Sample records for uranium depleted uranium

  1. Depleted Uranium Technical Brief

    E-Print Network [OSTI]

    Depleted Uranium Technical Brief United States Environmental Protection Agency Office of Air and Radiation Washington, DC 20460 EPA-402-R-06-011 December 2006 #12;#12;Depleted Uranium Technical Brief EPA of Radiation and Indoor Air Radiation Protection Division ii #12;iii #12;FOREWARD The Depleted Uranium

  2. Depleted uranium management alternatives

    SciTech Connect (OSTI)

    Hertzler, T.J.; Nishimoto, D.D.

    1994-08-01T23:59:59.000Z

    This report evaluates two management alternatives for Department of Energy depleted uranium: continued storage as uranium hexafluoride, and conversion to uranium metal and fabrication to shielding for spent nuclear fuel containers. The results will be used to compare the costs with other alternatives, such as disposal. Cost estimates for the continued storage alternative are based on a life-cycle of 27 years through the year 2020. Cost estimates for the recycle alternative are based on existing conversion process costs and Capital costs for fabricating the containers. Additionally, the recycle alternative accounts for costs associated with intermediate product resale and secondary waste disposal for materials generated during the conversion process.

  3. Depleted uranium disposal options evaluation

    SciTech Connect (OSTI)

    Hertzler, T.J.; Nishimoto, D.D.; Otis, M.D. [Science Applications International Corp., Idaho Falls, ID (United States). Waste Management Technology Div.

    1994-05-01T23:59:59.000Z

    The Department of Energy (DOE), Office of Environmental Restoration and Waste Management, has chartered a study to evaluate alternative management strategies for depleted uranium (DU) currently stored throughout the DOE complex. Historically, DU has been maintained as a strategic resource because of uses for DU metal and potential uses for further enrichment or for uranium oxide as breeder reactor blanket fuel. This study has focused on evaluating the disposal options for DU if it were considered a waste. This report is in no way declaring these DU reserves a ``waste,`` but is intended to provide baseline data for comparison with other management options for use of DU. To PICS considered in this report include: Retrievable disposal; permanent disposal; health hazards; radiation toxicity and chemical toxicity.

  4. Review The Toxicity of Depleted Uranium

    E-Print Network [OSTI]

    Wayne Briner

    Abstract: Depleted uranium (DU) is an emerging environmental pollutant that is introduced into the environment primarily by military activity. While depleted uranium is less radioactive than natural uranium, it still retains all the chemical toxicity associated with the original element. In large doses the kidney is the target organ for the acute chemical toxicity of this metal, producing potentially lethal tubular necrosis. In contrast, chronic low dose exposure to depleted uranium may not produce a clear and defined set of symptoms. Chronic low-dose, or subacute, exposure to depleted uranium alters the appearance of milestones in developing organisms. Adult animals that were exposed to depleted uranium during development display persistent alterations in behavior, even after cessation of depleted uranium exposure. Adult animals exposed to depleted uranium demonstrate altered behaviors and a variety of alterations to brain chemistry. Despite its reduced level of radioactivity evidence continues to accumulate that depleted uranium, if ingested, may pose a radiologic hazard. The current state of knowledge concerning DU is discussed.

  5. Depleted Uranium Hexafluoride (DUF6) Fully Operational at the...

    Office of Environmental Management (EM)

    Depleted Uranium Hexafluoride (DUF6) Fully Operational at the Portsmouth and Paducah Gaseous Diffusion Sites Depleted Uranium Hexafluoride (DUF6) Fully Operational at the...

  6. Molten-Salt Depleted-Uranium Reactor

    E-Print Network [OSTI]

    Dong, Bao-Guo; Gu, Ji-Yuan

    2015-01-01T23:59:59.000Z

    The supercritical, reactor core melting and nuclear fuel leaking accidents have troubled fission reactors for decades, and greatly limit their extensive applications. Now these troubles are still open. Here we first show a possible perfect reactor, Molten-Salt Depleted-Uranium Reactor which is no above accident trouble. We found this reactor could be realized in practical applications in terms of all of the scientific principle, principle of operation, technology, and engineering. Our results demonstrate how these reactors can possess and realize extraordinary excellent characteristics, no prompt critical, long-term safe and stable operation with negative feedback, closed uranium-plutonium cycle chain within the vessel, normal operation only with depleted-uranium, and depleted-uranium high burnup in reality, to realize with fission nuclear energy sufficiently satisfying humanity long-term energy resource needs, as well as thoroughly solve the challenges of nuclear criticality safety, uranium resource insuffic...

  7. Depleted uranium disposition study -- Supplement, Revision 1

    SciTech Connect (OSTI)

    Becker, G.W.

    1993-11-01T23:59:59.000Z

    The Department of Energy Office of Weapons and Materials Planning has requested a supplemental study to update the recent Depleted Uranium Disposition report. This supplemental study addresses new disposition alternatives and changes in status.

  8. Depleted uranium: A DOE management guide

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) has a management challenge and financial liability in the form of 50,000 cylinders containing 555,000 metric tons of depleted uranium hexafluoride (UF{sub 6}) that are stored at the gaseous diffusion plants. The annual storage and maintenance cost is approximately $10 million. This report summarizes several studies undertaken by the DOE Office of Technology Development (OTD) to evaluate options for long-term depleted uranium management. Based on studies conducted to date, the most likely use of the depleted uranium is for shielding of spent nuclear fuel (SNF) or vitrified high-level waste (HLW) containers. The alternative to finding a use for the depleted uranium is disposal as a radioactive waste. Estimated disposal costs, utilizing existing technologies, range between $3.8 and $11.3 billion, depending on factors such as applicability of the Resource Conservation and Recovery Act (RCRA) and the location of the disposal site. The cost of recycling the depleted uranium in a concrete based shielding in SNF/HLW containers, although substantial, is comparable to or less than the cost of disposal. Consequently, the case can be made that if DOE invests in developing depleted uranium shielded containers instead of disposal, a long-term solution to the UF{sub 6} problem is attained at comparable or lower cost than disposal as a waste. Two concepts for depleted uranium storage casks were considered in these studies. The first is based on standard fabrication concepts previously developed for depleted uranium metal. The second converts the UF{sub 6} to an oxide aggregate that is used in concrete to make dry storage casks.

  9. Capstone Depleted Uranium Aerosols: Generation and Characterization

    SciTech Connect (OSTI)

    Parkhurst, MaryAnn; Szrom, Fran; Guilmette, Ray; Holmes, Tom; Cheng, Yung-Sung; Kenoyer, Judson L.; Collins, John W.; Sanderson, T. Ellory; Fliszar, Richard W.; Gold, Kenneth; Beckman, John C.; Long, Julie

    2004-10-19T23:59:59.000Z

    In a study designed to provide an improved scientific basis for assessing possible health effects from inhaling depleted uranium (DU) aerosols, a series of DU penetrators was fired at an Abrams tank and a Bradley fighting vehicle. A robust sampling system was designed to collect aerosols in this difficult environment and continuously monitor the sampler flow rates. Aerosols collected were analyzed for uranium concentration and particle size distribution as a function of time. They were also analyzed for uranium oxide phases, particle morphology, and dissolution in vitro. The resulting data provide input useful in human health risk assessments.

  10. The ultimate disposition of depleted uranium

    SciTech Connect (OSTI)

    Lemons, T.R. [Uranium Enrichment Organization, Oak Ridge, TN (United States)

    1991-12-31T23:59:59.000Z

    Depleted uranium (DU) is produced as a by-product of the uranium enrichment process. Over 340,000 MTU of DU in the form of UF{sub 6} have been accumulated at the US government gaseous diffusion plants and the stockpile continues to grow. An overview of issues and objectives associated with the inventory management and the ultimate disposition of this material is presented.

  11. Depleted Uranium in Kosovo Post-Conflict Environmental Assessment

    E-Print Network [OSTI]

    Unep Scientific; Mission Kosovo

    2.1 UNEP’s role in post-conflict environmental assessment................................................9 2.2 Depleted uranium............................................................10

  12. Depleted uranium plasma reduction system study

    SciTech Connect (OSTI)

    Rekemeyer, P.; Feizollahi, F.; Quapp, W.J.; Brown, B.W.

    1994-12-01T23:59:59.000Z

    A system life-cycle cost study was conducted of a preliminary design concept for a plasma reduction process for converting depleted uranium to uranium metal and anhydrous HF. The plasma-based process is expected to offer significant economic and environmental advantages over present technology. Depleted Uranium is currently stored in the form of solid UF{sub 6}, of which approximately 575,000 metric tons is stored at three locations in the U.S. The proposed system is preconceptual in nature, but includes all necessary processing equipment and facilities to perform the process. The study has identified total processing cost of approximately $3.00/kg of UF{sub 6} processed. Based on the results of this study, the development of a laboratory-scale system (1 kg/h throughput of UF6) is warranted. Further scaling of the process to pilot scale will be determined after laboratory testing is complete.

  13. Depleted uranium hexafluoride: Waste or resource?

    SciTech Connect (OSTI)

    Schwertz, N.; Zoller, J.; Rosen, R.; Patton, S. [Lawrence Livermore National Lab., CA (United States); Bradley, C. [USDOE Office of Nuclear Energy, Science, Technology, Washington, DC (United States); Murray, A. [SAIC (United States)

    1995-07-01T23:59:59.000Z

    the US Department of Energy is evaluating technologies for the storage, disposal, or re-use of depleted uranium hexafluoride (UF{sub 6}). This paper discusses the following options, and provides a technology assessment for each one: (1) conversion to UO{sub 2} for use as mixed oxide duel, (2) conversion to UO{sub 2} to make DUCRETE for a multi-purpose storage container, (3) conversion to depleted uranium metal for use as shielding, (4) conversion to uranium carbide for use as high-temperature gas-cooled reactor (HTGR) fuel. In addition, conversion to U{sub 3}O{sub 8} as an option for long-term storage is discussed.

  14. Assessment of Preferred Depleted Uranium Disposal Forms

    SciTech Connect (OSTI)

    Croff, A.G.; Hightower, J.R.; Lee, D.W.; Michaels, G.E.; Ranek, N.L.; Trabalka, J.R.

    2000-06-01T23:59:59.000Z

    The Department of Energy (DOE) is in the process of converting about 700,000 metric tons (MT) of depleted uranium hexafluoride (DUF6) containing 475,000 MT of depleted uranium (DU) to a stable form more suitable for long-term storage or disposal. Potential conversion forms include the tetrafluoride (DUF4), oxide (DUO2 or DU3O8), or metal. If worthwhile beneficial uses cannot be found for the DU product form, it will be sent to an appropriate site for disposal. The DU products are considered to be low-level waste (LLW) under both DOE orders and Nuclear Regulatory Commission (NRC) regulations. The objective of this study was to assess the acceptability of the potential DU conversion products at potential LLW disposal sites to provide a basis for DOE decisions on the preferred DU product form and a path forward that will ensure reliable and efficient disposal.

  15. The ultimate disposition of depleted uranium

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    Significant amounts of the depleted uranium (DU) created by past uranium enrichment activities have been sold, disposed of commercially, or utilized by defense programs. In recent years, however, the demand for DU has become quite small compared to quantities available, and within the US Department of Energy (DOE) there is concern for any risks and/or cost liabilities that might be associated with the ever-growing inventory of this material. As a result, Martin Marietta Energy Systems, Inc. (Energy Systems), was asked to review options and to develop a comprehensive plan for inventory management and the ultimate disposition of DU accumulated at the gaseous diffusion plants (GDPs). An Energy Systems task team, under the chairmanship of T. R. Lemons, was formed in late 1989 to provide advice and guidance for this task. This report reviews options and recommends actions and objectives in the management of working inventories of partially depleted feed (PDF) materials and for the ultimate disposition of fully depleted uranium (FDU). Actions that should be considered are as follows. (1) Inspect UF{sub 6} cylinders on a semiannual basis. (2) Upgrade cylinder maintenance and storage yards. (3) Convert FDU to U{sub 3}O{sub 8} for long-term storage or disposal. This will include provisions for partial recovery of costs to offset those associated with DU inventory management and the ultimate disposal of FDU. Another recommendation is to drop the term tails'' in favor of depleted uranium'' or DU'' because the tails'' label implies that it is waste.'' 13 refs.

  16. Uranio impoverito: perché? (Depleted uranium: why?)

    E-Print Network [OSTI]

    Germano D'Abramo

    2003-06-05T23:59:59.000Z

    In this paper we develop a simple model of the penetration process of a long rod through an uniform target. Applying the momentum and energy conservation laws, we derive an analytical relation which shows how the penetration depth depends upon the density of the rod, given a fixed kinetic energy. This work was sparked off by the necessity of understanding the effectiveness of high density penetrators (e.g. depleted uranium penetrators) as anti-tank weapons.

  17. Conversion of depleted uranium hexafluoride to a solid uranium compound

    DOE Patents [OSTI]

    Rothman, Alan B. (Willowbrook, IL); Graczyk, Donald G. (Lemont, IL); Essling, Alice M. (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A process for converting UF.sub.6 to a solid uranium compound such as UO.sub.2 and CaF. The UF.sub.6 vapor form is contacted with an aqueous solution of NH.sub.4 OH at a pH greater than 7 to precipitate at least some solid uranium values as a solid leaving an aqueous solution containing NH.sub.4 OH and NH.sub.4 F and remaining uranium values. The solid uranium values are separated from the aqueous solution of NH.sub.4 OH and NH.sub.4 F and remaining uranium values which is then diluted with additional water precipitating more uranium values as a solid leaving trace quantities of uranium in a dilute aqueous solution. The dilute aqueous solution is contacted with an ion-exchange resin to remove substantially all the uranium values from the dilute aqueous solution. The dilute solution being contacted with Ca(OH).sub.2 to precipitate CaF.sub.2 leaving dilute NH.sub.4 OH.

  18. DOE Announces Transfer of Depleted Uranium to Advance the U.S...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transfer of Depleted Uranium to Advance the U.S. National Security Interests, Extend Operations at Paducah Gaseous Diffusion Plant DOE Announces Transfer of Depleted Uranium to...

  19. Processing depleted uranium quad alloy penetrator rods

    SciTech Connect (OSTI)

    Bokan, S.L.

    1987-02-19T23:59:59.000Z

    Two depleted uranium (DU) quad alloys were cast, extruded and rolled to produce penetrator rods. The two alloy combinations were (1) 1 wt % molybdenum (Mo), 1 wt % niobium (Nb), and 0.75 wt % titanium (Ti); and (2) 1 wt % tantalum (Ta), 1 wt % Nb, and 0.75 wt % Ti. This report covers the processing and results with limited metallographic information available. The two alloys were each vacuum induction melted (VIM) into an 8-in. log, extruded into a 3-in. log, then cut into 4 logs and extruded at 4 different temperatures into 0.8-in. bars. From the 8 conditions (2 alloys, 4 extrusion temperatures each), 10 to 13 16-in. rods were cut for rolling and swaging. Due to cracking problems, the final processing changed from rolling and swaging to limited rolling and heat treating. The contracted work was completed with the delivery of 88 rods to Dr. Zabielski. 28 figs.

  20. Status Report and Proposal Concerning the Supply of Depleted Uranium Metal Bands for a Particle Detector

    E-Print Network [OSTI]

    1980-01-01T23:59:59.000Z

    Status Report and Proposal Concerning the Supply of Depleted Uranium Metal Bands for a Particle Detector

  1. The Hazard Posed by Depleted Uranium Munitions

    E-Print Network [OSTI]

    Steve Fetter And; Steve Fetter A

    This paper assesses the radiological and chemical hazards resulting from the use of depleted uranium (DU) munitions. Due to the low radioactivity of DU, radiological hazards to individuals would become significant in comparison to natural background radiation doses only in cases of prolonged contact---for example, when shards of a DU penetrator remain embedded in a soldier's body. Although the radiation doses to virtually all civilians would be very low, the cumulative "population dose" resulting from the dispersal of hundreds of tons of DU, as occurred during the Gulf War, could result in up to ten cancer deaths. It is highly unlikely that exposures of persons downwind from the use of DU munitions or consuming food or water contaminated by DU dust would reach the estimated threshold for chemical heavy-metal effects. The exposures of soldiers in vehicles struck by DU munitions could be much higher, however, and persons who subsequently enter such vehicles without adequate respiratory protection could potentially be at risk. Soldiers should be trained to avoid unnecessary exposure to DU, and vehicles struck by DU munitions should be made inaccessible to curious civilians. INTRODUCTION

  2. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, Charles W. (Oak Ridge, TN)

    1998-01-01T23:59:59.000Z

    A method for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package.

  3. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, C.W.

    1998-11-03T23:59:59.000Z

    A method is described for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package. 6 figs.

  4. Sampling Plan for Assaying Plates Containing Depleted or Normal Uranium

    SciTech Connect (OSTI)

    Ivan R. Thomas

    2011-11-01T23:59:59.000Z

    This paper describes the rationale behind the proposed method for selecting a 'representative' sample of uranium metal plates, portions of which will be destructively assayed at the Y-12 Security Complex. The total inventory of plates is segregated into two populations, one for Material Type 10 (depleted uranium (DU)) and one for Material Type 81 (normal [or natural] uranium (NU)). The plates within each population are further stratified by common dimensions. A spreadsheet gives the collective mass of uranium element (and isotope for DU) and the piece count of all plates within each stratum. These data are summarized in Table 1. All plates are 100% uranium metal, and all but approximately 60% of the NU plates have Kel-F{reg_sign} coating. The book inventory gives an overall U-235 isotopic percentage of 0.22% for the DU plates, ranging from 0.19% to 0.22%. The U-235 ratio of the NU plates is assumed to be 0.71%. As shown in Table 1, the vast majority of the plates are comprised of depleted uranium, so most of the plates will be sampled from the DU population.

  5. Ultrafiltration evaluation with depleted uranium oxide

    SciTech Connect (OSTI)

    Weisbrod, K.R.; Schake, A.R.; Morgan, A.N.; Purdy, G.M.; Martinez, H.E.; Nelson, T.O.

    1998-03-01T23:59:59.000Z

    Scientists at the Los Alamos National Laboratory Plutonium Facility are using electrodissolution in neutral to alkaline solutions to decontaminate oralloy parts that have surface plutonium contamination. Ultrafiltration of the electrolyte stream removes precipitate so that the electrolyte stream to the decontamination fixture is precipitate free. This report describes small-scale laboratory ultrafiltration experiments that the authors performed to determine conditions necessary for full-scale operation of an ultrafiltration module. Performance was similar to what they observed in the ferric hydroxide system. At 12 psi transmembrane pressure, a shear rate of 12,000 sec{sup {minus}1} was sufficient to sustain membrane permeability. Ultrafiltration of uranium(VI) oxide appears to occur as easily as ultrafiltration of ferric hydroxide. Considering the success reported in this study, the authors plan to add ultrafiltration to the next decontamination system for oralloy parts.

  6. EIS-0269: Long-Term Management of Depleted Uranium Hexaflouride

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) prepared this programmatic environmental impact statement to assess the potential impacts of alternative management strategies for depleted uranium hexafluoride currently stored at three DOE sites: Paducah site near Paducah, Kentucky; Portsmouth site near Portsmouth, Ohio; and K-25 site on the Oak Ridge Reservation in Oak Ridge, Tennessee.

  7. Characterization of Thermal Properties of Depleted Uranium Metal Microspheres

    E-Print Network [OSTI]

    Humrickhouse, Carissa Joy

    2012-07-16T23:59:59.000Z

    that combines these previous two methods to characterize the diffusivity of a packed bed of microspheres of depleted uranium (DU) metal, which have a nominal diameter of 250 micrometers. The new apparatus is designated as the Crucible Heater Test Assembly (CHTA...

  8. Microstructure of depleted uranium under uniaxial strain conditions

    SciTech Connect (OSTI)

    Zurek, A.K.; Embury, J.D.; Kelly, A.; Thissell, W.R.; Gustavsen, R.L.; Vorthman, J.E.; Hixson, R.H.

    1997-09-01T23:59:59.000Z

    Uranium samples of two different purities were used for spall strength measurements. Samples of depleted uranium were taken from very high purity material (38 ppM carbon) and from material containing 280 ppM C. Experimental conditions were chosen to effectively arrest the microstructural damage at two places in the development to full spall separation. Samples were soft recovered and characterized with respect to the microstructure and the form of damage. This allowed determination of the dependence of spall mechanisms on stress level, stress state, and sample purity. This information is used in developing a model to predict the mode of fracture.

  9. Uranio impoverito: perch'e? (Depleted uranium: why?)

    E-Print Network [OSTI]

    D'Abramo, G

    2003-01-01T23:59:59.000Z

    In this paper we develop a simple model of the penetration process of a long rod through an uniform target. Applying the momentum and energy conservation laws, we derive an analytical relation which shows how the penetration depth depends upon the density of the rod, given a fixed kinetic energy. This work was sparked off by the necessity of the author of understanding the reasons of the effectiveness of high density penetrators (e.g. depleted uranium penetrators) as anti-tank weapons.

  10. Composition of the U.S. DOE Depleted Uranium Inventory

    E-Print Network [OSTI]

    Concentration Of Less

    about 2.75 wt% U-235. For further enrichment, the material was shipped to the Oak Ridge and Portsmouth plants. In addition to natural uranium, also uranium recycled from spent fuel was fed into the Paducah enrichment cascade (Table 2 and Fig. 2). The recycled uranium introduced various isotopes not found in natural uranium into the cascade: fission products, such as Technetium-99; transuranics, such as Neptunium-237 and Plutonium-239; and the artificial uranium isotope of Uranium-236. The spent fuel, from which uranium was recycled, originated from the Hanford and Savannah River military plutonium production reactors. This uranium was recycled, although its assay of U-235 was somewhat lower than in natural uranium (Table 2). This obviously must be seen in the context of the Cold War era, when uranium was a scarce resource. Due to the low burn-up of the military reactors, concentrations of artificial U-236 are comparatively low in this recycled uranium. The recycled uranium represents

  11. EIS-0329: Proposed Construction, Operation, Decontamination/Decommissioning of Depleted Uranium Hexafluoride Conversion Facilities

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposal to construct, operate, maintain, and decontaminate and decommission two depleted uranium hexafluoride (DUF 6) conversion facilities, at Portsmouth, Ohio, and Paducah, Kentucky.

  12. Depleted uranium storage and disposal trade study: Summary report

    SciTech Connect (OSTI)

    Hightower, J.R.; Trabalka, J.R.

    2000-02-01T23:59:59.000Z

    The objectives of this study were to: identify the most desirable forms for conversion of depleted uranium hexafluoride (DUF6) for extended storage, identify the most desirable forms for conversion of DUF6 for disposal, evaluate the comparative costs for extended storage or disposal of the various forms, review benefits of the proposed plasma conversion process, estimate simplified life-cycle costs (LCCs) for five scenarios that entail either disposal or beneficial reuse, and determine whether an overall optimal form for conversion of DUF6 can be selected given current uncertainty about the endpoints (specific disposal site/technology or reuse options).

  13. Depleted-Uranium Weapons the Whys and Wherefores

    E-Print Network [OSTI]

    Gsponer, A

    2003-01-01T23:59:59.000Z

    The only military application in which present-day depleted-uranium (DU) alloys out-perform tungsten alloys is long-rod penetration into a main battle-tank's armor. However, this advantage is only on the order of 10% and disappearing when the comparison is made in terms of actual lethality of complete anti-tank systems instead of laboratory-type steel penetration capability. Therefore, new micro- and nano-engineered tungsten alloys may soon out-perform existing DU alloys, enabling the production of tungsten munition which will be better than uranium munition, and whose overall life-cycle cost will be less due to the absence of the problems related to the radioactivity of uranium. The reasons why DU weapons have been introduced and used are analysed from the perspective that their radioactivity must have played an important role in the decision making process. It is found that DU weapons belong to the diffuse category of low-radiological-impact nuclear weapons to which emerging types of low-yield, i.e., fourth...

  14. Including environmental concerns in management strategies for depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Goldberg, M. [Argonne National Laboratory, Washington, DC (United States); Avci, H.I. [Argonne National Lab., IL (United States); Bradley, C.E. [USDOE, Washington, DC (United States)

    1995-12-31T23:59:59.000Z

    One of the major programs within the Office of Nuclear Energy, Science, and Technology of the US Department of Energy (DOE) is the depleted uranium hexafluoride (DUF{sub 6}) management program. The program is intended to find a long-term management strategy for the DUF{sub 6} that is currently stored in approximately 46,400 cylinders at Paducah, KY; Portsmouth, OH; and Oak Ridge, TN, USA. The program has four major components: technology assessment, engineering analysis, cost analysis, and the environmental impact statement (EIS). From the beginning of the program, the DOE has incorporated the environmental considerations into the process of strategy selection. Currently, the DOE has no preferred alternative. The results of the environmental impacts assessment from the EIS, as well as the results from the other components of the program, will be factored into the strategy selection process. In addition to the DOE`s current management plan, other alternatives continued storage, reuse, or disposal of depleted uranium, will be considered in the EIS. The EIS is expected to be completed and issued in its final form in the fall of 1997.

  15. FEASIBILITY STUDY OF DUPOLY TO RECYCLE DEPLETED URANIUM.

    SciTech Connect (OSTI)

    ADAMS,J.W.; LAGERAAEN,P.R.; KALB,P.D.; RUTENKROGER,S.P.

    1998-02-01T23:59:59.000Z

    DUPoly, depleted uranium (DU) powder microencapsulated in a low-density polyethylene binder, has been demonstrated as an innovative and efficient recycle product, a very durable high density material with significant commercial appeal. DUPoly was successfully prepared using uranium tetrafluoride (UF{sub 4}) ''green salt'' obtained from Fluor Daniel-Fernald, a U.S. Department of Energy reprocessing facility near Cincinnati, Ohio. Samples containing up to 90 wt% UF{sub 4} were produced using a single screw plastics extruder, with sample densities of up to 3.97 {+-} 0.08 g/cm{sup 3} measured. Compressive strength of as-prepared samples (50-90 wt% UF4 ) ranged from 1682 {+-} 116 psi (11.6 {+-} 0.8 MPa) to 3145 {+-} 57 psi (21.7 {+-} 0.4 MPa). Water immersion testing for a period of 90 days produced no visible degradation of the samples. Leach rates were low, ranging from 0.02 % (2.74 x 10{sup {minus}6} gm/gm/d) for 50 wt% UF{sub 4} samples to 0.72 % (7.98 x 10{sup {minus}5} gm/gm/d) for 90 wt% samples. Sample strength was not compromised by water immersion. DUPoly samples containing uranium trioxide (UO{sub 3}), a DU reprocessing byproduct material stockpiled at the Savannah River Site, were gamma irradiated to 1 x 10{sup 9} rad with no visible deterioration. Compressive strength increased significantly, however: up to 200% for samples with 90 wt% UO{sub 3}. Correspondingly, percent deformation (strain) at failure was decreased for all samples. Gamma attenuation data on UO{sub 3} DUPoly samples yielded mass attenuation coefficients greater than those for lead. Neutron removal coefficients were calculated and shown to correlate well with wt% of DU. Unlike gamma attenuation, both hydrogenous and nonhydrogenous materials interact to attenuate neutrons.

  16. Proposal concerning the participation of CERN in the procurement of depleted-uranium sheets for the UA1 calorimeter upgrading

    E-Print Network [OSTI]

    1985-01-01T23:59:59.000Z

    Proposal concerning the participation of CERN in the procurement of depleted-uranium sheets for the UA1 calorimeter upgrading

  17. Military use of depleted uranium assessment of prolonged population exposure

    E-Print Network [OSTI]

    Giannardi, C

    2001-01-01T23:59:59.000Z

    This work is an exposure assessment for a population living in an area contaminated by use of depleted uranium (DU) weapons. RESRAD 5.91 code is used to evaluate the average effective dose delivered from 1, 10, 20 cm depths of contaminated soil, in a residential farmer scenario. Critical pathway and group are identified in soil inhalation or ingestion and children playing with the soil, respectively. From available information on DU released on targeted sites, both critical and average exposure can leave to toxicological hazards; annual dose limit for population can be exceeded on short-term period (years) for soil inhalation. As a consequence, in targeted sites cleaning up must be planned on the basis of measured concentration, when available, while special cautions have to be adopted altogether to reduce unaware exposures, taking into account the amount of the avertable dose.

  18. Dupoly process for treatment of depleted uranium and production of beneficial end products

    DOE Patents [OSTI]

    Kalb, Paul D. (Wading River, NY); Adams, Jay W. (Stony Brook, NY); Lageraaen, Paul R. (Seaford, NY); Cooley, Carl R. (Gaithersburg, MD)

    2000-02-29T23:59:59.000Z

    The present invention provides a process of encapsulating depleted uranium by forming a homogenous mixture of depleted uranium and molten virgin or recycled thermoplastic polymer into desired shapes. Separate streams of depleted uranium and virgin or recycled thermoplastic polymer are simultaneously subjected to heating and mixing conditions. The heating and mixing conditions are provided by a thermokinetic mixer, continuous mixer or an extruder and preferably by a thermokinetic mixer or continuous mixer followed by an extruder. The resulting DUPoly shapes can be molded into radiation shielding material or can be used as counter weights for use in airplanes, helicopters, ships, missiles, armor or projectiles.

  19. Attainable Burnup in a LIFE Engine Loaded with Depleted Uranium

    SciTech Connect (OSTI)

    Fratoni, M; Kramer, K J; Latkowski, J F

    2009-11-30T23:59:59.000Z

    The Laser Inertial Fusion-based Energy (LIFE) system uses a laser-based fusion source for electricity production. The (D,T) reaction, beside a pure fusion system, allows the option to drive a sub-critical fission blanket in order to increase the total energy gain. In a typical fusion-fission LIFE engine the fission blanket is a spherical shell around the fusion source, preceded by a beryllium shell for neutron multiplications by means of (n,2n) reactions. The fuel is in the form of TRISO particles dispersed in carbon pebbles, cooled by flibe. The optimal design features 80 cm thick blanket, 16 cm multiplier, and 20% TRISO packing factor. A blanket loaded with depleted uranium and depleted in a single batch with continuous mixing can achieve burnup as high as {approx}85% FIMA while generating 2,000 MW of total thermal power and producing enough tritium to be used for fusion. A multi-segment blanket with a central promotion shuffling scheme enhances burnup to {approx}90% FIMA, whereas a blanket that is operated with continuous refueling achieves only 82% FIMA under the same constraints of thermal power and tritium self-sufficiency. Both, multi-segment and continuous refueling eliminate the need for a fissile breeding phase.

  20. Delayed neutron measurements for Th-232, Np-237, Pu-239, Pu-241 and depleted uranium

    E-Print Network [OSTI]

    Stone, Joseph C.

    2001-01-01T23:59:59.000Z

    The neutron emission rates from five very pure actinide samples (Th-232, Np-237, Pu-239, Pu-241 and depleted uranium) were measured following equilibrium irradiation in fast and thermal neutron fluxes. The relative abundances (alphas) for the first...

  1. DUSCOBS - a depleted-uranium silicate backfill for transport, storage, and disposal of spent nuclear fuel

    SciTech Connect (OSTI)

    Forsberg, C.W.; Pope, R.B.; Ashline, R.C.; DeHart, M.D.; Childs, K.W.; Tang, J.S.

    1995-11-30T23:59:59.000Z

    A Depleted Uranium Silicate COntainer Backfill System (DUSCOBS) is proposed that would use small, isotopically-depleted uranium silicate glass beads as a backfill material inside storage, transport, and repository waste packages containing spent nuclear fuel (SNF). The uranium silicate glass beads would fill all void space inside the package including the coolant channels inside SNF assemblies. Based on preliminary analysis, the following benefits have been identified. DUSCOBS improves repository waste package performance by three mechanisms. First, it reduces the radionuclide releases from SNF when water enters the waste package by creating a local uranium silicate saturated groundwater environment that suppresses (1) the dissolution and/or transformation of uranium dioxide fuel pellets and, hence, (2) the release of radionuclides incorporated into the SNF pellets. Second, the potential for long-term nuclear criticality is reduced by isotopic exchange of enriched uranium in SNF with the depleted uranium (DU) in the glass. Third, the backfill reduces radiation interactions between SNF and the local environment (package and local geology) and thus reduces generation of hydrogen, acids, and other chemicals that degrade the waste package system. In addition, the DUSCOBS improves the integrity of the package by acting as a packing material and ensures criticality control for the package during SNF storage and transport. Finally, DUSCOBS provides a potential method to dispose of significant quantities of excess DU from uranium enrichment plants at potential economic savings. DUSCOBS is a new concept. Consequently, the concept has not been optimized or demonstrated in laboratory experiments.

  2. Summary of the engineering analysis report for the long-term management of depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Dubrin, J.W., Rahm-Crites, L.

    1997-09-01T23:59:59.000Z

    The Department of Energy (DOE) is reviewing ideas for the long-term management and use of its depleted uranium hexafluoride. DOE owns about 560,000 metric tons (over a billion pounds) of depleted uranium hexafluoride. This material is contained in steel cylinders located in storage yards near Paducah, Kentucky; Portsmouth, Ohio; and at the East Tennessee Technology Park (formerly the K-25 Site) in Oak Ridge, Tennessee. On November 10, 1994, DOE announced its new Depleted Uranium Hexafluoride Management Program by issuing a Request for Recommendations and an Advance Notice of Intent in the Federal Register (59 FR 56324 and 56325). The first part of this program consists of engineering, costs and environmental impact studies. Part one will conclude with the selection of a long-term management plan or strategy. Part two will carry out the selected strategy.

  3. Bacterial Community Succession During in situ Uranium Bioremediation: Spatial Similarities Along Controlled Flow Paths

    E-Print Network [OSTI]

    Hwang, Chiachi

    2009-01-01T23:59:59.000Z

    problem, and the use of depleted uranium and other heavyenvironmental hazard. Depleted uranium is weakly radioactive

  4. A comparison of two lung clearance models based on the dissolution rates of oxidized depleted uranium

    E-Print Network [OSTI]

    Crist, Kevin Craig

    1983-01-01T23:59:59.000Z

    by Cuddihy. Predictions fr'om bai. h models based on the dissolution rates of the amount of oxidized depleted uranium that wau'ld be cleared to blood irom the pu lraana ry region i'o'i)owing an i nba !at i cn exposure were compared . It was f:urd ti... to oxidized depleted uranium (DU) aerosol. The ob, ject. ive of th. is i:hesis was three fold: (1) to determine the dissolution rates for two respirable DU samples, (2) to determine the specific pulmonary clearance characteristics of oxidized DU, (3) Co...

  5. Depleted Uranium Hexafluoride Management Program. The technology assessment report for the long-term management of depleted uranium hexafluoride. Volume 1

    SciTech Connect (OSTI)

    Zoller, J.N.; Rosen, R.S.; Holliday, M.A. [and others] [and others

    1995-06-30T23:59:59.000Z

    With the publication of a Request for Recommendations and Advance Notice of Intent in the November 10, 1994 Federal Register, the Department of Energy initiated a program to assess alternative strategies for the long-term management or use of depleted uranium hexafluoride. This Request was made to help ensure that, by seeking as many recommendations as possible, Department management considers reasonable options in the long-range management strategy. The Depleted Uranium Hexafluoride Management Program consists of three major program elements: Engineering Analysis, Cost Analysis, and an Environmental Impact Statement. This Technology Assessment Report is the first part of the Engineering Analysis Project, and assesses recommendations from interested persons, industry, and Government agencies for potential uses for the depleted uranium hexafluoride stored at the gaseous diffusion plants in Paducah, Kentucky, and Portsmouth, Ohio, and at the Oak Ridge Reservation in Tennessee. Technologies that could facilitate the long-term management of this material are also assessed. The purpose of the Technology Assessment Report is to present the results of the evaluation of these recommendations. Department management will decide which recommendations will receive further study and evaluation. These Appendices contain the Federal Register Notice, comments on evaluation factors, independent technical reviewers resumes, independent technical reviewers manual, and technology information packages.

  6. Depleted Uranium Hexafluoride Management Program. The technology assessment report for the long-term management of depleted uranium hexafluoride. Volume 2

    SciTech Connect (OSTI)

    Zoller, J.N.; Rosen, R.S.; Holliday, M.A. [and others] [and others

    1995-06-30T23:59:59.000Z

    With the publication of a Request for Recommendations and Advance Notice of Intent in the November 10, 1994 Federal Register, the Department of Energy initiated a program to assess alternative strategies for the long-term management or use of depleted uranium hexafluoride. This Request was made to help ensure that, by seeking as many recommendations as possible, Department management considers reasonable options in the long-range management strategy. The Depleted Uranium Hexafluoride Management Program consists of three major program elements: Engineering Analysis, Cost Analysis, and an Environmental Impact Statement. This Technology Assessment Report is the first part of the Engineering Analysis Project, and assesses recommendations from interested persons, industry, and Government agencies for potential uses for the depleted uranium hexafluoride stored at the gaseous diffusion plants in Paducah, Kentucky, and Portsmouth, Ohio, and at the Oak Ridge Reservation in Tennessee. Technologies that could facilitate the long-term management of this material are also assessed. The purpose of the Technology Assessment Report is to present the results of the evaluation of these recommendations. Department management will decide which recommendations will receive further study and evaluation.

  7. D0 Decomissioning : Storage of Depleted Uranium Modules Inside D0 Calorimeters after the Termination of D0 Experiment

    SciTech Connect (OSTI)

    Sarychev, Michael; /Fermilab

    2011-09-21T23:59:59.000Z

    Dzero liquid Argon calorimeters contain hadronic modules made of depleted uranium plates. After the termination of DO detector's operation, liquid Argon will be transferred back to Argon storage Dewar, and all three calorimeters will be warmed up. At this point, there is no intention to disassemble the calorimeters. The depleted uranium modules will stay inside the cryostats. Depleted uranium is a by-product of the uranium enrichment process. It is slightly radioactive, emits alpha, beta and gamma radiation. External radiation hazards are minimal. Alpha radiation has no external exposure hazards, as dead layers of skin stop it; beta radiation might have effects only when there is a direct contact with skin; and gamma rays are negligible - levels are extremely low. Depleted uranium is a pyrophoric material. Small particles (such as shavings, powder etc.) may ignite with presence of Oxygen (air). Also, in presence of air and moisture it can oxidize. Depleted uranium can absorb moisture and keep oxidizing later, even after air and moisture are excluded. Uranium oxide can powder and flake off. This powder is also pyrographic. Uranium oxide may create health problems if inhaled. Since uranium oxide is water soluble, it may enter the bloodstream and cause toxic effects.

  8. Uranium Ore Uranium is extracted

    E-Print Network [OSTI]

    Milling of Uranium Ore Uranium is extracted from ore with strong acids or bases. The uranium is concentrated in a solid substance called"yellowcake." Chemical Conversion Plants convert the uranium in yellowcake to uranium hexafluoride (UF6 ), a compound that can be made into nuclear fuel. Enrichment

  9. BLENDING LOW ENRICHED URANIUM WITH DEPLETED URANIUM TO CREATE A SOURCE MATERIAL ORE THAT CAN BE PROCESSED FOR THE RECOVERY OF YELLOWCAKE AT A CONVENTIONAL URANIUM MILL

    SciTech Connect (OSTI)

    Schutt, Stephen M.; Hochstein, Ron F.; Frydenlund, David C.; Thompson, Anthony J.

    2003-02-27T23:59:59.000Z

    Throughout the United States Department of Energy (DOE) complex, there are a number of streams of low enriched uranium (LEU) that contain various trace contaminants. These surplus nuclear materials require processing in order to meet commercial fuel cycle specifications. To date, they have not been designated as waste for disposal at the DOE's Nevada Test Site (NTS). Currently, with no commercial outlet available, the DOE is evaluating treatment and disposal as the ultimate disposition path for these materials. This paper will describe an innovative program that will provide a solution to DOE that will allow disposition of these materials at a cost that will be competitive with treatment and disposal at the NTS, while at the same time recycling the material to recover a valuable energy resource (yellowcake) for reintroduction into the commercial nuclear fuel cycle. International Uranium (USA) Corporation (IUSA) and Nuclear Fuel Services, Inc. (NFS) have entered into a commercial relationship to pursue the development of this program. The program involves the design of a process and construction of a plant at NFS' site in Erwin, Tennessee, for the blending of contaminated LEU with depleted uranium (DU) to produce a uranium source material ore (USM Ore{trademark}). The USM Ore{trademark} will then be further processed at IUC's White Mesa Mill, located near Blanding, Utah, to produce conventional yellowcake, which can be delivered to conversion facilities, in the same manner as yellowcake that is produced from natural ores or other alternate feed materials. The primary source of feed for the business will be the significant sources of trace contaminated materials within the DOE complex. NFS has developed a dry blending process (DRYSM Process) to blend the surplus LEU material with DU at its Part 70 licensed facility, to produce USM Ore{trademark} with a U235 content within the range of U235 concentrations for source material. By reducing the U235 content to source material levels in this manner, the material will be suitable for processing at a conventional uranium mill under its existing Part 40 license to remove contaminants and enable the product to re-enter the commercial fuel cycle. The tailings from processing the USM Ore{trademark} at the mill will be permanently disposed of in the mill's tailings impoundment as 11e.(2) byproduct material. Blending LEU with DU to make a uranium source material ore that can be returned to the nuclear fuel cycle for processing to produce yellowcake, has never been accomplished before. This program will allow DOE to disposition its surplus LEU and DU in a cost effective manner, and at the same time provide for the recovery of valuable energy resources that would be lost through processing and disposal of the materials. This paper will discuss the nature of the surplus LEU and DU materials, the manner in which the LEU will be blended with DU to form a uranium source material ore, and the legal means by which this blending can be accomplished at a facility licensed under 10 CFR Part 70 to produce ore that can be processed at a conventional uranium mill licensed under 10 CFR Part 40.

  10. EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site

    Broader source: Energy.gov [DOE]

    This site-specific EIS analyzes the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three alternative locations within the Paducah site; transportation of all cylinders (DUF6, enriched, and empty) currently stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Portsmouth; construction of a new cylinder storage yard at Portsmouth (if required) for ETTP cylinders; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as a conversion coproduct; and neutralization of HF to calcium fluoride and its sale or disposal in the event that the HF product is not sold.

  11. WISE Uranium Project - Fact Sheet

    E-Print Network [OSTI]

    Hazards From Depleted

    t in the depleted uranium. For this purpose, we first need to calculate the mass balance of the enrichment process. We then calculate the inhalation doses from the depleted uranium and compare the dose contributions from the nuclides of interest. Mass balance for uranium enrichment at Paducah [DOE_1984, p.35] Feed Product Tails Other Mass [st] 758002 124718 621894 11390 Mass fraction 100.00% 16.45% 82.04% 1.50% Concentration of plutonium in tails (depleted uranium) from enrichment of reprocessed uranium, assuming that all plutonium were transfered to the tails: Concentration of neptunium in tails from enrichment of reprocessed uranium uranium, assuming that all neptunium were transfered to the tails: - 2 - Schematic of historic uranium enrichment process at Paducah [DOE_1999b] - -7 For comparison, we first calculate the inhalation dose from depleted uranium produced from natural uranium. We assume that the short-lived decay products have reached secular equilibrium with th

  12. Bacterial Community Succession During in situ Uranium Bioremediation: Spatial Similarities Along Controlled Flow Paths

    E-Print Network [OSTI]

    Hwang, Chiachi

    2009-01-01T23:59:59.000Z

    problem, and the use of depleted uranium and other heavyenvironmental hazard. Depleted uranium is weakly radioactiveMB. (2004). Depleted and natural uranium: chemistry and

  13. Use of depleted uranium metal as cask shielding in high-level waste storage, transport, and disposal systems

    SciTech Connect (OSTI)

    Yoshimura, H.R.; Ludwigsen, J.S.; McAllaster, M.E. [and others

    1996-09-01T23:59:59.000Z

    The US DOE has amassed over 555,000 metric tons of depleted uranium from its uranium enrichment operations. Rather than dispose of this depleted uranium as waste, this study explores a beneficial use of depleted uranium as metal shielding in casks designed to contain canisters of vitrified high-level waste. Two high-level waste storage, transport, and disposal shielded cask systems are analyzed. The first system employs a shielded storage and disposal cask having a separate reusable transportation overpack. The second system employs a shielded combined storage, transport, and disposal cask. Conceptual cask designs that hold 1, 3, 4 and 7 high-level waste canisters are described for both systems. In all cases, cask design feasibility was established and analyses indicate that these casks meet applicable thermal, structural, shielding, and contact-handled requirements. Depleted uranium metal casting, fabrication, environmental, and radiation compatibility considerations are discussed and found to pose no serious implementation problems. About one-fourth of the depleted uranium inventory would be used to produce the casks required to store and dispose of the nearly 15,400 high-level waste canisters that would be produced. This study estimates the total-system cost for the preferred 7-canister storage and disposal configuration having a separate transportation overpack would be $6.3 billion. When credits are taken for depleted uranium disposal cost, a cost that would be avoided if depleted uranium were used as cask shielding material rather than disposed of as waste, total system net costs are between $3.8 billion and $5.5 billion.

