National Library of Energy BETA

Sample records for upland surface soil

  1. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Soil Surface Soil We compare local soil samples with samples collected from northern New Mexico locations that are beyond the range of potential influence from normal Laboratory operations. April 12, 2012 Farm soil sampling Two LANL environmental field team members take soil samples from a farm. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Measurements are compared to samples from the regional sites and

  2. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    environmental field team members take soil samples from a farm. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505)...

  3. EVALUATION OF ENHANCED VOC REMOVAL WITH SOIL FRACTURING IN THE SRS UPLAND UNIT

    SciTech Connect (OSTI)

    Riha, B

    2005-10-31

    The Environmental Restoration Technology Section (ERTS) of the Savannah River National Laboratory (SRNL) conducted pilot scale testing to evaluate the effectiveness of using hydraulic fracturing as a means to improve soil vapor extraction (SVE) system performance. Laboratory and field research has shown that significant amounts of solvents can be entrapped in low permeability zones by capillary forces and removal by SVE can be severely limited due to low flow rates, mass transfer resistance of the hydrophobic compounds by trapped interparticle water, and diffusion resistance. Introducing sand-filled fractures into these tight zones improves the performance of SVE by (1) increasing the overall permeability of the formation and thereby increasing SVE flow rates, (2) shortening diffusion pathways, and (3) increasing air permeability by improving pore water removal. The synergistic effect of the fracture well completion methods, fracture and flow geometry, and pore water removal appears to increase the rate of solvent mass removal over that of increasing flow rate alone. A field test was conducted where a conventional well in the SRS Upland Unit was tested before and after hydraulic fracturing. ERTS teamed with Clemson University through the South Carolina University and Education Foundation (SCUREF) program utilizing their expertise in fracturing and fracture modeling. The goals of the fracturing pilot testing were to evaluate the following: (1) The effect of hydraulic fractures on the performance of a conventional well. This was the most reliable way to remove the effects of spatial variations in permeability and contaminant distribution on relative well performance. It also provided data on the option of improving the performance of existing wells using hydraulic fractures. (2) The relative performance of a conventional SVE well and isolated hydraulic fractures. This was the most reliable indicator of the performance of hydraulic fractures that could be created in a

  4. ARM - Measurement - Soil surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surface temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil surface temperature The temperature of the soil measured near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those

  5. Pattern Effects of Soil on Photovoltaic Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burton, Patrick D.; Hendrickson, Alex; Ulibarri, Stephen Seth; Riley, Daniel; Boyson, William E.; King, Bruce H.

    2016-06-06

    The texture or patterning of soil on PV surfaces may influence light capture at various angles of incidence (AOI). Accumulated soil can be considered a microshading element, which changes with respect to AOI. Laboratory deposition of simulated soil was used to prepare test coupons for simultaneous AOI and soiling loss experiments. A mixed solvent deposition technique was used to consistently deposit patterned test soils onto glass slides. Transmission decreased as soil loading and AOI increased. Dense aggregates significantly decreased transmission. But, highly dispersed particles are less prone to secondary scattering, improving overall light collection. In order to test AOI losses on relevant systems, uniform simulated soil coatings were applied to split reference cells to further examine this effect. Finally, the measured optical transmission and area coverage correlated closely to the observedmore » $$I_{{rm SC}}$$. Angular losses were significant at angles as low as 25°.« less

  6. Bacteria increase arid-land soil surface temperature through...

    Office of Scientific and Technical Information (OSTI)

    Bacteria increase arid-land soil surface temperature through the production of sunscreens Prev Next Title: Bacteria increase arid-land soil surface temperature through the ...

  7. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  8. Variations in clay mineralogy and sediment texture of salt marsh soils on the Eastern Shore of Virginia

    SciTech Connect (OSTI)

    Robinson, S.E.; Furman, T. . Dept. of Environmental Sciences)

    1993-03-01

    On the Eastern Shore of VA, relative sea level rise has resulted in encroachment of marsh onto upland areas. The amount and type of sediment determines the morphologic environment of the system: lagoon, mudflat, low marsh, high marsh or upland. This research is part of a study to examine the relationship between marsh soil characteristics and the production of Spartina alterniflora. The productivity of marsh vegetation depends on the import and entrapment of sediments that maintain marsh elevation and control water and nutrient availability. This work focused on distribution patterns of sediment texture and mineralogy. One meter deep cores were taken at marsh sites with 10 cm intervals homogenized for analysis. In order to distinguish potential sediment sources, samples were also taken from upland soil pits on the mainland and dredged one-half mile seaward of the barrier islands. Samples have undergone size analysis with a hydrometer and the clay fraction has been analyzed by XRD. Results from the marsh surface indicate large variations in sediment texture, but only slight differences in clay mineralogy between marshes. Barrier island marshes contain a higher average sand content than mainland marshes because of their closer proximity to barrier island beaches and inputs from overwash deposits. The clay minerals found in all marsh surface deposits are illite and chlorite, indicative of oceanic clays. The clay mineralogy of upland soils (kaolinite, chlorite, illite, vermiculite mixed-layer clay) differs from marsh surface clays, indicating that recent sediment deposited on the marsh surface is no upland soil but rather material brought in through tidal inlets. The sediment texture and clay mineralogy at different depths varies as a function of the past geomorphic and depositional history of the site. These data will be used to determine the timing of marsh development on flooded upland sites and to determine the pre-Holocene source of inorganic sediment inputs.

  9. Soil erosion rates from mixed soil and gravel surfaces in a wind tunnel

    SciTech Connect (OSTI)

    Ligotke, M.W.; Klopfer, D.C.

    1990-08-01

    Protective barriers have been identified as integral components of plans to isolate defense waste on the Hanford Site. The use of natural materials to construct protective barriers over waste site is being considered. Design requirements for protective barriers include preventing exposure of buried waste, and restricting penetration or percolation of surface waters through the waste zone. Studies were initiated to evaluate the effects of wind erosion on candidate protective barrier surfaces. A wind tunnel was used to provide controlled erosive stresses and to investigate the erosive effects of wind forces on proposed surface layers for protective barriers. Mixed soil and gravel surfaces were prepared and tested for resistance to wind erosion at the Pacific Northwest Laboratory Aerosol Wind Tunnel Research Facility. These tests were performed to investigate surface deflation caused by suspension of soil from various surface layer configurations and to provide a comparison of the relative resistance of the different surfaces to wind erosion. Planning, testing, and analyzing phases of this wind erosion project were coordinated with other tasks supporting the development of protective barriers. These tasks include climate-change predictions, field studies and modeling efforts. This report provides results of measurements of deflation caused by wind forces over level surfaces. Section 2.0 reviews surface layer characteristics and previous relevant studies on wind erosion, describes effects of erosion, and discusses wind tunnel modeling. Materials and methods of the wind tunnel tests are discussed in Section 3.0. Results and discussion are presented in Section 4.0, and conclusions and recommendations Section 5.0. 53 refs., 29 figs., 7 tabs.

  10. Atmospheric and soil-gas monitoring for surface leakage at the...

    Office of Scientific and Technical Information (OSTI)

    Atmospheric and soil-gas monitoring for surface leakage at the San Juan Basin COsub 2 pilot test site at Pump Canyon New Mexico, using perfluorocarbon tracers, COsub 2 soil-gas ...

  11. Soils Soil Series

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soils Soil Series and Phase DBaC i:JFu IIiiiiIO!:l _PK _TuE _Ud DVeD o o o 1180 Meters o 590 \' Community _ Loblolly Pine D Mixed Pine/Hardwood D Upland Hardwood D Bonomland Hardwood iiiI Bonomland HardwoodlPine N Streams * TES Plants (1) D TES Plants (2) U Monitoring Wells o SRS Bays 6 ~ Utili1y ROW !.! Openwells tit NPDES outfalls ** Areas WI Roads rnOther Set-Asides ~ Hydric Soils Figure 15-1. Plant cOllllllunities and soils associated with the WhippldOH ER Study Site Set-Aside Area. 15-7

  12. Soils Soil Series

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Soils Soil Series and Phase D Fa D LaB _ TrB D TrC _ VeC .Wm '" Vegetation Compartment 28 Community D Mixed Pine/Hardwood D Upland Hardwod D Bottomland Hardwood _Water D Sandhill Scrub oak/Pine D Sandhill Pine/Scrub oak N Streams Roads _Water [2LJ Other Set-Asides DTES Plants (2) llilliJ Hydric Soils Road 8.11 560 Meters Figure 29-1. Plant cOllll1lunities and soils associated with the Scrub Oak Natural Area. 29-5 Set-Aside 29: Scrub Oak Natural Area

  13. Effects of PV Module Soiling on Glass Surface Resistance and Potential-Induced Degradation

    SciTech Connect (OSTI)

    Hacke, Peter; Button, Patrick; Hendrickson, Alex; Spataru, Sergiu; Glick, Stephen

    2015-06-14

    The goals of the project were: Determine applicability of transmission line method (TLM) to evaluate sheet resistance of soils on module glass;
    Evaluate various soils on glass for changes in surface resistance and their ability to promote potential-induced degradation with humidity (PID);
    Evaluate PID characteristics, rate, and leakage current increases on full-size mc-Si modules associated with a conductive soil on the surface.

  14. Fixation of soil surface contamination using natural polysaccharides

    SciTech Connect (OSTI)

    Sackschewsky, M.R.

    1993-09-01

    Natural polysaccharides were evaluated as alternatives to commercially available dust-control agents for application in buried-waste and contaminated-soil remediation situations. Materials were identified and evaluated with specific criteria in mind: the materials must be environmentally benign and must not introduce any additional hazardous materials; they must be effective for at least 2 or 3 days, but they do not necessarily have to be effective for more than 2 to 3 weeks; they should be relatively resistant to light traffic; they must not interfere with subsequent soil treatment techniques, especially soil washing; and they must be relatively inexpensive. Two products, a pregelled potato starch and a mixture of carbohydrates derived from sugar beets, were selected for evaluation. Testing included small- and large-scale field demonstrations, laboratory physical property analyses, and wind-tunnel evaluations.

  15. Bacteria increase arid-land soil surface temperature through the production of sunscreens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Couradeau, Estelle; Karaoz, Ulas; Lim, Hsiao Chien; Nunes da Rocha, Ulisses; Northen, Trent; Brodie, Eoin; Garcia-Pichel, Ferran

    2016-01-20

    Soil surface temperature, an important driver of terrestrial biogeochemical processes, depends strongly on soil albedo, which can be significantly modified by factors such as plant cover. In sparsely vegetated lands, the soil surface can be colonized by photosynthetic microbes that build biocrust communities. Here we use concurrent physical, biochemical and microbiological analyses to show that mature biocrusts can increase surface soil temperature by as much as 10 °C through the accumulation of large quantities of a secondary metabolite, the microbial sunscreen scytonemin, produced by a group of late-successional cyanobacteria. Scytonemin accumulation decreases soil albedo significantly. Such localized warming has apparentmore » and immediate consequences for the soil microbiome, inducing the replacement of thermosensitive bacterial species with more thermotolerant forms. In conclusion, these results reveal that not only vegetation but also microorganisms are a factor in modifying terrestrial albedo, potentially impacting biosphere feedbacks on past and future climate, and call for a direct assessment of such effects at larger scales.« less

  16. The use of plants to enhance microbial degradation of de-icing agents in soil and surface water

    SciTech Connect (OSTI)

    Rice, P.J.; Coats, J.R.; Anderson, T.A.

    1995-12-31

    Significant quantities of ethylene glycol (EG) and propylene glycol (PG) enter the environment through de-icing of aircraft, spills, and improper disposal of used antifreeze. An estimated 80% of the de-icing fluids spill onto the ground, which may lead to the contamination of soil, surface water, and groundwater. EG and PG contamination of surface waters creates a high biological oxygen demand (BOD) that can adversely impact aquatic communities. Plants and rhizosphere soils have been shown to enhance the degradation of organic pollutants in the soil. The research investigates the use of vegetation to enhance the transformation of EG and PG in soil by studying the fate of these chemicals in nonrhizosphere and rhizosphere soils at three temperatures ({minus}10 C, 0 C, 20 C). Terrestrial and aquatic emergent plants were evaluated as a cost-effective and aesthetically pleasing way to remediate and restore soil and surface waters contaminated with chemical de-icing agents. Additional surface runoff and vegetated undisturbed soil column studies were used to determine the influence of vegetation on the prevention of offsite movement by surface runoff and infiltration. Enhanced degradation of EG occurred in all the rhizosphere soils in comparison to the nonrhizosphere and autoclaved soils. After 28 days at 0 C, 40%, 41%, and 18% of applied EG degraded to CO{sub 2} in the Medicago sativa (alfalfa) and Festuca arundinacea (tall fescue) rhizosphere soil, and nonrhizosphere soil, respectively.

  17. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-03-15

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  18. Operable Unit 3-13, Group 3, Other Surface Soils (Phase II) Field Sampling Plan

    SciTech Connect (OSTI)

    G. L. Schwendiman

    2006-07-27

    This Field Sampling Plan describes the Operable Unit 3-13, Group 3, Other Surface Soils, Phase II remediation field sampling activities to be performed at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory Site. Sampling activities described in this plan support characterization sampling of new sites, real-time soil spectroscopy during excavation, and confirmation sampling that verifies that the remedial action objectives and remediation goals presented in the Final Record of Decision for Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13 have been met.

  19. Experimental observation of signature changes in bulk soil electrical conductivity in response to engineered surface CO2 leakage

    SciTech Connect (OSTI)

    Zhou X.; Wielopolski L.; Lakkaraju, V. R.; Apple, M.; Dobeck, L. M.; Gullickson, K.; Shaw, J. A.; Cunningham, A. B.; Spangler, L. H.

    2012-03-01

    Experimental observations of signature changes of bulk soil electrical conductivity (EC) due to CO{sub 2} leakage were carried out at a field site at Bozeman, Montana, to investigate the change of soil geophysical properties in response to possible leakage of geologically sequestered CO{sub 2}. The dynamic evolution of bulk soil EC was measured during an engineered surface leakage of CO{sub 2} through in situ continuous monitoring of bulk soil EC, soil moisture, soil temperature, rainfall rate, and soil CO{sub 2} concentration to investigate the response of soil bulk EC signature to CO{sub 2} leakage. Observations show that: (1) high soil CO{sub 2} concentration due to CO{sub 2} leakage enhances the dependence of bulk soil EC on soil moisture. The bulk soil EC is a linear multivariate function of soil moisture and soil temperature, the coefficient for soil moisture increased from 2.111 dS for the non-leaking phase to 4.589 dS for the CO{sub 2} leaking phase; and the coefficient for temperature increased from 0.003 dS/C for the non-leaking phase to 0.008 dS/C for the CO{sub 2} leaking phase. The dependence of bulk soil EC on soil temperature is generally weak, but leaked CO{sub 2} enhances the dependence, (2) after the CO{sub 2} release, the relationship between soil bulk EC and soil CO{sub 2} concentration observes three distinct CO{sub 2} decay modes. Rainfall events result in sudden changes of soil moisture and are believed to be the driving forcing for these decay modes, and (3) within each mode, increasing soil CO{sub 2} concentration results in higher bulk soil EC. Comparing the first 2 decay modes, it is found that the dependence of soil EC on soil CO{sub 2} concentration is weaker for the first decay mode than the second decay mode.

  20. Active cooling-based surface confinement system for thermal soil treatment

    DOE Patents [OSTI]

    Aines, Roger D.; Newmark, Robin L.

    1997-01-01

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.

  1. Active cooling-based surface confinement system for thermal soil treatment

    DOE Patents [OSTI]

    Aines, R.D.; Newmark, R.L.

    1997-10-28

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders. 1 fig.

  2. Effect of soil erosion on the long-term stability of FUSRAP near-surface waste-burial sites

    SciTech Connect (OSTI)

    Knight, M.J.

    1983-04-01

    Decontamination of FUSRAP sites could result in the generation of large volumes (in excess of 400,000 m/sup 3/) of low-activity radioactive wastes (primarily contaminated soil and building materials) requiring subsequent disposal. It is likely that near-surface burial will be seriously considered as an option for disposal of these materials. A number of factors - including soil erosion - could adversely affect the long-term stability of a near-surface waste-burial site. The majority of FUSRAP sites are located in the humid eastern United States, where the principal cause of erosion is the action of water. This report examines the effect of soil erosion by water on burial-site stability based on analysis of four hypothetical near-surface burial sites. The Universal Soil Loss Equation was employed to estimate average annual soil loss from burial sites and the 1000-year effects of soil loss on the soil barrier (burial trench cap) placed over low-activity wastes. Results suggest that the land use of the burial site and the slope gradient of the burial trench cap significantly affect the rate of soil erosion. The development of measures limiting the potential land use of a burial site (e.g., mixing large rocks into the burial trench cap) may be required to preserve the integrity of a burial trench for long periods of time.

  3. Wind-induced contaminant transport in near-surface soils with application to radon entry into buildings

    SciTech Connect (OSTI)

    Riley, W J

    1996-05-01

    Indoor air exposures to gaseous contaminants originating in soil can cause large human health risks. To predict and control these exposures, the mechanisms that affect vapor transport in near-surface soils need to be understood. In particular, radon exposure is a concern since average indoor radon concentrations lead to much higher risks than are generally accepted for exposure to other environmental contaminants. This dissertation examines an important component of the indoor radon problem: the impacts of wind on soil-gas and radon transport and entry into buildings. The research includes experimental and modeling studies of wind`s interactions with a building`s superstructure and the resulting soil-gas and radon flows in the surrounding soil. In addition to exploring the effects of steady winds, a novel modeling technique is developed to examine the impacts of fluctuating winds on soil-gas and radon transport.

  4. Assessing the relative influence of surface soil moisture and ENSO SST on precipitation predictability over the contiguous United States

    SciTech Connect (OSTI)

    Yoon, Jin-Ho; Leung, Lai-Yung R.

    2015-06-28

    This study assesses the relative influence of soil moisture memory and tropical sea surface temperature (SST) in seasonal rainfall over the contiguous United States. Using observed precipitation, the NINO3.4 index and soil moisture and evapotranspiration simulated by a land surface model for 61 years, analysis was performed using partial correlations to evaluate to what extent land surface and SST anomaly of El Niño and Southern Oscillation (ENSO) can affect seasonal precipitation over different regions and seasons. Results show that antecedent soil moisture is as important as concurrent ENSO condition in controlling rainfall anomalies over the U.S., but they generally dominate in different seasons with SST providing more predictability during winter while soil moisture, through its linkages to evapotranspiration and snow water, has larger influence in spring and early summer. The proposed methodology is applicable to climate model outputs to evaluate the intensity of land-atmosphere coupling and its relative importance.

  5. Operable Unit 3-13, Group 3, Other Surface Soils (Phase I) Remedial Action Report

    SciTech Connect (OSTI)

    L. Davison

    2007-07-31

    This Remedial Action Report summarizes activities undertaken to remediate the Operable Unit 3-13, Group 3, Other Surface Soils, Phase I sites at the Idaho Nuclear Technology and Engineering Center at the Idaho National Laboratory Site. The 10 sites addressed in this report were defined in the Operable Unit 3-13 Record of Decision and subsequent implementing documents. This report concludes that remediation requirements and cleanup goals established for these 10 sites have been accomplished and are hereafter considered No Action or No Further Action sites.

  6. Effects of Photovoltaic Module Soiling on Glass Surface Resistance and Potential-Induced Degradation

    SciTech Connect (OSTI)

    Hacke, Peter; Burton, Patrick; Hendrickson, Alex; Spataru, Sergiu; Glick, Stephen; Terwilliger, Kent

    2015-06-14

    The sheet resistance of three soil types (Arizona road dust, soot, and sea salt) on glass were measured by the transmission line method as a function of relative humidity (RH) between 39% and 95% at 60 degrees C. Sea salt yielded a 3.5 orders of magnitude decrease in resistance on the glass surface when the RH was increased over this RH range. Arizona road dust showed reduced sheet resistance at lower RH, but with less humidity sensitivity over the range tested. The soot sample did not show significant resistivity change compared to the unsoiled control. Photovoltaic modules with sea salt on their faces were step-stressed between 25% and 95% RH at 60 degrees C applying -1000 V bias to the active cell circuit. Leakage current from the cell circuit to ground ranged between two and ten times higher than that of the unsoiled controls. Degradation rate of modules with salt on the surface increased with increasing RH and time.

  7. Effects of PV Module Soiling on Glass Surface Resistance and Potential-Induced Degradation: Preprint

    SciTech Connect (OSTI)

    Hacke, Peter; Burton, Patrick; Hendrickson, Alex; Spartaru, Sergiu; Glick, Stephen; Terwilliger, Kent

    2015-12-03

    The sheet resistance of three soil types (Arizona road dust, soot, and sea salt) on glass were measured by the transmission line method as a function of relative humidity (RH) between 39% and 95% at 60 degrees C. Sea salt yielded a 3.5 order of magnitude decrease in resistance on the glass surface when the RH was increased over this RH range. Arizona road dust showed reduced sheet resistance at lower RH, but with less humidity sensitivity over the range tested. The soot sample did not show significant resistivity change compared to the unsoiled control. Photovoltaic modules with sea salt on their faces were step-stressed between 25% and 95% RH at 60 degrees C applying -1000 V bias to the active cell circuit. Leakage current from the cell circuit to ground ranged between two and ten times higher than that of the unsoiled controls. Degradation rate of modules with salt on the surface increased with increasing RH and time.

  8. Diurnal activity of soil surface arthropods in agroecosystems: design for an inexpensive time-sorting pitfall trap

    SciTech Connect (OSTI)

    Blumberg, A.Y.; Crossley, D.A. Jr.

    1986-01-01

    The design for an inexpensive time-sorting pitfall trap is presented. The basis of the mechanism is a rotary stepping solenoid powered by lantern batteries. Traps were utilized to sample soil surface arthropods at two hour intervals for five 24 hr periods in 1983. One trap each was placed in conventional tillage (CT) and no-tillage (NT) agroecosystems. Soil arthropod surface activity was greatest in CT on 9 July during the dawn and dusk periods but the data did not indicate other dominant trends. Activity in NT was greatest during dusk on 27 June, but again no other dominant trends were evident. When CT and NT are combined over the sample dates, surface soil arthropod activity peaked during dusk, with a smaller activity peak at dawn. 10 refs., 6 figs.

  9. Soil Series

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Soil Series and Phase D Bae D Da rn Fa D FuB D LuB ~ 09 _ Pk _ TrB _ TuE DUo _ vee D VeD o o * '='1 ~*.1* **..oC'" ~) OJ rI.:) o.Q 600 1200 Soils n O~:-* ilL 10., 1800 O~ c? ~ 0 ~ O~ Community _ Loblolly Pine D Mixed Pine/Hardwood o Upland Hardwood D Bottomland Hardwood _ Water a Bottomland HardwoodlPine o Monitoringwells .._.' *** TES Plants (1) :l!.-.~I ... 0 TES Plants (2) :='.Y-r::.: ~ Streams ){" ~ Rails . :1'\;:'/ Utility ROW ""If WasteSItes III NPDES outfalls CZI

  10. Multiple soil nutrient competition between plants, microbes, and mineral surfaces: model development, parameterization, and example applications in several tropical forests

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Q.; Riley, W. J.; Tang, J.; Koven, C. D.

    2015-03-05

    Soil is a complex system where biotic (e.g., plant roots, micro-organisms) and abiotic (e.g., mineral surfaces) consumers compete for resources necessary for life (e.g., nitrogen, phosphorus). This competition is ecologically significant, since it regulates the dynamics of soil nutrients and controls aboveground plant productivity. Here we develop, calibrate, and test a nutrient competition model that accounts for multiple soil nutrients interacting with multiple biotic and abiotic consumers. As applied here for tropical forests, the Nutrient COMpetition model (N-COM) includes three primary soil nutrients (NH4+, NO3?, and POx (representing the sum of PO43?, HPO42?, and H2PO4?)) and five potential competitors (plantmoreroots, decomposing microbes, nitrifiers, denitrifiers, and mineral surfaces). The competition is formulated with a quasi-steady-state chemical equilibrium approximation to account for substrate (multiple substrates share one consumer) and consumer (multiple consumers compete for one substrate) effects. N-COM successfully reproduced observed soil heterotrophic respiration, N2O emissions, free phosphorus, sorbed phosphorus, and free NH4+ at a tropical forest site (Tapajos). The overall model posterior uncertainty was moderately well constrained. Our sensitivity analysis revealed that soil nutrient competition was primarily regulated by consumer-substrate affinity rather than environmental factors such as soil temperature or soil moisture. Our results imply that the competitiveness (from most to least competitive) followed this order: (1) for NH4+, nitrifiers ~ decomposing microbes > plant roots, (2) for NO3?, denitrifiers ~ decomposing microbes > plant roots, (3) for POx, mineral surfaces > decomposing microbes ~ plant roots. Although smaller, plant relative competitiveness is of the same order of magnitude as microbes. We then applied the N-COM model to analyze field nitrogen and phosphorus perturbation experiments in two tropical forest sites (in

  11. Project test plan for runoff and erosion on fine-soil barrier surfaces and rock-covered side slopes

    SciTech Connect (OSTI)

    Walters, W.H.; Hoover, K.A.; Cadwell, L.L.

    1990-06-01

    Pacific Northwest Laboratory (PNL) and Westinghouse Hanford Company are working together to develop protective barriers to isolate near-surface radioactive waste. The purpose of the barriers is to protect defense wastes at the US Department of Energy's (DOE) Hanford Site from infiltration of precipitation, biointrusion, and surficial erosion for up to 10,000 years without the need for long-term monitoring, maintenance, or institutional control. The barriers will be constructed of layered earth and rock material designed to direct surface and groundwater pathways away from the buried waste. To address soil erosion as it applies to barrier design and long-term stability, a task designed to study this problem has been included in the Protective Barriers Program at PNL. The barrier soil-erosion task will investigate the ability of the soil cover and side slopes to resist the erosional and destabilizing processes from externally applied water. The study will include identification and field testing of the dominant processes contributing to erosion and barrier failure. The effects of rock mulches, vegetation cover on the top fine-grained soil surface, as well as the stability of rock armoring on the side slopes, will be evaluated. Some of the testing will include the effects of animal intrusion on barrier erosion, and these will be coordinated with other animal intrusion studies. 6 refs., 4 figs., 1 tab.

  12. CO2 and CH4 Surface Flux, Soil Profile Concentrations, and Stable Isotope Composition, Barrow, Alaska, 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Curtis, J.B.; Vaughn, L.S.; Torn, M.S.; Conrad, M.S.; Chafe, O.; Bill, M.

    2015-12-31

    In August-October 2012 and June-October 2013, co-located measurements were made of surface CH4 and CO2 flux, soil pore space concentrations and stable isotope compositions of CH4 and CO2, and subsurface temperature and soil moisture. Measurements were made in intensive study site 1 areas A, B, and C, and from the site 0 and AB transects, from high-centered, flat-centered, and low-centered polygons, from the center, edge, and trough of each polygon.

