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1

FAQ 14-What does a depleted uranium hexafluoride cylinder look...  

NLE Websites -- All DOE Office Websites (Extended Search)

depleted uranium hexafluoride cylinder look like? What does a depleted uranium hexafluoride cylinder look like? A picture is worth a thousand words The pictures below show typical...

2

Video: Part of the 'Hole' Story (of Uranium Hexafluoride Cylinders)  

NLE Websites -- All DOE Office Websites (Extended Search)

Hole Story Hole Story Part of the "Hole" Story (of Uranium Hexafluoride Cylinders) Holes in the depleted Uranium Hexafluoride storage cylinders are investigated. It is shown that corrosion products cause the openings to be self-healing. View this Video in Real Player format Download free RealPlayer SP Highlights of the Video: Video 00:00 Part of the 'Hole' Story Video 00:05 One of the depleted UF6 cylinder storage lots at Portsmouth Video 00:28 48G cylinders, each containing 14 tons of depleted UF6, in storage Video 00:52 Stacked 48G cylinders Video 01:35 UF6 sealed in glass tube Video 02:01 A lifting lug of one cylinder damaging a neighboring cylinder Video 02:37 Damage to small hole cylinder from impact with a lifting lub of an adjoining cylinder

3

Video: The Inside Story (of a Depleted Uranium Hexafluoride Cylinder)  

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Inside Story Inside Story The Inside Story The Inside Story (of a Depleted Uranium Hexafluoride Cylinder) Probes are used to look at the inside of a Uranium Hexafluoride cylinder. The distribution and structure of the contents are discussed. View this Video in Real Player format Download free RealPlayer SP Highlights of the Video: Video 00:42 10 ton 48Xcylinder of UF6 Video 01:19 Liquid UF6 filling 95% of cylinder volume Video 02:15 Liquid UF6 Video 02:23 Beginning of UF6 phase change from liquid to solid Video 02:32 Solid UF6 Video 03:00 Probe and instrument to investigate inside cylinder Video 04:09 Workers preparing to insert TV camera probe into 48X cylinder containing 10 tons of solid UF6 Video 04:28 Inner surface of head of cylinder showing no corrosion

4

Criticality concerns in cleaning large uranium hexafluoride cylinders  

SciTech Connect

Cleaning large cylinders used to transport low-enriched uranium hexafluoride (UF{sub 6}) presents several challenges to nuclear criticality safety. This paper presents a brief overview of the cleaning process, the criticality controls typically employed and their bases. Potential shortfalls in implementing these controls are highlighted, and a simple example to illustrate the difficulties in complying with the Double Contingency Principle is discussed. Finally, a summary of recommended criticality controls for large cylinder cleaning operations is presented.

Sheaffer, M.K.; Keeton, S.C.; Lutz, H.F.

1995-06-01T23:59:59.000Z

5

FAQ 15-What are the dimensions of a depleted uranium hexafluoride cylinder?  

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are the dimensions of a depleted uranium hexafluoride cylinder? are the dimensions of a depleted uranium hexafluoride cylinder? What are the dimensions of a depleted uranium hexafluoride cylinder? Several different cylinder types are in use, although the vast majority of cylinders are designed to contain 14-tons (12-metric tons) of depleted UF6. The 14-ton-capacity cylinders are 12 ft (3.7 m) long by 4 ft (1.2 m) in diameter, with most having an initial wall thickness of 5/16 in. (0.79 cm) of steel. The cylinders have external stiffening rings that provide support. Lifting lugs for handling are attached to the stiffening rings. A small percentage of the cylinders have skirted ends (extensions of the cylinder walls past the rounded ends of the cylinder). Each cylinder has a single valve for filling and emptying located on one end at the 12 o'clock position. Similar, but slightly smaller, cylinders designed to contain 10 tons (9 metric tons) of depleted UF6 are also in use. Cylinders are manufactured in accordance with an American National Standards Institute standard (ANSI N14.1, American National Standard for Nuclear Materials - Uranium Hexafluoride - Packaging for Transport) as specified in 49 CFR 173.420, the federal regulations governing transport of depleted UF6.

6

Depleted Uranium Hexafluoride Management  

NLE Websites -- All DOE Office Websites (Extended Search)

OFFICE OF DEPLETED URANIUM HEXAFLUORIDE MANAGEMENT Issuance Of Final Report On Preconceptual Designs For Depleted Uranium Hexafluoride Conversion Plants The Department of Energy...

7

A concept of a nonfissile uranium hexafluoride overpack for storage, transport, and processing of corroded cylinders  

SciTech Connect

There is a need to develop a means of safely transporting breached 48-in. cylinders containing depleted uranium hexafluoride (UF{sub 6}) from current storage locations to locations where the contents can be safely removed. There is also a need to provide a method of safely and easily transporting degraded cylinders that no longer meet the US Department of Transportation (DOT) and American National Standards Institute, Inc., (ANSI) requirements for shipments of depleted UF{sub 6}. A study has shown that an overpack can be designed and fabricated to satisfy these needs. The envisioned overpack will handle cylinder models 48G, 48X, and 48Y and will also comply with the ANSI N14.1 and the American Society of Mechanical Engineers (ASME) Sect. 8 requirements.

Pope, R.B.; Cash, J.M. [Oak Ridge National Lab., TN (United States); Singletary, B.H. [Lockheed Martin Energy Systems, Oak Ridge, TN (United States)

1996-06-01T23:59:59.000Z

8

Results of the remote sensing feasibility study for the uranium hexafluoride storage cylinder yard program  

Science Conference Proceedings (OSTI)

The US DOE manages the safe storage of approximately 650,000 tons of depleted uranium hexafluoride remaining from the Cold War. This slightly radioactive, but chemically active, material is contained in more than 46,000 steel storage cylinders that are located at Oak Ridge, Tennessee; Paducah, Kentucky; and Portsmouth, Ohio. Some of the cylinders are more than 40 years old, and approximately 17,500 are considered problem cylinders because their physical integrity is questionable. These cylinders require an annual visual inspection. The remainder of the 46,000-plus cylinders must be visually inspected every four years. Currently, the cylinder inspection program is extremely labor intensive. Because these inspections are accomplished visually, they may not be effective in the early detection of leaking cylinders. The inspection program requires approximately 12--14 full-time-equivalent (FTE) employees. At the cost of approximately $125K per FTE, this translates to $1,500K per annum just for cylinder inspection. As part of the technology-development portion of the DOE Cylinder Management Program, the DOE Office of Facility Management requested the Remote Sensing Laboratory (RSL) to evaluate remote sensing techniques that have potential to increase the effectiveness of the inspection program and, at the same time, reduce inspection costs and personnel radiation exposure. During two site visits (March and May 1996) to the K-25 Site at Oak Ridge, TN, RSL personnel tested and characterized seven different operating systems believed to detect leakage, surface contamination, thickness and corrosion of cylinder walls, and general area contamination resulting from breached cylinders. The following techniques were used and their performances are discussed: Laser-induced fluorescent imaging; Long-range alpha detection; Neutron activation analysis; Differential gamma-ray attenuation; Compton scatterometry; Active infrared inspection; and Passive thermal infrared imaging.

Balick, L.K.; Bowman, D.R. [Bechtel Nevada, Las Vegas, NV (United States). Remote Sensing Lab.; Bounds, J.H. [Los Alamos National Lab., NM (United States)] [and others

1997-02-01T23:59:59.000Z

9

Method of recovering uranium hexafluoride  

DOE Patents (OSTI)

A method of recovering uranium hexafluoride from gaseous mixtures which comprises adsorbing said uranium hexafluoride on activated carbon is described.

Schuman, S.

1975-12-01T23:59:59.000Z

10

Uranium Hexafluoride (UF6)  

NLE Websites -- All DOE Office Websites (Extended Search)

Hexafluoride (UF6) Hexafluoride (UF6) Uranium Hexafluoride (UF6) line line Properties of UF6 UF6 Health Effects Uranium Hexafluoride (UF6) Physical and chemical properties of UF6, and its use in uranium processing. Uranium Hexafluoride and Its Properties Uranium hexafluoride is a chemical compound consisting of one atom of uranium combined with six atoms of fluorine. It is the chemical form of uranium that is used during the uranium enrichment process. Within a reasonable range of temperature and pressure, it can be a solid, liquid, or gas. Solid UF6 is a white, dense, crystalline material that resembles rock salt. UF6 crystals in a glass vial image UF6 crystals in a glass vial. Uranium hexafluoride does not react with oxygen, nitrogen, carbon dioxide, or dry air, but it does react with water or water vapor. For this reason,

11

FAQ 10-Why is uranium hexafluoride used?  

NLE Websites -- All DOE Office Websites (Extended Search)

uranium hexafluoride used? Why is uranium hexafluoride used? Uranium hexafluoride is used in uranium processing because its unique properties make it very convenient. It can...

12

FAQ 19-Is storage of uranium hexafluoride safe?  

NLE Websites -- All DOE Office Websites (Extended Search)

storage of uranium hexafluoride safe? Is storage of uranium hexafluoride safe? The advanced age of some of the steel cylinders in which the depleted UF6 is contained, and the way...

13

PREPARATION OF URANIUM HEXAFLUORIDE  

DOE Patents (OSTI)

A process is described for preparing uranium hexafluoride from carbonate- leach uranium ore concentrate. The briquetted, crushed, and screened concentrate is reacted with hydrogen fluoride in a fluidized bed, and the uranium tetrafluoride formed is mixed with a solid diluent, such as calcium fluoride. This mixture is fluorinated with fluorine and an inert diluent gas, also in a fluidized bed, and the uranium hexafluoride obtained is finally purified by fractional distillation.

Lawroski, S.; Jonke, A.A.; Steunenberg, R.K.

1959-10-01T23:59:59.000Z

14

Refurbishment of uranium hexafluoride cylinder storage yards C-745-K, L, M, N, and P and construction of a new uranium hexafluoride cylinder storage yard (C-745-T) at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

Science Conference Proceedings (OSTI)

The Paducah Gaseous Diffusion Plant (PGDP) is a uranium enrichment facility owned by the US Department of Energy (DOE). A residual of the uranium enrichment process is depleted uranium hexafluoride (UF6). Depleted UF6, a solid at ambient temperature, is stored in 32,200 steel cylinders that hold a maximum of 14 tons each. Storage conditions are suboptimal and have resulted in accelerated corrosion of cylinders, increasing the potential for a release of hazardous substances. Consequently, the DOE is proposing refurbishment of certain existing yards and construction of a new storage yard. This environmental assessment (EA) evaluates the impacts of the proposed action and no action and considers alternate sites for the proposed new storage yard. The proposed action includes (1) renovating five existing cylinder yards; (2) constructing a new UF6 storage yard; handling and onsite transport of cylinders among existing yards to accommodate construction; and (4) after refurbishment and construction, restacking of cylinders to meet spacing and inspection requirements. Based on the results of the analysis reported in the EA, DOE has determined that the proposed action is not a major Federal action that would significantly affect the quality of the human environment within the context of the National Environmental Policy Act of 1969. Therefore, DOE is issuing a Finding of No Significant Impact. Additionally, it is reported in this EA that the loss of less than one acre of wetlands at the proposed project site would not be a significant adverse impact.

NONE

1996-07-01T23:59:59.000Z

15

FAQ 20-How is uranium hexafluoride being managed now?  

NLE Websites -- All DOE Office Websites (Extended Search)

being managed now? How is uranium hexafluoride being managed now? Since 1990, DOE has conducted a program of cylinder inspections, recoatings, and relocations to assure that...

16

Uranium hexafluoride handling. Proceedings  

SciTech Connect

The United States Department of Energy, Oak Ridge Field Office, and Martin Marietta Energy Systems, Inc., are co-sponsoring this Second International Conference on Uranium Hexafluoride Handling. The conference is offered as a forum for the exchange of information and concepts regarding the technical and regulatory issues and the safety aspects which relate to the handling of uranium hexafluoride. Through the papers presented here, we attempt not only to share technological advances and lessons learned, but also to demonstrate that we are concerned about the health and safety of our workers and the public, and are good stewards of the environment in which we all work and live. These proceedings are a compilation of the work of many experts in that phase of world-wide industry which comprises the nuclear fuel cycle. Their experience spans the entire range over which uranium hexafluoride is involved in the fuel cycle, from the production of UF{sub 6} from the naturally-occurring oxide to its re-conversion to oxide for reactor fuels. The papers furnish insights into the chemical, physical, and nuclear properties of uranium hexafluoride as they influence its transport, storage, and the design and operation of plant-scale facilities for production, processing, and conversion to oxide. The papers demonstrate, in an industry often cited for its excellent safety record, continuing efforts to further improve safety in all areas of handling uranium hexafluoride. Selected papers were processed separately for inclusion in the Energy Science and Technology Database.

Not Available

1991-12-31T23:59:59.000Z

17

PROCESS FOR MAKING URANIUM HEXAFLUORIDE  

DOE Patents (OSTI)

A process is described for producing uranium hexafluoride by reacting uranium hexachloride with hydrogen fluoride at a temperature below about 150 deg C, under anhydrous conditions.

Rosen, R.

1959-07-14T23:59:59.000Z

18

Overview of Depleted Uranium Hexafluoride Management Program  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE's DUF DOE's DUF 6 Cylinder Inventory a Location Number of Cylinders DUF 6 (MT) b Paducah, Kentucky 36,910 450,000 Portsmouth, Ohio 16,041 198,000 Oak Ridge (ETTP), Tennessee 4,683 56,000 Total 57,634 704,000 a The DOE inventory includes DUF 6 generated by the government, as well as DUF 6 transferred from U.S. Enrichment Corporation pursuant to two memoranda of agreement. b A metric ton (MT) is equal to 1,000 kilograms, or 2,200 pounds. Overview of Depleted Uranium Hexafluoride Management Program Over the last four decades, large quantities of uranium were processed by gaseous diffusion to produce enriched uranium for U.S. national defense and civilian purposes. The gaseous diffusion process uses uranium in the form of uranium hexafluoride (UF 6 ), primarily because UF 6 can conveniently be used in

19

PRODUCTION OF URANIUM HEXAFLUORIDE  

DOE Patents (OSTI)

A process for the production of uranium hexafluoride from the oxides of uranium is reported. In accordance with the method, the higher oxides of uranium may be reduced to uranium dioxide (UO/sub 2/), the latter converted into uranium tetrafluoride by reaction with hydrogen fluoride, and the UF/sub 4/ converted to UF/sub 6/ by reaction with a fluorinating agent, such as CoF/sub 3/. The UO/sub 3/ or U/sub 3/O/sub 8/ is placed in a reac tion chamber in a copper boat or tray enclosed in a copper oven, and heated to 500 to 650 deg C while hydrogen gas is passed through the oven. After nitrogen gas is used to sweep out the hydrogen and the water vapor formed, and while continuing to inaintain the temperature between 400 deg C and 600 deg C, anhydrous hydrogen fluoride is passed through. After completion of the conversion of UO/sub 2/ to UF/sub 4/ the temperature of the reaction chamber is lowered to about 400 deg C or less, the UF/sub 4/ is mixed with the requisite quantity of CoF/sub 3/, and after evacuating the chamber, the mixture is heated to 300 to 400 deg C, and the resulting UF/sub 6/ is led off and delivered to a condenser.

Fowler, R.D.

1957-08-27T23:59:59.000Z

20

FAQ 11-What are the properties of uranium hexafluoride?  

NLE Websites -- All DOE Office Websites (Extended Search)

properties of uranium hexafluoride? What are the properties of uranium hexafluoride? Uranium hexafluoride can be a solid, liquid, or gas, depending on its temperature and pressure....

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Depleted Uranium Hexafluoride Management  

NLE Websites -- All DOE Office Websites (Extended Search)

for for DUF 6 Conversion Project Environmental Impact Statement Scoping Meetings November/December 2001 Overview Depleted Uranium Hexafluoride (DUF 6 ) Management Program DUF 6 EIS Scoping Briefing 2 DUF 6 Management Program Organizational Chart DUF 6 Management Program Organizational Chart EM-10 Policy EM-40 Project Completion EM-20 Integration EM-50 Science and Technology EM-31 Ohio DUF6 Management Program EM-32 Oak Ridge EM-33 Rocky Flats EM-34 Small Sites EM-30 Office of Site Closure Office of Environmental Management EM-1 DUF 6 EIS Scoping Briefing 3 DUF 6 Management Program DUF 6 Management Program * Mission: Safely and efficiently manage the DOE inventory of DUF 6 in a way that protects the health and safety of workers and the public, and protects the environment DUF 6 EIS Scoping Briefing 4 DUF 6 Inventory Distribution

22

Video: The Depleted Uranium Hexafluoride Story  

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Depleted UF6 Story The Depleted Uranium Hexafluoride Story An overview of Uranium, its isotopes, the need and history of diffusive separation, the handling of the Depleted Uranium...

23

Video: Metamorphosis (Physical Characteristics of Uranium Hexafluoride)  

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Metamorphosis Metamorphosis Metamorphosis (Physical Characteristics of Uranium Hexafluoride) The Uranium Hexafluoride phase diagram is investigated. An experimental setup is shown to look at the gas, liquid, and solid phases at various temperatures and pressures. This information is used to understand what happens inside a DUF6 storage cylinder. View this Video in Real Player format Download free RealPlayer SP Highlights of the Video: Video 00:12 Metamorphosis from the U.S. Department of Energy Video 00:45 Laboratory setup to examine the phases of UF6 Video 01:45 UF6 Phase Diagram Video 03:25 Liquid UF6 appearing in a glass tube Video 03:38 Cloud of HF from moisture reaction dissolving in UF6 gas Video 04:27 Beginning of UF6 phase change from liquid to solid Video 04:40 Formation of porous solid structure

24

Uranium hexafluoride public risk  

SciTech Connect

The limiting value for uranium toxicity in a human being should be based on the concentration of uranium (U) in the kidneys. The threshold for nephrotoxicity appears to lie very near 3 {mu}g U per gram kidney tissue. There does not appear to be strong scientific support for any other improved estimate, either higher or lower than this, of the threshold for uranium nephrotoxicity in a human being. The value 3 {mu}g U per gram kidney is the concentration that results from a single intake of about 30 mg soluble uranium by inhalation (assuming the metabolism of a standard person). The concentration of uranium continues to increase in the kidneys after long-term, continuous (or chronic) exposure. After chronic intakes of soluble uranium by workers at the rate of 10 mg U per week, the concentration of uranium in the kidneys approaches and may even exceed the nephrotoxic limit of 3 {mu}g U per gram kidney tissue. Precise values of the kidney concentration depend on the biokinetic model and model parameters assumed for such a calculation. Since it is possible for the concentration of uranium in the kidneys to exceed 3 {mu}g per gram tissue at an intake rate of 10 mg U per week over long periods of time, we believe that the kidneys are protected from injury when intakes of soluble uranium at the rate of 10 mg U per week do not continue for more than two consecutive weeks. For long-term, continuous occupational exposure to low-level, soluble uranium, we recommend a reduced weekly intake limit of 5 mg uranium to prevent nephrotoxicity in workers. Our analysis shows that the nephrotoxic limit of 3 {mu}g U per gram kidney tissues is not exceeded after long-term, continuous uranium intake at the intake rate of 5 mg soluble uranium per week.

Fisher, D.R.; Hui, T.E.; Yurconic, M.; Johnson, J.R.

1994-08-01T23:59:59.000Z

25

Health Effects Associated with Uranium Hexafluoride (UF6)  

NLE Websites -- All DOE Office Websites (Extended Search)

Hexafluoride (UF6) UF6 Health Effects Uranium Hexafluoride (UF6) line line Properties of UF6 UF6 Health Effects Health Effects Associated with Uranium Hexafluoride (UF6) Uranium...

26

Audit Report on "Depleted Uranium Hexafluoride Conversion," DOE...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Marketing Administration Other Agencies You are here Home Audit Report on "Depleted Uranium Hexafluoride Conversion," DOEIG-0642 Audit Report on "Depleted Uranium Hexafluoride...

27

Follow-up of Depleted Uranium Hexafluoride Conversion, IG-0751...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Marketing Administration Other Agencies You are here Home Follow-up of Depleted Uranium Hexafluoride Conversion, IG-0751 Follow-up of Depleted Uranium Hexafluoride...

28

FAQ 12-What are the hazards associated with uranium hexafluoride...  

NLE Websites -- All DOE Office Websites (Extended Search)

hazards associated with uranium hexafluoride? What are the hazards associated with uranium hexafluoride? The characteristics of UF6 pose potential health risks, and the material is...

29

PROCESS FOR PRODUCING URANIUM HEXAFLUORIDE  

DOE Patents (OSTI)

A process for the production of uranium hexafluoride from the oxides of uranium is reported. In accordance with the method the higher oxides of uranium may be reduced to uranium dioxide (UO/sub 2/), the latter converted into uranium tetrafluoride by reaction with hydrogen fluoride, and the UF/sub 4/ convented to UF/sub 6/ by reaction with a fluorinating agent. The UO/sub 3/ or U/sub 3/O/sub 8/ is placed in a reaction chamber in a copper boat or tray enclosed in a copper oven, and heated to 500 to 650 deg C while hydrogen gas is passed through the oven. The oven is then swept clean of hydrogen and the water vapor formed by means of nitrogen and then while continuing to maintain the temperature between 400 and 600 deg C, anhydrous hydrogen fluoride is passed through. After completion of the conversion to uranium tetrafluoride, the temperature of the reaction chamber is lowered to ahout 400 deg C, and elemental fluorine is used as the fluorinating agent for the conversion of UF/sub 4/ into UF/sub 6/. The fluorine gas is passed into the chamber, and the UF/sub 6/ formed passes out and is delivered to a condenser.

Fowler, R.D.

1957-10-22T23:59:59.000Z

30

FAQ 9-Where does uranium hexafluoride come from?  

NLE Websites -- All DOE Office Websites (Extended Search)

hexafluoride come from? Where does uranium hexafluoride come from? The gaseous diffusion process used to enrich uranium requires uranium in the form of UF6. In the first step of...

31

PROCESS FOR PRODUCTION OF URANIUM HEXAFLUORIDE  

DOE Patents (OSTI)

A process is described for the manufacture of uranium bexafluoride which consists in contacting an oxide of uranium simultaneously with elemental carbon and elemental fluorine at an elevated temperature, using a proportion of the carbon to the oxide about 50% in excess of that theoretically required to combine with f the oxygen as C0/.sub 2/. The process has the advantage that the uranium oxide is reduced by tbe carbon aad converted to the hexafluoride in a single operation.

Fowler, R.D.

1958-11-01T23:59:59.000Z

32

Transportation Impact Assessment for Shipment of Uranium Hexafluoride (UF<sub>6</sub>) Cylinders from the East Tennessee Technology Park to the Portsmouth and Paducah Gaseous Diffusion  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 Transportation Impact Assessment for Shipment of Uranium Hexafluoride (UF 6 ) Cylinders from the East Tennessee Technology Park to the Portsmouth and Paducah Gaseous Diffusion Plants Environmental Assessment Division Argonne National Laboratory Operated by The University of Chicago, under Contract W-31-109-Eng-38, for the United States Department of Energy Argonne National Laboratory Argonne National Laboratory, with facilities in the states of Illinois and Idaho, is owned by the United States Government and operated by The University of Chicago under the provisions of a contract with the Department of Energy. This technical memorandum is a product of Argonne's Environmental Assessment Division (EAD). For information on the division's scientific and engineering

33

FAQ 16-How much depleted uranium hexafluoride is stored in the United  

NLE Websites -- All DOE Office Websites (Extended Search)

How much depleted uranium hexafluoride is stored in the United States? How much depleted uranium hexafluoride is stored in the United States? How much depleted uranium hexafluoride is stored in the United States? U.S. DOE's inventory of depleted UF6 consists of approximately 700,000 metric tons of depleted UF6, containing about 470,000 metric tons of uranium, currently stored at the Paducah Site in Kentucky, the Portsmouth Site in Ohio, and the East Tennessee Technology Park (ETTP) in Tennessee (formerly known as the K-25 Site). This inventory of depleted UF6 is stored in about 57,000 steel cylinders. The inventory is listed in the table below. DOE Inventory of Depleted UF6 Location Total Cylinders Total Depleted UF6 (metric tons) Paducah, Kentucky 36,191 436,400 Portsmouth, Ohio 16,109 195,800 Oak Ridge, Tennessee 4,822 54,300

34

REDUCTION OF URANIUM HEXAFLUORIDE RETENTION ON BEDS OF MAGNESIUM FLUORIDE USED FOR REMOVAL OF TECHNETIUM HEXAFLUORIDE  

SciTech Connect

The excessive loss of uranium incurred when discarding magnesium fluoride, (the adsorber used to selectively remove technetium hexafluoride from uranium hexafluoride streams) is a problem common to all volatility processes for recovering enriched uranium fuels. As a result of the work described, two schemes for the release of the uranium hexafluoride from the magnesium fluoride and its separation from the technetium hexafluoride are proposed. One scheme depends on preferential thermal desorption of the uranium hexafluoride at 350 deg C and the other on selective adsorption of the uranium hexafluoride on sodium fluoride pellets following the codesorption of the two hexafluorides with fluorine at 500 deg C from the magnesium fluoride pellets. These proposals are aimed at reducing the amount of retained uranium to less than 1 g per 1000 g of discardable magnesium fluoride. In the work reported, the deposition of uranium on magnesium fluoride as a function of heating, fluorination, and hydrogen fluoride pretreatment of the magnesium fluoride pellets prior to exposure to uranium hexafluoride was characterized in a series of gasometric studies. The dependence of the quantity of uranium hexafluoride adsorbed on pressure and temperature was also determined. The data show that physical adsorption is the mechanism for the deposition of most of the uranium hexafluoride on well- stabilized magnesium fluoride pellets. More than 90% of the adsorbate can be removed by heating to 350 deg C. Chemisorption (formation of a double salt) is probably not involved because of the small (<0.05) mole ratio of UF/sub 6//MgF/ sub 2/ observed. (auth)

Katz, S.

1964-01-31T23:59:59.000Z

35

Press Release: DOE Seeks Public Input for Depleted Uranium Hexafluorid...  

NLE Websites -- All DOE Office Websites (Extended Search)

Perry, (865) 576-0885 September 24, 2001 www.oakridge.doe.gov DOE SEEKS PUBLIC INPUT FOR DEPLETED URANIUM HEXAFLUORIDE ENVIRONMENTAL IMPACT STATEMENT Public Meetings Planned in...

36

FAQ 8-What is uranium hexafluoride (UF6)?  

NLE Websites -- All DOE Office Websites (Extended Search)

is uranium hexafluoride (UF6)? is uranium hexafluoride (UF6)? What is uranium hexafluoride (UF6)? Uranium hexafluoride is a chemical compound consisting of one atom of uranium combined with six atoms of fluorine. It is the chemical form of uranium that is used during the uranium enrichment process. Within a reasonable range of temperature and pressure, it can be a solid, liquid, or gas. Solid UF6 is a white, dense, crystalline material that resembles rock salt. Liquid UF6 is formed only at temperatures greater than 147° F (64° C) and at pressures greater than 1.5 times atmospheric pressure (22 psia). At atmospheric pressure, solid UF6 will transform directly to UF6 gas (sublimation) when the temperature is raised to 134° F (57° C), without going through a liquid phase.

37

Summary of the engineering analysis report for the long-term management of depleted uranium hexafluoride  

SciTech Connect

The Department of Energy (DOE) is reviewing ideas for the long-term management and use of its depleted uranium hexafluoride. DOE owns about 560,000 metric tons (over a billion pounds) of depleted uranium hexafluoride. This material is contained in steel cylinders located in storage yards near Paducah, Kentucky; Portsmouth, Ohio; and at the East Tennessee Technology Park (formerly the K-25 Site) in Oak Ridge, Tennessee. On November 10, 1994, DOE announced its new Depleted Uranium Hexafluoride Management Program by issuing a Request for Recommendations and an Advance Notice of Intent in the Federal Register (59 FR 56324 and 56325). The first part of this program consists of engineering, costs and environmental impact studies. Part one will conclude with the selection of a long-term management plan or strategy. Part two will carry out the selected strategy.

Dubrin, J.W., Rahm-Crites, L.

1997-09-01T23:59:59.000Z

38

EIS-0359: Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

59: Uranium Hexafluoride Conversion Facility at the Paducah, 59: Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky Site EIS-0359: Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky Site Summary This site-specific EIS considers the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three locations within the Paducah site; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as a conversion co-product; and neutralization of HF to calcium fluoride and its sale or disposal in the event that the HF product is not sold. This EIS also considers a no action alternative that assumes continued storage of DUF6 at the Paducah site. A

39

DOE Issues Request for Quotations for Depleted Uranium Hexafluoride  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Issues Request for Quotations for Depleted Uranium Hexafluoride Issues Request for Quotations for Depleted Uranium Hexafluoride Conversion Technical Services DOE Issues Request for Quotations for Depleted Uranium Hexafluoride Conversion Technical Services December 12, 2012 - 12:00pm Addthis Media Contact Bill Taylor, 803-952-8564 bill.taylor@srs.gov Cincinnati - The U.S. Department of Energy (DOE) today issued a Request for Quotation (RFQ) for engineering and operations technical services to support the Portsmouth Paducah Project Office and the oversight of operations of the Depleted Uranium Hexafluoride (DUF6) Conversion Project located in Paducah KY, and Portsmouth OH. The RFQ is for a Time-and-Materials Task Order for three years with two one-year option periods. The estimated contract value is approximately $15 - 20 million.

40

DOE Issues Request for Quotations for Depleted Uranium Hexafluoride  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Issues Request for Quotations for Depleted Uranium Hexafluoride Issues Request for Quotations for Depleted Uranium Hexafluoride Conversion Technical Services DOE Issues Request for Quotations for Depleted Uranium Hexafluoride Conversion Technical Services December 12, 2012 - 12:00pm Addthis Media Contact Bill Taylor, 803-952-8564 bill.taylor@srs.gov Cincinnati - The U.S. Department of Energy (DOE) today issued a Request for Quotation (RFQ) for engineering and operations technical services to support the Portsmouth Paducah Project Office and the oversight of operations of the Depleted Uranium Hexafluoride (DUF6) Conversion Project located in Paducah KY, and Portsmouth OH. The RFQ is for a Time-and-Materials Task Order for three years with two one-year option periods. The estimated contract value is approximately $15 - 20 million.

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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41

Moderation control in low enriched {sup 235}U uranium hexafluoride packaging operations and transportation  

Science Conference Proceedings (OSTI)

Moderation control is the basic parameter for ensuring nuclear criticality safety during the packaging and transport of low {sup 235}U enriched uranium hexafluoride before its conversion to nuclear power reactor fuel. Moderation control has permitted the shipment of bulk quantities in large cylinders instead of in many smaller cylinders and, therefore, has resulted in economies without compromising safety. Overall safety and uranium accountability have been enhanced through the use of the moderation control. This paper discusses moderation control and the operating procedures to ensure that moderation control is maintained during packaging operations and transportation.

Dyer, R.H. [USDOE Oak Ridge Operations Office, TN (United States); Kovac, F.M. [Oak Ridge National Lab., TN (United States); Pryor, W.A. [PAI Corp., Oak Ridge, TN (United States)

1993-10-01T23:59:59.000Z

42

Including environmental concerns in management strategies for depleted uranium hexafluoride  

Science Conference Proceedings (OSTI)

One of the major programs within the Office of Nuclear Energy, Science, and Technology of the US Department of Energy (DOE) is the depleted uranium hexafluoride (DUF{sub 6}) management program. The program is intended to find a long-term management strategy for the DUF{sub 6} that is currently stored in approximately 46,400 cylinders at Paducah, KY; Portsmouth, OH; and Oak Ridge, TN, USA. The program has four major components: technology assessment, engineering analysis, cost analysis, and the environmental impact statement (EIS). From the beginning of the program, the DOE has incorporated the environmental considerations into the process of strategy selection. Currently, the DOE has no preferred alternative. The results of the environmental impacts assessment from the EIS, as well as the results from the other components of the program, will be factored into the strategy selection process. In addition to the DOE`s current management plan, other alternatives continued storage, reuse, or disposal of depleted uranium, will be considered in the EIS. The EIS is expected to be completed and issued in its final form in the fall of 1997.

Goldberg, M. [Argonne National Laboratory, Washington, DC (United States); Avci, H.I. [Argonne National Lab., IL (United States); Bradley, C.E. [USDOE, Washington, DC (United States)

1995-12-31T23:59:59.000Z

43

FAQ 22-What is going to happen to the uranium hexafluoride stored...  

NLE Websites -- All DOE Office Websites (Extended Search)

going to happen to the uranium hexafluoride stored in the United States? What is going to happen to the uranium hexafluoride stored in the United States? The DOE has been...

44

FAQ 17-Where is uranium hexafluoride stored in the United States...  

NLE Websites -- All DOE Office Websites (Extended Search)

Where is uranium hexafluoride stored in the United States? Where is uranium hexafluoride stored in the United States? Most of the depleted UF6 accumulated since the 1940s is stored...

45

RADIATION EFFECTS OF ALPHA PARTICLES ON URANIUM HEXAFLUORIDE  

SciTech Connect

Alpha irradiation of uranium hexafluoride results in the formation of fluorine and intermediate, solid uranium fluorides: these products react with each other, apparently by a radiation-induced process. to reform uranium hexifluoride. The number of molecules of uranium hexafluoride decomposed, excluding recombiapproximately 1 in the temperature range 21 to 87 deg C. Irradiation of a mixture of fluorine and uranium hexafluoride in a vessel containing uranium fluorides substantistes the postulated mechanism. At fluorine pressures of 50 to 100 mm Hg, there is an increase, rather than a decrease, in uranium hexafluoride pressure. Rates of both decomposition and recombination processes appear to depend only on the rates of radiation energy absorption. Equations formnulated to describe the combined decomposition and reformation reactions can be used to calculate equilibrium concentrations of uranium hexfluoride and fluorine when the intensity of the radiation source is defined. The effects of three diluent gases, helium, nitrogen and oxygen, were studied in an attempt to find possible electron transfer processes. (auth)

Bernhardt, H.A.; Davis, W. Jr.; Shiflett, C.H.

1958-06-01T23:59:59.000Z

46

Uranium hexafluoride: A manual of good handling practices. Revision 7  

SciTech Connect

The United States Enrichment Corporation (USEC) is continuing the policy of the US Department of Energy (DOE) and its predecessor agencies in sharing with the nuclear industry their experience in the area of uranium hexafluoride (UF{sub 6}) shipping containers and handling procedures. The USEC has reviewed Revision 6 or ORO-651 and is issuing this new edition to assure that the document includes the most recent information on UF{sub 6} handling procedures and reflects the policies of the USEC. This manual updates the material contained in earlier issues. It covers the essential aspects of UF{sub 6} handling, cylinder filling and emptying, general principles of weighing and sampling, shipping, and the use of protective overpacks. The physical and chemical properties of UF{sub 6} are also described. The procedures and systems described for safe handling of UF{sub 6} presented in this document have been developed and evaluated during more than 40 years of handling vast quantities of UF{sub 6}. With proper consideration for its nuclear properties, UF{sub 6} may be safely handled in essentially the same manner as any other corrosive and/or toxic chemical.

NONE

1995-01-01T23:59:59.000Z

47

Containment and storage of uranium hexafluoride at US Department of Energy uranium enrichment plants  

Science Conference Proceedings (OSTI)

Isotopically depleted UF{sub 6} (uranium hexafluoride) accumulates at a rate five to ten times greater than the enriched product and is stored in steel vessels at the enrichment plant sites. There are approximately 55,000 large cylinders now in storage at Paducah, Kentucky; Portsmouth, Ohio; and Oak Ridge, Tennessee. Most of them contain a nominal 14 tons of depleted UF{sub 6}. Some of these cylinders have been in the unprotected outdoor storage environment for periods approaching 40 years. Storage experience, supplemented by limited corrosion data, suggests a service life of about 70 years under optimum conditions for the 48-in. diameter, 5/16-in.-wall pressure vessels (100 psi working pressure), using a conservative industry-established 1/4-in.-wall thickness as the service limit. In the past few years, however, factors other than atmospheric corrosion have become apparent that adversely affect the serviceability of small numbers of the storage containers and that indicate the need for a managed program to ensure maintenance ofcontainment integrity for all the cylinders in storage. The program includes periodic visual inspections of cylinders and storage yards with documentation for comparison with other inspections, a group of corrosion test programs to permit cylinder life forecasts, and identification of (and scheduling for remedial action) situations in which defects, due to handling damage or accelerated corrosion, can seriously shorten the storage life or compromise the containment integrity of individual cylinders. The program also includes rupture testing to assess the effects of certain classes of damage on overall cylinder strength, aswell as ongoing reviews of specifications, procedures, practices, and inspection results to effect improvements in handling safety, containment integrity, and storage life.

Barlow, C.R.; Alderson, J.H.; Blue, S.C.; Boelens, R.A.; Conkel, M.E.; Dorning, R.E.; Ecklund, C.D.; Halicks, W.G.; Henson, H.M.; Newman, V.S.; Philpot, H.E.; Taylor, M.S.; Vournazos, J.P. [Oak Ridge K-25 Site, TN (United States). UEO Enrichment Technical Operations Div.; Russell, J.R. [USDOE Oak Ridge Field Office, TN (United States); Pryor, W.A. [PAI Corp., Oak Ridge, TN (United States); Ziehlke, K.T. [MJB Technical Associates (United States)

1992-07-01T23:59:59.000Z

48

A PILOT PLANT FOR THE REDUCTION OF URANIUM HEXAFLUORIDE TO URANIUM TETRAFLUORIDE WITH TRICHLOROETHYLENE  

SciTech Connect

Pilot plant experiments are described in which trichloroethylene was used for the reduction of uranium hexafluoride to uranium tetrafluoride. After unsatisfactory preliminary results with liquid phase reduction, satisfactory results were obtained with a vapor phase reduction system. It was found that vapor phase reduction at approximately 450 deg F, produced a low density product which contained only small quantities of uranium(VI); sintering the uranium tetrafluoride in a hydrogen fluoride atmosphere increased the product density to approximately 3 g/cc. The reduction was essentially complete, and the effluent gas contained less than 1 ppm of uranium hexafluoride. The purity of the uranium tetrafluoride produced was equivalent to that of the uranium hexafluoride used as feed. A complete discussion is given of the operation of the various parts of the system. (auth)

Baker, J.E.; Klaus, H.V.; Schmidt, R.A.; Smiley, S.H.

1956-05-31T23:59:59.000Z

49

Depleted Uranium Hexafluoride Management Program: Data Compilation...  

NLE Websites -- All DOE Office Websites (Extended Search)

Impacts Associated with Continued Storage of the Entire Portsmouth Site Cylinder Inventory . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-51 3.5.1 Approach Used to...

50

In-line assay monitor for uranium hexafluoride  

DOE Patents (OSTI)

An in-line assay monitor for determining the content of uranium-235 in a uranium hexafluoride gas isotopic separation system is provided which removes the necessity of complete access to the operating parameters of the system for determining the uranium-235 content. The method and monitor for carrying out the method involve cooling of a radiation pervious chamber connected in fluid communication with the selected point in the system to withdraw a specimen and solidify the specimen in the chamber. The specimen is irradiated by means of an ionizing radiation source of energy different from that of the 185 keV gamma emissions from uranium-235. The uranium-235 content of the specimen is determined from comparison of the accumulated 185 keV energy counts and reference energy counts. The latter is used to measure the total uranium isotopic content of the specimen.

Wallace, S.A.

1980-03-21T23:59:59.000Z

51

FAQ 13-How is uranium hexafluoride stored?  

NLE Websites -- All DOE Office Websites (Extended Search)

atmospheric pressure in the top. The UF6 inside the cylinder combines with the iron on the inner surfaces to form a surface layer of iron fluoride that inhibits internal corrosion...

52

Production and Handling Slide 38: 48G Depleted UF6 Storage Cylinder  

NLE Websites -- All DOE Office Websites (Extended Search)

48G Depleted UF6 Storage Cylinder Refer to caption below for image description After enrichment, depleted uranium hexafluoride is placed in large steel cylinders for storage....

53

Depleted Uranium Hexafluoride Management Program: Data Compilation for the Paducah Site  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 Depleted Uranium Hexafluoride Management Program: Data Compilation for the Paducah Site in Support of Site-Specific NEPA Requirements for Continued Cylinder Storage, Cylinder Preparation, Conversion, and Long-Term Storage Activities Environmental Assessment Division Argonne National Laboratory Operated by The University of Chicago, under Contract W-31-109-Eng-38, for the United States Department of Energy Argonne National Laboratory Argonne National Laboratory, with facilities in the states of Illinois and Idaho, is owned by the United States Government and operated by The University of Chicago under the provisions of a contract with the Department of Energy. This technical memorandum is a product of Argonne's Environmental Assessment Division (EAD). For information on the division's scientific and engineering

54

In-line assay monitor for uranium hexafluoride  

DOE Patents (OSTI)

An in-line assay monitor for determining the content of uranium-235 in a uranium hexafluoride gas isotopic separation system is provided which removes the necessity of complete access to the operating parameters of the system for determining the uranium-235 content. The monitor is intended for uses such as safeguard applications to assure that weapons grade uranium is not being produced in an enrichment cascade. The method and monitor for carrying out the method involve cooling of a radiation pervious chamber connected in fluid communication with the selected point in the system to withdraw a specimen and solidify the specimen in the chamber. The specimen is irradiated by means of an ionizing radiation source of energy different from that of the 185 keV gamma emissions from the uranium-235 present in the specimen. Simultaneously, the gamma emissions from the uranium-235 of the specimen and the source emissions transmitted through the sample are counted and stored in a multiple channel analyzer. The uranium-235 content of the specimen is determined from the comparison of the accumulated 185 keV energy counts and the reference energy counts. The latter is used to measure the total uranium isotopic content of the specimen. The process eliminates the necessity of knowing the system operating conditions and yet obtains the necessary data without need for large scintillation crystals and sophisticated mechanical designs.

Wallace, Steven A. (Knoxville, TN)

1981-01-01T23:59:59.000Z

55

Selection of a management strategy for depleted uranium hexafluoride  

Science Conference Proceedings (OSTI)

A consequence of the uranium enrichment process used in the United States (US) is the accumulation of a significant amount of depleted uranium hexafluoride (UF{sub 6}). Currently, approximately 560,000 metric tons of the material are stored at three different sites. The US Department of Energy (DOE) has recently initiated a program to consider alternative strategies for the cost-effective and environmentally safe long-term management of this inventory of depleted UF{sub 6}. The program involves a technology and engineering assessment of proposed management options (use/reuse, conversion, storage, or disposal) and an analysis of the potential environmental impacts and life-cycle costs of alternative management strategies. The information obtained from the studies will be used by the DOE to select a preferred long-term management strategy. The selection and implementation of a management strategy will involve consideration of a number of important issues such as environmental, health, and safety effects; the balancing of risks versus costs in a context of reduced government spending; socioeconomic implications, including effects on the domestic and international uranium industry; the technical status of proposed uses or technologies; and public involvement in the decision making process. Because of its provisions for considering a wide range of relevant issues and involving the public, this program has become a model for future DOE materials disposition programs. This paper presents an overview of the Depleted Uranium Hexafluoride Management Program. Technical findings of the program to date are presented, and major issues involved in selecting and implementing a management strategy are discussed.

Patton, S.E.; Hanrahan, E.J.; Bradley, C.E.

1995-09-06T23:59:59.000Z

56

Depleted uranium hexafluoride (DUF{sub 6}) management system--a decision tool  

Science Conference Proceedings (OSTI)

The Depleted Uranium Hexafluoride (DUF{sub 6}) Management System (DMS) is being developed as a decision tool to provide cost and risk data for evaluation of short-and long-term management strategies for depleted uranium. It can be used to assist decision makers on a programmatic or site-specific level. Currently, the DMS allows evaluation of near-term cylinder management strategies such as storage yard improvements, cylinder restocking, and reconditioning. The DMS has been designed to provide the user with maximum flexibility for modifying data and impact factors (e.g., unit costs and risk factors). Sensitivity analysis can be performed on all key parameters such as cylinder corrosion rate, inspection frequency, and impact factors. Analysis may be conducted on a system-wide, site, or yard basis. The costs and risks from different scenarios may be compared in graphic or tabular format. Ongoing development of the DMS will allow similar evaluation of long-term management strategies such as conversion to other chemical forms. The DMS is a Microsoft Windows 3.1 based, stand-alone computer application. It can be operated on a 486 or faster computer with VGA, 4 MB of RAM, and 10 MB of disk space.

