Climate Zone...

274

Ashland County, Wisconsin ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Ashland County, Wisconsin ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Ashland County, Wisconsin ASHRAE Standard ASHRAE 169-2006 Climate Zone...

275

Accomack County, Virginia ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Accomack County, Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Accomack County, Virginia ASHRAE Standard ASHRAE 169-2006 Climate Zone...

276

Benton County, Washington ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Washington ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Benton County, Washington ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate...

277

Asotin County, Washington ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Asotin County, Washington ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Asotin County, Washington ASHRAE Standard ASHRAE 169-2006 Climate Zone...

278

Property:ASHRAE 169 Climate Zone Number | Open Energy Information  

Open Energy Info (EERE)

Number Number Jump to: navigation, search This is a property of type Page. Pages using the property "ASHRAE 169 Climate Zone Number" Showing 25 pages using this property. (previous 25) (next 25) A Abbeville County, South Carolina ASHRAE 169-2006 Climate Zone + Climate Zone Number 3 + Acadia Parish, Louisiana ASHRAE 169-2006 Climate Zone + Climate Zone Number 2 + Accomack County, Virginia ASHRAE 169-2006 Climate Zone + Climate Zone Number 4 + Ada County, Idaho ASHRAE 169-2006 Climate Zone + Climate Zone Number 5 + Adair County, Iowa ASHRAE 169-2006 Climate Zone + Climate Zone Number 5 + Adair County, Kentucky ASHRAE 169-2006 Climate Zone + Climate Zone Number 4 + Adair County, Missouri ASHRAE 169-2006 Climate Zone + Climate Zone Number 5 + Adair County, Oklahoma ASHRAE 169-2006 Climate Zone + Climate Zone Number 3 +

279

Property:ASHRAE 169 Climate Zone Subtype | Open Energy Information  

Open Energy Info (EERE)

ASHRAE 169 Climate Zone Subtype ASHRAE 169 Climate Zone Subtype Jump to: navigation, search This is a property of type Page. Pages using the property "ASHRAE 169 Climate Zone Subtype" Showing 25 pages using this property. (previous 25) (next 25) A Abbeville County, South Carolina ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A + Acadia Parish, Louisiana ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A + Accomack County, Virginia ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A + Ada County, Idaho ASHRAE 169-2006 Climate Zone + Climate Zone Subtype B + Adair County, Iowa ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A + Adair County, Kentucky ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A + Adair County, Missouri ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A +

280

Enterprise Zones (Iowa) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Zones (Iowa) Zones (Iowa) Enterprise Zones (Iowa) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Installer/Contractor Institutional Investor-Owned Utility Municipal/Public Utility Nonprofit Rural Electric Cooperative Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Iowa Program Type Enterprise Zone Industry Recruitment/Support Training/Technical Assistance Provider Iowa Economic Development Authority The Enterprise Zones Program is an incentive for business expansion designed to stimulate development by targeting economically distressed areas in Iowa. Through state and local tax incentives, businesses and developers are encouraged to make new investments, and create or retain

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Enterprise Zone Program (Georgia) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Georgia) Georgia) Enterprise Zone Program (Georgia) < Back Eligibility Agricultural Commercial Construction Developer Fuel Distributor General Public/Consumer Industrial Installer/Contractor Investor-Owned Utility Municipal/Public Utility Retail Supplier Rural Electric Cooperative Systems Integrator Transportation Tribal Government Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Georgia Program Type Enterprise Zone Personal Tax Incentives Property Tax Incentive Provider Georgia Department of Community Affairs The Enterprise Zone Program provides various tax incentives to businesses within designated underdeveloped zones in rural or urban areas. The State Enterprise Zone program intends to improve geographic areas within cities

282

Geothermal Lost Circulation Zone Mapping Tool  

DOE Green Energy (OSTI)

Lost circulation is an expensive and often encountered problem when drilling into geothermal formations. A method is needed to more accurately describe loss zones encountered during geothermal drilling to allow for more realistic testing since present testing techniques are inadequate. A Lost Circulation Zone Mapping Tool (LCZMT) is being developed that will quickly locate a loss zone and then provide a visual image of this zone as it intersects the wellbore. A modified Sandia high temperature Acoustic Borehole Televiewer should allow modeling of geothermal loss zones, which would in turn lead to testing that can be performed to evaluate lost circulation materials under simulated downhole conditions. 5 refs., 5 figs.

Bauman, T.J.

1985-01-01T23:59:59.000Z

283

An integrated methodology for characterizing flow and transport processes in fractured rock  

E-Print Network (OSTI)

Unsaturated Zone, Yucca Mountain, Nevada. Water-Resourcesof the unsaturated zone of Yucca Mountain, NV from three-in fractured tuffs of Yucca Mountain, Vadose Zone Journal,

Wu, Yu-Shu

2007-01-01T23:59:59.000Z

284

Zoned heating and air conditioning system  

SciTech Connect

This patent describes a zoned heating and air conditioning system comprising: a central air handling system with an air heating means and an air cooling means and a blower connected to an air duct system; thermostats each have heating and cooling set points, respectively associated with and located in different zones of a building; dampers respectively associated with each building zone positioned in the air duct system. Each damper has an open position allowing air into the respective zone from the duct system and a closed position; relay means for connecting one thermostat to the air handling system upon a call for heating or cooling by one thermostat and disconnecting all other thermostats by connecting one thermostat's connections between the thermostat and air handling system. Only one thermostat is connected to the air handling system at a time and the relay means disconnects one thermostat from the air handling system after one thermostat is satisified; and damper actuating means for unlocking each damper in one building zone responsive actuated by a respective zone thermostat connected to the air handling system by the relay means. The damper actuates means including a damper solenoid for each damper located adjacent each damper and connected to a respective zone thermostat. It unlocks each damper in one building zone responsive to being actuated by the respective zone thermostat and unlocks the dampers in one building zone when one thermostat is actuated while preventing the dampers in another thermostat's building zone from unlocking.

Beachboard, S.A.

1987-06-16T23:59:59.000Z

285

Overview: Zoning for Small Wind Turbines  

Wind Powering America (EERE)

Overview: Overview: Zoning for Small Wind Turbines Jim Green NREL ASES Small Wind Division Webinar January 17, 2008 2 Zoning Basics * Zoning is one form of land use law * Based on legal principle of "police power:" the power to regulate in order to promote the health, morals, safety, and general welfare of the community * Zoning authority originates from state laws called "zoning enabling legislation" - Standard Zoning Enabling Act, Dept. of Commerce, 1920s * Enabling legislation delegates land use authority to local jurisdictions, "Home Rule" - counties, parishes, boroughs, townships, municipalities, cities, villages, etc. 3 Zoning is Daunting * 3,034 counties (National Association of Counties) * 16,504 townships * 19,429 municipalities (National League of Cities)

286

Enhanced Enterprise Zones (Missouri) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Enhanced Enterprise Zones (Missouri) Enhanced Enterprise Zones (Missouri) Enhanced Enterprise Zones (Missouri) < Back Eligibility Commercial Industrial Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Missouri Program Type Enterprise Zone Corporate Tax Incentive Provider Missouri Department of Economic Development Enhanced Enterprise Zones aim at attracting new businesses or promoting an expansion of existing business in Missouri Enhanced Enterprise Zone. Tax credits will be an amount authorized by DED, based on the state economic benefit, supported by the number of new jobs, wages and new capital investment that the project will create. To qualify, individual business eligibility will be determined by the zone, based on creation of

287

Environmental Measurement-While-Drilling System for Real-Time Field Screening of Contaminants  

SciTech Connect

Sampling during environmental drilling is essential to fully characterize the spatial distribution and migration of near surface contaminants. However, analysis of the samples is expensive and time-consuming: off-site laboratory analysis can take weeks or months. An alternative screening technology, Environmental Measurement-While-Drilling (EMWD), could save money and valuable time by quickly distinguishing between contaminated and uncontaminated areas. Real time measurements provided by an EMWD system enable on-the-spot decisions to be made regarding sampling strategies. The system also enhances worker safety and provides the added flexibility of being able to steer a drill bit in or out of hazardous zones.

Bishop, L.B.; Lockwood, G.J.; Normann, R.A.; Selph, M.M.; Williams, C.V.

1999-02-22T23:59:59.000Z

288

Property:Buildings/ModelClimateZone | Open Energy Information  

Open Energy Info (EERE)

ModelClimateZone ModelClimateZone Jump to: navigation, search This is a property of type Page. It links to pages that use the form Buildings Model. The allowed values for this property are: Climate Zone 1A Climate Zone 1B Climate Zone 2A Climate Zone 2B Climate Zone 3A Climate Zone 3B Climate Zone 3C Climate Zone 4A Climate Zone 4B Climate Zone 4C Climate Zone 5A Climate Zone 5B Climate Zone 5C Climate Zone 6A Climate Zone 6B Climate Zone 7A Climate Zone 7B Climate Zone 8A Climate Zone 8B Pages using the property "Buildings/ModelClimateZone" Showing 12 pages using this property. G General Merchandise 2009 TSD Chicago High Plug Load 50% Energy Savings + Climate Zone 5A + General Merchandise 2009 TSD Chicago High Plug Load Baseline + Climate Zone 5A + General Merchandise 2009 TSD Chicago Low Plug Load 50% Energy Savings + Climate Zone 5A +

289

U.S. Climate Zones Map for Commercial Buildings  

U.S. Energy Information Administration (EIA) Indexed Site

Past Climate Zones U. S. Climate Zones for 1979-1999 CBECS: climate zone map Return to Climate Zones for 2003 CBECS Return to CBECS Home Page Note:Map updated with corrections,...

290

U.S. Climate Zones Map for Commercial Buildings  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Climate Zone U. S. Climate Zones for 2003 CBECS: climate zones map Note:Map updated with corrections, February 2012 Further Explanation on How Climate Zones are Defined...

291

JGI - Why Sequence Contaminated Groundwater?  

NLE Websites -- All DOE Office Websites (Extended Search)

Contaminated Groundwater? Contaminated Groundwater? Because the majority of microorganisms in nature have never been cultured, little is known about their genetic properties, biochemical functions, and metabolic characteristics. Although the sequence of the microbial community "genome" can now be determined with high-throughput sequencing technology, the complexity and magnitude of most microbial communities make meaningful data acquisition and interpretation difficult. Thus, the sequence determination of a groundwater microbial community with manageable diversity and complexity (~20 phylotypes) is a timely challenge. The samples for this project come from the Natural and Accelerated Bioremediation Research (NABIR) Field Research Center (FRC), Well FW-010. The overall objective is to provide a fundamental and comprehensive

292

Modeling of contaminant transport in underground coal gasification  

Science Conference Proceedings (OSTI)

In order to study and discuss the impact of contaminants produced from underground coal gasification on groundwater, a coupled seepage-thermodynamics-transport model for underground gasification was developed on the basis of mass and energy conservation and pollutant-transport mechanisms, the mathematical model was solved by the upstream weighted multisell balance method, and the model was calibrated and verified against the experimental site data. The experiment showed that because of the effects of temperature on the surrounding rock of the gasification panel the measured pore-water-pressure was higher than the simulated one; except for in the high temperature zone where the simulation errors of temperature, pore water pressure, and contaminant concentration were relatively high, the simulation values of the overall gasification panel were well fitted with the measured values. As the gasification experiment progressed, the influence range of temperature field expanded, the gradient of groundwater pressure decreased, and the migration velocity of pollutant increased. Eleven months and twenty months after the test, the differences between maximum and minimum water pressure were 2.4 and 1.8 MPa, respectively, and the migration velocities of contaminants were 0.24-0.38 m/d and 0.27-0.46 m/d, respectively. It was concluded that the numerical simulation of the transport process for pollutants from underground coal gasification was valid. 42 refs., 13 figs., 1 tab.

