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1

Kinetics and thermodynamics of hydrotreating synthetic middle distillates  

SciTech Connect (OSTI)

Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

1987-04-01T23:59:59.000Z

2

Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions  

SciTech Connect (OSTI)

Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

2011-10-06T23:59:59.000Z

3

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of US Navy jet fuel (JP-5) has been related to the amounts of large n-alkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how the n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30, and 32 ppM in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-01-01T23:59:59.000Z

4

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of U.S. Navy jet fuel (JP-5) has been related to the amounts of large nalkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how th n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30 and 32 ppm in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-02-01T23:59:59.000Z

5

Two-stage hydrotreating of a bitumen-derived middle distillate to produce diesel and jet fuels, and kinetics of aromatics hydrogenation  

SciTech Connect (OSTI)

The middle distillate from a synthetic crude oil derived from Athabasca bitumen was further hydrotreated in a downflow pilot unit over a typical NiMo catalyst at 330 to 400 C, 7 to 11 MPa and 0.63 to 1.39 h{sup {minus}1} LHSV. Feed and liquid products were characterized for aromatics, cetane index (CI) and other diesel specification items. Aromatics were determined by a supercritical fluid chromatography method, while CI was determined using the correlation developed at Syncrude Canada Ltd. Also feed and selected products were distilled into a jet fuel cut (150/260 C) by spinning band distillation for the determination of smoke point and other jet fuel specification items. A good relationship between aromatics content and CI was obtained. Kinetics of aromatics hydrogenation were investigated, employing a simple-first order reversible reaction model.

Yui, S.M. [Syncrude Canada Ltd., Edmonton, Alberta (Canada)

1994-12-31T23:59:59.000Z

6

Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers  

E-Print Network [OSTI]

The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

Nelson, R. E.

1982-01-01T23:59:59.000Z

7

PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION  

SciTech Connect (OSTI)

Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

Pierce, R. A.; Pak, D. J.

2012-09-11T23:59:59.000Z

8

Overview of used antifreeze and industrial glycol recycling by vacuum distillation  

SciTech Connect (OSTI)

A leading method of reclaiming ethylene glycol from both used automotive coolants and waste industrial glycol streams is vacuum distillation. Over 15 million gallons per year of total glycols are recovered by this technology, which are marketed for use in antifreeze and industrial chemicals. It is a robust technology, tolerant of many common feed contaminants, and producing minimum waste. This paper presents an overview of vacuum distillation as one part of a multistep process for recovering glycols from a wide variety of feedstreams. Described are industry practices for laboratory prescreening of feedstreams, process adjustments and pretreatments, distillation technologies and post-distillation polishing methods. In each section, information and data are presented from two independent facilities and for several streams processed at each facility. It is concluded that the facilities participating in this study can reliably produce ethylene glycol suitable for the production of ASTM specification engine coolants.

Frye, D.K. [Filter Recovery Services, Alexandria, VA (United States); Chan, K.; Pourhassanian, C. [DeMenno/Kerdoon, Inc., Compton, CA (United States)

1999-08-01T23:59:59.000Z

9

APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE  

SciTech Connect (OSTI)

Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

Pierce, R.; Pak, D.

2011-08-10T23:59:59.000Z

10

Vacuum Distillation  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uraniumE. GreatVENTURADay)

11

Upgrading of western shale oil by hydropyrolysis and hydrotreating  

SciTech Connect (OSTI)

A proof-of-concept study for a new shale oil upgrading and refining process was undertaken. This project is aimed at reducing upgrading costs, thereby malting shale oil development more feasible for commercialization. Raw shale oil was topped to remove the most volatile components. The topped shale oil was distilled into three narrow boiling cuts, representing of 175--275{degrees}C, 275--365{degrees}C, and 365--455{degrees}C, and a residue portion (>455{degrees}C). The distillate cuts were used to study molecular weight effects, and the residue was used to test the performance of hydropyrolysis. Hydropyrolysis converts the heavy residue into lower boiling point materials which can be more easily hydrotreated. In the experiment to test molecular weight effects, it was found that geometric hindrance accounts for the inhibition effect. Diffusion limitation and inhibition by competitive adsorption are not strong effects. These results imply that there is no process substitute for the requirement of molecular weight reduction. In the experiment to test the performance of hydropyrolysis, average molecular weight is reduced from 495 to 359 at moderate severities. In HDN of the hydropyrolized residue, however, high process severities are still required to remove nitrogen to the level of refinery-acceptable-feed (< 0.15 wt %). Based on experimental data, the product slate is 1.9 wt % gas, 13.1 wt % gasoline, 27.3 wt % kerosene, 55.6 wt % total gas oil, 1.3 wt % vacuum residue, and 0.8 wt % coke with 1376 scf/bbl total hydrogen consumption. The removal of sulfur is 96%, and that of nitrogen is 84%. The concentration of sulfur in the final product is 0.038 wt %, and that of nitrogen in final product is 0.26%. The conversion of heavy residue to atmospheric distillate is 47%. However, the remaining residue is partially upgraded as a refinery feed.

Bunger, J.W.; Russell, C.P.; Jeong, Soon-Yong; Pu, J.

1992-07-01T23:59:59.000Z

12

Hydrotreating of oil from eastern oil shale  

SciTech Connect (OSTI)

Oil shale provides one of the major fossil energy reserves for the United States. The quantity of reserves in oil shale is less than the quantity in coal, but is much greater (by at least an order of magnitude) than the quantity of crude oil reserves. With so much oil potentially available from oil shale, efforts have been made to develop techniques for its utilization. In these efforts, hydrotreating has proved to be an acceptable technique for upgrading raw shale oil to make usuable products. The present work demonstrated the use of the hydrotreating technique for upgrading an oil from Indiana New Albany oil shale.

Scinta, J.; Garner, J.W.

1984-01-01T23:59:59.000Z

13

Regeneration of Hydrotreating and FCC Catalysts  

SciTech Connect (OSTI)

Hydrotreating, hydrocracking, and fluid catalytic cracking (FCC) catalysts are important components of petroleum refining processes. Hydrotreating and hydrocracking catalysts are used to improve the yield of high-quality light oil fractions from heavier crude oil and petroleum feedstocks containing high levels of impurities. FCC catalysts improve the yield of higher octane gasoline from crude oil. Residuum hydrotreating and cracking catalysts are susceptible to irreversible deactivation caused by adsorption of sulfur and by metals impurities, such as vanadium and nickel. The gradual buildup of these impurities in a hydrotreating catalyst eventually plugs the pores and deactivates it. Nickel and vanadium adversely affect the behavior of cracking catalysts, reducing product yield and quality. Replacing deactivated catalysts represents a significant cost in petroleum refining. Equally important are the costs and potential liabilities associated with treating and disposing spent catalysts. For example, recent US Environmental Protection Agency rulings have listed spent hydrotreating and hydrorefining catalysts as hazardous wastes. FCC catalysts, though more easily disposed of as road-base or as filler in asphalt and cement, are still an economic concern mainly because of the large volumes of spent catalysts generated. New processes are being considered to increase the useful life of catalysts or for meeting more stringent disposal requirements for spent catalysts containing metals. This report discusses a collaborative effort between Pacific Northwest National Laboratory (PNNL) and Phillips Petroleum, Inc., to identify promising chemical processes for removing metals adhered to spent hydrodesulfurization (HDS, a type of hydrotreating catalyst) and FCC catalysts. This study, conducted by PNNL, was funded by the US Department of Energy's Bartlesville Project Office. Fresh and spent catalysts were provided by Phillips Petroleum. The FCC catalyst was a rare-earth exchanged Y zeolite in a silica-alumina matrix. X-ray fluorescence analyses showed that the rare earths used in preparing the catalysts were a mixture of lanthanum and cerium. Antimony found in the spent catalyst was added during operation of the FCC unit as a way to suppress the adverse effects of deposited nickel. The fresh HDS samples consisted of sulfided nickel and molybdenum on an alumina support. The spent catalyst showed nearly 10% vanadium on the catalyst and a modest increase in nickel and sulfur on the catalyst as a result of operations. Hydrocracking catalysts were not available for this study.

CM Wai; JG Frye; JL Fulton; LE Bowman; LJ Silva; MA Gerber

1999-09-30T23:59:59.000Z

14

Energy efficient distillation apparatus  

SciTech Connect (OSTI)

An energy efficient distillation method is provided which is particularly adapted for use on a dairy farm, and which comprises a distilland evaporating receptacle, a distillate condensing receptacle, and a conduit interconnecting the evaporating receptacle and the condensing receptacle. A vacuum pump is provided for drawing a partial vacuum within the evaporating receptacle, and a vapor compression refrigeration system is provided which includes condenser coils disposed to heat and vaporize the distilland while it is within the evaporating receptacle, and evaporator coils for cooling and condensing the vaporized distilland in the condensing receptacle. A cooling distribution system is also provided whereby a variable portion of the cooling potential of the refrigeration system may be selectively directed to each of the condensing receptacle, a distillate receiver tank, or to a bulk milk container as utilized on a dairy farm or the like.

Melton, J.D.

1982-08-17T23:59:59.000Z

15

Methods of hydrotreating a liquid stream to remove clogging compounds  

DOE Patents [OSTI]

A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

2009-09-22T23:59:59.000Z

16

Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance  

SciTech Connect (OSTI)

In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

Eaton, Scott J [ORNL; Bunting, Bruce G [ORNL; Lewis Sr, Samuel Arthur [ORNL; Fairbridge, Craig [National Centre for Upgrading Technology, Canada

2009-01-01T23:59:59.000Z

17

Characterization of nitrogen compound types in hydrotreated Paraho shale oil  

SciTech Connect (OSTI)

Results from the separation and characterization of nitrogen compound types in hydrotreated Paraho shale oil samples were obtained. Two samples of Paraho shale oil were hydrotreated by Chevron Research Company such that one sample contained about 0.05 wt. percent nitrogen and the other sample contained about 0.10 wt. percent nitrogen. A separation method concentrate specific nitrogen compound types was developed. Characterization of the nitrogen types was accomplished by infrared spectroscopy, mass spectrometry, potentiometric titration, and elemental analysis. The distribution of nitrogen compound types in both samples and in the Paraho crude shale oil is compared.

Holmes, S.A.; Latham, D.R.

1980-10-01T23:59:59.000Z

18

Catalytic Distillation  

E-Print Network [OSTI]

removing both will occur in the temperature range ne~ded high and low boilers to maintain the tower for reaction. One limitation may be .I the composition profile, exothermic reactions critical point of the system, above w~ich can be easily temperature... with significantly less energy. There are two primary reasons for energy reduction: 1. The heat of reaction for exothermic reactions is fully re covered as useful boilup for fractionation. 2. Fewer attendant distillations are normally required than for a...

Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

1984-01-01T23:59:59.000Z

19

Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor  

SciTech Connect (OSTI)

The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental composition was little different from that of the native bitumen except for the hydrogen content which was lower. The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The extent of denitrogenation and desulfurization of the bitumen-derived liquid was used to monitor catalyst activity as a function of process operating variables and to estimate the extent of catalyst deactivation as a function of time on-stream. The apparent kinetics for the nitrogen and sulfur removal reactions were determined. Product distribution and yield data were also obtained.

Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.; Tsai, C.H.

1991-12-31T23:59:59.000Z

20

Hydrotreating the bitumen-derived hydrocarbon liquid produced in a fluidized-bed pyrolysis reactor  

SciTech Connect (OSTI)

The pyrolysis of bitumen-impregnated sandstone produces three primary product streams: C{sub 1}-C{sub 4} hydrocarbons gases, a C{sub 5}{sup +} total liquid product, and a carbonaceous residue on the spent sand. The bitumen-derived hydrocarbon liquid was significantly upgraded relative to the native bitumen: it had a higher API gravity, lower Conradson carbon residue, asphaltene content, pour point and viscosity and a reduced distillation endpoint relative to the native bitumen. The elemental composition was little different from that of the native bitumen except for the hydrogen content which was lower. The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The extent of denitrogenation and desulfurization of the bitumen-derived liquid was used to monitor catalyst activity as a function of process operating variables and to estimate the extent of catalyst deactivation as a function of time on-stream. The apparent kinetics for the nitrogen and sulfur removal reactions were determined. Product distribution and yield data were also obtained.

Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.; Tsai, C.H.

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case  

SciTech Connect (OSTI)

The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed prep, fast pyrolysis, and upgrading. Stabilized, upgraded pyrolysis oil is transferred to the refinery for separation and finishing into motor fuels. The off-gas from the hydrotreaters is also transferred to the refinery, and in return the refinery provides lower-cost hydrogen for the hydrotreaters. This reduces the capital investment. Production costs near $2/gal (in 2007 dollars) and petroleum industry infrastructure-ready products make the production and upgrading of pyrolysis oil to hydrocarbon fuels an economically attractive source of renewable fuels. The study also identifies technical areas where additional research can potentially lead to further cost improvements.

Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

2009-02-25T23:59:59.000Z

22

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case  

SciTech Connect (OSTI)

The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed prep, fast pyrolysis, and upgrading. Stabilized, upgraded pyrolysis oil is transferred to the refinery for separation and finishing into motor fuels. The off-gas from the hydrotreaters is also transferred to the refinery, and in return the refinery provides lower-cost hydrogen for the hydrotreaters. This reduces the capital investment. Production costs near $2/gal (in 2007 dollars) and petroleum industry infrastructure-ready products make the production and upgrading of pyrolysis oil to hydrocarbon fuels an economically attractive source of renewable fuels. The study also identifies technical areas where additional research can potentially lead to further cost improvements.

Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

2009-02-28T23:59:59.000Z

23

Energy Efficiency Improvement in the Petroleum Refining Industry  

E-Print Network [OSTI]

i.e. crude distillation, hydrotreating, reforming, vacuumthe severity and in hydrotreating the treated feed may

Worrell, Ernst; Galitsky, Christina

2005-01-01T23:59:59.000Z

24

Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)  

SciTech Connect (OSTI)

Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

French, R. J.

2013-09-01T23:59:59.000Z

25

Fast Pyrolysis and Hydrotreating 2013 State of Technology R&D and Projections to 2017  

SciTech Connect (OSTI)

This report documents the FY13 modeled costs and experimental basis for those costs for fast pyrolyis and hydrotreating to liquid fuels. The report also documents the projected costs to 2013.

Jones, Susanne B.; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Zacher, Alan H.; Olarte, Mariefel V.; Drennan, Corinne

2014-04-16T23:59:59.000Z

26

Elucidation of the inorganic chemistry of hydrotreating catalysts  

SciTech Connect (OSTI)

New environmental regulations are making it necessary to developed improved hydrotreating catalysts for the removal of sulfur, nitrogen and aromatics from refinery streams. In order to develop better catalysts, the authors must gain a more detailed understanding of the inorganic chemistry of these catalysts. Commercial catalysts typically contain ca. 15 wt% molybdenum or tungsten oxides and ca. 4 wt% nickel or cobalt. Additives, such as phosphate and fluoride, are often added to improve the catalytic activity. However, the role of these additives is not fully understood. The authors have, therefore, carried out studies on alumina supported phosphate and flouride materials using FT-IR, powder x-ray diffraction, and solid-state NMR ({sup 31}P, {sup 27}Al, and {sup 1}H). The results of this work have enabled the authors to determine the structures of the various compounds formed on the alumina system when fluoride or phosphate is present.

DeCanio, E.C.; Edwards, J.C.; Storm, D.A. [Texaco, Inc., Beacon, NY (United States); Bruno, J.W. [Wesleyan Univ., Middletown, CT (United States)

1993-12-31T23:59:59.000Z

27

INNOVATION EDUCATION EXCELLENCE DISTILLATIONS  

E-Print Network [OSTI]

INNOVATION · EDUCATION · EXCELLENCE DISTILLATIONS University of Toronto CHEMISTRY ALUMNI MAGAZINE.utoronto.ca / distillations 2012 MessagefromtheChair Our Department of Chemistry has one of the finest collection of peo- ple to a better, more sustain- able future. This issue of Distillations highlights the accomplishments last year

Chan, Hue Sun

28

Hydrotreating Uinta Basin bitumen-derived heavy oils  

SciTech Connect (OSTI)

Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

Longstaff, D.C.; Balaji, G.V.; Kim, J.W. [Univ. of Utah, Salt Lake City, UT (United States)] [and others

1995-12-31T23:59:59.000Z

29

Biofuels production from hydrotreating of vegetable oil using supported noble metals, and transition metal carbide and nitride.  

E-Print Network [OSTI]

?? The focus of this research is to prepare non-sulfided hydrotreating catalysts, supported noble metal and transition metal carbide/ nitride, and evaluate their hydrocracking activities… (more)

Wang, Huali

2012-01-01T23:59:59.000Z

30

Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates  

SciTech Connect (OSTI)

High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

1987-04-01T23:59:59.000Z

31

Hydrotreating the native bitumen from the Whiterocks tar sand deposit  

SciTech Connect (OSTI)

The bitumen from the Whiterocks oil sand deposit in the Uinta Basin of eastern Utah was hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The process variables investigated included reactor pressure (11.2--16.7 MPa); reactor temperature (641--712 K) and liquid hourly space velocity (0.19--0.77 h{sup {minus}1}). The hydrogen/oil ratio, 890 m{sup 3} m{sup {minus}3} was fixed in all experiments. A sulphided Ni-Mo on alumina hydrodenitrogenation catalyst was used in these studies. The deactivation of the catalyst, 0.2 {degree}C/day, was monitored by thedecline in the API gravity of the total liquid product with time on-stream at a standard set of conditions. The effect of temperature, WHSV, and pressure on denitrogenation, desulphurization, and metals removalwere studied and apparent kinetic parameters determined. The effect of process variables on residue conversion and Conradson carbon residue reduction were also investigated.

Longstaff, D.C.; Deo, M.D.; Hanson, F.V.

1993-03-01T23:59:59.000Z

32

Hydrotreating the native bitumen from the Whiterocks tar sand deposit  

SciTech Connect (OSTI)

The bitumen from the Whiterocks oil sand deposit in the Uinta Basin of eastern Utah was hydrotreated in a fixed-bed reactor to determine the extent of upgrading as a function of process operating variables. The process variables investigated included reactor pressure (11.2--16.7 MPa); reactor temperature (641--712 K) and liquid hourly space velocity (0.19--0.77 h[sup [minus]1]). The hydrogen/oil ratio, 890 m[sup 3] m[sup [minus]3] was fixed in all experiments. A sulphided Ni-Mo on alumina hydrodenitrogenation catalyst was used in these studies. The deactivation of the catalyst, 0.2 [degree]C/day, was monitored by thedecline in the API gravity of the total liquid product with time on-stream at a standard set of conditions. The effect of temperature, WHSV, and pressure on denitrogenation, desulphurization, and metals removalwere studied and apparent kinetic parameters determined. The effect of process variables on residue conversion and Conradson carbon residue reduction were also investigated.

Longstaff, D.C.; Deo, M.D.; Hanson, F.V.

1993-01-01T23:59:59.000Z

33

Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds  

SciTech Connect (OSTI)

There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

Wang, Huamin; Male, Jonathan L.; Wang, Yong

2013-05-01T23:59:59.000Z

34

Advanced Distillation Final Report  

SciTech Connect (OSTI)

The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

2010-03-24T23:59:59.000Z

35

Distillation: The Efficient Workhorse  

E-Print Network [OSTI]

DISTILLATION: THE EFFICIENT WORKHORSE Dan Steinmeyer Monsanto Company St. Louis, Missouri Distillation is inherently highly efficient: phase separation is clean it is relatively easy to build a mUltistage countercurrent device equilibrium... of separation to the work pmbedded in the reboiler and condenser thermal flows. The right application is one where the streams ? separated both exceed la' of the feed, relative volatility exceeds 1.2, and separation is complete - i.e. pure products...

Steinmeyer, D.

36

Accelerated deployment of nanostructured hydrotreating catalysts. Final CRADA Report.  

SciTech Connect (OSTI)

Nanomanufacturing offers an opportunity to create domestic jobs and facilitate economic growth. In response to this need, U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy issued a Research Call to develop nanomanufacturing capabilities at the National Laboratories. High performance catalysts represent a unique opportunity to deploy nanomanufacturing technologies. Re-refining of used lube oil offers an opportunity to create manufacturing jobs and decrease dependence on imported petroleum. Improved catalysts are required to produce a better quality product, decrease environmental impact, extend catalyst life, and improve overall economics of lube oil re-refining. Argonne National Laboratory (Argonne) in cooperation with Universal Lubricants, Inc. (ULI) and Chemical Engineering Partners (CEP) have carried out a Cooperative Research and Development Agreement (CRADA) to prepare nanostructured hydrotreating catalysts using atomic layer deposition (ALD) to exhibit superior performance for the re-refining of used lube oil. We investigated the upgrading of recycled lube oil by hydrogenation using commercial, synthetically-modified commercial catalysts, and synthesized catalysts. A down-flow (trickle bed) catalytic unit was used for the hydrogenation experiments. In addition to carrying out elemental analyses of the various feed and product fractions, characterization was undertaken using H{sup 1} and C{sup 13} NMR. Initially commercial were evaluated. Second these commercial catalysts were promoted with precious metals using atomic layer deposition (ALD). Performance improvements were observed that declined with catalyst aging. An alternate approach was undertaken to deeply upgrade ULI product oils. Using a synthesized catalyst, much lower hydrogenation temperatures were required than commercial catalysts. Other performance improvements were also observed. The resulting lube oil fractions were of high purity even at low reaction severity. The products recovered from both the ALD and other processes were water-white (even those from the low temperature, low residence time (high space velocity), low conversion runs). These results indicate that highly upgraded recycle lube oils can be produced using ALD-deposited active metal catalysts. The use of H{sup 1} and C{sup 13} NMR for the characterization of the treated lube oils has been shown to be effective.

Libera, J.A.; Snyder, S.W.; Mane, A.; Elam, J.W.; Cronauer, D.C.; Muntean, J.A.; Wu, T.; Miller, J.T. (Chemical Sciences and Engineering Division); ( ES)

2012-08-27T23:59:59.000Z

37

Review of SRC-II process product hydrotreating data, for completeness and applicability to the demo plant  

SciTech Connect (OSTI)

The SRC-II product naphtha, gas oil, and whole liquid product hydrotreating data base was reviewed for completeness and applicability to the design of the SRC-II Demonstration Plant. Primary data sources were the Chevron and the UOP experimental hydrotreating work and the PNL bioassay investigations on UOP hydrotreated samples. Secondary data were the hydrotreating data for both the EDS and the H-Coal liquid products. The SRC-II product hydrotreating data are sparse at this point, but in view of the fact that these data can be supplemented through correlation with the corresponding data for the EDS and H-Coal liquid fractions, it is concluded that a sufficient data base exists for the closure of a hydrotreating plant material balance at least in the hydrotreating severity range of the Phase 0 design goals. Little thermal property data appear in the literature for coal-derived liquids; thus it will be necessary to draw upon correlations developed in the petroleum industry for closure of the plant energy balance unless experimental thermal property data are forthcoming. An area of uncertainty and concern at this time is the extent to which the Demo Plant product mutagenicity would be reduced by hydrotreatment. Although bioassay tests were conducted on both moderately and severely hydrotreated SRC-II Pilot Plant gas oil, the Demo Plant product is expected to contain an appreciable fraction of 800/sup 0/F/sup +/ material, compared with the Pilot Plant product, which contained essentially no material in this higher boiling range.

Frazier, G.C.; Faruqi, A.

1981-03-01T23:59:59.000Z

38

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2011 State of Technology and Projections to 2017  

SciTech Connect (OSTI)

Review of the the status of DOE funded research for converting biomass to liquid transportation fuels via fast pyrolysis and hydrotreating for fiscal year 2011.

Jones, Susanne B.; Male, Jonathan L.

2012-02-01T23:59:59.000Z

39

Identifying Opportunities for Industrial Energy Conservation  

E-Print Network [OSTI]

. Cement Making 5. Vacuum Distillation 4. Cooking 6. Hydrocracking 5. Glass Melting 7. Hydrogen Production 6. Copper Smelting 8. Hydrorefining/Hydrotreating 7. Miscellaneous 9. Visbreaking 10. Petroleum Coking 11. Desulfurization C. Iron and Steel I...

Hoffman, A. R.

1981-01-01T23:59:59.000Z

40

Energy Conservation and the Environment - Designing for Cost Savings and Minimum Emissions  

E-Print Network [OSTI]

!' completed for a large West Coast refin r. The units evaluated included Crude and Vacuum, Gas Plant, Naphtha Hydrotreati g, Reforming, Distillate Hydrotreating, Hydrocracking, Hydrogen Plant, and cok~ng. A total of 80 energy conservation proj...

Johnnie, D. H., Jr.; Klooster, H. J.; Nagy, J. F.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Hydrotreating process kinetics for bitumen and bitumen-derived liquids  

SciTech Connect (OSTI)

Hydrodenitrogenation, hydrodesulfurization and resid conversion data for the Whiterocks bitumen and bitumen-derived liquid were analyzed using a modified power rate law model. The model incorporated the space velocity and pressure since the plug flow equation may not be applicable to laboratory-scale reactors in which complete wetting of the catalyst may not be attained. The data were obtained with the reactor operating as a fixed bed reactor in the upflow mode. The space velocity (WHSV{sup {alpha}}) term was included to account for deviations from plug flow behavior. The exponents (a,p) and the kinetic parameters were obtained by combined non-linear regression and ODE solver techniques for the analysis of laboratory data. A simple nth order power rate law expression for hydrodenitrogenation and hydrodesulfurization was examined. The higher than first order kinetics for hydrodenitrogenation and hydrodesulfurization of the bitumen and bitumen-derived liquids were explained by invoking two parallel first-order reactions; one slow and the other fast. Parallel and consecutive reaction schemes were used to examine the extent of conversion of the resid fraction to middle distillate, gas oil and gasoline and the apparent kinetic parameters were determined. It was determined that the upflow operating mode was preferred to the trickle-bed mode in the laboratory reactor to insure plug flow behavior.

Kwak, S.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.

1993-03-01T23:59:59.000Z

42

New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes  

SciTech Connect (OSTI)

This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

Agrawal, Rakesh

2013-11-21T23:59:59.000Z

43

Reflux for multifeed distillation  

SciTech Connect (OSTI)

Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

Chou, S.M.; Yaws, C.L.

1986-12-01T23:59:59.000Z

44

Low Energy Distillation Schemes  

E-Print Network [OSTI]

an important means of reducing energy consumption in distillation processes. However, its conventional use requires the installation of piping (and pipes carrying vapour streams tend to be of large diameter and are consequently expensive). So, finally we.... However, its conventional use requires the installation of piping (and pipes carrying vapour streams tend to be of large diameter and are consequently expensive). In the late eighties engineers in Germany [e.g. Kaibel, 1987] looked at one way in which...

Polley, G. T.

45

Energy efficiency improvement and cost saving opportunities for petroleum refineries  

E-Print Network [OSTI]

Hydrocracking Hydrotreating Alkylation Polymerization/Dim.i.e. , crude distillation, hydrotreating, reforming, vacuumin an increase of hydrotreating capacity at the petroleum

Worrell, Ernst; Galitsky, Christina

2005-01-01T23:59:59.000Z

46

A Characterization and Evaluation of Coal Liquefaction Process Streams. Results of Inspection Tests on Nine Coal-Derived Distillation Cuts in the Jet Fuel Boiling Range  

SciTech Connect (OSTI)

This report describes the assessment of the physical and chemical properties of the jet fuel (180-300 C) distillation fraction of nine direct coal liquefaction products and compares those properties to the corresponding specifications for aviation turbine fuels. These crude coal liquids were compared with finished fuel specifications specifically to learn what the refining requirements for these crudes will be to make them into finished fuels. The properties of the jet fuel fractions were shown in this work to require extensive hydrotreating to meet Jet A-1 specifications. However, these materials have a number of desirable qualities as feedstocks for the production of high energy-density jet fuels.

S. D. Brandes; R. A. Winschel

1999-12-30T23:59:59.000Z

47

Oil recovery from condensed corn distillers solubles.  

E-Print Network [OSTI]

??Condensed corn distillers solubles (CCDS) contains more oil than dried distillers grains with solubles (DDGS), 20 vs. 12% (dry weight basis). Therefore, significant amount of… (more)

Majoni, Sandra

2009-01-01T23:59:59.000Z

48

Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid  

SciTech Connect (OSTI)

The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

1991-12-31T23:59:59.000Z

49

Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid  

SciTech Connect (OSTI)

The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

1991-01-01T23:59:59.000Z

50

Optimal Control of Distillation Systems  

E-Print Network [OSTI]

The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

Chatterjee, N.; Suchdeo, S. R.

1984-01-01T23:59:59.000Z

51

Vacuum Technology  

SciTech Connect (OSTI)

The environmental condition called vacuum is created any time the pressure of a gas is reduced compared to atmospheric pressure. On earth we typically create a vacuum by connecting a pump capable of moving gas to a relatively leak free vessel. Through operation of the gas pump the number of gas molecules per unit volume is decreased within the vessel. As soon as one creates a vacuum natural forces (in this case entropy) work to restore equilibrium pressure; the practical effect of this is that gas molecules attempt to enter the evacuated space by any means possible. It is useful to think of vacuum in terms of a gas at a pressure below atmospheric pressure. In even the best vacuum vessels ever created there are approximately 3,500,000 molecules of gas per cubic meter of volume remaining inside the vessel. The lowest pressure environment known is in interstellar space where there are approximately four molecules of gas per cubic meter. Researchers are currently developing vacuum technology components (pumps, gauges, valves, etc.) using micro electro mechanical systems (MEMS) technology. Miniature vacuum components and systems will open the possibility for significant savings in energy cost and will open the doors to advances in electronics, manufacturing and semiconductor fabrication. In conclusion, an understanding of the basic principles of vacuum technology as presented in this summary is essential for the successful execution of all projects that involve vacuum technology. Using the principles described above, a practitioner of vacuum technology can design a vacuum system that will achieve the project requirements.

Biltoft, P J

2004-10-15T23:59:59.000Z

52

Distilling entanglement from arbitrary resources  

E-Print Network [OSTI]

We obtain the general formula for the optimal rate at which singlets can be distilled from any given noisy and arbitrarily correlated entanglement resource, by means of local operations and classical communication (LOCC). Our formula, obtained by employing the quantum information spectrum method, reduces to that derived by Devetak and Winter, in the special case of an i.i.d. resource. The proofs rely on a one-shot version of the so-called "hashing bound," which in turn provides bounds on the one-shot distillable entanglement under general LOCC.

Francesco Buscemi; Nilanjana Datta

2010-10-15T23:59:59.000Z

53

Corrosion inhibition for distillation apparatus  

DOE Patents [OSTI]

Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY); Schweighardt, Frank K. (Upper Macungie, PA)

1985-01-01T23:59:59.000Z

54

Optimal distillation using thermodynamic geometry Bjarne Andresen  

E-Print Network [OSTI]

(temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2Optimal distillation using thermodynamic geometry Bjarne Andresen Ørsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler

Salamon, Peter

55

Momentive Performance Materials Distillation Intercharger  

E-Print Network [OSTI]

Presenter: Nicki (Collins) Boucher Project Team: T. Baisley, C. Beers, R. Cameron, K. Holman, T. Kotkoskie, K. Norris Momentive Performance Materials Inc. Waterford, NY May 23, 2013 Industrial Energy Technology Conference ACC Responsible... Care? Energy Efficiency Program Momentive Performance Materials Distillation Interchanger ESL-IE-13-05-20 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Copyright 2013 Momentive Performance...

Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

2013-01-01T23:59:59.000Z

56

Vacuum Waves  

E-Print Network [OSTI]

As an example of the unification of gravitation and particle physics, an exact solution of the five-dimensional field equations is studied which describes waves in the classical Einstein vacuum. While the solution is essentially 5D in nature, the waves exist in ordinary 3D space, and may provide a way to test for an extra dimension.

Paul S. Wesson

2012-12-11T23:59:59.000Z

57

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2012 State of Technology and Projections to 2017  

SciTech Connect (OSTI)

This report summarizes the economic impact of the work performed at PNNL during FY12 to improve fast pyrolysis oil upgrading via hydrotreating. A comparison is made between the projected economic outcome and the actual results based on experimental data. Sustainability metrics are also included.

Jones, Susanne B.; Snowden-Swan, Lesley J.

2013-08-27T23:59:59.000Z

58

Rank three bipartite entangled states are distillable  

E-Print Network [OSTI]

We prove that the bipartite entangled state of rank three is distillable. So there is no rank three bipartite bound entangled state. By using this fact, We present some families of rank four states that are distillable. We also analyze the relation between the low rank state and the Werner state.

Lin Chen; Yi-Xin Chen

2008-03-07T23:59:59.000Z

59

Locally Accessible Information and Distillation of Entanglement  

E-Print Network [OSTI]

A new type of complementary relation is found between locally accessible information and final average entanglement for given ensemble. It is also shown that in some well known distillation protocol, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

Sibasish Ghosh; Pramod Joag; Guruprasad Kar; Samir Kunkri; Anirban Roy

2004-03-18T23:59:59.000Z

60

Forpeerreview Synthesis of Complex Thermally Coupled Distillation  

E-Print Network [OSTI]

US energy consumption, which is equivalent to 2.87x10 18 J (2.87 million TJ) per year, or to a power; Divided Wall Column; Superstructure optimization; GDP. Introduction Distillation is one of the most limitations. Distillation columns use very large amounts of energy because the evaporation steps involved

Grossmann, Ignacio E.

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Distillability of entanglement in accelerated frames  

E-Print Network [OSTI]

We study the entanglement distillability of bipartite mixed states of two modes of a free Dirac field as seen by two relatively accelerated parties. It is shown that there are states that will change from distillable into separable for a certain value of acceleration. We exemplify these criteria in the context of Werner states.

Shahpoor Moradi

2012-01-02T23:59:59.000Z

62

New Design Methods and Algorithms for Multi-component Distillation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf More...

63

acrobat distiller job: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

64

Distillation: Still towering over other options  

SciTech Connect (OSTI)

Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

Kunesh, J.G. [Fractionation Research, Inc., Stillwater, OK (United States); Kister, H.Z. [Brown and Root, Inc., Alhambra (Canada); Lockett, M.J. [Praxair, Inc., Tonawanda, NY (United States); Fair, J.R. [Univ. of Texas, Austin, TX (United States)

1995-10-01T23:59:59.000Z

65

Development of energy efficient membrane distillation systems  

E-Print Network [OSTI]

Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

Summers, Edward K

2013-01-01T23:59:59.000Z

66

Minimizing corrosion in coal liquid distillation  

DOE Patents [OSTI]

In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

1985-01-01T23:59:59.000Z

67

Absorptive Recycle of Distillation Waste Heat  

E-Print Network [OSTI]

condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

Erickson, D. C.; Lutz, E. J., Jr.

1982-01-01T23:59:59.000Z

68

An improved model for multiple effect distillation  

E-Print Network [OSTI]

Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

Mistry, Karan H.

69

Advancing Biorefining of Distillers Grain and Corn Stover Blends  

Broader source: Energy.gov (indexed) [DOE]

pretreatment process for distiller's grains and corn stover to convert residual starch, cellulose, and hemicellulose to ethanol and high- converting residual starch in order to...

70

Complex Fluid Analysis with the Advanced Distillation Curve Approach  

E-Print Network [OSTI]

of a complex fluid is a graph of boiling temperature versus volume fraction distilled, a procedure embodied for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements) an assessment of the energy content of each distillate fraction; (6) trace chemical analysis of each distillate

71

ultrahigh vacuum | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ultrahigh vacuum ultrahigh vacuum Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a...

72

Hydrogenation of individual components isolated from Athabasca bitumen vacuum resid  

SciTech Connect (OSTI)

The ability to produce synthetic fuels from heavy oils and vacuum resids depends on a number of factors, among them being geological origin, thermal history and type of upgrading process. In general, the properties of resids are sufficiently different that for each a unique set of processing conditions can be found to optimize its conversion to distillate. Ideally, one would like to predict a resid's upgradability and the optimum processing conditions from a few simple analytical lab tests. Unfortunately, properties of vacuum resids determined by conventional analytical methods correlate only loosely with upgradability. The pitch conversion and distillate yield most commonly used to monitor processes provide little insight into the upgrading chemistry. The same can be said for global parameters such as sulfur and nitrogen conversions. At present there is no recourse but to process each feedstock on a suitable large scale. This is expensive and time consuming. The objective of the present study is to establish a good model of upgrading chemistry that explains which components in a feedstock cause problems, which are most reactive, which interact with catalysts, and which convert to distillate or residue. Such knowledge should lead to analytical methods sensitive to the chemical changes occurring during upgrading. This paper reports the modified chromatographic separation procedures and some initial results for the hydroprocessing of Athabasca bitumen vacuum resid (ABVB) and its maltene and asphaltene components using a newly designed bubbling microautoclave.

Dawson, W.H. (CANMET, Ottawa, Ontario (Canada)); Chornet, E.; Tiwari, P.; Heitz, M. (Sherbrooke Univ., Quebec (Canada))

1989-04-01T23:59:59.000Z

73

Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) Geographic Area Month Kerosene No. 1 Distillate No. 2...

74

Desalination Using Vapor-Compression Distillation  

E-Print Network [OSTI]

and MSF, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas...

Lubis, Mirna R.

2010-07-14T23:59:59.000Z

75

Complex Distillation Arrangements : Extending the Petlyuk Ideas  

E-Print Network [OSTI]

to distillation columns ac- count for roughly 3 of the total energy consumption in the U.S. (Ognisty 1995 to reduce energy consumption at least two alternative approaches have been proposed both in the literature is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

Skogestad, Sigurd

76

Minimum Energy Diagrams for Multieffect Distillation Arrangements  

E-Print Network [OSTI]

and the energy use from this process accounts for an estimated 3% of the world energy consumption.1 With rising on the overall plant energy consumption. The use of heat integration combined with complex config- urations distillation ar- rangements. An easy form of comparison for energy consumption is the minimum vapor flow rate

Skogestad, Sigurd

77

Naphthenic acid corrosion in crude distillation units  

SciTech Connect (OSTI)

This paper summarizes corrosion experience in crude distillation units processing highly naphthenic California crude oils. Correlations have been developed relating corrosion rates to temperature and total acid number. There is a threshold acid number in the range of 1.5 to 2 mg KOH/g below which corrosion is minimal. High concentrations of hydrogen sulfide may raise this threshold value.