Gasper, J.R.; Sutter, R.J.; Avci, H.I. [and others

1995-12-31T23:59:59.000Z

57

Conversion of depleted uranium hexafluoride to a solid uranium compound  

DOE Patents (OSTI)

A process for converting UF.sub.6 to a solid uranium compound such as UO.sub.2 and CaF. The UF.sub.6 vapor form is contacted with an aqueous solution of NH.sub.4 OH at a pH greater than 7 to precipitate at least some solid uranium values as a solid leaving an aqueous solution containing NH.sub.4 OH and NH.sub.4 F and remaining uranium values. The solid uranium values are separated from the aqueous solution of NH.sub.4 OH and NH.sub.4 F and remaining uranium values which is then diluted with additional water precipitating more uranium values as a solid leaving trace quantities of uranium in a dilute aqueous solution. The dilute aqueous solution is contacted with an ion-exchange resin to remove substantially all the uranium values from the dilute aqueous solution. The dilute solution being contacted with Ca(OH).sub.2 to precipitate CaF.sub.2 leaving dilute NH.sub.4 OH.

Rothman, Alan B. (Willowbrook, IL); Graczyk, Donald G. (Lemont, IL); Essling, Alice M. (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

2001-01-01T23:59:59.000Z

58

What is going to happen to the uranium hexafluoride stored in...  

NLE Websites -- All DOE Office Websites (Extended Search)

What is going to happen to the uranium hexafluoride stored in the United States? The DOE has been evaluating the alternative strategies for long-term management and use of the...

59

Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio. Revision 1  

SciTech Connect

The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio, is operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy-Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of uranium hexafluoride (UF{sub 6}). Uranium hexafluoride enriched uranium than 1.0 wt percent {sup 235}U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF{sub 6} cylinders/overpacks. Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF{sub 6} packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a team of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the is documented in Reference 4.

Becker, D.L.; Green, D.J.; Lindquist, M.R.

1993-07-01T23:59:59.000Z

60

Record of Decision for Long-term Management and Use of Depleted Uranium Hexafluoride  

NLE Websites -- All DOE Office Websites (Extended Search)

Record of Decision for Long-Term Management and Use of Depleted Uranium Hexafluoride AGENCY: Department of Energy ACTION: Record of Decision SUMMARY: The Department of Energy ("DOE" or "the Department") issued the Final Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride (Final PEIS) on April 23, 1999. DOE has considered the environmental impacts, benefits, costs, and institutional and programmatic needs associated with the management and use of its approximately 700,000 metric tons of depleted uranium hexafluoride (DUF 6 ). DOE has decided to promptly convert the depleted UF 6 inventory to depleted uranium oxide, depleted uranium metal, or a combination of both. The depleted uranium oxide will be

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Preconceptual design studies and cost data of depleted uranium hexafluoride conversion plants  

SciTech Connect

One of the more important legacies left with the Department of Energy (DOE) after the privatization of the United States Enrichment Corporation is the large inventory of depleted uranium hexafluoride (DUF6). The DOE Office of Nuclear Energy, Science and Technology (NE) is responsible for the long-term management of some 700,000 metric tons of DUF6 stored at the sites of the two gaseous diffusion plants located at Paducah, Kentucky and Portsmouth, Ohio, and at the East Tennessee Technology Park in Oak Ridge, Tennessee. The DUF6 management program resides in NE's Office of Depleted Uranium Hexafluoride Management. The current DUF6 program has largely focused on the ongoing maintenance of the cylinders containing DUF6. However, the long-term management and eventual disposition of DUF6 is the subject of a Programmatic Environmental Impact Statement (PEIS) and Public Law 105-204. The first step for future use or disposition is to convert the material, which requires construction and long-term operation of one or more conversion plants. To help inform the DUF6 program's planning activities, it was necessary to perform design and cost studies of likely DUF6 conversion plants at the preconceptual level, beyond the PEIS considerations but not as detailed as required for conceptual designs of actual plants. This report contains the final results from such a preconceptual design study project. In this fast track, three month effort, Lawrence Livermore National Laboratory and Bechtel National Incorporated developed and evaluated seven different preconceptual design cases for a single plant. The preconceptual design, schedules, costs, and issues associated with specific DUF6 conversion approaches, operating periods, and ownership options were evaluated based on criteria established by DOE. The single-plant conversion options studied were similar to the dry-conversion process alternatives from the PEIS. For each of the seven cases considered, this report contains information on the conversion process, preconceptual plant description, rough capital and operating costs, and preliminary project schedule.

Jones, E

1999-07-26T23:59:59.000Z

62

BASIC STUDIES OF THE SEPARATION OF URANIUM HEXAFLUORIDE FROM MIXTURES CONTAINING CHLORINE TRIFLUORIDE AND HYDROGEN FLUORIDE  

SciTech Connect

Processes for the conversion of uranium compounds or uranium metal to uranium hexafluoride ordinarily involve the use of a powerful fluorinating agent. Elemental fluorine is used when the scale of operations justifies the construction of a fluorine generating plant, but for smaller operation the use of the interhalogens of fluorine has definite advantages. These compounds provide a high concentration of fluorinating power at moderate temperatures and pressures and are more easily stored and transported than fluorine. In addition, fluorinations in the liquid phase often proceed more smoothly than those with gaseous fluorine. However, the use of . the interhalogens introduces the problem of separating the uranium hexafluoride from the unreacted reagent and from any by-products which may have been formed. The present work is concerned with the determination of the phase equilibrai among the materials uranium hexafluoride, chlorine trifluoride, and hydrogen fluoride. metal with chlorine trifluoride-hydrogen fluoride solutions or as a result of treating many uranium compounds and ores with chlorine trifluoride. These phase equilibria define the physical conditions necessary for separating the components by the processes of crystallization or distillation and have made possinle the successful Operation of a pilot plant for the direct recovery of uranium hexafluoride from spent metallic uranium fuel elements. (auth)

Bernhardt, H.A.; Barber, E.J.; Davis, W. Jr.; McGill, R.M.

1958-10-31T23:59:59.000Z

63

Standard test methods for chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of uranium hexafluoride  

E-Print Network (OSTI)

1.1 These test methods cover procedures for subsampling and for chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of uranium hexafluoride UF6. Most of these test methods are in routine use to determine conformance to UF6 specifications in the Enrichment and Conversion Facilities. 1.2 The analytical procedures in this document appear in the following order: Note 1Subcommittee C26.05 will confer with C26.02 concerning the renumbered section in Test Methods C761 to determine how concerns with renumbering these sections, as analytical methods are replaced with stand-alone analytical methods, are best addressed in subsequent publications. Sections Subsampling of Uranium Hexafluoride 7 - 10 Gravimetric Determination of Uranium 11 - 19 Titrimetric Determination of Uranium 20 Preparation of High-Purity U3O 8 21 Isotopic Analysis 22 Isotopic Analysis by Double-Standard Mass-Spectrometer Method 23 - 29 Determination of Hydrocarbons, Chlorocarbons, and Partially Substitut...

American Society for Testing and Materials. Philadelphia

2011-01-01T23:59:59.000Z

64

DEVELOPMENT OF THE CONTINUOUS METHOD FOR THE REDUCTION OF URANIUM HEXAFLUORIDE WITH HYDROGEN-PROCESS DEVELOPMENT. HOT WALL REACTOR  

DOE Green Energy (OSTI)

>A continuous process for the reduction of uranium hexafluoride to uranium tetrafluoride was developed and proved on a pilot-plant scale. Complete conversion to uranium tetrafluoride was realized by contacting gaseous uranium hexafluoride with hydrogen in a heated, vertical, open-tube reactor. The purity and density of the solid product met metal grade uranium tetrafluoride specifications. Some difficulty with the accumulation of fused uranium fluorides in the tower was encountered, however, and it was necessary to stop and desing the unit about every 8 to 24 hours. The reaction of uranium hexafluoride with gaseous trichloroethylene was stadied before the tests with hydrogen were made. Although the reduction to uranium tetrafluoride was complete, the solid product was highly contaminated with the organic by-products of the reaction and was quite low in density. Tests of this method were discontinued when promising results were obtained with hydrogen as the reductant. (auth)

Smiley, S H; Brater, D C

1958-06-27T23:59:59.000Z

65

uranium hexafluoride - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA)

Uranium fuel, nuclear reactors, generation, spent fuel. Total Energy. ... UF 6 is the form of uranium required for the enrichment process. Thank You.

66

Cost update technology, safety, and costs of decommissioning a reference uranium hexafluoride conversion plant  

Science Conference Proceedings (OSTI)

The purpose of this study is to update the cost estimates developed in a previous report, NUREG/CR-1757 (Elder 1980) for decommissioning a reference uranium hexafluoride conversion plant from the original mid-1981 dollars to values representative of January 1993. The cost updates were performed by using escalation factors derived from cost index trends over the past 11.5 years. Contemporary price quotes wee used for costs that have increased drastically or for which is is difficult to find a cost trend. No changes were made in the decommissioning procedures or cost element requirements assumed in NUREG/CR-1757. This report includes only information that was changed from NUREG/CR-1757. Thus, for those interested in detailed descriptions and associated information for the reference uranium hexafluoride conversion plant, a copy of NUREG/CR-1757 will be needed.

Miles, T.L.; Liu, Y.

1995-08-01T23:59:59.000Z

67

WELDING THIN-WALLED URANIUM CYLINDERS  

SciTech Connect

One of Its Monograph Series, The Industrial Atom.'' The development of a satisfactory process for the fusion welding of thin-walled uranium cylinders is discussed. Optimum results were obtained using the inert-gas shielded-arc method without the use of filler metal. The ductility of the welded joints, however, was lower than that of cast metal. Surface conditions and and the purity of the inert gas used affected the weld soundness. Straight polarity direct current was used for welding to achieve maximum penetration and to provide are stability. Welding must be done in the flat position. (auth)

Brundige, E.L.; Taub, J.M.; Hanks, G.S.; Doll, D.T.

1957-01-01T23:59:59.000Z

68

The uranium cylinder assay system for enrichment plant safeguards  

Science Conference Proceedings (OSTI)

Safeguarding sensitive fuel cycle technology such as uranium enrichment is a critical component in preventing the spread of nuclear weapons. A useful tool for the nuclear materials accountancy of such a plant would be an instrument that measured the uranium content of UF{sub 6} cylinders. The Uranium Cylinder Assay System (UCAS) was designed for Japan Nuclear Fuel Limited (JNFL) for use in the Rokkasho Enrichment Plant in Japan for this purpose. It uses total neutron counting to determine uranium mass in UF{sub 6} cylinders given a known enrichment. This paper describes the design of UCAS, which includes features to allow for unattended operation. It can be used on 30B and 48Y cylinders to measure depleted, natural, and enriched uranium. It can also be used to assess the amount of uranium in decommissioned equipment and waste containers. Experimental measurements have been carried out in the laboratory and these are in good agreement with the Monte Carlo modeling results.

Miller, Karen A [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Marlow, Johnna B [Los Alamos National Laboratory; Menlove, Howard O [Los Alamos National Laboratory; Rael, Carlos D [Los Alamos National Laboratory; Iwamoto, Tomonori [JNFL; Tamura, Takayuki [JNFL; Aiuchi, Syun [JNFL

2010-01-01T23:59:59.000Z

69

Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site  

DOE Green Energy (OSTI)

This document is a site-specific environmental impact statement (EIS) for construction and operation of a proposed depleted uranium hexafluoride (DUF{sub 6}) conversion facility at the U.S. Department of Energy (DOE) Portsmouth site in Ohio (Figure S-1). The proposed facility would convert the DUF{sub 6} stored at Portsmouth to a more stable chemical form suitable for use or disposal. The facility would also convert the DUF{sub 6} from the East Tennessee Technology Park (ETTP) site near Oak Ridge, Tennessee. In a Notice of Intent (NOI) published in the Federal Register on September 18, 2001 (Federal Register, Volume 66, page 48123 [66 FR 48123]), DOE announced its intention to prepare a single EIS for a proposal to construct, operate, maintain, and decontaminate and decommission two DUF{sub 6} conversion facilities at Portsmouth, Ohio, and Paducah, Kentucky, in accordance with the National Environmental Policy Act of 1969 (NEPA) (United States Code, Title 42, Section 4321 et seq. [42 USC 4321 et seq.]) and DOE's NEPA implementing procedures (Code of Federal Regulations, Title 10, Part 1021 [10 CFR Part 1021]). Subsequent to award of a contract to Uranium Disposition Services, LLC (hereafter referred to as UDS), Oak Ridge, Tennessee, on August 29, 2002, for design, construction, and operation of DUF{sub 6} conversion facilities at Portsmouth and Paducah, DOE reevaluated its approach to the NEPA process and decided to prepare separate site-specific EISs. This change was announced in a Federal Register Notice of Change in NEPA Compliance Approach published on April 28, 2003 (68 FR 22368); the Notice is included as Attachment B to Appendix C of this EIS. This EIS addresses the potential environmental impacts from the construction, operation, maintenance, and decontamination and decommissioning (D&D) of the proposed conversion facility at three alternative locations within the Portsmouth site; from the transportation of all ETTP cylinders (DUF{sub 6}, low-enriched UF6 [LEU-UF{sub 6}], and empty) to Portsmouth; from the transportation of depleted uranium conversion products to a disposal facility; and from the transportation, sale, use, or disposal of the fluoride-containing conversion products (hydrogen fluoride [HF] or calcium fluoride [CaF{sub 2}]). An option of shipping the ETTP cylinders to Paducah is also considered. In addition, this EIS evaluates a no action alternative, which assumes continued storage of DUF{sub 6} in cylinders at the Portsmouth and ETTP sites. A separate EIS (DOE/EIS-0359) evaluates potential environmental impacts for the proposed Paducah conversion facility.

N /A

2003-11-28T23:59:59.000Z

70

Standard specification for uranium hexafluoride enriched to less than 5 % 235U  

E-Print Network (OSTI)

1.1 This specification covers nuclear grade uranium hexafluoride (UF6) that either has been processed through an enrichment plant, or has been produced by the blending of Highly Enriched Uranium with other uranium to obtain uranium of any 235U concentration below 5 % and that is intended for fuel fabrication. The objectives of this specification are twofold: (1) To define the impurity and uranium isotope limits for Enriched Commercial Grade UF6 so that, with respect to fuel design and manufacture, it is essentially equivalent to enriched uranium made from natural UF6; and (2) To define limits for Enriched Reprocessed UF6 to be expected if Reprocessed UF6 is to be enriched without dilution with Commercial Natural UF6. For such UF6, special provisions, not defined herein, may be needed to ensure fuel performance and to protect the work force, process equipment, and the environment. 1.2 This specification is intended to provide the nuclear industry with a standard for enriched UF6 that is to be used in the pro...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

71

Summary of the cost analysis report for the long-term management of depleted uranium hexafluoride  

SciTech Connect

This report is a summary of the Cost Analysis Report which provides comparative cost data for the management strategy alternatives. The PEIS and the Cost Analysis Report will help DOE select a management strategy. The Record of Decision, expected in 1998, will complete the first part of the Depleted Uranium Hexafluoride Management Program. The second part of the Program will look at specific sites and technologies for carrying out the selected strategy. The Cost Analysis Report estimates the primary capital and operating costs for the different alternatives. It reflects the costs of technology development construction of facilities, operation, and decontamination and decommissioning. It also includes potential revenues from the sale of by-products such as anhydrous hydrogen fluoride (ABF). These estimates are based on early designs. They are intended to help in comparing alternatives, rather than to indicate absolute costs for project budgets or bidding purposes. More detailed estimates and specific funding sources will be considered in part two of the Depleted Uranium Hexafluoride Management Program.

Dubrin, J.W.; Rahm-Crites, L.

1997-09-01T23:59:59.000Z

72

Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

DOE Green Energy (OSTI)

This document is a site-specific environmental impact statement (EIS) for construction and operation of a proposed depleted uranium hexafluoride (DUF{sub 6}) conversion facility at the U.S. Department of Energy (DOE) Paducah site in northwestern Kentucky (Figure S-1). The proposed facility would convert the DUF{sub 6} stored at Paducah to a more stable chemical form suitable for use or disposal. In a Notice of Intent (NOI) published in the ''Federal Register'' (FR) on September 18, 2001 (''Federal Register'', Volume 66, page 48123 [66 FR 48123]), DOE announced its intention to prepare a single EIS for a proposal to construct, operate, maintain, and decontaminate and decommission two DUF{sub 6} conversion facilities at Portsmouth, Ohio, and Paducah, Kentucky, in accordance with the National Environmental Policy Act of 1969 (NEPA) (''United States Code'', Title 42, Section 4321 et seq. [42 USC 4321 et seq.]) and DOE's NEPA implementing procedures (''Code of Federal Regulations'', Title 10, Part 1021 [10 CFR Part 1021]). Subsequent to award of a contract to Uranium Disposition Services, LLC (hereafter referred to as UDS), Oak Ridge, Tennessee, on August 29, 2002, for design, construction, and operation of DUF{sub 6} conversion facilities at Portsmouth and Paducah, DOE reevaluated its approach to the NEPA process and decided to prepare separate site-specific EISs. This change was announced in a ''Federal Register'' Notice of Change in NEPA Compliance Approach published on April 28, 2003 (68 FR 22368); the Notice is included as Attachment B to Appendix C of this EIS. This EIS addresses the potential environmental impacts from the construction, operation, maintenance, and decontamination and decommissioning (D&D) of the proposed conversion facility at three alternative locations within the Paducah site; from the transportation of depleted uranium conversion products to a disposal facility; and from the transportation, sale, use, or disposal of the fluoride-containing conversion products (hydrogen fluoride [HF] or calcium fluoride [CaF{sub 2}]). Although not part of the proposed action, an option of shipping all cylinders (DUF{sub 6}, low-enriched UF{sub 6} [LEU-UF{sub 6}], and empty) stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Paducah rather than to Portsmouth is also considered. In addition, this EIS evaluates a no action alternative, which assumes continued storage of DUF{sub 6} in cylinders at the Paducah site. A separate EIS (DOE/EIS-0360) evaluates the potential environmental impacts for the proposed Portsmouth conversion facility.

N /A

2003-11-28T23:59:59.000Z

73

Conversion and Blending Facility Highly enriched uranium to low enriched uranium as uranium hexafluoride. Revision 1  

SciTech Connect

This report describes the Conversion and Blending Facility (CBF) which will have two missions: (1) convert surplus HEU materials to pure HEU UF{sub 6} and a (2) blend the pure HEU UF{sub 6} with diluent UF{sub 6} to produce LWR grade LEU-UF{sub 6}. The primary emphasis of this blending be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The chemical and isotopic concentrations of the blended LEU product will be held within the specifications required for LWR fuel. The blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry.

1995-07-05T23:59:59.000Z

74

Disposition of DOE Excess Depleted Uranium, Natural Uranium, and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Disposition of DOE Excess Depleted Uranium, Natural Uranium, and Disposition of DOE Excess Depleted Uranium, Natural Uranium, and Low-Enriched Uranium Disposition of DOE Excess Depleted Uranium, Natural Uranium, and Low-Enriched Uranium The U.S. Department of Energy (DOE) owns and manages an inventory of depleted uranium (DU), natural uranium (NU), and low-enriched uranium (LEU) that is currently stored in large cylinders as depleted uranium hexafluoride (DUF6), natural uranium hexafluoride (NUF6), and low-enriched uranium hexafluoride (LEUF6) at the DOE Paducah site in western Kentucky (DOE Paducah) and the DOE Portsmouth site near Piketon in south-central Ohio (DOE Portsmouth)1. This inventory exceeds DOE's current and projected energy and defense program needs. On March 11, 2008, the Secretary of Energy issued a policy statement (the

75

Biological assessment of the effects of construction and operation of a depleted uranium hexafluoride conversion facility at the Paducah, Kentucky, site.  

SciTech Connect

The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF6 inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This biological assessment (BA) has been prepared by DOE, pursuant to the National Environmental Policy Act of 1969 (NEPA) and the Endangered Species Act of 1974, to evaluate potential impacts to federally listed species from the construction and operation of a conversion facility at the DOE Paducah site.

Van Lonkhuyzen, R.

2005-09-09T23:59:59.000Z

76

Biological assessment of the effects of construction and operation of a depleted uranium hexafluoride conversion facility at the Paducah, Kentucky, site.  

SciTech Connect

The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF6 inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This biological assessment (BA) has been prepared by DOE, pursuant to the National Environmental Policy Act of 1969 (NEPA) and the Endangered Species Act of 1974, to evaluate potential impacts to federally listed species from the construction and operation of a conversion facility at the DOE Paducah site.

Van Lonkhuyzen, R.

2005-09-09T23:59:59.000Z

77

Some Investigations of the Reaction of Activated Charcoal with Fluorine and Uranium Hexafluoride  

SciTech Connect

The Molten Salt Reactor Experiment (MSRE) at Oak Ridge National Laboratory has been shut down since 1969, when the fuel salt was drained from the core into two Hastelloy N drain tanks at the reactor site. Over time, fluorine (F{sub 2}) and uranium hexafluoride (UF{sub 6}) moved from the salt through the gas piping to a charcoal bed, where they reacted with the activated charcoal. Some of the immediate concerns related to the migration of F{sub 2} and UF{sub 6} to the charcoal bed were the possibility of explosive reactions between the charcoal and F{sub 2}, the existence of conditions that could induce a criticality accident, and the removal and recovery of the fissile uranium from the charcoal. This report addresses the reactions and reactivity of species produced by the reaction of fluorine and activated charcoal and between charcoal and F{sub 2}-UF{sub 6} gas mixtures in order to support remediation of the MSRE auxiliary charcoal bed (ACB) and the recovery of the fissile uranium. The chemical identity, stoichiometry, thermochemistry, and potential for explosive decomposition of the primary reaction product, fluorinated charcoal, was determined.

Del Cul, G.D.; Fiedor, J.N.; Simmons, D.W.; Toth, L.M.; Trowbridge, L.D.; Williams

1998-09-01T23:59:59.000Z

78

Evaluation of a RF-Based Approach for Tracking UF6 Cylinders at a Uranium Enrichment Plant  

SciTech Connect

Approved industry-standard cylinders are used globally to handle and store uranium hexafluoride (UF{sub 6}) feed, product, tails, and samples at uranium enrichment plants. The International Atomic Energy Agency (IAEA) relies on time-consuming physical inspections to verify operator declarations and detect possible diversion of UF{sub 6}. Development of a reliable, automated, and tamper-resistant system for near real-time tracking and monitoring UF{sub 6} cylinders (as they move within an enrichment facility) would greatly improve the inspector function. This type of system can reduce the risk of false or misreported cylinder tare weights, diversion of nuclear material, concealment of excess production, utilization of undeclared cylinders, and misrepresentation of the cylinders contents. This paper will describe a proof-of-concept approach that was designed to evaluate the feasibility of using radio frequency (RF)-based technologies to track individual UF{sub 6} cylinders throughout a portion of their life cycle, and thus demonstrate the potential for improved domestic accountability of materials, and a more effective and efficient method for application of site-level IAEA safeguards. The evaluation system incorporates RF-based identification devices (RFID) which provide a foundation for establishing a reliable, automated, and near real-time tracking system that can be set up to utilize site-specific, rules-based detection algorithms. This paper will report results from a proof-of-concept demonstration at a real enrichment facility that is specifically designed to evaluate both the feasibility of using RF to track cylinders and the durability of the RF equipment to survive the rigors of operational processing and handling. The paper also discusses methods for securely attaching RF devices and describes how the technology can effectively be layered with other safeguard systems and approaches to build a robust system for detecting cylinder diversion. Additionally, concepts for off-site tracking of cylinders are described.

Pickett, Chris A [ORNL; Younkin, James R [ORNL; Kovacic, Donald N [ORNL; Laughter, Mark D [ORNL; Hines, Jairus B [ORNL; Boyer, Brian [Los Alamos National Laboratory (LANL); Martinez, B. [Los Alamos National Laboratory (LANL)

2008-01-01T23:59:59.000Z

79

Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DRAFT ENVIRONMENTAL IMPACT DRAFT ENVIRONMENTAL IMPACT STATEMENT FOR CONSTRUCTION AND OPERATION OF A DEPLETED URANIUM HEXAFLUORIDE CONVERSION FACILITY AT THE PADUCAH, KENTUCKY, SITE DECEMBER 2003 U.S. Department of Energy-Oak Ridge Operations Office of Environmental Management Cover Sheet Paducah DUF 6 DEIS: December 2003 iii COVER SHEET RESPONSIBLE FEDERAL AGENCY: U.S. Department of Energy (DOE) TITLE: Draft Environmental Impact Statement (DEIS) for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site (DOE/EIS-0359) CONTACT: For further information on this environmental impact statement (EIS), contact: Gary S. Hartman DOE-ORO Cultural Resources Management Coordinator U.S. Department of Energy-Oak Ridge Operations P.O. Box 2001 Oak Ridge, TN 37831

80

Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at Portsmouth, Ohio, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DRAFT ENVIRONMENTAL IMPACT DRAFT ENVIRONMENTAL IMPACT STATEMENT FOR CONSTRUCTION AND OPERATION OF A DEPLETED URANIUM HEXAFLUORIDE CONVERSION FACILITY AT THE PORTSMOUTH, OHIO, SITE DECEMBER 2003 U.S. Department of Energy-Oak Ridge Operations Office of Environmental Management Cover Sheet Portsmouth DUF 6 DEIS: December 2003 iii COVER SHEET RESPONSIBLE FEDERAL AGENCY: U.S. Department of Energy (DOE) TITLE: Draft Environmental Impact Statement (DEIS) for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site (DOE/EIS-0360) CONTACT: For further information on this environmental impact statement (EIS), contact: Gary S. Hartman DOE-ORO Cultural Resources Management Coordinator U.S. Department of Energy-Oak Ridge Operations P.O. Box 2001 Oak Ridge, TN 37831

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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81

Draft Supplement Analysis for Location(s) to Dispose of Depleted Uranium Oxide Conversion Product Generated from DOE'S Inventory of Depleted Uranium Hexafluoride  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DRAFT SUPPLEMENT ANALYSIS FOR LOCATION(S) TO DISPOSE OF DEPLETED DRAFT SUPPLEMENT ANALYSIS FOR LOCATION(S) TO DISPOSE OF DEPLETED URANIUM OXIDE CONVERSION PRODUCT GENERATED FROM DOE'S INVENTORY OF DEPLETED URANIUM HEXAFLUORIDE (DOE/EIS-0359-SA1 AND DOE/EIS-0360-SA1) March 2007 March 2007 i CONTENTS NOTATION........................................................................................................................... iv 1 INTRODUCTION AND BACKGROUND ................................................................. 1 1.1 Why DOE Has Prepared This Draft Supplement Analysis .............................. 1 1.2 Background ....................................................................................................... 3 1.3 Proposed Actions Considered in this Draft Supplement Analysis.................... 4

82

Facilitate Intact Cylinder Reuse  

NLE Websites -- All DOE Office Websites (Extended Search)

Facilitate Intact Cylinder Reuse Many DU hexafluoride storage cylinders are in relatively good condition and capable of further use as a container. However, even after being...

83

Technology, Safety and Costs of Decommissioning a Reference Uranium Hexafluoride Conversion Plant  

Science Conference Proceedings (OSTI)

Safety and cost information is developed for the conceptual decommissioning of a commercial uranium hexafluoride conversion (UF{sub 6}) plant. Two basic decommissioning alternatives are studied to obtain comparisons between cost and safety impacts: DECON, and passive SAFSTOR. A third alternative, DECON of the plant and equipment with stabilization and long-term care of lagoon wastes. is also examined. DECON includes the immediate removal (following plant shutdown) of all radioactivity in excess of unrestricted release levels, with subsequent release of the site for public use. Passive SAFSTOR requires decontamination, preparation, maintenance, and surveillance for a period of time after shutdown, followed by deferred decontamination and unrestricted release. DECON with stabilization and long-term care of lagoon wastes (process wastes generated at the reference plant and stored onsite during plant operation} is also considered as a decommissioning method, although its acceptability has not yet been determined by the NRC. The decommissioning methods assumed for use in each decommissioning alternative are based on state-of-the-art technology. The elapsed time following plant shutdown required to perform the decommissioning work in each alternative is estimated to be: for DECON, 8 months; for passive SAFSTOR, 3 months to prepare the plant for safe storage and 8 months to accomplish deferred decontamination. Planning and preparation for decommissioning prior to plant shutdown is estimated to require about 6 months for either DECON or passive SAFSTOR. Planning and preparation prior to starting deferred decontamination is estimated to require an additional 6 months. OECON with lagoon waste stabilization is estimated to take 6 months for planning and about 8 months to perform the decommissioning work. Decommissioning cost, in 1981 dollars, is estimated to be $5.91 million for OECON. For passive SAFSTOR, preparing the facility for safe storage is estimated to cost $0.88 million, the annual maintenance and surveillance cost is estimated to be about $0.095 million, and deferred decontamination is estimated to cost about $6.50 million. Therefore, passive SAFSTOR for 10 years is estimated to cost $8.33 million in nondiscounted 1981 dollars. DECON with lagoon waste stabilization is estimated to cost about $4.59 million, with an annual cost of $0.011 million for long-term care. All of these estimates include a 25% contingency. Waste management costs for DECON, including the net cost of disposal of the solvent extraction lagoon wastes by shipping those wastes to a uranium mill for recovery of residual uranium, comprise about 38% of the total decommissioning cost. Disposal of lagoon waste at a commercial low-level waste burial ground is estimated to add $10.01 million to decommissioning costs. Safety analyses indicate that radiological and nonradiological safety impacts from decommissioning activities should be small. The 50-year committed dose equivalent to members of the public from airborne releases during normal decommissioning activities is estimated to 'Je about 4.0 man-rem. Radiation doses to the public from accidents are found to be very low for all phases of decommissioning. Occupational radiation doses from normal decommissioning operations (excluding transport operations) are estimated to be about 79 man-rem for DECON and about 80 man-rem for passive SAFSTOR with 10 years of safe storage. Doses from DECON with lagoon waste stabilization are about the same as for DECON except there is less dose resulting from transportation of radioactive waste. The number of fatalities and serious lost-time injuries not related to radiation is found to be very small for all decommissioning alternatives. Comparison of the cost estimates shows that DECON with lagoon waste stabilization is the least expensive method. However, this alternative does not allow unrestricted release of the site. The cumulative cost of maintenance and surveillance and the higher cost of deferred decontamination makes passive SAFSTOR more expensive than DECON. Seve

Elder, H. K.

1981-10-01T23:59:59.000Z

84

Indirect NMR detection of 235U in gaseous uranium hexafluoride National Center for Physics, P.O. Box MG-6, Bucharest, Romania  

E-Print Network (OSTI)

L-493 Indirect NMR detection of 235U in gaseous uranium hexafluoride I. Ursu National Center- vation of235 U NMR signal in liquid UF6 at B = 11.747 T has been recently reported [7]. The aim of this Letter is to investigate the effect of the 23 5U enrichment on the 19F NMR spectra in gaseous UF6. Using

Paris-Sud XI, Université de

85

Benchmark Gamma Spectroscopy Measurements of Uranium Hexafluoride in Aluminmum Pipe with a Sodium Iodide Detector  

SciTech Connect

The expected increased demand in fuel for nuclear power plants, combined with the fact that a significant portion of the current supply from the blend down of weapons-source material will soon be coming to an end, has led to the need for new sources of enriched uranium for nuclear fuel. As a result, a number of countries have announced plans, or are currently building, gaseous centrifuge enrichment plants (GCEPs) to supply this material. GCEPs have the potential to produce uranium at enrichments above the level necessary for nuclear fuel purposes-enrichments that make the uranium potentially usable for nuclear weapons. As a result, there is a critical need to monitor these facilities to ensure that nuclear material is not inappropriately enriched or diverted for unintended use. Significant advances have been made in instrument capability since the current International Atomic Energy Agency (IAEA) monitoring methods were developed. In numerous cases, advances have been made in other fields that have the potential, with modest development, to be applied in safeguards applications at enrichment facilities. A particular example of one of these advances is the flow and enrichment monitor (FEMO). (See Gunning, J. E. et al., 'FEMO: A Flow and Enrichment Monitor for Verifying Compliance with International Safeguards Requirements at a Gas Centrifuge Enrichment Facility,' Proceedings of the 8th International Conference on Facility Operations - Safeguards Interface. Portland, Oregon, March 30-April 4th, 2008.) The FEMO is a conceptual instrument capable of continuously measuring, unattended, the enrichment and mass flow of {sup 235}U in pipes at a GCEP, and consequently increase the probability that the potential production of HEU and/or diversion of fissile material will be detected. The FEMO requires no piping penetrations and can be installed on pipes containing the flow of uranium hexafluoride (UF{sub 6}) at a GCEP. This FEMO consists of separate parts, a flow monitor (FM) and an enrichment monitor (EM). Development of the FM is primarily the responsibility of Oak Ridge National Laboratory, and development of the EM is primarily the responsibility of Los Alamos National Laboratory. The FM will measure {sup 235}U mass flow rate by combining information from measuring the UF{sub 6} volumetric flow rate and the {sup 235}U density. The UF{sub 6} flow rate will be measured using characteristics of the process pumps used in product and tail UF{sub 6} header process lines of many GCEPs, and the {sup 235}U density will be measured using commercially available sodium iodide (NaI) gamma ray scintillation detectors. This report describes the calibration of the portion of the FM that measures the {sup 235}U density. Research has been performed to define a methodology and collect data necessary to perform this calibration without the need for plant declarations. The {sup 235}U density detector is a commercially available system (GammaRad made by Amptek, www.amptek.com) that contains the NaI crystal, photomultiplier tube, signal conditioning electronics, and a multichannel analyzer (MCA). Measurements were made with the detector system installed near four {sup 235}U sources. Two of the sources were made of solid uranium, and the other two were in the form of UF{sub 6} gas in aluminum piping. One of the UF{sub 6} gas sources was located at ORNL and the other at LANL. The ORNL source consisted of two pipe sections (schedule 40 aluminum pipe of 4-inch and 8-inch outside diameter) with 5.36% {sup 235}U enrichment, and the LANL source was a 4-inch schedule 40 aluminum pipe with 3.3% {sup 235}U enrichment. The configurations of the detector on these test sources, as well as on long straight pipe configurations expected to exist at GCEPs, were modeled using the computer code MCNP. The results of the MCNP calculations were used to define geometric correction factors between the test source and the GCEP application. Using these geometric correction factors, the experimental 186 keV counts in the test geometry were extrapolated to the expected GCEP ge

March-Leuba, Jose A [ORNL; Uckan, Taner [ORNL; Gunning, John E [ORNL; Brukiewa, Patrick D [ORNL; Upadhyaya, Belle R [ORNL; Revis, Stephen M [ORNL

2010-01-01T23:59:59.000Z

86

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at Portsmouth, Ohio, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Main Text and Appendixes A-H 1: Main Text and Appendixes A-H June 2004 U.S. Department of Energy Office of Environmental Management Cover Sheet Portsmouth DUF 6 Conversion Final EIS iii COVER SHEET * RESPONSIBLE FEDERAL AGENCY: U.S. Department of Energy (DOE) TITLE: Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site (DOE/EIS-0360) CONTACT: For further information on this environmental impact statement (EIS), contact: Gary S. Hartman DOE-ORO Cultural Resources Management Coordinator U.S. Department of Energy-Oak Ridge Operations P.O. Box 2001 Oak Ridge, TN 37831 e-mail: Ports_DUF6@anl.gov phone: 1-866-530-0944 fax: 1-866-530-0943 For general information on the DOE National Environmental Policy Act (NEPA) process, contact:

87

Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 1 Paducah DUF 6 DEIS: December 2003 SUMMARY S.1 INTRODUCTION This document is a site-specific environmental impact statement (EIS) for construction and operation of a proposed depleted uranium hexafluoride (DUF 6 ) conversion facility at the U.S. Department of Energy (DOE) Paducah site in northwestern Kentucky (Figure S-1). The proposed facility would convert the DUF 6 stored at Paducah to a more stable chemical form suitable for use or disposal. In a Notice of Intent (NOI) published in the Federal Register (FR) on September 18, 2001 (Federal Register, Volume 66, page 48123 [66 FR 48123]), DOE announced its intention to prepare a single EIS for a proposal to construct, operate, maintain, and decontaminate and decommission two DUF 6 conversion facilities at Portsmouth,

88

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at Portsmouth, Ohio, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2: Comment and Response Document 2: Comment and Response Document June 2004 U.S. Department of Energy Office of Environmental Management Comment & Response Document Portsmouth DUF 6 Conversion Final EIS iii COVER SHEET RESPONSIBLE FEDERAL AGENCY: U.S. Department of Energy (DOE) TITLE: Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site (DOE/EIS-0360) CONTACT: For further information on this environmental impact statement (EIS), contact: Gary S. Hartman DOE-ORO Cultural Resources Management Coordinator U.S. Department of Energy-Oak Ridge Operations P.O. Box 2001 Oak Ridge, TN 37831 e-mail: Ports_DUF6@anl.gov phone: 1-866-530-0944 fax: 1-866-530-0943 For general information on the DOE National Environmental Policy Act (NEPA) process, contact:

89

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2: Comment and Response Document 2: Comment and Response Document June 2004 U.S. Department of Energy Office of Environmental Management Comment & Response Document Paducah DUF 6 Conversion Final EIS iii COVER SHEET RESPONSIBLE FEDERAL AGENCY: U.S. Department of Energy (DOE) TITLE: Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site (DOE/EIS-0359) CONTACT: For further information on this environmental impact statement (EIS), contact: Gary S. Hartman DOE-ORO Cultural Resources Management Coordinator U.S. Department of Energy-Oak Ridge Operations P.O. Box 2001 Oak Ridge, TN 37831 e-mail: Pad_DUF6@anl.gov phone: 1-866-530-0944 fax: 1-866-530-0943 For general information on the DOE National Environmental Policy Act (NEPA) process,

90

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Main Text and Appendixes A-H 1: Main Text and Appendixes A-H June 2004 U.S. Department of Energy Office of Environmental Management Cover Sheet Paducah DUF 6 Conversion Final EIS iii COVER SHEET * RESPONSIBLE FEDERAL AGENCY: U.S. Department of Energy (DOE) TITLE: Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site (DOE/EIS-0359) CONTACT: For further information on this environmental impact statement (EIS), contact: Gary S. Hartman DOE-ORO Cultural Resources Management Coordinator U.S. Department of Energy-Oak Ridge Operations P.O. Box 2001 Oak Ridge, TN 37831 e-mail: Pad_DUF6@anl.gov phone: 1-866-530-0944 fax: 1-866-530-0943 For general information on the DOE National Environmental Policy Act (NEPA) process, contact:

91

Floodplain/wetland assessment of the effects of construction and operation ofa depleted uranium hexafluoride conversion facility at the Paducah, Kentucky,site.  

SciTech Connect

The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF{sub 6} inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This floodplain/wetland assessment has been prepared by DOE, pursuant to Executive Order 11988 (''Floodplain Management''), Executive Order 11990 (Protection of Wetlands), and DOE regulations for implementing these Executive Orders as set forth in Title 10, Part 1022, of the ''Code of Federal Regulations'' (10 CFR Part 1022 [''Compliance with Floodplain and Wetland Environmental Review Requirements'']), to evaluate potential impacts to floodplains and wetlands from the construction and operation of a conversion facility at the DOE Paducah site. Reconstruction of the bridge crossing Bayou Creek would occur within the Bayou Creek 100-year floodplain. Replacement of bridge components, including the bridge supports, however, would not be expected to result in measurable long-term changes to the floodplain. Approximately 0.16 acre (0.064 ha) of palustrine emergent wetlands would likely be eliminated by direct placement of fill material within Location A. Some wetlands that are not filled may be indirectly affected by an altered hydrologic regime, due to the proximity of construction, possibly resulting in a decreased frequency or duration of inundation or soil saturation and potential loss of hydrology necessary to sustain wetland conditions. Indirect impacts could be minimized by maintaining a buffer near adjacent wetlands. Wetlands would likely be impacted by construction at Location B; however, placement of a facility in the northern portion of this location would minimize wetland impacts. Construction at Location C could potentially result in impacts to wetlands, however placement of a facility in the southeastern portion of this location may best avoid direct impacts to wetlands. The hydrologic characteristics of nearby wetlands could be indirectly affected by adjacent construction. Executive Order 11990, ''Protection of Wetlands'', requires federal agencies to minimize the destruction, loss, or degradation of wetlands, and to preserve and enhance the natural and beneficial uses of wetlands. DOE regulations for implementing Executive Order 11990 as well as Executive Order 11988, ''Floodplain Management'', are set forth in 10 CFR Part 1022. Mitigation for unavoidable impacts may be developed in coordination with the appropriate regulatory agencies. Unavoidable impacts to wetlands that are within the jurisdiction of the USACE may require a CWA Section 404 Permit, which would trigger the requirement for a CWA Section 401 Water Quality Certification from the Commonwealth of Kentucky. A mitigation plan may be required prior to the initiation of construction. Cumulative impacts to floodplains and wetlands are anticipated to be negligible to minor under the proposed action, in conjunction with the effects of existing conditions and other activities. Habitat disturbance would involve settings commonly found i

Van Lonkhuyzen, R.

2005-09-09T23:59:59.000Z

92

Biological assessment of the effects of construction and operation of adepleted uranium hexafluoride conversion facility at the Portsmouth, Ohio,site.  

SciTech Connect

The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF{sub 6} inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This biological assessment (BA) has been prepared by DOE, pursuant to the National Environmental Policy Act of 1969 and the Endangered Species Act of 1974, to evaluate potential impacts to federally listed species from the construction and operation of a conversion facility at the DOE Portsmouth site. The Indiana bat is known to occur in the area of the Portsmouth site and may potentially occur on the site during spring or summer. Evaluations of the Portsmouth site indicated that most of the site was found to have poor summer habitat for the Indiana bat because of the small size, isolation, and insufficient maturity of the few woodlands on the site. Potential summer habitat for the Indiana bat was identified outside the developed area bounded by Perimeter Road, within the corridors along Little Beaver Creek, the Northwest Tributary stream, and a wooded area east of the X-100 facility. However, no Indiana bats were collected during surveys of these areas in 1994 and 1996. Locations A, B, and C do not support suitable habitat for the Indiana bat and would be unlikely to be used by Indiana bats. Indiana bat habitat also does not occur at Proposed Areas 1 and 2. Although Locations A and C contain small wooded areas, the small size and lack of suitable maturity of these areas indicate that they would provide poor habitat for Indiana bats. Trees that may be removed during construction would not be expected to be used for summer roosting by Indiana bats. Disturbance of Indiana bats potentially roosting or foraging in the vicinity of the facility during operations would be very unlikely, and any disturbance would be expected to be negligible. On the basis of these considerations, DOE concludes that the proposed action is not likely to adversely affect the Indiana bat. No critical habitat exists for this species in the action area. Although the timber rattlesnake occurs in the vicinity of the Portsmouth site, it has not been observed on the site. In addition, habitat for the timber rattlesnake is not present on the Portsmouth site. Therefore, DOE concludes that the proposed action would not affect the timber rattlesnake.

Van Lonkhuyzen, R.

2005-09-09T23:59:59.000Z

93

Biological assessment of the effects of construction and operation of adepleted uranium hexafluoride conversion facility at the Portsmouth, Ohio,site.  

SciTech Connect

The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF{sub 6} inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This biological assessment (BA) has been prepared by DOE, pursuant to the National Environmental Policy Act of 1969 and the Endangered Species Act of 1974, to evaluate potential impacts to federally listed species from the construction and operation of a conversion facility at the DOE Portsmouth site. The Indiana bat is known to occur in the area of the Portsmouth site and may potentially occur on the site during spring or summer. Evaluations of the Portsmouth site indicated that most of the site was found to have poor summer habitat for the Indiana bat because of the small size, isolation, and insufficient maturity of the few woodlands on the site. Potential summer habitat for the Indiana bat was identified outside the developed area bounded by Perimeter Road, within the corridors along Little Beaver Creek, the Northwest Tributary stream, and a wooded area east of the X-100 facility. However, no Indiana bats were collected during surveys of these areas in 1994 and 1996. Locations A, B, and C do not support suitable habitat for the Indiana bat and would be unlikely to be used by Indiana bats. Indiana bat habitat also does not occur at Proposed Areas 1 and 2. Although Locations A and C contain small wooded areas, the small size and lack of suitable maturity of these areas indicate that they would provide poor habitat for Indiana bats. Trees that may be removed during construction would not be expected to be used for summer roosting by Indiana bats. Disturbance of Indiana bats potentially roosting or foraging in the vicinity of the facility during operations would be very unlikely, and any disturbance would be expected to be negligible. On the basis of these considerations, DOE concludes that the proposed action is not likely to adversely affect the Indiana bat. No critical habitat exists for this species in the action area. Although the timber rattlesnake occurs in the vicinity of the Portsmouth site, it has not been observed on the site. In addition, habitat for the timber rattlesnake is not present on the Portsmouth site. Therefore, DOE concludes that the proposed action would not affect the timber rattlesnake.

