National Library of Energy BETA

Sample records for ultra-low sulfur distillate

  1. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  2. Cost-benefit analysis of ultra-low sulfur jet fuel

    E-Print Network [OSTI]

    Kuhn, Stephen (Stephen Richard)

    2010-01-01

    The growth of aviation has spurred increased study of its environmental impacts and the possible mitigation thereof. One emissions reduction option is the introduction of an Ultra Low Sulfur (ULS) jet fuel standard for ...

  3. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  4. Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car and Medium-duty Engine in Conjunction with Ultra Low Sulfur Fuel (Presentation)

    SciTech Connect (OSTI)

    Thornton, M.; Tatur, M.; Tomazic, D.; Weber, P.; Webb, C.

    2005-08-25

    Discusses the full useful life exhaust emission performance of a NOx (nitrogen oxides) adsorber and diesel particle filter equipped light-duty and medium-duty engine using ultra low sulfur diesel fuel.

  5. ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP

    SciTech Connect (OSTI)

    Ron Rohrbach; Gary Zulauf; Tim Gavin

    2003-04-01

    Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Mack Trucks Inc.), a filter recycler (American Wastes Industries), and a low-sulfur fuel supplier (Equilon, a joint venture between Shell and Texaco).

  6. Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap

    SciTech Connect (OSTI)

    Rohrbach, Ron; Barron, Ann

    2008-07-31

    Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Navistar Inc. (formerly International Truck & Engine Corporation) and Mack Trucks Inc.), and filter recycler (American Wastes Industries).

  7. Field Demonstration of High Efficiency Ultra-Low-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra-Low-Temperature Laboratory Freezers Field Demonstration of High Efficiency Ultra-Low-Temperature Laboratory Freezers Ultra-low temperature laboratory freezers (ULTs) are some...

  8. Multilayer Platform for Ultra-Low-Loss Waveguide Applications

    E-Print Network [OSTI]

    2012-01-01

    1, 2012 Multilayer Platform for Ultra-Low-Loss Waveguidepreviously demonstrated ultra-low-loss technologies. Groupet al. : MULTILAYER PLATFORM FOR ULTRA-LOW-LOSS WAVEGUIDE

  9. Ultra Low Power Bioelectronics Fundamentals, Biomedical Applications,

    E-Print Network [OSTI]

    Sarpeshkar, Rahul

    Ultra Low Power Bioelectronics Fundamentals, Biomedical Applications, and Bio-inspired Systems to articulate information-based principles for ultra-low-power design that apply to biology or to electronics of ultra- low-power electronics and bioelectronics is shown in the figure below. Engineering can aid

  10. ULTRA-LOW-ENERGY HIGH-CURRENT ION SOURCE

    E-Print Network [OSTI]

    Anders, Andre

    2010-01-01

    a high current ion source for ultra-low energy ions has beenthe Department of Energy ULTRA-LOW-ENERGY HIGH-CURRENT IONedited by A. Anders. ULTRA-LOW-ENERGY HIGH-CURRENT ION

  11. Adaptive Injection Strategies (AIS) for Ultra-low Emissions Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection Strategies (AIS) for Ultra-low Emissions Diesel Engines Adaptive Injection Strategies (AIS) for Ultra-low Emissions Diesel Engines Presentation given at the 2007 Diesel...

  12. Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading Presented at the Department of Energy Fuel Cell...

  13. A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials

    E-Print Network [OSTI]

    Delucchi, Mark

    2003-01-01

    = distillate fuel; ULSD = ultra-low-sulfur distillate fuel;ppm S and a reference ultra-low-sulfur diesel (ULSD) with 5content of the reference ultra-low-sulfur diesel (5 ppm). SF

  14. Development of Ultra-low Platinum Alloy Cathode Catalyst for...

    Energy Savers [EERE]

    Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells These slides were presented...

  15. Liquid fuels perspective on ultra low carbon vehicles | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fuels perspective on ultra low carbon vehicles Liquid fuels perspective on ultra low carbon vehicles Fuels challenges in the evolving global energy market deer11simnick.pdf More...

  16. Ultra-low field magnetic resonance using optically pumped noble gases and SQUID detection

    E-Print Network [OSTI]

    Wong-Foy, Annjoe G.

    2010-01-01

    Enhancement . . . . Ultra Low Field Xenon NMR ShowingIntroduction.. 4.2 Ultra Low FieldNuclear Polarization 5.10.3 Ultra Low Field Chemical Shift

  17. Ultra-Low Power Time Synchronization Using Passive Radio Receivers

    E-Print Network [OSTI]

    Amir, Yair

    Ultra-Low Power Time Synchronization Using Passive Radio Receivers Yin Chen Qiang Wang Marcus Chang. In this pa- per, we present an inexpensive and ultra-low power ( of elapsed seconds. The universal time sig- nal receiver combines an off-the-shelf radio chip with an ultra-low

  18. American Institute of Aeronautics and Astronautics Ultra Low Emissions Combustor

    E-Print Network [OSTI]

    Seitzman, Jerry M.

    1 American Institute of Aeronautics and Astronautics T Ultra Low Emissions Combustor with Non-premixed modes of combustion with ultra low NOx emissions. The combustor consists of a tube with open and closed low temperatures with ultra low NOx emission in the 1 ppm range and below. It is also shown

  19. Silicon on ultra-low-loss waveguide photonic integration platform

    E-Print Network [OSTI]

    Bauters, Jared; Davenport, Michael; Heck, Martijn; Doylend, Jonathan; Chen, Arnold; Fang, Alexander

    2013-01-01

    and J. E. Bowers, “Ultra-low-loss high-aspect-ratio Si 3 N 4and K. J. Vahala, “Ultra-low-loss optical delay line on aspiral is 78 mm long. 3. Ultra-low-loss waveguides with and

  20. Universal Hash Functions for Emerging Ultra-Low-Power Networks

    E-Print Network [OSTI]

    Universal Hash Functions for Emerging Ultra-Low-Power Networks Kaan Y¨uksel, Jens-Peter Kaps provable security in ultra-low-power applications such as the next generation self-powered sensor networks in ultra-low-power applications such as "Smart Dust" motes and RFIDs. By virtue of their security

  1. Ultra Low Power Electronics for Medicine Rahul Sarpeshkar

    E-Print Network [OSTI]

    Sarpeshkar, Rahul

    Ultra Low Power Electronics for Medicine Rahul Sarpeshkar Analog VLSI and Biological Systems Group on an implanted 100mAh rechargeable battery. Another example includes an ultra low power portable pulse oximeter monitoring. Medical applications in the future are likely to benefit greatly from ultra low power electronics

  2. AERODYNAMICS AND DESIGN FOR ULTRA-LOW REYNOLDS NUMBER FLIGHT

    E-Print Network [OSTI]

    Stanford University

    AERODYNAMICS AND DESIGN FOR ULTRA-LOW REYNOLDS NUMBER FLIGHT A DISSERTATION SUBMITTED at Reynolds numbers below 10,000, here termed ultra-low Reynolds numbers. The effects of airfoil geometry at ultra-low Reynolds numbers. To further explore this design space, the flow solver has been coupled

  3. Design Considerations for Ultra-Low Energy Wireless Microsensor Nodes

    E-Print Network [OSTI]

    Chen, Yuanzhu Peter

    Design Considerations for Ultra-Low Energy Wireless Microsensor Nodes Benton H. Calhoun, Student of an energy harvesting source. These requirements place demands on all levels of the design. We propose an architecture for achieving the required ultra-low energy operation and discuss the circuit techniques necessary

  4. Digital Bimodal Function: An Ultra-Low Energy Security Primitive

    E-Print Network [OSTI]

    Potkonjak, Miodrag

    Digital Bimodal Function: An Ultra-Low Energy Security Primitive Teng Xu, James B. Wendt function (DBF) that enables ultra low energy security protocols. DBF allows the computation of legitimate and energy expense. Our new approach is competitive with the energy efficiency of traditional security key

  5. Paper 2008-01-0434 Effects of Sulfur Level and Anisotropy of Sulfide Inclusions on

    E-Print Network [OSTI]

    Fatemi, Ali

    to fatigue strength, the high sulfur material had up to 25% lower fatigue strength than the ultra low sulfur, monotonic tensile and CVN impact behavior of SAE 4140 steel with high (0.077% S), low (0.012% S) and ultra low (0.004% S) sulfur contents at two hardness levels (40 HRC and 50 HRC). The longitudinally oriented

  6. One-dimensional ordering of ultra-low density ion beams in a storage ring

    E-Print Network [OSTI]

    Okamoto, H.; Okabe, K.; Yuri, Y.; Mohl, D.; Sessler, A.M.

    2004-01-01

    One-dimensional ordering of ultra-low density ion beams in ais applicable to an ultra-low density beam where collectiveabout 10 cm. In such an ultra-low density regime, no collec-

  7. Ultra-Low-Power Adder Stage Design for Exascale Floating Point Units

    E-Print Network [OSTI]

    Del Barrio, AA; Bagherzadeh, N; Hermida, R

    2014-01-01

    date: March 2014. Ultra-Low-Power Adder Stage Design fordate: March 2014. Ultra-Low-Power Adder Stage Design fordate: March 2014. Ultra-Low-Power Adder Stage Design for

  8. Development of a combustion technology for ultra-low emission (< 5 ppm nox) industrial burner

    E-Print Network [OSTI]

    Littlejohn, D.; Majeski, A.J.; Cheng, R.K.; Castaldini, C.

    2002-01-01

    Investigation of an Ultra-Low NO x Premixed CombustionInvestigation of an Ultra-Low NO x Premixed Combustioncombustion concept to achieve ultra-low emissions (NO x ? 2

  9. Ultra-low-loss high-aspect-ratio Si3N4 wavequides

    E-Print Network [OSTI]

    2011-01-01

    R. Gao, and A. Garito, “Ultra-Low-Loss Polymer Waveguides,”Ultra-low-loss high-aspect-ratio Si 3 N 4 waveguides Jaredan approach to make ultra-low-loss waveguides using stable

  10. Ultra-low field MRI of prostate cancer using SQUID detection

    E-Print Network [OSTI]

    Busch, Sarah Elizabeth

    2011-01-01

    coil. Chapter 3 3 Ultra low field MRI 3.1 Polarization TheUltra-low field MRI of prostate cancer using SQUID detectionSteven Conolly Spring 2011 Ultra-low field MRI of prostate

  11. Quadrature Rotating-Frame Gradient Fields for Ultra-Low Field Nuclear Magnetic Resonance and Imaging

    E-Print Network [OSTI]

    Bouchard, Louis-Serge

    2005-01-01

    Frame Gradient Fields For Ultra-Low Field Nuclear Magneticslow, as in the limit of ultra-low ?elds. In the ?rst case,B. Slice selection in ultra-low ?elds We ?rst examine the

  12. Electrical activation and spin coherence of ultra low dose antimony implants in silicon

    E-Print Network [OSTI]

    2005-01-01

    and spin coherence of ultra low dose antimony implants inClara, CA 95054 We implanted ultra low doses (0.2 to 2×10 11100 nm, corresponding to ultra low ion implantation doses of

  13. Field Demonstration of High Efficiency Ultra-Low-Temperature...

    Broader source: Energy.gov (indexed) [DOE]

    Ultra-low temperature laboratory freezers (ULTs) are some of the most energy-intensive pieces of equipment in a scientific research laboratory, yet there are several barriers to...

  14. Charge pumping techniques in ultra-low current transconductor design 

    E-Print Network [OSTI]

    Becker-Gomez, Adriana

    2002-01-01

    The purpose of this thesis is to introduce the use of interface-trap charge pumping devices (ITCP) in an analog application based in ultra-low-current transconductors. This application naturally exploits the continuous nature of the current...

  15. The Design Space of Ultra-low Energy Asymmetric Cryptography 

    E-Print Network [OSTI]

    Targhetta, Andrew David

    2015-05-06

    The energy cost of asymmetric cryptography, a vital component of modern secure communications, inhibits its wide spread adoption within the ultra-low energy regimes such as Implantable Medical Devices (IMDs), Wireless Sensor Networks (WSNs...

  16. An Advanced Ultra-Low Temperature Scanning Probe Microscope

    E-Print Network [OSTI]

    An Advanced Ultra-Low Temperature Scanning Probe Microscope P R O J E C T L E A D E R : Joseph); Steven Blankenship, Alan Band (NIST) G O A L To develop an ultra-high vacuum, ultra-low temperature, high of subpicometer stability and can operate in ultra-high vacuum at 10 mK, and in magnetic fields up to 15 T

  17. Ultra-low velocities and Superplumes Garnero, Thorne, McNamara, Rost [2005

    E-Print Network [OSTI]

    Garnero, Ed

    Ultra-low velocities and Superplumes Garnero, Thorne, McNamara, Rost [2005] - 1- Fine-scale ultra-low, Arizona 85287-1404 USA Abstract. Ultra-low velocity layering at Earth's core-mantle boundary has now been in the overlying few hundred km of the mantle. Ultra-low velocity zones contain properties consistent with partial

  18. An Ultra-Low-Power Analog Memory System with an Adaptive Sampling Rate

    E-Print Network [OSTI]

    Graham, David W.

    An Ultra-Low-Power Analog Memory System with an Adaptive Sampling Rate Brandon M. Kelly, Brandon normally associated with sleep states in WSNs, we introduce an ultra-low-power analog memory buffer in which ultra- low-power operation is a necessity. In this paper, we propose an ultra-low-power analog mem

  19. Low-voltage ultra-low-poweranalog IC design -djmamic translinearcircuits 1.3.1 1.3 Low-voltage ultra-low-power analog IC design

    E-Print Network [OSTI]

    Serdijn, Wouter A.

    Low-voltage ultra-low-poweranalog IC design -djmamic translinearcircuits 1.3.1 1.3 Low-voltage ultra-low-power analog IC design -dynamic translinear circuits 0 (rg G x m .- E . . . . . a r, a" P, 44' s" +N m - _ c o3 #12;Low-voltage ultra-low-power analog IC design -dynamic translinear circuits I

  20. Spintronic switches for ultra low energy global interconnects

    SciTech Connect (OSTI)

    Sharad, Mrigank Roy, Kaushik

    2014-05-07

    We present ultra-low energy interconnect design using nano-scale spin-torque (ST) switches for global data-links. Emerging spin-torque phenomena can lead to ultra-low-voltage, high-speed current-mode magnetic-switches. ST-switches can simultaneously provide large trans-impedance gain by employing magnetic tunnel junctions, to convert current-mode signals into large-swing voltage levels. Such device-characteristics can be used in the design of energy-efficient current-mode global interconnects.

  1. DISS. ETH NO. 18959 Ultra-Low Power Sensor Networks

    E-Print Network [OSTI]

    DISS. ETH NO. 18959 Ultra-Low Power Sensor Networks: Development Tools, Design, and Implementation) are a powerful tool for the surveillance of environmental conditions, natural habitats, or industrial machinery consider the design and implementation of energy-efficient communication protocols and applications

  2. Matched Public PUF: Ultra Low Energy Security Platform

    E-Print Network [OSTI]

    Potkonjak, Miodrag

    Matched Public PUF: Ultra Low Energy Security Platform Saro Meguerdichian and Miodrag Potkonjak and energy costs and enables a majority of security protocols to be completed in a single or a few clock an ultimately low energy and low latency security approach that enables the device to operate in hostile

  3. High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel Reactivity Control High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel...

  4. The MAJORANA experiment: an ultra-low background search for neutrinole...

    Office of Scientific and Technical Information (OSTI)

    The MAJORANA experiment: an ultra-low background search for neutrinoless double-beta decay Citation Details In-Document Search Title: The MAJORANA experiment: an ultra-low...

  5. Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines Presentation given at DEER...

  6. Tracking deep mantle reservoirs with ultra-low velocity zones Allen K. McNamara a,

    E-Print Network [OSTI]

    Rhoads, James

    Tracking deep mantle reservoirs with ultra-low velocity zones Allen K. McNamara a, , Edward J, that directly overlies the core-mantle boundary (CMB). These regions have been dubbed Ultra-Low Velocity Zones. Introduction For over 15 yrs seismologists have mapped regions of ultra-low P- and S-wave velocities

  7. Ultra-Low Voltage VCO Design Using Schmitt Trigger on SOI

    E-Print Network [OSTI]

    Ayers, Joseph

    Ultra-Low Voltage VCO Design Using Schmitt Trigger on SOI Kyung Ki Kim Department of Electrical trigger and an ultra low voltage current source on PD-SOI with low temperature and supply voltage oscillator based VCOs on SOI CMOS [4][5] have been reported. However, VCO with ultra low voltage less than 0

  8. Centralized Routing Protocol for Wireless Sensor Networks with Ultra Low Duty Cycle to Achieve Maximum Lifetime

    E-Print Network [OSTI]

    Bahk, Saewoong

    Centralized Routing Protocol for Wireless Sensor Networks with Ultra Low Duty Cycle to Achieve performance because most of them are designed without considering a ultra low duty cycled environment to improve a network lifetime and a routing maintenance cost. We explain the issues of a ultra low duty

  9. Challenge: Ultra-Low-Power Energy-Harvesting Active Networked Tags (EnHANTs)

    E-Print Network [OSTI]

    Zussman, Gil

    Challenge: Ultra-Low-Power Energy-Harvesting Active Networked Tags (EnHANTs) Maria Gorlatova, Peter posed by a new class of ultra-low-power devices referred to as Energy-Harvesting Ac- tive Networked Tags), and determining locations of disaster sur- vivors. Recent advances in ultra-low-power wireless communica- tions

  10. Integrated Ultra-Low-Loss 4-Bit Tunable Delay for Broadband Phased Array Antenna Applications

    E-Print Network [OSTI]

    2013-01-01

    F. Bauters, et al. , “Ultra-low-loss high-aspect-ratio Si3N4JUNE 15, 2013 Integrated Ultra-Low-Loss 4-Bit Tunable Delaya 4-bit tunable delay in an ultra-low-loss Si 3 N 4 planar

  11. Suppressing Multi-Channel Ultra-Low-Field MRI Measurement Noise Using Data Consistency and Image

    E-Print Network [OSTI]

    Suppressing Multi-Channel Ultra-Low-Field MRI Measurement Noise Using Data Consistency and Image of Mathematics, National Taiwan University, Taipei, Taiwan, 4 Elekta Oy, Helsinki, Finland Abstract Ultra-low. (2013) Suppressing Multi-Channel Ultra-Low-Field MRI Measurement Noise Using Data Consistency and Image

  12. Aerodynamic Shape Optimization of Airfoils in Ultra-Low Reynolds Number Flow using

    E-Print Network [OSTI]

    Stanford University

    Aerodynamic Shape Optimization of Airfoils in Ultra-Low Reynolds Number Flow using Simultaneous;Aerodynamic Shape Optimization of Airfoils in Ultra-Low Reynolds Number Flow using Simultaneous Pseudo Abstract. The paper presents numerical results of optimized airfoils at ultra-low Reynolds numbers

  13. Fluctuation-induced dynamics of multiphase liquid jets with ultra-low interfacial tension

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Fluctuation-induced dynamics of multiphase liquid jets with ultra-low interfacial tension Alban with an ultra-low interfacial tension presents new opportunities to the control of flow morphologies perturbation; this demonstrates the importance of the inertial effects in flow control at ultra-low interfacial

  14. Energy Efficient Routing Protocol for Wireless Sensor Networks with Ultra Low Duty Cycle

    E-Print Network [OSTI]

    Bahk, Saewoong

    Energy Efficient Routing Protocol for Wireless Sensor Networks with Ultra Low Duty Cycle Wooguil of high energy consumption mainly caused by the clock drift in ultra low duty cycled environments because most of them are designed without considering ultra low duty cycled environments. To achieve

  15. An Ultra Low Power SIMD Processor for Wireless Devices , Sangwon Seo1

    E-Print Network [OSTI]

    Kambhampati, Subbarao

    An Ultra Low Power SIMD Processor for Wireless Devices Mark Woh1 , Sangwon Seo1 , Chaitali, Tempe, AZ {mwoh,swseo,mahlke,tnm}@umich.edu chaitali@asu.edu ABSTRACT This paper presents an ultra low executed. For ultra low power operation, we advocate operating the processor at near threshold volt- age

  16. Invited Paper Ultra-low-power Electronics for Non-invasive

    E-Print Network [OSTI]

    Sarpeshkar, Rahul

    Invited Paper Ultra-low-power Electronics for Non-invasive Medical Monitoring L. Turicchia1 , S on the monitoring of the heart--because of its importance--and we describe a micropower electrocardiograph, an ultra-low-power pulse oximeter, an ultra-low-power phonocardiograph, an integrated- circuit switched-capacitor model

  17. An Ultra Low Power CMOS pA/V Transconductor and its Application to Wavelet Filters

    E-Print Network [OSTI]

    Serdijn, Wouter A.

    An Ultra Low Power CMOS pA/V Transconductor and its Application to Wavelet Filters Peterson R topologies of ultra low-power CMOS triode transconductor are proposed. Its input transistors are kept with an extremely small transconductance gm is needed. This paper presents two topologies of ultra low

  18. Telos: Enabling Ultra-Low Power Wireless Research Joseph Polastre, Robert Szewczyk, and David Culler

    E-Print Network [OSTI]

    Culler, David E.

    Telos: Enabling Ultra-Low Power Wireless Research Joseph Polastre, Robert Szewczyk, and David,szewczyk,culler}@cs.berkeley.edu Abstract-- We present Telos, an ultra low power wireless sensor module ("mote") for research and 128kB of flash), extensive sensor interfaces (8 analog lines, several digital IO Fig. 1. Telos ultra-low

  19. Ultra-Low Power DLMS Adaptive Filter For Hearing Aid Applications

    E-Print Network [OSTI]

    Kim, Chris H.

    Ultra-Low Power DLMS Adaptive Filter For Hearing Aid Applications Hyung-il Kim Purdue University, USA +1-765-494-2361 kaushik@ecn.purdue.edu ABSTRACT We present an ultra-low power DLMS (delayed least suitable application areas for sub-threshold logic since ultra-low power consumption takes first priority

  20. An ultra-low voltage high gain operational transconductance amplifier for biomedical

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    An ultra-low voltage high gain operational transconductance amplifier for biomedical applications that work at ultra low voltage power supply. Moreover, low power dissipation is essential in these systems dissipation is also proposed in [5]. Differential pairs are commonly used as input stages, in an ultra-low

  1. An Ultra-Low-Power Human Body Motion Sensor Using Static Electric Field Sensing

    E-Print Network [OSTI]

    Hunt, Galen

    An Ultra-Low-Power Human Body Motion Sensor Using Static Electric Field Sensing Gabe Cohn1 an ultra-low-power method for pas- sively sensing body motion using static electric fields by measuring to infer the amount and type of body motion anywhere on the body and demonstrate an ultra-low-power motion

  2. Performance of plasma sputtered Fuel Cell electrodes with ultra-low Pt M. Cavarroca

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Performance of plasma sputtered Fuel Cell electrodes with ultra-low Pt loadings M. Cavarroca , A. Abstract Ultra-low Pt content PEMFC electrodes have been manufactured using magnetron co- sputtering cell; Plasma sputtering deposition; ultra low platinum loading * Corresponding author: Fax: +33 2 38 41

  3. Variation-aware Clock Network Design Methodology for Ultra-Low Voltage (ULV) Circuits

    E-Print Network [OSTI]

    Lim, Sung Kyu

    Variation-aware Clock Network Design Methodology for Ultra-Low Voltage (ULV) Circuits Xin Zhao networks for ultra-low voltage (ULV) circuits. We show that both clock slew and skew play important roles) at comparable or even higher Fmax compared with the existing methods. Keywords--clock network design, ultra-low

  4. Ultra-Low Wearing Nanocomposites-How Low Can We Go? Angela Pitenis

    E-Print Network [OSTI]

    Roy, Subrata

    Ultra-Low Wearing Nanocomposites- How Low Can We Go? Angela Pitenis You know more about tribology), this new material, a nanocomposite, is able to achieve ultra-low wear (k~7x10-8 mm3 /(Nm)). This means limits of this ultra-low wearing nanocomposite. Our most recent experiments were conducted in a broad

  5. Bulk CMOS Device Optimization for High-Speed and Ultra-Low Power Operations

    E-Print Network [OSTI]

    Nyathi, Jabulani

    Bulk CMOS Device Optimization for High-Speed and Ultra-Low Power Operations Brent Bero and Jabulani- Interest in subthreshold design has increased due to the emergence of systems that require ultra-low power creating a clear divide between designing for high speed and ultra-low power. It might be beneficial

  6. A Hybrid Adiabatic Content Addressable Memory for Ultra Low-Power Applications

    E-Print Network [OSTI]

    Tessier, Russell

    A Hybrid Adiabatic Content Addressable Memory for Ultra Low-Power Applications Aiyappan Natarajan/write operation. The adiabatic CAM is suitable for ultra low-power, low per- formance applications such as smart, Performance Keywords Ultra-low power, Energy recovery, adiabatic switching 1. INTRODUCTION Content Addressable

  7. Environmental fate model for ultra-low-volume insecticide applications used for adult mosquito management

    E-Print Network [OSTI]

    Peterson, Robert K. D.

    Environmental fate model for ultra-low-volume insecticide applications used for adult mosquito T S No model can accurately predict deposition of insecticides applied with ultra-low-volume technology of insecticides. We develop a validated model to predict the deposition of insecticides after ultra-low

  8. Cryptography for Ultra-Low Power Devices Jens-Peter Kaps

    E-Print Network [OSTI]

    Cryptography for Ultra-Low Power Devices by Jens-Peter Kaps A Dissertation Submitted to the Faculty classify them as ultra-low power devices. Early sensor nodes used simple 8-bit microprocessors to implement of cryptographic algorithms tailored for ultra-low power applications. The goal of this dissertation is to de

  9. Heat capacity of adsorbed Helium-3 at ultra-low temperatures

    E-Print Network [OSTI]

    Boyer, Edmond

    Heat capacity of adsorbed Helium-3 at ultra-low temperatures J. Elbs, C. Winkelmann, Yu. M. Bunkov of monolayers of 3He adsorbed on the surface of a cell filled with superfluid 3He. We found that at ultra low in the limit of ultra low temperatures. 1. INTRODUCTION A closed cell with a small orifice, immersed

  10. Analysis, Design, and Testing of Airfoils for Use at Ultra-Low Reynolds Numbers

    E-Print Network [OSTI]

    Stanford University

    Analysis, Design, and Testing of Airfoils for Use at Ultra- Low Reynolds Numbers Peter J. Kunz Ilan M. Kroo Abstract: Advances in technology have begun to make ultra-low Reynolds number flight a real of the relevant aerodynamics. A reasonable starting point is the study of airfoil section aerodynamics at ultra-low

  11. Ultra-low-loss tapered optical fibers with minimal lengths

    E-Print Network [OSTI]

    Ryutaro Nagai; Takao Aoki

    2014-11-09

    We design and fabricate ultra-low-loss tapered optical fibers (TOFs) with minimal lengths. We first optimize variations of the torch scan length using the flame-brush method for fabricating TOFs with taper angles that satisfy the adiabaticity criteria. We accordingly fabricate TOFs with optimal shapes and compare their transmission to TOFs with a constant taper angle and TOFs with an exponential shape. The highest transmission measured for TOFs with an optimal shape is in excess of 99.7 % with a total TOF length of only 23 mm, whereas TOFs with a constant taper angle of 2 mrad reach 99.6 % transmission for a 63 mm TOF length.

  12. Cryostat for Ultra-low-energy Threshold Germanium Spectrometers

    SciTech Connect (OSTI)

    Aalseth, Craig E.; Bonicalzi, Ricco; Fast, James E.; Hossbach, Todd W.; Orrell, John L.; Overman, Cory T.; VanDevender, Brent A.

    2013-04-01

    Abstract: This paper presents progress on the development of a cryostat intended to improve upon the low-energy threshold (below 0.5 keV) of p-type point contact germanium gamma-ray spectrometers. Ultra-low energy thresholds are important in the detection of low-energy nuclear recoils, an event class relevant to both dark matter direct detection and measurement of coherent neutrino-nucleus scattering. The cryostat design, including a thermal and electrical-field model, is presented. A prototype cryostat has been assembled and data acquired to evaluate its vacuum and thermal performance.

  13. Cryostat for Ultra-low-energy Threshold Germanium Spectrometers

    E-Print Network [OSTI]

    Craig E. Aalseth; Ricco M. Bonicalzi; James E. Fast; Todd W. Hossbach; John L. Orrell; Cory T. Overman; Brent A. Vandevender

    2012-10-08

    This paper presents progress on the development of a cryostat intended to improve upon the low-energy threshold (below 0.5 keV) of p-type point contact germanium gamma-ray spectrometers. Ultra-low energy thresholds are important in the detection of low-energy nuclear recoils, an event class relevant to both dark matter direct detection and measurement of coherent neutrino-nucleus scattering. The cryostat design, including a thermal and electrical-field model, is given. A prototype cryostat has been assembled and data acquired to evaluate its vacuum and thermal performance.

