National Library of Energy BETA

Sample records for upthrown block urban

  1. Indian Community Development Block Grant Program Workshop- Seattle

    Broader source: Energy.gov [DOE]

    The U.S. Department of Housing and Urban Development (HUD) Southwest Office of Native American Programs is conducting this training workshop to assist applicants with the Indian Community Development Block Grant Program.

  2. Thermally actuated wedge block

    DOE Patents [OSTI]

    Queen, Jr., Charles C.

    1980-01-01

    This invention relates to an automatically-operating wedge block for maintaining intimate structural contact over wide temperature ranges, including cryogenic use. The wedging action depends on the relative thermal expansion of two materials having very different coefficients of thermal expansion. The wedge block expands in thickness when cooled to cryogenic temperatures and contracts in thickness when returned to room temperature.

  3. Indian Community Development Block Grant Program FY 2016 Notice of Funding Availability Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Housing and Urban Development (HUD) Southwest Office of Native American Programs is conducting this training workshop to assist applicants with the Indian Community Development Block Grant Program.

  4. Block copolymer battery separator

    DOE Patents [OSTI]

    Wong, David; Balsara, Nitash Pervez

    2016-04-26

    The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF.sub.6 in EC/DEC (1:1 v/v) using AC impedance spectroscopy and comparing these results to commercially available battery separators.

  5. Urban hopper.

    SciTech Connect (OSTI)

    Xavier, Patrick Gordon; Feddema, John Todd; Little, Charles Quentin; Spletzer, Barry Louis; Fischer, Gary John; Weagle, Christian A.; Salton, Jonathan Robert; Marron, Lisa Carol; Malchano, Matthew D.; Giarrantana, John; Murphy, Michael P.; Rizzi, Alfred A.; Buerger, Stephen P.

    2010-03-01

    Hopping robots provide the possibility of breaking the link between the size of a ground vehicle and the largest obstacle that it can overcome. For more than a decade, DARPA and Sandia National Laboratories have been developing small-scale hopping robot technology, first as part of purely hopping platforms and, more recently, as part of platforms that are capable of both wheeled and hopping locomotion. In this paper we introduce the Urban Hopper robot and summarize its capabilities. The advantages of hopping for overcoming certain obstacles are discussed. Several configurations of the Urban Hopper are described, as are intelligent capabilities of the system. Key challenges are discussed.

  6. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T.

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  7. Net Requirements Transparency Process for Slice/Block and Block...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 As part of its Net Requirements Transparency process, on July 31, 2013 BPA published the SliceBlock and Block customers' FY2012 and forecast FY2014 Total Retail Load (TRL) and...

  8. CORE SATURATION BLOCKING OSCILLATOR

    DOE Patents [OSTI]

    Spinrad, R.J.

    1961-10-17

    A blocking oscillator which relies on core saturation regulation to control the output pulse width is described. In this arrangement an external magnetic loop is provided in which a saturable portion forms the core of a feedback transformer used with the thermionic or semi-conductor active element. A first stationary magnetic loop establishes a level of flux through the saturation portion of the loop. A second adjustable magnet moves the flux level to select a saturation point giving the desired output pulse width. (AEC)

  9. Eikonalization of conformal blocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.; Wang, Junpu

    2015-09-03

    Classical field configurations such as the Coulomb potential and Schwarzschild solution are built from the t-channel exchange of many light degrees of freedom. We study the CFT analog of this phenomenon, which we term the 'eikonalization' of conformal blocks. We show that when an operator T appears in the OPE Ο(x)Ο(0), then the large spin Fock space states [TT···T]ℓ also appear in this OPE with a computable coefficient. The sum over the exchange of these Fock space states in an correlator build the classical 'T field' in the dual AdS description. In some limits the sum of all Fock spacemore » exchanges can be represented as the exponential of a single T exchange in the 4-pt correlator of O. Our results should be useful for systematizing 1/ℓ perturbation theory in general CFTs and simplifying the computation of large spin OPE coefficients. As examples we obtain the leading log ℓ dependence of Fock space conformal block coefficients, and we directly compute the OPE coefficients of the simplest ‘triple-trace’ operators.« less

  10. Eikonalization of conformal blocks

    SciTech Connect (OSTI)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.; Wang, Junpu

    2015-09-03

    Classical field configurations such as the Coulomb potential and Schwarzschild solution are built from the t-channel exchange of many light degrees of freedom. We study the CFT analog of this phenomenon, which we term the 'eikonalization' of conformal blocks. We show that when an operator T appears in the OPE Ο(x)Ο(0), then the large spin Fock space states [TT···T] also appear in this OPE with a computable coefficient. The sum over the exchange of these Fock space states in an correlator build the classical 'T field' in the dual AdS description. In some limits the sum of all Fock space exchanges can be represented as the exponential of a single T exchange in the 4-pt correlator of O. Our results should be useful for systematizing 1/ℓ perturbation theory in general CFTs and simplifying the computation of large spin OPE coefficients. As examples we obtain the leading log ℓ dependence of Fock space conformal block coefficients, and we directly compute the OPE coefficients of the simplest ‘triple-trace’ operators.

  11. Help:Blocking users | Open Energy Information

    Open Energy Info (EERE)

    3 What it means to be blocked 4 See Also Blocking Blocking users is fairly straightforward, visit Special:BlockIP and follow these steps: IP Address or username: Enter in...

  12. Urban runoff quality management

    SciTech Connect (OSTI)

    1998-12-31

    This new manual of practice, jointly produced by the Water Environment Federation and American Society of Civil Engineers, focuses on the protection and enhancement of urban water resources by controlling the transport of constituents into urban waterways by urban stormwater runoff. The manual emphasizes control of constituent discharges, reflecting the fact that chemical and particulate constituents in urban stormwater runoff play a key role in determining the negative effects of that runoff.

  13. Christopher Urban | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Urban Research Scientist Chris.Urban@nrel.gov | 303-384-7917 Research Interests Chris Urban's experience includes directed organic synthesis for the Liquid Crystal Materials Research Center at University of Colorado - Boulder, as well as liquid chromatography-mass spectrometry analysis for the pharmaceutical industry. Education B.A., Biochemistry and Molecular Biology, University of Colorado - Boulder, 2007

  14. Standard Missile Block IV battery

    SciTech Connect (OSTI)

    Martin, J.

    1996-11-01

    During the 1980`s a trend in automatic primary battery technologies was the replacement of silver-zinc batteries by thermal battery designs. The Standard missile (SM 2) Block IV development is a noteworthy reversal of this trend. The SM2, Block IV battery was originally attempted as a thermal battery with multiple companies attempting to develop a thermal battery design. These attempts resulted in failure to obtain a production thermal battery. A decision to pursue a silver-zinc battery design resulted in the development of a battery to supply the SM 2, Block IV (thermal battery design goal) and also the projected power requirements of the evolving SM 2, Block IVA in a single silver-zinc battery design. Several advancements in silver-zinc battery technology were utilized in this design that improve the producibility and extend the boundaries of silver-zinc batteries.

  15. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport How Antidepressants Block Serotonin Transport Print Tuesday, 12 July 2016 00:00 Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In

  16. Help:Range blocks | Open Energy Information

    Open Energy Info (EERE)

    accounts editing from these IP addresses will also be blocked, unless you check the box to only block anonymous editors. Range blocking is enabled on all Wikimedia wikis; to...

  17. Block LancZos PACKage

    Energy Science and Technology Software Center (OSTI)

    2005-05-01

    BLZPACK (for Block LancZos PACKage) is a standard Fortran 77 implementation of the block Lanczos algorithm intended for the solution of the standard eigenvalue problem Ax=ux or the generalized eigenvalue problem Ax=uBx, where A and B are real, sparse symmetric matrices, u and eigenvalue and x and eigenvector. The development of this eigensolver was motivated by the need to solve large, sparse, generalized problems from free vibration analyses in structural engineering. Several upgrades were performedmore » afterwards aiming at the solution of eigenvalues problems from a wider range of applications.« less

  18. Urban Food Initiative

    SciTech Connect (OSTI)

    Buluswar, Shashi

    2015-05-06

    Shashi Buluswar, Berkeley Lab's Executive Director of the Institute for Globally Transformative Technologies (LIGTT) discusses the issue of urban food deserts and malnutrition in American inner cities.

  19. Belos Block Linear Solvers Package

    Energy Science and Technology Software Center (OSTI)

    2004-03-01

    Belos is an extensible and interoperable framework for large-scale, iterative methods for solving systems of linear equations with multiple right-hand sides. The motivation for this framework is to provide a generic interface to a collection of algorithms for solving large-scale linear systems. Belos is interoperable because both the matrix and vectors are considered to be opaque objects--only knowledge of the matrix and vectors via elementary operations is necessary. An implementation of Balos is accomplished viamore » the use of interfaces. One of the goals of Belos is to allow the user flexibility in specifying the data representation for the matrix and vectors and so leverage any existing software investment. The algorithms that will be included in package are Krylov-based linear solvers, like Block GMRES (Generalized Minimal RESidual) and Block CG (Conjugate-Gradient).« less

  20. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system, causing

  1. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system,

  2. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system,

  3. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system,

  4. Liquid-blocking check valve

    DOE Patents [OSTI]

    Merrill, J.T.

    1982-09-27

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  5. Method for making block siloxane copolymers

    DOE Patents [OSTI]

    Butler, Nora; Jessop, Edward S.; Kolb, John R.

    1982-01-01

    A method for synthesizing block polysiloxane copolymers. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

  6. Method for making block siloxane copolymers

    DOE Patents [OSTI]

    Butler, N.L.; Jessop, E.S.; Kolb, J.R.

    1981-02-25

    A method for synthesizing block polysiloxane copolymers is disclosed. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

  7. BLOCKING OSCILLATOR DOUBLE PULSE GENERATOR CIRCUIT

    DOE Patents [OSTI]

    Haase, J.A.

    1961-01-24

    A double-pulse generator, particuiarly a double-pulse generator comprising a blocking oscillator utilizing a feedback circuit to provide means for producing a second pulse within the recovery time of the blocking oscillator, is described. The invention utilized a passive network which permits adjustment of the spacing between the original pulses derived from the blocking oscillator and further utilizes the original pulses to trigger a circuit from which other pulses are initiated. These other pulses are delayed and then applied to the input of the blocking oscillator, with the result that the output from the oscillator circuit contains twice the number of pulses originally initiated by the blocking oscillator itself.

  8. LARGE BLOCK TEST STATUS REPORT

    SciTech Connect (OSTI)

    Wilder, D. G.; Blair, S. C.; Buscheck, T.; Carloson, R. C.; Lee, K.; Meike, A.; Ramirez, J. L.; Sevougian, D.

    1997-08-26

    This report is intended to serve as a status report, which essentially transmits the data that have been collected to date on the Large Block Test (LBT). The analyses of data will be performed during FY98, and then a complete report will be prepared. This status report includes introductory material that is not needed merely to transmit data but is available at this time and therefore included. As such, this status report will serve as the template for the future report, and the information is thus preserved. The United States Department of Energy (DOE) is investigatinq the suitability of Yucca Mountain (YM) as a potential site for the nation's first high-level nuclear waste repository. As shown in Fig. 1-1, the site is located about 120 km northwest of Las Vegas, Nevada, in an area of uninhabited desert.

  9. Urban Hopper Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Urban Electric Power Takes Energy Storage from Startup to Grid-Scale Urban Electric Power Takes Energy Storage from Startup to Grid-Scale June 25, 2013 - 12:42pm Addthis Learn how the CUNY Energy Institute is creating safe, low cost, rechargeable, long lifecycle batteries that could be used to store renewable energy. | Video courtesy of the Energy Department. Alexa McClanahan Communications Support Contractor to ARPA-E What are the key facts? The CUNY Energy Institute

  10. Measurements of net radiation, ground heat flux and surface temperature in an urban canyon

    SciTech Connect (OSTI)

    Gouveia, F J; Leach, M J; Shinn, J H

    2003-11-06

    The Joint Urban 2003 (JU2003) field study was conducted in Oklahoma City in July 2003 to collect data to increase our knowledge of dispersion in urban areas. Air motions in and around urban areas are very complicated due to the influence of urban structures on both mechanical and thermal forcing. During JU2003, meteorological instruments were deployed at various locations throughout the urban area to characterize the processes that influence dispersion. Some of the instruments were deployed to characterize urban phenomena, such as boundary layer development. In addition, particular sites were chosen for more concentrated measurements to investigate physical processes in more detail. One such site was an urban street canyon on Park Avenue between Broadway and Robinson Avenues in downtown Oklahoma City. The urban canyon study was designed to examine the processes that control dispersion within, into and out of the urban canyon. Several towers were deployed in the Park Avenue block, with multiple levels on each tower for observing the wind using sonic anemometers. Infrared thermometers, net radiometers and ground heat flux plates were deployed on two of the towers midway in the canyon to study the thermodynamic effects and to estimate the surface energy balance. We present results from the surface energy balance observations.

  11. Block Island Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    energy Facility Type Commercial Scale Wind Facility Status Proposed Developer Deepwater Wind Location Offshore from Block Island RI Coordinates 41.1, -71.53 Show Map Loading...

  12. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Grant Program Project Title AK-TRIBE-NANWALEK (AKA ENGLISH BAY) Location: Tribe AK-TRIBE- NANWALEK (AKA ENGLISH BAY) AK American Recovery and Reinvestment Act: Proposed ...

  13. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program ... diode (LED) retrofits, 4) building retrofits to replace a 50 ton HVAC ...

  14. Alternating Current Photovoltaic Building Block - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Alternating Current Photovoltaic Building Block Sandia National Laboratories Contact SNL About This...

  15. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title ...

  16. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NEP A Determination for the Energy Efficiency and Conservation Block Grant Program Application submitted by the Native Village of Tetlin of AK Energy Efficiency and Conservation ...

  17. Light extraction block with curved surface

    DOE Patents [OSTI]

    Levermore, Peter; Krall, Emory; Silvernail, Jeffrey; Rajan, Kamala; Brown, Julia J.

    2016-03-22

    Light extraction blocks, and OLED lighting panels using light extraction blocks, are described, in which the light extraction blocks include various curved shapes that provide improved light extraction properties compared to parallel emissive surface, and a thinner form factor and better light extraction than a hemisphere. Lighting systems described herein may include a light source with an OLED panel. A light extraction block with a three-dimensional light emitting surface may be optically coupled to the light source. The three-dimensional light emitting surface of the block may includes a substantially curved surface, with further characteristics related to the curvature of the surface at given points. A first radius of curvature corresponding to a maximum principal curvature k.sub.1 at a point p on the substantially curved surface may be greater than a maximum height of the light extraction block. A maximum height of the light extraction block may be less than 50% of a maximum width of the light extraction block. Surfaces with cross sections made up of line segments and inflection points may also be fit to approximated curves for calculating the radius of curvature.

  18. Precision aligned split V-block

    DOE Patents [OSTI]

    George, Irwin S.

    1984-01-01

    A precision aligned split V-block for holding a workpiece during a milling operation having an expandable frame for allowing various sized workpieces to be accommodated, is easily secured directly to the mill table and having key lugs in one base of the split V-block that assures constant alignment.

  19. SF30 Continuation Page, Block 14

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Page 9 of 12 Contract DE-AC27-08RV 14800 Modification 083 SF30 Continuation Page, Block 14 7. Update Section J, J-4 Performance Evaluation and Measurement Plan (PEMP), page ...

  20. Building Blocks for the Future of Manufacturing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Blocks for the Future of Manufacturing Scott Smith 2011.05.04 Even though we grew ... Can you send more information on this technology? A photo of Scott Smith. About the Author ...

  1. Picture of the Week: Supercomputer building blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Supercomputer building blocks The first row of cabinets for the new Trinity supercomputer are being prepared for connection to the water cooling infrastructure at Los Alamos National Laboratory. Each set of 12 cabinets is delivered, connected and tested one row at a time, by the Cray installation team, until all five rows arrive. June 21, 2015 Supercomputer building blocks x View extra-large image on Flickr » The first row of cabinets for the new Trinity supercomputer are being prepared for

  2. Molecular origin of photovoltaic performance in donor-block-acceptor all-conjugated block copolymers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Kendall A.; Lin, Yen -Hao; Mok, Jorge W.; Yager, Kevin G.; Strzalka, Joseph; Nie, Wanyi; Mohite, Aditya D.; Verduzco, Rafael

    2015-11-03

    All-conjugated block copolymers may be an effective route to self-assembled photovoltaic devices, but we lack basic information on the relationship between molecular characteristics and photovoltaic performance. Here, we synthesize a library of poly(3-hexylthiophene) (P3HT) block poly((9,9-dialkylfluorene)-2,7-diyl-alt-[4,7-bis(alkylthiophen-5-yl)-2,1,3-benzothiadiazole]-2',2''-diyl) (PFTBT) donor-block-acceptor all-conjugated block copolymers and carry out a comprehensive study of processing conditions, crystallinity, domain sizes, and side-chain structure on photovoltaic device performance. We find that all block copolymers studied exhibit an out-of-plane crystal orientation after deposition, and on thermal annealing at high temperatures the crystal orientation flips to an in-plane orientation. By varying processing conditions on polymer photovoltaic devices, we show thatmore » the crystal orientation has only a modest effect (15-20%) on photovoltaic performance. The addition of side-chains to the PFTBT block is found to decrease photovoltaic power conversion efficiencies by at least an order of magnitude. Through grazing-incidence X-ray measurements we find that the addition of side-chains to the PFTBT acceptor block results in weak segregation and small (< 10 nm) block copolymer self-assembled donor and acceptor domains. This work is the most comprehensive to date on all-conjugated block copolymer systems and suggests that photovoltaic performance of block copolymers depends strongly on the miscibility of donor and acceptor blocks, which impacts donor and acceptor domain sizes and purity. Lastly, strategies for improving the device performance of block copolymer photovoltaics should seek to increase segregation between donor and acceptor polymer domains.« less

  3. Volker Urban | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Volker Urban Volker Urban Volker Urban Principal Investigator E-mail: urbanvs@ornl.gov Phone: 865-576-7221 Fax: 865-574-6080 Website: Oak Ridge National Lab Website Principal...

  4. Exploration of multi-block polymer morphologies using high performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exploration of multi-block polymer morphologies using high performance computing Modern material design increasingly relies on controlling small scale morphologies. Multi-block...

  5. Indian Community Development Block Grant Program FY 2016 Notice...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Indian Community Development Block Grant Program FY 2016 Notice of Funding Availability Workshop Indian Community Development Block Grant Program FY 2016 Notice of Funding ...

  6. Guidance for Energy Efficiency and Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conservation Block Grant Grantees on Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds Guidance for Energy Efficiency and Conservation Block Grant Program ...

  7. Guidance for Energy Efficiency and Conservation Block Grant Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Grant Program Recipients on Formula Grants U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Energy Efficiency and Conservation Block ...

  8. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Program Guidance Grantee Letter Energy Efficiency and Conservation Block Grant ... of Energy Efficiency and Conservation Block Grant-funded financing programs, including ...

  9. Energy Efficiency and Conservation Block Grant Program National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Grant Program National Evaluation Executive Summary This document presents findings from an evaluation of the Energy Efficiency and Conservation Block Grant ...

  10. Energy Efficiency and Consveration Block Grant Program National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Consveration Block Grant Program National Evaluation Fact Sheet Energy Efficiency and Consveration Block Grant Program National Evaluation Fact Sheet This fact sheet provides ...

  11. Energy Efficiency and Conservation Block Grant Financing Programs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement ...

  12. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON ...

  13. Guidance For Energy Efficiency And Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs U.S. ...

  14. Deformation Processes in Block Copolymer Toughened Epoxies (Journal...

    Office of Scientific and Technical Information (OSTI)

    Deformation Processes in Block Copolymer Toughened Epoxies Citation Details In-Document Search Title: Deformation Processes in Block Copolymer Toughened Epoxies Authors:...

  15. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency and Conservation Block Grant Financing Program Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy Efficiency ...

  16. Solvothermal Thin Film Deposition of Electron Blocking Layers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers...

  17. Guidance For Energy Efficiency And Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing ...

  18. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Conservation Block Grant Financing Program Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy ...

  19. A Blueprint for Urban Sustainability: Integrating Sustainable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Blueprint for Urban Sustainability: Integrating Sustainable Energy Practices into Metropolitan Planning, May 2004 A Blueprint for Urban Sustainability: Integrating Sustainable ...

  20. EPA Urban Waters Small Grant Program

    Broader source: Energy.gov [DOE]

    The U.S. Environmental Protection Agency is accepting applications for the Urban Waters Small Grants Program to address urban runoff pollution with a focus on underserved communities.

  1. Lennar Homes & Lennar Urban | Open Energy Information

    Open Energy Info (EERE)

    Lennar Homes & Lennar Urban Jump to: navigation, search Name: Lennar Homes & Lennar Urban Place: Miami, FL Information About Partnership with NREL Partnership with NREL Yes...

  2. HUD Community Development Block Grant Program

    Broader source: Energy.gov [DOE]

    The U.S. Department of Housing and Urban Development (HUD) is accepting applications to develop of viable Indian and Alaska Native communities, including the creation of decent housing, suitable living environments, and economic opportunities primarily for persons with low- and moderate-incomes.

  3. A novel power block for CSP systems

    SciTech Connect (OSTI)

    Mittelman, Gur; Epstein, Michael

    2010-10-15

    Concentrating Solar Thermal Power (CSP) and in particular parabolic trough, is a proven large-scale solar power technology. However, CSP cost is not yet competitive with conventional alternatives unless subsidized. Current CSP plants typically include a condensing steam cycle power block which was preferably designed for a continuous operation and higher operating conditions and therefore, limits the overall plant cost effectiveness and deployment. The drawbacks of this power block are as follows: (i) no power generation during low insolation periods (ii) expensive, large condenser (typically water cooled) due to the poor extracted steam properties (high specific volume, sub-atmospheric pressure) and (iii) high installation and operation costs. In the current study, a different power block scheme is proposed to eliminate these obstacles. This power block includes a top Rankine cycle with a back pressure steam turbine and a bottoming Kalina cycle comprising another back pressure turbine and using ammonia-water mixture as a working fluid. The bottoming (moderate temperature) cycle allows power production during low insolation periods. Because of the superior ammonia-water vapor properties, the condensing system requirements are much less demanding and the operation costs are lowered. Accordingly, air cooled condensers can be used with lower economical penalty. Another advantage is that back pressure steam turbines have a less complex design than condensing steam turbines which make their costs lower. All of these improvements could make the combined cycle unit more cost effective. This unit can be applicable in both parabolic trough and central receiver (solar tower) plants. The potential advantage of the new power block is illustrated by a detailed techno-economical analysis of two 50 MW parabolic trough power plants, comparing between the standard and the novel power block. The results indicate that the proposed plant suggests a 4-11% electricity cost saving

  4. ION PRODUCING MECHANISM (ARC EXTERNAL TO BLOCK)

    DOE Patents [OSTI]

    Brobeck, W.H.

    1958-09-01

    This patent pentains to an ion producing mechanism employed in a calutron which has the decided advantage of an increased amount of ionization effectuated by the arc, and a substantially uniform arc in poiat of time, i arc location and along the arc length. The unique features of the disclosed ion source lie in the specific structural arrangement of the source block, gas ionizing passage, filament shield and filament whereby the arc is established both within the ionizing passage and immediately outside the exit of the ionizing passage at the block face.

  5. Urban Sustainability Water Module

    Energy Science and Technology Software Center (OSTI)

    1998-09-22

    Most urban areas are experiencing substantial growth rate. In order to support the growth and still maintain the high quality of life currently available in these areas, government planners, and developers and general stakeholders are very interested in a product that will allow them to experiment with different development scenarios to determine the best path forward. One of the biggest concerns is the amount of water that will be available as the growth continues. Thismore » software package will allow them as a group to input their ideas and get a visual view of the results, immediately. They will be able to watch the water resources as they are consumed by the increasing growth in residential, commercial and industrial areas.« less

  6. Alternative fuelds in urban fleets

    SciTech Connect (OSTI)

    Lindsay, T.

    1994-12-31

    In this presentation the author addresses four main objectives. They are to: discuss programs that are driving the introduction of alternative fuels into fleet operations in urban areas around the country; define alternative fuels; quantify the present use and future projections on alternative fuel vehicles (AVFs) in the Chicago metropolitan statistical area; and discuss benefits of increased use of alternative fuels in urban areas. Factors which touch on these points include: present domestic dependence on petroleum for autos, with usage exceeding production; the large populations in urban areas which do not meet Clean Air Standards; recent legislative initiatives which give guidance and aid in the adoption of such strategies.

  7. Self-doped microphase separated block copolymer electrolyte

    DOE Patents [OSTI]

    Mayes, Anne M.; Sadoway, Donald R.; Banerjee, Pallab; Soo, Philip; Huang, Biying

    2002-01-01

    A polymer electrolyte includes a self-doped microphase separated block copolymer including at least one ionically conductive block and at least one second block that is immiscible in the ionically conductive block, an anion immobilized on the polymer electrolyte and a cationic species. The ionically conductive block provides a continuous ionically conductive pathway through the electrolyte. The electrolyte may be used as an electrolyte in an electrochemical cell.

  8. Urban Dispersion Program: Urban Measurements Applied to Emergency Response

    SciTech Connect (OSTI)

    Allwine, K Jerry; Clawson, Kirk L.; Flaherty, Julia E.; Heiser, John H.; Hosker, Rayford P.; Leach, Martin J.; stockham, Leo W.

    2007-09-10

    Air motions in and around cities are highly complex, and the increasing threat of harmful releases into urban atmospheres makes advancing the state-of-science of understanding and modeling atmospheric flows and dispersion in and around cities essential. The four-year Urban Dispersion Program (UDP) funded primarily by the U.S. Department of Homeland Security and the Defense Threat Reduction Agency has recently been completed. The program’s primary focus was to conduct tracer and meteorological field studies in Manhattan to improve our understanding of flow and dispersion of airborne contaminants through and around the deep street canyons of New York City, including outdoor-indoor-subway exchange mechanisms. Additionally, urban dispersion models are being validated and first-responder guidance are being refined using data collected during the two UDP field studies. Pacific Northwest National Laboratory led several government laboratories, universities and private companies in conducting the two UDP field studies. The first study was a small-scale study that investigated dispersion in the immediate vicinity of the Madison Square Garden during March 2005 (MSG05), while the second UDP study was an extensive study conducted during August 2005 in Midtown Manhattan (MID05). A brief overview of the UDP field studies will be given followed by a discussion of some limitations of current urban models in simulating dispersion in urban areas. Some first-responder guidance based on findings from recent urban field studies will also be presented.

  9. Community Development Block Grant (CDBG) Program

    Broader source: Energy.gov [DOE]

    This program promotes the development of viable urban communities by providing decent housing, a suitable living environment, and expanded economic opportunities, principally for persons of low and moderate incomes. It provides grantees with the flexibility to plan programs that best meet their unique needs within the program’s broad mission, and these funds can be applied toward solar projects that meet the criteria for the program.

  10. Poly(cyclohexylethylene)-block-poly(ethylene oxide) block polymers for metal oxide templating

    SciTech Connect (OSTI)

    Schulze, Morgan W.; Sinturel, Christophe

    2015-09-01

    A series of poly(cyclohexylethylene)-block-poly(ethylene oxide) (CEO) diblock copolymers were synthesized through tandem anionic polymerizations and heterogeneous catalytic hydrogenation. Solvent-annealed CEO diblock films were used to template dense arrays of inorganic oxide nanodots via simple spin coating of an inorganic precursor solution atop the ordered film. The substantial chemical dissimilarity of the two blocks enables (i) selective inclusion of the inorganic precursor within the PEO domain and (ii) the formation of exceptionally small feature sizes due to a relatively large interaction parameter estimated from mean-field analysis of the order–disorder transition temperatures of compositionally symmetric samples. UV/ozone treatment following incorporation produces an ordered arrangement of oxide nanodots and simultaneously removes the block polymer template. However, we report the smallest particles (6 ± 1 nm) templated from a selective precursor insertion method to date using a block polymer scaffold.

  11. Poly(cyclohexylethylene)-block-poly(ethylene oxide) block polymers for metal oxide templating

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schulze, Morgan W.; Sinturel, Christophe; Hillmyer, Marc A.

    2015-09-01

    A series of poly(cyclohexylethylene)-block-poly(ethylene oxide) (CEO) diblock copolymers were synthesized through tandem anionic polymerizations and heterogeneous catalytic hydrogenation. Solvent-annealed CEO diblock films were used to template dense arrays of inorganic oxide nanodots via simple spin coating of an inorganic precursor solution atop the ordered film. The substantial chemical dissimilarity of the two blocks enables (i) selective inclusion of the inorganic precursor within the PEO domain and (ii) the formation of exceptionally small feature sizes due to a relatively large interaction parameter estimated from mean-field analysis of the order–disorder transition temperatures of compositionally symmetric samples. UV/ozone treatment following incorporation produces anmore » ordered arrangement of oxide nanodots and simultaneously removes the block polymer template. However, we report the smallest particles (6 ± 1 nm) templated from a selective precursor insertion method to date using a block polymer scaffold.« less

  12. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title CA-City-Diamond Bar Location: City Diamond Bar CA American Recovery and Reinvestment Act: Proposed Action or Project Description 1) Install an approximately 50 kW, roof-mounted, solar photovoltaic system on the City Hall Building, 2) public outreach program, 3) signage installation - LED lighting, 4) ITS - signal

  13. A window on urban sustainability

    SciTech Connect (OSTI)

    Stigt, Rien van; Driessen, Peter P.J.; Spit, Tejo J.M.

    2013-09-15

    Sustainable urban development requires the integration of environmental interests in urban planning. Although various methods of environmental assessment have been developed, plan outcomes are often disappointing due to the complex nature of decision-making in urban planning, which takes place in multiple arenas within multiple policy networks involving diverse stakeholders. We argue that the concept of ‘decision windows’ can structure this seemingly chaotic chain of interrelated decisions. First, explicitly considering the dynamics of the decision-making process, we further conceptualized decision windows as moments in an intricate web of substantively connected deliberative processes where issues are reframed within a decision-making arena, and interests may be linked within and across arenas. Adopting this perspective in two case studies, we then explored how decision windows arise, which factors determine their effectiveness and how their occurrence can be influenced so as to arrive at more sustainable solutions. We conclude that the integration of environmental interests in urban planning is highly dependent on the ability of the professionals involved to recognize and manipulate decision windows. Finally, we explore how decision windows may be opened. -- Highlights: • Decision-making about sustainable urban development occurs in networks. • The concept of ‘decision windows’ was further elaborated. • Decision windows help understand how environmental interests enter decision-making. • Decision windows can, to some extent, be influenced.

  14. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-004A ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-004A REVISION: THIS GUIDANCE HAS BEEN AMENDED ...

  15. Indian Community Development Block Grant Program Workshop - Seattle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Indian Community Development Block Grant Program Workshop - Seattle Indian Community Development Block Grant Program Workshop - Seattle May 18, 2016 9:00AM to 3:00PM PDT Seattle, ...

  16. Measurement of the Magnet Blocks for SSRF Insertion Devices

    SciTech Connect (OSTI)

    He Yongzhou; Zhang Jidong; Zhou Qiaogen; Qian Zhenmei; Li Yang

    2010-06-23

    Two in-vacuum undulators IVU25s and one elliptically polarized undulator EPU100 have been developed for SSRF. Two IVU25s with the same hybrid design contain about 640 Sm{sub 2}Co{sub 17} magnet blocks and the dimension of blocks is 65 Wx25 Hx9 D. The EPU100 of the APPLE-II type contains about 690 NdFeB magnet blocks with the dimension of 35 Wx35 Hx25 D. This paper describes the magnetic measurements of these magnet blocks with the Helmholtz coil measurement system for IVU25 magnet blocks and the Hall probe measurement system for EPU100 magnet blocks. The measured maximum magnetic moment deviation and the maximum angle deviation are less than {+-}1.0% and 1.1 deg. respectively both for Sm{sub 2}Co{sub 17} blocks and NdFeB blocks and satisfy the specifications of undulators.

  17. Solvothermal Thin Film Deposition of Electron Blocking Layers | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers

  18. Guidance for Energy Efficiency and Conservation Block Grant Grantees on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Programs | Department of Energy Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs Provides general guidance to the U.S. Department of Energy's Energy Efficiency and Conservation Block Grant grantees on financing programs. Author: U.S. Department of Energy Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs (447.91

  19. Energy Efficiency and Conservation Block Grant Program Success Stories

    Broader source: Energy.gov [DOE]

    Energy Efficiency and Conservation Block Grant (EECBG) Program's success stories including news articles, EERE Successes and EERE Blog entries.

  20. Energy Efficiency and Conservation Block Grant Program Guidance |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » Energy Efficiency and Conservation Block Grant Program Guidance Energy Efficiency and Conservation Block Grant Program Guidance The Energy Efficiency and Conservation Block Grant (EECBG) Program released guidance documents that explain how the recipients of EECBG funds need to report and manage those funds. These documents are listed below by the year they were released. More program guidance documents are

  1. Energy Efficiency and Conservation Block Grant Program Success Stories |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » Energy Efficiency and Conservation Block Grant Program Success Stories Energy Efficiency and Conservation Block Grant Program Success Stories RSS Read Energy Efficiency and Conservation Block Grant Program success stories. August 25, 2014 Pictured here is one of the solar arrays that is providing New Bedford with clean, renewable energy to power its municipally owned buildings. This ground-mounted solar array is

  2. About the Energy Efficiency and Conservation Block Grant Program |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » About the Energy Efficiency and Conservation Block Grant Program About the Energy Efficiency and Conservation Block Grant Program The Energy Efficiency and Conservation Block Grant (EECBG) Program's purpose was to reduce fossil fuel emissions and total energy use and create jobs by working with cities, counties, states, U.S. territories, and Indian tribes to implement and manage energy efficiency and

  3. Energy Efficiency and Conservation Block Grant Program | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Energy Efficiency and Conservation Block Grant Program Energy Efficiency and Conservation Block Grant Program With a grant from the Energy Department's Energy Efficiency and Conservation Block Grant Program, the community of Ocean View, Delaware, installed a carport-mounted solar array that is saving taxpayers money on town utility bills. | Photo courtesy of the Town of Ocean View. With a grant from the Energy Department's Energy Efficiency and Conservation Block Grant Program, the

  4. Organic photosensitive optoelectronic device having a phenanthroline exciton blocking layer

    DOE Patents [OSTI]

    Thompson, Mark E.; Li, Jian; Forrest, Stephen; Rand, Barry

    2011-02-22

    An organic photosensitive optoelectronic device, having an anode, a cathode, and an organic blocking layer between the anode and the cathode is described, wherein the blocking layer comprises a phenanthroline derivative, and at least partially blocks at least one of excitons, electrons, and holes.

  5. Building blocks for correlated superconductors and magnets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarrao, J. L.; Ronning, F.; Bauer, E. D.; Batista, C. D.; Zhu, J. -X.; Thompson, J. D.

    2015-04-01

    Recent efforts at Los Alamos to discover strongly correlated superconductors and hard ferromagnets are reviewed. While serendipity remains a principal engine of materials discovery, design principles and structural building blocks are beginning to emerge that hold potential for predictive discovery. Successes over the last decade with the so-called “115” strongly correlated superconductors are summarized, and more recent efforts to translate these insights and principles to novel hard magnets are discussed. While true “materials by design” remains a distant aspiration, progress is being made in coupling empirical design principles to electronic structure simulation to accelerate and guide materials design and synthesis.

  6. Building blocks for correlated superconductors and magnets

    SciTech Connect (OSTI)

    Sarrao, J. L.; Ronning, F.; Bauer, E. D.; Batista, C. D.; Zhu, J. -X.; Thompson, J. D.

    2015-04-01

    Recent efforts at Los Alamos to discover strongly correlated superconductors and hard ferromagnets are reviewed. While serendipity remains a principal engine of materials discovery, design principles and structural building blocks are beginning to emerge that hold potential for predictive discovery. Successes over the last decade with the so-called 115 strongly correlated superconductors are summarized, and more recent efforts to translate these insights and principles to novel hard magnets are discussed. While true materials by design remains a distant aspiration, progress is being made in coupling empirical design principles to electronic structure simulation to accelerate and guide materials design and synthesis.

  7. A reciprocating rotating-block engine

    SciTech Connect (OSTI)

    O`Connor, L.

    1995-06-01

    This article describes the Newbold power plant, a lightweight, clean burning, and efficient engine that is designed to be used in a variety of small-engine applications, from ultralight planes to wheelchairs. A new turbo rotary-power engine brings together different design concepts from engine technology, including the rotary motion of a block, which is applied in a rotary engine, and the reciprocating motion of pistons. The new power plant also uses an air delivery system that operates similar to a turbojet engine. The turbo rotary-power engine, developed by Vernon Newbold, founder of Newbold and Associates, in Lyons, CO, produces power from the heat generated by combustion of most liquid or gaseous fuels. Production engines, expected to be built in August, will be optimized to operate using diesel fuel.

  8. Organic photovoltaic cell incorporating electron conducting exciton blocking layers

    SciTech Connect (OSTI)

    Forrest, Stephen R.; Lassiter, Brian E.

    2014-08-26

    The present disclosure relates to photosensitive optoelectronic devices including a compound blocking layer located between an acceptor material and a cathode, the compound blocking layer including: at least one electron conducting material, and at least one wide-gap electron conducting exciton blocking layer. For example, 3,4,9,10 perylenetetracarboxylic bisbenzimidazole (PTCBI) and 1,4,5,8-napthalene-tetracarboxylic-dianhydride (NTCDA) function as electron conducting and exciton blocking layers when interposed between the acceptor layer and cathode. Both materials serve as efficient electron conductors, leading to a fill factor as high as 0.70. By using an NTCDA/PTCBI compound blocking layer structure increased power conversion efficiency is achieved, compared to an analogous device using a conventional blocking layers shown to conduct electrons via damage-induced midgap states.

  9. Poly(lactide)-block-poly([epsilon]-caprolactone-co-[epsilon]-decalactone)-block-poly(lactide) copolymer elastomers

    SciTech Connect (OSTI)

    Schneiderman, Deborah K.; Hill, Erin M.; Martello, Mark T.; Hillmyer, Marc A.

    2015-08-28

    Batch ring opening transesterification copolymerization of ?-caprolactone and ?-decalactone was used to generate statistical copolymers over a wide range of compositions and molar masses. Reactivity ratios determined for this monomer pair, rCL = 5.9 and rDL = 0.03, reveal ?-caprolactone is added preferentially regardless of the propagating chain end. Relative to poly(?-caprolactone) the crystallinity and melting point of these statistical copolymers were depressed by the addition of ?-decalactone; copolymers containing greater than 31 mol% (46 wt%) ?-decalactone were amorphous. Poly(lactide)-block-poly(?-caprolactone-co-?-decalactone)-block-poly(lactide) triblock polymers were also prepared and used to explore the influence of midblock composition on the temperature dependent Flory-Huggins interaction parameter (?). In addition, uniaxial extension tests were used to determine the effects of midblock composition, poly(lactide) content, and molar mass on the mechanical properties of these new elastomeric triblocks.

  10. Update on Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Allocations | Department of Energy Update on Energy Efficiency and Conservation Block Grant Program Allocations Update on Energy Efficiency and Conservation Block Grant Program Allocations April 10, 2009 - 12:00am Addthis After a review of eligibility criteria for the Department of Energy's Energy Efficiency and Conservation Block Grant Program, $16,429,000 in additional funding will go to 23 counties in Delaware, Kansas, and Louisiana to support energy efficiency projects. Delaware counties

  11. Block copolymer adhesion promoters via ring-opening metathesis polymerization

    DOE Patents [OSTI]

    Kent, Michael S.; Saunders, Randall

    1997-01-01

    Coupling agents based on functionalized block copolymers for bonding thermoset polymers to solid materials. These are polymers which possess at least two types of functional groups, one which is able to attach to and react with solid surfaces, and another which can react with a thermoset resin, which are incorporated as pendant groups in monomers distributed in blocks (typically two) along the backbone of the chain. The block copolymers in this invention are synthesized by living ring-opening metathesis polymerization.

  12. Guidance For Energy Efficiency And Conservation Block Grant Grantees On

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Programs | Department of Energy For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs U.S. Department of Energy (DOE) Weatherization and Intergovernmental Program (WIP) Energy Efficiency and Conservation Block Grant (EECBG) Program Notice 09-002D modified October 17, 2012 that provides guidance about financing programs for state and local governments, overseas U.S.

  13. Guidance for Energy Efficiency and Conservation Block Grant Recipients on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Evaluation Guidelines | Department of Energy for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency and Conservation Block Grant Program grantees on planning and conducting program evaluations on Recovery Act funded EECBG programs and activities eecbg_evaluation_guidelines_10_017.pdf (184.79 KB) More Documents

  14. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. | Department of Energy GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. This document provides guidance for energy efficiency and block grant recipients on closeout procedures for non-state energy office recipients.

  15. State Energy Program and Energy Efficiency and Conservation Block Grant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Guidance 13-001: Guidance for Returning Interest Earned | Department of Energy and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned State Energy Program and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned U.S. Department of Energy (DOE) State Energy Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program guidance document for returning

  16. Energy Efficiency and Conservation Block Grant Financing Program Guidance |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy Efficiency and Conservation Block Grant financing programs is provided below in the Grantee Letter and supporting appendices listed here. Appendix 1: EECBG Financing Program Annual Report (372.67 KB) Appendix 2: EECBG Program Notice 09-002D Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs, revised October 17, 2012

  17. Energy Efficiency and Consveration Block Grant Program National Evaluation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet | Department of Energy and Consveration Block Grant Program National Evaluation Fact Sheet Energy Efficiency and Consveration Block Grant Program National Evaluation Fact Sheet This fact sheet provides summarized results of the National Evaluation of the Energy Efficiency and Conservation Block Grant Program, a national program funded one-time under the American Recovery and Reinvestment Act of 2009. Fact Sheet (477.88 KB) More Documents & Publications Energy Efficiency and

  18. Energy Efficiency and Conservation Block Grant Financing Programs After

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grant Retirement | Department of Energy Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement July 15, 2014 - 12:12pm Addthis The information below will help you manage successful Energy Efficiency and Conservation Block Grant (EECBG) financing programs: July 2014 Letter to EECBG Financing Program Managers. This document: Clarifies DOE's ongoing role in monitoring,

  19. NREL: Concentrating Solar Power Research - Power Block R&D

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power block research at NREL focuses on assessing the potential of advanced power cycles to integrate with concentrating solar power (CSP) systems. This research increases the ...

  20. Guidance for Energy Efficiency and Conservation Block Grant Recipients...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency ...

  1. Energy.gov Content Management System Block Types

    Broader source: Energy.gov [DOE]

    For Office of Energy Efficiency and Renewable Energy (EERE) websites, learn about the variety of block types available in the Energy.gov Drupal content management system (CMS).

  2. State Energy Program and Energy Efficiency and Conservation Block...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program guidance document for returning interest earned; Program year 2013. PDF icon sepeecbg13001...

  3. Microsoft Word - Final Dec 4 Annncmnt of Agg Blocks Adjustmnt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aggregate Blocks and Prepayments BPA will Accept for Prepayment Program, the Adjustment Cap, Market Clearing Purchase Price, and Reservation Price Background Pursuant to Paragraph...

  4. Structural response of a prealigned cylindrical block copolymer...

    Office of Scientific and Technical Information (OSTI)

    melt to extensional flow Citation Details In-Document Search Title: Structural response of a prealigned cylindrical block copolymer melt to extensional flow Authors: McCready, ...

  5. Net Requirements Transparency Process for Slice/Block Customers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2012 Net Requirements Transparency Process for SliceBlock Customers Description of Changes and a Response to Comments September 24, 2012 Background and Description of Changes:...

  6. Energy Efficiency and Conservation Block Grant Program Success...

    Broader source: Energy.gov (indexed) [DOE]

    RSS Read Energy Efficiency and Conservation Block Grant Program success stories. August ... New Bedford with clean, renewable energy to power its municipally owned buildings. ...

  7. Crystal Engineering on Superpolyhedral Building Blocks in Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Superpolyhedral Building Blocks in Metal-Organic Frameworks Applied in Gas Adsorption. Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 71, 613-618 (2015). DOI:...

  8. City of Los Angeles  Energy Efficiency and Conservation Block...

    Office of Environmental Management (EM)

    City of Los Angeles - Energy Efficiency and Conservation Block Grant Program Funds Provided by the ... use of faulty data in its compilation of Recovery Act job statistics. ...

  9. County of Los Angeles Energy Efficiency and Conservation Block...

    Broader source: Energy.gov (indexed) [DOE]

    County of Los Angeles - Energy Efficiency and Conservation Block Grant Program Funds Provided by the ... utilized by the Department in its compilation of Recovery Act job statistics. ...

  10. Association of a Multifunctional Ionic Block Copolymer in a Selective...

    Office of Scientific and Technical Information (OSTI)

    Results Journal Article: Association of a Multifunctional Ionic Block Copolymer in a Selective Solvent. Citation Details ... Publication Date: 2014-04-01 OSTI Identifier: 1143261 Report ...

  11. Germanium blocked impurity band infrared detectors

    SciTech Connect (OSTI)

    Rossington, C.S.; Haller, E.E.

    1988-08-01

    Germanium blocked impurity band (BIB) photoconductors have been fabricated and characterized for responsivity, dark current, and noise equivalent power. BIB photoconductors theoretically provide an extension of the spectral response, a reduction in sensitivity to cosmic radiation and a reduction in noise characteristics compared with conventional photoconductors. Silicon BIB detectors have been successfully developed by researchers at Rockwell International, which do indeed meet their theoretical potential. In the proper configuration, these same Si BIB detectors are capable of continuous detection of individual photons in the wavelength range from 0.4 to 28 ..mu..m. Until the BIB concept was developed, detection of individual photons was only possible with photomultiplier tubes which detected visible light. Due to the successes of the Si BIB detectors, it seemed natural to extend this concept to Ge detectors, which would then allow an extension of the spectral response over conventional Ge detectors from /approximately/100 ..mu..m to /approximately/200 ..mu..m. 8 refs., 2 figs.

  12. Molecular origin of photovoltaic performance in donor-block-acceptor all-conjugated block copolymers

    SciTech Connect (OSTI)

    Smith, Kendall A.; Lin, Yen -Hao; Mok, Jorge W.; Yager, Kevin G.; Strzalka, Joseph; Nie, Wanyi; Mohite, Aditya D.; Verduzco, Rafael

    2015-11-03

    All-conjugated block copolymers may be an effective route to self-assembled photovoltaic devices, but we lack basic information on the relationship between molecular characteristics and photovoltaic performance. Here, we synthesize a library of poly(3-hexylthiophene) (P3HT) block poly((9,9-dialkylfluorene)-2,7-diyl-alt-[4,7-bis(alkylthiophen-5-yl)-2,1,3-benzothiadiazole]-2',2''-diyl) (PFTBT) donor-block-acceptor all-conjugated block copolymers and carry out a comprehensive study of processing conditions, crystallinity, domain sizes, and side-chain structure on photovoltaic device performance. We find that all block copolymers studied exhibit an out-of-plane crystal orientation after deposition, and on thermal annealing at high temperatures the crystal orientation flips to an in-plane orientation. By varying processing conditions on polymer photovoltaic devices, we show that the crystal orientation has only a modest effect (15-20%) on photovoltaic performance. The addition of side-chains to the PFTBT block is found to decrease photovoltaic power conversion efficiencies by at least an order of magnitude. Through grazing-incidence X-ray measurements we find that the addition of side-chains to the PFTBT acceptor block results in weak segregation and small (< 10 nm) block copolymer self-assembled donor and acceptor domains. This work is the most comprehensive to date on all-conjugated block copolymer systems and suggests that photovoltaic performance of block copolymers depends strongly on the miscibility of donor and acceptor blocks, which impacts donor and acceptor domain sizes and purity. Lastly, strategies for improving the device performance of block copolymer photovoltaics should seek to increase segregation between donor and acceptor polymer domains.