Van Lonkhuyzen, R.

2005-09-09T23:59:59.000Z

94

Paducah DUF6 Conversion Final EIS - Appendix C: Scoping Summary Report for Depleted Uranium Hexafluoride Conversion Facilities - Environmental Impact Statement Scoping Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Paducah DUF Paducah DUF 6 Conversion Final EIS APPENDIX C: SCOPING SUMMARY REPORT FOR DEPLETED URANIUM HEXAFLUORIDE CONVERSION FACILITIES ENVIRONMENTAL IMPACT STATEMENT SCOPING PROCESS Scoping Summary Report C-2 Paducah DUF 6 Conversion Final EIS Scoping Summary Report C-3 Paducah DUF 6 Conversion Final EIS APPENDIX C This appendix contains the summary report prepared after the initial public scoping period for the depleted uranium hexafluoride conversion facilities environmental impact statement (EIS) project. The scoping period for the EIS began with the September 18, 2001, publication of a Notice of Intent (NOI) in the Federal Register (66 FR 23213) and was extended to January 11, 2002. The report summarizes the different types of public involvement opportunities provided and the content of the comments received.

95

DOE Selects Contractor for Depleted Hexafluoride Conversion Project...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

in Paducah, Kentucky and Portsmouth, Ohio. For several decades DOE was responsible for uranium enrichment, the uranium hexafluoride depleted in the 235U isotope (typically down...

96

Assessment of the Portsmouth/Paducah Project Office Conduct of Operations Oversight of the Depleted Uranium Hexafluoride Conversion Plants, May 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Assessment of the Assessment of the Portsmouth/Paducah Project Office Conduct of Operations Oversight of the Depleted Uranium Hexafluoride Conversion Plants May 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope ...................................................................................................................................................... 2

97

Assessment of the Portsmouth/Paducah Project Office Conduct of Operations Oversight of the Depleted Uranium Hexafluoride Conversion Plants, May 2012  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessment of the Assessment of the Portsmouth/Paducah Project Office Conduct of Operations Oversight of the Depleted Uranium Hexafluoride Conversion Plants May 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope ...................................................................................................................................................... 2

98

FAQ 21-What happens if a cylinder of uranium hexafluoride leaks...  

NLE Websites -- All DOE Office Websites (Extended Search)

(breach) occurs and the depleted UF6 is exposed to water vapor in the air, uranyl fluoride (UO2F2) and hydrogen fluoride (HF) are formed. The uranyl fluoride is a solid that...

99

Characterization of options and their analysis requirements for the long-term management of depleted uranium hexafluoride  

Science Conference Proceedings (OSTI)

The Department of Energy (DOE) is examining alternative strategies for the long-term management of depleted uranium hexafluoride (UF{sub 6}) currently stored at the gaseous diffusion plants at Portsmouth, Ohio, and Paducah, Kentucky, and on the Oak Ridge Reservation in Oak Ridge, Tennessee. This paper describes the methodology for the comprehensive and ongoing technical analysis of the options being considered. An overview of these options, along with several of the suboptions being considered, is presented. The long-term management strategy alternatives fall into three broad categories: use, storage, or disposal. Conversion of the depleted UF6 to another form such as oxide or metal is needed to implement most of these alternatives. Likewise, transportation of materials is an integral part of constructing the complete pathway between the current storage condition and ultimate disposition. The analysis of options includes development of pre-conceptual designs; estimates of effluents, wastes, and emissions; specification of resource requirements; and preliminary hazards assessments. The results of this analysis will assist DOE in selecting a strategy by providing the engineering information necessary to evaluate the environmental impacts and costs of implementing the management strategy alternatives.

Dubrin, J.W.; Rosen, R.S.; Zoller, J.N.; Harri, J.W.; Schwertz, N.L.

1995-12-01T23:59:59.000Z

100

Valve studies: Hydrogen fluoride monitoring of UF{sub 6} cylinder valves  

Science Conference Proceedings (OSTI)

Uranium hexafluoride (UF{sub 6}) cylinder valves have, like the cylinders, been in use and/or storage for periods ranging from 15 to 44 years. Visual inspection of the cylinders has shown that the extent of corrosion and the overall cylinder condition varies widely throughout the storage yards. One area of concern is the integrity of the cylinder valves. Visual inspection has found deposits which have been identified as radioactive material on or near the valves. These deposits suggest leakage of UF{sub 6} and may indicate valve degradation; however, these deposits may simply be residual material from cylinder filling operations.

Leedy, R.R.; Ellis, A.R.; Hoffmann, D.P.; Marsh, G.C. [and others

1996-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Results from a "Proof-of-Concept" Demonstration of RF-Based Tracking of UF6 Cylinders during a Processing Operation at a Uranium Enrichment Plant  

SciTech Connect

Approved industry-standard cylinders are used globally for processing, storing, and transporting uranium hexafluoride (UF{sub 6}) at uranium enrichment plants. To ensure that cylinder movements at enrichment facilities occur as declared, the International Atomic Energy Agency (IAEA) must conduct time-consuming periodic physical inspections to validate facility records, cylinder identity, and containment. By using a robust system design that includes the capability for real-time unattended monitoring (of cylinder movements), site-specific rules-based event detection algorithms, and the capability to integrate with other types of monitoring technologies, one can build a system that will improve overall inspector effectiveness. This type of monitoring system can provide timely detection of safeguard events that could be used to ensure more timely and appropriate responses by the IAEA. It also could reduce reliance on facility records and have the additional benefit of enhancing domestic safeguards at the installed facilities. This paper will discuss the installation and evaluation of a radio-frequency- (RF-) based cylinder tracking system that was installed at a United States Enrichment Corporation Centrifuge Facility. This system was installed primarily to evaluate the feasibility of using RF technology at a site and the operational durability of the components under harsh processing conditions. The installation included a basic system that is designed to support layering with other safeguard system technologies and that applies fundamental rules-based event processing methodologies. This paper will discuss the fundamental elements of the system design, the results from this site installation, and future efforts needed to make this technology ready for IAEA consideration.

Pickett, Chris A [ORNL; Kovacic, Donald N [ORNL; Whitaker, J Michael [ORNL; Younkin, James R [ORNL; Hines, Jairus B [ORNL; Laughter, Mark D [ORNL; Morgan, Jim [Innovative Solutions; Carrick, Bernie [USEC; Boyer, Brian [Los Alamos National Laboratory (LANL); Whittle, K. [USEC

2008-01-01T23:59:59.000Z

102

Standard test method for the analysis of refrigerant 114, plus other carbon-containing and fluorine-containing compounds in uranium hexafluoride via fourier-transform infrared (FTIR) spectroscopy  

E-Print Network (OSTI)

1.1 This test method covers determining the concentrations of refrigerant-114, other carbon-containing and fluorine-containing compounds, hydrocarbons, and partially or completely substituted halohydrocarbons that may be impurities in uranium hexafluoride. The two options are outlined for this test method. They are designated as Part A and Part B. 1.1.1 To provide instructions for performing Fourier-Transform Infrared (FTIR) spectroscopic analysis for the possible presence of Refrigerant-114 impurity in a gaseous sample of uranium hexafluoride, collected in a "2S" container or equivalent at room temperature. The all gas procedure applies to the analysis of possible Refrigerant-114 impurity in uranium hexafluoride, and to the gas manifold system used for FTIR applications. The pressure and temperatures must be controlled to maintain a gaseous sample. The concentration units are in mole percent. This is Part A. 1.2 Part B involves a high pressure liquid sample of uranium hexafluoride. This method can be appli...

American Society for Testing and Materials. Philadelphia

2004-01-01T23:59:59.000Z

103

Next Generations Safeguards Initiative: The Life of a Cylinder  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy/National Nuclear Security Administration Office of Nonproliferation and International Security's Next Generation Safeguards Initiative (NGSI) has begun a program based on a five-year plan to investigate the concept of a global monitoring scheme that uniquely identifies uranium hexafluoride (UF6) cylinders and their locations throughout the life cycle. A key initial activity in the NGSI program is to understand and document the 'life of a UF6 cylinder' from cradle to grave. This document describes the life of a UF6 cylinder and includes cylinder manufacture and procurement processes as well as cylinder-handling and operational practices at conversion, enrichment, fuel fabrication, and depleted UF6 conversion facilities. The NGSI multiple-laboratory team is using this document as a building block for subsequent tasks in the five-year plan, including development of the functional requirements for cylinder-tagging and tracking devices.

Morgan, James B [ORNL; White-Horton, Jessica L [ORNL

2012-01-01T23:59:59.000Z

104

Signatures and Methods for the Automated Nondestructive Assay of UF6 Cylinders at Uranium Enrichment Plants  

Science Conference Proceedings (OSTI)

International Atomic Energy Agency (IAEA) inspectors currently perform periodic inspections at uranium enrichment plants to verify UF6 cylinder enrichment declarations. Measurements are typically performed with handheld high-resolution sensors on a sampling of cylinders taken to be representative of the facilitys entire cylinder inventory. These measurements are time-consuming, expensive, and assay only a small fraction of the total cylinder volume. An automated nondestructive assay system capable of providing enrichment measurements over the full volume of the cylinder could improve upon current verification practices in terms of manpower and assay accuracy. Such a station would use sensors that can be operated in an unattended mode at an industrial facility: medium-resolution scintillators for gamma-ray spectroscopy (e.g., NaI(Tl)) and moderated He-3 neutron detectors. This sensor combination allows the exploitation of additional, more-penetrating signatures beyond the traditional 185-keV emission from U-235: neutrons produced from F-19(?,n) reactions (spawned primarily from U 234 alpha emission) and high-energy gamma rays (extending up to 8 MeV) induced by neutrons interacting in the steel cylinder. This paper describes a study of these non-traditional signatures for the purposes of cylinder enrichment verification. The signatures and the radiation sensors designed to collect them are described, as are proof-of-principle cylinder measurements and analyses. Key sources of systematic uncertainty in the non-traditional signatures are discussed, and the potential benefits of utilizing these non-traditional signatures, in concert with an automated form of the traditional 185-keV-based assay, are discussed.

Smith, Leon E.; Mace, Emily K.; Misner, Alex C.; Shaver, Mark W.

2010-08-08T23:59:59.000Z

105

FAQ 23-How much depleted uranium -- including depleted uranium...  

NLE Websites -- All DOE Office Websites (Extended Search)

is stored in the United States? How much depleted uranium -- including depleted uranium hexafluoride -- is stored in the United States? In addition to the depleted uranium stored...

106

NGSI: IAEA Verification of UF6 Cylinders  

Science Conference Proceedings (OSTI)

The International Atomic Energy Agency (IAEA) is often ignorant of the location of declared, uranium hexafluoride (UF6) cylinders following verification, because cylinders are not typically tracked onsite or off. This paper will assess various methods the IAEA uses to verify cylinder gross defects, and how the task could be ameliorated through the use of improved identification and monitoring. The assessment will be restricted to current verification methods together with one that has been applied on a trial basisshort-notice random inspections coupled with mailbox declarations. This paper is part of the NNSA Office of Nonproliferation and International Securitys Next Generation Safeguards Initiative (NGSI) program to investigate the concept of a global monitoring scheme that uniquely identifies and tracks UF6 cylinders.

Curtis, Michael M.

2012-06-05T23:59:59.000Z

107

Transcript of Public Scoping Meeting for Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities at Portsmouth, Ohio, and Paducah, Kentucky, held Nov. 28, 2001, Piketon, Ohio  

NLE Websites -- All DOE Office Websites (Extended Search)

U.S. DEPARTMENT OF ENERGY ENVIRONMENTAL 2 IMPACT STATEMENT 3 FOR DEPLETED URANIUM HEXAFLUORIDE 4 CONVERSION FACILITIES 5 AT PORTSMOUTH, OHIO AND PADUCAH, KENTUCKY 6 7 SCOPING MEETING 8 9 November 28, 2001. 10 11 6:00 p.m. 12 13 Riffe Beavercreek Vocational School 14 175 Beavercreek Road 15 Piketon, Ohio 45661 16 17 FACILITATORS: Darryl Armstrong 18 Harold Munroe 19 Kevin Shaw 20 Gary Hartman 21 22 23 24 Professional Reporters, Inc. (614) 460-5000 or (800) 229-0675 2 1 -=0=- 2 PROCEEDINGS 3 -=0=- 4 MR. ARMSTRONG: I have 6:00, 5 according to my watch. Good evening, ladies 6 and gentlemen. If you'll please take your 7 seats, we'll get started. This meeting is 8 now officially convened. 9 On behalf of DOE, we thank you for 10 attending the environmental impact 11 statement, or EIS, scoping meeting this 12 evening for the depleted uranium conversion 13 facilities. My name is Darryl Armstrong. I 14

108

Tungsten Cladding of Tungsten-Uranium Dioxide (W-UO2) Composites by Deposition from Tungsten Hexafluoride (WF6)  

DOE Green Energy (OSTI)

?A program is being conducted to develop a process for cladding tungsten and tungsten cermet fuels with tungsten deposited from the vapor state by the hydrogen reduction of tungsten hexafluoride. Early work was performed using recrystallized, high purity, commercial tungsten as the substrate material. Temperatures in the range 660 to 12950F (350 to 1700C) and pressures from 10 to 350 mm Hg were investigated. Hydrogen to WF 6 ratios of 10: 1 to 150: 1 were utilized. Efforts were directed toward optimizing deposition process parameters to attain control of qualities such as coating thickness, uniformity, density, impurity content, and surface quality. Substrate penetration methods have been investigated in the interest of completely eliminating the interface between the fueled substrate and cladding. In addition, the effects of process parameters and post-cladding heat treatments on the fuel retention properties of clad composites at 4500 degrees F (2480 degrees C) in hydrogen for 2 hours have been evaluated. As a result of work performed during the first phase of the program it has been shown that the rate of deposition of tungsten from WF 6 and the uniformity of the deposit can be varied in a predictable and reproducible manner by exercising control over the temperature, pressure, and gas flow rates at which the deposits are produced. A significant result of the study is the discovery that substrate nucleation and epitaxial growth in deposits made on both unfueled tungsten and fueled substrates may be effected by pretreating the substrates in hydrogen. High temperature fuel retention testing of tungsten clad W-U02 at 45000F (2480 degrees C) in hydrogen for 2 hours has demonstrated that the vapor deposited layer effectively and consistently restricts fuel loss.

Lamartine, J.T.; Hoppe, A.W.

1965-02-15T23:59:59.000Z

109

Milestones Keep DUF6 Plants Moving Ahead | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Milestones Keep DUF6 Plants Moving Ahead Milestones Keep DUF6 Plants Moving Ahead Milestones Keep DUF6 Plants Moving Ahead May 30, 2013 - 12:00pm Addthis Cylinders containing depleted uranium hexafluoride. Cylinders containing depleted uranium hexafluoride. The depleted uranium hexafluoride conversion plant in Paducah. The depleted uranium hexafluoride conversion plant in Paducah. Workers inspect cylinders containing depleted uranium hexafluoride. Workers inspect cylinders containing depleted uranium hexafluoride. The operating room at a depleted uranium hexafluoride conversion plant. The operating room at a depleted uranium hexafluoride conversion plant. Cylinders containing depleted uranium hexafluoride. The depleted uranium hexafluoride conversion plant in Paducah. Workers inspect cylinders containing depleted uranium hexafluoride.

110

Highly Enriched Uranium Metal Annuli and Cylinders with Polyethylene Reflectors and/or Internal Polyethylene Moderator  

SciTech Connect

A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, experiments of uranium metal annuli with and without polyethylene reflectors and with the central void region either empty or filled with polyethylene were evaluated under ICSBEP Identifier HEU-MET-FAST-076. The outer diameter of the uranium annuli varied from 9 to 15 inches in two-inch increments. In addition, there were uranium metal cylinders with diameters varying from 7 to 15 inches with complete reflection and reflection on one flat surface to simulate floor reflection. Most of the experiments were performed between February 1964 and April 1964. Five partially reflected (reflected on the top only) experiments were assembled in November 1967, but are judged by the evaluators not to be of benchmark quality. Twenty-four of the twenty-five experiments have been determined to have fast spectra. The only exception has a mixed spectrum. Analyses were performed in which uncertainty associated with five different parameters associated with the uranium parts and three associated with the polyethylene parts was evaluated. Included were uranium mass, height, diameter, isotopic content, and impurity content and polyethylene mass, diameter, and impurity content. There were additional uncertainties associated with assembly alignment, support structure, and the value for eff. In addition to the idealizations made by the experimenters (removal of a diaphragm), a few simplifications were also made to the benchmark models that resulted in a small bias and additional uncertainty. Simplifications included omission of the support structure, possible surrounding equipment, and the walls, floor, and ceiling of the experimental cell. Bias values that result from these simplifications were determined and associated uncertainty in the bias values were included in the overall uncertainty in benchmark keff values. Bias values ranged from 0.0002 ?k to 0.0093 ?k below the experimental value. Overall uncertainties range from ? 0.0002 to ? 0.0011. Major contributors to the overall uncertainty include uncertainty in the support structure and the polyethylene parts. A comparison of experimental, benchmark-model, and MCNP-model keff values is shown in Figure 1. The experimental keff values are derived from the original reactivities reported by the principal experimentalist. The benchmark-model keff values are the experimental keff values adjusted to account for biases that were introduced by removing the support structure and surroundings. The MCNP-model keff values are simply the values found from MCNP calculations using the benchmark specifications and ENDF/B-VI cross-section data. Figure 1. Comparison of Experimental, Benchmark-Model and MCNP-Model keff value. Calculated results for most of the experiments are

Tyler Sumner; J. Blair Briggs; Leland Montierth

2007-05-01T23:59:59.000Z

111

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at Portsmouth, Ohio, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth DUF Portsmouth DUF 6 Conversion Final EIS FIGURE S-1 Regional Map of the Portsmouth, Ohio, Site Vicinity Summary S-18 Portsmouth DUF 6 Conversion Final EIS FIGURE S-3 Three Alternative Conversion Facility Locations within the Portsmouth Site, with Location A Being the Preferred Alternative (A representative conversion facility footprint is shown within each location.) Summary S-20 Portsmouth DUF 6 Conversion Final EIS FIGURE S-4 Conceptual Overall Material Flow Diagram for the Portsmouth Conversion Facility Summary S-21 Portsmouth DUF 6 Conversion Final EIS FIGURE S-5 Conceptual Conversion Facility Site Layout for Portsmouth Summary S-25 Portsmouth DUF 6 Conversion Final EIS FIGURE S-6 Potential Locations for Construction of a New Cylinder Storage Yard at Portsmouth

112

Production and Handling Slide 43: The Uranium Fuel Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Presentation Table of Contents The Uranium Fuel Cycle Refer to caption below for image description Enriched uranium hexafluoride, generally containing 3 to 5% uranium-235, is sent...

113

U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants  

SciTech Connect

The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

Leich, D., LLNL

1998-07-27T23:59:59.000Z

114

PRODUCTION OF URANIUM TETRAFLUORIDE  

DOE Patents (OSTI)

A method is presented for producing uranium tetrafluoride from the gaseous hexafluoride by feeding the hexafluoride into a high temperature zone obtained by the recombination of molecularly dissociated hydrogen. The molal ratio of hydrogen to uranium hexnfluoride is preferably about 3 to 1. Uranium tetrafluoride is obtained in a finely divided, anhydrous state.

Shaw, W.E.; Spenceley, R.M.; Teetzel, F.M.

1959-08-01T23:59:59.000Z

115

EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

60: Depleted Uranium Oxide Conversion Product at the 60: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site Summary This site-specific EIS analyzes the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three alternative locations within the Portsmouth site; transportation of all cylinders (DUF6, enriched, and empty) currently stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Portsmouth; construction of a new cylinder storage yard at Portsmouth (if required) for ETTP cylinders; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride

116

NGSI: FUNCTION REQUIREMENTS FOR A CYLINDER TRACKING SYSTEM  

SciTech Connect

While nuclear suppliers currently track uranium hexafluoride (UF{sub 6}) cylinders in various ways, for their own purposes, industry practices vary significantly. The NNSA Office of Nonproliferation and International Security's Next Generation Safeguards Initiative (NGSI) has begun a 5-year program to investigate the concept of a global monitoring scheme that uniquely identifies and tracks UF{sub 6} cylinders. As part of this effort, NGSI's multi-laboratory team has documented the 'life of a UF{sub 6} cylinder' and reviewed IAEA practices related to UF{sub 6} cylinders. Based on this foundation, this paper examines the functional requirements of a system that would uniquely identify and track UF{sub 6} cylinders. There are many considerations for establishing a potential tracking system. Some of these factors include the environmental conditions a cylinder may be expected to be exposed to, where cylinders may be particularly vulnerable to diversion, how such a system may be integrated into the existing flow of commerce, how proprietary data generated in the process may be protected, what a system may require in terms of the existing standard for UF{sub 6} cylinder manufacture or modifications to it and what the limiting technology factors may be. It is desirable that a tracking system should provide benefit to industry while imposing as few additional constraints as possible and still meeting IAEA safeguards objectives. This paper includes recommendations for this system and the analysis that generated them.

Branney, S.

2012-06-06T23:59:59.000Z

117

Next Generation Safeguards Initiative: Overview and Policy Context of UF6 Cylinder Tracking Program  

Science Conference Proceedings (OSTI)

Thousands of cylinders containing uranium hexafluoride (UF{sub 6}) move around the world from conversion plants to enrichment plants to fuel fabrication plants, and their contents could be very useful to a country intent on diverting uranium for clandestine use. Each of these large cylinders can contain close to a significant quantity of natural uranium (48Y cylinder) or low-enriched uranium (LEU) (30B cylinder) defined as 75 kg {sup 235}U which can be further clandestinely enriched to produce 1.5 to 2 significant quantities of high enriched uranium (HEU) within weeks or months depending on the scale of the clandestine facility. The National Nuclear Security Administration (NNSA) Next Generation Safeguards Initiative (NGSI) kicked off a 5-year plan in April 2011 to investigate the concept of a unique identification system for UF{sub 6} cylinders and potentially to develop a cylinder tracking system that could be used by facility operators and the International Atomic Energy Agency (IAEA). The goal is to design an integrated solution beneficial to both industry and inspectorates that would improve cylinder operations at the facilities and provide enhanced capabilities to deter and detect both diversion of low-enriched uranium and undeclared enriched uranium production. The 5-year plan consists of six separate incremental tasks: (1) define the problem and establish the requirements for a unique identification (UID) and monitoring system; (2) develop a concept of operations for the identification and monitoring system; (3) determine cylinder monitoring devices and technology; (4) develop a registry database to support proof-of-concept demonstration; (5) integrate that system for the demonstration; and (6) demonstrate proof-of-concept. Throughout NNSA's performance of the tasks outlined in this program, the multi-laboratory team emphasizes that extensive engagement with industry stakeholders, regulatory authorities and inspectorates is essential to its success.

Boyer, Brian D [Los Alamos National Laboratory; Whitaker, J. Michael [ORNL; White-Horton, Jessica L. [ORNL; Durbin, Karyn R. [NNSA

2012-07-12T23:59:59.000Z

118

DOE Selects Contractor for Depleted Hexafluoride Conversion Project Support  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Selects Contractor for Depleted Hexafluoride Conversion Project DOE Selects Contractor for Depleted Hexafluoride Conversion Project Support DOE Selects Contractor for Depleted Hexafluoride Conversion Project Support March 25, 2013 - 12:00pm Addthis Media Contact Bill Taylor, 803-952-8564 Bill.Taylor@srs.gov Cincinnati - The U.S. Department of Energy (DOE) today awarded a competitive small business task order to Navarro Research and Engineering Inc. of Oak Ridge, Tennessee. The award is a $22 million, time and materials task order with a three-year performance period and two one-year extension options. Navarro Research and Engineering Inc. will provide engineering and operations technical support services to the DOE Portsmouth Paducah Project Office (PPPO) in Lexington, Kentucky and the Depleted Uranium Hexafluoride (DUF6) Conversion Project in Paducah, Kentucky and Portsmouth, Ohio.

119

DOE Selects Contractor for Depleted Hexafluoride Conversion Project Support  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contractor for Depleted Hexafluoride Conversion Project Contractor for Depleted Hexafluoride Conversion Project Support DOE Selects Contractor for Depleted Hexafluoride Conversion Project Support March 25, 2013 - 12:00pm Addthis Media Contact Bill Taylor, 803-952-8564 Bill.Taylor@srs.gov Cincinnati - The U.S. Department of Energy (DOE) today awarded a competitive small business task order to Navarro Research and Engineering Inc. of Oak Ridge, Tennessee. The award is a $22 million, time and materials task order with a three-year performance period and two one-year extension options. Navarro Research and Engineering Inc. will provide engineering and operations technical support services to the DOE Portsmouth Paducah Project Office (PPPO) in Lexington, Kentucky and the Depleted Uranium Hexafluoride (DUF6) Conversion Project in Paducah, Kentucky and Portsmouth, Ohio.

120

Correlation of radioactive-waste-treatment costs and the environmental impact of waste effluents in the nuclear fuel cycle: conversion of yellow cake to uranium hexafluoride. Part II. The solvent extraction-fluorination process  

Science Conference Proceedings (OSTI)

A cost/benefit study was made to determine the cost and effectiveness of radioactive waste (radwaste) treatment systems for decreasing the release of radioactive materials and chemicals from a model uranium hexafluoride (UF/sub 6/) production plant using the solvent extraction-fluorination process, and to evaluate the radiological impact (dose commitment) of the release materials on the environment. The model plant processes 10,000 metric tons of uranium per year. Base-case waste treatment is the minimum necessary to operate the process. Effluents meet the radiological requirements listed in the Code of Federal Regulations, Title 10, Part 20 (10 CFR 20), Appendix B, Table II, but may not be acceptable chemically at all sites. Additional radwaste treatment techniques are applied to the base-case plant in a series of case studies to decrease the amounts of radioactive materials released and to reduce the amounts of radioactive materials released and to reduce the radiological dose commitment to the population in the surrounding area. The costs for the added waste treatment operations and the corresponding dose committment are correlated with the annual cost for treatment of the radwastes. The status of the radwaste treatment methods used in the case studies is discussed. Much of the technology used in the advanced cases will require development and demonstration, or else is proprietary and unavailable for immediate use. The methodology and assumptions for the radiological doses are found in ORNL-4992.

Sears, M.B.; Etnier, E.L.; Hill, G.S.; Patton, B.D.; Witherspoon, J.P.; Yen, S.N.

1983-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
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121

THE RECOVERY OF URANIUM FROM GAS MIXTURE  

DOE Patents (OSTI)

A method of separating uranium from a mixture of uranium hexafluoride and other gases is described that comprises bringing the mixture into contact with anhydrous calcium sulfate to preferentially absorb the uranium hexafluoride on the sulfate. The calcium sulfate is then leached with a selective solvent for the adsorbed uranium. (AEC)

Jury, S.H.

1964-03-17T23:59:59.000Z

122

Production and Handling Slide 5: The Uranium Fuel Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Refer to caption below for image description The third step in the uranium fuel cycle involves the conversion of "yellowcake" to uranium hexafluoride (UF6), the chemical form...

123

Production and Handling Slide 37: The Uranium Fuel Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Table of Contents The Uranium Fuel Cycle Refer to caption below for image description The enrichment process generates two streams of uranium hexafluoride, one enriched in...

124

Releases of UF{sub 6} to the atmosphere after a potential fire in a cylinder storage yard  

Science Conference Proceedings (OSTI)

Uranium hexafluoride (UF{sub 6}), a toxic material, is stored in just over 6200 cylinders at the K-25 site in Oak Ridge, Tennessee. The safety analysis report (SAR) for cylinder yard storage operations at the plant required the development of accident scenarios for the potential release of UF{sub 6} to the atmosphere. In accordance with DOE standards and guidance, the general approach taken in this SAR was to examine the functions and contents of the cylinder storage yards to determine whether safety-significant hazards were present for workers in the immediate vicinity, workers on-site, the general public off-site, or the environment. and to evaluate the significance of any hazards that were found. A detailed accident analysis was performed to determine a set of limiting accidents that have potential for off-site consequences. One of the limiting accidents identified in the SAR was the rupture of a cylinder engulfed in a fire.

Lombardi, D.A.; Williams, W.R.; Anderson, J.C. [and others

1997-06-01T23:59:59.000Z

125

Overview: A Legacy of Uranium Enrichment  

NLE Websites -- All DOE Office Websites (Extended Search)

A Legacy of Uranium Enrichment Depleted Uranium is a Legacy of Uranium Enrichment Cylinders Photo Next Screen Management Responsibilities...

126

Prediction of External Corrosion for Steel Cylinders--2004 Report  

Science Conference Proceedings (OSTI)

Depleted uranium hexafluoride (UF{sub 6}) is stored in over 60,000 steel cylinders at the East Tennessee Technology Park (ETTP) in Oak Ridge, Tennessee, at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky, and at the Portsmouth Gaseous Diffusion Plant (PORTS) in Portsmouth, Ohio. The cylinders range in age from 4 to 53 years. Although when new the cylinders had wall thicknesses specified to within manufacturing tolerances, over the years corrosion has reduced their actual wall thicknesses. The UF{sub 6} Cylinder Project is managed by the United States Department of Energy (DOE) to safely maintain the UF{sub 6} and the cylinders containing it. This report documents activities that address UF{sub 6} Cylinder Project requirements and actions involving forecasting cylinder wall thicknesses. These requirements are delineated in the System Requirements Document (LMES 1997a), and the actions needed to fulfill them are specified in the System Engineering Management Plan (LMES 1997b). The report documents cylinder wall thickness projections based on models fit to ultrasonic thickness (UT) measurement data. UT data is collected at various locations on randomly sampled cylinders. For each cylinder sampled, the minimum UT measurement approximates the actual minimum thickness of the cylinder. Projections of numbers of cylinders expected to fail various thickness criteria are computed from corrosion models relating minimum wall thickness to cylinder age, initial thickness estimates, and cylinder subpopulations defined in terms of plant site, yard, top or bottom storage positions, nominal thickness, etc. In this report, UT data collected during FY03 is combined with UT data collected in earlier years (FY94-FY02), and all of the data is inventoried chronologically and by various subpopulations. The UT data is used to fit models of maximum pit depth and minimum thickness, and the fitted models are used to extrapolate minimum thickness estimates into the future and in turn to compute estimates of numbers of cylinders expected to fail various thickness criteria. A model evaluation is performed comparing UT measurements made in FY03 with model-fitted projections based only on data collected before FY03.

Schmoyer, RLS

2004-07-07T23:59:59.000Z

127

Prediction of external corrosion for steel storage cylinders  

Science Conference Proceedings (OSTI)

The US Department of Energy (DOE) currently manages the UF{sub 6} Cylinder Program (the program). The program was formed to address the depleted-uranium hexafluoride (UF{sub 6}) stored in approximately 50,000 carbon steel cylinders. The cylinders are located at three DOE sites: the K-25 site (K-25) at Oak Ridge, Tennessee; the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky, and the Portsmouth Gaseous Diffusion Plant (PORTS) in Portsmouth, Ohio. The System Requirements Document (SRD) (LMES 1996a) delineates the requirements of the program. The appropriate actions needed to fulfill these requirements are then specified within the System Engineering Management Plan (SEMP) (LMES 1996b). The report presented herein documents activities that in whole or in part satisfy specific requirements and actions stated in the UF{sub 6} Cylinder Program SRD and SEMP with respect to forecasting cylinder conditions. The wall thickness projections made in this report are based on the assumption that the corrosion trends noted will continue. Some activities planned may substantially reduce the rate of corrosion, in which case the results presented here are conservative. The results presented here are intended to supersede those presented previously, as the quality of several of the datasets has improved.

Lyon, B.F.

1997-02-01T23:59:59.000Z

128

Methods and results for stress analyses on 14-ton, thin-wall depleted UF{sub 6} cylinders  

Science Conference Proceedings (OSTI)

Uranium enrichment operations at the three US gaseous diffusion plants produce depleted uranium hexafluoride (DUF{sub 6}) as a residential product. At the present time, the inventory of DUF{sub 6} in this country is more than half a million tons. The inventory of DUF{sub 6} is contained in metal storage cylinders, most of which are located at the gaseous diffusion plants. The principal objective of the project is to ensure the integrity of the cylinders to prevent causing an environmental hazard by releasing the contents of the cylinders into the atmosphere. Another objective is to maintain the cylinders in such a manner that the DUF{sub 6} may eventually be converted to a less hazardous material for final disposition. An important task in the DUF{sub 6} cylinders management project is determining how much corrosion of the walls can be tolerated before the cylinders are in danger of being damaged during routine handling and shipping operations. Another task is determining how to handle cylinders that have already been damaged in a manner that will minimize the chance that a breach will occur or that the size of an existing breach will be significantly increased. A number of finite element stress analysis (FESA) calculations have been done to analyze the stresses for three conditions: (1) while the cylinder is being lifted, (2) when a cylinder is resting on two cylinders under it in the customary two-tier stacking array, and (3) when a cylinder is resting on tis chocks on the ground. Various documents describe some of the results and discuss some of the methods whereby they have been obtained. The objective of the present report is to document as many of the FESA cases done at Oak Ridge for 14-ton thin-wall cylinders as possible, giving results and a description of the calculations in some detail.

Kirkpatrick, J.R.; Chung, C.K.; Frazier, J.L.; Kelley, D.K.

1996-10-01T23:59:59.000Z

129

PRODUCTION OF URANIUM TETRACHLORIDE  

DOE Patents (OSTI)

A process is descrlbed for the production of uranium tetrachloride by contacting uranlum values such as uranium hexafluoride, uranlum tetrafluoride, or uranium oxides with either aluminum chloride, boron chloride, or sodium alumlnum chloride under substantially anhydrous condltlons at such a temperature and pressure that the chlorldes are maintained in the molten form and until the uranium values are completely converted to uranlum tetrachloride.

Calkins, V.P.

1958-12-16T23:59:59.000Z

130

Process for producing enriched uranium having a {sup 235}U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage  

DOE Patents (OSTI)

An uranium enrichment process capable of producing an enriched uranium, having a {sup 235}U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower {sup 235}U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF{sub 6} tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a {sup 235} U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % {sup 235} U; fluorinating this enriched metallic uranium isotopic mixture to form UF{sub 6}; processing the resultant isotopic mixture of UF{sub 6} in a gaseous diffusion process to produce a final enriched uranium product having a {sup 235}U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low {sup 235}U content UF{sub 6} having a {sup 235}U content of about 0.71 wt. % of the total uranium content of the low {sup 235}U content UF{sub 6}; and converting this low {sup 235}U content UF{sub 6} to metallic uranium for recycle to the atomic vapor laser isotope separation process. 4 figs.

Horton, J.A.; Hayden, H.W. Jr.

1995-05-30T23:59:59.000Z

131

Process for producing enriched uranium having a .sup.235 U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage  

DOE Patents (OSTI)

An uranium enrichment process capable of producing an enriched uranium, having a .sup.235 U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower .sup.235 U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF.sub.6 tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a .sup.235 U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % .sup.235 U; fluorinating this enriched metallic uranium isotopic mixture to form UF.sub.6 ; processing the resultant isotopic mixture of UF.sub.6 in a gaseous diffusion process to produce a final enriched uranium product having a .sup.235 U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low .sup.235 U content UF.sub.6 having a .sup.235 U content of about 0.71 wt. % of the total uranium content of the low .sup.235 U content UF.sub.6 ; and converting this low .sup.235 U content UF.sub.6 to metallic uranium for recycle to the atomic vapor laser isotope separation process.

Horton, James A. (Livermore, CA); Hayden, Jr., Howard W. (Oakridge, TN)

1995-01-01T23:59:59.000Z

132

A "Proof-of-Concept" Demonstration of RF-Based Technologies for UF6 Cylinder Tracking at Centrifuge Enrichment Plant  

SciTech Connect

This effort describes how radio-frequency (RF) technology can be integrated into a uranium enrichment facility's nuclear materials accounting and control program to enhance uranium hexafluoride (UF6) cylinder tracking and thus provide benefits to both domestic and international safeguards. Approved industry-standard cylinders are used to handle and store UF6 feed, product, tails, and samples at uranium enrichment plants. In the international arena, the International Atomic Energy Agency (IAEA) relies on time-consuming manual cylinder inventory and tracking techniques to verify operator declarations and to detect potential diversion of UF6. Development of a reliable, automated, and tamper-resistant process for tracking and monitoring UF6 cylinders would greatly reduce the risk of false or misreported cylinder tare weights, diversion of nuclear material, concealment of excess production, utilization of undeclared cylinders, and misrepresentation of the cylinders contents. This paper will describe a "proof-of concept" system that was designed show the feasibility of using RF based technologies to track individual UF6 cylinders throughout their entire life cycle, and thus ensure both increased domestic accountability of materials and a more effective and efficient method for application of IAEA international safeguards at the site level. The proposed system incorporates RF-based identification devices, which provide a mechanism for a reliable, automated, and tamper-resistant tracking network. We explore how securely attached RF tags can be integrated with other safeguards technologies to better detect diversion of cylinders. The tracking system could also provide a foundation for integration of other types of safeguards that would further enhance detection of undeclared activities.

Pickett, Chris A [ORNL; Younkin, James R [ORNL; Kovacic, Donald N [ORNL; Dixon, E. T. [Los Alamos National Laboratory (LANL); Martinez, B. [Los Alamos National Laboratory (LANL)

2007-01-01T23:59:59.000Z

133

Prediction of External Corrosion for Steel Cylinders--2007 Report  

Science Conference Proceedings (OSTI)

Depleted uranium hexafluoride (DUF{sub 6}) is stored in over 62,000 containment cylinders at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky, and at the Portsmouth Gaseous Diffusion Plant (PORTS) in Portsmouth, Ohio. Over 4,800 of the cylinders at Portsmouth were recently moved there from the East Tennessee Technology Park (ETTP) in Oak Ridge, Tennessee. The cylinders range in age up to 56 years and come in various models, but most are 48-inch diameter 'thin-wall'(312.5 mil) and 'thick-wall' (625 mil) cylinders and 30-inch diameter '30A' (including '30B') cylinders with 1/2-inch (500 mil) walls. Most of the cylinders are carbon steel, and they are subject to corrosion. The United States Department of Energy (DOE) manages the cylinders to maintain them and the DUF{sub 6} they contain. Cylinder management requirements are specified in the System Requirements Document (LMES 1997a), and the activities to fulfill them are specified in the System Engineering Management Plan (LMES 1997b). This report documents activities that address DUF{sub 6} cylinder management requirements involving measuring and forecasting cylinder wall thicknesses. As part of these activities, ultrasonic thickness (UT) measurements are made on samples of cylinders. For each sampled cylinder, multiple measurements are made in an attempt to find, approximately, the minimum wall thickness. Some cylinders have a skirt, which is an extension of the cylinder wall to protect the head (end) and valve. The head/skirt interface crevice is thought to be particularly vulnerable to corrosion, and for some skirted cylinders, in addition to the main body UT measurements, a separate suite of measurements is also made at the head/skirt interface. The main-body and head/skirt minimum thickness data are used to fit models relating minimum thickness to cylinder age, nominal thicknesses, and cylinder functional groups defined in terms of plant site, storage yard, top or bottom row storage positions, etc. These models are then used to compute projections of numbers of cylinders expected to fail various minimum wall thickness criteria. The minimum wall thickness criteria are as follows. For thin-wall cylinders: 0 (breach), 62.5, and 250 mils. For thick-wall cylinders: 0, 62.5, and 500 mils. For 30A cylinders: 0, 62.5, and 100 mils. Each of these criteria triplets are based respectively on (1) loss of DUF{sub 6} (breaching), (2) safe handling and stacking operations, and (3) ANSI N14.1 standards for off-site transport and contents transfer. This report complements and extends previous editions of the cylinder corrosion report by Lyon (1995, 1996, 1997, 1998, 2000), by Schmoyer and Lyon (2001, 2002, 2003), and by Schmoyer (2004). These reports are based on UT data collected in FY03 and before. In this report UT data collected after FY03 but before FY07 is combined with the earlier data, and all of the UT data is inventoried chronologically and by the various functional groups. The UT data is then used to fit models of maximum pit depth and minimum wall thickness, statistical outliers are investigated, and the fitted models are used to extrapolate minimum thickness estimates into the future and in turn to compute projections of numbers of cylinders expected to fail various thickness criteria. A model evaluation is performed comparing UT measurements made after FY05 with model-fitted projections based only on data collected in FY05 and before. As in previous reports, the projections depend on the treatment of outliers.

Schmoyer, Richard L [ORNL

2008-01-01T23:59:59.000Z

134

Derived enriched uranium market  

SciTech Connect

The potential impact on the uranium market of highly enriched uranium from nuclear weapons dismantling in the Russian Federation and the USA is analyzed. Uranium supply, conversion, and enrichment factors are outlined for each country; inventories are also listed. The enrichment component and conversion components are expected to cause little disruption to uranium markets. The uranium component of Russian derived enriched uranium hexafluoride is unresolved; US legislation places constraints on its introduction into the US market.

Rutkowski, E.

1996-12-01T23:59:59.000Z

135

Status Report on the Passive Neutron Enrichment Meter (PNEM) for UF6 Cylinder Assay  

SciTech Connect

The Passive Neutron Enrichment Meter (PNEM) is a nondestructive assay (NDA) system being developed at Los Alamos National Laboratory (LANL). It was designed to determine {sup 235}U mass and enrichment of uranium hexafluoride (UF{sub 6}) in product, feed, and tails cylinders (i.e., 30B and 48Y cylinders). These cylinders are found in the nuclear fuel cycle at uranium conversion, enrichment, and fuel fabrication facilities. The PNEM is a {sup 3}He-based neutron detection system that consists of two briefcase-sized detector pods. A photograph of the system during characterization at LANL is shown in Fig. 1. Several signatures are currently being studied to determine the most effective measurement and data reduction technique for unfolding {sup 235}U mass and enrichment. The system collects total neutron and coincidence data for both bare and cadmium-covered detector pods. The measurement concept grew out of the success of the Uranium Cylinder Assay System (UCAS), which is an operator system at Rokkasho Enrichment Plant (REP) that uses total neutron counting to determine {sup 235}U mass in UF{sub 6} cylinders. The PNEM system was designed with higher efficiency than the UCAS in order to add coincidence counting functionality for the enrichment determination. A photograph of the UCAS with a 48Y cylinder at REP is shown in Fig. 2, and the calibration measurement data for 30B product and 48Y feed and tails cylinders is shown in Fig. 3. The data was collected in a low-background environment, meaning there is very little scatter in the data. The PNEM measurement concept was first presented at the 2010 Institute of Nuclear Materials Management (INMM) Annual Meeting. The physics design and uncertainty analysis were presented at the 2010 International Atomic Energy Agency (IAEA) Safeguards Symposium, and the mechanical and electrical designs and characterization measurements were published in the ESARDA Bulletin in 2011.