Lanhe Yang; Xing Zhang [China University of Mining and Technology, Xuzhou (China). College of Resources and Geosciences

2009-01-15T23:59:59.000Z

293

Available at www.sciencedirect.com journal homepage: www.elsevier.com/locate/watres  

E-Print Network (OSTI)

and by the need of controlling biogas migration into the vadose zone. Recent advances involving the use

294

Development of an integrated, in-situ remediation technology: Task 1 -- Evaluation of treatment zone formation options. Topical report, September 26, 1994--May 25, 1996  

SciTech Connect

Contamination in low permeability soils poses a significant technical challenge to in-situ remediation efforts. Poor accessibility to the contaminants and difficulty in delivery of treatment reagents have rendered existing in-situ treatments such as bioremediation, vapor extraction, pump and treat rather ineffective when applied to low permeability soils present at many contaminated sites. The technology is an integrated in-situ treatment in which established geotechnical methods are used to install degradation zones directly in the contaminated soil and electro-osmosis is utilized to move the contaminants back and forth through those zones until the treatment is completed. This topical report presents the results of evaluations by E.I. duPont de Nemours and Co., Inc. of treatment zone and electrode emplacement alternatives for use in the integrated treatment process. Specifically, the scope of this study was limited to vertical configuration emplacements. Several promising alternatives were identified ranging from approaches involving standard excavation techniques to relatively specialized geotechnical construction methods which could be modified for the treatment zone emplacement purpose. Information developed in this report is designed to help the user select the most promising emplacement method(s) for a given site on the basis of (1) depth of emplacement, and (2) restrictions on handling excavated soils. Advantages, disadvantages, and estimated costs are identified for each alternative, and possible bases for improvement and cost reduction through further development are described.

Shoemaker, S.H.; Landis, R.C.; Griffith, R.J.; Schultz, D.S. [Monsanto Co., St. Louis, MO (United States); Quinton, G.E. [E.I. duPont de Nemours and Co., Inc., Wilmington, DE (United States)

1997-05-01T23:59:59.000Z

295

Climate Zone 3B | Open Energy Information  

Open Energy Info (EERE)

Climate Zone 3B Climate Zone 3B Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 3 and Climate Zone Subtype B. Climate Zone 3B is defined as Dry with IP Units 4500 < CDD50ºF ≤ 6300 and SI Units 2500 < CDD10ºC < 3500 . The following places are categorized as class 3B climate zones: Andrews County, Texas Baylor County, Texas Borden County, Texas Brewster County, Texas Butte County, California Callahan County, Texas Chaves County, New Mexico Childress County, Texas Clark County, Nevada Cochise County, Arizona Coke County, Texas Coleman County, Texas Collingsworth County, Texas Colusa County, California Concho County, Texas Contra Costa County, California Cottle County, Texas Crane County, Texas Crockett County, Texas

296

Coastal Zone Management Act | Open Energy Information  

Open Energy Info (EERE)

Zone Management Act Zone Management Act Jump to: navigation, search Statute Name Coastal Zone Management Act Year 1972 Url [[File:|160px|link=]] Description The Coastal Zone Management Act of 1972 (CZMA; Pub.L. 92-583, 86 Stat. 1280, enacted October 27, 1972, 16 U.S.C. §§ 1451-1464, Chapter 33) is an Act of Congress passed in 1972 to encourage coastal states to develop and implement coastal zone management plans (CZMPs). This act was established as a United States National policy to preserve, protect, develop, and where possible, restore or enhance, the resources of the Nation's coastal zone for this and succeeding generations. References Wikipedia[1] National Oceanic and Atmospheric Administration[2] The U.S. Congress recognized the importance of meeting the challenge of

297

Displacement Transfer Zone | Open Energy Information  

Open Energy Info (EERE)

Displacement Transfer Zone Displacement Transfer Zone Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Displacement Transfer Zone Dictionary.png Displacement Transfer Zone: Displacement transfer zones facilitate the transfer of strain between normal and strike-slip faults. Intersections between strike-slip faults in the Walker Lane and N- to NNE-striking normal faults commonly host geothermal systems, focused along the normal faults proximal to their dilational intersections with nearby strike-slip faults. Other definitions:Wikipedia Reegle Controlling Structures List of controlling structures typically associated with geothermal systems: Major Normal Fault Termination of a Major Normal Fault Stepover or Relay Ramp in Normal Fault Zones Apex or Salient of Normal Fault

298

Climate Zone 5A | Open Energy Information  

Open Energy Info (EERE)

Zone 5A Zone 5A Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 5 and Climate Zone Subtype A. Climate Zone 5A is defined as Cool- Humid with IP Units 5400 < HDD65ºF ≤ 7200 and SI Units 3000 < HDD18ºC ≤ 4000 . The following places are categorized as class 5A climate zones: Adair County, Iowa Adair County, Missouri Adams County, Illinois Adams County, Indiana Adams County, Iowa Adams County, Nebraska Adams County, Pennsylvania Albany County, New York Allegan County, Michigan Alleghany County, North Carolina Allegheny County, Pennsylvania Allen County, Indiana Allen County, Ohio Andrew County, Missouri Antelope County, Nebraska Appanoose County, Iowa Armstrong County, Pennsylvania Arthur County, Nebraska

299

Climate Zone 5B | Open Energy Information  

Open Energy Info (EERE)

Climate Zone 5B Climate Zone 5B Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 5 and Climate Zone Subtype B. Climate Zone 5B is defined as Dry with IP Units 5400 < HDD65ºF ≤ 7200 and SI Units 3000 < HDD18ºC ≤ 4000 . The following places are categorized as class 5B climate zones: Ada County, Idaho Adams County, Colorado Adams County, Washington Apache County, Arizona Arapahoe County, Colorado Asotin County, Washington Baker County, Oregon Beaver County, Utah Benewah County, Idaho Bent County, Colorado Benton County, Washington Boulder County, Colorado Broomfield County, Colorado Canyon County, Idaho Carson City County, Nevada Cassia County, Idaho Catron County, New Mexico Chelan County, Washington Cheyenne County, Colorado

300

Climate Zone Number 1 | Open Energy Information  

Open Energy Info (EERE)

Climate Zone Number 1 Climate Zone Number 1 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 1 is defined as Very Hot - Humid(1A) with IP Units 9000 < CDD50ºF and SI Units 5000 < CDD10ºC Dry(1B) with IP Units 9000 < CDD50ºF and SI Units 5000 < CDD10ºC . The following places are categorized as class 1 climate zones: Broward County, Florida Hawaii County, Hawaii Honolulu County, Hawaii Kalawao County, Hawaii Kauai County, Hawaii Maui County, Hawaii Miami-Dade County, Florida Monroe County, Florida Retrieved from "http://en.openei.org/w/index.php?title=Climate_Zone_Number_1&oldid=21604" Category: ASHRAE Climate Zones What links here Related changes Special pages Printable version Permanent link Browse properties

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Climate Zone 2A | Open Energy Information  

Open Energy Info (EERE)

Climate Zone 2A Climate Zone 2A Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 2 and Climate Zone Subtype A. Climate Zone 2A is defined as Hot - Humid with IP Units 6300 < CDD50ºF ≤ 9000 and SI Units 3500 < CDD10ºC ≤ 5000 . The following places are categorized as class 2A climate zones: Acadia Parish, Louisiana Alachua County, Florida Allen Parish, Louisiana Anderson County, Texas Angelina County, Texas Appling County, Georgia Aransas County, Texas Ascension Parish, Louisiana Assumption Parish, Louisiana Atascosa County, Texas Atkinson County, Georgia Austin County, Texas Avoyelles Parish, Louisiana Bacon County, Georgia Baker County, Florida Baker County, Georgia Baldwin County, Alabama Bastrop County, Texas

302

Enterprise Zone Program (Texas) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Enterprise Zone Program (Texas) Enterprise Zone Program (Texas) Enterprise Zone Program (Texas) < Back Eligibility Commercial Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Texas Program Type Corporate Tax Incentive Enterprise Zone Provider Texas Wide Open for Business The Enterprise Zone Program eligible projects to apply for state sales and use tax refunds on purchases of all taxable items purchased for use at qualified business sites related to the project or activity. The level and amount of refund is related to the capital investment and jobs created at the qualified business site. In addition, local communities must offer incentives to participants under the enterprise zone program, such as tax

303

Sidelobe Contamination in Bistatic Radars  

Science Conference Proceedings (OSTI)

The problem of sidelobe contamination in a bistatic network is explored. The McGill bistatic network consists of one S-band Doppler radar and two low-gain passive receivers at remote sites. Operational experience with the bistatic network ...

Ramón de Elía; Isztar Zawadzki

2000-10-01T23:59:59.000Z

304

Method for refining contaminated iridium  

DOE Patents (OSTI)

Contaminated iridium is refined by alloying it with an alloying agent selected from the group consisting of manganese and an alloy of manganese and copper, and then dissolving the alloying agent from the formed alloy to provide a purified iridium powder.

Heshmatpour, Bahman (Waltham, MA); Heestand, Richard L. (Oak Ridge, TN)

1983-01-01T23:59:59.000Z

305

Streamside Management Zones (Montana) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Streamside Management Zones (Montana) Streamside Management Zones (Montana) Streamside Management Zones (Montana) < Back Eligibility Utility Fed. Government Commercial Agricultural Investor-Owned Utility State/Provincial Govt Industrial Construction Municipal/Public Utility Local Government Residential Installer/Contractor Rural Electric Cooperative Tribal Government Low-Income Residential Schools Retail Supplier Institutional Multi-Family Residential Systems Integrator Fuel Distributor Nonprofit General Public/Consumer Transportation Savings Category Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Montana Program Type Environmental Regulations Provider Montana Department of Natural Resources and Conservation This chapter sets streamside management zones as encompassing a strip at

306

Enterprise Zone Incentives (Florida) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Incentives (Florida) Incentives (Florida) Enterprise Zone Incentives (Florida) < Back Eligibility Agricultural Commercial Fuel Distributor Industrial Retail Supplier Systems Integrator Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Florida Program Type Enterprise Zone Provider Florida Department of Economic Opportunity Enterprise Zone Incentives encourage business growth within certain geographic areas targeted for economic revitalization. Businesses which create jobs within a designated zone are eligible for several tax incentives, including sales and use tax credit, tax refunds for machinery or equipment, sales tax refund for building materials, and a sales tax exemption for electrical energy

307

UNDERWATER COATINGS FOR CONTAMINATION CONTROL  

SciTech Connect

The Idaho National Laboratory (INL) deactivated several aging nuclear fuel storage basins. Planners for this effort were greatly concerned that radioactive contamination present on the basin walls could become airborne as the sides of the basins became exposed during deactivation and allowed to dry after water removal. One way to control this airborne contamination was to fix the contamination in place while the pool walls were still submerged. There are many underwater coatings available on the market for marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives were easily applied and adhered well to the substrates (pool wall materials) found in INL fuel pools. Lab-scale experiments were conducted by applying fourteen different commercial underwater coatings to four substrate materials representative of the storage basin construction materials, and evaluating their performance. The coupons included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The evaluation criteria included ease of application, adherence to the four surfaces of interest, no change on water clarity or chemistry, non-hazardous in final applied form and be proven in underwater applications. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected from the underwater coatings tested for application to all four pools. Divers scrubbed loose contamination off the basin walls and floors using a ship hull scrubber and vacuumed up the sludge. The divers then applied the coating using a special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pools with no detectable airborne contamination releases.