  13. Urban Electric Vehicle (UEV) Technical Specifications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an independent assessment of urban electric vehicles (UEV), designed specifically for use ...inverter shall control the minimum traction battery discharge voltage to prevent ...

  14. Automatic Blocking Of QR and LU Factorizations for Locality

    SciTech Connect (OSTI)

    Yi, Q; Kennedy, K; You, H; Seymour, K; Dongarra, J

    2004-03-26

    QR and LU factorizations for dense matrices are important linear algebra computations that are widely used in scientific applications. To efficiently perform these computations on modern computers, the factorization algorithms need to be blocked when operating on large matrices to effectively exploit the deep cache hierarchy prevalent in today's computer memory systems. Because both QR (based on Householder transformations) and LU factorization algorithms contain complex loop structures, few compilers can fully automate the blocking of these algorithms. Though linear algebra libraries such as LAPACK provides manually blocked implementations of these algorithms, by automatically generating blocked versions of the computations, more benefit can be gained such as automatic adaptation of different blocking strategies. This paper demonstrates how to apply an aggressive loop transformation technique, dependence hoisting, to produce efficient blockings for both QR and LU with partial pivoting. We present different blocking strategies that can be generated by our optimizer and compare the performance of auto-blocked versions with manually tuned versions in LAPACK, both using reference BLAS, ATLAS BLAS and native BLAS specially tuned for the underlying machine architectures.

  15. Modeling Mechanical Behavior of a Prismatic Replaceable Reflector Block

    SciTech Connect (OSTI)

    Robert Bratton

    2009-04-01

    This report outlines the development of finite element models used to determine temperature and stresses in a prismatic core reflector block. This initial analysis determines an appropriate temperature distribution in a prismatic reflector from limiting conditions in the adjacent fuel block based on simplifying assumptions.

  16. Light-emitting block copolymers composition, process and use

    DOE Patents [OSTI]

    Ferraris, John P.; Gutierrez, Jose J.

    2006-11-14

    Generally, and in one form, the present invention is a composition of light-emitting block copolymer. In another form, the present invention is a process producing a light-emitting block copolymers that intends polymerizing a first di(halo-methyl) aromatic monomer compound in the presence of an anionic initiator and a base to form a polymer and contacting a second di(halo-methyl) aromatic monomer compound with the polymer to form a homopolymer or block copolymer wherein the block copolymer is a diblock, triblock, or star polymer. In yet another form, the present invention is an electroluminescent device comprising a light-emitting block copolymer, wherein the electroluminescent device is to be used in the manufacturing of optical and electrical devices.

  17. NANOSTRUCTURED METAL OXIDE CATALYSTS VIA BUILDING BLOCK SYNTHESES

    SciTech Connect (OSTI)

    Craig E. Barnes

    2013-03-05

    A broadly applicable methodology has been developed to prepare new single site catalysts on silica supports. This methodology requires of three critical components: a rigid building block that will be the main structural and compositional component of the support matrix; a family of linking reagents that will be used to insert active metals into the matrix as well as cross link building blocks into a three dimensional matrix; and a clean coupling reaction that will connect building blocks and linking agents together in a controlled fashion. The final piece of conceptual strategy at the center of this methodology involves dosing the building block with known amounts of linking agents so that the targeted connectivity of a linking center to surrounding building blocks is obtained. Achieving targeted connectivities around catalytically active metals in these building block matrices is a critical element of the strategy by which single site catalysts are obtained. This methodology has been demonstrated with a model system involving only silicon and then with two metal-containing systems (titanium and vanadium). The effect that connectivity has on the reactivity of atomically dispersed titanium sites in silica building block matrices has been investigated in the selective oxidation of phenols to benezoquinones. 2-connected titanium sites are found to be five times as active (i.e. initial turnover frequencies) than 4-connected titanium sites (i.e. framework titanium sites).

  18. Urban Surfaces and Heat Island Mitigation Potentials (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Urban Surfaces and Heat Island Mitigation Potentials Citation Details ... and urban vegetation (trees, grass, shrubs) on the meteorology and air quality of a city. ...

  19. Evaluating Exhaust Emission Performance of Urban Buses Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis ...

  20. AVTA: Urban Electric Vehicle Specifications and Test Procedures...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Urban Electric Vehicle Specifications and Test Procedures AVTA: Urban Electric Vehicle Specifications and Test Procedures UEVAmerica Specifications (252.08 KB) ETA-UTP001 ...

  1. GIZ Sourcebook Module 5h: Urban Transport and Energy Efficiency...

    Open Energy Info (EERE)

    h: Urban Transport and Energy Efficiency Jump to: navigation, search Tool Summary LAUNCH TOOL Name: GIZ Sourcebook Module 5h: Urban Transport and Energy Efficiency AgencyCompany...

  2. Energy Department Announces the SUN Project, Empowering Urban...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Department Announces the SUN Project, Empowering Urban Native Youth in STEM Education Energy Department Announces the SUN Project, Empowering Urban Native Youth in STEM ...

  3. Model for Sustainable Urban Design With Expanded Sections on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Model for Sustainable Urban Design With Expanded Sections on Distributed Energy Resources, February 2004 Model for Sustainable Urban Design With Expanded Sections on Distributed ...

  4. The Sourcebook on Sustainable Urban Transport | Open Energy Informatio...

    Open Energy Info (EERE)

    Sourcebook on Sustainable Urban Transport Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Sourcebook on Sustainable Urban Transport AgencyCompany Organization: GIZ...

  5. South Africa-Promoting Low Emission Urban Development Strategies...

    Open Energy Info (EERE)

    search Name South Africa-Promoting Low Emission Urban Development Strategies in Emerging Economy Countries (URBAN-LEDS) AgencyCompany Organization ICLEI - Local Governments for...

  6. GIZ Sourcebook Module 5f: Adapting Urban Transport to Climate...

    Open Energy Info (EERE)

    f: Adapting Urban Transport to Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: GIZ Sourcebook Module 5f: Adapting Urban Transport to Climate Change...

  7. Reclamation of urban stormwater. Book chapter

    SciTech Connect (OSTI)

    Field, R.

    1993-01-01

    Rainfall runoff becomes contaminated as it passes over urban land. Billions of gallons of water can be recovered for beneficial uses if urban stormwater is properly controlled and treated. The Storm and Combined Sewer Program of the United States Environmental Protection Agency Office of Research and Development has continuously supported the development and demonstration of stormwater control systems and treatment processes. Water quality of the treated storm runoff can meet the required standards for subpotable usage. Current urban stormwater control and treatment technology are discussed, leading to the feasibility of urban stormwater reuse for various purposes in industry, irrigation and recreation. A hypothetical case study illustrating the cost effectiveness of reclaiming urban stormwater for complete industrial supply is presented.

  8. Block copolymer adhesion promoters via ring-opening metathesis polymerization

    DOE Patents [OSTI]

    Kent, M.S.; Saunders, R.

    1997-02-18

    Coupling agents are disclosed based on functionalized block copolymers for bonding thermoset polymers to solid materials. These are polymers which possess at least two types of functional groups, one which is able to attach to and react with solid surfaces, and another which can react with a thermoset resin, which are incorporated as pendant groups in monomers distributed in blocks (typically two) along the backbone of the chain. The block copolymers in this invention are synthesized by living ring-opening metathesis polymerization. 18 figs.

  9. Model for Sustainable Urban Design With Expanded Sections on Distributed Energy Resources, February 2004

    Office of Energy Efficiency and Renewable Energy (EERE)

    Document describing a model design for urban development and redevelopment that will reduce urban energy consumption

  10. Bulk Vitrification Castable Refractory Block Protection Study

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Beck, Andrew E.; Brouns, Thomas M.; Caldwell, Dustin D.; Elliott, Michael L.; Matyas, Josef; Minister, Kevin BC; Schweiger, Michael J.; Strachan, Denis M.; Tinsley, Bronnie P.; Hollenberg, Glenn W.

    2005-05-01

    Bulk vitrification (BV) was selected for a pilot-scale test and demonstration facility for supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the Hanford U.S. DOE Site. During engineering-scale (ES) tests, a small fraction of radioactive Tc (and Re, its nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the castable refractory block (CRB). Laboratory experiments were undertaken to understand the mechanisms of the transport Tc/Re into the CRB during vitrification and to evaluate various means of CRB protection against the deposition of leachable Tc/Re. The tests used Re as a chemical surrogate for Tc. The tests with the baseline CRB showed that the molten LAW penetrates into CRB pores before it converts to glass, leaving deposits of sulfates and chlorides when the nitrate components decompose. Na2O from the LAW reacts with the CRB to create a durable glass phase that may contain Tc/Re. Limited data from a single CRB sample taken from an ES experiment indicate that, while a fraction of Tc/Re is present in the CRB in a readily leachable form, most of the Tc/Re deposited in the refractory is retained in the form of a durable glass phase. In addition, the molten salts from the LAW, mainly sulfates, chlorides, and nitrates, begin to evaporate from BV feeds at temperatures below 800 C and condense on solid surfaces at temperatures below 530 C. Three approaches aimed at reducing or preventing the deposition of soluble Tc/Re within the CRB were proposed: metal lining, sealing the CRB surface with a glaze, and lining the CRB with ceramic tiles. Metal liners were deemed unsuitable because evaluations showed that they can cause unacceptable distortions of the electric field in the BV system. Sodium silicate and a low-alkali borosilicate glaze were selected for testing. The glazes slowed down molten salt condensate penetration, but did little to reduce the

  11. Reordering transitions during annealing of block copolymer cylinder phases

    SciTech Connect (OSTI)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-10-06

    While equilibrium block-copolymer morphologies are dictated by energy-minimization effects, the semi-ordered states observed experimentally often depend on the details of ordering pathways and kinetics. In this study, we explore reordering transitions in thin films of block-copolymer cylinder-forming polystyrene-block-poly(methyl methacrylate). We observe several transient states as films order towards horizontally-aligned cylinders. In particular, there is an early-stage reorganization from randomly-packed cylinders into hexagonally-packed vertically-aligned cylinders; followed by a reorientation transition from vertical to horizontal cylinder states. These transitions are thermally activated. The growth of horizontal grains within an otherwise vertical morphology proceeds anisotropically, resulting in anisotropic grains in the final horizontal state. The size, shape, and anisotropy of grains are influenced by ordering history; for instance, faster heating rates reduce grain anisotropy. These results help elucidate aspects of pathway-dependent ordering in block-copolymer thin films.

  12. Square Grains in Asymmetric Rod-Coil Block Copolymers (Journal...

    Office of Scientific and Technical Information (OSTI)

    Unlike the rounded grains that are well known to form in most soft materials, square grains of microphase-separated lamellae are observed in thin films of a rod-coil block ...

  13. Virasoro conformal blocks and thermality from classical background fields

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.

    2015-11-30

    We show that in 2d CFTs at large central charge, the coupling of the stress tensor to heavy operators can be re-absorbed by placing the CFT in a non-trivial background metric. This leads to a more precise computation of the Virasoro conformal blocks between heavy and light operators, which are shown to be equivalent to global conformal blocks evaluated in the new background. We also generalize to the case where the operators carry U(1) charges. The refined Virasoro blocks can be used as the seed for a new Virasoro block recursion relation expanded in the heavy-light limit. Furthermore, we commentmore » on the implications of our results for the universality of black hole thermality in AdS3 , or equivalently, the eigenstate thermalization hypothesis for CFT2 at large central charge.« less

  14. Energy Efficiency and Conservation Block Grant Program Success...

    Broader source: Energy.gov (indexed) [DOE]

    like this will grace Gabe Nesbitt Community Park in McKinney, Texas, thanks to an Energy Efficiency and Conservation Block Grant | Photo courtesy of McKinney, Texas EECBG...

  15. Microsoft Word - Posted DSI Amendment of Alcoa Block Power Sales...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No. 1 Contract No. 06PB-11744 DRAFT AMENDMENT executed by the BONNEVILLE POWER ADMINISTRATION and ALCOA INC. This AMENDMENT to the BLOCK POWER SALES AGREEMENT is executed by the...

  16. Big Questions: The Ultimate Building Blocks of Matter

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07

    The Standard Model of particle physics treats quarks and leptons as having no size at all. Quarks are found inside protons and neutrons and the most familiar lepton is the electron. While the best measurements to date support that idea, there is circumstantial evidence that suggests that perhaps the these tiny particles might be composed of even smaller building blocks. This video explains this circumstantial evidence and introduces some very basic ideas of what those building blocks might be.

  17. Lower Cost, Nanoporous Block Copolymer Battery Separator - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Lower Cost, Nanoporous Block Copolymer Battery Separator Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication A.K. Jha, S.L. Tsang, A.E. Ozcam, R.D. Offeman, N.P. Balsara. "Master Curve Captures the Effect of Domain Morphology on Ethanol Pervaporation Through Block Copolymer Membranes," Journal of Membrane Science, published online, 2011. (695 KB) Technology Marketing Summary Although the polyolefin polymer

  18. Energy Efficiency and Conservation Block Grant Financing Program Guidance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grantee Letter | Department of Energy Guidance Grantee Letter Energy Efficiency and Conservation Block Grant Financing Program Guidance Grantee Letter This document clarifies the U.S. Department of Energy's ongoing role in the monitoring, reporting, and oversight of Energy Efficiency and Conservation Block Grant-funded financing programs, including Revolving Loan Funds, Loan Loss Reserves, and Interest Rate Buydowns. July 2014 Letter to EECGB Financing Program Managers (256.42 KB) More

  19. Frequently Asked Questions on Energy Efficiency and Conservation Block

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grant Financing Program Compliance and Reporting | Department of Energy Frequently Asked Questions on Energy Efficiency and Conservation Block Grant Financing Program Compliance and Reporting Frequently Asked Questions on Energy Efficiency and Conservation Block Grant Financing Program Compliance and Reporting Find answers to frequently asked questions (FAQs) regarding financing program reporting and compliance for programs developed using U.S. Department of Energy (DOE) Energy Efficiency

  20. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Wednesday, 27 January 2010 00:00 Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the

  1. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print Wednesday, 30 May 2012 00:00 In principle, tri-block copolymers...

  2. Urban Decontamination Experience at Pripyat Ukraine - 13526

    SciTech Connect (OSTI)

    Paskevych, Sergiy; Voropay, Dmitry; Schmieman, Eric

    2013-07-01

    This paper describes the efficiency of radioactive decontamination activities of the urban landscape in the town of Pripyat, Ukraine. Different methods of treatment for various urban infrastructure and different radioactive contaminants are assessed. Long term changes in the radiation condition of decontaminated urban landscapes are evaluated: 1. Decontamination of the urban system requires the simultaneous application of multiple methods including mechanical, chemical, and biological. 2. If a large area has been contaminated, decontamination of local areas of a temporary nature. Over time, there is a repeated contamination of these sites due to wind transport from neighboring areas. 3. Involvement of earth-moving equipment and removal of top soil by industrial method achieves 20-fold reduction in the level of contamination by radioactive substances, but it leads to large amounts of waste (up to 1500 tons per hectare), and leads to the re-contamination of treated areas due to scatter when loading, transport pollutants on the wheels of vehicles, etc.. (authors)

  3. Water resources and the urban environment

    SciTech Connect (OSTI)

    Loucks, E.D.

    1998-07-01

    140 abstracts from the conference cover topics such as urban stormwater management; geographic information systems, hydrologic and hydraulic computer modeling; groundwater analysis and management; drinking water supply and quality; and international water resources issues.

  4. Department of Energy Awards $300,000 Block Grant to the Rocky...

    Broader source: Energy.gov (indexed) [DOE]

    Block Grant to the Rocky Flats Community Reuse Organization Department of Energy Awards 300,000 Block Grant to the Rocky Flats Community Reuse Organization More Documents &...

  5. Tobacco mosaic virus: A biological building block for micro/nano...

    Office of Scientific and Technical Information (OSTI)

    Tobacco mosaic virus: A biological building block for micronanobio systems Citation Details In-Document Search Title: Tobacco mosaic virus: A biological building block for micro...

  6. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M. E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C. E-mail: christian.bonten@ikt.uni-stuttgart.de

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  7. Electrically conductive doped block copolymer of polyacetylene and polyisoprene

    DOE Patents [OSTI]

    Aldissi, Mahmoud

    1985-01-01

    An electrically conductive block copolymer of polyisoprene and polyacetyl and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I.sub.2 to give it an electrical conductivity in the metallic regime.

  8. Lignin-blocking treatment of biomass and uses thereof

    DOE Patents [OSTI]

    Yang, Bin; Wyman, Charles E.

    2009-10-20

    Disclosed is a method for converting cellulose in a lignocellulosic biomass. The method provides for a lignin-blocking polypeptide and/or protein treatment of high lignin solids. The treatment enhances cellulase availability in cellulose conversion. Cellulase efficiencies are improved by the protein or polypeptide treatment. The treatment may be used in combination with steam explosion and acid prehydrolysis techniques. Hydrolysis yields from lignin containing biomass are enhanced 5-20%, and enzyme utilization is increased from 10% to 50%. Thus, a more efficient and economical method of processing lignin containing biomass materials utilizes a polypeptide/protein treatment step that effectively blocks lignin binding of cellulase.

  9. Solar hydrogen for urban trucks

    SciTech Connect (OSTI)

    Provenzano, J.: Scott, P.B.; Zweig, R.

    1997-12-31

    The Clean Air Now (CAN) Solar Hydrogen Project, located at Xerox Corp., El Segundo, California, includes solar photovoltaic powered hydrogen generation, compression, storage and end use. Three modified Ford Ranger trucks use the hydrogen fuel. The stand-alone electrolyzer and hydrogen dispensing system are solely powered by a photovoltaic array. A variable frequency DC-AC converter steps up the voltage to drive the 15 horsepower compressor motor. On site storage is available for up to 14,000 standard cubic feet (SCF) of solar hydrogen, and up to 80,000 SCF of commercial hydrogen. The project is 3 miles from Los Angeles International airport. The engine conversions are bored to 2.9 liter displacement and are supercharged. Performance is similar to that of the Ranger gasoline powered truck. Fuel is stored in carbon composite tanks (just behind the driver`s cab) at pressures up to 3600 psi. Truck range is 144 miles, given 3600 psi of hydrogen. The engine operates in lean burn mode, with nil CO and HC emissions. NO{sub x} emissions vary with load and rpm in the range from 10 to 100 ppm, yielding total emissions at a small fraction of the ULEV standard. Two trucks have been converted for the Xerox fleet, and one for the City of West Hollywood. A public outreach program, done in conjunction with the local public schools and the Department of Energy, introduces the local public to the advantages of hydrogen fuel technologies. The Clean Air Now program demonstrates that hydrogen powered fleet development is an appropriate, safe, and effective strategy for improvement of urban air quality, energy security and avoidance of global warming impact. Continued technology development and cost reduction promises to make such implementation market competitive.

  10. Reordering transitions during annealing of block copolymer cylinder phases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-10-06

    While equilibrium block-copolymer morphologies are dictated by energy-minimization effects, the semi-ordered states observed experimentally often depend on the details of ordering pathways and kinetics. In this study, we explore reordering transitions in thin films of block-copolymer cylinder-forming polystyrene-block-poly(methyl methacrylate). We observe several transient states as films order towards horizontally-aligned cylinders. In particular, there is an early-stage reorganization from randomly-packed cylinders into hexagonally-packed vertically-aligned cylinders; followed by a reorientation transition from vertical to horizontal cylinder states. These transitions are thermally activated. The growth of horizontal grains within an otherwise vertical morphology proceeds anisotropically, resulting in anisotropic grains in the final horizontalmore » state. The size, shape, and anisotropy of grains are influenced by ordering history; for instance, faster heating rates reduce grain anisotropy. These results help elucidate aspects of pathway-dependent ordering in block-copolymer thin films.« less

  11. Energy Efficiency and Conservation Block Grant Program Fact Sheet

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s (DOE) Energy Efficiency and Conservation Block Grant (EECBG) program represents a Presidential priority to invest in the cheapest, cleanest and most reliable energy technologies we have – energy efficiency and conservation – which can be deployed immediately.

  12. Improving the environment in urban areas

    SciTech Connect (OSTI)

    Adamkus, V.V.

    1994-12-31

    The author discusses the need for improvements to the environment in urban areas, and efforts being made under the direction of the Environmental Protection Agency (EPA) to address these problems. The impact the new Clean Air Act can have on emissions from gasoline powered autos, diesel burning trucks, fixed emission sources ranging from utilities to chemical plants, and consumer products like hair sprays and charcoal starters, will all work together to improve air quality in urban areas. The author also discusses Brownfields Economic Redevelopment Plan efforts being supported by the EPA in a coordinated plan to get municipalities involved in cleaning up areas with pollution, to remove the blight on the urban areas, provide new land for development, and promote additional jobs.

  13. Lakeside: Merging Urban Design with Scientific Analysis

    SciTech Connect (OSTI)

    Guzowski, Leah; Catlett, Charlie; Woodbury, Ed

    2014-10-08

    Researchers at the U.S. Department of Energy's Argonne National Laboratory and the University of Chicago are developing tools that merge urban design with scientific analysis to improve the decision-making process associated with large-scale urban developments. One such tool, called LakeSim, has been prototyped with an initial focus on consumer-driven energy and transportation demand, through a partnership with the Chicago-based architectural and engineering design firm Skidmore, Owings & Merrill, Clean Energy Trust and developer McCaffery Interests. LakeSim began with the need to answer practical questions about urban design and planning, requiring a better understanding about the long-term impact of design decisions on energy and transportation demand for a 600-acre development project on Chicago's South Side - the Chicago Lakeside Development project.

  14. Lakeside: Merging Urban Design with Scientific Analysis

    ScienceCinema (OSTI)

    Guzowski, Leah; Catlett, Charlie; Woodbury, Ed

    2014-11-18

    Researchers at the U.S. Department of Energy's Argonne National Laboratory and the University of Chicago are developing tools that merge urban design with scientific analysis to improve the decision-making process associated with large-scale urban developments. One such tool, called LakeSim, has been prototyped with an initial focus on consumer-driven energy and transportation demand, through a partnership with the Chicago-based architectural and engineering design firm Skidmore, Owings & Merrill, Clean Energy Trust and developer McCaffery Interests. LakeSim began with the need to answer practical questions about urban design and planning, requiring a better understanding about the long-term impact of design decisions on energy and transportation demand for a 600-acre development project on Chicago's South Side - the Chicago Lakeside Development project.

  15. Manipulating Interfaces through Surface Confinement of Poly(glycidyl methacrylate)-block-poly(vinyldimethylazlactone), a Dually Reactive Block Copolymer

    SciTech Connect (OSTI)

    Lokitz, Bradley S; Wei, Jifeng; Hinestrosa Salazar, Juan P; Ivanov, Ilia N; Browning, James B; Ankner, John Francis; Kilbey, II, S Michael; Messman, Jamie M

    2012-01-01

    The assembly of dually reactive, well-defined diblock copolymers incorporating the chemoselective/functional monomer, 4,4-dimethyl-2-vinylazlactone (VDMA) and the surface-reactive monomer glycidyl methacrylate (GMA) is examined to understand how competition between surface attachment and microphase segregation influences interfacial structure. Reaction of the PGMA block with surface hydroxyl groups not only anchors the copolymer to the surface, but limits chain mobility, creating brush-like structures comprising PVDMA blocks, which contain reactive azlactone groups. The block copolymers are spin coated at various solution concentrations and annealed at elevated temperature to optimize film deposition to achieve a molecularly uniform layer. The thickness and structure of the polymer thin films are investigated by ellipsometry, infrared spectroscopy, and neutron reflectometry. The results show that deposition of PGMA-b-PVDMA provides a useful route to control film thickness while preserving azlactone groups that can be further modified with biotin-poly(ethylene glycol)amine to generate designer surfaces. The method described herein offers guidance for creating highly functional surfaces, films, or coatings through the use of dually reactive block copolymers and postpolymerization modification.

  16. Swarm Intelligence for Urban Dynamics Modelling

    SciTech Connect (OSTI)

    Ghnemat, Rawan; Bertelle, Cyrille; Duchamp, Gerard H. E.

    2009-04-16

    In this paper, we propose swarm intelligence algorithms to deal with dynamical and spatial organization emergence. The goal is to model and simulate the developement of spatial centers using multi-criteria. We combine a decentralized approach based on emergent clustering mixed with spatial constraints or attractions. We propose an extension of the ant nest building algorithm with multi-center and adaptive process. Typically, this model is suitable to analyse and simulate urban dynamics like gentrification or the dynamics of the cultural equipment in urban area.

  17. Method of forming oriented block copolymer line patterns, block copolymer line patterns formed thereby, and their use to form patterned articles

    DOE Patents [OSTI]

    Russell, Thomas P.; Hong, Sung Woo; Lee, Doug Hyun; Park, Soojin; Xu, Ting

    2015-10-13

    A block copolymer film having a line pattern with a high degree of long-range order is formed by a method that includes forming a block copolymer film on a substrate surface with parallel facets, and annealing the block copolymer film to form an annealed block copolymer film having linear microdomains parallel to the substrate surface and orthogonal to the parallel facets of the substrate. The line-patterned block copolymer films are useful for the fabrication of magnetic storage media, polarizing devices, and arrays of nanowires.

  18. Urban runoff and combined sewer overflow. [Wastewater treatment

    SciTech Connect (OSTI)

    Moffa, P.E.; Freedman, S.D.; Owens, E.M.; Field, R.; Cibik, C.

    1982-06-01

    The control, treatment and management of urban runoff and sewer overflow are reviewed. Simplified modeling and monitoring techniques are used to characterize urban runoff and to assess control alternatives. (KRM)

  19. Study reveals urban smoke absorbs sunlight, exacerbating climate warming

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study reveals urban smoke absorbs sunlight Study reveals urban smoke absorbs sunlight, exacerbating climate warming Cloaking urban areas and wildfire zones, tiny smoke particles suspended in the atmosphere have a sizeable effect on our climate. September 30, 2015 A new study by a science team led by Los Alamos National Laboratory stresses the importance of understanding mixed black and brown carbon in smoke emissions for climate models. The particulates found in urban smoke are especially prone

  20. Periodic nanostructures from self assembled wedge-type block-copolymers

    DOE Patents [OSTI]

    Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.; Weitekamp, Raymond; Miyake, Garret M.; Piunova, Victoria; Daeffler, Christopher Scot

    2015-06-02

    The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.

  1. Urban Consortium Energy Task Force - Year 21 Final Report

    SciTech Connect (OSTI)

    2003-04-01

    The Urban Consortium Energy Task Force (UCETF), comprised of representatives of large cities and counties in the United States, is a subgroup of the Urban Consortium, an organization of the nation's largest cities and counties joined together to identify, develop and deploy innovative approaches and technological solutions to pressing urban issues.

  2. Blocked impurity band hybrid infrared focal plane arrays for astronomy

    SciTech Connect (OSTI)

    Reynolds, D.B.; Seib, D.H.; Stetson, S.B.; Herter, T.; Rowlands, N.; Schoenwald, J.

    1989-02-01

    High-performance infrared hybrid focal plane arrays using 10 x 50 element Si:As Blocked-Impurity-Band (BIB) detectors (cut-off wavelength = 28 ..mu..m) and matching switched MOSFET multiplexers have been developed and characterized for space astronomy. Use of impurity band conduction technology provides detectors which are nuclear radiation hard and free of the many anomalies associated with conventional silicon photoconductive detectors. Emphasis in this paper is on recent advances in detector material quality which have led to significantly improved detector and hybrid characteristics. Results demonstrating increase quantum efficiency (particular at short wavelength infrared), obtained by varying the Blocked-Impurity-Band detector properties (infrared active layer thickness and arsenic doping profile), are summarized. Read noise and dark current for different temperatures have been measured and are also described. The hybrid array performance achieved clearly demonstrates that BIB detectors are well suited for use in astronomical instrumentation.

  3. Magnetic alignment of block copolymer microdomains by intrinsic chain anisotropy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rokhlenko, Yekaterina; Yager, Kevin G.; Gopinadhan, Manesh; Osuji, Chinedum O.; Zhang, Kai; O'Hern, Corey S.; Larson, Steven R.; Gopalan, Padma; Majewski, Pawel W.

    2015-12-18

    We examine the role of intrinsic chain susceptibility anisotropy in magnetic field directed self-assembly of a block copolymer using in situ x-ray scattering. Alignment of a lamellar mesophase is observed on cooling across the disorder-order transition with the resulting orientational order inversely proportional to the cooling rate. We discuss the origin of the susceptibility anisotropy, Δχ, that drives alignment and calculate its magnitude using coarse-grained molecular dynamics to sample conformations of surface-tethered chains, finding Δχ ≈ 2×10–8. From field-dependent scattering data, we estimate that grains of ≈ 1.2 μm are present during alignment. Furthermore, these results demonstrate that intrinsic anisotropymore » is sufficient to support strong field-induced mesophase alignment and suggest a versatile strategy for field control of orientational order in block copolymers.« less

  4. Reflectivity studies on adsorbed block copolymers under shear

    SciTech Connect (OSTI)

    Smith, G.S.; Wages, S.; Baker, S.M.; Toprakcioglu, C.; Hadziioannou, G.

    1994-12-01

    The authors report neutron reflectivity data on (poly)styrene-(poly)ethylene oxide (PS-PEO) diblock copolymers adsorbed onto quartz from the selective solvent cyclohexane (a non-solvent for PEO and a poor solvent for PS). The PEO ``anchor block`` adsorbs strongly to form a thin layer on the quartz substrate, while the deuterated PS chains dangle into the solvent. They find that under static conditions the density profile of the PS block in a poor solvent can be well described by a Schultz function which is indicative of a polymer ``mushroom.`` Furthermore, they have studied the same system under shear at shear rates from 0--400s{sup {minus}1}. They find that there is a dramatic increase in the thickness of the PS layer under shear in cyclohexane and that the relaxation time from the shear-on profile back to the static profile is on the order of several days.

  5. Magnetic alignment of block copolymer microdomains by intrinsic chain anisotropy

    SciTech Connect (OSTI)

    Rokhlenko, Yekaterina; Yager, Kevin G.; Gopinadhan, Manesh; Osuji, Chinedum O.; Zhang, Kai; O'Hern, Corey S.; Larson, Steven R.; Gopalan, Padma; Majewski, Pawel W.

    2015-12-18

    We examine the role of intrinsic chain susceptibility anisotropy in magnetic field directed self-assembly of a block copolymer using in situ x-ray scattering. Alignment of a lamellar mesophase is observed on cooling across the disorder-order transition with the resulting orientational order inversely proportional to the cooling rate. We discuss the origin of the susceptibility anisotropy, Δχ, that drives alignment and calculate its magnitude using coarse-grained molecular dynamics to sample conformations of surface-tethered chains, finding Δχ ≈ 2×10–8. From field-dependent scattering data, we estimate that grains of ≈ 1.2 μm are present during alignment. Furthermore, these results demonstrate that intrinsic anisotropy is sufficient to support strong field-induced mesophase alignment and suggest a versatile strategy for field control of orientational order in block copolymers.

  6. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  7. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  8. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  9. EIS-0006: Wind Turbine Generator System, Block Island, Rhode Island

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this EIS to evaluate the environmental impacts of installing and operating a large experimental wind turbine, designated the MOD-OA, which is proposed to be installed on a knoll in Rhode Island's New Meadow Hill Swamp, integrated with the adjacent Block Island Power Company power plant and operated to supply electricity to the existing utility network.

  10. Directed Spontaneous Assembly of Membrane Protein with Amphiphilic Block

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copolymers - Energy Innovation Portal Directed Spontaneous Assembly of Membrane Protein with Amphiphilic Block Copolymers Colorado School of Mines Contact CSM About This Technology Technology Marketing SummaryThis invention describes a method for using membrane proteins (MPs) in synthetic systems for biosensor design, high-throughput drug-screening, catalysis or energy harvesting. DescriptionCurrent efforts in the art face a challenge that practical applications involving liposomes have been

  11. Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrolytes - Joint Center for Energy Storage Research January 13, 2015, Research Highlights Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer Electrolytes (Top) The addition of 2 wt% nanoparticles (SEO-LiTFSI-POSS-2) results in an increase in ionic conductivity. STEM images show the bicontinuous morphology of the electrolyte with 2 wt% of nanoparticles. (Bottom) The value of morphology factor, f, for SEO-LiTFSI-POSS-2 is close to unity, the value expected for an

  12. ISU offering Financial Building Blocks sessions | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ISU offering Financial Building Blocks sessions Money is often considered the number one stressor. Your relationships, focus, safety and physical health may be impacted. Reduce the stress in your life by getting your finances under control. Build your financial knowledge and your skills. Iowa State University is offering five sessions geared towards informing employees how to build a sound financial future. The sessions will be presented by Brian Hood, a CFP from the Legacy Financial Group. As a

  13. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  14. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  15. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  16. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  17. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  18. Pauli blocking in the nuclear medium π N transition matrix

    SciTech Connect (OSTI)

    Moniz, Ernest J.; Sevgen, A.

    1981-07-01

    We give an analytic expression for the in-medium nonstatic πN transition matrix in nuclear matter. Pauli blocking and spreading effects are included explicitly. Spin-flip terms are retained. We discuss the modifications of the free-space amplitude as a function of energy and density and show that large dynamical isospin effects are expected in pion scattering on heavy nuclei.

  19. NFWF Five Star & Urban Waters Restoration Program

    Broader source: Energy.gov [DOE]

    The National Fish and Wildlife Foundation (NFWF) is accepting applications for up to $2.1 million to develop community capacity to sustain local natural resources for future generations by providing modest financial assistance to diverse local partnership for wetland, riparian, forest and coastal habitat restoration, urban wildlife conservation, stormwater management as well as outreach, education and stewardship.

  20. Radical-cured block copolymer-modified thermosets

    SciTech Connect (OSTI)

    Redline, Erica M.; Francis, Lorraine F.; Bates, Frank S.

    2013-01-10

    Poly(ethylene-alt-propylene)-b-poly(ethylene oxide) (PEP-PEO) diblock copolymers were synthesized and added at 4 wt % to 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (BisGMA), a monomer that cures using free radical chemistry. In separate experiments, poly(ethylene glycol) dimethacrylate (PEGDMA) was combined as a secondary monomer with BisGMA and the monomers were loaded with 4 wt % PEP-PEO. The diblock copolymers self-assembled into well-dispersed spherical micelles with PEP cores and PEO coronas. No appreciable change in the final extent of cure of the thermosets was caused by the addition of diblock copolymer, except in the case of BisGMA, where the addition of the block copolymer increased extent of cure by 12%. Furthermore, the extent of cure was increased by 29% and 37% with the addition of 25 and 50 wt % PEGDMA, respectively. Elastic modulus and fracture resistance were also determined, and the values indicate that the addition of block copolymers does not significantly toughen the thermoset materials. This finding is surprising when compared with the large increase in fracture resistance seen in block copolymer-modified epoxies, and an explanation is proposed.

  1. Gas block mechanism for water removal in fuel cells

    DOE Patents [OSTI]

    Issacci, Farrokh; Rehg, Timothy J.

    2004-02-03

    The present invention is directed to apparatus and method for cathode-side disposal of water in an electrochemical fuel cell. There is a cathode plate. Within a surface of the plate is a flow field comprised of interdigitated channels. During operation of the fuel cell, cathode gas flows by convection through a gas diffusion layer above the flow field. Positioned at points adjacent to the flow field are one or more porous gas block mediums that have pores sized such that water is sipped off to the outside of the flow field by capillary flow and cathode gas is blocked from flowing through the medium. On the other surface of the plate is a channel in fluid communication with each porous gas block mediums. The method for water disposal in a fuel cell comprises installing the cathode plate assemblies at the cathode sides of the stack of fuel cells and manifolding the single water channel of each of the cathode plate assemblies to the coolant flow that feeds coolant plates in the stack.

  2. Nanopatterning of ultrananocrystalline diamond thin films via block copolymer lithography.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B.; Sumant, A. V.; Auciello, O.

    2010-07-01

    Nanopatterning of diamond surfaces is critical for the development of diamond-based microelectromechanical system/nanoelectromechanical system (MEMS/NEMS), such as resonators or switches. Micro-/nanopatterning of diamond materials is typically done using photolithography or electron beam lithography combined with reactive ion etching (RIE). In this work, we demonstrate a simple process, block copolymer (BCP) lithography, for nanopatterning of ultrananocrystalline diamond (UNCD) films to produce nanostructures suitable for the fabrication of NEMS based on UNCD. In BCP lithography, nanoscale self-assembled polymeric domains serve as an etch mask for pattern transfer. The authors used thin films of a cylinder-forming organic-inorganic BCP, poly(styrene-block-ferrocenyldimethylsilane), PS-b-PFS, as an etch mask on the surface of UNCD films. Orientational control of the etch masking cylindrical PFS blocks is achieved by manipulating the polymer film thickness in concert with the annealing treatment. We have observed that the surface roughness of UNCD layers plays an important role in transferring the pattern. Oxygen RIE was used to etch the exposed areas of the UNCD film underneath the BCP. Arrays of both UNCD posts and wirelike structures have been created using the same starting polymeric materials as the etch mask.

  3. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined...

  4. Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-011 EFFECTIVE DATE: April 21, 2010 SUBJECT: AMERICAN RECOVERY AND REINVESTMENT ACT (ARRA) ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM - FORMULA GRANT GUIDANCE PURPOSE ........................................................................................................................... 3 SCOPE

  5. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block ... has succeeded in combining resonant soft x-ray scattering (RSoXS) at ALS Beamline 11.0.1 ...

  6. Plains and Eastern Clean Line Transmission Line: Comment from Block Plains

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Eastern Clean Line: Arkansas and Oklahoma | Department of Energy Block Plains and Eastern Clean Line: Arkansas and Oklahoma Plains and Eastern Clean Line Transmission Line: Comment from Block Plains and Eastern Clean Line: Arkansas and Oklahoma Comment submitted on updated Part 2 application. Comment from Block Plains & Eastern Clean Line Arkansas and Oklahoma 06-08-15.pdf (1.21 MB) More Documents & Publications Plains and Eastern Clean Line Transmission Line: Comment from Block

  7. Application of soil barriers for encapsulation of contaminants using special blocking materials and sealing technologies

    SciTech Connect (OSTI)

    Kretzschmar, H.J.; Lakatos, I.

    1997-12-31

    This paper describes the use of Montanwax and polymersilicate solution for use as blocking materials for the containment of pollutants.

  8. Non-crosslinked, amorphous, block copolymer electrolyte for batteries

    DOE Patents [OSTI]

    Mayes, Anne M.; Ceder, Gerbrand; Chiang, Yet-Ming; Sadoway, Donald R.; Aydinol, Mehmet K.; Soo, Philip P.; Jang, Young-Il; Huang, Biying

    2006-04-11

    Solid battery components are provided. A block copolymeric electrolyte is non-crosslinked and non-glassy through the entire range of typical battery service temperatures, that is, through the entire range of at least from about 0.degree. C. to about 70.degree. C. The chains of which the copolymer is made each include at least one ionically-conductive block and at least one second block immiscible with the ionically-conductive block. The chains form an amorphous association and are arranged in an ordered nanostructure including a continuous matrix of amorphous ionically-conductive domains and amorphous second domains that are immiscible with the ionically-conductive domains. A compound is provided that has a formula of Li.sub.xM.sub.yN.sub.zO.sub.2. M and N are each metal atoms or a main group elements, and x, y and z are each numbers from about 0 to about 1. y and z are chosen such that a formal charge on the M.sub.yN.sub.z portion of the compound is (4-x). In certain embodiments, these compounds are used in the cathodes of rechargeable batteries. The present invention also includes methods of predicting the potential utility of metal dichalgogenide compounds for use in lithium intercalation compounds. It also provides methods for processing lithium intercalation oxides with the structure and compositional homogeneity necessary to realize the increased formation energies of said compounds. An article is made of a dimensionally-stable, interpenetrating microstructure of a first phase including a first component and a second phase, immiscible with the first phase, including a second component. The first and second phases define interphase boundaries between them, and at least one particle is positioned between a first phase and a second phase at an interphase boundary. When the first and second phases are electronically-conductive and ionically-conductive polymers, respectively, and the particles are ion host particles, the arrangement is an electrode of a battery.

  9. Single Helix to Double Gyroid in Chiral Block Copolymers

    SciTech Connect (OSTI)

    C Chen; H Hsueh; Y Chiang; R Ho; S Akasaka; H Hasegawa

    2011-12-31

    An order-order phase transition of chiral block copolymers (BCPs*) from single helix to double gyroid (H* {yields} G) through a nucleation and growth process was demonstrated. The H* and G phases can be obtained by solution casting from fast and slow solvent evaporation, respectively, suggesting that the H* phase is a metastable phase. Consequently, the coexistence of H* and G phases can be found in the solution-cast samples from intermediate solvent evaporation. To truly examine the transition mechanism of the H* {yields} G, electron tomography was carried out to directly visualize the morphological evolution in real space, in particular, the transition zone at interface. Unlike the mechanisms for the transitions of block copolymers (BCPs) by considering the interdomain spacing matching, a significant mismatch in the lattices for the H* {yields} G was found. Consequently, the transition may require an adjustment on the geometric dimensions to justify corresponding lattice mismatch. As a result, the morphological observations from electron tomography offer new insights into BCP phase transitions.

  10. Deuteration Can Impact Micellization Pressure and Cloud Pressure of Polystyrene-block-polybutadiene and Polystyrene-block-polyisoprene in Compressible Propane

    SciTech Connect (OSTI)

    Winoto, Winoto; Shen, Youqin; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    The deuterated homopolymers and their corresponding polystyrene-block-polybutadiene and polystyrene-block-polyisoprene copolymers require lower cloud pressures than their hydrogenous analogues to dissolve in a compressible alkane solvent, such as propane. For symmetric diblocks, deuteration reduces the micellization pressure. By contrast, for asymmetric diblocks with a long diene block relative to the styrene block, deuteration can increase the micellization pressure. All in all, however, the deuteration effects, while measurable, do not qualitatively change the principal diblock properties in compressible propane solutions, such as pressure-induced micelle decomposition, micelle formation and micelle size, and their temperature dependence. Therefore, isotope labeling should be a useful approach to neutron-scattering characterization for styrene-diene block copolymers in compressible alkane systems.

  11. 2014 Race to Zero Student Design Competition: Ryerson University's Urban

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Harvest Team Submission | Department of Energy Ryerson University's Urban Harvest Team Submission 2014 Race to Zero Student Design Competition: Ryerson University's Urban Harvest Team Submission Ryerson University's Urban Harvest's team submission to the 2014 Race to Zero Student Design Competition. harvest_home_team_submission.pdf (38.41 MB) More Documents & Publications 2014 Race to Zero Student Design Competition: Ryerson University -- Harvest Home Presentation Indoor airPLUS

  12. Consequences of Urban Stability Conditions for Computational Fluid Dynamics Simulations of Urban Dispersion

    SciTech Connect (OSTI)

    Lundquist, J K; Chan, S T

    2005-11-30

    The validity of omitting stability considerations when simulating transport and dispersion in the urban environment is explored using observations from the Joint URBAN 2003 field experiment and computational fluid dynamics simulations of that experiment. Four releases of sulfur hexafluoride, during two daytime and two nighttime intensive observing periods, are simulated using the building-resolving computational fluid dynamics model, FEM3MP to solve the Reynolds Averaged Navier-Stokes equations with two options of turbulence parameterizations. One option omits stability effects but has a superior turbulence parameterization using a non-linear eddy viscosity (NEV) approach, while the other considers buoyancy effects with a simple linear eddy viscosity (LEV) approach for turbulence parameterization. Model performance metrics are calculated by comparison with observed winds and tracer data in the downtown area, and with observed winds and turbulence kinetic energy (TKE) profiles at a location immediately downwind of the central business district (CBD) in the area we label as the urban shadow. Model predictions of winds, concentrations, profiles of wind speed, wind direction, and friction velocity are generally consistent with and compare reasonably well with the field observations. Simulations using the NEV turbulence parameterization generally exhibit better agreement with observations. To further explore this assumption of a neutrally-stable atmosphere within the urban area, TKE budget profiles slightly downwind of the urban wake region in the 'urban shadow' are examined. Dissipation and shear production are the largest terms which may be calculated directly. The advection of TKE is calculated as a residual; as would be expected downwind of an urban area, the advection of TKE produced within the urban area is a very large term. Buoyancy effects may be neglected in favor of advection, shear production, and dissipation. For three of the IOPs, buoyancy production may

  13. Sustainable Urban Transport Project (SUTP) | Open Energy Information

    Open Energy Info (EERE)

    Urban Transport Project GIZ Sourcebook Module 4f: Eco Driving Experiences from Introduction of Ethanol Buses and Ethanol Fuel Station ... further results Find Another Tool...

  14. Energy Saving Potentials and Air Quality Benefits of Urban Heat...

    Office of Scientific and Technical Information (OSTI)

    Conference: Energy Saving Potentials and Air Quality Benefits of Urban Heat Island Mitigation Citation Details In-Document Search Title: Energy Saving Potentials and Air Quality ...

  15. Ethanol Usage in Urban Public Transportation - Presentation of...

    Open Energy Info (EERE)

    - Presentation of Results Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Ethanol Usage in Urban Public Transportation - Presentation of Results AgencyCompany...

  16. ICLEI Sustainable Urban Energy Planning | Open Energy Information

    Open Energy Info (EERE)

    Urban Energy Planning AgencyCompany Organization: ICLEI - Local Governments for Sustainability Sector: Energy Focus Area: Renewable Energy, Energy Efficiency Topics:...

  17. Urban structure and its influence on vehicle travel reduction strategies

    SciTech Connect (OSTI)

    Southworth, F.; Jones, D.W.; Harrison, G.

    1996-04-01

    This paper examines what is known about the relationship between urban spatial structure (i.e. the arrangement of residential, industrial, commercial, recreational and municipal buildings and land lots) and urban travel. The first section provides an overview of the empirical evidence for relationships between urban spatial structure and travel in the United States. Section two focuses on the barriers to and opportunities for reducing the use of automobiles and light trucks in urban areas. The final section offers a policy-point-of-impact perspective on the sort of instruments governments have at their disposal for reducing vehicular travel.

