National Library of Energy BETA

Sample records for us-japan rare elements

  1. US-Japan rare elements meeting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US-Japan rare elements meeting US-Japan rare elements meeting US-Japan rare earth elements meeting PDF icon US-Japan rare elements meeting More Documents & Publications Microsoft...

  2. Microsoft Word - US_Japan_REE_agenda_ver7.doc | Department of...

    Office of Environmental Management (EM)

    Microsoft Word - USJapanREEagendaver7.doc Microsoft Word - USJapanREEagendaver7.doc U.S. - Japan Roundtable on Rare Earth Elements Research PDF icon Microsoft Word -...

  3. Rare Earth Elements Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Rare Earth Elements from Coal and Coal By-Products logo. Download the 2016 Rare Earth Elements from Coal and Coal By-Products Project Portfolio Rare Earth ...

  4. 2016 Rare Earth Elements Workshop Accelerating Rare Earth Element...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Workshop Accelerating Rare Earth Element Recovery from U.S. Domestic Sources of Coal and Coal By-Products August 8-9, 2016 Hosted by: Dr. Cynthia Powell Acting ...

  5. Note: Portable rare-earth element analyzer using pyroelectric crystal

    SciTech Connect (OSTI)

    Imashuku, Susumu Fuyuno, Naoto; Hanasaki, Kohei; Kawai, Jun

    2013-12-15

    We report a portable rare-earth element analyzer with a palm-top size chamber including the electron source of a pyroelectric crystal and the sample stage utilizing cathodoluminescence (CL) phenomenon. The portable rare-earth element analyzer utilizing CL phenomenon is the smallest reported so far. The portable rare-earth element analyzer detected the rare-earth elements Dy, Tb, Er, and Sm of ppm order in zircon, which were not detected by scanning electron microscopy-energy dispersive X-ray spectroscopy analysis. We also performed an elemental mapping of rare-earth elements by capturing a CL image using CCD camera.

  6. Calculation of binary phase diagrams between the actinide elements, rare earth elements, and transition metal elements

    SciTech Connect (OSTI)

    Selle, J E

    1992-06-26

    Attempts were made to apply the Kaufman method of calculating binary phase diagrams to the calculation of binary phase diagrams between the rare earths, actinides, and the refractory transition metals. Difficulties were encountered in applying the method to the rare earths and actinides, and modifications were necessary to provide accurate representation of known diagrams. To calculate the interaction parameters for rare earth-rare earth diagrams, it was necessary to use the atomic volumes for each of the phases: liquid, body-centered cubic, hexagonal close-packed, and face-centered cubic. Determination of the atomic volumes of each of these phases for each element is discussed in detail. In some cases, empirical means were necessary. Results are presented on the calculation of rare earth-rare earth, rare earth-actinide, and actinide-actinide diagrams. For rare earth-refractory transition metal diagrams and actinide-refractory transition metal diagrams, empirical means were required to develop values for the enthalpy of vaporization for rare earth elements and values for the constant (C) required when intermediate phases are present. Results of using the values determined for each element are presented.

  7. Trace rare earth element analysis in briny groundwaters

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.; Smith, M.R.

    1986-08-01

    A rare-earth element (REE) group separation scheme has been developed. REE data for two briny groundwaters representing Granite Wash and Wolfcamp Carbonate formations are reported. (DLC)

  8. Thorium, uranium and rare earth elements content in lanthanide...

    Office of Scientific and Technical Information (OSTI)

    Thorium, uranium and rare earth elements content in lanthanide concentrate (LC) and water ... in lanthanide concentrate (LC) and water leach purification (WLP) residue of Lynas ...

  9. CMI Webinar: Recycling of Rare Earth Elements: A Microbiological Approach |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Critical Materials Institute Recycling of Rare Earth Elements: A Microbiological Approach The CMI Webinar series includes a presentation CMI Webinar: Recycling of Rare Earth Elements: A Microbiological Approach by David Reed, Idaho National Laboratory (INL), on April 23, 2015. The recording of the webinar runs nearly 39 minutes (38:52

  10. 2016 Rare Earth Elements Workshop Accelerating Rare Earth Element Recovery from U.S. Domestic Sources of Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Workshop Accelerating Rare Earth Element Recovery from U.S. Domestic Sources of Coal and Coal By-Products August 8-9, 2016 Hosted by: Dr. Cynthia Powell Acting Deputy Director, Science & Technology National Energy Technology Laboratory U.S. Department of Energy 541.207.7392 Office of Fossil Energy U.S. Department of Energy 301.903.2827 Location: National Energy Technology Laboratory 3610 Collins Ferry Road Morgantown, WV 26505 Time: 12:30 pm - 4:15 pm August 8, 2016 7:30

  11. Rare earth element patterns in biotite, muscovite and tourmaline minerals

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.

    1986-04-21

    Rare earth element concentrations in the minerals biotite and muscovite from the mica schist country rocks of the Etta pegmatite and tourmalines from the Bob Ingersoll pegmatite have been measured by INAA and CNAA. The concentrations range from 10/sup -4/ g/g to 10/sup -10g//sub g/. The REE patterns of biotite, muscovite and tourmaline reported herein are highly fractionated from light to heavy REE. The REE concentrations in biotite and muscovite are high and indigenous. The pegmatite tourmalines contain low concentrations of REE. Variations in tourmaline REE patterns reflect the geochemical evolution of pegmatite melt/fluid system during crystallization.

  12. DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements...

    Office of Environmental Management (EM)

    Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts ...

  13. US-Japan_NuclearEnergyActionPlan.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US-Japan_NuclearEnergyActionPlan.pdf US-Japan_NuclearEnergyActionPlan.pdf (551.62 KB) More Documents & Publications Fact Sheet: United States-Japan Joint Nuclear Energy Action Plan United States -Japan Joint Nuclear Energy Action Plan Slide 1

  14. Google Earth locations of USA and seafloor hydrothermal vents with associated rare earth element data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Andrew Fowler

    2016-02-10

    Google Earth .kmz files that contain the locations of geothermal wells and thermal springs in the USA, and seafloor hydrothermal vents that have associated rare earth element data. The file does not contain the actual data, the actual data is available through the GDR website in two tier 3 data sets entitled "Compilation of Rare Earth Element Analyses from US Geothermal Fields and Mid Ocean Ridge (MOR) Hydrothermal Vents" and "Rare earth element content of thermal fluids from Surprise Valley, California"

  15. Detection of rare earth elements in Powder River Basin sub-bituminous...

    Office of Scientific and Technical Information (OSTI)

    Report Number(s): NETL-PUB--20051 Journal ID: ISSN 0016-2361 Resource ... Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Rare earth elements; ...

  16. PROCESS FOR SEPARATING AMERICIUM AND CURIUM FROM RARE EARTH ELEMENTS

    DOE Patents [OSTI]

    Baybarz, R.D.; Lloyd, M.H.

    1963-02-26

    This invention relates to methods of separating americium and curium values from rare earth values. In accordance with the invention americium, curium, and rare earth values are sorbed on an anion exchange resin. A major portion of the rare earth values are selectively stripped from the resin with a concentrated aqueous solution of lithium chloride, and americium, curium, and a minor portion of rare earth values are then stripped from the resin with a dilute aqueous solution of lithium chloride. The americium and curium values are further purified by increasing the concentration of lithium chloride in the solution to at least 8 molar and selectively extracting rare earth values from the resulting solution with a monoalkylphosphoric acid. (AEC)

  17. Watch a Rare Earth Elements Event Live This Morning | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Ginny Simmons Ginny Simmons Former Managing Editor for Energy.gov, Office of Public Affairs From 9:30am to noon ET today you can tune into a live discussion on "rare earth ...

  18. Rare Earth Elements: A Tool for Understanding the Behaviour of Trivalent Actinides in the Geosphere

    SciTech Connect (OSTI)

    Buil, Belen; Gomez, Paloma; Garralon, Antonio; Turrero, M. Jesus

    2007-07-01

    Rare earth element (REE) concentrations have been determined in groundwaters, granite and fracture fillings in a restored uranium mine. The granitoids normalized REE patterns of groundwaters show heavy rare earth elements (HREE)-enrichment and positive Eu anomalies. This suggests that the REE are fractionated during leaching from the source rocks by groundwaters. Preferential leaching of HREE would be consistent with the greater stability of their aqueous complexes compared to those of the light rare earth elements (LREE), together with the dissolution of certain fracture filling minerals, dissolution/alteration of phyllosilicates and colloidal transport. (authors)

  19. DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Coal Byproducts | Department of Energy Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts September 25, 2014 - 9:55am Addthis DOE Seeks Your Novel Ideas for Recovery of Rare Earth Elements from Coal and Coal Byproducts Replies to the RFI are due October 10, 2014, by 8:00 p.m. EDT. Details about how and where to submit your ideas-and additional information

  20. Column Sorption Uptake and Regeneration Study; Rare Earth Element Sorbent Uptake and Sorbent Stripping

    SciTech Connect (OSTI)

    Tim Lanyk

    2015-12-18

    Study of rare earth element (REE) uptake from geothermal brine simulant by column loading, metal recovery through stripping, and regeneration of column for re-loading. Simulated brine testing.

  1. FE-Supported Research Looks to Coal as a Source for Rare Earth Elements

    Office of Energy Efficiency and Renewable Energy (EERE)

    FE, through the National Energy Technology Laboratory (NETL), is looking at ways to use coal and its byproducts (like coal ash from power plants, for instance) to develop new sources of critical rare earth elements, or REEs.

  2. Fluorescent lifetime measurements of rare-earth elements in gallium arsenide. Master's thesis

    SciTech Connect (OSTI)

    Topp, D.J.

    1990-12-01

    Lifetime measurements of the excited states of three GaAs semiconductors doped with the rare earth elements Erbium (Er), Praseodymium (Pr), and Thulium (Tm) has been studied using a pulsed nitrogen laser and germanium detector. The measurements were made with an experimental set up with a system response time of 0.34 microseconds. A 330 milliwatt nitrogen laser with a wavelength of 3370 angstroms was used to excite transitions of the rare earth elements.

  3. Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials for a Clean Energy Future

    Office of Energy Efficiency and Renewable Energy (EERE)

    Trans-Atlantic Workshop on Rare Earth Elements and Other Critical Materials for a Clean Energy Future

  4. SEPARATION OF TRANSURANIC ELEMENTS FROM RARE EARTH COMPOUNDS

    DOE Patents [OSTI]

    Kohman, T.P.

    1961-11-21

    A process of separating neptunium and plutonium values from rare earths and alkaline earth fission products present on a solid mixed actinide carrier (Th or U(IV) oxalate or fluoride) --fission product carrier (LaF/sub 3/, CeF/sub 3/, SrF/sub 2/, CaF/sub 2/, YF/sub 3/, La oxalate, cerous oxalate, Sr oxalate, Ca oxalate or Y oxalate) by extraction of the actinides at elevated temperature with a solution of ammonium fluoride and/or ammonium oxalate is described. Separation of the fission-product-containing carriers from the actinide solution formed and precipitation of the neptunium and plutonium from the solution with mineral acid are also accomplished. (AEC)

  5. US-Japan energy policy dialogue. [Final] report, June 1991--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-03-16

    The Atlantic Council has cooperated in an ongoing dialogue on energy policy issues with key Japanese organizations for the past twelve years. These Japanese organizations are the Committee for Energy Policy Promotion (CEPP) and the Institute of Energy Economics (IEE). The members of CEPP are major energy supplier and user companies. The IEE conducts sophisticated research and prepares policy papers on a range of international and Japanese energy issues. This energy dialogue is the only long-term US-Japan dialogue which engages CEPP/IEE members. Over the past twelve years the US-Japan energy dialogue has met seventeen times, with alternating meetings held in Tokyo, Hawaii, and Washington, DC. While the dialogue is a private sector activity, US and Japanese government officials are kept informed on the program and are invited to participate in the meetings in Washington and Tokyo. Major benefits of this activity have included: Establishment of close working relationships among Japanese and US private sector energy institutions and experts; exchange of papers on energy issues among participants and on a selected basis to others in the private and governmental sectors; facilitation of separate US-Japanese work on policy issues - for example a joint US-Japan cooperative policy paper on global climate change published in 1991, some government representatives participated in a May 1991 meeting on this subject. Encouragement of Japanese participation in separate Atlantic Council programs on US energy policy imperatives (1990); technology cooperation with developing countries in the field of energy supply and use for sustainable development (1992); creation of a World Energy Efficiency Association (1993); and a US-Japan-Newly Independent States project on NIS energy policy (1992--1994).

  6. Rare earth element content of thermal fluids from Surprise Valley, California

    SciTech Connect (OSTI)

    Andrew Fowler

    2015-09-23

    Rare earth element measurements for thermal fluids from Surprise Valley, California. Samples were collected in acid washed HDPE bottles and acidified with concentrated trace element clean (Fisher Scientific) nitric acid. Samples were pre-concentratated by a factor of approximately 10 using chelating resin with and IDA functional group and measured on magnetic sector ICP-MS. Samples include Seyferth Hot Springs, Surprise Valley Resort Mineral Well, Leonard's Hot Spring, and Lake City Mud Volcano Boiling Spring.

  7. Fluid rare earth element anlayses from wells RN-12 and RN-19, Reykjanes, Iceland

    SciTech Connect (OSTI)

    Andrew Fowler

    2015-07-24

    Results for fluid rare earth elment analyses from Reykjanes wells RN-12 and RN-19. The data have not been corrected for flashing. Samples preconcetrated using chelating resin with IDA functional group (InertSep ME-1). Analyzed using and Element magnetic sctor ICP-MS.

  8. Compilation of Rare Earth Element Analyses from US Geothermal Fields and Mid Ocean Ridge Hydrothermal Vents

    SciTech Connect (OSTI)

    Andrew Fowler

    2015-10-01

    Compilation of rare earth element and associated major and minor dissolved constituent analytical data for USA geothermal fields and global seafloor hydrothermal vents. Data is in original units. Reference to and use of this data should be attributed to the original authors and publications according to the provisions outlined therein.

  9. Proceedings of US-Japan heliotron-stellarator workshop: Volume 2

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    This paper is the second of four volumes on the US-Japan Heliotron-Stellarator workshop. It contains talks on the following: Ripple Transport at Arbitrary Collision Frequency, Transport Scaling in the Collisionless-Detrapping Regime, Transport Analysis for Heliotron E, Transport Analysis for ATF, Simulation Analysis of Heating and Transport, Analysis of W VII-A Data, Numerical Study of Fast Ion Confinement, Benchmarks of NBI Codes for Stellarators, ECH Commissioning and Plans for ATF, and ECH and ICH Startup Analysis. (LSP)

  10. US/Japan Cooperation in High Energy Physics. Review of activities, 1988--1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-16

    The objective of the Implementing Arrangement was to further the energy programs of both countries by establishing a framework for cooperation in the field of high energy physics, including research, accelerator and detector instrumentation research and development, the fabrication and subsequent use of new experimental devices and facilities, and related joint efforts as may be mutually agreed. Over the years, this cooperation has been very effective and has strengthened the overall collaborative efforts and the understanding between our nations and their citizens. It has demonstrated to the world our ability to work together to attack difficult problems. High Energy Physics goes across national borders; the bond is clearly intellectual and common ground is shared for the benefit of all in a most effective manner. This review covers the activities conducted under the aegis of the US/Japan Committee for Cooperation in High Energy Physics during the past five years (1988--1993). This was the second such US review of the US/Japan cooperative activities; the first was held in 1987.

  11. The effect of rare earth elements on the texture and formability of asymmetrically rolled magnesium sheet

    SciTech Connect (OSTI)

    Alderman, Dr. Martyn; Cavin, Odis Burl; Davis, Dr. Bruce; Muralidharan, Govindarajan; Muth, Thomas R; Peter, William H; Randman, David; Watkins, Thomas R

    2011-01-01

    The lack of formability is a serious issue when considering magnesium alloys for various applications. Standard symmetric rolling introduces a strong basal texture that decreases the formability; however, asymmetric rolling has been put forward as a possible route to produce sheet with weaker texture and greater ductility. It has also been shown in recent work that weaker textures can be produced through the addition of rare earth elements to magnesium alloys. Therefore, this study has been carried out to investigate the effect of rare earth additions on the texture changes during asymmetric rolling. Two alloys have been used, AZ31B and ZEK100. The effect that the rare earth additions have on the texture of asymmetrically rolled sheet and the subsequent changes in formability will be discussed.

  12. Symmetric charge-transfer cross sections of IIIa rare-earth-metal elements

    SciTech Connect (OSTI)

    Hashida, Masaki; Sakabe, Shuji; Izawa, Yasukazu

    2011-03-15

    Symmetric charge-transfer cross sections of IIIa rare-earth-metal elements (Sc, Y, and Gd) in the impact energy range of 30 to 1000 eV were measured for the first time. The experiments were performed with a crossed-beam apparatus that featured primary ion production by photoionization with a tunable dye laser. Comparing the cross sections of IIIa rare-earth-metal elements ({sigma}{sub Sc}, {sigma}{sub Y}, and {sigma}{sub Gd}) with those of alkali metals or helium {sigma}{sub 0}, we found that {sigma}{sub 0{approx_equal}{sigma}Sc}<{sigma}{sub Y}<{sigma}{sub Gd{approx_equal}}2{sigma}{sub 0}at an impact energy of 1000 eV.

  13. Proceedings of a joint US-Japan Seminar in the Environmental Sciences

    SciTech Connect (OSTI)

    DeAngelis, D.L.; Teramoto, E.; Neergaard, D.A.

    1993-11-01

    The Joint US-Japan Seminar in the Environmental Sciences was based on the premises that questions remain concerning the factors that control many of the regularities observed in ecological communities and that increased collaboration between researchers in the United States and Japan can contribute to answering these questions. The papers included in this report resulted from the Seminar. These papers as well as workshop discussions summarized here outline the main issues that face theoretical ecology today. The papers cover four different areas of theoretical ecology: (1) individual species adaptations, (2) ecological community-food web interactions, (3) food web theory, and (4) concepts related to the ecosystem. Individual projects are processed separately for the databases.

  14. Spectral Analysis of Rare Earth Elements using Laser-Induced Breakdown Spectroscopy

    SciTech Connect (OSTI)

    Martin, Madhavi Z; Fox, Dr. Richard V; Miziolek, Andrzej W; DeLucia, Frank C; Andre, Nicolas O

    2015-01-01

    There is growing interest in rapid analysis of rare earth elements (REEs) both due to the need to find new natural sources to satisfy increased demand in their use in various electronic devices, as well as the fact that they are used to estimate actinide masses for nuclear safeguards and nonproliferation. Laser-Induced Breakdown Spectroscopy (LIBS) appears to be a particularly well-suited spectroscopy-based technology to rapidly and accurately analyze the REEs in various matrices at low concentration levels (parts-per-million). Although LIBS spectra of REEs have been reported for a number of years, further work is still necessary in order to be able to quantify the concentrations of various REEs in real-world complex samples. LIBS offers advantages over conventional solution-based radiochemistry in terms of cost, analytical turnaround, waste generation, personnel dose, and contamination risk. Rare earth elements of commercial interest are found in the following three matrix groups: 1) raw ores and unrefined materials, 2) as components in refined products such as magnets, lighting phosphors, consumer electronics (which are mostly magnets and phosphors), catalysts, batteries, etc., and 3) waste/recyclable materials (aka e-waste). LIBS spectra for REEs such as Gd, Nd, and Sm found in rare earth magnets are presented.

  15. Spectral Analysis of Rare Earth Elements using Laser-Induced Breakdown Spectroscopy

    SciTech Connect (OSTI)

    Martin, Madhavi Z; Fox, Dr. Richard V; Miziolek, Andrzej W; DeLucia, Frank C; Andre, Nicolas O

    2015-01-01

    There is growing interest in rapid analysis of rare earth elements (REEs) both due to the need to find new natural sources to satisfy increased demand in their use in various electronic devices, as well as the fact that they are used to estimate actinide masses for nuclear safeguards and nonproliferation. Laser-Induced Breakdown Spectroscopy (LIBS) appears to be a particularly well-suited spectroscopy-based technology to rapidly and accurately analyze the REEs in various matrices at low concentration levels (parts-per-million). Although LIBS spectra of REEs have been reported for a number of years, further work is still necessary in order to be able to quantify the concentrations of various REEs in realworld complex samples. LIBS offers advantages over conventional solution-based radiochemistry in terms of cost, analytical turnaround, waste generation, personnel dose, and contamination risk. Rare earth elements of commercial interest are found in the following three matrix groups: 1) raw ores and unrefined materials, 2) as components in refined products such as magnets, lighting phosphors, consumer electronics (which are mostly magnets and phosphors), catalysts, batteries, etc., and 3) waste/recyclable materials (aka e-waste). LIBS spectra for REEs such as Gd, Nd, and Sm found in rare earth magnets are presented.

  16. Spectral Analysis of Rare Earth Elements using Laser-Induced Breakdown Spectroscopy

    SciTech Connect (OSTI)

    Madhavi Z. Martin; Robert V. Fox; Andrzej W. Miziolek; Frank C. DeLucia, Jr.; Nicolas Andre

    2001-05-01

    There is growing interest in rapid analysis of rare earth elements (REEs) both due to the need to find new natural sources to satisfy increased demand in their use in various electronic devices, as well as the fact that they are used to estimate actinide masses for nuclear safeguards and nonproliferation. Laser-Induced Breakdown Spectroscopy (LIBS) appears to be a particularly well-suited spectroscopy-based technology to rapidly and accurately analyze the REEs in various matrices at low concentration levels (parts-per-million). Although LIBS spectra of REEs have been reported for a number of years, further work is still necessary in order to be able to quantify the concentrations of various REEs in realworld complex samples. LIBS offers advantages over conventional solution-based radiochemistry in terms of cost, analytical turnaround, waste generation, personnel dose, and contamination risk. Rare earth elements of commercial interest are found in the following three matrix groups: 1) raw ores and unrefined materials, 2) as components in refined products such as magnets, lighting phosphors, consumer electronics (which are mostly magnets and phosphors), catalysts, batteries, etc., and 3) waste/recyclable materials (aka e-waste). LIBS spectra for REEs such as Gd, Nd, and Sm found in rare earth magnets are presented.

  17. Quantification of rare earth elements using laser-induced breakdown spectroscopy

    SciTech Connect (OSTI)

    Martin, Madhavi; Martin, Rodger C.; Allman, Steve; Brice, Deanne; Wymore, Ann; Andre, Nicolas

    2015-10-21

    In this paper, a study of the optical emission as a function of concentration of laser-ablated yttrium (Y) and of six rare earth elements, europium (Eu), gadolinium (Gd), lanthanum (La), praseodymium (Pr), neodymium (Nd), and samarium (Sm), has been evaluated using the laser-induced breakdown spectroscopy (LIBS) technique. Statistical methodology using multivariate analysis has been used to obtain the sampling errors, coefficient of regression, calibration, and cross-validation of measurements as they relate to the LIBS analysis in graphite-matrix pellets that were doped with elements at several concentrations. Each element (in oxide form) was mixed in the graphite matrix in percentages ranging from 1% to 50% by weight and the LIBS spectra obtained for each composition as well as for pure oxide samples. Finally, a single pellet was mixed with all the elements in equal oxide masses to determine if we can identify the elemental peaks in a mixed pellet. This dataset is relevant for future application to studies of fission product content and distribution in irradiated nuclear fuels. These results demonstrate that LIBS technique is inherently well suited for the future challenge of in situ analysis of nuclear materials. Finally, these studies also show that LIBS spectral analysis using statistical methodology can provide quantitative results and suggest an approach in future to the far more challenging multielemental analysis of ~ 20 primary elements in high-burnup nuclear reactor fuel.

  18. Quantification of rare earth elements using laser-induced breakdown spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martin, Madhavi; Martin, Rodger C.; Allman, Steve; Brice, Deanne; Wymore, Ann; Andre, Nicolas

    2015-10-21

    In this paper, a study of the optical emission as a function of concentration of laser-ablated yttrium (Y) and of six rare earth elements, europium (Eu), gadolinium (Gd), lanthanum (La), praseodymium (Pr), neodymium (Nd), and samarium (Sm), has been evaluated using the laser-induced breakdown spectroscopy (LIBS) technique. Statistical methodology using multivariate analysis has been used to obtain the sampling errors, coefficient of regression, calibration, and cross-validation of measurements as they relate to the LIBS analysis in graphite-matrix pellets that were doped with elements at several concentrations. Each element (in oxide form) was mixed in the graphite matrix in percentages rangingmore » from 1% to 50% by weight and the LIBS spectra obtained for each composition as well as for pure oxide samples. Finally, a single pellet was mixed with all the elements in equal oxide masses to determine if we can identify the elemental peaks in a mixed pellet. This dataset is relevant for future application to studies of fission product content and distribution in irradiated nuclear fuels. These results demonstrate that LIBS technique is inherently well suited for the future challenge of in situ analysis of nuclear materials. Finally, these studies also show that LIBS spectral analysis using statistical methodology can provide quantitative results and suggest an approach in future to the far more challenging multielemental analysis of ~ 20 primary elements in high-burnup nuclear reactor fuel.« less

  19. DOE Selects Projects To Enhance Its Research into Recovery of Rare Earth Elements from Coal and Coal Byproducts

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) has selected 10 projects to receive funding for research in support of the lab’s program on Recovery of Rare Earth Elements from Coal and Coal Byproducts. The selected research projects will further program goals by focusing on the development of cost-effective and environmentally benign approaches for the recovery of rare earth elements (REEs) from domestic coal and coal byproducts.

  20. Proceedings of the 3rd US-Japan Workshop on Plasma Polarization Spectroscopy

    SciTech Connect (OSTI)

    Beiersdorfer, P; Flyimoto, T

    2002-01-02

    The third US-Japan Workshop on Plasma Polarization Spectroscopy was held at the Lawrence Livermore National Laboratory in Livermore, California, on June 18-21, 2001. The talks presented at this workshop are summarized in these proceedings. The papers cover both experimental investigation and applications of plasma polarization spectroscopy as well as the theoretical foundation and formalisms to understand and describe the polarization phenomena. The papers give an overview of the history of plasma polarization spectroscopy, derive the formal aspects of polarization spectroscopy, including the effects of electric and magnetic fields, discuss spectra perturbed by intense microwave fields, charge exchange, and dielectronic recombination, and present calculations of various collisional excitation and ionization cross sections and the modeling of plasma polarization spectroscopy phenomena. Experimental results are given from the WT-3 tokamak, the MST reverse field pinch, the Large Helical Device, the GAMMA 10 mirror machine, the Nevada Terrawatt Facility, the Livermore EBIT-II electron beam ion trap, and beam-foil spectroscopy. In addition, results were presented from studies of several laser-produced plasma experiments and new instrumental techniques were demonstrated.

  1. Behavior of Rare Earth Element In Geothermal Systems; A New Exploration/Exploitation Tool

    SciTech Connect (OSTI)

    Scott A. Wood

    2002-01-28

    The goal of this four-year project was to provide a database by which to judge the utility of the rare earth elements (REE) in the exploration for and exploitation of geothermal fields in the United States. Geothermal fluids from hot springs and wells have been sampled from a number of locations, including: (1) the North Island of New Zealand (1 set of samples); (2) the Cascades of Oregon; (3) the Harney, Alvord Desert and Owyhee geothermal areas of Oregon; (4) the Dixie Valley and Beowawe fields in Nevada; (5) Palinpion, the Philippines: (6) the Salton Sea and Heber geothermal fields of southern California; and (7) the Dieng field in Central Java, Indonesia. We have analyzed the samples from all fields for REE except the last two.

  2. Study on the electrochemical extraction of rare earth elements from FLINAK

    SciTech Connect (OSTI)

    Long, Dewu; Huang, Wei; Jiang, Feng; Tian, Lifang; Li, Qingnuan

    2013-07-01

    Electrochemical behaviors of rare earth elements, such as NdF{sub 3}, GdF{sub 3}, SmF{sub 3}, YF{sub 3}, and EuF{sub 3}, were investigated in a LiF-NaF-KF (46.5-11.5-42.0 mol %, FLINAK, m. p. 454 Celsius degrees) solvent. The results indicated that it is possible to extract Nd, Gd and Y directly by electrochemical deposition since the reductions of those cations to metal are located in the electrochemical window of the FLINAK eutectic, while the reductions of Sm and Eu metal are out of the range of the medium. Subsequently electro-deposition of Nd was carried out with two kinds of cathodic materials, namely, an inert cathode, Pt, and a reactive electrode, Cu. The collected products were characterized by various techniques revealing that a Nd-rich product was obtained. (authors)

  3. Predictive model for ionic liquid extraction solvents for rare earth elements

    SciTech Connect (OSTI)

    Grabda, Mariusz; Oleszek, Sylwia; Panigrahi, Mrutyunjay; Kozak, Dmytro; Shibata, Etsuro; Nakamura, Takashi; Eckert, Franck

    2015-12-31

    The purpose of our study was to select the most effective ionic liquid extraction solvents for dysprosium (III) fluoride using a theoretical approach. Conductor-like Screening Model for Real Solvents (COSMO-RS), based on quantum chemistry and the statistical thermodynamics of predefined DyF{sub 3}-ionic liquid systems, was applied to reach the target. Chemical potentials of the salt were predicted in 4,400 different ionic liquids. On the base of these predictions set of ionic liquids’ ions, manifesting significant decrease of the chemical potentials, were selected. Considering the calculated physicochemical properties (hydrophobicity, viscosity) of the ionic liquids containing these specific ions, the most effective extraction solvents for liquid-liquid extraction of DyF{sub 3} were proposed. The obtained results indicate that the COSMO-RS approach can be applied to quickly screen the affinity of any rare earth element for a large number of ionic liquid systems, before extensive experimental tests.

  4. Bioadsorption of rare earth elements through cell surface display of lanthanide binding tags

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Park, Dan M.; Reed, David W.; Yung, Mimi C.; Eslamimanesh, Ali; Lencka, Malgorzata M.; Anderko, Andrzej; Fujita, Yoshiko; Riman, Richard E.; Navrotsky, Alexandra; Jiao, Yongqin

    2016-02-02

    In this study, with the increasing demand for rare earth elements (REEs) in many emerging clean energy technologies, there is an urgent need for the development of new approaches for efficient REE extraction and recovery. As a step toward this goal, we genetically engineered the aerobic bacterium Caulobacter crescentus for REE adsorption through high-density cell surface display of lanthanide binding tags (LBTs) on its S-layer. The LBT-displayed strains exhibited enhanced adsorption of REEs compared to cells lacking LBT, high specificity for REEs, and an adsorption preference for REEs with small atomic radii. Adsorbed Tb3+ could be effectively recovered using citrate,more » consistent with thermodynamic speciation calculations that predicted strong complexation of Tb3+ by citrate. No reduction in Tb3+ adsorption capacity was observed following citrate elution, enabling consecutive adsorption/desorption cycles. The LBT-displayed strain was effective for extracting REEs from the acid leachate of core samples collected at a prospective rare earth mine. Our collective results demonstrate a rapid, efficient, and reversible process for REE adsorption with potential industrial application for REE enrichment and separation.« less

  5. Rare earth element components in atmospheric particulates in the Bayan Obo mine region

    SciTech Connect (OSTI)

    Wang, Lingqing Liang, Tao Zhang, Qian; Li, Kexin

    2014-05-01

    The Bayan Obo mine, located in Inner Mongolia, China, is the largest light rare earth body ever found in the world. The research for rare earth elements (REEs) enrichment in atmospheric particulates caused by mining and ore processing is fairly limited so far. In this paper, atmospheric particulates including total suspended particulate (TSP) matter and particles with an equivalent aerodynamic diameter less than 10 μm (PM{sub 10}) were collected around the Bayan Obo mine region, in August 2012 and March 2013, to analyze the levels and distributions of REEs in particles. The total concentrations of REEs for TSP were 149.8 and 239.6 ng/m{sup 3}, and those for PM{sub 10} were 42.8 and 68.9 ng/m{sup 3}, in August 2012 and March 2013, respectively. Enrichment factor was calculated for all 14 REEs in the TSP and PM{sub 10} and the results indicated that REEs enrichment in atmosphere particulates was caused by anthropogenic sources and influenced by the strong wind in springtime. The spatial distribution of REEs in TSP showed a strong gradient concentration in the prevailing wind direction. REE chondrite normalized patterns of TSP and PM{sub 10} were similar and the normalized curves inclined to the right side, showing the conspicuous fractionation between the light REEs and heavy REE, which supported by the chondrite normalized concentration ratios calculated for selected elements (La{sub N}/Yb{sub N}, La{sub N}/Sm{sub N}, Gd{sub N}/Yb{sub N}). - Highlights: • TSP and PM{sub 10} samples were collected to analyze the levels and distributions of REE. • Enrichment factors indicated that REE enrichment was caused by anthropogenic sources. • The distribution of REEs showed a strong gradient in the prevailing wind direction. • Obvious fractionation between LREEs and HREEs is observed in atmospheric particulates.

  6. Rare earth element carriers in the Shergotty meteorite and implications for its chronology

    SciTech Connect (OSTI)

    Lundberg, L.L.; Crozaz, G.; Zinner, E. ); McKay, G. )

    1988-08-01

    Ion probe measurements of the rare earth element (REE) concentrations of individual grains of the Shergotty meteorite are reported. Phases analyzed include whitlockite, apatite, baddeleyite, augite, pigeonite, maskelynite and K-rich glass. U concentrations of whitlockite and apatite crystals were also obtained. The whole rock REE pattern is dominated by whitlockite, which contains over 95% of the light rare earth elements (LREE). REE concentrations in apatite are much lower than estimated by Laul et al. (1986). All of the whitlockites have the same relative abundances of LREE. The observation, by Jones et al. (1985), of a skeletal whitlockite with LREE enrichment is not confirmed by analyses of the same grain. Pyroxene rims are not enriched in LREE. No leachable carrier, enriched in LREE and associated with pyroxene, has been found. Instead, either a laboratory contamination or a petrographically cryptic phase such as a film on grain boundaries is suspected as the carrier of LREE enrichments. Estimates of REE abundances in the Shergotty intercumulus melt indicate that a complex petrogenesis is required, in agreement with the conclusions of McKay et al. (1986a). Pyroxene distribution coefficients measured experimentally are compared with estimates from measured REE abundances in augite and pigeonite. Evolution of REE abundances in the Shergotty late-stage interstitial melt, as inferred from analyses of whitlockite, conforms with trends predicted from partitioning considerations, and requires no special processes such as metasomatism. The average U concentrations of whitlockite and apatite are respectively 540 and 1,550 ppb. Although the calcium phosphates are enriched in U, they contain less than 20% of the U in Shergotty.

  7. Final Report US-Japan IEC Workshop on Small Plasma and Accelerator Neutron Sources

    SciTech Connect (OSTI)

    Miley, George, H.

    2008-06-04

    Abstract The history of IEC development will be briefly described, and some speculation about future directions will be offered. The origin of IEC is due to the brilliance of Phil Farnsworth, inventor of electronic TV in the US. Early experiments were pioneered in the late 1960s by Robert Hirsch who later became head of the DOE fusion program. At that time studies of IEC physics quickly followed at the University of Illinois and at Penn State University. However, despite many successes in this early work, IEC research died as DOE funding stopped in the mid 1980s. In the early 90’s, R. W. Bussard of EMC revived work with a new major project based on a magnetic assisted IEC. While doing supportive studies for that project, G. Miley proposed a grided “STAR mode” IEC as a neutron source for NAA. This concept was later used commercially by Daimler- Benz in Germany to analysis impurities in incoming ores. This represented a first practical application of the IEC. During this period other research groups at LANL, U of Wisconsin and Kyoto University entered IEC research with innovative new concepts and approaches to IEC physics and applications. Much of this work is documented in the present and in past US-Japan Workshops. At present we stand on the threshold of a new area of IEC applications as neutron source, for isotope production, and as a plasma source. These applications provide a way to continue IEC understanding and technology development with the ultimate goal being a fusion power plant. Indeed, a distinguishing feature of the IEC vs. other fusion confinement approaches is the unique opportunity for “spin off” applications along the way to a power producing plant.

  8. US-Japan energy policy dialogue. [Contains a list of attendees, agenda, report summaries, and a financial report

    SciTech Connect (OSTI)

    Guertin, Donald L.; Davis, W. Kenneth; Ikuta, Toyoaki

    1993-03-16

    The Atlantic Council has cooperated in an ongoing dialogue on energy policy issues with key Japanese organizations for the past twelve years. These Japanese organizations are the Committee for Energy Policy Promotion (CEPP) and the Institute of Energy Economics (IEE). The members of CEPP are major energy supplier and user companies. The IEE conducts sophisticated research and prepares policy papers on a range of international and Japanese energy issues. This energy dialogue is the only long-term US-Japan dialogue which engages CEPP/IEE members. Over the past twelve years the US-Japan energy dialogue has met seventeen times, with alternating meetings held in Tokyo, Hawaii, and Washington, DC. While the dialogue is a private sector activity, US and Japanese government officials are kept informed on the program and are invited to participate in the meetings in Washington and Tokyo. Major benefits of this activity have included: Establishment of close working relationships among Japanese and US private sector energy institutions and experts; exchange of papers on energy issues among participants and on a selected basis to others in the private and governmental sectors; facilitation of separate US-Japanese work on policy issues - for example a joint US-Japan cooperative policy paper on global climate change published in 1991, some government representatives participated in a May 1991 meeting on this subject. Encouragement of Japanese participation in separate Atlantic Council programs on US energy policy imperatives (1990); technology cooperation with developing countries in the field of energy supply and use for sustainable development (1992); creation of a World Energy Efficiency Association (1993); and a US-Japan-Newly Independent States project on NIS energy policy (1992--1994).

  9. Improved estimates of rare K decay matrix elements from K{sub l3} decays

    SciTech Connect (OSTI)

    Mescia, Federico; Smith, Christopher

    2007-08-01

    The estimation of rare K decay matrix elements from K{sub l3} experimental data is extended beyond LO in chiral perturbation theory. Isospin-breaking effects at next-to-leading order (and partially next-to-next-to-leading order) in the chiral perturbation theory expansion, as well as QED radiative corrections, are now accounted for. The analysis relies mainly on the cleanness of two specific ratios of form factors, for which the theoretical control is excellent. As a result, the uncertainties on the K{sup +}{yields}{pi}{sup +}{nu}{nu} and K{sub L}{yields}{pi}{sup 0}{nu}{nu} matrix elements are reduced by a factor of about 7 and 4, respectively, and similarly for the direct CP-violating contributions to K{sub L}{yields}{pi}{sup 0}e{sup +}e{sup -} and K{sub L}{yields}{pi}{sup 0}{mu}{sup +}{mu}{sup -}. They could be reduced even further with better experimental data for the K{sub l3} slopes and the K{sub l3}{sup +} branching ratios. As a result, the nonparametric errors for B(K{yields}{pi}{nu}{nu}) and for the direct CP-violating contributions to B(K{sub L}{yields}{pi}{sup 0}l{sup +}l{sup -}) are now completely dominated by those on the short-distance physics.