  14. High Efficiency, Ultra-Low Emission, Integrated Process Heater System

    SciTech Connect (OSTI)

    Mason, Howard; Boral, Anindya; Chhotray, San; Martin, Matthew

    2006-06-19

    The team of TIAX LLC, ExxonMobil Research and Engineering Company, and Callidus Technologies, LLC conducted a six-year program to develop an ultra-low emission process heater burner and an advanced high efficiency heater design. This project addresses the critical need of process heater operators for reliable, economical emission reduction technologies to comply with stringent emission regulations, and for heater design alternatives that reduce process heater energy requirements without significant cost increase. The key project targets were NOx emissions of 10 ppm (@ 3% O2), and a heater thermal efficiency of 95 percent. The ultra low NOx burner was developed through a series of pilot-scale and field tests combined with computational fluid dynamic modeling to arrive at simultaneous low emissions and suitable flame shape and stability. Pilot scale tests were run at TIAX, at the 2 MMBtu/hr scale, and at Callidus at 8 MMBtu/hr. The full scale burner was installed on a 14 burner atmospheric pipestill furnace at an ExxonMobil refinery. A variety of burner configurations, gas tips and flame stabilizers were tested to determine the lowest emissions with acceptable flame shape and stability. The resulting NOx emissions were 22 ppm on average. Starting in 2001, Callidus commercialized the original ultra low NOx burner and made subsequent design improvements in a series of commercial burners evolving from the original concept and/or development. Emissions in the field with the ultra low-NOx burner over a broad spectrum of heater applications have varied from 5 ppm to 30 ppm depending on heater geometry, heater service, fuel and firing capacity. To date, 1550 of the original burners, and 2500 of subsequent generation burners have been sold by Callidus. The advanced heater design was developed by parametric evaluations of a variety of furnace and combustion air preheater configurations and technologies for enhancing convective and radiative heat transfer. The design evolution relied heavily on computational fluid dynamic predictions of design alternatives. The final design features modular separate radiant cells, each with one and two-side fired vertical tubes. The convection section configuration is vertical tube banks enclosed in the radiant channels. Commercial modular plate air preheaters are used. The predicted performance for the integrated advanced heater and Callidus burner is 95 percent efficiency with 9 ppm NOx emissions firing natural gas, and 12 ppm firing refinery gas. The total erected cost is less than a conventional heater with combustion air preheat.

  15. PPPL3161 Preprint Date: February 1996, UC420, 426, 427 Global Stability Study of the Ultra Low Aspect Ratio Tokamak,

    E-Print Network [OSTI]

    Low Aspect Ratio Tokamak, Global Stability Study of the Ultra Low Aspect Ratio Tokamak, Global Stability Study of the Ultra Low Aspect Ratio Tokamak, Global Stability Study of the Ultra Low Aspect Ratio Tokamak, Global Stability Study of the Ultra Low Aspect Ratio Tokamak, ULART ULART ULART ULART ULART M

  16. Design Considerations for Large Mass Ultra-Low Background Experiments

    SciTech Connect (OSTI)

    Aguayo Navarrete, Estanislao; Reid, Douglas J.; Fast, James E.; Orrell, John L.

    2011-07-01

    Summary The objective of this document is to present the designers of the next generation of large-mass, ultra-low background experiments with lessons learned and design strategies from previous experimental work. Design issues divided by topic into mechanical, thermal and electrical requirements are addressed. Large mass low-background experiments have been recognized by the scientific community as appropriate tools to aid in the refinement of the standard model. The design of these experiments is very costly and a rigorous engineering review is required for their success. The extreme conditions that the components of the experiment must withstand (heavy shielding, vacuum/pressure and temperature gradients), in combination with unprecedented noise levels, necessitate engineering guidance to support quality construction and safe operating conditions. Physical properties and analytical results of typical construction materials are presented. Design considerations for achieving ultra-low-noise data acquisition systems are addressed. Five large-mass, low-background conceptual designs for the one-tonne scale germanium experiment are proposed and analyzed. The result is a series of recommendations for future experiments engineering and for the Majorana simulation task group to evaluate the different design approaches.

  17. PPPL-3161 -Preprint Date: February 1996, UC-420, 426, 427 Global Stability Study of the Ultra Low Aspect Ratio Tokamak,Global Stability Study of the Ultra Low Aspect Ratio Tokamak,Global Stability Study of the Ultra Low Aspect Ratio Tokamak,Global Stabili

    E-Print Network [OSTI]

    Low Aspect Ratio Tokamak,Global Stability Study of the Ultra Low Aspect Ratio Tokamak,Global Stability Study of the Ultra Low Aspect Ratio Tokamak,Global Stability Study of the Ultra Low Aspect Ratio Tokamak,Global Stability Study of the Ultra Low Aspect Ratio Tokamak, ULARTULARTULARTULARTULART M. Yamada1, A. Morita2, N

  18. Ultra-low density microcellular polymer foam and method

    DOE Patents [OSTI]

    Simandl, R.F.; Brown, J.D.

    1996-03-19

    An ultra-low density, microcellular open-celled polymer foam and a method for making such foam are disclosed. A polymer is dissolved in a heated solution consisting essentially of at least one solvent for the dissolution of the polymer in the heated solution and the phase inversion of the dissolved polymer to a liquid gel upon sufficient cooling of the heated solution. The heated solution is contained in a containment means provided with a nucleating promoting means having a relatively rough surface formed of fixed nucleating sites. The heated solution is cooled for a period of time sufficient to form a liquid gel of the polymer by phase inversion. From the gel, a porous foam having a density of less than about 12.0 mg/cm{sup 3} and open porosity provided by well interconnected strut morphology is formed.

  19. Ultra-Low Amplitude Cepheids in the Large Magellanic Cloud

    E-Print Network [OSTI]

    J. Robert Buchler; Peter R. Wood; Stefan Keller; Igor Soszynski

    2005-08-26

    The MACHO variables of LMC Field 77 that lie in the vicinity of the Cepheid instability strip are reexamined. Among the 144 variables that we identify as Cepheids we find 14 that have Fourier amplitudes ultra-low amplitude (ULA) Cepheids. The variability of these objects is verified by a comparison of the MACHO red with the MACHO blue lightcurves and with those of the corresponding OGLE LMC stars. The occurrence of ULA Cepheids is in agreement with theory. We have also discovered 2 low amplitude variables whose periods are about a factor of 5--6 smaller than those of F Cepheids of equal apparent magnitude. We suggest that these objects are Cepheids undergoing pulsations in a surface mode and that they belong to a novel class of Strange Cepheids (or Surface Mode Cepheids) whose existence was predicted by Buchler et al. (1997).

  20. Scenarios for the ATF2 Ultra-Low Betas Proposal

    SciTech Connect (OSTI)

    Marin, Eduardo; Tomas, Rogelio; Bambade, Philip; Kuroda, Shigeru; Okugi, Toshiyuki; Tauchi, Toshiaki; Terunuma, Nobuhiro; Urakawa, Junji; Parker, Brett; Seryi, Andrei; White, Glen; Woodley, Mark; /SLAC

    2012-06-29

    The current ATF2 Ultra-Low beta proposal was designed to achieve 20nm vertical IP beam size without considering the multipolar components of the FD magnets. In this paper we describe different scenarios that avoid the detrimental effect of these multipolar errors to the beam size at the interaction point (IP). The simplest approach consists in modifying the optics, but other solutions are studied as the introduction of super-conducting wigglers to reduce the emittance or the replacement of the normal-conducting focusing quadrupole in the Final Doublet (NC-QF1FF) with a super-conducting quadrupole one (SC-QF1FF). These are fully addressed in the paper.

  1. Scenarios For The ATF2 Ultra-Low Betas Proposal

    SciTech Connect (OSTI)

    Marin E.; Parker B.; Tomas R. Bambade Kuroda S. Okugi T. Tauchi T. Terunuma N. Urakawa J. Seryi A. White G. Woodley M.

    2010-05-23

    The current ATF2 Ultra-Low beta proposal was designed to achieve 20nm vertical IP beam size without considering the multipolar components of the FD magnets. In this paper we describe different scenarios that avoid the detrimental effect of these multipolar errors to the beam size at the interaction point (IP). The simplest approach consists in modifying the optics, but other solutions are studied as the introduction of super-conducting wigglers to reduce the emittance or the replacement of the normal-conducting focusing quadrupole in the Final Doublet (NC-QF1FF) with a super-conducting quadrupole one (SC-QF1FF). These are fully addressed in the paper.

  2. Ultra-low density microcellular polymer foam and method

    DOE Patents [OSTI]

    Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN)

    1996-01-01

    An ultra-low density, microcellular open-celled polymer foam and a method for making such foam. A polymer is dissolved in a heated solution consisting essentially of at least one solvent for the dissolution of the polymer in the heated solution and the phase inversion of the dissolved polymer to a liquid gel upon sufficient cooling of the heated solution. The heated solution is contained in a containment means provided with a nucleating promoting means having a relatively rough surface formed of fixed nucleating sites. The heated solution is cooled for a period of time sufficient to form a liquid gel of the polymer by phase inversion. From the gel, a porous foam having a density of less than about 12.0 mg/cm.sup.3 and open porosity provided by well interconnected strut morphology is formed.

  3. Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain 

    E-Print Network [OSTI]

    Benz, R,; Staedter, M.

    2008-01-01

    -1 Low Carbon Footprint and Ultra Low NOx Boilers through Efficiency Gain Robert Benz Marcel Staedter President Project Manager... / Low Carbon, Ultra Low NOx through Efficiency Gain where y denotes the mole fraction of excess oxygen. The presence of nitrogen and excess oxygen radicals in this hot combustion environment promotes the formation...

  4. An atom trap trace analysis (ATTA) system for measuring ultra-low contamination by krypton in

    E-Print Network [OSTI]

    Zelevinsky, Tanya

    An atom trap trace analysis (ATTA) system for measuring ultra-low contamination by krypton in xenon ultra-low contamination by krypton in xenon dark matter detectors Tae Hyun Yoon The XENON dark matter of the experiment. In order to achieve the desired sensitivity, the contamination by krypton is reduced to the part

  5. 9 Ultra Low Temperature ADI 2 9.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

    E-Print Network [OSTI]

    Cambridge, University of

    Contents 9 Ultra Low Temperature ADI 2 9.1 Introduction;Chapter 9 Ultra Low Temperature ADI 9.1 Introduction It has been indicated that a family of austempered]. These steels contain high carbon silicon and manganese, and they are isothermally heat treated at very low

  6. Technical Reports Ultra-low Dose Lung CT Perfusion Regularized by

    E-Print Network [OSTI]

    Wang, Ge

    Technical Reports Ultra-low Dose Lung CT Perfusion Regularized by a Previous Scan1 Hengyong Yu, Ph­regularized reconstruction (PSRR) method was proposed to reduce radiation dose and applied to lung perfusion studies. Normal and ultra-low-dose lung computed tomographic perfusion studies were compared in terms of the estimation

  7. Pipeline Strategy for Improving Optimal Energy Efficiency in Ultra-Low Voltage Design

    E-Print Network [OSTI]

    Kambhampati, Subbarao

    Pipeline Strategy for Improving Optimal Energy Efficiency in Ultra-Low Voltage Design Mingoo Seok technique that provides higher energy effi- ciency and performance than conventional approaches to ultra low to further improve energy efficiency and performance. Silicon results demonstrate a 16b mul- tiplier using

  8. Ultra-low power microwave CHFET integrated circuit development

    SciTech Connect (OSTI)

    Baca, A.G.; Hietala, V.M.; Greenway, D.; Sloan, L.R.; Shul, R.J.; Muyshondt, G.P.; Dubbert, D.F.

    1998-04-01

    This report summarizes work on the development of ultra-low power microwave CHFET integrated circuit development. Power consumption of microwave circuits has been reduced by factors of 50--1,000 over commercially available circuits. Positive threshold field effect transistors (nJFETs and PHEMTs) have been used to design and fabricate microwave circuits with power levels of 1 milliwatt or less. 0.7 {micro}m gate nJFETs are suitable for both digital CHFET integrated circuits as well as low power microwave circuits. Both hybrid amplifiers and MMICs were demonstrated at the 1 mW level at 2.4 GHz. Advanced devices were also developed and characterized for even lower power levels. Amplifiers with 0.3 {micro}m JFETs were simulated with 8--10 dB gain down to power levels of 250 microwatts ({mu}W). However 0.25 {micro}m PHEMTs proved superior to the JFETs with amplifier gain of 8 dB at 217 MHz and 50 {mu}W power levels but they are not integrable with the digital CHFET technology.

  9. Ultra-low rare earth element content in accreted ice from sub-glacial Lake Vostok, Antarctica

    E-Print Network [OSTI]

    Howat, Ian M.

    Ultra-low rare earth element content in accreted ice from sub-glacial Lake Vostok, Antarctica Paolo. We suggest that such ultra-low concentrations are unlikely to be representative of the real REE

  10. Active and Passive Elec. Comp., September 2003, Vol. 26, pp. 151166 ULTRA-LOW TEMPERATURE COEFFICIENT OF

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    Active and Passive Elec. Comp., September 2003, Vol. 26, pp. 151­166 ULTRA-LOW TEMPERATURE that this material system possessed low dielectric constant and ultra-low temperature coefficient of capacitance (TCC

  11. Life-Cycle Energy Demand of Computational Logic: From High-Performance 32nm CPU to Ultra-Low-Power 130nm MCU

    E-Print Network [OSTI]

    Bol, David; Boyd, Sarah; Dornfeld, David

    2011-01-01

    Performance 32 nm CPU to Ultra-Low-Power 130 nm MCU Davidboxes and smart phones to ultra-low-power 130 nm MCUs forthe energy demand for ultra-low-power MCUs is completely

  12. Analgesia, enhancement of spinal morphine antinociception, and inhibition of tolerance by ultra-low dose of the ?2A-adrenoceptor selective antagonist BRL44408

    E-Print Network [OSTI]

    2014-01-01

    Shen, K.F. , 1995. Ultra-low concentrations of naloxoneCahill, C.M. , 2010. Ultra-low dose naltrexone attenuatesand hyperalgesia by an ultra-low dose of the alpha-2-

  13. Life-Cycle Energy Demand of Computational Logic: From High-Performance 32nm CPU to Ultra-Low-Power 130nm MCU

    E-Print Network [OSTI]

    Bol, David; Boyd, Sarah; Dornfeld, David

    2011-01-01

    Performance 32 nm CPU to Ultra-Low-Power 130 nm MCU Davidboxes and smart phones to ultra-low-power 130 nm MCUs forthe energy demand for ultra-low-power MCUs is completely

  14. A Novel Si-Tunnel FET based SRAM Design for Ultra Low-Power 0.3V VDD Applications

    E-Print Network [OSTI]

    Yener, Aylin

    A Novel Si-Tunnel FET based SRAM Design for Ultra Low-Power 0.3V VDD Applications J. Singh, K-Band Tunnel Field Effect Transistors (TFETs) in SRAMs at ultra low supply voltages. The uni design using Si- TFETs for reliable operation with low leakage at ultra low voltages. We also demonstrate

  15. Characterization of oxygen and nitrogen rapid thermal annealing processes for ultra-low-k SiCOH films

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    Characterization of oxygen and nitrogen rapid thermal annealing processes for ultra-low-k Si is suggested and characterized in this work for improvement of SiCOH ultra-low-k (k 2.4) film properties. Low is decreased, and the ultra-low-k films (k

  16. Chair for Computer Networks and Internet -Universitt Tbingen 1 ffor an open source, ultra low delay audio coding

    E-Print Network [OSTI]

    Carle, Georg

    an open source, ultra low delay audio coding Extending the packet loss concealment algorithm ITU G 711 A di 1 t f ll b d idthITU G.711 Appendix 1 to full bandwidth Comparing ultra low delay audio codecs SSummary Chair for Computer Networks and Internet - Universität Tübingen 2 #12;From speech to ultra-low

  17. MAC Design for Supporting Ultra Low Duty Cycle in Wireless Sensor Networks1 *Wooguil PakO

    E-Print Network [OSTI]

    Bahk, Saewoong

    MAC Design for Supporting Ultra Low Duty Cycle in Wireless Sensor Networks1 *Wooguil PakO , *Hyuk.1%). Our proposed U-MAC (Ultra low duty cycle MAC) protocol targets achieving low energy consumption under. In this paper, we propose a new MAC algorithm called U-MAC (Ultra low duty cycle MAC) that works effectively

  18. Trading off Reliability and Power-Consumption in Ultra-Low Power Systems Atul Maheshwari, Wayne Burleson and Russell Tessier

    E-Print Network [OSTI]

    Tessier, Russell

    Trading off Reliability and Power-Consumption in Ultra-Low Power Systems Atul Maheshwari, Wayne but also for ultra-low power consumption due to limited battery life. This paper explores architecture (Binary and Gray) we show that temporal re- dundancy is best suited for these ultra-low power and low

  19. Modeling the ratios of SKKS and SKS amplitudes with ultra-low velocity zones at the core-mantle boundary

    E-Print Network [OSTI]

    Ritsema, Jeroen

    Modeling the ratios of SKKS and SKS amplitudes with ultra-low velocity zones at the core of earthquakes in Indonesia. Modeling of SKKS/SKS indicate that Ultra-Low Velocity Zones (ULVZs), layers, and M. S. Thorne (2009), Modeling the ratios of SKKS and SKS amplitudes with ultra-low velocity zones

  20. Centralized route recovery based on multi-hop wakeup time estimation for wireless sensor networks with ultra low duty cycles

    E-Print Network [OSTI]

    Bahk, Saewoong

    with ultra low duty cycles Wooguil Pak, Saewoong Bahk Department of EECS & INMC, Seoul National University Keywords: Wireless sensor network Routing protocol Ultra low duty cycle Network lifetime Multi-hop wakeup time estimation to maximize the network lifetime of WSNs under ultra low duty cycles. It does not use

  1. Seismic structure and ultra-low velocity zones at the base of the Earth's mantle beneath Southeast Asia

    E-Print Network [OSTI]

    Wen, Lianxing

    Seismic structure and ultra-low velocity zones at the base of the Earth's mantle beneath Southeast t We constrain seismic structure and ultra-low velocity zones near the Earth's core-mantle boundary that the strong scatterers represent ultra-low velocity zones (ULVZs). We suggest that the seismic structure

  2. Ultra low resistance, non-alloyed ohmic contacts to n-InGaAs Ashish K. Baraskar1

    E-Print Network [OSTI]

    Rodwell, Mark J. W.

    Ultra low resistance, non-alloyed ohmic contacts to n-InGaAs Ashish K. Baraskar1 , Mark A. Wistey1 and fmax [1], [2]. Here we report the ultra-low specific contact resistivity (c) of non-alloyed in duration. These data indicate that the in-situ Mo gives ultra low Ohmic contacts, probably due

  3. Ultra-low field nuclear magnetic resonance and magnetic resonance imaging to discriminate and identify materials

    DOE Patents [OSTI]

    Kraus, Robert H. (Los Alamos, NM); Matlashov, Andrei N. (Los Alamos, NM); Espy, Michelle A. (Los Alamos, NM); Volegov, Petr L. (Los Alamos, NM)

    2010-03-30

    An ultra-low magnetic field NMR system can non-invasively examine containers. Database matching techniques can then identify hazardous materials within the containers. Ultra-low field NMR systems are ideal for this purpose because they do not require large powerful magnets and because they can examine materials enclosed in conductive shells such as lead shells. The NMR examination technique can be combined with ultra-low field NMR imaging, where an NMR image is obtained and analyzed to identify target volumes. Spatial sensitivity encoding can also be used to identify target volumes. After the target volumes are identified the NMR measurement technique can be used to identify their contents.

  4. Ultra-Low Sulfur diesel Update & Future Light Duty Diesel | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Diesel Vehicles BiodieselFuelManagementBestPracticesReport.pdf A Life-Cycle Assessment Comparing Select Gas-to-Liquid Fuels with Conventional Fuels in the...

  5. Transition to Ultra-Low-Sulfur Diesel Fuel: Effects on Prices and Supply, The

    Reports and Publications (EIA)

    2001-01-01

    This report discusses the implications of the new regulations for vehicle fuel efficiency and examines the technology, production, distribution, and cost implications of supplying diesel fuel to meet the new standards.

  6. DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 2015 GATEWAY Takes 9. TechnologyDOE Web Managers

  7. Design and evaluation of a device for trapping hepatitis C viral particles at ultra low concentrations

    E-Print Network [OSTI]

    Ekchian, Gregory J

    2010-01-01

    A new method to quantify hepatitis C (HCV) viral particles when present in ultra low concentrations is being developed. Hepatitis C is a viral infection that affects the liver. There are 3.2 million people in the United ...

  8. Vehicle Technologies Office Merit Review 2014: Thermally Stable Ultra-Low Temperature Oxidation Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by [company name] at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about thermally stable ultra-low...

  9. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  10. IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES, VOL. 51, NO. 6, JUNE 2003 1705 Cryogenic Wide-Band Ultra-Low-Noise IF

    E-Print Network [OSTI]

    -Band Ultra-Low-Noise IF Amplifiers Operating at Ultra-Low DC Power Niklas Wadefalk, Anders Mellberg, Iltcho Identifier 10.1109/TMTT.2003.812570 ultra-low-noise and ultra-low dc power dissipation are of interest--This paper describes cryogenic broad-band ampli- fiers with very low power consumption and very low noise

  11. Ultra-low power, Zeno effect based optical modulation in a degenerate V-system with a

    E-Print Network [OSTI]

    Shahriar, Selim

    Ultra-low power, Zeno effect based optical modulation in a degenerate V-system with a tapered nano@northwestern.edu Abstract: We demonstrate an ultra-low light level optical modulator using a tapered nano fiber embedded. For a control power of 40 nW and a signal power of 100 pW, we observe near 100% modulation. The ultra-low power

  12. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOE’s) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  13. High Performance Plasma Sputtered PdPt Fuel Cell Electrodes with Ultra Low Loading

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    fuel cells currently used in cars have a resource efficiency of 1 or 2 kW gPt -1 . The high amount of platinum makes commercial fuel cells reliable but the resource efficiency is far too low to provideHigh Performance Plasma Sputtered PdPt Fuel Cell Electrodes with Ultra Low Loading M. Mougenot1, 2

  14. High rate, long-distance quantum key distribution over 250km of ultra low loss fibres

    E-Print Network [OSTI]

    D. Stucki; N. Walenta; F. Vannel; R. T. Thew; N. Gisin; H. Zbinden; S. Gray; C. R. Towery; S. Ten

    2009-03-23

    We present a fully automated quantum key distribution prototype running at 625 MHz clock rate. Taking advantage of ultra low loss fibres and low-noise superconducting detectors, we can distribute 6,000 secret bits per second over 100 km and 15 bits per second over 250km.

  15. High Performance Plasma Sputtered Fuel Cell Electrodes with Ultra Low catalytic metal Loadings

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 High Performance Plasma Sputtered Fuel Cell Electrodes with Ultra Low catalytic metal Loadings C in plasma fuel cell deposition devices. Pt loadings lower than 0.01 mg cm-2 have been realized. The Pt density of 250 kW gPt -1 . 1-Introduction The great potential for the fuel cell technology to overcome

  16. Ultra-low power fiber-coupled gallium arsenide photonic crystal cavity electro-optic modulator

    E-Print Network [OSTI]

    Vuckovic, Jelena

    -induced change in refractive index of InP, GaAs, and InGaAsP," IEEE J. Quantum Electron. 26(1), 113­122 (1990). 7, "Ultra-low threshold, electrically pumped quantum dot photonic crystal nanocavity laser," to be published

  17. Ultra Low-Power implementation of ECC on the ARM Cortex-M0+

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Ultra Low-Power implementation of ECC on the ARM Cortex-M0+ Ruan de Clercq, Leif Uhsadel, Anthony of a public-key cryptography algorithm on the ARM Cortex-M0+. The goal of this implementation is to make selection, the energy consumption of different instructions on the ARM Cortex-M0+ was measured

  18. Graphene nanoribbon based negative resistance device for ultra-low voltage digital logic applications

    E-Print Network [OSTI]

    Graphene nanoribbon based negative resistance device for ultra-low voltage digital logic). In this paper, a design for a 2-port negative resistance device based on arm-chair graphene nanoribbon of the semiconductor, which leads to high excess current.2 In this paper, we propose a negative resistance device based

  19. Delayed Linear Expansion of Two Ultra-low Expansion Dental Stones 

    E-Print Network [OSTI]

    Oppedisano, Michael

    2013-12-20

    The purpose of this study was to measure the linear setting expansion of two ultra-low expansion dental stones used in definitive cast/ prosthesis fabrication which claim to have very low to no setting expansion. Five specimens of each material...

  20. Dozer: Ultra-Low Power Data Gathering in Sensor Networks Nicolas Burri

    E-Print Network [OSTI]

    Maróti, Miklós

    or solar cells, energy efficiency is a fundamental requisite for prolonged network lifetime. All sensor- mit data from all nodes in a possibly large area to the data sink. Energy-efficient data exchangeDozer: Ultra-Low Power Data Gathering in Sensor Networks Nicolas Burri Computer Engineering

  1. Stainless steel pitting and early-stage stress corrosion cracking under ultra-low elastic load

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Stainless steel pitting and early-stage stress corrosion cracking under ultra-low elastic load Available online 7 September 2013 Keywords: A. Stainless steel B. SEM B. Modeling studies C. Stress] in stainless steel (SS), are key factors inducing the preferential pitting initiation. For homoge- neous

  2. Development of Ultra-low Platinum Alloy C th d C t l t f PEM F l C ll

    E-Print Network [OSTI]

    Development of Ultra-low Platinum Alloy C th d C t l t f PEM F l C ll Cathode Catalyst for PEM Objectives · Ultra-low loading Pt catalyysts for oxygen reduction reaction with higgh activityyand ggoodg yg Definition ­ In Developing Low Loading Platinum Catalysts · C l PCatalyst Perfformance ¾ Platinum

  3. EVALUATION OF EFFICACY AND HUMAN HEALTH RISK OF AERIAL ULTRA-LOW VOLUME APPLICATIONS OF PYRETHRINS AND

    E-Print Network [OSTI]

    Peterson, Robert K. D.

    EVALUATION OF EFFICACY AND HUMAN HEALTH RISK OF AERIAL ULTRA-LOW VOLUME APPLICATIONS OF PYRETHRINS). A human health risk assessment conducted by Peterson et al. (2006) for truck-mounted ultra-low volume (ULV to epidemic levels and dispersed to all 58 counties in the state, and was associated with low

  4. Ultra low-mass star and substellar formation in sigma Orionis

    E-Print Network [OSTI]

    J. A. Caballero

    2005-11-07

    The nearby young sigma Orionis cluster (~360 pc, ~3 Ma) is becoming one of the most important regions for the study of ultra low-mass star formation and its extension down to the mass regimes of the brown dwarfs and planetary-mass objects. Here, I introduce the sigma Orionis cluster and present three studies that the JOVIAN group is developing: a pilot programme of near-infrared adaptive-optics imaging, intermediate-resolution optical spectroscopy of a large sample of stars of the cluster and a study of the mass function down to the planetary-mass domain. This paper is a summary of the content of four posters that I presented in the Ultra low-mass star formation and evolution Workshop, as single author or on behalf of different collaborations.

  5. Diffuse Surface Scattering in the Plasmonic Resonances of Ultra-Low Electron Density Nanospheres

    E-Print Network [OSTI]

    Monreal, R Carmina; Apell, S Peter

    2015-01-01

    Localized surface plasmon resonances (LSPRs) have recently been identified in extremely diluted electron systems obtained by doping semiconductor quantum dots. Here we investigate the role that different surface effects, namely electronic spill-out and diffuse surface scattering, play in the optical properties of these ultra-low electron density nanosystems. Diffuse scattering originates from imperfections or roughness at a microscopic scale on the surface. Using an electromagnetic theory that describes this mechanism in conjunction with a dielectric function including the quantum size effect, we find that the LSPRs show an oscillatory behavior both in position and width for large particles and a strong blueshift in energy and an increased width for smaller radii, consistent with recent experimental results for photodoped ZnO nanocrystals. We thus show that the commonly ignored process of diffuse surface scattering is a more important mechanism affecting the plasmonic properties of ultra-low electron density ...

  6. Integrated production/use of ultra low-ash coal, premium liquids and clean char

    SciTech Connect (OSTI)

    Kruse, C.W.

    1991-01-01

    This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  7. Multi-Gate Modulation Doped In0.7Ga0.3As Quantum Well FET for Ultra Low Power Digital Logic

    E-Print Network [OSTI]

    Yener, Aylin

    Multi-Gate Modulation Doped In0.7Ga0.3As Quantum Well FET for Ultra Low Power Digital Logic L. LiuQFET is promising device architecture for future ultra low power information processing applications. Introduction for reconfigurable and ultra-low-power binary decision diagram (BDD) logic ECS Transactions, 35 (3) 311-317 (2011) 10

  8. A Baseband Ultra-Low Noise SiGe:C BiCMOS 0.25 m Amplifier And Its Application For

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A Baseband Ultra-Low Noise SiGe:C BiCMOS 0.25 µm Amplifier And Its Application For An On-Chip Phase of an ultra-low noise operational amplifier is presented. Its applications are integrated low-frequency noise and ultra low input noise to achieve the required signal to noise ratio. In these instrumentation

  9. Novel ultra-low power RF Lateral BJT on 801-CMOS compatible substrate

    E-Print Network [OSTI]

    Ng, Wai Tung

    Novel ultra-low power RF Lateral BJT on 801-CMOS compatible substrate I-Shan Michael Sun, Wai Tung) in the range between 190-300 GHz*V. The frax of the optimal device reaches 46 GHz at collector current density) for the collector region, which is incompatible with thin-film SOI-CMOS [2]. An alternative that uses thin-film SOI

  10. Impact of picolitre droplets on superhydrophobic surfaces with ultra-low spreading ratios

    E-Print Network [OSTI]

    Brown, P.S.; Berson, A.; Talbot, E.L.; Wood, T.J.; Schofield, W.C.E.; Bain, C.D.; Badyal, J.P.S.