  18. High Performance Without Increased Cost: Urbane Homes, Louisville...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In this profile, Urbane Homes of Louisville, KY, worked with Building America team National Association of Home Builders Research Center to build its first high performance home at ...

  19. Building America Whole-House Solutions for New Homes: Urbane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case study of Urbane Homes who worked with Building America research partner NAHBRC to build HERS-57 homes with rigid foam insulated slabs and foundation walls, advanced framed ...

  20. Energy Saving Potentials and Air Quality Benefits of Urban Heat...

    Office of Scientific and Technical Information (OSTI)

    ... Resource Type: Conference Resource Relation: Conference: First International Conference on ... PAVEMENTS; PLANTS; POWER PLANTS; REFLECTION; SMOG; SOLAR RADIATION; TREES; URBAN AREAS

  1. Indonesia-GTZ Emissions Reductions in Urban Transport | Open...

    Open Energy Info (EERE)

    policy on sustainable urban transport, as well as general deficiencies regarding personal and financial resources in city administrations. The methodological approach of GTZ...

  2. The LANL urban consequences project (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: The LANL urban consequences project Authors: Bos, Randall J 1 ; Brown, Michael J 1 ; Goorley, John T 1 ; Grinstein, Fernando 1 ; ...

  3. Clean Urban Transport for Europe CUTE | Open Energy Information

    Open Energy Info (EERE)

    Transport for Europe CUTE Jump to: navigation, search Name: Clean Urban Transport for Europe (CUTE) Place: Ulm, Germany Zip: 89077 Product: Germany-based, European Union project...

  4. Property:PotentialUrbanUtilityScalePVCapacity | Open Energy Informatio...

    Open Energy Info (EERE)

    Description The nameplate capacity technical potential from utility-scale PV in urban areas of a particular place. Use this property to express potential electric energy...

  5. Adapting Urban Transport to Climate Change- Module 5f - Sustainable...

    Open Energy Info (EERE)

    Adapting Urban Transport to Climate Change- Module 5f - Sustainable transport: a sourcebook for policy-makers in developing cities Jump to: navigation, search Tool Summary LAUNCH...

  6. Nanoporous Gold as a Platform for a Building Block Catalyst

    SciTech Connect (OSTI)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporous gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.

  7. Sealed Battery Block Provided With A Cooling System

    DOE Patents [OSTI]

    Verhoog, Roelof; Barbotin, Jean-Loup

    1999-11-16

    The present invention relates to a sealed battery block operating at a pressure of at least 1 bar relative, the battery including a container made of a plastics material and made up of a lid and of a case subdivided into wells by at least one partition, said battery being provided with a cooling system including two cheek plates made of a plastics material and co-operating with the outside faces of respective ones of two opposite walls of said case, each cheek plate co-operating with the corresponding wall to define a compartment provided with a plurality of ribs forming baffles for fluid flow purposes, and with an inlet orifice and an outlet orifice for the fluid, said battery being characterized in that each of said ribs extends in a direction that forms an angle relative to the plane of said partition lying in the range 60.degree. to 90.degree..

  8. Linked supramolecular building blocks for enhanced cluster formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLellan, Ross; Palacios, Maria A.; Beavers, Christine M.; Teat, Simon J.; Piligkos, Stergios; Brechin, Euan K.; Dalgarno, Scott J.

    2015-01-09

    Methylene-bridged calix[4]arenes have emerged as extremely versatile ligand supports in the formation of new polymetallic clusters possessing fascinating magnetic properties. Metal ion binding rules established for this building block allow one to partially rationalise the complex assembly process. The ability to covalently link calix[4]arenes at the methylene bridge provides significantly improved control over the introduction of different metal centres to resulting cluster motifs. Clusters assembled from bis-calix[4]arenes and transition metal ions or 3d-4f combinations display characteristic features of the analogous calix[4]arene supported clusters, thereby demonstrating an enhanced and rational approach towards the targeted synthesis of complex and challenging structures.

  9. Nanoporous Gold as a Platform for a Building Block Catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporousmore » gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.« less

  10. Linked supramolecular building blocks for enhanced cluster formation

    SciTech Connect (OSTI)

    McLellan, Ross; Palacios, Maria A.; Beavers, Christine M.; Teat, Simon J.; Piligkos, Stergios; Brechin, Euan K.; Dalgarno, Scott J.

    2015-01-09

    Methylene-bridged calix[4]arenes have emerged as extremely versatile ligand supports in the formation of new polymetallic clusters possessing fascinating magnetic properties. Metal ion binding rules established for this building block allow one to partially rationalise the complex assembly process. The ability to covalently link calix[4]arenes at the methylene bridge provides significantly improved control over the introduction of different metal centres to resulting cluster motifs. Clusters assembled from bis-calix[4]arenes and transition metal ions or 3d-4f combinations display characteristic features of the analogous calix[4]arene supported clusters, thereby demonstrating an enhanced and rational approach towards the targeted synthesis of complex and challenging structures.

  11. Converting urban tree maintenance residue to energy

    SciTech Connect (OSTI)

    Murphey, W.K.; Massey, J.G.; Sumrall, A.

    1980-01-01

    Three methods of utilizing urban wood waste collected by a tree maintenance firm in Houston, Texas (handling 30,000 ton waste/year) are examined: (a) hauling to a remote landfill; (b) chipping and hauling to a (local) power plant and converting to electricity; and (c) chipping and selling to an outside firm for use as boiler fuel. Breakdown of costs are given for each method in monetary and energy terms. Method (b) was the cheapest, producing a net energy gain (870 million Btu/day), but the firm chose method (c), since it realized a direct monetary return.

  12. Housing and urban development research reports

    SciTech Connect (OSTI)

    Not Available

    1984-01-01

    The sixth in a series of documents published by the Department of Housng and Urban Development (HUD) to assist in the formulation of policy decision contains 247 abstracts entered in the HUD USER automated data base during the past six months, bringing the data base total to 3,583 documents. There are 45 subject areas in the main section, with the abstracts in each area arranged alphabetically by title. Each abstract is identified by an order number and is followed by descriptive keywords. Other listings of the documents are alphabetical, numerical, by personal or corporate author, by contract and grant number, and by subject index.

  13. Solar Urban Neighborhood (SUN). Final report

    SciTech Connect (OSTI)

    Ellertson, J.

    1984-07-10

    The Solar Urban Neighborhood (SUN) project was conceived to demonstrate a widely applicable cooperative procedure for low and moderate income urban residents to conserve energy and promote neighborhood revitalization through installing affordable energy conservation and solar retrofit measures on their homes. The self-help retrofit systems demonstrated fan-assisted air panels for walls and a mansard roof as well as vented Trombe wall and a sunspace. Building upon a strong tradition of cooperation within their neighborhood (security watches, community gardening, bartering of skills for do-it-yourself projects), these Roxbury neighbors were able to use the DOE grant as a catalyst for doing a far more ambitious undertaking. Additionally, the project used elements of a private-public partnership since the project director was also an energy retrofit contractor with specialized equipment and skills to share, wholesale purchase access, etc. Countervailing negative forces which impeded the progress of the project were the very ambitiousness of the solar retrofit itself, the delays in receiving the initial start up grant advance and in overcoming zoning restrictions which required design modifications; and discovery of building defects (dry rot, carpenter ants) within the structures at the time of retrofit. Nevertheless, the SUN project did have a wide impact through formal and informal outreach; through an associated project, SUN-TECH, which promoted solar retrofit awareness and involvement of City of Boston building, energy, and housing officials; and through evolvement of a grass roots level public-private partnership.

  14. A Web Based Geographic Information Platform to Support Urban Adaptation to Climate Change

    SciTech Connect (OSTI)

    Nugent, Philip J; Omitaomu, Olufemi A; Parish, Esther S; Mei, Rui; Ernst, Kathleen M; Absar, Mariya

    2015-01-01

    The urban climate is changing rapidly. Therefore, climate change and its projected impacts on environmental conditions must be considered in assessing and comparing urban planning alternatives. In this paper, we present an integrated framework for urban climate adaptation tool (Urban-CAT) that will help cities to plan for, rather than react to, possible risks. Urban-CAT will be developed as a scenario planning tool that is locally relevant to existing urban decision-making processes.

  15. Cooperative storage of shared files in a parallel computing system with dynamic block size

    DOE Patents [OSTI]

    Bent, John M.; Faibish, Sorin; Grider, Gary

    2015-11-10

    Improved techniques are provided for parallel writing of data to a shared object in a parallel computing system. A method is provided for storing data generated by a plurality of parallel processes to a shared object in a parallel computing system. The method is performed by at least one of the processes and comprises: dynamically determining a block size for storing the data; exchanging a determined amount of the data with at least one additional process to achieve a block of the data having the dynamically determined block size; and writing the block of the data having the dynamically determined block size to a file system. The determined block size comprises, e.g., a total amount of the data to be stored divided by the number of parallel processes. The file system comprises, for example, a log structured virtual parallel file system, such as a Parallel Log-Structured File System (PLFS).

  16. Framework for integration of urban planning, strategic environmental assessment and ecological planning for urban sustainability within the context of China

    SciTech Connect (OSTI)

    He Jia; Bao Cunkuan; Shu Tingfei; Yun Xiaoxue; Jiang Dahe; Brwon, Lex

    2011-11-15

    Sustainable development or sustainability has been highlighted as an essential principle in urban master planning, with increasing recognition that uncontrollable urbanization may well give rise to various issues such as overexploitation of natural resources, ecosystem destruction, environmental pollution and large-scale climate change. Thus, it is deemed necessary to modify the existing urban and regional administrative system so as to cope with the challenges urban planning is being confronted with and realize the purpose of urban sustainability. This paper contributed to proposing a mechanism which helps to make urban planning with full consideration of issues with respect to sustainable development. We suggested that the integration of urban planning, SEA and ecological planning be a multi-win strategy to offset deficiency of each mentioned political tool being individually applied. We also proposed a framework where SEA and ecological planning are fully incorporated into urban planning, which forms a two-way constraint mechanism to ascertain environmental quality of urban planning, although in practice, planning and SEA processes may conditionally be unified. Moreover, as shown in the case study, the integration of the three political tools may be constrained due to slow changes in the contextual factors, in particular the political and cultural dimensions. Currently within the context of China, there may be three major elements which facilitate integration of the three political tools, which are (1) regulatory requirement of PEIA on urban planning, (2) the promotion or strong administrative support from government on eco-district building, and (3) the willingness of urban planners to collaborate with SEA experts or ecologists.

  17. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  18. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  19. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  20. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  1. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  2. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  3. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  4. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 DAVIS-BACON ACT WAGE RATES FOR ARRA-FUNDED ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM PROJECTS INVOLVING RESIDENTIAL WEATHERIZATION WORK eecbg_guidance_not_using_wap_rates_05062010.pdf (57.2 KB) More Documents & Publications Davis-Bacon Act Wage Rates for ARRA-Funded State Energy Program Projects Involving

  5. Thermal-stress analysis of a Fort St. Vrain core-support block under accident conditions

    SciTech Connect (OSTI)

    Carruthers, L.M.; Butler, T.A.; Anderson, C.A.

    1982-01-01

    A thermoelastic stress analysis of a graphite core support block in the Fort St. Vrain High Temperature Gas Cooled Reactor is described. The support block is subjected to thermal stresses caused by a loss of forced circulation accident of the reactor system. Two- and three-dimensional finite element models of the core support block are analyzed using the ADINAT and ADINA codes, and results are given that verify the integrity of this structural component under the given accident condition.

  6. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print Wednesday, 30 May 2012 00:00 In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks

  7. Collapse transitions in thermosensitive multi-block copolymers: A Monte Carlo study

    SciTech Connect (OSTI)

    Rissanou, Anastassia N.; Tzeli, Despoina S.; Anastasiadis, Spiros H.; Bitsanis, Ioannis A.

    2014-05-28

    Monte Carlo simulations are performed on a simple cubic lattice to investigate the behavior of a single linear multiblock copolymer chain of various lengths N. The chain of type (A{sub n}B{sub n}){sub m} consists of alternating A and B blocks, where A are solvophilic and B are solvophobic and N = 2nm. The conformations are classified in five cases of globule formation by the solvophobic blocks of the chain. The dependence of globule characteristics on the molecular weight and on the number of blocks, which participate in their formation, is examined. The focus is on relative high molecular weight blocks (i.e., N in the range of 5005000 units) and very differing energetic conditions for the two blocks (very goodalmost athermal solvent for A and bad solvent for B). A rich phase behavior is observed as a result of the alternating architecture of the multiblock copolymer chain. We trust that thermodynamic equilibrium has been reached for chains of N up to 2000 units; however, for longer chains kinetic entrapments are observed. The comparison among equivalent globules consisting of different number of B-blocks shows that the more the solvophobic blocks constituting the globule the bigger its radius of gyration and the looser its structure. Comparisons between globules formed by the solvophobic blocks of the multiblock copolymer chain and their homopolymer analogs highlight the important role of the solvophilic A-blocks.

  8. Self-assembly of block copolymers on topographically patterned polymeric substrates

    DOE Patents [OSTI]

    Russell, Thomas P.; Park, Soojin; Lee, Dong Hyun; Xu, Ting

    2016-05-10

    Highly-ordered block copolymer films are prepared by a method that includes forming a polymeric replica of a topographically patterned crystalline surface, forming a block copolymer film on the topographically patterned surface of the polymeric replica, and annealing the block copolymer film. The resulting structures can be used in a variety of different applications, including the fabrication of high density data storage media. The ability to use flexible polymers to form the polymeric replica facilitates industrial-scale processes utilizing the highly-ordered block copolymer films.

  9. In Situ SAXS Studies of Structural Relaxation of an Ordered Block...

    Office of Scientific and Technical Information (OSTI)

    Flow Citation Details In-Document Search Title: In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow ...

  10. 50 kW Power Block for Distributed Energy Applications - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search 50 kW Power Block for Distributed Energy Applications National Renewable Energy Laboratory Contact NREL About This Technology Actual prototype ...

  11. $300,000 Block Grant Awarded to Tri-City Industrial Development Council

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (TRIDEC) | Department of Energy $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) (37.6 KB) More Documents & Publications Department of Energy Awards $300,000 to Tri-City Industrial Development Council in Washington

  12. A global map of urban extent from nightlights

    SciTech Connect (OSTI)

    Zhou, Yuyu; Smith, Steven J.; Zhao, Kaiguang; Imhoff, Marc L.; Thomson, Allison M.; Bond-Lamberty, Benjamin; Asrar, Ghassem R.; Zhang, Xuesong; He, Chunyang; Elvidge, Christopher

    2015-05-13

    Urbanization, one of the major human induced land-cover and land-use changes, has a profound impact on the Earth system including biodiversity, the cycling of water and carbon and exchange of energy and water between Earth’s surface and atmosphere, all affecting weather and climate. Accurate information on urban areas and their spatial distribution at the regional and global scales is important for scientific understanding of their contribution to the changing Earth system, and for practical management and policy decisions. We developed a method to map the urban extent from the Defense Meteorological Satellite Program/Operational Linescan System (DMSP/OLS) nighttime stable-light data at the global level and derived a new global map of 1-km urban extent for year 2000. Based on this map, we found that globally, urban land area is about 0.5% of total land area but ranges widely at regional level from 0.1% in Oceania to 2.3% in Europe. At the country level, urban land area varies from lower than 0.01% to higher than 10%, but is lower than 1% for most (70%) countries. Urbanization follows land mass distribution, as anticipated, with the highest concentration found between 30°N to 45°N latitude and the largest longitudinal peak around 80°W. Based on a sensitivity analysis and comparison with other global urban area products, we found that our global product of urban area provides a reliable estimate of global urban areas and offer the potential of capturing more accurately their spatial and temporal dynamics.

  13. A global map of urban extent from nightlights

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yuyu; Smith, Steven J.; Zhao, Kaiguang; Imhoff, Marc L.; Thomson, Allison M.; Bond-Lamberty, Benjamin; Asrar, Ghassem R.; Zhang, Xuesong; He, Chunyang; Elvidge, Christopher

    2015-05-13

    Urbanization, one of the major human induced land-cover and land-use changes, has a profound impact on the Earth system including biodiversity, the cycling of water and carbon and exchange of energy and water between Earth’s surface and atmosphere, all affecting weather and climate. Accurate information on urban areas and their spatial distribution at the regional and global scales is important for scientific understanding of their contribution to the changing Earth system, and for practical management and policy decisions. We developed a method to map the urban extent from the Defense Meteorological Satellite Program/Operational Linescan System (DMSP/OLS) nighttime stable-light data atmore » the global level and derived a new global map of 1-km urban extent for year 2000. Based on this map, we found that globally, urban land area is about 0.5% of total land area but ranges widely at regional level from 0.1% in Oceania to 2.3% in Europe. At the country level, urban land area varies from lower than 0.01% to higher than 10%, but is lower than 1% for most (70%) countries. Urbanization follows land mass distribution, as anticipated, with the highest concentration found between 30°N to 45°N latitude and the largest longitudinal peak around 80°W. Based on a sensitivity analysis and comparison with other global urban area products, we found that our global product of urban area provides a reliable estimate of global urban areas and offer the potential of capturing more accurately their spatial and temporal dynamics.« less

  14. Nanostructure of Solid Precipitates Obtained by Expansion of Polystyrene-block-Polybutadiene Solutions in Near Critical Propane: Block Ratio and Micellar Solution Effects

    SciTech Connect (OSTI)

    Green, Jade; Tyrrell, Zachary; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2011-01-01

    In contrast to incompressible liquid solutions, compressible near-critical solutions of block copolymers allow for controlling rapid structure transformations with pressure alone. For example, when dissolved in near-critical propane, polystyrene-block-polybutadiene can form a random molecular solution at high pressures, a micellar solution at moderate pressures, and a solvent-free precipitate at low pressures. In contrast to the unstructured virgin copolymer, such a propane-treated precipitate rapidly self-assembles toward structures characteristic of equilibrated block copolymers, such as lamellae, spheres, or cylinders, which depend on the block ratio rather than on the decompression rate or temperature, at least within the rate and temperature ranges investigated in this work. At lower temperatures, however, say below 40 C, glass transition of the styrene-butadiene diblocks can inhibit independent structure formation, while crystallization of their hydrogenated-butadiene analogues can preserve the micellar-solution structure.

  15. STUDIES IN ASTRONOMICAL TIME SERIES ANALYSIS. VI. BAYESIAN BLOCK REPRESENTATIONS

    SciTech Connect (OSTI)

    Scargle, Jeffrey D.; Norris, Jay P.; Jackson, Brad; Chiang, James

    2013-02-20

    This paper addresses the problem of detecting and characterizing local variability in time series and other forms of sequential data. The goal is to identify and characterize statistically significant variations, at the same time suppressing the inevitable corrupting observational errors. We present a simple nonparametric modeling technique and an algorithm implementing it-an improved and generalized version of Bayesian Blocks-that finds the optimal segmentation of the data in the observation interval. The structure of the algorithm allows it to be used in either a real-time trigger mode, or a retrospective mode. Maximum likelihood or marginal posterior functions to measure model fitness are presented for events, binned counts, and measurements at arbitrary times with known error distributions. Problems addressed include those connected with data gaps, variable exposure, extension to piecewise linear and piecewise exponential representations, multivariate time series data, analysis of variance, data on the circle, other data modes, and dispersed data. Simulations provide evidence that the detection efficiency for weak signals is close to a theoretical asymptotic limit derived by Arias-Castro et al. In the spirit of Reproducible Research all of the code and data necessary to reproduce all of the figures in this paper are included as supplementary material.

  16. The nucleocapsid protein of measles virus blocks host interferon response

    SciTech Connect (OSTI)

    Takayama, Ikuyo; Sato, Hiroki; Watanabe, Akira; Omi-Furutani, Mio; Sugai, Akihiro; Kanki, Keita; Yoneda, Misako; Kai, Chieko

    2012-03-01

    Measles virus (MV) belongs to the genus Morbillivirus of the family Paramyxoviridae. A number of paramyxoviruses inhibit host interferon (IFN) signaling pathways in host immune systems by various mechanisms. Inhibition mechanisms have been described for many paramyxoviruses. Although there are inconsistencies among previous reports concerning MV, it appears that P/V/C proteins interfere with the pathways. In this study, we confirmed the effects of MV P gene products of a wild MV strain on IFN pathways and examined that of other viral proteins on it. Interestingly, we found that N protein acts as an IFN-{alpha}/{beta} and {gamma}-antagonist as strong as P gene products. We further investigated the mechanisms of MV-N inhibition, and revealed that MV-N blocks the nuclear import of activated STAT without preventing STAT and Jak activation or STAT degradation, and that the nuclear translocation of MV-N is important for the inhibition. The inhibitory effect of the N protein was observed as a common feature of other morbilliviruses. The results presented in this report suggest that N protein of MV as well as P/V/C proteins is involved in the inhibition of host IFN signaling pathways.

  17. Parallel Block Structured Adaptive Mesh Refinement on Graphics Processing Units

    SciTech Connect (OSTI)

    Beckingsale, D. A.; Gaudin, W. P.; Hornung, R. D.; Gunney, B. T.; Gamblin, T.; Herdman, J. A.; Jarvis, S. A.

    2014-11-17

    Block-structured adaptive mesh refinement is a technique that can be used when solving partial differential equations to reduce the number of zones necessary to achieve the required accuracy in areas of interest. These areas (shock fronts, material interfaces, etc.) are recursively covered with finer mesh patches that are grouped into a hierarchy of refinement levels. Despite the potential for large savings in computational requirements and memory usage without a corresponding reduction in accuracy, AMR adds overhead in managing the mesh hierarchy, adding complex communication and data movement requirements to a simulation. In this paper, we describe the design and implementation of a native GPU-based AMR library, including: the classes used to manage data on a mesh patch, the routines used for transferring data between GPUs on different nodes, and the data-parallel operators developed to coarsen and refine mesh data. We validate the performance and accuracy of our implementation using three test problems and two architectures: an eight-node cluster, and over four thousand nodes of Oak Ridge National Laboratory’s Titan supercomputer. Our GPU-based AMR hydrodynamics code performs up to 4.87× faster than the CPU-based implementation, and has been scaled to over four thousand GPUs using a combination of MPI and CUDA.

  18. Matrix-free constructions of circulant and block circulant preconditioners

    SciTech Connect (OSTI)

    Yang, Chao; Ng, Esmond G.; Penczek, Pawel A.

    2001-12-01

    A framework for constructing circulant and block circulant preconditioners (C) for a symmetric linear system Ax=b arising from certain signal and image processing applications is presented in this paper. The proposed scheme does not make explicit use of matrix elements of A. It is ideal for applications in which A only exists in the form of a matrix vector multiplication routine, and in which the process of extracting matrix elements of A is costly. The proposed algorithm takes advantage of the fact that for many linear systems arising from signal or image processing applications, eigenvectors of A can be well represented by a small number of Fourier modes. Therefore, the construction of C can be carried out in the frequency domain by carefully choosing its eigenvalues so that the condition number of C{sup T} AC can be reduced significantly. We illustrate how to construct the spectrum of C in a way such that the smallest eigenvalues of C{sup T} AC overlaps with those of A extremely well while the largest eigenvalues of C{sup T} AC are smaller than those of A by several orders of magnitude. Numerical examples are provided to demonstrate the effectiveness of the preconditioner on accelerating the solution of linear systems arising from image reconstruction application.

  19. Disaster incubation, cumulative impacts and the urban/ex-urban/rural dynamic

    SciTech Connect (OSTI)

    Mulvihill, Peter R. . E-mail: prm@yorku.ca; Ali, S. Harris . E-mail: hali@yorku.ca

    2007-05-15

    This article explores environmental impacts and risks that can accumulate in rural and ex-urban areas and regions and their relation to urban and global development forces. Two Southern Ontario cases are examined: an area level water disaster and cumulative change at the regional level. The role of disaster incubation analysis and advanced environmental assessment tools are discussed in terms of their potential to contribute to more enlightened and effective assessment and planning processes. It is concluded that conventional approaches to EA and planning are characteristically deficient in addressing the full range of impacts and risks, and particularly those originating from pathogens, dispersed and insidious sources. Rigorous application of disaster incubation analysis and more advanced forms of EA has considerable potential to influence a different pattern of planning and decision making.

  20. Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes

    DOE Patents [OSTI]

    Fujimoto, Cy H.; Hibbs, Michael; Ambrosini, Andrea

    2012-02-07

    Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

  1. Tunable Encapsulation Structure of Block Copolymer Coated Single-Walled Carbon Nanotubes in Aqueous Solution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Youngkyu; Ahn, Suk-Kyun; Zhang, Zhe; Smith, Gregory Scott; Do, Changwoo

    2015-01-01

    The nano-sized and shape-tunable molecular building blocks can provide great opportunities for the fabrication of precisely controlled nanostructures. In this work, we have fabricated a molecular building block of single-walled carbon nanotubes (SWNTs) coated by PPO-PEO-PPO block copolymers whose encapsulation structure can be controlled via temperature or addition of small molecules. The structure and optical properties of SWNT-block copolymers have been investigated by small angle neutron scattering (SANS), ultraviolet-visible (UV-vis) spectroscopy, atomic force microscopy (AFM), and molecular dynamics (MD) simulation. The structure of the hydrated block copolymer layer surrounding SWNT can be controlled reversibly by varying temperature as well asmore » by irreversibly adding 5-methylsalicylic acid (5MS). Increasing hydrophobicity of the polymers with temperature and strong tendency of 5MS to interact with both block copolymers and orbitals of the SWNTs are likely to be responsible for the significant structural change of the block copolymer encapsulation layer, from loose corona shell to tightly encapsulating compact shell. These result shows an efficient and simple way to fabricate and manipulate carbon-based nano building blocks in aqueous systems with tunable structure.« less

  2. Monitoring Plan for Weatherization Assistance Program, State Energy Program, Energy Efficiency and Conservation Block Grants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    American Recovery and Reinvestment Act Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants Revised: June 30, 2010 U.S. Department of Energy Office of Weatherization and Intergovernmental Program Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants Concurrences:

  3. Global Cooling: Effect of Urban Albedo on Global Temperature

    SciTech Connect (OSTI)

    Akbari, Hashem; Menon, Surabi; Rosenfeld, Arthur

    2007-05-22

    In many urban areas, pavements and roofs constitute over 60% of urban surfaces (roof 20-25%, pavements about 40%). The roof and the pavement albedo can be increased by about 0.25 and 0.10, respectively, resulting in a net albedo increase for urban areas of about 0.1. Many studies have demonstrated building cooling-energy savings in excess of 20% upon raising roof reflectivity from an existing 10-20% to about 60%. We estimate U.S. potential savings in excess of $1 billion (B) per year in net annual energy bills. Increasing albedo of urban surfaces can reduce the summertime urban temperature and improve the urban air quality. Increasing the urban albedo has the added benefit of reflecting more of the incoming global solar radiation and countering the effect of global warming. We estimate that increasing albedo of urban areas by 0.1 results in an increase of 3 x 10{sup -4} in Earth albedo. Using a simple global model, the change in air temperature in lowest 1.8 km of the atmosphere is estimated at 0.01K. Modelers predict a warming of about 3K in the next 60 years (0.05K/year). Change of 0.1 in urban albedo will result in 0.01K global cooling, a delay of {approx}0.2 years in global warming. This 0.2 years delay in global warming is equivalent to 10 Gt reduction in CO2 emissions.

  4. Ultrasonic examination of the heavy section test blocks for hydroprocessing reactors used by the petroleum industry

    SciTech Connect (OSTI)

    Dodd, F.J.; Zhang, Y.; Imgram, A.

    1995-12-01

    An 18-inch (457 mm) thick Cr-Mo steel test block with an austenitic stainless steel ID cladding was designed and fabricated at the direction of the Material Properties Council in cooperation with the Pressure Vessel Research Committee (PVRC) Committee on Nondestructive Examination of Components. The test block contains several embedded flaws located near both ID and OD surfaces. Chevron Research and Technology Company and WesDyne International conducted the initial UT Examinations on this block at Chevron. In addition, a 10-inch (254 mm) thick block with embedded flaws was also examined. All the flaws m the two blocks were either cracks or lack of fusion. The examination results demonstrate the feasibility of UT to detect and size flaws in hydroprocessing reactor vessels and provide a basis to compare the relative capabilities of UT with the radiographic (RT) inspections currently required by the fabrication code.

  5. Sub-5 nm Domains in Ordered Poly(cyclohexylethylene)-block-poly(methyl methacrylate) Block Polymers for Lithography.

    SciTech Connect (OSTI)

    Kennemur, Justin; Yao, Li; Bates, Frank Stephen; Hillmyer, Marc

    2014-01-01

    A series of poly(cyclohexylethylene)-block-poly- (methyl methacrylate) (PCHE PMMA) diblock copolymers with varying molar mass (4.9 kg/mol Mn 30.6 kg/mol) and narrow molar mass distribution were synthesized through a combination of anionic and atom transfer radical polymerization (ATRP) techniques. Heterogeneous catalytic hydrogenation of -(hydroxy)polystyrene (PS-OH) yielded -(hydroxy)poly(cyclohexylethylene) (PCHEOH) with little loss of hydroxyl functionality. PCHE-OH was reacted with -bromoisobutyryl bromide (BiBB) to produce an ATRP macroinitiator used for the polymerization of methyl methacrylate. PCHE PMMA is a glassy, thermally stable material with a large effective segment segment interaction parameter, eff = (144.4 6.2)/T (0.162 0.013), determined by meanfield analysis of order-to-disorder transition temperatures (TODT) measured by dynamic mechanical analysis and differential scanning calorimetry. Ordered lamellar domain pitches (9 D 33 nm) were identified by small-angle X-ray scattering from neat BCPs containing 43 52 vol % PCHE ( f PCHE). Atomic force microscopy was used to show 7.5 nm lamellar features (D = 14.8 nm) which are some of the smallest observed to date. The lowest molar mass sample (Mn = 4.9 kg/mol, f PCHE = 0.46) is characterized by TODT = 173 3 C and sub-5 nm nanodomains, which together with the sacrificial properties of PMMA and the high overall thermal stability place this material at the forefront of high- systems for advanced nanopatterning applications.

  6. USDA National Urban and Community Forestry Challenge Cost Share...

    Broader source: Energy.gov (indexed) [DOE]

    5 5:00PM EST U.S. Department of Agriculture The U.S. Department of Agriculture is accepting proposals for the National Urban and Community Forestry Challenge Cost Share Grant...

  7. Long-term energy consumptions of urban transportation: A prospective...

    Open Energy Info (EERE)

    emissions, if and only if they are implemented in the framework of appropriate urban planning. LEDSGP green logo.png This tool is included in the Transportation Toolkit from...

  8. Study reveals urban smoke absorbs sunlight, exacerbating climate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provide a framework to capture them in climate models." The researchers used state-of-the-art instruments in field studies near London tracking an urban plume as it moved across...

  9. Property:PotentialUrbanUtilityScalePVGeneration | Open Energy...

    Open Energy Info (EERE)

    Quantity Description The estimated potential energy generation from utility-scale PV in urban areas of a particular place. Use this type to express a quantity of energy. The...

  10. Detecting and Blocking Network Attacks at Ultra High Speeds

    SciTech Connect (OSTI)

    Paxson, Vern

    2010-11-29

    Stateful, in-depth, in-line traffic analysis for intrusion detection and prevention has grown increasingly more difficult as the data rates of modern networks rise. One point in the design space for high-performance network analysis - pursued by a number of commercial products - is the use of sophisticated custom hardware. For very high-speed processing, such systems often cast the entire analysis process in ASICs. This project pursued a different architectural approach, which we term Shunting. Shunting marries a conceptually quite simple hardware device with an Intrusion Prevention System (IPS) running on commodity PC hardware. The overall design goal is was to keep the hardware both cheap and readily scalable to future higher speeds, yet also retain the unparalleled flexibility that running the main IPS analysis in a full general-computing environment provides. The Shunting architecture we developed uses a simple in-line hardware element that maintains several large state tables indexed by packet header fields, including IP/TCP flags, source and destination IP addresses, and connection tuples. The tables yield decision values the element makes on a packet-by-packet basis: forward the packet, drop it, or divert ('shunt') it through the IPS (the default). By manipulating table entries, the IPS can, on a fine-grained basis: (i) specify the traffic it wishes to examine, (ii) directly block malicious traffic, and (iii) 'cut through' traffic streams once it has had an opportunity to 'vet' them, or (iv) skip over large items within a stream before proceeding to further analyze it. For the Shunting architecture to yield benefits, it needs to operate in an environment for which the monitored network traffic has the property that - after proper vetting - much of it can be safely skipped. This property does not universally hold. For example, if a bank needs to examine all Web traffic involving its servers for regulatory compliance, then a monitor in front of one of the bank

  11. AVTA: Urban Electric Vehicle Specifications and Test Procedures |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Urban Electric Vehicle Specifications and Test Procedures AVTA: Urban Electric Vehicle Specifications and Test Procedures UEVAmerica Specifications (252.08 KB) ETA-UTP001 Implementation of SAE Standard J1263, Feb. 1996 - Road Load Measurement and Dynamometer Simulation Using Coastdown Techniques (50.53 KB) ETA-UTP002 Implementation of SAE Standard J1666, May 1993 - Electric Vehicle Acceleration, Gradeability, and Deceleration Test Procedure (65.68 KB) ETA-UTP003

  12. Developing micro-level urban ecosystem indicators for sustainability assessment

    SciTech Connect (OSTI)

    Dizdaroglu, Didem

    2015-09-15

    Sustainability assessment is increasingly being viewed as an important tool to aid in the shift towards sustainable urban ecosystems. An urban ecosystem is a dynamic system and requires regular monitoring and assessment through a set of relevant indicators. An indicator is a parameter which provides information about the state of the environment by producing a quantitative value. Indicator-based sustainability assessment needs to be considered on all spatial scales to provide efficient information of urban ecosystem sustainability. The detailed data is necessary to assess environmental change in urban ecosystems at local scale and easily transfer this information to the national and global scales. This paper proposes a set of key micro-level urban ecosystem indicators for monitoring the sustainability of residential developments. The proposed indicator framework measures the sustainability performance of urban ecosystem in 3 main categories including: natural environment, built environment, and socio-economic environment which are made up of 9 sub-categories, consisting of 23 indicators. This paper also describes theoretical foundations for the selection of each indicator with reference to the literature [Turkish] Highlights: • As the impacts of environmental problems have multi-scale characteristics, sustainability assessment needs to be considered on all scales. • The detailed data is necessary to assess local environmental change in urban ecosystems to provide insights into the national and global scales. • This paper proposes a set of key micro-level urban ecosystem indicators for monitoring the sustainability of residential developments. • This paper also describes theoretical foundations for the selection of each indicator with reference to the literature.

  13. National setting for productive conservation in urban transportation

    SciTech Connect (OSTI)

    Johnson, L.R.; LaBelle, S.J.

    1981-04-01

    The need for productive conservation strategies in urban transportation is discussed. Key trends in urban transportation are discussed as a basis for identifying target areas for productive conservation strategies. The need for and expected impacts of such candidate strategies as improvements in conventional automobiles, increases in automobile load factors, changes in highway and transit system operation, price-driven reductions in travel, and shifts to more-efficient modes are briefly outlined.

  14. High Performance Without Increased Cost: Urbane Homes, Louisville, KY -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Top Innovation | Department of Energy High Performance Without Increased Cost: Urbane Homes, Louisville, KY - Building America Top Innovation High Performance Without Increased Cost: Urbane Homes, Louisville, KY - Building America Top Innovation Photo of a Housing Award logo with a home. This Top Innovation highlights Building America field projects that demonstrated minimal or cost-neutral impacts for high-performance homes and that have significantly influenced the housing

  15. High-Pressure Micellar Solutions of Polystyrene-block-Polybutadiene and Polystyrene-block-Polyisoprene Solutions in Propane Exhibit Cloud-Pressure Reduction and Distinct Micellization End Points

    SciTech Connect (OSTI)

    Winoto, Winoto; Radosz, Maciej; Tan, Sugata; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical non-micellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size and ratio, and on the polymer concentration. For a given pressure, the micellization end-point temperature corresponds to the "critical micelle temperature." The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

  16. Sources and transport of nitrogen in arid urban watersheds

    SciTech Connect (OSTI)

    Hale, Rebecca L.; Turnbull, Laura; Earl, Stevan; Grimm, Nancy B.; Riha, Krystin M.; Michalski, Greg; Lohse, Kathleen; Childers, Daniel L.

    2014-06-03

    Urban watersheds are often sources of nitrogen (N) to downstream systems, contributing to poor water quality. However, it is unknown which components (e.g., land cover and stormwater infrastructure type) of urban watersheds contribute to N export and which may be sites of retention. In this study we investigated which watershed characteristics control N sourcing, biogeochemical processing of nitrate (NO3–) during storms, and the amount of rainfall N that is retained within urban watersheds. We used triple isotopes of NO3– (δ15N, δ18O, and Δ17O) to identify sources and transformations of NO3– during storms from 10 nested arid urban watersheds that varied in stormwater infrastructure type and drainage area. Stormwater infrastructure and land cover—retention basins, pipes, and grass cover—dictated the sourcing of NO3– in runoff. Urban watersheds can be strong sinks or sources of N to stormwater depending on the proportion of rainfall that leaves the watershed as runoff, but we found no evidence that denitrification occurred during storms. Our results suggest that watershed characteristics control the sources and transport of inorganic N in urban stormwater but that retention of inorganic N at the timescale of individual runoff events is controlled by hydrologic, rather than biogeochemical, mechanisms.

  17. Boston Architectural College Urban Sustainability Initiative

    SciTech Connect (OSTI)

    Byers, Arthur C.

    2013-07-31

    The Boston Architectural College's Urban Sustainability initiative is a demonstration project as defined by the National Energy Technology Laboratory. BAC's proposed project with the U.S. Department of Energy - NETL, is a large part of that overall initiative. The BAC's Urban Sustainability Initiative is a multi-part project with several important goals and objectives that will have a significant impact on the surrounding neighborhood including: energy conservation, reduction of storm water runoff, generation of power through alternative energy sources, elimination/reduction of BAC carbon footprint, and to create a vehicle for ongoing public outreach and education. Education and outreach opportunities will serve to add to the already comprehensive Sustainability Design courses offered at BAC relative to energy savings, performance and conservation in building design. At the finish of these essential capital projects there will be technical materials created for the education of the design, sustainability, engineering, community development and historic preservation communities, to inform a new generation of environmentally-minded designers and practitioners, the city of Boston and the general public. The purpose of the initiative, through our green renovations program, is to develop our green alley projects and energy saving renovations to the BAC physical plant, to serve as a working model for energy efficient design in enclosed 19th century and 20th century urban sites and as an educational laboratory for teaching ecological and sustainable technologies to students and the public while creating jobs. The scope of our project as it relates to the BAC and the U.S. Department of Energy- NETL combined efforts includes: Task I of the project is Phase II (Green Alley). Task I encompasses various renovation activities that will demonstrate the effectiveness of permeable paving and ground water recharge systems. It will aid in the reduction of storm water runoff into the

  18. Maintaining urban gas systems demands special technologies

    SciTech Connect (OSTI)

    Anglero, T.F. )

    1994-04-01

    Brooklyn Union Gas Co. has been providing gas to 50% of the population of New York City for the last 100 years. The company has constructed an elaborate gas distribution network that includes a gas main under nearly every city street in a service territory that includes Brooklyn, Staten Island and parts of Queens. Conventional ways of pipeline construction and maintenance are inadequate in today's environment of heightened competition, increased regulations and, most importantly, demanding customer expectations of quality service. As a result, Brooklyn Union Gas must use special construction and maintenance methods in its operations, and in particular trenchless technologies. Over the past 10 years the company has paid close attention to developing a variety of trenchless techniques. Like many gas distribution companies providing service in densely populated urban areas, Brooklyn Union must operate and maintain its gas distribution network in a challenging environment of increasing governmental regulation and escalating field construction costs. Technological innovation is not a luxury, but instead a necessity to achieve corporate growth, regulatory compliance and greater customer satisfaction. Trenchless technologies offset rising pipe installation costs and provide benefits both to the customer and the company. Of special value to Brooklyn Union is the development of systems that renovate old metal pipes by lining. Such techniques are described.

  19. Non-immunogenic, hydrophilic/cationic block copolymers and uses thereof

    DOE Patents [OSTI]

    Scales, Charles W.; Huang, Faqing; McCormick, Charles L.

    2010-05-18

    The present invention provides novel non-immunogenic, hydrophilic/cationic block copolymers comprising a neutral-hydrophilic polymer and a cationic polymer, wherein both polymers have well-defined chain-end functionality. A representative example of such a block copolymer comprises poly(N-(2-hydroxypropyl)methacrylamide) (PHPMA) and poly(N-[3-(dimethylamino)propyl]methacrylamide) (PDMAPMA). Also provided is a synthesis method thereof in aqueous media via reversible addition fragmentation chain transfer (RAFT) polymerization. Further provided are uses of these block copolymers as drug delivery vehicles and protection agents.

  20. Organic photosensitive cells having a reciprocal-carrier exciton blocking layer

    DOE Patents [OSTI]

    Rand, Barry P.; Forrest, Stephen R.; Thompson, Mark E.

    2007-06-12

    A photosensitive cell includes an anode and a cathode; a donor-type organic material and an acceptor-type organic material forming a donor-acceptor junction connected between the anode and the cathode; and an exciton blocking layer connected between the acceptor-type organic material of the donor-acceptor junction and the cathode, the blocking layer consisting essentially of a material that has a hole mobility of at least 10.sup.-7 cm.sup.2/V-sec or higher, where a HOMO of the blocking layer is higher than or equal to a HOMO of the acceptor-type material.

  1. Three-dimensional thermoelastic analysis of a Fort St. Vrain core support block

    SciTech Connect (OSTI)

    Butler, T.A.; Anderson, C.A.

    1981-09-01

    A thermoelastic stress analysis of a graphite core support block in the Fort St. Vrain High-Temperature Gas-Cooled Reactor is described. The support block is subjected to thermal stresses caused by a loss of forced circulation accident of the reactor system. Two- and three-dimensional finite element models of the core support block are analyzed using the ADINAT and ADINA codes, and results are given that verify the integrity of this structural component under the given accident condition. 10 refs., 39 figs.

  2. Interaction of Nocturnal Low-Level Jets with Urban Geometries as seen in Joint URBAN 2003 Data

    SciTech Connect (OSTI)

    K.Lundquist, J; D.Mirocha, J

    2006-09-06

    As accurate modeling of atmospheric flows in urban environments requires sophisticated representation of complex urban geometries, much work has been devoted to treatment of the urban surface. However, the importance of the larger-scale flow impinging upon the urban complex to the flow, transport and dispersion within it and downwind has received less attention. Building-resolving computational fluid dynamics (CFD) models are commonly employed to investigate interactions between the flow and three-dimensional structures comprising the urban environment, however such models are typically forced with simplified boundary conditions that fail to include important regional-scale phenomena that can strongly influence the flow within the urban complex and downwind. This paper investigates the interaction of an important and frequently occurring regional-scale phenomenon, the nocturnal low-level jet (LLJ), with urban-scale turbulence and dispersion in Oklahoma City using data from the Joint URBAN 2003 (JU2003) field experiment. Two simulations of nocturnal tracer release experiments from JU2003 using Lawrence Livermore National laboratory's FEM3MP CFD model yield differing levels of agreement with the observations in wind speed, turbulence kinetic energy (TKE) and concentration profiles in the urban wake, approximately 750m downwind of the central business district. Profiles of several observed turbulence parameters at this location indicate characteristics of both bottom-up and top-down boundary layers during each of the experiments. These data are consistent with turbulence production due to at least two sources, the complex flow structures of the urban area and the region of strong vertical wind shear occurring beneath the LLJs present each night. While strong LLJs occurred each night, their structures varied considerably, resulting in significant differences in the magnitudes of the turbulence parameters observed during the two experiments. As FEM3MP was forced only

  3. Testing of TAMU3: a Nb3Sn Block-Coil Dipole with Stress Management...

    Office of Scientific and Technical Information (OSTI)

    The Accelerator Research Lab (ARL) at Texas A&M has recently concluded the construction and testing of a superconducting block-coil dipole TAMU3. TAMU3 reached 85% of the ...

  4. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    enormous parameter space for the creation of new morphologies. Illustration from F.S. Bates and G.H. Fredrickson, "Block copolymers-designer soft materials," Physics Today 52, 32...

  5. Block entropy and quantum phase transition in the anisotropic Kondo necklace model

    SciTech Connect (OSTI)

    Mendoza-Arenas, J. J.; Franco, R.; Silva-Valencia, J.

    2010-06-15

    We study the von Neumann block entropy in the Kondo necklace model for different anisotropies {eta} in the XY interaction between conduction spins using the density matrix renormalization group method. It was found that the block entropy presents a maximum for each {eta} considered, and, comparing it with the results of the quantum criticality of the model based on the behavior of the energy gap, we observe that the maximum block entropy occurs at the quantum critical point between an antiferromagnetic and a Kondo singlet state, so this measure of entanglement is useful for giving information about where a quantum phase transition occurs in this model. We observe that the block entropy also presents a maximum at the quantum critical points that are obtained when an anisotropy {Delta} is included in the Kondo exchange between localized and conduction spins; when {Delta} diminishes for a fixed value of {eta}, the critical point increases, favoring the antiferromagnetic phase.

  6. Method of producing nanopatterned articles using surface-reconstructed block copolymer films

    DOE Patents [OSTI]

    Russell, Thomas P; Park, Soojin; Wang, Jia-Yu; Kim, Bokyung

    2013-08-27

    Nanopatterned surfaces are prepared by a method that includes forming a block copolymer film on a substrate, annealing and surface reconstructing the block copolymer film to create an array of cylindrical voids, depositing a metal on the surface-reconstructed block copolymer film, and heating the metal-coated block copolymer film to redistribute at least some of the metal into the cylindrical voids. When very thin metal layers and low heating temperatures are used, metal nanodots can be formed. When thicker metal layers and higher heating temperatures are used, the resulting metal structure includes nanoring-shaped voids. The nanopatterned surfaces can be transferred to the underlying substrates via etching, or used to prepare nanodot- or nanoring-decorated substrate surfaces.

  7. Well-defined PI-b-PAA/PS-b-PI-b-PAA Block Copolymers: Synthesis...

    Office of Scientific and Technical Information (OSTI)

    Media Citation Details In-Document Search Title: Well-defined PI-b-PAAPS-b-PI-b-PAA Block Copolymers: Synthesis and Their Self-Assembled Hierarchical Structures in Aqueous Media ...

  8. Nanoscale Building Blocks and DNA "Glue" Help Shape 3D Architectures...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Building Blocks and DNA "Glue" Help Shape 3D Architectures Basic Energy Sciences (BES) ... by the U.S. Department of Energy, Office of Science, Office of Basic Energy ...

  9. Energy Department Announces Energy Efficiency and Conservation Block Grant Program National Evaluation Results

    Broader source: Energy.gov [DOE]

    The Energy Department announced today the results of a major national evaluation of the Energy Efficiency and Conservation Block Grant (EECBG) program funded by the American Recovery and Reinvestment Act (ARRA).