Miller, Karen A. [Los Alamos National Laboratory; Swinhoe, Martyn T. [Los Alamos National Laboratory; Menlove, Howard O. [Los Alamos National Laboratory; Marlow, Johnna B. [Los Alamos National Laboratory

2012-05-02T23:59:59.000Z

136

Transcript of Public Scoping Meeting for Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities at Portsmouth, Ohio, and Paducah, Kentucky, held Dec. 4, 2001, Oak Ridge, Tennessee  

NLE Websites -- All DOE Office Websites (Extended Search)

TRANSCRIPT TRANSCRIPT OF MEETING ______________________________________________________ FACILITATOR: MR. DARRYL ARMSTRONG SPEAKER: MR. DALE RECTOR SPEAKER: MR. NORMAN MULVENON SPEAKER: MS. SUSAN GAWARECKI SPEAKER: MR. GENE HOFFMAN DECEMBER 4, 2001 ____________________________________________________ JOAN S. ROBERTS COURT REPORTER P.O. BOX 5924 OAK RIDGE, TENNESSEE 37831 (865-457-4027) 2 1 MR. ARMSTRONG: TAKE YOUR SEATS AND WE 2 WILL BEGIN THE MEETING. GOOD EVENING, LADIES 3 AND GENTLEMEN. IF YOU WILL, WE WILL START, THE 4 TIME IS NOW 6:02 P.M. THE MEETING IS 5 OFFICIALLY CONVENED. ON BEHALF OF THE 6 DEPARTMENT OF ENERGY, WE THANK YOU FOR 7 ATTENDING THIS ENVIRONMENTAL IMPACT STATEMENT 8 SCOPING MEETING, ALSO KNOWN AS AN EIS SCOPING 9 MEETING, FOR THE DEPLETED URANIUM CONVERSION 10 FACILITIES. MY NAME IS DARRYL ARMSTRONG. I'M 11 AN INDEPENDENT AND NEUTRAL FACILITATOR HIRED BY 12 AGENCIES

137

Benchmark Evaluation of Uranium Metal Annuli and Cylinders with Beryllium Reflectors  

SciTech Connect

An extensive series of delayed critical experiments were performed at the Oak Ridge Critical Experiments Facility using enriched uranium metal during the 1960s and 1970s in support of criticality safety operations at the Y-12 Plant. These experiments were designed to evaluate the storage, casting, and handling limits of the Y-12 Plant and to provide data for the verification of cross sections and calculation methods utilized in nuclear criticality safety applications. Many of these experiments have already been evaluated and included in the International Criticality Safety Benchmark Evaluation Project (ICSBEP) Handbook: unreflected (HEU-MET-FAST-051), graphite-reflected (HEU-MET-FAST-071), and polyethylene-reflected (HEU-MET-FAST-076). Three of the experiments consisted of highly-enriched uranium (HEU, ~93.2% 235U) metal parts reflected by beryllium metal discs. The first evaluated experiment was constructed from a stack of 7-in.-diameter, 4-1/8-in.-high stack of HEU discs top-reflected by a 7-in.-diameter, 5-9/16-in.-high stack of beryllium discs. The other two experiments were formed from stacks of concentric HEU metal annular rings surrounding a 7-in.diameter beryllium core. The nominal outer diameters were 13 and 15 in. with a nominal stack height of 5 and 4 in., respectively. These experiments have been evaluated for inclusion in the ICSBEP Handbook.

John D. Bess

2010-06-01T23:59:59.000Z

138

Corrosion monitoring in the UF{sub 6} cylinder yards at the Oak Ridge K-25 Site: FY 1994 report  

Science Conference Proceedings (OSTI)

Depleted uranium hexafluoride (UF{sub 6}) at the U.S. Department of Energy`s K-25 Site at Oak Ridge, Tennessee, has been stored in large steel cylinders that have undergone significant atmospheric corrosion damage over the last 35 years. A detailed experimental program to characterize the corrosion damage was initiated in 1992. Large amounts of corrosion scale and deep pits are found to cover UF{sub 6} cylinder surfaces. Ultrasonic wall thickness measurements have shown uniform corrosion losses up to 20 mils (0.5 mm) and pits up to 100 mils (2.5 mm) deep. Electrical resistance corrosion probes, TOW sensors, and thermocouples have been attached to cylinder bodies. Atmospheric conditions are monitored using rain gauges, relative humidity sensors, and thermocouples. Long-term (16-year) data are being obtained from mild steel corrosion coupons on test racks as well as attached directly to cylinder surfaces. Corrosion rates have been found to be intimately related to the times-of-wetness, both tending to be higher on cylinder tops due to apparent sheltering effects. Data from the various tests are compared, discrepancies are discussed, and a pattern of cylinder corrosion as a function of cylinder position and location is described.

Rao, M. [Midwest Technical Inc., Oak Ridge, TN (United States); Adamski, R.; Broders, J.; Ellis, A.; Freels, D.; Kelley, D.; Phillips, B. [Oak Ridge K-25 Site, TN (United States)

1994-10-01T23:59:59.000Z

139

Prediction of external corrosion for steel cylinders at the Paducah Gaseous Diffusion Plant: Application of an empirical method  

Science Conference Proceedings (OSTI)

During the summer of 1995, ultrasonic wall thickness data were collected for 100 steel cylinders containing depleted uranium (DU) hexafluoride located at Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The cylinders were selected for measurement to assess the condition of the more vulnerable portion of the cylinder inventory at PGDP. The purpose of this report is to apply the method used in Lyon to estimate the effects of corrosion for larger unsampled populations as a function of time. The scope of this report is limited and is not intended to represent the final analyses of available data. Future efforts will include continuing analyses of available data to investigate defensible deviations from the conservative assumptions made to date. For each cylinder population considered, two basic types of analyses were conducted: (1) estimates were made of the number of cylinders as a function of time that will have a minimum wall thickness of either 0 mils (1 mil = 0.00 1 in.) or 250 mils and (2) the current minimum wall thickness distributions across cylinders were estimated for each cylinder population considered. Additional analyses were also performed investigating comparisons of the results for F and G yards with the results presented in Lyon (1995).

Lyon, B.F.

1996-02-01T23:59:59.000Z

140

New Prototype Safeguards Technology Offers Improved Confidence and Automation for Uranium Enrichment Facilities  

Science Conference Proceedings (OSTI)

An important requirement for the international safeguards community is the ability to determine the enrichment level of uranium in gas centrifuge enrichment plants and nuclear fuel fabrication facilities. This is essential to ensure that countries with nuclear nonproliferation commitments, such as States Party to the Nuclear Nonproliferation Treaty, are adhering to their obligations. However, current technologies to verify the uranium enrichment level in gas centrifuge enrichment plants or nuclear fuel fabrication facilities are technically challenging and resource-intensive. NNSAs Office of Nonproliferation and International Security (NIS) supports the development, testing, and evaluation of future systems that will strengthen and sustain U.S. safeguards and security capabilitiesin this case, by automating the monitoring of uranium enrichment in the entire inventory of a fuel fabrication facility. One such system is HEVAhybrid enrichment verification array. This prototype was developed to provide an automated, nondestructive assay verification technology for uranium hexafluoride (UF6) cylinders at enrichment plants.

Brim, Cornelia P.

2013-03-04T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

MCNP-DSP calculations of the {sup 252}Cf-source-driven noise analysis measurements of highly enriched uranium metal cylinders  

SciTech Connect

This paper presents calculations of the {sup 252}Cf-source-driven noise analysis measurements for subcritical highly enriched uranium metal cylinders using the Monte Carlo code MCNP-DSP. This code directly calculates the noise analysis data from the {sup 252}Cf- source-driven noise analysis method for both neutron and gamma ray detectors. Direct calculation of experimental observables by the Monte Carlo method allows for the benchmarking of the calculational model and the cross sections and for determining the bias in the calculation.

Valentine, T.E.; Mihalczo, J.T.

1995-07-01T23:59:59.000Z

142

Depleted Uranium Hexafluoride Management Program: Data Compilation...  

NLE Websites -- All DOE Office Websites (Extended Search)

Code USEC United States Enrichment Corporation Chemicals AlF 3 aluminum trifluoride CaF 2 calcium fluoride CO carbon monoxide Fe iron HF hydrogen fluoride HNO 3 nitric acid Mg...

143

Depleted Uranium Hexafluoride Materials Use Roadmap  

NLE Websites -- All DOE Office Websites (Extended Search)

8 8 U.S. Department of Energy DUF 6 MATERIALS USE ROADMAP Edited by: M. Jonathan Haire Allen G. Croff August 27, 2001 DUF 6 Materials Use Workshop Participants August 24-25, 1999 Name Organization Halil Avci ANL Bob Bernero Consultant Lavelle Clark PNNL Carl Cooley DOE/EM-50 Allen Croff ORNL Juan Ferrada ORNL Charles Forsberg ORNL John Gasper ANL Bob Hightower ORNL Julian Hill PNNL Ed Jones LLNL Asim Khawaja PNNL George Larson Consultant Paul Lessing INEEL Dan O'Connor ORNL Robert Price DOE/NE-30 Nancy Ranek ANL Mark Senderling DOE/RW-46 Roger Spence ORNL John Tseng DOE/EM-21 John Warren DOE/NE-30 Ken Young LLNL iii CONTENTS ACRONYMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v EXECUTIVE SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . .

144

RESULTS FROM A DEMONSTRATION OF RF-BASED UF6 CYLINDER ACCOUNTING AND TRACKING SYSTEM INSTALLED AT A USEC FACILITY  

SciTech Connect

Approved industry-standard cylinders are used globally for storing and transporting uranium hexafluoride (UF{sub 6}) at uranium enrichment plants and processing facilities. To verify that no diversion or undeclared production of nuclear material involving UF{sub 6} cylinders at the facility has occurred, the International Atomic Energy Agency (IAEA) conducts periodic, labor-intensive physical inspections to validate facility records, cylinder identities, and cylinder weights. A reliable cylinder monitoring system that would improve overall inspector effectiveness would be a significant improvement to the current international safeguards inspection regime. Such a system could include real-time unattended monitoring of cylinder movements, situation-specific rules-based event detection algorithms, and the capability to integrate with other types of safeguards technologies. This type of system could provide timely detection of abnormal operational activities that may be used to ensure more appropriate and efficient responses by the IAEA. A system of this type can reduce the reliance on paper records and have the additional benefit of facilitating domestic safeguards at the facilities at which it is installed. A radio-frequency (RF)-based system designed to track uranium hexafluoride (UF{sub 6}) cylinders during processing operations was designed, assembled, and tested at the United States Enrichment Corporation (USEC) facility in Portsmouth, Ohio, to determine the operational feasibility and durability of RF technology. The overall objective of the effort was to validate the robustness of RF technology for potential use as a future international safeguards tool for tracking UF6 cylinders at uranium-processing facilities. The results to date indicate that RF tags represent a feasible technique for tracking UF{sub 6} cylinders in operating facilities. Additional work will be needed to improve the operational robustness of the tags for repeated autoclave processing and to add tamper-indicating and data authentication features to some of the pertinent system components. Future efforts will focus on these needs along with implementing protocols relevant to IAEA safeguards. The work detailed in this report demonstrates the feasibility of constructing RF devices that can survive the operational rigors associated with the transportation, storage, and processing of UF6 cylinders. The system software specially designed for this project is called Cylinder Accounting and Tracking System (CATS). This report details the elements of the CATS rules-based architecture and its use in safeguards-monitoring and asset-tracking applications. Information is also provided on improvements needed to make the technology ready, as well as options for improving the safeguards aspects of the technology. The report also includes feedback from personnel involved in the testing, as well as individuals who could utilize an RF-based system in supporting the performance of their work. The system software was set up to support a Mailbox declaration, where a declaration can be made either before or after cylinder movements take place. When the declaration is made before cylinders move, the operators must enter this information into CATS. If the IAEA then shows up unexpectedly at the facility, they can see how closely the operational condition matches the declaration. If the declaration is made after the cylinders move, this provides greater operational flexibility when schedules are interrupted or are changed, by allowing operators to declare what moves have been completed. The IAEA can then compare where cylinders are with where CATS or the system says they are located. The ability of CATS to automatically generate Mailbox declarations is seen by the authors as a desirable feature. The Mailbox approach is accepted by the IAEA but has not been widely implemented (and never in enrichment facilities). During the course of this project, we have incorporated alternative methods for implementation.

Pickett, Chris A [ORNL; Kovacic, Donald N [ORNL; Morgan, Jim [Innovative Solutions; Younkin, James R [ORNL; Carrick, Bernie [USEC; Ken, Whittle [USEC; Johns, R E [Pacific Northwest National Laboratory (PNNL)

2008-09-01T23:59:59.000Z

145

Prediction of External Corrosion for Steel Cylinders 2003 Report  

Science Conference Proceedings (OSTI)

Depleted uranium hexafluoride (UF{sub 6}) is stored in over 60,000 steel cylinders at the East Tennessee Technology Park (ETTP) in Oak Ridge, Tennessee, at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky, and at the Portsmouth Gaseous Diffusion Plant (PORTS) in Portsmouth, Ohio. The cylinders range in age from six to 52 years. Although when new the cylinders had wall thicknesses specified to within manufacturing tolerances, over the years corrosion has reduced their actual wall thicknesses. The UF{sub 6} Cylinder Project is managed by the United States Department of Energy (DOE) to safely maintain the UF{sub 6} and the cylinders containing it. The requirements of the Project are delineated in the System Requirements Document (LMES 1997a), and the actions needed to fulfill those requirements are specified in the System Engineering Management Plan (LMES 1997b). This report documents activities that address requirements and actions involving forecasting cylinder wall thicknesses. Wall thickness forecasts are based on models fit to ultrasonic thickness (UT) measurement data. First, UT data collected during FY02 is combined with UT data collected in earlier years (FY92-FY01), and all of the data is inventoried chronologically and by various subpopulations. Next, the data is used to model either maximum pit depth or minimum thickness as a function of cylinder age, subpopulation (e.g., PGDP G-yard, bottom-row cylinders), and initial thickness estimates. The fitted models are then used to extrapolate minimum thickness estimates into the future and to compute estimates of numbers of cylinders expected to fail various thickness criteria. A model evaluation is performed comparing UT measurements made in FY02 with model-fitted projections based only on data collected before FY02. The FY02 UT data, entered into the corrosion model database and not available for the previous edition of this report (Schmoyer and Lyon 2002), consists of thickness measurements of 48'' thin-wall cylinders: 102 cylinders at Paducah, 104 at ETTP, and 117 at Portsmouth; and 72 thick-wall cylinders at Portsmouth. However, because of missing values, repeated measures on the same cylinders, outliers, and other data problems, not all of these measurements are necessarily used in the corrosion analysis, and some previous measurements may simply be replaced with the new ones. In this edition of the report, cylinder subpopulation definitions and counts are updated using the latest (as of June 2003) information from the Cylinder Inventory Database (CID). Cylinders identified in the CID as painted during the last ten years are excluded from subpopulations considered at-risk of failing minimum thickness criteria, because it is assumed that painting fully arrests corrosion for ten years. As in the previous edition of the report, two different approaches to corrosion modeling are pursued: (1) a direct approach in which minimum thickness is modeled directly as a function of age, subpopulation, and initial thickness estimates; and (2) an indirect approach, in which maximum pit depth is modeled, and the pit-depth model is then combined with a model of initial thickness to compute estimates of minimum thickness.

Schmoyer, RLS

2003-09-24T23:59:59.000Z

146

Evaluation of coverage of enriched UF{sub 6} cylinder storage lots by existing criticality accident alarms  

SciTech Connect

The Portsmouth Gaseous Diffusion Plant (PORTS) is leased from the US Department of Energy (DOE) by the United States Enrichment Corporation (USEC), a government corporation formed in 1993. PORTS is in transition from regulation by DOE to regulation by the Nuclear Regulatory Commission (NRC). One regulation is 10 CFR Part 76.89, which requires that criticality alarm systems be provided for the site. PORTS originally installed criticality accident alarm systems in all building for which nuclear criticality accidents were credible. Currently, however, alarm systems are not installed in the enriched uranium hexafluoride (UF{sub 6}) cylinder storage lots. This report analyzes and documents the extent to which enriched UF{sub 6} cylinder storage lots at PORTS are covered by criticality detectors and alarms currently installed in adjacent buildings. Monte Carlo calculations are performed on simplified models of the cylinder storage lots and adjacent buildings. The storage lots modelled are X-745B, X-745C, X745D, X-745E, and X-745F. The criticality detectors modelled are located in building X-343, the building X-344A/X-342A complex, and portions of building X-330. These criticality detectors are those located closest to the cylinder storage lots. Results of this analysis indicate that the existing criticality detectors currently installed at PORTS are largely ineffective in detecting neutron radiation from criticality accidents in most of the cylinder storage lots at PORTS, except sometimes along portions of their peripheries.

Lee, B.L. Jr.; Dobelbower, M.C.; Woollard, J.E.; Sutherland, P.J.; Tayloe, R.W. Jr.

1995-03-01T23:59:59.000Z

147

Depleted uranium: A DOE management guide  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy (DOE) has a management challenge and financial liability in the form of 50,000 cylinders containing 555,000 metric tons of depleted uranium hexafluoride (UF{sub 6}) that are stored at the gaseous diffusion plants. The annual storage and maintenance cost is approximately $10 million. This report summarizes several studies undertaken by the DOE Office of Technology Development (OTD) to evaluate options for long-term depleted uranium management. Based on studies conducted to date, the most likely use of the depleted uranium is for shielding of spent nuclear fuel (SNF) or vitrified high-level waste (HLW) containers. The alternative to finding a use for the depleted uranium is disposal as a radioactive waste. Estimated disposal costs, utilizing existing technologies, range between $3.8 and $11.3 billion, depending on factors such as applicability of the Resource Conservation and Recovery Act (RCRA) and the location of the disposal site. The cost of recycling the depleted uranium in a concrete based shielding in SNF/HLW containers, although substantial, is comparable to or less than the cost of disposal. Consequently, the case can be made that if DOE invests in developing depleted uranium shielded containers instead of disposal, a long-term solution to the UF{sub 6} problem is attained at comparable or lower cost than disposal as a waste. Two concepts for depleted uranium storage casks were considered in these studies. The first is based on standard fabrication concepts previously developed for depleted uranium metal. The second converts the UF{sub 6} to an oxide aggregate that is used in concrete to make dry storage casks.

NONE

1995-10-01T23:59:59.000Z

148

DISSOLUTION OF URANIUM FUELS BY MONOOR DIFLUOROPHOSPHORIC ACID  

DOE Patents (OSTI)

A method of dissolving and separating uranium from a uranium matrix fuel element by dissolving the uraniumcontaining matrix in monofluorophosphoric acid and/or difluorophosphoric acid at temperatures ranging from 150 to 275 un. Concent 85% C, thereafter neutralizing the solution to precipitate uranium solids, and converting the solids to uranium hexafluoride by treatment with a halogen trifluoride is presented. (AEC)

Johnson, R.; Horn, F.L.; Strickland, G.

1963-05-01T23:59:59.000Z

149

A nuclear criticality safety assessment of the loss of moderation control in 2 1/2 and 10-ton cylinders containing enriched UF sub 6  

Science Conference Proceedings (OSTI)

Moderation control for maintaining nuclear criticality safety in 2-1/2-ton, 10-ton, and 14-ton cylinders containing enriched uranium hexafluoride (UF{sub 6}) has been used safely within the nuclear industry for over thirty years, and is dependent on cylinder integrity and containment. This assessment evaluates the loss of moderation control by the breaching of containment and entry of water into the cylinders. The first objective of this study was to estimate the required amounts of water entering these large UF{sub 6} cylinders to react with, and to moderate the uranium compounds sufficiently to cause criticality. Hypothetical accident situations were modeled as a uranyl fluoride (UO{sub 2}F{sub 2}) slab above a UF{sub 6} hemicylinder, and a UO{sub 2} sphere centered within a UF{sub 6} hemicylinder. These situations were investigated by computational analyses utilizing the KENO V.a Monte Carlo Computer Code. The results were used to estimate both the masses of water required for criticality, and the limiting masses of water that could be considered safe. The second objective of the assessment was to calculate the time available for emergency control actions before a criticality would occur, i.e., a safetime,'' for various sources of water and different size openings in a breached cylinder. In the situations considered, except the case for a fire hose, the safetime appears adequate for emergency control actions. The assessment shows that current practices for handling moderation controlled cylinders of low enriched UF{sub 6}, along with the continuation of established personnel training programs, ensure nuclear criticality safety for routine and emergency operations. 2 refs., 5 figs., 1 tab.

Newvahner, R.L. (Portsmouth Gaseous Diffusion Plant, OH (United States)); Pryor, W.A. (PAI Corp., Oak Ridge, TN (United States))

1991-08-16T23:59:59.000Z

150

Wetland assessment of the effects of construction and operation of a depleteduranium hexafluoride conversion facility at the Portsmouth, Ohio, site.  

SciTech Connect

The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF{sub 6} inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This wetland assessment has been prepared by DOE, pursuant to Executive Order 11990 (''Protection of Wetlands'') and DOE regulations for implementing this Executive Order as set forth in Title 10, Part 1022, of the ''Code of Federal Regulations'' (10 CFR Part 1022 [Compliance with Floodplain and Wetland Environmental Review Requirements]), to evaluate potential impacts to wetlands from the construction and operation of a conversion facility at the DOE Portsmouth site. Approximately 0.02 acre (0.009 ha) of a 0.08-acre (0.03-ha) palustrine emergent wetland would likely be eliminated by direct placement of fill material during facility construction at Location A. Portions of this wetland that are not filled may be indirectly affected by an altered hydrologic regime because of the proximity of construction, possibly resulting in a decreased frequency or duration of inundation or soil saturation, and potential loss of hydrology necessary to sustain wetland conditions. Construction at Locations B or C would not result in direct impacts to wetlands. However, the hydrologic characteristics of nearby wetlands could be indirectly affected by adjacent construction. Executive Order 11990, ''Protection of Wetlands'', requires federal agencies to minimize the destruction, loss, or degradation of wetlands, and to preserve and enhance the natural and beneficial uses of wetlands. DOE regulations for implementing Executive Order 11990 are set forth in 10 CFR Part 1022. The impacts at Location A may potentially be avoided by an alternative routing of the entrance road, or mitigation may be developed in coordination with the appropriate regulatory agencies. Unavoidable impacts to wetlands that are within the jurisdiction of the USACE may require a CWA Section 404 Permit, which would trigger the requirement for a CWA Section 401 Water Quality Certification from the State of Ohio. Unavoidable impacts to isolated wetlands may require an Isolated Wetlands Permit from the Ohio Environmental Protection Agency. A mitigation plan may be required prior to the initiation of construction. Cumulative impacts to wetlands are anticipated to be negligible to minor for the proposed action, in conjunction with the effects of existing conditions and other activities. Habitat disturbance would involve settings commonly found in this part of Ohio, which in many cases involve previously disturbed habitats.

Van Lonkhuyzen, R.

2005-09-09T23:59:59.000Z

151

Reducing Sulfur Hexafluoride Use at LANSCE  

NLE Websites -- All DOE Office Websites (Extended Search)

U N C L A S S I F I E D U N C L A S S I F I E D Reducing Sulfur Hexafluoride Use at LANSCE Hank Alvestad presents to the Fugitive Emissions Working Group September 8, 2011...

152

Depleted uranium management alternatives  

SciTech Connect

This report evaluates two management alternatives for Department of Energy depleted uranium: continued storage as uranium hexafluoride, and conversion to uranium metal and fabrication to shielding for spent nuclear fuel containers. The results will be used to compare the costs with other alternatives, such as disposal. Cost estimates for the continued storage alternative are based on a life-cycle of 27 years through the year 2020. Cost estimates for the recycle alternative are based on existing conversion process costs and Capital costs for fabricating the containers. Additionally, the recycle alternative accounts for costs associated with intermediate product resale and secondary waste disposal for materials generated during the conversion process.

Hertzler, T.J.; Nishimoto, D.D.

1994-08-01T23:59:59.000Z

153

METHOD OF DEHYDRATING URANIUM TETRAFLUORIDE  

DOE Patents (OSTI)

Drying and dehydration of aqueous-precipitated uranium tetrafluoride are described. The UF/sub 4/ which normally contains 3 to 4% water, is dispersed into the reaction zone of an operating reactor wherein uranium hexafluoride is being reduced to UF/sub 4/ with hydrogen. The water-containing UF/sub 4/ is dried and blended with the UF/sub 4/ produced in the reactor without interfering with the reduction reaction. (AEC)

Davis, J.O.; Fogel, C.C.; Palmer, W.E.

1962-12-18T23:59:59.000Z

154

ELECTROLYTIC PRODUCTION OF URANIUM TETRAFLUORIDE  

DOE Patents (OSTI)

This patent relates to electrolytic methods for the production of uranium tetrafluoride. According to the present invention a process for the production of uranium tetrafluoride comprises submitting to electrolysis an aqueous solution of uranyl fluoride containing free hydrofluoric acid. Advantageously the aqueous solution of uranyl fluoride is obtained by dissolving uranium hexafluoride in water. On electrolysis, the uranyl ions are reduced to uranous tons at the cathode and immediately combine with the fluoride ions in solution to form the insoluble uranium tetrafluoride which is precipitated.

Lofthouse, E.

1954-08-31T23:59:59.000Z

155

Cylinder Surveillance and Maintenance  

NLE Websites -- All DOE Office Websites (Extended Search)

Surveillance and Maintenance Cylinder Surveillance and Maintenance DOE has a Cylinder Management program in place to inspect and maintain depleted UF6 cylinders, and to improve...

156

FAQ 30-Have there been accidents involving uranium hexafluoride...  

NLE Websites -- All DOE Office Websites (Extended Search)

UF6 was released, which reacted with steam from the process and created HF and uranyl fluoride. This accident resulted in two deaths from HF inhalation and three individuals...

157

NEPA Activities for the Depleted Uranium Hexafluoride Management...  

NLE Websites -- All DOE Office Websites (Extended Search)

ETTP) to some other stable chemical form acceptable for transportation, beneficial usereuse, andor disposal. Conversion facilities will be constructed at Paducah and...

158

Trifluoromethyl Sulfur Pentafluoride (SF5CF3) and Sulfur Hexafluoride...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur Pentafluoride (SF5CF3) and Sulfur Hexafluoride (SF6) from Dome Concordia graphics Graphics data Data Investigators W. T. Sturges,1 T. J. Wallington,2 M. D. Hurley,2 K....

159

Documents: Transportation  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Documents: Search PDF Documents View a list of all documents Transportation PDF Icon Transportation Impact Assessment for Shipment of Uranium Hexafluoride (UF6) Cylinders...

160

Portsmouth Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

implement Cold Shutdown requirements; disposition of depleted uranium hexafluoride cylinders; and perform Decontamination and Decommissioning. Portsmouth D&D Project Portsmouth...

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

FAQ 7-How is depleted uranium produced?  

NLE Websites -- All DOE Office Websites (Extended Search)

How is depleted uranium produced? How is depleted uranium produced? How is depleted uranium produced? Depleted uranium is produced during the uranium enrichment process. In the United States, uranium is enriched through the gaseous diffusion process in which the compound uranium hexafluoride (UF6) is heated and converted from a solid to a gas. The gas is then forced through a series of compressors and converters that contain porous barriers. Because uranium-235 has a slightly lighter isotopic mass than uranium-238, UF6 molecules made with uranium-235 diffuse through the barriers at a slightly higher rate than the molecules containing uranium-238. At the end of the process, there are two UF6 streams, with one stream having a higher concentration of uranium-235 than the other. The stream having the greater uranium-235 concentration is referred to as enriched UF6, while the stream that is reduced in its concentration of uranium-235 is referred to as depleted UF6. The depleted UF6 can be converted to other chemical forms, such as depleted uranium oxide or depleted uranium metal.

162

FLUORIDE VOLATILITY PROCESS FOR THE RECOVERY OF URANIUM  

DOE Patents (OSTI)

The separation and recovery of uraniunn from contaminants introduced by neutron irradiation by a halogenation and volatilization method are described. The irradiated uranium is dissolved in bromine trifluoride in the liquid phase. The uranium is converted to the BrF/sub 3/ soluble urmium hexafluoride compound whereas the fluorides of certain contaminating elements are insoluble in liquid BrF/sub 3/, and the reaction rate of the BrF/sub 3/ with certain other solid uranium contamirnnts is sufficiently slower than the reaction rate with uranium that substantial portions of these contaminating elements will remain as solids. These solids are then separated from the solution by a distillation, filtration, or centrifugation step. The uranium hexafluoride is then separated from the balance of the impurities and solvent by one or more distillations.

Katz, J.J.; Hyman, H.H.; Sheft, I.

1958-04-15T23:59:59.000Z

163

Investigation of breached depleted UF sub 6 cylinders  

Science Conference Proceedings (OSTI)

In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. An investigation team was immediately formed to determine the cause of the failures and their impact on future storage procedures and to recommend corrective actions. Subsequent investigation showed that the failures most probably resulted from mechanical damage that occurred at the time that the cylinders had been placed in the storage yard. In both cylinders evidence pointed to the impact of a lifting lug of an adjacent cylinder near the front stiffening ring, where deflection of cylinder could occur only by tearing the cylinder. The impacts appear to have punctured the cylinders and thereby set up corrosion processes that greatly extended the openings in the wall and obliterated the original crack. Fortunately, the reaction products formed by this process were relatively protective and prevented any large-scale loss of uranium. The main factors that precipitated the failures were inadequate spacing between cylinders and deviations in the orientations of lifting lugs from their intended horizontal position. After reviewing the causes and effects of the failures, the team's principal recommendation for remedial action concerned improved cylinder handling and inspection procedures. Design modifications and supplementary mechanical tests were also recommended to improve the cylinder containment integrity during the stacking operation. 4 refs., 2 figs.

DeVan, J.H.

1991-01-01T23:59:59.000Z

164

PLATINUM HEXAFLUORIDE AND METHOD OF FLUORINATING PLUTONIUM CONTAINING MIXTURES THERE-WITH  

DOE Patents (OSTI)

The preparation of platinum hexafluoride and its use as a fluorinating agent in a process for separating plutonium from fission products is presented. According to the invention, platinum is reacted with fluorine gas at from 900 to 1100 deg C to form platinum hexafluoride. The platinum hexafluoride is then contacted with the plutonium containing mixture at room temperature to form plutonium hexafluoride which is more volatile than the fission products fluorides and therefore can be isolated by distillation.

Malm, J.G.; Weinstock, B.; Claassen, H.H.

1959-07-01T23:59:59.000Z

165

gas cylinder storage guidelines  

NLE Websites -- All DOE Office Websites (Extended Search)

Compressed Gas Cylinder Storage Guidelines Compressed Gas Cylinder Storage Guidelines All cylinders must be stored vertical, top up across the upper half the cylinder but below the shoulder. Small cylinder stands or other methods may be appropriate to ensure that the cylinders are secured from movement. Boxes, cartons, and other items used to support small cylinders must not allow water to accumulate and possible cause corrosion. Avoid corrosive chemicals including salt and fumes - keep away from direct sunlight and keep objects away that could fall on them. Use Gas pressure regulators that have been inspected in the last 5 years. Cylinders that contain fuel gases whether full or empty must be stored away from oxidizer cylinders at a minimum of 20 feet. In the event they are stored together, they must be separated by a wall 5 feet high with

166

Uranium Enrichment  

NLE Websites -- All DOE Office Websites (Extended Search)

Enrichment Depleted Uranium line line Uranium Enrichment Depleted Uranium Health Effects Uranium Enrichment A description of the uranium enrichment process, including gaseous...

167

Compressed Gas Cylinder Policy  

E-Print Network (OSTI)

, storage, and usage of compressed gas cylinders. 2.0 POLICY Colorado School of Mines ("Mines" or "the, storage, and usage requirements outlined below. This policy is applicable school-wide including all, or electrical circuits. Flammable gas cylinders must be stored in the building's gas cylinder storage cage until

168

Enrichment Assay Methods for a UF6 Cylinder Verification Station  

Science Conference Proceedings (OSTI)

International Atomic Energy Agency (IAEA) inspectors currently perform periodic inspections at uranium enrichment plants to verify UF6 cylinder enrichment declarations. Measurements are typically performed with handheld high-resolution sensors on a sampling of cylinders taken to be representative of the facilitys entire cylinder inventory. These enrichment assay methods interrogate only a small fraction of the total cylinder volume, and are time-consuming and expensive to execute for inspectors. Pacific Northwest National Laboratory (PNNL) is developing an unattended measurement system capable of automated enrichment measurements over the full volume of Type 30B and Type 48 cylinders. This Integrated Cylinder Verification System (ICVS) could be located at key measurement points to positively identify each cylinder, measure its mass and enrichment, store the collected data in a secure database, and maintain continuity of knowledge on measured cylinders until IAEA inspector arrival. The focus of this paper is the development of nondestructive assay (NDA) methods that combine traditional enrichment signatures (e.g. 185-keV emission from U-235) and more-penetrating non-traditional signatures (e.g. high-energy neutron-induced gamma rays spawned primarily from U-234 alpha emission) collected by medium-resolution gamma-ray spectrometers (i.e. sodium iodide or lanthanum bromide). The potential of these NDA methods for the automated assay of feed, tail and product cylinders is explored through MCNP modeling and with field measurements on a cylinder population ranging from 0.2% to 5% in U-235 enrichment.

Smith, Leon E.; Jordan, David V.; Misner, Alex C.; Mace, Emily K.; Orton, Christopher R.

2010-11-30T23:59:59.000Z

169

A LABORATORY INVESTIGATION OF THE FLUORINATION OF CRUDE URANIUM TETRAFLUORIDE  

DOE Green Energy (OSTI)

Ore concentrates were converted directly to crude uranium tetrafluoride by hydrogen reduction aad hydrofluorination in fluidized-bed reactors. Small- scale laboratory experiments demonstrated that this process can be extended to the production of crude uranium hexafluoride through fluorination of the uranium tetrafluoride in a fluidized bed. The satisfactory temperature range for the reaction lies between 300 and 600 deg C. At 450 deg C the fluorine utilization is between 50 and 80%. With excess fluorine, over 99% of the uranium is volatilized from the solid material. The fluidization characteristics of certain materials are improved by the addition of an inert solid diluent to the bed. (auth) .

Sandus, O.; Steunenberg, R.K.

1957-12-01T23:59:59.000Z

170

CONTINUOUS PROCESS FOR PREPARING URANIUM HEXAFLUORIDE FROM URANIUM TETRAFLUORIDE AND OXYGEN  

DOE Patents (OSTI)

A process for preparing UF/sub 6/ by reacting UF/sub 4/ and oxygen is described. The UF/sub 4/ and oxygen are continuously introduced into a fluidized bed of UO/sub 2/F/sub 2/ at a temperature of 600 to 900 deg C. The concentration of UF/sub 4/ in the bed is maintained below 25 weight per cent in order to avoid sintering and intermediate compound formation. By-product U0/sub 2/F/sub 2/ is continuously removed from the top of the bed recycled. In an alternative embodiment heat is supplied to the reaction bed by burning carbon monoxide in the bed. The product UF/sub 6/ is filtered to remove entrained particles and is recovered in cold traps and chemical traps. (AEC)

Adams, J.B.; Bresee, J.C.; Ferris, L.M.

1961-11-21T23:59:59.000Z

171

FAQ 3-What are the common forms of uranium?  

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are the common forms of uranium? are the common forms of uranium? What are the common forms of uranium? Uranium can take many chemical forms. In nature, uranium is generally found as an oxide, such as in the olive-green-colored mineral pitchblende. Uranium oxide is also the chemical form most often used for nuclear fuel. Uranium-fluorine compounds are also common in uranium processing, with uranium hexafluoride (UF6) and uranium tetrafluoride (UF4) being the two most common. In its pure form, uranium is a silver-colored metal. The most common forms of uranium oxide are U3O8 and UO2. Both oxide forms have low solubility in water and are relatively stable over a wide range of environmental conditions. Triuranium octaoxide (U3O8) is the most stable form of uranium and is the form most commonly found in nature. Uranium dioxide (UO2) is the form in which uranium is most commonly used as a nuclear reactor fuel. At ambient temperatures, UO2 will gradually convert to U3O8. Because of their stability, uranium oxides are generally considered the preferred chemical form for storage or disposal.

172

Investigation of breached depleted UF{sub 6} cylinders  

Science Conference Proceedings (OSTI)

In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton steel cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. Both holes, concealed by UF{sub 4} reaction products identical in color to the cylinder coating, were similarly located near the front stiffening ring. The UF{sub 4} appeared to have self-sealed the holes, thus containing nearly all of the uranium contents. Martin Marietta Energy Systems, Inc., Vice President K.W. Sommerfeld immediately formed an investigation team to: (1) identify the most likely cause of failure for the two breached cylinders, (2) determine the impact of these incidents on the three-site inventory, and (3) provide recommendations and preventive measures. This document discusses the results of this investigation.

Barber, E.J.; Butler, T.R.; DeVan, J.H.; Googin, J.M.; Taylor, M.S.; Dyer, R.H.; Russell, J.R.

1991-09-01T23:59:59.000Z

173

Investigation of breached depleted UF sub 6 cylinders  

Science Conference Proceedings (OSTI)

In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton steel cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. Both holes, concealed by UF{sub 4} reaction products identical in color to the cylinder coating, were similarly located near the front stiffening ring. The UF{sub 4} appeared to have self-sealed the holes, thus containing nearly all of the uranium contents. Martin Marietta Energy Systems, Inc., Vice President K.W. Sommerfeld immediately formed an investigation team to: (1) identify the most likely cause of failure for the two breached cylinders, (2) determine the impact of these incidents on the three-site inventory, and (3) provide recommendations and preventive measures. This document discusses the results of this investigation.

Barber, E.J.; Butler, T.R.; DeVan, J.H.; Googin, J.M.; Taylor, M.S.; Dyer, R.H.; Russell, J.R.

1991-09-01T23:59:59.000Z

174

EA-1290: Disposition of Russian Federation Titled Natural Uranium |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

290: Disposition of Russian Federation Titled Natural Uranium 290: Disposition of Russian Federation Titled Natural Uranium EA-1290: Disposition of Russian Federation Titled Natural Uranium SUMMARY This EA evaluates the potential environmental impacts of a proposal to transport up to an average of 9,000 metric tons per year of natural uranium as uranium hexafluoride (UF6) from the United States to the Russian Federation. This amount of uranium is equivalent to 13,3000 metric tons of UF6. The EA also examines the impacts of this action on the global commons. Transfer of natural UF6 to the Russian Federation is part of a joint U.S./Russian program to dispose of highly enriched uranium (HEU) from dismantled Russian nuclear weapons. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD

175

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation  

E-Print Network (OSTI)

The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

176

DOE/EA-1607: Final Environmental Assessment for Disposition of DOE Excess Depleted Uranium, Natural Uranium, and Low-Enriched Uranium (June 2009)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

μCi/cc microcuries per cubic centimeter μCi/cc microcuries per cubic centimeter MAP mitigation action plan MEI maximally exposed individual mg/kg milligrams per kilogram mrem millirem mSv millisievert MT metric ton MTCA Model Toxics Control Act MTU metric tons of uranium N/A not applicable Final Environmental Assessment: Disposition of DOE Excess Depleted Uranium, Natural Uranium, and Low-Enriched Uranium vi NAAQS National Ambient Air Quality Standards NEF National Enrichment Facility NEPA National Environmental Policy Act NRC U.S. Nuclear Regulatory Commission NU natural uranium NUF 6 natural uranium hexafluoride pCi/g picocuries per gram PEIS programmatic environmental impact statement PM 2.5 particulate matter with a diameter of 2.5 microns or less PM 10 particulate matter with a diameter of 10 microns or less

177

Fiber Tracking Cylinder Nesting  

SciTech Connect

The fiber tracker consists of 8 concentric carbon fiber cylinders of varying diameters, from 399mm to 1032.2mm and two different lengths. 1.66 and 2.52 meters. Each completed cylinder is covered over the entire o.d. with scintillating fiber ribbons with a connector on each ribbon. These ribbons are axial (parallel to the beam line) at one end and stereo (at 3 deg. to the beam line) at the other. The ribbon connectors have dowel pins which are used to match with the connectors on the wave guide ribbons. These dowel pins are also used during the nesting operation, locating and positioning measurements. The nesting operation is the insertion of one cylinder into another, aligning them with one another and fastening them together into a homogeneous assembly. For ease of assembly. the nesting operation is accomplished working from largest diameter to smallest. Although the completed assembly of all 8 cylinders glued and bolted together is very stiff. individual cylinders are relatively flexible. Therefore. during this operation, No.8 must be supported in a manner which maintains its integrity and yet allows the insertion of No.7. This is accomplished by essentially building a set of dummy end plates which replicate a No.9 cylinder. These end plates are mounted on a wheeled cart that becomes the nesting cart. Provisions for a protective cover fastened to these rings has been made and will be incorporated in finished product. These covers can be easily removed for access to No.8 and/or the connection of No.8 to No.9. Another wheeled cart, transfer cart, is used to push a completed cylinder into the cylinder(s) already mounted in the nesting cart.

Stredde, H.; /Fermilab

1999-03-30T23:59:59.000Z

178

Safety Bulletin 2009-01, Sulfur Hexafluoride Awareness  

NLE Websites -- All DOE Office Websites (Extended Search)

cylinders and equipment should be followed (see HSS Safety Bulletin 2007-01, http:www.hss.energy.gov CSAcspsafetybulletinsSB2007-01.pdf). In the event of fire, personnel...

179

Depleted Uranium  

NLE Websites -- All DOE Office Websites (Extended Search)

Depleted Uranium Depleted Uranium Depleted Uranium line line Uranium Enrichment Depleted Uranium Health Effects Depleted Uranium Depleted uranium is uranium that has had some of its U-235 content removed. Over the last four decades, large quantities of uranium were processed by gaseous diffusion to produce uranium having a higher concentration of uranium-235 than the 0.72% that occurs naturally (called "enriched" uranium) for use in U.S. national defense and civilian applications. "Depleted" uranium is also a product of the enrichment process. However, depleted uranium has been stripped of some of its natural uranium-235 content. Most of the Department of Energy's (DOE) depleted uranium inventory contains between 0.2 to 0.4 weight-percent uranium-235, well

180

Method for fluorination of uranium oxide  

SciTech Connect

Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

Petit, George S. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Nuclear & Uranium  

U.S. Energy Information Administration (EIA)

Nuclear & Uranium. Uranium fuel ... nuclear reactors, generation, spent fuel. Total Energy. Comprehensive data summaries, comparisons, analysis, and projections ...

182

Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation.  

E-Print Network (OSTI)

??The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test (more)

Guffey, Eric J. (Eric Jemison)

2011-01-01T23:59:59.000Z

183

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents (OSTI)

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium and a mixture of uranium and plutonium for use as a fresh blanket and core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped cathode is disposed about the outer anodic dissolution baskets. Uranium is deposited from the anode baskets in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium collection efficiency enhanced by increasing the electrode area and reducing the anode-cathode spacing for enhanced trapping and recovery of uranium dendrites scraped off of the cylindrical cathodes which may be greater in number than two.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1995-12-31T23:59:59.000Z

184

Corrosion of breached UF[sub 6] storage cylinders  

Science Conference Proceedings (OSTI)

This paper describes the corrosion processes that occurred following the mechanical failure of two steel 14-ton storage cylinders containing depleted UF[sub 6]. The failures both were traced to small mechanical tears that occurred during stacking of the cylinders. Although subsequent corrosion processes greatly extended the openings in the wall. the reaction products formed were quite protective and prevented any significant environmental insult or loss of uranium. The relative sizes of the two holes correlated with the relative exposure times that had elapsed from the time of stacking. From the sizes and geometries of the two holes, together with analyses of the reaction products, it was possible to determine the chemical reactions that controlled the corrosion process and to develop a scenario for predicting the rate of hydrolysis of UF[sub 6], the loss rate of HF, and chemical attack of a breached UF[sub 6] storage cylinder.

Barber, E.J.; Taylor, M.S.; DeVan, J.H.

1993-01-01T23:59:59.000Z

185

Corrosion of breached UF{sub 6} storage cylinders  

Science Conference Proceedings (OSTI)

This paper describes the corrosion processes that occurred following the mechanical failure of two steel 14-ton storage cylinders containing depleted UF{sub 6}. The failures both were traced to small mechanical tears that occurred during stacking of the cylinders. Although subsequent corrosion processes greatly extended the openings in the wall. the reaction products formed were quite protective and prevented any significant environmental insult or loss of uranium. The relative sizes of the two holes correlated with the relative exposure times that had elapsed from the time of stacking. From the sizes and geometries of the two holes, together with analyses of the reaction products, it was possible to determine the chemical reactions that controlled the corrosion process and to develop a scenario for predicting the rate of hydrolysis of UF{sub 6}, the loss rate of HF, and chemical attack of a breached UF{sub 6} storage cylinder.

Barber, E.J.; Taylor, M.S.; DeVan, J.H.