  13. Surface study of stainless steel electrode deposition from soil electrokinetic (EK) treatment using X-ray photoelectron spectroscopy (XPS)

    SciTech Connect (OSTI)

    Embong, Zaidi; Johar, Saffuwan; Tajudin, Saiful Azhar Ahmad; Sahdan, Mohd Zainizan

    2015-04-29

    Electrokinetic (EK) remediation relies upon application of a low-intensity direct current through the soil between stainless steel electrodes that are divided into a cathode array and an anode array. This mobilizes charged species, causing ions and water to move toward the electrodes. Metal ions and positively charged organic compounds move toward the cathode. Anions such as chloride, fluoride, nitrate, and negatively charged organic compounds move toward the anode. Here, this remediation techniques lead to a formation of a deposition at the both cathode and anode surface that mainly contributed byanion and cation from the remediated soil. In this research, Renggam-Jerangau soil species (HaplicAcrisol + RhodicFerralsol) with a surveymeter reading of 38.0 ± 3.9 μR/hr has been investigation in order to study the mobility of the anion and cation under the influence electric field. Prior to the EK treatment, the elemental composition of the soil and the stainless steel electrode are measured using XRF analyses. Next, the soil sample is remediated at a constant electric potential of 30 V within an hour of treatment period. A surface study for the deposition layer of the cathode and anode using X-ray Photoelectron spectroscopy (XPS) revealed that a narrow photoelectron signal from oxygen O 1s, carbon, C 1s silica, Si 2p, aluminium, Al 2p and chromium, Cr 2p exhibited on the electrode surface and indicate that a different in photoelectron intensity for each element on both electrode surface. In this paper, the mechanism of Si{sup 2+} and Al{sup 2+} cation mobility under the influence of voltage potential between the cathode and anode will be discussed in detail.

  14. Surface radiation survey and soil sampling of the 300-FF-1 operable unit, Hanford Site, southeastern Washington: A case study

    SciTech Connect (OSTI)

    Teel, S.S.; Olsen, K.B.

    1990-10-01

    The methods used for conducting a radiological characterization of the soil surface for the Phase I Remedial Investigation of a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) site is presented via a case study. The study site is an operable unit (300-FF-1) located in and adjacent to the 300 Area of the US Department of Energy's Hanford Site in southeastern Washington State. The operable unit contains liquid and solid waste disposal facilities associated with nuclear fuels fabrication. Continuous surface radiation surveying and soil sampling of selected locations were conducted. Contamination was found in several locations within the operable unit including areas near the liquid and solid waste disposal facilities. Instruments used during surveying included portable beta/gamma (P-11) detectors, and the Ultrasonic Ranging and Data System using an NaI (Tl) detector. Laboratory analyses results indicate that above-background radiation levels were primarily due to the presence of uranium. Both types of field instruments used in the study were effective in detecting surface contamination from radionuclides; however, each had specific advantages. Guidelines are presented for the optimum use of these instruments when performing a radiological characterization of the soil surface. 4 refs., 3 figs., 3 tabs.

  15. Multiple soil nutrient competition between plants, microbes, and mineral surfaces: model development, parameterization, and example applications in several tropical forests

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Q.; Riley, W. J.; Tang, J.; Koven, C. D.

    2016-01-18

    Soil is a complex system where biotic (e.g., plant roots, micro-organisms) and abiotic (e.g., mineral surfaces) consumers compete for resources necessary for life (e.g., nitrogen, phosphorus). This competition is ecologically significant, since it regulates the dynamics of soil nutrients and controls aboveground plant productivity. Here we develop, calibrate and test a nutrient competition model that accounts for multiple soil nutrients interacting with multiple biotic and abiotic consumers. As applied here for tropical forests, the Nutrient COMpetition model (N-COM) includes three primary soil nutrients (NH4+, NO3− and POx; representing the sum of PO43−, HPO42− and H2PO4−) and five potential competitors (plantmore » roots, decomposing microbes, nitrifiers, denitrifiers and mineral surfaces). The competition is formulated with a quasi-steady-state chemical equilibrium approximation to account for substrate (multiple substrates share one consumer) and consumer (multiple consumers compete for one substrate) effects. N-COM successfully reproduced observed soil heterotrophic respiration, N2O emissions, free phosphorus, sorbed phosphorus and NH4+ pools at a tropical forest site (Tapajos). The overall model uncertainty was moderately well constrained. Our sensitivity analysis revealed that soil nutrient competition was primarily regulated by consumer–substrate affinity rather than environmental factors such as soil temperature or soil moisture. Our results also imply that under strong nutrient limitation, relative competitiveness depends strongly on the competitor functional traits (affinity and nutrient carrier enzyme abundance). We then applied the N-COM model to analyze field nitrogen and phosphorus perturbation experiments in two tropical forest sites (in Hawaii and Puerto Rico) not used in model development or calibration. Under soil inorganic nitrogen and phosphorus elevated conditions, the model accurately replicated the experimentally observed

  16. Resolving Carbon's Rainbow from Uplands to the Deep-sea | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resolving Carbon's Rainbow from Uplands to the Deep-sea Event Sponsor: Environmental Science Division Seminar Start Date: Sep 17 2015 - 11:00am BuildingRoom: Building 240Room...

  17. Operable Unit 3-13, Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) Waste Management Plan

    SciTech Connect (OSTI)

    G. L. Schwendiman

    2006-07-01

    This Waste Management Plan describes waste management and waste minimization activities for Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory. The waste management activities described in this plan support the selected response action presented in the Final Record of Decision for Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13. This plan identifies the waste streams that will be generated during implementation of the remedial action and presents plans for waste minimization, waste management strategies, and waste disposition.

  18. Artificial Soiling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Artificial Soiling of Photovoltaic Module Surfaces using Traceable Soil Components Patrick D. Burton and Bruce H. King Sandia National Laboratories Albuquerque NM 87185 USA Email: pdburto@sandia.gov Abstract-Effective evaluation and prediction of photovoltaic performance loss due to soiling requires consistent test methods. Natural grime accumulation is time-consuming and location- specific, and thus does not provide reproducible results across different geographic regions. Therefore, we have

  19. Comparative plant uptake and microbial degradation of trichloroethylene in the rhizospheres of five plant species-- implications for bioremediation of contaminated surface soils

    SciTech Connect (OSTI)

    Anderson, T.A. ); Walton, B.T. )

    1992-01-01

    The objective of this study was to collect data that would provide a foundation for the concept of using vegetation to enhance in situ bioremediation of contaminated surface soils. Soil and vegetation (Lespedeza cuneata, Paspalum notatum, Pinus taeda, and Solidago sp.) samples from the Miscellaneous Chemicals Basin (MCB) at the Savannah River Site were used in tests to identify critical plant and microbiological variables affecting the fate of trichloroethylene (TCE) in the root zone. Microbiological assays including phospholipid acid analyses, and {sup 14}C-acetate incorporation were conducted to elucidate differences in rhizosphere and nonvegetated soil microbial communities from the MCB. The microbial activity, biomass, and degradation of TCE in rhizosphere soils were significantly greater than corresponding nonvegetated soils. Vegetation had a positive effect on microbial degradation of {sup 14}C-TCE in whole-plant experiments. Soils from the MCB containing Lespedeza cuneata, Pinus taeda, and Glycine max mineralized greater than 25% of the {sup 14}C- TCE added compared with less than 20% in nonvegetated soils. Collectively, these results provide evidence for the positive role of vegetation in enhancing biodegradation.

  20. Riparian and Upland Restoration at the U.S. Department of Energy Rocky Flats, Colorado, Site - 12360

    SciTech Connect (OSTI)

    Nelson, Jody K.

    2012-07-01

    Remedial investigation and cleanup at the Rocky Flats, Colorado, Site was completed in 2005. Uplands, riparian, and wetland habitat were disturbed during cleanup and closure activities and required extensive revegetation. Unavoidable disturbances to habitat of the Preble's meadow jumping mouse (a federally listed species) and wetlands required consultation with regulatory agencies and mitigation. Mitigation wetlands were constructed in two drainages, and a third developed naturally where a soil borrow area intercepted the groundwater table. During the 50-plus years of site operations, 12 ponds were constructed in three drainages to manage and retain runoff and sewage treatment plant discharges prior to release off site. A batch-release protocol has been used for the past several decades at the terminal ponds, which has affected the riparian communities downstream. To return the hydrologic regime to a more natural flow-through system similar to the pre-industrial-use conditions, seven interior dams (of 12) have been breached, and the remaining five dams are scheduled for breaching between 2011 and 2020. At the breached dams, the former open water areas have transformed to emergent wetlands, and the stream reaches have returned to a flow-through system. Riparian and wetland vegetation has established very well. The valves of the terminal ponds were opened in fall 2011 to begin flow-through operations and provide water to the downstream plant communities while allowing reestablishment of vegetation in the former pond bottoms prior to breaching. A number of challenges and issues were addressed during the revegetation effort. These included reaching an agreement on revegetation goals, addressing poor substrate quality and soil compaction problems, using soil amendments and topsoil, selecting seeds, determining the timing and location of revegetation projects relative to continuing closure activities, weed control, erosion control, revegetation project field oversight

  1. Surface and subsurface soils at the Pond B dam: July 1998

    SciTech Connect (OSTI)

    Halverson, N.V.

    1999-12-03

    Pond B, 685-13G, is an inactive reactor cooling impoundment built in 1961 on the Savannah River Site (SRS). Between 1961 and 1964, Pond B received R-Reactor cooling water discharges that were contaminated with {sup 137}Cs, {sup 90}Sr and plutonium. Though the pond has not been used since 1964, radionuclides from the contaminated cooling water remain in the water and in the surface sediments of the pond. The current proposal to fix and repair the Pond B dam structure includes installing a new drain system and monitoring equipment. The dam will be reinforced with additional previous material on the downstream face of the dam. The objectives of this report are to describe the sampling methodology used during the July 1998 sampling event at the downstream face of the Pond B dam and in Pond B, present the results of the sampling event, and compare, where possible, these results to related risk-based standards.

  2. Environmental impact of APC residues from municipal solid waste incineration: Reuse assessment based on soil and surface water protection criteria

    SciTech Connect (OSTI)

    Quina, Margarida J.; Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

    2011-09-15

    Highlights: > The Dutch Building Material Decree (BMD) was used to APC residues from MSWI. > BMD is a straightforward tool to calculate expectable loads to the environment of common pollutants. > Chloride load to the environment lead to classification of building material not allowed. > At least a pre-treatment (e.g. washing) is required in order to remove soluble salts. > The stabilization with phosphates or silicates eliminate the problem of heavy metals. - Abstract: Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of 'building material not allowed'. The treatments with phosphates or silicates are able to solve the problem of heavy metals, but

  3. ARM - Campaign Instrument - soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Soil Measurement from the SGP (SOIL) Instrument Categories SurfaceSubsurface Properties Campaigns ...

  4. ARM - Instrument - soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Soil Measurement from the SGP (SOIL) Instrument Categories SurfaceSubsurface ...

  5. ARM - Measurement - Soil moisture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    moisture ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil moisture The moisture of the soil measured near the surface. This includes soil wetness and soil water potential. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  6. Soil and variety effects on energy use and carbon emissions associated with switchgrass-based ethanol production in Mississippi

    SciTech Connect (OSTI)

    Woli, Prem; Paz, Joel O.; Baldwin, Brian S.; Lang, David J.; Kiniry, James R.

    2012-06-29

    High biomass production potential, wide adaptability, low input requirement, and low environmental risk make switchgrass an economically and ecologically viable energy crop.The inherent variablity in switchgrass productivity due to variations in soil and variety could affect the sustainability and eco-friendliness of switchgrass-based ethanol production. This study examined the soil and variety effects on these variables. Three locations in Mississippi were selected based on latitude and potential acreage. Using ALMANAC, switchgrass biomass yields were simulated for several scenarios of soils and varities. The simulated yields were fed to IBSAL to compute energy use and CO2 emissions in various operations in the biomass supply From the energy and emissions values, the sustainability and eco-friendliness of ethanol production were determined using net energy value (NEV) and carbon credit balance (CCB) as indicators, respectively. Soil and variety effects on NEV and CCB were analyzed using the Kruskal-Wallis test. Results showed significant differences in NEV and CCB across soils and varieties. Both NEV and CCB increased in the direction of heavier to lighter soils and on the order of north-upland , south-upland, north-lowland, and south-lowland varieties. Only north-upland and south-lowland varieties were significantly significantly different because they were different in both cytotype and ecotype. Gaps between lowland and upland varieties were smaller in a dry year than in a wet year. The NEV and CCB increased in the direction of dry to wet year. From south to north, they decreased for lowland cytotypes but increased for upland cytotypes. Thus, the differences among varieties decreased northwards.

  7. Operable Unit 3-13, Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) Remedial Design/Remedial Action Work Plan

    SciTech Connect (OSTI)

    D. E. Shanklin

    2006-06-01

    This Remedial Design/Remedial Action Work Plan provides the framework for defining the remedial design requirements, preparing the design documentation, and defining the remedial actions for Waste Area Group 3, Operable Unit 3-13, Group 3, Other Surface Soils, Remediation Sets 4-6 (Phase II) located at the Idaho Nuclear Technology and Engineering Center at the Idaho National Laboratory. This plan details the design developed to support the remediation and disposal activities selected in the Final Operable Unit 3-13, Record of Decision.

  8. Responses of upland herpetofauna to the restoration of Carolina Bays and thinning of forested Bay Margins.

    SciTech Connect (OSTI)

    Ledvina, Joseph A.

    2008-05-01

    Research on the effects of wetland restoration on reptiles and amphibians is becoming more common, but almost all of these studies have observed the colonization of recently disturbed habitats that were completely dry at the time of restoration. In a similar manner, investigations herpetofaunal responses to forest management have focused on clearcuts, and less intensive stand manipulations are not as well studied. To evaluate community and population responses of reptiles and amphibians to hydrology restoration and canopy removal in the interior of previously degraded Carolina bays, I monitored herpetofauna in the uplands adjacent to six historically degraded Carolina bays at the Savannah River Site (SRS) in South Carolina for four years after restoration. To evaluate the effects of forest thinning on upland herpetofauna, forests were thinned in the margins of three of these bays. I used repeated measures ANOVA to compare species richness and diversity and the abundance of selected species and guilds between these bays and with those at three reference bays that were not historically drained and three control bays that remained degraded. I also used Non-metric Multidimensional Scaling (NMDS) to look for community-level patterns based treatments.

  9. Atmospheric and soil-gas monitoring for surface leakage at the San Juan Basin CO{sub 2} pilot test site at Pump Canyon New Mexico, using perfluorocarbon tracers, CO{sub 2} soil-gas flux and soil-gas hydrocarbons

    SciTech Connect (OSTI)

    Wells, Arthur W.; Diehl, J. Rodney; Strazisar, Brian R.; Wilson, Thomas; H Stanko, Dennis C.

    2012-05-01

    Near-surface monitoring and subsurface characterization activities were undertaken in collaboration with the Southwest Regional Carbon Sequestration Partnership on their San Juan Basin coal-bed methane pilot test site near Navajo City, New Mexico. Nearly 18,407 short tons (1.670 107 kg) of CO{sub 2} were injected into 3 seams of the Fruitland coal between July 2008 and April 2009. Between September 18 and October 30, 2008, two additions of approximately 20 L each of perfluorocarbon (PFC) tracers were mixed with the CO{sub 2} at the injection wellhead. PFC tracers in soil-gas and in the atmosphere were monitored over a period of 2 years using a rectangular array of permanent installations. Additional monitors were placed near existing well bores and at other locations of potential leakage identified during the pre-injection site survey. Monitoring was conducted using sorbent containing tubes to collect any released PFC tracer from soil-gas or the atmosphere. Near-surface monitoring activities also included CO{sub 2} surface flux and carbon isotopes, soil-gas hydrocarbon levels, and electrical conductivity in the soil. The value of the PFC tracers was demonstrated when a significant leakage event was detected near an offset production well. Subsurface characterization activities, including 3D seismic interpretation and attribute analysis, were conducted to evaluate reservoir integrity and the potential that leakage of injected CO{sub 2} might occur. Leakage from the injection reservoir was not detected. PFC tracers made breakthroughs at 2 of 3 offset wells which were not otherwise directly observable in produced gases containing 2030% CO{sub 2}. These results have aided reservoir geophysical and simulation investigations to track the underground movement of CO{sub 2}. 3D seismic analysis provided a possible interpretation for the order of appearance of tracers at production wells.

  10. In-situ vitrification of soil

    DOE Patents [OSTI]

    Brouns, Richard A.; Buelt, James L.; Bonner, William F.

    1983-01-01

    A method of vitrifying soil at or below a soil surface location. Two or more conductive electrodes are inserted into the soil for heating of the soil mass between them to a temperature above its melting temperature. Materials in the soil, such as buried waste, can thereby be effectively immobilized.

  11. THE RESILIENCE OF UPLAND-OAK FOREST CANOPY TREES TO CHRONIC AND ACUTE PRECIPITATION MANIPULATIONS

    SciTech Connect (OSTI)

    Hanson, Paul J; Tschaplinski, Timothy J; Wullschleger, Stan D; Todd Jr, Donald E; Auge, Robert M.

    2007-01-01

    Implications of chronic ( 33 percent) and acute (-100 percent) precipitation change were evaluated for trees of upland-oak forests of the eastern United States. Chronic manipulations have been conducted since 1993, and acute manipulations of dominant canopy trees (Quercus prinus; Liriodendron tulipifera) were initiated in 2003. Through 12 years of chronic manipulations tree growth remained unaffected by natural or induced rainfall deficits even though severe drought conditions dramatically reduced canopy function in some years. The resilience of canopy trees to chronic-change was the result of a disconnect between tree growth phenology and late-season drought occurrence. Acute precipitation exclusion from the largest canopy trees also produced limited growth reductions from 2003 through 2005. Elimination of lateral root water sources for the acute treatment trees, via trenching midway through the 2004 growing-season, forced the conclusion that deep rooting was a key mechanism for large-tree resilience to severe drought.

  12. Soiling of building envelope surfaces and its effect on solar reflectance. Part I: Analysis of roofing product databases

    SciTech Connect (OSTI)

    Sleiman, Mohamad; Ban-Weiss, George; Gilbert, Haley E.; François, David; Berdahl, Paul; Kirchstetter, Thomas W.; Destaillats, Hugo; Levinson, Ronnen

    2011-12-01

    The use of highly reflective “cool” roofing materials can decrease demand for air conditioning, mitigate the urban heat island effect, and potentially slow global warming. However, initially high roof solar reflectance can be degraded by natural soiling and weathering processes. We evaluated solar reflectance losses after three years of natural exposure reported in two separate databases: the Rated Products Directory of the US Cool Roof Rating Council (CRRC) and information reported by manufacturers to the US Environmental Protection Agency (EPA)’s ENERGY STAR® rating program. Many product ratings were culled because they were duplicative (within a database) or not measured. A second, site-resolved version of the CRRC dataset was created by transcribing from paper records the site-specific measurements of aged solar reflectance in Florida, Arizona and Ohio. Products with high initial solar reflectance tended to lose reflectance, while those with very low initial solar reflectance tended to become more reflective as they aged. Within the site-resolved CRRC database, absolute solar reflectance losses for samples of medium-to-high initial solar reflectance were 2 - 3 times greater in Florida (hot and humid) than in Arizona (hot and dry); losses in Ohio (temperate but polluted) were intermediate. Disaggregating results by product type, factory-applied coating, field-applied coating, metal, modified bitumen, shingle, singleply membrane and tile, revealed that absolute solar reflectance losses were largest for fieldapplied coating, modified bitumen and single-ply membrane products, and smallest for factoryapplied coating and metal products.The 2008 Title 24 provisional aged solar reflectance formula overpredicts the measured aged solar reflectance of 0% to 30% of each product type in the culled public CRRC database. The rate of overprediction was greatest for field-applied coating and single-ply membrane products and least for factory-applied coating, shingle, and

  13. Soiling of building envelope surfaces and its effect on solar reflectance. Part I: Analysis of roofing product databases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sleiman, Mohamad; Ban-Weiss, George; Gilbert, Haley E.; François, David; Berdahl, Paul; Kirchstetter, Thomas W.; Destaillats, Hugo; Levinson, Ronnen

    2011-12-01

    The use of highly reflective “cool” roofing materials can decrease demand for air conditioning, mitigate the urban heat island effect, and potentially slow global warming. However, initially high roof solar reflectance can be degraded by natural soiling and weathering processes. We evaluated solar reflectance losses after three years of natural exposure reported in two separate databases: the Rated Products Directory of the US Cool Roof Rating Council (CRRC) and information reported by manufacturers to the US Environmental Protection Agency (EPA)’s ENERGY STAR® rating program. Many product ratings were culled because they were duplicative (within a database) or not measured. Amore » second, site-resolved version of the CRRC dataset was created by transcribing from paper records the site-specific measurements of aged solar reflectance in Florida, Arizona and Ohio. Products with high initial solar reflectance tended to lose reflectance, while those with very low initial solar reflectance tended to become more reflective as they aged. Within the site-resolved CRRC database, absolute solar reflectance losses for samples of medium-to-high initial solar reflectance were 2 - 3 times greater in Florida (hot and humid) than in Arizona (hot and dry); losses in Ohio (temperate but polluted) were intermediate. Disaggregating results by product type, factory-applied coating, field-applied coating, metal, modified bitumen, shingle, singleply membrane and tile, revealed that absolute solar reflectance losses were largest for fieldapplied coating, modified bitumen and single-ply membrane products, and smallest for factoryapplied coating and metal products.The 2008 Title 24 provisional aged solar reflectance formula overpredicts the measured aged solar reflectance of 0% to 30% of each product type in the culled public CRRC database. The rate of overprediction was greatest for field-applied coating and single-ply membrane products and least for factory-applied coating

  14. Multiple soil nutrient competition between plants, microbes,...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Multiple soil nutrient competition between plants, microbes, and mineral surfaces: model development, parameterization, and example applications in several...

  15. Development testing of the chemical analysis automation polychlorinated biphenyl standard analysis method during surface soils sampling at the David Witherspoon 1630 site

    SciTech Connect (OSTI)

    Hunt, M.A.; Klatt, L.N.; Thompson, D.H.

    1998-02-01

    The Chemical Analysis Automation (CAA) project is developing standardized, software-driven, site-deployable robotic laboratory systems with the objective of lowering the per-sample analysis cost, decreasing sample turnaround time, and minimizing human exposure to hazardous and radioactive materials associated with DOE remediation projects. The first integrated system developed by the CAA project is designed to determine polychlorinated biphenyls (PCB) content in soil matrices. A demonstration and development testing of this system was conducted in conjuction with surface soil characterization activities at the David Witherspoon 1630 Site in Knoxville, Tennessee. The PCB system consists of five hardware standard laboratory modules (SLMs), one software SLM, the task sequence controller (TSC), and the human-computer interface (HCI). Four of the hardware SLMs included a four-channel Soxhlet extractor, a high-volume concentrator, a column cleanup, and a gas chromatograph. These SLMs performed the sample preparation and measurement steps within the total analysis protocol. The fifth hardware module was a robot that transports samples between the SLMs and the required consumable supplies to the SLMs. The software SLM is an automated data interpretation module that receives raw data from the gas chromatograph SLM and analyzes the data to yield the analyte information. The TSC is a software system that provides the scheduling, management of system resources, and the coordination of all SLM activities. The HCI is a graphical user interface that presents the automated laboratory to the analyst in terms of the analytical procedures and methods. Human control of the automated laboratory is accomplished via the HCI. Sample information required for processing by the automated laboratory is entered through the HCI. Information related to the sample and the system status is presented to the analyst via graphical icons.

  16. Tropical forest soil microbial communities couple iron and carbon biogeochemistry

    SciTech Connect (OSTI)

    Dubinsky, E.A.; Silver, W.L.; Firestone, M.K.

    2009-10-15

    We report that iron-reducing bacteria are primary mediators of anaerobic carbon oxidation in upland tropical soils spanning a rainfall gradient (3500 - 5000 mm yr-1) in northeast Puerto Rico. The abundant rainfall and high net primary productivity of these tropical forests provide optimal soil habitat for iron-reducing and iron-oxidizing bacteria. Spatially and temporally dynamic redox conditions make iron-transforming microbial communities central to the belowground carbon cycle in these wet tropical forests. The exceedingly high abundance of iron-reducing bacteria (up to 1.2 x 10{sup 9} cells per gram soil) indicated that they possess extensive metabolic capacity to catalyze the reduction of iron minerals. In soils from the higher rainfall sites, measured rates of ferric iron reduction could account for up to 44 % of organic carbon oxidation. Iron reducers appeared to compete with methanogens when labile carbon availability was limited. We found large numbers of bacteria that oxidize reduced iron at sites with high rates of iron reduction and large numbers of iron-reducers. the coexistence of large populations of ironreducing and iron-oxidizing bacteria is evidence for rapid iron cycling between its reduced and oxidized states, and suggests that mutualistic interactions among these bacteria ultimately fuel organic carbon oxidation and inhibit CH4 production in these upland tropical forests.

  17. Surface Environmental Surveillance Project: Locations Manual Volume 1 – Air and Water Volume 2 – Farm Products, Soil & Vegetation, and Wildlife

    SciTech Connect (OSTI)

    Fritz, Brad G.; Patton, Gregory W.; Stegen, Amanda; Poston, Ted M.

    2009-01-01

    This report describes all environmental monitoring locations associated with the Surface Environmental Surveillance Project. Environmental surveillance of the Hanford site and surrounding areas is conducted by the Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE). Sampling is conducted to evaluate levels of radioactive and nonradioactive pollutants in the Hanford environs, as required in DOE Order 450.1, Environmental Protection Program, and DOE Order 5400.5, Radiation Protection of the Public and the Environment. The environmental surveillance sampling design is described in the Hanford Site Environmental Monitoring Plan, United States Department of Energy, Richland Operation Office (DOE/RL-91-50). This document contains the locations of sites used to collect samples for the Surface Environmental Surveillance Project (SESP). Each section includes directions, maps, and pictures of the locations. A general knowledge of roads and highways on and around the Hanford Site is necessary to successfully use this manual. Supplemental information (Maps, Gazetteer, etc.) may be necessary if user is unfamiliar with local routes. The SESP is a multimedia environmental surveillance effort to measure the concentrations of radionuclides and chemicals in environmental media to demonstrate compliance with applicable environmental quality standards and public exposure limits, and assessing environmental impacts. Project personnel annually collect selected samples of ambient air, surface water, agricultural products, fish, wildlife, and sediments. Soil and vegetation samples are collected approximately every 5 years. Analytical capabilities include the measurement of radionuclides at very low environmental concentrations and, in selected media, nonradiological chemicals including metals, anions, volatile organic compounds, and total organic carbon.