  14. Controlling uranium reactivity March 18, 2008

    E-Print Network [OSTI]

    Meyer, Karsten

    for the last decade. Most of their work involves depleted uranium, a more common form of uraniumMarch 2008 Controlling uranium reactivity March 18, 2008 Uranium is an often misunderstood metal uranium research. In reality, uranium presents a wealth of possibilities for funda- mental chemistry. Many

  15. Proposal for the award of a contract for the supply of 5 mm depleted-uranium plates for the UA1 calorimeter upgrading

    E-Print Network [OSTI]

    1986-01-01T23:59:59.000Z

    Proposal for the award of a contract for the supply of 5 mm depleted-uranium plates for the UA1 calorimeter upgrading

  16. Proposal for the award of a contract for the supply of 5 mm depleted-uranium plates for the UA1 experiment

    E-Print Network [OSTI]

    1986-01-01T23:59:59.000Z

    Proposal for the award of a contract for the supply of 5 mm depleted-uranium plates for the UA1 experiment

  17. Incentives for the use of depleted uranium alloys as transport cask containment structure

    SciTech Connect (OSTI)

    McConnell, P [GRAM, Inc., Albuquerque, NM (United States); Salzbrenner, R; Wellman, G W; Sorenson, K B [Sandia National Labs., Albuquerque, NM (United States)

    1992-01-01T23:59:59.000Z

    Radioactive material transport casks use either lead or depleted uranium (DU) as gamma-ray shielding material. Stainless steel is conventionally used for structural containment. If a DU alloy had sufficient properties to guarantee resistance to failure during both nominal use and accident conditions to serve the dual-role of shielding and containment, the use of other structure materials (i.e., stainless steel) could be reduced. (It is recognized that lead can play no structural role.) Significant reductions in cask weight and dimensions could then be achieved perhaps allowing an increase in payload. The mechanical response of depleted uranium has previously not been included in calculations intended to show that DU-shielded transport casks will maintain their containment function during all conditions. This paper describesa two-part study of depleted uranium alloys: First, the mechanical behavior of DU alloys was determined in order to extend the limited set of mechanical properties reported in the literature. The mechanical properties measured include the tensile behavior the impact energy. Fracture toughness testing was also performed to determine the sensitivity of DU alloys to brittle fracture. Fracture toughness is the inherent material property which quantifies the fracmm resistance of a material. Tensile strength and ductility are significant in terms of other failure modes, however, as win be discussed. These mechanical properties were then input into finite element calculations of cask response to loading conditions to quantify the potential for claiming structural credit for DU. (The term structural credit'' describes whether a material has adequate properties to allow it to assume a positive role in withstanding structural loadings.)

  18. Assessing the risk from the depleted uranium weapons used in Operation Allied Force

    E-Print Network [OSTI]

    Liolios, T E

    1999-01-01T23:59:59.000Z

    The conflict in Yugoslavia has been a source of great concern for the neighboring countries, about the radiological and toxic hazard posed by the alleged presence of depleted uranium in NATO weapons. In the present study a worst-case scenario is assumed mainly to assess the risk for Greece and other neighboring countries of Yugoslavia at similar distances . The risk of the weapons currently in use is proved to be negligible at distances greater than 100 Km. For shorter distances classified data of weapons composition are needed to obtain a reliable assessment.

  19. Depleted uranium hexafluoride (DUF{sub 6}) management system--a decision tool

    SciTech Connect (OSTI)

    Gasper, J.R.; Sutter, R.J.; Avci, H.I. [and others

    1995-12-31T23:59:59.000Z

    The Depleted Uranium Hexafluoride (DUF{sub 6}) Management System (DMS) is being developed as a decision tool to provide cost and risk data for evaluation of short-and long-term management strategies for depleted uranium. It can be used to assist decision makers on a programmatic or site-specific level. Currently, the DMS allows evaluation of near-term cylinder management strategies such as storage yard improvements, cylinder restocking, and reconditioning. The DMS has been designed to provide the user with maximum flexibility for modifying data and impact factors (e.g., unit costs and risk factors). Sensitivity analysis can be performed on all key parameters such as cylinder corrosion rate, inspection frequency, and impact factors. Analysis may be conducted on a system-wide, site, or yard basis. The costs and risks from different scenarios may be compared in graphic or tabular format. Ongoing development of the DMS will allow similar evaluation of long-term management strategies such as conversion to other chemical forms. The DMS is a Microsoft Windows 3.1 based, stand-alone computer application. It can be operated on a 486 or faster computer with VGA, 4 MB of RAM, and 10 MB of disk space.

  20. Summary of the cost analysis report for the long-term management of depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Dubrin, J.W.; Rahm-Crites, L.

    1997-09-01T23:59:59.000Z

    This report is a summary of the Cost Analysis Report which provides comparative cost data for the management strategy alternatives. The PEIS and the Cost Analysis Report will help DOE select a management strategy. The Record of Decision, expected in 1998, will complete the first part of the Depleted Uranium Hexafluoride Management Program. The second part of the Program will look at specific sites and technologies for carrying out the selected strategy. The Cost Analysis Report estimates the primary capital and operating costs for the different alternatives. It reflects the costs of technology development construction of facilities, operation, and decontamination and decommissioning. It also includes potential revenues from the sale of by-products such as anhydrous hydrogen fluoride (ABF). These estimates are based on early designs. They are intended to help in comparing alternatives, rather than to indicate absolute costs for project budgets or bidding purposes. More detailed estimates and specific funding sources will be considered in part two of the Depleted Uranium Hexafluoride Management Program.

  1. Packaging and Disposal of a Radium-beryllium Source using Depleted Uranium Polyethylene Composite Shielding

    SciTech Connect (OSTI)

    Keith Rule; Paul Kalb; Pete Kwaschyn

    2003-02-11T23:59:59.000Z

    Two, 111-GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from the Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (depleted uranium and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

  2. ZPR-3 Assembly 11 : A cylindrical sssembly of highly enriched uranium and depleted uranium with an average {sup 235}U enrichment of 12 atom % and a depleted uranium reflector.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D.; Tsiboulia, A.; Rozhikhin, Y.; National Security; Inst. of Physics and Power Engineering

    2010-09-30T23:59:59.000Z

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 11 (ZPR-3/11) was designed as a fast reactor physics benchmark experiment with an average core {sup 235}U enrichment of approximately 12 at.% and a depleted uranium reflector. Approximately 79.7% of the total fissions in this assembly occur above 100 keV, approximately 20.3% occur below 100 keV, and essentially none below 0.625 eV - thus the classification as a 'fast' assembly. This assembly is Fast Reactor Benchmark No. 8 in the Cross Section Evaluation Working Group (CSEWG) Benchmark Specificationsa and has historically been used as a data validation benchmark assembly. Loading of ZPR-3 Assembly 11 began in early January 1958, and the Assembly 11 program ended in late January 1958. The core consisted of highly enriched uranium (HEU) plates and depleted uranium plates loaded into stainless steel drawers, which were inserted into the central square stainless steel tubes of a 31 x 31 matrix on a split table machine. The core unit cell consisted of two columns of 0.125 in.-wide (3.175 mm) HEU plates, six columns of 0.125 in.-wide (3.175 mm) depleted uranium plates and one column of 1.0 in.-wide (25.4 mm) depleted uranium plates. The length of each column was 10 in. (254.0 mm) in each half of the core. The axial blanket consisted of 12 in. (304.8 mm) of depleted uranium behind the core. The thickness of the depleted uranium radial blanket was approximately 14 in. (355.6 mm), and the length of the radial blanket in each half of the matrix was 22 in. (558.8 mm). The assembly geometry approximated a right circular cylinder as closely as the square matrix tubes allowed. According to the logbook and loading records for ZPR-3/11, the reference critical configuration was loading 10 which was critical on January 21, 1958. Subsequent loadings were very similar but less clean for criticality because there were modifications made to accommodate reactor physics measurements other than criticality. Accordingly, ZPR-3/11 loading 10 was selected as the only configuration for this benchmark. As documented below, it was determined to be acceptable as a criticality safety benchmark experiment. A very accurate transformation to a simplified model is needed to make any ZPR assembly a practical criticality-safety benchmark. There is simply too much geometric detail in an exact (as-built) model of a ZPR assembly, even a clean core such as ZPR-3/11 loading 10. The transformation must reduce the detail to a practical level without masking any of the important features of the critical experiment. And it must do this without increasing the total uncertain

  3. URANIUM MILLING ACTIVITIES AT SEQUOYAH FUELS CORPORATION

    E-Print Network [OSTI]

    unknown authors

    Sequoyah Fuels Corporation (SFC) describes previous operations at its Gore, Oklahoma, uranium conversion facility as: (1) the recovery of uranium by concentration and purification processes; and (2) the conversion of concentrated and purified uranium ore into uranium hexafluoride (UF 6), or the reduction of depleted uranium tetrafluoride (UF 4) to UF 6. SFC contends that these

  4. Safe Operating Procedure SAFETY PROTOCOL: URANIUM

    E-Print Network [OSTI]

    Farritor, Shane

    involve the use of natural or depleted uranium. Natural isotopes of uranium are U-238, U-235 and U-234 (see Table 1 for natural abundances). Depleted uranium contains less of the isotopes: U-235 and U-234. The specific activity of depleted uranium (5.0E-7 Ci/g) is less than that of natural uranium (7.1E-7 Ci

  5. Characterization of Alpha-Phase Sintering of Uranium and Uranium-Zirconium Alloys for Advanced Nuclear Fuel Applications

    E-Print Network [OSTI]

    Helmreich, Grant

    2012-02-14T23:59:59.000Z

    The sintering behavior of uranium and uranium-zirconium alloys in the alpha phase were characterized in this research. Metal uranium powder was produced from pieces of depleted uranium metal acquired from the Y-12 plant via hydriding...

  6. Determination of Depleted Uranium in Environmental Bio-monitor Samples and Soil from Target sites in Western Balkan Region

    SciTech Connect (OSTI)

    Sahoo, Sarata K.; Enomoto, Hiroko; Tokonami, Shinji; Ishikawa, Tetsuo [National Institute of Radiological Sciences, 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan); Ujic, Predrag; Celikovic, Igor; Zunic, Zora S. [Institute of Nuclear Sciences, Vinca, Mike Petrovica Alasa 12-14, 11000 Belgrade (Serbia)

    2008-08-07T23:59:59.000Z

    Lichen and Moss are widely used to assess the atmospheric pollution by heavy metals and radionuclides. In this paper, we report results of uranium and its isotope ratios using mass spectrometric measurements (followed by chemical separation procedure) for mosses, lichens and soil samples from a depleted uranium (DU) target site in western Balkan region. Samples were collected in 2003 from Han Pijesak (Republika Srpska in Bosnia and Hercegovina). Inductively coupled plasma mass spectrometry (ICP-MS) measurements show the presence of high concentration of uranium in some samples. Concentration of uranium in moss samples ranged from 5.2-755.43 Bq/Kg. We have determined {sup 235}U/{sup 238}U isotope ratio using thermal ionization mass spectrometry (TIMS) from the samples with high uranium content and the ratios are in the range of 0.002097-0.002380. TIMS measurement confirms presence of DU in some samples. However, we have not noticed any traces of DU in samples containing lesser amount of uranium or from any samples from the living environment of same area.

  7. Using Hydro-Cutting to Aid in Remediation of a Firing Range Contaminated with Depleted Uranium

    SciTech Connect (OSTI)

    Styvaert, Michael S.; Conley, Richard D.; Watters, David J.

    2003-02-24T23:59:59.000Z

    This paper describes the challenges encountered in decommissioning a firing range that had been used to test fire depleted uranium rounds in the late 1950's and early 1960's. The paper details the operational challenges and innovative solutions involved in remediating and decommissioning a firing range bullet catcher once unexploded ordnance was discovered. It also discusses how the Army dealt with an intertwining web of regulatory and permit issues that arose in treating and disposing of multiple waste streams. The paper will show how the use of a Resource Conservation and Recovery Act (RCRA) Temporary Authorization allowed the Army to deal with the treatment of a variety of waste streams and how hydro-cutting process was used to demilitarize the potentially unexploded rounds.

  8. Remediation application strategies for depleted uranium contaminated soils at the US Army Yuma Proving Ground

    SciTech Connect (OSTI)

    Vandel, D.S.; Medina, S.M.; Weidner, J.R.

    1994-03-01T23:59:59.000Z

    The US Army Yuma Proving Ground (YPG), located in the southwest portion of Arizona conducts firing of projectiles into the Gunpoint (GP-20) firing range. The penetrators are composed of titanium and DU. The purpose of this project was to determine feasible cleanup technologies and disposal alternatives for the cleanup of the depleted uranium (DU) contaminated soils at YPG. The project was split up into several tasks that include (a) collecting and analyzing samples representative of the GP-20 soils, (b) evaluating the data results, (c) conducting a literature search of existing proven technologies for soil remediation, and (0) making final recommendations for implementation of this technology to the site. As a result of this study, several alternatives for the separation, treatment, and disposal procedures are identified that would result in meeting the cleanup levels defined by the Nuclear Regulatory Commission for unrestricted use of soils and would result in a significant cost savings over the life of the firing range.

  9. Uranium industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-04-01T23:59:59.000Z

    This report provides statistical data on the U.S. uranium industry`s activities relating to uranium raw materials and uranium marketing.

  10. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    Greenland," in Uranium Exploration Geology, Int. AtomicOklahoma," 1977 Nure Geology Uranium Symposium, Igneous HostMcNeil, M. , 1977. "Geology of Brazil's Uranium and Thorium

  11. Long-term criticality control in radioactive waste disposal facilities using depleted uranium

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1997-02-19T23:59:59.000Z

    Plant photosynthesis has created a unique planetary-wide geochemistry - an oxidizing atmosphere with oxidizing surface waters on a planetary body with chemically reducing conditions near or at some distance below the surface. Uranium is four orders of magnitude more soluble under chemically oxidizing conditions than it is under chemically reducing conditions. Thus, uranium tends to leach from surface rock and disposal sites, move with groundwater, and concentrate where chemically reducing conditions appear. Earth`s geochemistry concentrates uranium and can separate uranium from all other elements except oxygen, hydrogen (in water), and silicon (silicates, etc). Fissile isotopes include {sup 235}U, {sup 233}U, and many higher actinides that eventually decay to one of these two uranium isotopes. The potential for nuclear criticality exists if the precipitated uranium from disposal sites has a significant fissile enrichment, mass, and volume. The earth`s geochemistry suggests that isotopic dilution of fissile materials in waste with {sup 238}U is a preferred strategy to prevent long-term nuclear criticality in and beyond the boundaries of waste disposal facilities because the {sup 238}U does not separate from the fissile uranium isotopes. Geological, laboratory, and theoretical data indicate that the potential for nuclear criticality can be minimized by diluting fissile materials with-{sup 238}U to 1 wt % {sup 235}U equivalent.

  12. Control of structure and reactivity by ligand design : applications to small molecule activation by low-valent uranium complexes

    E-Print Network [OSTI]

    Lam, Oanh Phi

    2010-01-01T23:59:59.000Z

    coordination chemistry is depleted uranium, a by-product innuclear reactors. Depleted uranium Figure 1-1. The periodic

  13. Advancing Performance Assessment for Disposal of Depleted Uranium at Clive Utah - 12493

    SciTech Connect (OSTI)

    Black, Paul; Tauxe, John; Perona, Ralph; Lee, Robert; Catlett, Kate; Balshi, Mike; Fitzgerald, Mark; McDermott, Greg [Neptune and Company, Inc., Los Alamos, New Mexico 87544 (United States); Shrum, Dan; McCandless, Sean; Sobocinski, Robert; Rogers, Vern [EnergySolutions, LLC, Salt Lake City, Utah 84101 (United States)

    2012-07-01T23:59:59.000Z

    A Performance Assessment (PA) for disposal of depleted uranium (DU) waste has recently been completed for a potential disposal facility at Clive in northwestern Utah. For the purposes of this PA, 'DU waste' includes uranium oxides of all naturally-occurring isotopes, though depleted in U-235, varying quantities of other radionuclides introduced to the uranium enrichment process in the form of used nuclear reactor fuel (reactor returns), and decay products of all of these radionuclides. The PA will be used by the State of Utah to inform an approval decision for disposal of DU waste at the facility, and will be available to federal regulators as they revisit rulemaking for the disposal of DU. The specific performance objectives of the Clive DU PA relate to annual individual radiation dose within a 10,000-year performance period, groundwater concentrations of specific radionuclides within a 500-year compliance period, and site stability in the longer term. Fate and transport processes that underlie the PA model include radioactive decay and ingrowth, diffusion in gaseous and water phases, water advection in unsaturated and saturated zones, transport caused by plant and animal activity, cover naturalization, natural and anthropogenic erosion, and air dispersion. Fate and transport models were used to support the dose assessment and the evaluation of groundwater concentrations. Exposure assessment was based on site-specific scenarios, since the traditional human exposure scenarios suggested by DOE and NRC guidance are unrealistic for this site. Because the U-238 in DU waste reaches peak radioactivity (secular equilibrium) after 2 million years (My) following its separation, the PA must also evaluate the impact of climate change cycles, including the return of pluvial lakes such as Lake Bonneville. The first draft of the PA has been submitted to the State of Utah for review. The results of this preliminary analysis indicate that doses are very low for the site-specific receptors for the 10,000-year compliance period. This is primarily because DU waste is not highly radioactive within this time frame, the DU waste is assumed to be buried beneath zones exposed by erosion, groundwater concentrations of DU waste constituents do not exceed groundwater protection limits with in the 500-year compliance period, and the first deep lake occurrence will disperse DU waste across a large area, and will ultimately be covered by lake-derived sediment. A probabilistic PA model was constructed that considered DU waste and decay product doses to site-specific receptors for a 10,000-yr performance period, as well as deep-time effects. The quantitative results are summarized in Table VII. Doses (as TEDE) are always less than 5 mSv in a year, and doses to the offsite receptors are always much less than 0.25 mSv in a year. Groundwater concentrations of Tc-99 are always less than its GWPL except when the Tc-99 contaminated waste is disposed below grade. Even in this case, the median groundwater concentration is only 4.18 Bq/L (113 pCi/L), which is more than one order of magnitude less than the GWPL for Tc-99. The results overall suggest that there are disposal configurations that can be used to dispose of the proposed quantities of DU waste that are adequately protective of human health. (authors)

  14. ZPR-3 Assembly 6F : A spherical assembly of highly enriched uranium, depleted uranium, aluminum and steel with an average {sup 235}U enrichment of 47 atom %.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D; Schaefer, R. W.; Nuclear Engineering Division

    2010-09-30T23:59:59.000Z

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 6 consisted of six phases, A through F. In each phase a critical configuration was constructed to simulate a very simple shape such as a slab, cylinder or sphere that could be analyzed with the limited analytical tools available in the 1950s. In each case the configuration consisted of a core region of metal plates surrounded by a thick depleted uranium metal reflector. The average compositions of the core configurations were essentially identical in phases A - F. ZPR-3 Assembly 6F (ZPR-3/6F), the final phase of the Assembly 6 program, simulated a spherical core with a thick depleted uranium reflector. ZPR-3/6F was designed as a fast reactor physics benchmark experiment with an average core {sup 235}U enrichment of approximately 47 at.%. Approximately 81.4% of the total fissions in this assembly occur above 100 keV, approximately 18.6% occur below 100 keV, and essentially none below 0.625 eV - thus the classification as a 'fast' assembly. This assembly is Fast Reactor Benchmark No. 7 in the Cross Section Evaluation Working Group (CSEWG) Benchmark Specifications and has historically been used as a data validation benchmark assembly. Loading of ZPR-3/6F began in late December 1956, and the experimental measurements were performed in January 1957. The core consisted of highly enriched uranium (HEU) plates, depleted uranium plates, perforated aluminum plates and stainless steel plates loaded into aluminum drawers, which were inserted into the central square stainless steel tubes of a 31 x 31 matrix on a split table machine. The core unit cell consisted of three columns of 0.125 in.-wide (3.175 mm) HEU plates, three columns of 0.125 in.-wide depleted uranium plates, nine columns of 0.125 in.-wide perforated aluminum plates and one column of stainless steel plates. The maximum length of each column of core material in a drawer was 9 in. (228.6 mm). Because of the goal to produce an approximately spherical core, core fuel and diluent column lengths generally varied between adjacent drawers and frequently within an individual drawer. The axial reflector consisted of depleted uranium plates and blocks loaded in the available space in the front (core) drawers, with the remainder loaded into back drawers behind the front drawers. The radial reflector consisted of blocks of depleted uranium loaded directly into the matrix tubes. The assembly geometry approximated a reflected sphere as closely as the square matrix tubes, the drawers and the shapes of fuel and diluent plates allowed. According to the logbook and loading records for ZPR-3/6F

  15. Determination of Young's modulus and mechanical damping as a function of temperature for depleted uranium-0.75 wt% titanium using the PUCOT

    E-Print Network [OSTI]

    Keene, Keith Howard

    1986-01-01T23:59:59.000Z

    DETERMINATION OF YOUNG'S MODULUS AND MECHANICAL DAMPING AS A FUNCTION OF TEMPERATURE FOR DEPLETED URANIUM-0. 75 WT% TITANIUM USING THE PUCOT A Thesis bY KEITH HOWARD KEENE Submitted to the Graduate College of Texas A&M University in partial... fulfillment of requirements for the degree of MASTER OF SCIENCE May 1986 Major Subject: Mechanical Engineerinq DETERMINATION OF YOUNG'S MODULUS AND MECHANICAL DAMPING AS A FUNCTION OF TEMPERATURE FOR DEPLETED URANIUM-0. 75 WT% TITANIUM USING THE PUCOT A...

  16. Modeling exposure to depleted uranium in support of decommissioning at Jefferson Proving Ground, Indiana

    SciTech Connect (OSTI)

    Ebinger, M.H. [Los Alamos National Lab., NM (United States); Oxenburg, T.P. [Army Test and Evaluation Command, Aberdeen Proving Ground, MD (United States)

    1997-02-01T23:59:59.000Z

    Jefferson Proving Ground was used by the US Army Test and Evaluation Command for testing of depleted uranium munitions and closed in 1995 under the Base Realignment and Closure Act. As part of the closure of JPG, assessments of potential adverse health effects to humans and the ecosystem were conducted. This paper integrates recent information obtained from site characterization surveys at JPG with environmental monitoring data collected from 1983 through 1994 during DU testing. Three exposure scenarios were evaluated for potential adverse effects to human health: an occasional use scenario and two farming scenarios. Human exposure was minimal from occasional use, but significant risk were predicted from the farming scenarios when contaminated groundwater was used by site occupants. The human health risk assessments do not consider the significant risk posed by accidents with unexploded ordnance. Exposures of white-tailed deer to DU were also estimated in this study, and exposure rates result in no significant increase in either toxicological or radiological risks. The results of this study indicate that remediation of the DU impact area would not substantially reduce already low risks to humans and the ecosystem, and that managed access to JPG is a reasonable model for future land use options.

  17. Proceedings of a workshop on uses of depleted uranium in storage, transportation and repository facilities

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    A workshop on the potential uses of depleted uranium (DU) in the repository was organized to coordinate the planning of future activities. The attendees, the original workshop objective and the agenda are provided in Appendices A, B and C. After some opening remarks and discussions, the objectives of the workshop were revised to: (1) exchange information and views on the status of the Department of Energy (DOE) activities related to repository design and planning; (2) exchange information on DU management and planning; (3) identify potential uses of DU in the storage, transportation, and disposal of high-level waste and spent fuel; and (4) define the future activities that would be needed if potential uses were to be further evaluated and developed. This summary of the workshop is intended to be an integrated resource for planning of any future work related to DU use in the repository. The synopsis of the first day`s presentations is provided in Appendix D. Copies of slides from each presenter are presented in Appendix E.

  18. PACKAGING AND DISPOSAL OF A RADIUM BERYLLIUM SOURCE USING DEPLETED URANIUM POLYETHYLENE COMPOSITE SHIELDING.

    SciTech Connect (OSTI)

    RULE,K.; KALB,P.; KWASCHYN,P.

    2003-02-23T23:59:59.000Z

    Two, 111 GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (DU and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

  19. Evaluation of depleted uranium in the environment at Aberdeen Proving Grounds, Maryland and Yuma Proving Grounds, Arizona. Final report

    SciTech Connect (OSTI)

    Kennedy, P.L.; Clements, W.H.; Myers, O.B.; Bestgen, H.T.; Jenkins, D.G. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Fishery and Wildlife Biology

    1995-01-01T23:59:59.000Z

    This report represents an evaluation of depleted uranium (DU) introduced into the environment at the Aberdeen Proving Grounds (APG), Maryland and Yuma Proving Grounds (YPG) Arizona. This was a cooperative project between the Environmental Sciences and Statistical Analyses Groups at LANL and with the Department of Fishery and Wildlife Biology at Colorado State University. The project represents a unique approach to assessing the environmental impact of DU in two dissimilar ecosystems. Ecological exposure models were created for each ecosystem and sensitivity/uncertainty analyses were conducted to identify exposure pathways which were most influential in the fate and transport of DU in the environment. Research included field sampling, field exposure experiment, and laboratory experiments. The first section addresses DU at the APG site. Chapter topics include bioenergetics-based food web model; field exposure experiments; bioconcentration by phytoplankton and the toxicity of U to zooplankton; physical processes governing the desorption of uranium from sediment to water; transfer of uranium from sediment to benthic invertebrates; spead of adsorpion by benthic invertebrates; uptake of uranium by fish. The final section of the report addresses DU at the YPG site. Chapters include the following information: Du transport processes and pathway model; field studies of performance of exposure model; uptake and elimination rates for kangaroo rates; chemical toxicity in kangaroo rat kidneys.

  20. Uranium industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-04-01T23:59:59.000Z

    The Uranium Industry Annual 1996 (UIA 1996) provides current statistical data on the US uranium industry`s activities relating to uranium raw materials and uranium marketing. The UIA 1996 is prepared for use by the Congress, Federal and State agencies, the uranium and nuclear electric utility industries, and the public. Data on uranium raw materials activities for 1987 through 1996 including exploration activities and expenditures, EIA-estimated reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities for 1994 through 2006, including purchases of uranium and enrichment services, enrichment feed deliveries, uranium fuel assemblies, filled and unfilled market requirements, uranium imports and exports, and uranium inventories are shown in Chapter 2. A feature article, The Role of Thorium in Nuclear Energy, is included. 24 figs., 56 tabs.

  1. Uranium Acquisition | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Interest (EOI) to acquire up to 6,800 metric tons of Uranium (MTU) of high purity depleted uranium metal (DU) and related material and services. This request for EOI does...

  2. Hydrologic transport of depleted uranium associated with open air dynamic range testing at Los Alamos National Laboratory, New Mexico, and Eglin Air Force Base, Florida

    SciTech Connect (OSTI)

    Becker, N.M. [Los Alamos National Lab., NM (United States); Vanta, E.B. [Wright Laboratory Armament Directorate, Eglin Air Force Base, FL (United States)

    1995-05-01T23:59:59.000Z

    Hydrologic investigations on depleted uranium fate and transport associated with dynamic testing activities were instituted in the 1980`s at Los Alamos National Laboratory and Eglin Air Force Base. At Los Alamos, extensive field watershed investigations of soil, sediment, and especially runoff water were conducted. Eglin conducted field investigations and runoff studies similar to those at Los Alamos at former and active test ranges. Laboratory experiments complemented the field investigations at both installations. Mass balance calculations were performed to quantify the mass of expended uranium which had transported away from firing sites. At Los Alamos, it is estimated that more than 90 percent of the uranium still remains in close proximity to firing sites, which has been corroborated by independent calculations. At Eglin, we estimate that 90 to 95 percent of the uranium remains at test ranges. These data demonstrate that uranium moves slowly via surface water, in both semi-arid (Los Alamos) and humid (Eglin) environments.

  3. Uranium Industry Annual, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-28T23:59:59.000Z

    The Uranium Industry Annual provides current statistical data on the US uranium industry for the Congress, Federal and State agencies, the uranium and electric utility industries, and the public. The feature article, ``Decommissioning of US Conventional Uranium Production Centers,`` is included. Data on uranium raw materials activities including exploration activities and expenditures, resources and reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities including domestic uranium purchases, commitments by utilities, procurement arrangements, uranium imports under purchase contracts and exports, deliveries to enrichment suppliers, inventories, secondary market activities, utility market requirements, and uranium for sale by domestic suppliers are presented in Chapter 2.

  4. ZPR-3 Assembly 12 : A cylindrical assembly of highly enriched uranium, depleted uranium and graphite with an average {sup 235}U enrichment of 21 atom %.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D.; Perel, R. L.; Wagschal, J. J.; Nuclear Engineering Division; Racah Inst. of Physics

    2010-09-30T23:59:59.000Z

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 12 (ZPR-3/12) was designed as a fast reactor physics benchmark experiment with an average core {sup 235}U enrichment of approximately 21 at.%. Approximately 68.9% of the total fissions in this assembly occur above 100 keV, approximately 31.1% occur below 100 keV, and essentially none below 0.625 eV - thus the classification as a 'fast' assembly. This assembly is Fast Reactor Benchmark No. 9 in the Cross Section Evaluation Working Group (CSEWG) Benchmark Specifications and has historically been used as a data validation benchmark assembly. Loading of ZPR-3 Assembly 12 began in late Jan. 1958, and the Assembly 12 program ended in Feb. 1958. The core consisted of highly enriched uranium (HEU) plates, depleted uranium plates and graphite plates loaded into stainless steel drawers which were inserted into the central square stainless steel tubes of a 31 x 31 matrix on a split table machine. The core unit cell consisted of two columns of 0.125 in.-wide (3.175 mm) HEU plates, seven columns of 0.125 in.-wide depleted uranium plates and seven columns of 0.125 in.-wide graphite plates. The length of each column was 9 in. (228.6 mm) in each half of the core. The graphite plates were included to produce a softer neutron spectrum that would be more characteristic of a large power reactor. The axial blanket consisted of 12 in. (304.8 mm) of depleted uranium behind the core. The thickness of the radial blanket was approximately 12 in. and the length of the radial blanket in each half of the matrix was 21 in. (533.4 mm). The assembly geometry approximated a right circular cylinder as closely as the square matrix tubes allowed. According to the logbook and loading records for ZPR-3/12, the reference critical configuration was loading 10 which was critical on Feb. 5, 1958. The subsequent loadings were very similar but less clean for criticality because there were modifications made to accommodate reactor physics measurements other than criticality. Accordingly, ZPR-3/12 loading 10 was selected as the only configuration for this benchmark. As documented below, it was determined to be acceptable as a criticality safety benchmark experiment. An accurate transformation to a simplified model is needed to make any ZPR assembly a practical criticality-safety benchmark. There is simply too much geometric detail in an exact (as-built) model of a ZPR assembly, even a clean core such as ZPR-3/12 loading 10. The transformation must reduce the detail to a practical level without masking any of the important features of the critical experiment. And it must d

  5. Uranium deposits of Brazil

    SciTech Connect (OSTI)

    NONE

    1991-09-01T23:59:59.000Z

    Brazil is a country of vast natural resources, including numerous uranium deposits. In support of the country`s nuclear power program, Brazil has developed the most active uranium industry in South America. Brazil has one operating reactor (Angra 1, a 626-MWe PWR), and two under construction. The country`s economic challenges have slowed the progress of its nuclear program. At present, the Pocos de Caldas district is the only active uranium production. In 1990, the Cercado open-pit mine produced approximately 45 metric tons (MT) U{sub 3}O{sub 8} (100 thousand pounds). Brazil`s state-owned uranium production and processing company, Uranio do Brasil, announced it has decided to begin shifting its production from the high-cost and nearly depleted deposits at Pocos de Caldas, to lower-cost reserves at Lagoa Real. Production at Lagoa Real is schedules to begin by 1993. In addition to these two districts, Brazil has many other known uranium deposits, and as a whole, it is estimated that Brazil has over 275,000 MT U{sub 3}O{sub 8} (600 million pounds U{sub 3}O{sub 8}) in reserves.

  6. Feasibility study on consolidation of Fernald Environmental Management Project depleted uranium materials

    SciTech Connect (OSTI)

    NONE

    1995-11-30T23:59:59.000Z

    In 1991, the DOE made a decision to close the FMPC located in Fernald, Ohio, and end its production mission. The site was renamed FEMP to reflect Fernald`s mission change from uranium production to environmental restoration. As a result of this change, the inventory of strategic uranium materials maintained at Fernald by DOE DP will need to be relocated to other DOE sites. Although considered a liability to the Fernald Plant due to its current D and D mission, the FEMP DU represents a potentially valuable DOE resource. Recognizing its value, it may be important for the DOE to consolidate the material at one site and place it in a safe long-term storage condition until a future DOE programmatic requirement materializes. In August 1995, the DOE Office of Nuclear Weapons Management requested, Lockheed Martin Energy Systems (LMES) to assess the feasibility of consolidating the FEMP DU materials at the Oak Ridge Reservation (ORR). This feasibility study examines various phases associated with the consolidation of the FEMP DU at the ORR. If useful short-term applications for the DU fail to materialize, then long-term storage (up to 50 years) would need to be provided. Phases examined in this report include DU material value; potential uses; sampling; packaging and transportation; material control and accountability; environmental, health and safety issues; storage; project management; noneconomic factors; schedule; and cost.

  7. Uranium industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-07-05T23:59:59.000Z

    The Uranium Industry Annual 1994 (UIA 1994) provides current statistical data on the US uranium industry`s activities relating to uranium raw materials and uranium marketing during that survey year. The UIA 1994 is prepared for use by the Congress, Federal and State agencies, the uranium and nuclear electric utility industries, and the public. It contains data for the 10-year period 1985 through 1994 as collected on the Form EIA-858, ``Uranium Industry Annual Survey.`` Data collected on the ``Uranium Industry Annual Survey`` (UIAS) provide a comprehensive statistical characterization of the industry`s activities for the survey year and also include some information about industry`s plans and commitments for the near-term future. Where aggregate data are presented in the UIA 1994, care has been taken to protect the confidentiality of company-specific information while still conveying accurate and complete statistical data. A feature article, ``Comparison of Uranium Mill Tailings Reclamation in the United States and Canada,`` is included in the UIA 1994. Data on uranium raw materials activities including exploration activities and expenditures, EIA-estimated resources and reserves, mine production of uranium, production of uranium concentrate, and industry employment are presented in Chapter 1. Data on uranium marketing activities, including purchases of uranium and enrichment services, and uranium inventories, enrichment feed deliveries (actual and projected), and unfilled market requirements are shown in Chapter 2.

  8. A comparison of delayed radiobiological effects of depleted-uranium munitions versus fourth-generation nuclear weapons

    E-Print Network [OSTI]

    Gsponer, A; Vitale, B; Gsponer, Andre; Hurni, Jean-Pierre; Vitale, Bruno

    2002-01-01T23:59:59.000Z

    It is shown that the radiological burden due to the battle-field use of circa 400 tons of depleted-uranium munitions in Iraq (and of about 40 tons in Yugoslavia) is comparable to that arising from the hypothetical battle-field use of more than 600 kt (respectively 60 kt) of high-explosive equivalent pure-fusion fourth-generation nuclear weapons. Despite the limited knowledge openly available on existing and future nuclear weapons, there is sufficient published information on their physical principles and radiological effects to make such a comparison. In fact, it is shown that this comparison can be made with very simple and convincing arguments so that the main technical conclusions of the paper are undisputable -- although it would be worthwhile to supplement the hand calculations presented in the paper by more detailed computer simulations in order to consolidate the conclusions and refute any possible objections.

  9. A novel hohlraum with ultrathin depleted-uranium-nitride coating layer for low hard x-ray emission and high radiation temperature

    E-Print Network [OSTI]

    Guo, Liang; Xing, Peifeng; Li, Sanwei; Yi, Taimin; Kuang, Longyu; Li, Zhichao; Li, Renguo; Wu, Zheqing; Jing, Longfei; Zhang, Wenhai; Zhan, Xiayu; Yang, Dong; Jiang, Bobi; Yang, Jiamin; Liu, Shenye; Jiang, Shaoen; Li, Yongsheng; Liu, Jie; Huo, Wenyi; Lan, Ke

    2014-01-01T23:59:59.000Z

    An ultra-thin layer of uranium nitrides (UN) has been coated on the inner surface of the depleted uranium hohlraum (DUH), which has been proved by our experiment can prevent the oxidization of Uranium (U) effectively. Comparative experiments between the novel depleted uranium hohlraum and pure golden (Au) hohlraum are implemented on Shenguang III prototype laser facility. Under the laser intensity of 6*10^14 W/cm2, we observe that, the hard x-ray (> 1.8 keV) fraction of this uranium hohlraum decreases by 61% and the peak intensity of total x-ray flux (0.1 keV ~ 5 keV) increases by 5%. Two dimensional radiation hydrodynamic code LARED are exploited to interpret the above observations. Our result for the first time indicates the advantage of the UN-coated DUH in generating the uniform x-ray field with a quasi Planckian spectrum and thus has important implications in optimizing the ignition hohlraum design.

  10. Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Portsmouth, Ohio, Site

    SciTech Connect (OSTI)

    N /A

    2003-11-28T23:59:59.000Z

    This document is a site-specific environmental impact statement (EIS) for construction and operation of a proposed depleted uranium hexafluoride (DUF{sub 6}) conversion facility at the U.S. Department of Energy (DOE) Portsmouth site in Ohio (Figure S-1). The proposed facility would convert the DUF{sub 6} stored at Portsmouth to a more stable chemical form suitable for use or disposal. The facility would also convert the DUF{sub 6} from the East Tennessee Technology Park (ETTP) site near Oak Ridge, Tennessee. In a Notice of Intent (NOI) published in the Federal Register on September 18, 2001 (Federal Register, Volume 66, page 48123 [66 FR 48123]), DOE announced its intention to prepare a single EIS for a proposal to construct, operate, maintain, and decontaminate and decommission two DUF{sub 6} conversion facilities at Portsmouth, Ohio, and Paducah, Kentucky, in accordance with the National Environmental Policy Act of 1969 (NEPA) (United States Code, Title 42, Section 4321 et seq. [42 USC 4321 et seq.]) and DOE's NEPA implementing procedures (Code of Federal Regulations, Title 10, Part 1021 [10 CFR Part 1021]). Subsequent to award of a contract to Uranium Disposition Services, LLC (hereafter referred to as UDS), Oak Ridge, Tennessee, on August 29, 2002, for design, construction, and operation of DUF{sub 6} conversion facilities at Portsmouth and Paducah, DOE reevaluated its approach to the NEPA process and decided to prepare separate site-specific EISs. This change was announced in a Federal Register Notice of Change in NEPA Compliance Approach published on April 28, 2003 (68 FR 22368); the Notice is included as Attachment B to Appendix C of this EIS. This EIS addresses the potential environmental impacts from the construction, operation, maintenance, and decontamination and decommissioning (D&D) of the proposed conversion facility at three alternative locations within the Portsmouth site; from the transportation of all ETTP cylinders (DUF{sub 6}, low-enriched UF6 [LEU-UF{sub 6}], and empty) to Portsmouth; from the transportation of depleted uranium conversion products to a disposal facility; and from the transportation, sale, use, or disposal of the fluoride-containing conversion products (hydrogen fluoride [HF] or calcium fluoride [CaF{sub 2}]). An option of shipping the ETTP cylinders to Paducah is also considered. In addition, this EIS evaluates a no action alternative, which assumes continued storage of DUF{sub 6} in cylinders at the Portsmouth and ETTP sites. A separate EIS (DOE/EIS-0359) evaluates potential environmental impacts for the proposed Paducah conversion facility.

  11. Draft Environmental Impact Statement for Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky, Site

    SciTech Connect (OSTI)

    N /A

    2003-11-28T23:59:59.000Z

    This document is a site-specific environmental impact statement (EIS) for construction and operation of a proposed depleted uranium hexafluoride (DUF{sub 6}) conversion facility at the U.S. Department of Energy (DOE) Paducah site in northwestern Kentucky (Figure S-1). The proposed facility would convert the DUF{sub 6} stored at Paducah to a more stable chemical form suitable for use or disposal. In a Notice of Intent (NOI) published in the ''Federal Register'' (FR) on September 18, 2001 (''Federal Register'', Volume 66, page 48123 [66 FR 48123]), DOE announced its intention to prepare a single EIS for a proposal to construct, operate, maintain, and decontaminate and decommission two DUF{sub 6} conversion facilities at Portsmouth, Ohio, and Paducah, Kentucky, in accordance with the National Environmental Policy Act of 1969 (NEPA) (''United States Code'', Title 42, Section 4321 et seq. [42 USC 4321 et seq.]) and DOE's NEPA implementing procedures (''Code of Federal Regulations'', Title 10, Part 1021 [10 CFR Part 1021]). Subsequent to award of a contract to Uranium Disposition Services, LLC (hereafter referred to as UDS), Oak Ridge, Tennessee, on August 29, 2002, for design, construction, and operation of DUF{sub 6} conversion facilities at Portsmouth and Paducah, DOE reevaluated its approach to the NEPA process and decided to prepare separate site-specific EISs. This change was announced in a ''Federal Register'' Notice of Change in NEPA Compliance Approach published on April 28, 2003 (68 FR 22368); the Notice is included as Attachment B to Appendix C of this EIS. This EIS addresses the potential environmental impacts from the construction, operation, maintenance, and decontamination and decommissioning (D&D) of the proposed conversion facility at three alternative locations within the Paducah site; from the transportation of depleted uranium conversion products to a disposal facility; and from the transportation, sale, use, or disposal of the fluoride-containing conversion products (hydrogen fluoride [HF] or calcium fluoride [CaF{sub 2}]). Although not part of the proposed action, an option of shipping all cylinders (DUF{sub 6}, low-enriched UF{sub 6} [LEU-UF{sub 6}], and empty) stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Paducah rather than to Portsmouth is also considered. In addition, this EIS evaluates a no action alternative, which assumes continued storage of DUF{sub 6} in cylinders at the Paducah site. A separate EIS (DOE/EIS-0360) evaluates the potential environmental impacts for the proposed Portsmouth conversion facility.

  12. Magnetic Exchange Coupling and Single-Molecule Magnetism in Uranium Complexes

    E-Print Network [OSTI]

    Rinehart, Jeffrey Dennis

    2010-01-01T23:59:59.000Z

    greater than 99% U-238 (depleted uranium), which has no neturanium, since this actinide element offers minimal radioactivity (in depleted

  13. Final Uranium Leasing Program Programmatic Environmental Impact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Uranium Leasing Program Programmatic Environmental Impact Statement (PEIS) Final Uranium Leasing Program Programmatic Environmental Impact Statement (PEIS) Uranium Leasing...

  14. Characterization of options and their analysis requirements for the long-term management of depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Dubrin, J.W.; Rosen, R.S.; Zoller, J.N.; Harri, J.W.; Schwertz, N.L.

    1995-12-01T23:59:59.000Z

    The Department of Energy (DOE) is examining alternative strategies for the long-term management of depleted uranium hexafluoride (UF{sub 6}) currently stored at the gaseous diffusion plants at Portsmouth, Ohio, and Paducah, Kentucky, and on the Oak Ridge Reservation in Oak Ridge, Tennessee. This paper describes the methodology for the comprehensive and ongoing technical analysis of the options being considered. An overview of these options, along with several of the suboptions being considered, is presented. The long-term management strategy alternatives fall into three broad categories: use, storage, or disposal. Conversion of the depleted UF6 to another form such as oxide or metal is needed to implement most of these alternatives. Likewise, transportation of materials is an integral part of constructing the complete pathway between the current storage condition and ultimate disposition. The analysis of options includes development of pre-conceptual designs; estimates of effluents, wastes, and emissions; specification of resource requirements; and preliminary hazards assessments. The results of this analysis will assist DOE in selecting a strategy by providing the engineering information necessary to evaluate the environmental impacts and costs of implementing the management strategy alternatives.