1993-02-01T23:59:59.000Z

186

Notice of Intent to Prepare an Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities  

NLE Websites -- All DOE Office Websites (Extended Search)

123 123 Federal Register / Vol. 66, No. 181 / Tuesday, September 18, 2001 / Notices Section 615-Procedural Safeguards Topic Addressed: Due Process Hearings * Letter dated April 19, 2001 to Virginia Department of Education Director Judith A. Douglas, regarding whether a State educational agency is required to convene a due process hearing initiated by someone other than the parent of a child with a disability or a public agency. Topic Addressed: Surrogate Parents * Letter dated April 16, 2001 to Pinal County, Arizona Deputy County Attorney Linda L. Harant, regarding the appointment of surrogate parents for children who are wards of a tribal court. Topic Addressed: Student Discipline * Letter dated April 16, 2001 to Professor Perry A. Zirkel, regarding the calculation of disciplinary removals of

187

THE CHEMISTRY OF THE REACTION OF URANIUM HEXAFLUORIDE WITH ACTIVATED CARBON  

SciTech Connect

The effects of temperature, time and other variables on the rate and extent of reaction between UF/sub 6/ and various types, grades and particle sizes of commercial activated carbon have been studied experimentally. It is shown that both hydrolysis and reduction of the UF/sub 6/ occur, the latter more slowly than the former. Reduction leads to the formation of a mixture of fluorocarbons ranging from CF/sub 4/ to a wax-like maternial volatile only above 250 deg C. There is also evidence for the adsorption of UF/sub 6/ on an undetermined substrate. (auth)

Wilson, T.P.; Schuman, S.C.; Simons, E.L.

1946-04-12T23:59:59.000Z

188

Assessment of Preferred Depleted Uranium Disposal Forms  

SciTech Connect

The Department of Energy (DOE) is in the process of converting about 700,000 metric tons (MT) of depleted uranium hexafluoride (DUF6) containing 475,000 MT of depleted uranium (DU) to a stable form more suitable for long-term storage or disposal. Potential conversion forms include the tetrafluoride (DUF4), oxide (DUO2 or DU3O8), or metal. If worthwhile beneficial uses cannot be found for the DU product form, it will be sent to an appropriate site for disposal. The DU products are considered to be low-level waste (LLW) under both DOE orders and Nuclear Regulatory Commission (NRC) regulations. The objective of this study was to assess the acceptability of the potential DU conversion products at potential LLW disposal sites to provide a basis for DOE decisions on the preferred DU product form and a path forward that will ensure reliable and efficient disposal.

Croff, A.G.; Hightower, J.R.; Lee, D.W.; Michaels, G.E.; Ranek, N.L.; Trabalka, J.R.

2000-06-01T23:59:59.000Z

189

Converting {sup 99}Mo production from high- to low-enriched uranium  

SciTech Connect

This paper discusses efforts towards LEU substitution in two HEU targets. One type is the Cintichem target, a closed cylinder with a thin coating of uranium dioxide electroplated ion the inside wall. To successfully increase the amount of uranium per target, we are developing a target that uses LEU metal foil. Uranium surface preparation is discussed.

Vandegrift, G.F.; Conner, C.J.; Sedlet, J.; Wygmans, D.G.

1997-09-01T23:59:59.000Z

190

NUCLEAR BOMBS FROM LOW- ENRICHED URANIUM OR SPENT FUEL  

E-Print Network (OSTI)

Conventional wisdom says that low-enriched uranium is not suitable for making nuclear weapons. However, an article in USA Today claims that rogue states and terrorists have discovered that this is untrue. Not only that, but terrorists could separate plutonium from irradiated fuel (often called spent fuel) more easily than previously thought. (584.5495) WISE Amsterdam Lowenriched uranium (LEU) is uranium containing up to 20 % uranium-235. Uranium with higher enrichment levels is classified as high-enriched, and is subject to international safeguards because it can be used to make nuclear weapons. However, a USA Today article claims that rogue countries and terrorists have discovered that it is possible to make nuclear weapons with uranium of lower enrichment, according to classified nuclear threat reports (1). The information is not entirely new. Back in 1996, a standard book on nuclear weapons material stated, a self-sustaining chain reaction in a nuclear weapon cannot occur in depleted or natural or low-enriched uranium and is only theoretically IN THIS ISSUE: possible in LEU of roughly 10 percent or greater (2). Fuel for nuclear power reactors would not be suitable this is typically enriched to 3-5 % uranium-235. However, for a rogue state wanting to make high-enriched uranium, it would take less work to start with nuclear fuel than with natural uranium. It could be done in a small and easy to hide uranium enrichment plant perhaps similar to the plant which has recently been discovered in Iran (3). Nevertheless, it would still require a substantial operation, since the fuel would need to be converted to uranium hexafluoride, enriched and then reconverted to uranium metal. More significantly, many research reactors use uranium of just under

unknown authors

2003-01-01T23:59:59.000Z

191

Uranium and Its Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

and Its Compounds Uranium and Its Compounds line line What is Uranium? Chemical Forms of Uranium Properties of Uranium Compounds Radioactivity and Radiation Uranium Health Effects...

192

Depleted Uranium Uses Research and Development  

NLE Websites -- All DOE Office Websites (Extended Search)

DU Uses DU Uses Depleted Uranium Uses Research & Development A Depleted Uranium Uses Research and Development Program was initiated to explore beneficial uses of depleted uranium (DU) and other materials resulting from conversion of depleted UF6. A Depleted Uranium Uses Research and Development Program was initiated to explore the safe, beneficial use of depleted uranium and other materials resulting from conversion of depleted UF6 (e.g., fluorine and empty carbon steel cylinders) for the purposes of resource conservation and cost savings compared with disposal. This program explored the risks and benefits of several depleted uranium uses, including uses as a radiation shielding material, a catalyst, and a semi-conductor material in electronic devices.

193

Transportation  

NLE Websites -- All DOE Office Websites (Extended Search)

Transportation Transportation Transportation of Depleted Uranium Materials in Support of the Depleted Uranium Hexafluoride Conversion Program Issues associated with transport of depleted UF6 cylinders and conversion products. Conversion Plan Transportation Requirements The DOE has prepared two Environmental Impact Statements (EISs) for the proposal to build and operate depleted uranium hexafluoride (UF6) conversion facilities at its Portsmouth and Paducah gaseous diffusion plant sites, pursuant to the National Environmental Policy Act (NEPA). The proposed action calls for transporting the cylinder at ETTP to Portsmouth for conversion. The transportation of depleted UF6 cylinders and of the depleted uranium conversion products following conversion was addressed in the EISs.

194

Gas Cylinder Lifting at the NCNR  

Science Conference Proceedings (OSTI)

... Gas Cylinder Lifting at the NCNR. ... We have recently made a gas cylinder lifting cage so that this transfer can be done in a safe manner. ...

195

SULFUR HEXAFLUORIDE TREATMENT OF USED NUCLEAR FUEL TO ENHANCE SEPARATIONS  

SciTech Connect

Reactive Gas Recycling (RGR) technology development has been initiated at Savannah River National Laboratory (SRNL), with a stretch-goal to develop a fully dry recycling technology for Used Nuclear Fuel (UNF). This approach is attractive due to the potential of targeted gas-phase treatment steps to reduce footprint and secondary waste volumes associated with separations relying primarily on traditional technologies, so long as the fluorinators employed in the reaction are recycled for use in the reactors or are optimized for conversion of fluorinator reactant. The developed fluorination via SF{sub 6}, similar to the case for other fluorinators such as NF{sub 3}, can be used to address multiple fuel forms and downstream cycles including continued processing for LWR via fluorination or incorporation into a aqueous process (e.g. modified FLUOREX) or for subsequent pyro treatment to be used in advanced gas reactor designs such metal- or gas-cooled reactors. This report details the most recent experimental results on the reaction of SF{sub 6} with various fission product surrogate materials in the form of oxides and metals, including uranium oxides using a high-temperature DTA apparatus capable of temperatures in excess of 1000{deg}C . The experimental results indicate that the majority of the fission products form stable solid fluorides and sulfides, while a subset of the fission products form volatile fluorides such as molybdenum fluoride and niobium fluoride, as predicted thermodynamically. Additional kinetic analysis has been performed on additional fission products. A key result is the verification that SF{sub 6} requires high temperatures for direct fluorination and subsequent volatilization of uranium oxides to UF{sub 6}, and thus is well positioned as a head-end treatment for other separations technologies, such as the volatilization of uranium oxide by NF{sub 3} as reported by colleagues at PNNL, advanced pyrochemical separations or traditional full recycle approaches. Based on current results of the research at SRNL on SF{sub 6} fluoride volatility for UNF separations, SF{sub 6} treatment renders all anticipated volatile fluorides studied to be volatile, and all non-volatile fluorides studied to be non-volatile, with the notable exception of uranium oxides. This offers an excellent opportunity to use this as a head-end separations treatment process because: 1. SF{sub 6} can be used to remove volatile fluorides from a UNF matrix while leaving behind uranium oxides. Therefore an agent such as NF{sub 3} should be able to very cleanly separate a pure UF{sub 6} stream, leaving compounds in the bottoms such as PuF{sub 4}, SrF{sub 2} and CsF after the UNF matrix has been pre-treated with SF{sub 6}. 2. Due to the fact that the uranium oxide is not separated in the volatilization step upon direct contact with SF{sub 6} at moderately high temperatures (? 1000{deg}C), this fluoride approach may be wellsuited for head-end processing for Gen IV reactor designs where the LWR is treated as a fuel stock, and it is not desired to separate the uranium from plutonium, but it is desired to separate many of the volatile fission products. 3. It is likely that removal of the volatile fission products from the uranium oxide should simplify both traditional and next generation pyroprocessing techniques. 4. SF{sub 6} treatment to remove volatile fission products, with or without treatment with additional fluorinators, could be used to simplify the separations of traditional aqueous processes in similar fashion to the FLUOREX process. Further research should be conducted to determine the separations efficiency of a combined SF{sub 6}/NF{sub 3} separations approach which could be used as a stand-alone separations technology or a head-end process.

Gray, J.; Torres, R.; Korinko, P.; Martinez-Rodriguez, M.; Becnel, J.; Garcia-Diaz, B.; Adams, T.

2012-09-25T23:59:59.000Z

196

Prototype Radiation Detector Positioning System For The Automated Nondestructive Assay Of Uf6 Cylinders  

Science Conference Proceedings (OSTI)

International Atomic Energy Agency (IAEA) inspectors currently perform periodic inspections at uranium enrichment plants to verify UF6 cylinder enrichment declarations. Measurements are typically performed with handheld high-resolution sensors on a sampling of cylinders taken to be representative of the facilitys entire cylinder inventory. These measurements are time-consuming, expensive, and assay only a small fraction of the total cylinder volume. An automated nondestructive assay system capable of providing enrichment measurements over the full volume of the cylinder could improve upon current verification practices in terms of efficiency and assay accuracy. This paper describes an approach denoted the Integrated Cylinder Verification Station (ICVS) that supports 100% cylinder verification, provides volume-averaged cylinder enrichment assay, and reduces inspector manpower needs. To allow field measurements to be collected to validate data collection algorithms, a prototype radiation detector positioning system was constructed. The system was designed to accurately position an array of radiation detectors along the length of a cylinder to measure UF6 enrichment. A number of alternative radiation shields for the detectors were included with the system. A collimated gamma-ray spectrometer module that allows translation of the detectors in the surrounding shielding to adjust the field of view, and a collimating plug in the end to further reduce the low-energy field of view, were also developed. Proof-of-principle measurements of neutron and high-energy gamma-ray signatures, using moderated neutron detectors and large-volume spectrometers in a fixed-geometry, portal-like configuration, supported an early assessment of the viability of the concept. The system has been used successfully on two testing campaigns at an AREVA fuel fabrication plant to scan over 30 product cylinders. This paper will describe the overall design of the detector positioning system and provide an overview of the Integrated Cylinder Verification Station (ICVS) approach.

Hatchell, Brian K.; Valdez, Patrick LJ; Orton, Christopher R.; Mace, Emily K.

2011-08-07T23:59:59.000Z

197

Method for monitoring stack gases for uranium activity  

DOE Patents (OSTI)

A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

1988-01-01T23:59:59.000Z

198

Method for monitoring stack gases for uranium activity  

DOE Patents (OSTI)

A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

Beverly, C.R.; Ernstberger, E.G.

1985-07-03T23:59:59.000Z

199

Conceptual Ideas for New Nondestructive UF6 Cylinder Assay Techniques  

SciTech Connect

Nondestructive assay (NDA) measurements of uranium cylinders play an important role in helping the International Atomic Energy Agency (IAEA) safeguard uranium enrichment plants. Traditionally, these measurements have consisted of a scale or load cell to determine the mass of UF{sub 6} in the cylinder combined with a gamma-ray measurement of the 186 keV peak from {sup 235}U to determine enrichment. More recently, Los Alamos National Laboratory (LANL) and Pacific Northwest National Laboratory (PNNL) have developed systems that exploit the passive neutron signal from UF{sub 6} to determine uranium mass and/or enrichment. These include the Uranium Cylinder Assay System (UCAS), the Passive Neutron Enrichment Meter (PNEM), and the Hybrid Enrichment Verification Array (HEVA). The purpose of this report is to provide the IAEA with new ideas on technologies that may or may not be under active development but could be useful for UF{sub 6} cylinder assay. To begin, we have included two feasibility studies of active interrogation techniques. There is a long history of active interrogation in the field of nuclear safeguards, especially for uranium assay. Both of the active techniques provide a direct measure of {sup 235}U content. The first is an active neutron method based on the existing PNEM design that uses a correlated {sup 252}Cf interrogation source. This technique shows great promise for UF{sub 6} cylinder assay and is based on advanced technology that could be implemented in the field in the near term. The second active technique is nuclear resonance fluorescence (NRF). In the NRF technique, a bremsstrahlung photon beam could be used to illuminate the cylinder, and high-resolution gamma-ray detectors would detect the characteristic de-excitation photons. The results of the feasibility study show that under certain measurement geometries, NRF is impractical for UF6 cylinder assay, but the 'grazing transmission' and 'secant transmission' geometries have more potential for this application and should be assessed quantitatively. The next set of techniques leverage scintillator detectors that are sensitive to both neutron and gamma radiation. The first is the BC-523A capture-gated organic liquid scintillator. The detector response from several different neutron energies has been characterized and is included in the study. The BC-523A has not yet been tested with UF{sub 6} cylinders, but the application appears to be well suited for this technology. The second detector type is a relatively new inorganic scintillator called CLYC. CLYC provides a complementary detection approach to the HEVA and PNEM systems that could be used to determine uranium enrichment in UF{sub 6} cylinders. In this section, the conceptual idea for an integrated CLYC-HEVA/PNEM system is explored that could yield more precision and robustness against systemic uncertainties than any one of the systems by itself. This is followed by a feasibility study on using alpha-particle-induced reaction gamma-rays as a way to estimate {sup 234}U abundance in UF{sub 6}. Until now, there has been no readily available estimate of the strength of these reaction gamma-rays. Thick target yields of the chief reaction gammas are computed and show that they are too weak for practical safeguards applications. In special circumstances where long count times are permissible, the 1,275 keV F({alpha},x{gamma}) is observable. Its strength could help verify an operator declaration provided other knowledge is available (especially the age). The other F({alpha},x{gamma}) lines are concealed by the dominant uranium line spectrum and associated continuum. Finally, the last section provides several ideas for electromagnetic and acoustic nondestructive evaluation (NDE) techniques. These can be used to measure cylinder wall thickness, which is a source of systematic uncertainty for gamma-ray-based NDA techniques; characterize the UF{sub 6} filling profile inside the cylinder, which is a source of systematic uncertainty for neutron-based NDA techniques; locate hidden objects inside the cylinder; a

Miller, Karen A. [Los Alamos National Laboratory

2012-05-02T23:59:59.000Z

200

Photon compression in cylinders  

DOE Green Energy (OSTI)

It has been shown theoretically that intense microwave radiation is absorbed non-classically by a newly enunciated mechanism when interacting with hydrogen plasma. Fields > 1 Mg, lambda > 1 mm are within this regime. The predicted absorption, approximately P/sub rf/v/sub theta/sup e/, has not yet been experimentally confirmed. The applications of such a coupling are many. If microwave bursts approximately > 5 x 10/sup 14/ watts, 5 ns can be generated, the net generation of power from pellet fusion as well as various military applications becomes feasible. The purpose, then, for considering gas-gun photon compression is to obtain the above experimental capability by converting the gas kinetic energy directly into microwave form. Energies of >10/sup 5/ joules cm/sup -2/ and powers of >10/sup 13/ watts cm/sup -2/ are potentially available for photon interaction experiments using presently available technology. The following topics are discussed: microwave modes in a finite cylinder, injection, compression, switchout operation, and system performance parameter scaling.

Ensley, D.L.

1977-01-12T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Depleted uranium storage and disposal trade study: Summary report  

SciTech Connect

The objectives of this study were to: identify the most desirable forms for conversion of depleted uranium hexafluoride (DUF6) for extended storage, identify the most desirable forms for conversion of DUF6 for disposal, evaluate the comparative costs for extended storage or disposal of the various forms, review benefits of the proposed plasma conversion process, estimate simplified life-cycle costs (LCCs) for five scenarios that entail either disposal or beneficial reuse, and determine whether an overall optimal form for conversion of DUF6 can be selected given current uncertainty about the endpoints (specific disposal site/technology or reuse options).

Hightower, J.R.; Trabalka, J.R.

2000-02-01T23:59:59.000Z

202

URANIUM ALLOYS  

DOE Patents (OSTI)

A uranium alloy is reported containing from 0.1 to 5 per cent by weight of molybdenum and from 0.1 to 5 per cent by weight of silicon, the balance being uranium.

Colbeck, E.W.

1959-12-29T23:59:59.000Z

203

Sorption of Np and Tc in Underground Waters by Uranium Oxides  

NLE Websites -- All DOE Office Websites (Extended Search)

worldwide. As a rule DUF 6 is stored in steel cylinders near power stations 1,2 in Russia, and at uranium en- richment plants in the U.S. It is desirable to convert the UF 6 to...

204

Pyrolitic Uranium Compound (PYRUC)  

NLE Websites -- All DOE Office Websites (Extended Search)

Pyrolitic Uranium Compound Pyrolitic Uranium Compound (PYRUC) PYRolitic Uranium Compound (PYRUC) is a shielding material consisting of depleted uranium UO2 or UC in either pellet...

205

Automated Nondestructive Assay of UF6 Cylinders: Detector Characterization and Initial Measurements  

Science Conference Proceedings (OSTI)

International Atomic Energy Agency (IAEA) inspectors currently perform periodic inspections at uranium enrichment plants to verify UF6 cylinder enrichment declarations. Measurements are typically performed with handheld high-resolution sensors on a sampling of cylinders assumed to be representative of the facility's entire cylinder inventory. These measurements are time-consuming and assay only a small fraction of the total cylinder volume. An automated nondestructive assay system capable of providing enrichment measurements over the full volume of the cylinder could improve upon current verification practices in terms of manpower and assay accuracy. Pacific Northwest National Laboratory is developing an Integrated Cylinder Verification System (ICVS) intended for this purpose and has developed a field prototype of the nondestructive assay (NDA) components of an ICVS. The nondestructive assay methods would combine the 'traditional' enrichment-meter signature (i.e. 186-keV emission from 235U) as well as 'non-traditional' high-energy photon signatures derived from neutrons produced primarily by 19F({alpha},n) reactions. This paper describes the design, calibration and characterization of the NaI(Tl) and LaBr3(Ce) spectrometers utilized in the field prototype. An overview of a recent field measurement campaign is then provided, supported by example gamma-ray pulse-height spectra collected on cylinders of known enrichment.

Mace, Emily K.; Smith, Leon E.

2011-10-01T23:59:59.000Z

206

SF6 (Sulfur Hexafluoride) Computer-Based Training Module 4.0  

Science Conference Proceedings (OSTI)

The SF6 (Sulfur Hexafluoride): Computer-Based Training Modules consist of four sub-modules that each provide approximately one hour of instruction to users on SF6 topics. A browser interface helps the user navigate through the interactive training. As the user moves through the module, it provides instruction and assessment. At the end of the module, the user receives a final scored assessment and a pass/fail result. Four SF6 sub-modules are included in the ...

2013-11-26T23:59:59.000Z

207

Occupational Hygiene Aspects of Sulfur Hexafluoride Decomposition By-Products: Workshop Summary  

Science Conference Proceedings (OSTI)

Sulfur hexafluoride (SF6) is an inert gas that is present in many different types of electrical utility equipment. While the environmental concerns about this gas have been widely addressed, worker exposure aspects of SF6 decomposition by-products have not been fully explored. To address this knowledge gap, EPRI conducted a workshop on March 12, 2013, in Charlotte, North Carolina. This workshop was designed to 1) address the perspectives of occupational hygiene and engineering ...

2013-11-18T23:59:59.000Z

208

Production and Handling Slide 31: Certification of UF6 Cylinder...  

NLE Websites -- All DOE Office Websites (Extended Search)

UF6 Cylinder Volume Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Certification of UF6 Cylinder Volume The cylinder...

209

US Department of Energy Uranium Enrichment Activity  

Science Conference Proceedings (OSTI)

KPMG Peat Marwick (KPMG), Certified Public Accountants, has completed its audit of the Department of Energy's Uranium Enrichment Activity (UEA) financial.statements as of September 30, 1991. The purpose of the audit was to determine whether (1) the financial statements were presented fairly in accordance with applicable accounting principles, (2) the auditee complied with all applicable laws and regulations that may have materially affected the financial statements, and (3) the internal accounting controls, taken as a whole, were adequate. The US Government, through the Department of Energy (DOE) and the management and operating contractor, operates the UEA to enrich uranium hexafluoride in the isotope U-235 for commercial power reactor operators, as further discussed in note 1 of the financial statements. The enrichment of uranium for Government program users, which had been a function of UEA, was transferred outside the UEA affective September 30, 1991, as described in note 3 of the financial statements. UEA is a part of DOE and does not exist as a separate legal entity. For financial reporting purposes, the entity is defined as those activities which provide enriching services to its customers. The financial statements are prepared by extracting and adjusting UEA related data from the financial records of DOE and its contractors.

Not Available

1992-06-16T23:59:59.000Z

210

URANIUM COMPOSITIONS  

DOE Patents (OSTI)

This patent relates to high purity uranium alloys characterized by improved stability to thermal cycling and low thermal neutron absorption. The high purity uranium alloy contains less than 0.1 per cent by weight in total amount of any ore or more of the elements such as aluminum, silicon, phosphorous, tin, lead, bismuth, niobium, and zinc.

Allen, N.P.; Grogan, J.D.

1959-05-12T23:59:59.000Z

211

Production and Handling Slide 35: UF6 Cylinder Data Summary  

NLE Websites -- All DOE Office Websites (Extended Search)

UF6 Cylinder Data Summary UF6 Cylinder Data Summary Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents UF6 Cylinder Data Summary Cylinder Model Nominal Diam. (in.) Material of Construction Minimum Volume Approximate Tare Weight Without Valve Protector Maximum Enrichment Uranium-235 Shipping Limit Maximum, a UF6 ft3 liters lb kg Weight % lb kg 1S 1.5 Nickel 0.0053 0.15 1.75 0.79 100.00 1.0 0.45 2S .5 Nickel 0.026 0.74 4.2 1.91 100.00 4.9 2.22 5A 5 Monel 0.284 8.04 55 25 100.00 55 24.95 5B 5 Nickel 0.284 8.04 55 25 100.00 55 24.95 8A 8 Monel 1.319 37.35 120 54 12.5 255 115.67 12A 12 Nickel 2.38 67.4 185 84 5.0 460 208.7 12B 12 Monel 2.38 67.4 185 84 5.0 460 208.7 308c 30 Steel 26.0 736.0 1,400 635 5.0b 5,020 2,277 48A 48 Steel 108.9 3,.84 4,500 2,041 4.5b 21,030 9,539 48Xd 48 Steel 108.9 3,084 4,500 2,041 4.5b,g 21,030 9,539 48F 48 Steel

212

Depleted Uranium and Uranium Alloys  

Science Conference Proceedings (OSTI)

...Naturally occurring uranium makes up 0.0004% of the crust of the Earth; it is 40 times more plentiful than silver, and 800 times more plentiful than gold. Natural uranium contains approximately 0.7% fissionable U 235 and 99.3%

213

SF6 (Sulfur Hexafluoride) Computer-Based Training (CBT) Module Version 3.0  

Science Conference Proceedings (OSTI)

The SF6 (Sulfur Hexafluoride): Computer-Based Training Modules consist of four sub-modules that each provide approximately one hour of instruction to users on SF6 topics. A browser interface helps the user navigate through the interactive training. As the user moves through the module, it provides instruction and assessment. At the end of the module, the user receives a final scored assessment and a pass/fail result.The four SF6 sub-modules are included in the ...

2012-11-20T23:59:59.000Z

214

Uranium industry annual 1997  

SciTech Connect

This report provides statistical data on the U.S. uranium industry`s activities relating to uranium raw materials and uranium marketing.

NONE

1998-04-01T23:59:59.000Z

215

Uranium Marketing Annual Report - Release Date: May 31, 2011  

Gasoline and Diesel Fuel Update (EIA)

4. Uranium purchased by owners and operators of U.S. civilian nuclear power reactors by origin and material type, 2012 deliveries 4. Uranium purchased by owners and operators of U.S. civilian nuclear power reactors by origin and material type, 2012 deliveries thousand pounds U3O8 equivalent; dollars per pound U3O8 equivalent Deliveries Uranium Concentrate Natural UF6 Enriched UF6 Natural UF6 and Enriched UF6 Total U.S.-Origin Uranium Purchases W W W W 9,807 Weighted-Average Price W W W W 59.44 Foreign-Origin Uranium Purchases W W W W 47,713 Weighted-Average Price W W W W 54.07 Total Purchases 28,642 W W 28,878 57,520 Weighted-Average Price 54.20 W W 55.80 54.99 W = Data withheld to avoid disclosure of individual company data. Notes: Totals may not equal sum of components because of independent rounding. Weighted-average prices are not adjusted for inflation. Natural UF6 is uranium hexafluoride. The natural UF6 and enriched UF6 quantity represents only the U3O8 equivalent uranium-component quantity specified in the contract for each delivery of natural UF6 and enriched UF6. The natural UF6 and enriched UF6 weighted-average price represent only the U3O8 equivalent uranium-component price specified in the contract for each delivery of natural UF6 and enriched UF6, and does not include the conversion service and enrichment service components.

216

Nuclear & Uranium  

U.S. Energy Information Administration (EIA)

Table 21. Foreign sales of uranium from U.S. suppliers and owners and operators of U.S. civilian nuclear power reactors by origin and delivery year, 2008-2012

217

What is Depleted Uranium?  

NLE Websites -- All DOE Office Websites (Extended Search)

What is Uranium? What is Uranium? Uranium and Its Compounds line line What is Uranium? Chemical Forms of Uranium Properties of Uranium Compounds Radioactivity and Radiation Uranium Health Effects What is Uranium? Physical and chemical properties, origin, and uses of uranium. Properties of Uranium Uranium is a radioactive element that occurs naturally in varying but small amounts in soil, rocks, water, plants, animals and all human beings. It is the heaviest naturally occurring element, with an atomic number of 92. In its pure form, uranium is a silver-colored heavy metal that is nearly twice as dense as lead. In nature, uranium atoms exist as several isotopes, which are identified by the total number of protons and neutrons in the nucleus: uranium-238, uranium-235, and uranium-234. (Isotopes of an element have the

218

URANIUM IN ALKALINE ROCKS  

E-Print Network (OSTI)

combine to indicate uranium enrichment of an alkaline magma.uranium, the Ilfmaussaq intrusion contains an unusually high enrichment

Murphy, M.

2011-01-01T23:59:59.000Z

219

Lubricated Reciprocating Frictional Properties of Marine Cylinder ...  

Science Conference Proceedings (OSTI)

... Process Design of the Ductile Cast Iron Cylinder Head for Marine Diesel Engine ... Heavy Section Ductile Iron Castings for Use in Wind Turbine Generators.

220

Production and Handling Slide 41: Cylinder Handler  

NLE Websites -- All DOE Office Websites (Extended Search)

Handler Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Cylinder Handler Refer to caption below for image description...

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Uranium Mining and Enrichment  

NLE Websites -- All DOE Office Websites (Extended Search)

Overview Presentation » Uranium Mining and Enrichment Overview Presentation » Uranium Mining and Enrichment Uranium Mining and Enrichment Uranium is a radioactive element that occurs naturally in the earth's surface. Uranium is used as a fuel for nuclear reactors. Uranium-bearing ores are mined, and the uranium is processed to make reactor fuel. In nature, uranium atoms exist in several forms called isotopes - primarily uranium-238, or U-238, and uranium-235, or U-235. In a typical sample of natural uranium, most of the mass (99.3%) would consist of atoms of U-238, and a very small portion of the total mass (0.7%) would consist of atoms of U-235. Uranium Isotopes Isotopes of Uranium Using uranium as a fuel in the types of nuclear reactors common in the United States requires that the uranium be enriched so that the percentage of U-235 is increased, typically to 3 to 5%.

222

Automated UF6 Cylinder Enrichment Assay: Status of the Hybrid Enrichment Verification Array (HEVA) Project: POTAS Phase II  

SciTech Connect

Pacific Northwest National Laboratory (PNNL) intends to automate the UF6 cylinder nondestructive assay (NDA) verification currently performed by the International Atomic Energy Agency (IAEA) at enrichment plants. PNNL is proposing the installation of a portal monitor at a key measurement point to positively identify each cylinder, measure its mass and enrichment, store the data along with operator inputs in a secure database, and maintain continuity of knowledge on measured cylinders until inspector arrival. This report summarizes the status of the research and development of an enrichment assay methodology supporting the cylinder verification concept. The enrichment assay approach exploits a hybrid of two passively-detected ionizing-radiation signatures: the traditional enrichment meter signature (186-keV photon peak area) and a non-traditional signature, manifested in the high-energy (3 to 8 MeV) gamma-ray continuum, generated by neutron emission from UF6. PNNL has designed, fabricated, and field-tested several prototype assay sensor packages in an effort to demonstrate proof-of-principle for the hybrid assay approach, quantify the expected assay precision for various categories of cylinder contents, and assess the potential for unsupervised deployment of the technology in a portal-monitor form factor. We refer to recent sensor-package prototypes as the Hybrid Enrichment Verification Array (HEVA). The report provides an overview of the assay signatures and summarizes the results of several HEVA field measurement campaigns on populations of Type 30B UF6 cylinders containing low-enriched uranium (LEU), natural uranium (NU), and depleted uranium (DU). Approaches to performance optimization of the assay technique via radiation transport modeling are briefly described, as are spectroscopic and data-analysis algorithms.

Jordan, David V.; Orton, Christopher R.; Mace, Emily K.; McDonald, Benjamin S.; Kulisek, Jonathan A.; Smith, Leon E.

2012-06-01T23:59:59.000Z

223

Uranium (U)  

Science Conference Proceedings (OSTI)

Table 63   Properties of unstable uranium isotopes with α-particle emission...Table 63 Properties of unstable uranium isotopes with α-particle emission Isotope Abundance, % Half-life ( t 1/2 ), years Energy, MeV 234 U 0.0055 2.47 ? 10 5 4.77, 4.72, 4.58, 4.47, 235 U 0.720 7.1 ? 10 6 4.40, 4.2 238 U 99.274 4.51 ? 10 9 4.18...

224

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at Portsmouth, Ohio, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth DUF Portsmouth DUF 6 Conversion Final EIS APPENDIX A: TEXT OF PUBLIC LAW 107-206 PERTINENT TO THE MANAGEMENT OF DUF 6 Public Law 107-206 A-2 Portsmouth DUF 6 Conversion Final EIS Public Law 107-206 A-3 Portsmouth DUF 6 Conversion Final EIS APPENDIX A: TEXT OF PUBLIC LAW 107-206 PERTINENT TO THE MANAGEMENT OF DUF 6 Section 502 of Public Law 107-206, "2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States" (signed by the President 08/02/2002) SEC. 502. Section 1 of Public Law 105-204 (112 Stat. 681) is amended - (1) in subsection (b), by striking "until the date" and all that follows and inserting "until the date that is 30 days after the date on which the Secretary of Energy awards a contract under

225

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Paducah DUF Paducah DUF 6 Conversion Final EIS FIGURE S-1 Regional Map of the Paducah, Kentucky, Site Vicinity Summary S-18 Paducah DUF 6 Conversion Final EIS FIGURE S-3 Three Alternative Conversion Facility Locations within the Paducah Site, with Location A Being the Preferred Alternative (A representative conversion facility footprint is shown within each location.) Summary S-20 Paducah DUF 6 Conversion Final EIS FIGURE S-4 Conceptual Overall Material Flow Diagram for the Paducah Conversion Facility Summary S-21 Paducah DUF 6 Conversion Final EIS FIGURE S-5 Conceptual Conversion Facility Site Layout for Paducah Summary S-28 Paducah DUF 6 Conversion Final EIS FIGURE S-6 Areas of Potential Impact Evaluated for Each Alternative Alternatives 2-7 Paducah DUF 6 Conversion Final EIS

226

Final Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Paducah DUF Paducah DUF 6 Conversion Final EIS APPENDIX A: TEXT OF PUBLIC LAW 107-206 PERTINENT TO THE MANAGEMENT OF DUF 6 Public Law 107-206 A-2 Paducah DUF 6 Conversion Final EIS Public Law 107-206 A-3 Paducah DUF 6 Conversion Final EIS APPENDIX A: TEXT OF PUBLIC LAW 107-206 PERTINENT TO THE MANAGEMENT OF DUF 6 Section 502 of Public Law 107-206, "2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States" (signed by the President 08/02/2002) SEC. 502. Section 1 of Public Law 105-204 (112 Stat. 681) is amended - (1) in subsection (b), by striking "until the date" and all that follows and inserting "until the date that is 30 days after the date on which the Secretary of Energy awards a contract under

227

List of common materials available for ESTAR continued  

Science Conference Proceedings (OSTI)

... Cadmium Tungstate Calcium Carbonate Calcium Fluoride Calcium Oxide ... Triethyl Phosphate Tungsten Hexafluoride Uranium Dicarbide Uranium ...

228

46 | NewScientist | 14 July 2007 www.newscientist.com Earlier this year an Iranian  

E-Print Network (OSTI)

scientist at the uranium conversion facility at Isfahan died from poisoning with uranium hexafluoride gas

Valero-Cuevas, Francisco

229

FAQ 18-What does a cylinder storage yard look like?  

NLE Websites -- All DOE Office Websites (Extended Search)

cylinder storage yard look like? What does a cylinder storage yard look like? Pictures of depleted UF6 cylinder storage yards are shown below. Storage yards are large outdoor areas...

230

Uranium-234  

SciTech Connect

Translation of Uran-234 by J. Sehmorak. The following subjects are discussed: /sup 234/U and other natural radioactive isotopes, fractionation of heavy radioactive elements in nature, fractionation of radioactive isotopes, /sup 234/U in nuclear geochemistry, /sup 234/U in uranium minerals, /sup 234/U in continental waters and in quaternary deposits, and /sup 234/U in the ocean. (LK)

Cherdyntsev, V.V.

1971-01-01T23:59:59.000Z

231

Production and Handling Slide 36: Full Cylinder in Autoclave...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cylinder in Autoclave Prior to Feeding Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Full Cylinder in Autoclave Prior to...

232

Production and Handling Slide 39: Weighing the Cylinder  

NLE Websites -- All DOE Office Websites (Extended Search)

Weighing the Cylinder Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Weighing the Cylinder Refer to caption below for image...

233

Production and Handling Slide 42: Typical Depleted Cylinder Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

Typical Depleted Cylinder Storage Yard Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Typical Depleted Cylinder Storage Yard...

234

Depleted Uranium Health Effects  

NLE Websites -- All DOE Office Websites (Extended Search)

Depleted Uranium Health Effects Depleted Uranium Health Effects Depleted Uranium line line Uranium Enrichment Depleted Uranium Health Effects Depleted Uranium Health Effects Discussion of health effects of external exposure, ingestion, and inhalation of depleted uranium. Depleted uranium is not a significant health hazard unless it is taken into the body. External exposure to radiation from depleted uranium is generally not a major concern because the alpha particles emitted by its isotopes travel only a few centimeters in air or can be stopped by a sheet of paper. Also, the uranium-235 that remains in depleted uranium emits only a small amount of low-energy gamma radiation. However, if allowed to enter the body, depleted uranium, like natural uranium, has the potential for both chemical and radiological toxicity with the two important target organs

235

Uranium industry annual 1996  

SciTech Connect

The Uranium Industry Annual 1996 (UIA 1996) provides current statistical data on the US uranium industry`s activities relating to uranium raw materials and uranium marketing. The UIA 1996 is prepared for use by the Congress, Federal and State agencies, the uranium and nuclear electric utility industries, and the public. Data on uranium raw materials activities for 1987 through 1996 including exploration activities and expenditures, EIA-estimated reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities for 1994 through 2006, including purchases of uranium and enrichment services, enrichment feed deliveries, uranium fuel assemblies, filled and unfilled market requirements, uranium imports and exports, and uranium inventories are shown in Chapter 2. A feature article, The Role of Thorium in Nuclear Energy, is included. 24 figs., 56 tabs.

NONE

1997-04-01T23:59:59.000Z

236

Detection of illicit HEU production in gaseous centrifuge enrichment plants using neutron counting techniques on product cylinders  

SciTech Connect

Innovative and novel safeguards approaches are needed for nuclear energy to meet global energy needs without the threat of nuclear weapons proliferation. Part of these efforts will include creating verification techniques that can monitor uranium enrichment facilities for illicit production of highly-enriched uranium (HEU). Passive nondestructive assay (NDA) techniques will be critical in preventing illicit HEU production because NDA offers the possibility of continuous and unattended monitoring capabilities with limited impact on facility operations. Gaseous centrifuge enrichment plants (GCEP) are commonly used to produce low-enriched uranium (LEU) for reactor fuel. In a GCEP, gaseous UF{sub 6} spins at high velocities in centrifuges to separate the molecules containing {sup 238}U from those containing the lighter {sup 235}U. Unfortunately, the process for creating LEU is inherently the same as HEU, creating a proliferation concern. Insuring that GCEPs are producing declared enrichments poses many difficult challenges. In a GCEP, large cascade halls operating thousands of centrifuges work together to enrich the uranium which makes effective monitoring of the cascade hall economically prohibitive and invasive to plant operations. However, the enriched uranium exiting the cascade hall fills product cylinders where the UF{sub 6} gas sublimes and condenses for easier storage and transportation. These product cylinders hold large quantities of enriched uranium, offering a strong signal for NDA measurement. Neutrons have a large penetrability through materials making their use advantageous compared to gamma techniques where the signal is easily attenuated. One proposed technique for detecting HEU production in a GCEP is using neutron coincidence counting at the product cylinder take off stations. This paper discusses findings from Monte Carlo N-Particle eXtended (MCNPX) code simulations that examine the feasibility of such a detector.

Freeman, Corey R [Los Alamos National Laboratory; Geist, William H [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

237

Stability of Anisotropic Cylinder with Zero Expansion  

E-Print Network (OSTI)

We study the dynamical instability of anisotropic collapsing cylinder with the expansion-free condition, which generates vacuum cavity within fluid distribution. The perturbation scheme is applied to distinguish Newtonian, post-Newtonian and post-post Newtonian terms, which are used for constructing dynamical equation at Newtonian and post-Newtonian regimes. We analyze the role of pressure anisotropy and energy density inhomogeneity on the stability of collapsing cylinder. It turns out that stability of the cylinder depends upon these physical properties of the fluid, not on the stiffness of the fluid.

M. Sharif; M. Azam

2013-05-24T23:59:59.000Z

238

Stability of Anisotropic Cylinder with Zero Expansion  

E-Print Network (OSTI)

We study the dynamical instability of anisotropic collapsing cylinder with the expansion-free condition, which generates vacuum cavity within fluid distribution. The perturbation scheme is applied to distinguish Newtonian, post-Newtonian and post-post Newtonian terms, which are used for constructing dynamical equation at Newtonian and post-Newtonian regimes. We analyze the role of pressure anisotropy and energy density inhomogeneity on the stability of collapsing cylinder. It turns out that stability of the cylinder depends upon these physical properties of the fluid, not on the stiffness of the fluid.

Sharif, M

2013-01-01T23:59:59.000Z

239

PREPARATION OF URANIUM MONOSULFIDE  

DOE Patents (OSTI)

A process is given for preparing uranium monosulfide from uranium tetrafluoride dissolved in molten alkali metal chloride. A hydrogen-hydrogen sulfide gas mixture passed through the solution precipitates uranium monosulfide. (AEC)

Yoshioka, K.

1964-01-28T23:59:59.000Z

240

Properties of Uranium Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Triuranium Octaoxide (U3O8) Uranium Dioxide (UO2) Uranium Tetrafluoride (U4) Uranyl Fluoride (UO2F2) The physical properties of the pertinent chemical forms of uranium are...

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Uranium Quick Facts  

NLE Websites -- All DOE Office Websites (Extended Search)

Uranium Quick Facts Uranium Quick Facts A collection of facts about uranium, DUF6, and DOEs DUF6 inventory. Over the years, the Department of Energy has received numerous...

242

URANIUM IN ALKALINE ROCKS  

E-Print Network (OSTI)

1977. "Geology of Brazil's Uranium and Thorium Occurrences,"A tantalo-niobate of uranium, near pyrochlore. Isometric,niobate and tantalate of uranium, with ferrous iron and rare

Murphy, M.

2011-01-01T23:59:59.000Z

243

Determination of the 235U Mass and Enrichment within Small UF6 Cylinders via a Neutron Coincidence Well Counting System  

Science Conference Proceedings (OSTI)

The construction of three new uranium enrichment facilities in the United States has sparked renewed interest in the development and enhancement of methods to determine the enrichment and fissile mass content of UF6 cylinders. We describe the design and examine the expected performance of a UF6 bottle counter developed for the assay of Type 5A cylinders. The counter, as designed and subsequently constructed, is a tall passive neutron well counter with a clam-shell configuration and graphite end plugs operated in fast neutron mode. Factory performance against expectation is described. The relatively high detection efficiency and effectively 4 detection geometry provide a near-ideal measurement configuration, making the UF6 bottle counter a valuable tool for the evaluation of the neutron coincidence approach to UF6 cylinder assay. The impacts of non-uniform filling, voids, enrichment, and mixed enrichments are examined

McElroy, Robert Dennis [ORNL; Croft, Dr. Stephen [Los Alamos National Laboratory (LANL); Young, Brian M [Canberra Industries, Inc., Meriden, CT; Venkataraman, Ram [Canberra Industries, Inc., Meriden, CT

2011-01-01T23:59:59.000Z

244

Casimir forces between cylinders at different temperatures  

E-Print Network (OSTI)

We study Casimir interactions between cylinders in thermal nonequilibrium, where the objects as well as the environment are held at different temperatures. We provide the general formula for the force, in a one reflection ...

Golyk, Vladyslav A.

245

Parabolic cylinder functions implemented in Matlab  

E-Print Network (OSTI)

Routines for computation of Weber's parabolic cylinder functions and their derivatives are implemented in Matlab for both moderate and great values of the argument. Standard, real solutions are considered. Tables of values are included.

E. Cojocaru

2009-01-15T23:59:59.000Z

246

COPPER COATED URANIUM ARTICLE  

DOE Patents (OSTI)

Various techniques and methods for obtaining coppercoated uranium are given. Specifically disclosed are a group of complex uranium coatings having successive layers of nickel, copper, lead, and tin.

Gray, A.G.

1958-10-01T23:59:59.000Z

247

Domestic Uranium Production Report  

U.S. Energy Information Administration (EIA)

Home > Nuclear > Domestic Uranium Production Report Domestic Uranium Production Report Data for: 2005 Release Date: May 15, 2006 Next Release: May 15, 2007

248

Uranium Oxide Semiconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

of semiconductors, it would consume the annual production rate of depleted uranium from uranium enrichment facilities. For more information: PDF Semiconductive Properties of...

249

Manhattan Project: Uranium cubes  

Office of Scientific and Technical Information (OSTI)

Cubes of uranium metal, Los Alamos, 1945 Events > Difficult Choices, 1942 > More Uranium Research, 1942 Events > Bringing It All Together, 1942-1945 > Basic Research at Los Alamos,...