  10. Rare earth elements and critical metal content of extracted landfilled material and potential recovery opportunities

    SciTech Connect (OSTI)

    Gutiérrez-Gutiérrez, Silvia C.; Coulon, Frédéric; Jiang, Ying; Wagland, Stuart

    2015-08-15

    Highlights: • Samples from multiple core drills were obtained from 4× landfill sites in the UK. • Each sample analysed for rare earth elements, critical metals and valuable metals. • Two stage microwave digestion method ensuring high yield. • High quantities of copper and aluminium were observed in the soil layers of landfill. • Across 4× landfills aluminium and copper present has a value of around $400 million. - Abstract: Rare earth elements (REEs), Platinum group metals (PGMs) and other critical metals currently attract significant interest due to the high risks of supply shortage and substantial impact on the economy. Their uses in many applications have made them present in municipal solid waste (MSW) and in commercial and industrial waste (C&I), since several industrial processes produce by-products with high content of these metals. With over 4000 landfills in the UK alone, the aim of this study was to assess the existence of these critical metals within landfills. Samples collected from four closed landfills in UK were subjected to a two-step acid digestion to extract 27 metals of interest. Concentrations across the four landfill sites were 58 ± 6 mg kg{sup −1} for REEs comprising 44 ± 8 mg kg{sup −1} for light REEs, 11 ± 2 mg kg{sup −1} for heavy REEs and 3 ± 1 mg kg{sup −1} for Scandium (Sc) and 3 ± 1.0 mg kg{sup −1} of PGMs. Compared to the typical concentration in ores, these concentrations are too low to achieve a commercially viable extraction. However, content of other highly valuable metals (Al and Cu) was found in concentrations equating to a combined value across the four landfills of around $400 million, which increases the economic viability of landfill mining. Presence of critical metals will mainly depend on the type of waste that was buried but the recovery of these metals through landfill mining is possible and is economically feasible only if additional materials (plastics, paper, metallic items and other) are

  11. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect (OSTI)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at a proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ

  12. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore » proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir

  13. Rare earth element geochemistry of outcrop and core samples from the Marcellus Shale

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Noack, Clinton W.; Jain, Jinesh C.; Stegmeier, John; Hakala, J. Alexandra; Karamalidis, Athanasios K.

    2015-06-26

    In this paper, we studied the geochemistry of the rare earth elements (REE) in eleven outcrop samples and six, depth-interval samples of a core from the Marcellus Shale. The REE are classically applied analytes for investigating depositional environments and inferring geochemical processes, making them of interest as potential, naturally occurring indicators of fluid sources as well as indicators of geochemical processes in solid waste disposal. However, little is known of the REE occurrence in the Marcellus Shale or its produced waters, and this study represents one of the first, thorough characterizations of the REE in the Marcellus Shale. In thesemore » samples, the abundance of REE and the fractionation of REE profiles were correlated with different mineral components of the shale. Namely, samples with a larger clay component were inferred to have higher absolute concentrations of REE but have less distinctive patterns. Conversely, samples with larger carbonate fractions exhibited a greater degree of fractionation, albeit with lower total abundance. Further study is necessary to determine release mechanisms, as well as REE fate-and-transport, however these results have implications for future brine and solid waste management applications.« less

  14. Selective Extraction of Rare Earth Elements from Permanent Magnet Scraps with Membrane Solvent Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Daejin; Powell, Lawrence E.; Delmau, Lætitia H.; Peterson, Eric S.; Herchenroeder, Jim; Bhave, Ramesh R.

    2015-06-24

    In this paper, the rare earth elements (REEs) such as neodymium, praseodymium, and dysprosium were successfully recovered from commercial NdFeB magnets and industrial scrap magnets via membrane assisted solvent extraction (MSX). A hollow fiber membrane system was evaluated to extract REEs in a single step with the feed and strip solutions circulating continuously through the MSX system. The effects of several experimental variables on REE extraction such as flow rate, concentration of REEs in the feed solution, membrane configuration, and composition of acids were investigated with the MSX system. A multimembrane module configuration with REEs dissolved in aqueous nitric acidmore » solutions showed high selectivity for REE extraction with no coextraction of non-REEs, whereas the use of aqueous hydrochloric acid solution resulted in coextraction of non-REEs due to the formation of chloroanions of non-REEs. The REE oxides were recovered from the strip solution through precipitation, drying, and annealing steps. Finally, the resulting REE oxides were characterized with XRD, SEM-EDX, and ICP-OES, demonstrating that the membrane assisted solvent extraction is capable of selectively recovering pure REEs from the industrial scrap magnets.« less

  15. Rare earth element geochemistry of outcrop and core samples from the Marcellus Shale

    SciTech Connect (OSTI)

    Noack, Clinton W.; Jain, Jinesh C.; Stegmeier, John; Hakala, J. Alexandra; Karamalidis, Athanasios K.

    2015-06-26

    In this paper, we studied the geochemistry of the rare earth elements (REE) in eleven outcrop samples and six, depth-interval samples of a core from the Marcellus Shale. The REE are classically applied analytes for investigating depositional environments and inferring geochemical processes, making them of interest as potential, naturally occurring indicators of fluid sources as well as indicators of geochemical processes in solid waste disposal. However, little is known of the REE occurrence in the Marcellus Shale or its produced waters, and this study represents one of the first, thorough characterizations of the REE in the Marcellus Shale. In these samples, the abundance of REE and the fractionation of REE profiles were correlated with different mineral components of the shale. Namely, samples with a larger clay component were inferred to have higher absolute concentrations of REE but have less distinctive patterns. Conversely, samples with larger carbonate fractions exhibited a greater degree of fractionation, albeit with lower total abundance. Further study is necessary to determine release mechanisms, as well as REE fate-and-transport, however these results have implications for future brine and solid waste management applications.

  16. Selective Extraction of Rare Earth Elements from Permanent Magnet Scraps with Membrane Solvent Extraction

    SciTech Connect (OSTI)

    Kim, Daejin; Powell, Lawrence E.; Delmau, Lætitia H.; Peterson, Eric S.; Herchenroeder, Jim; Bhave, Ramesh R.

    2015-06-24

    In this paper, the rare earth elements (REEs) such as neodymium, praseodymium, and dysprosium were successfully recovered from commercial NdFeB magnets and industrial scrap magnets via membrane assisted solvent extraction (MSX). A hollow fiber membrane system was evaluated to extract REEs in a single step with the feed and strip solutions circulating continuously through the MSX system. The effects of several experimental variables on REE extraction such as flow rate, concentration of REEs in the feed solution, membrane configuration, and composition of acids were investigated with the MSX system. A multimembrane module configuration with REEs dissolved in aqueous nitric acid solutions showed high selectivity for REE extraction with no coextraction of non-REEs, whereas the use of aqueous hydrochloric acid solution resulted in coextraction of non-REEs due to the formation of chloroanions of non-REEs. The REE oxides were recovered from the strip solution through precipitation, drying, and annealing steps. Finally, the resulting REE oxides were characterized with XRD, SEM-EDX, and ICP-OES, demonstrating that the membrane assisted solvent extraction is capable of selectively recovering pure REEs from the industrial scrap magnets.

  17. Rare earth elements in chloride-rich groundwater, Palo Duro Basin, Texas, USA

    SciTech Connect (OSTI)

    Gosselin, D.C. ); Smith, M.R.; Lepel, E.A. ); Laul, J.C. )

    1992-04-01

    Rare earth element (REE) data for groundwater samples from the Deep-Basin Brine aquifer of the Palo Duro Basin, Texas, USA, illustrates the potential use of REE for inferring groundwater flow paths through different geologic materials. The REE content of the groundwaters range over 2.5 orders of magnitude and are depleted by 10{sup 2} to 10{sup 5} relative to aquifer materials. The shale-normalized REE patterns for groundwater that have primarily interacted with arkosic sandstones (granite wash) are flat with similar heavy REE (HREE) enrichments ((Lu/La){sub n} = 0.60 to 0.80). The samples with highest REE contents and REE patterns, which are enriched in the intermediate REEs (IREEs; Sm-Tb) reflect variable degrees of interaction with carbonate rocks. The IREE enrichment is the result of fluid interaction with Fe-Mn coatings on carbonate minerals and/or secondary minerals in fractures and vugs. The chloride complex. (LnCl{sup 2+}), and free-ions are the predominant REE species, accounting for over 95% of the REEs. Carbonate and sulfate species account for the other 5% and have very little influence on the behavior of the REEs. Although this study indicates a potentially important role for the REEs in understanding geochemical transport and groundwater movement, it also indicates the necessity for developing a better understanding of REE speciation in high ionic strength solutions.

  18. Drill core major, trace and rare earth element anlayses from wells RN-17B and RN-30, Reykjanes, Iceland

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Andrew Fowler

    2015-04-01

    Analytical results for X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) measurement of major, trace and rare earth elements in drill core from geothermal wells in Reykjanes, Iceland. Total Fe was analyzed as FeO, therefore is not included under the Fe2O3 column.

  19. β-decay of neutron-rich Z∼60 nuclei and the origin of rare earth elements

    SciTech Connect (OSTI)

    Wu, J.; Nishimura, S.; Lorusso, G.; Baba, H.; Doornenbal, P.; Isobe, T.; Söderström, P. A.; Sakurai, H.; Xu, Z. Y.; Browne, F.; Daido, R.; Fang, Y. F.; Yagi, A.; Nishibata, H.; Odahara, A.; Yamamoto, T.; Ideguchi, E.; Aoi, N.; Tanaka, M.; Collaboration: EURICA Collaboration; and others

    2014-05-02

    A large fraction of the rare-earth elements observed in the solar system is produced in the astrophysical rapid neutron capture process (r-process). However, current stellar models cannot completely explain the relative abundance of these elements partially because of nuclear physics uncertainties. To address this problem, a β-decay spectroscopy experiment was performed at RI Beam Factory (RIBF) at RIKEN, aimed at studying a wide range of very neutron-rich nuclei with Z∼60 that are progenitors of the rare-earth elements with mass number A∼460. The experiment provides a test of nuclear models as well as experimental inputs for r-process calculations. This contribution presents the experimental setup and some preliminary results of the experiment.

  20. Extraction processes and solvents for recovery of cesium, strontium, rare earth elements, technetium and actinides from liquid radioactive waste

    DOE Patents [OSTI]

    Zaitsev, Boris N.; Esimantovskiy, Vyacheslav M.; Lazarev, Leonard N.; Dzekun, Evgeniy G.; Romanovskiy, Valeriy N.; Todd, Terry A.; Brewer, Ken N.; Herbst, Ronald S.; Law, Jack D.

    2001-01-01

    Cesium and strontium are extracted from aqueous acidic radioactive waste containing rare earth elements, technetium and actinides, by contacting the waste with a composition of a complex organoboron compound and polyethylene glycol in an organofluorine diluent mixture. In a preferred embodiment the complex organoboron compound is chlorinated cobalt dicarbollide, the polyethylene glycol has the formula RC.sub.6 H.sub.4 (OCH.sub.2 CH.sub.2).sub.n OH, and the organofluorine diluent is a mixture of bis-tetrafluoropropyl ether of diethylene glycol with at least one of bis-tetrafluoropropyl ether of ethylene glycol and bis-tetrafluoropropyl formal. The rare earths, technetium and the actinides (especially uranium, plutonium and americium), are extracted from the aqueous phase using a phosphine oxide in a hydrocarbon diluent, and reextracted from the resulting organic phase into an aqueous phase by using a suitable strip reagent.

  1. Aluminoborosilicate glasses codoped with rare-earth elements as radiation-protective covers for solar cells

    SciTech Connect (OSTI)

    Malchukova, E. V. Abramov, A. S.; Nepomnyashchikh, A. I.; Terukov, E. I.

    2015-06-15

    The radiation hardness of aluminoborosilicate glasses codoped with rare-earth ions of Sm, Gd or Sm, Eu in various ratios is studied. The effect of codoping and β irradiation at a dose of 10{sup 9} Gr on the optical transmission and electron paramagnetic resonance spectra is examined. It is found that the introduction of Sm and Gd codopants in a 1 : 1 ratio reduces the number of radiation defects and raises the transmission of irradiated glasses in the visible spectral range.

  2. Proceedings of US/Japan workshop, Q219 on high heat flux components and plasma surface interactions for next fusion devices

    SciTech Connect (OSTI)

    Ulrickson, M.A.; Stevens, P.L.; Hino, T.; Hirohata, Y.

    1996-12-01

    This report contains the viewgraphs from the proceedings of US/Japan Workshop on High Heat Flux Components and Plasma Surface Interactions for Next Fusion Devices. Some of the general topics covered by this report are: PFC/PSI in tokamak and helical devices; development of high heat flux components; PSIS and plasma facing materials;tritium; and material damage.

  3. Precious metals and rare earth elements in municipal solid waste – Sources and fate in a Swiss incineration plant

    SciTech Connect (OSTI)

    Morf, Leo S.; Gloor, Rolf; Haag, Olaf; Haupt, Melanie; Skutan, Stefan; Lorenzo, Fabian Di; Böni, Daniel

    2013-03-15

    Highlights: ► We carefully addressed all the very valuable comments and suggestions of the reviewers. ► We also have shortened the size of the paper and tried simplify it substantially, as requested by the reviewers (introduction 25% reduced!). ► We have decided to take the chance and have replaced the data for the “additional” elements (Cu, Cd, Zn, Pb, Sn, Cr, Ni, Fe, Al) of the earlier MFA (Morf, 2011) with data that belong to the samples of this study. ► We are convinced that with the revision the paper has significantly improved in quality and attractiveness. - Abstract: In Switzerland many kinds of waste, e.g. paper, metals, electrical and electronic equipment are separately collected and recycled to a large extent. The residual amount of municipal solid waste (MSW) has to be thermally treated before final disposal. Efforts to recover valuable metals from incineration residues have recently increased. However, the resource potential of critical elements in the waste input (sources) and their partitioning into recyclable fractions and residues (fate) is unknown. Therefore, a substance flow analysis (SFA) for 31 elements including precious metals (Au, Ag), platinum metal group elements (Pt, Rh) and rare earth elements (La, Ce, etc.) has been conducted in a solid waste incinerator (SWI) with a state-of-the-art bottom ash treatment according to the Thermo-Re® concept. The SFA allowed the determination of the element partitioning in the SWI, as well as the elemental composition of the MSW by indirect analysis. The results show that the waste-input contains substantial quantities of precious metals, such as 0.4 ± 0.2 mg/kg Au and 5.3 ± 0.7 mg/kg Ag. Many of the valuable substances, such as Au and Ag are enriched in specific outputs (e.g. non-ferrous metal fractions) and are therefore recoverable. As the precious metal content in MSW is expected to rise due to its increasing application in complex consumer products, the results of this study are

  4. Rare-earth elements in hot brines (165 to 190 degree C) from the Salton Sea geothermal field

    SciTech Connect (OSTI)

    Lepel, E.A.; Laul, J.C.; Smith, M.R.

    1988-01-01

    Rare-earth element (REE) concentrations are important indicators for revealing various chemical fractionation processes (water/rock interactions) and source region geochemistry. Since the REE patterns are characteristic of geologic materials (basalt, granite, shale, sediments, etc.) and minerals (K-feldspar, calcite, illite, epidote, etc.), their study in geothermal fluids may serve as a geothermometer. The REE study may also enable us to address the issue of groundwater mixing. In addition, the behavior of the REE can serve as analogs of the actinides in radioactive waste (e.g., neodymium is an analog of americium and curium). In this paper, the authors port the REE data for a Salton Sea Geothermal Field (SSGF) brine (two aliquots: port 4 at 165{degree}C and port 5 at 190{degree}C) and six associated core samples.

  5. Partitioning and Leaching Behavior of Actinides and Rare Earth Elements in a Zirconolite- Bearing Hydrothermal Vein System

    SciTech Connect (OSTI)

    Payne, Timothy E.; Hart, Kaye P.; Lumpkin, Gregory R.; McGlinn, Peter J.; Giere, Reto

    2007-07-01

    Chemical extraction techniques and scanning electron microscopy were used to study the distribution and behavior of actinides and rare earth elements (REE) in hydrothermal veins at Adamello (Italy). The six samples discussed in this paper were from the phlogopite zone, which is one of the major vein zones. The samples were similar in their bulk chemical composition, mineralogy, and leaching behavior of major elements (determined by extraction with 9 M HCl). However, there were major differences in the extractability of REE and actinides. The most significant influence on the leaching characteristics appears to be the amounts of U, Th and REE incorporated in resistant host phases (zirconolite and titanite) rather than readily leached phases (such as apatite). Uranium and Th are very highly enriched in zirconolite grains. Actinides were more readily leached from samples with a higher content of U and Th, relative to the amount of zirconium. The results show that REE and actinides present in chemically resistant host minerals can be retained under aggressive leaching conditions. (authors)

  6. Fluid rare earth element anlayses from geothermal wells located on the Reykjanes Peninsula, Iceland and Middle Valley seafloor hydrothermal system on the Juan de Fuca Ridge.

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Andrew Fowler

    2015-05-01

    Results for fluid rare earth element analyses from four Reykjanes peninsula high-temperature geothermal fields. Data for fluids from hydrothermal vents located 2400 m below sea level from Middle Valley on the Juan de Fuca Ridge are also included. Data have been corrected for flashing. Samples preconcentrated using a chelating resin with IDA functional group (InertSep ME-1). Analyzed using an Element magnetic sector inductively coupled plasma mass spectrometry (ICP-MS).

  7. Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature

    SciTech Connect (OSTI)

    Li, Jiawei; Huo, Juntao; Chang, Chuntao E-mail: dujun@nimte.ac.cn; Du, Juan E-mail: dujun@nimte.ac.cn; Man, Qikui; Wang, Xinmin; Li, Run-Wei; Law, Jiayan

    2014-08-14

    The effects of heavy rare earth (RE) additions on the Curie temperature (T{sub C}) and magnetocaloric effect of the Fe-RE-B-Nb (RE = Gd, Dy and Ho) bulk metallic glasses were studied. The type of dopping RE element and its concentration can easily tune T{sub C} in a large temperature range of 120 K without significantly decreasing the magnetic entropy change (ΔS{sub M}) and refrigerant capacity (RC) of the alloys. The observed values of ΔS{sub M} and RC of these alloys compare favorably with those of recently reported Fe-based metallic glasses with enhanced RC compared to Gd{sub 5}Ge{sub 1.9}Si{sub 2}Fe{sub 0.1}. The tunable T{sub C} and large glass-forming ability of these RE doped Fe-based bulk metallic glasses can be used in a wide temperature range with the final required shapes.

  8. Drill cutting and core major, trace and rare earth element anlayses from wells RN-17B and RN-30, Reykjanes, Iceland

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Andrew Fowler

    2015-05-01

    Analytical results for x-ray fluorescence (XRF) and Inductively Couple Plasma Mass Spectrometry (ICP-MS) measurement of major, trace and rare earth elements in drill cuttings from geothermal wells in Reykjanes, Iceland. Total Fe was analyzed as FeO, therefore is not included under the Fe2O3 column.

  9. Detection of rare earth elements in Powder River Basin sub-bituminous coal ash using laser-induced breakdown spectroscopy (LIBS)

    SciTech Connect (OSTI)

    Tran, Phuoc

    2015-10-01

    We reported our preliminary results on the use of laser-induced breakdown spectroscopy to analyze the rare earth elements contained in ash samples from Powder River Basin sub-bituminous coal (PRB-coal). We have identified many elements in the lanthanide series (cerium, europium, holmium, lanthanum, lutetium, praseodymium, promethium, samarium, terbium, ytterbium) and some elements in the actinide series (actinium, thorium, uranium, plutonium, berkelium, californium) in the ash samples. In addition, various metals were also seen to present in the ash samples

  10. Am phases in the matrix of a U–Pu–Zr alloy with Np, Am, and rare-earth elements

    SciTech Connect (OSTI)

    Janney, Dawn E.; Kennedy, J. Rory; Madden, James W.; O’Holleran, Thomas P.

    2015-01-01

    Phases and microstructures in the matrix of an as-cast U-Pu-Zr alloy with 3 wt% Am, 2% Np, and 8% rare-earth elements were characterized by scanning and transmission electron microscopy. The matrix consists primarily of two phases, both of which contain Am: ζ-(U, Np, Pu, Am) (~70 at% U, 5% Np, 14% Pu, 1% Am, and 10% Zr) and δ-(U, Np, Pu, Am)Zr2 (~25% U, 2% Np, 10-15% Pu, 1-2% Am, and 55-60 at% Zr). These phases are similar to those in U-Pu-Zr alloys, although the Zr content in ζ-(U, Np, Pu, Am) is higher than that in ζ-(U, Pu) and the Zr content in δ-(U, Np, Pu, Am)Zr2 is lower than that in δ-UZr2. Nanocrystalline actinide oxides with structures similar to UO2 occurred in some areas, but may have formed by reactions with the atmosphere during sample handling. Planar features consisting of a central zone of ζ-(U, Np, Pu, Am) bracketed by zones of δ-(U, Np, Pu, Am)Zr2 bound irregular polygons ranging in size from a few micrometers to a few tens of micrometers across. The rest of the matrix consists of elongated domains of ζ-(U, Np, Pu, Am) and δ-(U, Np, Pu, Am)Zr2. Each of these domains is a few tens of nanometers across and a few hundred nanometers long. The domains display strong preferred orientations involving areas a few hundred nanometers to a few micrometers across.

  11. Rare Earth Metals & Alloys | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Metals & Alloys Quantities of high-purity rare earth metals and alloys in ... storage, cutting and cleaning and SDS information for the rare earth elements (metals).

  12. Thorium, uranium and rare earth elements content in lanthanide concentrate (LC) and water leach purification (WLP) residue of Lynas advanced materials plant (LAMP)

    SciTech Connect (OSTI)

    AL-Areqi, Wadeeah M. Majid, Amran Ab. Sarmani, Sukiman

    2014-02-12

    Lynas Advanced Materials Plant (LAMP) has been licensed to produce the rare earths elements since early 2013 in Malaysia. LAMP processes lanthanide concentrate (LC) to extract rare earth elements and subsequently produce large volumes of water leach purification (WLP) residue containing naturally occurring radioactive material (NORM). This residue has been rising up the environmental issue because it was suspected to accumulate thorium with significant activity concentration and has been classified as radioactive residue. The aim of this study is to determine Th-232, U-238 and rare earth elements in lanthanide concentrate (LC) and water leach purification (WLP) residue collected from LAMP and to evaluate the potential radiological impacts of the WLP residue on the environment. Instrumental Neutron Activation Analysis and γ-spectrometry were used for determination of Th, U and rare earth elements concentrations. The results of this study found that the concentration of Th in LC was 1289.7 ± 129 ppm (5274.9 ± 527.6Bq/kg) whereas the Th and U concentrations in WLP were determined to be 1952.9±17.6 ppm (7987.4 ± 71.9 Bq/kg) and 17.2 ± 2.4 ppm respectively. The concentrations of Th and U in LC and WLP samples determined by γ- spectrometry were 1156 ppm (4728 ± 22 Bq/kg) and 18.8 ppm and 1763.2 ppm (7211.4 Bq/kg) and 29.97 ppm respectively. This study showed that thorium concentrations were higher in WLP compare to LC. This study also indicate that WLP residue has high radioactivity of {sup 232}Th compared to Malaysian soil natural background (63 - 110 Bq/kg) and come under preview of Act 304 and regulations. In LC, the Ce and Nd concentrations determined by INAA were 13.2 ± 0.6% and 4.7 ± 0.1% respectively whereas the concentrations of La, Ce, Nd and Sm in WLP were 0.36 ± 0.04%, 1.6%, 0.22% and 0.06% respectively. This result showed that some amount of rare earth had not been extracted and remained in the WLP and may be considered to be reextracted.

  13. Trace rare earth element analysis of IAEA hair (HH-1), animal bone (H-5) and other biological standards by radiochemical neutron activation

    SciTech Connect (OSTI)

    Lepel, E.A.; Laul, J.C.

    1986-03-01

    A radiochemical neutron activation analysis using a rare earth group separation scheme has been used to measure ultratrace levels of rare earth elements (REE) in IAEA Human Hair (HH-1), IAEA Animal Bone (H-5), NBS Bovine Liver (SRM 1577), and NBS Orchard Leaf (SRM 1571) standards. The REE concentrations in Human Hair and Animal Bone range from 10/sup -8/g/g to 10/sup -11/g/g and their chondritic normalized REE patterns show a negative Eu anomaly and follow as a smooth function of the REE ionic radii. The REE patterns for NBS Bovine Liver and Orchard Leaf are identical except that their concentrations are higher. The similarity among the REE patterns suggest that the REE do not appear to be fractionated during the intake of biological materials by animals or humans. 14 refs., 3 figs., 2 tabs.

  14. Element

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Departmental Element 2. System Name/ Major Application Name 3. Location 4. Name of System Owner/ Information or Data Owner 5. Contact Information 6. Does the system collect or maintain Social Security numbers? 7. Source of Legal Requirement/Authority to Collect or Maintain Social Security Numbers? 8. Does the system have a Privacy Impact Assessment (PIA)? 9. Does the system have a System of Records Notice (SORN)? If yes, provide the name of the System of Records Notice. 10. Does the system

  15. Crystal structure of high-Zr inclusions in an alloy containing U, Pu, Np, Am, Zr and rare-earth elements

    SciTech Connect (OSTI)

    Dawn E. Janney; James W. Madden; J. Rory Kennedy; Thomas P. O'Holleran

    2014-05-01

    Researchers commonly observe high-Zr inclusions in actinide-Zr alloys. As there is very little published data on the crystal structures of these inclusions, it has generally been assumed that the inclusions were impurity-stabilized a-Zr. However, new electron-diffraction data from two high-Zr inclusions in an alloy containing U, Pu, Np, Am, Zr, and rare-earth elements show that these inclusions are not a-Zr (which has a hexagonal structure) but instead have a face-centered cubic structure. This data is unique in that it combines single-crystal diffraction patterns and microchemical analyses from individual inclusions. More data on other high-Zr inclusions is clearly required. However, the present results suggest that caution is needed in assuming that all high-Zr inclusions in actinide-Zr alloys are a-Zr.

  16. As-cast microstructures in U-Pu-Zr alloy fuel pins with 5-8 wt% minor actinides and 0-1.5 wt% rare-earth elements

    SciTech Connect (OSTI)

    Dawn E. Janney; J. Rory Kennedy

    2010-11-01

    The Idaho National Laboratory (INL) is investigating U–Pu–Zr alloys with low concentrations of minor actinides (Np and Am) and rare-earth elements (La, Ce, Pr, and Nd) as possible nuclear fuels to be used to transmute minor actinides. Alloys with compositions 60U–20Pu– 3Am–2Np–15Zr, 42U–30Pu–5Am–3Np–20Zr, 59U–20Pu–3Am–2Np–1RE–15Zr, 58.5U–20Pu– 3Am–2Np–1.5RE–15Zr, 41U–30Pu–5Am–3Np–1RE–20Zr, and 40.5U–30Pu–5Am–3Np–1.5RE– 20Zr (where numbers represent weight percents of each element and RE is a rare-earth alloy consisting of 6% La, 16% Pr, 25% Ce, and 53% Nd by weight) were arc-melted and vacuum cast as fuel pins approximately 4 mmin diameter. The as-cast pins were sectioned, polished, and examined by scanning electron microscopy. Each alloy contains high-Zr inclusions surrounded by a high-actinide matrix. Alloys with rare-earth elements also contain inclusions that are high in these elements. Within the matrix, concentrations of U and Zr vary inversely, while concentrations of Np and Pu appear approximately constant. Am occurs in the matrix and with some high-rare-earth inclusions, and occasionally as high-Am inclusions in samples without rare-earth elements.

  17. As-cast microstructures in U-Pu-Zr alloy fuel pins with 5-8 wt.% minor actinides and 0-1.5 wt% rare-earth elements

    SciTech Connect (OSTI)

    Janney, Dawn E. Kennedy, J. Rory

    2010-11-15

    The Idaho National Laboratory (INL) is investigating U-Pu-Zr alloys with low concentrations of minor actinides (Np and Am) and rare-earth elements (La, Ce, Pr, and Nd) as possible nuclear fuels to be used to transmute minor actinides. Alloys with compositions 60U-20Pu-3Am-2Np-15Zr, 42U-30Pu-5Am-3Np-20Zr, 59U-20Pu-3Am-2Np-1RE-15Zr, 58.5U-20Pu-3Am-2Np-1.5RE-15Zr, 41U-30Pu-5Am-3Np-1RE-20Zr, and 40.5U-30Pu-5Am-3Np-1.5RE-20Zr (where numbers represent weight percents of each element and RE is a rare-earth alloy consisting of 6% La, 16% Pr, 25% Ce, and 53% Nd by weight) were arc-melted and vacuum cast as fuel pins approximately 4 mm in diameter. The as-cast pins were sectioned, polished, and examined by scanning electron microscopy. Each alloy contains high-Zr inclusions surrounded by a high-actinide matrix. Alloys with rare-earth elements also contain inclusions that are high in these elements. Within the matrix, concentrations of U and Zr vary inversely, while concentrations of Np and Pu appear approximately constant. Am occurs in the matrix and with some high-rare-earth inclusions, and occasionally as high-Am inclusions in samples without rare-earth elements. - Research Highlights: {yields}Microstructures consist of high-Zr inclusions surrounded by a high-actinide matrix. {yields}Alloys with rare-earth (RE) elements contain inclusions that are high in REs. {yields}Concentrations of U and Zr vary inversely in the matrix. {yields}Am occurs in the matrix and with high-RE inclusions.

  18. Information basis for developing comprehensive waste management system-US-Japan joint nuclear energy action plan waste management working group phase I report.

    SciTech Connect (OSTI)

    Nutt, M.; Nuclear Engineering Division

    2010-05-25

    The activity of Phase I of the Waste Management Working Group under the United States - Japan Joint Nuclear Energy Action Plan started in 2007. The US-Japan JNEAP is a bilateral collaborative framework to support the global implementation of safe, secure, and sustainable, nuclear fuel cycles (referred to in this document as fuel cycles). The Waste Management Working Group was established by strong interest of both parties, which arise from the recognition that development and optimization of waste management and disposal system(s) are central issues of the present and future nuclear fuel cycles. This report summarizes the activity of the Waste Management Working Group that focused on consolidation of the existing technical basis between the U.S. and Japan and the joint development of a plan for future collaborative activities. Firstly, the political/regulatory frameworks related to nuclear fuel cycles in both countries were reviewed. The various advanced fuel cycle scenarios that have been considered in both countries were then surveyed and summarized. The working group established the working reference scenario for the future cooperative activity that corresponds to a fuel cycle scenario being considered both in Japan and the U.S. This working scenario involves transitioning from a once-through fuel cycle utilizing light water reactors to a one-pass uranium-plutonium fuel recycle in light water reactors to a combination of light water reactors and fast reactors with plutonium, uranium, and minor actinide recycle, ultimately concluding with multiple recycle passes primarily using fast reactors. Considering the scenario, current and future expected waste streams, treatment and inventory were discussed, and the relevant information was summarized. Second, the waste management/disposal system optimization was discussed. Repository system concepts were reviewed, repository design concepts for the various classifications of nuclear waste were summarized, and the factors

  19. Grain refinement in heavy rare earth element-free sintered Nd–Fe–B magnets by addition of a small amount of molybdenum

    SciTech Connect (OSTI)

    Kim, Jin Woo; Lee, Won Suk; Byun, Jong Min; Kim, Young Do; Kim, Se Hoon

    2015-05-07

    We employed a modified refractory-metal-addition method to achieve higher coercivity and remanence in heavy rare earth element (HREE)-free Nd–Fe–B sintered magnets. This process involved inducing the formation of a homogeneous secondary phase at the grain boundaries during sintering, making it possible to control the intergrain diffusion by adding small amounts of Mo, a refractory metal. To control the microstructure of the secondary phase effectively, a metal organic compound of the refractory metal was coated on the surfaces of the particles of an HREE-free Nd–Fe–B powder. The average grain size after this process was 5.60 μm, which was approximately 1.8 μm smaller than that of the HREE-free sintered Nd–Fe–B magnets (7.4 μm). The coercivity of the magnets prepared through this process could be increased from 11.88 kOe to 13.91 kOe without decreasing their remanence.

  20. A rare opportunity beckons

    SciTech Connect (OSTI)

    Gschneidner, K

    2011-02-01

    There is a great deal of uncertainty for the future of rare-earth production. Rare-earths are a collection of 17 chemical elements in the periodic table, which include scandium and yttrium as well as the 15 lanthanides, such as dysprosium and ytterbium. China has a stranglehold on today's rare-earth market, which was worth about $3bn in 2010, with the country accounting for about 95% of worldwide production. Yet China's future actions can only be guessed at best. In September it halted shipments of rare-earth elements to Japan over a diplomatic spat concerning the detention of a Chinese trawler captain. Although the ban was later lifted, the episode raised concerns around the world about China's rare-earth monopoly and its use in diplomacy. China has already warned that it will not export any rare-earth material in the coming years as it expects its own consumption of rare-earth metals to increase. The country has introduced export taxes as well as production and export quotas, and also refused to grant any new rare-earth mining licences. Furthermore, because its reserves are limited and China's internal markets are growing so rapidly, the country has suggested it will no longer export products that require rare-earth elements, especially those that need heavy rare-earth elements, such as terbium and dysprosium. China's actions have led to huge rises in the cost of rare-earth materials and products. Dysprosium oxide, for example, has shot up from $36 per kilogram in 2005 to a massive $305 per kilogram by late last year. This could have a huge impact on much of today's electronics industry, given that rare-earth elements are ubiquitous in electric motors, computers, batteries, liquid-crystal displays (LCDs) and mobile phones. Neodymium-iron-boron permanent magnets, for example, are used as computer spindle drives. The question is: what can be done to ensure that China's dominance of the rare-earth industry does not affect the military and energy security of the US

  1. ORNL Licenses Rare Earth Magnet Recycling Process to Momentum...

    Office of Environmental Management (EM)

    ORNL Licenses Rare Earth Magnet Recycling Process to Momentum Technologies ORNL Licenses ... Dallas-based Momentum Technologies is focused on extraction of rare earth elements and ...

  2. Rare Earth Metals for Science | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Metals for Science The Ames Laboratory has been actively involved in the ... More information on the rare-earth elements Quantities of high-purity rare earth metals ...

  3. Phase stable rare earth garnets

    SciTech Connect (OSTI)

    Kuntz, Joshua D.; Cherepy, Nerine J.; Roberts, Jeffery J.; Payne, Stephen A.

    2013-06-11

    A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.

  4. Crosscutting Research & Rare Earth Elements Portfolios Review...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Inc., James Pschirer Novel Functional Graded Thermal Barrier Coatings in Coal-fired Power Plant Turbines Babcock & Wilcox Power Generation Group, Inc., Paul S. Weitzel ...

  5. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R.W.; Ellis, T.W.; Dennis, K.W.; Hofer, R.J.; Branagan, D.J.

    1997-11-25

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g., a transition metal and optional boron), and a carbide-forming element (e.g., a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g., Nd{sub 2}Fe{sub 14}B or LaNi{sub 5}) and a carbide of the carbide-forming element are formed.

  6. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R. William; Ellis, Timothy W.; Dennis, Kevin W.; Hofer, Robert J.; Branagan, Daniel J.

    1997-11-25

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

  7. DOE-Led Research Team Makes Significant Rare Earth Discovery...

    Office of Environmental Management (EM)

    DOE-Led Research Team Makes Significant Rare Earth Discovery DOE-Led Research Team Makes ... Energy (DOE) has found that rare earth elements (REEs) can be removed from two U.S. ...

  8. Modeling Magnetism in Rare-Earth Intermetallic Materials | The...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling Magnetism in Rare-Earth Intermetallic Materials Theoretical modeling has led to a ... Rare-earth elements are unique in that their cores hold strongly localized electrons that ...

  9. Modeling Magnetism in Rare-Earth Intermetallic Materials | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Modeling Magnetism in Rare-Earth Intermetallic Materials Theoretical modeling has led to a key development in our understanding of the deeply complex magnetic properties in a series of rare-earth intermetallic materials. Rare-earth elements are unique in that their cores hold strongly localized electrons that underpin their novel magnetic properties. When combined with transition metals, rare earths become technologically-useful intermetallic materials. Here gadolinium-an element

  10. Ternary rare earth-lanthanide sulfides

    DOE Patents [OSTI]

    Takeshita, Takuo; Gschneidner JR., Karl A.; Beaudry, Bernard J.

    1987-01-06

    A new ternary rare earth sulfur compound having the formula: where M is a rare earth element selected from the group europium, samarium and ytterbium and x=0.15 to 0.8. The compound has good high-temperature thermoelectric properties and exhibits long-term structural stability up to 1000.degree. C.

  11. Influence of rare-earth elements doping on thermoelectric properties of Ca{sub 0.98}Dy{sub 0.02}MnO{sub 3} at high temperature

    SciTech Connect (OSTI)

    Zhu, Yuanhu Wang, Chunlei; Su, Wenbin; Liu, Jian; Li, Jichao; Zhang, Xinhua; Mei, Liangmo

    2015-05-15

    Ca{sub 0.98}Dy{sub 0.02}MnO{sub 3} and Ca{sub 0.96}Dy{sub 0.02}Re{sub 0.02}MnO{sub 3} (Re=La, Pr, Sm, Eu, Ho, and Yb) have been synthesized by the solid state reaction method. Samples with relative densities all over 96% have been obtained. Thermoelectric properties are evaluated between 300 and 1000 K. The electrical resistivity shows a typical metal-like conductivity behavior, and at high temperature, 973 K, decreases from 36.1 mΩ cm for Ca{sub 0.98}Dy{sub 0.02}MnO{sub 3} to 8.6 mΩ cm for Ca{sub 0.96}Dy{sub 0.02}Yb{sub 0.02}MnO{sub 3}. Both the absolute values of Seebeck coefficient and thermal conductivity are reduced by the introduction of second rare-earth element. The highest power factor of 415 μW/(K{sup 2}m) is obtained for Ca{sub 0.96}Dy{sub 0.02}Yb{sub 0.02}MnO{sub 3} sample, resulting in the highest dimensionless figure of merit (ZT) 0.25 at 973 K. This value shows an improvement of 144% compared with that of Ca{sub 0.98}Dy{sub 0.02}MnO{sub 3} ceramics at the same temperature. - Graphical abstract: The Ca{sub 0.96}Dy{sub 0.02}Re{sub 0.02}MnO{sub 3} (Re=La, Pr, …, Yb) were prepared by solid state reaction. Highest ZT value obtained is 0.25 at 973 K for Re=Yb, which shows 144% improvement compared with Ca{sub 0.98}Dy{sub 0.02}MnO{sub 3}. - Highlights: • Ca{sub 0.96}Dy{sub 0.02}Re{sub 0.02}MnO{sub 3} (Re=La, Pr, …, Yb) are produced by solid state reaction. • Lowest resistivity is obtained due to the highest carrier mobility for Re=Yb. • Highest power factor obtained is 415 μW/(K{sup 2}m) at 973 K for Re=Yb. • Highest ZT value obtained is 0.25 at 973 K for Ca{sub 0.96}Dy{sub 0.02}Yb{sub 0.02}MnO{sub 3} sample.

  12. The New Element Americium (Atomic Number 95)

    DOE R&D Accomplishments [OSTI]

    Seaborg, G.T.; James, R.A.; Morgan, L.O.

    1948-01-00

    Several isotopes of the new element 95 have been produced and their radiations characterized. The chemical properties of this tripositive element are similar to those of the typical tripositive lanthanide rare-earth elements. Element 95 is different from the latter in the degree and rate of formation of certain compounds of the complex ion type, which makes possible the separation of element 95 from the lanthanide rare-earths. The name americium (after the Americas) and the symbol Am are suggested for the element on the basis of its position as the sixth member of the actinide rare-earth series, analogous to europium, Eu, of the lanthanide series.

  13. Ternary rare earth-lanthanide sulfides

    DOE Patents [OSTI]

    Takeshita, Takuo; Gschneidner, Jr., Karl A.; Beaudry, Bernard J.

    1987-01-06

    A new ternary rare earth sulfur compound having the formula: La.sub.3-x M.sub.x S.sub.4 where M is a rare earth element selected from the group europium, samarium and ytterbium and x=0.15 to 0.8. The compound has good high-temperature thermoelectric properties and exhibits long-term structural stability up to 1000.degree. C.

  14. William Fowler and Elements in the Stars

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fusion rates for a wide variety of elements, and experiments with accelerators to ... Abundances of the Rare-Earth Nuclei Produced by Rapid Neutron Capture in Supernovae; Physical ...

  15. The Search for Heavy Elements

    ScienceCinema (OSTI)

    None

    2010-01-08

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  16. The Search for Heavy Elements

    SciTech Connect (OSTI)

    2008-04-17

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  17. Rare earth gas laser

    DOE Patents [OSTI]

    Krupke, W.F.