Piehl, R.L.

1988-01-01T23:59:59.000Z

78

Distillation: Present Status and Future Directions  

E-Print Network [OSTI]

-pressure steam as a heat source. The steam has, very likely, been sent through one or more users (turbi ne dri ves) before reaching the distillation reboiler. It seems almost characteristic of large chemical and refining complexes that there is a chronic...

Fair, J. R.; Humphrey, J. L.

1984-01-01T23:59:59.000Z

79

Construction and operation of a flash distillation apparatus  

E-Print Network [OSTI]

, Calibration Data of Orifioe ~, i, . ~ ~ ~ . ~ ~ . ~ 13 III. Equilibrium Data of Ethanol-Eater Mixtures . ~ * ~ ~ , 17 IV, . Flash Vaporieation Data of Ethanol Hater hIlxtures& + , 18 VI ~ Hempel Distillation of Oklahoma City Crude ~ . . . Flash... Vaporiration of Oklahoma City Crude ~ . ~ 21 22 VII' Hempel Distillations of Flash Distillates of Oklahoma City Crude . ~ ~ ~ ~ ~ ~ ~ i ~ ~ ~ ~ ~ ~ ~ ~ 24 VIII+ Hompel Distillations of Flash Residuums of Oklahoma City Crude ~ ~ ~ ~ ~ i ~ ~ o...

Knezevich, Milan

2012-06-07T23:59:59.000Z

80

Integrated C3 Feedstock and Aggregated Distillation Model for  

E-Print Network [OSTI]

Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits Distillation Model Relates overhead composition of propane with flowrate of propane feed to the splitter

Grossmann, Ignacio E.

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens,  

E-Print Network [OSTI]

to infinity. We call such protocols asymp- totic and the fraction of distilled Bell states per initial copy#12;#12;Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens, Jeroen: July 13, 2006) We present a new asymptotic bipartite entanglement distillation protocol

82

DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY  

E-Print Network [OSTI]

: 47-7-594080 Figure 1: Typical simple distillation column. zF, yD and xB are mole fractions. tureDYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed

Skogestad, Sigurd

83

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network [OSTI]

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

84

DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY  

E-Print Network [OSTI]

distillation column. z F , yD and xB are mole fractions. ture review, but a few new ideas are also presentedDYNAMICS AND CONTROL OF DISTILLATION COLUMNS ­ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177­217, 1997. Abstract Distillation column dynamics and control has been viewed

Skogestad, Sigurd

85

Model Predictive Control of a Kaibel Distillation Column  

E-Print Network [OSTI]

column with model predictive control (MPC). A Kaibel distillation column has several advantages comparedModel Predictive Control of a Kaibel Distillation Column Martin Kvernland Ivar Halvorsen Sigurd only a single column shell. The distillation process is a multivariable process which leads

Skogestad, Sigurd

86

RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT  

E-Print Network [OSTI]

RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT J. R. Taylor**, 0. Hansen*, C. Jensen*, 0. F. A risk analysis of a batch distillation unit is de- scribed. The analysis has been carried out at several.2. Objectives and organisation 5 1.2.2. Philosophy and approach 6 1.3.1. The distillation unit 8 1

87

CHEM333: Experiment 4: Steam Distillation of Essential Oils;  

E-Print Network [OSTI]

CHEM­333: Experiment 4: Steam Distillation of Essential Oils; Experiments A, C, D and below. Reading: For this experiment read Chapter 10. This week you will get to use steam distillation to isolate may wait until you come to lab to find out which spice you get. Steam distillation is not a common

Taber, Douglass

88

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1984-03-27T23:59:59.000Z

89

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1985-08-20T23:59:59.000Z

90

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1984-01-01T23:59:59.000Z

91

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1985-01-01T23:59:59.000Z

92

Material Safety Data Sheet 1. PRODUCT IDENTIFICATION  

E-Print Network [OSTI]

Weight% ACGIH; TLV-TWA OSHA PEL DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC 64742-52-5 >50

Rollins, Andrew M.

93

Material Safety Data Sheet Revision Number: 003.2 Issue date: 11/17/2011  

E-Print Network [OSTI]

% Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 30 - 60 Copper 7440-50-8 10 - 30 Graphite

Rollins, Andrew M.

94

Apparatus for distilling shale oil from oil shale  

SciTech Connect (OSTI)

An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

Shishido, T.; Sato, Y.

1984-02-14T23:59:59.000Z

95

An evaluation of the potential end uses of a Utah tar sand bitumen. [Tar sand distillate  

SciTech Connect (OSTI)

To date the commercial application of tar sand deposits in the United States has been limited to their use as paving materials for county roads, parking lots, and driveways because the material, as obtained from the quarries, does not meet federal highway specifications. The bitumen in these deposits has also been the subject of upgrading and refining studies to produce transportation fuels, but the results have not been encouraging from an economic standpoint. The conversion of tar sand bitumen to transportation fuels cannot compete with crude oil refining. The purposes of this study were two-fold. The first was to produce vacuum distillation residues and determine if their properties met ASTM asphalt specifications. The second was to determine if the distillates could serve as potential feedstocks for the production of aviation turbine fuels. The bitumen used for this study was the oil produced during an in situ steamflood project at the Northwest Asphalt Ridge (Utah) tar sand deposit. Two distillation residues were produced, one at +316/sup 0/C and one at +399/sup 0/C. However, only the lower boiling residue met ASTM specifications, in this case as an AC-30 asphalt. The original oil sample met specifications as an AC-5 asphalt. These residue samples showed some unique properties in the area of aging; however, these properties need to be investigated further to determine the implications. It was also suggested that the low aging indexes and high flow properties of the asphalts may be beneficial for pavements that require good low-temperature performance. Two distillate samples were produced, one at IBP-316/sup 0/C and one at IBP-399/sup 0/C. The chemical and physical properties of these samples were determined, and it was concluded that both samples appear to be potential feedstocks for the production of aviation turbine fuels. However, hydrogenation studies need to be conducted and the properties of the finished fuels determined to verify the prediction. 14 refs., 12 tabs.

Thomas, K.P.; Harnsberger, P.M.; Guffey, F.D.

1986-09-01T23:59:59.000Z

96

Physical Vacuum in Superconductors  

E-Print Network [OSTI]

Although experiments carried out by Jain et al. showed that the Cooper pairs obey the strong equivalence principle, The measurement of the Cooper pairs inertial mass by Tate et al. revealed an anomalous excess of mass. In the present paper we interpret these experimental results in the framework of an electromagnetic model of dark energy for the superconductors' vacuum. We argue that this physical vacuum is associated with a preferred frame. Ultimately from the conservation of energy for Cooper pairs we derive a model for a variable vacuum speed of light in the superconductors physical vacuum in relation with a possible breaking of the weak equivalence principle for Cooper pairs.

Clovis Jacinto de Matos

2009-08-31T23:59:59.000Z

97

EMSL - ultrahigh vacuum  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ultrahigh-vacuum en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-structural-d...

98

Energy conservation in distillation: a technology applications manual  

SciTech Connect (OSTI)

Distillation is the most widely practiced technique for separating mixtures of chemical species, but it is an energy intensive process. A 10% reduction in distillation energy consumption would effect a significant savings. On a national basis this would be an annual savings of 200 trillion Btu, or the equivalent of 36.5 million barrels of oil per year. Technology to achieve these savings in distillation energy is available and measures are presented to assist process engineers in technical and economic analysis of the energy conservation measures most suitable for particular distillation applications. The manual catalogs all of the energy conservation options applicable to distillation and the options by the investment required; describes in detail the options having a significant potential to reduce distillation energy requirements economically; provides guidelines that will allow the plant engineer to quickly screen each option for his application; and provides short-cut calculation procedures for use in a preliminary economic analysis of promising options.

Not Available

1980-05-01T23:59:59.000Z

99

Energy Conservation Options in Distillation Processes  

E-Print Network [OSTI]

~itroo.? ':!OD.e~tell.,..ot!.k1 .'k..,.-.ottNltlu'..,. II ""'I'JI ..... ~I_ """-.4008l1"OO I ~.z.,. 1 ,1'1 (-frl-.'....u_~ R.da at AC~Ofllftl\\,J'ftlit...." ? I 5 "'-tlnc&! Tt.,.. ? 21.' \\lip Gilil.In31 j TnyE.'tIc>Mcy .11.1'llo I ~~TI""'.'2.at... I There are many options available to the engi*eer seeking to reduce the energy requirements of a distil lation process. The technology for most of these I, options has been available for many years, but it has only recently become economically...

Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

1980-01-01T23:59:59.000Z

100

Use of computers for multicomponent distillation calculations  

E-Print Network [OSTI]

The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

Sullivan, Samuel Lane

1959-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Advanced Distillation: Programs Proposed to DOE  

E-Print Network [OSTI]

to the foremost practitioner of the Advanced Distillation art, due to a 30 year continuity in Ule area as both a consultant and a university professor. His consulting assignments lu1ve been long-ternl

Woinsky, S. G.

102

advanced distillation control: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Morari California.Eng., Norwegian Institute of Technology (NTH), N-7034 Trondheim, Norway Paper presented at Symposium Distillation Skogestad, Sigurd 14 CONTROL AND ENERGY...

103

azeotropic distillation columns: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT How can we separate ternary mixtures in closed batch...

104

Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

105

Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...  

Gasoline and Diesel Fuel Update (EIA)

Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

106

Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...  

Gasoline and Diesel Fuel Update (EIA)

Marketing Annual 1996 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

107

Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

108

Vacuum Energy Decay  

E-Print Network [OSTI]

The problem of the vacuum energy decay is studied through the analysis of the vacuum survival amplitude ${\\mathcal A}(z, z')$. Transition amplitudes are computed for finite time-span, $Z\\equiv z^\\prime-z$, and their {\\em late time} behavior is discussed up to first order in the coupling constant, $\\l$.

Enrique Álvarez; Roberto Vidal

2011-11-09T23:59:59.000Z

109

Vacuum Vessel Remote Handling  

E-Print Network [OSTI]

and Remote Handling 4 Vacuum vessel functions · Plasma vacuum environment · Primary tritium confinement, incl ports 65 tonnes - Weight of torus shielding 100 tonnes · Coolant - Normal Operation Water, Handling 12 Vessel octant subassembly fab. (3) · Octant-to-octant splice joint requires double wall weld

110

Microfabricated triggered vacuum switch  

DOE Patents [OSTI]

A microfabricated vacuum switch is disclosed which includes a substrate upon which an anode, cathode and trigger electrode are located. A cover is sealed over the substrate under vacuum to complete the vacuum switch. In some embodiments of the present invention, a metal cover can be used in place of the trigger electrode on the substrate. Materials used for the vacuum switch are compatible with high vacuum, relatively high temperature processing. These materials include molybdenum, niobium, copper, tungsten, aluminum and alloys thereof for the anode and cathode. Carbon in the form of graphitic carbon, a diamond-like material, or carbon nanotubes can be used in the trigger electrode. Channels can be optionally formed in the substrate to mitigate against surface breakdown.

Roesler, Alexander W. (Tijeras, NM); Schare, Joshua M. (Albuquerque, NM); Bunch, Kyle (Albuquerque, NM)

2010-05-11T23:59:59.000Z

111

Energy Use in Distillation Operation: Nonlinear Economic Effects  

E-Print Network [OSTI]

important. For many distillation columns there is a tradeoff in operation between energy usage and product recovery and setting the proper usage target involves a calculation of the economic tradeoff between these two factors. However, distillation is a non-linear...

White, D. C.

2010-01-01T23:59:59.000Z

112

Evading death by vacuum  

E-Print Network [OSTI]

In the Standard Model, the Higgs potential allows only one minimum at tree-level. But the open possibility that there might be two scalar doublets enriches the vacuum structure, allowing for the risk that we might now be in a metastable state, which we dub the panic vacuum. Current experiments at the LHC are probing the Higgs particle predicted as a result of the spontaneous symmetry breaking. Remarkably, in the two Higgs model with a softly broken U(1) symmetry, the LHC experiments already preclude panic vacuum solutions.

A. Barroso; P. M. Ferreira; I. P. Ivanov; Rui Santos; João P. Silva

2013-03-15T23:59:59.000Z

113

Thermophoretic vacuum wand  

DOE Patents [OSTI]

A thermophoretic vacuum wand that is particularly suited for transporting articles in a cleanroom environment so that potential particle contaminants in the air do not become adhered to the surface of the article is described. The wand includes a housing having a platen with a front surface with suction port(s) through the platen; a vacuum source for applying a negative pressure to the suction port(s); and heating device for the object. Heating the article when it is held by the vacuum wand affords thermophoretic protection that effectively prevents particles in the air from depositing onto the article.

Klebanoff, Leonard Elliott (San Ramon, CA); Rader, Daniel John (Lafayette, CA)

2001-01-01T23:59:59.000Z

114

Thermophoretic vacuum wand  

DOE Patents [OSTI]

A thermophoretic vacuum wand that is particularly suited for transporting articles in a cleanroom environment so that potential particle contaminants in the air do not become adhered to the surface of the article is described. The wand includes a housing having a platen with a front surface with suction port(s) through the platen; a vacuum source for applying a negative pressure to the suction port(s); and heating device for the object. Heating the article when it is held by the vacuum wand affords thermophoretic protection that effectively prevents particles in the air from depositing onto the article.

Klebanoff, Leonard Elliott (San Ramon, CA); Rader, Daniel John (Lafayette, CA)

2000-01-01T23:59:59.000Z

115

Thermophoretic vacuum wand  

SciTech Connect (OSTI)

A thermophoretic vacuum wand that is particularly suited for transporting articles in a cleanroom environment so that potential particle contaminants in the air do not become adhered to the surface of the article is described. The wand includes a housing having a platen with a front surface with suction port(s) through the platen; a vacuum source for applying a negative pressure to the suction port(s); and heating device for the object. Heating the article when it is held by the vacuum wand affords thermophoretic protection that effectively prevents particles in the air from depositing onto the article.

Klebanoff, L.E.; Rader, D.J.

2000-06-06T23:59:59.000Z

116

Combined electron beam and vacuum ARC melting for barrier tube shell material  

SciTech Connect (OSTI)

This patent describes a process of the type wherein zirconium tetrachloride is reduced to produce a metallic zirconium sponge. The sponge is distilled to generally remove residual magnesium and magnesium chloride, and the distilled sponge is melted to produce an ingot, the improvement for making a non-crystal bar material for use in lining the interior of zirconium alloy fuel element cladding which comprises: a. forming the distilled sponge into a consumable electrode; b. melting the consumable electrode in a multiple swept beam electron furnace with a feed rate between 1 and 20 inches per hour to form an intermediate ingot; and c. vacuum arc melting the intermediate ingot to produce a homogeneous final ingot, having 50-500 ppm iron.

Worcester, S.A.; Woods, C.R.

1989-07-18T23:59:59.000Z

117

Heat Integrated Distillation through Use of Microchannel Technology  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

118

CHEM333: Lab Experiment 3: Distillation and Gas Chromatography  

E-Print Network [OSTI]

. Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wine much about the mathematics of Raoult's Law; you will see it again in physical chemistry. Pay particular

Taber, Douglass

119

Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings  

E-Print Network [OSTI]

The absorption cycle offers one of the most economic and widely applicable technologies for waste heat upgrading. It can use off-the-shelf hardware that is available now, at any required capacity rating. Fractional distillations, as a class...

Erickson, D. C.; Davidson, W. F.

1984-01-01T23:59:59.000Z

120

Membrane augmented distillation to separate solvents from water  

DOE Patents [OSTI]

Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

2012-09-11T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

An experimental and mathematical investigation of hydrocarbon steam distillation  

E-Print Network [OSTI]

of Committee) Dr. Pau B. Crawford (Member) r. William D. McCain Jr. r. A ber t T. Watson (Member) Dr. i l. iam D. on Gonten ead of Department) December 1984 ABSTRACT An Experimental and Mathematical Investigation of Hydrocarbon Steam Distillation... mechanism associated with steam flooding and in-situ combustion enhanced oil recovery projects. It also takes place in hydrocarbon recovery from deep volatile oil reservoirs. Nethods for predicting the recovery of hydrocarbons by steam distillation have...

Langhoff, John Allan

1984-01-01T23:59:59.000Z

122

Determination of plate efficiencies for conventional distillation columns  

E-Print Network [OSTI]

DETERMINATION OF PLATE EFFICIENCIES FOR CONVENTIONAL DISTILLATION COIUMNS A Thesis By Thomas Raymond Harris Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1962 Ma)or Sub)ect t Chemical Engineering DETERMINATION OF PLATE EFFICIENCIES FOR CONVENTIONAL DISTILLATION COLUMNS A Thesis Thomas Raymond Harris Approred as to style and content bye Chairman of ommittee Head...

Harris, Thomas Raymond

2012-06-07T23:59:59.000Z

123

Single-step distillation protocol with generalized beam splitters  

SciTech Connect (OSTI)

We develop a distillation protocol for multilevel qubits (qudits) using generalized beam splitters like in the proposal of Pan et al. for ordinary qubits. We find an acceleration with respect to the scheme of Bennet et al. when extended to qudits. It is also possible to distill entangled pairs of photons carrying orbital angular momenta states that conserve the total angular momenta as those produced in recent experiments.

Martin-Delgado, M. A.; Navascues, M. [Departamento de Fisica Teorica I, Universidad Complutense, 28040 Madrid, (Spain)

2003-07-01T23:59:59.000Z

124

Integrated Thermal and Hydraulic Analysis of Distillation Columns  

E-Print Network [OSTI]

significant additional insights to help screen the options for distillation column revamps. Column Targeting Aspen Plus Column Targeting tool offers capabilities for thermal and hydraulic analysis of distillation columns. During design or retrofit analysis...). Aspen Plus Column Targeting Tool generates the CGCCs based on the Practical Near-Minimum Thermodynamic Condition (PNMTC) approximation (Dhole and Linnhoff). The enthalpies used in plotting the CGCCs are calculated at a given stage of the column...

Samant, K.; Sinclair, I.; Keady, G.

125

Synthesis and design of optimal thermal membrane distillation networks  

E-Print Network [OSTI]

distillation as a technology that can be driven by thermal energy at low enthalpy, such as geothermal energy, by using a hybrid air gap membrane distillation- fluidized bed crystallization assembly for desalination. Tomaszewska (2000) has studied... of pre-pressurizing of the membrane pores and control of dissolved gas concentrations in the feed and recycled permeate in order to prevent pore penetration and wetting (Agashichev and Sivakov, 1993). Temperature polarization effects have been...

Nyapathi Seshu, Madhav

2006-10-30T23:59:59.000Z

126

Key Distillation and the Secret-Bit Fraction  

E-Print Network [OSTI]

We consider distillation of secret bits from partially secret noisy correlations P_ABE, shared between two honest parties and an eavesdropper. The most studied distillation scenario consists of joint operations on a large number of copies of the distribution (P_ABE)^N, assisted with public communication. Here we consider distillation with only one copy of the distribution, and instead of rates, the 'quality' of the distilled secret bits is optimized, where the 'quality' is quantified by the secret-bit fraction of the result. The secret-bit fraction of a binary distribution is the proportion which constitutes a secret bit between Alice and Bob. With local operations and public communication the maximal extractable secret-bit fraction from a distribution P_ABE is found, and is denoted by Lambda[P_ABE]. This quantity is shown to be nonincreasing under local operations and public communication, and nondecreasing under eavesdropper's local operations: it is a secrecy monotone. It is shown that if Lambda[P_ABE]>1/2 then P_ABE is distillable, thus providing a sufficient condition for distillability. A simple expression for Lambda[P_ABE] is found when the eavesdropper is decoupled, and when the honest parties' information is binary and the local operations are reversible. Intriguingly, for general distributions the (optimal) operation requires local degradation of the data.

Nick S. Jones; Lluis Masanes

2008-05-12T23:59:59.000Z

127

Process for removing naphthenic acids from petroleum distillates  

SciTech Connect (OSTI)

A liquid extraction process is described for removing naphthenic acids from naphthenic acid containing petroleum distillates boiling within the range of about 180/sup 0/-600/sup 0/C. and having an acid number of at least about 0.2 which process comprises the steps of: (a) intimately contacting the petroleum distillates with a solvent consisting essentially of methanol, water, and about from 2-20 wt. % ammonia and having a methanol: water ratio in the range of about from 0.2 to 3 parts by weight of methanol per part by weight of water and using an ammonia to petroleum distillate ratio of about 0.1-1 part by weight of ammonia per 100 parts by weight of the petroleum distillate. This selectively extracts the naphthenic acids into the solvent and yielding an immiscible two-phase liquid mixture, one of which is naphthenic acid-rich solvent phase and the other of which is a substantially napthenic acid-free petroleum distillate phase; and (b) separating and respectively recovering the naphtenic acid-rich solvent phase and petroleum distillate phase.

Danzik, M.

1987-01-06T23:59:59.000Z

128

Vacuum arc deposition devices  

SciTech Connect (OSTI)

The vacuum arc is a high-current, low-voltage electrical discharge which produces a plasma consisting of vaporized and ionized electrode material. In the most common cathodic arc deposition systems, the arc concentrates at minute cathode spots on the cathode surface and the plasma is emitted as a hypersonic jet, with some degree of contamination by molten droplets [known as macroparticles (MPs)] of the cathode material. In vacuum arc deposition systems, the location and motion of the cathode spots are confined to desired surfaces by an applied magnetic field and shields around undesired surfaces. Substrates are mounted on a holder so that they intercept some portion of the plasma jet. The substrate often provides for negative bias to control the energy of depositing ions and heating or cooling to control the substrate temperature. In some systems, a magnetic field is used to guide the plasma around an obstacle which blocks the MPs. These elements are integrated with a deposition chamber, cooling, vacuum gauges and pumps, and power supplies to produce a vacuum arc deposition system.

Boxman, R.L.; Zhitomirsky, V.N. [Electrical Discharge and Plasma Laboratory, Faculty of Engineering, Tel Aviv University, P.O. Box 39040, Tel Aviv 69978 (Israel)

2006-02-15T23:59:59.000Z

129

Safety of Minkowski Vacuum  

E-Print Network [OSTI]

We give a simple argument suggesting that in a consistent quantum field theory tunneling from Minkowski to a lower energy vacuum must be impossible. Theories that allow for such a tunneling also allow for localized states of negative mass, and therefore, should be inconsistent.

Gia Dvali

2011-07-05T23:59:59.000Z

130

Langmuir vacuum and superconductivity  

SciTech Connect (OSTI)

It is shown that, in the 'jelly' model of cold electron-ion plasma, the interaction between electrons and the quantum electromagnetic vacuum of Langmuir waves involves plasma superconductivity with an energy gap proportional to the energy of the Langmuir quantum.

Veklenko, B. A. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

2012-06-15T23:59:59.000Z

131

The vacuum conservation theorem  

E-Print Network [OSTI]

A version of the vacuum conservation theorem is proved which does not assume the existence of a time function nor demands stronger properties than the dominant energy condition. However, it is shown that a stronger stable version plays a role in the study of compact Cauchy horizons.

E. Minguzzi

2015-02-28T23:59:59.000Z

132

ISAC target vacuum system  

SciTech Connect (OSTI)

The Isotope Separator and Accelerator (ISAC) facility at TRIUMF has been in full operation since 1999. The ISAC east and west targets use proton beam from the cyclotron to produce various radioactive isotopes, which are then ionized and extracted. The ions are then passed through the mass separator and selected ions are transferred to the low energy experiments or injected into a radio frequency quadrupole accelerator. The accompanying radioactive contamination from the production of radioactive ions requires a complex vacuum system. The main target vacuum space consists of two semiseparate (primary and secondary) volumes pumped by turbo-molecular pumps. The primary volume uses four pumps while the secondary volume uses two pumps. Two hermetic rotary vane pumps are used as backing pumps. The nominal vacuum in both volumes is about 1.33x10{sup -4} Pa (1.0x10{sup -6} Torr). The pressure is monitored by two cold cathode and two hot filament ion gauges. The cold cathode gauges are used to interlock the system, which is critical during the bake out of the target and beam production. The exhaust gas from the vacuum pumps can be radioactive. Three gas storage tanks (decay tanks) are used for temporary storage of the radioactive exhaust and its controlled release to the atmosphere. Gas-species insensitive membrane gauges are used for monitoring the pressure in the storage tanks. This article describes the details of the ISAC target vacuum system as well as some procedures related to the handling of the exhaust gas with traces of radioactive contamination produced by the targets.

Yosifov, Dimo; Sekachev, Igor [TRIUMF, Canada's National Laboratory for Particle and Nuclear Physics, Vancouver, British Columbia V6T 2A3 (Canada)

2006-07-15T23:59:59.000Z

133

A radiation hard vacuum switch  

DOE Patents [OSTI]

A vacuum switch with an isolated trigger probe which is not directly connected to the switching electrodes. The vacuum switch within the plasmatron is triggered by plasma expansion initiated by the trigger probe which travels through an opening to reach the vacuum switch elements. The plasma arc created is directed by the opening to the space between the anode and cathode of the vacuum switch to cause conduction. 3 figs.

Boettcher, G.E.

1988-07-19T23:59:59.000Z

134

Surge-damping vacuum valve  

DOE Patents [OSTI]

A valve having a mechanism for damping out flow surges in a vacuum system which utilizes a slotted spring-loaded disk positioned adjacent the valve's vacuum port. Under flow surge conditions, the differential pressure forces the disk into sealing engagement with the vacuum port, thereby restricting the flow path to the slots in the disk damping out the flow surge.

Bullock, Jack C. (Pleasanton, CA); Kelly, Benjamin E. (Tracy, CA)

1980-01-01T23:59:59.000Z

135

Compact vacuum insulation  

DOE Patents [OSTI]

An ultra-thin compact vacuum insulation panel is comprised of two hard, but bendable metal wall sheets closely spaced apart from each other and welded around the edges to enclose a vacuum chamber. Glass or ceramic spacers hold the wall sheets apart. The spacers can be discrete spherical beads or monolithic sheets of glass or ceramic webs with nodules protruding therefrom to form essentially "point" or "line" contacts with the metal wall sheets. In the case of monolithic spacers that form "line" contacts, two such spacers with the line contacts running perpendicular to each other form effectively "point" contacts at the intersections. Corrugations accommodate bending and expansion, tubular insulated pipes and conduits, and preferred applications are also included.

Benson, David K. (Golden, CO); Potter, Thomas F. (Denver, CO)

1993-01-01T23:59:59.000Z

136

Compact vacuum insulation embodiments  

DOE Patents [OSTI]

An ultra-thin compact vacuum insulation panel is comprised of two hard, but bendable metal wall sheets closely spaced apart from each other and welded around the edges to enclose a vacuum chamber. Glass or ceramic spacers hold the wall sheets apart. The spacers can be discrete spherical beads or monolithic sheets of glass or ceramic webs with nodules protruding therefrom to form essentially "point" or "line" contacts with the metal wall sheets. In the case of monolithic spacers that form "line" contacts, two such spacers with the line contacts running perpendicular to each other form effectively "point" contacts at the intersections. Corrugations accommodate bending and expansion, tubular insulated pipes and conduits, and preferred applications are also included.

Benson, David K. (Golden, CO); Potter, Thomas F. (Denver, CO)

1992-01-01T23:59:59.000Z

137

Compact vacuum insulation embodiments  

DOE Patents [OSTI]

An ultra-thin compact vacuum insulation panel is comprised of two hard, but bendable metal wall sheets closely spaced apart from each other and welded around the edges to enclose a vacuum chamber. Glass or ceramic spacers hold the wall sheets apart. The spacers can be discrete spherical beads or monolithic sheets of glass or ceramic webs with nodules protruding therefrom to form essentially point' or line' contacts with the metal wall sheets. In the case of monolithic spacers that form line' contacts, two such spacers with the line contacts running perpendicular to each other form effectively point' contacts at the intersections. Corrugations accommodate bending and expansion, tubular insulated pipes and conduits, and preferred applications are also included. 26 figs.

Benson, D.K.; Potter, T.F.

1992-04-28T23:59:59.000Z

138

Vacuum tool manipulator  

DOE Patents [OSTI]

Apparatus for manipulating a vacuum hose in a reactor vessel comprises a housing with two opposing openings, an arm carried by the housing and deployable from a stowed position essentially completely within the housing to an extended position where the arm extends through the two openings in a generally horizontal position. The arm preferably has a two-fingered gripping device for gripping the vacuum hose but may carry a different end effector such as a grinding wheel. The fingers are opened and closed by one air cylinder. A second air cylinder extends the device. A third air cylinder within the housing pivotally pulls the opposing end of the arm into the housing via a pivoting member pivotally connected between the third air cylinder shaft and the arm. 6 figures.

Zollinger, W.T.

1993-11-23T23:59:59.000Z

139

Avoiding Death by Vacuum  

E-Print Network [OSTI]

The two-Higgs doublet model (2HDM) can have two electroweak breaking, CP-conserving, minima. The possibility arises that the minimum which corresponds to the known elementary particle spectrum is metastable, a possibility we call the "panic vacuum". We present analytical bounds on the parameters of the softly broken Peccei-Quinn 2HDM which are necessary and sufficient conditions to avoid this possibility. We also show that, for this particular model, the current LHC data already tell us that we are necessarily in the global minimum of the theory, regardless of any cosmological considerations about the lifetime of the false vacua.

A. Barroso; P. M. Ferreira; I. Ivanov; R. Santos; Joao P. Silva

2013-05-08T23:59:59.000Z

140

Polymers in a Vacuum  

SciTech Connect (OSTI)

In a variety of situations, isolated polymer molecules are found in a vacuum, and here we examine their properties. Angular momentum conservation is shown to significantly alter the average size of a chain and its conservation is only broken slowly by thermal radiation. For an ideal chain, the time autocorrelation for monomer position oscillates with a period proportional to chain length. The oscillations and damping are analyzed in detail. Short-range repulsive interactions suppress oscillations and speed up relaxation, but stretched chains still show damped oscillatory correlations.

Deutsch, J. M. [Department of Physics, University of California, Santa Cruz, California 95064 (United States)

2007-12-07T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Refining and upgrading of synfuels from coal and oil shales by advanced catalytic processes. Sixth interim report Task 9: hydrotreating 400/sup 0/F+ SRC-II oil for biological studies  

SciTech Connect (OSTI)

400/sup 0/F+ SRC-II oil derived from Pittsburgh Seam coal was hydrotreated to provide DOE samples for subsequent biological testing at the Oak Ridge National Laboratory. Samples containing about 500 ppM nitrogen, 2000 ppM nitrogen, and 5000 ppM nitrogen were prepared. These samples do not represent finished products, but conditions were selected to provide a wide range of processing severities. The feedstock was somewhat higher boiling and more difficult to hydrotreat than another 400/sup 0/F+ SRC-II oil studied previously.

Sullivan, R.F.

1982-04-01T23:59:59.000Z

142

Hydrothermal Liquefaction Oil and Hydrotreated Product from Pine Feedstock Characterized by Heteronuclear Two-Dimensional NMR Spectroscopy and FT-ICR Mass Spectrometry  

SciTech Connect (OSTI)

Hydrothermal liquefaction (HTL) crude oil and hydrotreated product from pine tree farm waste (forest product residual, FPR) have been analyzed by direct infusion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) in both positive- and negative-ionization modes and high-resolution twodimensional heteronuclear 1H-13C NMR spectroscopy. FT-ICR MS resolves thousands of compounds in complex oils and provides unparalleled compositional details for individual molecules for identification of compound class (heteroatom content), type (number of rings plus double bonds to carbon or double bond equivalents (DBE) and carbon number (degree of alkylation). Heteronuclear 1H-13C NMR spectroscopy provides one-bond and multiple-bond correlations between pairs of 1H and 13C chemical shifts that are characteristic of different organic functional groups. Taken together this information provides a picture of the chemical composition of these oils. Pyrolysis crude oil product from pine wood was characterized for comparison. Generally, pyrolysis oil is comprised of a more diverse distribution of heteroatom classes with higher oxygen number relative to HTL oil as shown by both positive- and negative-ion ESI FT-ICR MS. A total of 300 N1, 594 O1 and 267 O2 compounds were observed as products of hydrotreatment. The relative abundance of N1O1, N1O2, N1O3, N2, N2O1, N2O2 and O3 compounds are reduced to different degrees after hydrotreatment and other higher heteroatom containing species (O4-O10, N1O4, N1O5 and N2O3) are completely removed by hydrotreatment.

Sudasinghe, Nilusha; Cort, John R.; Hallen, Richard T.; Olarte, Mariefel V.; Schmidt, Andrew J.; Schaub, Tanner

2014-12-14T23:59:59.000Z

143

Table A3. Refiner/Reseller Prices of Distillate and Residual...  

Gasoline and Diesel Fuel Update (EIA)

A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

144

Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump  

E-Print Network [OSTI]

(Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

Skogestad, Sigurd

145

ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried  

E-Print Network [OSTI]

. Physical properties . Protein . Twin-screw extruder Introduction As a consequence of changes in energyORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced

146

Rigorous Synthesis and Simulation of Complex Distillation Networks  

E-Print Network [OSTI]

energy-efficient distillation net- works. Complex column networks have substantial potential for energy- thesizing such complex energy-efficient networks. A robust feasibility criterion drives the selection foundations of se st in exploring energy-efficient distillatin exploring energy-efficient distillat ave

Linninger, Andreas A.

147

Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements  

E-Print Network [OSTI]

Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

Skogestad, Sigurd

148

Solar Ethanol Distillation Oara Neumann,1,3  

E-Print Network [OSTI]

requiring no energy input by conventional sources, with the potential to replace, or significantly reduce-harvesting nanoparticles that capture solar energy for direct liquid-vapor conversion, eliminating the energy O-9 Solar Ethanol Distillation Oara Neumann,1,3 Albert D. Neumann,2 Julius Müller,1

149

Thermal insulations using vacuum panels  

DOE Patents [OSTI]

Thermal insulation vacuum panels are formed of an inner core of compressed low thermal conductivity powders enclosed by a ceramic/glass envelope evaluated to a low pressure.

Glicksman, Leon R. (Lynnfield, MA); Burke, Melissa S. (Pittsburgh, PA)

1991-07-16T23:59:59.000Z

150

III. Vacuum PumpsIII. Vacuum Pumps Gas transfer  

E-Print Network [OSTI]

III. Vacuum PumpsIII. Vacuum Pumps Mechanism Gas transfer Gas capture FunctionFunction Roughing (backing, mechanical pumps) Rotary vane Sorption Rotary lobe Scroll ScrewSorption, Rotary lobe, Scroll Phy250-1, 2011, NanoFab16 #12;IIIIII--A. Roughing: Rotary Vane PumpA. Roughing: Rotary Vane Pump (Gas

Liu, Kai

151

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

152

Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units  

E-Print Network [OSTI]

, Pennsylvania 15213, United States. Crude-oil assays, Distillation, Fractionation, Swing-cuts, Temperature cut with in the nonlinear optimization. 1. INTRODUCTION Distillation or fractionation models for planning and scheduling1 Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units Brenno

Grossmann, Ignacio E.

153

Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating  

E-Print Network [OSTI]

Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating Vidar the unexpected result that over-fractionating one of the product streams in a Petlyuk distillation column may is optimal in some cases. 1. Introduction The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator

Skogestad, Sigurd

154

Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel  

E-Print Network [OSTI]

into a number of product fractions in a single batch column whereas, in continuous distillation several columnsIntegrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum-boiling azeotropic mixtures, where the extractive agent

Skogestad, Sigurd

155

Model predictive control of a pilot-scale distillation column using a programmable automation controller  

E-Print Network [OSTI]

Model predictive control of a pilot-scale distillation column using a programmable automation). The controller is tested on a pilot-scale binary distillation column to track reference temperatures. A majorRIO) to control a pilot-scale binary distillation col- umn. Both the PI-controllers and the supervising online MPC

156

Control Dewar Secondary Vacuum Container  

SciTech Connect (OSTI)

This engineering note provides background information regarding the control dewar secondary vacuum container. The secondary vacuum container has it's origin with the CDP control dewar design. The name secondary vacuum container replaced the CDP term 'Watt can' which was named after Bob Watt (SLAC), a PAC/DOE review committee member who participated in a review of CDP and recommended a secondary vacuum enclosure. One of the most fragile parts of the control dewar design is the ceramic electrical feed throughs located in the secondary vacuum container. The secondary vacuum container is provided to guard against potential leaks in these ceramic insulating feed throughs. The secondary vacuum container has a pumping line separate from the main solenoid/control dewar insulating vacuum. This pumping line is connected to the inlet of the turbo pump for initial pumpdown. Under normal operation the container is isolated. Should a feedthrough develop a small leak, alternate pumping arrangements for the secondary vacuum container could be arranged. The pressure in the secondary vacuum container should be kept in a range that the breakdown voltage is kept at a maximum. The breakdown voltage is known to be a function of pressure and is described by a Paschen curve. I cannot find a copy of the curve at this time, but from what I remember, the breakdown voltage is a minimum somewhere around 10-3 torr. Ideally the pressure in the secondary vacuum can should be kept very low, around 10 E-6 or 10 E-7 torr for maximum breakdown voltage. If however a leak developed and this was not possible, then one could operate at a pressure higher than the minima point.

Rucinski, R.; /Fermilab

1993-10-04T23:59:59.000Z

157

Vacuum Technology for Superconducting Devices  

E-Print Network [OSTI]

The basic notions of vacuum technology for superconducting applications are presented, with an emphasis on mass and heat transport in free molecular regimes. The working principles and practical details of turbomolecular pumps and cryopumps are introduced. The specific case of the Large Hadron Collider’s cryogenic vacuum system is briefly reviewed.