  18. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Friday, G. P. 54 ENVIRONMENTAL SCIENCES; SOILS; SURFACE WATERS; SEDIMENTS; ECOLOGICAL CONCENTRATION; ENVIRONMENTAL...

  19. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Citation Details In-Document Search Title: Ecological Screening Values for Surface Water, Sediment, and Soil ...

  20. Accelerated Aging of Roofing Surfaces

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Accelerated aging of roofing surfaces Hugo Destaillats, Ph.D. Lawrence Berkeley National ... H. Laboratory method mimicking natural soiling and weathering of outdoor surfaces. Ser. ...

  1. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Services » Soil and Groundwater Soil and Groundwater Soil and Groundwater Legacy soil and groundwater remediation activities at Los Alamos National Laboratory (LANL) are conducted in accordance with regulatory requirements, DOE regulations, and other applicable environmental laws. The scope of work requires investigation and remediation of contaminated sites known as solid waste management units (SWMUs) or areas of concern (AOCs). The protection of surface water and groundwater is also within

  2. Mass Transport within Soils

    SciTech Connect (OSTI)

    McKone, Thomas E.

    2009-03-01

    Contaminants in soil can impact human health and the environment through a complex web of interactions. Soils exist where the atmosphere, hydrosphere, geosphere, and biosphere converge. Soil is the thin outer zone of the earth's crust that supports rooted plants and is the product of climate and living organisms acting on rock. A true soil is a mixture of air, water, mineral, and organic components. The relative proportions of these components determine the value of the soil for agricultural and for other human uses. These proportions also determine, to a large extent, how a substance added to soil is transported and/or transformed within the soil (Spositio, 2004). In mass-balance models, soil compartments play a major role, functioning both as reservoirs and as the principal media for transport among air, vegetation, surface water, deeper soil, and ground water (Mackay, 2001). Quantifying the mass transport of chemicals within soil and between soil and atmosphere is important for understanding the role soil plays in controlling fate, transport, and exposure to multimedia pollutants. Soils are characteristically heterogeneous. A trench dug into soil typically reveals several horizontal layers having different colors and textures. As illustrated in Figure 1, these multiple layers are often divided into three major horizons: (1) the A horizon, which encompasses the root zone and contains a high concentration of organic matter; (2) the B horizon, which is unsaturated, lies below the roots of most plants, and contains a much lower organic carbon content; and (3) the C horizon, which is the unsaturated zone of weathered parent rock consisting of bedrock, alluvial material, glacial material, and/or soil of an earlier geological period. Below these three horizons lies the saturated zone - a zone that encompasses the area below ground surface in which all interconnected openings within the geologic media are completely filled with water. Similarly to the unsaturated zone

  3. Soiling of building envelope surfaces and its effect on solar reflectance – Part II: Development of an accelerated aging method for roofing materials

    SciTech Connect (OSTI)

    Sleiman, Mohamad; Kirchstetter, Thomas W.; Berdahl, Paul; Gilbert, Haley E.; Quelen, Sarah; Marlot, Lea; Preble, Chelsea V.; Chen, Sharon; Montalbano, Amandine; Rosseler, Olivier; Akbari, Hashem; Levinson, Ronnen; Destaillats, Hugo

    2014-01-09

    Highly reflective roofs can decrease the energy required for building air conditioning, help mitigate the urban heat island effect, and slow global warming. However, these benefits are diminished by soiling and weathering processes that reduce the solar reflectance of most roofing materials. Soiling results from the deposition of atmospheric particulate matter and the growth of microorganisms, each of which absorb sunlight. Weathering of materials occurs with exposure to water, sunlight, and high temperatures. This study developed an accelerated aging method that incorporates features of soiling and weathering. The method sprays a calibrated aqueous soiling mixture of dust minerals, black carbon, humic acid, and salts onto preconditioned coupons of roofing materials, then subjects the soiled coupons to cycles of ultraviolet radiation, heat and water in a commercial weatherometer. Three soiling mixtures were optimized to reproduce the site-specific solar spectral reflectance features of roofing products exposed for 3 years in a hot and humid climate (Miami, Florida); a hot and dry climate (Phoenix, Arizona); and a polluted atmosphere in a temperate climate (Cleveland, Ohio). A fourth mixture was designed to reproduce the three-site average values of solar reflectance and thermal emittance attained after 3 years of natural exposure, which the Cool Roof Rating Council (CRRC) uses to rate roofing products sold in the US. This accelerated aging method was applied to 25 products₋single ply membranes, factory and field applied coatings, tiles, modified bitumen cap sheets, and asphalt shingles₋and reproduced in 3 days the CRRC's 3-year aged values of solar reflectance. In conclusion, this accelerated aging method can be used to speed the evaluation and rating of new cool roofing materials.

  4. Field Summary Report for Remedial Investigation of Hanford Site Releases to the Columbia River, Hanford Site, Washington, Collection of Surface Water, River Sediments, and Island Soils

    SciTech Connect (OSTI)

    L. C. Hulstrom

    2009-09-28

    This report has been prepared in support of the remedial investigation of Hanford Site Releases to the Columbia River and describes the 2008/2009 data collection efforts. This report documents field activities associated with collection of sediment, river water, and soil in and adjacent to the Columbia River near the Hanford Site and in nearby tributaries.

  5. Development of Surface Complexation Models of Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, γ-Alumina, Hydrous Manganese and Ferric Oxides and Goethite

    SciTech Connect (OSTI)

    Koretsky, Carla

    2013-11-29

    Hexavalent chromium is a highly toxic contaminant that has been introduced into aquifers and shallow sediments and soils via many anthropogenic activities. Hexavalent chromium contamination is a problem or potential problem in the shallow subsurface at several DOE sites, including Hanford, Idaho National Laboratory, Los Alamos National Laboratory and the Oak Ridge Reservation (DOE, 2008). To accurately quantify the fate and transport of hexavalent chromium at DOE and other contaminated sites, robust geochemical models, capable of correctly predicting changes in chromium chemical form resulting from chemical reactions occurring in subsurface environments are needed. One important chemical reaction that may greatly impact the bioavailability and mobility of hexavalent chromium in the subsurface is chemical binding to the surfaces of particulates, termed adsorption or surface complexation. Quantitative thermodynamic surface complexation models have been derived that can correctly calculate hexavalent chromium adsorption on well-characterized materials over ranges in subsurface conditions, such pH and salinity. However, models have not yet been developed for hexavalent chromium adsorption on many important constituents of natural soils and sediments, such as clay minerals. Furthermore, most of the existing thermodynamic models have been developed for relatively simple, single solid systems and have rarely been tested for the complex mixtures of solids present in real sediments and soils. In this study, the adsorption of hexavalent chromium was measured as a function of pH (3-10), salinity (0.001 to 0.1 M NaNO3), and partial pressure of carbon dioxide(0-5%) on a suite of naturally-occurring solids including goethite (FeOOH), hydrous manganese oxide (MnOOH), hydrous ferric oxide (Fe(OH)3), γ-alumina (Al2O3), kaolinite (Al2Si2O5(OH)4), and montmorillonite (Na3(Al, Mg)2Si4O10(OH)2-nH2O). The results show that all of these materials can bind substantial quantities of

  6. ARM - Measurement - Soil characteristics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    characteristics ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil characteristics Includes available water capacity, bulk density, permeability, porosity, rock fragment classification, rock fragment volume, percent clay, percent sand, and texture classification Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer

  7. ARM - Measurement - Soil moisture flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    moisture flux ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil moisture flux A quantity measured according to the formula B = {lambda}(dq/dz), where {lambda} is the conductivity of the soil that the moisture is moving through. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file

  8. Detection of explosives in soils

    DOE Patents [OSTI]

    Chambers, William B.; Rodacy, Philip J.; Phelan, James M.; Woodfin, Ronald L.

    2002-01-01

    An apparatus and method for detecting explosive-indicating compounds in subsurface soil. The apparatus has a probe with an adsorbent material on some portion of its surface that can be placed into soil beneath the ground surface, where the adsorbent material can adsorb at least one explosive-indicating compound. The apparatus additional has the capability to desorb the explosive-indicating compound through heating or solvent extraction. A diagnostic instrument attached to the probe detects the desorbed explosive-indicating compound. In the method for detecting explosive-indicating compounds in soil, the sampling probe with an adsorbent material on at least some portion of a surface of the sampling probe is inserted into the soil to contact the adsorbent material with the soil. The explosive-indicating compounds are then desorbed and transferred as either a liquid or gas sample to a diagnostic tool for analysis. The resulting gas or liquid sample is analyzed using at least one diagnostic tool selected from the group consisting of an ion-mobility spectrometer, a gas chromatograph, a high performance liquid chromatograph, a capillary electrophoresis chromatograph, a mass spectrometer, a Fourier-transform infrared spectrometer and a Raman spectrometer to detect the presence of explosive-indicating compounds.

  9. 100 Area soil washing: Bench scale tests on 116-F-4 pluto crib soil

    SciTech Connect (OSTI)

    Field, J.G.

    1994-06-10

    The Pacific Northwest Laboratory conducted a bench-scale treatability study on a pluto crib soil sample from 100 Area of the Hanford Site. The objective of this study was to evaluate the use of physical separation (wet sieving), treatment processes (attrition scrubbing, and autogenous surface grinding), and chemical extraction methods as a means of separating radioactively-contaminated soil fractions from uncontaminated soil fractions. The soil washing treatability study was conducted on a soil sample from the 116-F-4 Pluto Crib that had been dug up as part of an excavation treatability study. Trace element analyses of this soil showed no elevated concentrations above typically uncontaminated soil background levels. Data on the distribution of radionuclide in various size fractions indicated that the soil-washing tests should be focused on the gravel and sand fractions of the 116-F-4 soil. The radionuclide data also showed that {sup 137}Cs was the only contaminant in this soil that exceeded the test performance goal (TPG). Therefore, the effectiveness of subsequent soil-washing tests for 116-F-4 soil was evaluated on the basis of activity attenuation of {sup 137}Cs in the gravel- and sand-size fractions.

  10. Arsenic distribution in soils surrounding the Utah copper smelter

    SciTech Connect (OSTI)

    Ball, A.L.; Rom, W.N.; Glenne, B.

    1983-05-01

    We investigated the extent of arsenic contamination from a Utah copper smelter as reflected by arsenic residue accumulated in the surface soil. The highest arsenic concentrations occurred within 3 km of the smelter. Arsenic soil contamination was evident up to 10 km from the smelter, with the major transport direction being ESE. Data from the subsurface soil samples indicated that arsenic has also leached through the soil.

  11. Heavy metal movement in metal-contaminated soil profiles

    SciTech Connect (OSTI)

    Li, Zhenbin; Shuman, L.M.

    1996-10-01

    Heavy metal movement in soil profiles is a major environmental concern because even slow transport through the soil may eventually lead to deterioration of groundwater quality. In this study, three metal-contaminated soil (Fuquay, Dothan, and Clarendon) were selected from cropland were a high-metal flue dust had been applied annually for 6 years to raise soil pH, with application ending 4 years before sampling. One uncontaminated soil (Tifton) from the same physiographic area was also sampled as a control. Soil samples were collected in 15-cm increments from the surface to 105 cm in depth. Total contents of Zn, Cd, and Pb in the soils samples were determined. To better understand metal movement in relation to metal fractions in the soil profile, soil samples were also extracted sequentially for exchangeable (EXC), organic matter (OM), Mn oxide (MNO), amorphous Fe oxide (AFEO), crystalline Fe oxide (CFEO), and residual (RES) fractions. 35 refs., 6 figs., 2 tabs.

  12. ARM - Measurement - Soil heat flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    heat flux ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil heat flux A quantity measured according to the formula B = {lambda}(dT/dz), where {lambda} is the conductivity of the soil that the heat is moving through. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  13. AX Tank farm closure settlement estimates and soil testing

    SciTech Connect (OSTI)

    BECKER, D.L.

    1999-03-25

    This study provides a conservative three-dimensional settlement study of the AX Tank Farm closure with fill materials and a surface barrier. The finite element settlement model constructed included the interaction of four tanks and the surface barrier with the site soil and bedrock. Also addressed are current soil testing techniques suitable for the site soil with recommendations applicable to the AX Tank Farm and the planned cone penetration testing.

  14. Soils | Open Energy Information

    Open Energy Info (EERE)

    Soils Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleSoils&oldid612253" Feedback Contact needs updating Image needs updating Reference...

  15. Thermal properties of soils and soils testing

    SciTech Connect (OSTI)

    Not Available

    1981-02-17

    The thermal properties of soils are reviewed with reference to the use of soils as heat sources, heat sinks, or thermal storage. Specific heat and thermal conductivity are discussed. (ACR)

  16. Monitoring Soil Erosion on a Burned Site in the Mojave-Great Basin Transition Zone: Final Report for the Jacob Fire Site

    SciTech Connect (OSTI)

    Miller, Julianne; Etyemezian, Vic; Cablk, Mary E.; Shillito, Rose; Shafer, David

    2013-06-01

    A historic return interval of 100 years for large fires in the U.S. southwestern deserts is being replaced by one where fires may reoccur as frequently as every 20 to 30 years. The shortened return interval, which translates to an increase in fires, has implications for management of Soil Corrective Action Units (CAUs) and Corrective Action Sites (CASs) for which the Department of Energy, National Nuclear Security Administration Nevada Field Office has responsibility. A series of studies was initiated at uncontaminated analog sites to better understand the possible impacts of erosion and transport by wind and water should contaminated soil sites burn. The first of these studies was undertaken at the Jacob Fire site approximately 12 kilometers (7.5 miles) north of Hiko, Nevada. A lightning-caused fire burned approximately 200 hectares during August 6-8, 2008. The site is representative of a transition between Mojave and Great Basin desert ecoregions on the Nevada National Security Site (NNSS), where the largest number of Soil CAUs/CASs are located. The area that burned at the Jacob Fire site was primarily a Coleogyne ramosissima (blackbrush) and Ephedra nevadensis (Mormon tea) community, also an abundant shrub assemblage in the similar transition zone on the NNSS. This report summarizes three years of measurements after the fire. Seven measurement campaigns at the Jacob Fire site were completed. Measurements were made on burned ridge (upland) and drainage sites, and on burned and unburned sites beneath and between vegetation. A Portable In-Situ Wind Erosion Lab (PI-SWERL) was used to estimate emissions of suspended particles at different wind speeds. Context for these measurements was provided through a meteorological tower that was installed at the Jacob Fire site to obtain local, relevant environmental parameters. Filter samples, collected from the exhaust of the PI-SWERL during measurements, were analyzed for chemical composition. Runoff and water erosion were

  17. Surface Energy Balance System (SEBS) Handbook (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    The surface energy balance system consists of upwelling and downwelling solar and infrared radiometers within one net radiometer, a wetness sensor, and soil measurements. The SEBS ...

  18. Assessment of produced water contaminated soils to determine remediation requirements

    SciTech Connect (OSTI)

    Clodfelter, C.

    1995-12-31

    Produced water and drilling fluids can impact the agricultural properties of soil and result in potential regulatory and legal liabilities. Produced water typically is classified as saline or a brine and affects surface soils by increasing the sodium and chloride content. Sources of produced water which can lead to problems include spills from flowlines and tank batteries, permitted surface water discharges and pit areas, particularly the larger pits including reserve pits, emergency pits and saltwater disposal pits. Methods to assess produced water spills include soil sampling with various chemical analyses and surface geophysical methods. A variety of laboratory analytical methods are available for soil assessment which include electrical conductivity, sodium adsorption ratio, cation exchange capacity, exchangeable sodium percent and others. Limiting the list of analytical parameters to reduce cost and still obtain the data necessary to assess the extent of contamination and determine remediation requirements can be difficult. The advantage to using analytical techniques is that often regulatory remediation standards are tied to soil properties determined from laboratory analysis. Surface geophysical techniques can be an inexpensive method to rapidly determine the extent and relative magnitude of saline soils. Data interpretations can also provide an indication of the horizontal as well as the vertical extent of impacted soils. The following discussion focuses on produced water spills on soil and assessment of the impacted soil. Produced water typically contains dissolved hydrocarbons which are not addressed in this discussion.

  19. VARIATION IN EROSION/DEPOSITION RATES OVER THE LAST FIFTTY YEARS ON ALLUVIAL FAN SURFACES OF L. PLEISTOCENE-MID HOLOCENE AGE, ESTIMATIONS USING 137CS SOIL PROFILE DATA, AMARGOSA VALLEY, NEVADA

    SciTech Connect (OSTI)

    C. Harrington; R. Kelly; K.T. Ebert

    2005-08-26

    Variations in erosion and deposition for the last fifty years (based on estimates from 137Cs profiles) on surfaces (Late Pleistocene to Late Holocene in age) making up the Fortymile Wash alluvial fan south of Yucca Mountain, is a function of surface age and of desert pavement development or absence. For purposes of comparing erosion and deposition, the surfaces can be examined as three groups: (1) Late Pleistocene surfaces possess areas of desert pavement development with thin Av or sandy A horizons, formed by the trapping capabilities of the pavements. These zones of deposition are complemented by coppice dune formation on similar parts of the surface. Areas on the surface where no pavement development has occurred are erosional in nature with 0.0 +/- 0.0 cm to 1.5 +/- 0.5 cm of erosion occurring primarily by winds blowing across the surface. Overall these surfaces may show either a small net depositional gain or small erosional loss. (2) Early Holocene surfaces have no well-developed desert pavements, but may have residual gravel deposits in small areas on the surfaces. These surfaces show the most consistent erosional surface areas on which it ranges from 1.0 +/-.01 cm to 2.0+/- .01 cm. Fewer depositional forms are found on this age of surface so there is probably a net loss of 1.5 cm across these surfaces. (3) The Late Holocene surfaces show the greatest variability in erosion and deposition. Overbank deposition during floods cover many edges of these surfaces and coppice dune formation also creates depositional features. Erosion rates are highly variable and range from 0.0 +/- 0.0 to a maximum of 2.0+/-.01. Erosion occurs because of the lack of protection of the surface. However, the common areas of deposition probably result in the surface having a small net depositional gain across these surfaces. Thus, the interchannel surfaces of the Fortymile Wash fan show a variety of erosional styles as well as areas of deposition. The fan, therefore, is a dynamic

  20. Soil washing technology evaluation

    SciTech Connect (OSTI)

    Suer, A.

    1995-04-01

    Environmental Restoration Engineering (ERE) continues to review innovative, efficient, and cost effective technologies for SRS soil and/or groundwater remediation. As part of this effort, this technical evaluation provides review and the latest information on the technology for SRS soil remediation. Additional technology evaluation reports will be issued periodically to update these reports. The purpose of this report is to review the soil washing technology and its potential application to SRS soil remediation. To assess whether the Soil Washing technology is a viable option for SRS soil remediation, it is necessary to review the technology/process, technology advantages/limitations, performance, applications, and cost analysis.

  1. Exfiltrometer apparatus and method for measuring unsaturated hydrologic properties in soil

    DOE Patents [OSTI]

    Hubbell, Joel M.; Sisson, James B.; Schafer, Annette L.

    2006-01-17

    Exfiltrometer apparatus includes a container for holding soil. A sample container for holding sample soil is positionable with respect to the container so that the sample soil contained in the sample container is in communication with soil contained in the container. A first tensiometer operatively associated with the sample container senses a surface water potential at about a surface of the sample soil contained in the sample container. A second tensiometer operatively associated with the sample container senses a first subsurface water potential below the surface of the sample soil. A water content sensor operatively associated with the sample container senses a water content in the sample soil. A water supply supplies water to the sample soil. A data logger operatively connected to the first and second tensiometers, and to the water content sensor receives and processes data provided by the first and second tensiometers and by the water content sensor.

  2. ARM - Datastreams - soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamssoil Documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : SOIL ABLE: soil temperature, moisture, heat flow, 30-min avg Active Dates 1999.05.23 - 2004.04.01 Originating Instrument Soil Measurement from the SGP (SOIL) Measurements The measurements below provided by this product are those considered scientifically relevant. Measurement Variable Locations Southern

  3. Effect of soiling in CPV systems

    SciTech Connect (OSTI)

    Vivar, M.; Herrero, R.; Anton, I.; Martinez-Moreno, F.; Moreton, R.; Sala, G.

    2010-07-15

    The effect of soiling in flat PV modules has been already studied, causing a reduction of the electrical output of 4% on average. For CPV's, as far as soiling produces light scattering at the optical collector surface, the scattered rays should be definitively lost because they cannot be focused onto the receivers again. While the theoretical study becomes difficult because soiling is variable at different sites, it becomes easier to begin the monitoring of the real field performance of concentrators and then raise the following question: how much does the soiling affect to PV concentrators in comparison with flat panels?' The answers allow to predict the PV concentrator electrical performance and to establish a pattern of cleaning frequency. Some experiments have been conducted at the IES-UPM and CSES-ANU sites, consisting in linear reflective concentration systems, a point focus refractive concentrator and a flat module. All the systems have been measured when soiled and then after cleaning, achieving different increases of I{sub SC}. In general, results show that CPV systems are more sensitive to soiling than flat panels, accumulating losses in I{sub SC} of about 14% on average in three different tests conducted at IES-UPM and CSES-ANU test sites in Madrid (Spain) and Canberra (Australia). Some concentrators can reach losses up to 26% when the system is soiled for 4 months of exposure. (author)

  4. The Unified North American Soil Map and Its Implication on the Soil Organic Carbon Stock in North America

    SciTech Connect (OSTI)

    Liu, Shishi; Wei, Yaxing; Post, Wilfred M; Cook, Robert B; Schaefer, Kevin; Thornton, Michele M

    2013-01-01

    The Unified North American Soil Map (UNASM) was developed to provide more accurate regional soil information for terrestrial biosphere modeling. The UNASM combines information from state-of-the-art U.S. STATSGO2 and Soil Landscape of Canada (SLCs) databases. The area not covered by these datasets is filled with the Harmonized World Soil Database version 1.1 (HWSD1.1). The UNASM contains maximum soil depth derived from the data source as well as seven soil attributes (including sand, silt, and clay content, gravel content, organic carbon content, pH, and bulk density) for the top soil layer (0-30 cm) and the sub soil layer (30-100 cm) respectively, of the spatial resolution of 0.25 degrees in latitude and longitude. There are pronounced differences in the spatial distributions of soil properties and soil organic carbon between UNASM and HWSD, but the UNASM overall provides more detailed and higher-quality information particularly in Alaska and central Canada. To provide more accurate and up-to-date estimate of soil organic carbon stock in North America, we incorporated Northern Circumpolar Soil Carbon Database (NCSCD) into the UNASM. The estimate of total soil organic carbon mass in the upper 100 cm soil profile based on the improved UNASM is 347.70 Pg, of which 24.7% is under trees, 14.2% is under shrubs, and 1.3% is under grasses and 3.8% under crops. This UNASM data will provide a resource for use in land surface and terrestrial biogeochemistry modeling both for input of soil characteristics and for benchmarking model output.

  5. Percolation behavior of tritiated water into a soil packed bed

    SciTech Connect (OSTI)

    Honda, T.; Katayama, K.; Uehara, K.; Fukada, S.; Takeishi, T.

    2015-03-15

    A large amount of cooling water is used in a D-T fusion reactor. The cooling water will contain tritium with high concentration because tritium can permeate metal walls at high temperature easily. A development of tritium handling technology for confining tritiated water in the fusion facility is an important issue. In addition, it is also important to understand tritium behavior in environment assuming severe accidents. In this study, percolation experiments of tritiated water in soil packed bed were carried out and tritium behavior in soil was discussed. Six soil samples were collected in Hakozaki campus of Kyushu University. These particle densities were of the same degree as that of general soils and moisture contents were related to BET surface area. For two soil samples used in the percolation experiment of tritiated water, saturated hydraulic conductivity agreed well with the estimating value by Creager. Tritium retention ratio in the soil packed bed was larger than water retention. This is considered to be due to an effect of tritium sorption on the surface of soil particles. The isotope exchange capacity estimated by assuming that H/T ratio of supplied tritiated water and H/T ratio of surface water of soil particle was equal was comparable to that on cement paste and mortar which were obtained by exposure of tritiated water vapor. (authors)

  6. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    SciTech Connect (OSTI)

    Margaret Torn

    2015-01-14

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  7. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Margaret Torn

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  8. Missing links in the root-soil organic matter continuum

    SciTech Connect (OSTI)

    O'Brien, Sarah L.; Iversen, Colleen M

    2009-01-01

    The soil environment remains one of the most complex and poorly understood research frontiers in ecology. Soil organic matter (SOM), which spans a continuum from fresh detritus to highly processed, mineral-associated organic matter, is the foundation of sustainable terrestrial ecosystems. Heterogeneous SOM pools are fueled by inputs from living and dead plants, driven by the activity of micro- and mesofauna, and are shaped by a multitude of abiotic factors. The specialization required to measure unseen processes that occur on a wide range of spatial and temporal scales has led to the partitioning of soil ecology research across several disciplines. In the organized oral session 'Missing links in the root-soil organic matter continuum' at the annual Ecological Society of America meeting in Albuquerque, NM, USA, we joined the call for greater communication and collaboration among ecologists who work at the root-soil interface (e.g. Coleman, 2008). Our goal was to bridge the gap between scientific disciplines and to synthesize disconnected pieces of knowledge from root-centric and soil-centric studies into an integrated understanding of belowground ecosystem processes. We focused this report around three compelling themes that arose from the session: (1) the influence of the rhizosphere on SOM cycling, (2) the role of soil heterotrophs in driving the transformation of root detritus to SOM, and (3) the controlling influence of the soil environment on SOM dynamics. We conclude with a discussion of new approaches for gathering data to bridge gaps in the root-SOM continuum and to inform the next generation of ecosystem models. Although leaf litter has often been considered to be the main source of organic inputs to soil, Ann Russell synthesized a convincing body of work demonstrating that roots, rather than surface residues, control the accumulation of SOM in a variety of ecosystems. Living roots, which are chemically diverse and highly dynamic, also influence a wide

  9. Chemical-Specific Representation of Air-Soil Exchange and Soil Penetration in Regional Multimedia Models

    SciTech Connect (OSTI)

    McKone, T.E.; Bennett, D.H.

    2002-08-01

    In multimedia mass-balance models, the soil compartment is an important sink as well as a conduit for transfers to vegetation and shallow groundwater. Here a novel approach for constructing soil transport algorithms for multimedia fate models is developed and evaluated. The resulting algorithms account for diffusion in gas and liquid components; advection in gas, liquid, or solid phases; and multiple transformation processes. They also provide an explicit quantification of the characteristic soil penetration depth. We construct a compartment model using three and four soil layers to replicate with high reliability the flux and mass distribution obtained from the exact analytical solution describing the transient dispersion, advection, and transformation of chemicals in soil with fixed properties and boundary conditions. Unlike the analytical solution, which requires fixed boundary conditions, the soil compartment algorithms can be dynamically linked to other compartments (air, vegetation, ground water, surface water) in multimedia fate models. We demonstrate and evaluate the performance of the algorithms in a model with applications to benzene, benzo(a)pyrene, MTBE, TCDD, and tritium.