Julia L. Tripp; Kip Archibald; Ann Marie Phillips; Joseph Campbell

2004-02-01T23:59:59.000Z

308

Analytical Requirements for Petroleum Contaminated Soils  

E-Print Network (OSTI)

Analytical Requirements for Petroleum Contaminated Soils According to 20 NMAC 9.1.704 704. REQUIRED), or other applicable statutes. Page 1 of 1Analytical Requirements for Petroleum Contaminated Soils 4

309

Regulatory Resources for Process Contaminants (3-MCPD)  

Science Conference Proceedings (OSTI)

Regulatory information and references for 3-MCPD(3-Monochloropropane-1,2-diol )process contaminants. Regulatory Resources for Process Contaminants (3-MCPD) 3-MCPD 2-diol 3-MCPD 3-MCPD Esters 3-monochloropropane-1 acid analysis aocs april articles certifi

310

Remediation of Mercury and Industrial Contaminants  

Energy.gov (U.S. Department of Energy (DOE))

The mission of the Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative is to control the flux of contaminants in soil and water environments for the purpose of...

311

Natural Contamination from the Mancos Shale | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Other Agencies You are here Home Natural Contamination from the Mancos Shale Natural Contamination from the Mancos Shale Natural Contamination from the Mancos...

312

Measurements and Standards for Contaminants in ...  

Science Conference Proceedings (OSTI)

Measurements and Standards for Contaminants in Environmental Samples. ... Kelly, WR, Long, SE, and Seiber, JR, Standard Reference Materials ...

2013-07-23T23:59:59.000Z

313

Radiological Contamination Control Training for Laboratory Research  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3 of 3) 3 of 3) RADIOLOGICAL CONTAMINATION CONTROL TRAINING FOR LABORATORY RESEARCH Student's Guide Office of Environment, Safety & Health U.S. Department of Energy February 1997 DOE-HDBK-1106-97 ii This page intentionally left blank. DOE-HDBK-1106-97 iii Table of Contents Page TERMINAL OBJECTIVE............................................................................1 ENABLING OBJECTIVES...........................................................................1 I. RADIOLOGICAL CONTAMINATION................................................. 2 A. Comparison of Radiation and Radioactive Contamination ..................... 2 B. Types of Contamination.............................................................. 2

314

Google Earth Tour: How Contaminants Got There  

NLE Websites -- All DOE Office Websites (Extended Search)

Google Earth Tour: How Contaminants Got There Click here to load the tour...then click the play button below...

315

A Prognostic Relationship for Entrainment Zone Thickness  

Science Conference Proceedings (OSTI)

The thickness of the entrainment zone at the top of the atmospheric mixed layer is analyzed using measurements made with a ground-based lidar during the BLX83 and CIRCE field programs. When the entrainment-zone depth normalized by mixed-layer ...

Eric Nelson; Roland Stull; Edwin Eloranta

1989-09-01T23:59:59.000Z

316

CLEANING OF RADIOACTIVE CONTAMINATED OCCUPATIONAL CLOTHING  

SciTech Connect

The soiling and contamination of work clothing and ways of removing this contamination are discussed. Means of disinfection, washing tests with radioactive-contaminated cotton clothing, construction of the laundry, and cleaning protective clothing of plastic and other materials with the help of washing methods and polyphosphates are described. (M.C.G.)

Siewert, G.; Schikora, Th.

1963-11-01T23:59:59.000Z

317

WASTE DISPOSAL WORKSHOPS: ANTHRAX CONTAMINATED WASTE  

E-Print Network (OSTI)

WASTE DISPOSAL WORKSHOPS: ANTHRAX CONTAMINATED WASTE January 2010 Prepared for the Interagency DE-AC05-76RL01830 Waste Disposal Workshops: Anthrax-Contaminated Waste AM Lesperance JF Upton SL #12;#12;PNNL-SA-69994 Waste Disposal Workshops: Anthrax- Contaminated Waste AM Lesperance JF Upton SL

318

Climate Zone 7B | Open Energy Information  

Open Energy Info (EERE)

B B Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 7 and Climate Zone Subtype B. Climate Zone 7A is defined as Very Cold with IP Units 9000 < HDD65ºF ≤ 12600 and SI Units 5000 < HDD18ºC ≤ 7000 . The following places are categorized as class 7B climate zones: Clear Creek County, Colorado Grand County, Colorado Gunnison County, Colorado Hinsdale County, Colorado Jackson County, Colorado Lake County, Colorado Lincoln County, Wyoming Mineral County, Colorado Park County, Colorado Pitkin County, Colorado Rio Grande County, Colorado Routt County, Colorado San Juan County, Colorado Sublette County, Wyoming Summit County, Colorado Teton County, Wyoming Retrieved from "http://en.openei.org/w/index.php?title=Climate_Zone_7B&oldid=2161

319

Climate Zone 6B | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » Climate Zone 6B Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 6 and Climate Zone Subtype B. Climate Zone 6B is defined as Dry with IP Units 7200 < HDD65ºF ≤ 9000 and SI Units 4000 < HDD18ºC ≤ 5000 . The following places are categorized as class 6B climate zones: Adams County, Idaho Alamosa County, Colorado Albany County, Wyoming Alpine County, California Archuleta County, Colorado Bannock County, Idaho Bear Lake County, Idaho Beaverhead County, Montana Big Horn County, Montana Big Horn County, Wyoming

320

Climate Zone 4C | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » Climate Zone 4C Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 4 and Climate Zone Subtype C. Climate Zone 4C is defined as Mixed - Marine with IP Units 3600 < HDD65ºF ≤ 5400 and SI Units 2000 < HDD18ºC ≤ 3000 . The following places are categorized as class 4C climate zones: Benton County, Oregon Clackamas County, Oregon Clallam County, Washington Clark County, Washington Clatsop County, Oregon Columbia County, Oregon Coos County, Oregon Cowlitz County, Washington Curry County, Oregon Douglas County, Oregon

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Contaminated Outdoor High Voltage Insulators  

Science Conference Proceedings (OSTI)

The external insulation of power lines and outdoor substations is a weak point in transmission systems. The insulation is particularly susceptible to failure if proper attention has not been given to its design, condition monitoring, and maintenance. In regions with high contamination levels, regular maintenance and the application of palliative measures can be critical to ensure that the system meets its outage performance targets. This can involve pure maintenance measures such as cleaning the insulato...

2009-12-22T23:59:59.000Z

322

Underwater Coatings for Contamination Control  

Science Conference Proceedings (OSTI)

The Idaho National Engineering and Environmental Laboratory (INEEL) is deactivating several fuel storage basins. Airborne contamination is a concern when the sides of the basins are exposed and allowed to dry during water removal. One way of controlling this airborne contamination is to fix the contamination in place while the pool walls are still submerged. There are many underwater coatings available on the market that are used in marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives are easily applied and adhere well to the substrates (pool wall materials) found in INEEL fuel pools. The four pools considered included 1) Test Area North (TAN-607) with epoxy painted concrete walls; 2) Idaho Nuclear Technology and Engineering Center (INTEC) (CPP-603) with bare concrete walls; 3) Materials Test Reactor (MTR) Canal with stainless steel lined concrete walls; and 4) Power Burst Facility (PBF-620) with stainless steel lined concrete walls on the bottom and epoxy painted carbon steel lined walls on the upper portions. Therefore, the four materials chosen for testing included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The typical water temperature of the pools varies from 55oF to 80oF dependent on the pool and the season. These tests were done at room temperature. The following criteria were used during this evaluation. The underwater coating must: · Be easy to apply · Adhere well to the four surfaces of interest · Not change or have a negative impact on water chemistry or clarity · Not be hazardous in final applied form · Be proven in other underwater applications. In addition, it is desirable for the coating to have a high pigment or high cross-link density to prevent radiation from penetrating. This paper will detail the testing completed and the test results. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected to be applied by divers after scrubbing loose contamination off the basin walls and floors using a ship hull scrubber and vacuuming up the sludge. A special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pool with no airborne contamination problems.

Julia L. Tripp; Kip Archibald; Ann-Marie Phillips; Joseph Campbell

2004-02-01T23:59:59.000Z

323

In situ removal of contamination from soil  

DOE Patents (OSTI)

A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination, and further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed.

Lindgren, Eric R. (Albuquerque, NM); Brady, Patrick V. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

324

Doffing Procedures for Firefighters' Contaminated Turnout Gear: Documentation for Videotape  

Science Conference Proceedings (OSTI)

Firefighting in an area contaminated by radioactive materials can result in contaminated clothing that requires careful handling. This report documents a videotape that provides simple how-to procedures for doffing contaminated or potentially contaminated firefighter turnout gear.

1992-07-01T23:59:59.000Z

325

Seismic Imaging of UXO-Contaminated Underwater Sites (Interim Report)  

E-Print Network (OSTI)

Imaging of UXO-Contaminated Underwater Sites” Roland GrittoImaging of UXO-Contaminated Underwater Sites” over the first

Gritto, Roland; Korneev, Valeri; Nihei, Kurt; Johnson, Lane

2004-01-01T23:59:59.000Z

326

Desiccant contamination research: Report on the desiccant contamination test facility  

DOE Green Energy (OSTI)

The activity in the cooling systems research involves research on high performance dehumidifiers and chillers that can operate efficiently with the variable thermal outputs and delivery temperatures associated with solar collectors. It also includes work on advanced passive cooling techniques. This report describes the work conducted to improve the durability of solid desiccant dehumidifiers by investigating the causes of degradation of desiccant materials from airborne contaminants and thermal cycling. The performance of a dehumidifier strongly depends on the physical properties and durability of the desiccant material. To make durable and reliable dehumidifiers, an understanding is needed of how and to what degree the performance of a dehumidifier is affected by desiccant degradation. This report, an account of work under Cooling Systems Research, documents the efforts to design and fabricate a test facility to investigate desiccant contamination based on industry and academia recommendations. It also discusses the experimental techniques needed for obtaining high-quality data and presents plans for next year. Researchers of the Mechanical and Industrial Technology Division performed this work at the Solar Energy Research Institute in FY 1988 for DOE's Office of Solar Heat Technologies. 7 refs., 19 figs., 1 tab.

Pesaran, A.A.; Bingham, C.E.