Chiggiato, P

2014-01-01T23:59:59.000Z

158

Vacuum flash evaporated polymer composites  

DOE Patents [OSTI]

A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

Affinito, J.D.; Gross, M.E.

1997-10-28T23:59:59.000Z

159

Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation  

SciTech Connect (OSTI)

A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

Garg, D.

1986-08-19T23:59:59.000Z

160

Vacuum energy and cosmological evolution  

E-Print Network [OSTI]

An expanding universe is not expected to have a static vacuum energy density. The so-called cosmological constant $\\Lambda$ should be an approximation, certainly a good one for a fraction of a Hubble time, but it is most likely a temporary description of a true dynamical vacuum energy variable that is evolving from the inflationary epoch to the present day. We can compare the evolving vacuum energy with a Casimir device where the parallel plates slowly move apart ("expand"). The total vacuum energy density cannot be measured, only the effect associated to the presence of the plates, and then also their increasing separation with time. In the universe there is a nonvanishing spacetime curvature $R$ as compared to Minkowskian spacetime that is changing with the expansion. The vacuum energy density must change accordingly, and we naturally expect $\\delta\\Lambda\\sim R\\sim H^2$. A class of dynamical vacuum models that trace such rate of change can be constructed. They are compatible with the current cosmological data, and conveniently extended can account for the complete cosmic evolution from the inflationary epoch till the present days. These models are very close to the $\\Lambda$CDM model for the late universe, but very different from it at the early times. Traces of the inherent vacuum dynamics could be detectable in our recent past.

Joan Sola

2014-03-03T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Precooler Ring Vacuum System  

SciTech Connect (OSTI)

The precooler vacuum system, as proposed by FNAL, is based on a suitable modification of the existing Electron Cooling Ring System. Because of the magnetic cycle of the bending magnets, distributed ion pumping, as exists in the Electron Cooling Ring, is not applicable. Instead, the proposed pumping will be done with commercial appendage ion pumps mounted approximately every two meters around the circumference of the ring. The loss of effective pumping speed and non-uniformity of system pressure with appendage pumps may not be major considerations but the large number required does effect experimental and analytical equipment placement considerations. There is a distributed pumping technique available which: (1) is not affected by the magnetic cycle of the bending magnets; (2) will provide a minimum of four times the hydrogen pumping speed of the proposed appendage ion pumps; (3) will require no power during pumping after the strip is activated; (4) will provide the heat source for bakeout; (5) is easily replaceable; and (6) can be purchased, installed, and operated at a generous economic advantage over the presently proposed ion pumped system. The pumping technique referred to is non-evaporable gettering with ST101 Zr/Al pumping strip. A technical description of this pumping strip is given on Data Sheet 1 and 2 attached to this report.

Moenich, J.

1980-10-02T23:59:59.000Z

162

Compact vacuum insulation  

DOE Patents [OSTI]

Improved compact insulation panel is provided which is comprised of two adjacent metal sheets spaced close together with a plurality of spherical, or other discretely shaped, glass or ceramic beads optimally positioned between the sheets to provide support and maintain the spacing between the metal sheets when the gases there between are evacuated to form a vacuum. These spherical glass beads provide the maximum support while minimizing thermal conductance. In its preferred embodiment; these two metal sheets are textured with ribs or concave protrusions in conjunction with the glass beads to maximize the structural integrity of the panels while increasing the spacing between beads, thereby reducing the number of beads and the number of thermal conduction paths. Glass or porcelain-enameled liners in combination with the glass spacers and metal sidewalls effectively decrease thermal conductivity, and various laminates, including wood, porcelain-enameled metal, and others effectively increase the strength and insulation capabilities of the panels. Also, a metal web is provided to hold the spacers in place, and strategic grooves are shown to accommodate expansion and contraction or shaping of the panels. 35 figs.

Benson, D.K.; Potter, T.F.

1992-10-27T23:59:59.000Z

163

Compact vacuum insulation  

DOE Patents [OSTI]

Improved compact insulation panel is provided which is comprised of two adjacent metal sheets spaced close together with a plurality of spherical, or other discretely shaped, glass or ceramic beads optimally positioned between the sheets to provide support and maintain the spacing between the metal sheets when the gases therebetween are evacuated to form a vacuum. These spherical glass beads provide the maximum support while minimizing thermal conductance. In its preferred embodiment; these two metal sheets are textured with ribs or concave protrusions in conjunction with the glass beads to maximize the structural integrity of the panels while increasing the spacing between beads, thereby reducing the number of beads and the number of thermal conduction paths. Glass or porcelain-enameled liners in combination with the glass spacers and metal sidewalls effectively decrease thermal conductivity, and variious laminates, including wood, porcelain-enameled metal, and others effectively increase the strength and insulation capabilities of the panels. Also, a metal web is provided to hold the spacers in place, and strategic grooves are shown to accommodate expansion and contraction or shaping of the panels.

Benson, David K. (Golden, CO); Potter, Thomas F. (Denver, CO)

1992-01-01T23:59:59.000Z

164

Reactive Distillation for Esterification of Bio-based Organic Acids  

SciTech Connect (OSTI)

The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

2008-09-23T23:59:59.000Z

165

Enhanced Separation Efficiency in Olefin/Paraffin Distillation  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

166

"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering  

E-Print Network [OSTI]

distillation · Underwood (1946, 1948a,b), Fractional distillation of multicomponent mixtures · Shiras (1950"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science

Skogestad, Sigurd

167

Non-Petroleum Based Fuel Effects on Advanced Combustion  

Broader source: Energy.gov (indexed) [DOE]

Ranch Consulting, and PNNL * Heavy gasoline and diesel cut of mildly hydrotreated oil shale - <50 ppm S and N - Distilled into 7 narrow cuts * HCCI experiments completed during...

168

Catalyst for hydrotreating carbonaceous liquids  

DOE Patents [OSTI]

A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

Berg, Lloyd (Bozeman, MT); McCandless, Frank P. (Bozeman, MT); Ramer, Ronald J. (Idaho Falls, ID)

1982-01-01T23:59:59.000Z

169

Probability distribution of the vacuum energy density  

SciTech Connect (OSTI)

As the vacuum state of a quantum field is not an eigenstate of the Hamiltonian density, the vacuum energy density can be represented as a random variable. We present an analytical calculation of the probability distribution of the vacuum energy density for real and complex massless scalar fields in Minkowski space. The obtained probability distributions are broad and the vacuum expectation value of the Hamiltonian density is not fully representative of the vacuum energy density.

Duplancic, Goran; Stefancic, Hrvoje [Theoretical Physics Division, Rudjer Boskovic Institute, P.O. Box 180, HR-10002 Zagreb (Croatia); Glavan, Drazen [Department of Physics, Faculty of Science, University of Zagreb, P.O. Box 331, HR-10002 Zagreb (Croatia)

2010-12-15T23:59:59.000Z

170

Heat Recovery in Distillation by Mechanical Vapor Recompression  

E-Print Network [OSTI]

matc~ can be made between low-grade waste energy sourc~s and process uses, thereby improving plant energ~ efficiency. I A relatively high rate of return on invest-JI ment is expected in most cases. The optimum op, erating conditions are dictated...," Chem. Eng. Prog., Vol. 76:7, pp. 44-49, July 1980. I 2. Anon, "Di,stillation Prime Target for Energ~ Conservation," Oil & Gas Journal, Vol. 76:~6, pp. 92-94, April 17, 1978. I 3. W. F. Kenne'y, "Reducing the Energy Demand o~ Separation Processes...

Becker, F. E.; Zakak, A. I.

171

Multiple steady states during reactive distillation of methyl tert-butyl ether  

SciTech Connect (OSTI)

This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

1993-11-01T23:59:59.000Z

172

E-Print Network 3.0 - advanced distillation curve Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

58 (2003) 26712680 www.elsevier.comlocateces Summary: distillation: Advanced simulation and experimental validation. Computers and Chemical Engineering, 22, S371-S......

173

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Gasoline and Diesel Fuel Update (EIA)

Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

174

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Gasoline and Diesel Fuel Update (EIA)

Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

175

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

U.S. Energy Information Administration (EIA) Indexed Site

Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

176

Table A3. Refiner/Reseller Prices of Distillate and Residual...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

177

E-Print Network 3.0 - atmospheric crude distillation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Problems Summary: and atmospheric distillations of crude-oil mixtures from charging tanks. The crude is then processed in order... of resources: crude marine vessels, storage...

178

Development of a Fuzzy Logic Controller for a Distillation Column using Rockwell Software .  

E-Print Network [OSTI]

??In this thesis, an alternative control method based on Fuzzy Inference System (FIS) is proposed to keep the product composition of a distillation column constant.… (more)

Nizami, Muhammad

2011-01-01T23:59:59.000Z

179

Method for vacuum fusion bonding  

DOE Patents [OSTI]

An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

2001-01-01T23:59:59.000Z

180

Quantum Vacuum Structure and Cosmology  

SciTech Connect (OSTI)

Contemporary physics faces three great riddles that lie at the intersection of quantum theory, particle physics and cosmology. They are: (1) The expansion of the universe is accelerating - an extra factor of two appears in the size; (2) Zero-point fluctuations do not gravitate - a matter of 120 orders of magnitude; and (3) The 'True' quantum vacuum state does not gravitate. The latter two are explicitly problems related to the interpretation and the physical role and relation of the quantum vacuum with and in general relativity. Their resolution may require a major advance in our formulation and understanding of a common unified approach to quantum physics and gravity. To achieve this goal we must develop an experimental basis and much of the discussion we present is devoted to this task. In the following, we examine the observations and the theory contributing to the current framework comprising these riddles. We consider an interpretation of the first riddle within the context of the universe's quantum vacuum state, and propose an experimental concept to probe the vacuum state of the universe.

Rafelski, Johann; Labun, Lance; Hadad, Yaron; /Arizona U. /Munich U.; Chen, Pisin; /Taiwan, Natl. Taiwan U. /KIPAC, Menlo Park /SLAC

2011-12-05T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Vacuum-insulated catalytic converter  

DOE Patents [OSTI]

A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

Benson, David K. (Golden, CO)

2001-01-01T23:59:59.000Z

182

Plates for vacuum thermal fusion  

DOE Patents [OSTI]

A process for effectively bonding arbitrary size or shape substrates. The process incorporates vacuum pull down techniques to ensure uniform surface contact during the bonding process. The essence of the process for bonding substrates, such as glass, plastic, or alloys, etc., which have a moderate melting point with a gradual softening point curve, involves the application of an active vacuum source to evacuate interstices between the substrates while at the same time providing a positive force to hold the parts to be bonded in contact. This enables increasing the temperature of the bonding process to ensure that the softening point has been reached and small void areas are filled and come in contact with the opposing substrate. The process is most effective where at least one of the two plates or substrates contain channels or grooves that can be used to apply vacuum between the plates or substrates during the thermal bonding cycle. Also, it is beneficial to provide a vacuum groove or channel near the perimeter of the plates or substrates to ensure bonding of the perimeter of the plates or substrates and reduce the unbonded regions inside the interior region of the plates or substrates.

Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2002-01-01T23:59:59.000Z

183

Vacuum barrier for excimer lasers  

DOE Patents [OSTI]

A barrier for separating the vacuum area of a diode from the pressurized gas area of an excimer laser. The barrier is a composite material comprising layers of a metal such as copper, along with layers of polyimide, and a matrix of graphite fiber yarns impregnated with epoxy. The barrier is stronger than conventional foil barriers, and allows greater electron throughput. 3 figs.

Shurter, R.P.

1992-09-15T23:59:59.000Z

184

HIGH PRODUCTIVITY VACUUM BLASTING SYSTEM  

SciTech Connect (OSTI)

The purpose of the project is to increase the productivity and economics of existing vacuum blasting technology. This technology is used to remove radioactive contamination, PCB's and lead-base paint and provides worker and environmental protection by continuously recycling the blast media and the full containment of the dust generated in the process.

Dr. M.A. Ebadian

2000-01-13T23:59:59.000Z

185

Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column  

E-Print Network [OSTI]

Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column how the minimum energy consumption is related to the feed-component distribution for all possible operating points in a two-product distillation column with a multicomponent feed. The classical Underwood

Skogestad, Sigurd

186

Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products and Generalized Petlyuk Arrangements  

E-Print Network [OSTI]

Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products-component feed into M products has been derived. Interestingly, the minimum-energy solution in a complex solution of minimum energy for distillation of a multicomponent feed into multiple products has not been

Skogestad, Sigurd

187

Study of the Distillability of Werner States Using Entanglement Witnesses and Robust Semidefinite Programs  

E-Print Network [OSTI]

We use Robust Semidefinite Programs and Entanglement Witnesses to study the distillability of Werner states. We perform exact numerical calculations which show 2-undistillability in a region of the state space which was previously conjectured to be undistillable. We also introduce bases which yield interesting expressions for the {\\em distillability witnesses} and for a tensor product of Werner states with arbitrary number of copies.

Reinaldo O. Vianna; Andrew C. Doherty

2006-08-11T23:59:59.000Z

188

Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation  

E-Print Network [OSTI]

Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation · The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator (C1) and a main column (C21 and C22) N-7465 Trondheim, Norway Abstract This work shows the unexpected result that over-fractionating one

Skogestad, Sigurd

189

Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)  

E-Print Network [OSTI]

coupling 1. Introduction Separation by distillation is responsible for a large fraction of immense amountDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved indicated that a 15 component aromatic's mixture can be separated very efficiently into four fractions

Skogestad, Sigurd

190

Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**  

E-Print Network [OSTI]

that handle more than 90% of separations and purifications. The capital investment for these distillation.87 million TJ) per year, or to a power consumption of 91 GW, or 54 million tons of crude oil. Distillation conditions to minimize the total investment and operating cost. Continuous decisions are related

Grossmann, Ignacio E.

191

Manufacture of naphthenic type lubricating oils  

SciTech Connect (OSTI)

A process for making naphthenic type lubricating oils from a low viscosity waxy crude which comprises distilling said low viscosity waxy crude to 500 to 650/sup 0/F. At atmospheric pressure to separate distillable fractions therefrom, subjecting the residue to a vacuum distillation at about 25 to about 125 mm Hg absolute pressure to obtain one or more gas oil fractions, optionally hydrotreating said gas oil fractions in the presence of a Ni/Mo catalyst at 550 to 650/sup 0/F, 0.25 to 1.0 lhsv, and 700-1500 psig, and catalytically dewaxing said distillates in the presence of a H+ form mordenite catalyst containing a group VI or group VIII metal at 550 to 750/sup 0/F, 500 to 1500 psig and 0.25 to 5.0 lhsv, to obtain said naphthenic type oils having pour points of from about -60 to +20/sup 0/F.

Reynolds, R.W.

1981-02-24T23:59:59.000Z

192

Cosmological and Astrophysical Probes of Vacuum Energy  

E-Print Network [OSTI]

Vacuum energy changes during cosmological phase transitions and becomes relatively important at epochs just before phase transitions. For a viable cosmology the vacuum energy just after a phase transition must be set by the critical temperature of the next phase transition, which exposes the cosmological constant problem from a different angle. Here we propose to experimentally test the properties of vacuum energy under circumstances different from our current vacuum. One promising avenue is to consider the effect of high density phases of QCD in neutron stars. Such phases have different vacuum expectation values and a different vacuum energy from the normal phase, which can contribute an order one fraction to the mass of neutron stars. Precise observations of the mass of neutron stars can potentially yield information about the gravitational properties of vacuum energy, which can significantly affect their mass-radius relation. A more direct test of cosmic evolution of vacuum energy could be inferred from a ...

Bellazzini, Brando; Hubisz, Jay; Serra, Javi; Terning, John

2015-01-01T23:59:59.000Z

193

Inflation in a Symmetric Vacuum  

E-Print Network [OSTI]

If in a finite universe, the tree-level vacuum is a symmetric superposition of coherent states, in each of which the inflaton field assumes a different, energy-minimizing mean value (vev), then the resulting energy is positive and decreases exponentially as the volume of the universe increases. This effect can drive inflation when that volume is small and explain part of dark energy when it is big, but the effect is exceedingly tiny except at very early times.

Kevin Cahill

2007-05-23T23:59:59.000Z

194

Material Safety Data Sheet Revision Number: 001.2 Issue date: 02/03/2012  

E-Print Network [OSTI]

% Distillates (petroleum), hydrotreated heavy naphthenic 64742-52-5 10 - 30 Mineral oil light naphthenic not powder, dust or fume 7429-90-5 5 - 10 4. FIRST AID MEASURES Inhalation: Move to fresh air. If symptoms OTHER Distillates (petroleum), hydrotreated heavy naphthenic 5 mg/m3 TWA mist 10 mg/m3 STEL mist 5 mg/m3

Rollins, Andrew M.

195

Fractionation studies on the unidentified growth factor(s) in distillers dried solubles  

E-Print Network [OSTI]

. This was called "methyl aloohol soluble fraction of distillers dried solublesi The residue wss air drie4 and labeled "aetna 1 alcohol insoluble fraotion of distillers drie4 solubles". $. r fo m at nt ist e i o ubl s Five hundred gm of distillexs dried... fraction ox Ms- tillers Cried solubles (pH 1)"L "water soluole fr~ction of distillers dried solubles (PH '/)"L ~ "water soluble fxaction of dis~illers dried solubles (pH 11)". ur h r Pra tionatio f th Sate 8 lub e }raut of 9 still rs ed Soluo es a...

Dannenburg, Warren Nathaniel

1955-01-01T23:59:59.000Z

196

Distillation sequence for the purification and recovery of hydrocarbons  

DOE Patents [OSTI]

This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

2007-12-25T23:59:59.000Z

197

Simple rules help select best hydrocarbon distillation scheme  

SciTech Connect (OSTI)

Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del (Inst. Mexicano del Petroleo, Mexico City (Mexico))

1993-12-06T23:59:59.000Z

198

MSW Effects in Vacuum Oscillations  

E-Print Network [OSTI]

We point out that for solar neutrino oscillations with the mass-squared difference of Delta m^2 ~ 10^-10 - 10^-9 eV^2, traditionally known as ``vacuum oscillation'' range, the solar matter effects are non-negligible, particularly for the low energy pp neutrinos. One consequence of this is that the values of the mixing angle theta and pi/2-theta are not equivalent, leading to the need to consider the entire physical range of the mixing angle 0<=theta<=pi/2 when determining the allowed values of the neutrino oscillation parameters.

Alexander Friedland

2000-05-18T23:59:59.000Z

199

Vacuum friction in rotating particles  

E-Print Network [OSTI]

We study the frictional torque acting on particles rotating in empty space. At zero temperature, vacuum friction transforms mechanical energy into light emission and produces particle heating. However, particle cooling relative to the environment occurs at finite temperatures and low rotation velocities. Radiation emission is boosted and its spectrum significantly departed from a hot-body emission profile as the velocity increases. Stopping times ranging from hours to billions of years are predicted for materials, particle sizes, and temperatures accessible to experiment. Implications for the behavior of cosmic dust are discussed.

A. Manjavacas; F. J. García de Abajo

2010-09-21T23:59:59.000Z

200

Shielding vacuum fluctuations with graphene  

E-Print Network [OSTI]

The Casimir-Polder interaction of ground-state and excited atoms with graphene is investigated with the aim to establish whether graphene systems can be used as a shield for vacuum fluctuations of an underlying substrate. We calculate the zero-temperature Casimir-Polder potential from the reflection coefficients of graphene within the framework of the Dirac model. For both doped and undoped graphene we show limits at which graphene could be used effectively as a shield. Additional results are given for AB-stacked bilayer graphene.

Sofia Ribeiro; Stefan Scheel

2014-03-14T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Water distillation using waste engine heat from an internal combustion engine  

E-Print Network [OSTI]

To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

Mears, Kevin S

2006-01-01T23:59:59.000Z

202

Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle  

E-Print Network [OSTI]

Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle Ethanol, but sorghum grain is commonly either blended with corn before use or used as the sole grain for ethanol

203

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

204

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Gasoline and Diesel Fuel Update (EIA)

839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

205

Solvent refined coal (SRC) process. Flashing of SRC-II slurry in the vacuum column on Process Development Unit P-99. Interim report, February-June 1980  

SciTech Connect (OSTI)

This report presents the results of 73 tests on the vacuum flash system of Process Development Unit P-99 performed during processing of three different coals; the second batch, fourth shipment (low ash batch) of Powhatan No. 5 Mine (LR-27383), Powhatan No. 6 Mine (LR-27596) and Ireland Mine (LR-27987). The objective of this work was to obtain experimental data for use in confirming and improving the design of the vacuum distillation column for the 6000 ton/day SRC-II Demonstration Plant. The 900/sup 0/F distillate content of the bottoms and the percent of feed flashed overhead were correlated with flash zone operating conditions for each coal, and the observed differences in performance were attributed to differences in the feed compositions. Retrogressive reactions appeared to be occurring in the 900/sup 0/F+ pyridine soluble material leading to an increase in the quantity of pyridine insoluble organic matter. Stream physical properties determined include specific gravity, viscosity and melting point. Elemental, distillation and solvent analyses were used to calculate component material balances. The Technology and Materials Department has used these results in a separate study comparing experimental K-values and vapor/liquid split with CHAMP computer program design predictions.

Gray, J. A.; Mathias, S. T.

1980-10-01T23:59:59.000Z

206

The Scaleup of Structured Packing from Distillation Pilot Plant Testing to Commercial Application  

E-Print Network [OSTI]

fractionator was performed, it was necessary to inventory the column with feed and, under total reflux conditions, draw off distillate or bottoms product until the proper composition profile was achieved. To investigate various design options, both... stream by a factor of five. In summary, from the customer's point of view, the application of structured packing to the main fractionator in the SFP fractionation train is a cOOluercial success. NEW DISTILLATION DEVELOPMENT PILOT PLANT Since...

Berven, O. J.; Ulowetz, M. A.

207

Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation  

E-Print Network [OSTI]

EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

Jaiswal, Namit

2007-09-17T23:59:59.000Z

208

The thermodynamics of a gravitating vacuum  

E-Print Network [OSTI]

In the present days of modern cosmology it is assumed that the main ingredient to cosmic energy presently is vacuum energy with an energy density $\\epsilon_\\mathrm{vac}$ that is constant over the cosmic evolution. In this paper here we show, however, that this assumption of constant vacuum energy density is unphysical, since it conflicts with the requirements of cosmic thermodynamics. We start from the total vacuum energy including the negatively valued gravitational binding energy and show that cosmic thermodynamics then requires that the cosmic vacuum energy density can only vary with cosmic scale $R=R(t)$ according to $\\epsilon _\\mathrm{vac}\\sim R^{-\

M. Heyl; H. J. Fahr; M. Siewert

2014-12-09T23:59:59.000Z

209

Cold vacuum drying facility design requirements  

SciTech Connect (OSTI)

This document provides the detailed design requirements for the Spent Nuclear Fuel Project Cold Vacuum Drying Facility. Process, safety, and quality assurance requirements and interfaces are specified.

IRWIN, J.J.

1999-07-01T23:59:59.000Z

210

Gravitation and vacuum entanglement entropy  

E-Print Network [OSTI]

The vacuum of quantum fields contains correlated fluctuations. When restricted to one side of a surface these have a huge entropy of entanglement that scales with the surface area. If UV physics renders this entropy finite, then a thermodynamic argument implies the existence of gravity. That is, the causal structure of spacetime must be dynamical and governed by the Einstein equation with Newton's constant inversely proportional to the entropy density. Conversely, the existence of gravity makes the entanglement entropy finite. This thermodynamic reasoning is powerful despite the lack of a detailed description of the dynamics at the cutoff scale, but it has its limitations. In particular, we should not expect to understand corrections to Einstein gravity in this way.

Ted Jacobson

2012-04-28T23:59:59.000Z

211

Laser sealed vacuum insulating window  

DOE Patents [OSTI]

A laser sealed evacuated window panel is comprised of two glass panes held spaced apart in relation to each other by a plurality of spherical glass beads and glass welded around the edges to provide an evacuated space between the glass panes that is completely glass sealed from the exterior. The glass welded edge seal is obtained by welding the edges of the glass panes together with a laser beam while the glass panes and bead spacers are positioned in a vacuum furnace and heated to the annealing point of the glass to avoid stress fracture in the area of the glass weld. The laser welding in the furnace can be directed around the perimeter of the galss panel by a combination of rotating the glass panel and linearly translating or aiming the laser with a relay mirror.

Benson, D.K.; Tracy, C.E.

1985-08-19T23:59:59.000Z

212

Laser sealed vacuum insulation window  

DOE Patents [OSTI]

A laser sealed evacuated window panel is comprised of two glass panes held spaced apart in relation to each other by a plurality of spherical glass beads and glass welded around the edges to provide an evacuated space between the glass panes that is completely glass sealed from the exterior. The glass welded edge seal is obtained by welding the edges of the glass panes together with a laser beam while the glass panes and bead spacers are positioned in a vacuum furnace and heated to the annealing point of the glass to avoid stress fracture in the area of the glass weld. The laser welding in the furnace can be directed around the perimeter of the glass panel by a combination of rotating the glass panel and linearly translating or aiming the laser with a relay mirror.

Benson, David K. (Golden, CO); Tracy, C. Edwin (Golden, CO)

1987-01-01T23:59:59.000Z

213

Quality Management of CERN Vacuum Controls  

E-Print Network [OSTI]

The vacuum controls Section (TE-VSC-ICM) is in charge of the monitoring, maintenance and consolidation of the control systems of all accelerators and detectors in CERN; this represents 6 000 instruments distributed along 128 km of vacuum chambers, often of heterogeneous architectures and of diverse

Antoniotti, F; Fortescue-Beck, E; Gama, J; Gomes, P; Le Roux, P; Pereira, H F; Pigny, G

2014-01-01T23:59:59.000Z

214

On the Vacuum Propagation of Gravitational Waves  

E-Print Network [OSTI]

We show that, for any local, causal quantum field theory which couples covariantly to gravity, and which admits Minkowski spacetime vacuum(a) invariant under the inhomogeneous proper orthochronous Lorentz group, plane gravitational waves propagating in such Minkowski vacuum(a) do not dissipate energy or momentum via quantum field theoretic effects.

Xiao Liu

2007-06-05T23:59:59.000Z

215

Measuring Vacuum Polarization with Josephson Junctions  

SciTech Connect (OSTI)

We argue that the vacuum polarization by the virtual electron-positron pairs can be measured by studying a Josephson junction in a strong magnetic field. The vacuum polarization results in a weak dependence of the Josephson constant on the magnetic field strength which is within the reach of the existing experimental techniques.

Penin, Alexander A. [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2J1 (Canada) and Institute for Nuclear Research of Russian Academy of Sciences, 117312 Moscow (Russian Federation)

2010-03-05T23:59:59.000Z

216

The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients  

SciTech Connect (OSTI)

As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

1989-07-01T23:59:59.000Z

217

Source book for planning nuclear dual-purpose electric/distillation desalination plants  

SciTech Connect (OSTI)

A source book on nuclear dual-purpose electric/distillation desalination plants was prepared to assist government and other planners in preparing broad evaluations of proposed applications of dual-purpose plants. The document is divided into five major sections. Section 1 presents general discussions relating to the benefits of dual-purpose plants, and spectrum for water-to-power ratios. Section 2 presents information on commercial nuclear plants manufactured by US manufacturers. Section 3 gives information on distillation desalting processes and equipment. Section 4 presents a discussion on feedwater pretreatment and scale control. Section 5 deals with methods for coupling the distillation and electrical generating plants to operate in the dual mode.

Reed, S.A.

1981-02-01T23:59:59.000Z

218

Vacuum control subsystem for the Fermilab Tevatron  

SciTech Connect (OSTI)

The CAMAC 170 module and CIA crate provide a convenient, cost effective method of interfacing any system requiring a large number of simple devices to be multiplexed into the Accelerator Control System. The system is ideal for relatively slowly changing systems where ten bit analog to digital conversions are sufficiently accurate. Together with vacuum interface CIA cards and prom-based software resident in the 170, this system is used to provide intelligent local monitoring and control for the Tevatron vacuum subsystems. Although not implemented in the vacuum interface, digital to analog converters could be included on the plug in modules as well, providing a total digital and analog multiplexing scheme. 2 refs.

Zagel, J.R.; Chapman, L.J.

1981-06-01T23:59:59.000Z

219

Vacuum fluctuations for spherical gravitational impulsive waves  

E-Print Network [OSTI]

We propose a method for calculating vacuum fluctuations on the background of a spherical impulsive gravitational wave which results in a finite expression for the vacuum expectation value of the stress-energy tensor. The method is based on first including a cosmological constant as an auxiliary constant. We show that the result for the vacuum expectation value of the stress-energy tensor in second-order perturbation theory is finite if both the cosmological constant and the infrared parameter tend to zero at the same rate.

M. Hortaçsu

1998-04-30T23:59:59.000Z

220

Vacuum breaks of the doubler magnet system  

SciTech Connect (OSTI)

The energy doubler system contains two vacuum systems; the cold beam tube vacuum and the insulating vacuum system. These two systems are independent of each other. Both have connections to the outside world through pumpouts. This report attempts to make an estimate of the effect of a massive failure (large rupture of a connection to the outside world) upon the magnets and the contained helium in the magnet system. It is assumed that the event takes place with magnets full of helium, at steady state cryogenic conditions, but without magnetic field. Quenching of the magnets is therefore not a part of this analysis.

Not Available

1980-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Independent Oversight Review, Hanford K Basin and Cold Vacuum...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

K Basin and Cold Vacuum Drying Facility - August 2012 Independent Oversight Review, Hanford K Basin and Cold Vacuum Drying Facility - August 2012 August 2012 Review of Hanford K...

222

The Products of the Destructive Distillation of Keratin in the Form of Leather  

E-Print Network [OSTI]

ure to the air. After this came a white crystal­ line solid, fourth a reddish fciquid, fifth a red­ dish crystalline compound and sixth the black oil spoken of abovd. A volume of the distillate, equaling about a liter was collected and the two... the material the temperature rose to 200° C. and then reduction started and the temperature fell rapidly. The tar or oil constitutes from 3 to 4 per cent of the weight of the leather used. The aqueous portion of the distillate was subjected to a fractional...

Rose, Reed Phillips

1913-01-01T23:59:59.000Z

223

Process for converting heavy oil deposited on coal to distillable oil in a low severity process  

DOE Patents [OSTI]

A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

1994-01-01T23:59:59.000Z

224

SHINE Vacuum Pump Test Verification  

SciTech Connect (OSTI)

Normetex pumps used world-wide for tritium service are no longer available. DOE and other researchers worldwide have spent significant funds characterizing this pump. Identification of alternate pumps is required for performance and compatibility with tritium gas. Many of the pumps that could be used to meet the functional performance requirements (e.g. pressure and flow conditions) of the Normetex pump have features that include the use of polymers or oils and greases that are not directly compatible with tritium service. This study assembles a test system to determine the flow characteristics for candidate alternate pumps. These tests are critical to the movement of tritium through the SHINE Tritium Purification System (TPS). The purpose of the pump testing is two-fold: (1) obtain baseline vacuum pump characteristics for an alternate (i.e. ''Normetex replacement'') pump intended for use in tritium service; and (2) verify that low pressure hydrogen gas can be transported over distances up to 300 feet by the candidate pumps. Flow rates and nominal system pressures have been identified for the SHINE Mo-99 production process Tritium Purification System (TPS). To minimize the line sizes for the transfer of low pressure tritium from the Neutron Driver Accelerator System (NDAS) to the primary processing systems in the TPS, a ''booster'' pump has been located near the accelerator in the design. A series of pump tests were performed at various configurations using hydrogen gas (no tritium) to ensure that this concept is practical and maintains adequate flow rates and required pressures. This report summarizes the results of the tests that have been performed using various pump configurations. The current design of the Tritium Purification System requires the ''booster'' pump to discharge to or to be backed by another vacuum pump. Since Normetex pumps are no longer manufactured, a commercially available Edwards scroll pump will be used to back the booster pump. In this case the ''booster pump'' is an Adixen Molecular Drag Pump (MDP 5011) and the backing pump is an Edwards (nXDS15iC) scroll pump. Various configurations of the two pumps and associated lengths of 3/4 inch tubing (0 feet to 300 feet) were used in combination with hydrogen and nitrogen flow rates ranging from 25-400 standard cubic centimeters per minute (sccm) to determine whether the proposed pump configuration meets the design criteria for SHINE. The results of this study indicate that even under the most severe conditions (300 feet of tubing and 400 sccm flow rate) the Adixen 5011 MDP can serve as a booster pump to transport gases from the accelerator (NDAS) to the TPS. The Target Gas Receiving System pump (Edwards nXDS15iC) located approximately 300 feet from the accelerator can effectively back the Adixen MDP. The molecular drag pump was able to maintain its full rotational speed even when the flow rate was 400 sccm hydrogen or nitrogen and 300 feet of tubing was installed between the drag pump and the Edwards scroll pump. In addition to maintaining adequate rotation, the pressure in the system was maintained below the target pressure of 30 torr for all flow rates, lengths of tubing, and process gases. This configuration is therefore adequate to meet the SHINE design requirements in terms of flow and pressure.

Morgan, Gregg A; Peters, Brent

2013-09-30T23:59:59.000Z

225

Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC  

DOE Patents [OSTI]

In this invention, a process is disclosed characterized by heating a slurry of coal in the presence of a process-derived recycle solvent and passing same to a dissolver zone, separating the resultant gases and liquid/solid products therefrom, vacuum distilling the liquid/solids products, separating the portions of the liquid/solids vacuum distillation effluent into a solid ash, unconverted coal particles and SRC material having a boiling point above 850.degree. F. and subjecting same to a critical solvent deashing step to provide an ash-free SRC product. The lighter liquid products from the vacuum distillation possess a boiling point below 850.degree. F. and are passed through a distillation tower, from which recycled solvent is recovered in addition to light distillate boiling below 400.degree. F. (overhead). The ash-free SRC product in accompanyment with at least a portion of the process derived solvent is passed in combination to a hydrotreating zone containing a hydrogenation catalyst and in the presence of hydrogen is hydroprocessed to produce a desulfurized and denitrogenized low-sulfur, low-ash boiler fuel and a process derived recycle solvent which is recycled to slurry the coal in the beginning of the process before heating.

Roberts, George W. (Emmaus, PA); Tao, John C. (Perkiomenville, PA)

1985-01-01T23:59:59.000Z

226

Mass spectrometer vacuum housing and pumping system  

DOE Patents [OSTI]

A vacuum housing and pumping system for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof.

Coutts, Gerald W. (Livermore, CA); Bushman, John F. (Oakley, CA); Alger, Terry W. (Tracy, CA)

1996-01-01T23:59:59.000Z

227

SLAC All Access: Vacuum Microwave Device Department  

ScienceCinema (OSTI)

The Vacuum Microwave Device Department (VMDD) builds the devices that make SLAC's particle accelerators go. These devices, called klystrons, generate intense waves of microwave energy that rocket subatomic particles up to nearly the speed of light.

Haase, Andy

2014-06-13T23:59:59.000Z

228

Source replenishment device for vacuum deposition  

DOE Patents [OSTI]

A material source replenishment device for use with a vacuum deposition apparatus is described. The source replenishment device comprises an intermittent motion producing gear arrangement disposed within the vacuum deposition chamber. An elongated rod having one end operably connected to the gearing arrangement is provided with a multiarmed head at the opposite end disposed adjacent the heating element of the vacuum deposition apparatus. An inverted U-shaped source material element is releasably attached to the outer end of each arm member whereby said multiarmed head is moved to locate a first of said material elements above said heating element, whereupon said multiarmed head is lowered to engage said material element with the heating element and further lowered to release said material element on the heating element. After vaporization of said material element, second and subsequent material elements may be provided to the heating element without the need for opening the vacuum deposition apparatus to the atmosphere.

Hill, R.A.

1986-05-15T23:59:59.000Z

229

Mass spectrometer vacuum housing and pumping system  

DOE Patents [OSTI]

A vacuum housing and pumping system is described for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof. 7 figs.

Coutts, G.W.; Bushman, J.F.; Alger, T.W.

1996-07-23T23:59:59.000Z

230

Electrospray emitters For diffusion vacuum pumps  

E-Print Network [OSTI]

Following similar principles as regular diffusion vacuum pumps, an electrospray emitter is set to produce a jet of charged particles that will drag air molecules out of a volume. To be a feasible concept, the emitted ...

Diaz Gómez Maqueo, Pablo (Pablo Ly)

2011-01-01T23:59:59.000Z

231

Cold vacuum drying facility design requirements  

SciTech Connect (OSTI)

This release of the Design Requirements Document is a complete restructuring and rewrite to the document previously prepared and released for project W-441 to record the design basis for the design of the Cold Vacuum Drying Facility.

Irwin, J.J.

1997-09-24T23:59:59.000Z

232

Efficient use of an intermediate reboiler or condenser in a binary distillation  

SciTech Connect (OSTI)

The impact of an intermediate reboiler or condenser on the distillation of ideal binary mixtures into pure product streams is studied using a simplified model. The advantage of heuristics derived from this study is that they can quickly tell a process engineer if an intermediate reboiler or condenser is going to be effective in improving the efficiency and, of the two options, which one would be more effective. The heuristics simply states that if the actual fraction of liquid in a given feed is less than that with the maximum thermodynamic efficiency for distillation with no intermediate reboiler or condenser, then an intermediate condenser not only substantially improves the thermodynamic efficiency but is also more effective than an intermediate reboiler. An analogous heuristics exists for the intermediate reboiler when the fraction of liquid in the feed is greater than the optimum. Quick identification of cases that can achieve a substantial improvement in efficiency provides an incentive to search for the proper utilities needed for the intermediate reboiler or condenser. When relatively pure feed streams (concentration of either component greater than 90%) are distilled, the extremely low efficiencies of distillation can be remarkably improved by using an intermediate reboiler or condenser.