250

Electromagnetic Casimir Forces in Elliptic Cylinder Geometries  

E-Print Network (OSTI)

The scattering theory approach makes it possible to carry out exact calculations of Casimir energies in any geometry for which the scattering T-matrix and a partial wave expansion of the free Green's function are available. We implement this program for the case of a perfectly conducting elliptic cylinder, thereby completing the set of geometries where electromagnetic scattering is separable. Particular emphasis is placed on the case of zero radius, where the elliptic cylinder reduces to a strip.

Noah Graham

2013-03-26T23:59:59.000Z

251

Notice of Availability of a Draft Supplement Analysis for Disposal of Depleted Uranium Oxide Conversion Produce Generated from DOE's Inventory of Depleted Uranium Hexafluoride  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

69 Federal Register 69 Federal Register / Vol. 72, No. 63 / Tuesday, April 3, 2007 / Notices DEPARTMENT OF EDUCATION The Historically Black Colleges and Universities Capital Financing Advisory Board AGENCY: The Historically Black Colleges and Universities Capital Financing Board, Department of Education. ACTION: Notice of an open meeting. SUMMARY: This notice sets forth the schedule and proposed agenda of an upcoming open meeting of the Historically Black Colleges and Universities Capital Financing Advisory Board. The notice also describes the functions of the Board. Notice of this meeting is required by Section 10(a)(2) of the Federal Advisory Committee Act and is intended to notify the public of their opportunity to attend. DATES: Friday, April 20, 2007. Time: 10 a.m.-2 p.m.

252

Uranium Industry Annual, 1992  

Science Conference Proceedings (OSTI)

The Uranium Industry Annual provides current statistical data on the US uranium industry for the Congress, Federal and State agencies, the uranium and electric utility industries, and the public. The feature article, ``Decommissioning of US Conventional Uranium Production Centers,`` is included. Data on uranium raw materials activities including exploration activities and expenditures, resources and reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities including domestic uranium purchases, commitments by utilities, procurement arrangements, uranium imports under purchase contracts and exports, deliveries to enrichment suppliers, inventories, secondary market activities, utility market requirements, and uranium for sale by domestic suppliers are presented in Chapter 2.

Not Available

1993-10-28T23:59:59.000Z

253

Uranium Enrichment Measurements without Calibration Using Gamma Rays Above 100 keV  

DOE Green Energy (OSTI)

The verification of UF{sub 6} shipping cylinders is an important activity in routine safeguards inspections. Current measurement methods using either sodium-iodide or high-purity germanium detectors require calibrations that are not always appropriate for field measurements, because of changes in geometry or container wall thickness. The introduction of the MGAU code demonstrated the usefulness of intrinsically calibrated measurements for inspections. MGAU uses the 100-keV region of the uranium gamma-ray spectrum. The thick walls of UF{sub 6} shipping cylinders and the low-energy analysis preclude the routine use of MGAU for these measurements. We have developed a uranium enrichment measurement method for measurements using high-purity germanium detectors, which do not require calibration, and uranium gamma rays above 100 keV. The method uses seven gamma rays from {sup 235}U and {sup 238}U to determine their relative detection efficiency intrinsically and with an additional gamma ray from {sup 234}U, the relative abundance of these three uranium isotopes. The method uses a function that describes the basic physical processes that predominantly determine the relative detection efficiency curve. These are the detector efficiency, the absorption by the cylinder wall, and the self-absorption by the uranium contents. We will describe this model and initial testing on various uranium materials and detector types.

Ruhter, W D; Wang, T F; Hayden, C

2001-09-27T23:59:59.000Z

254

The ultimate disposition of depleted uranium  

SciTech Connect

Significant amounts of the depleted uranium (DU) created by past uranium enrichment activities have been sold, disposed of commercially, or utilized by defense programs. In recent years, however, the demand for DU has become quite small compared to quantities available, and within the US Department of Energy (DOE) there is concern for any risks and/or cost liabilities that might be associated with the ever-growing inventory of this material. As a result, Martin Marietta Energy Systems, Inc. (Energy Systems), was asked to review options and to develop a comprehensive plan for inventory management and the ultimate disposition of DU accumulated at the gaseous diffusion plants (GDPs). An Energy Systems task team, under the chairmanship of T. R. Lemons, was formed in late 1989 to provide advice and guidance for this task. This report reviews options and recommends actions and objectives in the management of working inventories of partially depleted feed (PDF) materials and for the ultimate disposition of fully depleted uranium (FDU). Actions that should be considered are as follows. (1) Inspect UF{sub 6} cylinders on a semiannual basis. (2) Upgrade cylinder maintenance and storage yards. (3) Convert FDU to U{sub 3}O{sub 8} for long-term storage or disposal. This will include provisions for partial recovery of costs to offset those associated with DU inventory management and the ultimate disposal of FDU. Another recommendation is to drop the term tails'' in favor of depleted uranium'' or DU'' because the tails'' label implies that it is waste.'' 13 refs.

Not Available

1990-12-01T23:59:59.000Z

255

PRODUCTION OF URANIUM MONOCARBIDE  

DOE Patents (OSTI)

A method of making essentially stoichiometric uranium monocarbide by pelletizing a mixture of uranium tetrafluoride, silicon, and carbon and reacting the mixture at a temperature of approximately 1500 to 1700 deg C until the reaction goes to completion, forming uranium monocarbide powder and volatile silicon tetrafluoride, is described. The powder is then melted to produce uranium monocarbide in massive form. (AEC)

Powers, R.M.

1962-07-24T23:59:59.000Z

256

DECONTAMINATION OF URANIUM  

DOE Patents (OSTI)

This patent deals with the separation of rare earth and other fission products from neutron bombarded uranium. This is accomplished by melting the uranium in contact with either thorium oxide, maguesium oxide, alumnum oxide, beryllium oxide, or uranium dioxide. The melting is preferably carried out at from 1150 deg to 1400 deg C in an inert atmosphere, such as argon or helium. During this treatment a scale of uranium dioxide forms on the uranium whtch contains most of the fission products.

Feder, H.M.; Chellew, N.R.

1958-02-01T23:59:59.000Z

257

Energy Department Selects Global Laser Enrichment for Future Operations at  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Energy Department Selects Global Laser Enrichment for Future Energy Department Selects Global Laser Enrichment for Future Operations at Paducah Site Energy Department Selects Global Laser Enrichment for Future Operations at Paducah Site November 27, 2013 - 12:00pm Addthis Workers inspect cylinders containing depleted uranium hexafluoride. Workers inspect cylinders containing depleted uranium hexafluoride. Media Contact (202) 586-4940 Washington, D.C. - The U.S. Department of Energy announced today that it will open negotiations with Global Laser Enrichment (GLE) for the sale of the depleted uranium hexafluoride inventory. The Department determined that GLE offered the greatest benefit to the government among those who responded to a Request for Offers (RFO) released earlier this year. Through the RFO review process, the Department also decided to enter into

258

Documents: Program Planning and Decision Making  

NLE Websites -- All DOE Office Websites (Extended Search)

documents Program Planning and Decision Making PDF Icon Final Plan for the Conversion of Depleted Uranium Hexafluoride 345 KB details PDF Icon Depleted Uranium Hexafluoride...

259

FAQ 38-What are the potential environmental impacts from continued...  

NLE Websites -- All DOE Office Websites (Extended Search)

continued storage of depleted uranium hexafluoride? What are the potential environmental impacts from continued storage of depleted uranium hexafluoride? In addition to human...

260

Safeguarding a NWS International Enrichment Center as an Enriched Uranium Store  

SciTech Connect

The operational and regulatory singularities of a multilateral facility designed to provide enriched uranium to a consortium of members may engender a new sub-category of safeguard criteria for the International Atomic Energy Agency (IAEA). This paper introduces the contingency of monitoring such a facility as a uranium storage center with cylinders containing low-enriched uranium (LEU) as the principal, and perhaps only, material open to verification. Accountancy and verification techniques will be proffered together with disparate means for maintaining continuity of knowledge (CoK) on verified stock.

Curtis, Michael M.

2008-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Uranium industry annual 1998  

SciTech Connect

The Uranium Industry Annual 1998 (UIA 1998) provides current statistical data on the US uranium industry`s activities relating to uranium raw materials and uranium marketing. It contains data for the period 1989 through 2008 as collected on the Form EIA-858, ``Uranium Industry Annual Survey.`` Data provides a comprehensive statistical characterization of the industry`s activities for the survey year and also include some information about industry`s plans and commitments for the near-term future. Data on uranium raw materials activities for 1989 through 1998, including exploration activities and expenditures, EIA-estimated reserves, mine production of uranium, production of uranium concentrate, and industry employment, are presented in Chapter 1. Data on uranium marketing activities for 1994 through 2008, including purchases of uranium and enrichment services, enrichment feed deliveries, uranium fuel assemblies, filled and unfilled market requirements, and uranium inventories, are shown in Chapter 2. The methodology used in the 1998 survey, including data edit and analysis, is described in Appendix A. The methodologies for estimation of resources and reserves are described in Appendix B. A list of respondents to the ``Uranium Industry Annual Survey`` is provided in Appendix C. The Form EIA-858 ``Uranium Industry Annual Survey`` is shown in Appendix D. For the readers convenience, metric versions of selected tables from Chapters 1 and 2 are presented in Appendix E along with the standard conversion factors used. A glossary of technical terms is at the end of the report. 24 figs., 56 tabs.

NONE

1999-04-22T23:59:59.000Z

262

Uranium industry annual 1994  

SciTech Connect

The Uranium Industry Annual 1994 (UIA 1994) provides current statistical data on the US uranium industry`s activities relating to uranium raw materials and uranium marketing during that survey year. The UIA 1994 is prepared for use by the Congress, Federal and State agencies, the uranium and nuclear electric utility industries, and the public. It contains data for the 10-year period 1985 through 1994 as collected on the Form EIA-858, ``Uranium Industry Annual Survey.`` Data collected on the ``Uranium Industry Annual Survey`` (UIAS) provide a comprehensive statistical characterization of the industry`s activities for the survey year and also include some information about industry`s plans and commitments for the near-term future. Where aggregate data are presented in the UIA 1994, care has been taken to protect the confidentiality of company-specific information while still conveying accurate and complete statistical data. A feature article, ``Comparison of Uranium Mill Tailings Reclamation in the United States and Canada,`` is included in the UIA 1994. Data on uranium raw materials activities including exploration activities and expenditures, EIA-estimated resources and reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities, including purchases of uranium and enrichment services, and uranium inventories, enrichment feed deliveries (actual and projected), and unfilled market requirements are shown in Chapter 2.

NONE

1995-07-05T23:59:59.000Z

263

Process for electroslag refining of uranium and uranium alloys  

DOE Patents (OSTI)

A process is described for electroslag refining of uranium and uranium alloys wherein molten uranium and uranium alloys are melted in a molten layer of a fluoride slag containing up to about 8 weight percent calcium metal. The calcium metal reduces oxides in the uranium and uranium alloys to provide them with an oxygen content of less than 100 parts per million. (auth)

Lewis, P.S. Jr.; Agee, W.A.; Bullock, J.S. IV; Condon, J.B.

1975-07-22T23:59:59.000Z

264

PRODUCTION OF PURIFIED URANIUM  

DOE Patents (OSTI)

A pyrometallurgical method for processing nuclear reactor fuel elements containing uranium and fission products and for reducing uranium compound; to metallic uranium is reported. If the material proccssed is essentially metallic uranium, it is dissolved in zinc, the sulution is cooled to crystallize UZn/sub 9/ , and the UZn/sub 9/ is distilled to obtain uranium free of fission products. If the material processed is a uranium compound, the sollvent is an alloy of zinc and magnesium and the remaining steps are the same.

Burris, L. Jr.; Knighton, J.B.; Feder, H.M.

1960-01-26T23:59:59.000Z

265

URANIUM RECOVERY PROCESS  

DOE Patents (OSTI)

A method is described for recovering uranium values from uranium bearing phosphate solutions such as are encountered in the manufacture of phosphate fertilizers. The solution is first treated with a reducing agent to obtain all the uranium in the tetravalent state. Following this reduction, the solution is treated to co-precipitate the rcduced uranium as a fluoride, together with other insoluble fluorides, thereby accomplishing a substantially complete recovery of even trace amounts of uranium from the phosphate solution. This precipitate usually takes the form of a complex fluoride precipitate, and after appropriate pre-treatment, the uranium fluorides are leached from this precipitate and rccovered from the leach solution.

Bailes, R.H.; Long, R.S.; Olson, R.S.; Kerlinger, H.O.

1959-02-10T23:59:59.000Z

266

SOLDERING OF URANIUM  

SciTech Connect

One of Its Monograph Series, The Industrial Atom.'' The joining of uranium to uranium has been done successfully using a number of commercial soft solders and fusible alloys. Soldering by using an ultrasonic soldering iron has proved the best method for making sound soldered joints of uranium to uranium and of uranium to other metals, such as stainless steel. Other method of soldering have shown some promise but did not give reliable joints all the time. The soldering characteristics of uranium may best be compared to those of aluminum. (auth)

Hanks, G.S.; Doll, D.T.; Taub, J.M.; Brundige, E.L.

1957-01-01T23:59:59.000Z

267

Compressed Gas Cylinder Safety I. Background. Due to the nature  

E-Print Network (OSTI)

of these gases can cause a cylinder to become a missile-like projectile, destroying everything in its path (empty or full) in storage should be separated from fuel-gas cylinders and combustible materials

Suzuki, Masatsugu

268

Defect Analysis of Vehicle Compressed Natural Gas Composite Cylinder  

NLE Websites -- All DOE Office Websites (Extended Search)

Defect Analysis of Vehicle Defect Analysis of Vehicle Compressed Natural Gas Composite Cylinder A China Paper on Type 4 Cylinder, translated and presented by J. P. Hsu, PhD, Smart Chemistry Reason for Defect Analysis of CNG Composite Cylinder * Safety Issue - Four explosion accidents of auto used CNG composite material cylinders resulting huge personnel and vehicles loss. * Low Compliance Rate - Inspect 12119 Auto used CNG composite cylinders and only 3868 are qualified with compliance rate of 32%. Plastic CNG Composite Cylinder Process Fitting Internal Plastic Liner External Composite Layer Metal Fitting HDPE Cylinder Liner * HDPE has a high density, great stiffness, good anti-permeability and high melting point, but poor environmental stress cracking Resistance (ESCR). * The defects of cylinder liner quality can be

269

EPA Update: NESHAP Uranium Activities  

E-Print Network (OSTI)

measurements have been performed on high-enriched uranium (HEU) oxide fuel pins and depleted uranium metal

270

Atomic Data for Uranium (U )  

Science Conference Proceedings (OSTI)

... Uranium (U) Homepage - Introduction Finding list Select element by name. Select element by atomic number. ... Atomic Data for Uranium (U). ...

271

The development of uranium foil farication technology utilizing twin roll method for Mo-99 irradiation target  

E-Print Network (OSTI)

MDS Nordion in Canada, occupying about 75% of global supply of Mo-99 isotope, has provided the irradiation target of Mo-99 using the rod-type UAl sub x alloys with HEU(High Enrichment Uranium). ANL (Argonne National Laboratory) through co-operation with BATAN in Indonesia, leading RERTR (Reduced Enrichment for Research and Test Reactors) program substantially for nuclear non-proliferation, has designed and fabricated the annular cylinder of uranium targets, and successfully performed irradiation test, in order to develop the fabrication technology of fission Mo-99 using LEU(Low Enrichment Uranium). As the uranium foils could be fabricated in laboratory scale, not in commercialized scale by hot rolling method due to significant problems in foil quality, productivity and economic efficiency, attention has shifted to the development of new technology. Under these circumstances, the invention of uranium foil fabrication technology utilizing twin-roll casting method in KAERI is found to be able to fabricate LEU or...

Kim, C K; Park, H D

2002-01-01T23:59:59.000Z

272

ORALLOY (93.2 235U) METAL CYLINDER WITH BERYLLIUM TOP REFLECTOR  

SciTech Connect

A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, one experiment was comprised of a stack of approximately 7-inch-diameter metal discs. The bottom of the stack consisted of uranium with an approximate height of 4-1/8 inches. The top of the stack consisted of beryllium with an approximate height of 5-9/16 inches. This experiment was performed on August 20, 1963 by J. T. Mihalczo and R. G. Taylor (Ref. 1) with accompanying logbook. Both detailed and simplified model specifications are provided in this evaluation. This fast-spectra experiment was determined to represent an acceptable benchmark. The calculated eigenvalues for both the detailed and simple models are within approximately 0.5% of the benchmark values, but significantly greater than 3s from the benchmark value because the uncertainty in the benchmark is very small: 0.0002 (1s). There is significant variability between results using different neutron cross section libraries, the greatest being a ?keff of ~0.65% . Unreflected and unmoderated experiments with the same highly enriched uranium metal parts were performed at the Oak Ridge Critical Experiments Facility in the 1960s and are evaluated in HEU MET FAST 051. Thin graphite reflected (2 inches or less) experiments also using the same highly enriched uranium metal parts are evaluated in HEU MET FAST 071. Polyethylene-reflected configurations are evaluated in HEU-MET-FAST-076. Highly enriched metal annuli with beryllium cores are evaluated in HEU-MET-FAST-059.

John D. Bess; Leland M. Montierth; Raymond Reed; John T. Mihalczo

2010-09-01T23:59:59.000Z

273

METHOD FOR PURIFYING URANIUM  

DOE Patents (OSTI)

A process is given for purifying a uranium-base nuclear material. The nuclear material is dissolved in zinc or a zinc-magnesium alloy and the concentration of magnesium is increased until uranium precipitates.

Knighton, J.B.; Feder, H.M.

1960-04-26T23:59:59.000Z

274

Uranium Health Effects  

NLE Websites -- All DOE Office Websites (Extended Search)

For inhalation or ingestion of soluble or moderately soluble compounds such as uranyl fluoride (UO2F2) or uranium tetrafluoride (UF4), the uranium enters the bloodstream and...

275

Uranium from phosphate ores  

SciTech Connect

The following topics are described briefly: the way phosphate fertilizers are made; how uranium is recovered in the phosphate industry; and how to detect covert uranium recovery operations in a phsophate plant.

Hurst, F.J.

1983-01-01T23:59:59.000Z

276

Cathodoluminescence of uranium oxides  

SciTech Connect

The cathodoluminescence of uranium oxide surfaces prepared in-situ from clean uranium exposed to dry oxygen was studied. The broad asymmetric peak observed at 470 nm is attributed to F-center excitation.

Winer, K.; Colmenares, C.; Wooten, F.

1984-08-09T23:59:59.000Z

277

Uranium Quick Facts  

NLE Websites -- All DOE Office Websites (Extended Search)

Uranium Quick Facts A collection of facts about uranium, DUF6, and DOEs DUF6 inventory. Over the years, the Department of Energy has received numerous inquiries from the...

278

U.S. Energy Information Administration / 2012 Uranium Marketing Annual Report  

U.S. Energy Information Administration (EIA) Indexed Site

9 9 2012 Uranium Marketing Annual Report Release Date: May 16, 2013 Next Release Date: May 2014 Deliveries Uranium Concentrate Natural UF 6 Enriched UF 6 Natural UF 6 and Enriched UF 6 Total Purchases W W W W 9,807 Weighted-Average Price W W W W 59.44 Purchases W W W W 47,713 Weighted-Average Price W W W W 54.07 Purchases 28,642 W W 28,878 57,520 Weighted-Average Price 54.20 W W 55.80 54.99 Notes: Totals may not equal sum of components because of independent rounding. Weighted-average prices are not adjusted for inflation. Natural UF 6 is uranium hexafluoride. The natural UF 6 and enriched UF 6 quantity represents only the U 3 O 8 equivalent uranium-component quantity specified in the contract for each delivery of natural UF 6 and enriched UF 6 . The natural UF 6 and enriched UF 6 weighted-average price represent only the U

279

Uranium industry annual 1995  

SciTech Connect

The Uranium Industry Annual 1995 (UIA 1995) provides current statistical data on the U.S. uranium industry`s activities relating to uranium raw materials and uranium marketing. The UIA 1995 is prepared for use by the Congress, Federal and State agencies, the uranium and nuclear electric utility industries, and the public. It contains data for the period 1986 through 2005 as collected on the Form EIA-858, ``Uranium Industry Annual Survey``. Data collected on the ``Uranium Industry Annual Survey`` provide a comprehensive statistical characterization of the industry`s plans and commitments for the near-term future. Where aggregate data are presented in the UIA 1995, care has been taken to protect the confidentiality of company-specific information while still conveying accurate and complete statistical data. Data on uranium raw materials activities for 1986 through 1995 including exploration activities and expenditures, EIA-estimated reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities for 1994 through 2005, including purchases of uranium and enrichment services, enrichment feed deliveries, uranium fuel assemblies, filled and unfilled market requirements, uranium imports and exports, and uranium inventories are shown in Chapter 2. The methodology used in the 1995 survey, including data edit and analysis, is described in Appendix A. The methodologies for estimation of resources and reserves are described in Appendix B. A list of respondents to the ``Uranium Industry Annual Survey`` is provided in Appendix C. For the reader`s convenience, metric versions of selected tables from Chapters 1 and 2 are presented in Appendix D along with the standard conversion factors used. A glossary of technical terms is at the end of the report. 14 figs., 56 tabs.

NONE

1996-05-01T23:59:59.000Z

280

Bicarbonate leaching of uranium  

SciTech Connect

The alkaline leach process for extracting uranium from uranium ores is reviewed. This process is dependent on the chemistry of uranium and so is independent on the type of mining system (conventional, heap or in-situ) used. Particular reference is made to the geochemical conditions at Crownpoint. Some supporting data from studies using alkaline leach for remediation of uranium-contaminated sites is presented.

Mason, C.

1998-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

ETTP Environmental Monitoring Program 4-1 4. ETTP Environmental Monitoring Programs  

E-Print Network (OSTI)

of radionuclides from ETTP operations were well within the allowable derived concentration guides published in DOE to the public from uranium hexafluoride cylinder storage yards at ETTP remained below the requirements in DOE than 99%. 4.1 ETTP RADIONUCLIDE AIRBORNE EFFLUENT MONITORING Inorder to demonstrate compliance withDOE

Pennycook, Steve

282

Summary of Field Measurement on UF6 Cylinders Using Electro-Mechanically Cooled Systems  

SciTech Connect

Measurement of the enrichment of solid state UF6 stored within large metal cylinders is a task commonly performed by plant operators and inspectors. The measurement technologies typically used range from low-resolution, high-efficiency sodium iodide detectors to high-resolution, moderate-efficiency high-purity germanium (HPGe) detectors. The technology used and methods deployed are dependent upon the material being measured, environmental conditions, time constraints, and measurement-precision requirements. Operators and inspectors typically use specially designed, HPGe detectors that are cooled with liquid nitrogen in situations where high-resolution measurements are required. However, the requirement for periodically refilling the system with liquid nitrogen makes remote usage cumbersome and slow. The task of cooling the detector reduces the available time for the inspector to perform other safeguards activities while on site. If the inspector has to reduce the count time for each selected cylinder to ensure that all preselected cylinders are measured during the inspection, the resulting measurement uncertainties may be increased, making it more difficult to detect and verify potential discrepancies in the operator's declarations. However, recent advances in electromechanically cooled HPGe detectors may provide the inspector with an improved verification tool by eliminating the need for liquid nitrogen. This report provides a summary of test results for field measurements performed using electromechanically cooled HPGe detectors on depleted, natural, and low-enriched uranium cylinders. The results of the study provide valuable information to inspectors and operators regarding the capabilities and limitations of electromechanically cooled systems based on true field-measurement conditions.

McGinnis, Brent R [ORNL; Smith, Steven E [ORNL; Solodov, Alexander A [ORNL; Whitaker, J Michael [ORNL; Morgan, James B [ORNL; MayerII, Richard L. [USEC; Montgomery, J. Brent [U.S. Enrichment Corporation Paducah Gaseous Diffusion Plant

2009-01-01T23:59:59.000Z

283

Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

CNG Fuel System and CNG Fuel System and Cylinder Maintenance to someone by E-mail Share Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance on Facebook Tweet about Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance on Twitter Bookmark Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance on Google Bookmark Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance on Delicious Rank Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance on Digg Find More places to share Alternative Fuels Data Center: CNG Fuel System and Cylinder Maintenance on AddThis.com... More in this section... Natural Gas Basics Benefits & Considerations Stations Vehicles Availability Conversions Emissions Maintenance & Safety

284

URANIUM RECOVERY PROCESS  

DOE Patents (OSTI)

In the prior art processing of uranium ores, the ore is flrst digested with nitric acid and filtered, and the uranium values are then extracted tom the filtrate by contacting with an organic solvent. The insoluble residue has been processed separately in order to recover any uranium which it might contain. The improvement consists in contacting a slurry, composed of both solution and residue, with the organic solvent prior to filtration. Tbe result is that uranium values contained in the residue are extracted along with the uranium values contained th the solution in one step.

Yeager, J.H.

1958-08-12T23:59:59.000Z

285

URANIUM SEPARATION PROCESS  

DOE Patents (OSTI)

The separation of uranium from a mixture of uranium and thorium by organic solvent extraction from an aqueous solution is described. The uranium is separrted from an aqueous mixture of uranium and thorium nitrates 3 N in nitric acid and containing salting out agents such as ammonium nitrate, so as to bring ihe total nitrate ion concentration to a maximum of about 8 N by contacting the mixture with an immiscible aliphatic oxygen containing organic solvent such as diethyl carbinol, hexone, n-amyl acetate and the like. The uranium values may be recovered from the organic phase by back extraction with water.

Hyde, E.K.; Katzin, L.I.; Wolf, M.J.

1959-07-14T23:59:59.000Z

286

PRODUCTION OF URANIUM  

DOE Patents (OSTI)

The production of uranium metal by the reduction of uranium tetrafluoride is described. Massive uranium metal of high purily is produced by reacting uranium tetrafluoride with 2 to 20% stoichiometric excess of magnesium at a temperature sufficient to promote the reaction and then mantaining the reaction mass in a sealed vessel at temperature in the range of 1150 to 2000 d C, under a superatomospheric pressure of magnesium for a period of time sufficient 10 allow separation of liquid uranium and liquid magnesium fluoride into separate layers.

Spedding, F.H.; Wilhelm, H.A.; Keller, W.H.

1958-04-15T23:59:59.000Z

287

Intergalactic Filaments as Isothermal Gas Cylinders  

E-Print Network (OSTI)

Using a cosmological simulation at redshift 5, we find that the baryon-rich cores of intergalactic filaments radiating from galaxies commonly form isothermal gas cylinders. The central gas density is typically about 500 times the cosmic mean total density, and the temperature is typically 1-2 times 10^4 K, just above the Lyman alpha cooling floor. These findings argue that the hydrodynamic properties of the gas are more important than the dark matter in determining the structure. Filaments form a major pipeline for the transport of gas into the centers of galaxies. Since the temperature and ionization state of the gas completely determine the mass per unit length of an isothermal gas cylinder, our findings suggest a constraint upon gas transport into galaxies by this mechanism.

Harford, A Gayler

2010-01-01T23:59:59.000Z

288

DDES and IDDES of tandem cylinders.  

Science Conference Proceedings (OSTI)

The paper presents an overview of the authors contribution to the BANC-I Workshop on the flow past tandem cylinders (Category 2). It includes an outline of the simulation approaches, numerics, and grid used, the major results of the simulations, their comparison with available experimental data, and some preliminary conclusions. The effect of varying the spanwise period in the simulations is strong for some quantities, and not others.

Balakrishnan, R.; Garbaruk, A.; Shur, M.; Strelets, M.; Spalart, P.; New Technologies and Services - Russia; St.-Peterburg State Polytechnic Univ.; Boeing Commercial Airplanes

2010-09-09T23:59:59.000Z

289

Method for converting uranium oxides to uranium metal  

DOE Patents (OSTI)

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixtures is then cooled to a temperature less than -100/sup 0/C in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Duerksen, W.K.

1987-01-01T23:59:59.000Z

290

Method for converting uranium oxides to uranium metal  

DOE Green Energy (OSTI)

A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixture is then cooled to a temperature less than -100.degree. C. in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

Duerksen, Walter K. (Norris, TN)

1988-01-01T23:59:59.000Z

291

FAQ 1-What is uranium?  

NLE Websites -- All DOE Office Websites (Extended Search)

What is uranium? What is uranium? What is uranium? Uranium is a radioactive element that occurs naturally in low concentrations (a few parts per million) in soil, rock, and surface and groundwater. It is the heaviest naturally occurring element, with an atomic number of 92. Uranium in its pure form is a silver-colored heavy metal that is nearly twice as dense as lead. In nature, uranium atoms exist as several isotopes: primarily uranium-238, uranium-235, and a very small amount of uranium-234. (Isotopes are different forms of an element that have the same number of protons in the nucleus, but a different number of neutrons.) In a typical sample of natural uranium, most of the mass (99.27%) consists of atoms of uranium-238. About 0.72% of the mass consists of atoms of uranium-235, and a very small amount (0.0055% by mass) is uranium-234.

292

Use of Savannah River Site facilities for blend down of highly enriched uranium  

SciTech Connect

Westinghouse Savannah River Company was asked to assess the use of existing Savannah River Site (SRS) facilities for the conversion of highly enriched uranium (HEU) to low enriched uranium (LEU). The purpose was to eliminate the weapons potential for such material. Blending HEU with existing supplies of depleted uranium (DU) would produce material with less than 5% U-235 content for use in commercial nuclear reactors. The request indicated that as much as 500 to 1,000 MT of HEU would be available for conversion over a 20-year period. Existing facilities at the SRS are capable of producing LEU in the form of uranium trioxide (UO{sub 3}) powder, uranyl nitrate [UO{sub 2}(NO{sub 3}){sub 2}] solution, or metal. Additional processing, and additional facilities, would be required to convert the LEU to uranium dioxide (UO{sub 2}) or uranium hexafluoride (UF{sub 3}), the normal inputs for commercial fuel fabrication. This study`s scope does not include the cost for new conversion facilities. However, the low estimated cost per kilogram of blending HEU to LEU in SRS facilities indicates that even with fees for any additional conversion to UO{sub 2} or UF{sub 6}, blend-down would still provide a product significantly below the spot market price for LEU from traditional enrichment services. The body of the report develops a number of possible facility/process combinations for SRS. The primary conclusion of this study is that SRS has facilities available that are capable of satisfying the goals of a national program to blend HEU to below 5% U-235. This preliminary assessment concludes that several facility/process options appear cost-effective. Finally, SRS is a secure DOE site with all requisite security and safeguard programs, personnel skills, nuclear criticality safety controls, accountability programs, and supporting infrastructure to handle large quantities of special nuclear materials (SNM).

Bickford, W.E.; McKibben, J.M.

1994-02-01T23:59:59.000Z

293

Uranium Marketing Annual Report  

Gasoline and Diesel Fuel Update (EIA)

4. Uranium sellers to owners and operators of U.S. civilian nuclear power reactors, 2010-2012 2010 2011 2012 4. Uranium sellers to owners and operators of U.S. civilian nuclear power reactors, 2010-2012 2010 2011 2012 American Fuel Resources, LLC Advance Uranium Asset Management Ltd. (was Uranium Asset Management) Advance Uranium Asset Management Ltd. (was Uranium Asset Management) AREVA NC, Inc. (was COGEMA, Inc.) American Fuel Resources, LLC American Fuel Resources, LLC BHP Billiton Olympic Dam Corporation Pty Ltd AREVA NC, Inc. AREVA NC, Inc. CAMECO BHP Billiton Olympic Dam Corporation Pty Ltd BHP Billiton Olympic Dam Corporation Pty Ltd ConverDyn CAMECO CAMECO Denison Mines Corp. ConverDyn ConverDyn Energy Resources of Australia Ltd. Denison Mines Corp. Energy Fuels Resources Energy USA, Inc. Effective Energy N.V. Energy Resources of Australia Ltd.

294

Vehicle Technologies Office: Fact #643: October 4, 2010 Four Cylinder  

NLE Websites -- All DOE Office Websites (Extended Search)

3: October 4, 3: October 4, 2010 Four Cylinder Engine Installations Continue to Rise to someone by E-mail Share Vehicle Technologies Office: Fact #643: October 4, 2010 Four Cylinder Engine Installations Continue to Rise on Facebook Tweet about Vehicle Technologies Office: Fact #643: October 4, 2010 Four Cylinder Engine Installations Continue to Rise on Twitter Bookmark Vehicle Technologies Office: Fact #643: October 4, 2010 Four Cylinder Engine Installations Continue to Rise on Google Bookmark Vehicle Technologies Office: Fact #643: October 4, 2010 Four Cylinder Engine Installations Continue to Rise on Delicious Rank Vehicle Technologies Office: Fact #643: October 4, 2010 Four Cylinder Engine Installations Continue to Rise on Digg Find More places to share Vehicle Technologies Office: Fact #643:

295

Preparation of uranium compounds  

SciTech Connect

UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

2013-02-19T23:59:59.000Z

296

Process for continuous production of metallic uranium and uranium alloys  

DOE Patents (OSTI)

A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO{sub 3}), or any other substantially stable uranium oxide, to form the uranium dioxide (UO{sub 2}). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl{sub 4}), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation. 4 figs.

Hayden, H.W. Jr.; Horton, J.A.; Elliott, G.R.B.

1995-06-06T23:59:59.000Z

297

Process for continuous production of metallic uranium and uranium alloys  

DOE Patents (OSTI)

A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO.sub.3), or any other substantially stable uranium oxide, to form the uranium dioxide (UO.sub.2). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl.sub.4), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation.

Hayden, Jr., Howard W. (Oakridge, TN); Horton, James A. (Livermore, CA); Elliott, Guy R. B. (Los Alamos, NM)

1995-01-01T23:59:59.000Z

298

First Principles Calculations of Uranium and Uranium-Zirconium Alloys  

Science Conference Proceedings (OSTI)

Presentation Title, First Principles Calculations of Uranium and Uranium- Zirconium Alloys. Author(s), Benjamin Good, Benjamin Beeler, Chaitanya Deo, Sergey...

299

EIS-0360: Final Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE))

Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site

300

EIS-0359: Draft Environmental Impact Statement  

Energy.gov (U.S. Department of Energy (DOE))

Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

EIS-0360: Record of Decision  

Energy.gov (U.S. Department of Energy (DOE))

Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site

302

EIS-0359: Record of Decision  

Energy.gov (U.S. Department of Energy (DOE))

Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site

303

Uranium Purchases Report  

Reports and Publications (EIA)

Final issue. This report details natural and enriched uranium purchases as reported by owners and operators of commercial nuclear power plants. 1996 represents the most recent publication year.

Douglas Bonnar

1996-06-01T23:59:59.000Z

304

PRODUCTION OF URANIUM  

DOE Patents (OSTI)

An improved process is described for the magnesium reduction of UF/sub 4/ to produce uranium metal. In the past, there have been undesirable premature reactions between the Mg and the bomb liner or the UF/sub 4/ before the actual ignition of the bomb reaction. Since these premature reactions impair the yield of uranium metal, they have been inhibited by forming a protective film upon the particles of Mg by reacting it with hydrated uranium tetrafluoride, sodium bifluoride, uranyl fluoride, or uranium trioxide. This may be accomplished by adding about 0.5 to 2% of the additive to the bomb charge.

Ruehle, A.E.; Stevenson, J.W.

1957-11-12T23:59:59.000Z

305

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

1. U.S. uranium drilling activities, 2003-2012 Exploration Drilling Development Drilling Exploration and Development Drilling Year Number of Holes Feet (thousand) Number of Holes...

306

Uranium 'pearls' before slime  

NLE Websites -- All DOE Office Websites (Extended Search)

harm to themselves, scientists have wondered how on Earth these microbes do it. For Shewanella oneidensis, a microbe that modifies uranium chemistry, the pieces are coming...

307

Uranium Purchases Report 1995  

U.S. Energy Information Administration (EIA)

DOE/EIA0570(95) Distribution Category UC950 Uranium Purchases Report 1995 June 1996 Energy Information Administration Office of Coal, Nuclear, ...

308

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

Totals may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration: Form EIA-851A, "Domestic Uranium Production Report"...

309

Radial Segregation of Granular Materials in Rotating Cylinders  

Science Conference Proceedings (OSTI)

... tablet manufacturing to cement production to rock cutting transportation with drilling fluids. Rotating cylinders are used as kilns, mixers, dryers and granulators .

310

US Department of Energy Uranium Enrichment Activity. Financial statements, September 30, 1991 and 1990  

SciTech Connect

KPMG Peat Marwick (KPMG), Certified Public Accountants, has completed its audit of the Department of Energy`s Uranium Enrichment Activity (UEA) financial.statements as of September 30, 1991. The purpose of the audit was to determine whether (1) the financial statements were presented fairly in accordance with applicable accounting principles, (2) the auditee complied with all applicable laws and regulations that may have materially affected the financial statements, and (3) the internal accounting controls, taken as a whole, were adequate. The US Government, through the Department of Energy (DOE) and the management and operating contractor, operates the UEA to enrich uranium hexafluoride in the isotope U-235 for commercial power reactor operators, as further discussed in note 1 of the financial statements. The enrichment of uranium for Government program users, which had been a function of UEA, was transferred outside the UEA affective September 30, 1991, as described in note 3 of the financial statements. UEA is a part of DOE and does not exist as a separate legal entity. For financial reporting purposes, the entity is defined as those activities which provide enriching services to its customers. The financial statements are prepared by extracting and adjusting UEA related data from the financial records of DOE and its contractors.

Not Available

1992-06-16T23:59:59.000Z

311

Arms Control and Nonproliferation Technologies Second Quarter 1993I................................................................................................................................................................  

E-Print Network (OSTI)

Observers from the Department of Energy and the Defense Nuclear Agency watch as a tag/seal is applied to a uranium hexafluoride cylinder during the demonstration held at Portsmouth Gaseous Diffusion Plant. In June 1993, the Department of Energy conducted a demonstration of the ability to tag and seal potential nuclear material containers appropriate for the U.S.-Russian conversion of highly enriched uranium (HEU) to lowenrichment uranium (LEU). Begun in the Office of Arms Control and Nonproliferation, the task was carried out after DOE's reorganization by the Qffice of Research and Development. Tags and seals that were previously developed at the DOE national laboratories and under the sponsorship of the Defense Nuclear Agency were demonstrated on three possible containers: the Department of Transportation Specification 6M HEU container, the AT-400R HEU container, and the Type 30B uranium hexafluoride cylinder.

Thepurposeof Armscontroland

1993-01-01T23:59:59.000Z

312

URANIUM LEACHING AND RECOVERY PROCESS  

DOE Patents (OSTI)

A process is described for recovering uranium from carbonate leach solutions by precipitating uranium as a mixed oxidation state compound. Uranium is recovered by adding a quadrivalent uranium carbon;te solution to the carbonate solution, adjusting the pH to 13 or greater, and precipitating the uranium as a filterable mixed oxidation state compound. In the event vanadium occurs with the uranium, the vanadium is unaffected by the uranium precipitation step and remains in the carbonate solution. The uranium-free solution is electrolyzed in the cathode compartment of a mercury cathode diaphragm cell to reduce and precipitate the vanadium.

McClaine, L.A.

1959-08-18T23:59:59.000Z

313

2012 Domestic Uranium Production Report  

U.S. Energy Information Administration (EIA)

udrilling 2012 Domestic Uranium Production Report Next Release Date: May 2014 Table 1. U.S. uranium drilling activities, 2003-2012 Year Exploration Drilling

314

Uranium industry annual 1993  

SciTech Connect

Uranium production in the United States has declined dramatically from a peak of 43.7 million pounds U{sub 3}O{sub 8} (16.8 thousand metric tons uranium (U)) in 1980 to 3.1 million pounds U{sub 3}O{sub 8} (1.2 thousand metric tons U) in 1993. This decline is attributed to the world uranium market experiencing oversupply and intense competition. Large inventories of uranium accumulated when optimistic forecasts for growth in nuclear power generation were not realized. The other factor which is affecting U.S. uranium production is that some other countries, notably Australia and Canada, possess higher quality uranium reserves that can be mined at lower costs than those of the United States. Realizing its competitive advantage, Canada was the world`s largest producer in 1993 with an output of 23.9 million pounds U{sub 3}O{sub 8} (9.2 thousand metric tons U). The U.S. uranium industry, responding to over a decade of declining market prices, has downsized and adopted less costly and more efficient production methods. The main result has been a suspension of production from conventional mines and mills. Since mid-1992, only nonconventional production facilities, chiefly in situ leach (ISL) mining and byproduct recovery, have operated in the United States. In contrast, nonconventional sources provided only 13 percent of the uranium produced in 1980. ISL mining has developed into the most cost efficient and environmentally acceptable method for producing uranium in the United States. The process, also known as solution mining, differs from conventional mining in that solutions are used to recover uranium from the ground without excavating the ore and generating associated solid waste. This article describes the current ISL Yang technology and its regulatory approval process, and provides an analysis of the factors favoring ISL mining over conventional methods in a declining uranium market.

Not Available

1994-09-01T23:59:59.000Z

315

Determination of the Relative Amount of Fluorine in Uranium Oxyfluoride Particles using Secondary Ion Mass Spectrometry and Optical Spectroscopy  

Science Conference Proceedings (OSTI)

Both nuclear forensics and environmental sampling depend upon laboratory analysis of nuclear material that has often been exposed to the environment after it has been produced. It is therefore important to understand how those environmental conditions might have changed the chemical composition of the material over time, particularly for chemically sensitive compounds. In the specific case of uranium enrichment facilities, uranium-bearing particles stem from small releases of uranium hexafluoride, a highly reactive gas that hydrolyzes upon contact with moisture from the air to form uranium oxyfluoride (UO{sub 2}F{sub 2}) particles. The uranium isotopic composition of those particles is used by the International Atomic Energy Agency (IAEA) to verify whether a facility is compliant with its declarations. The present study, however, aims to demonstrate how knowledge of time-dependent changes in chemical composition, particle morphology and molecular structure can contribute to an even more reliable interpretation of the analytical results. We prepared a set of uranium oxyfluoride particles at the Institute for Reference Materials and Measurements (IRMM, European Commission, Belgium) and followed changes in their composition, morphology and structure with time to see if we could use these properties to place boundaries on the particle exposure time in the environment. Because the rate of change is affected by exposure to UV-light, humidity levels and elevated temperatures, the samples were subjected to varying conditions of those three parameters. The NanoSIMS at LLNL was found to be the optimal tool to measure the relative amount of fluorine in individual uranium oxyfluoride particles. At PNNL, cryogenic laser-induced time-resolved U(VI) fluorescence microspectroscopy (CLIFS) was used to monitor changes in the molecular structure.

Kips, R; Kristo, M J; Hutcheon, I D; Amonette, J; Wang, Z; Johnson, T; Gerlach, D; Olsen, K B

2009-05-29T23:59:59.000Z

316

Reconstruction of mechanically recorded sound from an edison cylinder using three dimensional non-contact optical surface metrology  

E-Print Network (OSTI)

Recorded Sound from an Edison Cylinder using Threeet al. , Optomechanical method of Edison cylinders soundComments on Historical Edison Cylinder Styli , Association

Fadeyev, V.; Haber, C.; Maul, C.; McBride, J.W.; Golden, M.

2004-01-01T23:59:59.000Z

317

CYLINDER LENS ALIGNMENT IN THE LTP  

SciTech Connect

The Long Trace Profiler (LTP), is well-suited for the measurement of the axial figure of cylindrical mirrors that usually have a long radius of curvature in the axial direction but have a short radius of curvature in the sagittal direction. The sagittal curvature causes the probe beam to diverge in the transverse direction without coming to a focus on the detector, resulting in a very weak signal. It is useful to place a cylinder lens into the optical system above the mirror under test to refocus the sagittal divergence and increase the signal level. A positive cylinder lens can be placed at two positions above the surface: the Cat's Eye reflection position and the Wavefront-Matching position. The Cat's Eye position, is very tolerant to mirror misalignment, which is not good if absolute axial radius of curvature is to be measured. Lateral positioning and rotational misalignments of lens and the mirror combine to produce unusual profile results. This paper looks at various alignment issues with measurements and by raytrace simulations to determine the best strategy to minimize radius of curvature errors in the measurement of cylindrical aspheres.

TAKACS, P.Z.