  10. Soil bacterial and fungal community responses to nitrogen addition across soil depth and microhabitat in an arid shrubland

    SciTech Connect (OSTI)

    Mueller, Rebecca C.; Belnap, Jayne; Kuske, Cheryl R.

    2015-09-04

    Arid shrublands are stressful environments, typified by alkaline soils low in organic matter, with biologically-limiting extremes in water availability, temperature, and UV radiation. The widely-spaced plants and interspace biological soil crusts in these regions provide soil nutrients in a localized fashion, creating a mosaic pattern of plant- or crust-associated microhabitats with distinct nutrient composition. With sporadic and limited rainfall, nutrients are primarily retained in the shallow surface soil, patterning biological activity. We examined soil bacterial and fungal community responses to simulated nitrogen (N) deposition in an arid Larrea tridentata-Ambrosia dumosa field experiment in southern Nevada, USA, using high-throughput sequencing of ribosomal RNA genes. To examine potential interactions among the N application, microhabitat and soil depth, we sampled soils associated with shrub canopies and interspace biological crusts at two soil depths (0–0.5 or 0–10 cm) across the N-amendment gradient (0, 7, and 15 kg ha–1 yr–1). We hypothesized that localized compositional differences in soil microbiota would constrain the impacts of N addition to a microhabitat distribution that would reflect highly localized geochemical conditions and microbial community composition. The richness and community composition of both bacterial and fungal communities differed significantly by microhabitat and with soil depth in each microhabitat. Only bacterial communities exhibited significant responses to the N addition. Community composition correlated with microhabitat and depth differences in soil geochemical features. Provided the distinct roles of soil bacteria and fungi in major nutrient cycles, the resilience of fungi and sensitivity of bacteria to N amendments suggests that increased N input predicted for many arid ecosystems could shift nutrient cycling toward pathways driven primarily by fungal communities.

  11. Soil bacterial and fungal community responses to nitrogen addition across soil depth and microhabitat in an arid shrubland

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mueller, Rebecca C.; Belnap, Jayne; Kuske, Cheryl R.

    2015-09-04

    Arid shrublands are stressful environments, typified by alkaline soils low in organic matter, with biologically-limiting extremes in water availability, temperature, and UV radiation. The widely-spaced plants and interspace biological soil crusts in these regions provide soil nutrients in a localized fashion, creating a mosaic pattern of plant- or crust-associated microhabitats with distinct nutrient composition. With sporadic and limited rainfall, nutrients are primarily retained in the shallow surface soil, patterning biological activity. We examined soil bacterial and fungal community responses to simulated nitrogen (N) deposition in an arid Larrea tridentata-Ambrosia dumosa field experiment in southern Nevada, USA, using high-throughput sequencing ofmore » ribosomal RNA genes. To examine potential interactions among the N application, microhabitat and soil depth, we sampled soils associated with shrub canopies and interspace biological crusts at two soil depths (0–0.5 or 0–10 cm) across the N-amendment gradient (0, 7, and 15 kg ha–1 yr–1). We hypothesized that localized compositional differences in soil microbiota would constrain the impacts of N addition to a microhabitat distribution that would reflect highly localized geochemical conditions and microbial community composition. The richness and community composition of both bacterial and fungal communities differed significantly by microhabitat and with soil depth in each microhabitat. Only bacterial communities exhibited significant responses to the N addition. Community composition correlated with microhabitat and depth differences in soil geochemical features. Provided the distinct roles of soil bacteria and fungi in major nutrient cycles, the resilience of fungi and sensitivity of bacteria to N amendments suggests that increased N input predicted for many arid ecosystems could shift nutrient cycling toward pathways driven primarily by fungal communities.« less

  12. Microsoft Word - S06584StSoil.doc

    Office of Legacy Management (LM)

    University of Arizona Letter This page intentionally left blank December 17, 2009 Memo to: Jody Waugh Regarding: Uranium in Former Evaporation Pond Area at Monument Valley We analyzed the stained surface soils in the former evaporation pond area and extended field west in the subpile soil area for a suite of heavy metals to determine if potential toxic substances were associated with the chemical stains observed in some areas of the site. This was part of Task 6, Mn Toxicity Field Study. Our

  13. ARM - Evaluation Product - Oklahoma Mesonet Soil Moisture Product

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsOklahoma Mesonet Soil Moisture Product ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file level. Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : Oklahoma Mesonet Soil Moisture Product [ ARM research - evaluation data product ] Land surface and subsurface states (e.g., soil moisture) are critical for analyses of land-atmospheric interactions in climate

  14. Automated soil gas monitoring chamber

    DOE Patents [OSTI]

    Edwards, Nelson T.; Riggs, Jeffery S.

    2003-07-29

    A chamber for trapping soil gases as they evolve from the soil without disturbance to the soil and to the natural microclimate within the chamber has been invented. The chamber opens between measurements and therefore does not alter the metabolic processes that influence soil gas efflux rates. A multiple chamber system provides for repetitive multi-point sampling, undisturbed metabolic soil processes between sampling, and an essentially airtight sampling chamber operating at ambient pressure.

  15. Superhydrophobic surfaces

    DOE Patents [OSTI]

    Wang, Evelyn N; McCarthy, Matthew; Enright, Ryan; Culver, James N; Gerasopoulos, Konstantinos; Ghodssi, Reza

    2015-03-24

    Surfaces having a hierarchical structure--having features of both microscale and nanoscale dimensions--can exhibit superhydrophobic properties and advantageous condensation and heat transfer properties. The hierarchical surfaces can be fabricated using biological nanostructures, such as viruses as a self-assembled nanoscale template.

  16. Airborne soil organic particles generated by precipitation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Bingbing; Harder, Tristan H.; Kelly, Stephen T.; Piens, Dominique S.; China, Swarup; Kovarik, Libor; Keiluweit, Marco; Arey, Bruce W.; Gilles, Mary K.; Laskin, Alexander

    2016-05-02

    Airborne organic particles play a critical role in Earth’s climate1, public health2, air quality3, and hydrological and carbon cycles4. However, sources and formation mechanisms for semi-solid and solid organic particles5 are poorly understood and typically neglected in atmospheric models6. Laboratory evidence suggests that fine particles can be formed from impaction of mineral surfaces by droplets7. Here, we use chemical imaging of particles collected following rain events in the Southern Great Plains, Oklahoma, USA and after experimental irrigation to show that raindrop impaction of soils generates solid organic particles. We find that after rain events, sub-micrometre solid particles, with a chemicalmore » composition consistent with soil organic matter, contributed up to 60% of atmospheric particles. Our irrigation experiments indicate that intensive water impaction is sufficient to cause ejection of airborne soil organic particles from the soil surface. Chemical imaging and micro-spectroscopy analysis of particle physico-chemical properties suggest that these particles may have important impacts on cloud formation and efficiently absorb solar radiation. Lastly, we suggest that raindrop-induced formation of solid organic particles from soils may be a widespread phenomenon in ecosystems such as agricultural systems and grasslands where soils are exposed to strong, episodic precipitation events8.« less

  17. Strontium Sorption onto SRP Soils

    SciTech Connect (OSTI)

    Hoeffner, S.L.

    2001-07-02

    This report discusses the effect of water and soil quality variables on the sorption of strontium onto SRP soils. The variables cover the range of conditions observed in the low-level waste burial ground.

  18. Fernald Environmental Management Project Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Fernald Environmental Management Project Archived Soil & Groundwater Master Reports Fernald Environmental Management Project Archived Soil & Groundwater Master Reports Fernald ...

  19. Miamisburg Environmental Management Project Archived Soil & Groundwate...

    Office of Environmental Management (EM)

    Miamisburg Environmental Management Project Archived Soil & Groundwater Master Reports Miamisburg Environmental Management Project Archived Soil & Groundwater Master Reports ...

  20. Weathering controls on mechanisms of carbon storage in grassland soils

    SciTech Connect (OSTI)

    Masiello, C.A.; Chadwick, O.A.; Southon, J.; Torn, M.S.; Harden, J.W.

    2004-09-01

    On a sequence of soils developed under similar vegetation, temperature, and precipitation conditions, but with variations in mineralogical properties, we use organic carbon and 14C inventories to examine mineral protection of soil organic carbon. In these soils, 14C data indicate that the creation of slow-cycling carbon can be modeled as occurring through reaction of organic ligands with Al3+ and Fe3+ cations in the upper horizons, followed by sorption to amorphous inorganic Al compounds at depth. Only one of these processes, the chelation of Al3+ and Fe3+ by organic ligands, is linked to large carbon stocks. Organic ligands stabilized by this process traverse the soil column as dissolved organic carbon (both from surface horizons and root exudates). At our moist grassland site, this chelation and transport process is very strongly correlated with the storage and long-term stabilization of soil organic carbon. Our 14C results show that the mechanisms of organic carbon transport and storage at this site follow a classic model previously believed to only be significant in a single soil order (Spodosols), and closely related to the presence of forests. The presence of this process in the grassland Alfisol, Inceptisol, and Mollisol soils of this chronosequence suggests that this process is a more significant control on organic carbon storage than previously thought.

  1. Permafrost carbon—climate feedback is sensitive to deep soil carbon decomposability but not deep soil nitrogen dynamics

    SciTech Connect (OSTI)

    Koven, Charles D.; Lawrence, David M.; Riley, William J.

    2015-03-09

    Permafrost soils contain enormous amounts of organic carbon whose stability is contingent on remaining frozen. With future warming, these soils may release carbon to the atmosphere and act as a positive feedback to climate change. Significant uncertainty remains on the postthaw carbon dynamics of permafrost-affected ecosystems, in particular since most of the carbon resides at depth where decomposition dynamics may differ from surface soils, and since nitrogen mineralized by decomposition may enhance plant growth. Here we show, using a carbon–nitrogen model that includes permafrost processes forced in an unmitigated warming scenario, that the future carbon balance of the permafrost region is highly sensitive to the decomposability of deeper carbon, with the net balance ranging from 21 Pg C to 164 Pg C losses by 2300. Increased soil nitrogen mineralization reduces nutrient limitations, but the impact of deep nitrogen on the carbon budget is small due to enhanced nitrogen availability from warming surface soils and seasonal asynchrony between deeper nitrogen availability and plant nitrogen demands. The future carbon balance of this region is projected to hinge more on the rate and extent of permafrost thaw and soil decomposition than on enhanced nitrogen availability for vegetation growth resulting from permafrost thaw.

  2. Permafrost carbon—climate feedback is sensitive to deep soil carbon decomposability but not deep soil nitrogen dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Koven, Charles D.; Lawrence, David M.; Riley, William J.

    2015-03-09

    Permafrost soils contain enormous amounts of organic carbon whose stability is contingent on remaining frozen. With future warming, these soils may release carbon to the atmosphere and act as a positive feedback to climate change. Significant uncertainty remains on the postthaw carbon dynamics of permafrost-affected ecosystems, in particular since most of the carbon resides at depth where decomposition dynamics may differ from surface soils, and since nitrogen mineralized by decomposition may enhance plant growth. Here we show, using a carbon–nitrogen model that includes permafrost processes forced in an unmitigated warming scenario, that the future carbon balance of the permafrost regionmore » is highly sensitive to the decomposability of deeper carbon, with the net balance ranging from 21 Pg C to 164 Pg C losses by 2300. Increased soil nitrogen mineralization reduces nutrient limitations, but the impact of deep nitrogen on the carbon budget is small due to enhanced nitrogen availability from warming surface soils and seasonal asynchrony between deeper nitrogen availability and plant nitrogen demands. The future carbon balance of this region is projected to hinge more on the rate and extent of permafrost thaw and soil decomposition than on enhanced nitrogen availability for vegetation growth resulting from permafrost thaw.« less

  3. Underground barrier construction apparatus with soil-retaining shield

    DOE Patents [OSTI]

    Gardner, B.M.; Smith, A.M.; Hanson, R.W.; Hodges, R.T.

    1998-08-04

    An apparatus is described for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment. 17 figs.

  4. Underground barrier construction apparatus with soil-retaining shield

    DOE Patents [OSTI]

    Gardner, Bradley M.; Smith, Ann Marie; Hanson, Richard W.; Hodges, Richard T.

    1998-01-01

    An apparatus for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment.

  5. Physico-chemical and Bio-chemical Controls on Soil C Saturation Behavior

    SciTech Connect (OSTI)

    Six, Johan; Plante, Alain

    2011-06-02

    In this project, we tested through a multitude of lab and field experiments the concept of soil C stabilization and determined metrics for the level of C saturation across soils and soil organic matter fractions. The basic premise of the soil C saturation concept is that there is a maximum amount of C that can be stabilized within a soil, even when C input is further increased. In a first analysis, our results showed that linear regression models do not adequately predict maximal organic C stabilization by fine soil particles. Soil physical and chemical properties associated with soil clay mineralogy, such as specific surface area and organic C loading, should be incorporated into models for predicting maximal organic C stabilization. In a second analysis, we found significantly greater maximal C stabilization in the microaggregate-protected versus the non-microaggregate protected mineral fractions, which provides independent validation that microaggregation plays an important role in increasing the protection and stabilization of soil C leading to greater total soil C accumulation in these pools. In a third study, our results question the role of biochemical preference in mineral C stabilization and of the chemical recalcitrance of specific plant-derived compounds in non-protected soil C accumulation. Because C biochemical composition of slowly turning over mineral protected C pools does not change with C saturation, input C composition is unlikely to affect long-term C stabilization. Rather, C saturation and stabilization in soil is controlled only by the quantity of C input to the soil and the physical and chemical protection mechanisms at play in long-term C stabilization. In conclusion, we have further corroborated the concept of soil C saturation and elucidated several mechanisms underlying this soil C saturation.

  6. The use of stable isotopes to evaluate selective extraction techniques for solid phase metal speciation in contaminated soils

    SciTech Connect (OSTI)

    Weiss, A.D.; Gintautas, P.A.; Piwoni, M.D.

    1994-12-31

    The present study attempts to answer some of the problems associated with sequential extraction techniques and is an attempt to find a means of validation. Model soils consisting of individual soil phases (i.e. carbonates, iron oxides and clays) spiked with enriched stable isotopes of Cd were prepared. Each soil phase is spiked with a specific isotope of Cd and then combined to make model soil systems. The individual phases were characterized using various surface techniques. The model systems were subjected to sequential extractions similar to those proposed by Tessier et al. in which five soil phases are targeted. Cadmium isotopic analysis of the extracts was performed using an ICP-MS. Results indicate that sequential extraction techniques for metal speciation in soils is highly dependent upon the soil type. If the extraction is properly tailored to the soil type, one can obtain recoveries approaching 90% specificity and efficiency. These experiments provide a potentially unambiguous test of partial extraction metal speciation methods.

  7. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2015-02-05

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region's soil organic carbon (SOC) stocks to changing climatic conditions. Inmore » this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of organic carbon stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this organic carbon to permafrost thaw under a warming climate. Overall, frozen conditions and cryopedogenic processes, such as cryoturbation, have slowed decomposition and enhanced the sequestration of organic carbon in permafrost-affected soils over millennial timescales. Due to the low temperatures, the organic matter in permafrost soils is often less humified than in more temperate soils, making some portion of this stored organic carbon relatively vulnerable to mineralization upon thawing of permafrost.« less

  8. Soiling of building envelope surfaces and its effect on solar...

    Office of Scientific and Technical Information (OSTI)

    Subject: 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE Word Cloud ...

  9. Soiling of building envelope surfaces and its effect on solar...

    Office of Scientific and Technical Information (OSTI)

    air conditioning, help mitigate the urban heat island effect, and slow global warming. ... Weathering of materials occurs with exposure to water, sunlight, and high temperatures. ...

  10. Bacteria increase arid-land soil surface temperature through...

    Office of Scientific and Technical Information (OSTI)

    ... During the process, overall microbial biomass increases steadily, and eventually the ... a as a proxy of photosynthetic biomass), which increased across the gradient ...

  11. FRACTURE ENHANCED SOIL VAPOR EXTRACTION TECHNOLOGY DEMONSTRATION AT THE A-014 OUTFALL

    SciTech Connect (OSTI)

    Riha, B; Warren Hyde, W; Richard Hall , R

    2008-03-12

    Data collected during this study show that the performance of hydraulically fractured wells (with respect to mass removal rates) may tend to decrease with time following precipitation events. These effects are due to temporary increases in water saturation in the formation within the vicinity of the fractures, therefore, the wells should tend to rebound during subsequent dry periods. The data available for fractured well versus conventional well performance (with respect to flow rate versus vacuum pressure) are limited in this study. However, the data that we have to draw from suggest that, with the possible exception of a few extreme examples, hydraulically fractured wells tend to perform better than conventional wells during soil vapor extraction (SVE) operation at the A-14 Outfall. The pancake like geometry associated with hydraulic fractures also leads to a significant increase in zone of influence (ZOI), as compared to conventional wells. The increase in ZOI is due to the radially extending, horizontal, high-permeability conduit nature of the hydraulic fracture, however, air-flow into the fracture is predominately vertical (occurring at right angles to the fracture plane). Flow rates from above and below the fracture will tend to be equivalent when the formation is homogeneous, however, in the case of directionally fining depositional sequences flow rates will be greater from the direction of increasing permeability. The Upland Unit is a fining upward sequence, therefore flow rates (and contaminant mass flow rates) will tend to be higher below the fracture. This suggests that emplacing the fractures slightly above the source zone is an important strategy for accelerating contaminant removal at the A-014 Outfall site and in the Upland Unit at the SRS. However, due to the multitude of previous borings at the A-014 Outfall site, the shallower fractures failed. More than 2500 lbs of chlorinated volatile organic compounds (cVOCs) were removed during approximately 6

  12. Pneumatic soil removal tool

    DOE Patents [OSTI]

    Neuhaus, J.E.

    1992-10-13

    A soil removal tool is provided for removing radioactive soil, rock and other debris from the bottom of an excavation, while permitting the operator to be located outside of a containment for that excavation. The tool includes a fixed jaw, secured to one end of an elongate pipe, which cooperates with a movable jaw pivotably mounted on the pipe. Movement of the movable jaw is controlled by a pneumatic cylinder mounted on the pipe. The actuator rod of the pneumatic cylinder is connected to a collar which is slidably mounted on the pipe and forms part of the pivotable mounting assembly for the movable jaw. Air is supplied to the pneumatic cylinder through a handle connected to the pipe, under the control of an actuator valve mounted on the handle, to provide movement of the movable jaw. 3 figs.

  13. Pneumatic soil removal tool

    DOE Patents [OSTI]

    Neuhaus, John E.

    1992-01-01

    A soil removal tool is provided for removing radioactive soil, rock and other debris from the bottom of an excavation, while permitting the operator to be located outside of a containment for that excavation. The tool includes a fixed jaw, secured to one end of an elongate pipe, which cooperates with a movable jaw pivotably mounted on the pipe. Movement of the movable jaw is controlled by a pneumatic cylinder mounted on the pipe. The actuator rod of the pneumatic cylinder is connected to a collar which is slidably mounted on the pipe and forms part of the pivotable mounting assembly for the movable jaw. Air is supplied to the pneumatic cylinder through a handle connected to the pipe, under the control of an actuator valve mounted on the handle, to provide movement of the movable jaw.

  14. The Effect of Steady Winds on Radon-222 Entry from soil into houses

    SciTech Connect (OSTI)

    Riley, W.J.; Gadgil, A.J.; Bonnefous, Y.C.; Nazaroff, W.W.

    1994-10-01

    Wind affects the radon-222 entry rate from soil into buildings and the resulting indoor concentrations. To investigate this phenomenon, we employ a previously tested three-dimensional numerical model of soil-gas Bow around houses, a commercial computational fluid dynamics code, an established model for determining ventilation rates in the presence of wind, and new wind tunnel results for the ground-surface pressure field caused by wind. These tools and data, applied under steady-state conditions to a prototypical residential building, allow us (1) to determine the complex soil-gas flow patterns that result from the presence of wind-generated ground-surface pressures, (2) to evaluate the effect of these flows on the radon concentration in the soil, and (3) to calculate the effect of wind on the radon entry rate and indoor concentration. For a broad range of soil permeabilities, two wind speeds, and two wind directions, we quantify the"flushing" effect of wind on the radon in the soil surrounding a house, and the consequent sharp decrease in radon entry rates. Experimental measurements of the time-dependent radon concentration in soil gas beneath houses confirm the existence of wind-induced flushing. Comparisons are made to modeling predictions obtained while ignoring the effect of the wind-generated ground-surface pressures. These investigations lead to the conclusion that wind-generated ground-surface pressures play a significant role in determining radon entry rates into residential buildings. [References: 26

  15. Radon exhalation rates from some soil samples of Kharar, Punjab

    SciTech Connect (OSTI)

    Mehta, Vimal; Singh, Tejinder Pal; Chauhan, R. P.; Mudahar, G. S.

    2015-08-28

    Radon and its progeny are major contributors in the radiation dose received by general population of the world. Because radon is a noble gas, a large portion of it is free to migrate away from radium. The primary sources of radon in the houses are soils and rocks source emanations, emanation from building materials, and entry of radon into a structure from outdoor air. Keeping this in mind the study of radon exhalation rate from some soil samples of the Kharar, Punjab has been carried out using Can Technique. The equilibrium radon concentration in various soil samples of Kharar area of district Mohali varied from 12.7 Bqm{sup −3} to 82.9 Bqm{sup −3} with an average of 37.5 ± 27.0 Bqm{sup −3}. The radon mass exhalation rates from the soil samples varied from 0.45 to 2.9 mBq/kg/h with an average of 1.4 ± 0.9 mBq/kg/h and radon surface exhalation rates varied from 10.4 to 67.2 mBq/m{sup 2}/h with an average of 30.6 ± 21.8 mBq/m{sup 2}/h. The radon mass and surface exhalation rates of the soil samples of Kharar, Punjab were lower than that of the world wide average.

  16. Soil-structure interaction. Volume 3. Influence of ground water

    SciTech Connect (OSTI)

    Costantino, C.J.

    1986-04-01

    This report, Volume 3 of the report, presents a summary of the first year's effort on the subject of the influence of foundation ground water on the SSI phenomenon. A finite element computer program was developed for the two-phased formulation of the combined soil-water problem. This formulation is based on the Biot dynamic equations of motion for both the solid and fluid phases of a typical soil. Frequency dependent interaction coefficients were generated for the two-dimensional plane problem of a rigid surface footing moving against a saturated linear soil. The results indicate that interaction coefficients are significantly modified as compared to the comparable values for a dry soil, particularly for the rocking mode of response. Calculations were made to study the impact of the modified interaction coefficients on the response of a typical nuclear reactor building. The amplification factors for a stick model placed atop a dry and saturated soil were computed. It was found that pore water caused the rocking response to decrease and translatinal response to increase over the frequency range of interest, as compared to the response on dry soil. 56 refs., 31 figs.

  17. Lead Sequestration and Species Redistribution During Soil Organic Matter Decomposition

    SciTech Connect (OSTI)

    Schroth,A.; Bostick, B.; Kaste, J.; Friedland, A.

    2008-01-01

    The turnover of soil organic matter (SOM) maintains a dynamic chemical environment in the forest floor that can impact metal speciation on relatively short timescales. Here we measure the speciation of Pb in controlled and natural organic (O) soil horizons to quantify changes in metal partitioning during SOM decomposition in different forest litters. We provide a link between the sequestration of pollutant Pb in O-horizons, estimated by forest floor Pb inventories, and speciation using synchrotron-based X-ray fluorescence and X-ray absorption spectroscopy. When Pb was introduced to fresh forest Oi samples, it adsorbed primarily to SOM surfaces, but as decomposition progressed over two years in controlled experiments, up to 60% of the Pb was redistributed to pedogenic birnessite and ferrihydrite surfaces. In addition, a significant fraction of pollutant Pb in natural soil profiles was associated with similar mineral phases ({approx}20-35%) and SOM ({approx}65-80%). Conifer forests have at least 2-fold higher Pb burdens in the forest floor relative to deciduous forests due to more efficient atmospheric scavenging and slower organic matter turnover. We demonstrate that pedogenic minerals play an important role in surface soil Pb sequestration, particularly in deciduous forests, and should be considered in any assessment of pollutant Pb mobility.

  18. Surface mining

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    This paper reports on a GAO study of attorney and expert witness fees awarded as a result of litigation brought under the Surface Mining Control and Reclamation Act. As of March 24, 1989, a total of about $1.4 million had been awarded in attorney fees and expenses - about $1.3 subject to the provisions of the Employee Retirement Income Security Act, a comparison of its features with provisions of ERISA showed that the plan differed from ERISA provisions in areas such as eligibility, funding, and contribution limits.

  19. Geotechnical considerations in surface mine reclamation

    SciTech Connect (OSTI)

    Kuhn, A.K.

    1999-07-01

    Most attention in surface mine reclamation is given to agronomic soils and revegetation, but reclamation success depends on the geotechnical characteristics of the underlying earth. If the soil and rock that underline the surface are not stable, surface treatments lack the dependable foundation needed for them to succeed. Reclamation practioners need to understand those geotechnical considerations--material properties, structure, and processes--that affect stability. properties of rock and soil are altered by mining, and those altered materials together with water and processing waste form often-complex mixtures of materials that must be stabilized in reclamation. Surface mining alters existing landforms and creates new ones such as pit walls, spoil and waste rock piles, tailings impoundments, and earthfills. those structures need to be constructed or stabilized so that they can endure and support successful reclamation. processes that affect material properties and landforms include mechanical breakage, accelerated weathering, erosion, and mass movements. Mechanical breakage and the resulting accelerated weathering combine to change material properties, usually expressed as degraded strength, that can lead to instability of landforms. Erosion, especially that related to extreme storm events, and mass movements in the form of slop failures are the most problematic processes that must be taken into account in reclaiming mined lands. These geotechnical considerations are essential in successful reclamation, and practioners who overlook them may find their work literally sliding down a slippery slope.