Agrawal, R.; Herron, D.M. [Air Products and Chemicals, Inc., Allentown, PA (United States)] [Air Products and Chemicals, Inc., Allentown, PA (United States)

1998-06-01T23:59:59.000Z

233

Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation  

E-Print Network [OSTI]

prefer a process where the energy may be supplied at a low temperature and cooling may be supplied law). This leads us to the reversible Petlyuk arrangement. However the total required heat supply). A characteristic of the reversible distillation column is that some of the heat is supplied continuously along

Skogestad, Sigurd

234

Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni  

E-Print Network [OSTI]

A study on middle distillate hydrotreatment zeolite catalysts containing Pt/Pd and/or Ni was performed. The effect of the addition of the corresponding CoMo, CoMoPd, CoMoPtPd and CoMoNi in PdNiPt-zeolite, Pt-zeolite, Ni-zeolite, and Pd...

Marin-Rosas, Celia

2009-05-15T23:59:59.000Z

235

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates*  

E-Print Network [OSTI]

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates samples, such as petroleum and coal, or for man-made samples, such as coal liquids, a major desire- nique for studying coal-liquid samples. 1-4 We demon- strated that the Raman spectra of polycyclic

Asher, Sanford A.

236

Distillate fuel-oil processing for phosphoric acid fuel-cell power plants  

SciTech Connect (OSTI)

The current efforts to develop distillate oil-steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high-temperature steam reforming (HTSR); autothermal reforming (ATR); autothermal gasification (AG); and ultra desulfurization followed by steam reforming. Sulfur in the feed is a key problem in the process development. A majority of the developers consider sulfur as an unavoidable contaminant of distillate fuel and are aiming to cope with it by making the process sulfur-tolerant. In the HTSR development, the calcium aluminate catalyst developed by Toyo Engineering represents the state of the art. United Technology (UTC), Engelhard, and Jet Propulsion Laboratory (JPL) are also involved in the HTSR research. The ATR of distillate fuel is investigated by UTC and JPL. The autothermal gasification (AG) of distillate fuel is being investigated by Engelhard and Siemens AG. As in the ATR, the fuel is catalytically gasified utilizing the heat generated by in situ partial combustion of feed, however, the goal of the AG is to accomplish the initial breakdown of the feed into light gases and not to achieve complete conversion to CO and H/sub 2/. For the fuel-cell integration, a secondary reforming of the light gases from the AG step is required. Engelhard is currently testing a system in which the effluent from the AG section enters the steam-reforming section, all housed in a single vessel. (WHK)

Ushiba, K. K.

1980-02-01T23:59:59.000Z

237

Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements  

E-Print Network [OSTI]

1 Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements of this paper is to present a simple graphical method for obtaining the energy usage and to compare the energy of Chemical Engineering, 7491 Trondheim, Norway Abstract The minimum energy requirements of six different heat

Skogestad, Sigurd

238

Hybrid magic state distillation for universal fault-tolerant quantum computation  

E-Print Network [OSTI]

A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

2014-12-11T23:59:59.000Z

239

Black-Box Identification for PLC based MPC of a Binary Distillation Column  

E-Print Network [OSTI]

Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

240

HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT  

E-Print Network [OSTI]

321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E hydrogen gas (so- called protium) must be used. It is necessary to avoid transfers of - to impurities imposes strict and critical requirements on the hydrogen gas system supporting the detector. Desirable

Titov, Anatoly

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Mixed MSW and Vacuum Solutions of Solar Neutrino Problem  

E-Print Network [OSTI]

Assuming three flavour neutrino mixing takes place in vacuum, we investigate the possibility that the solar $\

Qiu-Yu Liu

1997-08-11T23:59:59.000Z

242

Quality Management of CERN Vacuum Controls  

E-Print Network [OSTI]

The vacuum controls Section (TE-VSC-ICM) is in charge of the monitoring, maintenance and consolidation of the control systems of all accelerators and detectors in CERN; this represents 6 000 instruments distributed along 128 km of vacuum chambers, often of heterogeneous architectures and of diverse technical generations. In order to improve the efficiency of the services provided by ICM, to vacuum experts and to accelerator operators, a Quality Management Plan is being put into place. The first step was the standardization of the naming convention across different accelerators. The traceability of problems, requests, repairs, and other actions, has also been put into place (VTL). This was combined with the effort to identify each individual device by a coded label, and register it in a central database (MTF). Occurring in parallel, was the gathering of old documents and the centralization of information concerning architectures, procedures, equipment and settings (EDMS). To describe the topology of control c...

Antoniotti, F; Fortescue-Beck, E; Gama, J; Gomes, P; Le Roux, P; Pereira, H; Pigny, G

2014-01-01T23:59:59.000Z

243

A Road Map to Extreme High Vacuum  

SciTech Connect (OSTI)

Ultimate pressure of a well-designed vacuum system very much depends on pretreatments, processing and the procedures [1,2]. Until now much attention has been paid in minimizing hydrogen outgassing from the chamber material. However, procedures and processing deserves further scrutiny than hitherto given so far. For reducing the gas load, high sensitivity helium leak detection techniques with sensitivities better than 1× 10-12 Torr l/sec need to be used. Effects that are induced by vacuum instrumentation need to be reduced in order to obtain accurate pressure measurements. This presentation will discuss: clean assembly procedures, metal sponges for cryosorption pumping of hydrogen to extreme high vacuum, low cost surface diffusion barriers for reducing the hydrogen gas load, cascade pumping, sensitive helium leak detection techniques and the use of modified extractor and residual gas analyzers. Further, alternative back up pumping systems based on active NEG’s [3] for turbo molecular pumps will be presented.

Ganapati Rao Myneni

2007-06-20T23:59:59.000Z

244

Giant vacuum forces via transmission lines  

E-Print Network [OSTI]

Quantum electromagnetic fluctuations induce forces between neutral particles, known as the van der Waals (vdW) and Casimir interactions. These fundamental forces, mediated by virtual photons from the vacuum, play an important role in basic physics and chemistry, and in emerging technologies involving, e.g. micro-electromechanical systems or quantum information processing. Here we show that these interactions can be enhanced by many orders of magnitude upon changing the character of the mediating vacuum-modes. By considering two polarizable particles in the vicinity of any standard electric transmission line, along which photons can propagate in one dimension (1d), we find a much stronger and longer-range interaction than in free-space. This enhancement may have profound implications on many-particle and bulk systems, and impact the quantum technologies mentioned above. The predicted giant vacuum force is estimated to be measurable in a coplanar waveguide line.

Ephraim Shahmoon; Igor Mazets; Gershon Kurizki

2014-07-23T23:59:59.000Z

245

Remote vacuum compaction of compressible hazardous waste  

DOE Patents [OSTI]

A system for remote vacuum compaction and containment of low-level radioactive or hazardous waste comprising a vacuum source, a sealable first flexible container, and a sealable outer flexible container for receiving one or more first flexible containers. A method for compacting low level radioactive or hazardous waste materials at the point of generation comprising the steps of sealing the waste in a first flexible container, sealing one or more first containers within an outer flexible container, breaching the integrity of the first containers, evacuating the air from the inner and outer containers, and sealing the outer container shut.

Coyne, Martin J. (Pittsburgh, PA); Fiscus, Gregory M. (McMurray, PA); Sammel, Alfred G. (Pittsburgh, PA)

1998-01-01T23:59:59.000Z

246

Remote vacuum compaction of compressible hazardous waste  

DOE Patents [OSTI]

A system is described for remote vacuum compaction and containment of low-level radioactive or hazardous waste comprising a vacuum source, a sealable first flexible container, and a sealable outer flexible container for receiving one or more first flexible containers. A method for compacting low level radioactive or hazardous waste materials at the point of generation comprising the steps of sealing the waste in a first flexible container, sealing one or more first containers within an outer flexible container, breaching the integrity of the first containers, evacuating the air from the inner and outer containers, and sealing the outer container shut. 8 figs.

Coyne, M.J.; Fiscus, G.M.; Sammel, A.G.

1998-10-06T23:59:59.000Z

247

Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction  

SciTech Connect (OSTI)

The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

2007-09-15T23:59:59.000Z

248

Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation  

SciTech Connect (OSTI)

Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

Yang, Dali [Los Alamos National Laboratory; Orler, Bruce [Los Alamos National Laboratory; Tornga, Stephanie [Los Alamos National Laboratory; Welch, Cindy [Los Alamos National Laboratory

2011-01-26T23:59:59.000Z

249

Interactive chemical effects and instability of shale derived middle distillate fuels  

SciTech Connect (OSTI)

This paper presents a study of instability of shale-derived fuels. Changes in fuel properties with time have been a continuing problem in the use of middle distillate fuels. The authors define instability as the formation of insoluble sediments and gums as well as the production of peroxides and color bodies. Nitrogen and sulfur heterocycles have long been implicated in fuel degradation, but present knowledge is limited regarding the chemistry of their autoxidation reactions in the complex fuel media. Based on the GC/MS identification of nitrogen heterocyclic constituents in several shale-derived middle distillate fuels, the authors have conducted gravimetric instability tests employing three model nitrogen heterocycles in shale-derived diesel fuels. Model sulfur compound dopant studies on shale-derived jet fuels were conducted by monitoring hydroperoxide formation/decomposition and the decreased quantity of sulfur compound. Potential interactive effects have been defined for these model dopants.

Mushrush, G.W.; Beal, E.J.; Watkins, J.M.; Morris, R.E.; Hardy, D.R. (Fuels Section, Naval Research Lab., Washington, DC (US))

1989-01-01T23:59:59.000Z

250

Wave guides: vacuum w/ tube of conductor  

E-Print Network [OSTI]

Wave guides: vacuum w/ tube of conductor boundary conditions for conductor Properties: non-transverse waves except TEM mode in coaxial cable speed normal modes (from Liouville problem) TE or TM TEM for coaxial cable cuto frequency otherwise evanescent waves separation into and components with 1 #12;B

Hart, Gus

251

Vacuum fusion bonding of glass plates  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

252

Vacuum fusion bonding of glass plates  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2000-01-01T23:59:59.000Z

253

Design of the EBIS vacuum system  

SciTech Connect (OSTI)

At Brookhaven National Laboratory the Electron Beam Ion Source (EBIS) is presently being commissioned. The EBIS will be a new heavy ion pre-injector for the Relativistic Heavy Ion Collider (RHIC). The new preinjector has the potential for significant future intensity increases and can produce heavy ion beams of all species including uranium. The background pressure in the ionization region of the EBIS required to be low enough that it does not produce a significant number of ions from background gas. The pressure in the regions of the electron gun and electron collector can be higher than in the ionization region provided there is efficient vacuum separation between the sections. For injection the ions must be accelerated to 100KV by pulsing the EBIS platform. All associated equipment including the vacuum equipment on the platform is at a 100KV potential. The vacuum system design and the vacuum controls for the EBIS platform and transport system will be presented as well as the interface with the Booster Ring which has a pressure 10-11 Torr.

Mapes, M.; Smart, L.; Weiss, D.

2011-03-28T23:59:59.000Z

254

Fractal Threshold Behavior in Vacuum Gravitational Collapse  

E-Print Network [OSTI]

We present the numerical evidence for fractal threshold behavior in the five dimensional vacuum Einstein equations satisfying the cohomogeneity-two triaxial Bianchi type-IX ansatz. In other words, we show that a flip of the wings of a butterfly may influence the process of the black hole formation.

Sebastian J. Szybka; Tadeusz Chmaj

2008-04-02T23:59:59.000Z

255

2nd IEEE International Vacuum Electronics Conference  

E-Print Network [OSTI]

2nd IEEE International Vacuum Electronics Conference Huis ter Duin, Noordwijk, The Netherlands) model based on Eulerian electron beam equations. We identify and illustrate with preliminary exam- ples. With such multifrequency input signals, the inherent nonlinear behavior of the electron beam produces unwanted frequencies

Dobson, Ian

256

The distribution of n-alkanes in partially frozen middle distillate fuels  

SciTech Connect (OSTI)

This work on partially frozen fuels is one of a continuing series of studies on the effect of composition on the freezing properties of hydrocarbon fuels. The method used for this purpose was reported previously. By means of this method the authors were able to determine the composition of the liquid and solid phases in partially frozen mixtures consisting of liquid and of solid crystals plus entrapped liquid. This paper presents the results of this study on five different middle distillate fuels.

Van Winkle, T.L.; Affens, W.A.; Beal, E.J.; Hazlett, R.N.; Guzman, J.

1986-04-01T23:59:59.000Z

257

Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves  

SciTech Connect (OSTI)

Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

1996-11-01T23:59:59.000Z

258

Magnetocaloric properties of distilled gadolinium: Effects of structural inhomogeneity and hydrogen impurity  

SciTech Connect (OSTI)

High-purity Gd prepared by distillation is a structurally inhomogeneous system consisting of needle-shaped crystals of cross section 0.5–2.5??m with near-c-axis orientation embedded in a matrix of nanosized (30–100?nm) grains. By measuring the magnetocaloric effect (MCE) directly, we find that the MCE values differ markedly for the plate-shaped samples cut out of a distillate along and perpendicular to the crystals. The effect of small controlled amounts of impurity (hydrogen) on the properties of distilled Gd is further studied. We observe opposite trends in the MCE response to hydrogen charging with respect to the crystal's orientation within the samples and discuss mechanisms interrelating the unique structural morphology with the impurity behavior. As an overall assessment, the Curie temperatures of ?-GdH{sub x} solid solutions increase from 291?K up to 294?K when increasing hydrogen concentration x from 0 to 0.15. Hydrogenation is found to broaden the ferromagnetic-to-paramagnetic phase transition. Hydrogen-containing specimens demonstrate reversibility of MCE at these temperatures.

Burkhanov, G. S.; Kolchugina, N. B.; Chzhan, V. B.; Chistyakov, O. D. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); Tereshina, E. A. [Institute of Physics ASCR, 18221 Prague (Czech Republic); Tereshina, I. S. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow (Russian Federation); Politova, G. A. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Badurski, D.; Drulis, H. [Institute of Low Temperature and Structure Research PAS, 50-950 Wroclaw (Poland); Paukov, M.; Havela, L. [Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, 12116 Prague (Czech Republic)

2014-06-16T23:59:59.000Z

259

A novel proportional--integral-derivative control configuration with application to the control of batch distillation  

SciTech Connect (OSTI)

The aim of this paper is to propose a novel proportional-integral-derivative (PID) control configuration based on an observer structure. Batch distillation is used as the base case study where the regulated output is the distillate composition. The proposed PID control law is derived in the framework of robust nonlinear control with modeling error compensation techniques. A reduced-order observer is proposed to estimate both the derivative of the regulated output and the underlying modeling error. These observations are subsequently used in a control loop to feedback variations of distillate composition (derivative feedback) and to counteract the effects of modeling errors. It is shown that, under certain conditions, the resulting control law is equivalent to a classical PID controller with an antireset windup scheme. Moreover, the tuning of the controller is performed very easily in terms of a prescribed closed-loop time constant and an estimation time constant. Numerical results are provided for binary and multicomponent separations. Sampled/delayed measurements and several sources of uncertainties are considered in order to provide a realistic test scenario for the proposed control design procedure.

Alvarez-Ramirez, J.; Monroy-Loperena, R.; Cervantes, I.; Morales, A.

2000-02-01T23:59:59.000Z

260

Spent nuclear fuel project cold vacuum drying facility vacuum and purge system design description  

SciTech Connect (OSTI)

This document provides the System Design Description (SDD) for the Cold Vacuum Drying Facility (CVDF) Vacuum and Purge System (VPS) . The SDD was developed in conjunction with HNF-SD-SNF-SAR-O02, Safety Analysis Report for the Cold Vacuum Drying Facility, Phase 2, Supporting Installation of Processing Systems (Garvin 1998), The HNF-SD-SNF-DRD-002, 1998, Cold Vacuum Drying Facility Design Requirements, and the CVDF Design Summary Report. The SDD contains general descriptions of the VPS equipment, the system functions, requirements and interfaces. The SDD provides references for design and fabrication details, operation sequences and maintenance. This SDD has been developed for the SNFP Operations Organization and shall be updated, expanded, and revised in accordance with future design, construction and startup phases of the CVDF until the CVDF final ORR is approved.

IRWIN, J.J.

1998-11-30T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Energy Comparison Vacuum Producing Equipment - Mechanical Vacuum Pumps vs. Steam Ejectors  

E-Print Network [OSTI]

vacuum on condensers, process reactors, or equipment and processes requiring subatmospheric conditions, has been to utilize steam ejectors. Due to the inherent operating inefficiency and wastefulness of the steam ejector, coupled with the rapidly...

Foisy, E. C.; Munkittrick, M. T.

1982-01-01T23:59:59.000Z

262

Vacuum insulation tandem accelerator for B. Bayanov1  

E-Print Network [OSTI]

273 Vacuum insulation tandem accelerator for NCT B. Bayanov1 , Yu. Belchenko1 , V. Belov1 , G of high current hydrogen negative ions by special geometry of potential electrodes with vacuum insulation. Fig. 1 shows the construction of vacuum insulation tandem accelerator developed at BINP, as a base

Taskaev, Sergey Yur'evich

263

Copolymers useful as additives for lowering the cloud point of middle hydrocarbon distillates, and compositions of middle hydrocarbon distillates comprising them  

SciTech Connect (OSTI)

Products useful as additives for lowering the cloud point of middle distillates have a molecular weight from 1,000 to 50,000, and are obtained by reacting a compound of the formula R-Z((CH/sub 2/) /SUB n/ NH) /SUB m/ H or HO-CH/sub 2/-R'-NH/sub 2/ where R is a monovalent saturated aliphatic radical of 1-30 carbon atoms, Z is -NH- or oxygen, n is 2 to 4, m is zero or 1 to 4 and R' is a saturated divalent aliphatic radical of 1-18 carbon atoms, with a copolymer comprising recurrent units (A) from an alkyl ester of an unsaturated monocarboxylic acid and/or a vinyl ester of a saturated monocarboxylic acid, recurrent units (B) from diisobutylene and recurrent units (C) from an unsaturated a,b-dicarboxylic compound.

Durand, J. P.; Damin, B.; Dawans, F.; Leger, R.

1985-03-05T23:59:59.000Z

264

Spontaneous Emission from a Fractal Vacuum  

E-Print Network [OSTI]

Spontaneous emission of a quantum emitter coupled to a QED vacuum with a deterministic fractal structure of its spectrum is considered. We show that the decay probability does not follow a Wigner-Weisskopf exponential decrease but rather an overall power law behavior with a rich oscillatory structure, both depending on the local fractal properties of the vacuum spectrum. These results are obtained by giving first a general perturbative derivation for short times. Then we propose a simplified model which retains the main features of a fractal spectrum to establish analytic expressions valid for all time scales. Finally, we discuss the case of a Fibonacci cavity and its experimental relevance to observe these results.

Eric Akkermans; Evgeni Gurevich

2012-10-25T23:59:59.000Z

265

Vacuum die attach for integrated circuits  

DOE Patents [OSTI]

A thin film eutectic bond for attaching an integrated circuit die to a circuit substrate is formed by coating at least one bonding surface on the die and substrate with an alloying metal, assembling the die and substrate under compression loading, and heating the assembly to an alloying temperature in a vacuum. A very thin bond, 10 microns or less, which is substantially void free, is produced. These bonds have high reliability, good heat and electrical conduction, and high temperature tolerance. The bonds are formed in a vacuum chamber, using a positioning and loading fixture to compression load the die, and an IR lamp or other heat source. For bonding a silicon die to a silicon substrate, a gold silicon alloy bond is used. Multiple dies can be bonded simultaneously. No scrubbing is required.

Schmitt, Edward H. (Livermore, CA); Tuckerman, David B. (Livermore, CA)

1991-01-01T23:59:59.000Z

266

Interacting vacuum energy in the dark sector  

E-Print Network [OSTI]

We analyse three cosmological scenarios with interaction in the dark sector, which are particular cases of a general expression for the energy flux from vacuum to matter. In the first case the interaction leads to a transition from an unstable de Sitter phase to a radiation dominated universe, avoiding in this way the initial singularity. In the second case the interaction gives rise to a slow-roll power-law inflation. Finally, the third scenario is a concordance model for the late-time universe, with the vacuum term decaying into cold dark matter. We identify the physics behind these forms of interaction and show that they can be described as particular types of the modified Chaplygin gas.

L. P. Chimento; S. Carneiro

2014-04-02T23:59:59.000Z

267

Vacuum die attach for integrated circuits  

DOE Patents [OSTI]

A thin film eutectic bond for attaching an integrated circuit die to a circuit substrate is formed by coating at least one bonding surface on the die and substrate with an alloying metal, assembling the die and substrate under compression loading, and heating the assembly to an alloying temperature in a vacuum. A very thin bond, 10 microns or less, which is substantially void free, is produced. These bonds have high reliability, good heat and electrical conduction, and high temperature tolerance. The bonds are formed in a vacuum chamber, using a positioning and loading fixture to compression load the die, and an IR lamp or other heat source. For bonding a silicon die to a silicon substrate, a gold silicon alloy bond is used. Multiple dies can be bonded simultaneously. No scrubbing is required. 1 figure.

Schmitt, E.H.; Tuckerman, D.B.

1991-09-10T23:59:59.000Z

268

Flat Spacetime Vacuum in Loop Quantum Gravity  

E-Print Network [OSTI]

We construct a state in the loop quantum gravity theory with zero cosmological constant, which should correspond to the flat spacetime vacuum solution. This is done by defining the loop transform coefficients of a flat connection wavefunction in the holomorphic representation which satisfies all the constraints of quantum General Relativity and it is peaked around the flat space triads. The loop transform coefficients are defined as spin foam state sum invariants of the spin networks embedded in the spatial manifold for the SU(2) quantum group. We also obtain an expression for the vacuum wavefunction in the triad represntation, by defining the corresponding spin networks functional integrals as SU(2) quantum group state sums.

A. Mikovic

2004-04-06T23:59:59.000Z

269

Trapping atoms using nanoscale quantum vacuum forces  

E-Print Network [OSTI]

Quantum vacuum forces dictate the interaction between individual atoms and dielectric surfaces at nanoscale distances. For example, their large strengths typically overwhelm externally applied forces, which makes it challenging to controllably interface cold atoms with nearby nanophotonic systems. Here, we show that it is possible to tailor the vacuum forces themselves to provide strong trapping potentials. The trapping scheme takes advantage of the attractive ground state potential and adiabatic dressing with an excited state whose potential is engineered to be resonantly enhanced and repulsive. This procedure yields a strong metastable trap, with the fraction of excited state population scaling inversely with the quality factor of the resonance of the dielectric structure. We analyze realistic limitations to the trap lifetime and discuss possible applications that might emerge from the large trap depths and nanoscale confinement.

D. E. Chang; K. Sinha; J. M. Taylor; H. J. Kimble

2013-10-22T23:59:59.000Z

270

Representing the vacuum polarization on de Sitter  

SciTech Connect (OSTI)

Previous studies of the vacuum polarization on de Sitter have demonstrated that there is a simple, noncovariant representation of it in which the physics is transparent. There is also a cumbersome, covariant representation in which the physics is obscure. Despite being unwieldy, the latter form has a powerful appeal for those who are concerned about de Sitter invariance. We show that nothing is lost by employing the simple, noncovariant representation because there is a closed form procedure for converting its structure functions to those of the covariant representation. We also present a vastly improved technique for reading off the noncovariant structure functions from the primitive diagrams. And we discuss the issue of representing the vacuum polarization for a general metric background.

Leonard, Katie E.; Woodard, Richard P. [Department of Physics, University of Florida, Gainesville, Florida 32611 (United States)] [Department of Physics, University of Florida, Gainesville, Florida 32611 (United States); Prokopec, Tomislav [Institute of Theoretical Physics (ITP) and Spinoza Institute, Utrecht University, Postbus 80195, 3508 TD Utrecht (Netherlands)] [Institute of Theoretical Physics (ITP) and Spinoza Institute, Utrecht University, Postbus 80195, 3508 TD Utrecht (Netherlands)

2013-03-15T23:59:59.000Z

271

Physical vacuum is a special superfluid medium  

E-Print Network [OSTI]

The Navier-Stokes equation contains two terms which have been subjected to slight modification: (a) the viscosity term depends of time (the viscosity in average on time is zero, but its variance is non-zero); (b) the pressure gradient contains an added term describing the quantum entropy gradient multiplied by the pressure. Owing to these modifications, the Navier-Stokes equation can be reduced to the Schr\\"odinger equation describing behavior of a particle into the vacuum being as a superfluid medium. Vortex structures arising in this medium show infinitely long life owing to zeroth average viscosity. The non-zero variance describes exchange of the vortex energy with zero-point energy of the vacuum. Radius of the vortex trembles around some average value. This observation sheds the light to the Zitterbewegung phenomenon. The long-lived vortex has a non-zero core where the vortex velocity vanishes.

Sbitnev, Valeriy I

2015-01-01T23:59:59.000Z

272

Is graphene in vacuum an insulator?  

E-Print Network [OSTI]

We present evidence, from Lattice Monte Carlo simulations of the phase diagram of graphene as a function of the Coulomb coupling between quasiparticles, that graphene in vacuum is likely to be an insulator. We find a semimetal-insulator transition at $\\alpha_g^\\text{crit} = 1.11 \\pm 0.06$, where $\\alpha_g^{} \\simeq 2.16$ in vacuum, and $\\alpha_g^{} \\simeq 0.79$ on a SiO$_2^{}$ substrate. Our analysis uses the logarithmic derivative of the order parameter, supplemented by an equation of state. The insulating phase disappears above a critical number of four-component fermion flavors $4 < N_f^{\\text{crit}} < 6$. Our data are consistent with a second-order transition.

Joaquín E. Drut; Timo A. Lähde

2009-01-15T23:59:59.000Z

273

Nonsingular Decaying Vacuum Cosmology and Entropy Production  

E-Print Network [OSTI]

The thermodynamic behavior of a decaying vacuum cosmology describing the entire cosmological history evolving between two extreme (early and late time) de Sitter eras is investigated. The thermal evolution from the early de Sitter to the radiation phase is discussed in detail. The temperature evolution law and the increasing entropy function are analytically determined. The entropy of the effectively massless particles is initially zero but evolves continuously to the present day maximum value within the current Hubble radius, $S_0 \\sim 10^{88}$ in natural units. By using the Gibbons-Hawking temperature relation for the de Sitter spacetime, it is found that the ratio between the primeval and the late time vacuum energy densities is $\\rho_{vI}/\\rho_{v0} \\sim 10^{123}$, as required by some naive estimates from quantum field theory.

J. A. S. Lima; S. Basilakos; Joan Solà

2015-03-08T23:59:59.000Z

274

Vacuum decay in a soluble model  

SciTech Connect (OSTI)

We study a field-theoretical model where the decay rate of the false vacuum can be computed up to the first quantum corrections in both the high-temperature and zero-temperature limits. We find that the dependence of the decay rate on the height and width of the potential barrier does not follow the same simple area rule as in the quantum-mechanical case. Furthermore, its behavior is strongly model dependent.

Ferraz de Camargo F, A.; Shellard, R.C.; Marques, G.C.

1984-03-15T23:59:59.000Z

275

Bremsstrahlung Radiation At a Vacuum Bubble Wall  

E-Print Network [OSTI]

When charged particles collide with a vacuum bubble, they can radiate strong electromagnetic waves due to rapid deceleration. Owing to the energy loss of the particles by this bremsstrahlung radiation, there is a non-negligible damping pressure acting on the bubble wall even when thermal equilibrium is maintained. In the non-relativistic region, this pressure is proportional to the velocity of the wall and could have influenced the bubble dynamics in the early universe.

Jae-Weon Lee; Kyungsub Kim; Chul H. Lee; Ji-ho Jang

2007-04-06T23:59:59.000Z

276

Dual superconducting properties of the QCD vacuum  

E-Print Network [OSTI]

A consistent description of the confining QCD vacuum as a dual superconductor requires a determination of fundamental parameters such as the superconductor correlation length $\\xi$ and the field penetration depth $\\lambda$, which determine whether the superconductor is of type I or type II. We illustrate preliminary results of a lattice determination of $\\xi$ for the case of pure Yang-Mills with two colors, obtained by measuring the temporal correlator of a disorder parameter detecting dual superconductivity.

A. D'Alessandro; M. D'Elia

2005-10-27T23:59:59.000Z

277

Remote controlled vacuum joint closure mechanism  

DOE Patents [OSTI]

A remotely operable and maintainable vacuum joint closure mechanism for a noncircular aperture is disclosed. The closure mechanism includes an extendible bellows coupled at one end to a noncircular duct and at its other end to a flange assembly having sealed grooves for establishing a high vacuum seal with the abutting surface of a facing flange which includes an aperture forming part of the system to be evacuated. A plurality of generally linear arrangements of pivotally coupled linkages and piston combinations are mounted around the outer surface of the duct and aligned along the length thereof. Each of the piston/linkage assemblies is adapted to engage the flange assembly by means of a respective piston and is further coupled to a remote controlled piston drive shaft to permit each of the linkages positioned on a respective flat outer surface of the duct to simultaneously and uniformly displace a corresponding piston and the flange assembly with which it is in contact along the length of the duct in extending the bellows to provide a high vacuum seal between the movable flange and the facing flange. A plurality of latch mechanisms are also pivotally mounted on the outside of the duct. A first end of each of the latch mechanisms is coupled to a remotely controlled latch control shaft for displacing the latch mechanism about its pivot point. In response to the pivoting displacement of the latch mechanism, a second end thereof is displaced so as to securely engage the facing flange and maintain the high vacuum seal established by the displacement of the flange assembly and extension of the bellows without displacing the entire duct.

Doll, D.W.; Hager, E.R.

1984-02-22T23:59:59.000Z

278

Cold Vacuum Drying Facility hazard analysis report  

SciTech Connect (OSTI)

This report describes the methodology used in conducting the Cold Vacuum Drying Facility (CVDF) hazard analysis to support the CVDF phase 2 safety analysis report (SAR), and documents the results. The hazard analysis was performed in accordance with DOE-STD-3009-94, Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, and implements the requirements of US Department of Energy (DOE) Order 5480.23, Nuclear Safety Analysis Reports.

Krahn, D.E.

1998-02-23T23:59:59.000Z

279

Vacuum energy sequestering and cosmic dynamics  

E-Print Network [OSTI]

We explicitly compute the dynamics of closed homogeneous and isotropic universes permeated by a single perfect fluid with a constant equation of state parameter $w$ in the context of a recent reformulation of general relativity, proposed in [1], which prevents the vacuum energy from acting as a gravitational source. This is done using an iterative algorithm, taking as an initial guess the background cosmological evolution obtained using standard general relativity in the absence of a cosmological constant. We show that, in general, the impact of the vacuum energy sequestering mechanism on the dynamics of the universe is significant, except for the $w=1/3$ case where the results are identical to those obtained in the context of general relativity with a null cosmological constant. We also show that there are well behaved models in general relativity that do not have a well behaved counterpart in the vacuum energy sequestering paradigm studied in this paper, highlighting the specific case of a quintessence scalar field with a linear potential.

P. P. Avelino

2014-10-16T23:59:59.000Z

280

Vacuum Predictions and Measurements for an Internal Pellet Target  

E-Print Network [OSTI]

Measurements with low Z targets at internal experiments typically imply a gas load which deteriorates the ring vacuum. Future experiments need reliable estimates for the expected vacuum conditions in order to design 4-pi detectors closely surrounding the interaction area. We present a method for the calculation of the resulting vacuum of such a complex system using a Pellet Target. In order to test the method, a vacuum system with diagnostic tools has been set up and a Pellet Target was operated under realistic conditions. The results for the absolute vacuum agree within factors of two with the expected pressures.

Lehmann, I; Friden, C J; Norman, G; Ekström, C; Johansson, T; Wiedner, U; Lehmann, Inti; Nordhage, Orjan; Friden, Carl-Johan; Norman, Gunar; Ekstrom, Curt; Johansson, Tord; Wiedner, Ulrich

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Vacuum Predictions and Measurements for an Internal Pellet Target  

E-Print Network [OSTI]

Measurements with low Z targets at internal experiments typically imply a gas load which deteriorates the ring vacuum. Future experiments need reliable estimates for the expected vacuum conditions in order to design 4-pi detectors closely surrounding the interaction area. We present a method for the calculation of the resulting vacuum of such a complex system using a Pellet Target. In order to test the method, a vacuum system with diagnostic tools has been set up and a Pellet Target was operated under realistic conditions. The results for the absolute vacuum agree within factors of two with the expected pressures.

Inti Lehmann; Orjan Nordhage; Carl-Johan Friden; Gunar Norman; Curt Ekstrom; Tord Johansson; Ulrich Wiedner

2007-01-04T23:59:59.000Z

282

Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant  

SciTech Connect (OSTI)

When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

Gambert, G.

1996-12-31T23:59:59.000Z

283

,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: EnergyShale ProvedTexas"Brunei (Dollars perReserves (Billion Cubic Feet)"+ LeaseDistillate

284

Method and apparatus for assessing distillate-fuel stability by oxygen overpressure  

SciTech Connect (OSTI)

Reactions leading to insoluble sediments formation in distillate fuel are accelerated by forcing oxygen into solution in the fuel at pressures of between about 90 and 110 psig and then stressing the fuel under conditions of accelerated storage at temperatures of between about 40 C to 100 C. The method then makes use of gravimetric determination of the total insoubles formed. The stability of the fuel over a period of time as well as its comparitive stability to other fuels can then be predicted from the amount of insolubles formed. The method can be carried out by using a specialized pressure vessel.

Hardy, D.R.; Beal, E.J.; Burnett, J.C.

1989-06-27T23:59:59.000Z

285

Ultra-high vacuum photoelectron linear accelerator  

DOE Patents [OSTI]

An rf linear accelerator for producing an electron beam. The outer wall of the rf cavity of said linear accelerator being perforated to allow gas inside said rf cavity to flow to a pressure chamber surrounding said rf cavity and having means of ultra high vacuum pumping of the cathode of said rf linear accelerator. Said rf linear accelerator is used to accelerate polarized or unpolarized electrons produced by a photocathode, or to accelerate thermally heated electrons produced by a thermionic cathode, or to accelerate rf heated field emission electrons produced by a field emission cathode.

Yu, David U.L.; Luo, Yan

2013-07-16T23:59:59.000Z

286

Vacuum chamber for containing particle beams  

DOE Patents [OSTI]

A vacuum chamber for containing a charged particle beam in a rapidly changing magnetic environment comprises a ceramic pipe with conducting strips oriented along the longitudinal axis of the pipe and with circumferential conducting bands oriented perpendicular to the longitudinal axis but joined with a single longitudinal electrical connection. When both strips and bands are on the outside of the ceramic pipe, insulated from each other, a high-resistance conductive layer such as nickel can be coated on the inside of the pipe.

Harvey, A.

1985-11-26T23:59:59.000Z

287

Ultracapacitor having residual water removed under vacuum  

DOE Patents [OSTI]

A multilayer cell is provided that comprises two solid, nonporous current collectors, two porous electrodes separating the current collectors, a porous separator between the electrodes and an electrolyte occupying pores in the electrodes and separator. The mutilayer cell is electrolyzed to disassociate water within the cell to oxygen gas and hydrogen gas. A vacuum is applied to the cell substantially at the same time as the electrolyzing step, to remove the oxygen gas and hydrogen gas. The cell is then sealed to form a ultracapacitor substantially free from water.

Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); Day, James (Scotia, NY)

2002-10-15T23:59:59.000Z

288

Non-Vacuum Electron Beam Welding  

SciTech Connect (OSTI)

Original objectives of CRADA number BNL-01-03 between BNL and Acceleron, Inc., were to further develop the Plasma Window concept (a BNL invention covered by US Patent number 5,578,831), mate the Plasma Window to an existing electron beam welder to perform in-air electron beam welding, and mount the novel nonvacuum electron beam welder on a robot arm. Except for the last objective, all other goals were met or exceeded. Plasma Window design and operation was enhanced during the project, and it was successfully mated to a conventional4 kW electron beam welder. Unprecedented high quality non-vacuum electron beam . welding was demonstrated. Additionally, a new invention the Plasma Shield (US Patent number 7,075,030) that chemically and thermally shields a target object was set forth. Great interest in the new technology was shown by a number of industries and three arcs were sold for experimental use. However, the welding industry requested demonstration of high speed welding, which requires 100 kW electron beam welders. The cost of such a welder involved the need for additional funding. Therefore, some of the effort was directed towards Plasma Shield development. Although relatively a small portion of the R&D effort was spent on the Plasma Shield, some very encouraging results were obtained. Inair Plasma Shield was demonstrated. With only a partial shield, enhanced vacuum separation and cleaner welds were realized. And, electron beam propagation in atmosphere improved by a factor of about 3. Benefits to industry are the introduction of two new technologies. BNL benefited from licensing fee cash, from partial payment for employee salary, and from a new patent In addition to financial benefits, a new technology for physics studies was developed. Recommendations for future work are to develop an under-water plasma shield, perform welding with high-power electron beam:s, carry out other plasma shielded electron beam and laser processes. Potential benefits from further R&D are that various processes involving electron ion and laser beams that have now restrictions can, with the Plasma Shield be performed in practically any environment. For example, electron beam and laser welding can be performed under water, as well as, in situ repair of ship and nuclear reactor components. The plasma shield results in both thermal (since the plasma is hotter than the environment) and chemical shielding. The latter feature brings about in-vacuum process purity out of vacuum, and the thermal shielding aspect results in higher production rates.

Hershcovitch, Ady

2007-01-31T23:59:59.000Z

289

Quality of vacuum packaged lamb retail cuts  

E-Print Network [OSTI]

) provision of an ideal environment for the ag1ng of meat. Materials wh1ch prevent the rapid exchange of gases result in longer storage 11fe of meat than is obta1ned by packaging with more permeable materials (Kraft and Ayres, 1952). Jaye et al. (1962... storage for up to 35 days. Hanna et al. (1976) reported that these coryneform bacteria were species of ~Cba t i d a o hath i ~th rmos ha t m. B. ~th rmos hactu has been reported to be a major constituent of the bacterial flora of vacuum packaged...