    1975-10-31

    A high energy gas laser with light output in the infrared or visible region of the spectrum is described. Laser action is obtained by generating vapors of rare earth halides, particularly neodymium iodide or, to a lesser extent, neodymium bromide, and disposing the rare earth vapor medium in a resonant cavity at elevated temperatures; e.g., approximately 1200/sup 0/ to 1400/sup 0/K. A particularly preferred gaseous medium is one involving a complex of aluminum chloride and neodymium chloride, which exhibits tremendously enhanced vapor pressure compared to the rare earth halides per se, and provides comparable increases in stored energy densities.

  18. What are the Rare Earths? | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What are the Rare Earths? Rare-earth metals or elements typically include scandium (Sc-21), yttrium (Y-39) and the lanthanides: lanthanum (La-57), cerium (Ce-58), praseodymium (Pr-59), neodymium (Nd-60), promethium (Pm-61), samarium (Sm-62), europium (Eu-63), gadolinium (Gd-64), terbium (Tb-65), dysprosium (Dy-66), holmium (Ho-67), erbium (Er-68), thulium (Tm-69), ytterbium (Yb-70), and lutetium (Lu-71). When alloyed with other metals, the rare-earths can provide enhanced magnetic, strength and

  19. Good Earths and Rare Earths | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Good Earths and Rare Earths Good Earths and Rare Earths April 20, 2011 - 6:17pm Addthis Charles Rousseaux Charles Rousseaux Senior Communications Specialist (detailee) What does this mean for me? Rare earth elements -- dysprosium, neodymium, terbium, europium and yttrium -- are essential to a wide range of green energy technologies ranging from windmills to electric vehicles One of their primary uses is in permanent magnets, which amount to over a $4 billion global industry Ames Laboratory

  20. Rare-earth nanoparticles for catalysis | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Developing new materials based on these two elements is expected to impact favorably the supply chain of the more scarce rare earths. The SULI student in this program will work...

  1. Rare Earths -- The Fraternal Fifteen | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For an up-to-date review of the rare earth elements, which is more technical, see the 2012 articles by Karl A. Gschneidner, Jr. and Vitalij K. Pecharsky in the Encyclopedia ...

  2. The Ames Process for Rare Earth Metals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Ames Process for Rare Earth Metals The Ames Process for the preparation of high purity ... If we rearrange the order of elements from increasing atomic weight to increasing boiling ...

  3. Microsoft Word - US_Japan_REE_agenda_ver7.doc

    Office of Environmental Management (EM)

    i,NationalInstituteofAdvancedIndustrialScienceandTechnology, Japan;CeriainAutomotiveCatalysts 12:30-1:30 Lunch ...

  4. US-Japan Clean Energy Cooperation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Edward Jones, Lawrence Livermore National Laboratory, Outcomes of U.S.-Japan Roundtable U.S.-Japan Joint Statement China CERC, U.S. India and Other ...

  5. The Heaviest Elements in the Universe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The artificial elements bring the total to 117. 244 244 244 ... Crust: 5 10 -25 g 244 Pu per gram of Earth. There is an ... We observe rare isotopes through their ...

  6. Solvent extraction of rare-earth ions based on functionalized ionic liquids

    SciTech Connect (OSTI)

    Sun, Xiaoqi; Dai, Sheng; Luo, Huimin

    2012-01-01

    We herein report the achievement of enhanced extractabilities and selectivities for separation of rare earth elements based on functionalized ionic liquids. This work highlights the potential of developing a comprehensive ionic liquid-based extraction strategy for rare earth elements using ionic liquids as both extractant and diluent.

  7. Behavior of Rare Earth Elements in Geothermal Systems- A New...

    Open Energy Info (EERE)

    ExplorationExploitation Tool? Abstract NA Author Scott A. Wood Published Department of Geology and Geological Engineering University of Idaho, 2001 DOI Not Provided Check for...

  8. 2016 CROSSCUTTING RESEARCH AND RARE EARTH ELEMENTS PORTFOLIOS...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Concepts for High Temperature Fossil Energy Applications Yukinori Yamamoto 14 Water Treatment and Reuse Maria Reidpath Research Triangle Institute Low-Energy Water Recovery from ...

  9. 2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University of Maine System * Low-Cost Efficient and Durable High Temperature Wireless Sensors by Direct ... High Salinity Produced Brine Treatment via Direct Waste Heat ...

  10. Rare earth element behavior in the development of energy resources

    SciTech Connect (OSTI)

    Laul, J.C.

    1984-04-02

    The REE patterns in soil-soil extract-plant-coal-flyash are all identical, show a negative Eu anomaly, and follow a smooth function of the REE ionic radii. The patterns are similar to that observed in the secondary mineral apatite. Their enrichment factors in various liquefaction products and ash depositories of a coal fired power plant are nearly unity (Class 1). The REE do not chemically fractionate even in size fractions 25 ..mu..m-0.5 ..mu..m of flyash. Almost all (99%) of the REE are bound in an inorganic form in high temperature clay minerals. The remarkable similarity in REE patterns in a wide variety of matrices with REE content varying over six orders of magnitude demonstrates that the REE do not significantly fractionate during transformation from the geological-biological-geological chain over geological time scales.

  11. Rare B Decays

    SciTech Connect (OSTI)

    Jackson, P.D.; /Victoria U.

    2006-02-24

    Recent results from Belle and BaBar on rare B decays involving flavor-changing neutral currents or purely leptonic final states are presented. Measurements of the CP asymmetries in B {yields} K*{gamma} and b {yields} s{gamma} are reported. Also reported are updated limits on B{sup +} {yields} K{sup +}{nu}{bar {nu}}, B{sup +} {yields} {tau}{sup +}{nu}, B{sup +} {yields} {mu}{sup +}{nu} and the recent measurement of B {yields} X{sub s}{ell}{sup +}{ell}{sup -}.

  12. Ames Lab 101: Rare Earths

    ScienceCinema (OSTI)

    Gschneidner, Karl

    2012-08-29

    "Mr. Rare Earth," Ames Laboratory scientist Karl Gschneidner Jr., explains the importance of rare-earth materials in many of the technologies we use today -- ranging from computers to hybrid cars to wind turbines. Gschneidner is a world renowned rare-earths expert at the U.S. Department of Energy's Ames Laboratory.

  13. Ames Lab 101: Rare Earths

    SciTech Connect (OSTI)

    Gschneidner, Karl

    2010-01-01

    "Mr. Rare Earth," Ames Laboratory scientist Karl Gschneidner Jr., explains the importance of rare-earth materials in many of the technologies we use today -- ranging from computers to hybrid cars to wind turbines. Gschneidner is a world renowned rare-earths expert at the U.S. Department of Energy's Ames Laboratory.

  14. Yttrium and rare earth stabilized fast reactor metal fuel

    DOE Patents [OSTI]

    Guon, Jerold; Grantham, LeRoy F.; Specht, Eugene R.

    1992-01-01

    To increase the operating temperature of a reactor, the melting point and mechanical properties of the fuel must be increased. For an actinide-rich fuel, yttrium, lanthanum and/or rare earth elements can be added, as stabilizers, to uranium and plutonium and/or a mixture of other actinides to raise the melting point of the fuel and improve its mechanical properties. Since only about 1% of the actinide fuel may be yttrium, lanthanum, or a rare earth element, the neutron penalty is low, the reactor core size can be reduced, the fuel can be burned efficiently, reprocessing requirements are reduced, and the nuclear waste disposal volumes reduced. A further advantage occurs when yttrium, lanthanum, and/or other rare earth elements are exposed to radiation in a reactor, they produce only short half life radioisotopes, which reduce nuclear waste disposal problems through much shorter assured-isolation requirements.

  15. Replacing the Rare Earth Intellectual Capital

    SciTech Connect (OSTI)

    Gschneidner, Jr., Karl

    2011-04-01

    The rare earth crisis slowly evolved during a 10 to 15 year period beginning in the mid-1980s, when the Chinese began to export mixed rare earth concentrates. In the early 1990s, they started to move up the supply chain and began to export the individual rare earth oxides and metals. By the late 1990s the Chinese exported higher value products, such as magnets, phosphors, polishing compounds, catalysts; and in the 21st century they supplied finished products including electric motors, computers, batteries, liquid-crystal displays (LCDs), TVs and monitors, mobile phones, iPods and compact fluorescent lamp (CFL) light bulbs. As they moved to higher value products, the Chinese slowly drove the various industrial producers and commercial enterprises in the US, Europe and Japan out of business by manipulating the rare earth commodity prices. Because of this, the technically trained rare earth engineers and scientists who worked in areas from mining to separations, to processing to production, to manufacturing of semifinished and final products, were laid-off and moved to other fields or they retired. However, in the past year the Chinese have changed their philosophy of the 1970s and 1980s of forming a rare earth cartel to control the rare earth markets to one in which they will no longer supply the rest of the world (ROW) with their precious rare earths, but instead will use them internally to meet the growing demand as the Chinese standard of living increases. To this end, they have implemented and occasionally increased export restrictions and added an export tariff on many of the high demand rare earth elements. Now the ROW is quickly trying to start up rare earth mines, e.g. Molycorp Minerals in the US and Lynas Corp. in Australia, to cover this shortfall in the worldwide market, but it will take about five years for the supply to meet the demand, even as other mines in the ROW become productive. Unfortunately, today there is a serious lack of technically trained

  16. Growth and defect structure of CdF{sub 2} crystal and nonstoichiometric Cd{sub 1-x}R{sub x}F{sub 2+x} phases (R are rare earth elements and in): 6. Growth and ionic conductivity of Cd{sub 0.904}In{sub 0.096}F{sub 2.096} single crystal

    SciTech Connect (OSTI)

    Sorokin, N. I. Sul'yanova, E. A.; Buchinskaya, I. I.; Artyukhov, A. A.; Sobolev, B. P.

    2013-07-15

    Cd{sub 0.904}In{sub 0.096}F{sub 2.096} crystals with fluorite-type defect structures have been grown from melt in a fluorinating atmosphere by the Bridgman method, and their ionic conductivity is investigated. The fluorine-ion transport activation enthalpy in Cd{sub 0.904}In{sub 0.096}F{sub 2.096} ({Delta}H = 0.68 eV) is much smaller than the corresponding characteristic of the crystals belonging to the isoconcentration series Cd{sub 0.9}R{sub 0.1}F{sub 2.1}, R = La-Lu, Y ({Delta}H = 0.8-0.9 eV). The ionic conductivity of Cd{sub 0.904}In{sub 0.096}F{sub 2.096} is {sigma} = 2 Multiplication-Sign 10{sup -4} S/cm (at 467 K); this value exceeds the conductivity of the CdF{sub 2} crystal matrix and the highest conductivity Cd{sub 0.9}R{sub 0.1}F{sub 2.1} crystals with rare earth elements by factors of 3 Multiplication-Sign 10{sup 3} and {approx}10, respectively. Nonstoichiometric crystals of solid electrolyte Cd{sub 1-x}In{sub x}F{sub 2+x} have the highest conductivity out of all studied electrolytes based on the CdF{sub 2} matrix.

  17. Method of determining lanthanidies in a transition element host

    DOE Patents [OSTI]

    De Kalb, Edward L.; Fassel, Velmer A.

    1976-02-03

    A phosphor composition contains a lanthanide activator element within a host matrix having a transition element as a major component. The host matrix is composed of certain rare earth phosphates or vanadates such as YPO.sub.4 with a portion of the rare earth replaced with one or more of the transition elements. On X-ray or other electromagnetic excitation, trace lanthanide impurities or additives within the phosphor are spectrometrically determined from their characteristic luminescence.

  18. Rare Isotopes in Cosmic Explosions and Accelerators on Earth

    ScienceCinema (OSTI)

    Schatz, Hendrick [Michigan State University, East Lansing, Michigan, United States

    2010-01-08

    Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

  19. METHOD OF SEPARATING RARE EARTHS BY ION EXCHANGE

    DOE Patents [OSTI]

    Spedding, F.H.; Powell, J.E.

    1960-10-18

    A process is given for separating yttrium and rare earth values having atomic numbers of from 57 through 60 and 68 through 71 from an aqueous solution whose pH value can range from 1 to 9. All rare earths and yttrium are first adsorbed on a cation exchange resin, and they are then eluted with a solution of N-hydroxyethylethylenediaminetriacetic acid (HEDTA) in the order of decreasing atomic number, yttrium behaving like element 61; the effluents are collected in fractions. The HEDTA is recovered by elution with ammonia solution and the resin is regenerated with sulfuric acid. Rare earths are precipitated from the various effluents with oxalic acid, and each supernatant is passed over cation exchange resin for adsorption of HEDTA and nonprecipitated rare earths: the oxalic acid is not retained by the resin.

  20. FUEL ELEMENT

    DOE Patents [OSTI]

    Bean, R.W.

    1963-11-19

    A ceramic fuel element for a nuclear reactor that has improved structural stability as well as improved cooling and fission product retention characteristics is presented. The fuel element includes a plurality of stacked hollow ceramic moderator blocks arranged along a tubular raetallic shroud that encloses a series of axially apertured moderator cylinders spaced inwardly of the shroud. A plurality of ceramic nuclear fuel rods are arranged in the annular space between the shroud and cylinders of moderator and appropriate support means and means for directing gas coolant through the annular space are also provided. (AEC)

  1. Semiconductor sensor for optically measuring polarization rotation of optical wavefronts using rare earth iron garnets

    DOE Patents [OSTI]

    Duncan, Paul G.

    2002-01-01

    Described are the design of a rare earth iron garnet sensor element, optical methods of interrogating the sensor element, methods of coupling the optical sensor element to a waveguide, and an optical and electrical processing system for monitoring the polarization rotation of a linearly polarized wavefront undergoing external modulation due to magnetic field or electrical current fluctuation. The sensor element uses the Faraday effect, an intrinsic property of certain rare-earth iron garnet materials, to rotate the polarization state of light in the presence of a magnetic field. The sensor element may be coated with a thin-film mirror to effectively double the optical path length, providing twice the sensitivity for a given field strength or temperature change. A semiconductor sensor system using a rare earth iron garnet sensor element is described.

  2. Process to separate transuranic elements from nuclear waste

    DOE Patents [OSTI]

    Johnson, Terry R.; Ackerman, John P.; Tomczuk, Zygmunt; Fischer, Donald F.

    1989-01-01

    A process for removing transuranic elements from a waste chloride electrolytic salt containing transuranic elements in addition to rare earth and other fission product elements so the salt waste may be disposed of more easily and the valuable transuranic elements may be recovered for reuse. The salt is contacted with a cadmium-uranium alloy which selectively extracts the transuranic elements from the salt. The waste salt is generated during the reprocessing of nuclear fuel associated with the Integral Fast Reactor (IFR).

  3. News about Rare Earths, New or Critical Materials, and Their Uses: |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Critical Materials Institute Rare Earths, New or Critical Materials, and Their Uses: 2016 Rare earth materials: Developing a comprehensive approach could help DOD better manage national security risks in the supply chain, Feb. 11, 2016 New request for information to inform Department of Energy Critical Materials Strategy, Feb. 10, 2016 2015 UK gets federal funds to research coal-based rare earth elements, Dec. 20, 2015 Salvage neodymium magnets from an old hard drive, Dec. 10, 2015 Battery

  4. Facility for Rare Isotope Beams: The Journey Has Begun on DOE...

    Office of Environmental Management (EM)

    ... rare that they can't be found naturally on earth. Instead, they're created in extreme conditions such as the centers of exploding supernovae. These isotopes decay into the elements ...

  5. Rare Earth Oxide Fluoride Nanoparticles And Hydrothermal Method For Forming Nanoparticles

    DOE Patents [OSTI]

    Fulton, John L.; Hoffmann, Markus M.

    2003-12-23

    A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

  6. Rare earth oxide fluoride nanoparticles and hydrothermal method for forming nanoparticles

    DOE Patents [OSTI]

    Fulton, John L [Richland, WA; Hoffmann, Markus M [Richland, WA

    2001-11-13

    A hydrothermal method for forming nanoparticles of a rare earth element, oxygen and fluorine has been discovered. Nanoparticles comprising a rare earth element, oxygen and fluorine are also described. These nanoparticles can exhibit excellent refractory properties as well as remarkable stability in hydrothermal conditions. The nanoparticles can exhibit excellent properties for numerous applications including fiber reinforcement of ceramic composites, catalyst supports, and corrosion resistant coatings for high-temperature aqueous solutions.

  7. RECONDITIONING FUEL ELEMENTS

    DOE Patents [OSTI]

    Brandt, H.L.

    1962-02-20

    A process is given for decanning fuel elements that consist of a uranium core, an intermediate section either of bronze, silicon, Al-Si, and uranium silicide layers or of lead, Al-Si, and uranium silicide layers around said core, and an aluminum can bonded to said intermediate section. The aluminum can is dissolved in a solution of sodium hydroxide (9 to 20 wt%) and sodium nitrate (35 to 12 wt %), and the layers of the intermediate section are dissolved in a boiling sodium hydroxide solution of a minimum concentration of 50 wt%. (AEC) A method of selectively reducing plutonium oxides and the rare earth oxides but not uranium oxides is described which comprises placing the oxides in a molten solvent of zinc or cadmium and then adding metallic uranium as a reducing agent. (AEC)

  8. Programmatic Elements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides acceptable methods of meeting the requirements of DOE O 151.1C for programmatic elements that sustain the emergency management program and maintain the readiness of the program to respond to an emergency. Supersedes DOE G 151.1-1, Volume 5-1, DOE G 151.1-1, Volume 5-2, DOE G 151.1-1, Volume 5-3, DOE G 151.1-1, Volume 5-4, DOE G 151.1-1, Volume 7-1, and DOE G 151.1-1, Volume 7-3.

  9. Rare Earth-Bearing Murataite Ceramics

    SciTech Connect (OSTI)

    Stefanovsky, Sergey; Stefanovsky, Olga; Yudintsev, Sergey; Nikonov, Boris

    2007-07-01

    Phase composition of the murataite-based ceramics containing 10 wt.% lanthanum, cerium, neodymium, europium, gadolinium, yttrium, zirconium oxides was studied. The ceramics were prepared by melting of oxide mixtures in 20 mL glass-carbon crucibles in air at {approx}1500 deg. C. They are composed of predominant murataite-type phases and minor extra phases: rutile, crichtonite, perovskite, ilmenite/pyrophanite, and zirconolite (in the Zr-bearing sample only). Three murataite-related phases with five- (5C), eight- (8C), and three-fold (3C) elementary fluorite unit cell are normally present in all the ceramics. These phases form core, intermediate zone, and rim of the murataite grains, respectively. They are predominant host phases for the rare earth elements whose concentrations are reduced in a row: 5C>8C>3C. Appreciate fraction of La and Ce may enter the perovskite phase. (authors)

  10. Rare earth doped zinc oxide varistors

    DOE Patents [OSTI]

    McMillan, A.D.; Modine, F.A.; Lauf, R.J.; Alim, M.A.; Mahan, G.D.; Bartkowiak, M.

    1998-12-29

    A varistor includes a Bi-free, essentially homogeneous sintered body of a ceramic composition including, expressed as nominal weight %, 0.2--4.0% oxide of at least one rare earth element, 0.5--4.0% Co{sub 3}O{sub 4}, 0.05--0.4% K{sub 2}O, 0.05--0.2% Cr{sub 2}O{sub 3}, 0--0.2% CaO, 0.00005--0.01% Al{sub 2}O{sub 3}, 0--2% MnO, 0--0.05% MgO, 0--0.5% TiO{sub 3}, 0--0.2% SnO{sub 2}, 0--0.02% B{sub 2}O{sub 3}, balance ZnO. 4 figs.

  11. Rare earth doped zinc oxide varistors

    DOE Patents [OSTI]

    McMillan, April D.; Modine, Frank A.; Lauf, Robert J.; Alim, Mohammad A.; Mahan, Gerald D.; Bartkowiak, Miroslaw

    1998-01-01

    A varistor includes a Bi-free, essentially homogeneous sintered body of a ceramic composition including, expressed as nominal weight %, 0.2-4.0% oxide of at least one rare earth element, 0.5-4.0% Co.sub.3 O.sub.4, 0.05-0.4% K.sub.2 O, 0.05-0.2% Cr.sub.2 O.sub.3, 0-0.2% CaO, 0.00005-0.01% Al.sub.2 O.sub.3, 0-2% MnO, 0-0.05% MgO, 0-0.5% TiO.sub.3, 0-0.2% SnO.sub.2, 0-0.02% B.sub.2 O.sub.3, balance ZnO.

  12. Exploration of R2XM2 (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge): Structural Motifs, the novel Compound Gd2AlGe2 and Analysis of the U3Si2 and Zr3Al2 Structure Types

    SciTech Connect (OSTI)

    Sean William McWhorter

    2006-05-01

    In the process of exploring and understanding the influence of crystal structure on the system of compounds with the composition Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} several new compounds were synthesized with different crystal structures, but similar structural features. In Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, the main feature of interest is the magnetocaloric effect (MCE), which allows the material to be useful in magnetic refrigeration applications. The MCE is based on the magnetic interactions of the Gd atoms in the crystal structure, which varies with x (the amount of Si in the compound). The crystal structure of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} can be thought of as being formed from two 3{sup 2}434 nets of Gd atoms, with additional Gd atoms in the cubic voids and Si/Ge atoms in the trigonal prismatic voids. Attempts were made to substitute nonmagnetic atoms for magnetic Gd using In, Mg and Al. Gd{sub 2}MgGe{sub 2} and Gd{sub 2}InGe{sub 2} both possess the same 3{sup 2}434 nets of Gd atoms as Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, but these nets are connected differently, forming the Mo{sub 2}FeB{sub 2} crystal structure. A search of the literature revealed that compounds with the composition R{sub 2}XM{sub 2} (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge) crystallize in one of four crystal structures: the Mo{sub 2}FeB{sub 2}, Zr{sub 3}Al{sub 2}, Mn{sub 2}AlB{sub 2} and W{sub 2}CoB{sub 2} crystal structures. These crystal structures are described, and the relationships between them are highlighted. Gd{sub 2}AlGe{sub 2} forms an entirely new crystal structure, and the details of its synthesis and characterization are given. Electronic structure calculations are performed to understand the nature of bonding in this compound and how electrons can be accounted for. A series of electronic structure calculations were performed on models with the U{sub 3}Si{sub 2} and Zr{sub 3}Al{sub 2} structures, using Zr and A1 as

  13. Are Earths Rare? Perhaps Not

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Are Earths Rare? Perhaps Not Are Earths Rare? Perhaps Not Developed at NERSC, a Pipeline for Finding Earth-like Planets in the Milky Way January 13, 2014 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov habitablezones450.jpg Artist's representation of the "habitable zone," the range of orbits where liquid water is permitted on the surface of a planet. The authors find that 22% of Sun-like stars harbor a planet between one and two times the size of Earth in the habitable zone One out of

  14. Laminated rare earth structure and method of making

    DOE Patents [OSTI]

    Senor, David J [West Richland, WA; Johnson, Roger N [Richland, WA; Reid, Bruce D [Pasco, WA; Larson, Sandra [Richland, WA

    2002-07-30

    A laminated structure having two or more layers, wherein at least one layer is a metal substrate and at least one other layer is a coating comprising at least one rare earth element. For structures having more than two layers, the coating and metal substrate layers alternate. In one embodiment of the invention, the structure is a two-layer laminate having a rare earth coating electrospark deposited onto a metal substrate. In another embodiment of the invention, the structure is a three-layer laminate having the rare earth coating electrospark deposited onto a first metal substrate and the coating subsequently abonded to a second metal substrate. The bonding of the coating to the second metal substrate may be accomplished by hot pressing, hot rolling, high deformation rate processing, or combinations thereof. The laminated structure may be used in nuclear components where reactivity control or neutron absorption is desired and in non-nuclear applications such as magnetic and superconducting films.

  15. Response Elements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides acceptable methods for meeting the requirement of DOE O 151.1C for response elements that respond or contribute to response as needed in an emergency. Supersedes DOE G 151.1-1, Volume 3-1, DOE G 151.1-1, Volume 3-2, DOE G 151.1-1, Volume 3-3, DOE G 151.1-1, Volume 3-4, DOE G 151.1-1, Volume 4-1, DOE G 151.1-1, Volume 4-2, DOE G 151.1-1, Volume 4-3, DOE G 151.1-1, Volume 4-4, DOE G 151.1-1, Volume 4-5, and DOE G 151.1-1, Volume 4-6.

  16. HISTORY OF THE ORIGIN OF THE CHEMICAL ELEMENTS AND THEIR DISCOVERIES...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The claim of discovery of an element has varied over the centuries. Many claims, e.g., the discovery of certain rare earth elements of the lanthanide series, involved the discovery ...

  17. Rare B decays at CDF

    SciTech Connect (OSTI)

    Farrington, Sinead M.; /Liverpool U.

    2006-10-01

    The confidence level limits of the CDF search for the B{sub s}{sup 0} and B{sub d}{sup 0} {yields} {mu}{sup +}{mu}{sup -} rare decays and the branching ratio measurement of B{sub s}{sup 0} {yields} D{sub s}{sup +} D{sub s}{sup -} are presented.

  18. Potential synergy: the thorium fuel cycle and rare earths processing

    SciTech Connect (OSTI)

    Ault, T.; Wymer, R.; Croff, A.; Krahn, S.

    2013-07-01

    The use of thorium in nuclear power programs has been evaluated on a recurring basis. A concern often raised is the lack of 'thorium infrastructure'; however, for at least a part of a potential thorium fuel cycle, this may less of a problem than previously thought. Thorium is frequently encountered in association with rare earth elements and, since the U.S. last systematically evaluated the large-scale use of thorium (the 1970's,) the use of rare earth elements has increased ten-fold to approximately 200,000 metric tons per year. Integration of thorium extraction with rare earth processing has been previously described and top-level estimates have been done on thorium resource availability; however, since ores and mining operations differ markedly, what is needed is process flowsheet analysis to determine whether a specific mining operation can feasibly produce thorium as a by-product. Also, the collocation of thorium with rare earths means that, even if a thorium product stream is not developed, its presence in mining waste streams needs to be addressed and there are previous instances where this has caused issues. This study analyzes several operational mines, estimates the mines' ability to produce a thorium by-product stream, and discusses some waste management implications of recovering thorium. (authors)

  19. Rare events: a state of the art

    SciTech Connect (OSTI)

    Uppuluri, V.R.R.

    1980-12-01

    The study of rare events has become increasingly important in the context of nuclear safety. Some philosophical considerations, such as the framework for the definition of a rare event, rare events and science, rare events and trans-science, and rare events and public perception, are discussed. The technical work of the Task Force on problems of Rare Events in the Reliability Analysis of Nuclear Plants (1976-1978), sponsored by OECD, is reviewed. Some recent technical considerations are discussed, and conclusions are drawn. The appendix contains an essay written by Anne E. Beachey, under the title: A Study of Rare Events - Problems and Promises.

  20. Theoretical and Computational Studies of Rare Earth Substitutes: A Test-bed for Accelerated Materials Development

    SciTech Connect (OSTI)

    Benedict, Lorin X.

    2015-10-26

    Hard permanent magnets in wide use typically involve expensive Rare Earth elements. In this effort, we investigated candidate permanent magnet materials which contain no Rare Earths, while simultaneously exploring improvements in theoretical methodology which enable the better prediction of magnetic properties relevant for the future design and optimization of permanent magnets. This included a detailed study of magnetocrystalline anisotropy energies, and the use of advanced simulation tools to better describe magnetic properties at elevated temperatures.

  1. Precise rare earth analysis of geological materials

    SciTech Connect (OSTI)

    Laul, J.C.; Wogman, N.A.

    1982-01-01

    Rare earth element (REE) concentrations are very informative in revealing chemical fractionation processs in geological systems. The REE's (La-Lu) behavior is characteristic of various primary and secondary minerals which comprise a rock. The REE's contents and their patterns provide a strong fingerprint in distinguishing among various rock types and in understanding the partial melting and/or fractional crystallization of the source region. The REE contents in geological materials are usually at trace levels. To measure all the REE at such levels, radiochemical neutron activation analysis (RNAA) has been used with a REE group separation scheme. To maximize detection sensitivites for individual REE, selective ..gamma..-ray/x-ray measurements have been made using normal Ge(Li) and low-energy photon detectors (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometer systems. Using these detection methods an individual REE can be measured at or below the ppB levels; chemical yields of the REE are determined by reactivation.

  2. Process to separate transuranic elements from nuclear waste

    DOE Patents [OSTI]

    Johnson, T.R.; Ackerman, J.P.; Tomczuk, Z.; Fischer, D.F.

    1989-03-21

    A process is described for removing transuranic elements from a waste chloride electrolytic salt containing transuranic elements in addition to rare earth and other fission product elements so the salt waste may be disposed of more easily and the valuable transuranic elements may be recovered for reuse. The salt is contacted with a cadmium-uranium alloy which selectively extracts the transuranic elements from the salt. The waste salt is generated during the reprocessing of nuclear fuel associated with the Integral Fast Reactor (IFR). 2 figs.

  3. Process to separate transuranic elements from nuclear waste

    DOE Patents [OSTI]

    Johnson, T.R.; Ackerman, J.P.; Tomczuk, Z.; Fischer, D.F.

    1988-07-12

    A process for removing transuranic elements from a waste chloride electrolytic salt containing transuranic elements in addition to rare earth and other fission product elements so the salt waste may be disposed of more easily and the valuable transuranic elements may be recovered for reuse. The salt is contacted with a cadmium-uranium alloy which selectively extracts the transuranic elements from the salt. The waste salt is generated during the reprocessing of nuclear fuel associated with the Integral Fast Reactor (IFR). 2 figs.

  4. Discrete Element Modeling

    SciTech Connect (OSTI)

    Morris, J; Johnson, S

    2007-12-03

    The Distinct Element Method (also frequently referred to as the Discrete Element Method) (DEM) is a Lagrangian numerical technique where the computational domain consists of discrete solid elements which interact via compliant contacts. This can be contrasted with Finite Element Methods where the computational domain is assumed to represent a continuum (although many modern implementations of the FEM can accommodate some Distinct Element capabilities). Often the terms Discrete Element Method and Distinct Element Method are used interchangeably in the literature, although Cundall and Hart (1992) suggested that Discrete Element Methods should be a more inclusive term covering Distinct Element Methods, Displacement Discontinuity Analysis and Modal Methods. In this work, DEM specifically refers to the Distinct Element Method, where the discrete elements interact via compliant contacts, in contrast with Displacement Discontinuity Analysis where the contacts are rigid and all compliance is taken up by the adjacent intact material.

  5. Improved method for preparing rare earth sesquichalcogenides

    DOE Patents [OSTI]

    Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

    1982-04-14

    An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

  6. Ames Lab 101: Rare-Earth Recycling

    ScienceCinema (OSTI)

    Ryan Ott

    2013-06-05

    Recycling keeps paper, plastics, and even jeans out of landfills. Could recycling rare-earth magnets do the same? Perhaps, if the recycling process can be improved. Scientists at the U.S. Department of Energy's Ames Laboratory are working to more effectively remove the neodymium, a rare earth, from the mix of other materials in a magnet.

  7. Pt nanoparticles modified by rare earth oxides: Electronic effect and influence to catalytic hydrogenation of 3-phenoxybenzaldehyde

    SciTech Connect (OSTI)

    Mou, Zhigang; Han, Ming; Li, Gang; Du, Yukou; Yang, Ping; Zhang, Hailu; Deng, Zongwu

    2013-11-15

    Graphical abstract: - Highlights: • The rare earths modified Pt/Al{sub 2}O{sub 3} were prepared by colloidal deposition method. • Modification of Pt by the rare earth enhanced catalytic hydrogenation activity. • The activity improvement is due to electron interaction between Pt and rare earth. • The hydrogenation mechanism of rare earth modified Pt catalyst was proposed. - Abstract: The rare earth elements (La, Ce, Nd, Sm, Pr, and Gd) modified Pt/Al{sub 2}O{sub 3} catalysts were prepared by the colloidal deposition and chemical reduction methods, respectively. Pt nanoparticles with average size 3 ± 0.5 nm were uniformly dispersed on the surface of Al{sub 2}O{sub 3} for the samples prepared by the colloidal deposition method, which exhibited higher activities in the hydrogenation of 3-phenoxybenzadehyde than the corresponding samples prepared by chemical reduction method. Moreover, except Gd, the catalysts modified by rare earth elements showed better catalytic performance than unmodified Pt/Al{sub 2}O{sub 3}. For Pt–Ce/Al{sub 2}O{sub 3} catalyst, when the weight percent of Pt and Ce was 0.5 and 0.25, respectively, the hydrogenation conversion of 3-phenoxybenzaldehyde was 97.3% after 6 h reaction. This activity improvement is due to the electronic interaction between Pt and rare earth elements, which was investigated by X-ray photoelectron spectroscopy.

  8. NEUTRONIC REACTOR CONTROL ELEMENT

    DOE Patents [OSTI]

    Beaver, R.J.; Leitten, C.F. Jr.

    1962-04-17

    A boron-10 containing reactor control element wherein the boron-10 is dispersed in a matrix material is describeri. The concentration of boron-10 in the matrix varies transversely across the element from a minimum at the surface to a maximum at the center of the element, prior to exposure to neutrons. (AEC)

  9. Prospects for Non-Rare Earth Permanent Magnets for Traction Motors and Generators

    SciTech Connect (OSTI)

    Kramer, Matthew; McCallum, Kendall; Anderson, Iver; Constantinides, Steven

    2012-06-29

    With the advent of high-flux density permanent magnets based on rare earth elements such as neodymium (Nd) in the 1980s, permanent magnet-based electric machines had a clear performance and cost advantage over induction machines when weight and size were factors such as in hybrid electric vehicles and wind turbines. However, the advantages of the permanent magnet-based electric machines may be overshadowed by supply constraints and high prices of their key constituents, rare earth elements, which have seen nearly a 10-fold increase in price in the last 5 years and the imposition of export limits by the major producing country, China, since 2010. We outline the challenges, prospects, and pitfalls for several potential alloys that could replace Nd-based permanent magnets with more abundant and less strategically important elements.

  10. Rare Iron Oxide in Ancient Chinese Pottery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 2-3. Citation: C. Dejoie, P. Sciau, W. Li, L. No, A. Mehta, K. Chen, H. Luo, M. Kunz, N. Tamura, and Z. Liu, "Learning from the past: Rare -Fe2O3 in the ancient...

  11. Ames Lab 101: Rare-Earth Magnets

    ScienceCinema (OSTI)

    McCallum, Bill

    2012-08-29

    Senior Scientist, Bill McCallum, briefly discusses rare-earth magnets and their uses and how Ames Lab is research new ways to save money and energy using magnets.

  12. Recovery of Rare Earths, Precious Metals and Other Critical Materials from Geothermal Waters with Advanced Sorbent Structures

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Pamela M. Kinsey

    2015-09-30

    The work evaluates, develops and demonstrates flexible, scalable mineral extraction technology for geothermal brines based upon solid phase sorbent materials with a specific focus upon rare earth elements (REEs). The selected organic and inorganic sorbent materials demonstrated high performance for collection of trace REEs, precious and valuable metals. The nanostructured materials typically performed better than commercially available sorbents. Data contains organic and inorganic sorbent removal efficiency, Sharkey Hot Springs (Idaho) water chemsitry analysis, and rare earth removal efficiency from select sorbents.

  13. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Liu, Wei

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  14. U.S-, Japan Exchange Best Practices on Nuclear Emergency Response...

    National Nuclear Security Administration (NNSA)

    S-, Japan Exchange Best Practices on Nuclear Emergency Response | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile...

  15. US-Japan theory workshop on 3-D MHD studies: proceedings

    SciTech Connect (OSTI)

    Carreras, B.A.

    1984-05-01

    Abstracts for 12 of the 15 included papers were entered into EDB. Abstracts for the remaining three papers appeared previously in EDB. (MOW)

  16. 50th Anniversary of U.S.- Japan Health Studies | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In 1947, at the request of the U.S. Government, the National Academy of Sciences-National Research Council (NAS-NRC) initiated a long-term investigation of the health effects ...

  17. Summary and viewgraphs from the Q-121 US/Japan advanced current drive concepts workshop

    SciTech Connect (OSTI)

    Bonoli, P.; Porkolab, M. ); Chan, V.; Pinsker, R.; Politzer, P. ); Darrow, D. . Plasma Physics Lab.); Ehst, D. ); Fukuyama, Atsushi ); Imai, Tsuyoshi; Watari, Tetsuo ); Itoh, Satoshi; Naka

    1990-03-09

    With the emphasis placed on current drive by ITER, which requires steady state operation in its engineering phase, it is important to bring theory and experiment in agreement for each of the schemes that could be used in that design. Both neutral beam and lower hybrid (LH) schemes are in excellent shape in that regard. Since the projected efficiency of all schemes is marginal it is also important to continue our search for more efficient processes. This workshop featured experimental and theoretical work in each processes. This workshop featured experimental and theoretical work in each of these areas, that is, validation of theory and the search for better ideas. There were a number of notable results to report, the most striking again (as with last year) the long pulse operation of TRIAM-1M. A low current was sustained for over 1 hour with LH waves, using new hall-effect sensors in the equilibrium field circuit to maintain position control. In JT-60, by sharpening the wave spectrum the current drive efficiency was improved to 0.34 {times} 10{sup 20}m{sup -2}A/W and 1.5 MA of current was driven entirely by the lower hybrid system. Also in that machine, using two different LH frequencies, the H-mode was entered. Finally, by using the LH system for startup they saved 2.5 resistive volt-sec of flux, which if extrapolated to ITER would save 40 volt-sec there. For the first time, and experiment on ECH current drive showed reasonable agreement with theory. Those experiments are reported here by James (LLNL) on the D3-D machine. Substantially lower ECH current drive than expected theoretically was observed on WT-3, but if differed by being in a low absorption regime. Nonetheless, excellent physics results were achieved in the WT-3 experiments, notably in having careful measurements of the parallel velocity distributions.

  18. 1991 US-Japan workshop on Nuclear Fusion in Dense Plasmas. Proceedings

    SciTech Connect (OSTI)

    Ichimaru, S.; Tajima, T.

    1991-10-01

    The scientific areas covered at the Workshop may be classified into the following subfields: (1) basic theory of dense plasma physics and its interface with atomic physics and nuclear physics; (2) physics of dense z-pinches, ICF plasmas etc; (3) stellar interior plasmas; (4) cold fusion; and (5) other dense plasmas.

  19. The synthetic elements

    SciTech Connect (OSTI)

    Hoffman, D.C.

    1990-05-01

    Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered.

  20. China’s rare earth supply chain: Illegal production, and response to new cerium demand

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nguyen, Ruby Thuy; Imholte, D. Devin

    2016-03-29

    As the demand for personal electronic devices, wind turbines, and electric vehicles increases, the world becomes more dependent on rare earth elements. Given the volatile, Chinese-concentrated supply chain, global attempts have been made to diversify supply of these materials. However, the overall effect of supply diversification on the entire supply chain, including increasing low-value rare earth demand, is not fully understood. This paper is the first attempt to shed some light on China’s supply chain from both demand and supply perspectives, taking into account different Chinese policies such as mining quotas, separation quotas, export quotas, and resource taxes. We constructedmore » a simulation model using Powersim Studio that analyzes production (both legal and illegal), production costs, Chinese and rest-of-world demand, and market dynamics. We also simulated new demand of an automotive aluminum-cerium alloy in the U.S. market starting from 2018. Results showed that market share of the illegal sector has grown since 2007 to 2015, ranging between 22% and 25% of China’s rare earth supply, translating into 59–65% illegal heavy rare earths and 14–16% illegal light rare earths. There would be a shortage in certain light and heavy rare earths given three production quota scenarios and constant demand growth rate from 2015 to 2030. The new simulated Ce demand would require supply beyond that produced in China. Lastly, we illustrated revenue streams for different ore compositions in China in 2015.« less

  1. Rate Case Elements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proceeding Rate Information Residential Exchange Program Surplus Power Sales Reports Rate Case Elements BPA's rate cases are decided "on the record." That is, in making a decision...

  2. NEUTRONIC REACTOR CONTROL ELEMENT

    DOE Patents [OSTI]

    Newson, H.W.