1991-07-01T23:59:59.000Z

327

Desiccant contamination research: Report on the desiccant contamination test facility  

SciTech Connect

The activity in the cooling systems research involves research on high performance dehumidifiers and chillers that can operate efficiently with the variable thermal outputs and delivery temperatures associated with solar collectors. It also includes work on advanced passive cooling techniques. This report describes the work conducted to improve the durability of solid desiccant dehumidifiers by investigating the causes of degradation of desiccant materials from airborne contaminants and thermal cycling. The performance of a dehumidifier strongly depends on the physical properties and durability of the desiccant material. To make durable and reliable dehumidifiers, an understanding is needed of how and to what degree the performance of a dehumidifier is affected by desiccant degradation. This report, an account of work under Cooling Systems Research, documents the efforts to design and fabricate a test facility to investigate desiccant contamination based on industry and academia recommendations. It also discusses the experimental techniques needed for obtaining high-quality data and presents plans for next year. Researchers of the Mechanical and Industrial Technology Division performed this work at the Solar Energy Research Institute in FY 1988 for DOE's Office of Solar Heat Technologies. 7 refs., 19 figs., 1 tab.

Pesaran, A.A.; Bingham, C.E.

1991-07-01T23:59:59.000Z

328

Category:County Climate Zones | Open Energy Information  

Open Energy Info (EERE)

County Climate Zones County Climate Zones Jump to: navigation, search This category contains county climate zone information in the United States of America. Contents: Top - 0-9 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Pages in category "County Climate Zones" The following 200 pages are in this category, out of 3,141 total. (previous 200) (next 200) A Abbeville County, South Carolina ASHRAE 169-2006 Climate Zone Acadia Parish, Louisiana ASHRAE 169-2006 Climate Zone Accomack County, Virginia ASHRAE 169-2006 Climate Zone Ada County, Idaho ASHRAE 169-2006 Climate Zone Adair County, Iowa ASHRAE 169-2006 Climate Zone Adair County, Kentucky ASHRAE 169-2006 Climate Zone Adair County, Missouri ASHRAE 169-2006 Climate Zone Adair County, Oklahoma ASHRAE 169-2006 Climate Zone

329

Environmental geochemistry of radioactive contamination.  

Science Conference Proceedings (OSTI)

This report attempts to describe the geochemical foundations of the behavior of radionuclides in the environment. The information is obtained and applied in three interacting spheres of inquiry and analysis: (1) experimental studies and theoretical calculations, (2) field studies of contaminated and natural analog sites and (3) model predictions of radionuclide behavior in remediation and waste disposal. Analyses of the risks from radioactive contamination require estimation of the rates of release and dispersion of the radionuclides through potential exposure pathways. These processes are controlled by solubility, speciation, sorption, and colloidal transport, which are strong functions of the compositions of the groundwater and geomedia as well as the atomic structure of the radionuclides. The chemistry of the fission products is relatively simple compared to the actinides. Because of their relatively short half-lives, fission products account for a large fraction of the radioactivity in nuclear waste for the first several hundred years but do not represent a long-term hazard in the environment. The chemistry of the longer-lived actinides is complex; however, some trends in their behavior can be described. Actinide elements of a given oxidation state have either similar or systematically varying chemical properties due to similarities in ionic size, coordination number, valence, and electron structure. In dilute aqueous systems at neutral to basic pH, the dominant actinide species are hydroxy- and carbonato-complexes, and the solubility-limiting solid phases are commonly oxides, hydroxides or carbonates. In general, actinide sorption will decrease in the presence of ligands that complex with the radionuclide; sorption of the (IV) species of actinides (Np, Pu, U) is generally greater than of the (V) species. The geochemistry of key radionuclides in three different environments is described in this report. These include: (1) low ionic strength reducing waters from crystalline rocks at nuclear waste research sites in Sweden; (2) oxic water from the J-13 well at Yucca Mountain, Nevada, the site of a proposed repository for high level nuclear waste (HLW) in tuffaceous rocks; and (3) reference brines associated with the Waste Isolation Pilot Plant (WIPP). The transport behaviors of radionuclides associated with the Chernobyl reactor accident and the Oklo Natural Reactor are described. These examples span wide temporal and spatial scales and include the rapid geochemical and physical processes important to nuclear reactor accidents or industrial discharges as well as the slower processes important to the geologic disposal of nuclear waste. Application of geochemical information to remediating or assessing the risk posed by radioactive contamination is the final subject of this report. After radioactive source terms have been removed, large volumes of soil and water with low but potentially hazardous levels of contamination may remain. For poorly-sorbing radionuclides, capture of contaminated water and removal of radionuclides may be possible using permeable reactive barriers and bioremediation. For strongly sorbing radionuclides, contaminant plumes will move very slowly. Through a combination of monitoring, regulations and modeling, it may be possible to have confidence that they will not be a hazard to current or future populations. Abstraction of the hydrogeochemical properties of real systems into simple models is required for probabilistic risk assessment. Simplifications in solubility and sorption models used in performance assessment calculations for the WIPP and the proposed HLW repository at Yucca Mountain are briefly described.

Bryan, Charles R.; Siegel, Malcolm Dean

2003-09-01T23:59:59.000Z

330

Hydrogen Contamination of Niobium Surfaces  

DOE Green Energy (OSTI)

The presence of hydrogen is blamed for dramatic reductions in cavity Q's. Hydrogen concentration is difficult to measure, so there is a great deal of Fear, Uncertainty, and Doubt (FUD) associated with the problem. This paper presents measurements of hydrogen concentration depth profiles, commenting on the pitfalls of the methods used and exploring how material handling can change the amount of hydrogen in pieces of niobium. Hydrogen analysis was performed by a forward scattering experiment with Helium used as the primary beam. This technique is variously known as FRES (Forward Recoil Elastic Scattering), FRS, HFS (Hydrogen Forward Scattering), and HRA (Hydrogen Recoil Analysis). Some measurements were also made using SIMS (Secondary Ion Mass Spectrometry). Both HFS and SIMS are capable of measuring a depth profile of Hydrogen. The primary difficulty in interpreting the results from these techniques is the presence of a surface peak which is due (at least in part) to contamination with either water or hydrocarbons. With HFS, the depth resolution is about 30 nm, and the maximum depth profiled is about 300 nm. (This 10-1 ratio is unusually low for ion beam techniques, and is a consequence of the compromises that must be made in the geometry of the experiment, surface roughness, and energy straggling in the absorber foil that must be used to filter out the forward scattered helium.) All the observed HFS spectra include a surface peak which includes both surface contamination and any real hydrogen uptake by the niobium surface. Some contamination occurs during the analysis. The vacuum in the analysis chamber is typically a few times 10{sup -6} torr, and some of the contamination is in the form of hydrocarbons from the pumping system. Hydrocarbons normally form a very thin (less than a monolayer) film which is in equilibrium between arrival rate and the evaporation rate. In the presence of the incoming ion beam, however, these hydrocarbons crack on the surface into non-volatile components. Equilibrium is lost, and the surface builds up a layer of carbon-based gunk.

Viet Nguyen-Tuong; Lawrence Doolittle

1993-10-01T23:59:59.000Z

331

Observing Surf-Zone Dispersion with Drifters  

Science Conference Proceedings (OSTI)

Surf-zone dispersion is studied using drifter observations collected within about 200 m of the shoreline (at depths of less than about 5 m) on a beach with approximately alongshore uniform bathymetry and waves. There were about 70 individual ...

Matthew Spydell; Falk Feddersen; R. T. Guza; W. E. Schmidt

2007-12-01T23:59:59.000Z

332

Climate Zone 3C | Open Energy Information  

Open Energy Info (EERE)

C C Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 3 and Climate Zone Subtype C. Climate Zone 3C is defined as Warm - Marine with IP Units CDD50ºF ≤ 4500 AND HDD65ºF ≤ 3600 and SI Units CDD10ºC ≤ 2500 AND HDD18ºC ≤ 2000 . The following places are categorized as class 3C climate zones: Alameda County, California Marin County, California Mendocino County, California Monterey County, California Napa County, California San Benito County, California San Francisco County, California San Luis Obispo County, California San Mateo County, California Santa Barbara County, California Santa Clara County, California Santa Cruz County, California Sonoma County, California Ventura County, California

333

Climate Zone 3A | Open Energy Information  

Open Energy Info (EERE)

A A Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 3 and Climate Zone Subtype A. Climate Zone 3A is defined as Warm - Humid with IP Units 4500 < CDD50ºF ≤ 6300 and SI Units 2500 < CDD10ºC < 3500 . The following places are categorized as class 3A climate zones: Abbeville County, South Carolina Adair County, Oklahoma Adams County, Mississippi Aiken County, South Carolina Alcorn County, Mississippi Alfalfa County, Oklahoma Allendale County, South Carolina Amite County, Mississippi Anderson County, South Carolina Anson County, North Carolina Archer County, Texas Arkansas County, Arkansas Ashley County, Arkansas Atoka County, Oklahoma Attala County, Mississippi Autauga County, Alabama Baldwin County, Georgia

334

Definition: Accommodation Zone | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Accommodation Zone Jump to: navigation, search Dictionary.png Accommodation Zone Accommodation zones occur at fault intersections consisting of belts of interlocking, oppositely dipping normal faults. Multiple subsurface fault intersections in these zones are a favorable host for geothermal activity.[2] View on Wikipedia Wikipedia Definition References ↑ James E. Faulds,Nicholas H. Hinz,Mark F. Coolbaugh,Patricia H. Cashman,Christopher Kratt,Gregory Dering,Joel Edwards,Brett Mayhew,Holly McLachlan. 2011. Assessment of Favorable Structural Settings of Geothermal Systems in the Great Basin, Western USA. In: Transactions. GRC Anual Meeting; 2011/10/23; San Diego, CA. Davis, CA: Geothermal Resources

335

Climate Zone Number 7 | Open Energy Information  

Open Energy Info (EERE)

Climate Zone Number 7 Climate Zone Number 7 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 7 is defined as Very Cold with IP Units 9000 < HDD65ºF ≤ 12600 and SI Units 5000 < HDD18ºC ≤ 7000 . The following places are categorized as class 7 climate zones: Aitkin County, Minnesota Aleutians East Borough, Alaska Aleutians West Census Area, Alaska Anchorage Borough, Alaska Aroostook County, Maine Ashland County, Wisconsin Baraga County, Michigan Barnes County, North Dakota Bayfield County, Wisconsin Becker County, Minnesota Beltrami County, Minnesota Benson County, North Dakota Bottineau County, North Dakota Bristol Bay Borough, Alaska Burke County, North Dakota Burnett County, Wisconsin Carlton County, Minnesota Cass County, Minnesota

336

Climate Zone 2B | Open Energy Information  

Open Energy Info (EERE)

B B Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 2 and Climate Zone Subtype B. Climate Zone 2B is defined as Dry with IP Units 6300 < CDD50ºF ≤ 9000 and SI Units 3500 < CDD10ºC ≤ 5000 . The following places are categorized as class 2B climate zones: Bandera County, Texas Dimmit County, Texas Edwards County, Texas Frio County, Texas Imperial County, California Kinney County, Texas La Paz County, Arizona La Salle County, Texas Maricopa County, Arizona Maverick County, Texas Medina County, Texas Pima County, Arizona Pinal County, Arizona Real County, Texas Uvalde County, Texas Val Verde County, Texas Webb County, Texas Yuma County, Arizona Zapata County, Texas Zavala County, Texas Retrieved from