  10. New Shielding Is Designed to Put the Block on Neutrons | Jefferson...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shielding Is Designed to Put the Block on Neutrons New Shielding Is Designed to Put the ... Their patented and patent-pending products are currently being installed in Hall C. New ...

  11. Funding Opportunity Announcement: Recovery Act … Energy Efficiency and Conversation Block Grants … Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE)

    Funding opportunity announcement for the Energy Efficiency and Conversation Block Grants, an opportunity open from March 26, 2009 to May 26, 2009 for state applicants and June 25, 2009 for local government and tribal applicants.

  12. How to create formatted blocks to hold OpenEI wiki content |...

    Open Energy Info (EERE)

    format, which you can see in use on the OpenEI frontpage. As an example of the migration, please see below. You can see that classes after "block-v1" moved in addition to...

  13. Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE)

    U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Energy Efficiency and Conservation Block Grant (EECBG) Program Guidance 10-011 dealing with formula grants.

  14. Video compression of coronary angiograms based on discrete wavelet transform with block classification

    SciTech Connect (OSTI)

    Ho, B.K.T.; Tsai, M.J.; Wei, J.; Ma, M.; Saipetch, P.

    1996-12-01

    A new method of video compression for angiographic images has been developed to achieve high compression ratio ({approximately}20:1) while eliminating block artifacts which leads to loss of diagnostic accuracy. This method adopts motion picture experts group`s (MPEG`s) motion compensated prediction to take advantage of frame to frame correlation. However, in contrast to MPEG, the error images arising from mismatches in the motion estimation are encoded by discrete wavelet transform (DWT) rather than block discrete cosine transform (DCT). Furthermore, the authors developed a classification scheme which label each block in an image as intra, error, or background type and encode it accordingly. This hybrid coding can significantly improve the compression efficiency in certain cases. This method can be generalized for any dynamic image sequences applications sensitive to block artifacts.

  15. Environmental geological input into urban construction planning

    SciTech Connect (OSTI)

    Berry, W.B.N. . Dept. of Geology and Geophysics)

    1992-01-01

    Environmental issues resulting from planning new construction in urban areas requires understanding of geological processes at many steps in project development. Steps include: assessments of geological characteristics of the proposed construction site, building design features in light of the geological characteristics, development of the geology component of the EIR as well as any mitigations required, and writing special environmental geological concerns into specifications required of the contractor. The latter step may be exemplified in planning a new underground library being constructed in the center of the Berkeley Campus. The site is within 50 yards of a creek that has been restored such that fish now live in it whereas none could three years ago. Runoff from paved parking lots and walkways around existing buildings goes into storm drains that empty directly into the creek. Because they do, creek water is monitored for chemical and solid wastes as well as turbidity. Based on geological input, special project procedures were written to which the contractor must adhere during site preparation and construction. These include: all liquid wastes must be contained in impermeable containers, all hazardous wastes must be removed under state waste removal guidelines, dewatering procedures were developed to remove groundwater that flows through permeable sands and gravels from the creek bed into the construction site and must be followed, and soil flux into the creek must be prevented. Mitigation of soil flux includes watering areas of the site as soil is excavated. Watering must be monitored because the contractor tends to overwater which flushes soil down nearby storm drains into the creek. As well, soil control monitoring includes preventing the contractor from sweeping soil into the storm drains and flushing it into the creek. Geological input has proven valuable in addressing different environmental concerns.

  16. Road Blocks Yield Key Information about a Catalyst | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Road Blocks Yield Key Information about a Catalyst Researchers systematically blocked key chemical reaction pathways to get unambiguous information about how carbon-nitrogen bonds are formed in a catalytic reaction known as hydroamination. Understanding a multi-step catalytic mechanism is like a solving a puzzle where you can't see the pieces. However, you can add your own "pieces" with known shapes to figure out what other pieces of the puzzle then will (or will not) fit.

  17. US-Guided Femoral and Sciatic Nerve Blocks for Analgesia During Endovenous Laser Ablation

    SciTech Connect (OSTI)

    Yilmaz, Saim Ceken, Kagan; Alimoglu, Emel; Sindel, Timur

    2013-02-15

    Endovenous laser ablation may be associated with significant pain when performed under standard local tumescent anesthesia. The purpose of this study was to investigate the efficacy of femoral and sciatic nerve blocks for analgesia during endovenous ablation in patients with lower extremity venous insufficiency. During a 28-month period, ultrasound-guided femoral or sciatic nerve blocks were performed to provide analgesia during endovenous laser ablation in 506 legs and 307 patients. The femoral block (n = 402) was performed at the level of the inguinal ligament, and the sciatic block at the posterior midthigh (n = 124), by injecting a diluted lidocaine solution under ultrasound guidance. After the blocks, endovenous laser ablations and other treatments (phlebectomy or foam sclerotherapy) were performed in the standard fashion. After the procedures, a visual analogue pain scale (1-10) was used for pain assessment. After the blocks, pain scores were 0 or 1 (no pain) in 240 legs, 2 or 3 (uncomfortable) in 225 legs, and 4 or 5 (annoying) in 41 legs. Patients never experienced any pain higher than score 5. The statistical analysis revealed no significant difference between the pain scores of the right leg versus the left leg (p = 0.321) and between the pain scores after the femoral versus sciatic block (p = 0.7). Ultrasound-guided femoral and sciatic nerve blocks may provide considerable reduction of pain during endovenous laser and other treatments, such as ambulatory phlebectomy and foam sclerotherapy. They may make these procedures more comfortable for the patient and easier for the operator.

  18. Power Block R&D for CSP Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Power Block R&D for CSP Systems Power Block R&D for CSP Systems Power plant components and systems for concentrating solar power (CSP) benefit from a mature and well-understood technology found elsewhere in the power generation industry. The most common cycles employed by conventional CSP plants include subcritical Rankine and Stirling. Gross thermal-to-electric conversion efficiencies are typically 35%-45%. Working fluids include steam, hydrogen, and helium. The primary driver for

  19. Polysulfide-Blocking Polymer Membrane for Li-S Batteries - Joint Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Research August 3, 2015, Research Highlights Polysulfide-Blocking Polymer Membrane for Li-S Batteries The microporous network allows the passage of smaller moieties such as solvent molecules, LiTFSI, and lithium ions while forbidding the passage of larger polysulfides (Li2Sx). Scientific Achievement Polymers of Intrinsic Microporosity are harnessed as an ion-selective membrane, effectively blocking polysulfide crossover due to its microporous molecular-sieving network.

  20. Preventive maintenance system for the photomultiplier detector blocks of pet scanners

    DOE Patents [OSTI]

    Levy, Alejandro V.; Warner, Donald

    1995-01-24

    A system including a method and apparatus for preventive maintenance of PET scanner photomultiplier detector blocks is disclosed. The quantitive comparisons used in the method of the present invention to provide an indication in the form of a display or printout advising the user that the photomultiplier block is stable, intermittently unstable, or drifting unstable, and also advising of the expected date of failure of a photomultiplier block in the PET scanner. The system alerts the user to replace the defective photomultiplier block prior to catastrophic failure in a scheduled preventative maintenance program, thus eliminating expensive and unscheduled downtime of the PET scanner due to photomultiplier failure. The apparatus for carrying out the method of the present invention preferably resides in the host computer controlling a PET scanner. It includes a memory adapted for storing a record of a number of iterative adjustments that are necessary to calibrate the gain of a photomultiplier detector block i at a time t.sub.0, a time t.sub.1 and a time T, where T>t.sub.1 >t.sub.0, which is designated as Histo(i,j(t)). The apparatus also includes a processor configured by a software program or a combination of programmed RAM and ROM devices to perform a number of calculations and operations on these values, and also includes a counter for analyzing each photomultiplier detector block i=1 through I of a PET scanner.

  1. Preventive maintenance system for the photomultiplier detector blocks of PET scanners

    DOE Patents [OSTI]

    Levy, A.V.; Warner, D.

    1995-01-24

    A system including a method and apparatus for preventive maintenance of PET scanner photomultiplier detector blocks is disclosed. The qualitative comparisons used in the method of the present invention to provide an indication in the form of a display or printout advising the user that the photomultiplier block is stable, intermittently unstable, or drifting unstable, and also advising of the expected date of failure of a photomultiplier block in the PET scanner. The system alerts the user to replace the defective photomultiplier block prior to catastrophic failure in a scheduled preventative maintenance program, thus eliminating expensive and unscheduled downtime of the PET scanner due to photomultiplier failure. The apparatus for carrying out the method of the present invention preferably resides in the host computer controlling a PET scanner. It includes a memory adapted for storing a record of a number of iterative adjustments that are necessary to calibrate the gain of a photomultiplier detector block i at a time t[sub 0], a time t[sub 1] and a time T, where T>t[sub 1]>t[sub 0], which is designated as Histo(i,j(t)). The apparatus also includes a processor configured by a software program or a combination of programmed RAM and ROM devices to perform a number of calculations and operations on these values, and also includes a counter for analyzing each photomultiplier detector block i=1 through I of a PET scanner. 40 figures.

  2. Report card on low level ozone in urban areas

    SciTech Connect (OSTI)

    Onischak, M.

    1994-12-31

    It has been four years since the Clean Air Act was amended in November of 1990. Much work has been done in this time, and the country is beginning to see real air quality benefits. Although these changes have not completely licked the urban ozone problem yet, they have made a lot of progress. All of the urban areas which have been required to reduce their ozone levels have done a good job of lowering their emissions. While the urban areas have not all been able to meet every federal deadline, the areas have all been able to achieve the control milestones before the mandatory Clean Air Act sanctions have taken effect. Some areas are even ready to declare their ozone problems solved.

  3. Past successes and future challenges: Improving the urban environment

    SciTech Connect (OSTI)

    Gade, M.

    1994-12-31

    The author discusses issues related to the Chicago urban environment from her perspective in the Illinois Environmental Protection Agency. Understanding of the ozone air pollution problem in the Chicago area has undergone significant changes in the past three years, and there is still more to be understood about the complex factors which contribute to ozone pollution over urban areas such as Chicago. Ability to address these problems to present clean air standards is not in hand at present. The author asserts that information, and the ability of governmental agencies to ingest and respond to that information in a timely manner is a key to improvement of the environment in urban areas in reasonable time spans. In addition cost and price information on environmental control and protection needs to be more clearly presented to the people so they can understand the difficult choices which must be made in addressing these environmental problems.

  4. Childhood leukemia and residential proximity to industrial and urban sites

    SciTech Connect (OSTI)

    García-Pérez, Javier; López-Abente, Gonzalo; Gómez-Barroso, Diana; Morales-Piga, Antonio; Pardo Romaguera, Elena; Tamayo, Ibon; Fernández-Navarro, Pablo; and others

    2015-07-15

    Background: Few risk factors for the childhood leukemia are well established. While a small fraction of cases of childhood leukemia might be partially attributable to some diseases or ionizing radiation exposure, the role of industrial and urban pollution also needs to be assessed. Objectives: To ascertain the possible effect of residential proximity to both industrial and urban areas on childhood leukemia, taking into account industrial groups and toxic substances released. Methods: We conducted a population-based case–control study of childhood leukemia in Spain, covering 638 incident cases gathered from the Spanish Registry of Childhood Tumors and for those Autonomous Regions with 100% coverage (period 1990-2011), and 13,188 controls, individually matched by year of birth, sex, and autonomous region of residence. Distances were computed from the respective subject’s residences to the 1068 industries and the 157 urban areas with ≥10,000 inhabitants, located in the study area. Using logistic regression, odds ratios (ORs) and 95% confidence intervals (95%CIs) for categories of distance to industrial and urban pollution sources were calculated, with adjustment for matching variables. Results: Excess risk of childhood leukemia was observed for children living near (≤2.5 km) industries (OR=1.31; 95%CI=1.03–1.67) – particularly glass and mineral fibers (OR=2.42; 95%CI=1.49–3.92), surface treatment using organic solvents (OR=1.87; 95%CI=1.24–2.83), galvanization (OR=1.86; 95%CI=1.07–3.21), production and processing of metals (OR=1.69; 95%CI=1.22–2.34), and surface treatment of metals (OR=1.62; 95%CI=1.22–2.15) – , and urban areas (OR=1.36; 95%CI=1.02–1.80). Conclusions: Our study furnishes some evidence that living in the proximity of industrial and urban sites may be a risk factor for childhood leukemia. - Highlights: • We studied proximity to both industrial and urban sites on childhood leukemia. • We conducted a case–control study in

  5. Synthesis of manganese oxide supported on mesoporous titanium oxide: Influence of the block copolymer

    SciTech Connect (OSTI)

    Schmit, F.; Bois, L.; Chiriac, R.; Toche, F.; Chassagneux, F.; Besson, M.; Descorme, C.; Khrouz, L.

    2015-01-15

    Manganese oxides supported on mesoporous titanium oxides were synthesized via a sol–gel route using block copolymer self-assembly. The oxides were characterized by X-ray diffraction, infrared spectroscopy, thermal analyses, nitrogen adsorption/desorption, electron microscopy and electronic paramagnetic resonance. A mesoporous anatase containing amorphous manganese oxide particles could be obtained with a 0.2 Mn:Ti molar ratio. At higher manganese loading (0.5 Mn:Ti molar ratio), segregation of crystalline manganese oxide occurred. The influence of block copolymer and manganese salt on the oxide structure was discussed. The evolution of the textural and structural characteristics of the materials upon hydrothermal treatment was also investigated. - Graphical abstract: One-pot amorphous MnO{sub 2} supported on mesoporous anataseTiO{sub 2}. - Highlights: • Mesoporous manganese titanium oxides were synthesized using block copolymer. • Block copolymers form complexes with Mn{sup 2+} from MnCl{sub 2}. • With block copolymer, manganese oxide can be dispersed around the titania crystallites. • With Mn(acac){sub 2}, manganese is dispersed inside titania. • MnOOH crystallizes outside mesoporous titania during hydrothermal treatment.

  6. Building America Whole-House Solutions for New Homes: Urbane Homes,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Louisville, Kentucky | Department of Energy Urbane Homes, Louisville, Kentucky Building America Whole-House Solutions for New Homes: Urbane Homes, Louisville, Kentucky Case study of Urbane Homes who worked with Building America research partner NAHBRC to build HERS-57 homes with rigid foam insulated slabs and foundation walls, advanced framed walls, high-efficiency heat pumps, and ducts in conditioned space. Urbane Homes - Louisville, KY (668.24 KB) More Documents & Publications High

  7. Millisecond ordering of block-copolymer films via photo-thermal gradients

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in lessmore » than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.« less

  8. Computer simulation of shading and blocking: Discussion of accuracy and recommendations

    SciTech Connect (OSTI)

    Lipps, F W

    1992-04-01

    A field of heliostats suffers losses caused by shading and blocking by neighboring heliostats. The complex geometry of multiple shading and blocking events suggests that a processing code is needed to update the boundary vector for each shading or blocking event. A new version, RSABS, (programmer`s manual included) simulates the split-rectangular heliostat. Researchers concluded that the dominant error for the given heliostat geometry is caused by the departure from planarity of the neighboring heliostats. It is recommended that a version of the heliostat simulation be modified to include losses due to nonreflective structural margins, if they occur. Heliostat neighbors should be given true guidance rather than assumed to be parallel, and the resulting nonidentical quadrilateral images should be processed, as in HELIOS, by ignoring overlapping events, rare in optimized fields.

  9. Millisecond ordering of block-copolymer films via photo-thermal gradients

    SciTech Connect (OSTI)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in less than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.

  10. Influence of shape and skin of matrix-rock blocks on pressure transients in fractured reservoirs

    SciTech Connect (OSTI)

    de Swaan, A.

    1986-01-01

    A formulation of pressure transients in terms of the intrinsic, or core, properties of the two media that compose the fractured reservoir, establishes the influence of these properties, and reciprocally, their corroboration from - the pressure-time relationship observed in well tests and interference tests. The following reservoir characteristics are analyzed: the area of fractures transverse to flow; the dimensions, shape and properties of rectangular parallelepiped matrix-rock blocks; and a permeability reduction in the blocks surface. A restatement of the so-called pseudo-steady state inter-media flow gives to parameters alfa and lambda in the theory of a previous study the physical meaning they lacked, and allows a direct determination of the blocks minimum dimension.

  11. Ordered porous mesostructured materials from nanoparticle-block copolymer self-assembly

    DOE Patents [OSTI]

    Warren, Scott; Wiesner, Ulrich; DiSalvo, Jr., Francis J

    2013-10-29

    The invention provides mesostructured materials and methods of preparing mesostructured materials including metal-rich mesostructured nanoparticle-block copolymer hybrids, porous metal-nonmetal nanocomposite mesostructures, and ordered metal mesostructures with uniform pores. The nanoparticles can be metal, metal alloy, metal mixture, intermetallic, metal-carbon, metal-ceramic, semiconductor-carbon, semiconductor-ceramic, insulator-carbon or insulator-ceramic nanoparticles, or combinations thereof. A block copolymer/ligand-stabilized nanoparticle solution is cast, resulting in the formation of a metal-rich (or semiconductor-rich or insulator-rich) mesostructured nanoparticle-block copolymer hybrid. The hybrid is heated to an elevated temperature, resulting in the formation of an ordered porous nanocomposite mesostructure. A nonmetal component (e.g., carbon or ceramic) is then removed to produce an ordered mesostructure with ordered and large uniform pores.

  12. Role of surface characteristics in urban meteorology and air quality

    SciTech Connect (OSTI)

    Sailor, D.J.

    1993-08-01

    Urbanization results in a landscape with significantly modified surface characteristics. The lower values of reflectivity to solar radiation, surface moisture availability, and vegetative cover, along with the higher values of anthropogenic heat release and surface roughness combine to result higher air temperatures in urban areas relative to their rural counterparts. Through their role in the surface energy balance and surface exchange processes, these surface characteristics are capable of modifying the local meteorology. The impacts on wind speeds, air temperatures, and mixing heights are of particular importance, as they have significant implications in terms of urban energy use and air quality. This research presents several major improvements to the meteorological modeling methodology for highly heterogeneous terrain. A land-use data-base is implemented to provide accurate specification of surface characteristic variability in simulations of the Los Angeles Basin. Several vegetation parameterizations are developed and implemented, and a method for including anthropogenic heat release into the model physics is presented. These modeling advancements are then used in a series of three-dimensional simulations which were developed to investigate the potential meteorological impact of several mitigation strategies. Results indicate that application of moderate tree-planting and urban-lightening programs in Los Angeles may produce summertime air temperature reductions on the order of 4{degree}C with a concomitant reduction in air pollution. The analysis also reveals several mechanisms whereby the application of these mitigation strategies may potentially increase pollutant concentrations. The pollution and energy use consequences are discussed in detail.

  13. Urban Options Solar Greenhouse Demonstration Project. Final report

    SciTech Connect (OSTI)

    Cipparone, L.

    1980-10-15

    The following are included: the design process, construction, thermal performance, horticulture, educational activities, and future plans. Included in appendices are: greenhouse blueprints, insulating curtain details, workshop schedules, sample data forms, summary of performance calculations on the Urban Options Solar Greenhouse, data on vegetable production, publications, news articles on th Solar Greenhouse Project, and the financial statement. (MHR)

  14. Safety in urban environment and emergency notice boards

    SciTech Connect (OSTI)

    Confortini, Claudia; Tira, Maurizio

    2008-07-08

    Reliable and safe urban system conditions have to be a crucial goal of ordinary planning activities. Among planning goals, priority must be given to indications relating to the safety levels to be achieved and to the amount of resources to be directed towards reducing the vulnerability of urban systems and therefore of the measures to be taken. Uban vulnerability cannot in fact be reduced to the sum of the vulnerability of single buildings or to the physical vulnerability of its various components. This research work consists of identifying those urban sub-areas that are important for safety in relation to natural risks, ambits that should be highlighted by means of permanent emergency notice boards/billboards. What are the hazard notices relating to all natural hazards and related risks? Where are they located? Are they clear and straightforward so that all residents and visitors are able to understand them, as it is already the case for road signs (or at least it should be)? What urban sub-areas are worth highlighting in relation to natural risks, acting for example as escape routes or meeting points? How is information for the public managed in order that people are immediately, easily and regularly notified? What is the relation of such signals to ordinary traffic signals? Research into the state of the art of permanent notice boards/billboards of this type, currently distinguished only by sporadic and local initiatives, aims at carrying out a census of and recognizing urban elements already considered as important for reducing the vulnerability of the urban system to different natural calamities and at providing new highlights as regards the identification of new ones. The next step is to work out a decision and common-language strategy for planning these elements and for their adequate signposting, so as to be able to live in the urban environment with awareness, safety and confidence, including with respect to more remote and therefore often neglected

  15. Block Diagram Simulator to Solve a User-Defined Network of Differential Equatios

    Energy Science and Technology Software Center (OSTI)

    1996-12-18

    BDBSIM simulates control and protection systems found in fossil and nuclear power plants. The software is based on the identification of a general equation form that encompasses all control and protection equations encountered in these plants. The user enters his equations in block diagram form as a collection of individual dynamic function, logic, and table blocks. Constructing plant control equations in this manner is analogous to setting up an analog computer for simulation. The capabilitymore » is thus sufficiently general for use in modeling a wide variety of control and protection systems.« less

  16. Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents

    DOE Patents [OSTI]

    Aldissi, M.

    1984-06-27

    An electrically conductive block copolymer of polyisoprene and polyacetylene and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I/sub 2/ to give it an electrical conductivity in the metallic regime.

  17. Capitol Area East End, Block 225: California Department of Education Headquarters

    High Performance Buildings Database

    Sacramento, CA The California Department of Education Headquarters, Block 225 was the first of the five buildings to make up the Capitol Area East End Complex. The entire project is being developed by the California Department of General Services Real Estate Division. At 336,000 square feet and six stories high, Block 225 was the most ambitious green-building initiative to have been undertaken by the State at that time and the largest office building project ever undertaken by the State. The project was delivered through a bridged design-build process.

  18. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  19. Guidance for Energy Efficiency and Conservation Block Grant Grantees on Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds

    Broader source: Energy.gov [DOE]

    Guidance for Energy Efficiency and Conservation Block Grant Program grantees regarding Qualified Energy Conservation Bonds (QECBs) and New Clean Renewable Energy Bonds (New CREBs)

  20. Efficient block processing of long duration biotelemetric brain data for health care monitoring

    SciTech Connect (OSTI)

    Soumya, I.; Zia Ur Rahman, M.; Rama Koti Reddy, D. V.; Lay-Ekuakille, A.

    2015-03-15

    In real time clinical environment, the brain signals which doctor need to analyze are usually very long. Such a scenario can be made simple by partitioning the input signal into several blocks and applying signal conditioning. This paper presents various block based adaptive filter structures for obtaining high resolution electroencephalogram (EEG) signals, which estimate the deterministic components of the EEG signal by removing noise. To process these long duration signals, we propose Time domain Block Least Mean Square (TDBLMS) algorithm for brain signal enhancement. In order to improve filtering capability, we introduce normalization in the weight update recursion of TDBLMS, which results TD-B-normalized-least mean square (LMS). To increase accuracy and resolution in the proposed noise cancelers, we implement the time domain cancelers in frequency domain which results frequency domain TDBLMS and FD-B-Normalized-LMS. Finally, we have applied these algorithms on real EEG signals obtained from human using Emotive Epoc EEG recorder and compared their performance with the conventional LMS algorithm. The results show that the performance of the block based algorithms is superior to the LMS counter-parts in terms of signal to noise ratio, convergence rate, excess mean square error, misadjustment, and coherence.

  1. Compact microwave lamp having a tuning block and a dielectric located in a lamp cavity

    DOE Patents [OSTI]

    Simpson, James E.

    2000-01-01

    A microwave lamp having a compact structure utilizing a coupling slot which has a dielectric member extending therethrough and a tuning block adjoining the coupling slot. A non-conventional waveguide is used which has about the width of a WR-284 waveguide and about the length of a WR-340 waveguide.

  2. Task Parallel Incomplete Cholesky Factorization using 2D Partitioned-Block Layout

    SciTech Connect (OSTI)

    Kim, Kyungjoo; Rajamanickam, Sivasankaran; Stelle, George Widgery; Edwards, Harold C.; Olivier, Stephen Lecler

    2016-01-01

    We introduce a task-parallel algorithm for sparse incomplete Cholesky factorization that utilizes a 2D sparse partitioned-block layout of a matrix. Our factorization algorithm follows the idea of algorithms-by-blocks by using the block layout. The algorithm-byblocks approach induces a task graph for the factorization. These tasks are inter-related to each other through their data dependences in the factorization algorithm. To process the tasks on various manycore architectures in a portable manner, we also present a portable tasking API that incorporates different tasking backends and device-specific features using an open-source framework for manycore platforms i.e., Kokkos. A performance evaluation is presented on both Intel Sandybridge and Xeon Phi platforms for matrices from the University of Florida sparse matrix collection to illustrate merits of the proposed task-based factorization. Experimental results demonstrate that our task-parallel implementation delivers about 26.6x speedup (geometric mean) over single-threaded incomplete Choleskyby- blocks and 19.2x speedup over serial Cholesky performance which does not carry tasking overhead using 56 threads on the Intel Xeon Phi processor for sparse matrices arising from various application problems.

  3. Lattice QCD Thermodynamics : 10k analysis with 1k thermalziation and block size of 500.

    SciTech Connect (OSTI)

    Soltz, R; Vranas, P; Gupta, R

    2007-05-10

    This is a re-analysis of the Lattice QCD Thermodynamics p4rhcm new beta analysis (UCRL-TR-230742) with approximately 10k trajectories per beta point, rerun with thermalization cut at 1000, and a block size of 500. Some diagnostic text has been omitted to reduce the number of pages.

  4. Energy Efficiency and Conservation Block Grant Program National Evaluation Executive Summary

    Office of Energy Efficiency and Renewable Energy (EERE)

    This document presents findings from an evaluation of the Energy Efficiency and Conservation Block Grant Program, a national program operated by the U.S. Department of Energy from 2009 to 2015 that provided grants and technical assistance to local governments, states and territories to support a wide variety of energy efficiency and renewable energy activities.

  5. A block matching-based registration algorithm for localization of locally advanced lung tumors

    SciTech Connect (OSTI)

    Robertson, Scott P.; Weiss, Elisabeth; Hugo, Geoffrey D.

    2014-04-15

    Purpose: To implement and evaluate a block matching-based registration (BMR) algorithm for locally advanced lung tumor localization during image-guided radiotherapy. Methods: Small (1 cm{sup 3}), nonoverlapping image subvolumes (“blocks”) were automatically identified on the planning image to cover the tumor surface using a measure of the local intensity gradient. Blocks were independently and automatically registered to the on-treatment image using a rigid transform. To improve speed and robustness, registrations were performed iteratively from coarse to fine image resolution. At each resolution, all block displacements having a near-maximum similarity score were stored. From this list, a single displacement vector for each block was iteratively selected which maximized the consistency of displacement vectors across immediately neighboring blocks. These selected displacements were regularized using a median filter before proceeding to registrations at finer image resolutions. After evaluating all image resolutions, the global rigid transform of the on-treatment image was computed using a Procrustes analysis, providing the couch shift for patient setup correction. This algorithm was evaluated for 18 locally advanced lung cancer patients, each with 4–7 weekly on-treatment computed tomography scans having physician-delineated gross tumor volumes. Volume overlap (VO) and border displacement errors (BDE) were calculated relative to the nominal physician-identified targets to establish residual error after registration. Results: Implementation of multiresolution registration improved block matching accuracy by 39% compared to registration using only the full resolution images. By also considering multiple potential displacements per block, initial errors were reduced by 65%. Using the final implementation of the BMR algorithm, VO was significantly improved from 77% ± 21% (range: 0%–100%) in the initial bony alignment to 91% ± 8% (range: 56%–100%;p < 0

  6. Theory for dynamical self arrest and gelation in microemulsions and the block copolymer systems

    SciTech Connect (OSTI)

    Wu, Sangwook

    2005-05-01

    The main purpose of this work is to investigate the glassy behavior of microemulsions and block copolymers. The origin of glassy behavior in microemulsions and block copolymers is frustration due to a competition between short-range interaction and long range interaction. According to the charge frustrated Ising model, the competition between ferromagnetic interaction and antiferromagnetic interaction is the origin of frustration in microemulsions. The competition between entropic effects and stoichiometric constraints responsible for the formation of micelles in microemulsions can lead to the emergence of a self generated glassy behavior in these systems. In the block copolymer, the competition between the repulsive short range interaction between monomers in polymer chains and the long range interaction by chemical bonds can lead to the emergence of a self generated glassy behavior. The criteria for the fluctuation induced first order transition and our microemulsion and block copolymer glasses are essentially the same. Both are a consequence of the large phase space of low energy excitations (14) (62) (all states with momenta q which fulfill |q| = q{sub m}) and are of at the most a moderate supercooling of the liquid state is required. This is strongly supported by the observation in Ref. (14) that the metastable states which are first to appear at a fluctuation induced first order transition are the ones build by a superposition of large amplitude waves of wavenumber q{sub m}, but with random orientations and phases, i.e. just the ones which form the metastable states of our microemulsion and block copolymer glass. (38)

  7. West Delta Block 35 - rediscovery of a 23-year-old field

    SciTech Connect (OSTI)

    Coburn, G.W.; Beeney, K.E. )

    1993-09-01

    The federal leases on the continental shelf, offshore Gulf of Mexico, are mature in terms of development. Many fields are reaching their productive and/or economic limits as defined by their operators and are being released, resulting in excellent opportunities for independents who recognize the importance of modern technology and apply it to their evaluation process. West Delta Block 35 originally was divided into two leases. The northern one-quarter and the southern three-quarters were combined and the entire block was available at the 1992 lease sale. The West Delta Block 35 was evaluated using the following methods: history (leases, companies involved, and changing economic conditions); well records (production, tests, recompletions.previous permits, and related activity); well-log evaluation, including (1) correlation, (2) analysis using PC-based software with user-defined saturation equations and multiple models to determine hydrocarbon-bearing zones, and (3) integration with all other available data; seismic evaluation, including (1) interpretation using workstation technology, (2) modeling various horizons using well data, (3) integration with well-log data; reservoir evaluation (pressure data, sand parameters, volumetrics, etc.). It was determined that significant reserves remained in an updip position on the northern one-quarter of the block in two reservoirs, with an additional reservoir having been penetrated but never produced. Additional potential on the southern part of the block was also recognized. The lease was acquired in the 1992 lease sale and the northern prospect was drilled in late 1992 and early 1993. The well found pay in three sands. Two sands were tested (prior to acidization) for a combined rate of 12.8 MMCFD, with the well still cleaning up. The well proved significant reserves in two previously produced reservoirs and added a new field pay.

  8. Urban stormwater management planning with analytical probabilistic models

    SciTech Connect (OSTI)

    Adams, B.J.

    2000-07-01

    Understanding how to properly manage urban stormwater is a critical concern to civil and environmental engineers the world over. Mismanagement of stormwater and urban runoff results in flooding, erosion, and water quality problems. In an effort to develop better management techniques, engineers have come to rely on computer simulation and advanced mathematical modeling techniques to help plan and predict water system performance. This important book outlines a new method that uses probability tools to model how stormwater behaves and interacts in a combined- or single-system municipal water system. Complete with sample problems and case studies illustrating how concepts really work, the book presents a cost-effective, easy-to-master approach to analytical modeling of stormwater management systems.

  9. Restoring our urban communities: A model for an empowered America

    SciTech Connect (OSTI)

    1995-08-01

    This booklet tells the story of how two very different types of organizations - Bethel New Life and Argonne National Laboratory - have forged a partnership to rebuild West Garfield Park. This unique Partnership blends Bethel`s theological and sociological roots with Argonne`s scientific and technological expertise. Together they hope to offer the community fresh, transferable approaches to solving urban socio-economic and environmental problems. The Partnership hopes to address and solve the inner city`s technological problems through community participation and collaborative demonstrations - without losing sight of the community`s social needs. The key themes throughout this booklet - jobs, sustainable community development, energy efficiency, and environment - highlight challenges the partners face. By bringing people and technologies together, this Partnership will give West Garfield Park residents a better life -- and, perhaps, offer other communities a successful model for urban renewal.

  10. Urban Heat Islands: Cool Roof Infrastructure | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cool Roof Infrastructure Urban Heat Islands: Cool Roof Infrastructure Lead Performer: Lawrence Berkeley National Laboratory - U.S.-China Clean Energy Research Center Project Partners: -- Guangdong Provincial Academy of Building Research - Guangdong, China -- Chongqing University - Chongqing, China -- Research Institute of Standards and Norms - China -- Chinese Academy of Sciences - Beijing, China DOE Funding: $795,000 Project Term: Jan. 2011 - Dec. 2015 Project Objective The U.S.-China Clean

  11. SCALING AN URBAN EMERGENCY EVACUATION FRAMEWORK: CHALLENGES AND PRACTICES

    SciTech Connect (OSTI)

    Karthik, Rajasekar; Lu, Wei

    2014-01-01

    Critical infrastructure disruption, caused by severe weather events, natural disasters, terrorist attacks, etc., has significant impacts on urban transportation systems. We built a computational framework to simulate urban transportation systems under critical infrastructure disruption in order to aid real-time emergency evacuation. This framework will use large scale datasets to provide a scalable tool for emergency planning and management. Our framework, World-Wide Emergency Evacuation (WWEE), integrates population distribution and urban infrastructure networks to model travel demand in emergency situations at global level. Also, a computational model of agent-based traffic simulation is used to provide an optimal evacuation plan for traffic operation purpose [1]. In addition, our framework provides a web-based high resolution visualization tool for emergency evacuation modelers and practitioners. We have successfully tested our framework with scenarios in both United States (Alexandria, VA) and Europe (Berlin, Germany) [2]. However, there are still some major drawbacks for scaling this framework to handle big data workloads in real time. On our back-end, lack of proper infrastructure limits us in ability to process large amounts of data, run the simulation efficiently and quickly, and provide fast retrieval and serving of data. On the front-end, the visualization performance of microscopic evacuation results is still not efficient enough due to high volume data communication between server and client. We are addressing these drawbacks by using cloud computing and next-generation web technologies, namely Node.js, NoSQL, WebGL, Open Layers 3 and HTML5 technologies. We will describe briefly about each one and how we are using and leveraging these technologies to provide an efficient tool for emergency management organizations. Our early experimentation demonstrates that using above technologies is a promising approach to build a scalable and high performance urban

  12. Joint Urban 2003: Study Overview And Instrument Locations

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2006-08-16

    Quality-assured meteorological and tracer data sets are vital for establishing confidence that indoor and outdoor dispersion models used to simulate dispersal of potential toxic agents in urban atmospheres are giving trustworthy results. The U.S. Department of Defense-Defense Threat Reduction Agency and the U.S. Department of Homeland Security joined together to conduct the Joint Urban 2003 atmospheric dispersion study to provide this critically-needed high-resolution dispersion data. This major urban study was conducted from June 28 through July 31, 2003, in Oklahoma City, Oklahoma, with the participation of over 150 scientists and engineers from over 20 U.S. and foreign institutions. The Joint Urban 2003 lead scientist was Jerry Allwine (Pacific Northwest National Laboratory) who oversaw study design, logistical arrangements and field operations with the help of Joe Shinn (Lawrence Livermore National Laboratory), Marty Leach (Lawrence Livermore National Laboratory), Ray Hosker (Atmospheric Turbulence and Diffusion Division), Leo Stockham (Northrop Grumman Information Technology) and Jim Bowers (Dugway Proving Grounds). This report gives a brief overview of the field campaign, describing the scientific objectives, the dates of the intensive observation periods, and the instruments deployed. The data from this field study is available to the scientific community through an on-line database that is managed by Dugway Proving Ground. This report will be included in the database to provide its users with some general information about the field study, and specific information about the instrument coordinates. Appendix A of this document provides the definitive record of the instrument locations during this field campaign, and Appendix B lists all the study principal investigators and participants.

  13. Transportation of radionuclides in urban environs: draft environmental assessment

    SciTech Connect (OSTI)

    Finley, N.C.; Aldrich, D.C.; Daniel, S.L.; Ericson, D.M.; Henning-Sachs, C.; Kaestner, P.C.; Ortiz, N.R.; Sheldon, D.D.; Taylor, J.M.

    1980-07-01

    This report assesses the environmental consequences of the transportation of radioactive materials in densely populated urban areas, including estimates of the radiological, nonradiological, and social impacts arising from this process. The chapters of the report and the appendices which follow detail the methodology and results for each of four causative event categories: incident free transport, vehicular accidents, human errors or deviations from accepted quality assurance practices, and sabotage or malevolent acts. The numerical results are expressed in terms of the expected radiological and economic impacts from each. Following these discussions, alternatives to the current transport practice are considered. Then, the detailed analysis is extended from a limited area of New York city to other urban areas. The appendices contain the data bases and specific models used to evaluate these impacts, as well as discussions of chemical toxicity and the social impacts of radioactive material transport in urban areas. The latter are evaluated for each causative event category in terms of psychological, sociological, political, legal, and organizational impacts. The report is followed by an extensive bibliography covering the many fields of study which were required in performing the analysis.

  14. Synthesis and Characterization of Stimuli Responsive Block Copolymers, Self-Assembly Behavior and Applications

    SciTech Connect (OSTI)

    Michael Duane Determan

    2005-12-17

    The central theme of this thesis work is to develop new block copolymer materials for biomedical applications. While there are many reports of stimuli-responsive amphiphilic [19-21] and crosslinked hydrogel materials [22], the development of an in situ gel forming, pH responsive pentablock copolymer is a novel contribution to the field, Figure 1.1 is a sketch of an ABCBA pentablock copolymer. The A blocks are cationic tertiary amine methacrylates blocked to a central Pluronic F127 triblock copolymer. In addition to the prerequisite synthetic and macromolecular characterization of these new materials, the self-assembled supramolecular structures formed by the pentablock were experimentally evaluated. This synthesis and characterization process serves to elucidate the important structure property relationships of these novel materials, The pH and temperature responsive behavior of the pentablock copolymer were explored especially with consideration towards injectable drug delivery applications. Future synthesis work will focus on enhancing and tuning the cell specific targeting of DNA/pentablock copolymer polyplexes. The specific goals of this research are: (1) Develop a synthetic route for gel forming pentablock block copolymers with pH and temperature sensitive properties. Synthesis of these novel copolymers is accomplished with ATRP, yielding low polydispersity and control of the block copolymer architecture. Well defined macromolecular characteristics are required to tailor the phase behavior of these materials. (2) Characterize relationship between the size and shape of pentablock copolymer micelles and gel structure and the pH and temperature of the copolymer solutions with SAXS, SANS and CryoTEM. (3) Evaluate the temperature and pH induced phase separation and macroscopic self-assembly phenomenon of the pentablock copolymer. (4) Utilize the knowledge gained from first three goals to design and formulate drug delivery formulations based on the multi

  15. A Study of the Effects of Different Urban Wind Models on Dispersion Patterns Using Joint Urban 2003 Data

    SciTech Connect (OSTI)

    Gowardhan, A A; Brown, M J

    2012-02-21

    The Quick Urban & Industrial Complex (QUIC) Dispersion Modeling System has been developed to rapidly compute the transport and dispersion of toxic agent releases in the vicinity of buildings. It is composed of a wind solver, an 'urbanized' Lagrangian random-walk model, and a graphical user interface. QUIC has two different wind models: (a) The QUIC-URB wind solver, an empirically-based diagnostic wind model and (b) The QUIC-CFD (RANS) solver, based on the 3D Reynolds-Averaged Navier-Stokes (RANS) equations. In this paper, we discuss the effect of different wind models on dispersion patterns in dense built-up areas. The model-computed wind from the two urban wind models- QUIC-URB and QUIC-CFD are used to drive the dispersion model. The concentration fields are then compared to measurements from the Oklahoma City Joint Urban 2003 field experiment. QUIC produces high-resolution 3-D mean wind and concentration fields around buildings, in addition to deposition on the ground and building surfaces. It has options for different release types, including point, moving point, line, area, and volumetric sources, as well as dense gas, explosive buoyant rise, multi-particle size, bioslurry, and two-phase releases. Other features include indoor infiltration, a pressure solver, outer grid simulations, vegetative canopies, and population exposure calculations. It has been used for biological agent sensor siting in cities, vulnerability assessments for heavier-than-air chemical releases at industrial facilities, and clean-up assessments for radiological dispersal device (RDD) releases in cities (e.g., see Linger et al., 2005; Brown, 2006a, b). QUIC has also been used for dust transport studies (Bowker et al., 2007a) and for the impact of highway sound barriers on the transport and dispersion of vehicle emissions (Bowker et al., 2007b).

  16. Dilute Group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2012-07-31

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  17. Dilute group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2015-02-24

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  18. Block copolymer with simultaneous electric and ionic conduction for use in lithium ion batteries

    DOE Patents [OSTI]

    2013-10-08

    Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction. A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO.sub.4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.

  19. Revisiting the blocking force test on ferroelectric ceramics using high energy x-ray diffraction

    SciTech Connect (OSTI)

    Daniel, L.; Hall, D. A.; Withers, P. J.; Koruza, J.; Webber, K. G.; King, A.

    2015-05-07

    The blocking force test is a standard test to characterise the properties of piezoelectric actuators. The aim of this study is to understand the various contributions to the macroscopic behaviour observed during this experiment that involves the intrinsic piezoelectric effect, ferroelectric domain switching, and internal stress development. For this purpose, a high energy diffraction experiment is performed in-situ during a blocking force test on a tetragonal lead zirconate titanate (PZT) ceramic (Pb{sub 0.98}Ba{sub 0.01}(Zr{sub 0.51}Ti{sub 0.49}){sub 0.98}Nb{sub 0.02}O{sub 3}). It is shown that the usual macroscopic linear interpretation of the test can also be performed at the single crystal scale, allowing the identification of local apparent piezoelectric and elastic properties. It is also shown that despite this apparent linearity, the blocking force test involves significant non-linear behaviour mostly due to domain switching under electric field and stress. Although affecting a limited volume fraction of the material, domain switching is responsible for a large part of the macroscopic strain and explains the high level of inter- and intra-granular stresses observed during the course of the experiment. The study shows that if apparent piezoelectric and elastic properties can be identified for PZT single crystals from blocking stress curves, they may be very different from the actual properties of polycrystalline materials due to the multiplicity of the physical mechanisms involved. These apparent properties can be used for macroscopic modelling purposes but should be considered with caution if a local analysis is aimed at.

  20. Relationship between Structural and Stress Relaxation in a Block-Copolymer Melt

    SciTech Connect (OSTI)

    Patel, Amish J.; Narayanan, Suresh; Sandy, Alec; Mochrie, Simon G. J.; Garetz, Bruce A.; Watanabe, Hiroshi; Balsara, Nitash P.

    2006-06-30

    The relationship between structural relaxation on molecular length scales and macroscopic stress relaxation was explored in a disordered block-copolymer melt. Experiments show that the structural relaxation time, measured by x-ray photon correlation spectroscopy is larger than the terminal stress relaxation time, measured by rheology, by factors as large as 100. We demonstrate that the structural relaxation data are dominated by the diffusion of intact micelles while the stress relaxation data are dominated by contributions due to disordered concentration fluctuations.

  1. Studying the Building Blocks of Matter: Public Talk Planned for Oct. 7 at

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jefferson Lab | Jefferson Lab Studying the Building Blocks of Matter: Public Talk Planned for Oct. 7 at Jefferson Lab Studying the Building locks of Matter: Public Talk Planned for Oct. 7 at Jefferson Lab CEBAF Race Track This aerial photo shows the outline of the racetrack-shaped CEBAF accelerator at Jefferson Lab, located in Newport News, Va.. NEWPORT NEWS, VA, Sept. 22, 2014 - In conjunction with Virginia Science Festival events around the Commonwealth, Jefferson Lab Staff Scientist

  2. Monitoring Plan for Weatherization Assistance Program, State Energy Program and Energy Efficiency and Conservation Block Grants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Revised: October 22, 2010 U.S. Department of Energy American Recovery and Reinvestment Act Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Appendix of Compliance Checklists Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants U.S. Department of Energy Appendix of Compliance Checklists October 22, 2010 Concurrences: LeAnn M. Oliver Program Manager, Weatherization &

  3. NATIONAL EVALUATION OF THE ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM Executive Summary Prepared for the US Department of Energy Under the Supervision of Oak Ridge National Laboratory Date: June 2015 DNV GL - Energy - www.dnvgl.com/energy ACKNOWLEDGEMENTS We would like to acknowledge the important contributions of the following people: Nick Hall of TecMarket Works was integrally involved with the EECBG National Evaluation from its inception: proposing a study approach; working with DOE and ORNL to prepare a

  4. K+ block is the mechanism of functional asymmetry in bacterial Nav channels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ngo, Van; Wang, Yibo; Haas, Stephan; Noskov, Sergei Y.; Farley, Robert A.; Weinstein, Harel

    2016-01-04

    Crystal structures of several bacterial Nav channels have been recently published and molecular dynamics simulations of ion permeation through these channels are consistent with many electrophysiological properties of eukaryotic channels. Bacterial Nav channels have been characterized as functionally asymmetric, and the mechanism of this asymmetry has not been clearly understood. To address this question, we combined non-equilibrium simulation data with two-dimensional equilibrium unperturbed landscapes generated by umbrella sampling and Weighted Histogram Analysis Methods for multiple ions traversing the selectivity filter of bacterial NavAb channel. This approach provided new insight into the mechanism of selective ion permeation in bacterial Nav channels.more » The non-equilibrium simulations indicate that two or three extracellular K+ ions can block the entrance to the selectivity filter of NavAb in the presence of applied forces in the inward direction, but not in the outward direction. The block state occurs in an unstable local minimum of the equilibrium unperturbed free-energy landscape of two K+ ions that can be ‘locked’ in place bymodest applied forces. In contrast to K+, three Na+ ions move favorably through the selectivity filter together as a unit in a loose “knock-on” mechanism of permeation in both inward and outward directions, and there is no similar local minimum in the two-dimensional free-energy landscape of two Na+ ions for a block state. The useful work predicted by the non-equilibrium simulations that is required to break the K+ block is equivalent to large applied potentials experimentally measured for two bacterial Nav channels to induce inward currents of K+ ions. Here, these results illustrate how inclusion of non-equilibrium factors in the simulations can provide detailed information about mechanisms of ion selectivity that is missing from mechanisms derived from either crystal structures or equilibrium unperturbed free

  5. The 1-AB block fields-a giant oil accumulation in Eastern Peru

    SciTech Connect (OSTI)

    Jarvis, H.A.; Lay, V. ); Orosco, C. )

    1993-02-01

    The 1-Ab block fields are located in the northeastern part of Peru. Geologically, the area is the sub-Andean Maranon Basin, a continuation of the Napo Basin from eastern Ecuador. During the 20 years that Occidental has operated Block 1-AB, approximately 11,500 km of seismic data has been recorded and 34 exploratory wells have been drilled, resulting in the discovery of 18 fields, or 53% exploration success. The 1-AB oil accumulation discovered in 1972 is a group of medium to small asymmetric anticlines distributed along six northwest-southeast trending structural alignments: North Capahuari-South Capahuari-Tambo, Carmen-North San Jaacinto and Bartra. This concentration of productive structures in a relative small area is unique within the Maranon basin. The controlling factors include exceptional pre-Cretaceous uplifting and the presence of very good to excellent Cretaceous sandstones reservoirs. The two major Cretaceous producing zones, the Chonta and Vivian sandstones, have been defined within the Coniacian and Campanian ages respectively. The Chonta sands are related to shelfal deposition across Block 1-AB, represented by strand plain and barrier island sediments. The Vivian formation is a massive fluvial sandstone covering all of the Maranon basin and ranging in thickness between 40 and 200 feet. After oil was accumulated, fresh water influxes into the reservoirs of the northern and eastern fields caused oil biodegradation and salinity variation of the reservoir waters, depending upon the intensity of biodegradation. Oil remigration also has been documented for the South Huayari field.