    2011-01-01

    :24 1 IMPACT OF PICOLITRE DROPLETS ON SUPERHYDROPHOBIC SURFACES WITH ULTRA-LOW SPREADING RATIOS P. S. Brown, A. Berson, E. L. Talbot, T. J. Wood, W. C. E. Schofield, C. D. Bain†, and J. P. S. Badyal†* Department of Chemistry Science... the dynamics of wetting to be precisely controlled. Final spreading ratios as low as 0.63 can be achieved. Comparison of the maximum spreading ratio and droplet oscillation frequencies with models described in the literature shows that both are found...

  11. CASCADES: An Ultra-Low-Background Germanium Crystal Array at Pacific Northwest National Laboratory

    SciTech Connect (OSTI)

    Keillor, M. E.; Aalseth, C. E.; Day, A. R.; Erikson, L. E.; Fast, J. E.; Glasgow, B. D.; Hoppe, E. W.; Hossbach, T. W.; Hyronimus, B. J.; Miley, H. S.; Myers, A. W.; Seifert, A.; Stavenger, T. J. [Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352 (United States)

    2011-12-13

    State-of-the-art treaty verification techniques, environmental surveillance, and physics experiments require increased sensitivity for detecting and quantifying radionuclides of interest. This can be accomplished with new detector designs that establish high detection efficiency and reduced instrument backgrounds. Current research is producing an intrinsic germanium (HPGe) array designed for high detection efficiency, ultra-low-background performance, and sensitive {gamma}--{gamma} coincidence detection. The system design is optimized to accommodate filter paper samples, e.g. samples collected by the Radionuclide Aerosol Sampler/Analyzer. The system will provide high sensitivity for weak collections on atmospheric filter samples (e.g.<10{sup 5} fissions) as well as offering the potential to gather additional information from higher activity filters using gamma cascade coincidence detection. The first of two HPGe crystal arrays in ultra-low-background vacuum cryostats has been assembled, with the second in progress. Traditional methods for constructing ultra-low-background detectors were followed, including use of materials known to be low in radioactive contaminants, use of ultra-pure reagents, and clean room assembly. The cryostat is constructed mainly from copper electroformed into near-final geometry at Pacific Northwest National Laboratory. Details of the detector assembly and initial background and spectroscopic measurement results are presented; also a description of the custom analysis package used by this project is given.

  12. CASCADES: An Ultra-Low-Background Germanium Crystal Array at Pacific Northwest National Laboratory

    SciTech Connect (OSTI)

    Keillor, Martin E.; Aalseth, Craig E.; Day, Anthony R.; Erikson, Luke E.; Fast, James E.; Glasgow, Brian D.; Hoppe, Eric W.; Hossbach, Todd W.; Hyronimus, Brian J.; Miley, Harry S.; Myers, Allan W.; Seifert, Allen; Stavenger, Timothy J.

    2011-07-14

    State-of-the-art treaty verification techniques, environmental surveillance, and physics experiments require increased sensitivity for detecting and quantifying radionuclides of interest. This can be accomplished with new detector designs that establish high detection efficiency and reduced instrument backgrounds. Current research is producing an intrinsic germanium (HPGe) array designed for high detection efficiency, ultra-low-background performance, and sensitive {gamma}-{gamma} coincidence detection. The system design is optimized to accommodate filter paper samples, e.g., samples collected by the Radionuclide Aerosol Sampler/Analyzer. The system will provide high sensitivity for weak collections on atmospheric filter samples (e.g., < 10{sup 5} fissions), as well as offering the potential to gather additional information from higher activity filters using gamma cascade coincidence detection. The first of two HPGe crystal arrays in ultra-low-background vacuum cryostats has been assembled, with the second in progress. Traditional methods for constructing ultra-low-background detectors were followed, including use of materials known to be low in radioactive contaminants, use of ultra-pure reagents, and clean room assembly. The cryostat is constructed mainly from copper electroformed into near-final geometry at Pacific Northwest National Laboratory. Details of the detector assembly and initial background and spectroscopic measurement results are presented; also a description of the custom analysis package used by this project is given.

  13. Measurement of Untruncated Nuclear Spin Interactions via Zero- to Ultra-Low-Field Nuclear Magnetic Resonance

    E-Print Network [OSTI]

    John W. Blanchard; Tobias F. Sjolander; Jonathan P. King; Micah P. Ledbetter; Emma H. Levine; Vikram S. Bajaj; Dmitry Budker; Alexander Pines

    2015-07-09

    Zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) provides a new regime for the measurement of nuclear spin-spin interactions free from effects of large magnetic fields, such as truncation of terms that do not commute with the Zeeman Hamiltonian. One such interaction, the magnetic dipole-dipole coupling, is a valuable source of spatial information in NMR, though many terms are unobservable in high-field NMR, and the coupling averages to zero under isotropic molecular tumbling. Under partial alignment, this information is retained in the form of so-called residual dipolar couplings. We report zero- to ultra-low-field NMR measurements of residual dipolar couplings in acetonitrile-2-$^{13}$C aligned in stretched polyvinyl acetate gels. This represents the first investigation of dipolar couplings as a perturbation on the indirect spin-spin $J$-coupling in the absence of an applied magnetic field. As a consequence of working at zero magnetic field, we observe terms of the dipole-dipole coupling Hamiltonian that are invisible in conventional high-field NMR. This technique expands the capabilities of zero- to ultra-low-field NMR and may have applications in precision measurement of subtle physical interactions, chemical analysis, and characterization of local mesoscale structure in materials.

  14. Jump Chaotic Behaviour of Ultra Low Loss Bulk Acoustic Wave Cavities

    E-Print Network [OSTI]

    Maxim Goryachev; Warrick G. Farr; Serge Galliou; Michael E. Tobar

    2014-06-16

    We demonstrate a previously unobserved nonlinear phenomenon in an ultra-low loss quartz Bulk Acoustic Wave cavity ($Q>3\\times10^9$), which only occurs below 20 milli-Kelvin in temperature and under relatively weak pumping. The phenomenon reveals the emergence of several stable equilibria (at least two foci and two nodes) and jumps between these quasi states at random times. The degree of this randomness as well as separations between levels can be controlled by the frequency of the incident carrier signal. It is demonstrated that the nature of the effect lays beyond the standard Duffing model.

  15. Jump chaotic behaviour of ultra low loss bulk acoustic wave cavities

    SciTech Connect (OSTI)

    Goryachev, Maxim, E-mail: maxim.goryachev@uwa.edu.au; Farr, Warrick G.; Tobar, Michael E. [ARC Centre of Excellence for Engineered Quantum Systems, University of Western Australia, 35 Stirling Highway, Crawley WA 6009 (Australia); Galliou, Serge [Department of Time and Frequency, FEMTO-ST Institute, ENSMM, 26 Chemin de l'Épitaphe 25000 Besançon (France)

    2014-08-11

    We demonstrate a previously unobserved nonlinear phenomenon in an ultra-low loss quartz bulk acoustic wave cavity (Q>3>10{sup 9}), which only occurs below 20 mK in temperature and under relatively weak pumping. The phenomenon reveals the emergence of several stable equilibria (at least two foci and two nodes) and jumps between these quasi states at random times. The degree of this randomness as well as separations between levels can be controlled by the frequency of the incident carrier signal. It is demonstrated that the nature of the effect lies beyond the standard Duffing model.

  16. High excitation power photoluminescence studies of ultra-low density GaAs quantum dots

    SciTech Connect (OSTI)

    Sonnenberg, D.; Graf, A.; Paulava, V.; Heyn, Ch.; Hansen, W. [Institut für Angewandte Physik und Zentrum für Mikrostrukturforschung, Universität Hamburg, Jungiusstr. 11, 20355 Hamburg (Germany)

    2013-12-04

    We fabricate GaAs epitaxial quantum dots (QDs) by filling of self-organized nanoholes in AlGaAs. The QDs are fabricated under optimized process conditions and have ultra-low density in the 10{sup 6} cm{sup ?2} regime. At low excitation power the optical emission of single QDs exhibit sharp excitonic lines, which are attributed to the recombination of excitonic and biexcitonic states. High excitation power measurements reveal surprisingly broad emission lines from at least six QD shell states.

  17. Natural Theories of Ultra-Low Mass PNGB's: Axions and Quintessence

    E-Print Network [OSTI]

    Christopher T. Hill; Adam K. Leibovich

    2002-06-06

    We consider the Wilson Line PNGB which arises in a U(1)^N gauge theory, abstracted from a latticized, periodically compactified extra dimension U(1). Planck scale breaking of the PNGB's global symmetry is suppressed, providing natural candidates for the axion and quintessence. We construct an explicit model in which the axion may be viewed as the 5th component of the U(1)_Y gauge field in a 1+4 latticized periodically compactified extra dimension. We also construct a quintessence PNGB model where the ultra-low mass arises from Planck-scale suppressed physics itself.

  18. Coherent-feedback control strategy to suppress spontaneous switching in ultra-low power optical bistability

    E-Print Network [OSTI]

    Hideo Mabuchi

    2011-01-18

    An optical resonator with intracavity Kerr nonlinearity can exhibit dispersive bistability suitable for all-optical switching. With nanophotonic elements it may be possible to achieve attojoule switching energies, which would be very attractive for ultra-low power operation but potentially problematic because of quantum fluctuation-induced spontaneous switching. In this manuscript I derive a quantum-optical model of two Kerr-nonlinear ring resonators connected in a coherent feedback loop, and show via numerical simulation that a properly designed `controller' cavity can significantly reduce the spontaneous switching rate of a bistable `plant' cavity in a completely embedded and autonomous manner.

  19. The Majorana experiment: an ultra-low background search for neutrinoless double-beta decay

    E-Print Network [OSTI]

    D. G. Phillips II; E. Aguayo; F. T. Avignone III; H. O. Back; A. S. Barabash; M. Bergevin; F. E. Bertrand; M. Boswell; V. Brudanin; M. Busch; Y. -D. Chan; C. D. Christofferson; J. I. Collar; D. C. Combs; R. J. Cooper; J. A. Detwiler; P. J. Doe; Y. Efremenko; V. Egorov; H. Ejiri; S. R. Elliott; J. Esterline; J. E. Fast; N. Fields; P. Finnerty; F. M. Fraenkle; V. M. Gehman; G. K. Giovanetti; M. P. Green; V. E. Guiseppe; K. Gusey; A. L. Hallin; R. Hazama; R. Henning; A. Hime; E. W. Hoppe; M. Horton; S. Howard; M. A. Howe; R. A. Johnson; K. J. Keeter; C. Keller; M. F. Kidd; A. Knecht; O. Kochetov; S. I. Konovalov; R. T. Kouzes; B. LaFerriere; B. H. LaRoque; J. Leon; L. E. Leviner; J. C. Loach; S. MacMullin; M. G. Marino; R. D. Martin; D. -M. Mei; J. Merriman; M. L. Miller; L. Mizouni; M. Nomachi; J. L. Orrell; N. R. Overman; A. W. P. Poon; G. Perumpilly; G. Prior; D. C. Radford; K. Rielage; R. G. H. Robertson; M. C. Ronquest; A. G. Schubert; T. Shima; M. Shirchenko; K. J. Snavely; D. Steele; J. Strain; K. Thomas; V. Timkin; W. Tornow; I. Vanyushin; R. L. Varner; K. Vetter; K. Vorren; J. F. Wilkerson; B. A. Wolfe; E. Yakushev; A. R. Young; C. -H. Yu; V. Yumatov; C. Zhang

    2011-11-23

    The observation of neutrinoless double-beta decay would resolve the Majorana nature of the neutrino and could provide information on the absolute scale of the neutrino mass. The initial phase of the Majorana experiment, known as the Demonstrator, will house 40 kg of Ge in an ultra-low background shielded environment at the 4850' level of the Sanford Underground Laboratory in Lead, SD. The objective of the Demonstrator is to determine whether a future 1-tonne experiment can achieve a background goal of one count per tonne-year in a narrow region of interest around the 76Ge neutrinoless double-beta decay peak.

  20. Measurements of ultra-low-energy electron scattering cross sections of atoms and molecules

    SciTech Connect (OSTI)

    Kitajima, M.; Shigemura, K.; Kurokawa, M. [Department of Chemistry, Tokyo Institute of Technology, 152-8551 Tokyo (Japan); Odagiri, T. [Department of Physics, Sophia University, 102-8554 Tokyo, Japan and Department of Chemistry, Tokyo Institute of Technology, 152-8551 Tokyo (Japan); Kato, H.; Hoshino, M.; Tanaka, H. [Department of Physics, Sophia University, 102-8554 Tokyo (Japan); Ito, K. [Photon Factory, Institute of Materials Structure Science, 305-0801 Tsukuba (Japan)

    2014-03-05

    A new experimental technique for the total cross section measurements of ultra-low energy electron collisions with atoms and molecules utilizing the synchrotron radiation is presented. The technique employs a combination of the penetrating field technique and the threshold photoionization of rare gas atoms using the synchrotron radiation as an electron source in order to produce a high resolution electron beam at very low energy. Absolute total cross sections for electron scattering from He, Ne, Ar, Kr, and Xe in the energy region from extremely low electron energy to 20 eV are presented.

  1. The MAJORANA experiment: an ultra-low background search for neutrinoless double-beta decay

    SciTech Connect (OSTI)

    Phillips, D.; Aguayo Navarrete, Estanislao; Avignone, Frank T.; Back, Henning O.; Barabash, Alexander S.; Bergevin, M.; Bertrand, F.; Boswell, M.; Brudanin, V.; Busch, Matthew; Chan, Yuen-Dat; Christofferson, Cabot-Ann; Collar, J. I.; Combs, Dustin C.; Cooper, R. J.; Detwiler, Jason A.; Doe, Peter J.; Efremenko, Yuri; Egorov, Viatcheslav; Ejiri, H.; Elliott, Steven R.; Esterline, James H.; Fast, James E.; Fields, N.; Finnerty, P.; Fraenkle, Florian; Gehman, Victor; Giovanetti, G. K.; Green, Matthew P.; Guiseppe, Vincente; Gusey, K.; Hallin, A. L.; Hazama, R.; Henning, Reyco; Hime, Andrew; Hoppe, Eric W.; Horton, Mark; Howard, Stanley; Howe, M. A.; Johnson, R. A.; Keeter, K.; Keller, C.; Kidd, Mary; Knecht, A.; Kochetov, Oleg; Konovalov, S.; Kouzes, Richard T.; LaFerriere, Brian D.; LaRoque, B. H.; Leon, Jonathan D.; Leviner, L.; Loach, J. C.; MacMullin, S.; Marino, Michael G.; Martin, R. D.; Mei, Dong-Ming; Merriman, Jason H.; Miller, M. L.; Mizouni, Leila; Nomachi, Masaharu; Orrell, John L.; Overman, Nicole R.; Poon, Alan; Perumpilly, Gopakumar; Prior, Gersende; Radford, D. C.; Rielage, Keith; Robertson, R. G. H.; Ronquest, M. C.; Schubert, Alexis G.; Shima, T.; Shirchenko, M.; Snavely, Kyle J.; Steele, David; Strain, J.; Thomas, K.; Timkin, V.; Tornow, W.; Vanyushin, I.; Varner, R. L.; Vetter, Kai; Vorren, Kris R.; Wilkerson, J. F.; Wolfe, B. A.; Yakushev, E.; Young, A.; Yu, Chang-Hong; Yumatov, Vladimir; Zhang, C.

    2012-12-01

    The observation of neutrinoless double-beta decay would resolve the Majorana nature of the neutrino and could provide information on the absolute scale of the neutrino mass. The initial phase of the Majorana Experiment, known as the Demonstrator, will house 40 kg of Ge in an ultra-low background shielded environment at the 4850' level of the Sanford Underground Laboratory in Lead, SD. The objective of the Demonstrator is to validate whether a future 1-tonne experiment can achieve a background goal of one count per tonne-year in a narrow region of interest around the 76Ge neutrinoless double-beta decay peak.

  2. Ultra-Low-Energy Germanium Detector for Neutrino-Nucleus Coherent Scattering and Dark Matter Searches

    E-Print Network [OSTI]

    Henry T. Wong

    2008-03-01

    The status and plans of a research program on the development of ultra-low-energy germanium detectors with sub-keV sensitivities are reported. We survey the scientific goals which include the observation of neutrino-nucleus coherent scattering, the studies of neutrino magnetic moments, as well as the searches of WIMP dark matter. In particular, a threshold of 100-200 eV and a sub-keV background comparable to underground experiments were achieved with prototype detectors. New limits were set for WIMPs with mass between 3-6 GeV. The prospects of the realization of full-scale experiments are discussed.

  3. Ultra-low field nuclear magnetic resonance and magnetic resonance imaging to discriminate and identify materials

    DOE Patents [OSTI]

    Matlashov, Andrei Nikolaevich; Urbaitis, Algis V.; Savukov, Igor Mykhaylovich; Espy, Michelle A.; Volegov, Petr Lvovich; Kraus, Jr., Robert Henry

    2013-03-05

    Method comprising obtaining an NMR measurement from a sample wherein an ultra-low field NMR system probes the sample and produces the NMR measurement and wherein a sampling temperature, prepolarizing field, and measurement field are known; detecting the NMR measurement by means of inductive coils; analyzing the NMR measurement to obtain at least one measurement feature wherein the measurement feature comprises T1, T2, T1.rho., or the frequency dependence thereof; and, searching for the at least one measurement feature within a database comprising NMR reference data for at least one material to determine if the sample comprises a material of interest.

  4. Specifications of the octupole magnets required for the ATF2 ultra-low ß* lattice

    SciTech Connect (OSTI)

    Marin, E.; Modena, M.; Tauchi, T.; Terunuma, N.; Tomas, R.; White, G.R.; /SLAC

    2014-05-28

    The Accelerator Test Facility 2 (ATF2) aims to test the novel chromaticity correction for higher chromaticity lattices as the one of CLIC. To this end the ATF2 ultra-low ß* lattice is designed to vertically focus the beam at the focal point or usually referred to as interaction point (IP), down to 23 nm. However when the measured multipole components of the ATF2 magnets are considered in the simulations, the evaluated spot sizes at the IP are well above the design value. The designed spot size is effectively recovered by inserting a pair of octupole magnets. In this note we address the technical specifications required for these octupole magnets.

  5. Low-noise pulsed pre-polarization magnet system for ultra-low field NMR

    SciTech Connect (OSTI)

    Sims, James R [Los Alamos National Laboratory; Schilling, Josef B [Los Alamos National Laboratory; Swenson, Charles A [Los Alamos National Laboratory; Gardner, David L [Los Alamos National Laboratory; Matlashov, Andrei N [Los Alamos National Laboratory; Ammerman, Curti N [Los Alamos National Laboratory

    2009-01-01

    A liquid cooled, pulsed electromagnet of solenoid configuration suitable for duty in an ultra-low field nuclear magnetic resonance system has been designed, fabricated and successfully operated. The magnet design minimizes Johnson noise, minimizes the hydrogen signal and incorporates minimal metal and no ferromagnetic materials. In addition, an acoustically quiet cooling system permitting 50% duty cycle operation was achieved by designing for single-phase, laminar flow, forced convection cooling. Winding, conductor splicing and epoxy impregnation techniques were successfully developed to produce a coil winding body with integral cooling passageways and adequate structural integrity. Issues of material compatibility, housing, coolant flow system and heat rejection system design will be discussed. Additionally, this pulsed electromagnet design has been extended to produce a boiling liquid cooled version in a paired solenoid configuration suitable for duty in an ultra-low field nuclear magnetic resonance system. This pair of liquid nitrogen cooled coils is currently being tested and commissioned. Issues of material compatibility, thermal insulation, thermal contraction, housing and coolant flow design are discussed.

  6. Calibration of an ultra-low-background proportional counter for measuring {sup 37}Ar

    SciTech Connect (OSTI)

    Seifert, A.; Aalseth, C. E.; Bonicalzi, R. M.; Bowyer, T. W.; Day, A. R.; Fuller, E. S.; Haas, D. A.; Hayes, J. C.; Hoppe, E. W.; Humble, P. H.; Keillor, M. E.; LaFerriere, B. D.; Mace, E. K.; McIntyre, J. I.; Merriman, J. H.; Miley, H. S.; Myers, A. W.; Orrell, J. L.; Overman, C. T.; Panisko, M. E. [Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99352 (United States)] [Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington, 99352 (United States); and others

    2013-08-08

    An ultra-low-background proportional counter design has been developed at Pacific Northwest National Laboratory (PNNL) using clean materials, primarily electro-chemically-purified copper. This detector, along with an ultra-low-background counting system (ULBCS), was developed to complement a new shallow underground laboratory (30 meters water-equivalent) at PNNL. The ULBCS design includes passive neutron and gamma shielding, along with an active cosmic-veto system. This system provides a capability for making ultra-sensitive measurements to support applications like age-dating soil hydrocarbons with {sup 14}C/{sup 3}H, age-dating of groundwater with {sup 39}Ar, and soil-gas assay for {sup 37}Ar to support On-Site Inspection (OSI). On-Site Inspection is a key component of the verification regime for the Comprehensive Nuclear-Test-Ban Treaty (CTBT). Measurements of radionuclides created by an underground nuclear explosion are valuable signatures of a Treaty violation. For OSI, the 35-day half-life of {sup 37}Ar, produced from neutron interactions with calcium in soil, provides both high specific activity and sufficient time for inspection before decay limits sensitivity. This work describes the calibration techniques and analysis methods developed to enable quantitative measurements of {sup 37}Ar samples over a broad range of proportional counter operating pressures. These efforts, along with parallel work in progress on gas chemistry separation, are expected to provide a significant new capability for {sup 37}Ar soil gas background studies.

  7. Controlling Low-Rate Signal Path Microdischarge for an Ultra-Low-Background Proportional Counter

    SciTech Connect (OSTI)

    Mace, Emily K.; Aalseth, Craig E.; Bonicalzi, Ricco; Day, Anthony R.; Hoppe, Eric W.; Keillor, Martin E.; Myers, Allan W.; Overman, Cory T.; Seifert, Allen

    2013-05-01

    ABSTRACT Pacific Northwest National Laboratory (PNNL) has developed an ultra-low-background proportional counter (ULBPC) made of high purity copper. These detectors are part of an ultra-low-background counting system (ULBCS) in the newly constructed shallow underground laboratory at PNNL (at a depth of ~30 meters water-equivalent). To control backgrounds, the current preamplifier electronics are located outside the ULBCS shielding. Thus the signal from the detector travels through ~1 meter of cable and is potentially susceptible to high voltage microdischarge and other sources of electronic noise. Based on initial successful tests, commercial cables and connectors were used for this critical signal path. Subsequent testing across different batches of commercial cables and connectors, however, showed unwanted (but still low) rates of microdischarge noise. To control this noise source, two approaches were pursued: first, to carefully validate cables, connectors, and other commercial components in this critical signal path, making modifications where necessary; second, to develop a custom low-noise, low-background preamplifier that can be integrated with the ULBPC and thus remove most commercial components from the critical signal path. This integrated preamplifier approach is based on the Amptek A250 low-noise charge-integrating preamplifier module. The initial microdischarge signals observed are presented and characterized according to the suspected source. Each of the approaches for mitigation is described, and the results from both are compared with each other and with the original performance seen with commercial cables and connectors.

  8. A University Consortium on Low Temperature Combustion for High Efficiency, Ultra-Low Emission Engines

    SciTech Connect (OSTI)

    Dennis N. Assanis; Arvind Atreya; Jyh-Yuan Chen; Wai K. Cheng; Robert W. Dibble; Chris Edwards; Zoran S. Filipi; Christian Gerdes; Hong Im; George A. Lavoie; Margaret S. Wooldridge

    2009-12-31

    The objective of the University consortium was to investigate the fundamental processes that determine the practical boundaries of Low Temperature Combustion (LTC) engines and develop methods to extend those boundaries to improve the fuel economy of these engines, while operating with ultra low emissions. This work involved studies of thermal effects, thermal transients and engine management, internal mixing and stratification, and direct injection strategies for affecting combustion stability. This work also examined spark-assisted Homogenous Charge Compression Ignition (HCCI) and exhaust after-treatment so as to extend the range and maximize the benefit of Homogenous Charge Compression Ignition (HCCI)/ Partially Premixed Compression Ignition (PPCI) operation. In summary the overall goals were: ? Investigate the fundamental processes that determine the practical boundaries of Low Temperature Combustion (LTC) engines. ? Develop methods to extend LTC boundaries to improve the fuel economy of HCCI engines fueled on gasoline and alternative blends, while operating with ultra low emissions. ? Investigate alternate fuels, ignition and after-treatment for LTC and Partially Premixed compression Ignition (PPCI) engines.

  9. 156 IEEE MICROWAVE AND WIRELESS COMPONENTS LETTERS, VOL. 14, NO. 4, APRIL 2004 An Ultra-Low Power InAs/AlSb HEMT Ka-Band

    E-Print Network [OSTI]

    Rodwell, Mark J. W.

    156 IEEE MICROWAVE AND WIRELESS COMPONENTS LETTERS, VOL. 14, NO. 4, APRIL 2004 An Ultra-Low Power dc power dissipation of the ABCS LNA was an ultra-low 1.5 mW per stage, or 4.5 mW total. This is less amplifier, mil- limeter-waves. I. INTRODUCTION ULTRA-LOW power millimeter-wave low-noise am- plifiers (LP

  10. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-02-10

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  11. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-09-08

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  12. TEMPERATURE ANISOTROPY IN THE PRESENCE OF ULTRA LOW FREQUENCY WAVES IN THE TERRESTRIAL FORESHOCK

    SciTech Connect (OSTI)

    Selzer, L. A.; Hnat, B.; Osman, K. T.; Nakariakov, V. M. [Centre for Fusion, Space and Astrophysics, University of Warwick, Coventry CV4 7AL (United Kingdom); Eastwood, J. P. [Space and Atmospheric Physics, The Blackett Laboratory, Imperial College London, London (United Kingdom); Burgess, D., E-mail: L.A.Selzer@warwick.ac.uk [School of Physics and Astronomy, Queen Mary University of London (United Kingdom)

    2014-06-10

    We report the first study of the correlation between elevated solar wind core plasma temperatures and temperature anisotropy in the terrestrial foreshock. Plasma temperature is enhanced near the fire hose marginal stability threshold in the presence of ultra low frequency (ULF) large amplitude magnetic perturbations, which are intrinsically right-hand circularly polarized. Direct comparison of contemporaneous anisotropic temperatures in the upstream solar wind and the foreshock suggests that the net heating of plasma is mediated via increase of the parallel temperature in the foreshock region where the ULF waves are present. We consider the possibility that a mechanism based on Landau damping, where solar wind plasma temperature parallel to the background magnetic field is increased by interaction with oblique compressible fast magneto-acoustic ULF waves, influences temperature anisotropy.

  13. Method for fabricating an ultra-low expansion mask blank having a crystalline silicon layer

    DOE Patents [OSTI]

    Cardinale, Gregory F. (Oakland, CA)

    2002-01-01

    A method for fabricating masks for extreme ultraviolet lithography (EUVL) using Ultra-Low Expansion (ULE) substrates and crystalline silicon. ULE substrates are required for the necessary thermal management in EUVL mask blanks, and defect detection and classification have been obtained using crystalline silicon substrate materials. Thus, this method provides the advantages for both the ULE substrate and the crystalline silicon in an Extreme Ultra-Violet (EUV) mask blank. The method is carried out by bonding a crystalline silicon wafer or member to a ULE wafer or substrate and thinning the silicon to produce a 5-10 .mu.m thick crystalline silicon layer on the surface of the ULE substrate. The thinning of the crystalline silicon may be carried out, for example, by chemical mechanical polishing and if necessary or desired, oxidizing the silicon followed by etching to the desired thickness of the silicon.

  14. Ultra-low field NMR for detection and characterization of 235 UF6

    SciTech Connect (OSTI)

    Espy, Michelle A; Magnelind, Per E; Matlashov, Andrei N; Urbaitis, Algis V; Volegov, Petr L

    2009-01-01

    We have demonstrated the first ultra-low field (ULF) nuclear magnetic resonance measurements of uranium hexafluoride (UF{sub 6}), both depleted and 70% enriched, which is used in the uranium enrichment process. A sensitive non-invasive detection system would have an important role in non-proliferation surveillance. A two-frequency technique was employed to remove the transients induced by rapidly switching off the 50 mT pre-polarization field. A mean transverse relaxation time T{sub 2} of 24 ms was estimated for the un-enriched UF{sub 6} sample measured at a mean temperature of 80 C. Nuclear magnetic resonance at ULF has several advantages including the ability to measure through metal, such as pipes, and simple magnetic field generation hardware. We present here recent data and discuss the potential for non-proliferation monitoring of enrichment and flow velocity.