337

Climate Zone 4A | Open Energy Information  

Open Energy Info (EERE)

A A Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 4 and Climate Zone Subtype A. Climate Zone 4A is defined as Mixed - Humid with IP Units CDD50ºF ≤ 4500 AND 3600 < HDD65ºF ≤ 5400 and SI Units CDD10ºC ≤ 2500 AND HDD18ºC ≤ 3000 . The following places are categorized as class 4A climate zones: Accomack County, Virginia Adair County, Kentucky Adams County, Ohio Alamance County, North Carolina Albemarle County, Virginia Alexander County, Illinois Alexander County, North Carolina Alexandria County, Virginia Allegany County, Maryland Alleghany County, Virginia Allen County, Kansas Allen County, Kentucky Amelia County, Virginia Amherst County, Virginia Anderson County, Kansas Anderson County, Kentucky

338

Climate Zone 4B | Open Energy Information  

Open Energy Info (EERE)

B B Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 4 and Climate Zone Subtype B. Climate Zone 4B is defined as Dry with IP Units CDD50ºF ≤ 4500 AND 3600 < HDD65ºF ≤ 5400 and SI Units CDD10ºC ≤ 2500 AND HDD18ºC ≤ 3000 . The following places are categorized as class 4B climate zones: Amador County, California Armstrong County, Texas Baca County, Colorado Bailey County, Texas Beaver County, Oklahoma Bernalillo County, New Mexico Briscoe County, Texas Calaveras County, California Carson County, Texas Castro County, Texas Cibola County, New Mexico Cimarron County, Oklahoma Cochran County, Texas Curry County, New Mexico Dallam County, Texas De Baca County, New Mexico Deaf Smith County, Texas

339

Climate Zone 6A | Open Energy Information  

Open Energy Info (EERE)

Jump to: navigation, search Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard consisting of Climate Zone Number 6 and Climate Zone Subtype A. Climate Zone 6A is defined as Cold - Humid with IP Units 7200 < HDD65ºF ≤ 9000 and SI Units 4000 < HDD18ºC ≤ 5000 . The following places are categorized as class 6A climate zones: Adams County, North Dakota Adams County, Wisconsin Addison County, Vermont Alcona County, Michigan Alger County, Michigan Allamakee County, Iowa Allegany County, New York Alpena County, Michigan Androscoggin County, Maine Anoka County, Minnesota Antrim County, Michigan Arenac County, Michigan Aurora County, South Dakota Barron County, Wisconsin Beadle County, South Dakota Belknap County, New Hampshire Bennington County, Vermont

340

Pine Tree Development Zones Program (Maine)  

Energy.gov (U.S. Department of Energy (DOE))

The Pine Tree Development Zones program offers eligible businesses the chance to reduce, and sometimes eliminate, state taxes for up to ten years. There is a statutory requirement of hiring a...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Climate Zone Number 8 | Open Energy Information  

Open Energy Info (EERE)

Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon Climate Zone Number 8 Jump to: navigation, search A type of climate defined in the ASHRAE...

342

Climate Zone 1A | Open Energy Information  

Open Energy Info (EERE)

Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon Climate Zone 1A Jump to: navigation, search A type of climate defined in the ASHRAE...

343

Microbial oceanography of anoxic oxygen minimum zones  

E-Print Network (OSTI)

Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

Ulloa, Osvaldo

344

Seismic imaging of the mantle transition zone  

E-Print Network (OSTI)

In this thesis, we developed a generalized Radon transform of SS precursors for large-scale, high-resolution seismo-stratigraphy of the upper mantle transition zone. The generalized Radon transform (GRT) is based on the ...

Cao, Qin, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

345

Zone Freezing Study for Pyrochemical Process Waste Minimization  

Science Conference Proceedings (OSTI)

Pyroprocessing technology is a non-aqueous separation process for treatment of used nuclear fuel. At the heart of pyroprocessing lies the electrorefiner, which electrochemically dissolves uranium from the used fuel at the anode and deposits it onto a cathode. During this operation, sodium, transuranics, and fission product chlorides accumulate in the electrolyte salt (LiCl-KCl). These contaminates change the characteristics of the salt overtime and as a result, large volumes of contaminated salt are being removed, reprocessed and stored as radioactive waste. To reduce the storage volumes and improve recycling process for cost minimization, a salt purification method called zone freezing has been proposed at Korea Atomic Energy Research Institute (KAERI). Zone freezing is melt crystallization process similar to the vertical Bridgeman method. In this process, the eutectic salt is slowly cooled axially from top to bottom. As solidification occurs, the fission products are rejected from the solid interface and forced into the liquid phase. The resulting product is a grown crystal with the bulk of the fission products near the bottom of the salt ingot, where they can be easily be sectioned and removed. Despite successful feasibility report from KAERI on this process, there were many unexplored parameters to help understanding and improving its operational routines. Thus, this becomes the main motivation of this proposed study. The majority of this work has been focused on the CsCl-LiCl-KCl ternary salt. CeCl3-LiCl-KCl was also investigated to check whether or not this process is feasible for the trivalent species—surrogate for rare-earths and transuranics. For the main part of the work, several parameters were varied, they are: (1) the retort advancement rate—1.8, 3.2, and 5.0 mm/hr, (2) the crucible lid configurations—lid versus no-lid, (3) the amount or size of mixture—50 and 400 g, (4) the composition of CsCl in the salt—1, 3, and 5 wt%, and (5) the temperature differences between the high and low furnace zones—200 and 300 ?C. During each experiment, the temperatures at selected locations around the crucible were measured and recorded to provide temperature profiles. Following each experiment, samples were collected and elemental analysis was done to determine the composition of iii the salt. Several models—non-mixed, well-mixed, Favier, and hybrid—were explored to describe the zone freezing process. For CsCl-LiCl-KCl system, experimental results indicate that through this process up to 90% of the used salt can be recycled, effectively reducing waste volume by a factor of ten. The optimal configuration was found to be a 5.0 mm/hr rate with a lid configuration and a ?T of 200°C. The larger 400 g mixtures had recycle percentages similar to the 50 g mixtures; however, the throughput per time was greater for the 400 g case. As a result, the 400 g case is recommended. For the CeCl3-LiCl-KCl system, the result implies that it is possible to use this process to separate the rare-earth and transuranics chlorides. Different models were applied to only CsCl ternary system. The best fit model was the hybrid model as a result of a solute transport transition from non- mixed to well-mixed throughout the growing process.

Ammon Williams

2012-05-01T23:59:59.000Z

346

Zone control system for energy conservation  

SciTech Connect

A zone control system adapted to control temperatures in a building is described having a temperature modifying plant to modify the temperature of a heat exchange medium, circulator means to circulate the medium, and flow control means to regulate the flow of the medium. The system includes zone thermostats with one thermostat per controlled zone, and with each thermostat including temperature responsive means and heat anticipator means to modify the temperature of the temperature responsive means; at least one of the flow control means per controlled zone, and each of the flow control means being capable of energizing the circulator means when the flow control means operates to permit circulation of the heat exchange medium; each zone thermostat including on-off timer means having normally open switch means, and further including intermediate on timer means having normally open switch means; first zone control circuit means including a temperature responsive means of the first thermostat, a heat anticipator means of the first thermostat, and circuit means with normally closed switch means capable of energizing a first flow control means to an open position upon the first thermostat calling for operation of the temperature modifying plant. The timer means of the first thermostat is actuated by the first thermostat calling for operation of the temperature modifying plant; a first of the on-off timer means operating its switch means to an on state after a fixed time interval to latch the first flow control means into an open condition; a first of the intermediate on timer means operating its switch means to an on state after a second fixed time interval to energize the modifying plant and complete a circuit to a secondary anticipation heater of a second zone thermostat capable of adding heat to the second zone thermostat; and the first on-off timer means maintaining its switch means closed.

Nelson, L.W.

1986-04-15T23:59:59.000Z

347

Zone heated diesel particulate filter electrical connection  

DOE Patents (OSTI)

An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

2010-03-30T23:59:59.000Z

348

Treating nahcolite containing formations and saline zones  

Science Conference Proceedings (OSTI)

A method for treating a nahcolite containing subsurface formation includes removing water from a saline zone in or near the formation. The removed water is heated using a steam and electricity cogeneration facility. The heated water is provided to the nahcolite containing formation. A fluid is produced from the nahcolite containing formation. The fluid includes at least some dissolved nahcolite. At least some of the fluid is provided to the saline zone.

Vinegar, Harold J

2013-06-11T23:59:59.000Z

349

Gulf of California Rift Zone Geothermal Region | Open Energy...  

Open Energy Info (EERE)

Gulf of California Rift Zone Geothermal Region Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Gulf of California Rift Zone Geothermal Region edit Details Areas (15)...

350

Anderson County, South Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Anderson County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, South Carolina ASHRAE Standard ASHRAE 169-2006...

351

Androscoggin County, Maine ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Androscoggin County, Maine ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Androscoggin County, Maine ASHRAE Standard ASHRAE 169-2006 Climate...

352

Bennington County, Vermont ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Bennington County, Vermont ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bennington County, Vermont ASHRAE Standard ASHRAE 169-2006 Climate...

353

Abbeville County, South Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Abbeville County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Abbeville County, South Carolina ASHRAE Standard ASHRAE 169-2006...

354

Baltimore County, Maryland ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Baltimore County, Maryland ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Baltimore County, Maryland ASHRAE Standard ASHRAE 169-2006 Climate...

355

Barnwell County, South Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Barnwell County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Barnwell County, South Carolina ASHRAE Standard ASHRAE 169-2006...

356

Berkshire County, Massachusetts ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Berkshire County, Massachusetts ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Berkshire County, Massachusetts ASHRAE Standard ASHRAE 169-2006...

357

Aleutians East Borough, Alaska ASHRAE 169-2006 Climate Zone ...  

Open Energy Info (EERE)

Aleutians East Borough, Alaska ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Aleutians East Borough, Alaska ASHRAE Standard ASHRAE 169-2006...

358

Alexander County, North Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Alexander County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alexander County, North Carolina ASHRAE Standard ASHRAE 169-2006...

359

Albemarle County, Virginia ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Albemarle County, Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Albemarle County, Virginia ASHRAE Standard ASHRAE 169-2006 Climate...

360

Berks County, Pennsylvania ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Berks County, Pennsylvania ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Berks County, Pennsylvania ASHRAE Standard ASHRAE 169-2006 Climate...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Bayfield County, Wisconsin ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Bayfield County, Wisconsin ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bayfield County, Wisconsin ASHRAE Standard ASHRAE 169-2006 Climate...

362

Alamance County, North Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Alamance County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alamance County, North Carolina ASHRAE Standard ASHRAE 169-2006...

363

Archuleta County, Colorado ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Archuleta County, Colorado ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Archuleta County, Colorado ASHRAE Standard ASHRAE 169-2006 Climate...

364

Beauregard Parish, Louisiana ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Beauregard Parish, Louisiana ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Beauregard Parish, Louisiana ASHRAE Standard ASHRAE 169-2006 Climate...