  6. A Cluster-based Method to Map Urban Area from DMSP/OLS Nightlights

    SciTech Connect (OSTI)

    Zhou, Yuyu; Smith, Steven J.; Elvidge, Christopher; Zhao, Kaiguang; Thomson, Allison M.; Imhoff, Marc L.

    2014-05-05

    Accurate information of urban areas at regional and global scales is important for both the science and policy-making communities. The Defense Meteorological Satellite Program/Operational Linescan System (DMSP/OLS) nighttime stable light data (NTL) provide a potential way to map urban area and its dynamics economically and timely. In this study, we developed a cluster-based method to estimate the optimal thresholds and map urban extents from the DMSP/OLS NTL data in five major steps, including data preprocessing, urban cluster segmentation, logistic model development, threshold estimation, and urban extent delineation. Different from previous fixed threshold method with over- and under-estimation issues, in our method the optimal thresholds are estimated based on cluster size and overall nightlight magnitude in the cluster, and they vary with clusters. Two large countries of United States and China with different urbanization patterns were selected to map urban extents using the proposed method. The result indicates that the urbanized area occupies about 2% of total land area in the US ranging from lower than 0.5% to higher than 10% at the state level, and less than 1% in China, ranging from lower than 0.1% to about 5% at the province level with some municipalities as high as 10%. The derived thresholds and urban extents were evaluated using high-resolution land cover data at the cluster and regional levels. It was found that our method can map urban area in both countries efficiently and accurately. Compared to previous threshold techniques, our method reduces the over- and under-estimation issues, when mapping urban extent over a large area. More important, our method shows its potential to map global urban extents and temporal dynamics using the DMSP/OLS NTL data in a timely, cost-effective way.

  7. Department of Housing and Urban Development-Independent Agencies Appropriations Bill, 1985

    SciTech Connect (OSTI)

    Not Available

    1984-01-01

    Federal aappropriations for the Department of Housing and Urban Development and for sundry independent agencies, boards, commissions, corporations, and offices are enumerated and discussed. Recommendations by the House Committee on Appropriations are given along with a detailed description of each program considered. Specific programs discussed include: urban research, urban development, urban planning, solar energy, environmental quality, space stations, space shuttle orbiters, scientific research and education, and selective service. This bill, H.R. 5713, makes appropriations for the fiscal year ending September 30, 1985.

  8. Urban Options Solar Greenhouse Project. Semi-annual technical progress report

    SciTech Connect (OSTI)

    Cipparone, L.

    1980-03-13

    The design changes and construction of the Urban Options Solar Greenhouse are described. The greenhouse performance and horticultural and educational activities are discussed. (MHR)

  9. How much of the world's land has been urbanized, really? A hierarchica...

    Office of Scientific and Technical Information (OSTI)

    "urban area" that is delineated by administrative boundaries, "built-up area" that is dominated by artificial surfaces, and "impervious surface area" that is devoid of life. ...

  10. Fact #902: December 7, 2015 Rural versus Urban Vehicle Miles of Travel by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State | Department of Energy 2: December 7, 2015 Rural versus Urban Vehicle Miles of Travel by State Fact #902: December 7, 2015 Rural versus Urban Vehicle Miles of Travel by State SUBSCRIBE to the Fact of the Week In the United States, the U.S. Department of Transportation classifies 3.9 million miles of roadway as rural and 1.2 million miles of roadway as urban. Each state has a different travel pattern affecting the proportion of vehicle miles traveled (VMT) on rural versus urban roads.

  11. Community Renewable Energy Success Stories: Wind Energy in Urban Environments Webinar (text version)

    Broader source: Energy.gov [DOE]

    Below is the text version of the Webinar titled "Community Renewable Energy Success Stories: Wind Energy in Urban Environments," originally presented on September 18, 2012.

  12. Thermally-induced transition of lamellae orientation in block-copolymer films on ‘neutral’ nanoparticle-coated substrates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yager, Kevin G.; Forrey, Christopher; Singh, Gurpreet; Satija, Sushil K.; Page, Kirt A.; Patton, Derek L.; Jones, Ronald L.; Karin, Alamgir; Douglas, Jack F.

    2015-06-01

    Block-copolymer orientation in thin films is controlled by the complex balance between interfacial free energies, including the inter-block segregation strength, the surface tensions of the blocks, and the relative substrate interactions. While block-copolymer lamellae orient horizontally when there is any preferential affinity of one block for the substrate, we recently described how nanoparticle-roughened substrates can be used to modify substrate interactions. We demonstrate how such ‘neutral’ substrates can be combined with control of annealing temperature to generate vertical lamellae orientations throughout a sample, at all thicknesses. We observe an orientational transition from vertical to horizontal lamellae upon heating, as confirmedmore » using a combination of atomic force microscopy (AFM), neutron reflectometry (NR) and rotational small-angle neutron scattering (RSANS). Using molecular dynamics (MD) simulations, we identify substrate-localized distortions to the lamellar morphology as the physical basis of the novel behavior. In particular, under strong segregation conditions, bending of horizontal lamellae induce a large energetic cost. At higher temperatures, the energetic cost of conformal deformations of lamellae over the rough substrate is reduced, returning lamellae to the typical horizontal orientation. Thus, we find that both surface interactions and temperature play a crucial role in dictating block-copolymer lamellae orientation. As a result, our combined experimental and simulation findings suggest that controlling substrate roughness should provide a useful and robust platform for controlling block-copolymer orientation in applications of these materials.« less

  13. Thermally-induced transition of lamellae orientation in block-copolymer films on ‘neutral’ nanoparticle-coated substrates

    SciTech Connect (OSTI)

    Yager, Kevin G.; Forrey, Christopher; Singh, Gurpreet; Satija, Sushil K.; Page, Kirt A.; Patton, Derek L.; Jones, Ronald L.; Karin, Alamgir; Douglas, Jack F.

    2015-06-01

    Block-copolymer orientation in thin films is controlled by the complex balance between interfacial free energies, including the inter-block segregation strength, the surface tensions of the blocks, and the relative substrate interactions. While block-copolymer lamellae orient horizontally when there is any preferential affinity of one block for the substrate, we recently described how nanoparticle-roughened substrates can be used to modify substrate interactions. We demonstrate how such ‘neutral’ substrates can be combined with control of annealing temperature to generate vertical lamellae orientations throughout a sample, at all thicknesses. We observe an orientational transition from vertical to horizontal lamellae upon heating, as confirmed using a combination of atomic force microscopy (AFM), neutron reflectometry (NR) and rotational small-angle neutron scattering (RSANS). Using molecular dynamics (MD) simulations, we identify substrate-localized distortions to the lamellar morphology as the physical basis of the novel behavior. In particular, under strong segregation conditions, bending of horizontal lamellae induce a large energetic cost. At higher temperatures, the energetic cost of conformal deformations of lamellae over the rough substrate is reduced, returning lamellae to the typical horizontal orientation. Thus, we find that both surface interactions and temperature play a crucial role in dictating block-copolymer lamellae orientation. As a result, our combined experimental and simulation findings suggest that controlling substrate roughness should provide a useful and robust platform for controlling block-copolymer orientation in applications of these materials.

  14. Comparing urban solid waste recycling from the viewpoint of urban metabolism based on physical input-output model: A case of Suzhou in China

    SciTech Connect (OSTI)

    Liang Sai; Zhang Tianzhu

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Impacts of solid waste recycling on Suzhou's urban metabolism in 2015 are analyzed. Black-Right-Pointing-Pointer Sludge recycling for biogas is regarded as an accepted method. Black-Right-Pointing-Pointer Technical levels of reusing scrap tires and food wastes should be improved. Black-Right-Pointing-Pointer Other fly ash utilization methods should be exploited. Black-Right-Pointing-Pointer Secondary wastes from reusing food wastes and sludge should be concerned. - Abstract: Investigating impacts of urban solid waste recycling on urban metabolism contributes to sustainable urban solid waste management and urban sustainability. Using a physical input-output model and scenario analysis, urban metabolism of Suzhou in 2015 is predicted and impacts of four categories of solid waste recycling on urban metabolism are illustrated: scrap tire recycling, food waste recycling, fly ash recycling and sludge recycling. Sludge recycling has positive effects on reducing all material flows. Thus, sludge recycling for biogas is regarded as an accepted method. Moreover, technical levels of scrap tire recycling and food waste recycling should be improved to produce positive effects on reducing more material flows. Fly ash recycling for cement production has negative effects on reducing all material flows except solid wastes. Thus, other fly ash utilization methods should be exploited. In addition, the utilization and treatment of secondary wastes from food waste recycling and sludge recycling should be concerned.

  15. Evaluation study of building-resolved urban dispersion models

    SciTech Connect (OSTI)

    Flaherty, Julia E.; Allwine, K Jerry; Brown, Mike J.; Coirier, WIlliam J.; Ericson, Shawn C.; Hansen, Olav R.; Huber, Alan H.; Kim, Sura; Leach, Martin J.; Mirocha, Jeff D.; Newsom, Rob K.; Patnaik, Gopal; Senocak, Inanc

    2007-09-10

    For effective emergency response and recovery planning, it is critically important that building-resolved urban dispersion models be evaluated using field data. Several full-physics computational fluid dynamics (CFD) models and semi-empirical building-resolved (SEB) models are being advanced and applied to simulating flow and dispersion in urban areas. To obtain an estimate of the current state-of-readiness of these classes of models, the Department of Homeland Security (DHS) funded a study to compare five CFD models and one SEB model with tracer data from the extensive Midtown Manhattan field study (MID05) conducted during August 2005 as part of the DHS Urban Dispersion Program (UDP; Allwine and Flaherty 2007). Six days of tracer and meteorological experiments were conducted over an approximately 2-km-by-2-km area in Midtown Manhattan just south of Central Park in New York City. A subset of these data was used for model evaluations. The study was conducted such that an evaluation team, independent of the six modeling teams, provided all the input data (e.g., building data, meteorological data and tracer release rates) and run conditions for each of four experimental periods simulated. Tracer concentration data for two of the four experimental periods were provided to the modeling teams for their own evaluation of their respective models to ensure proper setup and operation. Tracer data were not provided for the second two experimental periods to provide for an independent evaluation of the models. The tracer concentrations resulting from the model simulations were provided to the evaluation team in a standard format for consistency in inter-comparing model results. An overview of the model evaluation approach will be given followed by a discussion on the qualitative comparison of the respective models with the field data. Future model developments efforts needed to address modeling gaps identified from this study will also be discussed.

  16. Measuring and Mitigating Urban Warming in a Northern Metropolitan Area |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Measuring and Mitigating Urban Warming in a Northern Metropolitan Area Event Sponsor: Environmental Science Seminar Start Date: Aug 25 2016 - 11:00am Building/Room: Building 240/Room 4301 Location: Argonne National Laboratory Speaker(s): Peter Snyder Speaker(s) Title: University of Minnesota In the United States and much of the rest of the world, cities are warming at twice the rate of outlying rural areas and the planet as a whole. While the warming can

  17. Valuing the Environmental Benefits of Urban WaterConservation

    SciTech Connect (OSTI)

    Coughlin, Katie M.; Bolduc, Chris A.; Chan, Peter T.; Dunham-Whitehead, C.; Van Buskirk, R.D.

    2007-05-01

    This report documents a project undertaken for theCalifornia Urban Water Conservation Council (the Council) to create a newmethod of accounting for the diverse environmental benefits of raw watersavings. The environmental benefits (EB) model was designed to providewater utilities with a practical tool that they can use to assign amonetary value to the benefits that may accrue from implementing any ofthe Council-recommended Best Management Practices. The model treats onlyenvironmental services associated directly with water, and is intended tocover miscellaneous impacts that are not currently accounted for in anyother cost-benefit analysis.

  18. Acquisition and registration of aerial video imagery of urban traffic

    SciTech Connect (OSTI)

    Loveland, Rohan C

    2008-01-01

    The amount of information available about urban traffic from aerial video imagery is extremely high. Here we discuss the collection of such video imagery from a helicopter platform with a low-cost sensor, and the post-processing used to correct radial distortion in the data and register it. The radial distortion correction is accomplished using a Harris model. The registration is implemented in a two-step process, using a globally applied polyprojective correction model followed by a fine scale local displacement field adjustment. The resulting cleaned-up data is sufficiently well-registered to allow subsequent straight-forward vehicle tracking.

  19. Tectonic boundaries of the eastern Gulf Coast of North America

    SciTech Connect (OSTI)

    Leonard, C. Jr.; Phillips, R.R. )

    1993-09-01

    Two Precambrian extensional fault episodes, recorded in mapping from central Arkansas across Mississippi, central Alabama, southern Georgia, and into the Atlantic Ocean affected later Pennsylvanian and Triassic tectonics. This interpretation is from magnetic anomaly data and is supported by seismic, gravity, core, and well-log data. The fault system was first suspected from an anomalous magnetic high, representing a feature that affected tectonism during the Ouachita and the Alleghenian orogenies of the eastern Gulf Coast and southeastern United States. The northernmost upthrown block is considered part of an ancient passive continental margin developed during the late Precambrian. The southern downthrown block is deformed by left-lateral transverse faults active during the Ouachita Orogeny. The Ouachita Orogeny may have deformed terrain farther east than the Black Worrior basin. These transverse fault blocks were buttressed by the footwall of the extensional fault system. These left-lateral faults extending from Florida and Georgia into Alabama, Mississippi, and southern Arkansas.

  20. A decision-support system for sustainable urban metabolism in Europe

    SciTech Connect (OSTI)

    Gonzalez, Ainhoa; Donnelly, Alison; Jones, Mike; Chrysoulakis, Nektarios; Lopes, Myriam

    2013-01-15

    Urban metabolism components define the energy and material exchanges within a city and, therefore, can provide valuable information on the environmental quality of urban areas. Assessing the potential impact of urban planning alternatives on urban metabolism components (such as energy, water, carbon and pollutants fluxes) can provide a quantitative estimation of their sustainability performance. Urban metabolism impact assessment can, therefore, contribute to the identification of sustainable urban structures with regards, for example, to building types, materials and layout, as well as to location and capacity of transportation and infrastructural developments. In this way, it enables the formulation of planning and policy recommendations to promote efficient use of resources and enhance environmental quality in urban areas. The European FP7 project BRIDGE (sustainaBle uRban plannIng Decision support accountinG for urban mEtabolism) has developed a decision-support system (DSS) that systematically integrates urban metabolism components into impact assessment processes with the aim of accurately quantifying the potential effects of proposed planning interventions. The DSS enables integration of multiple spatial and non-spatial datasets (e.g. physical flows of energy and material with variables of social and economic change) in a systematic manner to obtain spatially defined assessment results and to thus inform planners and decision-makers. This multi-criteria approach also enables incorporation of stakeholders' perceptions in order to prioritise decisive assessment criteria. This paper describes the methodological framework used to develop the DSS and critically examines the results of its practical application in five European cities. - Highlights: Black-Right-Pointing-Pointer Urban metabolism in sustainability assessment of planning alternatives. Black-Right-Pointing-Pointer European FP7 project applied to 5 real life case studies across Europe. Black

  1. Dynamically reassigning a connected node to a block of compute nodes for re-launching a failed job

    DOE Patents [OSTI]

    Budnik, Thomas A.; Knudson, Brant L.; Megerian, Mark G.; Miller, Samuel J.; Stockdell, William M.

    2012-03-20

    Methods, systems, and products for dynamically reassigning a connected node to a block of compute nodes for re-launching a failed job that include: identifying that a job failed to execute on the block of compute nodes because connectivity failed between a compute node assigned as at least one of the connected nodes for the block of compute nodes and its supporting I/O node; and re-launching the job, including selecting an alternative connected node that is actively coupled for data communications with an active I/O node; and assigning the alternative connected node as the connected node for the block of compute nodes running the re-launched job.

  2. Blocking effect of crystalglass interface in lanthanum doped barium strontium titanate glassceramics

    SciTech Connect (OSTI)

    Wang, Xiangrong; Zhang, Yong; Baturin, Ivan; Liang, Tongxiang

    2013-10-15

    Graphical abstract: The blocking effect of the crystalglass interface on the carrier transport behavior in the lanthanum doped barium strontium titanate glassceramics: preparation and characterization. - Highlights: La{sub 2}O{sub 3} addition promotes the crystallization of the major crystalline phase. The Z? and M? peaks exist a significant mismatch for 0.5 mol% La{sub 2}O{sub 3} addition. The Z? and M? peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. Crystallite impedance decreases while crystalglass interface impedance increases. La{sub 2}O{sub 3} addition increases blocking factor of the crystalglass interface. - Abstract: The microstructures and dielectric properties in La{sub 2}O{sub 3}-doped barium strontium titanate glassceramics have been investigated by scanning electron microscopy (SEM) and impedance spectroscopy. SEM analysis indicated that La{sub 2}O{sub 3} additive decreases the average crystallite size. Impedance spectroscopy revealed that the positions of Z? and M? peaks are close for undoped samples. When La{sub 2}O{sub 3} concentration is 0.5 mol%, the Z? and M? peaks show a significant mismatch. Furthermore, these peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. With increasing La{sub 2}O{sub 3} concentration, the contribution of the crystallite impedance becomes smaller, while the contribution of the crystalglass interface impedance becomes larger. More interestingly, it was found that La{sub 2}O{sub 3} additive increases blocking factor of the crystalglass interface in the temperature range of 250450 C. This may be attributed to a decrease of activation energy of the crystallite and an increase of the crystalglass interface area.

  3. Trace metals in urban streams and detention ponds

    SciTech Connect (OSTI)

    Licsko, Z.J.; Struger, J.

    1995-12-31

    Trace metal levels were monitored over a nine month period in two urban creeks in the Hamilton Harbour watershed and in two urban stormwater retention ponds in Guelph, Ontario. Samples were collected both during dry or non-event periods and immediately after wet weather events. Both water and surficial sediment samples were collected and tested for cadmium, copper, lead, mercury, nickel, and zinc. In almost all cases during wet weather conditions, Canadian Water Quality Guidelines for the protection of freshwater aquatic life were exceeded in water for lead (>7 mg/L), copper (>4 mg/L), and zinc (>30 mg/L) . Both stormwater ponds accumulated trace metals in sediment to levels above the lowest effect level guideline for the protection and management of aquatic sediment in Ontario, and, in the case of zinc (> 820 ug/g), above the severe effect level guideline. These levels of contamination raise serious concerns about the use of these and similar facilities as habitat for biota.

  4. Urban lake sediment chemistry: Lake design, runoff, and watershed impact

    SciTech Connect (OSTI)

    Amalfi, F.A.

    1988-01-01

    Sediments of twenty-two urban lakes and stormwater discharge into five of the impoundments were analyzed for the presence of selected metallic priority pollutants, total petroleum hydrocarbons, and volatile and extractable organic compounds. The concentration (mg/kg dry weight) ranges of metals in lake sediments were: arsenic 7-29, cadmium < 0.5-0.5, chromium 14-55, lead <1-138, selenium <0.01-1.1, silver 0.2-2.1, copper 25-2760, nickel 5-40, and zinc 33.9-239. Concentrations of total petroleum hydrocarbons ranged from 30 to 4400 mg/kg (wet weight). Organic priority pollutants detected in the urban lake impoundments included tetrachlorethylene, 1,1,2-trichloroethane, trichlorofluoromethane, phthalate esters, chloroform, and dichlorobromomethane. Stormwater runoff contained measurable quantities of arsenic, chromium, lead, selenium, copper, nickel, zinc, and petroleum hydrocarbons; whereas organic priority pollutants were not detected. Stormwater runoff pollutant loads indicated that runoff provides a significant contribution of metals and petroleum hydrocarbons to lake sediments.

  5. Pathways for the Oxidation of Sarin in Urban Atmospheres

    SciTech Connect (OSTI)

    Gerald E. Streit; James E. Bossert; Jeffrey S. Gaffney; Jon Reisner; Laurie A. McNair; Michael Brown; Scott Elliott

    1998-11-01

    Terrorists have threatened and carried out chemicalhiological agent attacks on targets in major cities. The nerve agent sarin figured prominently in one well-publicized incident. Vapors disseminating from open containers in a Tokyo subway caused thousands of casualties. High-resolution tracer transport modeling of agent dispersion is at hand and will be enhanced by data on reactions with components of the urban atmosphere. As a sample of the level of complexity currently attainable, we elaborate the mechanisms by which sarin can decompose in polluted air. A release scenario is outlined involving the passage of a gas-phase agent through a city locale in the daytime. The atmospheric chemistry database on related organophosphorus pesticides is mined for rate and product information. The hydroxyl,radical and fine-mode particles are identified as major reactants. A review of urban air chernistry/rnicrophysics generates concentration tables for major oxidant and aerosol types in both clean and dirty environments. Organic structure-reactivity relationships yield an upper limit of 10-1' cm3 molecule-' S-* for hydrogen abstraction by hydroxyl. The associated midday loss time scale could be as little as one hour. Product distributions are difficult to define but may include nontoxic organic oxygenates, inorganic phosphorus acids, sarin-like aldehydes, and nitrates preserving cholinergic capabilities. Agent molecules will contact aerosol surfaces in on the order of minutes, with hydrolysis and side-chain oxidation as likely reaction channels.

  6. Nanoporous polysulfone membranes via a degradable block copolymer precursor for redox flow batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gindt, Brandon P.; Abebe, Daniel G.; Tang, Zhijiang J.; Lindsey, Melanie B.; Chen, Jihua; Elgammal, Ramez A.; Zawodzinski, Thomas A.; Fujiwara, Tomoko

    2016-01-01

    In this study, nanoporous polysulfone (PSU) membranes were fabricated via post-hydrolysis of polylactide (PLA) from PLA–PSU–PLA triblock copolymer membranes. The PSU scaffold was thermally crosslinked before sacrificing PLA blocks. The resulting nanopore surface was chemically modified with sulfonic acid moieties. The membranes were analyzed and evaluated as separators for vanadium redox flow batteries. Nanoporous PSU membranes prepared by this new method and further chemically modified to a slight degree exhibited unique behavior with respect to their ionic conductivity when exposed to solutions of increasing acid concentration.

  7. Interpenetrating metal-organic frameworks formed by self-assembly of tetrahedral and octahedral building blocks

    SciTech Connect (OSTI)

    Lu Yongming; Lan Yaqian; Xu Yanhong; Su Zhongmin; Li Shunli; Zang Hongying; Xu Guangjuan

    2009-11-15

    To investigate the relationship between topological types and molecular building blocks (MBBs), we have designed and synthesized a series of three-dimensional (3D) interpenetrating metal-organic frameworks based on different polygons or polyhedra under hydrothermal conditions, namely [Cd(bpib){sub 0.5}(L{sup 1})] (1), [Cd(bpib){sub 0.5}(L{sup 2})].H{sub 2}O (2), [Cd(bpib){sub 0.5}(L{sup 3})] (3) and [Cd(bib){sub 0.5}(L{sup 1})] (4), where bpib=1,4-bis(2-(pyridin-2-yl)-1H-imidazol-1-yl)butane, bib=1,4-bis(1H-imidazol-1-yl)butane, H{sub 2}L{sup 1}=4-(4-carboxybenzyloxy)benzoic acid, H{sub 2}L{sup 2}=4,4'-(ethane-1,2-diylbis(oxy))dibenzoic acid and H{sub 2}L{sup 3}=4,4'-(1,4-phenylenebis(methylene))bis(oxy)dibenzoic acid, respectively. Their structures have been determined by single crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectra, and thermogravimetric (TG) analyses. Compounds 1-3 display alpha-Po topological nets with different degrees of interpenetration based on the similar octahedral [Cd{sub 2}(-COO){sub 4}] building blocks. Compound 4 is a six-fold interpenetrating diamondoid net based on tetrahedral MBBs. By careful inspection of these structures, we find that various carboxylic ligands and N-donor ligands with different coordination modes and conformations, and metal centers with different geometries are important for the formation of the different MBBs. It is believed that different topological types lie on different MBBs with various polygons or polyhedra. Such as four- and six-connected topologies are formed by tetrahedral and octahedral building blocks. In addition, with the increase of carboxylic ligands' length, the degrees of interpenetration have been changed in the alpha-Po topological nets. And the luminescent properties of these compounds have been investigated in detail. - Graphical abstract: A series of three-dimensional interpenetrating metal-organic frameworks based on different polygons or polyhedra

  8. Nanoporous polysulfone membranes via a degradable block copolymer precursor for redox flow batteries

    SciTech Connect (OSTI)

    Gindt, Brandon P.; Abebe, Daniel G.; Tang, Zhijiang J.; Lindsey, Melanie B.; Chen, Jihua; Elgammal, Ramez A.; Zawodzinski, Thomas A.; Fujiwara, Tomoko

    2016-01-01

    In this study, nanoporous polysulfone (PSU) membranes were fabricated via post-hydrolysis of polylactide (PLA) from PLA–PSU–PLA triblock copolymer membranes. The PSU scaffold was thermally crosslinked before sacrificing PLA blocks. The resulting nanopore surface was chemically modified with sulfonic acid moieties. The membranes were analyzed and evaluated as separators for vanadium redox flow batteries. Nanoporous PSU membranes prepared by this new method and further chemically modified to a slight degree exhibited unique behavior with respect to their ionic conductivity when exposed to solutions of increasing acid concentration.

  9. Primary arm spacing in chill block melt spun Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient.

  10. Enzymatic Ligation Creates Discrete Multi-Nanoparticle Building Blocks for Self-Assembly

    SciTech Connect (OSTI)

    Claridge, Shelley A.; Mastroianni, Alexander J.; Au, Yeung B.; Liang, Huiyang W.; Micheel, Christine M.; Frechet, Jean M.J.; Alivisatos, A. Paul

    2008-05-27

    Enzymatic ligation of discrete nanoparticle?DNA conjugates creates nanoparticle dimer and trimer structures in which the nanoparticles are linked by single-stranded DNA, rather than double-stranded DNA as in previous experiments. Ligation is verified by agarose gel and small-angle X-ray scattering. This capability is utilized in two ways: first to create a new class of multiparticle building blocks for nanoscale self-assembly; second to develop a system which can amplify a population of discrete nanoparticle assemblies.

  11. Analysis of slot cutting methods for the Yucca Mountain heated block test using a compliant-joint model

    SciTech Connect (OSTI)

    Chen, E.P.; Costin, L.S.

    1991-12-31

    Pretest analysis of a heated block test, proposed for the Exploratory Studies Facility at Yucca Mountain, Nevada, was conducted in this investigation. Specifically, the study focuses on the evaluation of the various designs to drill holes and cut slots for the block. The thermal/mechanical analysis was based on the finite element method and a compliant-joint rock-mass constitutive model. Based on the calculated results, relative merits of the various test designs are discussed.

  12. Five-years of microenvironment data along an urban-rural transect; temperature and CO2 concentrations in urban area at levels expected globally with climate change.

    SciTech Connect (OSTI)

    George, Kate; Ziska, Lewis H; Bunce, James A; Quebedeaux, Bruno

    2007-11-01

    The heat island effect and the high use of fossil fuels in large city centers is well documented, but by how much fossil fuel consumption is elevating atmospheric CO2 concentrations and whether elevations in both atmospheric CO2 and air temperature are consistent from year to year are less well known. Our aim was to record atmospheric CO2 concentrations, air temperature and other environmental variables in an urban area and compare it to suburban and rural sites to see if urban sites are experiencing climates expected globally in the future with climate change. A transect was established from Baltimore city center (Urban site), to the outer suburbs of Baltimore (suburban site) and out to an organic farm (rural site). At each site a weather station was set-up to monitor environmental variables annually for five years. Atmospheric CO2 was significantly increased on average by 66 ppm from the rural to the urban site over the five years of the study. Air temperature was significantly higher at the urban site (14.8 oC) compared to the suburban (13.6 oC) and rural (12.7 oC) sites. Relative humidity was not different between sites but vapor pressure deficit (VPD) was significantly higher at the urban site compared to the suburban and rural sites. During wet years relative humidity was significantly increased and VPD significantly reduced. Increased nitrogen deposition at the rural site (2.1 % compared to 1.8 and 1.2 % at the suburban and urban sites) was small enough not to affect soil nitrogen content. Dense urban areas with large populations and high vehicular traffic have significantly different microclimates compared to outlying suburban and rural areas. The increases in atmospheric CO2 and air temperature are similar to changes predicted in the short term with global climate change, therefore providing an environment suitable for studying future effects of climate change on terrestrial ecosystems.

  13. Fact #775: April 15, 2013 Top Ten Urban Areas for Fuel Wasted due to Traffic Congestion, 2011

    Broader source: Energy.gov [DOE]

    The top ten urban areas across the U.S. accounted for nearly 40% of the total fuel wasted due to traffic congestion in 2011. Highway congestion caused vehicles in the combined urban areas of New...

  14. Decontamination of Terrorist-Dispersed Radionuclides from Surfaces in Urban Environments

    SciTech Connect (OSTI)

    Fischer, Robert; Sutton, Mark; Gates-Anderson, Dianne; Gray, Jeremy; Hu, Qinhong; McNab, Walt; Viani, Brian

    2008-01-15

    Research is currently underway at Lawrence Livermore National Laboratory (LLNL) to advance the basic scientific knowledge of radionuclide-substrate interactions in the urban environment. Investigations have focused on more optimized decontamination agents for cesium (Cs) and americium (Am) specifically for use in mass transit infrastructure and urban environments. This project is designed to enhance the capability of the United States to effectively respond to a Radiological Dispersal Device (RDD) attack. The work addresses recognized data gaps by advancing the basic scientific knowledge of radionuclide-substrate interactions in the urban environment and provides a solution to a national need. The research is focused in four major areas: (1) a better understanding of urban surface conditions that influence the efficacy of decontamination processes, (2) development of prototype decontamination agents for Am and Cs optimized for use in urban environments, (3) the development of capabilities to realistically contaminate surfaces at both the real world and laboratory scale and (4) a validated model for radionuclide-surface interactions. The decontamination of urban surfaces following the detonation of an RDD presents a number of challenges. The following key points are found to be critical for the efficiency of decontamination agents in an urban environment: - Particle size and surface deposition of radionuclide particles on urban surface materials. - Interactions between radionuclides and urban materials. - The presence of grime and carbonation/alteration layers on the surface of urban surfaces. - Post-detonation penetration of radionuclides strongly affected by the dynamic wetting/drying processes. A laboratory scale contamination system has been developed allowing for samples to be contaminated and radionuclide interactions to be studied. In combination with laboratory scale experiments, a real scale outdoor test is scheduled for the spring of 2007. In conclusion

  15. Process Controlled Multiscale Morphologies in Metal-containing Block Copolymer Thin Films

    SciTech Connect (OSTI)

    Ramanathan, Nathan Muruganathan [ORNL] [ORNL; Kilbey, II, S Michael [ORNL; Darling, Seth B. [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL)

    2014-01-01

    Poly(styrene-block-ferrocenyldimethylsilane) (PS-b-PFS) is a metal-containing block copolymer that exhibits certain advantages as a mask for lithographic applications. These advantages include compatibility with a wide range of substrates, ease of control over domain morphologies and robust stability to etch plasma, which aid in the development of high-aspect-ratio patterns. An asymmetric cylinder-forming PS-b-PFS copolymer is subjected to different processing to manipulate the morphology of the phase-separated domains. Control of film structure and domain morphology is achieved by adjusting the film thickness, mode of annealing, and/or annealing time. Changing the process from thermal or solvent annealing to hybrid annealing (thermal and then solvent annealing in sequence) leads to the formation of mesoscale spherulitic and dendritic morphologies. In this communication, we show that reversing the order of the hybrid annealing (solvent annealing first and then thermal annealing) of relatively thick films (>100 nm) on homogeneously thick substrates develops disordered lamellar structure. Furthermore, the same processing applied on a substrate with a thin, mechanically flexible window in the center leads to the formation of sub-micron scale concentric ring patterns. Enhanced material mobility in the thick film during hybrid annealing along with dynamic rippling effects that may arise from the vibration of the thin window during spin casting are likely causes for these morphologies.

  16. Development of flow network analysis code for block type VHTR core by linear theory method

    SciTech Connect (OSTI)

    Lee, J. H.; Yoon, S. J.; Park, J. W.; Park, G. C.

    2012-07-01

    VHTR (Very High Temperature Reactor) is high-efficiency nuclear reactor which is capable of generating hydrogen with high temperature of coolant. PMR (Prismatic Modular Reactor) type reactor consists of hexagonal prismatic fuel blocks and reflector blocks. The flow paths in the prismatic VHTR core consist of coolant holes, bypass gaps and cross gaps. Complicated flow paths are formed in the core since the coolant holes and bypass gap are connected by the cross gap. Distributed coolant was mixed in the core through the cross gap so that the flow characteristics could not be modeled as a simple parallel pipe system. It requires lot of effort and takes very long time to analyze the core flow with CFD analysis. Hence, it is important to develop the code for VHTR core flow which can predict the core flow distribution fast and accurate. In this study, steady state flow network analysis code is developed using flow network algorithm. Developed flow network analysis code was named as FLASH code and it was validated with the experimental data and CFD simulation results. (authors)

  17. Efficient Heterogeneous Execution on Large Multicore and Accelerator Platforms: Case Study Using a Block Tridiagonal Solver

    SciTech Connect (OSTI)

    Park, Alfred J; Perumalla, Kalyan S

    2013-01-01

    The algorithmic and implementation principles are explored in gainfully exploiting GPU accelerators in conjunction with multicore processors on high-end systems with large numbers of compute nodes, and evaluated in an implementation of a scalable block tridiagonal solver. The accelerator of each compute node is exploited in combination with multicore processors of that node in performing block-level linear algebra operations in the overall, distributed solver algorithm. Optimizations incorporated include: (1) an efficient memory mapping and synchronization interface to minimize data movement, (2) multi-process sharing of the accelerator within a node to obtain balanced load with multicore processors, and (3) an automatic memory management system to efficiently utilize accelerator memory when sub-matrices spill over the limits of device memory. Results are reported from our novel implementation that uses MAGMA and CUBLAS accelerator software systems simultaneously with ACML for multithreaded execution on processors. Overall, using 940 nVidia Tesla X2090 accelerators and 15,040 cores, the best heterogeneous execution delivers a 10.9-fold reduction in run time relative to an already efficient parallel multicore-only baseline implementation that is highly optimized with intra-node and inter-node concurrency and computation-communication overlap. Detailed quantitative results are presented to explain all critical runtime components contributing to hybrid performance.

  18. GaAs Blocked-Impurity-Band Detectors for Far-Infrared Astronomy

    SciTech Connect (OSTI)

    Cardozo, Benjamin Lewin

    2004-12-21

    High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing layer of a BIB detector, has been achieved. The control of the donor concentration, however, was found to be insufficient for detector production. The growth by LPE of a high-purity film onto a commercially grown vapor-phase epitaxial (VPE) n-type GaAs doped absorbing layer resulted in a BIB device that showed a significant reduction in the low-temperature dark current compared to the absorbing layer only. Extended optical response was not detected, most likely due to the high compensation of the commercially grown GaAs absorbing layer, which restricts the depletion width of the device.

  19. Neutral beamline with ion energy recovery based on magnetic blocking of electrons

    DOE Patents [OSTI]

    Stirling, W.L.

    1980-07-01

    A neutral beamline generator with energy recovery of the full-energy ion component of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the elecrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

  20. Neutral beamline with ion energy recovery based on magnetic blocking of electrons

    DOE Patents [OSTI]

    Stirling, William L.

    1982-01-01

    A neutral beamline generator with energy recovery of the full-energy ion ponent of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the electrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

  1. Quality assurance plan for the High Level Controller for the CBMS Block II

    SciTech Connect (OSTI)

    Reid, R.W.; Robbins, I.F.; Stewart, K.A.; Terry, C.L.; Whitaker, R.A.; Wolf, D.A.; Zager, J.C.

    1997-09-01

    This document establishes the software Quality Assurance Plan (QAP) for the High Level Controller for the Chemical and Biological Mass Spectrometer Block II (HLC/CBMS-II) project activities under the Computing, Robotics, and Education (CRE) Directorate management. It defines the requirements and assigns responsibilities for ensuring, with a high degree of confidence, that project objectives will be achieved as planned. The CBMS Program was awarded to ORNL by the US Army Chemical and Biological Defense command, Aberdeen Proving Ground, Maryland, to design the next version (Block II) mass spectrometer for the detection and identification of chemical and biological warfare agents, to fabricate four engineering prototypes, and to construct eight preproduction units. Section 1 of this document provides an introduction to the HLC/CBMS-II project QAP. Sections 2 and 3 describe the specific aspects of quality assurance as applicable to the project. Section 4 reviews the project approach to risk management. The Risk Management Matrix given in Appendix A is a tool to assess, prioritize, and prevent problems before they occur; therefore, the matrix will be reviewed and revised on a periodic basis. Appendix B shows the quality assurance criteria of the DOE Order 5700.6C and their applicability to this project.

  2. Climate Change and Infrastructure, Urban Systems, and Vulnerabilities

    SciTech Connect (OSTI)

    Wilbanks, Thomas J; Fernandez, Steven J

    2014-01-01

    This Technical Report on Climate Change and Infrastructure, Urban Systems, and Vulnerabilities has been prepared for the U.S. Department of Energy by the Oak Ridge National Laboratory in support of the U.S. National Climate Assessment (NCA). It is a summary of the currently existing knowledge base on its topic, nested within a broader framing of issues and questions that need further attention in the longer run. The report arrives at a number of assessment findings, each associated with an evaluation of the level of consensus on that issue within the expert community, the volume of evidence available to support that judgment, and the section of the report that provides an explanation for the finding. Cross-sectoral issues related to infrastructures and urban systems have not received a great deal of attention to date in research literatures in general and climate change assessments in particular. As a result, this technical report is breaking new ground as a component of climate change vulnerability and impact assessments in the U.S., which means that some of its assessment findings are rather speculative, more in the nature of propositions for further study than specific conclusions that are offered with a high level of confidence and research support. But it is a start in addressing questions that are of interest to many policymakers and stakeholders. A central theme of the report is that vulnerabilities and impacts are issues beyond physical infrastructures themselves. The concern is with the value of services provided by infrastructures, where the true consequences of impacts and disruptions involve not only the costs associated with the clean-up, repair, and/or replacement of affected infrastructures but also economic, social, and environmental effects as supply chains are disrupted, economic activities are suspended, and/or social well-being is threatened. Current knowledge indicates that vulnerability concerns tend to be focused on extreme weather events

  3. Instrumentation for slope stability -- Experience from an urban area

    SciTech Connect (OSTI)

    Flentje, P.; Chowdhury, R.

    1999-07-01

    This paper describes the monitoring of several existing landslides in an urban area near Wollongong in the state of New South Wales, Australia. A brief overview of topography and geology is given and reference is made to the types of slope movement, processes and causal factors. Often the slope movements are extremely slow and imperceptible to the eye, and catastrophic failures are quite infrequent. However, cumulative movements at these slower rates do, over time, cause considerable distress to structures and disrupt residential areas and transport routes. Inclinometers and piezometers have been installed at a number of locations and monitoring of these has been very useful. The performance of instrumentation at different sites is discussed in relation to the monitoring of slope movements and pore pressures. Interval rates of inclinometer shear displacement have been compared with various periods of cumulative rainfall to assess the relationships.

  4. Infrastructure Ecology for Sustainable and Resilient Urban Infrastructure Design

    SciTech Connect (OSTI)

    Jeong, Hyunju; Pandit, Arka; Crittenden, John; Xu, Ming; Perrings, Charles; Wang, Dali; Li, Ke; French, Steve

    2010-10-01

    The population growth coupled with increasing urbanization is predicted to exert a huge demand on the growth and retrofit of urban infrastructure, particularly in water and energy systems. The U.S. population is estimated to grow by 23% (UN, 2009) between 2005 and 2030. The corresponding increases in energy and water demand were predicted as 14% (EIA, 2009) and 20% (Elcock, 2008), respectively. The water-energy nexus needs to be better understood to satisfy the increased demand in a sustainable manner without conflicting with environmental and economic constraints. Overall, 4% of U.S. power generation is used for water distribution (80%) and treatment (20%). 3% of U.S. water consumption (100 billion gallons per day, or 100 BGD) and 40% of U.S. water withdrawal (340 BGD) are for thermoelectric power generation (Goldstein and Smith, 2002). The water demand for energy production is predicted to increase most significantly among the water consumption sectors by 2030. On the other hand, due to the dearth of conventional water sources, energy intensive technologies are increasingly in use to treat seawater and brackish groundwater for water supply. Thus comprehending the interrelation and interdependency between water and energy system is imperative to evaluate sustainable water and energy supply alternatives for cities. In addition to the water-energy nexus, decentralized or distributed concept is also beneficial for designing sustainable water and energy infrastructure as these alternatives require lesser distribution lines and space in a compact urban area. Especially, the distributed energy infrastructure is more suited to interconnect various large and small scale renewable energy producers which can be expected to mitigate greenhouse gas (GHG) emissions. In the case of decentralized water infrastructure, on-site wastewater treatment facility can provide multiple benefits. Firstly, it reduces the potable water demand by reusing the treated water for non-potable uses

  5. Evaluation of urban storm-water maintenance in North Carolina

    SciTech Connect (OSTI)

    Roenigk, D.J.; Paterson, R.G.; Heraty, M.A.; Kaiser, E.J.; Burby, R.J.

    1992-06-01

    Spurred by continuing urban growth and new federal mandates for control of nonpoint source pollution, local governments are increasingly concerned about the need to improve stormwater management. Long-term maintenance is a critical aspect of stormwater management if both water quality and water quantity benefits are to be realized in practice. The report examines what is actually being done in North Carolina cities to maintain stormwater systems and what selected stormwater experts feel should be done. Several actions are needed. First, local governments are recommended to pay greater attention to system planning, apply more stringent design standards, and monitor the effectiveness of structures protecting water quality as the most critical basis for successful long-term maintenance. Second, policy makers at all levels of government and researchers need to determine appropriate strategies for the treatment and disposal of accumulated sediments. Finally, further research about the best maintenance practices and financing arrangements may be needed.

  6. Urban Dispersion Program Overview and MID05 Field Study Summary

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2007-07-31

    The Urban Dispersion Program (UDP) was a 4-year project (2004–2007) funded by the U.S. Department of Homeland Security with additional support from the Defense Threat Reduction Agency. The U.S. Environmental Protection Agency (EPA) also contributed to UDP through funding a human-exposure component of the New York City (NYC) field studies in addition to supporting an EPA scientist in conducting modeling studies of NYC. The primary goal of UDP was to improve the scientific understanding of the flow and diffusion of airborne contaminants through and around the deep street canyons of NYC. The overall UDP project manager and lead scientist was Dr. Jerry Allwine of Pacific Northwest National Laboratory. UDP had several accomplishments that included conducting two tracer and meteorological field studies in Midtown Manhattan.

  7. Urban Integrated Industrial Cogeneration Systems Analysis. Phase II final report

    SciTech Connect (OSTI)

    Not Available

    1984-01-01

    Through the Urban Integrated Industrial Cogeneration Systems Analysis (UIICSA), the City of Chicago embarked upon an ambitious effort to identify the measure the overall industrial cogeneration market in the city and to evaluate in detail the most promising market opportunities. This report discusses the background of the work completed during Phase II of the UIICSA and presents the results of economic feasibility studies conducted for three potential cogeneration sites in Chicago. Phase II focused on the feasibility of cogeneration at the three most promising sites: the Stockyards and Calumet industrial areas, and the Ford City commercial/industrial complex. Each feasibility case study considered the energy load requirements of the existing facilities at the site and the potential for attracting and serving new growth in the area. Alternative fuels and technologies, and ownership and financing options were also incorporated into the case studies. Finally, site specific considerations such as development incentives, zoning and building code restrictions and environmental requirements were investigated.

  8. Systemic effects of urban form on air pollution and environmental quality

    SciTech Connect (OSTI)

    Okamoto, P.C.

    1997-12-31

    The form and design of cities and towns have a direct impact on the quality of the natural environment, particularly air and water quality. This paper illustrates some of the dynamic relationships between the form of urban environments and air and water pollution. Recent research suggests how urban form affects environmental quality in at least three ways: (a) how suburban development and its dependency on the private motor vehicle increases air pollution, (b) how exterior building materials help to generate urban heat islands and ozone precursors, and (c) how conventional stormwater drainage systems transport polluted urban runoff into waterways. Today`s aging urban infrastructure provides an important and timely opportunity to re-examine the design of cities and towns with a goal of enhancing overall environmental quality. Many miles of roads, freeways, bridges, and stormwater culverts and pipes are in poor condition and need to be repaired or replaced, while many cities are now failing to meet air and water quality standards designed to protect human and environmental health. This paper also explores seven urban planning and design concepts that could reduce the magnitude of air and water pollution in urban environments and help to improve the health of both cities and their residents.

  9. Fossil and Contemporary Fine Carbon Fractions at 12 Rural and Urban Sites in the United States

    SciTech Connect (OSTI)

    Schichtel, B; Malm, W; Bench, G; Fallon, S; McDade, C; Chow, J

    2007-03-01

    Fine particulate matter collected at two urban, four near-urban, and six remote sites throughout the United States were analyzed for total carbon (TC) and radiocarbon ({sup 14}C). Samples were collected at most sites for both a summer and winter season. The radiocarbon was used to partition the TC into fossil and contemporary fractions. On average, contemporary carbon composed about half of the carbon at the urban, {approx}70-97% at near-urban, and 82-100% at remote sites. At Phoenix, Arizona, and Seattle, Washington, one monitor was located within the urban center and one outside to assess the urban excess over background concentrations. During the summer the urban and rural sites had similar contemporary carbon concentrations. However, during the winter the urban sites had more than twice the contemporary carbon measured at the neighboring sites, indicating anthropogenic contributions to the contemporary carbon. The urban fossil carbon was 4-20 times larger than the neighboring rural sites for both seasons. Organic (OC) and elemental carbon (EC) from TOR analysis were available. These and the radiocarbon data were used to estimate characteristic fossil and contemporary EC/TC ratios for the winter and summer seasons. These ratios were applied to carbon data from the Interagency Monitoring of Protected Visual Environments network to estimate the fraction of contemporary carbon at mostly rural sites throughout the United States. In addition, the ratios were used to develop a semiquantitative, lower bound estimate of secondary organic carbon (SOC) contribution to fossil and contemporary carbon. SOC accounted for more than one-third of the fossil and contemporary carbon.