Wanstedt, Kristen Gae

1982-01-01T23:59:59.000Z

290

Vacuum Stability and the Higgs Boson  

E-Print Network [OSTI]

The discovery of the Higgs boson at the LHC, and especially the determination of its mass around 125 GeV, together with the absence of any trace of new physics make it conceivable that we live in a metastable (but long-lived) electroweak vacuum. I will describe the state-of-the-art calculation that leads to this conclusion, elaborate on possible implications as well as cures of this instability of the Higgs potential and discuss some possible lines of attack for lattice studies of such metastability.

Jose R. Espinosa

2013-11-08T23:59:59.000Z

291

Spontaneous Supersymmetry Breaking Induced by Vacuum Condensates  

E-Print Network [OSTI]

We propose a novel mechanism of spontaneous supersymmetry breaking which relies upon an ubiquitous feature of Quantum Field Theory, vacuum condensates. Such condensates play a crucial r\\^{o}le in many phenomena. Examples include Unruh effect, superconductors, particle mixing, and quantum dissipative systems. We argue that in all these phenomena supersymmetry, when present, is spontaneously broken. Evidence for our conjecture is given for the Wess--Zumino model, that can be considered an approximation to the supersymmetric extensions of the above mentioned systems. The magnitude of the effect is estimated for a recently proposed experimental setup based on an optical lattice.

Antonio Capolupo; Marco Di Mauro

2012-08-29T23:59:59.000Z

292

An automated vacuum gauge calibration system  

SciTech Connect (OSTI)

An automated system for calibrating vacuum gauges over the pressure range of 10{sup {minus}6} to 0.1 Pa was designed and constructed at the National Institute of Standards and Technology (NIST) for the Department of Energy (DOE) Primary Standards Laboratory at Sandia National Laboratories (SNL). Calculable pressures are generated by passing a known flow of gas through an orifice of known conductance. The orifice conductance is derived from dimensional measurements and accurate flows are generated using metal capillary leaks. The expanded uncertainty (k = 2) in the generated pressure is estimated to be between 1% and 4% over the calibration range. The design, calibration results. and component uncertainties will be discussed.

Abbott, P.J. [NIST, GAithersburg, MD (United States); Benner, M.S. [Sandia National Labs., Albuquerque, NM (United States)

1998-04-01T23:59:59.000Z

293

Metals purification by improved vacuum arc remelting  

DOE Patents [OSTI]

The invention relates to improved apparatuses and methods for remelting metal alloys in furnaces, particularly consumable electrode vacuum arc furnaces. Excited reactive gas is injected into a stationary furnace arc zone, thus accelerating the reduction reactions which purify the metal being melted. Additionally, a cooled condensation surface is disposed within the furnace to reduce the partial pressure of water in the furnace, which also fosters the reduction reactions which result in a purer produced ingot. Methods and means are provided for maintaining the stationary arc zone, thereby reducing the opportunity for contaminants evaporated from the arc zone to be reintroduced into the produced ingot.

Zanner, Frank J. (Sandia Park, NM); Williamson, Rodney L. (Albuquerque, NM); Smith, Mark F. (Albuquerque, NM)

1994-12-13T23:59:59.000Z

294

Vacuum Insulation for Windows | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up from theDepartment of Dept. ofUSAPotentially SensitiveUsersVOLTTRONofVacancyVacuum

295

Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry  

E-Print Network [OSTI]

Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

Colin J. Trout; Kenneth R. Brown

2015-01-29T23:59:59.000Z

296

Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry  

E-Print Network [OSTI]

Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

Colin J. Trout; Kenneth R. Brown

2015-01-07T23:59:59.000Z

297

Optimum Requirements for the Synthesis of Biodiesel Using Fatty Acid Distillates  

E-Print Network [OSTI]

The optimum requirements of temperature, retention time, mole ratio of reactants and catalyst for the direct synthesis of biodiesel from fatty acid distillates of palm kernel oil using tetraoxosulphate (VI) acid as catalyst was studied. The following parameters were used for the efficient and economic production of biodiesel: eight (8) moles of methanol per mole of fatty acid, 0.06 mole of tetraoxosulphate (VI) acid per mole of fatty acid, a retention time of sixty (60) minutes and reaction temperature of 65 OC. And this gave a maximum percentage yield of 98.4. Other parameters obtained include: an acid value of 0.1683 mg KOH/g, iodine value of 15.3549, flash point of 209 OC, viscosity of 3.7957 mm2s-1, density of 0.8776 g cm-3, water content of 400.05 mg kg-1, soap content of 2.30 mg/kg, and ester content of 98.804 %. From the obtained parameters, the biodiesel produced from fatty acid distillates of palm kernel oil reaches prescribed international standards for biodiesel production.

Akunna E. Ejele

298

Steam vacuum cleaning. Innovative technology summary report  

SciTech Connect (OSTI)

The US Department of Energy (DOE) continually seeks safer and more cost-effective remediation technologies for use in the decontamination and decommissioning (D and D) of nuclear facilities. The baseline technology currently used for washing debris is a high-pressure water cleaning (HPWC) system. The system used at the FEMP is the Hotsy{reg_sign} Model 550B HPWC. Although the HPWC technology has functioned satisfactorily, improvements are being sought in areas related to reduced liquid waste volume, increased productivity, increased washing effectiveness, and decreased airborne contamination. An innovative technology that offers potential improvements in these areas is a steam vacuum cleaning (SVC) system that integrates high-pressure steam cleaning with a vacuum recovery sub-system that simultaneously collects dislodged contaminants thereby reducing airborne contamination. The SVC system selected for demonstration at the FEMP was the Kelly{trademark} Decontamination System shown. This report provides comparative performance and cost analyses between the Hotsy HPWC system and the Kelly Decontamination System. Both technologies were demonstrated at the FEMP site located at Fernald, Ohio from July 29, 1996 through August 15, 1996. The demonstrations were conducted at the FEMP Plant 1 as part of the LSTD project sponsored by the Deactivation and Decommissioning Focus Area (DDFA) of the US DOE`s Office of Science and Technology.

NONE

1999-05-01T23:59:59.000Z

299

LTC vacuum blasting machine (concrete): Baseline report  

SciTech Connect (OSTI)

The LTC shot blast technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC 1073 Vacuum Blasting Machine uses a high-capacity, direct-pressure blasting system which incorporates a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast. It incorporates a vacuum system which removes dust and debris from the surface as it is blasted. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure during maintenance activities was minimal, but due to mechanical difficulties dust monitoring could not be conducted during operation. Noise exposure was significant. Further testing for each of these exposures is recommended because of the outdoor environment where the testing demonstration took place. This may cause the results to be inaccurate. It is feasible that the dust and noise levels will be higher in an enclosed environment. In addition, other safety and health issues found were ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, and arm-hand vibration.

NONE

1997-07-31T23:59:59.000Z

300

Initial conditioning of the TFTR vacuum vessel  

SciTech Connect (OSTI)

We report on the initial conditioning of the Tokamak Fusion Test Reactor (TFTR) vacuum vessel prior to the initiation of first plasma discharges, and during subsequent operation with high power ohmically-heated plasmas. Following evacuation of the 86 m/sup 3/ vessel with the 10/sup 4/ 1/s high vacuum pumping system, the vessel was conditioned by a 15 A dc glow discharge in H/sub 2/ at a pressure of 5 mTorr. Rapid-pulse discharge cleaning was used subsequently to preferentially condition the graphite plasma limiters. The effectiveness of the discharge cleaning was monitored by measuring the exhaust rates of the primary discharge products (CO/C/sub 2/H/sub 4/, CH/sub 4/, and H/sub 2/O). After 175 hours of glow discharge treatment, the equivalent of 50 monolayers of C and O was removed from the vessel, and the partial pressures of impurity gases were reduced to the range of 10/sup -9/-10/sup -10/ Torr.

Dylla, H.F.; Blanchard, W.R.; Krawchuk, R.B.; Hawryluk, R.J.; Owens, D.K.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Cosmologies with a time dependent vacuum  

E-Print Network [OSTI]

The idea that the cosmological term, Lambda, should be a time dependent quantity in cosmology is a most natural one. It is difficult to conceive an expanding universe with a strictly constant vacuum energy density, namely one that has remained immutable since the origin of time. A smoothly evolving vacuum energy density that inherits its time-dependence from cosmological functions, such as the Hubble rate or the scale factor, is not only a qualitatively more plausible and intuitive idea, but is also suggested by fundamental physics, in particular by quantum field theory (QFT) in curved space-time. To implement this notion, is not strictly necessary to resort to ad hoc scalar fields, as usually done in the literature (e.g. in quintessence formulations and the like). A "running" Lambda term can be expected on very similar grounds as one expects (and observes) the running of couplings and masses with a physical energy scale in QFT. Furthermore, the experimental evidence that the equation of state of the dark energy could be evolving with time/redshift (including the possibility that it might currently behave phantom-like) suggests that a time-variable Lambda term (possibly accompanied by a variable Newton's gravitational coupling G=G(t)) could account in a natural way for all these features. Remarkably enough, a class of these models (the "new cosmon") could even be the clue for solving the old cosmological constant problem, including the coincidence problem.

Joan Sola

2011-02-09T23:59:59.000Z

302

Material-controlled dynamic vacuum insulation  

DOE Patents [OSTI]

A compact vacuum insulation panel is described comprising a chamber enclosed by two sheets of metal, glass-like spaces disposed in the chamber between the sidewalls, and a high-grade vacuum in the chamber includes apparatus and methods for enabling and disabling, or turning ``on`` and ``off`` the thermal insulating capability of the panel. One type of enabling and disabling apparatus and method includes a metal hydride for releasing hydrogen gas into the chamber in response to heat, and a hydrogen grate between the metal hydride and the chamber for selectively preventing and allowing return of the hydrogen gas to the metal hydride. Another type of enabling and disabling apparatus and method includes a variable emissivity coating on the sheets of metal in which the emissivity is controllably variable by heat or electricity. Still another type of enabling and disabling apparatus and method includes metal-to-metal contact devices that can be actuated to establish or break metal-to-metal heat paths or thermal short circuits between the metal sidewalls. 25 figs.

Benson, D.K.; Potter, T.F.

1996-10-08T23:59:59.000Z

303

Material-controlled dynamic vacuum insulation  

DOE Patents [OSTI]

A compact vacuum insulation panel comprising a chamber enclosed by two sheets of metal, glass-like spaces disposed in the chamber between the sidewalls, and a high-grade vacuum in the chamber includes apparatus and methods for enabling and disabling, or turning "on" and "off" the thermal insulating capability of the panel. One type of enabling and disabling apparatus and method includes a metal hydride for releasing hydrogen gas into the chamber in response to heat, and a hydrogen grate between the metal hydride and the chamber for selectively preventing and allowing return of the hydrogen gas to the metal hydride. Another type of enabling and disabling apparatus and method includes a variable emissivity coating on the sheets of metal in which the emissivity is controllably variable by heat or electricity. Still another type of enabling and disabling apparatus and method includes metal-to-metal contact devices that can be actuated to establish or break metal-to-metal heat paths or thermal short circuits between the metal sidewalls.

Benson, David K. (14154 W. First Dr., Golden, CO 80401); Potter, Thomas F. (515 S. Magnolia La., Denver, CO 80224)

1996-10-08T23:59:59.000Z

304

Radiation-controlled dynamic vacuum insulation  

DOE Patents [OSTI]

A compact vacuum insulation panel is described comprising a chamber enclosed by two sheets of metal, glass-like spaces disposed in the chamber between the sidewalls, and a high-grade vacuum in the chamber that includes apparatus and methods for enabling and disabling, or turning ``on`` and ``off`` the thermal insulating capability of the panel. One type of enabling and disabling apparatus and method includes a metal hydride for releasing hydrogen gas into the chamber in response to heat, and a hydrogen grate between the metal hydride and the chamber for selectively preventing and allowing return of the hydrogen gas to the metal hydride. Another type of enabling and disabling apparatus and method includes a variable emissivity coating on the sheets of metal in which the emissivity is controllably variable by heat or electricity. Still another type of enabling and disabling apparatus and method includes metal-to-metal contact devices that can be actuated to establish or break metal-to-metal heat paths or thermal short circuits between the metal sidewalls. 25 figs.

Benson, D.K.; Potter, T.F.

1995-07-18T23:59:59.000Z

305

Radiation-controlled dynamic vacuum insulation  

DOE Patents [OSTI]

A compact vacuum insulation panel comprising a chamber enclosed by two sheets of metal, glass-like spaces disposed in the chamber between the sidewalls, and a high-grade vacuum in the chamber that includes apparatus and methods for enabling and disabling, or turning "on" and "off" the thermal insulating capability of the panel. One type of enabling and disabling apparatus and method includes a metal hydride for releasing hydrogen gas into the chamber in response to heat, and a hydrogen grate between the metal hydride and the chamber for selectively preventing and allowing return of the hydrogen gas to the metal hydride. Another type of enabling and disabling apparatus and method includes a variable emissivity coating on the sheets of metal in which the emissivity is controllably variable by heat or electricity. Still another type of enabling and disabling apparatus and method includes metal-to-metal contact devices that can be actuated to establish or break metal-to-metal heat paths or thermal short circuits between the metal sidewalls.

Benson, David K. (Golden, CO); Potter, Thomas F. (Denver, CO)

1995-01-01T23:59:59.000Z

306

Review of Current Nuclear Vacuum System Technologies  

SciTech Connect (OSTI)

Nearly all industrial operations generate unwanted dust, particulate matter, and/or liquid wastes. Waste dust and particulates can be readily tracked to other work locations, and airborne particulates can be spread through ventilation systems to all locations within a building, and even vented outside the building - a serious concern for processes involving hazardous, radioactive, or nuclear materials. Several varieties of vacuum systems have been proposed and/or are commercially available for clean up of both solid and liquid hazardous and nuclear materials. A review of current technologies highlights both the advantages and disadvantages of the various systems, and demonstrates the need for a system designed to address issues specific to hazardous and nuclear material cleanup. A review of previous and current hazardous/nuclear material cleanup technologies is presented. From simple conventional vacuums modified for use in industrial operations, to systems specifically engineered for such purposes, the advantages and disadvantages are examined in light of the following criteria: minimal worker exposure; minimal secondary waste generation;reduced equipment maintenance and consumable parts; simplicity of design, yet fully compatible with all waste types; and ease of use. The work effort reviews past, existing and proposed technologies in light of such considerations. Accomplishments of selected systems are presented, including identified areas where technological improvements could be suggested.

Carroll, M.; McCracken, J.; Shope, T.

2003-02-25T23:59:59.000Z

307

High specific surface area aerogel cryoadsorber for vacuum pumping applications  

DOE Patents [OSTI]

A cryogenic pumping system is provided, comprising a vacuum environment, an aerogel sorbent formed from a carbon aerogel disposed within the vacuum environment, and cooling means for cooling the aerogel sorbent sufficiently to adsorb molecules from the vacuum environment onto the aerogel sorbent. Embodiments of the invention include a liquid refrigerant cryosorption pump, a compressed helium cryogenic pump, a cryopanel and a Meissner coil, each of which uses carbon aerogel as a sorbent material.

Hill, Randal M. (Livermore, CA); Fought, Eric R. (Brentwood, CA); Biltoft, Peter J. (Livermore, CA)

2000-01-01T23:59:59.000Z

308

High Specific Surface area Aerogel Cryoadsorber for Vacuum Pumping Applications  

SciTech Connect (OSTI)

A cryogenic pumping system is provided, comprising a vacuum environment, an aerogel sorbent formed from a carbon aerogel disposed within the vacuum environment, and cooling means for cooling the aerogel sorbent sufficiently to adsorb molecules from the vacuum environment onto the aerogel sorbent. Embodiments of the invention include a liquid refrigerant cryosorption pump, a compressed helium cryogenic pump, a cryopanel and a Meissner coil, each of which uses carbon aerogel as a sorbent material.

Hill, Randal M.; Fought, Eric R.; Biltoft, Peter J.

1998-12-22T23:59:59.000Z

309

Gas Composition Transients in the Cold Vacuum Drying (CVD) Facility  

SciTech Connect (OSTI)

Calculations with plotted results presented as confirmation bases for selected problems involving the prediction of transient gas compositions during Cold Vacuum Drying Operations.

PACKER, M.J.

1999-07-01T23:59:59.000Z

310

Towards a regular type N vacuum gravitational field  

E-Print Network [OSTI]

An exact twisting type N vacuum solution is found. It has regular gauge and curvature invariants and decays to flat spacetime for big retarded times.

B. V. Ivanov

1999-10-21T23:59:59.000Z

311

Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation  

E-Print Network [OSTI]

Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

Plazas Garcia, Joyce Vivia

2002-01-01T23:59:59.000Z

312

Miniature piezo electric vacuum inlet valve  

DOE Patents [OSTI]

A miniature piezo electric vacuum inlet valve having a fast pulse rate and is battery operated with variable flow capability is disclosed. The low power (<1.6 watts), high pulse rate (<2 milliseconds), variable flow inlet valve is utilized for mass spectroscopic applications or other applications where pulsed or continuous flow conditions are needed. The inlet valve also has a very minimal dead volume of less than 0.01 std/cc. The valve can utilize, for example, a 12 Vdc input/750 Vdc, 3 mA output power supply compared to conventional piezo electric valves which require preloading of the crystal drive mechanism and 120 Vac, thus the valve of the present invention is smaller by a factor of three. 6 figs.

Keville, R.F.; Dietrich, D.D.

1998-03-24T23:59:59.000Z

313

Miniature piezo electric vacuum inlet valve  

DOE Patents [OSTI]

A miniature piezo electric vacuum inlet valve having a fast pulse rate and is battery operated with variable flow capability. The low power (<1.6 watts), high pulse rate (<2 milliseconds), variable flow inlet valve is utilized for mass spectroscopic applications or other applications where pulsed or continuous flow conditions are needed. The inlet valve also has a very minimal dead volume of less than 0.01 std/cc. The valve can utilize, for example, a 12 Vdc input/750 Vdc, 3 mA output power supply compared to conventional piezo electric valves which require preloading of the crystal drive mechanism and 120 Vac, thus the valve of the present invention is smaller by a factor of three.

Keville, Robert F. (Valley Springs, CA); Dietrich, Daniel D. (Livermore, CA)

1998-03-24T23:59:59.000Z

314

Vacuum (meta)stability beyond the MSSM  

SciTech Connect (OSTI)

We study the stability of the Higgs potential in the framework of the effective Lagrangian beyond the minimal supersymmetric standard model (MSSM). While the leading nonrenormalizable operators can shift the Higgs boson mass above the experimental bound, they also tend to render the scalar potential unbounded from below. The destabilization is correlated with the Higgs mass increase, so that if quantum corrections are small the problem is severe. We show that a supersymmetric subleading correction stabilizes the potential within the domain of validity of the effective theory. Constraints on MSSM parameters as well as on higher dimensional operators are derived, ensuring that our vacuum has a lifetime longer than the present age of the Universe. In addition we show that when effective operators are responsible for evading the LEP bound, stability constraints imply an upper bound on the scale of new physics in the few TeV range.

Blum, Kfir; Delaunay, Cedric; Hochberg, Yonit [Department of Particle Physics, Weizmann Institute of Science, Rehovot 76100 (Israel)

2009-10-01T23:59:59.000Z

315

Vacuum Selection on the String Landscape  

E-Print Network [OSTI]

I examine some non-anthropic approaches to the string landscape. These approaches are based on finding the initial conditions of the universe using the wavefunction of the multiverse to select the most probable vacuum out of this landscape. All approaches tackled so far seems to have their own problems and there is no clear cut alternative to anthropic reasoning. I suggest that finding the initial conditions may be irrelevant since all possible vacua on the landscape are possible initial state conditions and eternal inflation could generate all the other vacua. We are now left to reason out why we are observing the small value of the cosmological constant (CC). I address this issue in the contest of noncritical string theory in which all values of the cosmological constant on the landscape are departures from critical equilibrium state.

Edward Tetteh-Lartey

2007-05-08T23:59:59.000Z

316

Integrated vacuum absorption steam cycle gas separation  

DOE Patents [OSTI]

Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

2011-11-22T23:59:59.000Z

317

Theoretical Analysis of an Ideal Noiseless Linear Amplifier for Einstein-Podolsky-Rosen Entanglement Distillation  

E-Print Network [OSTI]

We study the operational regime of a noiseless linear amplifier based on quantum scissors that can nondeterministically amplify the one photon component of a quantum state with weak excitation. It has been shown that an arbitrarily large quantum state can be amplified by first splitting it into weak excitation states using a network of beamsplitters. The output states of the network can then be coherently recombined. In this paper, we analyse the performance of such a device for distilling entanglement after transmission through a lossy quantum channel, and look at two measures to determine the efficacy of the noiseless linear amplifier. The measures used are the amount of entanglement achievable and the final purity of the output amplified entangled state. We study the performances of both a single and a two-element noiseless linear amplifier for amplifying weakly excited states. Practically, we show that it may be advantageous to work with a limited number of stages.

J. Bernu; S. Armstrong; T. Symul; T. C. Ralph; P. K. Lam

2014-11-03T23:59:59.000Z

318

Upgrading of middle distillate fractions of syncrudes from athabasca oil sands  

SciTech Connect (OSTI)

Middle distillate fractions of syncrudes from Athabasca Oil Sands were evaluated for suitability as feedstocks in the catalytic conversion to diesel fuel meeting cetane number specifications. Hydrogenation of aromatic components to napthenes under severe conditions (380 to 400/sup 0/C, 2500 psig) using sulfided CoO/MoO/sub 3/ and NiO/WO/sub 3/ over ..cap alpha.. . Al/sub 2/O/sub 3/ in a previously described catalyst testing system. Reaction products were analyzed for aromatic carbon content using C/sup 13/ NMR spectroscopy and pseudo first order rate constants and activation energies (15.0 and 14.2 kcal 1 g-mole, respectively) were determined by regression analysis. At optimum conditions 97% aromatic conversion was obtained with the Ni-W catalyst. Product diesel fuel cetane number (42) was within specifications. Co-Mo catalyst was significantly less active.

Wilson, M.F.; Kriz, J.F.

1983-03-01T23:59:59.000Z

319

Dynamics and control of a heterogeneous azeotropic distillation column: Conventional control approach  

SciTech Connect (OSTI)

In this work, bifurcation analysis and dynamic simulation were used to investigate the optimum conventional control strategy of an isopropyl alcohol (IPA), cyclohexane (CyH), and water (H{sub 2}O) heterogeneous azeotropic column. Steady-state process analysis shows that the optimal operation point should be located at a critical reflux, a transition point at which the distillation path switches from a route that passes through the IPA + H{sub 2}O azeotrope to one that passes through the IPA + CyH azeotrope. A good control strategy must be able to maintain a steady column temperature profile that shows a plateau near 70 C to ensure passage around the IPA + CyH azeotrope. An inverse double-loop control strategy is proposed based on principal component analysis. This scheme is capable of maintaining the desired column temperature profile given all kinds of feed disturbances, thus keeping the product IPA purity at the desired level.

Chien, I.L. [National Taiwan Univ. of Science and Technology, Taipei (Taiwan, Province of China). Dept. of Chemical Engineering; Wang, C.J.; Wong, D.S.H. [National Tsing Hua Univ., Hsinchu (Taiwan, Province of China). Dept. of Chemical Engineering

1999-02-01T23:59:59.000Z

320

Re-refining of Waste Oil Solvent Is Used in Treatment/Distillation Process  

E-Print Network [OSTI]

INDUSTRIAL APPLICATION. A combination solvent treatment/distillation process has been designed for re-refining industrial waste oil (such as equipment lubricants, metal-working oil, and process oil) and used automotive lubricants (engine oil, hydraulic oil, and gear oil) for reuse. WASTE ENERGY RECOVERY. Recycling of waste oil in the United States has the potential to save the energy equivalent of 7-12 million bbl of crude oil annually.1 WASTE OIL RECOVERY. Prior to 1960, a significant portion of the demand for automotive lubricating oil was met by re-relined used oil. At the time, 150 re-refineries produced 300 million gal of motor oil annually. Since 1960, however, the production of re-refined oil has steadily declined. In 1981, for example, out of about 1.2 billion gal of automobile lubricating oil and 1.6 billion gal of industrial lubricating oils purchased, 25 U.S. rerefineries

unknown authors

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

On local indistinguishability of orthogonal pure states by using a bound on distillable entanglement  

E-Print Network [OSTI]

We show that the four states a|00>+b|11>, b^*|00>-a^*|11>, c|01>+d|10> and d^*|01>-c^*|10> cannot be discriminated with certainty if only local operations and classical communication (LOCC) are allowed and if only a single copy is provided, except in the case when they are simply |00>, |11>, |01> and |10> (in which case they are trivially distinguishable with LOCC). We go on to show that there exists a continuous range of values of a, b, c and d such that even three states among the above four are not locally distinguishable, if only a single copy is provided. The proof follows from the fact that logarithmic negativity is an upper bound of distillable entanglement.

Sibasish Ghosh; Guruprasad Kar; Anirban Roy; Debasis Sarkar; Aditi Sen De; Ujjwal Sen

2001-11-25T23:59:59.000Z

322

Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions  

SciTech Connect (OSTI)

This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

1995-03-01T23:59:59.000Z

323

Assigning a Value to Dried Distillers' Grains as a Protein Supplement in Cattle Consuming Low-Quality Forage  

E-Print Network [OSTI]

Cattle consuming low-quality forage may have decreased forage organic matter intake as a result of decreased nitrogen (N) intake. To date, a value has not been assigned to dried distillers' grains as a protein supplement to cattle consuming low...

Rambo, Zachary Joseph

2011-08-08T23:59:59.000Z

324

Vacuum Compatibility of 3D-Printed Materials  

E-Print Network [OSTI]

The fabrication fidelity and vacuum properties are tested for currently available 3D-printed materials including polyamide, glass, acrylic, and sterling silver. The silver was the only material found to be suitable to ultrahigh vacuum environments due to outgassing and sublimation observed in other materials.

Povilus, A P; Vendeiro, Z; Baquero-Ruiz, M; Fajans, J

2013-01-01T23:59:59.000Z

325

Vacuum aperture isolator for retroreflection from laser-irradiated target  

DOE Patents [OSTI]

The disclosure is directed to a vacuum aperture isolator for retroreflection of a laser-irradiated target. Within a vacuum chamber are disposed a beam focusing element, a disc having an aperture and a recollimating element. The edge of the focused beam impinges on the edge of the aperture to produce a plasma which refracts any retroreflected light from the laser's target.

Benjamin, Robert F. (Los Alamos, NM); Mitchell, Kenneth B. (Los Alamos, NM)

1980-01-01T23:59:59.000Z

326

A nonlinear prerelativistic approach to mathematical representation of vacuum electromagnetism  

E-Print Network [OSTI]

This paper presents an alternative prerelativistic approach to the vacuum case of classical electrodynamics represented by vacuum Maxwell equations. Our view is based on the understanding that the corresponding differential equations should be dynamical in nature and the physical relations represented by them should be directly verifiable at least in principle, so they must represent local energy-momentum balance relations.

Stoil Donev; Maria Tashkova

2014-02-21T23:59:59.000Z

327

Laser induced electron acceleration in vacuum K. P. Singha)  

E-Print Network [OSTI]

Laser induced electron acceleration in vacuum K. P. Singha) Department of Physics, Indian Institute acceleration by a plane polarized laser wave has been studied in vacuum. Relativistic equations of motion have been solved exactly for electron trajectory and energy as a function of laser intensity, phase

Singh, Kunwar Pal

328

LASER ACCELERATION IN VACUUM J.L. Hsu, T. Katsouleas  

E-Print Network [OSTI]

LASER ACCELERATION IN VACUUM J.L. Hsu, T. Katsouleas University of Southern California, Los Angeles electric fields of high-brightness lasers (e.g., up to order TV/cm) to accelerate particles. Unfortunately, as is well known, it is difficult to couple the vacuum field of the laser to particles so as to achieve a net

Wurtele, Jonathan

329

Highlights in these programmes are: i vacuum consolidation of thermoplastic  

E-Print Network [OSTI]

at a 180 °C and one- shot vacuum consolidation of a com- plete section of a wind turbine blade, ii of larger parts, such as wind turbine blades, autoclave consolida- tion is suitable for high performance. Vacuum consolidation of thermo- plastic composites for wind turbine blades The melt viscosity

330

Vacuum properties of sintered SmCo/sub 5/ magnets  

SciTech Connect (OSTI)

There are many desirable applications of powerful, rare-earth permanent magnets made of sintered SmCo/sub 5/ material within vacuum systems. One application is the use of large numbers of SmCo/sub 5/ magnets to provide the undulating magnetic field in a free-electron-laser wiggler structure. Tests were conducted at Los Alamos to determine the suitability of SmCo/sub 5/ magnets in a vacuum environment of approx. 10/sup -6/ torr. The vacuum performances of the wiggler system, with and without the SmCo/sub 5/ magnets (having approx. 11% of the total surface area) installed, were essentially identical. These tests indicate that SmCo/sub 5/ magnets have good vacuum properties and are suitable for use in many vacuum systems.

Warren, R.W.; DePaula, R.F.; Hansborough, L.D.

1981-12-01T23:59:59.000Z

331

The Role of Quantum Vacuum Forces in Microelectromechanical Systems  

E-Print Network [OSTI]

The presence of boundary surfaces in the vacuum alters the ground state of the quantized electromagnetic field and can lead to the appearance of vacuum forces. In the last decade, landmark measurements of the vacuum stress between conducting uncharged parallel plates (Casimir force) have been made. Recently the first micromachined MEMS (microelectromechanical system) device was fabricated that utilizes the Casimir force between parallel plates. The force dependence allows the device to serve as a highly sensitive position sensor. The are many other examples of quantum vacuum forces and effects besides the well known parallel plate Casimir force. Here we discuss potential roles of quantum vacuum forces and effects in MEMS systems and other systems. With the growing capability in nanofabrication, some of the roles may be actualized in the future. Because of the computational complexity, no theoretical results are yet available for a number of potentially interesting geometries and we can only speculate.

G. Jordan Maclay

2006-08-22T23:59:59.000Z

332

Cosmic expansion and structure formation in running vacuum cosmologies  

E-Print Network [OSTI]

We investigate the dynamics of the FLRW flat cosmological models in which the vacuum energy varies with redshift. A particularly well motivated model of this type is the so-called quantum field vacuum, in which both kind of terms $H^{2}$ and constant appear in the effective dark energy density affecting the evolution of the main cosmological functions at the background and perturbation levels. Specifically, it turns out that the functional form of the quantum vacuum endows the vacuum energy of a mild dynamical evolution which could be observed nowadays and appears as dynamical dark energy. Interestingly, the low-energy behaviour is very close to the usual $\\Lambda$CDM model, but it is by no means identical. Finally, within the framework of the quantum field vacuum we generalize the large scale structure properties, namely growth of matter perturbations, cluster number counts and spherical collapse model.

Basilakos, Spyros

2015-01-01T23:59:59.000Z

333

Hubble expansion & Structure Formation in Time Varying Vacuum Models  

E-Print Network [OSTI]

We investigate the properties of the FLRW flat cosmological models in which the vacuum energy density evolves with time, $\\Lambda(t)$. Using different versions of the $\\Lambda(t)$ model, namely quantum field vacuum, power series vacuum and power law vacuum, we find that the main cosmological functions such as the scale factor of the universe, the Hubble expansion rate $H$ and the energy densities are defined analytically. Performing a joint likelihood analysis of the recent supernovae type Ia data, the Cosmic Microwave Background (CMB) shift parameter and the Baryonic Acoustic Oscillations (BAOs) traced by the Sloan Digital Sky Survey (SDSS) galaxies, we put tight constraints on the main cosmological parameters of the $\\Lambda(t)$ scenarios. Furthermore, we study the linear matter fluctuation field and the growth rate of clustering of the above vacuum models. Finally, we derived the theoretically predicted dark-matter halo mass function and the corresponding distribution of cluster-size halos for all the models studied. Their expected redshift distribution indicates that it will be difficult to distinguish the closely resembling models (constant vacuum, quantum field and power-law vacuum), using realistic future X-ray surveys of cluster abundances. However, cluster surveys based on the Sunayev-Zeldovich detection method give some hope to distinguish the closely resembling models at high redshifts.

S. Basilakos; M. Plionis; J. Sola

2009-09-22T23:59:59.000Z

334

LTC vacuum blasting machine (metal): Baseline report  

SciTech Connect (OSTI)

The LTC coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC coating removal system consisted of several hand tools, a Roto Peen scaler, and a needlegun. They are designed to remove coatings from steel, concrete, brick, and wood. These hand tools are used with the LTC PTC-6 vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. The dust exposure was minimal but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body vibration, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

NONE

1997-07-31T23:59:59.000Z

335

Vacuum ultraviolet photoionization of carbohydrates and nucleotides  

SciTech Connect (OSTI)

Carbohydrates (2-deoxyribose, ribose, and xylose) and nucleotides (adenosine-, cytidine-, guanosine-, and uridine-5{sup ?}-monophosphate) are generated in the gas phase, and ionized with vacuum ultraviolet photons (VUV, 118.2 nm). The observed time of flight mass spectra of the carbohydrate fragmentation are similar to those observed [J.-W. Shin, F. Dong, M. Grisham, J. J. Rocca, and E. R. Bernstein, Chem. Phys. Lett. 506, 161 (2011)] for 46.9 nm photon ionization, but with more intensity in higher mass fragment ions. The tendency of carbohydrate ions to fragment extensively following ionization seemingly suggests that nucleic acids might undergo radiation damage as a result of carbohydrate, rather than nucleobase fragmentation. VUV photoionization of nucleotides (monophosphate-carbohydrate-nucleobase), however, shows that the carbohydrate-nucleobase bond is the primary fragmentation site for these species. Density functional theory (DFT) calculations indicate that the removed carbohydrate electrons by the 118.2 nm photons are associated with endocyclic C–C and C–O ring centered orbitals: loss of electron density in the ring bonds of the nascent ion can thus account for the observed fragmentation patterns following carbohydrate ionization. DFT calculations also indicate that electrons removed from nucleotides under these same conditions are associated with orbitals involved with the nucleobase-saccharide linkage electron density. The calculations give a general mechanism and explanation of the experimental results.

Shin, Joong-Won, E-mail: jshin@govst.edu [Division of Science, Governors State University, University Park, Illinois 60484-0975 (United States) [Division of Science, Governors State University, University Park, Illinois 60484-0975 (United States); Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872 (United States); Bernstein, Elliot R., E-mail: erb@lamar.colostate.edu [Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872 (United States)

2014-01-28T23:59:59.000Z

336

Project W-441, cold vacuum drying facility design requirements document  

SciTech Connect (OSTI)

This document has been prepared and is being released for Project W-441 to record the design basis for the design of the Cold Vacuum Drying Facility. This document sets forth the physical design criteria, Codes and Standards, and functional requirements that were used in the design of the Cold Vacuum Drying Facility. This document contains section 3, 4, 6, and 9 of the Cold Vacuum Drying Facility Design Requirements Document. The remaining sections will be issued at a later date. The purpose of the Facility is to dry, weld, and inspect the Multi-Canister Overpacks before transport to dry storage.

O`Neill, C.T.

1997-05-08T23:59:59.000Z

337

The spherical collapse model in time varying vacuum cosmologies  

E-Print Network [OSTI]

We investigate the virialization of cosmic structures in the framework of flat FLRW cosmological models, in which the vacuum energy density evolves with time. In particular, our analysis focuses on the study of spherical matter perturbations, as they decouple from the background expansion, "turn around" and finally collapse. We generalize the spherical collapse model in the case when the vacuum energy is a running function of the Hubble rate, $\\Lambda=\\Lambda(H)$. A particularly well motivated model of this type is the so-called quantum field vacuum, in which $\\Lambda(H)$ is a quadratic function, $\\Lambda(H)=n_0+n_2\\,H^2$, with $n_0\

S. Basilakos; M. Plionis; J. Sola

2010-09-22T23:59:59.000Z

338

Computing the hadronic vacuum polarization function by analytical continuation  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We propose a method to compute the hadronic vacuum polarization function on the lattice at continuous values of photon momenta bridging between the spacelike and timelike regions. We provide two independent demonstrations to show that this method leads to the desired hadronic vacuum polarization function in Minkowski spacetime. We show with the example of the leading-order QCD correction to the muon anomalous magnetic moment that this approach can provide a valuable alternative method for calculations of physical quantities where the hadronic vacuum polarization function enters.

Feng, Xu [KEK, Tsukuba, Japan; Hashimoto, Shoji [KEK, Tsukuba, Japan; Sokendai, Tsukuba, Japan; Hotzel, Grit [Institut fur Physik, Humboldt-Universitat zu Berlin; Jansen, Karl [DESY; University of Cyprus; Petschlies, Marcus [The Cyprus Institute; Renner, Dru B. [JLAB

2013-08-29T23:59:59.000Z

339

Vacuum fluctuations in a supersymmetric model in FRW spacetime  

SciTech Connect (OSTI)

We study a noninteracting supersymmetric model in an expanding FRW spacetime. A soft supersymmetry breaking induces a nonzero contribution to the vacuum energy density. A short distance cutoff of the order of Planck length provides a scale for the vacuum energy density comparable with the observed cosmological constant. Assuming the presence of a dark energy substance in addition to the vacuum fluctuations of the field, an effective equation of state is derived in a self-consistent approach. The effective equation of state is sensitive to the choice of the cutoff but no fine-tuning is needed.

Bilic, Neven [Rudjer Boskovic Institute, P.O. Box 180, HR-10002 Zagreb (Croatia)

2011-05-15T23:59:59.000Z

340

Highly sensitive vacuum ion pump current measurement system  

DOE Patents [OSTI]

A vacuum system comprising: 1) an ion pump; 2) power supply; 3) a high voltage DC--DC converter drawing power from the power supply and powering the vacuum pump; 4) a feedback network comprising an ammeter circuit including an operational amplifier and a series of relay controlled scaling resistors of different resistance for detecting circuit feedback; 5) an optional power block section intermediate the power supply and the high voltage DC--DC converter; and 6) a microprocessor receiving feedback information from the feedback network, controlling which of the scaling resistors should be in the circuit and manipulating data from the feedback network to provide accurate vacuum measurement to an operator.