  15. Long-term fate of depleted uranium at Aberdeen and Yuma Proving Grounds: Human health and ecological risk assessments

    SciTech Connect (OSTI)

    Ebinger, M.H.; Beckman, R.J.; Myers, O.B. [Los Alamos National Lab., NM (United States); Kennedy, P.L.; Clements, W.; Bestgen, H.T. [Colorado State Univ., Ft. Collins, CO (United States). Dept. of Fishery and Wildlife Biology

    1996-09-01T23:59:59.000Z

    The purpose of this study was to evaluate the immediate and long-term consequences of depleted uranium (DU) in the environment at Aberdeen Proving Ground (APG) and Yuma Proving Ground (YPG) for the Test and Evaluation Command (TECOM) of the US Army. Specifically, we examined the potential for adverse radiological and toxicological effects to humans and ecosystems caused by exposure to DU at both installations. We developed contaminant transport models of aquatic and terrestrial ecosystems at APG and terrestrial ecosystems at YPG to assess potential adverse effects from DU exposure. Sensitivity and uncertainty analyses of the initial models showed the portions of the models that most influenced predicted DU concentrations, and the results of the sensitivity analyses were fundamental tools in designing field sampling campaigns at both installations. Results of uranium (U) isotope analyses of field samples provided data to evaluate the source of U in the environment and the toxicological and radiological doses to different ecosystem components and to humans. Probabilistic doses were estimated from the field data, and DU was identified in several components of the food chain at APG and YPG. Dose estimates from APG data indicated that U or DU uptake was insufficient to cause adverse toxicological or radiological effects. Dose estimates from YPG data indicated that U or DU uptake is insufficient to cause radiological effects in ecosystem components or in humans, but toxicological effects in small mammals (e.g., kangaroo rats and pocket mice) may occur from U or DU ingestion. The results of this study were used to modify environmental radiation monitoring plans at APG and YPG to ensure collection of adequate data for ongoing ecological and human health risk assessments.

  16. Method for converting uranium oxides to uranium metal

    DOE Patents [OSTI]

    Duerksen, Walter K. (Norris, TN)

    1988-01-01T23:59:59.000Z

    A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixture is then cooled to a temperature less than -100.degree. C. in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

  17. Optical Constants ofOptical Constants of Uranium Nitride Thin FilmsUranium Nitride Thin Films

    E-Print Network [OSTI]

    Hart, Gus

    Optical Constants ofOptical Constants of Uranium Nitride Thin FilmsUranium Nitride Thin FilmsDelta--Beta Scatter Plot at 220 eVBeta Scatter Plot at 220 eV #12;Why Uranium Nitride?Why Uranium Nitride? UraniumUranium, uranium,Bombard target, uranium, with argon ionswith argon ions Uranium atoms leaveUranium atoms leave

  18. Welding of uranium and uranium alloys

    SciTech Connect (OSTI)

    Mara, G.L.; Murphy, J.L.

    1982-03-26T23:59:59.000Z

    The major reported work on joining uranium comes from the USA, Great Britain, France and the USSR. The driving force for producing this technology base stems from the uses of uranium as a nuclear fuel for energy production, compact structures requiring high density, projectiles, radiation shielding, and nuclear weapons. This review examines the state-of-the-art of this technology and presents current welding process and parameter information. The welding metallurgy of uranium and the influence of microstructure on mechanical properties is developed for a number of the more commonly used welding processes.

  19. EPA Update: NESHAP Uranium Activities

    E-Print Network [OSTI]

    for underground uranium mining operations (Subpart B) EPA regulatory requirements for operating uranium mill for Underground Uranium Mining Operations (Subpart B) #12;5 EPA Regulatory Requirements for Underground Uranium uranium mines include: · Applies to 10,000 tons/yr ore production, or 100,000 tons/mine lifetime · Ambient

  20. Uranium hexafluoride public risk

    SciTech Connect (OSTI)

    Fisher, D.R.; Hui, T.E.; Yurconic, M.; Johnson, J.R.

    1994-08-01T23:59:59.000Z

    The limiting value for uranium toxicity in a human being should be based on the concentration of uranium (U) in the kidneys. The threshold for nephrotoxicity appears to lie very near 3 {mu}g U per gram kidney tissue. There does not appear to be strong scientific support for any other improved estimate, either higher or lower than this, of the threshold for uranium nephrotoxicity in a human being. The value 3 {mu}g U per gram kidney is the concentration that results from a single intake of about 30 mg soluble uranium by inhalation (assuming the metabolism of a standard person). The concentration of uranium continues to increase in the kidneys after long-term, continuous (or chronic) exposure. After chronic intakes of soluble uranium by workers at the rate of 10 mg U per week, the concentration of uranium in the kidneys approaches and may even exceed the nephrotoxic limit of 3 {mu}g U per gram kidney tissue. Precise values of the kidney concentration depend on the biokinetic model and model parameters assumed for such a calculation. Since it is possible for the concentration of uranium in the kidneys to exceed 3 {mu}g per gram tissue at an intake rate of 10 mg U per week over long periods of time, we believe that the kidneys are protected from injury when intakes of soluble uranium at the rate of 10 mg U per week do not continue for more than two consecutive weeks. For long-term, continuous occupational exposure to low-level, soluble uranium, we recommend a reduced weekly intake limit of 5 mg uranium to prevent nephrotoxicity in workers. Our analysis shows that the nephrotoxic limit of 3 {mu}g U per gram kidney tissues is not exceeded after long-term, continuous uranium intake at the intake rate of 5 mg soluble uranium per week.

  1. Depleted uranium risk assessment for Jefferson Proving Ground using data from environmental monitoring and site characterization. Final report

    SciTech Connect (OSTI)

    Ebinger, M.H.; Hansen, W.R.

    1996-10-01T23:59:59.000Z

    This report documents the third risk assessment completed for the depleted uranium (DU) munitions testing range at Jefferson Proving Ground (JPG), Indiana, for the U.S. Army Test and Evaluation command. Jefferson Proving Ground was closed in 1995 under the Base Realignment and Closure Act and the testing mission was moved to Yuma Proving Ground. As part of the closure of JPG, assessments of potential adverse health effects to humans and the ecosystem were conducted. This report integrates recent information obtained from site characterization surveys at JPG with environmental monitoring data collected from 1983 through 1994 during DU testing. Three exposure scenarios were evaluated for potential adverse effects to human health: an occasional use scenario and two farming scenarios. Human exposure was minimal from occasional use, but significant risk were predicted from the farming scenarios when contaminated groundwater was used by site occupants. The human health risk assessments do not consider the significant risk posed by accidents with unexploded ordnance. Exposures of white-tailed deer to DU were also estimated in this study, and exposure rates result in no significant increase in either toxicological or radiological risks. The results of this study indicate that remediation of the DU impact area would not substantially reduce already low risks to humans and the ecosystem, and that managed access to JPG is a reasonable model for future land use options.

  2. Radiation- and Depleted Uranium-Induced Carcinogenesis Studies: Characterization of the Carcinogenic Process and Development of Medical Countermeasures

    E-Print Network [OSTI]

    A. C. Miller; D. Beltran; R. Rivas; M. Stewart; R. J. Merlot; P. B. Lison

    External or internal contamination from radioactive elements during military operations or a terrorist attack is a serious threat to military and civilian populations. External radiation exposure could result from conventional military scenarios including nuclear weapons use and low-dose exposures during radiation accidents or terrorist attacks. Alternatively, internal radiation exposure could result from depleted uranium exposure via DU shrapnel wounds or inhalation. The long-term health effects of these types of radiation exposures are not well known. Furthermore, development of pharmacological countermeasures to low-dose external and internal radiological contamination is essential to the health and safety of both military and civilian populations. The purpose of these studies is to evaluate low-dose radiation or DU-induced carcinogenesis using in vitro and in vivo models, and to test safe and efficacious medical countermeasures. A third goal of these studies is to identify biomarkers of both exposure and disease development. Initially, we used a human cell model (human osteoblast cells, HOS) to evaluate the carcinogenic potential of DU in vitro by assessing morphological transformation, genotoxicity (chromosomal aberrations), mutagenic (HPRT loci), and genomic instability. As a comparison, low-dose cobalt radiation, broad-beam alpha particles, and other military-projectile metals, i.e., tungsten mixtures, are being examined. Published data from

  3. Uranium Mill Tailings Management

    SciTech Connect (OSTI)

    Nelson, J.D.

    1982-01-01T23:59:59.000Z

    This book presents the papers given at the Fifth Symposium on Uranium Mill Tailings Management. Advances made with regard to uranium mill tailings management, environmental effects, regulations, and reclamation are reviewed. Topics considered include tailings management and design (e.g., the Uranium Mill Tailings Remedial Action Project, environmental standards for uranium mill tailings disposal), surface stabilization (e.g., the long-term stability of tailings, long-term rock durability), radiological aspects (e.g. the radioactive composition of airborne particulates), contaminant migration (e.g., chemical transport beneath a uranium mill tailings pile, the interaction of acidic leachate with soils), radon control and covers (e.g., radon emanation characteristics, designing surface covers for inactive uranium mill tailings), and seepage and liners (e.g., hydrologic observations, liner requirements).

  4. Process for continuous production of metallic uranium and uranium alloys

    DOE Patents [OSTI]

    Hayden, H.W. Jr.; Horton, J.A.; Elliott, G.R.B.

    1995-06-06T23:59:59.000Z

    A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO{sub 3}), or any other substantially stable uranium oxide, to form the uranium dioxide (UO{sub 2}). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl{sub 4}), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation. 4 figs.

  5. Process for continuous production of metallic uranium and uranium alloys

    DOE Patents [OSTI]

    Hayden, Jr., Howard W. (Oakridge, TN); Horton, James A. (Livermore, CA); Elliott, Guy R. B. (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO.sub.3), or any other substantially stable uranium oxide, to form the uranium dioxide (UO.sub.2). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl.sub.4), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation.

  6. Preparation of uranium compounds

    DOE Patents [OSTI]

    Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

    2013-02-19T23:59:59.000Z

    UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

  7. THE ENERGY SPECTRA OF URANIUM ATOMS SPUTTERED FROM URANIUM METAL AND URANIUM DIOXIDE TARGETS

    E-Print Network [OSTI]

    Winfree, Erik

    THE ENERGY SPECTRA OF URANIUM ATOMS SPUTTERED FROM URANIUM METAL AND URANIUM DIOXIDE TARGETS Thesis. I have benefitted from conversations with many persons w~ile engaged in this project. I would like

  8. Uranium industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-09-01T23:59:59.000Z

    Uranium production in the United States has declined dramatically from a peak of 43.7 million pounds U{sub 3}O{sub 8} (16.8 thousand metric tons uranium (U)) in 1980 to 3.1 million pounds U{sub 3}O{sub 8} (1.2 thousand metric tons U) in 1993. This decline is attributed to the world uranium market experiencing oversupply and intense competition. Large inventories of uranium accumulated when optimistic forecasts for growth in nuclear power generation were not realized. The other factor which is affecting U.S. uranium production is that some other countries, notably Australia and Canada, possess higher quality uranium reserves that can be mined at lower costs than those of the United States. Realizing its competitive advantage, Canada was the world`s largest producer in 1993 with an output of 23.9 million pounds U{sub 3}O{sub 8} (9.2 thousand metric tons U). The U.S. uranium industry, responding to over a decade of declining market prices, has downsized and adopted less costly and more efficient production methods. The main result has been a suspension of production from conventional mines and mills. Since mid-1992, only nonconventional production facilities, chiefly in situ leach (ISL) mining and byproduct recovery, have operated in the United States. In contrast, nonconventional sources provided only 13 percent of the uranium produced in 1980. ISL mining has developed into the most cost efficient and environmentally acceptable method for producing uranium in the United States. The process, also known as solution mining, differs from conventional mining in that solutions are used to recover uranium from the ground without excavating the ore and generating associated solid waste. This article describes the current ISL Yang technology and its regulatory approval process, and provides an analysis of the factors favoring ISL mining over conventional methods in a declining uranium market.

  9. CHARACTERIZATION OF URANIUM, URANIUM OXIDE AND SILICON MULTILAYER THIN FILMS

    E-Print Network [OSTI]

    Hart, Gus

    CHARACTERIZATION OF URANIUM, URANIUM OXIDE AND SILICON MULTILAYER THIN FILMS by David T. Oliphant. Woolley Dean, College of Physical and Mathematical Sciences #12;ABSTRACT CHARACTERIZATION OF URANIUM, URANIUM OXIDE AND SILICON MULTILAYER THIN FILMS David T. Oliphant Department of Physics and Astronomy

  10. Uranium dioxide electrolysis

    DOE Patents [OSTI]

    Willit, James L. (Batavia, IL); Ackerman, John P. (Prescott, AZ); Williamson, Mark A. (Naperville, IL)

    2009-12-29T23:59:59.000Z

    This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO.sub.2, is added to a solution of UCl.sub.4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

  11. India's Worsening Uranium Shortage

    SciTech Connect (OSTI)

    Curtis, Michael M.

    2007-01-15T23:59:59.000Z

    As a result of NSG restrictions, India cannot import the natural uranium required to fuel its Pressurized Heavy Water Reactors (PHWRs); consequently, it is forced to rely on the expediency of domestic uranium production. However, domestic production from mines and byproduct sources has not kept pace with demand from commercial reactors. This shortage has been officially confirmed by the Indian Planning Commission’s Mid-Term Appraisal of the country’s current Five Year Plan. The report stresses that as a result of the uranium shortage, Indian PHWR load factors have been continually decreasing. The Uranium Corporation of India Ltd (UCIL) operates a number of underground mines in the Singhbhum Shear Zone of Jharkhand, and it is all processed at a single mill in Jaduguda. UCIL is attempting to aggrandize operations by establishing new mines and mills in other states, but the requisite permit-gathering and development time will defer production until at least 2009. A significant portion of India’s uranium comes from byproduct sources, but a number of these are derived from accumulated stores that are nearing exhaustion. A current maximum estimate of indigenous uranium production is 430t/yr (230t from mines and 200t from byproduct sources); whereas, the current uranium requirement for Indian PHWRs is 455t/yr (depending on plant capacity factor). This deficit is exacerbated by the additional requirements of the Indian weapons program. Present power generation capacity of Indian nuclear plants is 4350 MWe. The power generation target set by the Indian Department of Atomic Energy (DAE) is 20,000 MWe by the year 2020. It is expected that around half of this total will be provided by PHWRs using indigenously supplied uranium with the bulk of the remainder provided by breeder reactors or pressurized water reactors using imported low-enriched uranium.

  12. Method for the recovery of uranium values from uranium tetrafluoride

    DOE Patents [OSTI]

    Kreuzmann, Alvin B. (Cincinnati, OH)

    1983-01-01T23:59:59.000Z

    The invention is a novel method for the recovery of uranium from dry, particulate uranium tetrafluoride. In one aspect, the invention comprises reacting particulate uranium tetrafluoride and calcium oxide in the presence of gaseous oxygen to effect formation of the corresponding alkaline earth metal uranate and alkaline earth metal fluoride. The product uranate is highly soluble in various acidic solutions wherein the product fluoride is virtually insoluble therein. The product mixture of uranate and alkaline earth metal fluoride is contacted with a suitable acid to provide a uranium-containing solution, from which the uranium is recovered. The invention can achieve quantitative recovery of uranium in highly pure form.

  13. Method for the recovery of uranium values from uranium tetrafluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.

    1982-10-27T23:59:59.000Z

    The invention is a novel method for the recovery of uranium from dry, particulate uranium tetrafluoride. In one aspect, the invention comprises reacting particulate uranium tetrafluoride and calcium oxide in the presence of gaseous oxygen to effect formation of the corresponding alkaline earth metal uranate and alkaline earth metal fluoride. The product uranate is highly soluble in various acidic solutions whereas the product fluoride is virtually insoluble therein. The product mixture of uranate and alkaline earth metal fluoride is contacted with a suitable acid to provide a uranium-containing solution, from which the uranium is recovered. The invention can achieve quantitative recovery of uranium in highly pure form.

  14. Uranium Enrichment Decontamination and Decommissioning Fund's...

    Broader source: Energy.gov (indexed) [DOE]

    Uranium Enrichment Decontamination and Decommissioning Fund's Fiscal Year 2008 and 2007 Financial Statement Audit Uranium Enrichment Decontamination and Decommissioning Fund's...

  15. Process for electrolytically preparing uranium metal

    DOE Patents [OSTI]

    Haas, Paul A. (Knoxville, TN)

    1989-01-01T23:59:59.000Z

    A process for making uranium metal from uranium oxide by first fluorinating uranium oxide to form uranium tetrafluoride and next electrolytically reducing the uranium tetrafluoride with a carbon anode to form uranium metal and CF.sub.4. The CF.sub.4 is reused in the fluorination reaction rather than being disposed of as a hazardous waste.

  16. Influence of uranium hydride oxidation on uranium metal behaviour

    SciTech Connect (OSTI)

    Patel, N.; Hambley, D. [National Nuclear Laboratory (United Kingdom); Clarke, S.A. [Sellafield Ltd (United Kingdom); Simpson, K.

    2013-07-01T23:59:59.000Z

    This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

  17. Uranium-titanium-niobium alloy

    DOE Patents [OSTI]

    Ludtka, Gail M. (Oak Ridge, TN); Ludtka, Gerard M. (Oak Ridge, TN)

    1990-01-01T23:59:59.000Z

    A uranium alloy having small additions of Ti and Nb shows improved strength and ductility in cross section of greater than one inch over prior uranium alloy having only Ti as an alloying element.

  18. Uranium Oxide as a Highly Reflective Coating from 150-350 eV

    E-Print Network [OSTI]

    Hart, Gus

    of depleted uranium metal (less than 0.2% U-235). After sputtering, the uranium was allowed to oxidize1 Uranium Oxide as a Highly Reflective Coating from 150-350 eV Richard L. Sandberg, David D. Allred.byu.edu ABSTRACT We present the measured reflectances (beamline 6.3.2, ALS at LBNL) of naturally oxidized uranium

  19. Uranium hexafluoride handling. Proceedings

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    The United States Department of Energy, Oak Ridge Field Office, and Martin Marietta Energy Systems, Inc., are co-sponsoring this Second International Conference on Uranium Hexafluoride Handling. The conference is offered as a forum for the exchange of information and concepts regarding the technical and regulatory issues and the safety aspects which relate to the handling of uranium hexafluoride. Through the papers presented here, we attempt not only to share technological advances and lessons learned, but also to demonstrate that we are concerned about the health and safety of our workers and the public, and are good stewards of the environment in which we all work and live. These proceedings are a compilation of the work of many experts in that phase of world-wide industry which comprises the nuclear fuel cycle. Their experience spans the entire range over which uranium hexafluoride is involved in the fuel cycle, from the production of UF{sub 6} from the naturally-occurring oxide to its re-conversion to oxide for reactor fuels. The papers furnish insights into the chemical, physical, and nuclear properties of uranium hexafluoride as they influence its transport, storage, and the design and operation of plant-scale facilities for production, processing, and conversion to oxide. The papers demonstrate, in an industry often cited for its excellent safety record, continuing efforts to further improve safety in all areas of handling uranium hexafluoride. Selected papers were processed separately for inclusion in the Energy Science and Technology Database.

  20. Uranium immobilization and nuclear waste

    SciTech Connect (OSTI)

    Duffy, C.J.; Ogard, A.E.

    1982-02-01T23:59:59.000Z

    Considerable information useful in nuclear waste storage can be gained by studying the conditions of uranium ore deposit formation. Further information can be gained by comparing the chemistry of uranium to nuclear fission products and other radionuclides of concern to nuclear waste disposal. Redox state appears to be the most important variable in controlling uranium solubility, especially at near neutral pH, which is characteristic of most ground water. This is probably also true of neptunium, plutonium, and technetium. Further, redox conditions that immobilize uranium should immobilize these elements. The mechanisms that have produced uranium ore bodies in the Earth's crust are somewhat less clear. At the temperatures of hydrothermal uranium deposits, equilibrium models are probably adequate, aqueous uranium (VI) being reduced and precipitated by interaction with ferrous-iron-bearing oxides and silicates. In lower temperature roll-type uranium deposits, overall equilibrium may not have been achieved. The involvement of sulfate-reducing bacteria in ore-body formation has been postulated, but is uncertain. Reduced sulfur species do, however, appear to be involved in much of the low temperature uranium precipitation. Assessment of the possibility of uranium transport in natural ground water is complicated because the system is generally not in overall equilibrium. For this reason, Eh measurements are of limited value. If a ground water is to be capable of reducing uranium, it must contain ions capable of reducing uranium both thermodynamically and kinetically. At present, the best candidates are reduced sulfur species.

  1. Corrosion-resistant uranium

    DOE Patents [OSTI]

    Hovis, V.M. Jr.; Pullen, W.C.; Kollie, T.G.; Bell, R.T.

    1981-10-21T23:59:59.000Z

    The present invention is directed to the protecting of uranium and uranium alloy articles from corrosion by providing the surfaces of the articles with a layer of an ion-plated metal selected from aluminum and zinc to a thickness of at least 60 microinches and then converting at least the outer surface of the ion-plated layer of aluminum or zinc to aluminum chromate or zinc chromate. This conversion of the aluminum or zinc to the chromate form considerably enhances the corrosion resistance of the ion plating so as to effectively protect the coated article from corrosion.

  2. Corrosion-resistant uranium

    DOE Patents [OSTI]

    Hovis, Jr., Victor M. (Kingston, TN); Pullen, William C. (Knoxville, TN); Kollie, Thomas G. (Oak Ridge, TN); Bell, Richard T. (Knoxville, TN)

    1983-01-01T23:59:59.000Z

    The present invention is directed to the protecting of uranium and uranium alloy articles from corrosion by providing the surfaces of the articles with a layer of an ion-plated metal selected from aluminum and zinc to a thickness of at least 60 microinches and then converting at least the outer surface of the ion-plated layer of aluminum or zinc to aluminum chromate or zinc chromate. This conversion of the aluminum or zinc to the chromate form considerably enhances the corrosion resistance of the ion plating so as to effectively protect the coated article from corrosion.

  3. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium froma. Uranium

  4. Streamlined approach for environmental restoration plan for corrective action unit 430, buried depleted uranium artillery round No. 1, Tonopah test range

    SciTech Connect (OSTI)

    NONE

    1996-09-01T23:59:59.000Z

    This plan addresses actions necessary for the restoration and closure of Corrective Action Unit (CAU) No. 430, Buried Depleted Uranium (DU) Artillery Round No. 1 (Corrective Action Site No. TA-55-003-0960), a buried and unexploded W-79 Joint Test Assembly (JTA) artillery test projectile with high explosives (HE), at the U.S. Department of Energy, Nevada Operations Office (DOE/NV) Tonopah Test Range (TTR) in south-central Nevada. It describes activities that will occur at the site as well as the steps that will be taken to gather adequate data to obtain a notice of completion from Nevada Division of Environmental Protection (NDEP). This plan was prepared under the Streamlined Approach for Environmental Restoration (SAFER) concept, and it will be implemented in accordance with the Federal Facility Agreement and Consent Order (FFACO) and the Resource Conservation and Recovery Act (RCRA) Industrial Sites Quality Assurance Project Plan.

  5. High loading uranium fuel plate

    DOE Patents [OSTI]

    Wiencek, Thomas C. (Bolingbrook, IL); Domagala, Robert F. (Indian Head Park, IL); Thresh, Henry R. (Palos Heights, IL)

    1990-01-01T23:59:59.000Z

    Two embodiments of a high uranium fuel plate are disclosed which contain a meat comprising structured uranium compound confined between a pair of diffusion bonded ductile metal cladding plates uniformly covering the meat, the meat having a uniform high fuel loading comprising a content of uranium compound greater than about 45 Vol. % at a porosity not greater than about 10 Vol. %. In a first embodiment, the meat is a plurality of parallel wires of uranium compound. In a second embodiment, the meat is a dispersion compact containing uranium compound. The fuel plates are fabricated by a hot isostatic pressing process.

  6. Biological assessment of the effects of construction and operation of a depleted uranium hexafluoride conversion facility at the Paducah, Kentucky, site.

    SciTech Connect (OSTI)

    Van Lonkhuyzen, R.

    2005-09-09T23:59:59.000Z

    The U.S. Department of Energy (DOE) Depleted Uranium Hexafluoride (DUF{sub 6}) Management Program evaluated alternatives for managing its inventory of DUF{sub 6} and issued the ''Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride'' (DUF{sub 6} PEIS) in April 1999 (DOE 1999). The DUF{sub 6} inventory is stored in cylinders at three DOE sites: Paducah, Kentucky; Portsmouth, Ohio; and East Tennessee Technology Park (ETTP), near Oak Ridge, Tennessee. In the Record of Decision for the DUF{sub 6} PEIS, DOE stated its decision to promptly convert the DUF6 inventory to a more stable chemical form. Subsequently, the U.S. Congress passed, and the President signed, the ''2002 Supplemental Appropriations Act for Further Recovery from and Response to Terrorist Attacks on the United States'' (Public Law No. 107-206). This law stipulated in part that, within 30 days of enactment, DOE must award a contract for the design, construction, and operation of a DUF{sub 6} conversion plant at the Department's Paducah, Kentucky, and Portsmouth, Ohio, sites, and for the shipment of DUF{sub 6} cylinders stored at ETTP to the Portsmouth site for conversion. This biological assessment (BA) has been prepared by DOE, pursuant to the National Environmental Policy Act of 1969 (NEPA) and the Endangered Species Act of 1974, to evaluate potential impacts to federally listed species from the construction and operation of a conversion facility at the DOE Paducah site.

  7. Uranium from seawater

    SciTech Connect (OSTI)

    Gregg, D.; Folkendt, M.

    1982-09-21T23:59:59.000Z

    A novel process for recovering uranium from seawater is proposed and some of the critical technical parameters are evaluated. The process, in summary, consists of two different options for contacting adsorbant pellets with seawater without pumping the seawater. It is expected that this will reduce the mass handling requirements, compared to pumped seawater systems, by a factor of approximately 10/sup 5/, which should also result in a large reduction in initial capital investment. Activated carbon, possibly in combination with a small amount of dissolved titanium hydroxide, is expected to be the preferred adsorbant material instead of the commonly assumed titanium hydroxide alone. The activated carbon, after exposure to seawater, can be stripped of uranium with an appropriate eluant (probably an acid) or can be burned for its heating value (possible in a power plant) leaving the uranium further enriched in its ash. The uranium, representing about 1% of the ash, is then a rich ore and would be recovered in a conventional manner. Experimental results have indicated that activated carbon, acting alone, is not adequately effective in adsorbing the uranium from seawater. We measured partition coefficients (concentration ratios) of approximately 10/sup 3/ in seawater instead of the reported values of 10/sup 5/. However, preliminary tests carried out in fresh water show considerable promise for an extraction system that uses a combination of dissolved titanium hydroxide (in minute amounts) which forms an insoluble compound with the uranyl ion, and the insoluble compound then being sorbed out on activated carbon. Such a system showed partition coefficients in excess of 10/sup 5/ in fresh water. However, the system was not tested in seawater.

  8. Conversion and Blending Facility highly enriched uranium to low enriched uranium as metal. Revision 1

    SciTech Connect (OSTI)

    NONE

    1995-07-05T23:59:59.000Z

    The mission of this Conversion and Blending Facility (CBF) will be to blend surplus HEU metal and alloy with depleted uranium metal to produce an LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal.

  9. Method of preparation of uranium nitride

    DOE Patents [OSTI]

    Kiplinger, Jaqueline Loetsch; Thomson, Robert Kenneth James

    2013-07-09T23:59:59.000Z

    Method for producing terminal uranium nitride complexes comprising providing a suitable starting material comprising uranium; oxidizing the starting material with a suitable oxidant to produce one or more uranium(IV)-azide complexes; and, sufficiently irradiating the uranium(IV)-azide complexes to produce the terminal uranium nitride complexes.

  10. Investigation of Trace Uranium in Biological Matrices

    E-Print Network [OSTI]

    Miller, James Christopher

    2013-05-31T23:59:59.000Z

    complex. As a result, the data varies in its breadth and quality due to the variety of sources.[41-44] Additional studies have been undertaken to understand the effects of using depleted uranium munitions in war and the accompanying exposures.[45...

  11. Method for fabricating uranium foils and uranium alloy foils

    DOE Patents [OSTI]

    Hofman, Gerard L. (Downers Grove, IL); Meyer, Mitchell K. (Idaho Falls, ID); Knighton, Gaven C. (Moore, ID); Clark, Curtis R. (Idaho Falls, ID)

    2006-09-05T23:59:59.000Z

    A method of producing thin foils of uranium or an alloy. The uranium or alloy is cast as a plate or sheet having a thickness less than about 5 mm and thereafter cold rolled in one or more passes at substantially ambient temperatures until the uranium or alloy thereof is in the shape of a foil having a thickness less than about 1.0 mm. The uranium alloy includes one or more of Zr, Nb, Mo, Cr, Fe, Si, Ni, Cu or Al.

  12. Unexpected, Stable Form of Uranium Detected | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unexpected, Stable Form of Uranium Detected Unexpected, Stable Form of Uranium Detected Insights on underappreciated reaction could shed light on environmental cleanup options...

  13. Solid State Phase Transformations in Uranium-Zirconium Alloys

    E-Print Network [OSTI]

    Irukuvarghula, Sandeep

    2013-08-06T23:59:59.000Z

    Depleted Uranium WDS Wavelength Dispersive Spectroscopy DIC Di erential Interference Contrast BSE Back Scattered Electron image SS Stainless Steel MIC Microscopy and Imaging Center OR Orientation Relationship EDS Energy Dispersive Spectroscopy UNLV...

  14. IPNS enriched uranium booster target

    SciTech Connect (OSTI)

    Schulke, A.W. Jr.

    1985-01-01T23:59:59.000Z

    Since startup in 1981, IPNS has operated on a fully depleted /sup 238/U target. With the booster as in the present system, high energy protons accelerated to 450 MeV by the Rapid Cycling Synchrotron are directed at the target and by mechanisms of spallation and fission of the uranium, produce fast neutrons. The neutrons from the target pass into adjacent moderator where they slow down to energies useful for spectroscopy. The target cooling systems and monitoring systems have operated very reliably and safely during this period. To provide higher neutron intensity, we have developed plans for an enriched uranium (booster) target. HETC-VIM calculations indicate that the target will produce approx.90 kW of heat, with a nominal x5 gain (k/sub eff/ = 0.80). The neutron beam intensity gain will be a factor of approx.3. Thermal-hydraulic and heat transport calculations indicate that approx.1/2 in. thick /sup 235/U discs are subject to about the same temperatures as the present /sup 238/U 1 in. thick discs. The coolant will be light demineralized water (H/sub 2/O) and the coolant flow rate must be doubled. The broadening of the fast neutron pulse width should not seriously affect the neutron scattering experiments. Delayed neutrons will appear at a level about 3% of the total (currently approx.0.5%). This may affect backgrounds in some experiments, so that we are assessing measures to control and correct for this (e.g., beam tube choppers). Safety analyses and neutronic calculations are nearing completion. Construction of the /sup 235/U discs at the ORNL Y-12 facility is scheduled to begin late 1985. The completion of the booster target and operation are scheduled for late 1986. No enriched uranium target assembly operating at the projected power level now exists in the world. This effort thus represents an important technological experiment as well as being a ''flux enhancer''.

  15. The uranium cylinder assay system for enrichment plant safeguards

    SciTech Connect (OSTI)

    Miller, Karen A [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Marlow, Johnna B [Los Alamos National Laboratory; Menlove, Howard O [Los Alamos National Laboratory; Rael, Carlos D [Los Alamos National Laboratory; Iwamoto, Tomonori [JNFL; Tamura, Takayuki [JNFL; Aiuchi, Syun [JNFL

    2010-01-01T23:59:59.000Z

    Safeguarding sensitive fuel cycle technology such as uranium enrichment is a critical component in preventing the spread of nuclear weapons. A useful tool for the nuclear materials accountancy of such a plant would be an instrument that measured the uranium content of UF{sub 6} cylinders. The Uranium Cylinder Assay System (UCAS) was designed for Japan Nuclear Fuel Limited (JNFL) for use in the Rokkasho Enrichment Plant in Japan for this purpose. It uses total neutron counting to determine uranium mass in UF{sub 6} cylinders given a known enrichment. This paper describes the design of UCAS, which includes features to allow for unattended operation. It can be used on 30B and 48Y cylinders to measure depleted, natural, and enriched uranium. It can also be used to assess the amount of uranium in decommissioned equipment and waste containers. Experimental measurements have been carried out in the laboratory and these are in good agreement with the Monte Carlo modeling results.

  16. 2013 Domestic Uranium Production Report

    E-Print Network [OSTI]

    Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA.S. Energy Information Administration | 2013 Domestic Uranium Production Report iii Preface The U.S. Energy://www.eia.doe.gov/glossary/. #12;U.S. Energy Information Administration | 2013 Domestic Uranium Production Report iv Contents

  17. Overview of the Capstone Depleted Uranium Study of Aerosols from Impact with Armored Vehicles: Test Setup and Aerosol Generation, Characterization, and Application in Assessing Dose and Risk

    SciTech Connect (OSTI)

    Parkhurst, MaryAnn; Guilmette, Raymond A.

    2009-03-01T23:59:59.000Z

    The Capstone Depleted Uranium (DU) Aerosol Characterization and Risk Assessment Study was conducted to generate data about DU aerosols generated during the perforation of armored combat vehicles with large-caliber DU penetrators, and to apply the data in assessments of human health risks to personnel exposed to these aerosols, primarily through inhalation, during the 1991 Gulf War or in future military operations. The Capstone study consisted of two components: 1) generating, sampling and characterizing DU aerosols by firing at and perforating combat vehicles and 2) applying the source-term quantities and characteristics of the aerosols to the evaluation of doses and risks. This paper reviews the background of the study including the bases for the study, previous reviews of DU particles and health assessments from DU used by the U.S. military, the objectives of the study components, the participants and oversight teams, and the types of exposures it was intended to evaluate. It then discusses exposure scenarios used in the dose and risk assessment and provides an overview of how the field tests and dose and risk assessments were conducted.

  18. Domestic Uranium Production Report

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9, 2015Year109 AppendixCostsDistributedSep-1410. Uranium

  19. Domestic Uranium Production Report

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9, 2015Year109 AppendixCostsDistributedSep-1410. Uranium9.

  20. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium from U.S.

  1. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium from U.S.2.

  2. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium from U.S.2.3.

  3. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium from U.S.2.3.5.

  4. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium from U.S.2.3.5.3.

  5. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium from

  6. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium froma. Uraniumb.

  7. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium froma. Uraniumb.7.

  8. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium froma.

  9. Uranium Marketing Annual Report -

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uranium froma.9.

  10. Fingerprinting Uranium | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityField Office FinalFinancingFingerprinting Uranium

  11. APPENDIX J Partition Coefficients For Uranium

    E-Print Network [OSTI]

    APPENDIX J Partition Coefficients For Uranium #12;Appendix J Partition Coefficients For Uranium J.1.0 Background The review of uranium Kd values obtained for a number of soils, crushed rock and their effects on uranium adsorption on soils are discussed below. The solution pH was also used as the basis

  12. The End of Cheap Uranium

    E-Print Network [OSTI]

    Michael Dittmar

    2011-06-21T23:59:59.000Z

    Historic data from many countries demonstrate that on average no more than 50-70% of the uranium in a deposit could be mined. An analysis of more recent data from Canada and Australia leads to a mining model with an average deposit extraction lifetime of 10+- 2 years. This simple model provides an accurate description of the extractable amount of uranium for the recent mining operations. Using this model for all larger existing and planned uranium mines up to 2030, a global uranium mining peak of at most 58 +- 4 ktons around the year 2015 is obtained. Thereafter we predict that uranium mine production will decline to at most 54 +- 5 ktons by 2025 and, with the decline steepening, to at most 41 +- 5 ktons around 2030. This amount will not be sufficient to fuel the existing and planned nuclear power plants during the next 10-20 years. In fact, we find that it will be difficult to avoid supply shortages even under a slow 1%/year worldwide nuclear energy phase-out scenario up to 2025. We thus suggest that a worldwide nuclear energy phase-out is in order. If such a slow global phase-out is not voluntarily effected, the end of the present cheap uranium supply situation will be unavoidable. The result will be that some countries will simply be unable to afford sufficient uranium fuel at that point, which implies involuntary and perhaps chaotic nuclear phase-outs in those countries involving brownouts, blackouts, and worse.

  13. Enclosure 1 -CCP-AK-INL-004, Table 5-2 (1 page) Table 5-2. Isotopic Compositions of Rocky Flats Plutonium and Uranium

    E-Print Network [OSTI]

    Flats Plutonium and Uranium Weapons-Grade Plutonium Enriched Uranium Depleted Uranium Plutonium-238 0.01 ­ 0.05% Uranium-234 0.1 ­ 1.02% Uranium-234 0.0006% Plutonium-239 92.8 ­ 94.4% Uranium-235 90 ­ 94% Uranium-235 0.2 ­ 0.3% Plutonium-240 4.85 ­ 6.5% Uranium-236 0.4 ­ 0.5% Uranium-238 99.7 ­ 99.8% Plutonium

  14. DEPARTMENT OF ENERGY Excess Uranium Management: Effects of DOE...

    Broader source: Energy.gov (indexed) [DOE]

    Excess Uranium Management: Effects of DOE Transfers of Excess Uranium on Domestic Uranium Mining, Conversion, and Enrichment Industries; Request for Information AGENCY: Office of...

  15. Laser induced phosphorescence uranium analysis

    DOE Patents [OSTI]

    Bushaw, Bruce A. (Kennewick, WA)

    1986-01-01T23:59:59.000Z

    A method is described for measuring the uranium content of aqueous solutions wherein a uranyl phosphate complex is irradiated with a 5 nanosecond pulse of 425 nanometer laser light and resultant 520 nanometer emissions are observed for a period of 50 to 400 microseconds after the pulse. Plotting the natural logarithm of emission intensity as a function of time yields an intercept value which is proportional to uranium concentration.

  16. Laser induced phosphorescence uranium analysis

    DOE Patents [OSTI]

    Bushaw, B.A.

    1983-06-10T23:59:59.000Z

    A method is described for measuring the uranium content of aqueous solutions wherein a uranyl phosphate complex is irradiated with a 5 nanosecond pulse of 425 nanometer laser light and resultant 520 nanometer emissions are observed for a period of 50 to 400 microseconds after the pulse. Plotting the natural logarithm of emission intensity as a function of time yields an intercept value which is proportional to uranium concentration.

  17. acute tryptophan depletion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Psychopharmacology ISSN 0269-8811 SAGE Publications Ltd 12 Review The Toxicity of Depleted Uranium CiteSeer Summary: Abstract: Depleted uranium (DU) is an emerging...

  18. Standard Test Method for Determination of Uranium, Oxygen to Uranium (O/U), and Oxygen to Metal (O/M) in Sintered Uranium Dioxide and Gadolinia-Uranium Dioxide Pellets by Atmospheric Equilibration

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01T23:59:59.000Z

    Standard Test Method for Determination of Uranium, Oxygen to Uranium (O/U), and Oxygen to Metal (O/M) in Sintered Uranium Dioxide and Gadolinia-Uranium Dioxide Pellets by Atmospheric Equilibration

  19. Nuclear power fleets and uranium resources recovered from phosphates

    SciTech Connect (OSTI)

    Gabriel, S.; Baschwitz, A.; Mathonniere, G. [CEA, DEN/DANS/I-tese, F-91191 Gif-sur-Yvette (France)

    2013-07-01T23:59:59.000Z

    Current light water reactors (LWR) burn fissile uranium, whereas some future reactors, as Sodium fast reactors (SFR) will be capable of recycling their own plutonium and already-extracted depleted uranium. This makes them a feasible solution for the sustainable development of nuclear energy. Nonetheless, a sufficient quantity of plutonium is needed to start up an SFR, with the plutonium already being produced in light water reactors. The availability of natural uranium therefore has a direct impact on the capacity of the reactors (both LWR and SFR) that we can build. It is therefore important to have an accurate estimate of the available uranium resources in order to plan for the world's future nuclear reactor fleet. This paper discusses the correspondence between the resources (uranium and plutonium) and the nuclear power demand. Sodium fast reactors will be built in line with the availability of plutonium, including fast breeders when necessary. Different assumptions on the global uranium resources are taken into consideration. The largely quoted estimate of 22 Mt of uranium recovered for phosphate rocks can be seriously downscaled. Based on our current knowledge of phosphate resources, 4 Mt of recoverable uranium already seems to be an upper bound value. The impact of the downscaled estimate on the deployment of a nuclear fleet is assessed accordingly. (authors)

  20. Evidence of uranium biomineralization in sandstone-hosted roll-front uranium deposits, northwestern China

    E-Print Network [OSTI]

    Fayek, Mostafa

    Evidence of uranium biomineralization in sandstone-hosted roll-front uranium deposits, northwestern Available online 25 January 2005 Abstract We show evidence that the primary uranium minerals, uraninite-front uranium deposits, Xinjiang, northwestern China were biogenically precipitated and psuedomorphically

  1. Inherently safe in situ uranium recovery

    DOE Patents [OSTI]

    Krumhansl, James L; Brady, Patrick V

    2014-04-29T23:59:59.000Z

    An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

  2. The End of Cheap Uranium

    E-Print Network [OSTI]

    Dittmar, Michael

    2011-01-01T23:59:59.000Z

    Historic data from many countries demonstrate that on average no more than 50-70% of the uranium in a deposit could be mined. An analysis of more recent data from Canada and Australia leads to a mining model with an average deposit extraction lifetime of 10+- 2 years. This simple model provides an accurate description of the extractable amount of uranium for the recent mining operations. Using this model for all larger existing and planned uranium mines up to 2030, a global uranium mining peak of at most 58 +- 4 ktons around the year 2015 is obtained. Thereafter we predict that uranium mine production will decline to at most 54 +- 5 ktons by 2025 and, with the decline steepening, to at most 41 +- 5 ktons around 2030. This amount will not be sufficient to fuel the existing and planned nuclear power plants during the next 10-20 years. In fact, we find that it will be difficult to avoid supply shortages even under a slow 1%/year worldwide nuclear energy phase-out scenario up to 2025. We thus suggest that a world...

  3. Disposition of Depleted Uranium Oxide

    SciTech Connect (OSTI)

    Crandall, J.L.

    2001-08-13T23:59:59.000Z

    This document summarizes environmental information which has been collected up to June 1983 at Savannah River Plant. Of particular interest is an updating of dose estimates from changes in methodology of calculation, lower cesium transport estimates from Steel Creek, and new sports fish consumption data for the Savannah River. The status of various permitting requirements are also discussed.

  4. High strength uranium-tungsten alloys

    DOE Patents [OSTI]

    Dunn, Paul S. (Santa Fe, NM); Sheinberg, Haskell (Los Alamos, NM); Hogan, Billy M. (Los Alamos, NM); Lewis, Homer D. (Bayfield, CO); Dickinson, James M. (Los Alamos, NM)

    1991-01-01T23:59:59.000Z

    Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

  5. High strength uranium-tungsten alloy process

    DOE Patents [OSTI]

    Dunn, Paul S. (Santa Fe, NM); Sheinberg, Haskell (Los Alamos, NM); Hogan, Billy M. (Los Alamos, NM); Lewis, Homer D. (Bayfield, CO); Dickinson, James M. (Los Alamos, NM)

    1990-01-01T23:59:59.000Z

    Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

  6. Clean Air Act Requirements: Uranium Mill Tailings

    E-Print Network [OSTI]

    EPA'S Clean Air Act Requirements: Uranium Mill Tailings Radon Emissions Rulemaking Reid J. Rosnick requirements for operating uranium mill tailings (Subpart W) Status update on Subpart W activities Outreach/Communications #12;3 EPA Regulatory Requirements for Operating Uranium Mill Tailings (Clean Air Act) · 40 CFR 61

  7. URANIUM MILL TAILINGS RADON FLUX CALCULATIONS

    E-Print Network [OSTI]

    URANIUM MILL TAILINGS RADON FLUX CALCULATIONS PIÃ?ON RIDGE PROJECT MONTROSE COUNTY, COLORADO Inc. (Golder) was commissioned by EFRC to evaluate the operations of the uranium mill tailings storage in this report were conducted using the WISE Uranium Mill Tailings Radon Flux Calculator, as updated on November

  8. Remediation and Recovery of Uranium from Contaminated

    E-Print Network [OSTI]

    Lovley, Derek

    Remediation and Recovery of Uranium from Contaminated Subsurface Environments with Electrodes K E L that Geobacter species can effectively remove uranium from contaminated groundwater by reducing soluble U was stably precipitated until reoxidized in the presence of oxygen. When an electrode was placed in uranium

  9. Uranium Watch REGULATORY CONFUSION: FEDERALAND STATE

    E-Print Network [OSTI]

    Uranium Watch Report REGULATORY CONFUSION: FEDERALAND STATE ENFORCEMENT OF 40 C.F.R. PART 61 SUBPART W INTRODUCTION 1. This Uranium Watch Report, Regulatory Confusion: Federal and State Enforcement at the White Mesa Uranium Mill, San Juan County, Utah. 2. The DAQ, a Division of the Utah Department

  10. D Riso-R-429 Automated Uranium

    E-Print Network [OSTI]

    routinely used analytical techniques for uranium determina- tions in geological samples, fissionCM i D Riso-R-429 Automated Uranium Analysis by Delayed-Neutron Counting H. Kunzendorf, L. Løvborg AUTOMATED URANIUM ANALYSIS BY DELAYED-NEUTRON COUNTING H. Kunzendorf, L. Løvborg and E.M. Christiansen

  11. Y-12 Uranium Exposure Study

    SciTech Connect (OSTI)

    Eckerman, K.F.; Kerr, G.D.