  15. Ultra low energy results and their impact to dark matter and low energy neutrino physics

    E-Print Network [OSTI]

    E. Bougamont; P. Colas; J. Derre; I. Giomataris; G. Gerbier; M. Gros; P. Magnier; X. F. Navick; P. Salin; I. Savvidis; G. Tsiledakis; J. D. Vergados

    2010-10-20

    We present ultra low energy results taken with the novel Spherical Proportional Counter. The energy threshold has been pushed down to about 25 eV and single electrons are clearly collected and detected. To reach such performance low energy calibration systems have been successfully developed: - A pulsed UV lamp extracting photoelectrons from the inner surface of the detector - Various radioactive sources allowing low energy peaks through fluorescence processes. The bench mark result is the observation of a well resolved peak at 270 eV due to carbon fluorescence which is unique performance for such large-massive detector. It opens a new window in dark matter and low energy neutrino search and may allow detection of neutrinos from a nuclear reactor or from supernova via neutrino-nucleus elastic scattering

  16. Low energy conversion electron detection in superfluid He3 at ultra-low temperature

    E-Print Network [OSTI]

    E. Moulin; C. Winkelmann; J. F. Macias-Perez; Yu. M. Bunkov; H. Godfrin; D. Santos

    2005-04-12

    We report on the first results of the MACHe3 (MAtrix of Cells of Helium 3) prototype experiment concerning the measurement of low energy conversion electrons at ultra-low temperature. For the first time, the feasibility of the detection of low energy electrons is demonstrated in superfluid He3-B cooled down to 100 microK. Low energy electrons at 7.3 keV coming from the K shell conversion of the 14.4 keV nuclear transition of a low activity Co57 source are detected, opening the possibility to use a He3-based detector for the detection of Weakly Interacting Massive Particles (WIMPs) which are expected to release an amount of energy higher-bounded by 5.6 keV.

  17. Ultra low-K shrinkage behavior when under electron beam in a scanning electron microscope

    SciTech Connect (OSTI)

    Lorut, F.; Imbert, G. [ST Microelectronics, 850 rue Jean Monnet, 38926 Crolles Cedex (France)] [ST Microelectronics, 850 rue Jean Monnet, 38926 Crolles Cedex (France); Roggero, A. [Centre National d'Etudes Spatiales, 18 Avenue Edouard Belin, 31400 Toulouse (France)] [Centre National d'Etudes Spatiales, 18 Avenue Edouard Belin, 31400 Toulouse (France)

    2013-08-28

    In this paper, we investigate the tendency of porous low-K dielectrics (also named Ultra Low-K, ULK) behavior to shrink when exposed to the electron beam of a scanning electron microscope. Various experimental electron beam conditions have been used for irradiating ULK thin films, and the resulting shrinkage has been measured through use of an atomic force microscope tool. We report the shrinkage to be a fast, cumulative, and dose dependent effect. Correlation of the shrinkage with incident electron beam energy loss has also been evidenced. The chemical modification of the ULK films within the interaction volume has been demonstrated, with a densification of the layer and a loss of carbon and hydrogen elements being observed.

  18. Gravity Control by means of Electromagnetic Field through Gas or Plasma at Ultra-Low Pressure

    E-Print Network [OSTI]

    Fran De Aquino

    2013-12-02

    It is shown that the gravity acceleration just above a chamber filled with gas or plasma at ultra-low pressure can be strongly reduced by applying an Extra Low-Frequency (ELF) electromagnetic field across the gas or the plasma. This Gravitational Shielding Effect is related to recent discovery of quantum correlation between gravitational mass and inertial mass. According to the theory samples hung above the gas or the plasma should exhibit a weight decrease when the frequency of the electromagnetic field is decreased or when the intensity of the electromagnetic field is increased. This Gravitational Shielding Effect is unprecedented in the literature and can not be understood in the framework of the General Relativity. From the technical point of view, there are several applications for this discovery; possibly it will change the paradigms of energy generation, transportation and telecommunications.

  19. Ultra--low noise differential AC-coupled photodetector for sensitive pulse detection applications

    E-Print Network [OSTI]

    P. J. Windpassinger; M. Kubasik; M. Koschorreck; A. Boisen; N. Kjaergaard; E. S. Polzik; J. H. Mueller

    2009-03-19

    We report on the performance of ultra low noise differential photodetectors especially designed for probing of atomic ensembles with weak light pulses. The working principle of the detectors is described together with the analysis procedures employed to extract the photon shot noise of light pulses with $\\sim1 \\mu$s duration. As opposed to frequency response peaked detectors, our approach allows for broadband quantum noise measurements. The equivalent noise charge (ENC) for two different hardware approaches is evaluated to 280 and 340 electrons per pulse, respectively which corresponds to a dark noise equivalent photon number of $n_\\mathrm{3dB}=0.8\\cdot 10^5$ and $n_\\mathrm{3dB}=1.2\\cdot 10^5$ in the two approaches. Finally, we discuss the possibility of removing classical correlations in the output signal caused by detector imperfection by using double--correlated sampling methods.

  20. Direct imaging of neural currents using ultra-low field magnetic resonance techniques

    DOE Patents [OSTI]

    Volegov, Petr L. (Los Alamos, NM); Matlashov, Andrei N. (Los Alamos, NM); Mosher, John C. (Los Alamos, NM); Espy, Michelle A. (Los Alamos, NM); Kraus, Jr., Robert H. (Los Alamos, NM)

    2009-08-11

    Using resonant interactions to directly and tomographically image neural activity in the human brain using magnetic resonance imaging (MRI) techniques at ultra-low field (ULF), the present inventors have established an approach that is sensitive to magnetic field distributions local to the spin population in cortex at the Larmor frequency of the measurement field. Because the Larmor frequency can be readily manipulated (through varying B.sub.m), one can also envision using ULF-DNI to image the frequency distribution of the local fields in cortex. Such information, taken together with simultaneous acquisition of MEG and ULF-NMR signals, enables non-invasive exploration of the correlation between local fields induced by neural activity in cortex and more `distant` measures of brain activity such as MEG and EEG.

  1. Prospects of cold dark matter searches with an ultra-low-energy germanium detector

    E-Print Network [OSTI]

    H. T. Wong

    2007-11-08

    The report describes the research program on the development of ultra-low-energy germanium detectors, with emphasis on WIMP dark matter searches. A threshold of 100 eV is achieved with a 20 g detector array, providing a unique probe to the low-mas WIMP. Present data at a surface laboratory is expected to give rise to comparable sensitivities with the existing limits at the $\\rm{5 - 10 GeV}$ WIMP-mass range. The projected parameter space to be probed with a full-scale, kilogram mass-range experiment is presented. Such a detector would also allow the studies of neutrino-nucleus coherent scattering and neutrino magnetic moments.

  2. A magnetically shielded room with ultra low residual field and gradient

    SciTech Connect (OSTI)

    Altarev, I.; Chesnevskaya, S.; Gutsmiedl, E.; Kuchler, F.; Lins, T.; Marino, M.; McAndrew, J.; Niessen, B.; Paul, S.; Petzoldt, G.; Singh, J.; Stoepler, R.; Stuiber, S.; Sturm, M.; Taubenheim, B. [Physikdepartment, Technische Universität München, D-85748 Garching (Germany); Babcock, E. [Jülich Center for Neutron Science, Lichtenbergstrasse 1, D-85748 Garching (Germany); Beck, D.; Sharma, S. [Physics Department, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Burghoff, M.; Fan, I. [Physikalisch-Technische Bundesanstalt Berlin, D-10587 Berlin (Germany); and others

    2014-07-15

    A versatile and portable magnetically shielded room with a field of (700 ± 200) pT within a central volume of 1 m × 1 m × 1 m and a field gradient less than 300 pT/m, achieved without any external field stabilization or compensation, is described. This performance represents more than a hundredfold improvement of the state of the art for a two-layer magnetic shield and provides an environment suitable for a next generation of precision experiments in fundamental physics at low energies; in particular, searches for electric dipole moments of fundamental systems and tests of Lorentz-invariance based on spin-precession experiments. Studies of the residual fields and their sources enable improved design of future ultra-low gradient environments and experimental apparatus. This has implications for developments of magnetometry beyond the femto-Tesla scale in, for example, biomagnetism, geosciences, and security applications and in general low-field nuclear magnetic resonance (NMR) measurements.

  3. Ultra Low-Cost 3.2Gb/s Optical-Rate Reed Solomon Decoder IC Design

    E-Print Network [OSTI]

    Wu, An-Yeu "Andy"

    decoder by using a novel Just-in-Time Folding Modified Euclidean Algorithm (JIT-FMEA). The JIT- FMEA VLSI called Just-in-Time Folding Modified Euclidean Algorithm (JIT-FMEA), which can construes an ultra low of JIT-FMEA architecture can overcome the critical paths of the bottleneck in a RS decoding procedure

  4. Abstract--Design of low-cost, miniature, lightweight, ultra low-power, intelligent sensors capable of

    E-Print Network [OSTI]

    Milenkovi, Aleksandar

    1 of 4 Abstract--Design of low-cost, miniature, lightweight, ultra low-power, intelligent sensors promises a cost-effective, flexible platform that allows easy customization, run-time reconfiguration for hardware acceleration will increase reuse and alleviate costs of transition to a new generation of sensors

  5. A Low Leakage 9T SRAM Cell for Ultra-Low Power Operation Department of Electrical and

    E-Print Network [OSTI]

    Ayers, Joseph

    A Low Leakage 9T SRAM Cell for Ultra-Low Power Operation Sheng Lin Department of Electrical SRAM cell, low power, nanotechnology, leakage power, static noise margin 1. INTRODUCTION Advances on designing SRAM cells for low power operation in the deep sub-micron/nano ranges [2] [3] [4]. The common

  6. Analysis of Bioproducts from Ultra-Low Cost Biomass Processing Lucy Cheadle, Chemical Engineering, Washington University in St. Louis, MO

    E-Print Network [OSTI]

    Collins, Gary S.

    countries Using the process to oven-dry wood would reduce transportation costs needed to haul the biomassAnalysis of Bioproducts from Ultra-Low Cost Biomass Processing Lucy Cheadle, Chemical Engineering of biochar product to processing variations. Possible uses for biochar: · Natural coal replacement · Soil

  7. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  8. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  9. Infrared Spectroscopy of the Ultra Low Mass Binary Oph 162225-240515

    E-Print Network [OSTI]

    Alexis Brandeker; Ray Jayawardhana; Valentin D. Ivanov; Radostin Kurtev

    2006-10-19

    Binary properties are an important diagnostic of the star and brown dwarf formation processes. While wide binaries appear to be rare in the sub-stellar regime, recent observations have revealed Ophiuchus 162225-240515 (2MASS J16222521-2405139) as a likely young ultra-low-mass binary with an apparent separation of ~240 AU. Here, we present low-resolution near-infrared spectra of the pair from NTT/SOFI (R~600) and VLT/ISAAC (R~1400), covering the 1.0-2.5um spectral region. By comparing to model atmospheres from Chabrier & Baraffe and Burrows et al., we confirm the surface temperatures to be T_A = (2350+/-150) K and T_B = (2100+/-100) K for the two components of the binary, consistent with earlier estimates from optical spectra. Using gravity sensitive K I features, we find the surface gravity to be significantly lower than field dwarfs of the same spectral type, providing the best evidence so far that these objects are indeed young. However, we find that models are not sufficiently reliable to infer accurate ages/masses from surface gravity. Instead, we derive masses of M_A = 13 (+8/-4) M_J and M_B = 10 (+5/-4) M_J for the two objects using the well-constrained temperatures and assuming an age of 1-10 Myr, consistent with the full range of ages reported for the Oph region.

  10. An ultra low noise AC beam transformer for deceleration and diagnostics of low intensity beams

    E-Print Network [OSTI]

    González, C

    1999-01-01

    The design of a broad band ultra-low noise ferrite loaded AC beam transformer is presented. It is designed for use in the CERN Antiproton Decelerator (AD), where beams of a few 107 charges must be decelerated from 3.5 GeV/c to 100 MeV/c. It is used in the RF beam-phase loop, and for intensity and bunch shape measurements during deceleration. When the beam is debunched for cooling on magnetic flat tops, the pick-up is used for measurements of intensity and momentum distribution by means of longitudinal Schottky scans. When used as Schottky pick-up, the signal to noise ratio should be better by about 40 dB than the existing stripline based longitudinal Schottky pick-up. The integrated design of pick-up and associated low-noise amplifier is presented. The achieved noise performance of a few from 1 to 3 MHz is obtained by attaching a low-noise, high-impedance silicon JFET (junction field effect transistor) amplifier to a high-Q resonant ferrite loaded cavity, and then eliminating the resonant response by low-nois...

  11. ATF2 ULTRA-LOW IP BETAS PROPOSAL R. Tomas, H. Braun, J.P. Delahaye, E. Marn, D. Schulte, F. Zimmermann, CERN

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ATF2 ULTRA-LOW IP BETAS PROPOSAL R. Tom´as, H. Braun, J.P. Delahaye, E. Mar´n, D. Schulte, F at these ultra-low IP betas. INTRODUCTION ATF2 is a test facility with the aim of testing the FFS design that has Design 0.1 1.0 19000 ATF2 ultra-low Proposed 0.025 1.0 76000 CLIC 3TeV Design 0.09 3.5 63000 ILC Design 0

  12. Effect of silicon on ultra-low temperature toughness of Nb–Ti microalloyed cryogenic pressure vessel steels

    SciTech Connect (OSTI)

    Qiu, J.A. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Wu, K.M., E-mail: wukaiming2000@yahoo.com [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Li, J.H. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Research and Development Center of WISCO, Wuhan 430080 (China); Hodgson, P.D. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Institute for Frontier Materials, Deakin University, Geelong, Victoria 3220 (Australia); Hou, T.P. [Hubei Collaborative Innovation Center for Advanced Steels, International Research Institute for Steel Technology, Wuhan University of Science and Technology, Wuhan 430081 (China); Ding, Q.F. [Research and Development Center of WISCO, Wuhan 430080 (China)

    2013-09-15

    The effect of Si on the ultra-low temperature toughness of Nb–Ti microalloyed cryogenic pressure vessel steels was investigated by electron back-scattered diffraction and transmission electron microscope with energy dispersive spectroscopy. Equiaxed ferrite and bainite were obtained in the tempered steels with small Si additions. Nanosized Nb–Ti carbides (< 10 nm) were formed in the steel containing 0.05% Si, whereas much coarser carbides (> 30 nm) were found in the steel containing 0.47% Si. The ultra-low temperature toughness of the Nb–Ti microalloyed cryogenic pressure vessel steel was remarkably enhanced by the reduction in the Si content, which was attributed to the pre-existing iron carbide formation before the precipitation of nanosized Nb–Ti carbides during tempering. - Highlights: • Nanosized Nb-Ti carbides formed in the tempered steel with smaller Si addition. • Coarser Nb-Ti carbides formed in the tempered steel with more Si addition. • Pre-existing cememtites provide nucleation sites for Nb-Ti carbide precipitation. • Ultra-low temperature toughness was remarkably enhanced by Si content reduction.

  13. The Design of an Ultra-Low Background Thermosyphon for the Majorana Demonstrator

    SciTech Connect (OSTI)

    Aguayo Navarrete, Estanislao; Busch, Matthew; Daniels, Randy; Fast, James E.; Green, Matthew P.; Reid, Douglas J.

    2013-05-01

    The MAJORANA DEMONSTRATOR (MJD) is an ultra-low background neutrinoless double-beta decay (0???) experiment that will deploy up to 40 kg of high purity germanium detectors (HPGe). The goal of this experiment is to demonstrate the feasibility of building a detector array with less than 1 event/ton-year in a 4 keV region of interest around the 0??? signal. HPGe diodes, when used as ionizing radiation detectors, need to be maintained at a temperature close to that of liquid nitrogen (77 K). This work describes the R&D results of a cryogenic system capable of meeting the requirements of low background and the cooling capacity required to successfully operate such a detector system. The MJD germanium detector modules will operate at liquid nitrogen temperature to provide adequate cooling for a full range of HPGe impurity concentrations. This paper shows the experimental results obtained using a two-phase horizontal thermosyphon using liquid nitrogen as the MJD’s cooling system. The cold test shows that the proposed thermosyphon has sufficient cooling power to handle the heat load of an MJD module. Results for the temperature gradient across the thermosyphon, cooling capacity, and design considerations demonstrate that the thermosyphon can effectively remove the calculated heat load of each module of the experiment. The thermosyphon will be bolted to a cold plate from which detector strings will hang. The thermal conductivity of a mockup of the MJD bolted thermal joint is experimentally determined to be below 0.1 K/W.

  14. Estimation of Cosmic Induced Contamination in Ultra-low Background Detector Materials

    SciTech Connect (OSTI)

    Aguayo Navarrete, Estanislao; Kouzes, Richard T.; Orrell, John L.; Berguson, Timothy J.; Greene, Austen T.

    2012-08-01

    Executive Summary This document presents the result of investigating a way to reliably determine cosmic induced backgrounds for ultra-low background materials. In particular, it focuses on those radioisotopes produced by the interactions with cosmic ray particles in the detector materials that act as a background for experiments looking for neutrinoless double beta decay. This investigation is motivated by the desire to determine background contributions from cosmic ray activation of the electroformed copper that is being used in the construction of the MAJORANA DEMONSTRATOR. The most important radioisotope produced in copper that contributes to the background budget is 60Co, which has the potential to deposit energy in the region of interest of this experiment. Cobalt-60 is produced via cosmic ray neutron collisions in the copper. This investigation aims to provide a method for determining whether or not the copper has been exposed to cosmic radiation beyond the threshold which the Majorana Project has established as the maximum exposure. This threshold is set by the Project as the expected contribution of this source of background to the overall background budget. One way to estimate cosmic ray neutron exposure of materials on the surface of the Earth is to relate it to the cosmic ray muon exposure. Muons are minimum-ionizing particles and the available technologies to detect muons are easier to implement than those to detect neutrons. We present the results of using a portable, ruggedized muon detector, the µ-Witness made by our research group, for determination of muon exposure of materials for the MAJORANA DEMONSTRATOR. From the muon flux measurement, this report presents a method to estimate equivalent sea-level exposure, and then infer the neutron exposure of the tracked material and thus the cosmogenic activation of the copper. This report combines measurements of the muon flux taken by the µ-Witness detector with Geant4 simulations in order to assure our understanding of the µ-Witness prototype. As a proof of concept, we present the results of using this detector with electroformed copper during its transport from Pacific Northwest National Laboratory, where the copper is grown, to the underground lab in Lead, South Dakota, where the experiment is being deployed. The development of a code to be used with the Majorana parts tracking database, designed to aid in estimating the cosmogenic activation, is also presented.

  15. Membership and Behavior of Ultra-Low-Diversity Pathogen Communities Present in the Gut of Humans during Prolonged Critical Illness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zaborin, A.; Smith, D.; Garfield, K.; Quensen, J.; Shakhsheer, B.; Kade, M.; Tirrell, M.; Tiedje, J.; Gilbert, J. A.; Zaborina, O.; et al

    2014-09-23

    We analyzed the 16S rRNA amplicon composition in fecal samples of selected patients during their prolonged stay in an intensive care unit (ICU) and observed the emergence of ultra-low-diversity communities (1 to 4 bacterial taxa) in 30% of the patients. Bacteria associated with the genera Enterococcus and Staphylococcus and the family Enterobacteriaceae comprised the majority of these communities. The composition of cultured species from stool samples correlated to the 16S rRNA analysis and additionally revealed the emergence of Candida albicans and Candida glabrata in ~75% of cases. Four of 14 ICU patients harbored 2-member pathogen communities consisting of one Candidamore »taxon and one bacterial taxon. Bacterial members displayed a high degree of resistance to multiple antibiotics. The virulence potential of the 2-member communities was examined in C. elegans during nutrient deprivation and exposure to opioids in order to mimic local conditions in the gut during critical illness. Under conditions of nutrient deprivation, the bacterial members attenuated the virulence of fungal members, leading to a “commensal lifestyle.” However, exposure to opioids led to a breakdown in this commensalism in 2 of the ultra-low-diversity communities. Application of a novel antivirulence agent (phosphate-polyethylene glycol [Pi-PEG]) that creates local phosphate abundance prevented opioid-induced virulence among these pathogen communities, thus rescuing the commensal lifestyle. To conclude, the gut microflora in critically ill patients can consist of ultra-low-diversity communities of multidrug-resistant pathogenic microbes. Local environmental conditions in gut may direct pathogen communities to adapt to either a commensal style or a pathogenic style.« less

  16. Membership and Behavior of Ultra-Low-Diversity Pathogen Communities Present in the Gut of Humans during Prolonged Critical Illness

    SciTech Connect (OSTI)

    Zaborin, A.; Smith, D.; Garfield, K.; Quensen, J.; Shakhsheer, B.; Kade, M.; Tirrell, M.; Tiedje, J.; Gilbert, J. A.; Zaborina, O.; Alverdy, J. C.

    2014-09-23

    We analyzed the 16S rRNA amplicon composition in fecal samples of selected patients during their prolonged stay in an intensive care unit (ICU) and observed the emergence of ultra-low-diversity communities (1 to 4 bacterial taxa) in 30% of the patients. Bacteria associated with the genera Enterococcus and Staphylococcus and the family Enterobacteriaceae comprised the majority of these communities. The composition of cultured species from stool samples correlated to the 16S rRNA analysis and additionally revealed the emergence of Candida albicans and Candida glabrata in ~75% of cases. Four of 14 ICU patients harbored 2-member pathogen communities consisting of one Candida taxon and one bacterial taxon. Bacterial members displayed a high degree of resistance to multiple antibiotics. The virulence potential of the 2-member communities was examined in C. elegans during nutrient deprivation and exposure to opioids in order to mimic local conditions in the gut during critical illness. Under conditions of nutrient deprivation, the bacterial members attenuated the virulence of fungal members, leading to a “commensal lifestyle.” However, exposure to opioids led to a breakdown in this commensalism in 2 of the ultra-low-diversity communities. Application of a novel antivirulence agent (phosphate-polyethylene glycol [Pi-PEG]) that creates local phosphate abundance prevented opioid-induced virulence among these pathogen communities, thus rescuing the commensal lifestyle. To conclude, the gut microflora in critically ill patients can consist of ultra-low-diversity communities of multidrug-resistant pathogenic microbes. Local environmental conditions in gut may direct pathogen communities to adapt to either a commensal style or a pathogenic style.

  17. Application methods and evaluations of ultra-low-volume sprays for controlling the bollworm, tobacco budworm and boll weevil 

    E-Print Network [OSTI]

    Nemec, Stanley Joseph

    1967-01-01

    Xgof e ~ ~ ~ ~ o e ~ F e o ~ The ultra-low volume methos of epplyieg insecticises proviaes egricxxlture sag puhiid health with 8 technique for the eppR. Ication oi' insecticides that presentlp appears to be as efficient 886 more edeoomicel then e... wes oh- teixxeg with technical ~thion upping bp aircraft at rates es low as 6 fluM ounces per cere. The ultra-los-volume msthog of s~ insedticQles has since ethueietel sxxch interest for possible uee in control of insects attaching msgr cxops...

  18. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2 Distillate + No. 4 Fuel Oil (published on Table 46). Note: In January 2007, ultra low-sulfur diesel fuel was added. Note: Totals may not equal the sum of the components due to...

  19. X:\\L6046\\Data_Publication\\Pma\\current\\ventura\\pma.vp

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2 Distillate + No. 4 Fuel Oil (published on Table 46). Note: In January 2007, ultra low-sulfur diesel fuel was added. Note: Totals may not equal the sum of the components due to...

  20. Hydrocracking distillate feedstocks

    SciTech Connect (OSTI)

    Kurganov, V.M.; Gorshtein, A.B.; Shkol'nik, B.L.; Shtein, V.I.

    1987-05-01

    The main shortcoming of single-stage hydrocracking is the very high level of feedstock cracking. The authors discuss the development of multistage technology in which each stage can operate under optimal conditions at a moderate conversion level, better flexibility in process control, and better process indexes. The main feature of the multistage technology is the preliminary hydrogenation of the original feed. The composition of the original feed and the middle distillate cuts obtaining in two-stage hydrocracking of a vacuum distillate from West Siberian crude, using cobalt-molybdenum oxide catalyst in the first stage and a zeolitic catalyst in the second stage is presented. Data is provided on the influence of pressure on the hydrocracking indexes.

  1. The Design, Construction, and Initial Characterization of an Ultra-Low-Background Gas-Proportional Counting System

    SciTech Connect (OSTI)

    Seifert, Allen; Aalseth, Craig E.; Day, Anthony R.; Fuller, Erin S.; Hoppe, Eric W.; Keillor, Martin E.; Mace, Emily K.; Overman, Cory T.; Warren, Glen A.

    2013-05-01

    ABSTRACT Over the past several years, the Pacific Northwest National Laboratory (PNNL) has developed an ultra-low background proportional counter (ULBPC) technology. The resulting detector is the product of an effort to produce a low-background, physically robust gas proportional counter for applications like radon emanation measurements, groundwater tritium, and 37Ar. In order to fully take advantage of the inherent low-background properties designed into the ULBPC, a comparably low-background dedicated counting system is required. An ultra-low-background counting system (ULBCS) was recently built in the new shallow underground laboratory at PNNL. With a design depth of 30 meters water-equivalent, the shallow underground laboratory provides approximately 100x fewer fast neutrons and 6x fewer muons than a surface location. The ULBCS itself provides additional shielding in the form of active anti-cosmic veto (via 2-in. thick plastic scintillator paddles) and passive borated poly (1 in.), lead (6 in.), and copper (~3 in.) shielding. This work will provide details on PNNL’s new shallow underground laboratory, examine the motivation for the design of the counting system, and provide results from the characterization of the ULBCS, including initial detector background.

  2. Digital Pulse-Shape Discrimination Applied to an Ultra-Low-Background Gas-Proportional Counting System: First Results

    SciTech Connect (OSTI)

    Aalseth, Craig E.; Day, Anthony R.; Fuller, Erin S.; Hoppe, Eric W.; Keillor, Martin E.; Mace, Emily K.; Myers, A. W.; Overman, Cory T.; Panisko, Mark E.; Seifert, Allen; Warren, Glen A.; Williams, Richard M.

    2013-05-01

    Abstract A new ultra-low-background proportional counter (ULBPC) design was recently developed at Pacific Northwest National Laboratory (PNNL). This design, along with an ultra-low-background counting system (ULBCS) which provides passive and active shielding with radon exclusion, has been developed to complement a new shallow underground laboratory (~30 meters water-equivalent) constructed at PNNL. After these steps to mitigate dominant backgrounds (cosmic rays, external gamma-rays, radioactivity in materials), remaining background events do not exclusively arise from ionization of the proportional counter gas. Digital pulse-shape discrimination (PSD) is thus employed to further improve measurement sensitivity. In this work, a template shape is generated for each individual sample measurement of interest, a "self-calibrating" template. Differences in event topology can also cause differences in pulse shape. In this work, the temporal region analyzed for each event is refined to maximize background discrimination while avoiding unwanted sensitivity to event topology. This digital PSD method is applied to sample and background data, and initial measurement results from a biofuel methane sample are presented in the context of low-background measurements currently being developed.

  3. Intergranular corrosion mechanism of ultra-low carbon type 304 stainless steel in a nuclear reprocessing plant

    SciTech Connect (OSTI)

    Ueno, Fumiyoshi; Kato, Chiaki; Motooka, Takafumi; Yamamoto, Masahiro [Japan Atomic Energy Agency Shirakata Shirane 2-4, Tokai-mura, Ibaraki pref., 319-1195 (Japan); Ichikawa, Shiro [Kobelco Research Institute, Inc. 1-5-5, Takatsukadai, Nishi-ku, Kobe city, 651-2271 (Japan)

    2007-07-01

    Corrosion of the components which contains nitric acid solution such as vessels, tanks and pipes is an important problem for a PUREX method nuclear fuel reprocessing plant. In Tokai Reprocessing Plant which was startup in 1977 as the first Japanese plant, several events caused by corrosion have been experienced for about 30 years operation. The second plant in Japan, Rokkasho Reprocessing Plant, will start commercial operation from 2007. For stable operation of Rokkasho plant, maintenance management of components will be important. Therefore, it is necessary to clarify the corrosion mechanism and to reflect the results of the research for a maintenance program of the plant adequately. If high burnup fuel will increase in future nuclear power plants, it will become necessary to reprocess the spent fuel which includes more fission products and transuranium from now. Then the study of corrosion mechanism and life evaluation will become more important problem. Authors were aimed for development of life evaluation method of components and clarification of intergranular corrosion mechanism of ultra-low carbon type 304 stainless steel in a nuclear fuel reprocessing plant. In this report, the results of long-term corrosion test in boiling nitric acid by using ultra-low carbon stainless steel made mock-up test apparatus was described. And then, the relation between corrosion rate change and intergranular corrosion behavior were discussed. (authors)

  4. 5/28/10 3:40 PMNSF Funds Ultra-Low Energy Circuits | The Fu Foundation School of Engineering & Applied Science -Columbia University Page 1 of 1http://www.engineering.columbia.edu/nsf-funds-microelectronic-systems-research

    E-Print Network [OSTI]

    Yang, Junfeng

    5/28/10 3:40 PMNSF Funds Ultra-Low Energy Circuits | The Fu Foundation School of Engineering://www.engineering.columbia.edu/nsf-funds-microelectronic-systems-research Columbia University Home Directory | Help NSF Funds Ultra-Low Energy Circuits (http://www.compeng.columbia.edu/) . The grant will fund their proposal to perform research in ultra low-power microelectronic systems, which

  5. * email: nidhi@ece.ucsb.edu phone: +1-805-893-3812 ext 202 Ultra-low contact resistance for Self-aligned HEMT structures on N-polar GaN by MBE

    E-Print Network [OSTI]

    Rodwell, Mark J. W.