  10. Relativistic quasiparticle time blocking approximation. II. Pygmy dipole resonance in neutron-rich nuclei

    SciTech Connect (OSTI)

    Litvinova, E.; Ring, P.; Tselyaev, V.; Langanke, K.

    2009-05-15

    Theoretical studies of low-lying dipole strength in even-even spherical nuclei within the relativistic quasiparticle time blocking approximation (RQTBA) are presented. The RQTBA developed recently as an extension of the self-consistent relativistic quasiparticle random-phase approximation (RQRPA) enables one to investigate the effects of the coupling of two-quasiparticle excitations to collective vibrations within a fully consistent calculation scheme based on covariant energy density functional theory. Dipole spectra of even-even {sup 130}Sn-{sup 140}Sn and {sup 68}Ni-{sup 78}Ni isotopes calculated within both RQRPA and RQTBA show two well-separated collective structures: the higher lying giant dipole resonance and the lower lying pygmy dipole resonance, which can be identified by the different behavior of the transition densities of states in these regions.

  11. Development of HELIOS/CAPP code system for the analysis of block type VHTR cores

    SciTech Connect (OSTI)

    Lee, H. C.; Han, T. Y.; Jo, C. K.; Noh, J. M.

    2012-07-01

    In this paper, the HELIOS/CAPP code system developed for the analysis of block type VHTR cores is presented and verified against several VHTR core configurations. Verification results shows that HELIOS code predicts less negative MTC and RTC than McCARD code does and thus HELIOS code overestimates the multiplication factors at the states with high moderator and reflector temperature especially when the B{sub 4}C BP is loaded. In the depletion calculation for the VHTR single cell fuel element, the error of HELIOS code increases as burnup does. It is ascribed to the fact that HELIOS code treats some fission product nuclides with large resonances as non-resonant nuclides. In the 2-D core depletion calculation, a relatively large reactivity error is observed in the case with BP loading while the reactivity error in the case without BP loading is less than 300 pcm. (authors)

  12. Remote Stabilization of Copper Paddlewheel Based Molecular Building Blocks in Metal-Organic Frameworks

    SciTech Connect (OSTI)

    Gao, Wen-Yang; Cai, Rong; Pham, Tony; Forrest, Katherine A.; Hogan, Adam; Nugent, Patrick; Williams, Kia; Wojtas, Lukasz; Luebke, Ryan; Weseliinski, Lukasz J.; Zaworotko, Michael J.; Space, Brian; Chen, Yu-Sheng; Eddaoudi, Mohamed; Shi, Xiaodong; Ma, Shengqian

    2015-08-21

    Copper paddlewheel based molecular building blocks (MBBs) are ubiquitous and have been widely employed for the construction of highly porous metal–organic frameworks (MOFs). However, most copper paddlewheel based MOFs fail to retain their structural integrity in the presence of water. This instability is directly correlated to the plausible displacement of coordinating carboxylates in the copper paddlewheel MBB, [Cu₂(O₂C-)₄], by the strongly coordinating water molecules. In this comprehensive study, we illustrate the chemical stability control in the rht-MOF platform via strengthening the coordinating bonds within the triangular inorganic MBB, [Cu₃O(N4–x(CH)xC-)₃] (x = 0, 1, or 2). Remotely, the chemical stabilization propagated into the paddlewheel MBB to afford isoreticular rht-MOFs with remarkably enhanced water/chemical stabilities compared to the prototypal rht-MOF-1.

  13. Chemically directing d-block heterometallics to nanocrystal surfaces as molecular beacons of surface structure

    SciTech Connect (OSTI)

    Rosen, Evelyn L.; Gilmore, Keith; Sawvel, April M.; Hammack, Aaron T.; Doris, Sean E.; Aloni, Shaul; Altoe, Virginia; Nordlund, Dennis; Weng, Tsu -Chien; Sokaras, Dimosthenis; Cohen, Bruce E.; Urban, Jeffrey J.; Ogletree, D. Frank; Milliron, Delia J.; Prendergast, David; Helms, Brett A.

    2015-07-28

    Our understanding of structure and bonding in nanoscale materials is incomplete without knowledge of their surface structure. Needed are better surveying capabilities responsive not only to different atoms at the surface, but also their respective coordination environments. We report here that d-block organometallics, when placed at nanocrystal surfaces through heterometallic bonds, serve as molecular beacons broadcasting local surface structure in atomic detail. This unique ability stems from their elemental specificity and the sensitivity of their d-orbital level alignment to local coordination environment, which can be assessed spectroscopically. Re-surfacing cadmium and lead chalcogenide nanocrystals with iron- or ruthenium-based molecular beacons is readily accomplished with trimethylsilylated cyclopentadienyl metal carbonyls. For PbSe nanocrystals with iron-based beacons, we show how core-level X-ray spectroscopies and DFT calculations enrich our understanding of both charge and atomic reorganization at the surface when beacons are bound.

  14. Vectorization, threading, and cache-blocking considerations for hydrocodes on emerging architectures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fung, J.; Aulwes, R. T.; Bement, M. T.; Campbell, J. M.; Ferenbaugh, C. R.; Jean, B. A.; Kelley, T. M.; Kenamond, M. A.; Lally, B. R.; Lovegrove, E. G.; et al

    2015-07-14

    This work reports on considerations for improving computational performance in preparation for current and expected changes to computer architecture. The algorithms studied will include increasingly complex prototypes for radiation hydrodynamics codes, such as gradient routines and diffusion matrix assembly (e.g., in [1-6]). The meshes considered for the algorithms are structured or unstructured meshes. The considerations applied for performance improvements are meant to be general in terms of architecture (not specifically graphical processing unit (GPUs) or multi-core machines, for example) and include techniques for vectorization, threading, tiling, and cache blocking. Out of a survey of optimization techniques on applications such asmore » diffusion and hydrodynamics, we make general recommendations with a view toward making these techniques conceptually accessible to the applications code developer. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.« less

  15. Vectorization, threading, and cache-blocking considerations for hydrocodes on emerging architectures

    SciTech Connect (OSTI)

    Fung, J.; Aulwes, R. T.; Bement, M. T.; Campbell, J. M.; Ferenbaugh, C. R.; Jean, B. A.; Kelley, T. M.; Kenamond, M. A.; Lally, B. R.; Lovegrove, E. G.; Nelson, E. M.; Powell, D. M.

    2015-07-14

    This work reports on considerations for improving computational performance in preparation for current and expected changes to computer architecture. The algorithms studied will include increasingly complex prototypes for radiation hydrodynamics codes, such as gradient routines and diffusion matrix assembly (e.g., in [1-6]). The meshes considered for the algorithms are structured or unstructured meshes. The considerations applied for performance improvements are meant to be general in terms of architecture (not specifically graphical processing unit (GPUs) or multi-core machines, for example) and include techniques for vectorization, threading, tiling, and cache blocking. Out of a survey of optimization techniques on applications such as diffusion and hydrodynamics, we make general recommendations with a view toward making these techniques conceptually accessible to the applications code developer. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.

  16. Identification of crystalline elastic anisotropy in PZT ceramics from in-situ blocking stress measurements

    SciTech Connect (OSTI)

    Daniel, L.; Hall, D. A.; Withers, P. J.; Webber, K. G.; King, A.

    2014-05-07

    High energy x-ray diffraction measurements of lattice strains were performed on a rhombohedral Lead Zirconate Titanate ceramic (PZT 55-45) under combinations of applied electric field and compressive stress. These measurements allow the construction of blocking stress curves for different sets of crystallographic orientations which reflect the single crystal elastic anisotropy. A micro-mechanical interpretation of the results is then proposed. Assuming cubic symmetry for the crystalline elastic stiffness tensor and isotropy for the macroscopic elastic properties, the elastic properties of the single crystal are extracted from the measured data. An anisotropy ratio close to 0.3 is found (compared to 1 for isotropic materials). The high level of anisotropy found in this work suggests that crystalline elastic anisotropy should not be neglected in the modelling of ferroelectric materials.

  17. Algorithmically scalable block preconditioner for fully implicit shallow-water equations in CAM-SE

    SciTech Connect (OSTI)

    Lott, P. Aaron; Woodward, Carol S.; Evans, Katherine J.

    2014-10-19

    Performing accurate and efficient numerical simulation of global atmospheric climate models is challenging due to the disparate length and time scales over which physical processes interact. Implicit solvers enable the physical system to be integrated with a time step commensurate with processes being studied. The dominant cost of an implicit time step is the ancillary linear system solves, so we have developed a preconditioner aimed at improving the efficiency of these linear system solves. Our preconditioner is based on an approximate block factorization of the linearized shallow-water equations and has been implemented within the spectral element dynamical core within the Community Atmospheric Model (CAM-SE). Furthermore, in this paper we discuss the development and scalability of the preconditioner for a suite of test cases with the implicit shallow-water solver within CAM-SE.

  18. Algorithmically scalable block preconditioner for fully implicit shallow-water equations in CAM-SE

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lott, P. Aaron; Woodward, Carol S.; Evans, Katherine J.

    2014-10-19

    Performing accurate and efficient numerical simulation of global atmospheric climate models is challenging due to the disparate length and time scales over which physical processes interact. Implicit solvers enable the physical system to be integrated with a time step commensurate with processes being studied. The dominant cost of an implicit time step is the ancillary linear system solves, so we have developed a preconditioner aimed at improving the efficiency of these linear system solves. Our preconditioner is based on an approximate block factorization of the linearized shallow-water equations and has been implemented within the spectral element dynamical core within themore » Community Atmospheric Model (CAM-SE). Furthermore, in this paper we discuss the development and scalability of the preconditioner for a suite of test cases with the implicit shallow-water solver within CAM-SE.« less

  19. Nonlinear organic plasmonics: Applications to optical control of Coulomb blocking in nanojunctions

    SciTech Connect (OSTI)

    Fainberg, B. D.; Li, G.

    2015-08-03

    Purely organic materials with negative and near-zero dielectric permittivity can be easily fabricated. Here, we develop a theory of nonlinear non-steady-state organic plasmonics with strong laser pulses that enable us to obtain near-zero dielectric permittivity during a short time. Our consideration is based on the model of the interaction of strong (phase modulated) laser pulse with organic molecules developed by one of the authors before, extended to the dipole-dipole intermolecular interactions in the condensed matter. We have proposed to use non-steady-state organic plasmonics for the enhancement of intersite dipolar energy-transfer interaction in the quantum dot wire that influences on electron transport through nanojunctions. Such interactions can compensate Coulomb repulsions for particular conditions. We propose the exciton control of Coulomb blocking in the quantum dot wire based on the non-steady-state near-zero dielectric permittivity of the organic host medium.

  20. Chemically directing d-block heterometallics to nanocrystal surfaces as molecular beacons of surface structure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rosen, Evelyn L.; Gilmore, Keith; Sawvel, April M.; Hammack, Aaron T.; Doris, Sean E.; Aloni, Shaul; Altoe, Virginia; Nordlund, Dennis; Weng, Tsu -Chien; Sokaras, Dimosthenis; et al

    2015-07-28

    Our understanding of structure and bonding in nanoscale materials is incomplete without knowledge of their surface structure. Needed are better surveying capabilities responsive not only to different atoms at the surface, but also their respective coordination environments. We report here that d-block organometallics, when placed at nanocrystal surfaces through heterometallic bonds, serve as molecular beacons broadcasting local surface structure in atomic detail. This unique ability stems from their elemental specificity and the sensitivity of their d-orbital level alignment to local coordination environment, which can be assessed spectroscopically. Re-surfacing cadmium and lead chalcogenide nanocrystals with iron- or ruthenium-based molecular beacons ismore » readily accomplished with trimethylsilylated cyclopentadienyl metal carbonyls. For PbSe nanocrystals with iron-based beacons, we show how core-level X-ray spectroscopies and DFT calculations enrich our understanding of both charge and atomic reorganization at the surface when beacons are bound.« less

  1. Comparative Study on Exhaust Emissions from Diesel- and CNG-Powered Urban

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buses | Department of Energy Study on Exhaust Emissions from Diesel- and CNG-Powered Urban Buses Comparative Study on Exhaust Emissions from Diesel- and CNG-Powered Urban Buses 2003 DEER Conference Presentations: French Agency of Environment and Energy Management deer_2003_seguelong.pdf (468.36 KB) More Documents & Publications Initial Results of the DeNOx SCR System by Urea Injection in the Euro 5 Bus Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty

  2. Fact #902: December 7, 2015 Rural versus Urban Vehicle Miles of Travel by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State - Dataset | Department of Energy 2: December 7, 2015 Rural versus Urban Vehicle Miles of Travel by State - Dataset Fact #902: December 7, 2015 Rural versus Urban Vehicle Miles of Travel by State - Dataset Excel file and dataset for Rural versus Urban Vehicle Miles of Travel by State fotw#902_web.xlsx (177.48 KB) More Documents & Publications Fact #904: December 21, 2015 Gross Domestic Product and Vehicle Travel: Both Increased during 2015 - Dataset Fact #906: January 4, 2016 VMT

  3. Department of Housing and Urban Development-Independent Agencies Appropriation Act, 1984

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    The budget appropriations for FY 1983 for the National Science Foundation, the National Aeronautics and Space Administration, the Department of Housing and Urban Development-Independent Agencies are presented.

  4. Environmental Externalities in Electric Power Markets: Acid Rain, Urban Ozone, and Climate Change

    Reports and Publications (EIA)

    1995-01-01

    This article discusses the emissions resulting from the generation of electricity by utilities and their role in contributing to the environmental problems of acid rain, urban ozone, and climate change.

  5. Physics-based statistical model and simulation method of RF propagation in urban environments

    DOE Patents [OSTI]

    Pao, Hsueh-Yuan; Dvorak, Steven L.

    2010-09-14

    A physics-based statistical model and simulation/modeling method and system of electromagnetic wave propagation (wireless communication) in urban environments. In particular, the model is a computationally efficient close-formed parametric model of RF propagation in an urban environment which is extracted from a physics-based statistical wireless channel simulation method and system. The simulation divides the complex urban environment into a network of interconnected urban canyon waveguides which can be analyzed individually; calculates spectral coefficients of modal fields in the waveguides excited by the propagation using a database of statistical impedance boundary conditions which incorporates the complexity of building walls in the propagation model; determines statistical parameters of the calculated modal fields; and determines a parametric propagation model based on the statistical parameters of the calculated modal fields from which predictions of communications capability may be made.

  6. Energy Department Announces the SUN Project, Empowering Urban Native Youth in STEM Education

    Broader source: Energy.gov [DOE]

    The SUN Project is a new collaboration between the U.S. Department of Energy and the American Indian Science and Engineering Society to engage urban Native American youth in science, technology, engineering, and mathematics (STEM) fields.

  7. Assessing climate impacts of planning policies-An estimation for the urban region of Leipzig (Germany)

    SciTech Connect (OSTI)

    Schwarz, Nina Bauer, Annette Haase, Dagmar

    2011-03-15

    Local climate regulation by urban green areas is an important urban ecosystem service, as it reduces the extent of the urban heat island and therefore enhances quality of life. Local and regional planning policies can control land use changes in an urban region, which in turn alter local climate regulation. Thus, this paper describes a method for estimating the impacts of current land uses as well as local and regional planning policies on local climate regulation, using evapotranspiration and land surface emissivity as indicators. This method can be used by practitioners to evaluate their policies. An application of this method is demonstrated for the case study Leipzig (Germany). Results for six selected planning policies in Leipzig indicate their distinct impacts on climate regulation and especially the role of their spatial extent. The proposed method was found to easily produce a qualitative assessment of impacts of planning policies on climate regulation.

  8. Best Practices Case Study: Urbane Homes - Crestwood, KY, Various Locations, Greater Louisville, KY

    SciTech Connect (OSTI)

    2011-09-01

    Case study of Urbane Homes, who worked with Building America to build market rate homes with HERS scores of 57 to 62. Despite a down market they’ve sold every home within 3 weeks of listing, without any advertising.

  9. A Cluster-based Method to Map Urban Area from DMSP/OLS Nightlights...

    Office of Scientific and Technical Information (OSTI)

    Two large countries of United States and China with different urbanization patterns were ... at the state level, and less than 1% in China, ranging from lower than 0.1% to about 5% ...

  10. GIZ Sourcebook Module 2a: Land Use Planning and Urban Transport...

    Open Energy Info (EERE)

    GIZ Sourcebook Module 2a: Land Use Planning and Urban Transport (Espaol) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: GIZ Sourcebook Module 2a: Land Use Planning...

  11. How Can China Lighten Up? Urbanization, Industrialization and Energy Demand Scenarios

    SciTech Connect (OSTI)

    Aden, Nathaniel T.; Zheng, Nina; Fridley, David G.

    2009-07-01

    Urbanization has re-shaped China's economy, society, and energy system. Between 1990 and 2007 China added 290 million new urban residents, bringing the total urbanization rate to 45%. This population adjustment spurred energy demand for construction of new buildings and infrastructure, as well as additional residential use as rural biomass was replaced with urban commercial energy services. Primary energy demand grew at an average annual rate of 10% between 2000 and 2007. Urbanization's effect on energy demand was compounded by the boom in domestic infrastructure investment, and in the export trade following World Trade Organization (WTO) accession in 2001. Industry energy consumption was most directly affected by this acceleration. Whereas industry comprised 32% of 2007 U.S. energy use, it accounted for 75% of China's 2007 energy consumption. Five sub-sectors accounted for 78% of China's industry energy use in 2007: iron and steel, energy extraction and processing, chemicals, cement, and non-ferrous metals. Ferrous metals alone accounted for 25% of industry and 18% of total primary energy use. The rapid growth of heavy industry has led China to become by far the world's largest producer of steel, cement, aluminum, and other energy-intensive commodities. However, the energy efficiency of heavy industrial production continues to lag world best practice levels. This study uses scenario analysis to quantify the impact of urbanization and trade on industrial and residential energy consumption from 2000 to 2025. The BAU scenario assumed 67% urbanization, frozen export amounts of heavy industrial products, and achievement of world best practices by 2025. The China Lightens Up (CLU) scenario assumed 55% urbanization, zero net exports of heavy industrial products, and more aggressive efficiency improvements by 2025. The five dominant industry sub-sectors were modeled in both scenarios using a LEAP energy end-use accounting model. The results of this study show that a CLU

  12. Retrofit Program of a Euro 1 andn EUro 2 Urban Bus Fleet in La Rochelle:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Status after One Year Experience | Department of Energy Program of a Euro 1 andn EUro 2 Urban Bus Fleet in La Rochelle: Status after One Year Experience Retrofit Program of a Euro 1 andn EUro 2 Urban Bus Fleet in La Rochelle: Status after One Year Experience 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Rhodia Electronics and Catalysis 2004_deer_rocher.pdf (151.33 KB) More Documents & Publications Improvement and Simplification of Diesel Particulate Filter System

  13. Global Cooling: Increasing World-Wide Urban Albedos to Offset CO2

    SciTech Connect (OSTI)

    Akbari, Hashem; Menon, Surabi; Rosenfeld, Arthur

    2008-01-14

    Modification of urban albedos reduces summertime urban temperatures, resulting in a better urban air quality and building air-conditioning savings. Furthermore, increasing urban albedos has the added benefit of reflecting some of the incoming global solar radiation and countering to some extent the effects of global warming. In many urban areas, pavements and roofs constitute over 60% of urban surfaces (roof 20-25%, pavements about 40%). Using reflective materials, both roof and the pavement albedos can be increased by about 0.25 and 0.10, respectively, resulting in a net albedo increase for urban areas of about 0.1. Many studies have demonstrated building cooling-energy savings in excess of 20% upon raising roof reflectivity from an existing 10-20% to about 60% (a U.S. potential savings in excess of $1 billion (B) per year in net annual energy bills). On a global basis, our preliminary estimate is that increasing the world-wide albedos of urban roofs and paved surfaces will induce a negative radiative forcing on the earth equivalent to removing {approx} 22-40 Gt of CO{sub 2} from the atmosphere. Since, 55% of the emitted CO{sub 2} remains in the atmosphere, removal of 22-40 Gt of CO{sub 2} from the atmosphere is equivalent to reducing global CO{sub 2} emissions by 40-73 Gt. At {approx} $25/tonne of CO{sub 2}, a 40-73 Gt CO{sub 2} emission reduction from changing the albedo of roofs and paved surfaces is worth about $1,000B to 1800B. These estimated savings are dependent on assumptions used in this study, but nevertheless demonstrate considerable benefits that may be obtained from cooler roofs and pavements.

  14. Optimal integrated design of air separation unit and gas turbine block for IGCC systems

    SciTech Connect (OSTI)

    Kamath, R.; Grossman, I.; Biegler, L.; Zitney, S.

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine

  15. Optimal Integrated Design of Air Separation Unit and Gas Turbine Block for IGCC Systems

    SciTech Connect (OSTI)

    Ravindra S. Kamath; Ignacio E. Grossmann; Lorenz T. Biegler; Stephen E. Zitney

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine

  16. A Sensitivity Model (SM) approach to analyze urban development in Taiwan based on sustainability indicators

    SciTech Connect (OSTI)

    Huang Shuli Yeh Chiatsung Budd, William W. Chen Liling

    2009-02-15

    Sustainability indicators have been widely developed to monitor and assess sustainable development. They are expected to guide political decision-making based on their capability to represent states and trends of development. However, using indicators to assess the sustainability of urban strategies and policies has limitations - as they neither reflect the systemic interactions among them, nor provide normative indications in what direction they should be developed. This paper uses a semi-quantitative systematic model tool (Sensitivity Model Tools, SM) to analyze the role of urban development in Taiwan's sustainability. The results indicate that the natural environment in urban area is one of the most critical components and the urban economic production plays a highly active role in affecting Taiwan's sustainable development. The semi-quantitative simulation model integrates sustainability indicators and urban development policy to provide decision-makers with information about the impacts of their decisions on urban development. The system approach incorporated by this paper can be seen as a necessary, but not sufficient, condition for a sustainability assessment. The participatory process of expert participants for providing judgments on the relations between indicator variables is also discussed.

  17. Analysis of colloidal phases in urban stormwater runoff

    SciTech Connect (OSTI)

    Grout, H.; Wiesner, M.R.; Bottero, J.Y.

    1999-03-15

    The composition and morphology of colloidal materials entering an urban waterway (Brays Bayou, Houston, USA) during a storm event was investigated. Analyses of organic carbon, Si, Al, Fe, Cr, Cu, Mn, Zn, Ca, Mg, and Ba were performed on the fraction of materials passing through a 0.45 {micro}m filter. This fraction, traditionally defined as dissolved, was further fractionated by ultracentrifugation into colloidal and dissolved fractions. Colloids, operationally defined by this procedure, accounted for 17% of the carbon, 32% of the silica, 79% of the Al, 85% of the Fe, 52% of the Cr, 43% of the Mn, and 29% of the Zn present in filtrates when averaged over the storm event. However, the composition of colloidal material was observed to change over time. For example, colloids were predominantly composed of silica during periods of dry weather flow and at the maximum of the stormwater flow, while carbon dominated the colloidal fraction at the beginning and declining stages of the storm event. These changes in colloidal composition were accompanied by changes in colloidal morphologies, varying from organic aggregates to diffuse gel-like structures rich in Si, Al, and Fe. The colloidal phase largely determined the variability of elements in the 0.45 {micro}m filtrate.

  18. Visualizing Diurnal Population Change in Urban Areas for Emergency Management

    SciTech Connect (OSTI)

    Kobayashi, Tetsuo; Medina, Richard M; Cova, Thomas

    2011-01-01

    There is an increasing need for a quick, simple method to represent diurnal population change in metropolitan areas for effective emergency management and risk analysis. Many geographic studies rely on decennial U.S. Census data that assume that urban populations are static in space and time. This has obvious limitations in the context of dynamic geographic problems. The U.S. Department of Transportation publishes population data at the transportation analysis zone level in fifteen-minute increments. This level of spatial and temporal detail allows for improved dynamic population modeling. This article presents a methodology for visualizing and analyzing diurnal population change for metropolitan areas based on this readily available data. Areal interpolation within a geographic information system is used to create twenty-four (one per hour) population surfaces for the larger metropolitan area of Salt Lake County, Utah. The resulting surfaces represent diurnal population change for an average workday and are easily combined to produce an animation that illustrates population dynamics throughout the day. A case study of using the method to visualize population distributions in an emergency management context is provided using two scenarios: a chemical release and a dirty bomb in Salt Lake County. This methodology can be used to address a wide variety of problems in emergency management.

  19. The Airborne Metagenome in an Indoor Urban Environment

    SciTech Connect (OSTI)

    Tringe, Susannah; Zhang, Tao; Liu, Xuguo; Yu, Yiting; Lee, Wah Heng; Yap, Jennifer; Yao, Fei; Suan, Sim Tiow; Ing, Seah Keng; Haynes, Matthew; Rohwer, Forest; Wei, Chia Lin; Tan, Patrick; Bristow, James; Rubin, Edward M.; Ruan, Yijun

    2008-02-12

    The indoor atmosphere is an ecological unit that impacts on public health. To investigate the composition of organisms in this space, we applied culture-independent approaches to microbes harvested from the air of two densely populated urban buildings, from which we analyzed 80 megabases genomic DNA sequence and 6000 16S rDNA clones. The air microbiota is primarily bacteria, including potential opportunistic pathogens commonly isolated from human-inhabited environments such as hospitals, but none of the data contain matches to virulent pathogens or bioterror agents. Comparison of air samples with each other and nearby environments suggested that the indoor air microbes are not random transients from surrounding outdoor environments, but rather originate from indoor niches. Sequence annotation by gene function revealed specific adaptive capabilities enriched in the air environment, including genes potentially involved in resistance to desiccation and oxidative damage. This baseline index of air microbiota will be valuable for improving designs of surveillance for natural or man-made release of virulent pathogens.

  20. The tectonic mechanism for uplift and rotation of crustal blocks in the Central basin platform, Permian basin, Texas and New Mexico

    SciTech Connect (OSTI)

    Yang Kennming; Dorobek, S.L. )

    1991-03-01

    The Central basin platform is a positive tectonic element in the subsurface of the Permian basin. This enigmatic platform strikes north-northwest-south-southeast and at a high angle to the Marathon fold-and-thrust belt to the south. Although the uplift of the platform was related temporally to major overthrusting in the orogenic belt to the south and east, its formative mechanisms are still poorly understood. Previously compiled tectonic maps and cross sections were analyzed to identify the significant characteristics of this complicated structure. (1) Much of the platform is bounded by laterally discontinuous, high-angle faults with large vertical displacements. (2) The bounding faults suggest that the platform is composed of several discrete blocks that are arranged in a dextral en echelon pattern. (3) The southwest and northeast corners of each block typically are bounded by major faults; block uplift is greatest at the southwest and northeast corners. (4) Blocks are separated by west-northwest-east-southeast-trending transfer zones. These characteristics suggest that the Central Basin platform was subjected to a north-northwest-south-southeast-trending dextral couple that caused the platform to split into several blocks. Individual blocks rotated in the same clockwise sense and produced the maximum uplift observed at the southwest and northeast corners of blocks. In addition to the above characteristics, the amount of uplift an the width of individual blocks progressively decrease toward the north; block boundaries also become less defined northward. However, these additional complexities are not fully understood yet.

  1. Titanium dioxide/silicon hole-blocking selective contact to enable double-heterojunction crystalline silicon-based solar cell

    SciTech Connect (OSTI)

    Nagamatsu, Ken A. Man, Gabriel; Jhaveri, Janam; Berg, Alexander H.; Kahn, Antoine; Wagner, Sigurd; Sturm, James C.; Avasthi, Sushobhan; Sahasrabudhe, Girija; Schwartz, Jeffrey

    2015-03-23

    In this work, we use an electron-selective titanium dioxide (TiO{sub 2}) heterojunction contact to silicon to block minority carrier holes in the silicon from recombining at the cathode contact of a silicon-based photovoltaic device. We present four pieces of evidence demonstrating the beneficial effect of adding the TiO{sub 2} hole-blocking layer: reduced dark current, increased open circuit voltage (V{sub OC}), increased quantum efficiency at longer wavelengths, and increased stored minority carrier charge under forward bias. The importance of a low rate of recombination of minority carriers at the Si/TiO{sub 2} interface for effective blocking of minority carriers is quantitatively described. The anode is made of a poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) heterojunction to silicon which forms a hole selective contact, so that the entire device is made at a maximum temperature of 100 °C, with no doping gradients or junctions in the silicon. A low rate of recombination of minority carriers at the Si/TiO{sub 2} interface is crucial for effective blocking of minority carriers. Such a pair of complementary carrier-selective heterojunctions offers a path towards high-efficiency silicon solar cells using relatively simple and near-room temperature fabrication techniques.

  2. Sedimentation and reservoir distribution related to a tilted block system in the Sardinia Oligocene-Miocene rift (Italy)

    SciTech Connect (OSTI)

    Tremolieres, P.; Cherchi, A.; Eschard, R.; De Graciansky, P.C.; Montadert, L.

    1988-08-01

    In the western Mediterranean basin lies a rift system about 250 km long and 50 km wide and its infilling outcrop (central Sardinia). Seismic reflection surveys show its offshore extension. Block tilting started during the late Oligocene and lasted during Aquitanian-early Burdigalian time. Two main fault trends, with synthetic and antithetic throws, define the more-or-less collapsed blocks. This morphology guided the transit and trapping of sediments. The sedimentation started in a continental environment then, since the Chattian, in marine conditions. In the central part, the series can reach a thickness of 2,000 m. The basement composition and the volcanics products related to the main fault motion controlled the nature of the synrift deposits. According to their location in the rift context, the tilted blocks trap either continental deposits or marine siliciclastic or carbonate deposits. In the deeper part of the graben, sands were redeposited by gravity flows into the basinal marls. The younger prerift deposits are from Eocene to early Oligocene age and locally comprise thick coal layers. Postrift deposits, mainly marls, sealed the blocks and synrift sedimentary bodies. In middle and late Miocene time some faults were reactivated during compressional events. Then, a quaternary extensional phase created the Campidano graben, filled with about 1,000 m of sediments superimposed on the Oligocene-Miocene rift.

  3. Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico

    SciTech Connect (OSTI)

    Dunbar, John

    2012-12-31

    Electrical methods offer a geophysical approach for determining the sub-bottom distribution of hydrate in deep marine environments. Methane hydrate is essentially non-conductive. Hence, sediments containing hydrate are more resistive than sediments without hydrates. To date, the controlled source electromagnetic (CSEM) method has been used in marine hydrates studies. This project evaluated an alternative electrical method, direct current resistivity (DCR), for detecting marine hydrates. DCR involves the injection of direct current between two source electrodes and the simultaneous measurement of the electric potential (voltage) between multiple receiver electrodes. The DCR method provides subsurface information comparable to that produced by the CSEM method, but with less sophisticated instrumentation. Because the receivers are simple electrodes, large numbers can be deployed to achieve higher spatial resolution. In this project a prototype seafloor DCR system was developed and used to conduct a reconnaissance survey at a site of known hydrate occurrence in Mississippi Canyon Block 118. The resulting images of sub-bottom resistivities indicate that high-concentration hydrates at the site occur only in the upper 50 m, where deep-seated faults intersect the seafloor. Overall, there was evidence for much less hydrate at the site than previously thought based on available seismic and CSEM data alone.

  4. Microstructured block copolymer surfaces for control of microbe capture and aggregation

    SciTech Connect (OSTI)

    Hansen, Ryan R; Shubert, Katherine R; Morrell, Jennifer L.; Lokitz, Bradley S; Doktycz, Mitchel John; Retterer, Scott T

    2014-01-01

    The capture and arrangement of surface-associated microbes is influenced by biochemical and physical properties of the substrate. In this report, we develop lectin-functionalized substrates containing patterned, three-dimensional polymeric structures of varied shapes and densities and use these to investigate the effects of topology and spatial confinement on lectin-mediated microbe capture. Films of poly(glycidyl methacrylate)-block-4,4-dimethyl-2-vinylazlactone (PGMA-b-PVDMA) were patterned on silicon surfaces into line or square grid patterns with 5 m wide features and varied edge spacing. The patterned films had three-dimensional geometries with 900 nm film thickness. After surface functionalization with wheat germ agglutinin, the size of Pseudomonas fluorescens aggregates captured was dependent on the pattern dimensions. Line patterns with edge spacing of 5 m or less led to the capture of individual microbes with minimal formation of aggregates, while grid patterns with the same spacing also captured individual microbes with further reduction in aggregation. Both geometries allowed for increases in aggregate size distribution with increased in edge spacing. These engineered surfaces combine spatial confinement with affinity-based microbe capture based on exopolysaccharide content to control the degree of microbe aggregation, and can also be used as a platform to investigate intercellular interactions and biofilm formation in microbial populations of controlled sizes.

  5. Cross-Linked Nanoporous Materials from Reactive and Multifunctional Block Polymers

    SciTech Connect (OSTI)

    Seo, Myungeun; Amendt, Mark A.; Hillmyer, Marc A.

    2012-10-10

    Polylactide-b-poly(styrene-co-2-hydroxyethylmethacrylate) (PLA-b-P(S-co-HEMA)) and polylactide-b-poly(styrene-co-2-hydroxyethylacrylate) (PLA-b-P(S-co-HEA)) were synthesized by combination of ring-opening polymerization and reversible addition-fragmentation chain transfer polymerization. {sup 1}H nuclear magnetic resonance spectroscopy and size exclusion chromatography data indicated that the polymerizations were controlled and that hydroxyl groups were successfully incorporated into the block polymers. The polymers were reacted with 4,4{prime}-methylenebis(phenyl isocyanate) (MDI) to form the corresponding cross-linked materials. The materials were annealed at 150 C to complete the coupling reaction. Robust nanoporous materials were obtained from the cross-linked polymers by treatment with aqueous base to hydrolyze the PLA phase. Small-angle X-ray scattering study combined with scanning electron microscopy showed that MDI-cross-linked PLA-b-P(S-co-HEMA)/PLA-b-P(S-co-HEA) can adopt lamellar, hexagonally perforated lamellar, and hexagonally packed cylindrical morphologies after annealing. In particular, the HPL morphology was found to evolve from lamellae due to increase in volume fraction of PS phase as MDI reacted with hydroxyl groups. The reaction also kinetically trapped the morphology by cross-linking. Bicontinuous morphologies were also observed when dibutyltin dilaurate was added to accelerate reaction between the polymer and MDI.

  6. An early warning indicator for atmospheric blocking events using transfer operators

    SciTech Connect (OSTI)

    Tantet, Alexis Burgt, Fiona R. van der; Dijkstra, Henk A.

    2015-03-15

    The existence of persistent midlatitude atmospheric flow regimes with time-scales larger than 5–10 days and indications of preferred transitions between them motivates to develop early warning indicators for such regime transitions. In this paper, we use a hemispheric barotropic model together with estimates of transfer operators on a reduced phase space to develop an early warning indicator of the zonal to blocked flow transition in this model. It is shown that the spectrum of the transfer operators can be used to study the slow dynamics of the flow as well as the non-Markovian character of the reduction. The slowest motions are thereby found to have time scales of three to six weeks and to be associated with meta-stable regimes (and their transitions) which can be detected as almost-invariant sets of the transfer operator. From the energy budget of the model, we are able to explain the meta-stability of the regimes and the existence of preferred transition paths. Even though the model is highly simplified, the skill of the early warning indicator is promising, suggesting that the transfer operator approach can be used in parallel to an operational deterministic model for stochastic prediction or to assess forecast uncertainty.

  7. Methods for estimating wake flow and effluent dispersion near simple block-like buildings

    SciTech Connect (OSTI)

    Hosker, R.P. Jr.

    1981-05-01

    This report is intended as an interim guide for those who routinely face air quality problems associated with near-building exhaust stack placement and height, and the resulting concentration patterns. Available data and methods for estimating wake flow and effluent dispersion near isolated block-like structures are consolidated. The near-building and wake flows are described, and quantitative estimates for frontal eddy size, height and extent of roof and wake cavities, and far wake behavior are provided. Concentration calculation methods for upwind, near-building, and downwind pollutant sources are given. For an upwind source, it is possible to estimate the required stack height, and to place upper limits on the likely near-building concentration. The influences of near-building source location and characteristics relative to the building geometry and orientation are considered. Methods to estimate effective stack height, upper limits for concentration due to flush roof vents, and the effect of changes in rooftop stack height are summarized. Current wake and wake cavity models are presented. Numerous graphs of important expressions have been prepared to facilitate computations and quick estimates of flow patterns and concentration levels for specific simple buildings. Detailed recommendations for additional work are given.

  8. Design study of 15-Tesla RHQT Nb3Al block type dipole magnet

    SciTech Connect (OSTI)

    Yamada, R.; Ambrosio, G.; Barzi, E.; Kashikin, V.; Kikuchi, A.; Novitski, I.; Takeuchi, T.; Wake, M.; Zlobin, A.; /Fermilab /NIMC, Tsukuba /KEK, Tsukuba

    2005-09-01

    The design study of the block type 15-Tesla RHQT Nb{sub 3}Al dipole magnet, and its merits over Nb{sub 3}Sn magnets are presented. The copper stabilized RHQT Nb{sub 3}Al strand is now becoming commercially available for the application to the accelerator magnets. A 1 mm diameter RHQT Nb{sub 3}Al strand with filament size about 50 {mu}, non-copper Jc about 1000 A/mm{sup 2} at 15 Tesla at 4.2K, copper ratio of 50%, can now be produced over several hundred meters. The stress and strain characteristics of the Nb{sub 3}Al strand are superior to the Nb{sub 3}Sn strand. Another advantage is that it can tolerate a longitudinal strain up to 0.55%. The RHQT Nb{sub 3}Al Rutherford cable will have less chance of contamination of the stabilizer, compared to Nb{sub 3}Sn cable. These characteristics of the RHQT Nb{sub 3}Al will be beneficial for designing and producing 15-Tesla dipole magnets. An example 15-Tesla magnet cross section, utilizing the RHQT Nb{sub 3}Sn strand is presented. A systematic investigation on RHQT Nb{sub 3}Al strands, its Rutherford cables, and building a small racetrack magnet for cable testing are proposed.

  9. Methods And System Suppressing Clutter In A Gain-Block, Radar-Responsive Tag System

    DOE Patents [OSTI]

    Ormesher, Richard C.; Axline, Robert M.

    2006-04-18

    Methods and systems reduce clutter interference in a radar-responsive tag system. A radar transmits a series of linear-frequency-modulated pulses and receives echo pulses from nearby terrain and from radar-responsive tags that may be in the imaged scene. Tags in the vicinity of the radar are activated by the radar's pulses. The tags receive and remodulate the radar pulses. Tag processing reverses the direction, in time, of the received waveform's linear frequency modulation. The tag retransmits the remodulated pulses. The radar uses a reversed-chirp de-ramp pulse to process the tag's echo. The invention applies to radar systems compatible with coherent gain-block tags. The invention provides a marked reduction in the strength of residual clutter echoes on each and every echo pulse received by the radar. SAR receiver processing effectively whitens passive-clutter signatures across the range dimension. Clutter suppression of approximately 14 dB is achievable for a typical radar system.

  10. Nanocluster building blocks of artificial square spin ice: Stray-field studies of thermal dynamics

    SciTech Connect (OSTI)

    Pohlit, Merlin Porrati, Fabrizio; Huth, Michael; Müller, Jens

    2015-05-07

    We present measurements of the thermal dynamics of a Co-based single building block of an artificial square spin ice fabricated by focused electron-beam-induced deposition. We employ micro-Hall magnetometry, an ultra-sensitive tool to study the stray field emanating from magnetic nanostructures, as a new technique to access the dynamical properties during the magnetization reversal of the spin-ice nanocluster. The obtained hysteresis loop exhibits distinct steps, displaying a reduction of their “coercive field” with increasing temperature. Therefore, thermally unstable states could be repetitively prepared by relatively simple temperature and field protocols allowing one to investigate the statistics of their switching behavior within experimentally accessible timescales. For a selected switching event, we find a strong reduction of the so-prepared states' “survival time” with increasing temperature and magnetic field. Besides the possibility to control the lifetime of selected switching events at will, we find evidence for a more complex behavior caused by the special spin ice arrangement of the macrospins, i.e., that the magnetic reversal statistically follows distinct “paths” most likely driven by thermal perturbation.

  11. Oil geochemistry study; Blocks III and IV Bachaquedro Field, Lake Maracaibo, Venezuela

    SciTech Connect (OSTI)

    Patterson, B.A.; Villarroel, H.G. de; Rondon, L.

    1996-08-01

    Blocks III and IV Bachaquero, Field, located on the east side of Lake Maracaibo, comprise an area of 40 square kilometers. In 1956 the discovery well penetrated oil saturated sands in a south dipping homoclinal structure. In 1958 production reached a maximum of 245,000 barrels per day of moderate gravity oil from three Miocene age Lagunillas Formation sands, designated as L, M, and N. The Bachaquero Field has experienced production problems including high gas-oil ratios from M and N sands to the north, high water cuts in all three sands to the south, and low production rates in the southeast. In addition, the vertical and lateral continuity of the oil pools are unknown. High resolution gas chromatography and analysis of biological markers was employed in order to resolve the continuity of the oil pools, determine genetic origin of the oils, and shed light on erratic production. Oil in the L sands are vertically discontinuous from oil in the M+N sands. The two oil pools appear laterally continuous within the study area, indicating absence of fault barriers. Well VLD 311, open to both L and M sands, produces a mix of oils, but with a strong contribution from the M sand. Bachaquero Field reservoirs were charged with oil from two different facies of the Upper Cretaceous La Luna or perhaps from La Luna and Colon source rocks as the stratigraphically younger L sands contain less mature oil with a stronger terrigenous imprint than oil the M and N sands.

  12. New opportunities in Lower B sands VLC-100/949 reservoirs, Block III, Lake Maracaibo

    SciTech Connect (OSTI)

    Gonzalez, G.; Coll, C.; Mora, J.L. )

    1996-01-01

    The Lower B Misoa Formation of Middle Eocene age is characterized by massive sand bodies. These sands were successfully tested in the northern part of Block III in Lake Maracaibo in 1956. Subsequent drilling during the next 27 years has failed to locate any productive pay zones. Only during the past 8 years, new seismic and well data have delineated a number of minor oil reservoirs resulting in extensive production from Misoa Lower B sands. The oil production came primarily from small structural traps located on the hanging walls of normal listric faults. Fault diagnosis and locations were more accurately mapped with the availability of 3-D seismic data. Consequently, VLC-100 and VLC-949 reservoirs are now considered to be part of the same trap instead of being separated. A careful review of the fluid distribution and material balance calculations has confirmed that the wells from these reservoirs have, in fact, been producing from the same accumulation thereby validating the new geological model. The new model has defined new opportunities of oil exploitation. Firstly, it has led to the drilling of 4 new wells and increased production by 4,500 STB/D. Secondly, it has indicated additional recovery opportunities in the form of drilling horizontal wells in the updip area. Finally, the new model indicates the existence of an aquifer of much lower strength than was previously thought. This has caused a revision in our reservoir management strategy and we now recommend water injection to supplement the aquifer support and enhance oil recovery.

  13. Reservoir characterization of the Lower B sands VLC 100/949 Reservoirs, Block III, Lake Maracaibo

    SciTech Connect (OSTI)

    Gonzalez, G.; Coll, C.; Mora, J.L.; Meza, E.

    1996-08-01

    The Lower B Misoa Formation of Middle Eocene age is characterized by massive sand bodies. These sands were successfully tested in the northern part of Block III in Lake Maracaibo in 1956. Subsequent drilling during the next 27 years has failed to locate any productive pay zones. Only during the past 8 years, new seismic and well data have delineated a number of minor oil reservoirs resulting in extensive production from Misoa Lower B sands. The oil production came primarily from small structural traps located on the hanging walls of normal listric faults. Fault diagnosis and locations were more accurately mapped with the availability of 3-D seismic data. Consequently VLC-100 and VLC-949 reservoirs are now considered to be part of the same trap instead of being separated. A careful review of the fluid distribution and material balance calculations has confirmed that the wells from these reservoirs have, in fact, been producing from the same accumulation thereby validating the new geological model. The new model has defined new opportunities of oil exploitation. Firstly, it has led to the drilling of 4 new wells and increased production by 4500 STB/D. Secondly, it has indicated additional recovery opportunities in the form of drilling horizontal wells in the updip area. Finally, the new model indicates the existence of an aquifer of much lower strength than was previously thought. This has caused a revision in our reservoir management strategy, and we now recommend water injection to supplement the aquifer support and enhance oil recovery.

  14. New opportunities in Lower B sands VLC-100/949 reservoirs, Block III, Lake Maracaibo

    SciTech Connect (OSTI)

    Gonzalez, G.; Coll, C.; Mora, J.L.

    1996-12-31

    The Lower B Misoa Formation of Middle Eocene age is characterized by massive sand bodies. These sands were successfully tested in the northern part of Block III in Lake Maracaibo in 1956. Subsequent drilling during the next 27 years has failed to locate any productive pay zones. Only during the past 8 years, new seismic and well data have delineated a number of minor oil reservoirs resulting in extensive production from Misoa Lower B sands. The oil production came primarily from small structural traps located on the hanging walls of normal listric faults. Fault diagnosis and locations were more accurately mapped with the availability of 3-D seismic data. Consequently, VLC-100 and VLC-949 reservoirs are now considered to be part of the same trap instead of being separated. A careful review of the fluid distribution and material balance calculations has confirmed that the wells from these reservoirs have, in fact, been producing from the same accumulation thereby validating the new geological model. The new model has defined new opportunities of oil exploitation. Firstly, it has led to the drilling of 4 new wells and increased production by 4,500 STB/D. Secondly, it has indicated additional recovery opportunities in the form of drilling horizontal wells in the updip area. Finally, the new model indicates the existence of an aquifer of much lower strength than was previously thought. This has caused a revision in our reservoir management strategy and we now recommend water injection to supplement the aquifer support and enhance oil recovery.

  15. A Case Study of Urbanization Impact on Summer Precipitation in the Greater Beijing Metropolitan Area. Urban Heat Island Versus Aerosol Effects

    SciTech Connect (OSTI)

    Zhong, Shi; Qian, Yun; Zhao, Chun; Leung, Lai-Yung R.; Yang, Xiuqun

    2015-10-23

    Convection-resolving ensemble simulations using the WRF-Chem model coupled with a single-layer Urban Canopy Model (UCM) are conducted to investigate the individual and combined impacts of land use and anthropogenic pollutant emissions from urbanization on a heavy rainfall event in the Greater Beijing Metropolitan Area (GBMA) in China. The simulation with the urbanization effect included generally captures the spatial pattern and temporal variation of the rainfall event. An improvement of precipitation is found in the experiment including aerosol effect on both clouds and radiation. The expanded urban land cover and increased aerosols have an opposite effect on precipitation processes, with the latter playing a more dominant role, leading to suppressed convection and rainfall over the upstream (northwest) area, and enhanced convection and more precipitation in the downstream (southeast) region of the GBMA. In addition, the influence of aerosol indirect effect is found to overwhelm that of direct effect on precipitation in this rainfall event. Increased aerosols induce more cloud droplets with smaller size, which favors evaporative cooling and reduce updrafts and suppress convection over the upstream (northwest) region in the early stage of the rainfall event. As the rainfall system propagates southeastward, more latent heat is released due to the freezing of larger number of smaller cloud drops that are lofted above the freezing level, which is responsible for the increased updraft strength and convective invigoration over the downstream (southeast) area.