    1999-08-05T23:59:59.000Z

    Following the recent restart of operations at the Y-12 Plant, the Radiological Control Organization (RCO) observed that the enriched uranium exposures appeared to involve insoluble rather than soluble uranium that presumably characterized most earlier Y-12 operations. These observations necessitated changes in the bioassay program, particularly the need for routine fecal sampling. In addition, it was not reasonable to interpret the bioassay data using metabolic parameter values established during earlier Y-12 operations. Thus, the recent urinary and fecal bioassay data were interpreted using the default guidance in Publication 54 of the International Commission on Radiological Protection (ICRP); that is, inhalation of Class Y uranium with an activity median aerodynamic diameter (AMAD) of 1 {micro}m. Faced with apparently new workplace conditions, these actions were appropriate and ensured a cautionary approach to worker protection. As additional bioassay data were accumulated, it became apparent that the data were not consistent with Publication 54. Therefore, this study was undertaken to examine the situation.

  12. The non-aqueous chemistry of uranium has been an active area of exploration in recent decades1,2

    E-Print Network [OSTI]

    Cai, Long

    -purity depleted uranium produced as a by-product of nuclear isotope enrichment programmes. The early actinideThe non-aqueous chemistry of uranium has been an active area of exploration in recent decades1 for uranium will be created in part by the quest of researchers to understand the properties and potential

  13. Uranium Powder Production Via Hydride Formation and Alpha Phase Sintering of Uranium and Uranium-zirconium Alloys for Advanced Nuclear Fuel Applications

    E-Print Network [OSTI]

    Garnetti, David J.

    2010-07-14T23:59:59.000Z

    The research in this thesis covers the design and implementation of a depleted uranium (DU) powder production system and the initial results of a DU-Zr-Mg alloy alpha phase sintering experiment where the Mg is a surrogate for Pu and Am. The powder...

  14. Electron Backscatter Diffraction (EBSD) Characterization of Uranium and Uranium Alloys

    SciTech Connect (OSTI)

    McCabe, Rodney J. [Los Alamos National Laboratory; Kelly, Ann Marie [Los Alamos National Laboratory; Clarke, Amy J. [Los Alamos National Laboratory; Field, Robert D. [Los Alamos National Laboratory; Wenk, H. R. [University of California, Berkeley

    2012-07-25T23:59:59.000Z

    Electron backscatter diffraction (EBSD) was used to examine the microstructures of unalloyed uranium, U-6Nb, U-10Mo, and U-0.75Ti. For unalloyed uranium, we used EBSD to examine the effects of various processes on microstructures including casting, rolling and forming, recrystallization, welding, and quasi-static and shock deformation. For U-6Nb we used EBSD to examine the microstructural evolution during shape memory loading. EBSD was used to study chemical homogenization in U-10Mo, and for U-0.75Ti, we used EBSD to study the microstructure and texture evolution during thermal cycling and deformation. The studied uranium alloys have significant microstructural and chemical differences and each of these alloys presents unique preparation challenges. Each of the alloys is prepared by a sequence of mechanical grinding and polishing followed by electropolishing with subtle differences between the alloys. U-6Nb and U-0.75Ti both have martensitic microstructures and both require special care in order to avoid mechanical polishing artifacts. Unalloyed uranium has a tendency to rapidly oxidize when exposed to air and a two-step electropolish is employed, the first step to remove the damaged surface layer resulting from the mechanical preparation and the second step to passivate the surface. All of the alloying additions provide a level of surface passivation and different one and two step electropolishes are employed to create good EBSD surfaces. Because of its low symmetry crystal structure, uranium exhibits complex deformation behavior including operation of multiple deformation twinning modes. EBSD was used to observe and quantify twinning contributions to deformation and to examine the fracture behavior. Figure 1 shows a cross section of two mating fracture surfaces in cast uranium showing the propensity of deformation twinning and intergranular fracture largely between dissimilarly oriented grains. Deformation of U-6Nb in the shape memory regime occurs by the motion of twin boundaries formed during the martensitic transformation. Deformation actually results in a coarsening of the microstructure making EBSD more practical following a limited amount of strain. Figure 2 shows the microstructure resulting from 6% compression. Casting of U-10Mo results in considerable chemical segregation as is apparent in Figure 2a. The segregation subsists through rolling and heat treatment processes as shown in Figure 2b. EBSD was used to study the effects of homogenization time and temperature on chemical heterogeneity. It was found that times and temperatures that result in a chemically homogeneous microstructure also result in a significant increase in grain size. U-0.75Ti forms an acicular martinsite as shown in Figure 4. This microstructure prevails through cycling into the higher temperature solid uranium phases.

  15. Process for alloying uranium and niobium

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Farragut, TN); Northcutt, Jr., Walter G. (Oak Ridge, TN); Masters, David R. (Knoxville, TN); Chapman, Lloyd R. (Knoxville, TN)

    1991-01-01T23:59:59.000Z

    Alloys such as U-6Nb are prepared by forming a stacked sandwich array of uraniun sheets and niobium powder disposed in layers between the sheets, heating the array in a vacuum induction melting furnace to a temperature such as to melt the uranium, holding the resulting mixture at a temperature above the melting point of uranium until the niobium dissolves in the uranium, and casting the uranium-niobium solution. Compositional uniformity in the alloy product is enabled by use of the sandwich structure of uranium sheets and niobium powder.

  16. Uranium 2014 resources, production and demand

    E-Print Network [OSTI]

    Organisation for Economic Cooperation and Development. Paris

    2014-01-01T23:59:59.000Z

    Published every other year, Uranium Resources, Production, and Demand, or the "Red Book" as it is commonly known, is jointly prepared by the OECD Nuclear Energy Agency and the International Atomic Energy Agency. It is the recognised world reference on uranium and is based on official information received from 43 countries. It presents the results of a thorough review of world uranium supplies and demand and provides a statistical profile of the world uranium industry in the areas of exploration, resource estimates, production and reactor-related requirements. It provides substantial new information from all major uranium production centres in Africa, Australia, Central Asia, Eastern Europe and North America. Long-term projections of nuclear generating capacity and reactor-related uranium requirements are provided as well as a discussion of long-term uranium supply and demand issues. This edition focuses on recent price and production increases that could signal major changes in the industry.

  17. Uranium 2005 resources, production and demand

    E-Print Network [OSTI]

    Organisation for Economic Cooperation and Development. Paris

    2006-01-01T23:59:59.000Z

    Published every other year, Uranium Resources, Production, and Demand, or the "Red Book" as it is commonly known, is jointly prepared by the OECD Nuclear Energy Agency and the International Atomic Energy Agency. It is the recognised world reference on uranium and is based on official information received from 43 countries. This 21st edition presents the results of a thorough review of world uranium supplies and demand as of 1st January 2005 and provides a statistical profile of the world uranium industry in the areas of exploration, resource estimates, production and reactor-related requirements. It provides substantial new information from all major uranium production centres in Africa, Australia, Central Asia, Eastern Europe and North America. Projections of nuclear generating capacity and reactor-related uranium requirements through 2025 are provided as well as a discussion of long-term uranium supply and demand issues. This edition focuses on recent price and production increases that could signal major c...

  18. Reports on investigations of uranium anomalies. National Uranium Resource Evaluation

    SciTech Connect (OSTI)

    Goodknight, C.S.; Burger, J.A. (comps.) [comps.

    1982-10-01T23:59:59.000Z

    During the National Uranium Resource Evaluation (NURE) program, conducted for the US Department of Energy (DOE) by Bendix Field Engineering Corporation (BFEC), radiometric and geochemical surveys and geologic investigations detected anomalies indicative of possible uranium enrichment. Data from the Aerial Radiometric and Magnetic Survey (ARMS) and the Hydrogeochemical and Stream-Sediment Reconnaissance (HSSR), both of which were conducted on a national scale, yielded numerous anomalies that may signal areas favorable for the occurrence of uranium deposits. Results from geologic evaluations of individual 1/sup 0/ x 2/sup 0/ quadrangles for the NURE program also yielded anomalies, which could not be adequately checked during scheduled field work. Included in this volume are individual reports of field investigations for the following six areas which were shown on the basis of ARMS, HSSR, and (or) geologic data to be anomalous: (1) Hylas zone and northern Richmond basin, Virginia; (2) Sischu Creek area, Alaska; (3) Goodman-Dunbar area, Wisconsin; (4) McCaslin syncline, Wisconsin; (5) Mt. Withington Cauldron, Socorro County, New Mexico; (6) Lake Tecopa, Inyo County, California. Field checks were conducted in each case to verify an indicated anomalous condition and to determine the nature of materials causing the anomaly. The ultimate objective of work is to determine whether favorable conditions exist for the occurrence of uranium deposits in areas that either had not been previously evaluated or were evaluated before data from recent surveys were available. Most field checks were of short duration (2 to 5 days). The work was done by various investigators using different procedures, which accounts for variations in format in their reports. All papers have been abstracted and indexed.

  19. Global terrestrial uranium supply and its policy implications : a probabilistic projection of future uranium costs

    E-Print Network [OSTI]

    Matthews, Isaac A

    2010-01-01T23:59:59.000Z

    An accurate outlook on long-term uranium resources is critical in forecasting uranium costresource relationships, and for energy policy planning as regards the development and deployment of nuclear fuel cycle alternatives. ...

  20. Conversion and Blending Facility highly enriched uranium to low enriched uranium as oxide. Revision 1

    SciTech Connect (OSTI)

    NONE

    1995-07-05T23:59:59.000Z

    This Conversion and Blending Facility (CBF) will have two missions: (1) convert HEU materials into pure HEU oxide and (2) blend the pure HEU oxide with depleted and natural uranium oxide to produce an LWR grade LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. To the extent practical, the chemical and isotopic concentrations of blended LEU product will be held within the specifications required for LWR fuel. Such blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry. Otherwise, blended LEU will be produced as a waste suitable for storage or disposal.

  1. Uranium 2009 resources, production and demand

    E-Print Network [OSTI]

    Organisation for Economic Cooperation and Development. Paris

    2010-01-01T23:59:59.000Z

    With several countries currently building nuclear power plants and planning the construction of more to meet long-term increases in electricity demand, uranium resources, production and demand remain topics of notable interest. In response to the projected growth in demand for uranium and declining inventories, the uranium industry – the first critical link in the fuel supply chain for nuclear reactors – is boosting production and developing plans for further increases in the near future. Strong market conditions will, however, be necessary to trigger the investments required to meet projected demand. The "Red Book", jointly prepared by the OECD Nuclear Energy Agency and the International Atomic Energy Agency, is a recognised world reference on uranium. It is based on information compiled in 40 countries, including those that are major producers and consumers of uranium. This 23rd edition provides a comprehensive review of world uranium supply and demand as of 1 January 2009, as well as data on global ur...

  2. Uranium Metal Analysis via Selective Dissolution

    SciTech Connect (OSTI)

    Delegard, Calvin H.; Sinkov, Sergey I.; Schmidt, Andrew J.; Chenault, Jeffrey W.

    2008-09-10T23:59:59.000Z

    Uranium metal, which is present in sludge held in the Hanford Site K West Basin, can create hazardous hydrogen atmospheres during sludge handling, immobilization, or subsequent transport and storage operations by its oxidation/corrosion in water. A thorough knowledge of the uranium metal concentration in sludge therefore is essential to successful sludge management and waste process design. The goal of this work was to establish a rapid routine analytical method to determine uranium metal concentrations as low as 0.03 wt% in sludge even in the presence of up to 1000-fold higher total uranium concentrations (i.e., up to 30 wt% and more uranium) for samples to be taken during the upcoming sludge characterization campaign and in future analyses for sludge handling and processing. This report describes the experiments and results obtained in developing the selective dissolution technique to determine uranium metal concentration in K Basin sludge.

  3. L'URANIUM ET LES ARMES L'URANIUM APPAUVRI. Pierre Roussel*

    E-Print Network [OSTI]

    Boyer, Edmond

    L'URANIUM ET LES ARMES � L'URANIUM APPAUVRI. Pierre Roussel* Institut de Physique Nucléaire, CNRS massivement dans la guerre du Golfe, des obus anti- chars ont été utilisés, avec des "charges d'uranium, avec une charge de 300 g d'uranium et tiré par des avions, l'autre de 120 mm de diamètre avec une

  4. Dry process fluorination of uranium dioxide using ammonium bifluoride

    E-Print Network [OSTI]

    Yeamans, Charles Burnett, 1978-

    2003-01-01T23:59:59.000Z

    An experimental study was conducted to determine the practicality of various unit operations for fluorination of uranium dioxide. The objective was to prepare ammonium uranium fluoride double salts from uranium dioxide and ...

  5. SHEEP MOUNTAIN URANIUM PROJECT CROOKS GAP, WYOMING

    E-Print Network [OSTI]

    ;PROJECT OVERVIEW ·Site Location·Site Location ·Fremont , Wyoming ·Existing Uranium Mine Permit 381C·Existing Uranium Mine Permit 381C ·Historical Operation ·Western Nuclear Crooks Gap Project ·Mined 1956 ­ 1988 and Open Pit Mining ·Current Mine Permit (381C) ·Updating POO, Reclamation Plan & Bond ·Uranium Recovery

  6. Review of uranium bioassay techniques

    SciTech Connect (OSTI)

    Bogard, J.S.

    1996-04-01T23:59:59.000Z

    A variety of analytical techniques is available for evaluating uranium in excreta and tissues at levels appropriate for occupational exposure control and evaluation. A few (fluorometry, kinetic phosphorescence analysis, {alpha}-particle spectrometry, neutron irradiation techniques, and inductively-coupled plasma mass spectrometry) have also been demonstrated as capable of determining uranium in these materials at levels comparable to those which occur naturally. Sample preparation requirements and isotopic sensitivities vary widely among these techniques and should be considered carefully when choosing a method. This report discusses analytical techniques used for evaluating uranium in biological matrices (primarily urine) and limits of detection reported in the literature. No cost comparison is attempted, although references are cited which address cost. Techniques discussed include: {alpha}-particle spectrometry; liquid scintillation spectrometry, fluorometry, phosphorometry, neutron activation analysis, fission-track counting, UV-visible absorption spectrophotometry, resonance ionization mass spectrometry, and inductively-coupled plasma mass spectrometry. A summary table of reported limits of detection and of the more important experimental conditions associated with these reported limits is also provided.

  7. Uranium Tris-aryloxide Derivatives Supported by Triazacyclononane: Engendering a Reactive Uranium(III)

    E-Print Network [OSTI]

    Meyer, Karsten

    , we are currently investigating the coordina- tion chemistry of uranium metal centers with classicalUranium Tris-aryloxide Derivatives Supported by Triazacyclononane: Engendering a Reactive Uranium, and Karsten Meyer* Contribution from the Department of Chemistry and Biochemistry, UniVersity of California

  8. Statistical data of the uranium industry

    SciTech Connect (OSTI)

    none,

    1982-01-01T23:59:59.000Z

    Statistical Data of the Uranium Industry is a compendium of information relating to US uranium reserves and potential resources and to exploration, mining, milling, and other activities of the uranium industry through 1981. The statistics are based primarily on data provided voluntarily by the uranium exploration, mining, and milling companies. The compendium has been published annually since 1968 and reflects the basic programs of the Grand Junction Area Office (GJAO) of the US Department of Energy. The production, reserves, and drilling information is reported in a manner which avoids disclosure of proprietary information.

  9. Adsorptive Stripping Voltammetric Measurements of Trace Uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurements of Trace Uranium at the Bismuth Film Electrode. Abstract: Bismuth-coated carbon-fiber electrodes have been successfully applied for adsorptive-stripping...

  10. Biogeochemical Processes In Ethanol Stimulated Uranium Contaminated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A laboratory incubation experiment was conducted with uranium contaminated subsurface sediment to assess the geochemical and microbial community response to ethanol amendment. A...

  11. Colorimetric detection of uranium in water

    DOE Patents [OSTI]

    DeVol, Timothy A. (Clemson, SC); Hixon, Amy E. (Piedmont, SC); DiPrete, David P. (Evans, GA)

    2012-03-13T23:59:59.000Z

    Disclosed are methods, materials and systems that can be used to determine qualitatively or quantitatively the level of uranium contamination in water samples. Beneficially, disclosed systems are relatively simple and cost-effective. For example, disclosed systems can be utilized by consumers having little or no training in chemical analysis techniques. Methods generally include a concentration step and a complexation step. Uranium concentration can be carried out according to an extraction chromatographic process and complexation can chemically bind uranium with a detectable substance such that the formed substance is visually detectable. Methods can detect uranium contamination down to levels even below the MCL as established by the EPA.

  12. Uranium Weapons Components Successfully Dismantled | National...

    National Nuclear Security Administration (NNSA)

    Successfully Dismantled March 20, 2007 Uranium Weapons Components Successfully Dismantled Oak Ridge, TN Continuing its efforts to reduce the size of the U.S. nuclear weapons...

  13. High strength and density tungsten-uranium alloys

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1993-01-01T23:59:59.000Z

    Alloys of tungsten and uranium and a method for making the alloys. The amount of tungsten present in the alloys is from about 55 vol % to about 85 vol %. A porous preform is made by sintering consolidated tungsten powder. The preform is impregnated with molten uranium such that (1) uranium fills the pores of the preform to form uranium in a tungsten matrix or (2) uranium dissolves portions of the preform to form a continuous uranium phase containing tungsten particles.

  14. Distribution of uranium-bearing phases in soils from Fernald

    SciTech Connect (OSTI)

    Buck, E.C.; Brown, N.R.; Dietz, N.L.

    1993-12-31T23:59:59.000Z

    Electron beam techniques have been used to characterize uranium-contaminated soils and the Fernald Site, Ohio. Uranium particulates have been deposited on the soil through chemical spills and from the operation of an incinerator plant on the site. The major uranium phases have been identified by electron microscopy as uraninite, autunite, and uranium phosphite [U(PO{sub 3}){sub 4}]. Some of the uranium has undergone weathering resulting in the redistribution of uranium within the soil.

  15. Uranium in the Oatman Creek granite of Central Texas and its economic potential

    E-Print Network [OSTI]

    Conrad, Curtis Paul

    1982-01-01T23:59:59.000Z

    , however, the need to explore for new materials containing uranium will incr ease as the high grade sedimentary uranium deposits become depleted. A logical place to begin this search lies with the source rock for many of the known sedimentary uranium... potential uranium source. Th1s study focuses on an 80 acre outcrop of the Oatman Creek granite known as Bear Mountain, in Gillespie County, Texas. The gran1te is a medium-grained, gray to pink rock. Nodal analysis indicates the composit1on 1s 35. 5...

  16. President Truman Increases Production of Uranium and Plutonium...

    National Nuclear Security Administration (NNSA)

    Increases Production of Uranium and Plutonium October 09, 1950 President Truman Increases Production of Uranium and Plutonium Washington, DC President Truman approves a 1.4...

  17. Atomistic Simulations of Uranium Incorporation into Iron (Hydr...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Uranium Incorporation into Iron (Hydr)Oxides. Atomistic Simulations of Uranium Incorporation into Iron (Hydr)Oxides. Abstract: Atomistic simulations were carried out to...

  18. Toxic Substances Control Act Uranium Enrichment Federal Facility...

    Office of Environmental Management (EM)

    Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance Agreement Toxic Substances Control Act Uranium Enrichment Federal Facility Compliance Agreement Toxic...

  19. Geochemical Controls on Contaminant Uranium in Vadose Hanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controls on Contaminant Uranium in Vadose Hanford Formation Sediments at the 200 Area and 300 Area, Hanford Site, Geochemical Controls on Contaminant Uranium in Vadose Hanford...

  20. Microbial Reduction of Uranium under Iron- and Sulfate-reducing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Uranium under Iron- and Sulfate-reducing Conditions: Effect of Amended Goethite on Microbial Community Microbial Reduction of Uranium under Iron- and Sulfate-reducing Conditions:...

  1. Uncertainty analysis of multi-rate kinetics of uranium desorption...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Uncertainty analysis of multi-rate kinetics of uranium desorption from sediments. Uncertainty analysis of multi-rate kinetics of uranium desorption from sediments. Abstract: A...

  2. Legacy Management Work Progresses on Defense-Related Uranium...

    Broader source: Energy.gov (indexed) [DOE]

    Most recently, LM visited 84 defense-related legacy uranium mine sites located within 11 uranium mining districts in 6 western states. At these sites, photographs and global...

  3. Highly Enriched Uranium Materials Facility, Major Design Changes...

    Energy Savers [EERE]

    Highly Enriched Uranium Materials Facility, Major Design Changes Late...Lessons Learned Report, NNSA, Dec 2010 Highly Enriched Uranium Materials Facility, Major Design Changes...

  4. Record of Decision for the Uranium Leasing Program Programmatic...

    Energy Savers [EERE]

    Record of Decision for the Uranium Leasing Program Programmatic Environmental Impact Statement Record of Decision for the Uranium Leasing Program Programmatic Environmental Impact...

  5. DOE Extends Public Comment Period for the Draft Uranium Leasing...

    Office of Environmental Management (EM)

    Extends Public Comment Period for the Draft Uranium Leasing Program Programmatic Environmental Impact Statement DOE Extends Public Comment Period for the Draft Uranium Leasing...

  6. Sequestering Uranium from Seawater: Binding Strength and Modes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sequestering Uranium from Seawater: Binding Strength and Modes of Uranyl Complexes with Glutarimidedioxime Sequestering Uranium from Seawater: Binding Strength and Modes of Uranyl...

  7. a. ASTM Standard C787-11, Standard Specification for Uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in support of a request for proposals to design, build, and operate facilities to convert depleted uranium hexafluoride (DUF 6 ) to more chemically stable forms. On page C-8 in the...

  8. Uranium Certified Reference Materials Price List | U.S. DOE Office...

    Office of Science (SC) Website

    Hexafluoride (4.5% U-235) 1700 g 59,420 . .pdf file (50KB) . .pdf file (63KB) A 115 Uranium (Depleted) Metal (0.99977 g Ug) 75 g 2,980 . .pdf file (121KB) . .pdf file...

  9. Preserving Ultra-Pure Uranium-233

    SciTech Connect (OSTI)

    Krichinsky, Alan M [ORNL; Goldberg, Dr. Steven A. [DOE SC - Chicago Office; Hutcheon, Dr. Ian D. [Lawrence Livermore National Laboratory (LLNL)

    2011-10-01T23:59:59.000Z

    Uranium-233 ({sup 233}U) is a synthetic isotope of uranium formed under reactor conditions during neutron capture by natural thorium ({sup 232}Th). At high purities, this synthetic isotope serves as a crucial reference material for accurately quantifying and characterizing uranium-bearing materials assays and isotopic distributions for domestic and international nuclear safeguards. Separated, high purity {sup 233}U is stored in vaults at Oak Ridge National Laboratory (ORNL). These materials represent a broad spectrum of {sup 233}U from the standpoint of isotopic purity - the purest being crucial for precise analyses in safeguarding uranium. All {sup 233}U at ORNL is currently scheduled to be disposed of by down-blending with depleted uranium beginning in 2015. This will reduce safety concerns and security costs associated with storage. Down-blending this material will permanently destroy its potential value as a certified reference material for use in uranium analyses. Furthermore, no credible options exist for replacing {sup 233}U due to the lack of operating production capability and the high cost of restarting currently shut down capabilities. A study was commissioned to determine the need for preserving high-purity {sup 233}U. This study looked at the current supply and the historical and continuing domestic need for this crucial isotope. It examined the gap in supplies and uses to meet domestic needs and extrapolated them in the context of international safeguards and security activities - superimposed on the recognition that existing supplies are being depleted while candidate replacement material is being prepared for disposal. This study found that the total worldwide need by this projection is at least 850 g of certified {sup 233}U reference material over the next 50 years. This amount also includes a strategic reserve. To meet this need, 18 individual items totaling 959 g of {sup 233}U were identified as candidates for establishing a lasting supply of certified reference materials (CRM), all having an isotopic purity of at least 99.4% {sup 233}U and including materials up to 99.996% purity. Current plans include rescuing the purest {sup 233}U materials during a 3-year project beginning in FY 2012 in three phases involving preparations, handling preserved materials, and cleanup. The first year will involve preparations for handling the rescued material for sampling, analysis, distribution, and storage. Such preparations involve modifying or developing work control documents and physical preparations in the laboratory, which include preparing space for new material-handling equipment and procuring and (in some cases) refurbishing equipment needed for handling {sup 233}U or qualifying candidate CRM. Once preparations are complete, an evaluation of readiness will be conducted by independent reviewers to verify that the equipment, work controls, and personnel are ready for operations involving handling radioactive materials with nuclear criticality safety as well as radiological control requirements. The material-handling phase will begin in FY 2013 and be completed early in FY 2014, as currently scheduled. Material handling involves retrieving candidate CRM items from the ORNL storage facility and shipping them to another laboratory at ORNL; receiving and handling rescued items at the laboratory (including any needed initial processing, acquisition and analysis of samples from each item, and preparation for shipment); and shipping bulk material to destination labs or to a yet-to-be-designated storage location. There are seven groups of {sup 233}U identified for handling based on isotopic purity that require the utmost care to prevent cross-contamination. The last phase, cleanup, also will be completed in 2014. It involves cleaning and removing the equipment and material-handling boxes and characterizing, documenting, and disposing of waste. As part of initial planning, the cost of rescuing candidate {sup 233}U items was estimated roughly. The annualized costs were found to be $1,228K in FY 2012, $1,375K in FY 2013,

  10. Porous membrane electrochemical cell for uranium and transuranic recovery from molten salt electrolyte

    DOE Patents [OSTI]

    Willit, James L. (Ratavia, IL)

    2007-09-11T23:59:59.000Z

    An improved process and device for the recovery of the minor actinides and the transuranic elements (TRU's) from a molten salt electrolyte. The process involves placing the device, an electrically non-conducting barrier between an anode salt and a cathode salt. The porous barrier allows uranium to diffuse between the anode and cathode, yet slows the diffusion of uranium ions so as to cause depletion of uranium ions in the catholyte. This allows for the eventual preferential deposition of transuranics present in spent nuclear fuel such as Np, Pu, Am, Cm. The device also comprises an uranium oxidation anode. The oxidation anode is solid uranium metal in the form of spent nuclear fuel. The spent fuel is placed in a ferric metal anode basket which serves as the electrical lead or contact between the molten electrolyte and the anodic uranium metal.

  11. Porous membrane electrochemical cell for uranium and transuranic recovery from molten salt electrolyte

    DOE Patents [OSTI]

    Willit, James L. (Batavia, IL)

    2010-09-21T23:59:59.000Z

    An improved process and device for the recovery of the minor actinides and the transuranic elements (TRU's) from a molten salt electrolyte. The process involves placing the device, an electrically non-conducting barrier between an anode salt and a cathode salt. The porous barrier allows uranium to diffuse between the anode and cathode, yet slows the diffusion of uranium ions so as to cause depletion of uranium ions in the catholyte. This allows for the eventual preferential deposition of transuranics present in spent nuclear fuel such as Np, Pu, Am, Cm. The device also comprises an uranium oxidation anode. The oxidation anode is solid uranium metal in the form of spent nuclear fuel. The spent fuel is placed in a ferric metal anode basket which serves as the electrical lead or contact between the molten electrolyte and the anodic uranium metal.

  12. EIS-0359: Uranium Hexafluoride Conversion Facility at the Paducah, Kentucky Site

    Broader source: Energy.gov [DOE]

    This site-specific EIS considers the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three locations within the Paducah site; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as a conversion co-product; and neutralization of HF to calcium fluoride and its sale or disposal in the event that the HF product is not sold.

  13. Bioremediation of uranium contaminated soils and wastes

    SciTech Connect (OSTI)

    Francis, A.J.

    1998-12-31T23:59:59.000Z

    Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (1) stabilization of uranium and toxic metals with reduction in waste volume and (2) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

  14. Uranium Management - Preservation of a National Asset

    SciTech Connect (OSTI)

    Jackson, J. D.; Stroud, J. C.

    2002-02-27T23:59:59.000Z

    The Uranium Management Group (UMG) was established at the Department of Energy's (DOE's) Oak Ridge Operations in 1999 as a mechanism to expedite the de-inventory of surplus uranium from the Fernald Environmental Management Project site. This successful initial venture has broadened into providing uranium material de-inventory and consolidation support to the Hanford site as well as retrieving uranium materials that the Department had previously provided to universities under the loan/lease program. As of December 31, 2001, {approx} 4,300 metric tons of uranium (MTU) have been consolidated into a more cost effective interim storage location at the Portsmouth site near Piketon, OH. The UMG continues to uphold its corporate support mission by promoting the Nuclear Materials Stewardship Initiative (NMSI) and the twenty-five (25) action items of the Integrated Nuclear Materials Management Plan (1). Before additional consolidation efforts may commence to remove excess inventory from Environmental Management closure sites and universities, a Programmatic Environmental Assessment (PEA) must be completed. Two (2) noteworthy efforts currently being pursued involve the investigation of re-use opportunities for surplus uranium materials and the recovery of usable uranium from the shutdown Portsmouth cascade. In summary, the UMG is available as a DOE complex-wide technical resource to promote the responsible management of surplus uranium.

  15. Method for fabricating laminated uranium composites

    DOE Patents [OSTI]

    Chapman, L.R.

    1983-08-03T23:59:59.000Z

    The present invention is directed to a process for fabricating laminated composites of uranium or uranium alloys and at least one other metal or alloy. The laminated composites are fabricated by forming a casting of the molten uranium with the other metal or alloy which is selectively positioned in the casting and then hot-rolling the casting into a laminated plate in or around which the casting components are metallurgically bonded to one another to form the composite. The process of the present invention provides strong metallurgical bonds between the laminate components primarily since the bond disrupting surface oxides on the uranium or uranium alloy float to the surface of the casting to effectively remove the oxides from the bonding surfaces of the components.

  16. Scrap uranium recycling via electron beam melting

    SciTech Connect (OSTI)

    McKoon, R.

    1993-11-01T23:59:59.000Z

    A program is underway at the Lawrence Livermore National Laboratory (LLNL) to recycle scrap uranium metal. Currently, much of the material from forging and machining processes is considered radioactive waste and is disposed of by oxidation and encapsulation at significant cost. In the recycling process, uranium and uranium alloys in various forms will be processed by electron beam melting and continuously cast into ingots meeting applicable specifications for virgin material. Existing vacuum processing facilities at LLNL are in compliance with all current federal and state environmental, safety and health regulations for the electron beam melting and vaporization of uranium metal. One of these facilities has been retrofitted with an auxiliary electron beam gun system, water-cooled hearth, crucible and ingot puller to create an electron beam melt furnace. In this furnace, basic process R&D on uranium recycling will be performed with the goal of eventual transfer of this technology to a production facility.

  17. National Uranium Resource Evaluation, Tonopah quadrangle, Nevada

    SciTech Connect (OSTI)

    Hurley, B W; Parker, D P

    1982-04-01T23:59:59.000Z

    The Tonopah Quadrangle, Nevada, was evaluated using National Uranium Resource Evaluation criteria to identify and delineate areas favorable for uranium deposits. Investigations included reconnaissance and detailed surface geologic and radiometric studies, geochemical sampling and evaluation, analysis and ground-truth followup of aerial radiometric and hydrogeochemical and stream-sediment reconnaissance data, and subsurface data evaluation. The results of these investigations indicate environments favorable for hydroallogenic uranium deposits in Miocene lacustrine sediments of the Big Smoky Valley west of Tonopah. The northern portion of the Toquima granitic pluton is favorable for authigenic uranium deposits. Environments considered unfavorable for uranium deposits include Quaternary sediments; intermediate and mafic volcanic and metavolcanic rocks; Mesozoic, Paleozoic, and Precambrian sedimentary and metasedimentary rocks; those plutonic rocks not included within favorable areas; and those felsic volcanic rocks not within the Northumberland and Mount Jefferson calderas.

  18. Uranium in prehistoric Indian pottery

    E-Print Network [OSTI]

    Filberth, Ernest William

    2012-06-07T23:59:59.000Z

    present in the sample, and the cross l section of the process (the measure of the probability of a neutron interacting with an uranium atom), In general, a daughter product 235 of U fission is analyzed on a detector which counts either gamma rays... for quantitative analysis of various elements on archaeological artifacts, Manganese has been determined in Mesoamerican pot sherds (Bennyhoff and Heizer 1965). A Pu-Be radioisotope neutron source with a flux of 4 x 10 4 -2 -1 neutrons cm sec was used...

  19. 2013 Uranium Marketing Annual Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ec 1827190List of Tables3 Uranium

  20. 2013 Uranium Marketing Annual Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ec 1827190List of Tables3 Uranium11

  1. 2013 Uranium Marketing Annual Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ec 1827190List of6,2009Uranium

  2. 2013 Uranium Marketing Annual Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ec 1827190List of6,2009UraniumNext

  3. 2013 Uranium Marketing Annual Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ec 1827190List of6,2009UraniumNext

  4. U.S.Uranium Reserves

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand28 198 18BiomassThree-Dimensional SeismicUranium

  5. 2013 Uranium Marketing Annual Report

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World liquids consumption by region,Purchases2 U.S.Feed6a. Uranium

  6. 2013 Uranium Marketing Annual Report

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World liquids consumption by region,Purchases2 U.S.Feed6a.4. Uranium

  7. Bugs boost Cold War clean-up: Bacteria could scrub uranium from sites contaminated decades ago. updated at midnight GMTtoday is friday, november 14

    E-Print Network [OSTI]

    Lovley, Derek

    2003 · Fungus catches radioactive fallout 8 May 2002 · Depleted uranium soils battlefields 12 MarchBugs boost Cold War clean-up: Bacteria could scrub uranium from sites contaminated decades ago boost Cold War clean-up Bacteria could scrub uranium from sites contaminated decades ago. 13 October

  8. Removal of uranium from uranium-contaminated soils -- Phase 1: Bench-scale testing. Uranium in Soils Integrated Demonstration

    SciTech Connect (OSTI)

    Francis, C. W.

    1993-09-01T23:59:59.000Z

    To address the management of uranium-contaminated soils at Fernald and other DOE sites, the DOE Office of Technology Development formed the Uranium in Soils Integrated Demonstration (USID) program. The USID has five major tasks. These include the development and demonstration of technologies that are able to (1) characterize the uranium in soil, (2) decontaminate or remove uranium from the soil, (3) treat the soil and dispose of any waste, (4) establish performance assessments, and (5) meet necessary state and federal regulations. This report deals with soil decontamination or removal of uranium from contaminated soils. The report was compiled by the USID task group that addresses soil decontamination; includes data from projects under the management of four DOE facilities [Argonne National Laboratory (ANL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), and the Savannah River Plant (SRP)]; and consists of four separate reports written by staff at these facilities. The fundamental goal of the soil decontamination task group has been the selective extraction/leaching or removal of uranium from soil faster, cheaper, and safer than current conventional technologies. The objective is to selectively remove uranium from soil without seriously degrading the soil`s physicochemical characteristics or generating waste forms that are difficult to manage and/or dispose of. Emphasis in research was placed more strongly on chemical extraction techniques than physical extraction techniques.

  9. Recovery of uranium by using new microorganisms isolated from North American uranium deposits

    SciTech Connect (OSTI)

    Sakaguchi, T.; Nakajima, A.; Tsuruta, T. [Miyazaki Medical College (Japan)

    1995-12-31T23:59:59.000Z

    Some attempts were made to remove uranium that may be present in refining effluents, mine tailings by using new microorganisms isolated from uranium deposits and peculiar natural environments. To screen microorganisms isolated from uranium deposits and peculiar natural environments in North America and Japan for maximal accumulation of uranium, hundreds of microorganisms were examined. Some microorganisms can accumulate about 500 mg (4.2 mEq) of uranium per gram of Microbial cells within 1 h. The uranium accumulation capacity of the cells exceeds that of commercially available chelating agents (2-3 mEq/g adsorbent). We attempted to recover uranium from uranium refining waste water by using new microorganisms. As a result, these microbial cells can recover trace amounts of uranium from uranium waste water with high efficiency. These strains also have a high accumulating ability for thorium. Thus, these new microorganisms can be used as an adsorbing agent for the removal of nuclear elements may be present in metallurgical effluents, mine tailings and other waste sources.

  10. Uranium Cluster Chemistry DOI: 10.1002/anie.200906605

    E-Print Network [OSTI]

    Uranium Cluster Chemistry DOI: 10.1002/anie.200906605 Tetranuclear Uranium Clusters by Reductive in the coordination chemistry and small-molecule reactivity of uranium. Among the intriguing reactivity patterns of tetravalent uranium with 3,5-dimethylpyrazolate (Me2PzÃ? ) led to forma- tion of an unprecedented homoleptic

  11. Technical Basis for Assessing Uranium Bioremediation Performance

    SciTech Connect (OSTI)

    PE Long; SB Yabusaki; PD Meyer; CJ Murray; AL N’Guessan

    2008-04-01T23:59:59.000Z

    In situ bioremediation of uranium holds significant promise for effective stabilization of U(VI) from groundwater at reduced cost compared to conventional pump and treat. This promise is unlikely to be realized unless researchers and practitioners successfully predict and demonstrate the long-term effectiveness of uranium bioremediation protocols. Field research to date has focused on both proof of principle and a mechanistic level of understanding. Current practice typically involves an engineering approach using proprietary amendments that focuses mainly on monitoring U(VI) concentration for a limited time period. Given the complexity of uranium biogeochemistry and uranium secondary minerals, and the lack of documented case studies, a systematic monitoring approach using multiple performance indicators is needed. This document provides an overview of uranium bioremediation, summarizes design considerations, and identifies and prioritizes field performance indicators for the application of uranium bioremediation. The performance indicators provided as part of this document are based on current biogeochemical understanding of uranium and will enable practitioners to monitor the performance of their system and make a strong case to clients, regulators, and the public that the future performance of the system can be assured and changes in performance addressed as needed. The performance indicators established by this document and the information gained by using these indicators do add to the cost of uranium bioremediation. However, they are vital to the long-term success of the application of uranium bioremediation and provide a significant assurance that regulatory goals will be met. The document also emphasizes the need for systematic development of key information from bench scale tests and pilot scales tests prior to full-scale implementation.

  12. Electrochemistry, Spectroscopy, and Reactivity of Uranium Complexes Supported by Ferrocene Diamide Ligands

    E-Print Network [OSTI]

    Duhovic, Selma

    2012-01-01T23:59:59.000Z

    J. L. , Pentavalent Uranium Chemistry-Synthetic Pursuit of afor Trivalent Uranium Chemistry. Inorg. Chem. 1989, 28, (and High-Valent Uranium Chemistry. Organometallics 2011,

  13. Recent International R&D Activities in the Extraction of Uranium from Seawater

    E-Print Network [OSTI]

    Rao, Linfeng

    2011-01-01T23:59:59.000Z

    Uranium and Rare Earth Elements Using Biomass of Algae, Bioinorganic ChemistryRecovery of uranium from sea water. Chemistry & Industry (uranium recovery from seawater. Industrial & Engineering Chemistry

  14. Measurement and Analysis of Fission Rates in a Spherical Mockup of Uranium and Polyethylene

    E-Print Network [OSTI]

    Tong-Hua, Zhu; Xin-Xin, Lu; Rong, Liu; Zi-Jie, Han; Li, Jiang; Mei, Wang

    2013-01-01T23:59:59.000Z

    Measurements of the reaction rate distribution were carried out using two kinds of Plate Micro Fission Chamber(PMFC). The first is a depleted uranium chamber and the second an enriched uranium chamber. The material in the depleted uranium chamber is strictly the same as the material in the uranium assembly. With the equation solution to conduct the isotope contribution correction, the fission rate of 238U and 235U were obtained from the fission rate of depleted uranium and enriched uranium. And then, the fission count of 238U and 235U in an individual uranium shell was obtained. In this work, MCNP5 and continuous energy cross sections ENDF/BV.0 were used for the analysis of fission rate distribution and fission count. The calculated results were compared with the experimental ones. The calculation of fission rate of DU and EU were found to agree with the measured ones within 10% except at the positions in polyethylene region and the two positions near the outer surface. Beacause the fission chamber was not co...

  15. Electrolytic process for preparing uranium metal

    DOE Patents [OSTI]

    Haas, Paul A. (Knoxville, TN)

    1990-01-01T23:59:59.000Z

    An electrolytic process for making uranium from uranium oxide using Cl.sub.2 anode product from an electrolytic cell to react with UO.sub.2 to form uranium chlorides. The chlorides are used in low concentrations in a melt comprising fluorides and chlorides of potassium, sodium and barium in the electrolytic cell. The electrolysis produces Cl.sub.2 at the anode that reacts with UO.sub.2 in the feed reactor to form soluble UCl.sub.4, available for a continuous process in the electrolytic cell, rather than having insoluble UO.sub.2 fouling the cell.

  16. Crystal Chemistry of Early Actinides (Thorium, Uranium, and Neptunium) and Uranium Mesoporous Materials.

    E-Print Network [OSTI]

    Sigmon, Ginger E.

    2010-01-01T23:59:59.000Z

    ??Despite their considerable global importance, the structural chemistry of actinides remains understudied. Thorium and uranium fuel cycles are used in commercial nuclear reactors in India… (more)

  17. Prokaryotic microorganisms in uranium mining waste piles and their interactions with uranium and other heavy metals.

    E-Print Network [OSTI]

    Geißler, Andrea

    2007-01-01T23:59:59.000Z

    ??The influence of uranyl and sodium nitrate under aerobic and anaerobic conditions on the microbial community structure of a soil sample from the uranium mining… (more)

  18. In situ remediation of uranium contaminated groundwater

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C. [Sandia National Labs., Albuquerque, NM (United States)

    1997-12-31T23:59:59.000Z

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment - various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field preliminary results are discussed with regard to other potential contaminated groundwater treatment applications.

  19. In situ remediation of uranium contaminated groundwater

    SciTech Connect (OSTI)

    Dwyer, B.P.; Marozas, D.C.

    1997-02-01T23:59:59.000Z

    In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field results are discussed with regard to other potential contaminated groundwater treatment applications.

  20. Process for reducing beta activity in uranium

    DOE Patents [OSTI]

    Briggs, Gifford G. (Cincinnatti, OH); Kato, Takeo R. (Cincinnatti, OH); Schonegg, Edward (Cleves, OH)

    1986-01-01T23:59:59.000Z

    This invention is a method for lowering the beta radiation hazards associated with the casting of uranium. The method reduces the beta radiation emitted from the as-cast surfaces of uranium ingots. The method also reduces the amount of beta radiation emitters retained on the interiors of the crucibles that have been used to melt the uranium charges and which have undergone cleaning in a remote handling facility. The lowering of the radioactivity is done by scavenging the beta emitters from the molten uranium with a molten mixture containing the fluorides of magnesium and calcium. The method provides a means of collection and disposal of the beta emitters in a manner that reduces radiation exposure to operating personnel in the work area where the ingots are cast and processed.

  1. Method of recovering uranium from aqueous solution

    SciTech Connect (OSTI)

    Albright, R.L.

    1980-01-22T23:59:59.000Z

    Anion exchange resin derived from insoluble crosslinked polymers of vinyl benzyl chloride which are prepared by polymerizing vinyl benzyl chloride and a crosslinking monomer are particularly suitable in the treatment of uranium bearing leach liquors.

  2. Innovative design of uranium startup fast reactors

    E-Print Network [OSTI]

    Fei, Tingzhou

    2012-01-01T23:59:59.000Z

    Sodium Fast Reactors are one of the three candidates of GEN-IV fast reactors. Fast reactors play an important role in saving uranium resources and reducing nuclear wastes. Conventional fast reactors rely on transuranic ...