  20. Validation of Noah-simulated Soil Temperature in the North American Land Data Assimilation System Phase 2

    SciTech Connect (OSTI)

    Xia, Youlong; Ek, Michael; Sheffield, Justin; Livneh, Ben; Huang, Maoyi; Wei, Helin; Song, Feng; Luo, Lifeng; Meng, Jesse; Wood, Eric

    2013-02-25

    Soil temperature can exhibit considerable memory from weather and climate signals and is among the most important initial conditions in numerical weather and climate models. Consequently, a more accurate long-term land surface soil temperature dataset is needed to improve weather and climate simulation and prediction, and is also important for the simulation of agricultural crop yield and ecological processes. The North-American Land Data Assimilation (NLDAS) Phase 2 (NLDAS-2) has generated 31-years (1979-2009) of simulated hourly soil temperature data with a spatial resolution of 1/8o. This dataset has not been comprehensively evaluated to date. Thus, the ultimate purpose of the present work is to assess Noah-simulated soil temperature for different soil depths and timescales. We used long-term (1979-2001) observed monthly mean soil temperatures from 137 cooperative stations over the United States to evaluate simulated soil temperature for three soil layers (0-10 cm, 10-40 cm, 40-100 cm) for annual and monthly timescales. We used short-term (1997-1999) observed soil temperature from 72 Oklahoma Mesonet stations to validate simulated soil temperatures for three soil layers and for daily and hourly timescales. The results showed that the Noah land surface model (Noah LSM) generally matches observed soil temperature well for different soil layers and timescales. At greater depths, the simulation skill (anomaly correlation) decreased for all time scales. The monthly mean diurnal cycle difference between simulated and observed soil temperature revealed large midnight biases in the cold season due to small downward longwave radiation and issues related to model parameters.

  1. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2014-10-30

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon (OC) stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous OC stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global C cycle and the potential vulnerability of the region's soil OC stocks to changing climatic conditions. In this review,more » we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of OC stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this OC to permafrost thaw under a warming climate.« less

  2. Selective leaching of uranium from uranium-contaminated soils: Progress report 1

    SciTech Connect (OSTI)

    Francis, C.W.; Mattus, A.J.; Farr, L.L.; Elless, M.P.; Lee, S.Y.

    1993-02-01

    Three soils and a sediment contaminated with uranium were used to determine the effectiveness of sodium carbonate and citric acid leaching to decontaminated or remove uranium to acceptable regulatory levels. Two of the soils were surface soils from the DOE facility formerly called the Feed Materials Production Center (FMPC) at Fernald, Ohio. This facility is presently called the Femald Environmental Management Project (FEMP). Carbonate extractions generally removed from 70 to 90% of the uranium from the Fernald storage pad soil. Uranium was slightly more difficult to extract from the Fernald incinerator and the Y-12 landfarm soils. Very small amounts of uranium could be extracted from the storm sewer sediment. Extraction with carbonate at high solution-to-soil ratios were as effective as extractions at low solution-to-soil ratios, indicating attrition by the paddle mixer was not significantly different than that provided in a rotary extractor. Also, pretreatments such as milling or pulverizing the soil sample did not appear to increase extraction efficiency when carbonate extractions were carried out at elevated temperatures (60{degree}C) or long extraction times (23 h). Adding KMnO{sub 4} in the carbonate extraction appeared to increase extraction efficiency from the Fernald incinerator soil but not the Fernald storage pad soil. The most effective leaching rates (> 90 % from both Fernald soils) were obtained using a citrate/dithionite extraction procedure designed to remove amorphous (noncrystalline) iron/aluminum sesquioxides from surfaces of clay minerals. Citric acid also proved to be a very good extractant for uranium.

  3. Selective leaching of uranium from uranium-contaminated soils: Progress report 1

    SciTech Connect (OSTI)

    Francis, C.W.; Mattus, A.J.; Farr, L.L.; Elless, M.P.; Lee, S.Y.

    1993-02-01

    Three soils and a sediment contaminated with uranium were used to determine the effectiveness of sodium carbonate and citric acid leaching to decontaminated or remove uranium to acceptable regulatory levels. Two of the soils were surface soils from the DOE facility formerly called the Feed Materials Production Center (FMPC) at Fernald, Ohio. This facility is presently called the Femald Environmental Management Project (FEMP). Carbonate extractions generally removed from 70 to 90% of the uranium from the Fernald storage pad soil. Uranium was slightly more difficult to extract from the Fernald incinerator and the Y-12 landfarm soils. Very small amounts of uranium could be extracted from the storm sewer sediment. Extraction with carbonate at high solution-to-soil ratios were as effective as extractions at low solution-to-soil ratios, indicating attrition by the paddle mixer was not significantly different than that provided in a rotary extractor. Also, pretreatments such as milling or pulverizing the soil sample did not appear to increase extraction efficiency when carbonate extractions were carried out at elevated temperatures (60[degree]C) or long extraction times (23 h). Adding KMnO[sub 4] in the carbonate extraction appeared to increase extraction efficiency from the Fernald incinerator soil but not the Fernald storage pad soil. The most effective leaching rates (> 90 % from both Fernald soils) were obtained using a citrate/dithionite extraction procedure designed to remove amorphous (noncrystalline) iron/aluminum sesquioxides from surfaces of clay minerals. Citric acid also proved to be a very good extractant for uranium.

  4. Remote sensing of soil radionuclide fluxes in a tropical ecosystem

    SciTech Connect (OSTI)

    Clegg, B.; Koranda, J.; Robinson, W.; Holladay, G.

    1980-11-06

    We are using a transponding geostationary satellite to collect surface environmental data to describe the fate of soil-borne radionuclides. The remote, former atomic testing grounds at the Eniwetok and Bikini Atolls present a difficult environment in which to collect continuous field data. Our land-based, solar-powered microprocessor and environmental data systems remotely acquire measurements of net and total solar radiation, rain, humidity, temperature, and soil-water potentials. For the past year, our water flux model predicts wet season plant transpiration rates nearly equal to the 6 to 7 mm/d evaporation pan rate, which decreases to 2 to 3 mm/d for the dry season. Radioisotopic analysis confirms the microclimate-estimated 1:3 to 1:20 soil to plant /sup 137/Cs dry matter concentration ratio. This ratio exacerbates the dose to man from intake of food plants. Nephelometer measurements of airborne particulates presently indicate a minimum respiratory radiological dose.

  5. Contrasting soil microbial community functional structures in...

    Office of Scientific and Technical Information (OSTI)

    Contrasting soil microbial community functional structures in two major landscapes of the Tibetan alpine meadow Prev Next Title: Contrasting soil microbial community...

  6. NNSS Soils Monitoring: Plutonium Valley (CAU366) FY2012

    SciTech Connect (OSTI)

    Miller, Julianne J.; Mizell, Steve A.; Nikolich, George; McCurdy, Greg; Campbell, Scott

    2013-01-01

    The U.S. Department of Energy (DOE) National Nuclear Security Administration (NNSA), Nevada Site Office (NSO), Environmental Restoration Soils Activity has authorized the Desert Research Institute (DRI) to conduct field assessments of potential sediment transport of contaminated soil from Corrective Action Unit (CAU) 366, Area 11 Plutonium Valley Dispersion Sites Contamination Area (CA) during precipitation runoff events. Field measurements at the T-4 Atmospheric Test Site (CAU 370) suggest that radionuclide-contaminated soils may have migrated along a shallow ephemeral drainage that traverses the site (NNSA/NSO, 2009). (It is not entirely clear how contaminated soils got into their present location at the T-4 Site, but flow to the channel has been redirected and the contamination does not appear to be migrating at present.) Aerial surveys in selected portions of the Nevada National Security Site (NNSS) also suggest that radionuclide-contaminated soils may be migrating along ephemeral channels in Areas 3, 8, 11, 18, and 25 (Colton, 1999). In Area 11, several low-level airborne surveys of the Plutonium Valley Dispersion Sites (CAU 366) show plumes of Americium 241 (Am-241) extending along ephemeral channels (Figure 1, marker numbers 5 and 6) below Corrective Action Site (CAS) 11-23-03 (marker number 3) and CAS 11 23-04 (marker number 4) (Colton, 1999). Plutonium Valley in Area 11 of the NNSS was selected for the study because of the aerial survey evidence suggesting downstream transport of radionuclide-contaminated soil. The aerial survey (Figure 1) shows a well defined finger of elevated radioactivity (marker number 5) extending to the southwest from the southernmost detonation site (marker number 4). This finger of contamination overlies a drainage channel mapped on the topographic base map used for presentation of the survey data suggesting surface runoff as a likely cause of the contaminated area. Additionally, instrumenting sites strongly suspected of conveying

  7. Influence of ground water on soil-structure interaction

    SciTech Connect (OSTI)

    Costantino, C.J.; Philippacopoulos, A.J.

    1987-12-01

    This report presents a summary of the second year's effort on the subject of the influence of foundation ground water on the SSI phenomenon. A finite element computer program, developed during the first year's effort, was used to study the impact of depth to the ground water surface on the SSI problem. The formulation used therein is based on the Biot dynamic equations of motion for both the solid and fluid phases of a typical soil. Frequency dependent interaction coefficients were then generated for the two-dimensional plane problem of a rigid surface footing moving against a linear soil. The soil is considered dry above the GWT and fully saturated below. The results indicate that interaction coefficients are significantly modified as compared to the comparable values for a dry soil, particularly for the rocking mode of response, if the GWT is close to the foundation. As the GWT moves away from the foundation, these effects decrease in a relatively orderly fashion for both the horizontal and rocking modes of response. For the vertical interaction coefficients, the rate of convergence to the dry solution is frequency dependent. Calculations were made to study the impact of the modified interaction coefficients on the response of a typical nuclear reactor building. The amplification factors for a stick model placed atop a dry and saturated soil were computed. It was found that pore water caused the rocking response to decrease and translational response to increase over the frequency range of interest, as compared to the response on dry soil. 30 refs., 31 figs.

  8. In situ formation of magnetite reactive barriers in soil for waste stabilization

    DOE Patents [OSTI]

    Moore, Robert C.

    2003-01-01

    Reactive barriers containing magnetite and methods for making magnetite reactive barriers in situ in soil for sequestering soil contaminants including actinides and heavy metals, organic materials, iodine and technetium are disclosed. According to one embodiment, a two-step reagent introduction into soil takes place. In the first step, free oxygen is removed from the soil by separately injecting into the soil aqueous solutions of iron (II) salt, for example FeCl.sub.2, and base, for example NaOH or NH.sub.3 in about a 1:1 volume ratio. Then, in the second step, similar reagents are injected a second time (however, according to about a 1:2 volume ratio, iron to salt) to form magnetite. The magnetite formation is facilitated, in part, due to slow intrusion of oxygen into the soil from the surface. The invention techniques are suited to injection of reagents into soil in proximity to a contamination plume or source allowing in situ formation of the reactive barrier at the location of waste or hazardous material. Mixing of reagents to form. precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

  9. Soil Stabilization Methods with Potential for Application at the Nevada National Security Site: A Literature Review

    SciTech Connect (OSTI)

    Shillito, Rose; Fenstermaker, Lynn

    2014-01-01

    Nuclear testing at the Nevada National Security Site (NNSS) has resulted in large areas of surficial radionuclide-contaminated soils. Much of the radionuclide contamination is found at or near the soil surface, and due to the dry climate setting, and the long half-life of radioactive isotopes, soil erosion poses a long-term health risk at the NNSS. The objective of this literature review is to present a survey of current stabilization methods used for minimizing soil erosion, both by water and wind. The review focuses on in situ uses of fundamental chemical and physical mechanisms for soil stabilization. A basic overview of the physical and chemical properties of soil is also presented to provide a basis for assessing stabilization methods. Some criteria for stabilization evaluation are identified based on previous studies at the NNSS. Although no specific recommendations are presented as no stabilization method, alone or in combination, will be appropriate in all circumstances, discussions of past and current stabilization procedures and specific soil tests that may aid in current or future soil stabilization activities at the NNSS are presented. However, not all Soils Corrective Action Sites (CASs) or Corrective Action Units (CAUs) will require stabilization of surficial radionuclide-contaminated soils. Each Soils CAS or CAU should be evaluated for site-specific conditions to determine if soil stabilization is necessary or practical for a given specific site closure alternative. If stabilization is necessary, then a determination will be made as to which stabilization technique is the most appropriate for that specific site.

  10. Surface barrier research at the Hanford Site

    SciTech Connect (OSTI)

    Gee, G.W.; Ward, A.L.; Fayer, M.J.

    1997-12-31

    At the DOE Hanford Site, a field-scale prototype surface barrier was constructed in 1994 over an existing waste site as a part of a CERCLA treatability test. The above-grade barrier consists of a fine-soil layer overlying coarse layers of sands, gravels, basalt rock (riprap), and a low permeability asphalt layer. Two sideslope configurations, clean-fill gravel on a 10:1 slope and basalt riprap on a 2:1 slope, were built and are being tested. Design considerations included: constructability; drainage and water balance monitoring, wind and water erosion control and monitoring; surface revegetation and biotic intrusion; subsidence and sideslope stability, and durability of the asphalt layer. The barrier is currently in the final year of a three-year test designed to answer specific questions related to stability and long-term performance. One half of the barrier is irrigated such that the total water applied, including precipitation, is 480 mm/yr (three times the long-term annual average). Each year for the past two years, an extreme precipitation event (71 mm in 8 hr) representing a 1,000-yr return storm was applied in late March, when soil water storage was at a maximum. While the protective sideslopes have drained significant amounts of water, the soil cover (2-m of silt-loam soil overlying coarse sand and rock) has never drained. During the past year there was no measurable surface runoff or wind erosion. This is attributed to extensive revegetation of the surface. In addition, the barrier elevation has shown a small increase of 2 to 3 cm that is attributed to a combination of root proliferation and freeze/thaw activity. Testing will continue through September 1997. Performance data from the prototype barrier will be used by DOE in site-closure decisions at Hanford.

  11. Complementary system for long term measurements of radon exhalation rate from soil

    SciTech Connect (OSTI)

    Mazur, J.; Kozak, K.

    2014-02-15

    A special set-up for continuous measurements of radon exhalation rate from soil is presented. It was constructed at Laboratory of Radiometric Expertise, Institute of Nuclear Physics Polish Academy of Sciences (IFJ PAN), Krakow, Poland. Radon exhalation rate was determined using the AlphaGUARD PQ2000 PRO (Genitron) radon monitor together with a special accumulation container which was put on the soil surface during the measurement. A special automatic device was built and used to raise and lower back onto the ground the accumulation container. The time of raising and putting down the container was controlled by an electronic timer. This set-up made it possible to perform 4–6 automatic measurements a day. Besides, some additional soil and meteorological parameters were continuously monitored. In this way, the diurnal and seasonal variability of radon exhalation rate from soil can be studied as well as its dependence on soil properties and meteorological conditions.

  12. Uranium soils integrated demonstration: Soil characterization project report

    SciTech Connect (OSTI)

    Cunnane, J.C.; Gill, V.R.; Lee, S.Y.; Morris, D.E.; Nickelson, M.D.; Perry, D.L.; Tidwell, V.C.

    1993-08-01

    An Integrated Demonstration Program, hosted by the Fernald Environmental Management Project (FEMP), has been established for investigating technologies applicable to the characterization and remediation of soils contaminated with uranium. Critical to the design of relevant treatment technologies is detailed information on the chemical and physical characteristics of the uranium waste-form. To address this need a soil sampling and characterization program was initiated which makes use of a variety of standard analytical techniques coupled with state-of-the-art microscopy and spectroscopy techniques. Sample representativeness is evaluated through the development of conceptual models in an effort to identify and understand those geochemical processes governing the behavior of uranium in FEMP soils. Many of the initial results have significant implications for the design of soil treatment technologies for application at the FEMP.

  13. Grounding electrode and method of reducing the electrical resistance of soils

    DOE Patents [OSTI]

    Koehmstedt, Paul L.

    1980-01-01

    A first solution of an electrolyte is injected underground into a volume of soil having negative surface charges on its particles. A cationic surfactant suspended in this solution neutralizes these surface charges of the soil particles within the volume. Following the first solution, a cationic asphalt emulsion suspended in a second solution is injected into the volume. The asphalt emulsion diffuses through the volume and electrostatically bonds with additional soil surrounding the volume such that an electrically conductive water repellant shell enclosing the volume is formed. This shell prevents the leaching of electrolyte from the volume into the additional soil. The second solution also contains a dissolved deliquescent salt which draws water into the volume prior to the formation of the shell. When electrically connected to an electrical installation such as a power line tower, the volume constitutes a grounding electrode for the tower.

  14. Advanced Assay Systems for Radionuclide Contamination in Soils

    SciTech Connect (OSTI)

    J. R. Giles; L. G. Roybal; M. V. Carpenter; C. P. Oertel; J. A. Roach

    2008-02-01

    Through the support of the Department of Energy (DOE) Office of Environmental Management (EM) Technical Assistance Program, the Idaho National Laboratory (INL) has developed and deployed a suite of systems that rapidly scan, characterize, and analyze surface soil contamination. The INL systems integrate detector systems with data acquisition and synthesis software and with global positioning technology to provide a real-time, user-friendly field deployable turn-key system. INL real-time systems are designed to characterize surface soil contamination using methodologies set forth in the Multi-Agency Radiation Surveys and Site Investigation Manual (MARSSIM). MARSSIM provides guidance for planning, implementing, and evaluating environmental and facility radiological surveys conducted to demonstrate compliance with a dose or risk-based regulation and provides real-time information that is immediately available to field technicians and project management personnel. This paper discusses the history of the development of these systems and describes some of the more recent examples and their applications.

  15. Surface Energy Balance System (SEBS) Handbook

    SciTech Connect (OSTI)

    Cook, DR

    2011-02-14

    A Surface Energy Balance System (SEBS) has been installed collocated with each deployed ECOR system at the Southern Great Plains (SGP), North Slope of Alaska (NSA), Tropical Western Pacific (TWP), ARM Mobile Facility 1 (AMF1), and ARM Mobile Facility 2 (AMF2). The surface energy balance system consists of upwelling and downwelling solar and infrared radiometers within one net radiometer, a wetness sensor, and soil measurements. The SEBS measurements allow the comparison of ECOR sensible and latent heat fluxes with the energy balance determined from the SEBS and provide information on wetting of the sensors for data quality purposes.

  16. Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries

    DOE Patents [OSTI]

    Mincher, Bruce J.; Curry, Randy Dale; Clevenger, Thomas E.; Golden, Jeffry

    2000-01-01

    A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacting a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

  17. Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries

    DOE Patents [OSTI]

    Mincher, Bruce J.; Curry, Randy Dale; Clevenger, Thomas E.; Golden, Jeffry

    2003-05-27

    A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacts a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

  18. Process for the solvent extraction for the radiolysis and dehalogenation of halogenated organic compounds in soils, sludges, sediments and slurries

    DOE Patents [OSTI]

    Golden, Jeffry

    2007-02-13

    A process of extracting halogenated organic compounds, and particularly PCBs, from soil, sediment, slurry, sludge and dehalogenating the compounds contacts a contaminated soil sample with an extraction medium of a mixture of an alkane and a water miscible alcohol. The organic compounds dissolve in the extraction medium which is separated from the soil by passing water upwardly through the soil. The extraction medium floats to the surface of the water and is separated. Thereafter, the extraction medium containing the halogenated organic contaminants is subjected to ionizing radiation to radiolytically dehalogenate the compounds.

  19. Soil & Groundwater Home - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil & Groundwater Home Soil & Groundwater Home Annual Reports Environmental Data Access Administrative Record Soil & Groundwater Home Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size Soil & Groundwater Home Annual Reports Environmental Data Access Administrative Record Share on Last Updated 08/28/2016 4:15

  20. Multi-omics of Permafrost, Active Layer and Thermokarst Bog Soil

    Office of Scientific and Technical Information (OSTI)

    Microbiomes (Journal Article) | SciTech Connect Journal Article: Multi-omics of Permafrost, Active Layer and Thermokarst Bog Soil Microbiomes Citation Details In-Document Search Title: Multi-omics of Permafrost, Active Layer and Thermokarst Bog Soil Microbiomes Over 20% of Earth's terrestrial surface is underlain by permafrost with vast stores of carbon that, if thawed may represent the largest future transfer of C from the biosphere to the atmosphere 1. This process is largely dependent on

  1. Worldwide organic soil carbon and nitrogen data

    SciTech Connect (OSTI)

    Zinke, P.J.; Stangenberger, A.G.; Post, W.M.; Emanual, W.R.; Olson, J.S.

    1986-09-01

    The objective of the research presented in this package was to identify data that could be used to estimate the size of the soil organic carbon pool under relatively undisturbed soil conditions. A subset of the data can be used to estimate amounts of soil carbon storage at equilibrium with natural soil-forming factors. The magnitude of soil properties so defined is a resulting nonequilibrium values for carbon storage. Variation in these values is due to differences in local and geographic soil-forming factors. Therefore, information is included on location, soil nitrogen content, climate, and vegetation along with carbon density and variation.

  2. Comprehensive appraisal of {sup 239+240}Pu in soils around Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Litaor, M.I.; Allen, L.; Ellerbroek, D.

    1995-12-01

    Plutonium contamination of soils around Rocky Flats Environmental & Technology Site, near Golden, Colorado, resulted from past outdoor storage practices and subsequent remobilization due to inadequate cleanup practices. Until now human-health risk assessment has not been performed because of a lack of sufficient information regarding the spatial extent of {sup 239+240}Pu in soils. The purpose of this work was to elucidate the extent of plutonium contamination in surface soils, and to assess the uncertainty associated with the spatial distribution of {sup 239+240}Pu around Rocky Flats Environmental & Technology Site.

  3. Soil Moisture Sensor - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil & Groundwater Remediation Soil & Groundwater Remediation Soil & Groundwater Remediation The U.S. Department of Energy (DOE) manages one of the largest groundwater and soil remediation efforts in the world. The inventory at the DOE sites includes 6.5 trillion liters of contaminated groundwater, an amount equal to about four times the daily U.S. water consumption, and 40 million cubic meters of soil and debris contaminated with radionuclides, metals, and organics. The Office of

  4. Nuclear forensics: Soil content

    SciTech Connect (OSTI)

    Beebe, Merilyn Amy

    2015-08-31

    Nuclear Forensics is a growing field that is concerned with all stages of the process of creating and detonating a nuclear weapon. The main goal is to prevent nuclear attack by locating and securing nuclear material before it can be used in an aggressive manner. This stage of the process is mostly paperwork; laws, regulations, treaties, and declarations made by individual countries or by the UN Security Council. There is some preliminary leg work done in the form of field testing detection equipment and tracking down orphan materials; however, none of these have yielded any spectacular or useful results. In the event of a nuclear attack, the first step is to analyze the post detonation debris to aid in the identification of the responsible party. This aspect of the nuclear forensics process, while reactive in nature, is more scientific. A rock sample taken from the detonation site can be dissolved into liquid form and analyzed to determine its chemical composition. The chemical analysis of spent nuclear material can provide valuable information if properly processed and analyzed. In order to accurately evaluate the results, scientists require information on the natural occurring elements in the detonation zone. From this information, scientists can determine what percentage of the element originated in the bomb itself rather than the environment. To this end, element concentrations in soils from sixty-nine different cities are given, along with activity concentrations for uranium, thorium, potassium, and radium in various building materials. These data are used in the analysis program Python.

  5. Amino acid treatment enhances protein recovery from sediment and soils for metaproteomic studies

    SciTech Connect (OSTI)

    Nicora, Carrie D.; Anderson, Brian J.; Callister, Stephen J.; Norbeck, Angela D.; Purvine, Samuel O.; Jansson, Janet K.; Mason, Olivia U.; David, Maude; Jurelevicius, Diogo D.; Smith, Richard D.; Lipton, Mary S.

    2013-10-01

    Characterization of geomicrobial protein expression provides information necessary to better understand the unique biological pathways that occur within soil microbial communities and the role they play in regulating atmospheric CO2 levels and the Earth’s climate. A significant challenge in studying soil microbial proteins is their initial dissociation from the complex mixture of particles found in natural soil. Due to bias of the most robust cells, the removal of intact bacterial cells limits the characterization of the complete representation of a microbial community. However, in-situ lysis of bacterial cells leads to the expulsion of proteins to the soil surface, which can lead to potentially high levels of adsorption due to the physicochemical properties of both the protein and the soil. We investigated various compounds for their ability to block protein adsorption soil sites prior to in-situ lysis of bacterial cells, as well as their compatibility with both tryptic digestion and mass spectrometric analysis. The treatments were tested by adding lysed Escherichia coli proteins to representative treated and untreated soil samples. The results show that it is possible to significantly increase protein identifications through blockage of binding sites on a variety of soil textures; use of an optimized desorption buffer further increases the number of identifications.

  6. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns ofmore » dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.« less

  7. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    SciTech Connect (OSTI)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.

  8. Category:Soil Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    Soil Gas Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Soil Gas Sampling page? For detailed information on Soil Gas...

  9. Treatment of radionuclide contaminated soils

    SciTech Connect (OSTI)

    Pettis, S.A.; Kallas, A.J.; Kochen, R.L.; McGlochlin, S.C.

    1988-06-01

    Rockwell, International, Rocky Flats Plants, is committed to remediating within the scope of RCRA/CERCLA, Solid Waste Managements Units (SWMUs) at Rocky Flats found to be contaminated with hazardous substances. SWMUs fund to have radionuclide (uranium, plutonium, and/or americium) concentrations in the soils and/or groundwater that exceed background levels or regulatory limits will also be included in this remediation effort. This paper briefly summarizes past and present efforts by Rockwell International, Rocky Flats Plant, to identify treatment technologies appropriate for remediating actinide contaminated soils. Many of the promising soil treatments evaluated in Rocky Flats' laboratories during the late 1970's and early 1980's are currently being revisited. These technologies are generally directed toward substantially reducing the volume of contaminated soils, with the subsequent intention of disposing of a small remaining concentrated fraction of contaminated soil in a facility approved to receive radioactive wastes. Treatment processes currently will be treated to remove actinides, and recycled back to the process. Past investigations have included evaluations of dry screening, wet screening, scrubbing, ultrasonics, chemical oxidation, calcination, desliming, flotation, and heavy-liquid density separation. 8 refs., 2 figs.

  10. Lasagna{trademark} soil remediation

    SciTech Connect (OSTI)

    1996-04-01

    Lasagna{trademark} is an integrated, in situ remediation technology being developed which remediates soils and soil pore water contaminated with soluble organic compounds. Lasagna{trademark} is especially suited to sites with low permeability soils where electroosmosis can move water faster and more uniformly than hydraulic methods, with very low power consumption. The process uses electrokinetics to move contaminants in soil pore water into treatment zones where the contaminants can be captured and decomposed. Initial focus is on trichloroethylene (TCE), a major contaminant at many DOE and industrial sites. Both vertical and horizontal configurations have been conceptualized, but fieldwork to date is more advanced for the vertical configuration. Major features of the technology are electrodes energized by direct current, which causes water and soluble contaminants to move into or through the treatment layers and also heats the soil; treatment zones containing reagents that decompose the soluble organic contaminants or adsorb contaminants for immobilization or subsequent removal and disposal; and a water management system that recycles the water that accumulates at the cathode (high pH) back to the anode (low pH) for acid-base neutralization. Alternatively, electrode polarity can be reversed periodically to reverse electroosmotic flow and neutralize pH.