    * email: nidhi@ece.ucsb.edu phone: +1-805-893-3812 ext 202 Ultra-low contact resistance for SelfN) are regrown to achieve ultra-low Ohmic contact resistance. All MBE regrowths were done on MOCVD GaN templates of InN. To summarize, ultra-low Ohmic contact resistance of 60 -µm was obtained for a self-aligned devi

  6. Lossy compression and real-time geovisualization for ultra-low bandwidth telemetry from untethered underwater vehicles

    E-Print Network [OSTI]

    Murphy, Christopher Alden

    2008-01-01

    Oceanographic applications of robotics are as varied as the undersea environment itself. As underwater robotics moves toward the study of dynamic processes with multiple vehicles, there is an increasing need to distill ...

  7. Stocks of Distillate Fuel Oil 15 ppm Sulfur and Under

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG Oil10:Price27,84320,354

  8. Stocks of Distillate Fuel Oil Greater Than 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG

  9. Data acquisition, distillation,Data acquisition, distillation, and storageand storage

    E-Print Network [OSTI]

    ' to executeDetermines `best time' to execute a program based on weather,a program based on weather, arrayData acquisition, distillation,Data acquisition, distillation, and storageand storage · FASR will produce ~10 Tbyte/day at maturity · "Raw" data products include visibility data, M&C data, calibration

  10. First search for double beta decay of platinum by ultra-low background HP Ge gamma spectrometry

    E-Print Network [OSTI]

    P. Belli; R. Bernabei; F. Cappella; R. Cerulli; F. A. Danevich; A. Di Marco; A. Incicchitti; M. Laubenstein; S. S. Nagorny; S. Nisi; O. G. Polischuk; V. I. Tretyak

    2011-04-29

    A search for double beta processes in 190Pt and 198Pt was realized with the help of ultra-low background HP Ge 468 cm^3 gamma spectrometer in the underground Gran Sasso National Laboratories of the INFN (Italy). After 1815 h of data taking with 42.5 g platinum sample, T_{1/2} limits on 2beta processes in 190Pt (\\epsilon\\beta^+ and 2\\epsilon) have been established on the level of 10^{14}-10^{16} yr, 3 to 4 orders of magnitude higher than those known previously. In particular, a possible resonant double electron capture in 190Pt was restricted on the level of 2.9 \\times 10^{16} yr at 90% C.L. In addition, T_{1/2} limit on 2 beta^- decay of 198Pt (2\

  11. Laminar round jet diffusion flame buoyant instabilities: Study on the disappearance of varicose structures at ultra-low Froude number

    SciTech Connect (OSTI)

    Boulanger, Joan [Gas Turbine Laboratory, Institute for Aerospace Research, Ottawa, Ontario (Canada)

    2010-04-15

    At very low Froude number, buoyancy instabilities of round laminar jet diffusion flames disappear (except for small tip oscillations referred to as flickering) and those flames look stable and smooth. This study examines the contributions of the different phenomena in the flow dynamics that may explain this effect. It is observed that, at ultra-low Froude/Reynolds numbers, the material influenced by buoyancy is the plume of the flame and not the flame itself (reaction zone) that is short. Therefore, the vorticity creation zone does not profit from the reaction neighbourhood promoting a sharp gradient of density. Expansion and stretch are also important as they push vorticity creation terms more inside the flame and closer to the burner rim compared to moderate Froude flames. In these latter, the vorticity is continuously created around the flame reaction zone, along its developed height and closer to the vertical direction (in average). (author)

  12. Plasticity and ultra-low stress induced twin boundary migration in nanotwinned Cu by in situ nanoindentation studies

    SciTech Connect (OSTI)

    Liu, Y.; Chen, Y. [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Jian, J. [Department of Electrical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Wang, H. [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Electrical Engineering, Texas A and M University, College Station, Texas 77843 (United States); Zhang, X., E-mail: zhangx@tamu.edu [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Mechanical Engineering, Texas A and M University, College Station, Texas 77843 (United States)

    2014-06-09

    Nanotwinned metals have rare combinations of mechanical strength and ductility. Previous studies have shown that detwinning occurs in plastically deformed nanotwinned metals. Although molecular dynamics simulations have predicted that fine nanotwins can migrate at low stress, there is little in situ evidence to validate such predictions. Also it is unclear if detwinning occurs prior to or succeeding plastic yielding. Here, by using in situ nanoindentation in a transmission electron microscope, we show that a non-elastic detwinning process in nanotwinned Cu occurred at ultra-low indentation stress (0.1?GPa), well before the stress necessary for plastic yielding. Furthermore, the in situ nanoindentation technique allows us to differentiate dislocation-nucleation dominated microscopic yielding preceding macroscopic yielding manifested by dislocation-transmission through twin boundaries. This study thus provides further insights for understanding plasticity in nanotwinned metals at microscopic levels.

  13. A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis

    E-Print Network [OSTI]

    Farrell, Alexander E.; Sperling, Dan

    2007-01-01

    produced in CA Diesel Ultra-low-sulfur diesel produced in CAbelow) California ultra low sulfur diesel, pathway D2

  14. Investigation of Solid Particle Number Measurement of Engine Emissions

    E-Print Network [OSTI]

    Zheng, Zhongqing

    2012-01-01

    of the testing. CARB Ultra Low Sulfur Diesel (ULSD) fuel (SResources Board (CARB) ultra low sulfur diesel (ULSD) fuel (

  15. A Low-Carbon Fuel Standard for California Part 1: Technical Analysis

    E-Print Network [OSTI]

    2007-01-01

    produced in CA Diesel Ultra-low-sulfur diesel produced in CAbelow) California ultra low sulfur diesel, pathway D2

  16. CRYOGENIC 1.5-4.5 GHz ULTRA LOW NOISE AMPLIFIER Niklas Wadefalk*, Anders Mellberg, Iltcho Angelov, Emmanuil Choumas**, Erik Kollberg,

    E-Print Network [OSTI]

    in the InGaAs-layer. The HEMT technology does not suffer from freeze-out at cryogenic temperaturesCRYOGENIC 1.5-4.5 GHz ULTRA LOW NOISE AMPLIFIER Niklas Wadefalk*, Anders Mellberg, Iltcho Angelov Trading AG, Truebbach, Switzerland Abstract - This paper describes cryogenic broadband amplifier with very

  17. An Ultra Low Power System Architecture for Sensor Network Applications Mark Hempstead, Nikhil Tripathi, Patrick Mauro, Gu-Yeon Wei, David Brooks

    E-Print Network [OSTI]

    Brooks, David

    - crocontroller, a radio, and a variety of (often MEMS-based) sensors. One of the main limitationsAn Ultra Low Power System Architecture for Sensor Network Applications Mark Hempstead, Nikhil a burgeoning interest in em- bedded wireless sensor networks with applications rang- ing from habitat

  18. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated...

  19. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  20. Optimal Control of Distillation Systems 

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  1. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

    2009-11-03

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  2. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H. (LaJolla, CA)

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  3. An ultra low-noise AC beam transformer and digital signal processing system for CERN's ELENA ring

    E-Print Network [OSTI]

    Angoletta, M E; Caspers, F; Federmann, S; Molendijk, J; Pedersen, F; Sanchez-Quesada, J

    2013-01-01

    CERN’s Extra Low ENergy Antiproton (ELENA) ring is a new synchrotron that will be commissioned in 2016 to further decelerate the antiprotons coming from CERN’s Antiproton Decelerator (AD). Essential longitudinal diagnostics required for commissioning and operation include the intensity measurement for bunched and debunched beams and the measurement of p/p for debunched beams to assess the electron cooling performance. The beam phase information is also needed by the Low-Level RF (LLRF) system. The baseline system for providing the required beam parameters and signals is based upon two ultra-low-noise AC beam transformers and associated digital signal processing. The AC beam transformers cover different frequency regions and are an adaptation to the ELENA layout of those used in the AD. Two AC beam transformers will also be installed in the extraction lines to provide beam intensity measurements. The digital signal processing will be carried out with the leadingedge hardware family used for ELENA’s L...

  4. Comparison of precipitate behaviors in ultra-low carbon, titanium-stabilized interstitial free steel sheets under different annealing processes

    SciTech Connect (OSTI)

    Shi, J.; Wang, X.

    1999-12-01

    Ultra-low carbon, titanium-stabilized interstitial free (ULC Ti-IF) steel sheets are widely used in the automobile industry because of excellent deep drawability. The annealing process is critical to their final property, and there are two different annealing processes used in industrial production of interstitial free (IF) steel sheets, namely batch annealing and continuous annealing. In this study, precipitation behaviors of titanium IF steels, that is, TiN, TiS, Ti{sub 4}(CS){sub 2}, and TiC, the size and dispersion of TiN, TiS, and Ti{sub 4}(CS){sub 2} remained almost unchanged after either annealing process. Conversely, the average size of a TiC particle increased substantially after both annealing processes, while TiC after continuous annealing was larger than that after batch annealing due to the higher heating temperature of continuous annealing. Two new particles, FeTiP and (Ti, Mn)S, were also observed in the batch annealing process but not in continuous annealing. The structure of FeTiP and (Ti, Mn)S were studied, and furthermore the evolution of FeTiP precipitation was found to be closely related to recrystallization in batch annealing. Finally, the interrelation among processing parameters, precipitation behaviors, and final property was studied.

  5. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

  6. Integrated production/use of ultra low-ash coal, premium liquids and clean char. [Quarterly] report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Kruse, C.W. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-08-01

    The first step in the integrated, mufti-product approach for utilizing Illinois coal is the production of ultra low-ash coal. Subsequent steps convert low-ash coal to high-value, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  7. Integrated production/use of ultra low-ash coal, premium liquids and clean char. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Kruse, C.W.

    1991-12-31

    This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  8. An Ultra-Low Noise Telecom Wavelength Free Running Single Photon Detector Using Negative Feedback Avalanche Diode

    E-Print Network [OSTI]

    Zhizhong Yan; Deny R. Hamel; Aimee K. Heinrichs; Xudong Jiang; Mark A. Itzler; Thomas Jennewein

    2012-05-31

    It is challenging to implement genuine free running single photon detectors for the 1550 nm wavelength range with simultaneously high detection efficiency (DE), low dark noise, and good time resolution. We report a novel read out system for the signals from a negative feedback avalanche diode (NFAD) which allows useful operation of these devices at a temperature of 193 K and results in very low dark counts (~100 CPS), good time jitter (~30 ps), and good DE (~10%). We characterized two NFADs with a time correlation method using photons generated from weak coherent pulses (WCP) and photon pairs produced by spontaneous parametric down conversion (SPDC). The inferred detector efficiencies for both types of photon sources agree with each other. The best noise equivalent power of the device is estimated to be 8.1 x 10^(-18) W Hz^(-1/2), more than 10 times better than typical InP/InGaAs SPADs show in free running mode. The afterpulsing probability was found to be less than 0.1% per ns at the optimized operating point. In addition, we studied the performance of an entanglement-based quantum key distribution (QKD) using these detectors and develop a model for the quantum bit error rate (QBER) that incorporates the afterpulsing coefficients. We verified experimentally that using these NFADs it is feasible to implement QKD over 400 km of telecom fibre. Our NFAD photon detector system is very simple, and is well suited for single-photon applications where ultra-low noise and free-running operation is required, and some afterpulsing can be tolerated.

  9. AN ULTRA-LOW-MASS AND SMALL-RADIUS COMPACT OBJECT IN 4U 1746-37?

    SciTech Connect (OSTI)

    Li, Zhaosheng; Qu, Zhijie; Guo, Yanjun; Xu, Renxin; Chen, Li; Qu, Jinlu

    2015-01-01

    Photospheric radius expansion (PRE) bursts have already been used to constrain the masses and radii of neutron stars. RXTE observed three PRE bursts in 4U 1746-37, all with low touchdown fluxes. We discuss here the possibility of a low-mass neutron star in 4U 1746-37 because the Eddington luminosity depends on stellar mass. With typical values of hydrogen mass fraction and color correction factor, a Monte Carlo simulation was applied to constrain the mass and radius of a neutron star in 4U 1746-37. 4U 1746-37 has a high inclination angle. Two geometric effects, the reflection of the far-side accretion disk and the obscuration of the near-side accretion disk, have also been included in the mass and radius constraints of 4U 1746-37. If the reflection of the far-side accretion disk is accounted for, a low-mass compact object (mass of 0.41 ± 0.14 M {sub ?} and radius of 8.73 ± 1.54 km at 68% confidence) exists in 4U 1746-37. If another effect operated, 4U 1746-37 may contain an ultra-low-mass and small-radius object (M = 0.21 ± 0.06 M {sub ?}, R = 6.26 ± 0.99 km at 68% confidence). Combining all possibilities, the mass of 4U 1746-37 is 0.41{sub ?0.30}{sup +0.70} M{sub ?} at 99.7% confidence. For such low-mass neutron stars, it could be reproduced by a self-bound compact star, i.e., a quark star or quark-cluster star.

  10. Hardware assembly and prototype testing for the development of a dedicated liquefied propane gas ultra low emission vehicle

    SciTech Connect (OSTI)

    1995-07-01

    On February 3, 1994, IMPCO Technologies, Inc. started the development of a dedicated LPG Ultra Low Emissions Vehicle (ULEV) under contract to the Midwest Research Institute National Renewable Energy Laboratory Division (NREL). The objective was to develop a dedicated propane vehicle that would meet or exceed the California ULEV emissions standards. The project is broken into four phases to be performed over a two year period. The four phases of the project include: (Phase 1) system design, (Phase 2) prototype hardware assembly and testing, (Phase 3) full-scale systems testing and integration, (Phase 4) vehicle demonstration. This report describes the approach taken for the development of the vehicle and the work performed through the completion of Phase II dynamometer test results. Work was started on Phase 2 (Hardware Assembly and Prototype Testing) in May 1994 prior to completion of Phase 1 to ensure that long lead items would be available in a timely fashion for the Phase 2 work. In addition, the construction and testing of the interim electronic control module (ECM), which was used to test components, was begun prior to the formal start of Phase 2. This was done so that the shortened revised schedule for the project (24 months) could be met. In this report, a brief summary of the activities of each combined Phase 1 and 2 tasks will be presented, as well as project management activities. A technical review of the system is also given, along with test results and analysis. During the course of Phase 2 activities, IMPCO staff also had the opportunity to conduct cold start performance tests of the injectors. The additional test data was most positive and will be briefly summarized in this report.

  11. Ultra low noise YBa{sub 2}Cu{sub 3}O{sub 7??} nano superconducting quantum interference devices implementing nanowires

    SciTech Connect (OSTI)

    Arpaia, R.; Arzeo, M.; Nawaz, S.; Charpentier, S.; Lombardi, F.; Bauch, T.

    2014-02-17

    We present results on ultra low noise YBa{sub 2}Cu{sub 3}O{sub 7–?} (YBCO) nano Superconducting QUantum Interference Devices (nanoSQUIDs). To realize such devices, we implemented high quality YBCO nanowires, working as weak links between two electrodes. We observe critical current modulation as a function of an externally applied magnetic field in the full temperature range below the transition temperature T{sub C}. The white flux noise below 1??{sub 0}/?(Hz) at T=8?K makes our nanoSQUIDs very attractive for the detection of small spin systems.

  12. 217 km long distance photon-counting optical time-domain reflectometry based on ultra-low noise up-conversion single photon detector

    E-Print Network [OSTI]

    Guo-Liang Shentu; Qi-Chao Sun; Xiao Jiang; Xiao-Dong Wang; Jason S. Pelc; M. M. Fejer; Qiang Zhang; Jian-Wei Pan

    2013-08-05

    We demonstrate a photon-counting optical time-domain reflectometry with 42.19 dB dynamic range using an ultra-low noise up-conversion single photon detector. By employing the long wave pump technique and a volume Bragg grating, we reduce the noise of our up-conversion single photon detector, and achieve a noise equivalent power of -139.7 dBm/sqrt(Hz). We perform the OTDR experiments using a fiber of length 216.95 km, and show that our system can identify defects along the entire fiber length with a distance resolution better than 10 cm in a measurement time of 13 minutes.

  13. Assisted distillation of quantum coherence

    E-Print Network [OSTI]

    Chitambar, E; Rana, S; Bera, M N; Adesso, G; Lewenstein, M

    2015-01-01

    We introduce and study the task of assisted coherence distillation. This task arises naturally in bipartite systems where both parties work together to generate the maximal possible coherence on one of the subsystems. Only incoherent operations are allowed on the target system while general local quantum operations are permitted on the other, an operational paradigm that we call local quantum-incoherent operations and classical communication (LQICC). We show that the asymptotic rate of assisted coherence distillation for pure states is equal to the coherence of assistance, a direct analog of the entanglement of assistance, whose properties we characterize. Our findings imply a novel interpretation of the von Neumann entropy: it quantifies the maximum amount of extra quantum coherence a system can gain when receiving assistance from a collaborative party. Our results are generalized to coherence localization in a multipartite setting and possible applications are discussed.

  14. MATERIALS DEGRADATION ANALYSIS AND DEVELOPMENT TO ENABLE ULTRA LOW COST, WEB-PROCESSED WHITE P-OLED FOR SSL

    SciTech Connect (OSTI)

    DR. DEVIN MACKENZIE

    2011-12-13

    Progress over Phase II of DE-FG02-07ER86293 'Materials Degradation Analysis and Development to Enable Ultra Low Cost, Web-Processed White P-OLED for SSL' was initially rapid in terms of device performance improvements. We exceeded our device luminance lifetime goals for printed flexible white OLEDs as laid out in our project proposal. Our Phase II performance target was to demonstrate >1500 hours luminance lifetime at 100 Cd/m2 from a printed flexible device. We now have R&D devices well in excess of 8000 hrs lifetime at 100 Cd/m2, tested in air. We also were able to produce devices which met the voltage target of >1500 hours below 15V operation. After completing the initial performance milestones, we went on to focus on color-related degradation issues which were cited as important to commercialization of the technology by our manufacturing partners. We also put additional focus on cathode work as the active material development that occurred over the STTR time period required an adaptation of the cathode from the original cathode formulations which were developed based on previous generation active layer materials. We were able to improve compatibility of the cathode with some of the newer generation active layer materials and improve device yield and voltage behavior. An additional objective of the initial Phase II was to further develop the underlying manufacturing technology and real-life product specifications. This is a key requirement that must be met to ensure eventual commercialization of this DOE-funded technology. The link between commercial investment for full commercialization and R&D efforts in OLED solid State Lighting is often a large one. Add-Vision's lower cost, printed OLED manufacturing approach is an attraction, but close engagement with manufacturing partners and addressing customer specifications is a very important link. Manufacturing technology encompasses development of moisture reduction encapsulation technology, improved cost performance, and reductions in operating voltage through thinner and higher uniformity active device layers. We have now installed a pilot encapsulation system at AVI for controlled, high throughput lamination encapsulation of flexible OLEDs in a novel process. Along with this, we have developed, with our materials supply partners, adhesives, barrier films and other encapsulation materials and we are showing total air product lifetimes in the 2-4 years range from a process consistent with our throughput goals of {approx}1M device per month ({approx}30,000 sq. ft. of processed OLEDs). Within the last year of the project, we have been working to introduce the manufacturing improvements made in our LEP deposition and annealing process to our commercial partners. Based on the success of this, a pilot scale-up program was begun. During this process, Add-Vision was acquired by a strategic partner, in no small part, because of the promise of future success of the technology as evidenced by our commercial partners pilot scale-up plans. Overall, the performance, manufacturing and product work in this project has been successful. Additional analysis and device work at LBL has also shown a unique adhesion change with device bias stressing which may result from active layer polymer cross-linking during bias stressing of device. It was shown that even small bias stresses, as a fraction of a full device lifetime stress period, result in measurable chemical change in the device. Further work needs to be conducted to fully understand the chemical nature of this interaction. Elucidation of this effect would enable doped OLED formulation to be engineered to suppress this effect and further extend lifetimes and reduce voltage climb.

  15. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01

    of Low Sulfur, Ultra Low Sulfur and Biodiesel Blends in a DIengine fueled with ultra low sulfur diesel, RME-dieselengine fueled with ultra-low sulfur diesel fuel blended with

  16. The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology

    E-Print Network [OSTI]

    He, Wei

    2011-01-01

    of low sulfur, ultra low sulfur and biodiesel blends in a DIbiofuels produced have ultra-low sulfur levels thanks to thefuels; 5. It contains ultra-low sulfur level and could meet

  17. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  18. A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials

    E-Print Network [OSTI]

    Delucchi, Mark

    2003-01-01

    n.e. RFG n.e. dist. n.e. ULSD n.e. fuel oil n.e. LPG n.e.dist. = distillate fuel; ULSD = ultra-low-sulfur distillateultra-low-sulfur diesel (ULSD) with 5 ppm S, then weights

  19. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated as a manufacturing method for microchannel...

  20. Energy Recovery in Industrial Distillation Processes 

    E-Print Network [OSTI]

    Paul, D. B.

    1983-01-01

    Distillation processes are energy intensive separation processes which present attractive opportunities for energy conservation. Through the use of multistage vapor recompression, heat which is normally unavailable can be ...

  1. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  2. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  3. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  4. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Hu, Zhicheng (Somerville, MA)

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  5. Type-I superconductor pick-up coil in superconducting quantum interference device-based ultra-low field nuclear magnetic resonance

    SciTech Connect (OSTI)

    Hwang, Seong-min, E-mail: smhwang@kriss.re.kr; Kim, Kiwoong; Kyu Yu, Kwon; Lee, Seong-Joo; Hyun Shim, Jeong [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Körber, Rainer [Physikalisch-Technische Bundesanstalt (PTB), Abbestraße 2-12, 10587 Berlin (Germany); Magnicon GmbH, Division Berlin, Abbestraße 2-12, D-10587 Berlin (Germany); Burghoff, Martin [Physikalisch-Technische Bundesanstalt (PTB), Abbestraße 2-12, 10587 Berlin (Germany)

    2014-02-10

    In ultra-low field nuclear magnetic resonance (ULF-NMR) with strong prepolarization field (B{sub p}), type-II superconducting pick-up coils may be vulnerable to flux pinning from the strong B{sub p}. Pick-up coils made of NbTi, Nb, and Pb were evaluated in terms of acquired NMR signal quality. The type-II pick-up coils showed degraded signals above 61?mT maximum exposure, while the Pb pick-up coil exhibited no such degradation. Furthermore, a negative counter pulse following a strong B{sub p} was shown to follow magnetic hysteresis loop to unpin the trapped flux in the type-II pick-up coil and restore the NMR signal.

  6. Search for 2? decays of 96Ru and 104Ru by ultra-low background HPGe gamma spectrometry at LNGS: final results

    E-Print Network [OSTI]

    P. Belli; R. Bernabei; F. Cappella; R. Cerulli; F. A. Danevich; S. d'Angelo; A. Incicchitti; G. P. Kovtun; N. G. Kovtun; M. Laubenstein; D. V. Poda; O. G. Polischuk; A. P. Shcherban; D. A. Solopikhin; J. Suhonen; V. I. Tretyak

    2013-02-28

    An experiment to search for double beta decay processes in 96Ru and 104Ru, which are accompanied by gamma rays, has been realized in the underground Gran Sasso National Laboratories of the I.N.F.N. (Italy). Ruthenium samples with masses of about (0.5-0.7) kg were measured with the help of ultra-low background high purity Ge gamma ray spectrometry. After 2162 h of data taking the samples were deeply purified to reduce the internal contamination of 40K. The last part of the data has been accumulated over 5479 h. New improved half life limits on 2\\beta+/\\epsilon \\beta+/2\\epsilon\\ processes in 96Ru have been established on the level of 10^{20} yr, in particular for decays to the ground state of 96Mo: T1/2(2\

  7. Limits on Low-Mass WIMP Dark Matter with an Ultra-Low-Energy Germanium Detector at 220 eV Threshold

    E-Print Network [OSTI]

    Shin-Ted Lin; H. T. Wong; for the TEXONO Collaboration

    2008-10-20

    An energy threshold of (220$\\pm$10) eV was achieved at an efficiency of 50% with a four-channel ultra-low-energy germanium detector each with an active mass of 5 g\\cite{wimppaper}. This provides a unique probe to WIMP dark matter with mass below 10 GeV. With low background data taken at the Kuo-Sheng Laboratory, constraints on WIMPs in the galactic halo were derived. Both spin-independent WIMP-nucleon and spin-dependent WIMP-neutron bounds improve over previous results for WIMP mass between 3$-$6 GeV. These results, together with those on spin-dependent couplings, will be presented. Sensitivities for full-scale experiments were projected. This detector technique makes the unexplored sub-keV energy window accessible for new neutrino and dark matter experiments.

  8. Ultra-low phase-noise microwave generation using a diode-pumped solid-state laser based frequency comb and a polarization-maintaining pulse interleaver

    E-Print Network [OSTI]

    Portuondo-Campa, Erwin; Kundermann, Stefan; Balet, Laurent; Lecomte, Steve

    2015-01-01

    We report ultra-low phase-noise microwave generation at a 9.6 GHz carrier frequency from optical frequency combs based on diode-pumped solid-state lasers emitting at telecom wavelength and referenced to a common cavity-stabilized continuous-wave laser. Using a novel fibered polarization-maintaining pulse interleaver, a single-oscillator phase-noise floor of -171 dBc/Hz has been measured with commercial PIN InGaAs photodiodes, constituting a record for this type of detector. Also, a direct optical measurement of the stabilized frequency combs timing jitter was performed using a balanced optical cross correlator, allowing for an identification of the origin of the current phase-noise limitations in the system.

  9. Analysis and Control of Heteroazeotropic Batch Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , called an entrainer, has to be added to facilitate separation and enhance distillation. When a heavy entrainer is added continuously in the top section of the batch column the process is called extractive batch distillation. When an entrainer is added batchwise to the original mixture we simply call

  10. Strategies and Technologies for Improving Air Quality Around Ports

    E-Print Network [OSTI]

    Khan, Mohammad Yusuf

    2013-01-01

    fueled by ultra-low sulfur diesel (ULSD) and operating on afrom burning ultra-low sulfur diesel (ULSD) to a 50/50 blendwhen switching from ultra-low sulfur diesel (ULSD) to A50.

  11. A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials

    E-Print Network [OSTI]

    Delucchi, Mark

    2003-01-01

    S and a reference ultra-low-sulfur diesel (ULSD) with 5 ppmof the reference ultra-low-sulfur diesel (5 ppm). SF CD =diesel fuel (CD), ultra-low-sulfur diesel fuel (ULSD),

  12. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01

    fueled with ultra low sulfur diesel, RME-diesel blends andengine fueled with ultra-low sulfur diesel fuel blended withMaterials B0 Ultra Low Sulfur Diesel B20 20% Biodiesel 80%

  13. Emissions Benefits From Renewable Fuels and Other Alternatives for Heavy-Duty Vehicles

    E-Print Network [OSTI]

    Hajbabaei, Maryam

    2013-01-01

    with a 10% aromatic, ultra-low sulfur diesel fuel used inequivalent 10% aromatic ultra-low sulfur diesel fuel used inx emissions compared to ultra-low sulfur diesel fuel (ULSD).

  14. Strategies and Technologies for Improving Air Quality Around Ports

    E-Print Network [OSTI]

    Khan, Mohammad Yusuf

    2013-01-01

    profile from burning ultra-low sulfur diesel (ULSD) to awhen switching from ultra-low sulfur diesel (ULSD) to A50.emission profile burning ultra low sulfur diesel (ULSD) to a

  15. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  16. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01

    condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

  17. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  18. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  19. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  20. Electric Driven Heat Pumps in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.

    1983-01-01

    Radian Corporation, under contract to the Electric Power Research Institute, has recently completed a study of the potential range of application for retrofitting electric driven heat pumps to existing distillation columns. ...