    1960-09-13

    A novel composite neutronic reactor control element is offered. The element comprises a multiplicity of sections arranged in end-to-end relationship, each of the sections having a markedly different neutron-reactive characteristic. For example, a three-section control element could contain absorber, moderator, and fuel sections. By moving such an element longitudinally through a reactor core, reactivity is decreased by the absorber, increased slightly by the moderator, or increased substantially by the fuel. Thus, control over a wide reactivity range is provided.

  3. Preparations of rare earth-iron alloys by thermite reduction

    DOE Patents [OSTI]

    Schmidt, Frederick A.; Peterson, David T.; Wheelock, John T.

    1986-09-16

    An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

  4. Characterization and Recovery of Rare Earths from Coal and By...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Characterization and Recovery of Rare Earths from Coal and By-Products Citation Details In-Document Search Title: Characterization and Recovery of Rare Earths ...

  5. Researchers use light to create rare uranium molecule

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare uranium molecule Researchers use light to create rare uranium molecule Uranium nitride materials show promise as advanced nuclear fuels due to their high density, high ...

  6. Assembly of uniaxially aligned rare-earth-free nanomagnets

    SciTech Connect (OSTI)

    Balamurugan, B; Das, B; Shah, VR; Skomski, R; Li, XZ; Sellmyer, DJ

    2012-09-17

    We report HfCo7 nanoparticles with appreciable permanent-magnet properties (magnetocrystalline anisotropy K-1 approximate to 10 Mergs/cm(3), coercivity H-c approximate to 4.4 kOe, and magnetic polarization J(s) approximate to 10.9 kG at 300 K) deposited by a single-step cluster-deposition method. The direct crystalline-ordering of nanoparticles during the gas-aggregation process, without the requirement of a high-temperature thermal annealing, provides an unique opportunity to align their easy axes uniaxially by applying a magnetic field of about 5 kOe prior to deposition, and subsequently to fabricate exchange-coupled nanocomposites having J(s) as high as 16.6 kG by co-depositing soft magnetic Fe-Co. This study suggests HfCo7 as a promising rare-earth-free permanent-magnet alloy, which is important for mitigating the critical-materials aspects of rare-earth elements. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4753950

  7. Precise trace rare earth analysis by radiochemical neutron activation

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.; Weimer, W.C.; Wogman, N.A.

    1981-06-01

    A rare earth group separation scheme followed by normal Ge(Li), low energy photon detector (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometry significantly enhances the detection sensitivity of individual rare earth elements (REE) at or below the ppB level. Based on the selected ..gamma..-ray energies, normal Ge(Li) counting is favored for /sup 140/La, /sup 170/Tb, and /sup 169/Yb; LEPD is favored for low ..gamma..-ray energies of /sup 147/Nd, /sup 153/Sm, /sup 166/Ho, and /sup 169/Yb; and noncoincidence counting is favored for /sup 141/Ce, /sup 143/Ce, /sup 142/Pr, /sup 153/Sm, /sup 171/Er, and /sup 175/Yb. The detection of radionuclides /sup 152m/Eu, /sup 159/Gd, and /sup 177/Lu is equally sensitive by normal Ge(Li) and noncoincidence counting; /sup 152/Eu is equally sensitive by LEPD and normal Ge(Li); and /sup 153/Gd and /sup 170/Tm is equally favored by all the counting modes. Overall, noncoincidence counting is favored for most of the REE. Precise measurements of the REE were made in geological and biological standards.

  8. Rare earth phosphors and phosphor screens

    DOE Patents [OSTI]

    Buchanan, Robert A.; Maple, T. Grant; Sklensky, Alden F.

    1981-01-01

    This invention relates to rare earth phosphor screens for converting image carrying incident radiation to image carrying visible or near-visible radiation and to the rare earth phosphor materials utilized in such screens. The invention further relates to methods for converting image carrying charged particles to image carrying radiation principally in the blue and near-ultraviolet region of the spectrum and to stabilized rare earth phosphors characterized by having a continuous surface layer of the phosphors of the invention. More particularly, the phosphors of the invention are oxychlorides and oxybromides of yttrium, lanthanum and gadolinium activated with trivalent cerium and the conversion screens are of the type illustratively including x-ray conversion screens, image amplifier tube screens, neutron imaging screens, cathode ray tube screens, high energy gamma ray screens, scintillation detector screens and screens for real-time translation of image carrying high energy radiation to image carrying visible or near-visible radiation.

  9. MOLDED SEALING ELEMENT

    DOE Patents [OSTI]

    Bradford, B.W.; Skinner, W.J.

    1959-03-24

    Molded sealing elements suitable for use under conditions involving exposure to uranium hexafluoride vapor are described. Such sealing elements are made by subjecting graphitic carbons to a preliminary treatment with uranium hexafluoride vapor, and then incorporating polytetrafluorethylene in them. The resulting composition has good wear resistant and frictional properties and is resistant to disintegration by uranium hexafluoride over long periods of exposure.

  10. Method for preparing high cure temperature rare earth iron compound magnetic material

    DOE Patents [OSTI]

    Huang, Yuhong; Wei, Qiang; Zheng, Haixing

    2002-01-01

    Insertion of light elements such as H,C, or N in the R.sub.2 Fe.sub.17 (R=rare earth metal) series has been found to modify the magnetic properties of these compounds, which thus become prospective candidates for high performance permanent magnets. The most spectacular changes are increases of the Curie temperature, T.sub.c, of the magnetization, M.sub.s, and of coercivity, H.sub.c, upon interstitial insertion. A preliminary product having a component R--Fe--C,N phase is produced by a chemical route. Rare earth metal and iron amides are synthesized followed by pyrolysis and sintering in an inert or reduced atmosphere, as a result of which, the R--Fe--C,N phases are formed. Fabrication of sintered rare earth iron nitride and carbonitride bulk magnet is impossible via conventional process due to the limitation of nitridation method.

  11. Method of forming magnetostrictive rods from rare earth-iron alloys

    DOE Patents [OSTI]

    McMasters, O.D.

    1986-09-02

    Rods of magnetostrictive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube. 5 figs.

  12. Method of forming magnetostrictive rods from rare earth-iron alloys

    DOE Patents [OSTI]

    McMasters, O. Dale

    1986-09-02

    Rods of magnetrostructive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube.

  13. Behavior Of Rare Earth Element In Geothermal Systems, A NewExploratio...

    Open Energy Info (EERE)

    and Heber geothermal fields of southern California; and (7) the Dieng field in Central Java, Indonesia. We have analyzed the samples from all fields for REE except the last two....

  14. Trans-Atlantic Workshop on Rare Earth Elements and Other Critical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials and Alternatives for Storage Batteries Session C: Strategies and Research for ... of Science and Technology, Material Flow Analysis Session D: Opportunities for ...

  15. Shaker Table Experiments with Rare Earth Elements Sorption from Geothermal Brine

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  16. Density-functional calculations for rare-earth atoms and ions

    SciTech Connect (OSTI)

    Forstreuter, J.; Steinbeck, L.; Richter, M.; Eschrig, H.

    1997-04-01

    Relativistic local-spin-density (RLSD) and self-interaction-corrected (SIC) RLSD calculations were performed for the whole series of the rare-earth elements. Ionization potentials and radial expectation values with 4f wave functions were calculated. Improvement on nearly all quantities is found for SIC calculations. Comparison with other calculational methods shows that for a description of rare-earth elements SIC-RLSD competes well in accuracy with all of them, including the most accurate quantum-chemical approach. This is important since the SIC calculation has the advantage of being suited for a description of localized f states in solids with a comparatively moderate effort. {copyright} {ital 1997} {ital The American Physical Society}

  17. Neutronic fuel element fabrication

    DOE Patents [OSTI]

    Korton, George

    2004-02-24

    This disclosure describes a method for metallurgically bonding a complete leak-tight enclosure to a matrix-type fuel element penetrated longitudinally by a multiplicity of coolant channels. Coolant tubes containing solid filler pins are disposed in the coolant channels. A leak-tight metal enclosure is then formed about the entire assembly of fuel matrix, coolant tubes and pins. The completely enclosed and sealed assembly is exposed to a high temperature and pressure gas environment to effect a metallurgical bond between all contacting surfaces therein. The ends of the assembly are then machined away to expose the pin ends which are chemically leached from the coolant tubes to leave the coolant tubes with internal coolant passageways. The invention described herein was made in the course of, or under, a contract with the U.S. Atomic Energy Commission. It relates generally to fuel elements for neutronic reactors and more particularly to a method for providing a leak-tight metal enclosure for a high-performance matrix-type fuel element penetrated longitudinally by a multiplicity of coolant tubes. The planned utilization of nuclear energy in high-performance, compact-propulsion and mobile power-generation systems has necessitated the development of fuel elements capable of operating at high power densities. High power densities in turn require fuel elements having high thermal conductivities and good fuel retention capabilities at high temperatures. A metal clad fuel element containing a ceramic phase of fuel intimately mixed with and bonded to a continuous refractory metal matrix has been found to satisfy the above requirements. Metal coolant tubes penetrate the matrix to afford internal cooling to the fuel element while providing positive fuel retention and containment of fission products generated within the fuel matrix. Metal header plates are bonded to the coolant tubes at each end of the fuel element and a metal cladding or can completes the fuel-matrix enclosure

  18. Crystalline rare-earth activated oxyorthosilicate phosphor

    DOE Patents [OSTI]

    McClellan, Kenneth J.; Cooke, D. Wayne

    2004-02-10

    Crystalline, transparent, rare-earth activated lutetium oxyorthosilicate phosphor. The phosphor consists essentially of lutetium yttrium oxyorthosilicate activated with a rare-earth metal dopant M and having the general formula Lu(.sub.2-x-z)Y.sub.x M.sub.z SiO.sub.5, wherein 0.00.ltoreq.x.ltoreq.1.95, wherein 0.001.ltoreq.z.ltoreq.0.02, and wherein M is selected from Sm, Tb, Tm, Eu, Yb, and Pr. The phosphor also consists essentially of lutetium gadolinium oxyorthosilicate activated with a rare-earth metal dopant M and having the general formula Lu(.sub.2-x-z)Gd.sub.x M.sub.z SiO.sub.5, wherein 0.00.ltoreq.x.ltoreq.1.95, wherein 0.001.ltoreq.z.ltoreq.0.02, and wherein M is selected from Sm, Tb, Tm, Eu, Yb, and Pr. The phosphor also consists essentially of gadolinium yttrium oxyorthosilicate activated with a rare-earth metal dopant M and having the general formula Gd(.sub.2-x-z)Y.sub.x M.sub.z SiO.sub.5, wherein 0.00.ltoreq.x.ltoreq.1.95, wherein 0.001.ltoreq.z.ltoreq.0.02, and wherein M is selected from Sm, Tb, Tm, Eu, Yb, and Pr. The phosphor may be optically coupled to a photodetector to provide a radiation detector.

  19. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Shackleford, M.H.

    1958-12-16

    A fuel element possessing good stability and heat conducting properties is described. The fuel element comprises an outer tube formed of material selected from the group consisting of stainhess steel, V, Ti. Mo. or Zr, a fuel tube concentrically fitting within the outer tube and containing an oxide of an isotope selected from the group consisting of U/sup 235/, U/sup 233/, and Pu/sup 239/, and a hollow, porous core concentrically fitting within the fuel tube and formed of an oxide of an element selected from the group consisting of Mg, Be, and Zr.

  20. NUCLEAR REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Anderson, W.F.; Tellefson, D.R.; Shimazaki, T.T.

    1962-04-10

    A plate type fuel element which is particularly useful for organic cooled reactors is described. Generally, the fuel element comprises a plurality of fissionable fuel bearing plates held in spaced relationship by a frame in which the plates are slidably mounted in grooves. Clearance is provided in the grooves to allow the plates to expand laterally. The plates may be rigidly interconnected but are floatingly supported at their ends within the frame to allow for longi-tudinal expansion. Thus, this fuel element is able to withstand large temperature differentials without great structural stresses. (AEC)

  1. Elements in biological AMS

    SciTech Connect (OSTI)

    Vogel, J.S.; McAninch, J.; Freeman, S.

    1996-08-01

    AMS (Accelerator Mass Spectrometry) provides high detection sensitivity for isotopes whose half-lives are between 10 years and 100 million years. {sup 14}C is the most developed of such isotopes and is used in tracing natural and anthropogenic organic compounds in the Earth`s biosphere. Thirty-three elements in the main periodic table and 17 lanthanides or actinides have long lived isotopes, providing potential tracers for research in elemental biochemistry. Overlap of biologically interesting heavy elements and possible AMS tracers is discussed.

  2. JACKETED FUEL ELEMENT

    DOE Patents [OSTI]

    Wigner, E.P.; Szilard, L.; Creutz, E.C.

    1959-02-01

    These fuel elements are comprised of a homogeneous metallic uranium body completely enclosed and sealed in an aluminum cover. The uranium body and aluminum cover are bonded together by a layer of zinc located between them. The bonding layer serves to improve transfer of heat, provides an additional protection against corrosion of the uranium by the coolant, and also localizes any possible corrosion by preventing travel of corrosive material along the surface of the fuel element.

  3. COMPOSITE FUEL ELEMENT

    DOE Patents [OSTI]

    Hurford, W.J.; Gordon, R.B.; Johnson, W.A.

    1962-12-25

    A sandwich-type fuel element for a reactor is described. This fuel element has the shape of an elongated flat plate and includes a filler plate having a plurality of compartments therein in which the fuel material is located. The filler plate is clad on both sides with a thin cladding material which is secured to the filler plate only to completely enclose the fuel material in each compartment. (AEC)

  4. Rare earths for life: an 85th birthday visit with Mr. Rare Earth...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth While scientists often talk about their life's work, few lives have been fuller than that of Ames Laboratory's Karl A. Gschneidner, Jr. who's being honored for over...

  5. SEPARATION OF RARE EARTHS BY SOLVENT EXTRACTION

    DOE Patents [OSTI]

    Peppard, D.F.; Mason, G.W.

    1960-10-11

    A process is given for separating lanthanide rare earths from each other from an aqueous mineral acid solution, e.g., hydrochloric or nitric acid of a concentration of above 3 M, preferably 12 to 16 M, by extraction with a water- immiscible alkyl phosphate, such as tributyl phosphate or a mixture of mono-, di- and tributyl phosphate, and fractional back-extraction with mineral acid whereby the lanthanides are taken up by the acid in the order of increasing atomic number.

  6. Concerning the Facility for Rare Isotope Beams

    ScienceCinema (OSTI)

    Symons, James

    2013-05-29

    James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

  7. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  8. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  9. Nuclear fuel element

    DOE Patents [OSTI]

    Zocher, Roy W.

    1991-01-01

    A nuclear fuel element and a method of manufacturing the element. The fuel element is comprised of a metal primary container and a fuel pellet which is located inside it and which is often fragmented. The primary container is subjected to elevated pressure and temperature to deform the container such that the container conforms to the fuel pellet, that is, such that the container is in substantial contact with the surface of the pellet. This conformance eliminates clearances which permit rubbing together of fuel pellet fragments and rubbing of fuel pellet fragments against the container, thus reducing the amount of dust inside the fuel container and the amount of dust which may escape in the event of container breach. Also, as a result of the inventive method, fuel pellet fragments tend to adhere to one another to form a coherent non-fragmented mass; this reduces the tendency of a fragment to pierce the container in the event of impact.

  10. FUEL ELEMENT CONSTRUCTION

    DOE Patents [OSTI]

    Simnad, M.T.

    1961-08-15

    A method of preventing diffusible and volatile fission products from diffusing through a fuel element container and contaminating reactor coolant is described. More specifically, relatively volatile and diffusible fission products either are adsorbed by or react with magnesium fluoride or difluoride to form stable, less volatile, less diffusible forms. The magnesium fluoride or difluoride is disposed anywhere inwardly from the outer surface of the fuel element container in order to be contacted by the fission products before they reach and contaminate the reactor coolant. (AEC)

  11. Super-Heavy Element Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Targets for Super-Heavy Element Research Presented at International Workshop on Super-Heavy Element Research SHE-15 J. B. Roberto Oak Ridge National Laboratory Oak Ridge,...

  12. CONSTRUCTION OF NUCLEAR FUEL ELEMENTS

    DOE Patents [OSTI]

    Weems, S.J.

    1963-09-24

    >A rib arrangement and an end construction for nuclearfuel elements laid end to end in a coolant tube are described. The rib arrangement is such that each fuel element, when separated from other fuel elements, fits loosely in the coolant tube and so can easily be inserted or withdrawn from the tube. The end construction of the fuel elements is such that the fuel elements when assembled end to end are keyed against relative rotation, and the ribs of each fuel element cooperate with the ribs of the adjacent fuel elements to give the assembled fuel elements a tight fit with the coolant tube. (AEC)

  13. Elemental Energy | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Logo: Elemental Energy Name: Elemental Energy Address: 14500 SW 92nd Ave Place: Portland, Oregon Country: United States Zip: 97224 Region: Pacific...

  14. American Elements | Open Energy Information

    Open Energy Info (EERE)

    Elements Jump to: navigation, search Name: American Elements Place: Los Angeles, California Zip: 90024 Product: US-based manufacturer and supplier of PV feedstocks such as silicon,...

  15. Element Partners | Open Energy Information

    Open Energy Info (EERE)

    Product: DFJ Element, a partnership between Element Venture Partners and Draper Fisher Jurvetson, manages a venture capital fund focusing on investments in high growth,...

  16. Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction

    DOE Patents [OSTI]

    Ellis, T.W.; Schmidt, F.A.

    1995-08-01

    A method is described for treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation. 2 figs.

  17. Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction

    DOE Patents [OSTI]

    Ellis, Timothy W.; Schmidt, Frederick A.

    1995-08-01

    Method of treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation.

  18. JACKETED REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Smith, K.F.; Van Thyne, R.J.

    1958-12-01

    A fuel element is described for fast reactors comprised of a core of uranium metal containing material and a jacket around the core, the jacket consisting of from 2.5 to 15 percent of titanium, from 1 to 5 percent of niobium, and from 80 to 96.5 percent of vanadium.

  19. Senescence responsive transcriptional element

    DOE Patents [OSTI]

    Campisi, Judith; Testori, Alessandro

    1999-01-01

    Recombinant polynucleotides have expression control sequences that have a senescence responsive element and a minimal promoter, and which are operatively linked to a heterologous nucleotide sequence. The molecules are useful for achieving high levels of expression of genes in senescent cells. Methods of inhibiting expression of genes in senescent cells also are provided.

  20. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Gurinsky, D.H.; Powell, R.W.; Fox, M.

    1959-11-24

    A nuclear fuel element comprising a plurality of nuclear fuel bearing strips is presented. The strips are folded along their longitudinal axes to an angle of about 60 deg and are secured at each end by ferrule to form an elongated assembly suitable for occupying a cylindrical coolant channel.

  1. Photovoltaic radiation detector element

    DOE Patents [OSTI]

    Agouridis, D.C.

    1980-12-17

    A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein in the edge of which closely approaches but is spaced from the current collector strips.

  2. Photovoltaic radiation detector element

    DOE Patents [OSTI]

    Agouridis, Dimitrios C.

    1983-01-01

    A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein the edge of which closely approaches but is spaced from the current collector strips.

  3. Heating element support clip

    DOE Patents [OSTI]

    Sawyer, William C.

    1995-01-01

    An apparatus for supporting a heating element in a channel formed in a heater base is disclosed. A preferred embodiment includes a substantially U-shaped tantalum member. The U-shape is characterized by two substantially parallel portions of tantalum that each have an end connected to opposite ends of a base portion of tantalum. The parallel portions are each substantially perpendicular to the base portion and spaced apart a distance not larger than a width of the channel and not smaller than a width of a graphite heating element. The parallel portions each have a hole therein, and the centers of the holes define an axis that is substantially parallel to the base portion. An aluminum oxide ceramic retaining pin extends through the holes in the parallel portions and into a hole in a wall of the channel to retain the U-shaped member in the channel and to support the graphite heating element. The graphite heating element is confined by the parallel portions of tantalum, the base portion of tantalum, and the retaining pin. A tantalum tube surrounds the retaining pin between the parallel portions of tantalum.

  4. Heating element support clip

    DOE Patents [OSTI]

    Sawyer, W.C.

    1995-08-15

    An apparatus for supporting a heating element in a channel formed in a heater base is disclosed. A preferred embodiment includes a substantially U-shaped tantalum member. The U-shape is characterized by two substantially parallel portions of tantalum that each have an end connected to opposite ends of a base portion of tantalum. The parallel portions are each substantially perpendicular to the base portion and spaced apart a distance not larger than a width of the channel and not smaller than a width of a graphite heating element. The parallel portions each have a hole therein, and the centers of the holes define an axis that is substantially parallel to the base portion. An aluminum oxide ceramic retaining pin extends through the holes in the parallel portions and into a hole in a wall of the channel to retain the U-shaped member in the channel and to support the graphite heating element. The graphite heating element is confined by the parallel portions of tantalum, the base portion of tantalum, and the retaining pin. A tantalum tube surrounds the retaining pin between the parallel portions of tantalum. 6 figs.

  5. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Stacy, J.T.

    1958-12-01

    A reactor fuel element having a core of molybdenum-uranium alloy jacketed in stainless steel is described. A barrier layer of tungsten, tantalum, molybdenum, columbium, or silver is interposed between the core and jacket to prevent formation of a low melting eutectic between uranium and the varlous alloy constituents of the stainless steel.

  6. Critical Materials and Rare Futures: Ames Laboratory Signs a...

    Energy Savers [EERE]

    Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement on Rare-Earth Research June 15, 2011 - 7:07pm Addthis The plasma torch in the Retech plasma furnace is ...

  7. The Materials Preparation Center - Making Rare Earth Metals - Part 1

    ScienceCinema (OSTI)

    Riedemann, Trevor

    2013-03-01

    Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 1 of 4.

  8. Preparations of rare earth-iron alloys by thermite reduction

    DOE Patents [OSTI]

    Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.

    1985-10-28

    Disclosed is an improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

  9. The Materials Preparation Center - Making Rare Earth Metals - Part 4

    ScienceCinema (OSTI)

    Riedemann, Trevor

    2013-03-01

    Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 4 of 4.

  10. The Materials Preparation Center - Making Rare Earth Metals - Part 3

    ScienceCinema (OSTI)

    Riedemann, Trevor

    2013-03-01

    Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 3 of 4.

  11. What would we do without rare earths? | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an Energy Innovation Hub created by the U.S. Department of Energy, has a big problem to solve -- what would we do without rare earths? Rare earths are a big part of our modern...

  12. The Materials Preparation Center - Making Rare Earth Metals - Part 2

    ScienceCinema (OSTI)

    Riedemann, Trevor

    2013-03-01

    Trevor Riedeman, manager of the MPC Rare Earth Materials Section, gives a presentation on the importance of rare earth metals and how they are made at Ames Laboratory. Part 2 of 4.

  13. Aljazeera story on rare earths features Alex King | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aljazeera story on rare earths features Alex King Aljazeera America recently did a story on the demand and scarcity of rare-earth metals and spoke to Ames Laboratory scientist and...

  14. Caterpillar and Cummins Gain Edge Through Argonnne's Rare Computer...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Caterpillar and Cummins Gain Edge Through Argonnne's Rare Computer Modeling and Analysis Resources PDF icon catcumminscomputingsuccessstorydec2015...

  15. Rare-Earth-Free Traction Motor: Rare Earth-Free Traction Motor for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: Baldor will develop a new type of traction motor with the potential to efficiently power future generations of EVs. Unlike todays large, bulky EV motors which use expensive, imported rare-earth-based magnets, Baldors motor could be light, compact, contain no rare earth materials, and have the potential to deliver more torque at a substantially lower cost. Key innovations in this project include the use of a unique motor design, incorporation of an improved cooling system, and the development of advanced materials manufacturing techniques. These innovations could significantly reduce the cost of an electric motor.

  16. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2006-03-08

    MAPVAR-KD is designed to transfer solution results from one finite element mesh to another. MAPVAR-KD draws heavily from the structure and coding of MERLIN II, but it employs a new finite element data base, EXODUS II, and offers enhanced speed and new capabilities not available in MERLIN II. In keeping with the MERLIN II documentation, the computational algorithms used in MAPVAR-KD are described. User instructions are presented. Example problems are included to demonstrate the operationmore » of the code and the effects of various input options. MAPVAR-KD is a modification of MAPVAR in which the search algorithm was replaced by a kd-tree-based search for better performance on large problems.« less

  17. Effects of simulated rare earth recycling wastewaters on biological nitrification

    SciTech Connect (OSTI)

    Fujita, Yoshiko; Barnes, Joni; Eslamimanesh, Ali; Lencka, Malgorzata M.; Anderko, Andrzej; Riman, Richard E.; Navrotsky, Alexandra

    2015-07-16

    Current efforts to increase domestic availability of rare-earth element (REE) supplies by recycling and expanded ore processing efforts will result in increased generation of associated wastewaters. In some cases disposal to a sewage treatment plant may be favored but plant performance must be maintained. To assess the potential effects of such wastewaters on biological wastewater treatment, model nitrifying organisms Nitrosomonas europaea and Nitrobacter winogradskyi were exposed to simulated wastewaters containing varying levels of yttrium or europium (10, 50 and 100 ppm), and the REE extractant tributyl phosphate (TBP, at 0.1 g/L). Y and Eu additions above 10 ppm inhibited N. europaea activity, even when initially virtually all of the REE was insoluble. The provision of TBP together with Eu increased inhibition of nitrite production by the N. europaea, although TBP alone did not substantially alter nitrifying activity N. winogradskyi was more sensitive to the stimulated wastewaters, with even 10 ppm Eu or Y inducing significant inhibition, and a complete shutdown of nitrifying activity occurred in the presence of the TBP. To analyze the availability of REEs in aqueous solutions, REE solubility has been calculated using the previously developed MSE (Mixed-Solvent Electrolyte) thermodynamic model. The model calculations reveal a strong pH dependence of solubility, which is typically controlled by the precipitation of REE hydroxides but may also be influenced by the formation of a phosphate phase.

  18. Effects of simulated rare earth recycling wastewaters on biological nitrification

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fujita, Yoshiko; Barnes, Joni; Eslamimanesh, Ali; Lencka, Malgorzata M.; Anderko, Andrzej; Riman, Richard E.; Navrotsky, Alexandra

    2015-07-16

    Current efforts to increase domestic availability of rare-earth element (REE) supplies by recycling and expanded ore processing efforts will result in increased generation of associated wastewaters. In some cases disposal to a sewage treatment plant may be favored but plant performance must be maintained. To assess the potential effects of such wastewaters on biological wastewater treatment, model nitrifying organisms Nitrosomonas europaea and Nitrobacter winogradskyi were exposed to simulated wastewaters containing varying levels of yttrium or europium (10, 50 and 100 ppm), and the REE extractant tributyl phosphate (TBP, at 0.1 g/L). Y and Eu additions above 10 ppm inhibited N.more » europaea activity, even when initially virtually all of the REE was insoluble. The provision of TBP together with Eu increased inhibition of nitrite production by the N. europaea, although TBP alone did not substantially alter nitrifying activity N. winogradskyi was more sensitive to the stimulated wastewaters, with even 10 ppm Eu or Y inducing significant inhibition, and a complete shutdown of nitrifying activity occurred in the presence of the TBP. To analyze the availability of REEs in aqueous solutions, REE solubility has been calculated using the previously developed MSE (Mixed-Solvent Electrolyte) thermodynamic model. The model calculations reveal a strong pH dependence of solubility, which is typically controlled by the precipitation of REE hydroxides but may also be influenced by the formation of a phosphate phase.« less

  19. Rare earth patterns in shergottite phosphates and residues

    SciTech Connect (OSTI)

    Laul, J.C.

    1987-03-30

    Leaching experiments with 1M HCl on ALHA 77005 power show that rare earth elements (REE) are concentrated in accessory phosphate phases (whitlockite, apatite) that govern the REE patterns of bulk shergottites. The REE patterns of whitlockite are typically light REE depleted with a negative Eu anomaly and show a hump at the heavy REE side, while the REE pattern of apatite (in Shergotty) is light REE enriched. Parent magmas are calculated from the model compositions of residues of ALHA 77005, Shergotty, and EETA 79001. The parent magmas lack a Eu anomaly, indicating that plagioclase was a late-stage crystallizing phase and it probably crystallized before the phosphates. The parent magmas of ALHA 77005 and Shergotty have similar REE patterns with a subchondritic Nd/Sm ratio. However, the Sm/Nd isotopics require a light REE depleted source for ALHA 77005 (if the crystallization age is <600 m.y.) and a light REE enriched source for Shergotty. Distinct Nd and Sr isotopic signatures may suggest different source regions for shergottites. copyright American Geophysical Union 1987

  20. Nuclear fuel element

    DOE Patents [OSTI]

    Meadowcroft, Ronald Ross; Bain, Alastair Stewart

    1977-01-01

    A nuclear fuel element wherein a tubular cladding of zirconium or a zirconium alloy has a fission gas plenum chamber which is held against collapse by the loops of a spacer in the form of a tube which has been deformed inwardly at three equally spaced, circumferential positions to provide three loops. A heat resistant disc of, say, graphite separates nuclear fuel pellets within the cladding from the plenum chamber. The spacer is of zirconium or a zirconium alloy.

  1. OXIDATION OF TRANSURANIC ELEMENTS

    DOE Patents [OSTI]

    Moore, R.L.

    1959-02-17

    A method is reported for oxidizing neptunium or plutonium in the presence of cerous values without also oxidizing the cerous values. The method consists in treating an aqueous 1N nitric acid solution, containing such cerous values together with the trivalent transuranic elements, with a quantity of hydrogen peroxide stoichiometrically sufficient to oxidize the transuranic values to the hexavalent state, and digesting the solution at room temperature.

  2. The transuranium elements: From neptunium and plutonium to element 112

    SciTech Connect (OSTI)

    Hoffman, D.C. |

    1996-07-26

    Beginning in the 1930`s, both chemists and physicists became interested in synthesizing new artificial elements. The first transuranium element, Np, was synthesized in 1940. Over the past six decades, 20 transuranium elements have been produced. A review of the synthesis is given. The procedure of naming the heavy elements is also discussed. It appears feasible to produce elements 113 and 114. With the Berkeley Gas-filled Separator, it should be possible to reach the superheavy elements in the region of the spherical Z=114 shell, but with fewer neutrons than the N=184 spherical shell. 57 refs, 6 figs.

  3. Synthesis of metastable rare-earth-iron mixed oxide with the hexagonal crystal structure

    SciTech Connect (OSTI)

    Nishimura, Tatsuya; Hosokawa, Saburo; Masuda, Yuichi; Wada, Kenji; Inoue, Masashi

    2013-01-15

    Rare-earth-iron mixed oxides with the rare earth/iron ratio=1 have either orthorhombic (o-REFeO{sub 3}) or hexagonal (h-REFeO{sub 3}) structure. h-REFeO{sub 3} is a metastable phase and the synthesis of h-REFeO{sub 3} is usually difficult. In this work, the crystallization process of the precursors obtained by co-precipitation and Pechini methods was investigated in detail to synthesize h-REFeO{sub 3}. It was found that the crystallization from amorphous to hexagonal phase and the phase transition from hexagonal to orthorhombic phase occurred at a similar temperature range for rare earth elements with small ionic radii (Er-Lu, Y). For both co-precipitation and Pechini methods, single-phase h-REFeO{sub 3} was obtained by shortening the heating time during calcination process. The hexagonal-to-orthorhombic phase transition took place by a nucleation growth mechanism and vermicular morphology of the thus-formed orthorhombic phase was observed. The hexagonal YbFeO{sub 3} had higher catalytic activity for C{sub 3}H{sub 8} combustion than orthorhombic YbFeO{sub 3}. - Graphical abstract: Although the synthesis of metastable hexagonal REFeO{sub 3} by the conventional method is difficult, we found that this phase is obtained by shortening the heating time of the precursor prepared by co-precipitation method. Highlights: Black-Right-Pointing-Pointer Synthesis of metastable REFeO{sub 3} with hexagonal structure by the co-precipitation method. Black-Right-Pointing-Pointer Hexagonal REFeO{sub 3} is obtained for the rare earth elements with small ionic radii. Black-Right-Pointing-Pointer Hexagonal-to-orthorhombic transformation of REFeO{sub 3}. Black-Right-Pointing-Pointer Catalytic activity of hexagonal REFeO{sub 3} for C{sub 3}H{sub 8} combustion.

  4. FUEL ELEMENT CONSTRUCTION

    DOE Patents [OSTI]

    Zumwalt, L.R.

    1961-08-01

    Fuel elements having a solid core of fissionable material encased in a cladding material are described. A conversion material is provided within the cladding to react with the fission products to form stable, relatively non- volatile compounds thereby minimizing the migration of the fission products into the coolant. The conversion material is preferably a metallic fluoride, such as lead difluoride, and may be in the form of a coating on the fuel core or interior of the cladding, or dispersed within the fuel core. (AEC)

  5. CONCENTEIC TUBULAR FUEL ELEMENT

    DOE Patents [OSTI]

    Wheelock, C.W.

    1960-08-16

    An improved fuel element for an organic-moderated reactor was designed that comprises an inner and an outer container tube, a plurality of spaced, concentric fuel tubes positioned between the container tubes, each of the fuel tubes comprising a core of fissionable material with cladding on the sides thereof, each of the sides having a plurality of fins, the fuel tubes and the container tubes defining annular spaces for coolant flow, and the inner container tube defining a channel for a reactor moderator.

  6. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2005-06-26

    Exotxt is an analysis code that reads finite element results data stored in an exodusII file and generates a file in a structured text format. The text file can be edited or modified via a number of text formatting tools. Exotxt is used by analysis to translate data from the binary exodusII format into a structured text format which can then be edited or modified and then either translated back to exodusII format or tomore » another format.« less

  7. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2005-05-07

    CONEX is a code for joining sequentially in time multiple exodusll database files which all represent the same base mesh topology and geometry. It is used to create a single results or restart file from multiple results or restart files which typically arise as the result of multiple restarted analyses. CONEX is used to postprocess the results from a series of finite element analyses. It can join sequentially the data from multiple results databases intomore » a single database which makes it easier to postprocess the results data.« less

  8. Nuclear reactor fuel element

    DOE Patents [OSTI]

    Johnson, Carl E.; Crouthamel, Carl E.

    1980-01-01

    A nuclear reactor fuel element is described which has an outer cladding, a central core of fissionable or mixed fissionable and fertile fuel material and a layer of oxygen gettering material on the inner surface of the cladding. The gettering material reacts with oxygen released by the fissionable material during irradiation of the core thereby preventing the oxygen from reacting with and corroding the cladding. Also described is an improved method for coating the inner surface of the cladding with a layer of gettering material.

  9. FUEL ELEMENT FABRICATION METHOD

    DOE Patents [OSTI]

    Hix, J.N.; Cooley, G.E.; Cunningham, J.E.

    1960-05-31

    A method is given for assembling and fabricating a fuel element comprising a plurality of spaced parallel fuel plates of a bowed configuration supported by and between a pair of transperse aluminum side plates. In this method, a brasing alloy is preplated on one surface of the aluminum side plates in the form of a cladding or layer-of uniform thickness. Grooves are then cut into the side plates through the alloy layer and into the base aluminum which results in the utilization of thinner aluminum side plates since a portion of the necessary groove depth is supplied by the brazing alloy.

  10. TWISTED RIBBON FUEL ELEMENT

    DOE Patents [OSTI]

    Breden, C.R.; Schultz, A.B.

    1961-06-01

    A reactor core formed of bundles of parallel fuel elements in the form of ribbons is patented. The fuel ribbons are twisted about their axes so as to have contact with one another at regions spaced lengthwise of the ribbons and to be out of contact with one another at locations between these spaced regions. The contact between the ribbons is sufficient to allow them to be held together in a stable bundle in a containing tube without intermediate support, while permitting enough space between the ribbon for coolant flowing.

  11. Actinide targets for the synthesis of super-heavy elements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roberto, J.; Alexander, Charles W.; Boll, Rose Ann; Ezold, Julie G.; Felker, Leslie Kevin; Rykaczewski, Krzysztof Piotr; Hogle, Susan L.

    2015-06-18

    Since 2000, six new super-heavy elements with atomic numbers 113 through 118 have been synthesized in hot fusion reactions of 48Ca beams on actinide targets. These target materials, including 242Pu, 244Pu, 243Am, 245Cm, 248Cm, 249Cf, and 249Bk, are available in very limited quantities and require specialized production and processing facilities resident in only a few research centers worldwide. This report describes the production and chemical processing of heavy actinide materials for super-heavy element research, current availabilities of these materials, and related target fabrication techniques. The impact of actinide materials in super-heavy element discovery is reviewed, and strategies for enhancing themore » production of rare actinides including 249Bk, 251Cf, and 254Es are described.« less

  12. Actinide targets for the synthesis of super-heavy elements

    SciTech Connect (OSTI)

    Roberto, J.; Alexander, Charles W.; Boll, Rose Ann; Ezold, Julie G.; Felker, Leslie Kevin; Rykaczewski, Krzysztof Piotr; Hogle, Susan L.

    2015-06-18

    Since 2000, six new super-heavy elements with atomic numbers 113 through 118 have been synthesized in hot fusion reactions of 48Ca beams on actinide targets. These target materials, including 242Pu, 244Pu, 243Am, 245Cm, 248Cm, 249Cf, and 249Bk, are available in very limited quantities and require specialized production and processing facilities resident in only a few research centers worldwide. This report describes the production and chemical processing of heavy actinide materials for super-heavy element research, current availabilities of these materials, and related target fabrication techniques. The impact of actinide materials in super-heavy element discovery is reviewed, and strategies for enhancing the production of rare actinides including 249Bk, 251Cf, and 254Es are described.

  13. Synthesis and characterization of rare-earth-free magnetic manganese bismuth nanocrystals

    SciTech Connect (OSTI)

    Shen, J; Cui, HZ; Huang, XP; Gong, MG; Qin, W; Kirkeminde, A; Cui, J; Ren, SQ

    2015-01-01

    Earth abundant manganese bismuth (MnBi) has long been of interest due to its largemagnetocrystalline anisotropy and high energy density for advanced permanent magnet applications. However, solution synthesis of MnBi phase is challenging due to the reduction potential mismatch between Mn and Bi elements. In this study, we show a versatile MnBi synthesis method involving the metal co-reduction followed by thermal annealing. The magnetically hard MnBi crystalline phase is then exchange coupled with magnetically soft cobalt coating. Our processing approach offers a promising strategy for manufacturing rare-earth-free magnetic nanocrystals.

  14. The adsorption of rare earth ions using carbonized polydopamine nano shells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Xiaoqi; Luo, Huimin; Mahurin, Shannon Mark; Dai, Sheng; Liu, Rui; Hou, Xisen; Dai, Sheng

    2016-01-07

    Herein we report the structure effects of nano carbon shells prepared by carbonized polydopamine for rare earth elements (REEs) adsorption for the first time. The solid carbon sphere, 60 nm carbon shell and 500 nm carbon shell were prepared and investigated for adsorption and desorption of REEs. The adsorption of carbon shells for REEs was found to be better than the solid carbon sphere. The effect of acidities on the adsorption and desorption properties was discussed in this study. The good adsorption performance of carbon shells can be attributed to their porous structure, large specific surface area, amine group andmore » carbonyl group of dopamine.« less

  15. Synthesis and Characterization of Rare-earth-free Magnetic Manganese Bismuth Nanocrystals

    SciTech Connect (OSTI)

    Shen, Jian Q.; Cui, Huizhong; Huang, Xiaopeng; Gong, Maogang; Qin, Wei; Kirkeminde, Alec; Cui, Jun; Ren, Shenqiang

    2015-01-01

    Earth abundant manganese bismuth (MnBi) has long been of interest due to its large magnetocrystalline anisotropy and high energy density for advanced permanent magnet applications. However, solution synthesis of MnBi phase is challenging due to the reduction potential mismatch between Mn and Bi elements. In this study, we show a versatile MnBi synthesis method involving the metal co-reduction followed by thermal annealing. The magnetically hard MnBi crystalline phase is then exchange coupled with magnetically soft cobalt coating. Our processing approach offers a promising strategy for manufacturing rare-earth-free magnetic nanocrystals.