  11. Interpretation of storage field well casing surface potentials

    SciTech Connect (OSTI)

    Dabkowski, J.

    1987-01-01

    The shape of a well casing-to-soil potential gradient surface profile is influenced by many variables. Hence, the interpretation of such field data can be difficult. The paper illustrates how such factors as layered ground resistivity, polarization potential variations with depth, and external interference affect the profiles and, therefore, the interpretation of field data.

  12. Natural mercury isotope variation in coal deposits and organic soils

    SciTech Connect (OSTI)

    Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie

    2008-11-15

    There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

  13. Interannual Variability in Global Soil Respiration on a 0.5 Degree Grid Cell Basis (1980-1994)

    SciTech Connect (OSTI)

    Raich, J.W.

    2003-09-15

    We used a climate-driven regression model to develop spatially resolved estimates of soil-CO{sub 2} emissions from the terrestrial land surface for each month from January 1980 to December 1994, to evaluate the effects of interannual variations in climate on global soil-to-atmosphere CO{sub 2} fluxes. The mean annual global soil-CO{sub 2} flux over this 15-y period was estimated to be 80.4 (range 79.3-81.8) Pg C. Monthly variations in global soil-CO{sub 2} emissions followed closely the mean temperature cycle of the Northern Hemisphere. Globally, soil-CO{sub 2} emissions reached their minima in February and peaked in July and August. Tropical and subtropical evergreen broad-leaved forests contributed more soil-derived CO{sub 2} to the atmosphere than did any other vegetation type ({approx}30% of the total) and exhibited a biannual cycle in their emissions. Soil-CO{sub 2} emissions in other biomes exhibited a single annual cycle that paralleled the seasonal temperature cycle. Interannual variability in estimated global soil-CO{sub 2} production is substantially less than is variability in net carbon uptake by plants (i.e., net primary productivity). Thus, soils appear to buffer atmospheric CO{sub 2} concentrations against far more dramatic seasonal and interannual differences in plant growth. Within seasonally dry biomes (savannas, bushlands, and deserts), interannual variability in soil-CO{sub 2} emissions correlated significantly with interannual differences in precipitation. At the global scale, however, annual soil-CO{sub 2} fluxes correlated with mean annual temperature, with a slope of 3.3 PgCY{sup -1} per degree Celsius. Although the distribution of precipitation influences seasonal and spatial patterns of soil-CO{sub 2} emissions, global warming is likely to stimulate CO{sub 2} emissions from soils.

  14. Soil microbial responses to nitrogen addition in arid ecosystems

    SciTech Connect (OSTI)

    Sinsabaugh, Robert L.; Belnap, Jayne; Rudgers, Jennifer; Kuske, Cheryl R.; Martinez, Noelle; Sandquist, Darren

    2015-08-14

    The N cycle of arid ecosystems is influenced by low soil organic matter, high soil pH, and extremes in water potential and temperature that lead to open canopies and development of biological soil crusts (biocrusts). We investigated the effects of N amendment on soil microbial dynamics in a Larrea tridentata-Ambrosia dumosa shrubland site in southern Nevada USA. Sites were fertilized with a NO3-NH4 mix at 0, 7, and 15 kg N ha-1 y-1 from March 2012 to March 2013. In March 2013, biocrust (0–0.5 cm) and bulk soils (0–10 cm) were collected beneath Ambrosia canopies and in the interspaces between plants. Biomass responses were assessed as bacterial and fungal SSU rRNA gene copy number and chlorophyll a concentration. Metabolic responses were measured by five ecoenzyme activities and rates of N transformation. With most measures, nutrient availability, microbial biomass, and process rates were greater in soils beneath the shrub canopy compared to the interspace between plants, and greater in the surface biocrust horizon compared to the deeper 10 cm soil profile. Most measures responded positively to experimental N addition. Effect sizes were generally greater for bulk soil than biocrust. Results were incorporated into a meta-analysis of arid ecosystem responses to N amendment that included data from 14 other studies. Effect sizes were calculated for biomass and metabolic responses. Regressions of effect sizes, calculated for biomass, and metabolic responses, showed similar trends in relation to N application rate and N load (rate × duration). The critical points separating positive from negative treatment effects were 88 kg ha-1 y-1 and 159 kg ha-1, respectively, for biomass, and 70 kg ha-1 y-1 and 114 kg ha-1, respectively, for metabolism. These critical values are comparable to those for microbial biomass, decomposition rates and respiration

  15. Soil microbial responses to nitrogen addition in arid ecosystems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sinsabaugh, Robert L.; Belnap, Jayne; Rudgers, Jennifer; Kuske, Cheryl R.; Martinez, Noelle; Sandquist, Darren

    2015-08-14

    The N cycle of arid ecosystems is influenced by low soil organic matter, high soil pH, and extremes in water potential and temperature that lead to open canopies and development of biological soil crusts (biocrusts). We investigated the effects of N amendment on soil microbial dynamics in a Larrea tridentata-Ambrosia dumosa shrubland site in southern Nevada USA. Sites were fertilized with a NO3-NH4 mix at 0, 7, and 15 kg N ha-1 y-1 from March 2012 to March 2013. In March 2013, biocrust (0–0.5 cm) and bulk soils (0–10 cm) were collected beneath Ambrosia canopies and in the interspaces betweenmore » plants. Biomass responses were assessed as bacterial and fungal SSU rRNA gene copy number and chlorophyll a concentration. Metabolic responses were measured by five ecoenzyme activities and rates of N transformation. With most measures, nutrient availability, microbial biomass, and process rates were greater in soils beneath the shrub canopy compared to the interspace between plants, and greater in the surface biocrust horizon compared to the deeper 10 cm soil profile. Most measures responded positively to experimental N addition. Effect sizes were generally greater for bulk soil than biocrust. Results were incorporated into a meta-analysis of arid ecosystem responses to N amendment that included data from 14 other studies. Effect sizes were calculated for biomass and metabolic responses. Regressions of effect sizes, calculated for biomass, and metabolic responses, showed similar trends in relation to N application rate and N load (rate × duration). The critical points separating positive from negative treatment effects were 88 kg ha-1 y-1 and 159 kg ha-1, respectively, for biomass, and 70 kg ha-1 y-1 and 114 kg ha-1, respectively, for metabolism. These critical values are comparable to those for microbial biomass, decomposition rates and respiration reported in broader meta-analyses of N amendment effects in mesic ecosystems. The large effect sizes at low N

  16. Biosurfactant-enhanced soil bioremediation

    SciTech Connect (OSTI)

    Kosaric, N.; Lu, G.; Velikonja, J.

    1995-12-01

    Bioremediation of soil contaminated with organic chemicals is a viable alternative method for clean-up and remedy of hazardous waste sites. The final objective in this approach is to convert the parent toxicant into a readily biodegradable product which is harmless to human health and/or the environment. Biodegradation of hydrocarbons in soil can also efficiently be enhanced by addition or in-situ production of biosufactants. It was generally observed that the degradation time was shortened and particularly the adaptation time for the microbes. More data from our laboratories showed that chlorinated aromatic compounds, such as 2,4-dichlorophenol, a herbicide Metolachlor, as well as naphthalene are degraded faster and more completely when selected biosurfactants are added to the soil. More recent data demonstrated an enhanced biodegradation of heavy hydrocarbons in petrochemical sludges, and in contaminated oil when biosurfactants were present or were added prior to the biodegradation process.

  17. Project plan for the background soils project for the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    1995-09-01

    The Background Soils Project for the Paducah Gaseous Diffusion Plant (BSPP) will determine the background concentration levels of selected naturally occurring metals, other inorganics, and radionuclides in soils from uncontaminated areas in proximity to the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The data will be used for comparison with characterization and compliance data for soils, with significant differences being indicative of contamination. All data collected as part of this project will be in addition to other background databases established for the PGDP. The BSPP will address the variability of surface and near-surface concentration levels with respect to (1) soil taxonomical types (series) and (2) soil sampling depths within a specific soil profile. The BSPP will also address the variability of concentration levels in deeper geologic formations by collecting samples of geologic materials. The BSPP will establish a database, with recommendations on how to use the data for contaminated site assessment, and provide data to estimate the potential human and health and ecological risk associated with background level concentrations of potentially hazardous constituents. BSPP data will be used or applied as follows.

  18. Automated soil gas monitoring chamber (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Title: Automated soil gas monitoring chamber A chamber for trapping soil gases as they evolve from the soil without disturbance to the soil and to the natural microclimate within ...

  19. Sweet Surface Area

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sweet Surface Area Sweet Surface Area Create a delicious root beer float and learn sophisticated science concepts at the same time. Sweet Surface Area Science is all around us, so ...

  20. Soil Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    "normal" background soil gas contents of a particular geothermal area. References Toxic Substances Hydrology Program 2.0 2.1 The Application of Soil-Gas Technique to...

  1. Chemotactic selection of pollutant degrading soil bacteria (Patent...

    Office of Scientific and Technical Information (OSTI)

    RADIATION SOURCES; BACTERIA; EVALUATION; POLLUTANTS; BIODEGRADATION; SOILS; NUTRIENTS; COLONY FORMATION; INVENTIONS; SOIL CHEMISTRY; MINERALIZATION; LAND POLLUTION 540120; 053003; ...

  2. Multi-Year Lags between Forest Browning and Soil Respiration at High Northern Latitudes

    SciTech Connect (OSTI)

    Bond-Lamberty, Benjamin; Bunn, Andrew G.; Thomson, Allison M.

    2012-11-26

    High-latitude northern ecosystems are experiencing rapid climate changes, and represent a large potential climate feedback because of their high soil carbon densities and shifting disturbance regimes. A significant carbon flow from these ecosystems is soil respiration (RS, the flow of carbon dioxide, generated by plant roots and soil fauna, from the soil surface to atmosphere), and any change in the high-latitude carbon cycle might thus be reflected in RS observed in the field. This study used two variants of a machine-learning algorithm and least squares regression to examine how remotely-sensed canopy greenness (NDVI), climate, and other variables are coupled to annual RS based on 105 observations from 64 circumpolar sites in a global database. The addition of NDVI roughly doubled model performance, with the best-performing models explaining ~62% of observed RS variability

  3. Qualitative evaluation of heavy metals in soils using portable XRF instruments

    SciTech Connect (OSTI)

    McCain, R.G.

    1993-10-01

    Portable isotope-source energy dispersive x-ray fluorescence (XRF) analyzers can provide rapid on site screening for heavy metals in soils. Their use generally involves empirical calibration to a suite of representative soil samples spiked with a range of concentrations of the analytes of interest. In most cases, only a limited number of analytes can be measured with this approach, because of constraints imposed by the operational software and costs associated with preparing the calibration suite. A simple approach is described that provides a qualitative indication of anomalous concentrations of heavy metals based on numeric comparison of gross count rates to background values. This approach can rapidly identify contaminated soils and does not depend on a suite of calibration samples. Direct measurements can be made to rapidly map soil contamination without sample collection, and the method can also be applied to other surfaces such as concrete.

  4. Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis to Identify Hidden, High Enthalpy, Extensional Geothermal Systems | Department of Energy Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural Analysis to Identify Hidden, High Enthalpy, Extensional Geothermal Systems Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural Analysis to Identify Hidden, High Enthalpy, Extensional Geothermal Systems Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural Analysis to Identify Hidden, High Enthalpy,

  5. Shiprock Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Environmental Management (EM)

    Shiprock Archived Soil & Groundwater Master Reports Shiprock Archived Soil & Groundwater Master Reports Shiprock Archived Soil & Groundwater Master Reports Shiprock - Shiprock (19.31 KB) More Documents & Publications Slick Rock Archived Soil & Groundwater Master Reports Tuba City Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports

  6. Spook Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Environmental Management (EM)

    Spook Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports Spook - Spook (17.91 KB) More Documents & Publications Tuba City Archived Soil & Groundwater Master Reports Slick Rock Archived Soil & Groundwater Master Reports Weldon Spring Site Archived Soil & Groundwater Master Reports

  7. Oil to soil fluorescence-a vital link

    SciTech Connect (OSTI)

    Calhoun, G.G. )

    1994-03-01

    The aromatic component in oils may prove to be the key to defining oil traps in mature basins as well as pioneer areas. This is a direct indication of vertical oil migration and can precisely duplicate the oil signature in soil samples. This study traces the changes that occur in San Andres oils over the Permian basin. The sequence of sync-scans along the Central Basin platform pictures the gradual changes in the mix of lighter aromatics in the north toward predominately heavier aromatics in the south. This change parallels decreasing depth, freshening of formations waters, and decreased gravity of the oil. A comparison of oils and their source rocks is presented for the Woodford, Pennsylvanian, and Wolfcamp generation-migration systems. The sieving effect of the source shales is evident in the higher concentrations of complex molecules retained in the source rock as compared to the resultant oils trapped in conventional reservoir rocks. Movable oil retained in the source rock is also evident using synchronous scans. Productive areas are reflected at the surface with oil to soil correlation coefficients up to 90%. Barren areas are often evident in soil samples by their close resemblance to the source rock signature. The contrast between productive and barren area is also evident in a 100+% increase in the concentration of the various families of compounds-Benzenes, Naphthalenes, Phenanthrenes-Anthracene, and compounds containing five or more aromatic rings. Any surface geochemical evaluation should include no less than three techniques, and one of these should be soil fluorescence. No other geochemical technique can identify the source of microseeping oil. Only fluorescence cannot only say [open quotes]yes[close quotes] or [open quotes]no,[close quotes] but can also name the objective horizon.

  8. Clay slurry and engineered soils as containment technologies for remediation of contaminated sites

    SciTech Connect (OSTI)

    Williams, J.R.; Dudka, S.; Miller, W.P.; Johnson, D.O.

    1997-12-31

    Clay Slurry and Engineered Soils are containment technologies for remediation of waste disposal sites where leaching, groundwater plumes and surface runoff of contaminants are serious ecological hazards to adjacent environments. This technology is a patent-pending process which involves the use of conditioned clay materials mixed with sand and water to form a readily pourable suspension, a clay slurry, which is either placed into a trench barrier system or allowed to de-water to create Engineered Soils. The Engineered Soil forms a layer impervious to water and air, therefore by inhibiting both water and oxygen from penetrating through the soil the material. This material can be installed in layers and as a vertical barrier to create a surface barrier containment system. The clay percentage in the clay slurry and Engineered Soils varies depending on site characteristics and desired performance standards. For example Engineered Soils with 1-2% of clay (dry wt.) had a hydraulic conductivity (K) of 10{sup -8} to 10{sup -1} cm/sec. Tests of tailing materials from a kyanite and pyrite mine showed that the clay slurry was effective not only in reducing the permeability of the treated tailings, but also in decreasing their acidity due to the inherent alkalinity of the clay. The untreated tailings had pH values in the range of 2.4 - 3.1; whereas, the effluent from clay and tailings mixtures had pH values in a slightly alkaline range (7.7-7.9). Pug-mills and high volume slurry pumps can be readily adapted for use in constructing and placing caps and creating Engineered Soils. Moreover, material on site or from a local sand supply can be used to create clay slurries and engineered soils. Clay materials used in cap construction are likewise readily available commercially. As a result, the clay slurry system is very cost effective compared to other capping systems, including the commonly used High Density Polyethylene (HDPE) liner systems.

  9. ALTERNATIVE FIELD METHODS TO TREAT MERCURY IN SOIL

    SciTech Connect (OSTI)

    Ernest F. Stine Jr; Steven T. Downey

    2002-08-14

    U.S. Department of Energy (DOE) used large quantities of mercury in the uranium separating process from the 1950s until the late 1980s in support of national defense. Some of this mercury, as well as other hazardous metals and radionuclides, found its way into, and under, several buildings, soil and subsurface soils and into some of the surface waters. Several of these areas may pose potential health or environmental risks and must be dealt with under current environmental regulations. DOE's National Energy Technology Laboratory (NETL) awarded a contract ''Alternative Field Methods to Treat Mercury in Soil'' to IT Group, Knoxville TN (IT) and its subcontractor NFS, Erwin, TN to identify remedial methods to clean up mercury-contaminated high-clay content soils using proven treatment chemistries. The sites of interest were the Y-12 National Security Complex located in Oak Ridge, Tennessee, the David Witherspoon properties located in Knoxville, Tennessee, and at other similarly contaminated sites. The primary laboratory-scale contract objectives were (1) to safely retrieve and test samples of contaminated soil in an approved laboratory and (2) to determine an acceptable treatment method to ensure that the mercury does not leach from the soil above regulatory levels. The leaching requirements were to meet the TC (0.2 mg/l) and UTS (0.025 mg/l) TCLP criteria. In-situ treatments were preferred to control potential mercury vapors emissions and liquid mercury spills associated with ex-situ treatments. All laboratory work was conducted in IT's and NFS laboratories. Mercury contaminated nonradioactive soil from under the Alpha 2 building in the Y-12 complex was used. This soils contained insufficient levels of leachable mercury and resulted in TCLP mercury concentrations that were similar to the applicable LDR limits. The soil was spiked at multiple levels with metallic (up to 6000 mg/l) and soluble mercury compounds (up to 500 mg/kg) to simulate expected ranges of mercury

  10. Barrier erosion control test plan: Gravel mulch, vegetation, and soil water interactions

    SciTech Connect (OSTI)

    Waugh, W.J.; Link, S.O. (Pacific Northwest Lab., Richland, WA (USA))

    1988-07-01

    Soil erosion could reduce the water storage capacity of barriers that have been proposed for the disposal of near-surface waste at the US Department of Energy's Hanford Site. Gravel mixed into the top soil surface may create a self-healing veneer that greatly retards soil loss. However, gravel admixtures may also enhance infiltration of rainwater, suppress plant growth and water extraction, and lead to the leaching of underlying waste. This report describes plans for two experiments that were designed to test hypotheses concerning the interactive effects of surface gravel admixtures, revegetation, and enhanced precipitation on soil water balance and plant abundance. The first experiment is a factorial field plot set up on the site selected as a soil borrow area for the eventual construction of barriers. The treatments, arranged in a a split-split-plot design structure, include two densities of gravel admix, a mixture of native and introduced grasses, and irrigation to simulate a wetter climate. Changes in soil water storage and plant cover are monitored with neutron moisture probes and point intercept sampling, respectively. The second experiment consists of an array of 80 lysimeters containing several different barrier prototypes. Surface treatments are similar to the field-plot experiment. Drainage is collected from a valve at the base of each lysimeter tube, and evapotranspiration is estimated by subtraction. The lysimeters are also designed to be coupled to a whole-plant gas exchange system that will be used to conduct controlled experiments on evapotranspiration for modeling purposes. 56 refs., 6 figs., 8 tabs.

  11. Effect of altitude on the carbon-isotope composition of forest and grassland soils from Papua New Guinea

    SciTech Connect (OSTI)

    Bird, M.I.; Haberle, S.G.; Chivas, A.R. )

    1994-03-01

    The stable isotope composition of carbon can be used to provide information on the origin of carbon in soil organic matter. This study looks at the effect of decreasing temperature and atmospheric pressure (altitude) on the carbon-isotope composition of soil organic carbon from forests and grasslands in tropical regions. Investigators examine whether a predictable relationship exists between vegetation type, the 13C value of surface soil organic matter, and altitude. The results provide a framework within which to more accurately constrain the carbon-isotope composition of terrestrial carbon ppls and to interpret the observed variations in the isotopic composition of rivere particulate organic carbon. 31 refs., 5 figs., 1 tab.

  12. Innovative Vitrification for Soil Remediation

    SciTech Connect (OSTI)

    Hnat, James G.; Patten, John S.; Jetta, Norman W.

    1996-12-31

    Vortec has successfully completed Phases 1 and 2 of a technology demonstration program for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation.'' The principal objective of the program is to demonstrate the ability of a Vortec Cyclone Melting System (CMS) to remediate DOE contaminated soils and other waste forms containing TM RCRA hazardous materials, low levels of radionuclides and TSCA (PCB) containing wastes. The demonstration program will verify the ability of this vitrification process to produce a chemically stable glass final waste form which passes both TCLP and PCT quality control requirements, while meeting all federal and state emission control regulations. The demonstration system is designed to process 36 ton/day of as-received drummed or bulk wastes. The processing capacity equates to approximately 160 barrels/day of waste materials containing 30% moisture at an average weight of 450 lbs./barrel.

  13. Fluorinated silica microchannel surfaces

    DOE Patents [OSTI]

    Kirby, Brian J.; Shepodd, Timothy Jon

    2005-03-15

    A method for surface modification of microchannels and capillaries. The method produces a chemically inert surface having a lowered surface free energy and improved frictional properties by attaching a fluorinated alkane group to the surface. The coating is produced by hydrolysis of a silane agent that is functionalized with either alkoxy or chloro ligands and an uncharged C.sub.3 -C.sub.10 fluorinated alkane chain. It has been found that the extent of surface coverage can be controlled by controlling the contact time from a minimum of about 2 minutes to a maximum of 120 minutes for complete surface coverage.

  14. Determination of the potential for release of mercury from combustion product amended soils: Part 1 - Simulations of beneficial use

    SciTech Connect (OSTI)

    Mae Sexauer Gustin; Jody Ericksen; George C. Fernandez

    2008-05-15

    This paper describes a project that assessed the potential for mercury (Hg) release to air and water from soil amended with combustion products to simulate beneficial use. Combustion products (ash) derived from wood, sewage sludge, subbituminous coal, and a subbituminous coal-petroleum coke mixture were added to soil as agricultural supplements, soil stabilizers, and to develop low permeability surfaces. Hg release was measured from the latter when intact and after it was broken up and mixed into the soil. Air-substrate Hg exchange was measured for all materials six times over 24 hr, providing data that reflected winter, spring, summer, and fall meteorological conditions. Dry deposition of atmospheric Hg and emission of Hg to the atmosphere were both found to be important fluxes. Measured differences in seasonal and diel (24 hr) fluxes demonstrated that to establish an annual estimate of air-substrate flux from these materials data on both of these time steps should be collected. Air-substrate exchange was highly correlated with soil and air temperature, as well as incident light. Hg releases to the atmosphere from coal and wood combustion product-amended soils to simulate an agricultural application were similar to that measured for the unamended soil, whereas releases to the air for the sludge-amended materials were higher. Hg released to soil solutions during the Synthetic Precipitation Leaching Procedure for ashamended materials was higher than that released from soil alone. On the basis of estimates of annual releases of Hg to the air from the materials used, emissions from coal and wood ash-amended soil to simulate an agricultural application could simply be re-emission of Hg deposited by wet processes from the atmosphere; however, releases from sludge-amended materials and those generated to simulate soil stabilization and disturbed low-permeability pads include Hg indigenous to the material. 37 refs., 5 figs., 4 tabs.

  15. T-TY Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY10 Report

    SciTech Connect (OSTI)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

    2011-01-01

    The U.S. Department of Energy’s Office of River Protection has constructed interim surface barriers over a portion of the T and TY tank farms as part of the Interim Surface Barrier Demonstration Project. The interim surface barriers (hereafter referred to as the surface barriers or barriers) are designed to minimize the infiltration of precipitation into the soil zones containing radioactive contaminants and minimize the movement of the contaminants. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barriers at reducing soil moisture. Solar-powered systems were installed to continuously monitor soil water conditions at four locations in the T (i.e., instrument Nests TA, TB, TC, and TD) and the TY (i.e., instrument Nests TYA and TYB) Farms beneath the barriers and outside the barrier footprint as well as site meteorological conditions. Nests TA and TYA are placed in the area outside the barrier footprint and serve as controls, providing subsurface conditions outside the influence of the surface barriers. Nest TB provides subsurface measurements to assess surface-barrier edge effects. Nests TC, TD, and TYB are used to assess changes in soil-moisture conditions beneath the interim surface barriers.

  16. Multi-analytical approach reveals potential microbial indicators in soil for sugarcane model systems

    SciTech Connect (OSTI)

    Navarrete, Acacio Aparecido; Diniz, Tatiana Rosa; Braga, Lucas Palma Perez; Silva, Genivaldo Gueiros Zacarias; Franchini, Julio Cezar; Rossetto, Raffaella; Edwards, Robert Alan; Tsai, Siu Mui; Lehman, R. Michael

    2015-06-09

    This study focused on the effects of organic and inorganic amendments and straw retention on the microbial biomass (MB) and taxonomic groups of bacteria in sugarcane-cultivated soils in a greenhouse mesocosm experiment monitored for gas emissions and chemical factors. The experiment consisted of combinations of synthetic nitrogen (N), vinasse (V; a liquid waste from ethanol production), and sugarcane-straw blankets. Increases in CO2-C and N2O-N emissions were identified shortly after the addition of both N and V to the soils, thus increasing MB nitrogen (MB-N) and decreasing MB carbon (MB-C) in the N+V-amended soils and altering soil chemical factors that were correlated with the MB. Across 57 soil metagenomic datasets, Actinobacteria (31.5%), Planctomycetes (12.3%), Deltaproteobacteria (12.3%), Alphaproteobacteria (12.0%) and Betaproteobacteria (11.1%) were the most dominant bacterial groups during the experiment. Differences in relative abundance of metagenomic sequences were mainly revealed for Acidobacteria, Actinobacteria, Gammaproteobacteria and Verrucomicrobia with regard to N+V fertilization and straw retention. Differential abundances in bacterial groups were confirmed using 16S rRNA gene-targeted phylum-specific primers for real-time PCR analysis in all soil samples, whose results were in accordance with sequence data, except for Gammaproteobacteria. Actinobacteria were more responsive to straw retention with Rubrobacterales, Bifidobacteriales and Actinomycetales related to the chemical factors of N+V-amended soils. Acidobacteria subgroup 7 and Opitutae, a verrucomicrobial class, were related to the chemical factors of soils without straw retention as a surface blanket. Taken together, the results showed that MB-C and MB-N responded to changes in soil chemical factors and CO2-C and N2O-N emissions

  17. Multi-analytical approach reveals potential microbial indicators in soil for sugarcane model systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Navarrete, Acacio Aparecido; Diniz, Tatiana Rosa; Braga, Lucas Palma Perez; Silva, Genivaldo Gueiros Zacarias; Franchini, Julio Cezar; Rossetto, Raffaella; Edwards, Robert Alan; Tsai, Siu Mui; Lehman, R. Michael

    2015-06-09

    This study focused on the effects of organic and inorganic amendments and straw retention on the microbial biomass (MB) and taxonomic groups of bacteria in sugarcane-cultivated soils in a greenhouse mesocosm experiment monitored for gas emissions and chemical factors. The experiment consisted of combinations of synthetic nitrogen (N), vinasse (V; a liquid waste from ethanol production), and sugarcane-straw blankets. Increases in CO2-C and N2O-N emissions were identified shortly after the addition of both N and V to the soils, thus increasing MB nitrogen (MB-N) and decreasing MB carbon (MB-C) in the N+V-amended soils and altering soil chemical factors that weremore » correlated with the MB. Across 57 soil metagenomic datasets, Actinobacteria (31.5%), Planctomycetes (12.3%), Deltaproteobacteria (12.3%), Alphaproteobacteria (12.0%) and Betaproteobacteria (11.1%) were the most dominant bacterial groups during the experiment. Differences in relative abundance of metagenomic sequences were mainly revealed for Acidobacteria, Actinobacteria, Gammaproteobacteria and Verrucomicrobia with regard to N+V fertilization and straw retention. Differential abundances in bacterial groups were confirmed using 16S rRNA gene-targeted phylum-specific primers for real-time PCR analysis in all soil samples, whose results were in accordance with sequence data, except for Gammaproteobacteria. Actinobacteria were more responsive to straw retention with Rubrobacterales, Bifidobacteriales and Actinomycetales related to the chemical factors of N+V-amended soils. Acidobacteria subgroup 7 and Opitutae, a verrucomicrobial class, were related to the chemical factors of soils without straw retention as a surface blanket. Taken together, the results showed that MB-C and MB-N responded to changes in soil chemical factors and CO2-C and N2O-N emissions, especially for N+V-amended soils. The results also indicated that several taxonomic groups of bacteria, such as Acidobacteria, Actinobacteria and

  18. Identification of sediment sources in forested watersheds with surface coal mining disturbance using carbon and nitrogen isotopes

    SciTech Connect (OSTI)

    Fox, J.F.