  1. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio blog distillation by adding a link analysis phase to the standard retrieval-by-topicality phase, where in blog distillation. 1 Introduction Blog distillation is a subtask of blog search. It is defined

  2. Sulfur distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    by the thermal cracking process of the El-Lujjan oil shale showed that the yield of oil was around 12 wt of the boiling point for different distillate fractions. Sulfur in Jordanian oil shale was found to be mainly the dominant phases in these fractions. q 2005 Published by Elsevier Ltd. 1. Introduction Oil shale

  3. Investigation of Solid Particle Number Measurement of Engine Emissions

    E-Print Network [OSTI]

    Zheng, Zhongqing

    2012-01-01

    the testing. CARB Ultra Low Sulfur Diesel (ULSD) fuel (S = 8Board (CARB) ultra low sulfur diesel (ULSD) fuel (S < 15

  4. Environmental implications of trade liberalization on North American transport services: the case of the trucking sector

    E-Print Network [OSTI]

    Fernandez, Linda

    2010-01-01

    requires the use of ultra low-sulfur diesel, now required inthe shift toward ultra low-sulfur fuel. The nationwide plan

  5. Investigation of Solid Particle Number Measurement of Engine Emissions

    E-Print Network [OSTI]

    Zheng, Zhongqing

    2012-01-01

    CARB Ultra Low Sulfur Diesel (ULSD) fuel (S = 8 ppmw) andCARB) ultra low sulfur diesel (ULSD) fuel (S < 15 ppm). The

  6. Ultra-low emittance beam generation using two-color ionization injection in a CO2 laser-driven plasma accelerator

    E-Print Network [OSTI]

    Schroeder, C B; Bulanov, S S; Chen, M; Esarey, E; Geddes, C G R; Vay, J -L; Yu, L -L; Leemans, W P

    2015-01-01

    Ultra-low emittance (tens of nm) beams can be generated in a plasma accelerator using ionization injection of electrons into a wakefield. An all-optical method of beam generation uses two laser pulses of different colors. A long-wavelength drive laser pulse (with a large ponderomotive force and small peak electric field) is used to excite a large wakefield without fully ionizing a gas, and a short-wavelength injection laser pulse (with a small ponderomotive force and large peak electric field), co-propagating and delayed with respect to the pump laser, to ionize a fraction of the remaining bound electrons at a trapped wake phase, generating an electron beam that is accelerated in the wake. The trapping condition, the ionized electron distribution, and the trapped bunch dynamics are discussed. Expressions for the beam transverse emittance, parallel and orthogonal to the ionization laser polarization, are presented. An example is shown using a 10-micron CO2 laser to drive the wake and a frequency-doubled Ti:Al2...

  7. Integrated production/use of ultra low-ash coal, premium liquids and clean char. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Kruse, C.W.; Carlson, S.L. [Illinois State Geological Survey, Champaign, IL (United States); Snoeyink, V.L.; Feizoulof, C.; Assanis, D.N.; Syrimis, M. [Illinois Univ., Urbana, IL (United States); Fatemi, S.M. [Amoco Research Center, Naperville, IL (United States)

    1992-10-01

    The first step in the envisioned integrated, multi-product approach for utilizing Illinois coal is the production of ultra low-ash coal. Subsequent steps would convert low-ash coal to high-value products through mild gasification, char activation, and oxidation reactions. Approximately eight pounds of low-ash coal has been obtained from the crude reactor slurry produced for us at the University of North Dakota Energy and Environmental Research Center (UNDEERC). After treatment to remove the remaining meta-cresol, this material will be subjected to mild gasification. Low-ash mild gasification char will be activated and a catalyst surface will be added by oxidation. A 20% coal: 80% diesel fuel slurry was tested in cylinder two of a two-cylinder, diesel engine after the necessary modifications in the engine`s fuel injection system were made. Four tests indicated that the coal successfully substitutes for diesel fuel in the slurry. The fuel burns in the cylinder, with slightly improved thermal and combustion efficiency. The tests were performed at 1800 rpm and 2200 rpm and 75% load. The change in the surface properties of Calgon F-400 commercial activated carbon caused by several treatments were examined by X-ray Photoelectron Spectroscopy (XPS).

  8. Orbital effects of a monochromatic plane gravitational wave with ultra-low frequency incident on a gravitationally bound two-body system

    E-Print Network [OSTI]

    Lorenzo Iorio

    2014-09-12

    We analytically compute the long-term orbital variations of a test particle orbiting a central body acted upon by an incident monochromatic plane gravitational wave. We assume that the characteristic size of the perturbed two-body system is much smaller than the wavelength of the wave. Moreover, we also suppose that the wave's frequency is much smaller than the particle's orbital one. We make neither a priori assumptions about the direction of the wavevector nor on the orbital geometry of the planet. We find that, while the semi-major axis is left unaffected, the eccentricity, the inclination, the longitude of the ascending node, the longitude of pericenter and the mean anomaly undergo non-vanishing long-term changes. They are not secular trends because of the slow modulation introduced by the tidal matrix coefficients and by the orbital elements themselves. They could be useful to indepenedently constrain the ultra-low frequency waves which may have been indirectly detected in the BICEP2 experiment. Our calculation holds, in general, for any gravitationally bound two-body system whose characteristic frequency is much larger than the frequency of the external wave. It is also valid for a generic perturbation of tidal type with constant coefficients over timescales of the order of the orbital period of the perturbed particle.

  9. Sensitivity to Z-prime and non-standard neutrino interactions from ultra-low threshold neutrino-nucleus coherent scattering

    E-Print Network [OSTI]

    Bhaskar Dutta; Rupak Mahapatra; Louis E. Strigari; Joel W. Walker

    2015-08-31

    We discuss prospects for probing Z-prime and non-standard neutrino interactions using neutrino-nucleus coherent scattering with ultra-low energy (~ 10 eV) threshold Si and Ge detectors. The analysis is performed in the context of a specific and contemporary reactor-based experimental proposal, developed in cooperation with the Nuclear Science Center at Texas A&M University, and referencing available technology based upon economical and scalable detector arrays. For expected exposures, we show that sensitivity to the Z-prime mass is on the order of several TeV, and is complementary to the LHC search with low mass detectors in the near term. This technology is also shown to provide sensitivity to the neutrino magnetic moment, at a level that surpasses terrestrial limits, and is competitive with more stringent astrophysical bounds. We demonstrate the benefits of combining silicon and germanium detectors for distinguishing between classes of models of new physics, and for suppressing correlated systematic uncertainties.

  10. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA)

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  11. Entanglement distillation in optomechanics via unsharp measurements

    E-Print Network [OSTI]

    Víctor Montenegro; Alessandro Ferraro; Sougato Bose

    2015-03-15

    Quantum technologies based on optical Gaussian states have proven very promising in terms of scalability. However, their use in quantum networking is hindered by the fact that Gaussian entanglement cannot be distilled via Gaussian operations. We take advantage of hybrid optomechanical systems to address this problem, proposing a scheme to distill optical two-mode squeezed vacua via unsharp measurements. Here, one of the optical modes is injected into a single sided Fabry-P\\'{e}rot cavity and non-linearly coupled to a mechanical oscillator. Afterwards, the position of the oscillator is measured using pulsed optomechanics and homodyne detection. Our results show that this measurement can conditionally increase the initial entanglement under an optimal radiation-pressure interaction strength, which corresponds to an effective unsharp non-Gaussian measurement of the photon number inside the cavity. We show how the resulting entanglement distillation can be verified by using a standard quantum teleportation procedure.

  12. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Zamarripa, Pablo A. Marchetti, Ignacio E. Grossmann Department of Chemical Engineering Carnegie Mellon Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits

  13. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    homes in the United States use middle distillate as a primary energy source for heating. -homes in the United States use middle distillate as their primary energy source for heating. -

  14. Crude Distillation Unit Heat Recovery Study 

    E-Print Network [OSTI]

    John, P.

    1979-01-01

    Baytown's Pipe Still 3 is a 95,000 barrel per day crude distillation unit. A comprehensive heat recovery and energy utilization study was done on Pipe Still 3 after a preliminary cursory study had indicated that an overall look at the total picture...

  15. Intelligent fuzzy supervisory control for distillation columns 

    E-Print Network [OSTI]

    Santhanam, Srinivasan

    1993-01-01

    (disturbance) and the response of the top tray temperature(controlled variable). This thesis will also outline a simulation software to characterize a benzene-toluene binary distillation column and an X-window based Graphical User Interface to run the simulation....

  16. Energy Conservation Options in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01

    of theoretical trays in any re boiled distillation column. Columns in which all of the required heat enters with the feed cannot achieve i I I ....e-.........c..._. I "

  17. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and Technology N--7034 Trondheim Norway Abstract The task of separating a multicomponent mixture into streams shell using dividing walls or vertical partitions. INTRODUCTION Industrial distillation processes is also known as the Petlyuk column, due to a theoretical study of Pet­ lyuk et al. (1965), or as a fully

  18. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and Technology N­7034 Trondheim Norway Abstract The task of separating a multicomponent mixture intostreams shell using dividing walls or vertical partitions. INTRODUCTION Industrial distillation processes is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  19. Advanced Distillation: Programs Proposed to DOE 

    E-Print Network [OSTI]

    Woinsky, S. G.

    2001-01-01

    to the foremost practitioner of the Advanced Distillation art, due to a 30 year continuity in Ule area as both a consultant and a university professor. His consulting assignments lu1ve been long-ternl companies such as M, W, Kellogg... when a plgasoline have lead...

  20. New Design Methods and Algorithms for Multi-component Distillation...

    Broader source: Energy.gov (indexed) [DOE]

    multicomponent.pdf More Documents & Publications CX-100137 Categorical Exclusion Determination ITP Chemicals: Hybripd SeparationsDistillation Technology. Research Opportunities...

  1. Stratospheric sulfur oxidation kinetics

    SciTech Connect (OSTI)

    Jayne, J.T.; Worsnop, D.R.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States)] [and others

    1995-12-31

    Oxidation of SO2 to H2SO4 in the atmosphere is believed to involve the reaction of SO3 with water. It is commonly assumed that this is an important step leading to homogeneous nucleation of H2SO4 aerosol particles. Heterogeneous chemistry on sulfuric acid aerosols regulate much of the ozone photochemistry in the lower stratosphere and are also believed to have significant effect on the climate. Understanding aerosol loading requires a detailed knowledge of the stratospheric sulfur budget, including its oxidation kinetics. Here we present results of a laboratory project studying a key step in the oxidation process, the homogeneous reaction between SO3 and H2O vapor. Kinetic measurements are performed in a high-pressure turbulent fast-flow reactor (fabricated at MIT) which minimizes heterogeneous loss of SO3 on reactorwalls. The rate of decay of SO3 and the appearance of H2SO4 is monitored in the presence of excess water vapor. Gas phase reactants and products are detected via an atmospheric pressure chemical ionization mass spectrometer which is coupled to the exit of the flow reactor. Sulfuric acid nucleation studies can also be performed using the turbulent flow reactor. Initial measurements using a particle detector (based on Mie scattering) showed that aerosol formation and particle size distribution are controlled by varying the SO3/H2O gas ratio and the reactor temperature. Results for the reaction SO3J+ H2O show a second order dependence in water vapor density and a strong negative temperature dependence. The results, measured in the range -30C to +95C, imply that an SO3.H2O adduct and/or a water dimer species is likely involved in the reaction mechanism. Results of recent theoretical calculations on the SO3 + H2O system also support the finding that two water molecules are involved. Implications for the gas phase production of sulfuric acid in the atmosphere will be discussed.

  2. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    . Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wineCHEM­333: Lab Experiment 3: Distillation and Gas Chromatography: Prelab-Assignment: read Chapters 5 and 6. Distillation is one of the most powerful techniques for purifying volatile organic compounds

  3. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  4. Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC

    DOE Patents [OSTI]

    Roberts, George W. (Emmaus, PA); Tao, John C. (Perkiomenville, PA)

    1985-01-01

    In this invention, a process is disclosed characterized by heating a slurry of coal in the presence of a process-derived recycle solvent and passing same to a dissolver zone, separating the resultant gases and liquid/solid products therefrom, vacuum distilling the liquid/solids products, separating the portions of the liquid/solids vacuum distillation effluent into a solid ash, unconverted coal particles and SRC material having a boiling point above 850.degree. F. and subjecting same to a critical solvent deashing step to provide an ash-free SRC product. The lighter liquid products from the vacuum distillation possess a boiling point below 850.degree. F. and are passed through a distillation tower, from which recycled solvent is recovered in addition to light distillate boiling below 400.degree. F. (overhead). The ash-free SRC product in accompanyment with at least a portion of the process derived solvent is passed in combination to a hydrotreating zone containing a hydrogenation catalyst and in the presence of hydrogen is hydroprocessed to produce a desulfurized and denitrogenized low-sulfur, low-ash boiler fuel and a process derived recycle solvent which is recycled to slurry the coal in the beginning of the process before heating.

  5. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  6. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  7. Production of gasoline and distillate fuels from light cycle oil

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Owens, P.J.; Sarli, M.S.

    1991-01-15

    This patent describes a process for the co-production of high quality gasoline and distillate products from catalytically cracked feedstocks. It comprises: hydrocracking a substantially dealkylated feedstock with a hydrocracking catalyst at a hydrogen partial pressure not greater than 1200 psig and a conversion to gasoline boiling range products not more than 75 wt. percent; separating the products of hydrocracking into a gasoline boiling range fraction, a first distillate range fraction boiling immediately above the gasoline fraction with an end point in the range of 450{degrees} to 500{degrees} F. and a second distillate fraction boiling above the first distillate fraction; recycling at least a portion of the first distillate fraction to the hydrocracking step to effect saturation and partial cracking of aromatics in the recycled fraction to increase the paraffin content of the second distillate fraction; recovering the second distillate fraction.

  8. The Engineering Meetings Board has approved this paper for publication. It has successfully completed SAE's peer review process under the supervision of the session organizer. This process requires a minimum of three (3) reviews by industry experts.

    E-Print Network [OSTI]

    Wu, Mingshen

    through the use of engine optimization, aftertreatment system integration, and ultra-low sulfur diesel

  9. Stocks of Distillate Fuel Oil Greater Than 15 ppm to 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG Oil10:Price27,84320,3548,679

  10. Refiner and Blender Net Production of Distillate Fuel Oil 15 ppm Sulfur and

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space5,168 5,228 5,107

  11. Refiner and Blender Net Production of Distillate Fuel Oil > 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space5,168 5,228 5,107ppm

  12. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Jozewicz, Wojciech (Chapel Hill, NC)

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  13. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati (Ann Arbor, MI)

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  14. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  15. November 30, 2006 -TCAT to put six hybrid buses on the road Home News Opinion Accent Sports Click. Exclusively Online

    E-Print Network [OSTI]

    be using an ultra-low-sulfur diesel fuel that is being phased in nationally starting this fall. Sulfur

  16. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01

    Transfer Tube TL Transfer Line ULSD Ultra Low Sulfur Diesellow sulfur diesel (ULSD) (ULSD/biodiesel blends (B20,

  17. Production of gasoline and distillate fuels from light cycle oil

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Owens, P.J.; Sarli, M.S.

    1991-02-05

    This patent describes a process for the co-production of high quality gasoline and distillate products from catalytically cracked feedstocks. It comprises catalytically cracking a hydrocarbon feedstock to produce a substantially dealkylated cracked product, hydrocracking the substantially dealkylated product with a hydrocracking catalyst at a hydrogen partial pressure not greater than 1200 psig and a conversion to gasoline boiling range products not more than 75 wt. percent; separating the products of hydrocracking into a gasoline boiling range fraction, a first distillate range fraction boiling immediately above the gasoline fraction with an end point in the range of 450{degrees} to 500{degrees} F and a second, higher boiling distillate fraction which is more paraffinic than the first distillate fraction; recycling at least a portion of the first, lower boiling distillate fraction to the catalytic cracking step, recovering the second, higher boiling distillate fraction.

  18. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Knight, R.A. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In this project, two approaches to sulfur reduction are being explored in conjunction with thermocracking: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to thermocracking. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation of the scrubbing solvent and light-to-middle oils to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization is the same material previously studied, which was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous either as live cultures or in the form of concentrated biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous flash thermocracker (FTC) constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches. This quarter, 45 kg of IBC-109 coal was obtained and sized to 40 x 80 mesh for mild gasification. Laboratory experiments were conducted to identify means of dispersing or emulsifying pitch in water to render is accessible to biocatalysts, and exploratory desulfurization tests on one-gram pitch samples were begun.

  19. Unifying classical and quantum key distillation

    E-Print Network [OSTI]

    Matthias Christandl; Artur Ekert; Michal Horodecki; Pawel Horodecki; Jonathan Oppenheim; Renato Renner

    2007-02-28

    Assume that two distant parties, Alice and Bob, as well as an adversary, Eve, have access to (quantum) systems prepared jointly according to a tripartite state. In addition, Alice and Bob can use local operations and authenticated public classical communication. Their goal is to establish a key which is unknown to Eve. We initiate the study of this scenario as a unification of two standard scenarios: (i) key distillation (agreement) from classical correlations and (ii) key distillation from pure tripartite quantum states. Firstly, we obtain generalisations of fundamental results related to scenarios (i) and (ii), including upper bounds on the key rate. Moreover, based on an embedding of classical distributions into quantum states, we are able to find new connections between protocols and quantities in the standard scenarios (i) and (ii). Secondly, we study specific properties of key distillation protocols. In particular, we show that every protocol that makes use of pre-shared key can be transformed into an equally efficient protocol which needs no pre-shared key. This result is of practical significance as it applies to quantum key distribution (QKD) protocols, but it also implies that the key rate cannot be locked with information on Eve's side. Finally, we exhibit an arbitrarily large separation between the key rate in the standard setting where Eve is equipped with quantum memory and the key rate in a setting where Eve is only given classical memory. This shows that assumptions on the nature of Eve's memory are important in order to determine the correct security threshold in QKD.

  20. American Distillation Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen5AllEnergyAmeriPower LLC Jump to:Distillation Inc Jump

  1. Increasing Distillate Production at U.S. Refineries

    Reports and Publications (EIA)

    2010-01-01

    Paper explores the potential for U.S. refiners to create more distillate and less gasoline without major additional investments beyond those already planned.

  2. Volatile organic emissions from the distillation and pyrolysis of vegetation

    E-Print Network [OSTI]

    Greenberg, T

    2006-01-01

    emissions from vegetation pyrolysis Comprehensive laboratoryfrom the distillation and pyrolysis of vegetation J. P.J. Anal. and Appl. Pyrolysis, 60, 123–130, 2000. Fall, R. :

  3. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  4. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  5. Sulfur-Free Selective Pulping 

    E-Print Network [OSTI]

    Dimmel, D. R.; Bozell, J. J.

    1994-01-01

    an increase in pulping rate and yields, which translates to less energy required per ton of product. Less sulfur means a simplified process, lower odor emissions, and a decrease requirement for bleaching chemicals, meaning less organics being discharged...

  6. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio report a new approach to blog distillation, defined as the task in which, given a user query, the system ranks the blogs in descending order of relevance to the query topic. Our approach is based on the idea

  7. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K???Bi???TiO?-BaTiO?-Na???Bi???TiO? piezoelectric materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26

    We synthesized grain-oriented lead-free piezoelectric materials in (K???Bi???TiO?-BaTiO?-xNa???Bi???TiO? (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d?? ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectricmore »materials.« less

  8. Method of preparing graphene-sulfur nanocomposites for rechargeable...

    Office of Scientific and Technical Information (OSTI)

    Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Method of preparing graphene-sulfur...

  9. On the Origin of Sulfur

    E-Print Network [OSTI]

    Nils Ryde; David L. Lambert

    2005-10-05

    We present our work on the halo evolution of sulfur, based on observations of the S I lines around 9220 A for ten stars for which the S abundance was obtained previously from much weaker S I lines at 8694 A. We cannot confirm the rise and the high [S/Fe] abundances for low [Fe/H], as claimed in the literature from analysis of the 8694 A lines. The reasons for claims of an increase in [S/Fe] with decreasing [Fe/H] are probably twofold: uncertainties in the measurements of the weak 8694 A lines, and systematic errors in metallicity determinations from Fe I lines. The near-infrared sulfur triplet at 9212.9, 9228.1, and 9237.5 A are preferred for an abundance analysis of sulfur for metal-poor stars. Our work was presented in full by Ryde & Lambert (2004).

  10. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E. (Manassas, VA)

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  11. Synthesis and design of optimal thermal membrane distillation networks 

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30

    Thermal membrane distillation is one of the novel separation methods in the process industry. It involves the simultaneous heat and mass transfer through a hydrophobic semipermeable membrane through the use of thermal energy to bring about...

  12. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  13. Energy Saving in Distillation Using Structured Packing and Vapor Recompression 

    E-Print Network [OSTI]

    Hill, J.H.

    1987-01-01

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated ...

  14. Energy Use in Distillation Operation: Nonlinear Economic Effects 

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation is obviously very...

  15. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  16. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings 

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01

    of applications, embody characteristics that inherently make them economic candidates for absorption cycle heat upgrading. Practical applications to current U.S. distillations could save 30 trillion BTU per year, at payback periods ranging from 1 to 3 years. So...

  17. Integrated Thermal and Hydraulic Analysis of Distillation Columns 

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    2002-01-01

    and Hydraulic Analysis of Distillation Columns Ketan Samant, Aspen Technology Ian Sinclair, Aspen Technology Ginger Keady, Aspen Technology This paper outlines the implementation of column thermal and hydraulic analysis in a simulation environment...

  18. Energy Efficiency in Cryogenic Fractionation Through Distributive Distillation 

    E-Print Network [OSTI]

    Carradine, C. R.; McCue, R. H.

    1992-01-01

    The Advanced Recovery System (ARS) is a patented process that uses the principle of distributed distillation to achieve energy efficiency in the olefins process. This paper describes the concept of ARS and how, by integrating the chill...

  19. Safety considerations for the use of sulfur in sulfur-modified pavement materials 

    E-Print Network [OSTI]

    Jacobs, Carolyn Yuriko

    1980-01-01

    Liquid Sulfur Page v111 ix 33 33 35 IV Symptoms of Poisoning . First Aid SULFUR IN THE PAVING INDUSTRY General Sand-Asphalt-Sulfur Pavements (SAS) ', , Sulfur-Extended Asphalt Pavements (SEA) Sulfur Concrete EVALUATION OF RISKS AND SAFETY... RECOMMENDATIONS General Stationary Sources Mobile Sources Maintenance 40 41 43 43 44 45 46 Hot-Mix Recycling VI EMISSIONS MONITORING METHODS General Area Monitoring - Continuous Samplina Short Term Sampling (" Grab" Sampling) Personnel Monitoring...

  20. Heat Recovery in Distillation by Mechanical Vapor Recompression 

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    1986-01-01

    IN DISTILLATION BY MECHANICAL VAPOR RECOMPRESSION Frederick E. Becker and Alexandra I. Zakak Tecogen, Inc., A Subsidiary of Thermo Electron Corporation Waltham, Massachusetts ABSTRACT A significant reduction in distillation tower energy requirements can..., and then recompressing the low-pressure bottom vapors and injecting them directly into the column bottom. The choice of either scheme is a function of the physical properties of the vapors; i.e., the specific volume of the top or bottom vapors may dictate the most...

  1. Identification of sulfur heterocycles in coal liquids and shale oils. Technical progress report, August 1, 1980-May 1, 1981

    SciTech Connect (OSTI)

    Lee, M. L.; Castle, R. N.

    1981-01-01

    The sulfur heterocycle separation scheme which was described in the last progress report was evaluated for quantitative recovery of individual components. The results indicate that recoveries can range from 10% to approx. 30% depending on the structure of the compound. During this period, 23 unsubstituted sulfur-containing heterocyclic ring systems were synthesized in oder to confirm GC/MS identifications and for biological testing. The four possible 3-ring heterocycles and the thirteen possible 4-ring heterocycles were tested for mutagenic activity in the histidine reversion (Ames assay) system. One of the 3-ring isomers, naphtho(1,2-b)-thiophene, and six of the 4-ring isomers induced mutations in Salmonella test strains. One of these compounds, phenanthro(3,4-b)thiophene, displayed approximately the same mutagenic activity as benzo(a)pyrene. A two-step adsorption chromatographic procedure was developed in order to fractionate synthetic fuels into various chemical-type classes for studying the relative concentrations and mutagenic activities of the various types. An SRC-II Heavy Distillate was fractionated into aliphatic hydrocarbons, polycyclic aromatic hydrocarbons, sulfur heterocycles, indoles and carbazoles, azaarenes, and amino polycyclic aromatic hydrocarbons. It was found that the amino-PAH fraction contained most of the mutagenic activity. A survey was made for compounds containing both nitrogen and sulfur heteroatoms in their structures. A number of these compounds were detected by GC using nitrogen- and sulfur-selective detection.

  2. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  3. Contribution of isotopologue self-shielding to sulfur mass-independent fractionation during sulfur dioxide photolysis

    E-Print Network [OSTI]

    Lyons, J. R.

    Signatures of sulfur mass-independent fractionation (S-MIF) are observed for sulfur minerals in Archean rocks, and for modern stratospheric sulfate aerosols (SSA) deposited in polar ice. Ultraviolet light photolysis of ...

  4. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  5. HYBRID SULFUR FLOWSHEETS USING PEM ELECTROLYSIS AND A BAYONET DECOMPOSITION REACTOR

    SciTech Connect (OSTI)

    Gorensek, M; William Summers, W

    2008-05-30

    A conceptual design is presented for a Hybrid Sulfur process for the production of hydrogen using a high-temperature nuclear heat source to split water. The process combines proton exchange membrane-based SO{sub 2}-depolarized electrolyzer technology being developed at Savannah River National Laboratory with silicon carbide bayonet decomposition reactor technology being developed at Sandia National Laboratories. Both are part of the US DOE Nuclear Hydrogen Initiative. The flowsheet otherwise uses only proven chemical process components. Electrolyzer product is concentrated from 50 wt% sulfuric acid to 75 wt% via recuperative vacuum distillation. Pinch analysis is used to predict the high-temperature heat requirement for sulfuric acid decomposition. An Aspen Plus{trademark} model of the flowsheet indicates 340.3 kJ high-temperature heat, 75.5 kJ low-temperature heat, 1.31 kJ low-pressure steam, and 120.9 kJ electric power are consumed per mole of H{sub 2} product, giving an LHV efficiency of 35.3% (41.7% HHV efficiency) if electric power is available at a conversion efficiency of 45%.

  6. Distillation and Dehydro Reactors Advanced Process Conrol Freeport Texas PLant 

    E-Print Network [OSTI]

    Eisele, D.

    2014-01-01

    Reactors Advanced Process Control Freeport Texas Plant ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC 6/2/2014 INTERNAL... Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC – Control Matrix 6/2/2014 INTERNAL; CONFIDENTIAL 3 ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20...

  7. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  8. Utilizing Supplemental Ultra-Low-NO

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    technology into a 65-kilowatt (kW) microturbine and 100-horsepower (HP) heat recovery boiler. Introduction A combined heat and power (CHP) system can be a financially attractive...

  9. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    thermal energy (e.g. Koschikowski et al, 2003): #12;Solar thermal powered desalination: reviewSolar thermal powered desalination: membrane versus distillation technologies G. Burgess and K considered to be the desalination technology most suited to integration with concentrating solar thermal

  10. Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b

    E-Print Network [OSTI]

    Skogestad, Sigurd

    savings in energy consumption and reduction of investment cost. In this paper we give an overview of some and calculate energy requirements and provide a basis for detailed design. Reduced CO2 emission is an additional, and to carry out this separation with a minimum cost and energy consumption. Distillation is the most widely

  11. Hydrocracking process with integrated distillate product hydrogenation reactor

    SciTech Connect (OSTI)

    Hoehn, R.K.; Reno, M.E.

    1991-06-25

    This patent describes a hydrocracking process. It comprises passing a feed stream which comprises an admixture of hydrocarbons boiling above 240 degrees Centigrade and hydrogen through a hydrocracking reaction zone maintained at hydrocracking conditions and producing a mixed-phase hydrocracking reaction zone effluent stream; separating the mixed-phase hydrocracking reaction zone effluent stream into a first vapor stream, which comprises hydrogen, light hydrocarbons and distillate hydrocarbons, and a first liquid stream, which comprises distillate hydrocarbons; forming a second vapor stream and a second liquid, stream by partially condensing the first vapor stream, with the second liquid stream comprising distillate hydrocarbons and having a lower average boiling point than the first liquid stream; passing the second liquid stream and added hydrogen through a hydrogenation reaction zone maintained at hydrogenation conditions and producing a hydrogenation zone effluent stream; and, passing distillate hydrocarbons present in the hydrogenation zone effluent stream and the first liquid stream into a fractionation zone, and recovering a hydrocracking zone product stream.

  12. ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried

    E-Print Network [OSTI]

    ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced amounts of fish meal, fish oil, whole wheat flour, corn gluten meal, and vitamin and mineral premixes

  13. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    . The daily desalinated water output per square metre of solar collector area is estimated for a number suited to integration with concentrating solar thermal concentrating collectors on a medium to largeSolar thermal powered desalination: membrane versus distillation technologies G. Burgess and K

  14. Improved Analysis and Understanding of the Petlyuk Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the energy consumption. When the column is oper­ ated optimally, the infinite staged Petlyuk column always Extended Abstract The Petlyuk (Petlyuk 1965) arrangement for separation of a ternary mixture into three pure product streams has the potential of 20­50% energy savings compared to conventional distillation

  15. Improved Analysis and Understanding of the Petlyuk Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the energy consumption. When the column is oper- ated optimally, the infinite staged Petlyuk column always Extended Abstract The Petlyuk (Petlyuk 1965) arrangement for separation of a ternary mixture into three pure product streams has the potential of 20-50% energy savings compared to conventional distillation

  16. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17

    the synthetic sample and experimental study previously carried out. (e) To correlate steam-propane distillation yields for some crude oils and synthetic hydrocarbons to generate steam-propane distillation data that could be used to develop the input data... there is need to develop a model to predict distillate yield under any set of conditions for any heavy oil, requiring only the simulated distillation (SIMDIS) trace (i.e. percent off vs. normal boiling temperature) of the oil. The expected deliverables from...