  3. Process for reducing beta activity in uranium

    DOE Patents [OSTI]

    Briggs, G.G.; Kato, T.R.; Schonegg, E.

    1985-04-11T23:59:59.000Z

    This invention is a method for lowering the beta radiation hazards associated with the casting of uranium. The method reduces the beta radiation emitted from the as-cast surfaces of uranium ingots. The method also reduces the amount of beta radiation emitters retained on the interiors of the crucibles that have been used to melt the uranium charges and which undergone cleaning in a remote handling facility. The lowering of the radioactivity is done by scavenging the beta emitters from the molten uranium with a molten mixture containing the fluorides of magnesium and calcium. The method provides a means of collection and disposal of the beta emitters in a manner that reduces radiation exposure to operating personnel in the work area where the ingots are cast and processed. 5 tabs.

  4. BIOREMEDIATION OF URANIUM CONTAMINATED SOILS AND WASTES.

    SciTech Connect (OSTI)

    FRANCIS,A.J.

    1998-09-17T23:59:59.000Z

    Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (i) stabilization of uranium and toxic metals with reduction in waste volume and (ii) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste such as Ca, Fe, K, Mg and Na released into solution are removed, thus reducing the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

  5. Material property correlations for uranium mononitride

    E-Print Network [OSTI]

    Hayes, Steven Lowe

    2012-06-07T23:59:59.000Z

    MATERIAL PROPERTY CORRELATIONS FOR URANIUM MONONITRIDE A Thesis by STEVEN LOWE HAYES Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1989 Major Subject: Nuclear Engineering MATERIAL PROPERTY CORRELATIONS FOR URANIUM MONONITRIDE A Thesis by STEVEN LOWE HAYES Approved as to style and content by: K. L. Peddicord (Chair of Committee) R. R. Hart (Member) C. P. Burger (Member...

  6. Electrochemical method of producing eutectic uranium alloy and apparatus

    DOE Patents [OSTI]

    Horton, James A. (Livermore, CA); Hayden, H. Wayne (Oakridge, TN)

    1995-01-01T23:59:59.000Z

    An apparatus and method for continuous production of liquid uranium alloys through the electrolytic reduction of uranium chlorides. The apparatus includes an electrochemical cell formed from an anode shaped to form an electrolyte reservoir, a cathode comprising a metal, such as iron, capable of forming a eutectic uranium alloy having a melting point less than the melting point of pure uranium, and molten electrolyte in the reservoir comprising a chlorine or fluorine containing salt and uranium chloride. The method of the invention produces an eutectic uranium alloy by creating an electrolyte reservoir defined by a container comprising an anode, placing an electrolyte in the reservoir, the electrolyte comprising a chlorine or fluorine containing salt and uranium chloride in molten form, positioning a cathode in the reservoir where the cathode comprises a metal capable of forming an uranium alloy having a melting point less than the melting point of pure uranium, and applying a current between the cathode and the anode.

  7. Conversion and Blending Facility Highly enriched uranium to low enriched uranium as uranium hexafluoride. Revision 1

    SciTech Connect (OSTI)

    NONE

    1995-07-05T23:59:59.000Z

    This report describes the Conversion and Blending Facility (CBF) which will have two missions: (1) convert surplus HEU materials to pure HEU UF{sub 6} and a (2) blend the pure HEU UF{sub 6} with diluent UF{sub 6} to produce LWR grade LEU-UF{sub 6}. The primary emphasis of this blending be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The chemical and isotopic concentrations of the blended LEU product will be held within the specifications required for LWR fuel. The blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry.

  8. Experimental partitioning of uranium between liquid iron sulfide and liquid silicate: Implications for radioactivity in the Earth's core

    E-Print Network [OSTI]

    Minarik, William

    Experimental partitioning of uranium between liquid iron sulfide and liquid silicate: Implications Measurable uranium (U) is found in metal sulfide liquids in equilibrium with molten silicate at conditions shows that K is depleted in the Earth by $50%, while U and Th are slightly enriched (Palme and O

  9. Idaho National Engineering and Environmental Laboratory Site Report on the Production and Use of Recycled Uranium

    SciTech Connect (OSTI)

    L. C. Lewis; D. C. Barg; C. L. Bendixsen; J. P. Henscheid; D. R. Wenzel; B. L. Denning

    2000-09-01T23:59:59.000Z

    Recent allegations regarding radiation exposure to radionuclides present in recycled uranium sent to the gaseous diffusion plants prompted the Department of Energy to undertake a system-wide study of recycled uranium. Of particular interest, were the flowpaths from site to site operations and facilities in which exposure to plutonium, neptunium and technetium could occur, and to the workers that could receive a significant radiation dose from handling recycled uranium. The Idaho National Engineering and Environmental Laboratory site report is primarily concerned with two locations. Recycled uranium was produced at the Idaho Chemical Processing Plant where highly enriched uranium was recovered from spent fuel. The other facility is the Specific Manufacturing Facility (SMC) where recycled, depleted uranium is manufactured into shapes for use by their customer. The SMC is a manufacturing facility that uses depleted uranium metal as a raw material that is then rolled and cut into shapes. There are no chemical processes that might concentrate any of the radioactive contaminant species. Recyclable depleted uranium from the SMC facility is sent to a private metallurgical facility for recasting. Analyses on the recast billets indicate that there is no change in the concentrations of transuranics as a result of the recasting process. The Idaho Chemical Processing Plant was built to recover high-enriched uranium from spent nuclear fuel from test reactors. The facility processed diverse types of fuel which required uniquely different fuel dissolution processes. The dissolved fuel was passed through three cycles of solvent extraction which resulted in a concentrated uranyl nitrate product. For the first half of the operating period, the uranium was shipped as the concentrated solution. For the second half of the operating period the uranium solution was thermally converted to granular, uranium trioxide solids. The dose reconstruction project has evaluated work exposure and exposure to the public as the result of normal operations and accidents that occurred at the INEEL. As a result of these studies, the maximum effective dose equivalent from site activities did not exceed seventeen percent of the natural background in Eastern Idaho. There was no year in which the radiation dose to the public exceeded the applicable limits for that year. Worker exposure to recycled uranium was minimized by engineering features that reduced the possibility of direct exposure.

  10. Compact reaction cell for homogenizing and down-blending highly enriched uranium metal

    DOE Patents [OSTI]

    McLean, W. II; Miller, P.E.; Horton, J.A.

    1995-05-02T23:59:59.000Z

    The invention is a specialized reaction cell for converting uranium metal to uranium oxide. In a preferred form, the reaction cell comprises a reaction chamber with increasing diameter along its length (e.g. a cylindrical chamber having a diameter of about 2 inches in a lower portion and having a diameter of from about 4 to about 12 inches in an upper portion). Such dimensions are important to achieve the necessary conversion while at the same time affording criticality control and transportability of the cell and product. The reaction chamber further comprises an upper port and a lower port, the lower port allowing for the entry of reactant gases into the reaction chamber, the upper port allowing for the exit of gases from the reaction chamber. A diffuser plate is attached to the lower port of the reaction chamber and serves to shape the flow of gas into the reaction chamber. The reaction cell further comprises means for introducing gases into the reaction chamber and a heating means capable of heating the contents of the reaction chamber. The present invention also relates to a method for converting uranium metal to uranium oxide in the reaction cell of the present invention. The invention is useful for down-blending highly enriched uranium metal by the simultaneous conversion of highly enriched uranium metal and natural or depleted uranium metal to uranium oxide within the reaction cell. 4 figs.

  11. Compact reaction cell for homogenizing and down-blanding highly enriched uranium metal

    DOE Patents [OSTI]

    McLean, II, William (Oakland, CA); Miller, Philip E. (Livermore, CA); Horton, James A. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    The invention is a specialized reaction cell for converting uranium metal to uranium oxide. In a preferred form, the reaction cell comprises a reaction chamber with increasing diameter along its length (e.g. a cylindrical chamber having a diameter of about 2 inches in a lower portion and having a diameter of from about 4 to about 12 inches in an upper portion). Such dimensions are important to achieve the necessary conversion while at the same time affording criticality control and transportability of the cell and product. The reaction chamber further comprises an upper port and a lower port, the lower port allowing for the entry of reactant gasses into the reaction chamber, the upper port allowing for the exit of gasses from the reaction chamber. A diffuser plate is attached to the lower port of the reaction chamber and serves to shape the flow of gas into the reaction chamber. The reaction cell further comprises means for introducing gasses into the reaction chamber and a heating means capable of heating the contents of the reaction chamber. The present invention also relates to a method for converting uranium metal to uranium oxide in the reaction cell of the present invention. The invention is useful for down-blending highly enriched uranium metal by the simultaneous conversion of highly enriched uranium metal and natural or depleted uranium metal to uranium oxide within the reaction cell.

  12. Disposition of DOE Excess Depleted Uranium, Natural Uranium, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent(CRADA and DOW Area 5 LLRW & MLLWLow-Enriched

  13. EA-1290: Disposition of Russian Federation Titled Natural Uranium

    Broader source: Energy.gov [DOE]

    This EA evaluates the potential environmental impacts of a proposal to transport up to an average of 9,000 metric tons per year of natural uranium as uranium hexafluoride (UF6) from the United...

  14. Fabrication and Characterization of Uranium-based High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fabrication and Characterization of Uranium-based High Temperature Reactor Fuel June 01, 2013 The Uranium Fuel Development Laboratory is a modern R&D scale lab for the fabrication...

  15. Assessments of long-term uranium supply availability

    E-Print Network [OSTI]

    Zaterman, Daniel R

    2009-01-01T23:59:59.000Z

    The future viability of nuclear power will depend on the long-term availability of uranium. A two-form uranium supply model was used to estimate the date at which peak production will occur. The model assumes a constant ...

  16. Prospects for the recovery of uranium from seawater

    E-Print Network [OSTI]

    Best, F. R.

    1980-01-01T23:59:59.000Z

    A computer program entitled URPE (Uranium Recovery Performance and Economics) has been developed to simulate the engineering performance and provide an economic analysis O of a plant recovering uranium from seawater. The ...

  17. Monitoring Uranium Transformations Determined by the Evolution of Biogeochemical Processes

    SciTech Connect (OSTI)

    Marsh, Terence L.

    2013-07-30T23:59:59.000Z

    Our contribution to the larger project (ANL) was the phylogenetic analysis of evolved communities capable of reducing metals including uranium.

  18. acute catecholamine depletion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    about NM biosynthesis, and it is not known where Sulzer, David 9 Review The Toxicity of Depleted Uranium CiteSeer Summary: Abstract: Depleted uranium (DU) is an emerging...

  19. Uranium Mill Tailings Remedial Action Project surface project management plan

    SciTech Connect (OSTI)

    Not Available

    1994-09-01T23:59:59.000Z

    This Project Management Plan describes the planning, systems, and organization that shall be used to manage the Uranium Mill Tailings Remedial Action Project (UMTRA). US DOE is authorized to stabilize and control surface tailings and ground water contamination at 24 inactive uranium processing sites and associated vicinity properties containing uranium mill tailings and related residual radioactive materials.

  20. Microbial Janitors: Enabling natural microbes to clean up uranium contamination

    E-Print Network [OSTI]

    Microbial Janitors: Enabling natural microbes to clean up uranium contamination Oak Ridge to the development of the atomic bomb. Uranium enrichment activities on the Oak Ridge Reservation in the 1940s until then the uranium and nitrate contamination has spread through the ground and now covers an area of about 7 km

  1. Plutonium recovery from spent reactor fuel by uranium displacement

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL)

    1992-01-01T23:59:59.000Z

    A process for separating uranium values and transuranic values from fission products containing rare earth values when the values are contained together in a molten chloride salt electrolyte. A molten chloride salt electrolyte with a first ratio of plutonium chloride to uranium chloride is contacted with both a solid cathode and an anode having values of uranium and fission products including plutonium. A voltage is applied across the anode and cathode electrolytically to transfer uranium and plutonium from the anode to the electrolyte while uranium values in the electrolyte electrolytically deposit as uranium metal on the solid cathode in an amount equal to the uranium and plutonium transferred from the anode causing the electrolyte to have a second ratio of plutonium chloride to uranium chloride. Then the solid cathode with the uranium metal deposited thereon is removed and molten cadmium having uranium dissolved therein is brought into contact with the electrolyte resulting in chemical transfer of plutonium values from the electrolyte to the molten cadmium and transfer of uranium values from the molten cadmium to the electrolyte until the first ratio of plutonium chloride to uranium chloride is reestablished.

  2. Standard Review Plan for In Situ Leach Uranium

    E-Print Network [OSTI]

    NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License Applications Final Washington, DC 20555-0001 #12;NUREG-1569 Standard Review Plan for In Situ Leach Uranium Extraction License OF A STANDARD REVIEW PLAN (NUREG­1569) FOR STAFF REVIEWS FOR IN SITU LEACH URANIUM EXTRACTION LICENSE

  3. Bioremediation of Uranium Plumes with Nano-scale

    E-Print Network [OSTI]

    Fay, Noah

    (IV) (UO2[s], uraninite) Anthropogenic · Release of mill tailings during uranium mining - MobilizationBioremediation of Uranium Plumes with Nano-scale Zero-valent Iron Angela Athey Advisers: Dr. Reyes Undergraduate Student Fellowship Program April 15, 2011 #12;Main Sources of Uranium Natural · Leaching from

  4. EPA Uranium Program Update Loren W. Setlow and

    E-Print Network [OSTI]

    30, 2008 #12;2 Overview EPA Radiation protection program Uranium reports and abandoned mine lands and Liability Act #12;4 Uranium Reports and Abandoned Mine Lands Program ·Technologically Enhanced Naturally Occurring Radioactive Materials from Uranium Mining, Volume I: Mining and Reclamation Background (Revised

  5. Soil to plant transfer of 238 Th on a uranium

    E-Print Network [OSTI]

    Hu, Qinhong "Max"

    Soil to plant transfer of 238 U, 226 Ra and 232 Th on a uranium mining-impacted soil from species grown in soils from southeastern China contaminated with uranium mine tailings were analyzed The radioactive waste (e.g. tailings) produced by uranium mining activities contains a series of long

  6. Plutonium recovery from spent reactor fuel by uranium displacement

    DOE Patents [OSTI]

    Ackerman, J.P.

    1992-03-17T23:59:59.000Z

    A process is described for separating uranium values and transuranic values from fission products containing rare earth values when the values are contained together in a molten chloride salt electrolyte. A molten chloride salt electrolyte with a first ratio of plutonium chloride to uranium chloride is contacted with both a solid cathode and an anode having values of uranium and fission products including plutonium. A voltage is applied across the anode and cathode electrolytically to transfer uranium and plutonium from the anode to the electrolyte while uranium values in the electrolyte electrolytically deposit as uranium metal on the solid cathode in an amount equal to the uranium and plutonium transferred from the anode causing the electrolyte to have a second ratio of plutonium chloride to uranium chloride. Then the solid cathode with the uranium metal deposited thereon is removed and molten cadmium having uranium dissolved therein is brought into contact with the electrolyte resulting in chemical transfer of plutonium values from the electrolyte to the molten cadmium and transfer of uranium values from the molten cadmium to the electrolyte until the first ratio of plutonium chloride to uranium chloride is reestablished.

  7. Modeling Uranium-Proton Ion Exchange in Biosorption

    E-Print Network [OSTI]

    Volesky, Bohumil

    threatening heavy metals because of its high toxicity and some radioactivity. Excessive amounts of uranium seaweed biomass was used to remove the heavy metal uranium from the aqueous solution. Uranium biosorption the heavy metal uptake performance of different biosorbents.LangmuirandFreundlichmodelsoftengenerally fit

  8. Estimating terrestrial uranium and thorium by antineutrino flux measurements

    E-Print Network [OSTI]

    Mcdonough, William F.

    of uranium and thorium concentrations in geological reservoirs relies largely on geochemi- cal modelEstimating terrestrial uranium and thorium by antineutrino flux measurements Stephen T. Dye, and approved November 16, 2007 (received for review July 11, 2007) Uranium and thorium within the Earth produce

  9. A Geostatistical Study of the Uranium Deposit at Kvanefjeld,

    E-Print Network [OSTI]

    with the geology. It is also shown that, although anisotropy exists, the uranium variation has a secondRisa-R-468 A Geostatistical Study of the Uranium Deposit at Kvanefjeld, The Ilimaussaq Intrusion A GEOSTATISTICAL STUDY OF THE URANIUM DEPOSIT AT KVANEFJELD, THE ILIMAUSSAQ INTRUSION, SOUTH GREENLAND Flemming

  10. Method for fluorination of uranium oxide

    DOE Patents [OSTI]

    Petit, George S. (Oak Ridge, TN)

    1987-01-01T23:59:59.000Z

    Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

  11. Evaporation of Enriched Uranium Solutions Containing Organophosphates

    SciTech Connect (OSTI)

    Pierce, R.A.

    1999-03-18T23:59:59.000Z

    The Savannah River Site has enriched uranium (EU) solution which has been stored for almost 10 years since being purified in the second uranium cycle of the H area solvent extraction process. The preliminary SRTC data, in conjunction with information in the literature, is promising. However, very few experiments have been run, and none of the results have been confirmed with repeat tests. As a result, it is believed that insufficient data exists at this time to warrant Separations making any process or program changes based on the information contained in this report. When this data is confirmed in future testing, recommendations will be presented.

  12. Decarburization of uranium via electron beam processing

    SciTech Connect (OSTI)

    McKoon, R H

    1998-10-23T23:59:59.000Z

    For many commercial and military applications, the successive Vacuum Induction Melting of uranium metal in graphite crucibles results in a product which is out of specification in carbon. The current recovery method involves dissolution of the metal in acid and chemical purification. This is both expensive and generates mixed waste. A study was undertaken at Lawrence Livermore National Laboratory to investigate the feasibility of reducing the carbon content of uranium metal using electron beam techniques. Results will be presented on the rate and extent of carbon removal as a function of various operating parameters.

  13. Progress toward uranium scrap recycling via EBCHR

    SciTech Connect (OSTI)

    McKoon, R.H.

    1994-11-01T23:59:59.000Z

    A 250 kW electron beam cold hearth refining (EBCHR) melt furnace at Lawrence Livermore National Laboratory (LLNL) has been in operation for over a year producing 5.5 in.-diameter ingots of various uranium alloys. Production of in-specification uranium-6%-niobium (U-6Nb) alloy ingots has been demonstrated using virgin feedstock. A vibratory scrap feeder has been installed on the system and the ability to recycle chopped U-6Nb scrap has been established. A preliminary comparison of vacuum arc remelted (VAR) and electron beam (EB) melted product is presented.

  14. Simplifying strong electronic correlations in uranium: Localized uranium heavy-fermion UM2Zn20 (M=Co,Rh) compounds

    E-Print Network [OSTI]

    Lawrence, Jon

    Simplifying strong electronic correlations in uranium: Localized uranium heavy-fermion UM2Zn20 (M Atómica, 8400 Bariloche, Argentina 6 Department of Chemistry and Biochemistry, University of Delaware-field effects corroborate an ionic-like uranium electronic configura- tion in UM2Zn20. DOI: 10.1103/PhysRevB.78

  15. Fabrication of Cerium Oxide and Uranium Oxide Microspheres for Space Nuclear Power Applications

    SciTech Connect (OSTI)

    Jeffrey A. Katalenich; Michael R. Hartman; Robert C. O'Brien

    2013-02-01T23:59:59.000Z

    Cerium oxide and uranium oxide microspheres are being produced via an internal gelation sol-gel method to investigate alternative fabrication routes for space nuclear fuels. Depleted uranium and non-radioactive cerium are being utilized as surrogates for plutonium-238 (Pu-238) used in radioisotope thermoelectric generators and for enriched uranium required by nuclear thermal rockets. While current methods used to produce Pu-238 fuels at Los Alamos National Laboratory (LANL) involve the generation of fine powders that pose a respiratory hazard and have a propensity to contaminate glove boxes, the sol-gel route allows for the generation of oxide microsphere fuels through an aqueous route. The sol-gel method does not generate fine powders and may require fewer processing steps than the LANL method with less operator handling. High-quality cerium dioxide microspheres have been fabricated in the desired size range and equipment is being prepared to establish a uranium dioxide microsphere production capability.

  16. Method for making a uranium chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

    2004-10-05T23:59:59.000Z

    The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

  17. Geodatabase of the South Texas Uranium District

    E-Print Network [OSTI]

    Mark Beaman; William Wade Mcgee

    Uranium and its associated trace elements and radionuclides are ubiquitous in the South Texas Tertiary environment. Surface mining of this resource from the 1960s through the early 1980s at over sixty locations has left an extensive anthropological footprint (Fig. 1) in the lower Nueces and San Antonio river basins. Reclamation of mining initiated after 1975 has been under the regulatory authority of the Railroad Commission of Texas (RCT). However, mines that were active before the Texas Surface Mining Act of 1975 was enacted, and never reclaimed, are now considered abandoned. The Abandoned Mine Land Section of the RCT is currently reclaiming these pre-regulation uranium mines with funding from the federal government. The RCT monitors the overall effectiveness of this process through post-reclamation radiation and vegetative cover surveys, water quality testing, slope stability and erosion control monitoring. Presently a number of graduate and postgraduate students are completing research on the watershed and reservoir distribution of trace elements and radionuclides downstream of the South Texas Uranium District. The question remains as to whether the elevated levels of uranium, its associated trace elements and radiation levels in the South Texas environment are due to mining

  18. The Quest for the Heaviest Uranium Isotope

    E-Print Network [OSTI]

    S. Schramm; D. Gridnev; D. V. Tarasov; V. N. Tarasov; W. Greiner

    2012-01-17T23:59:59.000Z

    We study Uranium isotopes and surrounding elements at very large neutron number excess. Relativistic mean field and Skyrme-type approaches with different parametrizations are used in the study. Most models show clear indications for isotopes that are stable with respect to neutron emission far beyond N=184 up to the range of around N=258.

  19. The multiphoton ionization of uranium hexafluoride

    SciTech Connect (OSTI)

    Armstrong, D.P. (Oak Ridge K-25 Site, TN (United States). UEO Enrichment Technical Operations Div.)

    1992-05-01T23:59:59.000Z

    Multiphoton ionization (MPI) time-of-flight mass spectroscopy and photoelectron spectroscopy studies of UF{sub 6} have been conducted using focused light from the Nd:YAG laser fundamental ({lambda}=1064 nm) and its harmonics ({lambda}=532, 355, or 266 nm), as well as other wavelengths provided by a tunable dye laser. The MPI mass spectra are dominated by the singly and multiply charged uranium ions rather than by the UF{sub x}{sup +} fragment ions even at the lowest laser power densities at which signal could be detected. The laser power dependence of U{sup n+} ions signals indicates that saturation can occur for many of the steps required for their ionization. In general, the doubly-charged uranium ion (U{sup 2+}) intensity is much greater than that of the singly-charged uranium ion (U{sup +}). For the case of the tunable dye laser experiments, the U{sup n+} (n = 1- 4) wavelength dependence is relatively unstructured and does not show observable resonance enhancement at known atomic uranium excitation wavelengths. The dominance of the U{sup 2+} ion and the absence or very small intensities of UF{sub x}{sup +} fragments, along with the unsaturated wavelength dependence, indicate that mechanisms may exist other than ionization of bare U atoms after the stepwise photodissociation of F atoms from the parent molecule.

  20. Radiological health aspects of uranium milling

    SciTech Connect (OSTI)

    Fisher, D.R.; Stoetzel, G.A.

    1983-05-01T23:59:59.000Z

    This report describes the operation of conventional and unconventional uranium milling processes, the potential for occupational exposure to ionizing radiation at the mill, methods for radiological safety, methods of evaluating occupational radiation exposures, and current government regulations for protecting workers and ensuring that standards for radiation protection are adhered to. In addition, a survey of current radiological health practices is summarized.

  1. Standard test method for determination of uranium or gadolinium (or both) in gadolinium oxide-uranium oxide pellets or by X-ray fluorescence (XRF)

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01T23:59:59.000Z

    Standard test method for determination of uranium or gadolinium (or both) in gadolinium oxide-uranium oxide pellets or by X-ray fluorescence (XRF)

  2. Control of structure and reactivity by ligand design : applications to small molecule activation by low-valent uranium complexes

    E-Print Network [OSTI]

    Lam, Oanh Phi

    2010-01-01T23:59:59.000Z

    researchers from uranium chemistry. Fortunately, despitescarce in uranium coordination chemistry. A more detailedligands for uranium coordination chemistry. Figure 4-2.

  3. Radiochemical Analysis Methodology for uranium Depletion Measurements

    SciTech Connect (OSTI)

    Scatena-Wachel DE

    2007-01-09T23:59:59.000Z

    This report provides sufficient material for a test sponsor with little or no radiochemistry background to understand and follow physics irradiation test program execution. Most irradiation test programs employ similar techniques and the general details provided here can be applied to the analysis of other irradiated sample types. Aspects of program management directly affecting analysis quality are also provided. This report is not an in-depth treatise on the vast field of radiochemical analysis techniques and related topics such as quality control. Instrumental technology is a very fast growing field and dramatic improvements are made each year, thus the instrumentation described in this report is no longer cutting edge technology. Much of the background material is still applicable and useful for the analysis of older experiments and also for subcontractors who still retain the older instrumentation.

  4. Uranium-Loaded Water Treatment Resins: 'Equivalent Feed' at NRC and Agreement State-Licensed Uranium Recovery Facilities - 12094

    SciTech Connect (OSTI)

    Camper, Larry W.; Michalak, Paul; Cohen, Stephen; Carter, Ted [Nuclear Regulatory Commission (United States)

    2012-07-01T23:59:59.000Z

    Community Water Systems (CWSs) are required to remove uranium from drinking water to meet EPA standards. Similarly, mining operations are required to remove uranium from their dewatering discharges to meet permitted surface water discharge limits. Ion exchange (IX) is the primary treatment strategy used by these operations, which loads uranium onto resin beads. Presently, uranium-loaded resin from CWSs and mining operations can be disposed as a waste product or processed by NRC- or Agreement State-licensed uranium recovery facilities if that licensed facility has applied for and received permission to process 'alternate feed'. The disposal of uranium-loaded resin is costly and the cost to amend a uranium recovery license to accept alternate feed can be a strong disincentive to commercial uranium recovery facilities. In response to this issue, the NRC issued a Regulatory Issue Summary (RIS) to clarify the agency's policy that uranium-loaded resin from CWSs and mining operations can be processed by NRC- or Agreement State-licensed uranium recovery facilities without the need for an alternate feed license amendment when these resins are essentially the same, chemically and physically, to resins that licensed uranium recovery facilities currently use (i.e., equivalent feed). NRC staff is clarifying its current alternate feed policy to declare IX resins as equivalent feed. This clarification is necessary to alleviate a regulatory and financial burden on facilities that filter uranium using IX resin, such as CWSs and mine dewatering operations. Disposing of those resins in a licensed facility could be 40 to 50 percent of the total operations and maintenance (O and M) cost for a CWS. Allowing uranium recovery facilities to treat these resins without requiring a license amendment lowers O and M costs and captures a valuable natural resource. (authors)

  5. Uranium and other heavy metals in the plant-animal-human food chain near abandoned mining sites and structures in an American Indian community in northwestern New Mexico

    E-Print Network [OSTI]

    Samuel-Nakamura, Christine

    2013-01-01T23:59:59.000Z

    comparable to National Uranium Resource Evaluation (NURE)comparable to National Uranium Resource Evaluation (NURE)

  6. In-line assay monitor for uranium hexafluoride

    DOE Patents [OSTI]

    Wallace, S.A.

    1980-03-21T23:59:59.000Z

    An in-line assay monitor for determining the content of uranium-235 in a uranium hexafluoride gas isotopic separation system is provided which removes the necessity of complete access to the operating parameters of the system for determining the uranium-235 content. The method and monitor for carrying out the method involve cooling of a radiation pervious chamber connected in fluid communication with the selected point in the system to withdraw a specimen and solidify the specimen in the chamber. The specimen is irradiated by means of an ionizing radiation source of energy different from that of the 185 keV gamma emissions from uranium-235. The uranium-235 content of the specimen is determined from comparison of the accumulated 185 keV energy counts and reference energy counts. The latter is used to measure the total uranium isotopic content of the specimen.

  7. Uranium Oxide Aerosol Transport in Porous Graphite

    SciTech Connect (OSTI)

    Blanchard, Jeremy; Gerlach, David C.; Scheele, Randall D.; Stewart, Mark L.; Reid, Bruce D.; Gauglitz, Phillip A.; Bagaasen, Larry M.; Brown, Charles C.; Iovin, Cristian; Delegard, Calvin H.; Zelenyuk, Alla; Buck, Edgar C.; Riley, Brian J.; Burns, Carolyn A.

    2012-01-23T23:59:59.000Z

    The objective of this paper is to investigate the transport of uranium oxide particles that may be present in carbon dioxide (CO2) gas coolant, into the graphite blocks of gas-cooled, graphite moderated reactors. The transport of uranium oxide in the coolant system, and subsequent deposition of this material in the graphite, of such reactors is of interest because it has the potential to influence the application of the Graphite Isotope Ratio Method (GIRM). The GIRM is a technology that has been developed to validate the declared operation of graphite moderated reactors. GIRM exploits isotopic ratio changes that occur in the impurity elements present in the graphite to infer cumulative exposure and hence the reactor’s lifetime cumulative plutonium production. Reference Gesh, et. al., for a more complete discussion on the GIRM technology.

  8. Energy balance for uranium recovery from seawater

    SciTech Connect (OSTI)

    Schneider, E.; Lindner, H. [The University of Texas, 1 University Station C2200, Austin, TX 78712 (United States)

    2013-07-01T23:59:59.000Z

    The energy return on investment (EROI) of an energy resource is the ratio of the energy it ultimately produces to the energy used to recover it. EROI is a key viability measure for a new recovery technology, particularly in its early stages of development when financial cost assessment would be premature or highly uncertain. This paper estimates the EROI of uranium recovery from seawater via a braid adsorbent technology. In this paper, the energy cost of obtaining uranium from seawater is assessed by breaking the production chain into three processes: adsorbent production, adsorbent deployment and mooring, and uranium elution and purification. Both direct and embodied energy inputs are considered. Direct energy is the energy used by the processes themselves, while embodied energy is used to fabricate their material, equipment or chemical inputs. If the uranium is used in a once-through fuel cycle, the braid adsorbent technology EROI ranges from 12 to 27, depending on still-uncertain performance and system design parameters. It is highly sensitive to the adsorbent capacity in grams of U captured per kg of adsorbent as well as to potential economies in chemical use. This compares to an EROI of ca. 300 for contemporary terrestrial mining. It is important to note that these figures only consider the mineral extraction step in the fuel cycle. At a reference performance level of 2.76 g U recovered per kg adsorbent immersed, the largest energy consumers are the chemicals used in adsorbent production (63%), anchor chain mooring system fabrication and operations (17%), and unit processes in the adsorbent production step (12%). (authors)

  9. Uranium enrichment export control guide: Gaseous diffusion

    SciTech Connect (OSTI)

    Not Available

    1989-09-01T23:59:59.000Z

    This document was prepared to serve as a guide for export control officials in their interpretation, understanding, and implementation of export laws that relate to the Zangger International Trigger List for gaseous diffusion uranium enrichment process components, equipment, and materials. Particular emphasis is focused on items that are especially designed or prepared since export controls are required for these by States that are party to the International Nuclear Nonproliferation Treaty.

  10. Engineering assessment of inactive uranium mill tailings

    SciTech Connect (OSTI)

    Not Available

    1981-07-01T23:59:59.000Z

    The Grand Junction site has been reevaluated in order to revise the October 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Grand Junction, Colorado. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 1.9 million tons of tailings at the Grand Junction site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation are also factors. The eight alternative actions presented herein range from millsite and off-site decontamination with the addition of 3 m of stabilization cover material (Option I), to removal of the tailings to remote disposal sites and decontamination of the tailings site (Options II through VIII). Cost estimates for the eight options range from about $10,200,000 for stabilization in-place to about $39,500,000 for disposal in the DeBeque area, at a distance of about 35 mi, using transportation by rail. If transportation to DeBeque were by truck, the cost estimated to be about $41,900,000. Three principal alternatives for the reprocessing of the Grand Junction tailings were examined: (a) heap leaching; (b) treatment at an existing mill; and (c) reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $200/lb by heap leach and $150/lb by conventional plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery appears not to be economically attractive.

  11. Containment and storage of uranium hexafluoride at US Department of Energy uranium enrichment plants

    SciTech Connect (OSTI)

    Barlow, C.R.; Alderson, J.H.; Blue, S.C.; Boelens, R.A.; Conkel, M.E.; Dorning, R.E.; Ecklund, C.D.; Halicks, W.G.; Henson, H.M.; Newman, V.S.; Philpot, H.E.; Taylor, M.S.; Vournazos, J.P. [Oak Ridge K-25 Site, TN (United States). UEO Enrichment Technical Operations Div.; Russell, J.R. [USDOE Oak Ridge Field Office, TN (United States); Pryor, W.A. [PAI Corp., Oak Ridge, TN (United States); Ziehlke, K.T. [MJB Technical Associates (United States)

    1992-07-01T23:59:59.000Z

    Isotopically depleted UF{sub 6} (uranium hexafluoride) accumulates at a rate five to ten times greater than the enriched product and is stored in steel vessels at the enrichment plant sites. There are approximately 55,000 large cylinders now in storage at Paducah, Kentucky; Portsmouth, Ohio; and Oak Ridge, Tennessee. Most of them contain a nominal 14 tons of depleted UF{sub 6}. Some of these cylinders have been in the unprotected outdoor storage environment for periods approaching 40 years. Storage experience, supplemented by limited corrosion data, suggests a service life of about 70 years under optimum conditions for the 48-in. diameter, 5/16-in.-wall pressure vessels (100 psi working pressure), using a conservative industry-established 1/4-in.-wall thickness as the service limit. In the past few years, however, factors other than atmospheric corrosion have become apparent that adversely affect the serviceability of small numbers of the storage containers and that indicate the need for a managed program to ensure maintenance ofcontainment integrity for all the cylinders in storage. The program includes periodic visual inspections of cylinders and storage yards with documentation for comparison with other inspections, a group of corrosion test programs to permit cylinder life forecasts, and identification of (and scheduling for remedial action) situations in which defects, due to handling damage or accelerated corrosion, can seriously shorten the storage life or compromise the containment integrity of individual cylinders. The program also includes rupture testing to assess the effects of certain classes of damage on overall cylinder strength, aswell as ongoing reviews of specifications, procedures, practices, and inspection results to effect improvements in handling safety, containment integrity, and storage life.

  12. Measurement of uranium enrichment by gamma spectroscopy: result of an experimental design

    E-Print Network [OSTI]

    , Gamma Spectrometry, uranium enrichment #12;PAPER Measurement of uranium enrichment by gamma spectroscopy: result of an experimental design Gamma spectroscopy is commonly used in nuclear safeguards to measure uranium enrichment. An experimental

  13. Magnetic Exchange Coupling and Single-Molecule Magnetism in Uranium Complexes

    E-Print Network [OSTI]

    Rinehart, Jeffrey Dennis

    2010-01-01T23:59:59.000Z

    in molecular uranium cluster chemistry. 13 Compound 2 ischemistry and small-molecule reactivity of uranium. AmongUranium Complexes by Jeffrey Dennis Rinehart Doctor of Philosophy in Chemistry

  14. E-Print Network 3.0 - active uranium americium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    << < 1 2 3 4 5 > >> 21 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  15. E-Print Network 3.0 - alkaline-earth metal uranium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In metamorphic rocks uranium and rare earth metals can form minerals. An example... Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  16. E-Print Network 3.0 - arlit uranium mines Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mathematics 5 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  17. E-Print Network 3.0 - area uranium plume Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 4 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  18. E-Print Network 3.0 - abandoned uranium mill Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 17 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  19. E-Print Network 3.0 - anaconda uranium mill Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 7 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  20. E-Print Network 3.0 - anthropogenic uranium enrichments Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ecology ; Engineering 99 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  1. E-Print Network 3.0 - acute uranium intoxication Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biology and Medicine 19 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  2. E-Print Network 3.0 - atomized uranium silicide Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Science 11 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  3. E-Print Network 3.0 - abandoned uranium mines Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 15 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  4. E-Print Network 3.0 - ash doped uranium Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 2 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  5. E-Print Network 3.0 - adepleted uranium hexafluoride Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mathematics 15 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  6. E-Print Network 3.0 - alloyed uranium sicral Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 33 geology and Ranger 1 open-pit uranium mine in Australia Summary: Uranium geology and mining Ranger 1 open-pit uranium mine in Australia Mikael Hk UHDSG...

  7. The geochemistry of uranium in the Orca Basin

    E-Print Network [OSTI]

    Weber, Frederick Fewell

    1979-01-01T23:59:59.000Z

    no uranium enrichment, with concentrations ranging from 2. 1 to 4. gppm, reflective of normal Gulf of Mexico sediments. This is the result of two dominant processes operating within the basin. First, the sharp pycnocline at the brine/seawater interface... . . . . . . . . , . . . , 37 xi Figure Page 16 Ores Basin Seismic Reflection Profile A 40 17 Ores Basin Seismic Reflection Profile B 42 18 Proposed Mechanism of Uranium Uptake in the Atlantis II Deep 59 INTRODUCTION Economic Status of Uranium in the United States...

  8. Tables des principaux minerais d'uranium et de thorium

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    233 Tables des principaux minerais d'uranium et de thorium Par B. SZILARD [Faculté des Sciences de minerais d'uranium et de thorium avec leurs données les plus importantes, telles que la com- position, la teneur en uranium et en thorium, la provenance et quelques indications générales. La liste ne prétend pas

  9. Uncertainty clouds uranium enrichment corporation's plans

    SciTech Connect (OSTI)

    Lane, E.

    1993-03-24T23:59:59.000Z

    An expected windfall to the US Treasury from the sale of the Energy Dept.'s commercial fuel enrichment facilities may evaporate in the next few weeks when the Clinton administration submits its fiscal 1994 budget proposal to Congress, according to congressional and administration officials. Under the Energy Policy Act of 1992, DOE is required to lease two uranium enrichment facilities, Portsmouth, Ohio, and Paducah, KY., to the government-owned US Enrichment Corp. (USEC) by July 1. Estimates by OMB and Treasury indicate a potential yearly payoff of $300 million from the government-owned company's sale of fuel for commercial reactors. Those two facilities use a process of gaseous diffusion to enrich uranium to about 3 percent for use as fuel in commercial power plants. DOE has contracts through at least 1996 to provide about 12 million separative work units (SWUs) yearly to US utilities and others world-wide. But under an agreement signed between the US and Russia last August, at least 10 metric tons, or 1.5 million SWUs, of low-enriched uranium (LEU) blended down from Russia warheads is expected to be delivered to the US starting in 1994. It could be sold at $50 to $60 per SWU, far below what DOE currently charges for its SWUs - $135 per SWU for 70 percent of the contract price and $90 per SWU for the remaining 30 percent.

  10. Chapter 3. Volume and Characteristics of Uranium Mine Wastes Uranium has been found and mined in a wide variety of rocks, including sandstone, carbonates1

    E-Print Network [OSTI]

    3-1 Chapter 3. Volume and Characteristics of Uranium Mine Wastes Uranium has been found and mined conventional mining, solution extraction, and milling of uranium, a principal focus of this report is TENORM, or which may need future reclamation. When uranium mining first started, most of the ores were recovered

  11. Uranium from Seawater Program Review; Fuel Resources Uranium from Seawater Program DOE Office of Nuclear Energy

    SciTech Connect (OSTI)

    none,

    2013-07-01T23:59:59.000Z

    For nuclear energy to remain sustainable in the United States, economically viable sources of uranium beyond terrestrial ores must be developed. The goal of this program is to develop advanced adsorbents that can extract uranium from seawater at twice the capacity of the best adsorbent developed by researchers at the Japan Atomic Energy Agency (JAEA), 1.5 mg U/g adsorbent. A multidisciplinary team from Oak Ridge National Laboratory, Lawrence Berkeley National Laboratory, Pacific Northwest National Laboratory, and the University of Texas at Austin was assembled to address this challenging problem. Polymeric adsorbents, based on the radiation grafting of acrylonitrile and methacrylic acid onto high surface-area polyethylene fibers followed by conversion of the nitriles to amidoximes, have been developed. These poly(acrylamidoxime-co-methacrylic acid) fibers showed uranium adsorption capacities for the extraction of uranium from seawater that exceed 3 mg U/g adsorbent in testing at the Pacific Northwest National Laboratory Marine Sciences Laboratory. The essence of this novel technology lies in the unique high surface-area trunk material that considerably increases the grafting yield of functional groups without compromising its mechanical properties. This technology received an R&D100 Award in 2012. In addition, high surface area nanomaterial adsorbents are under development with the goal of increasing uranium adsorption capacity by taking advantage of the high surface areas and tunable porosity of carbon-based nanomaterials. Simultaneously, de novo structure-based computational design methods are being used to design more selective and stable ligands and the most promising candidates are being synthesized, tested and evaluated for incorporation onto a support matrix. Fundamental thermodynamic and kinetic studies are being carried out to improve the adsorption efficiency, the selectivity of uranium over other metals, and the stability of the adsorbents. Understanding the rate-limiting step of uranium uptake from seawater is also essential in designing an effective uranium recovery system. Finally, economic analyses have been used to guide these studies and highlight what parameters, such as capacity, recyclability, and stability, have the largest impact on the cost of extraction of uranium from seawater. Initially, the cost estimates by the JAEA for extraction of uranium from seawater with braided polymeric fibers functionalized with amidoxime ligands were evaluated and updated. The economic analyses were subsequently updated to reflect the results of this project while providing insight for cost reductions in the adsorbent development through “cradle-to-grave” case studies for the extraction process. This report highlights the progress made over the last three years on the design, synthesis, and testing of new materials to extract uranium for seawater. This report is organized into sections that highlight the major research activities in this project: (1) Chelate Design and Modeling, (2) Thermodynamics, Kinetics and Structure, (3) Advanced Polymeric Adsorbents by Radiation Induced Grafting, (4) Advanced Nanomaterial Adsorbents, (5) Adsorbent Screening and Modeling, (6) Marine Testing, and (7) Cost and Energy Assessment. At the end of each section, future research directions are briefly discussed to highlight the challenges that still remain to reduce the cost of extractions of uranium for seawater. Finally, contributions from the Nuclear Energy University Programs (NEUP), which complement this research program, are included at the end of this report.

  12. Uranium in Framboidal Pyrite from a Naturally Bioreduced Alluvial...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Framboidal Pyrite from a Naturally Bioreduced Alluvial Sediment . Uranium in Framboidal Pyrite from a Naturally Bioreduced Alluvial Sediment . Abstract: Samples of a naturally...

  13. Microscopic Reactive Diffusion of Uranium in the Contaminated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    States. Abstract: Microscopic and spectroscopic analysis of uranium-contaminated sediment cores beneath the BX waste tank farm at the US Department of Energy (DOE) Hanford...

  14. NNSA Authorizes Start-Up of Highly Enriched Uranium Materials...

    National Nuclear Security Administration (NNSA)

    Authorizes Start-Up of Highly Enriched Uranium Materials Facility at Y-12 | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the...

  15. Method of fabricating a uranium-bearing foil

    DOE Patents [OSTI]

    Gooch, Jackie G. (Seymour, TN); DeMint, Amy L. (Kingston, TN)

    2012-04-24T23:59:59.000Z

    Methods of fabricating a uranium-bearing foil are described. The foil may be substantially pure uranium, or may be a uranium alloy such as a uranium-molybdenum alloy. The method typically includes a series of hot rolling operations on a cast plate material to form a thin sheet. These hot rolling operations are typically performed using a process where each pass reduces the thickness of the plate by a substantially constant percentage. The sheet is typically then annealed and then cooled. The process typically concludes with a series of cold rolling passes where each pass reduces the thickness of the plate by a substantially constant thickness amount to form the foil.

  16. Uranium Leasing Program Draft PEIS Public Comment Period Extended...

    Broader source: Energy.gov (indexed) [DOE]

    Uranium Leasing Program Draft PEIS Public Comment Period Extended to May 31, 2013 Draft ULPEIS comment extension community notification041813 (3).pdf More Documents & Publications...

  17. Uranium immobilization by sulfate-reducing biofilms grown on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    immobilization by sulfate-reducing biofilms grown on hematite, dolomite, and calcite. Uranium immobilization by sulfate-reducing biofilms grown on hematite, dolomite, and calcite....

  18. Electrochemical method of producing eutectic uranium alloy and apparatus

    DOE Patents [OSTI]

    Horton, J.A.; Hayden, H.W.