  16. Cohesive Zone Model User Element

    Energy Science and Technology Software Center (OSTI)

    2007-04-17

    Cohesive Zone Model User Element (CZM UEL) is an implementation of a Cohesive Zone Model as an element for use in finite element simulations. CZM UEL computes a nodal force vector and stiffness matrix from a vector of nodal displacements. It is designed for structural analysts using finite element software to predict crack initiation, crack propagation, and the effect of a crack on the rest of a structure.

  17. Multi-element microelectropolishing method

    DOE Patents [OSTI]

    Lee, Peter J.

    1994-01-01

    A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle.

  18. Multi-element microelectropolishing method

    DOE Patents [OSTI]

    Lee, P.J.

    1994-10-11

    A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle. 10 figs.

  19. REACTOR FUEL ELEMENTS TESTING CONTAINER

    DOE Patents [OSTI]

    Whitham, G.K.; Smith, R.R.

    1963-01-15

    This patent shows a method for detecting leaks in jacketed fuel elements. The element is placed in a sealed tank within a nuclear reactor, and, while the reactor operates, the element is sparged with gas. The gas is then led outside the reactor and monitored for radioactive Xe or Kr. (AEC)

  20. Enhanced pinning in mixed rare earth-123 films

    DOE Patents [OSTI]

    Driscoll, Judith L.; Foltyn, Stephen R.

    2009-06-16

    An superconductive article and method of forming such an article is disclosed, the article including a substrate and a layer of a rare earth barium cuprate film upon the substrate, the rare earth barium cuprate film including two or more rare earth metals capable of yielding a superconductive composition where ion size variance between the two or more rare earth metals is characterized as greater than zero and less than about 10.times.10.sup.-4, and the rare earth barium cuprate film including two or more rare earth metals is further characterized as having an enhanced critical current density in comparison to a standard YBa.sub.2Cu.sub.3O.sub.y composition under identical testing conditions.

  1. Photoconductive circuit element reflectometer

    DOE Patents [OSTI]

    Rauscher, C.

    1987-12-07

    A photoconductive reflectometer for characterizing semiconductor devices at millimeter wavelength frequencies where a first photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short first laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test. Second PCEs are connected along the transmission line to sample the signals on the transmission line when excited into conductance by short second laser light pulses, spaced apart in time a determinable period from the first laser light pulses. Electronic filters connected to each of the second PCEs act as low-pass filters and remove parasitic interference from the sampled signals and output the sampled signals in the form of slowed-motion images of the signals on the transmission line. 4 figs.

  2. Photoconductive circuit element reflectometer

    DOE Patents [OSTI]

    Rauscher, Christen (Alexandria, VA)

    1990-01-01

    A photoconductive reflectometer for characterizing semiconductor devices at millimeter wavelength frequencies where a first photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short first laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test. Second PCEs are connected along the transmission line to sample the signals on the transmission line when excited into conductance by short second laser light pulses, spaced apart in time a variable period from the first laser light pulses. Electronic filters connected to each of the second PCEs act as low-pass filters and remove parasitic interference from the sampled signals and output the sampled signals in the form of slowed-motion images of the signals on the transmission line.

  3. Nuclear fuel element

    DOE Patents [OSTI]

    Armijo, Joseph S.; Coffin, Jr., Louis F.

    1980-04-29

    A nuclear fuel element for use in the core of a nuclear reactor is disclosed and has an improved composite cladding comprised of a moderate purity metal barrier of zirconium metallurgically bonded on the inside surface of a zirconium alloy tube. The metal barrier forms a shield between the alloy tube and a core of nuclear fuel material enclosed in the composite cladding. There is a gap between the cladding and the core. The metal barrier forms about 1 to about 30 percent of the thickness of the composite cladding and has low neutron absorption characteristics. The metal barrier serves as a preferential reaction site for gaseous impurities and fission products and protects the alloy tube from contact and reaction with such impurities and fission products. Methods of manufacturing the composite cladding are also disclosed.

  4. Nuclear fuel element

    DOE Patents [OSTI]

    Armijo, Joseph S.; Coffin, Jr., Louis F.

    1983-01-01

    A nuclear fuel element for use in the core of a nuclear reactor is disclosed and has a composite cladding having a substrate and a metal barrier metallurgically bonded on the inside surface of the substrate so that the metal barrier forms a shield between the substrate and the nuclear fuel material held within the cladding. The metal barrier forms about 1 to about 30 percent of the thickness of the cladding and is comprised of a low neutron absorption metal of substantially pure zirconium. The metal barrier serves as a preferential reaction site for gaseous impurities and fission products and protects the substrate from contact and reaction with such impurities and fission products. The substrate of the composite cladding is selected from conventional cladding materials and preferably is a zirconium alloy. Methods of manufacturing the composite cladding are also disclosed.

  5. SALICYLATE PROCESS FOR THORIUM SEPARATION FROM RARE EARTHS

    DOE Patents [OSTI]

    Cowan, G.A.

    1959-08-25

    The separation of thorium from rare earths is accomplished by forming an aqueous solution of salts of thorium and rare earths and sufficient acetate buffer to provide a pH of between 2 and 5, adding an ammonium salicylate to the aqueous buffered solution, contacting the resultant solution with a substantially water-immiscible organic solvent mixture of an ether and an ester, and separating the solvent extract phase containing thorium salicylate from the aqueous phase containing the rare earths.

  6. Jefferson Lab Laser Twinkles in Rare Color | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser Twinkles in Rare Color Jefferson Lab Laser Twinkles in Rare Color NEWPORT NEWS, VA, Dec. 21 - December is a time for twinkling lights, and scientists at the Department of Energy's Thomas Jefferson National Accelerator Facility are delivering. They've just produced a long-sought, rare color of laser light 100 times brighter than that generated anywhere else. The light was produced by Jefferson Lab's Free-Electron Laser facility. The laser delivered vacuum ultraviolet light in the form of 10

  7. COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technical Challenges | Princeton Plasma Physics Lab February 4, 2015, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Facility for Rare Isotope Beams - Scientific Opportunities and Technical Challenges Dr. Georg Bollen Michigan State University - The Facility for Rare Isotope Beams Wednesday Colloquium, February 4, 2015, "Facility for Rare Isotope Beams - Scientific Opportunities and Technial Chanllenges", Dr. Georg Bollen Colloquium Committee: The Princeton Plasma Physics

  8. Pyrometallurgical processes for recovery of actinide elements

    SciTech Connect (OSTI)

    Battles, J.E.; Laidler, J.J.; McPheeters, C.C.; Miller, W.E.

    1994-01-01

    A metallic fuel alloy, nominally U-20-Pu-lOZr, is the key element of the Integral Fast Reactor (IFR) fuel cycle. Metallic fuel permits the use of an innovative, simple pyrometallurgical process, known as pyroprocessing, (the subject of this report), which features fused salt electrorefining of the spent fuel. Electrorefining separates the actinide elements from fission products, without producing a separate stream of plutonium. The plutonium-bearing product is contaminated with higher actinides and with a minor amount of rare earth fission products, making it diversion resistant while still suitable as a fuel material in the fast spectrum of the IFR core. The engineering-scale demonstration of this process will be conducted in the refurbished EBR-II Fuel Cycle Facility, which has entered the start-up phase. An additional pyrometallurgical process is under development for extracting transuranic (TRU) elements from Light Water Reactor (LWR) spent fuel in a form suitable for use as a feed to the IFR fuel cycle. Four candidate extraction processes have been investigated and shown to be chemically feasible. The main steps in each process are oxide reduction with calcium or lithium, regeneration of the reductant and recycle of the salt, and separation of the TRU product from the bulk uranium. Two processes, referred to as the lithium and salt transport (calcium reductant) processes, have been selected for engineering-scale demonstration, which is expected to start in late 1993. An integral part of pyroprocessing development is the treatment and packaging of high-level waste materials arising from the operations, along with the qualification of these waste forms for disposal in a geologic repository.

  9. DOE Announces RFI on Rare Earth Metals | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RFI on Rare Earth Metals DOE Announces RFI on Rare Earth Metals May 6, 2010 - 12:00am Addthis Washington, D.C. - The Department of Energy has released a Request for Information (RFI) soliciting information on rare earth metals and other materials used in the energy sector. The request is specifically focused on rare earth metals (e.g., lanthanum, cerium and neodymium) and several other metals including lithium and cobalt, but respondents are welcome to identify other materials of interest. These

  10. Characterization and Recovery of Rare Earths from Coal and By...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Characterization and Recovery of Rare Earths from Coal and By-Products ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  11. At 85, Mr. Rare Earth is Retiring | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    At 85, Mr. Rare Earth is Retiring At 85, Mr. Rare Earth is Retiring February 19, 2016 - 11:00am Addthis We first talked to Dr. Gschneider back in 2013 for one of our <a href="/node/609731">"10 Questions with a Scientist"</a> blogs. Today he looks back at over 60 years of studying rare earth metals. We first talked to Dr. Gschneider back in 2013 for one of our "10 Questions with a Scientist" blogs. Today he looks back at over 60 years of studying rare

  12. PROCESS FOR PREPARING RARE EARTH CHROMITE BASED CERAMIC MATERIALS...

    Office of Scientific and Technical Information (OSTI)

    Title: PROCESS FOR PREPARING RARE EARTH CHROMITE BASED CERAMIC MATERIALS AND THE MATERIALS OBTAINED. (in French) Authors: Elston, J. ; Roux, M. Publication Date: 1971-01-01 OSTI ...

  13. CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED...

    Office of Scientific and Technical Information (OSTI)

    CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM ALLOYS FOR HIGH TEMPERATURE APPLICATION Citation Details In-Document Search Title: CHARACTERIZATION OF NEAR ...

  14. Magnetic properties of RT2Zn20; R = rare earth, T = Fe, Co, Ru, Os and Ir

    SciTech Connect (OSTI)

    Jia, Shuang

    2008-12-15

    It is well known that rare earth intermetallic compounds have versatile, magnetic properties associated with the 4f electrons: a local moment associated with the Hund's rule ground state is formed in general, but a strongly correlated, hybridized state may also appear for specific 4f electronic configuration (eg. for rare earth elements such as Ce or Yb). On the other hand, the conduction electrons in rare earth intermetallic compounds, certainly ones associated with non hybridizing rare earths, usually manifest non-magnetic behavior and can be treated as a normal, non-interacted Fermi liquid, except for some 3d-transition metal rich binary or ternary systems which often manifest strong, itinerant, d electron dominant magnetic behavior. Of particular interest are examples in which the band filling of the conduction electrons puts the system in the vicinity of a Stoner transition: such systems, characterized as nearly or weakly ferromagnet, manifest strongly correlated electronic properties [Moriya, 1985]. For rare earth intermetallic compounds, such systems provide an additional versatility and allow for the study of the behaviors of local moments and hybridized moments which are associated with 4f electron in a correlated conduction electron background.

  15. Resistive hydrogen sensing element

    DOE Patents [OSTI]

    Lauf, Robert J.

    2000-01-01

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  16. COMPARTMENTED REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Cain, F.M. Jr.

    1962-09-11

    A method of making a nuclear reactor fuel element of the elongated red type is given wherein the fissionable fuel material is enclosed within a tubular metal cladding. The method comprises coating the metal cladding tube on its inside wall with a brazing alloy, inserting groups of cylindrical pellets of fissionable fuel material into the tube with spacing members between adjacent groups of pellets, sealing the ends of the tubes to leave a void space therewithin, heating the tube and its contents to an elevated temperature to melt the brazing alloy and to expand the pellets to their maximum dimensions under predetermined operating conditions thereby automatically positioning the spacing members along the tube, and finally cooling the tube to room temperature whereby the spacing disks become permanently fixed at their edges in the brazing alloy and define a hermetically sealed compartment for each fl group of fuel pellets. Upon cooling, the pellets contract thus leaving a space to accommodate thermal expansion of the pellets when in use in a reactor. The spacing members also provide lateral support for the tubular cladding to prevent collapse thereof when subjected to a reactor environment. (AEC)

  17. Tunable, rare earth-doped solid state lasers

    DOE Patents [OSTI]

    Emmett, John L.; Jacobs, Ralph R.; Krupke, William F.; Weber, Marvin J.

    1980-01-01

    Laser apparatus comprising combinations of an excimer pump laser and a rare earth-doped solid matrix, utilizing the 5d-4f radiative transition in a rare earth ion to produce visible and ultra-violet laser radiation with high overall efficiency in selected cases and relatively long radiative lifetimes.

  18. CADMIUM-RARE EARTH BORATE GLASS AS REACTOR CONTROL MATERIAL

    DOE Patents [OSTI]

    Ploetz, G.L.; Ray, W.E.

    1958-11-01

    A reactor control rod fabricated from a cadmiumrare earth-borate glass is presented. The rare earth component of this glass is selected from among those rare earths having large neutron capture cross sections, such as samarium, gadolinium or europium. Partlcles of this glass are then dispersed in a metal matrix by standard powder metallurgy techniques.

  19. Influence of rare earth doping on thermoelectric properties of SrTiO{sub 3} ceramics

    SciTech Connect (OSTI)

    Liu, J. Wang, C. L.; Li, Y.; Su, W. B.; Zhu, Y. H.; Li, J. C.; Mei, L. M.

    2013-12-14

    Thermoelectric properties of SrTiO{sub 3} ceramics, doped with different rare earth elements, were investigated in this work. It's found that the ionic radius of doping elements plays an important role on thermoelectric properties: SrTiO{sub 3} ceramics doped with large rare earth ions (such as La, Nd, and Sm) exhibit large power factors, and those doped with small ions (such as Gd, Dy, Er, and Y) exhibit low thermal conductivities. Therefore, a simple approach for enhancing the thermoelectric performance of SrTiO{sub 3} ceramics is proposed: mainly doped with large ions to obtain a large power factor and, simultaneously, slightly co-doped with small ions to obtain a low thermal conductivity. Based on this rule, Sr{sub 0.8}La{sub 0.18}Yb{sub 0.02}TiO{sub 3} ceramics were prepared, whose ZT value at 1 023 K reaches 0.31, increasing by a factor of 19% compared with the single-doped counterpart Sr{sub 0.8}La{sub 0.2}TiO{sub 3} (ZT = 0.26)

  20. FUEL ELEMENT FOR NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Evans, T.C.; Beasley, E.G.

    1961-01-17

    A fuel element for neutronic reactors, particularly the gas-cooled type of reactor, is described. The element comprises a fuel-bearing plate rolled to form a cylinder having a spiral passageway passing from its periphery to its center. In operation a coolant is admitted to the passageway at the periphery of the element, is passed through the spiral passageway, and emerges into a central channel defined by the inner turn of the rolled plate. The advantage of the element is that the fully heated coolant (i.e., coolant emerging into the central channel) is separated and thus insulated from the periphery of the element, which may be in contact with a low-temperature moderator, by the intermediate turns of the spiral fuel element.

  1. NUCLEAR REACTOR FUEL ELEMENT ASSEMBLY

    DOE Patents [OSTI]

    Stengel, F.G.

    1963-12-24

    A method of fabricating nuclear reactor fuel element assemblies having a plurality of longitudinally extending flat fuel elements in spaced parallel relation to each other to form channels is presented. One side of a flat side plate is held contiguous to the ends of the elements and a welding means is passed along the other side of the platertransverse to the direction of the longitudinal extension of the elements. The setting and speed of travel of the welding means is set to cause penetration of the side plate with welds at bridge the gap in each channel between adjacent fuel elements with a weld-through bubble of predetermined size. The fabrication of a high strength, dependable fuel element is provided, and the reduction of distortion and high production costs are facilitated by this method. (AEC)

  2. Finite element modeling of lightning

    SciTech Connect (OSTI)

    Hwang, C.C.; Huang, S.R.; Bor, S.S.

    1995-12-31

    In this paper the transmission line equation which describes the transient voltage and current distributions of a lightning stroke is employed. Finite element method is used to derive the element equations and one-dimensional linear elements are used to discretize the field region. The implicit Newmark time integration technique is used to convert the resulting second-order ordinary differential equations into a set of recurrence equations which are then solved at each time step. Numerical example is included and discussed.

  3. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-05-16

    A fuel element particularly adapted for use in nuclear reactors of high power density is offered. It has fissionable fuel pellet segments mounted in a tubular housing and defining a central passage in the fuel element. A burnable poison element extends through the central passage, which is designed to contain more poison material at the median portion than at the end portions thereby providing a more uniform hurnup and longer reactivity life.

  4. FUEL ELEMENTS FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Blainey, A.; Lloyd, H.

    1961-07-11

    A method of sheathing a tubular fuel element for a nuclear reactor is described. A low melting metal core member is centered in a die, a layer of a powdered sheathing substance is placed on the bottom of the die, the tubular fuel element is inserted in the die, the space between the tubular fuel element and the die walls and core member is filled with the same powdered sheathing substance, a layer of the same substance is placed over the fissile material, and the charge within the die is subjected to pressure in the direction of the axis of the fuel element at the sintering temperature of the protective substance.

  5. Element Labs | Open Energy Information

    Open Energy Info (EERE)

    Labs Jump to: navigation, search Name: Element Labs Address: 3350 Scott Blvd Place: Santa Clara, California Zip: 95054 Region: Bay Area Sector: Efficiency Product: LED Producer...

  6. Cerium-Based Magnets: Novel High Energy Permanent Magnet Without Critical Elements

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: Ames Laboratory will develop a new class of permanent magnets based on the more commonly available element cerium for use in both EVs and renewable power generators. Cerium is 4 times more abundant and significantly less expensive than the rare earth element neodymium, which is frequently used in today’s most powerful magnets. Ames Laboratory will combine other metal elements with cerium to create a new magnet that can remain stable at the high temperatures typically found in electric motors. This new magnetic material will ultimately be demonstrated in a prototype electric motor, representing a cost-effective and efficient alternative to neodymium-based motors.

  7. Rare-earth-free magnet made from cheap materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare-earth-free magnet Rare-earth-free magnet made from cheap materials Researchers create a powerful permanent magnet out of iron and nitrogen as part of a program to cut the need for rare-earth metals May 17, 2016 Mars (a) 2 × 1016/cm2 fluence, embedded dots can be observed (rich N region), with a diameter of 20 nm, separated by 140 to 200 nm; (b) 8 × 1016/cm2 fluence, besides embedded dots, obvious cracks appeared; (c) 1 × 1017/cm2 fluence, an obvious microstructure is generated, with

  8. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier S.; Hajaligol, Mohammad R.; Lilly, Jr., A. Clifton

    2001-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  9. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, V.K.; Deevi, S.C.; Fleischhauer, G.S.; Hajaligol, M.R.; Lilly, A.C. Jr.

    1997-04-15

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, {<=}1% Cr and either {>=}0.05% Zr or ZrO{sub 2} stringers extending perpendicular to an exposed surface of the heating element or {>=}0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, {<=}2% Ti, {<=}2% Mo, {<=}1% Zr, {<=}1% C, {<=}0.1% B, {<=}30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, {<=}1% rare earth metal, {<=}1% oxygen, {<=}3% Cu, balance Fe. 64 figs.

  10. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier S.; Hajaligol, Mohammad R.; Lilly, Jr., A. Clifton

    1999-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  11. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier S.; Hajaligol, Mohammad R.; Lilly, Jr., A. Clifton

    1997-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  12. US-Japan workshop Q-181 on high heat flux components and plasma-surface interactions for next devices: Proceedings

    SciTech Connect (OSTI)

    McGrath, R.T.; Yamashina, T.

    1994-04-01

    This report contain viewgraphs of papers from the following sessions: plasma facing components issues for future machines; recent PMI results from several tokamaks; high heat flux technology; plasma facing components design and applications; plasma facing component materials and irradiation damage; boundary layer plasma; plasma disruptions; conditioning and tritium; and erosion/redeposition.

  13. Department of Energy Hosts First Steering Committee Meeting on U.S.- Japan Joint Nuclear Energy Action Plan

    Broader source: Energy.gov [DOE]

    WASHINGTON, DC - U.S. Department of Energy Assistant Secretary for Nuclear Energy, Dennis R. Spurgeon, today hosted Director-General of Japan's Agency of Natural Resources and Energy, Harufumi...

  14. US-Japan seminar on magnetic multilayered structures held in Kauai, Hawaii on 15-17 May 1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-17

    This seminar included the following topics: Advancement in soft magnetic materials by means of multilayering, Elastic moduli of metallic multilayered films measured by Brillouin Scattering method, Structural aspects of the superlattices under high pressure, Structural influence on the magnetic anisotropy of Co/Pd superlattices, Low dimensional magnetic and structural effects in single crystals grown by molecular beam epitaxy, Polarized neutron reflection and diffraction from magnetic superlattices, and Nuclear magnetic resonance studies of magnetic multilayers.

  15. DOE Science Showcase - Rare Earth Metal Research from DOE Databases...

    Office of Scientific and Technical Information (OSTI)

    Energy - LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells Science.gov - H.R.4866 - Rare Earths Supply-Chain Technology and Resources Transformation Act ...

  16. ORNL Licenses Rare Earth Magnet Recycling Process to Momentum Technologies

    Broader source: Energy.gov [DOE]

    The Department of Energy’s Oak Ridge National Laboratory and Momentum Technologies have signed a non-exclusive licensing agreement for an ORNL process designed to recover rare earth magnets from used computer hard drives.

  17. Chemical pressure and hidden one-dimensional behavior in rare...

    Office of Scientific and Technical Information (OSTI)

    report on the first optical measurements of the rare-earth tri-telluride charge-density-wave systems. Our data, collected over an extremely broad spectral range, allow us to...

  18. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus; Yanagihara, Naohisa; Dyke, James T.; Vemulapalli, Krishna

    1991-09-03

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  19. DOE Science Showcase - Rare Earth Metal Research from DOE Databases...

    Office of Scientific and Technical Information (OSTI)

    Energy Citations Database - Intermultiplet transitions in rare-earth metals DOE Green Energy - LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells ...

  20. Extraordinary Responsive Rare Earth Magnetic Materials | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Extraordinary Responsive Rare Earth Magnetic Materials Research Personnel Updates Publications https://www.ameslab.gov/dmse/highlight/real-estate-atoms-it-all-about-location-location-location Read More Rare Earth Alloys - Why Purity Matters Read More A Mystery at Cryogenic Temperatures Read More Previous Pause Next Synthesis Responsive systems, where a small change of an extrinsic thermodynamic variable, such as temperature, pressure, or magnetic field, triggers an intrinsic phase

  1. METHOD OF MAKING ALLOYS OF SECOND RARE EARTH SERIES METALS

    DOE Patents [OSTI]

    Baker, R.D.; Hayward, B.R.

    1963-01-01

    >This invention relates to a process for alloying the second rare earth series metals with Mo, Nb, or Zr. A halide of the rare earth metal is mixed with about 1 to 20 at.% of an oxide of Mo, Nb, or Zr. Iodine and an alkali or alkaline earth metal are added, and the resulting mixture is heated in an inert atmosphere to 350 deg C. (AEC)

  2. DOE - Office of Legacy Management -- International Rare Metals Refinery Inc

    Office of Legacy Management (LM)

    - NY 38 Rare Metals Refinery Inc - NY 38 Site ID (CSD Index Number): NY.38 Site Name: International Rare Metals Refinery, Inc. Site Summary: Site Link: External Site Link: Alternate Name(s): Canadian Radium and Uranium Corporation Alternate Name Documents: NY.38-1 Location: 69 Kisco Avenue, Mt. Kisco, New York Location Documents: NY.38-1 NY.38-3 Historical Operations (describe contaminants): Manufactured and distributed radium and polonium products. Historical Operations Documents: NY.38-5

  3. Magnetic coupling at rare earth ferromagnet/transition metal ferromagnet

    Office of Scientific and Technical Information (OSTI)

    interfaces: A comprehensive study of Gd/Ni (Journal Article) | SciTech Connect Magnetic coupling at rare earth ferromagnet/transition metal ferromagnet interfaces: A comprehensive study of Gd/Ni Citation Details In-Document Search Title: Magnetic coupling at rare earth ferromagnet/transition metal ferromagnet interfaces: A comprehensive study of Gd/Ni Thin film magnetic heterostructures with competing interfacial coupling and Zeeman energy provide a fertile ground to study phase transition

  4. Method for detecting an element

    DOE Patents [OSTI]

    Blackwood, Larry G.; Reber, Edward L.; Rohde, Kenneth W.

    2007-02-06

    A method for detecting an element is disclosed and which includes the steps of providing a gamma-ray spectrum which depicts, at least in part, a test region having boundaries, and which has a small amount of the element to be detected; providing a calculation which detects the small amount of the element to be detected; and providing a moving window and performing the calculation within the moving window, and over a range of possible window boundaries within the test region to determine the location of the optimal test region within the gamma-ray spectrum.

  5. Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.; Rawn, Claudia J.; Richardson, Jim

    2016-01-01

    When appropriately activated, alkali rare-earth double phosphates of the form: M3RE(PO4)2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K3RE(PO4)2 with RE = Lu, Er, Ho, Dy, Gd, Nd, Ce, plus Ymore » and Sc - as well as the compounds: A3Lu(PO4)2, with A = Rb, and Cs. The double phosphate K3Lu(PO4)2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K3Lu(PO4)2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K3Lu(PO4)2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K3Yb(PO4)2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single-crystal growth methods structural systematics, and thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by X-ray and neutron diffraction methods, are treated here.« less

  6. Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

    SciTech Connect (OSTI)

    Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.; Rawn, Claudia J.; Richardson, Jim

    2016-01-01

    When appropriately activated, alkali rare-earth double phosphates of the form: M3RE(PO4)2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K3RE(PO4)2 with RE = Lu, Er, Ho, Dy, Gd, Nd, Ce, plus Y and Sc - as well as the compounds: A3Lu(PO4)2, with A = Rb, and Cs. The double phosphate K3Lu(PO4)2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K3Lu(PO4)2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K3Lu(PO4)2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K3Yb(PO4)2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single

  7. FUEL ELEMENTS FOR NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Foote, F.G.; Jette, E.R.

    1963-05-01

    A fuel element for a nuclear reactor is described that consists of a jacket containing a unitary core of fissionable material and a filling of a metal of the group consisting of sodium and sodium-potassium alloys. (AEC)

  8. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Dickson, J.J.

    1963-09-24

    A method is described whereby fuel tubes or pins are cut, loaded with fuel pellets and a heat transfer medium, sealed at each end with slotted fittings, and assembled into a rectangular tube bundle to form a fuel element. The tubes comprising the fuel element are laterally connected between their ends by clips and tabs to form a linear group of spaced parallel tubes, which receive their vertical support by resting on a grid. The advantages of this method are that it permits elimination of structural material (e.g., fuel-element cans) within the reactor core, and removal of at least one fuel pin from an element and replacement thereof so that a burnable poison may be utilized during the core lifetime. (AEC)

  9. Environmental research on actinide elements

    SciTech Connect (OSTI)

    Pinder, J.E. III; Alberts, J.J.; McLeod, K.W.; Schreckhise, R.G.

    1987-08-01

    The papers synthesize the results of research sponsored by DOE's Office of Health and Environmental Research on the behavior of transuranic and actinide elements in the environment. Separate abstracts have been prepared for the 21 individual papers. (ACR)

  10. U.S. Rare Earth Magnet Patents Table © 6-28-2016 page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ...itasaku-gun, JAPAN) Rare earth bonded magnet Abstract A rare earth bonded magnet is provided which is produced such that a mixture which comprises: a rare earth magnet powder; a ...

  11. U.S. Rare Earth Magnet Patents Table © 3-1-2016 page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Magnet Patents Table 3-1-2016 page 1 Disclaimer: This U.S. Rare Earth Magnet Patents Table contains a sample of the rare earth-magnet patents issued by the U.S. ...

  12. Theory of rare Kaon and Pion decays (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Theory of rare Kaon and Pion decays Citation Details In-Document Search Title: Theory of rare Kaon and Pion decays I discuss recent theoretical progress in rare (leptonic) decay...

  13. ARPA-E Workshop on Rare Earth and Critical Materials | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ARPA-E Workshop on Rare Earth and Critical Materials ARPA-E Workshop on Rare Earth and Critical Materials ARPA-E Workshop on Rare Earth and Critical Materials, December 6, 2010 PDF...

  14. Wall rock-magma interactions in Etna, Italy, studied by U-Th disequilibrium and rare earth element systematics

    SciTech Connect (OSTI)

    Villemant, B. CNRS URA 196, Paris ); Michaud, V.; Metrich, N. )

    1993-03-01

    [sup 230]Th/[sup 238]U disequilibria have been studied in xenoliths and associated lavas of the 1892 and 1989 eruptions of Etna. Most xenoliths are out of secular equilibrium within 1 [sigma] errors and have lower [sup 230]Th/[sup 232]Th ratios than their host magmas. Siliceous and peraluminous xenoliths display large ranges of Th/U ratios for similar [sup 230]Th/[sup 232]Th values, which are interpreted in terms of Th isotopic rehomogenization. The siliceous xenoliths have also suffered thorium and uranium enrichments, which are best explained by chemical diffusion between xenolith melts and differentiated magmas. Estimates of thorium self-diffusivities and [sup 230]Th-[sup 238]U disequilibria give age constraints on these events corresponding to the last major volcanic event of Etna at 14 ka (formation of the elliptic crater caldera). These results suggest that magma storage in superficial and long-lived magma chambers favors the thorium isotopic homogenization of wall rocks by a thermal effect. Chemical diffusion of uranium and thorium and isotopic homogenization between siliceous melts of wall rocks and differentiated magmas may significantly modify the initial thorium isotopic compositions. Such contamination processes could explain the large variations of the [sup 230]Th/[sup 232]Th initial ratios of Etna magmas. 33 refs., 7 figs., 1 tab.

  15. Crystal structure and optical properties of oxynitride rare-earth tantalates RTa-(O, N) (R = Nd, Gd, Y)

    SciTech Connect (OSTI)

    Kikkawa, Shinichi Takeda, Takashi; Yoshiasa, Akira; Maillard, Pascal; Tessier, Franck

    2008-04-01

    X-ray absorption and photoluminescence were used to investigate the structure of rare-earth tantalum oxynitrides RTa-(O, N) (R = Nd, Gd, Y). Owing to the size of the rare-earth element, the crystal structure tends towards the pyrochlore or defect fluorite-type structure. EXAFS suggested neodymium and yttrium atoms are coordinated either by 6 + 2 or 6 oxygen/nitrogen atoms in the Nd or Y respective oxynitrides although the coordination number of tantalum is six in both compounds. Photoluminescence for 5 at.% doped europium showed the spectra compatible with the point symmetry C{sub 3v} lower than O{sub h} in fluorite and D{sub 3d} in pyrochlore structure type for both the Gd and Y tantalum oxynitrides. These measurements supported that their structure types were basically pyrochlore for Nd and Gd tantalum oxynitrides and defect fluorite for Y tantalum oxynitride but they are highly defective.

  16. The impact of trade costs on rare earth exports : a stochastic frontier estimation approach.

    SciTech Connect (OSTI)

    Sanyal, Prabuddha; Brady, Patrick Vane; Vugrin, Eric D.

    2013-09-01

    The study develops a novel stochastic frontier modeling approach to the gravity equation for rare earth element (REE) trade between China and its trading partners between 2001 and 2009. The novelty lies in differentiating betweenbehind the border' trade costs by China and theimplicit beyond the border costs' of China's trading partners. Results indicate that the significance level of the independent variables change dramatically over the time period. While geographical distance matters for trade flows in both periods, the effect of income on trade flows is significantly attenuated, possibly capturing the negative effects of financial crises in the developed world. Second, the total export losses due tobehind the border' trade costs almost tripled over the time period. Finally, looking atimplicit beyond the border' trade costs, results show China gaining in some markets, although it is likely that some countries are substituting away from Chinese REE exports.

  17. Rare earth/iron fluoride and methods for making and using same

    DOE Patents [OSTI]

    Schmidt, Frederick A.; Wheelock, John T.; Peterson, David T.

    1991-12-17

    A particulate mixture of Fe.sub.2 O.sub.3 and RE.sub.2 O.sub.3, where RE is a rare earth element, is reacted with an excess of HF acid to form an insoluble fluoride compound (salt) comprising REF.sub.3 and FeF.sub.3 present in solid solution in the REF.sub.3 crystal lattice. The REF.sub.3 /FeF.sub.3 compound is dried to render it usable as a reactant in the thermite reduction process as well as other processes which require an REF.sub.3 /FeF.sub.3 mixture. The dried REF.sub.3 /FeF.sub.3 compound comprises about 5 weight % to about 40 weight % of FeF.sub.3 and the balance REF.sub.3 to this end.

  18. Modeling the Value Recovery of Rare Earth Permanent Magnets at End-of-Life

    SciTech Connect (OSTI)

    Cong, Liang; Jin, Hongyue; Fitsos, Pete; McIntyre, Timothy; Yih, Yuehwern; Zhao, Fu; Sutherland, John W.

    2015-05-21

    Permanent magnets containing rare earth elements (REEs) such as Dysprosium and Neodymium offer an advantage over non-REE containing magnets (e.g. ferrite or AlNiCo) in terms of power relative to size. However, REE availability has varied significantly in recent years leading to volatility in the cost of rare earth permanent magnets (REPMs). The supply of REEs can be increased by recycling consumer products and industrial machinery that contain REPMs at product end-of-life (EOL). This paper discusses the REE recovery process for EOL products. The optimal dismantling of products is examined with an emphasis placed on obtaining used REPMs. The challenge of collecting, managing, transporting, and processing used products is addressed through the development of a cost model for REPM recovery. This model is used to investigate several EOL strategies for recovering REPMs. Sensitivity analysis is conducted to identify the key factors that influence value recovery economics. A hard disk drive serves as a case study for model demonstration.

  19. Modeling the Value Recovery of Rare Earth Permanent Magnets at End-of-Life

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cong, Liang; Jin, Hongyue; Fitsos, Pete; McIntyre, Timothy; Yih, Yuehwern; Zhao, Fu; Sutherland, John W.

    2015-05-21

    Permanent magnets containing rare earth elements (REEs) such as Dysprosium and Neodymium offer an advantage over non-REE containing magnets (e.g. ferrite or AlNiCo) in terms of power relative to size. However, REE availability has varied significantly in recent years leading to volatility in the cost of rare earth permanent magnets (REPMs). The supply of REEs can be increased by recycling consumer products and industrial machinery that contain REPMs at product end-of-life (EOL). This paper discusses the REE recovery process for EOL products. The optimal dismantling of products is examined with an emphasis placed on obtaining used REPMs. The challenge ofmore » collecting, managing, transporting, and processing used products is addressed through the development of a cost model for REPM recovery. This model is used to investigate several EOL strategies for recovering REPMs. Sensitivity analysis is conducted to identify the key factors that influence value recovery economics. A hard disk drive serves as a case study for model demonstration.« less

  20. Modeling the value recovery of rare earth permanent magnets at end-of-life

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cong, Liang; Jin, Hongyue; Fitsos, Pete; McIntyre, Timothy; Yih, Yuehwern; Zhao, Fu; Sutherland, John W.

    2015-01-01

    Permanent magnets containing rare earth elements (REEs) such as Dysprosium and Neodymium offer an advantage over non-REE containing magnets (e.g., ferrite and AlNiCo) in terms of power relative to size. However, REE availability has varied significantly in recent years leading to volatility in the cost of rare earth permanent magnets (REPMs). The supply of REEs can be increased by recycling consumer products and industrial machinery that contain REPMs at product end-of-life (EOL). This paper discusses the REE recovery process for EOL products. The optimal dismantling of products is examined with an emphasis placed on obtaining used REPMs. The challenge ofmore » collecting, managing, transporting, and processing used products is addressed through the development of a cost model for REPM recovery. This model is used to investigate several EOL strategies for recovering REPMs. Sensitivity analysis is conducted to identify the key factors that influence value recovery economics. A hard disk drive serves as a case study for model demonstration.« less

  1. Modeling the value recovery of rare earth permanent magnets at end-of-life

    SciTech Connect (OSTI)

    Cong, Liang; Jin, Hongyue; Fitsos, Pete; McIntyre, Timothy; Yih, Yuehwern; Zhao, Fu; Sutherland, John W.

    2015-01-01

    Permanent magnets containing rare earth elements (REEs) such as Dysprosium and Neodymium offer an advantage over non-REE containing magnets (e.g., ferrite and AlNiCo) in terms of power relative to size. However, REE availability has varied significantly in recent years leading to volatility in the cost of rare earth permanent magnets (REPMs). The supply of REEs can be increased by recycling consumer products and industrial machinery that contain REPMs at product end-of-life (EOL). This paper discusses the REE recovery process for EOL products. The optimal dismantling of products is examined with an emphasis placed on obtaining used REPMs. The challenge of collecting, managing, transporting, and processing used products is addressed through the development of a cost model for REPM recovery. This model is used to investigate several EOL strategies for recovering REPMs. Sensitivity analysis is conducted to identify the key factors that influence value recovery economics. A hard disk drive serves as a case study for model demonstration.

  2. Method for treating rare earth-transition metal scrap

    DOE Patents [OSTI]

    Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.

    1992-12-29

    Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a rare earth fluoride-bearing flux of CaF[sub 2], CaCl[sub 2] or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy. 3 figs.

  3. Method for treating rare earth-transition metal scrap

    DOE Patents [OSTI]

    Schmidt, Frederick A.; Peterson, David T.; Wheelock, John T.; Jones, Lawrence L.

    1992-12-29

    Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a prefused, rare earth fluoride-bearing flux of CaF.sub.2, CaCl.sub.2 or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy.

  4. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, J.P.; Johnson, T.R.

    1992-01-01

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

  5. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, J.P.; Johnson, T.R.

    1994-08-09

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner. 1 fig.

  6. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, John P.; Johnson, Terry R.

    1994-01-01

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

  7. Rare earth-transition metal scrap treatment method

    DOE Patents [OSTI]

    Schmidt, Frederick A.; Peterson, David T.; Wheelock, John T.; Jones, Lawrence L.; Lincoln, Lanny P.

    1992-02-11

    Rare earth-transition metal (e.g. iron) scrap (e.g. Nd-Fe-B scrap) is melted to reduce the levels of tramp oxygen and nitrogen impurities therein. The tramp impurities are reduced in the melt by virtue of the reaction of the tramp impurities and the rare earth to form dross on the melt. The purified melt is separated from the dross for reuse. The oxygen and nitrogen of the melt are reduced to levels acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets.

  8. Rare earth-transition metal scrap treatment method

    DOE Patents [OSTI]

    Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.; Lincoln, L.P.

    1992-02-11

    Rare earth-transition metal (e.g. iron) scrap (e.g. Nd-Fe-B scrap) is melted to reduce the levels of tramp oxygen and nitrogen impurities therein. The tramp impurities are reduced in the melt by virtue of the reaction of the tramp impurities and the rare earth to form dross on the melt. The purified melt is separated from the dross for reuse. The oxygen and nitrogen of the melt are reduced to levels acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. 3 figs.