  17. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  18. Microbial Architecture of Environmental Sulfur Processes: A

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    potential impacts on water quality, including acid generation in acid mine drainage (AMD) environments, 2009. Accepted July 9, 2009. Microbial oxidation of sulfur-rich mining waste materials drives acid mine drainage (AMD) and affects the global sulfur biogeochemical cycle. The generation of AMD is a complex

  19. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  20. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  1. Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad Department. It is well known which variables to control in normal distillation columns. But for heat integrated for heat integrated distillation columns. We will use the concept of self­optimizing control (Skogestad et

  2. Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad Department. It is well known which variables to control in normal distillation columns. But for heat integrated for heat integrated distillation columns. We will use the concept of self-optimizing control (Skogestad et

  3. SERVICE STATION INFORMATION There are 2 campus service stations for use by University of Michigan vehicles. The Baxter Road Service

    E-Print Network [OSTI]

    Kirschner, Denise

    to alternative fuel by refining our biodiesel fuel to Ultra Low Sulfur B20 biodiesel meeting 2009 diesel fuel

  4. Project Sponsor: Siemens Power GenerationUCI Combustion Laboratory www.ucicl.uci.edu

    E-Print Network [OSTI]

    Mease, Kenneth D.

    in ultra low sulfur diesel fuel (DF2), its discrete water droplet size distribution and the injection

  5. January2013Update Growing Together

    E-Print Network [OSTI]

    Kim, Philip

    , electric or ultra-low sulfur diesel fuel equipment, and the washing of truck undercarriages and wheels

  6. Growing Together Columbia University's

    E-Print Network [OSTI]

    Yang, Junfeng

    . In addition, all construction equipment use air pollution control devices and Ultra-Low Sulfur Diesel (ULSD

  7. Integrated process of distillation with side reactors for synthesis of organic acid esters

    DOE Patents [OSTI]

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  8. Atmos. Chem. Phys., 8, 47294739, 2008 www.atmos-chem-phys.net/8/4729/2008/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    and Physics Nanoparticle formation in the exhaust of vehicles running on ultra-low sulfur fuel H. Du and F. Yu on vehicles and fuel with ultra-low sulfur is to be used. Although CRDPFs were found to be effective in reduc of nanoparticles in an exhaust plume under ultra-low sulfur conditions. Such a study is necessary to project fu

  9. 8, 27152744, 2008 Nanoparticle

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    formation in the exhaust of vehicles running on ultra-low sulfur fuel Hua Du and Fangqun Yu Atmospheric regenerating diesel particle filters (CRDPFs) have to be employed5 on vehicles and fuel with ultra-low sulfur concentrations have also been detected for vehicles running on ultra-low sulfur fuel but without CRDPFs. The main

  10. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  11. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  12. Entanglement cost and distillable entanglement of symmetric states

    E-Print Network [OSTI]

    Keiji Matsumoto

    2007-08-23

    We compute entanglement cost and distillable entanglement of states supported on symmetric subspace. Not only giving general formula, we apply them to the output states of optimal cloning machines. Surprisingly, under some settings, the optimal n to m clone and true m copies are the same in entanglement measures. However, they differ in the error exponent of entanglement dilution. We also presented a general theory of entanglement dilution which is applicable to any non-i.i.d sequence of states.

  13. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  14. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    SciTech Connect (OSTI)

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  15. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  16. 2006 ORNL Story Tips | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the original amount of information, making what remains manageable. Emissions - Ultra-low sulfur October 16, 2006 - New low-sulfur diesel available at gas stations and travel...

  17. Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer membrane PEM electrolyzer has been investigated as a viable system for the electrolysis step of the electrolyzer and membranes developed to limit SO2 crossover. © 2009 The Electrochemical Society. DOI: 10

  18. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore »cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  19. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zheng, Jianming [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Walter, Eric [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pan, Huilin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lv, Dongping [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zuo, Pengjian [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Chen, Honghao [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Deng, Z. D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liaw, Bor Y. [School of Ocean and Earth Science and Technology, Hawaii Natural Energy Institute, (United States); Yu, Xiqian [Brookhaven National Laboratory, Upton, NY (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Upton, NY (United States); Zhang, Ji-Guang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liu, Jun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Xiao, Jie [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  20. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  1. Mild hydrocracking: a low cost route to more distillate

    SciTech Connect (OSTI)

    Kalnes, T.N.; Lamb, P.R.; Pegg, D.R.; Tajbl, D.G.

    1984-03-01

    The UOP MHC Unibon process, a relatively new application of distillate hydrocracking technology, combines the features of desulfurization and hydrocracking to provide a useful tool to aid the refiner in meeting future product demand trends. Already commercialized in four locations, the process is particularly attractive to those refiners who do not have residual conversion capacity. Pay backs of less than one year are common. In addition, the process can provide the FCC refiner with added capability for adjusting the product slate to meet seasonal demands.

  2. An Aerosol Condensation Model for Sulfur Trioxide

    SciTech Connect (OSTI)

    Grant, K E

    2008-02-07

    This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

  3. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  4. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon...

  5. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  6. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  7. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  8. Multiple-sulfur isotope effects during photolysis of carbonyl sulfide

    E-Print Network [OSTI]

    Lin, Ying

    Laboratory experiments were carried out to determine sulfur isotope effects during ultraviolet photolysis of carbonyl sulfide (OCS) to carbon monoxide (CO) and elemental sulfur (S[superscript 0]). The OCS gas at 3.7 to 501 ...

  9. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control – Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  10. Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio Sebastiani

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio in revised form 10 May 2013 Accepted 30 May 2013 Available online 14 June 2013 Keywords: Blog distillation Blog search Link analysis Sentiment analysis a b s t r a c t In this paper we test a new approach

  11. Scaling control during membrane distillation of coal seam gas reverse osmosis brine

    E-Print Network [OSTI]

    Scaling control during membrane distillation of coal seam gas reverse osmosis brine Hung C. Duong during membrane distillation (MD) of brine from reverse osmosis (RO) treatment of coal seam gas (CSG. During CSG production, both gas and water are extracted to the surface. Gas is commonly separated from

  12. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process Q H columnPROMS. AIChE 1999 Annual meeting / 11.03.99 2 NTNU #12; T. Larsson, S. Skogestad Control of a industrial heat

  13. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process QH columnE 1999 Annual meeting / 11.03.99 2 NTNU #12;T. Larsson, S. Skogestad Control of a industrial heat

  14. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Distillation Ivar J. Halvorsen1 and Sigurd Skogestad Norwegian University of Science and Technology, Department Also at SINTEF Electronics and Cybernetics, 7465 Trondheim, Norway Prepared for presentation at the Topical conference on Separations Technology, Session 23 - Distillation Modeling and Processes II. 2001

  15. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    that handle more than 90% of separations and purifications. The capital investment for these distillation.87 million TJ) per year, or to a power consumption of 91 GW, or 54 million tons of crude oil. Distillation conditions to minimize the total investment and operating cost. Continuous decisions are related

  16. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  17. Mass-independent sulfur isotope fractionation during photochemistry of sulfur dioxide

    E-Print Network [OSTI]

    Whitehill, Andrew (Andrew Richard)

    2015-01-01

    Mass-independent sulfur isotope signatures are observed in Archean and early Paleoproterozoic sedimentary sulfate and sulfide minerals, and provide the most robust constraints on early atmospheric oxygen levels. Smaller ...

  18. Policy Analysis Changing Trends in Sulfur Emissions

    E-Print Network [OSTI]

    Jacobson, Mark

    Goddard Institute for Space Studies, New York, New York, and Disaster Prevention Research Institute, Kyoto in Asia where the pressing environ- mental problems of urban pollution, acid deposition, and climate change are intimately linked to sulfur (1). Over the last 25 years the primary energy demand in Asia has

  19. On the galactic chemical evolution of sulfur

    E-Print Network [OSTI]

    N. Ryde; D. L. Lambert

    2003-12-02

    Sulfur abundances have been determined for ten stars to resolve a debate in the literature on the Galactic chemical evolution of sulfur in the halo phase of the Milky Way. Our analysis is based on observations of the S I lines at 9212.9, 9228.1, and 9237.5 A for stars for which the S abundance was obtained previously from much weaker S I lines at 8694.0 and 8694.6 A. In contrast to the previous results showing [S/Fe] to rise steadily with decreasing [Fe/H], our results show that [S/Fe] is approximately constant for metal-poor stars ([Fe/H] < -1) at [S/Fe] = +0.3. Thus, sulfur behaves in a similar way to the other alpha elements, with an approximately constant [S/Fe] for metallicities lower than [Fe/H] = -1. We suggest that the reason for the earlier claims of a rise of [S/Fe] is partly due to the use of the weak S I 8694.0 and 8694.6 A lines and partly uncertainties in the determination of the metallicity when using Fe I lines. The S I 9212.9, 9228.1, and 9237.5 A lines are preferred for an abundance analysis of sulfur for metal-poor stars.

  20. Requirements for Emergency Generator Operation All Emergency Generators

    E-Print Network [OSTI]

    Lawson, Catherine L.

    .2% Sulfur or less) As of October 1, 2007 Ultra low Sulfur Diesel must be used (0.05% Sulfur or less be received from manufacturer and sent to REHS Diesel emergency Generators must use low Sulfur Diesel ( 0

  1. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-01-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  2. Low capital implementation of distributed distillation in ethylene recovery

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  3. Effects of system densities on distillation column performance

    SciTech Connect (OSTI)

    Fasesan, S.O.; Sanni, S.A.; Taiwo, E.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria). Dept. of Chemical Engineering

    1998-06-01

    Distillation experiments were carried out on three binary systems (ethanol-butanol, ethanol-propan-2-ol, and propan-2-ol-butanol) in a 0.1-m internal diameter glass column packed with 8 mm diameter Raschig rings. The experiments were performed under total reflux conditions and at atmospheric pressure. The data collected on column performance showed that performance declined with increasing average bulk liquid density. The results also lend credence to earlier reports on the behavior of column performance with respect to component concentration in the feed mixtures. The system densities of the three binary systems were measured at four different temperatures, 30, 40, 50, and 60 C. The data were compared with the predicted data of Yen-Woods and Multifluid models. The accuracy of the predictions of the Yen-Woods model was rather poor while that of the Multifluid model was very encouraging.

  4. An experimental and mathematical investigation of hydrocarbon steam distillation 

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01

    I LIJ D D CO D CIC D P1a L), OOLQLI [ [ LQS LQ WP8Q$ ?7) I/I I?I hl m ~ III O I?I I/I O & P) ?I- 0 O nj (Z) 4J Q O E III ID Cl ?I ?I Q ?/ ??: PJ Cl C C I?l ICl E ?J ??I I III 0 az I? I W K Q3 Ctl IQ C) PV... decreases near the end of the run. Th1s occurs when the volume of hydrocarbon 1n the 11quid phase of the distillation cell becomes small and cannot support 1ts vapor pressure. 07 C5 0 III QI 5- I/I QI 5- 0- 5- 0 CL IQ ) 0 CQ Ol O 0 4J Itl...

  5. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  6. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  7. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  8. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K0.5Bi0.5TiO3-BaTiO3-Na0.5Bi0.5TiO3 piezoelectric materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26

    We synthesized grain-oriented lead-free piezoelectric materials in (K0.5Bi0.5TiO3-BaTiO3-Na0.5Bi0.5TiO3 (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (,0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d33 , 190pC/N) and high temperature stability (,1606C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-1806 domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectricmore »materials.« less

  9. Costs to reduce sulfur dioxide emissions

    SciTech Connect (OSTI)

    None

    1982-03-01

    Central to the resolution of the acid rain issue are debates about the costs and benefits of controlling man-made emissions of chemicals that may cause acid rain. In this briefing, the position of those who are calling for immediate action and implicating coal-fired powerplants as the cause of the problem is examined. The costs of controlling sulfur dioxide emissions using alternative control methods available today are presented. No attempt is made to calculate the benefits of reducing these emissions since insufficient information is available to provide even a rough estimate. Information is presented in two steps. First, costs are presented as obtained through straightforward calculations based upon simplifying but realistic assumptions. Next, the costs of sulfur dioxide control obtained through several large-scale analyses are presented, and these results are compared with those obtained through the first method.

  10. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Liu, Wei (Cambridge, MA)

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  11. Refiner/marketer targets production of transportation fuels and distillates

    SciTech Connect (OSTI)

    Thompson, J.E.

    1997-01-01

    Citgo Petroleum Corp., the wholly owned subsidiary of Petroleos de Venezuela, S.A. (PDVSA), the Venezuelan national oil company, owns two gasoline producing refineries, a 305,000-b/d system in Lake Charles, La., and a 130,000-b/d facility in Corpus Christi, Texas. Each is considered a deep conversion facility capable of converting heavy, sour crudes into a high percentage of transportation fuels and distillates. Two smaller refineries, one in Paulsboro, N.J., and one in Savannah, GA., have the capacity to process 40,000 b/d and 28,000 b/d of crude, respectively, for asphalt products. In the past two years, Citgo`s light oils refineries operated safely and reliably with a minimum of unscheduled shutdowns. An ongoing emphasis to increase reliability has resulted in extended run lengths at the refineries. Citgo has invested $314 million at its facilities in 1995, much of this toward environmental and regulatory projects, such as the new waste water treatment unit at the Lake Charles refinery. Over the next few years, Citgo expects to complete $1.5 billion in capital spending for major processing units such as a 60,000-b/d FCC feed hydrotreater unit at the Lake Charles refinery and crude expansion at the Corpus Christi refinery. Product exchanges and expanded transport agreements are allowing Citgo to extend its marketing reach.

  12. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect (OSTI)

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  13. Use of extractive distillation to produce concentrated nitric acid

    SciTech Connect (OSTI)

    Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

    1981-04-01

    Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

  14. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  15. A heat & mass integration approach to reduce capital and operating costs of a distillation configuration

    SciTech Connect (OSTI)

    Madenoor Ramapriya, Gautham; Jiang, Zheyu; Tawarmalani, Mohit; Agrawal, Rakesh

    2015-11-11

    We propose a general method to consolidate distillation columns of a distillation configuration using heat and mass integration. The proposed method encompasses all heat and mass integrations known till date, and includes many more. Each heat and mass integration eliminates a distillation column, a condenser, a reboiler and the heat duty associated with a reboiler. Thus, heat and mass integration can potentially offer significant capital and operating cost benefits. In this talk, we will study the various possible heat and mass integrations in detail, and demonstrate their benefits using case studies. This work will lay out a framework to synthesize an entire new class of useful configurations based on heat and mass integration of distillation columns.

  16. DYNAMIC MODELING AND CONTROL OF REACTIVE DISTILLATION FOR HYDROGENATION OF BENZENE 

    E-Print Network [OSTI]

    Aluko, Obanifemi

    2010-01-16

    This work presents a modeling and control study of a reactive distillation column used for hydrogenation of benzene. A steady state and a dynamic model have been developed to investigate control structures for the column. ...

  17. Water distillation using waste engine heat from an internal combustion engine

    E-Print Network [OSTI]

    Mears, Kevin S

    2006-01-01

    To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

  18. High Performance Trays and Heat Exchangers in Heat Pumped Distillation Columns 

    E-Print Network [OSTI]

    Wisz, M. W.; Antonelli, R.; Ragi, E. G.

    1981-01-01

    exchangers and distillation trays permits additional energy savings by lower reboiler temperature differences, and reduced reflux requirements for a fixed column height, due to closer tray spacings. This paper surveys the heat pump systems currently...

  19. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

  20. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  1. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  2. Characteristics of various methods for solving steady state and unsteady state distillation problems 

    E-Print Network [OSTI]

    Coco, Vincent Joseph

    1965-01-01

    CHARACTERISTICS OF VARIOUS METHODS FOR SOLVING STEADY STATE AND UNSTEADY STATE DISTILLATION PROBLEMS A Thesis By VINCENT JOSEPH COCO Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1965 Major Subject: Chemical Engineering CHARACTERISTICS OF VARIOUS METHODS FOR SOLVING STEADY STATE AND UNSTEADY STATE DISTILLATION PROBLEMS A Thesis By VINCENT JOSEPH COCO Approved as to style and content by...

  3. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01

    are treated under the same conditions* Prom our knowledge of the de­ structive distillation of organic substances, the most common of which are coal, wood, bones, peat and lignite, it is reasonable to conclude also that the destructive distillation... the question as to what are the char­ acteristic properties of the two carbon residues 20 obtained from the decomposition of carbonaceous materials, termed coke and charcoal. Some author­ ities use the term coke for the carbon residue from coal and call all...

  4. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  5. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  6. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    E-Print Network [OSTI]

    Maddalena, Randy

    2012-01-01

    sulfide (H 2 S), carbonyl sulfide (OCS), sulfur dioxide (SOof hydrogen sulfide, carbonyl sulfide, methyl mercaptan,associated with the carbonyl sulfide that typically had very

  7. More Economical Sulfur Removal for Fuel Processing Plants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    crude oil it is present in sulfur-containing organic compounds which are converted into hydrocarbons and H 2 S during the removal process (hydrodesulfurization). In both cases,...

  8. Nonflame, source-induced sulfur fluorescence detector for sulfur-containing compounds

    SciTech Connect (OSTI)

    Gage, D.R.; Farwell, S.O.

    1980-12-01

    Results of some preliminary investigations of the fluorescence spectra of S/sub 2/ and the non-flame production of S/sub 2/ from sulfur-containing molecules are reported. Passage of the gas to be analyzed through a catalyst-oven containing a plug of NiO/sub 2//Al/sub 2/O/sub 3/ catalyst containing 10 wt% NiO/sub 2/ and heated to 400/sup 0/C resulted in conversion of H/sub 2/S to S/sub 2/ and elemental sulfur. The S/sub 2/ was detected by measurement of its fluorescence bands at 260 and 310nm, and elemental sulfur condensed on the cool parts of the apparatus. However, determination of sulfur-content of gas mixtures with the apparatus described herein were not as repeatable as desired, and the work is being continued on various facets of the non-flame system with work being directed toward the evaluation of different catalysts, catalyst temperature, design of a smaller detector geometry utilizing a pulsed-light excitation source, a windowless cell, and optical filters instead of monochromators to select the S/sub 2/ excitation and emission wavelengths. (BLM)

  9. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  10. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  11. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

    1988-01-01

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  12. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News Publications TraditionalWith PropaneNaturalTestAn Evolutionary Arms Race for Sulfur An

  13. Using ISC & GIS to predict sulfur deposition from coal-fired power plants 

    E-Print Network [OSTI]

    Lopez, Jose Ignacio

    1993-01-01

    The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

  14. Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer John A. Staser for the hybrid sulfur electrolyzer is controlled mainly by water transport in the cell. Water is required electrolyzer performance and operation. Experimental The experimental setup was the same as that described

  15. Sulfur removal from diesel fuel-contaminated methanol.

    SciTech Connect (OSTI)

    Lee, S. H. D.; Kumar, R.; Krumpelt, M.; Chemical Engineering

    2002-03-01

    Methanol is considered to be a potential on-board fuel for fuel cell-powered vehicles. In current distribution systems for liquid fuels used in the transportation sector, commodity methanol can occasionally become contaminated with the sulfur in diesel fuel or gasoline. This sulfur would poison the catalytic materials used in fuel reformers for fuel cells. We tested the removal of this sulfur by means of ten activated carbons (AC) that are commercially available. Tests were conducted with methanol doped with 1 vol.% grade D-2 diesel fuel containing 0.29% sulfur, which was present essentially as 33-35 wt.% benzothiophenes (BTs) and 65-67 wt.% dibenzothiophenes (DBT). In general, coconut shell-based carbons activated by high-temperature steam were more effective at sulfur removal than coal-based carbons. Equilibrium sorption data showed linear increase in sulfur capture with the increase of sulfur concentration in methanol. Both types of carbons had similar breakthrough characteristics, with the dynamic sorption capacity of each being about one-third of its equilibrium sorption capacity. Results of this study suggest that a fixed-bed sorber of granular AC can be used, such as in refueling stations, for the removal of sulfur in diesel fuel-contaminated methanol.

  16. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  17. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  18. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    by Sulfur Content and Sales Type (Cents per Gallon Excluding Taxes) Year Month Ultra Low-Sulfur Diesel Fuel Low-Sulfur Diesel Fuel Sales to End Users Sales for Resale Sales to End...

  19. X:\\L6046\\Data_Publication\\Pma\\current\\ventura\\pma.vp

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    by Sulfur Content and Sales Type (Cents per Gallon Excluding Taxes) Year Month Ultra Low-Sulfur Diesel Fuel Low-Sulfur Diesel Fuel Sales to End Users Sales for Resale Sales to End...

  20. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect (OSTI)

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  1. DEVELOPMENT AND DEPLOYMENT OF VACUUM SALT DISTILLATION AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.; Edwards, T.

    2010-10-28

    The Savannah River Site has a mission to dissolve fissile materials and disposition them. The primary fissile material is plutonium dioxide (PuO{sub 2}). To support dissolution of these materials, the Savannah River National Laboratory (SRNL) designed and demonstrated a vacuum salt distillation (VSD) apparatus using both representative radioactive samples and non-radioactive simulant materials. Vacuum salt distillation, through the removal of chloride salts, increases the quantity of materials suitable for processing in the site's HB-Line Facility. Small-scale non-radioactive experiments at 900-950 C show that >99.8 wt % of the initial charge of chloride salt distilled from the sample boat with recovery of >99.8 wt % of the ceric oxide (CeO{sub 2}) - the surrogate for PuO{sub 2} - as a non-chloride bearing 'product'. Small-scale radioactive testing in a glovebox demonstrated the removal of sodium chloride (NaCl) and potassium chloride (KCl) from 13 PuO{sub 2} samples. Chloride concentrations were distilled from a starting concentration of 1.8-10.8 wt % to a final concentration <500 mg/kg chloride. Initial testing of a non-radioactive, full-scale production prototype is complete. A designed experiment evaluated the impact of distillation temperature, time at temperature, vacuum, product depth, and presence of a boat cover. Significant effort has been devoted to mechanical considerations to facilitate simplified operation in a glovebox.

  2. Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3

    SciTech Connect (OSTI)

    Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

    1995-09-01

    The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

  3. Accelerating From vehicles on the road to the energy that powers

    E-Print Network [OSTI]

    Pennycook, Steve

    ultra-low sulfur diesel fuel rule ORNL and the National Renewable Energy Laboratory co-2 emis- sions levels with ultra-low sulfur diesel fuel. Power electronics and electric propulsion-led a comprehensive research and test program to determine the effects of diesel fuel sulfur on emissions and emission

  4. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  5. Technical Report Documentation Page 1. Report No.

    E-Print Network [OSTI]

    Texas at Austin, University of

    of Transportation and the Federal Highway Administration. 16. Abstract When TxDOT began using an ultra-low sulfur EMISSIONS TESTING, PERFORMANCE EVALUATION, AND OPERATIONAL ASSESSMENT; PROJECT EXTENSION TO EXAMINE AN ULTRA-LOW Emission Testing, Performance Evaluation and Operational Assessment; Project Extension to Examine an Ultra-Low

  6. BID MUST BE RECEIVED NO LATER THAN Please indicate: Minority Business

    E-Print Network [OSTI]

    Gering, Jon C.

    for unleaded gasoline and Number 2 Ultra Low Sulfur Diesel fuel (#2 Red Diesel) for use on their Grounds or decrease quantities. ESTIMATES: Grounds Unleaded Gasoline ­ 2,000 gallons Diesel, ultra low sulphur #2 Red gallons Diesel, ultra low sulphur #2 Red ­ 700 gallons Award will be made on an "all or none" or "item

  7. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  8. Systems and methods for reactive distillation with recirculation of light components

    DOE Patents [OSTI]

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  9. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  10. Shell. The Evolution of Movement Continues

    Broader source: Energy.gov [DOE]

    Focus of presentation is on emergence of future diesel fuel technologires and fule properties compare to ultra-low sulfur diesel fuel properties.

  11. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    to avoid disclosure of individual company data. Note: In January 2007, ultra low-sulfur diesel fuel was added. Source: Energy Information Administration Form EIA-782A,...

  12. ORNL 's Sluder elected SAE International fellow | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    policies. Sluder's research has supported the 2000 Environmental Protection Agency ultra-low sulfur diesel rulemaking, EPA decisions in 2010 and 2011 related to gasoline...

  13. Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction Technologies for the Iron and Steel Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01

    sulfur dioxide smelting reduction smelting reduction iron three-dimensional tonne top-gas recycling blast furnace tonnes per day ultra-low-

  14. Perspectives Regarding Diesel Engine Emissions Reduction in the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2004deerblock.pdf More Documents & Publications Dumping Dirty Diesels: The View From the Bridge EPA Diesel Update Ultra-Low Sulfur diesel Update & Future Light Duty Diesel...

  15. Biodiesel Effects on Diesel Particle Filter Performance: Milestone Report

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R.; Ireland, J.

    2006-03-01

    Research results on the performance of biodiesel and biodiesel blends with ultra-low sulfur diesel (ULSD) and a diesel particle filter (DPF).

  16. Port Authority of Allegheny County: Green Facts Hybrid Buses

    E-Print Network [OSTI]

    Sibille, Etienne

    began using ultra-low sulfur diesel (ULSD) on select buses in April 2005, and went system-wide with ULSD

  17. Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Sulfur Batteries Guangyuan Zheng, Qianfan Zhang, Judy J. Cha, Yuan Yang, Weiyang Li, Zhi Wei Seh, and Yi lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit

  18. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  19. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  20. Abatement of Air Pollution: Control of Sulfur Compound Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    set limits on the sulfur content of allowable fuels (1.0% by weight, dry basis) for combustion, as well as for the heat input of any fuel burning equipment (250,000 Btuhour)....

  1. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  2. Impact of Sulfur Oxides on Mercury Capture by Activated Carbon

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J.

    2007-09-15

    Recent field tests of mercury removal with activated carbon injection (ACI) have revealed that mercury capture is limited in flue gases containing high concentrations of sulfur oxides (SOx). In order to gain a more complete understanding of the impact of SOx on ACI, mercury capture was tested under varying conditions of SO2 and SO3 concentrations using a packed bed reactor and simulated flue gas (SFG). The final mercury content of the activated carbons is independent of the SO2 concentration in the SFG, but the presence of SO3 inhibits mercury capture even at the lowest concentration tested (20 ppm). The mercury removal capacity decreases as the sulfur content of the used activated carbons increases from 1 to 10%. In one extreme case, an activated carbon with 10% sulfur, prepared by H2SO4 impregnation, shows almost no mercury capacity. The results suggest that mercury and sulfur oxides are in competition for the same binding sites on the carbon surface.

  3. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  4. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect (OSTI)

    Eaton, Scott J; Bunting, Bruce G; Lewis Sr, Samuel Arthur; Fairbridge, Craig

    2009-01-01

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  5. Hybrid Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction

    SciTech Connect (OSTI)

    Eldridge, R. Bruce; Seibert, A. Frank; Robinson, Sharon; Rogers, Jo

    2005-04-01

    This report focuses on improving the existing separations systems for the two largest energy-consuming sectors: the chemicals and petroleum refining industries. It identifies the technical challenges and research needs for improving the efficiency of distillation systems. Areas of growth are also highlighted.

  6. Hydrocracking process with improved distillate selectivity with high silica large pore zeolites

    SciTech Connect (OSTI)

    Partridge, R.D.; LaPierre, R.B.

    1989-04-11

    A process is described for increasing the selectivity of the production of higher boiling distillate range product in hydrocracking reactions which can produce gasoline boiling range product and higher boiling distillate range product, which process comprises: contacting a feedstock to be hydrocracked in a hydrocracking, in the presence of hydrogen and under hydrocracking conditions, with a catalyst comprising a hydrogenation component and a zeolite which has a porous lattice structure having pores with a dimension greater than 6 Angstroms and a hydrocarbon sorption capacity for hexane of at least 6 percent and has a framework silica:alumina ratio of at least about 50:1, whereby the selectivity of the process for production of the higher boiling distillate range product is preferentially increased, wherein the distillate selectivity is defined by reference to the amounts of the 165/sup 0/C-343/sup 0/C (330 F-650/sup 0/F) fraction and the total 343/sup 0/C-fraction in the hydrocracker effluent.

  7. Evaluation of Intake Limiting Agents in a Self-fed Dried Distillers' Supplement 

    E-Print Network [OSTI]

    Sugg, Joel D

    2013-08-14

    Response to range supplementation is in part driven by level of supplement consumed and amount of associated variation. In order to evaluate intake limiting agents in a self-fed dried distillers’ grain supplement (DDG), heifers (n=59) in Trial 1...