2005-07-26T23:59:59.000Z

318

Uranium from phosphate ores  

Science Conference Proceedings (OSTI)

Phosphate rock, the major raw material for phosphate fertilizers, contains uranium that can be recovered when the rock is processed. This makes it possible to produce uranium in a country that has no uranium ore deposits. The author briefly describes the way that phosphate fertilizers are made, how uranium is recovered in the phosphate industry, and how to detect uranium recovery operations in a phosphate plant. Uranium recovery from the wet-process phosphoric acid involves three unit operations: (1) pretreatment to prepare the acid; (2) solvent extraction to concentrate the uranium; (3) post treatment to insure that the acid returning to the acid plant will not be harmful downstream. There are 3 extractants that are capable of extracting uranium from phosphoric acid. The pyro or OPPA process uses a pyrophosphoric acid that is prepared on site by reacting an organic alcohol (usually capryl alcohol) with phosphorous pentoxide. The DEPA-TOPO process uses a mixture of di(2-ethylhexyl)phosphoric acid (DEPA) and trioctyl phosphine oxide (TOPO). The components can be bought separately or as a mixture. The OPAP process uses octylphenyl acid phosphate, a commercially available mixture of mono- and dioctylphenyl phosphoric acids. All three extractants are dissolved in kerosene-type diluents for process use.

Hurst, F.J.

1983-01-01T23:59:59.000Z

319

DECONTAMINATION OF URANIUM  

DOE Patents (OSTI)

A process is given for separating fission products from uranium by extracting the former into molten aluminum. Phase isolation can be accomplished by selectively hydriding the uranium at between 200 and 300 deg C and separating the hydride powder from coarse particles of fissionproduct-containing aluminum. (AEC)

Spedding, F.H.; Butler, T.A.

1962-05-15T23:59:59.000Z

320

URANIUM SEPARATION PROCESS  

DOE Patents (OSTI)

The separation of uranium from an aqueous solution containing a water soluble uranyl salt is described. The process involves adding an alkali thiocyanate to the aqueous solution, contacting the resulting solution with methyl isobutyl ketons and separating the resulting aqueous and organic phase. The uranium is extracted in the organic phase as UO/sub 2/(SCN)/sub/.

McVey, W.H.; Reas, W.H.

1959-03-10T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Study of Chemical Changes in Uranium Oxyfluoride Particles Progress Report March - October 2009  

SciTech Connect

Nuclear forensics relies on the analysis of certain sample characteristics to determine the origin and history of a nuclear material. In the specific case of uranium enrichment facilities, it is the release of trace amounts of uranium hexafluoride (UF{sub 6}) gas - used for the enrichment of uranium - that leaves a process-characteristic fingerprint. When UF{sub 6} gas interacts with atmospheric moisture, uranium oxyfluoride particles or particle agglomerates are formed with sizes ranging from several microns down to a few tens of nanometers. These particles are routinely collected by safeguards organizations, such as the International Atomic Energy Agency (IAEA), allowing them to verify whether a facility is compliant with its declarations. Spectrometric analysis of uranium particles from UF{sub 6} hydrolysis has revealed the presence of both particles that contain fluorine, and particles that do not. It is therefore assumed that uranium oxyfluoride is unstable, and decomposes to form uranium oxide. Understanding the rate of fluorine loss in uranium oxyfluoride particles, and the parameters that control it, may therefore contribute to placing boundaries on the particle's exposure time in the environment. Expressly for the purpose of this study, we prepared a set of uranium oxyfluoride particles at the Institute for Reference Materials and Measurements (EU-JRC-IRMM) from a static release of UF{sub 6} in a humid atmosphere. The majority of the samples was stored in controlled temperature, humidity and lighting conditions. Single particles were characterized by a suite of micro-analytical techniques, including NanoSIMS, micro-Raman spectrometry (MRS), scanning (SEM) and transmission (TEM) electron microscopy, energy-dispersive X-ray spectrometry (EDX) and focused ion beam (FIB). The small particle size was found to be the main analytical challenge. The relative amount of fluorine, as well as the particle chemical composition and morphology were determined at different stages in the ageing process, and immediately after preparation. This report summarizes our most recent findings for each of the analytical techniques listed above, and provides an outlook on what remains to be resolved. Additional spectroscopic and mass spectrometric measurements were carried out at Pacific Northwest National Laboratory, but are not included in this summary.

Kips, R; Kristo, M; Hutcheon, I

2009-11-22T23:59:59.000Z

322

Uranium Marketing Annual Report  

Gasoline and Diesel Fuel Update (EIA)

Uranium Marketing Uranium Marketing Annual Report May 2011 www.eia.gov U.S. Department of Energy Washington, DC 20585 This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States Government. The views in this report therefore should not be construed as representing those of the Department of Energy or other Federal agencies. U.S. Energy Information Administration | 2010 Uranium Marketing Annual Report ii Contacts This report was prepared by the staff of the Renewables and Uranium Statistics Team, Office of Electricity, Renewables, and Uranium Statistics. Questions about the preparation and content of this report may be directed to Michele Simmons, Team Leader,

323

recycled_uranium.cdr  

Office of Legacy Management (LM)

Recycled Uranium and Transuranics: Recycled Uranium and Transuranics: Their Relationship to Weldon Spring Site Remedial Action Project Introduction Historical Perspective On August 8, 1999, Energy Secretary Bill Richardson announced a comprehensive set of actions to address issues raised at the Paducah, Kentucky, Gaseous Diffusion Plant that may have had the potential to affect the health of the workers. One of the issues addressed the need to determine the extent and significance of radioactive fission products and transuranic elements in the uranium feed and waste products throughout the U.S. Department of Energy (DOE) national complex. Subsequently, a DOE agency-wide Recycled Uranium Mass Balance Project (RUMBP) was initiated. For the Weldon Spring Uranium Feed Materials Plant (WSUFMP or later referred to as Weldon Spring),

324

URANIUM PRECIPITATION PROCESS  

DOE Patents (OSTI)

A method for the recovery of uranium from sulfuric acid solutions is described. In the present process, sulfuric acid is added to the uranium bearing solution to bring the pH to between 1 and 1.8, preferably to about 1.4, and aluminum metal is then used as a reducing agent to convert hexavalent uranium to the tetravalent state. As the reaction proceeds, the pH rises amd a selective precipitation of uranium occurs resulting in a high grade precipitate. This process is an improvement over the process using metallic iron, in that metallic aluminum reacts less readily than metallic iron with sulfuric acid, thus avoiding consumption of the reducing agent and a raising of the pH without accomplishing the desired reduction of the hexavalent uranium in the solution. Another disadvantage to the use of iron is that positive ferric ions will precipitate with negative phosphate and arsenate ions at the pH range employed.

Thunaes, A.; Brown, E.A.; Smith, H.W.; Simard, R.

1957-12-01T23:59:59.000Z

325

Production and Handling Slide 29: UF6 Cylinder Fill Limit Criteria  

NLE Websites -- All DOE Office Websites (Extended Search)

Criteria Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents UF6 Cylinder Fill Limit Criteria No UF6 cylinder shall be filled...

326

India's Worsening Uranium Shortage  

Science Conference Proceedings (OSTI)

As a result of NSG restrictions, India cannot import the natural uranium required to fuel its Pressurized Heavy Water Reactors (PHWRs); consequently, it is forced to rely on the expediency of domestic uranium production. However, domestic production from mines and byproduct sources has not kept pace with demand from commercial reactors. This shortage has been officially confirmed by the Indian Planning Commissions Mid-Term Appraisal of the countrys current Five Year Plan. The report stresses that as a result of the uranium shortage, Indian PHWR load factors have been continually decreasing. The Uranium Corporation of India Ltd (UCIL) operates a number of underground mines in the Singhbhum Shear Zone of Jharkhand, and it is all processed at a single mill in Jaduguda. UCIL is attempting to aggrandize operations by establishing new mines and mills in other states, but the requisite permit-gathering and development time will defer production until at least 2009. A significant portion of Indias uranium comes from byproduct sources, but a number of these are derived from accumulated stores that are nearing exhaustion. A current maximum estimate of indigenous uranium production is 430t/yr (230t from mines and 200t from byproduct sources); whereas, the current uranium requirement for Indian PHWRs is 455t/yr (depending on plant capacity factor). This deficit is exacerbated by the additional requirements of the Indian weapons program. Present power generation capacity of Indian nuclear plants is 4350 MWe. The power generation target set by the Indian Department of Atomic Energy (DAE) is 20,000 MWe by the year 2020. It is expected that around half of this total will be provided by PHWRs using indigenously supplied uranium with the bulk of the remainder provided by breeder reactors or pressurized water reactors using imported low-enriched uranium.

Curtis, Michael M.

2007-01-15T23:59:59.000Z

327

RECOVERY OF URANIUM VALUES  

DOE Patents (OSTI)

A liquid-liquid extraction method is presented for recovering uranium values from an aqueous acidic solution by means of certain high molecular weight amine in the amine classes of primary, secondary, heterocyclic secondary, tertiary, or heterocyclic tertiary. The uranium bearing aqueous acidic solution is contacted with the selected amine dissolved in a nonpolar water-immiscible organic solvent such as kerosene. The uranium which is substantially completely exiracted by the organic phase may be stripped therefrom by waters and recovered from the aqueous phase by treatment into ammonia to precipitate ammonium diuranate.

Brown, K.B.; Crouse, D.J. Jr.; Moore, J.G.

1959-03-10T23:59:59.000Z

328

BEHAVIOR OF METALLIC INCLUSIONS IN URANIUM DIOXIDE  

E-Print Network (OSTI)

Metallic Inclusions in Uranium Dioxide", LBL-11117 (1980).in Hypostoichiornetric Uranium Dioxide 11 , LBL-11095 (OF METALLIC INCLUSIONS IN URANIUM DIOXIDE Rosa L. Yang and

Yang, Rosa L.

2013-01-01T23:59:59.000Z

329

Notice of Change in National Environmental Policy (NEPA) Compliance Approach for the Depleted Uranium Hexafluoride (DUF6) Conversion Facilities Project (4/28/03)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

68 68 Federal Register / Vol. 68, No. 81 / Monday, April 28, 2003 / Notices ''Browse Pending Collections'' link and by clicking on link number 2270. When you access the information collection, click on ''Download Attachments'' to view. Written requests for information should be addressed to Vivian Reese, Department of Education, 400 Maryland Avenue, SW., Room 4050, Regional Office Building 3, Washington, DC 20202-4651 or to the e-mail address vivan.reese@ed.gov. Requests may also be electronically mailed to the internet address OCIO_RIMG@ed.gov or faxed to 202-708-9346. Please specify the complete title of the information collection when making your request. Comments regarding burden and/or the collection activity requirements should be directed to Joseph Schubart at

330

Record of Decision for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site (DOE/EIS-0360) (07/20/04)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

49 49 Federal Register / Vol. 69, No. 143 / Tuesday, July 27, 2004 / Notices halseypj@oro.doe.gov or check the Web site at www.oakridge.doe.gov/em/ssab. SUPPLEMENTARY INFORMATION: Purpose of the Board: The purpose of the Board is to make recommendations to DOE in the areas of environmental restoration, waste management, and related activities. Tentative Agenda 8 a.m.-Introductions, overview of meeting agenda and logistics (Dave Mosby) 8:15 a.m.-Past year evaluation-Board and stakeholder survey results, what worked, what can be improved (Facilitator) 9:50 a.m.-Break 10:05 a.m.-Past year evaluation continued 10:45 a.m.-Summaries and Q&A on the most important issues to DOE, TN Department of Environment & Conservation, and EPA (Facilitator) 11:30 a.m.-Lunch

331

Notice of Intent To Prepare an Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities (DOE/EIS-0329) (9/18/01)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

23 23 Federal Register / Vol. 66, No. 181 / Tuesday, September 18, 2001 / Notices Section 615-Procedural Safeguards Topic Addressed: Due Process Hearings * Letter dated April 19, 2001 to Virginia Department of Education Director Judith A. Douglas, regarding whether a State educational agency is required to convene a due process hearing initiated by someone other than the parent of a child with a disability or a public agency. Topic Addressed: Surrogate Parents * Letter dated April 16, 2001 to Pinal County, Arizona Deputy County Attorney Linda L. Harant, regarding the appointment of surrogate parents for children who are wards of a tribal court. Topic Addressed: Student Discipline * Letter dated April 16, 2001 to Professor Perry A. Zirkel, regarding the calculation of disciplinary removals of

332

Advance Notice of Intent To Prepare an Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities (DOE/EIS-0329) (5/7/01)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

010 010 Federal Register / Vol. 66, No. 88 / Monday, May 7, 2001 / Notices centers. The commenter believes that by working independently of schools, the centers can better assist families who do not feel connected with the schools and provide families with the tools needed to create change in the schools. Discussion: The Secretary is not requiring non-profit organizations to apply in consortium with one or more LEAs. However, the Secretary believes that strengthening school-community- family partnerships will help children in low-performing schools succeed in school. Under the priority, the parent centers still will have considerable autonomy in designing proposals that best meet local needs and in coordinating with low-performing schools in implementing comprehensive strategies to assist children in these

333

Notice of Change in National Environmental Policy Act (NEPA) Compliance Approach for the Depleted Uranium Hexafluoride (DUF6) Conversion Facilities Project  

NLE Websites -- All DOE Office Websites (Extended Search)

68 68 Federal Register / Vol. 68, No. 81 / Monday, April 28, 2003 / Notices ''Browse Pending Collections'' link and by clicking on link number 2270. When you access the information collection, click on ''Download Attachments'' to view. Written requests for information should be addressed to Vivian Reese, Department of Education, 400 Maryland Avenue, SW., Room 4050, Regional Office Building 3, Washington, DC 20202-4651 or to the e-mail address vivan.reese@ed.gov. Requests may also be electronically mailed to the internet address OCIO_RIMG@ed.gov or faxed to 202-708-9346. Please specify the complete title of the information collection when making your request. Comments regarding burden and/or the collection activity requirements should be directed to Joseph Schubart at

334

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

4. U.S. uranium mills by owner, location, capacity, and operating status at end of the year, 2008-2012 4. U.S. uranium mills by owner, location, capacity, and operating status at end of the year, 2008-2012 Mill Owner Mill Name County, State (existing and planned locations) Milling Capacity (short tons of ore per day) Operating Status at End of the Year 2008 2009 2010 2011 2012 Cotter Corporation Canon City Mill Fremont, Colorado 0 Standby Standby Standby Reclamation Demolished Denison White Mesa LLC White Mesa Mill San Juan, Utah 2,000 Operating Operating Operating Operating Operating Energy Fuels Resources Corporation Piñon Ridge Mill Montrose, Colorado 500 Developing Developing Developing Permitted And Licensed Partially Permitted And Licensed Kennecott Uranium Company/Wyoming Coal Resource Company Sweetwater Uranium Project Sweetwater, Wyoming 3,000 Standby Standby Standby Standby Standby

335

Uranium Management and Policy  

Energy.gov (U.S. Department of Energy (DOE))

The Office of Uranium Management and Policy (NE-54), as part of the Office of Fuel Cycle Technologies (NE-5), supports the Department of Energy (DOE) by assuring domestic supplies of fuel for...

336

Chemical Forms of Uranium  

NLE Websites -- All DOE Office Websites (Extended Search)

such as water vapor in the air, the UF6 and water react, forming corrosive hydrogen fluoride (HF) and a uranium-fluoride compound called uranyl fluoride (UO2F2). For this reason,...

337

300 AREA URANIUM CONTAMINATION  

SciTech Connect

{sm_bullet} Uranium fuel production {sm_bullet} Test reactor and separations experiments {sm_bullet} Animal and radiobiology experiments conducted at the. 331 Laboratory Complex {sm_bullet} .Deactivation, decontamination, decommissioning,. and demolition of 300 Area facilities

BORGHESE JV

2009-07-02T23:59:59.000Z

338

Uranium-Based Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Uranium-Based Catalysts S. H. Overbury, Cyrus Riahi-Nezhad, Zongtao Zhang, Sheng Dai, and Jonathan Haire Oak Ridge National Laboratory* P.O. Box 2008 Oak Ridge, Tennessee...

339

Domestic Uranium Production Report  

Annual Energy Outlook 2012 (EIA)

6. Employment in the U.S. uranium production industry by category, 2003-2012 person-years Year Exploration Mining Milling Processing Reclamation Total 2003 W W W W 117 321 2004 18...

340

Uranium tailings bibliography  

SciTech Connect

A bibliography containing 1,212 references is presented with its focus on the general problem of reducing human exposure to the radionuclides contained in the tailings from the milling of uranium ore. The references are divided into seven broad categories: uranium tailings pile (problems and perspectives), standards and philosophy, etiology of radiation effects, internal dosimetry and metabolism, environmental transport, background sources of tailings radionuclides, and large-area decontamination. (JSR)

Holoway, C.F.; Goldsmith, W.A.; Eldridge, V.M.

1975-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

URANIUM EXTRACTION PROCESS  

DOE Patents (OSTI)

A process is described for recovering uranium values from acidic aqueous solutions containing hexavalent uranium by contacting the solution with an organic solution comprised of a substantially water-immiscible organlc diluent and an organic phosphate to extract the uranlum values into the organic phase. Carbon tetrachloride and a petroleum hydrocarbon fraction, such as kerosene, are sultable diluents to be used in combination with organlc phosphates such as dibutyl butylphosphonate, trlbutyl phosphine oxide, and tributyl phosphate.

Baldwin, W.H.; Higgins, C.E.

1958-12-16T23:59:59.000Z

342

Depleted uranium valuation  

SciTech Connect

The following uses for depleted uranium were examined to determine its value: a substitute for lead in shielding applications, feed material in gaseous diffusion enrichment facilities, feed material for an advanced enrichment concept, Mixed Oxide (MOx) diluent and blanket material in LMFBRs, and fertile material in LMFBR systems. A range of depleted uranium values was calculated for each of these applications. The sensitivity of these values to analysis assumptions is discussed. 9 tables.

Lewallen, M.A.; White, M.K.; Jenquin, U.P.

1979-04-01T23:59:59.000Z

343

Uranium purchases report 1994  

SciTech Connect

US utilities are required to report to the Secretary of Energy annually the country of origin and the seller of any uranium or enriched uranium purchased or imported into the US, as well as the country of origin and seller of any enrichment services purchased by the utility. This report compiles these data and also contains a glossary of terms and additional purchase information covering average price and contract duration. 3 tabs.

1995-07-01T23:59:59.000Z

344

URANIUM SEPARATION PROCESS  

DOE Patents (OSTI)

A method of separating uranium oxides from PuO/sub 2/, ThO/sub 2/, and other actinide oxides is described. The oxide mixture is suspended in a fused salt melt and a chlorinating agent such as chlorine gas or phosgene is sparged through the suspension. Uranium oxides are selectively chlorinated and dissolve in the melt, which may then be filtered to remove the unchlorinated oxides of the other actinides. (AEC)

Lyon, W.L.

1962-04-17T23:59:59.000Z

345

Method for the recovery of uranium values from uranium tetrafluoride  

DOE Patents (OSTI)

The invention is a novel method for the recovery of uranium from dry, particulate uranium tetrafluoride. In one aspect, the invention comprises reacting particulate uranium tetrafluoride and calcium oxide in the presence of gaseous oxygen to effect formation of the corresponding alkaline earth metal uranate and alkaline earth metal fluoride. The product uranate is highly soluble in various acidic solutions whereas the product fluoride is virtually insoluble therein. The product mixture of uranate and alkaline earth metal fluoride is contacted with a suitable acid to provide a uranium-containing solution, from which the uranium is recovered. The invention can achieve quantitative recovery of uranium in highly pure form.

Kreuzmann, A.B.

1982-10-27T23:59:59.000Z

346

Method for the recovery of uranium values from uranium tetrafluoride  

DOE Patents (OSTI)

The invention is a novel method for the recovery of uranium from dry, particulate uranium tetrafluoride. In one aspect, the invention comprises reacting particulate uranium tetrafluoride and calcium oxide in the presence of gaseous oxygen to effect formation of the corresponding alkaline earth metal uranate and alkaline earth metal fluoride. The product uranate is highly soluble in various acidic solutions wherein the product fluoride is virtually insoluble therein. The product mixture of uranate and alkaline earth metal fluoride is contacted with a suitable acid to provide a uranium-containing solution, from which the uranium is recovered. The invention can achieve quantitative recovery of uranium in highly pure form.

Kreuzmann, Alvin B. (Cincinnati, OH)

1983-01-01T23:59:59.000Z

347

Speed control with end cushion for high speed air cylinder  

DOE Patents (OSTI)

A high speed air cylinder in which the longitudinal movement of the piston within the air cylinder tube is controlled by pressurizing the air cylinder tube on the accelerating side of the piston and releasing pressure at a controlled rate on the decelerating side of the piston. The invention also includes a method for determining the pressure required on both the accelerating and decelerating sides of the piston to move the piston with a given load through a predetermined distance at the desired velocity, bringing the piston to rest safely without piston bounce at the end of its complete stroke. 4 figs.

Stevens, W.W.; Solbrig, C.W.

1989-06-20T23:59:59.000Z

348

Static fluid cylinders and their fields: global solutions  

E-Print Network (OSTI)

The global properties of static perfect-fluid cylinders and their external Levi-Civita fields are studied both analytically and numerically. The existence and uniqueness of global solutions is demonstrated for a fairly general equation of state of the fluid. In the case of a fluid admitting a non-vanishing density for zero pressure, it is shown that the cylinder's radius has to be finite. For incompressible fluid, the field equations are solved analytically for nearly Newtonian cylinders and numerically in fully relativistic situations. Various physical quantities such as proper and circumferential radii, external conicity parameter and masses per unit proper/coordinate length are exhibited graphically.

J. Bicak; T. Ledvinka; B. G. Schmidt; M. Zofka

2004-03-02T23:59:59.000Z

349

EGR Distribution in Engine Cylinders Using Advanced Virtual Simulation  

DOE Green Energy (OSTI)

Exhaust Gas Recirculation (EGR) is a well-known technology for reduction of NOx in diesel engines. With the demand for extremely low engine out NOx emissions, it is important to have a consistently balanced EGR flow to individual engine cylinders. Otherwise, the variation in the cylinders' NOx contribution to the overall engine emissions will produce unacceptable variability. This presentation will demonstrate the effective use of advanced virtual simulation in the development of a balanced EGR distribution in engine cylinders. An initial design is analyzed reflecting the variance in the EGR distribution, quantitatively and visually. Iterative virtual lab tests result in an optimized system.

Fan, Xuetong

2000-08-20T23:59:59.000Z

350

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

10. Uranium reserve estimates at the end of 2012 10. Uranium reserve estimates at the end of 2012 million pounds U3O8 Forward Cost2 Uranium Reserve Estimates1 by Mine and Property Status, Mining Method, and State(s) $0 to $30 per pound $0 to $50 per pound $0 to $100 per pound Properties with Exploration Completed, Exploration Continuing, and Only Assessment Work W W 102.0 Properties Under Development for Production W W W Mines in Production W 21.4 W Mines Closed Temporarily and Closed Permanently W W 133.1 In-Situ Leach Mining W W 128.6 Underground and Open Pit Mining W W 175.4 Arizona, New Mexico and Utah 0 W 164.7 Colorado, Nebraska and Texas W W 40.8 Wyoming W W 98.5 Total 51.8 W 304.0 1 Sixteen respondents reported reserve estimates on 71 mines and properties. These uranium reserve estimates cannot be compared with the much larger historical data set of uranium reserves that were published in the July 2010 report U.S. Uranium Reserves Estimates at http://www.eia.gov/cneaf/nuclear/page/reserves/ures.html. Reserves, as reported here, do not necessarily imply compliance with U.S. or Canadian government definitions for purposes of investment disclosure.

351

Audit Report: IG-0642 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 2 Audit Report: IG-0642 March 18, 2004 Depleted Uranium Hexafluoride Conversion For over 30 years, the Department of Energy (Department) operated geous diffusion plans in Oak Ridge, Tennessee; Portsmouth, Ohio; and Paducah, Kentucky, to meet its enriched uranium needs. As a byproduct of the enrichment process, about 704,000 metric tons of depleted uranium hexafluoride were generated and stored in approximately 58,00 cylinders at the enrichment plants. While the cylinders are currently stored with little risk to workers, the public, and the environment, they are gradually deteriorating. Prolonged storage has the potential to increase the Department's safety and health risks from handling operations, natural disasters, or malicious acts. Audit Report: IG-0642

352

FAQ 5-Is uranium radioactive?  

NLE Websites -- All DOE Office Websites (Extended Search)

Is uranium radioactive? Is uranium radioactive? Is uranium radioactive? All isotopes of uranium are radioactive, with most having extremely long half-lives. Half-life is a measure of the time it takes for one half of the atoms of a particular radionuclide to disintegrate (or decay) into another nuclear form. Each radionuclide has a characteristic half-life. Half-lives vary from millionths of a second to billions of years. Because radioactivity is a measure of the rate at which a radionuclide decays (for example, decays per second), the longer the half-life of a radionuclide, the less radioactive it is for a given mass. The half-life of uranium-238 is about 4.5 billion years, uranium-235 about 700 million years, and uranium-234 about 25 thousand years. Uranium atoms decay into other atoms, or radionuclides, that are also radioactive and commonly called "decay products." Uranium and its decay products primarily emit alpha radiation, however, lower levels of both beta and gamma radiation are also emitted. The total activity level of uranium depends on the isotopic composition and processing history. A sample of natural uranium (as mined) is composed of 99.3% uranium-238, 0.7% uranium-235, and a negligible amount of uranium-234 (by weight), as well as a number of radioactive decay products.

353

Development of Integrated Online Monitoring Systems for Detection of Diversion at Natural Uranium Conversion Facilities  

SciTech Connect

Recent work at Oak Ridge National Laboratory (ORNL) has focused on some source term modeling of uranyl nitrate (UN) as part of a comprehensive validation effort employing gamma-ray detector instrumentation for the detection of diversion from declared conversion activities. Conversion, the process by which natural uranium ore (yellowcake) is purified and converted through a series of chemical processes into uranium hexafluoride gas (UF6), has historically been excluded from the nuclear safeguards requirements of the 235U-based nuclear fuel cycle. The undeclared diversion of this product material could potentially provide feedstock for a clandestine weapons program for state or non-state entities. Given the changing global political environment and the increased availability of dual-use nuclear technology, the International Atomic Energy Agency has evolved its policies to emphasize safeguarding this potential feedstock material in response to dynamic and evolving potential diversion pathways. To meet the demand for instrumentation testing at conversion facilities, ORNL developed the Uranyl Nitrate Calibration Loop Equipment (UNCLE) facility to simulate the full-scale operating conditions of a purified uranium-bearing aqueous stream exiting the solvent extraction process in a natural uranium conversion plant. This work investigates gamma-ray signatures of UN circulating in the UNCLE facility and evaluates detector instrumentation sensitivity to UN for safeguards applications. These detector validation activities include assessing detector responses to the UN gamma-ray signatures for spectrometers based on sodium iodide, lanthanum bromide, and germanium detectors. The results of measurements under static and dynamic operating conditions at concentrations ranging from 10-90g U/L of naturally enriched UN will be presented. A range of gamma-ray lines was examined and self-attenuation factors were calculated, in addition to attenuation for transmission measurement of density, concentration and enrichment. A detailed uncertainty analysis will be presented providing insights into instrumentation limitations to spoofing.

Dewji, Shaheen A [ORNL; Lee, Denise L [ORNL; Croft, Stephen [ORNL; McElroy, Robert Dennis [ORNL; Hertel, Nolan [Georgia Institute of Technology; Chapman, Jeffrey Allen [ORNL; Cleveland, Steven L [ORNL

2013-01-01T23:59:59.000Z

354

FAQ 6-What is depleted uranium?  

NLE Websites -- All DOE Office Websites (Extended Search)

depleted uranium? What is depleted uranium? Depleted uranium is created during the processing that is done to make natural uranium suitable for use as fuel in nuclear power plants...

355

Tag: uranium | Y-12 National Security Complex  

NLE Websites -- All DOE Office Websites (Extended Search)

uranium Tag: uranium Displaying 1 - 10 of 23... Category: News The Nation's Expert in All Things Uranium Y-12 serves the nation and the world as a center of excellence for uranium...

356

The Nature of Vibrational Softening in ? - Uranium  

Science Conference Proceedings (OSTI)

... The Nature of Vibrational Softening in ? - Uranium. The standard textbook ... B / atom. All experiments used uranium powder. High ...

357

Education: Digital Resource Center - WEB: Uranium Information ...  

Science Conference Proceedings (OSTI)

Sep 24, 2007 ... Uranium, Electricity and the Greenhouse Effect ... Educational Resource Papers," Australian Uranium Association Ltd. Site updated weekly.

358

Energy Levels of Neutral Uranium ( U I )  

Science Conference Proceedings (OSTI)

... Data, Uranium (U) Homepage - Introduction Finding list Select element by name. ... Version Energy Levels of Neutral Uranium ( U I ). ...

359

Domestic Uranium Production Report 2004 -2011  

U.S. Energy Information Administration (EIA)

Nuclear & Uranium. Uranium fuel, nuclear reactors, generation, spent fuel. Total Energy. Comprehensive data summaries, comparisons, analysis, and projections ...

360

Domestic Uranium Production Report - Energy Information Administration  

U.S. Energy Information Administration (EIA)

Nuclear & Uranium. Uranium fuel, nuclear reactors, generation, ... with currently proven mining and processing technology and under current law and regulations.

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

The Time-dependent Collapse of a Rotating Fluid Cylinder  

Science Conference Proceedings (OSTI)

The behavior of a reduced-gravity cylinder of fluid, released from rest in a rotating system, is considered. The eventual steady state, found by normal principles of conservation of angular momentum, mass, and potential vorticity, is shown to ...

Peter D. Killworth

1992-04-01T23:59:59.000Z

362

By-products from DU Storage (Fluorine and Empty Cylinders)  

NLE Websites -- All DOE Office Websites (Extended Search)

By-products from DU Storage By-products from DU Storage (Fluorine and Empty Cylinders) Potential applications involving by-products from DUF6 storage include fluorine applications...

363

Axial Compression of a Hollow Cylinder Filled with a Foam  

Science Conference Proceedings (OSTI)

Presentation Title, Axial Compression of a Hollow Cylinder Filled with a Foam: A Porcupine ... Characterization of (Ti,Mg)N Thin Film Coatings Produced Via Physical Vapor Deposition ... Non-Toxic SPD Processed Ti Alloys for Orthopaedics.

364

Method of making superconducting cylinders for flux detectors  

DOE Patents (OSTI)

A method of making superconducting cylinders of the ''weak link'' type is provided. The method allows the weak link to be made much smaller than was heretofore possible, thereby greatly increasing sensitivity and operating temperature range when the cylinder is used in a flux detector. The resistance of the weak link is monitored continuously as metal is removed from the link by electrochemical action.

Goodkind, J.M.; Stolfa, D.L.

1971-07-06T23:59:59.000Z

365

Process for electrolytically preparing uranium metal  

DOE Patents (OSTI)

A process for making uranium metal from uranium oxide by first fluorinating uranium oxide to form uranium tetrafluoride and next electrolytically reducing the uranium tetrafluoride with a carbon anode to form uranium metal and CF.sub.4. The CF.sub.4 is reused in the fluorination reaction rather than being disposed of as a hazardous waste.

Haas, Paul A. (Knoxville, TN)

1989-01-01T23:59:59.000Z

366

Inspection of compressed natural gas cylinders on school buses  

DOE Green Energy (OSTI)

The US Department of Energy (DOE) is sponsoring compressed natural gas (CNF)-powered school bus demonstrations in various locations around the country. Early in 1994, two non-DOE-sponsored CNG pickup trucks equipped with composite-reinforced-aluminum fuel cylinders experienced cylinder ruptures during refueling. As reported by the Gas Research Institute (GRI): ...analysis of the cylinder ruptures on the pickup trucks revealed that they were due to acid-induced stress corrosion cracking (SCC) of the overwrap. The overwrap that GRI refers to is a resin-impregnated fiber that is wrapped around the outside of the gas cylinder for added strength. Because ensuring the safety of the CNG vehicles it sponsors is of paramount concern to DOE, the Department, through the National Renewable Energy Laboratory (NREL), conducted inspections of DOE-sponsored vehicles nationwide. The work had three objectives: inspection, documentation, and education. First, inspectors visited sites where CNG-powered school buses sponsored by DOE are based, and inspected the CNG cylinders for damage. Second, information learned during the inspections was collected for DOE. Third, the inspections found that the education and awareness of site personnel, in terms of cylinder damage detection, needed to be increased.

NONE

1995-07-01T23:59:59.000Z

367

Uranium-titanium-niobium alloy  

DOE Patents (OSTI)

A uranium alloy having small additions of Ti and Nb shows improved strength and ductility in cross section of greater than one inch over prior uranium alloy having only Ti as an alloying element.

Ludtka, Gail M. (Oak Ridge, TN); Ludtka, Gerard M. (Oak Ridge, TN)

1990-01-01T23:59:59.000Z

368

METHOD OF SINTERING URANIUM DIOXIDE  

DOE Green Energy (OSTI)

This patent relates to a method of sintering uranium dioxide. Uranium dioxide bodies are heated to above 1200 nif- C in hydrogen, sintered in steam, and then cooled in hydrogen. (AEC)

Henderson, C.M.; Stavrolakis, J.A.

1963-04-30T23:59:59.000Z

369

It's Elemental - The Element Uranium  

NLE Websites -- All DOE Office Websites (Extended Search)

into uranium-233, also through beta decay. If completely fissioned, one pound (0.45 kilograms) of uranium-233 will provide the same amount of energy as burning 1,500 tons...

370

Uranium resources: Issues and facts  

SciTech Connect

Although there are several secondary issues, the most important uranium resource issue is, ``will there be enough uranium available at a cost which will allow nuclear power to be competitive in the future?`` This paper will attempt to answer this question by discussing uranium supply, demand, and economics from the perspective of the United States. The paper will discuss: how much uranium is available; the sensitivity of nuclear power costs to uranium price; the potential future demand for uranium in the Unites States, some of the options available to reduce this demand, the potential role of the Advanced Liquid Metal Cooled Reactor (ALMR) in reducing uranium demand; and potential alternative uranium sources and technologies.

Delene, J.G.

1993-12-31T23:59:59.000Z

371

METHOD OF RECOVERING URANIUM COMPOUNDS  

DOE Patents (OSTI)

S>The recovery of uranium compounds which have been adsorbed on anion exchange resins is discussed. The uranium and thorium-containing residues from monazite processed by alkali hydroxide are separated from solution, and leached with an alkali metal carbonate solution, whereby the uranium and thorium hydrorides are dissolved. The carbonate solution is then passed over an anion exchange resin causing the uranium to be adsorbed while the thorium remains in solution. The uranium may be recovered by contacting the uranium-holding resin with an aqueous ammonium carbonate solution whereby the uranium values are eluted from the resin and then heating the eluate whereby carbon dioxide and ammonia are given off, the pH value of the solution is lowered, and the uranium is precipitated.

Poirier, R.H.

1957-10-29T23:59:59.000Z

372

Results of ultrasonic testing evaluations on UF{sub 6} storage cylinders  

Science Conference Proceedings (OSTI)

The three site cylinder management program is responsible for the safe storage of the DOE owned UF{sub 6} storage cylinders at PORTS, PGDP and at the K-25 site. To ensure the safe storage of the UF{sub 6} in the cylinders, the structural integrity of the cylinders must be evaluated. This report represents the latest cylinder integrity investigation that utilized wall thickness evaluations to identify thinning due to atmospheric exposure.

Lykins, M.L.

1997-02-01T23:59:59.000Z

373

Environmental assessment for the purchase of Russian low enriched uranium derived from the dismantlement of nuclear weapons in the countries of the former Soviet Union  

SciTech Connect

The United States is proposing to purchase from the Russian Federation low enriched uranium (LEU) derived from highly enriched uranium (HEU) resulting from the dismantlement of nuclear weapons in the countries of the former Soviet Union. The purchase would be accomplished through a proposed contract requiring the United States to purchase 15,250 metric tons (tonnes) of LEU (or 22,550 tonnes of UF{sub 6}) derived from blending 500 metric tones uranium (MTU) of HEU from nuclear warheads. The LEU would be in the form of uranium hexafluoride (UF{sub 6}) and would be converted from HEU in Russia. The United States Enrichment Corporation (USEC) is the entity proposing to undertake the contract for purchase, sale, and delivery of the LEU from the Russian Federation. The US Department of Energy (DOE) is negotiating the procedure for gaining confidence that the LEU is derived from HEU that is derived from dismantled nuclear weapons (referred to as ``transparency),`` and would administer the transparency measures for the contract. There are six environments that could potentially be affected by the proposed action; marine (ocean); US ports of entry; truck or rail transportation corridors; the Portsmouth GDP; the electric power industry; and the nuclear fuel cycle industry. These environmental impacts are discussed.

Not Available

1994-01-01T23:59:59.000Z

374

EXTRACTION OF URANIUM  

DOE Patents (OSTI)

An improved process is presented for recovering uranium from a carnotite ore. In the improved process U/sub 2/O/sub 5/ is added to the comminuted ore along with the usual amount of NaCl prior to roasting. The amount of U/sub 2/O/ sub 5/ is dependent on the amount of free calcium oxide and the uranium in the ore. Specifically, the desirable amount of U/sub 2/O/sub 5/ is 3.2% for each 1% of CaO, and 5 to 6% for each 1% of uranium. The mixture is roasted at about 1560 deg C for about 30 min and then leached with a 3 to 9% aqueous solution of sodium carbonate.

Kesler, R.D.; Rabb, D.D.

1959-07-28T23:59:59.000Z

375

Uranium immobilization and nuclear waste  

SciTech Connect

Considerable information useful in nuclear waste storage can be gained by studying the conditions of uranium ore deposit formation. Further information can be gained by comparing the chemistry of uranium to nuclear fission products and other radionuclides of concern to nuclear waste disposal. Redox state appears to be the most important variable in controlling uranium solubility, especially at near neutral pH, which is characteristic of most ground water. This is probably also true of neptunium, plutonium, and technetium. Further, redox conditions that immobilize uranium should immobilize these elements. The mechanisms that have produced uranium ore bodies in the Earth's crust are somewhat less clear. At the temperatures of hydrothermal uranium deposits, equilibrium models are probably adequate, aqueous uranium (VI) being reduced and precipitated by interaction with ferrous-iron-bearing oxides and silicates. In lower temperature roll-type uranium deposits, overall equilibrium may not have been achieved. The involvement of sulfate-reducing bacteria in ore-body formation has been postulated, but is uncertain. Reduced sulfur species do, however, appear to be involved in much of the low temperature uranium precipitation. Assessment of the possibility of uranium transport in natural ground water is complicated because the system is generally not in overall equilibrium. For this reason, Eh measurements are of limited value. If a ground water is to be capable of reducing uranium, it must contain ions capable of reducing uranium both thermodynamically and kinetically. At present, the best candidates are reduced sulfur species.

Duffy, C.J.; Ogard, A.E.

1982-02-01T23:59:59.000Z

376

PROCESS OF PREPARING URANIUM CARBIDE  

DOE Patents (OSTI)

A process of preparing uranium monocarbide is de scribed. Uranium metal is dissolved in cadmium, zinc, cadmium-- zinc, or magnesium-- zinc alloy and a small quantity of alkali metal is added. Addition of stoichiometric amounts of carbon at 500 to 820 deg C then precipitates uranium monocarbide. (AEC)

Miller, W.E.; Stethers, H.L.; Johnson, T.R.

1964-03-24T23:59:59.000Z

377

In-Cylinder Fuel Blending of Gasoline/Diesel for Improved Efficiency and Lowest Possible Emissions on a Multi-Cylinder Light-Duty Diesel Engine  

DOE Green Energy (OSTI)

In-cylinder fuel blending of gasoline/diesel fuel is investigated on a multi-cylinder light-duty diesel engine as a potential strategy to control in-cylinder fuel reactivity for improved efficiency and lowest possible emissions. This approach was developed and demonstrated at the University of Wisconsin through modeling and single-cylinder engine experiments. The objective of this study is to better understand the potential and challenges of this method on a multi-cylinder engine. More specifically, the effect of cylinder-to-cylinder imbalances, heat rejection, and in-cylinder charge motion as well as the potential limitations imposed by real-world turbo-machinery were investigated on a 1.9-liter four-cylinder engine. This investigation focused on one engine condition, 2300 rpm, 4.2 bar brake mean effective pressure (BMEP). Gasoline was introduced with a port-fuel-injection system. Parameter sweeps included gasoline-to-diesel fuel ratio, intake air mixture temperature, in-cylinder swirl number, and diesel start-of-injection phasing. In addition, engine parameters were trimmed for each cylinder to balance the combustion process for maximum efficiency and lowest emissions. An important observation was the strong influence of intake charge temperature on cylinder pressure rise rate. Experiments were able to show increased thermal efficiency along with dramatic decreases in oxides of nitrogen (NOX) and particulate matter (PM). However, indicated thermal efficiency for the multi-cylinder experiments were less than expected based on modeling and single-cylinder results. The lower indicated thermal efficiency is believed to be due increased heat transfer as compared to the model predictions and suggest a need for improved cylinder-to-cylinder control and increased heat transfer control.

Curran, Scott [ORNL; Prikhodko, Vitaly Y [ORNL; Wagner, Robert M [ORNL; Parks, II, James E [ORNL; Cho, Kukwon [ORNL; Sluder, Scott [ORNL; Kokjohn, Sage [University of Wisconsin, Madison; Reitz, Rolf [University of Wisconsin

2010-01-01T23:59:59.000Z

378

TREATMENT OF URANIUM SURFACES  

DOE Patents (OSTI)

An improved process is presented for prcparation of uranium surfaces prior to electroplating. The surfacc of the uranium to be electroplated is anodized in a bath comprising a solution of approximately 20 to 602 by weight of phosphoric acid which contains about 20 cc per liter of concentrated hydrochloric acid. Anodization is carried out for approximately 20 minutes at a current density of about 0.5 amperes per square inch at a temperature of about 35 to 45 C. The oxidic film produced by anodization is removed by dipping in strong nitric acid, followed by rinsing with water just prior to electroplating.

Slunder, C.J.

1959-02-01T23:59:59.000Z

379

PROCESS OF RECOVERING URANIUM  

DOE Patents (OSTI)

An improved precipitation method is described for the recovery of uranium from aqueous solutions. After removal of all but small amounts of Ni or Cu, and after complexing any iron present, the uranium is separated as the peroxide by adding H/sub 2/O/sub 2/. The improvement lies in the fact that the addition of H/sub 2/O/sub 2/ and consequent precipitation are carried out at a temperature below the freezing; point of the solution, so that minute crystals of solvent are present as seed crystals for the precipitation.

Price, T.D.; Jeung, N.M.

1958-06-17T23:59:59.000Z

380

Production and Handling Slide 21: Melting Points of Uranium and...  

NLE Websites -- All DOE Office Websites (Extended Search)

Points of Uranium and Uranium Compounds Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Melting Points of Uranium and Uranium...

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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381

FAQ 26-Are there any uses for depleted uranium?  

NLE Websites -- All DOE Office Websites (Extended Search)

uses for depleted uranium? Are there any uses for depleted uranium? Several current and potential uses exist for depleted uranium. Depleted uranium could be mixed with highly...

382

High loading uranium fuel plate  

DOE Patents (OSTI)

Two embodiments of a high uranium fuel plate are disclosed which contain a meat comprising structured uranium compound confined between a pair of diffusion bonded ductile metal cladding plates uniformly covering the meat, the meat having a uniform high fuel loading comprising a content of uranium compound greater than about 45 Vol. % at a porosity not greater than about 10 Vol. %. In a first embodiment, the meat is a plurality of parallel wires of uranium compound. In a second embodiment, the meat is a dispersion compact containing uranium compound. The fuel plates are fabricated by a hot isostatic pressing process.

Wiencek, Thomas C. (Bolingbrook, IL); Domagala, Robert F. (Indian Head Park, IL); Thresh, Henry R. (Palos Heights, IL)

1990-01-01T23:59:59.000Z

383

STRIPPING OF URANIUM FROM ORGANIC EXTRACTANTS  

DOE Patents (OSTI)

A liquid-liquid extraction method is given for recovering uranium values from uranium-containing solutions. Uranium is removed from a uranium-containing organic solution by contacting said organic solution with an aqueous ammonium carbonate solution substantially saturated in uranium values. A uranium- containing precipitate is thereby formed which is separated from the organic and aqueous phases. Uranium values are recovered from this separated precipitate. (AE C)

Crouse, D.J. Jr.