    2009-10-15

    Sediments and soils were analyzed using stable carbon and nitrogen isotope ratio mass spectrometry and carbon and nitrogen elemental analyses to evaluate the their ability to indicate land-use and land management disturbance and pinpoint loading from sediment transport sources in forested watersheds disturbed by surface coal mining. Samples of transported sediment particulate organic matter were collected from four watersheds in the Southern Appalachian forest in Kentucky. The four watersheds had different surface coal mining history that were classified as undisturbed, active mining, and reclaimed conditions. Soil samples were analyzed including reclaimed grassland soils, undisturbed forest soils, geogenic organic matter associated with coal fragments in mining spoil, and soil organic matter from un-mined grassland soils. Statistically significant differences were found for all biogeochemical signatures when comparing transported sediments from undisturbed watersheds and surface coal mining disturbed watersheds and the results were attributed to differences in erosion sources and the presence of geogenic organic matter. Sediment transport sources in the surface coal mining watersheds analyzed using Monte Carlo mass balance un-mixing found that: {delta}{sup 15}N showed the ability to differentiate streambank erosion and surface soil erosion; and {delta} {sup 13}C showed the ability to differentiate soil organic matter and geogenic organic matter. This suggests that streambank erosion downstream of surface coal mining sites is a significant source of sediment in coal mining disturbed watersheds. The results suggest that the sediment transport processes governing streambank erosion loads are taking longer to reach geomorphologic equilibrium in the watershed as compared with the surface erosion processes.

  19. Code System Calculate One-Dimensional Vertical Transport Unsaturated Soil Zone

    Energy Science and Technology Software Center (OSTI)

    1989-03-01

    SESOIL, as an integrated screening-level soil compartment model, is designed to simultaneously model water transport, sediment transport, and pollutant fate. SESOIL is a one-dimensional vertical transport model for the unsaturated soil zone. Only one compound at a time can be considered. The model is based on mass balance and equilibrium partitioning of the chemical between different phases (dissolved, sorbed, vapor, and pure). The SESOIL model was designed to perform long-term simulations of chemical transport andmore » transformations in the soil and uses theoretically derived equations to represent water transport, sediment transport on the land surface, pollutant transformation, and migration of the pollutant to the atmosphere and groundwater. Climatic data, compartment geometry, and soil and chemical property data are the major components used in the equations. SESOIL was developed as a screening-level model, utilizing less soil, chemical, and meteorological values as input than most other similar models. Output of SESOIL includes time-varying pollutant concentrations at various soil depths and pollutant loss from the unsaturated zone in terms of surface runoff, percolation to the groundwater, volatilization, and degradation. The February 1995 release corrects an error that caused the code to fail when average monthly air temperature was -10C and includes an improved iteration procedure for the mass balance equations in the model. PLEASE NOTE: The RISKPRO information management software (see OTHER PROG/OPER SYS INFO) was used by the developers of the New SESOIL User''s Guide in their study and revisions of SESOIL. Using RISKPRO in conjunction with SESOIL is an option, and it may provide the easiest way to use SESOIL. The other option, use of SESOIL in stand-alone mode, has been tested and used. The stand-alone option is covered in ''Instructions for Running Stand-Alone SESOIL Code'', and in ''A Seasonal Soil Compartment Model''.« less

  20. Comparison of Laboratory and Field Methods for Determining the Quasi-Saturated Hydraulic Conductivity of Soils

    SciTech Connect (OSTI)

    Faybishenko, Boris

    1997-08-01

    Laboratory and field ponded infiltration tests in quasi-saturated soils (containing entrapped air) exhibit the same three-stage temporal variability for the flow rate and hydraulic conductivity. However, the values for the hydraulic conductivity may differ by as much as two orders of magnitude due to differences in the geometry and physics of flow when different laboratory and field methods are applied. The purpose of this paper is to investigate this variability using a comparison of results of ponded infiltration tests conducted under laboratory conditions using confined cores, with results of field tests conducted using partially isolated cores and double-ring infiltrometers. Under laboratory conditions in confined cores, during the firs stage, the water flux decreases over time because entrapped air plugs the largest pores in the soils; during the second stage, the quasi-saturated hydraulic conductivity increases by one to two orders of magnitude, essentially reaching the saturated hydraulic conductivity, when entrapped air is discharged from the soils; during the third stage, the hydraulic conductivity decreases to minimum values due to sealing of the soil surface and the effect of biofilms sealing the pores within the wetted zone. Under field conditions, the second stage is only partially developed, and when the surface sealing process begins, the hydraulic pressure drops below the air entry value, thereby causing atmospheric air to enter the soils. As a result, the soils become unsaturated with a low hydraulic conductivity, and the infiltration rate consequently decreases. Contrary to the laboratory experiments in confined cores, the saturated hydraulic conductivity cannot be reached under field conditions. In computations of infiltration one has to take into account the variations in the quasi-saturated and unsaturated hydraulic conductivities, moisture and entrapped air content, and the hydraulic gradient in the quasi-saturated or unsaturated soils.

  1. ARM - Measurement - Surface condition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    condition ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface condition State of the surface, including vegetation, land use, surface type, roughness, and such; often provided in model output. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list

  2. Mississippi exploration field trials using microbial, radiometrics, free soil gas, and other techniques

    SciTech Connect (OSTI)

    Moody, J.S.; Brown, L.R.; Thieling, S.C.

    1995-12-31

    The Mississippi Office of Geology has conducted field trials using the surface exploration techniques of geomicrobial, radiometrics, and free soil gas. The objective of these trials is to determine if Mississippi oil and gas fields have surface hydrocarbon expression resulting from vertical microseepage migration. Six fields have been surveyed ranging in depth from 3,330 ft to 18,500 ft. The fields differ in trapping styles and hydrocarbon type. The results so far indicate that these fields do have a surface expression and that geomicrobial analysis as well as radiometrics and free soil gas can detect hydrocarbon microseepage from pressurized reservoirs. All three exploration techniques located the reservoirs independent of depth, hydrocarbon type, or trapping style.

  3. Surface cleanliness measurement procedure

    DOE Patents [OSTI]

    Schroder, Mark Stewart; Woodmansee, Donald Ernest; Beadie, Douglas Frank

    2002-01-01

    A procedure and tools for quantifying surface cleanliness are described. Cleanliness of a target surface is quantified by wiping a prescribed area of the surface with a flexible, bright white cloth swatch, preferably mounted on a special tool. The cloth picks up a substantial amount of any particulate surface contamination. The amount of contamination is determined by measuring the reflectivity loss of the cloth before and after wiping on the contaminated system and comparing that loss to a previous calibration with similar contamination. In the alternative, a visual comparison of the contaminated cloth to a contamination key provides an indication of the surface cleanliness.

  4. Performance evaluation soil samples utilizing encapsulation technology

    DOE Patents [OSTI]

    Dahlgran, James R.

    1999-01-01

    Performance evaluation soil samples and method of their preparation using encapsulation technology to encapsulate analytes which are introduced into a soil matrix for analysis and evaluation by analytical laboratories. Target analytes are mixed in an appropriate solvent at predetermined concentrations. The mixture is emulsified in a solution of polymeric film forming material. The emulsified solution is polymerized to form microcapsules. The microcapsules are recovered, quantitated and introduced into a soil matrix in a predetermined ratio to form soil samples with the desired analyte concentration.

  5. Performance evaluation soil samples utilizing encapsulation technology

    DOE Patents [OSTI]

    Dahlgran, J.R.

    1999-08-17

    Performance evaluation soil samples and method of their preparation uses encapsulation technology to encapsulate analytes which are introduced into a soil matrix for analysis and evaluation by analytical laboratories. Target analytes are mixed in an appropriate solvent at predetermined concentrations. The mixture is emulsified in a solution of polymeric film forming material. The emulsified solution is polymerized to form microcapsules. The microcapsules are recovered, quantitated and introduced into a soil matrix in a predetermined ratio to form soil samples with the desired analyte concentration. 1 fig.

  6. Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural...

    Broader source: Energy.gov (indexed) [DOE]

    Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural Analysis to Identify Hidden, High Enthalpy, Extensional Geothermal Systems presentation at the April 2013 peer ...

  7. Enhanced durability transparent superhydrophobic anti-soiling...

    Office of Scientific and Technical Information (OSTI)

    Title: Enhanced durability transparent superhydrophobic anti-soiling coatings for CSP applications Authors: Polyzos, Georgios 1 ; Schaeffer, Daniel A 1 ; Smith, Barton Barton ...

  8. Soil Machine Dynamics Ltd | Open Energy Information

    Open Energy Info (EERE)

    Machine Dynamics Ltd Jump to: navigation, search Name: Soil Machine Dynamics Ltd Region: United Kingdom Sector: Marine and Hydrokinetic Website: http: This company is listed in the...

  9. Contrasting soil microbial community functional structures in...

    Office of Scientific and Technical Information (OSTI)

    two major landscapes of the Tibetan alpine meadow Prev Next Title: Contrasting soil microbial community functional structures in two major landscapes of the Tibetan alpine...

  10. Nitric oxide emissions from engineered soil systems

    SciTech Connect (OSTI)

    Peirce, J.J.; Aneja, V.P.

    2000-03-01

    Sophisticated laboratory equipment and procedures are developed and used in controlled experiments to measure nitric oxide (NO) emissions ranging from 42 to 75 ng N/m{sup 2}{center_dot}s from sludge-amended soil of concern to environmental engineers because nitric oxide emitted to the troposphere is a precursor to troublesome ozone formation and also of concern to agricultural engineers because valuable nitrogen as fertilizer is lost from the soil. Water-filled pore space is confirmed to be of critical importance to NO flux, and the upper layers of soil are determined to contribute the larger portion of the NO fluxing from the soil to the troposphere. More than 42% of the total NO flux comes from the top 1 cm of soil, with NO contributions decreasing exponentially with soil depth and very little if any tropospheric NO contributed from soil at a depth of 20 cm or greater. The results are discussed in terms of microbiological, chemical, and soil transport processes that influence NO flux from sludge-amended soil.

  11. In-Situ Contained And Of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  12. In-Situ Containment and Extraction of Volatile Soil Contaminants

    DOE Patents [OSTI]

    Varvel, Mark Darrell

    2005-12-27

    The invention relates to a novel approach to containing and removing toxic waste from a subsurface environment. More specifically the present invention relates to a system for containing and removing volatile toxic chemicals from a subsurface environment using differences in surface and subsurface pressures. The present embodiment generally comprises a deep well, a horizontal tube, at least one injection well, at least one extraction well and a means for containing the waste within the waste zone (in-situ barrier). During operation the deep well air at the bottom of well (which is at a high pressure relative to the land surface as well as relative to the air in the contaminated soil) flows upward through the deep well (or deep well tube). This stream of deep well air is directed into the horizontal tube, down through the injection tube(s) (injection well(s)) and into the contaminate plume where it enhances volatization and/or removal of the contaminants.

  13. STANDARDS CONTROLLING AIR EMISSIONS FOR THE SOIL DESICCATION PILOT TEST

    SciTech Connect (OSTI)

    BENECKE MW

    2010-09-08

    expected that Tc-99 and nitrate will remain with the water residual that is not removed, or remain as a salt bound to the soil particles. In addition, the SDPT will be conducted at lower extraction velocities to preclude pore water entrainment and thus, the extracted air effluent should be free of the contaminant residual present in the targeted moist zone. However, to conservatively bound the planned activity for potential radionuclide air emissions, it is assumed, hypothetically, that the Tc-99 does not remain in the zone of interest, but that it instead travels with the evaporated moisture to the extraction well and to the test equipment at the land surface. Thus, a release potential would exist from the planned point source (powered exhaust) for Tc-99 in the extracted moist air. In this hypothetical bounding case there would also be a potential for very minor fugitive emissions to occur due to nitrogen injection into the soil. The maximum value for Tc-99, measured in the contaminated moist zone, is used in calculating the release potential described in Section 2.3. The desiccation mechanism will be evaporation. Nitrate is neither a criteria pollutant nor a toxic air pollutant. It would remain nitrate as a salt adhered to sand and silt grains or as nitrate dissolved in the pore water. Nitrogen, an inert gas, will be injected into the ground during the test. Tracer gasses will also be injected near the beginning, middle, and the end of the test. The tracer gasses are sulfur hexafluoride, trichlorofluoromethane, and difluoromethane.

  14. T Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY08 Report

    SciTech Connect (OSTI)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

    2009-02-01

    DOE’s Office of River Protection constructed a temporary surface barrier over a portion of the T Tank Farm as part of the T Farm Interim Surface Barrier Demonstration Project. The surface barrier is designed to minimize the infiltration of precipitation into the contaminated soil zone created by the Tank T-106 leak and minimize movement of the contamination. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barrier at reducing soil moisture. A solar-powered system was installed to continuously monitor soil water conditions at four locations (i.e., instrument Nests A, B, C, and D) beneath the barrier and outside the barrier footprint as well as site meteorological conditions. Nest A is placed in the area outside the barrier footprint and serves as a control, providing subsurface conditions outside the influence of the surface barrier. Nest B provides subsurface measurements to assess surface-barrier edge effects. Nests C and D are used to assess changes in soil-moisture conditions beneath the interim surface barrier.

  15. DNA ELECTROPHORESIS AT SURFACES

    SciTech Connect (OSTI)

    RAFAILOVICH, MIRIAM; SOKOLOV, JONATHAN; GERSAPPE, DILIP

    2003-09-01

    During this year we performed two major projects: I. We developed a detailed theoretical model which complements our experiments on surface DNA electrophoresis. We found that it was possible to enhance the separation of DNA chains by imposing a chemical nanoscale pattern on the surface. This approach utilized the surface interaction effect of the DNA chains with the substrate and is a refinement to our previous method in which DNA chains were separated on homogeneous flat surfaces. By introducing the nano-patterns on the surface, the conformational changes of DNA chains of different lengths can be amplified, which results in the different friction strengths with the substrate surface. Our results also show that, when compared to the DNA electrophoresis performed on homogeneous flat surfaces, nanopatterned surfaces offer a larger window in choosing different surface interactions to achieve separation. II. In collaboration with a large international manufacturer of skin care products we also embarked on a project involving photo toxicity of titanium dioxide nanoparticles, which are a key ingredient in sunscreen and cosmetic lotions. The results clearly implicated the nanoparticles in catalyzing damage to chromosomal DNA. We then used this knowledge to develop a polymer/anti-oxidant coating which prevented the photocatalytic reaction on DNA while still retaining the UV absorptive properties of the nanoparticles. The standard gel electrophoresis was not sufficient in determining the extent of the DNA damage. The conclusions of this study were based predominantly on analysis obtained with the surface electrophoresis method.

  16. Convergence of microbial assimilations of soil carbon, nitrogen...

    Office of Scientific and Technical Information (OSTI)

    We found a convergence of the relationships between elements in soils and in soil microbial biomass across C, N, P, and S. The element concentrations in soil microbial biomass ...

  17. T Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY09 Report

    SciTech Connect (OSTI)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

    2010-01-01

    DOEs Office of River Protection constructed a temporary surface barrier over a portion of the T Tank Farm as part of the T Farm Interim Surface Barrier Demonstration Project. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barrier at reducing soil moisture. A solar-powered system was installed to continuously monitor soil water conditions at four locations (i.e., instrument Nests A, B, C, and D) beneath the barrier and outside the barrier footprint as well as site meteorological conditions. Nest A is placed in the area outside the barrier footprint and serves as a control, providing subsurface conditions outside the influence of the surface barrier. Nest B provides subsurface measurements to assess surface-barrier edge effects. Nests C and D are used to assess changes in soil-moisture conditions beneath the interim surface barrier. Each instrument nest is composed of a capacitance probe (CP) with multiple sensors, multiple heat-dissipation units (HDUs), and a neutron probe (NP) access tube. The monitoring results in FY09 are summarized below. The solar panels functioned normally and could provide sufficient power to the instruments. The CP in Nest C after September 20, 2009, was not functional. The CP sensors in Nest B after July 13 and the 0.9-m CP sensor in Nest D before June 10 gave noisy data. Other CPs were functional normally. All the HDUs were functional normally but some pressure-head values measured by HDUs were greater than the upper measurement-limit. The higher-than-upper-limit values might be due to the very wet soil condition and/or measurement error but do not imply the malfunction of the sensors. Similar to FY07 and FY08, in FY09, the soil under natural conditions (Nest A) was generally recharged during the winter period (October-March) and discharged during the summer period (April-September). Soil water conditions above about 1.5-m to 2-m depth from all three types of measurements (i

  18. Innovative vitrification for soil remediation

    SciTech Connect (OSTI)

    Jetta, N.W.; Patten, J.S.; Hnat, J.G.

    1995-10-01

    The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase I consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at a specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project.

  19. Innovative vitrification for soil remediation

    SciTech Connect (OSTI)

    Jetta, N.W.; Patten, J.S.; Hnat, J.G. [Vortec Corp., Collegeville, PA (United States)] [and others

    1996-03-01

    The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase 1 consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at a specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project.

  20. Process for removing polychlorinated biphenyls from soil

    DOE Patents [OSTI]

    Hancher, C.W.; Saunders, M.B.; Googin, J.M.

    1984-11-16

    The present invention relates to a method of removing polychlorinated biphenyls from soil. The polychlorinated biphenyls are extracted from the soil by employing a liquid organic solvent dispersed in water in the ratio of about 1:3 to 3:1. The organic solvent includes such materials as short-chain hydrocarbons including kerosene or gasoline which are immiscible with water and are nonpolar. The organic solvent has a greater affinity for the PCB's than the soil so as to extract the PCB's from the soil upon contact. The organic solvent phase is separated from the suspended soil and water phase and distilled for permitting the recycle of the organic solvent phase and the concentration of the PCB's in the remaining organic phase. The present process can be satisfactorily practiced with soil containing 10 to 20% petroleum-based oils and organic fluids such as used in transformers and cutting fluids, coolants and the like which contain PCB's. The subject method provides for the removal of a sufficient concentration of PCB's from the soil to provide the soil with a level of PCB's within the guidelines of the Environmental Protection Agency.

  1. Analysis of large soil samples for actinides

    DOE Patents [OSTI]

    Maxwell, III; Sherrod L.

    2009-03-24

    A method of analyzing relatively large soil samples for actinides by employing a separation process that includes cerium fluoride precipitation for removing the soil matrix and precipitates plutonium, americium, and curium with cerium and hydrofluoric acid followed by separating these actinides using chromatography cartridges.

  2. Data management system for organic soil

    SciTech Connect (OSTI)

    Stinnette, P.

    1999-07-01

    A Data Management System for Organic Soil (DMSOS) has been developed that enables the acquisition, management and analysis of organic soil data as well as the presentation of results to be conducted effectively through a common interface. This development was in response to the data management needs of research investigating the engineering properties of organic soil and its extension to the stabilization of organic soil through dynamic replacement (DR). It is shown how the above functions are implemented efficiently using Windows-based software to perform comprehensive data management and analysis of data gathered from both laboratory and field tests. When the engineering properties of a given organic soil deposit are needed, a build-in Computer Advisor for Organic Soil Projects (CAOSP) predicts the properties from DMSOS based correlations. A unique and useful feature of the CAOSP is its ability to estimate the anticipated ultimate settlement of an organic soil deposit given the loading conditions and the moisture or organic content. Also incorporated in the DMSOS is a quality control system that utilizes computerized data acquisition/data management techniques in order to evaluate the degree of improvement of an organic soil layer at a given stage of treatment using DR.

  3. NNSS Soils Monitoring: Plutonium Valley (CAU366)

    SciTech Connect (OSTI)

    Miller, Julianne J.; Mizell, Steve A.; Nikolich, George; Campbell, Scott

    2012-02-01

    The U.S. Department of Energy (DOE) National Nuclear Security Administration (NNSA), Nevada Site Office (NSO), Environmental Restoration Soils Activity has authorized the Desert Research Institute (DRI) to conduct field assessments of potential sediment transport of contaminated soil from Corrective Action Unit (CAU) 366, Area 11 Plutonium Valley Dispersion Sites Contamination Area (CA) during precipitation runoff events.

  4. Soil washing enhancement with solid sorbents

    SciTech Connect (OSTI)

    El-Shoubary, Y.M.; Woodmansee, D.E.

    1996-12-31

    Soil washing is a dynamic, physical process that remediates contaminated soil through two mechanisms: particle size separation and transfer of the contaminant into the (mostly) liquid stream. The performance of different sorbents and additives to remove motor oil from sea sand was tested. Hydrocyclone, attrition scrubber, and froth flotation equipment were used for the decontamination study. Sorbents and additives were mixed with soils in the attrition scrubber prior to flotation. Sorbents used were granular activated carbon, powder activated carbon, and rubber tires. Chemical additives used were calcium hydroxide, sodium carbonate, Alconox{reg_sign}, Triton{reg_sign} X-100 and Triton{reg_sign} X-114. When a froth flotation run was performed using no additive, washed soils {open_quotes}tails{close_quotes} contained 4000 ppm of total oil and grease (TOG). However, when carbon or rubber (6% by weight) was added to the contaminated soils the washed soils {open_quotes}tails{close_quotes} contained 4000 ppm of total oil and grease (TOG). The addition of sodium carbonate or calcium hydroxide (6% by weight) had same effects as sorbents. In both cases washed soil {open_quotes}tails{close_quotes} contained total oil and grease of less than 1000 ppm. The use of these non-hazardous additives or sorbent can enhance the soil washing process and consequently saves on time (residence time in equipment design) required to achieve the target clean up levels. 18 refs., 12 figs.

  5. Effect of Dead Algae on Soil Permeability

    SciTech Connect (OSTI)

    Harvey, R.S.

    2003-02-21

    Since existing basins support heavy growths of unicellular green algae which may be killed by temperature variation or by inadvertent pH changes in waste and then deposited on the basin floor, information on the effects of dead algae on soil permeability was needed. This study was designed to show the effects of successive algal kills on the permeability of laboratory soil columns.

  6. Surface modification to waveguides

    DOE Patents [OSTI]

    Timberlake, John R.; Ruzic, David N.; Moore, Richard L.; Cohen, Samuel A.; Manos, Dennis M.

    1983-01-01

    A method of treating the interior surfaces of a waveguide to improve power transmission comprising the steps of mechanically polishing to remove surface protrusions; electropolishing to remove embedded particles; ultrasonically cleaning to remove any residue; coating the interior waveguide surfaces with an alkyd resin solution or electrophoretically depositing carbon lamp black suspended in an alkyd resin solution to form a 1.mu. to 5.mu. thick film; vacuum pyrolyzing the film to form a uniform adherent carbon coating.

  7. Surface modification to waveguides

    DOE Patents [OSTI]

    Timberlake, J.R.; Ruzic, D.N.; Moore, R.L.; Cohen, S.A.; Manos, D.M.

    1982-06-16

    A method is described for treating the interior surfaces of a waveguide to improve power transmission comprising the steps of mechanically polishing to remove surface protrusions; electropolishing to remove embedded particles; ultrasonically cleaning to remove any residue; coating the interior waveguide surfaces with an alkyd resin solution or electrophoretically depositing carbon lamp black suspended in an alkyd resin solution to form a 1..mu.. to 5..mu.. thick film; vacuum pyrolyzing the film to form a uniform adherent carbon coating.

  8. Appendix PORSURF: Porosity Surface

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PORSURF-2014 Porosity Surface United States Department of Energy Waste Isolation Pilot Plant Carlsbad Field Office Carlsbad, New Mexico Compliance Recertification Application 2014 Appendix PORSURF-2014 Table of Contents PORSURF-1.0 Introduction PORSURF-2.0 Creep Closure Method PORSURF-3.0 Conceptual Model for Porosity Surface PORSURF-4.0 SANTOS Numerical Analyses PORSURF-5.0 Implementation of Porosity Surface in BRAGFLO PORSURF-6.0 Dynamic Closure of the North End and Hallways PORSURF-7.0

  9. CONTAMINATED SOIL VOLUME ESTIMATE TRACKING METHODOLOGY

    SciTech Connect (OSTI)

    Durham, L.A.; Johnson, R.L.; Rieman, C.; Kenna, T.; Pilon, R.

    2003-02-27

    The U.S. Army Corps of Engineers (USACE) is conducting a cleanup of radiologically contaminated properties under the Formerly Utilized Sites Remedial Action Program (FUSRAP). The largest cost element for most of the FUSRAP sites is the transportation and disposal of contaminated soil. Project managers and engineers need an estimate of the volume of contaminated soil to determine project costs and schedule. Once excavation activities begin and additional remedial action data are collected, the actual quantity of contaminated soil often deviates from the original estimate, resulting in cost and schedule impacts to the project. The project costs and schedule need to be frequently updated by tracking the actual quantities of excavated soil and contaminated soil remaining during the life of a remedial action project. A soil volume estimate tracking methodology was developed to provide a mechanism for project managers and engineers to create better project controls of costs and schedule. For the FUSRAP Linde site, an estimate of the initial volume of in situ soil above the specified cleanup guidelines was calculated on the basis of discrete soil sample data and other relevant data using indicator geostatistical techniques combined with Bayesian analysis. During the remedial action, updated volume estimates of remaining in situ soils requiring excavation were calculated on a periodic basis. In addition to taking into account the volume of soil that had been excavated, the updated volume estimates incorporated both new gamma walkover surveys and discrete sample data collected as part of the remedial action. A civil survey company provided periodic estimates of actual in situ excavated soil volumes. By using the results from the civil survey of actual in situ volumes excavated and the updated estimate of the remaining volume of contaminated soil requiring excavation, the USACE Buffalo District was able to forecast and update project costs and schedule. The soil volume

  10. ARM - Measurement - Surface albedo

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    albedo ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface albedo The fraction of incoming solar radiation at a surface (i.e. land, cloud top) that is effectively reflected by that surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of

  11. The cell surface

    SciTech Connect (OSTI)

    Axel, R.; Goodman, C.; Hynes, R.; Stillman, B.