    1995-01-10T23:59:59.000Z

    An apparatus and method are disclosed for continuous production of liquid uranium alloys through the electrolytic reduction of uranium chlorides. The apparatus includes an electrochemical cell formed from an anode shaped to form an electrolyte reservoir, a cathode comprising a metal, such as iron, capable of forming a eutectic uranium alloy having a melting point less than the melting point of pure uranium, and molten electrolyte in the reservoir comprising a chlorine or fluorine containing salt and uranium chloride. The method of the invention produces an eutectic uranium alloy by creating an electrolyte reservoir defined by a container comprising an anode, placing an electrolyte in the reservoir, the electrolyte comprising a chlorine or fluorine containing salt and uranium chloride in molten form, positioning a cathode in the reservoir where the cathode comprises a metal capable of forming an uranium alloy having a melting point less than the melting point of pure uranium, and applying a current between the cathode and the anode. 2 figures.

  19. Uranium-contaminated soils: Ultramicrotomy and electron beam analysis

    SciTech Connect (OSTI)

    Buck, E.C.; Dietz, N.L.; Bates, J.K.; Cunnane, J.C.

    1994-04-01T23:59:59.000Z

    Uranium contaminated soils from the Fernald Operation Site, Ohio, have been examined by a combination of optical microscopy, scanning electron microscopy with backscattered electron detection (SEM/BSE), and analytical electron microscopy (AEM). A method is described for preparing of transmission electron microscopy (TEM) thin sections by ultramicrotomy. By using these thin sections, SEM and TEM images can be compared directly. Uranium was found in iron oxides, silicates (soddyite), phosphates (autunites), and fluorite. Little uranium was associated with clays. The distribution of uranium phases was found to be inhomogeneous at the microscopic level.

  20. High grade uranium resources in the United States : an overview

    E-Print Network [OSTI]

    Graves, Richard E.

    1974-01-01T23:59:59.000Z

    A time analysis of uranium exploration, production and known reserves in the United States is employed to reveal industry trends. The

  1. Uranium and Strontium Batch Sorption and Diffusion Kinetics into...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Uranium and Strontium Batch Sorption and Diffusion Kinetics into Mesoporous Silica Friday, February 27, 2015 Figure 1 Figure 1. Transmission electron microscopy images of (A)...

  2. Basic characterization of highly enriched uranium by gamma spectrometry

    E-Print Network [OSTI]

    Cong Tam Nguyen; Jozsef Zsigrai

    2005-08-25T23:59:59.000Z

    Gamma-spectrometric methods suitable for the characterization of highly enriched uranium samples encountered in illicit trafficking of nuclear materials are presented. In particular, procedures for determining the 234U, 235U, 238U, 232U and 236U contents and the age of highly enriched uranium are described. Consequently, the total uranium content and isotopic composition can be calculated. For determining the 238U and 232U contents a low background chamber was used. In addition, age dating of uranium was also performed using low-background spectrometry.

  3. Basic characterization of highly enriched uranium by gamma spectrometry

    E-Print Network [OSTI]

    Nguyen, C T

    2006-01-01T23:59:59.000Z

    Gamma-spectrometric methods suitable for the characterization of highly enriched uranium samples encountered in illicit trafficking of nuclear materials are presented. In particular, procedures for determining the 234U, 235U, 238U, 232U and 236U contents and the age of highly enriched uranium are described. Consequently, the total uranium content and isotopic composition can be calculated. For determining the 238U and 232U contents a low background chamber was used. In addition, age dating of uranium was also performed using low-background spectrometry.

  4. Measurements of uranium in soils and small mammals

    SciTech Connect (OSTI)

    Miera, F.R. Jr.

    1980-12-01T23:59:59.000Z

    The objective of this study was to evaluate the bioavailability of uranium to a single species of small mammal, Peromyscus maniculatus rufinus (Merriam), white-footed deer mouse, from two different source terms: a Los Alamos National Laboratory dynamic weapons testing site in north central New Mexico, where an estimated 70,000 kg of uranium have been expended over a 31-y period; and an inactive uranium mill tailings pile located in west central New Mexico near Grants, which received wastes over a 5-y period from the milling of 2.7 x 10/sup 9/ kg of uranium ore.

  5. EIS-0472: Uranium Leasing Program, Mesa, Montrose, and San Miguel...

    Broader source: Energy.gov (indexed) [DOE]

    Uranium Leasing Program, Mesa, Montrose, and San Miguel Counties, Colorado March 15, 2013 EIS-0472: DOE Notice of Availability of a Draft Programmatic Environmental Impact...

  6. Uranium biokinetics in gavaged young adult female rats.

    E-Print Network [OSTI]

    Keizer, Philip John

    1986-01-01T23:59:59.000Z

    ??Blood, liver, kidney, femur, and ovaries were assayed from female Wistar rats following oral administration of uranyl nitrate. Three uranium concentrations were studied for six… (more)

  7. Assessment of Controlling Processes for Field-Scale Uranium Reactive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at the 300A site. However, the model simulations also revealed that the groundwater chemistry was relatively stable during the uranium tracer experiment and therefore...

  8. americium plutonium uranium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a fascinating ele- ment. Last year, we learned that some com- pounds of plutonium superconduct at sur- prisingly Steinberger, Bernhard 110 Standard specification for uranium...

  9. Secretarial Determination of No Adverse Material Impact for Uranium...

    Energy Savers [EERE]

    set forth in the 2012 Secretarial Determination and the Department's Excess Uranium Inventory Management Plan released in July 2013. Secretarial Determination 5-15-14.pdf More...

  10. Collaboration and Communication: DOE and Navajo Nation Tour Uranium...

    Broader source: Energy.gov (indexed) [DOE]

    site managers, along with Navajo Nation technical staff, visited five reclaimed uranium-mine sites on tribal lands to share expertise in the use of technical approaches...

  11. Financial Assurance for In Situ Uranium Facilities (Texas)

    Broader source: Energy.gov [DOE]

    Owners or operators are required to provide financial assurance for in situ uranium sites. This money is required for: decommissioning, decontamination, demolition, and waste disposal for buildings...

  12. Selective leaching of uranium from uranium-contaminated soils: Progress report 1

    SciTech Connect (OSTI)

    Francis, C.W.; Mattus, A.J.; Farr, L.L.; Elless, M.P.; Lee, S.Y.

    1993-02-01T23:59:59.000Z

    Three soils and a sediment contaminated with uranium were used to determine the effectiveness of sodium carbonate and citric acid leaching to decontaminated or remove uranium to acceptable regulatory levels. Two of the soils were surface soils from the DOE facility formerly called the Feed Materials Production Center (FMPC) at Fernald, Ohio. This facility is presently called the Femald Environmental Management Project (FEMP). Carbonate extractions generally removed from 70 to 90% of the uranium from the Fernald storage pad soil. Uranium was slightly more difficult to extract from the Fernald incinerator and the Y-12 landfarm soils. Very small amounts of uranium could be extracted from the storm sewer sediment. Extraction with carbonate at high solution-to-soil ratios were as effective as extractions at low solution-to-soil ratios, indicating attrition by the paddle mixer was not significantly different than that provided in a rotary extractor. Also, pretreatments such as milling or pulverizing the soil sample did not appear to increase extraction efficiency when carbonate extractions were carried out at elevated temperatures (60[degree]C) or long extraction times (23 h). Adding KMnO[sub 4] in the carbonate extraction appeared to increase extraction efficiency from the Fernald incinerator soil but not the Fernald storage pad soil. The most effective leaching rates (> 90 % from both Fernald soils) were obtained using a citrate/dithionite extraction procedure designed to remove amorphous (noncrystalline) iron/aluminum sesquioxides from surfaces of clay minerals. Citric acid also proved to be a very good extractant for uranium.

  13. Selective leaching of uranium from uranium-contaminated soils: Progress report 1

    SciTech Connect (OSTI)

    Francis, C.W.; Mattus, A.J.; Farr, L.L.; Elless, M.P.; Lee, S.Y.

    1993-02-01T23:59:59.000Z

    Three soils and a sediment contaminated with uranium were used to determine the effectiveness of sodium carbonate and citric acid leaching to decontaminated or remove uranium to acceptable regulatory levels. Two of the soils were surface soils from the DOE facility formerly called the Feed Materials Production Center (FMPC) at Fernald, Ohio. This facility is presently called the Femald Environmental Management Project (FEMP). Carbonate extractions generally removed from 70 to 90% of the uranium from the Fernald storage pad soil. Uranium was slightly more difficult to extract from the Fernald incinerator and the Y-12 landfarm soils. Very small amounts of uranium could be extracted from the storm sewer sediment. Extraction with carbonate at high solution-to-soil ratios were as effective as extractions at low solution-to-soil ratios, indicating attrition by the paddle mixer was not significantly different than that provided in a rotary extractor. Also, pretreatments such as milling or pulverizing the soil sample did not appear to increase extraction efficiency when carbonate extractions were carried out at elevated temperatures (60{degree}C) or long extraction times (23 h). Adding KMnO{sub 4} in the carbonate extraction appeared to increase extraction efficiency from the Fernald incinerator soil but not the Fernald storage pad soil. The most effective leaching rates (> 90 % from both Fernald soils) were obtained using a citrate/dithionite extraction procedure designed to remove amorphous (noncrystalline) iron/aluminum sesquioxides from surfaces of clay minerals. Citric acid also proved to be a very good extractant for uranium.

  14. Corrosion Evaluation of RERTR Uranium Molybdenum Fuel

    SciTech Connect (OSTI)

    A K Wertsching

    2012-09-01T23:59:59.000Z

    As part of the National Nuclear Security Agency (NNSA) mandate to replace the use of highly enriched uranium (HEU) fuel for low enriched uranium (LEU) fuel, research into the development of LEU fuel for research reactors has been active since the late 1970’s. Originally referred to as the Reduced Enrichment for Research and Test Reactor (RERTR) program the new effort named Global Threat Reduction Initiative (GTRI) is nearing the goal of replacing the standard aluminum clad dispersion highly enriched uranium aluminide fuel with a new LEU fuel. The five domestic high performance research reactors undergoing this conversion are High Flux Isotope reactor (HFIR), Advanced Test Reactor (ATR), National Institute of Standards and Technology (NIST) Reactor, Missouri University Research Reactor (MURR) and the Massachusetts Institute of Technology Reactor II (MITR-II). The design of these reactors requires a higher neutron flux than other international research reactors, which to this point has posed unique challenges in the design and development of the new mandated LEU fuel. The new design utilizes a monolithic fuel configuration in order to obtain sufficient 235U within the LEU stoichoimetry to maintain the fission reaction within the domestic test reactors. The change from uranium aluminide dispersion fuel type to uranium molybdenum (UMo) monolithic configuration requires examination of possible corrosion issues associated with the new fuel meat. A focused analysis of the UMo fuel under potential corrosion conditions, within the ATR and under aqueous storage indicates a slow and predictable corrosion rate. Additional corrosion testing is recommended for the highest burn-up fuels to confirm observed corrosion rate trends. This corrosion analysis will focus only on the UMo fuel and will address corrosion of ancillary components such as cladding only in terms of how it affects the fuel. The calculations and corrosion scenarios are weighted with a conservative bias to provide additional confidence with the results. The actual corrosion rates of UMo fuel is very likely to be lower than assumed within this report which can be confirmed with additional testing.

  15. Decolonizing cartographies : sovereignty, territoriality, and maps of meaning in the uranium landscape

    E-Print Network [OSTI]

    Voyles, Traci Brynne

    2010-01-01T23:59:59.000Z

    the open-pit mining employed elsewhere in uranium landscape.as open-pit and underground uranium mining. Local residents,

  16. EA-1172: Sale of Surplus Natural and Low Enriched Uranium, Piketon, Ohio

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to sell uranium for subsequent enrichment and fabrication into commercial nuclear power reactor fuel.  The uranium is currently stored...

  17. Novel Transformations using Uranium and Group 5 Metal Complexes Supported by 1,1'-diamidoferrocene Ligands

    E-Print Network [OSTI]

    Lopez, Michael Joseph

    2013-01-01T23:59:59.000Z

    Chemistry by Michael Joseph Lopez ABSTRACT OF THE THESIS Novel Transformations using Uranium andchemistry has grown significantly in the past decade. 1 Uranium

  18. CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV)

    E-Print Network [OSTI]

    Andersen, Richard A.

    2012-01-01T23:59:59.000Z

    Chemistry CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTRIS[BIS(TRIMETHYLSILYL)AMIDO]URANIUM(Chemistry University of California Berkeley, California 94720 New hydride derivatives of thorium (IV) and uranium (

  19. E-Print Network 3.0 - aqueuous uranium complexes Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12;Breccia complex deposits: This is a type of uranium formations that occur near... Uranium geology and mining Ranger ... Source: Uppsala Universitet, Department of...

  20. E-Print Network 3.0 - adsorbing uranium compounds Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compound, davidite-brannerite-absite type of uranium titanates and the euxenite... Uranium geology and mining Ranger 1 ... Source: Uppsala Universitet, Department of...

  1. E-Print Network 3.0 - alloyed uranium transformation Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the sink term in the governing mass balance equation and the transformation from average uranium... Mathematical Geology, Vol. 33, No. 1, 2001 Modeling Uranium Transport in ......

  2. Stratigraphy of the PB-1 well, Nopal I uranium deposit, Sierra Pena Blanca, Chihuahua, Mexico

    E-Print Network [OSTI]

    Dobson, P.

    2009-01-01T23:59:59.000Z

    P.C. , 1981, Geology of the Peña Blanca uranium deposits,uranium mineralizations in the Sierra Peña Blanca district, Chihuahua, Mexico: Three genetic models: Economic Geology,

  3. Stability of uranium incorporated into Fe(hydr)oxides under fluctuating redox conditions

    E-Print Network [OSTI]

    Stewart, B.D.

    2009-01-01T23:59:59.000Z

    uranium budgets and behavior along a Hawaiian chronosequence. Chemical GeologyUranium isotopic evidence for the origin of the Bahariya iron deposits, Egypt. Ore Geology

  4. Process for recovering uranium from waste hydrocarbon oils containing the same. [Uranium contaminated lubricating oils from gaseous diffusion compressors

    DOE Patents [OSTI]

    Conrad, M.C.; Getz, P.A.; Hickman, J.E.; Payne, L.D.

    1982-06-29T23:59:59.000Z

    The invention is a process for the recovery of uranium from uranium-bearing hydrocarbon oils containing carboxylic acid as a degradation product. In one aspect, the invention comprises providing an emulsion of water and the oil, heating the same to a temperature effecting conversion of the emulsion to an organic phase and to an acidic aqueous phase containing uranium carboxylate, and recovering the uranium from the aqueous phase. The process is effective, simple and comparatively inexpensive. It avoids the use of toxic reagents and the formation of undesirable intermediates.

  5. Development of Novel Sorbents for Uranium Extraction from Seawater

    SciTech Connect (OSTI)

    Lin, Wenbin; Taylor-Pashow, Kathryn

    2014-01-08T23:59:59.000Z

    As the uranium resource in terrestrial ores is limited, it is difficult to ensure a long-term sustainable nuclear energy technology. The oceans contain approximately 4.5 billion tons of uranium, which is one thousand times the amount of uranium in terrestrial ores. Development of technologies to recover the uranium from seawater would greatly improve the uranium resource availability, sustaining the fuel supply for nuclear energy. Several methods have been previously evaluated including solvent extraction, ion exchange, flotation, biomass collection, and adsorption; however, none have been found to be suitable for reasons such as cost effectiveness, long term stability, and selectivity. Recent research has focused on the amidoxime functional group as a promising candidate for uranium sorption. Polymer beads and fibers have been functionalized with amidoxime functional groups, and uranium adsorption capacities as high as 1.5 g U/kg adsorbent have recently been reported with these types of materials. As uranium concentration in seawater is only ~3 ppb, great improvements to uranium collection systems must be made in order to make uranium extraction from seawater economically feasible. This proposed research intends to develop transformative technologies for economic uranium extraction from seawater. The Lin group will design advanced porous supports by taking advantage of recent breakthroughs in nanoscience and nanotechnology and incorporate high densities of well-designed chelators into such nanoporous supports to allow selective and efficient binding of uranyl ions from seawater. Several classes of nanoporous materials, including mesoporous silica nanoparticles (MSNs), mesoporous carbon nanoparticles (MCNs), meta-organic frameworks (MOFs), and covalent-organic frameworks (COFs), will be synthesized. Selective uranium-binding liagnds such as amidoxime will be incorporated into the nanoporous materials to afford a new generation of sorbent materials that will be evaluated for their uranium extraction efficiency. The initial testing of these materials for uranium binding will be carried out in the Lin group, but more detailed sorption studies will be carried out by Dr. Taylor-Pashow of Savannah River National Laboratory in order to obtain quantitative uranyl sorption selectivity and kinetics data for the proposed materials. The proposed nanostructured sorbent materials are expected to have higher binding capacities, enhanced extraction kinetics, optimal stripping efficiency for uranyl ions, and enhanced mechanical and chemical stabilities. This transformative research will significantly impact uranium extraction from seawater as well as benefit DOE’s efforts on environmental remediation by developing new materials and providing knowledge for enriching and sequestering ultralow concentrations of other metals.

  6. Mixed uranium dicarbide and uranium dioxide microspheres and process of making same

    DOE Patents [OSTI]

    Stinton, David P. (Knoxville, TN)

    1983-01-01T23:59:59.000Z

    Nuclear fuel microspheres are made by sintering microspheres containing uranium dioxide and uncombined carbon in a 1 mole percent carbon monoxide/99 mole percent argon atmosphere at 1550.degree. C. and then sintering the microspheres in a 3 mole percent carbon monoxide/97 mole percent argon atmosphere at the same temperature.

  7. Appendix IV. Risks Associated with Conventional Uranium Milling Introduction

    E-Print Network [OSTI]

    by the addition of water/lixiviant is generally collected by air pollution control mechanisms, which return as in situ leaching (ISL) mining operations, to provide a more complete picture of uranium production. While this report focuses on the impacts associated with conventional surface and underground uranium mines

  8. Process for recovering niobium from uranium-niobium alloys

    DOE Patents [OSTI]

    Wallace, Steven A. (Knoxville, TN); Creech, Edward T. (Oak Ridge, TN); Northcutt, Walter G. (Oak Ridge, TN)

    1983-01-01T23:59:59.000Z

    Niobium is recovered from scrap uranium-niobium alloy by melting the scrap with tin, solidifying the billet thus formed, heating the billet to combine niobium with tin therein, placing the billet in hydrochloric acid to dissolve the uranium and leave an insoluble residue of niobium stannide, then separating the niobium stannide from the acid.

  9. In-line assay monitor for uranium hexafluoride

    DOE Patents [OSTI]

    Wallace, Steven A. (Knoxville, TN)

    1981-01-01T23:59:59.000Z

    An in-line assay monitor for determining the content of uranium-235 in a uranium hexafluoride gas isotopic separation system is provided which removes the necessity of complete access to the operating parameters of the system for determining the uranium-235 content. The monitor is intended for uses such as safeguard applications to assure that weapons grade uranium is not being produced in an enrichment cascade. The method and monitor for carrying out the method involve cooling of a radiation pervious chamber connected in fluid communication with the selected point in the system to withdraw a specimen and solidify the specimen in the chamber. The specimen is irradiated by means of an ionizing radiation source of energy different from that of the 185 keV gamma emissions from the uranium-235 present in the specimen. Simultaneously, the gamma emissions from the uranium-235 of the specimen and the source emissions transmitted through the sample are counted and stored in a multiple channel analyzer. The uranium-235 content of the specimen is determined from the comparison of the accumulated 185 keV energy counts and the reference energy counts. The latter is used to measure the total uranium isotopic content of the specimen. The process eliminates the necessity of knowing the system operating conditions and yet obtains the necessary data without need for large scintillation crystals and sophisticated mechanical designs.

  10. Uranium and cesium diffusion in fuel cladding of electrogenerating channel

    SciTech Connect (OSTI)

    Vasil’ev, I. V., E-mail: fnti@mail.ru; Ivanov, A. S.; Churin, V. A. [National Research Center Kurchatov Institute (Russian Federation)

    2014-12-15T23:59:59.000Z

    The results of reactor tests of a carbonitride fuel in a single-crystal cladding from a molybdenum-based alloy can be used in substantiating the operational reliability of fuels in developing a project of a megawatt space nuclear power plant. The results of experimental studies of uranium and cesium penetration into the single-crystal cladding of fuel elements with a carbonitride fuel are interpreted. Those fuel elements passed nuclear power tests in the Ya-82 pilot plant for 8300 h at a temperature of about 1500°C. It is shown that the diffusion coefficients for uranium diffusion into the cladding are virtually coincident with the diffusion coefficients measured earlier for uranium diffusion into polycrystalline molybdenum. It is found that the penetration of uranium into the cladding is likely to occur only in the case of a direct contact between the cladding and fuel. The experimentally observed nonmonotonic uranium-concentration profiles are explained in terms of predominant uranium diffusion along grain boundaries. It is shown that a substantially nonmonotonic behavior observed in our experiment for the uranium-concentration profile may be explained by the presence of a polycrystalline structure of the cladding in the surface region from its inner side. The diffusion coefficient is estimated for the grain-boundary diffusion of uranium. The diffusion coefficients for cesium are estimated on the basis of experimental data obtained in the present study.

  11. Uranium in US surface, ground, and domestic waters. Volume 2

    SciTech Connect (OSTI)

    Drury, J.S.; Reynolds, S.; Owen, P.T.; Ross, R.H.; Ensminger, J.T.

    1981-04-01T23:59:59.000Z

    The report Uranium in US Surface, Ground, and Domestic Waters comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium conentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms.

  12. Process for recovering niobium from uranium-niobium alloys

    DOE Patents [OSTI]

    Wallace, S.A.; Creech, E.T.; Northcutt, W.G.

    1982-09-27T23:59:59.000Z

    Niobium is recovered from scrap uranium-niobium alloy by melting the scrap with tin, solidifying the billet thus formed, heating the billet to combine niobium with tin therein, placing the billet in hydrochloric acid to dissolve the uranium and form a precipitate of niobium stannide, then separating the precipitate from the acid.

  13. NUREG/CR-6911 Tests of Uranium (VI) Adsorption

    E-Print Network [OSTI]

    NUREG/CR-6911 Tests of Uranium (VI) Adsorption Models in a Field Setting U.S. Geological Survey U/CR-6911 Tests of Uranium (VI) Adsorption Models in a Field Setting Manuscript Completed: August 2006 Date Published: August 2006 Prepared by G. P. Curtis, J. A. Davis Water Resources Division U.S. Geological Survey

  14. Spectroscopic Evidence for Uranium Bearing Precipitates in Vadose Zone

    E-Print Network [OSTI]

    Spectroscopic Evidence for Uranium Bearing Precipitates in Vadose Zone Sediments at the Hanford 300, Advanced Light Source, One Cyclotron Road, Berkeley, California 94720, United States Geological Survey Northwest Laboratory, Richland, Washington 99352 Uranium (U) solid-state speciation in vadose zone sediments

  15. Case Study/ Effects of Groundwater Development on Uranium

    E-Print Network [OSTI]

    Case Study/ Effects of Groundwater Development on Uranium: Central Valley, California, USA Abstract Uranium (U) concentrations in groundwater in several parts of the eastern San Joaquin Valley products sold (U.S. Department of 1Corresponding author: U.S. Geological Survey, California Water Science

  16. Electron Microbeam Investigation of Uranium-Contaminated Soils from

    E-Print Network [OSTI]

    Zhu, Chen

    Research Electron Microbeam Investigation of Uranium-Contaminated Soils from Oak Ridge, TN, USA J O Street, Baltimore, Maryland 21218, Department of Geological Sciences, Indiana University, 1001 East 10th Street, Bloomington, Indiana 47405 Two samples of uranium-contaminated soil from the Department of Energy

  17. Modeled atmospheric radon concentrations from uranium mines

    SciTech Connect (OSTI)

    Droppo, J.G.

    1985-04-01T23:59:59.000Z

    Uranium mining and milling operations result in the release of radon from numerous sources of various types and strengths. The US Environmental Protection Agency (EPA) under the Clean Air Act, is assessing the health impact of air emissions of radon from underground uranium mines. In this case, the radon emissions may impact workers and residents in the mine vicinity. To aid in this assessment, the EPA needs to know how mine releases can affect the radon concentrations at populated locations. To obtain this type of information, Pacific Northwest Laboratory used the radon emissions, release characteristics and local meterological conditions for a number of mines to model incremental radon concentrations. Long-term, average, incremental radon concentrations were computed based on the best available information on release rates, plume rise parameters, number and locations of vents, and local dispersion climatology. Calculations are made for a model mine, individual mines, and multiple mines. Our approach was to start with a general case and then consider specific cases for comparison. A model underground uranium mine was used to provide definition of the order of magnitude of typical impacts. Then computations were made for specific mines using the best mine-specific information available for each mine. These case study results are expressed as predicted incremental radon concentration contours plotted on maps with local population data from a previous study. Finally, the effect of possible overlap of radon releases from nearby mines was studied by calculating cumulative radon concentrations for multiple mines in a region with many mines. The dispersion model, modeling assumptions, data sources, computational procedures, and results are documented in this report. 7 refs., 27 figs., 18 tabs.

  18. Production of Mo-99 using low-enriched uranium silicide

    SciTech Connect (OSTI)

    Hutter, J. C.; Srinivasan, B.; Vicek, M.; Vandegrift, G. F.

    1994-09-01T23:59:59.000Z

    Over the last several years, uranium silicide fuels have been under development as low-enriched uranium (LEU) targets for Mo-99. The use of LEU silicide is aimed at replacing the UAl{sub x} alloy in the highly-enriched uranium dissolution process. A process to recover Mo-99 from low-enriched uranium silicide is being developed at Argonne National Laboratory. The uranium silicide is dissolved in alkaline hydrogen peroxide. Experiments performed to determine the optimum dissolution procedure are discussed, and the results of dissolving a portion of a high-burnup (>40%) U{sub 3}Si{sub 2} miniplate are presented. Future work related to Mo-99 separation and waste disposal are also discussed.

  19. Selective Extraction of Uranium from Liquid or Supercritical Carbon Dioxide

    SciTech Connect (OSTI)

    Farawila, Anne F.; O'Hara, Matthew J.; Wai, Chien M.; Taylor, Harry Z.; Liao, Yu-Jung

    2012-07-31T23:59:59.000Z

    Current liquid-liquid extraction processes used in recycling irradiated nuclear fuel rely on (1) strong nitric acid to dissolve uranium oxide fuel, and (2) the use of aliphatic hydrocarbons as a diluent in formulating the solvent used to extract uranium. The nitric acid dissolution process is not selective. It dissolves virtually the entire fuel meat which complicates the uranium extraction process. In addition, a solvent washing process is used to remove TBP degradation products, which adds complexity to the recycling plant and increases the overall plant footprint and cost. A liquid or supercritical carbon dioxide (l/sc -CO2) system was designed to mitigate these problems. Indeed, TBP nitric acid complexes are highly soluble in l/sc -CO2 and are capable of extracting uranium directly from UO2, UO3 and U3O8 powders. This eliminates the need for total acid dissolution of the irradiated fuel. Furthermore, since CO2 is easily recycled by evaporation at room temperature and pressure, it eliminates the complex solvent washing process. In this report, we demonstrate: (1) A reprocessing scheme starting with the selective extraction of uranium from solid uranium oxides into a TBP-HNO3 loaded Sc-CO2 phase, (2) Back extraction of uranium into an aqueous phase, and (3) Conversion of recovered purified uranium into uranium oxide. The purified uranium product from step 3 can be disposed of as low level waste, or mixed with enriched uranium for use in a reactor for another fuel cycle. After an introduction on the concept and properties of supercritical fluids, we first report the characterization of the different oxides used for this project. Our extraction system and our online monitoring capability using UV-Vis absorbance spectroscopy directly in sc-CO2 is then presented. Next, the uranium extraction efficiencies and kinetics is demonstrated for different oxides and under different physical and chemical conditions: l/sc -CO2 pressure and temperature, TBP/HNO3 complex used, reductant or complexant used for selectivity, and ionic liquids used as supportive media. To complete the extraction and recovery cycle, we then demonstrate uranium back extraction from the TBP loaded sc-CO2 phase into an aqueous phase and the characterization of the uranium complex formed at the end of this process. Another aspect of this project was to limit proliferation risks by either co-extracting uranium and plutonium, or by leaving plutonium behind by selectively extracting uranium. We report that the former is easily achieved, since plutonium is in the tetravalent or hexavalent oxidation state in the oxidizing environment created by the TBP-nitric acid complex, and is therefore co-extracted. The latter is more challenging, as a reductant or complexant to plutonium has to be used to selectively extract uranium. After undertaking experiments on different reducing or complexing systems (e.g., AcetoHydroxamic Acid (AHA), Fe(II), ascorbic acid), oxalic acid was chosen as it can complex tetravalent actinides (Pu, Np, Th) in the aqueous phase while allowing the extraction of hexavalent uranium in the sc-CO2 phase. Finally, we show results using an alternative media to commonly used aqueous phases: ionic liquids. We show the dissolution of uranium in ionic liquids and its extraction using sc-CO2 with and without the presence of AHA. The possible separation of trivalent actinides from uranium is also demonstrated in ionic liquids using neodymium as a surrogate and diglycolamides as the extractant.

  20. National uranium resource evaluation: Clifton Quadrangle, Arizona and New Mexico

    SciTech Connect (OSTI)

    White, D L; Foster, M

    1982-05-01T23:59:59.000Z

    The Clifton Quadrangle, Arizona and New Mexico, was evaluated to identify environments and delineate areas favorable for uranium deposits. The evaluation used criteria formulated for the National Uranium Resource Evaluation program. Evidence for the evaluation was based on surface studies, hydrogeochemical and stream-sediment reconnaissance, and aerial radiometric surveys. The quadrangle encompasses parts of three physiographic provinces: the Colorado Plateau, the transition zone, and the Basin and Range. The one environment determined, during the present study, to be favorable for uranium deposits is the Whitewater Creek member of the Cooney tuff, which is favorable for magmatic-hydrothermal uranium deposits on the west side of the Bursum caldera. No other areas were favorable for uranium deposits in sandstone, limestone, volcanogenic, igneous, or metamorphic environments. The subsurface is unevaluated because of lack of information, as are areas where access is a constraint.

  1. Active neutron multiplicity counting of bulk uranium

    SciTech Connect (OSTI)

    Ensslin, N.; Krick, M.S.; Langner, D.G.; Miller, M.C.

    1991-01-01T23:59:59.000Z

    This paper describes a new nondestructive assay technique being developed to assay bulk uranium containing kilogram quantities of {sup 235}U. The new technique uses neutron multiplicity analysis of data collected with a coincidence counter outfitted with AmLi neutron sources. We have calculated the expected neutron multiplicity count rate and assay precision for this technique and will report on its expected performance as a function of detector design characteristics, {sup 235 }U sample mass, AmLi source strength, and source-to-sample coupling. 11 refs., 2 figs., 2 tabs.

  2. Uranium Management and Policy | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEM with EDAXUpdatedEnergyUranium Management

  3. Uranium Marketing Annual Report - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version) Themonthly4 Oil(EIA)Uranium

  4. SciTech Connect: enriched uranium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2) CawithMicrofluidicJournalWhat is aenriched uranium

  5. U.S. Uranium Reserves Estimates

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand28 198 18Biomass GasPropane,Major U.S. Uranium

  6. U.S. Uranium Reserves Estimates

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand28 198 18Biomass GasPropane,Major U.S. Uranium1. U.S.

  7. U.S. Uranium Reserves Estimates

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand28 198 18Biomass GasPropane,Major U.S. Uranium1.

  8. Innovative Elution Processes for Recovering Uranium from Seawater

    SciTech Connect (OSTI)

    Wai, Chien; Tian, Guoxin; Janke, Christopher

    2014-05-29T23:59:59.000Z

    Utilizing amidoxime-based polymer sorbents for extraction of uranium from seawater has attracted considerable interest in recent years. Uranium collected in the sorbent is recovered typically by elution with an acid. One drawback of acid elution is deterioration of the sorbent which is a significant factor that limits the economic competitiveness of the amidoxime-based sorbent systems for sequestering uranium from seawater. Developing innovative elution processes to improve efficiency and to minimize loss of sorbent capacity become essential in order to make this technology economically feasible for large-scale industrial applications. This project has evaluated several elution processes including acid elution, carbonate elution, and supercritical fluid elution for recovering uranium from amidoxime-based polymer sorbents. The elution efficiency, durability and sorbent regeneration for repeated uranium adsorption- desorption cycles in simulated seawater have been studied. Spectroscopic techniques are used to evaluate chemical nature of the sorbent before and after elution. A sodium carbonate-hydrogen peroxide elution process for effective removal of uranium from amidoxime-based sorbent is developed. The cause of this sodium carbonate and hydrogen peroxide synergistic leaching of uranium from amidoxime-based sorbent is attributed to the formation of an extremely stable uranyl peroxo-carbonato complex. The efficiency of uranium elution by the carbonate-hydrogen peroxide method is comparable to that of the hydrochloric acid elution but damage to the sorbent material is much less for the former. The carbonate- hydrogen peroxide elution also does not need any elaborate step to regenerate the sorbent as those required for hydrochloric acid leaching. Several CO2-soluble ligands have been tested for extraction of uranium from the sorbent in supercritical fluid carbon dioxide. A mixture of hexafluoroacetylacetone and tri-n-butylphosphate shows the best result but uranium removal from the sorbent reaches only 80% after 10 hours of leaching. Some information regarding coordination of vanadium with amidoxime molecules and elution of vanadium from amidoxime- based sorbents is also given in the report.

  9. Decommissioning of U.S. uranium production facilities

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    From 1980 to 1993, the domestic production of uranium declined from almost 44 million pounds U{sub 3}O{sub 8} to about 3 million pounds. This retrenchment of the U.S. uranium industry resulted in the permanent closing of many uranium-producing facilities. Current low uranium prices, excess world supply, and low expectations for future uranium demand indicate that it is unlikely existing plants will be reopened. Because of this situation, these facilities eventually will have to be decommissioned. The Uranium Mill Tailings and Radiation Control Act of 1978 (UMTRCA) vests the U.S. Environmental Protection Agency (EPA) with overall responsibility for establishing environmental standards for decommissioning of uranium production facilities. UMTRCA also gave the U.S. Nuclear Regulatory Commission (NRC) the responsibility for licensing and regulating uranium production and related activities, including decommissioning. Because there are many issues associated with decommissioning-environmental, political, and financial-this report will concentrate on the answers to three questions: (1) What is required? (2) How is the process implemented? (3) What are the costs? Regulatory control is exercised principally through the NRC licensing process. Before receiving a license to construct and operate an uranium producing facility, the applicant is required to present a decommissioning plan to the NRC. Once the plan is approved, the licensee must post a surety to guarantee that funds will be available to execute the plan and reclaim the site. This report by the Energy Information Administration (EIA) represents the most comprehensive study on this topic by analyzing data on 33 (out of 43) uranium production facilities located in Colorado, Nebraska, New Mexico, South Dakota, Texas, Utah, and Washington.

  10. Electrorefining process and apparatus for recovery of uranium and a mixture of uranium and plutonium from spent fuels

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL); Miller, William E. (Naperville, IL)

    1989-01-01T23:59:59.000Z

    An electrorefining process and apparatus for the recovery of uranium and a mixture of uranium and plutonium from spent fuel using an electrolytic cell having a lower molten cadmium pool containing spent nuclear fuel, an intermediate electrolyte pool, an anode basket containing spent fuel, and two cathodes, the first cathode composed of either a solid alloy or molten cadmium and the second cathode composed of molten cadmium. Using this cell, additional amounts of uranium and plutonium from the anode basket are dissolved in the lower molten cadmium pool, and then substantially pure uranium is electrolytically transported and deposited on the first alloy or molten cadmium cathode. Subsequently, a mixture of uranium and plutonium is electrotransported and deposited on the second molten cadmium cathode.

  11. Defining Conditions for Maximizing Bioreduction of Uranium

    SciTech Connect (OSTI)

    David C. White; Aaron D. Peacock; Yun-Juan Chang; Roland Geyer; Philip E. Long; Jonathan D. Istok; Amanda N.; R. Todd Anderson; Dora Ogles

    2004-03-17T23:59:59.000Z

    Correlations between modifying electron donor and acceptor accessibility, the in-situ microbial community, and bioreduction of Uranium at the FRC and UMTRA research sites indicated that significant modifications in the rate, amount and by inference the potential stability of immobilized Uranium are feasible in these environments. The in-situ microbial community at these sites was assessed with a combination of lipid and real-time molecular techniques providing quantitative insights of effects of electron donor and manipulations. Increased (9mM in 2003 vs 3mM 2002) donor amendment at the Old Rifle site resulted in the stimulation of anaerobic conditions downgradient of the injection gallery. Biomass within the test plot increased relative to the control well at 17 feet. Q-PCR specific for IRB/SRB showed increased copy numbers within the test plot and was the highest at the injection gallery. Q-PCR specific for Geobacter sp. showed increased copy numbers within the test plot but further downgradient from the injection gallery than the SRB/IRB. DNA and Lipid analysis confirm changes in the microbial community structure due to donor addition. See also the PNNL (Long) and UMASS (Anderson) posters for more information about this site.

  12. RIB Production with Photofission of Uranium

    E-Print Network [OSTI]

    Oganessian, Yu T; Kliman, J; Maslov, O D; Starodub, G Ya; Belov, A G; Tretyakova, S P

    2002-01-01T23:59:59.000Z

    The process of uranium photofission with electron beams of 20 div 50 MeV is considered in terms of the production of fission fragments. It is shown that in the interaction between an electron beam (25 MeV in energy and 20 mu A in intensity), produced by a compact accelerator of the microtron type, and a uranium target of about 40 g/cm^2 in thickness, an average of 1.5 cdot 10^11 fission events/second is generated. According to the calculations and test experiments, this corresponds to the yield of ^132 Sn and ^142 Xe isotopes of approximately 2 cdot 10^9/s. The results of experiments on the optimal design of the U-target are presented. Problems are discussed connected with the separation of isotopes and isobars for their furher acceleration up to energies of 5-18 MeV/n. The photofission reactions of a heavy nucleus are compared with other methods of RIB production of medium mass nuclei.

  13. Heterogeneous modeling of the uranium in situ recovery: Kinetic versus solubility Jrmy. Nosa,1, 2

    E-Print Network [OSTI]

    Boyer, Edmond

    Heterogeneous modeling of the uranium in situ recovery: Kinetic versus solubility control Jérémy Mines, Tour AREVA, 1 place Jean Millier, 92084 Paris La Défense Cedex, France The uranium in situ, into the deposit to selectively dissolve uranium. The solution enriched in uranium is pumped out and processed

  14. Short Communication Bioreduction and precipitation of uranium in ionic liquid aqueous

    E-Print Network [OSTI]

    Ohta, Shigemi

    with uranium from mining and milling operations, radioactive wastes, and from nuclear accidents is a majorShort Communication Bioreduction and precipitation of uranium in ionic liquid aqueous solution t s Uranium forms various complexes with ionic liquids. Uranium bioreduction was affected by the type

  15. Stability of uranium incorporated into Fe(hydr)oxides under fluctuating redox conditions

    E-Print Network [OSTI]

    Stewart, B.D.

    2009-01-01T23:59:59.000Z

    uranium deposit, Northern Australia - Lessons from the Alligator Rivers analogue project. Physics and Chemistry

  16. Complexation of Gluconate with Uranium(VI) in Acidic Solutions: Thermodynamic Study with Structural Analysis

    E-Print Network [OSTI]

    Zhang, Zhicheng

    2009-01-01T23:59:59.000Z

    uranium is approximately one order of magnitude lower than expected, suggesting that the coordination chemistry

  17. Final Scientific/Technical Report for Project entitled "Mechanism of Uranium Reduction by Shewanella oneidensis"

    SciTech Connect (OSTI)

    DiChristina, Thomas J. [Georgia Tech

    2013-04-30T23:59:59.000Z

    Final Scientific/Technical Report for Project entitled "Mechanism of Uranium Reduction by Shewanella oneidensis"

  18. E-Print Network 3.0 - arsenic manganese uranium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IN-SITU LEACHIN-SITU RECOVERY (ISLISR) SITES Radiation Protection Division Office... .1 Uranium Geology......

  19. Conversion and Blending Facility highly enriched uranium to low enriched uranium as uranyl nitrate hexahydrate. Revision 1

    SciTech Connect (OSTI)

    NONE

    1995-07-05T23:59:59.000Z

    This Conversion and Blending Facility (CBF) will have two missions: (1) convert HEU materials to pure HEU uranyl nitrate (UNH) and (2) blend pure HEU UNH with depleted and natural UNH to produce HEU UNH crystals. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. To the extent practical, the chemical and isotopic concentrations of blended LEU product will be held within the specifications required for LWR fuel. Such blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry. Otherwise, blended LEU Will be produced as a waste suitable for storage or disposal.

  20. Occupational exposures to uranium: processes, hazards, and regulations

    SciTech Connect (OSTI)

    Stoetzel, G.A.; Fisher, D.R.; McCormack, W.D.; Hoenes, G.R.; Marks, S.; Moore, R.H.; Quilici, D.G.; Breitenstein, B.D.

    1981-04-01T23:59:59.000Z

    The United States Uranium Registry (USUR) was formed in 1978 to investigate potential hazards from occupational exposure to uranium and to assess the need for special health-related studies of uranium workers. This report provides a summary of Registry work done to date. The history of the uranium industry is outlined first, and the current commercial uranium industry (mining, milling, conversion, enrichment, and fuel fabrication) is described. This description includes information on basic processes and areas of greatest potential radiological exposure. In addition, inactive commercial facilities and other uranium operations are discussed. Regulation of the commercial production industry for uranium fuel is reported, including the historic development of regulations and the current regulatory agencies and procedures for each phase of the industry. A review of radiological health practices in the industry - facility monitoring, exposure control, exposure evaluation, and record-keeping - is presented. A discussion of the nonradiological hazards of the industry is provided, and the final section describes the tissue program developed as part of the Registry.

  1. Dissolution rates of uranium compounds in simulated lung fluid

    SciTech Connect (OSTI)

    Kalkwarf, D.R.

    1981-01-01T23:59:59.000Z

    Maximum dissolution rates of uranium into simulated lung fluid from a variety of materials were measured at 37/sup 0/in the where f/sub i/ is in order to estimate clearance rates from the deep lung. A batch procedure was utilized in which samples containing as little as 10 ..mu..g of natural uranium could be tested. The materials included: products of uranium mining, milling and refining operations, coal fly ash, an environmental sample from a site exposed to multiple uranium sources, and purified samples of (NH/sub 4/)/sub 2/U/sub 2/O/sub 7/ U/sub 3/O/sub 8/, UO/sub 2/, and UF/sub 4/. Dissolution of uranium from several materials indicated the presence of more than one type of uranium compound; but in all cases, the fraction F of uranium remaining undissolved at any time t could be represented by the sum of up to three terms in the series: F = ..sigma../sub i/f/sub i/ exp (-0.693t/UPSILON/sub i/), where f/sub i/ is the initial fraction of component i with dissolution half-time epsilon/sub i/. Values of epsilon/sub i/ varied from 0.01 day to several thousand days depending on the physical and chemical form of the uranium. Dissolution occurred predominantly by formation of the (UO/sub 2/(CO/sub 3/)/sub 3/)/sup 4 -/ ion; and as a result, tetravalent uranium compounds dissolved slowly. Dissolution rates of size-separated yellow-cake aerosols were found to be more closely correlated with specific surface area than with aerodynamic diameter.

  2. Method of precipitating uranium from an aqueous solution and/or sediment

    DOE Patents [OSTI]

    Tokunaga, Tetsu K; Kim, Yongman; Wan, Jiamin

    2013-08-20T23:59:59.000Z

    A method for precipitating uranium from an aqueous solution and/or sediment comprising uranium and/or vanadium is presented. The method includes precipitating uranium as a uranyl vanadate through mixing an aqueous solution and/or sediment comprising uranium and/or vanadium and a solution comprising a monovalent or divalent cation to form the corresponding cation uranyl vanadate precipitate. The method also provides a pathway for extraction of uranium and vanadium from an aqueous solution and/or sediment.