Hansknecht, John Christopher (Williamsburg, VA)

2006-02-21T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Enhancement of vacuum polarization effects in a plasma  

E-Print Network [OSTI]

The dispersive effects of vacuum polarization on the propagation of a strong circularly polarized electromagnetic wave through a cold collisional plasma are studied analytically. It is found that, due to the singular dielectric features of the plasma, the vacuum effects on the wave propagation in a plasma are qualitatively different and much larger than those in pure vacuum in the regime when the frequency of the propagating wave approaches the plasma frequency. A possible experimental setup to detect these effects in plasma is described.

A. Di Piazza; K. Z. Hatsagortsyan; C. H. Keitel

2007-03-09T23:59:59.000Z

342

E-Print Network 3.0 - acceptance thermal vacuum Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Design 38 Nuclear htg and thermal effects Vacuum vessel is subject to two basic heat loads: - Direct... : Vacuum Vessel Design 43 VV thermal deformation and ... Source:...

343

E-Print Network 3.0 - accelerator vacuum systems Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

systems... Transfer 11 Licensing of NEG and Palladium: Vacuum Systems (12) Vacuum Pumps (Varian) Internal coating... Lines Laboratory ... Source: Council for the Central...

344

Cold Vacuum Drying (CVD) Facility Diesel Generator Fire Protection  

SciTech Connect (OSTI)

This Acceptance Test Procedure (ATP) has been prepared to demonstrate that the Fire Protection and Detection System installed by Project W-441 (Cold Vacuum Drying Facility and Diesel Generator Building) functions as required by project specifications.

SINGH, G.

2000-04-25T23:59:59.000Z

345

Hyperbolic Equations for Vacuum Gravity Using Special Orthonormal Frames  

E-Print Network [OSTI]

By adopting Nester's higher dimensional special orthonormal frames (HSOF) the tetrad equations for vacuum gravity are put into first order symmetric hyperbolic (FOSH) form with constant coefficients, independent of any time slicing or coordinate specialization.

Frank B. Estabrook; R. Steve Robinson; Hugo D. Wahlquist

2004-09-29T23:59:59.000Z

346

Design of a variable-conductance vacuum insulation  

SciTech Connect (OSTI)

This paper describes one approach to the design of a variable-conductance vacuum insulation. In this design, the vacuum insulation consists of a permanently sealed, thin sheet steel, evacuated envelope of whatever geometry is required for the application. The steel envelope is supported internally against the atmospheric pressure loads by an array of discrete, low-conductance, ceramic supports, and radiative heat transfer is blocked by layers of thin metal radiation shields. Thermal conductance through this insulation is controlled electronically by changing the temperature of a small metal hydride connected to the vacuum envelope. The hydride reversibly absorbs/desorbs hydrogen to produce a hydrogen pressure typically within the range from less than 10{sup {minus}6} to as much as 1 torr. Design calculations are compared with results from laboratory tests of bench scale samples, and some possible automotive applications for this variable-conductance vacuum insulation are suggested.

Benson, D K; Potter, T F; Tracy, C E

1994-01-01T23:59:59.000Z

347

Extreme-UV lithography vacuum chamber zone seal  

DOE Patents [OSTI]

Control of particle contamination on the reticle and carbon contamination of optical surfaces in photolithography systems can be achieved by the establishment of multiple pressure zones in the photolithography systems. The different zones will enclose the reticle, projection optics, wafer, and other components of system. The system includes a vacuum apparatus that includes: a housing defining a vacuum chamber; one or more metrology trays situated within the vacuum chamber each of which is supported by at least one support member, wherein the tray separates the vacuum chamber into a various compartments that are maintained at different pressures; and conductance seal devices for adjoining the perimeter of each tray to an inner surface of the housing wherein the tray is decoupled from vibrations emanating from the inner surface of the housing.

Haney, Steven J. (Tracy, CA); Herron, Donald Joe (Manteca, CA); Klebanoff, Leonard E. (San Ramon, CA); Replogle, William C. (Livermore, CA)

2001-01-01T23:59:59.000Z

348

Extreme-UV lithography vacuum chamber zone seal  

DOE Patents [OSTI]

Control of particle contamination on the reticle and carbon contamination of optical surfaces in photolithography systems can be achieved by the establishment of multiple pressure zones in the photolithography systems. The different zones will enclose the reticle, projection optics, wafer, and other components of system. The system includes a vacuum apparatus that includes: a housing defining a vacuum chamber; one or more metrology trays situated within the vacuum chamber each of which is supported by at least one support member, wherein the tray separates the vacuum chamber into a various compartments that are maintained at different pressures; and conductance seal devices for adjoining the perimeter of each tray to an inner surface of the housing wherein the tray is decoupled from vibrations emanating from the inner surface of the housing.

Haney, Steven J. (Tracy, CA); Herron, Donald Joe (Manteca, CA); Klebanoff, Leonard E. (San Ramon, CA); Replogle, William C. (Livermore, CA)

2003-04-08T23:59:59.000Z

349

Extreme-UV lithography vacuum chamber zone seal  

DOE Patents [OSTI]

Control of particle contamination on the reticle and carbon contamination of optical surfaces in photolithography systems can be achieved by the establishment of multiple pressure zones in the photolithography systems. The different zones will enclose the reticle, projection optics, wafer, and other components of system. The system includes a vacuum apparatus that includes: a housing defining a vacuum chamber; one or more metrology trays situated within the vacuum chamber each of which is supported by at least one support member, wherein the tray separates the vacuum chamber into a various compartments that are maintained at different pressures; and conductance seal devices for adjoining the perimeter of each tray to an inner surface of the housing wherein the tray is decoupled from vibrations emanating from the inner surface of the housing.

Haney, Steven J. (Tracy, CA); Herron, Donald Joe (Manteca, CA); Klebanoff, Leonard E. (San Ramon, CA); Replogle, William C. (Livermore, CA)

2003-04-15T23:59:59.000Z

350

Errata to "Flat Spacetime Vacuum in Loop Quantum Gravity"  

E-Print Network [OSTI]

We give the correct expressions for the spin network evaluations proposed in Class. Quant. Grav. 21 (2004) 3909 as the coefficients of the quantum gravity vacuum wavefunction in the spin network basis.

A. Mikovic

2006-06-19T23:59:59.000Z

351

Does Cosmological Vacuum Energy Density have an Electric Reason ?  

E-Print Network [OSTI]

Rather uncomplicated calculations by hand display a surprising connection between the energy density of the vacuum and the diameter and age of the universe. Among other things, the result explains the observation of the accelerated expansion of the universe.

Claus W. Turtur

2004-03-11T23:59:59.000Z

352

Improved Vacuum Frying Process for High Quality Sweet Potato Chips  

E-Print Network [OSTI]

to high temperature processing. However, in vacuum frying the product should be pre-treated before frying to obtain a better texture. The kinetics of oil absorption and oil distribution in sweet potato chips (total, internal, and surface oil content...

Ravli, Yagmur 1985-

2012-08-27T23:59:59.000Z

353

A study of micromachined displacement pumps for vacuum generation  

E-Print Network [OSTI]

Micromachined vacuum pumps are one of the key components in miniature systems for chemical and biological analysis. Miniature sensors and analyzers are normally operated at the pressure range lower than a few millitorr. ...

Zhou, Hui, Ph. D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

354

Microwave pyrolysis of distillers dried grain with solubles (DDGS) for biofuel production  

SciTech Connect (OSTI)

Microwave pyrolysis of distillers dried grain with solubles (DDGS) was investigated to determine the effects of pyrolytic conditions on the yields of bio-oil, syngas, and biochar. Pyrolysis process variables included reaction temperature, time, and power input. Microwave pyrolysis of DDGS was analyzed using response surface methodology to ?nd out the effect of process variables on the biofuel (bio-oil and syn- gas) conversion yield and establish prediction models. Bio-oil recovery was in the range of 26.5–50.3 wt.% of the biomass. Biochar yields were 23.5–62.2% depending on the pyrolysis conditions. The energy con- tent of DDGS bio-oils was 28 MJ/kg obtained at the 650 oC and 8 min, which was about 66.7% of the heat- ing value of gasoline. GC/MS analysis indicated that the biooil contained a series of important and useful chemical compounds: aliphatic and aromatic hydrocarbons. At least 13% of DDGS bio-oil was the same hydrocarbon compounds found in regular unleaded gasoline.

Lei, Hanwu; Ren, Shoujie; Wang, Lu; Bu, Quan; Julson, James; Holladay, Johnathan E.; Ruan, Roger

2011-05-01T23:59:59.000Z

355

Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review  

SciTech Connect (OSTI)

In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

Brinkman, D.W.; Whisman, M.L.

1984-11-01T23:59:59.000Z

356

Recovery of Navy distillate fuel from reclaimed product. Volume I. Technical discussion  

SciTech Connect (OSTI)

In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). The first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 referenvces and abstracts. This appendix, because of its volume, has been published separately as Volume 2. 18 figures, 4 tables.

Brinkman, D.W.; Whisman, M.L.

1984-11-01T23:59:59.000Z

357

Sealed vacuum canister and method for pick-up and containment of material  

DOE Patents [OSTI]

A vacuum canister is described including a housing with a sealed vacuum chamber having a predetermined vacuum pressure therein and a valve having a first port for fluid communication with the vacuum chamber and a second port for receiving at least one of a fluid and a particulate material. The valve is operable between a first position to seal the vacuum chamber and retain the predetermined vacuum within the vacuum chamber, and a second position to access the vacuum chamber to permit vacuum fluid flow through the valve from the second port into the vacuum chamber. The vacuum canister, in the operation to pick up material with the valve in the second position, when the second port is located adjacent at least one of a fluid and a particulate material, is effective to displace through the valve at least one of a fluid and a particulate material into the housing. The vacuum canister is desirably suitable for picking up and containing hazardous material such as radioactive material, in which the vacuum canister includes a protective layer of lead having a predetermined thickness that is effective to shield radiation emitted from the radioactive material contained within the housing. Advantageously, the vacuum canister includes a vacuum means for establishing a predetermined vacuum pressure within the vacuum chamber. 6 figs.

Stoutenburgh, R.R.

1996-02-13T23:59:59.000Z

358

Vacuum high harmonic generation in the shock regime  

E-Print Network [OSTI]

Electrodynamics becomes nonlinear and permits the self-interaction of fields when the quantised nature of vacuum states is taken into account. The effect on a plane probe pulse propagating through a stronger constant crossed background is calculated using numerical simulation and by analytically solving the corresponding wave equation. The electromagnetic shock resulting from vacuum high harmonic generation is investigated and a nonlinear shock parameter identified.

Böhl, P; Ruhl, H

2015-01-01T23:59:59.000Z

359

Model of the Stochastic Vacuum and QCD Parameters  

E-Print Network [OSTI]

Accounting for the two independent correlation functions of the QCD vacuum, we improve the simple and consistent description given by the model of the stochastic vacuum to the high-energy pp and pbar-p data, with a new determination of parameters of non-perturbative QCD. The increase of the hadronic radii with the energy accounts for the energy dependence of the observables.

Erasmo Ferreira; Flávio Pereira

1997-05-09T23:59:59.000Z

360

Instrument for measurement of vacuum in sealed thin wall packets  

DOE Patents [OSTI]

An instrument is described for the measurement of vacuum within sealed packets, the packets having a wall sufficiently thin that it can be deformed by the application of an external vacuum to small area thereof. The instrument has a detector head for placement against the deformable wall of the packet to apply the vacuum in a controlled manner to accomplish a limited deformation or lift of the wall, with this deformation or lift monitored by the application of light as via a bifurcated light pipe. Retro-reflected light through the light pipe is monitored with a photo detector. An abrupt change (e.g., a decrease) of retro-reflected light signals the wall movement such that the value of the vacuum applied through the head to achieve this initiation of movement is equal to the vacuum within the packet. In a preferred embodiment a vacuum reference plate is placed beneath the packet to ensure that no deformation occurs on the reverse surface of the packet. A packet production line model is also described. 3 figures.

Kollie, T.G.; Thacker, L.H.; Fine, H.A.

1993-10-05T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Vacuum system of the cyclotrons in VECC, Kolkata  

SciTech Connect (OSTI)

The vacuum system of the K=130 Room Temperature Cyclotron (RTC) (operational since 1978) has been recently modernized and the same of the K{sub bend}=520 Superconducting Cyclotron (SCC), currently under commissioning, is being deployed for remote monitoring and control. The vacuum system of RTC is designed to achieve and maintain vacuum level of 2 X 10{sup -6} mbar inside 23 m{sup 3} volume of Resonator tank and DEE tank. This has been upgraded by replacing several valves, Freon units, gauges and pumps. The relay based manual control system has been replaced by PLC based automated system. The SCC vacuum system also has an elaborate arrangement comprising of turbo molecular pumping modules with associated isolation valves and characteristic gauges. This paper describes essential elements, typically used to obtain high (1X10{sup -7} mbar) vacuum using rotary pumps, diffusion pumps and cold traps/turbo-molecular pumps and other system components such as valves, gauges and baffles. The supervisory control methodology/scheme of both the vacuum systems, developed in-house using EPICS (Experimental Physics and Industrial Control System), a standard open-source software tool for designing distributed control system, is also elaborated here. (author)

Roy, Anindya; Bhole, R.B.; Akhtar, J.; Yadav, R.C.; Pal, Sarbajit; Sarkar, D.; Bhandari, R.K., E-mail: r_ani@vecc.gov.in, E-mail: rbb@vecc.gov.in, E-mail: javed@vecc.gov.in, E-mail: yadav@vecc.gov.in, E-mail: sarbajit@vecc.gov.in, E-mail: dsarkar@vecc.gov.in, E-mail: bhandari@vecc.gov.in [Variable Energy Cyclotron Centre, Kolkata (India)

2011-07-01T23:59:59.000Z

362

Failure Modes of Vacuum Plasma Spray Tungsten Coating Created on Carbon Fibre Composites under Thermal Loads  

E-Print Network [OSTI]

Failure Modes of Vacuum Plasma Spray Tungsten Coating Created on Carbon Fibre Composites under Thermal Loads

363

Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.  

SciTech Connect (OSTI)

Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

Arora, S.; Wu, M.; Wang, M.; Energy Systems

2011-02-01T23:59:59.000Z

364

Naphthenic lube oils  

SciTech Connect (OSTI)

A process is disclosed for increasing the volume of lubricating oil base stocks recovered from a crude oil. A fraction having an atmospheric boiling range of about 675/sup 0/ to 1100/sup 0/ F. is recovered by vacuum distillation. This fraction is treated with furfural to extract a hydrocarbon mixture containing at least 50 volume % aromatic hydrocarbons. The raffinate is a lubricating oil base stock very high in paraffinic hydrocarbons and low in naphthenic hydrocarbons. The fraction extracted by the furfural contains at least about 50 volume % aromatic hydrocarbons and less than about 10 volume % paraffinic hydrocarbons. The mixture is hydrotreated to hydrogenate a substantial portion of the aromatic hydrocarbons. The hydrotreated product then is catalytically dewaxed. After removal of low boiling components, the finished lubricating oil base stock has a viscosity of at least about 200 SUS at 100/sup 0/ F., a pour point of less than 20/sup 0/ F. and contains at least 50 volume % of naphthenic hydrocarbons, a maximum of about 40 volume % aromatic hydrocarbons, and a maximum of about 10 volume % paraffinic hydrocarbons.

Hettinger Jr., W. P.; Beck, H. W.; Rozman, G. J.; Turrill, F. H.

1985-05-07T23:59:59.000Z

365

LTC vacuum blasting machine (metal): Baseline report; Summary  

SciTech Connect (OSTI)

The LTC coating removal system consists of several hand tools such as a Roto Peen scaler and a needlegun. They are designed to remove coatings from steel, concrete, brick, and wood. These are used with the LTC PTC-6 vacuum system to capture dust and debris as removal of the coating takes place. The PTC-6 is a vacuum system designed to be used with surface decontamination equipment. Dust and debris are captured by a high efficiency particulate filter (HEPA) vacuum system that deposits the waste directly into an on-board 23-gallon waste drum. The PTC-6 utilizes compressed air delivered from a source via an air hose connected to the air inlet to drive the hand held power tools. The control panel regulated the air pressure delivered to the tool. A separate compressed air flow powers the vacuum generator. The vacuum hoses connect the power tools to the dust chamber, returning paint chips and dust from the surface. A third compressed air flow is used to clean filters by pulsing air through a pipe with slots. The blasts of air shake dust and debris from the filter fabric.

NONE

1997-07-31T23:59:59.000Z

366

The New Control System for the Vacuum of ISOLDE  

E-Print Network [OSTI]

The On-Line Isotope Mass Separator (ISOLDE) is a facility dedicated to the production of radioactive ion beams for nuclear and atomic physics. From ISOLDE vacuum sectors to the pressurized exhaust gas storage tanks there are up to five stages of pumping for a total of more than one hundred pumps including turbo-molecular, cryogenic, dry, membrane and oil pumps. The ISOLDE vacuum control system is critical; the volatile radioactive elements present in the exhaust gases and the high and ultra high vacuum pressure specifications require a complex control and interlock system. This paper describes the reengineering of the control system developed using the CERN UNICOS-CPC framework. An additional challenge has been the usage of the UNICOS-CPC in a vacuum domain for the first time. The process automation provides multiple operating modes (rough pumping, bake-out, high vacuum pumping, regeneration for cryo-pumped sectors, venting, etc). The control system is composed of local controllers driven by...

Blanchard, S; Bernard, FB; Blanco, E; Gomes, P; Vestergard, H; Willeman, D

2011-01-01T23:59:59.000Z

367

Decaying Vacuum Inflationary Cosmologies: A Complete Scenario Including Curvature Effects  

E-Print Network [OSTI]

We propose a large class of nonsingular cosmologies of arbitrary spatial curvature whose cosmic history is determined by a primeval dynamical $\\Lambda (t)$-term. For all values of the curvature, the models evolve between two extreme de Sitter phases driven by the relic time-varying vacuum energy density. The transition from inflation to the radiation phase is universal and points to a natural solution of the graceful exit problem regardless of the values of the curvature parameter. The flat case recovers the scenario recently discussed in the literature (Perico et al., Phys. Rev. D88, 063531, 2013). The early de Sitter phase is characterized by an arbitrary energy scale $H_I$ associated to the primeval vacuum energy density. If $H_I$ is fixed to be nearly the Planck scale, the ratio between the relic and the present observed vacuum energy density is $\\rho_{vI}/\\rho_{v0} \\simeq 10^{123}$.

Lima, J A S; Zilioti, G J M

2015-01-01T23:59:59.000Z

368

In-Vacuum Active Electronics for Microfabricated Ion Traps  

E-Print Network [OSTI]

The advent of microfabricated ion traps for the quantum information community has allowed research groups to build traps that incorporate an unprecedented number of trapping zones. However, as device complexity has grown, the number of digital-to-analog converter (DAC) channels needed to control these devices has grown as well, with some of the largest trap assemblies now requiring nearly one hundred DAC channels. Providing electrical connections for these channels into a vacuum chamber can be bulky and difficult to scale beyond the current numbers of trap electrodes. This paper reports on the development and testing of an in-vacuum DAC system that uses only 9 vacuum feedthrough connections to control a 78-electrode microfabricated ion trap. The system is characterized by trapping single and multiple $^{40}$Ca$^+$ ions. The measured axial mode stability, ion heating rates, and transport fidelities for a trapped ion are comparable to systems with external(air-side) commercial DACs.

Nicholas D. Guise; Spencer D. Fallek; Harley Hayden; C-S Pai; Curtis Volin; K. R. Brown; J. True Merrill; Alexa W. Harter; Jason M. Amini; Lisa M. Lust; Kelly Muldoon; Doug Carlson; Jerry Budach

2014-06-02T23:59:59.000Z

369

Spent nuclear fuel project cold vacuum drying facility operations manual  

SciTech Connect (OSTI)

This document provides the Operations Manual for the Cold Vacuum Drying Facility (CVDF). The Manual was developed in conjunction with HNF-SD-SNF-SAR-002, Safety Analysis Report for the Cold Vacuum Drying Facility, Phase 2, Supporting Installation of Processing Systems (Garvin 1998) and, the HNF-SD-SNF-DRD-002, 1997, Cold Vacuum Drying Facility Design Requirements, Rev. 3a. The Operations Manual contains general descriptions of all the process, safety and facility systems in the CVDF, a general CVD operations sequence, and has been developed for the SNFP Operations Organization and shall be updated, expanded, and revised in accordance with future design, construction and startup phases of the CVDF until the CVDF final ORR is approved.

IRWIN, J.J.

1999-05-12T23:59:59.000Z

370

Electron Matter Wave Interferences at High Vacuum Pressures  

E-Print Network [OSTI]

The ability to trap and guide coherent electrons is gaining importance in fundamental as well as in applied physics. In this regard novel quantum devices are currently developed that may operate under low vacuum conditions. Here we study the loss of electron coherence with increasing background gas pressure. Thereby optionally helium, hydrogen or nitrogen is introduced in a biprism interferometer where the interference contrast is a measure for the coherence of the electrons. The results indicate a constant contrast that is not decreasing in the examined pressure range between $10^{-9}$ mbar and $10^{-4}$ mbar. Therefore no decoherence was observed even under poor vacuum conditions. Due to scattering of the electron beam with background H$_2$-molecules a signal loss of 94 % was determined. The results may lower the vacuum requirements for novel quantum devices with free coherent electrons.

Schütz, Georg; Pooch, Andreas; Stibor, Alexander

2015-01-01T23:59:59.000Z

371

Chirped pulse inverse free-electron laser vacuum accelerator  

DOE Patents [OSTI]

A chirped pulse inverse free-electron laser (IFEL) vacuum accelerator for high gradient laser acceleration in vacuum. By the use of an ultrashort (femtosecond), ultrahigh intensity chirped laser pulse both the IFEL interaction bandwidth and accelerating gradient are increased, thus yielding large gains in a compact system. In addition, the IFEL resonance condition can be maintained throughout the interaction region by using a chirped drive laser wave. In addition, diffraction can be alleviated by taking advantage of the laser optical bandwidth with negative dispersion focusing optics to produce a chromatic line focus. The combination of these features results in a compact, efficient vacuum laser accelerator which finds many applications including high energy physics, compact table-top laser accelerator for medical imaging and therapy, material science, and basic physics.

Hartemann, Frederic V. (Dublin, CA); Baldis, Hector A. (Pleasanton, CA); Landahl, Eric C. (Walnut Creek, CA)

2002-01-01T23:59:59.000Z

372

Advanced Space Propulsion Based on Vacuum (Spacetime Metric) Engineering  

E-Print Network [OSTI]

A theme that has come to the fore in advanced planning for long-range space exploration is the concept that empty space itself (the quantum vacuum, or spacetime metric) might be engineered so as to provide energy/thrust for future space vehicles. Although far-reaching, such a proposal is solidly grounded in modern physical theory, and therefore the possibility that matter/vacuum interactions might be engineered for space-flight applications is not a priori ruled out. As examples, the current development of theoretical physics addresses such topics as warp drives, traversable wormholes and time machines that provide for such vacuum engineering possibilities. We provide here from a broad perspective the physics and correlates/consequences of the engineering of the spacetime metric.

Puthoff, Harold E

2012-01-01T23:59:59.000Z

373

HOM Sensitivity in the PEP-II HER Vacuum Chamber  

SciTech Connect (OSTI)

Synchrotron radiation is the main source of vacuum chamber heating in the PEP-II storage ring collider. This heating is reduced substantially as lattice energy is lowered. Energy scans over {Upsilon} energy states were performed by varying the high energy ring (HER) lattice energy at constant gap voltage and frequency. We observed unexpected temperature rise at particular locations when HER lattice energy was lowered from 8.6 GeV ({Upsilon}(3S)) to 8.0 GeV ({Upsilon}(2S)) while most other temperatures decreased. Bunch length measurements reveal a shorter bunch at the lower energy. The shortened bunch overheated a beam position monitoring electrode causing a vacuum breach. We explain the unexpected heating as a consequence of increased higher order mode (HOM) power generated by a shortened bunch. In this case, temperature rise helps to identify HOM sources and HOM sensitive vacuum chamber elements. Reduction of gap voltage helps to reduce this unexpected heating.

Weathersby, Stephen; Novokhatski, Alexander; Sullivan, Mike; /SLAC

2010-02-10T23:59:59.000Z

374

Spherically symmetric static spacetimes in vacuum f(T) gravity  

SciTech Connect (OSTI)

We show that Schwarzschild geometry remains as a vacuum solution for those four-dimensional f(T) gravitational theories behaving as ultraviolet deformations of general relativity. In the gentler context of three-dimensional gravity, we also find that the infrared-deformed f(T) gravities, like the ones used to describe the late cosmic speed up of the Universe, have as the circularly symmetric vacuum solution a Deser-de Sitter or a Banados, Teitelboim and Zanelli-like spacetime with an effective cosmological constant depending on the infrared scale present in the function f(T).

Ferraro, Rafael [Instituto de Astronomia y Fisica del Espacio, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina); Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon I, 1428 Buenos Aires (Argentina); Fiorini, Franco [Instituto de Astronomia y Fisica del Espacio, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina)

2011-10-15T23:59:59.000Z

375

On the vacuum energy of a spherical plasma shell  

E-Print Network [OSTI]

We consider the vacuum energy of the electromagnetic field interacting with a spherical plasma shell together with a model for the classical motion of the shell. We calculate the heat kernel coefficients, especially that for the TM mode, and carry out the renormalization by redefining the parameters of the classical model. It turns out that this is possible and results in a model, which in the limit of the plasma shell becoming an ideal conductor reproduces the vacuum energy found by Boyer in 1968.

M. Bordag; N. Khusnutdinov

2008-01-14T23:59:59.000Z

376

Pulsed particle beam vacuum-to-air interface  

DOE Patents [OSTI]

A vacuum-to-air interface is provided for a high-powered, pulsed particle beam accelerator. The interface comprises a pneumatic high speed gate valve, from which extends a vacuum-tight duct, that terminates in an aperture. Means are provided for periodically advancing a foil strip across the aperture at the repetition rate of the particle pulses. A pneumatically operated hollow sealing band urges foil strip, when stationary, against and into the aperture. Gas pressure means periodically lift off and separate foil strip from aperture, so that it may be readily advanced. 5 figs.

Cruz, G.E.; Edwards, W.F.

1987-06-18T23:59:59.000Z

377

Ultra high vacuum broad band high power microwave window  

DOE Patents [OSTI]

An improved high vacuum microwave window has been developed that utilizes high density polyethylene coated on two sides with SiOx, SiNx, or a combination of the two. The resultant low dielectric and low loss tangent window creates a low outgassing, low permeation seal through which broad band, high power microwave energy may be passed. No matching device is necessary and the sealing technique is simple. The features of the window are broad band transmission, ultra-high vacuum compatibility with a simple sealing technique, low voltage standing wave ratio, high power transmission and low cost.

Nguyen-Tuong, Viet (Seaford, VA); Dylla, III, Henry Frederick (Yorktown, VA)

1997-01-01T23:59:59.000Z

378

Ultra high vacuum broad band high power microwave window  

DOE Patents [OSTI]

An improved high vacuum microwave window has been developed that utilizes high density polyethylene coated on two sides with SiOx, SiNx, or a combination of the two. The resultant low dielectric and low loss tangent window creates a low outgassing, low permeation seal through which broad band, high power microwave energy may be passed. No matching device is necessary and the sealing technique is simple. The features of the window are broad band transmission, ultra-high vacuum compatibility with a simple sealing technique, low voltage standing wave ratio, high power transmission and low cost. 5 figs.

Nguyen-Tuong, V.; Dylla, H.F. III

1997-11-04T23:59:59.000Z

379

The Quantum Vacuum and the Cosmological Constant Problem  

E-Print Network [OSTI]

The cosmological constant problem arises at the intersection between general relativity and quantum field theory, and is regarded as a fundamental problem in modern physics. In this paper we describe the historical and conceptual origin of the cosmological constant problem which is intimately connected to the vacuum concept in quantum field theory. We critically discuss how the problem rests on the notion of physical real vacuum energy, and which relations between general relativity and quantum field theory are assumed in order to make the problem well-defined.

Svend Erik Rugh; Henrik Zinkernagel

2000-12-28T23:59:59.000Z

380

The Quantum Vacuum and the Cosmological Constant Problem  

E-Print Network [OSTI]

The cosmological constant problem arises at the intersection between general relativity and quantum field theory, and is regarded as a fundamental problem in modern physics. In this paper we describe the historical and conceptual origin of the cosmological constant problem which is intimately connected to the vacuum concept in quantum field theory. We critically discuss how the problem rests on the notion of physical real vacuum energy, and which relations between general relativity and quantum field theory are assumed in order to make the problem well-defined.

Rugh, S E; Rugh, Svend Erik; Zinkernagel, Henrik

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

A phase transition model for metric fluctuations in vacuum  

E-Print Network [OSTI]

Regarding metric fluctuations as generating {\\it roughness} on the fabric of the otherwise smooth vacuum, it is shown that in its simplest form, the effect can be described by the scalar $\\phi^4$ model. The model exhibits a second order phase transition between a smooth (low-temperature) phase and a rough (high-temperature) one, corroborating the absence of metric fluctuations at low energies. In the rough phase near the critical point, vacuum is characterized by a power-law behavior for the fluctuating field with critical exponent $\\beta \\approx 0.33$.

M. Mehrafarin

2002-05-30T23:59:59.000Z

382

Vacuum fusion bonded glass plates having microstructures thereon  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

383

Fire Hazard Analysis for the Cold Vacuum Drying (CVD) Facility  

SciTech Connect (OSTI)

This Fire Hazard Analysis assesses the risk from fire within individual fire areas in the Cold Vacuum Drying Facility at the Hanford Site in relation to existing or proposed fire protection features to ascertain whether the objectives of DOE Order 5480.7A Fire Protection are met.

JOHNSON, B.H.

1999-08-19T23:59:59.000Z

384

Vacuum condensates, flavor mixing and spontaneous supersymmetry breaking  

E-Print Network [OSTI]

Spontaneous supersymmetry (SUSY) breaking is revealed in all phenomena in which vacuum condensates are physically relevant. The dynamical breakdown of SUSY is generated by the condensates themselves, which lift the zero point energy. Evidence is presented in the case of the Wess-Zuimino model, and the flavor mixing case is treated in detail.

Antonio Capolupo; Marco Di Mauro

2013-01-05T23:59:59.000Z

385

MFR PAPER 1151 Vacuum Cooling and Thawing Fishery Products  

E-Print Network [OSTI]

that water will boil or steam condense at a lower temperature under vacuum conditions, but also to pro- mote a rapid evaporation of water from the surface ofthe fish. Since heat energy is required. This added water can, by dehydrocooling, freeze onto the surface of the fish. Thus, without the use of ice

386

Ultrahigh vacuum focused ion beam micromill and articles therefrom  

DOE Patents [OSTI]

An ultrahigh vacuum focused ion beam micromilling apparatus and process are disclosed. Additionally, a durable data storage medium using the micromilling process is disclosed, the durable data storage medium capable of storing, e.g., digital or alphanumeric characters as well as graphical shapes or characters. 6 figs.

Lamartine, B.C.; Stutz, R.A.

1998-02-24T23:59:59.000Z

387

Ultrahigh vacuum focused ion beam micromill and articles therefrom  

DOE Patents [OSTI]

An ultrahigh vacuum focused ion beam micromilling apparatus and process are isclosed. Additionally, a durable data storage medium using the micromilling process is disclosed, the durable data storage medium capable of storing, e.g., digital or alphanumeric characters as well as graphical shapes or characters.

Lamartine, Bruce C. (Los Alamos, NM); Stutz, Roger A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

388

Varying vacuum energy of a self-interacting scalar field  

E-Print Network [OSTI]

Understanding mechanisms capable of altering the vacuum energy is currently of interest in field theories and cosmology. We consider an interacting field and show that the vacuum energy naturally takes any value between its maximum and zero because interaction affects the number of operating field modes, the assertion that involves no assumptions or postulates. The mechanism is similar to the recently discussed temperature evolution of collective modes in liquids. The cosmological implication concerns the evolution of field $\\phi$ during the inflation of the Universe. $\\phi$ starts with all field modes operating and maximal vacuum energy in the early inflation-dominated epoch. As a result of inflation, $\\phi$ undergoes a dynamic crossover and arrives in the state with one long-wavelength longitudinal mode and small positive vacuum energy predicted to be asymptotically decreasing to zero in the late epoch. Accordingly, we predict that the currently observed cosmological constant will decrease in the future. We comment on the possibility of a cyclic Universe in this picture.

Kostya Trachenko

2015-01-23T23:59:59.000Z

389

Vacuum polarization induced by a uniformly accelerated charge  

E-Print Network [OSTI]

We consider a point charge fixed in the Rindler coordinates which describe a uniformly accelerated frame. We determine an integral expression of the induced charge density due to the vacuum polarization at the first order in the fine structure constant. In the case where the acceleration is weak, we give explicitly the induced electrostatic potential.

B. Linet

1995-03-30T23:59:59.000Z

390

Cold Vacuum Drying Facility Stack Air Sampling System Qualification Tests  

SciTech Connect (OSTI)

This report documents tests that were conducted to verify that the air monitoring system for the Cold Vacuum Drying Facility ventilation exhaust stack meets the applicable regulatory criteria regarding the placement of the air sampling probe, sample transport, and stack flow measurement accuracy.

Glissmeyer, John A.

2001-01-24T23:59:59.000Z

391

Vacuum Stability in two-Higgs doublet models  

E-Print Network [OSTI]

In this work we review the status of tree-level vacuum stability in general two-Higgs doublet models. We also discuss the problem of Normal minima in some classes of potentials. In some of these potentials, Normal minima can coexist leading to potentially dangerous physic scenarios as, for instance, a two step spontaneous symmetry breaking.

Nuno Barros e Sa; Augusto Barroso; Pedro Ferreira; Rui Santos

2009-09-04T23:59:59.000Z

392

Cold Vacuum Drying (CVD) Electrical System Design Description  

SciTech Connect (OSTI)

This document provides a technical explanation of the design and operation of the electrical system for the Cold Vacuum Drying Facility. This document identifies the requirements, and the basis for the requirements and details on how the requirements have been implemented in the design and construction of the facility. This document also provides general guidance for the surveillance, testing, and maintenance of this system.

BRISBIN, S.A.

1999-06-17T23:59:59.000Z

393

Vacuum compatible, high-speed, 2-D mirror tilt stage  

DOE Patents [OSTI]

A compact and vacuum compatible magnetic-coil driven tiltable stage that is equipped with a high efficiency reflective coating can be employed as a scanner in EUV applications. The drive electronics for the scanner is fully in situ programmable and rapidly switchable.

Denham; Paul E. (Crockett, CA)

2007-09-25T23:59:59.000Z

394

Design package for vacuum wand for fuel retrieval system  

SciTech Connect (OSTI)

This is a design package that contains the details for the design, fabrication, and testing of a vacuum wand that will pick up sludge and corrosion products generated during fuel assembly handling operations at K-Basin. This document contains requirements, development design information, design calculations, tests, and test reports.

ROACH, H.L.

1999-07-28T23:59:59.000Z

395

Quantum Gravity, Dynamical Energy-Momentum Space and Vacuum Energy  

E-Print Network [OSTI]

We argue that the combination of the principles of quantum theory and general relativity allow for a dynamical energy-momentum space. We discuss the freezing of vacuum energy in such a dynamical energy-momentum space and present a phenomenologically viable seesaw formula for the cosmological constant in this context.

Lay Nam Chang; Djordje Minic; Tatsu Takeuchi

2010-04-23T23:59:59.000Z

396

Vacuum stability of asymptotically safe gauge-Yukawa theories  

E-Print Network [OSTI]

We study the phase diagram and the stability of the ground state for certain four-dimensional gauge-Yukawa theories whose high-energy behaviour is controlled by an interacting fixed point. We also provide analytical and numerical results for running couplings, their crossover scales, the separatrix, and the Coleman-Weinberg effective potential. Classical and quantum stability of the vacuum is established.

Litim, Daniel F; Sannino, Francesco

2015-01-01T23:59:59.000Z

397

Vacuum quantum fluctuation energy in expanding universe and dark energy  

E-Print Network [OSTI]

This article is based on the Planckon densely piled vacuum model and the principle of cosmology. With the Planck era as initial conditions and including the early inflation, we have solved the Einstein-Friedmann equations to describe the evolution of the universe. The results are: 1) the ratio of the dark energy density to the vacuum quantum fluctuation energy density is $\\frac{{{\\rho }_{de}}}{{{\\rho }_{vac}}}\\sim{{(\\frac{{{t}_{P}}}{{{T}_{0}}})}^{2}}\\sim{{10}^{-122}} $; 2) at the inflation time ${{t}_{\\inf }}={{10}^{-35}}s$, the calculated universe radiation energy density is $\\rho ({{t}_{\\inf }})\\sim{{10}^{-16}}{{\\rho }_{vac}}$ and the corresponding temperature is ${{E}_{c}}\\sim{{10}^{15}}GeV$ consistent with the GUT phase transition temperature; 3) the expanding universe with vacuum as its environment is a non-equilibrium open system constantly exchanging energy with vacuum; during its expansion, the Planckons in the universe lose quantum fluctuation energy and create the cosmic expansion quanta-cosmons, the energy of cosmons is the lost part of the vacuum quantum fluctuation energy and contributes to the universe energy with the calculated value ${{E}_{\\cos mos}}={{10}^{22}}{{M}_{\\otimes }}{{c}^{2}}$ (where ${{M}_{\\otimes }}$ is solar mass); 4) the total energy of the universe, namely the negative gravity energy plus the positive universe energy is zero; 5) the negative gravity potential and the gravity acceleration related to the creation of cosmons are derived with the nature of outward repulsive force, indicating that the cosmon may be the candidate of the dark energy quantum; 6) both the initial Planck era solution and the infinite asymptotic solution of the Einstein-Friedman equations are unstable: the former tends to expand and the latter tends to shrink, so that the Einstein-Friedman universe will undergo a cyclic evolution of successive expansion and shrinking.