    1992-12-31

    This volume contains abstracts of oral presentations and poster sessions of made at the LVII Cold Springs Symposium on Quantitative Biology, entitled The Cell Surface.

  12. Incompressible Flows Free Surfaces

    Energy Science and Technology Software Center (OSTI)

    1992-02-01

    NASA-VOF3D is a three-dimensional, transient, free surface, incompressible fluid dynamics program. It is specifically designed to calculate confined flows in a low gravity environment in which surface physics must be accurately treated. It allows multiple free surfaces with surface tension and wall adhesion and includes a partial cell treatment that allows curved boundaries and internal obstacles. Variable mesh spacing is permitted in all three coordinate directions. Boundary conditions available are rigid free-slip wall, rigid no-slipmore » wall, continuative, periodic, and specified pressure outflow boundary.« less

  13. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, J.; May, C.P.; Pemberton, B.E.; Shinn, J.; Sprague, K.

    1999-03-30

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus. 8 figs.

  14. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, Joseph; May, Christopher P.; Pemberton, Bradley E.; Shinn, Jim; Sprague, Keith

    1999-01-01

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus.

  15. Measuring spatial variability in soil characteristics

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Svoboda, John M.; Sawyer, J. Wayne; Hess, John R.; Hess, J. Richard

    2002-01-01

    The present invention provides systems and methods for measuring a load force associated with pulling a farm implement through soil that is used to generate a spatially variable map that represents the spatial variability of the physical characteristics of the soil. An instrumented hitch pin configured to measure a load force is provided that measures the load force generated by a farm implement when the farm implement is connected with a tractor and pulled through or across soil. Each time a load force is measured, a global positioning system identifies the location of the measurement. This data is stored and analyzed to generate a spatially variable map of the soil. This map is representative of the physical characteristics of the soil, which are inferred from the magnitude of the load force.

  16. Clean soil at Eniwetok and Johnston Atolls

    SciTech Connect (OSTI)

    Bramlitt, E.T.

    1990-01-01

    The Defense Nuclear Agency has managed two large-scale soil cleanups (landmass decontaminations) of plutonium contamination. Both are at Pacific Ocean atolls formerly used for nuclear weapons tests. The Eniwetok Atoll (EA) cleanup between 1977 and 1980 evaluated 390 ha of contaminated land and cleaned 50 ha by removing 80,000 m[sup 3] of contaminated soil. The Johnston Atoll (JA) cleanup is in process. It has checked 270 ha, will clean 15 ha, and plans for removal of 80,000 m[sup 3] of soil. The cleanups are similar in other respects including carbonate-based soil, in situ radiation surveys, contamination characteristics, soil excavation methods, safety, and weather. The two cleanups are in contrast relative to planning time, agencies involved, funding, documentation, environmental considerations, cleanup workforce, site beneficiaries, waste characterization, regulatory permits, management, and project duration. The most noteworthy differences are the rationale for cleanup, the cleanup process, the definition of clean, and the cost.

  17. After More Than 20 Years Operating, Hanford's Soil Vapor Extraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wise, Juan Aguilar, Doug Rybarski, and Christina Agular. The soil vapor extraction trailer is shown near Hanfords Plutonium Finishing Plant. The soil vapor extraction...

  18. South Valley Archived Soil & Groundwater Master Reports | Department...

    Broader source: Energy.gov (indexed) [DOE]

    South Valley Archived Soil & Groundwater Master Reports South Valley - South Valley Plume (16.5 KB) More Documents & Publications Slick Rock Archived Soil & Groundwater Master ...

  19. Rocky Flats Environmental Technology Site Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky ...

  20. Non-Linear Seismic Soil Structure Interaction (SSI) Method for...

    Office of Environmental Management (EM)

    Non-Linear Seismic Soil Structure Interaction (SSI) Method for Developing Non-Linear Seismic SSI Analysis Techniques Non-Linear Seismic Soil Structure Interaction (SSI) Method for ...

  1. Fate of Isolated Spills on Savannah River Site Soils

    SciTech Connect (OSTI)

    Denham, M.

    1998-01-26

    Spills of acids and bases onto Savannah River Site soils will generally be neutralized to acceptable pH levels by passage through the soils.

  2. System for Analysis of Soil-Structure Interaction (SASSI) Verification...

    Broader source: Energy.gov (indexed) [DOE]

    the System for Analysis of Soil-Structure Interaction, a computer code for performing finite element analyses of soil-structure interaction during seismic ground motions. It was...

  3. Plant stimulation of soil microbial community succession: how...

    Office of Scientific and Technical Information (OSTI)

    Plant stimulation of soil microbial community succession: how sequential expression mediates soil carbon stabilization and turnover Citation Details In-Document Search Title: Plant...

  4. Soil carbon sequestration and land use change associated with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil carbon sequestration and land use change associated with biofuel production: empirical evidence Title Soil carbon sequestration and land use change associated with biofuel...

  5. EM Soil and Groundwater Database Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EM Soil and Groundwater Database Reports EM Soil and Groundwater Database Reports Brookhaven National Laboratory - HFBR Tritium Groundwater Database Report - Brookhaven National ...

  6. Final Report Limited Soil Investigation of Project Chariot Test...

    Office of Legacy Management (LM)

    Limited Soil Investigation of Project Chariot Test Holes Cape Thompson, Alaska December ... Soil Investigation of Project Chariot Test Holes, Cape Thompson, Alaska Fairbanks ...

  7. Mapping Soil Carbon from Cradle to Grave: Identifying the Microbial...

    Office of Scientific and Technical Information (OSTI)

    Conference: Mapping Soil Carbon from Cradle to Grave: Identifying the Microbial Blueprint for Root-carbon Transformations in Soil Citation Details In-Document Search Title: Mapping...

  8. Mapping Soil Carbon from Cradle to Grave: Identifying the Microbial...

    Office of Scientific and Technical Information (OSTI)

    In-Document Search Title: Mapping Soil Carbon from Cradle to Grave: Identifying the Microbial Blueprint for Root-carbon Transformations in Soil Erin Nuccio, Lawrence...

  9. Evaluation of the Mercury Soil Mapping Geothermal Exploration...

    Open Energy Info (EERE)

    the Mercury Soil Mapping Geothermal Exploration Techniques Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Evaluation of the Mercury Soil...

  10. Worldwide organic soil carbon and nitrogen data (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Worldwide organic soil carbon and nitrogen data Citation Details In-Document Search Title: Worldwide organic soil carbon and nitrogen data You are accessing a document from the ...

  11. Soil Sampling At Yellowstone Region (Hellman & Ramsey, 2004)...

    Open Energy Info (EERE)

    Soil Sampling At Yellowstone Region (Hellman & Ramsey, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Soil Sampling At Yellowstone Region...

  12. ARM - Measurement - Sea surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sea surface temperature The temperature of sea water near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  13. Identification of slip surface location by TLS-GPS datafor landslide mitigation case study: Ciloto-Puncak, West Java

    SciTech Connect (OSTI)

    Sadarviana, Vera Hasanuddin, A. Z.; Joenil, G. K.; Irwan; Wijaya, Dudy; Ilman, H.; Agung, N.; Achmad, R. T.; Pangeran, C.; Martin, S.; Gamal, M.; Santoso, Djoko

    2015-04-24

    Landslide can prevented by understanding the direction of movement to the safety evacuation track or slip surface location to hold avalanches. Slip surface is separating between stable soil and unstable soil in the slope. The slip surface location gives information about stable material depth. The information can be utilize to mitigate technical step, such as pile installation to keep construction or settlement safe from avalanches.There are two kinds landslide indicators which are visualization and calculation. By visualization, landslide identified from soil crack or scarp. Scarp is a scar of exposed soil on the landslide. That identification can be done by Terrestrial Laser Scanner (TLS) Image. Shape of scarp shows type of slip surface, translation or rotational. By calculation, kinematic and dynamic mathematic model will give vector, velocity and acceleration of material movement. In this calculation need velocity trend line at GPS point from five GPS data campaign. From intersection of trend lines it will create curves or lines of slip surface location. The number of slip surface can be known from material movement direction in landslide zone.Ciloto landslide zone have complicated phenomenon because that zone have influence from many direction of ground water level pressure. The pressure is causes generating several slip surface in Ciloto zone. Types of Ciloto slip surface have mix between translational and rotational type.

  14. Post-Closure Groundwater Monitoring Plan for the 1324-N Surface Impoundment and 1324-NA Percolation Pond

    SciTech Connect (OSTI)

    Hartman, Mary J.

    2004-04-02

    The 1324-N Surface Impoundment and the 1324-NA Percolation Pond, located in the 100-N Area of the Hanford Site, are regulated under the Resource Consevation and Recovery Act (RCRA). Surface and underground features of the facilities have been removed and laboratory analyses showed that soil met the closure performance standards. These sites have been backfilled and revegetated.

  15. Solar absorption surface panel

    DOE Patents [OSTI]

    Santala, Teuvo J.

    1978-01-01

    A composite metal of aluminum and nickel is used to form an economical solar absorption surface for a collector plate wherein an intermetallic compound of the aluminum and nickel provides a surface morphology with high absorptance and relatively low infrared emittance along with good durability.

  16. Long-term soil warming and Carbon Cycle Feedbacks to the Climate System

    SciTech Connect (OSTI)

    Melillo, Jerry M.

    2014-04-30

    The primary objective of the proposed research was to quantify and explain the effects of a sustained in situ 5oC soil temperature increase on net carbon (C) storage in a northeastern deciduous forest ecosystem. The research was done at an established soil warming experiment at the Harvard Forest in central Massachusetts – Barre Woods site established in 2001. In the field, a series of plant and soil measurements were made to quantify changes in C storage in the ecosystem and to provide insights into the possible relationships between C-storage changes and nitrogen (N) cycling changes in the warmed plots. Field measurements included: 1) annual woody increment; 2) litterfall; 3) carbon dioxide (CO2) efflux from the soil surface; 4) root biomass and respiration; 5) microbial biomass; and 6) net N mineralization and net nitrification rates. This research was designed to increase our understanding of how global warming will affect the capacity of temperate forest ecosystems to store C. The work explored how soil warming changes the interactions between the C and N cycles, and how these changes affect land-atmosphere feedbacks. This core research question framed the project – What are the effects of a sustained in situ 5oC soil temperature increase on net carbon (C) storage in a northeastern deciduous forest ecosystem? A second critical question was addressed in this research – What are the effects of a sustained in situ 5{degrees}C soil temperature increase on nitrogen (N) cycling in a northeastern deciduous forest ecosystem?

  17. Innovative vitrification for soil remediation

    SciTech Connect (OSTI)

    Jetta, N.W.; Patten, J.S.; Hart, J.G.

    1995-12-01

    The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase 1 consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at a specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project. During Phase 2, the basic nitrification process design was modified to meet the specific needs of the new waste streams available at Paducah. The system design developed for Paducah has significantly enhanced the processing capabilities of the Vortec vitrification process. The overall system design now includes the capability to shred entire drums and drum packs containing mud, concrete, plastics and PCB`s as well as bulk waste materials. This enhanced processing capability will substantially expand the total DOE waste remediation applications of the technology.

  18. Spray-on anti-soiling coatings that exhibit high transparency and mechanical durability

    SciTech Connect (OSTI)

    Schaeffer, Daniel A; Polyzos, Georgios; Smith, Barton; Lee, Dominic F; Rajic, Slobodan; Datskos, Panos G; Hunter, Scott Robert

    2014-01-01

    A superhydrophobic (SH) surface has many characteristics, one of which is its self-cleaning, anti-soiling functionality, that are desirable across various industries. A transparent, self-cleaning surface utilizes the right combination of surface chemistry and roughness that force water droplets to form high water contact angles (CA). This in turn allows droplets to easily roll off and pick up dirt and debris across the surface. In theory this is simple but in practice this can be very difficult as superhydrophobicity and optical transparency are competitive. We have developed a simple, spray-on coating based on functionalized SiO2 nanoparticles that can easily be applied to surfaces whose application requires high transparency including, but not limited to, optical sensors, photovoltaics, sights, and lenses. In addition, these coatings exhibit practical mechanical and environmental durability that allow prolonged use of the coatings in harsh environments.

  19. Thermal Removal of Tritium from Concrete and Soil to Reduce Groundwater Impacts - 13197

    SciTech Connect (OSTI)

    Jackson, Dennis G.; Blount, Gerald C.; Wells, Leslie H.; Cardoso, Joao E.; Kmetz, Thomas F.; Reed, Misty L.

    2013-07-01

    Legacy heavy-water moderator operations at the Savannah River Site (SRS) have resulted in the contamination of equipment pads, building slabs, and surrounding soil with tritium. At the time of discovery the tritium had impacted the shallow (< 3-m) groundwater at the facility. While tritium was present in the groundwater, characterization efforts determined that a significant source remained in a concrete slab at the surface and within the associated vadose zone soils. To prevent continued long-term impacts to the shallow groundwater a CERCLA non-time critical removal action for these source materials was conducted to reduce the leaching of tritium from the vadose zone soils and concrete slabs. In order to minimize transportation and disposal costs, an on-site thermal treatment process was designed, tested, and implemented. The on-site treatment consisted of thermal detritiation of the concrete rubble and soil. During this process concrete rubble was heated to a temperature of 815 deg. C (1,500 deg. F) resulting in the dehydration and removal of water bound tritium. During heating, tritium contaminated soil was used to provide thermal insulation during which it's temperature exceeded 100 deg. C (212 deg. F), causing drying and removal of tritium. The thermal treatment process volatiles the water bound tritium and releases it to the atmosphere. The released tritium was considered insignificant based upon Clean Air Act Compliance Package (CAP88) analysis and did not exceed exposure thresholds. A treatability study evaluated the effectiveness of this thermal configuration and viability as a decontamination method for tritium in concrete and soil materials. Post treatment sampling confirmed the effectiveness at reducing tritium to acceptable waste site specific levels. With American Recovery and Reinvestment Act (ARRA) funding three additional treatment cells were assembled utilizing commercial heating equipment and common construction materials. This provided a total

  20. Polychlorodibenzo-p-dioxins and polychlorodibenzofurans in the soil near the municipal incinerator of Florence, Italy

    SciTech Connect (OSTI)

    Berlincioni, M.; di Domenico, A.

    1987-11-01

    Tetra- to octachlorinated dibenzo-p-dioxin (PCDD) and dibenzofuran (PCDF) emissions from the municipal incinerator near Florence were monitored during 1980-1985. Typical PCDD or PCDF series concentrations in vapors and smokes ranged from 10/sup 2/ to 10/sup 3/ ng/m/sup 3/. The more chlorinated congeners generally exhibited levels remarkably higher than the less chlorinated ones. Contrary to earlier findings, fly ash in 1985 contributed <10% of overall PCDD and PCDF emissions. Most topsoil sampling sites in the study area were within approximately 1 km of the incineration plant. Findings from 1979 to 1985 indicated the presence of widespread contamination: this was due to the more chlorinated PCDD and PCDF congeners, in particular. The maximum level found was in the order of 2 x 10/sup 4/ ng/m/sup 2/ of soil surface. In late 1985, five soil sampling sites were selected near the site that had previously shown the highest PCDD and PCDF levels. Each soil specimen was obtained by coring the 20 cm thick upper layer. Results were qualitatively and quantitatively consistent and confirmed the prevailing presence of the more chlorinated congeners. Maximum PCDD content was approximately 7 x 10/sup 4/ ng/m/sup 2/ of soil surface. 18 references, 5 figures, 4 tables.

  1. Site-specific analysis of radiological and physical parameters for cobbly soils at the Gunnison, Colorado, processing site

    SciTech Connect (OSTI)

    Not Available

    1993-10-01

    The remedial action at the Gunnison, Colorado, processing site is being performed under the Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978 [Public Law (PL) 95-6041]. Under UMTRCA, the US Environmental Protection Agency (EPA) is charged with the responsibility of developing appropriate and applicable standards for the cleanup of radiologically contaminated land and buildings at 24 designated sites, including the Gunnison, Colorado, inactive processing site. The remedial action at the processing site will be conducted to remove the tailings and contaminated materials to meet the EPA bulk soil cleanup standards for surface and subsurface soils. The site areas disturbed by remedial action excavation will be either contoured or backfilled with radiologically uncontaminated soil and contoured to restore the site. The final contours will produce a final surface grade that will create positive drainage from the site.

  2. Nonfunctionalized Polydimethyl Siloxane Superhydrophobic Surfaces...

    Office of Scientific and Technical Information (OSTI)

    Surfaces Based on Hydrophobic-Hydrophilic Interactions Citation Details In-Document Search Title: Nonfunctionalized Polydimethyl Siloxane Superhydrophobic Surfaces Based ...

  3. In situ chemical fixation of arsenic-contaminated soils: Anexperimental study

    SciTech Connect (OSTI)

    Yang, Li; Donahoe, Rona J.; Redwine, James C.

    2007-03-27

    procedure (TCLP) and EPA Method 1312 [USEPA.Method 1312:synthetic precipitation leaching procedure. Test methods for evaluatingsolid waste, physical/chemical methods. 3rd ed. Washington, DC: U.S.Environmental Protection Agency, Office of Solid Waste. U.S. GovernmentPrinting Office; 1994]synthetic precipitation leaching procedure(SPLP).Both FW and BH soils showed significant decreases in arsenicleachability for all three treatment solutions, compared to untreatedsoil. While soils treated with solution (3) showed the best results withsubsequent TCLP sequential leaching, SPLP sequential leaching of treatedsoils indicated that lowest arsenic mobility was obtained using treatmentsolution (1). Treatment solution (1) with only FeSO4 is considered thebest choice for remediation of arsenic-contaminated soil because SPLPsequential leaching better simulates natural weathering. Analysis oftreated soils produced no evidence of newly-formed arsenic-bearing phasesin either soil after treatment. Sequential chemical extractions oftreated soils indicate that surface complexation of arsenic on ferrichydroxide is the major mechanism for the fixation process.

  4. Study on the reduction of atmospheric mercury emissions from mine waste enriched soils through native grass cover in the Mt. Amiata region of Italy

    SciTech Connect (OSTI)

    Fantozzi, L.; Dini, F.; Tamburello, L.; Pirrone, N.; Sprovieri, F.

    2013-08-15

    Atmospheric mercury emissions from mine-waste enriched soils were measured in order to compare the mercury fluxes of bare soils with those from other soils covered by native grasses. Our research was conducted near Mt. Amiata in central Italy, an area that was one of the largest and most productive mining centers in Europe up into the 1980s. To determine in situ mercury emissions, we used a Plexiglas flux chamber connected to a portable mercury analyzer (Lumex RA-915+). This allowed us to detect, in real time, the mercury vapor in the air, and to correlate this with the meteorological parameters that we examined (solar radiation, soil temperature, and humidity). The highest mercury flux values (8000 ng m{sup −2} h{sup −1}) were observed on bare soils during the hours of maximum insulation, while lower values (250 ng m{sup −2} h{sup −1}) were observed on soils covered by native grasses. Our results indicate that two main environmental variables affect mercury emission: solar radiation intensity and soil temperature. The presence of native vegetation, which can shield soil surfaces from incident light, reduced mercury emissions, a result that we attribute to a drop in the efficiency of mercury photoreduction processes rather than to decreases in soil temperature. This finding is consistent with decreases in mercury flux values down to 3500 ng m{sup −2} h{sup −1}, which occurred under cloudy conditions despite high soil temperatures. Moreover, when the soil temperature was 28 °C and the vegetation was removed from the experimental site, mercury emissions increased almost four-fold. This increase occurred almost immediately after the grasses were cut, and was approximately eight-fold after 20 h. Thus, this study demonstrates that enhancing wild vegetation cover could be an inexpensive and effective approach in fostering a natural, self-renewing reduction of mercury emissions from mercury-contaminated soils. -- Highlights: ► Mercury air/surface exchange

  5. Selected heavy metals and other constituents in soil and stormwater runoff at the Interstate 95 interchange near Atlee, Virginia, April 1993--May 1997

    SciTech Connect (OSTI)

    Speiran, G.K.

    1998-12-31

    Concentrations of the heavy metals copper, lead, and zinc, and other constituents, were measured in soil and runoff before and after construction of a stormwater detention basin at the Interstate 95-State Route 656 interchange near Atlee, VA, from April 1993 through May 1997. The spatial and vertical distribution of heavy metals in soil indicate that the paved traffic lanes of the interstate highway are a source of the metals. Concentrations of the metals in soil decrease with increasing soil depth below the ground surface and with increasing distance from the highway lanes. Of the three metals for which samples were analyzed, lead was generally present at the greatest concentration, and copper was at the lowest concentration in the soil.

  6. ASTM sampling methods and analytical validation for lead in paint, dust, soil, and air

    SciTech Connect (OSTI)

    Ashley, K.; Schlecht, P.C.; Song, R.; Feng, A.; DeWalt, G.; McKnight, M.E.

    1996-12-31

    ASTM Subcommittee E06.23 on Abatement/Mitigation of Lead Hazards has developed a number of standards that are concerned with the sampling of leas in environmental media, namely paint, dust, soil and airborne particulate. An ASTM practice for the collection of airborne particulate lead in the workplace has been published. New ASTM standards for the collection of dry paint film samples, surface soil samples, and surface dust wipe samples for subsequent lead analysis have also been promulgated. Other draft standards pertinent to lead sampling are under development. The ASTM standards concerned with lead sample collection are accompanied by separate sample preparation standard practices and a standard analysis method. Sample preparation and analytical methods have been evaluated by interlaboratory testing; such analyses may be used to assess the efficacy of sampling protocols.

  7. Surface Energy Balance System (SEBS) Handbook

    SciTech Connect (OSTI)

    Cook, D. R.

    2016-01-01

    A Surface Energy Balance System (SEBS) has been installed collocated with each deployed Eddy Correlation Flux Measurement System (ECOR) at the Atmospheric Radiation Measurement (ARM) Climate Research Facility’s Southern Great Plains (SGP) site, North Slope of Alaska (NSA) site, first ARM Mobile Facility (AMF1), second ARM Mobile Facility (AMF2), and third ARM Mobile Facility (AMF3) at Oliktok Point (OLI). A SEBS was also deployed with the Tropical Western Pacific (TWP) site, before it was decommissioned. Data from these sites, including the retired TWP, are available in the ARM Data Archive. The SEBS consists of upwelling and downwelling solar and infrared radiometers within one net radiometer, a wetness sensor, and soil measurements. The SEBS measurements allow the comparison of ECOR sensible and latent heat fluxes with the energy balance determined from the SEBS and provide information on wetting of the sensors for data quality purposes.

  8. Method for treatment of soils contaminated with organic pollutants

    DOE Patents [OSTI]

    Wickramanayake, Godage B.

    1993-01-01

    A method for treating soil contaminated by organic compounds wherein an ozone containing gas is treated with acid to increase the stability of the ozone in the soil environment and the treated ozone applied to the contaminated soil to decompose the organic compounds. The soil may be treated in situ or may be removed for treatment and refilled.

  9. CARBON SEQUESTRATION IN RECLAIMED MINED SOILS OF OHIO

    SciTech Connect (OSTI)

    M.K. Shukla; R. Lal

    2004-10-01

    This research project is aimed at assessing the soil organic carbon (SOC) sequestration potential of reclaimed minesoils (RMS). The experimental sites, owned and maintained by the American Electrical Power, are located in Guernsey, Morgan, Noble, and Muskingum Counties of Ohio. These sites, characterized by age chronosequences, were reclaimed with and without topsoil application and are under continuous grass or forest cover. During this quarter, water infiltration tests were performed on the soil surface in the experimental sites. Soil samples were analyzed for the soil carbon and nitrogen contents, texture, water stable aggregation, and mean weight and geometric mean diameter of aggregates. This report presents the results from two sites reclaimed during 1978 and managed under grass (Wilds) and forest (Cumberland) cover, respectively. The trees were planted in 1982 in the Cumberland site. The analyses of data on soil bulk density ({rho}{sub b}), SOC and total nitrogen (TN) concentrations and stocks were presented in the third quarter report. This report presents the data on infiltration rates, volume of transport and storage pores, available water capacity (AWC) of soil, particle size distribution, and soil inorganic carbon (SIC) and coal carbon contents. The SIC content ranged from 0.04 to 1.68% in Cumberland tree site and 0.01 to 0.65% in the Wilds. The coal content assumed to be the carbon content after oven drying the sample at 350 C varied between 0.04 and 3.18% for Cumberland and 0.06 and 3.49% for Wilds. The sand, silt and clay contents showed moderate to low variability (CV < 0.16) for 0-15 and 15-30 cm depths. The volume of transmission (VTP) and storage pores (VSP) also showed moderate to high variability (CV ranged from 0.22 to 0.39 for Wilds and 0.17 to 0.36 for Cumberland). The CV for SIC was high (0.7) in Cumberland whereas that for coal content was high (0.4) in the Wilds. The steady state infiltration rates (i{sub c}) also showed high variability

  10. Temperature-associated increases in the global soil respiration record

    SciTech Connect (OSTI)

    Bond-Lamberty, Benjamin; Thomson, Allison M.

    2010-03-25

    Soil respiration (RS), the flux of CO2 from the soil surface to the atmosphere, comprises the second-largest terrestrial carbon flux, but its dynamics are incompletely understood, and the global flux remains poorly constrained. Ecosystem warming experiments, modelling analyses, and biokinetics all suggest that RS should change with climate. This has been difficult to confirm observationally because of the high spatial variability of RS, inaccessibility of the soil medium, and inability of remote sensing instruments to measure large-scale RS fluxes. Given these constraints, is it possible to discern climate-driven changes in regional or global RS fluxes in the extant four-decade record of RS chamber measurements? Here we use a database of worldwide RS observations, matched with high-resolution historical climate data, to show a previously unknown temporal trend in the RS record after accounting for mean annual climate, leaf area, nitrogen deposition, and changes in CO2 measurement technique. Air temperature anomaly (deviation from the 1961-1990 mean) is significantly and positively correlated with changes in RS fluxes; both temperature and precipitation anomalies exert effects in specific biomes. We estimate that the current (2008) annual global RS flux is 9812 Pg and has increased 0.1 Pg yr-1 over the last 20 years, implying a global RS temperature response (Q10) of 1.5. An increasing global RS flux does not necessarily constitute a positive feedback loop to the atmosphere; nonetheless, the available data are consistent with an acceleration of the terrestrial carbon cycle in response to global climate change.