  16. Urban energy management today: Ten year compendium of UCETF programs. Products and expertise of the Urban Consortium Energy Task Force, 1979--1989

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The reports listed in this Overview summarize projects conducted through the Urban Consortium Energy Task Force by local government staff who have defined and implemented many of the energy strategies described above. Reports from their projects illustrate effective approaches to plan and implement these strategies, as well as software tools, surveys, and technical instruments valuable to other local government officials conducting similar projects.

  17. A Strategic Project Appraisal framework for ecologically sustainable urban infrastructure

    SciTech Connect (OSTI)

    Morrissey, John; Iyer-Raniga, Usha; McLaughlin, Patricia; Mills, Anthony

    2012-02-15

    Actors in the built environment are progressively considering environmental and social issues alongside functional and economic aspects of development projects. Infrastructure projects represent major investment and construction initiatives with attendant environmental, economic and societal impacts across multiple scales. To date, while sustainability strategies and frameworks have focused on wider national aspirations and strategic objectives, they are noticeably weak in addressing micro-level integrated decision making in the built environment, particularly for infrastructure projects. The proposed approach of this paper is based on the principal that early intervention is the most cost-effective and efficient means of mitigating the environmental effects of development projects, particularly macro infrastructure developments. A strategic overview of the various project alternatives, taking account for stakeholder and expert input, could effectively reduce project impacts/risks at low cost to the project developers but provide significant benefit to wider communities, including communities of future stakeholders. This paper is the first exploratory step in developing a more systematic framework for evaluating strategic alternatives for major metropolitan infrastructure projects, based on key sustainability principles. The developed Strategic Project Appraisal (SPA) framework, grounded in the theory of Strategic Environmental Assessment (SEA), provides a means of practically appraising project impacts and alternatives in terms of quantified ecological limits; addresses the neglected topic of metropolitan infrastructure as a means of delivering sustainability outcomes in the urban context and more broadly, seeks to open a debate on the potential for SEA methodology to be more extensively applied to address sustainability challenges in the built environment. Practically applied and timed appropriately, the SPA framework can enable better decision-making and more

  18. Large scale, urban decontamination; developments, historical examples and lessons learned

    SciTech Connect (OSTI)

    Demmer, R.L.

    2007-07-01

    Recent terrorist threats and actions have lead to a renewed interest in the technical field of large scale, urban environment decontamination. One of the driving forces for this interest is the prospect for the cleanup and removal of radioactive dispersal device (RDD or 'dirty bomb') residues. In response, the United States Government has spent many millions of dollars investigating RDD contamination and novel decontamination methodologies. The efficiency of RDD cleanup response will be improved with these new developments and a better understanding of the 'old reliable' methodologies. While an RDD is primarily an economic and psychological weapon, the need to cleanup and return valuable or culturally significant resources to the public is nonetheless valid. Several private companies, universities and National Laboratories are currently developing novel RDD cleanup technologies. Because of its longstanding association with radioactive facilities, the U. S. Department of Energy National Laboratories are at the forefront in developing and testing new RDD decontamination methods. However, such cleanup technologies are likely to be fairly task specific; while many different contamination mechanisms, substrate and environmental conditions will make actual application more complicated. Some major efforts have also been made to model potential contamination, to evaluate both old and new decontamination techniques and to assess their readiness for use. There are a number of significant lessons that can be gained from a look at previous large scale cleanup projects. Too often we are quick to apply a costly 'package and dispose' method when sound technological cleaning approaches are available. Understanding historical perspectives, advanced planning and constant technology improvement are essential to successful decontamination. (authors)

  19. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    SciTech Connect (OSTI)

    Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-07-15

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  20. A Block-Structured KIVA Program for Engines with Vertical or Canted Valves

    Energy Science and Technology Software Center (OSTI)

    1999-08-23

    KIVA3VRELEASE2 is a computer program for the numerical calculation of transient, two and three-dimensional, chemically reactive flows with sprays. It is a newer version of the earlier KIVA3 (1993) that has now been extended to model vertical of canted valves in the cylinder head of a gasoline or diesel engine. KIVA3, in turn, was based on the earlier KIVA2 (1989) and uses the same numerical solution procedure and solves the same sort of equations. KIVA3VRELEASE2more » uses a block-structured mesh with connectivity defined through indirect addressing. The departure from a single rectangular structure in logical space allows complex geometries to be modeled with significantly greater efficiency because large regions of deactivated cells are no longer necessary. Cell-face boundary conditions permit greater flexibility and simplification in the application of boundary conditions. KIVA3VRELEASE2 contains a number of significant changes. New features enhance the robustness, efficiency, and usefullness of the overall program for engine modeling. Automatic restart of the cycle with a reduced timestep in case of iteration limit or temperature overflow will reduce code crashes. A new option provides automatic deactivation of a port region when it is closed from the cylinder and reactivation when it communicates with the cylinder. Corrections in the code improve accuracy; extensions to the particle-based liquid wall film model makes the model more complete and a spli injection option has been added. A new subroutine monitors the liquid and gaseous fuel phases and energy balance data and emissions are monitored and printed. New features have been added to the grid generator K3PREP and the graphics post processor, K3POST.« less

  1. 3-D seismic and reservoir modeling, ram prospect, Viosca Knoll Block 912, offshore Gulf of Mexico

    SciTech Connect (OSTI)

    Carew, W.; Ostendorf, P.F. ); Krum, G.K. )

    1993-09-01

    Ram prospect is a large stratigraphic trap located in Viosca Knoll Block 912/956/957, offshore Alabama in 3500-ft water depth. Reservoirs are Pliocene and Miocene gas- and oil-bearing deep-water sands deposited as fan complexes in an intraslope basin. The field has been proved by a total of 12 well penetrations and is nearing the development stage. In an effort to predict reservoir performance and recovery efficiencies, we constructed three-dimensional (3-D) reservoir models Exxon's in-house 3-D modeling program (GEOSET). Reservoir simulation studies will be based upon these 3-D geological models. We used 3-D seismic data to map seismic attributes around the prospect and well control to calibrate the seismic attributes based on known reservoir characteristics, thereby deriving a facies map for the entire field. Top/base structure, gross isopach, facies polygons, porosity, and Vshale were input into GEOSET to define the overall reservoir container and fill. The paucity of well data was compensated by using the 3-D-seismic based facies as a guide to filling polygons and by creating [open quotes]pseudowells[close quotes] from the real well data. These pseudowells aided in correlating within and between polygons. The resulting 3-D models (total porosity, effective porosity, Vsand) faithfully reflect the heterogeneity inferred from both 3-D seismic data and well control and provide visualization of reservoir continuity much better than models derived from well data alone. The models serve as a framework within which one can perform reservoir simulations and run various sensitivities. Additionally, the GEOSET porosity models can provide an alternative reservoir volume calculation.

  2. Decontamination Technologies, Task 3, Urban Remediation and Response Project

    SciTech Connect (OSTI)

    Heiser,J.; Sullivan, T.

    2009-06-30

    In the aftermath of a Radiological Dispersal Device (RDD, also known as a dirty bomb) it will be necessary to remediate the site including building exteriors and interiors, equipment, pavement, vehicles, personal items etc. Remediation will remove or reduce radioactive contamination from the area using a combination of removing and disposing of many assets (including possible demolition of buildings), decontaminating and returning to service other assets, and fixing in place or leaving in place contamination that is deemed 'acceptable'. The later will require setting acceptable dose standards, which will require negotiation with all involved parties and a balance of risk and cost to benefit. To accomplish the first two, disposal or decontamination, a combination of technologies will be deployed that can be loosely classified as: Decontamination; Equipment removal and size reduction; and Demolition. This report will deal only with the decontamination technologies that will be used to return assets to service or to reduce waste disposal. It will not discuss demolition, size reduction or removal technologies or equipment (e.g., backhoe mounted rams, rock splitter, paving breakers and chipping hammers, etc.). As defined by the DOE (1994), decontamination is removal of radiological contamination from the surfaces of facilities and equipment. Expertise in this field comes primarily from the operation and decommissioning of DOE and commercial nuclear facilities as well as a small amount of ongoing research and development closely related to RDD decontamination. Information related to decontamination of fields, buildings, and public spaces resulting from the Goiania and Chernobyl incidents were also reviewed and provide some meaningful insight into decontamination at major urban areas. In order to proceed with decontamination, the item being processed needs to have an intrinsic value that exceeds the cost of the cleaning and justifies the exposure of any workers during the

  3. State Energy Program and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    STATE ENERGY PROGRAM NOTICE 13-001 EECBG PROGRAM NOTICE 13-001 EFFECTIVE DATE: MARCH 21, 2013 SUBJECT: GUIDANCE FOR RETURNING INTEREST EARNED PURPOSE To provide an overview to the Department of Energy' s (DOE) State Energy Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program prime recipients (hereafter refe1Ted to as grantees) on guidance for the procedural requirements of returning interest earned on advanced Federal funds . This guidance does not create new

  4. Analysis of sheltering and evacuation strategies for an urban nuclear detonation scenario.

    SciTech Connect (OSTI)

    Yoshimura, Ann S.; Brandt, Larry D.

    2009-05-01

    Development of an effective strategy for shelter and evacuation is among the most important planning tasks in preparation for response to a low yield, nuclear detonation in an urban area. This study examines shelter-evacuate policies and effectiveness focusing on a 10 kt scenario in Los Angeles. The goal is to provide technical insights that can support development of urban response plans. Results indicate that extended shelter-in-place can offer the most robust protection when high quality shelter exists. Where less effective shelter is available and the fallout radiation intensity level is high, informed evacuation at the appropriate time can substantially reduce the overall dose to personnel. However, uncertainties in the characteristics of the fallout region and in the exit route can make evacuation a risky strategy. Analyses indicate that only a relatively small fraction of the total urban population may experience significant dose reduction benefits from even a well-informed evacuation plan.

  5. Self-reliant cities: energy and the transformation of urban America

    SciTech Connect (OSTI)

    Morris, D.

    1982-01-01

    An urban strategist looks at the patterns of urban energy use through history and offers a blueprint for urban survival in a resource-conscious age. Morris follows the evolution of American cities from self-sufficient frontier villages to compact city cores, which vanished when the automobile created suburban towns without centers, separated home from workplace, and removed the production of goods from their consumption. Transmission of electricity at nominal cost brought energy across increasing distances for energy-hungry consumers. Since the 1973 oil embargo, communities have faced the twin problems of rising energy costs and deepening resource shortages. Morris envisions a near-future city where production and consumption are closely linked and where the wastes of one process are the raw materials of another. 87 references, 4 figures, 3 tables.

  6. Mixed-Salt Effects on the Ionic Conductivity of Lithium-Doped PEO-Containing Block Copolymers

    SciTech Connect (OSTI)

    Young, Wen-Shiue; Albert, Julie N.L.; Schantz, A. Benjamin; Epps, III, Thomas H.

    2012-10-10

    We demonstrate a simple, yet effective, mixed-salt method to increase the room temperature ionic conductivity of lithium-doped block copolymer electrolyte membranes by suppressing the crystalline phases in the conducting block. We examined a mixed-salt system of LiClO{sub 4} and LiN(SO{sub 2}CF{sub 3}){sub 2} (LiTFSI) doped into a lamellae-forming poly(styrene-b-ethylene oxide) (PS-PEO) diblock copolymer. The domain spacings, morphologies, thermal behavior, and crystalline phases of salt-doped PS-PEO samples were characterized, and the ionic conductivities of block copolymer electrolytes were obtained through ac impedance measurements. Comparing the ionic conductivity profiles of salt-doped PS-PEO samples at different mixed-salt ratios and total salt concentrations, we found that the ionic conductivity at room temperature can be improved by more than an order of magnitude when coinhibition of crystallite growth is promoted by the concerted behavior of the PEO:LiClO{sub 4} and PEO:LiTFSI phases. Additionally, we examined the influence of mixed-salt ratio and total salt concentration on copolymer energetics, and we found that the slope of the effective interaction parameter ({chi}{sub eff}) vs salt concentration in our lamellae-forming PS-PEO system was lower than that reported for a cylinder-forming PS-PEO system due to the balance between chain stretching and salt segregation in the PEO domains.

  7. Thermoreversible Changes in Aligned and Cross-Linked Block Copolymer Melts Studied by Two Color Depolarized Light Scattering

    SciTech Connect (OSTI)

    Wilbur, Jeffrey D.; Gomez, Enrique D.; Ellsworth, Mark W.; Garetz, Bruce A.; Balsara, Nitash P.

    2012-09-04

    A procedure for creating samples that can be repeatedly cycled between weakly aligned and strongly aligned states is described. Poly(styrene-b-isoprene) block copolymer samples were first shear-aligned and then cross-linked using a high energy electron beam. Samples with more than 1.0 cross-links per chain on average showed almost complete recovery of their initial alignment state even after 20 cycles of heating above the order–disorder transition temperature of the un-cross-linked block copolymer. Samples with 1.1 cross-links per chain, which showed over 90% loss of alignment on heating and almost 100% recovery of alignment on cooling, provided the best example of a reversible aligned-to-unaligned transition. Samples with lower cross-linking densities exhibited irreversible loss of alignment upon heating, while those with higher cross-linking densities exhibited less than 90% loss of alignment upon heating. Alignment was quantified by a technique that we call two color depolarized light scattering (TCDLS), an extension of the traditional depolarized light scattering experiment used to determine the state of order in block copolymers. Qualitative confirmation of our interpretation of TCDLS data was obtained by small-angle X-ray scattering and transmission electron microscopy.

  8. Final Technical Report - Commercially Important Carbohydrate Diacids - Building Blocks from Renewable Carbohydrates

    SciTech Connect (OSTI)

    Kiely, Donald E.

    2009-01-07

    The primary objective of this project was to develop oxidation methods appropriate for the conversion of agriculturally derived simple sugars to their corresponding diacids (aldaric acids) for use as biobased chemical building blocks for new biodegradable polymers and other materials. Principal target diacids were D-glucaric, meso-xylaric, D-mannaric and L-arabinaric acid, each to be prepared by nitric acid oxidation of the naturally occurring precursor carbohydrates (monosaccharides) D-glucose, D-xylose, D-mannose and L-arabinose, respectively, all from hydrolysis of naturally abundant plant polysaccharides. These conversions were to be designed for scale up to a level suitable for transfer first to a pilot plant scale, and then to an industrial plant scale. The core of the project involved a comprehensive study of the title oxidation employing a computer controlled reactor. The plan of action involved defining experimental parameters to allow for control of the oxidations with considerable precision and reproducibility. The prototype oxidations were typically run using ca. 0.75 molar amounts of carbohydrate, with a goal of eventually doubling the reaction size when appropriate reaction parameters were established. During the course of the funding period for this grant, the fundamentals of reaction control were established for oxidation of D-glucose, a critical component of the project given the exothermic character of the reaction. The reactions were monitored using a reliable GC/MS protocol. The glucose to glucaric acid conversion represented the most important and potentially highest value conversion. During the grant period we were able to establish one workable system to carry out the glucose to glucaric acid conversion, but were not able to optimize the process or establish a protocol that was satisfactory for a scale up to a pilot plant scale. However, the work carried out showed the possibility that with appropriate innovation and continued effort, a

  9. Pore size distribution and methane equilibrium conditions at Walker Ridge Block 313, northern Gulf of Mexico

    SciTech Connect (OSTI)

    Bihani, Abhishek; Daigle, Hugh; Cook, Ann; Glosser, Deborah; Shushtarian, Arash

    2015-12-15

    Coexistence of three methane phases (liquid (L), gas (G), hydrate (H)) in marine gas hydrate systems may occur according to in-situ pressure, temperature, salinity and pore size. In sediments with salinity close to seawater, a discrete zone of three-phase (3P) equilibrium may occur near the base of the regional hydrate stability zone (RHSZ) due to capillary effects. The existence of a 3P zone influences the location of the bottom-simulating reflection (BSR) and has implications for methane fluxes at the base of the RHSZ. We studied hydrate stability conditions in two wells, WR313-G and WR313-H, at Walker Ridge Block 313 in the northern Gulf of Mexico. We determined pore size distributions (PSD) by constructing a synthetic nuclear magnetic resonance (NMR) relaxation time distribution. Correlations were obtained by non-linear regression on NMR, gamma ray, and bulk density logs from well KC-151 at Keathley Canyon. The correlations enabled construction of relaxation time distributions for WR313-G and WR313-H, which were used to predict PSD through comparison with mercury injection capillary pressure measurements. With the computed PSD, L+H and L+G methane solubility was determined from in-situ pressure and temperature. The intersection of the L+G and L+H curves for various pore sizes allowed calculation of the depth range of the 3P equilibrium zone. As in previous studies at Blake Ridge and Hydrate Ridge, the top of the 3P zone moves upwards with increasing water depth and overlies the bulk 3P equilibrium depth. In clays at Walker Ridge, the predicted thickness of the 3P zone is approximately 35 m, but in coarse sands it is only a few meters due to the difference in absolute pore sizes and the width of the PSD. The thick 3P zone in the clays may explain in part why the BSR is only observed in the sand layers at Walker Ridge, although other factors may influence the presence or absence of a BSR.

  10. A study of the Oklahoma City urban heat island using ground measurements and remote sensing

    SciTech Connect (OSTI)

    Brown, M. J.; Ivey, A.; McPherson, T. N.; Boswell, D.; Pardyjak, E. R.

    2004-01-01

    Measurements of temperature and position were collected during the night from an instrumented van on routes through Oklahoma City and the rural outskirts. The measurements were taken as part of the Joint URBAN 2003 Tracer Field Experiment conducted in Oklahoma City from June 29, 2003 to July 30, 2003 (Allwine et al., 2004). The instrumented van was driven over four primary routes that included legs from the downtown core to four different 'rural' areas. Each route went through residential areas and most often went by a line of permanently fixed temperature probes (Allwine et al., 2004) for cross-checking purposes. Each route took from 20 to 40 minutes to complete. Based on seven nights of data, initial analyses indicate that there was a temperature difference of 0.5-6.5 C between the urban core and nearby 'rural' areas. Analyses also suggest that there were significant fine scale temperature differences over distances of tens of meters within the city and in the nearby rural areas. The temperature measurements that were collected are intended to supplement the meteorological measurements taken during the Joint URBAN 2003 Field Experiment, to assess the importance of the urban heat island phenomenon in Oklahoma City, and to test new urban canopy parameterizations that have been developed for regional scale meteorological codes (e.g., Chin et al., 2000; Holt and Shi, 2004). In addition to the ground measurements, skin temperature measurements were also analyzed from remotely sensed images taken from the Earth Observing System's Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER). A surface kinetic temperature thermal infrared image captured by the ASTER of the Oklahoma City area on July 21, 2001 was analyzed within ESRI's ArcGIS 8.3 to correlate variations in temperature with land use type. Analysis of this imagery suggests distinct variations in temperature across different land use categories. Through the use of remotely sensed imagery we hope to

  11. Table HC7-8a. Home Office Equipment by Urban/Rural Location,

    U.S. Energy Information Administration (EIA) Indexed Site

    8a. Home Office Equipment by Urban/Rural Location, Million U.S. Households, 2001 Home Office Equipment RSE Column Factor: Total Urban/Rural Location 1 RSE Row Factors City Town Suburbs Rural 0.5 0.9 1.3 1.2 1.4 Total .............................................................. 107.0 49.9 18.0 21.2 17.9 4.1 Households Using Office Equipment ......................................... 96.2 43.9 16.0 20.2 16.1 4.1 Personal Computers 2 ................................. 60.0 25.6 9.3 15.0 10.1 4.7

  12. Urban Electric Power Takes Energy Storage from Startup to Grid-Scale |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Urban Electric Power Takes Energy Storage from Startup to Grid-Scale Urban Electric Power Takes Energy Storage from Startup to Grid-Scale June 25, 2013 - 12:42pm Addthis Learn how the CUNY Energy Institute is creating safe, low cost, rechargeable, long lifecycle batteries that could be used to store renewable energy. | Video courtesy of the Energy Department. Alexa McClanahan Communications Support Contractor to ARPA-E What are the key facts? The CUNY Energy Institute

  13. Urban leakage of liquefied petroleum gas and its impact on Mexico City air quality

    SciTech Connect (OSTI)

    Blake, D.R.; Rowland, F.S.

    1995-08-18

    Alkane hydrocarbons (propane, isobutane, and n-butane) from liquefied petroleum gas (LPG) are present in major quantities throughout Mexico City air because of leakage of the unburned gas from numerous urban sources. These hydrocarbons, together with olefinic minor LPG components, furnish substantial amounts of hydroxyl radical reactivity, a major precursor to formation of the ozone component of urban smog. The combined processes of unburned leakage and incomplete combustion of LPG play significant role in causing the excessive ozone characteristic of Mexico City. Reductions in ozone levels should be possible through changes in LPG composition and lowered rates of leakage. 23 refs., 3 tabs.

  14. Compressible Solution Properties of Amorphous Polystyrene-block-Polybutadiene, Crystalline Polystyrene-block-Poly(Hydrogenated Polybutadiene) and Their Corresponding Homopolymers: Fluid-Fluid, Fluid-Solid and Fluid-Micelle Phase Transitions in Propane and Propylene

    SciTech Connect (OSTI)

    Hong, Kunlun; Mays, Jimmy; Winoto, Winoto; Radosz, Maciej

    2009-01-01

    Abstract Polystyrene, polybutadiene, hydrogenated polybutadiene, and styrene diblock copolymers of these homopolymers can form homogenous solutions in compressible solvents, such as propane and propylene, which separate into two bulk phases upon reducing pressure. The cloud and micellization pressures for homopolymer and diblock copolymers are generally found to be higher in propane than in propylene, except for hydrogenated polybutadiene and polystyrene-block-(hydrogenated polybutadiene). Hydrogenated polybutadiene homopolymers and copolymers exhibit relatively pressure-independent crystallization and melting observed in both propane and propylene solutions.

  15. Energy in the urban environment. Proceedings of the 22. annual Illinois energy conference

    SciTech Connect (OSTI)

    1994-12-31

    The conference addressed the energy and environmental challenges facing large metropolitan areas. The topics included a comparison of the environmental status of cities twenty years ago with the challenges facing today`s large cities, sustainable economic development, improving the energy and environmental infrastructure, and the changing urban transportation sector. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  16. Improving Building Performance at Urban Scale with a Framework for Real-time Data Sharing

    SciTech Connect (OSTI)

    Pang, Xiufeng; Hong, Tianzhen; Piette, Mary Ann

    2013-06-03

    This paper describes work in progress toward an urban-scale system aiming to reduce energy use in neighboring buildings by providing three components: a database for accessing past and present weather data from high quality weather stations; a network for communicating energy-saving strategies between building owners; and a set of modeling tools for real-time building energy simulation.

  17. USDA National Urban and Community Forestry Challenge Cost Share Grant Program

    Broader source: Energy.gov [DOE]

    The U.S. Department of Agriculture is accepting proposals for the National Urban and Community Forestry Challenge Cost Share Grant Program to assist the U.S. Forest Service in establishing the grant categories and recommendations of final proposals for the Forest Service to consider.

  18. Sorption (Kd) measurements on cinder block and grout in support of dose assessments for Zion Nuclear Station decommissioning

    SciTech Connect (OSTI)

    Milian L.; Sullivan T.

    2014-06-24

    The Zion Nuclear Power Station is being decommissioned. ZionSolutions proposes to leave much of the below grade structures in place and to fill them with a backfill to provide structural support. Backfills under consideration include clean concrete demolition debris from the above grade parts of the facility, a flowable grout, cinder block construction debris and sand. A previous study (Yim, 2012) examined the sorption behavior of five nuclides (Fe-55, Co-60, Ni-63, Sr-85, and Cs-137) on concrete and local soils. This study, commissioned by ZionSolutions and conducted by the Brookhaven National Laboratory (BNL) examines the sorption behavior on cinder block and grout materials. Specifically, this study measured the distribution coefficient for four radionuclides of concern using site-groundwater and cinder block from the Zion site and a flowable grout. The distributions coefficient is a measure of the amount of the radionuclide that will remain sorbed to the solid material that is present relative to the amount that will remain in solution. A high distribution coefficient indicates most of the radionuclide will remain on the solid material and will not be available for transport by the groundwater. The radionuclides examined in this set of tests were Co-60, Ni-63, Sr-85, and Cs-137. Tests were performed following ASTM C1733-10, Standard Test Methods for Distribution Coefficients of Inorganic Species by the Batch Method. Sr-85 was used in the testing as an analogue for Sr-90 because it behaves similarly with respect to sorption and has a gamma emission that is easier to detect than the beta emission from Sr-90.

  19. Radiative forcing and temperature response to changes in urban albedos and associated CO2 offsets

    SciTech Connect (OSTI)

    Menon, Surabi; Akbari, Hashem; Mahanama, Sarith; Sednev, Igor; Levinson, Ronnen

    2010-02-12

    The two main forcings that can counteract to some extent the positive forcings from greenhouse gases from pre-industrial times to present-day are the aerosol and related aerosol-cloud forcings, and the radiative response to changes in surface albedo. Here, we quantify the change in radiative forcing and land surface temperature that may be obtained by increasing the albedos of roofs and pavements in urban areas in temperate and tropical regions of the globe by 0.1. Using the catchment land surface model (the land model coupled to the GEOS-5 Atmospheric General Circulation Model), we quantify the change in the total outgoing (outgoing shortwave+longwave) radiation and land surface temperature to a 0.1 increase in urban albedos for all global land areas. The global average increase in the total outgoing radiation was 0.5 Wm{sup -2}, and temperature decreased by {approx}0.008 K for an average 0.003 increase in surface albedo. These averages represent all global land areas where data were available from the land surface model used and are for the boreal summer (June-July-August). For the continental U.S. the total outgoing radiation increased by 2.3 Wm{sup -2}, and land surface temperature decreased by {approx}0.03 K for an average 0.01 increase in surface albedo. Based on these forcings, the expected emitted CO{sub 2} offset for a plausible 0.25 and 0.15 increase in albedos of roofs and pavements, respectively, for all global urban areas, was found to be {approx} 57 Gt CO{sub 2}. A more meaningful evaluation of the impacts of urban albedo increases on global climate and the expected CO{sub 2} offsets would require simulations which better characterizes urban surfaces and represents the full annual cycle.

  20. It's a Bird, It's a Plane, It's Super-ion Building Blocks | U.S. DOE Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Science (SC) It's a Bird, It's a Plane, It's Super-ion Building Blocks Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 07.25.16 It's a Bird,

  1. Guidance on the Required Period for Grantees to Obligate Funds and the Procedures for Reporting of Obligated Funds for the Energy Efficiency Conservation Block Grant (EECBG) Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EECBG PROGRAM NOTICE 11-003 EFFECTIVE DATE: NOVEMBER 1, 2011 SUBJECT: GUIDANCE ON THE REQUIRED PERIOD FOR GRANTEES TO OBLIGATE FUNDS AND THE PROCEDURES FOR REPORTING OF OBLIGATED FUNDS FOR THE ENERGY EFFICIENCY CONSERVATION BLOCK GRANT PROGRAM (EECBG) PURPOSE To provide guidance and clarify the required period for obligation of funds as established in the Energy Efciency Conservation Block Grant (EECBG) Program Funding Opportunit Announcements (FOAs) Number DE-FOA-0000013 and DE-FOA-0000148, and

  2. Population genomics of the Anthropocene: Urbanization is negatively associated with genome-wide variation in white-footed mouse populations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Munshi-South, Jason; Zolnik, Christine P.; Harris, Stephen E.

    2016-02-11

    Urbanization results in pervasive habitat fragmentation and reduces standing genetic variation through bottlenecks and drift. Loss of genomewide variation may ultimately reduce the evolutionary potential of animal populations experiencing rapidly changing conditions. In this study, we examined genomewide variation among 23 white-footed mouse (Peromyscus leucopus) populations sampled along an urbanization gradient in the New York City metropolitan area. Genomewide variation was estimated as a proxy for evolutionary potential using more than 10000 single nucleotide polymorphism (SNP) markers generated by ddRAD-Seq. We found that genomewide variation is inversely related to urbanization as measured by percent impervious surface cover, and to amore » lesser extent, human population density. We also report that urbanization results in enhanced genomewide differentiation between populations in cities. There was no pattern of isolation by distance among these populations, but an isolation by resistance model based on impervious surface significantly explained patterns of genetic differentiation. Isolation by environment modeling also indicated that urban populations deviate much more strongly from global allele frequencies than suburban or rural populations. Lastly, this study is the first to examine loss of genomewide SNP variation along an urban-to-rural gradient and quantify urbanization as a driver of population genomic patterns.« less

  3. A technical review of urban land use - transportation models as tools for evaluating vehicle travel reduction strategies

    SciTech Connect (OSTI)

    Southworth, F.

    1995-07-01

    The continued growth of highway traffic in the United States has led to unwanted urban traffic congestion as well as to noticeable urban air quality problems. These problems include emissions covered by the 1990 Clean Air Act Amendments (CAAA) and 1991 Intermodal Surface Transportation Efficiency Act (ISTEA), as well as carbon dioxide and related {open_quotes}greenhouse gas{close_quotes} emissions. Urban travel also creates a major demand for imported oil. Therefore, for economic as well as environmental reasons, transportation planning agencies at both the state and metropolitan area level are focussing a good deal of attention on urban travel reduction policies. Much discussed policy instruments include those that encourage fewer trip starts, shorter trip distances, shifts to higher-occupancy vehicles or to nonvehicular modes, and shifts in the timing of trips from the more to the less congested periods of the day or week. Some analysts have concluded that in order to bring about sustainable reductions in urban traffic volumes, significant changes will be necessary in the way our households and businesses engage in daily travel. Such changes are likely to involve changes in the ways we organize and use traffic-generating and-attracting land within our urban areas. The purpose of this review is to evaluate the ability of current analytic methods and models to support both the evaluation and possibly the design of such vehicle travel reduction strategies, including those strategies involving the reorganization and use of urban land. The review is organized into three sections. Section 1 describes the nature of the problem we are trying to model, Section 2 reviews the state of the art in operational urban land use-transportation simulation models, and Section 3 provides a critical assessment of such models as useful urban transportation planning tools. A number of areas are identified where further model development or testing is required.

  4. ANALYSIS OF 3-D URBAN DATABASES WITH RESPECT TO POLLUTION DISPERSION FOR A NUMBER OF EUROPEAN AND AMERICAN CITIES

    SciTech Connect (OSTI)

    C. RATTI; ET AL

    2001-03-01

    Models to estimate pollution dispersion and wind flow in cities (both at the city-scale and above) require a parametrical description of the urban canopy. For instance, two key parameters are the aerodynamic roughness length z{sub 0} and the zero-plane displacement height z{sub d}, which are related, amongst others, to the surface drag coefficient, the scale and intensity of turbulence, the depth of the roughness sub-layer and the wind speed profile. The calculation of z{sub 0} and z{sub d}, however, is not straightforward. The classical way to estimate them in open terrain is based on the measurement of wind profile data from a tall mast or, less accurately, on the inference from published roughness values for similar terrain elsewhere (Davenport, 1960; Davenport et al., 2000). Both methods, however, are very difficult to apply to cities, due to the considerable height where wind measurements should be taken (well above the urban canopy) and to the irregularities of urban texture. A promising alternative that has become available in recent years, due to increasing computing resources and the availability of high-resolution 3-D databases in urban areas, is based on the calculation of z{sub 0} and z{sub d} from the analysis and measure of the city geometry (urban morphometry). This method is reviewed for instance in Grimmond and Oke (1999), where values are calculated using different formulas and then compared with the results of field measurements. Urban morphometry opens up a new range of parameters that can easily be calculated in urban areas and used as input for meso-scale and urban dispersion models. This paper reviews a number of them and shows how they could be calculated from urban Digital Elevation Models (DEM) using image-processing techniques. It builds up on the recent work by Ratti et al. 2000, extending the number of case studies cities: London, Toulouse, Berlin, Salt Lake City and Los Angeles.

  5. Lectin-functionalized poly(glycidyl methacrylate)-block-poly(vinyldimethyl azlactone) surface supports for high avidity microbial capture

    SciTech Connect (OSTI)

    Hansen, Ryan R; Hinestrosa Salazar, Juan P; Shubert, Katherine R; Morrell, Jennifer L.; Pelletier, Dale A; Messman, Jamie M; Kilbey, II, S Michael; Lokitz, Bradley S; Retterer, Scott T

    2013-01-01

    Microbial exopolysaccharides (EPS) play a critical and dynamic role in shaping the interactions between microbial community members and their local environment. The capture of targeted microbes using surface immobilized lectins that recognize specific extracellular oligosaccharide moieties offers a non-destructive method for functional characterization based on EPS content. In this report, we evaluate the use of the block co-polymer, poly(glycidyl methacrylate)-block-4,4-dimethyl-2-vinylazlactone (PGMA-b-PVDMA), as a surface support for lectin-specific microbial capture. Arrays of circular polymer supports ten micron in diameter were generated on silicon substrates to provide discrete, covalent coupling sites for Triticum vulgare and Lens culinaris lectins. These supports promoted microbe adhesion and colony formation in a lectin-specific manner. Silicon posts with similar topography containing only physisorbed lectins showed significantly less activity. These results demonstrate that micropatterned PGMA-b-PVDMA supports provide a unique platform for microbial capture and screening based on EPS content by combining high avidity lectin surfaces with three-dimensional topography.

  6. Feeling lucky? Using search engines to assess perceptions of urban sustainability

    SciTech Connect (OSTI)

    Keirstead, James

    2009-02-15

    The sustainability of urban environments is an important issue at both local and international scales. Indicators are frequently used by decision-makers seeking to improve urban performance but these metrics can be dependent on sparse quantitative data. This paper explores the potential of an alternative approach, using an internet search engine to quickly gather qualitative data on the key attributes of cities. The method is applied to 21 world cities and the results indicate that, while the technique does shed light on direct and indirect aspects of sustainability, the validity of derived metrics as objective indicators of long-term sustainability is questionable. However the method's ability to provide subjective short-term assessments is more promising and it could therefore play an important role in participatory policy exercises such as public consultations. A number of promising technical improvements to the method's performance are also highlighted.

  7. Combatting urban air pollution through Natural Gas Vehicle (NGV) analysis, testing, and demonstration

    SciTech Connect (OSTI)

    1995-03-01

    Deteriorating urban air quality ranks as a top concern worldwide, since air pollution adversely affects both public health and the environment. The outlook for improving air quality in the world`s megacities need not be bleak, however, The use of natural gas as a transportation fuel can measurably reduce urban pollution levels, mitigating chronic threats to health and the environment. Besides being clean burning, natural gas vehicles (NGVs) are economical to operate and maintain. The current cost of natural gas is lower than that of gasoline. Natural gas also reduces the vehicle`s engine wear and noise level, extends engine life, and decreases engine maintenance. Today, about 700,000 NGVs operate worldwide, the majority of them converted from gasoline or diesel fuel. This article discusses the economic, regulatory and technological issues of concern to the NGV industry.

  8. Autonomous UAV-Based Mapping of Large-Scale Urban Firefights

    SciTech Connect (OSTI)

    Snarski, S; Scheibner, K F; Shaw, S; Roberts, R S; LaRow, A; Oakley, D; Lupo, J; Neilsen, D; Judge, B; Forren, J

    2006-03-09

    This paper describes experimental results from a live-fire data collect designed to demonstrate the ability of IR and acoustic sensing systems to detect and map high-volume gunfire events from tactical UAVs. The data collect supports an exploratory study of the FightSight concept in which an autonomous UAV-based sensor exploitation and decision support capability is being proposed to provide dynamic situational awareness for large-scale battalion-level firefights in cluttered urban environments. FightSight integrates IR imagery, acoustic data, and 3D scene context data with prior time information in a multi-level, multi-step probabilistic-based fusion process to reliably locate and map the array of urban firing events and firepower movements and trends associated with the evolving urban battlefield situation. Described here are sensor results from live-fire experiments involving simultaneous firing of multiple sub/super-sonic weapons (2-AK47, 2-M16, 1 Beretta, 1 Mortar, 1 rocket) with high optical and acoustic clutter at ranges up to 400m. Sensor-shooter-target configurations and clutter were designed to simulate UAV sensing conditions for a high-intensity firefight in an urban environment. Sensor systems evaluated were an IR bullet tracking system by Lawrence Livermore National Laboratory (LLNL) and an acoustic gunshot detection system by Planning Systems, Inc. (PSI). The results demonstrate convincingly the ability for the LLNL and PSI sensor systems to accurately detect, separate, and localize multiple shooters and the associated shot directions during a high-intensity firefight (77 rounds in 5 sec) in a high acoustic and optical clutter environment with no false alarms. Preliminary fusion processing was also examined that demonstrated an ability to distinguish co-located shooters (shooter density), range to <0.5 m accuracy at 400m, and weapon type.

  9. Spatial and temporal variations in toxicity in a marsh receiving urban runoff

    SciTech Connect (OSTI)

    Katznelson, R.; Jewell, W.T.; Anderson, S.L.

    1993-06-01

    This project is composed of two sections. The first section describes dry weather toxicity surveys to evaluate the distribution of toxicity in the waters of San Francisco Bay and adjacent wetland habitat, and the second is a series of wet weather toxicity studies with emphasis on a marsh receiving urban runoff. The dry weather studies are reported in the appendices, while the wet weather work comprises the main report.

  10. Literature survey of blast and fire effects of nuclear weapons on urban areas

    SciTech Connect (OSTI)

    Reitter, T.A.; McCallen, D.B.; Kang, S.W.

    1982-06-01

    The American literature of the past 30 years on fire and blast effects of nuclear weapons on urban areas has been surveyed. The relevant work is briefly sketched and areas where information is apparently lacking are noted. This report is intended to provide the basis for suggesting research priorities in the fire and blast effects area for the Federal Emergency Management Agency. It is also intended to provide entry into the literature for researchers. over 850 references are given.

  11. Impacts of urban transportation mode split on CO{sub 2} emissions in Jinan, China.

    SciTech Connect (OSTI)

    He, D.; Meng, F.; Wang, M.; He, K.

    2011-04-01

    As the world's largest developing country, China currently is undergoing rapid urbanization and motorization, which will result in far-reaching impacts on energy and the environment. According to estimates, energy use and carbon emissions in the transportation sector will comprise roughly 30% of total emissions by 2030. Since the late 1990s, transportation-related issues such as energy, consumption, and carbon emissions have become a policy focus in China. To date, most research and policies have centered on vehicle technologies that promote vehicle efficiency and reduced emissions. Limited research exists on the control of greenhouse gases through mode shifts in urban transportation - in particular, through the promotion of public transit. The purpose of this study is to establish a methodology to analyze carbon emissions from the urban transportation sector at the Chinese city level. By using Jinan, the capital of China's Shandong Province, as an example, we have developed an analytical model to simulate energy consumption and carbon emissions based on the number of trips, the transportation mode split, and the trip distance. This model has enabled us to assess the impacts of the transportation mode split on energy consumption and carbon emissions. Furthermore, this paper reviews a set of methods for data collection, estimation, and processing for situations where statistical data are scarce in China. This paper also describes the simulation of three transportation system development scenarios. The results of this study illustrate that if no policy intervention is implemented for the transportation mode split (the business-as-usual (BAU) case), then emissions from Chinese urban transportation systems will quadruple by 2030. However, a dense, mixed land-use pattern, as well as transportation policies that encourage public transportation, would result in the elimination of 1.93 million tons of carbon emissions - approximately 50% of the BAU scenario emissions.

  12. URBAN ATMOSPHERIC OBSERVATORY (UAO) FIRST PLANNING WORKSHOP, JANUARY 27-28-2003. WORKSHOP SUMMARY.

    SciTech Connect (OSTI)

    REYNOLDS,R.M.; LEE,H.N.

    2003-03-27

    The Urban Atmospheric Observatory (UAO) First Planning Workshop was held on 27-28 January 2003 at the Environmental Measurements Laboratory (EML) in downtown Manhattan, New York City. The meeting was well attended by local, state, and national administrators, as well as scientists and engineers from the national laboratories and academia. The real-time intensive UAO is a necessary step toward the development and validation of new technologies in support of the New York City emergency management and anti-terrorism effort. The real-time intensive UAO will be a dense array of meteorological instrumentation, remote sensing and satellite products and model output, as well as radiation detection, gamma spectrometer and aerosol measurements focused onto a small area in the heart of Manhattan. Such a test-bed, developed in a somewhat homogeneous urban area, and with a well-developed communication and data collection backbone, will be of immense utility for understanding how models of all scales can be improved and how they can best be integrated into the city's emergency program. The goal of the First Planning Workshop was to bring together a small group of experts in the fields of urban meteorology, modeling from mesoscale to fine-mesh computational fluid dynamics, instrumentation, communications and visualization, in order to (1) establish the importance of the observational program, (2) define the most efficient and cost-effective design for the program, (3) define needed intensive observational efforts and establish a schedule, and (4) define the importance of the UAO in emergency operations. The workshop achieved its goals with the enthusiastic participation of over forty persons. There was a synthesis of ideas towards a world-class facility that would benefit both immediate emergency management activities and, over an extended time, the entire field of urban meteorology and contaminant dispersion modeling.

  13. CERC-BEE Cool Roofs and Urban Heat Islands: infrastructure and anti-soiling coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ronnen Levinson, Staff Scientist, LBNL RMLevinson@LBL.gov Scott Hunter, Senior Research Scientist, ORNL HunterSR@ORNL.gov CERC-BEE Cool Roofs and Urban Heat Islands: infrastructure and anti-soiling coatings 2014 Building Technologies Office Peer Review 2 Project Summary (Cool Roof Infrastructure) Timeline: Start date: January 2011 Planned end date: December 2015 Key Milestones 1. Initiate natural exposure trials in many Chinese cities for roof product rating (6/2014) 2. Start black/white/garden

  14. Regional climate effects of irrigation and urbanization in thewestern united states: a model intercomparison

    SciTech Connect (OSTI)

    Snyder, M.A.; Kueppers, L.M.; Sloan, L.C.; Cavan, D.C.; Jin, J.; Kanamaru, H.; Miller, N.L.; Tyree, M.; Du, H.; Weare, B.

    2006-05-01

    In the western United States, more than 30,500 square miles has been converted to irrigated agriculture and urban areas. This study compares the climate responses of four regional climate models (RCMs) to these past land-use changes. The RCMs used two contrasting land cover distributions: potential natural vegetation, and modern land cover that includes agriculture and urban areas. Three of the RCMs represented irrigation by supplementing soil moisture, producing large decreases in August mean (-2.5 F to -5.6 F) and maximum (-5.2 F to -10.1 F) 2-meter temperatures where natural vegetation was converted to irrigated agriculture. Conversion to irrigated agriculture also resulted in large increases in relative humidity (9 percent 36 percent absolute change). Only one of the RCMs produced increases in summer minimum temperature. Converting natural vegetation to urban land cover produced modest but discernable climate effects in all models, with the magnitude of the effects dependent upon the preexisting vegetation type. Overall, the RCM results indicate that land use change impacts are most pronounced during the summer months, when surface heating is strongest and differences in surface moisture between irrigated land and natural vegetation are largest. The irrigation effect on summer maximum temperatures is comparable in magnitude (but opposite in sign) to predicted future temperature change due to increasing greenhouse gas concentrations.

  15. X-ray microprobe studies of Hungarian background and urban aerosols

    SciTech Connect (OSTI)

    Toeroek, S.; Sandor, S.; Xhoffer, C.; Van Grieken, R.; Jones, K.W.; Sutton, S.R.; Rivers, M.L.

    1991-10-01

    In order to determine the polluting atmospheric sources in urban and background areas source apportionment of the air particulate matter is necessary. Hitherto these studies were mostly based on bulk composition measurements of the aerosol. Source profiles, i.e. the concentrations of several elements for air particulate matter originating from one source, can be deduced from the receptor data using a number of multivariate techniques among which the chemical mass balance. The application is limited by the large number of observations that must be made for each of the variables. Often an elaborated sample preparation is necessary for fractionating the sample into several sub samples, according to the density, particle diameter or other relevant properties. Often this may results in poorly resolved source profiles. The aim of the present work is to find the relative abundance of the particle types originating from two different background monitoring stations in the middle of the Great Hungarian Plain. In urban areas most pollutants originate from traffic and municipal waste incineration. Since heavy metals play an important role in these samples the highly sensitive x-ray microscope (XRM) of the National Synchrotron Light Source (NSLS) of the Brookhaven National Laboratory was used. A feasibility study on individual aerosol particles sampled at the above background stations and in the urban area of Budapest is discussed.

  16. Alternative energy facility siting policies for urban coastal areas: executive summary of findings and policy recommendations

    SciTech Connect (OSTI)

    Morell, D; Singer, G

    1980-11-01

    An analysis was made of siting issues in the coastal zone, one of the nation's most critical natural resource areas and one which is often the target for energy development proposals. The analysis addressed the changing perceptions of citizens toward energy development in the coastal zone, emphasizing urban communities where access to the waterfront and revitalization of waterfront property are of interest to the citizen. The findings of this analysis are based on an examination of energy development along New Jersey's urban waterfront and along the Texas-Louisiana Gulf Coast, and on redevelopment efforts in Seattle, San Francisco, Boston, and elsewhere. The case studies demonstrate the significance of local attitudes and regional cooperation in the siting process. In highly urbanized areas, air quality has become a predominant concern among citizen groups and an influential factor in development of alternative energy facility siting strategies, such as consideration of inland siting connected by pipeline to a smaller coastal facility. The study addresses the economic impact of the permitting process on the desirability of energy facility investments, and the possible effects of the location selected for the facility on the permitting process and investment economics. The economic analysis demonstrates the importance of viewing energy facility investments in a broad perspective that includes the positive or negative impacts of various alternative siting patterns on the permitting process. Conclusions drawn from the studies regarding Federal, state, local, and corporate politics; regulatory, permitting, licensing, environmental assessment, and site selection are summarized. (MCW)

  17. Resource recovery from urban stock, the example of cadmium and tellurium from thin film module recycling

    SciTech Connect (OSTI)

    Simon, F.-G.; Holm, O.; Berger, W.