  8. Hybrid magic state distillation for universal fault-tolerant quantum computation

    E-Print Network [OSTI]

    Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

    2014-12-11

    A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

  9. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E hydrogen gas (so- called protium) must be used. It is necessary to avoid transfers of - to impurities imposes strict and critical requirements on the hydrogen gas system supporting the detector. Desirable

  10. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process, Dhahran, 31261, Saudi Arabia Abstract This paper studies the synthesis and the design of methanol recovery that methanol could be recovered completely from the hydrocarbon when 5 equilibrium trays in the extraction

  11. Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column Edward the column . We have previously shown (Jimenez et al. 2003) that optimaloperation of serial heat exchangers total heat exchanger area in different trays and calculate the optimal allocation of a given heat

  12. Black-Box Identification for PLC based MPC of a Binary Distillation Column

    E-Print Network [OSTI]

    Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

  13. An electrochemical Claus process for sulfur recovery

    SciTech Connect (OSTI)

    Pujare, N.U.; Tsai, K.J.; Sammuells, A.F. (Eltron Research, Inc., Aurora, IL (US))

    1989-12-01

    Electrochemical oxidation of H{sub 2}S to give sulfur and water was achieved at 900{degrees}C using fuel cells possessing the general configuration where anode electrocatalysts experimentally investigated for promoting the subject oxidation reaction included WS{sub 2} and the thiospinels CuNi{sub 2}S{sub 4}, CuCo{sub 2}S{sub 4}, CuFe{sub 2}S{sub 4}, and NiFe{sub 2}S{sub 4}. The predominant oxidizable electroactive species present in the fuel cell anode compartment was suggested to be hydrogen originating from the initial thermal dissociation of H{sub 2}S (H{sub 2}S {r reversible} H{sub 2} + 1/2 S{sub 2}) at fuel cell operating temperatures. Rapid anode kinetics were found for the anodic reaction with the empirical trend for exchange currents (i{sub o}) per geometric area being found to be NiFe{sub 2}S{sub 4}{gt}WS{sub 2}{gt}CuCo{sub 2}S{sub 4}{gt}CuFe{sub 2}S{sub 4}{approx equal}NiCo{sub 2}S{sub 4}{gt}CuNi{sub 2}S{sub 4}.

  14. Designing an ultra low quiescent current buck switching regulator

    E-Print Network [OSTI]

    Gardner, John Underhill

    2008-01-01

    The new buck regulator proposed in this thesis was designed to operate with only a few micro-amps of supply current during no load output conditions, while maintaining low output voltage ripple. The regulator also has high ...

  15. Field Demonstration of High-Efficiency Ultra-Low-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Alliance Building Technologies Office Office of Energy Efficiency and Renewable Energy U.S. Department of Energy By: Rebecca Legett, Navigant Consulting, Inc....

  16. An Ultra-Low-Power Programmable Analog Bionic Ear Processor

    E-Print Network [OSTI]

    Sarpeshkar, Rahul

    2004-09-28

    We report a programmable analog bionic ear (cochlear implant) processor in a 1.5µm BiCMOS technology with a power

  17. Power management circuits for ultra-low power systems

    E-Print Network [OSTI]

    El-Damak, Dina Reda

    2015-01-01

    Power management circuits perform a wide range of vital tasks for electronic systems including DC-DC conversion, energy harvesting, battery charging and protection as well as dynamic voltage scaling. The impact of the ...

  18. Novel Ultra-Low-Energy Consumption Ultrasonic Clothes Dryer

    Broader source: Energy.gov [DOE]

    Lead Performer: Oak Ridge National Laboratory – Oak Ridge, TNPartners: General Electric Appliances – Louisville, KY

  19. Ultra-Low NOx Premixed Industrial Burner | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology licensed to Maxon Corporation and sold as the M-PAKT burner. Over 1408 burners estimated to reduce NOx by over 1.550 million pounds in 2011. Applications Can be...

  20. Stable, Ultra-Low Residence Time Partial Oxidation

    DOE Patents [OSTI]

    Schmidt, Lanny D. (Minneapolis, MN); Hickman, Daniel A. (Midland, MI)

    1997-07-15

    A process for the catalytic partial oxidation of methane in gas phase at very short residence time (800,000 to 12,000,000 hr.sup.-1) by contacting a gas stream containing methane and oxygen with a metal supported catalyst, such as platinum deposited on a ceramic monolith.

  1. Novel Ultra-Low-Energy Consumption Ultrasonic Clothes Dryer ...

    Energy Savers [EERE]

    ultrasonic transducer can dry fabric 2 orders of magnitudes faster than thermal drying. Preliminary measured drying time of fabric sample using ultrasonic cold...

  2. Ultra low thermal expansion, highly thermal shock resistant ceramic

    DOE Patents [OSTI]

    Limaye, S.Y.

    1996-01-30

    Three families of ceramic compositions having the given formula: {phi}{sub 1+X}Zr{sub 4}P{sub 6{minus}2X}Si{sub 2X}O{sub 24}, {phi}{sub 1+X}Zr{sub 4{minus}2X}Y{sub 2X}P{sub 6}O{sub 24} and {phi}{sub 1+X}Zr{sub 4{minus}X}Y{sub X}P{sub 6{minus}2X}Si{sub X}O{sub 24} wherein {phi} is either strontium or barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures. 7 figs.

  3. Method of produce ultra-low friction carbon films

    DOE Patents [OSTI]

    Erdemir, Ali (Naperville, IL); Fenske, George R. (Downers Grove, IL); Eryilmaz, Osman Levent (Istanbul, TK); Lee, Richard H. (Lemont, IL)

    2003-04-15

    A method and article of manufacture of amorphous diamond-like carbon. The method involves providing a substrate in a chamber, providing a mixture of a carbon containing gas and hydrogen gas with the mixture adjusted such that the atomic molar ratio of carbon to hydrogen is less than 0.3, including all carbon atoms and all hydrogen atoms in the mixture. A plasma is formed of the mixture and the amorphous diamond-like carbon film is deposited on the substrate. To achieve optimum bonding an intervening bonding layer, such as Si or SiO.sub.2, can be formed from SiH.sub.4 with or without oxidation of the layer formed.

  4. An Ultra-Low Background PMT for Liquid Xenon Detectors

    E-Print Network [OSTI]

    D. S. Akerib; X. Bai; E. Bernard; A. Bernstein; A. Bradley; D. Byram; S. B. Cahn; M. C. Carmona-Benitez; D. Carr; J. J. Chapman; Y-D. Chan; K. Clark; T. Coffey; L. deViveiros; M. Dragowsky; E. Druszkiewicz; B. Edwards; C. H. Faham; S. Fiorucci; R. J. Gaitskell; K. R. Gibson; C. Hall; M. Hanhardt; B. Holbrook; M. Ihm; R. G. Jacobsen; L. Kastens; K. Kazkaz; N. Larsen; C. Lee; K. Lesko; A. Lindote; M. I. Lopes; A. Lyashenko; D. C. Malling; R. Mannino; D. McKinsey; D. Mei; J. Mock; M. Morii; H. Nelson; F. Neves; J. A. Nikkel; M. Pangilinan; K. Pech; P. Phelps; T. Shutt; C. Silva; W. Skulski; V. N. Solovov; P. Sorensen; J. Spaans; T. Stiegler; M. Sweany; M. Szydagis; D. Taylor; J. Thomson; M. Tripathi; S. Uvarov; J. R. Verbus; N. Walsh; R. Webb; J. T. White; M. Wlasenko; F. L. H. Wolfs; M. Woods; C. Zhang

    2013-06-24

    Results are presented from radioactivity screening of two models of photomultiplier tubes designed for use in current and future liquid xenon experiments. The Hamamatsu 5.6 cm diameter R8778 PMT, used in the LUX dark matter experiment, has yielded a positive detection of four common radioactive isotopes: 238U, 232Th, 40K, and 60Co. Screening of LUX materials has rendered backgrounds from other detector materials subdominant to the R8778 contribution. A prototype Hamamatsu 7.6 cm diameter R11410 MOD PMT has also been screened, with benchmark isotope counts measured at <0.4 238U / <0.3 232Th / <8.3 40K / 2.0+-0.2 60Co mBq/PMT. This represents a large reduction, equal to a change of \\times 1/24 238U / \\times 1/9 232Th / \\times 1/8 40K per PMT, between R8778 and R11410 MOD, concurrent with a doubling of the photocathode surface area (4.5 cm to 6.4 cm diameter). 60Co measurements are comparable between the PMTs, but can be significantly reduced in future R11410 MOD units through further material selection. Assuming PMT activity equal to the measured 90% upper limits, Monte Carlo estimates indicate that replacement of R8778 PMTs with R11410 MOD PMTs will change LUX PMT electron recoil background contributions by a factor of \\times1/25 after further material selection for 60Co reduction, and nuclear recoil backgrounds by a factor of \\times 1/36. The strong reduction in backgrounds below the measured R8778 levels makes the R11410 MOD a very competitive technology for use in large-scale liquid xenon detectors.

  5. Ultra-low Q values for neutrino mass measurements

    E-Print Network [OSTI]

    Joachim Kopp; Alexander Merle

    2010-04-21

    We investigate weak nuclear decays with extremely small kinetic energy release (Q value) and thus extremely good sensitivity to the absolute neutrino mass scale. In particular, we consider decays into excited daughter states, and we show that partial ionization of the parent atom can help to tune Q values to low-Q decays might only be feasible if no ionization is required, and if future improvements in isotope production technology, nuclear mass spectroscopy, and atomic structure calculations are possible. Experiments using ions, however, are extremely challenging due to the large number of ions that must be stored. New precision data on nuclear excitation levels could help to identify further isotopes with low-Q decay modes and possibly less challenging requirements.

  6. Demonstration of Ultra Low Dissipation Optomechanical Resonators on a Chip

    E-Print Network [OSTI]

    G. Anetsberger; R. Rivière; A. Schliesser; O. Arcizet; T. J. Kippenberg

    2008-07-18

    Cavity-enhanced radiation-pressure coupling of optical and mechanical degrees of freedom gives rise to a range of optomechanical phenomena, in particular providing a route to the quantum regime of mesoscopic mechanical oscillators. A prime challenge in cavity optomechanics has however been to realize systems which simultaneously maximize optical finesse and mechanical quality. Here we demonstrate for the first time independent control over both mechanical and optical degree of freedom within one and the same on-chip resonator. The first direct observation of mechanical normal mode coupling in a micromechanical system allows for a quantitative understanding of mechanical dissipation. Subsequent optimization of the resonator geometry enables intrinsic material loss limited mechanical Q-factors, rivalling the best values reported in the high MHz frequency range, while simultaneously preserving the resonators' ultra-high optical finesse. Besides manifesting a complete understanding of mechanical dissipation in microresonator based optomechanical systems, our results provide an ideal setting for cavity optomechanics.

  7. POLYMER PROGRAM SEMINAR "Ultra-low Wear Fluoropolymer Composites

    E-Print Network [OSTI]

    Alpay, S. Pamir

    on Teflon* PTFE 7C (a granular molding resin) and certain alumina "nanoparticles." These materials of the PTFE composite by over four orders of magnitude. It is believed that the "nano" sized alumina somehow shuts down the flaky wear mechanism of the PTFE, and stabilizes the formation of a persistent transfer

  8. Ultra-low threshold Gallium Nitride photonic crystal nanobeam laser

    E-Print Network [OSTI]

    Niu, Nan; Woolf, Alexander; Wang, Danquing; Zhu, Tongtong; Quan, Qimin; Oliver, Rachel A.; Hu, Evelyn L.

    2015-06-10

    to achieve lasing in the QW structures, heating of the nanobeam structures and effects such as free carrier absorption may explain the lower percentage of successful lasing in the QW devices. For 5 fQW nanobeams that were analyzed in detail, the lasing... with excellent performance. Because of their compact size and low thresholds, these devices are excellent candidates for efficient, on-chip optical sources in the blue portion of the spectrum. Corresponding Author *email: nanniu...

  9. Thermally Stable Ultra-Low Temperature Oxidation Catalysts

    SciTech Connect (OSTI)

    Szanyi, Janos; Peden, Charles HF; Howden, Ken; Kim, Chang H.; Oh, Se H.; Schmieg, Steven J.

    2014-12-09

    This annual reports describes recent results of a CRADA between General Motors Company (GM) and Battelle/Pacific Northwest National Laboratory (PNNL). In the CRADA, we are investigating a number of candidate low temperature oxidation catalysts as fresh materials, and after realistic laboratory- and engine-aging. These studies will lead to a better understanding of fundamental characteristics and various aging factors that impact the long-term performance of catalysts, while also providing an assessment of the appropriateness of the laboratory conditions in realistically reproducing the effects of actual engine aging conditions.

  10. ULTRA LOW NOx CATALYTIC COMBUSTION FOR IGCC POWER PLANTS

    SciTech Connect (OSTI)

    Lance L. Smith

    2004-03-01

    Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using PCI's two-stage (catalytic / gas-phase) combustion process for syngas fuel. In this process, the first stage is a Rich-Catalytic Lean-burn (RCL{trademark}) catalytic reactor, wherein a fuel-rich mixture contacts the catalyst and reacts while final and excess combustion air cool the catalyst. The second stage is a gas-phase combustor, wherein the catalyst cooling air mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During the reporting period, PCI successfully achieved NOx = 0.011 lbs/MMBtu at 10 atm pressure (corresponding to 2.0 ppm NOx corrected to 15% O{sub 2} dry) with near-zero CO emissions, surpassing the project goal of < 0.03 lbs/MMBtu NOx. These emissions levels were achieved at scaled (10 atm, sub-scale) baseload conditions corresponding to Tampa Electric's Polk Power Station operation on 100% syngas (no co-firing of natural gas).

  11. Ultra low thermal expansion, highly thermal shock resistant ceramic

    DOE Patents [OSTI]

    Limaye, Santosh Y. (1440 Sandpiper Cir. #38, Salt Lake City, UT 84117)

    1996-01-01

    Three families of ceramic compositions having the given formula: .phi..sub.1+X Zr.sub.4 P.sub.6-2X Si.sub.2X O.sub.24, .phi..sub.1+X Zr.sub.4-2X Y.sub.2X P.sub.6 O.sub.24 and .phi..sub.1+X Zr.sub.4-X Y.sub.X P.sub.6-2X Si.sub.X O.sub.24 wherein .phi. is either Strontium or Barium and X has a value from about 0.2 to about 0.8 have been disclosed. Ceramics formed from these compositions exhibit very low, generally near neutral, thermal expansion over a wide range of elevated temperatures.

  12. Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIX FOrigin

  13. Field Demonstration of High Efficiency Ultra-Low-Temperature Laboratory

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n cEnergyNaturaldefinesMayWorkshop: Summary Report 1 | P a gThorium,

  14. Ultra Low Density Amorphous Shape Memory polymer Foams. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of rare Kaon and(Conference) |Article) | SciTech Connect

  15. Ultra Low Density Amorphous Shape Memory polymer Foams. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of rare Kaon and(Conference) |Article) | SciTech ConnectSciTech

  16. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  17. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  18. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  19. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  20. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  1. Weigh options for meeting future gasoline sulfur specifications

    SciTech Connect (OSTI)

    Johnson, T.E.

    1997-03-01

    The most frequently mentioned methods for reducing pool gasoline sulfur to the 50-ppm range are FCC feed hydrotreating and desulfurization of heavy cat naptha (HCN). Of these, cat feed hydrotreating (CFH) is preferred because of the compelling economics of improved FCC gasoline yield. Also, the additional C{sub 3}/C{sub 4} olefin yield opens up the possibility of additional production of sulfur-free alkylate and oxygenate. In addition to the obvious yield benefits, the ability to upgrade lower quality, higher sulfur stocks for inclusion in the FCC charge slate, while lowering flue gas SO{sub x} emissions, is also advantageous to the refiner. However, depending o the level of FCC feed sulfur and the severity of hydrotreating used, it may not be possible to meet 50-ppm sulfur in the gasoline pool. Two possible solutions to this problem are to use: (1) a very severe cat feed hydrotreating operation (i.e., 98%-plus desulfurization), (2) partial conversion hydrocracking.

  2. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01

    This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than the potential service costs reduction, it is very significant. It represents an important red

  3. Gas phase reaction of sulfur trioxide with water vapor

    SciTech Connect (OSTI)

    Kolb, C.E.; Molina, M.J.; Jayne, J.T.; Meads, R.F.; Worsnop, D.R.

    1994-12-31

    Sulfur trioxide (SO3) has long been known to react with water to produce sulfuric acid (H2S04). It has been commonly assumed that the gas phase reaction in the Earth`s atmosphere between SO3 and water vapor to produce sulfuric acid vapor is an important step in the production of sulfuric acid aerosol particles. The kinetics of the gas phase reaction of SO3 with water vapor have previously been studied by Castleman and co-workers, Wang et al and Reiner and Arnold. Each of these studies was carried out in a flow reactor, with the first two studies performed at low pressure (1-10 Torr) and the latter from approx. 30 to 260 Torr. Each of these studies measured SO3 decays over a range of H2O vapor levels, obtaining data consistent with interpreting the reaction of gaseous SO3 and H2O as a bimolecular process. It is not clear why previous experimental studies failed to observe a nonlinear dependence of SO3 consumption on water vapor concentration. It is probable that sufficient water dimer exists in much of the Earth`s atmosphere to allow dimer reactions to participate in sulfuric acid vapor formation.

  4. ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Amoroso, J.; Fox, K.

    2011-09-07

    The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

  5. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  6. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01

    S breakthrough time and sulfur capture capacity increased asspace velocity on H 2 S on sulfur capture capacity for H 2 Sbased on the optimal sulfur capture capacity under CE-CERT

  7. Preliminary Investigation of Sulfur Loading in Hanford LAW Glass

    SciTech Connect (OSTI)

    Vienna, John D.; Hrma, Pavel R.; Buchmiller, William C.; Ricklefs, Joel S.

    2004-04-01

    A preliminary estimate was developed for loading limits for high-sulfur low-activity waste (LAW) feeds that will be vitrified into borosilicate glass at the Hanford Site in the waste-cleanup effort. Previous studies reported in the literature were consulted to provide a basis for the estimate. The examination of previous studies led to questions about sulfur loading in Hanford LAW glass, and scoping tests were performed to help answer these questions. These results of these tests indicated that a formulation approach developed by Vienna and colleagues shows promise for maximizing LAW loading in glass. However, there is a clear need for follow-on work. The potential for significantly lowering the amount of LAW glass produced at Hanford (after the initial phase of processing) because of higher sulfur tolerances may outweigh the cost and effort required to perform the necessary testing.

  8. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report

    SciTech Connect (OSTI)

    NONE

    1997-01-01

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

  9. Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers 

    E-Print Network [OSTI]

    Nelson, R. E.

    1982-01-01

    The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

  10. Direct sulfur recovery during sorbent regeneration. Final report

    SciTech Connect (OSTI)

    Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1993-08-01

    The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

  11. Improving fractionation lowers butane sulfur level at Saudi gas plant

    SciTech Connect (OSTI)

    Harruff, L.G.; Martinie, G.D.; Rahman, A. [Saudi Arabian Oil Co., Dhahran (Saudi Arabia)

    1998-10-12

    Increasing the debutanizer reflux/feed ratio to improve fractionation at an eastern Saudi Arabian NGL plant reduced high sulfur in the butane product. The sulfur resulted from dimethyl sulfide (DMS) contamination in the feed stream from an offshore crude-oil reservoir in the northern Arabian Gulf. The contamination is limited to two northeastern offshore gas-oil separation plants operated by Saudi Arabian Oil Co. (Saudi Aramco) and, therefore, cannot be transported to facilities outside the Eastern Province. Two technically acceptable solutions for removing this contaminant were investigated: 13X molecular-sieve adsorption of the DMS and increased fractionation efficiency. The latter would force DMS into the debutanizer bottoms.

  12. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  13. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  14. Composition-explicit distillation curves of aviation fuel JP-8 and a coal-based jet fuel

    SciTech Connect (OSTI)

    Beverly L. Smith; Thomas J. Bruno [National Institute of Standards and Technology, Boulder, CO (United States). Physical and Chemical Properties Division

    2007-09-15

    We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications to the classical measurement provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements that are true thermodynamic state points; (3) temperature, volume, and pressure measurements of low uncertainty suitable for an equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; (6) a trace chemical analysis of each distillate fraction; and (7) a corrosivity assessment of each distillate fraction. The most significant modification is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to the measurement of rocket propellant, gasoline, and jet fuels. In this paper, we present the application of the technique to representative batches of the military aviation fuel JP-8, and also to a coal-derived fuel developed as a potential substitute. We present not only the distillation curves but also a chemical characterization of each fraction and discuss the contrasts between the two fluids. 26 refs., 5 figs., 6 tabs.

  15. Structural insight into the assembly of iron-sulfur clusters and their function in radical generation

    E-Print Network [OSTI]

    Vey, Jessica L. (Jessica Lynn)

    2008-01-01

    This thesis addresses two emerging areas in the study of iron-sulfur cluster biochemistry: bioassembly of iron-sulfur clusters, and their involvement in initiation of radical chemistry. The structure of a cysteine desulfurase ...

  16. KINETICS AND MECHANISM FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDE ON CARBON IN AQUEOUS SUSPENSIONS

    E-Print Network [OSTI]

    Brodzinsky, R.

    2012-01-01

    AND MECHANISM FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDEmechanism for the catalytic oxidation of in an aqueous sus1ECHANISf 1 1 FOR TilE CATALYTIC OXIDATION OF SULFUR DIOXIDE

  17. A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts

    E-Print Network [OSTI]

    Tang, Hairong

    2005-01-01

    Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

  18. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  19. Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process

    SciTech Connect (OSTI)

    Klint, V.W.; Dale, P.R.; Stephenson, C.

    1997-10-01

    Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus process also allow for use of the methane/H{sub 2}S separation unit as a Claus tail gas treating unit by recycling the CNG Claus tail gas stream. This allows for virtually 100 percent sulfur recovery efficiency (virtually zero SO{sub 2} emissions) by recycling the sulfur laden tail gas to extinction. The use of the tail gas recycle scheme also deemphasizes the conventional requirement in Claus units to have high unit conversion efficiency and thereby make the operation much less affected by process upsets and feed gas composition changes. The development of these technologies has been ongoing for many years and both the CFZ and the TPC processes have been demonstrated at large pilot plant scales. On the other hand, prior to this project, the CNG Claus process had not been proven at any scale. Therefore, the primary objective of this portion of the program was to design, build and operate a pilot scale CNG Claus unit and demonstrate the required fundamental reaction chemistry and also demonstrate the viability of a reasonably sized working unit.

  20. A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy

    E-Print Network [OSTI]

    Paytan, Adina

    A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy Abstract: The sulfur isotopic.4. Measurement and Materials for Sulfur Isotope Stratigraphy 171 9.4.1. Isotope Analyses 171 9.4.2. Materials. The features in the record can also be used to correlate between stratigraphic sections and sequences

  1. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India*

    E-Print Network [OSTI]

    The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India* A.L. Ganesan of methane, nitrous oxide and sulfur hexafluoride in Northeast India A. L. Ganesan1, A. Chatterjee2, R. G-frequency atmospheric measurements of methane (CH4), nitrous oxide (N2O) and sulfur hexafluo- ride (SF6) from Darjeeling

  2. Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions

    E-Print Network [OSTI]

    Denver, University of

    sulfur diesel fuel is less expensive due to reduced taxes and as such may be prone to illegal use in on-road November 2005; published online 18 January 2006 A remote sensor for measuring on-road vehicles passing of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

  3. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    DOE Patents [OSTI]

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  4. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  5. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  6. Catalyst added to Claus furnace reduces sulfur losses

    SciTech Connect (OSTI)

    Luinstra, E.A.; d'Haene, P.E. (Shell Canada Ltd., Toronto, ON (Canada). Oakville Research Centre)

    1989-07-01

    Several substances effectively catalyze the reduction of carbon disulfide in Claus gas streams at Claus reaction furnace conditions (about 1,000{sup 0}C). Some conversion of carbonyl sulfide also occurs. Carbon disulfide and carbonyl sulfide as well-known problem compounds that reduce sulfur recovery efficiency in many sulfur recovery plants. Installation of a suitable catalytic material in the reaction furnace promises significant improvement of Claus plant efficiency, and prolonged life of the catalytic converters. Almost every Claus sulfur recovery plant makes some carbon disulfide (CS/sub 2/) and carbonyl sulfide (COS) in the reaction furnace, and in many of these plants, these compounds constitute a significant problem. CS/sub 2/ and COS often comprise more than 50% of sulfur losses in the tail gas. This article reexamines the issue of CS/sub 2/ and COS in the Claus plant. The relative importance of these two troublesome components is explored with data accumulated from Shell Canada Claus plants. The authors discuss which factors tend to produce these components. Then a method for reducing CS/sub 2/ and COS virtually at the source will be introduced.

  7. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  8. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  9. Auction design and the market for sulfur dioxide emissions

    E-Print Network [OSTI]

    Joskow, Paul L.

    1996-01-01

    Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

  10. Hydroprocessing key issue in low-sulfur' era

    SciTech Connect (OSTI)

    Not Available

    1993-07-26

    Refiners gave heavy attention to hydroprocessing operations at the most recent National Petroleum Refiners Association annual question and answer session on refining and petrochemical technology. Among the topics covered were diesel color, blending to meet diesel sulfur specs, and ammonia injection in hydrocracking units. The panelists also related their experiences with increasing vacuum gas oil conversion in hydrocracking operations. These discussions are reproduced here.

  11. Sulfur controls edge closer in acid-rain debate

    SciTech Connect (OSTI)

    Not Available

    1984-10-04

    The role of airborne sulfur emissions from midwestern and southern coal-fired power plants in exacerbating the acid rain problem is discussed. This problem is discussed from the standpoint of legislation, compliance costs, scrubber performance and cost, and chemistry of acid rains.

  12. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  13. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01

    This document summarizes progress on the Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2000 through September 30, 2000. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid will also be determined, as will the removal of arsenic, a known poison for NOX selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), First Energy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the second reporting period for the subject Cooperative Agreement. During this period, the first of four short-term sorbent injection tests were conducted at the First Energy Bruce Mansfield Plant. This test determined the effectiveness of dolomite injection through out-of-service burners as a means of controlling sulfuric acid emissions from this unit. The tests showed that dolomite injection could achieve up to 95% sulfuric acid removal. Balance of plant impacts on furnace slagging and fouling, air heater fouling, ash loss-on-ignition, and the flue gas desulfurization system were also determined. These results are presented and discussed in this report.

  14. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    and PAD District (Cents per Gallon Excluding Taxes) Geographic Area Month Ultra Low-Sulfur Diesel Fuel Low-Sulfur Diesel Fuel Sales to End Users Sales for Resale Sales to End...

  15. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    District (Cents per Gallon Excluding Taxes) - Continued Geographic Area Month Ultra Low-Sulfur Diesel Fuel Low-Sulfur Diesel Fuel Sales to End Users Sales for Resale Sales to End...

  16. X:\\L6046\\Data_Publication\\Pma\\current\\ventura\\pma.vp

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    and PAD District (Cents per Gallon Excluding Taxes) Geographic Area Month Ultra Low-Sulfur Diesel Fuel Low-Sulfur Diesel Fuel Sales to End Users Sales for Resale Sales to End...

  17. Appendix D: FEDERAL EMERGENCY AUTHORITIES AND POLICY DIRECTIVES

    Office of Environmental Management (EM)

    Institute, 2013. Agency Waiver Used for Allows EPA 40 C.F.R. 80.510 and 80.520 Ultra-Low Sulfur Diesel Allows the use of higher sulfur diesel in older cars, generators,...

  18. North Carolina State University, Campus Box 7409, Raleigh, NC 27695 | 919-513-7831 www.cleantransportation.org 8/13/13 Advancing Clean Energy for a Sustainable Economy

    E-Print Network [OSTI]

    biodiesel perform? Because biodiesel is a better lubricant, using it reduces engine wear and tear. Ultra-low-sulfur particulate matter, carbon monoxide, sulfur dioxide, and unburned hydrocarbon emissions. It can also reduce

  19. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M; Lytle, J.M.; Ruch, R.R.; Kruse, C.W.; Chaven, C.; Hackley, K.C.; Hughes, R.E.; Harvey, R.D.; Frost, J.K. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States); Huffman, G.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States)

    1992-09-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal preoxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation.

  20. ENGINEERING EVALUATION OF HOT-GAS DESULFURIZATION WITH SULFUR RECOVERY

    SciTech Connect (OSTI)

    G.W. ROBERTS; J.W. PORTZER; S.C. KOZUP; S.K. GANGWAL

    1998-05-31

    Engineering evaluations and economic comparisons of two hot-gas desulfurization (HGD) processes with elemental sulfur recovery, being developed by Research Triangle Institute, are presented. In the first process, known as the Direct Sulfur Recovery Process (DSRP), the SO{sub 2} tail gas from air regeneration of zinc-based HGD sorbent is catalytically reduced to elemental sulfur with high selectivity using a small slipstream of coal gas. DSRP is a highly efficient first-generation process, promising sulfur recoveries as high as 99% in a single reaction stage. In the second process, known as the Advanced Hot Gas Process (AHGP), the zinc-based HGD sorbent is modified with iron so that the iron portion of the sorbent can be regenerated using SO{sub 2} . This is followed by air regeneration to fully regenerate the sorbent and provide the required SO{sub 2} for iron regeneration. This second-generation process uses less coal gas than DSRP. Commercial embodiments of both processes were developed. Process simulations with mass and energy balances were conducted using ASPEN Plus. Results show that AHGP is a more complex process to operate and may require more labor cost than the DSRP. Also capital costs for the AHGP are higher than those for the DSRP. However, annual operating costs for the AHGP appear to be considerably less than those for the DSRP with a potential break-even point between the two processes after just 2 years of operation for an integrated gasification combined cycle (IGCC) power plant using 3 to 5 wt% sulfur coal. Thus, despite its complexity, the potential savings with the AHGP encourage further development and scaleup of this advanced process.