365

Allendale County, South Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Allendale County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Allendale County, South Carolina ASHRAE Standard ASHRAE 169-2006...

366

Baltimore City County, Maryland ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Baltimore City County, Maryland ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Baltimore City County, Maryland ASHRAE Standard ASHRAE 169-2006...

367

Berkeley County, South Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Berkeley County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Berkeley County, South Carolina ASHRAE Standard ASHRAE 169-2006...

368

Alameda County, California ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Edit History Facebook icon Twitter icon Alameda County, California ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alameda County,...

369

Bedford City County, Virginia ASHRAE 169-2006 Climate Zone |...  

Open Energy Info (EERE)

Bedford City County, Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bedford City County, Virginia ASHRAE Standard ASHRAE 169-2006...

370

Beaufort County, North Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

History Facebook icon Twitter icon Beaufort County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Beaufort County, North...

371

Alleghany County, North Carolina ASHRAE 169-2006 Climate Zone...  

Open Energy Info (EERE)

Alleghany County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alleghany County, North Carolina ASHRAE Standard ASHRAE 169-2006...

372

Aitkin County, Minnesota ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Page Edit History Facebook icon Twitter icon Aitkin County, Minnesota ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Aitkin County, Minnesota...

373

Barbour County, West Virginia ASHRAE 169-2006 Climate Zone |...  

Open Energy Info (EERE)

Barbour County, West Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Barbour County, West Virginia ASHRAE Standard ASHRAE 169-2006...

374

Avoyelles Parish, Louisiana ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Avoyelles Parish, Louisiana ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Avoyelles Parish, Louisiana ASHRAE Standard ASHRAE 169-2006 Climate...

375

Beltrami County, Minnesota ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Beltrami County, Minnesota ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Beltrami County, Minnesota ASHRAE Standard ASHRAE 169-2006 Climate...

376

Belknap County, New Hampshire ASHRAE 169-2006 Climate Zone |...  

Open Energy Info (EERE)

Belknap County, New Hampshire ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Belknap County, New Hampshire ASHRAE Standard ASHRAE 169-2006...

377

Bertie County, North Carolina ASHRAE 169-2006 Climate Zone |...  

Open Energy Info (EERE)

Bertie County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bertie County, North Carolina ASHRAE Standard ASHRAE 169-2006...

378

Arlington County, Virginia ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Arlington County, Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Arlington County, Virginia ASHRAE Standard ASHRAE 169-2006 Climate...

379

Bamberg County, South Carolina ASHRAE 169-2006 Climate Zone ...  

Open Energy Info (EERE)

Bamberg County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bamberg County, South Carolina ASHRAE Standard ASHRAE 169-2006...

380

Geographic Information System At Walker-Lane Transitional Zone...  

Open Energy Info (EERE)

Geographic Information System At Walker-Lane Transitional Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Geographic Information System At Walker-Lane Transitional Zone...  

Open Energy Info (EERE)

Geographic Information System At Walker-Lane Transitional Zone Region (Coolbaugh, Et Al., 2005 - 2) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal...

382

Reference Buildings by Climate Zone and Representative City:...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

& Publications Reference Buildings by Climate Zone and Representative City: 2A Houston, Texas Reference Buildings by Building Type: Small Hotel Reference Buildings by Climate Zone...

383

Baoding High Tech Industry Development Zone | Open Energy Information  

Open Energy Info (EERE)

Zone" Retrieved from "http:en.openei.orgwindex.php?titleBaodingHighTechIndustryDevelopmentZone&oldid342524" Categories: Clean Energy Organizations Companies...

384

Pages that link to "Baoding High Tech Industry Development Zone...  

Open Energy Info (EERE)

Zone. Retrieved from "http:en.openei.orgwikiSpecial:WhatLinksHereBaodingHighTechIndustryDevelopmentZone" Special pages About us Disclaimers Energy blogs Developer...

385

Variation in sericite composition from fracture zones within...  

Open Energy Info (EERE)

zones of the crystalline basement contain coarse-grained relict muscovite, whereas rock alteration near fracture zones at temperatures > 150C is characterized by abundant...

386

Renewable Energy Generation Zone Property Tax Abatement | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Generation Zone Property Tax Abatement Renewable Energy Generation Zone Property Tax Abatement Eligibility Commercial Industrial Savings For Bioenergy Biofuels Alternative Fuel...

387

Details of U.S. Climate Zones:  

U.S. Energy Information Administration (EIA) Indexed Site

Details of U.S. Climate Zones Details of U.S. Climate Zones Details of U.S. Climate Zones: The CBECS climate zones are groups of climate divisions, as defined by the National Oceanic and Atmospheric Administration (NOAA), which are regions within a state that are as climatically homogeneous as possible. Each NOAA climate division is placed into one of five CBECS climate zones based on its 30-year average heating degree-days (HDD) and cooling degree-days (CDD) for the period 1971 through 2000. (These climate zones have been updated for the 2003 CBECS. All previous CBECS used averages for the 45-year period from 1931 through 1975.) A HDD is a measure of how cold a location was over a period of time, relative to a base temperature (in CBECS, 65 degrees Fahrenheit). The heating degree-day is the difference between that day's average temperature and 65 degrees if the daily average is less than 65; it is zero if the daily average temperature is greater than or equal to 65. For example, if the average temperature for a given day is 40 degrees, then the heating degree-days for that single day equal 25. Heating degree-days for a year are the sum of the daily heating degree-days that year.

388

Situ treatment of contaminated groundwater  

DOE Green Energy (OSTI)

A system for treating dissolved halogenated organic compounds in groundwater that relies upon electrolytically-generated hydrogen to chemically reduce the halogenated compounds in the presence of a suitable catalyst. A direct current is placed across at least a pair, or an array, of electrodes which are housed within groundwater wells so that hydrogen is generated at the cathode and oxygen at the anode. A pump is located within the well housing in which the cathode(s) is(are) located and draws in groundwater where it is hydrogenated via electrolysis, passes through a well-bore treatment unit, and then transported to the anode well(s) for reinjection into the ground. The well-bore treatment involves a permeable cylinder located in the well bore and containing a packed bed of catalyst material that facilitates the reductive dehalogenation of the halogenated organic compounds by hydrogen into environmentally benign species such as ethane and methane. Also, electro-osmatic transport of contaminants toward the cathode also contributes to contaminant mass removal. The only above ground equipment required are the transfer pipes and a direct circuit power supply for the electrodes. The electrode wells in an array may be used in pairs or one anode well may be used with a plurality of cathode wells. The DC current flow between electrode wells may be periodically reversed which controls the formation of mineral deposits in the alkaline cathode well-bore water, as well as to help rejuvenate the catalysis.

McNab, Jr., Walt W. (Concord, CA); Ruiz, Roberto (Tracy, CA); Pico, Tristan M. (Livermore, CA)

2001-01-01T23:59:59.000Z

389

Surface CO2 leakage during the first shallow subsurface CO2 release experiment  

E-Print Network (OSTI)

verification of geologic carbon sequestration, Geophys. Res.from geologic carbon sequestration sites: unsaturated zoneCO 2 from geologic carbon sequestration sites, Vadose Zone

Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

2008-01-01T23:59:59.000Z

390

U-Sr isotopic speedometer: Fluid flow and chemical weathering rates inaquifers  

E-Print Network (OSTI)

zone sediment from the Hanford Reservation—RCRA boreholecontamination at the Hanford Site in Washington using high-vadose zone pore fluids at Hanford, Washington: implications

Maher, Kate; DePaolo, Donald J.; Christensen, John N.

2005-01-01T23:59:59.000Z

391

Process for reducing radioactive contamination in phosphogypsum  

Science Conference Proceedings (OSTI)

A process of two crystallization stages for reducing radioactive contamination of phosphogypsum is disclosed. In the process anhydrite crystals are obtained through dehydration of the radiation containing phosphogypsum in strong sulfuric acid; a portion of the anhydrite crystals containing the radioactive contamination is converted to substantially radiation free gypsum by crystallizing out on a large solids concentration of radiation free gypsum seed crystals; and coarse radiation free gypsum crystals are separated from small anhydrite crystal relics containing substantially all of the radioactive contamination.

Gaynor, J.C.; Palmer, J.W.

1983-06-14T23:59:59.000Z

392

Radiological Worker Training - Radiological Contamination Control...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

B December 2008 DOE HANDBOOK RADIOLOGICAL WORKER TRAINING RADIOLOGICAL CONTAMINATION CONTROL TRAINING FOR LABORATORY RESEARCH U.S. Department of Energy FSC 6910 Washington, D.C....

393

Accident Investigation Report Plutonium Contamination in the...  

NLE Websites -- All DOE Office Websites (Extended Search)

Accident Investigation Report Plutonium Contamination in the Zero Power Physics Reactor Facility at the Idaho National Laboratory, November 8, 2011 January 2012 Disclaimer...

394

Estimating the Amount of Coal Tar Weathering in Sediments by Two-Dimensional Automated-Sequential Gas Chromatography/Mass Spectrometry (GC-GC/MS) and Comprehensive Gas Chromatography/Mass Spectrometry (GCxGC/MS) Techniques — Phase III  

Science Conference Proceedings (OSTI)

This report is intended to inform scientists and engineers concerned with assessing and remediating former manufactured gas plants and other coal tar-contaminated sites. Although the report focuses on coal tar in sediment, the results are equally applicable to studies investigating and remediating coal tar, crude oil, and their by-products in the vadose zone or in ground or pore waters, as well as marine animals. The data provided in this report should allow more accurate analyses to better direct remedi...

2012-03-14T23:59:59.000Z

395

Remediation of Groundwater Contaminated with Organics and Radionuclides - An Innovative Approach Eases Traditional Hurdles  

DOE Green Energy (OSTI)

Traditional approaches to the remediation of contaminated groundwater, such as pump-and-treat, have been used for many years for the treatment of groundwater contaminated with various organics. However the treatment of groundwater contaminated with organics and radionuclides has been considerably more challenging. Safety and Ecology Corporation (SEC) was recently faced with these challenges while designing a remediation system for the remediation of TCE-contaminated groundwater and soil at the RMI Extrusion Plant in Ashtabula, OH. Under contract with RMI Environmental Services (RMIES), SEC teamed with Regenesis, Inc. to design, implement, and execute a bioremediation system to remove TCE and associated organics from groundwater and soil that was also contaminated with uranium and technetium. The SEC-Regenesis system involved the injection of Hydrogen Release Compound (HRC), a natural attenuation accelerant that has been patented, designed, and produced by Regenesis, to stimulate the reductive dechlorination and remediation of chlorinated organics in subsurface environments. The compound was injected using direct-push Geoprobe rods over a specially designed grid system through the zone of contaminated groundwater. The innovative approach eliminated the need to extract contaminated groundwater and bypassed the restrictive limitations listed above. The system has been in operation for roughly six months and has begun to show considerable success at dechlorinating and remediating the TCE plume and in reducing the radionuclides into insoluble precipitants. The paper will provide an overview of the design, installation, and initial operation phase of the project, focusing on how traditional design challenges of remediating radiologically contaminated groundwater were overcome. The following topics will be specifically covered: a description of the mechanics of the HRC technology; an assessment of the applicability of the HRC technology to contaminated groundwater plumes and other potential remediation opportunities; a discussion of how the implementation of the HRC technology eased permitting issues and other challenges of remediating groundwater contaminated with radionuclides and organics; an overview of the remedial design and installation of the design including the inputs required to design the remediation system; a summary of results achieved to date and a forecast of future results; and a discussion of future needs and lessons learned.