  3. Heavy Ion Beam in Resolution of the Critical Point Problem for Uranium and Uranium Dioxide

    E-Print Network [OSTI]

    Igor Iosilevskiy; Victor Gryaznov

    2010-05-23T23:59:59.000Z

    Important advantages of heavy ion beam (HIB) irradiation of matter are discussed in comparison with traditional sources - laser heating, electron beam, electrical discharge etc. High penetration length (~ 10 mm) is of primary importance for investigation of dense matter properties. This gives an extraordinary chance to reach the uniform heating regime when HIB irradiation is being used for thermophysical property measurements. Advantages of HIB heating of highly-dispersive samples are claimed for providing free and relatively slow quasi-isobaric heating without fast hydrodynamic expansion of heated sample. Perspective of such HIB application are revised for resolution of long-time thermophysical problems for uranium and uranium-bearing compounds (UO2). The priorities in such HIB development are stressed: preferable energy levels, beam-time duration, beam focusing, deposition of the sample etc.

  4. Standard guide for the determination of uranium-232 in uranium hexafluoride

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2006-01-01T23:59:59.000Z

    1.1 This method covers the determination of 232U in uranium hexafluoride by alpha spectrometry. 1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use.

  5. Potential incorporation of transuranics into uranium phases

    SciTech Connect (OSTI)

    Kim, C. W.; Wronkiewicz, D. J.; Buck, E. C.

    1999-12-07T23:59:59.000Z

    The UO{sub 2} in spent nuclear fuel is unstable under moist oxidizing conditions and will be altered to uranyl oxide hydrate phases. The transuranics released during the corrosion of spent fuel may also be incorporated into the structures of secondary U{sup 6+} phases. The incorporation of radionuclides into alteration products will affect their mobility. A series of precipitation tests were conducted at either 150 or 90 C for seven days to determine the potential incorporation of Ce{sup 4+} and Nd{sup 3+} (surrogates for Pu{sup 4+} and Am{sup 3+}, respectively) into uranium phases. Ianthinite ([U{sub 2}{sup 4+}(UO{sub 2}){sub 4}O{sub 6}(OH){sub 4}(H{sub 2}O){sub 4}](H{sub 2}O){sub 5}) was produced by dissolving uranium oxyacetate in a solution containing copper acetate monohydrate as a reductant. The leachant used in these tests were doped with either 2.1 ppm cerium or 399 ppm neodymium. Inductively coupled plasma-mass spectrometer (ICP-MS) analysis of the solid phase reaction products which were dissolved in a HNO{sub 3} solution indicates that about 306 ppm Ce (K{sub d} = 146) was incorporated into ianthinite, while neodymium contents were much higher, being approximately 24,800 ppm (K{sub d} = 62). Solid phase examinations using an analytical transmission electron microscope/electron energy-loss spectrometer (AEM/EELS) indicate a uniform distribution of Nd, while Ce contents were below detection. Becquerelite (Ca[(UO{sub 2}){sub 6}O{sub 4}(OH){sub 6}]{center_dot}8H{sub 2}O) was produced by dissolving uranium oxyacetate in a solution containing calcium acetate. The leachant in these tests was doped with either 2.1 ppm cerium or 277 ppm neodymium. ICP-MS results indicate that about 33 ppm Ce (K{sub d}=16) was incorporated into becquerelite, while neodymium contents were higher, being approximately 1,300 ppm (K{sub d}=5). Homogeneous distribution of Nd in the solid phase was noted during AEM/EELS examination, and Ce contents were also below detection.

  6. TRIMOLECULAR REACTIONS OF URANIUM HEXAFLUORIDE WITH WATER

    SciTech Connect (OSTI)

    Westbrook, M.; Becnel, J.; Garrison, S.

    2010-02-25T23:59:59.000Z

    The hydrolysis reaction of uranium hexafluoride (UF{sub 6}) is a key step in the synthesis of uranium dioxide (UO{sub 2}) powder for nuclear fuels. Mechanisms for the hydrolysis reactions are studied here with density functional theory and the Stuttgart small-core scalar relativistic pseudopotential and associated basis set for uranium. The reaction of a single UF{sub 6} molecule with a water molecule in the gas phase has been previously predicted to proceed over a relatively sizeable barrier of 78.2 kJ {center_dot} mol{sup -1}, indicating this reaction is only feasible at elevated temperatures. Given the observed formation of a second morphology for the UO{sub 2} product coupled with the observations of rapid, spontaneous hydrolysis at ambient conditions, an alternate reaction pathway must exist. In the present work, two trimolecular hydrolysis mechanisms are studied with density functional theory: (1) the reaction between two UF{sub 6} molecules and one water molecule, and (2) the reaction of two water molecules with a single UF{sub 6} molecule. The predicted reaction of two UF{sub 6} molecules with one water molecule displays an interesting 'fluorine-shuttle' mechanism, a significant energy barrier of 69.0 kJ {center_dot} mol{sup -1} to the formation of UF{sub 5}OH, and an enthalpy of reaction ({Delta}H{sub 298}) of +17.9 kJ {center_dot} mol{sup -1}. The reaction of a single UF{sub 6} molecule with two water molecules displays a 'proton-shuttle' mechanism, and is more favorable, having a slightly lower computed energy barrier of 58.9 kJ {center_dot} mol{sup -1} and an exothermic enthalpy of reaction ({Delta}H{sub 298}) of -13.9 kJ {center_dot} mol{sup -1}. The exothermic nature of the overall UF{sub 6} + 2 {center_dot} H{sub 2}O trimolecular reaction and the lowering of the barrier height with respect to the bimolecular reaction are encouraging; however, the sizable energy barrier indicates further study of the UF{sub 6} hydrolysis reaction mechanism is warranted to resolve the remaining discrepancies between the predicted mechanisms and experimental observations.

  7. National Uranium Resource Evaluation. Bibliographic index of Grand Junction office uranium reports

    SciTech Connect (OSTI)

    Johnson, J.B.

    1981-05-01T23:59:59.000Z

    In October 1978, Mesa College entered into subcontract with Bendix Field Engineering Corporation (BFEC) to prepare a bibliographic index of the uranium raw materials reports issued by the Grand Junction Office of the US Department of Energy (DOE). Bendix, prime contractor to the Grand Junction Office, operates the Technical Library at the DOE facility. Since the early 1950s, approximately 2700 reports have been issued by the Grand Junction Office. These reports were the results of uranium investigations conducted by federal agencies and their subcontractors. The majority of the reports cover geology, mineralogy, and metallurgy of uranium and/or thorium. No single, complete list of these reports existed. The purpose of this subcontract was to compile a comprehensive index to these reports. The Mesa College geology faculty worked with the BFEC and DOE staffs to develop the format for the index. Undergraduate geology students from Mesa compiled a master record sheet for each report. All reports issued up to January 1, 1979 were included in the bibliography. The bibliography is in preliminary, unedited form. It is being open-filed at this time, on microfiche, to make the information available to the public on a timely basis. The bibliography is divided into a master record list arranged in alpha-numeric order by report identification number, with separate indices arranged by title, author, state and county, 1/sup 0/ x 2/sup 0/ NTMS quadrangle, key words, and exploration area.

  8. Uranium-series constraints on radionuclide transport and groundwater flow at the Nopal I uranium deposit, Sierra Pena Blanca, Mexico

    SciTech Connect (OSTI)

    Goldstein, S.J.; Abdel-Fattah, A.I.; Murrell, M.T.; Dobson, P.F.; Norman, D.E.; Amato, R.S.; Nunn, A. J.

    2009-10-01T23:59:59.000Z

    Uranium-series data for groundwater samples from the Nopal I uranium ore deposit were obtained to place constraints on radionuclide transport and hydrologic processes for a nuclear waste repository located in fractured, unsaturated volcanic tuff. Decreasing uranium concentrations for wells drilled in 2003 are consistent with a simple physical mixing model that indicates that groundwater velocities are low ({approx}10 m/y). Uranium isotopic constraints, well productivities, and radon systematics also suggest limited groundwater mixing and slow flow in the saturated zone. Uranium isotopic systematics for seepage water collected in the mine adit show a spatial dependence which is consistent with longer water-rock interaction times and higher uranium dissolution inputs at the front adit where the deposit is located. Uranium-series disequilibria measurements for mostly unsaturated zone samples indicate that {sup 230}Th/{sup 238}U activity ratios range from 0.005-0.48 and {sup 226}Ra/{sup 238}U activity ratios range from 0.006-113. {sup 239}Pu/{sup 238}U mass ratios for the saturated zone are <2 x 10{sup -14}, and Pu mobility in the saturated zone is >1000 times lower than the U mobility. Saturated zone mobility decreases in the order {sup 238}U{approx}{sup 226}Ra > {sup 230}Th{approx}{sup 239}Pu. Radium and thorium appear to have higher mobility in the unsaturated zone based on U-series data from fractures and seepage water near the deposit.

  9. National Uranium Resource Evaluation. Volume 1. Summary of the geology and uranium potential of Precambrian conglomerates in southeastern Wyoming

    SciTech Connect (OSTI)

    Karlstrom, K.E.; Houston, R.S.; Flurkey, A.J.; Coolidge, C.M.; Kratochvil, A.L.; Sever, C.K.

    1981-02-01T23:59:59.000Z

    A series of uranium-, thorium-, and gold-bearing conglomerates in Late Archean and Early Proterozoic metasedimentary rocks have been discovered in southern Wyoming. The mineral deposits were found by applying the time and strata bound model for the origin of uranium-bearing quartz-pebble conglomerates to favorable rock types within a geologic terrane known from prior regional mapping. No mineral deposits have been discovered that are of current (1981) economic interest, but preliminary resource estimates indicate that over 3418 tons of uranium and over 1996 tons of thorium are present in the Medicine Bow Mountains and that over 440 tons of uranium and 6350 tons of thorium are present in Sierra Madre. Sampling has been inadequate to determine gold resources. High grade uranium deposits have not been detected by work to date but local beds of uranium-bearing conglomerate contain as much as 1380 ppM uranium over a thickness of 0.65 meters. This project has involved geologic mapping at scales from 1/6000 to 1/50,000 detailed sampling, and the evaluation of 48 diamond drill holes, but the area is too large to fully establish the economic potential with the present information. This first volume summarizes the geologic setting and geologic and geochemical characteristics of the uranium-bearing conglomerates. Volume 2 contains supporting geochemical data, lithologic logs from 48 drill holes in Precambrian rocks, and drill site geologic maps and cross-sections from most of the holes. Volume 3 is a geostatistical resource estimate of uranium and thorium in quartz-pebble conglomerates.

  10. Molten uranium dioxide structure and dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Skinner, L. B. [Argonne National Laboratory (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States); Materials Development Inc., Arlington Heights, IL (United States); Parise, J. B. [Stony Brook Univ., Stony Brook, NY (United States); Benmore, C. J. [Argonne National Laboratory (ANL), Argonne, IL (United States); Weber, J. K.R. [Materials Development Inc., Arlington Heights, IL (United States); Williamson, M. A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Tamalonis, A. [Materials Development Inc., Arlington Heights, IL (United States); Hebden, A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Wiencek, T. [Argonne National Laboratory (ANL), Argonne, IL (United States); Alderman, O. L.G. [Materials Development Inc., Arlington Heights, IL (United States); Guthrie, M. [Carnegie Inst., Washington, DC (United States); Leibowitz, L. [Argonne National Laboratory (ANL), Argonne, IL (United States)

    2014-11-20T23:59:59.000Z

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

  11. Uranium Adsorption on Granular Activated Carbon – Batch Testing

    SciTech Connect (OSTI)

    Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

    2013-09-26T23:59:59.000Z

    The uranium adsorption performance of two activated carbon samples (Tusaar Lot B-64, Tusaar ER2-189A) was tested using unadjusted source water from well 299-W19-36. These batch tests support ongoing performance optimization efforts to use the best material for uranium treatment in the Hanford Site 200 West Area groundwater pump-and-treat system. A linear response of uranium loading as a function of the solution-to-solid ratio was observed for both materials. Kd values ranged from ~380,000 to >1,900,000 ml/g for the B-64 material and ~200,000 to >1,900,000 ml/g for the ER2-189A material. Uranium loading values ranged from 10.4 to 41.6 ?g/g for the two Tusaar materials.

  12. Uranium Exerts Acute Toxicity by Binding to Pyrroloquinoline Quinone Cofactor

    SciTech Connect (OSTI)

    Michael R. VanEngelen; Robert I. Szilagyi; Robin Gerlach; Brady E. Lee; William A. Apel; Brent M. Peyton

    2011-02-01T23:59:59.000Z

    Uranium as an environmental contaminant has been shown to be toxic to eukaryotes and prokaryotes; however, no specific mechanisms of uranium toxicity have been proposed so far. Here a combination of in vivo, in vitro, and in silico studies are presented describing direct inhibition of pyrroloquinoline quinone (PQQ)-dependent growth and metabolism by uranyl cations. Electrospray-ionization mass spectroscopy, UV-vis optical spectroscopy, competitive Ca2+/uranyl binding studies, relevant crystal structures, and molecular modeling unequivocally indicate the preferred binding of uranyl simultaneously to the carboxyl oxygen, pyridine nitrogen, and quinone oxygen of the PQQ molecule. The observed toxicity patterns are consistent with the biotic ligand model of acute metal toxicity. In addition to the environmental implications, this work represents the first proposed molecular mechanism of uranium toxicity in bacteria, and has relevance for uranium toxicity in many living systems.

  13. Uranium(VI) Diffusion in Low-Permeability Subsurface Materials...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abstract: Uranium(VI) diffusion was investigated in a fine-grained saprolite sediment that was collected from U.S. Department of Energy (DOE) Oak Ridge site, TN, where...

  14. Speciation of Uranium in Biologically Reduced Sediments in the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Speciation of Uranium in Biologically Reduced Sediments in the Old Rifle Aquifer Wednesday, May 16, 2012 - 1:30pm SSRL Conference Room 137-322 Juan S. Lezama Pacheco The speciation...

  15. Method to remove uranium/vanadium contamination from groundwater

    DOE Patents [OSTI]

    Metzler, Donald R. (DeBeque, CO); Morrison, Stanley (Grand Junction, CO)

    2004-07-27T23:59:59.000Z

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  16. Uranium-contaminated soils: Ultramicrotomy and electron beam analysis

    SciTech Connect (OSTI)

    Buck, E.C.; Dietz, N.L.; Bates, J.K.; Cunnane, J.C.

    1994-02-01T23:59:59.000Z

    Uranium-contaminated soils from the U.S. Department of Energy (DOE) Fernald Site, Ohio, have been examined by a combination of scanning electron microscopy with backscattered electron imaging (SEM/BSE) and analytical electron microscopy (AEM). The inhomogeneous distribution of particulate uranium phases in the soil required the development of a method for using ultramicrotomy to prepare transmission electron microscopy (TEM) thin sections of the SEM mounts. A water-miscible resin was selected that allowed comparison between SEM and TEM images, permitting representative sampling of the soil. Uranium was found in iron oxides, silicates (soddyite), phosphates (autunites), and fluorite (UO{sub 2}). No uranium was detected in association with phyllosilicates in the soil.

  17. Fuel cycle optimization of thorium and uranium fueled PWR systems

    E-Print Network [OSTI]

    Garel, Keith Courtnay

    1977-01-01T23:59:59.000Z

    The burnup neutronics of uniform PWR lattices are examined with respect to reduction of uranium ore requirements with an emphasis on variation of the fuel-to-moderator ratio

  18. Purification de l'hexafluorure d'uranium.

    E-Print Network [OSTI]

    Benzouaa, Rachid

    2014-01-01T23:59:59.000Z

    ??L’hexafluorure d’uranium (UF6), est le seul composé utilisé à l’état gazeux dans les procédés d’enrichissement pour la production du combustible nucléaire. Pour le bon déroulement… (more)

  19. Probing the Electronic Structures of Low Oxidation-State Uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fluoride Molecules UFx- (x2-4). Probing the Electronic Structures of Low Oxidation-State Uranium Fluoride Molecules UFx- (x2-4). Abstract: We report the experimental observation...

  20. Probing the electronic structures of low oxidation-state uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    molecules UFx- (x2-4) . Probing the electronic structures of low oxidation-state uranium fluoride molecules UFx- (x2-4) . Abstract: We report the experimental observation...

  1. Final report on improved uranium utilization in PWRs

    E-Print Network [OSTI]

    Driscoll, Michael J.

    1982-01-01T23:59:59.000Z

    This is the final summary progress report on a research program carried out within the MIT Energy Laboratory/Nuclear Engineering Department under the US Department of Energy's program to increase the effectiveness of uranium ...

  2. Uranium Leasing Program: Program Summary | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    which called for the continued leasing of DOE-managed lands for the exploration and production of uranium and vanadium ores. In 1996, DOE reoffered respective leases to the...

  3. Systems studies on the extraction of uranium from seawater

    E-Print Network [OSTI]

    Driscoll, Michael J.

    1981-01-01T23:59:59.000Z

    This report summarizes the work done at MIT during FY 1981 on the overall system design of a uranium-from-seawater facility. It consists of a sequence of seven major chapters, each of which was originally prepared as a ...

  4. Method to Remove Uranium/Vanadium Contamination from Groundwater

    DOE Patents [OSTI]

    Metzler, Donald R.; Morrison Stanley

    2004-07-27T23:59:59.000Z

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  5. Radiation and Uranium Resources Exposure Control (South Dakota)

    Broader source: Energy.gov [DOE]

    The public policy of South Dakota is to encourage the constructive uses of radiation, the proper development of uranium resources, and the control of any associated harmful effects. The disposal of...

  6. Texas Uranium Exploration, Surface Mining, and Reclamation Act (Texas)

    Broader source: Energy.gov [DOE]

    The Railroad Commission of Texas is the regulatory authority for uranium surface mining. Law authorizes the Commission to assure that reclamation of mining sites is possible, to protect land owners...

  7. Pentavalent Uranium Chemistry - Synthetic Pursuit Of A Rare Oxidation State

    SciTech Connect (OSTI)

    Graves, Christopher R [Los Alamos National Laboratory; Kiplinger, Jaqueline L [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    This feature article presents a comprehensive overview of pentavalent uranium systems in non-aqueous solution with a focus on the various synthetic avenues employed to access this unusual and very important oxidation state. Selected characterization data and theoretical aspects are also included. The purpose is to provide a perspective on this rapidly evolving field and identify new possibilities for future developments in pentavalent uranium chemistry.

  8. Fundamental study on recovery uranium oxide from HEPA filters

    SciTech Connect (OSTI)

    Izumida, T. [Hitachi Ltd., Ibaraki (Japan). Hitachi Works; Matsumoto, H.; Tsuchiya, H.; Iba, H. [Hitachi Nuclear Engineering Co., Ltd., Ibaraki (Japan); Noguchi, Y. [Radioactive Waste Management Center, Tokyo (Japan)

    1993-12-31T23:59:59.000Z

    Large numbers of spent HEPA filters are produced at uranium fuel fabrication facilities. Uranium oxide particles have been collected on these filters. Then, a spent HEPA filter treatment system was developed from the viewpoint of recovering the UO{sub 2} and minimizing the volume. The system consists of a mechanical separation process and a chemical dissolution process. This paper describes the results of fundamental experiments on recovering UO{sub 2} from HEPA filters.

  9. Immobilization of uranium in contaminated soil by natural apatite addition

    SciTech Connect (OSTI)

    Mrdakovic Popic, Jelena; Stojanovic, Mirjana; Milosevic, Sinisa; Iles, Deana; Zildzovic, Snezana [Institute for Technology of Nuclear and other Mineral Raw Materials, Franche d' Epere 86, Belgrade (Serbia)

    2007-07-01T23:59:59.000Z

    Available in abstract form only. Full text of publication follows: The goal of this study was to evaluate the effectiveness of Serbian natural mineral apatite as soil additive for reducing the migration of uranium from contaminated sediments. In laboratory study we investigated the sorption properties of domestic apatite upon different experimental conditions, such as pH, adsorbent mass, reaction period, concentration of P{sub 2}O{sub 5} in apatite, solid/liquid ratio. In second part of study, we did the quantification of uranium in soil samples, taken from uranium mine site 'Kalna', by sequential extraction method. The same procedure was, also, used for uranium determination in contaminated soil samples after apatite addition, in order to determine the changes in U distribution in soil fraction. The obtained results showed the significant level of immobilization (96.7%) upon certain conditions. Increase of %P{sub 2}O{sub 5} in apatite and process of mechano-chemical activation led to increase of immobilization capacity from 17.50% till 91.64%. The best results for uranium binding were obtained at pH 5.5 and reaction period 60 days (98.04%) The sequential extraction showed the presence of uranium (48.2%) in potentially available soil fractions, but with the apatite addition uranium content in these fractions decreased (30.64%), what is considering environmental aspect significant fact. In situ immobilization of radionuclide using inexpensive sequestering agents, such as apatite, is very adequate for big contaminated areas of soil with low level of contamination. This investigation study on natural apatite from deposit 'Lisina' Serbia was the first one of this type in our country. Key words: apatite, uranium, immobilization, soil, contamination. (authors)

  10. Uranium - thorium series study on Yucatan slope cores

    E-Print Network [OSTI]

    Exner, Mary Elizabeth

    1972-01-01T23:59:59.000Z

    URANIUM ? THORIUM SERIES STUDY ON YUCATAN SLOPE CORES A Thesis by Mary Elizabeth Exner Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August, 1972... Major Subject: Oceanography URANIUM ? THORIUM SERIES STUDY ON YUCATAN SLOPE CORES A Thesis by Mary Elizabeth Exner Approved as to style and content by: (Chairman of ommittee) , 1 (Head of Department)' p (Member ) (Member) August, 1972 gg...

  11. Geological and geochemical aspects of uranium deposits. A selected, annotated bibliography

    SciTech Connect (OSTI)

    Garland, P.A.; Thomas, J.M.; Brock, M.L.; Daniel, E.W. (comps.)

    1980-06-01T23:59:59.000Z

    A bibliography of 479 references encompassing the fields of uranium and thorium geochemistry and mineralogy, geology of uranium deposits, uranium mining, and uranium exploration techniques has been compiled by the Ecological Sciences Information Center of Oak Ridge National Laboratory. The bibliography was produced for the National Uranium Resource Evaluation Program, which is funded by the Grand Junction Office of the Department of Energy. The references contained in the bibliography have been divided into the following eight subject categories: (1) geology of deposits, (2) geochemistry, (3) genesis O deposits, (4) exploration, (5) mineralogy, (6) uranium industry, (7) reserves and resources, and (8) geology of potential uranium-bearing areas. All categories specifically refer to uranium and thorium; the last category contains basic geologic information concerning areas which the Grand Junction Office feels are particularly favorable for uranium deposition. The references are indexed by author, geographic location, quadrangle name, geoformational feature, taxonomic name, and keyword.

  12. The IMCA: A field instrument for uranium enrichment measurements

    SciTech Connect (OSTI)

    Gardner, G.H.; Koskelo, M.; Moeslinger, M. [Canberra Industries, Meriden, CT (United States); Mayer, R.L. II; McGinnis, B.R. [Lockheed Martin Utility Services, Piketon, OH (United States). Portsmouth Gaseous Diffusion Plant; Wishard, B. [International Atomic Energy Agency, Vienna (Austria)

    1996-12-31T23:59:59.000Z

    The IMCA (Inspection Multi-Channel Analyzer) is a portable gamma-ray spectrometer designed to measure the enrichment of uranium either in a laboratory or in the field. The IMCA consists of a Canberra InSpector Multi-Channel Analyzer, sodium iodide or a planar germanium detector, and special application software. The system possesses a high degree of automation. The IMCA uses the uranium enrichment meter principle, and is designed to meet the International Atomic Energy Agency (IAEA) requirements for the verification of enriched uranium materials. The IMCA is available with MGA plutonium isotopic analysis software or MGAU uranium analysis software as well. In this paper, the authors present a detailed description of the hardware and software of the IMCA system, as well as results from preliminary measurements testing compliance of IMCA with IAEA requirements using uranium standards and UF6 cylinders. Measurements performed on UF6 cylinders in the field under variable environmental conditions (temperatures ranging from 0 to 35 C) have shown that good results can be achieved. The enrichment of UF6 contained in the cylinder is determined by using calibration constants generated from an instrument calibration, using traceable uranium oxide standards, performed in the laboratory under controlled environmental conditions. The IMCA software is designed to make the necessary matrix and container corrections to ensure that accurate results are achieved in the field.

  13. Standard specification for sintered gadolinium oxide-uranium dioxide pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01T23:59:59.000Z

    1.1 This specification is for finished sintered gadolinium oxide-uranium dioxide pellets for use in light-water reactors. It applies to gadolinium oxide-uranium dioxide pellets containing uranium of any 235U concentration and any concentration of gadolinium oxide. 1.2 This specification recognizes the presence of reprocessed uranium in the fuel cycle and consequently defines isotopic limits for gadolinium oxide-uranium dioxide pellets made from commercial grade UO2. Such commercial grade UO2 is defined so that, regarding fuel design and manufacture, the product is essentially equivalent to that made from unirradiated uranium. UO2 falling outside these limits cannot necessarily be regarded as equivalent and may thus need special provisions at the fuel fabrication plant or in the fuel design. 1.3 This specification does not include (1) provisions for preventing criticality accidents or (2) requirements for health and safety. Observance of this specification does not relieve the user of the obligation to be aw...

  14. Examination of the conversion of the U.S. submarine fleet from highly enriched uranium to low enriched uranium

    E-Print Network [OSTI]

    McCord, Cameron (Cameron Liam)

    2014-01-01T23:59:59.000Z

    The nuclear reactors used by the U.S. Navy for submarine propulsion are currently fueled by highly enriched uranium (HEU), but HEU brings administrative and political challenges. This issue has been studied by the Navy ...

  15. EIS-0126: Remedial Actions at the Former Climax Uranium Company Uranium Mill Site, Grand Junction, Mesa County, Colorado

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this EIS to assess the environmental impacts of remediating the residual radioactive materials left from the inactive uranium processing site and associated properties located in Grand Junction, Colorado.

  16. Standard test method for the determination of uranium by ignition and the oxygen to uranium (O/U) atomic ratio of nuclear grade uranium dioxide powders and pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2000-01-01T23:59:59.000Z

    1.1 This test method covers the determination of uranium and the oxygen to uranium atomic ratio in nuclear grade uranium dioxide powder and pellets. 1.2 This test method does not include provisions for preventing criticality accidents or requirements for health and safety. Observance of this test method does not relieve the user of the obligation to be aware of and conform to all international, national, or federal, state and local regulations pertaining to possessing, shipping, processing, or using source or special nuclear material. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. 1.4 This test method also is applicable to UO3 and U3O8 powder.

  17. An analysis of uranium dispersal and health effects using a Gulf War case study.

    SciTech Connect (OSTI)

    Marshall, Albert Christian

    2005-07-01T23:59:59.000Z

    The study described in this report used mathematical modeling to estimate health risks from exposure to depleted uranium (DU) during the 1991 Gulf War for both U.S. troops and nearby Iraqi civilians. The analysis found that the risks of DU-induced leukemia or birth defects are far too small to result in an observable increase in these health effects among exposed veterans or Iraqi civilians. Only a few veterans in vehicles accidentally struck by U.S. DU munitions are predicted to have inhaled sufficient quantities of DU particulate to incur any significant health risk (i.e., the possibility of temporary kidney damage from the chemical toxicity of uranium and about a 1% chance of fatal lung cancer). The health risk to all downwind civilians is predicted to be extremely small. Recommendations for monitoring are made for certain exposed groups. Although the study found fairly large calculational uncertainties, the models developed and used are generally valid. The analysis was also used to assess potential uranium health hazards for workers in the weapons complex. No illnesses are projected for uranium workers following standard guidelines; nonetheless, some research suggests that more conservative guidelines should be considered.

  18. Evaluation of Uranium Measurements in Water by Various Methods - 13571

    SciTech Connect (OSTI)

    Tucker, Brian J. [Shaw Environmental and Infrastructure Group, 150 Royall Street, Canton, MA (United States)] [Shaw Environmental and Infrastructure Group, 150 Royall Street, Canton, MA (United States); Workman, Stephen M. [ALS Laboratory Group, Environmental Division, 225 Commerce Drive, Fort Collins, CO 80524 (United States)] [ALS Laboratory Group, Environmental Division, 225 Commerce Drive, Fort Collins, CO 80524 (United States)

    2013-07-01T23:59:59.000Z

    In December 2000, EPA amended its drinking water regulations for radionuclides by adding a Maximum Contaminant Level (MCL) for uranium (so called MCL Rule)[1] of 30 micrograms per liter (?g/L). The MCL Rule also included MCL goals of zero for uranium and other radionuclides. Many radioactively contaminated sites must test uranium in wastewater and groundwater to comply with the MCL rule as well as local publicly owned treatment works discharge limitations. This paper addresses the relative sensitivity, accuracy, precision, cost and comparability of two EPA-approved methods for detection of total uranium: inductively plasma/mass spectrometry (ICP-MS) and alpha spectrometry. Both methods are capable of measuring the individual uranium isotopes U-234, U- 235, and U-238 and both methods have been deemed acceptable by EPA. However, the U-238 is by far the primary contributor to the mass-based ICP-MS measurement, especially for naturally-occurring uranium, which contains 99.2745% U-238. An evaluation shall be performed relative to the regulatory requirement promulgated by EPA in December 2000. Data will be garnered from various client sample results measured by ALS Laboratory in Fort Collins, CO. Data shall include method detection limits (MDL), minimum detectable activities (MDA), means and trends in laboratory control sample results, performance evaluation data for all methods, and replicate results. In addition, a comparison will be made of sample analyses results obtained from both alpha spectrometry and the screening method Kinetic Phosphorescence Analysis (KPA) performed at the U.S. Army Corps of Engineers (USACE) FUSRAP Maywood Laboratory (UFML). Many uranium measurements occur in laboratories that only perform radiological analysis. This work is important because it shows that uranium can be measured in radiological as well as stable chemistry laboratories and it provides several criteria as a basis for comparison of two uranium test methods. This data will indicate which test method is the most accurate and most cost effective. This paper provides a benefit to Formerly Utilized Sites Remedial Action Program (FUSRAP) and other Department of Defense (DOD) programs that may be performing uranium measurements. (authors)

  19. Uranium 238U/235U isotope ratios as indicators of reduction: Results from an in situ biostimulation experiment at Rifle, Colorado, USA

    E-Print Network [OSTI]

    Bopp IV, C.J.

    2010-01-01T23:59:59.000Z

    sandstone-type uranium deposits. Economic Geology; 1962; (5)uranium ore deposits: Isotopic signatures of the U reduction process? ; Geology,

  20. An Optically Stimulated Luminescence Uranium Enrichment Monitor

    SciTech Connect (OSTI)

    Miller, Steven D.; Tanner, Jennifer E.; Simmons, Kevin L.; Conrady, Matthew M.; Benz, Jacob M.; Greenfield, Bryce A.

    2010-08-11T23:59:59.000Z

    The Pacific Northwest National Laboratory (PNNL) has pioneered the use of Optically Stimulated Luminescence (OSL) technology for use in personnel dosimetry and high dose radiation processing dosimetry. PNNL has developed and patented an alumina-based OSL dosimeter that is being used by the majority of medical X-ray and imaging technicians worldwide. PNNL has conceived of using OSL technology to passively measure the level of UF6 enrichment by attaching the prototype OSL monitor to pipes containing UF6 gas within an enrichment facility. The prototype OSL UF6 monitor utilizes a two-element approach with the first element open and unfiltered to measure both the low energy and high energy gammas from the UF6, while the second element utilizes a 3-mm thick tungsten filter to eliminate the low energy gammas and pass only the high energy gammas from the UF6. By placing a control monitor in the room away from the UF6 pipes and other ionizing radiation sources, the control readings can be subtracted from the UF6 pipe monitor measurements. The ratio of the shielded to the unshielded net measurements provides a means to estimate the level of uranium enrichment. PNNL has replaced the commercially available MicroStar alumina-based dosimeter elements with a composite of polyethylene plastic, high-Z glass powder, and BaFBr:Eu OSL phosphor powder at various concentrations. The high-Z glass was added in an attempt to raise the average “Z” of the composite dosimeter and increase the response. Additionally, since BaFBr:Eu OSL phosphor is optimally excited and emits light at different wavelengths compared to alumina, the commercially available MicroStar reader was modified for reading BaFBr:Eu in a parallel effort to increase reader sensitivity. PNNL will present the design and performance of our novel OSL uranium enrichment monitor based on a combination of laboratory and UF6 test loop measurements. PNNL will also report on the optimization effort to achieve the highest possible performance from both the OSL enrichment monitor and the new custom OSL reader modified for this application. This project has been supported by the US Department of Energy’s National Nuclear Security Administration’s Office of Dismantlement and Transparency (DOE/NNSA/NA-241).

  1. Uranium- and thorium-bearing pegmatites of the United States

    SciTech Connect (OSTI)

    Adams, J.W.; Arengi, J.T.; Parrish, I.S.

    1980-04-01T23:59:59.000Z

    This report is part of the National Uranium Resource Evaluation (NURE) Program designed to identify criteria favorable for the occurrence of the world's significant uranium deposits. This project deals specifically with uranium- and thorium-bearing pegmatites in the United States and, in particular, their distribution and origin. From an extensive literature survey and field examination of 44 pegmatite localities in the United States and Canada, the authors have compiled an index to about 300 uranium- and thorium-bearing pegmatites in the United States, maps giving location of these deposits, and an annotated bibliography to some of the most pertinent literature on the geology of pegmatites. Pegmatites form from late-state magma differentiates rich in volatile constituents with an attendant aqueous vapor phase. It is the presence of an aqueous phase which results in the development of the variable grain size which characterizes pegmatites. All pegmatites occur in areas of tectonic mobility involving crustal material usually along plate margins. Those pegmatites containing radioactive mineral species show, essentially, a similar distribution to those without radioactive minerals. Criteria such as tectonic setting, magma composition, host rock, and elemental indicators among others, all serve to help delineate areas more favorable for uranium- and thorium-bearing pegmatites. The most useful guide remains the radioactivity exhibited by uranium- and thorium-bearing pegmatites. Although pegmatites are frequently noted as favorable hosts for radioactive minerals, the general paucity and sporadic distribution of these minerals and inherent mining and milling difficulties negate the resource potential of pegmatites for uranium and thorium.

  2. Influence of Acidic and Alkaline Waste Solution Properties on Uranium Migration in Subsurface Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; Truex, Michael J.; Qafoku, Nikolla; Wellman, Dawn M.; Resch, Charles T.; Zhong, Lirong

    2013-08-01T23:59:59.000Z

    This study shows that acidic and alkaline wastes co-disposed with uranium into subsurface sediments has significant impact on changes in uranium retardation, concentration, and mass during downward migration. For uranium co-disposal with acidic wastes, significant rapid (i.e., hours) carbonate and slow (i.e., 100s of hours) clay dissolution resulted, releasing significant sediment-associated uranium, but the extent of uranium release and mobility change was controlled by the acid mass added relative to the sediment proton adsorption capacity. Mineral dissolution in acidic solutions (pH 2) resulted in a rapid (< 10 h) increase in aqueous carbonate (with Ca2+, Mg2+) and phosphate and a slow (100s of hours) increase in silica, Al3+, and K+, likely from 2:1 clay dissolution. Infiltration of uranium with a strong acid resulted in significant shallow uranium mineral dissolution and deeper uranium precipitation (likely as phosphates and carbonates) with downward uranium migration of three times greater mass at a faster velocity relative to uranium infiltration in pH neutral groundwater. In contrast, mineral dissolution in an alkaline environment (pH 13) resulted in a rapid (< 10 h) increase in carbonate, followed by a slow (10s to 100s of hours) increase in silica concentration, likely from montmorillonite, muscovite, and kaolinite dissolution. Infiltration of uranium with a strong base resulted in uranium-silicate precipitation (presumed Na-boltwoodite) but also desorption of natural uranium on the sediment due to the high ionic strength solution, or 60% greater mass with greater retardation compared with groundwater. Overall, these results show that acidic or alkaline co-contaminant disposal with uranium can result in complex depth- and time-dependent changes in uranium dissolution/precipitation reactions and uranium sorption, which alter the uranium migration mass, concentration, and velocity.

  3. Development and demonstration of biosorbents for clean-up of uranium in water. CRADA final report

    SciTech Connect (OSTI)

    Faison, B.D.; Hu, M.Z.C.; Norman, J.M.; Reeves, M.E.; Williams, L.; Schmidt-Kuster, W.; Darnell, K. [Oak Ridge National Lab., TN (United States)]|[Ogden Environmental Service, Oak Ridge, TN (United States)

    1997-08-01T23:59:59.000Z

    Pseudomonas aeruginosa strain CSU, a nongenetically engineered bacterial strain known to bind dissolved hexavalent uranium, shows particular promise as the basis of an immobilized-cell process for removal of dissolved uranium from contaminated wastewaters. It was characterized with respect to its sorptive active. Living, heat-killed, permeabilized, and unreconstituted lyophilized cells were all capable of binding uranium. The uranium biosorption equilibrium could be described by the Langmuir isotherm. The rate of uranium adsorption increased following permeabilization of the outer and/or cytoplasmic membrane by organic solvents such as acetone. P. aeruginosa CSU biomass was significantly more sorptive toward uranium than certain novel, patented biosorbents derived from algal or fungal biomass sources. P. aeruginosa CSU biomass was also competitive with commercial cation-exchange resins, particularly in the presence of dissolved transition metals. Uranium binding by P. aeruginosa was clearly pH dependent. Uranium loading capacity increased with increasing pH under acidic conditions, presumably as a function of uranium speciation and due to the H{sup +} competition at some binding sites. Nevertheless, preliminary evidence suggests that this microorganism is also capable of binding anionic hexavalent uranium complexes. Ferric iron was a strong inhibitor of uranium binding to P. aeruginosa CSU biomass, and the presence of uranium also decreased the Fe{sup 3+} loading when the biomass was not saturated with Fe{sup 3+}, suggesting that Fe{sup 3+} and uranium may share the same binding sites on biomass.

  4. Detection of uranium-based nuclear weapons using neutron-induced fission

    SciTech Connect (OSTI)

    Moss, C.E.; Byrd, R.C.; Feldman, W.C.; Auchampaugh, G.F.; Estes, G.P. [Los Alamos National Lab., NM (United States); Ewing, R.I.; Marlow, K.W. [Sandia National Labs., Albuquerque, NM (United States)

    1991-12-01T23:59:59.000Z

    Although plutonium-based nuclear weapons can usually be detected by their spontaneous emission of neutrons and gammas, the radiation emitted by weapons based entirely on highly-enriched uranium can often be easily shielded. Verification of a treaty that limits the number of such weapons may require an active technique, such as interrogating the suspect assembly with an external neutron source and measuring the number of fission neutrons produced. Difficulties include distinguishing between source and fission neutrons, the variations in yield for different materials and geometries, and the possibility of non-nuclear weapons that may contain significant amounts of fissionable depleted uranium. We describe simple measurements that test the induced-fission technique using an isotopic Am-Li source, an novel energy-sensitive neutron detector, and several small assemblies containing {sup 235}U, {sup 238}U, lead, and polyethylene. In all cases studied, the neutron yields above the source energy are larger for the {sup 235}U assemblies than for assemblies containing only lead or depleted uranium. For more complex geometries, corrections for source transmission may be necessary. The results are promising enough to recommend further experiments and calculations using examples of realistic nuclear and non-nuclear weapons. 5 refs., 11 figs.

  5. Detection of uranium-based nuclear weapons using neutron-induced fission

    SciTech Connect (OSTI)

    Moss, C.E.; Byrd, R.C.; Feldman, W.C.; Auchampaugh, G.F.; Estes, G.P. (Los Alamos National Lab., NM (United States)); Ewing, R.I.; Marlow, K.W. (Sandia National Labs., Albuquerque, NM (United States))

    1991-01-01T23:59:59.000Z

    Although plutonium-based nuclear weapons can usually be detected by their spontaneous emission of neutrons and gammas, the radiation emitted by weapons based entirely on highly-enriched uranium can often be easily shielded. Verification of a treaty that limits the number of such weapons may require an active technique, such as interrogating the suspect assembly with an external neutron source and measuring the number of fission neutrons produced. Difficulties include distinguishing between source and fission neutrons, the variations in yield for different materials and geometries, and the possibility of non-nuclear weapons that may contain significant amounts of fissionable depleted uranium. We describe simple measurements that test the induced-fission technique using an isotopic Am-Li source, an novel energy-sensitive neutron detector, and several small assemblies containing {sup 235}U, {sup 238}U, lead, and polyethylene. In all cases studied, the neutron yields above the source energy are larger for the {sup 235}U assemblies than for assemblies containing only lead or depleted uranium. For more complex geometries, corrections for source transmission may be necessary. The results are promising enough to recommend further experiments and calculations using examples of realistic nuclear and non-nuclear weapons. 5 refs., 11 figs.

  6. Thermal hydraulics analysis of the MIT research reactor in support of a low enrichment uranium (LEU) core conversion .

    E-Print Network [OSTI]

    Ko, Yu-Chih, Ph. D. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    ??The MIT research reactor (MITR) is converting from the existing high enrichment uranium (HEU) core to a low enrichment uranium (LEU) core using a high-density… (more)

  7. Fire testing of bare uranium hexafluoride cylinders

    SciTech Connect (OSTI)

    Pryor, W.A. [PAI Corp., Oak Rige, TN (United States)

    1991-12-31T23:59:59.000Z

    In 1965, the Oak Ridge Gaseous Diffusion Plant (ORGDP), now the K-25 Site, conducted a series of tests in which bare cylinders of uranium hexafluoride (UF{sub 6}) were exposed to engulfing oil fires for the US Atomic Energy Commission (AEC), now the US Department of Energy (DOE). The tests are described and the results, conclusions, and observations are presented. Two each of the following types of cylinders were tested: 3.5-in.-diam {times} 7.5-in.-long cylinders of Monel (Harshaw), 5.0-in.-diam {times} 30-in.-long cylinders of Monel, and 8-in.-diam {times} 48-in.-long cylinders of nickel. The cylinders were filled approximately to the standard UF{sub 6} fill limits of 5, 55, and 250 lb, respectively, with a U-235 content of 0.22%. The 5-in.- and 8-in.-diam cylinders were tested individually with and without their metal valve covers. For the 3.5-in.-diam Harshaw cylinders and the 5.0-in.-diam cylinder without a valve cover the valves failed and UF{sub 6} was released. The remaining cylinders ruptured explosively in time intervals ranging from about 8.5 to 11 min.

  8. Fire testing of bare uranium hexafluoride cylinders

    SciTech Connect (OSTI)

    Pryor, W.A. [PAI Corp., Oak Ridge, TN (United States)

    1991-12-31T23:59:59.000Z

    In 1965, the Oak Ridge Gaseous Diffusion Plant (ORGDP), now the K-25 Site, conducted a series of tests in which bare cylinders of uranium hexafluoride (UF{sub 6}) were exposed to engulfing oil fires for the US Atomic Energy Commission (AEC), now the US Department of Energy (DOE). The tests are described and the results, conclusions, and observations are presented. Two each of the following types of cylinders were tested: 3.5-in.-diam {times} 7.5-in.-long cylinders of Monel (Harshaw), 5.0-in.-diam {times} x 30-in.-long cylinders of Monel, and 8-in.-diam {times} 48-in.-long cylinders of nickel. The cylinders were filled approximately to the standard UF{sub 6} fill limits of 5, 55, and 250 lb, respectively, with a U-235 content of 0.22%. The 5-in.- and 8-in.-diam cylinders were tested individually with and without their metal valve covers. For the 3.5-in.-diam Harshaw cylinders and the 5.0-in.-diam cylinder without a valve cover, the valves failed and UF{sub 6} was released. The remaining 6 cylinders ruptured explosively in time intervals ranging from about 8.5 to 11 min.

  9. Density Prediction of Uranium-6 Niobium Ingots

    SciTech Connect (OSTI)

    D.F.Teter; P.K. Tubesing; D.J.Thoma; E.J.Peterson

    2003-04-15T23:59:59.000Z

    The densities of uranium-6 niobium (U-Nb) alloys have been compiled from a variety of literature sources such as Y-12 and Rocky Flats datasheets. We also took advantage of the 42 well-pedigreed, homogeneous baseline U-Nb alloys produced under the Enhanced Surveillance Program for density measurements. Even though U-Nb alloys undergo two-phase transitions as the Nb content varies from 0 wt. % to 8 wt %, the theoretical and measured densities vary linearly with Nb content. Therefore, the effect of Nb content on the density was modeled with a linear regression. From this linear regression, a homogeneous ingot of U-6 wt.% Nb would have a density of 17.382 {+-} 0.040 g/cc (95% CI). However, ingots produced at Y-12 are not homogeneous with respect to the Nb content. Therefore, using the 95% confidence intervals, the density of a Y-12 produced ingot would vary from 17.310 {+-} 0.043 g/cc at the center to 17.432 {+-} 0.039 g/cc at the edge. Ingots with larger Nb inhomogeneities will also have larger variances in the density.