    2013-04-15

    Highlights: ► The semiconductor layer on thin-film photovoltaic modules can be removed from the glass-plate by vacuum blast cleaning. ► The separation of blasting agent and semiconductor can be performed using flotation with a valuable yield of 55%. ► PV modules are a promising source for the recovery of tellurium in the future. - Abstract: Raw material supply is essential for all industrial activities. The use of secondary raw material gains more importance since ore grade in primary production is decreasing. Meanwhile urban stock contains considerable amounts of various elements. Photovoltaic (PV) generating systems are part of the urban stock and recycling technologies for PV thin film modules with CdTe as semiconductor are needed because cadmium could cause hazardous environmental impact and tellurium is a scarce element where future supply might be constrained. The paper describes a sequence of mechanical processing techniques for end-of-life PV thin film modules consisting of sandblasting and flotation. Separation of the semiconductor material from the glass surface was possible, however, enrichment and yield of valuables in the flotation step were non-satisfying. Nevertheless, recovery of valuable metals from urban stock is a viable method for the extension of the availability of limited natural resources.

  18. Human–environment interactions in urban green spaces — A systematic review of contemporary issues and prospects for future research

    SciTech Connect (OSTI)

    Kabisch, Nadja; Qureshi, Salman; Haase, Dagmar

    2015-01-15

    Scientific papers on landscape planning underline the importance of maintaining and developing green spaces because of their multiple environmental and social benefits for city residents. However, a general understanding of contemporary human–environment interaction issues in urban green space is still incomplete and lacks orientation for urban planners. This review examines 219 publications to (1) provide an overview of the current state of research on the relationship between humans and urban green space, (2) group the different research approaches by identifying the main research areas, methods, and target groups, and (3) highlight important future prospects in urban green space research. - Highlights: • Reviewed literature on urban green pins down a dearth of comparative studies. • Case studies in Africa and Russia are marginalized – the Europe and US dominate. • Questionnaires are used as major tool followed by GIS and quantitative approaches. • Developing countries should contribute in building an urban green space agenda. • Interdisciplinary, adaptable and pluralistic approaches can satiate a knowledge gap.

  19. Dynamic analysis of the urban-based low-carbon policy using system dynamics: Focused on housing and green space

    SciTech Connect (OSTI)

    Hong, Taehoon; Kim, Jimin Jeong, Kwangbok; Koo, Choongwan

    2015-02-09

    To systematically manage the energy consumption of existing buildings, the government has to enforce greenhouse gas reduction policies. However, most of the policies are not properly executed because they do not consider various factors from the urban level perspective. Therefore, this study aimed to conduct a dynamic analysis of an urban-based low-carbon policy using system dynamics, with a specific focus on housing and green space. This study was conducted in the following steps: (i) establishing the variables of urban-based greenhouse gases (GHGs) emissions; (ii) creating a stock/flow diagram of urban-based GHGs emissions; (iii) conducting an information analysis using the system dynamics; and (iv) proposing the urban-based low-carbon policy. If a combined energy policy that uses the housing sector (30%) and the green space sector (30%) at the same time is implemented, 2020 CO{sub 2} emissions will be 7.23 million tons (i.e., 30.48% below 2020 business-as-usual), achieving the national carbon emissions reduction target (26.9%). The results of this study could contribute to managing and improving the fundamentals of the urban-based low-carbon policies to reduce greenhouse gas emissions.

  20. Household energy use in urban Venezuela: Implications from surveys in Maracaibo, Valencia, Merida, and Barcelona-Puerto La Cruz

    SciTech Connect (OSTI)

    Figueroa, M.J.; Sathaye, J.

    1993-08-01

    This report identifies the most important results of a comparative analysis of household commercial energy use in Venezuelan urban cities. The use of modern fuels is widespread among all cities. Cooking consumes the largest share of urban household energy use. The survey documents no use of biomass and a negligible use of kerosene for cooking. LPG, natural gas, and kerosene are the main fuels available. LPG is the fuel choice of low-income households in all cities except Maracaibo, where 40% of all households use natural gas. Electricity consumption in Venezuela`s urban households is remarkably high compared with the levels used in households in comparable Latin American countries and in households of industrialized nations which confront harsher climatic conditions and, therefore, use electricity for water and space heating. The penetration of appliances in Venezuela`s urban households is very high. The appliances available on the market are inefficient, and there are inefficient patterns of energy use among the population. Climate conditions and the urban built form all play important roles in determining the high level of energy consumption in Venezuelan urban households. It is important to acknowledge the opportunities for introducing energy efficiency and conservation in Venezuela`s residential sector, particularly given current economic and financial constraints, which may hamper the future provision of energy services.

  1. Defect reduction in epitaxial GaSb grown on nanopatterned GaAs substrates using full wafer block copolymer lithography

    SciTech Connect (OSTI)

    Jha, Smita; Liu, C.-C.; Nealey, P. F.; Kuech, T. F.; Kuan, T. S.; Babcock, S. E.; Park, J. H.; Mawst, L. J.

    2009-08-10

    Defect reduction in the large lattice mismatched system of GaSb on GaAs, {approx}7%, was accomplished using full wafer block copolymer (BCP) lithography. A self-assembled BCP mask layer was used to generate a hexagonal pattern of {approx}20 nm holes on {approx}40 nm centers in a 20 nm SiO{sub 2} layer. GaSb growth initially takes place selectively within these holes leading to a dense array of small, strain-relaxed epitaxial GaSb islands. The GaSb grown on the patterned SiO{sub 2} layer exhibits a reduction in the x-ray linewidth attributed to a decrease in the threading dislocation density when compared to blanket pseudomorphic film growth.

  2. Mesoporous Silica Films with Long-Range Order Prepared from Strongly Segregated Block Copolymer/Homopolymer Blend Templates

    SciTech Connect (OSTI)

    Tirumala, Vijay R.; Pai, Rajaram A.; Agarwal, Sumit; Testa, Jason J.; Bhatnagar, Gaurav; Romang, Alvin H.; Chandler, Curran; Gorman, Brian P.; Jones, Ronald L.; Lin, Eric K.; Watkins, James J.

    2008-06-30

    Well-ordered mesoporous silica films were prepared by infusion and selective condensation of Si alkoxides within preorganized block copolymer/homopolymer blend templates using supercritical CO{sub 2} as the delivery medium. The morphologies of the mesoporous silica films reflect significant improvements in the strength of segregation and long-range order of template blends of poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) triblock copolymers with selectively associating homopolymers such as poly(acrylic acid) or poly(4-hydroxystyrene) prior as compared to templates comprised of the neat copolymer. Control over film porosity, pore ordering, and morphology of the films is achieved through simple variations in the homopolymer concentration. The films were characterized using X-ray reflectivity, small-angle X-ray scattering, and transmission electron microscopy.

  3. Evaluation of the reliability of a conventional platform installed in South Pass Block 47 of the Mississippi River delta

    SciTech Connect (OSTI)

    Bea, R.G.

    1996-12-31

    In August 1995, the Energy Development Corporation (EDC) installed a conventional drilling and production platform in South Pass Block 47 (SP 47). Due to its proximity to the delta of the Mississippi River, this platform will be subject to the environmental forces developed by hurricanes and movements of the sea floor. This paper summarizes results from probability based study of the reliability characteristics of a conventional platform installed in SP 47. Bases for evaluation of the acceptability of the reliability of the platform are developed. This paper shows how reliability methods can be used to help improve the efficiency of offshore platforms. Application of traditional engineering approaches indicated the need for a mudslide resistant platform. Given that a mudslide resistant platform was required, then the gas reserves could not have been developed.

  4. DETECTIONS OF FAINT Ly{alpha} EMITTERS AT z = 5.7: GALAXY BUILDING BLOCKS AND ENGINES OF REIONIZATION

    SciTech Connect (OSTI)

    Dressler, Alan; McCarthy, Patrick; Martin, Crystal L.; Henry, Alaina; Sawicki, Marcin E-mail: sawicki@ap.smu.ca

    2011-10-20

    We report results of an unprecedentedly deep, blind search for Ly{alpha} emitters (LAEs) at z = 5.7 using the Inamori-Magellan Areal Camera and Spectrograph (IMACS), with the goal of identifying missing sources of reionization that could also be basic building blocks for today's L* galaxies. We describe how improvements in wide field imaging with the Baade telescope, upgrades to IMACS, and the accumulation of {approx}20 hr of integration per field in excellent seeing led to the detection of single-emission-line sources as faint as F {approx} 2 x 10{sup -18} erg s{sup -1} cm{sup -2}, a sensitivity five times deeper than our first search. A reasonable correction for foreground interlopers implies a steep rise of approximately an order of magnitude in source density for a factor of four drop in flux, from F = 10{sup -17.0} erg s{sup -1} cm{sup -2} to F = 10{sup -17.6} (2.5 x 10{sup -18}) erg s{sup -1} cm{sup -2}. At this flux the putative LAEs have reached a surface density of {approx}1 arcmin{sup -2}-a comoving volume density of 4 x 10{sup -3} Mpc{sup -3}, several times the density of L* galaxies today. Such a population of faint LAEs would account for a significant fraction of the critical flux density required to complete reionization at this epoch, and would be good candidates for building blocks of stellar mass {approx}10{sup 8}-10{sup 9} M{sub sun} for the young galaxies of this epoch.

  5. A critical review of environmental assessment tools for sustainable urban design

    SciTech Connect (OSTI)

    Ameen, Raed Fawzi Mohammed; Mourshed, Monjur; Li, Haijiang

    2015-11-15

    Cities are responsible for the depletion of natural resources and agricultural lands, and 70% of global CO{sub 2} emissions. There are significant risks to cities from the impacts of climate change in addition to existing vulnerabilities, primarily because of rapid urbanization. Urban design and development are generally considered as the instrument to shape the future of the city and they determine the pattern of a city's resource usage and resilience to change, from climate or otherwise. Cities are inherently dynamic and require the participation and engagement of their diverse stakeholders for the effective management of change, which enables wider stakeholder involvement and buy-in at various stages of the development process. Sustainability assessment of urban design and development is increasingly being seen as indispensable for informed decision-making. A sustainability assessment tool also acts as a driver for the uptake of sustainable pathways by recognizing excellence through their rating system and by creating a market demand for sustainable products and processes. This research reviews six widely used sustainability assessment tools for urban design and development: BREEAM Communities, LEED-ND, CASBEE-UD, SBTool{sup PT}–UP, Pearl Community Rating System (PCRS) and GSAS/QSAS, to identify, compare and contrast the aim, structure, assessment methodology, scoring, weighting and suitability for application in different geographical contexts. Strengths and weaknesses of each tool are critically discussed. The study highlights the disparity in local and international contexts for global sustainability assessment tools. Despite their similarities in aim on environmental aspects, differences exist in the relative importance and share of mandatory vs optional indicators in both environmental and social dimensions. PCRS and GSAS/QSAS are new incarnations, but have widely varying shares of mandatory indicators, at 45.4% and 11.36% respectively, compared to 30% in

  6. Urban Form Energy Use and Emissions in China: Preliminary Findings and Model Proof of Concept

    SciTech Connect (OSTI)

    Aden, Nathaniel; Qin, Yining; Fridley, David

    2010-12-15

    Urbanization is reshaping China's economy, society, and energy system. Between 1990 and 2008 China added more than 300 million new urban residents, bringing the total urbanization rate to 46%. The ongoing population shift is spurring energy demand for new construction, as well as additional residential use with the replacement of rural biomass by urban commercial energy services. This project developed a modeling tool to quantify the full energy consequences of a particular form of urban residential development in order to identify energy- and carbon-efficient modes of neighborhood-level development and help mitigate resource and environmental implications of swelling cities. LBNL developed an integrated modeling tool that combines process-based lifecycle assessment with agent-based building operational energy use, personal transport, and consumption modeling. The lifecycle assessment approach was used to quantify energy and carbon emissions embodied in building materials production, construction, maintenance, and demolition. To provide more comprehensive analysis, LBNL developed an agent-based model as described below. The model was applied to LuJing, a residential development in Jinan, Shandong Province, to provide a case study and model proof of concept. This study produced results data that are unique by virtue of their scale, scope and type. Whereas most existing literature focuses on building-, city-, or national-level analysis, this study covers multi-building neighborhood-scale development. Likewise, while most existing studies focus exclusively on building operational energy use, this study also includes embodied energy related to personal consumption and buildings. Within the boundaries of this analysis, food is the single largest category of the building energy footprint, accounting for 23% of the total. On a policy level, the LCA approach can be useful for quantifying the energy and environmental benefits of longer average building lifespans. In

  7. High Temperature Reactor (HTR) Deep Burn Core and Fuel Analysis: Design Selection for the Prismatic Block Reactor

    SciTech Connect (OSTI)

    Francesco Venneri; Chang-Keun Jo; Jae-Man Noh; Yonghee Kim; Claudio Filippone; Jonghwa Chang; Chris Hamilton; Young-Min Kim; Ji-Su Jun; Moon-Sung Cho; Hong-Sik Lim; MIchael A. Pope; Abderrafi M. Ougouag; Vincent Descotes; Brian Boer

    2010-09-01

    The Deep Burn (DB) Project is a U.S. Department of Energy sponsored feasibility study of Transuranic Management using high burnup fuel in the high temperature helium cooled reactor (HTR). The DB Project consists of seven tasks: project management, core and fuel analysis, spent fuel management, fuel cycle integration, TRU fuel modeling, TRU fuel qualification, and HTR fuel recycle. In the Phase II of the Project, we conducted nuclear analysis of TRU destruction/utilization in the HTR prismatic block design (Task 2.1), deep burn fuel/TRISO microanalysis (Task 2.3), and synergy with fast reactors (Task 4.2). The Task 2.1 covers the core physics design, thermo-hydraulic CFD analysis, and the thermofluid and safety analysis (low pressure conduction cooling, LPCC) of the HTR prismatic block design. The Task 2.3 covers the analysis of the structural behavior of TRISO fuel containing TRU at very high burnup level, i.e. exceeding 50% of FIMA. The Task 4.2 includes the self-cleaning HTR based on recycle of HTR-generated TRU in the same HTR. Chapter IV contains the design and analysis results of the 600MWth DB-HTR core physics with the cycle length, the average discharged burnup, heavy metal and plutonium consumptions, radial and axial power distributions, temperature reactivity coefficients. Also, it contains the analysis results of the 450MWth DB-HTR core physics and the analysis of the decay heat of a TRU loaded DB-HTR core. The evaluation of the hot spot fuel temperature of the fuel block in the DB-HTR (Deep-Burn High Temperature Reactor) core under full operating power conditions are described in Chapter V. The investigated designs are the 600MWth and 460MWth DB-HTRs. In Chapter VI, the thermo-fluid and safety of the 600MWth DB-HTRs has been analyzed to investigate a thermal-fluid design performance at the steady state and a passive safety performance during an LPCC event. Chapter VII describes the analysis results of the TRISO fuel microanalysis of the 600MWth and 450

  8. Dispersion of Radionuclides and Exposure Assessment in Urban Environments: A Joint CEA and LLNL Report

    SciTech Connect (OSTI)

    Glascoe, Lee; Gowardhan, Akshay; Lennox, Kristin; Simpson, Matthew; Yu, Kristen; Armand, Patrick; Duchenne, Christophe; Mariotte, Frederic; Pectorin, Xavier

    2014-12-19

    In the interest of promoting the international exchange of technical expertise, the US Department of Energy’s Office of Emergency Operations (NA-40) and the French Commissariat à l'Energie Atomique et aux énergies alternatives (CEA) requested that the National Atmospheric Release Advisory Center (NARAC) of Lawrence Livermore National Laboratory (LLNL) in Livermore, California host a joint table top exercise with experts in emergency management and atmospheric transport modeling. In this table top exercise, LLNL and CEA compared each other’s flow and dispersion models. The goal of the comparison is to facilitate the exchange of knowledge, capabilities, and practices, and to demonstrate the utility of modeling dispersal at different levels of computational fidelity. Two modeling approaches were examined, a regional scale modeling approach, appropriate for simple terrain and/or very large releases, and an urban scale modeling approach, appropriate for small releases in a city environment. This report is a summary of LLNL and CEA modeling efforts from this exercise. Two different types of LLNL and CEA models were employed in the analysis: urban-scale models (Aeolus CFD at LLNL/NARAC and Parallel- Micro-SWIFT-SPRAY, PMSS, at CEA) for analysis of a 5,000 Ci radiological release and Lagrangian Particle Dispersion Models (LODI at LLNL/NARAC and PSPRAY at CEA) for analysis of a much larger (500,000 Ci) regional radiological release. Two densely-populated urban locations were chosen: Chicago with its high-rise skyline and gridded street network and Paris with its more consistent, lower building height and complex unaligned street network. Each location was considered under early summer daytime and nighttime conditions. Different levels of fidelity were chosen for each scale: (1) lower fidelity mass-consistent diagnostic, intermediate fidelity Navier-Stokes RANS models, and higher fidelity Navier-Stokes LES for urban-scale analysis, and (2) lower-fidelity single

  9. TEMPERATURE MEASUREMENTS COLLECTED FROM AN INSTRUMENTED VAN IN SALT LAKE CITY, UTAH AS PART OF URBAN 2000

    SciTech Connect (OSTI)

    M.J. BROWN; E.R. PARDYJAK

    2001-08-01

    Measurements of temperature and position were collected during the night from an instrumented van on routes through Salt Lake City and the rural outskirts. The measurements were taken as part of the Department of Energy Chemical and Biological National Security Program URBAN 2 Field Experiment conducted in October 2000 (Shinn et al., 2000 and Allwine et al., 2001a). The instrumented van was driven over three primary routes, two including downtown, residential, and ''rural'' areas and a third that went by a line of permanently fixed temperature probes (Allwine et al., 2001b) for cross-checking purposes. Each route took from 45 to 60 minutes to complete. Based on four nights of data, initial analyses indicate that there was a temperature difference of 2-5 C between the urban core and nearby ''rural'' areas. Analyses also suggest that there were significant fine scale temperature differences over distances of tens of meters within the city and in the nearby rural areas. The temperature measurements that were collected are intended to supplement the meteorological measurements taken during the URBAN2000 Field Experiment, to assess the importance of the urban heat island phenomenon in Salt Lake City, and to test the urban canopy parameterizations that have been developed for regional scale meteorological codes as part of the DOE CBNP program.

  10. Chemical characteristics of urban stormwater sediments and implications for environmental management, Maricopa County, Arizona

    SciTech Connect (OSTI)

    Parker, J.T.C.; Fossum, K.D.; Ingersoll, T.L.

    2000-07-01

    Investigations of the chemical characteristics of urban stormwater sediments in the rapidly growing Phoenix metropolitan area of Maricopa County, Arizona, showed that the inorganic component of these sediments generally reflects geologic background values. Some concentrations of metals were above background values, especially cadmium, copper, lead, and zinc, indicating an anthropogenic contribution of these elements to the sediment chemistry. Concentrations, however, were not at levels that would require soil remediation according to guidelines of the US Environmental Protection Agency. Arsenic concentrations generally were above recommended values for remediation at a few sites, but these concentrations seem to reflect geologic rather than anthropogenic factors. Several organochlorine compounds no longer in use were ubiquitous in the Phoenix area, although concentrations generally were low. Chlordane, DDT and its decay products DDE and DDD, dieldrin, toxaphene, and PCBs were found at almost all sites sampled, although some of the pesticides in which these compounds are found have been banned for almost 30 years. A few sites showed exceptionally high concentrations of organochlorine compounds. On the basis of published guidelines, urban stormwater sediments do not appear to constitute a major regional environmental problem with respect to the chemical characteristics investigated here. At individual sites, high concentrations of organic compounds--chlordane, dieldrin, PCBs, and toxaphene--may require some attention. The possible environmental hazard presented by low-level organochlorine contamination is not addresses in this paper; however, high levels of toxicity in urban sediments are difficult to explain. Sediment toxicity varied significantly with time, which indicates that these tests should be evaluated carefully before they are used for management decisions.

  11. Legacy Site Decontamination Experience as Applied to the Urban Radiological Dispersal Device

    SciTech Connect (OSTI)

    Drake, J.L.; MacKinney, J.A.

    2007-07-01

    Pursuant to the National Response Plan, Nuclear/Radiological Incident Annex [1], the Environmental Protection Agency (EPA) is assigned lead agency responsibility for decontamination and clean-up efforts following a domestic terrorist event involving a radiological dispersal device (RDD). An RDD incident in a modern city environment poses many of the same issues and problems traditionally faced at 'legacy' clean up projects being performed across our country. However there are also many aspects associated with an urban RDD clean-up that have never been faced in legacy site remediation. For example, the demolition and destructive technologies widely used in legacy remediation would be unacceptable in the case of historically or architecturally significant properties or those with prohibitively high replacement cost; contaminated properties will likely belong to numerous small private entities whose business interests are at stake; reducing the time required to decontaminate and return a city to normal use cannot be overemphasized due to its tremendous economic and political impact. The mission of the EPA's National Homeland Security Research Center (NHSRC) includes developing the best technology and tools needed for field personnel to achieve their goals should that event occur. To that end, NHSRC has been exploring how the vast experience within the legacy site remediation community could be tapped to help meet this need, and to identify gaps in decontamination technology. This paper articulates much of what has been learned over the past year as a result of efforts to identify these technology and procedural needs to address the urban RDD. This includes comparing and contrasting remediation techniques and methodologies currently used in nuclear facility and site cleanup with those that would be needed following an urban RDD event. Finally, this presentation includes an appeal to the radiological decontamination community to come forward with ideas and technologies

  12. Characterization of coastal urban watershed bacterial communities leads to alternative community-based indicators

    SciTech Connect (OSTI)

    Wu, C.H.; Sercu, B.; Van De Werhorst, L.C.; Wong, J.; DeSantis, T.Z.; Brodie, E.L.; Hazen, T.C.; Holden, P.A.; Andersen, G.L.

    2010-03-01

    Microbial communities in aquatic environments are spatially and temporally dynamic due to environmental fluctuations and varied external input sources. A large percentage of the urban watersheds in the United States are affected by fecal pollution, including human pathogens, thus warranting comprehensive monitoring. Using a high-density microarray (PhyloChip), we examined water column bacterial community DNA extracted from two connecting urban watersheds, elucidating variable and stable bacterial subpopulations over a 3-day period and community composition profiles that were distinct to fecal and non-fecal sources. Two approaches were used for indication of fecal influence. The first approach utilized similarity of 503 operational taxonomic units (OTUs) common to all fecal samples analyzed in this study with the watershed samples as an index of fecal pollution. A majority of the 503 OTUs were found in the phyla Firmicutes, Proteobacteria, Bacteroidetes, and Actinobacteria. The second approach incorporated relative richness of 4 bacterial classes (Bacilli, Bacteroidetes, Clostridia and a-proteobacteria) found to have the highest variance in fecal and non-fecal samples. The ratio of these 4 classes (BBC:A) from the watershed samples demonstrated a trend where bacterial communities from gut and sewage sources had higher ratios than from sources not impacted by fecal material. This trend was also observed in the 124 bacterial communities from previously published and unpublished sequencing or PhyloChip- analyzed studies. This study provided a detailed characterization of bacterial community variability during dry weather across a 3-day period in two urban watersheds. The comparative analysis of watershed community composition resulted in alternative community-based indicators that could be useful for assessing ecosystem health.

  13. FDATMOS16 non-linear partitioning and organic volatility distributions in urban aerosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Madronich, Sasha; Kleinman, Larry; Conley, Andrew; Lee-Taylor, Julie; Hodzic, A.; Aumont, Bernard

    2015-12-17

    Gas-to-particle partitioning of organic aerosols (OA) is represented in most models by Raoult’s law, and depends on the existing mass of particles into which organic gases can dissolve. This raises the possibility of non-linear response of particle-phase OA to the emissions of precursor volatile organic compounds (VOCs) that contribute to this partitioning mass. Implications for air quality management are evident: A strong non-linear dependence would suggest that reductions in VOC emission would have a more-than-proportionate benefit in lowering ambient OA concentrations. Chamber measurements on simple VOC mixtures generally confirm the non-linear scaling between OA and VOCs, usually stated as amore » mass-dependence of the measured OA yields. However, for realistic ambient conditions including urban settings, no single component dominates the composition of the organic particles, and deviations from linearity are presumed to be small. Here we re-examine the linearity question using volatility spectra from several sources: (1) chamber studies of selected aerosols, (2) volatility inferred for aerosols sampled in two megacities, Mexico City and Paris, and (3) an explicit chemistry model (GECKO-A). These few available volatility distributions suggest that urban OA may be only slightly super-linear, with most values of the sensitivity exponent in the range 1.1-1.3, also substantially lower than seen in chambers for some specific aerosols. Furthermore, the rather low values suggest that OA concentrations in megacities are not an inevitable convergence of non-linear effects, but can be addressed (much like in smaller urban areas) by proportionate reductions in emissions.« less

  14. FDATMOS16 non-linear partitioning and organic volatility distributions in urban aerosols

    SciTech Connect (OSTI)

    Madronich, Sasha; Kleinman, Larry; Conley, Andrew; Lee-Taylor, Julie; Hodzic, A.; Aumont, Bernard

    2015-12-17

    Gas-to-particle partitioning of organic aerosols (OA) is represented in most models by Raoult’s law, and depends on the existing mass of particles into which organic gases can dissolve. This raises the possibility of non-linear response of particle-phase OA to the emissions of precursor volatile organic compounds (VOCs) that contribute to this partitioning mass. Implications for air quality management are evident: A strong non-linear dependence would suggest that reductions in VOC emission would have a more-than-proportionate benefit in lowering ambient OA concentrations. Chamber measurements on simple VOC mixtures generally confirm the non-linear scaling between OA and VOCs, usually stated as a mass-dependence of the measured OA yields. However, for realistic ambient conditions including urban settings, no single component dominates the composition of the organic particles, and deviations from linearity are presumed to be small. Here we re-examine the linearity question using volatility spectra from several sources: (1) chamber studies of selected aerosols, (2) volatility inferred for aerosols sampled in two megacities, Mexico City and Paris, and (3) an explicit chemistry model (GECKO-A). These few available volatility distributions suggest that urban OA may be only slightly super-linear, with most values of the sensitivity exponent in the range 1.1-1.3, also substantially lower than seen in chambers for some specific aerosols. Furthermore, the rather low values suggest that OA concentrations in megacities are not an inevitable convergence of non-linear effects, but can be addressed (much like in smaller urban areas) by proportionate reductions in emissions.

  15. Thickness dependent hierarchical meso/nano scale morphologies of a metal-containing block copolymer thin film induced by hybrid annealing and their pattern transfer abilities.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B.; Center for Nanoscale Materials

    2009-01-01

    In this paper we describe dewetting phenomena in organic (polystyrene, PS)/inorganic (polyferrocenyldimethylsilane, PFS) block copolymer thin films. Mesoscale dendritic structures are induced when the spin-cast thin film of this polymer is subjected to so-called hybrid annealing, which involves both thermal and solvent annealing. We show that the development and arrangement of these mesoscale dendritic structures depends on the initial film thickness in addition to the annealing time. Importantly, there are two criteria that must be fulfilled to achieve these mesoscale morphologies: (i) the film has to be subjected to hybrid annealing, i.e. either only thermal or only solvent annealing does not produce any notable mesostructures and (ii) both PS and PFS blocks must be present during the thermal and solvent annealing procedures; if one of the blocks, for instance PS, is removed before annealing then there is no mesostructure. Various possible mechanisms for the formation of these structures are discussed and results indicate that the PFS block dominates the structure formation. We also observe a ring- or worm-like nanostructure which develops only when the film is subjected to hybrid annealing at a particular film thickness. Apart from these results, here we demonstrate that mesoscale structures can be successfully transferred onto underlying substrates.

  16. DAVIS-BACON ACT WAGE RATES FOR ARRA-FUNDED ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT (EECBG) PROGRAM PROJECTS INCLUDING RESIDENTIAL WEATHERIZATION WORK

    Broader source: Energy.gov [DOE]

    Guidance on using appropriate prevailing wage rates for all Davis-Bacon Act (DBA) covered-work, including weatherization work, performed under the Energy Efficiency and Conservation Block Grants (EECBG) Program using American Recovery and Reinvestment Act of 2009 (ARRA) funds to ensure compliance with DBA requirements.

  17. Guidance on the Required Period for Grantees to Obligate Funds and the Procedures for Reporting of Obligated Funds for the Energy Efficiency Conservation Block Grant (EECBG) Program

    Broader source: Energy.gov [DOE]

    This document provides guidance and clarifies the required period for obligation of funds as established in the Energy Efficiency Conservation Block Grant (EECBG) Program Funding Opportunity Announcements (FOAs) Number DE-FOA-0000013 and DE-FOA-0000148, and to clarify the procedures for the reporting of funds obligated by the grantees.

  18. State Energy Program Notice (10-004A), Energy Efficiency Conservation Block Grant Program Notice (10-005A), and Appliance Rebate Program Notice (10-001A)

    Broader source: Energy.gov [DOE]

    Guidance on Davis Bacon Act (DBA) requirements for American Reinvestment and Recovery Act of 2009 (ARRA)-funded rebate, grant and financing programs for individual homeowners conducted under the State Energy Program (SEP), Energy Efficiency and Conservation Block Grant (EECBG) program, and the appliance rebate program. Revised April 7, 2010.

  19. Urban and rural demonstration of a wind-powered water pump. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    One of the two prototype windmills is still being modified, and the final results are not yet in. Our original intent was to complete a four-year design effort so that the prototype Sailwing could be built by a do-it-yourselfer completely from off-the-shelf components. Once the design modifications were completed, we proposed to construct two mills - one at an urban community garden in Boston, the other at the Cape Code Bioshelter in Hatchville, Massachusetts. Plans for the machine would then be published and made available in several forms.

  20. Coping with urban water shortages during drought: the effects of legal and administrative factors. Final report

    SciTech Connect (OSTI)

    Dziegielewski, B.; Ferrell-Dillard, R.; Beck, R.E.

    1992-04-01

    The study describes the results of a survey of 547 local water supply systems serving some 31 million residents of urban areas in the states of Alabama, California, Florida, Oklahoma, Tennessee and Wyoming. While examining the legal and administrative aspects of drought management, the survey also included the assessment of the current status of drought preparedness and long-term drought protection among the responding water supply systems. The rate of legal or administrative problems encountered during drought response was surprisingly low, affecting only twenty percent of all implementing systems. The low incidence of difficulties counters a widespread assumption that the legal environment frequently restrains or constricts drought response efforts.

  1. Maintenance of solar systems--Housing and urban development demonstration program

    SciTech Connect (OSTI)

    Freeborne, W.E.

    1983-06-01

    The Department of Housing and Urban Development (HUD) residential solar heating and cooling demonstration program provided funding support for over 600 solar projects. These projects provide the largest single data base of solar heating and cooling experience now available. These data suggest that maintenance and system operation have been mixed even though system configurations are similar throughout the program. HUD has been involved in the upgrading of one-third of the 600 solar projects and now can report that projects can be maintained with a more uniform level of effort.

  2. The benzene metabolite trans,trans-muconaldehyde blocks gap junction intercellular communication by cross-linking connexin43

    SciTech Connect (OSTI)

    Rivedal, Edgar Leithe, Edward

    2008-11-01

    Benzene is used at large volumes in many different human activities. Hematotoxicity and cancer-causation as a result of benzene exposure was recognized many years ago, but the mechanisms involved remain unclear. Aberrant regulation of gap junction intercellular communication (GJIC) has been linked to both cancer induction and interference with normal hematopoietic development. We have previously suggested that inhibition of GJIC may play a role in benzene toxicity since benzene metabolites were found to block GJIC, the ring-opened trans,trans-muconaldehyde (MUC) being the most potent metabolite. In the present work we have studied the molecular mechanisms underlying the MUC-induced inhibition of gap junctional communication. We show that MUC induces cross-linking of the gap junction protein connexin43 and that this is likely to be responsible for the induced inhibition of GJIC, as well as the loss of connexin43 observed in Western blots. We also show that glutaraldehyde possesses similar effects as MUC, and we compare the effects to that of formaldehyde. The fact that glutaraldehyde and formaldehyde have been associated with induction of leukemia as well as disturbance of hematopoiesis, strengthens the possible link between the effect of MUC on gap junctions, and the toxic effects of benzene.

  3. Deprotonated Water Dimers: The Building Blocks of Segmented Water Chains on Rutile RuO2(110)

    SciTech Connect (OSTI)

    Mu, Rentao; Cantu Cantu, David; Glezakou, Vassiliki Alexandra; Lyubinetsky, Igor; Rousseau, Roger J.; Dohnalek, Zdenek

    2015-10-15

    Despite the importance of RuO2 in photocatalytic water splitting and catalysis in general, the interactions of water with even its most stable (110) surface are not well-understood. In this study we employ a combination of high-resolution scanning tunneling microscopy imaging with density functional theory based ab initio molecular dynamics, and we follow the formation and binding of linear water clusters on coordinatively unsaturated ruthenium rows. We find that clusters of all sizes (dimers, trimers, tetramers, extended chains) are stabilized by donating one proton per every two water molecules to the surface bridge bonded oxygen sites, in contrast with water monomers that do not show a significant propensity for dissociation. The clusters with odd number of water molecules are less stable than the clusters with even number, and are generally not observed under thermal equilibrium. For all clusters with even numbers, the dissociated dimers represent the fundamental building blocks with strong intra-dimer hydrogen bonds and only very weak inter-dimer interactions resulting in segmented water chains.

  4. Implementation of Generalized Coarse-Mesh Rebalance of NEWTRNX for Acceleration of Parallel Block-Jacobi Transport

    SciTech Connect (OSTI)

    Clarno, Kevin T

    2007-01-01

    The NEWTRNX transport module solves the multigroup, discrete-ordinates source-driven or k-eigenvalue transport equation in parallel on a 3-D unstructured tetrahedral mesh using the extended step characteristics (ESC), also known as the slice-balance approach (SBA), spatial discretization. The spatial domains are decomposed using METIS. NEWTRNX is under development for nuclear reactor analysis on computer hardware ranging from clusters to massively parallel machines, like the Cray XT4. Transport methods that rely on full sweeps across the spatial domain have been shown to display poor scaling for thousands of processors. The Parallel Block-Jacobi (PBJ) algorithm allows each spatial partition to sweep over all discrete-ordinate directions and energies independently of all other domains, potentially allowing for much better scaling than possible with full sweeps. The PBJ algorithm has been implemented in NEWTRNX using a Gauss-Seidel iteration in energy and an asynchronous communication by an energy group, such that each partition utilizes the latest boundary solution available for each group before solving the withingroup scattering in a given group. For each energy group, the within-group scattering converges with a generalized minimum residual (GMRES) solver, preconditioned with beta transport synthetic acceleration ({beta}-TSA).

  5. Characterization study of lower Lagunillas member, Block IV, Lake Maracaibo. Application of horizontal well to revive a mature oil field

    SciTech Connect (OSTI)

    Coll, C.; Gamero, H.; Jimenez, Z. )

    1996-01-01

    The Lower Lagunillas is one of the largest reservoirs in Venezuela located in Block IV in the Lake Maracaibo Basin in Zulia State in Western Venezuela. The estimated remaining reserves are 270 MMSTB. A multidisciplinary, integrated reservoir characterization study was performed to evaluate reservoir heterogeneity and fluid flow dynamics in fine scale. The majority of the remaining reserves are in the form of oil bypassed in the low resistivity pay zones. These zones were identified by the now core-log calibration performed in this area. Significant pressure decline from the initial 4200 psi to 1400 psi has prompted us to explore new development strategy of selective drilling of horizontal wells. A key step in the study was acquisition and integration of new geoscience, well log and pressure data. The available geology, geophysics, sedimentology and petrophysics were integrated and loaded on to a 3-D visualization package for correlating and validating the various lithofacies with petrophysics and sedimentology. The resulting reservoir model was exported to a flow simulator for developing a dynamic simulation model. A target layer was selected based on the results of the characterization study and risk assessment strategy. A pilot well was drilled in the reservoir to acquire new data and information. These information were processed to evaluate the borehole stability, petrophysical properties, location of the fluid phases, pressure behavior and target zone. The processed data were utilized to confirm the location and to develop the completion diagram of the horizontal well.

  6. What are hot and what are not in an urban landscape: quantifying and explaining the land surface temperature pattern in Beijing, China

    SciTech Connect (OSTI)

    Kuang, Wenhui; Liu, Yue; Dou, Yinyin; Chi, Wenfeng; Chen, Guangsheng; Gao, Chengfeng; Yang, Tianrong; Liu, Jiyuan; Zhang, Renhua

    2014-12-06

    Understanding how landscape components affect the urban heat islands is crucial for urban ecological planning and sustainable development. The purpose of this research was to quantify the spatial pattern of land surface temperatures (LSTs) and associated heat fluxes in relation to land-cover types in Beijing, China, using portable infrared thermometers, thermal infrared imagers, and the moderate resolution imaging spectroradiometer. The spatial differences and the relationships between LSTs and the hierarchical landscape structure were analyzed with in situ observations of surface radiation and heat fluxes. Large LST differences were found among various land-use/land-cover types, urban structures, and building materials. Within the urban area, the mean LST of urban impervious surfaces was about 6–12°C higher than that of the urban green space. LSTs of built-up areas were on average 3–6°C higher than LSTs of rural areas. The observations for surface radiation and heat fluxes indicated that the differences were caused by different fractions of sensible heat or latent heat flux in net radiation. LSTs decreased with increasing elevation and normalized difference vegetation index. Variations in building materials and urban structure significantly influenced the spatial pattern of LSTs in urban areas. By contrast, elevation and vegetation cover are the major determinants of the LST pattern in rural areas. In summary, to alleviate urban heat island intensity, urban planners and policy makers should pay special attention to the selection of appropriate building materials, the reasonable arrangement of urban structures, and the rational design of landscape components.

  7. What are hot and what are not in an urban landscape: quantifying and explaining the land surface temperature pattern in Beijing, China

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuang, Wenhui; Liu, Yue; Dou, Yinyin; Chi, Wenfeng; Chen, Guangsheng; Gao, Chengfeng; Yang, Tianrong; Liu, Jiyuan; Zhang, Renhua

    2014-12-06

    Understanding how landscape components affect the urban heat islands is crucial for urban ecological planning and sustainable development. The purpose of this research was to quantify the spatial pattern of land surface temperatures (LSTs) and associated heat fluxes in relation to land-cover types in Beijing, China, using portable infrared thermometers, thermal infrared imagers, and the moderate resolution imaging spectroradiometer. The spatial differences and the relationships between LSTs and the hierarchical landscape structure were analyzed with in situ observations of surface radiation and heat fluxes. Large LST differences were found among various land-use/land-cover types, urban structures, and building materials. Within themore » urban area, the mean LST of urban impervious surfaces was about 6–12°C higher than that of the urban green space. LSTs of built-up areas were on average 3–6°C higher than LSTs of rural areas. The observations for surface radiation and heat fluxes indicated that the differences were caused by different fractions of sensible heat or latent heat flux in net radiation. LSTs decreased with increasing elevation and normalized difference vegetation index. Variations in building materials and urban structure significantly influenced the spatial pattern of LSTs in urban areas. By contrast, elevation and vegetation cover are the major determinants of the LST pattern in rural areas. In summary, to alleviate urban heat island intensity, urban planners and policy makers should pay special attention to the selection of appropriate building materials, the reasonable arrangement of urban structures, and the rational design of landscape components.« less

  8. Richland Analytical Building Blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 $ in Thousands Draft Pre-Decisional PBS ABB Title FY 2015 FY 2015 FY 2015 Description (Range $000) Cumulative Range RL-0030 Groundwater Monitoring (GWM), integration & Assessment, and Operations & Maintenance 100,000 - 120,000 100,000 - 120,000 Accomplishes continued integration of Site-wide groundwater and vadose zone cleanup activities, groundwater contamination monitoring, as well as operations, maintenance, and necessary modifications of existing remediation systems. RL-0041 River

  9. Richland Analytical Building Blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Draft Pre-Decisional ($ in 000's) PBS Work Description Title FY 2014 Description FY 2014 ($000) FY 2014 Cumulative ($000) RL-0011 PFP Surveillance and Maintenance (S&M) and Min Safe Provide minimum safe and essential services for industrial, radiological and nuclear Plutonium Finishing Plant (PFP) facilities/structures and systems. PFP surveillance includes the monitoring of residual radioactive and chemical contamination to ensure safe and compliant condition. Activities include

  10. Block coordination copolymers

    DOE Patents [OSTI]

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2014-11-11

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  11. Block coordination copolymers

    DOE Patents [OSTI]

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2012-11-13

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  12. Block coordination copolymers

    DOE Patents [OSTI]

    Koh, Kyoung Moo; Wong-Foy, Antek G.; Matzger, Adam J.; Benin, Annabelle I.; Willis, Richard R.

    2012-12-04

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  13. Anasazi Block Eigensolvers Package

    Energy Science and Technology Software Center (OSTI)

    2004-03-01

    ANASAZI is an extensible and interoperable framework for large-scale eigenvalue algorithms. The motivation for this framework is to provide a generic interface to a collection of algorithms for solving large-scale eigenvalue problems. ANASAZI is interoperable because both the matrix and vectors (defining the eigenspace) are considered to be opaque objects---only knowledge of the matrix and vectors via elementary operations is necessary. An implementation of Anasazi is accomplished via the use of interfaces. One of themore » goals of ANASAZI is to allow the user the flexibility to specify the data representation for the matrix and vectors and so leverage any existing software investment. The algorithms that will be included in package are Krylov-based and preconditioned eigensolvers.« less

  14. Richland Analytical Building Blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    appropriate and compliant Safeguards and Security programs for the Hanford site. ... operations necessary to support safe and compliant interim storage of Spent Nuclear Fuel (SNF). ...

  15. Power Electronics Block Set

    Energy Science and Technology Software Center (OSTI)

    2008-12-31

    The software consists of code that will allow rapid prototyping of advanced power electronics for use in renewable energy systems.

  16. The potential for reducing urban air temperatures and energy consumption through vegetative cooling

    SciTech Connect (OSTI)

    Kurn, D.M.; Bretz, S.E.; Huang, B.; Akbari, H.

    1994-05-01

    A network of 23 weather stations was used to detect existing oases in Southern California. Four stations, separated from one another by 15--25 miles (24--40 km), were closely examined. Data were strongly affected by the distance of the stations from the Pacific Ocean. This and other city-scale effects made the network inadequate for detection of urban oases. We also conducted traverse measurements of temperature and humidity in the Whittier Narrows Recreation Area in Los Angeles County on September 8--10, 1993. Near-surface air temperatures over vegetated areas were 1--2{degrees}C lower than background air temperatures. We estimate that vegetation may lower urban temperatures by 1{degrees}C, while the establishment of vegetative canopies may lower local temperatures by an additional 2{degrees}C. An increase in vegetation in residential neighborhoods may reduce peak loads in the Los Angeles area by 0.3 GW, and reduce energy consumption by 0.2 BkWh/year, saving $20 million annually. Large additional savings would result from regional cooling.

  17. Conceptual framework for describing selected urban and community impacts of federal energy policies

    SciTech Connect (OSTI)

    Morris, F.A,; Marcus, A.A.; Keller, D.

    1980-06-01

    A conceptual framework is presented for describing selected urban and community impacts of Federal energy policies. The framework depends on a simple causal model. The outputs of the model are impacts, changes in the state of the world of particular interest to policymakers. At any given time, a set of determinants account for the state of the world with respect to an impact category. Application of the model to a particular impact category requires: establishing a definition and measure for the impact category and identifying the determinants of these impacts. Analysis of the impact of a particular policy requires the following: identifying the policy and its effects (as estimated by others), isolating any effects that themselves constitute an urban and community impact, identifying any effects that change the value of determinants, and describing the impact with reference to the new values of determinants. This report provides a framework for these steps. Three impacts addressed are: neighborhood stability, housing availability, and quality and availability of public services. In each chapter, a definition and measure for the impact are specified; its principal determinants are identified; how the causal model can be used to estimate impacts by applying it to three illustrative Federal policies (domestic oil price decontrol, building energy performance standards, and increased Federal aid for mass transit) is demonstrated. (MCW)

  18. Pollutant transfer through air and water pathways in an urban environment

    SciTech Connect (OSTI)

    Brown, M.; Burian, S.; McPherson, T.; Streit, G.; Costigan, K.; Greene, B.

    1998-12-31

    The authors are attempting to simulate the transport and fate of pollutants through air and water pathways in an urban environment. This cross-disciplinary study involves linking together models of mesoscale meteorology, air pollution chemistry and deposition, urban runoff and stormwater transport, water quality, and wetland chemistry and biology. The authors are focusing on the transport and fate of nitrogen species because (1) they track through both air and water pathways, (2) the physics, chemistry, and biology of the complete cycle is not well understood, and (3) they have important health, local ecosystem, and global climate implications. The authors will apply their linked modeling system to the Los Angeles basin, following the fate of nitrates from their beginning as nitrate-precursors produced by auto emissions and industrial processes, tracking their dispersion and chemistry as they are transported by regional winds and eventually wet or dry deposit on the ground, tracing their path as they are entrained into surface water runoff during rain events and carried into the stormwater system, and then evaluating their impact on receiving water bodies such as wetlands where biologically-mediated chemical reactions take place. In this paper, the authors wish to give an overview of the project and at the conference show preliminary results.

  19. Freshwater wetlands, urban stormwater, and nonpoint pollution control: A literature review and annotated bibliography (revised)

    SciTech Connect (OSTI)

    Stockdale, E.C.

    1991-02-01

    The literature review and annotated bibliography contained in the document were first printed as two separate documents in 1986 at the beginning of a long-term research program titled the Puget Sound Wetlands and Stormwater Management Research Program. The review was conducted to determine the extent of information available on the long-term ecological impacts of stormwater on wetlands and, conversely, the ability of wetlands to improve the water quality of urban stormwater. The two reports have now been combined, and updated with the most recent literature. The revised report also briefly discusses the status of the Wetlands Research Program currently underway. The subject of the report is complex and diverse. For that reason the annotated bibliography in Part II contains references from the entire spectrum of wetland literature, including: urban runoff control technology, cumulative impacts, stormwater and wastewater treatment, functions and values, wetland creation, best management practices, and general wetland ecology. Most of the entrees contain abstracts. Where possible, the original author abstract or introduction was included.

  20. Use of SPMDs to determine average water concentration of polycyclic aromatic hydrocarbons in urban stormwater runoff

    SciTech Connect (OSTI)

    DeVita, W.; Crunkilton, R.

    1995-12-31

    Semipermeable polymeric membrane devices (SPMDS) were deployed for 30 day periods to monitor polycyclic aromatic hydrocarbons (PAHs) in an urban stream which receives much of its flow from urban runoff. SPMDs are capable of effectively sampling several liters of water per day for some PAHs. Unlike conventional methods, SPMDs sample only those non-polar organic contaminants which are truly dissolved and available for bioconcentration. Also, SPMDs may concentrate contaminants from episodic events such as stormwater discharge. The State of Wisconsin has established surface water quality criteria based upon human lifetime cancer risk of 23 ppt for benzo(a)pyrene and 23 ppt as the sum of nine other potentially carcinogenic PAHs. Bulk water samples analyzed by conventional methodology were routinely well above this criteria, but contained particulate bound PAHs as well as PAHs bound by dissolved organic carbon (DOC) which are not available for bioconcentration. Average water concentrations of dissolved PAHs determined using SPMDs were also above this criteria. Variables used for determining water concentration included sampling rate at the exposure temperature, length of exposure and estimation of biofouling of SPMD surface.