  9. Multi-element Neutron Energy Spectrometer

    SciTech Connect (OSTI)

    Sanjoy Mukhopadhyay, Richard Maurer, Ronald Wolff, Stephen Mitchell, Alexis Reed

    2009-09-11

    In the area of nuclear radiological emergency response and preparedness applications, interest in neutron detection stems from several factors. Unlike gamma rays, which are abundant in nature and present serious difficulties in differentiating a signal from a changing background, whose values are location specific, neutrons are rare and nearly homogenous in spatial distribution. Additionally, many special nuclear materials (SNM) emit neutrons either directly by spontaneous fission or produce neutrons indirectly through (α, n) reactions in nearby light elements. Also of importance in detection scenarios is the fact that neutrons are not easily attenuated. Typically neutron detection is done by simply counting the low energy thermal neutrons by employing pressurized helium tubes operated at high voltages. Not much emphasis is put on determining the energy of the incident neutrons. However, critical information can be obtained by analyzing the neutron energy given off from radioactive materials. In the detection of an SNM, neutron energy information from an unknown source can be of paramount importance. We have modeled, designed, and prototyped multi-element neutron energy spectrometers that contain three to five pressurized helium tubes of dimensions 2" diam. x 10" in length. Each individual helium tube has a specific amount of high density plastic neutron moderators to slow down the incident energetic neutrons to an accurately estimated energy. A typical spectrometer is a set of moderator cylinders surrounding detectors that have high efficiency for detecting thermal neutrons. The larger the moderator, the higher the energy of incident neutrons for which the detector assembly has matched detection efficiency. If all the detectors are exposed to the same radiation field and the efficiency as a function of energy (response function) of each of the detectors is known, the neutron energy spectrum can be determined from the detector count rates. Monte Carlo simulation

  10. Room Temperature Dispenser Photocathode Using Elemental Cesium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Room Temperature Dispenser Photocathode Using Elemental Cesium Room Temperature Dispenser Photocathode Using Elemental Cesium Los Alamos National Laboratory (LANL) researchers have...

  11. Element Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Element Energy Ltd Jump to: navigation, search Name: Element Energy Ltd. Place: Cambridge, England, United Kingdom Zip: CB1 2JD Product: Cambridge-based strategic energy...

  12. Element Labs Inc | Open Energy Information

    Open Energy Info (EERE)

    Labs Inc Jump to: navigation, search Name: Element Labs, Inc. Place: Santa Clara, California Zip: 95054 Product: Element Labs is a developer of LED video technology for...

  13. Rare-Earth Transition-Metal Intermetallics: Structure-bonding-Property Relationships

    SciTech Connect (OSTI)

    Mi-Kyung Han

    2006-05-01

    Our explorations of rare-earth, transition metal intermetallics have resulted in the synthesis and characterization, and electronic structure investigation, as well as understanding the structure-bonding-property relationships. Our work has presented the following results: (1) Understanding the relationship between compositions and properties in LaFe{sub 13-x}Si{sub x} system: A detailed structural and theoretical investigation provided the understanding of the role of a third element on stabilizing the structure and controlling the transformation of cubic NaZn{sub 13}-type structures to the tetragonal derivative, as well as the relationship between the structures and properties. (2) Synthesis of new ternary rare-earth iron silicides RE{sub 2-x}Fe{sub 4}Si{sub 14-y} and proposed superstructure: This compound offers complex structural challenges such as fractional occupancies and their ordering in superstructure. (3) Electronic structure calculation of FeSi{sub 2}: This shows that the metal-semiconductor phase transition depends on the structure. The mechanism of band gap opening is described in terms of bonding and structural distortion. This result shows that the electronic structure calculations are an essential tool for understanding the relationship between structure and chemical bonding in these compounds. (4) Synthesis of new ternary rare-earth Zinc aluminides Tb{sub 3}Zn{sub 3.6}Al{sub 7.4}: Partially ordered structure of Tb{sub 3}Zn{sub 3.6}Al{sub 7.4} compound provides new insights into the formation, composition and structure of rare-earth transition-metal intermetallics. Electronic structure calculations attribute the observed composition to optimizing metal-metal bonding in the electronegative (Zn, Al) framework, while the specific ordering is strongly influenced by specific orbital interactions. (5) Synthesis of new structure type of Zn{sub 39}(Cr{sub x}Al{sub 1-x}){sub 81}: These layered structures are similar to icosahedral Mn-Al quasicrystalline

  14. Rare-earth transition-metal intermetallics: Structure-bonding-property relationships

    SciTech Connect (OSTI)

    Han, M.K.

    2006-05-06

    The explorations of rare-earth, transition metal intermetallics have resulted in the synthesis and characterization, and electronic structure investigation, as well as understanding the structure-bonding property relationships. The work has presented the following results: (1) Understanding the relationship between compositions and properties in LaFe{sub 13-x}Si{sub x} system: A detailed structural and theoretical investigation provided the understanding of the role of a third element on stabilizing the structure and controlling the transformation of cubic NaZn{sub 13}-type structures to the tetragonal derivative, as well as the relationship between the structures and properties. (2) Synthesis of new ternary rare-earth iron silicides Re{sub 2-x}Fe{sub 4}Si{sub 14-y} and proposed superstructure: This compound offers complex structural challenges such as fractional occupancies and their ordering in superstructure. (3) Electronic structure calculation of FeSi{sub 2}: This shows that the metal-semiconductor phase transition depends on the structure. The mechanism of band gap opening is described in terms of bonding and structural distortion. This result shows that the electronic structure calculations are an essential tool for understanding the relationship between structure and chemical bonding in these compounds. (4) Synthesis of new ternary rare-earth Zinc aluminides Tb{sub 3}Zn{sub 3.6}Al{sub 7.4}: Partially ordered structure of Tb{sub 3}Zn{sub 3.6}Al{sub 7.4} compound provides new insights into the formation, composition and structure of rare-earth transition-metal intermetallics. Electronic structure calculations attribute the observed composition to optimizing metal-metal bonding in the electronegative (Zn, Al) framework, while the specific ordering is strongly influenced by specific orbital interactions. (5) Synthesis of new structure type of Zn{sub 39}(Cr{sub x}Al{sub 1-x}){sub 81}: These layered structures are similar to icosahedral Mn-Al quasicrystalline

  15. Quadrilateral finite element mesh coarsening

    DOE Patents [OSTI]

    Staten, Matthew L; Dewey, Mark W; Benzley, Steven E

    2012-10-16

    Techniques for coarsening a quadrilateral mesh are described. These techniques include identifying a coarsening region within the quadrilateral mesh to be coarsened. Quadrilateral elements along a path through the coarsening region are removed. Node pairs along opposite sides of the path are identified. The node pairs along the path are then merged to collapse the path.

  16. FOIL ELEMENT FOR NUCLEAR REACTOR

    DOE Patents [OSTI]

    Noland, R.A.; Walker, D.E.; Spinrad, B.I.

    1963-07-16

    A method of making a foil-type fuel element is described. A foil of fuel metal is perforated in; regular design and sheets of cladding metal are placed on both sides. The cladding metal sheets are then spot-welded to each other through the perforations, and the edges sealed. (AEC)

  17. Single element laser beam shaper

    DOE Patents [OSTI]

    Zhang, Shukui; Michelle D. Shinn

    2005-09-13

    A single lens laser beam shaper for converting laser beams from any spatial profile to a flat-top or uniform spatial profile. The laser beam shaper includes a lens having two aspheric surfaces. The beam shaper significantly simplifies the overall structure in comparison with conventional 2-element systems and therefore provides great ease in alignment and reduction of cost.

  18. Infrared trace element detection system

    DOE Patents [OSTI]

    Bien, F.; Bernstein, L.S.; Matthew, M.W.

    1988-11-15

    An infrared trace element detection system includes an optical cell into which the sample fluid to be examined is introduced and removed. Also introduced into the optical cell is a sample beam of infrared radiation in a first wavelength band which is significantly absorbed by the trace element and a second wavelength band which is not significantly absorbed by the trace element for passage through the optical cell through the sample fluid. The output intensities of the sample beam of radiation are selectively detected in the first and second wavelength bands. The intensities of a reference beam of the radiation are similarly detected in the first and second wavelength bands. The sensed output intensity of the sample beam in one of the first and second wavelength bands is normalized with respect to the other and similarly, the intensity of the reference beam of radiation in one of the first and second wavelength bands is normalized with respect to the other. The normalized sample beam intensity and normalized reference beam intensity are then compared to provide a signal from which the amount of trace element in the sample fluid can be determined. 11 figs.

  19. Fast acting multiple element valve

    DOE Patents [OSTI]

    Yang, Jefferson Y. S.; Wada, James M.

    1991-01-01

    A plurality of slide valve elements having plural axial-spaced annular parts and an internal slide are inserted into a bulkhead in a fluid conduit from a downstream side of the bulkhead, locked in place by a bayonet coupling and set screw, and project through the bulkhead into the upstream conduit. Pneumatic lines connecting the slide valve element actuator to pilot valves are brought out the throat of the valve element to the downstream side. Pilot valves are radially spaced around the exterior of the valve to permit the pneumatic lines to be made identical, thereby to minimize adverse timing tolerances in operation due to pressure variations. Ring manifolds surround the valve adjacent respective pilot valve arrangements to further reduce adverse timing tolerances due to pressure variations, the manifolds being directly connected to the respective pilot valves. Position sensors are provided the valve element slides to signal the precise time at which a slide reaches or passes through a particular point in its stroke to initiate a calibrated timing function.

  20. Superheavy Elements - Achievements and Challenges

    SciTech Connect (OSTI)

    Ackermann, Dieter

    2009-03-04

    The search for superheavy elements (SHE) has yielded exciting results for both the 'cold fusion' approach with reactions employing Pb and Bi targets and the ''hot fusion'' reactions with {sup 48}Ca beams on actinide targets. The most recent activities at GSI were the successful production of a more neutron rich isotope of element 112 in the reaction {sup 48}Ca+{sup 238}U confirming earlier result from FLNR, and the attempt to synthesize an isotope with Z 120 in the reaction {sup 64}Ni+{sup 238}U. Apart from the synthesis of new elements, advanced nuclear structure studies for heavy and super heavy elements promise a detailed insight in the properties of nuclear matter under the extreme conditions of high Z and A. The means are evaporation residue(ER)-{alpha}-{alpha} and -{alpha}-{gamma} coincidence techniques applied after separation of the reaction products from the beam. Recent examples of interesting physics to be discovered in this region of the chart of nuclides are the investigation of K-isomers observed for {sup 252,254}No and indicated for {sup 270}Ds. Fast chemistry and precision mass measurements deliver in addition valuable information on the fundamental properties of the SHE.

  1. Complex Electronic Structure of Rare Earth Activators in Scintillators

    SciTech Connect (OSTI)

    Aberg, D.; Yu, S. W.; Zhou, F.

    2015-10-27

    To aid and further the understanding of the microscopic mechanisms behind the scintillator nonproportionality that leads to degradation of the attainable energy resolution, we have developed theoretical and experimental algorithms and procedures to determine the position of the 4f energy levels of rare earth dopants relative to the host band edge states.

  2. Rare Isotope Beams for the 21st Century

    ScienceCinema (OSTI)

    James Symons

    2010-01-08

    In a scientific keynote address on Friday, June 12 at Michigan State University (MSU) in East Lansing, James Symons, Director of Berkeley Labs Nuclear Science Division (NSD), discussed the exciting research prospects of the new Facility for Rare Isotope Beams (FRIB) to be built at MSUs National Superconducting Cyclotron Laboratory.

  3. Method for locating defective nuclear fuel elements

    SciTech Connect (OSTI)

    Lawrie, W.E.; White, N.W.; Womack, R.E.

    1982-02-02

    Defects in nuclear fuel elements are ascertained and located within an assembled fuel assembly by ultrasonic means. In a typical embodiment of the invention, an ultrasonic search unit is positioned within the fuel assembly opposite the lower plenum of the fuel element to be tested. An ultrasonic pulse is radially projected into the element. Defective fuel elements are ascertained by ultrasonic reflection measurements.

  4. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-11-21

    A fuel element is designed which is particularly adapted for reactors of high power density used to generate steam for the production of electricity. The fuel element consists of inner and outer concentric tubes forming an annular chamber within which is contained fissionable fuel pellet segments, wedge members interposed between the fuel segments, and a spring which, acting with wedge members, urges said fuel pellets radially into contact against the inner surface of the outer tube. The wedge members may be a fertile material convertible into fissionable fuel material by absorbing neutrons emitted from the fissionable fuel pellet segments. The costly grinding of cylindrical fuel pellets to close tolerances for snug engagement is reduced because the need to finish the exact size is eliminated. (AEC)

  5. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C.; Besecker, Charles J.; Chen, Hancun; Robinson, Earil T.

    2007-06-12

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  6. The Origin of the Elements

    SciTech Connect (OSTI)

    Murphy, Edward

    2012-11-20

    The world around us is made of atoms. Did you ever wonder where these atoms came from? How was the gold in our jewelry, the carbon in our bodies, and the iron in our cars made? In this lecture, we will trace the origin of a gold atom from the Big Bang to the present day, and beyond. You will learn how the elements were forged in the nuclear furnaces inside stars, and how, when they die, these massive stars spread the elements into space. You will learn about the origin of the building blocks of matter in the Big Bang, and we will speculate on the future of the atoms around us today.

  7. The Origin of the Elements

    ScienceCinema (OSTI)

    Murphy, Edward

    2014-08-06

    The world around us is made of atoms. Did you ever wonder where these atoms came from? How was the gold in our jewelry, the carbon in our bodies, and the iron in our cars made? In this lecture, we will trace the origin of a gold atom from the Big Bang to the present day, and beyond. You will learn how the elements were forged in the nuclear furnaces inside stars, and how, when they die, these massive stars spread the elements into space. You will learn about the origin of the building blocks of matter in the Big Bang, and we will speculate on the future of the atoms around us today.

  8. Self supporting heat transfer element

    DOE Patents [OSTI]

    Story, Grosvenor Cook (Livermore, CA); Baldonado, Ray Orico (Livermore, CA)

    2002-01-01

    The present invention provides an improved internal heat exchange element arranged so as to traverse the inside diameter of a container vessel such that it makes good mechanical contact with the interior wall of that vessel. The mechanical element is fabricated from a material having a coefficient of thermal conductivity above about 0.8 W cm.sup.-1.degree. K.sup.-1 and is designed to function as a simple spring member when that member has been cooled to reduce its diameter to just below that of a cylindrical container or vessel into which it is placed and then allowed to warm to room temperature. A particularly important application of this invention is directed to a providing a simple compartmented storage container for accommodating a hydrogen absorbing alloy.

  9. Element of an inductive coupler

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe

    2006-08-15

    An element for an inductive coupler in a downhole component comprises magnetically conductive material, which is disposed in a recess in annular housing. The magnetically conductive material forms a generally circular trough. The circular trough comprises an outer generally U-shaped surface, an inner generally U-shaped surface, and two generally planar surfaces joining the inner and outer surfaces. The element further comprises pressure relief grooves in at least one of the surfaces of the circular trough. The pressure relief grooves may be scored lines. Preferably the pressure relief grooves are parallel to the magnetic field generated by the magnetically conductive material. The magnetically conductive material is selected from the group consisting of soft iron, ferrite, a nickel iron alloy, a silicon iron alloy, a cobalt iron alloy, and a mu-metal. Preferably, the annular housing is a metal ring.

  10. Derivation of an optical potential for statically deformed rare-earth nuclei from a global spherical potential

    SciTech Connect (OSTI)

    Nobre, G. P. A.; Palumbo, A.; Herman, M.; Brown, D.; Hoblit, S.; Dietrich, F. S.

    2015-02-25

    The coupled-channel theory is a natural way of treating nonelastic channels, in particular those arising from collective excitations characterized by nuclear deformations. A proper treatment of such excitations is often essential to the accurate description of experimental nuclear-reaction data and to the prediction of a wide variety of scattering observables. Stimulated by recent work substantiating the near validity of the adiabatic approximation in coupled-channel calculations for scattering on statically deformed nuclei, we explore the possibility of generalizing a global spherical optical model potential (OMP) to make it usable in coupled-channel calculations on this class of nuclei. To do this, we have deformed the Koning-Delaroche global spherical potential for neutrons, coupling a sufficient number of states of the ground state band to ensure convergence. We present an extensive study of the effects of collective couplings and nuclear deformations on integrated cross sections as well as on angular distributions for neutron-induced reactions on statically deformed nuclei in the rare-earth region. We choose isotopes of three rare-earth elements (Gd, Ho, W), which are known to be nearly perfect rotors, to exemplify the results of the proposed method. Predictions from our model for total, elastic and inelastic cross sections, as well as for elastic and inelastic angular distributions, are in reasonable agreement with measured experimental data. In conclusion, these results suggest that the deformed Koning-Delaroche potential provides a useful regional neutron optical potential for the statically deformed rare earth nuclei.

  11. Photoconductive circuit element pulse generator

    DOE Patents [OSTI]

    Rauscher, Christen

    1989-01-01

    A pulse generator for characterizing semiconductor devices at millimeter wavelength frequencies where a photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test.

  12. 2.10 Heavy Element Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 6/1/2011 2.10 Heavy Element Chemistry For more than 50 years, the Office of Science and predecessor agencies have supported the discovery and study of the actinide elements, in particular the transuranium elements-atoms that are heavier than uranium. Glenn Seaborg and Ed McMillan of the Lawrence Berkeley National Laboratory, 1951 Nobel Laureates in Chemistry for the discovery of plutonium and other actinide elements, began this quest. Today, the Heavy Element Chemistry program continues the

  13. CATIONIC EXCHANGE PROCESS FOR THE SEPARATION OF RARE EARTHS

    DOE Patents [OSTI]

    Choppin, G.R.; Thompson, S.G.; Harvey, B.G.

    1960-02-16

    A process for separating mixtures of elements in the lanthanum and actinium series of the periodic table is described. The mixture of elements is dissolved in 0.05 M HCI, wherein the elements exist as tripositive ions. The resulting solution is then transferred to a column of cationic exchange resin and the column eluted with 0.1 to 0.6 M aqueous ammonium alpha hydroxy isobutyrate solution of pH 3.8 to 5.0. The use of ammonium alpha hydroxy isobutyrate as an eluting agent results in sharper and more rapid separations than previously obtainable with eluants such as citric, tartaric, glycolic, and lactic acids.

  14. Peridynamic Multiscale Finite Element Methods

    SciTech Connect (OSTI)

    Costa, Timothy; Bond, Stephen D.; Littlewood, David John; Moore, Stan Gerald

    2015-12-01

    The problem of computing quantum-accurate design-scale solutions to mechanics problems is rich with applications and serves as the background to modern multiscale science research. The prob- lem can be broken into component problems comprised of communicating across adjacent scales, which when strung together create a pipeline for information to travel from quantum scales to design scales. Traditionally, this involves connections between a) quantum electronic structure calculations and molecular dynamics and between b) molecular dynamics and local partial differ- ential equation models at the design scale. The second step, b), is particularly challenging since the appropriate scales of molecular dynamic and local partial differential equation models do not overlap. The peridynamic model for continuum mechanics provides an advantage in this endeavor, as the basic equations of peridynamics are valid at a wide range of scales limiting from the classical partial differential equation models valid at the design scale to the scale of molecular dynamics. In this work we focus on the development of multiscale finite element methods for the peridynamic model, in an effort to create a mathematically consistent channel for microscale information to travel from the upper limits of the molecular dynamics scale to the design scale. In particular, we first develop a Nonlocal Multiscale Finite Element Method which solves the peridynamic model at multiple scales to include microscale information at the coarse-scale. We then consider a method that solves a fine-scale peridynamic model to build element-support basis functions for a coarse- scale local partial differential equation model, called the Mixed Locality Multiscale Finite Element Method. Given decades of research and development into finite element codes for the local partial differential equation models of continuum mechanics there is a strong desire to couple local and nonlocal models to leverage the speed and state of the

  15. Method of monitoring stored nuclear fuel elements

    SciTech Connect (OSTI)

    Borloo, E.; Buergers, W.; Crutzen, S.; Vinche, C.

    1983-05-24

    To monitor a nuclear fuel element or fuel elements located in a store, e.g. a pond in a swimming pool reactor, the store is illuminated ultrasonically using one or more transducers transmitting ultrasonic signals in one or more predetermined directions to obtain an output which, because it depends on the number and relative location of the fuel elements in the store, and the structure of the store itself is distinctive to the fuel elements or elements stored therein. From this distinctive output is derived an identity unique to the stored fuel element or elements and a reference signal indicative of the whole structure when intact, the reference signal and identity being recorded. Subsequent ultrasonic testing of the store and its contents under identical operating conditions produces a signal which is compared to the recorded reference signal and if different therefrom reveals the occurrence of tampering with the store and/or the fuel element or elements.

  16. Process for separation of the rare earths by solvent extraction

    DOE Patents [OSTI]

    Mason, George W.; Lewey, Sonia

    1977-04-05

    Production rates for solvent extraction separation of the rare earths and yttrium from each other can be improved by the substitution of di(2-ethylhexyl) mono-thiophosphoric acid for di(2-ethylhexyl) phosphoric acid. The di(2-ethylhexyl) mono-thiophosphoric acid does not form an insoluble polymer at approximately 50% saturation as does the former extractant, permitting higher feed solution concentration and thus greater throughput.

  17. Detecting rare, abnormally large grains by x-ray diffraction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detecting rare, abnormally large grains by x-ray diffraction - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense

  18. Non-Rare Earth magnetic materials | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation pm035_mcguire_2011_o.pdf (397.61 KB) More Documents & Publications Non-Rare Earth magnetic materials (Agreement ID:19201) Vehicle Technologies Office: 2011 Propulsion Materials R&D Annual Progress Report Vehicle Technologies Office Merit Review 2014: Applied ICME for New Propulsion Materials (Agreement ID:26391) Project ID:18865

  19. CMI Offers Webinars on Critical Materials and Rare Earths | Critical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Institute Offers Webinars on Critical Materials and Rare Earths CMI at Mines offers webinars about critical materials at no charge. Registration is required to obtain a link to the webinar. September 21: Parans Paranthaman, Oak Ridge National Laboratory, "Additive Manufacturing of NdFeB Magnets" Registration is open August 23: CMI Director Alex King, "CMI Director's Perspective." A recording of the webinar is available. July 20: Corby Anderson, Colorado School

  20. Public to have rare opportunity to tour Neutron Science Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rosenfest: celebrate Louis Rosen, tour LANSCE Public to have rare opportunity to tour Neutron Science Center Tour attendees can expect to see many facets of the LANSCE, including areas along the linear accelerator beam line, the control room area, and one or more experimental areas. May 10, 2011 Aerial View of Neutron Science Center Aerial View of Neutron Science Center Contact James Rickman Communications Office (505) 665-9203 Email LANL Rosenfest will celebrate life of LANSCE founder Louis

  1. Physics and Outlook for Rare, All-neutral Eta Decays

    SciTech Connect (OSTI)

    Mack, David J.

    2014-06-01

    The $\\eta$ meson provides a laboratory to study isospin violation and search for new flavor-conserving sources of C and CP violation with a sensitivity approaching $10^{-6}$ of the isospin-conserving strong amplitude. Some of the most interesting rare $\\eta$ decays are the neutral modes, yet the effective loss of photons from the relatively common decay $\\eta \\rightarrow 3\\pi^0 \\rightarrow 6\\gamma$ (33$\\%$) has largely limited the sensitivity for decays producing 3-5$\\gamma$'s. Particularly important relevant branches include the highly suppressed $\\eta \\rightarrow \\pi^0 2\\gamma \\rightarrow 4\\gamma$, which provides a rare window on testing models of $O(p^6)$ contributions in ChPTh, and $\\eta \\rightarrow 3\\gamma$ and $\\eta \\rightarrow 2\\pi^0 \\gamma \\rightarrow 5\\gamma$ which provide direct constraints on C violation in flavor-conserving processes. The substitution of lead tungstate in the forward calorimeter of the GluEx setup in Jefferson Lab's new Hall D would allow dramatically improved measurements. The main niche of this facility, which we call the JLab Eta Factory (JEF), would be $\\eta$ decay neutral modes. However, this could likely be expanded to rare $\\eta'(958)$ decays for low energy QCD studies as well as $\\eta$ decays involving muons for new physics searches.

  2. Monitoring arrangement for vented nuclear fuel elements

    DOE Patents [OSTI]

    Campana, Robert J.

    1981-01-01

    In a nuclear fuel reactor core, fuel elements are arranged in a closely packed hexagonal configuration, each fuel element having diametrically opposed vents permitting 180.degree. rotation of the fuel elements to counteract bowing. A grid plate engages the fuel elements and forms passages for communicating sets of three, four or six individual vents with respective monitor lines in order to communicate vented radioactive gases from the fuel elements to suitable monitor means in a manner readily permitting detection of leakage in individual fuel elements.

  3. METHOD OF MAKING FUEL ELEMENTS

    DOE Patents [OSTI]

    Bean, C.H.; Macherey, R.E.

    1959-12-01

    A method is described for fabricating fuel elements, particularly for enclosing a plate of metal with a second metal by inserting the plate into an aperture of a frame of a second plate, placing a sheet of the second metal on each of opposite faces of the assembled plate and frame, purging with an inert gas the air from the space within the frame and the sheets while sealing the seams between the frame and the sheets, exhausting the space, purging the space with air, re-exhausting the spaces, sealing the second aperture, and applying heat and pressure to bond the sheets, the plate, and the frame to one another.

  4. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-05-01

    A nuclear reactor fuel element comprising high density ceramic fissionable material enclosed in a tubular cladding of corrosion-resistant material is described. The fissionable material is in the form of segments of a tube which have cooperating tapered interfaces which produce outward radial displacement when the segments are urged axially together. A resilient means is provided within the tubular housing to constantly urge the fuel segments axially. This design maintains the fuel material in tight contacting engagement against the inner surface of the outer cladding tube to eliminate any gap therebetween which may be caused by differential thermal expansion between the fuel material and the material of the tube.

  5. Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on Rare-Earth Research | Department of Energy Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement on Rare-Earth Research Critical Materials and Rare Futures: Ames Laboratory Signs a New Agreement on Rare-Earth Research June 15, 2011 - 7:07pm Addthis The plasma torch in the Retech plasma furnace is one tool used in Materials Preparation Center to create ultra-high purity metal alloy samples, particularly rare-earth metals, located at the Ames Lab. | Photo Courtesy of

  6. A family of rare earth molybdenum bronzes: Oxides consisting of periodic arrays of interacting magnetic units

    SciTech Connect (OSTI)

    Schneemeyer, L.F.; Siegrist, T.; Besara, T.; Lundberg, M.; Sun, J.; Singh, D.J.

    2015-07-15

    The family of rare earth molybdenum bronzes, reduced ternary molybdates of composition LnMo{sub 16}O{sub 44,} was synthesized and a detailed structural study carried out. Bond valence sum (BVS) calculations clearly show that the molybdenum ions in tetrahedral coordination are hexavalent while the electron count in the primitive unit cell is odd. Yet, measurements show that the phases are semiconductors. The temperature dependence of the magnetic susceptibility of samples containing several different rare earth elements was measured. These measurements verified the presence of a 6.5 K magnetic phase transition not arising from the rare earth constituent, but likely associated with the unique isolated ReO{sub 3}-type Mo{sub 8}O{sub 36} structural subunits in this phase. To better understand the behavior of these materials, electronic structure calculations were performed within density functional theory. Results suggest a magnetic state in which these structural moieties have an internal ferromagnetic arrangement, with small ~1/8 μ{sub B} moments on each Mo. We suggest that the Mo{sub 8}O{sub 36} units behave like pseudoatoms with spin 1/2 derived from a single hole distributed over the eight Mo atoms that are strongly hybridized with the O atoms of the subunit. Interestingly, while the compound is antiferromagnetic, our calculations suggest that a field-stabilized ferromagnetic state, if achievable, will be a narrow band half-metal. - Graphical abstract: LnMo{sub 16}O{sub 44} phases comprise corner sharing tetrahedral and octahedral molybdenum ions. The MoO{sub 6} octahedra form Mo{sub 8}O{sub 36} units that are well separated and act like pseudo-atoms, accommodating 11 electrons each. - Highlights: • Single crystal X-ray diffraction refinements of LnMo{sub 16}O{sub 44} single crystals for Ln=Ce, Pr, Nd, Tb, Dy and Ho. • DFT calculations based on LaMo{sub 16}O{sub 44}. • [Mo{sub 8}O{sub 36}] units behaving as superatoms with a net magnetic moment of 1 µ

  7. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-07-11

    Nuclear reactor fuel elements of the type in which the flssionsble material is in ceramic form, such as uranium dioxide, are described. The fuel element is comprised of elongated inner and outer concentric spaced tubular members providing an annular space therebetween for receiving the fissionable material, the annular space being closed at both ends and the inner tube being open at both ends. The fuel is in the form of compressed pellets of ceramic fissionsble material having the configuration of split bushings formed with wedge surfaces and arranged in seriated inner and outer concentric groups which are urged against the respective tubes in response to relative axial movement of the pellets in the direction toward each other. The pairs of pellets are axially urged together by a resilient means also enclosed within the annulus. This arrangement-permits relative axial displacement of the pellets during use dial stresses on the inner and outer tube members and yet maintains the fuel pellets in good thermal conductive relationship therewith.

  8. Fuel elements of thermionic converters

    SciTech Connect (OSTI)

    Hunter, R.L.; Gontar, A.S.; Nelidov, M.V.; Nikolaev, Yu.V.; Schulepov, L.N.

    1997-01-01

    Work on thermionic nuclear power systems has been performed in Russia within the framework of the TOPAZ reactor program since the early 1960s. In the TOPAZ in-core thermionic convertor reactor design, the fuel element`s cladding is also the thermionic convertor`s emitter. Deformation of the emitter can lead to short-circuiting and is the primary cause of premature TRC failure. Such deformation can be the result of fuel swelling, thermocycling, or increased unilateral pressure on the emitter due to the release of gaseous fission products. Much of the work on TRCs has concentrated on preventing or mitigating emitter deformation by improving the following materials and structures: nuclear fuel; emitter materials; electrical insulators; moderator and reflector materials; and gas-exhaust device. In addition, considerable effort has been directed toward the development of experimental techniques that accurately mimic operational conditions and toward the creation of analytical and numerical models that allow operational conditions and behavior to be predicted without the expense and time demands of in-pile tests. New and modified materials and structures for the cores of thermionic NPSs and new fabrication processes for the materials have ensured the possibility of creating thermionic NPSs for a wide range of powers, from tens to several hundreds of kilowatts, with life spans of 5 to 10 years.

  9. Elements of doing work at SSRL (rev

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Elements of a Federal Privacy Program Elements of a Federal Privacy Program The seven elements described in this document provide the basis for a robust federal privacy program, and will assist federal organizations to implement and sustain privacy awareness and stewardship. Elements of a Federal Privacy Program v1.0_June2010 Final.pdf (569.77 KB) More Documents & Publications PIA - GovTrip (DOE data) PIA - INL PeopleSoft - Human Resource System Energy Employees' Occupational Illness

  10. Element One, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Element One, Inc. America's Next Top Energy Innovator Challenge 191524 likes Element One, Inc. National Renewable Energy Laboratory Element One's detection products will change the paradigm in the way hydrogen and other hazardous gas leaks are detected, achieving a new level of safety in existing industrial and emerging consumer environments. Element One has patented the only available coatings for the detection of hydrogen that change color reversibly or non-reversibly as desired to give both

  11. Stacked Switchable Element and Diode Combination

    DOE Patents [OSTI]

    Branz, H. M.; Wang, Q.

    2006-06-27

    A device (10) comprises a semiconductor diode (12) and a switchable element (14) positioned in stacked adjacent relationship so that the semiconductor diode (12) and the switchable element (14) are electrically connected in series with one another. The switchable element (14) is switchable from a low-conductance state to a high-conductance state in response to the application of a forming voltage to the switchable element (14).

  12. Stacked switchable element and diode combination

    DOE Patents [OSTI]

    Branz, Howard M.; Wang, Qi

    2006-06-27

    A device (10) comprises a semiconductor diode (12) and a switchable element (14) positioned in stacked adjacent relationship so that the semiconductor diode (12) and the switchable element (14) are electrically connected in series with one another. The switchable element (14) is switchable from a low-conductance state to a high-conductance state in response to the application of a forming voltage to the switchable element (14).

  13. Identification of Human Repetitive DNA Elements

    Energy Science and Technology Software Center (OSTI)

    1995-11-01

    PYTHIA identifies the subfamily membership of Alu sequences, occurrences of repetitive human DNA elements, and simple DNA sequences.

  14. Rare-earth tantalates and niobates suitable for use as nanophosphors

    DOE Patents [OSTI]

    Nyman, May D; Rohwer, Lauren E.S& gt

    2013-11-19

    A family of rare-earth Group 5 oxides, where the Group 5 oxide is a niobate or tantalate. The rare-earth Group 5 oxides can be doped with suitable emitter ions to form nanophosphors.

  15. GROUND-STATE PROPERTIES OF RARE-EARTH METALS: AN EVALUATION OF...

    Office of Scientific and Technical Information (OSTI)

    GROUND-STATE PROPERTIES OF RARE-EARTH METALS: AN EVALUATION OF DENSITY-FUNCTIONAL THEORY Citation Details In-Document Search Title: GROUND-STATE PROPERTIES OF RARE-EARTH METALS: AN ...

  16. Alternative High-Performance Motors with Non-Rare Earth Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Performance Motors with Non-Rare Earth Materials Alternative High-Performance Motors with Non-Rare Earth Materials 2012 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  17. Rare {Lambda}{sub b} decays in a quark model

    SciTech Connect (OSTI)

    Mott, L.; Roberts, W.

    2010-08-05

    Hadronic form factors for the rare weak transitions {Lambda}{sub b{yields}{Lambda}}{sup (*)} are calculated using a nonrelativistic quark model. The form factors obtained in this way are found to satisfy the relationships expecetd from the heavy quark effective theory. Differential decay rates and branching ratios are calculated for the dileptonic decays {Lambda}{sub b{yields}{Lambda}}{sup (*)}l{sup +}l{sup -}, for both ground state and excited daughter baryons. Inclusion of the long distance contributions from charmonium resonances significantly enhances the decay rates. Future work is outlined.

  18. Resonance electronic Raman scattering in rare earth crystals

    SciTech Connect (OSTI)

    Williams, G.M.

    1988-11-10

    The intensities of Raman scattering transitions between electronic energy levels of trivalent rare earth ions doped into transparent crystals were measured and compared to theory. A particle emphasis was placed on the examination of the effect of intermediate state resonances on the Raman scattering intensities. Two specific systems were studied: Ce/sup 3 +/(4f/sup 1/) in single crystals of LuPO/sub 4/ and Er/sup 3 +/(4f/sup 11/) in single crystals of ErPO/sub 4/. 134 refs., 92 figs., 33 tabs.

  19. Rare Decays And Exotic States With BaBar

    SciTech Connect (OSTI)

    Robertson, S.H.; /McGill U.

    2006-08-28

    Results from the BABAR experiment are presented for searches for several rare FCNC B and D meson decays, including the modes B{sup 0} {yields} {ell}{sup +}{ell}{sup -} and D{sup 0} {yields} {ell}{sup +}{ell}{sup -}, B {yields} ({rho},{omega}){gamma} and B{sup +} {yields} (K,{pi}){sup +}{nu}{bar {nu}}. Limits on lepton flavor violation in neutrino-less {tau} decays are also discussed. Finally, results of BABAR searches for the strange pentaquark states {Theta}{sup +}(1540), {Xi}{sup --}(1860) and {Xi}{sup 0}(1860) are summarized.

  20. Multicanonical sampling of rare events in random matrices

    SciTech Connect (OSTI)

    Saito, Nen; Iba, Yukito; Hukushima, Koji

    2010-09-15

    A method based on multicanonical Monte Carlo is applied to the calculation of large deviations in the largest eigenvalue of random matrices. The method is successfully tested with the Gaussian orthogonal ensemble, sparse random matrices, and matrices whose components are subject to uniform density. Specifically, the probability that all eigenvalues of a matrix are negative is estimated in these cases down to the values of {approx}10{sup -200}, a region where simple random sampling is ineffective. The method can be applied to any ensemble of matrices and used for sampling rare events characterized by any statistics.

  1. Population and community ecology of the rare plant amsinckia grandiflora

    SciTech Connect (OSTI)

    Carlsen, T.M.

    1996-11-01

    Research was conducted between the fall of 1992 and the spring on the population and community ecology of the rare annual plant, Amsinckia glandiflora (Gray) Kleeb. ex Greene (Boraginaceae). The research goal was to investigate the causes of the species rarity, data useful to restorative efforts. The work focused on the examination of competitive suppression by exotic annual grasses; comparisons with common, weedy congener; and the role of litter cover and seed germination and seedling establishment. Annual exotic grasses reduced A. grandiflora reproductive output to a greater extent than did the native perennial bunch grass.

  2. Data transmission element for downhole drilling components

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Dahlgren, Scott; Fox, Joe; Sneddon, Cameron; Briscoe, Michael

    2006-01-31

    A robust data transmission element for transmitting information between downhole components, such as sections of drill pipe, in the presence of hostile environmental conditions, such as heat, dirt, rocks, mud, fluids, lubricants, and the like. The data transmission element components include a generally U-shaped annular housing, a generally U-shaped magnetically conductive, electrically insulating element such as ferrite, and an insulated conductor. Features on the magnetically conducting, electrically insulating element and the annular housing create a pocket when assembled. The data transmission element is filled with a polymer to retain the components within the annular housing by filling the pocket with the polymer. The polymer can bond with the annular housing and the insulated conductor but preferably not the magnetically conductive, electrically insulating element. A data transmission element is mounted within a recess proximate a mating surface of a downhole drilling component, such as a section of drill pipe.

  3. Ab Initio Nuclear Structure and Reaction Calculations for Rare Isotopes

    SciTech Connect (OSTI)

    Draayer, Jerry P.

    2014-09-28

    We have developed a novel ab initio symmetry-adapted no-core shell model (SA-NCSM), which has opened the intermediate-mass region for ab initio investigations, thereby providing an opportunity for first-principle symmetry-guided applications to nuclear structure and reactions for nuclear isotopes from the lightest p-shell systems to intermediate-mass nuclei. This includes short-lived proton-rich nuclei on the path of X-ray burst nucleosynthesis and rare neutron-rich isotopes to be produced by the Facility for Rare Isotope Beams (FRIB). We have provided ab initio descriptions of high accuracy for low-lying (including collectivity-driven) states of isotopes of Li, He, Be, C, O, Ne, Mg, Al, and Si, and studied related strong- and weak-interaction driven reactions that are important, in astrophysics, for further understanding stellar evolution, X-ray bursts and triggering of s, p, and rp processes, and in applied physics, for electron and neutrino-nucleus scattering experiments as well as for fusion ignition at the National Ignition Facility (NIF).

  4. Sublattice Magnetic Relaxation in Rare Earth Iron Garnets

    SciTech Connect (OSTI)

    McCloy, John S.; Walsh, Brian

    2013-07-08

    The magnetic properties of rare earth garnets make them attractive materials for applications ranging from optical communications to magnetic refrigeration. The purpose of this research was to determine the AC magnetic properties of several rare earth garnets, in order to ascertain the contributions of various sublattices. Gd3Fe5O¬12, Gd3Ga5O12, Tb3Fe5O12, Tb3Ga5O12, and Y3Fe5O12 were synthesized by a solid state reaction of their oxides and verified by x-ray diffraction. Frequency-dependent AC susceptibility and DC magnetization were measured versus temperature (10 – 340 K). Field cooling had little effect on AC susceptibility, but large effect on DC magnetization, increasing magnetization at the lowest temperature and shifting the compensation point to lower temperatures. Data suggest that interaction of the two iron lattices results in the two frequency dependent magnetic relaxations in the iron garnets, which were fit using the Vogel-Fulcher and Arrhenius laws.

  5. Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making

    DOE Patents [OSTI]

    McCallum, R. William; Branagan, Daniel J.

    1996-01-23

    A method of making a permanent magnet wherein 1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and 2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties.

  6. Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making

    DOE Patents [OSTI]

    McCallum, R.W.; Branagan, D.J.

    1996-01-23

    A method of making a permanent magnet is disclosed wherein (1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and (2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties. 33 figs.

  7. Derivation of an optical potential for statically deformed rare-earth nuclei from a global spherical potential

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nobre, G. P. A.; Palumbo, A.; Herman, M.; Brown, D.; Hoblit, S.; Dietrich, F. S.