Shun-Jin Wang

2014-10-27T23:59:59.000Z

398

The effect of degree of vacuum on the physical and organoleptic properties of vacuum packaged beef wholesale cuts  

E-Print Network [OSTI]

, oxygenation is rapid immediately after open'ng the package (Cutaia and Ordal, 1964). Rikert et al. (1957) reported that for meat stored under a vacuum of 20 in, or mox'e ~ both initial loss of redness and zeturn of redness were more rapid than...

Seideman, Steven Charles

2012-06-07T23:59:59.000Z

399

SciTech Connect: A recording linear-response gage for vacuum...  

Office of Scientific and Technical Information (OSTI)

A recording linear-response gage for vacuum fusion analyses Citation Details In-Document Search Title: A recording linear-response gage for vacuum fusion analyses Application data,...

400

Mass dependence of the vacuum energy density in the massive Schwinger model  

E-Print Network [OSTI]

The vacuum energy density of the massive Schwinger model is shown to be not power expandable in the fermion mass.

Taekoon Lee

2007-03-09T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes  

SciTech Connect (OSTI)

Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2(53:35:12). And for an H2O2 distillation process, the two promising fluids are Trifluoroethanol (TFE) + Triethylene Glycol Dimethyl ether (DMETEG) and Ammonia+ Water. Thermo-physical properties calculated by Aspen+ are reasonably accurate. Documentation of the installation of pilot-plants or full commercial units were not found in the literature for validating thermo-physical properties in an operating unit. Therefore, it is essential to install a pilot-scale unit to verify thermo-physical properties of working fluid pairs and validate the overall efficiency of the thermal heat pump at temperatures typical of distillation processes. For an HO2 process, the ammonia-water heat pump system is more compact and preferable than the TFE-DMETEG heat pump. The ammonia-water heat pump is therefore recommended for the H2O2 process. Based on the complex nature of the heat recovery system, we anticipated that capital costs could make investments financially unattractive where steam costs are low, especially where co-generation is involved. We believe that the enhanced heat transfer equipment has the potential to significantly improve the performance of TEE crystallizers, independent of the absorption heat-pump recovery system. Where steam costs are high, more detailed design/cost engineering will be required to verify the economic viability of the technology. Due to the long payback period estimated for the TEE open system, further studies on the TEE system are not warranted unless there are significant future improvements to heat pump technology. For the H2O2 distillation cycle heat pump waste heat recovery system, there were no significant process constraints and the estimated 5 years payback period is encouraging. We therefore recommend further developments of application of the thermal heat pump in the H2O2 distillation process with the focus on the technical and economic viability of heat exchangers equipped with the state-of-the-art enhancements. This will require additional funding for a prototype unit to validate enhanced thermal performances of heat transfer equipment, evaluat

Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

2012-12-03T23:59:59.000Z

402

Electrospray Emitters For Diffusion Vacuum Pumps Pablo Diaz Gomez Maqueo, Paulo C. Lozano  

E-Print Network [OSTI]

Electrospray Emitters For Diffusion Vacuum Pumps Pablo Diaz Gomez Maqueo, Paulo C. Lozano June 2011 SSL # 12-11 #12;#12;Electrospray Emitters For Diffusion Vacuum Pumps Pablo Diaz Gomez Maqueo, Paulo C;Electrospray Emitters For Diffusion Vacuum Pumps by Pablo Diaz Gomez Maqueo Submitted to the Department

403

American Institute of Aeronautics and Astronautics The Optimum Vacuum Nozzle: an MDO Approach  

E-Print Network [OSTI]

designing a vacuum nozzle, key trades exist in deciding upon the physical dimensions. A larger area ratioAmerican Institute of Aeronautics and Astronautics 122807 1 The Optimum Vacuum Nozzle: an MDO) methodology for the design of vacuum nozzles is presented, based on the maximization of the total stage

Alonso, Juan J.

404

Distillation of Bose-Einstein Condensates in a Double-Well Potential Y. Shin, M. Saba, A. Schirotzek, T. A. Pasquini, A. E. Leanhardt, D. E. Pritchard, and W. Ketterle*  

E-Print Network [OSTI]

Distillation of Bose-Einstein Condensates in a Double-Well Potential Y. Shin, M. Saba, A-Einstein condensates of sodium atoms, prepared in an optical dipole trap, were distilled into a second empty dipole the potential barrier separating the two wells and then forming a new condensate. This process serves as a model

405

Vacuum chamber with a supersonic-flow aerodynamic window  

DOE Patents [OSTI]

A supersonic flow aerodynamic window is disclosed whereby a steam ejector situated in a primary chamber at vacuum exhausts superheated steam toward an orifice to a region of higher pressure, creating a barrier to the gas in the region of higher pressure which attempts to enter through the orifice. In a mixing chamber outside and in fluid communication with the primary chamber, superheated steam and gas are combined into a mixture which then enters the primary chamber through the orifice. At the point of impact of the ejector/superheated steam and the incoming gas/superheated steam mixture, a barrier is created to the gas attempting to enter the ejector chamber. This barrier, coupled with suitable vacuum pumping means and cooling means, serves to keep the steam ejector and primary chamber at a negative pressure, even though the primary chamber has an orifice to a region of higher pressure.

Hanson, C.L.

1980-10-14T23:59:59.000Z

406

Vacuum chamber with a supersonic flow aerodynamic window  

DOE Patents [OSTI]

A supersonic flow aerodynamic window, whereby a steam ejector situated in a primary chamber at vacuum exhausts superheated steam toward an orifice to a region of higher pressure, creating a barrier to the gas in the region of higher pressure which attempts to enter through the orifice. In a mixing chamber outside and in fluid communication with the primary chamber, superheated steam and gas are combined into a mixture which then enters the primary chamber through the orifice. At the point of impact of the ejector/superheated steam and the incoming gas/superheated steam mixture, a barrier is created to the gas attempting to enter the ejector chamber. This barrier, coupled with suitable vacuum pumping means and cooling means, serves to keep the steam ejector and primary chamber at a negative pressure, even though the primary chamber has an orifice to a region of higher pressure.

Hanson, Clark L. (Livermore, CA)

1982-01-01T23:59:59.000Z

407

Vacuum Stability and Triviality Analyses of the Renormalizable Coloron Model  

E-Print Network [OSTI]

The renormalizable coloron model is built around a minimally extended color gauge group, which is spontaneously broken to QCD. The formalism introduces massive color-octet vector bosons (colorons), as well as several new scalars and fermions associated with the symmetry breaking sector. In this paper, we examine vacuum stability and triviality conditions within the context of the renormalizable coloron model up to a cutoff energy scale of 100~TeV, by computing the beta-functions of all relevant couplings and determining their running behavior as a function of the renormalization scale. We constrain the parameter space of the theory for four separate scenarios based on differing fermionic content, and demonstrate that the vectorial scenarios are less constrained by vacuum stability and triviality bounds than the chiral scenarios. Our results are summarized in exclusion plots for the separate scenarios, with previous bounds on the model overlaid for comparison. We find that a 100 TeV hadron collider could explo...

Chivukula, R Sekhar; Simmons, Elizabeth H

2015-01-01T23:59:59.000Z

408

Non-adiabatic perturbations in decaying vacuum cosmology  

SciTech Connect (OSTI)

We investigate a spatially flat Friedmann-Lemaître-Robertson-Walker cosmology in which a decaying vacuum term causes matter production at late times. Assuming a decay proportional to the Hubble rate, the ratio of the background energy densities of dark matter and dark energy changes with the cosmic scale factor as a{sup ?3/2}. The intrinsically non-adiabatic two-component perturbation dynamics of this model is reduced to a single second-order equation. Perturbations of the vacuum term are shown to be negligible on scales that are relevant for structure formation. On larger scales, dark-energy perturbations give a somewhat higher contribution but remain always smaller than the dark-matter perturbations.

Zimdahl, W.; Fabris, J.C. [Departamento de Física, Universidade Federal do Espírito Santo, Vitória, ES (Brazil); Borges, H.A.; Carneiro, S. [Instituto de Física, Universidade Federal da Bahia, Salvador, BA (Brazil); Hipólito-Ricaldi, W.S., E-mail: winfried.zimdahl@pq.cnpq.br, E-mail: humberto@ufba.br, E-mail: saulo.carneiro@pq.cnpq.br, E-mail: fabris@pq.cnpq.br, E-mail: whipolito@gmail.com [Departamento de Ciências Matemáticas e Naturais, UFES, São Mateus, ES (Brazil)

2011-04-01T23:59:59.000Z

409

Dual superconductivity and vacuum properties in Yang--Mills theories  

E-Print Network [OSTI]

We address, within the dual superconductivity model for color confinement, the question whether the Yang-Mills vacuum behaves as a superconductor of type I or type II. In order to do that we compare, for the theory with gauge group SU(2), the determination of the field penetration depth $\\lambda$ with that of the superconductor correlation length $\\xi$. The latter is obtained by measuring the temporal correlator of a disorder parameter developed by the Pisa group to detect dual superconductivity. The comparison places the vacuum close to the border between type I and type II and marginally on the type II side. We also check our results against the study of directly measurable effects such as the interaction between two parallel flux tubes, obtaining consistent indications for a weak repulsive behaviour. Future strategies to improve our investigation are discussed.

A. D'Alessandro; M. D'Elia; L. Tagliacozzo

2007-05-03T23:59:59.000Z

410

Management of vacuum leak-detection processes, standards, and calibration  

SciTech Connect (OSTI)

Vacuum leak detection requires integrated management action to ensure the successful production of apparatus having required leak tightness. Implementation of properly planned, scheduled, and engineering procedures and test arrangements are an absolute necessity to prevent unexpected, impractical, technically inadequate, or unnecessarily costly incidents in leak-testing operations. The use of standard procedures, leak standards appropriate to the task, and accurate calibration systems or devices is necessary to validate the integrity of any leak-test procedure. In this paper, the need for implementing these practices is discussed using case histories of typical examples of large complex vacuum systems. Aggressive management practices are of primary importance throughout a project's life cycle to ensure the lowest cost; this includes successful leak testing of components. It should be noted that the opinions and conclusions expressed in this paper are those of the author and are not those of the Los Alamos National Laboratory or the Department of Energy.

Wilson, N.G.

1984-01-01T23:59:59.000Z

411

Fernald vacuum transfer system for uranium materials repackaging  

SciTech Connect (OSTI)

The Fernald Environmental Management Project (FEMP) is the site of a former Department of Energy (DOE) uranium processing plant. When production was halted, many materials were left in an intermediate state. Some of this product material included enriched uranium compounds that had to be repackaged for shipment of off-site storage. This paper provides an overview, technical description, and status of a new application of existing technology, a vacuum transfer system, to repackage the uranium bearing compounds for shipment. The vacuum transfer system provides a method of transferring compounds from their current storage configuration into packages that meet the Department of Transportation (DOT) shipping requirements for fissile materials. This is a necessary activity, supporting removal of nuclear materials prior to site decontamination and decommissioning, key to the Fernald site's closure process.

Kaushiva, Shirley; Weekley, Clint; Molecke, Martin; Polansky, Gary

2002-02-24T23:59:59.000Z

412

Harnessing vacuum forces for quantum sensing of graphene motion  

E-Print Network [OSTI]

Position measurements at the quantum level are vital for many applications, but also challenging. Typically, methods based on optical phase shifts are used, but these methods are often weak and difficult to apply to many materials. An important example is graphene, which is an excellent mechanical resonator due to its small mass and an outstanding platform for nanotechnologies, but is largely transparent. Here, we present a novel detection scheme based upon the strong, dispersive vacuum interactions between a graphene sheet and a quantum emitter. In particular, the mechanical displacement causes strong changes in the vacuum-induced shifts of the transition frequency of the emitter, which can be read out via optical fields. We show that this enables strong quantum squeezing of the graphene position on time scales short compared to the mechanical period.

Christine A. Muschik; Simon Moulieras; Adrian Bachtold; Maciej Lewenstein; Frank Koppens; Darrick Chang

2014-05-26T23:59:59.000Z

413

THE SNS VACUUM CONTROL SYSTEM UPGRADE FOR THE SUPERCONDUCTING LINAC  

SciTech Connect (OSTI)

The superconducting linac of the Spallation Neutron Source (SNS) has 23 cryomodules whose vacuum system is monitored and controlled by custom built hardware. The original control hardware was provided by Thomas Jefferson National Accelerator Facility (JLab) and contained a variety of custom boards utilizing integrated circuits to perform logic. The need for control logic changes, a desire to increase maintainability, and a desire to increase flexibility to adapt for the future has led to a Programmable Logic Controller (PLC) based upgrade. This paper provides an overview of the commercial off-the-shelf (COTS) hardware being used in the superconducting vacuum control system. Details of the design and challenges to convert a control system during small windows of maintenance periods without disrupting beam operation will be covered in this paper.

Williams, Derrick C [ORNL] [ORNL

2009-01-01T23:59:59.000Z

414

Geometric Phase in Vacuum Instability:APPLICATIONS in Quantum Cosmology  

E-Print Network [OSTI]

Three different methods viz. i) a perturbative analysis of the Schr\\"odinger equation ii) abstract differential geometric method and iii) a semiclassical reduction of the Wheeler-Dewitt equation, relating Pancharatnam phase to vacuum instability are discussed. An improved semiclassical reduction is also shown to yield the correct zeroth order semicalssical Einstein equations with backreaction. This constitutes an extension of our earlier discussions on the topic

D. P. Datta

1993-06-24T23:59:59.000Z

415

Particles, Waves and Vacuum in Five Dimensions: A Status Report  

E-Print Network [OSTI]

Since the 5D canonical metric embeds all 4D vacuum solutions of Einstein's equations, I review its application to the cosmological 'constant', quantized particles, deBroglie waves, scalar fields and wave-particle duality. There are several ways to ra-tionalize these things using an extra dimension. A possible explanation of wave-particle duality is that an observed particle manifests two isometries of flat 5D space in different 4D ways, one with waves and one without.

Paul S. Wesson

2012-05-20T23:59:59.000Z

416

Cold Vacuum Drying (CVD) Facility Hazards Analysis Report  

SciTech Connect (OSTI)

This report describes the methodology used in conducting the Cold Vacuum Drying Facility (CVDF) Hazard Analysis to support the CVDF Final Safety Analysis Report and documents the results. The hazard analysis was performed in accordance with DOE-STD-3009-94, ''Preparation Guide for US. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports,'' and implements the requirements of DOE Order 5480.23, ''Nuclear Safety Analysis Reports.''

CROWE, R.D.

2000-08-07T23:59:59.000Z

417

Static, massive fields and vacuum polarization potential in Rindler space  

E-Print Network [OSTI]

In Rindler space, we determine in terms of special functions the expression of the static, massive scalar or vector field generated by a point source. We find also an explicit integral expression of the induced electrostatic potential resulting from the vacuum polarization due to an electric charge at rest in the Rindler coordinates. For a weak acceleration, we give then an approximate expression in the Fermi coordinates associated with the uniformly accelerated observer.

B. Linet

1997-04-03T23:59:59.000Z

418

Vacuum self-focussing of very intense laser beams  

E-Print Network [OSTI]

We argue that long-range photon-photon attraction induced by the dipole interaction of two electron-positron loops can lead to "vacuum self-focussing" of very intense laser beams. The focussing angle theta(F) is found to increase with the beam intensity I as theta(F) I^(4/3); for the laser beams available at present or in the near future, theta(F) 10^(-10)--10^(-7).

Dmitri Kharzeev; Kirill Tuchin

2007-02-21T23:59:59.000Z

419

Cold Vacuum Drying (CVD) Electrical System Design Description  

SciTech Connect (OSTI)

This system design description (SDD) provides a technical explanation of the design and operation of the electrical system for the Cold Vacuum Drying Facility (CVDF). This SDD also identifies the requirements, and the basis for the requirements and details on how the requirements have been implemented in the design and construction of the facility. This SDD also provides general guidance for the surveillance, testing, and maintenance of this system.

SINGH, G.

2000-05-01T23:59:59.000Z

420

Nonlinear optical properties of the magnetized QED Vacuum  

E-Print Network [OSTI]

New processes associated with the nonlinear optical properties of the electromagnetic vacuum, as predicted by quantum electrodynamics are described. We consider the presence of a static and a rotating magnetic field. The cases of harmonic generation and two different types of sideband cascades are considered. First order and second order effects with respect to the external magnetic field are discussed in detail. Possible experimental configurations using ultra-intense lasers are compared with the alternative use of cw lasers in stable optical cavities.

J. T. Mendonca

2007-04-12T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

LTC 1073 vacuum blasting (concrete) human factors assessment -- Baseline (summary)  

SciTech Connect (OSTI)

The LTC 1073 Vacuum Blasting Machine uses a high capacity, direct pressure blasting system incorporating a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast head. A vacuum system removes dust and debris from the surfaces as it is blasted. After cleaning the surface, the abrasive, together with the rust or coating that was removed from the surface, is vacuumed into the machine through the suction hose. The dust separator contains angled steel collision pads, working with the force of gravity, to allow any reusable abrasive to fall back into the pressure vessel. The filters are manually back flushed to prevent clogging. After back flushing, dust is dumped from the dust chamber into the dust collection bag or drum by operation of the bellows valve. The safety and health evaluation during the testing demonstration focused on dust and noise exposure. Dust exposure was found to be minimal, but noise exposure was potentially significant. Further testing for each of these exposures is recommended because the outdoor environment where the testing demonstration took place may cause the results to be inapplicable to indoor settings. It is feasible that the dust and noise levels will be higher in an enclosed operating environment. Other safety and health issues found were ergonomics, heat stress, tripping hazards, lockout/tagout, and arm-hand vibration.

NONE

1997-07-31T23:59:59.000Z

422

Induced energy polarization of the vacuum and the resulting cosmology  

E-Print Network [OSTI]

The theory of an induced energy polarized vacuum provides an alternative to the standard cosmological model. The theory has previously been shown to lead to the Baryonic Tully-Fisher Relationship [1], to agree with the observed rotation curve of the Galaxy [2], to readily produce the observed features in the rotational curves of other spiral galaxies [3], and to agree with observations of the Coma cluster [4]. All without the need for any free parameters. The theory of an induced energy polarized vacuum is now applied to superclusters. From a model of the distribution of superclusters, the overall density parameter of universe as given by the theory of an induced energy polarized vacuum is Omega = 0.94 plus/minus 0.23. This is consistent with a geometrically flat universe. In addition, by treating the superclusters as unbound systems, the theory leads to an accelerating expansion of the universe in line with observations and without requiring the need for dark energy.

Albert Raymond Penner

2014-04-10T23:59:59.000Z

423

Dynamics of holographic vacuum energy in the DGP model  

E-Print Network [OSTI]

We consider the evolution of the vacuum energy in the DGP model according to the holographic principle under the assumption that the relation linking the IR and UV cut-offs still holds in this scenario. The model is studied when the IR cut-off is chosen to be the Hubble scale $H^{-1}$, the particle horizon $R_{\\rm ph}$ and the future event horizon $R_{\\rm eh}$, respectively. And the two branches of the DGP model are also taken into account. Through numerical analysis, we find that in the cases of $H^{-1}$ in the (+) branch and $R_{\\rm eh}$ in both branches, the vacuum energy can play the role of dark energy. Moreover, when considering the combination of the vacuum energy and the 5D gravity effect in both branches, the equation of state of the effective dark energy may cross -1, which may lead to the Big Rip singularity. Besides, we constrain the model with the Type Ia supernovae and baryon oscillation data and find that our model is consistent with current data within $1\\sigma$, and that the observations prefer either a pure holographic dark energy or a pure DGP model

Xing Wu; Rong-Gen Cai; Zong-Hong Zhu

2007-12-21T23:59:59.000Z

424

Impact of Dynamical Fermions on QCD Vacuum Structure  

E-Print Network [OSTI]

We examine how dynamical fermions affect both the UV and infrared structure of the QCD vacuum. We consider large $28^3 \\times 96$ lattices from the MILC collaboration, using a gluonic definition of the topological charge density, founded on a new over-improved stout-link smearing algorithm. The algorithm reproduces established results from the overlap formalism and is designed to preserve nontrivial topological objects including instantons. At short distances we focus on the topological charge correlator, $$, where negative values at small $x$ reveal a sign-alternating layered structure to the topological-charge density of the QCD vacuum. We find that the magnitudes of the negative dip in the $$ correlator and the positive $$ contact term are both increased with the introduction of dynamical fermion degrees of freedom. This is in accord with expectations based on charge renormalization and the vanishing of the topological susceptibility in the chiral limit. At large distances we examine the extent to which instanton-like objects are found on the lattice, and how their distributions vary between quenched and dynamical gauge fields. We show that dynamical gauge fields contain more instanton-like objects with an average size greater than in the quenched vacuum. Finally, we directly visualize the topological charge density in order to investigate the effects of dynamical sea-quark degrees of freedom on topology.

Peter J. Moran; Derek B. Leinweber

2008-01-14T23:59:59.000Z

425

A characterization and evaluation of coal liquefaction process streams. The kinetics of coal liquefaction distillation resid conversion  

SciTech Connect (OSTI)

Under subcontract from CONSOL Inc., the University of Delaware studied the mechanism and kinetics of coal liquefaction resid conversion. The program at Delaware was conducted between August 15, 1994, and April 30, 1997. It consisted of two primary tasks. The first task was to develop an empirical test to measure the reactivity toward hydrocracking of coal-derived distillation resids. The second task was to formulate a computer model to represent the structure of the resids and a kinetic and mechanistic model of resid reactivity based on the structural representations. An introduction and Summary of the project authored by CONSOL and a report of the program findings authored by the University of Delaware researchers are presented here.

Klein, M.T.; Calkins, W.H.; Huang, H.; Wang, S.; Campbell, D.

1998-03-01T23:59:59.000Z

426

Requirements and guidelines for NSLS experimental beam line vacuum systems: Revision A  

SciTech Connect (OSTI)

Requirements are provided for NSLS beam line front ends and vacuum interlocks. Guidelines are provided for UHV beam line vacuum systems, including materials, vacuum hardware (pumps, valves, and flanges), acoustic delay lines and beam line fast valves, instrumentation, fabrication and testing, and the NSLS cleaning facility. Also discussed are the design review for experimenters' equipment that would be connected to the NSLS and acceptance tests for any beam line to be connected with the ring vacuum. Also appended are a description of the acoustic delay line as well as the NSLS vacuum standards and NSLS procedures. (LEW)

Foerster, C.; Halama, H.; Thomlinson, W.

1986-10-01T23:59:59.000Z

427

Mitigation of Radiation and EMI Effects on the Vacuum Control System of LHC  

E-Print Network [OSTI]

The 26 km of vacuum chambers where circulates the beam of the Large Hadron Collider (LHC) must be maintained under Ultra High Vacuum (UHV) to minimize the beam interactions with residual gases, and allow the operation of specific systems. The vacuum level is measured by several thousands of gauges along the accelerator. Bad vacuum quality may trigger a beam dump and close the associated sector valves. The effects of radiation or Electromagnetic Interferences (EMI) on components that may stop the machine must be evaluated and minimized. We report on the actions implemented to mitigate their impact on the vacuum control system.

Pigny, G; Krakowski, P; Rio, B

2014-01-01T23:59:59.000Z

428

T-534: Vulnerability in the PDF distiller of the BlackBerry Attachment Service for the BlackBerry Enterprise Server  

Broader source: Energy.gov [DOE]

BlackBerry advisory describes a security issue that the BlackBerry Attachment Service component of the BlackBerry Enterprise Server is susceptible to. The issue relates to a known vulnerability in the PDF distiller component of the BlackBerry Attachment Service that affects how the BlackBerry Attachment Service processes PDF files.

429

Distillation of Bose-Einstein condensates in a double-well potential The characteristic feature of Bose-Einstein condensation is the accumulation of a  

E-Print Network [OSTI]

Distillation of Bose-Einstein condensates in a double-well potential The characteristic feature of Bose-Einstein condensation is the accumulation of a macroscopic number of particles in the lowest quantum state. Condensate fragmentation, the macroscopic occupation of two or more quantum states

430

Theory versus experiment for vacuum Rabi oscillations in lossy cavities. II. Direct test of uniqueness of vacuum  

SciTech Connect (OSTI)

The paper continues the analysis of vacuum Rabi oscillations we started in part I [Phys. Rev. A 79, 033836 (2009)]. Here we concentrate on experimental consequences for cavity QED of two different classes of representations of harmonic-oscillator Lie algebras. The zero-temperature master equation, derived in part I for irreducible representations of the algebra, is reformulated in a reducible representation that models electromagnetic fields by a gas of harmonic-oscillator wave packets. The representation is known to introduce automatic regularizations that in irreducible representations would have to be justified by ad hoc arguments. Predictions based on this representation are characterized in thermodynamic limit by a single parameter {sigma}, responsible for collapses and revivals of Rabi oscillations in exact vacuum. Collapses and revivals disappear in the limit {sigma}{yields}{infinity}. Observation of a finite {sigma} would mean that cavity quantum fields are described by a non-Wightmanian theory, where vacuum states are zero-temperature Bose-Einstein condensates of a N-particle bosonic oscillator gas and, thus, are nonunique. The data collected in the experiment of Brune et al. [Phys. Rev. Lett. 76, 1800 (1996)] are consistent with any {sigma}>400.

Wilczewski, Marcin; Czachor, Marek [Katedra Fizyki Teoretycznej i Informatyki Kwantowej, Politechnika Gdanska, 80-952 Gdansk (Poland); Krajowe Centrum Informatyki Kwantowej, 81-824 Sopot (Poland) and Centrum Leo Apostel (CLEA), Vrije Universiteit Brussel, 1050 Brussels (Belgium)

2009-07-15T23:59:59.000Z

431

Theory versus experiment for vacuum Rabi oscillations in lossy cavities (II): Direct test of uniqueness of vacuum  

E-Print Network [OSTI]

The paper continues the analysis of vacuum Rabi oscillations we started in Part I [Phys. Rev. A {\\bf 79}, 033836 (2009)]. Here we concentrate on experimental consequences for cavity QED of two different classes of representations of harmonic oscillator Lie algebras. The zero-temperature master equation, derived in Part I for irreducible representations of the algebra, is reformulated in a reducible representation that models electromagnetic fields by a gas of harmonic oscillator wave packets. The representation is known to introduce automatic regularizations that in irreducible representations would have to be justified by ad hoc arguments. Predictions based on this representation are characterized in thermodynamic limit by a single parameter $\\varsigma$, responsible for collapses and revivals of Rabi oscillations in exact vacuum. Collapses and revivals disappear in the limit $\\varsigma\\to\\infty$. Observation of a finite $\\varsigma$ would mean that cavity quantum fields are described by a non-Wightmanian theory, where vacuum states are zero-temperature Bose-Einstein condensates of a finite-particle bosonic oscillator gas and, thus, are non-unique. The data collected in the experiment of Brune {\\it et al.} [Phys. Rev. Lett. {\\bf{76}}, 1800 (1996)] are consistent with any $\\varsigma>400$.

Marcin Wilczewski; Marek Czachor

2009-05-28T23:59:59.000Z

432

Hydrotreating process kinetics for bitumen and bitumen-derived liquids  

SciTech Connect (OSTI)

Hydrodenitrogenation, hydrodesulfurization and resid conversion data for the Whiterocks bitumen and bitumen-derived liquid were analyzed using a modified power rate law model. The model incorporated the space velocity and pressure since the plug flow equation may not be applicable to laboratory-scale reactors in which complete wetting of the catalyst may not be attained. The data were obtained with the reactor operating as a fixed bed reactor in the upflow mode. The space velocity (WHSV[sup [alpha

Kwak, S.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.

1993-01-01T23:59:59.000Z

433

Renewable Acid-hydrolysis Condensation Hydrotreating (REACH) Pilot Plant  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartmentnews-flashes OfficeTexas |4WebinarAccessOpportunities

434

Distillation 29 Chem 355 Jasperse DISTILLATION  

E-Print Network [OSTI]

vaporize. The vapors produced are subsequently passed through a water-cooled condenser. Upon cooling liquid doesn't change, only the rate of vaporization. The energy supplied by heating is used

Jasperse, Craig P.

435

Extending Shelf Life of Sliced Mushrooms (Agaricus bisporus) by using Vacuum Impregnation and Electron-beam Irradiation  

E-Print Network [OSTI]

. The best treatment was the combination of vacuum impregnation with irradiation according to the consumer studies....

Sevimli, Zeynep

2013-01-14T23:59:59.000Z

436

Wide band cryogenic ultra-high vacuum microwave absorber  

DOE Patents [OSTI]

An absorber wave guide assembly for absorbing higher order modes of microwave energy under cryogenic ultra-high vacuum conditions, that absorbs wide-band multi-mode energy. The absorber is of a special triangular shape, made from flat tiles of silicon carbide and aluminum nitride. The leading sharp end of the absorber is located in a corner of the wave guide and tapers to a larger cross-sectional area whose center is located approximately in the center of the wave guide. The absorber is relatively short, being of less height than the maximum width of the wave guide.

Campisi, Isidoro E. (Newport News, VA)

1992-01-01T23:59:59.000Z

437

A laser triggered vacuum spark x-ray lithography source  

E-Print Network [OSTI]

ionized state or the physical processes occurring 15 in a high temperature plasma. There are many advantages to the use of the vacuum spark as an x-ray source; the simplicity of the machine is one. The x-ray output is within the range usable for x-ray... spark apparatus ha- been studied here to determine its applicability to x-ray lithography. A capacitor which stored approximately 3 KJ supplied most of the energy for the plasma. A Nd-YAG laser was used to supply electrons and metallic atoms...

Keating, Richard Allen

1987-01-01T23:59:59.000Z

438

Large area, surface discharge pumped, vacuum ultraviolet light source  

DOE Patents [OSTI]

Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source is disclosed. A contamination-free VUV light source having a 225 cm{sup 2} emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm{sup 2} at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing. 3 figs.

Sze, R.C.; Quigley, G.P.

1996-12-17T23:59:59.000Z

439

Abort interlock diagnostic for protection of APS vacuum chamber  

SciTech Connect (OSTI)

The Advanced Photon Source (APS) vacuum system has been designed to be passively safe from bending magnet radiation heating at positron beam currents up to 30 mA. Above this value, certain components may be damaged from vertical beam missteering, although work is proceeding to raise the safe current threshold. Because of this, a system for preventing the misalignment of high power density beams is required. This report details a system for protection from dipole radiation only. Work on a system for ID radiation is continuing.

Decker, G.

1993-01-01T23:59:59.000Z

440

Abort interlock diagnostic for protection of APS vacuum chamber  

SciTech Connect (OSTI)

The Advanced Photon Source (APS) vacuum system has been designed to be passively safe from bending magnet radiation heating at positron beam currents up to 30 mA. Above this value, certain components may be damaged from vertical beam missteering, although work is proceeding to raise the safe current threshold. Because of this, a system for preventing the misalignment of high power density beams is required. This report details a system for protection from dipole radiation only. Work on a system for ID radiation is continuing.

Decker, G.

1993-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Trapped surfaces in vacuum arising dynamically from mild incoming radiation  

E-Print Network [OSTI]

In this paper, we study the "minimal requirement" on the incoming radiation that guarantees a trapped surface to form in vacuum. First, we extend the region of existence in Christodoulou's theorem on the formation of trapped surfaces and consequently show that the lower bound required to form a trapped surface can be relaxed. Second, we demonstrate that trapped surfaces form dynamically from a class of initial data which are large merely in a scaling-critical norm. This result is motivated in part by the scaling in Christodoulou's formation of trapped surfaces theorem for the Einstein-scalar field system in spherical symmetry.

Xinliang An; Jonathan Luk

2014-09-22T23:59:59.000Z

442

Wide band cryogenic ultra-high vacuum microwave absorber  

DOE Patents [OSTI]

An absorber waveguide assembly for absorbing higher order modes of microwave energy under cryogenic ultra-high vacuum conditions, that absorbs wide-band multi-mode energy. The absorber is of a special triangular shape, made from flat tiles of silicon carbide and aluminum nitride. The leading sharp end of the absorber is located in a corner of the waveguide and tapers to a larger cross-sectional area whose center is located approximately in the center of the wave guide. The absorber is relatively short, being of less height than the maximum width of the waveguide. 11 figs.

Campisi, I.E.

1992-05-12T23:59:59.000Z

443

Cold Vacuum Drying facility HVAC system design description  

SciTech Connect (OSTI)

This System Design Description (SDD) addresses the HVAC system for the CVDF. The CVDF HVAC system consists of five subsystems: (1) Administration building HVAC system; (2) Process bay recirculation HVAC system; (3) Process bay local exhaust HVAC and process vent system; (4) Process general supply/exhaust HVAC system; and (5) Reference air system. The HVAC and reference air systems interface with the following systems: the fire protection control system, Monitoring and Control System (MCS), electrical power distribution system (including standby power), compressed air system, Chilled Water (CHW) system, drainage system, and other Cold Vacuum Drying (CVD) control systems not addressed in this SDD.

SINGH, G.

2000-09-22T23:59:59.000Z

444

Radiative friction on an excited atom moving in vacuum  

E-Print Network [OSTI]

It is known that, when an excited atom spontaneously emits one photon, two effects are produced. First, the atom's internal and external states are entangled with the states of the emitted photon. Second, the atom receives a momentum transfered from the photon. In this work, the dynamics of such an atom in vacuum is studied. Through a specific calculation, it is demonstrated that these effects cause the atom to experience, on average, a friction force opposite to its initial velocity. Properties of the force are also discussed.

Wei Guo

2012-04-30T23:59:59.000Z

445

Uniformly accelerated detector in the $?$-deformed Dirac vacuum  

E-Print Network [OSTI]

In this paper, we investigate how a uniformly accelerated detector responds to vacuum state of a Dirac field in the $\\kappa$-Minkowski space-time. Starting from $\\kappa$-deformed Dirac theory, which is invariant under $\\kappa$-Poincare algebra, we derive $\\kappa$-deformed Wightmann function for Dirac field, which is valid up to first order in the deformation parameter $a$. Using this, we calculate the response function of the uniformly accelerated detector, which is coupled to massless Dirac field in $\\kappa$-spacetime. From this, we obtain the modification to Unruh effect for the $\\kappa$-deformed Dirac field, valid up to first order in the deformation parameter.

E. Harikumar; Ravikant Verma

2012-11-19T23:59:59.000Z

446

Analysis of Zinc 65 Contamination after Vacuum Thermal Process  

SciTech Connect (OSTI)

Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

Korinko, Paul S.; Tosten, Michael H.

2013-01-01T23:59:59.000Z

447

Disposable Vacuum Viewport Protector | Princeton Plasma Physics Lab  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesDataTranslocation oftheAmperometric Detection ofDisposable Vacuum

448

Advanced Vacuum Clean Equipment Optimizer Ltd AVACO | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDIT REPORTOpenWende NewSowitecAWS OceanInformation Advanced Vacuum Clean

449

Microbiology of precooked, uncured, refrigerated vacuum-packaged meat products  

E-Print Network [OSTI]

/Springfield B. S. , Texas A&N University Chairman of Advisory Committee: Dr. Jimmy T. Keeton Microbial evaluation of 29 packages of precooked, vacuum-packaged meat products purchased at local and regional supermarkets did not reveal the presence... of the Census, 1984) over the same time period. Because these changes have had a dramatic effect on the type of meals consumed by families and the time and/or desire to prepare the meals, new products have been developed to meet these needs. precooked...

Anderson, Mark Leon

1988-01-01T23:59:59.000Z

450

Large area, surface discharge pumped, vacuum ultraviolet light source  

DOE Patents [OSTI]

Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source. A contamination-free VUV light source having a 225 cm.sup.2 emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm.sup.2 at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing.

Sze, Robert C. (Santa Fe, NM); Quigley, Gerard P. (Los Alamos, NM)

1996-01-01T23:59:59.000Z

451

Flexible edge seal for vacuum insulating glazing units  

DOE Patents [OSTI]

A flexible edge seal is provided for a vacuum insulating glazing unit having a first glass pane and a second glass pane spaced-apart from the first. The edge seal comprises a seal member formed of a hermetically bondable material and having a first end, a second end and a center section disposed therebetween. The first end is hermetically bondable to a first glass pane. The second end is hermetically bondable to a second glass pane. The center section comprises a plurality of convolutes.

Bettger, Kenneth J.; Stark, David H.

2012-12-11T23:59:59.000Z

452

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

SciTech Connect (OSTI)

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

453

LTC vacuum blasting maching (concrete): Baseline report: Greenbook (Chapter)  

SciTech Connect (OSTI)

The LTC shot blast technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjuction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC 1073 Vacuum Blasting Machine uses a high-capacity, direct-pressure blasting system which incorporates a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast. It incorporates a vacuum system which removes dust and debris from the surface as it is blasted. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure during maintenance activities was minimal, but due to mechanical difficulties dust monitoring could not be conducted during operation. Noise exposure was significant. Further testing for each of these exposures is recommended because of the outdoor environment where the testing demonstration took place. This may cause the results to be inaccurate. It is feasible that the dust and noise levels will be higher in an enclosed environment. In addition, other safety and health issues found were ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, and arm-hand vibration.

NONE

1997-07-31T23:59:59.000Z

454

Vacuum Stability and Triviality Analyses of the Renormalizable Coloron Model  

E-Print Network [OSTI]

The renormalizable coloron model is built around a minimally extended color gauge group, which is spontaneously broken to QCD. The formalism introduces massive color-octet vector bosons (colorons), as well as several new scalars and fermions associated with the symmetry breaking sector. In this paper, we examine vacuum stability and triviality conditions within the context of the renormalizable coloron model up to a cutoff energy scale of 100~TeV, by computing the beta-functions of all relevant couplings and determining their running behavior as a function of the renormalization scale. We constrain the parameter space of the theory for four separate scenarios based on differing fermionic content, and demonstrate that the vectorial scenarios are less constrained by vacuum stability and triviality bounds than the chiral scenarios. Our results are summarized in exclusion plots for the separate scenarios, with previous bounds on the model overlaid for comparison. We find that a 100 TeV hadron collider could explore the entire allowed parameter space of the chiral models very effectively.