Scott, J.; Case, N.; Coltman, K.

2003-02-25T23:59:59.000Z

396

Earthquake Patterns in Diverse Tectonic Zones of the Globe  

E-Print Network (OSTI)

Fast ridge. * ‘‘western Aleutians’’ orogen: (4) Trench. * ‘‘geographic name like ‘‘Aleutian;’’ instead, each zone has a

Kagan, Y. Y.; Bird, P.; Jackson, D. D.

2010-01-01T23:59:59.000Z

397

Transport of Bottom Water in the Romanche Fracture Zone and the Chain Fracture Zone  

Science Conference Proceedings (OSTI)

Two moored arrays deployed in the Romanche Fracture Zone and Chain Fracture Zone in the equatorial Atlantic Ocean provide two-year-long time series of current and temperature in the Lower North Atlantic Deep Water and the Antarctic Bottom Water. ...

Herlé Mercier; Kevin G. Speer

1998-05-01T23:59:59.000Z

398

Opportunity and Enterprise Zones (Oklahoma) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Opportunity and Enterprise Zones (Oklahoma) Opportunity and Enterprise Zones (Oklahoma) Opportunity and Enterprise Zones (Oklahoma) < Back Eligibility Utility Commercial Agricultural Investor-Owned Utility Industrial Construction Municipal/Public Utility Installer/Contractor Rural Electric Cooperative Retail Supplier Institutional Systems Integrator Fuel Distributor Transportation Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Oklahoma Program Type Enterprise Zone Provider Oklahoma Department of Commerce Opportunity and Enterprise Zones provide enhanced financial incentives for businesses located in such zones aimed at stimulating economic expansion in rural and disadvantaged communities Opportunity Zones are those census

399

Zoned electrical heater arranged in spaced relationship from particulate filter  

DOE Patents (OSTI)

A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

Gonze, Eugene V [Pinckney, MI

2011-11-15T23:59:59.000Z

400

Dismantling an alpha-contaminated facility  

SciTech Connect

The difficult task of removing large pieces of highly contaminated equipment from an obsolete plutonium-239 facility was completed in a seven-month operation that included structural alteration of the process building. Detailed job planning, job execution and contamination control were major factors in accomplishing the task. (auth)

Caldwell, R.D.; Harper, R.M.

1975-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

CONTAMINATION CONTROL AT THE HANFORD LAUNDRY  

SciTech Connect

The laundry operation consists of a decontamination laundry, non- regulated laundry service, and a central mask cleaning station. Control of radioactive contamination is accomplished by presorting at the point of use, minimizing handling of contaminated articles, and the discharge of waste effluents under controlled conditions. Procedures are described in detail. (C.H.)

Linderoth, C.E.; Little, G.A.

1962-05-11T23:59:59.000Z

402

Method of removing contaminants from plastic resins  

DOE Patents (OSTI)

A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee' s Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

2008-11-18T23:59:59.000Z

403

Method for removing contaminants from plastic resin  

Science Conference Proceedings (OSTI)

A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

2008-12-30T23:59:59.000Z

404

Method of removing contaminants from plastic resins  

Science Conference Proceedings (OSTI)

A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

Bohnert,George W. (Harrisonville, MO); Hand,Thomas E. (Lee's Summit, MO); Delaurentiis,Gary M. (Jamestown, CA)

2007-08-07T23:59:59.000Z

405

Definition: Displacement Transfer Zone | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Displacement Transfer Zone Jump to: navigation, search Dictionary.png Displacement Transfer Zone Displacement transfer zones facilitate the transfer of strain between normal and strike-slip faults. Intersections between strike-slip faults in the Walker Lane and N- to NNE-striking normal faults commonly host geothermal systems, focused along the normal faults proximal to their dilational intersections with nearby strike-slip faults.[2] View on Wikipedia Wikipedia Definition References ↑ James E. Faulds,Nicholas H. Hinz,Mark F. Coolbaugh,Patricia H. Cashman,Christopher Kratt,Gregory Dering,Joel Edwards,Brett Mayhew,Holly McLachlan. 2011. Assessment of Favorable Structural Settings of Geothermal

406

Phytoremediation of Metal-Contaminated Soils  

DOE Green Energy (OSTI)

Recent concerns regarding environmental contamination have necessitated the development of appropriate technologies to assess the presence and mobility of metals in soil and estimate possible ways to decrease the level of soil metal contamination. Phytoremediation is an emerging technology that may be used to cleanup contaminated soils. Successful application of phytoremediation, however, depends upon various factors that must be carefully investigated and properly considered for specific site conditions. To efficiently affect the metal removal from contaminated soils we used the ability of plants to accumulate different metals and agricultural practices to improve soil quality and enhance plant biomass. Pot experiments were conducted to study metal transport through bulk soil to the rhizosphere and stimulate transfer of the metals to be more available for plants' form. The aim of the experimental study was also to find fertilizers that could enhance uptake of metals and their removal from contaminated soil.

Shtangeeva, I.; Laiho, J.V-P.; Kahelin, H.; Gobran, G.R.

2004-03-31T23:59:59.000Z

407

RADIATION ECOLOGY ISSUES ASSOCIATED WITH MURINE RODENTS AND SHREWS IN THE CHERNOBYL EXCLUSION ZONE  

Science Conference Proceedings (OSTI)

This article describes major studies performed by the Chernobyl Center's International Radioecology Laboratory (Slavutich, Ukraine) on radioecology of murine rodents and shrews inhabiting the Chernobyl Exclusion Zone. The article addresses the long-term (1986-2005) and seasonal dynamics of radioactive contamination of animals, and reviews interspecies differences in radionuclide accumulations and factors affecting the radionuclide accumulations. It is shown that bioavailability of radionuclides in the 'soil-to-plant' chain and a trophic specialization of animals play key roles in determining their actual contamination levels. The total absorbed dose rates in small mammals significantly reduced during the years following the Chernobyl Nuclear Power Plant accident. In 1986, the absorbed dose rate reached 1.3-6.0 Gy hr{sup -1} in the central areas of the Chernobyl Exclusion Zone (the 'Red Forest'). In 1988 and 1990, the total absorbed dose rates were 1.3 and 0.42 Gy hr{sup -1}, respectively. In 1995, 2000, and 2005, according to the present study, the total absorbed dose rates rarely exceeded 0.00023, 0.00018, and 0.00015 Gy hr{sup -1}, respectively. Contributions of individual radiation sources into the total absorbed dose are described.

Farfan, E.; Jannik, T.

2011-10-01T23:59:59.000Z

408

Vapor port and groundwater sampling well  

DOE Patents (OSTI)

A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

Hubbell, J.M.; Wylie, A.H.

1996-01-09T23:59:59.000Z

409

Vapor port and groundwater sampling well  

DOE Patents (OSTI)

A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

410

Effect of oil-contaminated sediment on the longhorn sculpin (Myoxocephalus octodecemspinosus) following chronic exposure  

SciTech Connect

One of the most common pollutants in coastal marine areas is petroleum that is discharged continually from bilges and tankers. Fish which inhabit the littoral zone are usually exposed to a variety of pollutants, including petroleum, that originate from urban and industrial waste. The longhorn sculpin, Myoxocephalus octodecemspinosus, is one of the fish species that inhabits littoral areas adjacent to wharves and fish-processing plants were it feeds on discarded offal. Discharged crude oil has been reported to contaminate and persist in sediment for long periods and is known to affect fish in a variety of ways. The present study was conducted to ascertain the effect of oil-contaminated sediment, following long-term exposure, on body weight, organs, tissues and parasitofauna of the sculpin and the potential use of its parasites as indicators of pollution.

Khan, R.A. (Memorial Univ. of Newfoundland, St. John's (Canada))

1991-07-01T23:59:59.000Z

411

Origin of the South Pacific Convergence Zone  

Science Conference Proceedings (OSTI)

The importance of the presence of South America and Australia to the existence and orientation of the South Pacific Convergence Zone (SPCZ) during January is explored using the ECMWF T21 model. Each of the continents is removed from the model and ...

George N. Kiladis; Hans von Storch; Harryvan Loon

1989-10-01T23:59:59.000Z

412

Injectivity Testing for Vapour Dominated Feed Zones  

DOE Green Energy (OSTI)

Wells with vapor dominated feed zones yield abnormal pressure data. This is caused by the condensation of vapor during water injection. A revised injectivity test procedure currently applied by PNOC at the Leyte Geothermal Power Project has improved the injectivity test results.

Clotworthy, A.W.; Hingoyon, C.S.

1995-01-01T23:59:59.000Z

413

Mixing in the Romanche Fracture Zone  

Science Conference Proceedings (OSTI)

The Romanche Fracture Zone is a major gap in the Mid-Atlantic Ridge at the equator, which is deep enough to allow significant eastward flows of Antarctic Bottom Water from the Brazil Basin to the Sierra Leone and Guinea Abyssal Plains. While ...

Bruno Ferron; Herlé Mercier; Kevin Speer; Ann Gargett; Kurt Polzin

1998-10-01T23:59:59.000Z

414

A GPS-Tracked Surf Zone Drifter  

Science Conference Proceedings (OSTI)

A drifter designed to measure surf zone circulation has been developed and field tested. Drifter positions accurate to within a few meters are estimated in real time at 0.1 Hz using the global positioning system (GPS) and a shore-to-drifter radio ...

W. E. Schmidt; B. T. Woodward; K. S. Millikan; R. T. Guza; B. Raubenheimer; Steve Elgar

2003-07-01T23:59:59.000Z

415

FREE ZONE Rb-276 Chiller Monitoring Project  

Science Conference Proceedings (OSTI)

Regulations prohibiting the production of chlorofluorocarbons (CFCs) have spurred the development of alternative refrigerants with similar thermodynamic properties and operating characteristics for use in large chiller systems. This study evaluates refrigerant FREE ZONE RB-276, a "drop in" replacement for R-12, which has been out of production since January 1, 1996.