    2015-02-25

    The coupled-channel theory is a natural way of treating nonelastic channels, in particular those arising from collective excitations characterized by nuclear deformations. A proper treatment of such excitations is often essential to the accurate description of experimental nuclear-reaction data and to the prediction of a wide variety of scattering observables. Stimulated by recent work substantiating the near validity of the adiabatic approximation in coupled-channel calculations for scattering on statically deformed nuclei, we explore the possibility of generalizing a global spherical optical model potential (OMP) to make it usable in coupled-channel calculations on this class of nuclei. To do this, wemore » have deformed the Koning-Delaroche global spherical potential for neutrons, coupling a sufficient number of states of the ground state band to ensure convergence. We present an extensive study of the effects of collective couplings and nuclear deformations on integrated cross sections as well as on angular distributions for neutron-induced reactions on statically deformed nuclei in the rare-earth region. We choose isotopes of three rare-earth elements (Gd, Ho, W), which are known to be nearly perfect rotors, to exemplify the results of the proposed method. Predictions from our model for total, elastic and inelastic cross sections, as well as for elastic and inelastic angular distributions, are in reasonable agreement with measured experimental data. In conclusion, these results suggest that the deformed Koning-Delaroche potential provides a useful regional neutron optical potential for the statically deformed rare earth nuclei.« less

  8. Effect of temperature and rare-earth doping on charge-carrier mobility in indium-monoselenide crystals

    SciTech Connect (OSTI)

    Abdinov, A. Sh.; Babayeva, R. F.; Amirova, S. I.; Rzayev, R. M.

    2013-08-15

    In the temperature range T = 77-600 K, the dependence of the charge-carrier mobility ({mu}) on the initial dark resistivity is experimentally investigated at 77 K ({rho}d{sub 0}), as well as on the temperature and the level (N) of rare-earth doping with such elements as gadolinium (Gd), holmium (Ho), and dysprosium (Dy) in n-type indium-monoselenide (InSe) crystals. It is established that the anomalous behavior of the dependences {mu}(T), {mu}({rho}d{sub 0}), and {mu}(N) found from the viewpoint of the theory of charge-carrier mobility in crystalline semiconductors is related, first of all, to partial disorder in indium-monoselenide crystals and can be attributed to the presence of random drift barriers in the free energy bands.

  9. Theoretical studies of strongly correlated rare-earth intermetallics RIn₃ and RSn₃ (R=Sm, Eu, and Gd)

    SciTech Connect (OSTI)

    Shafiq, M.; Ahmad, Iftikhar E-mail: dr.iftikhar@uom.edu.pk; Jalali Asadabadi, S.

    2014-09-14

    In this paper, the structural, elastic, and electronic properties of RIn₃ and RSn₃ (R = Sm, Eu, Gd) compounds have been investigated using the full potential linearized augmented plane wave plus local orbital method within the density functional theory. The structural properties are investigated using the LDA, GGA, and the band correlated LDA+U and GGA+U schemes. The lattice parameters are in good agreement with the available experimental results and the divalent state of Eu is also verified. The spin-orbit coupling is included in order to predict the correct electronic properties and splitting of 4f states of the rare earth elements is also incorporated. We calculated Bulk modulus, shear modulus, Young's modulus, anisotropic ratio, Kleinman parameters, Poisson's ratio, Lame's co-efficient, sound velocities for shear and longitudinal waves, and Debye temperature. We also predict the Cauchy pressure and B/G ratio in order to explore the ductile and brittle behaviors of these compounds.

  10. Iron-Nickel-Based SuperMagnets: Multiscale Development of L10 Materials for Rare Earth-Free Permanent Magnets

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: Northeastern University will develop bulk quantities of rare-earth-free permanent magnets with an iron-nickel crystal structure for use in the electric motors of renewable power generators and EVs. These materials could offer magnetic properties that are equivalent to today’s best commercial magnets, but with a significant cost reduction and diminished environmental impact. This iron-nickel crystal structure, which is only found naturally in meteorites and developed over billions of years in space, will be artificially synthesized by the Northeastern University team. Its material structure will be replicated with the assistance of alloying elements introduced to help it achieve superior magnetic properties. The ultimate goal of this project is to demonstrate bulk magnetic properties that can be fabricated at the industrial scale.

  11. Rack for storing spent nuclear fuel elements

    DOE Patents [OSTI]

    Rubinstein, Herbert J.; Clark, Philip M.; Gilcrest, James D.

    1978-06-20

    A rack for storing spent nuclear fuel elements in which a plurality of aligned rows of upright enclosures of generally square cross-sectional areas contain vertically disposed fuel elements. The enclosures are fixed at the lower ends thereof to a base. Pockets are formed between confronting walls of adjacent enclosures for receiving high absorption neutron absorbers, such as Boral, cadmium, borated stainless steel and the like for the closer spacing of spent fuel elements.

  12. A proposed generic authentication information element

    SciTech Connect (OSTI)

    Tarman, T.D.

    1995-08-01

    This contribution describes a proposed information element that can convey authentication information within an ATM signaling message. The design of this information element provides a large amount of flexibility to the user because it does not specify a particular signature algorithm, and it does not specify which information elements must accompany the Authentication IE in a signaling message. This allows the user to implement authenticated signaling based on her site`s security policies and performance requirements.

  13. Refining quadrilateral and brick element meshes

    SciTech Connect (OSTI)

    Schneiders, R.; Debye, J.

    1995-12-31

    We consider the problem of refining unstructured quadrilateral and brick element meshes. We present an algorithm which is a generalization of an algorithm developed by Cheng et. al. for structured quadrilateral element meshes. The problem is solved for the two-dimensional case. Concerning three dimensions we present a solution for some special cases and a general solution that introduces tetrahedral and pyramidal transition elements.

  14. Widget:HoverMultipleElements | Open Energy Information

    Open Energy Info (EERE)

    of the element with hovered state to be applied without being hovered targetclass - css class to apply to target element when trigger element is hovered Example...

  15. Flerovium, Livermorium proposed names for elements 114,116 |...

    National Nuclear Security Administration (NNSA)

    Laboratory of Nuclear Reactions, participated in the work carried out in Dubna on the synthesis of superheavy elements, including element 116. (Lawrencium -- Element 103 -- was...

  16. Gaps and pseudogaps in perovskite rare earth nickelates

    SciTech Connect (OSTI)

    Allen, S. James; Ouellette, Daniel G.; Kally, James; Kozhanov, Alex; Hauser, Adam J.; Mikheev, Evgeny; Zhang, Jack Y.; Moreno, Nelson E.; Son, Junwoo; Stemmer, Susanne; Balents, Leon

    2015-06-01

    We report on tunneling measurements that reveal the evolution of the quasiparticle state density in two rare earth perovskite nickelates, NdNiO{sub 3} and LaNiO{sub 3}, that are close to a bandwidth controlled metal to insulator transition. We measure the opening of a sharp gap of ∼30 meV in NdNiO{sub 3} in its insulating ground state. LaNiO{sub 3}, which remains a correlated metal at all practical temperatures, exhibits a pseudogap of the same order. The results point to both types of gaps arising from a common origin, namely, a quantum critical point associated with the T = 0 K metal-insulator transition. The results support theoretical models of the quantum phase transition in terms of spin and charge instabilities of an itinerant Fermi surface.

  17. Detecting Rare Events in the Time-Domain

    SciTech Connect (OSTI)

    Rest, A; Garg, A

    2008-10-31

    One of the biggest challenges in current and future time-domain surveys is to extract the objects of interest from the immense data stream. There are two aspects to achieving this goal: detecting variable sources and classifying them. Difference imaging provides an elegant technique for identifying new transients or changes in source brightness. Much progress has been made in recent years toward refining the process. We discuss a selection of pitfalls that can afflict an automated difference imagine pipeline and describe some solutions. After identifying true astrophysical variables, we are faced with the challenge of classifying them. For rare events, such as supernovae and microlensing, this challenge is magnified because we must balance having selection criteria that select for the largest number of objects of interest against a high contamination rate. We discuss considerations and techniques for developing classification schemes.

  18. Heavy-ion excitation of rare-gas excimers

    SciTech Connect (OSTI)

    Ulrich, A.; Koerner, H.J.; Kroetz, W.; Ribitzki, G.; Murnick, D.E.; Matthias, E.; Kienle, P.; Hoffmann, D.H.H.

    1987-07-15

    Beams of high-energy heavy ions (Ar and U) from the UNILAC accelerator have been used to excite rare gases at pressures near 1 bar. The dominant spectroscopic feature observed in Ar, Kr, and Xe gases was molecular excimer emission at the second excimer continuum at 130, 150, and 170 nm, respectively. The excimer radiation was studied as a function of time (with respect to the excitation pulse), ion-beam current, pressure, and excitation density. The efficiency of excimer production from heavy-ion-beam energy was found to be several percent. Details of spectral shape, especially the ratio of first-to-second continuum emission, were found to depend on pressure and exciting beam type.

  19. Cryogenic distribution for the Facility for Rare Isotope Beams

    SciTech Connect (OSTI)

    S. Jones, Dana Arenius, Adam Fila, P. Geutschow, Helmut Laumer, Matt Johnson, Cory S. Waltz, J. G. Weisend II

    2012-06-01

    The Facility for Rare Isotope Beams (FRIB) is a new National User Facility for nuclear science funded by the Department of Energy Office of Science and operated by Michigan State University. The FRIB accelerator linac consists of superconducting radio-frequency (SCRF) cavities operating at 2 K and SC magnets operating at 4.5 K all cooled by a large scale cryogenic refrigeration system. A major subsystem of the cryogenic system will be the distribution system whose primary components will include a distribution box, the transfer lines and the interconnect valve boxes at each cryogenic device. An overview of the conceptual design of the distribution system including engineering details, capabilities and schedule is described.

  20. Method of lightening radiation darkened optical elements

    DOE Patents [OSTI]

    Reich, Frederich R.; Schwankoff, Albert R.

    1980-01-01

    A method of lightening a radiation-darkened optical element in wich visible optical energy or electromagnetic radiation having a wavelength in the range of from about 2000 to about 20,000 angstroms is directed into the radiation-darkened optical element; the method may be used to lighten radiation-darkened optical element in-situ during the use of the optical element to transmit data by electronically separating the optical energy from the optical output by frequency filtering, data cooling, or interlacing the optic energy between data intervals.

  1. Trace Element Analysis | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Trace Element Analysis At Central Nevada Seismic Zone Region...

  2. Elemental Energy LLC | Open Energy Information

    Open Energy Info (EERE)

    Sector: Solar Product: Elemental Energy develops, owns and operates distributed solar energy facilities and sells solar-generated electricity through Power Purchase Agreements...

  3. Nature Elements Holding AG | Open Energy Information

    Open Energy Info (EERE)

    Holding AG Jump to: navigation, search Name: Nature Elements Holding AG Place: Baar, Switzerland Zip: CH-6340 Sector: Renewable Energy Product: Swiss developer of renewable energy...

  4. Nature Elements Capital | Open Energy Information

    Open Energy Info (EERE)

    Capital Jump to: navigation, search Name: Nature Elements Capital Place: Beijing, Beijing Municipality, China Zip: 100125 Product: Beijing-based private equity firm investing in...

  5. Fractionation of elements during copper smelting

    SciTech Connect (OSTI)

    Germani, M.S.; Zoller, W.H.; Small, M.; Moyers, J.L.

    1981-03-01

    A recent study of the elemental composition of particulate material collected from the plumes of five copper smelters in southeastern Arizona indicated that arsenic, lead, selenium, cadmium, zinc, tungsten, indium, and other chalcophilic elements are highly enriched in the plume materials relative to the background aerosol. Enrichments are due to the volatilization of these elements during copper smelting. Significant differences in the elemental compositions of plumes from the various smelters appear to be due to differences in the feed material, smelting conditions, and equipment use by the smelters. (3 graphs, 13 references, 7 tables)

  6. Two position optical element actuator device

    DOE Patents [OSTI]

    Holdener, Fred R.; Boyd, Robert D.

    2002-01-01

    The present invention is a two position optical element actuator device utilizing a powered means to hold an actuation arm, to which an optical element is attached, in a first position. A non-powered means drives the actuation arm to a second position, when the powered means ceases to receive power. The optical element may be a electromagnetic (EM) radiation or particle source, an instrument, or EM radiation or particle transmissive, reflective or absorptive elements. A bearing is used to transfer motion and smoothly transition the actuation arm from the first to second position.

  7. Bi-stable optical element actuator device

    DOE Patents [OSTI]

    Holdener, Fred R.; Boyd, Robert D.

    2002-01-01

    The present invention is a bistable optical element actuator device utilizing a powered means to move an actuation arm, to which an optical element is attached, between two stable positions. A non-powered means holds the actuation arm in either of the two stable positions. The optical element may be a electromagnetic (EM) radiation or particle source, an instrument, or EM radiation or particle transmissive reflective or absorptive elements. A bearing is used to transfer motion and smoothly transition the actuation arm between the two stable positions.

  8. Low exchange element for nuclear reactor

    DOE Patents [OSTI]

    Brogli, Rudolf H. (Aarau, CH); Shamasunder, Bangalore I. (Encinitas, CA); Seth, Shivaji S. (Encinitas, CA)

    1985-01-01

    A flow exchange element is presented which lowers temperature gradients in fuel elements and reduces maximum local temperature within high temperature gas-cooled reactors. The flow exchange element is inserted within a column of fuel elements where it serves to redirect coolant flow. Coolant which has been flowing in a hotter region of the column is redirected to a cooler region, and coolant which has been flowing in the cooler region of the column is redirected to the hotter region. The safety, efficiency, and longevity of the high temperature gas-cooled reactor is thereby enhanced.

  9. Nations Work Together to Discover New Element

    DOE R&D Accomplishments [OSTI]

    Cabage, Bill

    2011-03-28

    The discovery of element 117 increases evidence for the "island of stability" in super-heavy nuclei, opening new frontiers of chemistry.

  10. Spectral analysis method for detecting an element

    DOE Patents [OSTI]

    Blackwood, Larry G [Idaho Falls, ID; Edwards, Andrew J [Idaho Falls, ID; Jewell, James K [Idaho Falls, ID; Reber, Edward L [Idaho Falls, ID; Seabury, Edward H [Idaho Falls, ID

    2008-02-12

    A method for detecting an element is described and which includes the steps of providing a gamma-ray spectrum which has a region of interest which corresponds with a small amount of an element to be detected; providing nonparametric assumptions about a shape of the gamma-ray spectrum in the region of interest, and which would indicate the presence of the element to be detected; and applying a statistical test to the shape of the gamma-ray spectrum based upon the nonparametric assumptions to detect the small amount of the element to be detected.

  11. 3-D Finite Element Code Postprocessor

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    TAURUS is an interactive post-processing application supporting visualization of finite element analysis results on unstructured grids. TAURUS provides the ability to display deformed geometries and contours or fringes of a large number of derived results on meshes consisting of beam, plate, shell, and solid type finite elements. Time history plotting is also available.

  12. DISSOLUTION OF ZIRCONIUM-CONTAINING FUEL ELEMENTS

    DOE Patents [OSTI]

    Horn, F.L.

    1961-12-12

    Uranium is recovered from spent uranium fuel elements containing or clad with zirconium. These fuel elements are placed in an anhydrous solution of hydrogen fluoride and nitrogen dioxide. Within this system uranium forms a soluble complex and zirconium forms an insoluble complex. The uranium can then be separated, treated, and removed from solution as uranium hexafluoride. (AEC)

  13. MODERATOR ELEMENTS FOR UNIFORM POWER NUCLEAR REACTOR

    DOE Patents [OSTI]

    Balent, R.

    1963-03-12

    This patent describes a method of obtaining a flatter flux and more uniform power generation across the core of a nuclear reactor. The method comprises using moderator elements having differing moderating strength. The elements have an increasing amount of the better moderating material as a function of radial and/or axial distance from the reactor core center. (AEC)

  14. Damper mechanism for nuclear reactor control elements

    DOE Patents [OSTI]

    Taft, William Elwood

    1976-01-01

    A damper mechanism which provides a nuclear reactor control element decelerating function at the end of the scram stroke. The total damping function is produced by the combination of two assemblies, which operate in sequence. First, a tapered dashram assembly decelerates the control element to a lower velocity, after which a spring hydraulic damper assembly takes over to complete the final damping.

  15. NUCLEAR REACTOR FUEL-BREEDER FUEL ELEMENT

    DOE Patents [OSTI]

    Currier, E.L. Jr.; Nicklas, J.H.

    1962-08-14

    A fuel-breeder fuel element was developed for a nuclear reactor wherein discrete particles of fissionable material are dispersed in a matrix of fertile breeder material. The fuel element combines the advantages of a dispersion type and a breeder-type. (AEC)

  16. Laser optical element mounting arrangement and method

    SciTech Connect (OSTI)

    Whitehouse, D.R.

    1988-10-11

    This patent describes a method of mounting and sealing an optical element of a laser to a mounting support member of the laser comprising the steps of providing an optical element mounting surface the the support member with a smooth surface which is sufficiently smooth to form a vacuum seal with a surface of the optical element, the vacuum seal preventing at least to a large and acceptable degree, movement of gases through the seal between the optical element and the mounting support member as a result of a gas pressure differential across the seal during operation of the laser and contacting the surface of the optical element with the mounting surface of the support member, at ambient temperature to form the vacuum seal between the surfaces without the use of a sealant between the surfaces, and therein the vacuum seal between the surfaces can be broken and remade without use of a sealant.

  17. Elemental composition of two cumulate rocks

    SciTech Connect (OSTI)

    Naeem, A.; Almohandis, A.A.

    1983-04-01

    Two cumulate rock samples K-185, K-250 from the Kapalagulu intrusion, W. Tanzania, were analyzed using X-ray fluorescence (XRF), wet chemical and neutron activation analysis (NAA) techniques. Major element oxides were determined by XRF and wet chemical methods, while the concentration of trace elements were measured by NAA, using high resolution Ge(Li) detector, minicomputer-based data acquisition system and off-line computer. The percentage of major oxides and sixteen trace elements have been reported. It has been found that Cr, Ni, and Co are highly concentrated in K-250 while Sc, and most of the major elements are more concentrated in K-185. The variation of major and trace elements in these two samples have been discussed.

  18. TRACE ELEMENT ANALYSES OF URANIUM MATERIALS

    SciTech Connect (OSTI)

    Beals, D; Charles Shick, C

    2008-06-09

    The Savannah River National Laboratory (SRNL) has developed an analytical method to measure many trace elements in a variety of uranium materials at the high part-per-billion (ppb) to low part-per-million (ppm) levels using matrix removal and analysis by quadrapole ICP-MS. Over 35 elements were measured in uranium oxides, acetate, ore and metal. Replicate analyses of samples did provide precise results however none of the materials was certified for trace element content thus no measure of the accuracy could be made. The DOE New Brunswick Laboratory (NBL) does provide a Certified Reference Material (CRM) that has provisional values for a series of trace elements. The NBL CRM were purchased and analyzed to determine the accuracy of the method for the analysis of trace elements in uranium oxide. These results are presented and discussed in the following paper.

  19. (Relative mobilities and transport mechanisms of trace elements during contact metamorphism of carbonate rocks). Progress report

    SciTech Connect (OSTI)

    1980-01-01

    The main objective of this study is to investigate the relative mobilities and transport mechanisms of major, minor, and trace elements during the contact metamorphism of carbonate rocks. The large contrasts in chemical potentials of SiO/sub 2/, Al/sub 2/O/sub 3/, and CaO across a granitic pluton-limestone contact may induce metasomatism. In addition, rare earth and transition metal elements may act as tracers, and their redistribution during metamorphism may record convective cooling processes. The results of this study may have an application toward the problem of radioactive waste disposal and the degree to which radioactive nuclides may be expected to migrate during geologically significant periods of time.

  20. Methods for preparation of nanocrystalline rare earth phosphates for lighting applications

    DOE Patents [OSTI]

    Comanzo, Holly Ann; Manoharan, Mohan; Martins Loureiro, Sergio Paulo; Setlur, Anant Achyut; Srivastava, Alok Mani

    2013-04-16

    Disclosed here are methods for the preparation of optionally activated nanocrystalline rare earth phosphates. The optionally activated nanocrystalline rare earth phosphates may be used as one or more of quantum-splitting phosphor, visible-light emitting phosphor, vacuum-UV absorbing phosphor, and UV-emitting phosphor. Also disclosed herein are discharge lamps comprising the optionally activated nanocrystalline rare earth phosphates provided by these methods.

  1. Metal sulfide and rare-earth phosphate nanostructures and methods of making same

    DOE Patents [OSTI]

    Wong, Stanislaus; Zhang, Fen

    2016-06-28

    The present invention provides a method of producing a crystalline rare earth phosphate nanostructure. The method comprising: providing a rare earth metal precursor solution and providing a phosphate precursor solution; placing a porous membrane between the metal precursor solution and the phosphate precursor solution, wherein metal cations of the metal precursor solution and phosphate ions of the phosphate precursor solution react, thereby producing a crystalline rare earth metal phosphate nanostructure.

  2. Control volume finite element method with multidimensional edge element Scharfetter-Gummel upwinding. Part 1, formulation.

    SciTech Connect (OSTI)

    Bochev, Pavel Blagoveston

    2011-06-01

    We develop a new formulation of the Control Volume Finite Element Method (CVFEM) with a multidimensional Scharfetter-Gummel (SG) upwinding for the drift-diffusion equations. The formulation uses standard nodal elements for the concentrations and expands the flux in terms of the lowest-order Nedelec H(curl; {Omega})-compatible finite element basis. The SG formula is applied to the edges of the elements to express the Nedelec element degree of freedom on this edge in terms of the nodal degrees of freedom associated with the endpoints of the edge. The resulting upwind flux incorporates the upwind effects from all edges and is defined at the interior of the element. This allows for accurate evaluation of integrals on the boundaries of the control volumes for arbitrary quadrilateral elements. The new formulation admits efficient implementation through a standard loop over the elements in the mesh followed by loops over the element nodes (associated with control volume fractions in the element) and element edges (associated with flux degrees of freedom). The quantities required for the SG formula can be precomputed and stored for each edge in the mesh for additional efficiency gains. For clarity the details are presented for two-dimensional quadrilateral grids. Extension to other element shapes and three dimensions is straightforward.

  3. DOE Announces Second RFI on Rare Earth Metals | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Second RFI on Rare Earth Metals DOE Announces Second RFI on Rare Earth Metals March 22, 2011 - 12:00am Addthis Washington, D.C. - The Department of Energy today released a Request for Information (RFI) soliciting information from the public on rare earth metals and other materials used in the energy sector. Responses to this RFI will inform an update to DOE's Critical Materials Strategy (pdf - 5.7mb ), released December 15, 2010, that assessed the use of rare earth metals and other materials

  4. A consistent approach to falsifying ?CDM with rare galaxy clusters

    SciTech Connect (OSTI)

    Harrison, Ian; Hotchkiss, Shaun E-mail: shaun.hotchkiss@helsinki.fi

    2013-07-01

    We consider methods with which to answer the question ''is any observed galaxy cluster too unusual for ?CDM?'' After emphasising that many previous attempts to answer this question will overestimate the confidence level at which ?CDM can be ruled out, we outline a consistent approach to these rare clusters, which allows the question to be answered. We define three statistical measures, each of which are sensitive to changes in cluster populations arising from different modifications to the cosmological model. We also use these properties to define the ''equivalent mass at redshift zero'' for a cluster the mass of an equally unusual cluster today. This quantity is independent of the observational survey in which the cluster was found, which makes it an ideal proxy for ranking the relative unusualness of clusters detected by different surveys. These methods are then used on a comprehensive sample of observed galaxy clusters and we confirm that all are less than 2? deviations from the ?CDM expectation. Whereas we have only applied our method to galaxy clusters, it is applicable to any isolated, collapsed, halo. As motivation for future surveys, we also calculate where in the mass redshift plane the rarest halo is most likely to be found, giving information as to which objects might be the most fruitful in the search for new physics.

  5. FUEL ELEMENT FOR A NEUTRONIC REACTOR

    DOE Patents [OSTI]

    McGeary, R.K.; Winslow, F.R.

    1963-08-13

    A method of making fuel elements wherein several individual fuel pellets are positioned into a cladding tube and the tape stretched longitudinally until the cladding tube grips each pellet and, in addition, necks down between each pellet is described. (AEC)

  6. Method and apparatus for staking optical elements

    DOE Patents [OSTI]

    Woods, Robert O.

    1988-01-01

    A method and apparatus for staking two optical elements together in order to retain their alignment is disclosed. The apparatus includes a removable adaptor made up of first and second adaptor bodies each having a lateral slot in their front and side faces. The adaptor also includes a system for releasably attaching each adaptor body to a respective optical element such that when the two optical elements are positioned relative to one another the adaptor bodies are adjacent and the lateral slots therein are aligned to form key slots. The adaptor includes keys which are adapted to fit into the key slots. A curable filler material is employed to retain the keys in the key slots and thereby join the first and second adaptor bodies to form the adaptor. Also disclosed is a method for staking together two optical elements employing the adaptor of the present invention.

  7. Method and apparatus for staking optical elements

    DOE Patents [OSTI]

    Woods, Robert O.

    1988-10-04

    A method and apparatus for staking two optical elements together in order to retain their alignment is disclosed. The apparatus includes a removable adaptor made up of first and second adaptor bodies each having a lateral slot in their front and side faces. The adaptor also includes a system for releasably attaching each adaptor body to a respective optical element such that when the two optical elements are positioned relative to one another the adaptor bodies are adjacent and the lateral slots therein are aligned to form key slots. The adaptor includes keys which are adapted to fit into the key slots. A curable filler material is employed to retain the keys in the key slots and thereby join the first and second adaptor bodies to form the adaptor. Also disclosed is a method for staking together two optical elements employing the adaptor of the present invention.

  8. Ion processing element with composite media

    DOE Patents [OSTI]

    Mann, Nick R.; Tranter, Troy J.; Todd, Terry A.; Sebesta, Ferdinand

    2003-02-04

    An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to effectively process a high volume flows.

  9. Ion processing element with composite media

    DOE Patents [OSTI]

    Mann, Nick R.; Tranter, Troy J.; Todd, Terry A.; Sebesta, Ferdinand

    2009-03-24

    An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to effectively process a high volume flows.

  10. Pressurization of whole element canister during staging

    SciTech Connect (OSTI)

    Huang, F.F.

    1998-01-27

    An analytical model was developed to estimate the buildup of gas pressure for a single outer element in a hot cell test container for a post cold vacuum drying staging/storage test. This model considers various sources of gas generation and gas consumption as a function of time. In a canister containing spent nuclear fuel, hydrogen is generated from the reactions of uranium with free water or hydrated water, hydride decomposition, and radiolysis. The canister pressurization model predicts a stable pressure and a peak temperature during staging, with an assumption that a fuel element contains 40 gm of corrosion products and a decay heat of 2.07 or 1.06 Watts. Calculations were also performed on constant temperature tests for fuel elements containing varied amounts of sludge tested at 150, 125, 105, and 85 C. The pressurization model will be used to evaluate test results obtained from post-drying testing on whole fuel elements.

  11. NEUTRONIC REACTOR AND FUEL ELEMENT THEREFOR

    DOE Patents [OSTI]

    Szilard, L.; Young, G.J.

    1958-03-01

    This patent relates to a reactor design of the type which employs solid fuel elements disposed in channels within the moderator through which channels and around the fuel elements is conveyed a coolant fiuid. The coolant channels are comprised of aluminum tubes extending through a solid moderator such as graphite and the fuel elements are comprised of an elongated solid body of natural uranium jacketed in an aluminum jacket with the ends thereof closed by aluminum caps of substantially greater thickness than the jacket was and in good thermal contact with the fuel material to facilitate the conduction of heat from the central portion of said ends to the coolant surrounding the fuel element to prevent overheating of said central portion.

  12. Magnetic bearing element with adjustable stiffness

    DOE Patents [OSTI]

    Post, Richard F

    2013-11-12

    A compact magnetic bearing element is provided which is made of permanent magnet discs configured to be capable of the adjustment of the bearing stiffness and levitation force over a wide range.

  13. Scoping Inventory Calculations for the Rare Isotope Accelerator

    SciTech Connect (OSTI)

    Ahle, L E; Boles, J L

    2003-07-25

    This document is a report on our activities in FY03 exploring nuclear safety and hazard analysis issues relevant to the Rare Isotope Accelerator (RIA). It is not clear whether DOE will classify the RIA as an accelerator facility subject to the accelerator-specific safety requirements of DOE Order 420.2A or as a nonreactor nuclear facility subject to the requirements of 10 CFR 830. The final outcome of this issue will have significant impact on the construction and operation of the facility and the quality assurance requirements for items or services that may affect nuclear safety. The resolution of this issue will be an important earlier decision for the RIA project team and will require early consultation with the appropriate DOE authorities. For nuclear facilities, facility hazard classification depends on the inventory of releasable radionuclides; therefore, some simplistic, scoping inventory calculations for some assumed targets and beams are done to estimate the hazard category of RIA if it is declared a nuclear facility. These calculations show that for the scenarios analyzed, RIA would produce sufficient quantities of radionuclides to be classified as a Category 3 nuclear facility. Over the lifetime of RIA operations, it may be possible to build up Category 2 quantities of {sup 227}Ac and {sup 228}Th. A storage building, separate from the driver, target, and experimental buildings, used to store and isolate accumulated targets and other hardware, can mitigate the potential impact on RIA. The more onerous requirements of Category 2 facilities would only be imposed on the storage facility and not on the rest of the RIA facilities. Some of the differences in a category 2 and category 3 facility are discussed in Appendix 1.

  14. Quadrilateral/hexahedral finite element mesh coarsening

    DOE Patents [OSTI]

    Staten, Matthew L; Dewey, Mark W; Scott, Michael A; Benzley, Steven E

    2012-10-16

    A technique for coarsening a finite element mesh ("FEM") is described. This technique includes identifying a coarsening region within the FEM to be coarsened. Perimeter chords running along perimeter boundaries of the coarsening region are identified. The perimeter chords are redirected to create an adaptive chord separating the coarsening region from a remainder of the FEM. The adaptive chord runs through mesh elements residing along the perimeter boundaries of the coarsening region. The adaptive chord is then extracted to coarsen the FEM.

  15. Stretchable semiconductor elements and stretchable electrical circuits

    DOE Patents [OSTI]

    Rogers, John A.; Khang, Dahl-Young; Menard, Etienne

    2009-07-07

    The invention provides methods and devices for fabricating printable semiconductor elements and assembling printable semiconductor elements onto substrate surfaces. Methods, devices and device components of the present invention are capable of generating a wide range of flexible electronic and optoelectronic devices and arrays of devices on substrates comprising polymeric materials. The present invention also provides stretchable semiconductor structures and stretchable electronic devices capable of good performance in stretched configurations.

  16. Poole-frenkel piezoconductive element and sensor

    DOE Patents [OSTI]

    Habermehl, Scott D.

    2004-08-03

    A new class of highly sensitive piezoconductive strain sensor elements and sensors has been invented. The new elements function under conditions such that electrical conductivity is dominated by Poole-Frenkel transport. A substantial piezoconductive effect appears in this regime, allowing the new sensors to exhibit sensitivity to applied strain as much as two orders of magnitude in excess of prior art sensors based on doped silicon.

  17. Molten metal containment vessel with rare earth oxysulfide protective coating thereon and method of making same

    DOE Patents [OSTI]

    Krikorian, Oscar H.; Curtis, Paul G.

    1992-01-01

    An improved molten metal containment vessel is disclosed in which wetting of the vessel's inner wall surfaces by molten metal is inhibited by coating at least the inner surfaces of the containment vessel with one or more rare earth oxysulfide or rare earth sulfide compounds to inhibit wetting and or adherence by the molten metal to the surfaces of the containment vessel.

  18. Hydrothermal method of synthesis of rare-earth tantalates and niobates

    DOE Patents [OSTI]

    Nyman, May D; Rohwer, Lauren E.S.; Martin, James E

    2012-10-16

    A hydrothermal method of synthesis of a family of rare-earth Group 5 oxides, where the Group 5 oxide is a niobate or tantalate. The rare-earth Group 5 oxides can be doped with suitable emitter ions to form nanophosphors.

  19. Grant Helps Make U.S. Rare Earth Magnets More Common

    Broader source: Energy.gov [DOE]

    Sintered rare earth magnets - which are vital components in hybrid vehicle motors and wind turbine generators - are a $4 billion worldwide industry. Landisville, Pa.-based Electron Energy Corporation is hoping to bring a share of that market (and jobs) to the U.S. with their sintered rare earth magnet innovation.

  20. Development of a fast cyclotron gas stopper for intense rare isotope beams from projectile fragmentation: Study of ion extraction with a radiofrequency carpet

    SciTech Connect (OSTI)

    Bollen, Georg; Morrissey, David

    2011-01-16

    Research and development has been performed in support of the design of a future rare isotope beam facility in the US. An important aspect of plans for earlier RIA (Rare Isotope Accelerator) and a requirement of FRIB (Facility of Rare Isotope Beams) to be built at Michigan State University are the availability of so-called stopped beams for research that contributes to answering questions like how elements in the universe are created and to provide better insight into the nature of Fundamental Interactions. In order to create stopped beams techniques are required that transform fast rare isotopes beams as they are available directly after addresses questions like the origin of that will allow and High priority is given to the evaluation of intensity limitations and the efficiency of stopping of fast fragment beams in gas cells and to the exploration of options to increase the efficiency and the reduction of space charge effects. Systematic studies performed at MSU as part of the RIA R&D with a linear gas cell under conditions close to those expected at RIA and related simulations confirm that the efficiency of stopping and extracting ions decreases with increasing beam intensity. Similar results have also been observed at RIKEN in Japan. These results indicate the concepts presently under study will not be able to cover the full range of intensities of fast beams expected at RIA without major losses. The development of a more robust concept is therefore critical to the RIA concept. Recent new beam simulation studies performed at the NSCL show that the stopping of heavy ions in a weakly focusing gas-filled magnetic field can overcome the intensity limitation of present systems while simultaneously providing a much faster ion extraction. We propose to design and build such a cyclotron gas stopper and to test it at the NSCL under conditions as close as possible to those found at RIA.

  1. Stacked switchable element and diode combination with a low breakdown switchable element

    DOE Patents [OSTI]

    Wang, Qi; Ward, James Scott; Hu, Jian; Branz, Howard M.

    2012-06-19

    A device (10) comprises a semiconductor diode (12) and a switchable element (14) positioned in stacked adjacent relationship. The semiconductor diode (12) and the switchable element (14) are electrically connected in series with one another. The switchable element (14) is switchable from a low-conductance state to a high-conductance state in response to the application of a low-density forming current and/or a low voltage.

  2. NEUTRONIC REACTOR FUEL ELEMENT AND CORE SYSTEM

    DOE Patents [OSTI]

    Moore, W.T.

    1958-09-01

    This patent relates to neutronic reactors and in particular to an improved fuel element and a novel reactor core system for facilitating removal of contaminating fission products, as they are fermed, from association with the flssionable fuel, so as to mitigate the interferent effects of such fission products during reactor operation. The fuel elements are comprised of tubular members impervious to fluid and contatning on their interior surfaces a thin layer of fissionable material providing a central void. The core structure is comprised of a plurality of the tubular fuel elements arranged in parallel and a closed manifold connected to their ends. In the reactor the core structure is dispersed in a water moderator and coolant within a pressure vessel, and a means connected to said manifuld is provided for withdrawing and disposing of mobile fission product contamination from the interior of the feel tubes and manifold.

  3. Spark discharge trace element detection system

    DOE Patents [OSTI]

    Adler-Golden, Steven; Bernstein, Lawrence S.; Bien, Fritz

    1988-01-01

    A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas.

  4. Spark discharge trace element detection system

    DOE Patents [OSTI]

    Adler-Golden, S.; Bernstein, L.S.; Bien, F.

    1988-08-23

    A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas. 12 figs.

  5. Logic elements for reactor period meter

    DOE Patents [OSTI]

    McDowell, William P.; Bobis, James P.

    1976-01-01

    Logic elements are provided for a reactor period meter trip circuit. For one element, first and second inputs are applied to first and second chopper comparators, respectively. The output of each comparator is O if the input applied to it is greater than or equal to a trip level associated with each input and each output is a square wave of frequency f if the input applied to it is less than the associated trip level. The outputs of the comparators are algebraically summed and applied to a bandpass filter tuned to f. For another element, the output of each comparator is applied to a bandpass filter which is tuned to f to give a sine wave of frequency f. The outputs of the filters are multiplied by an analog multiplier whose output is 0 if either input is 0 and a sine wave of frequency 2f if both inputs are a frequency f.

  6. Broadband diffractive lens or imaging element

    DOE Patents [OSTI]

    Ceglio, Natale M. (Livermore, CA); Hawryluk, Andrew M. (Modesto, CA); London, Richard A. (Oakland, CA); Seppala, Lynn G. (Livermore, CA)

    1993-01-01

    A broadband diffractive lens or imaging element produces a sharp focus and/or a high resolution image with broad bandwidth illuminating radiation. The diffractive lens is sectored or segmented into regions, each of which focuses or images a distinct narrowband of radiation but all of which have a common focal length. Alternatively, a serial stack of minus filters, each with a diffraction pattern which focuses or images a distinct narrowband of radiation but all of which have a common focal length, is used. The two approaches can be combined. Multifocal broadband diffractive elements can also be formed. Thin film embodiments are described.

  7. TAURUS. 3-d Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1991-05-01

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D (ESTSC 139), DYNA3D (ESTSC 138), TACO3D (ESTSC 287), TOPAZ3D (ESTSC 231), and GEMINI (ESTSC 455) and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  8. TAURUS. 3-d Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1992-03-03

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D (ESTSC 139), DYNA3D (ESTSC 138), TACO3D (ESTSC 287), TOPAZ3D (ESTSC 231), and GEMINI (ESTSC 455) and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  9. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1984-05-01

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  10. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1993-11-30

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  11. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Whirley, R.G.

    1992-03-03

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories,and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  12. TAURUS. 3-D Finite Element Code Postprocessor

    SciTech Connect (OSTI)

    Kennedy, T.

    1992-03-03

    TAURUS reads the binary plot files generated by the LLNL three-dimensional finite element analysis codes, NIKE3D, DYNA3D, TACO3D, TOPAZ3D, and GEMINI and plots contours, time histories, and deformed shapes. Contours of a large number of quantities may be plotted on meshes consisting of plate, shell, and solid type elements. TAURUS can compute a variety of strain measures, reaction forces along constrained boundaries, and momentum. TAURUS has three phases: initialization, geometry display with contouring, and time history processing.

  13. JACKETED FUEL ELEMENTS FOR GRAPHITE MODERATED REACTORS

    DOE Patents [OSTI]

    Szilard, L.; Wigner, E.P.; Creutz, E.C.

    1959-05-12

    Fuel elements for a heterogeneous, fluid cooled, graphite moderated reactor are described. The fuel elements are comprised of a body of natural uranium hermetically sealed in a jacket of corrosion resistant material. The jacket, which may be aluminum or some other material which is non-fissionable and of a type having a low neutron capture cross-section, acts as a barrier between the fissioning isotope and the coolant or moderator or both. The jacket minimizes the tendency of the moderator and coolant to become radioactive and/or contaminated by fission fragments from the fissioning isotope.

  14. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  15. Broadband diffractive lens or imaging element

    DOE Patents [OSTI]

    Ceglio, Natale M. (Livermore, CA); Hawryluk, Andrew M. (Modesto, CA); London, Richard A. (Oakland, CA); Seppala, Lynn G. (Livermore, CA)

    1991-01-01

    A broadband diffractive lens or imaging element produces a sharp focus and/or a high resolution image with broad bandwidth illuminating radiation. The diffractive lens is sectored or segmented into regions, each of which focuses or images a distinct narrowband of radiation but all of which have a common focal length. Alternatively, a serial stack of minus filters, each with a diffraction pattern which focuses or images a distinct narrowband of radiation but all of which have a common focal length, is used. The two approaches can be combined. Multifocal broadband diffractive elements can also be formed.

  16. Broadband diffractive lens or imaging element

    DOE Patents [OSTI]

    Ceglio, N.M.; Hawryluk, A.M.; London, R.A.; Seppala, L.G.