R. Sekhar Chivukula; Arsham Farzinnia; Elizabeth H. Simmons

2015-04-12T23:59:59.000Z

455

Human factors engineering report for the cold vacuum drying facility  

SciTech Connect (OSTI)

The purpose of this report is to present the results and findings of the final Human Factors Engineering (HFE) technical analysis and evaluation of the Cold Vacuum Drying Facility (CVDF). Ergonomics issues are also addressed in this report, as appropriate. This report follows up and completes the preliminary work accomplished and reported by the Preliminary HFE Analysis report (SNF-2825, Spent Nuclear Fuel Project Cold Vacuum Drying Facility Human Factors Engineering Analysis: Results and Findings). This analysis avoids redundancy of effort except for ensuring that previously recommended HFE design changes have not affected other parts of the system. Changes in one part of the system may affect other parts of the system where those changes were not applied. The final HFE analysis and evaluation of the CVDF human-machine interactions (HMI) was expanded to include: the physical work environment, human-computer interface (HCI) including workstation and software, operator tasks, tools, maintainability, communications, staffing, training, and the overall ability of humans to accomplish their responsibilities, as appropriate. Key focal areas for this report are the process bay operations, process water conditioning (PWC) skid, tank room, and Central Control Room operations. These key areas contain the system safety-class components and are the foundation for the human factors design basis of the CVDF.

IMKER, F.W.

1999-06-30T23:59:59.000Z

456

Electron beam melting at high pressures with a vacuum separator/plasma lens  

SciTech Connect (OSTI)

Plasmas can be used to provide a vacuum-atmosphere interface or separation between vacua regions as an alternative to differential pumping. Vacuum-atmosphere interface utilizing a cascade arc discharge was successfully propagated from vacuum through such a plasma interface and out into atmospheric pressure. This plasma device also functions as an effective plasma lens. Such a device can be adopted for use in electron beam melting.

Hershcovitch, A. [Brookhaven National Laboratory, Upton, NY (United States)

1995-12-31T23:59:59.000Z

457

Zeldovich flow on cosmic vacuum background new exact nonlinear analytical solution  

E-Print Network [OSTI]

A new exact nonlinear Newtonian solution for a plane matter flow superimposed on the isotropic Hubble expansion is reported. The dynamical effect of cosmic vacuum is taken into account. The solution describes the evolution of nonlinear perturbations via gravitational instability of matter and the termination of the perturbation growth by anti-gravity of vacuum at the epoch of transition from matter domination to vacuum domination. On this basis, an `approximate' 3D solution is suggested as an analog of the Zeldovich ansatz.

Chernin, A D; Starikova, S V; Chernin, Arthur D.; Nagirner, Dmitrij I.; Starikova, Svetlana V.

2001-01-01T23:59:59.000Z

458

Heat transfer through horizontal films of liquids evaporating under high vacuum  

E-Print Network [OSTI]

generally have been accomplished by the use of vacuum systems' However, in the past the systems were rarely operated under 100 mm of mercury pressure. Some evaporation processes were operated under this limit but the majority of the vacuum operations... plate fractionater described by Cronan (7) operates at a pressure of 1 mm of mercury. The need of processing industries to go to higher vacuum systems has caused a reappraisal of engineering data in this field. Very little data have been published...

Stiles, Graham Bill

1961-01-01T23:59:59.000Z

459

Electron beam melting at high pressures with a vacuum separator/plasma lens  

SciTech Connect (OSTI)

Plasmas can be used to provide a vacuum-atmosphere interface or separation between vacua regions as an alternative to differential pumping. Vacuum-atmosphere interface utilizing a cascade arc discharge was successfully demonstrated and a 175 keV electron beam was successfully propagated from vacuum through such a plasma interface and out into atmospheric pressure. This plasma device also functions as an effective plasma tens. Such a device can be adopted for use in electron beam melting.

Hershcovitch, A.

1995-12-31T23:59:59.000Z

460

E-Print Network 3.0 - axicell vacuum vessel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Princeton Plasma Physics Laboratory, Theory Department Collection: Plasma Physics and Fusion 34 LET: a cold neutron chopper spectrometer on ISIS TS2 Summary: Jaws Vacuum Vessel...

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

E-Print Network 3.0 - auxiliary vacuum exhaust Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and particles from the plasma) test tritium breeding... Divertor Vacuum Vessel 12;Heat Flux >15 MWm2, CFCW R&D Activities completed by July 2001. REMOTE Source:...

462

E-Print Network 3.0 - art high vacuum Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

deals with the cooling of water under vacuum and its spectacular transformation into ice. We ... Source: Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics...

463

Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.  

E-Print Network [OSTI]

Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

Chakraborty, Subrata

2013-01-01T23:59:59.000Z

464

E-Print Network 3.0 - atlas vacuum chamber Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Particle Physics Summary: monoxide and dioxide. Hydrocarbons are pumped with lumped ion pumps. The ATLAS experimental vacuum chamber... ). There will be 4 big experiments operating...

465

E-Print Network 3.0 - accumulator ring vacuum Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ring 3, 4. ELECTRON GENERATION We classify electron production... house turbo pumps to function at a vacuum pressure ... Source: Furman, Miguel - Center for Beam Physics,...

466

Inverse Cotton-Mouton effect of the Vacuum and of atomic systems  

E-Print Network [OSTI]

In this letter we calculate the Inverse Cotton-Mouton Effect (ICME) for the vacuum following the predictions of Quantum ElectroDynamics. We compare the value of this effect for the vacuum with the one expected for atomic systems. We finally show that ICME could be measured for the first time for noble gases using state-of-the-art laser systems and for the quantum vacuum with near-future laser facilities like ELI and HiPER, providing in particular a test of the nonlinear behaviour of quantum vacuum at intensities below the Schwinger limit of 4.5x10^33 W/m^2.

C. Rizzo; A. Dupays; R. Battesti; M. Fouché; G. L. J. A. Rikken

2010-05-04T23:59:59.000Z

467

Inverse Cotton-Mouton effect of the Vacuum and of atomic systems  

E-Print Network [OSTI]

In this letter we calculate the Inverse Cotton-Mouton Effect (ICME) for the vacuum following the predictions of Quantum ElectroDynamics. We compare the value of this effect for the vacuum with the one expected for atomic systems. We finally show that ICME could be measured for the first time for noble gases using state-of-the-art laser systems and for the quantum vacuum with near-future laser facilities like ELI and HiPER, providing in particular a test of the nonlinear behaviour of quantum vacuum at intensities below the Schwinger limit of 4.5x10^33 W/m^2.

Rizzo, C; Battesti, R; Fouché, M; Rikken, G L J A

2010-01-01T23:59:59.000Z

468

Distribution of higher n-alkanes in partially frozen middle-distillate fuels. Final report, October 1982-September 1984  

SciTech Connect (OSTI)

In conjunction with continuing studies on the effect of composition on the freezing points of middle distillate fuels, attention was directed to partially frozen fuels. The crystals and residual liquid from partially frozen JP-5 and DFM fuel samples derived from both petroleum and shale were separated from each other and collected by means of the NRL liquid-solid separator apparatus (LSS) at several temperatures below the freezing points of the original samples. The original fuel samples, the solid material (precipitate), and liquid (filtrate) were characterized by gas chromatography (GC). The filtrate data were straightforward. As expected, Van't Hoff plot of the n-alkanes concentrations (log concentrations vs reciprocal absolute temperature) formed straight lines, and their slopes demonstrated the importance of the higher n-alkanes in fuel crystallization at cold temperatures. The precipitate data presented some problems of interpretation since it was observed that the waxy crystal precipitate matrix entrapped significant amounts of liquid (filtrate). The data on solid which were obtained by these methods demonstrated that the higher n-alkanes play the key role in fuel crystallization at low temperatures, concentrating as much as tenfold in the crystallized solids compared to the liquid. Also, it was clearly shown that the n-alkanes form the major part, up to least 95% by weight in some fuels, of the solid crystals formed.

Van Winkle, T.L.; Affens, W.A.; Beal, E.J.; Hazlett, R.N.; DeGuzman, J.

1985-04-10T23:59:59.000Z

469

W(310) cold-field emission characteristics reflecting the vacuum states of an extreme high vacuum electron gun  

SciTech Connect (OSTI)

An extremely high vacuum cold-field electron emission (CFE) gun operating at pressures ranging from {approx}10{sup -8} Pa to {approx}10{sup -10} Pa was constructed. Only the CFE current emitting from W(310) surfaces revealed the existence of a 'stable region' with high current angular density just after tip flash heating. In the 'stable region,' the CFE current was damped very slowly. The presence of non-hydrogen gas eliminated this region from the plot. Improvement of the vacuum prolonged the 90% damping time of the CFE current from {approx}10 min to 800 min. The current angular density I{sup Prime} of CFE current was 60 and 250 {mu}A/sr in the 'stable region' for total CFE currents of 10 and 50 {mu}A, respectively. These results were about three times larger than I{sup Prime} when measured after the complete damping of the CFE current. The CFE gun generated bright scanning transmission electron microscopy images of a carbon nanotube at 30 kV.

Cho, Boklae; Shigeru, Kokubo [Hitachi High-Technologies Corporation 882, Ichige, Hitachinaka-shi, Ibaraki-ken 312-8504 (Japan); Oshima, Chuhei [Kagami Memorial Laboratory for Materials Science and Technology, Waseda University, 2-8-26 Nishi-Waseda, Shinjuku-ku, Tokyo 169-0072 (Japan)

2013-01-15T23:59:59.000Z

470

N d'ordre Anne 2008 devant l'UNIVERSITE CLAUDE BERNARD -LYON 1  

E-Print Network [OSTI]

...............................................................................................................................................5 I.2. Hydrotreatments and hydrotreating catalysts

Paris-Sud XI, Université de

471

Assessment of Energy Efficiency Improvement in the United States Petroleum Refining Industry  

E-Print Network [OSTI]

27  3.5 Hydrotreating Units (Hydrocracking Unit Hydrotreating Unit Hydrogen Production &to fuel.   3.5 Hydrotreating Units (HTU) Hydrotreating units

Morrow III, William R.

2014-01-01T23:59:59.000Z

472

Fundamental constants and cosmic vacuum: the micro and macro connection  

E-Print Network [OSTI]

The idea that the vacuum energy density $\\rho_{\\Lambda}$ could be time dependent is a most reasonable one in the expanding Universe; in fact, much more reasonable than just a rigid cosmological constant for the entire cosmic history. Being $\\rho_{\\Lambda}=\\rho_{\\Lambda}(t)$ dynamical, it offers a possibility to tackle the cosmological constant problem in its various facets. Furthermore, for a long time (most prominently since Dirac's first proposal on a time variable gravitational coupling) the possibility that the fundamental "constants" of Nature are slowly drifting with the cosmic expansion has been continuously investigated. In the last two decades, and specially in recent times, mounting experimental evidence attests that this could be the case. In this paper, we consider the possibility that these two groups of facts might be intimately connected, namely that the observed acceleration of the Universe and the possible time variation of the fundamental constants are two manifestations of the same underlyi...

Fritzsch, Harald

2015-01-01T23:59:59.000Z

473

Just So? Vacuum Oscillations and MSW: An Update  

E-Print Network [OSTI]

We find that vacuum oscillations (VO), large-mixing-angle and small-mixing-angle MSW solutions to the solar neutrino problem (SNP) give all very good fits to the most recent results. Measurements of the $^7$Be flux can, in some cases, discriminate between different solutions to the SNP; in particular, VO allow $^7$Be fluxes almost as large as the one predicted by the SSM. We find that no evidence for seasonal variations can be extracted from present data, but that the large statistics of SuperKamiokande should make possible to study a significant portion of the presently allowed parameter space by just looking for seasonal variations. We also discuss the Borexino potential for detecting seasonal variations, which looks really impressive.

E. Calabresu; N. Ferrari; G. Fiorentini; M. Lissia

1995-07-20T23:59:59.000Z

474

Ultra high vacuum heating and rotating specimen stage  

DOE Patents [OSTI]

A heating and rotating specimen stage provides for simultaneous specimen heating and rotating. The stage is ideally suited for operation in ultrahigh vacuum (1{times}10{sup {minus}9} torr or less), but is useful at atmosphere and in pressurized systems as well. A specimen is placed on a specimen holder that is attached to a heater that, in turn, is attached to a top housing. The top housing is rotated relative to a bottom housing and electrically connected thereto by electrically conductive brushes. This stage is made of materials that are compatible with UHV, able to withstand high temperatures, possess low outgassing rates, are gall and seize resistant, and are able to carry substantial electrical loading without overheating. 5 figs.

Coombs, A.W. III

1995-05-02T23:59:59.000Z

475

Gas-controlled dynamic vacuum insulation with gas gate  

DOE Patents [OSTI]

Disclosed is a dynamic vacuum insulation comprising sidewalls enclosing an evacuated chamber and gas control means for releasing hydrogen gas into a chamber to increase gas molecule conduction of heat across the chamber and retrieving hydrogen gas from the chamber. The gas control means includes a metal hydride that absorbs and retains hydrogen gas at cooler temperatures and releases hydrogen gas at hotter temperatures; a hydride heating means for selectively heating the metal hydride to temperatures high enough to release hydrogen gas from the metal hydride; and gate means positioned between the metal hydride and the chamber for selectively allowing hydrogen to flow or not to flow between said metal hydride and said chamber. 25 figs.

Benson, D.K.; Potter, T.F.

1994-06-07T23:59:59.000Z

476

Gas-controlled dynamic vacuum insulation with gas gate  

DOE Patents [OSTI]

Disclosed is a dynamic vacuum insulation comprising sidewalls enclosing an evacuated chamber and gas control means for releasing hydrogen gas into a chamber to increase gas molecule conduction of heat across the chamber and retrieving hydrogen gas from the chamber. The gas control means includes a metal hydride that absorbs and retains hydrogen gas at cooler temperatures and releases hydrogen gas at hotter temperatures; a hydride heating means for selectively heating the metal hydride to temperatures high enough to release hydrogen gas from the metal hydride; and gate means positioned between the metal hydride and the chamber for selectively allowing hydrogen to flow or not to flow between said metal hydride and said chamber.

Benson, David K. (Golden, CO); Potter, Thomas F. (Denver, CO)

1994-06-07T23:59:59.000Z

477

Propagation of gravitational waves in the nonperturbative spinor vacuum  

E-Print Network [OSTI]

The propagation of gravitational waves on the background of a nonperturbative vacuum of a spinor field is considered. It is shown that there are several distinctive features in comparison with the propagation of plane gravitational waves through empty space: there exists the fixed phase difference between the $h_{yy,zz}$ and $h_{yz}$ components of the wave; the phase and group velocities of gravitational waves are not equal to the velocity of light; the group velocity is always less than the velocity of light; under some conditions the gravitational waves are either damped or absent; for given frequency, there exist two waves with different wave vectors. We also discuss the possibility of experimental verification of the obtained effects as a tool to investigate nonperurbative quantum field theories.

Vladimir Dzhunushaliev; Vladimir Folomeev

2014-09-02T23:59:59.000Z

478

NSLS IN-VACUUM UNDULATORS AND MINI-BETA STRAIGHTS.  

SciTech Connect (OSTI)

We review the work carried out in the X13 R&D Straight Section of the NSLS X-Ray Ring on small gap in-vacuum undulators (IVUNs). Then we discuss: (1) plans to replace the pure permanent magnet undulator in X13 by a hybrid design providing stronger magnetic fields, enhancing the tunability of the device; (2) plans to install hybrid IVUNs in the two RF straights of the X-Ray Ring, increasing the number of insertion devices in the XRay Ring to eight; (3) the possibility of reducing the vertical beta function in the X13 straight from 0.33 m down to 0.16 m. This reduction in beta function would allow us to decrease the usable undulator gap from 3mm down to 2mm, further increasing the tuning range.

RAKOWSKY,G.; LYNCH,D.; BLUM,E.B.; KRINSKY,S.

2001-06-18T23:59:59.000Z

479

Superheavy hidden sectors and the vacuum energy density  

E-Print Network [OSTI]

In the present work a quintessence like mechanism is presented, which models a considerable fraction of the critical energy density today $\\rho_c\\simeq 10^{-47}\\;\\hbox{GeV}^4$. By assuming that the Quantum Field Theory vacuum energy is lowered down to zero by a suitable adjustment mechanism, the critical energy density is modelled in terms of a quintessence axion field $a$. This axion is a pseudo-Goldstone boson arising due to a symmetry breaking mechanism in a hidden sector, corresponding to an $\\hbox{SU(2)}$ gauge interaction. The unification between the latter sector and QCD is produced at a very large energy scale, of the order of the GUT or even of the Planck energy. This theory is confining at a very low scale, of the order of a very light neutrino mass $m_\

Santillán, Osvaldo P

2015-01-01T23:59:59.000Z

480

Origin of Matter from Vacuum in Conformal Cosmology  

E-Print Network [OSTI]

We introduce the hypothesis that the matter content of the universe can be a product of the decay of primordial vector bosons. The effect of the intensive cosmological creation of these primordial vector $W, ~Z $ bosons from the vacuum is studied in the framework of General Relativity and the Standard Model where the relative standard of measurement identifying conformal quantities with the measurable ones is accepted. The relative standard leads to the conformal cosmology with the z-history of masses with the constant temperature, instead of the conventional z-history of the temperature with constant masses in inflationary cosmology. In conformal cosmology both the latest supernova data and primordial nucleosynthesis are compatible with a stiff equation of state associated with one of the possible states of the infrared gravitation field. The distribution function of the created bosons in the lowest order of perturbation theory exposes a cosmological singularity as a consequence of the theorem about the absence of the massless limit of massive vector fields in quantum theory. This singularity can be removed by taking into account the collision processes leading to a thermalization of the created particles. The cosmic microwave background (CMB) temperature T=(M_W^2H_0)^{1/3} ~ 2.7 K occurs as an integral of motion for the universe in the stiff state. We show that this temperature can be attained by the CMB radiation being the final product of the decay of primordial bosons. The effect of anomalous nonconservation of baryon number due to the polarization of the Dirac sea vacuum by these primordial bosons is considered.

D. Blaschke; V. Pervushin; D. Proskurin; S. Vinitsky; A. Gusev

2002-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "vacuum distillation hydrotreating" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Studies of electrical breakdown processes across vacuum gaps between metallic electrodes  

E-Print Network [OSTI]

Studies of electrical breakdown processes across vacuum gaps between metallic electrodes L Available online 3 June 2013 Keywords: Magnetic insulation Vacuum electrical breakdown Bacteria-induced electrical breakdown Accelerator a b s t r a c t An experimental program to elucidate the physical causes

Gilson, Erik

482

Studies of electrical breakdown processes across vacuum gaps between metallic electrodes  

E-Print Network [OSTI]

Studies of electrical breakdown processes across vacuum gaps between metallic electrodes L Keywords: Magnetic insulation Vacuum electrical breakdown Bacteria-induced electrical breakdown Accelerator a b s t r a c t An experimental program to elucidate the physical causes of electrical breakdown

Gilson, Erik

483

Failure Analysis of the Beam Vacuum in the Superconducting Cavities of the TESLA Main Linear Accelerator  

E-Print Network [OSTI]

1 Failure Analysis of the Beam Vacuum in the Superconducting Cavities of the TESLA Main Linear Hamburg, Germany Abstract For the long term successful operation of the superconducting TESLA accelerator The beam vacuum system of the TESLA main linear accelerators contains about 20.000 superconducting cavities

484

Systematics of the Relationship between Vacuum Energy Calculations and Heat Kernel Coe#cients  

E-Print Network [OSTI]

Systematics of the Relationship between Vacuum Energy Calculations and Heat Kernel Coe#cients S. A Casimir energy is a nonlocal e#ect; its magnitude cannot be deduced from heat kernel expan­ sions, even in the regularized (but not yet renormalized) total vacuum energy are associated with the heat kernel coe

485

Method and apparatus for in-cell vacuuming of radiologically contaminated materials  

DOE Patents [OSTI]

A vacuum air flow operated cyclone separator arrangement for collecting, handling and packaging loose contaminated material in accordance with acceptable radiological and criticality control requirements. The vacuum air flow system includes a specially designed fail-safe prefilter installed upstream of the vacuum air flow power supply. The fail-safe prefilter provides in-cell vacuum system flow visualization and automatically reduces or shuts off the vacuum air flow in the event of an upstream prefilter failure. The system is effective for collecting and handling highly contaminated radiological waste in the form of dust, dirt, fuel element fines, metal chips and similar loose material in accordance with radiological and criticality control requirements for disposal by means of shipment and burial.

Spadaro, Peter R. (Pittsburgh, PA); Smith, Jay E. (Pittsburgh, PA); Speer, Elmer L. (Ruffsdale, PA); Cecconi, Arnold L. (Clairton, PA)

1987-01-01T23:59:59.000Z

486

Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading  

SciTech Connect (OSTI)

This report provides a preliminary analysis of the costs associated with converting whole wet algal biomass into primarily diesel fuel. Hydrothermal liquefaction converts the whole algae into an oil that is then hydrotreated and distilled. The secondary aqueous product containing significant organic material is converted to a medium btu gas via catalytic hydrothermal gasification.

Jones, Susanne B.; Zhu, Yunhua; Anderson, Daniel B.; Hallen, Richard T.; Elliott, Douglas C.; Schmidt, Andrew J.; Albrecht, Karl O.; Hart, Todd R.; Butcher, Mark G.; Drennan, Corinne; Snowden-Swan, Lesley J.; Davis, Ryan; Kinchin, Christopher

2014-03-20T23:59:59.000Z

487

REQUIREMENTS AND GUIDELINES FOR NSLS EXPERIMENTAL BEAM LINE VACUUM SYSTEMS-REVISION B.  

SciTech Connect (OSTI)

Typical beam lines are comprised of an assembly of vacuum valves and shutters referred to as a ''front end'', optical elements to monochromatize, focus and split the photon beam, and an experimental area where a target sample is placed into the photon beam and data from the interaction is detected and recorded. Windows are used to separate sections of beam lines that are not compatible with storage ring ultra high vacuum. Some experimental beam lines share a common vacuum with storage rings. Sections of beam lines are only allowed to vent up to atmospheric pressure using pure nitrogen gas after a vacuum barrier is established to protect ring vacuum. The front end may only be bled up when there is no current in the machine. This is especially true on the VUV storage ring where for most experiments, windows are not used. For the shorter wavelength, more energetic photons of the x-ray ring, beryllium windows are used at various beam line locations so that the monochromator, mirror box or sample chamber may be used in a helium atmosphere or rough vacuum. The window separates ring vacuum from the environment of the downstream beam line components. The stored beam lifetime in the storage rings and the maintenance of desirable reflection properties of optical surfaces depend upon hydrocarbon-free, ultra-high vacuum systems. Storage ring vacuum systems will operate at pressures of {approximately} 1 x 10{sup {minus}10} Torr without beam and {approximately} 1 x 10{sup {minus}9} Torr with beam. Systems are free of hydrocarbons in the sense that no pumps, valves, etc. containing organics are used. Components are all-metal, chemically cleaned and bakeable. To the extent that beam lines share a common vacuum with the storage ring, the same criteria will hold for beam line components. The design philosophy for NSLS beam lines is to use all-metal, hydrocarbon-free front end components and recommend that experimenters use this approach for common vacuum hardware downstream of front ends. O-ring-sealed valves, if used, are not permitted upstream of the monochromator exit aperture. It will be the responsibility of users to demonstrate that their experiment will not degrade the pressure or quality of the storage ring vacuum. As a matter of operating policy, all beam lines will be monitored for prescribed pressure and the contribution of high mass gases to this pressure each time a beam line has been opened to ring vacuum.

FOERSTER,C.

1999-05-01T23:59:59.000Z

488

A vacuum disengager for tritium removal from HYLIFE-II Reactor Flibe  

SciTech Connect (OSTI)

We have designed a vacuum disengager system to remove tritium from the Flibe (Li{sub 2}BeF{sub 4}) molten salt coolant of the HYLIFE-II fusion reactor. There is a two-stage vacuum disengager in each of three intermediate heat exchanger (IHX) loops. Each stage consists of a vacuum chamber 4 m in diameter and 7 m tall. As 0.2 mm diameter molten salt droplets fall vertically downward into the vacuum, most of the tritium diffuses out of the droplets and is pumped away. A fraction {Phi} {approximately}10{sup {minus}5} of the 8.6 MCi/day tritium source (from breeding in the Flibe and from unburned fuel) remains in the Flibe as it leaves the vacuum disengagers, and about 21% of that permeates into the intermediate coolant loop, so about 20 Ci/day leak into the steam system. With Flibe primary coolant and a vacuum disengager, it appears that an intermediate coolant loop is not needed to prevent tritium from leaking into the steam system. An experiment is needed to demonstrate Flibe vacuum disengager operation.

Dolan, T.J.; Longhurst, G.R. (EG and G Idaho, Inc., Idaho Falls, ID (United States)); Garcia-Otero, E. (Missouri Univ., Columbia, MO (United States). Dept. of Nuclear Engineering)

1992-01-01T23:59:59.000Z

489

A vacuum disengager for tritium removal from HYLIFE-II Reactor Flibe  

SciTech Connect (OSTI)

We have designed a vacuum disengager system to remove tritium from the Flibe (Li{sub 2}BeF{sub 4}) molten salt coolant of the HYLIFE-II fusion reactor. There is a two-stage vacuum disengager in each of three intermediate heat exchanger (IHX) loops. Each stage consists of a vacuum chamber 4 m in diameter and 7 m tall. As 0.2 mm diameter molten salt droplets fall vertically downward into the vacuum, most of the tritium diffuses out of the droplets and is pumped away. A fraction {Phi} {approximately}10{sup {minus}5} of the 8.6 MCi/day tritium source (from breeding in the Flibe and from unburned fuel) remains in the Flibe as it leaves the vacuum disengagers, and about 21% of that permeates into the intermediate coolant loop, so about 20 Ci/day leak into the steam system. With Flibe primary coolant and a vacuum disengager, it appears that an intermediate coolant loop is not needed to prevent tritium from leaking into the steam system. An experiment is needed to demonstrate Flibe vacuum disengager operation.

Dolan, T.J.; Longhurst, G.R. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Garcia-Otero, E. [Missouri Univ., Columbia, MO (United States). Dept. of Nuclear Engineering

1992-09-01T23:59:59.000Z

490

LTC vacuum blasting machine (metal) baseline report: Greenbook (chapter)  

SciTech Connect (OSTI)

The LTC coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC coating removal system consisted of several hand tools, a Roto Peen scaler, and a needlegun. They are designed to remove coatings from steel, concrete, brick, and wood. These hand tools are used with the LTC PTC-6 vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. The dust exposure was minimal but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body vibration, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

NONE

1997-07-31T23:59:59.000Z

491

Design Document for Control Dewar and Vacuum Pump Platforms  

SciTech Connect (OSTI)

This engineering note documents the design of the control dewar and vacuum pump platform that is to be installed on the D-Zero detector. It's purpose is twofold. Firstly it is a summary and repository of the final design calculations of the structure. Secondly, it documents that design follows the American Institute of Steel Construction (AISC) manual and applicable OSHA requirements with respect to walking working surfaces. The information contained in the main body of this note is supported by raw calculations included as the appendix. The platform is a truss type frame strucrure constructed primarily of rectangular steel tubing. The upper platform is for support of the control dewar (cryogenic/electrical interface for the solenoid), visible light photon counter (VLPC) cryogenic bayonet can, and infrequently, personnel during the connection and disconnection of the detector to building services. Figure 1 shows a layout of the structure as mounted on the detector and with the installed equipment. The connection of the platform to the detector is not conventional. Two main booms cantilever the structure to a location outside of the detector. The mounting location and support booms allow for the uninhibited motion of the detector components.

Rucinksi, R.; /Fermilab

1997-08-27T23:59:59.000Z

492

Welding/sealing glass-enclosed space in a vacuum  

DOE Patents [OSTI]

A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbant material, such as FeO, VO.sub.2, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbant material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbant material melts glass in the portions of both glass sheets that are adjacent the absorbant material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbant material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbant material to source energy power and welding heat needed, the process can be made self-stopping.

Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

1996-01-01T23:59:59.000Z

493

Vacuum electron acceleration by using two variable frequency laser pulses  

SciTech Connect (OSTI)

A method is proposed for producing a relativistic electron bunch in vacuum via direct acceleration by using two frequency-chirped laser pulses. We consider the linearly polarized frequency-chiped Hermit-Gaussian 0, 0 mode lasers with linear chirp in which the local frequency varies linearly in time and space. Electron motion is investigated through a numerical simulation using a three-dimensional particle trajectory code in which the relativistic Newton's equations of motion with corresponding Lorentz force are solved. Two oblique laser pulses with proper chirp parameters and propagation angles are used for the electron acceleration along the z-axis. In this way, an electron initially at rest located at the origin could achieve high energy, ?=319 with the scattering angle of 1.02{sup ?} with respect to the z-axis. Moreover, the acceleration of an electron in different initial positions on each coordinate axis is investigated. It was found that this mechanism has the capability of producing high energy electron microbunches with low scattering angles. The energy gain of an electron initially located at some regions on each axis could be greatly enhanced compared to the single pulse acceleration. Furthermore, the scattering angle will be lowered compared to the acceleration by using laser pulses propagating along the z-axis.

Saberi, H.; Maraghechi, B. [Department of Physics, Amirkabir University of Technology, 15875-4413 Tehran (Iran, Islamic Republic of)] [Department of Physics, Amirkabir University of Technology, 15875-4413 Tehran (Iran, Islamic Republic of)

2013-12-15T23:59:59.000Z

494

Automatic thermocouple positioner for use in vacuum furnaces  

DOE Patents [OSTI]

The invention is a simple and reliable mechanical arrangement for automatically positioning a thermocouple-carrying rod in a vacuum-furnace assembly of the kind including a casing, a furnace mounted in the casing, and a charge-containing crucible mounted in the furnace for vertical movement between a lower (loading) position and a raised (charge-melting) position. In a preferred embodiment, a welded-diaphragm metal bellows is mounted above the furnace, the upper end of the bellows being fixed against movement and the lower end of the bellows being affixed to support means for a thermocouple-carrying rod which is vertically oriented and extends freely through the furnace lid toward the mouth of the crucible. The support means and rod are mounted for relative vertical movement. Before pumpdown of the furnace, the differential pressure acting on the bellows causes it to contract and lift the thermocouple rod to a position where it will not be contacted by the crucible charge when the crucible is elevated to its raised position. During pumpdown, the bellows expands downward, lowering the thermocouple rod and its support. The bellows expands downward beyond a point where downward movement of the thermocouple rod is arrested by contact with the crucible charge and to a point where the upper end of the thermocouple extends well above the thermocouple support. During subsequent melting of the charge, the thermocouple sinks into the melt to provide an accurate measurement of melt temperatures.

Mee, D.K.; Stephens, A.E.

1980-06-06T23:59:59.000Z

495

Cold-Cathodes for Sensors and Vacuum Microelectronics  

SciTech Connect (OSTI)

The aim of this laboratory-directed research and development project was to study amorphous carbon (a-C) thin films for eventual cold-cathode electron emitter applications. The development of robust, cold-cathode emitters are likely to have significant implications for modern technology and possibly launch a new industry: vacuum micro-electronics (VME). The potential impact of VME on Sandia`s National Security missions, such as defense against military threats and economic challenges, is profound. VME enables new microsensors and intrinsically radiation-hard electronics compatible with MOSFET and IMEM technologies. Furthermore, VME is expected to result in a breakthrough technology for the development of high-visibility, low-power flat-panel displays. This work covers four important research areas. First, the authors studied the nature of the C-C bonding structures within these a-C thin films. Second, they determined the changes in the film structures resulting from thermal annealing to simulate the effects of device processing on a-C properties. Third, they performed detailed electrical transport measurements as a function of annealing temperature to correlate changes in transport properties with structural changes and to propose a model for transport in these a-C materials with implications on the nature of electron emission. Finally, they used scanning atom probes to determine important aspects on the nature of emission in a-C.

Siegal, M.P.; Sullivan, J.P.; Tallant, D.R.; Simpson, R.L. [Sandia National Labs., Albuquerque, NM (United States); DiNardo, N.J.; Mercer, T.W. [Drexel Univ., Philadelphia, PA (United States). Dept. of Physics and Astronomy; Martinez-Miranda, L.J. [Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering

1998-05-01T23:59:59.000Z

496

Fundamental constants and cosmic vacuum: the micro and macro connection  

E-Print Network [OSTI]

The idea that the vacuum energy density $\\rho_{\\Lambda}$ could be time dependent is a most reasonable one in the expanding Universe; in fact, much more reasonable than just a rigid cosmological constant for the entire cosmic history. Being $\\rho_{\\Lambda}=\\rho_{\\Lambda}(t)$ dynamical, it offers a possibility to tackle the cosmological constant problem in its various facets. Furthermore, for a long time (most prominently since Dirac's first proposal on a time variable gravitational coupling) the possibility that the fundamental "constants" of Nature are slowly drifting with the cosmic expansion has been continuously investigated. In the last two decades, and specially in recent times, mounting experimental evidence attests that this could be the case. In this paper, we consider the possibility that these two groups of facts might be intimately connected, namely that the observed acceleration of the Universe and the possible time variation of the fundamental constants are two manifestations of the same underlying dynamics. We call it: the "micro and macro connection", and on its basis we expect that the cosmological term in Einstein's equations, Newton's coupling and the masses of all the particles in the Universe, both the dark matter particles and the ordinary baryons and leptons, should all drift with the cosmic expansion. Here we discuss specific cosmological models realizing such possibility in a way that preserves the principle of covariance of General Relativity.

Harald Fritzsch; Joan Sola

2015-03-26T23:59:59.000Z

497

Welding/sealing glass-enclosed space in a vacuum  

DOE Patents [OSTI]

A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbent material, such as FeO, VO{sub 2}, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbent material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbent material melts glass in the portions of both glass sheets that are adjacent the absorbent material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbent material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbent material to source energy power and welding heat needed, the process can be made self-stopping. 8 figs.

Tracy, C.E.; Benson, D.K.

1996-02-06T23:59:59.000Z

498

Topological Structure of the QCD Vacuum Revealed by Overlap Fermions  

E-Print Network [OSTI]

Overlap fermions preserve a remnant of chiral symmetry on the lattice. They are a powerful tool to investigate the topological structure of the vacuum of Yang-Mills theory and full QCD. Recent results concerning the localization of topological charge and the localization and local chirality of the overlap eigenmodes are reported. The charge distribution is radically different, if a spectral cut-off for the Dirac eigenmodes is applied. The density q(x) is changing from the scale-a charge density (with full lattice resolution) to the ultraviolet filtered charge density. The scale-a density, computed on the Linux cluster of LRZ, has a singular, sign-coherent global structure of co-dimension 1 first described by the Kentucky group. We stress, however, the cluster properties of the UV filtered topological density resembling the instanton picture. The spectral cut-off can be mapped to a bosonic smearing procedure. The UV filtered field strength reveals a high degree of (anti)selfduality at "hot spots" of the action. The fermionic eigenmodes show a high degree of local chirality. The lowest modes are seen to be localized in low-dimensional space-time regions.

E. -M. Ilgenfritz; K. Koller; Y. Koma; G. Schierholz; V. Weinberg

2010-03-15T23:59:59.000Z

499

SUMMARY ON TITANIUM NITRIDE COATING OF SNS RING VACUUM CHAMBERS.  

SciTech Connect (OSTI)

The inner surfaces of the 248 m Spallation Neutron Source (SNS) accumulator ring vacuum chambers are coated with {approx}100nm of titanium nitride (TiN) to reduce the secondary electron yield (SEY) of the chamber walls. There are approximately 135 chambers and kicker modules, some up to 5m in length and 36cm in diameter, coated with TiN. The coating is deposited by means of reactive DC magnetron sputtering -using a - cylindrical cathode with internal permanent magnets. This cathode configuration generates a deposition-rate sufficient to meet the required production schedule and produces stoichiometric films with good adhesion, low SEY and acceptable outgassing. Moreover, the cathode magnet configuration allows for simple changes in length and has been adapted to coat the wide variety of chambers and components contained within the arcs, injection, extraction, collimation and RF straight sections. Chamber types and quantities as well as the cathode configurations are presented herein. The unique coating requirements of the injection kicker ceramic chambers and the extraction kicker ferrite surface will be emphasized. A brief summary of the salient coating properties is given including the interdependence of SEY as a function of surface roughness and its effect on outgassing.

TODD, R.; HE, P.; HSEUH, H.C.; WEISS, D.

2005-05-16T23:59:59.000Z

500

High Reliability R-10 Windows Using Vacuum Insulating Glass Units  

SciTech Connect (OSTI)

The objective of this effort was for EverSealed Windows (“EverSealed” or “ESW”) to design, assemble, thermally and environmentally test and demonstrate a Vacuum Insulating Glass Unit (“VIGU” or “VIG”) that would enable a whole window to meet or exceed the an R-10 insulating value (U-factor ? 0.1). To produce a VIGU that could withstand any North American environment, ESW believed it needed to design, produce and use a flexible edge seal system. This is because a rigid edge seal, used by all other know VIG producers and developers, limits the size and/or thermal environment of the VIG to where the unit is not practical for typical IG sizes and cannot withstand severe outdoor environments. The rigid-sealed VIG’s use would be limited to mild climates where it would not have a reasonable economic payback when compared to traditional double-pane or triple-pane IGs. ESW’s goals, in addition to achieving a sufficiently high R-value to enable a whole window to achieve R-10, included creating a VIG design that could be produced for a cost equal to or lower than a traditional triple-pane IG (low-e, argon filled). ESW achieved these goals. EverSealed produced, tested and demonstrated a flexible edge-seal VIG that had an R-13 insulating value and the edge-seal system durability to operate reliably for at least 40 years in the harshest climates of North America.

Stark, David

2012-08-16T23:59:59.000Z