1999-11-16T23:59:59.000Z

416

Complexity of Groundwater Contaminants at DOE Sites  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy (DOE) is responsible for the remediation and long-term stewardship of one of the world's largest groundwater contamination portfolios, with a significant number of plumes containing various contaminants, and considerable total mass and activity. As of 1999, the DOE's Office of Environmental Management was responsible for remediation, waste management, or nuclear materials and facility stabilization at 144 sites in 31 states and one U.S. territory, out of which 109 sites were expected to require long-term stewardship. Currently, 19 DOE sites are on the National Priority List. The total number of contaminated plumes on DOE lands is estimated to be 10,000. However, a significant number of DOE sites have not yet been fully characterized. The most prevalent contaminated media are groundwater and soil, although contaminated sediment, sludge, and surface water also are present. Groundwater, soil, and sediment contamination are present at 72% of all DOE sites. A proper characterization of the contaminant inventory at DOE sites is critical for accomplishing one of the primary DOE missions -- planning basic research to understand the complex physical, chemical, and biological properties of contaminated sites. Note that the definitions of the terms 'site' and 'facility' may differ from one publication to another. In this report, the terms 'site,' 'facility' or 'installation' are used to identify a contiguous land area within the borders of a property, which may contain more than one plume. The term 'plume' is used here to indicate an individual area of contamination, which can be small or large. Even though several publications and databases contain information on groundwater contamination and remediation technologies, no statistical analyses of the contaminant inventory at DOE sites has been prepared since the 1992 report by Riley and Zachara. The DOE Groundwater Data Base (GWD) presents data as of 2003 for 221 groundwater plumes at 60 DOE sites and facilities. Note that Riley and Zachara analyzed the data from only 18 sites/facilities including 91 plumes. In this paper, we present the results of statistical analyses of the data in the GWD as guidance for planning future basic and applied research of groundwater contaminants within the DOE complex. Our analyses include the evaluation of a frequency and ranking of specific contaminants and contaminant groups, contaminant concentrations/activities and total contaminant masses and activities. We also compared the results from analyses of the GWD with those from the 1992 report by Riley and Zachara. The difference between our results and those summarized in the 1992 report by Riley and Zachara could be caused by not only additional releases, but also by the use of modern site characterization methods, which more accurately reveal the extent of groundwater contamination. Contaminated sites within the DOE complex are located in all major geographic regions of the United States, with highly variable geologic, hydrogeologic, soil, and climatic conditions. We assume that the information from the 60 DOE sites included in the GWD are representative for the whole DOE complex. These 60 sites include the major DOE sites and facilities, such as Rocky Flats Environmental Technology Site, Colorado; Idaho National Laboratory, Idaho; Savannah River Site, South Carolina; Oak Ridge Reservation, Tennessee; and Hanford Reservation, Washington. These five sites alone ccount for 71% of the value of the remediation work.

Hazen, T.C.; Faybishenko, B.; Jordan, P.

2010-12-03T23:59:59.000Z

417

Recycle of radiologically contaminated austenitic stainless steels  

Science Conference Proceedings (OSTI)

The United States Department of Energy owns large quantities of radiologically contaminated austenitic stainless steel which could by recycled for reuse if appropriate release standards were in place. Unfortunately, current policy places the formulation of a release standard for USA industry years, if not decades, away. The Westinghouse Savannah River Company, Idaho National Engineering Laboratory and various university and industrial partners are participating in initiative to recycle previously contaminated austenitic stainless steels into containers for the storage and disposal of radioactive wastes. This paper describes laboratory scale experiments which demonstrated the decontamination and remelt of stainless steel which had been contaminated with radionuclides.

Imrich, K.J.; Leader, D.R.; Iyer, N.C.; Louthan, M.R. Jr.

1995-02-01T23:59:59.000Z

418

Remediation of Mercury and Industrial Contaminants Applied Field...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Remediation of Mercury and Industrial Contaminants Applied Field Research...

419

Handling and Packaging a Potentially Radiologically Contaminated Patient |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Handling and Packaging a Potentially Radiologically Contaminated Handling and Packaging a Potentially Radiologically Contaminated Patient Handling and Packaging a Potentially Radiologically Contaminated Patient The purpose of this procedure is to provide guidance to EMS care providers for properly handling and packaging potentially radiologically contaminated patients. This procedure applies to Emergency Medical Service care providers who respond to a radioactive material transportation incident that involves potentially contaminated injuries. Handling and Packaging a Potentially Radiologically Contaminated Patient.docx More Documents & Publications Pre-Hospital Practices for Handling a Radiologically Contaminated Patient Medical Examiner/Coroner on the Handling of a Body/Human Remains that are Potentially Radiologically Contaminated

420

Hanford Groundwater Contamination Areas Shrink as EM Exceeds...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Groundwater Contamination Areas Shrink as EM Exceeds Cleanup Goals Hanford Groundwater Contamination Areas Shrink as EM Exceeds Cleanup Goals June 26, 2013 - 12:00pm Addthis The...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Vertical Distribution of Contamination in Ground Water at the...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vertical Distribution of Contamination in Ground Water at the Tuba City, Arizona, Site Vertical Distribution of Contamination in Ground Water at the Tuba City, Arizona, Site...

422

Remediation of Uranium-Contaminated Ground Water  

NLE Websites -- All DOE Office Websites (Extended Search)

The shallow alluvial aquifer at Fry Canyon, Utah, is contaminated with up to 17 mgL uranium leached from processed tailings at an ore upgrader processing plant that was operated...

423

Oil price, mean reversion and zone readjustments  

SciTech Connect

Observing OPEC`s short-term price-output ceiling behavior during the late 1980s and 1990s, one can conclude that it attempts to stabilize the market price within a range of its announced target price by controlling the output ceiling. If the price moves within four to five dollars below the target price, it usually reduces the output ceiling and assigns new quotas to its member countries to keep the price close to the target price. In reality, OPEC established a band for the market price positioned round the target price by basically choosing suitable upper and lower limits for the output or, at least in soft markets, it places tolerance zone below the target price in order to restrict the discrepancy between the market price and the target price. The lower limit is particularly needed because it sets a price floor and ensures that the market price stays above the significantly lower marginal cost of oil production. If the limits of these zones are backed by a perfectly credible intervention policy, they can generate an expectations process that should turn the market prices around even before any intervention takes place. While OPEC in some sense observes the target zones for its prices, those zones are neither well defined nor vigorously defended. It can not always or may not be willing to maintain the price within the limits of the desired zone by cutting the output ceiling; it must sometimes readjust the target price and output ceiling, and thus create a new target zone to reflect the market`s new fundamentals. This is particularly true now because OPEC is losing market share to the other oil producers and is contemplating to shift the current band. Actual readjustments in the target price can be so large, as in 1980 and 1985, that the newmarket price must jump as well. They can occur when both the market price is near the limits of the band as well as when it is inside the band but still further away from those limits.

Hammoudeh, S. [Drexel Univ., Philadelphia, PA (United States)

1996-04-01T23:59:59.000Z

424

The Effects of Contamination on HVDC Insulators  

Science Conference Proceedings (OSTI)

EPRI is currently documenting the various issues that should be considered when converting existing AC lines to high voltage DC (HVDC) lines. One issue that has not yet been dealt with properly is the selection of external DC insulation with respect to contamination. Since the beginning of overhead power transmission, it has been recognized that the performance of external insulation is adversely affected when the insulating surface is contaminated with airborne deposits such as marine salt or industrial...

2010-12-13T23:59:59.000Z

425

Method for removing contaminants from plastic resin  

Science Conference Proceedings (OSTI)

A resin recycling method that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The method includes receiving the resin in container form. The containers are then ground into resin particles. The particles are exposed to a solvent, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. After separating the particles and the resin, a solvent removing agent is used to remove any residual solvent remaining on the resin particles after separation.

Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

2008-12-09T23:59:59.000Z

426

METHOD FOR REMOVING CONTAMINATION FROM PRECIPITATES  

DOE Patents (OSTI)

An improvement in the bismuth phosphate carrier precipitation process is presented for the recovery and purification of plutonium. When plutonium, in the tetravalent state, is carried on a bismuth phosphate precipitate, amounts of centain of the fission products are carried along with the plutonium. The improvement consists in washing such fission product contaminated preeipitates with an aqueous solution of ammonium hydrogen fluoride. since this solution has been found to be uniquely effective in washing fission production contamination from the bismuth phosphate precipitate.

Stahl, G.W.

1959-01-01T23:59:59.000Z

427

Problem of Vain Energy Consumption in a VAV Air Conditioning System Shared By an Inner Zone and Exterior Zone  

E-Print Network (OSTI)

In northern China, there are a large number of space buildings divided in inner zone and exterior zone based on usage requirements. The exterior zone needs to be heated in winter and cooled in summer, while the inner zone needs to be cooled both in winter and summer. Taking a practical project as example, this paper analyzes the energy consumption of a VAV air conditioning system that is shared by inner zone and exterior zone. The paper also points out the serious problem of useless energy consumption for this kind of system.

Wenji, G.; Ling, C.; Dongdong, L.; Mei, S.; Li, Z.

2006-01-01T23:59:59.000Z

428

Climate Zone Number 3 | Open Energy Information  

Open Energy Info (EERE)

Number 3 Number 3 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 3 is defined as Warm - Humid(3A) with IP Units 4500 < CDD50ºF ≤ 6300 and SI Units 2500 < CDD10ºC < 3500 Dry(3B) with IP Units 4500 < CDD50ºF ≤ 6300 and SI Units 2500 < CDD10ºC < 3500 Warm - Marine(3C) with IP Units CDD50ºF ≤ 4500 AND HDD65ºF ≤ 3600 and SI Units CDD10ºC ≤ 2500 AND HDD18ºC ≤ 2000 . The following places are categorized as class 3 climate zones: Abbeville County, South Carolina Adair County, Oklahoma Adams County, Mississippi Aiken County, South Carolina Alameda County, California Alcorn County, Mississippi Alfalfa County, Oklahoma Allendale County, South Carolina Amite County, Mississippi Anderson County, South Carolina

429

Climate Zone Number 5 | Open Energy Information  

Open Energy Info (EERE)

5 5 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 5 is defined as Cool- Humid(5A) with IP Units 5400 < HDD65ºF ≤ 7200 and SI Units 3000 < HDD18ºC ≤ 4000 Dry(5B) with IP Units 5400 < HDD65ºF ≤ 7200 and SI Units 3000 < HDD18ºC ≤ 4000 Marine(5C) with IP Units 5400 < HDD65ºF ≤ 7200 and SI Units 3000 < HDD18ºC ≤ 4000 . The following places are categorized as class 5 climate zones: Ada County, Idaho Adair County, Iowa Adair County, Missouri Adams County, Colorado Adams County, Illinois Adams County, Indiana Adams County, Iowa Adams County, Nebraska Adams County, Pennsylvania Adams County, Washington Albany County, New York Allegan County, Michigan Alleghany County, North Carolina

430

Beckham County, Oklahoma ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleBeckham...

431

Adams County, Mississippi ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAdamsC...

432

Adams County, Washington ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype B Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAdamsC...

433

Appomattox County, Virginia ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAppomat...

434

Amite County, Mississippi ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAmiteC...

435

Amador County, California ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype B Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAmador...

436

Allegany County, Maryland ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAllegan...

437

Alleghany County, Virginia ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAllegha...

438

Arkansas County, Arkansas ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleArkansa...

439

Antelope County, Nebraska ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAntelop...

440

Acadia Parish, Louisiana ASHRAE 169-2006 Climate Zone | Open...  

Open Energy Info (EERE)

Climate Zone Subtype Climate Zone Subtype A Start Date 2006-01-01 Source: ASHRAE 169 Standards http:www.ashrae.org Retrieved from "http:en.openei.orgwindex.php?titleAcadia...

Note: This page contains sample records for the topic "vadose zone contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Virginia Enterprise Zone Job Creation Grant (Virginia) | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Enterprise Zone Job Creation Grant (Virginia) Enterprise Zone Job Creation Grant (Virginia) Virginia Enterprise Zone Job Creation Grant (Virginia) < Back Eligibility Commercial Industrial Savings Cate