    1993-10-26

    A broadband diffractive lens or imaging element produces a sharp focus and/or a high resolution image with broad bandwidth illuminating radiation. The diffractive lens is sectored or segmented into regions, each of which focuses or images a distinct narrowband of radiation but all of which have a common focal length. Alternatively, a serial stack of minus filters, each with a diffraction pattern which focuses or images a distinct narrowband of radiation but all of which have a common focal length, is used. The two approaches can be combined. Multifocal broadband diffractive elements can also be formed. Thin film embodiments are described. 21 figures.

  17. PROCESS FOR SEPARATING YTTRIUM FROM THE RARE EARTHS BY SOLVENT EXTRACTION

    DOE Patents [OSTI]

    Peppard, D.F.; Mason, G.W.

    1963-11-12

    A process of isolating yttrium from other rare earths present together with it in aqueous solutions is presented. Yttrium and rare earths heavier than yttrium are first extracted with dialkyl phosphoric acid, after adjustment of the acidity to 2 N, and then back-extracted with 5-6 N mineral acid to form a strip solution. Thiocyanate is added to the strip solution and the rare earths heavier than yttrium are then selectively extracted with trialkyl phosphate, dialkyl phosphoric acid, alkyl phosphonate, or dialkyl aryl phosphonate, leaving the yttrium in the aqueous solution. (AEC)

  18. U.S. Rare Earth Magnet Patents Table © 8-29-2016 page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Magnet Patents Table © 8-29-2016 page 1 Disclaimer: This U.S. Rare Earth Magnet Patents Table contains a sample of the rare earth-magnet patents issued by the U.S. Patent and Trademark Office. It was created with key word searching. The Table is not all inclusive of U.S. magnet patents and does not include foreign patents. Some cells in the Table contain estimates, approximations or assessments. Please consult with a professional patent attorney or patent agent, possessing license to

  19. U.S. Rare Earth Magnet Patents Table | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. Rare Earth Magnet Patents Table Neodymium-iron-boron magnet created with one-step refining process developed at The Ames Laboratory. CMI reviewed the U.S. patent database to better understand what is known about rare earth magnets and to identify potential areas to explore. Based on this, CMI created a table of more than 460 recent U.S. patents that address rare earth magnet compositions and processes. The table is available as a searchable pdf document (updated August 29, 2016).

  20. The Common Elements of Atomic and Hadronic Physics (Conference...

    Office of Scientific and Technical Information (OSTI)

    The Common Elements of Atomic and Hadronic Physics Citation Details In-Document Search Title: The Common Elements of Atomic and Hadronic Physics Authors: Brodsky, Stanley J. ;...

  1. Compound and Elemental Analysis At Maui Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Maui Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Maui...

  2. In-Situ, Real Time Measurement of Elemental Constituents | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Situ, Real Time Measurement of Elemental Constituents In-Situ, Real Time Measurement of Elemental Constituents New Laser System Provides Real-Time Measurements for Improved ...

  3. Organic and Elemental Carbon Aerosol Particulates at the Southern...

    Office of Scientific and Technical Information (OSTI)

    Elemental Carbon Aerosol Particulates at the Southern Great Plains Site Field Campaign Report Citation Details In-Document Search Title: Organic and Elemental Carbon Aerosol ...

  4. Fundamental aspects of nuclear reactor fuel elements: solutions...

    Office of Scientific and Technical Information (OSTI)

    Fundamental aspects of nuclear reactor fuel elements: solutions to problems Citation Details In-Document Search Title: Fundamental aspects of nuclear reactor fuel elements: ...

  5. Fundamental aspects of nuclear reactor fuel elements (Technical...

    Office of Scientific and Technical Information (OSTI)

    Fundamental aspects of nuclear reactor fuel elements Citation Details In-Document Search Title: Fundamental aspects of nuclear reactor fuel elements You are accessing a document ...

  6. Thermal Analysis of Ball Type Fuel Element for PBR. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Thermal Analysis of Ball Type Fuel Element for PBR. Citation Details In-Document Search Title: Thermal Analysis of Ball Type Fuel Element for PBR. Authors: ...

  7. GNEP Element:Develop Advanced Burner Reactors | Department of...

    Office of Environmental Management (EM)

    Develop Advanced Burner Reactors GNEP Element:Develop Advanced Burner Reactors An article describing burner reactors and the role in GNEP. PDF icon GNEP Element:Develop Advanced...

  8. DOE Policy for Digital Research Data Management: Suggested Elements...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Suggested Elements for a Data Management Plan DOE Policy for Digital Research Data Management: Suggested Elements for a Data Management Plan The Principal Investigator or other ...

  9. Suggested Elements for an EERE Data Management Plan | Department...

    Office of Environmental Management (EM)

    Services Funding Digital Data Management Suggested Elements for an EERE Data Management Plan Suggested Elements for an EERE Data Management Plan The principal investigator ...

  10. Suggested Elements for a Data Management Plan | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Services Funding Digital Data Management Suggested Elements for a Data Management Plan Suggested Elements for a Data Management Plan The principal investigator should ...

  11. Visible light activated photocatalytic behaviour of rare earth modified commercial TiO{sub 2}

    SciTech Connect (OSTI)

    Tobaldi, D.M.; Seabra, M.P.; Labrincha, J.A.

    2014-02-01

    Highlights: RE gave more surface hydroxyl groups attached to the photocatalyst's surface. RE gave the modified and fired samples a high specific surface area. Photocatalytic activity was assessed in gassolid phase under visible-light exposure. Thermal treated RE-TiO{sub 2}s showed a superior visible-light photocatalytic activity. La-TiO{sub 2} was the best performing photocatalyst. - Abstract: A commercial TiO{sub 2} nanopowder, Degussa P25, was modified with several rare earth (RE) elements in order to extend its photocatalytic activity into the visible range. The mixtures were prepared via solid-state reaction of the precursor oxides, and thermally treated at high temperature (900 and 1000 C), with the aim of investigating the photocatalytic activity of the thermally treated samples. This thermal treatment was chosen for a prospective application as a surface layer in materials that need to be processed at high temperatures. The photocatalytic activity (PCA) of the samples was assessed in gassolid phase monitoring the degradation of isopropanol (IPA) under visible-light irradiation. Results showed that the addition of the REs lanthanum, europium and yttrium to TiO{sub 2} greatly improved its photocatalytic activity, despite the thermal treatment, because of the presence of more surface hydroxyl groups attached to the photocatalyst's surface, together with a higher specific surface area (SSA) of the modified and thermally treated samples, with regard to the unmodified and thermally treated Degussa P25. The samples doped with La, Eu and Y all had excellent PCA under visible-light irradiation, even higher than the untreated Degussa P25 reference sample, despite their thermal treatment at 900 C, with lanthanum producing the best results (i.e. the La-, Eu- and Y-TiO{sub 2} samples, thermally treated at 900 C, had, respectively, a PCA equal to 26, 27 and 18 ppm h{sup ?1} in terms of acetone formation versus 15 ppm h{sup ?1} for the 900 C

  12. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    NA

    2004-11-22

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this modeling activity is to predict dissolved concentrations or solubility limits for 14 elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) important to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are in the form of tabulated functions with pH and log (line integral) CO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. The output data from this report are fundamental inputs for Total System Performance Assessment for the License Application (TSPA-LA) to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for all of the actinides. These models cover broad ranges of environmental conditions so that they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  13. FUEL ELEMENT AND METHOD OF PREPARATION

    DOE Patents [OSTI]

    Kingston, W.E.

    1961-04-25

    A nuclear fuel element in the form of a wire is reported. A bar of uranium is enclosed in a thin layer of aluminum and the composite is sheathed in beryllium, zirconium, or stainnless steel. The sheathed article is then drawn to wire form, heated to alloy the aluminum with both uranium and sheath, and finally cold worked.

  14. Element Agglomeration Algebraic Multigrid and Upscaling Library

    Energy Science and Technology Software Center (OSTI)

    2015-02-11

    ELAG is a serial C++ library for numerical upscaling of finite element discretizations. It provides optimal complexity algorithms to build multilevel hierarchies and solvers that can be used for solving a wide class of partial differential equation (elliptic, hyperbolic, saddle point problems) on general unstructured mesh. Additionally, a novel multilevel solver for saddle point problems with divergence constraint is implemented.

  15. EERE Success Story-UQM Patents Non-Rare Earth Magnet Motor under...

    Office of Environmental Management (EM)

    for electric, hybrid electric, plug-in hybrid electric and fuel cell electric vehicles recently patented a new design for electric vehicle motors that use non-rare earth magnets. ...

  16. Pressure Dependence of the Charge-Density-Wave Gap in Rare-Earth...

    Office of Scientific and Technical Information (OSTI)

    Pressure Dependence of the Charge-Density-Wave Gap in Rare-Earth Tri-Tellurides Citation Details In-Document Search Title: Pressure Dependence of the Charge-Density-Wave Gap in...

  17. On the RMgSn rare earth compounds (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: On the RMgSn rare earth compounds Citation ... OSTI Identifier: 984445 Report Number(s): IS-J 7490 Journal ID: 0925-8388; TRN: ...

  18. U.S. Rare Earth Magnet Patents Table 11-10-2015 page...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which has a remanence, Mr, of 0.95 T or more; and a process where the laminated magnet is multi-polar magnetized in-plane of the thick films. U.S. Rare Earth Magnet Patents Table...

  19. The f-spin physics of rare-earth iron pnictides: influence of...

    Office of Scientific and Technical Information (OSTI)

    influence of d-electron antiferromagnetic order on heavy fermion phase diagram Citation Details In-Document Search Title: The f-spin physics of rare-earth iron pnictides: influence ...

  20. UQM Patents Non-Rare Earth Magnet Motor under DOE-Supported Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    While most plug-in electric vehicles (PEVs) use motors with rare earth metals, these materials are expensive, their prices have been highly volatile (from 80kg to 750kg), and ...

  1. Vehicle Technologies Office Merit Review 2015: Non-Rare Earth Motor Development

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about non-rare earth...

  2. Facility for Rare Isotope Beams: The Journey Has Begun on DOE's latest Scientific User Facility

    Broader source: Energy.gov [DOE]

    After many years of planning, ground was officially broken on the Facility for Rare Isotope Beams (FRIB) in a ceremony held at the construction site on Michigan State University’s campus.

  3. Need rare-earths know-how? The Critical Materials Institute offers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Need rare-earths know-how? The Critical Materials Institute offers lower-cost access to experts and research Contacts: For release: Dec. 1, 2015 Alex King, Director, Critical...

  4. THERMAL EXPANSION AND PHASE INVERSION OF RARE-EARTH OXIDES By...

    Office of Scientific and Technical Information (OSTI)

    ... do not take into account non-rare-earth impurities in ... CALCULATIONS Linear expansion (percent) and linear expansion ... l 2 (5) (6) For the cubic system, measurement of a single ...

  5. 10 Questions for a Materials Scientist: Mr. Rare Earth -- Dr. Karl A.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gschneidner, Jr. | Department of Energy Mr. Rare Earth -- Dr. Karl A. Gschneidner, Jr. 10 Questions for a Materials Scientist: Mr. Rare Earth -- Dr. Karl A. Gschneidner, Jr. April 3, 2013 - 12:59pm Addthis Dr. Karl Gschneidner is holding a neodymium-iron-boron magnet produced using a new, greener process. The process that Dr. Gschneidner helped develop doesn’t produce the environmentally unfriendly byproducts that result from traditional manufacturing methods. | Photo courtesy of Ames

  6. Metabolic characteristics of dominant microbes and key rare species from an

    Office of Scientific and Technical Information (OSTI)

    acidic hot spring in Taiwan revealed by metagenomics (Journal Article) | SciTech Connect Metabolic characteristics of dominant microbes and key rare species from an acidic hot spring in Taiwan revealed by metagenomics Citation Details In-Document Search Title: Metabolic characteristics of dominant microbes and key rare species from an acidic hot spring in Taiwan revealed by metagenomics Microbial diversity and community structures in acidic hot springs have been characterized by 16S rRNA

  7. Ferroelectric tunneling element and memory applications which utilize the tunneling element

    DOE Patents [OSTI]

    Kalinin, Sergei V. [Knoxville, TN; Christen, Hans M. [Knoxville, TN; Baddorf, Arthur P. [Knoxville, TN; Meunier, Vincent [Knoxville, TN; Lee, Ho Nyung [Oak Ridge, TN

    2010-07-20

    A tunneling element includes a thin film layer of ferroelectric material and a pair of dissimilar electrically-conductive layers disposed on opposite sides of the ferroelectric layer. Because of the dissimilarity in composition or construction between the electrically-conductive layers, the electron transport behavior of the electrically-conductive layers is polarization dependent when the tunneling element is below the Curie temperature of the layer of ferroelectric material. The element can be used as a basis of compact 1R type non-volatile random access memory (RAM). The advantages include extremely simple architecture, ultimate scalability and fast access times generic for all ferroelectric memories.

  8. The Optimization of an Ionic Liquid-Based TALSPEAK-Like Process for Rare Earth Ions Separation

    SciTech Connect (OSTI)

    Dai, Sheng; Sun, Xiaoqi; Luo, Huimin

    2014-01-01

    Five new functionalized ionic liquids (FILs), tetraethylammonium di(2-ethylhexyl)phosphate ([N2222][DEHP]), tetraethylammonium bis(2,4,4-trimethylpentyl)phosphinite ([N2222][BTMPP]), tetraethylammonium bis(2,4,4-trimethylpentyl)dithiophosphinite ([N2222][BTMPDTP]), tetrahexylammonium di(2-ethylhexyl)phosphate ([N6666][DEHP]), and tetraoctylammonium di(2-ethylhexyl)phosphate ([N8888][DEHP]) were synthesized and characterized. These ILs along with two previously synthesized FILs ([N4444][DEHP] & [N1888][DEHP]) were used as ionic extractants and investigated for rare earth elements (REEs) separation in 1-decyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide/bis(perfluoroethanesulfonyl)imide ([C10mim][NTf2]/[BETI]). These FILs as ionic extractants were miscible with [C10mim][NTf2]/[BETI]. We herein report the applications of these FILs in an IL-based TALSPEAK-like process and the optimization of the process by adjusting the cations and anions of the FILs, concentrations of the FILs as ionic extractants in the IL phase, concentrations of diethylenetriamine pentaacetic acid (DTPA) in the aqueous phase, and acidities of the aqueous phase.

  9. Magnetic coupling at rare earth ferromagnet/transition metal ferromagnet interfaces: A comprehensive study of Gd/Ni

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Higgs, T. D. C.; Bonetti, S.; Ohldag, H.; Banerjee, N.; Wang, X. L.; Rosenberg, A. J.; Cai, Z.; Zhao, J. H.; Moler, K. A.; Robinson, J. W. A.

    2016-07-22

    Thin film magnetic heterostructures with competing interfacial coupling and Zeeman energy provide a fertile ground to study phase transition between different equilibrium states as a function of external magnetic field and temperature. A rare-earth (RE)/transition metal (TM) ferromagnetic multilayer is a classic example where the magnetic state is determined by a competition between the Zeeman energy and antiferromagnetic interfacial exchange coupling energy. Technologically, such structures offer the possibility to engineer the macroscopic magnetic response by tuning the microscopic interactions between the layers. We have performed an exhaustive study of nickel/gadolinium as a model system for understanding RE/TM multilayers using themore » element-specific measurement technique x-ray magnetic circular dichroism, and determined the full magnetic state diagrams as a function of temperature and magnetic layer thickness. We compare our results to a modified Stoner-Wohlfarth-based model and provide evidence of a thickness-dependent transition to a magnetic fan state which is critical in understanding magnetoresistance effects in RE/TM systems. In conclusion, the results provide important insight for spintronics and superconducting spintronics where engineering tunable magnetic inhomogeneity is key for certain applications.« less

  10. Continuous, real time microwave plasma element sensor

    DOE Patents [OSTI]

    Woskov, Paul P.; Smatlak, Donna L.; Cohn, Daniel R.; Wittle, J. Kenneth; Titus, Charles H.; Surma, Jeffrey E.

    1995-01-01

    Microwave-induced plasma for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury.

  11. 2-d Finite Element Code Postprocessor

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    ORION is an interactive program that serves as a postprocessor for the analysis programs NIKE2D, DYNA2D, TOPAZ2D, and CHEMICAL TOPAZ2D. ORION reads binary plot files generated by the two-dimensional finite element codes currently used by the Methods Development Group at LLNL. Contour and color fringe plots of a large number of quantities may be displayed on meshes consisting of triangular and quadrilateral elements. ORION can compute strain measures, interface pressures along slide lines, reaction forcesmore » along constrained boundaries, and momentum. ORION has been applied to study the response of two-dimensional solids and structures undergoing finite deformations under a wide variety of large deformation transient dynamic and static problems and heat transfer analyses.« less

  12. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

    2014-04-29

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  13. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

    2013-04-30

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  14. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D.; Sulchek, Todd A.; Feigin, Stuart C.

    2010-04-06

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  15. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D.; Sulchek, Todd A.; Feigin, Stuart C.

    2012-07-10

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  16. Continuous, real time microwave plasma element sensor

    DOE Patents [OSTI]

    Woskov, P.P.; Smatlak, D.L.; Cohn, D.R.; Wittle, J.K.; Titus, C.H.; Surma, J.E.

    1995-12-26

    Microwave-induced plasma is described for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury. 3 figs.

  17. Oxidation of hydrogen halides to elemental halogens

    DOE Patents [OSTI]

    Rohrmann, Charles A. (Kennewick, WA); Fullam, Harold T. (Richland, WA)

    1985-01-01

    A process for oxidizing hydrogen halides having substantially no sulfur impurities by means of a catalytically active molten salt is disclosed. A mixture of the subject hydrogen halide and an oxygen bearing gas is contacted with a molten salt containing an oxidizing catalyst and alkali metal normal sulfates and pyrosulfates to produce an effluent gas stream rich in the elemental halogen and substantially free of sulfur oxide gases.

  18. SAMPLE CANCELLATION MEMORANDUM FOR NNSA ELEMENTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SAMPLE JUSTIFICATION MEMORANDUM FOR CANCELLATIONS ONLY (NON-NNSA ELEMENTS) (NOTE: Per Office of the Executive Secretariat procedures, please use Calibri, 12 point font for this action memorandum) MEMORANDUM FOR: INGRID KOLB DIRECTOR, OFFICE OF MANAGEMENT THROUGH: KEVIN T. HAGERTY DIRECTOR, OFFICE OF INFORMATION RESOURCES FROM: XXXXXXXXXXXX XXXXXXXXXXXXXXXXXXXXXX SUBJECT: Request to Cancel (enter directive number and title) PURPOSE: (Provide purpose for cancellation. Writer may provide background

  19. Finite Element Results Visualization for Unstructured Grids

    Energy Science and Technology Software Center (OSTI)

    1996-07-15

    GRIZ is a general-purpose post-processing application supporting interactive visualization of finite element analysis results on unstructured grids. In addition to basic pseudocolor renderings of state variables over the mesh surface, GRIZ provides modern visualization techniques such as isocontours and isosurfaces, cutting planes, vector field display, and particle traces. GRIZ accepts both command-line and mouse-driven input, and is portable to virtually any UNIX platform which provides Motif and OpenGl libraries.

  20. Circuit level modeling of inductive elements

    SciTech Connect (OSTI)

    Muyshondt, G.P.; Portnoy, W.M.

    1989-01-01

    Design and analysis of spacecraft power systems have been difficult to perform because of the lack of circuit level models for nonlinear inductive elements. This paper reviews some of the models which have been proposed, their limitations, and applications. An improved saturation dependent model will be described. The model has been implemented in SPICE and with a commercial circuit program and demonstrated to be satisfactory in both implementations. 3 refs., 9 figs.

  1. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    P. Bernot

    2005-07-13

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this activity is to predict dissolved concentrations or solubility limits for elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) relevant to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are provided in the form of tabulated functions with pH and log fCO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. Even though selection of an appropriate set of radionuclides documented in Radionuclide Screening (BSC 2002 [DIRS 160059]) includes actinium, transport of Ac is not modeled in the total system performance assessment for the license application (TSPA-LA) model because of its extremely short half-life. Actinium dose is calculated in the TSPA-LA by assuming secular equilibrium with {sup 231}Pa (Section 6.10); therefore, Ac is not analyzed in this report. The output data from this report are fundamental inputs for TSPA-LA used to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for the actinides discussed in this report. These models cover broad ranges of environmental conditions so they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or

  2. ExodusII Finite Element Data Model

    Energy Science and Technology Software Center (OSTI)

    2005-05-14

    EXODUS II is a model developed to store and retrieve data for finite element analyses. It is used for preprocessing (problem definition), postprocessing (results visualization), as well as code to code data transfer. An EXODUS II data file is a random access, machine independent, binary file that is written and read via C, C++, or Fortran library routines which comprise the Application Programming Interface. (exodus II is based on netcdf)

  3. METHOD OF MAKING WIRE FUEL ELEMENTS

    DOE Patents [OSTI]

    Zambrow, J.L.

    1960-08-01

    A method is given for making a nuclear reactor fuel element in the form of a uranium-bearing wire clad with zirconium. A uranium bar is enclosed in a zirconium sheath which is coated with an oxide of magnesium, beryllium, or zirconium. The sheathed bar is then placed in a steel tube and reduced to the desired diameter by swaging at 800 to 900 deg C, after which the steel and oxide are removed.

  4. NUCLEAR REACTOR AND THERMIONIC FUEL ELEMENT THEREFOR

    DOE Patents [OSTI]

    Rasor, N.S.; Hirsch, R.L.

    1963-12-01

    The patent relates to the direct conversion of fission heat to electricity by use of thermionic plasma diodes having fissionable material cathodes, said diodes arranged to form a critical mass in a nuclear reactor. The patent describes a fuel element comprising a plurality of diodes each having a fissionable material cathode, an anode around said cathode, and an ionizable gas therebetween. Provision is made for flowing the gas and current serially through the diodes. (AEC)

  5. GNEP Element:Demonstrate More Proliferation-Resistant Recycling |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy GNEP Element:Demonstrate More Proliferation-Resistant Recycling GNEP Element:Demonstrate More Proliferation-Resistant Recycling An article describing GNEP element of recycling. GNEP Element:Demonstrate More Proliferation-Resistant Recycling (478.08 KB) More Documents & Publications GNEP Element:Develop Enhanced Nuclear Safeguards Global Nuclear Energy Partnership Fact Sheet - Develop Enhanced Nuclear Safeguards Global Nuclear Energy Partnership Fact Sheet -

  6. Identifying Synonymous Regulatory Elements in Vertebrate Genomes

    SciTech Connect (OSTI)

    Ovcharenko, I; Nobrega, M A

    2005-02-07

    Synonymous gene regulation, defined as driving shared temporal and/or spatial expression of groups of genes, is likely predicated on genomic elements that contain similar modules of certain transcription factor binding sites (TFBS). We have developed a method to scan vertebrate genomes for evolutionary conserved modules of TFBS in a predefined configuration, and created a tool, named SynoR that identify synonymous regulatory elements (SREs) in vertebrate genomes. SynoR performs de novo identification of SREs utilizing known patterns of TFBS in active regulatory elements (REs) as seeds for genome scans. Layers of multiple-species conservation allow the use of differential phylogenetic sequence conservation filters in the search of SREs and the results are displayed as to provide an extensive annotation of genes containing detected REs. Gene Ontology categories are utilized to further functionally classify the identified genes, and integrated GNF Expression Atlas 2 data allow the cataloging of tissue-specificities of the predicted SREs. We illustrate how this new tool can be used to establish a linkage between human diseases and noncoding genomic content. SynoR is publicly available at http://synor.dcode.org.

  7. Denial technology, the neglected security element

    SciTech Connect (OSTI)

    Mauney, C.H.

    1982-01-01

    Even though there has been an increased concern over providing adequate security during the past decade, and even though some aspects of existing security systems have been enhanced during this period, much remains to be done to provide that balance which is so necessary to have all elements function as an effective unit. The area that primarily has been neglected is the delay element - the part of the system which makes possible the needed time for the security force to respond after an intrustion is detected and prior to the adversary attaining his desired goal. The purpose of this paper is to address the vulnerabilities of a security system which exist without the proper delay elements and to suggest how current technology can provide, through the use of activated barriers, that needed delay time to bring the system into balance. Security managers desire reliability and effectiveness; plant managers require safety, non-interference with operations, cost considerate capability, and aesthetic application - these characteristics will be addressed in the context of providing the required delay. This paper, hopefully, will set the stage for dialogue between developer and user, yielding a mutally acceptable approach to balanced security protection.

  8. Foreword [Special Issue on Superheavy Elements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Düllmann, Christoph E.; Herzberg, Rolf -Dietmar; Nazarewicz, Witold; Oganessian, Yuri

    2015-12-07

    Reflecting the breadth of research opportunities in the field of superheavy element research, this special issue covers the range of topics in a comprehensive way, including synthesis of superheavy isotopes, nuclear structure, atomic shell structure, and chemical properties. The contributions detail the status of the field and lay out perspectives for the future. The prospects are bright: new isotopes are awaiting discovery, completing the landscape of superheavy nuclei and bridging the currently existing gap between nuclei synthesized in cold fusion reactions and those from 48Ca induced fusion reactions. The possibility that the limits of nuclear structure studies can be pushedmore » even further in mass and charge has greatly motivated a number of new facilities. Advances in experimental techniques will allow studies on isotopes produced significantly below the 1 pb level. Chemical studies progressing to elements never studied to date are already being prepared. Ultra-fast chemistry setups are under development and it will be fascinating to see them at work, elucidating the influence of relativistic effects on superheavy elements. The richness of chemical systems available for transactinides will expand further, giving access to new chemical systems, giving more information on the architecture of the periodic table.« less

  9. Nuclear fuel elements having a composite cladding

    DOE Patents [OSTI]

    Gordon, Gerald M.; Cowan, II, Robert L.; Davies, John H.

    1983-09-20

    An improved nuclear fuel element is disclosed for use in the core of nuclear reactors. The improved nuclear fuel element has a composite cladding of an outer portion forming a substrate having on the inside surface a metal layer selected from the group consisting of copper, nickel, iron and alloys of the foregoing with a gap between the composite cladding and the core of nuclear fuel. The nuclear fuel element comprises a container of the elongated composite cladding, a central core of a body of nuclear fuel material disposed in and partially filling the container and forming an internal cavity in the container, an enclosure integrally secured and sealed at each end of said container and a nuclear fuel material retaining means positioned in the cavity. The metal layer of the composite cladding prevents perforations or failures in the cladding substrate from stress corrosion cracking or from fuel pellet-cladding interaction or both. The substrate of the composite cladding is selected from conventional cladding materials and preferably is a zirconium alloy.

  10. Nuclear fuel elements made from nanophase materials

    DOE Patents [OSTI]

    Heubeck, N.B.

    1998-09-08

    A nuclear reactor core fuel element is composed of nanophase high temperature materials. An array of the fuel elements in rod form are joined in an open geometry fuel cell that preferably also uses such nanophase materials for the cell structures. The particular high temperature nanophase fuel element material must have the appropriate mechanical characteristics to avoid strain related failure even at high temperatures, in the order of about 3000 F. Preferably, the reactor type is a pressurized or boiling water reactor and the nanophase material is a high temperature ceramic or ceramic composite. Nanophase metals, or nanophase metals with nanophase ceramics in a composite mixture, also have desirable characteristics, although their temperature capability is not as great as with all-ceramic nanophase material. Combinations of conventional or nanophase metals and conventional or nanophase ceramics can be employed as long as there is at least one nanophase material in the composite. The nuclear reactor so constructed has a number of high strength fuel particles, a nanophase structural material for supporting a fuel rod at high temperature, a configuration to allow passive cooling in the event of a primary cooling system failure, an ability to retain a coolable geometry even at high temperatures, an ability to resist generation of hydrogen gas, and a configuration having good nuclear, corrosion, and mechanical characteristics. 5 figs.

  11. Nuclear fuel elements made from nanophase materials

    DOE Patents [OSTI]

    Heubeck, Norman B.

    1998-01-01

    A nuclear reactor core fuel element is composed of nanophase high temperature materials. An array of the fuel elements in rod form are joined in an open geometry fuel cell that preferably also uses such nanophase materials for the cell structures. The particular high temperature nanophase fuel element material must have the appropriate mechanical characteristics to avoid strain related failure even at high temperatures, in the order of about 3000.degree. F. Preferably, the reactor type is a pressurized or boiling water reactor and the nanophase material is a high temperature ceramic or ceramic composite. Nanophase metals, or nanophase metals with nanophase ceramics in a composite mixture, also have desirable characteristics, although their temperature capability is not as great as with all-ceramic nanophase material. Combinations of conventional or nanophase metals and conventional or nanophase ceramics can be employed as long as there is at least one nanophase material in the composite. The nuclear reactor so constructed has a number of high strength fuel particles, a nanophase structural material for supporting a fuel rod at high temperature, a configuration to allow passive cooling in the event of a primary cooling system failure, an ability to retain a coolable geometry even at high temperatures, an ability to resist generation of hydrogen gas, and a configuration having good nuclear, corrosion, and mechanical characteristics.

  12. Foreword [Special Issue on Superheavy Elements

    SciTech Connect (OSTI)

    Düllmann, Christoph E.; Herzberg, Rolf -Dietmar; Nazarewicz, Witold; Oganessian, Yuri

    2015-12-07

    Reflecting the breadth of research opportunities in the field of superheavy element research, this special issue covers the range of topics in a comprehensive way, including synthesis of superheavy isotopes, nuclear structure, atomic shell structure, and chemical properties. The contributions detail the status of the field and lay out perspectives for the future. The prospects are bright: new isotopes are awaiting discovery, completing the landscape of superheavy nuclei and bridging the currently existing gap between nuclei synthesized in cold fusion reactions and those from 48Ca induced fusion reactions. The possibility that the limits of nuclear structure studies can be pushed even further in mass and charge has greatly motivated a number of new facilities. Advances in experimental techniques will allow studies on isotopes produced significantly below the 1 pb level. Chemical studies progressing to elements never studied to date are already being prepared. Ultra-fast chemistry setups are under development and it will be fascinating to see them at work, elucidating the influence of relativistic effects on superheavy elements. The richness of chemical systems available for transactinides will expand further, giving access to new chemical systems, giving more information on the architecture of the periodic table.

  13. Finite Element Interface to Linear Solvers

    Energy Science and Technology Software Center (OSTI)

    2005-03-18

    Sparse systems of linear equations arise in many engineering applications, including finite elements, finite volumes, and others. The solution of linear systems is often the most computationally intensive portion of the application. Depending on the complexity of problems addressed by the application, there may be no single solver capable of solving all of the linear systems that arise. This motivates the desire to switch an application from one solver librwy to another, depending on themore » problem being solved. The interfaces provided by solver libraries differ greatly, making it difficult to switch an application code from one library to another. The amount of library-specific code in an application Can be greatly reduced by having an abstraction layer between solver libraries and the application, putting a common "face" on various solver libraries. One such abstraction layer is the Finite Element Interface to Linear Solvers (EEl), which has seen significant use by finite element applications at Sandia National Laboratories and Lawrence Livermore National Laboratory.« less

  14. Fuel elements of research reactor CM

    SciTech Connect (OSTI)

    Kozlov, A.V.; Morozov, A.V.; Vatulin, A.V.; Ershov, S.A.

    2013-07-01

    In 1961 the CM research reactor was commissioned at the Research Institute of Atomic Reactors (Dimitrovgrad, Russia), it was intended to carry on investigations and the production of transuranium nuclides. The reactor is of a tank type. Original fuel assembly contained plate fuels that were spaced with vanes and corrugated bands. Nickel was used as a cladding material, fuel meat was produced from UO{sub 2} + electrolytic nickel composition. Fuel plates have been replaced by self-spacing cross-shaped dispersion fuels clad in stainless steel. In 2005 the reactor was updated. The purpose of this updating was to increase the quantity of irradiation channels in the reactor core and to improve the neutron balance. The updating was implemented at the expense of 20 % reduction in the quantity of fuel elements in the core which released a space for extra channels and decreased the mass of structural materials in the core. The updated reactor is loaded with modified standard fuel elements with 20 % higher uranium masses. At the same time stainless steel in fuel assembly shrouds was substituted by zirconium alloy. Today in progress are investigations and work to promote the second stage of reactor updating that involve developments of cross-shaped fuel elements having low neutron absorption matrix materials. This article gives an historical account of the design and main technical changes that occurred for the CM reactor since its commissioning.

  15. New rare-earth metal germanides with bismuth substitution. Synthesis, structural variations, and magnetism of the RE[Bi{sub x}Ge{sub 1-x}]{sub 2} (RE=Y, Pr, Nd, Sm, Gd-Tm, Lu) compounds

    SciTech Connect (OSTI)

    Zhang, Jiliang; Hmiel, Benjamin; Antonelli, Anthony; Tobash, Paul H.; Bobev, Svilen; Saha, Shanta; Kirshenbaum, Kevin; Greene, Richard L.; Paglione, Johnpierre

    2012-12-15

    Single-crystals of the novel rare-earth metal-bismuth digermanides with idealized formula RE[Bi{sub x}Ge{sub 1-x}]{sub 2} (RE=Y, Pr, Nd, Sm, Gd-Tm, Lu; x<0.16(1)) have been obtained using the Bi-flux technique. Their structures have been established by single-crystal X-ray diffraction; they can be divided into three classes, closely related to the ZrSi{sub 2} structure with the space group Cmcm (no. 63). The structural relationship and the variations with the type of the rare-earth metal have been explored and discussed. Temperature-dependent magnetization measurements on the single-crystals reveal magnetic behavior, which have been rationalized based on the mean-field theory. At cryogenic temperatures, the localized 4f electrons in most of the compounds exhibit antiferromagnetic ordering, mediated by the conduction electrons via Ruderman-Kittel-Kasuya-Yosida (RKKY) exchange interactions. - Graphical abstract: This paper details the synthesis and the structural characterization of an extended series of rare-earth metal-bismuth-germanides RE[Bi{sub x}Ge{sub 1-x}]{sub 2} (RE=Y, Pr-Sm, Gd-Tm, Lu). They crystallize with the same extended symmetry (space group Cmcm), but with three distinct structures, which are closely related. Magnetization measurements show low-temperature antiferromagnetic ordering. RE[Bi{sub x}Ge{sub 1-x}]{sub 2} are the first compounds between these elements. Highlights: Black-Right-Pointing-Pointer RE[Bi{sub x}Ge{sub 1-x}]{sub 2} (RE=rare-earth metal) are the first compounds of the respective elements. Black-Right-Pointing-Pointer Their structures are closely related. Black-Right-Pointing-Pointer Three structures can be distinguished based on the packing of the REGe{sub 6} triangular prisms. Black-Right-Pointing-Pointer All compounds show low-temperature antiferromagnetic ordering.

  16. An association between the risk of ovarian cancer and rare HRAS1 alleles

    SciTech Connect (OSTI)

    Weitzel, J.N.; Patel, J.; Smith, D.M.

    1994-09-01

    The highly polymorphic HRAS1 minisatellite locus just downstream from the proto-oncogene H-ras-1 on chromosome 11p consists of four common progenitor alleles and several dozen rare alleles, which apparently derive from mutations of the progenitors. Mutant alleles of this locus represent a major risk factor for common types of cancer. Rare-sized HRAS1 alleles have been found more frequently in patients with carcinoma of the breast, colorectum, and urinary bladder and acute leukemia, compared to cancer-free controls. This highly significant association (p<1.001) results in a modest relative risk for patients with one rare allele, but the prevalence of this class of mutant alleles implies an important attributable risk: 1 in 11 cancers of the breast, colorectum, and bladder. Therefore, we performed a case-control study using conventional (Southern blot) and PCR-based methods to score HRAS1 alleles in the leukocyte DNA from 59 patients with ovarian cancer, and 51 cancer-free controls. Our preliminary data suggest an increased incidence of rare and intermediate HRAS1 alleles in caucasian ovarian cancer patients (13%) compared to cancer-free controls (4%). These results parallel the allele distribution seen in the large published series, and lend support for a significant association between rare HRAS1 alleles and ovarian cancer predisposition.

  17. Computer modelling of the reduction of rare earth dopants in barium aluminate

    SciTech Connect (OSTI)

    Rezende, Marcos V. dos S; Valerio, Mario E.G.; Jackson, Robert A.

    2011-08-15

    Long lasting phosphorescence in barium aluminates can be achieved by doping with rare earth ions in divalent charge states. The rare earth ions are initially in a trivalent charge state, but are reduced to a divalent charge state before being doped into the material. In this paper, the reduction of trivalent rare earth ions in the BaAl{sub 2}O{sub 4} lattice is studied by computer simulation, with the energetics of the whole reduction and doping process being modelled by two methods, one based on single ion doping and one which allows dopant concentrations to be taken into account. A range of different reduction schemes are considered and the most energetically favourable schemes identified. - Graphical abstract: The doping and subsequent reduction of a rare earth ion into the barium aluminate lattice. Highlights: > The doping of barium aluminate with rare earth ions reduced in a range of atmospheres has been modelled. > The overall solution energy for the doping process for each ion in each reducing atmosphere is calculated using two methods. > The lowest energy reduction process is predicted and compared with experimental results.

  18. Method and system for processing optical elements using magnetorheological finishing

    DOE Patents [OSTI]

    Menapace, Joseph Arthur; Schaffers, Kathleen Irene; Bayramian, Andrew James; Molander, William A

    2012-09-18

    A method of finishing an optical element includes mounting the optical element in an optical mount having a plurality of fiducials overlapping with the optical element and obtaining a first metrology map for the optical element and the plurality of fiducials. The method also includes obtaining a second metrology map for the optical element without the plurality of fiducials, forming a difference map between the first metrology map and the second metrology map, and aligning the first metrology map and the second metrology map. The method further includes placing mathematical fiducials onto the second metrology map using the difference map to form a third metrology map and associating the third metrology map to the optical element. Moreover, the method includes mounting the optical element in the fixture in an MRF tool, positioning the optical element in the fixture; removing the plurality of fiducials, and finishing the optical element.

  19. Upgraded HFIR Fuel Element Welding System

    SciTech Connect (OSTI)

    Sease, John D

    2010-02-01

    The welding of aluminum-clad fuel plates into aluminum alloy 6061 side plate tubing is a unique design feature of the High Flux Isotope Reactor (HFIR) fuel assemblies as 101 full-penetration circumferential gas metal arc welds (GMAW) are required in the fabrication of each assembly. In a HFIR fuel assembly, 540 aluminum-clad fuel plates are assembled into two nested annular fuel elements 610 mm (24-inches) long. The welding process for the HFIR fuel elements was developed in the early 1960 s and about 450 HFIR fuel assemblies have been successfully welded using the GMAW process qualified in the 1960 s. In recent years because of the degradation of the electronic and mechanical components in the old HFIR welding system, reportable defects in plate attachment or adapter welds have been present in almost all completed fuel assemblies. In October 2008, a contract was awarded to AMET, Inc., of Rexburg, Idaho, to replace the old welding equipment with standard commercially available welding components to the maximum extent possible while maintaining the qualified HFIR welding process. The upgraded HFIR welding system represents a major improvement in the welding system used in welding HFIR fuel elements for the previous 40 years. In this upgrade, the new inner GMAW torch is a significant advancement over the original inner GMAW torch previously used. The innovative breakthrough in the new inner welding torch design is the way the direction of the cast in the 0.762 mm (0.030-inch) diameter aluminum weld wire is changed so that the weld wire emerging from the contact tip is straight in the plane perpendicular to the welding direction without creating any significant drag resistance in the feeding of the weld wire.

  20. Visual examinations of K east fuel elements

    SciTech Connect (OSTI)

    Pitner, A.L., Fluor Daniel Hanford

    1997-02-03

    Selected fuel elements stored in both ``good fuel`` and ``bad fuel`` canisters in K East Basin were extracted and visually examined full length for damage. Lower end damage in the ``bad fuel`` canisters was found to be more severe than expected based on top end appearances. Lower end damage for the ``good fuel`` canisters, however, was less than expected based on top end observations. Since about half of the fuel in K East Basin is contained in ``good fuel`` canisters based on top end assessments, the fraction of fuel projected to be intact with respect to IPS processing considerations remains at 50% based on these examination results.