1962-09-01T23:59:59.000Z

384

Electromagnetic Casimir Forces of Parabolic Cylinder and Knife-Edge Geometries  

E-Print Network (OSTI)

An exact calculation of electromagnetic scattering from a perfectly conducting parabolic cylinder is employed to compute Casimir forces in several configurations. These include interactions between a parabolic cylinder and a plane, two parabolic cylinders, and a parabolic cylinder and an ordinary cylinder. To elucidate the effect of boundaries, special attention is focused on the "knife-edge" limit in which the parabolic cylinder becomes a half-plane. Geometrical effects are illustrated by considering arbitrary rotations of a parabolic cylinder around its focal axis, and arbitrary translations perpendicular to this axis. A quite different geometrical arrangement is explored for the case of an ordinary cylinder placed in the interior of a parabolic cylinder. All of these results extend simply to nonzero temperatures.

Noah Graham; Alexander Shpunt; Thorsten Emig; Sahand Jamal Rahi; Robert L. Jaffe; Mehran Kardar

2011-03-30T23:59:59.000Z

385

Electromagnetic Casimir forces of parabolic cylinder and knife-edge geometries  

SciTech Connect

An exact calculation of electromagnetic scattering from a perfectly conducting parabolic cylinder is employed to compute Casimir forces in several configurations. These include interactions between a parabolic cylinder and a plane, two parabolic cylinders, and a parabolic cylinder and an ordinary cylinder. To elucidate the effect of boundaries, special attention is focused on the 'knife-edge' limit in which the parabolic cylinder becomes a half-plane. Geometrical effects are illustrated by considering arbitrary rotations of a parabolic cylinder around its focal axis, and arbitrary translations perpendicular to this axis. A quite different geometrical arrangement is explored for the case of an ordinary cylinder placed in the interior of a parabolic cylinder. All of these results extend simply to nonzero temperatures.

Graham, Noah [Department of Physics, Middlebury College, Middlebury, Vermont 05753 (United States); Shpunt, Alexander; Kardar, Mehran [Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Emig, Thorsten [Laboratoire de Physique Theorique et Modeles Statistiques, CNRS UMR 8626, Bat. 100, Universite Paris-Sud, 91405 Orsay cedex (France); Rahi, Sahand Jamal [Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Center for Studies in Physics and Biology, The Rockefeller University, 1230 York Street, New York, New York 10065 (United States); Jaffe, Robert L. [Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Center for Theoretical Physics and Laboratory for Nuclear Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2011-06-15T23:59:59.000Z

386

Depleted Uranium Technical Brief  

E-Print Network (OSTI)

. This Technical Brief specifically addresses DU in an environmental contamination setting and specifically does.S. Department of Energy (DOE) and other govern ment sources. DU occurs in a number of different compounds airborne releases of uranium at one DOE facility amounted to 310,000 kg between 1951 and 1988, which

387

URANIUM RECOVERY PROCESS  

DOE Patents (OSTI)

The recovery of uranium from the acidic aqueous metal waste solutions resulting from the bismuth phosphate carrier precipitation of plutonium from solutions of neutron irradiated uranium is described. The waste solutions consist of phosphoric acid, sulfuric acid, and uranium as a uranyl salt, together with salts of the fission products normally associated with neutron irradiated uranium. Generally, the process of the invention involves the partial neutralization of the waste solution with sodium hydroxide, followed by conversion of the solution to a pH 11 by mixing therewith sufficient sodium carbonate. The resultant carbonate-complexed waste is contacted with a titanated silica gel and the adsorbent separated from the aqueous medium. The aqueous solution is then mixed with sufficient acetic acid to bring the pH of the aqueous medium to between 4 and 5, whereby sodium uranyl acetate is precipitated. The precipitate is dissolved in nitric acid and the resulting solution preferably provided with salting out agents. Uranyl nitrate is recovered from the solution by extraction with an ether such as diethyl ether.

Hyman, H.H.; Dreher, J.L.

1959-07-01T23:59:59.000Z

388

A PROCESS FOR THE RECOVERY OF URANIUM FROM NUCLEAR FUEL ELEMENTS USING FLUID-BED DRYING AND VOLATILITY TECHNIQUES  

SciTech Connect

A process scheme for the recovery of uranium from fuel elements has been developed. The scheme combines continuous fluid-bed drying and fluoride volatility techniques after initial dissolution of the fuel element in the appropriate aqueous system, hence the designation ADF, Aqueous Dry Fluorination Process. The application of this process to the recovery of uranium from highly enriched, low uranium-zirconium alloy plate-type fuels is described. ln the process, the feed solution is sprayed horizontally through a two-fluid nozzle and is atomized directly in the heated fluidized bed. The spray droplets are dried on the fluidized particles and form a dense coating. Excessive particle growth was limited by the use of air attrition-jets inserted directly in the bed. Aqueous hydrofluoric acid solutions containing l.2 to 3.6 M zirconiuni, 0.007 to 0.03 M uranium, and free acid concentrations from 1 to about l0 M were successfully processed in a 6-in.-diameter Inconel fluid-bed spray dryer. Rates equivalent to about 3.l kg/hr of zirconium were achieved, 160 ml/min with the most concentrated feed solution. Experiments were successfully carried out from 240 to 450 deg C. A new design for a two-fluid nozzle was developed. Extensive work was done to identify the various zirconium fluoride compounds formed. The granular dryer product was subsequently fluorinated at temperatures to 600 deg C in fluid beds and to 700 deg C in static beds to remove the uranium as the volatile hexafluoride. About 90 to 95% uranium removal was consistently achieved near 600 deg C. The relatively low uranium recovery under these conditions is a disadvantage for the application to zirconium-base fuels. It was found necessary to resort to static beds and higher temperatures to achieve greater removal. Since the fluorine attack on nickel, the material of construction, is prohibitive at temperatures above 600 deg C, a disposable fluorinator concept for use with static beds is described. Results of corrosion studies are reported. A preliminary chemical flowsheet with a design capacity of 1l00 kg of uranium (93% enriched) annually is presented. (auth)

Levitz, N.; Barghusen, J.; Carls, E.; Jonke, A.A.

1961-11-01T23:59:59.000Z

389

Nuclear Fuel Facts: Uranium | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Uranium Management and Uranium Management and Policy » Nuclear Fuel Facts: Uranium Nuclear Fuel Facts: Uranium Nuclear Fuel Facts: Uranium Uranium is a silvery-white metallic chemical element in the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium has the highest atomic weight (19 kg m) of all naturally occurring elements. Uranium occurs naturally in low concentrations in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite. Uranium ore can be mined from open pits or underground excavations. The ore can then be crushed and treated at a mill to separate the valuable uranium from the ore. Uranium may also be dissolved directly from the ore deposits

390

PRODUCTION OF URANIUM METAL BY CARBON REDUCTION  

DOE Patents (OSTI)

The preparation of uranium metal by the carbon reduction of an oxide of uranium is described. In a preferred embodiment of the invention a charge composed of carbon and uranium oxide is heated to a solid mass after which it is further heated under vacuum to a temperature of about 2000 deg C to produce a fused uranium metal. Slowly ccoling the fused mass produces a dendritic structure of uranium carbide in uranium metal. Reacting the solidified charge with deionized water hydrolyzes the uranium carbide to finely divide uranium dioxide which can be separated from the coarser uranium metal by ordinary filtration methods.

Holden, R.B.; Powers, R.M.; Blaber, O.J.

1959-09-22T23:59:59.000Z

391

Remediation and Recovery of Uranium from Contaminated  

E-Print Network (OSTI)

uranium containing the mixture of isotopes occurring in nature; uranium depleted in the isotope 235; Depleted uranium 1000 kilograms; and Thorium 1000 kilograms. #12;INFCIRC/254/Rev.9/Part.1 November 2007 Annex B, section 4.); 2.5. Plants for the separation of isotopes of natural uranium, depleted uranium

Lovley, Derek

392

Method of preparation of uranium nitride  

SciTech Connect

Method for producing terminal uranium nitride complexes comprising providing a suitable starting material comprising uranium; oxidizing the starting material with a suitable oxidant to produce one or more uranium(IV)-azide complexes; and, sufficiently irradiating the uranium(IV)-azide complexes to produce the terminal uranium nitride complexes.

Kiplinger, Jaqueline Loetsch; Thomson, Robert Kenneth James

2013-07-09T23:59:59.000Z

393

Transportation  

NLE Websites -- All DOE Office Websites (Extended Search)

Health Risks » Transportation Health Risks » Transportation DUF6 Health Risks line line Accidents Storage Conversion Manufacturing Disposal Transportation Transportation A discussion of health risks associated with transport of depleted UF6. Transport Regulations and Requirements In the future, it is likely that depleted uranium hexafluoride cylinders will be transported to a conversion facility. For example, it is currently anticipated that the cylinders at the ETTP Site in Oak Ridge, TN, will be transported to the Portsmouth Site, OH, for conversion. Uranium hexafluoride has been shipped safely in the United States for over 40 years by both truck and rail. Shipments of depleted UF6 would be made in accordance with all applicable transportation regulations. Shipment of depleted UF6 is regulated by the

394

Method of preparing uranium nitride or uranium carbonitride bodies  

DOE Patents (OSTI)

Sintered uranium nitride or uranium carbonitride bodies having a controlled final carbon-to-uranium ratio are prepared, in an essentially continuous process, from U.sub.3 O.sub.8 and carbon by varying the weight ratio of carbon to U.sub.3 O.sub.8 in the feed mixture, which is compressed into a green body and sintered in a continuous heating process under various controlled atmospheric conditions to prepare the sintered bodies.

Wilhelm, Harley A. (Ames, IA); McClusky, James K. (Valparaiso, IN)

1976-04-27T23:59:59.000Z

395

Method for fabricating uranium foils and uranium alloy foils  

DOE Patents (OSTI)

A method of producing thin foils of uranium or an alloy. The uranium or alloy is cast as a plate or sheet having a thickness less than about 5 mm and thereafter cold rolled in one or more passes at substantially ambient temperatures until the uranium or alloy thereof is in the shape of a foil having a thickness less than about 1.0 mm. The uranium alloy includes one or more of Zr, Nb, Mo, Cr, Fe, Si, Ni, Cu or Al.

Hofman, Gerard L. (Downers Grove, IL); Meyer, Mitchell K. (Idaho Falls, ID); Knighton, Gaven C. (Moore, ID); Clark, Curtis R. (Idaho Falls, ID)

2006-09-05T23:59:59.000Z

396

METHOD OF PRODUCING URANIUM  

DOE Patents (OSTI)

A modified process is described for the production of uranium metal by means of a bomb reduction of UF/sub 4/. Difficulty is sometimes experienced in obtaining complete separation of the uranium from the slag when the process is carried out on a snnall scale, i.e., for the production of 10 grams of U or less. Complete separation may be obtained by incorporating in the reaction mixture a quantity of MnCl/sub 2/, so that this compound is reduced along with the UF/sub 4/ . As a result a U--Mn alloy is formed which has a melting point lower than that of pure U, and consequently the metal remains molten for a longer period allowing more complete separation from the slag.

Foster, L.S.; Magel, T.T.

1958-05-13T23:59:59.000Z

397

ELECTROLYSIS OF THORIUM AND URANIUM  

DOE Patents (OSTI)

An electrolytic method is given for obtaining pure thorium, uranium, and thorium-uranium alloys. The electrolytic cell comprises a cathode composed of a metal selected from the class consisting of zinc, cadmium, tin, lead, antimony, and bismuth, an anode composed of at least one of the metals selected from the group consisting of thorium and uranium in an impure state, and an electrolyte composed of a fused salt containing at least one of the salts of the metals selected from the class consisting of thorium, uranium. zinc, cadmium, tin, lead, antimony, and bismuth. Electrolysis of the fused salt while the cathode is maintained in the molten condition deposits thorium, uranium, or thorium-uranium alloys in pure form in the molten cathode which thereafter may be separated from the molten cathode product by distillation.

Hansen, W.N.

1960-09-01T23:59:59.000Z

398

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

9. Summary production statistics of the U.S. uranium industry, 1993-2012 9. Summary production statistics of the U.S. uranium industry, 1993-2012 Item 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 E2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 Exploration and Development Surface Drilling (million feet) 1.1 0.7 1.3 3.0 4.9 4.6 2.5 1.0 0.7 W W 1.2 1.7 2.7 5.1 5.1 3.7 4.9 6.3 7.2 Drilling Expenditures (million dollars)1 5.7 1.1 2.6 7.2 20.0 18.1 7.9 5.6 2.7 W W 10.6 18.1 40.1 67.5 81.9 35.4 44.6 53.6 66.6 Mine Production of Uranium (million pounds U3O8) 2.1 2.5 3.5 4.7 4.7 4.8 4.5 3.1 2.6 2.4 2.2 2.5 3.0 4.7 4.5 3.9 4.1 4.2 4.1 4.3 Uranium Concentrate Production (million pounds U3O8) 3.1 3.4 6.0 6.3 5.6 4.7 4.6 4.0 2.6 2.3 2.0 2.3 2.7 4.1 4.5 3.9 3.7 4.2 4.0 4.1

399

WELDED JACKETED URANIUM BODY  

DOE Patents (OSTI)

A fuel element is presented for a neutronic reactor and is comprised of a uranium body, a non-fissionable jacket surrounding sald body, thu jacket including a portion sealed by a weld, and an inclusion in said sealed jacket at said weld of a fiux having a low neutron capture cross-section. The flux is provided by combining chlorine gas and hydrogen in the intense heat of-the arc, in a "Heliarc" welding muthod, to form dry hydrochloric acid gas.

Gurinsky, D.H.

1958-08-26T23:59:59.000Z

400

Operation of a Four-Cylinder 1.9L Propane Fueled Homogeneous Charge Compression Ignition Engine: Basic Operating Characteristics and Cylinder-to-Cylinder Effects  

DOE Green Energy (OSTI)

A four-cylinder 1.9 Volkswagen TDI Engine has been converted to run in Homogeneous Charge Compression Ignition (HCCI) mode. The stock configuration is a turbocharged direct injection Diesel engine. The combustion chamber has been modified by discarding the in-cylinder Diesel fuel injectors and replacing them with blank inserts (which contain pressure transducers). The stock pistons contain a reentrant bowl and have been retained for the tests reported here. The intake and exhaust manifolds have also been retained, but the turbocharger has been removed. A heater has been installed upstream of the intake manifold and fuel is added just downstream of this heater. The performance of this engine in naturally aspirated HCCI operation, subject to variable intake temperature and fuel flow rate, has been studied. The engine has been run with propane fuel at a constant speed of 1800 rpm. This work is intended to characterize the HCCI operation of the engine in this configuration that has been minimally modified from the base Diesel engine. The performance (BMEP, IMEP, efficiency, etc) and emissions (THC, CO, NOx) of the engine are presented, as are combustion process results based on heat release analysis of the pressure traces from each cylinder.

Flowers, D; Aceves, S M; Martinez-Frias, J; Smith, J R; Au, M; Girard, J; Dibble, R

2001-03-12T23:59:59.000Z

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

8. U.S. uranium expenditures, 2003-2012 8. U.S. uranium expenditures, 2003-2012 million dollars Year Drilling Production Land and Other Total Expenditures Total Land and Other Land Exploration Reclamation 2003 W W 31.3 NA NA NA W 2004 10.6 27.8 48.4 NA NA NA 86.9 2005 18.1 58.2 59.7 NA NA NA 136.0 2006 40.1 65.9 115.2 41.0 23.3 50.9 221.2 2007 67.5 90.4 178.2 77.7 50.3 50.2 336.2 2008 81.9 221.2 164.4 65.2 50.2 49.1 467.6 2009 35.4 141.0 104.0 17.3 24.2 62.4 280.5 2010 44.6 133.3 99.5 20.2 34.5 44.7 277.3 2011 53.6 168.8 96.8 19.6 43.5 33.7 319.2 2012 66.6 186.9 99.4 16.8 33.3 49.3 352.9 Drilling: All expenditures directly associated with exploration and development drilling. Production: All expenditures for mining, milling, processing of uranium, and facility expense.

402

Electromagnetic Casimir forces of parabolic cylinder and knife-edge geometries  

E-Print Network (OSTI)

An exact calculation of electromagnetic scattering from a perfectly conducting parabolic cylinder is employed to compute Casimir forces in several configurations. These include interactions between a parabolic cylinder and ...

Graham, Noah

403

METHOD OF JACKETING URANIUM BODIES  

DOE Patents (OSTI)

An improved process is presented for providing uranium slugs with thin walled aluminum jackets. Since aluminum has a slightiy higher coefficient of thermal expansion than does uraaium, both uranium slugs and aluminum cans are heated to an elevated temperature of about 180 C, and the slug are inserted in the cans at that temperature. During the subsequent cooling of the assembly, the aluminum contracts more than does the uranium and a tight shrink fit is thus assured.

Maloney, J.O.; Haines, E.B.; Tepe, J.B.

1958-08-26T23:59:59.000Z

404

PROCESS FOR PREPARING URANIUM METAL  

DOE Patents (OSTI)

A process is presented for producing oxygen-free uranium metal comprising contacting iodine vapor with crude uranium in a reaction zone maintained at 400 to 800 C to produce a vaporous mixture of UI/sub 4/ and iodine. Also disposed within the maction zone is a tungsten filament which is heated to about 1600 C. The UI/sub 4/, upon contacting the hot filament, is decomposed to molten uranium substantially free of oxygen.

Prescott, C.H. Jr.; Reynolds, F.L.

1959-01-13T23:59:59.000Z

405

FAQ 2-Where does uranium come from?  

NLE Websites -- All DOE Office Websites (Extended Search)

come from? Where does uranium come from? Small amounts of uranium are found almost everywhere in soil, rock, and water. However, concentrated deposits of uranium ores are found in...

406

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network (OSTI)

IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE Kee Chul Kim Ph.D.727-366; Figure 1. Oxygen-uranium phase-equilibrium _ystem [18]. uranium dioxide powders and 18 0 enriched carbon

Kim, Kee Chul

2010-01-01T23:59:59.000Z

407

Reoxidation of Bioreduced Uranium Under Reducing Conditions  

E-Print Network (OSTI)

Microbial reduction of uranium. Nature 350, 413-416 (1991).C. Enzymatic iron and uranium reduction by sulfate-reducingS. Reduction of hexavalent uranium from organic complexes by

2005-01-01T23:59:59.000Z

408

PROCESS FOR REMOVING NOBLE METALS FROM URANIUM  

DOE Patents (OSTI)

A pyrometallurgical method is given for purifying uranium containing ruthenium and palladium. The uranium is disintegrated and oxidized by exposure to air and then the ruthenium and palladium are extracted from the uranium with molten zinc.

Knighton, J.B.

1961-01-31T23:59:59.000Z

409

IMPROVED PROCESSES FOR RECOVERING AND PURIFYING URANIUM  

DOE Patents (OSTI)

A process is described for reclaiming metallic uranium enriched with uranium-235 from the collector of a calutron upon which the enriched metallic uranium is Editor please delete 22166.

Price, T.D.; Henrickson, A.V.

1959-05-12T23:59:59.000Z

410

Y-12 and uranium history  

NLE Websites -- All DOE Office Websites (Extended Search)

German chemists, Otto Hahn and Fritz Strassman, successfully described a new term, nuclear fission, for their experiment that resulted in the first splitting of the uranium atom....

411

Highly Enriched Uranium Transparency Program  

NLE Websites -- All DOE Office Websites (Extended Search)

and Climate Research Center for Geospatial Analysis Program Highlights Index Highly Enriched Uranium Transparency Program EVS staff members helped to implement transparency and...

412

THERMAL DECOMPOSITION OF URANIUM COMPOUNDS  

DOE Patents (OSTI)

A method is presented of preparing uranium metal of high purity consisting contacting impure U metal with halogen vapor at between 450 and 550 C to form uranium halide vapor, contacting the uranium halide vapor in the presence of H/sub 2/ with a refractory surface at about 1400 C to thermally decompose the uranium halides and deposit molten U on the refractory surface and collecting the molten U dripping from the surface. The entire operation is carried on at a sub-atmospheric pressure of below 1 mm mercury.

Magel, T.T.; Brewer, L.

1959-02-10T23:59:59.000Z

413

SEPARATION OF THORIUM FROM URANIUM  

DOE Patents (OSTI)

A description is given for the separation of thorium from uranium by forming an aqueous acidic solution containing ionic species of thorium, uranyl uranium, and hydroxylamine, flowing the solution through a column containing the phenol-formaldehyde type cation exchange resin to selectively adsorb substantially all the thorium values and a portion of the uranium values, flowing a dilute solution of hydrochloric acid through the column to desorb the uranium values, and then flowing a dilute aqueous acidic solution containing an ion, such as bisulfate, which has a complexing effect upon thortum through the column to desorb substantially all of the thorium.

Bane, R.W.

1959-09-01T23:59:59.000Z

414

METHOD FOR RECOVERING URANIUM FROM OILS  

DOE Patents (OSTI)

A method is presented for recovering uranium from hydrocarbon oils, wherein the uranium is principally present as UF/sub 4/. According to the invention, substantially complete removal of the uranium from the hydrocarbon oil may be effected by intimately mixing one part of acetone to about 2 to 12 parts of the hydrocarbon oil containing uranium and separating the resulting cake of uranium from the resulting mixture. The uranium in the cake may be readily recovered by burning to the oxide.

Gooch, L.H.

1959-07-14T23:59:59.000Z

415

PREPARATION OF URANIUM(IV) NITRATE SOLUTIONS  

SciTech Connect

A procedure was developed for the preparation of uranium(IV) nitrate solutions in dilute nitric acid. Zinc metal was used as a reducing agent for uranium(VI) in dilute sulfuric acid. The uranium(IV) was precipitated as the hydrated oxide and dissolved in nitric acid. Uranium(IV) nitrate solutions were prepared at a maximum concentration of 100 g/l. The uranium(VI) content was less than 2% of the uranium(IV). (auth)

Ondrejcin, R.S.

1961-07-01T23:59:59.000Z

416

Production and Handling Slide 27: Feed Cylinder with Normal Assay...  

NLE Websites -- All DOE Office Websites (Extended Search)

Normal Assay (0.711%U) Arriving at Plant Refer to caption below for image description The enrichment process begins with "feed material," natural uranium that contains 0.711%...

417

Processing of mixed-waste compressed-gas cylinders on the Oak Ridge Reservation  

Science Conference Proceedings (OSTI)

To comply with restrictions on the storage of old compressed gas cylinders, the environmental management organization of Lockheed Martin Energy Systems must dispose of several thousand kilograms of compressed gases stored on the Oak Ridge Reservation (ORR) because the cylinders cannot be taken off-site for disposal in their current configuration. In the ORR Site Treatment Plan, a milestone is cited that requires repackaging and shipment off-site of 21 cylinders by September 30, 1997. A project was undertaken to first evaluate and then either recontainerize or neutralize these cylinders using a transportable compressed gas recontainerization skid (TCGRS), which was developed by Integrated Environmental Services of Atlanta. The transportable system can: (1) sample, analyze, and identify at the site the chemical and radiological content of each cylinder, even those with inoperable valves; (2) breach cylinders, when necessary, to release their contents into a containment chamber; and (3) either neutralize the gas or liquid contents within the containment chamber or transfer the gas or liquids to a new cylinder. The old cylinders and cylinder fragments were disposed of and the gases neutralized or transferred to new cylinders for transportation off-site for disposal. The entire operation to process the 21 cylinders took place in only 5 days once the system was approved for operation. The system performed as expected and can now be used to process the potentially thousands of more cylinders located across the US Department of Energy (DOE) complex that have not yet been declared surplus.

Morris, M.I.; Conley, T.B.; Osborne-Lee, I.W.

1998-01-01T23:59:59.000Z

418

Gas-lubricated seal for sealing between a piston and a cylinder wall  

DOE Patents (OSTI)

A piston-cylinder seal uses gas for a lubricant and has a runner supported on a gapless structure and placed in the space between the piston and the cylinder wall. The runner is deformed elastically under the influence of the operating pressures to follow and compensate for variations in the piston-cylinder fit and maintain a seal. 4 figs.

Hoult, D.P.

1985-09-10T23:59:59.000Z

419

PROCESS OF PRODUCING REFRACTORY URANIUM OXIDE ARTICLES  

DOE Patents (OSTI)

A method is presented for fabricating uranium oxide into a shaped refractory article by introducing a uranium halide fluxing reagent into the uranium oxide, and then mixing and compressing the materials into a shaped composite mass. The shaped mass of uranium oxide and uranium halide is then fired at an elevated temperature so as to form a refractory sintered article. It was found in the present invention that the introduction of a uraninm halide fluxing agent afforded a fluxing action with the uranium oxide particles and that excellent cohesion between these oxide particles was obtained. Approximately 90% of uranium dioxide and 10% of uranium tetrafluoride represent a preferred composition.

Hamilton, N.E.

1957-12-01T23:59:59.000Z

420

Uranium Leasing Program | Department of Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Uranium Leasing Program Uranium Leasing Program Abandoned Mine Reclamation, Uravan Mineral Belt, Colorado Abandoned Mine Reclamation, Uravan Mineral Belt, Colorado LM currently...

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Consolidated Edison Uranium Solidification Project | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Consolidated Edison Uranium Solidification Project Consolidated Edison Uranium Solidification Project CEUSP Inventory11-6-13Finalprint-ready.pdf CEUSPtimelinefinalprint-ready...

422

Uranium Enrichment Decontamination and Decommissioning Fund's...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Uranium Enrichment Decontamination and Decommissioning Fund's Fiscal Year 2008 and 2007 Financial Statement Audit, OAS-FS-10-05 Uranium Enrichment Decontamination and...

423

Understanding How Uranium Changes in Subsurface Environments...  

Office of Science (SC) Website

whether it is immobilized or moves out of a contaminated area, potentially into water supplies. The Impact New research on the transformation of uranium (VI) to uranium...

424

Uranium Compounds and Other Natural Radioactivities  

NLE Websites -- All DOE Office Websites (Extended Search)

X-ray Science Division XSD Groups Industry Argonne Home Advanced Photon Source Uranium Compounds and Other Natural Radioactivities Uranium containing compounds and other...

425

Uranium Downblending and Disposition Project Technology Readiness...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Centers Field Sites Power Marketing Administration Other Agencies You are here Home Uranium Downblending and Disposition Project Technology Readiness Assessment Uranium...

426

Uranium Mining Tax (Nebraska) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sites Power Marketing Administration Other Agencies You are here Home Savings Uranium Mining Tax (Nebraska) Uranium Mining Tax (Nebraska) Eligibility Agricultural...

427

Microsoft Word - UraniumBioreductionV3  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Highlight - March 2013 Biotic-Abiotic Pathways: A New Paradigm for Uranium Reduction in Sediments Uranium, one of the most common radioactive elements on Earth, makes its...

428

Domestic Uranium Production Report - Quarterly - Energy ...  

U.S. Energy Information Administration (EIA)

Total anticipated uranium market requirements at U.S. civilian nuclear power reactors are 50 million pounds for 2013. 2. 1 2012 Uranium Marketing ...

429

FLAME DENITRATION AND REDUCTION OF URANIUM NITRATE TO URANIUM DIOXIDE  

DOE Patents (OSTI)

A process is given for converting uranyl nitrate solution to uranium dioxide. The process comprises spraying fine droplets of aqueous uranyl nitrate solution into a hightemperature hydrocarbon flame, said flame being deficient in oxygen approximately 30%, retaining the feed in the flame for a sufficient length of time to reduce the nitrate to the dioxide, and recovering uranium dioxide. (AEC)

Hedley, W.H.; Roehrs, R.J.; Henderson, C.M.

1962-06-26T23:59:59.000Z

430

Solubility measurement of uranium in uranium-contaminated soils  

SciTech Connect

A short-term equilibration study involving two uranium-contaminated soils at the Fernald site was conducted as part of the In Situ Remediation Integrated Program. The goal of this study is to predict the behavior of uranium during on-site remediation of these soils. Geochemical modeling was performed on the aqueous species dissolved from these soils following the equilibration study to predict the on-site uranium leaching and transport processes. The soluble levels of total uranium, calcium, magnesium, and carbonate increased continually for the first four weeks. After the first four weeks, these components either reached a steady-state equilibrium or continued linearity throughout the study. Aluminum, potassium, and iron, reached a steady-state concentration within three days. Silica levels approximated the predicted solubility of quartz throughout the study. A much higher level of dissolved uranium was observed in the soil contaminated from spillage of uranium-laden solvents and process effluents than in the soil contaminated from settling of airborne uranium particles ejected from the nearby incinerator. The high levels observed for soluble calcium, magnesium, and bicarbonate are probably the result of magnesium and/or calcium carbonate minerals dissolving in these soils. Geochemical modeling confirms that the uranyl-carbonate complexes are the most stable and dominant in these solutions. The use of carbonate minerals on these soils for erosion control and road construction activities contributes to the leaching of uranium from contaminated soil particles. Dissolved carbonates promote uranium solubility, forming highly mobile anionic species. Mobile uranium species are contaminating the groundwater underlying these soils. The development of a site-specific remediation technology is urgently needed for the FEMP site.

Lee, S.Y.; Elless, M.; Hoffman, F.

1993-08-01T23:59:59.000Z

431

Aluminosilicate Precipitation Impact on Uranium  

SciTech Connect

Experiments have been conducted to examine the fate of uranium during the formation of sodium aluminosilicate (NAS) when wastes containing high aluminate concentrations are mixed with wastes of high silicate concentration. Testing was conducted at varying degrees of uranium saturation. Testing examined typical tank conditions, e.g., stagnant, slightly elevated temperature (50 C). The results showed that under sub-saturated conditions uranium is not removed from solution to any large extent in both simulant testing and actual tank waste testing. This aspect was not thoroughly understood prior to this work and was necessary to avoid criticality issues when actual tank wastes were aggregated. There are data supporting a small removal due to sorption of uranium on sites in the NAS. Above the solubility limit the data are clear that a reduction in uranium concentration occurs concomitant with the formation of aluminosilicate. This uranium precipitation is fairly rapid and ceases when uranium reaches its solubility limit. At the solubility limit, it appears that uranium is not affected, but further testing might be warranted.

WILMARTH, WILLIAM

2006-03-10T23:59:59.000Z

432

METHOD OF SEPARATING URANIUM SUSPENSIONS  

DOE Patents (OSTI)

A process is presented for separating colloidally dissed uranium oxides from the heavy water medium in upwhich they are contained. The method consists in treating such dispersions with hydrogen peroxide, thereby converting the uranium to non-colloidal UO/sub 4/, and separating the UO/sub 4/ sfter its rapid settling.

Wigner, E.P.; McAdams, W.A.

1958-08-26T23:59:59.000Z

433

2012 Domestic Uranium Production Report  

U.S. Energy Information Administration (EIA) Indexed Site

7 7 2012 Domestic Uranium Production Report Release Date: June 6, 2013 Next Release Date: May 2014 Milling Capacity (short tons of ore per day) 2008 2009 2010 2011 2012 Cotter Corporation Canon City Mill Fremont, Colorado 0 Standby Standby Standby Reclamation Demolished EFR White Mesa LLC White Mesa Mill San Juan, Utah 2,000 Operating Operating Operating Operating Operating Energy Fuels Resources Corporation Piñon Ridge Mill Montrose, Colorado 500 Developing Developing Developing Permitted And Licensed Partially Permitted And Licensed Kennecott Uranium Company/Wyoming Coal Resource Company Sweetwater Uranium Project Sweetwater, Wyoming 3,000 Standby Standby Standby Standby Standby Uranium One Americas, Inc. Shootaring Canyon Uranium Mill Garfield, Utah 750 Changing License To Operational Standby

434

METHOD OF ELECTROPLATING ON URANIUM  

DOE Patents (OSTI)

This patent relates to a preparation of metallic uranium surfaces for receiving coatings, particularly in order to secure adherent electroplated coatings upon uranium metal. In accordance with the invention the uranium surface is pretreated by degreasing in trichloroethylene, followed by immersion in 25 to 50% nitric acid for several minutes, and then rinsed with running water, prior to pickling in trichloroacetic acid. The last treatment is best accomplished by making the uranium the anode in an aqueous solution of 50 per cent by weight trichloroacetic acid until work-distorted crystals or oxide present on the metal surface have been removed and the basic crystalline structure of the base metal has been exposed. Following these initial steps the metallic uranium is rinsed in dilute nitric acid and then electroplated with nickel. Adnerent firmly-bonded coatings of nickel are obtained.

Rebol, E.W.; Wehrmann, R.F.

1959-04-28T23:59:59.000Z

435

Standing by Ohio: Cleaning Up our Environmental Legacy | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

the start-up of operations at the Depleted Uranium Hexafluoride Conversion Plant, or DUF6, as we commonly call it. Depleted uranium hexafluoride has been generated in the United...

436

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

2. U.S. uranium mine production and number of mines and sources, 2003-2012 2. U.S. uranium mine production and number of mines and sources, 2003-2012 Production / Mining Method 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 Underground (estimated contained thousand pounds U3O8) W W W W W W W W W W Open Pit (estimated contained thousand pounds U3O8) 0 0 0 0 0 0 0 0 0 0 In-Situ Leaching (thousand pounds U3O8) W W 2,681 4,259 W W W W W W Other1 (thousand pounds U3O8) W W W W W W W W W W Total Mine Production (thousand pounds U3O8) E2,200 2,452 3,045 4,692 4,541 3,879 4,145 4,237 4,114 4,335 Number of Operating Mines Underground 1 2 4 5 6 10 14 4 5 6 Open Pit 0 0 0 0 0 0 0 0 0 0 In-Situ Leaching 2 3 4 5 5 6 4 4 5 5 Other Sources1 1 1 2 1 1 1 2 1 1 1

437

Domestic Uranium Production Report  

Gasoline and Diesel Fuel Update (EIA)

5. U.S. uranium in-situ-leach plants by owner, location, capacity, and operating status at end of the year, 2008-2012 5. U.S. uranium in-situ-leach plants by owner, location, capacity, and operating status at end of the year, 2008-2012 In-Situ-Leach Plant Owner In-Situ-Leach Plant Name County, State (existing and planned locations) Production Capacity (pounds U3O8 per year) Operating Status at End of the Year 2008 2009 2010 2011 2012 Cameco Crow Butte Operation Dawes, Nebraska 1,000,000 Operating Operating Operating Operating Operating Hydro Resources, Inc. Crownpoint McKinley, New Mexico 1,000,000 Partially Permitted And Licensed Partially Permitted And Licensed Partially Permitted And Licensed Partially Permitted And Licensed Partially Permitted And Licensed Hydro Resources,Inc. Church Rock McKinley, New Mexico 1,000,000 Partially Permitted And Licensed Partially Permitted And Licensed Partially Permitted And Licensed Partially Permitted And Licensed Partially Permitted And Licensed

438

Final report on PCRV thermal cylinder axial tendon failures  

SciTech Connect

The post-test examination of the failed tendons from the PCRV thermal cylinder experiment has been concluded. Failures in the wires are attributed to stress-corrosion cracking. The cause of tendon failures has not been unequivocably established, but they may have been due to nitrates in the duct. The wires employed in the manufacture of the tendons will crack in less than 72 hr in a 0.2 M solution of ammonium nitrate at 70$sup 0$C. The quality of the wires is poor, and surface cracks were detected. These could have acted as concentrating sites for both stress and the deleterious contaminants. It is believed that the factors that led to the failures in the thermal cylinder experiment were unique. An improper formulation of the epoxy resin did not provide the tendon anchor plate seal that was desired; indeed, the improper formulation is responsible for the high level of nitrogen in the ducts of the failed tendons. (auth)

Canonico, D.A.; Griess, J.C.; Robinson, G.C.

1976-01-01T23:59:59.000Z

439

Process for removing carbon from uranium  

DOE Patents (OSTI)

Carbon contamination is removed from uranium and uranium alloys by heating in inert atmosphere to 700.degree.-1900.degree.C in effective contact with yttrium to cause carbon in the uranium to react with the yttrium. The yttrium is either in direct contact with the contaminated uranium or in indirect contact by means of an intermediate transport medium.

Powell, George L. (Oak Ridge, TN); Holcombe, Jr., Cressie E. (Knoxville, TN)

1976-01-01T23:59:59.000Z

440

APPENDIX J Partition Coefficients For Uranium  

E-Print Network (OSTI)

APPENDIX J Partition Coefficients For Uranium #12;Appendix J Partition Coefficients For Uranium J.1.0 Background The review of uranium Kd values obtained for a number of soils, crushed rock and their effects on uranium adsorption on soils are discussed below. The solution pH was also used as the basis

Note: This page contains sample records for the topic "uranium hexafluoride cylinder" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Barriers and Issues Related to Achieving Final Disposition of Depleted Uranium  

Science Conference Proceedings (OSTI)

Approximately 750,000 metric tons (MT) of surplus depleted uranium (DU) in various chemical forms are stored at several Department of Energy (DOE) sites throughout the United States. Most of the DU is in the form of DU hexafluoride (DUF6) that resulted from uranium enrichment operations over the last several decades. DOE plans to convert the DUF6 to ''a more stable form'' that could be any one or combination of DU tetrafluoride (DUF4 or green salt), DU oxide (DUO3, DUO2, or DU3O8), or metal depending on the final disposition chosen for any given quantity. Barriers to final disposition of this material have existed historically and some continue today. Currently, the barriers are more related to finding uses for this material versus disposing as waste. Even though actions are beginning to convert the DUF6, ''final'' disposition of the converted material has yet to be decided. Unless beneficial uses can be implemented, DOE plans to dispose of this material as waste. This expresses the main barrier to DU disposition; DOE's strategy is to dispose unless uses can be found while the strategy should be only dispose as a last resort and make every effort to find uses. To date, only minimal research programs are underway to attempt to develop non-fuel uses for this material. Other issues requiring resolution before these inventories can reach final disposition (uses or disposal) include characterization, disposal of large quantities, storage (current and future), and treatment options. Until final disposition is accomplished, these inventories must be managed in a safe and environmentally sound manner; however, this is becoming more difficult as materials and facilities age. The most noteworthy final disposition technical issues include the development of reuse and treatment options.

Gillas, D. L.; Chambers, B. K.

2002-02-26T23:59:59.000Z

442

Integrated hydraulic cooler and return rail in camless cylinder head  

SciTech Connect

An engine assembly may include a cylinder head defining an engine coolant reservoir, a pressurized fluid supply, a valve actuation assembly, and a hydraulic fluid reservoir. The valve actuation assembly may be in fluid communication with the pressurized fluid supply and may include a valve member displaceable by a force applied by the pressurized fluid supply. The hydraulic fluid reservoir may be in fluid communication with the valve actuation assembly and in a heat exchange relation to the engine coolant reservoir.

Marriott, Craig D. (Clawson, MI); Neal, Timothy L. (Ortonville, MI); Swain, Jeff L. (Flushing, MI); Raimao, Miguel A. (Colorado Springs, CO)

2011-12-13T23:59:59.000Z

443

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

61 - 13770 of 31,917 results. 61 - 13770 of 31,917 results. Page EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site This site-specific EIS analyzes the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three alternative locations within the Paducah site; transportation of all cylinders (DUF6, enriched, and empty) currently stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Portsmouth; construction of a new cylinder storage yard at Portsmouth (if required) for ETTP cylinders; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as

444

Wave runup on cylinders subject to deep water random waves  

E-Print Network (OSTI)

The accurate prediction of wave runup on deepwater offshore platform columns is of great importance for design engineers. Although linear predictive models are commonly used in the design and analysis process, many of the important effects are of higher order, and thus can only be accounted for by complex nonlinear models that better reflect the physics of the problem. This study presents a two-parameter Weibull distribution function that utilizes empirical coefficients to model the surface wave runup. Laboratory measurements of irregular waves interfering with vertical platform cylinders were used to obtain the Weibull coefficients necessary for the analytical model. Six data sets with different configurations where the wave elevation was measured close to the test cylinders are analyzed. These data on wave runup in deepwater random waves were generated at similar water depths with significant wave heights and spectral peak periods. Statistical parameters, zero crossing analysis and spectral analysis were utilized to characterize and interpret the time series data. The analysis focused on interpreting the tails of the probability distributions by carefully fitting the analytical model to the measured model data. The main conclusion of this study is that the two-parameter Weibull model can be used to accurately model the wave runup on platform cylinders for the experimental data investigated in this study.

Indrebo, Ann Kristin

2001-01-01T23:59:59.000Z

445

Natural Gas Vehicle Cylinder Safety, Training and Inspection Project  

DOE Green Energy (OSTI)

Under the auspices of the National Energy Technology Laboratory and the US Department of Energy, the Clean Vehicle Education Foundation conducted a three-year program to increase the understanding of the safe and proper use and maintenance of vehicular compressed natural gas (CNG) fuel systems. High-pressure fuel systems require periodic inspection and maintenance to insure safe and proper operation. The project addressed the needs of CNG fuel containers (cylinders) and associated high-pressure fuel system components related to existing law, codes and standards (C&S), available training and inspection programs, and assured coordination among vehicle users, public safety officials, fueling station operators and training providers. The program included a public and industry awareness campaign, establishment and administration of a cylinder inspector certification training scholarship program, evaluation of current safety training and testing practices, monitoring and investigation of CNG vehicle incidents, evaluation of a cylinder recertification program and the migration of CNG vehicle safety knowledge to the nascent hydrogen vehicle community.

Hank Seiff

2008-12-31T23:59:59.000Z

446

The End of Cheap Uranium  

E-Print Network (OSTI)

Historic data from many countries demonstrate that on average no more than 50-70% of the uranium in a deposit could be mined. An analysis of more recent data from Canada and Australia leads to a mining model with an average deposit extraction lifetime of 10+- 2 years. This simple model provides an accurate description of the extractable amount of uranium for the recent mining operations. Using this model for all larger existing and planned uranium mines up to 2030, a global uranium mining peak of at most 58 +- 4 ktons around the year 2015 is obtained. Thereafter we predict that uranium mine production will decline to at most 54 +- 5 ktons by 2025 and, with the decline steepening, to at most 41 +- 5 ktons around 2030. This amount will not be sufficient to fuel the existing and planned nuclear power plants during the next 10-20 years. In fact, we find that it will be difficult to avoid supply shortages even under a slow 1%/year worldwide nuclear energy phase-out scenario up to 2025. We thus suggest that a worldwide nuclear energy phase-out is in order. If such a slow global phase-out is not voluntarily effected, the end of the present cheap uranium supply situation will be unavoidable. The result will be that some countries will simply be unable to afford sufficient uranium fuel at that point, which implies involuntary and perhaps chaotic nuclear phase-outs in those countries involving brownouts, blackouts, and worse.

Michael Dittmar

2011-06-18T23:59:59.000Z

447

Independent Oversight Assessment, Portsmouth/Paducah Project Office- May 2012  

Energy.gov (U.S. Department of Energy (DOE))

Assessment of the Portsmouth/Paducah Project Office Conduct of Operations Oversight of the Depleted Uranium Hexafluoride Conversion Plants

448

ELECTRODEPOSITION OF NICKEL ON URANIUM  

SciTech Connect

Electrodeposited nickel coatings on uranium for protection from destructive corrosion in boiling water wns investigated. Correlation between the pretreatment of the uranium and subsequent protection by thin nickel coatings was established. Thin electrodeposited nickel coatings provide better protection when applied to a matte surface produced by blasting with an aqueous suspension of silica (100 mesh) followed by a cathodic treatment in 35 wt% sulfuric acid than when applied to the rough surfaces produced on uranium by anodic pretreatments and acid pickling. Blistering of nickel electrodeposits arising from hydrogen was encountered and eliminated. (auth)

Beard, A.P.; Crooks, D.D.

1954-08-31T23:59:59.000Z

449

SEPARATION OF URANIUM FROM THORIUM  

DOE Patents (OSTI)

A process is presented for separating uranium from thorium wherein the ratio of thorium to uranium is between 100 to 10,000. According to the invention the thoriumuranium mixture is dissolved in nitric acid, and the solution is prepared so as to obtain the desired concentration within a critical range of from 4 to 8 N with regard to the total nitrate due to thorium nitrate, with or without nitric acid or any nitrate salting out agent. The solution is then contacted with an ether, such as diethyl ether, whereby uranium is extracted into ihe organic phase while thorium remains in the aqueous phase.

Hellman, N.N.

1959-07-01T23:59:59.000Z

450