  10. Liquid uranium alloy-helium fission reactor

    DOE Patents [OSTI]

    Minkov, V.

    1984-06-13T23:59:59.000Z

    This invention describes a nuclear fission reactor which has a core vessel and at least one tandem heat exchanger vessel coupled therewith across upper and lower passages to define a closed flow loop. Nuclear fuel such as a uranium alloy in its liquid phase fills these vessels and flow passages. Solid control elements in the reactor core vessel are adapted to be adjusted relative to one another to control fission reaction of the liquid fuel therein. Moderator elements in the other vessel and flow passages preclude fission reaction therein. An inert gas such as helium is bubbled upwardly through the heat exchanger vessel operable to move the liquid fuel upwardly therein and unidirectionally around the closed loop and downwardly through the core vessel. This helium gas is further directed to heat conversion means outside of the reactor vessels to utilize the heat from the fission reaction to generate useful output. The nuclear fuel operates in the 1200 to 1800/sup 0/C range, and even higher to 2500/sup 0/C.

  11. Liquid uranium alloy-helium fission reactor

    DOE Patents [OSTI]

    Minkov, Vladimir (Skokie, IL)

    1986-01-01T23:59:59.000Z

    This invention teaches a nuclear fission reactor having a core vessel and at least one tandem heat exchanger vessel coupled therewith across upper and lower passages to define a closed flow loop. Nuclear fuel such as a uranium alloy in its liquid phase fills these vessels and flow passages. Solid control elements in the reactor core vessel are adapted to be adjusted relative to one another to control fission reaction of the liquid fuel therein. Moderator elements in the other vessel and flow passages preclude fission reaction therein. An inert gas such as helium is bubbled upwardly through the heat exchanger vessel operable to move the liquid fuel upwardly therein and unidirectionally around the closed loop and downwardly through the core vessel. This helium gas is further directed to heat conversion means outside of the reactor vessels to utilize the heat from the fission reaction to generate useful output. The nuclear fuel operates in the 1200.degree.-1800.degree. C. range, and even higher to 2500.degree. C., limited only by the thermal effectiveness of the structural materials, increasing the efficiency of power generation from the normal 30-35% with 300.degree.-500.degree. C. upper limit temperature to 50-65%. Irradiation of the circulating liquid fuel, as contrasted to only localized irradiation of a solid fuel, provides improved fuel utilization.

  12. Measurements of uranium mill tailings consolidation characteristics

    SciTech Connect (OSTI)

    Fayer, M J

    1985-02-01T23:59:59.000Z

    A series of experiments were conducted on uranium mill tailings from the tailings pile in Grand Junction, Colorado, to determine their consolidation characteristics. Three materials (sand, sand/slimes mix, slimes) were loaded under saturated conditions to determine their saturated consolidated behavior. During a separate experiment, samples of the slimes material were kept under a constant load while the pore pressure was increased to determine the partially saturated consolidation behavior. Results of the saturated tests compared well with published data. Sand consolidated the least, while slimes consolidated the most. As each material consolidated, the measured hydraulic conductivity decreased in a linear fashion with respect to the void ratio. Partially saturated experiments with the slimes indicated that there was little consolidation as the pore pressure was increased progressively above 7 kPa. The small amount of consolidation that did occur was only a fraction of the amount of saturated consolidation. Preliminary measurements between pore pressures of 0 and 7 kPa indicated that measurable consolidation could occur in this range of pore pressure, but only if there was no load. 13 references, 13 figures.

  13. atp depletion precedes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    evolves, because new precedents are generated by the form... Smolin, Lee 2012-01-01 15 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  14. analogues deplete androgen: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with androgens has been shown to increase growth rate in fishes (Ron et al., 1995 13 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  15. antioxidant defence depletion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and defence reactions. Priya Roy; Ramamurthy Dhandapani Department Of Microbiology 15 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  16. administration depletes mitochondrial: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    recombination is widespread in plant mtDNA. Recombinant molecules have Nicolas Galtier 6 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  17. approaching waterflood depletion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are shown in Table 5 of the Appendix. Figure... Pettitt, Bobby Eugene 1963-01-01 19 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  18. DOE Selects Contractor for Depleted Hexafluoride Conversion Project...

    Broader source: Energy.gov (indexed) [DOE]

    to the DOE Portsmouth Paducah Project Office (PPPO) in Lexington, Kentucky and the Depleted Uranium Hexafluoride (DUF6) Conversion Project in Paducah, Kentucky and...

  19. aerosol depletion test: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    damage and realize optimum well productivity. To address... Chen, Guoqiang 2002-01-01 10 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  20. Baseline risk assessment of ground water contamination at the Uranium Mill Tailings Site in Lakeview, Oregon

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    This Baseline Risk Assessment of Ground Water Contamination at the Uranium Mill Tailings Site in Lake view, Oregon evaluates potential impacts to public health or the environment resulting from ground water contamination at the former uranium mill processing site.

  1. Bacterial influence on uranium oxidation reduction reactions : implications for environmental remediation and isotopic composition

    E-Print Network [OSTI]

    Mullen, Lisa Maureen

    2007-01-01T23:59:59.000Z

    The bacterial influence on the chemistry and speciation of uranium has some important impacts on the environment, and can be exploited usefully for the purposes of environmental remediation of uranium waste contamination. ...

  2. Moab Uranium Mill Tailings Cleanup Project Steps into Spotlight at International Meeting in Vienna

    Broader source: Energy.gov [DOE]

    VIENNA – The Moab Uranium Mill Tailings Remedial Action (UMTRA) Project has kept the United States at the forefront of characterization, remediation, and end-state reuse of uranium millsites around the world.

  3. EIS-0472: Uranium Leasing Program, Mesa, Montrose, and San Miguel Counties, Colorado

    Broader source: Energy.gov [DOE]

    This EIS evaluated the potential environmental impacts of management alternatives for DOE’s Uranium Leasing Program, under which DOE administers tracts of land in western Colorado for exploration, development, and the extraction of uranium and vanadium ores.

  4. Management Controls over the Department of Energy's Uranium Leasing Program, OAS-M-08-05

    Broader source: Energy.gov [DOE]

    The Department of Energy's Uranium Leasing Program was established by the Atomic Energy Act of 1954 to develop a supply of domestic uranium to meet the nation's defense needs. Pursuant to the Act,...

  5. Synthesis of Uranium Trichloride for the Pyrometallurgical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; J.C. Price; R.D. Mariani

    2011-11-01T23:59:59.000Z

    The pyroprocessing of used nuclear fuel via electrorefining requires the continued addition of uranium trichloride to sustain operations. Uranium trichloride is utilized as an oxidant in the system to allow separation of uranium metal from the minor actinides and fission products. The inventory of uranium trichloride had diminished to a point that production was necessary to continue electrorefiner operations. Following initial experimentation, cupric chloride was chosen as a reactant with uranium metal to synthesize uranium trichloride. Despite the variability in equipment and charge characteristics, uranium trichloride was produced in sufficient quantities to maintain operations in the electrorefiner. The results and conclusions from several experiments are presented along with a set of optimized operating conditions for the synthesis of uranium trichloride.

  6. Development of a low enrichment uranium core for the MIT reactor

    E-Print Network [OSTI]

    Newton, Thomas Henderson

    2006-01-01T23:59:59.000Z

    An investigation has been made into converting the MIT research reactor from using high enrichment uranium (HEU) to low enrichment uranium (LEU) with a newly developed fuel material. The LEU fuel introduces negative ...

  7. Use of uranium^thorium dating to determine C reservoir eects in lakes: examples from Antarctica

    E-Print Network [OSTI]

    Henderson, Gideon

    Use of uranium^thorium dating to determine past 14 C reservoir e¡ects in lakes: examples from of dissolved `dead' carbon or to slow air^water exchange. Here we use the TIMS uranium^thorium disequilibrium

  8. Safeguards assessment of gamma-ray detection for process monitoring at natural uranium conversion facilities.

    E-Print Network [OSTI]

    Dewji, Shaheen Azim

    2014-01-01T23:59:59.000Z

    ??Conversion, the process by which natural uranium ore (yellowcake) is puri?ed and converted through a series of chemical processes into uranium hexa?uoride gas (UF6), has… (more)

  9. E-Print Network 3.0 - area uranium stabilization Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Search Powered by Explorit Topic List Advanced Search Sample search results for: area uranium stabilization Page: << < 1 2 3 4 5 > >> 1 geology and Ranger 1 open-pit uranium...

  10. E-Print Network 3.0 - australian uranium projects Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: australian uranium projects Page: << < 1 2 3 4 5 > >> 1 geology and Ranger 1 open-pit uranium mine in...

  11. E-Print Network 3.0 - antei uranium deposit Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Search Powered by Explorit Topic List Advanced Search Sample search results for: antei uranium deposit Page: << < 1 2 3 4 5 > >> 1 geology and Ranger 1 open-pit uranium mine in...

  12. Mathematical Geology, Vol. 33, No. 1, 2001 Modeling Uranium Transport in Koongarra,

    E-Print Network [OSTI]

    Hassanizadeh, S. Majid

    Mathematical Geology, Vol. 33, No. 1, 2001 Modeling Uranium Transport in Koongarra, Australia waste disposal safety assessment studies. The Koongarra uranium deposit in the Alligator Rivers region weathering over several million years, during which many climatological, hydrological, and geological changes

  13. E-Print Network 3.0 - australian uranium mining Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: australian uranium mining Page: << < 1 2 3 4 5 > >> 1 geology and Ranger 1 open-pit uranium mine in...

  14. E-Print Network 3.0 - albarrana uranium ores Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Powered by Explorit Topic List Advanced Search Sample search results for: albarrana uranium ores Page: << < 1 2 3 4 5 > >> 1 geology and Ranger 1 open-pit uranium mine in...

  15. Uranium Mill Tailings Remedial Action (UMTRA) Project. [UMTRA project

    SciTech Connect (OSTI)

    Not Available

    1989-09-01T23:59:59.000Z

    The mission of the Uranium Mill Tailings Remedial Action (UMTRA) Project is explicitly stated and directed in the Uranium Mill Tailings Radiation Control Act of 1978, hereinafter referred to as the Act.'' Title I of the Act authorizes the Department of Energy (DOE) to undertake remedial action at designated inactive uranium processing sites (Attachment 1 and 2) and associated vicinity properties containing uranium mill tailings and other residual radioactive materials derived from the processing site. The purpose of the remedial actions is to stabilize and control such uranium mill tailings and other residual radioactive materials in a safe and environmentally sound manner to minimize radiation health hazards to the public. The principal health hazards and environmental concerns are: the inhalation of air particulates contaminated as a result of the emanation of radon from the tailings piles and the subsequent decay of radon daughters; and the contamination of surface and groundwaters with radionuclides or other chemically toxic materials. This UMTRA Project Plan identifies the mission and objectives of the project, outlines the technical and managerial approach for achieving them, and summarizes the performance, cost, and schedule baselines which have been established to guide operational activity. Estimated cost increases by 15 percent, or if the schedule slips by six months. 4 refs.

  16. Reclamation and groundwater restoration in the uranium milling industry: An assessment of UMTRCA, title II

    SciTech Connect (OSTI)

    Collins, J.D.

    1996-12-31T23:59:59.000Z

    In 1978, Congress passed the Uranium Mill Tailings Radiation Control Act (UMTRCA) to regulate the disposal and reclamation of uranium mill tailings.This article examines the implementation of this legislation through eight cases of uranium mills in New Mexico, Wyoming, and Utah now being reclaimed. The eight cases examined here make up an important part of the total reclamation picture in the uranium milling industry.

  17. Earthquake hazards in the Intermountain U.S.: Issues relevant to uranium mill tailings disposal

    E-Print Network [OSTI]

    Ivan G. Wong; Susan S. Olig; Bruce W. Hassinger; Richard E. Blubaugh

    . Consequently, the seismic safety of U.S. uranium mill tailings sites, which are located almost exclusively in

  18. Uraniumhydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III)w

    E-Print Network [OSTI]

    Girolami, Gregory S.

    Uranium­hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium919490h The reaction of UCl4 with Na(H3BNMe2BH3) in diethyl ether affords the uranium(III) product U(H3 in the two forms. Uranium hydride, UH3, has been proposed to be an ideal material for the generation of safe

  19. Detection of hexavalent uranium with inline and field-portable immunosensors

    E-Print Network [OSTI]

    Melton, Scott J.

    2009-01-01T23:59:59.000Z

    Uranium Mill Tailings Remedial Action (UMTRA) site located in Rifle, CO. Detailed descriptions of the history, geology

  20. E-Print Network 3.0 - acidic uranium-contaminated aquifer Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (19% of wells) and Other (14% of wells) aquifers and none in the Ogallala-N aquifer. Uranium... ... 69...

  1. Uranium in granites from the southwestern United States: actinide parent-daughter systems, sites and mobilization. Second year report. National Uranium Resource Evaluation

    SciTech Connect (OSTI)

    Silver, L.T.; Woodhead, J.A.; Williams, I.S.; Chappell, B.W.

    1984-09-01T23:59:59.000Z

    Results of detailed field and laboratory studies are reported on the primary distribution of uranium (and thorium and lead) in the radioactive minerals of five radioactive granite bodies in Arizona and California. This distribution was examined in a granite pluton. Granites with uranium concentrations ranging from 4 to 47 ppM, thorium concentrations from 11 to 181 ppM, and Th/U ratios of 0.6 to 16.0 were compared. Evidence for secondary mobilization, migration, fixation and/or loss of uranium, thorium and radiogenic leads was explored. Uranium distribution in radioactive granites is hosted in a far greater diversity of sites than has previously been known. Uranium and thorium distribution in primary minerals of granites is almost entirely a disequilibrium product involving local fractionation processes during magmatic crystallization. Every radioactive granite studied contains minerals that contain uranium and/or thorium as major stoichiometric components. When the granites are subject to secondary geochemical events and processes, the behavior of uranium is determined by the stability fields of the different radioactive minerals in the rocks. The two most powerful tools for evaluating uranium migration in a granite are (a) isotope dilution mass spectrometry and (b) the electron microprobe. Uranium mobilization and loss is a common feature in radioactive granites of the southwestern United States. A model for the evaluation of uranium loss from granites has been developed. The mineral zircon can be used as an independent indicator of uranium and thorium endowment. The weathering products show surprising differences in the response of different granites in arid region settings. Significant losses of primary uranium (up to 70%) has been a common occurrence. Uranium, thorium and radiogenic lead exist in labile (movable) form on surfaces of cleavages, fractures and grain boundaries in granites.

  2. Lung cancer in uranium miners and the implications of the U/V ratio in uranium-bearing particles

    SciTech Connect (OSTI)

    Paschoa, A.S.; Wrenn, M.E.; Singh, N.P.; Bruenger, F.W.; Miller, S.C.; Cholewa, M.; Jones, K.W.

    1985-01-01T23:59:59.000Z

    Several geological formations mined for uranium ore during and after the second World War had been mined earlier for vanadium. Most miners and millers from the Utah-Colorado mining region worked with this ore or its tailings at one time or another. Preliminary investigation to determine the size and location of uranium-bearing particles retained in the lungs of a former uranium miner and miller from this region, who died of lung cancer (mesothelioma), showed a high nonuniform distribution of vanadium. This observation leads to the hypothesis that the vanadium content in that lung could be associated with inhaled particles. Further examination of spectra of characteristic x-rays obtained by scanning microPIXE (particle induced x-ray emission) of an autopsy sample of this lung indicated that vanadium was indeed present in localized sites within the 20 ..mu..m spatial resolution of the proton beam. This work points out that the vanadium found in the lungs of this former miner and miller is nonuniformly distributed, and can be used for site localization and size determination of inhaled particles retained in the lungs. The meaning of U/V ratios in dust particles and in lungs is discussed. Further studies are in progress to: (1) locate uranium-bearing particles in lung tissues of former uranium miners and millers; and (2) evaluate the local alpha doses received from these particles. 11 refs., 3 figs., 1 tab.

  3. New Technique for Speciation of Uranium in Sediments Following Acetate-Stimulated Bioremediation

    SciTech Connect (OSTI)

    Not Available

    2011-06-22T23:59:59.000Z

    Acetate-stimulated bioremediation is a promising new technique for sequestering toxic uranium contamination from groundwater. The speciation of uranium in sediments after such bioremediation attempts remains unknown as a result of low uranium concentration, and is important to analyzing the stability of sequestered uranium. A new technique was developed for investigating the oxidation state and local molecular structure of uranium from field site sediments using X-Ray Absorption Spectroscopy (XAS), and was implemented at the site of a former uranium mill in Rifle, CO. Glass columns filled with bioactive Rifle sediments were deployed in wells in the contaminated Rifle aquifer and amended with a hexavalent uranium (U(VI)) stock solution to increase uranium concentration while maintaining field conditions. This sediment was harvested and XAS was utilized to analyze the oxidation state and local molecular structure of the uranium in sediment samples. Extended X-Ray Absorption Fine Structure (EXAFS) data was collected and compared to known uranium spectra to determine the local molecular structure of the uranium in the sediment. Fitting was used to determine that the field site sediments did not contain uraninite (UO{sub 2}), indicating that models based on bioreduction using pure bacterial cultures are not accurate for bioremediation in the field. Stability tests on the monomeric tetravalent uranium (U(IV)) produced by bioremediation are needed in order to assess the efficacy of acetate-stimulation bioremediation.

  4. Reconnaissance Soil Geochemistry at the Riverton Uranium Mill Tailings Remedial Action Site, Fremont

    E-Print Network [OSTI]

    Fleskes, Joe

    Reconnaissance Soil Geochemistry at the Riverton Uranium Mill Tailings Remedial Action Site, Reconnaissance soil geochemistry at the Riverton Uranium Mill Tailings Remedial Action Site, Fremont County.....................................................................................................................................................link Figures Figure 1. Location of 19 soil samples collected from the Riverton Uranium Mill Tailings Remedial

  5. DETERMINING OPTICAL CONSTANTS OF URANIUM NITRIDE THIN FILMS IN THE EXTREME

    E-Print Network [OSTI]

    Hart, Gus

    DETERMINING OPTICAL CONSTANTS OF URANIUM NITRIDE THIN FILMS IN THE EXTREME ULTRAVIOLET (1.6-35 NM deposition and characterization of reactively-sputtered uranium nitride thin films. I also report optical.1 Application 1 1.2 Optical Constants 2 1.3 Project Focus 7 2 Uranium Nitride Thin Films 8 2.1 Sputtering 8 2

  6. Author's personal copy Crystal structure of the uranium oxo borohydride complex

    E-Print Network [OSTI]

    Girolami, Gregory S.

    Author's personal copy Crystal structure of the uranium oxo borohydride complex U2(l-O)(BH4)6(dme)2 online 9 November 2011 Keywords: Uranium Borohydride Hydride Oxo Crystal structure Aminodiboranate a b s t r a c t The reaction of uranium tetrachloride, UCl4, with sodium N,N-dimethylaminodiboranate, Na(H3

  7. Consequences of a multi-generation exposure to uranium on Caenorhabditis elegans life parameters and sensitivity

    E-Print Network [OSTI]

    Boyer, Edmond

    Consequences of a multi-generation exposure to uranium on Caenorhabditis elegans life parameters) Consequences of a multi- generation exposure to uranium on Caenorhabditis el- egans life parametersM of uranium. Several gen- erations were selected to assess growth, reproduction, survival, and dose

  8. Microbial reduction of iron(III)-rich nontronite and uranium(VI)1 Gengxin Zhang1

    E-Print Network [OSTI]

    Burgos, William

    1 Microbial reduction of iron(III)-rich nontronite and uranium(VI)1 2 Gengxin Zhang1 , John M Cosmochimica Acta9 10 Title running head: bioreduction of nontronite and uranium11 12 *Corresponding author17 examined the reduction of iron(III)-rich nontronite NAu-2 and uranium(VI) by18 Shewanella

  9. TO: Reid Rosnick, Radiation Protection Division, Environmental Protection Agency FROM: Sarah M. Fields, Uranium Watch

    E-Print Network [OSTI]

    : Sarah M. Fields, Uranium Watch DATE: November 25, 2009 RE: EPA REVIEW OF 40 CFR PART 61, SUBPART W -- RADON NESHAP FOR OPERATING URANIUM RECOVERY FACILITIES Below are some issues that the Environmental radionuclide NESHAPS in a timely manner. · Failure to properly implement radionuclide NESHAPS for uranium mills

  10. EPA Review of Standards for Uranium and Thorium Milling Facilities @ 40 CFR Parts 61 and 192.

    E-Print Network [OSTI]

    EPA Review of Standards for Uranium and Thorium Milling Facilities @ 40 CFR Parts 61 of EPA standards for Uranium and Thorium Milling Facilities @ 40 CFR Parts 61 and 192. I have been scientific perspectives related to the adequacy of existing public exposure standards for uranium mills

  11. Uranium Watch 76 South Main Street, # 7 | P.O. Box 344

    E-Print Network [OSTI]

    Uranium Watch 76 South Main Street, # 7 | P.O. Box 344 Moab, Utah 84532 435-26O-8384, May 2, 2014. Dear Mr. Rosnick: REQUEST FOR EXTENSION OF TIME TO SUBMIT COMMENTS Uranium Watch requests Rosnick/EPA 2 June 10, 2014 1 http://www.radiationcontrol.utah.gov/Uranium_Mills/uraniumone/docs/2012

  12. Surface blistering and flaking of sintered uranium dioxide samples under high dose gas implantation and annealing

    E-Print Network [OSTI]

    Boyer, Edmond

    Surface blistering and flaking of sintered uranium dioxide samples under high dose gas implantation-sur-Yvette, France. a guillaume.martin@cea.fr Keywords: uranium dioxide, helium, hydrogen, implantation, blistering, flaking Abstract. High helium contents will be generated within minor actinide doped uranium dioxide

  13. CHAPTER 6. BIBLIOGRAPHY AAPG 2005--American Association of Petroleum Geologists. Recent Uranium Industry Developments,

    E-Print Network [OSTI]

    Industry Developments, Exploration, Mining and Environmental Programs in the U.S. and Overseas. Uranium-Solution Mining. Uranium 1 (1978): 37-52. Burghardt 2003--Burghardt. J. Capitol Reef National Park (Utah): Rainy Day and Duchess Uranium Mines-Site Characterization (September 2002) Summary results presented at U

  14. Guardian Unlimited | Life | Microbes that can mop up uranium Sign in Register

    E-Print Network [OSTI]

    Lovley, Derek

    that was contaminated by low levels of uranium from mining residue, but they hope the technique might eventually be usedGuardian Unlimited | Life | Microbes that can mop up uranium Sign in Register Go to: Home This week Dispatch Opinion Interview Bad science Far out Last word Online Search Microbes that can mop up uranium

  15. 2.0 GEOGRAPHIC ANALYSIS ON THE LOCATION OF URANIUM MINES

    E-Print Network [OSTI]

    2.0 GEOGRAPHIC ANALYSIS ON THE LOCATION OF URANIUM MINES With the exception of some phosphate mine areas in central and northern Florida, people are most likely to be exposed to uranium mining mines. Figure 2.1 was generated from uranium mining-related records from the U.S. Bureau of Mines-- now

  16. Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain)

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    Multicomponent reactive transport modeling at the Ratones uranium mine, Cáceres (Spain) Modelación management. The Ratones uranium mine was abandoned and flooded in 1974. Due to its reducing underground water, uranium, reactive transport, granite hydrochemistry, Ratones mine. Resumen La inundación de minas

  17. DOSAGE RADIOMTRIQUE RAPIDE DE L'URANIUM ET DU THORIUM DANS LES MINERAIS COMPLEXES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    35 A. DOSAGE RADIOM�TRIQUE RAPIDE DE L'URANIUM ET DU THORIUM DANS LES MINERAIS COMPLEXES Par G radio métrique rapide de dosage de l'uranium et du thorium dans des minerais complexes. Elle utilise method for the determination of uranium and thorium in complex ores. We use fundamentally two gamma

  18. Fermi Surface of Uranium at Ambient Pressure Gregory S. Boebinger, National High Magnetic Field Laboratory

    E-Print Network [OSTI]

    Weston, Ken

    Fermi Surface of ­Uranium at Ambient Pressure Gregory S. Boebinger, National High Magnetic Field Laboratory DMR-Award 0654118 DC Field Facility User Program The fermi surface of ­Uranium has been measured surface of alpha-uranium at ambient pressure, Phys. Rev. B Rapid Commun., 80, 241101 (2009). B//c-axis B

  19. Mineral paragenesis and textures associated with sandstone-hosted roll-front uranium deposits, NW China

    E-Print Network [OSTI]

    Fayek, Mostafa

    , People's Republic of China c Northwest Institute of Uranium Geology, China National Nuclear CorporationMineral paragenesis and textures associated with sandstone-hosted roll-front uranium deposits, NW, Wuyiyi and Shihongtan sandstone-hosted roll-front uranium deposits, northwest China. The mineralization

  20. Uranium Mill Tailings Remedial Action 1993 Roadmap

    SciTech Connect (OSTI)

    Not Available

    1993-10-18T23:59:59.000Z

    The 1993 Roadmap for the Uranium Mill Tailings Remedial Action (UMTRA) Project office is a tool to assess and resolve issues. The US Department of Energy (DOE) UMTRA Project Office uses the nine-step roadmapping process as a basis for Surface and Groundwater Project planning. This is the second year the Roadmap document has been used to identify key issues and assumptions, develop logic diagrams, and outline milestones. This document is a key element of the DOE planning process. A multi-interest group used the nine-step process to focus on issues, root cause analysis and resolutions. This core group updated and incorporated comments on the basic assumptions, then used these assumptions to identify issues. The list of assumptions was categorized into the following areas: institutional, regulatory compliance, project management, human resource requirements, and other site-specific assumptions. The group identified 10 issues in the analysis phase. All of the issues are ranked according to importance. The number one issue from the 1992 Roadmap, ``Lack of sufficient human resources,`` remained the number one issue in 1993. The issues and their ranking are as follows: Lack of sufficient human resources; increasing regulatory requirements; unresolved groundwater issues; extension of UMTRCA through September 30, 1998; lack of post-UMTRA and post-cell closure policies; unpredictable amounts and timing of Federal funding; lack of regulatory compliance agreements; problem with states providing their share of remedial action costs; different interests and priorities among participants; and technology development/transfer. The issues are outlined and analyzed in detail in Section 8.0, with a schedule for resolution of these issues in Section 9.0.

  1. Interaction of Uranium(VI) with Phthalic Acid

    SciTech Connect (OSTI)

    Vazquez, G.; Dodge, C; Francis, A

    2008-01-01T23:59:59.000Z

    Phthalic acid, a ubiquitous organic compound found in soil, water, and in domestic and nuclear wastes can affect the mobility and bioavailability of metals and radionuclides. We examined the complexation of uranium with phthalic acid by potentiometric titration, electrospray ionization-mass spectroscopy (ESI-MS), and extended X-ray absorption fine structure (EXAFS) analysis. Potentiometric titration of a 1:1 U/phthalic acid indicated uranyl ion bonding with both carboxylate groups of phthalic acid; above pH 5 the uranyl ion underwent hydrolysis with one hydroxyl group coordinated to the inner-sphere of uranium. In the presence of excess phthalic acid, ESI-MS analysis revealed the formation of both 1:1 and 1:2 U/phthalic acid complexes. EXAFS studies confirmed the mononuclear biligand 1:2 U/phthalic acid complex as the predominant form. These results show that phthalates can form soluble stable complexes with uranium and may affect its mobility.

  2. Irradiation behavior of miniature experimental uranium silicide fuel plates

    SciTech Connect (OSTI)

    Hofman, G.L.; Neimark, L.A.; Mattas, R.F.

    1983-01-01T23:59:59.000Z

    Uranium silicides, because of their relatively high uranium density, were selected as candidate dispersion fuels for the higher fuel densities required in the Reduced Enrichment Research and Test Reactor (RERTR) Program. Irradiation experience with this type of fuel, however, was limited to relatively modest fission densities in the bulk from, on the order of 7 x 10/sup 20/ cm/sup -3/, far short of the approximately 20 x 10/sup 20/ cm/sup -3/ goal established for the RERTR program. The purpose of the irradiation experiments on silicide fuels on the ORR, therefore, was to investigate the intrinsic irradiation behavior of uranium silicide as a dispersion fuel. Of particular interest was the interaction between the silicide particles and the aluminum matrix, the swelling behavior of the silicide particles, and the maximum volume fraction of silicide particles that could be contained in the aluminum matrix.

  3. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  4. Atlas of uranium emission intensities in a hollow cathode discharge

    SciTech Connect (OSTI)

    Palmer, B.A.; Keller, R.A.; Engleman, R. Jr.

    1980-07-01T23:59:59.000Z

    The uranium emission spectrum from a hollow cathode discharge is displayed from 11,000 to 26,000 cm/sup -1/. This atlas lists 4928 spectral lines of uranium; 3949 are classified to the neutral spectrum and 431 are classified to the singly ionized spectrum. Listed wavenumbers are accurate to +-0.003 cm/sup -1/ and the listed relative intensities to +-8%. The richness of the spectrum makes this atlas useful for wavenumber calibration of lasers, spectrographs, and monochromators to an accuracy of 1 part in 10/sup 7/. This atlas is also useful as a guide to the uranium spectrum, and relative oscillator strengths (gf values) can be calculated from the intensities to a precision of +-20%.

  5. Total effective dose equivalent associated with fixed uranium surface contamination

    SciTech Connect (OSTI)

    Bogard, J.S.; Hamm, R.N.; Ashley, J.C.; Turner, J.E.; England, C.A.; Swenson, D.E.; Brown, K.S.

    1997-04-01T23:59:59.000Z

    This report provides the technical basis for establishing a uranium fixed-contamination action level, a fixed uranium surface contamination level exceeding the total radioactivity values of Appendix D of Title 10, Code of Federal Regulations, part 835 (10CFR835), but below which the monitoring, posting, and control requirements for Radiological Areas are not required for the area of the contamination. An area of fixed uranium contamination between 1,000 dpm/100 cm{sup 2} and that level corresponding to an annual total effective dose equivalent (TEDE) of 100 mrem requires only routine monitoring, posting to alert personnel of the contamination, and administrative control. The more extensive requirements for monitoring, posting, and control designated by 10CFR835 for Radiological Areas do not have to be applied for these intermediate fixed-contamination levels.

  6. Uranium Metal Reaction Behavior in Water, Sludge, and Grout Matrices

    SciTech Connect (OSTI)

    Delegard, Calvin H.; Schmidt, Andrew J.

    2008-09-25T23:59:59.000Z

    This report summarizes information and data on the reaction behavior of uranium metal in water, in water-saturated simulated and genuine K Basin sludge, and in grout matrices. This information and data are used to establish the technical basis for metallic uranium reaction behavior for the K Basin Sludge Treatment Project (STP). The specific objective of this report is to consolidate the various sources of information into a concise document to serve as a high-level reference and road map for customers, regulators, and interested parties outside the STP (e.g., external reviewers, other DOE sites) to clearly understand the current basis for the corrosion of uranium metal in water, sludge, and grout.

  7. Uranium Metal Reaction Behavior in Water, Sludge, and Grout Matrices

    SciTech Connect (OSTI)

    Delegard, Calvin H.; Schmidt, Andrew J.

    2009-05-27T23:59:59.000Z

    This report summarizes information and data on the reaction behavior of uranium metal in water, in water-saturated simulated and genuine K Basin sludge, and in grout matrices. This information and data are used to establish the technical basis for metallic uranium reaction behavior for the K Basin Sludge Treatment Project (STP). The specific objective of this report is to consolidate the various sources of information into a concise document to serve as a high-level reference and road map for customers, regulators, and interested parties outside the STP (e.g., external reviewers, other DOE sites) to clearly understand the current basis for the corrosion of uranium metal in water, sludge, and grout.

  8. Method for providing uranium with a protective copper coating

    DOE Patents [OSTI]

    Waldrop, Forrest B. (Powell, TN); Jones, Edward (Knoxville, TN)

    1981-01-01T23:59:59.000Z

    The present invention is directed to a method for providing uranium metal with a protective coating of copper. Uranium metal is subjected to a conventional cleaning operation wherein oxides and other surface contaminants are removed, followed by etching and pickling operations. The copper coating is provided by first electrodepositing a thin and relatively porous flash layer of copper on the uranium in a copper cyanide bath. The resulting copper-layered article is then heated in an air or inert atmosphere to volatilize and drive off the volatile material underlying the copper flash layer. After the heating step an adherent and essentially non-porous layer of copper is electro-deposited on the flash layer of copper to provide an adherent, multi-layer copper coating which is essentially impervious to corrosion by most gases.

  9. Fernald vacuum transfer system for uranium materials repackaging

    SciTech Connect (OSTI)

    Kaushiva, Shirley; Weekley, Clint; Molecke, Martin; Polansky, Gary

    2002-02-24T23:59:59.000Z

    The Fernald Environmental Management Project (FEMP) is the site of a former Department of Energy (DOE) uranium processing plant. When production was halted, many materials were left in an intermediate state. Some of this product material included enriched uranium compounds that had to be repackaged for shipment of off-site storage. This paper provides an overview, technical description, and status of a new application of existing technology, a vacuum transfer system, to repackage the uranium bearing compounds for shipment. The vacuum transfer system provides a method of transferring compounds from their current storage configuration into packages that meet the Department of Transportation (DOT) shipping requirements for fissile materials. This is a necessary activity, supporting removal of nuclear materials prior to site decontamination and decommissioning, key to the Fernald site's closure process.

  10. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  11. Evaluation of integrated data sets: four examples. [Uranium deposits (exploration)

    SciTech Connect (OSTI)

    Bolivar, S.L.; Freeman, S.B.; Weaver, T.A.

    1982-01-01T23:59:59.000Z

    Several large data sets have been integrated and utilized for rapid evaluation on a reconnaissance scale for the Montrose 1/sup 0/ x 2/sup 0/ quadrangle, Colorado. The data sets include Landsat imagery, hydrogeochemical and stream sediment analyses, airborne geophysical data, known mineral occurrences, and a geologic map. All data sets were registered to a 179 x 119 rectangular grid and projected onto Universal Transverse Mercator coordinates. A grid resolution of 1 km was used. All possible combinations of three, for most data sets, were examined for general geologic correlations by utilizing a color microfilm output. In addition, gray-level pictures of statistical output, e.g., factor analysis, have been employed to aid evaluations. Examples for the data sets dysprosium-calcium, lead-copper-zinc, and equivalent uranium-uranium in water-uranium in sediment are described with respect to geologic applications, base-metal regimes, and geochemical associations.

  12. Uranium for hydrogen storage applications : a materials science perspective.

    SciTech Connect (OSTI)

    Shugard, Andrew D.; Tewell, Craig R.; Cowgill, Donald F.; Kolasinski, Robert D.

    2010-08-01T23:59:59.000Z

    Under appropriate conditions, uranium will form a hydride phase when exposed to molecular hydrogen. This makes it quite valuable for a variety of applications within the nuclear industry, particularly as a storage medium for tritium. However, some aspects of the U+H system have been characterized much less extensively than other common metal hydrides (particularly Pd+H), likely due to radiological concerns associated with handling. To assess the present understanding, we review the existing literature database for the uranium hydride system in this report and identify gaps in the existing knowledge. Four major areas are emphasized: {sup 3}He release from uranium tritides, the effects of surface contamination on H uptake, the kinetics of the hydride phase formation, and the thermal desorption properties. Our review of these areas is then used to outline potential avenues of future research.

  13. Method for the production of uranium chloride salt

    DOE Patents [OSTI]

    Westphal, Brian R.; Mariani, Robert D.

    2013-07-02T23:59:59.000Z

    A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

  14. Method for cleaning bomb-reduced uranium derbies

    DOE Patents [OSTI]

    Banker, John G. (Boulder, CO); Wigginton, Hubert L. (Oak Ridge, TN); Beck, David E. (Knoxville, TN); Holcombe, Cressie E. (Knoxville, TN)

    1981-01-01T23:59:59.000Z

    The concentration of carbon in uranium metal ingots induction cast from derbies prepared by the bomb-reduction of uranium tetrafluoride in the presence of magnesium is effectively reduced to less than 100 ppm by removing residual magnesium fluoride from the surface of the derbies prior to casting. This magnesium fluoride is removed from the derbies by immersing them in an alkali metal salt bath which reacts with and decomposes the magnesium fluoride. A water quenching operation followed by a warm nitric acid bath and a water rinse removes the residual salt and reaction products from the derbies.

  15. Reductive stripping process for uranium recovery from organic extracts

    DOE Patents [OSTI]

    Hurst, F.J. Jr.

    1983-06-16T23:59:59.000Z

    In the reductive stripping of uranium from an organic extractant in a uranium recovery process, the use of phosphoric acid having a molarity in the range of 8 to 10 increases the efficiency of the reductive stripping and allows the strip step to operate with lower aqueous to organic recycle ratios and shorter retention time in the mixer stages. Under these operating conditions, less solvent is required in the process, and smaller, less expensive process equipment can be utilized. The high strength H/sub 3/PO/sub 4/ is available from the evaporator stage of the process.

  16. Paragenesis and Geochronology of the Nopal I Uranium Deposit, Mexico

    SciTech Connect (OSTI)

    M. Fayek; M. Ren

    2007-02-14T23:59:59.000Z

    Uranium deposits can, by analogy, provide important information on the long-term performance of radioactive waste forms and radioactive waste repositories. Their complex mineralogy and variable elemental and isotopic compositions can provide important information, provided that analyses are obtained on the scale of several micrometers. Here, we present a structural model of the Nopal I deposit as well as petrography at the nanoscale coupled with preliminary U-Th-Pb ages and O isotopic compositions of uranium-rich minerals obtained by Secondary Ion Mass Spectrometry (SIMS). This multi-technique approach promises to provide ''natural system'' data on the corrosion rate of uraninite, the natural analogue of spent nuclear fuel.

  17. Criticality Safety of Low-Enriched Uranium and High-Enriched Uranium Fuel Elements in Heavy Water Lattices

    SciTech Connect (OSTI)

    Pesic, Milan P

    2003-10-15T23:59:59.000Z

    The RB reactor was designed as a natural-uranium, heavy water, nonreflected critical assembly in the Vinca Institute of Nuclear Sciences, Belgrade, Yugoslavia, in 1958. From 1962 until 2002, numerous critical experiments were carried out with low-enriched uranium and high-enriched uranium fuel elements of tubular shape, known as the Russian TVR-S fuel assembly type, placed in various heavy water square lattices within the RB cylindrical aluminum tank. Some of these well-documented experiments were selected, described, evaluated, and accepted for inclusion in the 'International Handbook of Evaluated Criticality Safety Benchmark Experiments', contributing to the preservation of a rather small number of heavy water benchmark critical experiments.

  18. Controlling intake of uranium in the workplace: Applications of biokinetic modeling and occupational monitoring data

    SciTech Connect (OSTI)

    Leggett, Richard Wayne [ORNL; Eckerman, Keith F [ORNL; McGinn, Wilson [ORNL; Meck, Dr. Robert A. [U.S. Nuclear Regulatory Commission

    2012-01-01T23:59:59.000Z

    This report provides methods for interpreting and applying occupational uranium monitoring data. The methods are based on current international radiation protection guidance, current information on the chemical toxicity of uranium, and best available biokinetic models for uranium. Emphasis is on air monitoring data and three types of bioassay data: the concentration of uranium in urine; the concentration of uranium in feces; and the externally measured content of uranium in the chest. Primary Reference guidance levels for prevention of chemical effects and limitation of radiation effects are selected based on a review of current scientific data and regulatory principles for setting standards. Generic investigation levels and immediate action levels are then defined in terms of these primary guidance levels. The generic investigation and immediate actions levels are stated in terms of radiation dose and concentration of uranium in the kidneys. These are not directly measurable quantities, but models can be used to relate the generic levels to the concentration of uranium in air, urine, or feces, or the total uranium activity in the chest. Default investigation and immediate action levels for uranium in air, urine, feces, and chest are recommended for situations in which there is little information on the form of uranium taken into the body. Methods are prescribed also for deriving case-specific investigation and immediate action levels for uranium in air, urine, feces, and chest when there is sufficient information on the form of uranium to narrow the range of predictions of accumulation of uranium in the main target organs for uranium: kidneys for chemical effects and lungs for radiological effects. In addition, methods for using the information herein for alternative guidance levels, different from the ones selected for this report, are described.

  19. Prompt Neutron Decay for Delayed Critical Bare and Natural-Uranium-Reflected Metal Spheres of Plutonium and Highly Enriched Uranium

    SciTech Connect (OSTI)

    Mihalczo, John T [ORNL

    2011-01-01T23:59:59.000Z

    Prompt neutron decay at delayed criticality was measured by Oak Ridge National Laboratory for uranium-reflected highly enriched uranium (HEU) and Pu metal spheres (FLATTOP), for an unreflected Pu metal (4.5% {sup 240}Pu) sphere (JEZEBEL) at Los Alamos National Laboratory (LANL) and for an unreflected HEU metal sphere at Oak Ridge Critical Experiments Facility. The average prompt neutron decay constants from hundreds of Rossi-{alpha} and randomly pulsed neutron measurements with {sup 252}Cf at delayed criticality are as follows: 3.8458 {+-} 0.0016 x 10{sup 5} s{sup -1}, 2.2139 {+-} 0.0022 x 10{sup 5} s{sup -1}, 6.3126 {+-} 0.0100 x 10{sup 5} s{sup -1}, and 1.1061 {+-} 0.0009 x 10{sup 6} s{sup -1}, respectively. These values agree with previous measurements by LANL for FLATTOP, JEZEBEL, and GODIVA I as follows: 3.82 {+-} 0.02 x 10{sup 5} s{sup -1} for a uranium core; 2.14 {+-} 0.05 x 10{sup 5} s{sup -1} and 2.29 x 10{sup 5} s{sup -1} (uncertainty not reported) for a plutonium core; 6.4 {+-} 0.1 x 10{sup 5} s{sup -1}, and 1.1 {+-} 0.1 x 10{sup 6} s{sup -1}, respectively, but have smaller uncertainties because of the larger number of measurements. For the FLATTOP and JEZEBEL assemblies, the measurements agree with calculations. Traditionally, the calculated decay constants for the bare uranium metal sphere GODIVA I and the Oak Ridge Uranium Metal Sphere were higher than experimental by {approx}10%. Other energy-dependent quantities for the bare uranium sphere agree within 1%.

  20. Stimulating the In Situ Activity of Geobacter Species to Remove Uranium from the Groundwater of a Uranium-Contaminated Aquifer

    SciTech Connect (OSTI)

    Anderson, R. T.; Vrionis, Helen A.; Ortiz-Bernad, Irene; Resch, Charles T.; Long, Philip E.; Dayvault, R. D.; Karp, Ken; Marutzky, Sammy J.; Metzler, Donald R.; Peacock, Aaron D.; White, David C.; Lowe, Mary; Lovley, Derek R.

    2003-10-01T23:59:59.000Z

    The potential for removing uranium from contaminated groundwater by stimulating the in situ activity of dissimilatory metal-reducing microorganisms was evaluated in a uranium-contaminated aquifer located in Rifle, Colo. Acetate (1 to 3 mM) was injected into the subsurface over a 3-month period via an injection gallery composed of 20 injection wells, which was installed upgradient from a series of 15 monitoring wells. U(VI) concentrations decreased in as little as 9 days after acetate injection was initiated, and within 50 days uranium had declined below the prescribed treatment level of 0.18 _M in some of the monitoring wells. Analysis of 16S ribosomal DNA (rDNA) sequences and phospholipid fatty acid profiles demonstrated that the initial loss of uranium from the groundwater was associated with an enrichment of Geobacter species in the treatment zone. Fe(II) in the groundwater also increased during this period, suggesting that U(VI) reduction was coincident with Fe(III) reduction. As the acetate injection continued over 50 days there was a loss of sulfate from the groundwater and an accumulation of sulfide and the composition of the microbial community changed. Organisms with 16S rDNA sequences most closely related to those of sulfate reducers became predominant, and Geobacter species became a minor component of the community. This apparent switch from Fe(III) reduction to sulfate reduction as the terminal electron accepting process for the oxidation of the injected acetate was associated with an increase in uranium concentration in the groundwater. These results demonstrate that in situ bioremediation of uranium-contaminated groundwater is feasible but suggest that the strategy should be optimized to better maintain long-term activity of Geobacter species.